F-16XL ship #1 - CAWAP boundary layer rakes and hot film on left wing

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the boundary layer hot film and the boundary layer rakes on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Pressure vessel with improved impact resistance and method of making the same

NASA Technical Reports Server (NTRS)

DeLay, Thomas K. (Inventor); Patterson, James E. (Inventor); Olson, Michael A. (Inventor)

2010-01-01

A composite overwrapped pressure vessel is provided which includes a composite overwrapping material including fibers disposed in a resin matrix. At least first and second kinds of fibers are used. These fibers typically have characteristics of high strength and high toughness to provide impact resistance with increased pressure handling capability and low weight. The fibers are applied to form a pressure vessel using wrapping or winding techniques with winding angles varied for specific performance characteristics. The fibers of different kinds are dispersed in a single layer of winding or wound in distinct separate layers. Layers of fabric comprised of such fibers are interspersed between windings for added strength or impact resistance. The weight percentages of the high toughness and high strength materials are varied to provide specified impact resistance characteristics. The resin matrix is formed with prepregnated fibers or through wet winding. The vessels are formed with or without liners.

Structural evolution of gypsum under high pressure: single-crystal X-ray experiments revisited

NASA Astrophysics Data System (ADS)

Li, Tsung-Lung; Lee, Pei-Lun

2018-05-01

The structures of gypsum at pressures up to approximately 4 GPa are studied with density functional theory (DFT) and thoroughly compared with single-crystal X-ray diffraction experiments reported in the literature [Comodi et al. in (Am Miner 93:1530-1537, 2008)]. It is found that the exchange-correlation density functional revPBE (revised Perdew-Burke-Ernzerhof) in conjunction with a nonlocal van der Waals (vdW) correction is capable of modeling the lattice constants, axial compressibility, and bulk modulus with good accuracy, suggesting that the inclusion of the vdW functional is crucially important for understanding the structure of hydrous minerals. To gain further physical insights, the geometric parameters associated with the constituting components of gypsum (water molecules, SO4 tetrahedra, and CaO8 polyhedra) are analyzed and compared with the experimental values. DFT simulations show that, under pressure, the polyhedral layers remain as nearly planar sheets of interconnecting SO4 tetrahedra and CaO8 polyhedra without further crinkling. DFT analysis on the layer compressibility along the major crystal axis reveals that, in contrast to experimental reports, the hydrous interlayer is less compressible than the polyhedral layer. Squeezed by the lateral pressure, the water molecules in the hydrous interlayer become better affixed along the major axis, making the interlayer harder to compress along this axis.

Using stepped anvils to make even insulation layers in laser-heated diamond-anvil cell samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, Zhixue; Gu, Tingting; Dobrosavljevic, Vasilije

Here, we describe a method to make even insulation layers for high-pressure laser-heated diamond-anvil cell samples using stepped anvils. Moreover, the method works for both single-sided and double-sided laser heating using solid or fluid insulation. The stepped anvils are used as matched pairs or paired with a flat culet anvil to make gasket insulation layers and not actually used at high pressures; thus, their longevity is ensured. We also compare the radial temperature gradients and Soret diffusion of iron between self-insulating samples and samples produced with stepped anvils and find that less pronounced Soret diffusion occurs in samples with evenmore » insulation layers produced by stepped anvils.« less

Using stepped anvils to make even insulation layers in laser-heated diamond-anvil cell samples

DOE PAGES

Du, Zhixue; Gu, Tingting; Dobrosavljevic, Vasilije; ...

2015-09-01

Here, we describe a method to make even insulation layers for high-pressure laser-heated diamond-anvil cell samples using stepped anvils. Moreover, the method works for both single-sided and double-sided laser heating using solid or fluid insulation. The stepped anvils are used as matched pairs or paired with a flat culet anvil to make gasket insulation layers and not actually used at high pressures; thus, their longevity is ensured. We also compare the radial temperature gradients and Soret diffusion of iron between self-insulating samples and samples produced with stepped anvils and find that less pronounced Soret diffusion occurs in samples with evenmore » insulation layers produced by stepped anvils.« less

Experimental Investigation of Transition to Turbulence as Affected By Passing Wakes

NASA Technical Reports Server (NTRS)

Kaszeta, Richard W.; Ashpis, David E.; Simon, Terrence W.

2001-01-01

This paper presents experimental results from a study of the effects of periodically passing wakes upon laminar-to-turbulent transition and separation in a low-pressure turbine passage. The test section geometry is designed to simulate unsteady wakes in turbine engines for studying their effects on boundary layers and separated flow regions over the suction surface by using a single suction surface and a single pressure surface to simulate a single turbine blade passage. Single-wire, thermal anemometry techniques are used to measure time-resolved and phase averaged, wall-normal profiles of velocity, turbulence intensity and intermittency at multiple streamwise locations over the turbine airfoil suction surface. These data are compared to steady-state wake-free data collected in the same geometry to identify the effects of wakes upon laminar-to-turbulent transition. Results are presented for flows with a Reynolds number based on suction surface length and stage exit velocity of 50,000 and an approach flow turbulence intensity of 2.5%. While both existing design and experimental data are primarily concerned with higher Reynolds number flows (Re greater than 100,000), recent advances in gas turbine engines, and the accompanying increase in laminar and transitional flow effects, have made low-Re research increasingly important. From the presented data, the effects of passing wakes on transition and separation in the boundary layer, due to both increased turbulence levels and varying streamwise pressure gradients are presented. The results show how the wakes affect transition. The wakes affect the flow by virtue of their difference in turbulence levels and scales from those of the free-stream and by virtue of their ensemble- averaged velocity deficits, relative to the free-stream velocity, and the concomitant changes in angle of attack and temporal pressure gradients. The relationships between the velocity oscillations in the freestream and the unsteady velocity profile shapes in the near-wall flow are described. In this discussion is support for the theory that bypass transition is a response of the near-wall viscous layer to pressure fluctuations imposed upon it from the free-stream flow. Recent transition models are based on that premise. The data also show a significant lag between when the wake is present over the surface and when transition begins.cous layer to pressure fluctuations imposed upon it from the free-stream flow. Recent transition models are based on that premise. The data also show a significant lag between when the wake is present over the surface and when transition begins.cous layer to pressure fluctuations imposed upon it from the free-stream flow. Recent transition models are based on that premise. The data also show a significant lag between when the wake is present over the surface and when transition begins.

F-16XL ship #1 wing close-up showing boundary layer detection Preston tubes

NASA Technical Reports Server (NTRS)

1995-01-01

This photo shows the boundary layer Preston tubes mounted on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Controlling the surface termination of NdGaO3 (110): the role of the gas atmosphere.

PubMed

Cavallaro, Andrea; Harrington, George F; Skinner, Stephen J; Kilner, John A

2014-07-07

In this work the effect of gas atmosphere on the surface termination reconstruction of single crystal NdGaO3 (110) (NGO) during thermal annealing was analyzed. Using Low Energy Ion Scattering (LEIS) it has been possible to study the chemical composition of the first atomic layer of treated NGO single crystal samples. NGO has been analyzed both as-received and after a specific thermal treatment at 1000 °C under different gas fluxes (argon, nitrogen, static air, synthetic air, nitrogen plus 5% hydrogen and wet synthetic air respectively). Thermal annealing of perovskite single crystals, as already reported in the literature, is used to obtain a fully A-cation surface termination. Nevertheless the effect of the gas-atmosphere on this process has not been previously reported. By the use of sequential low energy Ar(+) sputtering combined with the primary ion LEIS analysis, the reconstruction of the outermost atomic layers has allowed the clarification of the mechanism of NGO neodymium surface enrichment. It is proposed that the gallium at the surface is submitted to a reduction/evaporation mechanism caused by low oxygen partial pressure and/or high water pressure in the vector gas. Below the first surface atomic layers of an as-received NGO single-crystal a gallium-rich phase has also been observed.

F-16XL ship #1 CAWAP flight

NASA Technical Reports Server (NTRS)

1996-01-01

The single-seat F-16XL (ship #1) makes another run during the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Analysis of the pressure-induced potential arising through composite membranes with selective surface layers.

PubMed

Szymczyk, Anthony; Sbaï, Mohammed; Fievet, Patrick

2005-03-01

When a pressure gradient is applied through a charged selective membrane, the transmembrane electrical potential difference, called the filtration potential, results from both the applied pressure and induced concentration difference across the membrane. In this work we investigate the electrokinetic properties relative to both active and support layers of a composite ceramic membrane close to the nanofiltration range. First, the volume charge density of the active layer is obtained by fitting a transport model to experimental rejection rates (which are controlled by the active layer only). Next, the value of the volume charge density is used to compute the theoretical filtration potential through the active layer. For sufficiently high permeate volume fluxes, the concentration difference across the active layer becomes constant, which allows assessing the membrane potential of the active layer. Experimental measurements of the overall filtration potential arising through the whole membrane are performed. The contribution of the support layer to this overall filtration potential is put in evidence. That implies that the membrane potential of the active layer cannot be deduced directly from the overall filtration potential measurements. Finally, the contribution of the support layer is singled out by subtracting the theoretical filtration potential of the active layer from the experimental filtration potential measured across the whole membrane (i.e., support + active layers). The amphoteric behavior of both layers is put in evidence, which is confirmed by electrophoretic measurements carried out with the powdered support layer and by recently reported tangential streaming potential measurements.

Study on hot melt pressure sensitive coil material for removing surface nuclear pollution dust

NASA Astrophysics Data System (ADS)

Wang, Jing; Li, Jiao; Wang, Jianhui; Zheng, Li; Li, Jian; Lv, Linmei

2018-02-01

A new method for removing surface nuclear pollution by using hot melt pressure sensitive membrane was presented. The hot melt pressure sensitive membrane was designed and prepared by screening hot melt pressure sensitive adhesive and substrate. The simulated decontamination test of the hot melt pressure sensitive membrane was performed by using 100 mesh and 20 mesh standard sieve dust for simulation of nuclear explosion fall ash and radioactive contaminated particles, respectively. It was found that the single decontamination rate of simulated fall ash and contaminated particles were both above 80% under pressure conditions of 25kPa or more at 140°C. And the maximum single decontamination rate was 92.5%. The influence of heating temperature and pressure on the decontamination rate of the membrane was investigated at the same time. The results showed that higher heating temperature could increase the decontamination rate by increasing the viscosity of the adhesive. When the adhesive amount of the adhesive layer reached saturation, a higher pressure could increase the single decontamination rate also.

F-16XL ship #1 - CAWAP boundary layer rakes and hot film on left wing

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the boundary layer hot film and the boundary layer rakes on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Thermal Transport at Solid-Liquid Interfaces: High Pressure Facilitates Heat Flow through Nonlocal Liquid Structuring.

PubMed

Han, Haoxue; Mérabia, Samy; Müller-Plathe, Florian

2017-05-04

The integration of three-dimensional microelectronics is hampered by overheating issues inherent to state-of-the-art integrated circuits. Fundamental understanding of heat transfer across soft-solid interfaces is important for developing efficient heat dissipation capabilities. At the microscopic scale, the formation of a dense liquid layer at the solid-liquid interface decreases the interfacial heat resistance. We show through molecular dynamics simulations of n-perfluorohexane on a generic wettable surface that enhancement of the liquid structure beyond a single adsorbed layer drastically enhances interfacial heat conductance. Pressure is used to control the extent of the liquid layer structure. The interfacial thermal conductance increases with pressure values up to 16.2 MPa at room temperature. Furthermore, it is shown that liquid structuring enhances the heat-transfer rate of high-energy lattice waves by broadening the transmission peaks in the heat flux spectrum. Our results show that pressure is an important external parameter that may be used to control interfacial heat conductance at solid-soft interfaces.

Atomic layer epitaxy of GaN over sapphire using switched metalorganic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Khan, M. A.; Skogman, R. A.; van Hove, J. M.; Olson, D. T.; Kuznia, J. N.

1992-03-01

In this letter the first switched atomic layer epitaxy (SALE) of single crystal GaN over basal plane sapphire substrates is reported. A low pressure metalorganic chemical vapor deposition (LPMOCVD) system was used for the epilayer depositions. In contrast to conventional LPMOCVD requiring temperatures higher than 700 C, the SALE process resulted in single crystal insulating GaN layers at growth temperatures ranging from 900 to 450 C. The band-edge transmission and the photoluminescence of the films from the SALE process were comparable to the best LPMOCVD films. As best as is known this is the first report of insulating GaN films which show excellent band-edge photoluminescence.

Atomic layer epitaxy of GaN over sapphire using switched metalorganic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Asif Khan, M.; Skogman, R. A.; Van Hove, J. M.; Olson, D. T.; Kuznia, J. N.

1992-03-01

In this letter we report the first switched atomic layer epitaxy (SALE) of single crystal GaN over basal plane sapphire substrates. A low pressure metalorganic chemical vapor deposition (LPMOCVD) system was used for the epilayer depositions. In contrast to conventional LPMOCVD requiring temperatures higher than 700 °C, the SALE process resulted in single crystal insulating GaN layers at growth temperatures ranging from 900 to 450 °C. The band-edge transmission and the photoluminescence of the films from the SALE process were comparable to the best LPMOCVD films. To the best of our knowledge this is the first report of insulating GaN films which show excellent band-edge photoluminescence.

Wavelength-selective ultraviolet (Mg,Zn)O photodiodes: Tuning of parallel composition gradients with oxygen pressure

NASA Astrophysics Data System (ADS)

Zhang, Zhipeng; von Wenckstern, Holger; Lenzner, Jörg; Grundmann, Marius

2016-06-01

We report on ultraviolet photodiodes with integrated optical filter based on the wurtzite (Mg,Zn)O thin films. Tuning of the bandgap of filter and active layers was realized by employing a continuous composition spread approach relying on the ablation of a single segmented target in pulsed-laser deposition. Filter and active layers of the device were deposited on opposite sides of a sapphire substrate with nearly parallel compositional gradients. Ensure that for each sample position the bandgap of the filter layer blocking the high energy radiation is higher than that of the active layer. Different oxygen pressures during the two depositions runs. The absorption edge is tuned over 360 meV and the spectral bandwidth of photodiodes is typically 100 meV and as low as 50 meV.

F-16XL ship #1 outboard rake #7

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the #7 outboard rake on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

F-16XL ship #1 - CAWAP boundary layer hot film, left wing

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the boundary layer hot film on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. Hot film is used to measure temperature changes on a surface. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Pressure prediction model for compression garment design.

PubMed

Leung, W Y; Yuen, D W; Ng, Sun Pui; Shi, S Q

2010-01-01

Based on the application of Laplace's law to compression garments, an equation for predicting garment pressure, incorporating the body circumference, the cross-sectional area of fabric, applied strain (as a function of reduction factor), and its corresponding Young's modulus, is developed. Design procedures are presented to predict garment pressure using the aforementioned parameters for clinical applications. Compression garments have been widely used in treating burning scars. Fabricating a compression garment with a required pressure is important in the healing process. A systematic and scientific design method can enable the occupational therapist and compression garments' manufacturer to custom-make a compression garment with a specific pressure. The objectives of this study are 1) to develop a pressure prediction model incorporating different design factors to estimate the pressure exerted by the compression garments before fabrication; and 2) to propose more design procedures in clinical applications. Three kinds of fabrics cut at different bias angles were tested under uniaxial tension, as were samples made in a double-layered structure. Sets of nonlinear force-extension data were obtained for calculating the predicted pressure. Using the value at 0° bias angle as reference, the Young's modulus can vary by as much as 29% for fabric type P11117, 43% for fabric type PN2170, and even 360% for fabric type AP85120 at a reduction factor of 20%. When comparing the predicted pressure calculated from the single-layered and double-layered fabrics, the double-layered construction provides a larger range of target pressure at a particular strain. The anisotropic and nonlinear behaviors of the fabrics have thus been determined. Compression garments can be methodically designed by the proposed analytical pressure prediction model.

Comparisons of predicted steady-state levels in rooms with extended- and local-reaction bounding surfaces

NASA Astrophysics Data System (ADS)

Hodgson, Murray; Wareing, Andrew

2008-01-01

A combined beam-tracing and transfer-matrix model for predicting steady-state sound-pressure levels in rooms with multilayer bounding surfaces was used to compare the effect of extended- and local-reaction surfaces, and the accuracy of the local-reaction approximation. Three rooms—an office, a corridor and a workshop—with one or more multilayer test surfaces were considered. The test surfaces were a single-glass panel, a double-drywall panel, a carpeted floor, a suspended-acoustical ceiling, a double-steel panel, and glass fibre on a hard backing. Each test surface was modeled as of extended or of local reaction. Sound-pressure levels were predicted and compared to determine the significance of the surface-reaction assumption. The main conclusions were that the difference between modeling a room surface as of extended or of local reaction is not significant when the surface is a single plate or a single layer of material (solid or porous) with a hard backing. The difference is significant when the surface consists of multilayers of solid or porous material and includes a layer of fluid with a large thickness relative to the other layers. The results are partially explained by considering the surface-reflection coefficients at the first-reflection angles.

F-16XL ship #1 CAWAP flight - alpha 5 degrees, altitude 10,000 feet

NASA Technical Reports Server (NTRS)

1996-01-01

The single-seat F-16XL (ship #1) makes another run during the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. This photo shows the aircraft gathering data at an altitude of 10,000 feet, with an angle of attack of 5 degrees. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

F-16XL ship #1 - CAWAP outboard rakes #7 and inboard rack #3

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the #7 outboard rake and the #3 inboard rake on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

F-16XL ship #1 CAWAP flight

NASA Technical Reports Server (NTRS)

1996-01-01

The single-seat F-16XL (ship #1) makes another run during the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

F-16XL ship #1 - CAWAP outboard rake #7

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the #7 outboard rake on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Prediction of heat release effects on a mixing layer

NASA Technical Reports Server (NTRS)

Farshchi, M.

1986-01-01

A fully second-order closure model for turbulent reacting flows is suggested based on Favre statistics. For diffusion flames the local thermodynamic state is related to single conserved scalar. The properties of pressure fluctuations are analyzed for turbulent flows with fluctuating density. Closure models for pressure correlations are discussed and modeled transport equations for Reynolds stresses, turbulent kinetic energy dissipation, density-velocity correlations, scalar moments and dissipation are presented and solved, together with the mean equations for momentum and mixture fraction. Solutions of these equations are compared with the experimental data for high heat release free mixing layers of fluorine and hydrogen in a nitrogen diluent.

Deposition of single and layered amorphous fluorocarbon films by C8F18 PECVD

NASA Astrophysics Data System (ADS)

Yamauchi, Tatsuya; Mizuno, Kouichiro; Sugawara, Hirotake

2008-10-01

Amorphous fluorocarbon films were deposited by plasma-enhanced chemical vapor deposition (PECVD) using C8F18 in closed system at C8F18 pressures 0.1--0.3 Torr, deposition times 1--30 min and plasma powers 20--200 W@. The layered films were composed by repeated PECVD processes. We compared `two-layered' and `intermittently deposited' films, which were made by the PECVD, respectively, with and without renewal of the gas after the deposition of the first layer. The interlayer boundary was observed in the layered films, and that of the intermittently deposited films showed a tendency to be clearer when the deposition time until the interruption of the PECVD was shorter. The film thickness increased linearly in the beginning of the PECVD and it turned down after 10--15 min, that was similar between the single and intermittently deposited films. It was considered that large precursors made at a low decomposition degree of C8F18 contributed to the film deposition in the early phase and that the downturn was due to the development of the C8F18 decomposition. This explanation on the deposition mechanism agrees qualitatively with our experimental data of pressure change and optical emission spectra during the deposition. This work is supported by Grant-in-Aid from Japan Society for the Promotion of Science.

Annealing of gallium nitride under high-N 2 pressure

NASA Astrophysics Data System (ADS)

Porowski, S.; Jun, J.; Krukowski, S.; Grzegory, I.; Leszczynski, M.; Suski, T.; Teisseyre, H.; Foxon, C. T.; Korakakis, D.

1999-04-01

GaN is the key material for blue and ultraviolet optoelectronics. It is a strongly bonded wurztite structure semiconductor with the direct energy gap 3.5 eV. Due to strong bonding, the diffusion processes require high temperatures, above 1300 K. However at this temperature range at ambient pressure, GaN becomes unstable and dissociates into Ga and N 2. Therefore high pressure of N 2 is required to study the diffusion and other annealing related processes. We studied annealing of bulk GaN nitride single crystals grown under high pressure and also annealing of homo- and heteroepitaxial GaN layers grown by MOCVD technique. Annealing at temperatures above 1300 K influences strongly the structural and optical properties of GaN crystals and layers. At this temperature diffusion of the Mg and Zn acceptors have been observed. In spite of very interesting experimental observations the understanding of microscopic mechanisms of these processes is limited.

Simplified Physics Based Models Research Topical Report on Task #2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mishra, Srikanta; Ganesh, Priya

We present a simplified-physics based approach, where only the most important physical processes are modeled, to develop and validate simplified predictive models of CO2 sequestration in deep saline formation. The system of interest is a single vertical well injecting supercritical CO2 into a 2-D layered reservoir-caprock system with variable layer permeabilities. We use a set of well-designed full-physics compositional simulations to understand key processes and parameters affecting pressure propagation and buoyant plume migration. Based on these simulations, we have developed correlations for dimensionless injectivity as a function of the slope of fractional-flow curve, variance of layer permeability values, and themore » nature of vertical permeability arrangement. The same variables, along with a modified gravity number, can be used to develop a correlation for the total storage efficiency within the CO2 plume footprint. Similar correlations are also developed to predict the average pressure within the injection reservoir, and the pressure buildup within the caprock.« less

A Real-Time Method for Estimating Viscous Forebody Drag Coefficients

NASA Technical Reports Server (NTRS)

Whitmore, Stephen A.; Hurtado, Marco; Rivera, Jose; Naughton, Jonathan W.

2000-01-01

This paper develops a real-time method based on the law of the wake for estimating forebody skin-friction coefficients. The incompressible law-of-the-wake equations are numerically integrated across the boundary layer depth to develop an engineering model that relates longitudinally averaged skin-friction coefficients to local boundary layer thickness. Solutions applicable to smooth surfaces with pressure gradients and rough surfaces with negligible pressure gradients are presented. Model accuracy is evaluated by comparing model predictions with previously measured flight data. This integral law procedure is beneficial in that skin-friction coefficients can be indirectly evaluated in real-time using a single boundary layer height measurement. In this concept a reference pitot probe is inserted into the flow, well above the anticipated maximum thickness of the local boundary layer. Another probe is servomechanism-driven and floats within the boundary layer. A controller regulates the position of the floating probe. The measured servomechanism position of this second probe provides an indirect measurement of both local and longitudinally averaged skin friction. Simulation results showing the performance of the control law for a noisy boundary layer are then presented.

Direct Growth of Graphene on Silicon by Metal-Free Chemical Vapor Deposition

NASA Astrophysics Data System (ADS)

Tai, Lixuan; Zhu, Daming; Liu, Xing; Yang, Tieying; Wang, Lei; Wang, Rui; Jiang, Sheng; Chen, Zhenhua; Xu, Zhongmin; Li, Xiaolong

2018-06-01

The metal-free synthesis of graphene on single-crystal silicon substrates, the most common commercial semiconductor, is of paramount significance for many technological applications. In this work, we report the growth of graphene directly on an upside-down placed, single-crystal silicon substrate using metal-free, ambient-pressure chemical vapor deposition. By controlling the growth temperature, in-plane propagation, edge-propagation, and core-propagation, the process of graphene growth on silicon can be identified. This process produces atomically flat monolayer or bilayer graphene domains, concave bilayer graphene domains, and bulging few-layer graphene domains. This work would be a significant step toward the synthesis of large-area and layer-controlled, high-quality graphene on single-crystal silicon substrates. [Figure not available: see fulltext.

Turbulent Mixing of Primary and Secondary Flow Streams in a Rocket-Based Combined Cycle Engine

NASA Technical Reports Server (NTRS)

Cramer, J. M.; Greene, M. U.; Pal, S.; Santoro, R. J.; Turner, Jim (Technical Monitor)

2002-01-01

This viewgraph presentation gives an overview of the turbulent mixing of primary and secondary flow streams in a rocket-based combined cycle (RBCC) engine. A significant RBCC ejector mode database has been generated, detailing single and twin thruster configurations and global and local measurements. On-going analysis and correlation efforts include Marshall Space Flight Center computational fluid dynamics modeling and turbulent shear layer analysis. Potential follow-on activities include detailed measurements of air flow static pressure and velocity profiles, investigations into other thruster spacing configurations, performing a fundamental shear layer mixing study, and demonstrating single-shot Raman measurements.

Reflection and transmission coefficients of a single layer in poroelastic media.

PubMed

Corredor, Robiel Martinez; Santos, Juan E; Gauzellino, Patricia M; Carcione, José M

2014-06-01

Wave propagation in poroelastic media is a subject that finds applications in many fields of research, from geophysics of the solid Earth to material science. In geophysics, seismic methods are based on the reflection and transmission of waves at interfaces or layers. It is a relevant canonical problem, which has not been solved in explicit form, i.e., the wave response of a single layer, involving three dissimilar media, where the properties of the media are described by Biot's theory. The displacement fields are recast in terms of potentials and the boundary conditions at the two interfaces impose continuity of the solid and fluid displacements, normal and shear stresses, and fluid pressure. The existence of critical angles is discussed. The results are verified by taking proper limits-zero and 100% porosity-by comparison to the canonical solutions corresponding to single-phase solid (elastic) media and fluid media, respectively, and the case where the layer thickness is zero, representing an interface separating two poroelastic half-spaces. As examples, it was calculated the reflection and transmission coefficients for plane wave incident at a highly permeable and compliant fluid-saturated porous layer, and the case where the media are saturated with the same fluid.

Dynamic Testing of Signal Transduction Deregulation During Breast Cancer Initiation

DTIC Science & Technology

2011-07-01

1 at a chamber pressure of ~3 × 10-6 Torr for the electron beam evaporated films. A Hitachi FB2100 Focused Ion Beam milling machine with a gallium ...immobilization. These include physical absorption, layer-by-layer (LBL) assembly, and covalent attachment, and eventually chose the covalent attachment...testing real-time signaling in live breast cancer cells, it is important to evaluate the nanosensors to monitor fluorescent compounds in single

Experimental Study of Boundary Layer Behavior in a Simulated Low Pressure Turbine. Degree awarded by the University of Toledo, May 1998

NASA Technical Reports Server (NTRS)

Shyne, Rickey J.

1998-01-01

A detailed investigation of the flow physics occurring on the suction side of a simulated Low Pressure Turbine (LPT) blade was performed. A contoured upper wall was designed to simulate the pressure distribution of an actual LPT blade onto a flat plate. The experiments were carried out at Reynolds numbers of 100,000 and 250,000 with three levels of freestream turbulence. Freestream turbulence levels ranging from 0.8% to 3% was used in this experiment. Smoke-wire flow visualization data was used to confirm that the boundary layer was separated and formed a bubble. Hot-wires (single and x-wire) and surface mounted hot-film gases and static pressure taps were used to map the flowfield. The transition process over the separated flow region is observed to be similar to a laminar free shear layer flow with the formation of a large coherent eddy structure. For each condition, the locations defining the separation bubble were determined by careful examination of pressure and mean velocity profile data. Transition onset location and length determined from intermittency profiles decrease as freestream turbulence levels increase. Additionally, the length and height of the laminar separation bubbles were observed to be inversely proportional to the levels of freestream turbulence.

An extremely simple macroscale electronic skin realized by deep machine learning.

PubMed

Sohn, Kee-Sun; Chung, Jiyong; Cho, Min-Young; Timilsina, Suman; Park, Woon Bae; Pyo, Myungho; Shin, Namsoo; Sohn, Keemin; Kim, Ji Sik

2017-09-11

Complicated structures consisting of multi-layers with a multi-modal array of device components, i.e., so-called patterned multi-layers, and their corresponding circuit designs for signal readout and addressing are used to achieve a macroscale electronic skin (e-skin). In contrast to this common approach, we realized an extremely simple macroscale e-skin only by employing a single-layered piezoresistive MWCNT-PDMS composite film with neither nano-, micro-, nor macro-patterns. It is the deep machine learning that made it possible to let such a simple bulky material play the role of a smart sensory device. A deep neural network (DNN) enabled us to process electrical resistance change induced by applied pressure and thereby to instantaneously evaluate the pressure level and the exact position under pressure. The great potential of this revolutionary concept for the attainment of pressure-distribution sensing on a macroscale area could expand its use to not only e-skin applications but to other high-end applications such as touch panels, portable flexible keyboard, sign language interpreting globes, safety diagnosis of social infrastructures, and the diagnosis of motility and peristalsis disorders in the gastrointestinal tract.

Dry-spray deposition of TiO2 for a flexible dye-sensitized solar cell (DSSC) using a nanoparticle deposition system (NPDS).

PubMed

Kim, Min-Saeng; Chun, Doo-Man; Choi, Jung-Oh; Lee, Jong-Cheon; Kim, Yang Hee; Kim, Kwang-Su; Lee, Caroline Sunyong; Ahn, Sung-Hoon

2012-04-01

TiO2 powders were deposited on indium tin oxide (ITO) coated polyethylene terephthalate (PET) substrates for application to the photoelectrode of a dye-sensitized solar cell (DSSC). In the conventional DSSC manufacturing process, a semiconductor oxide such as TiO2 powder requires a sintering process at higher temperature than the glass transition temperature (T(g)) of polymers, and thus utilization of flexible polymer substrates in DSSC research has been constrained. To overcome this restriction related to sintering, we used a nanoparticle deposition system (NPDS) that could produce a thin coating layer through a dry-spray method under atmospheric pressure at room temperature. The powder was sprayed through a slit-type nozzle having a 0.4 x 10 mm2 rectangular outlet. In order to determine the deposited TiO2 thickness, five kinds of TiO2 layered specimens were prepared, where the specimens have single and double layer structures. Deposited powders on the ITO coated PET substrates were observed using FE-SEM and a scan profiler The thicker TiO2 photoelectrode with a DSSC having a double layer structure showed higher energy efficiency than the single layer case. The highest fabricated flexible DSSC displayed a short circuit current density J(sc) = 1.99 mA cm(-2), open circuit voltage V(oc) = 0.71 V, and energy efficiency eta = 0.94%. These results demonstrate the possibility of utilizing the dry-spray method to fabricate a TiO2 layer on flexible polymer substrates at room temperature under atmospheric pressure.

Method of manufacturing an overwrapped pressure vessel

NASA Technical Reports Server (NTRS)

Beck, Emory J. (Inventor)

1976-01-01

A pressure vessel of the type wherein a metallic liner in the shape of a cylindrical portion with a dome-shaped portion at each end thereof is overwrapped by a plurality of layers of resin coated, single fiberglass filaments. A four-step wrapping technique reinforces the vessel with overwrap material at the most likely areas for vessel failure. Overwrapping of the vessel is followed by a sizing pressurization cycle which induces a compressive prestress into the liner and thereby permits the liner to deform elastically through an increased strain range.

Equation of state and phase transformations study of Nd at ultra-high pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akella, J.; Smith, G.S.; Weir, S.

1991-10-01

Neodymium was investigated to 96.0 GPa pressure in a diamond-anvil ell at room temperature. The observed structural sequence as a function of pressure is dhcp-fcc- six layered'' structure. In the diffraction pattern hexagonal doublets; notably 102, 006 and 100, 108; appear as single reflection when the c/a ratio is 4.899. However, when cc/a approaches 4.7, the splitting is clear. So far in this study, no monoclinic phase or tetragonal phase were observed. 1 fig., 18 refs.

Development Requirements for Spacesuit Elbow Joint

NASA Technical Reports Server (NTRS)

Peters, Benjamin

2017-01-01

Functional Requirements for spacesuit elbow joint:1) The system is a conformal, single-axis spacesuit pressurized joint that encloses the elbow joint of the suited user and uses a defined interface to connect to the suit systems on either side of the joint.2) The system shall be designed to bear the loads incurred from the internal pressure of the system, as well as the expected loads induced by the user while enabling the user move the joint through the required range of motion. The joint torque of the system experienced by the user shall remain at or below the required specification for the entire range of motion.3) The design shall be constructed, at a minimum, as a two-layer system. The internal, air-tight layer shall be referred to as the bladder, and the layer on the unpressurized side of the bladder shall be referred to as the restraint. The design of the system may include additional features or layers, such as axial webbing, to meet the overall requirements of the design.

F-16XL ship #1 CAWAP flight - alpha 15 degrees, altitude 5,000 feet

NASA Technical Reports Server (NTRS)

1996-01-01

The single-seat F-16XL (ship #1) makes another run during the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. This photo shows the aircraft gathering data at an altitude of 5000 feet, with an angle of attack of 15 degrees. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

High-pressure synthesis and crystal structures of the strontium oxogallates Sr{sub 2}Ga{sub 2}O{sub 5} and Sr{sub 5}Ga{sub 6}O{sub 14}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kahlenberg, Volker, E-mail: volker.kahlenberg@uibk.ac.at; Goettgens, Valerie; Mair, Philipp

2015-08-15

High-pressure synthesis experiments in a piston–cylinder apparatus at 1.5 GPa/3.0 GPa and 1000 °C resulted in the formation of single-crystals of Sr{sub 2}Ga{sub 2}O{sub 5} and Sr{sub 5}Ga{sub 6}O{sub 14}, respectively. The structures of both compounds have been solved from single-crystal diffraction data sets using direct methods. The first compound is orthorhombic with space group type Pbca (a=10.0021(4) Å, b=9.601(4) Å, c=10.6700(4) Å, V=1024.6(4) Å{sup 3}, M{sub r}=394.68 u, Z=8, D{sub x}=5.12 g/cm{sup 3}) and belongs to the group of single layer gallates. Individual sheets are parallel to (0 0 1) and can be built from the condensation of unbranchedmore » vierer single chains running along [0 1 0]. The layers are characterized by the presence of four- and strongly elliptical eight-membered rings of corner connected tetrahedra in UUDD and UUUUDDDD conformation. Strontium atoms are sandwiched between the tetrahedral layers for charge compensation and are coordinated by six and seven oxygen ligands, respectively. Sr{sub 2}Ga{sub 2}O{sub 5} is isotypic with several other double sulfides and selenides. To the best of our knowledge, it is the first example of an oxide with this structure type. From a structural point of view, Sr{sub 5}Ga{sub 6}O{sub 14} is a phyllogallate as well. The crystal structure adopts the monoclinic space group P2{sub 1}/c (a=8.1426(3) Å, b=8.1803(3) Å, c=10.8755(4) Å, β=91.970(4)° V=723.98(5) Å{sup 3}, M{sub r}=1080.42 u, Z=2, D{sub x}=4.96 g/cm{sup 3}). Individual sheets extend along (0 0 1). Basic building units are unbranched dreier single chains parallel to [1 0 0]. The layers contain tertiary (Q{sup 3}) und quaternary (Q{sup 4}) connected [GaO{sub 4}]-tetrahedra in the ratio 2:1 resulting in a Ga:O ratio of 3:7 and the formation of exclusively five-membered rings. Linkage between adjacent tetrahedral sheets is provided by three symmetrically independent strontium ions which are surrounded by six to eight oxygen atoms. The layers in Sr{sub 5}Ga{sub 6}O{sub 14} are similar to those observed in the melilite structure-type. Crystallochemical relationships between the present phases and other known compounds are discussed in detail. - Graphical abstract: A single tetrahedral layer and the location of the Sr-cations directly above the sheet in high-pressure Sr{sub 5}Ga{sub 6}O{sub 14}. - Highlights: • We report the crystal structures of two new strontium oxogallates with composition Sr{sub 2}Ga{sub 2}O{sub 5} and Sr{sub 5}Ga{sub 6}O{sub 14.} • Both phases have been obtained in the course of high-pressure piston–cylinder experiments performed at 1.5 and 3.0 GPa. • The crystallochemical characteristics and similarities with known structure types are discussed in detail.« less

O 1s core levels in Bi2Sr2CaCu2O8+δ single crystals

NASA Astrophysics Data System (ADS)

Parmigiani, F.; Shen, Z. X.; Mitzi, D. B.; Lindau, I.; Spicer, W. E.; Kapitulnik, A.

1991-02-01

High-quality Bi2Sr2CaCu2O8+δ superconducting single crystals, annealed at different oxygen partial pressures, have been studied using angular-resolved x-ray photoelectron spectroscopy with a resolution higher than that used in any previous study. Two states of the oxygen, separated by ~=0.7 eV, are unambiguously observed. Examining these components at different angles makes it possible to distinguish bulk from surface components. Using this capability we discover that annealing under lower oxygen partial pressure (1 atm) results in oxygen intercalation beneath the Bi-O surface layer of the crystal, whereas for higher-pressure anneals (12 atm) additional oxygen is found on the Bi-O surfaces. This steplike intercalation mechanism is also confirmed by the changes observed in the Cu and Bi core lines as a function of the annealing oxygen partial pressure.

Enhanced Stability of Pt-Cu Single-Atom Alloy Catalysts: In Situ Characterization of the Pt/Cu(111) Surface in an Ambient Pressure of CO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simonovis, Juan Pablo; Hunt, Adrian; Palomino, Robert M.

The interaction between a catalyst and reactants often induce changes in the surface structure and composition of the catalyst, which, in turn, affect its reactivity. Therefore, it is important to study such changes using in situ techniques under well-controlled conditions. We have used ambient pressure X-ray photoelectron spectroscopy (AP-XPS) to study the surface stability of a Pt/Cu(111) single atom alloy (SAA) in an ambient pressure of CO. By directly probing the Pt atoms, we found that CO causes a slight surface segregation of Pt atoms at room temperature. In addition, while the Pt/Cu(111) surface demonstrates poor thermal stability in UHV,more » where surface Pt starts to diffuse to the subsurface layer above 400 K, the presence of adsorbed CO enhances the thermal stability of surface Pt atoms. Furthermore, we also found that temperatures above 450 K cause a restructuring of the subsurface layer, which consequently strengthens the CO binding to the surface Pt sites, likely due to the presence of neighboring subsurface Pt atoms.« less

Enhanced Stability of Pt-Cu Single-Atom Alloy Catalysts: In Situ Characterization of the Pt/Cu(111) Surface in an Ambient Pressure of CO

DOE PAGES

Simonovis, Juan Pablo; Hunt, Adrian; Palomino, Robert M.; ...

2018-02-05

The interaction between a catalyst and reactants often induce changes in the surface structure and composition of the catalyst, which, in turn, affect its reactivity. Therefore, it is important to study such changes using in situ techniques under well-controlled conditions. We have used ambient pressure X-ray photoelectron spectroscopy (AP-XPS) to study the surface stability of a Pt/Cu(111) single atom alloy (SAA) in an ambient pressure of CO. By directly probing the Pt atoms, we found that CO causes a slight surface segregation of Pt atoms at room temperature. In addition, while the Pt/Cu(111) surface demonstrates poor thermal stability in UHV,more » where surface Pt starts to diffuse to the subsurface layer above 400 K, the presence of adsorbed CO enhances the thermal stability of surface Pt atoms. Furthermore, we also found that temperatures above 450 K cause a restructuring of the subsurface layer, which consequently strengthens the CO binding to the surface Pt sites, likely due to the presence of neighboring subsurface Pt atoms.« less

Lens intracellular hydrostatic pressure is generated by the circulation of sodium and modulated by gap junction coupling

PubMed Central

Gao, Junyuan; Sun, Xiurong; Moore, Leon C.; White, Thomas W.; Brink, Peter R.

2011-01-01

We recently modeled fluid flow through gap junction channels coupling the pigmented and nonpigmented layers of the ciliary body. The model suggested the channels could transport the secretion of aqueous humor, but flow would be driven by hydrostatic pressure rather than osmosis. The pressure required to drive fluid through a single layer of gap junctions might be just a few mmHg and difficult to measure. In the lens, however, there is a circulation of Na+ that may be coupled to intracellular fluid flow. Based on this hypothesis, the fluid would cross hundreds of layers of gap junctions, and this might require a large hydrostatic gradient. Therefore, we measured hydrostatic pressure as a function of distance from the center of the lens using an intracellular microelectrode-based pressure-sensing system. In wild-type mouse lenses, intracellular pressure varied from ∼330 mmHg at the center to zero at the surface. We have several knockout/knock-in mouse models with differing levels of expression of gap junction channels coupling lens fiber cells. Intracellular hydrostatic pressure in lenses from these mouse models varied inversely with the number of channels. When the lens’ circulation of Na+ was either blocked or reduced, intracellular hydrostatic pressure in central fiber cells was either eliminated or reduced proportionally. These data are consistent with our hypotheses: fluid circulates through the lens; the intracellular leg of fluid circulation is through gap junction channels and is driven by hydrostatic pressure; and the fluid flow is generated by membrane transport of sodium. PMID:21624945

Aluminum surface modification by a non-mass-analyzed nitrogen ion beam

NASA Astrophysics Data System (ADS)

Ohira, Shigeo; Iwaki, Masaya

Non-mass-analyzed nitrogen ion implantation into polycrystal and single crystal aluminum sheets has been carried out at an accelerating voltage of 90 kV and a dose of 1 × 10 18 N ions/cm 2 using a Zymet implanter model Z-100. The pressure during implantation rose to 10 -3 Pa due to the influence of N gas feeding into the ion source. The characteristics of the surface layers were investigated by means of Auger electron spectroscopy (AES), X-ray diffraction (XRD), transmission electron diffraction (TED), and microscopy (TEM). The AES depth profiling shows a rectangular-like distribution of N atoms and little migration of O atoms near the surface. The high dose N-implantation forms c-axis oriented aluminum nitride (AIN) crystallines, and especially irradiation of Al single crystals with N ions leads to the formation of a hcp AlN single crystal. It is concluded that the high dose N-implantation in Al can result in the formation of AlN at room temperature without any thermal annealing. Furthermore, non-mass-analyzed N-implantation at a pressure of 10 -3 Pa of the nitrogen atmosphere causes the formation of pure AlN single crystals in the Al surface layer and consequently it can be practically used for AlN production.

Flow Coefficient Behavior for Boundary Layer Bleed Holes and Slots

NASA Technical Reports Server (NTRS)

Willis, B. P.; Davis, D. O.; Hingst, W. R.

1995-01-01

An experimental investigation into the flow coefficient behavior for nine boundary layer bleed orifice configurations is reported. This test was conducted for the purposes of exploring boundary layer control through mass flow removal and does not address issues of stability bleed. Parametric data consist of bleed region flow coefficient as a function of Mach number, bleed plenum pressure, and bleed orifice geometry. Seven multiple hole configurations and two single slot configurations were tested over a supersonic Mach number range of 1.3 to 2.5 (nominal). Advantages gained by using multiple holes in a bleed region instead of a single spanwise slot are discussed and the issue of modeling an entire array of bleed orifices based on the performance of a single orifice is addressed. Preconditioning the flow approaching a 90 degree inclined (normal) hole configuration resulted in a significant improvement in the performance of the configuration. The same preconditioning caused only subtle changes in performance for a 20 degree inclined (slanted) configuration.

Direct Numerical Simulation of Acoustic Noise Generation from the Nozzle Wall of a Hypersonic Wind Tunnel

NASA Astrophysics Data System (ADS)

Huang, Junji; Duan, Lian; Choudhari, Meelan; Missouri Univ of Sci; Tech Team; NASA Langley Research Center Team

2017-11-01

Direct numerical simulations (DNS) are used to examine the acoustic noise generation from the turbulent boundary layer on the nozzle wall of a Mach 6 Ludwieg Tube. The emphasis is on characterizing the freestream acoustic pressure disturbances radiated from the nozzle-wall turbulent boundary layer and comparing it with acoustic noise generated from a single, flat wall in an unconfined setting at a similar freestream Mach number to assess the effects of noise reverberation. In particular, the numerical database is used to provide insights into the pressure disturbance spectrum and amplitude scaling with respect to the boundary-layer parameters as well as to understand the acoustic source mechanisms. Such information is important for characterizing the freestream disturbance environment in conventional (i.e., noisy) hypersonic wind tunnels. Air Force Office of Scientific Research Award No. FA9550-14-1-0170.

Structural investigation of MF, RF and DC sputtered Mo thin films for backside photovoltaic electrode

NASA Astrophysics Data System (ADS)

Małek, Anna K.; Marszałek, Konstanty W.; Rydosz, Artur M.

2016-12-01

Recently photovoltaics attracts much attention of research and industry. The multidirectional studies are carried out in order to improve solar cells performance, the innovative materials are still searched and existing materials and technology are optimized. In the multilayer structure of CIGS solar cells molybdenum (Mo) layer is used as a back contact. Mo layers meet all requirements for back side electrode: low resistivity, good adhesion to the substrate, high optical reflection in the visible range, columnar structure for Na ions diffusion, formation of an ohmic contact with the ptype CIGS absorber layer, and high stability during the corrosive selenization process. The high adhesion to the substrate and low resistivity in single Mo layer is difficult to be achieved because both properties depend on the deposition parameters, particularly on working gas pressure. Therefore Mo bilayers are applied as a back contact for CIGS solar cells. In this work the Mo layers were deposited by medium frequency sputtering at different process parameters. The effect of substrate temperature within the range of 50°C-200°C and working gas pressure from 0.7 mTorr to 7 mTorr on crystalline structure of Mo layers was studied.

Patch nearfield acoustic holography combined with sound field separation technique applied to a non-free field

NASA Astrophysics Data System (ADS)

Bi, ChuanXing; Jing, WenQian; Zhang, YongBin; Xu, Liang

2015-02-01

The conventional nearfield acoustic holography (NAH) is usually based on the assumption of free-field conditions, and it also requires that the measurement aperture should be larger than the actual source. This paper is to focus on the problem that neither of the above-mentioned requirements can be met, and to examine the feasibility of reconstructing the sound field radiated by partial source, based on double-layer pressure measurements made in a non-free field by using patch NAH combined with sound field separation technique. And also, the sensitivity of the reconstructed result to the measurement error is analyzed in detail. Two experiments involving two speakers in an exterior space and one speaker inside a car cabin are presented. The experimental results demonstrate that the patch NAH based on single-layer pressure measurement cannot obtain a satisfied result due to the influences of disturbing sources and reflections, while the patch NAH based on double-layer pressure measurements can successfully remove these influences and reconstruct the patch sound field effectively.

DNA combing on low-pressure oxygen plasma modified polysilsesquioxane substrates for single-molecule studies

PubMed Central

Sriram, K. K.; Chang, Chun-Ling; Rajesh Kumar, U.; Chou, Chia-Fu

2014-01-01

Molecular combing and flow-induced stretching are the most commonly used methods to immobilize and stretch DNA molecules. While both approaches require functionalization steps for the substrate surface and the molecules, conventionally the former does not take advantage of, as the latter, the versatility of microfluidics regarding robustness, buffer exchange capability, and molecule manipulation using external forces for single molecule studies. Here, we demonstrate a simple one-step combing process involving only low-pressure oxygen (O2) plasma modified polysilsesquioxane (PSQ) polymer layer to facilitate both room temperature microfluidic device bonding and immobilization of stretched single DNA molecules without molecular functionalization step. Atomic force microscopy and Kelvin probe force microscopy experiments revealed a significant increase in surface roughness and surface potential on low-pressure O2 plasma treated PSQ, in contrast to that with high-pressure O2 plasma treatment, which are proposed to be responsible for enabling effective DNA immobilization. We further demonstrate the use of our platform to observe DNA-RNA polymerase complexes and cancer drug cisplatin induced DNA condensation using wide-field fluorescence imaging. PMID:25332730

Transition from moving to stationary double layers in a single-ended Q machine

NASA Technical Reports Server (NTRS)

Song, Bin; Merlino, R. L.; D'Angelo, N.

1990-01-01

Large-amplitude (less than about 100 percent) relaxation oscillations in the plasma potential are known to be generated when the cold endplate of a single-ended Q machine is biased positively. These oscillations are associated with double layers that form near the hot plate (plasma source) and travel toward the endplate at about the ion-acoustic velocity. At the endplate they dissolve and then form again near the hot plate, the entire process repeating itself in a regular manner. By admitting a sufficient amount of neutral gas into the system, the moving double layers were slowed down and eventually stopped. The production of stationary double layers requires an ion source on the high-potential side of the double layers. These ions are provided by ionization of the neutral gas by electrons that are accelerated through the double layer. The dependence of the critical neutral gas pressure required for stationary double-layer formation on endplate voltage, magnetic field strength, and neutral atom mass has been examined. These results are discussed in terms of a simple model of ion production and loss, including ion losses across the magnetic field.

Using the Multilayer Free-Surface Flow Model to Solve Wave Problems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prokof’ev, V. A., E-mail: ProkofyevVA@vniig.ru

2017-01-15

A method is presented for changing over from a single-layer shallow-water model to a multilayer model with hydrostatic pressure profile and, then, to a multilayer model with nonhydrostatic pressure profile. The method does not require complex procedures for solving the discrete Poisson’s equation and features high computation efficiency. The results of validating the algorithm against experimental data critical for the numerical dissipation of the numerical scheme are presented. Examples are considered.

Single-stage experimental evaluation of tandem-airfoil rotor stator blading for compressors. Part 6: Data and performance for stage D

NASA Technical Reports Server (NTRS)

Clemmons, D. R.

1973-01-01

An axial flow compressor stage, having single-airfoil blading, was designed for zero rotor prewhirl, constant rotor work across the span, and axial discharge flow. The stage was designed to produce a pressure ratio of 1.265 at a rotor tip velocity of 757 ft/sec. The rotor had an inlet hub/tip ratio of 0.8. The design procedure accounted for the rotor inlet boundary layer and included the effects of axial velocity ratio and secondary flow on blade row performance. The objectives of this experimental program were: (1) to obtain performance with uniform and distorted inlet flow for comparison with the performance of a stage consisting of tandem-airfoil blading designed for the same vector diagrams; and (2) to evaluate the effectiveness of accounting for the inlet boundary layer, axial velocity ratio, and secondary flows in the stage design. With uniform inlet flow, the rotor achieved a maximum adiabatic efficiency of 90.1% at design equivalent rotor speed and a pressure ratio of 1.281. The stage maximum adiabatic efficiency at design equivalent rotor speed with uniform inlet flow was 86.1% at a pressure ratio of 1.266. Hub radial, tip radial, and circumferential distortion of the inlet flow caused reductions in surge pressure ratio of approximately 2, 10 and 5%, respectively, at design rotor speed.

Underwater sound transmission through arrays of disk cavities in a soft elastic medium.

PubMed

Calvo, David C; Thangawng, Abel L; Layman, Christopher N; Casalini, Riccardo; Othman, Shadi F

2015-10-01

Scattering from a cavity in a soft elastic medium, such as silicone rubber, resembles scattering from an underwater bubble in that low-frequency monopole resonance is obtainable in both cases. Arrays of cavities can therefore be used to reduce underwater sound transmission using thin layers and low void fractions. This article examines the role of cavity shape by microfabricating arrays of disk-shaped air cavities into single and multiple layers of polydimethylsiloxane. Comparison is made with the case of equivalent volume cylinders which approximate spheres. Measurements of ultrasonic underwater sound transmission are compared with finite element modeling predictions. The disks provide a deeper transmission minimum at a lower frequency owing to the drum-type breathing resonance. The resonance of a single disk cavity in an unbounded medium is also calculated and compared with a derived estimate of the natural frequency of the drum mode. Variation of transmission is determined as a function of disk tilt angle, lattice constant, and layer thickness. A modeled transmission loss of 18 dB can be obtained at a wavelength about 20 times the three-layer thickness, and thinner results (wavelength/thickness ∼ 240) are possible for the same loss with a single layer depending on allowable hydrostatic pressure.

Numerical and experimental study of the effects of the electrical resistance and diffusivity under clamping pressure on the performance of a metallic gas-diffusion layer in polymer electrolyte fuel cells

NASA Astrophysics Data System (ADS)

Tanaka, Shiro; Bradfield, Warwick W.; Legrand, Cloe; Malan, Arnaud G.

2016-10-01

The performance of a perforated metal-sheet gas-diffusion layer incorporated with a microporous layer in a fuel cell is evaluated with fine-pitch channel/land designs for the gas flow field on a bipolar plate. The combination of metal-sheet gas-diffusion layer and microporous layer exhibits significant performance without a large flooding effect. When comparing the performance with wider and narrower land cases, the land width affects the performance. To investigate the roles of the microporous layer, land width, etc. in the fuel cell with the metal-sheet gas-diffusion layer, a single-phase, isothermal, and multi-physics simulation is developed and coupled with electrical, mechanical, electrochemical and fluid dynamics factors. The simulated current-voltage performance is then compared to the experimentally measure performance. These are shown to be in good agreement apart for very high current-density cases i.e. greater than 1.5 A cm-2. This is due the flooding effect predominantly appearing. It is further demonstrated that the microporous layer serves as the key component in facilitating gas diffusion and for preventing flooding. Furthermore, the pressure is found to have a strong impact on the performance, affecting the gas diffusion and electric resistance around the microporous layer.

Ultrasensitive and Highly Stable Resistive Pressure Sensors with Biomaterial-Incorporated Interfacial Layers for Wearable Health-Monitoring and Human-Machine Interfaces.

PubMed

Chang, Hochan; Kim, Sungwoong; Jin, Sumin; Lee, Seung-Woo; Yang, Gil-Tae; Lee, Ki-Young; Yi, Hyunjung

2018-01-10

Flexible piezoresistive sensors have huge potential for health monitoring, human-machine interfaces, prosthetic limbs, and intelligent robotics. A variety of nanomaterials and structural schemes have been proposed for realizing ultrasensitive flexible piezoresistive sensors. However, despite the success of recent efforts, high sensitivity within narrower pressure ranges and/or the challenging adhesion and stability issues still potentially limit their broad applications. Herein, we introduce a biomaterial-based scheme for the development of flexible pressure sensors that are ultrasensitive (resistance change by 5 orders) over a broad pressure range of 0.1-100 kPa, promptly responsive (20 ms), and yet highly stable. We show that employing biomaterial-incorporated conductive networks of single-walled carbon nanotubes as interfacial layers of contact-based resistive pressure sensors significantly enhances piezoresistive response via effective modulation of the interlayer resistance and provides stable interfaces for the pressure sensors. The developed flexible sensor is capable of real-time monitoring of wrist pulse waves under external medium pressure levels and providing pressure profiles applied by a thumb and a forefinger during object manipulation at a low voltage (1 V) and power consumption (<12 μW). This work provides a new insight into the material candidates and approaches for the development of wearable health-monitoring and human-machine interfaces.

Water transport and desalination through double-layer graphyne membranes.

PubMed

Akhavan, Mojdeh; Schofield, Jeremy; Jalili, Seifollah

2018-05-16

Non-equilibrium molecular dynamics simulations of water-salt solutions driven through single and double-layer graphyne membranes by a pressure difference created by rigid pistons are carried out to determine the relative performance of the membranes as filters in a reverse osmosis desalination process. It is found that the flow rate of water through a graphyne-4 membrane is twice that of a graphyne-3 membrane for both single and double-layer membranes. Although the addition of a second layer to a single-layer membrane reduces the membrane permeability, the double-layer graphyne membranes are still two or three orders of magnitude more permeable than commercial reverse osmosis membranes. The minimum reduction in flow rate for double-layer membranes occurs at a layer spacing of 0.35 nm with an AA stacking configuration, while at a spacing of 0.6 nm the flow rate is close to zero due to a high free energy barrier for permeation. This is caused by the difference in the environments on either side of the membrane sheets and the formation of a compact two-dimensional layer of water molecules in the interlayer space which slows down water permeation. The distribution of residence times of water molecules in the interlayer region suggests that at the critical layer spacing of 0.6 nm, a cross-over occurs in the mechanism of water flow from the collective movement of hydrogen-bonded water sheets to the permeation of individual water molecules. All membranes are demonstrated to have a high salt rejection fraction and the double-layered graphyne-4 membranes can further increase the salt rejection by trapping ions that have passed through the first membrane from the feed solution in the interlayer space.

The effect of multiple layers of linens on surface interface pressure: results of a laboratory study.

PubMed

Williamson, Rachel; Lachenbruch, Charlie; Vangilder, Catherine

2013-06-01

Underpads and layers of linens are frequently placed under patients who are incontinent, have other moisture-related issues, and/or are immobile and cannot reposition independently. Many of these patients are also at risk for pressure ulcers and placed on pressure-redistribution surfaces. The purpose of this study was to measure the effects of linens and incontinence pads on interface pressure. Interface sacral pressures were measured (mm Hg) using a mannequinlike pelvic indenter that has pressure transducers integrated into the unit and is covered with a soft flesh-like elastomer. The indenter was loaded to simulate a median-weight male (80 kg/176 lb), and the testing was performed at head-of bed (HOB) angles of 0°, 30°, and 45°. Two different surfaces, a high performance low-air-loss support (LAL) surface and a standard foam support surface, were used and covered with a fitted sheet (FS) only or a combination of the FS and various incontinence pads and transfer sheets. Linen combinations typically used for relatively immobile patients (n = 4), moisture management (n = 4), and moisture management and immobility (n = 1) were tested, as was the heavy use of linens/pads (nine layers, n = 1). All combinations were tested 10 times at HOB angles of 0°, 30°, and 45°. The highest pressure observed was recorded (peak pressure). Ninety five percent (95%) confidence interval (CI) surrounding the mean of the 10 trials for each combination was calculated using the t-distribution; differences between means for all surface combinations were determined using one-way ANOVA with follow-up Fisher Hayter test. Results indicated that each incontinence pad, transfer sheet, or combination of linens significantly increased the mean peak sacral pressure when compared to a single FS on both the low-air-loss surface and the foam surface, regardless of the head-of-bed angle. The magnitude of peak sacral interface pressure increase for the LAL surface at 30° head-of-bed angle was 20% to 64% depending on the linen combination. At 30°, the foam surface showed increases 6% to 29% (P <0.0001) compared with a FS baseline. If linens were wet, peak interface sacral pressures were equivalent to or less than pressures measured on the same pads when measured dry. The presence of linens on both surface types adversely affected the pressure redistribution capabilities of the surfaces; added layers increased pressure proportionally. The effect on interface pressure from the linen layers was more pronounced on the LAL than the foam surface. The study results illustrate that significant increases in peak interface pressure occur in a laboratory setting when linen layers are added to pressure redistribution surfaces. Results also indicated wetting incontinence pads on a support surface did not significantly increase interface pressure. Although additional preclinical and clinical studies are needed to guide practice, excessive linen usage for patients on therapeutic support surfaces should be discouraged.

24 CFR 3285.312 - Footings.

Code of Federal Regulations, 2014 CFR

2014-04-01

... section. Footings must be placed on undisturbed soil or fill compacted to 90 percent of maximum relative... (psi). Site-specific soil conditions or design load requirements may also require the use of... footings must consist of a minimum of two layers of nominal 2-inch thick pressure-treated wood, a single...

24 CFR 3285.312 - Footings.

Code of Federal Regulations, 2012 CFR

2012-04-01

... section. Footings must be placed on undisturbed soil or fill compacted to 90 percent of maximum relative... (psi). Site-specific soil conditions or design load requirements may also require the use of... footings must consist of a minimum of two layers of nominal 2-inch thick pressure-treated wood, a single...

24 CFR 3285.312 - Footings.

Code of Federal Regulations, 2011 CFR

2011-04-01

... section. Footings must be placed on undisturbed soil or fill compacted to 90 percent of maximum relative... (psi). Site-specific soil conditions or design load requirements may also require the use of... footings must consist of a minimum of two layers of nominal 2-inch thick pressure-treated wood, a single...

24 CFR 3285.312 - Footings.

Code of Federal Regulations, 2010 CFR

2010-04-01

... section. Footings must be placed on undisturbed soil or fill compacted to 90 percent of maximum relative... (psi). Site-specific soil conditions or design load requirements may also require the use of... footings must consist of a minimum of two layers of nominal 2-inch thick pressure-treated wood, a single...

24 CFR 3285.312 - Footings.

Code of Federal Regulations, 2013 CFR

2013-04-01

... section. Footings must be placed on undisturbed soil or fill compacted to 90 percent of maximum relative... (psi). Site-specific soil conditions or design load requirements may also require the use of... footings must consist of a minimum of two layers of nominal 2-inch thick pressure-treated wood, a single...

Pressure-sensitive strain sensor based on a single percolated Ag nanowire layer embedded in colorless polyimide

NASA Astrophysics Data System (ADS)

Lee, Chan-Jae; Jun, Sungwoo; Ju, Byeong-Kwon; Kim, Jong-Woong

2017-06-01

This paper presents the fabrication of an elastomer-free, transparent, pressure-sensitive strain sensor consisting of a specially designed silver nanowire (AgNW) pattern and colorless polyimide (cPI). A percolated AgNW network was patterned with a simple tandem compound circuit, which was then embedded in the surface of the cPI via inverted layer processing. The resulting film-type sensor was highly transparent ( 93.5% transmittance at 550 nm) and mechanically stable (capable of resisting 10000 cycles of bending to a 500 μm radius of curvature). We demonstrated that a thin, transparent, and mechanically stable electrode can be produced using a combination of AgNWs and cPI, and used to produce a system sensitive to pressure-induced bending. The capacitance of the AgNW tandem compound electrode pattern grew via fringing, which increased with the pressure-induced bending applied to the surface of the sensor. The sensitivity was four times higher than that of an elastomeric pressure sensor made with the same design. Finally, we demonstrated a skin-like pressure sensor attached to the inside wrist of a human arm.

Information content of OCO-2 oxygen A-band channels for retrieving marine liquid cloud properties

NASA Astrophysics Data System (ADS)

Richardson, Mark; Stephens, Graeme L.

2018-03-01

Information content analysis is used to select channels for a marine liquid cloud retrieval using the high-spectral-resolution oxygen A-band instrument on NASA's Orbiting Carbon Observatory-2 (OCO-2). Desired retrieval properties are cloud optical depth, cloud-top pressure and cloud pressure thickness, which is the geometric thickness expressed in hectopascals. Based on information content criteria we select a micro-window of 75 of the 853 functioning OCO-2 channels spanning 763.5-764.6 nm and perform a series of synthetic retrievals with perturbed initial conditions. We estimate posterior errors from the sample standard deviations and obtain ±0.75 in optical depth and ±12.9 hPa in both cloud-top pressure and cloud pressure thickness, although removing the 10 % of samples with the highest χ2 reduces posterior error in cloud-top pressure to ±2.9 hPa and cloud pressure thickness to ±2.5 hPa. The application of this retrieval to real OCO-2 measurements is briefly discussed, along with limitations and the greatest caution is urged regarding the assumption of a single homogeneous cloud layer, which is often, but not always, a reasonable approximation for marine boundary layer clouds.

Evaluation of the OMI Cloud Pressures Derived from Rotational Raman Scattering by Comparisons with other Satellite Data and Radiative Transfer Simulations

NASA Technical Reports Server (NTRS)

Vasilkov, Alexander; Joiner, Joanna; Spurr, Robert; Bhartia, Pawan K.; Levelt, Pieternel; Stephens, Graeme

2009-01-01

In this paper we examine differences between cloud pressures retrieved from the Ozone Monitoring Instrument (OMI) using the ultraviolet rotational Raman scattering (RRS) algorithm and those from the thermal infrared (IR) Aqua/MODIS. Several cloud data sets are currently being used in OMI trace gas retrieval algorithms including climatologies based on IR measurements and simultaneous cloud parameters derived from OMI. From a validation perspective, it is important to understand the OMI retrieved cloud parameters and how they differ with those derived from the IR. To this end, we perform radiative transfer calculations to simulate the effects of different geophysical conditions on the OMI RRS cloud pressure retrievals. We also quantify errors related to the use of the Mixed Lambert-Equivalent Reflectivity (MLER) concept as currently implemented of the OMI algorithms. Using properties from the Cloudsat radar and MODIS, we show that radiative transfer calculations support the following: (1) The MLER model is adequate for single-layer optically thick, geometrically thin clouds, but can produce significant errors in estimated cloud pressure for optically thin clouds. (2) In a two-layer cloud, the RRS algorithm may retrieve a cloud pressure that is either between the two cloud decks or even beneath the top of the lower cloud deck because of scattering between the cloud layers; the retrieved pressure depends upon the viewing geometry and the optical depth of the upper cloud deck. (3) Absorbing aerosol in and above a cloud can produce significant errors in the retrieved cloud pressure. (4) The retrieved RRS effective pressure for a deep convective cloud will be significantly higher than the physical cloud top pressure derived with thermal IR.

Above-Cloud Precipitable Water Retrievals using the MODIS 0.94 micron Band with Applications for Multi-Layer Cloud Detection

NASA Technical Reports Server (NTRS)

Platnick, S.; Wind, G.

2004-01-01

In order to perform satellite retrievals of cloud properties, it is important to account for the effect of the above-cloud atmosphere on the observations. The solar bands used in the operational MODIS Terra and Aqua cloud optical and microphysical algorithms (visible, NIR, and SWIR spectral windows) are primarily affected by water vapor, and to a lesser extent by well-mixed gases. For water vapor, the above-cloud column amount, or precipitable water, provides adequate information for an atmospheric correction; details of the vertical vapor distribution are not typically necessary for the level of correction required. Cloud-top pressure has a secondary effect due to pressure broadening influences. For well- mixed gases, cloud-top pressure is also required for estimates of above-cloud abundances. We present a method for obtaining above-cloud precipitable water over dark Ocean surfaces using the MODIS 0.94 pm vapor absorption band. The retrieval includes an iterative procedure for establishing cloud-top temperature and pressure, and is useful for both single layer water and ice clouds. Knowledge of cloud thermodynamic phase is fundamental in retrieving cloud optical and microphysical properties. However, in cases of optically thin cirrus overlapping lower water clouds, the concept of a single unique phase is ill- defined and depends, at least, on the spectral region of interest. We will present a method for multi-layer and multi-phase cloud detection which uses above-cloud precipitable water retrievals along with several existing MODIS operational cloud products (cloud-top pressure derived from a C02 slicing algorithm, IR and SWIR phase retrievals). Results are catagorized by whether the radiative signature in the MODIS solar bands is primarily that of a water cloud with ice cloud contamination, or visa-versa. Examples in polar and mid-latitude regions will be shown.

Experimental study of flow reattachment in a single-sided sudden expansion

NASA Technical Reports Server (NTRS)

Westphal, R. V.; Johnston, J. P.; Eaton, J. K.

1984-01-01

The reattachment of a fully turbulent, two dimensional, separated shear layer downstream of a single-sided sudden expansion in a planar duct flow was examined experimentally. The importance of changing the structure of the separated shear layer on the reattachment process itself was examined. For all cases, the Reynolds number based on step height was greater than 20,000, the expansion ratio was 5/3, and the inlet boundary layer was less than one-half step height in thickness. A crucially important phase was the development of a pulsed wall probe for measurement of skin friction in the reattachment region, thus providing an unambiguous definition of the reattachment length. Quantitative features of reattachment - including streamwise development of the mean and fluctuating velocity field, pressure rise, and skin friction - were found to be similar for all cases studied when scaled by the reattachment length. A definition of the reattachment zone is proposed.

A theoretical study of mixing downstream of transverse injection into a supersonic boundary layer

NASA Technical Reports Server (NTRS)

Baker, A. J.; Zelazny, S. W.

1972-01-01

A theoretical and analytical study was made of mixing downstream of transverse hydrogen injection, from single and multiple orifices, into a Mach 4 air boundary layer over a flat plate. Numerical solutions to the governing three-dimensional, elliptic boundary layer equations were obtained using a general purpose computer program. Founded upon a finite element solution algorithm. A prototype three-dimensional turbulent transport model was developed using mixing length theory in the wall region and the mass defect concept in the outer region. Excellent agreement between the computed flow field and experimental data for a jet/freestream dynamic pressure ratio of unity was obtained in the centerplane region of the single-jet configuration. Poorer agreement off centerplane suggests an inadequacy of the extrapolated two-dimensional turbulence model. Considerable improvement in off-centerplane computational agreement occured for a multi-jet configuration, using the same turbulent transport model.

Conceptual Design of a Single-Aisle Turboelectric Commercial Transport With Fuselage Boundary Layer Ingestion

NASA Technical Reports Server (NTRS)

Welstead, Jason R.; Felder, James L.

2016-01-01

A single-aisle commercial transport concept with a turboelectric propulsion system architecture was developed assuming entry into service in 2035 and compared to a similar technology conventional configuration. The turboelectric architecture consisted of two underwing turbofans with generators extracting power from the fan shaft and sending it to a rear fuselage, axisymmetric, boundary layer ingesting fan. Results indicate that the turbo- electric concept has an economic mission fuel burn reduction of 7%, and a design mission fuel burn reduction of 12% compared to the conventional configuration. An exploration of the design space was performed to better understand how the turboelectric architecture changes the design space, and system sensitivities were run to determine the sensitivity of thrust specific fuel consumption at top of climb and propulsion system weight to the motor power, fan pressure ratio, and electrical transmission efficiency of the aft boundary layer ingesting fan.

Compressible turbulence measurements in a supersonic boundary layer including favorable pressure gradient effects

NASA Astrophysics Data System (ADS)

Miller, Raymond S.

1994-12-01

The effect of a favorable pressure gradient on the turbulent flow structure in a Mach 2.9 boundary layer (Re/m approximately equal to 1.5 x 10(exp 7)) is investigated experimentally. Conventional flow and hot film measurements of turbulent fluctuation properties have been made upstream of and along an expansion ramp. Upstream measurements were taken in a zero pressure gradient boundary layer 44 cm from the nozzle throat in a 6.35 cm square test section. Measurements are obtained in the boundary layer, above the expansion ramp, 71.5 cm from the nozzle throat. Mean flow and turbulent flow characteristics are measured in all three dimensions. Comparisons are made between data obtained using single and multiple-overheat cross-wire anemometry as well as conventional mean flow probes. Conventional flow measurements were taken using a Pitot probe and a 10 degree cone static probe. Flow visualization was conducted via imaging techniques (Schlieren and shadowgraph photographs). Results suggest that compressibility effects, as seen through the density fluctuations in the Reynolds shear stress, are roughly 10% relative to the mean velocity and are large relative to the velocity fluctuations. This is also observed in the total Reynolds shear stress; compressibility accounts for 50-75% of the total shear. This is particularly true in the favorable pressure gradient region, where though the peak fluctuation intensities are diminished, the streamwise component of the mean flow is larger, hence the contribution of the compressibility term is significant in the Reynolds shear.

Structural studies on a high-pressure polymorph of NaYSi 2O 6

NASA Astrophysics Data System (ADS)

Kahlenberg, Volker; Konzett, Jürgen; Kaindl, Reinhard

2007-06-01

High-pressure synthesis experiments in the system Na 2O-Y 2O 3-SiO 2 revealed the existence of a previously unknown polymorph of NaYSi 2O 6 or Na 3Y 3[Si 3O 9] 2 which was quenched from 3.0 GPa and 1000 °C. Structural investigations on this modification have been performed using single-crystal X-ray diffraction data collected at ambient conditions. Furthermore, unpolarized micro-Raman spectra have been obtained from single-crystal material. The high-P modification of NaYSi 2O 6 crystallizes in the centrosymmetric space group C2/ c with 12 formula units per cell ( a=8.2131(9) Å, b=10.3983(14) Å, c=17.6542(21) Å, β=100.804(9)°, V=1481.0(3) Å 3, R(| F|)=0.033 for 1142 independent observed reflections) and belongs to the group of cyclo-silicates. Basic building units are isolated three-membered [Si 3O 9] rings located in layers parallel to (010). Within a single layer the rings are concentrated in strings parallel to [100]. The sequence of directedness of up ( U) or down ( D) pointing tetrahedra of a single ring is UUU or DDD, respectively. Stacking of the layers parallel to b results in the formation of a three-dimensional structure in which yttrium and sodium cations are incorporated for charge compensation. In more detail, four non-tetrahedral cation positions can be differentiated which are coordinated by 6 and 8 oxygen ligands. Refinements of the site occupancies did not reveal any indication for mixed Na-Y populations on these positions. Finally, several geometrical parameters of rings occurring in cyclo-trisilicate structures have been compiled and are discussed.

A highly addressable static droplet array enabling digital control of a single droplet at pico-volume resolution.

PubMed

Jeong, Heon-Ho; Lee, Byungjin; Jin, Si Hyung; Jeong, Seong-Geun; Lee, Chang-Soo

2016-04-26

Droplet-based microfluidics enabling exquisite liquid-handling has been developed for diagnosis, drug discovery and quantitative biology. Compartmentalization of samples into a large number of tiny droplets is a great approach to perform multiplex assays and to improve reliability and accuracy using a limited volume of samples. Despite significant advances in microfluidic technology, individual droplet handling in pico-volume resolution is still a challenge in obtaining more efficient and varying multiplex assays. We present a highly addressable static droplet array (SDA) enabling individual digital manipulation of a single droplet using a microvalve system. In a conventional single-layer microvalve system, the number of microvalves required is dictated by the number of operation objects; thus, individual trap-and-release on a large-scale 2D array format is highly challenging. By integrating double-layer microvalves, we achieve a "balloon" valve that preserves the pressure-on state under released pressure; this valve can allow the selective releasing and trapping of 7200 multiplexed pico-droplets using only 1 μL of sample without volume loss. This selectivity and addressability completely arranged only single-cell encapsulated droplets from a mixture of droplet compositions via repetitive selective trapping and releasing. Thus, it will be useful for efficient handling of miniscule volumes of rare or clinical samples in multiplex or combinatory assays, and the selective collection of samples.

Wall turbulence control

NASA Technical Reports Server (NTRS)

Wilkinson, Stephen P.; Lindemann, A. Margrethe; Beeler, George B.; Mcginley, Catherine B.; Goodman, Wesley L.; Balasubramanian, R.

1986-01-01

A variety of wall turbulence control devices which were experimentally investigated are discussed; these include devices for burst control, alteration of outer flow structures, large eddy substitution, increased heat transfer efficiency, and reduction of wall pressure fluctuations. Control of pre-burst flow was demonstrated with a single, traveling surface depression which is phase-locked to elements of the burst production process. Another approach to wall turbulence control is to interfere with the outer layer coherent structures. A device in the outer part of a boundary layer was shown to suppress turbulence and reduce drag by opposing both the mean and unsteady vorticity in the boundary layer. Large eddy substitution is a method in which streamline curvature is introduced into the boundary layer in the form of streamwise vortices. Riblets, which were already shown to reduce turbulent drag, were also shown to exhibit superior heat transfer characteristics. Heat transfer efficiency as measured by the Reynolds Analogy Factor was shown to be as much as 36 percent greater than a smooth flat plate in a turbulent boundary layer. Large Eddy Break-Up (LEBU) which are also known to reduce turbulent drag were shown to reduce turbulent wall pressure fluctuation.

Boundary-Layer Transition on a Group of Blunt Nose Shapes at a Mach Number of 2.20

NASA Technical Reports Server (NTRS)

Jackson, Mary W.; Czarnecki, K. R.

1961-01-01

An investigation has been made to study boundary-layer transition on six axisymmetrical blunt bodies of revolution. Model shapes were selected with respect to the degree of favorable pressure gradient over the model surface. Tests were conducted at a Mach number of 2.20 and over a range of free-stream Reynolds number per foot of about 1.4 x 10(exp 6) to 6.5 x 10(exp 6). The tests were made at an angle of attack of 0 deg. with zero heat transfer. For the hemisphere, the flow remained essentially laminar over the model surface length for the entire pressure range of the tests. For a strong favorable pressure gradient followed by any weak favorable, neutral, or adverse gradient, the tendency was for transition to occur at or immediately behind the shoulder. A single strip of three-dimensional roughness in the region of strong favorable pressure gradient did not fix transition on the models at the roughness location except at the maximum test pressures, whereas a second roughness strip added in a region of neutral or adverse pressure gradient did fix transition. Experimental pressure coefficients agreed closely with modified Newtonian theory except in the shoulder region.

F-16XL ship #1 CAWAP flight - alpha 10 degrees, beta -5 degrees, altitude 10,000 feet

NASA Technical Reports Server (NTRS)

1996-01-01

The single-seat F-16XL (ship #1) makes another run during the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. This photo shows the aircraft gathering data at an altitude of 10,000 feet, with an angle of attack of 10 degrees and a sideslip angle of -5 degrees. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

F-16XL ship #1 CAWAP flight - alpha 21 degrees, altitude 17,500 feet

NASA Technical Reports Server (NTRS)

1996-01-01

The single-seat F-16XL (ship #1) makes another run during the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing (visible here) has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. This photo shows the aircraft gathering data at an altitude of 17,500 feet, with an angle of attack of 21 degrees The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Modeling normal shock velocity curvature relations for heterogeneous explosives

NASA Astrophysics Data System (ADS)

Yoo, Choong-Shik; Tomasino, Dane; Smith, Jesse; Kim, Minseob

2017-01-01

Many simple molecules such as N2 and CO2 have the potential to form extended "polymeric" solids under extreme conditions, which can store a large sum of chemical energy in its three-dimensional network structures made of strong covalent bonds. Diatomic nitrogen is particularly of interest because of the uniquely large energy difference between the single (160 kJ/mol) and triple (950 kJ/mol) bonds. As such, the transformation of singly bonded polymeric nitrogen back to triply bonded diatomic nitrogen molecules can release large energy ( 33 kJ/cm3 - three times that of HMX) without any negative environmental impact. Therefore, the goal of the present study has been to investigate the transformation of nitrogen and nitrogen-rich compounds to new singly bonded nitrogen-rich solids at high pressures and temperatures, using heated diamond anvil cells, Raman spectroscopy, and third-generation synchrotron x-ray diffraction. Recently, we have found a new form of singly bonded layered polymeric nitrogen (LP-N), synthesized in the stability pressure-temperature field higher than that of cg-N. This new phase is characterized by a 2D layered structure similar to the predicted Pba2 and two colossal Raman bands, arising from two groups of highly polarized nitrogen atoms. This result also provides a new constraint for the nitrogen phase diagram, highlighting an unusual symmetry lowering 3D cg- to 2D LP-N transition and thereby the enhanced electrostatic contribution to the stabilization of this densely packed LP-N. In this paper, we will review this finding of LP-N, update the phase diagram of nitrogen, and offer a chemistry view of pressure-induced transformations in dense molecular solids.

The Onset of Channelling in a Fluidized Mud Layer

NASA Astrophysics Data System (ADS)

Papanicolaou, T.; Tsakiris, A. G.; Billing, B. M.

2012-12-01

Fluidization of a soil occurs when the drag force exerted on the soil grains by upwelling water equals the submerged weight of the soil grains, hence reducing the effective (or contact) stress between the soil grains to zero. In nature, fluidization is commonly encountered in localized portions of highly saturated mud layers found in tidal flats, estuaries and lakes, where upward flow is initiated by significant pore water pressure gradients triggered by wave or tidal action. The water propagates through the fluidized mud layer by forming channels (or vents), carrying the fluidized mud to the surface and forming mud volcano structures. The presence of these fluidization channels alters the mud layer structure with implications on its hydraulic and geotechnical properties, such as the hydraulic conductivity. Despite the importance of these channels, the conditions that lead to their formation and their effects on the mud layer structure still remain poorly documented. The present study couples experimental and theoretical methods aimed at quantifying the conditions, under which fluidization of a saturated mud layer is accompanied by the formation of channels, and assessing the effects of channeling on the mud layer structure. Fluidization and channel formation in a mud layer were reproduced in the laboratory using a carefully designed fluidization column attached to a pressurized vessel (plenum). To eliminate any effects of the material, the mud was produced from pure kaolin clay and deionized water. Local porosity measurements along the mud layer prior, during and after fluidization were conducted using an Americium-241 gamma source placed on a fully automated carriage. Different water inflow rates, q, were applied to the base of the mud layer and the plenum pressure was monitored throughout the experiment. These experiments revealed that for high q values, a single vertical channel formed and erupted at the center of the fluidization column. Instead for low q values, the experiments suggested that a channel network formed within the mud layer leading to the eruption of multiple channels on the mud layer surface. The gamma source measurements captured quantitatively the porosity increase as the channel formed. The experiments were complemented with a theoretical analysis using the two-phase, flow mass and momentum governing equations. This analysis aims to establish a relation between the applied pressure, the fluid velocity and the local porosity of mud during the formation of the channels.

An investigation of turbulence structure in a low-Reynolds-number incompressible turbulent boundary

NASA Technical Reports Server (NTRS)

White, B. R.; Strataridakis, C. J.

1987-01-01

An existing high turbulence intensity level (5%) atmospheric boundary-layer wind tunnel has been successfully converted to a relatively low level turbulence (0.3%) wind tunnel through extensive modification, testing, and calibration. A splitter plate was designed, built, and installed into the wind-tunnel facility to create thick, mature, two-dimensional turbulent boundary layer flow at zero pressure gradient. Single and cross hot-wire measurements show turbulent boundary layer characteristics of good quality with unusually large physical size, i.e., viscous sublayer of the order of 1 mm high. These confirm the potential ability of the tunnel to be utilized for future high-quality near-wall turbulent boundary layer measurements. It compares very favorably with many low turbulence research tunnels.

Purification and partial characterization of Flavotoxin A.

PubMed Central

Hu, W J; Zhang, G S; Chu, F S; Meng, H D; Meng, Z H

1984-01-01

A heat-resistant, low-molecular-weight toxin was isolated from semisolid potato dextrose agar medium after inoculation with Flavobacterium farinofermentans sp. nov., which was isolated from fermented corn meal that caused some outbreaks of food poisoning in China. The toxin was purified by solvent partition, Sephadex LH-20 gel filtration, and C-18 reversed-phase column chromatography. Thin-layer chromatography and high-pressure liquid chromatographic methods were developed for the identification and analysis of the toxin. The purified toxin exhibited a single spot in thin-layer chromatography and a single peak in high-pressure liquid chromatography and had adsorption maxima at 232 and 267 nm. Mass spectral analysis indicated a molecular weight of 169 with an experimental formula of C9H13O3. The 50% lethal dose of purified toxin in mice (oral) was less than 6.84 mg/kg, but greater than 0.68 mg/kg. Postmortem examination showed that the mice died of some type of neurological and cardiovascular system toxicity. The name Flavotoxin A is being assigned to the toxin. PMID:6391376

A mathematical model for filtration and macromolecule transport across capillary walls.

PubMed

Facchini, L; Bellin, A; Toro, E F

2014-07-01

Metabolic substrates, such as oxygen and glucose, are rapidly delivered to the cells of large organisms through filtration across microvessels walls. Modelling this important process is complicated by the strong coupling between flow and transport equations, which are linked through the osmotic pressure induced by the colloidal plasma proteins. The microvessel wall is a composite media with the internal glycocalyx layer exerting a strong sieving effect on macromolecules, with respect to the external layer composed by the endothelial cells. The physiological structure of the microvessel is represented as the superimposition of two membranes with different properties; the inner membrane represents the glycocalyx, while the outer membrane represents the surrounding endothelial cells. Application of the mass conservation principle and thermodynamic considerations lead to a model composed of two coupled second-order ordinary differential equations for the hydrostatic and osmotic pressures, one, expressing volumetric mass conservation and the other, which is non-linear in the unknown osmotic pressure, expressing macromolecules mass conservation. Despite the complexity of the system, the assumption that the properties of the layers are piece-wise constant allows us to obtain analytical solutions for the two pressures. This solution is in agreement with experimental observations, which contrary to common belief, show that flow reversal cannot occur in steady-state conditions unless the hydrostatic pressure in the lumen drops below physiologically plausible values. The observed variations of the volumetric flux and the solute mass flux in case of a significant reduction of the hydrostatic pressure at the lumen are in qualitative agreement with observed variations during detailed experiments reported in the literature. On the other hand, homogenising the microvessel wall into a single-layer membrane with equivalent properties leads to a very different distribution of pressure across the microvessel walls, not consistent with observations. Copyright © 2014 Elsevier Inc. All rights reserved.

Porous graphene-based membranes for water purification from metal ions at low differential pressures.

PubMed

Park, Jaewoo; Bazylewski, Paul; Fanchini, Giovanni

2016-05-14

A new generation of membranes for water purification based on weakly oxidized and nanoporous few-layer graphene is here introduced. These membranes dramatically decrease the high energy requirements of water purification by reverse osmosis. They combine the advantages of porous and non-oxidized single-layer graphene, offering energy-efficient water filtration at relatively low differential pressures, and highly oxidized graphene oxide, exhibiting high performance in terms of impurity adsorption. In the reported fabrication process, leaks between juxtaposed few-layer graphene flakes are sealed by thermally annealed colloidal silica, in a treatment that precedes the opening of (sub)nanometre-size pores in graphene. This process, explored for the first time in this work, results in nanoporous graphene flakes that are water-tight at the edges without occluding the (sub)nanopores. With this method, removal of impurities from water occurs through a combination of size-based pore rejection and pore-edge adsorption. Thinness of graphene flakes allows these membranes to achieve water purification from metal ions in concentrations of few parts-per-million at differential pressures as low as 30 kPa, outperforming existing graphene or graphene oxide purification systems with comparable flow rates.

Porous graphene-based membranes for water purification from metal ions at low differential pressures

NASA Astrophysics Data System (ADS)

Park, Jaewoo; Bazylewski, Paul; Fanchini, Giovanni

2016-05-01

A new generation of membranes for water purification based on weakly oxidized and nanoporous few-layer graphene is here introduced. These membranes dramatically decrease the high energy requirements of water purification by reverse osmosis. They combine the advantages of porous and non-oxidized single-layer graphene, offering energy-efficient water filtration at relatively low differential pressures, and highly oxidized graphene oxide, exhibiting high performance in terms of impurity adsorption. In the reported fabrication process, leaks between juxtaposed few-layer graphene flakes are sealed by thermally annealed colloidal silica, in a treatment that precedes the opening of (sub)nanometre-size pores in graphene. This process, explored for the first time in this work, results in nanoporous graphene flakes that are water-tight at the edges without occluding the (sub)nanopores. With this method, removal of impurities from water occurs through a combination of size-based pore rejection and pore-edge adsorption. Thinness of graphene flakes allows these membranes to achieve water purification from metal ions in concentrations of few parts-per-million at differential pressures as low as 30 kPa, outperforming existing graphene or graphene oxide purification systems with comparable flow rates.

Effect of high pressure on the electrical resistivity of optimally doped YBa2Cu3O7-δ single crystals with unidirectional planar defects

NASA Astrophysics Data System (ADS)

Vovk, R. V.; Vovk, N. R.; Khadzhai, G. Ya.; Goulatis, I. L.; Chroneos, A.

2013-08-01

In the present work the effect of hydrostatic pressure up to 10 kbar on in-plane electrical resistivity of well-structured YBa2Cu3O7-δ (δ<0.15, Тс≈91 K, ΔТс≈0.3 K) single crystals was investigated. The influence of the twin boundaries on the electrical resistivity was minimized. The resistivities temperature dependences in the interval Тс up to 300 K can be approximated by taking into account the linear term at high temperatures and the fluctuation conductivity (Maki-Thompson model) near Тс. The parameters of the linear dependence of R(T) are decreasing as the pressure is increasing. Тс increases linearly when the pressure increases with the derivative dTc/dP≈0.080 K/kbar. Among the Maki-Thompson model parameters the inter-layer distance, d, can be considered to be independent from pressure, the transverse coherence length, ξc(0)∼0.1d.

Impact of multilayered compression bandages on sub-bandage interface pressure: a model.

PubMed

Al Khaburi, J; Nelson, E A; Hutchinson, J; Dehghani-Sanij, A A

2011-03-01

Multi-component medical compression bandages are widely used to treat venous leg ulcers. The sub-bandage interface pressures induced by individual components of the multi-component compression bandage systems are not always simply additive. Current models to explain compression bandage performance do not take account of the increase in leg circumference when each bandage is applied, and this may account for the difference between predicted and actual pressures. To calculate the interface pressure when a multi-component compression bandage system is applied to a leg. Use thick wall cylinder theory to estimate the sub-bandage pressure over the leg when a multi-component compression bandage is applied to a leg. A mathematical model was developed based on thick cylinder theory to include bandage thickness in the calculation of the interface pressure in multi-component compression systems. In multi-component compression systems, the interface pressure corresponds to the sum of the pressures applied by individual bandage layers. However, the change in the limb diameter caused by additional bandage layers should be considered in the calculation. Adding the interface pressure produced by single components without considering the bandage thickness will result in an overestimate of the overall interface pressure produced by the multi-component compression systems. At the ankle (circumference 25 cm) this error can be 19.2% or even more in the case of four components bandaging systems. Bandage thickness should be considered when calculating the pressure applied using multi-component compression systems.

Recent modifications and calibration of the Langley low-turbulence pressure tunnel

NASA Technical Reports Server (NTRS)

Mcghee, R. J.; Beasley, W. D.; Foster, J. M.

1984-01-01

Modifications to the Langley Low-Turbulence Pressure Tunnel are presented and a calibration of the mean flow parameters in the test section is provided. Also included are the operational capability of the tunnel and typical test results for both single-element and multi-element airfoils. Modifications to the facility consisted of the following: replacement of the original cooling coils and antiturbulence screens and addition of a tunnel-shell heating system, a two dimensional model-support and force-balance system, a sidewall boundary layer control system, a remote-controlled survey apparatus, and a new data acquisition system. A calibration of the mean flow parameters in the test section was conducted over the complete operational range of the tunnel. The calibration included dynamic-pressure measurements, Mach number distributions, flow-angularity measurements, boundary-layer characteristics, and total-pressure profiles. In addition, test-section turbulence measurements made after the tunnel modifications have been included with these calibration data to show a comparison of existing turbulence levels with data obtained for the facility in 1941 with the original screen installation.

Thin-layer chromatography and mass spectrometry coupled using proximal probe thermal desorption with electrospray or atmospheric pressure chemical ionization.

PubMed

Ovchinnikova, Olga S; Van Berkel, Gary J

2010-06-30

An atmospheric pressure proximal probe thermal desorption sampling method coupled with secondary ionization by electrospray or atmospheric pressure chemical ionization was demonstrated for the mass spectrometric analysis of a diverse set of compounds (dyestuffs, pharmaceuticals, explosives and pesticides) separated on various high-performance thin-layer chromatography plates. Line scans along or through development lanes on the plates were carried out by moving the plate relative to a stationary heated probe positioned close to or just touching the stationary phase surface. Vapors of the compounds thermally desorbed from the surface were drawn into the ionization region of a combined electrospray ionization/atmospheric pressure chemical ionization source where they merged with reagent ions and/or charged droplets from a corona discharge or an electrospray emitter and were ionized. The ionized components were then drawn through the atmospheric pressure sampling orifice into the vacuum region of a triple quadrupole mass spectrometer and detected using full scan, single ion monitoring, or selected reaction monitoring mode. Studies of variable parameters and performance metrics including the proximal probe temperature, gas flow rate into the ionization region, surface scan speed, read-out resolution, detection limits, and surface type are discussed.

Two-dimensional simulation of discharge channels in atmospheric-pressure single dielectric barrier discharges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Jiao; Wang, Yanhui, E-mail: wangyh@dlut.edu.cn; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn

A two-dimensional fluid model is developed to study the filaments (or discharge channels) in atmospheric-pressure discharge with one plate electrode covered by a dielectric layer. Under certain discharge parameters, one or more stable filaments with wide radii could be regularly arranged in the discharge space. Different from the short-lived randomly distributed microdischarges, this stable and thick filament can carry more current and have longer lifetime. Because only one electrode is covered by a dielectric layer in the simulation, the formed discharge channel extends outwards near the dielectric layer and shrinks inwards near the naked electrode, agreeing with the experimental results.more » In this paper, the evolution of channel is studied, and its behavior is like a streamer or an ionization wave, but the propagation distance is short. The discharge parameters such as voltage amplitude, electrode width, and N{sub 2} impurities content could significantly influence the number of discharge channel, which is discussed in the paper.« less

Petalite under pressure: Elastic behavior and phase stability

DOE PAGES

Ross, Nancy L.; Zhao, Jing; Slebodnick, Carla; ...

2015-04-01

The lithium aluminosilicate mineral petalite (LiAlSi 4O 10) has been studied using high-pressure single-crystal X-ray diffraction (HP-XRD) up to 5 GPa. Petalite undergoes two pressure-induced first-order phase transitions, never reported in the literature, at ca. 1.5 and 2.5 GPa. The first of these transforms the low-pressure α-phase of petalite (P2/c) to an intermediate β-phase that then fully converts to the high-pressure β-phase at ca. 2.5 GPa. The α→β transition is isomorphic and is associated with a commensurate modulation that triples the unit cell volume. Analysis of the HP-XRD data show that although the fundamental features of the petalite structure aremore » retained through this transition, there are subtle alterations in the internal structure of the silicate double-layers in the β-phase relative to the α-phase. Measurement of the unit cell parameters of petalite as a function of pressure, and fitting of the data with 3rd order Birch-Murnaghan equations of state, has provided revised elastic constants for petalite. The bulk moduli of the α and β-phases are 49(1) and 35(3) GPa, respectively. These values indicate that the compressibility of the- phase of petalite lies between the alkali feldpsars and alkali feldspathoids, whereas the β-phase has a compressibility more comparable with layered silicates. Structure analysis has shown that the compression of the -phase is facilitated by the rigid body movement of the Si 2O 7 units from which the silicate double-layers are constructed.« less

Estimation of methacrylate monolith binding capacity from pressure drop data.

PubMed

Podgornik, Aleš; Smrekar, Vida; Krajnc, Peter; Strancar, Aleš

2013-01-11

Convective chromatographic media comprising of membranes and monoliths represent an important group of chromatographic supports due to their flow-unaffected chromatographic properties and consequently fast separation and purification even of large biological macromolecules. Consisting of a single piece of material, common characterization procedures based on analysis of a small sample assuming to be representative for the entire batch, cannot be applied. Because of that, non-invasive characterization methods are preferred. In this work pressure drop was investigated for an estimation of dynamic binding capacity (DBC) of proteins and plasmid DNA for monoliths with different pore sizes. It was demonstrated that methacrylate monolith surface area is reciprocally proportional to pore diameter and that pressure drop on monolith is reciprocally proportional to square pore size demonstrating that methacrylate monolith microstructure is preserved by changing pore size. Based on these facts mathematical formalism has been derived predicting that DBC is in linear correlation with the square root of pressure drop. This was experimentally confirmed for ion-exchange and hydrophobic interactions for proteins and plasmid DNA. Furthermore, pressure drop was also applied for an estimation of DBC in grafted layers of different thicknesses as estimated from the pressure drop data. It was demonstrated that the capacity is proportional to the estimated grafted layer thickness. Copyright © 2012 Elsevier B.V. All rights reserved.

The Effect of Buffer Types on the In0.82Ga0.18As Epitaxial Layer Grown on an InP (100) Substrate.

PubMed

Zhang, Min; Guo, Zuoxing; Zhao, Liang; Yang, Shen; Zhao, Lei

2018-06-08

In 0.82 Ga 0.18 As epitaxial layers were grown on InP (100) substrates at 530 °C by a low-pressure metalorganic chemical vapor deposition (LP-MOCVD) technique. The effects of different buffer structures, such as a single buffer layer, compositionally graded buffer layers, and superlattice buffer layers, on the crystalline quality and property were investigated. Double-crystal X-ray diffraction (DC-XRD) measurement, Raman scattering spectrum, and Hall measurements were used to evaluate the crystalline quality and electrical property. Scanning electron microscope (SEM), atomic force microscope (AFM), and transmission electron microscope (TEM) were used to characterize the surface morphology and microstructure, respectively. Compared with the In 0.82 Ga 0.18 As epitaxial layer directly grown on an InP substrate, the quality of the sample is not obviously improved by using a single In 0.82 Ga 0.18 As buffer layer. By introducing the graded In x Ga 1−x As buffer layers, it was found that the dislocation density in the epitaxial layer significantly decreased and the surface quality improved remarkably. In addition, the number of dislocations in the epitaxial layer greatly decreased under the combined action of multi-potential wells and potential barriers by the introduction of a In 0.82 Ga 0.18 As/In 0.82 Al 0.18 As superlattice buffer. However, the surface subsequently roughened, which may be explained by surface undulation.

Heterostructured semiconductor single-walled carbon nanotube films for solution-processed high-performance field-effect transistors

NASA Astrophysics Data System (ADS)

Park, Noh-Hwal; Lee, Seung-Hoon; Jeong, Seung-Hyeon; Khim, Dongyoon; Kim, Yun Ho; Yoo, Sungmi; Noh, Yong-Young; Kim, Jang-Joo

2018-03-01

In this paper, we report a simple and effective method to simultaneously achieve a high charge-carrier mobility and low off current in conjugated polymer-wrapped semiconducting single-walled carbon nanotube (s-SWNT) transistors by applying a SWNT bilayer. To achieve the high mobility and low off current, highly purified and less purified s-SWNTs are successively coated to form the semiconducting layer consisting of poly (3-dodecylthiophene-2,5-diyl) (P3DDT)-wrapped high-pressure carbon mono oxide (HiPCO) SWNT (P3DDT-HiPCO) and poly (9, 9-di-n-dodecylfluorene) (PFDD)-wrapped plasma discharge (PD) SWNT (PFDD-PD). The SWNT transistors with bilayer SWNT networked film showed highly improved hole field-effect mobility (6.18 ± 0.85 cm2V-1s-1 average), on/off current ratio (107), and off current (˜1 pA). Thus, the combination of less purified PFDD-PD (98%-99%) charge-injection layer and highly purified s-P3DDT-HiPCO (>99%) charge-transport layer as the bi-layered semiconducting film achieved high mobility and low off current simultaneously.

Evaluation of the operational Aerosol Layer Height retrieval algorithm for Sentinel-5 Precursor: application to O2 A band observations from GOME-2A

NASA Astrophysics Data System (ADS)

Sanders, A. F. J.; de Haan, J. F.; Sneep, M.; Apituley, A.; Stammes, P.; Vieitez, M. O.; Tilstra, L. G.; Tuinder, O. N. E.; Koning, C. E.; Veefkind, J. P.

2015-06-01

An algorithm setup for the operational Aerosol Layer Height product for TROPOMI on the Sentinel-5 Precursor mission is described and discussed, applied to GOME-2A data, and evaluated with lidar measurements. The algorithm makes a spectral fit of reflectance at the O2 A band in the near-infrared and the fit window runs from 758 to 770 nm. The aerosol profile is parameterized by a scattering layer with constant aerosol volume extinction coefficient and aerosol single scattering albedo and with a fixed pressure thickness. The algorithm's target parameter is the height of this layer. In this paper, we apply the algorithm to observations from GOME-2A in a number of systematic and extensive case studies and we compare retrieved aerosol layer heights with lidar measurements. Aerosol scenes cover various aerosol types, both elevated and boundary layer aerosols, and land and sea surfaces. The aerosol optical thicknesses for these scenes are relatively moderate. Retrieval experiments with GOME-2A spectra are used to investigate various sensitivities, in which particular attention is given to the role of the surface albedo. From retrieval simulations with the single-layer model, we learn that the surface albedo should be a fit parameter when retrieving aerosol layer height from the O2 A band. Current uncertainties in surface albedo climatologies cause biases and non-convergences when the surface albedo is fixed in the retrieval. Biases disappear and convergence improves when the surface albedo is fitted, while precision of retrieved aerosol layer pressure is still largely within requirement levels. Moreover, we show that fitting the surface albedo helps to ameliorate biases in retrieved aerosol layer height when the assumed aerosol model is inaccurate. Subsequent retrievals with GOME-2A spectra confirm that convergence is better when the surface albedo is retrieved simultaneously with aerosol parameters. However, retrieved aerosol layer pressures are systematically low (i.e., layer high in the atmosphere) to the extent that retrieved values are not realistically representing actual extinction profiles anymore. When the surface albedo is fixed in retrievals with GOME-2A spectra, convergence deteriorates as expected, but retrieved aerosol layer pressures become much higher (i.e., layer lower in atmosphere). The comparison with lidar measurements indicates that retrieved aerosol layer heights are indeed representative of the underlying profile in that case. Finally, subsequent retrieval simulations with two-layer aerosol profiles show that a model error in the assumed profile (two layers in the simulation but only one in the retrieval) is partly absorbed by the surface albedo when this parameter is fitted. This is expected in view of the correlations between errors in fit parameters and the effect is relatively small for elevated layers (less than 100 hPa). In case one of the scattering layers is near the surface (boundary layer aerosols), the effect becomes surprisingly large such that the retrieved height of the single layer is above the two-layer profile. Furthermore, we find that the retrieval solution, once retrieval converges, hardly depends on the starting values for the fit. Sensitivity experiments with GOME-2A spectra also show that aerosol layer height is indeed relatively robust against inaccuracies in the assumed aerosol model, even when the surface albedo is not fitted. We show spectral fit residuals, which can be used for further investigations. Fit residuals may be partly explained by spectroscopic uncertainties, which is suggested by an experiment showing the improvement of convergence when the absorption cross section is scaled in agreement with Butz et al. (2012) and Crisp et al. (2012) and a temperature offset to the a priori ECMWF temperature profile is fitted. Retrieved temperature offsets are always negative and quite large (ranging between -4 and -8 K), which is not expected if temperature offsets absorb remaining inaccuracies in meteorological data. Other sensitivity experiments investigate fitting of stray light and fluorescence emissions. We find negative radiance offsets and negative fluorescence emissions, also for non-vegetated areas, but from the results it is not clear whether fitting these parameters improves the retrieval. Based on the present results, the operational baseline for the Aerosol Layer Height product currently will not fit the surface albedo. The product will be particularly suited for elevated, optically thick aerosol layers. In addition to its scientific value in climate research, anticipated applications of the product for TROPOMI are providing aerosol height information for aviation safety and improving interpretation of the Absorbing Aerosol Index.

Evaluation of the operational Aerosol Layer Height retrieval algorithm for Sentinel-5 Precursor: application to O2 A band observations from GOME-2A

NASA Astrophysics Data System (ADS)

Sanders, A. F. J.; de Haan, J. F.; Sneep, M.; Apituley, A.; Stammes, P.; Vieitez, M. O.; Tilstra, L. G.; Tuinder, O. N. E.; Koning, C. E.; Veefkind, J. P.

2015-11-01

An algorithm setup for the operational Aerosol Layer Height product for TROPOMI on the Sentinel-5 Precursor mission is described and discussed, applied to GOME-2A data, and evaluated with lidar measurements. The algorithm makes a spectral fit of reflectance at the O2 A band in the near-infrared and the fit window runs from 758 to 770 nm. The aerosol profile is parameterised by a scattering layer with constant aerosol volume extinction coefficient and aerosol single scattering albedo and with a fixed pressure thickness. The algorithm's target parameter is the height of this layer. In this paper, we apply the algorithm to observations from GOME-2A in a number of systematic and extensive case studies, and we compare retrieved aerosol layer heights with lidar measurements. Aerosol scenes cover various aerosol types, both elevated and boundary layer aerosols, and land and sea surfaces. The aerosol optical thicknesses for these scenes are relatively moderate. Retrieval experiments with GOME-2A spectra are used to investigate various sensitivities, in which particular attention is given to the role of the surface albedo. From retrieval simulations with the single-layer model, we learn that the surface albedo should be a fit parameter when retrieving aerosol layer height from the O2 A band. Current uncertainties in surface albedo climatologies cause biases and non-convergences when the surface albedo is fixed in the retrieval. Biases disappear and convergence improves when the surface albedo is fitted, while precision of retrieved aerosol layer pressure is still largely within requirement levels. Moreover, we show that fitting the surface albedo helps to ameliorate biases in retrieved aerosol layer height when the assumed aerosol model is inaccurate. Subsequent retrievals with GOME-2A spectra confirm that convergence is better when the surface albedo is retrieved simultaneously with aerosol parameters. However, retrieved aerosol layer pressures are systematically low (i.e., layer high in the atmosphere) to the extent that retrieved values no longer realistically represent actual extinction profiles. When the surface albedo is fixed in retrievals with GOME-2A spectra, convergence deteriorates as expected, but retrieved aerosol layer pressures become much higher (i.e., layer lower in atmosphere). The comparison with lidar measurements indicates that retrieved aerosol layer heights are indeed representative of the underlying profile in that case. Finally, subsequent retrieval simulations with two-layer aerosol profiles show that a model error in the assumed profile (two layers in the simulation but only one in the retrieval) is partly absorbed by the surface albedo when this parameter is fitted. This is expected in view of the correlations between errors in fit parameters and the effect is relatively small for elevated layers (less than 100 hPa). If one of the scattering layers is near the surface (boundary layer aerosols), the effect becomes surprisingly large, in such a way that the retrieved height of the single layer is above the two-layer profile. Furthermore, we find that the retrieval solution, once retrieval converges, hardly depends on the starting values for the fit. Sensitivity experiments with GOME-2A spectra also show that aerosol layer height is indeed relatively robust against inaccuracies in the assumed aerosol model, even when the surface albedo is not fitted. We show spectral fit residuals, which can be used for further investigations. Fit residuals may be partly explained by spectroscopic uncertainties, which is suggested by an experiment showing the improvement of convergence when the absorption cross section is scaled in agreement with Butz et al. (2013) and Crisp et al. (2012), and a temperature offset to the a priori ECMWF temperature profile is fitted. Retrieved temperature offsets are always negative and quite large (ranging between -4 and -8 K), which is not expected if temperature offsets absorb remaining inaccuracies in meteorological data. Other sensitivity experiments investigate fitting of stray light and fluorescence emissions. We find negative radiance offsets and negative fluorescence emissions, also for non-vegetated areas, but from the results it is not clear whether fitting these parameters improves the retrieval. Based on the present results, the operational baseline for the Aerosol Layer Height product currently will not fit the surface albedo. The product will be particularly suited for elevated, optically thick aerosol layers. In addition to its scientific value in climate research, anticipated applications of the product for TROPOMI are providing aerosol height information for aviation safety and improving interpretation of the Absorbing Aerosol Index.

Sound field separation with sound pressure and particle velocity measurements.

PubMed

Fernandez-Grande, Efren; Jacobsen, Finn; Leclère, Quentin

2012-12-01

In conventional near-field acoustic holography (NAH) it is not possible to distinguish between sound from the two sides of the array, thus, it is a requirement that all the sources are confined to only one side and radiate into a free field. When this requirement cannot be fulfilled, sound field separation techniques make it possible to distinguish between outgoing and incoming waves from the two sides, and thus NAH can be applied. In this paper, a separation method based on the measurement of the particle velocity in two layers and another method based on the measurement of the pressure and the velocity in a single layer are proposed. The two methods use an equivalent source formulation with separate transfer matrices for the outgoing and incoming waves, so that the sound from the two sides of the array can be modeled independently. A weighting scheme is proposed to account for the distance between the equivalent sources and measurement surfaces and for the difference in magnitude between pressure and velocity. Experimental and numerical studies have been conducted to examine the methods. The double layer velocity method seems to be more robust to noise and flanking sound than the combined pressure-velocity method, although it requires an additional measurement surface. On the whole, the separation methods can be useful when the disturbance of the incoming field is significant. Otherwise the direct reconstruction is more accurate and straightforward.

Fabrication of All-SiC Fiber-Optic Pressure Sensors for High-Temperature Applications

PubMed Central

Jiang, Yonggang; Li, Jian; Zhou, Zhiwen; Jiang, Xinggang; Zhang, Deyuan

2016-01-01

Single-crystal silicon carbide (SiC)-based pressure sensors can be used in harsh environments, as they exhibit stable mechanical and electrical properties at elevated temperatures. A fiber-optic pressure sensor with an all-SiC sensor head was fabricated and is herein proposed. SiC sensor diaphragms were fabricated via an ultrasonic vibration mill-grinding (UVMG) method, which resulted in a small grinding force and low surface roughness. The sensor head was formed by hermetically bonding two layers of SiC using a nickel diffusion bonding method. The pressure sensor illustrated a good linearity in the range of 0.1–0.9 MPa, with a resolution of 0.27% F.S. (full scale) at room temperature. PMID:27763494

Fabrication of All-SiC Fiber-Optic Pressure Sensors for High-Temperature Applications.

PubMed

Jiang, Yonggang; Li, Jian; Zhou, Zhiwen; Jiang, Xinggang; Zhang, Deyuan

2016-10-17

Single-crystal silicon carbide (SiC)-based pressure sensors can be used in harsh environments, as they exhibit stable mechanical and electrical properties at elevated temperatures. A fiber-optic pressure sensor with an all-SiC sensor head was fabricated and is herein proposed. SiC sensor diaphragms were fabricated via an ultrasonic vibration mill-grinding (UVMG) method, which resulted in a small grinding force and low surface roughness. The sensor head was formed by hermetically bonding two layers of SiC using a nickel diffusion bonding method. The pressure sensor illustrated a good linearity in the range of 0.1-0.9 MPa, with a resolution of 0.27% F.S. (full scale) at room temperature.

Pressure Mapping Mat for Tele-Home Care Applications

PubMed Central

Saenz-Cogollo, Jose Francisco; Pau, Massimiliano; Fraboni, Beatrice; Bonfiglio, Annalisa

2016-01-01

In this paper we present the development of a mat-like pressure mapping system based on a single layer textile sensor and intended to be used in home environments for monitoring the physical condition of persons with limited mobility. The sensor is fabricated by embroidering silver-coated yarns on a light cotton fabric and creating pressure-sensitive resistive elements by stamping the conductive polymer poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) at the crossing points of conductive stitches. A battery-operated mat prototype was developed and includes the scanning circuitry and a wireless communication module. A functional description of the system is presented together with a preliminary experimental evaluation of the mat prototype in the extraction of plantar pressure parameters. PMID:26978369

An Introduction to Atomic Layer Deposition

NASA Technical Reports Server (NTRS)

Dwivedi, Vivek H.

2017-01-01

Atomic Layer Deposition has been instrumental in providing a deposition method for multiple space flight applications. It is well known that ALD is a cost effective nanoadditive-manufacturing technique that allows for the conformal coating of substrates with atomic control in a benign temperature and pressure environment. Through the introduction of paired precursor gases, thin films can be deposited on a myriad of substrates from flat surfaces to those with significant topography. By providing atomic layer control, where single layers of atoms can be deposited, the fabrication of metal transparent films, precise nano-laminates, and coatings of nano-channels, pores and particles is achievable. The feasibility of this technology for NASA line of business applications range from thermal systems, optics, sensors, to environmental protection. An overview of this technology will be presented.

The resonance of twin supersonic jets

NASA Technical Reports Server (NTRS)

Morris, Philip J.

1989-01-01

This paper presents an analytical study of the resonant interaction between twin supersonic jets. An instability wave model is used to describe the large scale coherent structures in the jet mixing layers. A linearized shock cell model is also given for the jets when operating off design. The problem's geometry admits four types of normal modes associated with each azimuthal mode number in the single jet. The stability of these modes is examined for both a vortex sheet model of the jet and a jet flow represented by realistic profiles. The growth rates of each mode number and type are found to vary with jet separation and mixing layer thickness and Strouhal number. Contours of equal pressure level are obtained for each mode. The region close to the symmetry axis is found to have the greatest pressure fluctuation amplitude.

Fabricating Large-Area Sheets of Single-Layer Graphene by CVD

NASA Technical Reports Server (NTRS)

Bronikowski, Michael; Manohara, Harish

2008-01-01

This innovation consists of a set of methodologies for preparing large area (greater than 1 cm(exp 2)) domains of single-atomic-layer graphite, also called graphene, in single (two-dimensional) crystal form. To fabricate a single graphene layer using chemical vapor deposition (CVD), the process begins with an atomically flat surface of an appropriate substrate and an appropriate precursor molecule containing carbon atoms attached to substituent atoms or groups. These molecules will be brought into contact with the substrate surface by being flowed over, or sprayed onto, the substrate, under CVD conditions of low pressure and elevated temperature. Upon contact with the surface, the precursor molecules will decompose. The substituent groups detach from the carbon atoms and form gas-phase species, leaving the unfunctionalized carbon atoms attached to the substrate surface. These carbon atoms will diffuse upon this surface and encounter and bond to other carbon atoms. If conditions are chosen carefully, the surface carbon atoms will arrange to form the lowest energy single-layer structure available, which is the graphene lattice that is sought. Another method for creating the graphene lattice includes metal-catalyzed CVD, in which the decomposition of the precursor molecules is initiated by the catalytic action of a catalytic metal upon the substrate surface. Another type of metal-catalyzed CVD has the entire substrate composed of catalytic metal, or other material, either as a bulk crystal or as a think layer of catalyst deposited upon another surface. In this case, the precursor molecules decompose directly upon contact with the substrate, releasing their atoms and forming the graphene sheet. Atomic layer deposition (ALD) can also be used. In this method, a substrate surface at low temperature is covered with exactly one monolayer of precursor molecules (which may be of more than one type). This is heated up so that the precursor molecules decompose and form one monolayer of the target material.

Development of multi-frequency ESR system for high-pressure measurements up to 2.5 GPa

NASA Astrophysics Data System (ADS)

Sakurai, T.; Fujimoto, K.; Matsui, R.; Kawasaki, K.; Okubo, S.; Ohta, H.; Matsubayashi, K.; Uwatoko, Y.; Tanaka, H.

2015-10-01

A new piston-cylinder pressure cell for electron spin resonance (ESR) has been developed. The pressure cell consists of a double-layer hybrid-type cylinder with internal components made of the ZrO2-based ceramics. It can generate a pressure of 2 GPa repeatedly and reaches a maximum pressure of around 2.5 GPa. A high-pressure ESR system using a cryogen-free superconducting magnet up 10 T has also been developed for this hybrid-type pressure cell. The frequency region is from 50 GHz to 400 GHz. This is the first time a pressure above 2 GPa has been achieved in multi-frequency ESR system using a piston-cylinder pressure cell. We demonstrate its potential by showing the results of the high-pressure ESR of the S = 1 system with the single ion anisotropy NiSnCl6 · 6H2O and the S = 1 / 2 quantum spin system CsCuCl3. We performed ESR measurements of these systems above 2 GPa successfully.

Comparison of the quality of single-crystal diamonds grown on two types of seed substrates by MPCVD

NASA Astrophysics Data System (ADS)

Zhao, Yun; Guo, Yanzhao; Lin, Liangzhen; Zheng, Yuting; Hei, Lifu; Liu, Jinlong; Wei, Junjun; Chen, Liangxian; Li, Chengming

2018-06-01

Microwave plasma chemical vapor deposition (MPCVD) was used to grow single-crystal diamonds on two types of single-crystal diamond seed substrates prepared by high-pressure, high-temperature (HPHT) and chemical vapor deposition (CVD) methods. The quality of diamonds grown on the different seed substrates was compared. Fluorescence characteristics showed that the sectors of the HPHT seed substrates were obviously partitioned. Raman and absorption spectra showed that the CVD seed substrate produced higher-quality crystals with fewer nitrogen impurities. X-ray topography showed that the HPHT seed substrate had obvious growth sector boundaries, inclusions, dislocations, and stacking faults. The polarization characteristics of HPHT seed substrate were obvious, and the stress distribution was not uniform. When etching HPHT and CVD seed substrates using the same parameters, the etching morphology and extent of different growth sectors of the two substrates differed. Although extended defects were inevitably formed at the interface and propagated in the CVD layer, the dislocation density of a 1 mm-thick CVD layer grown on a CVD seed substrate was only half that of a 1 mm-thick CVD layer grown on an HPHT seed substrate. Therefore, the use of CVD seed substrate enabled the growth of a relatively higher-quality CVD single-crystal diamond.

Reduced-Pressure Chemical Vapor Deposition Growth of Isolated Ge Crystals and Suspended Layers on Micrometric Si Pillars.

PubMed

Skibitzki, Oliver; Capellini, Giovanni; Yamamoto, Yuji; Zaumseil, Peter; Schubert, Markus Andreas; Schroeder, Thomas; Ballabio, Andrea; Bergamaschini, Roberto; Salvalaglio, Marco; Miglio, Leo; Montalenti, Francesco

2016-10-05

In this work, we demonstrate the growth of Ge crystals and suspended continuous layers on Si(001) substrates deeply patterned in high aspect-ratio pillars. The material deposition was carried out in a commercial reduced-pressure chemical vapor deposition reactor, thus extending the "vertical-heteroepitaxy" technique developed by using the peculiar low-energy plasma-enhanced chemical vapor deposition reactor, to widely available epitaxial tools. The growth process was thoroughly analyzed, from the formation of small initial seeds to the final coalescence into a continuous suspended layer, by means of scanning and transmission electron microscopy, X-ray diffraction, and μ-Raman spectroscopy. The preoxidation of the Si pillar sidewalls and the addition of hydrochloric gas in the reactants proved to be key to achieve highly selective Ge growth on the pillars top only, which, in turn, is needed to promote the formation of a continuous Ge layer. Thanks to continuum growth models, we were able to single out the different roles played by thermodynamics and kinetics in the deposition dynamics. We believe that our findings will open the way to the low-cost realization of tens of micrometers thick heteroepitaxial layer (e.g., Ge, SiC, and GaAs) on Si having high crystal quality.

Effect of Pressures on the Corrosion Behaviours of Materials at 625°C

NASA Astrophysics Data System (ADS)

Li, W.; Huang, X.; Li, J.; Woo, O. T.; Sanchez, R.; Bibby, C. D.

2017-02-01

The corrosion behaviors of austenitic stainless steels (SS) 310, 304 and Ni- and Fe-based A-286 exposed to 0.1 MPa, 8 MPa and 29 MPa at 625°C for 1000 h were investigated. These represent exposure to superheated steam, subcritical and supercritical water (SCW) at 625°C, respectively. As SS 310 showed the smallest weight change, the oxide cross-sections made from 310 samples were examined by transmission electron microscopy. The results revealed a single-layer oxide at 0.1 MPa and dual-layer oxides at 8 MPa and 29 MPa, followed by a Cr-depleted region into the austenite substrate. The compositions of the inner oxides at 8 MPa and 29 MPa are Cr-rich and largely similar to those of the single-layer oxides at 0.1 MPa exposure. These results suggest that corrosion testing in superheated steam may be a suitable surrogate for scoping tests of materials under SCW conditions at >650°C.

CVD synthesis of large-area, highly crystalline MoSe2 atomic layers on diverse substrates and application to photodetectors.

PubMed

Xia, Jing; Huang, Xing; Liu, Ling-Zhi; Wang, Meng; Wang, Lei; Huang, Ben; Zhu, Dan-Dan; Li, Jun-Jie; Gu, Chang-Zhi; Meng, Xiang-Min

2014-08-07

Synthesis of large-area, atomically thin transition metal dichalcogenides (TMDs) on diverse substrates is of central importance for the large-scale fabrication of flexible devices and heterojunction-based devices. In this work, we successfully synthesized a large area of highly-crystalline MoSe2 atomic layers on SiO2/Si, mica and Si substrates using a simple chemical vapour deposition (CVD) method at atmospheric pressure. Atomic force microscopy (AFM) and Raman spectroscopy reveal that the as-grown ultrathin MoSe2 layers change from a single layer to a few layers. Photoluminescence (PL) spectroscopy demonstrates that while the multi-layer MoSe2 shows weak emission peaks, the monolayer has a much stronger emission peak at ∼ 1.56 eV, indicating the transition from an indirect to a direct bandgap. Transmission electron microscopy (TEM) analysis confirms the single-crystallinity of MoSe2 layers with a hexagonal structure. In addition, the photoresponse performance of photodetectors based on MoSe2 monolayer was studied for the first time. The devices exhibit a rapid response of ∼ 60 ms and a good photoresponsivity of ∼ 13 mA/W (using a 532 nm laser at an intensity of 1 mW mm(-2) and a bias of 10 V), suggesting that MoSe2 monolayer is a promising material for photodetection applications.

Experimental and theoretical investigation of three-dimensional turbulent boundary layers and turbulence characteristics inside an axial flow inducer passage. Final Report. Ph.D. Thesis, Jun. 1971

NASA Technical Reports Server (NTRS)

Anand, A. K.; Lakshminarayana, B.

1977-01-01

Analytical and experimental investigations of the characteristics of three dimensional turbulent boundary layers in a rotating helical passage of an inducer rotor are reported. Expressions are developed for the velocity profiles in the inner layer, where the viscous effects dominate, in the outer layer, where the viscous effects are small, and in the interference layer, where the end walls influence the flow. The prediction of boundary layer growth is based on the momentum integral technique. The equations derived are general enough to be valid for all turbomachinery rotors with arbitrary pressure gradients. The experimental investigations are carried out in a flat plate inducer 3 feet in diameter. The mean velocity profiles, turbulence intensities and shear stresses, wall shear stress, and limiting streamline angles are measured at various radial and chordwise locations by using rotating probes. The measurements are in general agreement with the predictions. The radial flows are well represented by an expression which includes the effect of stagger angle and radial pressure gradient. The radial flows in the rotor channel are higher than those on a single blade. The collateral region exists only very near the blade surface. The radial component of turbulence intensity is higher than the streamwise component because of the effect of rotation.

Cryogenic target system for hydrogen layering

DOE PAGES

Parham, T.; Kozioziemski, B.; Atkinson, D.; ...

2015-11-24

Here, a cryogenic target positioning system was designed and installed on the National Ignition Facility (NIF) target chamber. This instrument incorporates the ability to fill, form, and characterize the NIF targets with hydrogen isotopes needed for ignition experiments inside the NIF target bay then transport and position them in the target chamber. This effort brought to fruition years of research in growing and metrologizing high-quality hydrogen fuel layers and landed it in an especially demanding operations environment in the NIF facility. D-T (deuterium-tritium) layers for NIF ignition experiments have extremely tight specifications and must be grown in a very highlymore » constrained environment: a NIF ignition target inside a cryogenic target positioner inside the NIF target bay. Exquisite control of temperature, pressure, contaminant level, and thermal uniformity are necessary throughout seed formation and layer growth to create an essentially-groove-free single crystal layer.« less

High-pressure synthesis and crystal structures of the strontium oxogallates Sr2Ga2O5 and Sr5Ga6O14

NASA Astrophysics Data System (ADS)

Kahlenberg, Volker; Goettgens, Valerie; Mair, Philipp; Schmidmair, Daniela

2015-08-01

High-pressure synthesis experiments in a piston-cylinder apparatus at 1.5 GPa/3.0 GPa and 1000 °C resulted in the formation of single-crystals of Sr2Ga2O5 and Sr5Ga6O14, respectively. The structures of both compounds have been solved from single-crystal diffraction data sets using direct methods. The first compound is orthorhombic with space group type Pbca (a=10.0021(4) Å, b=9.601(4) Å, c=10.6700(4) Å, V=1024.6(4) Å3, Mr=394.68 u, Z=8, Dx=5.12 g/cm3) and belongs to the group of single layer gallates. Individual sheets are parallel to (0 0 1) and can be built from the condensation of unbranched vierer single chains running along [0 1 0]. The layers are characterized by the presence of four- and strongly elliptical eight-membered rings of corner connected tetrahedra in UUDD and UUUUDDDD conformation. Strontium atoms are sandwiched between the tetrahedral layers for charge compensation and are coordinated by six and seven oxygen ligands, respectively. Sr2Ga2O5 is isotypic with several other double sulfides and selenides. To the best of our knowledge, it is the first example of an oxide with this structure type. From a structural point of view, Sr5Ga6O14 is a phyllogallate as well. The crystal structure adopts the monoclinic space group P21/c (a=8.1426(3) Å, b=8.1803(3) Å, c=10.8755(4) Å, β=91.970(4)° V=723.98(5) Å3, Mr=1080.42 u, Z=2, Dx=4.96 g/cm3). Individual sheets extend along (0 0 1). Basic building units are unbranched dreier single chains parallel to [1 0 0]. The layers contain tertiary (Q3) und quaternary (Q4) connected [GaO4]-tetrahedra in the ratio 2:1 resulting in a Ga:O ratio of 3:7 and the formation of exclusively five-membered rings. Linkage between adjacent tetrahedral sheets is provided by three symmetrically independent strontium ions which are surrounded by six to eight oxygen atoms. The layers in Sr5Ga6O14 are similar to those observed in the melilite structure-type. Crystallochemical relationships between the present phases and other known compounds are discussed in detail.

Gas diffusion in and out of super-hydrophobic surface in transitional and turbulent boundary layers

NASA Astrophysics Data System (ADS)

Ling, Hangjian; Fu, Matthew; Hultmark, Marcus; Katz, Joseph

2017-11-01

The rate of gas diffusion in and out of a super-hydrophobic surface (SHS) located in boundary layers is investigated at varying Reynolds numbers and ambient pressures. The hierarchical SHS consists of nano-textured, 100 μm wide spanwise grooves. The boundary layers over the SHS under the Cassie-Baxter and Wenzel states as well as a smooth wall at same conditions are characterized by particle image velocimetry. The Reynolds number based on momentum thickness of the smooth wall, ReΘ0, ranges from 518 to 2088, covering transitional and turbulent boundary layer regimes. The mass diffusion rate is estimated by using microscopy to measure the time-evolution of plastron shape and volume. The data is used for calculating the Sherwood number based on smooth wall momentum thickness, ShΘ0. As expected, the diffusion rate increases linearly with the under- or super-saturation level, i.e., ShΘ0 is independent of ambient pressure. For the turbulent boundary layers, the data collapses onto ShΘ0 = 0.47ReΘ00.77 . For the transitional boundary layer, ShΘ0 is lower than the turbulent power law. When ShΘ0 is plotted against the friction Reynolds number (Reτ0) , both the transitional and turbulent boundary layer data collapse onto a single power law, ShΘ0 = 0.34Reτ00.913 . Results scaled based on Wenzel state momentum thickness show very similar trends. Sponsored by ONR.

Surface Properties of PEMFC Gas Diffusion Layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

WoodIII, David L; Rulison, Christopher; Borup, Rodney

2010-01-01

The wetting properties of PEMFC Gas Diffusion Layers (GDLs) were quantified by surface characterization measurements and modeling of material properties. Single-fiber contact-angle and surface energy (both Zisman and Owens-Wendt) data of a wide spectrum of GDL types is presented to delineate the effects of hydrophobic post-processing treatments. Modeling of the basic sessile-drop contact angle demonstrates that this value only gives a fraction of the total picture of interfacial wetting physics. Polar forces are shown to contribute 10-20 less than dispersive forces to the composite wetting of GDLs. Internal water contact angles obtained from Owens-Wendt analysis were measured at 13-19 highermore » than their single-fiber counterparts. An inverse relationship was found between internal contact angle and both Owens-Wendt surface energy and % polarity of the GDL. The most sophisticated PEMFC mathematical models use either experimentally measured capillary pressures or the standard Young-Laplace capillary-pressure equation. Based on the results of the Owens-Wendt analysis, an advancement to the Young-Laplace equation is proposed for use in these mathematical models, which utilizes only solid surface energies and fractional surface coverage of fluoropolymer. Capillary constants for the spectrum of analyzed GDLs are presented for the same purpose.« less

Theoretical prediction of energy release rate for interface crack initiation by thermal stress in environmental barrier coatings for ceramics

NASA Astrophysics Data System (ADS)

Kawai, E.; Umeno, Y.

2017-05-01

As weight reduction of turbines for aircraft engines is demanded to improve fuel consumption and curb emission of carbon dioxide, silicon carbide (SiC) fiber reinforced SiC matrix composites (SiC/SiC) are drawing enormous attention as high-pressure turbine materials. For preventing degradation of SiC/SiC, environmental barrier coatings (EBC) for ceramics are deposited on the composites. The purpose of this study is to establish theoretical guidelines for structural design which ensures the mechanical reliability of EBC. We conducted finite element method (FEM) analysis to calculate energy release rates (ERRs) for interface crack initiation due to thermal stress in EBC consisting of Si-based bond coat, Mullite and Ytterbium (Yb)-silicate layers on a SiC/SiC substrate. In the FEM analysis, the thickness of one EBC layer was changed from 25 μm to 200 μm while the thicknesses of the other layers were fixed at 25 μm, 50 μm and 100 μm. We compared ERRs obtained by the FEM analysis and a simple theory for interface crack in a single-layered structure where ERR is estimated as nominal strain energy in the coating layers multiplied by a constant factor (independent of layer thicknesses). We found that, unlike the case of single-layered structures, the multiplication factor is no longer a constant but is determined by the combination of consisting coating layer thicknesses.

Fibrous filter efficiency and pressure drop in the viscous-inertial transition flow regime.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sanchez, Andres L.; Brockmann, John E.; Dellinger, Jennifer Gwynne

2011-10-01

Fibrous filter pressure drop and aerosol collection efficiency were measured at low air pressures (0.2 to 0.8 atm) and high face velocities (5 to 20 meters per second) to give fiber Reynolds numbers in the viscous-inertial transition flow regime (1 to 16). In this regime, contemporary filtration theory based on Kuwabara's viscous flow through an ensemble of fibers under-predicts single fiber impaction by several orders of magnitude. Streamline curvature increases substantially as inertial forces become dominant. Dimensionless pressure drop measurements followed the viscous-inertial theory of Robinson and Franklin rather than Darcy's linear pressure-velocity relationship (1972). Sodium chloride and iron nano-agglomeratemore » test aerosols were used to evaluate the effects of particle density and shape factor. Total filter efficiency collapsed when plotted against the particle Stokes and fiber Reynolds numbers. Efficiencies were then fitted with an impactor type equation where the cutpoint Stokes number and a steepness parameter described data well in the sharply increasing portion of the curve (20% to 80% efficiency). The cutpoint Stokes number was a linearly decreasing function of fiber Reynolds number. Single fiber efficiencies were calculated from total filter efficiencies and compared to contemporary viscous flow impaction theory (Stechkina et al. 1969), and numerical simulations from the literature. Existing theories under-predicted measured single fiber efficiencies although the assumption of uniform flow conditions for each successive layer of fibers is questionable; the common exponential relationship between single fiber efficiency and total filter efficiency may not be appropriate in this regime.« less

A feasible method to eliminate nanoleakage in dentin hybrid layers.

PubMed

Chen, Ji-Hua; Liu, Yan; Niu, Li-Na; Lu, Shuai; Tay, Franklin R; Gao, Yu

2014-10-01

To determine whether high-pressure air blowing during adhesive application affects the infiltration of resin comonomers and nanoleakage manifestation in the resin/dentin interface under simulated pulpal pressure. Thirty mid-coronal dentin surfaces were bonded with an etch-and-rinse adhesive (Adper Single Bond 2) under simulated pulpal pressure. In the control group, the adhesive was thinned by ordinary air blowing with a pressure of 0.2 MPa, while in the experimental group, a high-pressure air blowing technique (pressure: 0.4 MPa) was used. All other procedures followed the manufacturer's instructions. Resin tag formation and nanoleakage in the bonding interface were evaluated with scanning electron microscopy (SEM) and transmission electron microscopy (TEM). When adhesive was thinned with high pressure air blowing, longer and more homogeneous resin tags were formed. The bonding interface demonstrated good overall morphology and integrity. Almost perfect infiltration of resin and no obvious nanoleakage were observed. Thinning of adhesive with high-pressure air blowing provides a clinically feasible adjunctive procedure for better resin infiltration.

Apparatus and process to eliminate diffusional limitations in a membrane biological reactor by pressure cycling

DOEpatents

Efthymiou, George S.; Shuler, Michael L.

1989-08-29

An improved multilayer continuous biological membrane reactor and a process to eliminate diffusional limitations in membrane reactors in achieved by causing a convective flux of nutrient to move into and out of an immobilized biocatalyst cell layer. In a pressure cycled mode, by increasing and decreasing the pressure in the respective layers, the differential pressure between the gaseous layer and the nutrient layer is alternately changed from positive to negative. The intermittent change in pressure differential accelerates the transfer of nutrient from the nutrient layers to the biocatalyst cell layer, the transfer of product from the cell layer to the nutrient layer and the transfer of byproduct gas from the cell layer to the gaseous layer. Such intermittent cycling substantially eliminates mass transfer gradients in diffusion inhibited systems and greatly increases product yield and throughput in both inhibited and noninhibited systems.

Fabrication of diamond based sensors for use in extreme environments

DOE PAGES

Samudrala, Gopi K.; Moore, Samuel L.; Vohra, Yogesh K.

2015-04-23

Electrical and magnetic sensors can be lithographically fabricated on top of diamond substrates and encapsulated in a protective layer of chemical vapor deposited single crystalline diamond. This process when carried out on single crystal diamond anvils employed in high pressure research is termed as designer diamond anvil fabrication. These designer diamond anvils allow researchers to study electrical and magnetic properties of materials under extreme conditions without any possibility of damaging the sensing elements. We describe a novel method for the fabrication of designer diamond anvils with the use of maskless lithography and chemical vapor deposition in this paper. This methodmore » can be utilized to produce diamond based sensors which can function in extreme environments of high pressures, high and low temperatures, corrosive and high radiation conditions. Here, we demonstrate applicability of these diamonds under extreme environments by performing electrical resistance measurements during superconducting transition in rare earth doped iron-based compounds under high pressures to 12 GPa and low temperatures to 10 K.« less

Fabrication of diamond based sensors for use in extreme environments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samudrala, Gopi K.; Moore, Samuel L.; Vohra, Yogesh K.

Electrical and magnetic sensors can be lithographically fabricated on top of diamond substrates and encapsulated in a protective layer of chemical vapor deposited single crystalline diamond. This process when carried out on single crystal diamond anvils employed in high pressure research is termed as designer diamond anvil fabrication. These designer diamond anvils allow researchers to study electrical and magnetic properties of materials under extreme conditions without any possibility of damaging the sensing elements. We describe a novel method for the fabrication of designer diamond anvils with the use of maskless lithography and chemical vapor deposition in this paper. This methodmore » can be utilized to produce diamond based sensors which can function in extreme environments of high pressures, high and low temperatures, corrosive and high radiation conditions. Here, we demonstrate applicability of these diamonds under extreme environments by performing electrical resistance measurements during superconducting transition in rare earth doped iron-based compounds under high pressures to 12 GPa and low temperatures to 10 K.« less

Methods and systems for integrating fluid dispensing technology with stereolithography

DOEpatents

Medina, Francisco; Wicker, Ryan; Palmer, Jeremy A.; Davis, Don W.; Chavez, Bart D.; Gallegos, Phillip L.

2010-02-09

An integrated system and method of integrating fluid dispensing technologies (e.g., direct-write (DW)) with rapid prototyping (RP) technologies (e.g., stereolithography (SL)) without part registration comprising: an SL apparatus and a fluid dispensing apparatus further comprising a translation mechanism adapted to translate the fluid dispensing apparatus along the Z-, Y- and Z-axes. The fluid dispensing apparatus comprises: a pressurized fluid container; a valve mechanism adapted to control the flow of fluid from the pressurized fluid container; and a dispensing nozzle adapted to deposit the fluid in a desired location. To aid in calibration, the integrated system includes a laser sensor and a mechanical switch. The method further comprises building a second part layer on top of the fluid deposits and optionally accommodating multi-layered circuitry by incorporating a connector trace. Thus, the present invention is capable of efficiently building single and multi-material SL fabricated parts embedded with complex three-dimensional circuitry using DW.

Discrete particle modeling and micromechanical characterization of bilayer tablet compaction.

PubMed

Yohannes, B; Gonzalez, M; Abebe, A; Sprockel, O; Nikfar, F; Kiang, S; Cuitiño, A M

2017-08-30

A mechanistic particle scale model is proposed for bilayer tablet compaction. Making bilayer tablets involves the application of first layer compaction pressure on the first layer powder and a second layer compaction pressure on entire powder bed. The bonding formed between the first layer and the second layer particles is crucial for the mechanical strength of the bilayer tablet. The bonding and the contact forces between particles of the first layer and second layer are affected by the deformation and rearrangement of particles due to the compaction pressures. Our model takes into consideration the elastic and plastic deformations of the first layer particles due to the first layer compaction pressure, in addition to the mechanical and physical properties of the particles. Using this model, bilayer tablets with layers of the same material and different materials, which are commonly used pharmaceutical powders, are tested. The simulations show that the strength of the layer interface becomes weaker than the strength of the two layers as the first layer compaction pressure is increased. The reduction of strength at the layer interface is related to reduction of the first layer surface roughness. The reduced roughness decreases the available bonding area and hence reduces the mechanical strength at the interface. In addition, the simulations show that at higher first layer compaction pressure the bonding area is significantly less than the total contact area at the layer interface. At the interface itself, there is a non-monotonic relationship between the bonding area and first layer force. The bonding area at the interface first increases and then decreases as the first layer pressure is increased. These results are in agreement with findings of previous experimental studies. Copyright © 2017 Elsevier B.V. All rights reserved.

Wearable-Sensor-Based Classification Models of Faller Status in Older Adults.

PubMed

Howcroft, Jennifer; Lemaire, Edward D; Kofman, Jonathan

2016-01-01

Wearable sensors have potential for quantitative, gait-based, point-of-care fall risk assessment that can be easily and quickly implemented in clinical-care and older-adult living environments. This investigation generated models for wearable-sensor based fall-risk classification in older adults and identified the optimal sensor type, location, combination, and modelling method; for walking with and without a cognitive load task. A convenience sample of 100 older individuals (75.5 ± 6.7 years; 76 non-fallers, 24 fallers based on 6 month retrospective fall occurrence) walked 7.62 m under single-task and dual-task conditions while wearing pressure-sensing insoles and tri-axial accelerometers at the head, pelvis, and left and right shanks. Participants also completed the Activities-specific Balance Confidence scale, Community Health Activities Model Program for Seniors questionnaire, six minute walk test, and ranked their fear of falling. Fall risk classification models were assessed for all sensor combinations and three model types: multi-layer perceptron neural network, naïve Bayesian, and support vector machine. The best performing model was a multi-layer perceptron neural network with input parameters from pressure-sensing insoles and head, pelvis, and left shank accelerometers (accuracy = 84%, F1 score = 0.600, MCC score = 0.521). Head sensor-based models had the best performance of the single-sensor models for single-task gait assessment. Single-task gait assessment models outperformed models based on dual-task walking or clinical assessment data. Support vector machines and neural networks were the best modelling technique for fall risk classification. Fall risk classification models developed for point-of-care environments should be developed using support vector machines and neural networks, with a multi-sensor single-task gait assessment.

Structural and interfacial defects in c-axis oriented LiNbO3 thin films grown by pulsed laser deposition on Si using Al : ZnO conducting layer

NASA Astrophysics Data System (ADS)

Shandilya, Swati; Tomar, Monika; Sreenivas, K.; Gupta, Vinay

2009-05-01

Highly c-axis oriented LiNbO3 films are deposited using pulsed laser deposition on a silicon substrate using a transparent conducting Al doped ZnO layer. X-ray diffraction and Raman spectroscopic analysis show the fabrication of single phase and oriented LiNbO3 films under the optimized deposition condition. An extra peak at 905 cm-1 was observed in the Raman spectra of LiNbO3 film deposited at higher substrate temperature and higher oxygen pressure, and attributed to the presence of niobium antisite defects in the lattice. Dielectric constant and ac conductivity of oriented LiNbO3 films deposited under the static and rotating substrate modes have been studied. Films deposited under the rotating substrate mode exhibit dielectric properties close to the LiNbO3 single crystal. The cause of deviation in the dielectric properties of the film deposited under the static substrate mode, in comparison with the bulk, are discussed in the light of the possible formation of an interdiffusion layer at the interface of the LiNbO3 film and the Al : ZnO layer.

Normal stress effects on Knudsen flow

NASA Astrophysics Data System (ADS)

Eu, Byung Chan

2018-01-01

Normal stress effects are investigated on tube flow of a single-component non-Newtonian fluid under a constant pressure gradient in a constant temperature field. The generalized hydrodynamic equations are employed, which are consistent with the laws of thermodynamics. In the cylindrical tube flow configuration, the solutions of generalized hydrodynamic equations are exactly solvable and the flow velocity is obtained in a simple one-dimensional integral quadrature. Unlike the case of flow in the absence of normal stresses, the flow develops an anomaly in that the flow in the boundary layer becomes stagnant and the thickness of such a stagnant velocity boundary layer depends on the pressure gradient, the aspect ratio of the radius to the length of the tube, and the pressure (or density and temperature) at the entrance of the tube. The volume flow rate formula through the tube is derived for the flow. It generalizes the Knudsen flow rate formula to the case of a non-Newtonian stress tensor in the presence of normal stress differences. It also reduces to the Navier-Stokes theory formula in the low shear rate limit near equilibrium.

Thermochemical Assessment of Oxygen Gettering by SiC or ZrC in PuO2-x TRISO Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Besmann, Theodore M

2010-01-01

Particulate nuclear fuel in a modular helium reactor is being considered for the consumption of excess plutonium and related transuranics. In particular, efforts to largely consume transuranics in a single-pass will require the fuel to undergo very high burnup. This deep burn concept will thus make the proposed plutonia TRISO fuel particularly likely to suffer kernel migration where carbon in the buffer layer and inner pyrolytic carbon layer is transported from the high temperature side of the particle to the low temperature side. This phenomenon is oberved to cause particle failure and therefore must be mitigated. The addition of SiCmore » or ZrC in the oxide kernel or in a layer in communication with the kernel will lower the oxygen potential and therefore prevent kernel migration, and this has been demonstrated with SiC. In this work a thermochemical analysis was performed to predict oxygen potential behavior in the plutonia TRISO fuel to burnups of 50% FIMA with and without the presence of oxygen gettering SiC and ZrC. Kernel migration is believed to be controlled by CO gas transporting carbon from the hot side to the cool side, and CO pressure is governed by the oxygen potential in the presence of carbon. The gettering phases significantly reduce the oxygen potential and thus CO pressure in an otherwise PuO2-x kernel, and prevent kernel migration by limiting CO gas diffusion through the buffer layer. The reduction in CO pressure can also reduce the peak pressure within the particles by ~50%, thus reducing the likelihood of pressure-induced particle failure. A model for kernel migration was used to semi-quantitatively assess the effect of controlling oxygen potential with SiC or ZrC and did demonstrated the dramatic effect of the addition of these phases on carbon transport.« less

Pulsed ion beam surface analysis as a means of [ital in] [ital situ] real-time analysis of thin films during growth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krauss, A.R.; Lin, Y.; Auciello, O.

1994-07-01

Low-energy (5--15 keV) pulsed ion beam surface analysis comprises several different surface spectroscopies which possess the ability to provide a remarkably wide range of information directly relevant to the growth of single and multicomponent semiconductor, metal and metal-oxide thin films and layered structures. Ion beam methods have not however, been widely used as an [ital in] [ital situ] monitor of thin film growth because existing commercial instrumentation causes excessive film damage, physically conflicts with the deposition equipment, and requires a chamber pressure [similar to]10[sup [minus]7]--10[sup [minus]8] Torr, i.e., much lower than that associated with most deposition processes ([ge]10[sup [minus]4] Torr).more » We have developed time-of-flight ion scattering and recoil spectroscopy (TOF-SARS) as a nondestructive, [ital in] [ital situ], real-time probe of thin film composition and structure which does not physically interfere with the deposition process. Several TOF-SARS implementations are exceptionally surface specific, yet in a properly designed system can yield high-resolution data at ambient pressures well in excess of 10 mTorr (4--6 orders of magnitude higher than conventional surface analytic methods). Because of the exceptional surface specificity of these methods, TOF-SARS is ideally suited as a means of studying ultrathin layers and atomically abrupt interfaces. TOF-SARS instrumentation designed specifically for use as an [ital in] [ital situ], real-time monitor of growth processes for single and multicomponent thin films and layered structures is described here. Representative data are shown for [ital in] [ital situ] analysis of Pb and Zr layers at room temperature and high vacuum, as well as under conditions appropriate to the growth of Pb(Zr[sub [ital x

Effect of bandage thickness on interface pressure applied by compression bandages.

PubMed

Al Khaburi, Jawad; Dehghani-Sanij, Abbas A; Nelson, E Andrea; Hutchinson, Jerry

2012-04-01

Medical compression bandages are widely used in the treatment of chronic venous disorder. In order to design effective compression bandages, researchers have attempted to describe the interface pressure applied by these bandages using mathematical models. This paper reports on the work carried out to derive the mathematical model used to describe the interface pressure applied by single-layer bandage using two different approaches. The first assumes that the bandage thickness is negligible, whereas the second model includes the bandage thickness. The estimated pressures using the two formulae are then compared, simulated over a 3D representation of a real leg and validated experimentally. Both theoretical and experimental results have shown that taking bandage thickness into consideration while estimating the pressures applied by a medical compression bandage will result in more accurate estimation. However, the additional accuracy is clinically insignificant. Copyright © 2011 IPEM. Published by Elsevier Ltd. All rights reserved.

Pressure-induced superconductivity in semimetallic 1 T -TiTe2 and its persistence upon decompression

NASA Astrophysics Data System (ADS)

Dutta, U.; Malavi, P. S.; Sahoo, S.; Joseph, B.; Karmakar, S.

2018-02-01

Pristine 1 T -TiTe2 single crystal has been studied for resistance and magnetoresistance behavior under quasihydrostatic and nonhydrostatic compressions. While the semimetallic state is retained in nearly hydrostatic pressures, small nonhydrostatic compression leads to an abrupt change in low-temperature resistance, a signature of possible charge density wave (CDW) ordering, that eventually collapses above 6.2 GPa. Superconductivity emerges at ˜5 GPa, rapidly increasing to a critical temperature (Tc) of 5.3 K at 12 GPa, irrespective of pressure condition. Pressure studies thus evidence that 1 T -TiTe2 exhibits superconductivity irrespective of the formation of the CDW-like state, implying the existence of phase-separated domains. Most surprisingly, the superconducting state persists upon decompression, establishing a novel phase diagram with suppressed P scale. The pressure quenchable superconductivity, of multiband nature and relatively high upper critical field, makes 1 T -TiTe2 unique among other layered dichalcogenides.

Pressure-volume characteristics of dielectric elastomer diaphragms

NASA Astrophysics Data System (ADS)

Tews, Alyson M.; Pope, Kimberly L.; Snyder, Alan J.

2003-07-01

With the ultimate goal of constructing diaphragm-type pumps, we have measured pressure-volume characteristics of single-layer dielectric elastomers diaphragms. Circular dielectric elastomer diaphragms were prepared by biaxial stretching of 3M VHB 4905 polyacrylate, or spin casting and modest or no biaxial stretching of silicone rubber films, followed by mounting to a sealed chamber having a 3.8 cm diameter opening. Pressure-volume characteristics were measured at voltages that provided field strengths up to 80 MV/m in un-deformed VHB films and 50-75 MV/m in silicone films. The most highly pre-strained VHB diaphragms were found to have linear pressure-volume characteristics whose slopes (diaphragm compliance) depended sensitively upon applied field at higher field strengths. Compliance of unstretched silicone diaphragms was nearly independent of field strength at the fields tested, but pressure-volume characteristics shifted markedly. For both kinds of dielectric elastomers, pressure-volume work loops of significant size can be obtained for certain operating pressures. Each type of diaphragm may have advantages in certain applications.

Graphene Membranes for Atmospheric Pressure Photoelectron Spectroscopy.

PubMed

Weatherup, Robert S; Eren, Baran; Hao, Yibo; Bluhm, Hendrik; Salmeron, Miquel B

2016-05-05

Atmospheric pressure X-ray photoelectron spectroscopy (XPS) is demonstrated using single-layer graphene membranes as photoelectron-transparent barriers that sustain pressure differences in excess of 6 orders of magnitude. The graphene serves as a support for catalyst nanoparticles under atmospheric pressure reaction conditions (up to 1.5 bar), where XPS allows the oxidation state of Cu nanoparticles and gas phase species to be simultaneously probed. We thereby observe that the Cu(2+) oxidation state is stable in O2 (1 bar) but is spontaneously reduced under vacuum. We further demonstrate the detection of various gas-phase species (Ar, CO, CO2, N2, O2) in the pressure range 10-1500 mbar including species with low photoionization cross sections (He, H2). Pressure-dependent changes in the apparent binding energies of gas-phase species are observed, attributable to changes in work function of the metal-coated grids supporting the graphene. We expect atmospheric pressure XPS based on this graphene membrane approach to be a valuable tool for studying nanoparticle catalysis.

Development of multi-frequency ESR system for high-pressure measurements up to 2.5 GPa.

PubMed

Sakurai, T; Fujimoto, K; Matsui, R; Kawasaki, K; Okubo, S; Ohta, H; Matsubayashi, K; Uwatoko, Y; Tanaka, H

2015-10-01

A new piston-cylinder pressure cell for electron spin resonance (ESR) has been developed. The pressure cell consists of a double-layer hybrid-type cylinder with internal components made of the ZrO2-based ceramics. It can generate a pressure of 2 GPa repeatedly and reaches a maximum pressure of around 2.5 GPa. A high-pressure ESR system using a cryogen-free superconducting magnet up 10T has also been developed for this hybrid-type pressure cell. The frequency region is from 50 GHz to 400 GHz. This is the first time a pressure above 2 GPa has been achieved in multi-frequency ESR system using a piston-cylinder pressure cell. We demonstrate its potential by showing the results of the high-pressure ESR of the S=1 system with the single ion anisotropy NiSnCl6·6H2O and the S=1/2 quantum spin system CsCuCl3. We performed ESR measurements of these systems above 2 GPa successfully. Copyright © 2015 Elsevier Inc. All rights reserved.

Pressure-sensing performance of upright cylinders in a Mach 10 boundary-layer

NASA Technical Reports Server (NTRS)

Johnson, Steven; Murphy, Kelly

1994-01-01

An experimental research program to provide basic knowledge of the pressure-sensing performance of upright, flushported cylinders in a hypersonic boundary layer is described. Three upright cylinders of 0.25-, 0.5- and l.0-in. diameters and a conventional rake were placed in the test section sidewall boundary layer of the 31 Inch Mach 10 Wind Tunnel at NASA Langley Research Center, Hampton, Virginia. Boundary-layer pressures from these cylinders were compared to those measured with a conventional rake. A boundary-layer thickness-to-cylinder-diameter ratio of 8 proved sufficient to accurately measure an overall pressure profile and ascertain the boundary-layer thickness. Effects of Reynolds number, flow angularity, and shock wave impingement on pressure measurement were also investigated. Although Reynolds number effects were negligible at the conditions studied, flow angularity above 10 deg significantly affects the measured pressures. Shock wave impingement was used to investigate orifice-to-orifice pressure crosstalk. No crosstalk was measured. The lower pressure measured above the oblique shock wave impingement showed no influence of the higher pressure generated at the lower port locations.

Effect of fabrication parameters on coating properties of tubular solid oxide fuel cell electrolyte prepared by vacuum slurry coating

NASA Astrophysics Data System (ADS)

Son, Hui-Jeong; Song, Rak-Hyun; Lim, Tak-Hyoung; Lee, Seung-Bok; Kim, Sung-Hyun; Shin, Dong-Ryul

The process of vacuum slurry coating for the fabrication of a dense and thin electrolyte film on a porous anode tube is investigated for application in solid oxide fuel cells. 8 mol% yttria stabilized zirconia is coated on an anode tube by vacuum slurry-coating process as a function of pre-sintering temperature of the anode tube, vacuum pressure, slurry concentration, number of coats, and immersion time. A dense electrolyte layer is formed on the anode tube after final sintering at 1400 °C. With decrease in the pre-sintering temperature of the anode tube, the grain size of the coated electrolyte layer increases and the number of surface pores in the coating layer decreases. This is attributed to a reduced difference in the respective shrinkage of the anode tube and the electrolyte layer. The thickness of the coated electrolyte layer increases with the content of solid powder in the slurry, the number of dip-coats, and the immersion time. Although vacuum pressure has no great influence on the electrolyte thickness, higher vacuum produces a denser coating layer, as confirmed by low gas permeability and a reduced number of defects in the coating layer. A single cell with the vacuum slurry coated electrolyte shows a good performance of 620 mW cm -2 (0.7 V) at 750 °C. These experimental results indicate that the vacuum slurry-coating process is an effective method to fabricate a dense thin film on a porous anode support.

Flight-measured laminar boundary-layer transition phenomena including stability theory analysis

NASA Technical Reports Server (NTRS)

Obara, C. J.; Holmes, B. J.

1985-01-01

Flight experiments were conducted on a single-engine turboprop aircraft fitted with a 92-in-chord, 3-ft-span natural laminar flow glove at glove section lift coefficients from 0.15 to 1.10. The boundary-layer transition measurement methods used included sublimating chemicals and surface hot-film sensors. Transition occurred downstream of the minimum pressure point. Hot-film sensors provided a well-defined indication of laminar, laminar-separation, transitional, and turbulent boundary layers. Theoretical calculations of the boundary-layer parameters provided close agreement between the predicted laminar-separation point and the measured transition location. Tollmien-Schlichting (T-S) wave growth n-factors between 15 and 17 were calculated at the predicted point of laminar separation. These results suggest that for many practical airplane cruise conditions, laminar separation (as opposed to T-S instability) is the major cause of transition in predominantly two-dimensional flows.

Shock wave boundary layer interaction on suction side of compressor profile in single passage test section

NASA Astrophysics Data System (ADS)

Flaszynski, Pawel; Doerffer, Piotr; Szwaba, Ryszard; Kaczynski, Piotr; Piotrowicz, Michal

2015-11-01

The shock wave boundary layer interaction on the suction side of transonic compressor blade is one of the main objectives of TFAST project (Transition Location Effect on Shock Wave Boundary Layer Interaction). In order to investigate the flow structure on the suction side of a profile, a design of a generic test section in linear transonic wind tunnel was proposed. The experimental and numerical results for the flow structure investigations are shown for the flow conditions as the existing ones on the suction side of the compressor profile. Near the sidewalls the suction slots are applied for the corner flow structure control. It allows to control the Axial Velocity Density Ratio (AVDR), important parameter for compressor cascade investigations. Numerical results for Explicit Algebraic Reynolds Stress Model with transition modeling are compared with oil flow visualization, schlieren and Pressure Sensitive Paint. Boundary layer transition location is detected by Temperature Sensitive Paint.

Marching iterative methods for the parabolized and thin layer Navier-Stokes equations

NASA Technical Reports Server (NTRS)

Israeli, M.

1985-01-01

Downstream marching iterative schemes for the solution of the Parabolized or Thin Layer (PNS or TL) Navier-Stokes equations are described. Modifications of the primitive equation global relaxation sweep procedure result in efficient second-order marching schemes. These schemes take full account of the reduced order of the approximate equations as they behave like the SLOR for a single elliptic equation. The improved smoothing properties permit the introduction of Multi-Grid acceleration. The proposed algorithm is essentially Reynolds number independent and therefore can be applied to the solution of the subsonic Euler equations. The convergence rates are similar to those obtained by the Multi-Grid solution of a single elliptic equation; the storage is also comparable as only the pressure has to be stored on all levels. Extensions to three-dimensional and compressible subsonic flows are discussed. Numerical results are presented.

Single-stage experimental evaluation of tandem-airfoil rotor and stator blading for compressors. Part 7: Data and performance for stage E

NASA Technical Reports Server (NTRS)

Cheatham, J. G.

1974-01-01

An axial flow compressor stage, having tandem airfoil blading, was designed for zero rotor prewhirl, constant rotor work across the span, and axial discharge flow. The stage was designed to produce a pressure ratio of 1.265 at a rotor tip velocity of 757 ft/sec. The rotor has an inlet hub/tip ratio of 0.8. The design procedure accounted for the rotor inlet boundary layer and included the effects of axial velocity ratio and secondary flow on blade row performance. The objectives of this experimental program were (1) to obtain performance with uniform and distorted inlet flow for comparison with the performance of a stage consisting of single-airfoil blading designed for the same vector diagrams and (2) to evaluate the effectiveness of accounting for the inlet boundary layer, axial velocity ratio, and secondary flows in the stage design.

An analysis of contact stiffness between a finger and an object when wearing an air-cushioned glove: the effects of the air pressure.

PubMed

Wu, John Z; Wimer, Bryan M; Welcome, Daniel E; Dong, Ren G

2012-04-01

Air-cushioned gloves have the advantages of lighter weight, lower cost, and unique mechanical performance, compared to gloves made of conventional engineering materials. The goal of this study is to analyze the contact interaction between fingers and object when wearing an air-cushioned glove. The contact interactions between the the fingertip and air bubbles, which is considered as a cell of a typical air-cushioned glove, has been analyzed theoretically. Two-dimensional finite element models were developed for the analysis. The fingertip model was assumed to be composed of skin layers, subcutaneous tissue, bone, and nail. The air bubbles were modeled as air sealed in the container of nonelastic membrane. We simulated two common scenarios: a fingertip in contact with one single air bubble and with two air cushion bubbles simultaneously. Our simulation results indicated that the internal air pressure can modulate the fingertip-object contact characteristics. The contact stiffness reaches a minimum when the initial air pressure is equal to 1.3 and 1.05 times of the atmosphere pressure for the single air bubble and the double air bubble contact, respectively. Furthermore, the simulation results indicate that the double air bubble contact will result in smaller volumetric tissue strain than the single air bubble contact for the same force. Published by Elsevier Ltd.

Dense Carbon Monoxide to 160 GPa: Stepwise Polymerization to Two-Dimensional Layered Solid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryu, Young-Jay; Kim, Minseob; Lim, Jinhyuk

Carbon monoxide (CO) is the first molecular system found to transform into a nonmolecular “polymeric” solid above 5.5 GPa, yet been studied beyond 10 GPa. Here, we show a series of pressure-induced phase transformations in CO to 160 GPa: from a molecular solid to a highly colored, low-density polymeric phase I to translucent, high-density phase II to transparent, layered phase III. The properties of these phases are consistent with those expected from recently predicted 1D P2 1/m, 3D I2 12 12 1, and 2D Cmcm structures, respectively. Thus, the present results advocate a stepwise polymerization of CO triple bonds tomore » ultimately a 2D singly bonded layer structure with an enhanced ionic character.« less

A theoretical model of fuselage pressure levels due to fan tones radiated from the intake of an installed turbofan aero-engine.

PubMed

Gaffney, James; McAlpine, Alan; Kingan, Michael J

2018-06-01

An existing theoretical model to predict the pressure levels on an aircraft's fuselage is improved by incorporating a more physically realistic method to predict fan tone radiation from the intake of an installed turbofan aero-engine. Such a model can be used as part of a method to assess cabin noise. Fan tone radiation from a turbofan intake is modelled using the exact solution for the radiated pressure from a spinning mode exiting a semi-infinite cylindrical duct immersed in a uniform flow. This approach for a spinning duct mode incorporates scattering/diffraction by the intake lip, enabling predictions of the radiated pressure valid in both the forward and aft directions. The aircraft's fuselage is represented by an infinitely long, rigid cylinder. There is uniform flow aligned with the cylinder, except close to the cylinder's surface where there is a constant-thickness boundary layer. In addition to single mode calculations it is shown how the model may be used to rapidly calculate a multi-mode incoherent radiation from the engine intake. Illustrative results are presented which demonstrate the relative importance of boundary-layer shielding both upstream and downstream of the source, as well as examples of the fuselage pressure levels due to a multi-mode tonal source at high Helmholtz number.

Smooth e-beam-deposited tin-doped indium oxide for III-nitride vertical-cavity surface-emitting laser intracavity contacts

NASA Astrophysics Data System (ADS)

Leonard, J. T.; Cohen, D. A.; Yonkee, B. P.; Farrell, R. M.; DenBaars, S. P.; Speck, J. S.; Nakamura, S.

2015-10-01

We carried out a series of simulations analyzing the dependence of mirror reflectance, threshold current density, and differential efficiency on the scattering loss caused by the roughness of tin-doped indium oxide (ITO) intracavity contacts for 405 nm flip-chip III-nitride vertical-cavity surface-emitting lasers (VCSELs). From these results, we determined that the ITO root-mean-square (RMS) roughness should be <1 nm to minimize scattering losses in VCSELs. Motivated by this requirement, we investigated the surface morphology and optoelectronic properties of electron-beam (e-beam) evaporated ITO films, as a function of substrate temperature and oxygen flow and pressure. The transparency and conductivity were seen to increase with increasing temperature. Decreasing the oxygen flow and pressure resulted in an increase in the transparency and resistivity. Neither the temperature, nor oxygen flow and pressure series on single-layer ITO films resulted in highly transparent and conductive films with <1 nm RMS roughness. To achieve <1 nm RMS roughness with good optoelectronic properties, a multi-layer ITO film was developed, utilizing a two-step temperature scheme. The optimized multi-layer ITO films had an RMS roughness of <1 nm, along with a high transparency (˜90% at 405 nm) and low resistivity (˜2 × 10-4 Ω-cm). This multi-layer ITO e-beam deposition technique is expected to prevent p-GaN plasma damage, typically observed in sputtered ITO films on p-GaN, while simultaneously reducing the threshold current density and increasing the differential efficiency of III-nitride VCSELs.

An experimental study of the wall-pressure fluctuations beneath low Reynolds number turbulent boundary layers.

PubMed

Van Blitterswyk, Jared; Rocha, Joana

2017-02-01

A more complete understanding of the physical relationships, between wall-pressure and turbulence, is required for modeling flow-induced noise and developing noise reduction strategies. In this study, the wall-pressure fluctuations, induced by low Reynolds number turbulent boundary layers, are experimentally studied using a high-resolution microphone array. Statistical characteristics obtained using traditional cross-correlation and cross-spectra analyses are complimented with wall-pressure-velocity cross-spectra and wavelet cross-correlations. Wall-pressure-velocity correlations revealed that turbulent activity in the buffer layer contributes at least 40% of the energy to the wall-pressure spectrum at all measured frequencies. As Reynolds number increases, the low-frequency energy shifts from the buffer layer to the logarithmic layer, as expected for regions of uniform streamwise momentum formed by hairpin packets. Conditional cross-spectra suggests that the majority of broadband wall-pressure energy is concentrated within the packets, with the pressure signatures of individual hairpin vortices estimated to decay on average within traveling ten displacement thicknesses, and the packet signature is retained for up to seven boundary layer thicknesses on average.

Cost comparison of three kinds of compression therapy in venous ulcer*

PubMed Central

Pereira, Bruno Emmanuel de Medeiros; de Sousa, Alana Tamar Oliveira; França, Jael Rúbia Figueiredo de Sá; Soares, Maria Júlia Guimarães Oliveira

2016-01-01

Evolution and cost of three types of compression therapy (single layer, multilayer and Unna boot) in patients with venous ulceration were compared. The evaluation lasted two months and used photographic records and instrument based on pressure ulcer scale for healing (PUSH). Treatment with monolayer compression therapy presented the lowest cost and more efficacy of the three types, with 82% savings compared with the multilayer therapy. PMID:27579760

Design Models and Model Based Design in Fluid Flow With Application to Micro Air Vehicles

DTIC Science & Technology

2009-03-12

system is dynamically essential for the dynamic representation of transients. Initial validation, in [2], used the laminar cylinder wake as a...conceptually equivalnt harmonic balancing representations (e.g., for Helicopter blades ). A by-product of [J6] is a first systematic framework for...both rapid prototyping and implementation. Wake attenuation is achieved by symmetrizing the two shear layers, using a single pressure gauge: Pulsed

Imaging the Hydrogen Absorption Dynamics of Individual Grains in Polycrystalline Palladium Thin Films in 3D

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yau, Allison; Harder, Ross J.; Kanan, Matthew W.

Defects such as dislocations and grain boundaries often control the properties of polycrystalline materials. In nanocrystalline materials, investigating this structure-function relationship while preserving the sample remains challenging because of the short length scales and buried interfaces involved. Here we use Bragg coherent diffractive imaging to investigate the role of structural inhomogeneity on the hydriding phase transformation dynamics of individual Pd grains in polycrystalline films in three-dimensional detail. In contrast to previous reports on single- and polycrystalline nanoparticles, we observe no evidence of a hydrogen-rich surface layer and consequently no size dependence in the hydriding phase transformation pressure over a 125-325more » nm size range. We do observe interesting grain boundary dynamics, including reversible rotations of grain lattices while the material remains in the hydrogen-poor phase. The mobility of the grain boundaries, combined with the lack of a hydrogen-rich surface layer, suggests that the grain boundaries are acting as fast diffusion sites for the hydrogen atoms. Such hydrogen-enhanced plasticity in the hydrogen poor phase provides insight into the switch from the size-dependent behavior of single-crystal nanoparticles to the lower transformation pressures of polycrystalline materials and may play a role in hydrogen embrittlement.« less

Transitioning from a single-phase fluid to a porous medium: a boundary layer approach

NASA Astrophysics Data System (ADS)

Dalwadi, Mohit P.; Chapman, S. Jon; Oliver, James M.; Waters, Sarah L.

2014-11-01

Pressure-driven laminar channel flow is a classic problem in fluid mechanics, and the resultant Poiseuille flow is one of the few exact solutions to the Navier-Stokes equations. If the channel interior is a porous medium (governed by Darcy's law) rather than a single-phase fluid, the resultant behaviour is plug flow. But what happens when these two flow regions are coupled, as is the case for industrial membrane filtration systems or biological tissue engineering problems? How does one flow transition to the other? We use asymptotic methods to investigate pressure-driven flow through a long channel completely blocked by a finite-length porous obstacle. We analytically solve for the flow at both small and large Reynolds number (whilst remaining within the laminar regime). The boundary layer structure is surprisingly intricate for large Reynolds number. In that limit, the structure is markedly different depending on whether there is inflow or outflow through the porous medium, there being six asymptotic regions for inflow and three for outflow. We have extended this result to a wide class of 3D porous obstacles within a Hele-Shaw cell. We obtain general boundary conditions to couple the outer flows, and find that these conditions are far from obvious at higher order.

Pressure Fluctuations Induced by a Hypersonic Turbulent Boundary Layer

NASA Technical Reports Server (NTRS)

Duan, Lian; Choudhari, Meelan M.; Zhang, Chao

2016-01-01

Direct numerical simulations (DNS) are used to examine the pressure fluctuations generated by a spatially-developed Mach 5.86 turbulent boundary layer. The unsteady pressure field is analyzed at multiple wall-normal locations, including those at the wall, within the boundary layer (including inner layer, the log layer, and the outer layer), and in the free stream. The statistical and structural variations of pressure fluctuations as a function of wall-normal distance are highlighted. Computational predictions for mean velocity pro les and surface pressure spectrum are in good agreement with experimental measurements, providing a first ever comparison of this type at hypersonic Mach numbers. The simulation shows that the dominant frequency of boundary-layer-induced pressure fluctuations shifts to lower frequencies as the location of interest moves away from the wall. The pressure wave propagates with a speed nearly equal to the local mean velocity within the boundary layer (except in the immediate vicinity of the wall) while the propagation speed deviates from the Taylor's hypothesis in the free stream. Compared with the surface pressure fluctuations, which are primarily vortical, the acoustic pressure fluctuations in the free stream exhibit a significantly lower dominant frequency, a greater spatial extent, and a smaller bulk propagation speed. The freestream pressure structures are found to have similar Lagrangian time and spatial scales as the acoustic sources near the wall. As the Mach number increases, the freestream acoustic fluctuations exhibit increased radiation intensity, enhanced energy content at high frequencies, shallower orientation of wave fronts with respect to the flow direction, and larger propagation velocity.

Anomalous acceleration of ions in a plasma accelerator with an anodic layer

NASA Astrophysics Data System (ADS)

V, M. BARDAKOV; S, D. IVANOV; A, V. KAZANTSEV; N, A. STROKIN; A, N. STUPIN; Binhao, JIANG; Zhenyu, WANG

2018-03-01

In a plasma accelerator with an anodic layer (PAAL), we discovered experimentally the effect of ‘super-acceleration’ of the bulk of the ions to energies W exceeding the energy equivalent to the discharge voltage V d. The E × B discharge was ignited in an environment of atomic argon and helium and molecular nitrogen. Singly charged argon ions were accelerated most effectively in the case of the largest discharge currents and pressure P of the working gas. Helium ions with W > eV d (e being the electron charge) were only recorded at maximum pressures. Molecular nitrogen was not accelerated to energies W > eV d. Anomalous acceleration is realized in the range of radial magnetic fields on the anode 2.8 × 10 -2 ≤ B rA ≤ 4 × 10 -2 T. It was also found analytically that the cathode of the accelerator can receive anomalously accelerated ions. In this case, the value of the potential in the anodic layer becomes higher than the anode potential, and the anode current exceeds some critical value. Numerical modeling in terms of the developed theory showed qualitative agreement between modeling data and measurements.

Single-Layer graphene growth on crystalline Ni(111) and Ni(110) and the fate of Carbon on crystalline Ni(100).

NASA Astrophysics Data System (ADS)

Araujo, Paulo; Mafra, Daniela; Reina, Alfonso; Shin, Young Cheol; Kim, Ki Kang; Dresselhaus, Mildred; Kong, Jing

The growth of large area single-layer graphene (1-LG) is studied using ambient pressure CVD on single crystal Ni(111), Ni(110) and Ni(100). By varying both the furnace temperature in the range of 700 - 1100oC and the gas flow through the growth chamber, a uniform growth of high-quality 1-LG is obtained for Ni(111) and Ni(110), but only multilayer graphene (M-LG) growth could be obtained for Ni(100). The experimental results are interpreted to obtain the optimum combination of temperature and gas flow, and the results reported in this manuscript are interpreted through different thermodynamic mechanisms, such as diffusion, segregation and adsorption, which dictate the formation of different carbon structures over the different crystallographic directions of Ni. Characterization with optical microscopy, Raman spectroscopy and optical transmission accordingly support the experimental findings. DOE Award Number DE-SC0001088, College of Arts and Sciences at the University of Alabama, NRF Award Number 2015R1C1A1A02037083 and NSF-DMR 1507806.

Pressure-sensing properties of single-walled carbon nanotubes covered with a corona-poled piezoelectric polymer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ikawa, Takeshi; Tabata, Hiroshi, E-mail: tabata@eei.eng.osaka-u.ac.jp; Yoshizawa, Takeshi

Single-walled carbon nanotubes (SWNTs) have been studied extensively as sensing elements for chemical and biochemical sensors because of their excellent electrical properties, their ultrahigh ratio of surface area to volume, and the consequent extremely high sensitivity of their surface to the surrounding environment. The extremely high sensitivity indicates that SWNTs can operate as excellent transducers when combined with piezoelectric materials. In this paper, we present a touch sensor based on SWNT thin-film transistors (SWNT-TFTs) covered with a thin film of the piezoelectric polymer poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)). Devices were fabricated by spin-coating a P(VDF-TrFE) layer on an SWNT-TFT, which was followedmore » by in situ corona poling to polarize the P(VDF-TrFE) layer. We studied the effect of the corona polarity on the device characteristics and revealed that poling with a negative corona discharge induced a large amount of hole doping in the SWNTs and improved the touch-sensing performance of the devices, while a positive discharge had a negligible effect. The poled devices exhibited regular, stable, and positive drain current modulation in response to intermittent pressing, and the response was proportional to the magnitude of the applied pressure, suggesting that it was caused by the piezoelectric effect of the polarized P(VDF-TrFE) layer. Furthermore, we also fabricated a device using horizontally aligned SWNTs with a lower SWNT density as an alternative transducer to an SWNT thin film, which demonstrated sensitivity as high as 70%/MPa.« less

Effects of pressure and deposition time on the characteristics of In2Se3 films grown by magnetron sputtering

NASA Astrophysics Data System (ADS)

Yan, Yong; Li, Shasha; Ou, Yufeng; Ji, Yaxin; Yu, Zhou; Liu, Lian; Yan, Chuanpeng; Zhang, Yong; Zhao, Yong

2014-11-01

Crystalline In2Se3 films were fabricated by magnetron sputtering from a sintered In2Se3-compound target and the effects of the deposition parameters, including the working pressure and deposition time, on the phase composition, structure, morphology, and optical properties were clarified. Single-phase κ-In2Se3 was prepared at 4.0 Pa, but γ-In2Se3 was recognized when the working pressure was lower than 4.0 Pa. The optical transmittance of the films decreased to 45% and the optical band gap varied from 2.9 to 2.0 eV with increasing film thickness from 80 to 967 nm. Metal-semiconductor-metal (MSM) photodetectors based on γ-In2Se3 thin films with various thicknesses were also fabricated. The result of photosensitivity research on such MSM photodetectors suggests that it may be impossible to fabricate wide-absorption-range MSM devices by just using a single material ( γ-In2Se3) because of spatial potential fluctuations in the layers. [Figure not available: see fulltext.

Continuous Growth of Hexagonal Graphene and Boron Nitride In-Plane Heterostructures by Atmospheric Pressure Chemical Vapor Deposition

PubMed Central

Han, Gang Hee; Rodríguez-Manzo, Julio A.; Lee, Chan-Woo; Kybert, Nicholas J.; Lerner, Mitchell B.; Qi, Zhengqing John; Dattoli, Eric N.; Rappe, Andrew M.; Drndic, Marija; Charlie Johnson, A. T.

2013-01-01

Graphene-boron nitride monolayer heterostructures contain adjacent electrically active and insulating regions in a continuous, single-atom thick layer. To date structures were grown at low pressure, resulting in irregular shapes and edge direction, so studies of the graphene-boron nitride interface were restricted to microscopy of nano-domains. Here we report templated growth of single crystalline hexagonal boron nitride directly from the oriented edge of hexagonal graphene flakes by atmospheric pressure chemical vapor deposition, and physical property measurements that inform the design of in-plane hybrid electronics. Ribbons of boron nitride monolayer were grown from the edge of a graphene template and inherited its crystallographic orientation. The relative sharpness of the interface was tuned through control of growth conditions. Frequent tearing at the graphene-boron nitride interface was observed, so density functional theory was used to determine that the nitrogen-terminated interface was prone to instability during cool down. The electronic functionality of monolayer heterostructures was demonstrated through fabrication of field effect transistors with boron nitride as an in-plane gate dielectric. PMID:24182310

Continuous growth of hexagonal graphene and boron nitride in-plane heterostructures by atmospheric pressure chemical vapor deposition.

PubMed

Han, Gang Hee; Rodríguez-Manzo, Julio A; Lee, Chan-Woo; Kybert, Nicholas J; Lerner, Mitchell B; Qi, Zhengqing John; Dattoli, Eric N; Rappe, Andrew M; Drndic, Marija; Johnson, A T Charlie

2013-11-26

Graphene-boron nitride monolayer heterostructures contain adjacent electrically active and insulating regions in a continuous, single-atom thick layer. To date structures were grown at low pressure, resulting in irregular shapes and edge direction, so studies of the graphene-boron nitride interface were restricted to the microscopy of nanodomains. Here we report templated growth of single crystalline hexagonal boron nitride directly from the oriented edge of hexagonal graphene flakes by atmospheric pressure chemical vapor deposition, and physical property measurements that inform the design of in-plane hybrid electronics. Ribbons of boron nitride monolayer were grown from the edge of a graphene template and inherited its crystallographic orientation. The relative sharpness of the interface was tuned through control of growth conditions. Frequent tearing at the graphene-boron nitride interface was observed, so density functional theory was used to determine that the nitrogen-terminated interface was prone to instability during cool down. The electronic functionality of monolayer heterostructures was demonstrated through fabrication of field effect transistors with boron nitride as an in-plane gate dielectric.

A Marine Boundary Layer Water Vapor Climatology Derived from Microwave and Near-Infrared Imagery

NASA Astrophysics Data System (ADS)

Millan Valle, L. F.; Lebsock, M. D.; Teixeira, J.

2017-12-01

The synergy of the collocated Advanced Microwave Scanning Radiometer (AMSR) and the Moderate Resolution Imaging Spectroradiometer (MODIS) provides daily global estimates of partial marine planetary boundary layer water vapor. AMSR microwave radiometry provides the total column water vapor, while MODIS near-infrared imagery provides the water vapor above the cloud layers. The difference between the two gives the vapor between the surface and the cloud top, which may be interpreted as the boundary layer water vapor. Comparisons against radiosondes, and GPS-Radio occultation data demonstrate the robustness of these boundary layer water vapor estimates. We exploit the 14 years of AMSR-MODIS synergy to investigate the spatial, seasonal, and inter-annual variations of the boundary layer water vapor. Last, it is shown that the measured AMSR-MODIS partial boundary layer water vapor can be generally prescribed using sea surface temperature, cloud top pressure and the lifting condensation level. The multi-sensor nature of the analysis demonstrates that there exists more information on boundary layer water vapor structure in the satellite observing system than is commonly assumed when considering the capabilities of single instruments. 2017 California Institute of Technology. U.S. Government sponsorship acknowledged.

Design and analysis of axial aspirated compressor stages

NASA Astrophysics Data System (ADS)

Merchant, Ali A.

The pressure ratio of axial compressor stages can be significantly increased by controlling the development of blade and endwall boundary layers in regions of adverse pressure gradient by means of boundary layer suction. This concept is validated and demonstrated through the design and analysis of two unique aspirated compressor stages: a low-speed stage with a design pressure ratio of 1.6 at a tip speed of 750 ft/s, and a high-speed stage with a design pressure ratio of 3.5 at a tip speed of 1500 ft/s. The aspirated compressor stages were designed using a new procedure which is a synthesis of low speed and high speed blade design techniques combined with a flexible inverse design method which enabled precise independent control over the shape of the blade suction and pressure surfaces. Integration of the boundary layer suction calculation into the overall design process is an essential ingredient of the new procedure. The blade design system consists of two axisymmetric through-flow codes coupled with a quasi three-dimensional viscous cascade plane code with inverse design capability. Validation of the completed designs were carried out with three-dimensional Euler and Navier-Stokes calculations. A single spanwise slot on the blade suction surface is used to bleed the boundary layer. The suction mass flow requirement for the low-speed and high-speed stages are 1% and 4% of the inlet mass flow, respectively. Additional suction between 1-2% is also required on the compressor endwalls near shock impingement locations. The rotor is modeled with a tip shroud to eliminate tip clearance effects and to discharge the suction flow radially from the flowpath. Three-dimensional viscous evaluation of the designs showed good agreement with the quasi three-dimensional design intent, except in the endwall regions. The suction requirements predicted by the quasi three-dimensional calculation were confirmed by the three-dimensional viscous calculations. The three-dimensional viscous analysis predicted a peak pressure ratio of 1.59 at an isentropic efficiency of 89% for the low-speed stage, and a peak pressure ratio of 3.68 at an isentropic efficiency of 94% for the high-speed rotor. (Copies available exclusively from MIT Libraries, Rm. 14-0551, Cambridge, MA 02139-4307. Ph. 617-253-5668; Fax 617-253-1690.)

Using UAV's to Measure the Urban Boundary Layer

NASA Astrophysics Data System (ADS)

Jacob, R. L.; Sankaran, R.; Beckman, P. H.

2015-12-01

The urban boundary layer is one of the most poorly studied regions of the atmospheric boundary layer. Since a majority of the world's population now lives in urban areas, it is becoming a more important region to measure and model. The combination of relatively low-cost unmanned aerial vehicles and low-cost sensors can together provide a new instrument for measuring urban and other boundary layers. We have mounted a new sensor and compute platform called Waggle on an off-the-shelf XR8 octo-copter from 3DRobotics. Waggle consists of multiple sensors for measuring pressure, temperature and humidity as well as trace gases such as carbon monoxide, nitrogen dioxide, sulfur dioxide and ozone. A single board computer running Linux included in Waggle on the UAV allows in-situ processing and data storage. Communication of the data is through WiFi or 3G and the Waggle software can save the data in case communication is lost during flight. The flight pattern is a deliberately simple vertical ascent and descent over a fixed location to provide vertical profiles and so flights can be confined to urban parks, industrial areas or the footprint of a single rooftop. We will present results from test flights in urban and rural areas in and around Chicago.

Numerical simulation and experiment on multilayer stagger-split die.

PubMed

Liu, Zhiwei; Li, Mingzhe; Han, Qigang; Yang, Yunfei; Wang, Bolong; Sui, Zhou

2013-05-01

A novel ultra-high pressure device, multilayer stagger-split die, has been constructed based on the principle of "dividing dies before cracking." Multilayer stagger-split die includes an encircling ring and multilayer assemblages, and the mating surfaces of the multilayer assemblages are mutually staggered between adjacent layers. In this paper, we investigated the stressing features of this structure through finite element techniques, and the results were compared with those of the belt type die and single split die. The contrast experiments were also carried out to test the bearing pressure performance of multilayer stagger-split die. It is concluded that the stress distributions are reasonable and the materials are utilized effectively for multilayer stagger-split die. And experiments indicate that the multilayer stagger-split die can bear the greatest pressure.

Multi-dimensional effects in radiation pressure acceleration of ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tripathi, V. K., E-mail: tripathivipin@yahoo.co.in

A laser carries momentum. On reflection from an ultra-thin overdense plasma foil, it deposits recoil momentum on the foil, i.e. exerts radiation pressure on the foil electrons and pushes them to the rear. The space charge field thus created takes the ions along, accelerating the electron-ion double layer as a single unit. When the foil has surface ripple, of wavelength comparable to laser wavelength, the radiation pressure acts non-uniformly on the foil and the perturbation grows as Reyleigh-Taylor (RT) instability as the foil moves. The finite spot size of the laser causes foil to bend. These effects limit the quasi-monomore » energy acceleration of ions. Multi-ion foils, e.g., diamond like carbon foil embedded with protons offer the possibility of suppressing RT instability.« less

Role of boundary layer diffusion in vapor deposition growth of chalcogenide nanosheets: the case of GeS.

PubMed

Li, Chun; Huang, Liang; Snigdha, Gayatri Pongur; Yu, Yifei; Cao, Linyou

2012-10-23

We report a synthesis of single-crystalline two-dimensional GeS nanosheets using vapor deposition processes and show that the growth behavior of the nanosheet is substantially different from those of other nanomaterials and thin films grown by vapor depositions. The nanosheet growth is subject to strong influences of the diffusion of source materials through the boundary layer of gas flows. This boundary layer diffusion is found to be the rate-determining step of the growth under typical experimental conditions, evidenced by a substantial dependence of the nanosheet's size on diffusion fluxes. We also find that high-quality GeS nanosheets can grow only in the diffusion-limited regime, as the crystalline quality substantially deteriorates when the rate-determining step is changed away from the boundary layer diffusion. We establish a simple model to analyze the diffusion dynamics in experiments. Our analysis uncovers an intuitive correlation of diffusion flux with the partial pressure of source materials, the flow rate of carrier gas, and the total pressure in the synthetic setup. The observed significant role of boundary layer diffusions in the growth is unique for nanosheets. It may be correlated with the high growth rate of GeS nanosheets, ~3-5 μm/min, which is 1 order of magnitude higher than other nanomaterials (such as nanowires) and thin films. This fundamental understanding of the effect of boundary layer diffusions may generally apply to other chalcogenide nanosheets that can grow rapidly. It can provide useful guidance for the development of general paradigms to control the synthesis of nanosheets.

[Effects of Acupuncture Stimulation of Different Layers of "Tianshu" (ST 25) Region on Changes of Intra-colonic Pressure in Normal Rats].

PubMed

Sun, Xue-Yi; Yu, Zhi; Chen, Zhi-Yu; Xu, Bin

2018-02-25

To observe the effect of manual acupuncture stimulation of different layers (skin, muscle, peritoneum, sub-peritoneum) of "Tianshu" (ST 25) region on proximal colonic pressure in normal rats. Forty-eight male SD rats were divided into 6 groups: all layer-needling, brushing, cutaneous needling, muscular needling, peritoneum-needling and sub-peritoneum-needling groups ( n ＝8 in each group). Manual needling or brushing was applied to "Tianshu" (ST 25) region. The colonic internal pressure was measured by using an amplifier and a pressure transducer-connected balloon which was implanted into the colonic cavity about 6 cm from the ileocecal valve. For rats of the all-layer needling group, an acupuncture needle was inserted into ST 25 about 1 cm deep and rotated for a while, for rats of the brushing group, a Chinese calligraphy brush pen was used to brush the skin hair for 1 min. For rats of the rest 4 groups, an acupuncture needle was inserted into the skin, muscle layer after cutting open the skin (about 0.1 cm), the peritoneum layer after cutting open the skin and muscle layers, and the sub-peritoneum layer after cutting open the skin, muscle and peritoneum layers, respectively, and rotated using the uniform reinforcing-reducing technique for about 1 min at a frequency of 120 twirlings per minute every time. During manual needling stimulation of the full layers, cutaneous layer, muscle layer, peritoneum layer and the sub-peritoneum layer of bilateral "Tianshu" (ST 25), the internal pressure of proximal colon was significantly decreased relevant to pre-stimulation in each group ( P <0.05), and there were no significant differences between bilateral sides needling stimulation in the decreased pressure levels ( P >0.05). During hair brushing of ST 25 region, the colonic pressure was observably increased relevant to pre-needling stimulation ( P <0.05). One min after the acupuncture stimulation, the decreased pressures maintained in needling the all-layer on the left side, needling the skin on the right side, needling the peritoneum layer on both sides, and needling the sub-peritoneum layer on both sides relevant to the brushing group of the same side ( P <0.05). Manual acupuncture stimulation of each layer tissue of ST 25 on both sides may lower internal pressure of proximal colon in normal rats, suggesting their involvement of acupuncture effect in relaxing proximal colonic contraction.

An experimental investigation of heat transfer to reusable surface insulation tile array gaps in a turbulent boundary layer with pressure gradient. M.S. Thesis

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.

1975-01-01

An experimental investigation was performed to determine the effect of pressure gradient on the heat transfer to space shuttle reusable surface insulation (RSI) tile array gaps under thick, turbulent boundary layer conditions. Heat transfer and pressure measurements were obtained on a curved array of full-scale simulated RSI tiles in a tunnel wall boundary layer at a nominal freestream Mach number of 10.3 and freestream unit Reynolds numbers of 1.6, 3.3, and and 6.1 million per meter. Transverse pressure gradients were induced over the model surface by rotating the curved array with respect to the flow. Definition of the tunnel wall boundary layer flow was obtained by measurement of boundary layer pitot pressure profiles, and flat plate wall pressure and heat transfer. Flat plate wall heat transfer data were correlated and a method was derived for prediction of smooth, curved array heat transfer in the highly three-dimensional tunnel wall boundary layer flow and simulation of full-scale space shuttle vehicle pressure gradient levels was assessed.

On the estimation of wall pressure coherence using time-resolved tomographic PIV

NASA Astrophysics Data System (ADS)

Pröbsting, Stefan; Scarano, Fulvio; Bernardini, Matteo; Pirozzoli, Sergio

2013-07-01

Three-dimensional time-resolved velocity field measurements are obtained using a high-speed tomographic Particle Image Velocimetry (PIV) system on a fully developed flat plate turbulent boundary layer for the estimation of wall pressure fluctuations. The work focuses on the applicability of tomographic PIV to compute the coherence of pressure fluctuations, with attention to the estimation of the stream and spanwise coherence length. The latter is required for estimations of aeroacoustic noise radiation by boundary layers and trailing edge flows, but is also of interest for vibro-structural problems. The pressure field is obtained by solving the Poisson equation for incompressible flows, where the source terms are provided by time-resolved velocity field measurements. Measured 3D velocity data is compared to results obtained from planar PIV, and a Direct Numerical Simulation (DNS) at similar Reynolds number. An improved method for the estimation of the material based on a least squares estimator of the velocity derivative along a particle trajectory is proposed and applied. Computed surface pressure fluctuations are further verified by means of simultaneous measurements by a pinhole microphone and compared to the DNS results and a semi-empirical model available from literature. The correlation coefficient for the reconstructed pressure time series with respect to pinhole microphone measurements attains approximately 0.5 for the band-pass filtered signal over the range of frequencies resolved by the velocity field measurements. Scaled power spectra of the pressure at a single point compare favorably to the DNS results and those available from literature. Finally, the coherence of surface pressure fluctuations and the resulting span- and streamwise coherence lengths are estimated and compared to semi-empirical models and DNS results.

Photoelectrolysis at the oxide-electrolyte interface as interpreted through the 'transition' layer model

NASA Astrophysics Data System (ADS)

Kalia, R. K.; Weber, Michael F.; Schumacher, L.; Dignam, M. J.

1980-12-01

A transition layer model of the oxide-electrolyte interface, proposed earlier by one of us, is outlined and then examined in the light of experimental data relating primarily to photoelectrolysis of water at semiconducting oxide electrodes. The model provides useful insight into the behaviour of the system and allows a calculation of thc minimum bias potential needed for photoelectrolysis, thus illuminating the origin of the requirement for such an external bias. In order to electrolyse water without a bias, the model requires an n-type oxide to be sufficiently reduced so that it is thermodynamically capable of chemically reducing water to produce hydrogen at 1 atm pressure. Similarly, for bias-free operation, a p-type metal oxide must be thermodynamically unstable with respect to the release of oxygen at 1 atm pressure. In the face of these requirements it is apparent that oxide stability is bound to be in general a serious problem for nonstoichiometric single metal oxides.

Postadsorption Work Function Tuning via Hydrogen Pressure Control

PubMed Central

2015-01-01

The work function of metal substrates can be easily tuned, for instance, by adsorbing layers of molecular electron donors and acceptors. In this work, we discuss the possibility of changing the donor/acceptor mixing ratio reversibly after adsorption by choosing a donor/acceptor pair that is coupled via a redox reaction and that is in equilibrium with a surrounding gas phase. We discuss such a situation for the example of tetrafluoro-1,4-benzenediol (TFBD)/tetrafluoro-1,4-benzoquinone (TFBQ), adsorbed on Cu(111) and Ag(111) surfaces. We use density functional theory and ab initio thermodynamics to show that arbitrary TFBD/TFBQ mixing ratios can be set using hydrogen pressures attainable in low to ultrahigh vacuum. Adjusting the mixing ratio allows modifying the work function over a range of about 1 eV. Finally, we contrast single-species submonolayers with mixed layers to discuss why the resulting inhomogeneities in the electrostatic energy above the surface have different impacts on the interfacial level alignment and the work function. PMID:26692915

The dynamics and control of fluctuating pressure loads in the reattachment region of a supersonic free shear layer

NASA Technical Reports Server (NTRS)

Smits, A. J.

1990-01-01

The primary aim is to investigate the mechanisms which cause the unsteady wall-pressure fluctuations in shock wave turbulent shear layer interactions. The secondary aim is to find means to reduce the magnitude of the fluctuating pressure loads by controlling the unsteady shock motion. The particular flow proposed for study is the unsteady shock wave interaction formed in the reattachment zone of a separated supersonic flow. Similar flows are encountered in many practical situations, and they are associated with high levels of fluctuating wall pressure. Wall pressure fluctuations were measured in the reattachment region of the supersonic free shear layer. The free shear layer was formed by the separation of a Mach 2.9 turbulent boundary layer from a backward facing step. Reattachment occurred on a 20 deg ramp. By adjusting the position of the ramp, the base pressure was set equal to the freestream pressure, and the free shear layer formed in the absence of a separation shock. An array of flush-mounted, miniature, high-frequency pressure transducers was used to make multichannel measurements of the fluctuating wall pressure in the vicinity of the reattachment region. Contrary to previous observations of this flow, the reattachment region was found to be highly unsteady, and the pressure fluctuations were found to be significant. The overall behavior of the wall pressure loading is similar in scale and magnitude to the unsteadiness of the wall pressure field in compression ramp flows at the same Mach number. Rayleigh scattering was used to visualize the instantaneous shock structure in the streamwise and spanwise direction. Spanwise wrinkles on the order of half the boundary layer thickness were observed.

Structure and stability of hydrous minerals at high pressure

NASA Technical Reports Server (NTRS)

Duffy, T. S.; Fei, Y.; Meade, C.; Hemley, R. J.; Mao, H. K.

1994-01-01

The presence of even small amounts of hydrogen in the Earth's deep interior may have profound effects on mantle melting, rheology, and electrical conductivity. The recent discovery of a large class of high-pressure H-bearing silicates further underscores the potentially important role for hydrous minerals in the Earth's mantle. Hydrogen may also be a significant component of the Earth's core, as has been recently documented by studies of iron hydride at high pressure. In this study, we explore the role of H in crystal structures at high pressure through detailed Raman spectroscopic and x ray diffraction studies of hydrous minerals compressed in diamond anvil cells. Brucite, Mg(OH)2, has a simple structure and serves as an analogue for the more complex hydrous silicates. Over the past five years, this material has been studied at high pressure using shock-compression, powder x ray diffraction, infrared spectroscopy, Raman spectroscopy, and neutron diffraction. In addition, we have recently carried out single-crystal synchrotron x-ray diffraction on Mg(OH)2 and Raman spectroscopy on Mg(OD)2 at elevated pressure. From all these studies, an interesting picture of the crystal chemical behavior of this material at high pressure is beginning to emerge. Some of the primary conclusions are as follows: First, hydrogen bonding is enhanced by the application of pressure. Second, layered minerals which are elastically anisotropic at low pressure may not be so at high pressure. Furthermore, the brucite data place constraints on the effect of hydrogen on seismic velocities and density at very high pressure. Third, the stability of hydrous minerals may be enhanced at high P by subtle structural rearrangements that are difficult to detect using traditional probes and require detailed spectroscopic analyses. Finally, brucite appears to be unique in that it undergoes pressure-induced disordering that is confined solely to the H-containing layers of the structure.

Self-organized pattern on the surface of a metal anode in low-pressure DC discharge

NASA Astrophysics Data System (ADS)

Yaqi, YANG; Weiguo, LI

2018-03-01

Self-organization phenomena on the surface of a metal electrode in low-pressure DC discharge is studied. In this paper, we carry out laboratory investigations of self-organization in a low-pressure test platform for 100-200 mm rod-plane gaps with a needle tip, conical tip and hemispherical tip within 1-10 kPa. The factors influencing the pattern profile are the pressure value, gap length and shape of the electrode, and a variety of pattern structures are observed by changing these factors. With increasing pressure, first the pattern diameter increases and then decreases. With the needle tip, layer structure, single-ring structure and double-ring structure are displayed successively with increasing pressure. With the conical tip, the ring-like structure gradually forms separate spots with increasing pressure. With the hemispherical tip, there are anode spots inside the ring structure. With the increase of gap length, the diameter of the self-organized pattern increases and the profile of the pattern changes. The development process of the pattern contains three key stages: pattern enlargement, pattern stabilization and pattern shrink.

Experimental Evaluation of an Isolated Synthetic Jet IN Crossflow

NASA Technical Reports Server (NTRS)

Schaeffler, Norman W.; Jenkins, Luther N.; Hepner, Timothy E.

2007-01-01

The second case for this workshop builds upon the isolated synthetic jet of Case 1 by adding a crossflow, with no streamwise pressure gradient, for the developing jet to interact with. Formally, Case 2 examines the interaction of a single, isolated, synthetic jet and a fully turbulent zero-pressure gradient boundary layer. The resulting flow has many of the characteristics that need to be modeled with fidelity if the results of the calculations are to serve as the basis for research and design with active flow control devices. These include the turbulence in the boundary layer, the time-evolution of the large vortical structure emanating from the jet orifice and its subsequent interaction with and distortion by the boundary layer turbulence, and the effect of the suction cycle on the boundary layer flow. In a synthetic jet, the flow through the orifice and out into the outer flowfield alternates between an exhaust and a suction cycle, driven by the contraction and expansion of a cavity internal to the actuator. In the present experiment, the volume changes in the internal cavity are accomplished by replacing one of the rigid walls of the cavity, the wall opposite the orifice exit, with a deformable wall. This flexible wall is driven by a bottom-mounted moveable piston. The piston is driven electro-mechanically. The synthetic jet issues into the external flow through a circular orifice. In the present experiment, this orifice has a diameter of 0.250 inches (6.35 mm). The flow is conceptually similar to that documented in Schaeffler [1]. To document the flow, several measurement techniques were utilized. The upstream boundary conditions (in-flow conditions), and several key phase-averaged velocity profiles were measured with a 3-component laser-Doppler velocimetry system. Phase-averaged velocity field measurements were made with both stereo digital particle image velocimetry and 2-D digital particle image velocimetry as the primary measurement system. Surface pressure measurements were made utilizing an electronically scanned pressure system.

The influence of free-stream turbulence on turbulent boundary layers with mild adverse pressure gradients

NASA Technical Reports Server (NTRS)

Hoffmann, Jon A.

1988-01-01

The influence of near isotropic free-stream turbulence on the shape factors and skin friction coefficients of turbulent bounday layers is presented for the cases of zero and mild adverse pressure gradients. With free-stream turbulence, improved fluid mixing occurs in boundary layers with adverse pressure gradients relative to the zero pressure gradient condition, with the same free-stream turbulence intensity and length scale. Stronger boundary layers with lower shape factors occur as a result of a lower ratio of the integral scale of turbulence to the boundary layer thickness, and to vortex stretching of the turbulent eddies in the free stream, both of which act to improve the transmission of momentum from the free stream to the boundary layers.

The influence of free-stream turbulence on turbulent boundary layers with mild adverse pressure gradients

NASA Technical Reports Server (NTRS)

Hoffmann, J. A.; Kassir, S. M.; Larwood, S. M.

1989-01-01

The influence of near isotropic free-stream turbulence on the shape factors and skin friction coefficients of turbulent boundary layers is presented for the cases of zero and mild adverse pressure gradients. With free-stream turbulence, improved fluid mixing occurs in boundary layers with adverse pressure gradients relative to the zero pressure gradient condition, with the same free-stream turbulence intensity and length scale. Stronger boundary layers with lower shape factors occur as a result of a lower ratio of the integral scale of turbulence to the boundary layer thickness, and to vortex stretching of the turbulent eddies in the free-stream, both of which act to improve the transmission of momentum from the free-stream to the boundary layers.

Optical emission diagnostics of plasmas in chemical vapor deposition of single-crystal diamond

DOE PAGES

Hemawan, Kadek W.; Hemley, Russell J.

2015-08-03

Here, a key aspect of single crystal diamond growth via microwave plasma chemical vapor deposition is in-process control of the local plasma-substrate environment, that is, plasma gas phase concentrations of activated species at the plasma boundary layer near the substrate surface. Emission spectra of the plasma relative to the diamond substrate inside the microwave plasma reactor chamber have been analyzed via optical emission spectroscopy. The spectra of radical species such as CH, C 2, and H (Balmer series) important for diamond growth were found to be more depndent on operating pressure than on microwave power. Plasma gas temperatures were calculatedmore » from measurements of the C 2 Swan band (d 3Π → a 3Π transition) system. The plasma gas temperature ranges from 2800 to 3400 K depending on the spatial location of the plasma ball, microwave power and operating pressure. Addition of Ar into CH 4 + H 2 plasma input gas mixture has little influence on the Hα, Hβ, and Hγ intensities and single-crystal diamond growth rates.« less

UV-photodetector based on NiO/diamond film

NASA Astrophysics Data System (ADS)

Chang, Xiaohui; Wang, Yan-Feng; Zhang, Xiaofan; Liu, Zhangcheng; Fu, Jiao; Fan, Shuwei; Bu, Renan; Zhang, Jingwen; Wang, Wei; Wang, Hong-Xing; Wang, Jingjing

2018-01-01

In this study, a NiO/diamond UV-photodetector has been fabricated and investigated. A single crystal diamond (SCD) layer was grown on a high-pressure-high-temperature Ib-type diamond substrate by using a microwave plasma chemical vapor deposition system. NiO films were deposited directly by the reactive magnetron sputtering technique in a mixture gas of oxygen and argon onto the SCD layer. Gold films were patterned on NiO films as electrodes to form the metal-semiconductor-metal UV-photodetector which shows good repeatability and a 2 orders of magnitude UV/visible rejection ratio. Also, the NiO/diamond photodetector has a higher responsivity and a wider response range in contrast to a diamond photodetector.

Layers of air in the water beneath the floating fern Salvinia are exposed to fluctuations in pressure.

PubMed

Mayser, Matthias J; Barthlott, Wilhelm

2014-12-01

Superhydrophobic, hierarchically structured, technical surfaces (Lotus-effect) are of high scientific and economic interest because of their remarkable properties. Recently, the immense potential of air-retaining superhydrophobic surfaces, for example, for low-friction transport of fluids and drag-reducing coatings of ships has begun to be explored. A major problem of superhydrophobic surfaces mimicking the Lotus-effect is the limited persistence of the air retained, especially under rough conditions of flow. However, there are a variety of floating or diving plant and animal species that possess air-retaining surfaces optimized for durable water-repellency (Salvinia-effect). Especially floating ferns of the genus Salvinia have evolved superhydrophobic surfaces capable of maintaining layers of air for months. Apart from maintaining stability under water, the layer of air has to withstand the stresses of water pressure (up to 2.5 bars). Both of these aspects have an application to create permanent air layers on ships' hulls. We investigated the effect of pressure on air layers in a pressure cell and exposed the air layer to pressures of up to 6 bars. We investigated the suppression of the air layer at increasing pressures as well as its restoration during decreases in pressure. Three of the four examined Salvinia species are capable of maintaining air layers at pressures relevant to the conditions applying to ships' hulls. High volumes of air per surface area are advantageous for retaining at least a partial Cassie-Baxter-state under pressure, which also helps in restoring the air layer after depressurization. Closed-loop structures such as the baskets at the top of the "egg-beater hairs" (see main text) also help return the air layer to its original level at the tip of the hairs by trapping air bubbles. © The Author 2014. Published by Oxford University Press on behalf of the Society for Integrative and Comparative Biology. All rights reserved. For permissions please email: journals.permissions@oup.com.

Experimental investigation into vortex structure and pressure drop across microcavities in 3D integrated electronics

NASA Astrophysics Data System (ADS)

Renfer, Adrian; Tiwari, Manish K.; Brunschwiler, Thomas; Michel, Bruno; Poulikakos, Dimos

2011-09-01

Hydrodynamics in microcavities with cylindrical micropin fin arrays simulating a single layer of a water-cooled electronic chip stack is investigated experimentally. Both inline and staggered pin arrangements are investigated using pressure drop and microparticle image velocimetry (μPIV) measurements. The pressure drop across the cavity shows a flow transition at pin diameter-based Reynolds numbers ( Re d ) ~200. Instantaneous μPIV, performed using a pH-controlled high seeding density of tracer microspheres, helps visualize vortex structure unreported till date in microscale geometries. The post-transition flow field shows vortex shedding and flow impingement onto the pins explaining the pressure drop increase. The flow fluctuations start at the chip outlet and shift upstream with increasing Re d . No fluctuations are observed for a cavity with pin height-to-diameter ratio h/ d = 1 up to Re d ~330; however, its pressure drop was higher than for a cavity with h/d = 2 due to pronounced influence of cavity walls.

Analogue modelling of caprock failure and sediment mobilisation due to pore fluid overpressure in shallow reservoirs

NASA Astrophysics Data System (ADS)

Warsitzka, Michael; Kukowski, Nina; May, Franz

2017-04-01

Injection of CO2 in geological formations may cause excess pore fluid pressure by enhancing the fluid volume in the reservoir rock and by buoyancy-driven flow. If sediments in the reservoir and the caprock are undercompacted, pore fluid overpressure can lead to hydro-fractures in the caprock and fluidisation of sediments. Eventually, these processes trigger the formation of pipe structures, gas chimneys, gas domes or sand injections. Generally, such structures serve as high permeable pathways for fluid migration through a low-permeable seal layer and have to be considered in risk assessment or modelling of caprock integrity of CO2 storage sites. We applied scaled analogue experiments to characterise and quantify mechanisms determining the onset and migration of hydro-fractures in a low-permeable, cohesive caprock and fluidisation of unconsolidated sediments of the reservoir layer. The caprock is simulated by different types of cohesive powder. The reservoir layer consists of granulates with small particle density. Air injected through the base of the experiment and additionally through a single needle valve reaching into the analogue material is applied to generate fluid pressure within the materials. With this procedure, regional fluid pressure increase or a point-like local fluid pressure increase (e.g. injection well), respectively, can be simulated. The deformation in the analogue materials is analysed with a particle tracking imaging velocimetry technique. Pressure sensors at the base of the experiment and in the needle valve record the air pressure during an experimental run. The structural evolution observed in the experiments reveal that the cohesive cap rock first forms a dome-like anticline. Extensional fractures occur at the hinges of the anticline. A further increase of fluid pressure causes a migration of this fractures towards the surface, which is followed by intrusion of reservoir material into the fractures and the collapse of the anticline. The breakthrough of the fractures at the surface is accompanied by a significant drop of air pressure at the base of the analogue materials. The width of the dome shaped uplift is narrower and the initiating fluid pressure in the needle valve is lower, if the fluid pressure at the base of the experiment is larger. The experimental outcomes help to evaluate if the injection of CO2 into a reservoir potentially provokes initiation or reactivation of fractures and sediment mobilisation structures.

Analysis of results from wind tunnel tests of inlets for an advanced turboprop nacelle installation

NASA Technical Reports Server (NTRS)

Hancock, J. P.; Lyman, V.; Pennock, A. P.

1986-01-01

Inlets for tractor installations of advanced turboprop propulsion systems were tested in three phases, covering a period from November, 1982 to January, 1984. Nacelle inlet configuration types included single scoop, twin scoop, and annular arrangements. Tests were performed with and without boundary layer diverters and several different diverter heights were tested for the single scoop inlet. This same inlet was also tested at two different axial positions. Test Mach numbers ranged from Mach 0.20 to 0.80. Types of data taken were: (1) internal and external pressures, including inlet throat recoveries; (2) balance forces, including thrust-minus-drag; and (3) propellar blade stresses.

Radio frequency surface resistance of Tl-Ba-Ca-Cu-O films on metal and single-crystal substrates

NASA Astrophysics Data System (ADS)

Arendt, P. N.; Reeves, G. A.; Elliott, N. E.; Cooke, D. W.; Gray, E. R.; Houlton, R. J.; Brown, D. R.

1990-01-01

Films of Tl-Ba-Ca-Cu were dc magnetron sputtered from a single multielement target. The films were deposited onto substrates of: (1) magnesium oxide, (2) a silver based alloy (Consil 995), (3) a nickel based alloy (Haynes 230), and (4) buffer layers of barium fluoride or copper oxide on Consil. To form superconducting phases, post-deposition anneals were made on these films using an alumina crucible with an over pressure of thallium and flowing oxygen. After annealing, the film phases were determined using x-ray diffraction. The film surface resistances (Rs) were measured at 22 GHz in a TE011 cavity.

Low-speed single-element airfoil synthesis

NASA Technical Reports Server (NTRS)

Mcmasters, J. H.; Henderson, M. L.

1979-01-01

The use of recently developed airfoil analysis/design computational tools to clarify, enrich and extend the existing experimental data base on low-speed, single element airfoils is demonstrated. A discussion of the problem of tailoring an airfoil for a specific application at its appropriate Reynolds number is presented. This problem is approached by use of inverse (or synthesis) techniques, wherein a desirable set of boundary layer characteristics, performance objectives, and constraints are specified, which then leads to derivation of a corresponding viscous flow pressure distribution. Examples are presented which demonstrate the synthesis approach, following presentation of some historical information and background data which motivate the basic synthesis process.

Pressure sensing element based on the BN-graphene-BN heterostructure

NASA Astrophysics Data System (ADS)

Li, Mengwei; Wu, Chenggen; Zhao, Shiliang; Deng, Tao; Wang, Junqiang; Liu, Zewen; Wang, Li; Wang, Gao

2018-04-01

In this letter, we report a pressure sensing element based on the graphene-boron nitride (BN) heterostructure. The heterostructure consists of monolayer graphene sandwiched between two layers of vertically stacked dielectric BN nanofilms. The BN layers were used to protect the graphene layer from oxidation and pollution. Pressure tests were performed to investigate the characteristics of the BN-graphene-BN pressure sensing element. A sensitivity of 24.85 μV/V/mmHg is achieved in the pressure range of 130-180 kPa. After exposing the BN-graphene-BN pressure sensing element to the ambient environment for 7 days, the relative resistance change in the pressure sensing element is only 3.1%, while that of the reference open-faced graphene device without the BN protection layers is 15.7%. Thus, this strategy is promising for fabricating practical graphene pressure sensors with improved performance and stability.

Artificial neural network modeling and optimization of ultrahigh pressure extraction of green tea polyphenols.

PubMed

Xi, Jun; Xue, Yujing; Xu, Yinxiang; Shen, Yuhong

2013-11-01

In this study, the ultrahigh pressure extraction of green tea polyphenols was modeled and optimized by a three-layer artificial neural network. A feed-forward neural network trained with an error back-propagation algorithm was used to evaluate the effects of pressure, liquid/solid ratio and ethanol concentration on the total phenolic content of green tea extracts. The neural network coupled with genetic algorithms was also used to optimize the conditions needed to obtain the highest yield of tea polyphenols. The obtained optimal architecture of artificial neural network model involved a feed-forward neural network with three input neurons, one hidden layer with eight neurons and one output layer including single neuron. The trained network gave the minimum value in the MSE of 0.03 and the maximum value in the R(2) of 0.9571, which implied a good agreement between the predicted value and the actual value, and confirmed a good generalization of the network. Based on the combination of neural network and genetic algorithms, the optimum extraction conditions for the highest yield of green tea polyphenols were determined as follows: 498.8 MPa for pressure, 20.8 mL/g for liquid/solid ratio and 53.6% for ethanol concentration. The total phenolic content of the actual measurement under the optimum predicated extraction conditions was 582.4 ± 0.63 mg/g DW, which was well matched with the predicted value (597.2mg/g DW). This suggests that the artificial neural network model described in this work is an efficient quantitative tool to predict the extraction efficiency of green tea polyphenols. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

Broadband Shock Noise in Internally-Mixed Dual-Stream Jets

NASA Technical Reports Server (NTRS)

Bridges, James E.

2009-01-01

Broadband shock noise (BBSN) has been studied in some detail in single-flow jets and recently in dual-stream jets with separate flow exhaust systems. Shock noise is of great concern in these latter cases because of the noise created for the aircraft cabin by the underexpanded nozzle flow at cruise. Another case where shock noise is of concern is in the case of future supersonic aircraft that are expected to have bypass ratios small enough to justify internally mixed exhaust systems, and whose mission will push cycles to the point of imperfectly expanded flows. Dual-stream jets with internally mixed plume have some simplifying aspects relative to the separate flow jets, having a single shock structure given by the common nozzle pressure. This is used to separate the contribution of the turbulent shear layer to the broadband shock noise. Shock structure is held constant while the geometry and strength of the inner and merged shear layers are varying by changing splitter area ratio and core stream temperature. Flow and noise measurements are presented which document the efforts at separating the contribution of the inner shear layer to the broadband shock noise.

A Micromachined Piezoresistive Pressure Sensor with a Shield Layer

PubMed Central

Cao, Gang; Wang, Xiaoping; Xu, Yong; Liu, Sheng

2016-01-01

This paper presents a piezoresistive pressure sensor with a shield layer for improved stability. Compared with the conventional piezoresistive pressure sensors, the new one reported in this paper has an n-type shield layer that covers p-type piezoresistors. This shield layer aims to minimize the impact of electrical field and reduce the temperature sensitivity of piezoresistors. The proposed sensors have been successfully fabricated by bulk-micromachining techniques. A sensitivity of 0.022 mV/V/kPa and a maximum non-linearity of 0.085% FS are obtained in a pressure range of 1 MPa. After numerical simulation, the role of the shield layer has been experimentally investigated. It is demonstrated that the shield layer is able to reduce the drift caused by electrical field and ambient temperature variation. PMID:27529254

Tunable Interfacial Thermal Conductance by Molecular Dynamics

NASA Astrophysics Data System (ADS)

Shen, Meng

We study the mechanism of tunable heat transfer through interfaces between solids using a combination of non-equilibrium molecular dynamics simulation (NEMD), vibrational mode analysis and wave packet simulation. We investigate how heat transfer through interfaces is affected by factors including pressure, interfacial modulus, contact area and interfacial layer thickness, with an overreaching goal of developing fundamental knowledge that will allow one to tailor thermal properties of interfacial materials. The role of pressure and interfacial stiffness is unraveled by our studies on an epitaxial interface between two Lennard-Jones (LJ) crystals. The interfacial stiffness is varied by two different methods: (i) indirectly by applying pressure which due to anharmonic nature of bonding, increases interfacial stiffness, and (ii) directly by changing the interfacial bonding strength by varying the depth of the potential well of the LJ potential. When the interfacial bonding strength is low, quantitatively similar behavior to pressure tuning is observed when the interfacial thermal conductance is increased by directly varying the potential-well depth parameter of the LJ potential. By contrast, when the interfacial bonding strength is high, thermal conductance is almost pressure independent, and even slightly decreases with increasing pressure. This decrease can be explained by the change in overlap between the vibrational densities of states of the two crystalline materials. The role of contact area is studied by modeling structures comprised of Van der Waals junctions between single-walled nanotubes (SWCNT). Interfacial thermal conductance between SWCNTs is obtained from NEMD simulation as a function of crossing angle. In this case the junction conductance per unit area is essentially a constant. By contrast, interfacial thermal conductance between multiwalled carbon nanotubes (MWCNTs) is shown to increase with diameter of the nanotubes by recent experimental studies [1]. To elucidate this behavior we studied a simplified model comprised of an interface between two stacks of graphene ribbons to mimic the contact between multiwalled nanotubes. Our results, in agreement with experiment, show that the interfacial thermal conductance indeed increases with the number of graphene layers, corresponding to larger diameter and larger number of walls in MWCNT. The role of interfacial layer thickness is investigated by modeling a system of a few layers of graphene sandwiched between two silicon slabs. We show, by wave packet simulation and by theoretical calculation of a spring-mass model, that the transmission coefficient of individual vibrational modes is strongly dependent on the frequency and the number of graphene layers due to coherent interference effects; by contrast, the interfacial thermal conductance obtained in NEMD simulation, which represents an integral over all phonons, is essentially independent of the number of graphene layers, in agreement with recent experiments. Furthermore, when we heat one atomic layer of graphene directly, the effective interfacial conductance associated with heat dissipation to the silicon substrate is very small. We attribute this to the resistance associated with heat transfer between high and low frequency phonon modes within graphene. Finally, we also replaced graphene layers by a few WSe2 sheets and observed that interfacial thermal resistance of a Si/n-WSe2/Si structure increases linearly with interface thickness at least for 1 < n <= 20, indicating diffusive heat transfer mechanism, in contrast to ballistic behavior of a few graphene layers. The corresponding thermal conductivity (0.048 W m-1 K-1) of a few WSe2 layers is rather small. By comparing phonon dispersion of graphene layers and WSe2 sheets, we attribute the diffusive behavior of a few WSe2 sheets to abundant optical phonons at low and medium frequencies leading to very short mean free path. Our computational studies of effects of pressure and structural properties on interfacial thermal conductance provide fundamental insights for tunable heat transfer in nanostructures. [1] Professor D. Y. Li from University of Vanderbilt, private communication (Nov. 14, 2011).

Space-Time Correlations and Spectra of Wall Pressure in a Turbulent Boundary Layer

NASA Technical Reports Server (NTRS)

Willmarth, W. W.

1959-01-01

Measurements of the statistical properties of the fluctuating wall pressure produced by a subsonic turbulent boundary layer are described. The measurements provide additional information about the structure of the turbulent boundary layer; they are applicable to the problems of boundary-layer induced noise inside an airplane fuselage and to the generation of waves-on water. The spectrum of the wall pressure is presented in dimensionless form. The ratio of the root-mean-square wall pressure to the free-stream dynamic pressure is found to be a constant square root of bar P(sup 2)/q(sub infinity) = 0.006 independent of Mach number and Reynolds number. In addition, space- time correlation measurements in the stream direction show that pressure fluctuations whose scale is greater than or equal to 0.3 times the boundary-layer thickness are convected with the convection speed U(sub c) = 0.82U(sub infinity) where U(infinity) is the free-stream velocity and have lost their identity in a distance approximately equal to 10 boundary-layer thicknesses.

Resistance to forced airflow through layers of composting organic material.

PubMed

Teixeira, Denis Leocádio; de Matos, Antonio Teixeira; Melo, Evandro de Castro

2015-02-01

The objective of this study was to adjust equations to estimate the static pressure gradient of airflow through layers of organic residues submitted to two stages of biochemical degradation, and to evaluate the static pressure drop of airflow thought the material layer. Measurements of static pressure drop in the layers of sugarcane bagasse and coffee husks mixed with poultry litter on day 0 and after 30 days of composting were performed using a prototype with specific airflow rates ranging from 0.02 to 0.13 m(3) s(-1) m(-2). Static pressure gradient and specific airflow rate data were properly fit to the Shedd, Hukill & Ives and Ergun models, which may be used to predict the static pressure gradient of air to be blown through the organic residue layers. However, the Shedd model was that which best represented the phenomenon studied. The static pressure drop of airflow increased as a power of the material layer thickness and showed tendency for decreasing with the biochemical degradation time of the organic material. Copyright © 2014 Elsevier Ltd. All rights reserved.

Laser velocimetry applied to transonic and supersonic aerodynamics

NASA Technical Reports Server (NTRS)

Johnson, D. A.; Bachalo, W. D.; Moddaress, D.

1976-01-01

As a further demonstration of the capabilities of laser velocity in compressible aerodynamics, measurements obtained in a Mach 2.9 separated turbulent boundary layer and in the transonic flow past a two-dimensional airfoil section are presented and compared to data realized by conventional techniques. In the separated-flow study, the comparisons were made against pitot-static pressure data. Agreement in mean velocities was realized where the pressure measurements could be considered reliable; however, in regions of instantaneous reverse velocities, the laser results were found to be consistent with the physics of the flow whereas the pressure data were not. The laser data obtained in regions of extremely high turbulence suggest that velocity biasing does not occur if the particle occurrence rate is low relative to the turbulent fluctuation rate. Streamwise turbulence intensities are also presented. In the transonic airfoil study, velocity measurements obtained immediately outside the upper surface boundary layer of a 6-inch chord MACA 64A010 airfoil are compared to edge velocities inferred from surface pressure measurements. For free-stream Mach numbers of 0.6 and 0.8, the agreement in results was very good. Dual scatter optical arrangements in conjunction with a single particle, counter-type signal processor were employed in these investigations. Half-micron-diameter polystyrene spheres and naturally occurring condensed oil vapor acted as light scatterers in the two respective flows. Bragg-cell frequency shifting was utilized in the separated flow study.

Plasma Spray-Physical Vapor Deposition (PS-PVD) of Ceramics for Protective Coatings

NASA Technical Reports Server (NTRS)

Harder, Bryan J.; Zhu, Dongming

2011-01-01

In order to generate advanced multilayer thermal and environmental protection systems, a new deposition process is needed to bridge the gap between conventional plasma spray, which produces relatively thick coatings on the order of 125-250 microns, and conventional vapor phase processes such as electron beam physical vapor deposition (EB-PVD) which are limited by relatively slow deposition rates, high investment costs, and coating material vapor pressure requirements. The use of Plasma Spray - Physical Vapor Deposition (PS-PVD) processing fills this gap and allows thin (< 10 microns) single layers to be deposited and multilayer coatings of less than 100 microns to be generated with the flexibility to tailor microstructures by changing processing conditions. Coatings of yttria-stabilized zirconia (YSZ) were applied to NiCrAlY bond coated superalloy substrates using the PS-PVD coater at NASA Glenn Research Center. A design-of-experiments was used to examine the effects of process variables (Ar/He plasma gas ratio, the total plasma gas flow, and the torch current) on chamber pressure and torch power. Coating thickness, phase and microstructure were evaluated for each set of deposition conditions. Low chamber pressures and high power were shown to increase coating thickness and create columnar-like structures. Likewise, high chamber pressures and low power had lower growth rates, but resulted in flatter, more homogeneous layers

Effectiveness of Sealed Double-Ring Infiltrometers{trademark} and effects of changes in atmospheric pressure on hydraulic conductivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

McMullin, S.R.

The Savannah River Site is currently evaluating some 40 hazardous and radioactive-waste sites for remediation. Among the remedial alternatives considered is closure using a kaolin clay cap. The hydraulic conductivity suggested by the US Environmental Protection Agency is 1.0 {times} 10{sup {minus}7} cm/sec. One instrument to measure this value is the Sealed Double-Ring Infiltrometer{trademark} (SDRI). Six SDRI were recently installed on a kaolin test cap. Test results demonstrated uniform performance of these instruments. However, the test data showed as much as an order of magnitude of variation over time. This variation is attributed to both internal structural heterogeneity and variablemore » external boundary conditions. The internal heterogeneity is caused by construction variability within a specified range of moisture and density. The external influences considered are temperature and barometric pressure. Temperature was discharged as a source of heterogeneity because of a lack of correlation with test data and a negligible impact from the range of variability. However, a direct correlation was found between changes in barometric pressure and hydraulic conductivity. This correlation is most pronounced when pressure changes occur over a short period of time. Additionally, this correlation is related to a single soil layer. When the wetting front passes into a more porous foundation layer, the correlation with pressure changes disappears. Conclusions are that the SDRI performs adequately, with good repeatability of results. The duration of test is critical to assure a statistically valid data set. Data spikes resulting from pressure changes should be identified, and professional judgment used to determine the representative hydraulic conductivity. Further evaluation is recommended to determine the impact of pressure change on the actual hydraulic conductivity.« less

Initial development of the two-dimensional ejector shear layer - Experimental results

NASA Technical Reports Server (NTRS)

Benjamin, M. A.; Dufflocq, M.; Roan, V. P.

1993-01-01

An experimental investigation designed to study the development of shear layers in a two-dimensional single-nozzle ejector has been completed. In this study, combinations of air/air, argon/air, helium/air, and air/helium were used as the supersonic primary and subsonic secondary, respectively. Mixing of the gases occurred in a constant-area tube 39.1 mm high by 25.4 mm wide, where the inlet static pressure was maintained at 35 kPa. The cases studied resulted in convective Mach numbers between 0.058 and 1.64, density ratios between 0.102 and 3.49, and velocity ratios between 0.065 and 0.811. The resulting data shows the differences in the shear-layer development for the various combinations of independent variables utilized in the investigation. The normalized growth-rates in the near-field were found to be similar to two-dimensional mixing layers. These results have enhanced the ability to analyze and design ejector systems as well as providing a better understanding of the physics.

High-efficiency exfoliation of layered materials into 2D nanosheets in switchable CO2/Surfactant/H2O system

NASA Astrophysics Data System (ADS)

Wang, Nan; Xu, Qun; Xu, Shanshan; Qi, Yuhang; Chen, Meng; Li, Hongxiang; Han, Buxing

2015-11-01

Layered materials present attractive and important properties due to their two-dimensional (2D) structure, allowing potential applications including electronics, optoelectronics, and catalysis. However, fully exploiting the outstanding properties will require a method for their efficient exfoliation. Here we present that a series of layered materials can be successfully exfoliated into single- and few-layer nanosheets using the driving forces coming from the phase inversion, i.e., from micelles to reverse micelles in the emulsion microenvironment built by supercritical carbon dioxide (SC CO2). The effect of variable experimental parameters including CO2 pressure, ethanol/water ratio, and initial concentration of bulk materials on the exfoliation yield have been investigated. Moreover, we demonstrate that the exfoliated 2D nanosheets have their worthwhile applications, for example, graphene can be used to prepare conductive paper, MoS2 can be used as fluorescent label to perform cellular labelling, and BN can effectively reinforce polymers leading to the promising mechanical properties.

High-efficiency exfoliation of layered materials into 2D nanosheets in switchable CO2/Surfactant/H2O system.

PubMed

Wang, Nan; Xu, Qun; Xu, Shanshan; Qi, Yuhang; Chen, Meng; Li, Hongxiang; Han, Buxing

2015-11-16

Layered materials present attractive and important properties due to their two-dimensional (2D) structure, allowing potential applications including electronics, optoelectronics, and catalysis. However, fully exploiting the outstanding properties will require a method for their efficient exfoliation. Here we present that a series of layered materials can be successfully exfoliated into single- and few-layer nanosheets using the driving forces coming from the phase inversion, i.e., from micelles to reverse micelles in the emulsion microenvironment built by supercritical carbon dioxide (SC CO2). The effect of variable experimental parameters including CO2 pressure, ethanol/water ratio, and initial concentration of bulk materials on the exfoliation yield have been investigated. Moreover, we demonstrate that the exfoliated 2D nanosheets have their worthwhile applications, for example, graphene can be used to prepare conductive paper, MoS2 can be used as fluorescent label to perform cellular labelling, and BN can effectively reinforce polymers leading to the promising mechanical properties.

A theoretical and experimental investigation of nonlinear propagation of ultrasound through tissue mimicking media

NASA Astrophysics Data System (ADS)

Rielly, Matthew Robert

An existing numerical model (known as the Bergen code) is used to investigate finite amplitude ultrasound propagation through multiple layers of tissue-like media. This model uses a finite difference method to solve the nonlinear parabolic KZK wave equation. The code is modified to include an arbitrary frequency dependence of absorption and transmission effects for wave propagation across a plane interface at normal incidence. In addition the code is adapted to calculate the total intensity loss associated with the absorption of the fundamental and nonlinearly generated harmonics. Measurements are also taken of the axial nonlinear pressure field generated from a circular focused, 2.25 MHz source, through single and multiple layered tissue mimicking fluids, for source pressures in the range from 13 kPa to 310 kPa. Two tissue mimicking fluids are developed to provide acoustic properties similar to amniotic fluid and a typical soft tissue. The values of the nonlinearity parameter, sound velocity and frequency dependence of attenuation for both fluids are presented, and the measurement procedures employed to obtain these characteristics are described in detail. These acoustic parameters, together with the measured source conditions are used as input to the numerical model, allowing the experimental conditions to be simulated. Extensive comparisons are made between the model's predictions and the axial pressure field measurements. Results are presented in the frequency domain showing the fundamental and three subsequent harmonic amplitudes on axis, as a function of axial distance. These show that significant nonlinear distortion can occur through media with characteristics typical of tissue. Time domain waveform comparisons are also made. An excellent agreement is found between theory and experiment indicating that the model can be used to predict nonlinear ultrasound propagation through multiple layers of tissue-like media. The numerical code is also used to model the intensity loss through layered tissue mimics and results are presented illustrating the effects of altering the layered medium on the magnitude and spatial distribution of intensity loss.

Structure, Hydrodynamics, and Phase Transition of Freely Suspended Liquid Crystals

NASA Technical Reports Server (NTRS)

Clark, Noel A.

2000-01-01

Smectic liquid crystals are phases of rod shaped molecules organized into one dimensionally (1D) periodic arrays of layers, each layer being between one and two molecular lengths thick. In the least ordered smectic phases, the smectics A and C, each layer is a two dimensional (2D) liquid. Additionally there are a variety of more ordered smectic phases having hexatic short range translational order or 2D crystalline quasi long range translational order within the layers. The inherent fluid-layer structure and low vapor pressure of smectic liquid crystals enable the long term stabilization of freely suspended, single component, layered fluid films as thin as 30A, a single molecular layer. The layering forces the films to be an integral number of smectic layers thick, quantizing their thickness in layer units and forcing a film of a particular number of layers to be physically homogeneous with respect to its layer structure over its entire area. Optical reflectivity enables the precise determination of the number of layers. These ultrathin freely suspended liquid crystal films are structures of fundamental interest in condensed matter and fluid physics. They are the thinnest known stable condensed phase fluid structures and have the largest surface-to-volume ratio of any stable fluid preparation, making them ideal for the study of the effects of reduced dimensionality on phase behavior and on fluctuation and interface phenomena. Their low vapor pressure and quantized thickness enable the effective use of microgravity to extend the study of basic capillary phenomena to ultrathin fluid films. Freely suspended films have been a wellspring of new liquid crystal physics. They have been used to provide unique experimental conditions for the study of condensed phase transitions in two dimensions. They are the only system in which the hexatic has been unambiguously identified as a phase of matter, and the only physical system in which fluctuations of a 2D XY system and Kosterlitz Thouless phase transition has been observed and 2D XY quasi long range order verified. Smectic films have enabled the precise determination of smectic layer electron density and positional fluctuation profile and have been used to show that the interlayer interactions in anti-ferroelectric tilted smectics do not extend significantly beyond nearest neighbors. The interactions which are operative in liquid crystals are generally weak in comparison to those in crystalline phases, leading to the facile manipulation of the order in liquid crystals by external agents such as applied fields and surfaces. Effects arising from weak ordering are significantly enhanced in ultrathin free films and filaments wherein the intermolecular coupling is effectively reduced by loss of neighbors. Over the past four years this research, which we now detail, has produced a host of exciting new discoveries and unexpected results, maintaining the position of the study of freely suspended liquid crystal structures as one of most exciting and fruitful areas of complex fluid physics. In addition, several potentially interesting microgravity free film experiments have been identified.

On the impact of adverse pressure gradient on the supersonic turbulent boundary layer

NASA Astrophysics Data System (ADS)

Wang, Qian-Cheng; Wang, Zhen-Guo; Zhao, Yu-Xin

2016-11-01

By employing the particle image velocimetry, the mean and turbulent characteristics of a Mach 2.95 turbulent boundary layer are experimentally investigated without the impact of curvature. The physical mechanism with which the streamwise adverse pressure gradient affects the supersonic boundary layer is revealed. The data are compared to that of the concave boundary layer with similar streamwise distributions of wall static pressure to clarify the separate impacts of the adverse pressure gradient and the concave curvature. The logarithmic law is observed to be well preserved for both of the cases. The dip below the logarithmic law is not observed in present investigation. Theoretical analysis indicates that it could be the result of compromise between the opposite impacts of the compression wave and the increased turbulent intensity. Compared to the zero pressure gradient boundary layer, the principal strain rate and the turbulent intensities are increased by the adverse pressure gradient. The shear layer formed due the hairpin packets could be sharpened by the compression wave, which leads to higher principal strain rate and the associated turbulent level. Due to the additional impact of the centrifugal instability brought by the concave wall, even higher turbulent intensities than that of the adverse pressure gradient case are introduced. The existence of velocity modes within the zero pressure gradient boundary layer suggests that the large scale motions are statistically well organized. The generation of new velocity modes due to the adverse pressure gradient indicates that the turbulent structure is changed by the adverse pressure gradient, through which more turbulence production that cannot be effectively predicted by the Reynolds-stress transport equations could be brought.

Aseismic Slip of a Thin Slab Due to a Fluid Source

NASA Astrophysics Data System (ADS)

Aubin, P. W.; Viesca, R. C.

2017-12-01

We explore the effects of an increase of pore pressure on the frictional interface along the base of a thin slab. The thin slab approximation corresponds to a layer overriding a substrate in which variations along the layer's length occur over distances much greater than the layer thickness. We consider deformation that may be in-plane or anti-plane, but approximately uniform in depth, such that spatial variations of displacement (and hence, slip) occur only along one direction parallel to the interface. Such a thin-sheet model may well represent the deformation of landslides and glacial ice streams, and also serves as a first-pass for fault systems, which, while better represented by elastic half-spaces in frictional contact, nonetheless show qualitatively similar behavior. We consider that the friction coefficient at the layer's interface remains (approximately) constant, and that aseismic slip is initiated by a (line) source of fluid at constant pressure, with one-dimensional diffusion parallel to the interface. As posed, the problem yields a self-similar expansion of slip, whose extent grows proportionally to (α * t)^(1/2) (where α is the hydraulic diffusivity) and can either lag behind or outpace the fluid diffusion front. The problem is controlled by a single parameter, accounting for the friction coefficient and the initial (pre-injection) states of stress and pore pressure. The problem solution consists of the self-similar slip profile and the coefficient of proportionality for the crack-front motion. Within the problem parameter range, two end-member scenarios result: one in which the initial level of shear stress on the interface is close to the value of the pre-injection strength (critically stressed) or another in which fluid pressure is just enough to induce slip (marginally pressurized). For the critically stressed and marginally pressurized cases, the aseismic slip front lies far ahead or far behind, respectively, the fluid diffusion front. We find closed-form solutions for both end-members, and in the former case, via matched asymptotics. These solutions provide a basis to solve the general problem, which we also solve numerically for comparison. The solutions also provide a starting point for examining the progression of slip and locking following the shutoff of the fluid source.

Retrieval of ammonia abundances and cloud opacities on Jupiter from Voyager IRIS spectra

NASA Technical Reports Server (NTRS)

Conrath, B. J.; Gierasch, P. J.

1986-01-01

Gaseous ammonia abundances and cloud opacities are retrieved from Voyager IRIS 5- and 45-micron data on the basis of a simplified atmospheric model and a two-stream radiative transfer approximation, assuming a single cloud layer with 680-mbar base pressure and 0.14 gas scale height. Brightness temperature measurements obtained as a function of emission angle from selected planetary locations are used to verify the model and constrain a number of its parameters.

Frequency-domain prediction of broadband trailing edge noise from a blunt flat plate

NASA Astrophysics Data System (ADS)

Lee, Gwang-Se; Cheong, Cheolung

2013-10-01

The aim of this study is to develop an efficient methodology for frequency-domain prediction of broadband trailing edge noise from a blunt flat plate where non-zero pressure gradient may exist in its boundary layer. This is achieved in two ways: (i) by developing new models for point pressure spectra within the boundary layer over a flat plate, and (ii) by deriving a simple formula to approximate the effect of convective velocity on the radiated noise spectrum. Firstly, two types of point pressure spectra-required as input data to predict the trailing edge noise in the frequency domain-are used. One is determined using the semi-analytic (S-A) models based on the boundary-layer theory combined with existing empirical models. It is shown that the prediction using these models show good agreements with the measurements where zero-pressure gradient assumption is valid. However, the prediction show poor agreement with that obtained from large eddy simulation results where negative (favorable) pressure gradient is observed with the boundary layer. Based on boundary layer characteristics predicted using the large eddy simulations, new model for point wall pressure spectra is proposed to account for the effect of favorable pressure gradient over the blunt flat plate on the wall pressure spectra. Sound spectra that were predicted using these models are compared with measurements to validate the proposed prediction scheme. The advantage of the semi-analytic model is that it can be applied to problems at Reynolds numbers for which the empirical model is not available. In addition, it is expected that the current models can be applied to the cases where favorable pressure gradient exists in the boundary layer over a blunt flat plate. Secondly, in order to quantitatively analyze contributions of the pressure field within the turbulent boundary layer on the flat plate to trailing edge noise, total pressure over the surface of airfoil is decomposed into its two constituents: incident pressure generated in the boundary layer without a trailing edge and the pressure formed by the scattering of the incident pressure at the trailing edge. The predictions made using each of the incident and scattered pressures reveal that the convective velocity of turbulence in the boundary layer dominantly affects the radiated sound pressure spectrum, both in terms of the gross behavior of the overall acoustic pressure spectrum through the scattered pressure and in terms of the narrow band small fluctuations of the spectrum through the incident pressure. The interaction term between the incident and the scattered is defined and the incident is shown to contribute to the radiated acoustic pressure through the interaction term. Based on this finding, a simple model to effectively compute the effects of convection velocities of the turbulence on the radiated sound pressure spectrum is proposed. It is shown that the proposed method can effectively and accurately predict the broadband trailing edge noise from the plate with considering both the incident and the scattered contributions.

An Experimental Investigation of Forced Mixing of a Turbulent Boundary Layer in an Annular Diffuser. Ph.D. Thesis - Ohio State Univ.; [for boundary layer control

NASA Technical Reports Server (NTRS)

Shaw, R. J.

1979-01-01

The forced mixing process of a turbulent boundary layer in an axisymmetric annular diffuser using conventional wing-like vortex generators was studied. Flow field measurements were made at four axial locations downstream of the vortex generators. At each axial location, a total of 25 equally spaced profiles were measured behind three consecutive vortex generators which formed two pairs of vortex generators. Hot film anemometry probes measured the boundary layer turbulence structure at the same locations where pressure measurements were made. Both single and cross film probes were used. The diffuser turbulence data was teken only for a nominal inlet Mach number of 0.3. Three vortex generator configurations were tested. The differences between configurations involved changes in size and relative vortex generator positions. All three vortex generator configurations tested provided increases in diffuser performance. Distinct differences in the boundary layer integral properties and skin friction levels were noted between configurations. The axial turbulence intensity and Reynolds stress profiles measured displayed similarities in trends but differences in levels for the three configurations.

Longitudinal transvaginal ultrasound evaluation of cesarean scar niche incidence and depth in the first two years after single- or double-layer uterotomy closure: a randomized controlled trial.

PubMed

Bamberg, Christian; Hinkson, Larry; Dudenhausen, Joachim W; Bujak, Verena; Kalache, Karim D; Henrich, Wolfgang

2017-12-01

Cesarean deliveries are the most common abdominal surgery procedure globally, and the optimal way to suture the hysterotomy remains a matter of debate. The aim of this study was to assess the incidence of cesarean scar niches and the depth after single- or double-layer uterine closure. We performed a randomized controlled trial in which women were allocated to three uterotomy suture techniques: continuous single-layer unlocked, continuous locked single-layer, or double-layer sutures. Transvaginal ultrasound was performed six weeks and 6-24 months after cesarean delivery [Clinicaltrials.gov (NCT02338388)]. The study included 435 women. Six weeks after delivery, the incidence of niche was not significantly different between the groups (p = 0.52): 40% for single-layer unlocked, 32% for single-layer locked and 43% for double-layer sutures. The mean ± SD niche depths were 3.0 ± 1.4 mm for single-layer unlocked, 3.6 ± 1.7 mm for single-layer locked and 3.3 ± 1.3 mm for double-layer sutures (p = 1.0). There were no significant differences (p = 0.58) in niche incidence between the three groups at the second ultrasound follow up: 30% for single-layer unlocked, 23% for single-layer locked and 29% for double-layer sutures. The mean ± SD niche depth was 3.1 ± 1.5 mm after single-layer unlocked, 2.8 ± 1.5 mm after single-layer locked and 2.5 ± 1.2 mm after double-layer sutures (p = 0.61). There was a trend (p = 0.06) for the residual myometrium thickness to be thicker after double-layer repair at the long-term follow up. The incidence of cesarean scar niche formation and the niche depth was independent of the hysterotomy closure technique. © 2017 Nordic Federation of Societies of Obstetrics and Gynecology.

Numerical investigation of over expanded flow behavior in a single expansion ramp nozzle

NASA Astrophysics Data System (ADS)

Mousavi, Seyed Mahmood; Pourabidi, Reza; Goshtasbi-Rad, Ebrahim

2018-05-01

The single expansion ramp nozzle is severely over-expanded when the vehicle is at low speed, which hinders its ability to provide optimal configurations for combined cycle engines. The over-expansion leads to flow separation as a result of shock wave/boundary-layer interaction. Flow separation, and the presence of shocks themselves, result in a performance loss in the single expansion ramp nozzle, leading to reduced thrust and increased pressure losses. In the present work, the unsteady two dimensional compressible flow in an over expanded single expansion ramp nozzle has been investigated using finite volume code. To achieve this purpose, the Reynolds stress turbulence model and full multigrid initialization, in addition to the Smirnov's method for examining the errors accumulation, have been employed and the results are compared with available experimental data. The results show that the numerical code is capable of predicting the experimental data with high accuracy. Afterward, the effect of discontinuity jump in wall temperature as well as the length of straight ramp on flow behavior have been studied. It is concluded that variations in wall temperature and length of straight ramp change the shock wave boundary layer interaction, shock structure, shock strength as well as the distance between Lambda shocks.

Two-layer anti-reflection strategies for implant applications

NASA Astrophysics Data System (ADS)

Guerrero, Douglas J.; Smith, Tamara; Kato, Masakazu; Kimura, Shigeo; Enomoto, Tomoyuki

2006-03-01

A two-layer bottom anti-reflective coating (BARC) concept in which a layer that develops slowly is coated on top of a bottom layer that develops more rapidly was demonstrated. Development rate control was achieved by selection of crosslinker amount and BARC curing conditions. A single-layer BARC was compared with the two-layer BARC concept. The single-layer BARC does not clear out of 200-nm deep vias. When the slower developing single-layer BARC was coated on top of the faster developing layer, the vias were cleared. Lithographic evaluation of the two-layer BARC concept shows the same resolution advantages as the single-layer system. Planarization properties of a two-layer BARC system are better than for a single-layer system, when comparing the same total nominal thicknesses.

Methods and results of boundary layer measurements on a glider

NASA Technical Reports Server (NTRS)

Nes, W. V.

1978-01-01

Boundary layer measurements were carried out on a glider under natural conditions. Two effects are investigated: the effect of inconstancy of the development of static pressure within the boundary layer and the effect of the negative pressure difference in a sublaminar boundary layer. The results obtained by means of an ion probe in parallel connection confirm those results obtained by means of a pressure probe. Additional effects which have occurred during these measurements are briefly dealt with.

Conductive Polymer Synthesis with Single-Crystallinity via a Novel Plasma Polymerization Technique for Gas Sensor Applications.

PubMed

Park, Choon-Sang; Kim, Dong Ha; Shin, Bhum Jae; Kim, Do Yeob; Lee, Hyung-Kun; Tae, Heung-Sik

2016-09-30

This study proposes a new nanostructured conductive polymer synthesis method that can grow the single-crystalline high-density plasma-polymerized nanoparticle structures by enhancing the sufficient nucleation and fragmentation of the pyrrole monomer using a novel atmospheric pressure plasma jet (APPJ) technique. Transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM) results show that the plasma-polymerized pyrrole (pPPy) nanoparticles have a fast deposition rate of 0.93 µm·min -1 under a room-temperature process and have single-crystalline characteristics with porous properties. In addition, the single-crystalline high-density pPPy nanoparticle structures were successfully synthesized on the glass, plastic, and interdigitated gas sensor electrode substrates using a novel plasma polymerization technique at room temperature. To check the suitability of the active layer for the fabrication of electrochemical toxic gas sensors, the resistance variations of the pPPy nanoparticles grown on the interdigitated gas sensor electrodes were examined by doping with iodine. As a result, the proposed APPJ device could obtain the high-density and ultra-fast single-crystalline pPPy thin films for various gas sensor applications. This work will contribute to the design of highly sensitive gas sensors adopting the novel plasma-polymerized conductive polymer as new active layer.

Cloud retrievals from satellite data using optimal estimation: evaluation and application to ATSR

NASA Astrophysics Data System (ADS)

Poulsen, C. A.; Siddans, R.; Thomas, G. E.; Sayer, A. M.; Grainger, R. G.; Campmany, E.; Dean, S. M.; Arnold, C.; Watts, P. D.

2012-08-01

Clouds play an important role in balancing the Earth's radiation budget. Hence, it is vital that cloud climatologies are produced that quantify cloud macro and micro physical parameters and the associated uncertainty. In this paper, we present an algorithm ORAC (Oxford-RAL retrieval of Aerosol and Cloud) which is based on fitting a physically consistent cloud model to satellite observations simultaneously from the visible to the mid-infrared, thereby ensuring that the resulting cloud properties provide both a good representation of the short-wave and long-wave radiative effects of the observed cloud. The advantages of the optimal estimation method are that it enables rigorous error propagation and the inclusion of all measurements and any a priori information and associated errors in a rigorous mathematical framework. The algorithm provides a measure of the consistency between retrieval representation of cloud and satellite radiances. The cloud parameters retrieved are the cloud top pressure, cloud optical depth, cloud effective radius, cloud fraction and cloud phase. The algorithm can be applied to most visible/infrared satellite instruments. In this paper, we demonstrate the applicability to the Along-Track Scanning Radiometers ATSR-2 and AATSR. Examples of applying the algorithm to ATSR-2 flight data are presented and the sensitivity of the retrievals assessed, in particular the algorithm is evaluated for a number of simulated single-layer and multi-layer conditions. The algorithm was found to perform well for single-layer cloud except when the cloud was very thin; i.e., less than 1 optical depths. For the multi-layer cloud, the algorithm was robust except when the upper ice cloud layer is less than five optical depths. In these cases the retrieved cloud top pressure and cloud effective radius become a weighted average of the 2 layers. The sum of optical depth of multi-layer cloud is retrieved well until the cloud becomes thick, greater than 50 optical depths, where the cloud begins to saturate. The cost proved a good indicator of multi-layer scenarios. Both the retrieval cost and the error need to be considered together in order to evaluate the quality of the retrieval. This algorithm in the configuration described here has been applied to both ATSR-2 and AATSR visible and infrared measurements in the context of the GRAPE (Global Retrieval and cloud Product Evaluation) project to produce a 14 yr consistent record for climate research.

Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus.

PubMed

Lichtenberg, Mads; Nørregaard, Rasmus Dyrmose; Kühl, Michael

2017-03-01

The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O 2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O 2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O 2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O 2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant-microbe interactions. © 2017 The Author(s).

Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus

PubMed Central

Nørregaard, Rasmus Dyrmose

2017-01-01

The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant–microbe interactions. PMID:28330986

[Computer modeling the hydrostatic pressure characteristics of the membrane potential for polymeric membrane, separated non-homogeneous electrolyte solutions].

PubMed

Slezak, Izabella H; Jasik-Slezak, Jolanta; Rogal, Mirosława; Slezak, Andrzej

2006-01-01

On the basis of model equation depending the membrane potential deltapsis, on mechanical pressure difference (deltaP), concentration polarization coefficient (zetas), concentration Rayleigh number (RC) and ratio concentration of solutions separated by membrane (Ch/Cl), the characteristics deltapsis = f(deltaP)zetas,RC,Ch/Cl for steady values of zetas, RC and Ch/Cl in single-membrane system were calculated. In this system neutral and isotropic polymeric membrane oriented in horizontal plane, the non-homogeneous binary electrolytic solutions of various concentrations were separated. Nonhomogeneity of solutions is results from creations of the concentration boundary layers on both sides of the membrane. Calculations were made for the case where on a one side of the membrane aqueous solution of NaCl at steady concentration 10(-3) mol x l(-1) (Cl) was placed and on the other aqueous solutions of NaCl at concentrations from 10(-3) mol x l(-1) to 2 x 10(-2) mol x l(-1) (Ch). Their densities were greater than NaCl solution's at 10(-3) mol x l(-1). It was shown that membrane potential depends on hydrodynamic state of a complex concentration boundary layer-membrane-concentration boundary layer, what is controlled by deltaP, Ch/Cl, RC and zetas.

Protein deposition on field-emitter tips and its removal by UV radiation

NASA Astrophysics Data System (ADS)

Panitz, J. A.; Giaever, I.

1980-07-01

Protein deposition on field-emitter tips has been examined using Transmission Electron Microscopy to view the protein coated tip profile. A single layer of adsorbed protein is barely if at all detectable, but double and triple layers produced by the immunologic reaction can be directly observed. As a result, the thickness and morphology of antigen-antibody layers has been directly observed for the first time. Tips exposed first to Bovine Serum Albumin (BSA) and then to anti-BSA rabbit serum are covered with a reasonably uniform, double protein layer ≈130 Å thick. This layer can be built-up to a triple layer ≈275 Å thick by additional exposure to anti-rabbit IgG goat serum. Surface tension forces during the drying process which follows protein deposition appear to affect the thickness and morphology of the protein layers. The oxidation and subsequent change in the morphology of a protein layer exposed to ultraviolet radiation has also been observed using TEM. The destruction of a triple protein layer at a rate of ≈0.5 Å/s is observed for tungsten tips exposed to ≈6 W of UV radiation from a high-pressure mercury arc in laboratory ambient. These results are compared to those obtained from a simple, visual test for protein layer adsorption in which submonolayer coverages of protein can be detected with the unaided eye.

Critical pressure and multiphase flow in Blake Ridge gas hydrates

USGS Publications Warehouse

Flemings, P.B.; Liu, Xiuying; Winters, W.J.

2003-01-01

We use core porosity, consolidation experiments, pressure core sampler data, and capillary pressure measurements to predict water pressures that are 70% of the lithostatic stress, and gas pressures that equal the lithostatic stress beneath the methane hydrate layer at Ocean Drilling Program Site 997, Blake Ridge, offshore North Carolina. A 29-m-thick interconnected free-gas column is trapped beneath the low-permeability hydrate layer. We propose that lithostatic gas pressure is dilating fractures and gas is migrating through the methane hydrate layer. Overpressured gas and water within methane hydrate reservoirs limit the amount of free gas trapped and may rapidly export methane to the seafloor.

Thulium-170 heat source

DOEpatents

Walter, Carl E.; Van Konynenburg, Richard; VanSant, James H.

1992-01-01

An isotopic heat source is formed using stacks of thin individual layers of a refractory isotopic fuel, preferably thulium oxide, alternating with layers of a low atomic weight diluent, preferably graphite. The graphite serves several functions: to act as a moderator during neutron irradiation, to minimize bremsstrahlung radiation, and to facilitate heat transfer. The fuel stacks are inserted into a heat block, which is encased in a sealed, insulated and shielded structural container. Heat pipes are inserted in the heat block and contain a working fluid. The heat pipe working fluid transfers heat from the heat block to a heat exchanger for power conversion. Single phase gas pressure controls the flow of the working fluid for maximum heat exchange and to provide passive cooling.

A hot-wire surface gage for skin friction and separation detection measurements

NASA Technical Reports Server (NTRS)

Rubesin, M. W.; Okuno, A. F.; Mateer, G. G.; Brosh, A.

1975-01-01

A heated-element, skin-friction gage employing a very low thermal conductivity support is described. It is shown that the effective dimension of the gage in the stream direction in only 0.06 mm, including the effects of heat conduction in the supporting material. Because of its small size, the calibration of the gage is independent of the kind of boundary-layer flow (whether laminar or turbulent) and is insensitive to pressure gradients. Construction tolerances can be maintained so that a single universal calibration can be applied. Multiple gages, sufficiently closely spaced so as to interfere with each other, are shown to provide accurate determinations of the locations of the points of boundary-layer separation and reattachment.

Experimental measurements of the laminar separation bubble on an Eppler 387 airfoil at low Reynolds numbers

NASA Technical Reports Server (NTRS)

Cole, Gregory M.; Mueller, Thomas J.

1990-01-01

An experimental investigation was conducted to measure the flow velocity in the boundary layer of an Eppler 387 airfoil. In particular, the laminar separation bubble that this airfoil exhibits at low Reynolds numbers was the focus. Single component laser Doppler velocimetry data were obtained at a Reynolds number of 100,000 at an angle of attack of 2.0 degree. Static Pressure and flow visualization data for the Eppler 387 airfoil were also obtained. The difficulty in obtaining accurate experimental measurements at low Reynolds numbers is addressed. Laser Doppler velocimetry boundary layer data for the NACA 663-018 airfoil at a Reynolds number of 160,000 and angle of attack of 12 degree is also presented.

Epitaxial Ce and the magnetism of single-crystal Ce/Nd superlattices

NASA Astrophysics Data System (ADS)

Clegg, P. S.; Goff, J. P.; McIntyre, G. J.; Ward, R. C.; Wells, M. R.

2003-05-01

The chemical structure of epitaxial γ cerium and the chemical and magnetic structures of cerium/neodymium superlattices have been studied using x-ray and neutron diffraction techniques. The samples were grown using molecular-beam epitaxy, optimized to yield the desired Ce allotropes. The x-ray measurements show that, in the superlattices, both constituents adopt the dhcp structure and that the stacking sequence remains intact down to T˜2 K; these are the first measurements of magnetic ordering in single-crystal dhcp Ce. The magnetic structure of the superlattices with thicker Nd layers exhibit incommensurate order and ferromagnetism on separate sublattices in a similar manner to Nd under applied pressure. The sample with thickest Ce layers has a magnetic structure similar to bulk β Ce, which has commensurate transverse modulation with a propagation wave vector [1/2 0 0] and moments along the hexagonal a direction. These two types of magnetic order appear to be mutually exclusive. γ Ce is the high-temperature fcc phase of Ce, our single-phase epitaxial sample is observed to go through a new, but partial, structural transition not previously seen in the bulk material.

Large-scale synthesis of NbS2 nanosheets with controlled orientation on graphene by ambient pressure CVD.

PubMed

Ge, Wanyin; Kawahara, Kenji; Tsuji, Masaharu; Ago, Hiroki

2013-07-07

We report ambient pressure chemical vapor deposition (CVD) growth of single-crystalline NbS2 nanosheets with controlled orientation. On Si and SiO2 substrates, NbS2 nanosheets grow almost perpendicular to the substrate surface. However, when we apply transferred CVD graphene on SiO2 as a substrate, NbS2 sheets grow laterally lying on the graphene. The NbS2 sheets show the triangular and hexagonal shapes with a thickness of about 20-200 nm and several micrometres in the lateral dimension. Analyses based on X-ray diffraction and Raman spectroscopy indicate that the NbS2 nanosheets are single crystalline 3R-type with a rhombohedral structure of R3m space group. Our findings on the formation of highly aligned NbS2 nanosheets on graphene give new insight into the formation mechanism of NbS2 and would contribute to the templated growth of various layered materials.

Phosphorus atomic layer doping in Ge using RPCVD

NASA Astrophysics Data System (ADS)

Yamamoto, Yuji; Kurps, Rainer; Mai, Christian; Costina, Ioan; Murota, Junichi; Tillack, Bernd

2013-05-01

Phosphorus atomic layer doping (P-ALD) in Ge is investigated at temperatures between 100 °C and 400 °C using a single wafer reduced pressure chemical vapor deposition (RPCVD) system. Hydrogen-terminated and hydrogen-free Ge (1 0 0) surfaces are exposed to PH3 at different PH3 partial pressures after interrupting Ge growth. The adsorption and reaction of PH3 proceed on a hydrogen-free Ge surface. For all temperatures and PH3 partial pressures used for the P-ALD, the P dose increased with increasing PH3 exposure time and saturated. The saturation value of the incorporated P dose at 300 °C is ˜1.5 × 1014 cm-3, which is close to a quarter of a monolayer of the Ge (1 0 0) surface. The P dose could be simulated assuming a Langmuir-type kinetics model with a saturation value of Nt = 1.55 × 1014 cm-2 (a quarter of a monolayer), reaction rate constant kr = 77 s-1 and thermal equilibrium constant K = 3.0 × 10-2 Pa-1. An electrically active P concentration of 5-6 × 1019 cm-3, which is a 5-6 times higher thermal solubility of P in Ge, is obtained by multiple P spike fabrication using the P-ALD process.

Fitting aerodynamics and propulsion into the puzzle

NASA Technical Reports Server (NTRS)

Johnston, Patrick J.; Whitehead, Allen H., Jr.; Chapman, Gary T.

1987-01-01

The development of an airbreathing single-stage-to-orbit vehicle, in particular the problems of aerodynamics and propulsion integration, is examined. The boundary layer transition on constant pressure surfaces at hypersonic velocities, and the effects of noise on the transition are investigated. The importance of viscosity, real-gas effects, and drag at hypersonic speeds is discussed. A propulsion system with sufficient propulsive lift to enhance the performance of the vehicle is being developed. The difficulties of engine-airframe integration are analyzed.

Engine-Level Simulation of Liquid Rocket Combustion Instabilities: Transcritical Combustion Simulations in Single Injector Configurations

DTIC Science & Technology

2012-03-01

simple 1-step mechanism taking into account 4 species: CH4, O2, CO2 and H2O. Figure 2. Multiblock grid for the CVRC experiment. Left: Overall view, Right... Supercritical (and subcritical) fluid behavior and modeling: drops, streams, shear and mixing layers, jets and sprays. Progress in Energy and...hydrogen shear-coaxial jet flames at supercritical pressure. Com- bustion science and technology, 178(1-3):229–252, 2006. 12 B. E. Poling, J. M. Prausnitz

``Illuminating'' electron diffusion regions of collisionless magnetic reconnection using electron agyrotropy

NASA Astrophysics Data System (ADS)

Scudder, Jack; Daughton, William

2008-06-01

Agyrotropy is a scalar measure of the departure of the pressure tensor from cylindrical symmetry about the local magnetic field direction. Ordinarily electrons are well modeled as gyrotropic with very small agyrotropy. Intensified layers of electron agyrotropy are demonstrated to highlight the thin electron gyroradius scale boundary regions adjoining separatrices, X and O lines of full particle simulations of collisionless magnetic reconnection. Examples are presented to show these effects in antiparallel and guide field geometries, pair plasmas, and simulations at a variety of mass ratios, including a hydrogen plasma. Agyrotropy has been determined from the PIC pressure tensor using a new, fast algorithm developed to correct discreteness contributions to the apparent agyrotropy. As a local scalar diagnostic, agyrotropy is shown to be potentially useful with single spacecraft data to identify the crossing or proximity of electron scale current layers, thus providing a kinetic level diagnosis of a given layer's ability to be a possible site of the collisionless reconnection process. Such kinetic tools are certainly complimentary to the other macroscopic signatures of reconnection. Because of the extreme circumstances required for electron agyrotropy, detection of these signatures with framing macroscopic signatures might prove useful for the discovery of new reconnection sites in nature and 3-D codes of collisionless reconnection. The agyrotropy in the 2-D PIC codes reflect long-lived bulges on the distribution function that appear to be organized by the direction and size of slowly evolving perpendicular electric fields in these layers and are not consistent with gyrophase bunching.

High-pressure crystal structures of an insensitive energetic crystal: 1,1-diamino-2,2-dinitroethene

DOE PAGES

Dreger, Zbigniew A.; Stash, Adam I.; Yu, Zhi -Gang; ...

2015-12-03

Understanding the insensitivity/stability of insensitive high explosive crystals requires detailed structural information at high pressures and high temperatures of interest. Synchrotron single crystal x-ray diffraction experiments were used to determine the high-pressure structures of 1,1-diamino-2,2-dinitroethene (FOX-7), a prototypical insensitive high explosive. The phase transition around 4.5 GPa was investigated and the structures were determined at 4.27 GPa (α’-phase) and 5.9 GPa (ε-phase). The α’-phase (monoclinic, P2 1/ n), structurally indistinguishable from the ambient α-phase, transforms to the new ε-phase (triclinic, P1). The most notable features of the ε-phase, compared to the α’-phase, are: formation of planar layers and flattening ofmore » molecules. Density functional theory (DFT-D2) calculations complemented the experimental results. Furthermore, the results presented here are important for understanding the molecular and crystalline attributes governing the high-pressure insensitivity/stability of insensitive high explosive crystals.« less

High-pressure crystal structures of an insensitive energetic crystal: 1,1-diamino-2,2-dinitroethene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dreger, Zbigniew A.; Stash, Adam I.; Yu, Zhi -Gang

Understanding the insensitivity/stability of insensitive high explosive crystals requires detailed structural information at high pressures and high temperatures of interest. Synchrotron single crystal x-ray diffraction experiments were used to determine the high-pressure structures of 1,1-diamino-2,2-dinitroethene (FOX-7), a prototypical insensitive high explosive. The phase transition around 4.5 GPa was investigated and the structures were determined at 4.27 GPa (α’-phase) and 5.9 GPa (ε-phase). The α’-phase (monoclinic, P2 1/ n), structurally indistinguishable from the ambient α-phase, transforms to the new ε-phase (triclinic, P1). The most notable features of the ε-phase, compared to the α’-phase, are: formation of planar layers and flattening ofmore » molecules. Density functional theory (DFT-D2) calculations complemented the experimental results. Furthermore, the results presented here are important for understanding the molecular and crystalline attributes governing the high-pressure insensitivity/stability of insensitive high explosive crystals.« less

Pressure-actuated joint system

NASA Technical Reports Server (NTRS)

McGuire, John R. (Inventor)

2004-01-01

A pressure vessel is provided that includes first and second case segments mated with one another. First and second annular rubber layers are disposed inboard of the first and second case segments, respectively. The second annular rubber layer has a slot extending from the radial inner surface across a portion of its thickness to define a main body portion and a flexible portion. The flexible portion has an interfacing surface portion abutting against an interfacing surface portion of the first annular rubber layer to follow movement of the first annular rubber layer during operation of the pressure vessel. The slot receives pressurized gas and establishes a pressure-actuated joint between the interfacing surface portions. At least one of the interfacing surface portions has a plurality of enclosed and sealed recesses formed therein.

High-pressure behaviour of Cs{sub 2}V{sub 3}O{sub 8} fresnoite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grzechnik, Andrzej, E-mail: grzechnik@xtal.rwth-aachen.de; Yeon, Jeongho; Zur Loye, Hans-Conrad

2016-06-15

Crystal structure of Cs{sub 2}V{sub 3}O{sub 8} fresnoite (P4bm, Z=2) has been studied using single-crystal X-ray diffraction in a diamond anvil cell to 8.6 GPa at room temperature. Cs{sub 2}V{sub 3}O{sub 8} undergoes a reversible first-order phase transition at about 4 GPa associated with anomalies in the pressure dependencies of the lattice parameters and unit-cell volume but without any symmetry change. Both structures consist of layers of corner-sharing V{sup 5+}O{sub 4} tetrahedra and V{sup 4+}O{sub 5} tetragonal pyramids separated by the Cs{sup +} cations located between the layers. At low pressures, the compression has little effect on the polarity ofmore » the structure. Above 4 GPa, the pseudosymmetry with respect to the corresponding centrosymmetric space group P4/mbm abruptly increases. The effects of external pressure and of the A{sup +} cation substitution in the vanadate fresnoites A{sub 2}V{sub 3}O{sub 8} (A{sup +}: K{sup +}, Rb{sup +}, NH{sub 4}{sup +}, Cs{sup +}) are discussed. - Graphical abstract: Non-centrosymmetric Cs{sub 2}V{sub 3}O{sub 8} undergoes a reversible first-order phase transition at about 4 GPa associated with an abrupt change of the pseudosymmetry with respect to the centrosymmetric space group P4/mbm. Display Omitted - Highlights: • High-pressure behaviour of vanadate fresnoites depends on alkali metal cations. • The size of the alkali metal cation determines whether the high-pressure phase is centrosymmetric. • No incommensurate structures are observed upon compression.« less

An SOI CMOS-Based Multi-Sensor MEMS Chip for Fluidic Applications.

PubMed

Mansoor, Mohtashim; Haneef, Ibraheem; Akhtar, Suhail; Rafiq, Muhammad Aftab; De Luca, Andrea; Ali, Syed Zeeshan; Udrea, Florin

2016-11-04

An SOI CMOS multi-sensor MEMS chip, which can simultaneously measure temperature, pressure and flow rate, has been reported. The multi-sensor chip has been designed keeping in view the requirements of researchers interested in experimental fluid dynamics. The chip contains ten thermodiodes (temperature sensors), a piezoresistive-type pressure sensor and nine hot film-based flow rate sensors fabricated within the oxide layer of the SOI wafers. The silicon dioxide layers with embedded sensors are relieved from the substrate as membranes with the help of a single DRIE step after chip fabrication from a commercial CMOS foundry. Very dense sensor packing per unit area of the chip has been enabled by using technologies/processes like SOI, CMOS and DRIE. Independent apparatuses were used for the characterization of each sensor. With a drive current of 10 µA-0.1 µA, the thermodiodes exhibited sensitivities of 1.41 mV/°C-1.79 mV/°C in the range 20-300 °C. The sensitivity of the pressure sensor was 0.0686 mV/(V excit kPa) with a non-linearity of 0.25% between 0 and 69 kPa above ambient pressure. Packaged in a micro-channel, the flow rate sensor has a linearized sensitivity of 17.3 mV/(L/min) -0.1 in the tested range of 0-4.7 L/min. The multi-sensor chip can be used for simultaneous measurement of fluid pressure, temperature and flow rate in fluidic experiments and aerospace/automotive/biomedical/process industries.

An SOI CMOS-Based Multi-Sensor MEMS Chip for Fluidic Applications †

PubMed Central

Mansoor, Mohtashim; Haneef, Ibraheem; Akhtar, Suhail; Rafiq, Muhammad Aftab; De Luca, Andrea; Ali, Syed Zeeshan; Udrea, Florin

2016-01-01

An SOI CMOS multi-sensor MEMS chip, which can simultaneously measure temperature, pressure and flow rate, has been reported. The multi-sensor chip has been designed keeping in view the requirements of researchers interested in experimental fluid dynamics. The chip contains ten thermodiodes (temperature sensors), a piezoresistive-type pressure sensor and nine hot film-based flow rate sensors fabricated within the oxide layer of the SOI wafers. The silicon dioxide layers with embedded sensors are relieved from the substrate as membranes with the help of a single DRIE step after chip fabrication from a commercial CMOS foundry. Very dense sensor packing per unit area of the chip has been enabled by using technologies/processes like SOI, CMOS and DRIE. Independent apparatuses were used for the characterization of each sensor. With a drive current of 10 µA–0.1 µA, the thermodiodes exhibited sensitivities of 1.41 mV/°C–1.79 mV/°C in the range 20–300 °C. The sensitivity of the pressure sensor was 0.0686 mV/(Vexcit kPa) with a non-linearity of 0.25% between 0 and 69 kPa above ambient pressure. Packaged in a micro-channel, the flow rate sensor has a linearized sensitivity of 17.3 mV/(L/min)−0.1 in the tested range of 0–4.7 L/min. The multi-sensor chip can be used for simultaneous measurement of fluid pressure, temperature and flow rate in fluidic experiments and aerospace/automotive/biomedical/process industries. PMID:27827904

Compression stockings for treating venous leg ulcers: measurement of interface pressure under a new ulcer kit.

PubMed

Partsch, B; Partsch, H

2008-01-01

The aim of this study was to measure the interface pressure of a newly designed two-layer compression stocking (Mediven ulcer kit Medi QMBH, Bayreuth, Germany) in different body positions and to compare the values with those obtained with another two-layer product. Interface pressure was measured on the distal medial leg in 16 legs of volunteers, with the basic layer alone and with the whole stocking kit in the supine, sitting and standing position for both stocking systems. The literature concerning ulcer-healing rates is reviewed. Mediven ulcerkit produced statistically significant higher pressure values than the ulcer stocking with a median resting value of 35.5 mmHg in the supine and 42.5 mmHg in the standing position. The pressure while standing comes close to values exerted by bandages. The basic layer alone applies a pressure of 20.5 mmHg. Especially designed compression stockings exerting sufficient interface pressure may be indicated in patients with small ulcers of short duration.

Pressure gradient effects on heat transfer to reusable surface insulation tile-array gaps

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.

1975-01-01

An experimental investigation was performed to determine the effect of pressure gradient on the heat transfer within space shuttle reusable surface insulation (RSI) tile-array gaps under thick, turbulent boundary-layer conditions. Heat-transfer and pressure measurements were obtained on a curved array of full-scale simulated RSI tiles in a tunnel-wall boundary layer at a nominal free-stream Mach number and free-stream Reynolds numbers. Transverse pressure gradients of varying degree were induced over the model surface by rotating the curved array with respect to the flow. Definition of the tunnel-wall boundary-layer flow was obtained by measurement of boundary-layer pitot pressure profiles, wall pressure, and heat transfer. Flat-plate heat-transfer data were correlated and a method was derived for prediction of heat transfer to a smooth curved surface in the highly three-dimensional tunnel-wall boundary-layer flow. Pressure on the floor of the RSI tile-array gap followed the trends of the external surface pressure. Heat transfer to the surface immediately downstream of a transverse gap is higher than that for a smooth surface at the same location. Heating to the wall of a transverse gap, and immediately downstream of it, at its intersection with a longitudinal gap is significantly greater than that for the simple transverse gap.

The effects of inlet turbulence and rotor/stator interactions on the aerodynamics and heat transfer of a large-scale rotating turbine model. Part 4: Aerodynamic data tabulation

NASA Technical Reports Server (NTRS)

Dring, R. P.; Joslyn, H. D.; Blair, M. F.

1987-01-01

A combined experimental and analytical program was conducted to examine the effects of inlet turbulence and airfoil heat transfer. The experimental portion of the study was conducted in a large-scale (approx. 5X engine), ambient temperature, rotating turbine model configured in both single-stage and stage-and-a-half arrangements. Heat transfer measurements were obtained using low-conductivity airfoils with miniature thermocouples welded to a thin, electrically heated surface skin. Heat transfer data were acquired for various combinations of low or high inlet turbulence intensity, flow coefficient, first stator-rotor axial spacing, Reynolds number and relative circumferential position of the first and second stators. Aerodynamic measurements obtained include distributions of the mean and fluctuating velocities at the turbine inlet and, for each airfoil row, midspan airfoil surface pressures and circumferential distributions of the downstream steady state pressures and fluctuating velocities. Results include airfoil heat transfer predictions produced using existing 2-D boundary layer computation schemes and an examination of solutions of the unsteady boundary layer equations.

Effect of fibril shape on adhesive properties

NASA Astrophysics Data System (ADS)

Soto, Daniel; Hill, Ginel; Parness, Aaron; Esparza, Noé; Cutkosky, Mark; Kenny, Tom

2010-08-01

Research into the gecko's adhesive system revealed a unique architecture for adhesives using tiny hairs. By using a stiff material (β-keratin) to create a highly structured adhesive, the gecko's system demonstrates properties not seen in traditional pressure-sensitive adhesives which use a soft, unstructured planar layer. In contrast to pressure sensitive adhesives, the gecko adhesive displays frictional adhesion, in which increased shear force allows it to withstand higher normal loads. Synthetic fibrillar adhesives have been fabricated but not all demonstrate this frictional adhesion property. Here we report the dual-axis force testing of single silicone rubber pillars from synthetic adhesive arrays. We find that the shape of the adhesive pillar dictates whether frictional adhesion or pressure-sensitive behavior is observed. This work suggests that both types of behavior can be achieved with structures much larger than gecko terminal structures. It also indicates that subtle differences in the shape of these pillars can significantly influence their properties.

Geometry of α-Cr2O3(0001) as a Function of H2O Partial Pressure

PubMed Central

2015-01-01

Surface X-ray diffraction has been employed to elucidate the surface structure of α-Cr2O3(0001) as a function of water partial pressure at room temperature. In ultra high vacuum, following exposure to ∼2000 Langmuir of H2O, the surface is found to be terminated by a partially occupied double layer of chromium atoms. No evidence of adsorbed OH/H2O is found, which is likely due to either adsorption at minority sites, or X-ray induced desorption. At a water partial pressure of ∼30 mbar, a single OH/H2O species is found to be bound atop each surface Cr atom. This adsorption geometry does not agree with that predicted by ab initio calculations, which may be a result of some differences between the experimental conditions and those modeled. PMID:26877825

Regenerator cross arm seal assembly

DOEpatents

Jackman, Anthony V.

1988-01-01

A seal assembly for disposition between a cross arm on a gas turbine engine block and a regenerator disc, the seal assembly including a platform coextensive with the cross arm, a seal and wear layer sealingly and slidingly engaging the regenerator disc, a porous and compliant support layer between the platform and the seal and wear layer porous enough to permit flow of cooling air therethrough and compliant to accommodate relative thermal growth and distortion, a dike between the seal and wear layer and the platform for preventing cross flow through the support layer between engine exhaust and pressurized air passages, and air diversion passages for directing unregenerated pressurized air through the support layer to cool the seal and wear layer and then back into the flow of regenerated pressurized air.

Optimization of bump and blowing to control the flow through a transonic compressor blade cascade

NASA Astrophysics Data System (ADS)

Mazaheri, K.; Khatibirad, S.

2018-03-01

Shock control bump (SCB) and blowing are two flow control methods, used here to improve the aerodynamic performance of transonic compressors. Both methods are applied to a NASA rotor 67 blade section and are optimized to minimize the total pressure loss. A continuous adjoint algorithm is used for multi-point optimization of a SCB to improve the aerodynamic performance of the rotor blade section, for a range of operational conditions around its design point. A multi-point and two single-point optimizations are performed in the design and off-design conditions. It is shown that the single-point optimized shapes have the best performance for their respective operating conditions, but the multi-point one has an overall better performance over the whole operating range. An analysis is given regarding how similarly both single- and multi-point optimized SCBs change the wave structure between blade sections resulting in a more favorable flow pattern. Interactions of the SCB with the boundary layer and the wave structure, and its effects on the separation regions are also studied. We have also introduced the concept of blowing for control of shock wave and boundary-layer interaction. A geometrical model is introduced, and the geometrical and physical parameters of blowing are optimized at the design point. The performance improvements of blowing are compared with the SCB. The physical interactions of SCB with the boundary layer and the shock wave are analyzed. The effects of SCB on the wave structure in the flow domain outside the boundary-layer region are investigated. It is shown that the effects of the blowing mechanism are very similar to the SCB.

Adsorption of lysozyme to phospholipid and meibomian lipid monolayer films.

PubMed

Mudgil, Poonam; Torres, Margaux; Millar, Thomas J

2006-03-15

It is believed that a lipid layer forms the outer layer of the pre-ocular tear film and this layer helps maintain tear film stability by lowering its surface tension. Proteins of the aqueous layer of the tear film (beneath the lipid layer) may also contribute to reducing surface tension by adsorbing to, or penetrating the lipid layer. The purpose of this study was to compare the penetration of lysozyme, a tear protein, into films of meibomian lipids and phospholipids held at different surface pressures to determine if lysozyme were part of the surface layer of the tear film. Films of meibomian lipids or phospholipids were spread onto the surface of a buffered aqueous subphase. Films were compressed to particular pressures and lysozyme was injected into the subphase. Changes in surface pressure were monitored to determine adsorption or penetration of lysozyme into the surface film. Lysozyme penetrated a meibomian lipid film at all pressures tested (max=20 mN/m). It also penetrated phosphatidylglycerol, phosphatidylserine or phosphatidylethanolamine lipid films up to a pressure of 20 mN/m. It was not able to penetrate a phosphatidylcholine film at pressures >or=10 mN/m irrespective of the temperature being at 20 or 37 degrees C. However, it was able to penetrate it at very low pressures (<10 mN/m). Epifluorescence microscopy showed that the protein either adsorbs to or penetrates the lipid layer and the pattern of mixing depended upon the lipid at the surface. These results indicate that lysozyme is present at the surface of the tear film where it contributes to decreasing the surface tension by adsorbing and penetrating the meibomian lipids. Thus it helps to stabilize the tear film.

Joining of polypropylene/polypropylene and glass fiber reinforced polypropylene composites

NASA Astrophysics Data System (ADS)

Zhang, Jianguang

Joining behavior of polypropylene (PP) to PP and long glass fiber reinforced polypropylene (LFT) to LFT were investigated. Adhesive bonding was used to join PP/PP. Both adhesive bonding and ultrasonic welding were used to join LFT/LFT. Single-lap shear testing and low velocity impact (LVI) testing were used to evaluate the performance of bonded structures. The two-part acrylic adhesive DP8005 was determined to be the best among the three adhesive candidates, which was attributed to its low surface energy. The impact resistance of LFT/LFT joints, normalized with respect to thickness, was higher than that of PP/PP joints because of higher stiffness of LFT/LFT joints. The stress states in the adhesive layer of adhesively bonded structures were analyzed using ANSYS and LS-DYNA to simulate the single-lap shear testing and LVI testing, respectively. The shear and peel stresses peaked at the edges of the adhesive layer. Compared to LFT/LFT joints, higher peel stress occurred in the adhesive layer in the PP/PP joints in tension. Impact response of adhesively bonded structures as evaluated by LS-DYNA showed good agreement with the experimental results. The effect of weld time and weld pressure on the shear strength of ultrasonically welded LFT/LFT was evaluated. With higher weld pressure, less time was required to obtain a complete weld. At longer weld times, lower weld pressure was required. From the 15 weld conditions studied, a weld map was obtained that provides conditions to achieve a complete weld. Nanoindentation was used to evaluate the effect of ultrasonic weld on the modulus and hardness of the PP matrix. Modulus and hardness of the PP matrix were slightly decreased by ultrasonic welding possibly due to the decrease in the molecular weight. The temperature profile in LFT/LFT in the transverse direction during ultrasonic welding was analyzed by two ANSYS-based thermal models: (a) one in which heat generated by interfacial friction was treated as a heat flux and (b) one in which heat was generated in a thin slab at the interface. The weld map obtained from the thin slab model was closer to the one obtained experimentally.

Percolation in a Proton Exchange Membrane Fuel Cell Catalyst Layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stacy, Stephen; Allen, Jeffrey

Water management in the catalyst layers of proton exchange membrane fuel cells (PEMFC) is confronted by two issues, flooding and dry out, both of which result in improper functioning of the fuel cell and lead to poor performance and degradation. At the present time, the data that has been reported about water percolation and wettability within a fuel cell catalyst layer is limited. A method and apparatus for measuring the percolation pressure in the catalyst layer has been developed based upon an experimental apparatus used to test water percolation in porous transport layers (PTL). The experimental setup uses a pseudomore » Hele-Shaw type testing where samples are compressed and a fluid is injected into the sample. Testing the samples gives percolation pressure plots which show trends in increasing percolation pressure with an increase in flow rate. A decrease in pressure was seen as percolation occurred in one sample, however the pressure only had a rising effect in the other sample.« less

Pressure induced metallization with absence of structural transition in layered molybdenum diselenide

PubMed Central

Zhao, Zhao; Zhang, Haijun; Yuan, Hongtao; Wang, Shibing; Lin, Yu; Zeng, Qiaoshi; Xu, Gang; Liu, Zhenxian; Solanki, G. K.; Patel, K. D.; Cui, Yi; Hwang, Harold Y.; Mao, Wendy L.

2015-01-01

Layered transition-metal dichalcogenides have emerged as exciting material systems with atomically thin geometries and unique electronic properties. Pressure is a powerful tool for continuously tuning their crystal and electronic structures away from the pristine states. Here, we systematically investigated the pressurized behavior of MoSe2 up to ∼60 GPa using multiple experimental techniques and ab-initio calculations. MoSe2 evolves from an anisotropic two-dimensional layered network to a three-dimensional structure without a structural transition, which is a complete contrast to MoS2. The role of the chalcogenide anions in stabilizing different layered patterns is underscored by our layer sliding calculations. MoSe2 possesses highly tunable transport properties under pressure, determined by the gradual narrowing of its band-gap followed by metallization. The continuous tuning of its electronic structure and band-gap in the range of visible light to infrared suggest possible energy-variable optoelectronics applications in pressurized transition-metal dichalcogenides. PMID:26088416

Pressure induced metallization with absence of structural transition in layered molybdenum diselenide

DOE PAGES

Zhao, Zhao; Zhang, Haijun; Yuan, Hongtao; ...

2015-06-19

Layered transition-metal dichalcogenides have emerged as exciting material systems with atomically thin geometries and unique electronic properties. Pressure is a powerful tool for continuously tuning their crystal and electronic structures away from the pristine states. Here, we systematically investigated the pressurized behavior of MoSe 2 up to ~60 GPa using multiple experimental techniques and ab-initio calculations. MoSe 2 evolves from an anisotropic two-dimensional layered network to a three-dimensional structure without a structural transition, which is a complete contrast to MoS 2. The role of the chalcogenide anions in stabilizing different layered patterns is underscored by our layer sliding calculations. MoSemore » 2 possesses highly tunable transport properties under pressure, determined by the gradual narrowing of its band-gap followed by metallization. The continuous tuning of its electronic structure and band-gap in the range of visible light to infrared suggest possible energy-variable optoelectronics applications in pressurized transition-metal dichalcogenides.« less

Skin-Friction Measurements at Subsonic and Transonic Mach Numbers with Embedded-Wire Gages

DTIC Science & Technology

1981-01-01

Model ................................... 17 9. Boundary-Layer Rake Installation on EBOR Model...boundary-layer total pressure rake eliminates this bulky mechanism and the long data acquisition time, but it introduces interferences which affect the...its construction. Further, boundary-layer rakes are restricted to measurements in thick boundary layers. Surface pressure probes such as Stanton tubes

Probabilistic description of ice-supersaturated layers in low resolution profiles of relative humidity

NASA Astrophysics Data System (ADS)

Dickson, N. C.; Gierens, K. M.; Rogers, H. L.; Jones, R. L.

2010-02-01

The global observation, assimilation and prediction in numerical models of ice super-saturated (ISS) regions (ISSR) are crucial if the climate impact of aircraft condensations trails (contrails) is to be fully understood, and if, for example, contrail formation is to be avoided through aircraft operational measures. A robust assessment of the global distribution of ISSR will further this debate, and ISS event occurrence, frequency and spatial scales have recently attracted significant attention. The mean horizontal path length through ISSR as observed by MOZAIC aircraft is 150 km (±250 km). The average vertical thickness of ISS layers is 600-800 m (±575 m) but layers ranging from 25 m to 3000 m have been observed, with up to one third of ISS layers thought to be less than 100 m deep. Given their small scales compared to typical atmospheric model grid sizes, statistical representations of the spatial scales of ISSR are required, in both horizontal and vertical dimensions, if global occurrence of ISSR is to be adequately represented in climate models. This paper uses radiosonde launches made by the UK Meteorological Office, from the British Isles, Gibraltar, St. Helena and the Falkland Islands between January 2002 and December 2006, to investigate the probabilistic occurrence of ISSR. Specifically each radiosonde profile is divided into 50- and 100-hPa pressure layers, to emulate the coarse vertical resolution of some atmospheric models. Then the high resolution observations contained within each thick pressure layer are used to calculate an average relative humidity and an ISS fraction for each individual thick pressure layer. These relative humidity pressure layer descriptions are then linked through a probability function to produce an s-shaped curve describing the ISS fraction in any average relative humidity pressure layer. An empirical investigation has shown that this one curve is statistically valid for mid-latitude locations, irrespective of season and altitude, however, pressure layer depth is an important variable. Using this empirical understanding of the s-shaped relationship a mathematical model was developed to represent the ISS fraction within any arbitrary thick pressure layer. Here the statistical distributions of actual high resolution RHi observations in any thick pressure layer, along with an error function, are used to mathematically describe the s-shape. Two models were developed to represent both 50- and 100-hPa pressure layers with each reconstructing their respective s-shapes within 8-10% of the empirical curves. These new models can be used, to represent the small scale structures of ISS events, in modelled data where only low vertical resolution is available. This will be useful in understanding, and improving the global distribution, both observed and forecasted, of ice super-saturation.

A Prospective Randomized Clinical Trial of Single vs. Double Layer Closure of Hysterotomy at the Time of Cesarean Delivery: The Effect on Uterine Scar Thickness.

PubMed

Bamberg, Christian; Dudenhausen, Joachim W; Bujak, Verena; Rodekamp, Elke; Brauer, Martin; Hinkson, Larry; Kalache, Karim; Henrich, Wolfgang

2018-06-01

 We undertook a randomized clinical trial to examine the outcome of a single vs. a double layer uterine closure using ultrasound to assess uterine scar thickness.  Participating women were allocated to one of three uterotomy suture techniques: continuous single layer unlocked suturing, continuous locked single layer suturing, or double layer suturing. Transvaginal ultrasound of uterine scar thickness was performed 6 weeks and 6 - 24 months after Cesarean delivery. Sonographers were blinded to the closure technique.  An "intent-to-treat" and "as treated" ANOVA analysis included 435 patients (n = 149 single layer unlocked suturing, n = 157 single layer locked suturing, and n = 129 double layer suturing). 6 weeks postpartum, the median scar thickness did not differ among the three groups: 10.0 (8.5 - 12.3 mm) single layer unlocked vs. 10.1 (8.2 - 12.7 mm) single layer locked vs. 10.8 (8.1 - 12.8 mm) double layer; (p = 0.84). At the time of the second follow-up, the uterine scar was not significantly (p = 0.06) thicker if the uterus had been closed with a double layer closure 7.3 (5.7 - 9.1 mm), compared to single layer unlocked 6.4 (5.0 - 8.8 mm) or locked suturing techniques 6.8 (5.2 - 8.7 mm). Women who underwent primary or elective Cesarean delivery showed a significantly (p = 0.03, p = 0.02, "as treated") increased median scar thickness after double layer closure vs. single layer unlocked suture.  A double layer closure of the hysterotomy is associated with a thicker myometrium scar only in primary or elective Cesarean delivery patients. © Georg Thieme Verlag KG Stuttgart · New York.

Formation of hexagonal and cubic ice during low-temperature growth

PubMed Central

Thürmer, Konrad; Nie, Shu

2013-01-01

From our daily life we are familiar with hexagonal ice, but at very low temperature ice can exist in a different structure––that of cubic ice. Seeking to unravel the enigmatic relationship between these two low-pressure phases, we examined their formation on a Pt(111) substrate at low temperatures with scanning tunneling microscopy and atomic force microscopy. After completion of the one-molecule-thick wetting layer, 3D clusters of hexagonal ice grow via layer nucleation. The coalescence of these clusters creates a rich scenario of domain-boundary and screw-dislocation formation. We discovered that during subsequent growth, domain boundaries are replaced by growth spirals around screw dislocations, and that the nature of these spirals determines whether ice adopts the cubic or the hexagonal structure. Initially, most of these spirals are single, i.e., they host a screw dislocation with a Burgers vector connecting neighboring molecular planes, and produce cubic ice. Films thicker than ∼20 nm, however, are dominated by double spirals. Their abundance is surprising because they require a Burgers vector spanning two molecular-layer spacings, distorting the crystal lattice to a larger extent. We propose that these double spirals grow at the expense of the initially more common single spirals for an energetic reason: they produce hexagonal ice. PMID:23818592

Method and apparatus for producing composites of materials exhibiting thermoplastic properties

DOEpatents

Garvey, Raymond E.; Grostick, Edmund T.

1992-01-01

A mobile device for the complete consolidation of layers of material which exhibit thermoplastic properties for the formation of a composite of the layers upon a complex contoured substrate. The principal of the device is to provide heating into the molten temperature range of the thermoplastic material, applying sufficient pressure to the layers to cause flow of the plastic for a time sufficient to achieve full consolidation of the layers, and quickly cooling the structure to prevent delamination or other non-consolidation action. In the preferred form, there is an element to deposit a layer of the mateiral against another layer in close proximity. The two layers are pre-heated to near the melting temperature, and then further heated into the melting temperature range as they are brought into intimate contact with sufficient pressure to cause flow of the plastic for a time sufficient to achieve the full consolidation. The structure is then cooled. The mechanism for the application of pressure is selected such that the layers can be deformed to conform to a complex contour. In the preferred form, this pressurization is produced using a compliant hood that supplies both the pressure and at least a portion of the melting temperature, as well as the cooling. The apparatus, and method of operation, are described relative to the use of fiber-reinforced PEEK in the making of fully-consolidated composites. Other applications are discussed.

Casimir Pressure in Mds-Structures

NASA Astrophysics Data System (ADS)

Yurova, V. A.; Bukina, M. N.; Churkin, Yu. V.; Fedortsov, A. B.; Klimchitskaya, G. L.

2012-07-01

The Casimir pressure on the dielectric layer in metal-dielectric-semiconductor (MDS) structures is calculated in the framework of the Lifshitz theory at nonzero temperature. In this calculation the standard parameters of semiconductor devices with a thin dielectric layer are used. We consider the thickness of a layer decreasing from 40 to 1 nm. At the shortest thickness the Casimir pressure achieves 8 MPa. At small thicknesses the results are compared with the predictions of nonrelativistic theory.

Weak incident shock interactions with Mach 8 laminar boundary layers. [of flat plate

NASA Technical Reports Server (NTRS)

Kaufman, L. G., II; Johnson, C. B.

1974-01-01

Weak shock-wave interactions with boundary layers on a flat plate were investigated experimentally in Mach 8 variable-density tunnel for plate-length Reynolds numbers. The undisturbed boundary layers were laminar over the entire plate length. Pressure and heat-transfer distributions were obtained for wedge-generated incident shock waves that resulted in pressure rises ranging from 1.36 to 4.46 (both nonseparated and separated boundary-layer flows). The resulting heat-transfer amplifications ranged from 1.45 to 14. The distributions followed established trends for nonseparated flows, for incipient separation, and for laminar free-interaction pressure rises. The experimental results corroborated established trends for the extent of the pressure rise and for certain peak heat-transfer correlations.

High-Q Wafer Level Package Based on Modified Tri-Layer Anodic Bonding and High Performance Getter and Its Evaluation for Micro Resonant Pressure Sensor.

PubMed

Wang, Liying; Du, Xiaohui; Wang, Lingyun; Xu, Zhanhao; Zhang, Chenying; Gu, Dandan

2017-03-16

In order to achieve and maintain a high quality factor (high-Q) for the micro resonant pressure sensor, this paper presents a new wafer level package by adopting cross-layer anodic bonding technique of the glass/silicon/silica (GSS) stackable structure and integrated Ti getter. A double-layer structure similar to a silicon-on-insulator (SOI) wafer is formed after the resonant layer and the pressure-sensitive layer are bonded by silicon direct bonding (SDB). In order to form good bonding quality between the pressure-sensitive layer and the glass cap layer, the cross-layer anodic bonding technique is proposed for vacuum package by sputtering Aluminum (Al) on the combination wafer of the pressure-sensitive layer and the resonant layer to achieve electrical interconnection. The model and the bonding effect of this technique are discussed. In addition, in order to enhance the performance of titanium (Ti) getter, the prepared and activation parameters of Ti getter under different sputtering conditions are optimized and discussed. Based on the optimized results, the Ti getter (thickness of 300 nm to 500 nm) is also deposited on the inside of the glass groove by magnetron sputtering to maintain stable quality factor (Q). The Q test of the built testing system shows that the number of resonators with a Q value of more than 10,000 accounts for more than 73% of the total. With an interval of 1.5 years, the Q value of the samples remains almost constant. It proves the proposed cross-layer anodic bonding and getter technique can realize high-Q resonant structure for long-term stable operation.

Measurements in the near-wall region of a relaxing three-dimensional low speed turbulent air boundary layer

NASA Technical Reports Server (NTRS)

Hebbar, K. S.; Melnik, W. L.

1976-01-01

An experimental investigation was conducted at selected locations of the near-wall region of a three dimensional turbulent air boundary layer relaxing in a nominally zero external pressure gradient behind a transverse hump (in the form of a 30 deg swept, 5-foot chord wing-type model) faired into the side wall of a low speed wind tunnel. Wall shear stresses measured with a flush-mounted hot-film gage and a sublayer fence were in very good agreement with experimental data obtained with two Preston probes. With the upstream unit Reynolds number held constant at 325,000/ft. approximately one-fourth of the boundary layer thickness adjacent to the wall was surveyed with a single rotated hot-wire probe mounted on a specially designed minimum interference traverse mechanism. The boundary layer (approximately 3.5 in thick near the first survey station where the length Reynolds number was 5.5 million) had a maximum crossflow velocity ratio of 0.145 and a maximum crossflow angle of 21.875 deg close to the wall.

Selective-area catalyst-free MBE growth of GaN nanowires using a patterned oxide layer.

PubMed

Schumann, T; Gotschke, T; Limbach, F; Stoica, T; Calarco, R

2011-03-04

GaN nanowires (NWs) were grown selectively in holes of a patterned silicon oxide mask, by rf-plasma-assisted molecular beam epitaxy (PAMBE), without any metal catalyst. The oxide was deposited on a thin AlN buffer layer previously grown on a Si(111) substrate. Regular arrays of holes in the oxide layer were obtained using standard e-beam lithography. The selectivity of growth has been studied varying the substrate temperature, gallium beam equivalent pressure and patterning layout. Adjusting the growth parameters, GaN NWs can be selectively grown in the holes of the patterned oxide with complete suppression of the parasitic growth in between the holes. The occupation probability of a hole with a single or multiple NWs depends strongly on its diameter. The selectively grown GaN NWs have one common crystallographic orientation with respect to the Si(111) substrate via the AlN buffer layer, as proven by x-ray diffraction (XRD) measurements. Based on the experimental data, we present a schematic model of the GaN NW formation in which a GaN pedestal is initially grown in the hole.

Synthesis of Large and Few Atomic Layers of Hexagonal Boron Nitride on Melted Copper

PubMed Central

Khan, Majharul Haque; Huang, Zhenguo; Xiao, Feng; Casillas, Gilberto; Chen, Zhixin; Molino, Paul J.; Liu, Hua Kun

2015-01-01

Hexagonal boron nitride nanosheets (h-BNNS) have been proposed as an ideal substrate for graphene-based electronic devices, but the synthesis of large and homogeneous h-BNNS is still challenging. In this contribution, we report a facile synthesis of few-layer h-BNNS on melted copper via an atmospheric pressure chemical vapor deposition process. Comparative studies confirm the advantage of using melted copper over solid copper as a catalyst substrate. The former leads to the formation of single crystalline h-BNNS that is several microns in size and mostly in mono- and bi-layer forms, in contrast to the polycrystalline and mixed multiple layers (1–10) yielded by the latter. This difference is likely to be due to the significantly reduced and uniformly distributed nucleation sites on the smooth melted surface, in contrast to the large amounts of unevenly distributed nucleation sites that are associated with grain boundaries and other defects on the solid surface. This synthesis is expected to contribute to the development of large-scale manufacturing of h-BNNS/graphene-based electronics. PMID:25582557

Synthesis of large and few atomic layers of hexagonal boron nitride on melted copper.

PubMed

Khan, Majharul Haque; Huang, Zhenguo; Xiao, Feng; Casillas, Gilberto; Chen, Zhixin; Molino, Paul J; Liu, Hua Kun

2015-01-13

Hexagonal boron nitride nanosheets (h-BNNS) have been proposed as an ideal substrate for graphene-based electronic devices, but the synthesis of large and homogeneous h-BNNS is still challenging. In this contribution, we report a facile synthesis of few-layer h-BNNS on melted copper via an atmospheric pressure chemical vapor deposition process. Comparative studies confirm the advantage of using melted copper over solid copper as a catalyst substrate. The former leads to the formation of single crystalline h-BNNS that is several microns in size and mostly in mono- and bi-layer forms, in contrast to the polycrystalline and mixed multiple layers (1-10) yielded by the latter. This difference is likely to be due to the significantly reduced and uniformly distributed nucleation sites on the smooth melted surface, in contrast to the large amounts of unevenly distributed nucleation sites that are associated with grain boundaries and other defects on the solid surface. This synthesis is expected to contribute to the development of large-scale manufacturing of h-BNNS/graphene-based electronics.

Superior Field Emission Properties of Layered WS2-RGO Nanocomposites

PubMed Central

Rout, Chandra Sekhar; Joshi, Padmashree D.; Kashid, Ranjit V.; Joag, Dilip S.; More, Mahendra A.; Simbeck, Adam J.; Washington, Morris; Nayak, Saroj K.; Late, Dattatray J.

2013-01-01

We report here the field emission studies of a layered WS2-RGO composite at the base pressure of ~1 × 10−8 mbar. The turn on field required to draw a field emission current density of 1 μA/cm2 is found to be 3.5, 2.3 and 2 V/μm for WS2, RGO and the WS2-RGO composite respectively. The enhanced field emission behavior observed for the WS2-RGO nanocomposite is attributed to a high field enhancement factor of 2978, which is associated with the surface protrusions of the single-to-few layer thick sheets of the nanocomposite. The highest current density of ~800 μA/cm2 is drawn at an applied field of 4.1 V/μm from a few layers of the WS2-RGO nanocomposite. Furthermore, first-principles density functional calculations suggest that the enhanced field emission may also be due to an overalp of the electronic structures of WS2 and RGO, where graphene-like states are dumped in the region of the WS2 fundamental gap. PMID:24257504

Effects of the shear layer growth rate on the supersonic jet noise

NASA Astrophysics Data System (ADS)

Ozawa, Yuta; Nonomura, Taku; Oyama, Akira; Mamori, Hiroya; Fukushima, Naoya; Yamamoto, Makoto

2017-11-01

Strong acoustic waves emitted from rocket plume might damage to rocket payloads because their payloads consist of fragile structure. Therefore, understanding and prediction of acoustic wave generation are of importance not only in science, but also in engineering. The present study makes experiments of a supersonic jet flow at the Mach number of 2.0 and investigates a relationship between growth rate of a shear layer and noise generation of the supersonic jet. We conducted particle image velocimetry (PIV) and acoustic measurements for three different shaped nozzles. These nozzles were employed to control the condition of a shear layer of the supersonic jet flow. We applied single-pixel ensemble correlation method (Westerweel et al., 2004) for the PIV images to obtain high-resolution averaged velocity profiles. This correlation method enabled us to obtain detailed data of the shear layer. For all cases, acoustic measurements clearly shows the noise source position at the end of a potential core of the jet. In the case where laminar to turbulent transition occurred in the shear layer, the sound pressure level increased by 4 dB at the maximum. This research is partially supported by Presto, JST (JPMJPR1678) and KAKENHI (25709009 and 17H03473).

Reproduction of mouse-pup ultrasonic vocalizations by nanocrystalline silicon thermoacoustic emitter

NASA Astrophysics Data System (ADS)

Kihara, Takashi; Harada, Toshihiro; Kato, Masahiro; Nakano, Kiyoshi; Murakami, Osamu; Kikusui, Takefumi; Koshida, Nobuyoshi

2006-01-01

As one of the functional properties of ultrasound generator based on efficient thermal transfer at the nanocrystalline silicon (nc-Si) layer surface, its potential as an ultrasonic simulator of vocalization signals is demonstrated by using the acoustic data of mouse-pup calls. The device composed of a surface-heating thin-film electrode, an nc-Si layer, and a single-crystalline silicon (c-Si) wafer, exhibits an almost completely flat frequency response over a wide range without any mechanical surface vibration systems. It is shown that the fabricated emitter can reproduce digitally recorded ultrasonic mouse-pups vocalizations very accurately in terms of the call duration, frequency dispersion, and sound pressure level. The thermoacoustic nc-Si device provides a powerful physical means for the understanding of ultrasonic communication mechanisms in various living animals.

Rashba effect in single-layer antimony telluroiodide SbTeI

DOE PAGES

Zhuang, Houlong L.; Cooper, Valentino R.; Xu, Haixuan; ...

2015-09-04

Exploring spin-orbit coupling (SOC) in single-layer materials is important for potential spintronics applications. In this paper, using first-principles calculations, we show that single-layer antimony telluroiodide SbTeI behaves as a two-dimensional semiconductor exhibiting a G 0W 0 band gap of 1.82 eV. More importantly, we observe the Rashba spin splitting in the SOC band structure of single-layer SbTeI with a sizable Rashba coupling parameter of 1.39 eV Å, which is significantly larger than that of a number of two-dimensional systems including surfaces and interfaces. The low formation energy and real phonon modes of single-layer SbTeI imply that it is stable. Finally,more » our study suggests that single-layer SbTeI is a candidate single-layer material for applications in spintronics devices.« less

Three-dimensional fit-to-flow microfluidic assembly.

PubMed

Chen, Arnold; Pan, Tingrui

2011-12-01

Three-dimensional microfluidics holds great promise for large-scale integration of versatile, digitalized, and multitasking fluidic manipulations for biological and clinical applications. Successful translation of microfluidic toolsets to these purposes faces persistent technical challenges, such as reliable system-level packaging, device assembly and alignment, and world-to-chip interface. In this paper, we extended our previously established fit-to-flow (F2F) world-to-chip interconnection scheme to a complete system-level assembly strategy that addresses the three-dimensional microfluidic integration on demand. The modular F2F assembly consists of an interfacial chip, pluggable alignment modules, and multiple monolithic layers of microfluidic channels, through which convoluted three-dimensional microfluidic networks can be easily assembled and readily sealed with the capability of reconfigurable fluid flow. The monolithic laser-micromachining process simplifies and standardizes the fabrication of single-layer pluggable polymeric modules, which can be mass-produced as the renowned Lego(®) building blocks. In addition, interlocking features are implemented between the plug-and-play microfluidic chips and the complementary alignment modules through the F2F assembly, resulting in facile and secure alignment with average misalignment of 45 μm. Importantly, the 3D multilayer microfluidic assembly has a comparable sealing performance as the conventional single-layer devices, providing an average leakage pressure of 38.47 kPa. The modular reconfigurability of the system-level reversible packaging concept has been demonstrated by re-routing microfluidic flows through interchangeable modular microchannel layers.

Effects of the Process Parameters on the Microstructure and Properties of Nitrided 17-4PH Stainless Steel

NASA Astrophysics Data System (ADS)

Wang, Jun; Lin, Yuanhua; Zeng, Dezhi; Yan, Jing; Fan, Hongyuan

2013-04-01

The effects of process parameters on the microstructure, microhardness, and dry-sliding wear behavior of plasma nitrided 17-4PH stainless steel were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and wear testing. The results show that a wear-resistant nitrided layer was formed on the surface of direct current plasma nitrided 17-4PH martensitic stainless steel. The microstructure and thickness of the nitrided layer is dependent on the treatment temperature rather than process pressure. XRD indicated that a single α N phase was formed during nitriding at 623 K (350 °C). When the temperature increased, the α N phase disappeared and CrN transformed in the nitrided layer. The hardness measurement demonstrated that the hardness of the stainless substrate steel increased from 320 HV0.1 in the untreated condition increasing to about 1275HV0.1 after nitriding 623 K (350 °C)/600 pa/4 hours. The extremely high values of the microhardness achieved by the great misfit-induced stress fields associated with the plenty of dislocation group and stacking fault. Dry-sliding wear resistance was improved by DC plasma nitriding. The best wear-resistance performance of a nitrided sample was obtained after nitriding at 673 K (350 °C), when the single α N-phase was produced and there were no CrN precipitates in the nitrided layer.

One-dimensional pressure transfer models for acoustic-electric transmission channels

NASA Astrophysics Data System (ADS)

Wilt, K. R.; Lawry, T. J.; Scarton, H. A.; Saulnier, G. J.

2015-09-01

A method for modeling piezoelectric-based ultrasonic acoustic-electric power and data transmission channels is presented. These channels employ piezoelectric disk transducers to convey signals across a series of physical layers using ultrasonic waves. This model decomposes the mechanical pathway of the signal into individual ultrasonic propagation layers which are generally independent of the layer's adjacent domains. Each layer is represented by a two-by-two traveling pressure wave transfer matrix which relates the forward and reverse pressure waves on one side of the layer to the pressure waves on the opposite face, where each face is assumed to be in contact with a domain of arbitrary reference acoustic impedance. A rigorous implementation of ultrasonic beam spreading is introduced and implemented within applicable domains. Compatible pressure-wave models for piezoelectric transducers are given, which relate the electric voltage and current interface of the transducer to the pressure waves on one mechanical interface while also allowing for passive acoustic loading of the secondary mechanical interface. It is also shown that the piezoelectric model's electrical interface is compatible with transmission line parameters (ABCD-parameters), allowing for connection of electronic components and networks. The model is shown to be capable of reproducing the behavior of realistic physical channels.

Experimental Investigation of Unsteady Shock Wave Turbulent Boundary Layer Interactions About a Blunt Fin

NASA Technical Reports Server (NTRS)

Barnhart, Paul J.; Greber, Isaac

1997-01-01

A series of experiments were performed to investigate the effects of Mach number variation on the characteristics of the unsteady shock wave/turbulent boundary layer interaction generated by a blunt fin. A single blunt fin hemicylindrical leading edge diameter size was used in all of the experiments which covered the Mach number range from 2.0 to 5.0. The measurements in this investigation included surface flow visualization, static and dynamic pressure measurements, both on centerline and off-centerline of the blunt fin axis. Surface flow visualization and static pressure measurements showed that the spatial extent of the shock wave/turbulent boundary layer interaction increased with increasing Mach number. The maximum static pressure, normalized by the incoming static pressure, measured at the peak location in the separated flow region ahead of the blunt fin was found to increase with increasing Mach number. The mean and standard deviations of the fluctuating pressure signals from the dynamic pressure transducers were found to collapse to self-similar distributions as a function of the distance perpendicular to the separation line. The standard deviation of the pressure signals showed initial peaked distribution, with the maximum standard deviation point corresponding to the location of the separation line at Mach number 3.0 to 5.0. At Mach 2.0 the maximum standard deviation point was found to occur significantly upstream of the separation line. The intermittency distributions of the separation shock wave motion were found to be self-similar profiles for all Mach numbers. The intermittent region length was found to increase with Mach number and decrease with interaction sweepback angle. For Mach numbers 3.0 to 5.0 the separation line was found to correspond to high intermittencies or equivalently to the downstream locus of the separation shock wave motion. The Mach 2.0 tests, however, showed that the intermittent region occurs significantly upstream of the separation line. Power spectral densities measured in the intermittent regions were found to have self-similar frequency distributions when compared as functions of a Strouhal number for all Mach numbers and interaction sweepback angles. The maximum zero-crossing frequencies were found to correspond with the peak frequencies in the power spectra measured in the intermittent region.

Single-layer ZnMN2 (M = Si, Ge, Sn) zinc nitrides as promising photocatalysts.

PubMed

Bai, Yujie; Luo, Gaixia; Meng, Lijuan; Zhang, Qinfang; Xu, Ning; Zhang, Haiyang; Wu, Xiuqiang; Kong, Fanjie; Wang, Baolin

2018-05-30

Searching for two-dimensional semiconductor materials that are suitable for visible-light photocatalytic water splitting provides a sustainable solution to deal with the future energy crisis and environmental problems. Herein, based on first-principles calculations, single-layer ZnMN2 (M = Si, Ge, Sn) zinc nitrides are proposed as efficient photocatalysts for water splitting. Stability analyses show that the single-layer ZnMN2 zinc nitrides exhibit energetic and dynamical stability. The electronic properties reveal that all of the single-layer ZnMN2 zinc nitrides are semiconductors. Interestingly, single-layer ZnSnN2 is a direct band gap semiconductor with a desirable band gap (1.74 eV), and the optical adsorption spectrum confirms its optical absorption in the visible light region. The hydrogen evolution reaction (HER) calculations show that the catalytic activity for single-layer ZnMN2 (M = Ge, Sn) is better than that of single-layer ZnSiN2. Furthermore, the band gaps and band edge positions for the single-layer ZnMN2 zinc nitrides can be effectively tuned by biaxial strain. Especially, single-layer ZnGeN2 can be effectively tuned to match better with the redox potentials of water and enhance the light absorption in the visible light region at a tensile strain of 5%, which is confirmed by the corresponding optical absorption spectrum. Our results provide guidance for experimental synthesis efforts and future searches for single-layer materials suitable for photocatalytic water splitting.

Crystal structures of carbonates up to Mbar pressures determined by single crystal synchrotron radiation diffraction

NASA Astrophysics Data System (ADS)

Merlini, M.

2013-12-01

The recent improvements at synchrotron beamlines, currently allow single crystal diffraction experiments at extreme pressures and temperatures [1,2] on very small single crystal domains. We successfully applied such technique to determine the crystal structure adopted by carbonates at mantle pressures. The knowledge of carbon-bearing phases is in fact fundamental for any quantitative modelling of global carbon cycle. The major technical difficulty arises after first order transitions or decomposition reactions, since original crystal (apx. 10x10x5 μm3) is transformed in much smaller crystalline domains often with random orientation. The use of 3D reciprocal space visualization software and the improved resolution of new generation flat panel detectors, however, allow both identification and integration of each single crystal domain, with suitable accuracy for ab-initio structure solution, performed with direct and charge-flipping methods and successive structure refinements. The results obtained on carbonates, indicate two major crystal-chemistry trends established at high pressures. The CO32- units, planar and parallel in ambient pressure calcite and dolomite structures, becomes non parallel in calcite- and dolomite-II and III phases, allowing more flexibility in the structures with possibility to accommodate strain arising from different cation sizes (Ca and Mg in particular). Dolomite-III is therefore also observed to be thermodynamically stable at lower mantle pressures and temperatures, differently from dolomite, which undergoes decomposition into pure end-members in upper mantle. At higher pressure, towards Mbar (lowermost mantle and D'' region) in agreement with theoretical calculations [3,4] and other experimental results [5], carbon coordination transform into 4-fold CO4 units, with different polymerisation in the structure depending on carbonate composition. The second important crystal chemistry feature detected is related to Fe2+ in Fe-bearing magnesite, which spontaneously oxidises at HP/HT, forming Fe3+ carbonates, Fe3+ oxides and reduced carbon (diamonds). Single crystal diffraction approach allowed full structure determination of these phases, yielding to the discovery of few unpredicted structures, such as Mg2Fe2C4O13 and Fe13O19, which can be well reproduced in different experiments. Mg2Fe2C4O13 carbonate present truncated chain C4O13 groups, and Fe13O19 oxide, whose stoichiometry is intermediate between magnetite and hematite, is a one-layer structure, with features encountered in superconducting materials. The results fully support the ideas of unexpected complexities in the mineralogy of the lowermost mantle, and single crystal technique, once properly optimized in ad-hoc synchrotron beamlines, is fundamental for extracting accurate structural information, otherwise rarely accessible with other experimental techniques. References: [1] Merlini M., Hanfland M. (2013). Single crystal diffraction at Mbar conditions by synchrotron radiation. High Pressure Research, in press. [2] Dubrovinsky et al., (2010). High Pressure Research, 30, 620-633. [3] Arapan et al. (1997). Phys. Rev. Lett., 98, 268501. [4] Oganov et al. (2008) EPSL, 273, 38-47. [5] Boulard et al. (2011) PNAS, 108, 5184-5187.

Researching of the reduction of shock waves intensivity in the “pseudo boiling” layer

NASA Astrophysics Data System (ADS)

Pavlov, G. I.; Telyashov, D. A.; Kochergin, A. V.; Nakoryakov, P. V.; Sukhovaya, E. A.

2017-09-01

This article applies to the field of acoustics and deals with noise reduction of pulsating combustion chambers, in particular the reduction of the shock waves’ intensity with the help of pseudo boiling layer. In the course of work on a test stand that included a pulsator, a compressor with the receiver and a high pressure fan was simulated gas jet flowing from the chamber pulsating combustion and studied the effect of different types of fluidization on effect of reducing the sound pressure levels. Were obtained the experimental dependence of the sound pressure levels from parameters such as: height of the layer of granules; diameter of the used granules; amplitude of the pressure pulsations in the gas stream at the entrance to the camera; frequency of pressure pulsations. Based on the results of the study, it was concluded that the using of a pseudo boiling layer is promising for reducing shock wave noise.

Optimal disturbances in boundary layers subject to streamwise pressure gradient

NASA Technical Reports Server (NTRS)

Ashpis, David E.; Tumin, Anatoli

2003-01-01

An analysis of the optimal non-modal growth of perturbations in a boundary layer in the presence of a streamwise pressure gradient is presented. The analysis is based on PSE equations for an incompressible fluid. Examples with Falkner-Scan profiles indicate that a favorable pressure gradient decreases the non-modal growth, while an unfavorable pressure gradient leads to an increase of the amplification. It is suggested that the transient growth mechanism be utilized to choose optimal parameters of tripping elements on a low-pressure turbine (LPT) airfoil. As an example, a boundary layer flow with a streamwise pressure gradient corresponding to the pressure distribution over a LPT airfoil is considered. It is shown that there is an optimal spacing of the tripping elements and that the transient growth effect depends on the starting point.

Delaminated Transfer of CVD Graphene

NASA Astrophysics Data System (ADS)

Clavijo, Alexis; Mao, Jinhai; Tilak, Nikhil; Altvater, Michael; Andrei, Eva

Single layer graphene is commonly synthesized by dissociation of a carbonaceous gas at high temperatures in the presence of a metallic catalyst in a process known as Chemical Vapor Deposition or CVD. Although it is possible to achieve high quality graphene by CVD, the standard transfer technique of etching away the metallic catalyst is wasteful and jeopardizes the quality of the graphene film by contamination from etchants. Thus, development of a clean transfer technique and preservation of the parent substrate remain prominent hurdles to overcome. In this study, we employ a copper pretreatment technique and optimized parameters for growth of high quality single layer graphene at atmospheric pressure. We address the transfer challenge by utilizing the adhesive properties between a polymer film and graphene to achieve etchant-free transfer of graphene films from a copper substrate. Based on this concept we developed a technique for dry delamination and transferring of graphene to hexagonal boron nitride substrates, which produced high quality graphene films while at the same time preserving the integrity of the copper catalyst for reuse. DOE-FG02-99ER45742, Ronald E. McNair Postbaccalaureate Achievement Program.

Direct visualization of nanoparticle dynamics at liquid interfaces

NASA Astrophysics Data System (ADS)

Gao, Yige; Kim, Paul; Hoagland, David; Russell, Tom

Ionic liquids, because of their negligible vapor pressures and moderate viscosities, are suitable media to investigate the dynamics of different types of dispersed nanoparticles by scanning electron microscopy. No liquid cell is necessary. Here, Brownian motions of nanoparticles partially wetted at the vacuum-liquid interface are visualized by low voltage SEM under conditions that allow single particle tracking for tens-of-minutes or longer. Conductive, nonconductive, semiconductive, and core-shell conductive-nonconductive nanoparticles have all been studied, and their interactions with each other in one- and two-component layers, as manifested in particle trajectories, differ significantly. For example, Au-coated silica nanoparticles aggregate above a threshold current, whereas aggregated silica-coated Au nanoparticles disaggregate at the same conditions. The impacts of surface concentration of nanoparticle dynamics were observed for one-component and two-component layers, with both global and localized motions visualized for single particles even in dense environments. As the surface concentration increases, the diffusion coefficient drops, and when the concentration reaches a critical threshold, the nanoparticles are essentially frozen. Financial support from NSF DMR-1619651 is acknowledged.

Theoretical study on the top- and enclosed-contacted single-layer MoS{sub 2} piezotronic transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Wei, E-mail: wliu@binn.cas.cn, E-mail: zlwang@gatech.edu; Zhou, Yongli; Zhang, Aihua

Recently, the piezotronic effect has been observed in two-dimensional single-layer MoS{sub 2} materials, which have potential applications in force and pressure triggered or controlled electronic devices, sensors, and human-machine interfaces. However, classical theory faces the difficulty in explaining the mechanism of the piezotronic effect for the top- and enclosed-contacted MoS{sub 2} transistors, since the piezoelectric charges are assumed to exist only at the edge of the MoS{sub 2} flake that is far from the electronic transport pathway. In the present study, we identify the piezoelectric charges at the MoS{sub 2}/metal-MoS{sub 2} interface by employing both the density functional theory andmore » finite element method simulations. This interface is on the transport pathway of both top- and enclosed-contacted MoS{sub 2} transistors, thus it is capable of controlling their transport properties. This study deepens the understanding of piezotronic effect and provides guidance for the design of two-dimensional piezotronic devices.« less

Wall-pressure fluctuations beneath a spatially evolving turbulent boundary layer

NASA Astrophysics Data System (ADS)

Mahesh, Krishnan; Kumar, Praveen

2016-11-01

Wall-pressure fluctuations beneath a turbulent boundary layer are important in applications dealing with structural deformation and acoustics. Simulations are performed for flat plate and axisymmetric, spatially evolving zero-pressure-gradient turbulent boundary layers at inflow Reynolds number of 1400 and 2200 based on momentum thickness. The simulations generate their own inflow using the recycle-rescale method. The results for mean velocity and second-order statistics show excellent agreement with the data available in literature. The spectral characteristics of wall-pressure fluctuations and their relation to flow structure will be discussed. This work is supported by ONR.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Atwater, Harry A.; Leite, Marina S.; Warmann, Emily C.

A virtual substrate includes a handle support and a strain-relieved single crystalline layer on the handle support. A method of making the virtual substrate includes growing a coherently-strained single crystalline layer on an initial growth substrate, removing the initial growth substrate to relieve the strain on the single crystalline layer, and applying the strain-relieved single crystalline layer on a handle support.

The Compaction of Ultramafic Cumulates in Layered Intrusions - Time and Length Scales (Invited)

NASA Astrophysics Data System (ADS)

Schmidt, M. W.; Manoochehri, S.

2013-12-01

Many large mafic intrusions have thick series of mostly ultramafic cumulates composed of dense cumulus minerals (chromite, olivine, pyroxenes) precipitated from low viscosity (roughly basaltic) liquids. To understand the time and length scales involved, the crystal settling and compaction process was simulated through centrifuge-assisted experiments of olivine or chromite in basaltic melt. Experiments were performed in a centrifuging piston cylinder at 200-1500 g, 1200-1300 C, 0.5-1.1 GPa on previously annealed and texturally equilibrated samples. The mechanical settling of the dense olivine or chromite suspensions occurs at 1/6 and 1/2 the speed of simple Stokes settling. The porosity (φm ) of orthocumulates resulting from gravitational settling is 50-55 %, pile up times for natural grain sizes result to 0.1-10 m/day. Hence, gravitational deposition (including re-deposition) of crystals may take place within years, i.e. almost instantaneously with progressing crystallization. After (re-)deposition, grains rest on each other. Further (chemical) compaction occurs through pressure dissolution at grain contacts, olivine or chromite re-precipitates where in contact with melt. Concomitantly excess liquid is expulsed from the cumulate layer. Centrifugation let to porosities as low as 30.3 vol% for olivine. The crystal content at the bottom of the experimentally compacted cumulate is 1-φm ~ log(Δρ h a t), where Δρ = crystal-melt density difference, h = crystal layer thickness, a = acceleration and t = time. Compaction is hence proportional to effective stress integrated over time indicating that pressure dissolution is the dominant mechanism. Notably, chromite crystals compact only about half as fast as olivine crystals. The compaction limit, i.e. the lowermost porosity to be reached, is calculated by equating the lithostatic and hydraulic pressure gradients in the cumulate and results to 3-5 % porosity for the experiments. Crystal size distribution curves and a growth exponent n of 3.1(3) (for olivine) indicate that diffusion controlled Ostwald ripening is the dominant crystal growth mechanism. The experimentally calibrated compaction relationship, combined with a linear scaling for grain size as appropriate for reaction-controlled pressure solution creep, allows calculation of formation times of natural adcumulates. A single layer of olivine adcumulate of 1/2 m thickness with 70-75 vol% olivine at the base (as observed in Rhum), would have typical formation times of 0.4-3 yrs for grain sizes of 2-10 mm, comparing favourably with characteristic cooling times of sills. If a >20 m thick series of cumulate layers pressurizes a base layer with the porosity still filled by a melt, then compaction proceeds to the compaction limit within a few years. To understand the thickness of a simultaneously compacting (layered) crystal pile, (paleo)-porosity gradients determined from incompatible trace elements can be employed when combined with modelled characteristic cooling times. In layered mafic intrusions where cumulates are deposited from a large magma chamber, compaction zones of several tens to hundreds of meter may form adcumulates with porosities in the order of 5%. In conclusion, gravitation driven chemical compaction is feasible for dense mafic minerals in basaltic magmas, in particular in large layered intrusions. The limiting factor appears to be rather the supply of crystals then the time necessary for compaction.

Evaluation of Satellite-Based Upper Troposphere Cloud Top Height Retrievals in Multilayer Cloud Conditions During TC4

NASA Technical Reports Server (NTRS)

Chang, Fu-Lung; Minnis, Patrick; Ayers, J. Kirk; McGill, Matthew J.; Palikonda, Rabindra; Spangenberg, Douglas A.; Smith, William L., Jr.; Yost, Christopher R.

2010-01-01

Upper troposphere cloud top heights (CTHs), restricted to cloud top pressures (CTPs) less than 500 hPa, inferred using four satellite retrieval methods applied to Twelfth Geostationary Operational Environmental Satellite (GOES-12) data are evaluated using measurements during the July August 2007 Tropical Composition, Cloud and Climate Coupling Experiment (TC4). The four methods are the single-layer CO2-absorption technique (SCO2AT), a modified CO2-absorption technique (MCO2AT) developed for improving both single-layered and multilayered cloud retrievals, a standard version of the Visible Infrared Solar-infrared Split-window Technique (old VISST), and a new version of VISST (new VISST) recently developed to improve cloud property retrievals. They are evaluated by comparing with ER-2 aircraft-based Cloud Physics Lidar (CPL) data taken during 9 days having extensive upper troposphere cirrus, anvil, and convective clouds. Compared to the 89% coverage by upper tropospheric clouds detected by the CPL, the SCO2AT, MCO2AT, old VISST, and new VISST retrieved CTPs less than 500 hPa in 76, 76, 69, and 74% of the matched pixels, respectively. Most of the differences are due to subvisible and optically thin cirrus clouds occurring near the tropopause that were detected only by the CPL. The mean upper tropospheric CTHs for the 9 days are 14.2 (+/- 2.1) km from the CPL and 10.7 (+/- 2.1), 12.1 (+/- 1.6), 9.7 (+/- 2.9), and 11.4 (+/- 2.8) km from the SCO2AT, MCO2AT, old VISST, and new VISST, respectively. Compared to the CPL, the MCO2AT CTHs had the smallest mean biases for semitransparent high clouds in both single-layered and multilayered situations whereas the new VISST CTHs had the smallest mean biases when upper clouds were opaque and optically thick. The biases for all techniques increased with increasing numbers of cloud layers. The transparency of the upper layer clouds tends to increase with the numbers of cloud layers.

Exploratory study of in-plane streamline curvature effects on a turbulent boundary layer at a Mach number of 3

NASA Technical Reports Server (NTRS)

Bogdonoff, Seymour M.

1991-01-01

This report on a program to study in-plane streamline curvature effects in a turbulent boundary layer at a Mach number of 3. The original proposal, for a 3-year program to explore in-plane streamline curvature effects on a supersonic turbulent boundary layer using three-dimensional pressure fields generated by fins and wall geometry, ended after one year. The purpose of these tests was to compare these streamline curvature effects to the more classical two-dimensional curvature generated by wall shape and imposed pressure gradients, previously considered primarily in a plane normal to the floor. The studies were carried out in the Mach number of 3, 8 x 8 inch High Reynolds Number Supersonic Tunnel. The usual surface visualization and mean wall static pressures were supplemented by the use of many small high frequency wall static pressure gauges (Kulites) to get some indication of the amplification of boundary layer disturbances by the in-plane streamline curvature caused by the three-dimensional pressure fields imposed on the boundary layer.

A two-layered mechanical model of the rat esophagus. Experiment and theory

PubMed Central

Fan, Yanhua; Gregersen, Hans; Kassab, Ghassan S

2004-01-01

Background The function of esophagus is to move food by peristaltic motion which is the result of the interaction of the tissue forces in the esophageal wall and the hydrodynamic forces in the food bolus. The structure of the esophagus is layered. In this paper, the esophagus is treated as a two-layered structure consisting of an inner collagen-rich submucosa layer and an outer muscle layer. We developed a model and experimental setup for determination of elastic moduli in the two layers in circumferential direction and related the measured elastic modulus of the intact esophagus to the elastic modulus computed from the elastic moduli of the two layers. Methods Inflation experiments were done at in vivo length and pressure-diameters relations were recorded for the rat esophagus. Furthermore, the zero-stress state was taken into consideration. Results The radius and the strain increased as function of pressure in the intact as well as in the individual layers of the esophagus. At pressures higher than 1.5 cmH2O the muscle layer had a larger radius and strain than the mucosa-submucosa layer. The strain for the intact esophagus and for the muscle layer was negative at low pressures indicating the presence of residual strains in the tissue. The stress-strain curve for the submucosa-mucosa layer was shifted to the left of the curves for the muscle layer and for the intact esophagus at strains higher than 0.3. The tangent modulus was highest in the submucosa-mucosa layer, indicating that the submucosa-mucosa has the highest stiffness. A good agreement was found between the measured elastic modulus of the intact esophagus and the elastic modulus computed from the elastic moduli of the two separated layers. PMID:15518591

Probabilistic description of ice-supersaturated layers in low resolution profiles of relative humidity N. C. Dickson, K. Gierens, H. L. Rogers, R. L. Jones

NASA Astrophysics Data System (ADS)

Dickson, N.

2009-12-01

The global observation, assimilation and prediction in numerical models of ice super-saturated (ISS) regions (ISSR) are crucial if the climate impact of aircraft condensations trails (contrails) is to be fully understood, and if, for example, contrail formation is to be avoided through aircraft operational measures. A robust assessment of the global distribution of ISSR will further this debate, and ISS event occurrence, frequency and spatial scales have recently attracted significant attention. The mean horizontal size of ISSR is 150 km (±250km) although 12-14% of ISS events occur on horizontal scales of less than 5km. The average vertical thickness of ISS layers is 600-800m (±575m) but layers ranging from 25m to 3000m have been observed, with up to one third of ISS layers thought to be less than 100m deep. Given their small scales compared to typical atmospheric model grid sizes, statistical representations of the spatial scales of ISSR are required, in both horizontal and vertical dimensions, if global occurrence of ISSR is to be adequately represented in climate models. This paper uses radiosonde launches made by the UK Meteorological Office, from the British Isles, Gibraltar, St. Helena and the Falkland Islands between January 2002 and December 2006, to investigate the probabilistic occurrence of ISSR. Specifically each radiosonde profile is divided into 50 and 100 hPa pressure layers, to emulate the coarse vertical resolution of some atmospheric models. Then the high resolution observations contained within each thick pressure layer are used to calculate an average relative humidity and an ISS fraction for each individual thick pressure layer. These relative humidity pressure layer descriptions are then linked through a probability function to produce an s-shaped curve describing the ISS fraction in any average relative humidity pressure layer. An empirical investigation has shown that this one curve is statistically valid for mid-latitude locations, irrespective of season and altitude, however, pressure layer depth is an important variable. Using this empirical understanding of the s-shaped relationship a mathematical model was developed to represent the ISS fraction within any arbitrary thick pressure layer. Here the statistical distributions of actual high resolution RHi observations in any thick pressure layer, along with an error function, are used to mathematically describe the s-shape. Two models were developed to represent both 50 and 100 hPa pressure layers with each reconstructing their respective s-shapes within 8-10% of the empirical curves. These new models can be used, to represent the small scale structures of ISS events, in modelled data where only low vertical resolution is available. This will be useful in understanding, and improving the global distribution, both observed and forecasted, of ice super-saturation.

High intensity ultrasound transducer used in gene transfection

NASA Astrophysics Data System (ADS)

Morrison, Kyle P.; Keilman, George W.; Noble, Misty L.; Brayman, Andrew A.; Miao, Carol H.

2012-11-01

This paper describes a novel therapeutic high intensity non-focused ultrasound (HIU) transducer designed with uniform pressure distribution to aid in accelerated gene transfer in large animal liver tissues in vivo. The underlying HIU transducer was used to initiate homogeneous cavitation throughout the tissue while delivering up to 2.7 MPa at 1.1 MHz across its radiating surface. The HIU transducer was built into a 6 cm diameter x 1.3 cm tall housing ergonomically designed to avoid collateral damage to the surrounding anatomy during dynamic motion. The ultrasound (US) radiation was applied in a 'paintbrush-like' manner to the surface of the liver. The layers and geometry of the transducer were carefully selected to maximize the active diameter (5.74 cm), maximize the electrical to acoustic conversion efficiency (85%) to achieve 2.7 MPa of peak negative pressure, maximize the frequency operating band at the fundamental resonance to within a power transfer delta of 1 dB, and reduce the pressure delta to within 2 dB across the radiating surface. For maximum peak voltage into the transducer, a high performance piezoceramic was chosen and a DC bias circuit was built integral to the system. An apodized two element annular pattern was made from a single piezoceramic element, resulting in significant pressure uniformity enhancement. In addition to using apodization for pressure uniformity, a proprietary multi-layered structure was used to improve efficiency while sustaining an operating band from 900 kHz to 1.3 MHz. The resultant operating band allowed for dithering techniques using frequency modulation. The underlying HIU transducer for use in large animals enhances gene expression up to 6300-fold.

Measurements of the Free-Stream Fluctuations above a Turbulent Boundary Layer

NASA Technical Reports Server (NTRS)

Wood, D. H.; Westphal, R. V.

1988-01-01

In this paper an investigation of the velocity fluctuations in the free stream above an incompressible turbulent boundary layer developing at constant pressure is described. It is assumed that the fluctuations receive contributions from three statistically independent sources: (1) one-dimensional unsteadiness, (2) free-stream turbulence, and (3) the irrotational motion induced by the turbulent boundary layer. Measurements were made in a wind tunnel with a root-mean-square level of the axial velocity fluctuations of about 0.2%. All three velocity components were measured using an X-wire probe. The unsteadiness was determined from the spanwise covariance of the axial velocity fluctuations, measured using two single-wire probes. The results show that it is possible to separate the contributions to the rms level of the velocity fluctuations without resorting to the dubious technique of high-pass filtering. This separation could be extended to the spectral densities of the contributions if measurements of sufficient accuracy were available.

Measurements of the free stream fluctuations above a turbulent boundary layer

NASA Technical Reports Server (NTRS)

Wood, David H.; Westphal, Russell V.

1987-01-01

This paper investigates the velocity fluctuations in the free stream above an incompressible turbulent boundary layer developing at constant pressure. It is assumed that the fluctuations receive contributions from three statistically independent sources: (1) one-dimensional unsteadiness, (2) free stream turbulence, and (3) the potential motion induced by the turbulent boundary layer. Measurements were made in a wind tunnel with a root-mean-square level of the axial velocity fluctuations of about 0.2 percent. All three velocity components were measured using an X-wire probe. The unsteadiness was determined from the spanwise covariance of the axial velocity, measured using two single wire probes. The results show that it is possible to separate the contributions to the r.m.s. level of the velocity fluctuations, without resorting to the dubious technique of high-pass filtering. The separation could be extended to the spectral densities of the contributions, if measurements of sufficient accuracy were available. The Appendix provides a general guide for the measurement of small free stream fluctuation levels.

High-pressure, high-temperature equations of state using nanofabricated controlled-geometry Ni/SiO 2/Ni double hot-plate samples

DOE PAGES

Pigott, Jeffrey S.; Ditmer, Derek A.; Fischer, Rebecca A.; ...

2015-11-24

We have fabricated novel controlled-geometry samples for the laser-heated diamond anvil cell (LHDAC) in which a transparent oxide layer (SiO 2) is sandwiched between two laser-absorbing layers (Ni) in a single, cohesive sample. The samples were mass manufactured (>10 4 samples) using a combination of physical vapor deposition, photolithography, and wet and plasma etching. The double hot-plate arrangement of the samples, coupled with the chemical and spatial homogeneity of the laser-absorbing layers, addresses problems of spatial temperature heterogeneities encountered in previous studies where simple mechanical mixtures of transparent and opaque materials were used. Here we report thermal equations of statemore » (EOS) for nickel to 100 GPa and 3000 K and stishovite to 50 GPa and 2400 K obtained using the LHDAC and in situ synchrotron x-ray micro-diffraction. Lastly, we discuss the inner core composition and the stagnation of subducted slabs in the mantle based on our refined thermal EOS.« less

NASA Tech Briefs, July 2008

NASA Technical Reports Server (NTRS)

2008-01-01

Topics covered include: Torque Sensor Based on Tunnel-Diode Oscillator; Shaft-Angle Sensor Based on Tunnel-Diode Oscillator; Ground Facility for Vicarious Calibration of Skyborne Sensors; Optical Pressure-Temperature Sensor for a Combustion Chamber; Impact-Locator Sensor Panels; Low-Loss Waveguides for Terahertz Frequencies; MEMS/ECD Method for Making Bi(2-x)Sb(x)Te3 Thermoelectric Devices; Low-Temperature Supercapacitors; Making a Back-Illuminated Imager with Back-Side Contact and Alignment Markers; Compact, Single-Stage MMIC InP HEMT Amplifier; Nb(x)Ti(1-x)N Superconducting-Nanowire Single-Photon Detectors; Improved Sand-Compaction Method for Lost-Foam Metal Casting; Improved Probe for Evaluating Compaction of Mold Sand; Polymer-Based Composite Catholytes for Li Thin-Film Cells; Using ALD To Bond CNTs to Substrates and Matrices; Alternating-Composition Layered Ceramic Barrier Coatings; Variable-Structure Control of a Model Glider Airplane; Axial Halbach Magnetic Bearings; Compact, Non-Pneumatic Rock-Powder Samplers; Biochips Containing Arrays of Carbon-Nanotube Electrodes; Nb(x)Ti(1-x)N Superconducting-Nanowire Single-Photon Detectors; Neon as a Buffer Gas for a Mercury-Ion Clock; Miniature Incandescent Lamps as Fiber-Optic Light Sources; Bidirectional Pressure-Regulator System; and Prism Window for Optical Alignment. Single-Grid-Pair Fourier Telescope for Imaging in Hard-X Rays and gamma Rays Range-Gated Metrology with Compact Optical Head Lossless, Multi-Spectral Data Compressor for Improved Compression for Pushbroom-Typetruments.

Strongly luminescent monolayered MoS2 prepared by effective ultrasound exfoliation.

PubMed

Štengl, Václav; Henych, Jiří

2013-04-21

Intense ultrasound in a pressurized batch reactor was used for preparation of monolayered MoS2 nanosheets from natural mineral molybdenite. Exfoliation of bulk MoS2 using ultrasound is an attractive route to large-scale preparation of monolayered crystals. To evaluate the quality of delamination, methods like X-ray diffraction, Raman spectroscopy and microscopic techniques (TEM and AFM) were employed. From single- or few-layered products obtained from intense sonication, MoS2 quantum dots (MoSQDs) were prepared by a one-pot reaction by refluxing exfoliated nanosheets of MoS2 in ethylene glycol under atmospheric pressure. The synthesised MoSQDs were characterised by photoluminescence spectroscopy and laser-scattering particle size analysis. Our easy preparation leads to very strongly green luminescing quantum dots.

Boundary-layer transition and displacement thickness effects on zero-lift drag of a series of power-law bodies at Mach 6

NASA Technical Reports Server (NTRS)

Ashby, G. C., Jr.; Harris, J. E.

1974-01-01

Wave and skin-friction drag have been numerically calculated for a series of power-law bodies at a Mach number of 6 and Reynolds numbers, based on body length, from 1.5 million to 9.5 million. Pressure distributions were computed on the nose by the inverse method and on the body by the method of characteristics. These pressure distributions and the measured locations of boundary-layer transition were used in a nonsimilar-boundary-layer program to determine viscous effects. A coupled iterative approach between the boundary-layer and pressure-distribution programs was used to account for boundary-layer displacement-thickness effects. The calculated-drag coefficients compared well with previously obtained experimental data.

Probabilistic description of ice-supersaturated layers in low resolution profiles of relative humidity

NASA Astrophysics Data System (ADS)

Dickson, N. C.; Gierens, K. M.; Rogers, H. L.; Jones, R. L.

2010-07-01

The global observation, assimilation and prediction in numerical models of ice super-saturated (ISS) regions (ISSR) are crucial if the climate impact of aircraft condensation trails (contrails) is to be fully understood, and if, for example, contrail formation is to be avoided through aircraft operational measures. Given their small scales compared to typical atmospheric model grid sizes, statistical representations of the spatial scales of ISSR are required, in both horizontal and vertical dimensions, if global occurrence of ISSR is to be adequately represented in climate models. This paper uses radiosonde launches made by the UK Meteorological Office, from the British Isles, Gibraltar, St. Helena and the Falkland Islands between January 2002 and December 2006, to investigate the probabilistic occurrence of ISSR. Each radiosonde profile is divided into 50- and 100-hPa pressure layers, to emulate the coarse vertical resolution of some atmospheric models. Then the high resolution observations contained within each thick pressure layer are used to calculate an average relative humidity and an ISS fraction for each individual thick pressure layer. These relative humidity pressure layer descriptions are then linked through a probability function to produce an s-shaped curve which empirically describes the ISS fraction in any average relative humidity pressure layer. Using this empirical understanding of the s-shaped relationship a mathematical model was developed to represent the ISS fraction within any arbitrary thick pressure layer. Two models were developed to represent both 50- and 100-hPa pressure layers with each reconstructing their respective s-shapes within 8-10% of the empirical curves. These new models can be used, to represent the small scale structures of ISS events, in modelled data where only low vertical resolution is available. This will be useful in understanding, and improving the global distribution, both observed and forecasted, of ice super-saturation.

Methane adsorption in nanoporous carbon: the numerical estimation of optimal storage conditions

NASA Astrophysics Data System (ADS)

Ortiz, L.; Kuchta, B.; Firlej, L.; Roth, M. W.; Wexler, C.

2016-05-01

The efficient storage and transportation of natural gas is one of the most important enabling technologies for use in energy applications. Adsorption in porous systems, which will allow the transportation of high-density fuel under low pressure, is one of the possible solutions. We present and discuss extensive grand canonical Monte Carlo (GCMC) simulation results of the adsorption of methane into slit-shaped graphitic pores of various widths (between 7 Å and 50 Å), and at pressures P between 0 bar and 360 bar. Our results shed light on the dependence of film structure on pore width and pressure. For large widths, we observe multi-layer adsorption at supercritical conditions, with excess amounts even at large distances from the pore walls originating from the attractive interaction exerted by a very high-density film in the first layer. We are also able to successfully model the experimental adsorption isotherms of heterogeneous activated carbon samples by means of an ensemble average of the pore widths, based exclusively on the pore-size distributions (PSD) calculated from subcritical nitrogen adsorption isotherms. Finally, we propose a new formula, based on the PSD ensemble averages, to calculate the isosteric heat of adsorption of heterogeneous systems from single-pore-width calculations. The methods proposed here will contribute to the rational design and optimization of future adsorption-based storage tanks.

Pressure Study of Photoluminescence in GaN/InGaN/ AlGaN Quantum Wells

NASA Astrophysics Data System (ADS)

Perlin, Piotr; Iota, V.; Weinstein, B. A.; Wisniewski, P.; Osinski, M.; Eliseev, P. G.

1997-03-01

We have studied the photoluminescence (PL) from two commercial high brightness single quantum well light emitting diodes (Nichia Chem. Industs.) with In_xGa_1-x N (x=0.45 and 0.2) as the active layers under hydrostatic pressures up to 7 GPa. These diodes are the best existing light emitters at short wavelengths, having the emission wavelengths of 430 nm and 530 nm depending on the content of indium in the 30 Åthick quantum wells. Although these devices show a remarkable quality and efficiency (luminosity as high as 12 cd), the mechanism of recombination remains obscure. We discovered that the pressure coefficient for each of the observed PL peaks is dramatically (2-3 times) lower than that of the energy gap of its InGaN active layer. These observations, in conjunction with the fact that the observed emission occurs below the energy gap of the quantum well material, and also considering the anomalous temperature behavior of the emission (peak energy increasing with temperature) suggest the involvement of localized states and exclude a simple band-to-band recombination picture. These localized states may be tentatively attributed to the presence of band tails in the gap which stem from composition fluctuations in the InGaN alloy. (figures)

Experimental observation of hysteresis in a coherent metal-hydride phase transition

NASA Astrophysics Data System (ADS)

Huang, Wen; Pálsson, Gunnar K.; Brischetto, Martin; Droulias, Sotirios A.; Hartmann, Ola; Wolff, Max; Hjörvarsson, Björgvin

2017-12-01

We investigate the hysteresis obtained in the hydrogen absorption and desorption cycle for a single crystal Pd/V_28 ≤ft[Fe4 /V_28\\right]11 superlattice. Below the critical temperature, a small but clear hysteresis is observed in the pressure-composition isotherms, while it is absent above. The experimental results thereby prove the relevance of macroscopic energy barriers for obtaining hysteresis in coherent structural transformations. The textured Pd layer exhibits substantially larger hysteresis effects, which can be related to an irreversible energy loss caused by defect generation in Pd.

The behavior of a compressible turbulent boundary layer in a shock-wave-induced adverse pressure gradient. Ph.D. Thesis - Washington Univ., Seattle, Aug. 1972

NASA Technical Reports Server (NTRS)

Rose, W. C.

1973-01-01

The results of an experimental investigation of the mean- and fluctuating-flow properties of a compressible turbulent boundary layer in a shock-wave-induced adverse pressure gradient are presented. The turbulent boundary layer developed on the wall of an axially symmetric nozzle and test section whose nominal free-stream Mach number and boundary-layer thickness Reynolds number were 4 and 100,000, respectively. The adverse pressure gradient was induced by an externally generated conical shock wave. Mean and time-averaged fluctuating-flow data, including the complete experimental Reynolds stress tensor and experimental turbulent mass- and heat-transfer rates are presented for the boundary layer and external flow, upstream, within and downstream of the pressure gradient. The mean-flow data include distributions of total temperature throughout the region of interest. The turbulent mixing properties of the flow were determined experimentally with a hot-wire anemometer. The calibration of the wires and the interpretation of the data are discussed. From the results of the investigation, it is concluded that the shock-wave - boundary-layer interaction significantly alters the turbulent mixing characteristics of the boundary layer.

Fission product release and survivability of UN-kernel LWR TRISO fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

T. M. Besmann; M. K. Ferber; H.-T. Lin

2014-05-01

A thermomechanical assessment of the LWR application of TRISO fuel with UN kernels was performed. Fission product release under operational and transient temperature conditions was determined by extrapolation from fission product recoil calculations and limited data from irradiated UN pellets. Both fission recoil and diffusive release were considered and internal particle pressures computed for both 650 and 800 um diameter kernels as a function of buffer layer thickness. These pressures were used in conjunction with a finite element program to compute the radial and tangential stresses generated within a TRISO particle undergoing burnup. Creep and swelling of the inner andmore » outer pyrolytic carbon layers were included in the analyses. A measure of reliability of the TRISO particle was obtained by computing the probability of survival of the SiC barrier layer and the maximum tensile stress generated in the pyrolytic carbon layers from internal pressure and thermomechanics of the layers. These reliability estimates were obtained as functions of the kernel diameter, buffer layer thickness, and pyrolytic carbon layer thickness. The value of the probability of survival at the end of irradiation was inversely proportional to the maximum pressure.« less

Single layer multi-color luminescent display and method of making

NASA Technical Reports Server (NTRS)

Robertson, James B. (Inventor)

1992-01-01

The invention is a multi-color luminescent display comprising an insulator substrate and a single layer of host material, which may be a phosphor deposited thereon that hosts one or more different impurities, therein forming a pattern of selected and distinctly colored phosphors such as blue, green, and red phosphors in a single layer of host material. Transparent electrical conductor means may be provided for subjecting selected portions of the pattern of colored phosphors to an electric field, thereby forming a multi-color, single layer electroluminescent display. A method of forming a multi-color luminescent display includes the steps of depositing on an insulator substrate a single layer of host material, which itself may be a phosphor, with the properties to host varying quantities of different impurities and introducing one or more of said different impurities into selected areas of the said single layer of host material by thermal diffusion or ion implantation to form a pattern of phosphors of different colors in the said single layer of host material.

Improved properties of barium strontium titanate thin films grown on copper foils by pulsed laser deposition using a self-buffered layer.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, S.; Ma, B.; Narayanan, M.

2012-01-01

Ba{sub 0.6}Sr{sub 0.4}TiO{sub 3} (BST) films were deposited by pulsed laser deposition on copper foils with low-temperature self-buffered layers. The deposition conditions included a low oxygen partial pressure and a temperature of 700 C to crystallize the films without the formation of secondary phases and substrate oxidation. The results from x-ray diffraction and scanning electron microscopy indicated that the microstructure of the BST films strongly depended on the growth temperature. The use of the self-buffered layer improved the dielectric properties of the deposited BST films. The leakage current density of the BST films on the copper foil was 4.4 xmore » 10{sup -9} A cm{sup -2} and 3.3 x 10{sup -6} A cm{sup -2} with and without the self-buffered layer, respectively. The ferroelectric hysteresis loop for the BST thin film with buffer layer was slim, in contrast to the distorted loop observed for the film without the buffer layer. The permittivity (7 0 0) and dielectric loss tangent (0.013) of the BST film on the copper foil with self-buffered layer at room temperature were comparable to those of the film on metal and single-crystal substrates.« less

Spatially resolved observation of crystal-face-dependent catalysis by single turnover counting

NASA Astrophysics Data System (ADS)

Roeffaers, Maarten B. J.; Sels, Bert F.; Uji-I, Hiroshi; de Schryver, Frans C.; Jacobs, Pierre A.; de Vos, Dirk E.; Hofkens, Johan

2006-02-01

Catalytic processes on surfaces have long been studied by probing model reactions on single-crystal metal surfaces under high vacuum conditions. Yet the vast majority of industrial heterogeneous catalysis occurs at ambient or elevated pressures using complex materials with crystal faces, edges and defects differing in their catalytic activity. Clearly, if new or improved catalysts are to be rationally designed, we require quantitative correlations between surface features and catalytic activity-ideally obtained under realistic reaction conditions. Transmission electron microscopy and scanning tunnelling microscopy have allowed in situ characterization of catalyst surfaces with atomic resolution, but are limited by the need for low-pressure conditions and conductive surfaces, respectively. Sum frequency generation spectroscopy can identify vibrations of adsorbed reactants and products in both gaseous and condensed phases, but so far lacks sensitivity down to the single molecule level. Here we adapt real-time monitoring of the chemical transformation of individual organic molecules by fluorescence microscopy to monitor reactions catalysed by crystals of a layered double hydroxide immersed in reagent solution. By using a wide field microscope, we are able to map the spatial distribution of catalytic activity over the entire crystal by counting single turnover events. We find that ester hydrolysis proceeds on the lateral {1010} crystal faces, while transesterification occurs on the entire outer crystal surface. Because the method operates at ambient temperature and pressure and in a condensed phase, it can be applied to the growing number of liquid-phase industrial organic transformations to localize catalytic activity on and in inorganic solids. An exciting opportunity is the use of probe molecules with different size and functionality, which should provide insight into shape-selective or structure-sensitive catalysis and thus help with the rational design of new or more productive heterogeneous catalysts.

Density functional theory study of bulk and single-layer magnetic semiconductor CrPS4

NASA Astrophysics Data System (ADS)

Zhuang, Houlong L.; Zhou, Jia

2016-11-01

Searching for two-dimensional (2D) materials with multifunctionality is one of the main goals of current research in 2D materials. Magnetism and semiconducting are certainly two desirable functional properties for a single 2D material. In line with this goal, here we report a density functional theory (DFT) study of bulk and single-layer magnetic semiconductor CrPS4. We find that the ground-state magnetic structure of bulk CrPS4 exhibits the A-type antiferromagnetic ordering, which transforms to ferromagnetic (FM) ordering in single-layer CrPS4. The calculated formation energy and phonon spectrum confirm the stability of single-layer CrPS4. The band gaps of FM single-layer CrPS4 calculated with a hybrid density functional are within the visible-light range. We also study the effects of FM ordering on the optical absorption spectra and band alignments for water splitting, indicating that single-layer CrPS4 could be a potential photocatalyst. Our work opens up ample opportunities of energy-related applications of single-layer CrPS4.

Measurements of a turbulent horseshoe vortex formed around a cylinder

NASA Technical Reports Server (NTRS)

Eckerle, W. A.; Langston, L. S.

1986-01-01

An experimental investigation was conducted to characterize a symmetrical horseshoe vortex system in front of and around a single large-diameter right cylinder centered between the sidewalls of a wind tunnel. Surface flow visualization and surface static pressure measurements as well as extensive mean velocity and pressure measurements in and around the vortex system were acquired. The results lend new insight into the formation and development of the vortex system. Contrary to what has been assumed previously, a strong vortex was not identified in the streamwise plane of symmetry, but started a significant angular distance away from it. Rather than the multiple vortex systems reported by others, only a single primary vortex and saddle point were found. The scale of the separation process at the saddle point was much smaller than the scale of the approaching boundary layer thickness. Results of the present study not only shed light on such phenomena as the nonsymmetrical endwall flow in axial turbomachinery but can also be used as a test case for three-dimensional computational fluid mechanics computer codes.

Zinc oxide nanowire-poly(methyl methacrylate) dielectric layers for polymer capacitive pressure sensors.

PubMed

Chen, Yan-Sheng; Hsieh, Gen-Wen; Chen, Shih-Ping; Tseng, Pin-Yen; Wang, Cheng-Wei

2015-01-14

Polymer capacitive pressure sensors based on a dielectric composite layer of zinc oxide nanowire and poly(methyl methacrylate) show pressure sensitivity in the range of 2.63 × 10(-3) to 9.95 × 10(-3) cm(2) gf(-1). This represents an increase of capacitance change by as much as a factor of 23 over pristine polymer devices. An ultralight load of only 10 mg (corresponding to an applied pressure of ∼0.01 gf cm(-2)) can be clearly recognized, demonstrating remarkable characteristics of these nanowire-polymer capacitive pressure sensors. In addition, optical transmittance of the dielectric composite layer is approximately 90% in the visible wavelength region. Their low processing temperature, transparency, and flexible dielectric film makes them a highly promising means for flexible touching and pressure-sensing applications.

Electron emitting device and method of making the same

DOEpatents

Olsen, Gregory Hammond; Martinelli, Ramon Ubaldo; Ettenberg, Michael

1977-04-19

A substrate of single crystalline gallium arsenide has on a surface thereof a layer of single crystalline indium gallium phosphide. A layer of single crystalline gallium arsenide is on the indium gallium phosphide layer and a work function reducing material is on the gallium arsenide layer. The substrate has an opening therethrough exposing a portion of the indium gallium phosphide layer.

Diffusion and Monod kinetics model to determine in vivo human corneal oxygen-consumption rate during soft contact lens wear

PubMed Central

Del Castillo, Luis F.; da Silva, Ana R. Ferreira; Hernández, Saul I.; Aguilella, M.; Andrio, Andreu; Mollá, Sergio; Compañ, Vicente

2014-01-01

Purpose We present an analysis of the corneal oxygen consumption Qc from non-linear models, using data of oxygen partial pressure or tension (pO2) obtained from in vivo estimation previously reported by other authors.1 Methods Assuming that the cornea is a single homogeneous layer, the oxygen permeability through the cornea will be the same regardless of the type of lens that is available on it. The obtention of the real value of the maximum oxygen consumption rate Qc,max is very important because this parameter is directly related with the gradient pressure profile into the cornea and moreover, the real corneal oxygen consumption is influenced by both anterior and posterior oxygen fluxes. Results Our calculations give different values for the maximum oxygen consumption rate Qc,max, when different oxygen pressure values (high and low pO2) are considered at the interface cornea-tears film. Conclusion Present results are relevant for the calculation on the partial pressure of oxygen, available at different depths into the corneal tissue behind contact lenses of different oxygen transmissibility. PMID:25649636

Final Report for Project: Impacts of stratification and non-equilibrium winds and waves on hub-height winds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patton, Edward G.

This project used a combination of turbulence-resolving large-eddy simulations, single-column modeling (where turbulence is parameterized), and currently available observations to improve, assess, and develop a parameterization of the impact of non-equilibrium wave states and stratification on the buoy-observed winds to establish reliable wind data at the turbine hub-height level. Analysis of turbulence-resolving simulations and observations illuminates the non-linear coupling between the atmosphere and the undulating sea surface. This analysis guides modification of existing boundary layer parameterizations to include wave influences for upward extrapolation of surface-based observations through the turbine layer. Our surface roughness modifications account for the interaction between stratificationmore » and the effects of swell’s amplitude and wavelength as well as swell’s relative motion with respect to the mean wind direction. The single-column version of the open source Weather and Research Forecasting (WRF) model (Skamarock et al., 2008) serves as our platform to test our proposed planetary boundary layer parameterization modifications that account for wave effects on marine atmospheric boundary layer flows. WRF has been widely adopted for wind resource analysis and forecasting. The single column version is particularly suitable to development, analysis, and testing of new boundary layer parameterizations. We utilize WRF’s single-column version to verify and validate our proposed modifications to the Mellor-Yamada-Nakanishi-Niino (MYNN) boundary layer parameterization (Nakanishi and Niino, 2004). We explore the implications of our modifications for two-way coupling between WRF and wave models (e.g.,Wavewatch III). The newly implemented parameterization accounting for marine atmospheric boundary layer-wave coupling is then tested in three-dimensional WRF simulations at grid sizes near 1 km. These simulations identify the behavior of simulated winds at the wind plant scale. Overall project conclusions include; In the presence of fast-moving swell (significant wave height Hs = 6.4 m, and phase speed cp = 18 ms -1), the atmospheric boundary layer grows more rapidly when waves propagate opposite to the winds compared to when winds and waves are aligned. Pressure drag increases by nearly a factor of 2 relative to the turbulent stress for the extreme case where waves propagate at 180° compared to the pressure gradient forcing. Net wind speed reduces by nearly 15% at hub-height for the 180°-case compared to the 0°-case, and turbulence intensities increase by nearly a factor of 2. These impacts diminish with decreasing wave age; Stratification increases hub height wind speeds and increases the vertical shear of the mean wind across the rotor plane. Fortuitously, this stability-induced enhanced shear does not influence turbulence intensity at hub height, but does increase (decrease) turbulence intensity below (above) hub height. Increased stability also increases the wave-induced pressure stress by ~ 10%; Off the East Coast of the United States during Coupled Boundary Layers Air-Sea Transfer - Low Wind (CBLAST-Low), cases with short fetch include thin stable boundary layers with depths of only a few tens of meters. In the coastal zone, the relationship between the mean wind and the surface fiction velocity (u*(V )) is significantly related to wind direction for weak winds but is not systematically related to the air sea difference of virtual potential temperature, δθv; since waves generally propagate from the south at the Air-Sea Interaction Tower (ASIT) tower, these results suggest that under weak wind conditions waves likely influence surface stress more than stratification does; and Winds and waves are frequently misaligned in the coastal zone. Stability conditions persist for long duration. Over a four year period, the Forschungsplattformen in Nord- und Ostsee Nr. 1 (FINO1) tower (a site with long fetch) primarily experienced weakly-unstable conditions, while stability at the ASIT tower (with a larger influence of offshore winds) experiences a mix of both unstable and stable conditions, where the summer months are predominantly stable. Wind-wave misalignment likely explains the large scatter in observed non-dimensional surface roughness under swell-dominated conditions. Andreas et al.’s (2012) relationship between u* and the 10-m wind speed under predicts the increased u* produced by wave-induced pressure drag produced by misaligned winds and waves. Incorporating wave-state (speed and direction) influences in parameterizations improves predictive skill. In a broad sense, these results suggest that one needs information on winds, temperature, and wave state to upscale buoy measurements to hub-height and across the rotor plane. Our parameterization of wave-state influences on surface drag has been submitted for inclusion in the next publicly available release. In combination, our project elucidates the impacts of two important physical processes (non-equilibrium wind/waves and stratification) on the atmosphere within which offshore turbines operate. This knowledge should help guide and inform manufacturers making critical decisions surrounding design criteria of future turbines to be deployed in the coastal zone. Reductions in annually averaged hub height wind speed error using our new wave-state-aware surface layer parameterization are relatively modest. However since wind turbine power production depends on the wind speed cubed, the error in estimated power production is close to 5%; which is significant and can substantially impact wind resource assessment and decision making with regards to the viability of particular location for a wind plant location. For a single 30-hour forecast, significant reductions in wind speed prediction errors can yield substantially improved wind power forecast skill, thereby mitigating costs and/or increasing revenue through improved; forecasting for maintenance operations and planning; day-ahead forecasting for power trading and resource allocation; and short-term forecasting for dispatch and grid balancing.« less

The aortic valve microstructure: effects of transvalvular pressure.

PubMed

Sacks, M S; Smith, D B; Hiester, E D

1998-07-01

We undertook this study to establish a more quantitative understanding of the microstructural response of the aortic valve cusp to pressure loading. Fresh porcine aortic valves were fixed at transvalvular pressures ranging from 0 mmHg to 90 mmHg, and small-angle light scattering (SALS) was used to quantify the gross fiber structure of the valve cusps. At all pressures the fiber-preferred directions coursed along the circumferential direction. Increasing transvalvular pressure induced the greatest changes in fiber alignment between 0 and 1 mmHg, with no detectable change past 4 mmHg. When the fibrosa and ventricularis layers of the cusps were re-scanned separately, the fibrosa layer revealed a higher degree of orientation while the ventricularis was more randomly oriented. The degree of fiber orientation for both layers became more similar once the transvalvular pressure exceeded 4 mmHg, and the layers were almost indistinguishable by 60 mmHg. It is possible that, in addition to retracting the aortic cusp during systole, the ventricularis mechanically may contribute to the diastolic cuspal stiffness at high transvalvular pressures, which may help to prevent over distention of the cusp. Our results suggest a complex, highly heterogeneous structural response to transvalvular pressure on a fiber level that will have to be duplicated in future bioprosthetic heart valve designs.

Structure and Dynamics of Freely Suspended Liquid Crystals

NASA Technical Reports Server (NTRS)

Clark, Noel A.

2004-01-01

Smectic liquid crystals are phases of rod shaped molecules organized into one dimensionally (1 D) periodic arrays of layers, each layer being between one and two molecular lengths thick. In the least ordered smectic phases, the smectics A and C, each layer is a two dimensional (2D) liquid. Additionally there are a variety of more ordered smectic phases having hexatic short range translational order or 2D crystalline or quasi long range translational order within the layers. The inherent fluid-layer structure and low vapor pressure of smectic liquid crystals enables the long term stabilization of freely suspended, single component, layered fluid films as thin as 30A, a single molecular layer. The layering forces the films to be an integral number of smectic layers thick, quantizing their thickness in layer units and forcing a film of a particular number of layers to be physically homogeneous with respect to its layer structure over its entire area. Optical reflectivity enables the precise determination of the number of layers. These ultrathin freely suspended liquid crystal films are structures of fundamental interest in condensed matter and fluid physics. They are the thinnest known stable fluid structures and have the largest surface-to-volume ratio of any stable fluid preparation, making them ideal for the study of the effects of reduced dimensionality on phase behavior and on fluctuation and interface phenomena. Their low vapor pressure and quantized thickness enable the effective use of microgravity to extend the study of basic capillary phenomena to ultrathin fluid films. Freely suspended films have been a wellspring of new LC physics. They have been used to provide unique experimental conditions for the study of condensed phase transitions in two dimensions. They are the only system in which the hexatic has been unambiguously identified as a phase of matter, and the only physical system in which fluctuations of a 2D XY system and Kosterlitz Thouless phase transition has been observed and 2D XY quasi long range order verified. Smectic films have enabled the precise determination of smectic layer electron density and positional fluctuation profiles and have been used to show that the interlayer interactions in antiferroelectric tilted smectics do not extend significantly beyond nearest neighbors. Freely suspended films played a pivotal role in the recent discovery of macroscopic chiral-polar ordering in fluids of achiral molecules. The interactions which are operative in liquid crystals are generally weak in comparison to those in crystalline phases, leading to the facile manipulation of the order in liquid crystals by external agents such as applied fields and surfaces. Effects arising from weak ordering are significantly enhanced in ultrathin free films and filaments, in which the intermolecular coupling is effectively further reduced by loss of neighbors. Over the past four years this research, which we now detail, has produced a host of exciting new discoveries and unexpected results, maintaining the study of freely suspended liquid crystal structures as one of most exciting and fruitful areas of complex fluid physics. In addition, a class of experiments on the behavior of 1D interfaces in 2D films have been pursued with results that point to potentially quite interesting effects in microgravity.

Investigation of blown boundary layers with an improved wall jet system. Ph.D. Thesis. Final Technical Report, 1 Jul. 1978 - Dec. 1979; [to prevent turbulent boundary layer separation

NASA Technical Reports Server (NTRS)

Saripalli, K. R.; Simpson, R. L.

1979-01-01

The behavior of two dimensional incompressible turbulent wall jets submerged in a boundary layer when they are used to prevent boundary layer separation on plane surfaces is investigated. The experimental set-up and instrumentation are described. Experimental results of zero pressure gradient flow and adverse pressure gradient flow are presented. Conclusions are given and discussed.

The effect of facial expressions on respirators contact pressures.

PubMed

Cai, Mang; Shen, Shengnan; Li, Hui

2017-08-01

This study investigated the effect of four typical facial expressions (calmness, happiness, sadness and surprise) on contact characteristics between an N95 filtering facepiece respirator and a headform. The respirator model comprised two layers (an inner layer and an outer layer) and a nose clip. The headform model was comprised of a skin layer, a fatty tissue layer embedded with eight muscles, and a skull layer. Four typical facial expressions were generated by the coordinated contraction of four facial muscles. After that, the distribution of the contact pressure on the headform, as well as the contact area, were calculated. Results demonstrated that the nasal clip could help make the respirator move closer to the nose bridge while causing facial discomfort. Moreover, contact areas varied with different facial expressions, and facial expressions significantly altered contact pressures at different key areas, which may result in leakage.

On the estimation of thermal strains developed during oxide growth

NASA Astrophysics Data System (ADS)

Sabau, Adrian S.; Wright, Ian G.

2009-07-01

This paper presents results for the strains and stresses in oxide scales under the conditions of temperature and pressure expected in typical steam boiler operation. These conditions are radically different from those typically encountered in laboratory testing and include features such as a thermal gradient across the tube wall, significant internal (steam) pressure, and cycling of both steam temperature and pressure. Critical examination of the assumptions of flat-plate geometry, which is usually made in calculating stresses and strains in oxide scales, indicated that only the component of the hoop strain that generates stress must be reported for the cylindrical case, and that the use of simple plane-strain is adequate for the system studied. Calculations were made for alloy T22 with a hypothetical, single-layered oxide with appropriate properties. Typical conditions associated with transition of the boiler from full to partial load involve a decrease in both steam temperature and pressure, and these two sources of stress generation were found to exert opposite effects. The relative magnitudes of the resulting strains were used to explain the trends in strain levels calculated when the effects of thermal expansion, temperature loading, and pressure loading were superimposed.

Applications of Low Density Flow Techniques and Catalytic Recombination at the Johnson Space Center

NASA Technical Reports Server (NTRS)

Scott, Carl D.

2000-01-01

The talk presents a brief background on defInitions of catalysis and effects associated with chemically nonequilibrium and low-density flows of aerospace interest. Applications of catalytic recombination on surfaces in dissociated flow are given, including aero heating on reentry spacecraft thermal protection surfaces and reflection of plume flow on pressure distributions associated with the space station. Examples include aero heating predictions for the X-38 test vehicle, the inlet of a proposed gas-sampling probe used in high enthalpy test facilities, and a parabolic body at angle of attack. The effect of accommodation coefficients on thruster induced pressure distributions is also included. Examples of tools used include simple aero heating formulas based on boundary layer solutions, an engineering approximation that uses axisymmetric viscous shock layer flow to simulate full three dimensional flow, full computational fluid dynamics, and direct simulation Monte-Carlo calculations. Methods of determining catalytic recombination rates in arc jet flow are discus ed. An area of catalysis not fully understood is the formation of single-wall carbon nanotubes (SWNT) with gas phase or nano-size metal particles. The Johnson Space Center is making SWNTs using both a laser ablation technique and an electric arc vaporization technique.

Study on the Ag Nanowire/PDMS Pressure Sensors with Three-Layer and Back-to-Back Structures

NASA Astrophysics Data System (ADS)

Wu, Jianhao; Lan, Qiuming; Yang, Weijia; He, Xin; Yue, Yunting; Jiang, Jiayi; Jiang, Tinghui

2018-01-01

Ag nanowire (NW)/polydimethylsiloxane (PDMS) pressure sensors with the three-layer and back-to-back structures were fabricated by a coating-peeling method. The bending and pressing responses of the sensors were comparably investigated. The results reveal that two kinds of pressure sensors show similar response linearity in the bending test with a bending angle of 0-180°. However, the response sensitivity of the three-layer structured pressure sensor is superior to that of the back-to-back structural one, which exhibits that the relationship between the capacitance value (Y) and the bending angle (X) is: Y = 0.01244X + 2.9763. On the contrary, in the pressing test, the response sensitivity of the back-to-back structural sensor is better than that of the three-layer structural one. The relationship between capacitance value (Y) and the number of paper clips (pressure, X2) is Y = 0.09241X2 + 88.03597.

Instability of a shear layer between multicomponent fluids at supercritical pressure

NASA Astrophysics Data System (ADS)

Fu, Qing-fei; Zhang, Yun-xiao; Mo, Chao-jie; Yang, Li-jun

2018-04-01

The temporal instability of a thin shear layer lying between streams of two components of fluids has been studied. The effects of density profile of the layer on the instability behavior were mainly considered. The detailed density profile was obtained through Linear Gradient Theory. The eigenvalue problem was calculated, and the temporal instability curves were obtained for the thermodynamic parameters, e.g. pressure and temperature. The results show that, increase of pressure leads to the increase of the maximum growth rate. However, increasing pressure has opposite effects on the disturbances with small and large wave length. The increase of temperature causes the decrease of disturbance growth rate. The instability behavior of the shear layers was determined mainly by the interval between the inflections of the velocity and density profiles, and the maximum density gradient. The total effects, determined by coupling density stratification, and interval between the inflections of the velocity and density profiles, were quite distinct for different ranges of temperature and pressure.

Can single use negative pressure wound therapy be an alternative method to manage keloid scarring? A preliminary report of a clinical and ultrasound/colour-power-doppler study.

PubMed

Fraccalvieri, Marco; Sarno, Antonino; Gasperini, Stefano; Zingarelli, Enrico; Fava, Raffaella; Salomone, Marco; Bruschi, Stefano

2013-06-01

Keloid scarring represents a pathological healing where primary healing phenomenon is deviated from normal. Pico is a single use negative pressure wound therapy system originally introduced to manage open or just closed wounds. Pico dressing is made of silicone, and distributes an 80 mmHg negative pressure across wound bed. Combination of silicon layer and continuous compression could be a valid method to manage keloid scarring. Since November 2011, three patients were enrolled and evaluated before negative pressure treatment, at end of treatment (1 month) and 2 months later, through Vancouver Scar Scale (VSS), Visual Analog Scale (VAS) and a scoring system for itching. Ultrasound (US) and colour-power-doppler (CPD) examination was performed to evaluate thickness and vascularisation of the scar. One patient was discharged from study after 1 week. In last two patients, VSS, VAS and itching significantly improved after 1 month therapy and the results were stable after 2 months without any therapy. At end of therapy, the 'appearance of palisade vessels' disappeared in both cases at CPD exam; US showed a thickness reduction (average 43·8%). We propose a well-tolerated, non invasive treatment to manage keloid scarring. Prospective studies are necessary to investigate whether these preliminary observations are confirmed. © 2012 The Authors. International Wound Journal © 2012 John Wiley & Sons Ltd and Medicalhelplines.com Inc.

Ultrathin rhodium nanosheets.

PubMed

Duan, Haohong; Yan, Ning; Yu, Rong; Chang, Chun-Ran; Zhou, Gang; Hu, Han-Shi; Rong, Hongpan; Niu, Zhiqiang; Mao, Junjie; Asakura, Hiroyuki; Tanaka, Tsunehiro; Dyson, Paul Joseph; Li, Jun; Li, Yadong

2014-01-01

Despite significant advances in the fabrication and applications of graphene-like materials, it remains a challenge to prepare single-layered metallic materials, which have great potential applications in physics, chemistry and material science. Here we report the fabrication of poly(vinylpyrrolidone)-supported single-layered rhodium nanosheets using a facile solvothermal method. Atomic force microscope shows that the thickness of a rhodium nanosheet is <4 Å. Electron diffraction and X-ray absorption spectroscopy measurements suggest that the rhodium nanosheets are composed of planar single-atom-layered sheets of rhodium. Density functional theory studies reveal that the single-layered Rh nanosheet involves a δ-bonding framework, which stabilizes the single-layered structure together with the poly(vinylpyrrolidone) ligands. The poly(vinylpyrrolidone)-supported single-layered rhodium nanosheet represents a class of metallic two-dimensional structures that might inspire further fundamental advances in physics, chemistry and material science.

Direct Numerical Simulation of Acoustic Noise Generation from the Nozzle Wall of a Hypersonic Wind Tunnel

NASA Technical Reports Server (NTRS)

Huang, Junji; Duan, Lian; Choudhari, Meelan M.

2017-01-01

The acoustic radiation from the turbulent boundary layer on the nozzle wall of a Mach 6 Ludwieg Tube is simulated using Direct Numerical Simulations (DNS), with the flow conditions falling within the operational range of the Mach 6 Hypersonic Ludwieg Tube, Braunschweig (HLB). The mean and turbulence statistics of the nozzle-wall boundary layer show good agreement with those predicted by Pate's correlation and Reynolds Averaged Navier-Stokes (RANS) computations. The rms pressure fluctuation P'(rms)/T(w) plateaus in the freestream core of the nozzle. The intensity of the freestream noise within the nozzle is approximately 20% higher than that radiated from a single at pate with a similar freestream Mach number, potentially because of the contributions to the acoustic radiation from multiple azimuthal segments of the nozzle wall.

Investigation on single walled carbon nanotube thin films deposited by Langmuir Blodgett method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vishalli,, E-mail: vishalli-2008@yahoo.com; Dharamvir, Keya; Kaur, Ramneek

2015-05-15

Langmuir Blodgett is a technique to deposit a homogeneous film with a fine control over thickness and molecular organization. Thin films of functionalized SWCNTs have been prepared by Langmuir Blodgett method. The good surface spreading properties of SWCNTs at air/water interface are indicated by surface pressure-area isotherm and the monolayer formed on water surface is transferred onto the quartz substrate by vertical dipping. A multilayer film is thus obtained in a layer by layer manner. The film is characterized by Atomic Force Microscope (AFM), UV-Vis-NIR spectroscopy and FTIR.AFM shows the surface morphology of the deposited film. UV-Vis-NIR spectroscopy shows themore » characteristic peaks of semiconducting SWCNTs. The uniformity of LB film can be used further in understanding the optical and electrical behavior of these materials.« less

Axisymmetric computational fluid dynamics analysis of a film/dump-cooled rocket nozzle plume

NASA Technical Reports Server (NTRS)

Tucker, P. K.; Warsi, S. A.

1993-01-01

Prediction of convective base heating rates for a new launch vehicle presents significant challenges to analysts concerned with base environments. The present effort seeks to augment classical base heating scaling techniques via a detailed investigation of the exhaust plume shear layer of a single H2/O2 Space Transportation Main Engine (STME). Use of fuel-rich turbine exhaust to cool the STME nozzle presented concerns regarding potential recirculation of these gases to the base region with attendant increase in the base heating rate. A pressure-based full Navier-Stokes computational fluid dynamics (CFD) code with finite rate chemistry is used to predict plumes for vehicle altitudes of 10 kft and 50 kft. Levels of combustible species within the plume shear layers are calculated in order to assess assumptions made in the base heating analysis.

The Electric Honeycomb; an investigation of the Rose window instability

NASA Astrophysics Data System (ADS)

Niazi, Muhammad Shaheer

2017-10-01

The Rose window instability is a little-explored electrohydrodynamic instability that manifests when a layer of low-conducting oil is placed in an electric field generated by corona discharge in a point-to-plane configuration. Above a critical voltage, the instability starts as a single dimple in the oil layer right below the point electrode and subsequently evolves into a characteristic pattern of polygonal cells. In this study, we experimentally explore governing parameters that guide the instability and document geometric attributes of the characteristic cellular pattern. The driving force for the instability has been attributed to the buildup of charged ions which in turn apply an electric pressure on the oil surface. We confirm the charged surface distribution using thermal imaging and demonstrate that the instability can be locally inhibited by preventing charge buildup under an ion shadow.

The Electric Honeycomb; an investigation of the Rose window instability

PubMed Central

2017-01-01

The Rose window instability is a little-explored electrohydrodynamic instability that manifests when a layer of low-conducting oil is placed in an electric field generated by corona discharge in a point-to-plane configuration. Above a critical voltage, the instability starts as a single dimple in the oil layer right below the point electrode and subsequently evolves into a characteristic pattern of polygonal cells. In this study, we experimentally explore governing parameters that guide the instability and document geometric attributes of the characteristic cellular pattern. The driving force for the instability has been attributed to the buildup of charged ions which in turn apply an electric pressure on the oil surface. We confirm the charged surface distribution using thermal imaging and demonstrate that the instability can be locally inhibited by preventing charge buildup under an ion shadow. PMID:29134066

Microplasma Processed Ultrathin Boron Nitride Nanosheets for Polymer Nanocomposites with Enhanced Thermal Transport Performance.

PubMed

Zhang, Ri-Chao; Sun, Dan; Lu, Ai; Askari, Sadegh; Macias-Montero, Manuel; Joseph, Paul; Dixon, Dorian; Ostrikov, Kostya; Maguire, Paul; Mariotti, Davide

2016-06-01

This Research Article reports on the enhancement of the thermal transport properties of nanocomposite materials containing hexagonal boron nitride in poly(vinyl alcohol) through room-temperature atmospheric pressure direct-current microplasma processing. Results show that the microplasma treatment leads to exfoliation of the hexagonal boron nitride in isopropyl alcohol, reducing the number of stacks from >30 to a few or single layers. The thermal diffusivity of the resulting nanocomposites reaches 8.5 mm(2) s(-1), 50 times greater than blank poly(vinyl alcohol) and twice that of nanocomposites containing nonplasma treated boron nitride nanosheets. From TEM analysis, we observe much less aggregation of the nanosheets after plasma processing along with indications of an amorphous carbon interfacial layer, which may contribute to stable dispersion of boron nitride nanosheets in the resulting plasma treated colloids.

Layering garments during rest and exercise in the cold (8°C): wearer responses and comparability with selected fabric properties.

PubMed

MacRae, Braid A; Laing, Raechel M; Wilson, Cheryl A; Niven, Brian E

2014-01-01

How garments contribute to performance of the clothing system during wear is of interest, as is understanding the value of using fabric properties to inform end-use characteristics. To investigate the influences of layering upper-body garments, four fabrics were used to construct two first-layer garments (wool and polyester) and two outer-layer garments (wool and membrane laminate). Over six sessions, 10 moderately trained males wore each first-layer garment as a single layer and in combination with each outer-layer garment while resting, running and walking in cold environmental conditions (8 ± 1°C, 81 ± 4% RH). Here, the type of garment arrangement worn (fabric type or number of layers) had little influence on heart rate, core body temperature and change in body mass. Weighted mean covered skin temperature was warmer and weighted mean next-to-skin vapour pressure was typically higher (following the onset of exercise) with two layers versus one. Differences among fabrics for individual properties were typically overstated compared to differences among corresponding garments for physiological and psychophysical variables under the conditions of this study. These findings inform the interpretation of particular fabric properties and highlight issues to be acknowledged during development/refinement of fabric test methods. We examined the way in which selected fibre, fabric and garment (layering) characteristics contribute to performance of the clothing system during wear under cold conditions. Selected properties of the constituent fabrics were found to provide limited insight into how garments perform during wear under the conditions of this study.

The effects of micro-vortex generators on normal shock wave/boundary layer interactions

NASA Astrophysics Data System (ADS)

Herges, Thomas G.

Shock wave/boundary-layer interactions (SWBLIs) are complex flow phenomena that are important in the design and performance of internal supersonic and transonic flow fields such as engine inlets. This investigation was undertaken to study the effects of passive flow control devices on normal shock wave/boundary layer interactions in an effort to gain insight into the physics that govern these complex interactions. The work concentrates on analyzing the effects of vortex generators (VGs) as a flow control method by contributing a greater understanding of the flowfield generated by these devices and characterizing their effects on the SWBLI. The vortex generators are utilized with the goal of improving boundary layer health (i.e., reducing/increasing the boundary-layer incompressible shape factor/skin friction coefficient) through a SWBLI, increasing pressure recovery, and reducing flow distortion at the aerodynamic interface plane while adding minimal drag to the system. The investigation encompasses experiments in both small-scale and large-scale inlet testing, allowing multiple test beds for improving the characterization and understanding of vortex generators. Small-scale facility experiments implemented instantaneous schlieren photography, surface oil-flow visualization, pressure-sensitive paint, and particle image velocimetry to characterize the effects of an array of microramps on a normal shock wave/boundary-layer interaction. These diagnostics measured the time-averaged and instantaneous flow organization in the vicinity of the microramps and SWBLI. The results reveal that a microramp produces a complex vortex structure in its wake with two primary counter-rotating vortices surrounded by a train of Kelvin- Helmholtz (K-H) vortices. A streamwise velocity deficit is observed in the region of the primary vortices in addition to an induced upwash/downwash which persists through the normal shock with reduced strength. The microramp flow control also increased the spanwise-averaged skin-friction coefficient and reduced the spanwise-averaged incompressible shape factor, thereby improving the health of the boundary layer. The velocity in the near-wall region appears to be the best indicator of microramp effectiveness at controlling SWBLIs. Continued analysis of additional micro-vortex generator designs in the small-scale facility revealed reduced separation within a subsonic diffuser downstream of the normal shock wave/boundary layer interaction. The resulting attached flow within the diffuser from the micro-vortex generator control devices reduces shock wave position and pressure RMS fluctuations within the diffuser along with increased pressure recovery through the shock and at the entrance of the diffuser. The largest effect was observed by the micro-vortex generators that produce the strongest streamwise vortices. High-speed pressure measurements also indicated that the vortex generators shift the energy of the pressure fluctuations to higher frequencies. Implementation of micro-vortex generators into a large-scale, supersonic, axisymmetric, relaxed-compression inlet have been investigated with the use of a unique and novel flow-visualization measurement system designed and successfully used for the analysis of both upstream micro-VGs (MVGs) and downstream VGs utilizing surface oil-flow visualization and pressure-sensitive paint measurements. The inlet centerbody and downstream diffuser vortex-generator regions were imaged during wind-tunnel testing internally through the inlet cowl with the diagnostic system attached to the cowl. Surface-flow visualization revealed separated regions along the inlet centerbody for large mass-flow rates without vortex generators. Upstream vortex generators did reduce separation in the subsonic diffuser, and a unique perspective of the flowfield produced by the downstream vortex generators was obtained. In addition, pressure distributions on the inlet centerbody and vortex generators were measured with pressure-sensitive paint. At low mass-flow ratios the onset of buzz occurs in the large-scale low-boom inlet. Inlet buzz and how it is affected by vortex generators was characterized using shock tracking through high-speed schlieren imaging and pressure fluctuation measurements. The analysis revealed a dominant low frequency oscillation at 21.0 Hz for the single-stream inlet, corresponding with the duration of one buzz cycle. Pressure oscillations prior to the onset of buzz were not detected, leaving the location where the shock wave triggers large separation on the compression spike as the best indicator for the onset of buzz. The driving mechanism for a buzz cycle has been confirmed as the rate of depressurization and repressurization of the inlet as the buzz cycle fluctuates between an effectively unstarted (blocked) inlet and supercritical operation (choked flow), respectively. High-frequency shock position oscillations/pulsations (spike buzz) were also observed throughout portions of the inlet buzz cycle. The primary effect of the VGs was to trigger buzz at a higher mass-flow ratio.

Simulation of the Dynamics of Isothermal Growth of Single-Layer Graphene on a Copper Catalyst in the Process of Chemical Vapor Deposition of Hydrocarbons

NASA Astrophysics Data System (ADS)

Futko, S. I.; Shulitskii, B. G.; Labunov, V. A.; Ermolaeva, E. M.

2018-01-01

A new kinetic model of isothermal growth of single-layer graphene on a copper catalyst as a result of the chemical vapor deposition of hydrocarbons on it at a low pressure has been developed on the basis of in situ measurements of the growth of graphene in the process of its synthesis. This model defines the synthesis of graphene with regard for the chemisorption and catalytic decomposition of ethylene on the surface of a copper catalyst, the diffusion of carbon atoms in the radial direction to the nucleation centers within the thin melted near-surface copper layer, and the nucleation and autocatalytic growth of graphene domains. It is shown that the time dependence of the rate of growth of a graphene domain has a characteristic asymmetrical bell-like shape. The dependences of the surface area and size of a graphene domain and the rate of its growth on the time at different synthesis temperatures and ethylene concentrations have been obtained. Time characteristics of the growth of graphene domains depending on the parameters of their synthesis were calculated. The results obtained can be used for determining optimum regimes of synthesis of graphene in the process of chemical vapor deposition of hydrocarbons on different catalysts with a low solubility of carbon.

Open forum

NASA Technical Reports Server (NTRS)

1973-01-01

Some experiments on turbulent free shear layers in pressure gradients are discussed. Topics covered in the discussion include: (1) two dimensional vortex structures, (2) the effect of channel walls, and (3) the case of a mixing layer in pressure gradient.

Sustained compression and healing of chronic venous ulcers.

PubMed Central

Blair, S. D.; Wright, D. D.; Backhouse, C. M.; Riddle, E.; McCollum, C. N.

1988-01-01

STUDY OBJECTIVE--Comparison of four layer bandage system with traditional adhesive plaster bandaging in terms of (a) compression achieved and (b) healing of venous ulcers. DESIGN--Part of larger randomised trial of five different dressings. SETTING--Outpatient venous ulcer clinic in university hospital. PATIENTS--(a) Pressure exerted by both bandage systems was measured in the same 20 patients. (b) Healing with the four layer bandage was assessed in 148 legs in 126 consecutive patients (mean age 71 (SE 2); range 30-96) with chronic venous ulcers that had resisted treatment with traditional bandaging for a mean of 27.2 (SE 8) months. INTERVENTIONS--(a) Four layer bandage system or traditional adhesive plaster bandaging for pressure studies; (b) four layer bandaging applied weekly for studies of healing. END POINTS--(a) Comparison of pressures achieved at the ankle for up to one week; (b) complete healing within 12 weeks. MEASUREMENTS AND MAIN RESULTS--(a) Four layer bandage produced higher initial pressures at the ankle of 42.5 (SE 1) mm Hg compared with 29.8 (1.8) for the adhesive plaster (p less than 0.001; 95% confidence interval 18.5 to 6.9). Pressure was maintained for one week with the four layer bandage but fell to 10.4 (3.5) mm Hg at 24 hours with adhesive plaster bandaging. (b) After weekly bandaging with the four layer bandage 110 of 48 venous ulcers had healed completely within 12 (mean 6.3 (0.4)) weeks. CONCLUSION--Sustained compression of over 40 mm Hg achieved with a multilayer bandage results in rapid healing of chronic venous ulcers that have failed to heal in many months of compression at lower pressures with more conventional bandages. PMID:3144330

Uncertainty Analysis of the Grazing Flow Impedance Tube

NASA Technical Reports Server (NTRS)

Brown, Martha C.; Jones, Michael G.; Watson, Willie R.

2012-01-01

This paper outlines a methodology to identify the measurement uncertainty of NASA Langley s Grazing Flow Impedance Tube (GFIT) over its operating range, and to identify the parameters that most significantly contribute to the acoustic impedance prediction. Two acoustic liners are used for this study. The first is a single-layer, perforate-over-honeycomb liner that is nonlinear with respect to sound pressure level. The second consists of a wire-mesh facesheet and a honeycomb core, and is linear with respect to sound pressure level. These liners allow for evaluation of the effects of measurement uncertainty on impedances educed with linear and nonlinear liners. In general, the measurement uncertainty is observed to be larger for the nonlinear liners, with the largest uncertainty occurring near anti-resonance. A sensitivity analysis of the aerodynamic parameters (Mach number, static temperature, and static pressure) used in the impedance eduction process is also conducted using a Monte-Carlo approach. This sensitivity analysis demonstrates that the impedance eduction process is virtually insensitive to each of these parameters.

Unusual superconducting state at 49 K in electron-doped CaFe2As2 at ambient pressure

PubMed Central

Lv, Bing; Deng, Liangzi; Gooch, Melissa; Wei, Fengyan; Sun, Yanyi; Meen, James K.; Xue, Yu-Yi; Lorenz, Bernd; Chu, Ching-Wu

2011-01-01

We report the detection of unusual superconductivity up to 49 K in single crystalline CaFe2As2 via electron-doping by partial replacement of Ca by rare-earth. The superconducting transition observed suggests the possible existence of two phases: one starting at 49 K, which has a low critical field < 4 Oe, and the other at 21 K, with a much higher critical field > 5 T. Our observations are in strong contrast to previous reports of doping or pressurizing layered compounds AeFe2As2 (or Ae122), where Ae = Ca, Sr, or Ba. In Ae122, hole-doping has been previously observed to generate superconductivity with a transition temperature (Tc) only up to 38 K and pressurization has been reported to produce superconductivity with a Tc up to 30 K. The unusual 49 K phase detected will be discussed. PMID:21911404

Vacuum-sealed microcavity formed from suspended graphene by using a low-pressure dry-transfer technique

NASA Astrophysics Data System (ADS)

Takahashi, K.; Ishida, H.; Sawada, K.

2018-01-01

We report the development of a microcavity drum sealed by suspended graphene. The drum is fabricated by using a low-pressure dry-transfer technique, which involves vacuum de-aeration between a graphene sheet and a substrate and raising the temperature to above the glass transition of the supporting poly(methyl methacrylate) film, which serves to increase the real contact area. The result is a suspended graphene sheet with a maximum diameter of 48.6 μm. The Raman spectrum of the suspended graphene has a 2D/G ratio of 1.79 and a few D peaks, which suggests that the material is high-quality single-layer graphene. The dry-transfer technique yields a vacuum-sealed microcavity drum 1.1 μm deep up to 4.5 μm in diameter. The Raman shift indicates that the suspended graphene is subjected to a tensile strain of 0.05%, which is attributed to the pressure difference between the evacuated cavity and the exterior gas.

Sharply curved turn around duct flow predictions using spectral partitioning of the turbulent kinetic energy and a pressure modified wall law

NASA Technical Reports Server (NTRS)

Santi, L. Michael

1986-01-01

Computational predictions of turbulent flow in sharply curved 180 degree turn around ducts are presented. The CNS2D computer code is used to solve the equations of motion for two-dimensional incompressible flows transformed to a nonorthogonal body-fitted coordinate system. This procedure incorporates the pressure velocity correction algorithm SIMPLE-C to iteratively solve a discretized form of the transformed equations. A multiple scale turbulence model based on simplified spectral partitioning is employed to obtain closure. Flow field predictions utilizing the multiple scale model are compared to features predicted by the traditional single scale k-epsilon model. Tuning parameter sensitivities of the multiple scale model applied to turn around duct flows are also determined. In addition, a wall function approach based on a wall law suitable for incompressible turbulent boundary layers under strong adverse pressure gradients is tested. Turn around duct flow characteristics utilizing this modified wall law are presented and compared to results based on a standard wall treatment.

The aerodynamic characteristics of large angled cones with retrorockets

NASA Technical Reports Server (NTRS)

Jarvinen, P. O.; Adams, R. H.

1970-01-01

Analytical and experimental phases of the subject investigation are described. The analytical program for the single jet determines the terminal shock location, the jet boundary, the interface profile, the bow shock profile, the shear layer growth and the dead air region pressure. The experimental program described was conducted over the range from free stream Mach 0.4 to 2.0 at angles-of-attack up to 18 deg and at thrusting coefficients up to C sub T = T/q sub infinity A sub m = 30. Variables investigated included aeroshell angle, number of nozzles, engine thrust, size of nozzles, nozzle throttling and gas composition. The influence of these variables on the aeroshell stability, drag, and loads was determined by integrating pressure measurements on the aeroshell. The total system forces consist of components due to pure thrust and components due to pressure on the aeroshell arising from the jet-free stream interaction. Shadowgraphs provided flow field geometries which proved to be within 10% of those predicted analytically.

Settling and compaction of olivine in basaltic magmas: an experimental study on the time scales of cumulate formation

NASA Astrophysics Data System (ADS)

Schmidt, Max W.; Forien, Melanie; Solferino, Giulio; Bagdassarov, Nickolai

2012-12-01

A series of centrifuge-assisted settling experiments of 30 vol % olivine in 70 vol % basaltic melt was conducted to elucidate the formation mechanisms and time scales of gravitational cumulates. The settling experiments were performed in a centrifuging piston cylinder at 200-1,500 g, 1,270-1,280 °C, and 0.8-1.1 GPa on previously annealed and texturally equilibrated samples. The mechanical settling of the dense olivine suspension occurs at about 1/6 the speed of simple Stokes settling, resulting in a sedimentation exponent n = 4.1(6) in agreement with predictions from analogue systems. The porosity (φ m ) of the orthocumulate resulting from gravitational settling of crystals is about 54 % and formation times of olivine orthocumulates result to 0.1-10 m day-1 (for an initial crystal content of the melt of 1-5 % and grain sizes of 2-10 mm). After mechanical settling, olivine grains rest on each other, and further compaction occurs through pressure dissolution at grain contacts, olivine reprecipitation where olivine is in contact with melt, and concomitant expulsion of excess liquid from the cumulate layer. With centrifugation at 400 g for 50 h, porosities as low as 30.3 vol % were achieved. The olivine content at the bottom of the gravitational cumulate is 1 - φm ~ log(Δρ · h · a · t), where Δρ is the density difference between crystals and melt, h the crystal layer thickness, a the acceleration, and t the time of centrifuging. Compaction is hence proportional to effective stress integrated over time indicating that pressure dissolution is the dominant mechanism for chemical compaction. The compaction limit, that is the lowermost porosity to be reached by this mechanism, is calculated by equating the lithostatic and hydraulic pressure gradients in the cumulate and results to 3-5 % porosity for the experiments. Crystal size distribution curves and a growth exponent n of 3.1(3) indicate that diffusion-controlled Ostwald ripening is the dominant crystal growth mechanism. The above relationship, combined with a linear scaling for grain size as appropriate for reaction-controlled pressure solution creep, allows calculation of formation times of adcumulates. If chemical compaction is dissolution-reprecipitation limited, then single layers of natural olivine adcumulates of ½ m thickness with 70-75 vol % olivine at the base (as observed in the Rhum layered intrusion) would have typical formation times of 0.4-3 years for grain sizes of 2-10 mm. This time scale compares favourably with characteristic cooling times of sills. If a greater than 20-m-thick series of cumulate layers pressurizes a base layer with the porosity still filled by a melt, then compaction proceeds to the compaction limit within a few years. It can thus be expected that in layered mafic intrusions where cumulates are continuously deposited from a large magma chamber and which characteristic cooling times of more than decades, a compaction zone of several tens of metres forms with adcumulates only maintaining porosities in the order of 5 %. In conclusion, gravitational settling and gravitation-driven chemical compaction are feasible cumulate-forming processes for dense mafic minerals in basaltic magmas and in particular in large layered intrusions.

Some Simple Solutions to the Problem of Predicting Boundary-Layer Self-Induced Pressures

NASA Technical Reports Server (NTRS)

Bertram, Mitchel H.; Blackstock, Thomas A.

1961-01-01

Simplified theoretical approaches are shown, based on hypersonic similarity boundary-layer theory, which allow reasonably accurate estimates to be made of the surface pressures on plates on which viscous effects are important. The consideration of viscous effects includes the cases where curved surfaces, stream pressure gradients, and leadingedge bluntness are important factors.

Venting test analysis using Jacob`s approximation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, K.B.

1996-03-01

There are many sites contaminated by volatile organic compounds (VOCs) in the US and worldwide. Several technologies are available for remediation of these sites, including excavation, pump and treat, biological treatment, air sparging, steam injection, bioventing, and soil vapor extraction (SVE). SVE is also known as soil venting or vacuum extraction. Field venting tests were conducted in alluvial sands residing between the water table and a clay layer. Flow rate, barometric pressure, and well-pressure data were recorded using pressure transmitters and a personal computer. Data were logged as frequently as every second during periods of rapid change in pressure. Testsmore » were conducted at various extraction rates. The data from several tests were analyzed concurrently by normalizing the well pressures with respect to extraction rate. The normalized pressures vary logarithmically with time and fall on one line allowing a single match of the Jacob approximation to all tests. Though the Jacob approximation was originally developed for hydraulic pump test analysis, it is now commonly used for venting test analysis. Only recently, however, has it been used to analyze several transient tests simultaneously. For the field venting tests conducted in the alluvial sands, the air permeability and effective porosity determined from the concurrent analysis are 8.2 {times} 10{sup {minus}7} cm{sup 2} and 20%, respectively.« less

Comparison of the initial development of shear layers in two-dimensional and axisymmetric ejector configurations

NASA Technical Reports Server (NTRS)

Dufflocq, M.; Benjamin, M. A.; Roan, V. P.

1993-01-01

A two-phase experimental investigation designed to study the development of shear layers in axisymmetric and two-dimensional single-nozzle ejectors has been completed. In this study, combinations of similar and dissimilar gases were used as the supersonic primary and subsonic secondary. Test cases included combinations of air/air, argon/air and helium/air as the supersonic primary and subsonic secondary, respectively. Similar flow conditions were studied for each ejector configuration. Mixing of the gases occurred in a constant-area tube, where the inlet pressure was maintained at 34.5 kPa. The cases studied resulted in convective Mach numbers that range between 0.06 and 1.9. The data gathered shows differences between the initial shear-layer development for the two ejector geometries, and also between the different test cases studied for each ejector configuration. The measured growth rates for the axisymmetric ejector are more than twice those measured for the two-dimensional ejector. However, in both cases the results show that compressibility has a reducing effect on the growth rate. Further, in the region immediately after the inlet to the mixing tube, compressibility seems to affect the ejector shear layers in a manner similar to that of two-stream two-dimensional mixing layers.

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices

NASA Astrophysics Data System (ADS)

Lee, Ho Nyung; Christen, Hans M.; Chisholm, Matthew F.; Rouleau, Christopher M.; Lowndes, Douglas H.

2005-01-01

Theoretical predictions-motivated by recent advances in epitaxial engineering-indicate a wealth of complex behaviour arising in superlattices of perovskite-type metal oxides. These include the enhancement of polarization by strain and the possibility of asymmetric properties in three-component superlattices. Here we fabricate superlattices consisting of barium titanate (BaTiO3), strontium titanate (SrTiO3) and calcium titanate (CaTiO3) with atomic-scale control by high-pressure pulsed laser deposition on conducting, atomically flat strontium ruthenate (SrRuO3) layers. The strain in BaTiO3 layers is fully maintained as long as the BaTiO3 thickness does not exceed the combined thicknesses of the CaTiO3 and SrTiO3 layers. By preserving full strain and combining heterointerfacial couplings, we find an overall 50% enhancement of the superlattice global polarization with respect to similarly grown pure BaTiO3, despite the fact that half the layers in the superlattice are nominally non-ferroelectric. We further show that even superlattices containing only single-unit-cell layers of BaTiO3 in a paraelectric matrix remain ferroelectric. Our data reveal that the specific interface structure and local asymmetries play an unexpected role in the polarization enhancement.

Applying a uniform layer of disinfectant by wiping.

PubMed

Cooper, D W

2000-01-01

Disinfection or sterilization often requires applying a film of liquid to a surface, frequently done by using a wiper as the applicator. The wiper must not only hold a convenient amount of liquid, it must deposit it readily and uniformly. Contact time is critical to disinfection efficacy. Evaporation can limit the contact time. To lengthen the contact time, thickly applied layers are generally preferred. The thickness of such layers can be determined by using dyes or other tracers, as long as the tracers do not significantly affect the liquid's surface tension and viscosity and thus do not affect the thickness of the applied layer. Alternatively, as done here, the thickness of the layer can be inferred from the weight loss of the wiper. Results are reported of experiments on thickness of the layers applied under various conditions. Near saturation, hydrophilic polyurethane foam wipers gave layers roughly 10 microns thick, somewhat less than expected from hydrodynamic theory, but more than knitted polyester or woven cotton. Wipers with large liquid holding capacity, refilled often, should produce more nearly uniform layers. Higher pressures increase saturation in the wiper, tending to thicken the layer, but higher pressures also force liquid from the interface, tending to thin the layer, so the net result could be thicker or thinner layers, and there is likely to be an optimal pressure.

User's manual for three dimensional boundary layer (BL3-D) code

NASA Technical Reports Server (NTRS)

Anderson, O. L.; Caplin, B.

1985-01-01

An assessment has been made of the applicability of a 3-D boundary layer analysis to the calculation of heat transfer, total pressure losses, and streamline flow patterns on the surface of both stationary and rotating turbine passages. In support of this effort, an analysis has been developed to calculate a general nonorthogonal surface coordinate system for arbitrary 3-D surfaces and also to calculate the boundary layer edge conditions for compressible flow using the surface Euler equations and experimental data to calibrate the method, calculations are presented for the pressure endwall, and suction surfaces of a stationary cascade and for the pressure surface of a rotating turbine blade. The results strongly indicate that the 3-D boundary layer analysis can give good predictions of the flow field, loss, and heat transfer on the pressure, suction, and endwall surface of a gas turbine passage.

Unsteady separation and vortex shedding from a laminar separation bubble over a bluff body

NASA Astrophysics Data System (ADS)

Das, S. P.; Srinivasan, U.; Arakeri, J. H.

2013-07-01

Boundary layers are subject to favorable and adverse pressure gradients because of both the temporal and spatial components of the pressure gradient. The adverse pressure gradient may cause the flow to separate. In a closed loop unsteady tunnel we have studied the initiation of separation in unsteady flow past a constriction (bluff body) in a channel. We have proposed two important scalings for the time when boundary layer separates. One is based on the local pressure gradient and the other is a convective time scale based on boundary layer parameters. The flow visualization using a dye injection technique shows the flow structure past the body. Nondimensional shedding frequency (Strouhal number) is calculated based on boundary layer and momentum thicknesses. Strouhal number based on the momentum thickness shows a close agreement with that for flat plate and circular cylinder.

Control and reduction of unsteady pressure loads in separated shock wave turbulent boundary layer interaction

NASA Technical Reports Server (NTRS)

Dolling, David S.; Barter, John W.

1995-01-01

The focus was on developing means of controlling and reducing unsteady pressure loads in separated shock wave turbulent boundary layer interactions. Section 1 describes how vortex generators can be used to effectively reduce loads in compression ramp interaction, while Section 2 focuses on the effects of 'boundary-layer separators' on the same interaction.

Single-layer group IV-V and group V-IV-III-VI semiconductors: Structural stability, electronic structures, optical properties, and photocatalysis

NASA Astrophysics Data System (ADS)

Lin, Jia-He; Zhang, Hong; Cheng, Xin-Lu; Miyamoto, Yoshiyuki

2017-07-01

Recently, single-layer group III monochalcogenides have attracted both theoretical and experimental interest at their potential applications in photonic devices, electronic devices, and solar energy conversion. Excited by this, we theoretically design two kinds of highly stable single-layer group IV-V (IV =Si ,Ge , and Sn; V =N and P) and group V-IV-III-VI (IV =Si ,Ge , and Sn; V =N and P; III =Al ,Ga , and In; VI =O and S) compounds with the same structures with single-layer group III monochalcogenides via first-principles simulations. By using accurate hybrid functional and quasiparticle methods, we show the single-layer group IV-V and group V-IV-III-VI are indirect bandgap semiconductors with their bandgaps and band edge positions conforming to the criteria of photocatalysts for water splitting. By applying a biaxial strain on single-layer group IV-V, single-layer group IV nitrides show a potential on mechanical sensors due to their bandgaps showing an almost linear response for strain. Furthermore, our calculations show that both single-layer group IV-V and group V-IV-III-VI have absorption from the visible light region to far-ultraviolet region, especially for single-layer SiN-AlO and SnN-InO, which have strong absorption in the visible light region, resulting in excellent potential for solar energy conversion and visible light photocatalytic water splitting. Our research provides valuable insight for finding more potential functional two-dimensional semiconductors applied in optoelectronics, solar energy conversion, and photocatalytic water splitting.

Optimal Disturbances in Boundary Layers Subject to Streamwise Pressure Gradient

NASA Technical Reports Server (NTRS)

Ashpis, David E.; Tumin, Anatoli

2003-01-01

An analysis of the non-modal growth of perturbations in a boundary layer in the presence of a streamwise pressure gradient is presented. The analysis is based on PSE equations for an incompressible fluid. Examples with Falkner- Skan profiles indicate that a favorable pressure gradient decreases the non-modal growth while an unfavorable pressure gradient leads to an increase of the amplification. It is suggested that the transient growth mechanism be utilized to choose optimal parameters of tripping elements on a low-pressure turbine (LPT) airfoil. As an example, a boundary-layer flow with a streamwise pressure gradient corresponding to the pressure distribution over a LPT airfoil is considered. It is shown that there is an optimal spacing of the tripping elements and that the transient growth effect depends on the starting point. The amplification is found to be small at the LPT s very low Reynolds numbers, but there is a possibility to enhance the transient energy growth by means of wall cooling.

High-pressure X-ray diffraction, Raman, and computational studies of MgCl2 up to 1 Mbar: Extensive pressure stability of the β-MgCl2 layered structure.

PubMed

Stavrou, Elissaios; Yao, Yansun; Zaug, Joseph M; Bastea, Sorin; Kalkan, Bora; Konôpková, Zuzana; Kunz, Martin

2016-08-12

Magnesium chloride (MgCl2) with the rhombohedral layered CdCl2-type structure (α-MgCl2) has been studied experimentally using synchrotron angle-dispersive powder x-ray diffraction and Raman spectroscopy using a diamond-anvil cell up to 100 GPa at room temperature and theoretically using first-principles density functional calculations. The results reveal a pressure-induced second-order structural phase transition to a hexagonal layered CdI2-type structure (β-MgCl2) at 0.7 GPa: the stacking sequence of the Cl anions are altered resulting in a reduction of the c-axis length. Theoretical calculations confirm this phase transition sequence and the calculated transition pressure is in excellent agreement with the experiment. Lattice dynamics calculations also reproduce the experimental Raman spectra measured for the ambient and high-pressure phase. According to our experimental results MgCl2 remains in a 2D layered phase up to 100 GPa and further, the 6-fold coordination of Mg cations is retained. Theoretical calculations of relative enthalpy suggest that this extensive pressure stability is due to a low enthalpy of the layered structure ruling out kinetic barrier effects. This observation is unusual, as it contradicts with the general structural behavior of highly compressed AB2 compounds.

High-pressure X-ray diffraction, Raman, and computational studies of MgCl 2 up to 1 Mbar: Extensive pressure stability of the β-MgCl 2 layered structure

DOE PAGES

Stavrou, Elissaios; Yao, Yansun; Zaug, Joseph M.; ...

2016-08-12

We studied magnesium chloride (MgCl 2) with the rhombohedral layered CdCl 2-type structure (α-MgCl 2), experimentally, using synchrotron angle-dispersive powder x-ray diffraction and Raman spectroscopy using a diamond-anvil cell up to 100 GPa at room temperature and theoretically using first-principles density functional calculations. Our results reveal a pressure-induced second-order structural phase transition to a hexagonal layered CdI 2-type structure (β-MgCl 2) at 0.7 GPa: the stacking sequence of the Cl anions are altered resulting in a reduction of the c-axis length. Theoretical calculations confirm this phase transition sequence and the calculated transition pressure is in excellent agreement with the experiment.more » Lattice dynamics calculations also reproduce the experimental Raman spectra measured for the ambient and high-pressure phase. According to our experimental results MgCl 2 remains in a 2D layered phase up to 100 GPa and further, the 6-fold coordination of Mg cations is retained. Theoretical calculations of relative enthalpy suggest that this extensive pressure stability is due to a low enthalpy of the layered structure ruling out kinetic barrier effects. Our observation is unusual, as it contradicts with the general structural behavior of highly compressed AB 2 compounds.« less

Nitro stretch probing of a single molecular layer to monitor shock compression with picosecond time resolution

NASA Astrophysics Data System (ADS)

Berg, Christopher; Lagutchev, Alexei; Fu, Yuanxi; Dlott, Dana

2012-03-01

Ultrafast shock compression vibrational spectroscopy experiments with molecular monolayers provide atomic-scale time and space resolution, which enables critical testing of reactive molecular simulations. Since the origination of this project, we have greatly improved the ability to detect shocked monolayers by nonlinear coherent vibrational spectroscopy with nonresonant suppression. In this study, we show new results on a nitroaromatic monolayer, where the nitro symmetric stretch is probed. A small frequency blue-shift under shock conditions compared to measurements with static high pressure shows the shock is ~1 GPa. The ability to flash-preheat the monolayer by several hundred K is demonstrated. In order to observe shock monolayer chemistry in real time, along with pre-heating, the shock pressure needs to be increased and methods to do so are described.

Electronic localization in an extreme 1-D conductor: the organic salt (TTDM-TTF) [Au(mnt)

NASA Astrophysics Data System (ADS)

Lopes, E. B.; Alves, H.; Ribera, E.; Mas-Torrent, M.; Auban-Senzier, P.; Canadell, E.; Henriques, R. T.; Almeida, M.; Molins, E.; Veciana, J.; Rovira, C.; Jérome, D.

2002-09-01

This article reports the investigation of a new low-dimensional organic salt, (TTDM-TTF)2 [ Au(mnt)2] , by single crystal X-ray diffraction, static magnetic susceptibility, EPR, thermopower, electrical resistivity measurements under pressure up to 25 kbar and band structure calculations. The crystal structure consists in a dimerized head to tail stacking of TTDM-TTF molecules separated by layers of orthogonal Au(mnt)2 anions. The absence of overlap between neighboring chains coming from this particular crystal structure leads to an extreme one-dimensionality (1-D) for which the carriers of the half-filled conduction band become strongly localized in a Mott-Hubbard insulating state. This material is the first 1-D conductor in which the Mott-Hubbard insulating character cannot be suppressed under pressure.

Multiparametric AFM reveals turgor-responsive net-like peptidoglycan architecture in live streptococci

NASA Astrophysics Data System (ADS)

Saar Dover, Ron; Bitler, Arkady; Shimoni, Eyal; Trieu-Cuot, Patrick; Shai, Yechiel

2015-05-01

Cell-wall peptidoglycan (PG) of Gram-positive bacteria is a strong and elastic multi-layer designed to resist turgor pressure and determine the cell shape and growth. Despite its crucial role, its architecture remains largely unknown. Here using high-resolution multiparametric atomic force microscopy (AFM), we studied how the structure and elasticity of PG change when subjected to increasing turgor pressure in live Group B Streptococcus. We show a new net-like arrangement of PG, which stretches and stiffens following osmotic challenge. The same structure also exists in isogenic mutants lacking surface appendages. Cell aging does not alter the elasticity of the cell wall, yet destroys the net architecture and exposes single segmented strands with the same circumferential orientation as predicted for intact glycans. Together, we show a new functional PG architecture in live Gram-positive bacteria.

Pressure-induced spin reorientation transition in layered ferromagnetic insulator Cr2Ge2Te6

NASA Astrophysics Data System (ADS)

Lin, Zhisheng; Lohmann, Mark; Ali, Zulfikhar A.; Tang, Chi; Li, Junxue; Xing, Wenyu; Zhong, Jiangnan; Jia, Shuang; Han, Wei; Coh, Sinisa; Beyermann, Ward; Shi, Jing

2018-05-01

The anisotropic magnetoresistance (AMR) of Cr2Ge2Te6 (CGT), a layered ferromagnetic insulator, is investigated under an applied hydrostatic pressure up to 2 GPa. The easy-axis direction of the magnetization is inferred from the AMR saturation feature in the presence and absence of an applied pressure. At zero applied pressure, the easy axis is along the c direction or perpendicular to the layer. Upon application of a hydrostatic pressure > 1 GPa, the uniaxial anisotropy switches to easy-plane anisotropy which drives the equilibrium magnetization from the c axis to the a b plane at zero magnetic field, which amounts to a giant magnetic anisotropy energy change (> 100%). As the temperature is increased across the Curie temperature, the characteristic AMR effect gradually decreases and disappears. Our first-principles calculations confirm the giant magnetic anisotropy energy change with moderate pressure and assign its origin to the increased off-site spin-orbit interaction of Te atoms due to a shorter Cr-Te distance. Such a pressure-induced spin reorientation transition is very rare in three-dimensional ferromagnets, but it may be common to other layered ferromagnets with similar crystal structures to CGT, and therefore offers a unique way to control magnetic anisotropy.

Very low temperature (450 °C) selective epitaxial growth of heavily in situ boron-doped SiGe layers

NASA Astrophysics Data System (ADS)

Aubin, J.; Hartmann, J. M.; Veillerot, M.; Essa, Z.; Sermage, B.

2015-11-01

We have investigated the feasibility of selectively growing SiGe:B layers at 450 °C, 20 Torr in a 300 mm industrial reduced pressure chemical vapor deposition tool. A reduced H2 carrier gas mass-flow has been used in order to have acceptable growth rates at such a temperature, which is very low indeed. We have first of all studied on blanket Si wafers the in situ boron doping of SiGe with Si2H6, GeH4 and B2H6. A growth rate increase by a factor close to 7 together with a Ge concentration decrease from 53% down to 32% occurred as the diborane mass-flow increased. Very high B+ ion concentrations were obtained in layers that were single crystalline and smooth. Their concentration increased almost linearly with the B2H6 mass-flow, from 1.8 up to 8.3 × 1020 cm-3. The associated resistivity dropped from 0.43 down to 0.26 mΩ cm. We have then tested whether or not selectivity versus SiO2 could be achieved by adding various amounts of HCl to Si2H6 + GeH4 +B2H6. Single crystalline growth rates of intrinsic SiGe(:B) on Si were very similar to poly-crystalline growth rates on SiO2-covered substrates irrespective of the HCl flow. Straightforward selectivity was thus not feasible with a co-flow approach. As a consequence, a 450 °C deposition/etch (DE) process was evaluated. Growth occurred at 20 Torr with the above-mentioned chemistry, while the selective etch of poly-SiGe:B versus c-SiGe:B was conducted at 740 Torr with a medium HCl mass-flow (F(HCl)/F(H2) = 0.2) and a high H2 flow. A 2.2 etch selectivity was achieved while retaining single crystalline if slightly rough SiGe:B layers.

Mach 4 Test Results of a Dual-Flowpath, Turbine Based Combined Cycle Inlet

NASA Technical Reports Server (NTRS)

Albertson, Cindy w.; Emami, Saied; Trexler, Carl A.

2006-01-01

An experimental study was conducted to evaluate the performance of a turbine based combined cycle (TBCC) inlet concept, consisting of a low speed turbojet inlet and high speed dual-mode scramjet inlet. The main objectives of the study were (1) to identify any interactions between the low and the high speed inlets during the mode transition phase in which both inlets are operating simultaneously and (2) to determine the effect of the low speed inlet operation on the performance of the high speed inlet. Tests were conducted at a nominal freestream Mach number of 4 using an 8 percent scale model representing a single module of a TBCC inlet. A flat plate was installed upstream of the model to produce a turbulent boundary layer which simulated the full-scale vehicle forebody boundary layer. A flowmeter/back pressure device, with remote actuation, was attached aft of the high speed inlet isolator to simulate the back pressure resulting from dual-mode scramjet combustion. Results indicate that the inlets did not interact with each other sufficiently to affect inlet operability. Flow spillage resulting from a high speed inlet unstart did not propagate far enough upstream to affect the low speed inlet. Also, a low speed inlet unstart did not cause the high speed inlet to unstart. The low speed inlet improved the performance of the high speed inlet at certain conditions by diverting a portion of the boundary layer generated on the forebody plate.

Testing and Performance Verification of a High Bypass Ratio Turbofan Rotor in an Internal Flow Component Test Facility

NASA Technical Reports Server (NTRS)

VanZante, Dale E.; Podboy, Gary G.; Miller, Christopher J.; Thorp, Scott A.

2009-01-01

A 1/5 scale model rotor representative of a current technology, high bypass ratio, turbofan engine was installed and tested in the W8 single-stage, high-speed, compressor test facility at NASA Glenn Research Center (GRC). The same fan rotor was tested previously in the GRC 9x15 Low Speed Wind Tunnel as a fan module consisting of the rotor and outlet guide vanes mounted in a flight-like nacelle. The W8 test verified that the aerodynamic performance and detailed flow field of the rotor as installed in W8 were representative of the wind tunnel fan module installation. Modifications to W8 were necessary to ensure that this internal flow facility would have a flow field at the test package that is representative of flow conditions in the wind tunnel installation. Inlet flow conditioning was designed and installed in W8 to lower the fan face turbulence intensity to less than 1.0 percent in order to better match the wind tunnel operating environment. Also, inlet bleed was added to thin the casing boundary layer to be more representative of a flight nacelle boundary layer. On the 100 percent speed operating line the fan pressure rise and mass flow rate agreed with the wind tunnel data to within 1 percent. Detailed hot film surveys of the inlet flow, inlet boundary layer and fan exit flow were compared to results from the wind tunnel. The effect of inlet casing boundary layer thickness on fan performance was quantified. Challenges and lessons learned from testing this high flow, low static pressure rise fan in an internal flow facility are discussed.

Supersonic Wind Tunnel Tests of a Half-axisymmetric 12 Deg-spike Inlet to a Rocket-based Combined-cycle Propulsion System

NASA Technical Reports Server (NTRS)

DeBonis, J. R.; Trefny, C. J.

2001-01-01

Results of an isolated inlet test for NASA's GTX air-breathing launch vehicle concept are presented. The GTX is a Vertical Take-off/ Horizontal Landing reusable single-stage-to-orbit system powered by a rocket-based combined-cycle propulsion system. Tests were conducted in the NASA Glenn 1- by 1-Foot Supersonic Wind Tunnel during two entries in October 1998 and February 1999. Tests were run from Mach 2.8 to 6. Integrated performance parameters and static pressure distributions are reported. The maximum contraction ratios achieved in the tests were lower than predicted by axisymmetric Reynolds-averaged Navier-Stokes computational fluid dynamics (CFD). At Mach 6, the maximum contraction ratio was roughly one-half of the CFD value of 16. The addition of either boundary-layer trip strips or vortex generators had a negligible effect on the maximum contraction ratio. A shock boundary-layer interaction was also evident on the end-walls that terminate the annular flowpath cross section. Cut-back end-walls, designed to reduce the boundary-layer growth upstream of the shock and minimize the interaction, also had negligible effect on the maximum contraction ratio. Both the excessive turning of low-momentum comer flows and local over-contraction due to asymmetric end-walls were identified as possible reasons for the discrepancy between the CFD predictions and the experiment. It is recommended that the centerbody spike and throat angles be reduced in order to lessen the induced pressure rise. The addition of a step on the cowl surface, and planar end-walls more closely approximating a plane of symmetry are also recommended. Provisions for end-wall boundary-layer bleed should be incorporated.

Large-eddy simulations of adverse pressure gradient turbulent boundary layers

NASA Astrophysics Data System (ADS)

Bobke, Alexandra; Vinuesa, Ricardo; Örlü, Ramis; Schlatter, Philipp

2016-04-01

Adverse pressure-gradient (APG) turbulent boundary layers (TBL) are studied by performing well-resolved large-eddy simulations. The pressure gradient is imposed by defining the free-stream velocity distribution with the description of a power law. Different inflow conditions, box sizes and upper boundary conditions are tested in order to determine the final set-up. The statistics of turbulent boundary layers with two different power-law coefficients and thus magnitudes of adverse pressure gradients are then compared to zero pressure-gradient (ZPG) data. The effect of the APG on TBLs is manifested in the mean flow through a much more prominent wake region and in the Reynolds stresses through the existence of an outer peak. The pre-multiplied energy budgets show that more energy is transported from the near-wall region to farther away from the wall.

Base Pressure at Supersonic Speeds on Two-dimensional Airfoils and on Bodies of Revolution with and Without Fins Having Turbulent Boundary Layers

NASA Technical Reports Server (NTRS)

LOVE EUGENE S

1957-01-01

An analysis has been made of available experimental data to show the effects of most of the variables that are more predominant in determining base pressure at supersonic speeds. The analysis covers base pressures for two-dimensional airfoils and for bodies of revolution with and without stabilizing fins and is restricted to turbulent boundary layers. The present status of available experimental information is summarized as are the existing methods for predicting base pressure. A simple semiempirical method is presented for estimating base pressure. For two-dimensional bases, this method stems from an analogy established between the base-pressure phenomena and the peak pressure rise associated with the separation of the boundary layer. An analysis made for axially symmetric flow indicates that the base pressure for bodies of revolution is subject to the same analogy. Based upon the methods presented, estimations are made of such effects as Mach number, angle of attack, boattailing, fineness ratio, and fins. These estimations give fair predictions of experimental results. (author)

On the Unsteadiness of a Transitional Shock Wave-Boundary Layer Interaction Using Fast-Response Pressure-Sensitive Paint

NASA Astrophysics Data System (ADS)

Lash, E. Lara; Schmisseur, John

2017-11-01

Pressure-sensitive paint has been used to evaluate the unsteady dynamics of transitional and turbulent shock wave-boundary layer interactions generated by a vertical cylinder on a flat plate in a Mach 2 freestream. The resulting shock structure consists of an inviscid bow shock that bifurcates into a separation shock and trailing shock. The primary features of interest are the separation shock and an upstream influence shock that is intermittently present in transitional boundary layer interactions, but not observed in turbulent interactions. The power spectral densities, frequency peaks, and normalized wall pressures are analyzed as the incoming boundary layer state changes from transitional to fully turbulent, comparing both centerline and outboard regions of the interaction. The present study compares the scales and frequencies of the dynamics of the separation shock structure in different boundary layer regimes. Synchronized high-speed Schlieren imaging provides quantitative statistical analyses as well as qualitative comparisons to the fast-response pressure sensitive paint measurements. Materials based on research supported by the U.S. Office of Naval Research under Award Number N00014-15-1-2269.

Two-phase convection in the high-pressure ice layer of the large icy moons: geodynamical implications

NASA Astrophysics Data System (ADS)

Kalousova, K.; Sotin, C.; Tobie, G.; Choblet, G.; Grasset, O.

2015-12-01

The H2O layers of large icy satellites such as Ganymede, Callisto, or Titan probably include a liquid water ocean sandwiched between the deep high-pressure ice layer and the outer ice I shell [1]. It has been recently suggested that the high-pressure ice layer could be decoupled from the silicate core by a salty liquid water layer [2]. However, it is not clear whether accumulation of liquids at the bottom of the high-pressure layer is possible due to positive buoyancy of water with respect to high-pressure ice. Numerical simulation of this two-phase (i.e. ice and water) problem is challenging, which explains why very few studies have self-consistently handled the presence and transport of liquids within the solid ice [e.g. 3]. While using a simplified description of water production and transport, it was recently showed in [4] that (i) a significant fraction of the high-pressure layer reaches the melting point and (ii) the melt generation and its extraction to the overlying ocean significantly influence the global thermal evolution and interior structure of the large icy moons.Here, we treat the high-pressure ice layer as a compressible mixture of solid ice and liquid water [5]. Several aspects are investigated: (i) the effect of the water formation on the vigor of solid-state convection and its influence on the amount of heat that is transferred from the silicate mantle to the ocean; (ii) the fate of liquids within the upper thermal boundary layer - whether they freeze or reach the ocean; and (iii) the effect of salts and volatile compounds (potentially released from the rocky core) on the melting/freezing processes. Investigation of these aspects will allow us to address the thermo-chemical evolution of the internal ocean which is crucial to evaluate the astrobiological potential of large icy moons. This work has been performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract to NASA. [1] Hussmann et al. (2007), Treatise of Geophysics, 10.15, 509-539. [2] Vance et al. (2014), Planet. Space Sci., 96, 62-70. [3] Kalousova et al. (2014), J. Geophys. Res. Planets, 119(3), 532-549. [4] Tobie et al. (2014), AGU, P43C-3999. [5] Soucek et al. (2014), Geophys. Astro. Fluid, 108(6), 639-666.

Cirrus Cloud Retrieval Using Infrared Sounding Data: Multilevel Cloud Errors.

NASA Astrophysics Data System (ADS)

Baum, Bryan A.; Wielicki, Bruce A.

1994-01-01

In this study we perform an error analysis for cloud-top pressure retrieval using the High-Resolution Infrared Radiometric Sounder (HIRS/2) 15-µm CO2 channels for the two-layer case of transmissive cirrus overlying an overcast, opaque stratiform cloud. This analysis includes standard deviation and bias error due to instrument noise and the presence of two cloud layers, the lower of which is opaque. Instantaneous cloud pressure retrieval errors are determined for a range of cloud amounts (0.1 1.0) and cloud-top pressures (850250 mb). Large cloud-top pressure retrieval errors are found to occur when a lower opaque layer is present underneath an upper transmissive cloud layer in the satellite field of view (FOV). Errors tend to increase with decreasing upper-cloud elective cloud amount and with decreasing cloud height (increasing pressure). Errors in retrieved upper-cloud pressure result in corresponding errors in derived effective cloud amount. For the case in which a HIRS FOV has two distinct cloud layers, the difference between the retrieved and actual cloud-top pressure is positive in all casts, meaning that the retrieved upper-cloud height is lower than the actual upper-cloud height. In addition, errors in retrieved cloud pressure are found to depend upon the lapse rate between the low-level cloud top and the surface. We examined which sounder channel combinations would minimize the total errors in derived cirrus cloud height caused by instrument noise and by the presence of a lower-level cloud. We find that while the sounding channels that peak between 700 and 1000 mb minimize random errors, the sounding channels that peak at 300—500 mb minimize bias errors. For a cloud climatology, the bias errors are most critical.

Layer Structure of a Refractory Multilayer Ti/Al Composite After Pressure Diffusion Welding

NASA Astrophysics Data System (ADS)

Karpov, M. I.; Korzhov, V. P.; Zheltyakova, I. S.

2016-05-01

A composite refractory material with layer structure obtained by the method of pressure diffusion welding of multilayer Ti/Al packets composed of Ti- and Al-foils is studied. The welding temperature of the packets does not exceed 1200 - 1250°C. A layer structure forms in the process of interdiffusion of titanium and aluminum during welding of the packets.

Vortex detection through pressure measurements

NASA Astrophysics Data System (ADS)

Bhide, Aditi

Vortex Generators (VGs) are known to hinder boundary layer separation, a frequently unwanted phenomenon when it comes to external flows over aircraft wings, on-ground vehicles or internal flows within pipes, diffusers and turbomachinery. Boundary layer separation leads to loss of lift, higher drag and subsequently, energy losses. The vortices generated inhibit boundary layer separation. This thesis is an effort to discern the strength and location of these generated vortices using an array of VGs over a flat plate. Such information may be useful in the future in active control systems for streamwise vortices, which have been proposed to relaminarize turbulent boundary layers. Flow over flat plates, simulated using wind tunnel experiments, is studied for pressure variation using an array of pressure ports mounted over the plate and connected to suitable pressure sensors. Pressure coefficient and Velocity maps are generated using the data obtained from the Kirsten Wind Tunnel data acquisition system. These represent the nature of the flow field over the plate and are used to locate the vortices and determine their strength. It was found that the vortices can be detected using this method and their strength and location can be estimated.

Two-layer convective heating prediction procedures and sensitivities for blunt body reentry vehicles

NASA Technical Reports Server (NTRS)

Bouslog, Stanley A.; An, Michael Y.; Wang, K. C.; Tam, Luen T.; Caram, Jose M.

1993-01-01

This paper provides a description of procedures typically used to predict convective heating rates to hypersonic reentry vehicles using the two-layer method. These procedures were used to compute the pitch-plane heating distributions to the Apollo geometry for a wind tunnel test case and for three flight cases. Both simple engineering methods and coupled inviscid/boundary layer solutions were used to predict the heating rates. The sensitivity of the heating results in the choice of metrics, pressure distributions, boundary layer edge conditions, and wall catalycity used in the heating analysis were evaluated. Streamline metrics, pressure distributions, and boundary layer edge properties were defined from perfect gas (wind tunnel case) and chemical equilibrium and nonequilibrium (flight cases) inviscid flow-field solutions. The results of this study indicated that the use of CFD-derived metrics and pressures provided better predictions of heating when compared to wind tunnel test data. The study also showed that modeling entropy layer swallowing and ionization had little effect on the heating predictions.

Growth of multilayered polycrystalline reaction rims in the MgO-SiO2 system, part I: experiments

NASA Astrophysics Data System (ADS)

Gardés, E.; Wunder, B.; Wirth, R.; Heinrich, W.

2011-01-01

Growth of transport-controlled reaction layers between single crystals of periclase and quartz, and forsterite and quartz was investigated experimentally at 1.5 GPa, 1100°C to 1400°C, 5 min to 72 h under dry and melt-free conditions using a piston-cylinder apparatus. Starting assemblies consisting of Per | Qtz | Fo sandwiches produced polycrystalline double layers of forsterite and enstatite between periclase and quartz, and enstatite single layers between forsterite and quartz. The position of inert Pt-markers initially deposited at the interface of the reactants and inspection of mass balance confirmed that both layer-producing reactions are controlled by MgO diffusion, while SiO2 is relatively immobile. BSE and TEM imaging revealed thicknesses from 0.6 μm to 14 μm for double layers and from 0 to 6.8 μm for single layers. Both single and double layers displayed non-parabolic growth together with pronounced grain coarsening. Textural evolution and growth rates for each reaction are directly comparable. Forsterite-enstatite double layers are always wider than enstatite single layers, and the growth of enstatite in the double layer is slower than that in the single layer. In double layers, the enstatite/forsterite layer thickness ratio significantly increases with temperature, reflecting different MgO mobilities as temperature varies. Thus, thickness ratios in multilayered reaction zones may contain a record of temperature, but also that of any physico-chemical parameter that modifies the mobilities of the chemical components between the various layers. This potential is largely unexplored in geologically relevant systems, which calls for further experimental studies of multilayered reaction zones.

Schlieren and OH* chemiluminescence imaging of combustion in a turbulent boundary layer over a solid fuel

NASA Astrophysics Data System (ADS)

Jens, Elizabeth T.; Miller, Victor A.; Cantwell, Brian J.

2016-03-01

Combustion in a turbulent boundary layer over a solid fuel is studied using simultaneous schlieren and OH* chemiluminescence imaging. The flow configuration is representative of a hybrid rocket motor combustor. Six different hydrocarbon fuels, including both classical hybrid rocket fuels and a high regression rate fuel (paraffin wax), are burned in an undiluted oxygen free-stream at pressures ranging from atmospheric to 1524.2 kPa (221.1 psi). A detailed explanation of methods for registering the schlieren and OH* chemiluminescence images to one another is presented, and additionally, details of the routines used to extract flow features of interest (like the boundary layer height and flame location) are provided. At atmospheric pressure, the boundary layer location is consistent between all fuels; however, the flame location varies for each fuel. The flame zone appears to be smoothly distributed over the fuel surface at atmospheric pressure. At elevated pressures and correspondingly increased Dahmköhler number (but at constant Reynolds number), flame morphology is markedly different, exhibiting large rollers in a shear layer above the fuel grain and finer structures in the flame. The chemiluminescence intensity is found to be roughly proportional to the fuel burn rate at both atmospheric and elevated chamber pressures.

Experimental Studies of Low-Pressure Turbine Flows and Flow Control. Streamwise Pressure Profiles and Velocity Profiles

NASA Technical Reports Server (NTRS)

Volino, Ralph

2012-01-01

This report summarizes research performed in support of the NASA Glenn Research Center (GRC) Low-Pressure Turbine (LPT) Flow Physics Program. The work was performed experimentally at the U.S. Naval Academy faculties. The geometry corresponded to "Pak B" LPT airfoil. The test section simulated LPT flow in a passage. Three experimental studies were performed: (a) Boundary layer measurements for ten baseline cases under high and low freestream turbulence conditions at five Reynolds numbers of 25,000, 50,000, 100,000, 200,000, and 300,000, based on passage exit velocity and suction surface wetted length; (b) Passive flow control studies with three thicknesses of two-dimensional bars, and two heights of three-dimensional circular cylinders with different spanwise separations, at same flow conditions as the 10 baseline cases; (c) Active flow control with oscillating synthetic (zero net mass flow) vortex generator jets, for one case with low freestream turbulence and a low Reynolds number of 25,000. The Passive flow control was successful at controlling the separation problem at low Reynolds numbers, with varying degrees of success from case to case and varying levels of impact at higher Reynolds numbers. The active flow control successfully eliminated the large separation problem for the low Reynolds number case. Very detailed data was acquired using hot-wire anemometry, including single and two velocity components, integral boundary layer quantities, turbulence statistics and spectra, turbulent shear stresses and their spectra, and intermittency, documenting transition, separation and reattachment. Models were constructed to correlate the results. The report includes a summary of the work performed and reprints of the publications describing the various studies.This report summarizes research performed in support of the NASA Glenn Research Center (GRC) Low-Pressure Turbine (LPT) Flow Physics Program. The work was performed experimentally at the U.S. Naval Academy faculties. The geometry corresponded to "Pak B" LPT airfoil. The test section simulated LPT flow in a passage. Three experimental studies were performed: (a) Boundary layer measurements for ten baseline cases under high and low freestream turbulence conditions at five Reynolds numbers of 25,000, 50,000, 100,000, 200,000, and 300,000, based on passage exit velocity and suction surface wetted length; (b) Passive flow control studies with three thicknesses of two-dimensional bars, and two heights of three-dimensional circular cylinders with different spanwise separations, at same flow conditions as the 10 baseline cases; (c) Active flow control with oscillating synthetic (zero net mass flow) vortex generator jets, for one case with low freestream turbulence and a low Reynolds number of 25,000. The Passive flow control was successful at controlling the separation problem at low Reynolds numbers, with varying degrees of success from case to case and varying levels of impact at higher Reynolds numbers. The active flow control successfully eliminated the large separation problem for the low Reynolds number case. Very detailed data was acquired using hot-wire anemometry, including single and two velocity components, integral boundary layer quantities, turbulence statistics and spectra, turbulent shear stresses and their spectra, and intermittency, documenting transition, separation and reattachment. Models were constructed to correlate the results. The report includes a summary of the work performed and reprints of the publications describing the various studies. The folders in this supplement contain processed data in ASCII format. Streamwise pressure profiles and velocity profiles are included. The velocity profiles were acquired using single sensor and cross sensor hot-wire probes which were traversed from the wall to the freestream at various streamwise locations. In some of the flow control cases (3D Trips and Jets) profiles were acquired at multiple spanwise locations.

Single-unit-cell layer established Bi 2 WO 6 3D hierarchical architectures: Efficient adsorption, photocatalysis and dye-sensitized photoelectrochemical performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Hongwei; Cao, Ranran; Yu, Shixin

Single-layer catalysis sparks huge interests and gains widespread attention owing to its high activity. Simultaneously, three-dimensional (3D) hierarchical structure can afford large surface area and abundant reactive sites, contributing to high efficiency. Herein, we report an absorbing single-unit-cell layer established Bi2WO6 3D hierarchical architecture fabricated by a sodium dodecyl benzene sulfonate (SDBS)-assisted assembled strategy. The DBS- long chains can adsorb on the (Bi2O2)2+ layers and hence impede stacking of the layers, resulting in the single-unit-cell layer. We also uncovered that SDS with a shorter chain is less effective than SDBS. Due to the sufficient exposure of surface O atoms, single-unit-cellmore » layer 3D Bi2WO6 shows strong selectivity for adsorption on multiform organic dyes with different charges. Remarkably, the single-unit-cell layer 3D Bi2WO6 casts profoundly enhanced photodegradation activity and especially a superior photocatalytic H2 evolution rate, which is 14-fold increase in contrast to the bulk Bi2WO6. Systematic photoelectrochemical characterizations disclose that the substantially elevated carrier density and charge separation efficiency take responsibility for the strengthened photocatalytic performance. Additionally, the possibility of single-unit-cell layer 3D Bi2WO6 as dye-sensitized solar cells (DSSC) has also been attempted and it was manifested to be a promising dye-sensitized photoanode for oxygen evolution reaction (ORR). Our work not only furnish an insight into designing single-layer assembled 3D hierarchical architecture, but also offer a multi-functional material for environmental and energy applications.« less

Diverse and tunable electronic structures of single-layer metal phosphorus trichalcogenides for photocatalytic water splitting

NASA Astrophysics Data System (ADS)

Liu, Jian; Li, Xi-Bo; Wang, Da; Lau, Woon-Ming; Peng, Ping; Liu, Li-Min

2014-02-01

The family of bulk metal phosphorus trichalcogenides (APX3, A = MII, M_{0.5}^IM_{0.5}^{III}; X = S, Se; MI, MII, and MIII represent Group-I, Group-II, and Group-III metals, respectively) has attracted great attentions because such materials not only own magnetic and ferroelectric properties, but also exhibit excellent properties in hydrogen storage and lithium battery because of the layered structures. Many layered materials have been exfoliated into two-dimensional (2D) materials, and they show distinct electronic properties compared with their bulks. Here we present a systematical study of single-layer metal phosphorus trichalcogenides by density functional theory calculations. The results show that the single layer metal phosphorus trichalcogenides have very low formation energies, which indicates that the exfoliation of single layer APX3 should not be difficult. The family of single layer metal phosphorus trichalcogenides exhibits a large range of band gaps from 1.77 to 3.94 eV, and the electronic structures are greatly affected by the metal or the chalcogenide atoms. The calculated band edges of metal phosphorus trichalcogenides further reveal that single-layer ZnPSe3, CdPSe3, Ag0.5Sc0.5PSe3, and Ag0.5In0.5PX3 (X = S and Se) have both suitable band gaps for visible-light driving and sufficient over-potentials for water splitting. More fascinatingly, single-layer Ag0.5Sc0.5PSe3 is a direct band gap semiconductor, and the calculated optical absorption further convinces that such materials own outstanding properties for light absorption. Such results demonstrate that the single layer metal phosphorus trichalcogenides own high stability, versatile electronic properties, and high optical absorption, thus such materials have great chances to be high efficient photocatalysts for water-splitting.

A comparison of measured and predicted test flow in an expansion tube with air and oxygen test gases

NASA Technical Reports Server (NTRS)

Aaggard, K. V.; Goad, W. K.

1975-01-01

Simultaneous time-resolved measurements of temperature, density, pitot pressure, and wall pressure in both air and O2 test gases were obtained in the Langley pilot model expansion tube. These tests show nonequilibrium chemical and vibrational relaxation significantly affect the test-flow condition. The use of an electromagnetic device to preopen the secondary diaphragm before the arrival of the primary shock wave resulted in an improvement in the agreement between the measured pitot pressure and the value inferred from measured density and interface velocity. Boundary-layer splitter plates used to reduce the wall boundary layer show that this disagreement in the measured and inferred pitot pressures is not a result of boundary-layer effects.

A comparison of inferface pressures of three compression bandage systems.

PubMed

Hanna, Richard; Bohbot, Serge; Connolly, Nicki

To measure and compare the interface pressures achieved with two compression bandage systems - a four-layer system (4LB) and a two-layer short-stretch system (SSB) - with a new two-layer system (2LB), which uses an etalonnage (performance indicator) to help achieve the correct therapeutic pressure for healing venous leg ulcers - recommended as 40 mmHg. 32 nurses with experience of using compression bandages applied each of the three systems to a healthy female volunteer in a sitting position. The interface pressures and time taken to apply the systems were measured. A questionnaire regarding the concept of the new system and its application in comparison to the existing two systems was then completed by the nurses. The interface pressures achieved show that many nurses applied very high pressures with the 4LB (25% achieving pressures > 50 mmHg) whereas the majority of the nurses (75%) achieved a pressure of < 30 mmHg when using the SSB. A pressure of 30-50 mmHg was achieved with the new 2LB. The SSB took the least time to be applied (mean: 1 minute 50 seconds) with the 4LB the slowest (mean: 3 minutes 46 seconds). A mean time of 2 minutes 35 seconds was taken to apply the 2LB. Over 63% of the nurses felt the 2LB was very easy to apply. These results suggest that the 2LB achieves the required therapeutic pressure necessary for the management of venous leg ulcers, is easy to apply and may provide a suitable alternative to other multi-layer bandage systems.

Design and optimization of a single stage centrifugal compressor for a solar dish-Brayton system

NASA Astrophysics Data System (ADS)

Wang, Yongsheng; Wang, Kai; Tong, Zhiting; Lin, Feng; Nie, Chaoqun; Engeda, Abraham

2013-10-01

According to the requirements of a solar dish-Brayton system, a centrifugal compressor stage with a minimum total pressure ratio of 5, an adiabatic efficiency above 75% and a surge margin more than 12% needs to be designed. A single stage, which consists of impeller, radial vaned diffuser, 90° crossover and two rows of axial stators, was chosen to satisfy this system. To achieve the stage performance, an impeller with a 6:1 total pressure ratio and an adiabatic efficiency of 90% was designed and its preliminary geometry came from an in-house one-dimensional program. Radial vaned diffuser was applied downstream of the impeller. Two rows of axial stators after 90° crossover were added to guide the flow into axial direction. Since jet-wake flow, shockwave and boundary layer separation coexisted in the impeller-diffuser region, optimization on the radius ratio of radial diffuser vane inlet to impeller exit, diffuser vane inlet blade angle and number of diffuser vanes was carried out at design point. Finally, an optimized centrifugal compressor stage fulfilled the high expectations and presented proper performance. Numerical simulation showed that at design point the stage adiabatic efficiency was 79.93% and the total pressure ratio was 5.6. The surge margin was 15%. The performance map including 80%, 90% and 100% design speed was also presented.

Monolithic composite “pressure + acceleration + temperature + infrared” sensor using a versatile single-sided “SiN/Poly-Si/Al” process-module.

PubMed

Ni, Zao; Yang, Chen; Xu, Dehui; Zhou, Hong; Zhou, Wei; Li, Tie; Xiong, Bin; Li, Xinxin

2013-01-16

We report a newly developed design/fabrication module with low-cost single-sided "low-stress-silicon-nitride (LS-SiN)/polysilicon (poly-Si)/Al" process for monolithic integration of composite sensors for sensing-network-node applications. A front-side surface-/bulk-micromachining process on a conventional Si-substrate is developed, featuring a multifunctional SiN/poly-Si/Al layer design for diverse sensing functions. The first "pressure + acceleration + temperature + infrared" (PATIR) composite sensor with the chip size of 2.5 mm × 2.5 mm is demonstrated. Systematic theoretical design and analysis methods are developed. The diverse sensing components include a piezoresistive absolute-pressure sensor (up to 700 kPa, with a sensitivity of 49 mV/MPa under 3.3 V supplied voltage), a piezoresistive accelerometer (±10 g, with a sensitivity of 66 μV/g under 3.3 V and a -3 dB bandwidth of 780 Hz), a thermoelectric infrared detector (with a responsivity of 45 V/W and detectivity of 3.6 × 107 cm·Hz1/2/W) and a thermistor (-25-120 °C). This design/fabrication module concept enables a low-cost monolithically-integrated "multifunctional-library" technique. It can be utilized as a customizable tool for versatile application-specific requirements, which is very useful for small-size, low-cost, large-scale sensing-network node developments.

Residual strain effects on large aspect ratio micro-diaphragms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hijab, R.S.; Muller, R.S.

1988-09-30

Highly compliant, large aspect ratio diaphragms for use in low-pressure, capacitive-readout sensors, have been investigated. In such structures, unrelaxed strain in the diaphragms can radically alter mechanical behavior. Although strain can be reduced by thermal annealing, it usually reaches a remnant irreducible minimum. The purpose of this paper is to describe techniques that result in low-strain materials and that reduce the effects of residual strain in micro-diaphragms. Square polysilicon grilles and perforated diaphragms made from both single and double polysilicon layers and from single-crystal silicon, with aspect ratios (side/thickness) of up to 1000 and very low compressive strain ({approx}6 {times}more » 10{sup {minus}5}), have been fabricated. Strain reduction is achieved by combining thermal annealing with one of two mechanical design techniques. The first technique makes use of a series of cantilever beams to support the diaphragms. In a second procedure, corrugated surfaces in thinned membranes of single-crystal silicon are formed. The corrugations result from the use of boron doping and anisotropic silicon etching. In both of these techniques to produce low-strain diaphragms, an etched cavity is purposely formed in the substrate crystal below them. Only one-sided processing of wafers is employed, thus aiding reproducibility and providing ease of compatibility with an MOS process. A fast-etching sacrificial-support layer (phosphorus-doped CVD oxide) is used. 4 refs., 10 figs.« less

In-flight comparisons of boundary-layer and wake measurement probes for incompressible flow

NASA Technical Reports Server (NTRS)

Mertaugh, L. J., Jr.

1972-01-01

The results are presented of in-flight comparisons of a number of boundary-layer and wake measurement probes suitable for low-speed flight-test investigations. The tested boundary-layer probes included a traversing total-pressure probe and a hot-film probe mounted on an internally-mounted drive mechanism, a curved and a straight boundary-layer rake, and a traversing hot-film probe with an externally-mounted drive mechanism. The wake measuring devices included a traversing, self-aligning probe, a wake rake, and an integrating wake rate. The boundary-layer data are compared with a common reference velocity profile and comments given regarding the accuracy of the static-pressure and total-pressure measurements. Discussions on the various calibration presentations used with hot-wire and hot-film sensors and various aspects of improving the accuracy of hot-film sensor results are given in the appendix of this report.

Confirmation of theoretical colour predictions for layering dental composite materials.

PubMed

Mikhail, Sarah S; Johnston, William M

2014-04-01

The aim of this study is to confirm the theoretical colour predictions for single and double layers of dental composite materials on an opaque backing. Single and double layers of composite resins were fabricated, placed in optical contact with a grey backing and measured for spectral radiance. The spectral reflectance and colour were directly determined. Absorption and scattering coefficients as previously reported, the measured thickness of the single layers and the effective reflectance of the grey backing were utilized to theoretically predict the reflectance of the single layer using corrected Kubelka-Munk reflectance theory. For double layers the predicted effective reflectance of the single layer was used as the reflectance of the backing of the second layer and the thickness of the second layer was used to predict the reflectance of the double layer. Colour differences, using both the CIELAB and CIEDE2000 formulae, measured the discrepancy between each directly determined colour and its corresponding theoretical colour. The colour difference discrepancies generally ranged around the perceptibility threshold but were consistently below the respective acceptability threshold. This theory can predict the colour of layers of composite resin within acceptability limits and generally also within perceptibility limits. This theory could therefore be incorporated into computer-based optical measuring instruments that can automate the shade selections for layers of a more opaque first layer under a more translucent second layer for those clinical situations where an underlying background colour and a desirable final colour can be measured. Copyright © 2014 Elsevier Ltd. All rights reserved.

The effect of the hole injection layer on the performance of single layer organic light-emitting diodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wenjin, Zeng; Ran, Bi; Hongmei, Zhang, E-mail: iamhmzhang@njupt.edu.cn, E-mail: iamwhuang@njupt.edu.cn

2014-12-14

Efficient single-layer organic light-emitting diodes (OLEDs) were reported based on a green fluorescent dye 10-(2-benzothiazolyl)-2,3,6,7-tetrahydro-1,1,7,7–tetramethyl-1H,5H,11H-(1) benzopyropyrano (6,7-8-I,j)quinolizin-11-one (C545T). Herein, poly(3,4-ethylenedioxy thiophene) poly(styrene sulfonate) were, respectively, applied as the injection layer for comparison. The hole transport properties of the emission layer with different hole injection materials are well investigated via current-voltage measurement. It was clearly found that the hole injection layers (HILs) play an important role in the adjustment of the electron/hole injection to attain transport balance of charge carriers in the single emission layer of OLEDs with electron-transporting host. The layer of tris-(8-hydroxyquinoline) aluminum played a dual role of hostmore » and electron-transporting materials within the emission layer. Therefore, appropriate selection of hole injection layer is a key factor to achieve high efficiency OLEDs with single emission layer.« less

Structure and elasticity of serpentine at high-pressure

NASA Astrophysics Data System (ADS)

Mookherjee, Mainak; Stixrude, Lars

2009-03-01

Serpentines occur in the subduction zone settings, both along the slab and within the mantle wedge, they are candidates for transporting water in to the deep earth. Their presence is manifested by serpentine mud volcanoes, high electrical conductivities, magnetic and seismic anomalies. Using theoretical methods, we predict a pressure induced structural transformations in serpentine. The transformations are related to the behavior of the silicate framework and misfit between octahedral and tetrahedral layers. As the structure is compressed, the octahedral layer and tetrahedral layers are compressed at different rates. At 7 GPa, the misfit between the layers vanishes. This causes non-linear pressure dependence of tetrahedral rotational angle. This is also manifested by the onset of anomalous pressure dependence of the elastic constants c11, c33, c12, c13. Beyond 7 GPa, the misfit between the layers grows again reaching extremum at 22 GPa. This is also manifested by discontinuity in average Si-O bond length, volume of tetrahedron and re-orientation of hydroxyl vector. The symmetry of the crystal-structure however, remains unaffected. Evidence of pressure-induced hydrogen bonding is absent in serpentine, as evident from reduction of O-H bond length upon compression. Results of compression for the low-pressure regime ( P < 7 GPa) is well represented by a fourth order Birch-Murnaghan finite strain expression with K0 = 79 GPa, K0' = 12 and K0″ = - 2, where K is the bulk modulus, prime indicates pressure derivatives, and O refers to zero pressure. Our best estimates of K0, K0' and the Grüneisen parameter, γ at 300 K and zero pressure based on our results are: 61 GPa, 17, and 0.77, respectively. At low pressures, serpentine structure is anisotropic with c11 ~ 2.4 × c33. The pressure derivative of elastic constants ( ∂cij/ ∂P) are such, that around 22 GPa c11~ c33. An elastic instability ( c66 < 0) at somewhat higher pressures (> 50 GPa) is also noted. The elastic constant tensor reveals large acoustic anisotropy (41% in VP) and seismic wave velocities that are significantly higher than those inferred from experiments on serpentinites.

Secondary subharmonic instability of boundary layers with pressure gradient and suction

NASA Technical Reports Server (NTRS)

El-Hady, Nabil M.

1988-01-01

Three-dimensional linear secondary instability is investigated for boundary layers with pressure gradient and suction in the presence of a finite amplitude TS wave. The focus is on principal parametric resonance responsible for a strong growth of subharmonics in a low disturbance environment. Calculations are presented for the effect of pressure gradients and suction on controlling the onset and amplification of the secondary instability.

Computational discovery of ferromagnetic semiconducting single-layer CrSnTe 3

DOE PAGES

Zhuang, Houlong L.; Xie, Yu; Kent, P. R. C.; ...

2015-07-06

Despite many single-layer materials being reported in the past decade, few of them exhibit magnetism. Here we perform first-principles calculations using accurate hybrid density functional methods (HSE06) to predict that single-layer CrSnTe 3 (CST) is a ferromagnetic semiconductor, with band gaps of 0.9 and 1.2 eV for the majority and minority spin channels, respectively. We determine the Curie temperature as 170 K, significantly higher than that of single-layer CrSiTe 3 (90K) and CrGeTe 3 (130 K). This is due to the enhanced ionicity of the Sn-Te bond, which in turn increases the superexchange coupling between the magnetic Cr atoms. Wemore » further explore the mechanical and dynamical stability and strain response of this single-layer material for possible epitaxial growth. Lastly, our study provides an intuitive approach to understand and design novel single-layer magnetic semiconductors for a wide range of spintronics and energy applications.« less

Tunable phase transition in single-layer TiSe2 via electric field

NASA Astrophysics Data System (ADS)

Liu, Lei; Zhuang, Houlong L.

2018-06-01

Phase transition represents an intriguing physical phenomenon that exists in a number of single-layer transition-metal dichalcogenides. This phenomenon often occurs below a critical temperature and breaks the long-range crystalline order leading to a reconstructed superstructure called the charge-density wave (CDW) structure, which can therefore be recovered by external stimuli such as temperature. Alternatively, we show here that another external stimulation, electric field can also result in the phase transition between the regular and CDW structures of a single-layer transition-metal dichalcogenide. We used single-layer TiSe2 as an example to elucidate the mechanism of the CDW followed by calculations of the electronic structure using a hybrid density functional. We found that applying electric field can tune the phase transition between the 1T and CDW phases of single-layer TiSe2. Our work opens up a route of tuning the phase transition of single-layer materials via electric field.

Multilayer Nanoporous Graphene Membranes for Water Desalination.

PubMed

Cohen-Tanugi, David; Lin, Li-Chiang; Grossman, Jeffrey C

2016-02-10

While single-layer nanoporous graphene (NPG) has shown promise as a reverse osmosis (RO) desalination membrane, multilayer graphene membranes can be synthesized more economically than the single-layer material. In this work, we build upon the knowledge gained to date toward single-layer graphene to explore how multilayer NPG might serve as a RO membrane in water desalination using classical molecular dynamic simulations. We show that, while multilayer NPG exhibits similarly promising desalination properties to single-layer membranes, their separation performance can be designed by manipulating various configurational variables in the multilayer case. This work establishes an atomic-level understanding of the effects of additional NPG layers, layer separation, and pore alignment on desalination performance, providing useful guidelines for the design of multilayer NPG membranes.

Single layers and multilayers of GaN and AlN in square-octagon structure: Stability, electronic properties, and functionalization

NASA Astrophysics Data System (ADS)

Gürbüz, E.; Cahangirov, S.; Durgun, E.; Ciraci, S.

2017-11-01

Further to planar single-layer hexagonal structures, GaN and AlN can also form free-standing, single-layer structures constructed from squares and octagons. We performed an extensive analysis of dynamical and thermal stability of these structures in terms of ab initio finite-temperature molecular dynamics and phonon calculations together with the analysis of Raman and infrared active modes. These single-layer square-octagon structures of GaN and AlN display directional mechanical properties and have wide, indirect fundamental band gaps, which are smaller than their hexagonal counterparts. These density functional theory band gaps, however, increase and become wider upon correction. Under uniaxial and biaxial tensile strain, the fundamental band gaps decrease and can be closed. The electronic and magnetic properties of these single-layer structures can be modified by adsorption of various adatoms, or by creating neutral cation-anion vacancies. The single-layer structures attain magnetic moment by selected adatoms and neutral vacancies. In particular, localized gap states are strongly dependent on the type of vacancy. The energetics, binding, and resulting electronic structure of bilayer, trilayer, and three-dimensional (3D) layered structures constructed by stacking the single layers are affected by vertical chemical bonds between adjacent layers. In addition to van der Waals interaction, these weak vertical bonds induce buckling in planar geometry and enhance their binding, leading to the formation of stable 3D layered structures. In this respect, these multilayers are intermediate between van der Waals solids and wurtzite crystals, offering a wide range of tunability.

Metal-free, flexible triboelectric generator based on MWCNT mesh film and PDMS layers

NASA Astrophysics Data System (ADS)

Hwang, Hayoung; Lee, Kang Yeol; Shin, Dongjoon; Shin, Jungho; Kim, Sangtae; Choi, Wonjoon

2018-06-01

We demonstrate a metal-free triboelectric energy harvester consisted of MWCNT mesh film and PDMS layer. Upon touch from a finger, the single electrode-mode energy harvester generates up to 27.0 W/m2 output power at 10 MΩ matched impedance. The device generates stable power upon touch by bare fingers or gloved fingers. Using copper counter electrode results in decreased power output, due to the weaker tendency in triboelectrification. The power output also scales with the pressure applied by the finger. The intertwined, condensed MWCNT network acts as a flexible yet effective current collector, with resistance across the device less than 10 Ω. This current collector possesses strong corrosion resistance and stability against potential oxidation, while its metal counterpart may undergo oxidation over extended exposure to air or frequent fracture upon straining. The flexible device form may be applied to various curved or irregular surfaces that undergo frequent human touches.

Convective response of a wall-mounted hot-film sensor in a shock tube

NASA Technical Reports Server (NTRS)

Roberts, A. Sidney, Jr.; Ortgies, Kelly R.; Gartenberg, Ehud; Carraway, Debra L.

1991-01-01

Shock tube experiments were performed in order to determine the response of a single hot-film element of a sensor array to transiently induced flow behind weak normal shock waves. The experiments attempt to isolate the response due only to the change in convective heat transfer at the hot-film surface mounted on the wall of the shock tube. The experiments are described, the results being correlated with transient boundary layer theory and compared with an independent set of experimental results. One of the findings indicates that the change in the air properties (temperature and pressure) precedes the air mass transport, causing an ambiguity in the sensor response to the development of the velocity boundary layer. Also, a transient, local heat transfer coefficient is formulated to be used as a forcing function in an hot-film instrument model and simulation which remains under investigation.

Control of flow separation in a turbulent boundary layer

NASA Astrophysics Data System (ADS)

Cho, Minjeong; Choi, Sangho; Choi, Haecheon

2015-11-01

Towards the development of successful control methods for separation delay in a turbulent boundary layer, we adopt a model flow field, in which a turbulent separation occurs above a flat plate (Na and Moin 1998 JFM), and apply controls to this flow for reducing the size of the separation bubble and investigating the interaction between the forcing and flow near the separation bubble. We provide a single-frequency forcing with zero net mass flow rate at the upstream of the separation bubble. At low forcing frequencies, spanwise vortices are generated and travel downstream, bringing high momentum toward the wall and reducing the size of the separation bubble. Also, these vortices cause the separation and reattachment points to travel downstream. On the other hand, at high forcing frequencies, the size of the separation bubble becomes smaller and larger in time, respectively, due to the pressure gradient alternating favorably and adversely in time. Supported by NRF-2011-0028032 and 2014048162.

In vivo laser confocal microscopy of Bowman's layer of the cornea.

PubMed

Kobayashi, Akira; Yokogawa, Hideaki; Sugiyama, Kazuhisa

2006-12-01

To investigate in vivo microstructures of Bowman's layer in normal human subjects using a cornea-specific in vivo laser scanning confocal microscope (Heidelberg Retina Tomograph 2 Rostock Cornea Module, HRT2-RCM). Single-center, prospective, observational case series. Nineteen normal volunteers (10 male, 9 female; mean age, 46.2+/-21.7 years [range, 18-77]). The central and peripheral cornea, specifically the epithelium, Bowman's layer, and its subjacent stroma, were examined using the HRT2-RCM. Selected images of the corneal layers were evaluated qualitatively for the shape and degree of light reflection of the microstructures. In all subjects, normal epithelial (superficial, wing, basal) cells, subbasal nerve plexus, Bowman's layer, and its subjacent stoma were observed clearly. However, in all subjects, polymorphic structures composed of fibrillar materials with less reflectivity than corneal nerves were observed beneath Bowman's layer. After application of pressure by a Tomo-cap, we observed numerous ridges that protruded into the epithelial basal and wing cell layers. Superficial stromal striae were also observed. These ridges and striae corresponded exactly to the orientation of the fibrous structures located beneath the epithelial cells. We report for the first time, the presence of polymorphic structures composed of fibrillar materials (K-structures) beneath Bowman's layer in normal human subjects, detected by HRT2-RCM. We surmise that these microstructures may correspond to the modified and condensed anterior stromal collagen fibers/lamellae that merge into Bowman's layer and that these fibrillar materials may be responsible for the formation of the anterior corneal mosaic. Further investigation of these microstructures in diseased eyes may provide insights into their pathophysiologic role in Bowman's layer.

A KLM-circuit model of a multi-layer transducer for acoustic bladder volume measurements.

PubMed

Merks, E J W; Borsboom, J M G; Bom, N; van der Steen, A F W; de Jong, N

2006-12-22

In a preceding study a new technique to non-invasively measure the bladder volume on the basis of non-linear wave propagation was validated. It was shown that the harmonic level generated at the posterior bladder wall increases for larger bladder volumes. A dedicated transducer is needed to further verify and implement this approach. This transducer must be capable of both transmission of high-pressure waves at fundamental frequency and reception of up to the third harmonic. For this purpose, a multi-layer transducer was constructed using a single element PZT transducer for transmission and a PVDF top-layer for reception. To determine feasibility of the multi-layer concept for bladder volume measurements, and to ensure optimal performance, an equivalent mathematical model on the basis of KLM-circuit modeling was generated. This model was obtained in two subsequent steps. Firstly, the PZT transducer was modeled without PVDF-layer attached by means of matching the model with the measured electrical input impedance. It was validated using pulse-echo measurements. Secondly, the model was extended with the PVDF-layer. The total model was validated by considering the PVDF-layer as a hydrophone on the PZT transducer surface and comparing the measured and simulated PVDF responses on a wave transmitted by the PZT transducer. The obtained results indicated that a valid model for the multi-layer transducer was constructed. The model showed feasibility of the multi-layer concept for bladder volume measurements. It also allowed for further optimization with respect to electrical matching and transmit waveform. Additionally, the model demonstrated the effect of mechanical loading of the PVDF-layer on the PZT transducer.

Mathematical modelling of cell layer growth in a hollow fibre bioreactor.

PubMed

Chapman, Lloyd A C; Whiteley, Jonathan P; Byrne, Helen M; Waters, Sarah L; Shipley, Rebecca J

2017-04-07

Generating autologous tissue grafts of a clinically useful volume requires efficient and controlled expansion of cell populations harvested from patients. Hollow fibre bioreactors show promise as cell expansion devices, owing to their potential for scale-up. However, further research is required to establish how to specify appropriate hollow fibre bioreactor operating conditions for expanding different cell types. In this study we develop a simple model for the growth of a cell layer seeded on the outer surface of a single fibre in a perfused hollow fibre bioreactor. Nutrient-rich culture medium is pumped through the fibre lumen and leaves the bioreactor via the lumen outlet or passes through the porous fibre walls and cell layer, and out via ports on the outer wall of the extra-capillary space. Stokes and Darcy equations for fluid flow in the fibre lumen, fibre wall, cell layer and extra-capillary space are coupled to reaction-advection-diffusion equations for oxygen and lactate transport through the bioreactor, and to a simple growth law for the evolution of the free boundary of the cell layer. Cells at the free boundary are assumed to proliferate at a rate that increases with the local oxygen concentration, and to die and detach from the layer if the local fluid shear stress or lactate concentration exceed critical thresholds. We use the model to predict operating conditions that maximise the cell layer growth for different cell types. In particular, we predict the optimal flow rate of culture medium into the fibre lumen and fluid pressure imposed at the lumen outlet for cell types with different oxygen demands and fluid shear stress tolerances, and compare the growth of the cell layer when the exit ports on the outside of the bioreactor are open with that when they are closed. Model simulations reveal that increasing the inlet flow rate and outlet fluid pressure increases oxygen delivery to the cell layer and, therefore, the growth rate of cells that are tolerant to high shear stresses, but may be detrimental for shear-sensitive cells. The cell layer growth rate is predicted to increase, and be less sensitive to the lactate tolerance of the cells, when the exit ports are opened, as the radial flow through the bioreactor is enhanced and the lactate produced by the cells cleared more rapidly from the cell layer. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Experimental Investigation of Transition to Turbulence as Affected by Passing Wakes

NASA Technical Reports Server (NTRS)

Kaszeta, Richard W.; Simon, Terrence W.; Ashpis, David (Technical Monitor)

2002-01-01

Experimental results from a study of the effects of passing wakes upon laminar-to-turbulent transition in a low-pressure turbine passage are presented. The test section geometry is designed to simulate the effects of unsteady wakes resulting from rotor-stator interaction upon laminar-to-turbulent transition in turbine blade boundary layers and separated flow regions over suction surfaces. Single-wire, thermal anemometry techniques were used to measure time-resolved and phase-averaged, wall-normal profiles of velocity, turbulence intensity, and intermittency at multiple streamwise locations over the turbine airfoil suction surface. These data are compared to steady state, wake-free data collected in the same geometry to identify the effects of wakes upon laminar-to-turbulent transition. Results are presented for flows with a Reynolds number based on suction surface length and exit velocity of 50,000 and an approach flow turbulence intensity of 2.5 percent. From these data, the effects of passing wakes and associated increased turbulence levels and varying pressure gradients on transition and separation in the near-wall flow are presented. The results show that the wakes affect transition both by virtue of their difference in turbulence level from that of the free-stream but also by virtue of their velocity deficit relative to the freestream velocity, and the concomitant change in angle of attack and temporal pressure gradients. The results of this study seem to support the theory that bypass transition is a response of the near-wall viscous layer to pressure fluctuations imposed upon it from the free-stream flow. The data also show a significant lag between when the wake is present over the surface and when transition begins. The accompanying CD-ROM includes tabulated data, animations, higher resolution plots, and an electronic copy of this report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kahlenberg, Volker; Konzett, Juergen; Kaindl, Reinhard

High-pressure synthesis experiments in the system Na{sub 2}O-Y{sub 2}O{sub 3}-SiO{sub 2} revealed the existence of a previously unknown polymorph of NaYSi{sub 2}O{sub 6} or Na{sub 3}Y{sub 3}[Si{sub 3}O{sub 9}]{sub 2} which was quenched from 3.0 GPa and 1000 deg. C. Structural investigations on this modification have been performed using single-crystal X-ray diffraction data collected at ambient conditions. Furthermore, unpolarized micro-Raman spectra have been obtained from single-crystal material. The high-P modification of NaYSi{sub 2}O{sub 6} crystallizes in the centrosymmetric space group C2/c with 12 formula units per cell (a=8.2131(9) A, b=10.3983(14) A, c=17.6542(21) A, {beta}=100.804(9){sup o}, V=1481.0(3) A{sup 3}, R(|F|)=0.033 formore » 1142 independent observed reflections) and belongs to the group of cyclo-silicates. Basic building units are isolated three-membered [Si{sub 3}O{sub 9}] rings located in layers parallel to (010). Within a single layer the rings are concentrated in strings parallel to [100]. The sequence of directedness of up (U) or down (D) pointing tetrahedra of a single ring is UUU or DDD, respectively. Stacking of the layers parallel to b results in the formation of a three-dimensional structure in which yttrium and sodium cations are incorporated for charge compensation. In more detail, four non-tetrahedral cation positions can be differentiated which are coordinated by 6 and 8 oxygen ligands. Refinements of the site occupancies did not reveal any indication for mixed Na-Y populations on these positions. Finally, several geometrical parameters of rings occurring in cyclo-trisilicate structures have been compiled and are discussed. - Graphical abstract: Projection of the whole structure of high-P NaYSi{sub 2}O{sub 6} parallel to [100].« less

Improving the light-emitting properties of single-layered polyfluorene light-emitting devices by simple ionic liquid blending

NASA Astrophysics Data System (ADS)

Horike, Shohei; Nagaki, Hiroto; Misaki, Masahiro; Koshiba, Yasuko; Morimoto, Masahiro; Fukushima, Tatsuya; Ishida, Kenji

2018-03-01

This paper describes an evaluation of ionic liquids (ILs) as potential electrolytes for single-layered light-emitting devices with good emission performance. As optoelectronic devices continue to grow in abundance, high-performance light-emitting devices with a single emission layer are becoming increasingly important for low-cost production. We show that a simple technique of osmosing IL into the polymer layer can result in high luminous efficiency and good response times of single-layered light-emitting polymers, even without the additional stacking of charge carrier injection and transport layers. The IL contributions to the light-emission of the polymer are discussed from the perspectives of energy diagrams and of the electric double layers on the electrodes. Our findings enable a faster, cheaper, and lower-in-waste production of light-emitting devices.

Nanoshells as a high-pressure gauge

NASA Astrophysics Data System (ADS)

Tempere, Jacques; van den Broeck, Nick; Putteneers, Katrijn; Silvera, Isaac

2012-02-01

Nanoshells, consisting of multiple spherical layers, have an extensive list of applications, usually performing the function of a probe. We add a new application to this list in the form of a high-pressure gauge in a Diamond Anvil Cell (DAC). In a DAC, where high pressures are reached by pressing two diamonds together, existing gauges fail at higher pressures because of calibration difficulties and obscuring effects in the diamonds. The nanoshell gauge does not face this issue since its optical spectrum can be engineered by altering the thickness of its layers. Furthermore their properties are measured by broad band optical transmission spectroscopy leading to a very large signal-to-noise ratio even in the multi-megabar pressure regime where ruby measurements become challenging. Theoretical calculations based on the Maxwell equations in a spherical geometry combined with the Vinet equation of state show that a three-layer geometry (SiO2-Au-SiO2) indeed has a measurable pressure-dependent optical response desirable for gauges.

Graphene based resonance structure to enhance the optical pressure between two planar surfaces.

PubMed

Hassanzadeh, Abdollah; Azami, Darya

2015-12-28

To enhance the optical pressure on a thin dielectric sample, a resonance structure using graphene layers coated over a metal film on a high index prism sputtered with MgF2 was theoretically analyzed. The number of graphene layers and the thicknesses of metal and MgF2 films were optimized to achieve the highest optical pressure on the sample. Effects of three different types of metals on the optical pressure were investigated numerically. In addition, simulations were carried out for samples with various thicknesses. Our numerical results show that the optical pressure increased by more than five orders of magnitude compared to the conventional metal-film-base resonance structure. The highest optical pressure was obtained for 10 layers of graphene deposited on 29-nm thick Au film and 650 nm thickness of MgF2 at 633nm wavelength, The proposed graphene based resonance structure can open new possibilities for optical tweezers, nanomechnical devices and surface plasmon based sensing and imaging techniques.

Control of vortical separation on conical bodies

NASA Technical Reports Server (NTRS)

Mourtos, Nikos J.; Roberts, Leonard

1987-01-01

In a variety of aeronautical applications, the flow around conical bodies at incidence is of interest. Such applications include, but are not limited to, highly maneuverable aircraft with delta wings, the aerospace plane and nose portions of spike inlets. The theoretical model used has three parts. First, the single line vortex model is used within the framework of slender body theory, to compute the outer inviscid field for specified separation lines. Next, the three dimensional boundary layer is represented by a momentum equation for the cross flow, analogous to that for a plane boundary layer; a von Karman Pohlhausen approximation is applied to solve this equation. The cross flow separation for both laminar and turbulent layers is determined by matching the pressure at the upper and lower separation points. This iterative procedure yields a unique solution for the separation lines and consequently for the position of the vortices and the vortex lift on the body. Lastly, control of separation is achieved by blowing tangentially from a slot located along a cone generator. It is found that for very small blowing coefficients, the separation can be postponed or suppressedy completely.

Self-Organized Mantle Layering After the Magma-Ocean Period

NASA Astrophysics Data System (ADS)

Hansen, U.; Dude, S.

2017-12-01

The thermal history of the Earth, it's chemical differentiation and also the reaction of the interior with the atmosphere is largely determined by convective processes within the Earth's mantle. A simple physical model, resembling the situation, shortly after core formation, consists of a compositionally stable stratified mantle, as resulting from fractional crystallization of the magma ocean. The early mantle is subject to heating from below by the Earth's core and cooling from the top through the atmosphere. Additionally internal heat sources will serve to power the mantle dynamics. Under such circumstances double diffusive convection will eventually lead to self -organized layer formation, even without the preexisting jumps is material properties. We have conducted 2D and 3D numerical experiments in Cartesian and spherical geometry, taking into account mantle realistic values, especially a strong temperature dependent viscosity and a pressure dependent thermal expansivity . The experiments show that in a wide parameter range. distinct convective layers evolve in this scenario. The layering strongly controls the heat loss from the core and decouples the dynamics in the lower mantle from the upper part. With time, individual layers grow on the expense of others and merging of layers does occur. We observe several events of intermittent breakdown of individual layers. Altogether an evolution emerges, characterized by continuous but also spontaneous changes in the mantle structure, ranging from multiple to single layer flow. Such an evolutionary path of mantle convection allows to interpret phenomena ranging from stagnation of slabs at various depth to variations in the chemical signature of mantle upwellings in a new framework.

Effect of shock interactions on mixing layer between co-flowing supersonic flows in a confined duct

NASA Astrophysics Data System (ADS)

Rao, S. M. V.; Asano, S.; Imani, I.; Saito, T.

2018-03-01

Experiments are conducted to observe the effect of shock interactions on a mixing layer generated between two supersonic streams of Mach number M _{1} = 1.76 and M _{2} = 1.36 in a confined duct. The development of this mixing layer within the duct is observed using high-speed schlieren and static pressure measurements. Two-dimensional, compressible Reynolds averaged Navier-Stokes equations are solved using the k-ω SST turbulence model in Fluent. Further, adverse pressure gradients are imposed by placing inserts of small (<7% of duct height) but finite (> boundary layer thickness) thickness on the walls of the test section. The unmatched pressures cause the mixing layer to bend and lead to the formation of shock structures that interact with the mixing layer. The mixing layer growth rate is found to increase after the shock interaction (nearly doubles). The strongest shock is observed when a wedge insert is placed in the M _{2} flow. This shock interacts with the mixing layer exciting flow modes that produce sinusoidal flapping structures which enhance the mixing layer growth rate to the maximum (by 1.75 times). Shock fluctuations are characterized, and it is observed that the maximum amplitude occurs when a wedge insert is placed in the M _{2} flow.

Atmospheric pressure reaction cell for operando sum frequency generation spectroscopy of ultrahigh vacuum grown model catalysts

NASA Astrophysics Data System (ADS)

Roiaz, Matteo; Pramhaas, Verena; Li, Xia; Rameshan, Christoph; Rupprechter, Günther

2018-04-01

A new custom-designed ultrahigh vacuum (UHV) chamber coupled to a UHV and atmospheric-pressure-compatible spectroscopic and catalytic reaction cell is described, which allows us to perform IR-vis sum frequency generation (SFG) vibrational spectroscopy during catalytic (kinetic) measurements. SFG spectroscopy is an exceptional tool to study vibrational properties of surface adsorbates under operando conditions, close to those of technical catalysis. This versatile setup allows performing surface science, SFG spectroscopy, catalysis, and electrochemical investigations on model systems, including single crystals, thin films, and deposited metal nanoparticles, under well-controlled conditions of gas composition, pressure, temperature, and potential. The UHV chamber enables us to prepare the model catalysts and to analyze their surface structure and composition by low energy electron diffraction and Auger electron spectroscopy, respectively. Thereafter, a sample transfer mechanism moves samples under UHV to the spectroscopic cell, avoiding air exposure. In the catalytic cell, SFG spectroscopy and catalytic tests (reactant/product analysis by mass spectrometry or gas chromatography) are performed simultaneously. A dedicated sample manipulation stage allows the model catalysts to be examined from LN2 temperature to 1273 K, with gaseous reactants in a pressure range from UHV to atmospheric. For post-reaction analysis, the SFG cell is rapidly evacuated and samples are transferred back to the UHV chamber. The capabilities of this new setup are demonstrated by benchmark results of CO adsorption on Pt and Pd(111) single crystal surfaces and of CO adsorption and oxidation on a ZrO2 supported Pt nanoparticle model catalyst grown by atomic layer deposition.

Experimental Measurements of a High Reynolds Num- ber Adverse Pressure Gradient Turbulent Boundary Layer

NASA Astrophysics Data System (ADS)

Atkinson, Callum; Amili, Omid; Stanislas, Michel; Cuvier, Christophe; Foucaut, Jean-Marc; Srinath, Sricharan; Laval, Jean-Philippe; Kaehler, Christian; Hain, Rainer; Scharnowski, Sven; Schroeder, Andreas; Geisler, Reinhard; Agocs, Janos; Roese, Anni; Willert, Christian; Klinner, Joachim; Soria, Julio

2016-11-01

The study of adverse pressure gradient turbulent boundary layers is complicated by the need to characterise both the local pressure gradient and it's upstream flow history. It is therefore necessary to measure a significant streamwise domain at a resolution sufficient to resolve the small scales features. To achieve this collaborative particle image velocimetry (PIV) measurements were performed in the large boundary layer wind-tunnel at the Laboratoire de Mecanique de Lille, including: planar measurements spanning a streamwise domain of 3.5m using 16 cameras covering 15 δ spanwise wall-normal stereo-PIV measurements, high-speed micro-PIV of the near wall region and wall shear stress; and streamwise wall-normal PIV in the viscous sub layer. Details of the measurements and preliminary results will be presented.

Flight Measurement of Wall-Pressure Fluctuations and Boundary-Layer Turbulence

NASA Technical Reports Server (NTRS)

Mull, Harold R.; Algranti, Joseph S.

1960-01-01

The results are presented for a flight test program using a fighter type jet aircraft flying at pressure altitudes of 10,000, 20,000, and 30,000 feet at Mach numbers from 0.3 to 0.8. Specially designed apparatus was used to measure and record the output of microphones and hot-wire anemometers mounted on the forward-fuselage section and wing of the airplane. Mean-velocity profiles in the boundary layers were obtained from total-pressure measurements. The ratio of the root-mean-square fluctuating wall pressure to the free-stream dynamic pressure is presented as a function of Reynolds number and Mach number. The longitudinal component of the turbulent-velocity fluctuations was measured, and the turbulence-intensity profiles are presented for the wing and forward-fuselage section. In general, the results are in agreement with wind-tunnel measurements which have been-reported in the literature. For example, the variation the square root of p(sup 2)/q times the square root of p(sup 2) is the root mean square of the wall-pressure fluctuation, and q is the free-stream dynamic pressure) with Reynolds number was found to be essentially constant for the forward-fuselage-section boundary layer, while variations at the wing station were probably unduly affected by the microphone diameter (5/8 in.), which was large compared with the boundary-layer thickness.

Comparative Measurements of Total Temperature in a Supersonic Turbulent Boundary Layer Using a Conical Equilibrium and Combined Temperature-Pressure Probe

DTIC Science & Technology

1974-07-01

AD/A-002 982 COMPARATIVE MEASUREMENTS CF TOTAL TEMPERATURE IN A SUPERSONIC TURBULENT BOUNDARY LAYER USING A CONICAL EQUILIB- RIUM AND COMBINED...SUPERSONIC TURBULENT BOUNDARY LAYER USING A CONICAL EQUILIORIUM AND COMBINED TEMPERATURE-PRESSURE PROBE H.L.P. Vowt R.E. L" 0H.U. M.i July 1974 NAVAL...1 ~~o iotaPRO eig ature In A Supersonic Turbulent Boundary ____________ Layer Using A Conical Equilibrium and 6. 111111ORWING OR. 0111001117,~t

High gain durable anti-reflective coating with oblate voids

DOEpatents

Maghsoodi, Sina; Brophy, Brenor L.; Colson, Thomas E.; Gonsalves, Peter R.; Abrams, Ze'ev

2016-06-28

Disclosed herein are single layer transparent coatings with an anti-reflective property, a hydrophobic property, and that are highly abrasion resistant. The single layer transparent coatings contain a plurality of oblate voids. At least 1% of the oblate voids are open to a surface of the single layer transparent coatings.

Measurement of density and temperature in a hypersonic turbulent boundary layer using the electron beam fluorescence technique. Ph.D. Thesis. Final Report, 1 Oct. 1969 - 1 Sep. 1972

NASA Technical Reports Server (NTRS)

Mcronald, A. D.

1975-01-01

Mean density and temperature fluctuations were measured across the turbulent, cooled-wall boundary layer in a continuous hypersonic (Mach 9.4) wind tunnel in air, using the nitrogen fluorescence excited by a 50 kV electron beam. Data were taken at three values of the tunnel stagnation pressure, the corresponding free stream densities being equivalent to 1.2, 4.0, and 7.4 torr at room temperature, and the boundary layer thicknesses about 4.0, 4.5, and 6.0 inches. The mean temperature and density profiles were similar to those previously determined in the same facility by conventional probes (static and pitot pressure, total temperature). A static pressure variation of about 50% across the boundary layer was found, the shape of the variation changing somewhat for the three stagnation pressure levels. The quadrupole model for rotational temperature spectra gave closer agreement with the free stream isentropic level (approximately 44 K) than the dipole model.

Experimental Studies of Flow Separation of the NACA 2412 Airfoil at Low Speeds

NASA Technical Reports Server (NTRS)

Seetharam, H. C.; Rodgers, E. J.; Wentz, W. H., Jr.

1997-01-01

Wind tunnel tests have been conducted on an NACA 2412 airfoil section at Reynolds number of 2.2 x 10(exp 6) and Mach number of 0.13. Detailed measurements of flow fields associated with turbulent boundary layers have been obtained at angles of attack of 12.4 degrees, 14.4 degrees, and 16.4 degrees. Pre- and post-separated velocity and pressure survey results over the airfoil and in the associated wake are presented. Extensive force, pressure, tuft survey, hot-film survey, local skin friction, and boundary layer data are also included. Pressure distributions and separation point locations show good agreement with theory for the two layer angles of attack. Boundary layer displacement thickness, momentum thickness, and shape factor agree well with theory up to the point of separation. There is considerable disparity between extent of flow reversal in the wake as measured by pressure and hot-film probes. The difference is attributed to the intermittent nature of the flow reversal.

Flow prediction over a transport multi-element high-lift system and comparison with flight measurements

NASA Technical Reports Server (NTRS)

Vijgen, P. M. H. W.; Hardin, J. D.; Yip, L. P.

1992-01-01

Accurate prediction of surface-pressure distributions, merging boundary-layers, and separated-flow regions over multi-element high-lift airfoils is required to design advanced high-lift systems for efficient subsonic transport aircraft. The availability of detailed measurements of pressure distributions and both averaged and time-dependent boundary-layer flow parameters at flight Reynolds numbers is critical to evaluate computational methods and to model the turbulence structure for closure of the flow equations. Several detailed wind-tunnel measurements at subscale Reynolds numbers were conducted to obtain detailed flow information including the Reynolds-stress component. As part of a subsonic-transport high-lift research program, flight experiments are conducted using the NASA-Langley B737-100 research aircraft to obtain detailed flow characteristics for support of computational and wind-tunnel efforts. Planned flight measurements include pressure distributions at several spanwise locations, boundary-layer transition and separation locations, surface skin friction, as well as boundary-layer profiles and Reynolds stresses in adverse pressure-gradient flow.

Direct visualization of a two-dimensional topological insulator in the single-layer 1 T'-WT e2

NASA Astrophysics Data System (ADS)

Jia, Zhen-Yu; Song, Ye-Heng; Li, Xiang-Bing; Ran, Kejing; Lu, Pengchao; Zheng, Hui-Jun; Zhu, Xin-Yang; Shi, Zhi-Qiang; Sun, Jian; Wen, Jinsheng; Xing, Dingyu; Li, Shao-Chun

2017-07-01

We have grown nearly freestanding single-layer 1 T'-WT e2 on graphitized 6 H -SiC(0001) by using molecular beam epitaxy (MBE), and characterized its electronic structure with scanning tunneling microscopy/spectroscopy (STM/STS). The existence of topological edge states at the periphery of single-layer WT e2 islands was confirmed. Surprisingly, a bulk band gap at the Fermi level and insulating behaviors were also found in single-layer WT e2 at low temperature, which are likely associated with an incommensurate charge order transition. The realization of two-dimensional topological insulators (2D TIs) in single-layer transition-metal dichalcogenide provides a promising platform for further exploration of the 2D TIs' physics and related applications.

Research on subsurface deformed layer in ultra-precision cutting of single crystal copper by focused ion beam etching method

NASA Astrophysics Data System (ADS)

Chen, Y.; Huang, X. J.; Kong, J. X.

2018-03-01

In this paper, the focused ion beam was used to study the subsurface deformed layer of single crystal copper caused by the nanoscale single-point diamond fly cutting, and the possibility of using nanometer ultra-precision cutting to remove the larger deformation layer caused by traditional rough cutting process was explored. The maximum cutting thickness of single-point diamond cutting was about 146 nm, and the surface of the single-crystal copper after cutting was etched and observed by using the focused ion beam method. It was found that the morphology of the near-surface layer and the intermediate layer of the copper material were larger differences: the near-surface of the material was smaller and more compact, and the intermediate material layer of the material was more coarse sparse. The results showed that the traditional precision cutting would residual significant subsurface deformed layer and the thickness was on micron level. Even more, the subsurface deformed layer was obviously removed from about 12μm to 5μm after single-point diamond fly cutting in this paper. This paper proved that the large-scale subsurface deformed layer caused by traditional cutting process could be removed by nanometer ultra-precision cutting. It was of great significance to further establish the method that control of the deformation of weak rigid components by reducing the depth of the subsurface deformed layers.

Predictive Analytical Model for Isolator Shock-Train Location in a Mach 2.2 Direct-Connect Supersonic Combustion Tunnel

NASA Astrophysics Data System (ADS)

Lingren, Joe; Vanstone, Leon; Hashemi, Kelley; Gogineni, Sivaram; Donbar, Jeffrey; Akella, Maruthi; Clemens, Noel

2016-11-01

This study develops an analytical model for predicting the leading shock of a shock-train in the constant area isolator section in a Mach 2.2 direct-connect scramjet simulation tunnel. The effective geometry of the isolator is assumed to be a weakly converging duct owing to boundary-layer growth. For some given pressure rise across the isolator, quasi-1D equations relating to isentropic or normal shock flows can be used to predict the normal shock location in the isolator. The surface pressure distribution through the isolator was measured during experiments and both the actual and predicted locations can be calculated. Three methods of finding the shock-train location are examined, one based on the measured pressure rise, one using a non-physics-based control model, and one using the physics-based analytical model. It is shown that the analytical model performs better than the non-physics-based model in all cases. The analytic model is less accurate than the pressure threshold method but requires significantly less information to compute. In contrast to other methods for predicting shock-train location, this method is relatively accurate and requires as little as a single pressure measurement. This makes this method potentially useful for unstart control applications.

High-pressure high-temperature phase diagram of gadolinium studied using a boron-doped heater anvil

NASA Astrophysics Data System (ADS)

Montgomery, J. M.; Samudrala, G. K.; Velisavljevic, N.; Vohra, Y. K.

2016-04-01

A boron-doped designer heater anvil is used in conjunction with powder x-ray diffraction to collect structural information on a sample of quasi-hydrostatically loaded gadolinium metal up to pressures above 8 GPa and 600 K. The heater anvil consists of a natural diamond anvil that has been surface modified with a homoepitaxially grown chemical-vapor-deposited layer of conducting boron-doped diamond, and is used as a DC heating element. Internally insulating both diamond anvils with sapphire support seats allows for heating and cooling of the high-pressure area on the order of a few tens of seconds. This device is then used to scan the phase diagram of the sample by oscillating the temperature while continuously increasing the externally applied pressure and collecting in situ time-resolved powder diffraction images. In the pressure-temperature range covered in this experiment, the gadolinium sample is observed in its hcp, αSm, and dhcp phases. Under this temperature cycling, the hcp → αSm transition proceeds in discontinuous steps at points along the expected phase boundary. From these measurements (representing only one hour of synchrotron x-ray collection time), a single-experiment equation of state and phase diagram of each phase of gadolinium is presented for the range of 0-10 GPa and 300-650 K.

Supersonic turbulent boundary layers with periodic mechanical non-equilibrium

NASA Astrophysics Data System (ADS)

Ekoto, Isaac Wesley

Previous studies have shown that favorable pressure gradients reduce the turbulence levels and length scales in supersonic flow. Wall roughness has been shown to reduce the large-scales in wall bounded flow. Based on these previous observations new questions have been raised. The fundamental questions this dissertation addressed are: (1) What are the effects of wall topology with sharp versus blunt leading edges? and (2) Is it possible that a further reduction of turbulent scales can occur if surface roughness and favorable pressure gradients are combined? To answer these questions and to enhance the current experimental database, an experimental analysis was performed to provide high fidelity documentation of the mean and turbulent flow properties along with surface and flow visualizations of a high-speed (M = 2.86), high Reynolds number (Retheta ≈ 60,000) supersonic turbulent boundary layer distorted by curvature-induced favorable pressure gradients and large-scale ( k+s ≈ 300) uniform surface roughness. Nine models were tested at three separate locations. Three pressure gradient models strengths (a nominally zero, a weak, and a strong favorable pressure gradient) and three roughness topologies (aerodynamically smooth, square, and diamond shaped roughness elements) were used. Highly resolved planar measurements of mean and fluctuating velocity components were accomplished using particle image velocimetry. Stagnation pressure profiles were acquired with a traversing Pitot probe. Surface pressure distributions were characterized using pressure sensitive paint. Finally flow visualization was accomplished using schlieren photographs. Roughness topology had a significant effect on the boundary layer mean and turbulent properties due to shock boundary layer interactions. Favorable pressure gradients had the expected stabilizing effect on turbulent properties, but the improvements were less significant for models with surface roughness near the wall due to increased tendency towards flow separation. It was documented that proper roughness selection coupled with a sufficiently strong favorable pressure gradient produced regions of "negative" production in the transport of turbulent stress. This led to localized areas of significant turbulence stress reduction. With proper roughness selection and sufficient favorable pressure gradient strength, it is believed that localized relaminarization of the boundary layer is possible.

Diffusion and Monod kinetics model to determine in vivo human corneal oxygen-consumption rate during soft contact lens wear.

PubMed

Del Castillo, Luis F; da Silva, Ana R Ferreira; Hernández, Saul I; Aguilella, M; Andrio, Andreu; Mollá, Sergio; Compañ, Vicente

2015-01-01

We present an analysis of the corneal oxygen consumption Qc from non-linear models, using data of oxygen partial pressure or tension (P(O2) ) obtained from in vivo estimation previously reported by other authors. (1) METHODS: Assuming that the cornea is a single homogeneous layer, the oxygen permeability through the cornea will be the same regardless of the type of lens that is available on it. The obtention of the real value of the maximum oxygen consumption rate Qc,max is very important because this parameter is directly related with the gradient pressure profile into the cornea and moreover, the real corneal oxygen consumption is influenced by both anterior and posterior oxygen fluxes. Our calculations give different values for the maximum oxygen consumption rate Qc,max, when different oxygen pressure values (high and low P(O2)) are considered at the interface cornea-tears film. Present results are relevant for the calculation on the partial pressure of oxygen, available at different depths into the corneal tissue behind contact lenses of different oxygen transmissibility. Copyright © 2014. Published by Elsevier Espana.

Chemical and engineering approaches to enable organic field-effect transistors for electronic skin applications.

PubMed

Sokolov, Anatoliy N; Tee, Benjamin C-K; Bettinger, Christopher J; Tok, Jeffrey B-H; Bao, Zhenan

2012-03-20

Skin is the body's largest organ and is responsible for the transduction of a vast amount of information. This conformable material simultaneously collects signals from external stimuli that translate into information such as pressure, pain, and temperature. The development of an electronic material, inspired by the complexity of this organ is a tremendous, unrealized engineering challenge. However, the advent of carbon-based electronics may offer a potential solution to this long-standing problem. In this Account, we describe the use of an organic field-effect transistor (OFET) architecture to transduce mechanical and chemical stimuli into electrical signals. In developing this mimic of human skin, we thought of the sensory elements of the OFET as analogous to the various layers and constituents of skin. In this fashion, each layer of the OFET can be optimized to carry out a specific recognition function. The separation of multimodal sensing among the components of the OFET may be considered a "divide and conquer" approach, where the electronic skin (e-skin) can take advantage of the optimized chemistry and materials properties of each layer. This design of a novel microstructured gate dielectric has led to unprecedented sensitivity for tactile pressure events. Typically, pressure-sensitive components within electronic configurations have suffered from a lack of sensitivity or long mechanical relaxation times often associated with elastomeric materials. Within our method, these components are directly compatible with OFETs and have achieved the highest reported sensitivity to date. Moreover, the tactile sensors operate on a time scale comparable with human skin, making them ideal candidates for integration as synthetic skin devices. The methodology is compatible with large-scale fabrication and employs simple, commercially available elastomers. The design of materials within the semiconductor layer has led to the incorporation of selectivity and sensitivity within gas-sensing devices and has enabled stable sensor operation within aqueous media. Furthermore, careful tuning of the chemical composition of the dielectric layer has provided a means to operate the sensor in real time within an aqueous environment and without the need for encapsulation layers. The integration of such devices as electronic mimics of skin will require the incorporation of biocompatible or biodegradable components. Toward this goal, OFETs may be fabricated with >99% biodegradable components by weight, and the devices are robust and stable, even in aqueous environments. Collectively, progress to date suggests that OFETs may be integrated within a single substrate to function as an electronic mimic of human skin, which could enable a large range of sensing-related applications from novel prosthetics to robotic surgery.

Deplacement effect of the laminar boundary layer and the pressure drag

NASA Technical Reports Server (NTRS)

Gortler, H

1951-01-01

The displacement effect of the boundary layer on the outer frictionless flow is discussed for both steady and unsteady flows. The analysis is restricted to cases in which the potential flow pressure distribution remains valid for the boundary-layer calculation. Formulas are given for the dependence of the pressure drag, friction drag, and total drag of circular cylinders on the time from the start of motion for cases in which the velocity varies as a power of the time. Formulas for the locations and for the time for the appearance of the separation point are given for two dimensional bodies of arbitrary shape.

Numerical Study of Pressure Fluctuations due to a Mach 6 Turbulent Boundary Layer

NASA Technical Reports Server (NTRS)

Duan, Lian; Choudhari, Meelan M.

2013-01-01

Direct numerical simulations (DNS) are used to examine the pressure fluctuations generated by a Mach 6 turbulent boundary layer with nominal freestream Mach number of 6 and Reynolds number of Re(sub t) approx. =. 464. The emphasis is on comparing the primarily vortical pressure signal at the wall with the acoustic freestream signal under higher Mach number conditions. Moreover, the Mach-number dependence of pressure signals is demonstrated by comparing the current results with those of a supersonic boundary layer at Mach 2.5 and Re(sub t) approx. = 510. It is found that the freestream pressure intensity exhibits a strong Mach number dependence, irrespective of whether it is normalized by the mean wall shear stress or by the mean pressure, with the normalized fluctuation amplitude being significantly larger for the Mach 6 case. Spectral analysis shows that both the wall and freestream pressure fluctuations of the Mach 6 boundary layer have enhanced energy content at high frequencies, with the peak of the premultiplied frequency spectrum of freestream pressure fluctuations being at a frequency of omega(delta)/U(sub infinity) approx. = 3.1, which is more than twice the corresponding frequency in the Mach 2.5 case. The space-time correlations indicate that the pressure-carrying eddies for the higher Mach number case are of smaller size, less elongated in the spanwise direction, and convect with higher convection speeds relative to the Mach 2.5 case. The demonstrated Mach-number dependence of the pressure field, including radiation intensity, directionality, and convection speed, is consistent with the trend exhibited in experimental data and can be qualitatively explained by the notion of "eddy Mach wave" radiation.

Friction-induced skin injuries-are they pressure ulcers? An updated NPUAP white paper.

PubMed

Brienza, David; Antokal, Steven; Herbe, Laura; Logan, Susan; Maguire, Jeanine; Van Ranst, Jennifer; Siddiqui, Aamir

2015-01-01

Friction injuries are often misdiagnosed as pressure ulcers. The reason for the misdiagnosis may be a misinterpretation of classic pressure ulcer literature that reported friction increased the susceptibility of the skin to pressure damage. This analysis assesses the classic literature that led to the inclusion of friction as a causative factor in the development of pressure ulcers in light of more recent research on the effects of shear. The analysis in this article suggests that friction can contribute to pressure ulcers by creating shear strain in deeper tissues, but friction does not appear to contribute to pressure ulcers in the superficial layers of the skin. Injuries to the superficial layers of the skin caused by friction are not pressure ulcers and should not be classified or treated as such.

Electromodulation spectroscopy of direct optical transitions in Ge{sub 1−x}Sn{sub x} layers under hydrostatic pressure and built-in strain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dybała, F.; Żelazna, K.; Maczko, H.

Unstrained Ge{sub 1−x}Sn{sub x} layers of various Sn concentration (1.5%, 3%, 6% Sn) and Ge{sub 0.97}Sn{sub 0.03} layers with built-in compressive (ε = −0.5%) and tensile (ε = 0.3%) strain are grown by molecular beam epitaxy and studied by electromodulation spectroscopy (i.e., contactless electroreflectance and photoreflectance (PR)). In order to obtain unstrained GeSn layers and layers with different built-in in-plane strains, virtual InGaAs substrates of different compositions are grown prior to the deposition of GeSn layers. For unstrained Ge{sub 1−x}Sn{sub x} layers, the pressure coefficient for the direct band gap transition is determined from PR measurements at various hydrostatic pressures to be 12.2 ± 0.2 meV/kbar, whichmore » is very close to the pressure coefficient for the direct band gap transition in Ge (12.9 meV/kbar). This suggests that the hydrostatic deformation potentials typical of Ge can be applied to describe the pressure-induced changes in the electronic band structure of Ge{sub 1−x}Sn{sub x} alloys with low Sn concentrations. The same conclusion is derived for the uniaxial deformation potential, which describes the splitting between heavy-hole (HH) and light-hole (LH) bands as well as the strain-related shift of the spin-orbit (SO) split-off band. It is observed that the HH, LH, and SO related transitions shift due to compressive and tensile strain according to the Bir-Pikus theory. The dispersions of HH, LH, and SO bands are calculated for compressive and tensile strained Ge{sub 0.97}Sn{sub 0.03} with the 8-band kp Hamiltonian including strain effects, and the mixing of HH and LH bands is discussed. In addition, the dispersion of the electronic band structure is calculated for unstrained Ge{sub 1−x}Sn{sub x} layers (3% and 6% Sn) at high hydrostatic pressure with the 8-band kp Hamiltonian, and the pressure-induced changes in the electronic band structure are discussed.« less

Site selectivity on chalcogen atoms in superconducting La(O,F)BiSSe

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tanaka, Masashi, E-mail: Tanaka.Masashi@nims.go.jp; Matsushita, Yoshitaka; Fujioka, Masaya

2015-03-16

Single crystals of La(O,F)BiSSe were grown by using a CsCl flux method. Single crystal X-ray structural analysis reveals that the crystal structure is isostructural to the BiS{sub 2}- or BiSe{sub 2}-based compounds crystallizing with space group P4/nmm (lattice parameters a = 4.1110(2) Å, c = 13.6010(7) Å). However, the S atoms are selectively occupied at the apical site of the Bi-SSe pyramids in the superconducting layer. The single crystals show a superconducting transition at around 4.2 K in the magnetic susceptibility and resistivity measurements. The superconducting anisotropic parameter is determined to be 34–35 from its upper critical magnetic field. The anisotropy is in the same range withmore » that of other members of the La(O,F)BiCh{sub 2} (Ch = S, Se) family under ambient pressure.« less

Experimental results for a hypersonic nozzle/afterbody flow field

NASA Technical Reports Server (NTRS)

Spaid, Frank W.; Keener, Earl R.; Hui, Frank C. L.

1995-01-01

This study was conducted to experimentally characterize the flow field created by the interaction of a single-expansion ramp-nozzle (SERN) flow with a hypersonic external stream. Data were obtained from a generic nozzle/afterbody model in the 3.5 Foot Hypersonic Wind Tunnel at the NASA Ames Research Center, in a cooperative experimental program involving Ames and McDonnell Douglas Aerospace. The model design and test planning were performed in close cooperation with members of the Ames computational fluid dynamics (CFD) team for the National Aerospace Plane (NASP) program. This paper presents experimental results consisting of oil-flow and shadow graph flow-visualization photographs, afterbody surface-pressure distributions, rake boundary-layer measurements, Preston-tube skin-friction measurements, and flow field surveys with five-hole and thermocouple probes. The probe data consist of impact pressure, flow direction, and total temperature profiles in the interaction flow field.

Experimental vibroacoustic testing of plane panels using synthesized random pressure fields.

PubMed

Robin, Olivier; Berry, Alain; Moreau, Stéphane

2014-06-01

The experimental reproduction of random pressure fields on a plane panel and corresponding induced vibrations is studied. An open-loop reproduction strategy is proposed that uses the synthetic array concept, for which a small array element is moved to create a large array by post-processing. Three possible approaches are suggested to define the complex amplitudes to be imposed to the reproduction sources distributed on a virtual plane facing the panel to be tested. Using a single acoustic monopole, a scanning laser vibrometer and a baffled simply supported aluminum panel, experimental vibroacoustic indicators such as the Transmission Loss for Diffuse Acoustic Field, high-speed subsonic and supersonic Turbulent Boundary Layer excitations are obtained. Comparisons with simulation results obtained using a commercial software show that the Transmission Loss estimation is possible under both excitations. Moreover and as a complement to frequency domain indicators, the vibroacoustic behavior of the panel can be studied in the wave number domain.

Femtosecond-laser hyperdoping silicon in an SF{sub 6} atmosphere: Dopant incorporation mechanism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sher, Meng-Ju, E-mail: msher@stanford.edu; Mangan, Niall M.; Lin, Yu-Ting

2015-03-28

In this paper, we examine the fundamental processes that occur during femtosecond-laser hyperdoping of silicon with a gas-phase dopant precursor. We probe the dopant concentration profile as a function of the number of laser pulses and pressure of the dopant precursor (sulfur hexafluoride). In contrast to previous studies, we show the hyperdoped layer is single crystalline. From the dose dependence on pressure, we conclude that surface adsorbed molecules are the dominant source of the dopant atoms. Using numerical simulation, we estimate the change in flux with increasing number of laser pulses to fit the concentration profiles. We hypothesize that themore » native oxide plays an important role in setting the surface boundary condition. As a result of the removal of the native oxide by successive laser pulses, dopant incorporation is more efficient during the later stage of laser irradiation.« less

Single layer of Ge quantum dots in HfO2 for floating gate memory capacitors.

PubMed

Lepadatu, A M; Palade, C; Slav, A; Maraloiu, A V; Lazanu, S; Stoica, T; Logofatu, C; Teodorescu, V S; Ciurea, M L

2017-04-28

High performance trilayer memory capacitors with a floating gate of a single layer of Ge quantum dots (QDs) in HfO 2 were fabricated using magnetron sputtering followed by rapid thermal annealing (RTA). The layer sequence of the capacitors is gate HfO 2 /floating gate of single layer of Ge QDs in HfO 2 /tunnel HfO 2 /p-Si wafers. Both Ge and HfO 2 are nanostructured by RTA at moderate temperatures of 600-700 °C. By nanostructuring at 600 °C, the formation of a single layer of well separated Ge QDs with diameters of 2-3 nm at a density of 4-5 × 10 15 m -2 is achieved in the floating gate (intermediate layer). The Ge QDs inside the intermediate layer are arranged in a single layer and are separated from each other by HfO 2 nanocrystals (NCs) about 8 nm in diameter with a tetragonal/orthorhombic structure. The Ge QDs in the single layer are located at the crossing of the HfO 2 NCs boundaries. In the intermediate layer, besides Ge QDs, a part of the Ge atoms is segregated by RTA at the HfO 2 NCs boundaries, while another part of the Ge atoms is present inside the HfO 2 lattice stabilizing the tetragonal/orthorhombic structure. The fabricated capacitors show a memory window of 3.8 ± 0.5 V and a capacitance-time characteristic with 14% capacitance decay in the first 3000-4000 s followed by a very slow capacitance decrease extrapolated to 50% after 10 years. This high performance is mainly due to the floating gate of a single layer of well separated Ge QDs in HfO 2 , distanced from the Si substrate by the tunnel oxide layer with a precise thickness.

Shock Train/Boundary-Layer Interaction in Rectangular Scramjet Isolators

NASA Astrophysics Data System (ADS)

Geerts, Jonathan Simon

Numerous studies of the dual-mode scramjet isolator, a critical component in preventing inlet unstart and/or vehicle loss by containing a collection of flow disturbances called a shock train, have been performed since the dual-mode propulsion cycle was introduced in the 1960s. Low momentum corner flow and other three-dimensional effects inherent to rectangular isolators have, however, been largely ignored in experimental studies of the boundary layer separation driven isolator shock train dynamics. Furthermore, the use of two dimensional diagnostic techniques in past works, be it single-perspective line-of-sight schlieren/shadowgraphy or single axis wall pressure measurements, have been unable to resolve the three-dimensional flow features inside the rectangular isolator. These flow characteristics need to be thoroughly understood if robust dual-mode scramjet designs are to be fielded. The work presented in this thesis is focused on experimentally analyzing shock train/boundary layer interactions from multiple perspectives in aspect ratio 1.0, 3.0, and 6.0 rectangular isolators with inflow Mach numbers ranging from 2.4 to 2.7. Secondary steady-state Computational Fluid Dynamics studies are performed to compare to the experimental results and to provide additional perspectives of the flow field. Specific issues that remain unresolved after decades of isolator shock train studies that are addressed in this work include the three-dimensional formation of the isolator shock train front, the spatial and temporal low momentum corner flow separation scales, the transient behavior of shock train/boundary layer interaction at specific coordinates along the isolator's lateral axis, and effects of the rectangular geometry on semi-empirical relations for shock train length prediction. (Abstract shortened by ProQuest.).

Bi/In thermal resist for both Si anisotropic wet etching and Si/SiO2 plasma etching

NASA Astrophysics Data System (ADS)

Chapman, Glenn H.; Tu, Yuqiang; Peng, Jun

2004-01-01

Bi/In thermal resist is a bilayer structure of Bi over In films which can be exposed by laser with a wide range of wavelengths and can be developed by diluted RCA2 solutions. Current research shows bimetallic resist can work as etch masking layer for both dry plasma etching and wet anisotropic etching. It can act as both patterning and masking layers for Si and SiO2 with plasma "dry" etch using CF4/CHF3. The etching condition is CF4 flow rate 50 sccm, pressure 150 mTorr, and RF power 100 - 600W. The profile of etched structures can be tuned by adding CHF3 and other gases such as Ar, and by changing the CF4/CHF3 ratio. Depending on the fluorocarbon plasma etching recipe the etch rate of laser exposed Bi/In can be as low as 0.1 nm/min, 500 times lower than organic photoresists. O2 plasma ashing has little etching effect on exposed Bi/In. Bi/In also creates etch masking layers for alkaline-based (KOH, TMAH and EDP) "wet" anisotropic bulk Si etch without the need of SiO2 masking steps. The laser exposed Bi/In etches two times more slowly than SiO2. Experiment result shows that single metal Indium film exhibits thermal resist characteristics but at twice the exposure levels. It can be developed in diluted RCA2 solution and used as an etch mask layer for Si anisotropic etch. X-ray diffraction analysis shows that laser exposure causes both Bi and In single film to oxidize. In film may become amorphous when exposed to high laser power.

Bubble gate for in-plane flow control.

PubMed

Oskooei, Ali; Abolhasani, Milad; Günther, Axel

2013-07-07

We introduce a miniature gate valve as a readily implementable strategy for actively controlling the flow of liquids on-chip, within a footprint of less than one square millimetre. Bubble gates provide for simple, consistent and scalable control of liquid flow in microchannel networks, are compatible with different bulk microfabrication processes and substrate materials, and require neither electrodes nor moving parts. A bubble gate consists of two microchannel sections: a liquid-filled channel and a gas channel that intercepts the liquid channel to form a T-junction. The open or closed state of a bubble gate is determined by selecting between two distinct gas pressure levels: the lower level corresponds to the "open" state while the higher level corresponds to the "closed" state. During closure, a gas bubble penetrates from the gas channel into the liquid, flanked by a column of equidistantly spaced micropillars on each side, until the flow of liquid is completely obstructed. We fabricated bubble gates using single-layer soft lithographic and bulk silicon micromachining procedures and evaluated their performance with a combination of theory and experimentation. We assessed the dynamic behaviour during more than 300 open-and-close cycles and report the operating pressure envelope for different bubble gate configurations and for the working fluids: de-ionized water, ethanol and a biological buffer. We obtained excellent agreement between the experimentally determined bubble gate operational envelope and a theoretical prediction based on static wetting behaviour. We report case studies that serve to illustrate the utility of bubble gates for liquid sampling in single and multi-layer microfluidic devices. Scalability of our strategy was demonstrated by simultaneously addressing 128 bubble gates.

Effectiveness and Value of Prophylactic 5-Layer Foam Sacral Dressings to Prevent Hospital-Acquired Pressure Injuries in Acute Care Hospitals: An Observational Cohort Study.

PubMed

Padula, William V

The purpose of this study was to examine the effectiveness and value of prophylactic 5-layer foam sacral dressings to prevent hospital-acquired pressure injury rates in acute care settings. Retrospective observational cohort. We reviewed records of adult patients 18 years or older who were hospitalized at least 5 days across 38 acute care hospitals of the University Health System Consortium (UHC) and had a pressure injury as identified by Patient Safety Indicator #3 (PSI-03). All facilities are located in the United States. We collected longitudinal data pertaining to prophylactic 5-layer foam sacral dressings purchased by hospital-quarter for 38 academic medical centers between 2010 and 2015. Longitudinal data on acute care, hospital-level patient outcomes (eg, admissions and PSI-03 and pressure injury rate) were queried through the UHC clinical database/resource manager from the Johns Hopkins Medicine portal. Data on volumes of dressings purchased per UHC hospital were merged with UHC data. Mixed-effects negative binomial regression was used to test the longitudinal association of prophylactic foam sacral dressings on pressure injury rates, adjusted for hospital case-mix and Medicare payments rules. Significant pressure injury rate reductions in US acute care hospitals between 2010 and 2015 were associated with the adoption of prophylactic 5-layer foam sacral dressings within a prevention protocol (-1.0 cases/quarter; P = .002) and changes to Medicare payment rules in 2014 (-1.13 cases/quarter; P = .035). Prophylactic 5-layer foam sacral dressings are an effective component of a pressure injury prevention protocol. Hospitals adopting these technologies should expect good value for use of these products.

Effectiveness and Value of Prophylactic 5-Layer Foam Sacral Dressings to Prevent Hospital-Acquired Pressure Injuries in Acute Care Hospitals

PubMed Central

2017-01-01

PURPOSE: The purpose of this study was to examine the effectiveness and value of prophylactic 5-layer foam sacral dressings to prevent hospital-acquired pressure injury rates in acute care settings. DESIGN: Retrospective observational cohort. SAMPLE AND SETTING: We reviewed records of adult patients 18 years or older who were hospitalized at least 5 days across 38 acute care hospitals of the University Health System Consortium (UHC) and had a pressure injury as identified by Patient Safety Indicator #3 (PSI-03). All facilities are located in the United States. METHODS: We collected longitudinal data pertaining to prophylactic 5-layer foam sacral dressings purchased by hospital-quarter for 38 academic medical centers between 2010 and 2015. Longitudinal data on acute care, hospital-level patient outcomes (eg, admissions and PSI-03 and pressure injury rate) were queried through the UHC clinical database/resource manager from the Johns Hopkins Medicine portal. Data on volumes of dressings purchased per UHC hospital were merged with UHC data. Mixed-effects negative binomial regression was used to test the longitudinal association of prophylactic foam sacral dressings on pressure injury rates, adjusted for hospital case-mix and Medicare payments rules. RESULTS: Significant pressure injury rate reductions in US acute care hospitals between 2010 and 2015 were associated with the adoption of prophylactic 5-layer foam sacral dressings within a prevention protocol (−1.0 cases/quarter; P = .002) and changes to Medicare payment rules in 2014 (−1.13 cases/quarter; P = .035). CONCLUSIONS: Prophylactic 5-layer foam sacral dressings are an effective component of a pressure injury prevention protocol. Hospitals adopting these technologies should expect good value for use of these products. PMID:28816929

Pressure induced superconductivity in very lightly doped LaFeAsO0.975F0.025

NASA Astrophysics Data System (ADS)

Miyoshi, K.; Otsuka, K.; Shiota, A.; Shimojo, Y.; Motoyama, G.; Fujiwara, K.; Kitagawa, H.; Nishigori, S.

2018-05-01

We have investigated whether or not superconductivity is induced by the application of pressure in very lightly F-doped LaFeAsO1-xFx , which shows spin density wave (SDW) state at ambient pressure, through the measurements of DC magnetization and electrical resistivity under pressure using pulse current sintered (PCS) high density polycrystalline specimens. It has been confirmed that the specimens with x = 0.025 shows superconductivity with Tcdia ∼ 15 K under pressure above ∼ 1.3 GPa. The pressure induced superconductivity can be explained by the lattice compression along c-axis, which enhances the electron doping from LaO layers to FeAs layers.

Effect of Group-III precursors on unintentional gallium incorporation during epitaxial growth of InAlN layers by metalorganic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Kim, Jeomoh; Ji, Mi-Hee; Detchprohm, Theeradetch; Dupuis, Russell D.; Fischer, Alec M.; Ponce, Fernando A.; Ryou, Jae-Hyun

2015-09-01

Unintentional incorporation of gallium (Ga) in InAlN layers grown with different molar flow rates of Group-III precursors by metalorganic chemical vapor deposition has been experimentally investigated. The Ga mole fraction in the InAl(Ga)N layer was increased significantly with the trimethylindium (TMIn) flow rate, while the trimethylaluminum flow rate controls the Al mole fraction. The evaporation of metallic Ga from the liquid phase eutectic system between the pyrolized In from injected TMIn and pre-deposited metallic Ga was responsible for the Ga auto-incorporation into the InAl(Ga)N layer. The theoretical calculation on the equilibrium vapor pressure of liquid phase Ga and the effective partial pressure of Group-III precursors based on growth parameters used in this study confirms the influence of Group-III precursors on Ga auto-incorporation. More Ga atoms can be evaporated from the liquid phase Ga on the surrounding surfaces in the growth chamber and then significant Ga auto-incorporation can occur due to the high equilibrium vapor pressure of Ga comparable to effective partial pressure of input Group-III precursors during the growth of InAl(Ga)N layer.

Micromachining of silicon carbide on silicon fabricated by low-pressure chemical vapour deposition

NASA Astrophysics Data System (ADS)

Behrens, Ingo; Peiner, Erwin; Bakin, Andrey S.; Schlachetzki, Andreas

2002-07-01

We describe the fabrication of silicon carbide layers for micromechanical applications using low-pressure metal-organic chemical vapour deposition at temperatures below 1000 °C. The layers can be structured by lift-off using silicon dioxide as a sacrificial layer. A large selectivity with respect to silicon can be exploited for bulk micromachining. Thin membranes are fabricated which exhibit high mechanical quality, as necessary for applications in harsh environments.

Shock wave oscillation driven by turbulent boundary layer fluctuations

NASA Technical Reports Server (NTRS)

Plotkin, K. J.

1972-01-01

Pressure fluctuations due to the interaction of a shock wave with a turbulent boundary layer were investigated. A simple model is proposed in which the shock wave is convected from its mean position by velocity fluctuations in the turbulent boundary layer. Displacement of the shock is assumed limited by a linear restoring mechanism. Predictions of peak root mean square pressure fluctuation and spectral density are in excellent agreement with available experimental data.

Flow-field measurements in the windward surface shock layer of space shuttle orbiter configurations at Mach number 8. [wind tunnel tests of scale models

NASA Technical Reports Server (NTRS)

Martindale, W. R.; Carter, L. D.

1975-01-01

Pitot pressure and total-temperature measurements were made in the windward surface shock layer of two 0.0175-scale space shuttle orbiter models at simulated re-entry conditions. Corresponding surface static pressure measurements were also made. Flow properties at the edge of the model boundary layer were derived from these measurements and compared with values calculated using conventional methods.

Characteristics of a separating confluent boundary layer and the downstream wake

NASA Technical Reports Server (NTRS)

Adair, Desmond; Horne, W. Clifton

1987-01-01

Measurements of pressure and velocity characteristics are presented and analyzed for flow over and downstream of a NACA 4412 airfoil equipped with a NACA 4415 single-slotted flap at high angle of attack and close to maximum lift. The flow remained attached over the main element while a large region of recirculating flow occurred over the aft 61 percent of the flap. The airfoil configuration was tested at a Mach number of 0.09 and a chord Reynolds number of 1.8x10 to the 6th power in the NASA Ames Research Center 7- by 10-Foot Wind Tunnel. Measurement of mean and fluctuation velocities were obtained in regions of recirculation and high turbulence intensity using 3-D laser velocimetry. In regions where the flow had a preferred direction and relatively low turbulence intensity, hot-wire anemometry was used. Emphasis was placed on obtaining characteristics in the confluent boundary layer, the region of recirculating flow, and in the downstream wake. Surface pressure measurements were made on the main airfoil, flap, wind tunnel roof and floor. It is thought likely that because the model is large when compared to the wind tunnel cross section, the wind tunnel floor and ceiling interference should be taken into account when the flow field is calculated.

The effects of inlet turbulence and rotor/stator interactions on the aerodynamics and heat transfer of a large-scale rotating turbine model. Volume 2: Heat transfer data tabulation. 15 percent axial spacing

NASA Technical Reports Server (NTRS)

Dring, R. P.; Blair, M. F.; Joslyn, H. D.

1986-01-01

A combined experimental and analytical program was conducted to examine the effects of inlet turbulence on airfoil heat transfer. The experimental portion of the study was conducted in a large-scale (approx 5X engine), ambient temperature, rotating turbine model configured in both single stage and stage-and-a-half arrangements. Heat transfer measurements were obtained using low-conductivity airfoils with miniature thermcouples welded to a thin, electrically heated surface skin. Heat transfer data were acquired for various combinations of low or high inlet turbulence intensity, flow coefficient, first-stator/rotor axial spacing, Reynolds number and relative circumferential position of the first and second stators. Aerodynamic measurements obtained as part of the program include distributions of the mean and fluctuating velocities at the turbine inlet and, for each airfoil row, midspan airfoil surface pressures and circumferential distributions of the downstream steady state pressures and fluctuating velocities. Analytical results include airfoil heat transfer predictions produced using existing 2-D boundary layer computation schemes and an examination of solutions of the unsteady boundary layer equations. The results are reported in four separate volumes, of which this is Volume 2: Heat Transfer Data Tabulation; 15 Percent Axial Spacing.

Development of membrane electrode assembly for high temperature proton exchange membrane fuel cell by catalyst coating membrane method

NASA Astrophysics Data System (ADS)

Liang, Huagen; Su, Huaneng; Pollet, Bruno G.; Pasupathi, Sivakumar

2015-08-01

Membrane electrode assembly (MEA), which contains cathode and anode catalytic layer, gas diffusion layers (GDL) and electrolyte membrane, is the key unit of a PEMFC. An attempt to develop MEA for ABPBI membrane based high temperature (HT) PEMFC is conducted in this work by catalyst coating membrane (CCM) method. The structure and performance of the MEA are examined by scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and I-V curve. Effects of the CCM preparation method, Pt loading and binder type are investigated for the optimization of the single cell performance. Under 160 °C and atmospheric pressure, the peak power density of the MEA, with Pt loading of 0.5 mg cm-2 and 0.3 mg cm-2 for the cathode and the anode, can reach 277 mW cm-2, while a current density of 620 A cm-2 is delivered at the working voltage of 0.4 V. The MEA prepared by CCM method shows good stability operating in a short term durability test: the cell voltage maintained at ∼0.45 V without obvious drop when operated at a constant current density of 300 mA cm-2 and 160 °C under ambient pressure for 140 h.

A study of the possible characteristics of a low-altitude electron layer in the Martian atmosphere

NASA Technical Reports Server (NTRS)

Wallio, H. A.

1974-01-01

The apparent diurnal Martian surface pressure variations, as deduced from radio occultation experiments, is discussed and explained as possibly arising from the effect of a low-altitude electron layer. Possible source and loss mechanisms for the low altitude electron layer are presented and discussed. Time dependent differential equations describing the electron layer are derived, and then integrated to investigate the electron distribution resulting from several processes that might occur in the atmosphere. It is concluded that the source mechanism is the sublimation of alkali atoms from a permanent dust layer, and that the dominant loss process must involve CO2 clustering about the alkali atoms. An electron layer is developed which explains the apparent diurnal surface pressure variation.

Durable Suit Bladder with Improved Water Permeability for Pressure and Environment Suits

NASA Technical Reports Server (NTRS)

Bue, Grant C.; Kuznetz, Larry; Orndoff, Evelyne; Tang, Henry; Aitchison, Lindsay; Ross, Amy

2009-01-01

Water vapor permeability is shown to be useful in rejecting heat and managing moisture accumulation in launch-and-entry pressure suits. Currently this is accomplished through a porous Gortex layer in the Advanced Crew and Escape Suit (ACES) and in the baseline design of the Constellation Suit System Element (CSSE) Suit 1. Non-porous dense monolithic membranes (DMM) that are available offer potential improvements for water vapor permeability with reduced gas leak. Accordingly, three different pressure bladder materials were investigated for water vapor permeability and oxygen leak: ElasthaneTM 80A (thermoplastic polyether urethane) provided from stock polymer material and two custom thermoplastic polyether urethanes. Water vapor, carbon dioxide and oxygen permeability of the DMM's was measured in a 0.13 mm thick stand-alone layer, a 0.08 mm and 0.05 mm thick layer each bonded to two different nylon and polyester woven reinforcing materials. Additional water vapor permeability and mechanical compression measurements were made with the reinforced 0.05 mm thick layers, further bonded with a polyester wicking and overlaid with moistened polyester fleece thermal underwear .This simulated the pressure from a supine crew person. The 0.05 mm thick nylon reinforced sample with polyester wicking layer was further mechanically tested for wear and abrasion. Concepts for incorporating these materials in launch/entry and Extravehicular Activity pressure suits are presented.

Bulk Kosterlitz-Thouless Type Molecular Superconductor β″-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6.

PubMed

Martin, Lee; Lopez, Jordan R; Akutsu, Hiroki; Nakazawa, Yasuhiro; Imajo, Shusaku

2017-11-20

A new molecular superconductor, β″-(BEDT-TTF) 2 [(H 2 O)(NH 4 ) 2 Cr(C 2 O 4 ) 3 ]·18-crown-6, has been synthesized from the organic donor molecule BEDT-TTF with the anion Cr(C 2 O 4 ) 3 3- . The crystal structure consists of conducting organic layers of BEDT-TTF molecules which adopt the β″ packing motif (layer A), layers of NH 4 + and Λ-Cr(C 2 O 4 ) 3 3- (layer B), layers of (H 2 O)(NH 4 )18-crown-6 (layer C), and layers of NH 4 + and Δ-Cr(C 2 O 4 ) 3 3- (layer D) which produce a superstructure with a repeating pattern of ABCDABCDA. As a result of this packing arrangement, this is the 2D superconductor with the widest gap between conducting layers where only a single donor packing motif is present (β″). Superconducting critical temperatures at ambient pressure observed by electrical transport and magnetic measurements are 4.0-4.9 and 2.5 K, respectively. The strong 2D nature of this system, the broad transition to T zero at 1.8K, and the transition of α of V ∝ I α from 1 to 3 on I-V curves strongly suggest that the superconducting transition is very close to a Kosterlitz-Thouless transition. The magnetic field dependence of the superconducting critical temperature parallel to the conducting plane gives an upper critical field μ 0 H c2∥ > 8 T, which is over the calculated Pauli-Clogston limit for this material.

Effect of O 2 gas partial pressure on structures and dielectric characteristics of rf sputtered ZrO 2 thin films

NASA Astrophysics Data System (ADS)

Ma, C. Y.; Lapostolle, F.; Briois, P.; Zhang, Q. Y.

2007-08-01

Amorphous and polycrystalline zirconium oxide thin films have been deposited by reactive rf magnetron sputtering in a mixed argon/oxygen or pure oxygen atmosphere with no intentional heating of the substrate. The films were characterized by high-resolution transmission electron microscopy (HR-TEM), atomic force microscopy (AFM), spectroscopic ellipsometry (SE), and capacitance versus voltage ( C- V) measurements to investigate the variation of structure, surface morphology, thickness of SiO 2-like interfacial layer as well as dielectric characteristics with different oxygen partial pressures. The films deposited at low oxygen partial pressures (less than 15%) are amorphous and dense with a smooth surface. In contrast, the films prepared at an oxygen partial pressure higher than 73% are crystallized with the microstructure changing from the mixture of monoclinic and tetragonal phases to a single monoclinic structure. The film structural transition is believed to be consequences of decrease in the oxygen vacancy concentration in the film and of increase of the energetically neutral particles in the plasma due to an increased oxygen partial pressure. SE measurements showed that significant interfacial SiO 2 growth has taken place above approximately 51%. The best C- V results in terms of relative dielectric constant values are obtained for thin films prepared at an oxygen partial pressure of 15%.

Optical and electronic properties of 2 H -Mo S2 under pressure: Revealing the spin-polarized nature of bulk electronic bands

NASA Astrophysics Data System (ADS)

Brotons-Gisbert, Mauro; Segura, Alfredo; Robles, Roberto; Canadell, Enric; Ordejón, Pablo; Sánchez-Royo, Juan F.

2018-05-01

Monolayers of transition-metal dichalcogenide semiconductors present spin-valley locked electronic bands, a property with applications in valleytronics and spintronics that is usually believed to be absent in their centrosymmetric (as the bilayer or bulk) counterparts. Here we show that bulk 2 H -Mo S2 hides a spin-polarized nature of states determining its direct band gap, with the spin sequence of valence and conduction bands expected for its single layer. This relevant finding is attained by investigating the behavior of the binding energy of A and B excitons under high pressure, by means of absorption measurements and density-functional-theory calculations. These results raise an unusual situation in which bright and dark exciton degeneracy is naturally broken in a centrosymmetric material. Additionally, the phonon-assisted scattering process of excitons has been studied by analyzing the pressure dependence of the linewidth of discrete excitons observed at the absorption coefficient edge of 2 H -Mo S2 . Also, the pressure dependence of the indirect optical transitions of bulk 2 H -Mo S2 has been analyzed by absorption measurements and density-functional-theory calculations. These results reflect a progressive closure of the indirect band gap as pressure increases, indicating that metallization of bulk Mo S2 may occur at pressures higher than 26 GPa.

Determination of combustion parameters using engine crankshaft speed

NASA Astrophysics Data System (ADS)

Taglialatela, F.; Lavorgna, M.; Mancaruso, E.; Vaglieco, B. M.

2013-07-01

Electronic engine controls based on real time diagnosis of combustion process can significantly help in complying with the stricter and stricter regulations on pollutants emissions and fuel consumption. The most important parameter for the evaluation of combustion quality in internal combustion engines is the in-cylinder pressure, but its direct measurement is very expensive and involves an intrusive approach to the cylinder. Previous researches demonstrated the direct relationship existing between in-cylinder pressure and engine crankshaft speed and several authors tried to reconstruct the pressure cycle on the basis of the engine speed signal. In this paper we propose the use of a Multi-Layer Perceptron neural network to model the relationship between the engine crankshaft speed and some parameters derived from the in-cylinder pressure cycle. This allows to have a non-intrusive estimation of cylinder pressure and a real time evaluation of combustion quality. The structure of the model and the training procedure is outlined in the paper. A possible combustion controller using the information extracted from the crankshaft speed information is also proposed. The application of the neural network model is demonstrated on a single-cylinder spark ignition engine tested in a wide range of speeds and loads. Results confirm that a good estimation of some combustion pressure parameters can be obtained by means of a suitable processing of crankshaft speed signal.

Flake Orientation Effects On Physical and Mechanical Properties of Sweetgum Flakeboard

Treesearch

T.F. Shupe; Chung-Yun Hse; E.W. Price

2001-01-01

Research was initiated to determine the effect of flake orientation on the physical and mechanical properties offlakeboard. The panel fabrication techniques investigated were single-layer panels with random and oriented flake distribution, three-layer, five-layer, and seven-layer panels. Single-layer oriented panels had panel directional property ratios of 11.8 and 12....

High-order accurate finite-volume formulations for the pressure gradient force in layered ocean models

NASA Astrophysics Data System (ADS)

Engwirda, Darren; Kelley, Maxwell; Marshall, John

2017-08-01

Discretisation of the horizontal pressure gradient force in layered ocean models is a challenging task, with non-trivial interactions between the thermodynamics of the fluid and the geometry of the layers often leading to numerical difficulties. We present two new finite-volume schemes for the pressure gradient operator designed to address these issues. In each case, the horizontal acceleration is computed as an integration of the contact pressure force that acts along the perimeter of an associated momentum control-volume. A pair of new schemes are developed by exploring different control-volume geometries. Non-linearities in the underlying equation-of-state definitions and thermodynamic profiles are treated using a high-order accurate numerical integration framework, designed to preserve hydrostatic balance in a non-linear manner. Numerical experiments show that the new methods achieve high levels of consistency, maintaining hydrostatic and thermobaric equilibrium in the presence of strongly-sloping layer geometries, non-linear equations-of-state and non-uniform vertical stratification profiles. These results suggest that the new pressure gradient formulations may be appropriate for general circulation models that employ hybrid vertical coordinates and/or terrain-following representations.

Development of the Los Alamos National Laboratory Cryogenic Pressure Loader

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ebey, Peter S.; Dole, James M.; Hoffer, James K.

2003-05-15

Targets for inertial fusion research and ignition at OMEGA, the National Ignition Facility, LMJ, and future facilities rely on beta-radiation-driven layering of spherical cryogenic DT ice layers contained within plastic or metal shells. Plastic shells will be permeation filled at room temperature then cooled to cryogenic temperatures before removal of the overpressure. The cryogenic pressure loader (CPL) was recently developed at Los Alamos National Laboratory as a testbed for studying the filling and layering of plastic target shells with DT. A technical description of the CPL is provided. The CPL consists of a cryostat, which contains a high-pressure permeation cell,more » and has optical access for investigating beta layering. The cryostat is housed within a tritium glovebox that contains manifolds for supplying high-pressure DT. The CPL shares some design elements with the cryogenic target handling system at the OMEGA facility to allow testing of tritium issues related to that system. The CPL has the capability to fill plastic targets by permeation to pressures up to 100 MPa and to cool them to 15 K. The CPL will accommodate a range of targets and may be modified for future experiments.« less

Focus on superconducting properties of iron chalcogenides

NASA Astrophysics Data System (ADS)

Takano, Yoshihiko

2012-10-01

Since the discovery of iron-based superconductors, much attention has been given to the exploration of new superconducting compounds. Numerous superconducting iron compounds have been found and categorized into five groups: LnFeAsO (Ln = lanthanide), BaFe2As2, KFeAs, FeSe and FeAs with perovskite blocking layers. Among them, FeSe has the simplest crystal structure. Since the crystal structure is composed of only superconducting Fe layers, the FeSe family must be the best material to investigate the mechanism of iron-based superconductivity. FeSe shows very strong pressure effects. The superconducting transition temperature (Tc) of FeSe is approximately 8 K at ambient pressure. However Tc dramatically increases up to 37 K under applied pressure of 4-6 GPa. This is the third highest Tc value among binary superconductors, surpassed only by CsC60 under pressure (Tc = 38 K) and MgB2 (Tc = 39 K). On the other hand, despite FeTe having a crystal structure analogous to that of FeSe, FeTe shows antiferromagnetic properties without superconductivity. Doping of small ions, either Se or S, however, can induce superconductivity in FeTe1-xSex or FeTe1-xSx . The superconductivity is very weak for small x values, and annealing under certain conditions is required to obtain strong superconductivity, for instance annealing in oxygen or alcoholic beverages such as red wine. The following selection of papers describe many important experimental and theoretical studies on iron chalcogenide superconductors including preparation of single crystals, bulk samples and thin films; NMR measurements; photoemission spectroscopy; high-pressure studies; annealing effects and research on new BiS2-based superconductors. I hope this focus issue will help researchers understand the frontiers of iron chalcogenide superconductors and assist in the discovery of new phenomena related to iron-based superconductivity.

HPC in Basin Modeling: Simulating Mechanical Compaction through Vertical Effective Stress using Level Sets

NASA Astrophysics Data System (ADS)

McGovern, S.; Kollet, S. J.; Buerger, C. M.; Schwede, R. L.; Podlaha, O. G.

2017-12-01

In the context of sedimentary basins, we present a model for the simulation of the movement of ageological formation (layers) during the evolution of the basin through sedimentation and compactionprocesses. Assuming a single phase saturated porous medium for the sedimentary layers, the modelfocuses on the tracking of the layer interfaces, through the use of the level set method, as sedimentationdrives fluid-flow and reduction of pore space by compaction. On the assumption of Terzaghi's effectivestress concept, the coupling of the pore fluid pressure to the motion of interfaces in 1-D is presented inMcGovern, et.al (2017) [1] .The current work extends the spatial domain to 3-D, though we maintain the assumption ofvertical effective stress to drive the compaction. The idealized geological evolution is conceptualized asthe motion of interfaces between rock layers, whose paths are determined by the magnitude of a speedfunction in the direction normal to the evolving layer interface. The speeds normal to the interface aredependent on the change in porosity, determined through an effective stress-based compaction law,such as the exponential Athy's law. Provided with the speeds normal to the interface, the level setmethod uses an advection equation to evolve a potential function, whose zero level set defines theinterface. Thus, the moving layer geometry influences the pore pressure distribution which couplesback to the interface speeds. The flexible construction of the speed function allows extension, in thefuture, to other terms to represent different physical processes, analogous to how the compaction rulerepresents material deformation.The 3-D model is implemented using the generic finite element method framework Deal II,which provides tools, building on p4est and interfacing to PETSc, for the massively parallel distributedsolution to the model equations [2]. Experiments are being run on the Juelich Supercomputing Center'sJureca cluster. [1] McGovern, et.al. (2017). Novel basin modelling concept for simulating deformation from mechanical compaction using level sets. Computational Geosciences, SI:ECMOR XV, 1-14.[2] Bangerth, et. al. (2011). Algorithms and data structures for massively parallel generic adaptive finite element codes. ACM Transactions on Mathematical Software (TOMS), 38(2):14.

Raman study of supported molybdenum disulfide single layers

NASA Astrophysics Data System (ADS)

Durrer, William; Manciu, Felicia; Afanasiev, Pavel; Berhault, Gilles; Chianelli, Russell

2008-10-01

Owing to the increasing demand for clean transportation fuels, highly dispersed single layer transition metal sulfides such as MoS2-based catalysts play an important role in catalytic processes for upgrading and removing sulfur from heavy petroleum feed. In its crystalline bulk form, MoS2 is chemically rather inactive due to a strong tendency to form highly stacked layers, but, when dispersed as single-layer nanoclusters on a support, the MoS2 becomes catalytically active in the hydrogenolysis of sulphur and nitrogen from organic compounds (hydrotreating catalysis). In the present studies alumina-supported MoS2 samples were analyzed by confocal Raman spectroscopy. Evidence of peaks at 152 cm-1, 234 cm-1, and 336 cm-1, normally not seen in the Raman spectrum of the standard bulk crystal, confirms the formation of single layers of MoS2. Furthermore, the presence of the 383 cm-1 Raman line suggests the trigonal prismatic coordination of the formed MoS2 single layers. Depending on the sample preparation method, a restacking of MoS2 layers is also observed, mainly for ex-thiomolybdate samples sulfided at 550 C.

Numerical simulations of the flow in the HYPULSE expansion tube

NASA Technical Reports Server (NTRS)

Wilson, Gregory J.; Sussman, Myles A.; Bakos, Robert J.

1995-01-01

Axisymmetric numerical simulations with finite-rate chemistry are presented for two operating conditions in the HYPULSE expansion tube. The operating gas for these two cases is nitrogen and the computations are compared to experimental data. One test condition is at a total enthalpy of 15.2 MJ/Kg and a relatively low static pressure of 2 kPa. This case is characterized by a laminar boundary layer and significant chemical nonequilibrium in the acceleration gas. The second test condition is at a total enthalpy of 10.2 MJ/Kg and a static pressure of 38 kPa and is characterized by a turbulent boundary layer. For both cases, the time-varying test gas pressure predicted by the simulations is in good agreement with experimental data. The computations are also found to be in good agreement with Mirels' correlations for shock tube flow. It is shown that the nonuniformity of the test gas observed in the HYPULSE expansion tube is strongly linked to the boundary layer thickness. The turbulent flow investigated has a larger boundary layer and greater test gas nonuniformity. In order to investigate possibilities of improving expansion tube flow quality by reducing the boundary layer thickness, parametric studies showing the effect of density and turbulent transition point on the test conditions are also presented. Although an increase in the expansion tube operating pressure level would reduce the boundary layer thickness, the simulations indicate that the reduction would be less than what is predicted by flat plate boundary layer correlations.

Fuselage boundary-layer refraction of fan tones radiated from an installed turbofan aero-engine.

PubMed

Gaffney, James; McAlpine, Alan; Kingan, Michael J

2017-03-01

A distributed source model to predict fan tone noise levels of an installed turbofan aero-engine is extended to include the refraction effects caused by the fuselage boundary layer. The model is a simple representation of an installed turbofan, where fan tones are represented in terms of spinning modes radiated from a semi-infinite circular duct, and the aircraft's fuselage is represented by an infinitely long, rigid cylinder. The distributed source is a disk, formed by integrating infinitesimal volume sources located on the intake duct termination. The cylinder is located adjacent to the disk. There is uniform axial flow, aligned with the axis of the cylinder, everywhere except close to the cylinder where there is a constant thickness boundary layer. The aim is to predict the near-field acoustic pressure, and in particular, to predict the pressure on the cylindrical fuselage which is relevant to assess cabin noise. Thus no far-field approximations are included in the modelling. The effect of the boundary layer is quantified by calculating the area-averaged mean square pressure over the cylinder's surface with and without the boundary layer included in the prediction model. The sound propagation through the boundary layer is calculated by solving the Pridmore-Brown equation. Results from the theoretical method show that the boundary layer has a significant effect on the predicted sound pressure levels on the cylindrical fuselage, owing to sound radiation of fan tones from an installed turbofan aero-engine.

Turbulent boundary layers subjected to multiple curvatures and pressure gradients

NASA Technical Reports Server (NTRS)

Bandyopadhyay, Promode R.; Ahmed, Anwar

1993-01-01

The effects of abruptly applied cycles of curvatures and pressure gradients on turbulent boundary layers are examined experimentally. Two two-dimensional curved test surfaces are considered: one has a sequence of concave and convex longitudinal surface curvatures and the other has a sequence of convex and concave curvatures. The choice of the curvature sequences were motivated by a desire to study the asymmetric response of turbulent boundary layers to convex and concave curvatures. The relaxation of a boundary layer from the effects of these two opposite sequences has been compared. The effect of the accompaying sequences of pressure gradient has also been examined but the effect of curvature dominates. The growth of internal layers at the curvature junctions have been studied. Measurements of the Gortler and corner vortex systems have been made. The boundary layer recovering from the sequence of concave to convex curvature has a sustained lower skin friction level than in that recovering from the sequence of convex to concave curvature. The amplification and suppression of turbulence due to the curvature sequences have also been studied.

Observation of the effects of stronger magnetic fields on warm, higher energy electrons and ion beams transiting a double layer in a helicon plasma

NASA Astrophysics Data System (ADS)

Scharer, John; Sung, Yung-Ta; Li, Yan

2017-10-01

Fast, two-temperature electrons (>80 eV, Te =13 eV tail, 4 eV bulk) with substantial tail density fractions are created at low (< = 1.7 mtorr) Ar pressure @ 340 G in the antenna region with nozzle mirror ratio of 1.4 on MadHeX @ 900W. These distributions including a fast tail are observed upstream of a double layer. The fast, untrapped tail electrons measured downstream of the double layer have a higher temperature of 13 eV than the trapped, upstream electrons of 4 eV temperature. Upstream plasma potential fluctuations of + - 30 percent are observed. An RF-compensated Langmuir probe is used to measure the electron temperatures and densities and OES, mm wave IF and an RPA for the IEDF are also utilized. As the magnetic field is increased to 1020 G, an increase in the electron temperature and density upstream of the double layer is observed with Te= 15-25 eV with a primarily single temperature mode. Accelerated ion beam energies in the range of 65-120 eV are observed as the magnetic field is increased from 340 to 850 G. The role of the nozzle, plasma double layer and helicon wave coupling on the EEDF and ion acceleration will be discussed. Research supported in part by the University of Wisconsin.

Acoustic Radiation From a Mach 14 Turbulent Boundary Layer

NASA Technical Reports Server (NTRS)

Zhang, Chao; Duan, Lian; Choudhari, Meelan M.

2016-01-01

Direct numerical simulations (DNS) are used to examine the turbulence statistics and the radiation field generated by a high-speed turbulent boundary layer with a nominal freestream Mach number of 14 and wall temperature of 0:18 times the recovery temperature. The flow conditions fall within the range of nozzle exit conditions of the Arnold Engineering Development Center (AEDC) Hypervelocity Tunnel No. 9 facility. The streamwise domain size is approximately 200 times the boundary-layer thickness at the inlet, with a useful range of Reynolds number corresponding to Re 450 ?? 650. Consistent with previous studies of turbulent boundary layer at high Mach numbers, the weak compressibility hypothesis for turbulent boundary layers remains applicable under this flow condition and the computational results confirm the validity of both the van Driest transformation and Morkovin's scaling. The Reynolds analogy is valid at the surface; the RMS of fluctuations in the surface pressure, wall shear stress, and heat flux is 24%, 53%, and 67% of the surface mean, respectively. The magnitude and dominant frequency of pressure fluctuations are found to vary dramatically within the inner layer (z/delta 0.< or approx. 0.08 or z+ < or approx. 50). The peak of the pre-multiplied frequency spectrum of the pressure fluctuation is f(delta)/U(sub infinity) approx. 2.1 at the surface and shifts to a lower frequency of f(delta)/U(sub infinity) approx. 0.7 in the free stream where the pressure signal is predominantly acoustic. The dominant frequency of the pressure spectrum shows a significant dependence on the freestream Mach number both at the wall and in the free stream.

Diverse and tunable electronic structures of single-layer metal phosphorus trichalcogenides for photocatalytic water splitting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Jian; Beijing Computational Science Research Center, Beijing 100084; College of Electrical and Information Engineering, Hunan Institute of Engineering, Xiangtan 411105, Hunan

2014-02-07

The family of bulk metal phosphorus trichalcogenides (APX{sub 3}, A = M{sup II}, M{sub 0.5}{sup I}M{sub 0.5}{sup III}; X = S, Se; M{sup I}, M{sup II}, and M{sup III} represent Group-I, Group-II, and Group-III metals, respectively) has attracted great attentions because such materials not only own magnetic and ferroelectric properties, but also exhibit excellent properties in hydrogen storage and lithium battery because of the layered structures. Many layered materials have been exfoliated into two-dimensional (2D) materials, and they show distinct electronic properties compared with their bulks. Here we present a systematical study of single-layer metal phosphorus trichalcogenides by density functionalmore » theory calculations. The results show that the single layer metal phosphorus trichalcogenides have very low formation energies, which indicates that the exfoliation of single layer APX{sub 3} should not be difficult. The family of single layer metal phosphorus trichalcogenides exhibits a large range of band gaps from 1.77 to 3.94 eV, and the electronic structures are greatly affected by the metal or the chalcogenide atoms. The calculated band edges of metal phosphorus trichalcogenides further reveal that single-layer ZnPSe{sub 3}, CdPSe{sub 3}, Ag{sub 0.5}Sc{sub 0.5}PSe{sub 3}, and Ag{sub 0.5}In{sub 0.5}PX{sub 3} (X = S and Se) have both suitable band gaps for visible-light driving and sufficient over-potentials for water splitting. More fascinatingly, single-layer Ag{sub 0.5}Sc{sub 0.5}PSe{sub 3} is a direct band gap semiconductor, and the calculated optical absorption further convinces that such materials own outstanding properties for light absorption. Such results demonstrate that the single layer metal phosphorus trichalcogenides own high stability, versatile electronic properties, and high optical absorption, thus such materials have great chances to be high efficient photocatalysts for water-splitting.« less

Pressure and Humidity Measurements at the MSL Landing Site Supported by Modeling of the Atmospheric Conditions

NASA Astrophysics Data System (ADS)

Harri, A.; Savijarvi, H. I.; Schmidt, W.; Genzer, M.; Paton, M.; Kauhanen, J.; Atlaskin, E.; Polkko, J.; Kahanpaa, H.; Kemppinen, O.; Haukka, H.

2012-12-01

The Mars Science Laboratory (MSL) called Curiosity Rover landed safely on the Martian surface at the Gale crater on 6th August 2012. Among the MSL scientific objectives are investigations of the Martian environment that will be addressed by the Rover Environmental Monitoring Station (REMS) instrument. It will investigate habitability conditions at the Martian surface by performing a versatile set of environmental measurements including accurate observations of pressure and humidity of the Martian atmosphere. This paper describes the instrumental implementation of the MSL pressure and humidity measurement devices and briefly analyzes the atmospheric conditions at the Gale crater by modeling efforts using an atmospheric modeling tools. MSL humidity and pressure devices are based on proprietary technology of Vaisala, Inc. Humidity observations make use of Vaisala Humicap® relative humidity sensor heads and Vaisala Barocap® sensor heads are used for pressure observations. Vaisala Thermocap® temperature sensors heads are mounted in a close proximity of Humicap® and Barocap® sensor heads to enable accurate temperature measurements needed for interpretation of Humicap® and Barocap® readings. The sensor heads are capacitive. The pressure and humidity devices are lightweight and are based on a low-power transducer controlled by a dedicated ASIC. The transducer is designed to measure small capacitances in order of a few pF with resolution in order of 0.1fF (femtoFarad). The transducer design has a good spaceflight heritage, as it has been used in several previous missions, for example Mars mission Phoenix as well as the Cassini Huygens mission. The humidity device has overall dimensions of 40 x 25 x 55 mm. It weighs18 g, and consumes 15 mW of power. It includes 3 Humicap® sensor heads and 1 Thermocap®. The transducer electronics and the sensor heads are placed on a single multi-layer PCB protected by a metallic Faraday cage. The Humidity device has measurement range of 0 - 100%RH in temperature range of -70°C - +25°C. Its survival temperature is as low as -135°C. The pressure device has overall dimensions of 62 x 55 x 17 mm. It weighs 35 g, and consumes 15 mW of power. The sensor makes use of two transducers placed on a single multi-layer PCB and protected by box-like FR4 Faraday cages. The transducers of the pressure device can be used in turn, thus providing redundancy and improved reliability. The pressure device measurement range is 0 - 1025 hPa in temperature range of -45°C - +55°C, but its calibration is optimized for the Martian pressure range of 4 - 12 hPa. In support of the in situ measurements we have analyzed the atmospheric conditions at the MSL landing site at the Gale crater by utilizing mesoscale and limited area models. The compatibility of the results of these modeling tools with the actual environmental conditions will be discussed.

FOLDER: A numerical tool to simulate the development of structures in layered media

NASA Astrophysics Data System (ADS)

Adamuszek, Marta; Dabrowski, Marcin; Schmid, Daniel W.

2015-04-01

FOLDER is a numerical toolbox for modelling deformation in layered media during layer parallel shortening or extension in two dimensions. FOLDER builds on MILAMIN [1], a finite element method based mechanical solver, with a range of utilities included from the MUTILS package [2]. Numerical mesh is generated using the Triangle software [3]. The toolbox includes features that allow for: 1) designing complex structures such as multi-layer stacks, 2) accurately simulating large-strain deformation of linear and non-linear viscous materials, 3) post-processing of various physical fields such as velocity (total and perturbing), rate of deformation, finite strain, stress, deviatoric stress, pressure, apparent viscosity. FOLDER is designed to ensure maximum flexibility to configure model geometry, define material parameters, specify range of numerical parameters in simulations and choose the plotting options. FOLDER is an open source MATLAB application and comes with a user friendly graphical interface. The toolbox additionally comprises an educational application that illustrates various analytical solutions of growth rates calculated for the cases of folding and necking of a single layer with interfaces perturbed with a single sinusoidal waveform. We further derive two novel analytical expressions for the growth rate in the cases of folding and necking of a linear viscous layer embedded in a linear viscous medium of a finite thickness. We use FOLDER to test the accuracy of single-layer folding simulations using various 1) spatial and temporal resolutions, 2) time integration schemes, and 3) iterative algorithms for non-linear materials. The accuracy of the numerical results is quantified by: 1) comparing them to analytical solution, if available, or 2) running convergence tests. As a result, we provide a map of the most optimal choice of grid size, time step, and number of iterations to keep the results of the numerical simulations below a given error for a given time integration scheme. We also demonstrate that Euler and Leapfrog time integration schemes are not recommended for any practical use. Finally, the capabilities of the toolbox are illustrated based on two examples: 1) shortening of a synthetic multi-layer sequence and 2) extension of a folded quartz vein embedded in phyllite from Sprague Upper Reservoir (example discussed by Sherwin and Chapple [4]). The latter example demonstrates that FOLDER can be successfully used for reverse modelling and mechanical restoration. [1] Dabrowski, M., Krotkiewski, M., and Schmid, D. W., 2008, MILAMIN: MATLAB-based finite element method solver for large problems. Geochemistry Geophysics Geosystems, vol. 9. [2] Krotkiewski, M. and Dabrowski M., 2010 Parallel symmetric sparse matrix-vector product on scalar multi-core cpus. Parallel Computing, 36(4):181-198 [3] Shewchuk, J. R., 1996, Triangle: Engineering a 2D Quality Mesh Generator and Delaunay Triangulator, In: Applied Computational Geometry: Towards Geometric Engineering'' (Ming C. Lin and Dinesh Manocha, editors), Vol. 1148 of Lecture Notes in Computer Science, pp. 203-222, Springer-Verlag, Berlin [4] Sherwin, J.A., Chapple, W.M., 1968. Wavelengths of single layer folds - a Comparison between theory and Observation. American Journal of Science 266 (3), p. 167-179

Detection of boundary-layer transitions in wind tunnels

NASA Technical Reports Server (NTRS)

Wood, W. R.; Somers, D. M.

1978-01-01

Accelerometer replaces stethoscope in technique for detection of laminar-to-turbulent boundary-layer transitions on wind-tunnel models. Technique allows measurements above or below atmospheric pressure because human operator is not required within tunnel. Data may be taken from accelerometer, and pressure transducer simultaneously, and delivered to systems for analysis.

Characteristic of the carbon-tungsten co-deposition layers prepared by RF magnetron sputtering in a D2/Ar plasma

NASA Astrophysics Data System (ADS)

Tang, X. H.; Zhang, W. Z.; Shi, L. Q.; Qi, Q.; Zhang, B.; Zhang, W. Y.; Wang, K.; Hu, J. S.

2013-06-01

A C-W co-deposition layer, formed by radio frequency magnetron sputtering, was investigated to identify the characteristics of C-W mixed layers in fusion experimental reactors. The layers were characterized by ion beam analysis, Raman spectroscopy, X-ray diffraction and scanning electron microscopy. It was found that D atoms in C-W layers were mainly trapped by the C atoms. The ratio of C/W and D concentrations in the C-W layers deposited at a pressure of 5.0 Pa and a fixed flow rate ratio were 54/31 and 5%, respectively. They all increased significantly with increased flow rate of D2 but decreased with temperature at a relatively low level. The pressure dependence of the D concentration showed a maximum value around 5 Pa and it decreased with rising or decreasing pressure. Both Raman and X-ray analysis revealed that the structure of the C-W layers became more graphite-like with increasing temperature. Moreover, deuterium introduction made the tungsten carbide phase disappear in the deuterated C-W layers. Only erosion caves on the surface of the sample prepared at 300 K were observed by SEM. When the temperature increased, they disappeared, and convex bodies appeared.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kalantari, Alireza; Sullivan-Lewis, Elliot; McDonell, Vincent

Due to increasingly stringent air quality requirements stationary power gas turbines have moved to lean-premixed operation, which reduces pollutant emissions but can result in flashback. Curtailing flashback can be difficult with hydrocarbon fuels and becomes even more challenging when hydrogen is used as the fuel. In fact, flashback is a key operability issue associated with low emission combustion of high hydrogen content fuels. Flashback can cause serious damage to the premixer hardware. Hence, design tools to predict flashback propensity are of interest. Such a design tool has been developed based on the data gathered by experimental study to predict boundarymore » layer flashback using non-dimensional parameters. The flashback propensity of a premixed jet flame has been studied experimentally. Boundary layer flashback has been investigated under turbulent flow conditions at elevated pressures and temperatures (i.e. 3 atm to 8 atm and 300 K to 500 K). The data presented in this study are for hydrogen fuel at various Reynolds numbers, which are representative of practical gas turbine premixer conditions and are significantly higher than results currently available in the literature. Three burner heads constructed of different materials (stainless steel, copper, and zirconia ceramic) were used to evaluate the effect of tip temperature, a parameter found previously to be an important factor in triggering flashback. This study characterizes flashback systematically by developing a comprehensive non-dimensional model which takes into account all effective parameters in boundary layer flashback propensity. The model was optimized for new data and captures the behavior of the new results well. Further, comparison of the model with the single existing study of high pressure jet flame flashback also indicates good agreement. The model developed using the high pressure test rig is able to predict flashback tendencies for a commercial gas turbine engine and can thus serve as a design tool for identifying when flashback is likely to occur for a given geometry and condition.« less

Triple-layer configuration for stable high-speed lubricated pipeline transport

NASA Astrophysics Data System (ADS)

Sarmadi, Parisa; Hormozi, Sarah; Frigaard, Ian A.

2017-04-01

Lubricated transport of heavy viscous oils is a popular technology in the pipelining industry, where pumping pressures can be reduced significantly by concentrating the strain rate in a lubricating layer. However, the interface between the lubricating layer and heavy oil is vulnerable to any perturbations in the system as well as transients due to start up, shut down, temperature change, etc. We present a method in which we purposefully position an unyielded skin of a viscoplastic fluid between the oil and the lubricating fluid. The objective is to reduce the frictional pressure gradient while avoiding interfacial instability. We study this methodology in both concentric and eccentric configurations and show its feasibility for a wide range of geometric and flow parameters found in oil pipelining. The eccentric configuration benefits the transport process via generating lift forces to balance the density differences among the layers. We use classical lubrication theory to estimate the leading order pressure distribution in the lubricating layer and calculate the net force on the skin. We explore the effects of skin shape, viscosity ratio, and geometry on the pressure drop, the flow rates of skin and lubricant fluids, and the net force on the skin. We show that the viscosity ratio and the radius of the core fluid are the main parameters that control the pressure drop and consumptions of outer fluids, respectively. The shape of the skin and the eccentricity mainly affect the lubrication pressure. These predictions are essential in designing a stable transport process. Finally, we estimate the yield stress required in order that the skin remain unyielded and ensure interfacial stability.

In-flight boundary-layer measurements on a hollow cylinder at a Mach number of 3.0

NASA Technical Reports Server (NTRS)

Quinn, R. D.; Gong, L.

1980-01-01

Skin temperatures, shear forces, surface static pressures, boundary layer pitot pressures, and boundary layer total temperatures were measured on the external surface of a hollow cylinder that was 3.04 meters long and 0.437 meter in diameter and was mounted beneath the fuselage of the YF-12A airplane. The data were obtained at a nominal free stream Mach number of 3.0 (a local Mach number of 2.9) and at wall to recovery temperature ratios of 0.66 to 0.91. The local Reynolds number had a nominal value of 4,300,000 per meter. Heat transfer coefficients and skin friction coefficients were derived from skin temperature time histories and shear force measurements, respectively. In addition, boundary layer velocity profiles were derived from pitot pressure measurements, and a Reynolds analogy factor was obtained from the heat transfer and skin friction measurements. The measured data are compared with several boundary layer prediction methods.

Lidar observation of transition of cirrus clouds over a tropical station Gadanki (13.45° N, 79.18° E): case studies

NASA Astrophysics Data System (ADS)

Srinivasan, M. A.; Rao, C. Dhananjaya; Krishnaiah, M.

2016-05-01

The present study describes Mie lidar observations of the cirrus cloud passage showing transition between double thin layers into single thick and single thick layer into double thin layers of cirrus over Gadanki region. During Case1: 17 January 2007, Case4: 12 June 2007, Case5: 14 July 2007 and Case6: 24 July 2007 the transition is found to from two thin cirrus layers into single geometrically thick layer. Case2: 14 May 2007 and Case3: 15 May 2007, the transition is found to from single geometrically thick layer into two thin cirrus layers. Linear Depolarization Ratio (LDR) and Back Scatter Ration (BSR) are found to show similar variation with strong peaks during transition; both LDR and Cloud Optical Depth (COD) is found to show similar variation except during transition with strong peaks in COD which is not clearly found from LDR for the all cases. There is a significant weakening of zonal and meridional winds during Case1 which might be due to the transition from multiple to single thick cirrus indicating potential capability of thick cirrus in modulating the wind fields. There exists strong upward wind dominance contributed to significant ascent in cloud-base altitude thereby causing transition of multiple thin layers into single thick cirrus.

Thermal stability of epitaxial SrRuO3 films as a function of oxygen pressure

NASA Astrophysics Data System (ADS)

Lee, Ho Nyung; Christen, Hans M.; Chisholm, Matthew F.; Rouleau, Christopher M.; Lowndes, Douglas H.

2004-05-01

The thermal stability of electrically conducting SrRuO3 thin films grown by pulsed-laser deposition on (001) SrTiO3 substrates has been investigated by atomic force microscopy and reflection high-energy electron diffraction (RHEED) under reducing conditions (25-800 °C in 10-7-10-2 Torr O2). The as-grown SrRuO3 epitaxial films exhibit atomically flat surfaces with single unit-cell steps, even after exposure to air at room temperature. The films remain stable at temperatures as high as 720 °C in moderate oxygen ambients (>1 mTorr), but higher temperature anneals at lower pressures result in the formation of islands and pits due to the decomposition of SrRuO3. Using in situ RHEED, a temperature and oxygen pressure stability map was determined, consistent with a thermally activated decomposition process having an activation energy of 88 kJ/mol. The results can be used to determine the proper conditions for growth of additional epitaxial oxide layers on high quality electrically conducting SrRuO3.

Effect of thin oxide layers incorporated in spin valve structures

NASA Astrophysics Data System (ADS)

Gillies, M. F.; Kuiper, A. E. T.; Leibbrandt, G. W. R.

2001-06-01

The enhancement of the magnetoresistance effect, induced by incorporating nano-oxide layers (NOLs) in a bottom-type spin valve, was studied for various preparation conditions. The effect of a NOL in the Co90Fe10 pinned layer was found to depend critically on the oxygen pressure applied to form the thin oxide film. Pressures over 10-3 Torr O2 yield oxides thicker than about 0.7 nm, which apparently deteriorate the biasing field which exists over the oxide. The magnetoresistance values can further be raised by forming a specular reflecting oxide on top of the sense layer. Promising results were obtained with an Al2O3 capping layer formed in a solid-state oxidation reaction that occurs spontaneously when a thin Al layer is deposited on the oxidized surface of the Co90Fe10 sense layer.

Interaction between a normal shock wave and a turbulent boundary layer at high transonic speeds. I - Pressure distribution

NASA Technical Reports Server (NTRS)

Messiter, A. F.

1980-01-01

Asymptotic solutions are derived for the pressure distribution in the interaction of a weak normal shock wave with a turbulent boundary layer. The undisturbed boundary layer is characterized by the law of the wall and the law of the wake for compressible flow. In the limiting case considered, for 'high' transonic speeds, the sonic line is very close to the wall. Comparisons with experiment are shown, with corrections included for the effect of longitudinal wall curvature and for the boundary-layer displacement effect in a circular pipe.

Computation of the shock-wave boundary layer interaction with flow separation

NASA Technical Reports Server (NTRS)

Ardonceau, P.; Alziary, T.; Aymer, D.

1980-01-01

The boundary layer concept is used to describe the flow near the wall. The external flow is approximated by a pressure displacement relationship (tangent wedge in linearized supersonic flow). The boundary layer equations are solved in finite difference form and the question of the presence and unicity of the solution is considered for the direct problem (assumed pressure) or converse problem (assumed displacement thickness, friction ratio). The coupling algorithm presented implicitly processes the downstream boundary condition necessary to correctly define the interacting boundary layer problem. The algorithm uses a Newton linearization technique to provide a fast convergence.

A study of vapor-phase deposition of silicon nitride layers by ammonolysis of dichlorosilane at lowered pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manzha, N. M., E-mail: magazine@miee.ru

2010-12-15

Deposition kinetics of silicon nitride layers at lowered reactor pressures of 10-130 Pa and temperatures in the range 973-1073 K has been studied. The equilibrium constant of the bimolecular reaction of dichlorosilane with ammonia has been calculated. The apparent activation energies calculated taking into account the experimental growth rate nearly coincide with the experimental data. Recommendations for improving the quality of silicon nitride layers are made.

Characteristics of Boundary Layer Transition in a Multi-Stage Low-Pressure Turbine

NASA Technical Reports Server (NTRS)

Wisler, Dave; Halstead, David E.; Okiishi, Ted

2007-01-01

An experimental investigation of boundary layer transition in a multi-stage turbine has been completed using surface-mounted hot-film sensors. Tests were carried out using the two-stage Low Speed Research Turbine of the Aerodynamics Research Laboratory of GE Aircraft Engines. Blading in this facility models current, state-of-the-art low pressure turbine configurations. The instrumentation technique involved arrays of densely-packed hot-film sensors on the surfaces of second stage rotor and nozzle blades. The arrays were located at mid-span on both the suction and pressure surfaces. Boundary layer measurements were acquired over a complete range of relevant Reynolds numbers. Data acquisition capabilities provided means for detailed data interrogation in both time and frequency domains. Data indicate that significant regions of laminar and transitional boundary layer flow exist on the rotor and nozzle suction surfaces. Evidence of relaminarization both near the leading edge of the suction surface and along much of the pressure surface was observed. Measurements also reveal the nature of the turbulent bursts occuring within and between the wake segments convecting through the blade row. The complex character of boundary layer transition resulting from flow unsteadiness due to nozzle/nozzle, rotor/nozzle, and nozzle/rotor wake interactions are elucidated using these data. These measurements underscore the need to provide turbomachinery designers with models of boundary layer transition to facilitate accurate prediction of aerodynamic loss and heat transfer.

Interaction of viscous and inviscid instability modes in separation-bubble transition

NASA Astrophysics Data System (ADS)

Brinkerhoff, Joshua R.; Yaras, Metin I.

2011-12-01

This paper describes numerical simulations that are used to examine the interaction of viscous and inviscid instability modes in laminar-to-turbulent transition in a separation bubble. The results of a direct numerical simulation are presented in which separation of a laminar boundary-layer occurs in the presence of an adverse streamwise pressure gradient. The simulation is performed at low freestream-turbulence levels and at a flow Reynolds number and pressure distribution approximating those typically encountered on the suction side of low-pressure turbine blades in a gas-turbine engine. The simulation results reveal the development of a viscous instability upstream of the point of separation which produces streamwise-oriented vortices in the attached laminar boundary layer. These vortices remain embedded in the flow downstream of separation and are carried into the separated shear layer, where they are amplified by the local adverse pressure-gradient and contribute to the formation of coherent hairpin-like vortices. A strong interaction is observed between these vortices and the inviscid instability that typically dominates the shear layer in the separated zone. The interaction is noted to determine the spanwise extent of the vortical flow structures that periodically shed from the downstream end of the separated shear layer. The structure of the shed vortical flow structures is examined and compared with the coherent structures typically observed within turbulent boundary layers.

A dilute Cu(Ni) alloy for synthesis of large-area Bernal stacked bilayer graphene using atmospheric pressure chemical vapour deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Madito, M. J.; Bello, A.; Dangbegnon, J. K.

2016-01-07

A bilayer graphene film obtained on copper (Cu) foil is known to have a significant fraction of non-Bernal (AB) stacking and on copper/nickel (Cu/Ni) thin films is known to grow over a large-area with AB stacking. In this study, annealed Cu foils for graphene growth were doped with small concentrations of Ni to obtain dilute Cu(Ni) alloys in which the hydrocarbon decomposition rate of Cu will be enhanced by Ni during synthesis of large-area AB-stacked bilayer graphene using atmospheric pressure chemical vapour deposition. The Ni doped concentration and the Ni homogeneous distribution in Cu foil were confirmed with inductively coupledmore » plasma optical emission spectrometry and proton-induced X-ray emission. An electron backscatter diffraction map showed that Cu foils have a single (001) surface orientation which leads to a uniform growth rate on Cu surface in early stages of graphene growth and also leads to a uniform Ni surface concentration distribution through segregation kinetics. The increase in Ni surface concentration in foils was investigated with time-of-flight secondary ion mass spectrometry. The quality of graphene, the number of graphene layers, and the layers stacking order in synthesized bilayer graphene films were confirmed by Raman and electron diffraction measurements. A four point probe station was used to measure the sheet resistance of graphene films. As compared to Cu foil, the prepared dilute Cu(Ni) alloy demonstrated the good capability of growing large-area AB-stacked bilayer graphene film by increasing Ni content in Cu surface layer.« less

A dilute Cu(Ni) alloy for synthesis of large-area Bernal stacked bilayer graphene using atmospheric pressure chemical vapour deposition

NASA Astrophysics Data System (ADS)

Madito, M. J.; Bello, A.; Dangbegnon, J. K.; Oliphant, C. J.; Jordaan, W. A.; Momodu, D. Y.; Masikhwa, T. M.; Barzegar, F.; Fabiane, M.; Manyala, N.

2016-01-01

A bilayer graphene film obtained on copper (Cu) foil is known to have a significant fraction of non-Bernal (AB) stacking and on copper/nickel (Cu/Ni) thin films is known to grow over a large-area with AB stacking. In this study, annealed Cu foils for graphene growth were doped with small concentrations of Ni to obtain dilute Cu(Ni) alloys in which the hydrocarbon decomposition rate of Cu will be enhanced by Ni during synthesis of large-area AB-stacked bilayer graphene using atmospheric pressure chemical vapour deposition. The Ni doped concentration and the Ni homogeneous distribution in Cu foil were confirmed with inductively coupled plasma optical emission spectrometry and proton-induced X-ray emission. An electron backscatter diffraction map showed that Cu foils have a single (001) surface orientation which leads to a uniform growth rate on Cu surface in early stages of graphene growth and also leads to a uniform Ni surface concentration distribution through segregation kinetics. The increase in Ni surface concentration in foils was investigated with time-of-flight secondary ion mass spectrometry. The quality of graphene, the number of graphene layers, and the layers stacking order in synthesized bilayer graphene films were confirmed by Raman and electron diffraction measurements. A four point probe station was used to measure the sheet resistance of graphene films. As compared to Cu foil, the prepared dilute Cu(Ni) alloy demonstrated the good capability of growing large-area AB-stacked bilayer graphene film by increasing Ni content in Cu surface layer.

The Turbulent Flow in Diffusers of Small Divergence Angle

NASA Technical Reports Server (NTRS)

Gourzhienko, G. A.

1947-01-01

The turbulent flow in a conical diffuser represents the type of turbulent boundary layer with positive longitudinal pressure gradient. In contrast to the boundary layer problem, however, it is not necessary that the pressure distribution along the limits of the boundary layer(along the axis of the diffuser) be given, since this distribution can be obtained from the computation. This circumstance, together with the greater simplicity of the problem as a whole, provides a useful basis for the study of the extension of the results of semiempirical theories to the case of motion with a positive pressure gradient. In the first part of the paper,formulas are derived for the computation of the velocity and.pressure distributions in the turbulent flow along, and at right angles to, the axis of a diffuser of small cone angle. The problem is solved.

An experimental study of fluctuating pressure loads beneath swept shock/boundary-layer interactions

NASA Technical Reports Server (NTRS)

Settles, Gary S.

1991-01-01

A database is established on the fluctuating pressure loads produced on aerodynamic surfaces beneath 3-D shock wave/boundary layer interactions. Such loads constitute a fundamental problem of critical concern to future supersonic and hypersonic flight vehicles. A turbulent boundary layer on a flat plate is subjected to interactions with swept planar shock waves generated by sharp fins. Fin angles from 5 to 25 deg at freestream Mach numbers between 2.5 and 4 produce a variety of interaction strengths from weak to very strong. Miniature Kulite pressure transducers mounted in the flat plate were used to measure interaction-induced wall pressure fluctuations. These data will be correlated with proposed new optical data on the fluctuations of the interaction structure, especially that of the lambda-shock system and its associated high-speed jet impingement.

A prospective study of two methods of closing surgical scalp wounds.

PubMed

Adeolu, A A; Olabanji, J K; Komolafe, E O; Ademuyiwa, A O; Awe, A O; Oladele, A O

2012-02-01

Scalp wounds are commonly closed in two layers, although single layer closure is feasible. This study prospectively compared the two methods of closing scalp wounds. Patients with non-traumatic scalp wounds were allocated to either the single layer closure group or the multilayer closure group. We obtained relevant data from the patients. The primary outcome measures were wound edge related complications, rate of suturing and cost of sutures used for suturing. Thirty-one wounds were in the single layer closure group and 30 were in the multilayer closure group. Age range was 1-80 years. The most common indication for making a scalp incision was subdural hematoma, representing 27.8% of all the indications. The most common surgery was burr hole drainage of subdural hematoma. Polyglactin acid suture was used for the inner layer and polyamide -00- for the final layer in the multilayer closure group. Only the latter suture was used for the single layer closure method. Total cost of suturing per wound in the single layer closure group was N= 100 (0.70USD) and N= 800 (5.30USD) in the multilayer group. The mean rate of closure was 0.39 ± 1.89 mm/sec for single layer closure and 0.23 ± 0.89 mm/sec in multilayer closure. The difference was statistically significant. Wound edge related complication rate was 19.35% in the single layer closure group and 16.67% in the multilayer closure method group. The difference was not statistically significant (z: 0.00, p value: 1.000; Pearson chi-squared (DF = 1)= 0.0075, p = 0.0785). The study shows that closing the scalp in one layer is much faster and more cost effective compared to the multilayer closure method. We did not observe significant difference in the complication rates in the two methods of closure. Long-term outcome, especially cosmetic outcome, remains to be determined in this preliminary study.

Local Sensitivity of Predicted CO 2 Injectivity and Plume Extent to Model Inputs for the FutureGen 2.0 site

DOE PAGES

Zhang, Z. Fred; White, Signe K.; Bonneville, Alain; ...

2014-12-31

Numerical simulations have been used for estimating CO2 injectivity, CO2 plume extent, pressure distribution, and Area of Review (AoR), and for the design of CO2 injection operations and monitoring network for the FutureGen project. The simulation results are affected by uncertainties associated with numerous input parameters, the conceptual model, initial and boundary conditions, and factors related to injection operations. Furthermore, the uncertainties in the simulation results also vary in space and time. The key need is to identify those uncertainties that critically impact the simulation results and quantify their impacts. We introduce an approach to determine the local sensitivity coefficientmore » (LSC), defined as the response of the output in percent, to rank the importance of model inputs on outputs. The uncertainty of an input with higher sensitivity has larger impacts on the output. The LSC is scalable by the error of an input parameter. The composite sensitivity of an output to a subset of inputs can be calculated by summing the individual LSC values. We propose a local sensitivity coefficient method and applied it to the FutureGen 2.0 Site in Morgan County, Illinois, USA, to investigate the sensitivity of input parameters and initial conditions. The conceptual model for the site consists of 31 layers, each of which has a unique set of input parameters. The sensitivity of 11 parameters for each layer and 7 inputs as initial conditions is then investigated. For CO2 injectivity and plume size, about half of the uncertainty is due to only 4 or 5 of the 348 inputs and 3/4 of the uncertainty is due to about 15 of the inputs. The initial conditions and the properties of the injection layer and its neighbour layers contribute to most of the sensitivity. Overall, the simulation outputs are very sensitive to only a small fraction of the inputs. However, the parameters that are important for controlling CO2 injectivity are not the same as those controlling the plume size. The three most sensitive inputs for injectivity were the horizontal permeability of Mt Simon 11 (the injection layer), the initial fracture-pressure gradient, and the residual aqueous saturation of Mt Simon 11, while those for the plume area were the initial salt concentration, the initial pressure, and the initial fracture-pressure gradient. The advantages of requiring only a single set of simulation results, scalability to the proper parameter errors, and easy calculation of the composite sensitivities make this approach very cost-effective for estimating AoR uncertainty and guiding cost-effective site characterization, injection well design, and monitoring network design for CO2 storage projects.« less

Bottom boundary layer forced by finite amplitude long and short surface waves motions

NASA Astrophysics Data System (ADS)

Elsafty, H.; Lynett, P.

2018-04-01

A multiple-scale perturbation approach is implemented to solve the Navier-Stokes equations while including bottom boundary layer effects under a single wave and under two interacting waves. In this approach, fluid velocities and the pressure field are decomposed into two components: a potential component and a rotational component. In this study, the two components are exist throughout the entire water column and each is scaled with appropriate length and time scales. A one-way coupling between the two components is implemented. The potential component is assumed to be known analytically or numerically a prior, and the rotational component is forced by the potential component. Through order of magnitude analysis, it is found that the leading-order coupling between the two components occurs through the vertical convective acceleration. It is shown that this coupling plays an important role in the bottom boundary layer behavior. Its effect on the results is discussed for different wave-forcing conditions: purely harmonic forcing and impurely harmonic forcing. The approach is then applied to derive the governing equations for the bottom boundary layer developed under two interacting wave motions. Both motions-the shorter and the longer wave-are decomposed into two components, potential and rotational, as it is done in the single wave. Test cases are presented wherein two different wave forcings are simulated: (1) two periodic oscillatory motions and (2) short waves interacting with a solitary wave. The analysis of the two periodic motions indicates that nonlinear effects in the rotational solution may be significant even though nonlinear effects are negligible in the potential forcing. The local differences in the rotational velocity due to the nonlinear vertical convection coupling term are found to be on the order of 30% of the maximum boundary layer velocity for the cases simulated in this paper. This difference is expected to increase with the increase in wave nonlinearity.

Manufacturing of three-dimensionally microstructured nanocomposites through microfluidic infiltration.

PubMed

Dermanaki-Farahani, Rouhollah; Lebel, Louis Laberge; Therriault, Daniel

2014-03-12

Microstructured composite beams reinforced with complex three-dimensionally (3D) patterned nanocomposite microfilaments are fabricated via nanocomposite infiltration of 3D interconnected microfluidic networks. The manufacturing of the reinforced beams begins with the fabrication of microfluidic networks, which involves layer-by-layer deposition of fugitive ink filaments using a dispensing robot, filling the empty space between filaments using a low viscosity resin, curing the resin and finally removing the ink. Self-supported 3D structures with other geometries and many layers (e.g. a few hundreds layers) could be built using this method. The resulting tubular microfluidic networks are then infiltrated with thermosetting nanocomposite suspensions containing nanofillers (e.g. single-walled carbon nanotubes), and subsequently cured. The infiltration is done by applying a pressure gradient between two ends of the empty network (either by applying a vacuum or vacuum-assisted microinjection). Prior to the infiltration, the nanocomposite suspensions are prepared by dispersing nanofillers into polymer matrices using ultrasonication and three-roll mixing methods. The nanocomposites (i.e. materials infiltrated) are then solidified under UV exposure/heat cure, resulting in a 3D-reinforced composite structure. The technique presented here enables the design of functional nanocomposite macroscopic products for microengineering applications such as actuators and sensors.

Manufacturing of Three-dimensionally Microstructured Nanocomposites through Microfluidic Infiltration

PubMed Central

Dermanaki-Farahani, Rouhollah; Lebel, Louis Laberge; Therriault, Daniel

2014-01-01

Microstructured composite beams reinforced with complex three-dimensionally (3D) patterned nanocomposite microfilaments are fabricated via nanocomposite infiltration of 3D interconnected microfluidic networks. The manufacturing of the reinforced beams begins with the fabrication of microfluidic networks, which involves layer-by-layer deposition of fugitive ink filaments using a dispensing robot, filling the empty space between filaments using a low viscosity resin, curing the resin and finally removing the ink. Self-supported 3D structures with other geometries and many layers (e.g. a few hundreds layers) could be built using this method. The resulting tubular microfluidic networks are then infiltrated with thermosetting nanocomposite suspensions containing nanofillers (e.g. single-walled carbon nanotubes), and subsequently cured. The infiltration is done by applying a pressure gradient between two ends of the empty network (either by applying a vacuum or vacuum-assisted microinjection). Prior to the infiltration, the nanocomposite suspensions are prepared by dispersing nanofillers into polymer matrices using ultrasonication and three-roll mixing methods. The nanocomposites (i.e. materials infiltrated) are then solidified under UV exposure/heat cure, resulting in a 3D-reinforced composite structure. The technique presented here enables the design of functional nanocomposite macroscopic products for microengineering applications such as actuators and sensors. PMID:24686754

Vertical heterostructures of MoS2 and graphene nanoribbons grown by two-step chemical vapor deposition for high-gain photodetectors.

PubMed

Yunus, Rozan Mohamad; Endo, Hiroko; Tsuji, Masaharu; Ago, Hiroki

2015-10-14

Heterostructures of two-dimensional (2D) layered materials have attracted growing interest due to their unique properties and possible applications in electronics, photonics, and energy. Reduction of the dimensionality from 2D to one-dimensional (1D), such as graphene nanoribbons (GNRs), is also interesting due to the electron confinement effect and unique edge effects. Here, we demonstrate a bottom-up approach to grow vertical heterostructures of MoS2 and GNRs by a two-step chemical vapor deposition (CVD) method. Single-layer GNRs were first grown by ambient pressure CVD on an epitaxial Cu(100) film, followed by the second CVD process to grow MoS2 over the GNRs. The MoS2 layer was found to grow preferentially on the GNR surface, while the coverage could be further tuned by adjusting the growth conditions. The MoS2/GNR nanostructures show clear photosensitivity to visible light with an optical response much higher than that of a 2D MoS2/graphene heterostructure. The ability to grow a novel 1D heterostructure of layered materials by a bottom-up CVD approach will open up a new avenue to expand the dimensionality of the material synthesis and applications.

In vitro corrosion resistance of plasma source ion nitrided austenitic stainless steels.

PubMed

Le, M K; Zhu, X M

2001-04-01

Plasma source ion nitriding has emerged as a low-temperature, low-pressure nitriding approach for low-energy implanting nitrogen ions and then diffusing them into steel and alloy. In this work, a single high nitrogen face-centered-cubic (f.c.c.) phase (gammaN) formed on the 1Cr18Ni9Ti and AISI 316L austenitic stainless steels with a high nitrogen concentration of about 32 at % was characterized using Auger electron spectroscopy, electron probe microanalysis, glancing angle X-ray diffraction, and transmission electron microscopy. The corrosion resistance of the gammaN-phase layer was studied by the electrochemical cyclic polarization measurement in Ringer's solutions buffered to pH from 3.5 to 7.2 at a temperature of 37 degrees C. No pitting corrosion in the Ringer's solutions with pH = 7.2 and 5.5 was detected for the gammaN-phase layers on the two stainless steels. The high pitting potential for the gammaN-phase layers is higher, about 500 and 600 mV, above that of the two original stainless steels, respectively, in the Ringer's solution with pH = 3.5. The corroded surface morphologies of the gammaN-phase layers observed by scanning electron microscopy are consistent with the results of the electrochemical polarization measurement.

Anatomy of the python heart.

PubMed

Jensen, Bjarke; Nyengaard, Jens R; Pedersen, Michael; Wang, Tobias

2010-12-01

The hearts of all snakes and lizards consist of two atria and a single incompletely divided ventricle. In general, the squamate ventricle is subdivided into three chambers: cavum arteriosum (left), cavum venosum (medial) and cavum pulmonale (right). Although a similar division also applies to the heart of pythons, this family of snakes is unique amongst snakes in having intracardiac pressure separation. Here we provide a detailed anatomical description of the cardiac structures that confer this functional division. We measured the masses and volumes of the ventricular chambers, and we describe the gross morphology based on dissections of the heart from 13 ball pythons (Python regius) and one Burmese python (P. molurus). The cavum venosum is much reduced in pythons and constitutes approximately 10% of the cavum arteriosum. We suggest that shunts will always be less than 20%, while other studies conclude up to 50%. The high-pressure cavum arteriosum accounted for approximately 75% of the total ventricular mass, and was twice as dense as the low-pressure cavum pulmonale. The reptile ventricle has a core of spongious myocardium, but the three ventricular septa that separate the pulmonary and systemic chambers--the muscular ridge, the bulbuslamelle and the vertical septum--all had layers of compact myocardium. Pythons, however, have unique pads of connective tissue on the site of pressure separation. Because the hearts of varanid lizards, which also are endowed with pressure separation, share many of these morphological specializations, we propose that intraventricular compact myocardium is an indicator of high-pressure systems and possibly pressure separation.

Free-stream static pressure measurements in the Longshot hypersonic wind tunnel and sensitivity analysis

NASA Astrophysics Data System (ADS)

Grossir, Guillaume; Van Hove, Bart; Paris, Sébastien; Rambaud, Patrick; Chazot, Olivier

2016-05-01

The performance of fast-response slender static pressure probes is evaluated in the short-duration, cold-gas, VKI Longshot hypersonic wind tunnel. Free-stream Mach numbers range between 9.5 and 12, and unit Reynolds numbers are within 3-10 × 106/m. Absolute pressure sensors are fitted within the probes, and an inexpensive calibration method, suited to low static pressure environments (200-1000 Pa), is described. Transfer functions relating the probe measurements p w to the free-stream static pressure p ∞ are established for the Longshot flow conditions based on numerical simulations. The pressure ratios p w / p ∞ are found to be close to unity for both laminar and turbulent boundary layers. Weak viscous effects characterized by small viscous interaction parameters {bar{χ }}<1.5 are confirmed experimentally for probe aspect ratios of L/ D > 16.5 by installing multiple pressure sensors in a single probe. The effect of pressure orifice geometry is also evaluated experimentally and found to be negligible for either straight or chamfered holes, 0.6-1 mm in diameter. No sensitivity to probe angle of attack could be evidenced for α < 0.33°. Pressure measurements are compared to theoretical predictions assuming an isentropic nozzle flow expansion. Significant deviations from this ideal case and the Mach 14 contoured nozzle design are uncovered. Validation of the static pressure measurements is obtained by comparing shock wave locations on Schlieren photographs to numerical predictions using free-stream properties derived from the static pressure probes. While these results apply to the Longshot wind tunnel, the present methodology and sensitivity analysis can guide similar investigations for other hypersonic test facilities.

An optimized microstructure to minimizing in-plane and through-plane pressure drops of fibrous materials: Counter-intuitive reduction of gas diffusion layer permeability with porosity

NASA Astrophysics Data System (ADS)

Sadeghifar, Hamidreza

2018-05-01

The present study experimentally investigates the realistic functionality of in-plane and through-plane pressure drops of layered fibrous media with porosity, fiber diameter, fiber spacing, fiber-fiber angles and fiber-flow angles. The study also reveals that pressure drop may increase with porosity and fiber diameter under specific circumstances. This counter-intuitive point narrows down the validity range of widely-used permeability-porosity-diameter models or correlations. It is found that, for fibrous materials, the most important parameter that impacts the in-plane pressure drop is not their porosities but the number of fibers extended in the flow direction. It is also concluded that in-plane pressure drop is highly dependent upon the flow direction (fiber-flow angles), especially at lower porosities. Contrary to in-plane pressure drop, through-plane pressure drop is a weak function of fiber-fiber angles but is strongly impacted by fiber spacing, especially at lower porosities. At a given porosity, low through-plane pressure drops occur if fiber spacing does not change practically from one layer to another. Through-plane pressure drop also, insignificantly, increases with the intersecting angles between fibers. An optimized microstructure of fibrous media resulting in minimal in-plane and through-plane pressure drops is also offered for the first time in this work.

An experimental study of near wall flow parameters in the blade end-wall corner region

NASA Technical Reports Server (NTRS)

Bhargava, Rakesh K.; Raj, Rishi S.

1989-01-01

The near wall flow parameters in the blade end-wall corner region is investigated. The blade end-wall corner region was simulated by mounting an airfoil section (NACA 65-015 base profile) symmetric blades on both sides of the flat plate with semi-circular leading edge. The initial 7 cm from the leading edge of the flat plate was roughened by gluing No. 4 floor sanding paper to artificially increase the boundary layer thickness on the flat plate. The initial flow conditions of the boundary layer upstream of the corner region are expected to dictate the behavior of flow inside the corner region. Therefore, an experimental investigation was extended to study the combined effect of initial roughness and increased level of free stream turbulence on the development of a 2-D turbulent boundary layer in the absence of the blade. The measurement techniques employed in the present investigation included, the conventional pitot and pitot-static probes, wall taps, the Preston tube, piezoresistive transducer and the normal sensor hot-wire probe. The pitot and pitot-static probes were used to obtain mean velocity profile measurements within the boundary layer. The measurements of mean surface static pressure were obtained with the surface static tube and the conventional wall tap method. The wall shear vector measurements were made with a specially constructed Preston tube. The flush mounted piezoresistive type pressure transducer were employed to measure the wall pressure fluctuation field. The velocity fluctuation measurements, used in obtaining the wall pressure-velocity correlation data, were made with normal single sensor hot-wire probe. At different streamwise stations, in the blade end-wall corner region, the mean values of surface static pressure varied more on the end-wall surface in the corner region were mainly caused by the changes in the curvature of the streamlines. The magnitude of the wall shear stress in the blade end-wall corner region increased significantly in the close vicinity of the corner line. The maximum value of the wall shear stress and its location from the corner line, on both the surfaces forming the corner region, were observed to change along the corner. These observed changes in the maximum values of the wall shear stress and its location from the corner line could be associated with the stretching and attenuation of the horseshoe vortex. The wall shear stress vectors in the blade end-wall corner region were observed to be more skewed on the end-wall surface as compared to that on the blade surface. The differences in the wall shear stress directions obtained with the Preston tube and flow visualization method were within the range in which the Preston tube was found to be insensitive to the yaw angle.

Pressure-assisted fabrication of organic light emitting diodes with MoO{sub 3} hole-injection layer materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, J.; Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544; Anye, V. C.

2014-06-21

In this study, pressures of ∼5 to ∼8 MPa were applied to organic light emitting diodes containing either evaporated molybdenum trioxide (MoO{sub 3}) or spin-coated poly(3,4-ethylene dioxythiophene) doped with poly(styrene sulphonate) (PEDOT:PSS) hole-injection layers (HILs). The threshold voltages for both devices were reduced by about half, after the application of pressure. Furthermore, in an effort to understand the effects of pressure treatment, finite element simulations were used to study the evolution of surface contact between the HIL and emissive layer (EML) under pressure. The blister area due to interfacial impurities was also calculated. This was shown to reduce by about half,more » when the applied pressures were between ∼5 and 8 MPa. The finite element simulations used Young's modulus measurements of MoO{sub 3} that were measured using the nanoindentation technique. They also incorporated measurements of the adhesion energy between the HIL and EML (measured by force microscopy during atomic force microscopy). Within a fracture mechanics framework, the implications of the results are then discussed for the pressure-assisted fabrication of robust organic electronic devices.« less

Pressure-Aware Control Layer Optimization for Flow-Based Microfluidic Biochips.

PubMed

Wang, Qin; Xu, Yue; Zuo, Shiliang; Yao, Hailong; Ho, Tsung-Yi; Li, Bing; Schlichtmann, Ulf; Cai, Yici

2017-12-01

Flow-based microfluidic biochips are attracting increasing attention with successful biomedical applications. One critical issue with flow-based microfluidic biochips is the large number of microvalves that require peripheral control pins. Even using the broadcasting addressing scheme, i.e., one control pin controls multiple microvalves simultaneously, thousands of microvalves would still require hundreds of control prins, which is unrealistic. To address this critical challenge in control scalability, the control-layer multiplexer is introduced to effectively reduce the number of control pins into log scale of the number of microvalves. There are two practical design issues with the control-layer multiplexer: (1) the reliability issue caused by the frequent control-valve switching, and (2) the pressure degradation problem caused by the control-valve switching without pressure refreshing from the pressure source. This paper addresses these two design issues by the proposed Hamming-distance-based switching sequence optimization method and the XOR-based pressure refreshing method. Simulation results demonstrate the effectiveness and efficiency of the proposed methods with an average 77.2% (maximum 89.6%) improvement in total pressure refreshing cost, and an average 88.5% (maximum 90.0%) improvement in pressure deviation.

Habitability constraints on water-rich exoplanets

NASA Astrophysics Data System (ADS)

Noack, Lena; Höning, Dennis; Rivoldini, Attilio; Heistracher, Clemens; Zimov, Nastasia; Journaux, Baptiste; Lammer, Helmut; Van Hoolst, Tim; Hendrik Bredehöft, Jan

2016-04-01

This research addresses the characterization, modelling, thermal evolution and possible habitability of water-rich exoplanets. Water is necessary for the origin and survival of life as we know it. In the search for habitable worlds, water-rich planets therefore seem obvious candidates. The water layer on such planets could be hundreds of kilometers deep. Depending on the temperature profile and the pressure gradient, it is likely that at great depths a significant part of the water layer is solid high pressure ice. Whether the solid ice layer extends to the bottom of the water layer, or if a shallow lower ocean forms above the silicate mantle, depends amongst others on the thermal state of the planet. We therefore model the thermal evolution of water-rich planets with a 1D parameterized model. Depth-dependent profiles for thermodynamic properties as well as pressure and gravity are obtained by solving the Poisson equation for the gravity and the hydrostatic pressure equation for pre-defined mass and composition (in terms of iron, silicates and water) [1]. For density, equations of state are applied. For the simulation of the thermal evolution of water-rich planets, several parameters (as initial temperatures or layer thicknesses) are unknown. We therefore employ a quantitatve study with more than 20'000 simulations, where we investigated which parameters have the largest influence on the appearance of a lower ocean, i.e. the possible melting of high-pressure ice by heat flowing out of the silicate mantle [2]. We find that the surface temperature has the largest influence on the thickness of water layers, for which a lower ocean can still form between the high-pressure ice layer and the silicate mantle. For higher surface temperatures, not only entirely liquid oceans are possible for deeper water shells, also a liquid ocean can form under high-pressure ice layers of hundreds of kilometer thickness (for a 1 Earth-mass planet). Deeper down, the lower ocean can still appear episodically at the water-mantle boundary (WMB). We also investigated the main paramters influencing the existence of volcanic activity and silicate crust formation. Under deep water layers, the high pressure from the overlying water layer can inhibit melting in the mantle. The main parameters influencing the maximal water layer depth, for which melting is still possible, are indeed the parameters influencing the mantle energy budget, which are the amount of radioactive heat sources and the initial upper mantle temperature. Plate tectonics also has a strong influence on the existence of volcanism. Crustal parameters (initial thickness or heat sources enrichment factor) as well as the ice rheology (i.e. the isolating effect of the ice shell on the mantle) have only a small influence on melting processes in the interior and the formation of crust. [1] L. Noack, A. Rivoldini and T. Van Hoolst 2015: CHIC - Coupling Habitability, Interior and Crust: A new Code for Modeling the Thermal Evolution of Planets and Moons. INFOCOMP 2015, ISSN 2308-3484, ISBN 978-1-61208-416-9, pp. 84-90, IARIA, 2015. [2] L. Noack, D. Höning, A. Rivoldini, C. Heistracher, N. Zimov, B. Journaux, H. Lammer, T. Van Hoolst and J.H. Bredehöft: Water-rich planets: how habitable is a water layer deeper than on Earth? Submitted to Icarus.

Resilient Flexible Pressure-Activated Seal

NASA Technical Reports Server (NTRS)

Steinetz, Bruce M. (Inventor); Dunlap, Patrick H., Jr. (Inventor)

2009-01-01

A resilient, flexible, pressure-activated, high-temperature seal is adapted to be interposed between high and low pressure regions to provide sealing between opposing surfaces of adjacent relatively movable structures. The seal comprises at least one C-shaped sheet element. The C-shaped element design enables the seal to be pressure-activated to provide a radially outward biasing force, responsive to a seal-activating pressure differential acting across the seal thereby increasing resiliency. A centrally-located, resilient core structure provides load bearing and insulating properties. In an exemplary embodiment where at least two seal elements are used, each layer has a cutout slot pattern and the remaining strip material pattern. The slots provide flexibility to the seal, enabling the seal to be manually contoured to seal around corners and curves. The strip material of each layer covers the slots in each adjacent layer to minimize leakage through the slots. Attached barrier strips can block interface leakage between the seal and the opposing surfaces.

Design and development of novel bandages for compression therapy.

PubMed

Rajendran, Subbiyan; Anand, Subhash

2003-03-01

During the past few years there have been increasing concerns relating to the performance of bandages, especially their pressure distribution properties for the treatment of venous leg ulcers. This is because compression therapy is a complex system and requires two or multi-layer bandages, and the performance properties of each layer differs from other layers. The widely accepted sustained graduated compression mainly depends on the uniform pressure distribution of different layers of bandages, in which textile fibres and bandage structures play a major role. This article examines how the fibres, fibre blends and structures influence the absorption and pressure distribution properties of bandages. It is hoped that the research findings will help medical professionals, especially nurses, to gain an insight into the development of bandages. A total of 12 padding bandages have been produced using various fibres and fibre blends. A new technique that would facilitate good resilience and cushioning properties, higher and more uniform pressure distribution and enhanced water absorption and retention was adopted during the production. It has been found that the properties of developed padding bandages, which include uniform pressure distribution around the leg, are superior to existing commercial bandages and possess a number of additional properties required to meet the criteria stipulated for an ideal padding bandage. Results have indicated that none of the mostly used commercial padding bandages provide the required uniform pressure distribution around the limb.

Axisymmetric deformation of a poroelastic layer overlying an elastic half-space due to surface loading

NASA Astrophysics Data System (ADS)

Rani, Sunita; Rani, Sunita

2017-11-01

The axisymmetric deformation of a homogeneous, isotropic, poroelastic layer of uniform thickness overlying a homogeneous, isotropic, elastic half-space due to surface loads has been obtained. The fluid and the solid constituents of the porous layer are compressible and the permeability in vertical direction is different from its permeability in horizontal direction. The displacements and pore-pressure are taken as basic state variables. An analytical solution for the pore-pressure, displacements and stresses has been obtained using the Laplace-Hankel transform technique. The case of normal disc loading is discussed in detail. Diffusion of pore-pressure is obtained in the space-time domain. The Laplace inversion is evaluated using the fixed Talbot algorithm and the Hankel inversion using the extended Simpson's rule. Two different models of the Earth have been considered: continental crust model and oceanic crust model. For continental crust model, the layer is assumed to be of Westerly Granite and for the oceanic crust model of Hanford Basalt. The effect of the compressibilities of the fluid as well as solid constituents and anisotropy in permeability has been studied on the diffusion of pore-pressure. Contour maps have been plotted for the diffusion of pore-pressure for both models. It is observed that the pore-pressure changes to compression for the continental crust model with time, which is not true for the oceanic crust.

EC95-42960-5

NASA Image and Video Library

1995-02-15

NASA's single-seat F-16XL makes a drag chute landing on the runway at Edwards Air Force Base in California's Mojave Desert. The aircraft was most recently used in the Cranked-Arrow Wing Aerodynamics Project (CAWAP) to test boundary layer pressures and distribution. Previously it had been used in a program to investigate the characteristics of sonic booms for NASA's High Speed Research Program. Data from the program will be used in the development of a high speed civilian transport. During the series of sonic boom research flights, the F-16XL was used to probe the shock waves being generated by a NASA SR-71 and record their shape and intensity.

EC95-42960-4

NASA Image and Video Library

1995-02-15

NASA's single-seat F-16XL makes a drag chute landing at the Dryden Flight Research Center, Edwards, California. The aircraft was most recently used in the Cranked-Arrow Wing Aerodynamics Project (CAWAP) to test boundary layer pressures and distribution. Previously it had been used in a program to investigate the characteristics of sonic booms for NASA's High Speed Research Program. Data from the program will be used in the development of a high speed civilian transport. During the series of sonic boom research flights, the F-16XL was used to probe the shock waves being generated by a NASA SR-71 and record their shape and intensity.

Influence of free-stream disturbances on boundary-layer transition

NASA Technical Reports Server (NTRS)

Harvey, W. D.

1978-01-01

Considerable experimental evidence exists which shows that free stream disturbances (the ratio of root-mean-square pressure fluctuations to mean values) in conventional wind tunnels increase with increasing Mach number at low supersonic to moderate hypersonic speeds. In addition to local conditions, the free stream disturbance level influences transition behavior on simple test models. Based on this observation, existing noise transition data obtained in the same test facility were correlated for a large number of reference sharp cones and flat plates and are shown to collapse along a single curve. This result is a significant improvement over previous attempts to correlate noise transition data.

An analysis method for multi-component airfoils in separated flow

NASA Technical Reports Server (NTRS)

Rao, B. M.; Duorak, F. A.; Maskew, B.

1980-01-01

The multi-component airfoil program (Langley-MCARF) for attached flow is modified to accept the free vortex sheet separation-flow model program (Analytical Methods, Inc.-CLMAX). The viscous effects are incorporated into the calculation by representing the boundary layer displacement thickness with an appropriate source distribution. The separation flow model incorporated into MCARF was applied to single component airfoils. Calculated pressure distributions for angles of attack up to the stall are in close agreement with experimental measurements. Even at higher angles of attack beyond the stall, correct trends of separation, decrease in lift coefficients, and increase in pitching moment coefficients are predicted.

Thermoacoustic sound projector: exceeding the fundamental efficiency of carbon nanotubes.

PubMed

Aliev, Ali E; Codoluto, Daniel; Baughman, Ray H; Ovalle-Robles, Raquel; Inoue, Kanzan; Romanov, Stepan A; Nasibulin, Albert G; Kumar, Prashant; Priya, Shashank; Mayo, Nathanael K; Blottman, John B

2018-08-10

The combination of smooth, continuous sound spectra produced by a sound source having no vibrating parts, a nanoscale thickness of a flexible active layer and the feasibility of creating large, conformal projectors provoke interest in thermoacoustic phenomena. However, at low frequencies, the sound pressure level (SPL) and the sound generation efficiency of an open carbon nanotube sheet (CNTS) is low. In addition, the nanoscale thickness of fragile heating elements, their high sensitivity to the environment and the high surface temperatures practical for thermoacoustic sound generation necessitate protective encapsulation of a freestanding CNTS in inert gases. Encapsulation provides the desired increase of sound pressure towards low frequencies. However, the protective enclosure restricts heat dissipation from the resistively heated CNTS and the interior of the encapsulated device. Here, the heat dissipation issue is addressed by short pulse excitations of the CNTS. An overall increase of energy conversion efficiency by more than four orders (from 10 -5 to 0.1) and the SPL of 120 dB re 20 μPa @ 1 m in air and 170 dB re 1 μPa @ 1 m in water were demonstrated. The short pulse excitation provides a stable linear increase of output sound pressure with substantially increased input power density (>2.5 W cm -2 ). We provide an extensive experimental study of pulse excitations in different thermodynamic regimes for freestanding CNTSs with varying thermal inertias (single-walled and multiwalled with varying diameters and numbers of superimposed sheet layers) in vacuum and in air. The acoustical and geometrical parameters providing further enhancement of energy conversion efficiency are discussed.

Properties of medium-density fiberboard produced in an oil-heated laboratory press

Treesearch

O. Suchsland; G.E. Woodson

1976-01-01

Medium-density fiberboards from pressurized double-disk refined fibers have a close correlation between layer density and layer dynamic modulus of elasticity. Density distribution over the thickness was readily controlled by manipulating platen temperature and applied pressure. Thus, overall modulus of elasticity could be adjusted. In contrast to modulus of elasticity...

Nanomanufacturing of silicon surface with a single atomic layer precision via mechanochemical reactions.

PubMed

Chen, Lei; Wen, Jialin; Zhang, Peng; Yu, Bingjun; Chen, Cheng; Ma, Tianbao; Lu, Xinchun; Kim, Seong H; Qian, Linmao

2018-04-18

Topographic nanomanufacturing with a depth precision down to atomic dimension is of importance for advancement of nanoelectronics with new functionalities. Here we demonstrate a mask-less and chemical-free nanolithography process for regio-specific removal of atomic layers on a single crystalline silicon surface via shear-induced mechanochemical reactions. Since chemical reactions involve only the topmost atomic layer exposed at the interface, the removal of a single atomic layer is possible and the crystalline lattice beneath the processed area remains intact without subsurface structural damages. Molecular dynamics simulations depict the atom-by-atom removal process, where the first atomic layer is removed preferentially through the formation and dissociation of interfacial bridge bonds. Based on the parametric thresholds needed for single atomic layer removal, the critical energy barrier for water-assisted mechanochemical dissociation of Si-Si bonds was determined. The mechanochemical nanolithography method demonstrated here could be extended to nanofabrication of other crystalline materials.

Experimental Study of a Three-Dimensional Shear-Driven Turbulent Boundary Layer with Streamwise Adverse Pressure Gradient

NASA Technical Reports Server (NTRS)

Driver, David M.; Johnston, James P.

1990-01-01

The effects of a strong adverse pressure gradient on a three-dimensional turbulent boundary layer are studied in an axisymmetric spinning cylinder geometry. Velocity measurements made with a three-component laser Doppler velocimeter include all three mean flow components, all six Reynolds stress components, and all ten triple-product correlations. Reynolds stress diminishes as the flow becomes three-dimensional. Lower levels of shear stress were seen to persist under adverse pressure gradient conditions. This low level of stress was seen to roughly correlate with the magnitude of cross-flow (relative to free stream flow) for this experiment as well as most of the other experiments in the literature. Variations in pressure gradient do not appear to alter this correlation. For this reason, it is hypothesized that a three-dimensional boundary layer is more prone to separate than a two-dimensional boundary layer, although it could not be directly shown here. None of the computations performed with either a Prandtl mixing length, k-epsilon, or a Launder-Reece-Rodi full Reynolds-stress model were able to predict the reduction in Reynolds stress.

Selective epitaxial growth of Ge1-xSnx on Si by using metal-organic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Washizu, Tomoya; Ike, Shinichi; Inuzuka, Yuki; Takeuchi, Wakana; Nakatsuka, Osamu; Zaima, Shigeaki

2017-06-01

Selective epitaxial growth of Ge and Ge1-xSnx layers on Si substrates was performed by using metal-organic chemical vapor deposition (MOCVD) with precursors of tertiary-butyl-germane (t-BGe) and tri-butyl-vinyl-tin (TBVSn). We investigated the effects of growth temperature and total pressure during growth on the selectivity and the crystallinity of the Ge and Ge1-xSnx epitaxial layers. Under low total pressure growth conditions, the dominant mechanism of the selective growth of Ge epitaxial layers is the desorption of the Ge precursors. At a high total pressure case, it is needed to control the surface migration of precursors to realize the selectivity because the desorption of Ge precursors was suppressed. The selectivity of Ge growth was improved by diffusion of the Ge precursors on the SiO2 surfaces when patterned substrates were used at a high total pressure. The selective epitaxial growth of Ge1-xSnx layer was also realized using MOCVD. We found that the Sn precursors less likely to desorb from the SiO2 surfaces than the Ge precursors.