Microring resonator based modulator made by direct photodefinition of an electro-optic polymer

NASA Astrophysics Data System (ADS)

Balakrishnan, M.; Faccini, M.; Diemeer, M. B. J.; Klein, E. J.; Sengo, G.; Driessen, A.; Verboom, W.; Reinhoudt, D. N.

2008-04-01

A laterally coupled microring resonator was fabricated by direct photodefinition of negative photoresist SU8, containing tricyanovinylidenediphenylaminobenzene chromophore, by exploiting the low ultraviolet absorption window of this chromophore. The ring resonator was first photodefined by slight cross-linking. Thereafter, poling (to align the chromophores) and further cross-linking (to increase the glass transition temperature) were simultaneously carried out. The material showed excellent photostability and the electro-optic modulation with an r33 of 11pm/V was demonstrated at 10MHz.

l-Proline and RNA Duplex m-Value Temperature Dependence.

PubMed

Schwinefus, Jeffrey J; Baka, Nadia L; Modi, Kalpit; Billmeyer, Kaylyn N; Lu, Shutian; Haase, Lucas R; Menssen, Ryan J

2017-08-03

The temperature dependence of l-proline interactions with the RNA dodecamer duplex surface exposed after unfolding was quantified using thermal and isothermal titration denaturation monitored by uv-absorbance. The m-value quantifying proline interactions with the RNA duplex surface area exposed after unfolding was measured using RNA duplexes with GC content ranging between 17 and 83%. The m-values from thermal denaturation decreased with increasing GC content signifying increasingly favorable proline interactions with the exposed RNA surface area. However, m-values from isothermal titration denaturation at 25.0 °C were independent of GC content and less negative than those from thermal denaturation. The m-value from isothermal titration denaturation for a 50% GC RNA duplex decreased (became more negative) as the temperature increased and was in nearly exact agreement with the m-value from thermal denaturation. Since RNA duplex transition temperatures increased with GC content, the more favorable proline interactions with the high GC content duplex surface area observed from thermal denaturation resulted from the temperature dependence of proline interactions rather than the RNA surface chemical composition. The enthalpy contribution to the m-value was positive and small (indicating a slight increase in duplex unfolding enthalpy with proline) while the entropic contribution to the m-value was positive and increased with temperature. Our results will facilitate proline's use as a probe of solvent accessible surface area changes during biochemical reactions at different reaction temperatures.

Hemodynamic changes during whole body surface cooling and lower body negative pressure

NASA Technical Reports Server (NTRS)

Raven, P. B.; Pape, G.; Taylor, W. F.; Gaffney, F. A.; Blomqvist, C. G.

1981-01-01

Six young healthy male subjects were studied to evaluate the use of whole body surface cooling (WBSC) as an antiorthostatic intervention. Previous studies have demonstrated that perfusion of an Apollo cooling garment with 16 C water produced a significant increase in stroke volume and decrease in heart rate at rest and during lower body negative pressure (LBNP). However, optimal perfusion temperatures have not been determined. The present study examined the effects of WBSC using perfusion of water at a temperature of 10 C. This perfusion temperature produced a greater decrease in mean skin temperature than water at 16 C (4 C drop compared to 2 C). The hemodynamic effects were also more prominent with 10 C water as shown by the increase in stroke volume of 11% at rest and of 35% during LBNP at -50 torr compared to control measurements at ambient temperature. Heart rates were lowered significantly (8 beats/min) and systolic arterial blood pressure was higher (8 torr). Cooling with 10 C water produced a slight increase in muscle tone, reflected by a small but significant increase (+84 ml/min) in oxygen uptake. These data suggest that WBSC is an effective nonpharmacologic means of controlling preload and deserves further investigation as an antiorthostatic intervention.

Ocean warming ameliorates the negative effects of ocean acidification on Paracentrotus lividus larval development and settlement.

PubMed

García, Eliseba; Clemente, Sabrina; Hernández, José Carlos

2015-09-01

Ocean warming and acidification both impact marine ecosystems. All organisms have a limited body temperature range, outside of which they become functionally constrained. Beyond the absolute extremes of this range, they cannot survive. It is hypothesized that some stressors can present effects that interact with other environmental variables, such as ocean acidification (OA) that have the potential to narrow the thermal range where marine species are functional. An organism's response to ocean acidification can therefore be highly dependent on thermal conditions. This study evaluated the combined effects of predicted ocean warming conditions and acidification, on survival, development, and settlement, of the sea urchin Paracentrotus lividus. Nine combined treatments of temperature (19.0, 20.5 and 22.5 °C) and pH (8.1, 7.7 and 7.4 units) were carried out. All of the conditions tested were either within the current natural ranges of seawater pH and temperature or are within the ranges that have been predicted for the end of the century, in the sampling region (Canary Islands). Our results indicated that the negative effects of low pH on P. lividus larval development and settlement will be mitigated by a rise in seawater temperature, up to a thermotolerance threshold. Larval development and settlement performance of the sea urchin P. lividus was enhanced by a slight increase in temperature, even under lowered pH conditions. However, the species did show negative responses to the levels of ocean warming and acidification that have been predicted for the turn of the century. Copyright © 2015 Elsevier Ltd. All rights reserved.

Reuse of waste beer yeast sludge for biosorptive decolorization of reactive blue 49 from aqueous solution.

PubMed

Wang, Baoe; Guo, Xiu

2011-06-01

Reactive blue 49 was removed from aqueous solution by biosorption using powder waste sludge composed of Saccharomyces cerevisiae from the beer-brewing industry. The effect of initial pH, temperature and the biosorption thermodynamics, equilibrium, kinetics was investigated in this study. It was found that the biosorption capacity was at maximum at initial pH 3, that the effect of temperature on biosorption of reactive blue 49 was only slight in relation to the large biosorption capacity (25°C, 361 mg g(-1)) according as the biosorption capacity decreased only 43 mg g(-1) at the temperature increased from 25 to 50°C. The biosorption was spontaneous, exothermic in nature and the dye molecules movements decreased slightly in random at the solid/liquid interface during the biosorption of dye on biosorbents. The biosorption equilibrium data could be described by Freundich isotherm model. The biosorption rates were found to be consistent with a pseudo-second-order kinetics model. The functional group interaction analysis between waste beer yeast sludge and reactive blue 49 by the aid of Fourier transform infrared (abbr. FTIR) spectroscopy indicated that amino components involved in protein participated in the biosorption process, which may be achieved by the mutual electrostatic adsorption process between the positively charged amino groups in waste beer yeast sludge with negatively charged sulfonic groups in reactive blue 49.

Fine thermotactic discrimination between the optimal and slightly cooler temperatures via a TRPV channel in chordotonal neurons.

PubMed

Kwon, Young; Shen, Wei L; Shim, Hye-Seok; Montell, Craig

2010-08-04

Animals select their optimal environmental temperature, even when faced with alternatives that differ only slightly. This behavior is critical as small differences in temperature of only several degrees can have a profound effect on the survival and rate of development of poikilothermic animals, such as the fruit fly. Here, we demonstrate that Drosophila larvae choose their preferred temperature of 17.5 degrees C over slightly cooler temperatures (14-16 degrees C) through activation of chordotonal neurons. Mutations affecting a transient receptor potential (TRP) vanilloid channel, Inactive (Iav), which is expressed specifically in chordotonal neurons, eliminated the ability to choose 17.5 degrees C over 14-16 degrees C. The impairment in selecting 17.5 degrees C resulted from absence of an avoidance response, which is normally mediated by an increase in turns at the lower temperatures. We conclude that the decision to select the preferred over slightly cooler temperatures requires iav and is achieved by activating chordotonal neurons, which in turn induces repulsive behaviors, due to an increase in high angle turns.

Fine Thermotactic Discrimination between the Optimal and Slightly Cooler Temperatures via a TRPV Channel in Chordotonal Neurons

PubMed Central

Kwon, Young; Shen, Wei L.; Shim, Hye-Seok; Montell, Craig

2012-01-01

Animals select their optimal environmental temperature, even when faced with alternatives that differ only slightly. This behavior is critical as small differences in temperature of only several degrees can have a profound effect on the survival and rate of development of poikilothermic animals, such as the fruit fly. Here, we demonstrate that Drosophila larvae choose their preferred temperature of 17.5°C over slightly cooler temperatures (14–16°C) through activation of chordotonal neurons. Mutations affecting a transient receptor potential (TRP) vanilloid channel, Inactive (Iav), which is expressed specifically in chordotonal neurons, eliminated the ability to choose 17.5°C over 14–16°C. The impairment in selecting 17.5°C resulted from absence of an avoidance response, which is normally mediated by an increase in turns at the lower temperatures. We conclude that the decision to select the preferred over slightly cooler temperatures requires iav and is achieved by activating chordotonal neurons, which in turn induces repulsive behaviors, due to an increase in high angle turns. PMID:20685989

Negative response of photosynthesis to natural and projected high seawater temperatures estimated by pulse amplitude modulation fluorometry in a temperate coral.

PubMed

Caroselli, Erik; Falini, Giuseppe; Goffredo, Stefano; Dubinsky, Zvy; Levy, Oren

2015-01-01

Balanophyllia europaea is a shallow water solitary zooxanthellate coral, endemic to the Mediterranean Sea. Extensive field studies across a latitudinal temperature gradient highlight detrimental effects of rising temperatures on its growth, demography, and skeletal characteristics, suggesting that depression of photosynthesis at high temperatures might cause these negative effects. Here we test this hypothesis by analyzing, by means of pulse amplitude modulation fluorometry, the photosynthetic efficiency of B. europaea specimens exposed in aquaria to the annual range of temperatures experienced in the field (13, 18, and 28°C), and two extreme temperatures expected for 2100 as a consequence of global warming (29 and 32°C). The indicators of photosynthetic performance analyzed (maximum and effective quantum yield) showed that maximum efficiency was reached at 20.0-21.6°C, slightly higher than the annual mean temperature in the field (18°C). Photosynthetic efficiency decreased from 20.0 to 13°C and even more strongly from 21.6 to 32°C. An unusual form of bleaching was observed, with a maximum zooxanthellae density at 18°C that strongly decreased from 18 to 32°C. Chlorophyll a concentration per zooxanthellae cell showed an opposite trend as it was minimal at 18°C and increased from 18 to 32°C. Since the areal chlorophyll concentration is the product of the zooxanthellae density and its cellular content, these trends resulted in a homogeneous chlorophyll concentration per coral surface across temperature treatments. This confirms that B. europaea photosynthesis is progressively depressed at temperatures >21.6°C, supporting previous hypotheses raised by the studies on growth and demography of this species. This study also confirms the threats posed to this species by the ongoing seawater warming.

Preparation and characterization of methacrylate hydrogels for zeta potential control

NASA Technical Reports Server (NTRS)

Gregonis, D. E.; Ma, S. M.; Vanwagenen, R.; Andrade, J. D.

1976-01-01

A technique based on the measurement of streaming potentials has been developed to evaluate the effects of hydrophilic coatings on electroosmotic flow. The apparatus and procedure are described as well as some results concerning the electrokinetic potential of glass capillaries as a function of ionic strength, pH, and temperature. The effect that turbulence and entrance flow conditions have on accurate streaming potential measurements is discussed. Various silane adhesion promoters exhibited only a slight decrease in streaming potential. A coating utilizing a glycidoxy silane base upon which methylcellulose is applied affords a six-fold decrease over uncoated tubes. Hydrophilic methacrylate gels show similar streaming potential behavior, independent of the water content of the gel. By introduction of positive or negative groups into the hydrophilic methacrylate gels, a range of streaming potential values are obtained having absolute positive or negative signs.

Can hydrothermal pretreatment improve anaerobic digestion for biogas from lignocellulosic biomass?

PubMed

Wang, Dou; Shen, Fei; Yang, Gang; Zhang, Yanzong; Deng, Shihuai; Zhang, Jing; Zeng, Yongmei; Luo, Tao; Mei, Zili

2018-02-01

Hydrothermally-pretreated rice straw (HPRS) from various pretreatment temperatures was anaerobically-digested in whole slurry. Results indicated promoting pretreatment temperature significantly deconstructed rice straw, and facilitated the conversion of insoluble fractions to soluble fractions. Although 306.6 mL/g TS biogas was maximally yielded in HPRS-90 and HPRS-180, respectively, via digestion in whole slurry, it was only 3% promotion compared to the unpretreated rice straw. HPRS-210 yielded 208.5 mL/g TS biogas, which was 30% reduction with longer lag period of 19.8 d, suggesting serious inhibitions happened. Through slightly increasing organic loading, more serious acidification and reduction on biogas yield, especially at higher pretreatment temperatures, indicated the soluble fractions controlled digestion performances. Pearson correlation analysis suggested negative relationship existed between methane yield and the soluble fractions including soluble carbohydrates, formic acid and furfural. Hydrothermal pretreatment, especially at higher temperature, did not improve anaerobic digestion, thereby, was not recommended, however, lower temperature can be considered potentially. Copyright © 2017 Elsevier Ltd. All rights reserved.

Recovery, statistical validation and analysis of a historical meteorological dataset collected at the Hanbury Botanical Gardens (Liguria, northwestern Italy) from 1900 to 1940

NASA Astrophysics Data System (ADS)

Vagge, Greta; Cutroneo, Laura; Gandolfi, Daniela; Ferretti, Gabriele; Scafidi, Davide; Capello, Marco

2018-05-01

A historical set of daily meteorological data collected at the Hanbury Botanical Gardens (Liguria, northwestern Italy) from 1900 to 1940 was recovered from five manually entered registers. They were digitised and statistically analysed to check their reliability and study their trends and variations. In particular, air temperature, precipitation and their extreme values were considered, together with wind direction, sea state, sky conditions and relative humidity. The results show a decreasing trend in mean annual temperature of approximately 0.2 °C/decade due to a decrease in maximum air temperature. Annual cumulative precipitation increased by 65.2 mm/decade over the study period. The data analysis showed a summer temperature decrease in 1912 and a severe drought in 1921. Moreover, the years with most days with extreme temperatures were associated to the negative phases of the North Atlantic oscillation (NAO). During the study period, SW winds were prevailing. Sky conditions followed seasonal trends, while slight sea was the most frequent sea state.

Fluorescence quenching of human orosomucoid. Accessibility to drugs and small quenching agents.

PubMed Central

Friedman, M L; Schlueter, K T; Kirley, T L; Halsall, H B

1985-01-01

The fluorescence behaviour of human orosomucoid was investigated. The intrinsic fluorescence was more accessible to acrylamide than to the slightly larger succinimide, indicating limited accessibility to part of the tryptophan population. Although I- showed almost no quenching, that of Cs+ was enhanced, and suggested a region of negative charge proximal to an emitting tryptophan residue. Removal of more than 90% of sialic acid from the glycan chains led to no change in the Cs+, I-, succinimide or acrylamide quenching, indicating that the negatively charged region originates with the protein core. Quenching as a function of pH and temperature supported this view. The binding of chlorpromazine monitored by fluorescence quenching, in the presence and in the absence of the small quenching probes (above), led to a model of its binding domain on orosomucoid that includes two tryptophan residues relatively shielded from the bulk solvent, with the third tryptophan residue being on the periphery of the domain, or affected allotopically and near the negatively charged field. PMID:4091825

Circadian rhythms in human performance and mood under constant conditions

NASA Technical Reports Server (NTRS)

Monk, T. H.; Buysse, D. J.; Reynolds, C. F. 3rd; Berga, S. L.; Jarrett, D. B.; Begley, A. E.; Kupfer, D. J.

1997-01-01

This study explored the relationship between circadian performance rhythms and rhythms in rectal temperature, plasma cortisol, plasma melatonin, subjective alertness and well-being. Seventeen healthy young adults were studied under 36 h of 'unmasking' conditions (constant wakeful bedrest, temporal isolation, homogenized 'meals') during which rectal temperatures were measured every minute, and plasma cortisol and plasma melatonin measured every 20 min. Hourly subjective ratings of global vigour (alertness) and affect (well-being) were obtained followed by one of two performance batteries. On odd-numbered hours performance (speed and accuracy) of serial search, verbal reasoning and manual dexterity tasks was assessed. On even-numbered hours, performance (% hits, response speed) was measured at a 25-30 min visual vigilance task. Performance of all tasks (except search accuracy) showed a significant time of day variation usually with a nocturnal trough close to the trough in rectal temperature. Performance rhythms appeared not to reliably differ with working memory load. Within subjects, predominantly positive correlations emerged between good performance and higher temperatures and better subjective alertness; predominantly negative correlations between good performance and higher plasma levels of cortisol and melatonin. Temperature and cortisol rhythms correlated with slightly more performance measures (5/7) than did melatonin rhythms (4/7). Global vigour correlated about as well with performance (5/7) as did temperature, and considerably better than global affect (1/7). In conclusion: (1) between-task heterogeneity in circadian performance rhythms appeared to be absent when the sleep/wake cycle was suspended; (2) temperature (positively), cortisol and melatonin (negatively) appeared equally good as circadian correlates of performance, and (3) subjective alertness correlated with performance rhythms as well as (but not better than) body temperature, suggesting that performance rhythms were not directly mediated by rhythms in subjective alertness.

Thermodynamics of Host–Guest Interactions between Fullerenes and a Buckycatcher

PubMed Central

2015-01-01

1H NMR and isothermal titration calorimetry (ITC) experiments were employed to obtain reliable thermodynamic data for the formation of the 1:1 inclusion complexes of fullerenes C60 and C70 with the buckycatcher (C60H28). NMR measurements were done in toluene-d8 and chlorobenzene-d5 at 288, 298, and 308 K, while the ITC titrations were performed in toluene, chlorobenzene, o-dichlorobenzene, anisole, and 1,1,2,2-tetrachloroethane at temperatures from 278 to 323 K. The association constants, Ka, obtained with both techniques are in very good agreement. The thermodynamic data obtained by ITC indicate that generally the host–guest association is enthalpy-driven. Interestingly, the entropy contributions are, with rare exceptions, slightly stabilizing or close to zero. Neither ΔH nor ΔS is constant over the temperature range studied, and these thermodynamic functions exhibit classical enthalpy/entropy compensation. The ΔCp values calculated from the temperature dependence of the calorimetric ΔH values are negative for the association of both fullerenes with the buckycatcher in toluene. The negative ΔCp values are consistent with some desolvation of the host-cavity and the guest in the inclusion complexes, C60@C60H28 and C70@C60H28. PMID:25248285

Doors are closing on early development in corals facing climate change

NASA Astrophysics Data System (ADS)

Keshavmurthy, Shashank; Fontana, Silvia; Mezaki, Takuma; González, Laura Del Caño; Chen, Chaolun Allen

2014-07-01

Marine invertebrates are particularly vulnerable to climatic anomalies in early life history stages because of the time spent in the water column. Studies have focused on the effect of seawater temperature on fertilization, development, and larval stages in corals; however, none of them show comparative results along an environmental gradient. In this study, we show that temperatures in the range of 15-33°C have strong effects on fertilization rates and embryonic stages of two coral species, Acropora muricata in the subtropical environment and Acropora hyacinthus in subtropical and temperate environments. Deformations after the first cleavage stages were observed at low (15°C) and high (33°C) temperatures. Development was delayed by 6-7 h in the slightly non-optimal temperature of 20°C. We found significant differences in fertilization rates and responses of embryos from different latitudes, with temperate corals being more sensitive to extremely hot temperatures and vice versa. We hypothesize that the coral development is restricted to a narrow temperature range and deviation outside this window could inhibit a species' continuance and ecological success. Thus, it would have significant negative effects on adult populations and communities, playing a role in future of coral reef survival.

Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

USGS Publications Warehouse

Healy, R.W.; DeVries, M.P.; Sturrock, A.M.

1987-01-01

From July 1982 through June 1984, a study was made of the microclimate and evapotranspiration at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy-budget with the Bowen ratio, (2) an aerodynamic-profile, and (3) a soil-based water-budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data, then summed by days and months. Yearly estimates for March through November, by these methods, were quite close--648 and 626 millimeters, respectively. Daily estimates range up to a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soil-moisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately out of the south-southeast. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends in evapotranspiration rates mirrored those in net radiation; July was usually the month with the highest rate. The ratio of sensible- to latent-heat fluxes (commonly called the Bowen ratio) for the 2-year period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

Growth, carcass characteristics, and incidence of ascites in broilers exposed to environmental fluctuations and oiled litter.

PubMed

McGovern, R H; Feddes, J J; Robinson, F E; Hanson, J A

2000-03-01

The effects of diurnal temperature fluctuations and removal of respirable dust, by application of canola oil to straw litter, on growth, carcass traits, and the degree of ascites was evaluated with 1,200 male broilers studied in two replicated 6-wk trials. Each trial used four pens of 150 birds. The temperature treatment consisted of a fluctuation of 3 C in temperature above the required temperature during the day (0600 to 1800 h) and 3 C below the required temperature at night (1800 to 0600 h) for a 6 C change in daily temperature. The control temperature was constant. All pens had the same mean daily temperature. In each trial, one control temperature pen and one fluctuation temperature pen received bi-weekly applications of canola oil to the litter (1.1 L/m2 of oil over 6 wk). At 6 wk of age, 30 birds from each pen were killed for determination of breast muscle, fatpad, and heart weights. All birds were scored for lesions of ascites at time of processing. A score of 0 or 1 represented slight pericardial effusion, slight pulmonary congestion, and edema. A score of 4 represented birds with marked accumulation of ascitic fluid in one or more ceolomic cavities (other than the pericardium) and advanced liver lesions. A cross-sectional image of each 4-mm heart slice (cross-section of the ventricles) was digitally recorded, and with image analysis we determined the right ventricular area (RVA), left ventricular area (LVA), and total heart area (HA). The final BW of the broilers were significantly different, the oiled-litter treatment (2,249 g) had lower weight gain compared with the nonoiled litter treatment (2,293 g). There were no differences in fatpad weight, shank length, lung weight, and percentage breast muscle between the main treatments. The Pectoralis minor and Pectoralis major weight were significantly heavier in the temperature fluctuation treatment than in the control temperature treatment by 3.0 and 12.0 g, respectively. The birds subjected to the control temperature treatment had a lower RVW than the birds subjected to the fluctuating temperature treatment. Temperature fluctuations also resulted in a 1.4% increase in the incidence of mortality. Temperature fluctuations negatively impact broiler growth due to heat loss when litter oiling was excessive.

Negative ion source

DOEpatents

Delmore, James E.

1987-01-01

A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reeccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200.degree. to 500.degree. for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

Thermal conductivity and thermal diffusivity of methane hydrate formed from compacted granular ice

NASA Astrophysics Data System (ADS)

Zhao, Jie; Sun, Shicai; Liu, Changling; Meng, Qingguo

2018-05-01

Thermal conductivity and thermal diffusivity of pure methane hydrate samples, formed from compacted granular ice (0-75 μm), and were measured simultaneously by the transient plane source (TPS) technique. The temperature dependence was measured between 263.15 and 283.05 K, and the gas-phase pressure dependence was measured between 2 and 10 MPa. It is revealed that the thermal conductivity of pure methane hydrate exhibits a positive trend with temperature and increases from 0.4877 to 0.5467 W·m-1·K-1. The thermal diffusivity of methane hydrate has inverse dependence on temperature and the values in the temperature range from 0.2940 to 0.3754 mm2·s-1, which is more than twice that of water. The experimental results show that the effects of gas-phase pressure on the thermal conductivity and thermal diffusivity are very small. Thermal conductivity of methane hydrate is found to have weakly positive gas-phase pressure dependence, whereas the thermal diffusivity has slightly negative trend with gas-phase pressure.

The occurrence of ice production in slightly supercooled Arctic stratiform clouds as observed by ground-based remote sensors at the ARM NSA site

NASA Astrophysics Data System (ADS)

Zhang, Damao; Wang, Zhien; Luo, Tao; Yin, Yan; Flynn, Connor

2017-03-01

Ice particle formation in slightly supercooled stratiform clouds is not well documented or understood. In this study, 4 years of combined lidar depolarization and radar reflectivity (Ze) measurements are analyzed to distinguish between cold drizzle and ice crystal formations in slightly supercooled Arctic stratiform clouds over the Atmospheric Radiation Measurement Program Climate Research Facility North Slope of Alaska Utqiaġvik ("Barrow") site. Ice particles are detected and statistically shown to be responsible for the strong precipitation in slightly supercooled Arctic stratiform clouds at cloud top temperatures as high as -4°C. For ice precipitating Arctic stratiform clouds, the lidar particulate linear depolarization ratio (δpar_lin) correlates well with radar Ze at each temperature range, but the δpar_lin-Ze relationship varies with temperature ranges. In addition, lidar depolarization and radar Ze observations of ice generation characteristics in Arctic stratiform clouds are consistent with laboratory-measured temperature-dependent ice growth habits.

Effect of heat recovery water heater system on the performance of residential split air conditioner using hydrocarbon refrigerant (HCR22)

NASA Astrophysics Data System (ADS)

Aziz, A.; Thalal; Amri, I.; Herisiswanto; Mainil, A. K.

2017-09-01

This This paper presents the performance of residential split air conditioner (RSAC) using hydrocarbon refrigerant (HCR22) as the effect on the use of heat recovery water heater system (HRWHS). In this study, RSAC was modified with addition of dummy condenser (trombone coil type) as heat recovery water heater system (HRWHS). This HRWHS is installed between a compressor and a condenser by absorbing a part of condenser waste heat. The results show that RSAC with HRWHS is adequate to generate hot water with the temperature range about 46.58˚C - 48.81˚C when compared to without HRWHS and the use of dummy condenser does not give significant effect to the split air conditioner performance. When the use of HRWHS, the refrigerant charge has increase about 19.05%, the compressor power consumption has slightly increase about 1.42% where cooling capacity almost the same with slightly different about 0.39%. The condenser heat rejection is lower about 2.68% and the COP has slightly increased about 1.05% when compared to without HRWHS. The use of HRWHS provide free hot water, it means there is energy saving for heating water without negative impact to the system performance of RSAC.

Temperature and Term Low Birth Weight in California.

PubMed

Basu, Rupa; Rau, Reina; Pearson, Dharshani; Malig, Brian

2018-06-12

Few investigations have explored temperature and birth outcomes. In a retrospective cohort study, we examined apparent temperature, a combination of temperature and relative humidity, and term low birth weight (LBW) among 43,629 full-term LBW infants and 2,032,601 normal weight infants in California from 1999 to 2013. The California Department of Public Health provided birth certificate data, while meteorologic data came from the California Irrigation Management Information System, US Environmental Protection Agency, and National Centers for Environmental Information. After considering several temperature metrics, we observed the best model fit for term LBW over the full gestation (13.0% change, 95% confidence interval: 4.1, 22.7 per 10 degrees Fahrenheit (°F) increase in apparent temperature) above 55°F and the greatest association for third trimester exposure above 60°F (15.8%, 95% confidence interval: 5.0, 27.6). Apparent temperature during the first month of pregnancy exhibited no significant risk, while the first trimester had a significantly negative association, and second trimester, last month and last two weeks had slightly increased risks. Mothers who were Black, older, delivered male infants, or gave birth during the warm season conferred the highest risks. This study provides further evidence for adverse birth outcomes from heat exposure for vulnerable subgroups of pregnant women.

Monitoring of soil and air-rock temperatures in the Western Massif of the Picos de Europa (Spain)

NASA Astrophysics Data System (ADS)

Ruiz-Fernández, Jesús; Vieira, Gonçalo; García, Cristina

2013-04-01

In this paper we study the ground thermal regime and air-rock interface in the Western Massif of the Picos de Europa (Cantabrian Range, Spain). This calcareous massif is highly affected by karstification processes. Quaternary glaciers, fluvio-torrential processes and present-day periglacial processes also contribute to explain the landforms present in this massif. Up to 9 dataloggers were installed during 6 years in different sites in terms of altitude, orientation, slope and geomorpolohical setting recording temperatures every two hours. The number of freeze-thaw cycles in the soil(between 0 and 16) was controlled by the depth of the snow cover. The temperatures in the interface rock-air showed between 30-60 cycles, reaching 119 and 130 during the year 2007-2008. Extreme minimum temperatures in the soil oscillate between 0.3 and -6.3, while in the rocky walls the loggers recorded temperatures between -7.3 and -14.3°C. Monitoring of soil temperatures around the ice patch - the only one in the massif today - resulted in slightly negative mean annual temperatures. These conditions may reveal the existence of sporadic permafrost on debris that cover the ice patch. Both the buried ice and the permafrost are in disequilibrium with the current environmental conditions of the massif.

Effect of temperature on the treatment of domestic wastewater with a staged anaerobic fluidized membrane bioreactor.

PubMed

Yoo, R H; Kim, J H; McCarty, P L; Bae, J H

2014-01-01

A laboratory staged anaerobic fluidized membrane bioreactor (SAF-MBR) system was applied to the treatment of primary clarifier effluent from a domestic wastewater treatment plant with temperature decreasing from 25 to 10 °C. At all temperatures and with a total hydraulic retention time of 2.3 h, overall chemical oxygen demand (COD) and biochemical oxygen demand (BOD5) removals were 89% and 94% or higher, with permeate COD and BOD5 of 30 and 7 mg/L or lower, respectively. No noticeable negative effects of low temperature on organic removal were found, although a slight increase to 3 mg/L in volatile fatty acids concentrations in the effluent was observed. Biosolids production was 0.01-0.03 kg volatile suspended solids/kg COD, which is far less than that with aerobic processes. Although the rate of trans-membrane pressure at the membrane flux of 9 L/m(2)/h increased as temperature decreased, the SAF-MBR was operated for longer than 200 d before chemical cleaning was needed. Electrical energy potential from combustion of the total methane production (gaseous and dissolved) was more than that required for system operation.

The Feasibility of Using Thermal Strain Imaging to Regulate Energy Delivery During Intracardiac Radio-Frequency Ablation

PubMed Central

Seo, Chi Hyung; Stephens, Douglas N.; Cannata, Jonathan; Dentinger, Aaron; Lin, Feng; Park, Suhyun; Wildes, Douglas; Thomenius, Kai E.; Chen, Peter; Nguyen, Tho; de La Rama, Alan; Jeong, Jong Seob; Mahajan, Aman; Shivkumar, Kalyanam; Nikoozadeh, Amin; Oralkan, Omer; Truong, Uyen; Sahn, David J.; Khuri-Yakub, Pierre T.; O’Donnell, Matthew

2011-01-01

A method is introduced to monitor cardiac ablative therapy by examining slope changes in the thermal strain curve caused by speed of sound variations with temperature. The sound speed of water-bearing tissue such as cardiac muscle increases with temperature. However, at temperatures above about 50°C, there is no further increase in the sound speed and the temperature coefficient may become slightly negative. For ablation therapy, an irreversible injury to tissue and a complete heart block occurs in the range of 48 to 50°C for a short period in accordance with the well-known Arrhenius equation. Using these two properties, we propose a potential tool to detect the moment when tissue damage occurs by using the reduced slope in the thermal strain curve as a function of heating time. We have illustrated the feasibility of this method initially using porcine myocardium in vitro. The method was further demonstrated in vivo, using a specially equipped ablation tip and an 11-MHz microlinear intracardiac echocardiography (ICE) array mounted on the tip of a catheter. The thermal strain curves showed a plateau, strongly suggesting that the temperature reached at least 50°C. PMID:21768025

Analysis of Knock Phenomenon Induced in a Constant Volume Chamber by Local Gas Temperature Measurement and Visualization

NASA Astrophysics Data System (ADS)

Moriyoshi, Yasuo; Kobayashi, Shigemi; Enomoto, Yoshiteru

Knock phenomenon in SI engines is regarded as an auto-ignition of unburned end-gas, and it has been widely examined by using rapid compression machines (RCM), shock-tubes or test engines. Recent researches point out the importance of the low temperature chemical reaction and the negative temperature coefficient (NTC). To investigate the effects, analyses of instantaneous local gas temperature, flow visualization and gaseous pressure were conducted in this study. As measurements using real engines are too difficult to analyze, the authors aimed to make measurements using a constant volume vessel under knock conditions where propagating flame exists during the induction time of auto-ignition. Adopting the two-wire thermocouple method enabled us to measure the instantaneous local gas temperature until the moment when the flame front passes by. High-speed images inside the unburned region were also recorded simultaneously using an endoscope. As a result, it was found that when knock occurs, the auto-ignition initiation time seems slightly early compared to the results without knock. This causes a higher volume ratio of unburned mixture and existence of many hot spots and stochastically leads to an initiation of knock.

Experimental Investigation of A Twin Shaft Micro Gas-Turbine System

NASA Astrophysics Data System (ADS)

Sadig, Hussain; Sulaiman, Shaharin Anwar; Ibrahim, Idris

2013-06-01

Due to the fast depletion of fossil fuels and its negative impact on the environment, more attention has been concentrated to find new resources, policies and technologies, which meet the global needs with regard to fuel sustainability and emissions. In this paper, as a step to study the effect of burning low calorific value fuels on gas-turbine performance; a 50 kW slightly pressurized non-premixed tubular combustor along with turbocharger based twin shaft micro gas-turbine was designed and fabricated. A series of tests were conducted to characterize the system using LPG fuel. The tests include the analysis of the temperature profile, pressure and combustor efficiency as well as air fuel ratio and speed of the second turbine. The tests showed a stable operation with acceptable efficiency, air fuel ratio, and temperature gradient for the single and twin shaft turbines.

Late holocene climate changes in eastern North America estimated from pollen data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gajewski, K.

Well-dated pollen profiles from six sites from Maine to Minnesota record vegetation changes indicative of summer temperature and annual precipitation variations over the past 2000 yr. Laminations in the sediment provide accurate time control. Multiple regression techniques were used to calculate calibration functions from a spatial network of modern pollen and climate data. When applied to the six pollen diagrams, these calibration functions yielded estimates that show a long-term trend toward lower summer temperature. Superimposed on this long-term trend are short-term fluctuations that are frequently in phase at the sites. Departures from the long-term cooling trend are positive around 1500more » yr ago (indicating relative warmth) and negative between 200 and 500 yr ago (indicating relative cold). Annual precipitation showed a slight increase at several sites during the past 1000 yr relative to the previous 1000 yr.« less

Negative response of photosynthesis to natural and projected high seawater temperatures estimated by pulse amplitude modulation fluorometry in a temperate coral

PubMed Central

Caroselli, Erik; Falini, Giuseppe; Goffredo, Stefano; Dubinsky, Zvy; Levy, Oren

2015-01-01

Balanophyllia europaea is a shallow water solitary zooxanthellate coral, endemic to the Mediterranean Sea. Extensive field studies across a latitudinal temperature gradient highlight detrimental effects of rising temperatures on its growth, demography, and skeletal characteristics, suggesting that depression of photosynthesis at high temperatures might cause these negative effects. Here we test this hypothesis by analyzing, by means of pulse amplitude modulation fluorometry, the photosynthetic efficiency of B. europaea specimens exposed in aquaria to the annual range of temperatures experienced in the field (13, 18, and 28°C), and two extreme temperatures expected for 2100 as a consequence of global warming (29 and 32°C). The indicators of photosynthetic performance analyzed (maximum and effective quantum yield) showed that maximum efficiency was reached at 20.0–21.6°C, slightly higher than the annual mean temperature in the field (18°C). Photosynthetic efficiency decreased from 20.0 to 13°C and even more strongly from 21.6 to 32°C. An unusual form of bleaching was observed, with a maximum zooxanthellae density at 18°C that strongly decreased from 18 to 32°C. Chlorophyll a concentration per zooxanthellae cell showed an opposite trend as it was minimal at 18°C and increased from 18 to 32°C. Since the areal chlorophyll concentration is the product of the zooxanthellae density and its cellular content, these trends resulted in a homogeneous chlorophyll concentration per coral surface across temperature treatments. This confirms that B. europaea photosynthesis is progressively depressed at temperatures >21.6°C, supporting previous hypotheses raised by the studies on growth and demography of this species. This study also confirms the threats posed to this species by the ongoing seawater warming. PMID:26582993

Evaluation of the precipitation-in-gel reaction in the diagnosis of smallpox*

PubMed Central

Mitra, A. C.; Sarkar, J. K.; Mukherjee, M. K.; Chakravarty, M. S.

1973-01-01

Specimens of vesicular or pustular fluids and of scabs from patients with smallpox as well as emulsions of variola-infected chorioallantoic membrane (CAM) were tested for virus titres and by the precipitation-in-gel (PIG) reaction. They were also tested after exposing them directly to sunlight and after keeping them at temperatures of -20°C, 4°C, and 25°C. It was found that when extracts of fresh specimens were diluted to the point where the PIG reaction became negative there was still a titre of 104-105 infectivity in the swab extracts and 103-104 infectivity in the scab extracts. It was also found that the PIG reactions were all negative on specimens that were kept for 14 days at 25°C, and that several were negative after only 7 days; the loss in infectivity titre, however, was only slight in all the specimens tested. It is concluded that the laboratory diagnosis of smallpox by virus inoculation of CAM is more reliable than by the PIG test. PMID:4374321

Evaluation of the precipitation-in-gel reaction in the diagnosis of smallpox.

PubMed

Mitra, A C; Sarkar, J K; Mukherjee, M K; Chakravarty, M S

1973-01-01

Specimens of vesicular or pustular fluids and of scabs from patients with smallpox as well as emulsions of variola-infected chorioallantoic membrane (CAM) were tested for virus titres and by the precipitation-in-gel (PIG) reaction. They were also tested after exposing them directly to sunlight and after keeping them at temperatures of -20 degrees C, 4 degrees C, and 25 degrees C. It was found that when extracts of fresh specimens were diluted to the point where the PIG reaction became negative there was still a titre of 10(4)-10(5) infectivity in the swab extracts and 10(3)-10(4) infectivity in the scab extracts. It was also found that the PIG reactions were all negative on specimens that were kept for 14 days at 25 degrees C, and that several were negative after only 7 days; the loss in infectivity titre, however, was only slight in all the specimens tested. It is concluded that the laboratory diagnosis of smallpox by virus inoculation of CAM is more reliable than by the PIG test.

Cool-Flame Burning and Oscillations of Envelope Diffusion Flames in Microgravity

NASA Astrophysics Data System (ADS)

Takahashi, Fumiaki; Katta, Viswanath R.; Hicks, Michael C.

2018-05-01

The two-stage combustion, local extinction, and flame-edge oscillations have been observed in single-droplet combustion tests conducted on the International Space Station. To understand such dynamic behavior of initially enveloped diffusion flames in microgravity, two-dimensional (axisymmetric) computation is performed for a gaseous n-heptane flame using a time-dependent code with a detailed reaction mechanism (127 species and 1130 reactions), diffusive transport, and a simple radiation model (for CO2, H2O, CO, CH4, and soot). The calculated combustion characteristics vary profoundly with a slight movement of air surrounding a fuel source. In a near-quiescent environment (≤ 2 mm/s), with a sufficiently large fuel injection velocity (1 cm/s), extinction of a growing spherical diffusion flame due to radiative heat losses is predicted at the flame temperature at ≈ 1200 K. The radiative extinction is typically followed by a transition to the "cool flame" burning regime (due to the negative temperature coefficient in the low-temperature chemistry) with a reaction zone (at ≈ 700 K) in close proximity to the fuel source. By contrast, if there is a slight relative velocity (≈ 3 mm/s) between the fuel source and the air, a local extinction of the envelope diffusion flame is predicted downstream at ≈ 1200 K, followed by periodic flame-edge oscillations. At higher relative velocities (4 to 10 mm/s), the locally extinguished flame becomes steady state. The present 2D computational approach can help in understanding further the non-premixed "cool flame" structure and flame-flow interactions in microgravity environments.

Changes of Climate Extremes in Urmia Lake Basin: Observations and Multimodel Ensemble Projections

NASA Astrophysics Data System (ADS)

Ashraf, B.; AghaKouchak, A.

2017-12-01

This study presents an analysis of the changes in temperature and precipitation extremes in Urmia Lake Basin, in Iran in 21th century. The latest observations in the past three decades and multimodel ensemble projections from eleven General Circulation Models (GCMs) under the three Representative Concentration Pathways (RCPs) 2.6, 4.5 and 8.5 scenarios are employed for analysis in this study. The twenty-seven indicative temperature and precipitation indices recommended by the joint World Meteorological Organization CCL/CLIVAR/JCOMM Expert Team on Climate Change Detection and Indices (ETCCDI) were used for assessing changes in extremes. Results indicate that most warm (cold) extreme temperature indices have shown significantly positive (negative) trends in the Urmia Lake Basin in past three decades, while only slight changes in precipitation extremes can be observed. Ensemble projection from Bayesian Model Averaging (BMA) of Phase 5 of the Coupled Model Intercomparison Project (CMIP5) suggests that the increasing consecutive dry days (CDD), together with the decreasing frost day (FD) and increasing warm nights frequency (TN90) contribute to more frequent/severe droughts in Urmia Lake Basin. Meanwhile, the results show slight increase of annual count of days with precipitation of more than 10 mm (R10), maximum 5-day precipitation total (R5D), simple daily intensity index (SDII), and annual total precipitation with precipitation >95th percentile (R95) in projections. Our finding provides information on how extremes might change in the future from a wide range of scenarios that can potentially be sued for water resource and eco-environmental planning and adaptation strategies.

A Novel Mechanism for the Pathogenesis of Nonmelanoma Skin Cancer Resulting from Early Exposure to Ultraviolet Light

DTIC Science & Technology

2014-09-01

hybrid mice show a large population of cells that fluoresce with Tomato Red and few cells that fluoresce with GFP only or GFP/ Tomato Red double positive...percent of total cells Double Negative GFP Tomato Red Double Positive 15 Figure 3. Fluorescent activated cell sorting (FACS) shows slight...Negative Tomato Red Double Positive 17 Figure 5. Fluorescent activated cell sorting (FACS) shows no K14-GFP expressing cells and slight expression of

Effects of 9-hour time zone changes on fatigue and circadian rhythms of sleep/wake and core temperature

NASA Technical Reports Server (NTRS)

Gander, P. H.; Myhre, G.; Graeber, R. C.; Andersen, H. T.; Lauber, J. K.

1985-01-01

Physiological and psychological disruptions caused by transmeridian flights may affect the ability of flight crews to meet operational demands. To study these effects, 9 Royal Norwegian Airforces P3-Orion crewmembers flew from Norway to California (-9 hr), and back (+9 hr). Rectal temperature, heart rate and wrist activity were recorded every 2 min, fatigue and mood were rated every 2 hr during the waking day, and logs were kept of sleep times and ratings. Subjects also completed 4 personality inventories. The time-zone shifts produced negative changes in mood which persisted longer after westward flights. Sleep quality (subjective and objective) and duration were slightly disrupted (more after eastward flights). The circadian rhythms of sleep/wake and temperature both completed the 9-hr delay by day 5 in California, although temperature adjusted more slowly. The size of the delay shift was significantly correlated with scores on extraversion and achievement need personality scales. Response to the 9-hr advance were more variable. One subject exhibited a 15-hr delay in his temperature rhythm, and an atypical sleep/nap pattern. On average, the sleep/wake cycle (but not the temperature rhythm), completed the 9-hr advance by the end of the study. Both rhythms adapted more slowly after the eastward flight.

Radar stage uncertainty

USGS Publications Warehouse

Fulford, J.M.; Davies, W.J.

2005-01-01

The U.S. Geological Survey is investigating the performance of radars used for stage (or water-level) measurement. This paper presents a comparison of estimated uncertainties and data for radar water-level measurements with float, bubbler, and wire weight water-level measurements. The radar sensor was also temperature-tested in a laboratory. The uncertainty estimates indicate that radar measurements are more accurate than uncorrected pressure sensors at higher water stages, but are less accurate than pressure sensors at low stages. Field data at two sites indicate that radar sensors may have a small negative bias. Comparison of field radar measurements with wire weight measurements found that the radar tends to measure slightly lower values as stage increases. Copyright ASCE 2005.

Assessing vegetation response to climatic variations and human activities: spatiotemporal NDVI variations in the Hexi Corridor and surrounding areas from 2000 to 2010

NASA Astrophysics Data System (ADS)

Guan, Qingyu; Yang, Liqin; Guan, Wenqian; Wang, Feifei; Liu, Zeyu; Xu, Chuanqi

2018-03-01

Vegetation cover is a commonly used indicator for evaluating terrestrial environmental conditions, and for revealing environmental evolution and transitions. Spatiotemporal variations in the vegetation cover of the Hexi Corridor and surrounding areas from 2000 to 2010 were investigated using MODIS NDVI data, and the causes of vegetation cover changes were analyzed, considering both climatic variability and human activities. The vegetation cover of the study area increased during 2000-2010. The greenness of the vegetation showed a significant increase from the northwest to the southeast, which was similar to the spatial distribution of the annual precipitation. Variations in vegetation have a close relationship with those in precipitation within the Qilian Mountains region, but the NDVI is negatively correlated with precipitation in oasis areas. Increasing temperatures led to drought, inhibiting vegetation growth in summer; however, increasing temperatures may have also advanced and prolonged the growing periods in spring and autumn. The NDVI showed a slight degradation in March and July, primarily in the Qilian Mountains, and especially the Wushao Mountains. In March, due to low temperatures, the metabolism rate of vegetation was too slow to enable strong plant growth in high elevations of the Qilian Mountains. In July, increasing temperatures enhanced the intensity of transpiration and decreasing precipitation reduced the moisture available to plants, producing a slight degradation of vegetation in the Qilian Mountains. In May and August, the NDVI showed a significant improvement, primarily in the artificial oases and the Qilian Mountains. Abundant precipitation provided the necessary water for plant growth, and suitable temperatures increased the efficiency of photosynthesis, resulting in a significant improvement of vegetation in the Qilian Mountains. The improvement of production technologies, especially in irrigation, has been beneficial to the growth of vegetation in oasis areas. The implementation of large-scale vegetation management has led to several beneficial effects in the artificial oases and grasslands of the Qilian Mountains. [Figure not available: see fulltext.

Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

USGS Publications Warehouse

Healy, R.W.; DeVries, M.P.; Sturrock, Alex M.

1989-01-01

From July 1982 through June 1984, a study was made of the evapotranspiration and microclimate at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily awnless brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy budget with the Bowen ratio, (2) an aerodynamic profile, and (3) a soil-based water budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data and then summed by days and months. Yearly estimates (for March through November) by these methods were in close agreement: 648 and 626 millimeters, respectively. Daily estimates reach a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of total precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soilmoisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) at the Sheffield site were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately south-southeasterly. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends of evapotranspiration rates mirrored those of net radiation; July was usually the month with the highest evapotranspiration rate. The ratio of sensible- to latentheat fluxes (commonly called the Bowen ratio) for the 2-year study period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by' the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

Geochemical constraints on the origin of Doushantuo cap carbonates in the Yangtze Gorges area, South China

NASA Astrophysics Data System (ADS)

Wang, Qinxian; Lin, Zhijia; Chen, Duofu

2014-05-01

Marinoan cap carbonates have been suggested to be primarily deposited in glacial meltwater and upwelled seawater. However, elemental geochemistry evidence for this depositional model is lacking. Here, we report high-spatial-resolution measurements of major, trace and rare earth elements of the Doushantuo cap carbonates from the Jiulongwan section in the Yangtze Gorges area, South China. Our results show that: 1) the basal cap carbonates display slight MREE enrichment, weak positive La anomalies, near-chondritic Y/Ho ratios, and slight negative Ce anomalies; 2) the lower-middle cap carbonates show slight LREE depletion or MREE enrichment, weak positive La and Eu anomalies, supra-chondritic Y/Ho ratios, and slight negative Ce anomalies; 3) the upper-middle cap carbonates have consistent enrichment of P, Fe, and trace metals, slight LREE depletion, and weak positive Ce, La and Eu anomalies; and 4) the upper cap carbonates exhibit LREE enrichment, weak positive La and Eu anomalies, supra-chondritic Y/Ho ratios, and mild negative Ce anomalies. These findings indicate that the Doushantuo cap carbonates did not precipitate from normal contemporaneous seawater, rather, the basal cap carbonates were deposited in oxygenated, relatively pure deglacial meltwater; the lower-middle cap carbonates in oxygenated brackish water; the upper-middle cap carbonates in upwelled anoxic brine water; and the upper cap carbonates in oxygenated brackish water. Our depositional model is consistent with the proposed sequence of events after the meltdown of Marinoan glaciation by Shields (2005).

The velocity, refractive index, and equation of state of liquid ammonia at high temperatures and high pressures.

PubMed

Li, Fangfei; Li, Min; Cui, Qiliang; Cui, Tian; He, Zhi; Zhou, Qiang; Zou, Guangtian

2009-10-07

The high temperature and high pressure Brillouin scattering studies of liquid ammonia have been performed in a diamond anvil cell. Acoustic velocity, refractive index, adiabatic bulk modulus, and the equation of state of liquid ammonia were determined at temperatures up to 410 K and at pressures up to the solidification point. Velocity and refractive index increase smoothly with increasing pressure along isothermals but decrease slightly with the temperature increase. The bulk modulus increases linearly with pressure and its slope dB/dP decreases slightly with increasing temperature from 6.67 at 297 K to 5.94 at 410 K.

Retrieving air humidity, global solar radiation, and reference evapotranspiration from daily temperatures: development and validation of new methods for Mexico. Part I: humidity

NASA Astrophysics Data System (ADS)

Lobit, P.; López Pérez, L.; Lhomme, J. P.; Gómez Tagle, A.

2017-07-01

This study evaluates the dew point method (Allen et al. 1998) to estimate atmospheric vapor pressure from minimum temperature, and proposes an improved model to estimate it from maximum and minimum temperature. Both methods were evaluated on 786 weather stations in Mexico. The dew point method induced positive bias in dry areas but also negative bias in coastal areas, and its average root mean square error for all evaluated stations was 0.38 kPa. The improved model assumed a bi-linear relation between estimated vapor pressure deficit (difference between saturated vapor pressure at minimum and average temperature) and measured vapor pressure deficit. The parameters of these relations were estimated from historical annual median values of relative humidity. This model removed bias and allowed for a root mean square error of 0.31 kPa. When no historical measurements of relative humidity were available, empirical relations were proposed to estimate it from latitude and altitude, with only a slight degradation on the model accuracy (RMSE = 0.33 kPa, bias = -0.07 kPa). The applicability of the method to other environments is discussed.

Optimization of the extrusion conditions and formulation of spaghetti enriched with full-fat soy flour based on the cooking and color quality.

PubMed

Nasehi, B; Mortazavi, S A; Razavi, S M A; Mahallati, M Nasiri; Karim, R

2009-01-01

The influence of full-fat soy flour (FFSF) 0-27.0 g/100 g, water content 31.0-35.0 g/100 g and extrusion conditions on the cooking and color characteristics of spaghetti was investigated. The process was performed with a speed of 10-40 rpm and a water circulating temperature of 35-70 degrees C. The results showed that adding FFSF causes decreases (P< or =0.05) in cooking time, cooking weight, intensity and hue characteristics. However, the cooking loss and saturation of spaghetti increased (P< or =0.05). The temperature and speed of the extruder had no significant effect on the cooking and color attributes. Interaction between them and the components, however, had a slight synergistic effect on characteristics. Also, interaction between the components and the water temperature has a negative effect on the color and cooking loss. Data analysis showed that the cooking and color characteristics were optimized when 56.9 g/100 g wheat flour, 12.1 g/100 g FFSF and 31.0 g/100 g water content at a screw speed of 40 rpm and a temperature of 35 degrees C were applied.

The solubility of carbon monoxide in silicate melts at high pressures and its effect on silicate phase relations. [in terrestrial and other planetary interiors

NASA Technical Reports Server (NTRS)

Eggler, D. H.; Mysen, B. O.; Hoering, T. C.; Holloway, J. R.

1979-01-01

Autoradiographic analysis and gas chromatography were used to measure the solubility in silicate melts of CO-CO2 vapors (30 to 40% CO by thermodynamic calculation) in equilibrium with graphite at temperatures up to 1700 deg C and pressures to 30 kbar. At near-liquidus temperatures CO-CO2 vapors were found to be slightly more soluble than CO2 alone. As a result of the apparently negative temperature dependence of CO solubility, the solubility of CO-CO2 at superliquidus temperatures is less than that of CO2. Melting points of two silicates were depressed more by CO than by CO2. Phase boundary orientations suggest that CO/CO + CO2 is greater in the liquid than in the vapor. The effect of the presence of CO on periodotite phase relations was investigated, and it was found that melts containing both CO and CO2 are nearly as polymerized as those containing only CO2. These results suggest that crystallization processes in planetary interiors can be expected to be about the same, whether the melts contain CO2 alone or CO2 and CO.

Influence of CoO Nanoparticles on Properties of Barium Zirconium Titanate Ceramics

NASA Astrophysics Data System (ADS)

Jarupoom, Parkpoom; Jaita, Pharatree; Boothrawong, Narongdetch; Phatungthane, Thanatep; Sanjoom, Ratabongkot; Rujijanagul, Gobwute; Cann, David P.

2017-07-01

Composites of Ba(Zr0.07Ti0.93)O3 ceramic and CoO nanoparticles (at 1.0 vol.% to 3.0 vol.%) have been fabricated to investigate the effects of the CoO nanoparticles on the properties of the composites. X-ray diffraction data revealed that the modified samples contained Ba(Zr0.07Ti0.93)O3 and CoO phases. Addition of CoO nanoparticles improved the magnetic behavior and resulted in slight changes in ferroelectric properties. The composites showed a magnetoelectric effect in which the negative value of the magnetocapacitance increased with increasing CoO concentration. Examination of the dielectric spectra showed that the two phase-transition temperatures as observed for unmodified Ba(Zr0.07Ti0.93)O3 merged into a single phase-transition temperature for the composite samples. The composite samples also showed broad relative permittivity versus temperature ( ɛ r - T) curves with frequency dispersion. This dielectric behavior can be explained in terms of the Maxwell-Wagner mechanism. In addition, the Vickers hardness ( H v) value of the samples increased with increasing CoO content.

Effect of simulated climate warming on the morphological and physiological traits of Elsholtzia haichowensis in copper contaminated soil.

PubMed

Guan, Ming; Jin, Zexin; Li, Junmin; Pan, Xiaocui; Wang, Suizi; Li, Yuelin

2016-01-01

The aim of this study was to investigate the effects of temperature and Cu on the morphological and physiological traits of Elsholtzia haichowensis grown in soils amended with four Cu concentrations (0, 50, 500, and 1000 mg kg(-1)) under ambient temperature and slight warming. At the same Cu concentration, the height, shoot dry weight, total plant dry weight, and root morphological parameters such as length, surface area and tip number of E. haichowensis increased due to the slight warming. The net photosynthetic rate, stomatal conductance, transpiration, light use efficiency were also higher under the slight warming than under ambient temperature. The increased Cu concentrations, total Cu uptake, bioaccumulation factors and tolerance indexes of shoots and roots were also observed at the slight warming. The shoot dry weight, root dry weight, total plant dry weight and the bioaccumulation factors of shoots and roots at 50 mg Cu kg(-1) were significantly higher than those at 500 and 1000 mg Cu kg(-1) under the slight warming. Therefore, the climate warming may improve the ability of E. haichowensis to phytoremediate Cu-contaminated soil, and the ability improvement greatly depended on the Cu concentrations in soils.

Full spatial-field visualization of gas temperature in an air micro-glow discharge by calibrated Schlieren photography

NASA Astrophysics Data System (ADS)

Xiong, Qing; Xu, Le; Wang, Xia; Xiong, Lin; Huang, Qinghua; Chen, Qiang; Wang, Jingang; Peng, Wenxiong; Li, Jiarui

2018-03-01

Gas temperature is an important basic parameter for both fundamental research and applications of plasmas. In this work, efforts were made to visualize the full spatial field of gas temperature (T g) in a microdischarge with sharp T g gradients by a method of calibrated Schlieren (CS) photography. Compared to other two typical diagnostic approaches, optical emission spectroscopy (OES) and Rayleigh scattering, the proposed CS method exhibits the ability to capture the whole field of gas temperature using a single Schlieren image, even the discharge is of non-luminous zones like Faraday dark space (FDS). The image shows that the T g field in the studied micro-glow air discharge expands quickly with the increase of discharge currents, especially in the cathode region. The two-dimensional maps of gas temperature display a ‘W-shape’ with sharp gradients in both areas of negative and positive glows, slightly arched distributions in the positive column, and cooling zones in the FDS. The obtained T g fields show similar patterns to that of the discharge luminance. With an increase in discharge currents, more electric energy is dissipated by heating air gas and inducing constriction of the low-temperature FDS. Except in the vicinities of electrode boundaries, due to the interference from optical diffraction, the estimated gas temperature distributions are of acceptable accuracy, confirmed by the approaches of OES and UV Rayleigh scattering.

Study on the interaction of graphene oxide‑silver nanocomposites with bovine serum albumin and the formation of nanoparticle-protein corona.

PubMed

Xu, Xiangyu; Mao, Xuyan; Wang, Yunfei; Li, Dandan; Du, Zhongyu; Wu, Weihua; Jiang, Liang; Yang, Jie; Li, Jianjun

2018-05-09

The interaction between graphene oxide-sliver nanocomposites (GO-AgNCPs) and bovine serum albumin (BSA) in aqueous buffer solution was investigated by using several spectroscopic and imaging techniques. The visible absorbance intensity of GO-AgNCPs increased with increasing concentrations of BSA, and a slight redshift of the surface plasmon resonance band (SPR) occurred due to the absorption of BSA on the surface of GO-AgNCPs. Fluorescence data revealed a static quenching process of BSA caused by GO-AgNCPs. Thermodynamic parameters of the absorption process, including adsorption equilibrium constants, changes in Gibbs free energy (ΔG), enthalpy (ΔH) and entropy (ΔS), were evaluated at different temperatures. Negative values of ΔG showed that this process was spontaneous and the BSA-GO-AgNCPs complex might form in aqueous solution. Negative values of ΔH and ΔS suggested that the binding was mainly an enthalpy-driven process, and van der Waals forces and hydrogen bonding were the major force in the formation of the nanoparticle-protein corona. Analysis of synchronous, three dimensional (3D) fluorescence and circular dichroism (CD) spectra demonstrated that the conformation of BSA was slightly altered in the presence of GO-AgNCPs. The protein corona formed on the surface of GO-AgNCPs was directly observed by scanning probe microscopy (SPM). Copyright © 2018 Elsevier B.V. All rights reserved.

Decontamination of Streptococci biofilms and Bacillus cereus spores on plastic surfaces with DC and pulsed corona discharges

NASA Astrophysics Data System (ADS)

Koval'ová, Zuzana; Tarabová, Kataŕna; Hensel, Karol; Machala, Zdenko

2013-02-01

Cold air plasmas of DC and pulsed corona discharges: positive streamers and negative Trichel pulses were used for bio-decontamination of Streptococci biofilm and Bacillus cereus spores on polypropylene plastic surfaces. The reduction of bacterial population (evaluated as log10) in the biofilm on plastic surfaces treated by DC corona reached 2.4 logs with 10 min treatment time and 3.3 logs with 2 min treatment time with water spraying. The enhancement of plasma biocidal effects on the biofilm by electro-spraying of water through a hollow needle high-voltage electrode was investigated. No significant polarity effect was found with DC corona. Pulsed corona was demonstrated slightly more bactericidal for spores, especially in the negative polarity where the bacterial population reduction reached up to 2.2 logs at 10 min exposure time. Contribution to the Topical Issue "13th International Symposium on High Pressure Low Temperature Plasma Chemistry (Hakone XIII)", Edited by Nicolas Gherardi, Henryca Danuta Stryczewska and Yvan Ségui.

Improved negative ion source

DOEpatents

Delmore, J.E.

1984-05-01

A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reaccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200 to 500/sup 0/C for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

The slightly-enriched spectral shift control reactor. Final report, September 30, 1988--September 30, 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, W.R.; Lee, J.C.; Larsen, E.W.

1991-11-01

An advanced converter reactor design utilizing mechanical spectral shift control rods in a conventional pressurized water reactor configuration is under investigation. The design is based on the principle that a harder spectrum during the early part of the fuel cycle will result in large neutron captures in fertile {sup 238}U, which can then be burned in situ in a softer spectrum later in the cycle. Preliminary design calculations performed during FY 89 showed that the slightly-enriched spectral shift reactor design offers the benefit of substantially increased fuel resource utilization with the proven safety characteristics of the pressurized water reactor technologymore » retained. Optimization of the fuel design and development of fuel management strategies were carried out in FY 90, along with effort to develop and validate neutronic methodology for tight-lattice configurations with hard spectra. During FY 91, the final year of the grant, the final Slightly-Enriched Spectral Shift Reactor (SESSR) design was determined, and reference design analyses were performed for the assemblies as well as the global core configuration, both at the beginning of cycle (BOC) and with depletion. The final SESSR design results in approximately a 20% increase in the utilization of uranium resources, based on equilibrium fuel cycle analyses. Acceptable pin power peaking is obtained with the final core design, with assembly peaking factors equal to less than 1.04 for spectral shift control rods both inserted and withdrawn, and global peaking factors at BOC predicted to be 1.4. In addition, a negative Moderation Temperature Coefficient (MTC) is maintained for BOC, which is difficult to achieve with conventional advanced converter designs based on a closed fuel cycle. The SESSR design avoids the need for burnable poison absorber, although they could be added if desired to increase the cycle length while maintaining a negative MTC.« less

The slightly-enriched spectral shift control reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, W.R.; Lee, J.C.; Larsen, E.W.

1991-11-01

An advanced converter reactor design utilizing mechanical spectral shift control rods in a conventional pressurized water reactor configuration is under investigation. The design is based on the principle that a harder spectrum during the early part of the fuel cycle will result in large neutron captures in fertile {sup 238}U, which can then be burned in situ in a softer spectrum later in the cycle. Preliminary design calculations performed during FY 89 showed that the slightly-enriched spectral shift reactor design offers the benefit of substantially increased fuel resource utilization with the proven safety characteristics of the pressurized water reactor technologymore » retained. Optimization of the fuel design and development of fuel management strategies were carried out in FY 90, along with effort to develop and validate neutronic methodology for tight-lattice configurations with hard spectra. During FY 91, the final year of the grant, the final Slightly-Enriched Spectral Shift Reactor (SESSR) design was determined, and reference design analyses were performed for the assemblies as well as the global core configuration, both at the beginning of cycle (BOC) and with depletion. The final SESSR design results in approximately a 20% increase in the utilization of uranium resources, based on equilibrium fuel cycle analyses. Acceptable pin power peaking is obtained with the final core design, with assembly peaking factors equal to less than 1.04 for spectral shift control rods both inserted and withdrawn, and global peaking factors at BOC predicted to be 1.4. In addition, a negative Moderation Temperature Coefficient (MTC) is maintained for BOC, which is difficult to achieve with conventional advanced converter designs based on a closed fuel cycle. The SESSR design avoids the need for burnable poison absorber, although they could be added if desired to increase the cycle length while maintaining a negative MTC.« less

Experimental investigation of low temperature garnet-melt partitioning in CMASH, with application to subduction zone processes.

NASA Astrophysics Data System (ADS)

Morizet, Y.; Blundy, J.; McDade, P.

2003-04-01

During subduction, the slab undergoes several processes such as dehydration and partial melting at pressures of 2-3 GPa and temperatures of 600-900^oC. Under these conditions, there is little or no distinction between melt and fluid phases (Bureau &Keppler, 1999, EPSL 165, 187-196). To investigate the behaviour of trace elements under these conditions we have carried out partitioning experiments in the system CMASH at 2.2 GPa, 700-920^oC. CMAS starting compositions were doped with trace elements, and loaded together with quartz and water into a Pt capsule, which was in turn contained within a Ni-lined Ti capsule. Run durations were 3-7 days. A run at 810^oC produced euhedral calcic garnet, zoisite, quartz, hydrous melt and tiny clinopyroxene interpreted as quench crystals. LA-ICPMS and SIMS were used to quantify trace element concentrations of the phases. Garnet-melt D's for the HREE decrease from ˜300 for Lu to less than 0.2 for La. DSc and D_V are less than 5, consistent with the large X-site dimension in the garnet. DLi DSr and DBa are considerably less than the adjacent REE. There is a very slight negative partitioning anomaly for Zr and Hf relative to Nd and Sm; DHf is slightly greater than DZr. D_U < DTh, due largely to the oxidizing conditions of the experiment (NNO). The most striking result is very high D's for Nb and Ta: 18±10 and 5.4±1.9 (LA-ICPMS), 25.8±11.9 and 6.6±1.3 (SIMS) for Nb and Ta respectively. These are considerably larger than any previously measured (at much higher temperatures). The observed partitioning behaviour is consistent with the large temperature dependence for DREE proposed by Van Westrenen et al. (2001, Contrib Min Pet, 142, 219-234), and an even larger temperature dependence for DNb and DTa. These preliminary results suggest that garnet (rather than rutile) may play the key role in controlling the Nb and Ta budget of arc magmas and the Nb/Ta ratio of residual eclogites. For example, modelling of eclogite melting, using a N-MORB source and the new D's, shows that a residue with Nb > 2 ppm, 19 < Nb/Ta < 37 (as proposed by Rudnick et al., 2000, Science 287, 278-281), can be produced by ˜30% partial melting. Slightly lower melt fractions (˜15%) reproduce their proposed Nb/La (>1.2).

The health of glaciers: Recent changes in glacier regime

USGS Publications Warehouse

Meier, M.F.; Dyurgerov, M.B.; McCabe, G.J.

2003-01-01

Glacier wastage has been pervasive during the last century; small glaciers and those in marginal environments are disappearing, large mid-latitude glaciers are shrinking slightly, and arctic glaciers are warming. Net mass balances during the last 40 years are predominately negative and both winter and summer balances (accumulation and ablation) and mass turnover are increasing, especially after 1988. Two principal components of winter balance time-series explain about 50% of the variability in the data. Glacier winter balances in north and central Europe correlate with the Arctic Oscillation, and glaciers in western North America correlate with the Southern Oscillation and Northern Hemisphere air temperature. The degree of synchronization for distant glaciers relates to changes in time of atmospheric circulation patterns as well as differing dynamic responses.

Effect of commercial metals (Al, Cu, carbon steel, and Zn) on the oxidation of soy-biodiesel

NASA Astrophysics Data System (ADS)

Díaz-Ballote, L.; Castillo-Atoche, A.; Maldonado, L.; Ruiz-Gómez, M. A.; Hernández, E.

2016-09-01

The effect of aluminum, copper, low carbon steel and zinc on the oxidation of biodiesel derived from soybean oil is studied using residual mass curves from thermogravimetry. Biodiesel is oxidized in the presence and absence of each metal in static conditions and exposed to ambient air. Oxidized biodiesel parameters are confirmed by viscosity measurements, nuclear magnetic resonance and Fourier transform infrared spectroscopy. The results showed that the metals do not negatively influence the oxidative stability of biodiesel and it can even be considered that they slightly inhibit the oxidation process. This behavior was ascribed to a depletion of dissolved oxygen in biodiesel due to oxidation of the metal and the low solubility of oxygen at high temperature.

Clofibric acid degradation in UV254/H2O2 process: effect of temperature.

PubMed

Li, Wenzhen; Lu, Shuguang; Qiu, Zhaofu; Lin, Kuangfei

2010-04-15

The degradation of clofibric acid (CA) in UV(254)/H(2)O(2) process under three temperature ranges, i.e. T1 (9.0-11.5 degrees C), T2 (19.0-21.0 degrees C) and T3 (29.0-30.0 degrees C) was investigated. The effects of solution constituents including NO(3)(-) and HCO(3)(-) anions, and humic acid (HA) on CA degradation were evaluated in Milli-Q waters. CA degradation behaviors were simulated with the pseudo-first-order kinetic model and the apparent rate constant (k(ap)) and half-life time (t(1/2)) were calculated. The results showed that higher temperature would favor CA degradation, and CA degradation was taken place mostly by indirect oxidation through the formation of OH radicals in UV(254)/H(2)O(2) process. In addition, the effects of both NO(3)(-) and HCO(3)(-) anions at two selected concentrations (1.0x10(-3) and 0.1 mol L(-1)) and HA (20 mg L(-1)) on CA degradation were investigated. The results showed that HA had negative effect on CA degradation, and this effect was much more apparent under low temperature condition. On the other hand, the inhibitive effect on CA degradation at both lower and higher concentrations of bicarbonate was observed, and this inhibitive effect was much more apparent at higher bicarbonate concentration and lower temperature condition. While, at higher nitrate concentration the inhibitive effect on CA degradation under three temperature ranges was observed, and with the temperature increase this negative effect was apparently weakened. However, at lower nitrate concentration a slightly positive effect on CA degradation was found under T2 and T3 conditions. Moreover, when using a real wastewater treatment plant (WWTP) effluent spiked with CA over 99% of CA removal could be achieved under 30 degrees C within only 15 min compared with 40 and 80 min under 20 and 10 degrees C respectively, suggesting a significant promotion in CA degradation under higher temperature condition. Therefore, it can be concluded that temperature plays an important role in CA degradation in UV/H(2)O(2) process. 2009 Elsevier B.V. All rights reserved.

Mapping the Baby Universe

NASA Technical Reports Server (NTRS)

Wanjek, Christopher

2003-01-01

In June, NASA plans to launch the Microwave Anisotropy Probe (MAP) to survey the ancient radiation in unprecedented detail. MAP will map slight temperature fluctuations within the microwave background that vary by only 0.00001 C across a chilly radiation that now averages 2.73 C above absolute zero. The temperature differences today point back to density differences in the fiery baby universe, in which there was a little more matter here and a little less matter there. Areas of slightly enhanced density had stronger gravity than low-density areas. The high-density areas pulled back on the background radiation, making it appear slightly cooler in those directions.

Effect of Temperature Reversion on Hot Ductility and Flow Stress-Strain Curves of C-Mn Continuously Cast Steels

NASA Astrophysics Data System (ADS)

Dong, Zhihua; Li, Wei; Long, Mujun; Gui, Lintao; Chen, Dengfu; Huang, Yunwei; Vitos, Levente

2015-08-01

The influence of temperature reversion in secondary cooling and its reversion rate on hot ductility and flow stress-strain curve of C-Mn steel has been investigated. Tensile specimens were cooled at various regimes. One cooling regime involved cooling at a constant rate of 100 °C min-1 to the test temperature, while the others involved temperature reversion processes at three different reversion rates before deformation. After hot tensile test, the evolution of mechanical properties of steel was analyzed at various scales by means of microstructure observation, ab initio prediction, and thermodynamic calculation. Results indicated that the temperature reversion in secondary cooling led to hot ductility trough occurring at higher temperature with greater depth. With increasing temperature reversion rate, the low temperature end of ductility trough extended toward lower temperature, leading to wider hot ductility trough with slightly reducing depth. Microstructure examinations indicated that the intergranular fracture related to the thin film-like ferrite and (Fe,Mn)S particles did not changed with varying cooling regimes; however, the Widmanstatten ferrite surrounding austenite grains resulted from the temperature reversion process seriously deteriorated the ductility. In addition, after the temperature reversion in secondary cooling, the peak stress on the flow curve slightly declined and the peak of strain to peak stress occurred at higher temperature. With increasing temperature reversion rate, the strain to peak stress slightly increased, while the peak stress showed little variation. The evolution of plastic modulus and strain to peak stress of austenite with varying temperature was in line with the theoretical prediction on Fe.

Feasibility of leakage detection in lake pressure pipes using the Distributed Temperature Sensing Technology

NASA Astrophysics Data System (ADS)

Apperl, Benjamin; Pressl, Alexander; Schulz, Karsten

2016-04-01

This contribution describes a feasibility study carried out in the laboratory for the detection of leakages in lake pressure pipes using high-resolution fiber-optic temperature measurements (DTS). The usage of the DTS technology provides spatiotemporal high-resolution temperature measurements along a fibre optic cable. An opto-electrical device serves both as a light emitter as well as a spectrometer for measuring the scattering of light. The fiber optic cable serves as linear sensor. Measurements can be taken at a spatial resolution of up to 25 cm with a temperature accuracy of higher than 0.1 °C. The first warmer days after the winter stagnation provoke a temperature rise of superficial layers of lakes with barely stable temperature stratification. The warmer layer in the epilimnion differs 4 °C to 5 °C compared to the cold layers in the meta- or hypolimnion before water circulation in spring starts. The warmer water from the surface layer can be rinsed on the entire length of the pipe. Water intrudes at leakages by generating a slightly negative pressure in the pipe. This provokes a local temperature change, in case that the penetrating water (seawater) differs in temperature from the water pumped through the pipe. These temperature changes should be detectable and localized with a DTS cable introduced in the pipe. A laboratory experiment was carried out to determine feasibility as well as limits and problems of this methodology. A 6 m long pipe, submerged in a water tank at constant temperature, was rinsed with water 5-10 °C warmer than the water in the tank. Temperature measurements were taken continuously along the pipe. A negative pressure of 0.1 bar provoked the intrusion of colder water from the tank into the pipe through the leakages, resulting in local temperature changes. Experiments where conducted with different temperature gradients, leakage sizes, number of leaks as well as with different positioning of the DTS cable inside the pipe. Results showed that already small leakages (4mm) can be detected. Problems have arisen from the inside positioning of DTS cable, measuring a reduced temperature difference in the transition layer at the inside wall of the pipe.

Service temperature study for asphaltic concrete.

DOT National Transportation Integrated Search

1964-10-01

The Service Temperature Study was undertaken to supplement a pilot study started in 1959 which indicated that service temperatures obtained on Louisiana highways are slightly higher than those used for testing purposes. : Temperature recorders were i...

Sensitivity of glacier mass balance and equilibrium line altitude to climatic change on King George Island, Antarctic Peninsula.

NASA Astrophysics Data System (ADS)

Falk, Ulrike; Lopez, Damian; Silva-Busso, Adrian

2017-04-01

The South Shetland Islands are located at the northern tip of the Antarctic Peninsula which is among the fastest warming regions on Earth. Surface air temperature increases (ca. 3 K in 50 years) are concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K/100 m), and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns especially during winter glacial mass accumulation periods. The increased mesocyclonic activity during the winter time in the study area results in intensified advection of warm, moist air with high temperatures and rain, and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. The impact on winter accumulation results in even more negative mass balance estimates. Six years of glaciological measurements on mass balance stake transects are used with a glacier melt model to assess changes in melt water input to the coastal waters, glacier surface mass balance and the equilibrium line altitude. The average equilibrium line altitude (ELA) calculated from own glaciological observations for KGI over the time period 2010 - 2015 amounts to ELA=330±100 m. Published studies suggest rather stable condition slightly negative glacier mass balance until the mid 80's with an ELA of approx. 150 m. The calculated accumulation area ratio suggests rather dramatic changes in extension of the inland ice cap for the South Shetland Islands until an equilibrium with concurrent climate conditions is reached.

Surface sulfonamide modification of poly(N-isopropylacrylamide)-based block copolymer micelles to alter pH and temperature responsive properties for controlled intracellular uptake.

PubMed

Cyphert, Erika L; von Recum, Horst A; Yamato, Masayuki; Nakayama, Masamichi

2018-06-01

Two different surface sulfonamide-functionalized poly(N-isopropylacrylamide)-based polymeric micelles were designed as pH-/temperature-responsive vehicles. Both sulfadimethoxine- and sulfamethazine-surface functionalized micelles were characterized to determine physicochemical properties, hydrodynamic diameters, zeta potentials, temperature-dependent size changes, and lower critical solution temperatures (LCST) in both pH 7.4 and 6.8 solutions (simulating both physiological and mild low pH conditions), and tested in the incorporation of a proof-of-concept hydrophobic antiproliferative drug, paclitaxel. Cellular uptake studies were conducted using bovine carotid endothelial cells and fluorescently labeled micelles to evaluate if there was enhanced cellular uptake of the micelles in a low pH environment. Both variations of micelles showed enhanced intracellular uptake under mildly acidic (pH 6.8) conditions at temperatures slightly above their LCST and minimal uptake at physiological (pH 7.4) conditions. Due to the less negative zeta potential of the sulfamethazine-surface micelles compared to sulfadimethoxine-surface micelles, and the proximity of their LCST to physiological temperature (37°C), the sulfamethazine variation was deemed more amenable for clinically relevant temperature and pH-stimulated applications. Nevertheless, we believe both polymeric micelle variations have the capacity to be implemented as an intracellular drug or gene delivery system in response to mildly acidic conditions. © 2018 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 106A: 1552-1560, 2018. © 2018 Wiley Periodicals, Inc.

Temperature-induced sol-gel transition and microgel formation in α-actinin cross-linked actin networks: A rheological study

NASA Astrophysics Data System (ADS)

Tempel, M.; Isenberg, G.; Sackmann, E.

1996-08-01

We have studied the sol-gel transition, the viscoelastic and the structural properties of networks constituted of semiflexible actin filaments cross-linked by α-actinin. Cross-linking was regulated in a reversible way by varying the temperature through the association-dissociation equilibrium of the actin-α-actinin system. Viscoelastic parameters [shear storage modulus G'(ω), phase shift tan(Φ)(ω), creep compliance J(t)] were measured as a function of temperature and actin-to-cross-linker ratio by a magnetically driven rotating disc rheometer. G'(ω) and tan(Φ)(ω) were studied at a frequency ω corresponding to the elastic plateau regime of the G'(ω) versus ω spectrum of the purely entangled solution. The microstructure of the networks was viewed by negative staining electron microscopy (EM). The phase shift tan(Φ) (or equivalently the viscosity η) diverges and reaches a maximum when approaching the apparent gel point from lower and higher temperatures, and the maximum defines the gel point (temperature Tg). The elastic plateau modulus G'N diverges at temperatures beyond this gel point TTg. The cross-linking transition (corresponding to a sol-gel transition at zero frequency) is interpreted in terms of a percolation model and the divergence of G'N at TTg), (2) that microscopic segregation takes place at T<=Tg leading to local formation of clusters (a state termed microgel), and (3) that at low actin-α-actinin ratios (rAα<=10) and low temperatures (T<=10 °C) macroscopic segregation into bundles of cross-linked actin filaments and a diluted solution of actin filaments is observed. The three regimes of network structure are represented by an equivalent phase diagram.

Predictions of thermal buckling strengths of hypersonic aircraft sandwich panels using minimum potential energy and finite element methods

NASA Technical Reports Server (NTRS)

Ko, William L.

1995-01-01

Thermal buckling characteristics of hypersonic aircraft sandwich panels of various aspect ratios were investigated. The panel is fastened at its four edges to the substructures under four different edge conditions and is subjected to uniform temperature loading. Minimum potential energy theory and finite element methods were used to calculate the panel buckling temperatures. The two methods gave fairly close buckling temperatures. However, the finite element method gave slightly lower buckling temperatures than those given by the minimum potential energy theory. The reasons for this slight discrepancy in eigensolutions are discussed in detail. In addition, the effect of eigenshifting on the eigenvalue convergence rate is discussed.

Reaction CH3 + OH studied over the 294-714 K temperature and 1-100 bar pressure ranges.

PubMed

Sangwan, Manuvesh; Chesnokov, Evgeni N; Krasnoperov, Lev N

2012-08-30

Reaction of methyl radicals with hydroxyl radicals, CH(3) + OH → products (1) was studied using pulsed laser photolysis coupled to transient UV-vis absorption spectroscopy over the 294-714 K temperature and 1-100 bar pressure ranges (bath gas He). Methyl radicals were produced by photolysis of acetone at 193.3 nm. Hydroxyl radicals were generated in reaction of electronically excited oxygen atoms O((1)D), produced in the photolysis of N(2)O at 193.3 nm, with H(2)O. Temporal profiles of CH(3) were recorded via absorption at 216.4 nm using xenon arc lamp and a spectrograph; OH radicals were monitored via transient absorption of light from a dc discharge H(2)O/Ar low pressure resonance lamp at ca. 308 nm. The absolute intensity of the photolysis light inside the reactor was determined by an accurate in situ actinometry based on the ozone formation in the presence of molecular oxygen. The results of this study indicate that the rate constant of reaction 1 is pressure independent within the studied pressure and temperature ranges and has slight negative temperature dependence, k(1) = (1.20 ± 0.20) × 10(-10)(T/300)(-0.49) cm(3) molecule(-1) s(-1).

Case of Mycobacterium tuberculosis meningitis: Gram staining as a useful initial diagnostic clue for tuberculous meningitis.

PubMed

Kawakami, Sayoko; Kawamura, Yasuyosi; Nishiyama, Kyouhei; Hatanaka, Hiroki; Fujisaki, Ryuichi; Ono, Yasuo; Miyazawa, Yukihisa; Nishiya, Hajime

2012-12-01

A 32-year-old man was admitted to our hospital because of fever, headache, and loss of consciousness. Four days before admission, he had had difficulty speaking. On the day of admission, his colleague had found him to be unconscious and lying on his back. He was admitted to our hospital. The temperature at the eardrum was 35.2°C. Neurologic evaluation was negative. Computed tomography (CT) scan of the brain showed slight ventricular enlargement bilaterally. An X-ray film of the chest showed no abnormality. On the second hospital day, neck stiffness was noted. The cerebrospinal fluid (CSF) contained 870 white cells/μl, most of which were neutrophils; the glucose level in the CSF was 10 mg/dl, and the protein level was 140 mg/dl. Stained smears of the CSF, including Gram staining and India-ink preparations, disclosed no microorganisms. Capsular antigen tests for several bacteria were negative. Antimicrobial agents were started. However, by changing the microscope focus slightly while viewing Gram stains of the CSF, we could see brightened and Gram-positive bacilli that had been phagocytosed by neutrophils. This finding suggested the presence of Mycobacterium tuberculosis. Ziehl-Neelsen staining of the CSF and gastric juice revealed anti-acid bacilli. Polymerase chain reaction for M. tuberculosis in the gastric juice was positive. This case showed that Gram staining could be useful as an initial adjunct for the diagnosis of tuberculous meningitis, particularly when the CSF shows predominantly neutrocytic pleocytosis, but no other evidence of bacterial meningitis.

Cloud Tolerance of Remote-Sensing Technologies to Measure Land Surface Temperature

NASA Technical Reports Server (NTRS)

Holmes, Thomas R. H.; Hain, Christopher R.; Anderson, Martha C.; Crow, Wade T.

2016-01-01

Conventional methods to estimate land surface temperature (LST) from space rely on the thermal infrared(TIR) spectral window and is limited to cloud-free scenes. To also provide LST estimates during periods with clouds, a new method was developed to estimate LST based on passive microwave(MW) observations. The MW-LST product is informed by six polar-orbiting satellites to create a global record with up to eight observations per day for each 0.25resolution grid box. For days with sufficient observations, a continuous diurnal temperature cycle (DTC) was fitted. The main characteristics of the DTC were scaled to match those of a geostationary TIR-LST product. This paper tests the cloud tolerance of the MW-LST product. In particular, we demonstrate its stable performance with respect to flux tower observation sites (four in Europe and nine in the United States), over a range of cloudiness conditions up to heavily overcast skies. The results show that TIR based LST has slightly better performance than MW-LST for clear-sky observations but suffers an increasing negative bias as cloud cover increases. This negative bias is caused by incomplete masking of cloud-covered areas within the TIR scene that affects many applications of TIR-LST. In contrast, for MW-LST we find no direct impact of clouds on its accuracy and bias. MW-LST can therefore be used to improve TIR cloud screening. Moreover, the ability to provide LST estimates for cloud-covered surfaces can help expand current clear-sky-only satellite retrieval products to all-weather applications.

Assessing non-linear variation of temperature and precipitation for different growth periods of maize and their impacts on phenology in the Midwest of Jilin Province, China

NASA Astrophysics Data System (ADS)

Guo, Enliang; Zhang, Jiquan; Wang, Yongfang; Alu, Si; Wang, Rui; Li, Danjun; Ha, Si

2018-05-01

In the past two decades, the regional climate in China has undergone significant change, resulting in crop yield reduction and complete failure. The goal of this study is to detect the variation of temperature and precipitation for different growth periods of maize and assess their impact on phenology. The daily meteorological data in the Midwest of Jilin Province during 1960-2014 were used in the study. The ensemble empirical mode decomposition method was adopted to analyze the non-linear trend and fluctuation in temperature and precipitation, and the sensitivity of the length of the maize growth period to temperature and precipitation was analyzed by the wavelet cross-transformation method. The results show that the trends of temperature and precipitation change are non-linear for different growth periods of maize, and the average temperature in the sowing-jointing stage was different from that in the other growth stages, showing a slight decrease trend, while the variation amplitude of maximum temperature is smaller than that of the minimum temperature. This indicates that the temperature difference between day and night shows a gradually decreasing trend. Precipitation in the growth period also showed a decreasing non-linear trend, while the inter-annual variability with period of quasi-3-year and quasi-6-year dominated the variation of temperature and precipitation. The whole growth period was shortened by 10.7 days, and the sowing date was advanced by approximately 11 days. We also found that there was a significant resonance period among temperature, precipitation, and phenology. Overall, a negative correlation between phenology and temperature is evident, while a positive correlation with precipitation is exhibited. The results illustrate that the climate suitability for maize has reduced over the past decades.

Electronic and chemical structure of the H 2O/GaN(0001) interface under ambient conditions

DOE PAGES

Zhang, Xueqiang; Ptasinska, Sylwia

2016-04-25

We employed ambient pressure X-ray photoelectron spectroscopy to investigate the electronic and chemical properties of the H 2O/GaN(0001) interface under elevated pressures and/or temperatures. A pristine GaN(0001) surface exhibited upward band bending, which was partially flattened when exposed to H 2O at room temperature. However, the GaN surface work function was slightly reduced due to the adsorption of molecular H 2O and its dissociation products. At elevated temperatures, a negative charge generated on the surface by a vigorous H 2O/GaN interfacial chemistry induced an increase in both the surface work function and upward band bending. We tracked the dissociative adsorptionmore » of H 2O onto the GaN(0001) surface by recording the core-level photoemission spectra and obtained the electronic and chemical properties at the H 2O/GaN interface under operando conditions. In conclusion, our results suggest a strong correlation between the electronic and chemical properties of the material surface, and we expect that their evolutions lead to significantly different properties at the electrolyte/ electrode interface in a photoelectrochemical solar cell.« less

Dynamic and static initialization of a mesoscale model using VAS satellite data. M.S. Thesis

NASA Technical Reports Server (NTRS)

Beauchamp, James G.

1985-01-01

Various combinations of temperature and moisture data from the VISSR Atmospheric Sounder (VAS), conventional radiosonde data, and National Meteorological Center (NMC) global analysis, were used in a successive-correction type of objective-analysis procedure to produce analyses for 1200 GMT. The NMC global analyses served as the first-guess field for all of the objective analysis procedures. The first-guess field was enhanced by radiosonde data alone, VAS data alone, both radiosonde and VAS data, or by neither data source. In addition, two objective analyses were used in a dynamic initialization: one included only radiosonde data and the other used both radiosonde and VAS data. The dependence of 12 hour forecast skill on data type and the methods by which the data were used in the analysis/initialization were then investigated. This was done by comparison of forecast and observed fields, of sea-level pressure, temperature, wind, moisture, and accumulated precipitation. The use of VAS data in the initial conditions had a slight positive impact upon forecast temperature and moisture but a negative impact upon forecast wind. This was true for both the static and dynamic initialization experiments. Precipitation forecasts from all of the model simulations were nearly the same.

Unrealized Global Temperature Increase: Implications of Current Uncertainties

NASA Astrophysics Data System (ADS)

Schwartz, Stephen E.

2018-04-01

Unrealized increase in global mean surface air temperature (GMST) may result from the climate system not being in steady state with forcings and/or from cessation of negative aerosol forcing that would result from decreases in emissions. An observation-constrained method is applied to infer the dependence of Earth's climate sensitivity on forcing by anthropogenic aerosols within the uncertainty on that forcing given by the Fifth (2013) Assessment Report of the Intergovernmental Panel on Climate Change. Within these uncertainty ranges the increase in GMST due to temperature lag for future forcings held constant is slight (0.09-0.19 K over 20 years; 0.12-0.26 K over 100 years). However, the incremental increase in GMST that would result from a hypothetical abrupt cessation of sources of aerosols could be quite large but is highly uncertain, 0.1-1.3 K over 20 years. Decrease in CO2 abundance and forcing following abrupt cessation of emissions would offset these increases in GMST over 100 years by as little as 0.09 K to as much as 0.8 K. The uncertainties quantified here greatly limit confidence in projections of change in GMST that would result from any strategy for future reduction of emissions.

Improvement in low-temperature and instantaneous high-rate output performance of Al-free AB5-type hydrogen storage alloy for negative electrode in Ni/MH battery: Effect of thermodynamic and kinetic regulation via partial Mn substituting

NASA Astrophysics Data System (ADS)

Zhou, Wanhai; Zhu, Ding; Tang, Zhengyao; Wu, Chaoling; Huang, Liwu; Ma, Zhewen; Chen, Yungui

2017-03-01

A series of Al-free Mn-modified AB5-type hydrogen storage alloys have been designed and the effects of thermodynamic stability and electrochemical kinetics on electrochemical performance via Mn substituting have been investigated. Compared with high-Al alloys, the Al-free alloys in this study have better low-temperature performance and instantaneous high-rate output because of the higher surface catalytic ability. After partial substitution of Ni by Mn, both the hydrogen desorption capacity and plateau pressure decrease, and correspondingly results in an improved thermodynamic stability which is adverse to low-temperature delivery. Additionally, with the improvement of charge acceptance ability and anti-corrosion property via Mn substitution, the room-temperature discharge capacity and cycling stability increase slightly. However, Mn adversely affects the electrochemical kinetics and deteriorates both the surface catalytic ability and the bulk hydrogen diffusion ability, leading to the drop of low-temperature dischargeability, high-rate dischargeability and peak power (Ppeak). Based on the thermodynamic and kinetic regulation and overall electrochemical properties, the optimal composition is obtained when x = 0.2, the discharge capacity is 243.6 mAh g-1 at -40 °C with 60 mA g-1, and the Ppeak attains to 969.6 W kg-1 at -40 °C.

Variability of Antarctic Sea Ice 1979-1998

NASA Technical Reports Server (NTRS)

Zwally, H. Jay; Comiso, Josefino C.; Parkinson, Claire L.; Cavalieri, Donald J.; Gloersen, Per; Koblinsky, Chester J. (Technical Monitor)

2001-01-01

The principal characteristics of the variability of Antarctic sea ice cover as previously described from satellite passive-microwave observations are also evident in a systematically-calibrated and analyzed data set for 20.2 years (1979-1998). The total Antarctic sea ice extent (concentration > 15 %) increased by 13,440 +/- 4180 sq km/year (+1.18 +/- 0.37%/decade). The area of sea ice within the extent boundary increased by 16,960 +/- 3,840 sq km/year (+1.96 +/- 0.44%/decade). Regionally, the trends in extent are positive in the Weddell Sea (1.5 +/- 0.9%/decade), Pacific Ocean (2.4 +/- 1.4%/decade), and Ross (6.9 +/- 1.1 %/decade) sectors, slightly negative in the Indian Ocean (-1.5 +/- 1.8%/decade, and strongly negative in the Bellingshausen-Amundsen Seas sector (-9.5 +/- 1.5%/decade). For the entire ice pack, small ice increases occur in all seasons with the largest increase during autumn. On a regional basis, the trends differ season to season. During summer and fall, the trends are positive or near zero in all sectors except the Bellingshausen-Amundsen Seas sector. During winter and spring, the trends are negative or near zero in all sectors except the Ross Sea, which has positive trends in all seasons. Components of interannual variability with periods of about 3 to 5 years are regionally large, but tend to counterbalance each other in the total ice pack. The interannual variability of the annual mean sea-ice extent is only 1.6% overall, compared to 5% to 9% in each of five regional sectors. Analysis of the relation between regional sea ice extents and spatially-averaged surface temperatures over the ice pack gives an overall sensitivity between winter ice cover and temperature of -0.7% change in sea ice extent per K. For summer, some regional ice extents vary positively with temperature and others negatively. The observed increase in Antarctic sea ice cover is counter to the observed decreases in the Arctic. It is also qualitatively consistent with the counterintuitive prediction of a global atmospheric-ocean model of increasing sea ice around Antarctica with climate warming due to the stabilizing effects of increased snowfall on the Southern Ocean.

Valence of physical stimuli, not housing conditions, affects behaviour and frontal cortical brain activity in sheep.

PubMed

Vögeli, Sabine; Lutz, Janika; Wolf, Martin; Wechsler, Beat; Gygax, Lorenz

2014-07-01

Modulation of short-term emotions by long-term mood is little understood but relevant to understand the affective system and of importance in respect to animal welfare: a negative mood might taint experiences, whilst a positive mood might alleviate single negative events. To induce different mood states in sheep housing conditions were varied. Fourteen ewes were group-housed in an unpredictable, stimulus-poor and 15 ewes in a predictable, stimulus-rich environment. Sheep were tested individually for mood in a behavioural cognitive bias paradigm. Also, their reactions to three physical stimuli thought to differ in their perceived valence were observed (negative: pricking, intermediate: slight pressure, positive: kneading). General behaviour, activity, ear movements and positions, and haemodynamic changes in the cortical brain were recorded during stimulations. Generalised mixed-effects models and model probabilities based on the BIC (Bayesian information criterion) were used. Only weak evidence for mood difference was found. Sheep from the unpredictable, stimulus-poor housing condition had a somewhat more negative cognitive bias, showed slightly more aversive behaviour, were slightly more active and moved their ears somewhat more. Sheep most clearly differentiated the negative from the intermediate and positive stimulus in that they exhibited more aversive behaviour, less nibbling, were more active, showed more ear movements, more forward ear postures, fewer backward ear postures, and a stronger decrease in deoxyhaemoglobin when subjected to the negative stimulus. In conclusion, sheep reacted towards stimuli according to their presumed valence but their mood was not strongly influenced by housing conditions. Therefore, behavioural reactions and cortical brain activity towards the stimuli were hardly modulated by housing conditions. Copyright © 2014 Elsevier B.V. All rights reserved.

Measurement of gas species, temperatures, coal burnout, and wall heat fluxes in a 200 MWe lignite-fired boiler with different overfire air damper openings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jianping Jing; Zhengqi Li; Guangkui Liu

Measurements were performed on a 200 MWe, wall-fired, lignite utility boiler. For different overfire air (OFA) damper openings, the gas temperature, gas species concentration, coal burnout, release rates of components (C, H, and N), furnace temperature, and heat flux and boiler efficiency were measured. Cold air experiments for a single burner were conducted in the laboratory. The double-swirl flow pulverized-coal burner has two ring recirculation zones starting in the secondary air region in the burner. As the secondary air flow increases, the axial velocity of air flow increases, the maxima of radial velocity, tangential velocity and turbulence intensity all increase,more » and the swirl intensity of air flow and the size of recirculation zones increase slightly. In the central region of the burner, as the OFA damper opening widens, the gas temperature and CO concentration increase, while the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and coal particles ignite earlier. In the secondary air region of the burner, the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and the gas temperature and CO concentration vary slightly. In the sidewall region, the gas temperature, O{sub 2} concentration, and NOx concentration decrease, while the CO concentration increases and the gas temperature varies slightly. The furnace temperature and heat flux in the main burning region decrease appreciably, but increase slightly in the burnout region. The NOx emission decreases from 1203.6 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 0% to 511.7 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 80% and the boiler efficiency decreases from 92.59 to 91.9%. 15 refs., 17 figs., 3 tabs.« less

Fabrication and characterization of electrospun poly(e-caprolactone) fibrous membrane with antibacterial functionality

NASA Astrophysics Data System (ADS)

Cerkez, Idris; Sezer, Ayse; Bhullar, Sukhwinder K.

2017-02-01

This research study is mainly targeted on fabrication and characterization of antibacterial poly(e-caprolactone) (PCL) based fibrous membrane containing silver chloride particles. Micro/nano fibres were produced by electrospinning and characterized with TGA, DSC, SEM and mechanical analysis. It was found that addition of silver particles slightly reduced onset of thermal degradation and increased crystallization temperature of neat PCL. Silver-loaded samples exhibited higher tensile stress and lower strain revealing that the particles behaved as reinforcing agent. Moreover, addition of silver chloride resulted in beaded surface texture and formation of finer fibres as opposed to the neat. Antibacterial properties were tested against Gram-negative and Gram-positive bacteria and remarkable biocidal functionalities were obtained with about six logs reduction of Staphylococcus aureus and Escherichia coli O157:H7.

40 CFR 60.386 - Test methods and procedures.

Code of Federal Regulations, 2010 CFR

2010-07-01

.... The sample volume for each run shall be at least 1.70 dscm (60 dscf). The sampling probe and filter... probe and filter temperature slightly above the effluent temperature (up to a maximum filter temperature...

40 CFR 60.386 - Test methods and procedures.

Code of Federal Regulations, 2014 CFR

2014-07-01

.... The sample volume for each run shall be at least 1.70 dscm (60 dscf). The sampling probe and filter... probe and filter temperature slightly above the effluent temperature (up to a maximum filter temperature...

40 CFR 60.386 - Test methods and procedures.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... The sample volume for each run shall be at least 1.70 dscm (60 dscf). The sampling probe and filter... probe and filter temperature slightly above the effluent temperature (up to a maximum filter temperature...

40 CFR 60.386 - Test methods and procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

.... The sample volume for each run shall be at least 1.70 dscm (60 dscf). The sampling probe and filter... probe and filter temperature slightly above the effluent temperature (up to a maximum filter temperature...

Passive Safety Features Evaluation of KIPT Neutron Source Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhong, Zhaopeng; Gohar, Yousry

2016-06-01

Argonne National Laboratory (ANL) of the United States and Kharkov Institute of Physics and Technology (KIPT) of Ukraine have cooperated on the development, design, and construction of a neutron source facility. The facility was constructed at Kharkov, Ukraine and its commissioning process is underway. It will be used to conduct basic and applied nuclear research, produce medical isotopes, and train young nuclear specialists. The facility has an electron accelerator-driven subcritical assembly. The electron beam power is 100 kW using 100 MeV electrons. Tungsten or natural uranium is the target material for generating neutrons driving the subcritical assembly. The subcritical assemblymore » is composed of WWR-M2 - Russian fuel assemblies with U-235 enrichment of 19.7 wt%, surrounded by beryllium reflector assembles and graphite blocks. The subcritical assembly is seated in a water tank, which is a part of the primary cooling loop. During normal operation, the water coolant operates at room temperature and the total facility power is ~300 KW. The passive safety features of the facility are discussed in in this study. Monte Carlo computer code MCNPX was utilized in the analyses with ENDF/B-VII.0 nuclear data libraries. Negative reactivity temperature feedback was consistently observed, which is important for the facility safety performance. Due to the design of WWR-M2 fuel assemblies, slight water temperature increase and the corresponding water density decrease produce large reactivity drop, which offset the reactivity gain by mistakenly loading an additional fuel assembly. The increase of fuel temperature also causes sufficiently large reactivity decrease. This enhances the facility safety performance because fuel temperature increase provides prompt negative reactivity feedback. The reactivity variation due to an empty fuel position filled by water during the fuel loading process is examined. Also, the loading mistakes of removing beryllium reflector assemblies and replacing them with dummy assemblies were analyzed. In all these circumstances, the reactivity change results do not cause any safety concerns.« less

Ocean acidification exerts negative effects during warming conditions in a developing Antarctic fish

PubMed Central

Flynn, Erin E; Bjelde, Brittany E; Miller, Nathan A

2015-01-01

Abstract Anthropogenic CO2 is rapidly causing oceans to become warmer and more acidic, challenging marine ectotherms to respond to simultaneous changes in their environment. While recent work has highlighted that marine fishes, particularly during early development, can be vulnerable to ocean acidification, we lack an understanding of how life-history strategies, ecosystems and concurrent ocean warming interplay with interspecific susceptibility. To address the effects of multiple ocean changes on cold-adapted, slowly developing fishes, we investigated the interactive effects of elevated partial pressure of carbon dioxide (pCO2) and temperature on the embryonic physiology of an Antarctic dragonfish (Gymnodraco acuticeps), with protracted embryogenesis (∼10 months). Using an integrative, experimental approach, our research examined the impacts of near-future warming [−1 (ambient) and 2°C (+3°C)] and ocean acidification [420 (ambient), 650 (moderate) and 1000 μatm pCO2 (high)] on survival, development and metabolic processes over the course of 3 weeks in early development. In the presence of increased pCO2 alone, embryonic mortality did not increase, with greatest overall survival at the highest pCO2. Furthermore, embryos were significantly more likely to be at a later developmental stage at high pCO2 by 3 weeks relative to ambient pCO2. However, in combined warming and ocean acidification scenarios, dragonfish embryos experienced a dose-dependent, synergistic decrease in survival and developed more slowly. We also found significant interactions between temperature, pCO2 and time in aerobic enzyme activity (citrate synthase). Increased temperature alone increased whole-organism metabolic rate (O2 consumption) and developmental rate and slightly decreased osmolality at the cost of increased mortality. Our findings suggest that developing dragonfish are more sensitive to ocean warming and may experience negative physiological effects of ocean acidification only in the presence of an increased temperature. In addition to reduced hatching success, alterations in development and metabolism due to ocean warming and acidification could have negative ecological consequences owing to changes in phenology (i.e. early hatching) in the highly seasonal Antarctic ecosystem. PMID:27293718

Ocean acidification exerts negative effects during warming conditions in a developing Antarctic fish.

PubMed

Flynn, Erin E; Bjelde, Brittany E; Miller, Nathan A; Todgham, Anne E

2015-01-01

Anthropogenic CO2 is rapidly causing oceans to become warmer and more acidic, challenging marine ectotherms to respond to simultaneous changes in their environment. While recent work has highlighted that marine fishes, particularly during early development, can be vulnerable to ocean acidification, we lack an understanding of how life-history strategies, ecosystems and concurrent ocean warming interplay with interspecific susceptibility. To address the effects of multiple ocean changes on cold-adapted, slowly developing fishes, we investigated the interactive effects of elevated partial pressure of carbon dioxide (pCO2) and temperature on the embryonic physiology of an Antarctic dragonfish (Gymnodraco acuticeps), with protracted embryogenesis (∼10 months). Using an integrative, experimental approach, our research examined the impacts of near-future warming [-1 (ambient) and 2°C (+3°C)] and ocean acidification [420 (ambient), 650 (moderate) and 1000 μatm pCO2 (high)] on survival, development and metabolic processes over the course of 3 weeks in early development. In the presence of increased pCO2 alone, embryonic mortality did not increase, with greatest overall survival at the highest pCO2. Furthermore, embryos were significantly more likely to be at a later developmental stage at high pCO2 by 3 weeks relative to ambient pCO2. However, in combined warming and ocean acidification scenarios, dragonfish embryos experienced a dose-dependent, synergistic decrease in survival and developed more slowly. We also found significant interactions between temperature, pCO2 and time in aerobic enzyme activity (citrate synthase). Increased temperature alone increased whole-organism metabolic rate (O2 consumption) and developmental rate and slightly decreased osmolality at the cost of increased mortality. Our findings suggest that developing dragonfish are more sensitive to ocean warming and may experience negative physiological effects of ocean acidification only in the presence of an increased temperature. In addition to reduced hatching success, alterations in development and metabolism due to ocean warming and acidification could have negative ecological consequences owing to changes in phenology (i.e. early hatching) in the highly seasonal Antarctic ecosystem.

The Effects of Glacial and Oceanic Advection on Spatial Patterns of Freshwater Contents and Temperatures of Small Fjords and Major Basins in Prince William Sound, Alaska

NASA Astrophysics Data System (ADS)

Gay, S. M., III

2016-02-01

Using spatial principal component (PC) analysis, the variation in freshwater contents and temperatures in the upper 100m are quantified for small fjords and primary basins within Prince William Sound, Alaska. Two EOF modes explain over 90% of the variance in the freshwater content anomalies (FWCA) giving the total magnitude and vertical structure of the FWCAs respectively. Large, positive PC amplitudes (PCAs) of modes 1 and 2 indicate stratification from surface freshening, shown also by negative surface salinity anomalies, whereas positive FWCA PCAs in conjunction with negative mode 2 amplitudes infer higher subsurface freshening due to either vertical mixing or advection. In contrast, basins with negative mode 1 amplitudes are typically salty to slightly brackish, but the mode 2 PCAs determine if the FWC is concentrated near the surface or mixed deeper in the water column. The vertical structure of the temperature anomalies (TA) is more complicated, and at least three EOF modes are required to explain over 90% of the variance. The reasons for this include differences in solar heating (i.e. local climates) modulated by cold alpine runoff and advection of cold, brackish surface and subsurface glacial water. Fjords and major basins influenced by the latter exhibit large, positive mode 1 amplitudes of FWCA and negative mode 1 and 2 PCAs of TA and FWCA respectively. In certain fjords, however, advection of glacial water into the outer basins enhances the total FWC, whereas other fjords exhibit atypically low FWC due to unusual topographic features of the watersheds and inner basins. This combination of factors leads to generally poor correlations between average FWC and watershed to fjord surface area ratios or hydrology. With exception of a few sites, gradients in FWC between the small fjords and major basins are relatively weak. Thus the main driver of baroclinic flow in northern and western PWS is cold, brackish surface and subsurface water propagating from large tidewater glacial fjords. The glacial water has a marked affect on the dynamic topography, which shows southerly baroclinic-geostrophic flows within the western sound. At Montague Strait and Hinchinbrook Entrance inflows may occur from either fresh or salty conditions; low water density of the latter being shown by negative (positive) FWCA (TA) PCAs respectively.

Variability and trends of wet season temperature in the Sudano-Sahelian zone and relationships with precipitation

NASA Astrophysics Data System (ADS)

Oueslati, Boutheina; Camberlin, Pierre; Zoungrana, Joël; Roucou, Pascal; Diallo, Saliou

2018-02-01

The relationships between precipitation and temperature in the central Sudano-Sahelian belt are investigated by analyzing 50 years (1959-2008) of observed temperature (Tx and Tn) and rainfall variations. At daily time-scale, both Tx and Tn show a marked decrease as a response to rainfall occurrence, with a strongest departure from normal 1 day after the rainfall event (-0.5 to -2.5 °C depending on the month). The cooling is slightly larger when heavy rainfall events (>5 mm) are considered. The temperature anomalies weaken after the rainfall event, but are still significant several days later. The physical mechanisms accounting for the temperature response to precipitation are analysed. The Tx drop is accounted for by reduced incoming solar radiation associated with increased cloud cover and increased surface evaporation following surface moistening. The effect of evaporation becomes dominant a few days after the rainfall event. The reduced daytime heat storage and the subsequent sensible heat flux result in a later negative Tn anomaly. The effect of rainfall variations on temperature is significant for long-term warming trends. The rainfall decrease experienced between 1959 and 2008 accounts for a rainy season Tx increase of 0.15 to 0.3 °C, out of a total Tx increase of 1.3 to 1.5 °C. These results have strong implications on the assessment of future temperature changes. The dampening or amplifying effects of precipitation are determined by the sign of future precipitation trends. Confidence on temperature changes under global warming partly depend on the robustness of precipitation projections.

Changes in intensity of precipitation extremes in Romania on very hight temporal scale and implications on the validity of the Clausius-Clapeyron relation

NASA Astrophysics Data System (ADS)

Busuioc, Aristita; Baciu, Madalina; Breza, Traian; Dumitrescu, Alexandru; Stoica, Cerasela; Baghina, Nina

2016-04-01

Many observational, theoretical and based on climate model simulation studies suggested that warmer climates lead to more intense precipitation events, even when the total annual precipitation is slightly reduced. In this way, it was suggested that extreme precipitation events may increase at Clausius-Clapeyron (CC) rate under global warming and constraint of constant relative humidity. However, recent studies show that the relationship between extreme rainfall intensity and atmospheric temperature is much more complex than would be suggested by the CC relationship and is mainly dependent on precipitation temporal resolution, region, storm type and whether the analysis is conducted on storm events rather than fixed data. The present study presents the dependence between the very hight temporal scale extreme rainfall intensity and daily temperatures, with respect to the verification of the CC relation. To solve this objective, the analysis is conducted on rainfall event rather than fixed interval using the rainfall data based on graphic records including intensities (mm/min.) calculated over each interval with permanent intensity per minute. The annual interval with available a such data (April to October) is considered at 5 stations over the interval 1950-2007. For Bucuresti-Filaret station the analysis is extended over the longer interval (1898-2007). For each rainfall event, the maximum intensity (mm/min.) is retained and these time series are considered for the further analysis (abbreviated in the following as IMAX). The IMAX data were divided based on the daily mean temperature into bins 2oC - wide. The bins with less than 100 values were excluded. The 90th, 99th and 99.9th percentiles were computed from the binned data using the empirical distribution and their variability has been compared to the CC scaling (e.g. exponential relation given by a 7% increase per temperature degree rise). The results show a dependence close to double the CC relation for temperatures less than ~ 220C and negative scaling rates for higher temperatures. This behaviour is similar for all the 5 analysed stations over the common interval 1950-2007. This scaling is more exactly for the 90th percentile, while for the higher percentiles the rainfall intensity in response to warming exceeds sometimes the CC rate. For Bucuresti-Filaret station, the results are similar over a longer interval (1898-2007) showing that these findings are robust. Similar techniques has been previously applied to the hourly rainfall intensities recorded at 9 stations (including the 5 ones) and the results are slightly different: the 90th percentile shows dependence close to the CC relation for all temperatures; the 99th and 99.9th percentiles exhibit rates close to double the CC rate for temperatures between ~ 100C and ~ 220C and negative scaling rates for higher temperatures. In conclusion, these results show that the dependence between the extreme precipitation intensity and atmospheric temperature in Romania is mainly dependent on the temporal precipitation resolution and the degree of the extreme precipitation event (moderate or stronger); these findings are mainly in agreenment with the conclusions presented by previous international studies (mentioned above), with some regional specific features, showing the importance of the regional studies. The results presented is this study were funded by the Executive Agency for Higher Education, Research, Development and Innovation Funding (UEFISCDI) through the research project CLIMHYDEX, "Changes in climate extremes and associated impact in hydrological events in Romania", code PNII-ID-2011-2-0073 (http://climhydex.meteoromania.ro).

Douglas-Fir Seedlings Exhibit Metabolic Responses to Increased Temperature and Atmospheric Drought

PubMed Central

Jansen, Kirstin; Du, Baoguo; Kayler, Zachary; Siegwolf, Rolf; Ensminger, Ingo; Rennenberg, Heinz; Kammerer, Bernd; Jaeger, Carsten; Schaub, Marcus; Kreuzwieser, Jürgen; Gessler, Arthur

2014-01-01

In the future, periods of strongly increased temperature in concert with drought (heat waves) will have potentially detrimental effects on trees and forests in Central Europe. Norway spruce might be at risk in the future climate of Central Europe. However, Douglas-fir is often discussed as an alternative for the drought and heat sensitive Norway spruce, because some provenances are considered to be well adapted to drier and warmer conditions. In this study, we identified the physiological and growth responses of seedlings from two different Douglas-fir provenances to increased temperature and atmospheric drought during a period of 92 days. We analysed (i) plant biomass, (ii) carbon stable isotope composition as an indicator for time integrated intrinsic water use efficiency, (iii) apparent respiratory carbon isotope fractionation as well as (iv) the profile of polar low molecular metabolites. Plant biomass was only slightly affected by increased temperatures and atmospheric drought but the more negative apparent respiratory fractionation indicated a temperature-dependent decrease in the commitment of substrate to the tricarboxylic acid cycle. The metabolite profile revealed that the simulated heat wave induced a switch in stress protecting compounds from proline to polyols. We conclude that metabolic acclimation successfully contributes to maintain functioning and physiological activity in seedlings of both Douglas-fir provenances under conditions that are expected during heat waves (i.e. elevated temperatures and atmospheric drought). Douglas-fir might be a potentially important tree species for forestry in Central Europe under changing climatic conditions. PMID:25436455

Hematological variations at rest and during maximal and submaximal exercise in a cold (0°C) environment

NASA Astrophysics Data System (ADS)

Vogelaere, P.; Brasseur, M.; Quirion, A.; Leclercq, R.; Laurencelle, L.; Bekaert, S.

1990-03-01

The affect of negative thermal stress on hematological variables at rest, and during submaximal (sub ex) and maximal exercise (max ex) were observed for young males who volunteered in two experimental sessions, performed in cold (0°C) and in normal room temperature (20°C). At rest, hematological variables such as RBC and derivates Hb and Hct were significantly increased ( P<0.05) during cold stress exposure, while plasma volume decreased. The findings of this study suggest that the major factor inducing hypovolemia during low thermal stress can be imputed to local plasma water-shift mechanisms and especially to a transient shift of plasma water from intrato extravascular compartments. Rest values for WBC and platelets (Pla) were also slightly increased during cold stress exposure. However this increase can partly be related to hemoconcentration but also to the cold induced hyperventilation activating the lung circulation. Maximal exhaustive exercise induced, in both experimental temperatures, significant ( P<0.05) increments of RBC, Hb, Hct, and WBC while plasma volume decreased. However, Pla increase was less marked. On the other hand, cold stress raised slightly the observed variations of the different hematological variables. Submaximal exercise induced a similar, though non-significant, pattern for the different hematological variables in both experimental conditions. Observed plasma volume (Δ PV%) reduction appears during exercise. However cold stress induced resting plasma volume variations that are transferred at every exercise level. Neither exercise nor cold inducement significantly modified the hematological indices (MCH, MCV, MCHC). In conclusion hematological variables are affected by cold stress exposure, even when subjects perform a physical activity.

Inexistence of permafrost at the top of the Veleta peak (Sierra Nevada)

NASA Astrophysics Data System (ADS)

Gómez-Ortiz, Antonio; Salvador-Franch, Ferran; Salvà-Catarineu, Montserrat; Oliva, Marc; Palacios, David; Tanarro, Luis Miguel; Schulte, Lothar

2014-05-01

Several deep drillings wew carried out along a latitudinal transect from Svalbard (78°N) to Sierra Nevada (37°N, Spain) within the project Permafrost and Climate Change in Europe (PACE). In this abstract we discuss the data corresponding to the drilling existing at the top of the Veleta peak, at an altitude of 3380 m. This drilling reach a depth of 114.5 m depth, although we analyze here the data of the first 60 m depth. UTL-1 loggers were installed at depths of 0.2, 0.6, 1.2, 2.6, 4, 7, 10, 13, 15, 20 and 60 m. The observation period spans from 2002 to 2013 with data being taken every 2 h. The most surficial loggersrecorded the largest annual temperature oscillations, reaching 22.6°C at 20 cm. Down to 10 m depth the annual temperature amplitude is still remarkable and seasonal temperature changes are even observed at depths of 15 to 20 m. Below this level the temperature remains constant. The logger installed at 60 m depth recorded small temperature changes between 2006 and 2009, oscillating between 2.38 and 2.61ºC. Since January 2010 the temperatures stabilized at 2.61°C. However, this slight temperature increase must be framed within the margin of instrumentation error of the devices. Data shows evidence of the inexistence ofpermanent negative temperatures at depth. In contrast to what happens in the nearby Veleta cirque floor (3100 m), where marginal permafrost conditions have been recorded, in the Veleta peak (3380 m) data points to the absence of a permafrost regime. This may be due to several factors: a) The existence of permafrost in the Veletacirque is directly related to the presence of fossil glacier ice corresponding to a glacier that existed there during the Little Ice Age. b ) The early melting of snow cover in the Veleta peak due to wind effect and incidence of solar radiation condition the absence of permafrost conditions at the summitin contrast to the Veleta cirquefloor, where the longer persistence of snow favours the presence of continuous negative temperatures. c) The topographical setting of the Veleta peak favours a major incidence of radiation through therock walls,conditioning higher temperatures.

Low Cloud Type over the Ocean from Surface Observations. Part III: Relationship to Vertical Motion and the Regional Surface Synoptic Environment.

NASA Astrophysics Data System (ADS)

Norris, Joel R.; Klein, Stephen A.

2000-01-01

Composite large-scale dynamical fields contemporaneous with low cloud types observed at midlatitude Ocean Weather Station (OWS) C and eastern subtropical OWS N are used to establish representative relationships between low cloud type and the synoptic environment. The composites are constructed by averaging meteorological observations of surface wind and sea level pressure from volunteering observing ships (VOS) and analyses of sea level pressure, 1000-mb wind, and 700-mb pressure vertical velocity from the National Centers for Environmental Prediction-National Center for Atmospheric Research (NCEP-NCAR) reanalysis project on those dates and times of day when a particular low cloud type was reported at the OWS.VOS and NCEP results for OWS C during summer show that bad-weather stratus occurs with strong convergence and ascent slightly ahead of a surface low center and trough. Cumulus-under-stratocumulus and moderate and large cumulus occur with divergence and subsidence in the cold sector of an extratropical cyclone. Both sky-obscuring fog and no-low-cloud typically occur with southwesterly flow from regions of warmer sea surface temperature and differ primarily according to slight surface convergence and stronger warm advection in the case of sky-obscuring fog or surface divergence and weaker warm advection in the case of no-low-cloud. Fair-weather stratus and ordinary stratocumulus are associated with a mixture of meteorological conditions, but differ with respect to vertical motion in the environment. Fair-weather stratus occurs most commonly in the presence of slight convergence and ascent, while stratocumulus often occurs in the presence of divergence and subsidence.Surface divergence and estimated subsidence at the top of the boundary layer are calculated from VOS observations. At both OWS C and OWS N during summer and winter these values are large for ordinary stratocumulus, less for cumulus-under-stratocumulus, and least (and sometimes slightly negative) for moderate and large cumulus. Subsidence interpolated from NCEP analyses to the top of the boundary layer does not exhibit such variation, but the discrepancy may be due to deficiencies in the analysis procedure or the boundary layer parameterization of the NCEP model. The VOS results suggest that decreasing divergence and subsidence in addition to increasing sea surface temperature may promote the transition from stratocumulus to trade cumulus observed over low-latitude oceans.

Scattering of Light and Surface Plasmon Polaritons from Rough Surfaces

DTIC Science & Technology

2013-06-14

Scattering of an electromagnetic wave from a slightly random dielectric surface: Yoneda peak and Brewster angle in incoherent scattering.” Waves...device applications. Thus, the negative refraction of a surface plasmon polariton was studied in two papers. In the first [1], all- angle negative... angle of incidence, measured counterclockwise from the negative x1 axis, is . The surface plasmon polariton of frequency transmitted through the

Diurnal and seasonal changes in stem increment and water use by yellow poplar trees in response to environmental stress.

PubMed

McLaughlin, Samuel B; Wullschleger, Stan D; Nosal, Miloslav

2003-11-01

To evaluate indicators of whole-tree physiological responses to climate stress, we determined seasonal, daily and diurnal patterns of growth and water use in 10 yellow poplar (Liriodendron tulipifera L.) trees in a stand recently released from competition. Precise measurements of stem increment and sap flow made with automated electronic dendrometers and thermal dissipation probes, respectively, indicated close temporal linkages between water use and patterns of stem shrinkage and swelling during daily cycles of water depletion and recharge of extensible outer-stem tissues. These cycles also determined net daily basal area increment. Multivariate regression models based on a 123-day data series showed that daily diameter increments were related negatively to vapor pressure deficit (VPD), but positively to precipitation and temperature. The same model form with slight changes in coefficients yielded coefficients of determination of about 0.62 (0.57-0.66) across data subsets that included widely variable growth rates and VPDs. Model R2 was improved to 0.75 by using 3-day running mean daily growth data. Rapid recovery of stem diameter growth following short-term, diurnal reductions in VPD indicated that water stored in extensible stem tissues was part of a fast recharge system that limited hydration changes in the cambial zone during periods of water stress. There were substantial differences in the seasonal dynamics of growth among individual trees, and analyses indicated that faster-growing trees were more positively affected by precipitation, solar irradiance and temperature and more negatively affected by high VPD than slower-growing trees. There were no negative effects of ozone on daily growth rates in a year of low ozone concentrations.

Low-Temperature Rate Coefficients of C2H with CH4 and CD4 from 154 to 359 K

NASA Technical Reports Server (NTRS)

Opansky, Brian J.; Leone, Stephen R.

1996-01-01

Rate coefficients for the reaction C2H + CH4 yields C2H2 + CH3 and C2H + CD4 yields C2HD + CD3 are measured over the temperature range 154-359 K using transient infrared laser absorption spectroscopy. Ethynyl radicals are produced by pulsed laser photolysis of C2H2 in a variable temperature flow cell, and a tunable color center laser probes the transient removal of C2H (Chi(exp 2) Sigma(+) (0,0,0)) in absorption. The rate coefficients for the reactions of C2H with CH4 and CD4 both show a positive temperature dependence over the range 154-359 K, which can be expressed as k(sub CH4) = (1.2 +/- 0.1) x 10(exp -11) exp((-491 +/- 12)/T) and k(sub CD4) = (8.7 +/- 1.8) x 10(exp -12) exp((-650 +/- 61)/T) cm(exp 3) molecule(exp -1) s(exp -1), respectively. The reaction of C2H + CH4 exhibits a significant kinetic isotope effect at 300 K of k(sub CH4)/k(sub CD4) = 2.5 +/- 0.2. Temperature dependent rate constants for C2H + C2H2 were also remeasured over an increased temperature range from 143 to 359 K and found to show a slight negative temperature dependence, which can be expressed as k(sub C2H2) = 8.6 x 10(exp -16) T(exp 1.8) exp((474 +/- 90)/T) cm(exp 3) molecule(exp -1) s(exp -1).

Recrystallization method to selenization of thin-film Cu(In,Ga)Se.sub.2 for semiconductor device applications

DOEpatents

Albin, David S.; Carapella, Jeffrey J.; Tuttle, John R.; Contreras, Miguel A.; Gabor, Andrew M.; Noufi, Rommel; Tennant, Andrew L.

1995-07-25

A process for fabricating slightly Cu-poor thin-films of Cu(In,Ga)Se.sub.2 on a substrate for semiconductor device applications includes the steps of forming initially a slightly Cu-rich, phase separated, mixture of Cu(In,Ga)Se.sub.2 :Cu.sub.x Se on the substrate in solid form followed by exposure of the Cu(In,Ga)Se.sub.2 :Cu.sub.x Se solid mixture to an overpressure of Se vapor and (In,Ga) vapor for deposition on the Cu(In,Ga)Se.sub.2 :Cu.sub.x Se solid mixture while simultaneously increasing the temperature of the solid mixture toward a recrystallization temperature (about 550.degree. C.) at which Cu(In,Ga)Se.sub.2 is solid and Cu.sub.x Se is liquid. The (In,Ga) flux is terminated while the Se overpressure flux and the recrystallization temperature are maintained to recrystallize the Cu.sub.x Se with the (In, Ga) that was deposited during the temperature transition and with the Se vapor to form the thin-film of slightly Cu-poor Cu.sub.x (In,Ga).sub.y Se.sub.z. The initial Cu-rich, phase separated large grain mixture of Cu(In,Ga)Se.sub.2 :Cu.sub.x Se can be made by sequentially depositing or co-depositing the metal precursors, Cu and (In, Ga), on the substrate at room temperature, ramping up the thin-film temperature in the presence of Se overpressure to a moderate anneal temperature (about 450.degree. C.) and holding that temperature and the Se overpressure for an annealing period. A nonselenizing, low temperature anneal at about 100.degree. C. can also be used to homogenize the precursors on the substrates before the selenizing, moderate temperature anneal.

Effects of consecutive irradiation and bias temperature stress in p-channel power vertical double-diffused metal oxide semiconductor transistors

NASA Astrophysics Data System (ADS)

Davidović, Vojkan; Danković, Danijel; Ilić, Aleksandar; Manić, Ivica; Golubović, Snežana; Djorić-Veljković, Snežana; Prijić, Zoran; Prijić, Aneta; Stojadinović, Ninoslav

2018-04-01

The mechanisms responsible for the effects of consecutive irradiation and negative bias temperature (NBT) stress in p-channel power vertical double-diffused MOS (VDMOS) transistors are presented in this paper. The investigation was performed in order to clarify the mechanisms responsible for the effects of specific kind of stress in devices previously subjected to the other kind of stress. In addition, it may help in assessing the behaviour of devices subjected to simultaneous irradiation and NBT stressing. It is shown that irradiation of previously NBT stressed devices leads to additional build-up of oxide trapped charge and interface traps, while NBT stress effects in previously irradiated devices depend on gate bias applied during irradiation and on the total dose received. In the cases of low-dose irradiation or irradiation without gate bias, the subsequent NBT stress leads to slight further device degradation. On the other hand, in the cases of devices previously irradiated to high doses or with gate bias applied during irradiation, NBT stress may have a positive role, as it actually anneals a part of radiation-induced degradation.

Crystallization and melting properties of mixtures of milk fat stearin and omega-3 rich oils.

PubMed

Li, Bing-Zheng; Truong, Tuyen; Bhandari, Bhesh

2017-03-01

Solid milk fat stearin (S 25 ) can be a promising oxidation retarder due to its capacity to entrap liquid oils, especially for incorporating omega-3 (ω-3) rich oils into dairy products. Thermal properties of S 25 /ω-3 rich oil mixtures are necessary for such application. The effects of S 25 on the crystallization and melting behaviours of ω-3 rich oils, namely fish oil (FO), linseed oil (LO) and krill oil (KO), were investigated by differential scanning calorimetry (DSC). Thermograms showed that with S 25 concentration increasing, transitions of FO and LO shifted to lower and largely to higher temperatures, respectively, while crystallization temperature of KO slightly decreased. Negative, positive and low values of interaction enthalpy (ΔH int ) suggested the adverse, beneficial and limited effect of S 25 on the crystallization of S 25 /FO, S 25 /LO and S 25 /KO mixtures, respectively. LO could have the best oxidative stability upon the addition of S 25 since their interactions facilitated earlier and stronger crystallization. Copyright © 2016 Elsevier Ltd. All rights reserved.

Deglacial Meltwater Pulse Recorded in Last Interglacial Mollusk Shells from Bermuda

NASA Astrophysics Data System (ADS)

Winkelstern, I. Z.; Rowe, M. P.; Lohmann, K. C.; Defliese, W.; Petersen, S. V.; Brewer, A. W.

2016-12-01

Iceberg scours as far south as the Florida Strait and the presence of ice rafted debris in sediments from the Bermuda Rise indicate that during the last glacial phase icebergs traveled quite far south during episodes of excessive iceberg discharge from the Laurentide Ice Sheet (Heinrich Events). We present evidence that the effects of these events extended southward into the subtropics during the previous deglaciation (Termination-II), potentially aligned with Heinrich Event 11, and that meltwater reached Bermuda. Temperatures 10° C colder and seawater δ18O values 2 ‰ more negative than modern are derived from Last Interglacial Cittarium pica shells from Grape Bay, Bermuda using the clumped isotope paleothermometer. In contrast, Last Interglacial shells from Rocky Bay record temperatures only slightly colder and seawater δ18O values similar to modern, potentially representing more typical Last Interglacial conditions in Bermuda outside of a meltwater event. The cold ocean conditions observed illustrate extreme sensitivity of Bermudian climate to rapid climate and ocean circulation changes. They also provide further evidence for routine meltwater transport in the North Atlantic to near-equatorial latitudes during deglaciation.

An internal thermal sensor controlling temperature preference in Drosophila.

PubMed

Hamada, Fumika N; Rosenzweig, Mark; Kang, Kyeongjin; Pulver, Stefan R; Ghezzi, Alfredo; Jegla, Timothy J; Garrity, Paul A

2008-07-10

Animals from flies to humans are able to distinguish subtle gradations in temperature and show strong temperature preferences. Animals move to environments of optimal temperature and some manipulate the temperature of their surroundings, as humans do using clothing and shelter. Despite the ubiquitous influence of environmental temperature on animal behaviour, the neural circuits and strategies through which animals select a preferred temperature remain largely unknown. Here we identify a small set of warmth-activated anterior cell (AC) neurons located in the Drosophila brain, the function of which is critical for preferred temperature selection. AC neuron activation occurs just above the fly's preferred temperature and depends on dTrpA1, an ion channel that functions as a molecular sensor of warmth. Flies that selectively express dTrpA1 in the AC neurons select normal temperatures, whereas flies in which dTrpA1 function is reduced or eliminated choose warmer temperatures. This internal warmth-sensing pathway promotes avoidance of slightly elevated temperatures and acts together with a distinct pathway for cold avoidance to set the fly's preferred temperature. Thus, flies select a preferred temperature by using a thermal sensing pathway tuned to trigger avoidance of temperatures that deviate even slightly from the preferred temperature. This provides a potentially general strategy for robustly selecting a narrow temperature range optimal for survival.

[Histopathological and immunohistochemical studies on mucous cysts].

PubMed

Kuroda, N

1989-01-01

The present study investigated the histopathology, histochemistry of mucopolysaccharides, and immunohistochemistry of oral mucous cysts. The materials were obtained from ninety cases that were histopathologically diagnosed as oral mucous cysts at the Department of Oral Pathology, Meikai University School of Dentistry. Mucopolysaccharide staining was done with PAS, alcian blue (AB, pH 2.5) and high iron diamine (HID). Immunohistochemical studies were focused on secretory component (SC), lactoferrin (Lf), alpha-amylase (Am), IgA, lysozyme (Ly), and keratin (Kr). The following results were obtained: 1. Histopathological findings. (1) Retention and/or retention-like type cysts occurred in was twenty-six cases and the extravasation type in sixty-four cases. (2) Cases showing epithelial lining of the cystic wall were only eight in number, and many cystic walls were contained granulation tissue (fifty cases). (3) As for inflammation of the cystic wall, the degree was slight, and infiltrated cells were mainly macrophages (so-called mucinophages) and lymphocytes. (4) Regarding adjoining salivary glands, acinar cells showed atrophic changes, and hypertrophy of mucous acinar cells was evident. Many ducts showed dilatation, and stromal connective tissue showed fibrosis and hyalinization. 2. Histochemical findings on mucopolysaccharides. (1) Mucous materials in cystic cavity, mucous acinar cells, and secretory materials in ductal lumens were intensely stained by PAS and AB. But stainability with AB was less than that with PAS staining. Serous acinar cells and ductal epithelium were negative to PAS and AB staining. (2) Stainability of the above with HID was less than at with PAS or AB. Cystic walls were not stained by HID. Mucous acinar cells reactive with HID were intensely stained, but the number of the positive cells was limited when compared with the numbers of PAS-and AB-positive cells. 3. Immunohistochemical findings. (1) As for mucous materials in the cystic cavity, reactions for Sc, Am, IgA, and Ly were all positive, whereas those for Lf and Kr were negative. (2) Staining of cystic walls was generally weak: the walls were negative for IgA, Ly and Kr showed and borderline or slightly positive for Sc, Lf, and Am. (3) Mucous acinar cells were negative for all markers examined in this study, but serous acinar cells and/or demilunes were markedly positive for Sc, Ly, and Am. (4) In ductal epithelial cells, Ly and Kr were negative, but IgA was borderline or slightly positive. Sc and Am gave intensely positive staining. (5) Secretory materials in ductal lumens, Sc were intensely positive for Lf, and Ly; slightly or moderately positive for IgA; and slightly positive or negative for Am.(ABSTRACT TRUNCATED AT 400 WORDS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jinlong, Lv, E-mail: ljlbuaa@126.com; State Key Lab of New Ceramic and Fine Processing, Tsinghua University, Beijing 100084; Tongxiang, Liang, E-mail: ljltsinghua@126.com

The nanocrystalline pure nickels with different grain orientations were fabricated by direct current electrodeposition process. The grain size slightly decreased with the increasing of electrodeposition solution temperature. However, grain orientation was affected significantly. Comparing with samples obtained at 50 °C and 80 °C, sample obtained at 20 °C had the strongest (111) orientation plane which increased electrochemical corrosion resistance of this sample. At the same time, the lowest (111) orientation plane deteriorated electrochemical corrosion resistance of sample obtained at 50 °C. - Graphical abstract: The increased electrodeposition temperature promoted slightly grain refinement. The grain orientation was affected significantly by electrodepositionmore » solution temperature. The (111) orientation plane of sample increased significantly corrosion resistance. Display Omitted.« less

Effects of temperature and SDS on the structure of beta-glycosidase from the thermophilic archaeon Sulfolobus solfataricus.

PubMed Central

D'auria, S; Barone, R; Rossi, M; Nucci, R; Barone, G; Fessas, D; Bertoli, E; Tanfani, F

1997-01-01

The effects of temperature and SDS on the three-dimensional organization and secondary structure of beta-glycosidase from the thermophilic archaeon Sulfolobus solfataricus were investigated by CD, IR spectroscopy and differential scanning calorimetry. CD spectra in the near UV region showed that the detergent caused a remarkable change in the protein tertiary structure, and far-UV CD analysis revealed only a slight effect on secondary structure. Infrared spectroscopy showed that low concentrations of the detergent (up to 0.02%) induced slight changes in the enzyme secondary structure, whereas high concentrations caused the alpha-helix content to increase at high temperatures and prevented protein aggregation. PMID:9169619

Thermoeconomical Productivity Analysis in Manufacturing Sector in Indonesia

NASA Astrophysics Data System (ADS)

Liana Aji, Widya; Purqon, Acep

2017-07-01

Negative temperature is a phenomenon interesting to study. In negative temperature regime, Boltzmann distribution is inverted where many particles occupy the higher energy states than the lower one. Iyetomi proposed a negative temperature case in Japan and applied it to the labor productivity distribution where the particle and energy state are replaced by worker and labor productivity, respectively. In this paper, we investigate the negative temperature concept to the labor productivity distribution in manufacturing sector in Indonesia which is divided by three industry groups according to BPS (Center of Statistical Agency of Indonesia), i. e. large and medium industries, small industry, and micro industry. For all industry groups, food industry possesses maximum productivity. The results represent that the negative temperature of large and medium industries is around ten times lower than negative temperature of micro industry indicating large and medium industries is lack demand of worker, while the negative temperature of small industry is among the temperature negative of large and medium industries and micro industry.

Evaluation of inter-observer agreement when using a clinical respiratory scoring system in pre-weaned dairy calves.

PubMed

Buczinski, S; Faure, C; Jolivet, S; Abdallah, A

2016-07-01

To determine inter-observer agreement for a clinical scoring system for the detection of bovine respiratory disease complex in calves, and the impact of classification of calves as sick or healthy based on different cut-off values. Two third-year veterinary students (Observer 1 and 2) and one post-graduate student (Observer 3) received 4 hours of training on scoring dairy calves for signs of respiratory disease, including rectal temperature, cough, eye and nasal discharge, and ear position. Observers 1 and 2 scored 40 pre-weaning dairy calves 24 hours apart (80 observations) over three visits to a calf-rearing facility, and Observers 1, 2 and 3 scored 20 calves on one visit. Inter-observer agreement was assessed using percentage of agreement (PA) and Kappa statistics for individual clinical signs, comparing Observers 1 and 2. Agreement between the three observers for total clinical score was assessed using cut-off values of ≥4, ≥5 and ≥6 to indicate unhealthy calves. Inter-observer PA for rectal temperature was 0.68, for cough 0.78, for nasal discharge 0.62, for eye discharge 0.63, and for ear position 0.85. Kappa values for all clinical signs indicated slight to fair agreement (<0.4), except temperature that had moderate agreement (0.6). The Fleiss' Kappa for total score, using cut-offs of ≥4, ≥5 and ≥6 to indicate unhealthy calves, was 0.35, 0.06 and 0.13, respectively, indicating slight to fair agreement. There was important inter-observer discrepancies in scoring clinical signs of respiratory disease, using relatively inexperienced observers. These disagreements may ultimately mean increased false negative or false positive diagnoses and incorrect treatment of cases. Visual assessment of clinical signs associated with bovine respiratory disease needs to be thoroughly validated when disease monitoring is based on the use of a clinical scoring system.

Effects of Wind Chill Factor, Temperature and Other Meteorological Parameters on the Incidence of Bell's Palsy: Results Based on a Retrospective, 7-Year Long, Greek Population Study.

PubMed

Kokotis, Panagiotis; Katsavos, Serafeim

2015-01-01

The etiology of Bell's palsy (BP), the most common type of dysfunction of the facial nerve, remains unclear despite vigorous research. Data concerning the effects of meteorological factors (MFs) on its appearance are inconclusive. The aim of our study was to examine the demographics of a convenience sample of patients with BP and to determine the effects of several MFs in the recorded number of cases per month (cpm). We retrospectively reviewed 568 files of BP patients and concomitant data of MFs during an 84-month observation period. Information collected included age, gender, diabetic status, number of cpm (months further categorized as winter or summer), mean daily and monthly temperatures and wind speeds and monthly values of wind chill factor (WCF), a measure dependent on both temperature and wind speed. Potential correlations were estimated by univariate analyses (p = 0.05). Demographics were in line with previous research regarding age and diabetic status, but indicative of slight male preponderance. Summer months and mean monthly temperatures showed significant negative correlations with cpm (p = 0.002 and <0.000, respectively) and strong positive correlation with WCF (p < 0.000). MFs can substantially influence the possibility for BP appearance. We propose WCF as a novel, reliable estimator of the overall MF-derived risk. © 2015 S. Karger AG, Basel.

Solvation suppression of ion recombination in gas discharge afterglow

NASA Astrophysics Data System (ADS)

Amirov, R. Kh.; Lankin, A. V.; Norman, G. E.

2018-03-01

An effect which suppresses recombination in ion plasmas is considered both theoretically and experimentally. Experimental results are presented for the ion recombination rate in fluorine plasma, which are obtained from data for the gas discharge afterglow. To interpret them, a suppression factor is considered: ion solvation in weakly ionized plasma. It is shown that the recombination process has a two-stage character with the formation of intermediate metastable ion pairs. The pairs consist of negative and positive ion-molecular clusters. A theoretical explanation is given for the slowing down of the ion recombination with the increase of the Coulomb coupling compared to the ion recombination rate calculated in the ideal plasma approximation. The approximate similarity of the recombination rate of the ion temperature and concentration and reasons for the slight deviation from the similarity are elucidated.

An Impact Triggered Runaway Greenhouse on Mars

NASA Technical Reports Server (NTRS)

Segura, T. L.; McKay, C. P.; Toon, O. B.

2004-01-01

When a planet is in radiative equilibrium, the incoming solar flux balances the outgoing longwave flux. If something were to perturb the system slightly, say the incoming solar flux increased, the planet would respond by radiating at a higher surface temperature. Since any radiation that comes in must go out, if the incoming is increased, the outgoing must also increase, and this increase manifests itself as a warmer equilibrium temperature. The increase in solar flux would correspond to an increase in temperature, which would increase the amount of water vapor in the atmosphere due to increased evaporation. Since water vapor is a greenhouse gas, it would absorb more radiation in the atmosphere leading to a yet warmer equilibrium temperature. The planet would reach radiative equilibrium at this new temperature. There exists a point, however, past which this positive feedback leads to a "runaway" situation. In this case, the planet does not simply evaporate a little more water and eventually come to a slightly higher equilibrium temperature. Instead, the planet keeps evaporating more and more water until all of the planet's available liquid and solid water is in the atmosphere. The reason for this is generally understood. If the planet's temperature increases, evaporation of water increases, and the absorption of radiation increases. This increases the temperature and the feedback continues until all water is in the atmosphere. The resulting equilibrium temperature is very high, much higher than the equilibrium temperature of a point with slightly lower solar flux. One can picture that as solar flux increases, planetary temperature also increases until the runaway point where temperature suddenly "jumps" to a higher value, in response to all the available water now residing in the atmosphere. This new equilibrium is called a "runaway greenhouse" and it has been theorized that this is what happened to the planet Venus, where the surface temperature is more than 700 K (427 C).

Biochemical and physiological responses of Carcinus maenas to temperature and the fungicide azoxystrobin.

PubMed

Rodrigues, Elsa Teresa; Moreno, António; Mendes, Tito; Palmeira, Carlos; Pardal, Miguel Ângelo

2015-08-01

Research on the effects of thermal stress is currently pertinent as climate change is expected to cause more severe climate-driven events. Carcinus maenas, a recognised estuarine model organism, was selected to test temperature-dependence of azoxystrobin toxicity, a widely applied fungicide. Crabs' responses were assessed after a 10-d acclimation at different temperatures (5°C, 22°C, and 27°C) of which the last 72h were of exposure to an environmental concentration of azoxystrobin. SOD and GST activities, mitochondrial oxygen consumption rates and protein content, as well as the Coupling Index were determined. The hypothesis proposed that extreme temperatures (5°C and 27°C) and azoxystrobin would affect crabs' responses. Results showed statistically significant different effects of SOD and all oxygen rates measured promoted by temperature, and that neither 30.3μgL(-1) of azoxystrobin nor the combined effect were crab-responsive. Protein content at 5°C was statistically higher when compared with the control temperature (22°C). The Coupling Index revealed both a slight and a drastic decrease of this index promoted by 5°C and 27°C, respectively. Regarding azoxystrobin effects, at 22°C, this index only decreased slightly. However, at extreme temperatures it fell 47% at 5°C and slightly increased at 27°C. Results provided evidence that crabs' responses to cope with low temperatures were more effective than their responses to cope with high temperatures, which are expected in future climate projections. Moreover, crabs are capable of handling environmental concentrations of azoxystrobin. However, the Coupling Index showed that combined stress factors unbalance crabs' natural capability to handle a single stressor. Copyright © 2015 Elsevier Ltd. All rights reserved.

Temporal change and its spatial variety on land surface temperature and land use changes in the Red River Delta, Vietnam, using MODIS time-series imagery.

PubMed

Van Nguyen, On; Kawamura, Kensuke; Trong, Dung Phan; Gong, Zhe; Suwandana, Endan

2015-07-01

Temporal changes in the land surface temperature (LST) in urbanization areas are important for studying an urban heat island (UHI) and regional climate change. This study examined the LST trends under different land use categories in the Red River Delta, Vietnam, using the Moderate Resolution Imaging Spectroradiometer (MODIS) LST product (MOD11A2) and land cover type product (MCD12Q1) for 11 years (2002-2012). Smoothened time-series MODIS LST data were reconstructed by the Harmonic Analysis of Time Series (HANTS) algorithm. The reconstructed LST (maximum and minimum temperatures) was assessed using the hourly air temperature dataset in two land-based meteorological stations provided by the National Climatic Data Center (NCDC). Significant correlation was obtained between MODIS LST and the air temperature for the daytime (R (2) = 0.73, root mean square error [RMSE] = 1.66 °C) and night time (R (2) = 0.84, RMSE = 1.79 °C). Statistical analysis also showed that LST trends vary strongly depending on the land cover type. Forest, wetland, and cropland had a slight tendency to decline, whereas cropland and urban had sharper increases. In urbanized areas, these increasing trends are even more obvious. This is undeniable evidence of the negative impact of urbanization on a surface urban heat island (SUHI) and global warming.

Myofilament properties comprise the rate-limiting step for cardiac relaxation at body temperature in the rat.

PubMed

Janssen, Paul M L; Stull, Linda B; Marbán, Eduardo

2002-02-01

The majority of studies aimed at characterizing basic contractile mechanisms have been conducted at room temperature. To elucidate the mechanism of cardiac relaxation under more physiological conditions, we investigated contractile function and calcium handling in ultrathin rat cardiac trabeculae. Active developed tension was unaltered between 22.5 and 30.0 degrees C (from 89 +/- 10 to 86 +/- 11 mN/mm(2), P = not significant) but steeply declined at 37.5 degrees C (30 +/- 5 mN/mm(2)). Meanwhile, the speed of relaxation (time from peak force to 50% relaxation) declined from 22.5 to 30.0 degrees C (from 360 +/- 40 to 157 +/- 17 ms) and further declined at 37.5 degrees C to 76 +/- 13 ms. Phase-plane analysis of calcium versus force revealed that, with increasing temperature, the relaxation phase is shifted rightward, indicating that the rate-limiting step of relaxation tends to depend more on calcium kinetics as temperature rises. The force-frequency relationship, which was slightly negative at 22.5 degrees C (0.1 vs. 1 Hz: 77 +/- 12 vs. 66 +/- 7 mN/mm(2)), became clearly positive at 37.5 degrees C (1 vs. 10 Hz: 30 +/- 5 vs. 69 +/- 9 mN/mm(2)). Phase-plane analyses indicated that, with increasing frequency, the relaxation phase is shifted leftward. We conclude that temperature independently affects contraction and relaxation, and cross-bridge cycling kinetics become rate limiting for cardiac relaxation under experimental conditions closest to those in vivo.

Unrealized Global Temperature Increase: Implications of Current Uncertainties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwartz, Stephen E.

Unrealized increase in global mean surface air temperature (GMST) may result from the climate system not being in steady state with forcings and/or from cessation of negative aerosol forcing that would result from decreases in emissions. An observation-constrained method is applied to infer the dependence of Earth's climate sensitivity on forcing by anthropogenic aerosols within the uncertainty on that forcing given by the Fifth (2013) Assessment Report of the Intergovernmental Panel on Climate Change. Within these uncertainty ranges the increase in GMST due to temperature lag for future forcings held constant is slight (0.09–0.19 K over 20 years; 0.12–0.26 Kmore » over 100 years). However the incremental increase in GMST that would result from a hypothetical abrupt cessation of sources of aerosols could be quite large, but is highly uncertain, 0.1–1.3 K over 20 years. Decrease in CO2 abundance and forcing following abrupt cessation of emissions would offset these increases in GMST over 100 years by as little as 0.09 K to as much as 0.8 K. The uncertainties quantified here greatly limit confidence in projections of change in GMST that would result from any strategy for future reduction of emissions.« less

Unrealized Global Temperature Increase: Implications of Current Uncertainties

DOE PAGES

Schwartz, Stephen E.

2018-03-07

Unrealized increase in global mean surface air temperature (GMST) may result from the climate system not being in steady state with forcings and/or from cessation of negative aerosol forcing that would result from decreases in emissions. An observation-constrained method is applied to infer the dependence of Earth's climate sensitivity on forcing by anthropogenic aerosols within the uncertainty on that forcing given by the Fifth (2013) Assessment Report of the Intergovernmental Panel on Climate Change. Within these uncertainty ranges the increase in GMST due to temperature lag for future forcings held constant is slight (0.09–0.19 K over 20 years; 0.12–0.26 Kmore » over 100 years). However the incremental increase in GMST that would result from a hypothetical abrupt cessation of sources of aerosols could be quite large, but is highly uncertain, 0.1–1.3 K over 20 years. Decrease in CO2 abundance and forcing following abrupt cessation of emissions would offset these increases in GMST over 100 years by as little as 0.09 K to as much as 0.8 K. The uncertainties quantified here greatly limit confidence in projections of change in GMST that would result from any strategy for future reduction of emissions.« less

Geochemistry of waters from springs, wells, and snowpack on and adjacent to Medicine Lake volcano, northern California

USGS Publications Warehouse

Mariner, R.H.; Lowenstern, Jacob B.

1999-01-01

Chemical analyses of waters from cold springs and wells of the Medicine Lake volcano and surrounding region indicate small chloride anomalies that may be due to water-rock interaction or limited mixing with high-temperature geothermal fluids. The Fall River Springs (FRS) with a combined discharge of approximately 37 m3/s, show a negative correlation between chloride (Cl) and temperature, implying that the Cl is not derived from a high-temperature geothermal fluid. The high discharge from the FRS indicates recharge over a large geographic region. Chemical and isotopic variations in the FRS show that they contain a mixture of three distinct waters. The isotopic composition of recharge on and adjacent to the volcano are estimated from the isotopic composition of snow and precipitation amounts adjusted for evapotranspiration. Enough recharge of the required isotopic composition (-100 parts per thousand ??D) is available from a combination of the Medicine Lake caldera, the Fall River basin and the Long Bell basin to support the slightly warmer components of the FRS (32 m3/s). The cold-dilute part of the FRS (approximately 5 m3/s) may recharge in the Bear Creek basin or at lower elevations in the Fall River basin.

Apparent temperature and cause-specific emergency hospital admissions in Greater Copenhagen, Denmark.

PubMed

Wichmann, Janine; Andersen, Zorana; Ketzel, Matthias; Ellermann, Thomas; Loft, Steffen

2011-01-01

One of the key climate change factors, temperature, has potentially grave implications for human health. We report the first attempt to investigate the association between the daily 3-hour maximum apparent temperature (Tapp(max)) and respiratory (RD), cardiovascular (CVD), and cerebrovascular (CBD) emergency hospital admissions in Copenhagen, controlling for air pollution. The study period covered 1 January 2002-31 December 2006, stratified in warm and cold periods. A case-crossover design was applied. Susceptibility (effect modification) by age, sex, and socio-economic status was investigated. For an IQR (8°C) increase in the 5-day cumulative average of Tapp(max), a 7% (95% CI: 1%, 13%) increase in the RD admission rate was observed in the warm period whereas an inverse association was found with CVD (-8%, 95% CI: -13%, -4%), and none with CBD. There was no association between the 5-day cumulative average of Tapp(max) during the cold period and any of the cause-specific admissions, except in some susceptible groups: a negative association for RD in the oldest age group and a positive association for CVD in men and the second highest SES group. In conclusion, an increase in Tapp(max) is associated with a slight increase in RD and decrease in CVD admissions during the warmer months.

Teat apex colonization with coagulase-negative Staphylococcus species before parturition: Distribution and species-specific risk factors.

PubMed

De Visscher, A; Piepers, S; Haesebrouck, F; De Vliegher, S

2016-02-01

Coagulase-negative staphylococci (CNS) are the main cause of bovine intramammary infections and are also abundantly present in extramammary habitats such as teat apices. Teat apex colonization (TAC) with CNS has already been explored in lactating dairy cows at the species level, whereas this is not true for dry cows and end-term heifers. Therefore, the aim of this observational study was to describe CNS TAC in nonlactating dairy cows and end-term heifers in Flemish dairy herds and to identify associated risk factors at the herd, cow, and quarter level. All CNS were molecularly identified to the species level using transfer RNA intergenic spacer PCR (tDNA-PCR) and sequencing of the 16S rRNA gene, allowing for species-specific statistical analyses using multivariable, multilevel logistic regression. Staphylococcus devriesei, Staphylococcus chromogenes, Staphylococcus haemolyticus, and Staphylococcus equorum were the most frequently isolated species. Staphylococcus chromogenes was the sole species colonizing teat apices of cows and heifers in all herds, whereas large between-herd differences were observed for the other species. Teat apices of red and white Holstein Friesians, of quarters dried off without an internal teat sealer, and swabbed in months with lower precipitation and higher ambient temperature were significantly more likely to be colonized by S. devriesei. Slightly dirty teat apices and teat apices swabbed in months with lower precipitation had higher odds of being colonized by S. chromogenes, whereas teat apices sampled in months with lower precipitation and higher ambient temperature were more likely to be colonized by S. haemolyticus. Dirty teat apices and teat apices swabbed in months with lower ambient temperature in combination with low precipitation had higher odds of being colonized by S. equorum. Diverse factors explaining CNS TAC, yet mostly related to humidity, ambient temperature, and hygiene, substantiate differences in epidemiological behavior and ecology between species. Copyright © 2016 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Do invasive alien plants benefit more from global environmental change than native plants?

PubMed

Liu, Yanjie; Oduor, Ayub M O; Zhang, Zhen; Manea, Anthony; Tooth, Ifeanna M; Leishman, Michelle R; Xu, Xingliang; van Kleunen, Mark

2017-08-01

Invasive alien plant species threaten native biodiversity, disrupt ecosystem functions and can cause large economic damage. Plant invasions have been predicted to further increase under ongoing global environmental change. Numerous case studies have compared the performance of invasive and native plant species in response to global environmental change components (i.e. changes in mean levels of precipitation, temperature, atmospheric CO 2 concentration or nitrogen deposition). Individually, these studies usually involve low numbers of species and therefore the results cannot be generalized. Therefore, we performed a phylogenetically controlled meta-analysis to assess whether there is a general pattern of differences in invasive and native plant performance under each component of global environmental change. We compiled a database of studies that reported performance measures for 74 invasive alien plant species and 117 native plant species in response to one of the above-mentioned global environmental change components. We found that elevated temperature and CO 2 enrichment increased the performance of invasive alien plants more strongly than was the case for native plants. Invasive alien plants tended to also have a slightly stronger positive response to increased N deposition and increased precipitation than native plants, but these differences were not significant (N deposition: P = 0.051; increased precipitation: P = 0.679). Invasive alien plants tended to have a slightly stronger negative response to decreased precipitation than native plants, although this difference was also not significant (P = 0.060). So while drought could potentially reduce plant invasion, increases in the four other components of global environmental change considered, particularly global warming and atmospheric CO 2 enrichment, may further increase the spread of invasive plants in the future. © 2017 John Wiley & Sons Ltd.

Modelling daily water temperature from air temperature for the Missouri River.

PubMed

Zhu, Senlin; Nyarko, Emmanuel Karlo; Hadzima-Nyarko, Marijana

2018-01-01

The bio-chemical and physical characteristics of a river are directly affected by water temperature, which thereby affects the overall health of aquatic ecosystems. It is a complex problem to accurately estimate water temperature. Modelling of river water temperature is usually based on a suitable mathematical model and field measurements of various atmospheric factors. In this article, the air-water temperature relationship of the Missouri River is investigated by developing three different machine learning models (Artificial Neural Network (ANN), Gaussian Process Regression (GPR), and Bootstrap Aggregated Decision Trees (BA-DT)). Standard models (linear regression, non-linear regression, and stochastic models) are also developed and compared to machine learning models. Analyzing the three standard models, the stochastic model clearly outperforms the standard linear model and nonlinear model. All the three machine learning models have comparable results and outperform the stochastic model, with GPR having slightly better results for stations No. 2 and 3, while BA-DT has slightly better results for station No. 1. The machine learning models are very effective tools which can be used for the prediction of daily river temperature.

[Short-term effects of fire disturbance on greenhouse gases emission from Betula platyphylla-forested wetland in Xiaoxing'an Mountains, Northeast China].

PubMed

Mu, Chang-cheng; Zhang, Bo-wen; Han, Li-dong; Yu, Li-li; Gu, Han

2011-04-01

By the methods of static chamber and gas chromatography, this paper studied the effects of fire disturbance on the seasonal dynamics and source/sink functions of CH4, CO2 and N2O emissions from Betula platyphylla-forested wetland as well as their relations with environmental factors in Xiaoxing' an Mountains of China. In growth season, slight fire disturbance on the wetland induced an increase of air temperature and ground surface temperature by 1.8-3.9 degrees C and a decrease of water table by 6.3 cm; while heavy fire disturbance led to an increase of air temperature and 0-40 cm soil temperature by 1.4-3.8 degrees C and a decrease of water table by 33.9 cm. Under slight or no fire disturbance, the CH4 was absorbed by the wetland soil in spring but emitted in summer and autumn; under heavy fire disturbance, the CH4 was absorbed in spring and summer but emitted in autumn. The CO2 flux had a seasonal variation of summer > spring = autumn under no fire disturbance, but of summer > autumn > spring under fire disturbance; and the N2O flux varied in the order of spring > summer > autumn under no fire disturbance, but of autumn > spring > summer under slight fire disturbance, and of summer > spring = autumn under heavy fire disturbance. At unburned site, the CO2 flux was significantly positively correlated with air temperature and ground surface temperature; at slightly burned site, the CO2 flux had significant positive correlations with air temperature, 5-10 cm soil temperature, and water table; at heavily burned sites, there was a significant positive correlation between CO2 flux and 5-40 cm soil temperature. Fire disturbance made the CH4 emission increased by 169.5% at lightly burned site or turned into weak CH4 sink at heavily burned site, and made the CO2 and N2O emissions and the global warming potential (GWP) at burned sites decreased by 21.2% -34.7%, 65.6% -95.8%, and 22.9% -36.6% respectively, compared with those at unburned site. Therefore, fire disturbance could decrease the greenhouse gases emission from Betula platyphylla-forested wetland, and planned firing could be properly implemented in wetland management.

Method of solution preparation of polyolefin class polymers for electrospinning processing included

NASA Technical Reports Server (NTRS)

Rabolt, John F. (Inventor); Givens, Steven R. (Inventor); Lee, Keun-Hyung (Inventor)

2011-01-01

A process to make a polyolefin fiber which has the following steps: mixing at least one polyolefin into a solution at room temperature or a slightly elevated temperature to form a polymer solution and electrospinning at room temperature said polymer solution to form a fiber.

Interaction of the dietary pigment curcumin with hemoglobin: energetics of the complexation.

PubMed

Basu, Anirban; Kumar, Gopinatha Suresh

2014-08-01

Thermodynamics of the interaction of the chemotherapeutic and chemopreventive dietary pigment, curcumin, with hemoglobin was studied by isothermal titration calorimetry. The binding was characterized to be exothermic. At 293.15 K, the equilibrium constant for curcumin-Hb complexation was found to be (4.88 ± 0.06) × 10(5) M(-1). The binding stoichiometry was calculated to be 1.08 ± 0.05, confirming a 1:1 complexation. The binding was driven by a large negative standard molar enthalpy change (ΔH(0) = -118.45 ± 0.05 kJ mol(-1)) and an unfavorable standard molar entropy change (TΔS(0) = -86.53 ± 0.01 kJ mol(-1)) at 293.15 K. Increasing the temperature favoured the binding, and the magnitude of the negative standard molar heat capacity change suggested the involvement of significant hydrophobic forces in the binding process. With increasing salt concentration, the magnitude of the equilibrium constant decreased slightly; and the complexation mostly involved non-polyelectrolytic forces contributing about 92-94% of the standard molar Gibbs energy change. DSC studies revealed that curcumin binding caused a partial unfolding of the protein.

ELECTROPHORESIS EXPERIMENTS WITH THE VIRUS AND PROTECTIVE BODIES OF YELLOW FEVER

PubMed Central

Frobisher, Martin

1931-01-01

1. When suspended in slightly alkaline (pH 7.4 to 7.8) saline dilutions of clear, hemoglobin-free normal monkey serum, the virus of yellow fever from infected monkeys and from infected, but blood-free, mosquitoes, usually acts as if it were possessed of a positive electrical charge. 2. The virus tends to assume a negative charge in fluids having a slightly acid reaction. 3. The isoelectric point of the virus seems to be in the neighborhood of pH 7.0, possibly ranging from pH 7.3 to pH 6.9. 4. Exposure to fluid having a reaction of pH 5.0 for 3 hours appeared to inactivate the virus. 5. In experiments in which the suspending fluid was prepared with normal serum diluted with distilled water and containing a good quantity of partly hemolyzed erythrocytes, the virus tended to migrate to the anode. 6. The protective bodies in yellow fever immune serum appear to carry a negative charge in slightly alkaline saline dilutions of serum. PMID:19869954

ALTERNATIVE AVIATION FUELS FOR USE IN MILITARY APUS AND ENGINES VERSATILE AFFORDABLE ADVANCED TURBINE ENGINE (VAATE), PHASE II AND III. Delivery Order 0007: Alternative Aviation Fuels for Use in Military Auxiliary Power Units (APUs) and Engines

DTIC Science & Technology

2017-06-03

used and the test cell had been thoroughly purged of the previous fuel, and to provide fuel properties needed to run the test. Posttest fuel samples...altitude hot day generator load. All tests were run at actual engine conditions (not scaled). Fuel flows were adjusted to provide a constant heat input...blends had slightly higher temperatures at the blade tip location and slightly lower temperatures at the blade hub location, but these differences are

Overcharge and overdischarge protection of ambient temperature secondary lithium cells

NASA Technical Reports Server (NTRS)

Huang, Chen-Kuo (Inventor); Surampudi, Subbarao (Inventor); Attia, Alan I. (Inventor); Halpert, Gerald (Inventor)

1994-01-01

A cathode additive is provided for protecting an ambient temperature secondary lithium cell from overcharging or overdischarging. The cathode additive is chosen to create an upper voltage plateau which is slightly higher than a characteristic charge cutoff voltage of the cathode of the cell. The cathode additive additionally creates a lower voltage plateau which is slightly lower than the characteristic discharge cutoff voltage of the cell. Preferably, the cathode additive is a transition metal oxide or a sulfide and may, for example, include a mixture of Li2Mn2O4 and Li(0.1)MoO2.

Simulated East-west differences in F-region peak electron density at Far East mid-latitude region

NASA Astrophysics Data System (ADS)

Ren, Zhipeng; Zhao, Biqiang; Wan, Weixing; Liu, Libo

2017-04-01

In the present work, using Three-Dimensional Theoretical Ionospheric Model of the Earth in Institute of Geology and Geophysics, Chinese Academy of Sciences (TIME3D-IGGCAS), we simulated the east-west differences in Fregion peak electron density (NmF2) at Far East mid-latitude region.We found that, after removing the longitudinal variations of neutral parameters, TIME3D-IGGCAS can better represent the observed relative east-west difference (Rew) features. Rew is mainly negative (West NmF2 > East NmF2) at noon and positive (East NmF2 >West NmF2) at evening-night. The magnitude of daytime negative Rew is weak at local winter and strong at local summer, and the daytime Rew show two negative peaks around two equinoxes. With the increasing of solar flux level, the magnitude of Rew mainly become larger, and two daytime negative peaks slight shifts to June Solstice. With the decreasing of geographical latitude, Rew mainly become positive, and two daytime negative peaks slight shifts to June Solstice. Our simulation also suggested that the thermospheric zonal wind combined with the geomagnetic field configuration play a pivotal role in the formation of the ionospheric east-west differences at Far East midlatitude region.

Simulated East-west differences in F-region peak electron density at Far East mid-latitude region

NASA Astrophysics Data System (ADS)

Ren, Z.; Wan, W.

2017-12-01

In the present work, using Three-Dimensional Theoretical Ionospheric Model of the Earth in Institute of Geology and Geophysics, Chinese Academy of Sciences (TIME3D-IGGCAS), we simulated the east-west differences in Fregion peak electron density (NmF2) at Far East mid-latitude region.We found that, after removing the longitudinal variations of neutral parameters, TIME3D-IGGCAS can better represent the observed relative east-west difference (Rew) features. Rew is mainly negative (West NmF2 > East NmF2) at noon and positive (East NmF2 >West NmF2) at evening-night. The magnitude of daytime negative Rew is weak at local winter and strong at local summer, and the daytime Rew show two negative peaks around two equinoxes. With the increasing of solar flux level, the magnitude of Rew mainly become larger, and two daytime negative peaks slight shifts to June Solstice. With the decreasing of geographical latitude, Rew mainly become positive, and two daytime negative peaks slight shifts to June Solstice. Our simulation also suggested that the thermospheric zonal wind combined with the geomagnetic field configuration play a pivotal role in the formation of the ionospheric east-west differences at Far East midlatitude region.

Evaluation of Additive Manufacturing for Stainless Steel Components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peter, William H.; Lou, Xiaoyuan; List, III, Frederick Alyious

This collaboration between Oak Ridge National Laboratory and General Electric Company aimed to evaluate the mechanical properties, microstructure, and porosity of the additively manufactured 316L stainless steel by ORNL’s Renishaw AM250 machine for nuclear application. The program also evaluated the stress corrosion cracking and corrosion fatigue crack growth rate of the same material in high temperature water environments. Results show the properties of this material to be similar to the properties of 316L stainless steel fabricated additively with equipment from other manufacturers with slightly higher porosity. The stress corrosion crack growth rate is similar to that for wrought 316L stainlessmore » steel for an oxygenated high temperature water environment and slightly higher for a hydrogenated high temperature water environment. Optimized heat treatment of this material is expected to improve performance in high temperature water environments.« less

Optical and application study of gas-liquid discharge excited by bipolar nanosecond pulse in atmospheric air.

PubMed

Wang, Sen; Wang, Wen-chun; Yang, De-zheng; Liu, Zhi-jie; Zhang, Shuai

2014-10-15

In this study, a bipolar nanosecond pulse with 20ns rising time is employed to generate air gas-liquid diffuse discharge plasma with room gas temperature in quartz tube at atmospheric pressure. The image of the discharge and optical emission spectra of active species in the plasma are recorded. The plasma gas temperature is determined to be approximately 390K by compared the experimental spectra with the simulated spectra, which is slightly higher than the room temperature. The result indicated that the gas temperature rises gradually with pulse peak voltage increasing, while decreases slightly with the electrode gap distance increasing. As an important application, bipolar nanosecond pulse discharge is used to sterilize the common microorganisms (Actinomycetes, Candida albicans and Escherichia coli) existing in drinking water, which performs high sterilization efficiency. Copyright © 2014 Elsevier B.V. All rights reserved.

High-temperature Brillouin scattering study of haplogranitic glasses and liquids: Effects of F, K, Na and Li on Tg and elastic properties

NASA Astrophysics Data System (ADS)

Manghnani, M. H.; Hushur, A.; Williams, Q. C.; Dingwell, D. B.

2010-12-01

The density, compressibility and viscosity of silicate melts are important in understanding the thermodynamic and fluid dynamic properties of magmatic systems. Knowledge of the compressibility of silicate melts at 1 bar is an important component in the construction of accurate pressure-volume-temperature equations of state. In light of this, the velocity (nVp, Vp, Vs) and refractive index n of four anhydrous haplogranitic glasses and liquids with similar alkali abundances, but different cations, are measured at high temperature by Brillouin scattering spectroscopy through the glass transition temperature (Tg) in both platelet and back scattering geometry. The compositions of four haplogranites are 5 wt% of the components Li2O, Na2O, K2O and F each added to a base of haplogranitic (HPG8) composition. The glass transition temperature Tg of different haplogranite samples at the GHz frequency of the Brillouin probe are determined from the change in slope of the temperature-dependent longitudinal or transverse sound velocity. HPG8-Li5 has the lowest glass transition temperature (466°C), while HPG8-K5 has the highest glass transition temperature (575°C). Our Brillouin results, when compared with DSC measurements, show lower Tg values. This raises the possibility of a role of either heating rates or a frequency dependence of the glass transition in explaining the discrepancies in Tg values derived from the two methods. The sound velocity (nVp, Vp, Vs) shows markedly different temperature dependences (including differences in sign) below Tg depending on their different alkali contents. The unrelaxed elastic moduli of three haplogranitic glasses with added Li2O, Na2O and F components have been obtained as a function of temperature. The unrelaxed bulk modulus, shear modulus and Poisson’s ratio show strong compositional dependences at ambient temperature. On heating, The K initially decreases with increasing temperature up to ~ 135°C, then increases up to Tg, and then shows negative temperature dependences for HPG8-Na5. The slope changes from -0.0043(18) GPa/°C below 135°C to 0.0040(5) GPa/°C between 135°C and Tg. In the case of HPG8-Li5, both K and G decrease with increasing temperature.. For HPG8-F5, the K shows a markedly positive temperature dependence below Tg, and a very small temperature dependence above Tg. The shear modulus G shows a slight positive temperature dependence below Tg, and a larger negative temperature dependence above Tg. The Poisson’s ratios of HPG8-Li5 and HPG8-F5 glasses increase monotonically in the measured temperature range, while the Poisson’s ratio of HPG8-Na5 shows a distinct minimum at 135°C. Our results thus provide constraints on the visco-elastic properties of model granitic systems at a range of temperatures above and below their glass transition temperature.

Numerical renormalization group method for entanglement negativity at finite temperature

NASA Astrophysics Data System (ADS)

Shim, Jeongmin; Sim, H.-S.; Lee, Seung-Sup B.

2018-04-01

We develop a numerical method to compute the negativity, an entanglement measure for mixed states, between the impurity and the bath in quantum impurity systems at finite temperature. We construct a thermal density matrix by using the numerical renormalization group (NRG), and evaluate the negativity by implementing the NRG approximation that reduces computational cost exponentially. We apply the method to the single-impurity Kondo model and the single-impurity Anderson model. In the Kondo model, the negativity exhibits a power-law scaling at temperature much lower than the Kondo temperature and a sudden death at high temperature. In the Anderson model, the charge fluctuation of the impurity contributes to the negativity even at zero temperature when the on-site Coulomb repulsion of the impurity is finite, while at low temperature the negativity between the impurity spin and the bath exhibits the same power-law scaling behavior as in the Kondo model.

On the dispute between Boltzmann and Gibbs entropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buonsante, Pierfrancesco; Franzosi, Roberto, E-mail: roberto.franzosi@ino.it; Smerzi, Augusto

2016-12-15

The validity of the concept of negative temperature has been recently challenged by arguing that the Boltzmann entropy (that allows negative temperatures) is inconsistent from a mathematical and statistical point of view, whereas the Gibbs entropy (that does not admit negative temperatures) provides the correct definition for the microcanonical entropy. Here we prove that the Boltzmann entropy is thermodynamically and mathematically consistent. Analytical results on two systems supporting negative temperatures illustrate the scenario we propose. In addition we numerically study a lattice system to show that negative temperature equilibrium states are accessible and obey standard statistical mechanics prediction.

Pollutant emissions from flat-flame burners at high pressures

NASA Technical Reports Server (NTRS)

Maahs, H. G.; Miller, I. M.

1980-01-01

Maximum flame temperatures and pollutant emission measurements for NOx, CO, and UHC (unburned hydrocarbons) are reported for premixed methane air flat flames at constant total mass flow rate over the pressure range from 1.9 to 30 atm and for equivalence ratios from 0.84 to 1.12. For any given pressure, maxima typically occur in both the temperature and NOx emissions curves slightly to the lean side of stoichiometric conditions. The UHC emissions show minima at roughly the same equivalence ratios. The CO emissions, however, increase continually with increasing equivalence ratio. Flame temperature and NOx emissions decrease with increasing pressure, while the opposite is true for the CO and UHC emissions. The NOx data correlate reasonably well as a function of flame temperature only. Four flameholders, differing only slightly, were used. In general, the temperature and emissions data from these four flameholders are similar, but some differences also exist. These differences appear to be related to minor variations in the condition of the flameholder surfaces.

Thermal properties of polyethylene reinforced with recycled–poly (ethylene terephthalate) flakes.

NASA Astrophysics Data System (ADS)

Ruqiyah Nik Hassan, Nik; Mazni Ismail, Noor; Ghazali, Suriati; Nuruzzaman, Dewan Muhammad

2018-04-01

In this study, recycled plastic bottles (RPET) were used as a filler in high density polyethylene (HDPE) thermoplastic. The plastic sheet of RPET/HDPE was prepared by using hot and cold press machine. The effects of RPET addition and hot press process to the thermal properties of the composite RPET/HDPE were investigated using differential scanning calorimetry (DSC) and thermogravimetric (TGA). Results from DSC analysis show that the melting point of HDPE slightly shifted to a higher temperature for about 2°C to 4°C with the addition of RPET as a filler. The starting degradation temperature of RPET/HDPE composite examined from TGA analysis also seen to be slightly increased. It was observed that the incorporation of recycled PET flakes into HDPE is achievable using hot press process with slight improvement seen in both melting point and thermal stability of the composite compared to the neat HDPE.

High resolution imaging of latent fingerprints by localized corrosion on brass surfaces.

PubMed

Goddard, Alex J; Hillman, A Robert; Bond, John W

2010-01-01

The Atomic Force Microscope (AFM) is capable of imaging fingerprint ridges on polished brass substrates at an unprecedented level of detail. While exposure to elevated humidity at ambient or slightly raised temperatures does not change the image appreciably, subsequent brief heating in a flame results in complete loss of the sweat deposit and the appearance of pits and trenches. Localized elemental analysis (using EDAX, coupled with SEM imaging) shows the presence of the constituents of salt in the initial deposits. Together with water and atmospheric oxygen--and with thermal enhancement--these are capable of driving a surface corrosion process. This process is sufficiently localized that it has the potential to generate a durable negative topographical image of the fingerprint. AFM examination of surface regions between ridges revealed small deposits (probably microscopic "spatter" of sweat components or transferred particulates) that may ultimately limit the level of ridge detail analysis.

Apparatus for molecular weight separation

DOEpatents

Smith, Richard D.; Liu, Chuanliang

2001-01-01

The present invention relates generally to an apparatus and method for separating high molecular weight molecules from low molecular weight molecules. More specifically, the invention relates to the use of microdialysis for removal of the salt (low molecular weight molecules) from a nucleotide sample (high molecular weight molecules) for ESI-MS analysis. The dialysis or separation performance of the present invention is improved by (1) increasing dialysis temperature thereby increasing desalting efficiency and improving spectrum quality; (2) adding piperidine and imidazole to the dialysis buffer solution and reducing charge states and further increasing detection sensitivity for DNA; (3) using low concentrations (0-2.5 mM NH4OAc) of dialysis buffer and shifting the DNA negative ions to higher charge states, producing a nearly 10-fold increase in detection sensitivity and a slightly decreased desalting efficiency, (4) conducting a two-stage separation or (5) any combination of (1), (2), (3) and (4).

Microdialysis unit for molecular weight separation

DOEpatents

Smith, Richard D.; Liu, Chuanliang

1999-01-01

The present invention relates generally to an apparatus and method for separating high molecular weight molecules from low molecular weight molecules. More specifically, the invention relates to the use of microdialysis for removal of the salt (low molecular weight molecules) from a nucleotide sample (high molecular weight molecules) for ESI-MS analysis. The dialysis or separation performance of the present invention is improved by (1) increasing dialysis temperature thereby increasing desalting efficiency and improving spectrum quality; (2) adding piperidine and imidazole to the dialysis buffer solution and reducing charge states and further increasing detection sensitivity for DNA; (3) using low concentrations (0-2.5 mM NH4OAc) of dialysis buffer and shifting the DNA negative ions to higher charge states, producing a nearly 10-fold increase in detection sensitivity and a slightly decreased desalting efficiency, or (4) any combination of (1), (2), and (3).

Densitometric evaluation of Soludent and GBX developers.

PubMed

Patel, J R

1985-01-01

A quick-developing solution (Soludent) and a new developer (Kodak GBX) were compared with a standard x-ray liquid developer. Of the three solutions evaluated, Kodak GBX solution produced slightly greater useful densities in the radiograph at all temperatures evaluated. The rapid-developing solution produced acceptable radiographs in 80% less time, with only slightly higher film fog.

Temperature-Dependent Electrical Conductivity of GeTe-Based RF Switches

DTIC Science & Technology

2015-03-31

Short, high temperature pulses result in a melt -quench cycle, amorphizing the GeTe and leaving the switch in the electrically insulating OFF state...Longer, lower temperature pulses result in the recrystallization of the GeTe, leaving the switch in the electrically conductive ON state. The...shown to vary only weakly with temperature. OFF-state S-parameters also exhibit slight temperature variation, with an inflection point of ~175

Novel immobilization process of a thermophilic catalase: efficient purification by heat treatment and subsequent immobilization at high temperature.

PubMed

Xu, Juan; Luo, Hui; López, Claudia; Xiao, Jing; Chang, Yanhong

2015-10-01

The main goal of the present work is to investigate a novel process of purification and immobilization of a thermophilic catalase at high temperatures. The catalase, originated from Bacillus sp., was overexpressed in a recombinant Escherichia coli BL21(DE3)/pET28-CATHis and efficiently purified by heat treatment, achieving a threefold purification. The purified catalase was then immobilized onto an epoxy support at different temperatures (25, 40, and 55 °C). The immobilizate obtained at higher temperatures reached its maximum activity in a shorter time than that obtained at lower temperatures. Furthermore, immobilization at higher temperatures required a lower ionic strength than immobilization at lower temperatures. The characteristics of immobilized enzymes prepared at different temperatures were investigated. The high-temperature immobilizate (55 °C) showed the highest thermal stability, followed by the 40 °C immobilizate. And the high-temperature immobilizate (55 °C) had slightly higher operational stability than the 25 °C immobilizate. All of the immobilized catalase preparations showed higher stability than the free enzyme at alkaline pH 10.0, while the alkali resistance of the 25 °C immobilizate was slightly better than that of the 40 and 55 °C immobilizates.

Physics of negative absolute temperatures.

PubMed

Abraham, Eitan; Penrose, Oliver

2017-01-01

Negative absolute temperatures were introduced into experimental physics by Purcell and Pound, who successfully applied this concept to nuclear spins; nevertheless, the concept has proved controversial: a recent article aroused considerable interest by its claim, based on a classical entropy formula (the "volume entropy") due to Gibbs, that negative temperatures violated basic principles of statistical thermodynamics. Here we give a thermodynamic analysis that confirms the negative-temperature interpretation of the Purcell-Pound experiments. We also examine the principal arguments that have been advanced against the negative temperature concept; we find that these arguments are not logically compelling, and moreover that the underlying "volume" entropy formula leads to predictions inconsistent with existing experimental results on nuclear spins. We conclude that, despite the counterarguments, negative absolute temperatures make good theoretical sense and did occur in the experiments designed to produce them.

Anharmonicity of three minerals at high temperature: Forsterite, fayalite, and periclase

NASA Astrophysics Data System (ADS)

Anderson, O. L.; Suzuki, I.

1983-04-01

Recent data on Ks (the adiabatic bulk modulus) and α (the volume coefficient of thermal expansion) versus T (temperature) at high temperatures (500°C < T < 1000°C) have been published or are in press. These data, taken at ambient pressure, extend the measurement of single-crystal elastic constants for forsterite, fayalite and periclase to record temperatures. The high temperature anharmonic properties of forsterite and fayalite are presented for the first time in this paper, and they are compared with similar previously published data for MgO. The anharmonic properties referred to above concern the dependence of γ (the Grüneisen ratio), PTH (the thermal pressure), and Cv (the specific heat) with T. If γ (at constant V) is independent of T at high T, the anharmonicity in γ is said to be nil; similarly, for Cv. If PTH at constant V is proportional to T at high T, then the anharmonicity in PTH is said to be nil. The anharmonicity determined by these experiments indicates that the minerals are not alike with regard to their properties γ, PTH, and Cv. The γ versus T at constant V indicates that there is anharmonicity for all three minerals, but the effects are opposite in fayalite and forsterite in such a way that anharmonicity should be absent in olivine. For PTH at 1 bar, anharmonicity is detectable and positive in forsterite, absent in fayalite, and detectable and negative in periclase. It would be slight in olivine. In all three solids, anharmonicity in Cv is pronounced and positive.

Pollution characteristics and influencing factors of atmospheric particulate matter (PM2.5) in Chang-Zhu-Tan area

NASA Astrophysics Data System (ADS)

Zhang, Yong; Jiang, Wulin

2018-01-01

Using the same time data of PM2.5 concentration and meteorology from May 1st to May 31st in 2013 in Chang-Zhu-Tan area. This paper analyses the variation characteristics of PM2.5 concentration and the correlations between the variation characteristics and meteorological factors. In view of time, the results showed that the 24-h PM2.5 concentration varied with the two peaks and two valleys styles in Chang-Zhu-Tan area. And the daily PM2.5 concentration tends to the instability and great variation characteristics with the multi-peaks and multi-valleys style. In view of space, PM2.5 concentration values of the three cities from high to low are Zhuzhou>Xiangtan>Changsha. For cities and suburbs, PM2.5 concentration values of central towns are greater than that of the suburbs in Changsha and Xiangtan; however, the PM2.5 concentration values of the central town in Zhuzhou are slightly lower than the suburbs. At the same time, the correlation analysis between PM2.5 concentration and meteorological factors showed that the correlation from high to low was the relative air humidity>soil temperature>air temperature>soil humidity> wind velocity>rainfall. Among the above meteorological factors, wind velocity, rainfall, air temperature, soil temperature and soil humidity are negatively correlated with PM2.5 concentration, but the relationship between relative air humidity and PM2.5 concentration is a positive correlation.

A comparison of 2 evaporative cooling systems on a commercial dairy farm in Saudi Arabia.

PubMed

Ortiz, X A; Smith, J F; Villar, F; Hall, L; Allen, J; Oddy, A; Al-Haddad, A; Lyle, P; Collier, R J

2015-12-01

Efficacy of 2 cooling systems (Korral Kool, KK, Korral Kool Inc., Mesa, AZ; FlipFan dairy system, FF, Schaefer Ventilation Equipment LLC, Sauk Rapids, MN) was estimated utilizing 400 multiparous Holstein dairy cows randomly assigned to 1 of 4 cooled California-style shade pens (2 shade pens per cooling system). Each shaded pen contained 100 cows (days in milk=58±39, milk production=56±18 kg/d, and lactation=3±1). Production data (milk yield and reproductive performance) were collected during 3mo (June-August, 2013) and physiological responses (core body temperature, respiration rates, surface temperatures, and resting time) were measured in June and July to estimate responses of cows to the 2 different cooling systems. Water and electricity consumption were recorded for each system. Cows in the KK system displayed slightly lower respiration rates in the month of June and lower surface temperatures in June and July. However, no differences were observed in the core body temperature of cows, resting time, feed intake, milk yield, services/cow, and conception rate between systems. The FF system used less water and electricity during this study. In conclusion, both cooling systems (KK and FF) were effective in mitigating the negative effects of heat stress on cows housed in arid environments, whereas the FF system consumed less water and electricity and did not require use of curtains on the shade structure. Copyright © 2015 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Balanced conditions or slight mass gain of glaciers in the Lahaul and Spiti region (northern India, Himalaya) during the nineties preceded recent mass loss

NASA Astrophysics Data System (ADS)

Vincent, C.; Ramanathan, Al.; Wagnon, P.; Dobhal, D. P.; Linda, A.; Berthier, E.; Sharma, P.; Arnaud, Y.; Azam, M. F.; Jose, P. G.; Gardelle, J.

2013-04-01

The volume change of the Chhota Shigri Glacier (India, 32° 20 N, 77° 30' E) between 1988 and 2010 has been determined using in situ geodetic measurements. This glacier has experienced only a slight mass loss between 1988 and 2010 (-3.8 ± 2.0 m w.e. (water equivalent) corresponding to -0.17 ± 0.09 m w.e. yr-1). Using satellite digital elevation models (DEM) differencing and field measurements, we measure a negative mass balance (MB) between 1999 and 2010 (-4.8 ± 1.8 m w.e. corresponding to -0.44 ± 0.16 m w.e. yr-1). Thus, we deduce a slightly positive or near-zero MB between 1988 and 1999 (+1.0 ± 2.7 m w.e. corresponding to +0.09 ± 0.24 m w.e. yr-1). Furthermore, satellite DEM differencing reveals that the MB of the Chhota Shigri Glacier (-0.39 ± 0.15 m w.e. yr-1) has been only slightly less negative than the MB of a 2110 km2 glaciarized area in the Lahaul and Spiti region (-0.44 ± 0.09 m w.e. yr-1) during 1999-2011. Hence, we conclude that the ice wastage is probably moderate in this region over the last 22 yr, with near equilibrium conditions during the nineties, and an ice mass loss after. The turning point from balanced to negative mass budget is not known but lies probably in the late nineties and at the latest in 1999. This positive or near-zero MB for Chhota Shigri Glacier (and probably for the surrounding glaciers of the Lahaul and Spiti region) during at least part of the 1990s contrasts with a recent compilation of MB data in the Himalayan range that indicated ice wastage since 1975. However, in agreement with this compilation, we confirm more negative balances since the beginning of the 21st century.

Dynamics of Total Microcystin LR Concentration in Three Subtropical Hydroelectric Generation Reservoirs in Uruguay, South America.

PubMed

González-Piana, Mauricio; Fabián, Daniel; Piccardo, Andrea; Chalar, Guillermo

2017-10-01

This study analyzed the temporal dynamics of total microcystin LR concentrations between the years of 2012 and 2015 in the Bonete, Baygorria and Palmar hydroelectric generation reservoirs in the central region of the Negro River, Uruguay. The three reservoirs showed differents total microcystin LR concentration, with no significant differences among them. Over 20 sampling dates, the three reservoirs exhibited total microcystin LR concentrations on eight occasions that corresponded to a slight to moderate human health risk according to WHO guideline values for recreational waters. By determining the concentration of microcystin LR in cyanobacterial biomass, we identified cyanobacterial populations that occurred over time with varying degrees of toxin production (maximal 85.4 µg/mm 3 ). The microcystin LR concentration in Bonete was positively correlated with temperature (r = 0.587) and cyanobacterial biomass (r = 0.736), in Baygorria with cyanobacterial biomass (r = 0.521), and in Palmar with temperature (r = 0.500) and negatively correlated with ammonia (r = -0.492). Action is needed to reduce the presence of toxic cyanobacteria in these systems. A decrease in the use of agrochemicals and management changes in the reservoir basins could be successful long-term measures.

The existence of superconductivity in Nb1.75Ta0.25PdS5

NASA Astrophysics Data System (ADS)

Venkateshwarlu, D.; Patidar, Manju Mishra; Singh, Durgesh; Amarendra, G.; Ganesan, V.

2018-05-01

Nb2PdS5 is a novel superconductor having promising potential for applications. Synthesis of this by solid state reaction, characterization using susceptibility and resistivity of Ta substituted Nb2PdS5 is reported in the present paper. Nb1.75Ta0.25PdS5 shows a diamagnetic transition at 6K while the onset of superconducting transition in resistivity is found at 6.73K; the slight difference is attributed to Aslamazov-Larkin paraconductivity fluctuations. This can be ascertained from the fact that the transition seen in resistivity is so broad that the zero resistance state is elusive due to weak inter grain coupling. We also report temperature dependence of resistivity under magnetic fields up to 16T that shows considerable broadening in fields that can be attributed to the field induced resistive state with underlying vortex motion. The results are explained based on models like thermally activated flux flow (TAFF) in the light of Kramer's relation. The normal state just above Tc has a negative temperature co-efficient of resistivity reminiscent of the Anderson localization scenario. The estimated critical field of 27T is more than two times higher than that of Pauli limit.

Formation of (HCOO – )(H 2 SO 4 ) Anion Clusters: Violation of Gas-Phase Acidity Predictions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hou, Gao-Lei; Wang, Xue-Bin; Valiev, Marat

2017-08-10

Sulfuric acid is commonly known to be a strong acid and, by all counts, should readily donate its proton to formate, which has much higher proton affinity. This conventional wisdom is challenged in this work, where temperature-dependent negative ion photoelectron spectroscopy (NIPES) and theoretical studies demonstrate the existence of (HCOO?)(H2SO4) pair at the energy slightly below the conventional (HCOOH)(HSO4?) structure. Analysis of quantum-mechanical calculations indicates that large proton affinity barrier (~36 kcal/mol), favoring proton transfer to formate, is offset by the gain in inter-molecular interaction energy between HCOO? and H2SO4 through the formation of two strong hydrogen bonds. However, thismore » stabilization comes with severe entropic penalty, requiring the two species in the precise align-ment. As a result, the population of (HCOO?)(H2SO4) drops significantly at higher temperatures, rendering (HCOOH)(HSO4?) to be the dominant species. This phe-nomenon is consistent with the NIPES data, which shows depletion in the spectra assigned to (HCOO?)(H2SO4), and has also been verified by ab initio molecular dynamics simulations.« less

Development of SPR temperature sensor using Au/TiO2 on hetero-core optical fiber

NASA Astrophysics Data System (ADS)

Kitagawa, Sho; Yamazaki, Hiroshi; Hosoki, Ai; Nishiyama, Michiko; Watanabe, Kazuhiro

2016-03-01

This paper describes a novel temperature sensor based on a hetero-core structured fiber optic surface plasmon resonance (SPR) sensor with multi-layer thin film of gold (Au) and titanium dioxide (TiO2). Temperature condition is an essential parameter in chemical plants for avoiding fire accident and controlling qualities of chemical substances. Several fiber optic temperature sensors have been developed for some advantages such as immunity to electromagnetic interference, corrosion resistance and no electrical leakage. The proposed hetero-core fiber optic SPR sensor detects temperature condition by measuring slight refractive index changes of TiO2 which has a large thermo-optic coefficient. We experimentally confirmed that the SPR resonant wavelength in the hetero-core SPR sensor with coating an Au film which slightly depended on temperature changes in the range from 20 °C to 80 °C. In addition, it was experimentally shown that the proposed SPR temperature sensor with multi-layer film of Au and TiO2 had the SPR resonant wavelength shift of 1.6 nm due to temperature change from -10 °C to 50 °C. As a result, a series of experiments successfully demonstrated that the proposed sensor was able to detect temperature directly depending on the thermo-optic effect of TiO2.

40 CFR 60.386 - Test methods and procedures.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... The sample volume for each run shall be at least 1.70 dscm (60 dscf). The sampling probe and filter... probe and filter temperature slightly above the effluent temperature (up to a maximum filter temperature of 121 °C (250 °F)) in order to prevent water condensation on the filter. (2) Method 9 and the...

Accelerated in vitro release testing of implantable PLGA microsphere/PVA hydrogel composite coatings

PubMed Central

Shen, Jie; Burgess, Diane J.

2011-01-01

Dexamethasone loaded poly(lactic-co-glycolic acid) (PLGA) microsphere/PVA hydrogel composites have been investigated as an outer drug-eluting coating for implantable devices such as glucose sensors to counter negative tissue responses to implants. The objective of this study was to develop a discriminatory, accelerated in vitro release testing method for this drug-eluting coating using United States Pharmacopeia (USP) apparatus 4. Polymer degradation and drug release kinetics were investigated under “real-time” and accelerated conditions (i.e. extreme pH, hydro-alcoholic solutions and elevated temperatures). Compared to “real-time” conditions, the initial burst and lag phases were similar using hydro-alcoholic solutions and extreme pH conditions, while the secondary apparent zero-order release phase was slightly accelerated. Elevated temperatures resulted in a significant acceleration of dexamethasone release. The accelerated release data were able to predict “real-time” release when applying the Arrhenius equation. Microsphere batches with faster and slower release profiles were investigated under “real-time” and elevated temperature (60°C) conditions to determine the discriminatory ability of the method. The results demonstrated both the feasibility and the discriminatory ability of this USP apparatus 4 method for in vitro release testing of drug loaded PLGA microsphere/PVA hydrogel composites. This method may be appropriate for similar drug/device combination products and drug delivery systems. PMID:22016033

Accelerated in vitro release testing of implantable PLGA microsphere/PVA hydrogel composite coatings.

PubMed

Shen, Jie; Burgess, Diane J

2012-01-17

Dexamethasone loaded poly(lactic-co-glycolic acid) (PLGA) microsphere/PVA hydrogel composites have been investigated as an outer drug-eluting coating for implantable devices such as glucose sensors to counter negative tissue responses to implants. The objective of this study was to develop a discriminatory, accelerated in vitro release testing method for this drug-eluting coating using United States Pharmacopeia (USP) apparatus 4. Polymer degradation and drug release kinetics were investigated under "real-time" and accelerated conditions (i.e. extreme pH, hydro-alcoholic solutions and elevated temperatures). Compared to "real-time" conditions, the initial burst and lag phases were similar using hydro-alcoholic solutions and extreme pH conditions, while the secondary apparent zero-order release phase was slightly accelerated. Elevated temperatures resulted in a significant acceleration of dexamethasone release. The accelerated release data were able to predict "real-time" release when applying the Arrhenius equation. Microsphere batches with faster and slower release profiles were investigated under "real-time" and elevated temperature (60°C) conditions to determine the discriminatory ability of the method. The results demonstrated both the feasibility and the discriminatory ability of this USP apparatus 4 method for in vitro release testing of drug loaded PLGA microsphere/PVA hydrogel composites. This method may be appropriate for similar drug/device combination products and drug delivery systems. Copyright © 2011 Elsevier B.V. All rights reserved.

Post-deposition-annealing effect on current conduction in Al2O3 films formed by atomic layer deposition with H2O oxidant

NASA Astrophysics Data System (ADS)

Hiraiwa, Atsushi; Matsumura, Daisuke; Okubo, Satoshi; Kawarada, Hiroshi

2017-02-01

Atomic-layer-deposition (ALD) Al2O3 films are promising as gate insulators of non-Si semiconductor devices. Although they allow relatively small leakage currents just after deposition, ALD Al2O3 films formed at low temperatures are subject to high temperature during fabrication or operation of devices. Therefore, the effect of post-deposition annealing (PDA) on the properties of Al2O3 films is investigated in this study. ALD Al2O3 films formed using H2O oxidant at low temperatures are compacted by PDA, but their mass density and dielectric constant remain approximately unchanged or slightly decrease owing to the desorption of methyl groups contained in the films as impurities. In accordance with these results, the wet etching rate of Al2O3 films is not much reduced by PDA. The conduction current in ALD Al2O3 films formed on Si is reduced by PDA and becomes smaller than that in films formed at the same ALD temperatures as those of PDA. The conduction current for PDA temperatures above 250 °C, however, increases and, accordingly, spoils the merit of low-temperature ALD. Therefore, given that the dielectric constant of annealed films remains low, high-temperature ALD is practically more significant than applying PDA to low-temperature ALD Al2O3 films from the viewpoint of leakage current under the same thermal budget. Space-charge-controlled field emission analysis revealed that, at the aforementioned threshold temperature, PDA abruptly increases the Al2O3/SiO2 interfacial dipoles and simultaneously reduces the amount of the positive charge near the interface. The so-called negative-charge buildup by PDA might be caused by this decrease in the positive charge.

Tensile and compressive creep behavior of extruded Mg–10Gd–3Y–0.5Zr (wt.%) alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, H.; The State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240; Wang, Q.D., E-mail: wangqudong@sjtu.edu.cn

2015-01-15

The tensile and compressive creep behavior of an extruded Mg–10Gd–3Y–0.5Zr (wt.%) alloy was investigated at temperatures ranging from 200 °C to 300 °C and under stresses ranging from 30 MPa to 120 MPa. There existed an asymmetry in the tensile and compressive creep properties. The minimum creep rate of the alloy was slightly greater in tension than in compression. The measured values of the transient strain and initial creep rate in compression were greater than those in tension. The creep stress exponent was approximately 2.5 at low temperatures (T < 250 °C) and 3.4 at higher temperatures both in tensionmore » and in compression. The compression creep activation energy at low temperatures and high temperatures was 83.4 and 184.3 kJ/mol respectively, while one activation energy (184 kJ/mol) represented the tensile–creep behavior over the temperature range examined. Dislocation creep was suggested to be the main mechanism in tensile creep and in the high-temperature regime in compressive creep, while grain boundary sliding was suggested to dominate in the low-temperature regime in compressive creep. Precipitate free zones were observed near grain boundaries perpendicular to the loading direction in tension and parallel to the loading direction in compression. Electron backscattered diffraction analysis revealed that the texture changed slightly during creep. Non-basal slip was suggested to contribute to the deformation after basal slip was introduced. In the tensile–creep ruptured specimens, intergranular cracks were mainly observed at general high-angle boundaries. - Highlights: • Creep behavior of an extruded Mg–RE alloy was characterized by EBSD. • T5 aging treatment enhanced the tension–compression creep asymmetry. • The grains grew slightly during tensile creep, but not for compressive creep. • Precipitate free zones (PFZs) were observed at specific grain boundaries. • Intergranular fracture was dominant and cracks mainly originated at GHABs.« less

Elevated temperature altered photosynthetic products in wheat seedlings and organic compounds and biological activity in rhizopshere soil under cadmium stress.

PubMed

Jia, Xia; Zhao, YongHua; Wang, WenKe; He, Yunhua

2015-09-23

The objective of this study was to investigate the effects of slightly elevated atmospheric temperature in the spring on photosynthetic products in wheat seedlings and on organic compounds and biological activity in rhizosphere soil under cadmium (Cd) stress. Elevated temperature was associated with increased soluble sugars, reducing sugars, starch, and total sugars, and with decreased amino acids in wheat seedlings under Cd stress. Elevated temperature improved total soluble sugars, free amino acids, soluble phenolic acids, and organic acids in rhizosphere soil under Cd stress. The activity of amylase, phenol oxidase, invertase, β-glucosidase, and l-asparaginase in rhizosphere soil was significantly improved by elevated temperature under Cd stress; while cellulase, neutral phosphatase, and urease activity significantly decreased. Elevated temperature significantly improved bacteria, fungi, actinomycetes, and total microorganisms abundance and fluorescein diacetate activity under Cd stress. In conclusion, slightly elevated atmospheric temperature in the spring improved the carbohydrate levels in wheat seedlings and organic compounds and biological activity in rhizosphere soil under Cd stress in the short term. In addition, elevated atmospheric temperature in the spring stimulated available Cd by affecting pH, DOC, phenolic acids, and organic acids in rhizosphere soil, which resulted in the improvement of the Cd uptake by wheat seedlings.

Elevated temperature altered photosynthetic products in wheat seedlings and organic compounds and biological activity in rhizopshere soil under cadmium stress

PubMed Central

Jia, Xia; Zhao, YongHua; Wang, WenKe; He, Yunhua

2015-01-01

The objective of this study was to investigate the effects of slightly elevated atmospheric temperature in the spring on photosynthetic products in wheat seedlings and on organic compounds and biological activity in rhizosphere soil under cadmium (Cd) stress. Elevated temperature was associated with increased soluble sugars, reducing sugars, starch, and total sugars, and with decreased amino acids in wheat seedlings under Cd stress. Elevated temperature improved total soluble sugars, free amino acids, soluble phenolic acids, and organic acids in rhizosphere soil under Cd stress. The activity of amylase, phenol oxidase, invertase, β-glucosidase, and l-asparaginase in rhizosphere soil was significantly improved by elevated temperature under Cd stress; while cellulase, neutral phosphatase, and urease activity significantly decreased. Elevated temperature significantly improved bacteria, fungi, actinomycetes, and total microorganisms abundance and fluorescein diacetate activity under Cd stress. In conclusion, slightly elevated atmospheric temperature in the spring improved the carbohydrate levels in wheat seedlings and organic compounds and biological activity in rhizosphere soil under Cd stress in the short term. In addition, elevated atmospheric temperature in the spring stimulated available Cd by affecting pH, DOC, phenolic acids, and organic acids in rhizosphere soil, which resulted in the improvement of the Cd uptake by wheat seedlings. PMID:26395070

Elevated temperature altered photosynthetic products in wheat seedlings and organic compounds and biological activity in rhizopshere soil under cadmium stress

NASA Astrophysics Data System (ADS)

Jia, Xia; Zhao, Yonghua; Wang, Wenke; He, Yunhua

2015-09-01

The objective of this study was to investigate the effects of slightly elevated atmospheric temperature in the spring on photosynthetic products in wheat seedlings and on organic compounds and biological activity in rhizosphere soil under cadmium (Cd) stress. Elevated temperature was associated with increased soluble sugars, reducing sugars, starch, and total sugars, and with decreased amino acids in wheat seedlings under Cd stress. Elevated temperature improved total soluble sugars, free amino acids, soluble phenolic acids, and organic acids in rhizosphere soil under Cd stress. The activity of amylase, phenol oxidase, invertase, β-glucosidase, and L-asparaginase in rhizosphere soil was significantly improved by elevated temperature under Cd stress; while cellulase, neutral phosphatase, and urease activity significantly decreased. Elevated temperature significantly improved bacteria, fungi, actinomycetes, and total microorganisms abundance and fluorescein diacetate activity under Cd stress. In conclusion, slightly elevated atmospheric temperature in the spring improved the carbohydrate levels in wheat seedlings and organic compounds and biological activity in rhizosphere soil under Cd stress in the short term. In addition, elevated atmospheric temperature in the spring stimulated available Cd by affecting pH, DOC, phenolic acids, and organic acids in rhizosphere soil, which resulted in the improvement of the Cd uptake by wheat seedlings.

Dissolution and aggregation of Cu nanoparticles in culture media: effects of incubation temperature and particles size

NASA Astrophysics Data System (ADS)

Li, Lingxiangyu; Fernández-Cruz, María Luisa; Connolly, Mona; Schuster, Michael; Navas, José María

2015-01-01

Here, the effects of incubation temperature and particle size on the dissolution and aggregation behavior of copper nanoparticles (CuNPs) in culture media were investigated over 96 h, equivalent to the time period for acute cell toxicity tests. Three CuNPs with the nominal sizes of 25, 50, and 100 nm and one type of micro-sized particles (MPs, 500 nm) were examined in culture media used for human and fish hepatoma cell lines acute tests. A large decrease in sizes of CuNPs in the culture media was observed in the first 24 h incubation, and subsequently the sizes of CuNPs changed slightly over the following 72 h. Moreover, the decreasing rate in size was significantly dependent on the incubation temperature; the higher the incubation temperature, the larger the decreasing rate in size. In addition to that, we also found that the release of copper ions depended on the incubation temperature. Moreover, the dissolution rate of Cu particles increased very fast in the first 24 h, with a slight increase over the following 72 h.

[Impact of introduction of O2 on the welding arc of gas pool coupled activating TIG].

PubMed

Huang, Yong; Wang, Yan-Lei; Zhang, Zhi-Guo

2014-05-01

In the present paper, Boltzmann plot method was applied to analyze the temperature distributions of the are plasma when the gas pool coupled activating TIG welding was at different coupling degrees with the outer gas being O2. Based on this study of temperature distributions, the changing regularities of are voltage and are appearance were studied. The result shows that compared with traditional TIG welding, the introduction of O2 makes the welding arc constricted slightly, the temperature of the are center build up, and the are voltage increase. When argon being the inner gas, oxygen serving as the outer gas instead of argon makes the are constricted more obviously. When the coupling degree increases from 0 to 2, the temperature of the are center and the are voltage both increase slightly. In the gas pool coupled activating TIG welding the are is constricted not obviously, and the reason why the weld penetration is improved dramatically in the welding of stainless steel is not are constriction.

Characterization of commercial supercapacitors for low temperature applications

NASA Astrophysics Data System (ADS)

Iwama, E.; Taberna, P. L.; Azais, P.; Brégeon, L.; Simon, P.

2012-12-01

Electrochemical characterizations at low temperature and floating tests have been performed on 600F commercial supercapacitor (SC) for acetonitrile (AN)-based and AN + methyl acetate (MA) mixed electrolytes. From -40 to +20 °C, AN electrolyte showed slightly higher capacitance than those of AN + MA mixed electrolytes (25 and 33 vol.% of MA). At -55 °C, however, AN electrolyte did not cycle at all, while MA mixed electrolyte normally cycled with a slight decrease in their capacitance. From electrochemical impedance spectroscopy measurements, the whole resistance for AN-based cells at -55 °C was found to be about 10,000 times higher than that of +20 °C, while a 40-fold increase in the cell resistance was obtained for the MA mixture between 20 and -55 °C. From the results of floating tests at 2.7 V and 60 °C for 1 month, the 25 vol.% MA mixture showed no change and slight decreased but stable capacitance.

Investigations on Heat Treatment of a High-Speed Steel Roll

NASA Astrophysics Data System (ADS)

Fu, Hanguang; Qu, Yinhu; Xing, Jiandong; Zhi, Xiaohui; Jiang, Zhiqiang; Li, Mingwei; Zhang, Yi

2008-08-01

High-carbon high-speed steels (HSS) are very abrasion-resistant materials primarily due to their high hardness MC-type carbide and high hardness martensitic matrix. The effects of quenching and tempering treatment on the microstructure, mechanical properties, and abrasion resistance of centrifugal casting high-carbon HSS roll were studied. Different microstructures and mechanical properties were obtained after the quenching and tempering temperatures of HSS roll were changed. With air-cooling and sodium silicate solution cooling, when the austenitizing temperature reaches 1273 K, the metallic matrix all transforms into the martensite. Afterwards, the eutectic carbides dissolve into the metallic matrix and their continuous network distribution changes into the broken network. The second hardening temperature of high-carbon HSS roll is around 793 K. No significant changes in tensile strength and elongation percentage are observed unless the tempering temperature is beyond 753 K. The tensile strength increases obviously and the elongation percentage decreases slightly beyond 753 K. However, the tensile strength decreases and the elongation percentage increases when the tempering temperature exceeds 813 K. When the tempering temperature excels 773 K, the impact toughness has a slight decrease. Tempering at 793-813 K, high-carbon HSS roll presents excellent abrasion resistance.

Longitudinal studies of Aedes aegypti (Diptera: Culicidae) in Thailand and Puerto Rico: blood feeding frequency.

PubMed

Scott, T W; Amerasinghe, P H; Morrison, A C; Lorenz, L H; Clark, G G; Strickman, D; Kittayapong, P; Edman, J D

2000-01-01

We used a histologic technique to study multiple blood feeding in a single gonotrophic cycle by engorged Aedes aegypti (L.) that were collected weekly for 2 yr from houses in a rural village in Thailand (n = 1,891) and a residential section of San Juan, Puerto Rico (n = 1,675). Overall, mosquitoes from Thailand contained significantly more multiple meals (n = 1,300, 42% double meals, 5% triple meals) than mosquitoes collected in Puerto Rico (n = 1,156, 32% double meals, 2% triple meals). The portion of specimens for which frequency of feeding could not be determined was 31% at both sites. We estimated that on average Ae. aegypti take 0.76 and 0.63 human blood meals per day in Thailand and Puerto Rico, respectively. However, frequency of multiple feeding varied among houses and, in Puerto Rico, the neighborhoods from which mosquitoes were collected. In Thailand 65% of the mosquitoes fed twice on the same day, whereas in Puerto Rico 57% took multiple meals separated by > or = 1 d. At both sites, the majority of engorged specimens were collected inside houses (Thailand 86%, Puerto Rico 95%). The number of blood meals detected was independent of where mosquitoes were collected (inside versus outside of the house) at both sites and the time of day collections were made in Puerto Rico. Feeding rates were slightly higher for mosquitoes collected in the afternoon in Thailand. Temperatures were significantly higher and mosquitoes significantly smaller in Thailand than in Puerto Rico. At both sites female size was negatively associated with temperature. Rates of multiple feeding were associated positively with temperature and negatively with mosquito size in Thailand, but not in Puerto Rico. Multiple feeding during a single gonotrophic cycle is a regular part of Ae. aegypti biology, can vary geographically and under different climate conditions, and may be associated with variation in patterns of dengue virus transmission.

Coherence between sedimentary leaf wax hydrogen isotopes and diatom assemblages from Lake E5 in northern Alaska

NASA Astrophysics Data System (ADS)

Daniels, W.; Russell, J. M.; Huang, Y.; Giblin, A.

2013-12-01

We present a 4500 year lacustrine record of compound-specific hydrogen isotopes (C28 alkanoic acid; δDwax) from the northern foothills of the Brooks Range, AK. This compound is characteristic of terrestrial plant leaf waxes and has been demonstrated to record variation in source water δD. The δDwax in our core varies between -265 and -254‰. We interpret more enriched values to reflect higher summer air temperatures. Using the relationship between δD-precipitation and temperature at the Barrow GNIP station, we calculate that temperature varied by 4.4 °C over this time span. Prior to 3.8 ka, summer temperatures were comparable to present day. There was a cooling trend from 3.8 to 1.5 ka followed by increasing temperatures until approximately 90 years ago. Slight cooling is seen in the surface-most sediments. This record is remarkably similar to a δ18O-cellulose record, interpreted to reflect changes in effective moisture, from nearby Meli Lake (Anderson et al. Quaternary Research 2001). Cool/wet and warm/dry are predominant weather conditions on an interannual basis in modern Alaska, and this appears to be the case over longer time scales through the late Holocene. We also examined the effect of temperature fluctuations on lake ecosystem structure by comparing sedimentary diatom assemblages to δDwax. The δDwax is positively correlated with the planktonic:benthic diatom ratio (r2=0.70). Experimental nutrient additions to Arctic lakes have resulted in increased planktonic production at the expense of benthic production, and so our result supports the hypothesis that lake nutrient budgets are linked to summer temperature in the region. The relative abundance of stratification-loving Cyclotella (Kutzing) Brebisson is positively correlated with δDwax (r2=0.40), while tachyplanktonic Aulacoseira Thwaites is negatively correlated with δDwax, (r2=0.55) supporting our interpretation of δDwax as a temperature signal.

Y-piece temperature and humidification during mechanical ventilation.

PubMed

Solomita, Mario; Daroowalla, Feroza; Leblanc, Deniese S; Smaldone, Gerald C

2009-04-01

Practitioners often presume there is adequate humidification in the ventilator circuit if the Y-piece is at a specified temperature, but control of Y-piece temperature may be inadequate to ensure adequate humidification. In an in vitro bench model we measured water-vapor delivery with several heated humidification setups and a wide range of minute volume (V (E)) values. The setup included a condenser, hygrometry, and thermometer. First, we calibrated the system with a point-source humidifier and water pump. Then we tested the water-vapor delivery during non-heated-wire humidification and during heated-wire humidification with a temperature gradient of +3 degrees C, 0 degrees C, and -3 degrees C between the humidifier and the Y-piece. We compared the results to 2 recommended humidification values: 100% saturated (absolute humidity 44 mg H(2)O/L) gas at 37 degrees C (saturated/37 degrees C); and 75% saturated (absolute humidity 33 mg H(2)O/L), which is the humidity recommended by the International Organization for Standardization (the ISO standard). In all the experiments the setup was set to provide 35 degrees C at the Y-piece. Our method for measuring water-vapor delivery closely approximated the amount delivered by a calibrated pump, but slightly underestimated the water-vapor delivery in all the experiments and the whole V (E) range. At all V (E) values, water-vapor delivery during non-heated-wire humidification matched or exceeded saturated/37 degrees C and was significantly greater than that during heated-wire humidification. During heated-wire humidification, water-vapor delivery varied with the temperature gradient and did not reach saturated/37 degrees C at V (E) > 6 L/min. Water-vapor delivery with the negative temperature gradient was below the ISO standard. Maintaining temperature at one point in the inspiratory circuit (eg, Y-piece), does not ensure adequate water-vapor delivery. Other factors (humidification system, V (E), gradient setting) are critical. At a given temperature, humidification may be significantly higher or lower than expected.

Effect of interface deformability on thermocapillary motion of a drop in a tube

NASA Astrophysics Data System (ADS)

Mahesri, S.; Haj-Hariri, H.; Borhan, A.

2014-03-01

The effect of an externally imposed axial temperature gradient on the mobility and deformation of a drop in an otherwise stagnant liquid within an insulated cylindrical tube is investigated. In the absence of bulk transport of momentum and energy, the boundary integral technique is used to obtain the flow and temperature fields inside and outside the deformable drop. The steady drop shapes and the corresponding migration velocities are examined over a wide range of the dimensionless parameters. The steady drop shape is nearly spherical for dimensionless drop sizes <0.5, but becomes slightly elongated in the axial direction for drop sizes comparable to tube diameter. The adverse effect of drop deformation on the effective temperature gradient driving the motion is slightly more pronounced than its favorable effect of reducing drag, thereby leading to a slight reduction in drop mobility with increasing drop deformation. Increasing the viscosity ratio reduces drop deformation and leads to a slight enhancement in the relative mobility (with respect to free thermocapillary motion) of confined drops. When the drop fluid has a lower thermal conductivity than the exterior phase, the presence of the thermally-insulating wall increases the thermal driving force for drop motion (compared to that for the same drop in unbounded domain) by causing more pronounced bending of the isotherms toward the drop. However, the favorable thermal effect of the confining wall is overwhelmed by its retarding hydrodynamic effect, causing the confined drop to always move slower than its unbounded counterpart regardless of the value of the thermal conductivity ratio.

Trends in monthly precipitation over the northwest of Iran (NWI)

NASA Astrophysics Data System (ADS)

Asakereh, Hossein

2017-10-01

Increasing global temperatures during the last century have had their own effects on other climatic conditions, particularly on precipitation characteristics. This study was meant to investigate the spatial and temporal monthly trends of precipitation using the least square error (LSE) approach for the northwest of Iran (NWI). To this end, a database was obtained from 250 measuring stations uniformly scattered all over NWI from 1961 to 2010. The spatial average of annual precipitation in NWI during the period of study was approximately 220.9-726.7 mm. The annual precipitation decreased from southwest to northeast, while the large amount of precipitation was concentrated in the south-west and in the mountainous areas. All over NWI, the maximum and minimum precipitation records occurred from March to May and July to September, respectively. The coefficient of variation (CV) is greater than 44 % in all of NWI and may reach over 76 % in many places. The greatest range of CV, for instance, occurred during July. The spatial variability of precipitation was consistent with a tempo-spatial pattern of precipitation trends. There was a considerable difference between the amounts of change during the months, and the negative trends were mainly attributed to areas concentrated in eastern and southern parts of NWI far from the western mountain ranges. Moreover, limited areas with positive precipitation trends can be found in very small and isolated regions. This is observable particularly in the eastern half of NWI, which is mostly located far from Westerlies. On the other hand, seasonal precipitation trends indicated a slight decrease during winter and spring and a slight increase during summer and autumn. Consequently, there were major changes in average precipitation that occurred negatively in the area under study during the observation period. This finding is in agreement with those findings by recent studies which revealed a decreasing trend of around 2 mm/year over NWI during 1966-2005.

Early Spring in Europe: A Result of More Dominant North-Atlantic Southwesterlies?

NASA Technical Reports Server (NTRS)

Otterman, J.; Atlas, R.; Chase, T. N.; Chou, S.-H.; Jusem, J. C.; Pielke, R. A., Sr.; Rogers, J.; Russell, G. L.; Schubert, S. D.; Sud, Y. C.;

Rolled-up nanotechnology for the fabrication of three-dimensional fishnet-type GaAs-metal metamaterials with negative refractive index at near-infrared frequencies

NASA Astrophysics Data System (ADS)

Rottler, Andreas; Harland, Malte; Bröll, Markus; Schwaiger, Stephan; Stickler, Daniel; Stemmann, Andrea; Heyn, Christian; Heitmann, Detlef; Mendach, Stefan

2012-04-01

We propose and demonstrate the fabrication of a three-dimensional fishnet metamaterial by utilizing rolled-up nanotechnology. It consists of 6 alternating layers of silver and (In)GaAs with an array of subwavelength holes "drilled" by focused ion beams. By means of finite-integration technique simulations, we show that the fabricated structure is a single-negative material possessing a negative real part of the refractive index in the near-infrared regime. We show that the fabricated material can be made double negative by slightly changing the size of the holes.

Resistance of a northwestern crayfish, Pacifastacus leniusculus (Dana), to elevated temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Becker, C.D.; Genoway, R.G.; Merrill, J.A.

1975-04-01

Pacifastacus leniusculus from two populations in Washington State, the central Columbia River and a small tributary, were acclimated at 5/sup 0/C intervals and exposed to elevated temperatures in 48 hour thermal bioassays. The upper lethal temperature for both crayfish populations increased relatively slightly, from about 28.5 to 31.5/sup 0/C, over the entire acclimation range. A rise of 1/sup 0/C in test temperature often represented the difference between zero and total mortality when lethal limits were approached. The ultimate upper lethal temperature was near 32 to 33/sup 0/C. Statistically significant differences in thermal resistance patterns (slope and spacing of regression lines)more » occurred between the two crayfish populations at all acclimation levels, but resistance in terms of eventual mortality was similar for practical purposes. Moulting individuals were particularly susceptible to high temperature stress. Mature, pre-breeding female crayfish from the Columbia River during fall appeared less resistant, and egg-bearing females during winter more resistant, than other individuals. Larger crayfish from the Columbia River were slightly less resistant to elevated temperatures than smaller ones, and females were more resistant than males. The upper temperature triangle for P. leniusculus encompasses an area of 424/sup 0/C/sup 2/. This freshwater decapod is more tolerant of elevated temperatures than native salmonids, but less tolerant than some introduced ''warmwater'' fish.« less

PVC biodeterioration and DEHP leaching by DEHP-degrading bacteria

PubMed Central

Latorre, Isomar; Hwang, Sangchul; Sevillano, Maria; Montalvo-Rodriguez, Rafael

2012-01-01

Newly isolated, not previously reported, di-(2-ethylhexyl) phthalate (DEHP)-degraders were augmented to assess their role in polyvinyl chloride (PVC) shower curtain deterioration and DEHP leaching. The biofilms that developed on the surfaces of the bioaugmented shower curtains with Gram-positive strains LHM1 and LHM2 were thicker than those of the biostimulated and Gram-negative strain LHM3-augmented shower curtains. The first derivative thermogravimetric (DTG) peaks of the bioaugmented shower curtains with the Gram-positive bacteria were observed at ~287°C, whereas the control and Gram-negative strain LHM3-augmented shower curtains were detected at ~283°C. This slight delay in the first DTG peak temperature is indicative of lower plasticizer concentrations in the shower curtains that were bioaugmented with Gram positive bacteria. Despite bioaugmentation with DEHP-degraders, aqueous solutions of the bioaugmentation reactors were not DEHP-free due probably to the presence of co-solutes that must have supported microbial growth. Generally, the bioaugmented reactors with the Gram-positive strains LHM1 and LHM2 had greater aqueous DEHP concentrations in the first-half (<3 wk) of the biodeterioration experiment than the biostimulated and strain LHM3-augmented reactors. Therefore, strains LHM1 and LHM2 may play an important role in DEHP leaching to the environment and PVC biodeterioration. PMID:22736894

Effect of a central redistribution of fluid volume on response to lower-body negative pressure

NASA Technical Reports Server (NTRS)

Tomaselli, Clare M.; Frey, Mary A. B.; Kenney, Richard A.; Hoffler, G. Wyckliffe

1990-01-01

Cardiovascular responses to lower-body negative pressure (LBNP) were studied following 1 hour of 6-deg head-down tilt to determine whether a redistribution of blood volume toward the central circulation modifies the subsequent response to orthostatic stress. Responses of 12 men, ages 30-39 years, were evaluated by electrocardiography, impedance cardiography, sphygmomanometry, and measurement of calf circumference. During the LBNP that followed head-down tilt, as compared with control LBNP (no preceding head-down tilt) subjects, had smaller stroke volume and cardiac output, greater total peripheral resistance, and less calf enlargement. These differences reflect differences in the variables immediately preceding LBNP. Magnitudes of the responses from pre-LBNP to each pressure stage of the LBNP procedure did not differ between protocols. Mean and diastolic arterial pressures were slightly elevated after LBNP-control, but they fell slightly during LBNP post-tilt.

Effects of Storage Temperature and Semen Extender on Stored Canine Semen

PubMed Central

HORI, Tatsuya; YOSHIKUNI, Ryuta; KOBAYASHI, Masanori; KAWAKAMI, Eiichi

2013-01-01

ABSTRACT The objective of the present study was to determine an optimum temperature and extender for short-term transport of canine ejaculated semen. There was no significant difference in the qualities of semen diluted with two kinds of extender, egg yolk Tris-citrate fructose (EYT-FC) or glucose (EYT-GC) extender, between the 2, 8 or 12 and the 4°C control groups during storage for up to 48 hr, while the 16–24°C groups showed decreased sperm motility during storage for 48 hr. However, the 2°C group showed slightly lower sperm motility and slightly higher sperm abnormality than the 4°C group. Therefore, we concluded that semen qualities can be maintained for up to 48 hr when canine semen samples are extended with EYT-FC or EYT-GC and stored at a temperature in the range of 4–12°C. PMID:24088408

Strength advantages of chemically polished boron fibers before and after reaction with aluminum

NASA Technical Reports Server (NTRS)

Dicarlo, J. A.; Smith, R. J.

1982-01-01

In order to determine their strength potential, the fracture properties of different types of commercial boron fibers were measured before and after application of secondary strengthening treatments. The principal treatments employed were a slight chemical polish, which removed low strength surface flaws, and a heat treatment in oxygen, which contracted the fibers and thereby compressed intrinsic bulk flaws. Those fiber types most significantly strengthened were 200 to 400 micrometers (8 to 16 mil) diameter boron on tungsten fibers produced in a single chemical vapor deposition reactor. The slight polish increased average tensile strenghts from 3.4 to 4.4 CN/m2 (500 to 640 ksi) and reduced coefficients of variation from about 15 to 3 percent. The oxygen heat treatment plus slight polish further improved average strengths to 5.5 GN/m2 (800 ksi) with coefficients near 3 percent. To ascertain whether these excellent properties could be retained after fabrication of B/Al composites, as produced and polished 203 micrometers (8 mil) fibers were thinly coated with aluminum, heat treated at B/Al fabrication temperatures, and then tested in tension and flexure at room temperature. The pre-polished fibers were observed to retain their superior strengths to higher temperatures than the as-produced fibers even though both were subjected to the same detrimental reaction with aluminum.

Relative Abundance of Nitrotoga spp. in a Biofilter of a Cold-Freshwater Aquaculture Plant Appears To Be Stimulated by Slightly Acidic pH

PubMed Central

Hüpeden, Jennifer; Wegen, Simone; Off, Sandra; Lücker, Sebastian; Bedarf, Yvonne; Daims, Holger; Kühn, Carsten

2016-01-01

The functioning of recirculation aquaculture systems (RAS) is essential to maintain water quality for fish health, and one crucial process here is nitrification. The investigated RAS was connected to a rainbow trout production system and operated at an average temperature of 13°C and pH 6.8. Community analyses of the nitrifying biofilm revealed a coexistence of Nitrospira and Nitrotoga, and it is hypothesized that a slightly acidic pH in combination with lower temperatures favors the growth of the latter. Modification of the standard cultivation approach toward lower pH values of 5.7 to 6.0 resulted in the successful enrichment (99% purity) of Nitrotoga sp. strain HW29, which had a 16S rRNA sequence similarity of 99.0% to Nitrotoga arctica. Reference cultures of Nitrospira defluvii and the novel Nitrotoga sp. HW29 were used to confirm differentiation of these nitrite oxidizers in distinct ecological niches. Nitrotoga sp. HW29 revealed pH and temperature optima of 6.8 and 22°C, respectively, whereas Nitrospira defluvii displayed the highest nitrite oxidation rate at pH 7.3 and 32°C. We report here the occurrence of Nitrotoga as one of the main nitrite-oxidizing bacteria in freshwater aquaculture systems and indicate that a slightly acidic pH, in addition to temperatures below 20°C, can be applied as a selective isolation criterion for this microorganism. PMID:26746710

Electron attachment and positive ion chemistry of monohydrogenated fluorocarbon radicals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wiens, Justin P.; Shuman, Nicholas S.; Miller, Thomas M.

Rate coefficients and product branching fractions for electron attachment and for reaction with Ar{sup +} are measured over the temperature range 300–585 K for three monohydrogenated fluorocarbon (HFC) radicals (CF{sub 3}CHF, CHF{sub 2}CF{sub 2}, and CF{sub 3}CHFCF{sub 2}), as well as their five closed-shell precursors (1-HC{sub 2}F{sub 4}I, 2-HC{sub 2}F{sub 4}I, 2-HC{sub 2}F{sub 4}Br, 1-HC{sub 3}F{sub 6}I, 2-HC{sub 3}F{sub 6}Br). Attachment to the HFC radicals is always fairly inefficient (between 0.1% and 10% of the Vogt–Wannier capture rate), but generally faster than attachment to analogous perfluorinated carbon radicals. The primary products in all cases are HF-loss to yield C{sub n}F{submore » m−1}{sup −} anions, with only a minor branching to F{sup −} product. In all cases the temperature dependences are weak. Attachment to the precursor halocarbons is near the capture rate with a slight negative temperature dependence in all cases except for 2-HC{sub 2}F{sub 4}Br, which is ∼10% efficient at 300 K and becomes more efficient, approaching the capture rate at higher temperatures. All attachment kinetics are successfully reproduced using a kinetic modeling approach. Reaction of the HFC radicals with Ar{sup +} proceeds at or near the calculated collisional rate coefficient in all cases, yielding a wide variety of product ions.« less

Selected contribution: ambient temperature for experiments in rats: a new method for determining the zone of thermal neutrality.

PubMed

Romanovsky, Andrej A; Ivanov, Andrei I; Shimansky, Yury P

2002-06-01

There is a misbelief that the same animal has the same thermoneutral zone (TNZ) in different experimental setups. In reality, TNZ strongly depends on the physical environment and varies widely across setups. Current methods for determining TNZ require elaborate equipment and can be applied only to a limited set of experimental conditions. A new, broadly applicable approach that rapidly determines whether given conditions are neutral for a given animal is needed. Consistent with the definition of TNZ [the range of ambient temperature (T(a)) at which body core temperature (T(c)) regulation is achieved only by control of sensible heat loss], we propose three criteria of thermoneutrality: 1) the presence of high-magnitude fluctuations in skin temperature (T(sk)) of body parts serving as specialized heat exchangers with the environment (e.g., rat tail), 2) the closeness of T(sk) to the median of its operational range, and 3) a strong negative correlation between T(sk) and T(c). Thermocouple thermometry and liquid crystal thermography were performed in five rat strains at 13 T(a). Under the conditions tested (no bedding or filter tops, no group thermoregulation), the T(a) range of 29.5-30.5 degrees C satisfied all three TNZ criteria in Wistar, BDIX, Long-Evans, and Zucker lean rats; Zucker fatty rats had a slightly lower TNZ (28.0-29.0 degrees C). Skin thermometry or thermography is a definition-based, simple, and inexpensive technique to determine whether experimental or housing conditions are neutral, subneutral, or supraneutral for a given animal.

Slight temperature changes affect protein affinity and cellular uptake/toxicity of nanoparticles

NASA Astrophysics Data System (ADS)

Mahmoudi, Morteza; Shokrgozar, Mohammad A.; Behzadi, Shahed

2013-03-01

It is known that what the cell actually ``sees'' at the nanoscale is an outer shell formed of `protein corona' on the surface of nanoparticles (NPs). The amount and composition of various proteins on the corona are strongly dependent on the biophysicochemical properties of NPs, which have been extensively studied. However, the effect of a small variation in temperature, due to the human circadian rhythm, on the composition of the protein corona and the affinity of various proteins to the surface of NPs, was ignored. Here, the effect of temperature on the composition of protein corona and the affinity of various proteins to the surface of NPs and, subsequently, cell responses to the protein coated NPs are probed. The results confirmed that cellular entrance, dispersion, and toxicity of NPs are strongly diverse with slight body temperature changes. This new finding can help scientists to maximise NP entrance to specific cells/organs with lower toxicity by adjusting the cellular/organ temperature.It is known that what the cell actually ``sees'' at the nanoscale is an outer shell formed of `protein corona' on the surface of nanoparticles (NPs). The amount and composition of various proteins on the corona are strongly dependent on the biophysicochemical properties of NPs, which have been extensively studied. However, the effect of a small variation in temperature, due to the human circadian rhythm, on the composition of the protein corona and the affinity of various proteins to the surface of NPs, was ignored. Here, the effect of temperature on the composition of protein corona and the affinity of various proteins to the surface of NPs and, subsequently, cell responses to the protein coated NPs are probed. The results confirmed that cellular entrance, dispersion, and toxicity of NPs are strongly diverse with slight body temperature changes. This new finding can help scientists to maximise NP entrance to specific cells/organs with lower toxicity by adjusting the cellular/organ temperature. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr32551b

The Chamber for Studying Rice Response to Elevated Nighttime Temperature in Field

PubMed Central

Chen, Song; Zheng, Xi; Wang, Dangying; Xu, Chunmei; Laza, Ma. Rebecca C.; Zhang, Xiufu

2013-01-01

An in situ temperature-controlled field chamber was developed for studying a large population of rice plant under different nighttime temperature treatments while maintaining conditions similar to those in the field during daytime. The system consists of a pipe hoop shed-type chamber with manually removable covers manipulated to provide a natural environment at daytime and a relatively stable and accurate temperature at night. Average air temperatures of 22.4 ± 0.3°C at setting of 22°C, 27.6 ± 0.4°C at 27°C, and 23.8 ± 0.7°C ambient conditions were maintained with the system. No significant horizontal and vertical differences in temperature were found and only slight changes in water temperatures were observed between the chambers and ambient conditions at 36 days after transplanting. A slight variation in CO2 concentration was observed at the end of the treatment during the day, but the 10-μmol CO2 mol−1 difference was too small to alter plant response. The present utilitarian system, which only utilizes an air conditioner/heater, is suitable for studying the effect of nighttime temperature on plant physiological responses with minimal perturbation of other environmental factors. At the same time, it will enable in situ screening of many rice genotypes. PMID:24089603

The wet solidus of silica: predictions from the scaled particle theory and polarized continuum model.

PubMed

Ottonello, G; Richet, P; Vetuschi Zuccolini, M

2015-02-07

We present an application of the Scaling Particle Theory (SPT) coupled with an ab initio assessment of the electronic, dispersive, and repulsive energy terms based on the Polarized Continuum Model (PCM) aimed at reproducing the observed solubility behavior of OH2 over the entire compositional range from pure molten silica to pure water and wide pressure and temperature regimes. It is shown that the solution energy is dominated by cavitation terms, mainly entropic in nature, which cause a large negative solution entropy and a consequent marked increase of gas phase fugacity with increasing temperatures. Besides, the solution enthalpy is negative and dominated by electrostatic terms which depict a pseudopotential well whose minimum occurs at a low water fraction (XH2O) of about 6 mol. %. The fine tuning of the solute-solvent interaction is achieved through very limited adjustments of the electrostatic scaling factor γel which, in pure water, is slightly higher than the nominal value (i.e., γel  =  1.224 against 1.2), it attains its minimum at low H2O content (γel = 0.9958) and then rises again at infinite dilution (γel   =  1.0945). The complex solution behavior is interpreted as due to the formation of energetically efficient hydrogen bonding when OH functionals are in appropriate amount and relative positioning with respect to the discrete OH2 molecules, reinforcing in this way the nominal solute-solvent inductive interaction. The interaction energy derived from the SPT-PCM calculations is then recast in terms of a sub-regular Redlich-Kister expansion of appropriate order whereas the thermodynamic properties of the H2O component at its standard state (1-molal solution referred to infinite dilution) are calculated from partial differentiation of the solution energy over the intensive variables.

Net Community Production in the East Coastal waters of the United States from Oxygen to Argon Ratios

NASA Astrophysics Data System (ADS)

Gao, Y.; Cai, W. J.; Collins, A. L.; Jonsson, B.; Salisbury, J.

2016-02-01

The increase in anthropogenic nutrient input may enhance phytoplankton biomass and their photosynthesis may cause oxygen supersaturation in euphotic zone; while organic matter input from land to sea and decomposition during transportation may lead to oxygen undersaturation. Net community production (NCP) reflects the net outcome between photosynthesis and respiration. Our current understating of NCP mainly relies on bottle incubation and satellite data analysis, which may cause bias in the large area of coastal water. To improve our understanding in the east coast of the United States (25°N to 45 °N) from an integrated perspective, we conducted continuous onboard determination of oxygen (O2) to argon (Ar) ratios in order to separate biological activity from physical mixing effects during June to July 2015 as part of the NOAA East Coast Ocean Acidification (ECOA) investigation. Biological driven O2 supersaturation was derived from difference of O2/Ar in water away from the equilibrium status using equilibrator inlet mass spectrometer. Temperature changed 5°C to 30°C from north to south, and salinity ranged from 20 in the shore region (e.g. inside of Chesapeake Bay) to 36 in offshore water. Photosynthesis (positive NCP) was the dominant process in the Gulf of Maine and in lower Chesapeake Bay due to the re-occurring phytoplankton blooms. In response to large amount of terrestrial organic matter input and quick remineralization at temperature of 20-25°C, respiration (negative NCP) were often observed in the Block Island sound, Delaware Bay mouth and Chesapeake Bay mouth. In the warm subtropics gyre, NCP was slightly negative that may be related to nutrient deficiency and low organic matter input.

Climate change and potato cropping in the Peruvian Altiplano

NASA Astrophysics Data System (ADS)

Sanabria, J.; Lhomme, J. P.

2013-05-01

The potential impacts of climate change on potatoes cropping in the Peruvian highlands (Altiplano) is assessed using climate projections for 2071-2100, obtained from the HadRM3P regional atmospheric model of the Hadley Centre. The atmospheric model is run under two different special report on emission scenarios: high CO2 concentration (A2) and moderate CO2 concentration (B2) for four locations situated in the surroundings of Lake Titicaca. The two main varieties of potato cultivated in the area are studied: the Andean potato ( Solanum tuberosum) and the bitter potato ( Solanum juzepczukii). A simple process-oriented model is used to quantify the climatic impacts on crops cycles and yields by combining the effects of temperature on phenology, of radiation and CO2 on maximum yield and of water balance on yield deficit. In future climates, air temperature systematically increases, precipitation tends to increase at the beginning of the rainy season and slightly decreases during the rest of the season. The direct effects of these climatic changes are earlier planting dates, less planting failures and shorter crop cycles in all the four locations and for both scenarios. Consequently, the harvesting dates occur systematically earlier: roughly in January for the Andean potato instead of March in the current situation and in February for the bitter potato instead of April. Overall, yield deficits will be higher under climate change than in the current climate. There will be a strong negative impact on yields for S. tuberosum (stronger under A2 scenario than under B2); the impact on S. juzepczukii yields, however, appears to be relatively mixed and not so negative.

An evaluation of a zero-heat-flux cutaneous thermometer in cardiac surgical patients.

PubMed

Eshraghi, Yashar; Nasr, Vivian; Parra-Sanchez, Ivan; Van Duren, Albert; Botham, Mark; Santoscoy, Thomas; Sessler, Daniel I

2014-09-01

Although core temperature can be measured invasively, there are currently no widely available, reliable, noninvasive thermometers for its measurement. We thus compared a prototype zero-heat-flux thermometer with simultaneous measurements from a pulmonary artery catheter. Specifically, we tested the hypothesis that zero-heat-flux temperatures are sufficiently accurate for routine clinical use. Core temperature was measured from the thermistor of a standard pulmonary artery catheter and with a prototype zero-heat-flux deep-tissue thermometer in 105 patients having nonemergent cardiac surgery. Zero-heat-flux probes were positioned on the lateral forehead and lateral neck. Skin surface temperature probes were attached to the forehead just adjacent to the zero-heat-flux probe. Temperatures were recorded at 1-minute intervals, excluding the period of cardiopulmonary bypass, and for the first 4 postoperative hours. Zero-heat-flux and pulmonary artery temperatures were compared with bias analysis; differences exceeding 0.5°C were considered to be potentially clinically important. The mean duration in the operating room was 279 ± 75 minutes, and the mean cross-clamp time was 118 ± 50 minutes. All subjects were monitored for an additional 4 hours in the intensive care unit. The average overall difference between forehead zero-heat-flux and pulmonary artery temperatures (i.e., forehead minus pulmonary artery) was -0.23°C (95% limits of agreement of ±0.82); 78% of the differences were ≤0.5°C. The average intraoperative temperature difference was -0.08°C (95% limits of agreement of ±0.88); 84% of the differences were ≤0.5°C. The average postoperative difference was -0.32°C (95% limits of agreement of ±0.75); 84% of the differences were ≤0.5°C. Bias and precision values for neck site were similar to the forehead values. Uncorrected forehead skin temperature showed an increasing negative bias as core temperature decreased. Core temperature can be noninvasively measured using the zero-heat-flux method. Bias was small, but precision was slightly worse than our designated 0.5°C limits compared with measurements from a pulmonary artery catheter.

The influence of surface roughness on volatile transport on the Moon

NASA Astrophysics Data System (ADS)

Prem, P.; Goldstein, D. B.; Varghese, P. L.; Trafton, L. M.

2018-01-01

The Moon and other virtually airless bodies provide distinctive environments for the transport and sequestration of water and other volatiles delivered to their surfaces by various sources. In this work, we conduct Monte Carlo simulations of water vapor transport on the Moon to investigate the role of small-scale roughness (unresolved by orbital measurements) in the migration and cold-trapping of volatiles. Observations indicate that surface roughness, combined with the insulating nature of lunar regolith and the absence of significant exospheric heat flow, can cause large variations in temperature over very small scales. Surface temperature has a strong influence on the residence time of migrating water molecules on the lunar surface, which in turn affects the rate and magnitude of volatile transport to permanently shadowed craters (cold traps) near the lunar poles, as well as exospheric structure and the susceptibility of migrating molecules to photodestruction. Here, we develop a stochastic rough surface temperature model suitable for simulations of volatile transport on a global scale, and compare the results of Monte Carlo simulations of volatile transport with and without the surface roughness model. We find that including small-scale temperature variations and shadowing leads to a slight increase in cold-trapping at the lunar poles, accompanied by a slight decrease in photodestruction. Exospheric structure is altered only slightly, primarily at the dawn terminator. We also examine the sensitivity of our results to the temperature of small-scale shadows, and the energetics of water molecule desorption from the lunar regolith - two factors that remain to be definitively constrained by other methods - and find that both these factors affect the rate at which cold trap capture and photodissociation occur, as well as exospheric density and longevity.

Association between fluid intake and mortality in critically ill patients with negative fluid balance: a retrospective cohort study.

PubMed

Shen, Yanfei; Huang, Xinmei; Zhang, Weimin

2017-05-12

Compared to positive fluid balance (FB), negative FB is associated with improved clinical outcomes in critically ill patients. However, as to whether achieving more negative FB can further improve outcomes has not been investigated. This study aimed to investigate whether more negative FB and restricted fluid intake were associated with improved outcomes in critically ill patients. Data were extracted from the Multi-parameter Intelligent Monitoring in Intensive Care III Database. Patients achieving negative FB at 48 hours after intensive care unit (ICU) admission were screened. The primary outcome was hospital mortality. Logistic models were built to explore the association between FB, fluid intake and mortality, using FB and fluid intake (both four levels) as design variables and using the linear spline function method. There were 2068 patients meeting the inclusion criteria. Compared to slight negative FB (level 1), there was a decreased tendency towards mortality with FB level 2 (OR 0.88, 95% CI 0.69-1.11) and level 3 (OR 0.79, 95% CI 0. 65-1.11); however, only extreme negative FB (level 4) was significant (OR 0.56, 95% CI 0. 33-0.95). Fluid intake and urine output were evenly distributed over the first 48 hours after ICU admission. Fluid intake was inversely associated with hospital mortality, with the OR decreased stepwise from level 2 (OR 0.73, 95% CI 0.56-0.96) to level 4 (OR 0.47, 95% CI 0.30-0.74), referred to level 1. Urine output also showed a similar pattern. Diuretic use was associated with higher mortality in both models. In critically ill patients with negative FB, both increased fluid intake and urine output were associated with decreased hospital mortality. However, compared to slight FB, achieving more negative FB was not associated with reduced mortality.

Statistical thermodynamics of quantum Brownian motion: Construction of perpetuum mobile of the second kind

NASA Astrophysics Data System (ADS)

Nieuwenhuizen, Th. M.; Allahverdyan, A. E.

2002-09-01

The Brownian motion of a quantum particle in a harmonic confining potential and coupled to harmonic quantum thermal bath is exactly solvable. Though this system presents at high temperatures a pedagogic example to explain the laws of thermodynamics, it is shown that at low enough temperatures the stationary state is non-Gibbsian due to an entanglement with the bath. In physical terms, this happens when the cloud of bath modes around the particle starts to play a nontrivial role, namely, when the bath temperature T is smaller than the coupling energy. Indeed, equilibrium thermodynamics of the total system, particle plus bath, does not imply standard equilibrium thermodynamics for the particle itself at low T. Various formulations of the second law are found to be invalid at low T. First, the Clausius inequality can be violated, because heat can be extracted from the zero point energy of the cloud of bath modes. Second, when the width of the confining potential is suddenly changed, there occurs a relaxation to equilibrium during which the entropy production is partly negative. In this process the energy put on the particle does not relax monotonically, but oscillates between particle and bath, even in the limit of strong damping. Third, for nonadiabatic changes of system parameters the rate of energy dissipation can be negative, and, out of equilibrium, cyclic processes are possible which extract work from the bath. Conditions are put forward under which perpetuum mobility of the second kind, having one or several work extraction cycles, enter the realm of condensed matter physics. Fourth, it follows that the equivalence between different formulations of the second law (e.g., those by Clausius and Thomson) can be violated at low temperatures. These effects are the consequence of quantum entanglement in the presence of the slightly off-equilibrium nature of the thermal bath, and become important when the characteristic quantum time scale ħ/kBT is larger than or comparable to other time scales of the system. They show that there is no general consensus between standard thermodynamics and quantum mechanics. The known agreements occur only due to the weak coupling limit, which does not pertain to low temperatures. Experimental setups for testing the effects are discussed.

Statistical thermodynamics of quantum Brownian motion: construction of perpetuum mobile of the second kind.

PubMed

Nieuwenhuizen, Th M; Allahverdyan, A E

2002-09-01

The Brownian motion of a quantum particle in a harmonic confining potential and coupled to harmonic quantum thermal bath is exactly solvable. Though this system presents at high temperatures a pedagogic example to explain the laws of thermodynamics, it is shown that at low enough temperatures the stationary state is non-Gibbsian due to an entanglement with the bath. In physical terms, this happens when the cloud of bath modes around the particle starts to play a nontrivial role, namely, when the bath temperature T is smaller than the coupling energy. Indeed, equilibrium thermodynamics of the total system, particle plus bath, does not imply standard equilibrium thermodynamics for the particle itself at low T. Various formulations of the second law are found to be invalid at low T. First, the Clausius inequality can be violated, because heat can be extracted from the zero point energy of the cloud of bath modes. Second, when the width of the confining potential is suddenly changed, there occurs a relaxation to equilibrium during which the entropy production is partly negative. In this process the energy put on the particle does not relax monotonically, but oscillates between particle and bath, even in the limit of strong damping. Third, for nonadiabatic changes of system parameters the rate of energy dissipation can be negative, and, out of equilibrium, cyclic processes are possible which extract work from the bath. Conditions are put forward under which perpetuum mobility of the second kind, having one or several work extraction cycles, enter the realm of condensed matter physics. Fourth, it follows that the equivalence between different formulations of the second law (e.g., those by Clausius and Thomson) can be violated at low temperatures. These effects are the consequence of quantum entanglement in the presence of the slightly off-equilibrium nature of the thermal bath, and become important when the characteristic quantum time scale variant Planck's over 2pi /k(B)T is larger than or comparable to other time scales of the system. They show that there is no general consensus between standard thermodynamics and quantum mechanics. The known agreements occur only due to the weak coupling limit, which does not pertain to low temperatures. Experimental setups for testing the effects are discussed.

Glutamate Induced Thermal Equilibrium Intermediate and Counteracting Effect on Chemical Denaturation of Proteins.

PubMed

Anumalla, Bramhini; Prabhu, N Prakash

2018-01-25

When organisms are subjected to stress conditions, one of their adaptive responses is accumulation of small organic molecules called osmolytes. These osmolytes affect the structure and stability of the biological macromolecules including proteins. The present study examines the effect of a negatively charged amino acid osmolyte, glutamate (Glu), on two model proteins, ribonuclease A (RNase A) and α-lactalbumin (α-LA), which have positive and negative surface charges at pH 7, respectively. These proteins follow two-state unfolding transitions during both heat and chemical induced denaturation processes. The addition of Glu stabilizes the proteins against temperature and induces an early equilibrium intermediate during unfolding. The stability is found to be enthalpy-driven, and the free energy of stabilization is more for α-LA compared to RNase A. The decrease in the partial molar volume and compressibility of both of the proteins in the presence of Glu suggests that the proteins attain a more compact state through surface hydration which could provide a more stable conformation. This is also supported by molecule dynamic simulation studies which demonstrate that the water density around the proteins is increased upon the addition of Glu. Further, the intermediates could be completely destabilized by lower concentrations (∼0.5 M) of guanidinium chloride and salt. However, urea subverts the Glu-induced intermediate formed by α-LA, whereas it only slightly destabilizes in the case of RNase A which has a positive surface charge and could possess charge-charge interactions with Glu. This suggests that, apart from hydration, columbic interactions might also contribute to the stability of the intermediate. Gdm-induced denaturation of RNase A and α-LA in the absence and the presence of Glu at different temperatures was carried out. These results also show the Glu-induced stabilization of both of the proteins; however, all of the unfolding transitions followed two-state transitions during chemical denaturation. The extent of stability exerted by Glu is higher for RNase A at higher temperature, whereas it provides more stability for α-LA at lower temperature. Thus, the experiments indicate that Glu induces a thermal equilibrium intermediate and increases the thermodynamic stability of proteins irrespective of their surface charges. The extent of stability varies between the proteins in a temperature-dependent manner.

Impacts of climate change on rice production in Africa and causes of simulated yield changes.

PubMed

van Oort, Pepijn A J; Zwart, Sander J

2018-03-01

This study is the first of its kind to quantify possible effects of climate change on rice production in Africa. We simulated impacts on rice in irrigated systems (dry season and wet season) and rainfed systems (upland and lowland). We simulated the use of rice varieties with a higher temperature sum as adaptation option. We simulated rice yields for 4 RCP climate change scenarios and identified causes of yield declines. Without adaptation, shortening of the growing period due to higher temperatures had a negative impact on yields (-24% in RCP 8.5 in 2070 compared with the baseline year 2000). With varieties that have a high temperature sum, the length of the growing period would remain the same as under the baseline conditions. With this adaptation option rainfed rice yields would increase slightly (+8%) but they remain subject to water availability constraints. Irrigated rice yields in East Africa would increase (+25%) due to more favourable temperatures and due to CO2 fertilization. Wet season irrigated rice yields in West Africa were projected to change by -21% or +7% (without/with adaptation). Without adaptation irrigated rice yields in West Africa in the dry season would decrease by -45% with adaptation they would decrease significantly less (-15%). The main cause of this decline was reduced photosynthesis at extremely high temperatures. Simulated heat sterility hardly increased and was not found a major cause for yield decline. The implications for these findings are as follows. For East Africa to benefit from climate change, improved water and nutrient management will be needed to benefit fully from the more favourable temperatures and increased CO2 concentrations. For West Africa, more research is needed on photosynthesis processes at extreme temperatures and on adaptation options such as shifting sowing dates. © 2017 The Authors. Global Change Biology Published by John Wiley & Sons Ltd.

Climatic Implications of the Observed Temperature Dependence of the Liquid Water Path of Low Clouds in the Southern Great Plains

NASA Technical Reports Server (NTRS)

DelGenio, Anthony

1999-01-01

Satellite observations of low-level clouds have challenged the assumption that adiabatic liquid water content combined with constant physical thickness will lead to a negative cloud optics feedback in a decadal climate change. We explore the reasons for the satellite results using four years of surface remote sensing data from the Atmospheric Radiation Measurement Program Cloud and Radiation Testbed site in the Southern Great Plains of the United States. We find that low cloud liquid water path is approximately invariant with temperature in winter but decreases strongly with temperature in summer, consistent with the satellite inferences at this latitude. This behavior occurs because liquid water content shows no detectable temperature dependence while cloud physical thickness decreases with warming. Thinning of clouds with warming is observed on seasonal, synoptic, and diurnal time scales; it is most obvious in the warm sectors of baroclinic waves. Although cloud top is observed to slightly descend with warming, the primary cause of thinning, is the ascent of cloud base due to the reduction in surface relative humidity and the concomitant increase in the lifting condensation level of surface air. Low cloud liquid water path is not observed to be a continuous function of temperature. Rather, the behavior we observe is best explained as a transition in the frequency of occurrence of different boundary layer types. At cold temperatures, a mixture of stratified and convective boundary layers is observed, leading to a broad distribution of liquid water path values, while at warm temperatures, only convective boundary layers with small liquid water paths, some of them decoupled, are observed. Our results, combined with the earlier satellite inferences, imply that the commonly quoted 1.5C lower limit for the equilibrium global climate sensitivity to a doubling of CO2 which is based on models with near-adiabatic liquid water behavior and constant physical thickness, should be revised upward.

Climatic Implications of the Observed Temperature Dependence of the Liquid Water Path of Low Clouds in the Southern Great Plains

NASA Technical Reports Server (NTRS)

DelGenio, Anthony D.; Wolf, Audrey B.

1999-01-01

Satellite observations of low-level clouds have challenged the assumption that adiabatic liquid water content combined with constant physical thickness will lead to a negative cloud optics feedback in a decadal climate change. We explore the reasons for the satellite results using four years of surface remote sensing data from the Atmospheric Radiation Measurement Program Cloud and Radiation Testbed site in the Southern Great Plains of the United States. We find that low cloud liquid water path is approximately invariant with temperature in winter but decreases strongly with temperature in summer, consistent with the satellite inferences at this latitude. This behavior occurs because liquid water content shows no detectable temperature dependence while cloud physical thickness decreases with warming. Thinning of clouds with warming is observed on seasonal, synoptic, and diurnal time scales; it is most obvious in the warm sectors of baroclinic waves. Although cloud top is observed to slightly descend with warming, the primary cause of thinning is the ascent of cloud base due to the reduction in surface relative humidity and the concomitant increase in the lifting condensation level of surface air. Low cloud liquid water path is not observed to be a continuous function of temperature. Rather, the behavior we observe is best explained as a transition in the frequency of occurrence of different boundary layer types: At cold temperatures, a mixture of stratified and convective boundary layers is observed, leading to a broad distribution of liquid water path values, while at warm temperatures, only convective boundary layers with small liquid water paths, some of them decoupled, are observed. Our results, combined with the earlier satellite inferences, imply that the commonly quoted 1.50 C lower limit for the equilibrium global climate sensitivity to a doubling of CO2, which is based on models with near-adiabatic liquid water behavior and constant physical thickness, should be revised upward.

Confocal Laser Scanning Microscopy and Ultrastructural Study of VGLUT2 Thalamic Input to Striatal Projection Neurons in Rats

PubMed Central

Lei, Wanlong; Deng, Yunping; Liu, Bingbing; Mu, Shuhua; Guley, Natalie M.; Wong, Ting; Reiner, Anton

2014-01-01

We examined thalamic input to striatum in rats using immunolabeling for the vesicular glutamate transporter (VGLUT2). Double immunofluorescence viewed with confocal laser scanning microscopy (CLSM) revealed that VGLUT2+ terminals are distinct from VGLUT1+ terminals. CLSM of Phaseolus vulgaris-leucoagglutinin (PHAL)-labeled cortical or thalamic terminals revealed that VGLUT2 is rare in corticostriatal terminals but nearly always present in thalamostriatal terminals. Electron microscopy revealed that VGLUT2+ terminals made up 39.4% of excitatory terminals in striatum (with VGLUT1+ corticostriatal terminals constituting the rest), and 66.8% of VGLUT2+ terminals synapsed on spines and the remainder on dendrites. VGLUT2+ axo-spinous terminals had a mean diameter of 0.624 lm, while VGLUT2+ axodendritic terminals a mean diameter of 0.698 µm. In tissue in which we simultaneously immunolabeled thalamostriatal terminals for VGLUT2 and striatal neurons for D1 (with about half of spines immunolabeled for D1), 54.6% of VGLUT2+ terminals targeted D1+ spines (i.e., direct pathway striatal neurons), and 37.3% of D1+ spines received VGLUT2+ synaptic contacts. By contrast, 45.4% of VGLUT2+ terminals targeted D1-negative spines (i.e., indirect pathway striatal neurons), and only 25.8% of D1-negative spines received VGLUT2+ synaptic contacts. Similarly, among VGLUT2+ axodendritic synaptic terminals, 59.1% contacted D1+ dendrites, and 40.9% contacted D1-negative dendrites. VGLUT2+ terminals on D1+ spines and dendrites tended to be slightly smaller than those on D1-negative spines and dendrites. Thus, thala-mostriatal terminals contact both direct and indirect pathway striatal neurons, with a slight preference for direct. These results are consistent with physiological studies indicating slightly different effects of thalamic input on the two types of striatal projection neurons. PMID:23047588

Confocal laser scanning microscopy and ultrastructural study of VGLUT2 thalamic input to striatal projection neurons in rats.

PubMed

Lei, Wanlong; Deng, Yunping; Liu, Bingbing; Mu, Shuhua; Guley, Natalie M; Wong, Ting; Reiner, Anton

2013-04-15

We examined thalamic input to striatum in rats using immunolabeling for the vesicular glutamate transporter (VGLUT2). Double immunofluorescence viewed with confocal laser scanning microscopy (CLSM) revealed that VGLUT2+ terminals are distinct from VGLUT1+ terminals. CLSM of Phaseolus vulgaris-leucoagglutinin (PHAL)-labeled cortical or thalamic terminals revealed that VGLUT2 is rare in corticostriatal terminals but nearly always present in thalamostriatal terminals. Electron microscopy revealed that VGLUT2+ terminals made up 39.4% of excitatory terminals in striatum (with VGLUT1+ corticostriatal terminals constituting the rest), and 66.8% of VGLUT2+ terminals synapsed on spines and the remainder on dendrites. VGLUT2+ axospinous terminals had a mean diameter of 0.624 μm, while VGLUT2+ axodendritic terminals a mean diameter of 0.698 μm. In tissue in which we simultaneously immunolabeled thalamostriatal terminals for VGLUT2 and striatal neurons for D1 (with about half of spines immunolabeled for D1), 54.6% of VGLUT2+ terminals targeted D1+ spines (i.e., direct pathway striatal neurons), and 37.3% of D1+ spines received VGLUT2+ synaptic contacts. By contrast, 45.4% of VGLUT2+ terminals targeted D1-negative spines (i.e., indirect pathway striatal neurons), and only 25.8% of D1-negative spines received VGLUT2+ synaptic contacts. Similarly, among VGLUT2+ axodendritic synaptic terminals, 59.1% contacted D1+ dendrites, and 40.9% contacted D1-negative dendrites. VGLUT2+ terminals on D1+ spines and dendrites tended to be slightly smaller than those on D1-negative spines and dendrites. Thus, thalamostriatal terminals contact both direct and indirect pathway striatal neurons, with a slight preference for direct. These results are consistent with physiological studies indicating slightly different effects of thalamic input on the two types of striatal projection neurons. Copyright © 2012 Wiley Periodicals, Inc.

On retrodictions of global mantle flow with assimilated surface velocities

NASA Astrophysics Data System (ADS)

Colli, Lorenzo; Bunge, Hans-Peter; Schuberth, Bernhard S. A.

2016-04-01

Modeling past states of Earth's mantle and relating them to geologic observations such as continental-scale uplift and subsidence is an effective method for testing mantle convection models. However, mantle convection is chaotic and two identical mantle models initialized with slightly different temperature fields diverge exponentially in time until they become uncorrelated, thus limiting retrodictions (i.e., reconstructions of past states of Earth's mantle obtained using present information) to the recent past. We show with 3-D spherical mantle convection models that retrodictions of mantle flow can be extended significantly if knowledge of the surface velocity field is available. Assimilating surface velocities produces in some cases negative Lyapunov times (i.e., e-folding times), implying that even a severely perturbed initial condition may evolve toward the reference state. A history of the surface velocity field for Earth can be obtained from past plate motion reconstructions for time periods of a mantle overturn, suggesting that mantle flow can be reconstructed over comparable times.

On retrodictions of global mantle flow with assimilated surface velocities

NASA Astrophysics Data System (ADS)

Colli, Lorenzo; Bunge, Hans-Peter; Schuberth, Bernhard S. A.

2015-10-01

Modeling past states of Earth's mantle and relating them to geologic observations such as continental-scale uplift and subsidence is an effective method for testing mantle convection models. However, mantle convection is chaotic and two identical mantle models initialized with slightly different temperature fields diverge exponentially in time until they become uncorrelated, thus limiting retrodictions (i.e., reconstructions of past states of Earth's mantle obtained using present information) to the recent past. We show with 3-D spherical mantle convection models that retrodictions of mantle flow can be extended significantly if knowledge of the surface velocity field is available. Assimilating surface velocities produces in some cases negative Lyapunov times (i.e., e-folding times), implying that even a severely perturbed initial condition may evolve toward the reference state. A history of the surface velocity field for Earth can be obtained from past plate motion reconstructions for time periods of a mantle overturn, suggesting that mantle flow can be reconstructed over comparable times.

Nanodiamond decorated liposomes as highly biocompatible delivery vehicles and a comparison with carbon nanotubes and graphene oxide.

PubMed

Wang, Feng; Liu, Juewen

2013-12-21

Studying interactions between nano-carbons and lipid membranes is important for multiplexed drug delivery, device fabrication and for understanding toxicity. Herein, we report that nanodiamond (ND, sp(3) carbon) forms a complex with highly biocompatible zwitterionic liposomes based on hydrogen bonding, which is confirmed by pH-dependent and urea-dependent assays. Despite such weak interaction, the complex is highly stable. Comparisons were made with two sp(2) carbons: nanoscale graphene oxide (NGO) and carbon nanotubes (CNTs), where CNT adsorption is the weakest. Adsorption of the nano-carbons does not induce liposome leakage or affect lipid phase transition temperature. Therefore, the potential toxicity of nano-carbons is unlikely to be related to direct membrane damage. ND facilitates cellular uptake of liposomes and co-delivery of negatively charged calcein and positively charged doxorubicin has been demonstrated. ND has the lowest toxicity, while CNTs and NGO are slightly more toxic. The effect of introducing fusogenic lipids and cholesterol was further studied to understand the effect of lipid formulation.

Nocturnal activity patterns of northern myotis (Myotis septentrionalis) during the maternity season in West Virginia (USA)

USGS Publications Warehouse

Johnson, J.B.; Edwards, J.W.; Ford, W.M.

2011-01-01

Nocturnal activity patterns of northern myotis (Myotis septentrionalis) at diurnal roost trees remain largely uninvestigated. For example, the influence of reproductive status, weather, and roost tree and surrounding habitat characteristics on timing of emergence, intra-night activity, and entrance at their roost trees is poorly known. We examined nocturnal activity patterns of northern myotis maternity colonies during pregnancy and lactation at diurnal roost trees situated in areas that were and were not subjected to recent prescribed fires at the Fernow Experimental Forest, West Virginia from 2007 to 2009. According to exit counts and acoustic data, northern myotis colony sizes were similar between reproductive periods and roost tree settings. However, intra-night activity patterns differed slightly between reproductive periods and roost trees in burned and non-burned areas. Weather variables poorly explained variation in activity patterns during pregnancy, but precipitation and temperature were negatively associated with activity patterns during lactation. ?? Museum and Institute of Zoology PAS.

Fast Adaptive Thermal Camouflage Based on Flexible VO₂/Graphene/CNT Thin Films.

PubMed

Xiao, Lin; Ma, He; Liu, Junku; Zhao, Wei; Jia, Yi; Zhao, Qiang; Liu, Kai; Wu, Yang; Wei, Yang; Fan, Shoushan; Jiang, Kaili

2015-12-09

Adaptive camouflage in thermal imaging, a form of cloaking technology capable of blending naturally into the surrounding environment, has been a great challenge in the past decades. Emissivity engineering for thermal camouflage is regarded as a more promising way compared to merely temperature controlling that has to dissipate a large amount of excessive heat. However, practical devices with an active modulation of emissivity have yet to be well explored. In this letter we demonstrate an active cloaking device capable of efficient thermal radiance control, which consists of a vanadium dioxide (VO2) layer, with a negative differential thermal emissivity, coated on a graphene/carbon nanotube (CNT) thin film. A slight joule heating drastically changes the emissivity of the device, achieving rapid switchable thermal camouflage with a low power consumption and excellent reliability. It is believed that this device will find wide applications not only in artificial systems for infrared camouflage or cloaking but also in energy-saving smart windows and thermo-optical modulators.

Instability of the layered orthorhombic post-perovskite phase of SrTiO3 and other candidate orthorhombic phases under pressure

NASA Astrophysics Data System (ADS)

Bhandari, Churna; Lambrecht, Walter R. L.

2018-06-01

While the tetragonal antiferro-electrically distorted (AFD) phase with space group I 4 / mcm is well known for SrTiO3 to occur below 105 K, there are also some hints in the literature of an orthorhombic phase, either at the lower temperature or at high pressure. A previously proposed orthorhombic layered structure of SrTiO3, known as the post-perovskite or CaIrO3 structure with space group Cmcm is shown to have significantly higher energy than the cubic or tetragonal phase and to have its minimum volume at larger volume than cubic perovskite. The Cmcm structure is thus ruled out. We also study an alternative Pnma phase obtained by two octahedral rotations about different axes. This phase is found to have slightly lower energy than the I 4 / mcm phase in spite of the fact that its parent, in-phase tilted P 4 / mbm phase is not found to occur. Our calculated enthalpies of formation show that the I 4 / mcm phase occurs at slightly higher volume than the cubic phase and has a negative transition pressure relative to the cubic phase, which suggests that it does not correspond to the high-pressure tetragonal phase. The enthalpy of the Pnma phase is almost indistinguishable from the I 4 / mcm phase. Alternative ferro-electric tetragonal and orthorhombic structures previously suggested in literature are discussed.

Entropy of single-file water in (6,6) carbon nanotubes.

PubMed

Waghe, Aparna; Rasaiah, Jayendran C; Hummer, Gerhard

2012-07-28

We used molecular dynamics simulations to investigate the thermodynamics of filling of a (6,6) open carbon nanotube (diameter D = 0.806 nm) solvated in TIP3P water over a temperature range from 280 K to 320 K at atmospheric pressure. In simulations of tubes with slightly weakened carbon-water attractive interactions, we observed multiple filling and emptying events. From the water occupancy statistics, we directly obtained the free energy of filling, and from its temperature dependence the entropy of filling. We found a negative entropy of about -1.3 k(B) per molecule for filling the nanotube with a hydrogen-bonded single-file chain of water molecules. The entropy of filling is nearly independent of the strength of the attractive carbon-water interactions over the range studied. In contrast, the energy of transfer depends strongly on the carbon-water attraction strength. These results are in good agreement with entropies of about -0.5 k(B) per water molecule obtained from grand-canonical Monte Carlo calculations of water in quasi-infinite tubes in vacuum under periodic boundary conditions. Overall, for realistic carbon-water interactions we expect that at ambient conditions filling of a (6,6) carbon nanotube open to a water reservoir is driven by a favorable decrease in energy, and opposed by a small loss of water entropy.

Surface characterization of U(AlxSi1-x)3 alloy and its interaction with O2 and H2O, at room temperature

NASA Astrophysics Data System (ADS)

Matmor, M.; Cohen, S.; Rafailov, G.; Vaknin, M.; Shamir, N.; Gouder, T.; Zalkind, S.

2018-02-01

Surface characterization and the interactions of U(AlxSi1-x)3 alloy (x = 0.57) with oxygen and water vapor were studied, utilizing X-Ray Photoelectron Spectroscopy and Direct Recoil Spectrometry, at room temperature. The U 4f spectrum of U(AlxSi1-x)3 alloy exhibits weak correlation satellites, suggesting an itinerant description of the U 5f states for this compound. The Al and Si 2p lines are chemically shifted to lower binding energies. Exposing the alloy to oxygen and water vapor results in oxidation of mainly the uranium and aluminum components, while silicon is only slightly oxidized. Oxygen was found to be a stronger oxidizer than water vapor and the trend is consistent with the more negative enthalpies of formation of metal oxides produced by the O2 reaction, as compared to H2O. During oxygen exposure, fast oxidation occurs by oxide islands nucleation and lateral growth, followed by oxidation of the sub-surface, up to ∼4 nm, at 1000 L exposure. Water initially reacts with the surface by full dissociation and oxide islands formation, which is then covered by hydroxides. Only a minor increase in the oxide thickness of up to ∼2.5 nm, was observed after coalescence.

Is the zero emission requirement aligned with 2.0°C and 1.5°C stabilization targets?

NASA Astrophysics Data System (ADS)

Tanaka, K.; O'Neill, B. C.

2016-12-01

The Paris Agreement stipulates that the global warming be stabilized at well below 2°C and eventually 1.5°C above pre-industrial levels. While the landmark agreement has led to a wide range of associated analyses, less attention has been paid to another mitigation target in Paris: cut the net greenhouse gas emissions to zero during the second half of this century. This study explores how such an emission target may guide us to achieve the temperature target. We found that, if the emission target is met by 2060, the most likely outcome is that the warming will peak at slightly above 2°C and decline below 1.5°C by the early 22nd century. This corresponds roughly to the temperature target; however, it is important to realize that the warming inevitably exceeds 1.5°C temporarily. On the contrary, if delayed by 2100, the warming reaches as high as 4°C until it starts to fall. Furthermore, net negative CO2 emissions are implicitly required for the emission target, the intensity of which depends on unabatable anthropogenic non-CO2 greenhouse gas emissions as well as the emission metric used to equate greenhouse gas emissions on the basis of CO2.

Incidence of acute-onset atrial fibrillation correlates with air temperature. Results of a nine-year survey.

PubMed

Comelli, Ivan; Ferro, Jayme; Lippi, Giuseppe; Comelli, Denis; Sartori, Elisabetta; Cervellin, Gianfranco

2014-09-01

Some diseases, such as renal colic, stroke, and myocardial infarction, correlate with seasonality and microclimatic variations. Although evidence is limited and controversial, a correlation between acute-onset atrial fibrillation (AAF) and seasonality has been previously reported. In order to elucidate the possible correlations between weather and incidence of AAF in a country with a temperate climate, the influence of day-by-day climate changes was analyzed based on the number of visits for AAF (defined as onset of symptoms within 48h) in a large urban Emergency Department (ED) of northern Italy. All the episodes of AAF were retrieved from the hospital's electronic database during a period of 3287days (January 2002 to December 2010). Only the cases whose onset occurred within 48h from the ED visit were selected. The total number of ED visits was 725,812 throughout the observational period. Among these, 3633 AAF cases were observed, 52% of which were males. A slight but significant negative linear correlation was found between the number of AAFs and the daily temperature (R=-0.60; p=0.001). No correlation was found between the number of AAFs and the daily humidity (R=-0.07; p=0.2). Copyright © 2014 Ministry of Health, Saudi Arabia. Published by Elsevier Ltd. All rights reserved.

[Effects of venom from Sclerodermus sichuanensis Xiao on pupa of Tenebrio molitor].

PubMed

Zhuo, Zhi-Hang; Yang, Wei; Qin, Huan; Yang, Chun-Ping; Yang, Hua; Xu, Dan-Ping

2013-11-01

To explore the regulatory mechanisms of parasitism of Sclerodermus sichuanensis on Tenebrio molitor, the methods of natural parasitism and venom injection were adopted to investigate the effects of the venom from S. sichuanensis on the pupa of T. molitor in the parasitic process. Under venom injection, the paralytic degree of the pupa had a positive correlation with the concentration of injected venom, and the number of recovered pupa had a negative correlation with the injected venom concentration. The T. molitor pupa was in slight and reversible paralysis when injected with 0.01 VRE (venom reservoir equivalent) of venom, and in non-reversible and complete paralysis when 0.2 VRE was injected. The pupa died massively and appeared a wide range of melanization when injected with soil bacterial suspension alone, but the melanization delayed and the mortality declined significantly when the mixed liquor of bacterium and venom was injected. The bacteriostasis of the venom on Staphylococcus aureus was significantly stronger than that on Escherichia coli. Within a definite range of temperature, the paralytic activity decreased significantly with increasing temperature, the bacteriostasis on S. aureus increased significantly, while that on E. coli was opposite. This study showed that the venom from S. sichuanensis had the effects of paralysis, bacteriostasis, inhibiting exuviations, and delaying melanization.

Collective modes in CuxTiSe2 measured with meV-resolution EELS

NASA Astrophysics Data System (ADS)

Rak, Melinda; Vig, Sean; Husain, Ali; Mitrano, Matteo; Rubeck, Samantha; Kogar, Anshul; Karapetrov, Goran; Morosan, Emilia; Abbamonte, Peter

The charge density wave (CDW) in 1 T-TiSe2 has been widely thought to be the result of an excitonic insulator transition. We recently observed a soft electronic mode in TiSe2 using a new, momentum-resolved electron energy loss spectroscopy (M-EELS) technique, demonstrating a condensation of electron-hole pairs in this material. As TiSe2 is doped with Cu to produce CuxTiSe2, a superconducting dome emerges above x ˜ 0.04. In this talk, I describe how the electronic collective mode evolves with Cu doping. We find that the temperature dependence of the electronic mode reverses as Cu is introduced and that the mode is much broader at low temperature as compared to the undoped material. Additionally, the electronic mode no longer has a positive dispersion at 300 K as described by the Lindhard function, but has a slightly negative dispersion for small momentum transfers. We will discuss the implications of these results for the excitonic insulator transition in TiSe2. This work was supported by the Gordon and Betty Moore Foundation's EPiQS Initiative through Grant GBMF4542. An early prototype of the M-EELS instrument was supported by the DOE Center for Emergent Superconductivity under Award No. DE-AC02-98CH10886.

3D non-LTE corrections for the 6Li/7Li isotopic ratio in solar-type stars

NASA Astrophysics Data System (ADS)

Harutyunyan, G.; Steffen, M.; Mott, A.; Caffau, E.; Israelian, G.; González Hernández, J. I.; Strassmeier, K. G.

Doppler shifts induced by convective motions in stellar atmospheres affect the shape of spectral absorption lines and create slightly asymmetric line profiles. It is important to take this effect into account in modeling the subtle depression created by the 6Li isotope which lies on the red wing of the Li I 670.8 nm resonance doublet line, since convective motions in stellar atmospheres can mimic a presence of 6Li when intrinsically symmetric theoretical line profiles are presumed for the analysis of the 7Li doublet \\citep{cayrel2007}. Based on CO5BOLD hydrodynamical model atmospheres, we compute 3D non-local thermodynamic equilibrium (NLTE) corrections for the 6Li/7Li isotopic ratio by using a grid of 3D NLTE and 1D LTE synthetic spectra. These corrections must be added to the results of the 1D LTE analysis to correct them for the combined 3D non-LTE effects. As one would expect, the resulting corrections are always negative and they range between 0 and -5 %, depending on effective temperature, surface gravity, and metallicity. For each metallicity we derive an analytic expression approximating the 3D NLTE corrections as a function of effective temperature, surface gravity and projected rotational velocity.

Temperature peaks affect fire-induced soil water repellency, infiltration and erosion risk of Mediterranean shrublands. Implications for water and sediment connectivity

NASA Astrophysics Data System (ADS)

Jordán, Antonio; Zavala, Lorena M.; Gordillo-Rivero, Ángel J.; Miriam, Miriam; Keesstra, Saskia; Cerdà, Artemi

2017-04-01

We know that the impact of fire on soil water repellency varies largely with the availability of water and physical and chemical soil properties, as well as the intensity of pre-existing hydrophobicity. However, there are few studies that relate the intensity of post-fire soil hydrophobicity and its persistence to the intensity and duration of thermal peaks occurring during fire. Fundamentally, this is due to the difficulty of quantifying these factors in situ, so that experimental fires are an extremely useful tool. The objective of this work was to study the impact of the intensity and duration of the thermal peaks observed during an experimental fire in the hydrophobicity of previously wet or slightly hydrophobic soils and the consequences of these changes on infiltration, runoff and soil loss (through rainfall simulation) in the immediate (30 days) and medium-term (1 year) post-fire period. In general, soil water repellency increased in all cases, although high temperatures and residence times of moderate thermal peaks caused the greatest impact. Although infiltration rates determined by mini-disk infiltrometer with water generally declined, no significant changes were observed in the same measurement with ethanol (which negates the effect of hydrophobicity).

Long-pulse production of high current negative ion beam by using actively temperature controlled plasma grid for JT-60SA negative ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kojima, A.; Hanada, M.; Yoshida, M.

2015-04-08

The temperature control system of the large-size plasma grid has been developed to realize the long pulse production of high-current negative ions for JT-60SA. By using this prototype system for the JT-60SA ion source, 15 A negative ions has been sustained for 100 s for the first time, which is three times longer than that obtained in JT-60U. In this system, a high-temperature fluorinated fluid with a high boiling point of 270 degree Celsius is circulated in the cooling channels of the plasma grids (PG) where a cesium (Cs) coverage is formed to enhance the negative ion production. Because themore » PG temperature control had been applied to only 10% of the extraction area previously, the prototype PG with the full extraction area (110 cm × 45 cm) was developed to increase the negative ion current in this time. In the preliminary results of long pulse productions of high-current negative ions at a Cs conditioning phase, the negative ion production was gradually degraded in the last half of 100 s pulse where the temperature of an arc chamber wall was not saturated. From the spectroscopic measurements, it was found that the Cs flux released from the wall might affect to the negative ion production, which implied the wall temperature should be kept low to control the Cs flux to the PG for the long-pulse high-current production. The obtained results of long-pulse production and the PG temperature control method contributes the design of the ITER ion source.« less

Understanding the science of climate change: Talking Points - Impacts to arid lands

Treesearch

Rachel Loehman

2010-01-01

Arid ecosystems are particularly sensitive to climate change and climate variability because organisms in these regions live near their physiological limits for water and temperature stress. Slight changes in temperature or precipitation regimes, or in magnitude and frequency of extreme climatic events, can significantly alter the composition, abundance, and...

Environmental tests of metallization systems for terrestrial photovoltaic cells

NASA Technical Reports Server (NTRS)

Alexander, P., Jr.

1985-01-01

Seven different solar cell metallization systems were subjected to temperature cycling tests and humidity tests. Temperature cycling excursions were -50 deg C to 150 deg C per cycle. Humidity conditions were 70 deg C at 98% relative humidity. The seven metallization systems were: Ti/Ag, Ti/Pd/Ag, Ti/Pd/Cu, Ni/Cu, Pd/Ni/Solder, Cr/Pd/Ag, and thick film Ag. All metallization systems showed a slight to moderate decrease in cell efficiencies after subjection to 1000 temperature cycles. Six of the seven metallization systems also evidenced slight increases in cell efficiencies after moderate numbers of cycles, generally less than 100 cycles. The copper based systems showed the largest decrease in cell efficiencies after temperature cycling. All metallization systems showed moderate to large decreases in cell efficiencies after 123 days of humidity exposure. The copper based systems again showed the largest decrease in cell efficiencies after humidity exposure. Graphs of the environmental exposures versus cell efficiencies are presented for each metallization system, as well as environmental exposures versus fill factors or series resistance.

HIV-Associated Urogenital Malignancies.

PubMed

Hentrich, Marcus; Pfister, David

2017-01-01

Non-AIDS-defining malignancies (NADM) are a leading cause of morbidity and mortality for HIV-infected subjects. The risk of testicular germ cell cancer (GCC) and renal cell cancer is slightly increased in the setting of HIV, whereas there is a slightly decreased risk of prostate cancer and bladder cancer. As in industrialized countries the majority of people living with HIV are men, and people aged 55 and older now account for more than a quarter of persons living with HIV, both testis and prostate cancer are assumed to occur with increased frequency in HIV-infected subjects. Overall, treatments should be the same as in HIV-negative patients with urogenital malignancies. Since the introduction of combination antiretroviral therapy (cART) the outcome appears to have improved due to a decrease in HIV-related deaths. HIV-infected men who are treated with standard therapies for GCC now have a similar cancer-free survival compared with their HIV-negative counterparts. Screening and treatment for prostate cancer should follow recommendations established for HIV-negative men. During radio- or chemotherapy patients should receive concurrent cART but the drug-drug interaction potential must be taken into account. © 2017 S. Karger GmbH, Freiburg.

Neutral beamline with ion energy recovery based on magnetic blocking of electrons

DOEpatents

Stirling, W.L.

1980-07-01

A neutral beamline generator with energy recovery of the full-energy ion component of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the elecrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

Elevated temperature mechanical properties of line pipe steels

NASA Astrophysics Data System (ADS)

Jacobs, Taylor Roth

The effects of test temperature on the tensile properties of four line pipe steels were evaluated. The four materials include a ferrite-pearlite line pipe steel with a yield strength specification of 359 MPa (52 ksi) and three 485 MPa (70 ksi) yield strength acicular ferrite line pipe steels. Deformation behavior, ductility, strength, strain hardening rate, strain rate sensitivity, and fracture behavior were characterized at room temperature and in the temperature range of 200--350 °C, the potential operating range for steels used in oil production by the steam assisted gravity drainage process. Elevated temperature tensile testing was conducted on commercially produced as-received plates at engineering strain rates of 1.67 x 10 -4, 8.33 x 10-4, and 1.67 x 10-3 s-1. The acicular ferrite (X70) line pipe steels were also tested at elevated temperatures after aging at 200, 275, and 350 °C for 100 h under a tensile load of 419 MPa. The presence of serrated yielding depended on temperature and strain rate, and the upper bound of the temperature range where serrated yielding was observed was independent of microstructure between the ferrite-pearlite (X52) steel and the X70 steels. Serrated yielding was observed at intermediate temperatures and continuous plastic deformation was observed at room temperature and high temperatures. All steels exhibited a minimum in ductility as a function of temperature at testing conditions where serrated yielding was observed. At the higher temperatures (>275 °C) the X52 steel exhibited an increase in ductility with an increase in temperature and the X70 steels exhibited a maximum in ductility as a function of temperature. All steels exhibited a maximum in flow strength and average strain hardening rate as a function of temperature. The X52 steel exhibited maxima in flow strength and average strain hardening rate at lower temperatures than observed for the X70 steels. For all steels, the temperature where the maximum in both flow strength and strain hardening occurred increased with increasing strain rate. Strain rate sensitivities were measured using flow stress data from multiple tensile tests and strain rate jump tests on single tensile samples. In flow stress strain rate sensitivity measurements, a transition from negative to positive strain rate sensitivity was observed in the X52 steel at approximately 275--300 °C, and negative strain rate sensitivity was observed at all elevated temperature testing conditions in the X70 steels. In jump test strain rate sensitivity measurements, all four steels exhibited a transition from negative to positive strain rate sensitivity at approximately 250--275 °C. Anisotropic deformation in the X70 steels was observed by measuring the geometry of the fracture surfaces of the tensile samples. The degree of anisotropy changed as a function of temperature and minima in the degree of anisotropy was observed at approximately 300 °C for all three X70 steels. DSA was verified as an active strengthening mechanism at elevated temperatures for all line pipe steels tested resulting in serrated yielding, a minimum in ductility as a function of temperature, a maximum in flow strength as a function of temperature, a maximum in average strain hardening rate as a function of temperature, and negative strain rate sensitivities. Mechanical properties of the X70 steels exhibited different functionality with respect to temperature compared to the X52 steels at temperatures greater than 250 ºC. Changes in the acicular ferrite microstructure during deformation such as precipitate coarsening, dynamic precipitation, tempering of martensite in martensite-austenite islands, or transformation of retained austenite could account for differences in tensile property functionality between the X52 and X70 steels. Long term aging under load (LTA) testing of the X70 steels resulted in increased yield strength compared to standard elevated temperature tensile tests at all temperatures as a result of static strain aging. LTA specimen ultimate tensile strengths (UTS) increased slightly at 200 °C, were comparable at 275 °C, and decreased significantly at 350 °C when compared to as-received (standard) tests at 350 °C. Observed reductions in UTS were a result of decreased strain hardening in the LTA specimens compared to standard tensile specimens. Ideal elevated temperature operating conditions (based on tensile properties) for the X70 line pipe steels in the temperature range relevant to the steam assisted gravity drainage process are around 275--325 °C at the strain rates tested. In the temperature range of 275--325 °C the X70 steels exhibited continuous plastic deformation, a maximum in ductility, a maximum in flow stress, improved strain hardening compared to intermediate temperatures, reduced anisotropic deformation, and after extended use at elevated temperatures, yield strength increases with little change in UTS.

Crystallization of a Li2O2SiO2 Glass under High Hydrostatic Pressures

NASA Technical Reports Server (NTRS)

Fuss, T.; Day, D. E.; Lesher, C. E.; Ray, C. S.

2004-01-01

The crystallization behavior of a Li2O.2SiO2 (LS2) glass subjected to a uniform hydrostatic pressure of 4.5 or 6 GPa was investigated between 550 and 800 C using XRD, IR, Raman, TEM, NMR, and DTA. The density of the glass subjected to 6 GPa was between 2.52 plus or minus 0.01 and 2.57 plus or minus 0.01 grams per cubic centimeters, depending upon the processing temperatures, and was higher than that of the stoichiometric LS2 crystals, 2.46 plus or minus 0.01 grams per cubic centimeter. Thus, crystallization in 6 GPa glass occurred in a condition of negative volume dilatation, deltaV = V(sub glass) - V(sub crystal), while that for the 4.5 GPa glass occurred in the condition deltaV greater than 0. For deltaV greater than 0, which also includes the control glass at ambient (one atmosphere) pressure, the glasses always crystallize Li2Si2O5 (orthorhombic, Ccc2) crystals, but for deltaV less than 0 (6 GPa), the glasses crystallize Li2SiO3 crystals with a slightly deformed structure. The crystal growth rate vs. temperature curve moved to higher temperature with increasing pressure, and was independent of the sign of deltaV. These results for the effect of hydrostatic pressure on the crystallization of LS2 glass were discussed from thermodynamic considerations.

An inverse gas chromatographic methodology for studying gas-liquid mass transfer.

PubMed

Paloglou, A; Martakidis, K; Gavril, D

2017-01-13

A novel methodology of reversed flow inverse gas chromatography (RF-IGC) is presented. It permits the simultaneous determination of mass transfer coefficients across the gas liquid interface as well as the respective solubility parameters and thermodynamic functions of dissolution of gases into liquids. The standard deviation of the experimentally determined parameters is estimated for first time, which combined with the successful comparison of the values of the present parameters with other literature ones ascertain the reliability of the methodology. Another novelty of the present work is that the chromatographic sampling of the physicochemical phenomena is done without performing the usual flow reversals procedure. Vinyl chloride monomer's (VCM) interaction with various composition liquid foods: orange juice, milk and olive oil was used as model system. The present transfer rates are controlled by the gas film at lower temperatures, but at higher temperatures the resistances in both films tend to become equal. The found liquid diffusivity values express the total mass transfer from the gas phase into the liquid's bulk and they decrease with rising temperature, as the solubilities of gases in liquids do. Solubility, expressed by Henry's law constant and the mean values of interfacial thickness are of the same order of magnitude to literature ones. From the thermodynamic point of view, VCM dissolution in all liquids is accompanied by significant heat release and it is a slightly non-spontaneous process, near equilibrium, while the entropy change values are negative. Copyright © 2016 Elsevier B.V. All rights reserved.

Low Temperature Reflectance Spectra of Titan Tholins

NASA Technical Reports Server (NTRS)

Roush, T. L.; Dalton, J. B.; Fonda, Mark (Technical Monitor)

2001-01-01

Compositional interpretation of remotely obtained reflectance spectra of outer solar system surfaces is achieved by a variety of methods. These include matching spectral curves, matching spectral features, quantitative spectral interpretation, and theoretical modeling of spectra. All of these approaches rely upon laboratory measurements of one kind or another. The bulk of these laboratory measurements are obtained with the sample of interest at ambient temperatures and pressures. However, surface temperatures of planets, satellites, and asteroids in the outer solar system are significantly cooler than ambient laboratory conditions on Earth. The infrared spectra of many materials change as a function of temperature. As has been recently demonstrated it is important to assess what effects colder temperatures have on spectral properties and hence, compositional interpretations. Titan tholin is a solid residue created by energetic processing of H-, C-, and N-bearing gases. Such residues can also be created by energetic processing if the gases are condensed into ices. Titan tholin has been suggested as a coloring agent for several surfaces in the outer solar system. Here we report laboratory measurements of Titan tholin at a temperature of 100 K and compare these to measurements of the same sample near room temperature. At low temperature the absorption features beyond 1 micrometer narrow slightly. At wavelengths greater than approx. 0.8 micrometer the overall reflectance of the sample decreases slightly making the sample less red at low temperatures. We will discuss the implications of the laboratory measurements for interpretation of cold outer solar system surfaces.

Transient Shifts of Incubation Temperature Reveal Immediate and Long-Term Transcriptional Response in Chicken Breast Muscle Underpinning Resilience and Phenotypic Plasticity.

PubMed

Naraballobh, Watcharapong; Trakooljul, Nares; Murani, Eduard; Brunner, Ronald; Krischek, Carsten; Janisch, Sabine; Wicke, Michael; Ponsuksili, Siriluck; Wimmers, Klaus

2016-01-01

Variations in egg incubation temperatures can have acute or long-term effects on gene transcription in avian species. Altered gene expression may, in turn, affect muscle traits in poultry and indirectly influence commercial production. To determine how changes in eggshell temperature affect gene expression, incubation temperatures were varied [36.8°C (low), 37.8°C (control), 38.8°C (high)] at specific time periods reflecting two stages of myogenesis [embryonic days (ED) 7-10 and 10-13]. Gene expression was compared between interventions and matching controls by microarrays in broiler breast muscle at ED10 or ED13 and post-hatch at day 35. Early (ED7-10) high incubation temperature (H10ΔC) resulted in 1370 differentially expressed genes (DEGs) in embryos. Ingenuity pathway analysis revealed temporary activation of cell maintenance, organismal development, and survival ability genes, but these effects were not maintained in adults. Late high incubation temperature (ED10-13) (H13ΔC) had slightly negative impacts on development of cellular components in embryos, but a cumulative effect was observed in adults, in which tissue development and nutrition metabolism were affected. Early low incubation temperature (L10ΔC) produced 368 DEGs, most of which were down-regulated and involved in differentiation and formation of muscle cells. In adults, this treatment down-regulated pathways of transcriptional processes, but up-regulated cell proliferation. Late low temperature incubation (L13ΔC) produced 795 DEGs in embryos, and activated organismal survival and post-transcriptional regulation pathways. In adults this treatment activated cellular and organ development, nutrition and small molecule activity, and survival rate, but deactivated size of body and muscle cells. Thermal interventions during incubation initiate immediate and delayed transcriptional responses that are specific for timing and direction of treatment. Interestingly, the transcriptional response to transiently decreased incubation temperature, which did not affect the phenotypes, prompts compensatory effects reflecting resilience. In contrast, higher incubation temperature triggers gene expression and has long-term effects on the phenotype. These mechanisms of considerable phenotypic plasticity contribute to the biodiversity and broaden the basis for managing poultry populations.

Chemical characteristics of the major thermal springs of Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mariner, R.H.; Presser, T.S.; Evans, W.C.

1976-07-01

Twenty-one thermal springs in western Montana were sampled for chemical, isotope, and gas compositions. Most of the springs issue dilute to slightly saline sodium-bicarbonate waters of neutral to slightly alkaline pH. A few of the springs issue sodium-mixed anion waters of near neutral pH. Fluoride concentrations are high in most of the thermal waters, up to 18 miligrams per litre, while F/Cl ratios range from 3/1 in the dilute waters to 1/10 in the slightly saline waters. Most of the springs are theoretically in thermodynamic equilibrium with respect to calcite and fluorite. Nitrogen is the major gas escaping from mostmore » of the hot springs; however, Hunters Hot Springs issue principally methane. The deuterium content of the hot spring waters is typical of meteoric water in western Montana. Geothermal calculations based on silica concentrations and Na-K-Ca ratios indicate that most of the springs are associated with low temperature aquifers (less than 100/sup 0/C). Chalcedony may be controlling the silica concentrations in these low temperature aquifers even in ''granitic'' terranes.« less

The Effects of Groundwater Samplers on Water Quality. A Literature Review

DTIC Science & Technology

1993-10-01

Nacht 1983): borehole and sampler di- devices operate by applying negative pressure, ameter, sampling depth, ease of cleaning, initial or vacuum, at...come in contact with any atmospheric gases al. 1974, Barcelona et al. 1985) have shown that and are subject to only a slight negative pressure...and selenium. They felt the degassing was due to 20% for the three most volatile compounds at the partial vacuum exerted by the pump for lift, highest

[The microclimate of an unoccupied wintering sett of the badger, Meles meles (Carnivora: Mustelidae), in the Darwin State Nature Reserve, Vologda Region].

PubMed

Sidorchuk, N V; Rozhnov, V V

2008-01-01

Data on the microclimate (air temperature and humidity) within an unoccupied badger sett in the Darwin Reserve (the Vologda Region) between September 2005 and May 2006 have been analyzed in relation to changes in the temperature and humidity of the ground air layer and soil. A positive correlation has been revealed between the temperature regime of the soil and air temperature within the sett. After the establishment of snow cover, air and soil temperatures within the sett vary slightly and barely depend on ambient air temperature.

Specific gravity of bovine colostrum immunoglobulins as affected by temperature and colostrum components.

PubMed

Mechor, G D; Gröhn, Y T; McDowell, L R; Van Saun, R J

1992-11-01

The effects of temperature and colostrum components on specific gravity in bovine colostrum were investigated. Thirty-nine first milking colostrum samples were collected from Holstein cows. The samples were assayed for alpha-tocopherol, fat, protein, total solids, and IgG. The concentrations of total solids, total protein, total IgG, and fat in colostrum were 26.6, 12.5, 3.7, and 9.4 g/100 g, respectively. A range of 1.8 to 24.7 micrograms/ml for alpha-tocopherol was measured in the colostrum samples. Specific gravity of the colostrum was measured using a hydrometer in increments of 5 degrees C from 0 to 40 degrees C. Specific gravity explained 76% of the variation in colostral total IgG at a colostrum temperature of 20 degrees C. The regression model was improved only slightly with the addition of protein, fat, and total solids. The model for samples at 20 degrees C was IgG (milligrams per milliliter) = 958 x (specific gravity) - 969. Measurement of specific gravity at variable temperatures necessitated inclusion of temperature in the model for estimation of IgG. Inclusion of the other components of colostrum into the model slightly improved the fit. The regression model for samples at variable temperatures was as follows: IgG (milligrams per milliliter) = 853 x (specific gravity) + .4 x temperature (Celsius degrees) - 866.

Ice nucleation triggered by negative pressure.

PubMed

Marcolli, Claudia

2017-11-30

Homogeneous ice nucleation needs supercooling of more than 35 K to become effective. When pressure is applied to water, the melting and the freezing points both decrease. Conversely, melting and freezing temperatures increase under negative pressure, i.e. when water is stretched. This study presents an extrapolation of homogeneous ice nucleation temperatures from positive to negative pressures as a basis for further exploration of ice nucleation under negative pressure. It predicts that increasing negative pressure at temperatures below about 262 K eventually results in homogeneous ice nucleation while at warmer temperature homogeneous cavitation, i. e. bubble nucleation, dominates. Negative pressure occurs locally and briefly when water is stretched due to mechanical shock, sonic waves, or fragmentation. The occurrence of such transient negative pressure should suffice to trigger homogeneous ice nucleation at large supercooling in the absence of ice-nucleating surfaces. In addition, negative pressure can act together with ice-inducing surfaces to enhance their intrinsic ice nucleation efficiency. Dynamic ice nucleation can be used to improve properties and uniformity of frozen products by applying ultrasonic fields and might also be relevant for the freezing of large drops in rainclouds.

The petrogenesis of late Neoproterozoic mafic dyke-like intrusion in south Sinai, Egypt

NASA Astrophysics Data System (ADS)

Azer, M. K.; Abu El-Ela, F. F.; Ren, M.

2012-08-01

New field, petrographical and geochemical studies are presented here for the late Neoproterozoic Rimm intrusion (˜15 km long) exposed in the southern Sinai Peninsula, Egypt in the northernmost Arabian-Nubian Shield (ANS). Field relations indicate that the Rimm intrusion is younger than the surrounding metamorphic rocks and calc-alkaline syn-tectonic granodiorite and it was not affected by regional metamorphism. The anorogenic peralkaline granite of Gebel Serbal crosscuts the Rimm intrusion. The Rimm intrusion is made up of several consanguineous rock types with gradational contacts. It is composed chiefly of pyroxene-hornblende gabbro, hornblende gabbro and minor quartz diorite. The chemical composition of the mafic minerals indicated that the studied rocks derived from calc-alkaline mafic magma. Geochemically, the studied rocks are characterized by enrichment in LILE relative to HFSE and LREE relative to HREE [(Ce/Yb)N = 4.50-6.36]. Quartz diorite display slightly concave HREE pattern and slightly negative Eu-anomaly [(Eu/Eu*)n = 0.91] which may be the result of fractionation of amphibole and plagioclase from the source melt, respectively. The Rimm intrusion evolved from mafic mantle magma into different type rocks by fractional crystallization with minor crustal contamination. The initial magma corresponds to pyroxene-hornblende gabbro and the crystallization of hornblende was caused by slight H2O increase in magma after crystallization of near-liquidus clinopyroxene and Ca-rich plagioclase. Amphiboles geobarometer indicate that the gabbroic rocks of the Rimm intrusion crystallized at pressures between 4.8 and 6.4 Kb, while quartz diorite crystallized at 1.3-2.1 Kb. Crystallization temperatures range between 800 and 926 °C for the gabbros and between 667 and 784 °C for the quartz diorite. The Rimm intrusion represents a post-orogenic phase formed during the crustal thinning and extension of the Arabian-Nubian Shield.

Use of Patients With Diarrhea Who Test Negative for Rotavirus as Controls to Estimate Rotavirus Vaccine Effectiveness Through Case-Control Studies.

PubMed

Tate, Jacqueline E; Patel, Manish M; Cortese, Margaret M; Payne, Daniel C; Lopman, Benjamin A; Yen, Catherine; Parashar, Umesh D

2016-05-01

Case-control studies are often performed to estimate postlicensure vaccine effectiveness (VE), but the enrollment of controls can be challenging, time-consuming, and costly. We evaluated whether children enrolled in the same hospital-based diarrheal surveillance used to identify rotavirus cases but who test negative for rotavirus (test-negative controls) can be considered a suitable alternative to nondiarrheal hospital or community-based control groups (traditional controls). We compared calculated VE estimates as a function of varying values of true VE, attack rates of rotavirus and nonrotavirus diarrhea in the population, and sensitivity and specificity of the rotavirus enzyme immunoasssay. We also searched the literature to identify rotavirus VE studies that used traditional and test-negative control groups and compared VE estimates obtained using the different control groups. Assuming a 1% attack rate for severe rotavirus diarrhea, a 3% attack rate for severe nonrotavirus diarrhea in the population, a test sensitivity of 96%, and a specificity of 100%, the calculated VE estimates using both the traditional and test-negative control groups closely approximated the true VE for all values from 30% to 100%. As true VE decreased, the traditional case-control approach slightly overestimated the true VE and the test-negative case-control approach slightly underestimated this estimate, but the absolute difference was only ±0.2 percentage points. Field VE estimates from 10 evaluations that used both traditional and test-negative control groups were similar regardless of control group used. The use of rotavirus test-negative controls offers an efficient and cost-effective approach to estimating rotavirus VE through case-control studies. Published by Oxford University Press for the Infectious Diseases Society of America 2016. This work is written by (a) US Government employee(s) and is in the public domain in the US.

Effect of post annealing on spin accumulation and transport signals in Co{sub 2}FeSi/MgO/n{sup +}-Si on insulator devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tiwari, Ajay, E-mail: ajay1.tiwari@toshiba.co.jp; Inokuchi, Tomoaki; Ishikawa, Mizue

The post annealing temperature dependence of spin accumulation and transport signals in Co{sub 2}FeSi/MgO/n{sup +}-Si on insulator were investigated. The spin signals were detected using 3- and 4-terminal Hanle, 2-terminal local and 4-terminal nonlocal magnetoresistance measurements. The post annealing temperature (T{sub A}) dependence of the magnitude in 3-terminal narrow Hanle signals is nearly constant up to T{sub A} < 400°C, however a slight decrease above T{sub A} ≥ 400°C is observed. This behavior is consistent with the T{sub A} dependence of the magnitude of 4-terminal nonlocal magnetoresistance (MR) signals. The spin polarization estimated from the 3-terminal narrow Hanle signals andmore » the magnitude of 2-terminal local MR signals show a slight improvement with increasing post annealing temperature with a peak at around 325°C and then start reducing slowly. The slight increase in the spin signal would be due to high spin polarization of Co{sub 2}FeSi as a result of structural ordering. The 2-terminal local MR signals do not vary significantly by annealing between as-deposited and T{sub A} = 400°C, indicating the robustness of our device. This result would be useful for future Si spintronics devices.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burnham, A K; Weese, R K; Andrzejewski, W J

Decomposition kinetics are determined for HMX (nitramine octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) and CP (2-(5-cyanotetrazalato) pentaammine cobalt (III) perchlorate) separately and together. For high levels of thermal stress, the two materials decompose faster as a mixture than individually. This effect is observed both in high-temperature thermal analysis experiments and in long-term thermal aging experiments. An Arrhenius plot of the 10% level of HMX decomposition by itself from a diverse set of experiments is linear from 120 to 260 C, with an apparent activation energy of 165 kJ/mol. Similar but less extensive thermal analysis data for the mixture suggests a slightly lower activation energy formore » the mixture, and an analogous extrapolation is consistent with the amount of gas observed in the long-term detonator aging experiments, which is about 30 times greater than expected from HMX by itself for 50 months at 100 C. Even with this acceleration, however, it would take {approx}10,000 years to achieve 10% decomposition at {approx}30 C. Correspondingly, negligible decomposition is predicted by this kinetic model for a few decades aging at temperatures slightly above ambient. This prediction is consistent with additional sealed-tube aging experiments at 100-120 C, which are estimated to have an effective thermal dose greater than that from decades of exposure to temperatures slightly above ambient.« less

A Simple Photochemical Conversion of Perfluoroalkyl Hydrides to Perfluoroalkyl Bromides Using Interhalogen Compounds.

DTIC Science & Technology

1983-05-31

slower (100 hrs) than the ambient temperature chlorination of that compound (10 minutes). The reaction was followed by gas phase infrared spectroscopy...excess of bromine to chlorine and a slightly shorter (254 hrs) reaction time slightly increases the yield of bromo-F-neopentane. The 19F NMR data (Table... chlorination products, however, optimal bromina- tion (4.4:1) occurred for reaction 4 which produced predominately 1-bromo-3- hydryl-F-neopentane (48%). It

Ultrasound effects on the degradation kinetics, structure, and antioxidant activity of sea cucumber fucoidan.

PubMed

Guo, Xin; Ye, Xingqian; Sun, Yujing; Wu, Dan; Wu, Nian; Hu, Yaqin; Chen, Shiguo

2014-02-05

The effects of ultrasound on the molecular weight, structure, and antioxidant potential of a fucoidan found in Isostichopus badionotus were investigated. The results showed the molecular weight (Mw) of fucoidan decreased obviously after ultrasound treatment. Higher ultrasonic intensity, lower temperature, and lower fucoidan concentrations led to a more effective sonochemical effect. The kinetic model for fucoidan degradation fitted to 1/M(wt)-1/M(w0) = kt at the tested temperature. The optimized degradation conditions by response surface methodology (RSM) were temperature, 12 °C, and intensity, 508 W/cm². Structural analysis by FTIR and NMR indicated the fucoidan kept the linear tetrasaccharide repeating units as the original polysaccharides after the ultrasound treatment, with only slight destruction of the middle nonsulfated fucose units. Antioxidant activity assay showed the antioxidant activity was slightly improved by the ultrasound treatment. The results suggested that ultrasound treatment is an effective approach to decrease the M(w) of fucoidan with only minor structural destruction.

On the Impact of Wind Farms on a Convective Atmospheric Boundary Layer

NASA Astrophysics Data System (ADS)

Lu, Hao; Porté-Agel, Fernando

2015-10-01

With the rapid growth in the number of wind turbines installed worldwide, a demand exists for a clear understanding of how wind farms modify land-atmosphere exchanges. Here, we conduct three-dimensional large-eddy simulations to investigate the impact of wind farms on a convective atmospheric boundary layer. Surface temperature and heat flux are determined using a surface thermal energy balance approach, coupled with the solution of a three-dimensional heat equation in the soil. We study several cases of aligned and staggered wind farms with different streamwise and spanwise spacings. The farms consist of Siemens SWT-2.3-93 wind turbines. Results reveal that, in the presence of wind turbines, the stability of the atmospheric boundary layer is modified, the boundary-layer height is increased, and the magnitude of the surface heat flux is slightly reduced. Results also show an increase in land-surface temperature, a slight reduction in the vertically-integrated temperature, and a heterogeneous spatial distribution of the surface heat flux.

Effect of different postharvest temperatures on the accumulation of sugars, organic acids, and amino acids in the juice sacs of Satsuma mandarin (Citrus unshiu Marc.) fruit.

PubMed

Matsumoto, Hikaru; Ikoma, Yoshinori

2012-10-03

To elucidate the effect of different postharvest temperatures on the accumulation of sugars, organic acids, and amino acids and to determine the best temperature to minimize their postharvest change, their content after harvest was investigated at 5, 10, 20, and 30 °C for 14 days in the juice sacs of Satsuma mandarin (Citrus unshiu Marc. cv. Aoshima-unshiu) fruit. In all sugars, the changes were negligible at all temperatures. Organic acids decreased slightly at all temperatures, with the exception of malic acid at 30 °C, which increased slightly. Two amino acids, ornithine and glutamine, increased at 5 °C, but they did not increase at other temperatures. In 11 amino acids (phenylalanine, tryptophan, tyrosine, isoleucine, leucine, valine, threonine, lysine, methionine, histidine, and γ-amino butyric acid), the content was higher at 20 and 30 °C than at other temperatures. Thus, the content of amino acids was more variable than that of sugars and organic acids in response to temperatures. Moreover, amino acids responded to temperature differently: two amino acids were cold responsive, and 11 were heat-responsive. The best temperature to minimize the postharvest changes in amino acid profiles in the juice sacs of Aoshima-unshiu was 10 °C. The responsiveness to temperatures in two cold-responsive (ornithine and glutamine) and five heat-responsive (phenylalanine, tryptophan, valine, lysine, and histidine) amino acids was conserved among three different Satsuma mandarin cultivars, Aoshima-unshiu (late-maturing cultivar), Silverhill (midmaturing cultivar), and Miyagawa-wase (early-maturing cultivar). The metabolic responsiveness to temperature stress was discussed on the basis of the changes in the amino acid profile.

Accounting For Nonlinearity In A Microwave Radiometer

NASA Technical Reports Server (NTRS)

Stelzried, Charles T.

1991-01-01

Simple mathematical technique found to account adequately for nonlinear component of response of microwave radiometer. Five prescribed temperatures measured to obtain quadratic calibration curve. Temperature assumed to vary quadratically with reading. Concept not limited to radiometric application; applicable to other measuring systems in which relationships between quantities to be determined and readings of instruments differ slightly from linearity.

Extraction and separation of tungsten (VI) from aqueous media with Triton X-100-ammonium sulfate-water aqueous two-phase system without any extractant.

PubMed

Yongqiang Zhang; Tichang Sun; Tieqiang Lu; Chunhuan Yan

2016-11-25

An aqueous two-phase system composed of Triton X-100-(NH 4 ) 2 SO 4 -H 2 O was proposed for extraction and separation of tungsten(VI) from aqueous solution without using any extractant. The effects of aqueous pH, concentration of ammonium sulfate, Triton X-100 and tungsten, extracting temperature on the extraction of tungsten were investigated. The extraction of tungsten has remarkable relationship with aqueous pH and are to above 90% at pH=1.0-3.0 under studied pH range (pH=1.0-7.0) and increases gradually with increasing Triton X-100 concentration, but decreases slightly with increasing ammonium sulfate concentration. The extraction percentage of tungsten is hardly relevant to temperature but its distribution coefficient linearly increases with increasing temperature within 303.15-343.15K. The distribution coefficient of tungsten increases with the increase of initial tungsten concentration (0.1-3%) and temperature (303.15 K-333.15K). The solubilization capacity of tungsten in Triton X-100 micellar phase is independent of temperature. FT-IR analysis reveals that there is no evident interaction between polytungstate anion and ether oxygen unit in Triton X-100, and DLS analysis indicates that zeta potential of Triton X-100 micellar phase have a little change from positive to negative after extracting tungsten. Based on the above-mentioned results, it can be deduced that polytungstate anions are solubilized in hydrophilic outer shell of Triton X-100 micelles by electrostatic attraction depending on its relatively high hydrophobic nature. The stripping of tungsten is mainly influenced by temperature and can be easily achieved to 95% in single stage stripping. The tungsten (VI) is separated out from solution containing Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Al(III), Cr(III) and Mn(II) under the suitable conditions. Copyright © 2016 Elsevier B.V. All rights reserved.

Performance evaluation of NCEP climate forecast system for the prediction of winter temperatures over India

NASA Astrophysics Data System (ADS)

Nageswararao, M. M.; Mohanty, U. C.; Kiran Prasad, S.; Osuri, Krishna K.; Ramakrishna, S. S. V. S.

2016-11-01

The surface air temperature during the winter season (December-February) in India adversely affects agriculture as well as day-to-day life. Therefore, the accurate prediction of winter temperature in extended range is of utmost importance. The National Center for Environmental Prediction (NCEP) has been providing climatic variables from the fully coupled global climate model, known as Climate Forecast System version 1 (CFSv1) on monthly to seasonal scale since 2004, and it has been upgraded to CFSv2 subsequently in 2011. In the present study, the performance of CFSv1 and CFSv2 in simulating the winter 2 m maximum, minimum, and mean temperatures ( T max, T min, and T mean, respectively) over India is evaluated with respect to India Meteorological Department (IMD) 1° × 1° observations. The hindcast data obtained from both versions of CFS from 1982 to 2009 (27 years) with November initial conditions (lead-1) are used. The analyses of winter ( T max, T min, and T mean) temperatures revealed that CFSv1 and CFSv2 are able to replicate the patterns of observed climatology, interannual variability, and coefficient of variation with a slight negative bias. Of the two, CFSv2 is appreciable in capturing increasing trends of winter temperatures like observed. The T max, T min, and T mean correlations from CFSv2 is significantly high (0.35, 0.53, and 0.51, respectively), while CFSv1 correlations are less (0.29, 0.15, and 0.12) and insignificant. This performance of CFSv2 may be due to the better estimation of surface heat budget terms and realistic CO2 concentration, which were absent in CFSv1. CFSv2 proved to have a high probability of detection in predicting different categories (below, near, and above normal) for winter T min, which are required for crop yield and public utility services, over north India.

Dry seasons identified in oak tree-ring chronology in the Czech Lands over the last millennium

NASA Astrophysics Data System (ADS)

Dobrovolny, Petr; Brazdil, Rudolf; Büntgen, Ulf; Rybnicek, Michal; Kolar, Tomas; Reznickova, Ladislava; Valasek, Hubert; Kotyza, Oldrich

2015-04-01

There is growing evidence on amplification of hydrological regimes as a consequence of rising temperatures, increase in evaporation and changes in circulation patterns. These processes may be responsible for higher probability of hydroclimatic extremes occurrence in regional scale. Extreme events such as floods or droughts are rare from their definition and for better understanding of possible changes in the frequency and intensity of their occurrence, long-term proxy archives may be analysed. Recently several tree ring width chronologies were compiled from hardwood species occurring in lowland positions and their analysis proved that they are moisture-sensitive and suitable for hydroclimate reconstructions. Here, we introduce a new oak (Quercus sp) ring width (RW) dataset for the Czech Republic and the last 1250 years. We explain the process of oak chronology standardization that was based on several only slightly different de-trending techniques and subsequent chronology development steps. We hypothesize that the most severe RW increment reductions (negative extremes) reflect extremely dry spring-summer conditions. Negative extremes were assigned for years in which transformed oak RWs were lower than the minus 1.5 standard deviation. To verify our hypothesis, we compare typical climatic conditions in negative extreme years with climatology of the reference period 1961-1990. Comparison was done for various instrumental measurements (1805-2012), existing proxy reconstructions (1500-1804) and also for documentary evidence from historical archives (before 1500). We found that years of negative extremes are characterized with distinctly above average spring (MAM) and summer (JJA) air temperatures and below average precipitation amounts. Typical sea level pressure spatial distribution in those years shows positive pressure anomaly over British Isles and Northern Sea, the pattern that synoptically corresponds to blocking anticyclone bringing to Central Europe warm air from SW and low precipitation totals with higher probability of drought occurrence. Our results provide consistent physical explanation of extremely dry seasons occurring in Central Europe. However, direct comparisons of individual RW extreme seasons with existing documentary evidence show the complexity the problem as some extremes identified in oak RW chronology were not confirmed in documentary archives and vice versa. We discuss possible causes of such differences related to the fact that various proxies may have problems to record real intensity or duration of extreme events e.g. due to non-linear response of proxy data to climate drivers or due to shift in seasonality.

Age differences in the Big Five across the life span: evidence from two national samples.

PubMed

Donnellan, M Brent; Lucas, Richard E

2008-09-01

Cross-sectional age differences in the Big Five personality traits were investigated using 2 large datasets from Great Britain and Germany: the British Household Panel Study (BHPS; N > or = 14,039) and the German Socio-Economic Panel Study (GSEOP; N > or = 20,852). Participants, who ranged in age from 16 to the mid-80s, completed a 15-item version of the Big Five Inventory (e.g., John & Srivastava, 1999) in either 2005 or 2006. The observed age trends were generally consistent across both datasets. Extraversion and Openness were negatively associated with age, whereas Agreeableness was positively associated with age. Average levels of Conscientiousness were highest for participants in middle age. The only exception was Neuroticism, which was slightly negatively associated with age in the BHPS and slightly positively associated with age in the GSEOP. Neither gender nor education level were consistent moderators of age differences in the Big Five. (c) 2008 APA, all rights reserved

Cardiovascular responses of men and women to lower body negative pressure

NASA Technical Reports Server (NTRS)

Montgomery, L. D.; Kirk, P. J.; Payne, P. A.; Gerber, R. L.; Newton, S. D.; Williams, B. A.

1977-01-01

Changes in blood flow and blood redistribution were measured by impedance plethysmography in the pelvic and leg regions of six male and four female subjects during three 5-min exposures to -20, -40, and -60 mm Hg lower body negative pressure (LBNP). Female subjects demonstrated significantly higher mean heart rate and lower leg blood flow indices than the male subjects during the recumbent control periods. Men had slightly higher mean resting systolic and diastolic blood pressures and higher mean control pelvic blood indices. Women demonstrated significantly less blood pooling in the legs and slightly less in the pelvic region than the men. All of the 18 tests with male subjects at -60 mm Hg were completed without initial signs of syncope, while only two of the tests with women were completed successfully without the subject exhibiting presyncopal conditions. Results indicate that impedance plethysmography can be used to measure segmental cardiovascular responses during LBNP and that females may be less tolerant to -60 mm Hg LBNP than males.

When Slights Beget Slights: Attachment Anxiety, Subjective Time, and Intrusion of the Relational Past in the Present.

PubMed

Cortes, Kassandra; Wilson, Anne E

2016-12-01

Every close relationship has a history, but how people manage their relational past varies and can have important implications in the present. The current research investigated the role of subjective representation of time: How feeling subjectively close (vs. distant) to a past relational transgression (vs. kind act) predicted "kitchen thinking"-the tendency to bring to mind relational past memories in new, unrelated contexts. We explored the role of attachment anxiety as a predictor of subjective time perception and kitchen thinking. We found support for our hypothesis that when negative memories felt subjectively closer relative to positive memories, people were more likely to kitchen think (Studies 1-3). Kitchen thinking, in turn, predicted negative relationship outcomes (Study 4). Furthermore, people high (vs. low) in attachment anxiety were less likely to perceive the timing of their relational memories adaptively, accounting for more kitchen thinking and in turn, maladaptive relational outcomes. © 2016 by the Society for Personality and Social Psychology, Inc.

The incidence and role of negative citations in science.

PubMed

Catalini, Christian; Lacetera, Nicola; Oettl, Alexander

2015-11-10

Citations to previous literature are extensively used to measure the quality and diffusion of knowledge. However, we know little about the different ways in which a study can be cited; in particular, are papers cited to point out their merits or their flaws? We elaborated a methodology to characterize "negative" citations using bibliometric data and natural language processing. We found that negative citations concerned higher-quality papers, were focused on a study's findings rather than theories or methods, and originated from scholars who were closer to the authors of the focal paper in terms of discipline and social distance, but not geographically. Receiving a negative citation was also associated with a slightly faster decline in citations to the paper in the long run.

Differences in reported linguistic thermal sensation between Bangla and Japanese speakers.

PubMed

Khatun, Aklima; Hasib, Md Abdul; Nagano, Hisaho; Taimura, Akihiro

2017-06-05

Thermal sensation is a fundamental variable used to determine thermal comfort and is most frequently evaluated through the use of subjective reports in the field of environmental physiology. However, there has been little study of the relationship between the semantics of the words used to describe thermal sensation and the climatic background. The present study investigates the linguistic differences in thermal reports from native speakers of Bangla and Japanese. A total of 1141 university students (932 in Bangladesh and 209 in Japan) responded to a questionnaire survey consisting of 20 questions. Group differences between Bangladeshi and Japanese respondents were then tested with a chi-square test in a crosstab analysis using SPSS (version 21). For the Bangla-speaking respondents, the closest feeling of thermal comfort was "neutral" (66.6%) followed by "slightly cool" (10.2%), "slightly cold" (6.0%), "slightly hot" (4.1%), and "cold" (3.8%). For the Japanese respondents, the closest feeling of thermal comfort was "cool" (38.3%) followed by "slightly cool" (20.4%), "neutral" (14.6%), "slightly warm" (13.1%), and "warm" (10.7%). Of the Bangladeshi respondents, 37.7% reported that they were sensitive to cold weather and 18.1% reported that they were sensitive to hot weather. Of the Japanese respondents, 20.6% reported that they were sensitive to cold weather and 29.2% reported that they were sensitive to hot weather. Of the Bangladeshi respondents, 51.4% chose "higher than 29 °C" as hot weather and 38.7% of the Japanese respondents chose "higher than 32 °C" as hot weather. In the case of cold weather, 43.1% of the Bangladeshi respondents selected "lower than 15 °C" as cold weather and 53.4% of the Japanese respondents selected "lower than 10 °C" as cold weather. Most of the Bangla-speaking respondents chose "neutral" as the most comfortable temperature, and most of the Japanese respondents chose "cool." Most of the Bangladeshi respondents reported that they were sensitive to "cold temperatures," but most of the Japanese respondents reported that they were sensitive to "hot temperatures."

Exploring the causes of Colorado River streamflow declines

NASA Astrophysics Data System (ADS)

Xiao, M.; Lettenmaier, D. P.; Udall, B. H.

2016-12-01

As the major river of the Southwestern U.S., the Colorado River (CR) is central to the region's water resources. Over the period 1916-2014, the river's naturalized Apr-Sep flow at Lee's Ferry declined by 18.4%, a number that is closely matched (19.8%) by reconstructions for the same period using the Variable Infiltration Capacity (VIC) hydrology model. However, basin-average annual precipitation over that period declined by only 4.4%. In order to examine the causes of the runoff declines, we performed experiments with the VIC model in which we detrended the model's temperature forcings (about 1.6°C over the 100-year record) for each of 24 sub-basins that make up the basin. We find that decreases in winter precipitation (the season that controls annual runoff) mostly occured in the northeast part of the basin while summer precipitation decreases (which have much less effect on annual runoff) occurred over much of the lower basin. Our model simulations suggest that about 2/3 of observed runoff declines are attributable to decreases in winter precipitation (most importantly, in the upper basin, where most of the basin's runoff is generated). The remaining 1/3 is attributable to warming temperatures. We also examine what appear to be changing characteristics of droughts in the basin. Compared with a prolonged drought in the 1960s, which was characterized by abnormally low precipitation and cool temperatures, temperatures during the ongoing millennial drought have been much warmer, but winter precipitation anomalies have been only slightly negative. During the 2000s drought, the basin-wide runoff anomaly has been about -3.8 km3/yr, with four sub-basins in the northeastern part of the basin accounting for about 2/3 of the annual runoff anomaly.

Lattice constants and expansivities of gas hydrates from 10 K up to the stability limit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hansen, T. C.; Falenty, A.; Kuhs, W. F.

2016-02-07

The lattice constants of hydrogenated and deuterated CH{sub 4}-, CO{sub 2}-, Xe- (clathrate structure type I) and N{sub 2}-hydrates (clathrate structure type II) from 10 K up to the stability limit were established in neutron- and synchrotron diffraction experiments and were used to derive the related thermal expansivities. The following results emerge from this analysis: (1) The differences of expansivities of structure type I and II hydrates are fairly small. (2) Despite the larger guest-size of CO{sub 2} as compared to methane, CO{sub 2}-hydrate has the smaller lattice constants at low temperatures, which is ascribed to the larger attractive guest-hostmore » interaction of the CO{sub 2}-water system. (3) The expansivity of CO{sub 2}-hydrate is larger than for CH{sub 4}-hydrate which leads to larger lattice constants for the former at temperatures above ∼150 K; this is likely due to the higher motional degrees of freedom of the CO{sub 2} guest molecules. (4) The cage occupancies of Xe- and CO{sub 2}-hydrates affect significantly the lattice constants. (5) Similar to ice Ih, the deuterated compounds have generally slightly larger lattice constants which can be ascribed to the somewhat weaker H-bonding. (6) Compared to ice Ih, the high temperature expansivities are about 50% larger; in contrast to ice Ih and the empty hydrate, there is no negative thermal expansion at low temperature. (7) A comparison of the experimental results with lattice dynamical work, with models based on an Einstein oscillator model, and results from inelastic neutron scattering suggest that the contribution of the guest atoms’ vibrational energy to thermal expansion is important, most prominently for CO{sub 2}- and Xe-hydrates.« less

Risk of spring frost to apple production under future climate scenarios: the role of phenological acclimation.

PubMed

Eccel, Emanuele; Rea, Roberto; Caffarra, Amelia; Crisci, Alfonso

2009-05-01

In the context of global warming, the general trend towards earlier flowering dates of many temperate tree species is likely to result in an increased risk of damage from exposure to frost. To test this hypothesis, a phenological model of apple flowering was applied to a temperature series from two locations in an important area for apple production in Europe (Trentino, Italy). Two simulated 50-year climatic projections (A2 and B2 of the Intergovernmental Panel on Climate Change--Special Report on Emission Scenarios) from the HadCM3 general circulation model were statistically downscaled to the two sites. Hourly temperature records over a 40-year period were used as the reference for past climate. In the phenological model, the heat requirement (degree hours) for flowering was parameterized using two approaches; static (constant over time) and dynamic (climate dependent). Parameterisation took into account the trees' adaptation to changing temperatures based on either past instrumental records or the downscaled outputs from the climatic simulations. Flowering dates for the past 40 years and simulated flowering dates for the next 50 years were used in the model. A significant trend towards earlier flowering was clearly detected in the past. This negative trend was also apparent in the simulated data. However, the significance was less apparent when the "dynamic" setting for the degree hours requirement was used in the model. The number of frost episodes and flowering dates, on an annual basis, were graphed to assess the risk of spring frost. Risk analysis confirmed a lower risk of exposure to frost at present than in the past, and probably either constant or a slightly lower risk in future, especially given that physiological processes are expected to acclimate to higher temperatures.

Development of a Cell Sheet Transportation Technique for Regenerative Medicine

PubMed Central

Oie, Yoshinori; Nozaki, Takayuki; Takayanagi, Hiroshi; Hara, Susumu; Hayashi, Ryuhei; Takeda, Shizu; Mori, Keisuke; Moriya, Noboru; Soma, Takeshi; Tsujikawa, Motokazu; Saito, Kazuo

2014-01-01

Purpose: A transportation technique for cell sheets is necessary to standardize regenerative medicine. The aim of this article is to develop and evaluate a new transportation technique for cell sheets. Material and Methods: We developed a transportation container with three basic functions: the maintenance of interior temperature, air pressure, and sterility. The interior temperature and air pressure were monitored by a recorder. Human oral mucosal epithelial cells obtained from two healthy volunteers were cultured on temperature-responsive culture dishes. The epithelial cell sheets were transported via an airplane between the Osaka University and Tohoku University using the developed cell transportation container. Histological and immunohistochemical analyses and flow cytometric analyses for cell viability and cell purity were performed for the cell sheets before and 12 h after transportation to assess the influence of transportation on the cell sheets. Sterility tests and screening for endotoxin and mycoplasma in the cell sheets were performed before and after transportation. Results: During transportation via an airplane, the temperature inside the container was maintained above 32°C, and the changes in air pressure remained within 10 hPa. The cell sheets were well stratified and successfully harvested before and after transportation. The expression patterns of keratin 3/76, p63, and MUC16 were equivalent before and after transportation. However, the expression of ZO-1 in the cell sheet after transportation was slightly weaker than that before transportation. The cell viability was 72.0% before transportation and 77.3% after transportation. The epithelial purity was 94.6% before transportation and 87.9% after transportation. Sterility tests and screening for endotoxin and mycoplasma were negative for all cell sheets. Conclusion: The newly developed transportation technique for air travel is essential technology for regenerative medicine and promotes the standardization and spread of regenerative therapies. PMID:24044382

Thermal effects on bacterial bioaerosols in continuous air flow.

PubMed

Jung, Jae Hee; Lee, Jung Eun; Kim, Sang Soo

2009-08-01

Exposure to bacterial bioaerosols can have adverse effects on health, such as infectious diseases, acute toxic effects, and allergies. The search for ways of preventing and curing the harmful effects of bacterial bioaerosols has created a strong demand for the study and development of an efficient method of controlling bioaerosols. We investigated the thermal effects on bacterial bioaerosols of Escherichia coli and Bacillus subtilis by using a thermal electric heating system in continuous air flow. The bacterial bioaerosols were exposed to a surrounding temperature that ranged from 20 degrees C to 700 degrees C for about 0.3 s. Both E. coli and B. subtilis vegetative cells were rendered more than 99.9% inactive at 160 degrees C and 350 degrees C of wall temperature of the quartz tube, respectively. Although the data on bacterial injury showed that the bacteria tended to sustain greater damage as the surrounding temperature increased, Gram-negative E. coli was highly sensitive to structural injury but Gram-positive B. subtilis was slightly more sensitive to metabolic injury. In addition, the inactivation of E. coli endotoxins was found to range from 9.2% (at 200 degrees C) to 82.0% (at 700 degrees C). However, the particle size distribution and morphology of both bacterial bioaerosols were maintained, despite exposure to a surrounding temperature of 700 degrees C. Our results show that thermal heating in a continuous air flow can be used with short exposure time to control bacterial bioaerosols by rendering the bacteria and endotoxins to a large extent inactive. This result could also be useful for developing more effective thermal treatment strategies for use in air purification or sterilization systems to control bioaerosols.

Development of a cell sheet transportation technique for regenerative medicine.

PubMed

Oie, Yoshinori; Nozaki, Takayuki; Takayanagi, Hiroshi; Hara, Susumu; Hayashi, Ryuhei; Takeda, Shizu; Mori, Keisuke; Moriya, Noboru; Soma, Takeshi; Tsujikawa, Motokazu; Saito, Kazuo; Nishida, Kohji

2014-05-01

A transportation technique for cell sheets is necessary to standardize regenerative medicine. The aim of this article is to develop and evaluate a new transportation technique for cell sheets. We developed a transportation container with three basic functions: the maintenance of interior temperature, air pressure, and sterility. The interior temperature and air pressure were monitored by a recorder. Human oral mucosal epithelial cells obtained from two healthy volunteers were cultured on temperature-responsive culture dishes. The epithelial cell sheets were transported via an airplane between the Osaka University and Tohoku University using the developed cell transportation container. Histological and immunohistochemical analyses and flow cytometric analyses for cell viability and cell purity were performed for the cell sheets before and 12 h after transportation to assess the influence of transportation on the cell sheets. Sterility tests and screening for endotoxin and mycoplasma in the cell sheets were performed before and after transportation. During transportation via an airplane, the temperature inside the container was maintained above 32°C, and the changes in air pressure remained within 10 hPa. The cell sheets were well stratified and successfully harvested before and after transportation. The expression patterns of keratin 3/76, p63, and MUC16 were equivalent before and after transportation. However, the expression of ZO-1 in the cell sheet after transportation was slightly weaker than that before transportation. The cell viability was 72.0% before transportation and 77.3% after transportation. The epithelial purity was 94.6% before transportation and 87.9% after transportation. Sterility tests and screening for endotoxin and mycoplasma were negative for all cell sheets. The newly developed transportation technique for air travel is essential technology for regenerative medicine and promotes the standardization and spread of regenerative therapies.

Non-linear properties of metallic cellular materials with a negative Poisson's ratio

NASA Technical Reports Server (NTRS)

Choi, J. B.; Lakes, R. S.

1992-01-01

Negative Poisson's ratio copper foam was prepared and characterized experimentally. The transformation into re-entrant foam was accomplished by applying sequential permanent compressions above the yield point to achieve a triaxial compression. The Poisson's ratio of the re-entrant foam depended on strain and attained a relative minimum at strains near zero. Poisson's ratio as small as -0.8 was achieved. The strain dependence of properties occurred over a narrower range of strain than in the polymer foams studied earlier. Annealing of the foam resulted in a slightly greater magnitude of negative Poisson's ratio and greater toughness at the expense of a decrease in the Young's modulus.

Skin temperature evaluation by infrared thermography: Comparison of two image analysis methods during the nonsteady state induced by physical exercise

NASA Astrophysics Data System (ADS)

Formenti, Damiano; Ludwig, Nicola; Rossi, Alessio; Trecroci, Athos; Alberti, Giampietro; Gargano, Marco; Merla, Arcangelo; Ammer, Kurt; Caumo, Andrea

2017-03-01

The most common method to derive a temperature value from a thermal image in humans is the calculation of the average of the temperature values of all the pixels confined within a demarcated boundary defined region of interest (ROI). Such summary measure of skin temperature is denoted as Troi in this study. Recently, an alternative method for the derivation of skin temperature from the thermal image has been developed. Such novel method (denoted as Tmax) is based on an automated (software-driven) selection of the warmest pixels within the ROI. Troi and Tmax have been compared under basal, steady-state conditions, resulting very well correlated and characterized by a bias of approximately 1 °C (Tmax > Troi). Aim of this study was to investigate the relationship between Tmax and Troi under the nonsteady-state conditions induced by physical exercise. Thermal images of quadriceps of 13 subjects performing a squat exercise were recorded for 120 s before (basal steady state) and for 480 s after the initiation of the exercise (nonsteady state). The thermal images were then analysed to extract Troi and Tmax. Troi and Tmax changed almost in parallel during the nonstead -state. At a closer inspection, it was found that during the nonsteady state the bias between the two methods slightly increased (from 0.7 to 1.1 °C) and the degree of association between them slightly decreased (from Pearson's r = 0.96 to 0.83). Troi and Tmax had different relationships with the skin temperature histogram. Whereas Tmax was the mean, which could be interpreted as the centre of gravity of the histogram, Tmax was related with the extreme upper tail of the histogram. During the nonsteady state, the histogram increased its spread and became slightly more asymmetric. As a result, Troi deviated a little from the 50th percentile, while Tmax remained constantly higher than the 95th percentile. Despite their differences, Troi and Tmax showed a substantial agreement in assessing the changes in skin temperature following physical exercise. Further studies are needed to clarify the relationship existing among Tmax, Troi and cutaneous blood flow during physical exercise.

Cell viability and protein turnover in nongrowing Bacillus megaterium at sporulation suppressing temperature.

PubMed

Kucerová, H; Strnadová, M; Ludvík, J; Chaloupka, J

1999-01-01

In Bacillus megaterium, a temperature that suppresses sporulation (43 degrees C) only slightly exceeds both the optimum growth temperature and the temperature still permitting sporulation (40-41 degrees C). Here we show that, when cells grown at 35 degrees C and transferred to a sporulation medium, were subjected to shifts between 35 degrees C and the sporulation suppressing temperature (SST, 43 degrees C), their development and proteolytic activities were deeply affected. During the reversible sporulation phase that took place at 35 degrees C for 2-3 h (T2-T3), the cells developed forespores and their protein turnover was characterized by degradation of short-lived proteins and proteins made accessible to the proteolytic attack because of starvation. During the following irreversible sporulation phase refractile heat-resistant spores appeared at T4-T5. Protein turnover rate increased again after T2 and up to T8 60-70% prelabelled proteins were degraded. The SST suppressed sporulation at its beginning; at T3 no asymmetric septa were observed and the amount of heat-resistant spores at T8 was by 4-5 orders lower than at 35 degrees C. However, the cells remained viable and were able to sporulate when transferred to a lower temperature. Protein degradation was increased up to T3 but then its velocity sharply dropped and the amount of degraded protein at T8 corresponded to slightly more than one-half of that found at 35 degrees C. The cytoplasmic proteolytic activity was enhanced but the activity in the membrane fraction was decreased. When a temperature shift to SST was applied at the beginning of the irreversible sporulation phase (T2.5), the sporulation process was impaired. A portion of forespores lyzed, the others were able to complete their development but most spores were not heat-resistant and their coats showed defects. Protein degradation increased again because an effective proteolytic system was developed during the reversible sporulation phase but the amount of degraded protein was slightly lower than at 35 degrees C. A later (T4) shift to SST had no effect on the sporulation process.

Experimental and theoretical investigation of temperature effects on an interbedded betavoltaic employing epitaxial Si and bidirectional (63)Ni.

PubMed

Liu, Yunpeng; Tang, Xiaobin; Xu, Zhiheng; Hong, Liang; Chen, Da

2014-12-01

The performance of an interbedded betavoltaic employing epitaxial Si and bidirectional (63)Ni was measured and calculated at various temperatures. The experimental results indicate that the temperature dependence of the performance of interbedded betavoltaics is similar to that of monolayer betavoltaics: Voc and Pmax decrease approximately linearly with increasing temperature at low temperatures of 213.15-253.15K and decrease exponentially with increasing temperature at high temperatures of 253.15-333.15K. However, the calculation results indicate that the temperature dependences of Voc and Pmax are always linear at both high and low temperatures. Isc increases slightly with increasing temperature in both experiment and calculation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Soil Temperature Effects on the Interaction of Grape Rootstocks and Plant-parasitic Nematodes.

PubMed

Ferris, H; Zheng, L; Walker, M A

2013-03-01

Resistance to Meloidogyne spp. in commonly used resistant grape rootstocks is slightly compromised at soil temperatures above 27°C. Newly released UCD-GRN series rootstocks, which have broad nematode resistance, exhibit trace infections by Meloidogyne spp. at elevated temperature. Pathotypes of M. incognita and M. arenaria that are virulent on 'Harmony' rootstock, as well as M. incognita Race 3, which is avirulent on 'Harmony', failed to produce egg masses on the UCD-GRN series rootstocks and other resistant selections at 24°C. At 27°C and above, there was increased nematode galling and egg mass production; at 30°C, egg mass production levels of M. incognita Race 3 on 'Harmony' were up to 12% of that on susceptible 'Colombard' while reproduction of the virulent pathotypes on the UCD-GRN series was less than 5% of that on 'Colombard'. Resistance of several of the parental genotypes of the UCD-GRN rootstock series was slightly compromised at soil temperatures of 30°C and above; however, others maintained their resistance to even the virulent M. arenaria pathotype A at high temperatures. Effects of high temperature on resistance to Xiphinema index could not be assessed because of temperature sensitivity of the nematodes while resistance to Mesocriconema xenoplax was not compromised at high soil temperature. Resistance to Meloidogyne spp. in the UCD-GRN series rootstocks was not compromised when plants and nematodes were subjected to cyclical high and low temperature conditions, indicating that once initiated, the resistance mechanism is not reversed.

Soil Temperature Effects on the Interaction of Grape Rootstocks and Plant-parasitic Nematodes

PubMed Central

Ferris, H.; Zheng, L.; Walker, M. A.

2013-01-01

Resistance to Meloidogyne spp. in commonly used resistant grape rootstocks is slightly compromised at soil temperatures above 27°C. Newly released UCD-GRN series rootstocks, which have broad nematode resistance, exhibit trace infections by Meloidogyne spp. at elevated temperature. Pathotypes of M. incognita and M. arenaria that are virulent on ‘Harmony’ rootstock, as well as M. incognita Race 3, which is avirulent on ‘Harmony’, failed to produce egg masses on the UCD-GRN series rootstocks and other resistant selections at 24°C. At 27°C and above, there was increased nematode galling and egg mass production; at 30°C, egg mass production levels of M. incognita Race 3 on ‘Harmony’ were up to 12% of that on susceptible ‘Colombard’ while reproduction of the virulent pathotypes on the UCD-GRN series was less than 5% of that on ‘Colombard’. Resistance of several of the parental genotypes of the UCD-GRN rootstock series was slightly compromised at soil temperatures of 30°C and above; however, others maintained their resistance to even the virulent M. arenaria pathotype A at high temperatures. Effects of high temperature on resistance to Xiphinema index could not be assessed because of temperature sensitivity of the nematodes while resistance to Mesocriconema xenoplax was not compromised at high soil temperature. Resistance to Meloidogyne spp. in the UCD-GRN series rootstocks was not compromised when plants and nematodes were subjected to cyclical high and low temperature conditions, indicating that once initiated, the resistance mechanism is not reversed. PMID:23589660

Influence of nitromethane concentration on ignition energy and explosion parameters in gaseous nitromethane/air mixtures.

PubMed

Zhang, Qi; Li, Wei; Lin, Da-Chao; He, Ning; Duan, Yun

2011-01-30

The aim of this paper is to provide new experimental data of the minimum ignition energy (MIE) of gaseous nitromethane/air mixtures to discuss the explosion pressure and the flame temperature as a function of nitromethane concentration. Observations on the influence of nitromethane concentration on combustion pressure and temperature through the pressure and temperature measure system show that peak temperature (the peak of combustion temperature wave) is always behind peak pressure (the peak of the combustion pressure wave) in arrival time, the peak combustion pressure of nitromethane increases in the range of its volume fraction 10-40% as the concentration of nitromethane increases, and it slightly decreases in the range of 40-50%. The maximum peak pressure is equal to 0.94 MPa and the minimum peak pressure 0.58 MPa. Somewhat similar to the peak pressure, the peak combustion temperature increases with the volume fraction of nitromethane in the range of 10-40%, and slightly decreases in 40-50%. The maximum peak temperature is 1340 °C and the minimum 860 °C. The combustion temperature rise rate increases with the concentration of nitromethane in 10-30%, while decreases in 30-50% and its maximum value of combustion temperature rise rate in 10-50% is 4200 °C/s at the volume fraction of 30%. Influence of the concentration of nitromethane on the combustion pressure rise rate is relatively complicated, and the maximum value of rise rate of combustion pressure wave in 10-50% is 11 MPa/s at the concentration 20%. Copyright © 2010 Elsevier B.V. All rights reserved.

Effect of low air velocities on thermal homeostasis and comfort during exercise at space station operational temperature and humidity

NASA Technical Reports Server (NTRS)

Beumer, Ronald J.

1989-01-01

The effectiveness of different low air velocities in maintaining thermal comfort and homeostasis during exercise at space station operational temperature and humidity was investigated. Five male subjects exercised on a treadmill for successive ten minute periods at 60, 71, and 83 percent of maximum oxygen consumption at each of four air velocities, 30, 50, 80, and 120 ft/min, at 22 C and 62 percent relative humidity. No consistent trends or statistically significant differences between air velocities were found in body weight loss, sweat accumulation, or changes in rectal, skin, and body temperatures. Occurrence of the smallest body weight loss at 120 ft/min, the largest sweat accumulation at 30 ft/min, and the smallest rise in rectal temperature and the greatest drop in skin temperature at 120 ft/min all suggested more efficient evaporative cooling at the highest velocity. Heat storage at all velocities was evidenced by increased rectal and body temperatures; skin temperatures declined or increased only slightly. Body and rectal temperature increases corresponded with increased perception of warmth and slight thermal discomfort as exercise progressed. At all air velocities, mean thermal perception never exceeded warm and mean discomfort, greatest at 30 ft/min, was categorized at worst as uncomfortable; sensation of thermal neutrality and comfort returned rapidly after cessation of exercise. Suggestions for further elucidation of the effects of low air velocities on thermal comfort and homeostasis include larger numbers of subjects, more extensive skin temperature measurements and more rigorous analysis of the data from this study.

At the edge of the thermal window: effects of elevated temperature on the resting metabolism, hypoxia tolerance and upper critical thermal limit of a widespread African cichlid

PubMed Central

McDonnell, Laura H.; Chapman, Lauren J.

2015-01-01

Tropical inland fishes are predicted to be especially vulnerable to thermal stress because they experience small temperature fluctuations that may select for narrow thermal windows. In this study, we measured resting metabolic rate (RMR), critical oxygen tension (Pcrit) and critical thermal maximum (CTMax) of the widespread African cichlid (Pseudocrenilabrus multicolor victoriae) in response to short-term acclimation to temperatures within and above their natural thermal range. Pseudocrenilabrus multicolor collected in Lake Kayanja, Uganda, a population living near the upper thermal range of the species, were acclimated to 23, 26, 29 and 32°C for 3 days directly after capture, and RMR and Pcrit were then quantified. In a second group of P. multicolor from the same population, CTMax and the thermal onset of agitation were determined for fish acclimated to 26, 29 and 32°C for 7 days. Both RMR and Pcrit were significantly higher in fish acclimated to 32°C, indicating decreased tolerance to hypoxia and increased metabolic requirements at temperatures only slightly (∼1°C) above their natural thermal range. The CTMax increased with acclimation temperature, indicating some degree of thermal compensation induced by short-term exposure to higher temperatures. However, agitation temperature (likely to represent an avoidance response to increased temperature during CTMax trials) showed no increase with acclimation temperature. Overall, the results of this study demonstrate that P. multicolor is able to maintain its RMR and Pcrit across the range of temperatures characteristic of its natural habitat, but incurs a higher cost of resting metabolism and reduced hypoxia tolerance at temperatures slightly above its present range. PMID:27293734

Cold adapted features of Vibrio salmonicida catalase: characterisation and comparison to the mesophilic counterpart from Proteus mirabilis.

PubMed

Lorentzen, Marit Sjo; Moe, Elin; Jouve, Hélène Marie; Willassen, Nils Peder

2006-10-01

The gene encoding catalase from the psychrophilic marine bacterium Vibrio salmonicida LFI1238 was identified, cloned and expressed in the catalase-deficient Escherichia coli UM2. Recombinant catalase from V. salmonicida (VSC) was purified to apparent homogeneity as a tetramer with a molecular mass of 235 kDa. VSC contained 67% heme b and 25% protoporphyrin IX. VSC was able to bind NADPH, react with cyanide and form compounds I and II as other monofunctional small subunit heme catalases. Amino acid sequence alignment of VSC and catalase from the mesophilic Proteus mirabilis (PMC) revealed 71% identity. As for cold adapted enzymes in general, VSC possessed a lower temperature optimum and higher catalytic efficiency (k (cat)/K (m)) compared to PMC. VSC have higher affinity for hydrogen peroxide (apparent K (m)) at all temperatures. For VSC the turnover rate (k (cat)) is slightly lower while the catalytic efficiency is slightly higher compared to PMC over the temperature range measured, except at 4 degrees C. Moreover, the catalytic efficiency of VSC and PMC is almost temperature independent, except at 4 degrees C where PMC has a twofold lower efficiency compared to VSC. This may indicate that VSC has evolved to maintain a high efficiency at low temperatures.

An energy-balance model with multiply-periodic and quasi-chaotic free oscillations. [for climate forecasting

NASA Technical Reports Server (NTRS)

Bhattacharya, K.; Ghil, M.

1979-01-01

A slightly modified version of the one-dimensional time-dependent energy-balance climate model of Ghil and Bhattacharya (1978) is presented. The albedo-temperature parameterization has been reformulated and the smoothing of the temperature distribution in the tropics has been eliminated. The model albedo depends on time-lagged temperature in order to account for finite growth and decay time of continental ice sheets. Two distinct regimes of oscillatory behavior which depend on the value of the albedo-temperature time lag are considered.

Pluto's atmosphere - Models based on refraction, inversion, and vapor-pressure equilibrium

NASA Technical Reports Server (NTRS)

Eshleman, Von R.

1989-01-01

Viking spacecraft radio-occultation measurements indicate that, irrespective of substantial differences, the polar ice cap regions on Mars have inversions similar to those of Pluto, and may also share vapor pressure equilibrium characteristics at the surface. This temperature-inversion phenomenon occurs in a near-surface boundary layer; surface pressure-temperature may correspond to the vapor-pressure equilibrium with CH4 ice, or the temperature may be slightly higher to match the value derived from IRAS data.

100 s extraction of negative ion beams by using actively temperature-controlled plasma grid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kojima, A., E-mail: kojima.atsushi@jaea.go.jp; Hanada, M.; Yoshida, M.

2014-02-15

Long pulse beam extraction with a current density of 120 A/m{sup 2} for 100 s has been achieved with a newly developed plasma grid (PG) for the JT-60SA negative ion source which is designed to produce high power and long pulse beams with a negative ion current of 130 A/m{sup 2} (22 A) and a pulse length of 100 s. The PG temperature is regulated by fluorinated fluids in order to keep the high PG temperature for the cesium-seeded negative ion production. The time constant for temperature controllability of the PG was measured to be below 10 s, which wasmore » mainly determined by the heat transfer coefficient of the fluorinated fluid. The measured decay time of the negative ion current extracted from the actively temperature-controlled PG was 430 s which was sufficient for the JT-60SA requirement, and much longer than that by inertial-cooling PG of 60 s. Obtained results of the long pulse capability are utilized to design the full size PG for the JT-60SA negative ion source.« less

High temperature causes negative whole-plant carbon balance under mild drought.

PubMed

Zhao, Junbin; Hartmann, Henrik; Trumbore, Susan; Ziegler, Waldemar; Zhang, Yiping

2013-10-01

Theoretically, progressive drought can force trees into negative carbon (C) balance by reducing stomatal conductance to prevent water loss, which also decreases C assimilation. At higher temperatures, negative C balance should be initiated at higher soil moisture because of increased respiratory demand and earlier stomatal closure. Few data are available on how these theoretical relationships integrate over the whole plant. We exposed Thuja occidentalis to progressive drought under three temperature conditions (15, 25, and 35°C), and measured C and water fluxes using a whole-tree chamber design. High transpiration rates at higher temperatures led to a rapid decline in soil moisture. During the progressive drought, soil moisture-driven changes in photosynthesis had a greater impact on the whole-plant C balance than respiration. The soil moisture content at which whole-plant C balance became negative increased with temperature, mainly as a result of higher respiration rates and an earlier onset of stomatal closure under a warmer condition. Our results suggest that the effect of drought on whole-plant C balance is highly temperature-dependent. High temperature causes a negative C balance even under mild drought and may increase the risk of C starvation. © 2013 The Authors. New Phytologist © 2013 New Phytologist Trust.

An experimental study of the intersystem crossing and reactions of C2(X1Sigmag+) and C2(a3Pi(u)) with O2 and NO at very low temperature (24-300 K).

PubMed

Páramo, Alejandra; Canosa, André; Le Picard, Sébastien D; Sims, Ian R

2006-03-09

A low-temperature gas-phase kinetics study of the reactions and collisional relaxation processes involving C2(X1Sigma(g)+) and C2(a3Pi(u)) in collision with O2 and NO partners at temperatures from 300 to 24 K is reported. The experiments employed a CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme) apparatus to attain low temperatures. The C2 species were created using pulsed laser photolysis at 193 nm of mixtures containing C2Cl4 diluted in N2, Ar, or He carrier gas. C2(X1Sigma(g)+) molecules were detected via pulsed laser-induced fluorescence in the (D1Sigma(u)+ <-- X1Sigma(g)+) system, and C2(a3Pi(u)) molecules were detected via pulsed laser-induced fluorescence in the (d 3Pi(g) <-- a 3Pi(u)) system. Relaxation of 3C2 by intersystem crossing induced by oxygen was measured at temperatures below 200 K, and it was found that this process remains very efficient in the temperature range 50-200 K. Reactivity of C2(X1Sigma(g)+) with oxygen became very inefficient below room temperature. Using these two observations, it was found to be possible to obtain the C2(X1Sigma(g)+) state alone at low temperatures by addition of a suitable concentration of O2 and then study its reactivity with NO without any interference coming from the possible relaxation of C2(a3Pi(u)) to C2(X1Sigma(g)+) induced by this reagent. The rate coefficient for reaction of C2(X1Sigma(g)+) with NO was found to be essentially constant over the temperature range 36-300 K with an average value of (1.6 +/- 0.1) x 10(-10) cm3 molecule(-1) s(-1). Reactivity of C2(a3Pi(u)) with NO was found to possess a slight negative temperature dependence over the temperature range 50-300 K, which is in very good agreement with data obtained at higher temperatures.

Influence of Y doping concentration on the properties of nanostructured MxZn1-xO (M=Y) thin film deposited by nebulizer spray pyrolysis technique

NASA Astrophysics Data System (ADS)

Mariappan, R.; Ponnuswamy, V.; Chandra Bose, A.; Suresh, R.; Ragavendar, M.

2014-09-01

Yttrium doped Zinc Oxide (YxZn1-xO) thin films deposited at a substrate temperature 400 °C. The effect of substrate temperature on the structural, surface morphology, compositional, optical and electrical properties of YxZn1-xO thin films was studied. X-ray diffraction studies show that all films are polycrystalline in nature with hexagonal crystal structure having highly textured (002) plane parallel to the surface of the substrate. The structural parameters, such as lattice constants (a and c), crystallite size (D), dislocation density (δ), microstrain (σ) and texture coefficient were calculated for different yttrium doping concentrations (x). High resolution scanning electron microscopy measurements reveal that the surface morphology of the films change from platelet like grains to hexagonal structure with grain size increase due to the yttrium doping. Energy dispersive spectroscopy confirms the presence of Y, Zn and O elements in the films prepared. Optical studies showed that all samples have a strong optical transmittance higher than 70% in the visible range. A slight shift of the absorption edge towards the large wavelengths was observed as the Y doping concentration increased. This result shows that the band gap is slightly decreased from 3.10 to 2.05 eV with increase of the yttrium doping concentrations (up to 7.5%) and then slightly increased. Room temperature PL measurements were done and the band-to-band emission energies of films were determined and reported. The complex impedance of the 10%Y doped ZnO film shows two distinguished semicircles and the diameter of the arcs got decreased in diameter as the temperature increases from 70 to 175 °C.

Positron annihilation study of the high- Tc (Bi,Pb) 2Sr 2Ca 2Cu 3O x superconductor

NASA Astrophysics Data System (ADS)

Lim, H. J.; Byrne, J. G.

1997-03-01

Positron lifetime spectroscopy (PLS) and positron Doppler-broadening spectroscopy (PDBS) were applied to the high- Tc lead-doped Bi 2Sr 2Ca 2Cu 3O x (BPSCCO 2223) superconductor as a function of temperature. Neither positron lifetimes nor Doppler parameters ( S, W, and{S}/{W}) showed significant change through Tc. This may result from having the highest positron density in the open BiO 2 double layers and no significant positron density in the superconducting CuO 2 layers where positrons, if mainly present, are known to be sensitive to the transition in other high- Tc superconductors. Doppler parameters showed that the probability of positron annihilations with core electrons in the lattice slightly increased and that the probability of positron annihilations with conduction electrons slightly decreased as temperature decreased from ambient temperature to 20 K. The lifetime associated with positron annihilations in the perfect lattice of the sample ( τ1) was 209 ps and, due to the annihilations at internal surfaces or voids in the sample ( τ2) was about 540 ps, independent of temperature. Finally, the mean lifetime for BSCCO 2223 was about 307 ps.

Indoor air quality in an automotive assembly plant in Selangor, Malaysia.

PubMed

Edimansyah, B A; Rusli, B N; Naing, L; Azwan, B A; Aziah, B D

2009-01-01

The purpose of this study was to determine the indoor air quality (IAQ) status of an automotive assembly plant in Rawang, Selangor, Malaysia using selected IAQ parameters, such as carbon dioxide (CO2), carbon monoxide (CO), temperature, relative humidity (RH) and respirable particulate matter (PM10). A cross-sectional study was conducted in the paint shop and body shop sections of the plant in March 2005. The Q-TRAK Plus IAQ Monitor was used to record the patterns of CO, CO2, RH and temperature; whilst PM10 was measured using DUSTTRAK Aerosol Monitor over an 8-hour time weight average (8-TWA). It was found that the average temperatures, RH and PM10 in the paint shop section and body shop sections exceeded the Department of Safety and Health (DOSH) standards. The average concentrations of RH and CO were slightly higher in the body shop section than in the paint shop section, while the average concentrations of temperature and CO2 were slightly higher in the paint shop section than in the body shop section. There was no difference in the average concentrations of PM10 between the two sections.

High temperature alters the growth reaction of Pottia protonemata

NASA Astrophysics Data System (ADS)

Chaban, Ch. I.; Ripetskyj, R. T.; Kordyum, E. L.; Kit, N. A.

1999-01-01

Under gravistimulation, dark-grown protonemata of Pottia intermedia revealed negative gravitropism with a growth rate of approximately 28 μm.h-1 at room temperature (20 °C). In 7 days, the protonema formed a bundle of vertically oriented filaments. At an elevated temperature (30 °C), bundles of vertically growing filaments were also formed. However, both filament growth rate and amplitude of the gravicurvature were reduced. Red light (RL) irradiation induced a positive phototropism of most apical protonemal cells at 20 °C. In a following period of darkness, approximately two-thirds of such cells began to grow upward again, recovering their negative gravitropism. RL irradiation at the elevated temperature caused a partial increase in the number of protonemal cells with negative phototropism, but the protonemata did not exhibit negative gravitropism after transfer to darkness. The negative gravitropic reaction was renewed only when protonemata were placed at 20 °C. A dramatic decrease in starch amount in protonemal apical cells, which are sensitive to both gravity and light, occurred at the higher temperature. Such a decrease may be one of the reasons for the inhibition of the protonemal gravireaction at the higher temperature. The observation has a bearing on the starch-statolith theory.

Effect of Temperature on the Physico-Chemical Properties of a Room Temperature Ionic Liquid (1-Methyl-3-pentylimidazolium Hexafluorophosphate) with Polyethylene Glycol Oligomer

PubMed Central

Wu, Tzi-Yi; Chen, Bor-Kuan; Hao, Lin; Peng, Yu-Chun; Sun, I-Wen

2011-01-01

A systematic study of the effect of composition on the thermo-physical properties of the binary mixtures of 1-methyl-3-pentyl imidazolium hexafluorophosphate [MPI][PF6] with poly(ethylene glycol) (PEG) [Mw = 400] is presented. The excess molar volume, refractive index deviation, viscosity deviation, and surface tension deviation values were calculated from these experimental density, ρ, refractive index, n, viscosity, η, and surface tension, γ, over the whole concentration range, respectively. The excess molar volumes are negative and continue to become increasingly negative with increasing temperature; whereas the viscosity and surface tension deviation are negative and become less negative with increasing temperature. The surface thermodynamic functions, such as surface entropy, enthalpy, as well as standard molar entropy, Parachor, and molar enthalpy of vaporization for pure ionic liquid, have been derived from the temperature dependence of the surface tension values. PMID:21731460

Retrospective study of the prevalence of postanaesthetic hypothermia in dogs.

PubMed

Redondo, J I; Suesta, P; Serra, I; Soler, C; Soler, G; Gil, L; Gómez-Villamandos, R J

2012-10-13

The anaesthetic records of 1525 dogs were examined to determine the prevalence of postanaesthetic hypothermia, its clinical predictors and consequences. Temperature was recorded throughout the anaesthesia. At the end of the procedure, details coded in were: hyperthermia (>39.50°C), normothermia (38.50°C-39.50°C), slight (38.49°C-36.50°C), moderate (36.49°C-34.00°C) and severe hypothermia (<34.00°C). Statistical analysis consisted of multiple regression to identify the factors that are associated with the temperature at the end of the procedure. Before premedication, the temperature was 38.7 ± 0.6°C (mean ± sd). At 60, 120 and 180 minutes from induction, the temperature was 36.7 ± 1.3°C, 36.1 ± 1.4°C and 35.8 ± 1.5°C, respectively. The prevalence of hypothermia was: slight, 51.5 per cent (95 per cent CI 49.0 to 54.0 per cent); moderate, 29.3 per cent (27.1-31.7 per cent) and severe: 2.8% (2.0-3.7%). The variables that associated with a decrease in the temperature recorded at the end of the anaesthesia were: duration of the preanesthetic time, duration of the anaesthesia, physical condition (ASA III and ASA IV dogs showed lower temperatures than ASA I dogs), the reason for anaesthesia (anaesthesia for diagnostic procedures or thoracic surgery reduce the temperature when compared with minor procedures), and the recumbency during the procedure (sternal and dorsal recumbencies showed lower temperatures than lateral recumbency). The temperature before premedication and the body surface (BS) were associated with a higher temperature at the end of the anaesthesia, and would be considered as protective factors.

Static and dynamic protein impact on electronic properties of light-harvesting complex LH2.

PubMed

Zerlauskiene, O; Trinkunas, G; Gall, A; Robert, B; Urboniene, V; Valkunas, L

2008-12-11

A comparative analysis of the temperature dependence of the absorption spectra of the LH2 complexes from different species of photosynthetic bacteria, i.e., Rhodobacter sphaeroides, Rhodoblastus acidophilus, and Phaeospirillum molischianum, was performed in the temperature range from 4 to 300 K. Qualitatively, the temperature dependence is similar for all of the species studied. The spectral bandwidths of both B800 and B850 bands increases with temperature while the band positions shift in opposite directions: the B800 band shifts slightly to the red while the B850 band to the blue. These results were analyzed using the modified Redfield theory based on the exciton model. The main conclusion drawn from the analysis was that the spectral density function (SDF) is the main factor underlying the strength of the temperature dependence of the bandwidths for the B800 and B850 electronic transitions, while the bandwidths themselves are defined by the corresponding inhomogeneous distribution function (IDF). Slight variation of the slope of the temperature dependence of the bandwidths between species can be attributed to the changes of the values of the reorganization energies and characteristic frequencies determining the SDF. To explain the shift of the B850 band position with temperature, which is unusual for the conventional exciton model, a temperature dependence of the IDF must be postulated. This dependence can be achieved within the framework of the modified (dichotomous) exciton model. The slope of the temperature dependence of the B850 bandwidth is then defined by the value of the reorganization energy and by the difference between the transition energies of the dichotomous states of the pigment molecules. The equilibration factor between these dichotomous states mainly determines the temperature dependence of the peak shift.

Negative Temperature Dependence of Recrystallized Grain Size: Formulation and Experimental Confirmation on Copper

PubMed Central

Elmasry, Mohamed; Liu, Fan; Jiang, Yao; Mao, Ze Ning; Liu, Ying; Wang, Jing Tao

2017-01-01

The catalyzing effect on nucleation of recrystallization from existing grains resulting from previous lower temperature deformation is analyzed, analogous to the size effect of foreign nucleus in heterogeneous nucleation. Analytical formulation of the effective nucleation site for recrystallization leads to a negative temperature dependence of recrystallized grain size of metals. Non-isochronal annealing—where annealing time is set just enough for the completion of recrystallization at different temperatures—is conducted on pure copper after severe plastic deformation. More homogeneous and smaller grains are obtained at higher annealing temperature. The good fit between analytical and experimental results unveils the intrinsic feature of this negative temperature dependence of recrystallized grain size. PMID:28772676

Unipolar memristive Switching in Bulk Negative Temperature Coefficient Thermosensitive Ceramics

PubMed Central

Wu, Hongya; Cai, Kunpeng; Zhou, Ji; Li, Bo; Li, Longtu

2013-01-01

A memristive phenomenon was observed in macroscopic bulk negative temperature coefficient nickel monoxide (NiO) ceramic material. Current-voltage characteristics of memristors, pinched hysteretic loops were systematically observed in the Ag/NiO/Ag cell. A thermistor-based model for materials with negative temperature coefficient was proposed to explain the mechanism of the experimental phenomena. Most importantly, the results demonstrate the potential for a realization of memristive systems based on macroscopic bulk materials. PMID:24255717

Curie-Weiss behavior of Y1-xSrxMnO3 (x = 0 and 0.03)

NASA Astrophysics Data System (ADS)

Thakur, Rajesh K.; Thakur, Rasna; Gaur, N. K.; Bharathi, A.; Kaurav, N.; Okram, G. S.

2015-06-01

The effect of bivalent cation Sr-doping on magnetic properties in multiferroic YMnO3 manganites was systemically studied by DC magnetic measurements. Both of the reported samples were prepared by solid-state reaction method with composition Y1-xSrxMnO3 (x = 0.00 and 0.03). The X-ray diffraction (XRD) results show that the compounds are synthesized in hexagonal crystal structure with space group P63cm (JCPDS: 25-1079) and slight increase in the lattice parameter is observed with strontium doping. The magnetisation versus temperature curve shows no clear anomaly near the antiferromagnetic transition temperature (TN), however from the magnetic measurements at 1000Oe a slight increase in the magnetisation is clearly witnessed with increasing Stront ium content to the Y-site.

Presence and persistence of a highly ordered lipid phase state in the avian stratum corneum.

PubMed

Champagne, Alex M; Pigg, Victoria A; Allen, Heather C; Williams, Joseph B

2018-06-07

To survive high temperatures in a terrestrial environment, animals must effectively balance evaporative heat loss and water conservation. In passerine birds, cutaneous water loss (CWL) is the primary avenue of water loss at thermoneutral temperatures and increases slightly as ambient temperature increases, indicating a change in the permeability of the skin. In the stratum corneum (SC), the outermost layer of the skin, lipids arranged in layers called lamellae serve as the primary barrier to CWL in birds. The permeability of these lamellae depends in large part on the ability of lipid molecules to pack closely together in an ordered orthorhombic phase state. However, as temperature increases, lipids of the SC become more disordered, and may pack in more permeable hexagonal or liquid crystalline phase states. In this study, we used Fourier transform infrared spectroscopy to monitor the phase state of lipids in the SC of house sparrows ( Passer domesticus ) at skin temperatures ranging from 25 to 50°C. As temperature increased, lipids became slightly more disordered, but remained predominantly in the orthorhombic phase, consistent with the small increase in CWL observed in house sparrows as ambient temperature increases. These results differ considerably from studies on mammalian SC, which find a predominantly hexagonal arrangement of lipids at temperatures above 37°C, and the increased order in avian SC may be explained by longer lipid chain length, scarcity of cholesterol and the presence of cerebrosides. Our results lend further insight into the arrangement and packing of individual lipid molecules in avian SC. © 2018. Published by The Company of Biologists Ltd.

Effects of Intergenerational Interaction on Aging

ERIC Educational Resources Information Center

Hernandez, Carmen Requena; Gonzalez, Marta Zubiaur

2008-01-01

The world population pyramid has changed shape. However, this does not mean that societies have changed their negative concept of old age. Our study proposes an intergenerational service-learning program with 179 university students and 101 slightly depressed elderly people. The results show that the elderly people who interacted improved in…

Enhanced production of a single domain antibody with an engineered stabilizing extra disulfide bond.

PubMed

Liu, Jinny L; Goldman, Ellen R; Zabetakis, Dan; Walper, Scott A; Turner, Kendrick B; Shriver-Lake, Lisa C; Anderson, George P

2015-10-09

Single domain antibodies derived from the variable region of the unique heavy chain antibodies found in camelids yield high affinity and regenerable recognition elements. Adding an additional disulfide bond that bridges framework regions is a proven method to increase their melting temperature, however often at the expense of protein production. To fulfill their full potential it is essential to achieve robust protein production of these stable binding elements. In this work, we tested the hypothesis that decreasing the isoelectric point of single domain antibody extra disulfide bond mutants whose production fell due to the incorporation of the extra disulfide bond would lead to recovery of the protein yield, while maintaining the favorable melting temperature and affinity. Introduction of negative charges into a disulfide bond mutant of a single domain antibody specific for the L1 antigen of the vaccinia virus led to approximately 3.5-fold increase of protein production to 14 mg/L, while affinity and melting temperature was maintained. In addition, refolding following heat denaturation improved from 15 to 70 %. It also maintained nearly 100 % of its binding function after heating to 85 °C for an hour at 1 mg/mL. Disappointingly, the replacement of neutral or positively charged amino acids with negatively charged ones to lower the isoelectric point of two anti-toxin single domain antibodies stabilized with a second disulfide bond yielded only slight increases in protein production. Nonetheless, for one of these binders the charge change itself stabilized the structure equivalent to disulfide bond addition, thus providing an alternative route to stabilization which is not accompanied by loss in production. The ability to produce high affinity, stable single domain antibodies is critical for their utility. While the addition of a second disulfide bond is a proven method for enhancing stability of single domain antibodies, it frequently comes at the cost of reduced yields. While decreasing the isoelectric point of double disulfide mutants of single domain antibodies may improve protein production, charge addition appears to consistently improve refolding and some charge changes can also improve thermal stability, thus providing a number of benefits making the examination of such mutations worth consideration.

POMC neurons in heat: A link between warm temperatures and appetite suppression.

PubMed

Vicent, Maria A; Mook, Conor L; Carter, Matthew E

2018-05-01

When core body temperature increases, appetite and food consumption decline. A higher core body temperature can occur during exercise, during exposure to warm environmental temperatures, or during a fever, yet the mechanisms that link relatively warm temperatures to appetite suppression are unknown. A recent study in PLOS Biology demonstrates that neurons in the mouse hypothalamus that express pro-opiomelanocortin (POMC), a neural population well known to suppress food intake, also express a temperature-sensitive ion channel, transient receptor potential vanilloid 1 (TRPV1). Slight increases in body temperature cause a TRPV1-dependent increase in activity in POMC neurons, which suppresses feeding in mice. Taken together, this study suggests a novel mechanism linking body temperature and food-seeking behavior.

Plant molecular responses to the elevated ambient temperatures expected under global climate change.

PubMed

Fei, Qionghui; Li, Jingjing; Luo, Yunhe; Ma, Kun; Niu, Bingtao; Mu, Changjun; Gao, Huanhuan; Li, Xiaofeng

2018-01-02

Environmental temperatures affect plant distribution, growth, and development. The Intergovernmental Panel on Climate Change (IPCC) predicts that global temperatures will rise by at least 1.5°C by the end of this century. Global temperature changes have already had a discernable impact on agriculture, phenology, and ecosystems. At the molecular level, extensive literature exists on the mechanism controlling plant responses to high temperature stress. However, few studies have focused on the molecular mechanisms behind plant responses to mild increases in ambient temperature. Previous research has found that moderately higher ambient temperatures can induce hypocotyl elongation and early flowering. Recent evidence demonstrates roles for the phytohormones auxin and ethylene in adaptive growth of plant roots to slightly higher ambient temperatures.

Climate Change in the Western United States: Projections and Observations (Invited)

NASA Astrophysics Data System (ADS)

Redmond, K. T.

2009-12-01

The interplay between projections and observations of climate, and the role of observations as they unfold, form the primary emphasis for this talk. The consensus among climate projections is that the Western United States will warm, and that annual precipitation will increase near the Canada/US border and decrease near the Mexico/US border. Inter-model agreement is greater for temperature than precipitation, though precipitation projections show some tendency toward slow convergence. Seasonal temperature changes are expected to be similar from month to month, slightly greater in summer and slightly smaller in winter. Coastal temperature increases are expected to be smaller than inland. High elevation increases may be slightly greater than those at low elevation. The precipitation season is in general expected to be more concentrated in winter, with less (or less increase, depending on latitude) precipitation in spring, summer, and autumn than without climate change. Climate should have started to depart from the baseline (no-change) case about 30-35 years ago. Observations show that temperatures West-wide did begin to rise during the 1970s. Precipitation changes have been more ambiguous. Annual temperature increases in the U.S. have been much more prominent in the West (and to some extent the north) than in the East, especially during the last decade. Summer in particular has shown a marked temperature increase since around 2000. Minimum temperatures have shown more increase (in many cases considerably more) than maximum temperatures. Annual freezing levels, from essentially independent data sets, have risen during this time. Acceptance of climate change in the public mind is increased when evidence visibly aligns with projections. This appears to have been particularly important in the western states. However, other sources of climate variability, of human or natural origin, on seasonal to decadal scales, can obscure or partially and temporarily mask expected effects of greenhouse gas forcing. Observational factors can likewise affect the reported climate history. Changes in climate elements have been detected, but parallel efforts at attribution are necessary to properly interpret the measurements, and provide the consistency desired by scientists and the remainder of the public. All of the above factors converge in the region's most prominent climate narrative, the ongoing Colorado River drought and its uncertain outcome.

Large Decadal Decline of the Arctic Multiyear Ice Cover

NASA Technical Reports Server (NTRS)

Comiso, Josefino C.

2012-01-01

The perennial ice area was drastically reduced to 38% of its climatological average in 2007 but recovered slightly in 2008, 2009, and 2010 with the areas being 10%, 24%, and 11% higher than in 2007, respectively. However, trends in extent and area remained strongly negative at -12.2% and -13.5% decade (sup -1), respectively. The thick component of the perennial ice, called multiyear ice, as detected by satellite data during the winters of 1979-2011 was studied, and results reveal that the multiyear ice extent and area are declining at an even more rapid rate of -15.1% and -17.2% decade(sup -1), respectively, with a record low value in 2008 followed by higher values in 2009, 2010, and 2011. Such a high rate in the decline of the thick component of the Arctic ice cover means a reduction in the average ice thickness and an even more vulnerable perennial ice cover. The decline of the multiyear ice area from 2007 to 2008 was not as strong as that of the perennial ice area from 2006 to 2007, suggesting a strong role of second-year ice melt in the latter. The sea ice cover is shown to be strongly correlated with surface temperature, which is increasing at about 3 times the global average in the Arctic but appears weakly correlated with the Arctic Oscillation (AO), which controls the atmospheric circulation in the region. An 8-9-yr cycle is apparent in the multiyear ice record, which could explain, in part, the slight recovery in the last 3 yr.

Pt(110)(1×1) surfaces prepared by low temperature platinum deposition: surface characterization and stability

NASA Astrophysics Data System (ADS)

Alnot, M.; Ehrhardt, J. J.

1993-05-01

Adsorption of platinum atoms on Pt(110)(1×2) at low temperature has been studied by LEED, photoemission of adsorbed xenon (PAX) and Δφ measurements. Deposition of half a monolayer of platinum at 150 K produces a sharp (1×1) LEED pattern. A possible structural disorder of the as-grown surface is discussed. The (1×1) → (1×2) reconstruction is observed after annealing at a temperature slightly higher than 300 K.

Influence of deformation behavior, oxydation, and temperature on the long time cyclic stress behavior of high temperature steels

NASA Technical Reports Server (NTRS)

Maile, K.

1982-01-01

The influence of different parameters on the creep-fatigue behavior of several steel alloys was investigated. The higher the temperature the lower the crack initiation value. Pauses during the cycle reduce the damage. Oxidation reduces and protective gas increases the lifetime. Prior loading and prior deformation reduce the lifetime. Short annealing slightly affects the cycle stress behavior. The test results do not satisfactorily agree with methods of extrapolation and damage accumulation.

The contrasting effects of short-term climate change on the early recruitment of tree species.

PubMed

Ibáñez, Inés; Katz, Daniel S W; Lee, Benjamin R

2017-07-01

Predictions of plant responses to climate change are frequently based on organisms' presence in warmer locations, which are then assumed to reflect future performance in cooler areas. However, as plant life stages may be affected differently by environmental changes, there is little empirical evidence that this approach provides reliable estimates of short-term responses to global warming. Under this premise, we analyzed 8 years of early recruitment data, seed production and seedling establishment and survival, collected for two tree species at two latitudes. We quantified recruitment to a wide range of environmental conditions, temperature, soil moisture and light, and simulated recruitment under two forecasted climatic scenarios. Annual demographic transitions were affected by the particular conditions taking place during their onset, but the effects of similar environmental shifts differed among the recruitment stages; seed production was higher in warmer years, while seedling establishment and survival peaked during cold years. Within a species, these effects also varied between latitudes; increasing temperatures at the southern location will have stronger detrimental effects on recruitment than similar changes at the northern locations. Our simulations illustrate that warmer temperatures may increase seed production, but they will have a negative effect on establishment and survival. When the three early recruitment processes were simultaneously considered, simulations showed little change in recruitment dynamics at the northern site and a slight decrease at the southern site. It is only when we considered these three stages that we were able to assess likely changes in early recruitment under the predicted conditions.

The Role of the Snow Covers in the Permafrost Temperature Dynamics at the Northern Yakutia over the last 30 Years

NASA Astrophysics Data System (ADS)

Kholodov, A. L.

2011-12-01

This report concerns the changes of the dynamics of snow warming influence on the permafrost temperature at the northern Yakutia. Snow is a key factor determines the thermal state of permafrost here. Despite of the absence of air temperature latitudinal zonality mean annual ground temperature decreases northward approximately 1 centigrade per latitude degree due to changes of the snow warming impact. At the north-western part with a relatively maritime climate warming influence of the snow is 0.5 to 1.5°C, while in the southern and eastern part with more continental climate it is 3.5 to 4.5°C. Snow redistribution within the some types of landscape at the beginning of the winter season can lead to the extremely fast freezing of the active layer and cooling of the permafrost within such types of landscapes. The main goal of the current research was to estimate snow warming impact dynamics over the last 30 years in the northern Yakutia. We took in consideration changes of the three main parameters, are determining snow cover thermal state: - snow thickness; - amplitude of air temperature seasonal oscillation; - temperature during the winter period during. Following conclusion can be done based on the data analysis: Interannual changes of snow warming influence are tenth to first centigrades, what is comparable with air temperature fluctuations. During the 1980-90s snow impact on the permafrost stood stable in the south-eastern part of the region or had a slightly negative trend in the western part. It could be explained by the changes of snow thickness, reduced thermal resistivity of snow due to winter warming and decreasing of the amplitude of seasonal temperature oscillation in the western part of the region. Since the end of 90s general increasing of the snow cover warming influence was noticed for the entire investigated territory. These results correspond with data of modern permafrost temperature observations have been done in the region during the last decades. Most of monitoring sites did not show sustainable changes of the permafrost temperature until the end of 90s years of the XX century, but recent measurements record increasing of the mean annual ground temperature at the most of monitoring sites in the region.

Pressure-dependence of the phase transitions and thermal expansion in zirconium and hafnium pyrovanadate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gallington, Leighanne C.; Hester, Brett R.; Kaplan, Benjamin S.

Low or negative thermal expansion (NTE) has been previously observed in members of the ZrP{sub 2}O{sub 7} family at temperatures higher than their order-disorder phase transitions. The thermoelastic properties and phase behavior of the low temperature superstructure and high temperature negative thermal expansion phases of ZrV{sub 2}O{sub 7} and HfV{sub 2}O{sub 7} were explored via in situ variable temperature/pressure powder x-ray diffraction measurements. The phase transition temperatures of ZrV{sub 2}O{sub 7} and HfV{sub 2}O{sub 7} exhibited a very strong dependence on pressure (∼700 K GPa), with moderate compression suppressing the formation of their NTE phases below 513 K. Compression alsomore » reduced the magnitude of the coefficients of thermal expansion in both the positive and negative thermal expansion phases. Additionally, the high temperature NTE phase of ZrV{sub 2}O{sub 7} was found to be twice as stiff as the low temperature positive thermal expansion superstructure (24 and 12 GPa respectively). - Graphical abstract: The temperature at which ZrV{sub 2}O{sub 7} transforms to a phase displaying negative thermal expansion is strongly pressure dependent. The high temperature form of ZrV{sub 2}O{sub 7} is elastically stiffer than the low temperature form. - Highlights: • The order-disorder phase transition temperatures in ZrV{sub 2}O{sub 7} and HfV{sub 2}O{sub 7} are strongly pressure dependent (∼700 K.GPa). • The high temperature (disordered) phase of ZrV{sub 2}O{sub 7} is much stiffer than the ambient temperature (ordered) phase. • Compression reduces the magnitude of the negative thermal expansion in the high temperature phase of ZrV{sub 2}O{sub 7}.« less

Improving Durability of Turbine Components Through Trenched Film Cooling and Contoured Endwalls

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bogard, David G.; Thole, Karen A.

2014-09-30

The experimental and computational studies of the turbine endwall and vane models completed in this research program have provided a comprehensive understanding of turbine cooling with combined film cooling and TBC. To correctly simulate the cooling effects of TBC requires the use of matched Biot number models, a technique developed in our laboratories. This technique allows for the measurement of the overall cooling effectiveness which is a measure of the combined internal and external cooling for a turbine component. The overall cooling effectiveness provides an indication of the actual metal temperature that would occur at engine conditions, and is hencemore » a more powerful performance indicator than the film effectiveness parameter that is commonly used for film cooling studies. Furthermore these studies include the effects of contaminant depositions which are expected to occur when gas turbines are operated with syngas fuels. Results from the endwall studies performed at Penn State University and the vane model studies performed at the University of Texas are the first direct measurements of the combined effects of film cooling and TBC. These results show that TBC has a dominating effect on the overall cooling effectiveness, which enhances the importance of the internal cooling mechanisms, and downplays the importance of the film cooling of the external surface. The TBC was found to increase overall cooling effectiveness by a factor of two to four. When combined with TBC, the primary cooling from film cooling holes was found to be due to the convective cooling within the holes, not from the film effectiveness on the surface of the TBC. Simulations of the deposition of contaminants on the endwall and vane surfaces showed that these depositions caused a large increase in surface roughness and significant degradation of film effectiveness. However, despite these negative factors, the depositions caused only a slight decrease in the overall cooling effectiveness on the endwall, and in some cases a slight increase in overall cooling effectiveness on the vane model. This was attributed to the insulating effects of the depositions which compensated for the negative factors.« less

The presence and prognostic significance of human papillomavirus in squamous cell carcinoma of the larynx.

PubMed

Erkul, Evren; Yilmaz, Ismail; Narli, Gizem; Babayigit, Mustafa Alparslan; Gungor, Atila; Demirel, Dilaver

2017-07-01

The aim of the present study was to evaluate the role of HPV in laryngeal squamous cell carcinoma and correlate it with patients' clinicopathological data. In total, 78 laryngeal squamous cell carcinoma patients enrolled in this study. The presence of genotype-specific HPV DNA was evaluated using Genotyping Assay in formalin-fixed paraffin-embedded tissue which was diagnosed between 2005 and 2015. All samples were also evaluated for p16 immunohistochemical staining. HPV DNA and p16 status were assessed in terms of location, smoking, alcohol consumption, lymph node status, tumor stage, overall survival, disease-free survival, perineural invasion, and vascular invasion retrospectively. Five test samples were excluded from the study due to inadequate deoxyribonucleic acid purity. HPV DNA was detected in 19 of 73 (26.02%) in patients with laryngeal squamous cell carcinoma. Human papilloma virus genotyping revealed double human papilloma virus in one case (types 16 and 59) and HPV 16 in the remaining cases. Although HPV-positive cases showed slightly better 3 years survival than HPV-negative ones, this finding was not statistically significant (overall survival p = 0.417, HPV positive: 92.3%, HPV negative: 81.4%, and disease-free survival p = 0.526, HPV positive: 93.8%, HPV negative: 80.9%). The presence of HPV DNA was not significantly associated with any clinicopathological features (p > 0.05). Among 73 patients, only 4 had an immunohistochemical staining of p16 and these patients were also HPV DNA 16 positive. Although our study results revealed a slightly better survival in patients with HPV DNA positivity for HPV 16 compared to the negative ones, the difference was not statistically significant. However, an increasing rate in especially high-risk-type HPV-16 prevalence in laryngeal squamous cell carcinoma by RT-PCR method was observed compared to our previous study. Although the presence of HPV in laryngeal SCCs seems to be associated with slightly better prognosis, additional studies may be needed, since our results were not statistically significant. We believed that HPV is not an adequate biomarker for diagnostic and prognostic purposes in laryngeal squamous cell carcinoma.

Solution structure and stability of the DNA undecamer duplexes containing oxanine mismatch

PubMed Central

Pack, Seung Pil; Morimoto, Hirohisa; Makino, Keisuke; Tajima, Kunihiko; Kanaori, Kenji

2012-01-01

Solution structures of DNA duplexes containing oxanine (Oxa, O) opposite a cytosine (O:C duplex) and opposite a thymine (O:T duplex) have been solved by the combined use of 1H NMR and restrained molecular dynamics calculation. One mismatch pair was introduced into the center of the 11-mer duplex of [d(GTGACO6CACTG)/d(CAGTGX17GTCAC), X = C or T]. 1H NMR chemical shifts and nuclear Overhauser enhancement (NOE) intensities indicate that both the duplexes adopt an overall right-handed B-type conformation. Exchangeable resonances of C17 4-amino proton of the O:C duplex and of T17 imino proton of O:T duplex showed unusual chemical shifts, and disappeared with temperature increasing up to 30°C, although the melting temperatures were >50°C. The O:C mismatch takes a wobble geometry with positive shear parameter where the Oxa ring shifted toward the major groove and the paired C17 toward the minor groove, while, in the O:T mismatch pair with the negative shear, the Oxa ring slightly shifted toward the minor groove and the paired T17 toward the major groove. The Oxa mismatch pairs can be wobbled largely because of no hydrogen bond to the O1 position of the Oxa base, and may occupy positions in the strands that optimize the stacking with adjacent bases. PMID:22039100

Fascinating functional properties of Mn:Gd2O3 nanocrystalline phosphor

NASA Astrophysics Data System (ADS)

Heiba, Zein K.; Imam, N. G.; Bakr Mohamed, Mohamed

2015-10-01

In the present work we through the light on some of the fascinating structural, magnetic and optical properties of Mn:Gd2O3 nanophosphor. Manganese substituted nanocrystalline Mn:Gd2O3 was prepared via a sol gel procedure. The prepared samples were characterized applying X-ray diffraction (XRD), infrared spectroscopy (IR), squid magnometer and photoluminance (PL). XRD and IR analysis revealed a single phase solid solution up to x = 0.2. The cation distribution of Mn and Gd between the crystallographically non-equivalent sites 8b and 24d of the space group Ia 3 bar is found to be preferentially for all samples. The lattice parameter decreases with composition x, accompanied with systematic variation in the r.m.s. microstrain < εL2 > 1 / 2 . The magnetic measurement showed negative values for curie paramagnetic temperatures, θ, which indicates an antiferromagnetic interaction between the magnetic ions in Mn:Gd2O3. PL spectra showed a series of emission lines in the room temperature fluorescence measurements under UV excitation (220 nm). The observed emission lines are stokes-shifted and the non-linearity optical phenomenon is confirmed. Further, the emission lines are slightly shifted with Mn concentration (x). The blue emission around (390-402) nm was appeared due to Mn doping. Because of its fascinating properties, Mn:Gd2O3 is recommended for fuel cells, photocatalytic, and biomedical applications.

Cool-flame Extinction During N-Alkane Droplet Combustion in Microgravity

NASA Technical Reports Server (NTRS)

Nayagam, Vedha; Dietrich, Daniel L.; Hicks, Michael C.; Williams, Forman A.

2014-01-01

Recent droplet combustion experiments onboard the International Space Station (ISS) have revealed that large n-alkane droplets can continue to burn quasi-steadily following radiative extinction in a low-temperature regime, characterized by negative-temperaturecoefficient (NTC) chemistry. In this study we report experimental observations of n-heptane, n-octane, and n-decane droplets of varying initial sizes burning in oxygen/nitrogen/carbon dioxide and oxygen/helium/nitrogen environments at 1.0, 0.7, and 0.5 atmospheric pressures. The oxygen concentration in these tests varied in the range of 14% to 25% by volume. Large n-alkane droplets exhibited quasi-steady low-temperature burning and extinction following radiative extinction of the visible flame while smaller droplets burned to completion or disruptively extinguished. A vapor-cloud formed in most cases slightly prior to or following the "cool flame" extinction. Results for droplet burning rates in both the hot-flame and cool-flame regimes as well as droplet extinction diameters at the end of each stage are presented. Time histories of radiant emission from the droplet captured using broadband radiometers are also presented. Remarkably the "cool flame" extinction diameters for all the three n-alkanes follow a trend reminiscent of the ignition delay times observed in previous studies. The similarities and differences among the n-alkanes during "cool flame" combustion are discussed using simplified theoretical models of the phenomenon

Cold/menthol TRPM8 receptors initiate the cold-shock response and protect germ cells from cold-shock–induced oxidation

PubMed Central

Borowiec, Anne-Sophie; Sion, Benoit; Chalmel, Frédéric; D. Rolland, Antoine; Lemonnier, Loïc; De Clerck, Tatiana; Bokhobza, Alexandre; Derouiche, Sandra; Dewailly, Etienne; Slomianny, Christian; Mauduit, Claire; Benahmed, Mohamed; Roudbaraki, Morad; Jégou, Bernard; Prevarskaya, Natalia; Bidaux, Gabriel

2016-01-01

Testes of most male mammals present the particularity of being externalized from the body and are consequently slightly cooler than core body temperature (4–8°C below). Although, hypothermia of the testis is known to increase germ cells apoptosis, little is known about the underlying molecular mechanisms, including cold sensors, transduction pathways, and apoptosis triggers. In this study, using a functional knockout mouse model of the cold and menthol receptors, dubbed transient receptor potential melastatine 8 (TRPM8) channels, we found that TRPM8 initiated the cold-shock response by differentially modulating cold- and heat-shock proteins. Besides, apoptosis of germ cells increased in proportion to the cooling level in control mice but was independent of temperature in knockout mice. We also observed that the rate of germ cell death correlated positively with the reactive oxygen species level and negatively with the expression of the detoxifying enzymes. This result suggests that the TRPM8 sensor is a key determinant of germ cell fate under hypothermic stimulation.—Borowiec, A.-S., Sion, B., Chalmel, F., Rolland, A. D., Lemonnier, L., De Clerck, T., Bokhobza, A., Derouiche, S., Dewailly, E., Slomianny, C., Mauduit, C., Benahmed, M., Roudbaraki, M., Jégou, B., Prevarskaya, N., Bidaux, G. Cold/menthol TRPM8 receptors initiate the cold-shock response and protect germ cells from cold-shock–induced oxidation. PMID:27317670

Temperature measurements in an ytterbium fiber amplifier up to the mode instability threshold

NASA Astrophysics Data System (ADS)

Beier, F.; Heinzig, M.; Sattler, Bettina; Walbaum, Till; Haarlammert, N.; Schreiber, T.; Eberhardt, R.; Tünnermann, A.

2016-03-01

We report on the measurement of the longitudinal temperature distribution in a fiber amplifier fiber during high power operation. The measurement signal of an optical frequency domain reflectometer is coupled to an ytterbium doped amplifier fiber via a wavelength division multiplexer. The longitudinal temperature distribution was examined for different pump powers with a sub mm resolution. The results show even small temperature variations induced by slight changes of the environmental conditions along the fiber. The mode instability threshold of the fiber under investigation was determined to be 480W and temperatures could be measured overall the measured output power values.

Relations of spanking and other parenting characteristics to self-esteem and perceived fairness of parental discipline.

PubMed

Larzelere, R E; Klein, M; Schumm, W R; Alibrando, S A

1989-06-01

Punishment has long been a controversial topic in psychology, perhaps partly because its effects are different under different circumstances. This study used retrospective reports from college students to examine the effects of spanking, a common aversive punishment, on self-esteem and perceived fairness of parental discipline, while taking the effects of other parental characteristics into account. No parental characteristic interacted with the slightly negative effect of spanking on self-esteem and fairness. However, controlling for positive communication or for a parent-oriented motivation for spanking eliminated the negative effects of spanking, suggesting that the negative effects reflected use of spanking as a replacement for positive communication with the child.

Effects of discharge chamber length on the negative ion generation in volume-produced negative hydrogen ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chung, Kyoung-Jae; Jung, Bong-Ki; An, YoungHwa

2014-02-15

In a volume-produced negative hydrogen ion source, control of electron temperature is essential due to its close correlation with the generation of highly vibrationally excited hydrogen molecules in the heating region as well as the generation of negative hydrogen ions by dissociative attachment in the extraction region. In this study, geometric effects of the cylindrical discharge chamber on negative ion generation via electron temperature changes are investigated in two discharge chambers with different lengths of 7.5 cm and 11 cm. Measurements with a radio-frequency-compensated Langmuir probe show that the electron temperature in the heating region is significantly increased by reducingmore » the length of the discharge chamber due to the reduced effective plasma size. A particle balance model which is modified to consider the effects of discharge chamber configuration on the plasma parameters explains the variation of the electron temperature with the chamber geometry and gas pressure quite well. Accordingly, H{sup −} ion density measurement with laser photo-detachment in the short chamber shows a few times increase compared to the longer one at the same heating power depending on gas pressure. However, the increase drops significantly as operating gas pressure decreases, indicating increased electron temperatures in the extraction region degrade dissociative attachment significantly especially in the low pressure regime. It is concluded that the increase of electron temperature by adjusting the discharge chamber geometry is efficient to increase H{sup −} ion production as long as low electron temperatures are maintained in the extraction region in volume-produced negative hydrogen ion sources.« less

Effects of Stoichiometry on Transformation Temperatures and Actuator-Type Performance of NiTiPd and NiTiPdX High-Temperature Shape Memory Alloys

NASA Technical Reports Server (NTRS)

Bigelow, Glen S.; Gaydosh, Darrell; Garg, Anita; Padula, Santo A., II; Noebe, Ronald D.

2007-01-01

High-temperature shape memory NiTiPd and NiTiPdX (X=Au, Pt, Hf) alloys were produced with titanium equivalent (Ti+Hf) compositions of 50.5, 50.0, 49.5, and 49.0 at.%. Thermo-mechanical testing in compression was used to evaluate the transformation temperatures, transformation strain, work output, and permanent deformation behavior of each alloy to study the effects of quaternary alloying and stoichiometry on high-temperature shape memory alloy behavior. Microstructural evaluation showed the presence of second phases for all alloy compositions. No load transformation temperatures in the stoichiometric alloys were relatively unchanged by Au and Pt substitutions, while the substitution of Hf for Ti causes a drop in transformation temperatures. The NiTiPd, NiTiPdAu and NiTiPdHf alloys exhibited transformation temperatures that were highest in the Ti-rich compositions, slightly lower at stoichiometry, and significantly reduced when the Ti equivalent composition was less than 50 at.%. For the NiTiPdPt alloy, transformation temperatures were highest for the Ti-rich compositions, lowest at stoichiometry, and slightly higher in the Ni-rich composition. When thermally cycled under constant stresses of up to 300 MPa, all of the alloys had transformation strains, and therefore work outputs, which increased with increasing stress. In each series of alloys, the transformation strain and thus work output was highest for stoichiometric or Ti-rich compositions while permanent strain associated with the constant-load thermal cycling was lowest for alloys with Ni-equivalent-rich compositions. Based on these results, basic rules for optimizing the composition of NiTiPd alloys for actuator performance will be discussed.

Lunar Surface Charging during Solar Energetic Particle Events

NASA Astrophysics Data System (ADS)

Halekas, Jasper S.; Delory, G. T.; Mewaldt, R. A.; Lin, R. P.; Fillingim, M. O.; Brain, D. A.; Lee, C. O.; Stubbs, T. J.; Farrell, W. M.; Hudson, M. K.

2006-09-01

The surface of the Moon, not protected by any substantial atmosphere, is directly exposed to the impact of both solar UV and solar wind plasma and energetic particles. This creates a complex lunar electrostatic environment, with the surface typically charging slightly positive in sunlight, and negative in shadow. Observations from the Apollo era and theoretical considerations strongly suggest that surface charging leads to dust electrification and transport, posing a potentially significant hazard for exploration. The most significant charging effects should occur when the Moon is exposed to high-temperature plasmas like those encountered in the terrestrial plasmasheet or in solar storms. We now present evidence for kilovolt-scale negative charging of the shadowed lunar surface during solar energetic particle (SEP) events, utilizing data from the Lunar Prospector Electron Reflectometer (LP ER). We find that SEP events are associated with the most extreme lunar surface charging observed during the LP mission - rivaled only by previously reported charging during traversals of the terrestrial plasmasheet. The largest charging event observed by LP is a 4 kV negative surface potential (as compared to typical values of V) during a SEP event in May 1998. We characterize lunar surface charging during several SEP events, and compare to energetic particle measurements from ACE, Wind, and SOHO in order to determine the relationship between SEP events and extreme lunar surface charging. Space weather events are already considered by NASA to be a significant hazard to lunar exploration, due to high-energy ionizing radiation. Our observations demonstrate that plasma interactions with the lunar surface during SEP events, causing extreme surface charging and potentially significant dust electrification and transport, represent an additional hazard associated with space weather.

Kinetic bottlenecks to chemical exchange rates for deep-sea animals - Part 1: Oxygen

NASA Astrophysics Data System (ADS)

Hofmann, A. F.; Peltzer, E. T.; Brewer, P. G.

2012-10-01

Ocean warming will reduce dissolved oxygen concentrations which can pose challenges to marine life. Oxygen limits are traditionally reported simply as a static concentration thresholds with no temperature, pressure or flow rate dependency. Here we treat the oceanic oxygen supply potential for heterotrophic consumption as a dynamic molecular exchange problem analogous to familiar gas exchange processes at the sea surface. A combination of the purely physico-chemical oceanic properties temperature, hydrostatic pressure, and oxygen concentration defines the ability of the ocean to supply oxygen to any given animal. This general oceanic oxygen supply potential is modulated by animal specific properties such as the diffusive boundary layer thickness to define and limit maximal oxygen supply rates. Here we combine all these properties into formal, mechanistic equations defining novel oceanic properties that subsume various relevant classical oceanographic parameters to better visualize, map, comprehend, and predict the impact of ocean deoxygenation on aerobic life. By explicitly including temperature and hydrostatic pressure into our quantities, various ocean regions ranging from the cold deep-sea to warm, coastal seas can be compared. We define purely physico-chemical quantities to describe the oceanic oxygen supply potential, but also quantities that contain organism-specific properties which in a most generalized way describe general concepts and dependencies. We apply these novel quantities to example oceanic profiles around the world and find that temperature and pressure dependencies of diffusion and partial pressure create zones of greatest physical constriction on oxygen supply typically at around 1000 m depth, which coincides with oxygen concentration minimum zones. In these zones, which comprise the bulk of the world ocean, ocean warming and deoxygenation have a clear negative effect for aerobic life. In some shallow and warm waters the enhanced diffusion and higher partial pressure due to higher temperatures might slightly overcompensate for oxygen concentration decreases due to decreases in solubility.

Reflectance Spectra of Titan Tholins at Cryogenic Temperatures and Implications for Compositional Interpretation of Red Objects in the Outer Solar System

NASA Technical Reports Server (NTRS)

Roush, T. L.; Dalton, J. B.

2002-01-01

We report the visual and near-infrared (0.4-2.5 micron) laboratory bi-directional reflectance of Titan tholin at cryogenic temperatures (approx. 100-300 K). When compared with room temperature measurements, the visual and near-infrared color of Titan tholin becomes slightly redder by approx. 5% at low temperatures in the 0.4-1.3 micron region. We estimate the influence of these colr changes on the interpretation of the Centaur Pholus and find that the modest color changes will not significantly alter existing interpretations.

Elastic Modulus Measurement of ORNL ATF FeCrAl Alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, Zachary T.; Terrani, Kurt A.; Yamamoto, Yukinori

2015-10-01

Elastic modulus and Poisson’s ratio for a number of wrought FeCrAl alloys, intended for accident tolerant fuel cladding application, are determined via resonant ultrasonic spectroscopy. The results are reported as a function of temperature from room temperature to 850°C. The wrought alloys were in the fully annealed and unirradiated state. The elastic modulus for the wrought FeCrAl alloys is at least twice that of Zr-based alloys over the temperature range of this study. The Poisson’s ratio of the alloys was 0.28 on average and increased very slightly with increasing temperature.

Temperature-dependent surface density of alkylthiol monolayers on gold nanocrystals

NASA Astrophysics Data System (ADS)

Liu, Xuepeng; Lu, Pin; Zhai, Hua; Wu, Yucheng

2018-03-01

Atomistic molecular dynamics (MD) simulations are performed to study the surface density of passivating monolayers of alkylthiol chains on gold nanocrystals at temperatures ranging from 1 to 800 K. The results show that the surface density of alkylthiol monolayer reaches a maximum value at near room temperature (200-300 K), while significantly decreases with increasing temperature in the higher temperature region (> 300 {{K}}), and slightly decreases with decreasing temperature at low temperature (< 200 {{K}}). We find that the temperature dependence of surface ligand density in the higher temperature region is attributed to the substantial ligand desorption induced by the thermal fluctuation, while that at low temperature results from the reduction in entropy caused by the change in the ordering of passivating monolayer. These results are expected helpful to understand the temperature-dependent surface coverage of gold nanocrystals.

Analysis of recent climatic changes in the Arabian Peninsula region

NASA Astrophysics Data System (ADS)

Nasrallah, H. A.; Balling, R. C.

1996-12-01

Interest in the potential climatic consequences of the continued buildup of anthropo-generated greenhouse gases has led many scientists to conduct extensive climate change studies at the global, hemispheric, and regional scales. In this investigation, analyses are conducted on long-term historical climate records from the Arabian Peninsula region. Over the last 100 years, temperatures in the region increased linearly by 0.63 °C. However, virtually all of this warming occurred from 1911 1935, and over the most recent 50 years, the Arabian Peninsula region has cooled slightly. In addition, the satellite-based measurements of lower-tropospheric temperatures for the region do not show any statistically significant warming over the period 1979 1991. While many other areas of the world are showing a decrease in the diurnal temperature range, the Arabian Peninsula region reveals no evidence of a long-term change in this parameter. Precipitation records for the region show a slight, statistically insignificant decrease over the past 40 years. The results from this study should complement the mass of information that has resulted from similar regional climate studies conducted in the United States, Europe, and Australia.

Fast Equalization for Large Lithium Ion Batteries

DTIC Science & Technology

2008-09-01

Lithium - ion batteries use an electrolyte that is flammable if exposed to high temperatures. Slight differences between the series-connected cells in a LiIon battery pack can produce imbalances in the cell voltages, and this greatly reduces the charge capacity. These batteries cannot be trickle charged like a lead acid battery because this would slightly overcharge some cells and would cause these cells to ignite. There are different methods used to ensure that the cells of a battery pack are not overcharged. The targeted equalizer (EQU) described here can

Milling of gamma TiAl intermetallic alloys

NASA Astrophysics Data System (ADS)

Beranoagirre, A.; López de Lacalle, L. N.

2009-11-01

The work here exposed, is framed in the line of development of slight materials with good properties, used to reduction of weight in different components for the aviation and automotion. To use at high temperatures in slight pieces with high resistance. The superalloys of type Gamma TiAl is a attractive alternative to other titanium alloys, due to high relationship resistance/weigh and the resistance to the corrosion. This work, obtained the results in millin of three types of gamma TiAl alloys. Tools of integral hard metal are used, with different advances and cut speeds.

Variation of the channel temperature in the transmission of lightning leader

NASA Astrophysics Data System (ADS)

Chang, Xuan; Yuan, Ping; Cen, Jianyong; Wang, Xuejuan

2017-06-01

According to the time-resolved spectra of the lightning stepped leader and dart leader processes, the channel temperature, its evolution characteristics with time and the variation along the channel height in the transmission process were analyzed. The results show that the stepped leader tip has a slightly higher temperature than the trailing end, which should be caused by a large amount of electric charges on the leader tip. In addition, both temperature and brightness are enhanced at the position of the channel node. The dart leader has a higher channel temperature than the stepped leader but a lower temperature than the return stroke. Meanwhile, the channel temperature of the dart leader obviously increases when the dart leader propagates to the ground.

The effect of temperature mixing on the observable (T, β)-relation of interstellar dust clouds

NASA Astrophysics Data System (ADS)

Juvela, M.; Ysard, N.

2012-03-01

Context. Detailed studies of the shape of dust emission spectra are possible thanks to the current instruments capable of simultaneous observations in several sub-millimetre bands (e.g., Herschel and Planck). The relationship between the observed spectra and the intrinsic dust grain properties is known to be affected by the noise and the line-of-sight temperature variations. However, some controversy remains even on the basic effects resulting from the mixing of temperatures along the line-of-sight or within the instrument beam. Aims: Regarding the effect of temperature variations, previous studies have suggested either a positive or a negative correlation between the colour temperature TC and the observed spectral index βObs. Our aim is to show that both cases are possible and to determine the principal factors leading to either behaviour. Methods: We start by studying the behaviour of the sum of two or three modified black bodies at different temperatures. Then, with radiative transfer models of spherical clouds, we examine the probability distributions of the dust mass as a function of the physical dust temperature. With these results as a guideline, we examine the (TC, βobs) relations for different sets of clouds. Results: Even in the simple case of models consisting of two blackbodies at temperatures T0 and T0 + ΔT0, the correlation between TC and βobs can be either positive or negative. If one compares models where the temperature difference ΔT0 between the two blackbodies is varied, the correlation is negative. If the models differ in their mean temperature T0 rather than in ΔT0, the correlation remains positive. Radiative transfer models show that externally heated clouds have different mean temperatures but the widths of their temperature distributions are rather similar. Thus, in observations of samples of such clouds the correlation between TC and βObs is expected to be positive. The same result applies to clouds illuminated by external radiation fields of different intensity. For internally heated clouds a negative correlation is the more likely alternative. Conclusions: Previous studies of the (TC,β) relation have been correct in that, depending on the cloud sample, both positive and negative correlations are possible. For externally heated clouds the effect is opposite to the negative correlation seen in the observations. If the signal-to-noise ratio is high, the observed negative correlation could be explained by the temperature dependence of the dust optical properties but that intrinsic dependence could be even steeper than the observed one.

Characterization of Low Noise, Precision Voltage Reference REF5025-HT Under Extreme Temperatures

NASA Technical Reports Server (NTRS)

Patterson, Richard; Hammoud, Ahmad

2010-01-01

The performance of Texas Instruments precision voltage reference REF5025-HT was assessed under extreme temperatures. This low noise, 2.5 V output chip is suitable for use in high temperature down-hole drilling applications, but no data existed on its performance at cryogenic temperatures. The device was characterized in terms of output voltage and supply current at different input voltage levels as a function of temperature between +210 C and -190 C. Line and load regulation characteristics were also established at six load levels and at different temperatures. Restart capability at extreme temperatures and the effects of thermal cycling, covering the test temperature range, on its operation and stability were also investigated. Under no load condition, the voltage reference chip exhibited good stability in its output over the temperature range of -50 C to +200 C. Outside that temperature range, output voltage did change as temperature was changed. For example, at the extreme temperatures of +210 C and - 190 C, the output level dropped to 2.43 V and 2.32 V, respectively as compared to the nominal value of 2.5 V. At cryogenic test temperatures of -100 C and -150 C the output voltage dropped by about 20%. The quiescent supply current of the voltage reference varied slightly with temperature but remained close to its specified value. In terms of line regulation, the device exhibited excellent stability between -50 C and +150 C over the entire input voltage range and load levels. At the other test temperatures, however, while line regulation became poor at cryogenic temperatures of -100 C and below, it suffered slight degradation at the extreme high temperature but only at the high load level of 10 mA. The voltage reference also exhibited very good load regulation with temperature down to -100 C, but its output dropped sharply at +210 C only at the heavy load of 10 mA. The semiconductor chip was able restart at the extreme temperatures of -190 C and +210 C, and the limited thermal cycling did not influence its characteristics and had no impact on its packaging as no structural or physical damage was observed.

Communication: Rigorous quantum dynamics of O + O{sub 2} exchange reactions on an ab initio potential energy surface substantiate the negative temperature dependence of rate coefficients

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Yaqin; Sun, Zhigang, E-mail: zsun@dicp.ac.cn, E-mail: dawesr@mst.edu, E-mail: hguo@unm.edu; Center for Advanced Chemical Physics, University of Science and Technology of China, 96 Jinzhai Road, Hefei 230026

2014-08-28

The kinetics and dynamics of several O + O{sub 2} isotope exchange reactions have been investigated on a recently determined accurate global O{sub 3} potential energy surface using a time-dependent wave packet method. The agreement between calculated and measured rate coefficients is significantly improved over previous work. More importantly, the experimentally observed negative temperature dependence of the rate coefficients is for the first time rigorously reproduced theoretically. This negative temperature dependence can be attributed to the absence in the new potential energy surface of a submerged “reef” structure, which was present in all previous potential energy surfaces. In addition, contributionsmore » of rotational excited states of the diatomic reactant further accentuate the negative temperature dependence.« less

Potential of water-washing of rape straw on thermal properties and interactions during co-combustion with bituminous coal.

PubMed

Ma, Qiulin; Han, Lujia; Huang, Guangqun

2017-06-01

The aim of this work was to study the thermal properties and interactions during co-combustion of rape straw (RS) before and after water-washing with bituminous coal. A series of experiments was conducted to investigate the properties and interactions during co-combustion of RS with bituminous coal (at 10, 20, 40 and 60% RS). The feasibility and potential of water-washing as an RS pre-treatment was also explored. Reactivity and the amount of heat released followed a quadratic trend, while changes to the degree of interactions between the fuels conformed to a cosine curve. Water-washing increased the ignition and burn-out temperatures and slightly decreased reactivity. Demineralization negatively affected the previously synergistic co-firing relationship, nevertheless, the amount of heat released increased by 10.28% and the average activation energy (146kJ/mol) was lower than that of the unwashed blend (186kJ/mol). Overall, water-washing of RS could prove a useful pre-treatment before co-combustion with bituminous coal. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effects of phosphogypsum and superphosphate on compost maturity and gaseous emissions during kitchen waste composting.

PubMed

Yang, Fan; Li, Guoxue; Shi, Hong; Wang, Yiming

2015-02-01

This study investigated the effects of phosphogypsum and superphosphate on the maturity and gaseous emissions of composting kitchen waste. Two amended compost treatments were conducted using phosphogypsum and superphosphate as additives with the addition of 10% of initial raw materials (dry weight). A control treatment was also studied. The treatments were conducted under aerobic conditions in 60-L reactors for 35 days. Maturity indexes were determined, and continuous measurements of CH4, N2O, and NH3 were taken. Phosphogypsum and superphosphate had no negative effects on compost maturity, although superphosphate inhibited the temperature rise in the first few days. The addition of phosphogypsum and superphosphate drastically reduced CH4 emissions (by 85.8% and 80.5%, respectively) and decreased NH3 emissions (by 23.5% and 18.9%, respectively). However, a slight increase in N2O emissions (by 3.2% and 14.8%, respectively) was observed. Composting with phosphogypsum and superphosphate reduced total greenhouse gas emissions by 17.4% and 7.3% respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

Influence of hydrothermal processing on functional properties and grain morphology of finger millet.

PubMed

Dharmaraj, Usha; Meera, M S; Reddy, S Yella; Malleshi, Nagappa G

2015-03-01

Finger millet was hydrothermally processed followed by decortication. Changes in color, diameter, density, sphericity, thermal and textural characteristics and also some of the functional properties of the millet along with the grain morphology of the kernels after hydrothermal processing and decortication were studied. It was observed that, the millet turned dark after hydrothermal processing and color improved over native millet after decortication. A slight decrease in grain diameter was observed but sphericity of the grains increased on decortication. The soft and fragile endosperm turned into a hard texture and grain hardness increased by about 6 fold. Hydrothermal processing increased solubility and swelling power of the millet at ambient temperature. Pasting profile indicated that, peak viscosity decreased significantly on hydrothermal processing and both hydrothermally processed and decorticated millet exhibited zero breakdown viscosity. Enthalpy was negative for hydrothermally processed millet and positive for decorticated grains. Microscopic studies revealed that the orderly structure of endosperm changed to a coherent mass after hydrothermal processing and the different layers of seed coat get fused with the endosperm.

Enhanced photochemical conversion of NO2 to HONO on humic acids in the presence of benzophenone.

PubMed

Han, Chong; Yang, Wangjin; Yang, He; Xue, Xiangxin

2017-12-01

The photochemical conversion of NO 2 to HONO on humic acids (HA) in the presence of benzophenone (BP) was investigated using a flow tube reactor coupled to a NO x analyzer at ambient pressure. BP significantly enhanced the reduction of NO 2 to HONO on HA under simulated sunlight, as shown by the increase of NO 2 uptake coefficient (γ) and HONO yield with the mass ratio of BP to HA. The γ and HONO yield on the mixtures of HA and BP obviously depended on the environmental conditions. Both γ and HONO yield increased with the increase of irradiation intensity and temperature, whereas they decreased with pH. The γ exhibited a negative dependence on the NO 2 concentration, which had slight influences on the HONO yield. There were maximum values for the γ and HONO yield at relative humidity (RH) of 22%. Finally, atmospheric implications about the photochemical reaction of NO 2 and HA in the presence of photosensitive species were discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Characterization of thermotropism in primary roots of maize: dependence on temperature and temperature gradient, and interaction with gravitropism

NASA Technical Reports Server (NTRS)

Poff, K. L.

1991-01-01

Thermotropism in primary roots of Zea mays L. was studied with respect to gradient strength (degrees C cm-1), temperature of exposure within a gradient, pre-treatment temperature, and gravitropic stimulation. The magnitude of the response decreased with gradient strength. Maximum thermotropism was independent of gradient strength and pre-treatment temperature. The range of temperature for positive and negative thermotropism did not change with pre-treatment temperature. However, the exact range of temperatures for positive and negative thermotropism varied with gradient strengths. In general, temperatures of exposure lower than 25 degrees C resulted in positive tropic responses while temperatures of exposure of 39 degrees C or more resulted in negative tropic responses. Thermotropism was shown to modify and reverse the normal gravitropic curvature of a horizontal root when thermal gradients were applied opposite the 1 g vector. It is concluded that root thermotropism is a consequence of thermal sensing and that the curvature of the primary root results from the interaction of the thermal and gravitational sensing systems.

The relationship between thermal environments and clothing insulation for elderly individuals in Shanghai, China.

PubMed

Jiao, Yu; Yu, Hang; Wang, Tian; An, Yusong; Yu, Yifan

2017-12-01

The relationship between thermal environmental parameters and clothing insulation is an important element in improving thermal comfort for the elderly. A field study was conducted on the indoor, transition space, and outdoor thermal environments of 17 elderly facilities in Shanghai, China. A random questionnaire survey was used to gather data from 672 valid samples. A statistical analysis of the data was conducted, and multiple linear regression models were established to quantify the relationships between clothing insulation, respondent age, indoor air temperature, and indoor relative humidity. Results indicated that the average thermal insulation of winter and summer clothing is 1.38 clo and 0.44 clo, respectively, for elderly men and 1.39 clo and 0.45 clo, respectively, for elderly women. It was also found that the thermal insulation of winter clothing is linearly correlated with age, and that there were seasonal differences in the relationship between clothing insulation and the environment. During winter, the clothing insulation is negatively correlated only with indoor temperature parameters (air temperature and operative temperature) for elderly males, while it is negatively correlated with indoor temperature parameters as well as transition space and outdoor air temperature for elderly females. In summer, clothing insulation for both elderly males and females is negatively correlated with outdoor temperature, as well as indoor temperature parameters (air temperature and operative temperature). The thermal insulation of summer clothing is also negatively correlated with transitional space temperature for males. Copyright © 2017 Elsevier Ltd. All rights reserved.

Thermal Image Measurements of Infrared Signatures

DTIC Science & Technology

1986-12-01

110A𔃾 (mItm D#Ie. gnea.od Block 19 contd. "ý-been shown to var,% bc.th positively and negatively comparedwith the thermometric tem"h perature...This effective temperature difference has been shown to vary both positively and negatively compared with the thermometric temperature difference... thermometric temperature difference is no longer a good representation of the radiance contrast. An "effective temperature difference" can however be defined

[Measurement of rotational and vibrational temperatures in arc plasma based on the first negative system of N2+ (B(2) sigma --> X(2) sigma)].

PubMed

Tu, Xin; Yan, Jian-hua; Ma, Zeng-yi; Li, Xiao-dong; Pan, Xin-chao; Cen, Ke-fa; Cheron, Bruno

2006-12-01

The molecular emission spectra lines of the first negative system N2+ (B(2) sigma--> X(2) sigma ) are frequently observed in the plasma source containing nitrogen. (0-0) and (1--1) N2+ first negative system molecular bands around 391. 4 nm can be used to the measure the rotational and vibrational temperatures in a DC argon-nitrogen plasma at atmospheric pressure. The proposed method based on the comparison between this experimental emission spectrum and the computer simulated one is presented. The effect of the apparatus function, vibrational temperature and rotational temperatures on the line structure of numerical simulated spectrum is discussed. The results show that the electron temperature, rotational temperature, vibrational temperature and kinetic temperature of plasma arc are almost the same, which can be interpreted as that DC argon-nitrogen arc plasma at atmospheric pressure is in LTE under their experimental conditions.

Effect of temperature on life history parameters of adult Culicoides sonorensis (Diptera: Ceratopogonidae) in relation to geographic origin and vectorial capacity for bluetongue virus.

PubMed

Lysyk, T J; Danyk, T

2007-09-01

The effect of temperature on survival, oviposition, gonotrophic development, and a life history factor of vectorial capacity were examined in adult Culicoides sonorensis (Wirth & Jones) (Diptera: Ceratopogonidae) that originated from two geographic locations. Flies originating from the United States (Colorado) had slightly reduced survival after a bloodmeal compared with wild flies collected in southern Alberta (AB), Canada. Survival of AB flies declined in a curvilinear manner with temperature, whereas survival of U.S. flies showed a linear response to temperature. The survivorship curve of the AB flies more closely followed a Weibull distribution than an exponential, indicating survival was age-dependent. Survivorship of the U.S. flies followed an exponential distribution. Females from both sources laid similar numbers of eggs throughout their life. The first eggs were laid by females from both sources at 31.9 degree-day (DD)9.3. Dissections of blood-fed flies reared at various temperatures indicated that flies from both sources were 90% gravid at 32 DD9.3. Relationships among temperature and life history components of vectorial capacity were similar among flies from the two sources and indicated that vectorial capacity would be approximately 1.8-2.6-fold greater in a southern U.S. climate compared with southwestern Canada due solely to the effects of temperature on the life history of C. sonorensis. Using life history estimates derived from Weibull model had little effect on estimating vectorial capacity, whereas using estimates derived from the exponential model slightly overestimated vectorial capacity.

Validation of the Aura Microwave Limb Sounder Temperature and Geopotential Height Measurements

NASA Technical Reports Server (NTRS)

Schwartz, M. J.; Lambert, A.; Manney, G. L.; Read, W. G.; Livesey, N. J.; Froidevaux, L.; Ao, C. O.; Bernath, P. F.; Boone, C. D.; Cofield, R. E.;

Spatial correlation in precipitation trends in the Brazilian Amazon

NASA Astrophysics Data System (ADS)

Buarque, Diogo Costa; Clarke, Robin T.; Mendes, Carlos Andre Bulhoes

2010-06-01

A geostatistical analysis of variables derived from Amazon daily precipitation records (trends in annual precipitation totals, trends in annual maximum precipitation accumulated over 1-5 days, trend in length of dry spell, trend in number of wet days per year) gave results that are consistent with those previously reported. Averaged over the Brazilian Amazon region as a whole, trends in annual maximum precipitations were slightly negative, the trend in the length of dry spell was slightly positive, and the trend in the number of wet days in the year was slightly negative. For trends in annual maximum precipitation accumulated over 1-5 days, spatial correlation between trends was found to extend up to a distance equivalent to at least half a degree of latitude or longitude, with some evidence of anisotropic correlation. Time trends in annual precipitation were found to be spatially correlated up to at least ten degrees of separation, in both W-E and S-N directions. Anisotropic spatial correlation was strongly evident in time trends in length of dry spell with much stronger evidence of spatial correlation in the W-E direction, extending up to at least five degrees of separation, than in the S-N. Because the time trends analyzed are shown to be spatially correlated, it is argued that methods at present widely used to test the statistical significance of climate trends over time lead to erroneous conclusions if spatial correlation is ignored, because records from different sites are assumed to be statistically independent.

Continued development of abradable gas path seals. [for gas turbine engines

NASA Technical Reports Server (NTRS)

Shiembob, L. T.

1975-01-01

Major program objectives were the continued development of NiCrAlY feltmetal and honeycomb systems for knife edge seal applications in the 1144 to 1366 K temperature range, and to initiate abradable seal material evaluation for blade tip seal applications in the 1366 to 1589 K temperature range. Larger fiber size, higher density feltmetal showed greatly improved erosion resistance with a slight reduction in abradability compared to the baseline feltmetal. Pack aluminide coating of the honeycomb extended the oxidation resistance and slightly improved the abradability of this material. Evaluation through selected abradability, erosion and oxidation testing, and pertinent metallography led to selection of a plasma sprayed yttria stabilized zirconia (ZrO2)/CoCrAlY layered system as the system with the most potential to meet the 1589 K requirement for blade tip seals. This system demonstrated structural integrity, erosion resistance, and some degree of abradability.

Nonlinear problems of the theory of heterogeneous slightly curved shells

NASA Technical Reports Server (NTRS)

Kantor, B. Y.

1973-01-01

An account if given of the variational method of the solution of physically and geometrically nonlinear problems of the theory of heterogeneous slightly curved shells. Examined are the bending and supercritical behavior of plates and conical and spherical cupolas of variable thickness in a temperature field, taking into account the dependence of the elastic parameters on temperature. The bending, stability in general and load-bearing capacity of flexible isotropic elastic-plastic shells with different criteria of plasticity, taking into account compressibility and hardening. The effect of the plastic heterogeneity caused by heat treatment, surface work hardening and irradiation by fast neutron flux is investigated. Some problems of the dynamic behavior of flexible shells are solved. Calculations are performed in high approximations. Considerable attention is given to the construction of a machine algorithm and to the checking of the convergence of iterative processes.

Curie-Weiss behavior of Y{sub 1-x}Sr{sub x}MnO{sub 3} (x = 0 and 0.03)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thakur, Rajesh K., E-mail: thakur.rajesh2009@gmail.com; Thakur, Rasna; Gaur, N. K.

2015-06-24

The effect of bivalent cation Sr-doping on magnetic properties in multiferroic YMnO{sub 3} manganites was systemically studied by DC magnetic measurements. Both of the reported samples were prepared by solid-state reaction method with composition Y{sub 1−x}Sr{sub x}MnO{sub 3} (x = 0.00 and 0.03). The X-ray diffraction (XRD) results show that the compounds are synthesized in hexagonal crystal structure with space group P6{sub 3}cm (JCPDS: 25-1079) and slight increase in the lattice parameter is observed with strontium doping. The magnetisation versus temperature curve shows no clear anomaly near the antiferromagnetic transition temperature (T{sub N}), however from the magnetic measurements at 1000Oemore » a slight increase in the magnetisation is clearly witnessed with increasing Stront ium content to the Y-site.« less

Neutral beamline with ion energy recovery based on magnetic blocking of electrons

DOEpatents

Stirling, William L.

1982-01-01

A neutral beamline generator with energy recovery of the full-energy ion ponent of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the electrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

Effect of Frozen Storage Temperature on the Quality of Premium Ice Cream.

PubMed

Park, Sung Hee; Jo, Yeon-Ji; Chun, Ji-Yeon; Hong, Geun-Pyo; Davaatseren, Munkhtugs; Choi, Mi-Jung

2015-01-01

The market sales of premium ice cream have paralleled the growth in consumer desire for rich flavor and taste. Storage temperature is a major consideration in preserving the quality attributes of premium ice cream products for both the manufacturer and retailers during prolonged storage. We investigated the effect of storage temperature (-18℃, -30℃, -50℃, and -70℃) and storage times, up to 52 wk, on the quality attributes of premium ice cream. Quality attributes tested included ice crystal size, air cell size, melting resistance, and color. Ice crystal size increased from 40.3 μm to 100.1 μm after 52 wk of storage at -18℃. When ice cream samples were stored at -50℃ or -70℃, ice crystal size slightly increased from 40.3 μm to 57-58 μm. Initial air cell size increased from 37.1 μm to 87.7 μm after storage at -18℃ for 52 wk. However, for storage temperatures of -50℃ and -70℃, air cell size increased only slightly from 37.1 μm to 46-47 μm. Low storage temperature (-50℃ and -70℃) resulted in better melt resistance and minimized color changes in comparison to high temperature storage (-18℃ and -30℃). In our study, quality changes in premium ice cream were gradually minimized according to decrease in storage temperature up to-50℃. No significant beneficial effect of -70℃ storage was found in quality attributes. In the scope of our experiment, we recommend a storage temperature of -50℃ to preserve the quality attributes of premium ice cream.

Effect of Frozen Storage Temperature on the Quality of Premium Ice Cream

PubMed Central

Park, Sung Hee; Jo, Yeon-Ji; Chun, Ji-Yeon; Hong, Geun-Pyo

2015-01-01

The market sales of premium ice cream have paralleled the growth in consumer desire for rich flavor and taste. Storage temperature is a major consideration in preserving the quality attributes of premium ice cream products for both the manufacturer and retailers during prolonged storage. We investigated the effect of storage temperature (−18℃, −30℃, −50℃, and −70℃) and storage times, up to 52 wk, on the quality attributes of premium ice cream. Quality attributes tested included ice crystal size, air cell size, melting resistance, and color. Ice crystal size increased from 40.3 μm to 100.1 μm after 52 wk of storage at −18℃. When ice cream samples were stored at −50℃ or −70℃, ice crystal size slightly increased from 40.3 μm to 57-58 μm. Initial air cell size increased from 37.1 μm to 87.7 μm after storage at −18℃ for 52 wk. However, for storage temperatures of −50℃ and −70℃, air cell size increased only slightly from 37.1 μm to 46-47 μm. Low storage temperature (−50℃ and −70℃) resulted in better melt resistance and minimized color changes in comparison to high temperature storage (−18℃ and −30℃). In our study, quality changes in premium ice cream were gradually minimized according to decrease in storage temperature up to−50℃. No significant beneficial effect of −70℃ storage was found in quality attributes. In the scope of our experiment, we recommend a storage temperature of −50℃ to preserve the quality attributes of premium ice cream. PMID:26877639

Free-Flight Skin Temperature and Pressure Measurements on a Slightly Blunted 25 Deg Cone-Cylinder-Flare Configuration to a Mach Number of 9.89

NASA Technical Reports Server (NTRS)

Bond, Aleck C.; Rumsey, Charles B.

1957-01-01

Skin temperatures and surface pressures have been measured on a slightly blunted cone-cylinder-flare configuration to a maximum Mach number of 9.89 with a rocket-propelled model. The cone had a t o t a l angle of 25 deg and the flare had a 10 deg half-angle. Temperature data were obtained at eight cone locations, four cylinder locations, and seven flare locations; pressures were measured at one cone location, one cylinder location, and three flare locations. Four stages of propulsion were utilized and a reentry type of trajectory was employed in which the high-speed portion of flight was obtained by firing the last two stages during the descent of the model from a peak altitude of 99,400 feet. The Reynolds number at peak Mach number was 1.2 x 10(exp 6) per foot of model length. The model length was 6.68 feet. During the higher speed portions of flight, temperature measurements along one element of the nose cone indicated that the boundary layer was probably laminar, whereas on the opposite side of the nose the measurements indicated transitional or turbulent flow. Temperature distributions along one meridian of the model showed the flare to have the highest temperatures and the cylinder generally to have the lowest. A maximum temperature of 970 F was measured on the cone element showing the transitional or turbulent flow; along the opposite side of the model, the maximum temperatures of the cone, cylinder, and flare were 545 F, 340 F, and 680 F, respectively, at the corresponding time.

Thermal Properties of Contemporary and Conventional Gutta Percha Materials Used in Root Canal Treatment

DTIC Science & Technology

2015-01-15

α crystalline form to an amorphous gutta-percha.6,18 It should be noted that these temperatures for commercial endodontic gutta-percha will be...slightly different, as these temperature values are for pure gutta-percha. With the increased number endodontic gutta-percha materials being marketed...clinical technique. Furthermore, some literature has suggested that not all commercially available endodontic gutta-percha materials exist in the same

Altitude Performance of Modified J71 Afterburner with Revised Engine Operating Conditions

NASA Technical Reports Server (NTRS)

Useller, James W.; Russey, Robert E.

1955-01-01

An investigation was conducted in an altitude test chamber at the NACA Lewis laboratory to determine the effect of a revision of the rated engine operating conditions and modifications to the afterburner fue1 system, flameholder, and shell cooling on the augmented performance of the J71-A-2 (x-29) turbo jet engine operating at altitude . The afterburner modifications were made by the manufacturer to improve the endurance at sea-level, high-pressure conditions and to reduce the afterburner shell temperatures. The engine operating conditions of rated rotational speed and turbine-outlet gas temperature were increased. Data were obtained at conditions simulating flight at a Mach number of 0.9 and at altitudes from 40,000 to 60,000 feet. The afterburner modifications caused a reduction in afterburner combustion efficiency. The increase in rated engine speed and turbine-outlet temperature coupled with the afterburner modifications resulted in the over-all thrust of the engine and afterburner being unchanged at a given afterburner equivalence ratio, while the specific fuel consumption was increased slightly. A moderate shift in the range of equivalence ratios over which the afterburner would operate was encountered, but the maximum operable altitude remained unaltered. The afterburner-shell temperatures were also slightly reduced because of the modifications to the afterburner.

Temperature dependence of regioselectivity in nucleophilic photosubstitution of 4-nitroanisole. The activation energy criterion for regioselectivity.

PubMed

Wubbels, Gene G; Danial, Hanan; Policarpio, Danielle

2010-11-19

Photosubstitution of the nitro group vs the methoxy group of triplet 4-nitroanisole by hydroxide ion in water leads to product yields of about 80% 4-methoxyphenol and 20% 4-nitrophenol. The ratio depends slightly on temperature from 3 to 73 °C. The slight temperature variation in the yield ratio is reproduced almost perfectly with a simple Arrhenius model for a mechanism involving bonding of hydroxide ion with the triplet state of 4-nitroanisole. The competing transition states have activation energies of 2.2 and 2.6 kcal/mol, respectively. Correct prediction of regioselectivity can be done for this case by quantum chemical calculation of the competing triplet transition-state energies, or those of the corresponding triplet σ-complexes. Other models for aromatic photosubstitution regioselectivity in mechanisms of the S(N)2Ar* type, such as those based on calculated electron densities, HOMO/LUMO coefficients, or energy gap sizes, are discussed and shown to be inferior to the relative activation energies model. The photoreaction in alcohol solvents, claimed by others to generate the same products as in water and to have an exceedingly large variation of the product ratio with temperature, may reflect chemical changes other than those reported.

Simulation of the process kinetics and analysis of physicochemical properties in the freeze drying of kale

NASA Astrophysics Data System (ADS)

Dziki, Dariusz; Polak, Renata; Rudy, Stanisław; Krzykowski, Andrzej; Gawlik-Dziki, Urszula; Różyło, Renata; Miś, Antoni; Combrzyński, Maciej

2018-01-01

Investigations were performed to study the freeze-drying process of kale (Brassica oleracea L. var acephala). The process of freeze-drying was performed at temperatures of 20, 40, and 60°C for whole pieces of leaves and for pulped leaves. The kinetics of the freeze-drying of both kale leaves and kale pulp were best described by the Page model. The increasing freeze-drying temperature from 20 to 60°C induced an approximately two-fold decrease in the drying time. Freeze-drying significantly increased the value of the lightness, delta Chroma, and browning index of kale, and had little influence on the hue angle. The highest increase in the lightness and delta Chroma was observed for whole leaves freeze-dried at 20°C. An increase in the drying temperature brought about a slight decrease in the lightness, delta Chroma and the total colour difference. Pulping decreased the lightness and hue angle, and increased browning index. Freeze-drying engendered a slight decrease in the total phenolics content and antioxidant activity, in comparison to fresh leaves. The temperature of the process and pulping had little influence on the total phenolics content and antioxidant activity of dried kale, but significantly decreased the contents of chlorophyll a and chlorophyll b.

Effect of Temperature on Synthetic Positive and Negative Feedback Gene Networks

NASA Astrophysics Data System (ADS)

Charlebois, Daniel A.; Marshall, Sylvia; Balazsi, Gabor

Synthetic biological systems are built and tested under well controlled laboratory conditions. How altering the environment, such as the ambient temperature affects their function is not well understood. To address this question for synthetic gene networks with positive and negative feedback, we used mathematical modeling coupled with experiments in the budding yeast Saccharomyces cerevisiae. We found that cellular growth rates and gene expression dose responses change significantly at temperatures above and below the physiological optimum for yeast. Gene expression distributions for the negative feedback-based circuit changed from unimodal to bimodal at high temperature, while the bifurcation point of the positive feedback circuit shifted up with temperature. These results demonstrate that synthetic gene network function is context-dependent. Temperature effects should thus be tested and incorporated into their design and validation for real-world applications. NSERC Postdoctoral Fellowship (Grant No. PDF-453977-2014).

Assessment of microclimate conditions under artificial shades in a ginseng field.

PubMed

Lee, Kyu Jong; Lee, Byun-Woo; Kang, Je Yong; Lee, Dong Yun; Jang, Soo Won; Kim, Kwang Soo

2016-01-01

Knowledge on microclimate conditions under artificial shades in a ginseng field would facilitate climate-aware management of ginseng production. Weather data were measured under the shade and outside the shade at two fields located in Gochang-gun and Jeongeup-si, Korea, in 2011 and 2012 seasons to assess temperature and humidity conditions under the shade. An empirical approach was developed and validated for the estimation of leaf wetness duration (LWD) using weather measurements outside the shade as inputs to the model. Air temperature and relative humidity were similar between under the shade and outside the shade. For example, temperature conditions favorable for ginseng growth, e.g., between 8°C and 27°C, occurred slightly less frequently in hours during night times under the shade (91%) than outside (92%). Humidity conditions favorable for development of a foliar disease, e.g., relative humidity > 70%, occurred slightly more frequently under the shade (84%) than outside (82%). Effectiveness of correction schemes to an empirical LWD model differed by rainfall conditions for the estimation of LWD under the shade using weather measurements outside the shade as inputs to the model. During dew eligible days, a correction scheme to an empirical LWD model was slightly effective (10%) in reducing estimation errors under the shade. However, another correction approach during rainfall eligible days reduced errors of LWD estimation by 17%. Weather measurements outside the shade and LWD estimates derived from these measurements would be useful as inputs for decision support systems to predict ginseng growth and disease development.

Assessment of microclimate conditions under artificial shades in a ginseng field

PubMed Central

Lee, Kyu Jong; Lee, Byun-Woo; Kang, Je Yong; Lee, Dong Yun; Jang, Soo Won; Kim, Kwang Soo

2015-01-01

Background Knowledge on microclimate conditions under artificial shades in a ginseng field would facilitate climate-aware management of ginseng production. Methods Weather data were measured under the shade and outside the shade at two fields located in Gochang-gun and Jeongeup-si, Korea, in 2011 and 2012 seasons to assess temperature and humidity conditions under the shade. An empirical approach was developed and validated for the estimation of leaf wetness duration (LWD) using weather measurements outside the shade as inputs to the model. Results Air temperature and relative humidity were similar between under the shade and outside the shade. For example, temperature conditions favorable for ginseng growth, e.g., between 8°C and 27°C, occurred slightly less frequently in hours during night times under the shade (91%) than outside (92%). Humidity conditions favorable for development of a foliar disease, e.g., relative humidity > 70%, occurred slightly more frequently under the shade (84%) than outside (82%). Effectiveness of correction schemes to an empirical LWD model differed by rainfall conditions for the estimation of LWD under the shade using weather measurements outside the shade as inputs to the model. During dew eligible days, a correction scheme to an empirical LWD model was slightly effective (10%) in reducing estimation errors under the shade. However, another correction approach during rainfall eligible days reduced errors of LWD estimation by 17%. Conclusion Weather measurements outside the shade and LWD estimates derived from these measurements would be useful as inputs for decision support systems to predict ginseng growth and disease development. PMID:26843827

Effect of nonparallel placement of in-circle bipolar radiofrequency ablation probes on volume of tissue ablated with heat sink.

PubMed

Pillai, Krishna; Al-Alem, Ihssan; Akhter, Javed; Chua, Terence C; Shehata, Mena; Morris, David L

2015-06-01

Percutaneous bipolar radiofrequency ablation (RFA) is a minimally invasive technique for treating liver tumors. It is not always possible to insert the bipolar probes parallel to each other on either side of tumor, since it restricts maneuverability away from vital structures or ablate certain tumor shape. Therefore, we investigated how nonparallel placement of probes affected ablation. Bipolar RFA in parallel and in divergent positions were submerged in tissue model (800 mL egg white) at 37°C and ablated. Temperature probes, T1 and T2 were placed 8.00 mm below the tip of the probes, T3 in between the probe coil elements and T4 and T5 at water inlet and outlet, respectively. Both models with heat sink (+HS) and without (-HS) were investigated. The mean ablated tissue volume, mass, density and height increased linearly with unit angle increase for -HS model. With +HS, a smaller increase in mean volume and mass, a slightly greater increase in mean density but a reduction in height of tissue was seen. The mean ablation time and duration of maximum temperature with +HS was slightly larger, compared with -HS, while -HS ablated at a slightly higher temperature. The heat sink present was minimal for probes in parallel position compared to nonparallel positions. Divergence from parallel insertion of bipolar RFA probes increased the mean volume, mass, and density of tissue ablated. However, the presence of large heat sinks may limit the application of this technique, when tumors border on larger vessels. © The Author(s) 2014.

Searching for the signatures of terrestrial planets in F-, G-type main-sequence stars

NASA Astrophysics Data System (ADS)

González Hernández, J. I.; Delgado-Mena, E.; Sousa, S. G.; Israelian, G.; Santos, N. C.; Adibekyan, V. Zh.; Udry, S.

2013-04-01

Context. Detailed chemical abundances of volatile and refractory elements have been discussed in the context of terrestrial-planet formation during in past years. Aims: The HARPS-GTO high-precision planet-search program has provided an extensive database of stellar spectra, which we have inspected in order to select the best-quality spectra available for late type stars. We study the volatile-to-refractory abundance ratios to investigate their possible relation with the low-mass planetary formation. Methods: We present a fully differential chemical abundance analysis using high-quality HARPS and UVES spectra of 61 late F- and early G-type main-sequence stars, where 29 are planet hosts and 32 are stars without detected planets. Results: As for the previous sample of solar analogs, these stars slightly hotter than the Sun also provide very accurate Galactic chemical abundance trends in the metallicity range -0.3 < [Fe/H] < 0.4. Stars with and without planets show similar mean abundance ratios. Moreover, when removing the Galactic chemical evolution effects, these mean abundance ratios, Δ [X/Fe] SUN - STARS, against condensation temperature, tend to exhibit less steep trends with nearly zero or slightly negative slopes. We have also analyzed a subsample of 26 metal-rich stars, 13 with and 13 without known planets, with spectra at S/N ~ 850, on average, in the narrow metallicity range 0.04 < [Fe/H] < 0.19. We find the similar, although not equal, abundance pattern with negative slopes for both samples of stars with and without planets. Using stars at S/N ≥ 550 provides equally steep abundance trends with negative slopes for stars both with and without planets. We revisit the sample of solar analogs to study the abundance patterns of these stars, in particular, 8 stars hosting super-Earth-like planets. Among these stars having very low-mass planets, only four of them reveal clear increasing abundance trends versus condensation temperature. Conclusions: Finally, we compared these observed slopes with those predicted using a simple model that enables us to compute the mass of rocks that have formed terrestrial planets in each planetary system. We do not find any evidence supporting the conclusion that the volatile-to-refractory abundance ratio is related to the presence of rocky planets. Based on observations collected with the HARPS spectrograph at the 3.6-m telescope (072.C-0488(E)), installed at the La Silla Observatory, ESO (Chile), with the UVES spectrograph at the 8-m Very Large Telescope (VLT) - program IDs: 67.C-0206(A), 074.C-0134(A), 075.D-0453(A) -, installed at the Cerro Paranal Observatory, ESO (Chile), and with the UES spectrograph at the 4.2-m William Herschel Telescope (WHT), installed at the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofísica de Canarias, on the island of La Palma.Tables A.1-A.8 are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/552/A6

Refertilization process in the Patagonian subcontinental lithospheric mantle of Estancia Sol de Mayo (Argentina)

NASA Astrophysics Data System (ADS)

Melchiorre, Massimiliano; Coltorti, Massimo; Gregoire, Michel; Benoit, Mathieu

2015-05-01

Anhydrous mantle xenoliths equilibrated at 1003-1040 °C from Estancia Sol de Mayo (ESM, Central Patagonia, Argentina) and entrained in post-plateau alkaline lavas belonging to Meseta Lago Buenos Aires have been investigated aiming at reconstructing the depletion and enrichment processes that affected this portion of the Patagonia lithospheric mantle. Xenoliths are characterized by a coarse-grained protogranular texture and are devoid of evident modal metasomatism. They show two texturally different clinopyroxenes: protogranular (cpx1) and texturally related to spinel (cpx2). Three different types of orthopyroxenes are also recognized: large protogranular crystals with exsolution lamellae (opx1); small clean and undeformed grains without exsolution lamellae (opx2) and small grains arranged in a vein (opx3). Major element composition of clinopyroxenes and orthopyroxenes highlights two different trends characterized by i) a high Al2O3 content at almost constant mg# and ii) a slight increase in Al2O3 content with decreasing mg#. Clinopyroxenes are enriched in LREE and are characterized by prominent to slightly negative Nb, Zr and Ti anomalies. No geochemical differences are observed between cpx1 and cpx2, while a discrimination can be observed between opx1 and opx2 (LREE-depleted; prominent to slightly negative Ti and Zr anomalies) and opx3 (prominent positive Zr anomaly). Partial melting modeling using both major and trace elements indicates a melting degree between ~ 5% and ~ 13% (up to ~ 23% according to major element modeling) for lherzolites and between ~ 20% and ~ 30% for harzburgites (down to ~ 5% according to trace element modeling). La/Yb and Al2O3, as well as Sr and Al2O3 negative correlations in clinopyroxenes point to a refertilization event affecting this lithospheric mantle. The agent was most probably a transitional alkaline/subalkaline melt, as indicated by the presence of orthopyroxene in the vein and the similar geochemical features of ESM clinopyroxenes and those from Northern Patagonia pyroxenites which are derived from transitional alkaline/subalkaline lavas.

[Interaction Between Sulfonamide Antibiotics Fates and Chicken Manure Composting].

PubMed

Lin, Hui; Wang, Jian-mei; Sun, Wan-chun; Fu, Jian-rong; Chen, Hong-jin; Ma, Jun-wei

2016-05-15

Based on aerobic manure composting with or without the addition of a mixture of sulfadimethoxine SM2 and sulfamonomethoxine SMM (1:1, m/m), changes in the physic-chemical properties of manure compost, the microbial community physiological profiles, the antibiotics concentration and the abundances of five antibiotic resistance genes (ARGs) during the composting were tracked. The results indicated that the introduction of sulfonamide antibiotics led to inhibition on the basal respiration of manure compost during the early composting period, delayed the formation of thermophilic temperature and reduced the conversion of nutrients such as organic matter, ammonia nitrogen and nitrate nitrogen. Meanwhile, the introduction of sulfonamide antibiotics dramatically affected the physiological profile of microbial community in manure in the middle stage of composting. HPLC-MS/MS results showed that both SMM and SM2 in manure were completely degraded within 14 days, while the degradation rate of SMM was faster than that of SM2. For both composting treatments with or without addition of exogenous antibiotics, the relative abundance of sull and sul2 showed an initial decline in the first 14 or 21 days and a slight increase thereafter. The addition of exogenous antibiotics showed insignificant enhancement on increasing the relative abundance of sul1 and IntI1 in manure, but resulted in an apparent increase in sul2 relative abundance. Although the fates of tetQ and tetW during composting were different from that of sulfonamide ARGs, the introduction of sulfonamide antibiotics into manure increased the relative abundance of tetracycline ARGs. Redundancy analysis indicated that composting temperature correlated negatively with sul1, sul2 and IntI1 relative abundance in manure but had no obvious relationship with tetQ and tetW relative abundance. All the ARGs detected in this work correlated negatively with C/N ratio and the nitrate nitrogen concentration of manure compost but positively correlated with pH, moisture and ammonia nitrogen concentration of manure compost.

Chlorine dioxide oxidation of Escherichia coli in water - A study of the disinfection kinetics and mechanism.

PubMed

Ofori, Isaac; Maddila, Suresh; Lin, Johnson; Jonnalagadda, Sreekantha B

2017-06-07

This study investigated the kinetics and mechanism of chlorine dioxide (ClO 2 ) inactivation of a Gram-negative bacteria Escherichia coli (ATCC 35218) in oxidant demand free (ODF) water in detail as a function of disinfectant concentration (0.5-5.0 mg/L), water pH (6.5-8.5), temperature variations (4-37°C) and bacterial density (10 5 -10 7 cfu/mL). The effects of ClO 2 on bacterial cell morphology, outer membrane permeability, cytoplasmic membrane disruption and intracellular enzymatic activity were also studied to elucidate the mechanism of action on the cells. Increasing temperature and disinfectant concentration were proportional to the rate of cell killing, but efficacy was found to be significantly subdued at 0.5 mg/L and less dependent on the bacterial density. The bactericidal efficiency was higher at alkaline pH of 8 or above as compared to neutral and slightly acidic pH of 7 and 6.5 respectively. The disinfection kinetic curves followed a biphasic pattern of rapid inactivation within the initial 2 min which were followed by a tailing even in the presence of residual biocide. The curves were adequately described by the C avg Hom model. Transmission Electron Microscopy images of the bacteria cells exposed to lethal concentrations of ClO 2 indicated very little observable morphological damage to the outer membranes of the cells. ClO 2 however was found to increase the permeability of the outer and cytoplasmic membranes leading to the leakage of membrane components such as 260 nm absorbing materials and inhibiting the activity of the intracellular enzyme β-D-galactosidase. It is suggested that the disruption of the cytoplasmic membrane and subsequent efflux of intracellular components result in the inactivation of the Gram-negative bacteria.

Temperature histories of commercial flights at severe conditions from GASP data

NASA Technical Reports Server (NTRS)

Jasperson, W. H.; Nastrom, G. D.

1983-01-01

The thermal environment of commercial aircraft from a data set gathered during the Global Atmospheric Sampling Program (GASP) is studied. The data set covers a four-year period of measurements. The report presents plots of airplane location and speed and atmospheric temperature as functions of elapsed time for 35 extreme-condition flights, selected by minimum values of several temperature parameters. One of these parameters, the severity factor, is an approximation of the in-flight wing-tank temperature. Representative low-severity-factor flight histories may be useful for actual temperature-profile inputs to design and research studies. Comparison of the GASP atmospheric temperatures to interpolated temperatures from National Meteorological Center and Global Weather Central analysis fields shows that the analysis temperatures are slightly biased toward warmer than actual temperatures, particularly over oceans and at extreme conditions.

Interaction of temperature and an environmental stressor: Moina macrocopa responds with increased body size, increased lifespan, and increased offspring numbers slightly above its temperature optimum.

PubMed

Engert, Antonia; Chakrabarti, Shumon; Saul, Nadine; Bittner, Michal; Menzel, Ralph; Steinberg, Christian E W

2013-02-01

For organisms, temperature is one of the most important environmental factors and gains increasing importance due to global warming, since increasing temperatures may pose organisms close to their environmental tolerance limits and, thus, they may become more vulnerable to environmental stressors. We analyzed the temperature-dependence of the water-soluble antioxidant capacity of the cladoceran Moina macrocopa and evaluated its life trait variables with temperature (15, 20, 25, 30°C) and humic substance (HS) concentrations (0, 0.18, 0.36, 0.90, 1.79 mM DOC) as stressors. Temperatures below and above the apparent optimum (20°C) reduced the antioxidative capacity. Additions of HSs increased body length, but decreased mean lifespan at 15 and 20°C. There was no clear HS-effect on offspring numbers at 15, 20, and 30°C. At 25°C with increasing HS-concentration, lifespan was extended and offspring numbers increased tremendously, reaching 250% of the control. Although the applied HS preparation possesses estrogenic and antiandrogenic activities, a xenohormone mechanism does not seem plausible for the reproductive increase, because comparable effects did not occur at other temperatures. A more convincing explanation appears to be the mitohormesis hypothesis which states that a certain increase of reactive oxygen production leads to improved health and longevity and, with Moina, also to increased offspring numbers. Our results suggest that at least with the eurythermic M. macrocopa, a temperature above the optimum can be beneficial for several life trait variables, even when combined with a chemical stressor. Temperatures approximately 10°C above its optimum appear to adversely affect the lifespan and reproduction of M. macrocopa. This indicates that this cladoceran species seems to be able to utilize temperature as an ecological resource in a range slightly above its thermal optimum. Copyright © 2012 Elsevier Ltd. All rights reserved.

Neutron Resonance Spectrometry Shock Temperatures in Molybdenum

NASA Astrophysics Data System (ADS)

Swift, Damian; Seifter, Achim; Holtkamp, David; Yuan, Vincent; Clark, David; Buttler, William

2007-06-01

Neutron resonance spectrometry (NRS) has been used to measure the temperature in Mo during shock loading, giving temperatures higher than expected. The effect of plastic flow and non-ideal projectile behavior were assessed. Plastic flow was estimated to contribute a temperature rise of 55K compared with hydrodynamic flow, and 100-150K on release, consistent with pyrometry measurements. Simulations were performed of the HE flyer system used to induce the shock in the Mo sample. The simulations predicted that the flyer was slightly curved on impact. The resulting spatial variations in load, including radial components of velocity, were predicted to increase the apparent NRS temperature by 160K. These corrections are sufficient to reconcile the apparent temperatures deduced using NRS with the accepted properties of Mo.

Effects of heat treating PM Rene' 95 slightly below the gamma' solvus

NASA Technical Reports Server (NTRS)

Dreshfield, R. L.

1977-01-01

An investigation was performed on as-hot-isostatically-pressed (As-HIP) Rene' 95 to obtain additional information on the variation of the amount of gamma prime with solutioning temperatures near the gamma prime solvus temperature and the resulting effects on tensile and stress rupture strength of As-HIP Rene' 95. The amount of gamma prime phase was found to increase at a rate of about 0.5% per degree Celsius as the temperature decreased from the solvus temperature to about 50 C below the gamma prime solvus temperature. The change in the amount of gamma prime phase with decreasing solutioning temperature was observed to be primarily associated with decreasing solubilities of Al+Ti+Nb and increasing solubility of Cr in the gamma phase.

Low temperature coefficient of resistance and high gage factor in beryllium-doped silicon

NASA Technical Reports Server (NTRS)

Robertson, J. B.; Littlejohn, M. A.

1974-01-01

The gage factor and resistivity of p-type silicon doped with beryllium was studied as a function of temperature, crystal orientation, and beryllium doping concentration. It was shown that the temperature coefficient of resistance can be varied and reduced to zero near room temperature by varying the beryllium doping level. Similarly, the magnitude of the piezoresistance gage factor for beryllium-doped silicon is slightly larger than for silicon doped with a shallow acceptor impurity such as boron, whereas the temperature coefficient of piezoresistance is about the same for material containing these two dopants. These results are discussed in terms of a model for the piezoresistance of compensated p-type silicon.

Spray Drying of Mosambi Juice in Lab

NASA Astrophysics Data System (ADS)

Singh, S. V.; Verma, A.

2014-01-01

The studies on spray drying of mosambi juice were carried out with Laboratory spray dryer set-up (LSD-48 MINI SPRAY DRYER-JISL). Inlet and outlet air temperature and maltodextrin (drying agent) concentration was taken as variable parameters. Experiments were conducted by using 110 °C to 140 °C inlet air temperature, 60 °C to 70 °C outlet air temperature and 5-7 % maltodextrin concentration. The free flow powder of mosambi juice was obtained with 7 % maltodextrin at 140 °C inlet air temperature and 60 °C outlet air temperature. Fresh and reconstituted juices were evaluated for vitamin C, titrable acidity and sensory characteristics. The reconstituted juice was found slightly acceptable by taste panel.

Effects of phosphogypsum and superphosphate on compost maturity and gaseous emissions during kitchen waste composting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Fan; Beijing Municipal Research Institute of Environmental Protection, Beijing 100037; Li, Guoxue, E-mail: yangfan19870117@126.com

2015-02-15

Highlights: • Effect of phosphogypsum and superphosphate on composting gas emissions was studied. • The reduction mechanisms of composting gas were clarified in this study. • No negative effect was caused on maturity with phosphogypsum and superphosphate. • CH{sub 4} and NH{sub 3} emission was decreased with phosphogypsum and superphosphate addition. • GHG decreased by 17.4% and 7.3% with phosphogypsum and superphosphate addition. - Abstract: This study investigated the effects of phosphogypsum and superphosphate on the maturity and gaseous emissions of composting kitchen waste. Two amended compost treatments were conducted using phosphogypsum and superphosphate as additives with the addition ofmore » 10% of initial raw materials (dry weight). A control treatment was also studied. The treatments were conducted under aerobic conditions in 60-L reactors for 35 days. Maturity indexes were determined, and continuous measurements of CH{sub 4}, N{sub 2}O, and NH{sub 3} were taken. Phosphogypsum and superphosphate had no negative effects on compost maturity, although superphosphate inhibited the temperature rise in the first few days. The addition of phosphogypsum and superphosphate drastically reduced CH{sub 4} emissions (by 85.8% and 80.5%, respectively) and decreased NH{sub 3} emissions (by 23.5% and 18.9%, respectively). However, a slight increase in N{sub 2}O emissions (by 3.2% and 14.8%, respectively) was observed. Composting with phosphogypsum and superphosphate reduced total greenhouse gas emissions by 17.4% and 7.3% respectively.« less

Biocompatibility and in vivo degradation of chitosan based hydrogels as potential drug carrier.

PubMed

Su, Feng; Wang, Yuandou; Liu, Xue; Shen, Xin; Zhang, Xingjian; Xing, Quansheng; Wang, Lihong; Chen, Yangsheng

2018-06-07

Carboxymethyl chitosan-graft-polylactide (CMCS-PLA) and carboxymethyl chitosan (CMCS) hydrogels were prepared by using 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide (EDC/NHS) as crosslinking agent and catalyst at room temperature. The biocompatibility of the hydrogels was evaluated with the aim of assessing their potential as drug carrier. Various aspects of biocompatibility were considered, including MTT assay, agar diffusion test, release of lactate dehydrogenase (LDH), hemolytic test, plasma recalcification time (PRT), and dynamic clotting time. MTT assay showed that the cytotoxicity level of both hydrogels to L-929 cells was 0 or 1. The LDH release of CMCS and CMCS-PLA was 26 and 29%, respectively, which is slightly higher than that of the negative control (21%) and much lower than that of the negative control (87%). The hemolysis ratio of CMCS and CMCS-PLA was 1.4 and 1.7%, respectively, suggesting outstanding anti-hemolysis properties of both materials. The PRT value of CMCS and CMCS-PLA was higher by 77 and 99% than the value of the positive control. All the results revealed that the hydrogels present good cytocompatibility and hemocompatibility in vitro. In vivo degradation and tissue compatibility were evaluated by subcutaneous injection in the dorsal area of rats. CMCS and CMCS-PLA hydrogels were completely degraded and the inflammatory response also completely disappeared around hydrogels after 19 days in vivo. It is thus concluded that hydrogels formed of CMCS and CMCS-PLA with outstanding biocompatibility are promising as potential drug carrier.

Adsorption and release of ofloxacin from acid- and heat-treated halloysite.

PubMed

Wang, Qin; Zhang, Junping; Zheng, Yue; Wang, Aiqin

2014-01-01

Halloysite nanotube is an ideal vehicle of the controlled release of drugs. In this study, we systematically investigated the effects of acid- and heat-treatments on the physicochemical properties, structure and morphology of halloysite by XRD, FTIR, SEM and TEM. Afterwards, the adsorption and in vitro release properties of halloysite for cationic ofloxacin (OFL) were evaluated. The results indicate that HCl treatment has no influence on the crystal structure of halloysite, whereas it becomes amorphous after calcined at temperature higher than 500 °C. Both acid- and heat-treatments have no evident influence on the tubular structure of halloysite. OFL was adsorbed onto halloysite via electrostatic interaction between protonated OFL and negative halloysite surface, cation exchange as well as electrostatic interaction between the OFL-Al(3+) complexes and the negative halloysite surface. Acid-treatment facilitates the release of the adsorbed OFL compared with the natural halloysite in spite of a slight decrease of adsorption capacity. However, heat-treatment results in a sharp decrease of adsorption capacity for OFL owning to the OFL-promoted dissolution of aluminum and the disappearance of the porous structure. Although heat-treatment also facilitates release of the adsorbed OFL, the amount of OFL released is in fact less than the natural halloysite owing to the very low adsorption capacity. Thus, acid-activation is an effective protocol to improve the adsorption and release of halloysite for cationic drug molecules. Copyright © 2013 Elsevier B.V. All rights reserved.

Pressure-dependence of the phase transitions and thermal expansion in zirconium and hafnium pyrovanadate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gallington, Leighanne C.; Hester, Brett R.; Kaplan, Benjamin S.

Low or negative thermal expansion (NTE) has been previously observed in members of the ZrP 2O 7 family at temperatures higher than their order-disorder phase transitions. The thermoelastic properties and phase behavior of the low temperature superstructure and high temperature negative thermal expansion phases of ZrV 2O 7 and HfV 2O 7 were explored via in situ variable temperature/pressure powder x-ray diffraction measurements. The phase transition temperatures of ZrV 2O 7 and HfV 2O 7 exhibited a very strong dependence on pressure (~700 K GPa), with moderate compression suppressing the formation of their NTE phases below 513 K. Compression alsomore » reduced the magnitude of the coefficients of thermal expansion in both the positive and negative thermal expansion phases. Additionally, the high temperature NTE phase of ZrV 2O 7 was found to be twice as stiff as the low temperature positive thermal expansion superstructure (24 and 12 GPa respectively).« less

[Experience of integrated traditional Chinese and Western medicine in first case of imported Zika virus disease in China].

PubMed

Deng, Yichu; Zeng, Liping; Bao, Wen; Xu, Pinghua; Zhong, Gongrong

2016-02-01

Zika virus disease is an acute infectious disease caused by Zika virus transmitted through Aedes mosquitoes. To explore the therapeutic effect of integrated traditional Chinese and Western Medicine for Zika virus disease, the treatment process of the first imported case in China was reviewed. The first imported Zika virus disease in China was admitted to Ganxian People's Hospital in Jiangxi Province on February 6th, 2016, and the patient received isolation treatment for 9 days and cured later. The effect of antiviral treatments including Xiyanping injection was evaluated based on clinical diagnosis and treatment process of the patient. A 34-year old male patient was admitted with chief complaint of fever for 9 days, orbital pain and itching rash for 4 days on February 6th, 2016. (1) Epidemiological characteristics: the patient was bitted by mosquitoes during his business trip in Venezuela since January 1st, where Zika virus disease was spreading. On January 20th he had dizziness without fever, and the symptom disappeared after taking medicines without details. Paroxysmal dizziness, chills and mild fever without myalgia was experienced on January 28th. On February 3rd small red rash appeared in the neck, spreading to anterior part of chest, limbs and trunk, and the fever, fatigue, nausea was continued, and a new symptom of paroxysmal pain in back of ears and orbits appeared, during which he had not go to hospital. The symptoms relieved on February 4th. He returned to Ganxian County on February 5th, he had yellow stool 3 times with normal temperature, without abdominal pain, and red rash still appeared in the neck. He went to Ganxian People's Hospital on February 6th, 2016. (2) Clinical manifestation: the vital signs showed a temperature of 36.8?centigrade, a pulse rate of 80 bpm, a respiratory rate of 20 bpm, and a blood pressure of 110/70 mmHg (1 mmHg = 0.133 kPa). It was showed by physical examination that red rash appeared in the neck, and no superficial enlarged lymph nodes were found. Bilateral conjunctival congestion was obvious, physiological reflex existed and pathological reflex was not found. (3) Auxiliary lab test and examination: no abnormal finding were revealed throughout examination and laboratory tests, including routine blood test, liver function, renal function, serum myocardial enzyme, electrolyte, blood sugar, C-reactive protein (CRP), troponin I (TnI), and procalcitonin (PCT), except slight prolongation in activated partial thromboplastin time (APTT, 38.6 s) on February 6th; and slightly dense shadow in left lung in lung CT scan, considering inflammatory changes and slight emphysema (especially in the left lower lung) as well as bilateral renal calculus on February 8th. No significant abnormalities were found in electrocardiogram and B ultrasound test of liver, spleen, and pancreas. (4) Virus confirmation: Zika virus nucleic acid was positive reported by Jiangxi Province Center for Disease Control and Prevention (CDC) on February 7th and Chinese CDC on February 9th, respectively, though Dengue virus were negative reported by Ganzhou CDC on February 6th. Right after the first diagnosis, anyone who had been in close contact with the patient received medical monitoring. (5)Treatment process: on February 6th, symptomatic treatment was prescribed since admitted into the infectious isolation wards and daily intravenous drip of Xiyanping injection 250 mg was prescribed for antiviral therapy. On February 7th, the patient had no fever, with occasional chills, neck rash was disappeared, orbital pain relieved and bilateral conjunctival hyperemia range was paler and narrowed, and his condition improved. Ibuprofen was administered for defervesce 3 times a day when his temperature reached to 37.5?centigrade at 16:00. On February 8th, the patient had no fever, times of chills was significantly reduced, without myalgia and rash, orbital pain and conjunctival hyperemia further recovered. On February 9th, bilateral eyes slightly tingling, mild conjunctival congestion, no fever chills or other discomfort was found. The chloramphenicol eye drops was prescribed for relieving sting pain with conjunctival congestion twice a day as recombinant human interferon alpha eye drops was out of store. The patient was comfortable from February 11th to February 13th. Blood and urine test for Zika were reported negative by the Chinese CDC and Jiangxi Province CDC. Because all the discharge criteria were satisfied, the patient was discharged on February 14th. At present, there is no specific effective drug to prevent and treat Zika virus disease effectually. After receiving symptomatic treatment and antiviral treatments including Xiyanping injection, the patient's symptoms were relieved. Zika virus nucleic acid in blood and urine was negative. The patient was discharged. Combination of traditional Chinese medicine and Western medicine maybe a good method to prevent and treat Zika virus disease.

Thermal effects on fish ecology

USGS Publications Warehouse

Coutant, Charles C.

1976-01-01

Of all the environmental factors that influence aquatic organisms, temperature is the most all-pervasive. There is always an environmental temperature while other factors may or may not be present to exert their effects. Fish are, for all practical purposes, thermal conformers, or obligate poikilotherms. That is, they are able to exert little significant influence on maintaining a certain body temperature by specialized metabolic or behavioral means. Their body temperature thus fluctuates nearly in concert with the temperature of their aquatic medium (although particularly large, actively-moving fish such as tuna have deep muscle temperatures slightly higher than the water). Intimate contact at the gills of body fluids with the outside water and the high specific heat of water provide a very efficient heat exchanger that insures this near identity of internal and external temperatures.

‘Fire hardening’ spear wood does slightly harden it, but makes it much weaker and more brittle

PubMed Central

Chan, Tak Lok

2016-01-01

It is usually assumed that ‘fire hardening’ the tips of spears, as practised by hunter–gatherers and early Homo spp., makes them harder and better suited for hunting. This suggestion was tested by subjecting coppiced poles of hazel to a fire-hardening process and comparing their mechanical properties to those of naturally seasoned poles. A Shore D hardness test showed that fire treatment slightly increased the hardness of the wood, but flexural and impact tests showed that it reduced the strength and work of fracture by 30% and 36%, respectively. These results suggest that though potentially slightly sharper and more durable, fire-hardened tips would actually be more likely to break off when used, as may have been the case with the earliest known wooden tool, the Clacton spear. Fire might first have been used to help sharpen the tips of spears, and fire-hardening would have been a mostly negative side effect, not its primary purpose. PMID:27194289

Giant Negative Electrocaloric Effect in (Pb,La)(Zr,Sn,Ti)O3 Antiferroelectrics Near Room Temperature.

PubMed

Zhuo, Fangping; Li, Qiang; Gao, Jinghan; Ji, Yongjie; Yan, Qingfeng; Zhang, Yiling; Wu, Hong-Hui; Xi, Xiao-Qing; Chu, Xiangcheng; Cao, Wenwu

2018-04-11

(Pb 0.97 La 0.02 )(Zr x Sn 0.94- x Ti 0.06 )O 3 (PLZST) antiferroelectric ceramics with x = 0.75-0.90 have been fabricated and found to be a novel electrocaloric material system with a giant negative electrocaloric effect (Δ T = -11.5 K) and a large electrocaloric strength (|Δ T/Δ E| = 0.105 K cm kV -1 ) near room temperature. Additionally, the PLZST antiferroelectric ceramic also exhibits a large positive electrocaloric effect around the Curie temperature. The giant negative effect and the coexistence of both positive and negative electrocaloric effects in one material indicate a promising possibility to develop mid- to large-scale solid-state cooling devices with high efficiency.

Suppression of electron temperature gradient turbulence via negative magnetic shear in NSTX.

PubMed

Yuh, H Y; Kaye, S M; Levinton, F M; Mazzucato, E; Mikkelsen, D R; Smith, D R; Bell, R E; Hosea, J C; LeBlanc, B P; Peterson, J L; Park, H K; Lee, W

2011-02-04

Negative magnetic shear is found to suppress electron turbulence and improve electron thermal transport for plasmas in the National Spherical Torus Experiment (NSTX). Sufficiently negative magnetic shear results in a transition out of a stiff profile regime. Density fluctuation measurements from high-k microwave scattering are verified to be the electron temperature gradient (ETG) mode by matching measured rest frequency and linear growth rate to gyrokinetic calculations. Fluctuation suppression under negligible E×B shear conditions confirm that negative magnetic shear alone is sufficient for ETG suppression. Measured electron temperature gradients can significantly exceed ETG critical gradients with ETG mode activity reduced to intermittent bursts, while electron thermal diffusivity improves to below 0.1 electron gyro-Bohms.

Petunia × hybrida floral scent production is negatively affected by high-temperature growth conditions.

PubMed

Cna'ani, Alon; Mühlemann, Joelle K; Ravid, Jasmin; Masci, Tania; Klempien, Antje; Nguyen, Thuong T H; Dudareva, Natalia; Pichersky, Eran; Vainstein, Alexander

2015-07-01

Increasing temperatures due to changing global climate are interfering with plant-pollinator mutualism, an interaction facilitated mainly by floral colour and scent. Gas chromatography-mass spectroscopy analyses revealed that increasing ambient temperature leads to a decrease in phenylpropanoid-based floral scent production in two Petunia × hybrida varieties, P720 and Blue Spark, acclimated at 22/16 or 28/22 °C (day/night). This decrease could be attributed to down-regulation of scent-related structural gene expression from both phenylpropanoid and shikimate pathways, and up-regulation of a negative regulator of scent production, emission of benzenoids V (EOBV). To test whether the negative effect of increased temperature on scent production can be reduced in flowers with enhanced metabolic flow in the phenylpropanoid pathway, we analysed floral volatile production by transgenic 'Blue Spark' plants overexpressing CaMV 35S-driven Arabidopsis thaliana production of anthocyanin pigments 1 (PAP1) under elevated versus standard temperature conditions. Flowers of 35S:PAP1 transgenic plants produced the same or even higher levels of volatiles when exposed to a long-term high-temperature regime. This phenotype was also evident when analysing relevant gene expression as inferred from sequencing the transcriptome of 35S:PAP1 transgenic flowers under the two temperature regimes. Thus, up-regulation of transcription might negate the adverse effects of temperature on scent production. © 2014 John Wiley & Sons Ltd.

The effect of different temperature profiles upon the length and crystallinity of vertically-aligned multi-walled carbon nanotubes.

PubMed

Yun, Jongju; Lee, Cheesung; Zheng, Qing; Baik, Seunghyun

2012-08-01

We synthesized vertically-aligned multi-walled carbon nanotubes with an inner diameter of 1.6-7.5 nm and stack height of 80-28600 microm by chemical vapor deposition. The effects of synthesis conditions such as substrate position in the tube furnace, maximum temperature, temperature increasing rate and synthesis duration on the structure of nanotubes were investigated. It was found that slightly faster temperature increase rate resulted in significantly longer length, larger diameter and more defects of nanotubes. Structural parameters such as inner, outer diameters, wall thickness and defects were investigated using transmission electron microscopy and Raman spectroscopy.

Temperature dependence of the ozone obsorption spectrum over the wavelength range 410 to 760 nm

NASA Technical Reports Server (NTRS)

Burkholder, James B.; Talukdar, Ranajit K.

1994-01-01

The ozone, O3, absorption cross sections between 410 and 760 nm, the Chappuis band, were measured at 220, 240, 260, and 280 K relative to that at room temperature using a diode array spectrometer. The measured cross sections varied very slightly, less than 1%, with decreasing temperature between 550 and 660 nm, near the peak of the Chappuis band. At wavelengths away from the peak, the absorption cross sections decreased with decreasing temperature; e.g., about 40% at 420 nm between 298 and 220 K. These results are compared with previous measurements and the impact on atmospheric measurements are discussed.

Magneto-structural correlation in Co0.8Cu0.2Cr2O4 cubic spinel

NASA Astrophysics Data System (ADS)

Kumar, Ram; Rayaprol, S.; Siruguri, V.; Xiao, Y.; Ji, W.; Pal, D.

2018-05-01

Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magneto-structural phase transitions in 20% Cu substituted multiferroic CoCr2O4 spinel. The Jahn-Teller active Cu2+ ion in the tetrahedral A-site of the spinel configuration induces the Jahn-Teller distortion slightly above the Néel temperature. In this compound, we observe a Jahn-Teller distortion of the crystal structure at 90 K. It was further observed that the high temperature cubic (Fd 3 ‾ m) structure coexists with the low temperature orthorhombic (Fddd) structure till the lowest temperature of measurement.

Thermodynamic Calculations of Hydrogen-Oxygen Detonation Parameters for Various Initial Pressures

NASA Technical Reports Server (NTRS)

Bollinger, Loren E.; Edse, Rudolph

1961-01-01

Composition, temperature, pressure and density behind a stable detonation wave and its propagation rate have been calculated for seven hydrogen-oxygen mixture at 1, 5, 25 and 100 atm initial pressure, and at an initial temperature of 40C. For stoichiometric mixtures that calculations also include an initial temperature of 200C. According to these calculations the detonation velocities of hydrogen-oxygen mixtures increase with increasing initial pressure, but decrease slightly when the initial temperature is raised from 40 to 200 C. The calculated detonation velocities agree satisfactorily with values determined experimentally. These values will be published in the near future.

Temperature tolerance of young-of-the-year cisco, Coregonus artedii

USGS Publications Warehouse

Edsall, Thomas A.; Colby, Peter J.

1970-01-01

Young-of-the-year ciscoes (Coregonus artedii) acclimated to 2, 5, 10, 20 and 25 C and tested for tolerance to high and low temperatures provide the first detailed description of the thermal tolerance of coregonids in North America. The upper ultimate lethal temperature of the young ciscoes was 26 C (6 C higher than the maximum sustained temperature tolerated by adult ciscoes in nature) and the ultimate lower lethal temperature approached 0 C (near that commonly tolerated in nature by adult ciscoes). The temperature of 26 C is slightly higher than the lowest ultimate upper lethal temperature recorded for North American freshwater fishes; however, published information on the depth distributions of fishes in the Great Lakes suggests that some of the other coregonids may be less tolerant of high temperatures than the cisco.

Compression of rehydratable vegetables and cereals

NASA Technical Reports Server (NTRS)

Burns, E. E.

1978-01-01

Characteristics of freeze-dried compressed carrots, such as rehydration, volatile retention, and texture, were studied by relating histological changes to textural quality evaluation, and by determining the effects of storage temperature on freeze-dried compressed carrot bars. Results show that samples compressed with a high moisture content undergo only slight structural damage and rehydrate quickly. Cellular disruption as a result of compression at low moisture levels was the main reason for rehydration and texture differences. Products prepared from carrot cubes having 48% moisture compared favorably with a freshly cooked product in cohesiveness and elasticity, but were found slightly harder and more chewy.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The project was successful in confirming the suitability of shredded coconut husks in potting mix and the acceptability of untreated geothermal steam to pasteurize the mix. The pots were exposed to the steam; the average media temperature was maintained at 160 F for 30 min. The pH levels, which were slightly elevated in virgin media, rose only slightly (< 0.5) after steaming. Salt levels doubled (still safe). Mg solubility increased but not to toxic levels. Test plantings showed no significant differences after 8 months, indicating that coconut fiber can be pasteurized and used to replace imported peat moss. 6 refs,more » 4 tabs.« less

The Impact of Leisure-Time Television on School Learning: A Research Synthesis.

ERIC Educational Resources Information Center

Williams, Patricia A.; And Others

1982-01-01

To integrate empirical findings concerning the impact of leisure time television viewing on student achievement in grades K-12, 274 correlations were assembled from 23 studies. The effects were slightly positive for up to 10 hours of viewing a week, but beyond 10 hours the effects are negative and increasingly more deleterious. (Author/BW)

Micropepsia pineolensis gen. nov., sp. nov., a mildly acidophilic alphaproteobacterium isolated from a poor fen, and proposal of Micropepsiaceae fam. nov. within Micropepsiales ord. nov.

USDA-ARS?s Scientific Manuscript database

A novel, obligately anaerobic, acid-tolerant, fermentative alphaproteobacterium, designated strain CS4T, was isolated from an acidic, oligotrophic (nutrient-poor) poor fen located near Pineola, NC, USA. Cultures contained Gram-negative, slightly curved, non-motile, non-spore forming, non-prosthecat...

"Juntos Pero No Revueltos": Microaggressions and Language in the Mathematics Education of Non-Dominant Latinas/os

ERIC Educational Resources Information Center

LópezLeiva, Carlos A.; Khisty, Lena Licón

2014-01-01

In this paper, we discuss the characteristics of microaggressions based on minority language(s) as a form of discriminatory practice against non-dominant students in the mathematics context. Microaggressions are subtle, brief, and commonplace verbal, behavioral, or visual negative slights or insults toward people of color. We extend the concept of…

An analytic formula for heating due to ozone absorption

NASA Technical Reports Server (NTRS)

Lindzen, R. S.; Will, D. I.

1972-01-01

An attempt was made to devise a simple expression or formula to describe radiative heating in the atmosphere by ozone absorption. Such absorption occurs in the Hartley, Huggins, and Chappuis bands and is only slightly temperature and pressure dependent.

Chemistry of the Burning Surface

DTIC Science & Technology

1993-10-12

simulated combustion and explo- the temperature is nonuniform along the filament length sion events. SUFKS V~V 100 IWAQ10 0 t 1 10 CABRAM OIRV...temperature. Ilee filament is slightly altered by the sample, the power results clearly show that it is the nonuniform temper%- dissipation is essentially...sample explosive and propellant material, was chosen because it is presnt on the filamenL Liquefaction of AMMO is illustrates the laIr amount of chemical

High Temperature Electronics Technology

DTIC Science & Technology

1984-05-01

the hidrogen in the gold layer apparently was successful in suppressing the gold crystal growth. Since tape tests removed almost none of the...with others in the industry is that gold adhz-#s well to Ti-W. This refers to the undoped (no nitrogen stuffing) variety not the Ti-W diffusion...passivaiion film. The keys to v’. success were the production of a dense, slightly compreveive film, deposited at a temperature less than 330* C and the

Gas-film coefficients for the volatilization of ethylene dibromide from water

USGS Publications Warehouse

Rathbun, R.E.; Tal, D.Y.

1986-01-01

Gas-film coefficients for the volatilization of ethylene dibromide (EDB) and water were determined in the laboratory as a function of wind speed and temperature. The ratio of the coefficients was independent of wind speed and increased slightly with temperature. Use of this ratio with an environmentally determined gas-film coefficient for the evaporation of water permits determination of the gas-film coefficient for the volatilization of EDB from environmental waters.

Electrical conductivity, thermopower and 57Fe Mössbauer spectroscopy of aegirine (NaFeSi2O6)

NASA Astrophysics Data System (ADS)

Schmidbauer, E.; Kunzmann, Th.

DC and AC electrical conductivities were measured on samples of two different crystals of the mineral aegirine (NaFeSi2O6) parallel (∥) and perpendicular (⊥) to the [001] direction of the clinopyroxene structure between 200 and 600 K. Impedance spectroscopy was applied (20 Hz-1 MHz) and the bulk DC conductivity σDC was determined by extrapolating AC data to zero frequency. In both directions, the log σDC - 1/T curves bend slightly. In the high- and low-temperature limits, differential activation energies were derived for measurements ∥ [001] of EA 0.45 and 0.35 eV, respectively, and the numbers ⊥ [001] are very similar. The value of σDC ∥ [001] with σDC(300 K) 2.0 × 10-6 Ω-1cm-1 is by a factor of 2-10 above that measured ⊥ [001], depending on temperature, which means anisotropic charge transport. Below 350 K, the AC conductivity σ'(ω) (ω/2π=frequency) is enhanced relative to σDC for both directions with an increasing difference for rising frequencies on lowering the temperature. An approximate power law for σ'(ω) is noted at higher frequencies and low temperatures with σ'(ω) ωs, which is frequently observed on amorphous and disordered semiconductors. Scaling of σ'(ω) data is possible with reference to σDC, which results in a quasi-universal curve for different temperatures. An attempt was made to discuss DC and AC results in the light of theoretical models of hopping charge transport and of a possible Fe2+ --> Fe3+ electron hopping mechanism. The thermopower Θ (Seebeck effect) in the temperature range 360 K < T < 770 K is negative in both directions. There is a linear Θ - 1/T relationship above 400 K with activation energy EΘ 0.030 eV ∥ [001] and 0.070 eV ⊥ [001]. 57Fe Mössbauer spectroscopy was applied to detect Fe2+ in addition to the dominating concentration of Fe3+.

Effects of Heat of Vaporization and Octane Sensitivity on Knock-Limited Spark Ignition Engine Performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ratcliff, Matthew A; Burton, Jonathan L; Sindler, Petr

Knock-limited loads for a set of surrogate gasolines all having nominal 100 research octane number (RON), approximately 11 octane sensitivity (S), and a heat of vaporization (HOV) range of 390 to 595 kJ/kg at 25 degrees C were investigated. A single-cylinder spark-ignition engine derived from a General Motors Ecotec direct injection (DI) engine was used to perform load sweeps at a fixed intake air temperature (IAT) of 50 degrees C, as well as knock-limited load measurements across a range of IATs up to 90 degrees C. Both DI and pre-vaporized fuel (supplied by a fuel injector mounted far upstream ofmore » the intake valves and heated intake runner walls) experiments were performed to separate the chemical and thermal effects of the fuels' knock resistance. The DI load sweeps at 50 degrees C intake air temperature showed no effect of HOV on the knock-limited performance. The data suggest that HOV acts as a thermal contributor to S under the conditions studied. Measurement of knock-limited loads from the IAT sweeps for DI at late combustion phasing showed that a 40 vol% ethanol (E40) blend provided additional knock resistance at the highest temperatures, compared to a 20 vol% ethanol blend and hydrocarbon fuel with similar RON and S. Using the pre-vaporized fuel system, all the high S fuels produced nearly identical knock-limited loads at each temperature across the range of IATs studied. For these fuels RON ranged from 99.2 to 101.1 and S ranged from 9.4 to 12.2, with E40 having the lowest RON and highest S. The higher knock-limited loads for E40 at the highest IATs examined were consistent with the slightly higher S for this fuel, and the lower engine operating condition K values arising from use of this fuel. The study highlights how fuel HOV can affect the temperature at intake valve closing, and consequently the pressure-temperature history of the end gas leading to more negative values of K, thereby enhancing the effect of S on knock resistance.« less

Characterization of Desulfovibrio salinus sp. nov., a slightly halophilic sulfate-reducing bacterium isolated from a saline lake in Tunisia.

PubMed

Ben Ali Gam, Zouhaier; Thioye, Abdoulaye; Cayol, Jean-Luc; Joseph, Manon; Fauque, Guy; Labat, Marc

2018-03-01

A novel slightly halophilic sulfate-reducing bacterium, designated strain P1BSR T , was isolated from water of a saline lake in Tunisia. Strain P1BSR T had motile (single polar flagellum), Gram-negative, rod-shaped, non-spore-forming cells, occurring singly or in pairs. Strain P1BSR T grew at temperatures between 15 and 45 °C (optimum 40 °C), and in a pH range between 6 and 8.5 (optimum pH 6.7). The strain required NaCl for growth (1 % w/v), and tolerated high NaCl concentration (up to 12 % w/v) with an optimum of 3 % (w/v). Sulfate, thiosulfate and sulfite served as terminal electron acceptors, but not elemental sulfur, fumarate, nitrate and nitrite. Strain P1BSR T utilized lactate, pyruvate, formate, d-fructose and glycerol as carbon and energy sources. The main cellular fatty acid was C16 : 0 (50.8 %). The genomic DNA G+C content was 47.7 mol%. Phylogenetic analysis of 16S rRNA gene sequence similarity indicated that strain P1BSR T was affiliated to the genus Desulfovibrio, with the type strains Desulfovibrio salexigens (96.51 %), Desulfovibrio zosterae (95.68 %), Desulfovibrio hydrothermalis (94.81 %) and Desulfovibrio ferrireducens (94.73 %) as its closest phylogenetic relatives. On the basis of genotypic, phenotypic and phylogenetic characteristics, it is proposed to assign strain P1BSR T to a novel species of the genus Desulfovibrio, Desulfovibrio salinus sp. nov. The type strain is P1BSR T (=DSM 101510 T =JCM 31065 T ).

Combustion Characteristics in a Non-Premixed Cool-Flame Regime of n-Heptane in Microgravity

NASA Technical Reports Server (NTRS)

Takahashi, Fumiaki; Katta, Viswanath R.; Hicks, Michael C.

2015-01-01

A series of distinct phenomena have recently been observed in single-fuel-droplet combustion tests performed on the International Space Station (ISS). This study attempts to simulate the observed flame behavior numerically using a gaseous n-heptane fuel source in zero gravity and a time-dependent axisymmetric (2D) code, which includes a detailed reaction mechanism (127 species and 1130 reactions), diffusive transport, and a radiation model (for CH4, CO, CO2, H2O, and soot). The calculated combustion characteristics depend strongly on the air velocity around the fuel source. In a near-quiescent air environment (< or = 2 mm/s), with a sufficiently large fuel injection velocity (1 cm/s), a growing spherical diffusion flame extinguishes at ˜1200 K due to radiative heat losses. This is typically followed by a transition to the low-temperature (cool-flame) regime with a reaction zone (at ˜700 K) in close proximity to the fuel source. The 'cool flame' regime is formed due to the negative temperature coefficient in the low-temperature chemistry. After a relatively long period (˜18 s) of the cool flame regime, a flash re-ignition occurs, associated with flame-edge propagation and subsequent extinction of the re-ignited flame. In a low-speed (˜3 mm/s) airstream (which simulates the slight droplet movement), the diffusion flame is enhanced upstream and experiences a local extinction downstream at ˜1200 K, followed by steady flame pulsations (˜0.4 Hz). At higher air velocities (4-10 mm/s), the locally extinguished flame becomes steady state. The present axisymmetric computational approach helps in revealing the non-premixed 'cool flame' structure and 2D flame-flow interactions observed in recent microgravity droplet combustion experiments.

Gelled oil particles: a new approach to encapsulate a hydrophobic metallophthalocyanine.

PubMed

Siqueira-Moura, Marigilson P; Franceschi-Messant, Sophie; Blanzat, Muriel; Ré, Maria Inês; Perez, Emile; Rico-Lattes, Isabelle; Lattes, Armand; Tedesco, Antonio C

2013-07-01

Chloroaluminum phthalocyanine (ClAlPc) is a promising sensitizer molecule for photodynamic therapy, but its hydrophobicity makes it difficult to formulate. In this study, we have efficiently encapsulated ClAlPc into gelled soybean oil particles dispersed in water. 12-Hydroxystearic acid (HSA) and polyethyleneimine (PEI) were the gelling and stabilizing agents, respectively. The preparation process involved hot emulsification above the gelation temperature (Tgel), followed by cooling to room temperature, which gave a colloidal dispersion of gelled particles of oil in aqueous medium. The gelled particles containing ClAlPc had a medium diameter of 280 nm, homogeneous size distribution (polydispersity index ≈0.3) and large positive zeta potential (about +50 mV) and showed a spherical morphology. The gelled oil particle formulations exhibited good physical stability over a 6-month period. ClAlPc interfered with the HSA self-assembly only slightly, and decreased the gelation temperature to a small extent; however it did not affect gelation process of the oil droplets. The amounts of PEI and HSA employed during the preparation allowed us to control particle size and the dispersion stability, a phenomenon that results from complex electrostatic interactions between the positively charged PEI and the negatively charged HSA fibers present on the gelled particles surface. In summary, by using the right ClAlPc, HSA, and PEI proportions, we prepared very stable dispersions of gelled soybean oil particles with excellent ClAlPc encapsulation efficiency. The obtained colloidal formulation of gelled oil particles loaded with ClAlPc shall be very useful for photodynamic therapy protocols. Crown Copyright © 2013. Published by Elsevier Inc. All rights reserved.

Role of ground ice dynamics and ecological feedbacks in recent ice wedge degradation and stabilization

USGS Publications Warehouse

Mark Torre Jorgenson,; Mikhail Kanevskiy,; Yuri Shur,; Natalia Moskalenko,; Dana Brown,; Wickland, Kimberly P.; Striegl, Robert G.; Koch, Joshua C.

2015-01-01

Ground ice is abundant in the upper permafrost throughout the Arctic and fundamentally affects terrain responses to climate warming. Ice wedges, which form near the surface and are the dominant type of massive ice in the Arctic, are particularly vulnerable to warming. Yet processes controlling ice wedge degradation and stabilization are poorly understood. Here we quantified ice wedge volume and degradation rates, compared ground ice characteristics and thermal regimes across a sequence of five degradation and stabilization stages and evaluated biophysical feedbacks controlling permafrost stability near Prudhoe Bay, Alaska. Mean ice wedge volume in the top 3 m of permafrost was 21%. Imagery from 1949 to 2012 showed thermokarst extent (area of water-filled troughs) was relatively small from 1949 (0.9%) to 1988 (1.5%), abruptly increased by 2004 (6.3%) and increased slightly by 2012 (7.5%). Mean annual surface temperatures varied by 4.9°C among degradation and stabilization stages and by 9.9°C from polygon center to deep lake bottom. Mean thicknesses of the active layer, ice-poor transient layer, ice-rich intermediate layer, thermokarst cave ice, and wedge ice varied substantially among stages. In early stages, thaw settlement caused water to impound in thermokarst troughs, creating positive feedbacks that increased net radiation, soil heat flux, and soil temperatures. Plant growth and organic matter accumulation in the degraded troughs provided negative feedbacks that allowed ground ice to aggrade and heave the surface, thus reducing surface water depth and soil temperatures in later stages. The ground ice dynamics and ecological feedbacks greatly complicate efforts to assess permafrost responses to climate change.

Role of ground ice dynamics and ecological feedbacks in recent ice wedge degradation and stabilization

NASA Astrophysics Data System (ADS)

Jorgenson, M. T.; Kanevskiy, M.; Shur, Y.; Moskalenko, N.; Brown, D. R. N.; Wickland, K.; Striegl, R.; Koch, J.

2015-11-01

Ground ice is abundant in the upper permafrost throughout the Arctic and fundamentally affects terrain responses to climate warming. Ice wedges, which form near the surface and are the dominant type of massive ice in the Arctic, are particularly vulnerable to warming. Yet processes controlling ice wedge degradation and stabilization are poorly understood. Here we quantified ice wedge volume and degradation rates, compared ground ice characteristics and thermal regimes across a sequence of five degradation and stabilization stages and evaluated biophysical feedbacks controlling permafrost stability near Prudhoe Bay, Alaska. Mean ice wedge volume in the top 3 m of permafrost was 21%. Imagery from 1949 to 2012 showed thermokarst extent (area of water-filled troughs) was relatively small from 1949 (0.9%) to 1988 (1.5%), abruptly increased by 2004 (6.3%) and increased slightly by 2012 (7.5%). Mean annual surface temperatures varied by 4.9°C among degradation and stabilization stages and by 9.9°C from polygon center to deep lake bottom. Mean thicknesses of the active layer, ice-poor transient layer, ice-rich intermediate layer, thermokarst cave ice, and wedge ice varied substantially among stages. In early stages, thaw settlement caused water to impound in thermokarst troughs, creating positive feedbacks that increased net radiation, soil heat flux, and soil temperatures. Plant growth and organic matter accumulation in the degraded troughs provided negative feedbacks that allowed ground ice to aggrade and heave the surface, thus reducing surface water depth and soil temperatures in later stages. The ground ice dynamics and ecological feedbacks greatly complicate efforts to assess permafrost responses to climate change.

Ceramic tube seals cut heat loss, achieve six month payback

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-11-01

The methane reformer at the Celanese Chemical Company's Bishop, TX plant operates at approximately 1900/sup 0/F. The reformer has 32 tubes (9'' diameter) that pass through the firebox. Openings around the tubes measure 11'' in diameter to accommodate horizontal and vertical thermal expansion and movement as well as to facilitate tube removal. The gaps around the tubes permitted cool air to be drawn into the firebox (caused by slight negative pressure) and also allowed radiant heat to escape causing the reformer to operate at a lower than desired level of thermal efficiency. Celanese contracted to retrofit the old rigid firebrickmore » roof in the methane reformer with a 10'' thick ceramic fiber module lining. The gaps around the tubes were sealed by using a special tube seal made from Nextel woven ceramic fiber fabric, a 1984 CHEMICAL PROCESSING Vaaler Award winner (Mid-November 1984, p.52). The Nextel fabric used in this application is a heat resistant textile that has a continuous use temperature of 2200/sup 0/F - well above the 1900/sup 0/F operating temperature of the reformer. The tube seals have been working exactly as intended, verified by observation through inspection ports. Temperatures in the penthouse area above the roof dropped from 240/sup 0/F to 150/sup 0/F. The reduction in heat losses has been attributed to the elimination of the gaps around each tube by the seals and to the improved K-factor of the ceramic module lining. The tube seals have paid for themselves within six months of installation. At that time, the seal boots were inspected and showed no signs of wear. With these results, the improved efficiency of the methane reformer promises to yield additional economic benefits.« less

Absence of magnetic ordering and field-induced phase diagram in the gadolinium aluminum garnet

NASA Astrophysics Data System (ADS)

Florea, O.; Lhotel, E.; Jacobsen, H.; Knee, C. S.; Deen, P. P.

2017-12-01

The robustness of spin liquids with respect to small perturbations, and the way magnetic frustration can be lifted by slight changes in the balance between competing magnetic interactions, remains a rich and open issue. We address this question through the study of the gadolinium aluminum garnet Gd3Al5O12 , a related compound to the extensively studied Gd3Ga5O12 . We report on its magnetic properties at very low temperatures. We show that despite a freezing at about 300 mK, no magnetic transition is observed, suggesting the presence of a spin-liquid state down to the lowest temperatures, similarly to Gd3Ga5O12 , in spite of a larger ratio between exchange and dipolar interactions. Finally, the phase diagram as a function of field and temperature is strongly reminiscent of the one reported in Gd3Ga5O12 . This study reveals the robust nature of the spin-liquid phase for Gd ions on the garnet lattice, in stark contrast to Gd ions on the pyrochlore lattice for which a slight perturbation drives the compound into a range of magnetically ordered states.

Negative differential resistance in GaN tunneling hot electron transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Zhichao; Nath, Digbijoy; Rajan, Siddharth

Room temperature negative differential resistance is demonstrated in a unipolar GaN-based tunneling hot electron transistor. Such a device employs tunnel-injected electrons to vary the electron energy and change the fraction of reflected electrons, and shows repeatable negative differential resistance with a peak to valley current ratio of 7.2. The device was stable when biased in the negative resistance regime and tunable by changing collector bias. Good repeatability and double-sweep characteristics at room temperature show the potential of such device for high frequency oscillators based on quasi-ballistic transport.

Effect of sodium and calcium ingestion on thermoregulation during exercise in man

NASA Technical Reports Server (NTRS)

Greenleaf, J. E.; Brock, P. J.; Morse, J. T.; Van Beaumont, W.; Montgomery, L. D.; Convertino, V. A.; Mangseth, G. R.

1978-01-01

The effects of hypertonic sodium and calcium ingestion on body temperature during exercise in cool and hot environments are investigated. Rectal and mean skin temperatures, sweat rates and arm and leg total blood flows were measured in men during periods of rest, submaximal exercise and recovery at temperatures of 26.5 C and 39.4 C after ingestion of NaCl and CaCl2 solutions. In both environments, higher rectal temperatures are observed after hypertonic sodium ingestion, which is also associated with attenuated blood flow in the extremities, lower sweat rates and slightly higher skin temperature in the heat, indicating significant thermoregulatory responses. Hypertonic calcium and isotonic sodium cause no temperature change, although calcium caused a reduction of blood flow in the extremities.

Annual and Semi-Annual Temperature Oscillations in the Upper Mesosphere

NASA Technical Reports Server (NTRS)

Niciejewski, R. J.; Killeen, T. L.

1995-01-01

Fourier transform spectrometer observations of the mesosphere have been performed at the University of Michigan (latitude: 42.5 N) on a long term basis. A database of near infrared Meinel hydroxyl spectra has been accumulated from which rotational temperatures have been determined. Harmonic analysis of one-day averaged temperatures for the period 1992.0 to 1994.5 has shown a distinct annual and semi-annual variation. Subsequent fitting of a five term periodic function characterizing the annual and semi-annual temperature oscillations to the daily averaged temperatures was performed. The resultant mean temperature and the amplitudes and phases of the annual and semi-annual variations are shown to coincide with an emission height slightly above 85 km which is consistent with the mean rocket derived altitude for peak nocturnal hydroxyl emission.

Evolution of sensitivity to fosfomycin in bacteria isolated in 1973, 1974 and 1975 in the Servicio de Microbiologia y Epidemiologia of the 'Clinica Puerta de Hierro', Madrid.

PubMed

Dámaso, D; Moreno-López, M; Martínez-Beltrán, J

1977-01-01

The bacteriostatic activity of fosfomycin was studied in vitro against 1,243 clinical isolations of gram-positive cocci and 4,086 isolations of gram-negative bacilli that were obtained in 1973, 1974 and in the period from January to May of 1975. MIC was determined by the agar diffusion method, quantifying it by means of the standard curve that was worked out with the strain of E. coli NCTC 10,418. A slight increase in resistance was observed in the gram-positive cocci: 64 mug/ml were inhibitory for 63% of the 249 isolations obtained in 1973, 59.1% of the 716 isolations obtained in 1974, and 57.5% of the 278 isolations from 1975. A slight loss of sensitivity was also observed in the gram-negative bacilli: the aforementioned concentration of fosfomycin inhibited 36% of the 742 isolations from 1973, 33.6% of the 2,387 isolations from 1974 and 32.6% of the 957 isolations from 1975. 933 g of this antibiotic were consumed in our hospital in 1973, 4,203 g in 1974 and 957 g in 1975. The consumption rate per patient per year was 0.15, 0.72 and 0.20 g, respectively. In conclusion, although no change was observed in the sensitivity of some bacterial strains to fosfomycin, the overall study indicates a slight decrease in the sensitivity, although it does not apparently have any relationship to the consumption of fosfomycin in our hospital.

Agreement between allergen-specific IgE assays and ensuing immunotherapy recommendations from four commercial laboratories in the USA

PubMed Central

Plant, Jon D; Neradelik, Moni B; Polissar, Nayak L; Fadok, Valerie A; Scott, Brian A

2014-01-01

Background Canine allergen-specific IgE assays in the USA are not subjected to an independent laboratory reliability monitoring programme. Hypothesis/Objectives The aim of this study was to evaluate the agreement of diagnostic results and treatment recommendations of four serum IgE assays commercially available in the USA. Methods Replicate serum samples from 10 atopic dogs were submitted to each of four laboratories for allergen-specific IgE assays (ACTT®, VARL Liquid Gold, ALLERCEPT® and Greer® Aller-g-complete®). The interlaboratory agreement of standard, regional panels and ensuing treatment recommendations were analysed with the kappa statistic (κ) to account for agreement that might occur merely by chance. Six comparisons of pairs of laboratories and overall agreement among laboratories were analysed for ungrouped allergens (as tested) and also with allergens grouped according to reported cross-reactivity and taxonomy. Results The overall chance-corrected agreement of the positive/negative test results for ungrouped and grouped allergens was slight (κ = 0.14 and 0.13, respectively). Subset analysis of the laboratory pair with the highest level of diagnostic agreement (κ = 0.36) found slight agreement (κ = 0.13) for ungrouped plants and fungi, but substantial agreement (κ = 0.71) for ungrouped mites. The overall agreement of the treatment recommendations was slight (κ = 0.11). Altogether, 85.1% of ungrouped allergen treatment recommendations were unique to one laboratory or another. Conclusions and clinical importance Our study indicated that the choice of IgE assay may have a major influence on the positive/negative results and ensuing treatment recommendations. PMID:24461034

Astable Oscillator Circuits using Silicon-on-Insulator Timer Chip for Wide Range Temperature Sensing

NASA Technical Reports Server (NTRS)

Patterson, Richard L.; Culley, Dennis; Hammoud, Ahmad; Elbuluk, Malik

2008-01-01

Two astable oscillator circuits were constructed using a new silicon-on-insulator (SOI) 555 timer chip for potential use as a temperature sensor in harsh environments encompassing jet engine and space mission applications. The two circuits, which differed slightly in configuration, were evaluated between -190 and 200 C. The output of each circuit was made to produce a stream of rectangular pulses whose frequency was proportional to the sensed temperature. The preliminary results indicated that both circuits performed relatively well over the entire test temperature range. In addition, after the circuits were subjected to limited thermal cycling over the temperature range of -190 to 200 C, the performance of either circuit did not experience any significant change.

Physical origins of current and temperature controlled negative differential resistances in NbO 2

DOE PAGES

Kumar, Suhas; Wang, Ziwen; Davila, Noraica; ...

2017-09-22

Negative differential resistance behavior in oxide memristors, especially those using NbO 2, is gaining renewed interest because of its potential utility in neuromorphic computing. However, there has been a decade-long controversy over whether the negative differential resistance is caused by a relatively low-temperature non-linear transport mechanism or a high-temperature Mott transition. Resolving this issue will enable consistent and robust predictive modeling of this phenomenon for different applications. Here in this paper, we examine NbO 2 memristors that exhibit both a current-controlled and a temperature-controlled negative differential resistance. Through thermal and chemical spectromicroscopy and numerical simulations, we confirm that the formermore » is caused by a ~400 K non-linear-transport-driven instability and the latter is caused by the ~1000 K Mott metal-insulator transition, for which the thermal conductance counter-intuitively decreases in the metallic state relative to the insulating state.« less

Temperature induced phase transformations and negative electrocaloric effect in (Pb,La)(Zr,Sn,Ti)O3 antiferroelectric single crystal

NASA Astrophysics Data System (ADS)

Zhuo, Fangping; Li, Qiang; Yan, Qingfeng; Zhang, Yiling; Wu, Hong-Hui; Xi, Xiaoqing; Chu, Xiangcheng; Cao, Wenwu

2017-10-01

Temperature induced phase transitions and electrocaloric effect (ECE) of (Pb,La)(Zr,Sn,Ti)O3 (PLZST) single crystals have been comprehensively studied. Based on the in situ evolution of domain structures and dielectric properties of the PLZST crystals, the phase transitions during heating are in the sequence of orthorhombic antiferroelectric → rhombohedral ferroelectric → cubic paraelectric. Coexistence of the negative and positive ECEs has been achieved in the PLZST single crystals. A negative ECE value of -1.26 °C and enhanced electrocaloric strength of -0.21 K mm/kV near the Curie temperature have been obtained. A modified Landau model gives a satisfactory description of the experimentally observed unusual ECE. Moreover, a temperature-electric field phase diagram is also established based on theoretical analysis. Our results will help people understand better the electrocaloric family, particularly on the negative and/or positive effect in antiferroelectrics and ferroelectrics.

Physical origins of current and temperature controlled negative differential resistances in NbO 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Suhas; Wang, Ziwen; Davila, Noraica

Negative differential resistance behavior in oxide memristors, especially those using NbO 2, is gaining renewed interest because of its potential utility in neuromorphic computing. However, there has been a decade-long controversy over whether the negative differential resistance is caused by a relatively low-temperature non-linear transport mechanism or a high-temperature Mott transition. Resolving this issue will enable consistent and robust predictive modeling of this phenomenon for different applications. Here in this paper, we examine NbO 2 memristors that exhibit both a current-controlled and a temperature-controlled negative differential resistance. Through thermal and chemical spectromicroscopy and numerical simulations, we confirm that the formermore » is caused by a ~400 K non-linear-transport-driven instability and the latter is caused by the ~1000 K Mott metal-insulator transition, for which the thermal conductance counter-intuitively decreases in the metallic state relative to the insulating state.« less

Langevin equation in systems with also negative temperatures

NASA Astrophysics Data System (ADS)

Baldovin, Marco; Puglisi, Andrea; Vulpiani, Angelo

2018-04-01

We discuss how to derive a Langevin equation (LE) in non standard systems, i.e. when the kinetic part of the Hamiltonian is not the usual quadratic function. This generalization allows to consider also cases with negative absolute temperature. We first give some phenomenological arguments suggesting the shape of the viscous drift, replacing the usual linear viscous damping, and its relation with the diffusion coefficient modulating the white noise term. As a second step, we implement a procedure to reconstruct the drift and the diffusion term of the LE from the time-series of the momentum of a heavy particle embedded in a large Hamiltonian system. The results of our reconstruction are in good agreement with the phenomenological arguments. Applying the method to systems with negative temperature, we can observe that also in this case there is a suitable LE, obtained with a precise protocol, able to reproduce in a proper way the statistical features of the slow variables. In other words, even in this context, systems with negative temperature do not show any pathology.

Accumulation of dislocation loops in the α phase of Zr Excel alloy under heavy ion irradiation

NASA Astrophysics Data System (ADS)

Yu, Hongbing; Yao, Zhongwen; Idrees, Yasir; Zhang, He K.; Kirk, Mark A.; Daymond, Mark R.

2017-08-01

In-situ heavy ion irradiations were performed on the high Sn content Zr alloy 'Excel', measuring type dislocation loop accumulation up to irradiation damage doses of 10 dpa at a range of temperatures. The high content of Sn, which diffuses slowly, and the thin foil geometry of the sample provide a unique opportunity to study an extreme case where displacement cascades dominate the loop formation and evolution. The dynamic observation of dislocation loop evolution under irradiation at 200 °C reveals that type dislocation loops can form at very low dose (0.0025 dpa). The size of the dislocation loops increases slightly with irradiation damage dose. The mechanism controlling loop growth in this study is different from that in neutron irradiation; in this study, larger dislocation loops can condense directly from the interaction of displacement cascades and the high concentration of point defects in the matrix. The size of the dislocation loop is dependent on the point defect concentration in the matrix. A negative correlation between the irradiation temperature and the dislocation loop size was observed. A comparison between cascade dominated loop evolution (this study), diffusion dominated loop evolution (electron irradiation) and neutron irradiation suggests that heavy ion irradiation alone may not be enough to accurately reproduce neutron irradiation induced loop structures. An alternative method is proposed in this paper. The effects of Sn on the displacement cascades, defect yield, and the diffusion behavior of point defects are established.

Transverse anisotropic magnetoresistance effects in pseudo-single-crystal γ'-Fe4N thin films

NASA Astrophysics Data System (ADS)

Kabara, Kazuki; Tsunoda, Masakiyo; Kokado, Satoshi

2016-05-01

Transverse anisotropic magnetoresistance (AMR) effects, for which magnetization is rotated in an orthogonal plane to the current direction, were investigated at various temperatures, in order to clarify the structural transformation from a cubic to a tetragonal symmetry in a pseudo-single-crystal Fe4N film, which is predicted from the usual in-plane AMR measurements by the theory taking into account the spin-orbit interaction and crystal field splitting of 3d bands. According to a phenomenological theory of AMR, which derives only from the crystal symmetry, a cos 2θ component ( C2 tr ) exists in transverse AMR curves for a tetragonal system but does not for a cubic system. In the Fe4N film, the C2 tr shows a positive small value (0.12%) from 300 K to 50 K. However, the C2 t r increases to negative value below 50 K and reaches to -2% at 5 K. The drastic increasing of the C2 tr demonstrates the structural transformation from a cubic to a tetragonal symmetry below 50 K in the Fe4N film. In addition, the out-of-plane and in-plane lattice constants (c and a) were precisely determined with X-ray diffraction at room temperature using the Nelson-Riely function. As a result, the positive small C2 t r above 50 K is attributed to a slightly distorted Fe4N lattice (c/a = 1.002).

Seasonal exposure to drought and air warming affects soil Collembola and mites.

PubMed

Xu, Guo-Liang; Kuster, Thomas M; Günthardt-Goerg, Madeleine S; Dobbertin, Matthias; Li, Mai-He

2012-01-01

Global environmental changes affect not only the aboveground but also the belowground components of ecosystems. The effects of seasonal drought and air warming on the genus level richness of Collembola, and on the abundance and biomass of the community of Collembola and mites were studied in an acidic and a calcareous forest soil in a model oak-ecosystem experiment (the Querco experiment) at the Swiss Federal Research Institute WSL in Birmensdorf. The experiment included four climate treatments: control, drought with a 60% reduction in rainfall, air warming with a seasonal temperature increase of 1.4 °C, and air warming + drought. Soil water content was greatly reduced by drought. Soil surface temperature was slightly increased by both the air warming and the drought treatment. Soil mesofauna samples were taken at the end of the first experimental year. Drought was found to increase the abundance of the microarthropod fauna, but reduce the biomass of the community. The percentage of small mites (body length ≤ 0.20 mm) increased, but the percentage of large mites (body length >0.40 mm) decreased under drought. Air warming had only minor effects on the fauna. All climate treatments significantly reduced the richness of Collembola and the biomass of Collembola and mites in acidic soil, but not in calcareous soil. Drought appeared to have a negative impact on soil microarthropod fauna, but the effects of climate change on soil fauna may vary with the soil type.

Seasonal Exposure to Drought and Air Warming Affects Soil Collembola and Mites

PubMed Central

Xu, Guo-Liang; Kuster, Thomas M.; Günthardt-Goerg, Madeleine S.; Dobbertin, Matthias; Li, Mai-He

2012-01-01

Global environmental changes affect not only the aboveground but also the belowground components of ecosystems. The effects of seasonal drought and air warming on the genus level richness of Collembola, and on the abundance and biomass of the community of Collembola and mites were studied in an acidic and a calcareous forest soil in a model oak-ecosystem experiment (the Querco experiment) at the Swiss Federal Research Institute WSL in Birmensdorf. The experiment included four climate treatments: control, drought with a 60% reduction in rainfall, air warming with a seasonal temperature increase of 1.4°C, and air warming + drought. Soil water content was greatly reduced by drought. Soil surface temperature was slightly increased by both the air warming and the drought treatment. Soil mesofauna samples were taken at the end of the first experimental year. Drought was found to increase the abundance of the microarthropod fauna, but reduce the biomass of the community. The percentage of small mites (body length 0.20 mm) increased, but the percentage of large mites (body length >0.40 mm) decreased under drought. Air warming had only minor effects on the fauna. All climate treatments significantly reduced the richness of Collembola and the biomass of Collembola and mites in acidic soil, but not in calcareous soil. Drought appeared to have a negative impact on soil microarthropod fauna, but the effects of climate change on soil fauna may vary with the soil type. PMID:22905210

Seasonal variation in the biochemical composition of red seaweed ( Catenella repens) from Gangetic delta, northeast coast of India

NASA Astrophysics Data System (ADS)

Banerjee, Kakoli; Ghosh, Rajrupa; Homechaudhuri, Sumit; Mitra, Abhijit

2009-10-01

The biochemical composition of red seaweeds, Catenella repens was investigated in this present study along with subsequent analysis of relevant physico-chemical variables. In this study, the relationship between the nutritive components of this species and the ambient environmental parameters was established. Protein content varied from 2.78 ± 0.30% of dry weight (stn.3) to 16.03 ± 0.96% of dry weight (stn.1) with highest values during monsoon. The protein levels were positively correlated with dissolved nitrate content and negatively correlated with water temperature (except stn.3) and salinity. Carbohydrate content of this species varied significantly ( p < 0.05) during pre-monsoon between stations and the values showed positive relationship with salinity and surface water temperature. In contrast to carbohydrate, lipid concentration was lowest in values and varied very slightly between seasons and stations. Astaxanthin content of the seaweed species was greater in pre-monsoon than monsoon and post-monsoon in all the selected stations. Compared with the three seasons, samples of red seaweed collected in pre-monsoon has high carbohydrate-astaxanthin in contrast to protein-lipid which showed high values during monsoon. Statistical analysis computed among the environmental and biochemical parameters suggests the potential role played by the abiotic parameters on biosynthetic pathways of seaweed. This paper also highlights the influence of the nutritional quality of water that can be used for mass cultivation of Catenella repens.

Interaction of an antiepileptic drug, lamotrigine with human serum albumin (HSA): Application of spectroscopic techniques and molecular modeling methods.

PubMed

Poureshghi, Fatemeh; Ghandforoushan, Parisa; Safarnejad, Azam; Soltani, Somaieh

2017-01-01

Lamotrigine (an epileptic drug) interaction with human serum albumin (HSA) was investigated by fluorescence, UV-Vis, FTIR, CD spectroscopic techniques, and molecular modeling methods. Binding constant (K b ) of 5.74×10 3 and number of binding site of 0.97 showed that there is a slight interaction between lamotrigine and HSA. Thermodynamic studies was constructed using the flourimetric titrations in three different temperatures and the resulted data used to calculate the parameters using Vant Hoff equation. Decreased Stern Volmer quenching constant by enhanced temperature revealed the static quenching mechanism. Negative standard enthalpy (ΔH) and standard entropy (ΔS) changes indicated that van der Waals interactions and hydrogen bonds were dominant forces which facilitate the binding of Lamotrigine to HSA, the results were confirmed by molecular docking studies which showed no hydrogen binding. The FRET studies showed that there is a possibility of energy transfer between Trp214 and lamotrigine. Also the binding of lamotrigine to HSA in the studied concentrations was not as much as many other drugs, but the secondary structure of the HSA was significantly changed following the interaction in a way that α-helix percentage was reduced from 67% to 57% after the addition of lamotrigine in the molar ratio of 4:1 to HSA. According to the docking studies, lamotrigine binds to IB site preferably. Copyright © 2016. Published by Elsevier B.V.

Changes in coping and social motives for drinking and alcohol consumption across the menstrual cycle.

PubMed

Joyce, Kayla M; Hudson, Amanda; O'Connor, Roisin; Thompson, Kara; Hodgin, Megan; Perrot, Tara; Stewart, Sherry H

2018-04-01

Alcohol use has been reported to fluctuate over women's menstrual cycles (MCs), with increased intake occurring premenstrually/menstrually (phases characterized by heightened negative affect) and during the ovulatory phase (a phase characterized by positive affect). This suggests women may drink for particular emotion-focused reasons at specific points in their cycles. However, no research had yet examined MC variability in drinking motives, or links between cycle-related changes in drinking motives and alcohol consumption. Ninety-four normally cycling women (M age  = 22.9 years old, SD age  = 4.7) completed daily diary measures (via Smartphone surveys), with questions pertaining to state drinking motives and quantity of alcohol consumed for the course of a full MC. Drinking motives differed by cycle phase. Women reported a slight increase in drinking to self-medicate for negative affect premenstrually, with drinking to cope peaking in the menstrual phase and declining mid-cycle. Women reported a slight increasing trend across the cycle in social motives for drinking, while enhancement motives remained relatively stable across the cycle. Cycle-related changes in drinking motives predicted increases in the quantity of alcohol consumed. Drinking to cope with negative affect predicted a greater number of drinks menstrually (days 1-5). While social motives predicted a greater number of drinks during the follicular and ovulatory phases (days 5-16), enhancement motives were unrelated to drinking quantity across cycle phase. Clinicians should be attentive to cycle phase when treating reproductive-aged women with alcohol disorders (e.g., encouraging the use of healthier means of coping with negative affect during menses). © 2017 Wiley Periodicals, Inc.

Relationship of geological and geothermal field properties: Midcontinent area, USA, an example

USGS Publications Warehouse

Forster, A.; Merriam, D.F.; Brower, J.C.

1993-01-01

Quantitative approaches to data analysis in the last decade have become important in basin modeling and mineral-resource estimation. The interrelation of geological, geophysical, geochemical, and geohydrological variables is important in adjusting a model to a real-world situation. Revealing the interdependences of variables can contribute in understanding the processes interacting in sedimentary basins. It is reasonably simple to compare spatial data of the same type but more difficult if different properties are involved. Statistical techniques, such as cluster analysis or principal components analysis, or some algebraic approaches can be used to ascertain the relations of standardized spatial data. In this example, structural configuration on five different stratigraphic horizons, one total sediment thickness map, and four maps of geothermal data were copared. As expected, the structural maps are highly related because all had undergone about the same deformation with differing degrees of intensity. The temperature gradients derived (1) from shallow borehole logging measurements under equilibrium conditions with the surrounding rock, and (2) from non-equilibrium bottom-hole temperatures (BHT) from deeper depths are mainly independent of each other. This was expected and confirmed also for the two temperature maps at 1000 ft which were constructed using both types of gradient values. Thus, it is evident that the use of a 2-point (BHT and surface temperature) straightline calculation of a mean temperature gradient gives different information about the geothermal regime than using gradients from temperatures logged under equilibrium conditions. Nevertheless, it is useful to determine to what a degree the larger dataset of nonequilibrium temperatures could reflect quantitative relationships to geologic conditions. Comparing all maps of geothermal information vs. the structural and the sediment thickness maps, it was determined that all correlations are moderately negative or slightly positive. These results are clearly shown by the cluster analysis and the principal components. Considering a close relationship between temperature and thermal conductivity of the sediments as observed for most of the Midcontinent area and relatively homogeneous heat-flow density conditions for the study area these results support the following assumptions: (1) undifferentiated geothermal gradients, computed from temperatures of different depth intervals and differing sediment properties, cannot contribute to an improved understanding of the temperature structure and its controls within the sedimentary cover, and (2) the quantitative approach of revealing such relations needs refined datasets of temperature information valid for the different depth levels or stratigraphic units. ?? 1993 International Association for Mathematical Geology.

SiC JFET Transistor Circuit Model for Extreme Temperature Range

NASA Technical Reports Server (NTRS)

Neudeck, Philip G.

2008-01-01

A technique for simulating extreme-temperature operation of integrated circuits that incorporate silicon carbide (SiC) junction field-effect transistors (JFETs) has been developed. The technique involves modification of NGSPICE, which is an open-source version of the popular Simulation Program with Integrated Circuit Emphasis (SPICE) general-purpose analog-integrated-circuit-simulating software. NGSPICE in its unmodified form is used for simulating and designing circuits made from silicon-based transistors that operate at or near room temperature. Two rapid modifications of NGSPICE source code enable SiC JFETs to be simulated to 500 C using the well-known Level 1 model for silicon metal oxide semiconductor field-effect transistors (MOSFETs). First, the default value of the MOSFET surface potential must be changed. In the unmodified source code, this parameter has a value of 0.6, which corresponds to slightly more than half the bandgap of silicon. In NGSPICE modified to simulate SiC JFETs, this parameter is changed to a value of 1.6, corresponding to slightly more than half the bandgap of SiC. The second modification consists of changing the temperature dependence of MOSFET transconductance and saturation parameters. The unmodified NGSPICE source code implements a T(sup -1.5) temperature dependence for these parameters. In order to mimic the temperature behavior of experimental SiC JFETs, a T(sup -1.3) temperature dependence must be implemented in the NGSPICE source code. Following these two simple modifications, the Level 1 MOSFET model of the NGSPICE circuit simulation program reasonably approximates the measured high-temperature behavior of experimental SiC JFETs properly operated with zero or reverse bias applied to the gate terminal. Modification of additional silicon parameters in the NGSPICE source code was not necessary to model experimental SiC JFET current-voltage performance across the entire temperature range from 25 to 500 C.

Association Between Air Temperature and Cancer Death Rates in Florida: An Ecological Study.

PubMed

Hart, John

2015-01-01

Proponents of global warming predict adverse events due to a slight warming of the planet in the last 100 years. This ecological study tests one of the possible arguments that might support the global warming theory - that it may increase cancer death rates. Thus, average daily air temperature is compared to cancer death rates at the county level in a U.S. state, while controlling for variables of smoking, race, and land elevation. The study revealed that lower cancer death rates were associated with warmer temperatures. Further study is indicated to verify these findings.

Association Between Air Temperature and Cancer Death Rates in Florida

PubMed Central

2015-01-01

Proponents of global warming predict adverse events due to a slight warming of the planet in the last 100 years. This ecological study tests one of the possible arguments that might support the global warming theory – that it may increase cancer death rates. Thus, average daily air temperature is compared to cancer death rates at the county level in a U.S. state, while controlling for variables of smoking, race, and land elevation. The study revealed that lower cancer death rates were associated with warmer temperatures. Further study is indicated to verify these findings. PMID:26674418

Dialogue on Climate, Water, Energy and Human Security in Africa

DTIC Science & Technology

2014-07-01

winter periods.  The influence of the  ocean  mass on the coastal areas can be seen, with slightly lower increases in  average temperatures.       Figure 1...adaptation 1 1’ ~ + -foradaptllion m \\...A..AJ to reduce risk .... :’\\: " -••• \\ Warming Extreme Extreme Damaging Ocean Sea surface I Precipitation Sea...level Risk level with Risk level with trend temperature precipitation cyclone acidification temperature high adaptation cuJTentadaptation Institutions

Climate change impacts on Swiss groundwater: insights from historical records

NASA Astrophysics Data System (ADS)

Figura, S.; Livingstone, D. M.; Kipfer, R.

2012-04-01

Knowledge of the impact of climate change on groundwater is limited mainly by a lack of relevant long-term data that would allow the effects of climatic forcing to be assessed empirically. With the aim of assessing the consequences of climate change on groundwater, we collected and statistically analysed historical groundwater data from Switzerland. While most existing studies have focused on the impact of climate change on groundwater quantity, we focus on groundwater quality. As measures of groundwater quality we chose groundwater temperature and oxygen concentration because of their importance for biogeochemical processes and for reasons of data availability. Our analyses show that in aquifers that are recharged by riverbank infiltration, groundwater temperature has increased by 1°C - 1.5°C over the last 30 years. By contrast, in aquifers that are recharged only by the percolation of precipitation, increases in groundwater temperature are slight or non-existent. A detailed analysis of groundwater temperatures measured in the pumping wells of five aquifers that are recharged by riverbank infiltration revealed that an abrupt temperature increase in the late 1980s, which was also detected in Swiss air temperature and river water temperatures and which is traceable ultimately to a change in the behaviour of the Arctic Oscillation, accounted for a large proportion of the total groundwater warming [1]. Oxygen concentrations were available for four of the five aquifers we investigated. In two of these aquifers the oxygen concentration underwent a strong decrease, in the third a slight decrease, and in the fourth a slight increase. Neither long-term trends in river water oxygen concentration nor altered hydraulic conditions seem to be responsible for the long-term trends in groundwater oxygen concentrations. However, the decreasing oxygen concentrations were accompanied by decreasing DOC concentrations in the groundwater, while DOC concentrations in the river water increased over the same period. We therefore suggest that higher temperatures are resulting in enhanced microbiological activity in the hyporheic zone, resulting in increased oxygen consumption and decreasing groundwater oxygen concentrations. Based on our analyses of the available long-term Swiss data, we postulate that in aquifers that are recharged by riverbank infiltration, the frequency of occurrence of anoxic conditions will increase in future if temperatures continue to increase, assuming the nutrient load in river water remains constant. Groundwater anoxia may pose a challenge to the water supply infrastructure because of the dissolution of iron and manganese oxides, which, after re-oxidation, precipitate and cause clogging of the pumping wells. [1] Figura, S. et al. (2011), Geophys. Res. Lett., 38(23), L23401, DOI: 10.1029/2011GL049749.

Effects of origin, seasons and storage under different temperatures on germination of Senecio vulgaris (Asteraceae) seeds.

PubMed

Ndihokubwayo, Noel; Nguyen, Viet-Thang; Cheng, Dandan

2016-01-01

Invasive plants colonize new environments, become pests and cause biodiversity loss, economic loss and health damage. Senecio vulgaris L. (Common groundsel, Asteraceae), a widely distributing cosmopolitan weed in the temperate area, is reported with large populations in the north-eastern and south-western part, but not in southern, central, or north-western parts of China. We studied the germination behavior of S. vulgaris to explain the distribution and the biological invasion of this species in China. We used seeds originating from six native and six invasive populations to conduct germination experiments in a climate chamber and under outdoor condition. When incubated in a climate chamber (15 °C), seeds from the majority of the populations showed >90% germination percentage (GP) and the GP was equal for seeds with a native and invasive origin. The mean germination time (MGT) was significantly different among the populations. Under outdoor conditions, significant effects of origin, storage conditions (stored at 4 °C or ambient room temperature, ca. 27 °C) and seasons (in summer or autumn) were observed on the GP while the MGT was only affected by the season. In autumn, the GP (38.6%) was higher and the MGT was slightly longer than that in summer. In autumn, seeds stored at 4 °C showed higher GP than those stored at ambient room temperature (ca.27 °C), and seeds from invasive populations revealed higher GP than those from native populations. The results implied that the high temperature in summer has a negative impact on the germination and might cause viability loss or secondary dormancy to S. vulgaris seeds. Our study offers a clue to exploring what factor limits the distribution of S. vulgaris in China by explaining why, in the cities in South-East China and central China such as Wuhan, S. vulgaris cannot establish natural and viable populations.

Thermodynamics of alpha-Cyclodextrin-p-Nitrophenyl Glycoside Complexes. A Simple System To Understand the Energetics of Carbohydrate Interactions in Water.

PubMed

Junquera, Elena; Laynez, José; Menéndez, Margarita; Sharma, Sunil; Penadés, Soledad

1996-10-04

Thermodynamic studies of the binding of a series of p-nitrophenyl glycosides (PNPGly) of varying stereochemistry to alpha-cyclodextrin (alpha-CD) were performed at three different temperatures (25, 35, and 42 degrees C) using a microcalorimetric technique. The system p-nitrophenol (PNP) at pH = 3 and alpha-CD was also studied for the sake of comparison. All these complexes were found to be enthalpy driven with a favorable enthalpic term clearly dominant over an unfavorable entropic term. A clear enthalpy-entropy compensation effect was observed at all the temperatures, with a slope close to unity (alpha = 1.02) and an intercept TDeltaS degrees (o) = 2.91 kcal mol(-)(1). This thermodynamic pattern is in agreement with those usually found for lectin-carbohydrate associations and for the binding processes of several host-guest systems. This pattern is explained in terms of the contribution of primarily two driving forces: the van der Waals interactions between the host and the guest, and the solvation/desolvation processes which accompany the association reaction. The presence of the carbohydrate molecule in the PNP ring causes a slight destabilization of the complex at 25 degrees C with respect to the alpha-CD-PNP (pH = 3) complex, although a different behavior has been observed depending on the axial/equatorial configuration of the glycoside and the temperature. This behavior is modulated by the stereochemistry of the glycoside. Differences were observed between the deoxy-derivatives (LAra and LFuc) and those derivatives with a hydroxymethyl group (Glc, Gal, Man). DeltaC(p) degrees values were obtained from the dependency of DeltaH degrees on temperature (=( partial differentialDeltaH degrees / partial differentialT)(p)). These values are small and negative except for alphaMan complex. For the latter complex, discrepancy between the calorimetric and the calculated van't Hoff enthalpies was observed. Parallels are drawn between the thermodynamics of our model and those proposed for carbohydrate-protein associations.

Long-term climate impacts on breeding bird phenology in Pennsylvania, USA.

PubMed

McDermott, Molly E; DeGroote, Lucas W

2016-10-01

Climate change is influencing bird phenology worldwide, but we still lack information on how many species are responding over long temporal periods. We assessed how climate affected passerine reproductive timing and productivity at a constant effort mist-netting station in western Pennsylvania using a model comparison approach. Several lines of evidence point to the sensitivity of 21 breeding passerines to climate change over five decades. The trends for temperature and precipitation over 53 years were slightly positive due to intraseasonal variation, with the greatest temperature increases and precipitation declines in early spring. Regardless of broodedness, migration distance, or breeding season, 13 species hatched young earlier over time with most advancing >3 days per decade. Warm springs were associated with earlier captures of juveniles for 14 species, ranging from 1- to 3-day advancement for every 1 °C increase. This timing was less likely to be influenced by spring precipitation; nevertheless, higher rainfall was usually associated with later appearance of juveniles and breeding condition in females. Temperature and precipitation were positively related to productivity for seven and eleven species, respectively, with negative relations evident for six and eight species. We found that birds fledged young earlier with increasing spring temperatures, potentially benefiting some multibrooded species. Indeed, some extended the duration of breeding in these warm years. Yet, a few species fledged fewer juveniles in warmer and wetter seasons, indicating that expected future increases could be detrimental to locally breeding populations. Although there were no clear relationships between life history traits and breeding phenology, species-specific responses to climate found in our study provide novel insights into phenological flexibility in songbirds. Our research underscores the value of long-term monitoring studies and the importance of continuing constant effort sampling in the face of climate change. © 2016 John Wiley & Sons Ltd.

Negative differential resistance in GaN nanocrystals above room temperature.

PubMed

Chitara, Basant; Ivan Jebakumar, D S; Rao, C N R; Krupanidhi, S B

2009-10-07

Negative differential resistance (NDR) has been observed for the first time above room temperature in gallium nitride nanocrystals synthesized by a simple chemical route. Current-voltage characteristics have been used to investigate this effect through a metal-semiconductor-metal (M-S-M) configuration on SiO2. The NDR effect is reversible and reproducible through many cycles. The threshold voltage is approximately 7 V above room temperature.

Structural rejuvenation in bulk metallic glasses

DOE PAGES

Tong, Yang; Iwashita, T.; Dmowski, Wojciech; ...

2015-01-05

Using high-energy X-ray diffraction we study structural changes in bulk metallic glasses after uniaxial compressive homogeneous deformation at temperatures slightly below the glass transition. We observe that deformation results in structural disordering corresponding to an increase in the fictive, or effective, temperature. However, the structural disordering saturates after yielding. Lastly, examination of the experimental structure and molecular dynamics simulation suggests that local changes in the atomic connectivity network are the main driving force of the structural rejuvenation.

Solvent and temperature effects on the decay dynamics of [p-N,N-(dialkylamino)benzylidene]malononitriles

NASA Astrophysics Data System (ADS)

Safarzadeh-Amiri, A.

1986-08-01

The effects of solvent and temperature on the decay kinetics of p-(dialkylamino)benzylidenemalononitrile (1) and julodinemalononitrile (3) has been studied in glycerol and triacetin. The fluorescence decay curves of these compounds were non-exponential and varied slightly with wavelength. This is attributed to the existence of two ground state conformers and to reorientation of the solvent cage around solute molecules. The results were explained in terms of trans → cisphotoisomerization.

Comment on Modified Stokes Parameters

NASA Technical Reports Server (NTRS)

Le Vine, D.M.; Utku, C.

2009-01-01

It is common practice in passive microwave remote sensing (microwave radiometry) to express observables as temperatures and in the case of polarimetric radiometry to use what are called "Modified Stokes Parameters in Brightness Temperature" to describe the scene. However, definitions with slightly different normalization (with and without division by bandwidth) have appeared in the literature. The purpose of this manuscript is to present an analysis to clarify the meaning of terms in the definition and resolve the question of the proper normalization.

Structural rejuvenation in bulk metallic glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tong, Yang; Iwashita, T.; Dmowski, Wojciech

Using high-energy X-ray diffraction we study structural changes in bulk metallic glasses after uniaxial compressive homogeneous deformation at temperatures slightly below the glass transition. We observe that deformation results in structural disordering corresponding to an increase in the fictive, or effective, temperature. However, the structural disordering saturates after yielding. Lastly, examination of the experimental structure and molecular dynamics simulation suggests that local changes in the atomic connectivity network are the main driving force of the structural rejuvenation.

Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neises, Ty; Turchi, Craig

2014-09-01

A comparison of three supercritical CO2 Brayton cycles: the simple cycle, recompression cycle and partial-cooling cycle indicates the partial-cooling cycle is favored for use in concentrating solar power (CSP) systems. Although it displays slightly lower cycle efficiency versus the recompression cycle, the partial-cooling cycle is estimated to have lower total recuperator size, as well as a lower maximum s-CO2 temperature in the high-temperature recuperator. Both of these effects reduce recuperator cost. Furthermore, the partial-cooling cycle provides a larger temperature differential across the turbine, which translates into a smaller, more cost-effective thermal energy storage system. The temperature drop across the turbinemore » (and by extension, across a thermal storage system) for the partial-cooling cycle is estimated to be 23% to 35% larger compared to the recompression cycle of equal recuperator conductance between 5 and 15 MW/K. This reduces the size and cost of the thermal storage system. Simulations by NREL and Abengoa Solar indicate the partial-cooling cycle results in a lower LCOE compared with the recompression cycle, despite the former's slightly lower cycle efficiency. Advantages of the recompression cycle include higher thermal efficiency and potential for a smaller precooler. The overall impact favors the use of a partial-cooling cycle for CSP compared to the more commonly analyzed recompression cycle.« less

Amorphous silicon carbide passivating layers for crystalline-silicon-based heterojunction solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boccard, Mathieu; Holman, Zachary C.

Amorphous silicon enables the fabrication of very high-efficiency crystalline-silicon-based solar cells due to its combination of excellent passivation of the crystalline silicon surface and permeability to electrical charges. Yet, amongst other limitations, the passivation it provides degrades upon high-temperature processes, limiting possible post-deposition fabrication possibilities (e.g., forcing the use of low-temperature silver pastes). We investigate the potential use of intrinsic amorphous silicon carbide passivating layers to sidestep this issue. The passivation obtained using device-relevant stacks of intrinsic amorphous silicon carbide with various carbon contents and doped amorphous silicon are evaluated, and their stability upon annealing assessed, amorphous silicon carbide beingmore » shown to surpass amorphous silicon for temperatures above 300 °C. We demonstrate open-circuit voltage values over 700 mV for complete cells, and an improved temperature stability for the open-circuit voltage. Transport of electrons and holes across the hetero-interface is studied with complete cells having amorphous silicon carbide either on the hole-extracting side or on the electron-extracting side, and a better transport of holes than of electrons is shown. Also, due to slightly improved transparency, complete solar cells using an amorphous silicon carbide passivation layer on the hole-collecting side are demonstrated to show slightly better performances even prior to annealing than obtained with a standard amorphous silicon layer.« less

Amorphous silicon carbide passivating layers for crystalline-silicon-based heterojunction solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boccard, Mathieu; Holman, Zachary C.

With this study, amorphous silicon enables the fabrication of very high-efficiency crystalline-silicon-based solar cells due to its combination of excellent passivation of the crystalline silicon surface and permeability to electrical charges. Yet, amongst other limitations, the passivation it provides degrades upon high-temperature processes, limiting possible post-deposition fabrication possibilities (e.g., forcing the use of low-temperature silver pastes). We investigate the potential use of intrinsic amorphous silicon carbide passivating layers to sidestep this issue. The passivation obtained using device-relevant stacks of intrinsic amorphous silicon carbide with various carbon contents and doped amorphous silicon are evaluated, and their stability upon annealing assessed, amorphousmore » silicon carbide being shown to surpass amorphous silicon for temperatures above 300°C. We demonstrate open-circuit voltage values over 700 mV for complete cells, and an improved temperature stability for the open-circuit voltage. Transport of electrons and holes across the hetero-interface is studied with complete cells having amorphous silicon carbide either on the hole-extracting side or on the electron-extracting side, and a better transport of holes than of electrons is shown. Also, due to slightly improved transparency, complete solar cells using an amorphous silicon carbide passivation layer on the hole-collecting side are demonstrated to show slightly better performances even prior to annealing than obtained with a standard amorphous silicon layer.« less

Amorphous silicon carbide passivating layers for crystalline-silicon-based heterojunction solar cells

DOE PAGES

Boccard, Mathieu; Holman, Zachary C.

2015-08-14

With this study, amorphous silicon enables the fabrication of very high-efficiency crystalline-silicon-based solar cells due to its combination of excellent passivation of the crystalline silicon surface and permeability to electrical charges. Yet, amongst other limitations, the passivation it provides degrades upon high-temperature processes, limiting possible post-deposition fabrication possibilities (e.g., forcing the use of low-temperature silver pastes). We investigate the potential use of intrinsic amorphous silicon carbide passivating layers to sidestep this issue. The passivation obtained using device-relevant stacks of intrinsic amorphous silicon carbide with various carbon contents and doped amorphous silicon are evaluated, and their stability upon annealing assessed, amorphousmore » silicon carbide being shown to surpass amorphous silicon for temperatures above 300°C. We demonstrate open-circuit voltage values over 700 mV for complete cells, and an improved temperature stability for the open-circuit voltage. Transport of electrons and holes across the hetero-interface is studied with complete cells having amorphous silicon carbide either on the hole-extracting side or on the electron-extracting side, and a better transport of holes than of electrons is shown. Also, due to slightly improved transparency, complete solar cells using an amorphous silicon carbide passivation layer on the hole-collecting side are demonstrated to show slightly better performances even prior to annealing than obtained with a standard amorphous silicon layer.« less

Is applicable thermodynamics of negative temperature for living organisms?

NASA Astrophysics Data System (ADS)

Atanasov, Atanas Todorov

2017-11-01

During organismal development the moment of sexual maturity can be characterizes by nearly maximum basal metabolic rate and body mass. Once the living organism reaches extreme values of the mass and the basal metabolic rate, it reaches near equilibrium thermodynamic steady state physiological level with maximum organismal complexity. Such thermodynamic systems that reach equilibrium steady state level at maximum mass-energy characteristics can be regarded from the prospective of thermodynamics of negative temperature. In these systems the increase of the internal and free energy is accompanied with decrease of the entropy. In our study we show the possibility the living organisms to regard as thermodynamic system with negative temperature

Positive And Negative Feedback Loops Coupled By Common Transcription Activator And Repressor

NASA Astrophysics Data System (ADS)

Sielewiesiuk, Jan; Łopaciuk, Agata

2015-03-01

Dynamical systems consisting of two interlocked loops with negative and positive feedback have been studied using the linear analysis of stability and numerical solutions. Conditions for saddle-node bifurcation were formulated in a general form. Conditions for Hopf bifurcations were found in a few symmetrical cases. Auto-oscillations, when they exist, are generated by the negative feedback repressive loop. This loop determines the frequency and amplitude of oscillations. The positive feedback loop of activation slightly modifies the oscillations. Oscillations are possible when the difference between Hilll's coefficients of the repression and activation is sufficiently high. The highly cooperative activation loop with a fast turnover slows down or even makes the oscillations impossible. The system under consideration can constitute a component of epigenetic or enzymatic regulation network.

The incidence and role of negative citations in science

PubMed Central

Catalini, Christian; Lacetera, Nicola; Oettl, Alexander

2015-01-01

Citations to previous literature are extensively used to measure the quality and diffusion of knowledge. However, we know little about the different ways in which a study can be cited; in particular, are papers cited to point out their merits or their flaws? We elaborated a methodology to characterize “negative” citations using bibliometric data and natural language processing. We found that negative citations concerned higher-quality papers, were focused on a study’s findings rather than theories or methods, and originated from scholars who were closer to the authors of the focal paper in terms of discipline and social distance, but not geographically. Receiving a negative citation was also associated with a slightly faster decline in citations to the paper in the long run. PMID:26504239

Temperature and rainfall strongly drive temporal growth variation in Asian tropical forest trees.

PubMed

Vlam, Mart; Baker, Patrick J; Bunyavejchewin, Sarayudh; Zuidema, Pieter A

2014-04-01

Climate change effects on growth rates of tropical trees may lead to alterations in carbon cycling of carbon-rich tropical forests. However, climate sensitivity of broad-leaved lowland tropical trees is poorly understood. Dendrochronology (tree-ring analysis) provides a powerful tool to study the relationship between tropical tree growth and annual climate variability. We aimed to establish climate-growth relationships for five annual-ring forming tree species, using ring-width data from 459 canopy and understory trees from a seasonal tropical forest in western Thailand. Based on 183/459 trees, chronologies with total lengths between 29 and 62 years were produced for four out of five species. Bootstrapped correlation analysis revealed that climate-growth responses were similar among these four species. Growth was significantly negatively correlated with current-year maximum and minimum temperatures, and positively correlated with dry-season precipitation levels. Negative correlations between growth and temperature may be attributed to a positive relationship between temperature and autotrophic respiration rates. The positive relationship between growth and dry-season precipitation levels likely reflects the strong water demand during leaf flush. Mixed-effect models yielded results that were consistent across species: a negative effect of current wet-season maximum temperatures on growth, but also additive positive effects of, for example, prior dry-season maximum temperatures. Our analyses showed that annual growth variability in tropical trees is determined by a combination of both temperature and precipitation variability. With rising temperature, the predominantly negative relationship between temperature and growth may imply decreasing growth rates of tropical trees as a result of global warming.

The warmer the weather, the more gram-negative bacteria - impact of temperature on clinical isolates in intensive care units.

PubMed

Schwab, Frank; Gastmeier, Petra; Meyer, Elisabeth

2014-01-01

We investigated the relationship between average monthly temperature and the most common clinical pathogens causing infections in intensive care patients. A prospective unit-based study in 73 German intensive care units located in 41 different hospitals and 31 different cities with total 188,949 pathogen isolates (102,377 Gram-positives and 86,572 Gram-negatives) from 2001 to 2012. We estimated the relationship between the number of clinical pathogens per month and the average temperature in the month of isolation and in the month prior to isolation while adjusting for confounders and long-term trends using time series analysis. Adjusted incidence rate ratios for temperature parameters were estimated based on generalized estimating equation models which account for clustering effects. The incidence density of Gram-negative pathogens was 15% (IRR 1.15, 95%CI 1.10-1.21) higher at temperatures ≥ 20°C than at temperatures below 5°C. E. cloacae occurred 43% (IRR=1.43; 95%CI 1.31-1.56) more frequently at high temperatures, A. baumannii 37% (IRR=1.37; 95%CI 1.11-1.69), S. maltophilia 32% (IRR=1.32; 95%CI 1.12-1.57), K. pneumoniae 26% (IRR=1.26; 95%CI 1.13-1.39), Citrobacter spp. 19% (IRR=1.19; 95%CI 0.99-1.44) and coagulase-negative staphylococci 13% (IRR=1.13; 95%CI 1.04-1.22). By contrast, S. pneumoniae 35% (IRR=0.65; 95%CI 0.50-0.84) less frequently isolated at high temperatures. For each 5°C increase, we observed a 3% (IRR=1.03; 95%CI 1.02-1.04) increase of Gram-negative pathogens. This increase was highest for A. baumannii with 8% (IRR=1.08; 95%CI 1.05-1.12) followed by K. pneumoniae, Citrobacter spp. and E. cloacae with 7%. Clinical pathogens vary by incidence density with temperature. Significant higher incidence densities of Gram-negative pathogens were observed during summer whereas S. pneumoniae peaked in winter. There is increasing evidence that different seasonality due to physiologic changes underlies host susceptibility to different bacterial pathogens. Even if the underlying mechanisms are not yet clear, the temperature-dependent seasonality of pathogens has implications for infection control and study design.

Spatial and temporal variation of correlation between the Arctic total ozone and atmospheric temperature

NASA Astrophysics Data System (ADS)

Huang, Fuxiang; Ren, suling; Han, Shuangshuang; Zheng, xiangdong; Deng, xuejiao

2017-04-01

Daily total ozone and atmospheric temperature profile data in 2015 from the AIRS are used to investigate the spatial and temporal variation of the correlation between the Arctic atmospheric ozone and temperature. In the study, 11 lays atmospheric temperature profiles from the troposphere to the stratosphere are investigated. These layer heights are 20, 50, 70, 100, 200, 250, 300, 400, 500, 600 and 700 hPa respectively. The results show that a significant seasonal split exists in the correlation between the Arctic ozone and atmospheric temperature. Figure 1 shows the spatial and temporal variation of the coefficient between the atmospheric ozone and temperature at 50hPa. It can be seen from the figure that an obvious spatiotemporal difference exists in the correlation between the Arctic total ozone and atmospheric temperature in the lower stratosphere. First, the seasonal difference is very remarkable, which is shown as a significant positive correlation in most regions during winter and summer, while no correlation in the majority of regions occurs during spring and autumn, with a weak positive or negative correlation in a small number regions. Second, the spatial differences are also very obvious. The summer maximum correlation coefficient occurs in the Barents Sea and other locations at 0.8 and above, while the winter maximum occurs in the Baffin Bay area at 0.6 to 0.8. However, in a small number of regions, such as the land to the west of the Bering Strait in winter and the Arctic Ocean core area in summer, the correlation coefficients were unable to pass the significance test to show no correlation. At the same time, in spring and autumn, a positive correlation only occurs over a few low-latitude land areas, while over other Arctic areas, weak negative correlation exists. The differences in horizontal position are clearly related to the land-sea distribution, underlying surface characteristics, glacial melting, and other factors. In the troposphere, the ozone and temperature have a strong negative correlation in spring and autumn, while presenting a weak negative correlation or no correlation in winter and summer. Figure 2 shows the spatial and temporal variation of the correlation coefficient between the atmospheric ozone and temperature at 500hPa. From figure 2, it can be seen that in the Arctic troposphere, the atmospheric ozone and tropospheric temperature mainly have a negative correlation. In winter and summer, a weak negative correlation is shown overall, but more than a third of the regions show no correlation. In spring, the negative correlation is the strongest between the ozone and temperature. Especially in Greenland - Queen Elizabeth Islands and southern New Siberian Islands, the correlation is the highest, with a correlation coefficient of -0.9 and above, followed by a negative correlation in autumn. Except for a small number of low-latitude scattered regions with weak correlation, the correlation coefficients of most regions are ranged between -0.5 and -0.7. At 300 hPa near the tropopause, the horizontal distribution and seasonal change of the correlation between the Arctic total ozone and atmospheric temperature are as shown in Fig. 3.At the height near the Arctic tropopause, the atmospheric ozone mainly has no correlation to temperature, especially in winter and summer, when no correlation exists in the majority of regions, while weak positive or negative correlation occurs in a small number of areas. In the majority of regions during spring, a weak negative correlation is shown, while no correlation appears in Western Greenland - Queen Elizabeth Islands. In autumn, most regions show no correlation, while weak negative correlation is presented in Eastern Greenland, Norwegian Sea - Barents Sea, and other locations. From figure 1-3, we can see a significant difference exists from the common law of positive correlation in the lower stratosphere and negative correlation in the troposphere at mid-low latitudes. The Arctic atmospheric ozone has a relation with temperature, showing significant spatial and temporal variation characteristics. In the stratosphere, winter and summer atmospheric temperatures mainly have a positive correlation to ozone. The summer maximum occurs in the Barents Sea to achieve 0.8 and above, while the winter maximum is 0.6 to 0.8 in the Baffin Bay area. In the troposphere, the autumn and spring atmospheric temperatures mainly have a negative correlation to the ozone. The spring correlation coefficient in Greenland to the Queen Elizabeth Islands reaches up to -0.9 and above, while the autumn value is -0.5 to -0.7. At about 300 hPa, the tropopause value is reduced to 0, and further decreased in the troposphere, to show a strong negative correlation. Based on the comprehensive analysis of various influence factors, the possible action mechanism of the spatiotemporal variation pattern of the correlation between the Arctic atmospheric ozone and temperature is discussed based on the seasonal differences of various influence factors. The spatial and temporal variation characteristics of the correlation between the Arctic atmospheric ozone and temperature are determined by the seasonal variation of various influencing factors of the Arctic atmospheric ozone and temperature. These factors include the atmospheric heating effect from the ozone matching with the Arctic sunshine conditions, the influence of dynamic delivery on the ozone and heat, the impact of underlying-surface glacial melting on atmospheric radiation and heat budget, and so on. At different heights in each season, the different effects from all kinds of factors on the ozone and temperature determine the spatiotemporal variation of the correlation between the ozone and temperature.

Ion transport with charge-protected and non-charge-protected cations in alcohol-based electrolytes using the compensated Arrhenius formalism. Part I: ionic conductivity and the static dielectric constant.

PubMed

Petrowsky, Matt; Fleshman, Allison; Frech, Roger

2012-05-17

The temperature dependence of ionic conductivity and the static dielectric constant is examined for 0.30 m TbaTf- or LiTf-1-alcohol solutions. Above ambient temperature, the conductivity increases with temperature to a greater extent in electrolytes whose salt has a charge-protected cation. Below ambient temperature, the dielectric constant changes only slightly with temperature in electrolytes whose salt has a cation that is not charge-protected. The compensated Arrhenius formalism is used to describe the temperature-dependent conductivity in terms of the contributions from both the exponential prefactor σo and Boltzmann factor exp(-Ea/RT). This analysis explains why the conductivity decreases with increasing temperature above 65 °C for the LiTf-dodecanol electrolyte. At higher temperatures, the decrease in the exponential prefactor is greater than the increase in the Boltzmann factor.

Scanning electron microscope observations of sublimates from Merapi Volcano, Indonesia

USGS Publications Warehouse

Symonds, R.

1993-01-01

Sublimates were sampled from high-temperature (up to 800??C) fumaroles at Merapi volcano in January 1984. Sampling is accomplished by inserting silica tubes into high-temperature vents. Volcanic glass flows through the tubes and sublimates precipitate on the inner walls in response to the temperature gradient. With decreasing temperature (800-500??C) in the tubes, there are five sublimate zones. Texturally, the sublimate phases grade from large, well-formed crystals at their highest-temperature occurrence to more numerous, smaller crystals that are less perfect at lower temperatures. These changes imply that the crystal nucleation and growth rates increase and decrease, respectively, as temperature decreases. Overall, the textural data suggest that the gas is saturated or slightly super-saturated with the phases at their hottest occurrence, but that the gas becomes increasingly super-saturated with the phases at lower temperatures. -from Author

Brief Report: Investigating Uncertainty in the Minimum Mortality Temperature: Methods and Application to 52 Spanish Cities.

PubMed

Tobías, Aurelio; Armstrong, Ben; Gasparrini, Antonio

2017-01-01

The minimum mortality temperature from J- or U-shaped curves varies across cities with different climates. This variation conveys information on adaptation, but ability to characterize is limited by the absence of a method to describe uncertainty in estimated minimum mortality temperatures. We propose an approximate parametric bootstrap estimator of confidence interval (CI) and standard error (SE) for the minimum mortality temperature from a temperature-mortality shape estimated by splines. The coverage of the estimated CIs was close to nominal value (95%) in the datasets simulated, although SEs were slightly high. Applying the method to 52 Spanish provincial capital cities showed larger minimum mortality temperatures in hotter cities, rising almost exactly at the same rate as annual mean temperature. The method proposed for computing CIs and SEs for minimums from spline curves allows comparing minimum mortality temperatures in different cities and investigating their associations with climate properly, allowing for estimation uncertainty.

Parent Attitudes Toward the Virginia Beach Year-Round School Pilot Project. Final Report.

ERIC Educational Resources Information Center

Schlechty, Phillip C.

Part of the Virginia Beach year-round school program evaluation, this final report contains a detailed analysis of parental attitudes, beliefs, and perceptions. The data leads to the following conclusions: a majority (53.3 percent) of parents are dubious or negative toward the 45-15 pilot project; a slight majority of parents in the pilot schools…

Prevalence of Mycoplasma haemolamae infection in Peruvian and Chilean llamas and alpacas.

PubMed

Tornquist, Susan J; Boeder, Lisa; Rios-Phillips, Carolina; Alarcon, Virgilio

2010-09-01

Mycoplasma haemolamae is a hemotropic mycoplasma that affects red blood cells of llamas (Lama glama) and alpacas (Lama pacos). It is variably associated with anemia, and most infections are subclinical. Development of a polymerase chain reaction assay has facilitated detection of this infection in llamas and alpacas in the United States and other countries. Whether the infection occurs in camelids in South America has previously been unknown. The current study documents a 15.8% infection rate among 76 Peruvian llamas, a 19.3% infection rate among Peruvian alpacas at one site, and a 9.26% infection rate in 108 Chilean alpacas from selected herds. All of the camelids tested appeared to be clinically healthy. No gender or species predilection was found. Only 1 positive camelid younger than 18 months was found. Infection is not associated with anemia, and the mean packed cell volume (PCV) in positive Peruvian camelids was slightly higher than the mean PCV in negative Peruvian camelids. In the Chilean alpacas, the positive alpacas had a slightly lower PCV than the negative alpacas, although the mean PCV was not in the anemic range in any of the groups.

Lexical and phonological variability in preschool children with speech sound disorder.

PubMed

Macrae, Toby; Tyler, Ann A; Lewis, Kerry E

2014-02-01

The authors of this study examined relationships between measures of word and speech error variability and between these and other speech and language measures in preschool children with speech sound disorder (SSD). In this correlational study, 18 preschool children with SSD, age-appropriate receptive vocabulary, and normal oral motor functioning and hearing were assessed across 2 sessions. Experimental measures included word and speech error variability, receptive vocabulary, nonword repetition (NWR), and expressive language. Pearson product–moment correlation coefficients were calculated among the experimental measures. The correlation between word and speech error variability was slight and nonsignificant. The correlation between word variability and receptive vocabulary was moderate and negative, although nonsignificant. High word variability was associated with small receptive vocabularies. The correlations between speech error variability and NWR and between speech error variability and the mean length of children's utterances were moderate and negative, although both were nonsignificant. High speech error variability was associated with poor NWR and language scores. High word variability may reflect unstable lexical representations, whereas high speech error variability may reflect indistinct phonological representations. Preschool children with SSD who show abnormally high levels of different types of speech variability may require slightly different approaches to intervention.

Thrust and drag characteristics of a convergent-divergent nozzle with various exhaust jet temperatures

NASA Technical Reports Server (NTRS)

Hearth, Donald P; Wilcox, Fred A

1954-01-01

An investigation was conducted in the 8-by-6 foot supersonic wind tunnel on the effect of exhaust-gas temperatures on the external and internal characteristics of a convergent-divergent nozzle having an area expansion ratio of 1.83. Data were obtained over a pressure-ratio range from 1 to 20 at free-stream Mach numbers of 1.6 and 2.0 for exhaust temperatures of 860 degrees, 1650 degrees, and 2000 degrees R. Results of this investigation indicated that generally both the internal and external performance characteristics were only slightly affected by a large change in jet temperature. The small differences in performance which did occur were predicted satisfactorily from theoretical considerations.

Enhancement of thermal stability of porous bodies comprised of stainless steel or an alloy

DOEpatents

Bischoff, Brian L.; Sutton, Theodore G.; Judkins, Roddie R.; Armstrong, Timothy R.; Adcock, Kenneth D.

2010-11-09

A method for treating a porous item constructed of metal powder, such as a powder made of Series 400 stainless steel, involves a step of preheating the porous item to a temperature of between about 700 and 900.degree. C. degrees in an oxidizing atmosphere and then sintering the body in an inert or reducing atmosphere at a temperature which is slightly below the melting temperature of the metal which comprises the porous item. The thermal stability of the resulting item is enhanced by this method so that the item retains its porosity and metallic characteristics, such as ductility, at higher (e.g. near-melting) temperatures.

Liquid Nitrogen Temperature Operation of a Switching Power Converter

NASA Technical Reports Server (NTRS)

Ray, Biswajit; Gerber, Scott S.; Patterson, Richard L.; Myers, Ira T.

1995-01-01

The performance of a 42/28 V, 175 W, 50 kHz pulse-width modulated buck dc/dc switching power converter at liquid nitrogen temperature (LNT) is compared with room temperature operation. The power circuit as well as the control circuit of the converter, designed with commercially available components, were operated at LNT and resulted in a slight improvement in converter efficiency. The improvement in power MOSFET operation was offset by deteriorating performance of the output diode rectifier at LNT. Performance of the converter could be further improved at low temperatures by using only power MOSFET's as switches. The use of a resonant topology will further improve the circuit performance by reducing the switching noise and loss.

Dual shell pressure balanced vessel

DOEpatents

Fassbender, Alexander G.

1992-01-01

A dual-wall pressure balanced vessel for processing high viscosity slurries at high temperatures and pressures having an outer pressure vessel and an inner vessel with an annular space between the vessels pressurized at a pressure slightly less than or equivalent to the pressure within the inner vessel.

The effect of thermal history on crystalline structure and mechanical properties of β-nucleated isotactic polypropylene

NASA Astrophysics Data System (ADS)

Tian, Yefei; Zhou, Jian; Feng, Jiachun

2018-04-01

The effect of thermal history on β-nucleated iPP was systematically investigated by comparing the variance of crystalline microstructures and mechanical property of stepwise crystallized sample and annealed sample, which experienced different thermal history. The mechanical property tests exhibit that that the toughness of stepwise crystallized sample and annealed sample were both decreased compared to control sample, while the tensile strength of the stepwise crystallized sample increased slightly. Structure investigation showed that the α-relaxation peak, which is related to the assignment of chains in rigid amorphous phase, moved to the high temperature region for stepwise crystallized sample, while it moved to the low temperature region for annealed sample. The results indicated the weakening in rigid amorphous fraction (RAF) and the increase in lamellar thickness of β-iPP after stepwise crystallization treatment. For annealed sample, the RAF strengthened and lamellar thickness decreased slightly after thermal treatment. A mechanism of crystalline microstructures evolution of restricted area between the main lamellar under different treatments was proposed.

Structure of the cell wall of mango after application of ionizing radiation

NASA Astrophysics Data System (ADS)

Silva, Josenilda M.; Villar, Heldio P.; Pimentel, Rejane M. M.

2012-11-01

Cells of the mesocarp of mango cultivar Tommy Atkins were analyzed by Transmission Electron Microscope—TEM to evaluate the effects of doses of 0.5 and 1.0 kGy applied immediately after the fruit and after storage for twenty days at a temperature of 12 °C followed by 5 days of simulated marketing at a temperature of 21 °C. No alteration was found in the structure of the cell wall, middle lamella, and plasma membrane of fruits when analyzed immediately after application of doses. The mesocarp cell structure of the cell wall, middle lamella, and the plasma membrane did however undergo changes after storage. Fruits that received a dose of 0.5 kGy displayed slight changes in cell wall structure and slight disintegration of the middle lamella. Fruits that received a dose of 1.0 kGy displayed more severe changes in the structure of the cell wall, greater middle lamella degradation, and displacement of the plasma membrane.

Room temperature mechanical properties of electron beam welded zircaloy-4 sheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parga, C. J.; Rooyen, I. J.; Coryell, B. D.

Room temperature mechanical properties of electron beam welded and plain Zircaloy-4 sheet (1.6mm thick) have been measured and compared. Various welding parameters were utilized to join sheet material. Electron beam welded specimens and as-received sheet specimens show comparable mechanical properties. Zr-4 sheet displays anisotropy; tensile properties measured for transverse display higher elastic modulus, yield strength, reduction of area and slightly lower ductility than for the longitudinal (rolling direction). Higher welding power increases the alloy’s hardness, elastic modulus and yield strength, with a corresponding decrease in tensile strength and ductility. The hardness measured at weld is comparable to the parent metalmore » hardness. Hardness at heat-affected-zone is slightly higher. Electron microscopic examination shows distinct microstructure morphology and grain size at the weld zone, HAZ and parent metal. A correlation between welding parameters, mechanical properties and microstructural features was established for electron beam welded Zircaloy-4 sheet material.« less

Room temperature mechanical properties of electron beam welded zircaloy-4 sheet

DOE PAGES

Parga, C. J.; Rooyen, I. J.; Coryell, B. D.; ...

2017-11-04

Room temperature mechanical properties of electron beam welded and plain Zircaloy-4 sheet (1.6mm thick) have been measured and compared. Various welding parameters were utilized to join sheet material. Electron beam welded specimens and as-received sheet specimens show comparable mechanical properties. Zr-4 sheet displays anisotropy; tensile properties measured for transverse display higher elastic modulus, yield strength, reduction of area and slightly lower ductility than for the longitudinal (rolling direction). Higher welding power increases the alloy’s hardness, elastic modulus and yield strength, with a corresponding decrease in tensile strength and ductility. The hardness measured at weld is comparable to the parent metalmore » hardness. Hardness at heat-affected-zone is slightly higher. Electron microscopic examination shows distinct microstructure morphology and grain size at the weld zone, HAZ and parent metal. A correlation between welding parameters, mechanical properties and microstructural features was established for electron beam welded Zircaloy-4 sheet material.« less

High Velocity Burner Rig Oxidation and Thermal Fatigue Behavior of Si3N4- and SiC Base Ceramics to 1370 Deg C

NASA Technical Reports Server (NTRS)

Sanders, W. A.; Johnston, J. R.

1978-01-01

One SiC material and three Si3N4 materials including hot-pressed Si3N4 as a baseline were exposed in a Mach-1-gas-velocity burner rig simulating a turbine engine environment. Criteria for the materials selection were: potential for gas-turbine usage, near-net-shape fabricability and commercial/domestic availability. Cyclic exposures of test vanes up to 250 cycles (50 hr at temperature) were at leading-edge temperatures to 1370 C. Materials and batches were compared as to weight change, surface change, fluorescent penetrant inspection, and thermal fatigue behavior. Hot-pressed Si3N4 survived the test to 1370 C with slight weight losses. Two types of reaction-sintered Si3N4 displayed high weight gains and considerable weight-change variability, with one material exhibiting superior thermal fatigue behavior. A siliconized SiC showed slight weight gains, but considerable batch variability in thermal fatigue.

Sunlight penetration through the Martian polar caps: Effects on the thermal and frost budgets

NASA Technical Reports Server (NTRS)

Lindner, Bernhard Lee

1992-01-01

An energy balance model of the seasonal polar caps on Mars is modified to include penetration of solar radiation into and through the ice. Penetration of solar radiation has no effect on subsurface temperature or total frost sublimation if seasonal ice overlies a dust surface. An effect is noted for seasonal ice which overlies the residual polar caps. For the case of an exposed water-ice residual polar cap, the temperature at depth is calculated to be up to several degrees warmer and the calculated lifetime of seasonal CO2 frost is slightly lower when penetration of sunlight is properly treated in the model. For the case of a residual polar cap which is perennially covered by CO2 frost, the calculated lifetime of seasonal CO2 frost is very slightly increased as a result of sunlight penetration through the ice. Hence, penetration of sunlight into the ice helps to stabilize the observed dichotomy in the residual polar caps on Mars, although it is a small effect.

Sunlight penetration through the Martian polar caps - Effects on the thermal and frost budgets

NASA Technical Reports Server (NTRS)

Lindner, Bernhard L.

1992-01-01

An energy balance model of the seasonal polar caps on Mars is modified to include penetration of solar radiation into and through the ice. Penetration of solar radiation has no effect on subsurface temperature or total frost sublimation if seasonal ice overlies a dust surface. An effect is noted for seasonal ice which overlies the residual polar caps. For the case of an exposed water-ice residual polar cap, the temperature at depth is calculated to be up to several degrees warmer, and the calculated lifetime of seasonal CO2 frost is slightly lower when penetration of sunlight is properly treated in the model. For the case of a residual polar cap which is perennially covered by CO2 frost, the calculated lifetime of seasonal CO2 frost is very slightly increased as a result of sunlight penetration through the ice. Hence, penetration of sunlight into the ice helps to stabilize the observed dichotomy in the residual polar caps on Mars, although it is a small effect.

Differential regulation of IL-23 production in M1 macrophages by TIR8/SIGIRR through TLR4- or TLR7/8-mediated signaling.

PubMed

Yamaguchi, Rui; Sakamoto, Arisa; Yamamoto, Takatoshi; Narahara, Shinji; Sugiuchi, Hiroyuki; Yamaguchi, Yasuo

2017-11-01

Cross-talks between toll-like receptors (TLRs) including various negative regulatory mechanisms are many unknown. We investigated the differential mechanism of IL-23 production in M1 macrophages by single immunoglobulin interleukin-1 receptor-related (SIGIRR) molecule through TLR4 or TLR7/8. IL-12p40 production by M1 macrophages pretreated with human neutrophil elastase (HNE) was synergistically enhanced IL-12p40, but not IL-23 production, after exposure to lipopolysaccharide (LPS). LPS (a TLR4 agonist) induced a slight increase of IL-23 production, while Resiquimod (a TLR7/8 agonist) significantly enhanced IL-23 production. Expression of SIGIRR protein, a negative regulator of TLR4, was higher in M1 macrophages than in monocytes. Interestingly, SIGIRR siRNA induced a slight increment of IL-23 production after exposure of macrophages to LPS, while IL-23 production in response to Resiquimod was significantly upregulated by SIGIRR siRNA. Silencing SIGIRR enhanced IRF4 protein level determined by western blotting or ELISA. IRF4 siRNA dramatically restored IL-23 production after exposure to Resiquimod in macrophages transfected with SIGIRR siRNA. In conclusion, production of IL-23 is differentially regulated in M1 macrophages by SIGIRR through TLR4- or TLR7/8-mediated signaling. SIGIRR is both a negative regulator of TLR4 and a positive regulator of TLR7/8. Copyright © 2017 Elsevier Ltd. All rights reserved.

Ba(1-x)Sr(x)Zn2Si2O7--A new family of materials with negative and very high thermal expansion.

PubMed

Thieme, Christian; Görls, Helmar; Rüssel, Christian

2015-12-15

The compound BaZn2Si2O7 shows a high coefficient of thermal expansion up to a temperature of 280 °C, then a transition to a high temperature phase is observed. This high temperature phase exhibits negative thermal expansion. If Ba(2+) is successively replaced by Sr(2+), a new phase with a structure, similar to that of the high temperature phase of BaZn2Si2O7, forms. At the composition Ba0.8Sr0.2Zn2Si2O7, this new phase is completely stabilized. The crystal structure was determined with single crystal X-ray diffraction using the composition Ba0.6Sr0.4Zn2Si2O7, which crystallizes in the orthorhombic space group Cmcm. The negative thermal expansion is a result of motions and distortions inside the crystal lattice, especially inside the chains of ZnO4 tetrahedra. Dilatometry and high temperature X-ray powder diffraction were used to verify the negative thermal expansion. Coefficients of thermal expansion partially smaller than -10·10(-6) K(-1) were measured.

Multi-year analysis of distributed glacier mass balance modelling and equilibrium line altitude on King George Island, Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Falk, Ulrike; López, Damián A.; Silva-Busso, Adrián

2018-04-01

The South Shetland Islands are located at the northern tip of the Antarctic Peninsula (AP). This region was subject to strong warming trends in the atmospheric surface layer. Surface air temperature increased about 3 K in 50 years, concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. The positive trend in surface air temperature has currently come to a halt. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K (100 m)-1) and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns. The increased mesocyclonic activity during the wintertime over the past decades in the study area results in intensified advection of warm, moist air with high temperatures and rain and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. Its impact on winter accumulation results in the observed negative mass balance estimates. Six years of continuous glaciological measurements on mass balance stake transects as well as 5 years of climatological data time series are presented and a spatially distributed glacier energy balance melt model adapted and run based on these multi-year data sets. The glaciological surface mass balance model is generally in good agreement with observations, except for atmospheric conditions promoting snow drift by high wind speeds, turbulence-driven snow deposition and snow layer erosion by rain. No drift in the difference between simulated mass balance and mass balance measurements can be seen over the course of the 5-year model run period. The winter accumulation does not suffice to compensate for the high variability in summer ablation. The results are analysed to assess changes in meltwater input to the coastal waters, specific glacier mass balance and the equilibrium line altitude (ELA). The Fourcade Glacier catchment drains into Potter cove, has an area of 23.6 km2 and is glacierized to 93.8 %. Annual discharge from Fourcade Glacier into Potter Cove is estimated to q ¯ = 25±6 hm3 yr-1 with the standard deviation of 8 % annotating the high interannual variability. The average ELA calculated from our own glaciological observations on Fourcade Glacier over the time period 2010 to 2015 amounts to 260±20 m. Published studies suggest rather stable conditions of slightly negative glacier mass balance until the mid-1980s with an ELA of approx. 150 m. The calculated accumulation area ratio suggests dramatic changes in the future extent of the inland ice cap for the South Shetland Islands.

Molecular deformation and stress-strain behavior of poly(bisphenol-A-diphenyl sulfone)

NASA Technical Reports Server (NTRS)

Hong, S.-D.; Chung, S. Y.; Fedors, R. F.

1983-01-01

The strain-birefringence response of poly(bisphenol-A-diphenyl sulfone) is found to be independent of temperature at temperatures below -100 C; at higher temperatures, the response becomes slightly dependent on temperature, with lower birefringence seen at higher temperatures. The stress-strain behavior and the stress-birefringence response both depend on temperature over the entire testing temperature range (-179 C to 150 C) studied; this dependence, however, is not pronounced. The evidence is seen as suggesting that the polymer molecules respond to deformation by undergoing conformational rearrangements; the mode of the molecular deformation remains unchanged for temperatures of -100 C or lower. At higher temperatures, the average length of the chain segments involved in the rearrangement increases. The stress-strain response is attributed mainly to chain orientation. The entropic contribution deriving from chain orientation at temperatures below -100 C is still substantial. The modest temperature dependence of the stress-strain response suggests that the energy barriers for the chain segments involved in the rearrangement are relatively low.

Studies of Energy-Relevant Materials by Nuclear Magnetic Resonance

NASA Astrophysics Data System (ADS)

Cui, Jinfang

In this thesis, we have used nuclear magnetic resonance (NMR) as a local probe to microscopically study three different families of energy-relevant complex materials, namely the 122 Fe-based superconductors Ca(Fe1-xCox)2As2, GeTe-based thermoelectric tellurides GeTe and detonation nanodiamond. In Chapter 3 and Chapter 4, we investigated the Co substitution effects on static and dynamic magnetic properties of the single-crystalline Ca(Fe 1-xCox)2As2 (x = 0, 0.023, 0.028, 0.033, 0.059) via 75As NMR and resistivity measurements. Robustness of the Fe magnetic moments was evidenced by only slight decreases of Hint, although T N is strongly suppressed with Co substitution in antiferromagnetic (AFM) state. In the paramagnetic (PM) state, the temperature dependence of Knight shift K for all crystals shows similar T-dependence of magnetic susceptibility chi. The spin fluctuations with the q = 0 components are suppressed with Delta/k B. On the other hand, the growth of the stripe-type AFM fluctuations with q = (pi, 0) or (0, pi) upon cooling in the PM state for all samples is evidenced by the T-dependence of (1/ T1Tchi). A pseudogap-like phenomenon, i.e., suppression of the AFM spin fluctuations, was discovered with decreasing temperature below a x-independent characteristic temperature T* ( 100 K) in samples with x ≥ 0.028. In addition, clear evidence for the coexistence and competition of the stripe-type antiferromagnetic and ferromagnetic (FM) spin correlations was given by modified Korringa ratio analysis in Chapter 4. In Chapter 5, we have carried out 125Te NMR measurements to study the electronic properties of Ge50Te50, Ag 2Ge48Te50 and Sb2Ge48Te 50. NMR shift K and 1/T1T of Ge50Te50 are nearly temperature independent at T < 50 K and both increase slightly with increasing temperature at high temperatures. A two-band model, where one band overlaps the Fermi level and the other band is separated from the Fermi level by an energy gap, has been used to explain these behaviors. The first-principle calculation revealed that the metallic band originates from the Ge vacancy while the semiconductor-like band may be related to the fine structure of the density of states near the Fermi level. At low temperature, we found conduction carriers are free carriers with no significant electron correlations, while Korringa ratio increases slightly at high temperature, suggesting the slight enhancement of the electron correlation. In Chapter 6 and Chapter 7, we have used 13C NMR spectral editing technique to accurately analyze the surface composition of pristine purified, heat-treated (at 800 °C), and air-oxidized detonation nanodiamond. We have resolved ten peaks of C=O, COO, C=C, O-C-O, C-OH, C-N, CH, subsurface C, core C, and C-C-N. The aromatic fraction is only 1.1%, which corresponds to less than 1/20 of an aromatic surface layer. We have also shown that other surface functional groups (CH, COH, etc.) accounts for most of the surface sites, making up 11.5% of all C in pristine nanodiamond. The signal of carbon bonded to nitroge was observed selectively based on increased chemical-shift anisotropy due to breaking of the local symmetry. Furthermore, we used modified 13C{1H} REDOR experiments to observe the signals from carbons at different depths from the surface and estimate their quantities.

On the possibility of negative activation energies in bimolecular reactions

NASA Technical Reports Server (NTRS)

Jaffe, R. L.

1978-01-01

The temperature dependence of the rate constants for model reacting systems was studied to understand some recent experimental measurements which imply the existence of negative activation energies. A collision theory model and classical trajectory calculations are used to demonstrate that the reaction probability can vary inversely with collision energy for bimolecular reactions occurring on attractive potential energy surfaces. However, this is not a sufficient condition to ensure that the rate constant has a negative temperature dependence. On the basis of these calculations, it seems unlikely that a true bimolecular reaction between neutral molecules will have a negative activation energy.

Estimates of Ice Sheet Mass Balance from Satellite Altimetry: Past and Future

NASA Technical Reports Server (NTRS)

Zwally, H. Jay; Zukor, Dorothy J. (Technical Monitor)

2001-01-01

A major uncertainty in predicting sea level rise is the sensitivity of ice sheet mass balance to climate change, as well as the uncertainty in present mass balance. Since the annual water exchange is about 8 mm of global sea level equivalent, the 20% uncertainty in current mass balance corresponds to 1.6 mm/yr in sea level change. Furthermore, estimates of the sensitivity of the mass balance to temperature change range from perhaps as much as - 10% to + 10% per K. A principal purpose of obtaining ice sheet elevation changes from satellite altimetry has been estimation of the current ice sheet mass balance. Limited information on ice sheet elevation change and their implications about mass balance have been reported by several investigators from radar altimetry (Seasat, Geosat, ERS-1&2). Analysis of ERS-1&2 data over Greenland for 7 years from 1992 to 1999 shows mixed patterns of ice elevation increases and decreases that are significant in terms of regional-scale mass balances. Observed seasonal and interannual variations in ice surface elevation are larger than previously expected because of seasonal and interannUal variations in precipitation, melting, and firn compaction. In the accumulation zone, the variations in firn compaction are modeled as a function of temperature leaving variations in precipitation and the mass balance trend. Significant interannual variations in elevation in some locations, in particular the difference in trends from 1992 to 1995 compared to 1995 to 1999, can be explained by changes in precipitation over Greenland. Over the 7 years, trends in elevation are mostly positive at higher elevations and negative at lower elevations. In addition, trends for the winter seasons (from a trend analysis through the average winter elevations) are more positive than the corresponding trends for the summer. At lower elevations, the 7-year trends in some locations are strongly negative for summer and near zero or slightly positive for winter. These observations also demonstrate the potential for relating the variability in mass balance to changes in precipitation, temperature, and melting. Beginning in January 2002, NASA's ICESat laser altimeter mission will provide significantly better elevation accuracy and spatial coverage to 86E latitude and to the margins of the ice sheets.

Peripheral temperature drop in response to anticipation and consumption of a signaled palatable reward in laying hens (Gallus domesticus).

PubMed

Moe, Randi Oppermann; Stubsjøen, Solveig Marie; Bohlin, Jon; Flø, Andreas; Bakken, Morten

2012-06-25

The present study describes effects of anticipation and consumption of a palatable reward on comb surface temperature. The purpose was to investigate temperature responses as a potential physiological indicator of positive emotional states in laying hens. A rise in body temperature in response to stimuli predictive of or during exposure to unpleasant events has been interpreted as evidence of emotions in mammals and avians. However, this phenomenon has so far only been studied during anticipation of or exposure to negative events; i.e., emotions of a negative valence. Infrared thermography was used to record potential alterations in comb surface temperature to a conditioned cue signaling a reward (mealworms) and during reward delivery. On average, comb temperature dropped 1.5 °C (95% CI: +/-1.2 °C) after exposure to CS and consumption of reward (p~0.0014) when initial comb temperature was above 30 °C. Such temperature drop indicates a peripheral vasoconstriction and has clear resemblances to emotional fever as seen during negative emotional states. Thus, we propose that a drop in peripheral temperature reflects emotional arousal more than emotional valence. Substantial temperature responses due to diet-induced thermogenesis were found, further emphasizing a cautious interpretation of altered comb temperature in studies of animal welfare. Copyright © 2012 Elsevier Inc. All rights reserved.

Bias-induced conformational switching of supramolecular networks of trimesic acid at the solid-liquid interface

NASA Astrophysics Data System (ADS)

Ubink, J.; Enache, M.; Stöhr, M.

2018-05-01

Using the tip of a scanning tunneling microscope, an electric field-induced reversible phase transition between two planar porous structures ("chickenwire" and "flower") of trimesic acid was accomplished at the nonanoic acid/highly oriented pyrolytic graphite interface. The chickenwire structure was exclusively observed for negative sample bias, while for positive sample bias only the more densely packed flower structure was found. We suggest that the slightly negatively charged carboxyl groups of the trimesic acid molecule are the determining factor for this observation: their adsorption behavior varies with the sample bias and is thus responsible for the switching behavior.

Local and global stability for Lotka-Volterra systems with distributed delays and instantaneous negative feedbacks

NASA Astrophysics Data System (ADS)

Faria, Teresa; Oliveira, José J.

This paper addresses the local and global stability of n-dimensional Lotka-Volterra systems with distributed delays and instantaneous negative feedbacks. Necessary and sufficient conditions for local stability independent of the choice of the delay functions are given, by imposing a weak nondelayed diagonal dominance which cancels the delayed competition effect. The global asymptotic stability of positive equilibria is established under conditions slightly stronger than the ones required for the linear stability. For the case of monotone interactions, however, sharper conditions are presented. This paper generalizes known results for discrete delays to systems with distributed delays. Several applications illustrate the results.

Perceptions of temperature, moisture and comfort in clothing during environmental transients.

PubMed

Li, Y

2005-02-22

A study has been carried out to investigate the psychophysical mechanisms of the perception of temperature and moisture sensations in clothing during environmental transients. A series of wear trials was conducted to measure the psychological perception of thermal and moisture sensations and the simultaneous temperature and humidity at the skin surface, fabric surface and in the clothing under simulated moderate rain conditions. Jumpers made from wool and acrylic fibres were used in the trial. Analysis has been carried out to study the relationship between psychological perceptions of temperature and moisture and the objectively measured skin and fabric temperatures and relative humidity in clothing microclimate. The perception of warmth seems to follow Fechner's law and Stevens' power law, having positive relationships with the skin temperature and fabric temperatures. The perception of dampness appears to follow Fechner's law more closely than Stevens' power law with a negative relationship with skin temperature, and is nonlinearly and positively correlated with relative humidity in clothing microclimate. The perception of comfort is positively related to the perception of warmth and negatively to the perception of dampness. This perception of comfort is positively related to the skin temperature, which appears to follow both Fechner's law and Stevens' law, also non-linearly and negatively related to relative humidity in clothing microclimate.

Negative thermal expansion and anomalies of heat capacity of LuB 50 at low temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Novikov, V. V.; Zhemoedov, N. A.; Matovnikov, A. V.

2015-07-20

Heat capacity and thermal expansion of LuB 50 boride were experimentally studied in the 2–300 K temperature range. The data reveal an anomalous contribution to the heat capacity at low temperatures. The value of this contribution is proportional to the first degree of temperature. It was identified that this anomaly in heat capacity is caused by the effect of disorder in the LuB 50 crystalline structure and it can be described in the soft atomic potential model (SAP). The parameters of the approximation were determined. The temperature dependence of LuB 50 heat capacity in the whole temperature range was approximatedmore » by the sum of SAP contribution, Debye and two Einstein components. The parameters of SAP contribution for LuB 50 were compared to the corresponding values for LuB 66, which was studied earlier. Negative thermal expansion at low temperatures was experimentally observed for LuB 50. The analysis of the experimental temperature dependence for the Gruneisen parameter of LuB 50 suggested that the low-frequency oscillations, described in SAP mode, are responsible for the negative thermal expansion. As a result, the glasslike character of the behavior of LuB 50 thermal characteristics at low temperatures was confirmed.« less

Open loop increase in trunk temperature produced by face cooling in working humans.

PubMed Central

Cabanac, M; Caputa, M

1979-01-01

1. Five human subjects pedalled on a bicyle ergometer for at least two 74 min periods at 10 degrees C ambient temperature. During the first period the subjects cycled for 42 min with face fanning, followed by 32 min with the head thermally insulated. In the second period, this procedure was reversed. Oesophageal (tes), tympanic (Tty), forehead and hand skin temperatures were recorded. In addition, heart rate (H.R.) was counted throughout the experiments, and the technique of perceptual rating of cool and warm stimuli was used in order to appreciate whether the subjects were hypo-, normo-, or hyperthermic. 2. Face fanning resulted in decreased Tty, decreased H.R., mild skin vasoconstriction but increased Tes. 3. Head covering resulted in increased Tty and H.R., while Tes decreased slightly, due to peripheral vasodilatation. 4. When their faces were being fanned so that Tty was low and Tes was high, the subjects gave slightly hypothermic ratings. Ratings were clearly hyperthermic when their heads were covered and Tty was high and Tes was low. 5. The close correlation between vasomotor response and H.R. on the one hand and Tty on the other confirms that this variable is a better approximation of regulated core temperature than Tes. 6. Increase in Tes during face fanning and decrease in Tes during face insulation is new evidence for the possibility of the human brian being cooled during exercise by cool blood returning from the face. 7. We suggest that this selective brain cooling determines the apparent upper resetting of core temperature during exercise while brain temperature remains precisely regulated and constant. PMID:458648

High-pressure tolerance of earthworm fibrinolytic and digestive enzymes.

PubMed

Akazawa, Shin-Ichi; Tokuyama, Haruka; Sato, Shunsuke; Watanabe, Toshinori; Shida, Yosuke; Ogasawara, Wataru

2018-02-01

Earthworms contain several digestive and therapeutic enzymes that are beneficial to our health and useful for biomass utilization. Specifically, earthworms contain potent fibrinolytic enzymes called lumbrokinases, which are highly stable even at room temperature and remain active in dried earthworm powder. However, the high-temperature sterilization method leads to the inactivation of enzymes. Therefore, we investigated the effect of high-pressure treatment (HPT) (from 0.1 MPa to 500 MPa at 25°C and 50°C) on the enzymatic activity of lumbrokinase (LK), α-amylase (AMY), endoglucanase (EG), β-glucosidase (BGL), and lipase (LP) of the earthworm Eisenia fetida, Waki strain, and its sterilization ability in producing dietary supplement. LK showed thermo- and high-pressure tolerance. In addition, HPT may have resulted in pressure-induced stabilization and activation of LK. Although AMY activity was maintained up to 400 MPa at 25°C, the apparent activity decreased slightly at 50°C with HPT. EG showed almost the same pattern as AMY. However, it is possible that the effects of temperature and pressure compensated each other under 100 MPa at 50°C. BGL was shown to be a pressure- and temperature-sensitive enzyme, and LP showed a thermo- and high-pressure tolerance. The slight decrease in apparent activity occurred under 200 MPa at both temperatures. Furthermore, the low-temperature and pressure treatment completely sterilized the samples. These results provide a basis for the development of a novel earthworm dietary supplement with fibrinolytic and digestive activity and of high-pressure-tolerant enzymes to be used for biomass pretreatment. Copyright © 2017 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

Growth of carbon nanotubes on fully processed silicon-on-insulator CMOS substrates.

PubMed

Haque, M Samiul; Ali, S Zeeshan; Guha, P K; Oei, S P; Park, J; Maeng, S; Teo, K B K; Udrea, F; Milne, W I

2008-11-01

This paper describes the growth of Carbon Nanotubes (CNTs) both aligned and non-aligned on fully processed CMOS substrates containing high temperature tungsten metallization. While the growth method has been demonstrated in fabricating CNT gas sensitive layers for high temperatures SOI CMOS sensors, it can be employed in a variety of applications which require the use of CNTs or other nanomaterials with CMOS electronics. In our experiments we have grown CNTs both on SOI CMOS substrates and SOI CMOS microhotplates (suspended on membranes formed by post-CMOS deep RIE etching). The fully processed SOI substrates contain CMOS devices and circuits and additionally, some wafers contained high current LDMOSFETs and bipolar structures such as Lateral Insulated Gate Bipolar Transistors. All these devices were used as test structures to investigate the effect of additional post-CMOS processing such as CNT growth, membrane formation, high temperature annealing, etc. Electrical characterisation of the devices with CNTs were performed along with SEM and Raman spectroscopy. The CNTs were grown both at low and high temperatures, the former being compatible with Aluminium metallization while the latter being possible through the use of the high temperature CMOS metallization (Tungsten). In both cases we have found that there is no change in the electrical behaviour of the CMOS devices, circuits or the high current devices. A slight degradation of the thermal performance of the CMOS microhotplates was observed due to the extra heat dissipation path created by the CNT layers, but this is expected as CNTs exhibit a high thermal conductance. In addition we also observed that in the case of high temperature CNT growth a slight degradation in the manufacturing yield was observed. This is especially the case where large area membranes with a diameter in excess of 500 microns are used.

Simulation of hydrodynamics, temperature, and dissolved oxygen in Table Rock Lake, Missouri, 1996-1997

USGS Publications Warehouse

Green, W. Reed; Galloway, Joel M.; Richards, Joseph M.; Wesolowski, Edwin A.

2003-01-01

Outflow from Table Rock Lake and other White River reservoirs support a cold-water trout fishery of substantial economic yield in south-central Missouri and north-central Arkansas. The Missouri Department of Conservation has requested an increase in existing minimum flows through the Table Rock Lake Dam from the U.S. Army Corps of Engineers to increase the quality of fishable waters downstream in Lake Taneycomo. Information is needed to assess the effect of increased minimum flows on temperature and dissolved- oxygen concentrations of reservoir water and the outflow. A two-dimensional, laterally averaged, hydrodynamic, temperature, and dissolved-oxygen model, CE-QUAL-W2, was developed and calibrated for Table Rock Lake, located in Missouri, north of the Arkansas-Missouri State line. The model simulates water-surface elevation, heat transport, and dissolved-oxygen dynamics. The model was developed to assess the effects of proposed increases in minimum flow from about 4.4 cubic meters per second (the existing minimum flow) to 11.3 cubic meters per second (the increased minimum flow). Simulations included assessing the effect of (1) increased minimum flows and (2) increased minimum flows with increased water-surface elevations in Table Rock Lake, on outflow temperatures and dissolved-oxygen concentrations. In both minimum flow scenarios, water temperature appeared to stay the same or increase slightly (less than 0.37 ?C) and dissolved oxygen appeared to decrease slightly (less than 0.78 mg/L) in the outflow during the thermal stratification season. However, differences between the minimum flow scenarios for water temperature and dissolved- oxygen concentration and the calibrated model were similar to the differences between measured and simulated water-column profile values.

Heat Coma Temperature and Supercooling Point in Oceanic Sea Skaters (Heteroptera, Gerridae)

PubMed Central

Harada, Tetsuo

2018-01-01

Heat coma temperatures (HCTs) and super cooling points (SCPs) were examined for nearly 1000 oceanic sea skaters collected from in the Pacific and Indian Oceans representing four Halobates species; H. germanus, H. micans, H. sericeus, and H. sp. Analysis was conducted using the entire dataset because a negative correlation was seen between the HCTs and SCPs in all four species. A weak negative correlation was seen between HCTs and SCPs with a cross tolerance between warmer HCTs and colder SCPs. The weakness of the correlation may be due to the large size of the dataset and to the variability in ocean surface temperature. The negative correlation does however suggest that oceanic sea skaters may have some form of cross tolerance with a common physiological mechanism for their high and low temperature tolerances. PMID:29401693

Effect of quantum dispersion on the radial distribution function of a one-component sticky-hard-sphere fluid

NASA Astrophysics Data System (ADS)

Fantoni, Riccardo

2018-04-01

In this short communication we present a possible scheme to study the radial distribution function of the quantum slightly polydisperse Baxter sticky hard sphere liquid at finite temperature thorugh a semi-analytical method devised by Chandler and Wolynes.

Corrosion of aluminum alloys by chlorinated hydrocarbon/methanol mixtures

NASA Technical Reports Server (NTRS)

De Forest, W. S.

1967-01-01

Laboratory investigations show that water-free mixtures of Freon MF /trichlorofluoromethane/ and methanol vigorously attack aluminum alloys which contain significant amounts of copper. Freon MF alone did not attack the aluminum alloys at room temperature. Pure methanol had only a slight corrosive effect on the alloy.

Stress relaxation and mechanical properties of RL-1973 and PD-200-16 silicone resin sponge materials

NASA Technical Reports Server (NTRS)

Saylak, D.; Noel, J. S.; Ham, J. S.; Mccoy, R.

1975-01-01

Stress relaxation tests were conducted by loading specimens in double-lap shear to a preselected strain level and monitoring the decay of stress with time. The stress relaxation response characteristics were measured over a temperature range of 100 to 300 K and four strain levels. It is concluded that only a slight amount of stress relaxation was observed, and the stiffness increased approximately two orders of magnitude over the range of temperatures.

A Cooling System for Impermeable Clothing

PubMed Central

Gleeson, J. P.; Pisani, J. F.

1967-01-01

A self-contained conditioning unit for use with impermeable protective clothing is described. The pack-mounted unit weighing 10 lb. (4·5 kg.) will enable a wearer to work for approximately one hour at temperatures in the zone of evaporative regulation. At 40·6°C. (105°F.), the temperature at which the unit was tested, the heat load imposed by the complete assembly of suit, conditioning unit, and ducting is only slightly higher than that imposed by the wearing of shorts. Images PMID:6028716

Pion decay constant and the {rho}-meson mass at finite temperature in hidden local symmetry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harada, M.; Shibata, A.

1997-06-01

We study the temperature dependence of the pion decay constant and {rho}-meson mass in the hidden local symmetry model at one loop. Using the standard imaginary time formalism, we include the thermal effect of the {rho} meson as well as that of the pion. We show that the pion gives a dominant contribution to the pion decay constant and the {rho}-meson contribution slightly decreases the critical temperature. The {rho}-meson pole mass increases as T{sup 4}/m{sub {rho}}{sup 2} at low temperature, dominated by the pion-loop effect. At high temperature, although the pion-loop effect decreases the {rho}-meson mass, the {rho}-loop contribution overcomesmore » the pion-loop contribution and the {rho}-meson mass increases with temperature. We also show that the conventional parameter a is stable as the temperature increases. {copyright} {ital 1997} {ital The American Physical Society}« less

Geometrically frustrated GdInO3: An exotic system to study negative thermal expansion and spin-lattice coupling

NASA Astrophysics Data System (ADS)

Paul, Barnita; Chatterjee, Swastika; Roy, Anushree; Midya, A.; Mandal, P.; Grover, Vinita; Tyagi, A. K.

2017-02-01

In this article, we report negative thermal expansion and spin frustration in hexagonal GdInO3. Rietveld refinements of the x-ray diffraction patterns reveal that the negative thermal expansion in the temperature range of 50-100 K stems from the triangular lattice of Gd3 + ions. The downward deviation of the low-temperature inverse susceptibility (χ-1) versus T plot from the Curie-Weiss law and the large value of the ratio, | θCW|/ TN>28 , where θCW and TN are respectively Curie-Weiss and Neel temperature, indicate a strong spin frustration, which inhibits long-range magnetic ordering down to 1.8 K. Magnetostriction measurements clearly demonstrate a spin-lattice coupling in the system. Low-temperature anomalous phonon softening, as obtained from temperature-dependent Raman measurements, also reveals the same. Our experimental observations are supported by first-principles density functional theory calculations of the electronic and phonon dispersion in GdInO3. The calculations suggest that the GdInO3 lattice is highly frustrated at low temperature. Further, the calculated normal mode frequencies of the Gd-related Γ point phonon modes reveal significant magnetoelastic coupling in this system. The competitive role of magnetic interaction energy and thermal stabilization energy in determining the change in interatomic distances is the possible origin for the negative thermal expansion in GdInO3 over a limited range of temperature.

Flat-roof phenomenon of dynamic equilibrium phase in the negative bias temperature instability effect on a power MOSFET

NASA Astrophysics Data System (ADS)

Zhang, Yue; Zhuo, Qing-Qing; Liu, Hong-Xia; Ma, Xiao-Hua; Hao, Yue

2014-05-01

The effect of the static negative bias temperature (NBT) stress on a p-channel power metal—oxide—semiconductor field-effect transistor (MOSFET) is investigated by experiment and simulation. The time evolution of the negative bias temperature instability (NBTI) degradation has the trend predicted by the reaction—diffusion (R—D) model but with an exaggerated time scale. The phenomena of the flat-roof section are observed under various stress conditions, which can be considered as the dynamic equilibrium phase in the R—D process. Based on the simulated results, the variation of the flat-roof section with the stress condition can be explained.

Ongoing climatic extreme dynamics in Siberia

NASA Astrophysics Data System (ADS)

Gordov, E. P.; Shulgina, T. M.; Okladnikov, I. G.; Titov, A. G.

2013-12-01

Ongoing global climate changes accompanied by the restructuring of global processes in the atmosphere and biosphere are strongly pronounced in the Northern Eurasia regions, especially in Siberia. Recent investigations indicate not only large changes in averaged climatic characteristics (Kabanov and Lykosov, 2006, IPCC, 2007; Groisman and Gutman, 2012), but more frequent occurrence and stronger impacts of climatic extremes are reported as well (Bulygina et al., 2007; IPCC, 2012: Climate Extremes, 2012; Oldenborh et al., 2013). This paper provides the results of daily temperature and precipitation extreme dynamics in Siberia for the last three decades (1979 - 2012). Their seasonal dynamics is assessed using 10th and 90th percentile-based threshold indices that characterize frequency, intensity and duration of climatic extremes. To obtain the geographical pattern of these variations with high spatial resolution, the sub-daily temperature data from ECMWF ERA-Interim reanalysis and daily precipitation amounts from APHRODITE JMA dataset were used. All extreme indices and linear trend coefficients have been calculated using web-GIS information-computational platform Climate (http://climate.scert.ru/) developed to support collaborative multidisciplinary investigations of regional climatic changes and their impacts (Gordov et al., 2012). Obtained results show that seasonal dynamics of daily temperature extremes is asymmetric for tails of cold and warm temperature extreme distributions. Namely, the intensity of warming during cold nights is higher than during warm nights, especially at high latitudes of Siberia. The similar dynamics is observed for cold and warm day-time temperatures. Slight summer cooling was observed in the central part of Siberia. It is associated with decrease in warm temperature extremes. In the southern Siberia in winter, we also observe some cooling mostly due to strengthening of the cold temperature extremes. Changes in daily precipitation extremes are spatially inhomogeneous. The largest increase in frequency and intensity of heavy precipitation is observed in the north of East Siberia. Negative trends related to precipitation amount decrease are found in the central West Siberia and in the south of East Siberia. The authors acknowledge partial financial support for this research from the Russian Foundation for Basic Research projects (11-05-01190 and 13-05-12034), SB RAS Integration project 131 and project VIII.80.2.1., the Ministry of Education and Science of the Russian Federation contract 8345 and grant of the President of Russian Federation (decree 181).

Observing changes in atmospheric heat content

NASA Astrophysics Data System (ADS)

Balcerak, Ernie

2011-10-01

Globally, air temperatures near the surface over land have been rising in recent decades, and this has been presented as solid evidence of global warming. However, some scientists have argued that total heat content (energy), rather than temperature, should be used as a metric of warming trends. Surface air temperature is only one component of the energy content of the surface atmosphere—kinetic energy and latent heat also contribute. Peterson et al. present the first study to use observational data to estimate global changes in surface energy of the atmosphere over time. They include temperature, kinetic energy, and latent heat in their analysis. The authors found that total global surface atmospheric energy and heat content have increased since the 1970s, even though kinetic energy decreased slightly and in some regions latent heat declined while temperature increased.

Optimum Temperature for Storage of Fruit and Vegetables with Reference to Chilling Injury

NASA Astrophysics Data System (ADS)

Murata, Takao

Cold storage is an important technique for preserving fresh fruit and vegetables. Deterioration due to ripening, senescence and microbiological disease can be retarded by storage at optimum temperature being slightly above the freezing point of tissues of fruit and vegetables. However, some fruit and vegetables having their origins in tropical or subtropical regions of the world are subject to chilling injury during transportation, storage and wholesale distribution at low temperature above freezing point, because they are usually sensitive to low temperature in the range of 15&digC to 0°C. This review will focus on the recent informations regarding chilling injury of fruit and vegetables, and summarize the optimum temperature for transportation and storage of fruit and vegetables in relation to chilling injury.

Heat flux microsensor measurements and calibrations

NASA Technical Reports Server (NTRS)

Terrell, James P.; Hager, Jon M.; Onishi, Shinzo; Diller, Thomas E.

1992-01-01

A new thin-film heat flux gage has been fabricated specifically for severe high temperature operation using platinum and platinum-10 percent rhodium for the thermocouple elements. Radiation calibrations of this gage were performed at the AEDC facility over the available heat flux range (approx. 1.0 - 1,000 W/cu cm). The gage output was linear with heat flux with a slight increase in sensitivity with increasing surface temperature. Survivability of gages was demonstrated in quench tests from 500 C into liquid nitrogen. Successful operation of gages to surface temperatures of 750 C has been achieved. No additional cooling of the gages is required because the gages are always at the same temperature as the substrate material. A video of oxyacetylene flame tests with real-time heat flux and temperature output is available.

Infrared spectroscopic studies of the effect of elevated temperature on the association of pyroglutamic acid with clay and other minerals

NASA Astrophysics Data System (ADS)

Macklin, John W.; White, David H.

Fourier transform i.r. measurements of L-pyroglutamic acid dispersed in a matrix of a clay, silica or alumina have been obtained at various temperatures between 25 and 220°C. The i.r. spectrum of L-pyroglutamic acid varies in a manner slightly dependent upon the matrix material and shows considerable change as the temperature of the mixtures is increased. The differences in the spectrum at elevated temperatures are explained in terms of a chemical reaction between hydroxyl groups in the matrix and the carboxylic acid. The i.r. spectra of trimethylsilyl derivatives of L-pyroglutamic acid and aluminum pyroglutamate were also measured to assist the understanding of spectra and interpretation of the spectral changes dependent upon increasing temperature.

Mechanical properties of a fiberglass prepreg system at cryogenic and other temperatures

NASA Technical Reports Server (NTRS)

Klich, P. J.; Cockrell, C. E.

1982-01-01

The compressor driving the flow in the National Transonic Facility, which is nearing completion at the Langley Research Center, has 25 fiberglass blades. E-glass cloth with a pre-impregnated epoxy resin has been selected as the material for the fan blades because of its low cost, high damping, and fatigue resistance. A complete characterization is presented of this fan blade fiberglass system at temperatures of 367 K, room temperature, and 89 K. The characterization test results suggest that the material follows the general trends of metals and other glass-reinforced plastics at cryogenic temperatures. A slight diminution in strength was observed at the elevated temperature. The tests included the following: tensile, compression, fatigue, inplane shear, interlaminar shear, thermal expansion, creep, and thermal cycle.

Stability of peptides in high-temperature aqueous solutions

NASA Astrophysics Data System (ADS)

Shock, Everett L.

1992-09-01

Estimated standard molal thermodynamic properties of aqueous dipeptides and their constituent amino acids indicate that temperature increases correspond to increased stability of peptide bonds relative to hydrolysis reactions. Pressure increases cause slight decreases in peptide bond stability, which are generally offset by greater stability caused by temperature increases along geothermal gradients. These calculations suggest that peptides, polypeptides, and proteins may survive hydrothermal alteration of organic matter depending on the rates of the hydrolysis reactions. Extremely thermophilic organisms may be able to take advantage of the decreased energy required to form peptide bonds in order to maintain structural proteins and enzymes at elevated temperatures and pressures. As the rates of hydrolysis reactions increase with increasing temperature, formation of peptide bonds may become a facile process in hydrothermal systems and deep in sedimentary basins.

Forest fire danger index based on modifying Nesterov Index, fuel, and anthropogenic activities using MODIS TERRA, AQUA and TRMM satellite datasets

NASA Astrophysics Data System (ADS)

Suresh Babu, K. V.; Roy, Arijit; Ramachandra Prasad, P.

2016-05-01

Forest fire has been regarded as one of the major causes of degradation of Himalayan forests in Uttarakhand. Forest fires occur annually in more than 50% of forests in Uttarakhand state, mostly due to anthropogenic activities and spreads due to moisture conditions and type of forest fuels. Empirical drought indices such as Keetch-Byram drought index, the Nesterov index, Modified Nesterov index, the Zhdanko index which belongs to the cumulative type and the Angstrom Index which belongs to the daily type have been used throughout the world to assess the potential fire danger. In this study, the forest fire danger index has been developed from slightly modified Nesterov index, fuel and anthropogenic activities. Datasets such as MODIS TERRA Land Surface Temperature and emissivity (MOD11A1), MODIS AQUA Atmospheric profile product (MYD07) have been used to determine the dew point temperature and land surface temperature. Precipitation coefficient has been computed from Tropical Rainfall measuring Mission (TRMM) product (3B42RT). Nesterov index has been slightly modified according to the Indian context and computed using land surface temperature, dew point temperature and precipitation coefficient. Fuel type danger index has been derived from forest type map of ISRO based on historical fire location information and disturbance danger index has been derived from disturbance map of ISRO. Finally, forest fire danger index has been developed from the above mentioned indices and MODIS Thermal anomaly product (MOD14) has been used for validating the forest fire danger index.

Solution based zinc tin oxide TFTs: the dual role of the organic solvent

NASA Astrophysics Data System (ADS)

Salgueiro, Daniela; Kiazadeh, Asal; Branquinho, Rita; Santos, Lídia; Barquinha, Pedro; Martins, Rodrigo; Fortunato, Elvira

2017-02-01

Chemical solution deposition is a low cost, scalable and high performance technique to obtain metal oxide thin films. Recently, solution combustion synthesis has been introduced as a chemical route to reduce the processing temperature. This synthesis method takes advantage of the chemistry of the precursors as a source of energy for localized heating. According to the combustion chemistry some organic solvents can have a dual role in the reaction, acting both as solvent and fuel. In this work, we studied the role of 2-methoxyethanol in solution based synthesis of ZTO thin films and its influence on the performance of ZTO TFTs. The thermal behaviour of ZTO precursor solutions confirmed that 2-methoxyethanol acts simultaneously as a solvent and fuel, replacing the fuel function of urea. The electrical characterization of the solution based ZTO TFTs showed a slightly better performance and lower variability under positive gate bias stress when urea was not used as fuel, confirming that the excess fuel contributes negatively to the device operation and stability. Solution based ZTO TFTs demonstrated a low hysteresis (ΔV  =  -0.3 V) and a saturation mobility of 4-5 cm2 V-1 s-1.

FeSi4P4: A novel negative electrode with atypical electrochemical mechanism for Li and Na-ion batteries

NASA Astrophysics Data System (ADS)

Coquil, Gaël; Fullenwarth, Julien; Grinbom, Gal; Sougrati, Moulay Tahar; Stievano, Lorenzo; Zitoun, David; Monconduit, Laure

2017-12-01

The electrochemical mechanism and performance of FeSi4P4, vs. Na and Li were studied using a combination of operando X-ray diffraction, 57Fe Mössbauer spectroscopy, and SQUID magnetometry. This silicon- and phosphorous-rich material exhibits a high capacity of 1750 mAh/g, retaining 1120 mAh/g after 40 cycles, and reacts through an original reversible mechanism surprisingly involving only slight changes in the chemical environment of the iron. Magnetic measurements and 57Fe Mössbauer spectroscopy at low temperature reveal the reversible but incomplete change of the magnetic moment upon charge and discharge. Such a mild reversible process without drastic phase transition (with the exception of the crystalline to amorphous transition during the first lithiation) can explain the satisfying capacity retention. The electrochemical mechanism appears thus to be significantly different from the classical conversion or alloying/dealloying mechanisms usually observed in Lithium ion batteries for p-group element based materials. The same iron silicon phosphide electrode shows also interesting but significantly lower performance vs. Na, with a limited capacity retention 350 mAh/g.

Quantum chemistry and TST study of the mechanism and kinetics of the butadiene and isoprene reactions with mercapto radicals

NASA Astrophysics Data System (ADS)

Francisco-Márquez, Misaela; Alvarez-Idaboy, J. Raul; Galano, Annia; Vivier-Bunge, Annik

2008-03-01

The reactions of isoprene and butadiene with SH rad radicals have been investigated by density functional theory and ab initio molecular orbital theories. We report the thermodynamics and kinetics of four different pathways, involving addition of SH rad radicals to all double-bonded carbon atoms. Calculations have been performed on all stationary points using BHandHLYP functional, Moller-Plesset perturbation theory to second-order (MP2) and the composite CBS-QB3 method at the MP2 optimized geometries and frequencies. Pre-reactive complexes have been identified. The apparent activation energies are negative for SH rad addition at the terminal carbon atoms and are slightly smaller than those for OH rad addition at the same positions. The calculated overall rate coefficient for butadiene + SH rad reaction at 298 K is in excellent agreement with the only available experimentally measured value. Activation energies and overall rate coefficients at different temperatures are predicted for the first time for butadiene + SH rad and isoprene + SH rad reactions. The reactions of butadiene and isoprene with SH rad radicals were found to be about four times faster than with OH rad radicals.

Determination of γ/ γ' Lattice Misfit in Ni-Based Single-Crystal Superalloys at High Temperatures by Neutron Diffraction

NASA Astrophysics Data System (ADS)

Huang, Shenyan; An, Ke; Gao, Yan; Suzuki, Akane

2018-03-01

Constrained γ/ γ' lattice misfit as a function of temperature (room temperature, 871 °C, 982 °C, 1093 °C, and 1204 °C) is measured by neutron diffraction on the first-generation Ni-based single-crystal superalloy René N4 and second-generation superalloys René N5, CMSX4, and PWA1484. All the alloys studied show negative misfit at temperatures above 871 °C. For René N4, René N5, and PWA1484, the misfit becomes less negative at temperatures above 1093 °C, possibly due to either the chemistry effect or internal stress relaxation. The magnitude of the misfit shows a qualitative agreement with Caron's misfit model based on Vegard's coefficients. The Re-free alloy René N4 was found to have a larger γ lattice parameter and γ/ γ' misfit due to higher fractions of Cr, Ti, and Mo. After 100 hours of annealing at high temperatures, René N5 shows a more negative misfit than the misfit after the standard heat treatment.

Lake-specific variation in growth, migration timing and survival of juvenile sockeye salmon Oncorhynchus nerka: separating environmental from genetic influences.

PubMed

Reed, T E; Martinek, G; Quinn, T P

2010-08-01

Time series on juvenile life-history traits obtained from sockeye salmon Oncorhynchus nerka were analysed to assess lake-specific environmental influences on juvenile migration timing, size and survival of fish from a common gene pool. Every year for the past two decades, O. nerka have been spawned at a hatchery facility, and the progeny released into two lakes that differ in average summer temperatures, limnological attributes and growth opportunities. Juveniles reared in the warmer, more productive Crosswind Lake were larger and heavier as smolts compared to those from the cooler, less productive Summit Lake and had higher in-lake and subsequent marine survival. Crosswind Lake smolts migrated from the lake to sea slightly earlier in the season but the migration timing distributions overlapped considerably across years. Fry stocking density had a negative effect on smolt length for both lakes, and a negative effect on in-lake survival in Summit Lake. Taken together, the results revealed a strong effect of lake-rearing environment on the expression of life-history variation in O. nerka. The stocking of these lakes each year with juveniles from a single mixed-source population provided a large-scale reverse common-garden experiment, where the same gene pool was exposed to different environments, rather than the different gene pools in the same environment approach typical of evolutionary ecology studies. Other researchers are encouraged to seek and exploit similar serendipitous situations, which might allow environmental and genetic influences on ecologically important traits to be distinguished in natural or semi-natural settings.

Dilute stuffing in the pyrochlore iridate Eu2Ir2O7

NASA Astrophysics Data System (ADS)

Telang, Prachi; Mishra, Kshiti; Sood, A. K.; Singh, Surjeet

2018-06-01

The pyrochlore Eu2Ir2O7 has recently attracted significant attention as a candidate Weyl semimetal. The previous reports on this compound unanimously show a thermally induced metal-to-insulator (MI) transition, concomitant with antiferromagnetic long-range ordering of the Ir moments below TN˜120 K. However, there are contradictory reports concerning the slope d ρ /d T of the resistivity plots (ρ ) in the "metallic" state above the MI transition, and the value of ρ in the insulating state, both of which show significant sample dependence. Here, we explore this issue by investigating six different Eu2Ir2O7 samples with slightly varying Eu:Ir ratio. High-resolution synchrotron powder diffraction is done to probe minor variations in the cell parameters of the various Eu2Ir2O7 samples investigated here. Specific heat (Cp) and magnetic susceptibility of all the samples showed long-range antiferromagnetic ordering upon cooling below TN˜120 K. The transitions are, however, found to be smeared out for the off-stoichiometric samples. We show that the sign of d ρ /d T above the MI transition is highly sensitive to the unit-cell length, which, in turn, depends on the level of Eu stuffing at the Ir site. Samples with composition close to the ideal stoichiometry (Eu:Ir =1 ) showed a change of sign of d ρ /d T from negative to positive upon cooling below a certain temperature T*>TMI . With increasing Eu stuffing, T* decreased until a negative d ρ /d T persisted without any sign change down to TMI.

Effects of biochars on the availability of heavy metals to ryegrass in an alkaline contaminated soil.

PubMed

Zhang, Guixiang; Guo, Xiaofang; Zhao, Zhihua; He, Qiusheng; Wang, Shuifeng; Zhu, Yuen; Yan, Yulong; Liu, Xitao; Sun, Ke; Zhao, Ye; Qian, Tianwei

2016-11-01

A pot experiment was conducted to investigate the effects of biochars on the availability of heavy metals (Cd, Cu, Mn, Ni, Pb, and Zn) to ryegrass in an alkaline contaminated soil. Biochars only slightly decreased or even increased the availability of heavy metals assesses by chemical extractant (a mixture of 0.05 mol L -1 ethylenediaminetetraacetic acid disodium, 0.01 mol L -1 CaCl 2 , and 0.1 mol L -1 triethanolamine). The significantly positive correlation between most chemical-extractable heavy metals and the ash content in biochars indicated the positive role of ash in this extraction. Biochars significantly reduced the plant uptake of heavy metals, excluding Mn. The absence of a positive correlation between the chemical-extractable heavy metals and the plant uptake counterparts (except for Mn) indicates that chemical extractability is probably not a reliable indicator to predict the phytoavailability of most heavy metals in alkaline soils treated with biochars. The obviously negative correlation between the plant uptake of heavy metals (except for Mn) and the (O + N)/C and H/C indicates that biochars with more polar groups, which were produced at lower temperatures, had higher efficiency for reducing the phytoavailability of heavy metals. The significantly negative correlations between the plant uptake of Mn and ryegrass biomass indicated the "dilution effect" caused by the improvement of biomass. These observations will be helpful for designing biochars as soil amendments to reduce the availability of heavy metals to plants in soils, especially in alkaline soils. Copyright © 2016. Published by Elsevier Ltd.

The effect of GSM and TETRA mobile handset signals on blood pressure, catechol levels and heart rate variability.

PubMed

Barker, Anthony T; Jackson, Peter R; Parry, Helen; Coulton, Leslie A; Cook, Greg G; Wood, Steven M

2007-09-01

An acute rise in blood pressure has been reported in normal volunteers during exposure to signals from a mobile phone handset. To investigate this finding further we carried out a double blind study in 120 healthy volunteers (43 men, 77 women) in whom we measured mean arterial pressure (MAP) during each of six exposure sessions. At each session subjects were exposed to one of six different radio frequency signals simulating both GSM and TETRA handsets in different transmission modes. Blood catechols before and after exposure, heart rate variability during exposure, and post exposure 24 h ambulatory blood pressure were also studied. Despite having the power to detect changes in MAP of less than 1 mmHg none of our measurements showed any effect which we could attribute to radio frequency exposure. We found a single statistically significant decrease of 0.7 mmHg (95% CI 0.3-1.2 mmHg, P = .04) with exposure to GSM handsets in sham mode. This may be due to a slight increase in operating temperature of the handsets when in this mode. Hence our results have not confirmed the original findings of an acute rise in blood pressure due to exposure to mobile phone handset signals. In light of this negative finding from a large study, coupled with two smaller GSM studies which have also proved negative, we are of the view that further studies of acute changes in blood pressure due to GSM and TETRA handsets are not required.

Negative thermal quenching of the defects in GaInP top cell with temperature-dependent photoluminescence analysis

NASA Astrophysics Data System (ADS)

Junling, Wang; Rui, Wu; Tiancheng, Yi; Yong, Zheng; Rong, Wang

2018-01-01

Temperature-dependent photoluminescence (PL) measurements were carried out to investigate the irradiation effects of 1.0 MeV electrons on the n+- p GaInP top cell of GaInP/GaAs/Ge triple-junction solar cells in the 10-300 K temperature range. The PL intensities plotted against inverse temperature in an Arrhenius plot shows a thermal quenching behavior from 10 K to 140 K and an unusual negative thermal quenching (NTQ) behavior from 150 K to 300 K. The appearance of the PL thermal quenching with increasing temperature confirms that there is a nonradiative recombination center, i.e., the H2 hole trap located at Ev + 0.55 eV, in the cell after electron irradiation. The PL negative thermal quenching behavior may tentatively be attributed to the intermediate states at an energy level of 0.05 eV within the band gap in GaInP top cell.

A new material platform of Si photonics for implementing architecture of dense wavelength division multiplexing on Si bulk wafer

NASA Astrophysics Data System (ADS)

Zhang, Ziyi; Yako, Motoki; Ju, Kan; Kawai, Naoyuki; Chaisakul, Papichaya; Tsuchizawa, Tai; Hikita, Makoto; Yamada, Koji; Ishikawa, Yasuhiko; Wada, Kazumi

2017-12-01

A new materials group to implement dense wavelength division multiplexing (DWDM) in Si photonics is proposed. A large thermo-optic (TO) coefficient of Si malfunctions multiplexer/demultiplexer (MUX/DEMUX) on a chip under thermal fluctuation, and thus DWDM implementation, has been one of the most challenging targets in Si photonics. The present study specifies an optical materials group for DWDM by a systematic survey of their TO coefficients and refractive indices. The group is classified as mid-index contrast optics (MiDex) materials, and non-stoichiometric silicon nitride (SiNx) is chosen to demonstrate its significant thermal stability. The TO coefficient of non-stoichiometric SiNx is precisely measured in the temperature range 24-76 °C using the SiNx rings prepared by two methods: chemical vapor deposition (CVD) and physical vapor deposition (PVD). The CVD-SiNx ring reveals nearly the same TO coefficient reported for stoichiometric CVD-Si3N4, while the value for the PVD-SiNx ring is slightly higher. Both SiNx rings lock their resonance frequencies within 100 GHz in this temperature range. Since CVD-SiNx needs a high temperature annealing to reduce N-H bond absorption, it is concluded that PVD-SiNx is suited as a MiDex material introduced in the CMOS back-end-of-line. Further stabilization is required, considering the crosstalk between two channels; a 'silicone' polymer is employed to compensate for the temperature fluctuation using its negative TO coefficient, called athermalization. This demonstrates that the resonance of these SiNx rings is locked within 50 GHz at the same temperature range in the wavelength range 1460-1620 nm (the so-called S, C, and L bands in optical fiber communication networks). A further survey on the MiDex materials strongly suggests that Al2O3, Ga2O3 Ta2O5, HfO2 and their alloys should provide even more stable platforms for DWDM implementation in MiDex photonics. It is discussed that the MiDex photonics will find various applications such as medical and environmental sensing and in-vehicle data-communication.

Negative ion source with low temperature transverse divergence optical system

DOEpatents

Whealton, John H.; Stirling, William L.

1986-01-01

A negative ion source is provided which has extremely low transverse divergence as a result of a unique ion focusing system in which the focal line of an ion beam emanating from an elongated, concave converter surface is outside of the ion exit slit of the source and the path of the exiting ions. The beam source operates with a minimum ion temperature which makes possible a sharply focused (extremely low transverse divergence) ribbon like negative ion beam.

Negative ion source with low temperature transverse divergence optical system

DOEpatents

Whealton, J.H.; Stirling, W.L.

1985-03-04

A negative ion source is provided which has extremely low transverse divergence as a result of a unique ion focusing system in which the focal line of an ion beam emanating from an elongated, concave converter surface is outside of the ion exit slit of the source and the path of the exiting ions. The beam source operates with a minimum ion temperature which makes possible a sharply focused (extremely low transverse divergence) ribbon like negative ion beam.

Thermal equilibrium concentrations and effects of negatively charged Ga vacancies in n-type GaAs

NASA Astrophysics Data System (ADS)

Tan, T. Y.; You, H.-M.; Gösele, U. M.

1993-03-01

We have calculated the thermal equilibrium concentrations of the various negatively charged Ga vacancy species in GaAs. The triply-negatively-charged Ga vacancy, V {Ga/3-}, has been emphasized, since it dominates Ga self-diffusion and Ga-Al interdiffusion under intrinsic and n-doping conditions, as well as the diffusion of Si donor atoms occupying Ga sites. Under strong n-doping conditions, the thermal equilibrium V {Ga/3-}concentration, C_{V_{_{Ga} }^{3 - } }^{eq} (n), has been found to exhibit a temperature independence or a negative temperature dependence, i.e., the C_{V_{_{Ga} }^{3 - } }^{eq} (n) value is either unchanged or increases as the temperature is lowered. This is quite contrary to the normal point defect behavior for which the point defect thermal equilibrium concentration decreases as the temperature is lowered. This C_{V_{_{Ga} }^{3 - } }^{eq} (n) property provides explanations to a number of outstanding experimental results, either requiring the interpretation that V {Ga/3-}has attained its thermal equilibrium concentration at the onset of each experiment, or requiring mechanisms involving point defect non-equilibrium phenomena.

Mesospheric effects of solar ultraviolet variations - Further analysis of SME IR ozone and Nimbus 7 SAMS temperature data

NASA Astrophysics Data System (ADS)

Hood, L. L.; Huang, Z.; Bougher, S. W.

1991-07-01

In order to improve the constraints on models of the mesospheric response to solar UV variations, an analysis is conducted of the Solar Mesosphere Explorer (SME) IR ozone data and Nimbus 7 stratosphere and mesosphere sounder (SAMS) temperature data. Maximum low-altitude ozone and temperature-response amplitudes occur at about the same altitude, where a strong coupling between photochemical and thermal components of the mesospheric response is suggested by the simultaneous positive temperature and negative ozone response maxima. Increased Lyman-alpha dissociation of water vapor and temperature feedback are theorized to account for the negative ozone response. HO(x) chemical heating can increase as ozone destruction increases, and can therefore account for the positive temperature response.

Mesospheric effects of solar ultraviolet variations - Further analysis of SME IR ozone and Nimbus 7 SAMS temperature data

NASA Technical Reports Server (NTRS)

Hood, L. L.; Huang, Z.; Bougher, S. W.

1991-01-01

In order to improve the constraints on models of the mesospheric response to solar UV variations, an analysis is conducted of the Solar Mesosphere Explorer (SME) IR ozone data and Nimbus 7 stratosphere and mesosphere sounder (SAMS) temperature data. Maximum low-altitude ozone and temperature-response amplitudes occur at about the same altitude, where a strong coupling between photochemical and thermal components of the mesospheric response is suggested by the simultaneous positive temperature and negative ozone response maxima. Increased Lyman-alpha dissociation of water vapor and temperature feedback are theorized to account for the negative ozone response. HO(x) chemical heating can increase as ozone destruction increases, and can therefore account for the positive temperature response.

Modeling and Performance Estimation for Airborne Minefield Detection System

DTIC Science & Technology

2008-05-01

Difference Vegetation Index ( NDVI ) NDVI is defined as: NDVI = (NIR – RED)/ (NIR + RED...to minimize the effect of variable irradiance levels. NDVI is always bounded between -1 and 1. A higher positive value of NDVI indicates the...lakes, and rivers) which has low reflectance in both NIR as well as visible bands, results in very low positive or slightly negative NDVI values

Entanglement negativity and sudden death in the toric code at finite temperature

NASA Astrophysics Data System (ADS)

Hart, O.; Castelnovo, C.

2018-04-01

We study the fate of quantum correlations at finite temperature in the two-dimensional toric code using the logarithmic entanglement negativity. We are able to obtain exact results that give us insight into how thermal excitations affect quantum entanglement. The toric code has two types of elementary excitations (defects) costing different energies. We show that an O (1 ) density of the lower energy defect is required to degrade the zero-temperature entanglement between two subsystems in contact with one another. However, one type of excitation alone is not sufficient to kill all quantum correlations, and an O (1 ) density of the higher energy defect is required to cause the so-called sudden death of the negativity. Interestingly, if the energy cost of one of the excitations is taken to infinity, quantum correlations survive up to arbitrarily high temperatures, a feature that is likely shared with other quantum spin liquids and frustrated systems in general, when projected down to their low-energy states. We demonstrate this behavior both for small subsystems, where we can prove that the negativity is a necessary and sufficient condition for separability, as well as for extended subsystems, where it is only a necessary condition. We further observe that the negativity per boundary degree of freedom at a given temperature increases (parametrically) with the size of the boundary, and that quantum correlations between subsystems with extended boundaries are more robust to thermal fluctuations.

The complex impact of risk and protective factors on suicide mortality: a study of the Ukrainian general population.

PubMed

Yur'yev, Andriy; Yur'yeva, Lyudmyla; Värnik, Peeter; Lumiste, Kaur; Värnik, Airi

2015-01-01

This study assesses the complex impact of risk and protective factors on suicide mortality in the Ukrainian general population. Data on suicide rates and socioeconomic and medical factors were obtained from the Ukrainian State Statistical Office, WHO, and the European Social Survey. Structural equation modeling was used for data analysis. Religion and education were negatively associated with suicide. The relationship between drug addiction/alcoholism and suicide was positive. The association between urbanization and suicide mortality was negative. The relationship between gross regional product (GRP) and female suicide was slightly negative. Religiosity was the protective factor most strongly linked with suicide mortality followed by urbanization. The harmful role of drug addiction and alcoholism was confirmed. The role of education and GRP is controversial. No striking gender differences were found.

The Peculiar Negative Greenhouse Effect Over Antarctica

NASA Astrophysics Data System (ADS)

Sejas, S.; Taylor, P. C.; Cai, M.

2017-12-01

Greenhouse gases warm the climate system by reducing the energy loss to space through the greenhouse effect. Thus, a common way to measure the strength of the greenhouse effect is by taking the difference between the surface longwave (LW) emission and the outgoing LW radiation. Based on this definition, a paradoxical negative greenhouse effect is found over the Antarctic Plateau, which suprisingly indicates that greenhouse gases enhance energy loss to space. Using 13 years of NASA satellite observations, we verify the existence of the negative greenhouse effect and find that the magnitude and sign of the greenhouse effect varies seasonally and spectrally. A previous explanation attributes the negative greenhouse effect solely to stratospheric CO2 and warmer than surface stratospheric temperatures. However, we surprisingly find that the negative greenhouse effect is predominantly caused by tropospheric water vapor. A novel principle-based explanation provides the first complete account of the Antarctic Plateau's negative greenhouse effect indicating that it is controlled by the vertical variation of temperature and greenhouse gas absorption strength. Our findings indicate that the strong surface-based temperature inversion and scarcity of free tropospheric water vapor over the Antarctic Plateau cause the negative greenhouse effect. These are climatological features uniquely found in the Antarctic Plateau region, explaining why the greenhouse effect is positive everywhere else.

Agreement between allergen-specific IgE assays and ensuing immunotherapy recommendations from four commercial laboratories in the USA.

PubMed

Plant, Jon D; Neradelik, Moni B; Polissar, Nayak L; Fadok, Valerie A; Scott, Brian A

2014-02-01

Canine allergen-specific IgE assays in the USA are not subjected to an independent laboratory reliability monitoring programme. The aim of this study was to evaluate the agreement of diagnostic results and treatment recommendations of four serum IgE assays commercially available in the USA. Replicate serum samples from 10 atopic dogs were submitted to each of four laboratories for allergen-specific IgE assays (ACTT(®) , VARL Liquid Gold, ALLERCEPT(®) and Greer(®) Aller-g-complete(®) ). The interlaboratory agreement of standard, regional panels and ensuing treatment recommendations were analysed with the kappa statistic (κ) to account for agreement that might occur merely by chance. Six comparisons of pairs of laboratories and overall agreement among laboratories were analysed for ungrouped allergens (as tested) and also with allergens grouped according to reported cross-reactivity and taxonomy. The overall chance-corrected agreement of the positive/negative test results for ungrouped and grouped allergens was slight (κ = 0.14 and 0.13, respectively). Subset analysis of the laboratory pair with the highest level of diagnostic agreement (κ = 0.36) found slight agreement (κ = 0.13) for ungrouped plants and fungi, but substantial agreement (κ = 0.71) for ungrouped mites. The overall agreement of the treatment recommendations was slight (κ = 0.11). Altogether, 85.1% of ungrouped allergen treatment recommendations were unique to one laboratory or another. Our study indicated that the choice of IgE assay may have a major influence on the positive/negative results and ensuing treatment recommendations. © 2014 The Authors. Veterinary Dermatology published by John Wiley & Sons Ltd on behalf of the ESVD and the ACVD.

[Photosynthetic physiological adaptabilities of Pinus tabulaeformis and Robinia pseudoacacia in the Loess Plateau].

PubMed

Zheng, Shu-xia; Shangguan, Zhou-ping

2007-01-01

With Yangling, Yongshou, Fuxian, Ansai, Mizhi and Shenmu, the s ix counties from the south to the north in the Loess Plateau as study sites, this paper studied thoe photosynthetic charac teristics and leaf traits of Pinus tabulaeformis and Robinia pseudoacacia. The results showed that among the six sites, there were significant differences in the photosynthetic rate (Pn), photosynthetic nitrogen use efficiency (PNUE), water use efficiency (WUE), leaf mass per area (LMA), nitrogen content (Nmass), and chlorophyll content (Chl) of P. tabulaeformis and R. pseudoacacia, suggesting that the photosynthetic capacity and leaf traits of the two species differed with sites. From the south to the north, the Pn, PNUE and WUE of P. tabulaeformis increased slightly while those of R. pseudoacacia decreased significantly, indicating that in drought habitat, P. tabulaef6rmis could still maintain high photosynthetic capacity, hut the photosynthetic capacity of R. pseudoacacia was greatly restrained. Also from the south to the north, the LMA of P. tabulaeformis and R. pseudoacacia had a slight increasing trend, while Nmass and Chl decreased slightly. The variation ranges of the three parameters were greater for R. pseudoacacia than for P. tabulaeformis, indicating that P. tabulaeformis had stronger drought-tolerant capability than R. pseudoacacia, which was not only exhibited in physiological metabolism, but also in leaf morphological acclimation. The correlation analysis between photosynthetic parameters and leaf traits of P. tabulaeformis and R. pseudoacacia in the six sites showed that there was a significant negative correlation between LMA and Nmass. The Pn and PNUE of both test species had no correlations with LMA and Nmass, but had significant positive correlation with Chl. The WUE of the species was negatively correlated with LMA, but positively correlated with Nmass.

High temperature tensile properties of V-4Cr-4Ti

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zinkle, S.J.; Rowcliffe, A.F.; Stevens, C.O.

Tensile tests have been performed on V-4Cr-4Ti at 750 and 800 C in order to extend the data base beyond the current limit of 700 C. From comparison with previous measurements, the yield strength is nearly constant and tensile elongations decrease slightly with increasing temperature between 300 and 800 C. The ultimate strength exhibits an apparent maximum near 600 C (attributable to dynamic strain aging) but adequate strength is maintained up to 800 C. The reduction in area measured on tensile specimens remained high ({approximately}80%) for test temperatures up to 800 C, in contrast to previous reported results.