Approaching conversion limit with all-dielectric solar cell reflectors.

PubMed

Fu, Sze Ming; Lai, Yi-Chun; Tseng, Chi Wei; Yan, Sheng Lun; Zhong, Yan Kai; Shen, Chang-Hong; Shieh, Jia-Min; Li, Yu-Ren; Cheng, Huang-Chung; Chi, Gou-chung; Yu, Peichen; Lin, Albert

2015-02-09

Metallic back reflectors has been used for thin-film and wafer-based solar cells for very long time. Nonetheless, the metallic mirrors might not be the best choices for photovoltaics. In this work, we show that solar cells with all-dielectric reflectors can surpass the best-configured metal-backed devices. Theoretical and experimental results all show that superior large-angle light scattering capability can be achieved by the diffuse medium reflectors, and the solar cell J-V enhancement is higher for solar cells using all-dielectric reflectors. Specifically, the measured diffused scattering efficiency (D.S.E.) of a diffuse medium reflector is >0.8 for the light trapping spectral range (600nm-1000nm), and the measured reflectance of a diffuse medium can be as high as silver if the geometry of embedded titanium oxide(TiO(2)) nanoparticles is optimized. Moreover, the diffuse medium reflectors have the additional advantage of room-temperature processing, low cost, and very high throughput. We believe that using all-dielectric solar cell reflectors is a way to approach the thermodynamic conversion limit by completely excluding metallic dissipation.

Systematic analysis of diffuse rear reflectors for enhanced light trapping in silicon solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pfeffer, Florian; Eisenlohr, Johannes; Basch, Angelika

Simple diffuse rear reflectors can enhance the light path length of weakly absorbed near infrared light in silicon solar cells and set a benchmark for more complex and expensive light trapping structures like dielectric gratings or plasmonic particles. We analyzed such simple diffuse rear reflectors systematically by optical and electrical measurements. We applied white paint, TiO 2 nanoparticles, white backsheets and a silver mirror to bifacial silicon solar cells and measured the enhancement of the external quantum efficiency for three different solar cell geometries: planar front and rear side, textured front and planar rear side, and textured front and rearmore » side. We showed that an air-gap between the solar cell and the reflector decreases the absorption enhancement significantly, thus white paint and TiO 2 nanoparticles directly applied to the rear cell surface lead to the highest short circuit current density enhancements. Here, the short circuit current density gains for a 200 um thick planar solar cell reached up to 1.8 mA/cm 2, compared to a non-reflecting black rear side and up to 0.8 mA/cm 2 compared to a high-quality silver mirror rear side. For solar cells with textured front side the short circuit current density gains are in the range between 0.5 and 1.0 mA/cm 2 compared to a non-reflecting black rear side and do not significantly depend on the angular characteristic of the rear side reflector but mainly on its absolute reflectance.« less

Systematic analysis of diffuse rear reflectors for enhanced light trapping in silicon solar cells

DOE PAGES

Pfeffer, Florian; Eisenlohr, Johannes; Basch, Angelika; ...

2016-04-08

Simple diffuse rear reflectors can enhance the light path length of weakly absorbed near infrared light in silicon solar cells and set a benchmark for more complex and expensive light trapping structures like dielectric gratings or plasmonic particles. We analyzed such simple diffuse rear reflectors systematically by optical and electrical measurements. We applied white paint, TiO 2 nanoparticles, white backsheets and a silver mirror to bifacial silicon solar cells and measured the enhancement of the external quantum efficiency for three different solar cell geometries: planar front and rear side, textured front and planar rear side, and textured front and rearmore » side. We showed that an air-gap between the solar cell and the reflector decreases the absorption enhancement significantly, thus white paint and TiO 2 nanoparticles directly applied to the rear cell surface lead to the highest short circuit current density enhancements. Here, the short circuit current density gains for a 200 um thick planar solar cell reached up to 1.8 mA/cm 2, compared to a non-reflecting black rear side and up to 0.8 mA/cm 2 compared to a high-quality silver mirror rear side. For solar cells with textured front side the short circuit current density gains are in the range between 0.5 and 1.0 mA/cm 2 compared to a non-reflecting black rear side and do not significantly depend on the angular characteristic of the rear side reflector but mainly on its absolute reflectance.« less

Results from Solar Reflective Band End-to-End Testing for VIIRS F1 Sensor Using T-SIRCUS

NASA Technical Reports Server (NTRS)

McIntire, Jeff; Moyer, David; McCarthy, James K.; DeLuccia, Frank; Xiong, Xiaoxiong; Butler, James J.; Guenther, Bruce

2011-01-01

Verification of the Visible Infrared Imager Radiometer Suite (VIIRS) End-to-End (E2E) sensor calibration is highly recommended before launch, to identify any anomalies and to improve our understanding of the sensor on-orbit calibration performance. E2E testing of the Reflective Solar Bands (RSB) calibration cycle was performed pre-launch for the VIIRS Fight 1 (F1) sensor at the Ball Aerospace facility in Boulder CO in March 2010. VIIRS reflective band calibration cycle is very similar to heritage sensor MODIS in that solar illumination, via a diffuser, is used to correct for temporal variations in the instrument responsivity. Monochromatic light from the NIST T-SIRCUS was used to illuminate both the Earth View (EV), via an integrating sphere, and the Solar Diffuser (SD) view, through a collimator. The collimator illumination was cycled through a series of angles intended to simulate the range of possible angles for which solar radiation will be incident on the solar attenuation screen on-orbit. Ideally, the measured instrument responsivity (defined here as the ratio of the detector response to the at-sensor radiance) should be the same whether the EV or SD view is illuminated. The ratio of the measured responsivities was determined at each collimator angle and wavelength. In addition, the Solar Diffuser Stability Monitor (SDSM), a ratioing radiometer designed to track the temporal variation in the SD BRF by direct comparison to solar radiation, was illuminated by the collimator. The measured SDSM ratio was compared to the predicted ratio. An uncertainty analysis was also performed on both the SD and SDSM calibrations.

Utilizing Diffuse Reflection to Increase the Efficiency of Luminescent Solar Concentrators

NASA Astrophysics Data System (ADS)

Bowser, Seth; Weible, Seth; Solomon, Joel; Schrecengost, Jonathan; Wittmershaus, Bruce

A luminescent solar concentrator (LSC) consists of a high index solid plate containing a fluorescent material that converts sunlight into fluorescence. Utilizing total internal reflection, the LSC collects and concentrates the fluorescence at the plate's edges where it is converted into electricity via photovoltaic solar cells. The lower production costs of LSCs make them an attractive alternative to photovoltaic solar cells. To optimize an LSC's efficiency, a white diffusive surface (background) is positioned behind it. The background allows sunlight transmitted in the first pass to be reflected back through the LSC providing a second chance for absorption. Our research examines how the LSC's performance is affected by changing the distance between the white background and the LSC. An automated linear motion apparatus was engineered to precisely measure this distance and the LSC's electrical current, simultaneously. LSC plates, with and without the presence of fluorescent material and in an isolated environment, showed a maximum current at a distance greater than zero. Further experimentation has proved that the optimal distance results from the background's optical properties and how the reflected light enters the LSC. This material is based upon work supported by the National Science Foundation under Grant Number NSF-ECCS-1306157.

Fabrication of p(+)-n junction GaAs solar cells by a novel method

NASA Technical Reports Server (NTRS)

Ghandhi, S. K.; Mathur, G.; Rode, H.; Borrego, J. M.

1984-01-01

A novel method for making p(+)-n diffused junction GaAs solar cells, with the formation of a diffusion source, an anti-reflective coating, and a protective cover glass in a single chemical-vapor deposition operation is discussed. Consideration is given to device fabrication and to solar-cell characteristics. The advantages of the technique are that the number of process steps is kept to an absolute minimum, the fabrication procedure is low-cost, and the GaAs surface is protected during the entire operation.

Calibration of passive remote observing optical and microwave instrumentation; Proceedings of the Meeting, Orlando, FL, Apr. 3-5, 1991

NASA Technical Reports Server (NTRS)

Guenther, Bruce W. (Editor)

1991-01-01

Various papers on the calibration of passive remote observing optical and microwave instrumentation are presented. Individual topics addressed include: on-board calibration device for a wide field-of-view instrument, calibration for the medium-resolution imaging spectrometer, cryogenic radiometers and intensity-stabilized lasers for EOS radiometric calibrations, radiometric stability of the Shuttle-borne solar backscatter ultraviolet spectrometer, ratioing radiometer for use with a solar diffuser, requirements of a solar diffuser and measurements of some candidate materials, reflectance stability analysis of Spectralon diffuse calibration panels, stray light effects on calibrations using a solar diffuser, radiometric calibration of SPOT 23 HRVs, surface and aerosol models for use in radiative transfer codes. Also addressed are: calibrated intercepts for solar radiometers used in remote sensor calibration, radiometric calibration of an airborne multispectral scanner, in-flight calibration of a helicopter-mounted Daedalus multispectral scanner, technique for improving the calibration of large-area sphere sources, remote colorimetry and its applications, spatial sampling errors for a satellite-borne scanning radiometer, calibration of EOS multispectral imaging sensors and solar irradiance variability.

Modeling and simulation of the solar concentrator in photovoltaic systems through the application of a new BRDF function model

NASA Astrophysics Data System (ADS)

Plachta, Kamil

2016-04-01

The paper presents a new algorithm that uses a combination of two models of BRDF functions: Torrance-Sparrow model and HTSG model. The knowledge of technical parameters of a surface is especially useful in the construction of the solar concentrator. The concentrator directs the reflected solar radiation on the surface of photovoltaic panels, increasing the amount of incident radiance. The software applying algorithm allows to calculate surface parameters of the solar concentrator. Performed simulation showing the share of diffuse component and directional component in reflected stream for surfaces made from particular materials. The impact of share of each component in reflected stream on the efficiency of the solar concentrator and photovoltaic surface has also been described. Subsequently, simulation change the value of voltage, current and power output of monocrystalline photovoltaic panels installed in a solar concentrator system has been made for selected surface of materials solar concentrator.

Diffuse reflectance of TiO 2 pigmented paints: Spectral dependence of the average pathlength parameter and the forward scattering ratio

NASA Astrophysics Data System (ADS)

Vargas, William E.; Amador, Alvaro; Niklasson, Gunnar A.

2006-05-01

Diffuse reflectance spectra of paint coatings with different pigment concentrations, normally illuminated with unpolarized radiation, have been measured. A four-flux radiative transfer approach is used to model the diffuse reflectance of TiO2 (rutile) pigmented coatings through the solar spectral range. The spectral dependence of the average pathlength parameter and of the forward scattering ratio for diffuse radiation, are explicitly incorporated into this four-flux model from two novel approximations. The size distribution of the pigments has been taken into account to obtain the averages of the four-flux parameters: scattering and absorption cross sections, forward scattering ratios for collimated and isotropic diffuse radiation, and coefficients involved in the expansion of the single particle phase function in terms of Legendre polynomials.

Reduction of skylight reflection effects in the above-water measurement of diffuse marine reflectance.

PubMed

Fougnie, B; Frouin, R; Lecomte, P; Deschamps, P Y

1999-06-20

Reflected skylight in above-water measurements of diffuse marine reflectance can be reduced substantially by viewing the surface through an analyzer transmitting the vertically polarized component of incident radiance. For maximum reduction of effects, radiometric measurements should be made at a viewing zenith angle of approximately 45 degrees (near the Brewster angle) and a relative azimuth angle between solar and viewing directions greater than 90 degrees (backscattering), preferably 135 degrees. In this case the residual reflected skylight in the polarized signal exhibits minimum sensitivity to the sea state and can be corrected to within a few 10(-4) in reflectance units. For most oceanic waters the resulting relative error on the diffuse marine reflectance in the blue and green is less than 1%. Since the water body polarizes incident skylight, the measured polarized reflectance differs from the total reflectance. The difference, however, is small for the considered geometry. Measurements made at the Scripps Institution of Oceanography pier in La Jolla, Calif., with a specifically designed scanning polarization radiometer, confirm the theoretical findings and demonstrate the usefulness of polarization radiometry for measuring diffuse marine reflectance.

Solar flux incident on an orbiting surface after reflection from a planet

NASA Technical Reports Server (NTRS)

Modest, M. F.

1980-01-01

Algorithms describing the solar radiation impinging on an infinitesimal surface after reflection from a gray and diffuse planet are derived. The following conditions apply: only radiation from the sunny half of the planet is taken into account; the radiation must fall on the top of the orbiting surface, and radiation must come from that part of the planet that can be seen from the orbiting body. A simple approximate formula is presented which displays excellent accuracy for all significant situations, with an error which is always less than 5% of the maximum possible reflected flux. Attention is also given to solar albedo flux on a surface directly facing the planet, the influence of solar position on albedo flux, and to solar albedo flux as a function of the surface-planet tilt angle.

Impulsive solar X-ray bursts. 4: Polarization, directivity and spectrum of the reflected and total bremsstrahlung radiation from a beam of electrons directed toward the photosphere

NASA Technical Reports Server (NTRS)

Langer, S. H.; Petrosian, V.

1976-01-01

A Monte Carlo method is described for evaluation of the spectrum, directivity and polarization of X-rays diffusely reflected from stellar photospheres. the accuracy of the technique is evaluated through comparison with analytic results. Using the characteristics of the incident X-rays of the model for solar X-ray flares, the spectrum, directivity and polarization of the reflected and the total X-ray fluxes are evaluated. The results are compared with observations.

Ultraviolet stability and contamination analysis of Spectralon diffuse reflectance material

NASA Technical Reports Server (NTRS)

Stiegman, Albert E.; Bruegge, Carol J.; Springsteen, Arthur W.

1993-01-01

A detailed chemical analysis was carried out on Spectralon, a highly Lambertian, diffuse reflectance material. Results of this investigation unambiguously identified the presence of an organic (hydrocarbon) impurity intrinsic to the commercial material. This impurity could be removed by a vacuum bake-out procedure and was identified as the cause of optical changes (degradation) that occur in the material when exposed to UV light. It was found that when this impurity was removed, the Spectralon material was photochemically stable and maintained its reflectance properties even after extensive solar UV exposure.

Preliminary results of BTDF calibration of transmissive solar diffusers for remote sensing

NASA Astrophysics Data System (ADS)

Georgiev, Georgi T.; Butler, James J.; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2016-09-01

Satellite instruments operating in the reflected solar wavelength region require accurate and precise determination of the optical properties of their diffusers used in pre-flight and post-flight calibrations. The majority of recent and current space instruments use reflective diffusers. As a result, numerous Bidirectional Reflectance Distribution Function (BRDF) calibration comparisons have been conducted between the National Institute of Standards and Technology (NIST) and other industry and university-based metrology laboratories. However, based on literature searches and communications with NIST and other laboratories, no Bidirectional Transmittance Distribution Function (BTDF) measurement comparisons have been conducted between National Measurement Laboratories (NMLs) and other metrology laboratories. On the other hand, there is a growing interest in the use of transmissive diffusers in the calibration of satellite, air-borne, and ground-based remote sensing instruments. Current remote sensing instruments employing transmissive diffusers include the Ozone Mapping and Profiler Suite instrument (OMPS) Limb instrument on the Suomi-National Polar-orbiting Partnership (S-NPP) platform,, the Geostationary Ocean Color Imager (GOCI) on the Korea Aerospace Research Institute's (KARI) Communication, Ocean, and Meteorological Satellite (COMS), the Ozone Monitoring Instrument (OMI) on NASA's Earth Observing System (EOS) Aura platform, the Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument and the Geostationary Environmental Monitoring Spectrometer (GEMS).. This ensemble of instruments requires validated BTDF measurements of their onboard transmissive diffusers from the ultraviolet through the near infrared. This paper presents the preliminary results of a BTDF comparison between the NASA Diffuser Calibration Laboratory (DCL) and NIST on quartz and thin Spectralon samples.

An Update to the NASA Reference Solar Sail Thrust Model

NASA Technical Reports Server (NTRS)

Heaton, Andrew F.; Artusio-Glimpse, Alexandra B.

2015-01-01

An optical model of solar sail material originally derived at JPL in 1978 has since served as the de facto standard for NASA and other solar sail researchers. The optical model includes terms for specular and diffuse reflection, thermal emission, and non-Lambertian diffuse reflection. The standard coefficients for these terms are based on tests of 2.5 micrometer Kapton sail material coated with 100 nm of aluminum on the front side and chromium on the back side. The original derivation of these coefficients was documented in an internal JPL technical memorandum that is no longer available. Additionally more recent optical testing has taken place and different materials have been used or are under consideration by various researchers for solar sails. Here, where possible, we re-derive the optical coefficients from the 1978 model and update them to accommodate newer test results and sail material. The source of the commonly used value for the front side non-Lambertian coefficient is not clear, so we investigate that coefficient in detail. Although this research is primarily designed to support the upcoming NASA NEA Scout and Lunar Flashlight solar sail missions, the results are also of interest to the wider solar sail community.

Computation of diffuse sky irradiance from multidirectional radiance measurements

NASA Technical Reports Server (NTRS)

Ahmad, Suraiya P.; Middleton, Elizabeth M.; Deering, Donald W.

1987-01-01

Accurate determination of the diffuse solar spectral irradiance directly above the land surface is important in characterizing the reflectance properties of these surfaces, especially vegetation canopies. This determination is also needed to infer the net radiation budget of the earth-atmosphere system above these surfaces. An algorithm is developed here for the computation of hemispheric diffuse irradiance using the measurements from an instrument called PARABOLA, which rapidly measures upwelling and downwelling radiances in three selected wavelength bands. The validity of the algorithm is established from simulations. The standard reference data set of diffuse radiances of Dave (1978), obtained by solving the radiative transfer equation numerically for realistic atmospheric models, is used to simulate PARABOLA radiances. Hemispheric diffuse irradiance is estimated from a subset of simulated radiances by using the algorithm described. The algorithm is validated by comparing the estimated diffuse irradiance with the true diffuse irradiance of the standard data set. The validations include sensitivity studies for two wavelength bands (visible, 0.65-0.67 micron; near infrared, 0.81-0.84 micron), different atmospheric conditions, solar elevations, and surface reflectances. In most cases the hemispheric diffuse irradiance computed from simulated PARABOLA radiances and the true irradiance obtained from radiative transfer calculations agree within 1-2 percent. This technique can be applied to other sampling instruments designed to estimate hemispheric diffuse sky irradiance.

Development of Low-cost, High Energy-per-unit-area Solar Cell Modules

NASA Technical Reports Server (NTRS)

Jones, G. T.; Chitre, S.; Rhee, S. S.

1978-01-01

The development of two hexagonal solar cell process sequences, a laserscribing process technique for scribing hexagonal and modified hexagonal solar cells, a large through-put diffusion process, and two surface macrostructure processes suitable for large scale production is reported. Experimental analysis was made on automated spin-on anti-reflective coating equipment and high pressure wafer cleaning equipment. Six hexagonal solar cell modules were fabricated. Also covered is a detailed theoretical analysis on the optimum silicon utilization by modified hexagonal solar cells.

Tracking On-Orbit Stability of the Response Versus Scan Angle for the S-NPP VIIRS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Wu, Aisheng; Xiong, Xiaoxiong; Cao, Changyong

2016-01-01

The Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi NPP (National Polar-orbiting Partnership) satellite (http:npp.gsfc.nasa.govviirs.html) has been in operation for nearly five years. The onboard calibration of the VIIRS reflective solar bands (RSB) relies on a solar diffuser (SD) located at a fixed scan angle and a solar diffuser stability monitor (SDSM). The VIIRS response versus scan angle (RVS) was characterized prelaunch in ambient conditions and is currently used to determine the on-orbit response for all scan angles relative to the SD scan angle. Since the RVS is vitally important to the quality of calibrated level 1B products, it is important to monitor its on-orbit stability. In this study, the RVS stability is examined based on reflectance trends collected from 16-day repeatable orbits over pre-selected pseudo-invariant desert sites in Northern Africa. These trends nearly cover the entire Earth view scan range so that any systematic drifts in the scan angle direction would indicate a change in RVS. This study also compares VIIRS RVS on-orbit stability results with those from both Aqua and Terra MODIS over the first four years of mission for a few selected bands, which provides further information on potential VIIRS RVS on-orbit changes.

Landsat test of diffuse reflectance models for aquatic suspended solids measurement

NASA Technical Reports Server (NTRS)

Munday, J. C., Jr.; Alfoldi, T. T.

1979-01-01

Landsat radiance data were used to test mathematical models relating diffuse reflectance to aquatic suspended solids concentration. Digital CCT data for Landsat passes over the Bay of Fundy, Nova Scotia were analyzed on a General Electric Co. Image 100 multispectral analysis system. Three data sets were studied separately and together in all combinations with and without solar angle correction. Statistical analysis and chromaticity analysis show that a nonlinear relationship between Landsat radiance and suspended solids concentration is better at curve-fitting than a linear relationship. In particular, the quasi-single-scattering diffuse reflectance model developed by Gordon and coworkers is corroborated. The Gordon model applied to 33 points of MSS 5 data combined from three dates produced r = 0.98.

PRELIMINARY RESULTS OF BTDF CALIBRATION OF TRANSMISSIVE SOLAR DIFFUSERS FOR REMOTE SENSING.

PubMed

Georgiev, Georgi T; Butler, James J; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2016-01-01

Satellite instruments operating in the reflected solar wavelength region require accurate and precise determination of the optical properties of their diffusers used in pre-flight and post-flight calibrations. The majority of recent and current space instruments use reflective diffusers. As a result, numerous Bidirectional Reflectance Distribution Function (BRDF) calibration comparisons have been conducted between the National Institute of Standards and Technology (NIST) and other industry and university-based metrology laboratories. However, based on literature searches and communications with NIST and other laboratories, no Bidirectional Transmittance Distribution Function (BTDF) measurement comparisons have been conducted between National Measurement Laboratories (NMLs) and other metrology laboratories. On the other hand, there is a growing interest in the use of transmissive diffusers in the calibration of satellite, air-borne, and ground-based remote sensing instruments. Current remote sensing instruments employing transmissive diffusers include the Ozone Mapping and Profiler Suite instrument (OMPS) Limb instrument on the Suomi-National Polar-orbiting Partnership (S-NPP) platform,, the Geostationary Ocean Color Imager (GOCI) on the Korea Aerospace Research Institute's (KARI) Communication, Ocean, and Meteorological Satellite (COMS), the Ozone Monitoring Instrument (OMI) on NASA's Earth Observing System (EOS) Aura platform, the Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument and the Geostationary Environmental Monitoring Spectrometer (GEMS).. This ensemble of instruments requires validated BTDF measurements of their on-board transmissive diffusers from the ultraviolet through the near infrared. This paper presents the preliminary results of a BTDF comparison between the NASA Diffuser Calibration Laboratory (DCL) and NIST on quartz and thin Spectralon samples.

Preliminary Results of BTDF Calibration of Transmissive Solar Diffusers for Remote Sensing

NASA Technical Reports Server (NTRS)

Georgiev, Georgi T.; Butler, James J.; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2016-01-01

Satellite instruments operating in the reflected solar wavelength region require accurate and precise determination of the optical properties of their diffusers used in pre-flight and post-flight calibrations. The majority of recent and current space instruments use reflective diffusers. As a result, numerous Bidirectional Reflectance Distribution Function (BRDF) calibration comparisons have been conducted between the National Institute of Standards and Technology (NIST) and other industry and university-based metrology laboratories. However, based on literature searches and communications with NIST and other laboratories, no Bidirectional Transmittance Distribution Function (BTDF) measurement comparisons have been conducted between National Measurement Laboratories (NMLs) and other metrology laboratories. On the other hand, there is a growing interest in the use of transmissive diffusers in the calibration of satellite, air-borne, and ground-based remote sensing instruments. Current remote sensing instruments employing transmissive diffusers include the Ozone Mapping and Profiler Suite instrument (OMPS) Limb instrument on the Suomi-National Polar-orbiting Partnership (S-NPP) platform,, the Geostationary Ocean Color Imager (GOCI) on the Korea Aerospace Research Institute's (KARI) Communication, Ocean, and Meteorological Satellite (COMS), the Ozone Monitoring Instrument (OMI) on NASA's Earth Observing System (EOS) Aura platform, the Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument and the Geostationary Environmental Monitoring Spectrometer (GEMS).. This ensemble of instruments requires validated BTDF measurements of their on-board transmissive diffusers from the ultraviolet through the near infrared. This paper presents the preliminary results of a BTDF comparison between the NASA Diffuser Calibration Laboratory (DCL) and NIST on quartz and thin Spectralon samples.

PRELIMINARY RESULTS OF BTDF CALIBRATION OF TRANSMISSIVE SOLAR DIFFUSERS FOR REMOTE SENSING

PubMed Central

Georgiev, Georgi T.; Butler, James J.; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2016-01-01

Satellite instruments operating in the reflected solar wavelength region require accurate and precise determination of the optical properties of their diffusers used in pre-flight and post-flight calibrations. The majority of recent and current space instruments use reflective diffusers. As a result, numerous Bidirectional Reflectance Distribution Function (BRDF) calibration comparisons have been conducted between the National Institute of Standards and Technology (NIST) and other industry and university-based metrology laboratories. However, based on literature searches and communications with NIST and other laboratories, no Bidirectional Transmittance Distribution Function (BTDF) measurement comparisons have been conducted between National Measurement Laboratories (NMLs) and other metrology laboratories. On the other hand, there is a growing interest in the use of transmissive diffusers in the calibration of satellite, air-borne, and ground-based remote sensing instruments. Current remote sensing instruments employing transmissive diffusers include the Ozone Mapping and Profiler Suite instrument (OMPS) Limb instrument on the Suomi-National Polar-orbiting Partnership (S-NPP) platform,, the Geostationary Ocean Color Imager (GOCI) on the Korea Aerospace Research Institute’s (KARI) Communication, Ocean, and Meteorological Satellite (COMS), the Ozone Monitoring Instrument (OMI) on NASA’s Earth Observing System (EOS) Aura platform, the Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument and the Geostationary Environmental Monitoring Spectrometer (GEMS).. This ensemble of instruments requires validated BTDF measurements of their on-board transmissive diffusers from the ultraviolet through the near infrared. This paper presents the preliminary results of a BTDF comparison between the NASA Diffuser Calibration Laboratory (DCL) and NIST on quartz and thin Spectralon samples. PMID:28003712

Design Rules for Tailoring Antireflection Properties of Hierarchical Optical Structures

DOE PAGES

Leon, Juan J. Diaz; Hiszpanski, Anna M.; Bond, Tiziana C.; ...

2017-05-18

Hierarchical structures consisting of small sub-wavelength features stacked atop larger structures have been demonstrated as an effective means of reducing the reflectance of surfaces. However, optical devices require different antireflective properties depending on the application, and general unifying guidelines on hierarchical structures' design to attain a desired antireflection spectral response are still lacking. The type of reflectivity (diffuse, specular, or total/hemispherical) and its angular- and spectral-dependence are all dictated by the structural parameters. Through computational and experimental studies, guidelines have been devised to modify these various aspects of reflectivity across the solar spectrum by proper selection of the features ofmore » hierarchical structures. In this wavelength regime, micrometer-scale substructures dictate the long-wavelength spectral response and effectively reduce specular reflectance, whereas nanometer-scale substructures dictate primarily the visible wavelength spectral response and reduce diffuse reflectance. Coupling structures having these two length scales into hierarchical arrays impressively reduces surfaces' hemispherical reflectance across a broad spectrum of wavelengths and angles. Furthermore, such hierarchical structures in silicon are demonstrated having an average total reflectance across the solar spectrum of 1.1% (average weighted reflectance of 1% in the 280–2500 nm range of the AM 1.5 G spectrum) and specular reflectance <1% even at angles of incidence as high as 67°.« less

Skylab program earth resources experiment package: Ground truth data for test sites (SL-2)

NASA Technical Reports Server (NTRS)

1975-01-01

Field measurements were performed at selected ground sites in order to provide comparative calibration measurements of sensors for the Earth Resources Experiment Package. Specifically, the solar radiation (400 to 1300 namometers) and thermal radiation (8-14 micrometers) were measured. Sites employed for the thermal measurements consisted of warm and cold water lakes. The thermal brightness temperature of the lake water, the temperature and humidity profile above the lake, and near surface meteorology (wind speed, pressure, etc.) were measured near the time of overpass. Sites employed for the solar radiation measurements were two desert type sites. Ground measurements consisted of: (1) direct solar radiation - optical depth; (2) diffuse solar radiation; (3) total solar radiation, (4) target directional (normal) reflectance; (5) target hemispherical reflectance; and (6) near surface meteorology.

A study of the solar wind deceleration in the Earth's foreshock region

NASA Technical Reports Server (NTRS)

Zhang, T.-L.; Schwingenschuh, K.; Russell, C. T.

1995-01-01

Previous observations have shown that the solar wind is decelerated and deflected in the earth's upstream region populated by long-period waves. This deceleration is corelated with the 'diffuse' but not with the 'reflected' ion population. The speed of the solar wind may decrease tens of km/s in the foreshock region. The solar wind dynamic pressure exerted on the magnetopause may vary due to the fluctuation of the solar wind speed and density in the foreshock region. In this study, we examine this solar wind deceleration and determine how the solar wind deceleration varies in the foreshock region.

Monitoring of concentrated radiation beam for photovoltaic and thermal solar energy conversion applications.

PubMed

Parretta, Antonio; Privato, Carlo; Nenna, Giuseppe; Antonini, Andrea; Stefancich, Marco

2006-10-20

Methods for evaluating the light intensity distribution on receivers of concentrated solar radiation systems are described. They are based on the use of Lambertian diffusers in place of the illuminated receiver and on the acquisition of the scattered light, in reflection or transmission mode, by a CCD camera. The spatial distribution of intensity radiation is then numerically derived from the recorded images via a proprietary code. The details of the method are presented and a short survey of the main applications of the method in the photovoltaic and thermal solar energy conversion field is proposed. Methods for investigating the Lambertian character of commercial diffusers are also discussed.

ION INJECTION AT QUASI-PARALLEL SHOCKS SEEN BY THE CLUSTER SPACECRAFT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johlander, A.; Vaivads, A.; Khotyaintsev, Yu. V.

2016-01-20

Collisionless shocks in space plasma are known to be capable of accelerating ions to very high energies through diffusive shock acceleration (DSA). This process requires an injection of suprathermal ions, but the mechanisms producing such a suprathermal ion seed population are still not fully understood. We study acceleration of solar wind ions resulting from reflection off short large-amplitude magnetic structures (SLAMSs) in the quasi-parallel bow shock of Earth using in situ data from the four Cluster spacecraft. Nearly specularly reflected solar wind ions are observed just upstream of a SLAMS. The reflected ions are undergoing shock drift acceleration (SDA) andmore » obtain energies higher than the solar wind energy upstream of the SLAMS. Our test particle simulations show that solar wind ions with lower energy are more likely to be reflected off the SLAMS, while high-energy ions pass through the SLAMS, which is consistent with the observations. The process of SDA at SLAMSs can provide an effective way of accelerating solar wind ions to suprathermal energies. Therefore, this could be a mechanism of ion injection into DSA in astrophysical plasmas.« less

Analysis of direct to diffuse partitioning of global solar irradiance at the radiometric station in Badajoz (Spain)

NASA Astrophysics Data System (ADS)

Sanchez, G.; Cancillo, M. L.; Serrano, A.

2010-09-01

This study is aimed at the analysis of the partitioning of global solar irradiance into its direct and diffuse components at the radiometric station in Badajoz (Spain). The detailed knowledge of the solar radiation field is of increasing interest in Southern Europe due to its use as renewable energy. In particular, the knowledge of the solar radiation partitioning into direct and diffuse radiation has become a major demand for the design and suitable orientation of solar panels in solar power plants. In this study the first measurements of solar diffuse irradiance performed in the radiometric station in Badajoz (Spain) are presented and analyzed in the framework of the partitioning of solar global radiation. Thus, solar global and diffuse irradiance were measured at one-minute basis from 23 November 2009 to 31 March 2010. Solar irradiances were measured by two Kipp&Zonen CMP11 pyranometers, using a Kipp&Zonen CM121 shadow ring for the measurements of solar diffuse irradiance. Diffuse measurements were corrected from the solid angle hidden by the ring and direct irradiance was calculated as the difference between global and diffuse measurements. Irradiance was obtained from the pyranomenters by applying calibration coefficients obtained in an inter-comparison campaign performed at INTA/El Arenosillo, in Huelva (Spain), last September 2009. There, calibration coefficients were calculated using as a reference a CMP11 pyranometer which had been previously calibrated by the Physikalisch-Meteorologisches Observatorium Davos/World Radiation Centre in Switzerland. In order to study the partitioning of the solar radiation, the global and diffuse irradiances have been analyzed for three typical different sky conditions: cloud-free, broken clouds and overcast. Particular days within the period of study have been selected by visual inspection. Along with the analysis of the global and diffuse irradiances themselves, ratios of these irradiances to the downward irradiance at the top of the atmosphere have also been analyzed. Several interesting features have been found. It is particularly worth to note the decreasing relative contribution of the direct component to the global irradiance as the solar zenith angle increases, due to a longer path crossed within the atmosphere. In broken clouds and overcast conditions, the diffuse component becomes the major contribution to the irradiance being the high-frequency variability the main difference between both type of cases. While in overcast conditions the global irradiance remains remarkably low, under broken clouds the global irradiance shows a very high variability frequently reaching values higher than the irradiance at the top of the atmosphere, due to multi-reflection phenomenon. The present study contributes to a better knowledge of the radiation field and its partitioning, involving original high-frequency measurements.

The Solar Ultraviolet Environment at the Ocean.

PubMed

Mobley, Curtis D; Diffey, Brian L

2018-05-01

Atmospheric and oceanic radiative transfer models were used to compute spectral radiances between 285 and 400 nm onto horizontal and vertical plane surfaces over water. The calculations kept track of the contributions by the sun's direct beam, by diffuse-sky radiance, by radiance reflected from the sea surface and by water-leaving radiance. Clear, hazy and cloudy sky conditions were simulated for a range of solar zenith angles, wind speeds and atmospheric ozone concentrations. The radiances were used to estimate erythemal exposures due to the sun and sky, as well as from radiation reflected by the sea surface and backscattered from the water column. Diffuse-sky irradiance is usually greater than direct-sun irradiance at wavelengths below 330 nm, and reflected and water-leaving irradiance accounts for <20% of the UV exposure on a vertical surface. Total exposure depends strongly on solar zenith angle and azimuth angle relative to the sun. Sea surface roughness affects the UV exposures by only a few percent. For very clear waters and the sun high in the sky, the UV index within the water can be >10 at depths down to two meters and >6 down to 5 m. © 2018 The American Society of Photobiology.

Landsat-7 ETM+ on-orbit reflective-band radiometric stability and absolute calibration

USGS Publications Warehouse

Markham, B.L.; Thome, K.J.; Barsi, J.A.; Kaita, E.; Helder, Dennis L.; Barker, J. L.; Scaramuzza, Pat

2004-01-01

Launched in April 1999, the Landsat-7 Enhanced Thematic Mapper Plus (ETM+) instrument is in its sixth year of operation. The ETM+ instrument has been the most stable of any of the Landsat instruments. To date, the best onboard calibration source for the reflective bands has been the Full Aperture Solar Calibrator, a solar-diffuser-based system, which has indicated changes of between 1% to 2% per year in the ETM+ gain for bands 1-4 and 8 and less than 0.5%/year for bands 5 and 7. However, most of this change is believed to be caused by changes in the solar diffuser panel, as opposed to a change in the instrument's gain. This belief is based partially on vicarious calibrations and observations of "invariant sites", hyperarid sites of the Sahara and Arabia. Weighted average slopes determined from these datasets suggest changes of 0.0% to 0.4% per year for bands 1-4 and 8 and 0.4% to 0.5% per year for bands 5 and 7. Absolute calibration of the reflective bands of the ETM+ is consistent with vicarious observations and other sensors generally at the 5% level, though there appear to be some systematic differences.

A Traceable Ground to On-Orbit Radiometric Calibration System for the Solar Reflective Wavelength Region

NASA Technical Reports Server (NTRS)

Heath, Donald F.; Georgiev, Georgi

2012-01-01

This paper describes the combination of a Mie scattering spectral BSDF and BTDF albedo standard whose calibration is traceable to the NIST SIRCUS Facility or the NIST STARR II Facility. The Space-based Calibration Transfer Spectroradiometer (SCATS) sensor uses a simple, invariant optical configuration and dedicated narrow band spectral channel modules to provide very accurate, polarization-insensitive, stable measurements of earth albedo and lunar disk albedo. Optical degradation effects on calibration stability are eliminated through use of a common optical system for observations of the Sun, Earth, and Moon. The measurements from space would be traceable to SI units through preflight calibrations of radiance and irradiance at NIST's SIRCUS facility and the invariant optical system used in the sensor. Simultaneous measurements are made in multiple spectral channels covering the solar reflective wavelength range of 300 nm to 2.4 microns. The large dynamic range of signals is handled by use of single-element, highly-linear detectors, stable discrete electronic components, and a non imaging optical configuration. Up to 19 spectral modules can be mounted on a single-axis drive to give direct pointing at the Earth and at least once per orbit view of the Sun and Moon. By observing the Sun on every orbit, the most stringent stability requirements of the system are limited to short time periods. The invariant optical system for both radiance and irradiance measurements also give excellent transfer to-orbit SI traceability. Emerging instrumental requirements for remotely sensing tropospheric trace species have led to a rethinking by some of the paradigm for Systeme International d'Unites (SI) traceability of the spectral irradiance and radiance radiometric calibrations to spectral albedo (sr(exp -1)) which is not a SI unit. In the solar reflective wavelength region the spectral albedo calibrations are tied often to either the spectral albedo of a solar diffuser or the Moon. This new type of Mie scattering diffuser (MSD) is capable of withstanding high temperatures, and is more Lambertian than Spectralon(tm). It has the potential of covering the entire solar reflective wavelength region. Laboratory measurements have shown that the specular reflectance component is negligible, and indicate that internal absorption by multiple scattering is small. This MSD, a true volume diffuser, exhibits a high degree of radiometric stability which suggests that measurements at the National Institute of Standards and Technology (NIST) could provide a spectral albedo standard. Measurements have been made of its radiometric stability under a simulated space environment of high energy gamma rays, high energy protons, and UV radiation from ambient down to the vacuum ultraviolet H Lyman alpha at 121.6 nm for its eventual use in space as a solar diffuser.

Impacts of the Angular Dependence of the Solar Diffuser BRDF Degradation Factor on the SNPP VIIRS Reflective Solar Band On-Orbit Radiometric Calibration

NASA Technical Reports Server (NTRS)

Lei, Ning; Xiong, Xiaoxiong

2016-01-01

Using an onboard sunlit solar diffuser (SD) as the primary radiance source, the visible infrared imaging radiometer suite (VIIRS) on the Suomi National Polar-orbiting Partnership satellite regularly performs radiometric calibration of its reflective solar bands (RSBs). The SD bidirectional reflectance distribution function (BRDF) value decreases over time. A numerical degradation factor is used to quantify the degradation and is determined by an onboard SD stability monitor (SDSM), which observes the sun and the sunlit SD at almost the same time. We had shown previously that the BRDF degradation factor was angle-dependent. Consequently, due to that the SDSM and the RSB view the SD at very different angles relative to both the solar and the SD surface normal vectors, directly applying the BRDF degradation factor determined by the SDSM to the VIIRS RSB calibration can result in large systematic errors. We develop a phenomenological model to calculate the BRDF degradation factor for the RSB SD view from the degradation factor for the SDSM SD view. Using the yearly undulations observed in the VIIRS detector gains for the M1-M4 bands calculated with the SD BRDF degradation factor for the SDSM SD view and the difference between the VIIRS detector gains calculated from the SD and the lunar observations, we obtain the model parameter values and thus establish the relation between the BRDF degradation factors for the RSB and the SDSM SD view directions.

Diffuse reflection from a stochastically bounded, semi-infinite medium

NASA Technical Reports Server (NTRS)

Lumme, K.; Peltoniemi, J. I.; Irvine, W. M.

1990-01-01

In order to determine the diffuse reflection from a medium bounded by a rough surface, the problem of radiative transfer in a boundary layer characterized by a statistical distribution of heights is considered. For the case that the surface is defined by a multivariate normal probability density, the propagation probability for rays traversing the boundary layer is derived and, from that probability, a corresponding radiative transfer equation. A solution of the Eddington (two stream) type is found explicitly, and examples are given. The results should be applicable to reflection from the regoliths of solar system bodies, as well as from a rough ocean surface.

Radiation transfer in plant canopies - Scattering of solar radiation and canopy reflectance

NASA Technical Reports Server (NTRS)

Verstraete, Michel M.

1988-01-01

The one-dimensional vertical model of radiation transfer in a plant canopy described by Verstraete (1987) is extended to account for the transfer of diffuse radiation. This improved model computes the absorption and scattering of both visible and near-infrared radiation in a multilayer canopy as a function of solar position and leaf orientation distribution. Multiple scattering is allowed, and the spectral reflectance of the vegetation stand is predicted. The results of the model are compared to those of other models and actual observations.

ADEOS Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

NASA Technical Reports Server (NTRS)

Krueger, A.; Bhartia, P. K.; McPeters, R.; Herman, J.; Wellemeyer, C.; Jaross, G.; Seftor, C.; Torres, O.; Labow, G.; Byerly, W.;

VIIRS reflective solar bands on-orbit calibration and performance: a three-year update

NASA Astrophysics Data System (ADS)

Sun, Junqiang; Wang, Menghua

2014-11-01

The on-orbit calibration of the reflective solar bands (RSBs) of VIIRS and the result from the analysis of the up-to-date 3 years of mission data are presented. The VIIRS solar diffuser (SD) and lunar calibration methodology are discussed, and the calibration coefficients, called F-factors, for the RSBs are given for the latest reincarnation. The coefficients derived from the two calibrations are compared and the uncertainties of the calibrations are discussed. Numerous improvements are made, with the major improvement to the calibration result come mainly from the improved bidirectional reflectance factor (BRF) of the SD and the vignetting functions of both the SD screen and the sun-view screen. The very clean results, devoid of many previously known noises and artifacts, assures that VIIRS has performed well for the three years on orbit since launch, and in particular that the solar diffuser stability monitor (SDSM) is functioning essentially without flaws. The SD degradation, or H-factors, for most part shows the expected decline except for the surprising rise on day 830 lasting for 75 days signaling a new degradation phenomenon. Nevertheless the SDSM and the calibration methodology have successfully captured the SD degradation for RSB calibration. The overall improvement has the most significant and direct impact on the ocean color products which demands high accuracy from RSB observations.

Study on the fabrication of back surface reflectors in nano-crystalline silicon thin-film solar cells by using random texturing aluminum anodization

NASA Astrophysics Data System (ADS)

Shin, Kang Sik; Jang, Eunseok; Cho, Jun-Sik; Yoo, Jinsu; Park, Joo Hyung; Byungsung, O.

2015-09-01

In recent decades, researchers have improved the efficiency of amorphous silicon solar cells in many ways. One of the easiest and most practical methods to improve solar-cell efficiency is adopting a back surface reflector (BSR) as the bottom layer or as the substrate. The BSR reflects the incident light back to the absorber layer in a solar cell, thus elongating the light path and causing the so-called "light trapping effect". The elongation of the light path in certain wavelength ranges can be enhanced with the proper scale of BSR surface structure or morphology. An aluminum substrate with a surface modified by aluminum anodizing is used to improve the optical properties for applications in amorphous silicon solar cells as a BSR in this research due to the high reflectivity and the low material cost. The solar cells with a BSR were formed and analyzed by using the following procedures: First, the surface of the aluminum substrate was degreased by using acetone, ethanol and distilled water, and it was chemically polished in a dilute alkali solution. After the cleaning process, the aluminum surface's morphology was modified by using a controlled anodization in a dilute acid solution to form oxide on the surface. The oxidized film was etched off by using an alkali solution to leave an aluminum surface with randomly-ordered dimple-patterns of approximately one micrometer in size. The anodizing conditions and the anodized aluminum surfaces after the oxide layer had been removed were systematically investigated according to the applied voltage. Finally, amorphous silicon solar cells were deposited on a modified aluminum plate by using dc magnetron sputtering. The surfaces of the anodized aluminum were observed by using field-emission scanning electron microscopy. The total and the diffuse reflectances of the surface-modified aluminum sheets were measured by using UV spectroscopy. We observed that the diffuse reflectances increased with increasing anodizing voltage. The properties of the solar cells on anodized aluminum substrates were analyzed by using a solar simulator.

VIIRS On-Orbit Calibration for Ocean Color Data Processing

NASA Technical Reports Server (NTRS)

Eplee, Robert E., Jr.; Turpie, Kevin R.; Fireman, Gwyn F.; Meister, Gerhard; Stone, Thomas C.; Patt, Frederick S.; Franz, Bryan; Bailey, Sean W.; Robinson, Wayne D.; McClain, Charles R.

2012-01-01

The NASA VIIRS Ocean Science Team (VOST) has the task of evaluating Suomi NPP VIIRS ocean color data for the continuity of the NASA ocean color climate data records. The generation of science quality ocean color data products requires an instrument calibration that is stable over time. Since the VIIRS NIR Degradation Anomaly directly impacts the bands used for atmospheric correction of the ocean color data (Bands M6 and M7), the VOST has adapted the VIIRS on-orbit calibration approach to meet the ocean science requirements. The solar diffuser calibration time series and the solar diffuser stability monitor time series have been used to derive changes in the instrument response and diffuser reflectance over time for bands M1-M11.

SWIR calibration of Spectralon reflectance factor

NASA Astrophysics Data System (ADS)

Georgiev, Georgi T.; Butler, James J.; Cooksey, Catherine; Ding, Leibo; Thome, Kurtis J.

2011-11-01

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Factor (BRF) of laboratory-based diffusers used in their pre-flight and on-orbit radiometric calibrations. BRF measurements are required throughout the reflected-solar spectrum from the ultraviolet through the shortwave infrared. Spectralon diffusers are commonly used as a reflectance standard for bidirectional and hemispherical geometries. The Diffuser Calibration Laboratory (DCaL) at NASA's Goddard Space Flight Center is a secondary calibration facility with reflectance measurements traceable to those made by the Spectral Tri-function Automated Reference Reflectometer (STARR) facility at the National Institute of Standards and Technology (NIST). For more than two decades, the DCaL has provided numerous NASA projects with BRF data in the ultraviolet (UV), visible (VIS) and the Near InfraRed (NIR) spectral regions. Presented in this paper are measurements of BRF from 1475 nm to 1625 nm obtained using an indium gallium arsenide detector and a tunable coherent light source. The sample was a 50.8 mm (2 in) diameter, 99% white Spectralon target. The BRF results are discussed and compared to empirically generated data from a model based on NIST certified values of 6°directional-hemispherical spectral reflectance factors from 900 nm to 2500 nm. Employing a new NIST capability for measuring bidirectional reflectance using a cooled, extended InGaAs detector, BRF calibration measurements of the same sample were also made using NIST's STARR from 1475 nm to 1625 nm at an incident angle of 0° and at viewing angle of 45°. The total combined uncertainty for BRF in this ShortWave Infrared (SWIR) range is less than 1%. This measurement capability will evolve into a BRF calibration service in SWIR region in support of NASA remote sensing missions.

Calibration requirements and methodology for remote sensors viewing the ocean in the visible

NASA Technical Reports Server (NTRS)

Gordon, Howard R.

1987-01-01

The calibration requirements for ocean-viewing sensors are outlined, and the present methods of effecting such calibration are described in detail. For future instruments it is suggested that provision be made for the sensor to view solar irradiance in diffuse reflection and that the moon be used as a source of diffuse light for monitoring the sensor stability.

NPP VIIRS and Aqua MODIS RSB Comparison Using Observations from Simultaneous Nadir Overpasses (SNO)

NASA Technical Reports Server (NTRS)

Xiong, X.; Wu, A.

2012-01-01

Suomi NPP (National Polar-orbiting Partnership) satellite (http://npp.gsfc.nasa.gov/viirs.html) began to daily collect global data following its successful launch on October 28, 2011. The Visible Infrared Imaging Radiometer Suite (VIIRS) is a key NPP sensor. Similar to the design of the OLS, SeaWiFS and MODIS instruments, VIIRS has on-board calibration components including a solar diffuser (SD) and a solar diffuser stability monitor (SDSM) for the reflective solar bands (RSB), a V-groove blackbody for the thermal emissive bands (TEB), and a space view (SV) port for background subtraction. Immediately after the VIIRS nadir door s opening on November 21, 2011, anomalously large degradation in the SD response was identified in the near-IR wavelength region, which was unexpected as decreases in the SD reflectance usually occur gradually in the blue (0.4 m) wavelength region based on past experience. In this study, we use a well-calibrated Aqua MODIS as reference to track and evaluate VIIRS RSB stability and performance. Reflectances observed by both sensors from simultaneous nadir overpasses (SNO) are used to determine VIIRS to MODIS reflectance ratios for their spectral matching bands. Results of this study provide an immediate post-launch assessment, independent validation of the anomalous degradation observed in SD measurements at near-IR wavelengths and initial analysis of calibration stability and consistency.

A study of the effect on a typical orbiter payload thermal environment resulting from specular reflections from the forward orbiter radiators

NASA Technical Reports Server (NTRS)

Humphries, R.; Turner, L.; Littles, J. W.

1979-01-01

The orbiter radiator external coating is highly specular silverized Teflon. Solar energy specularly reflected from these radiators on a typical payload which, when deployed, extends above the payload bay envelope was studied. The flux levels are compared assuming both diffuse and specular radiators.

Assessment of stability of the response versus scan angle for the S-NPP VIIRS reflective solar bands using pseudo-invariant desert and Dome C sites

NASA Astrophysics Data System (ADS)

Wu, Aisheng; Xiong, Xiaoxiong J.; Cao, Changyong

2017-09-01

The Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi NPP (National Polar-orbiting Partnership) satellite has been in operation for over five years. VIIRS has 22 bands with a spectral range from 0.4 μm to 2.2 μm for the reflective solar bands (RSB). The Earth view swath covers a distance of 3000 km over scan angles of +/- 56.0° off nadir. The on-board calibration of the RSB relies on a solar diffuser (SD) located at a fixed scan angle and a solar diffuser stability monitor (SDSM). The response versus scan angle (RVS) was characterized prelaunch in ambient conditions and is currently used to determine the on-orbit response for all scan angles relative to the SD scan angle. Since the RVS is vitally important to the quality of calibrated level 1B products, it is important to monitor its on-orbit stability, particularly at the short wavelengths (blue) where the most degradation occurs. In this study, the RVS stability is examined based on reflectance trends collected at various scan angles over the selected pseudo-invariant desert sites in Northern Africa and the Dome C snow site in Antarctica. These trends are corrected by the site dependent BRDF (bi-directional reflectance function) model to reduce seasonally related fluctuations. The BRDF corrected trends are examined so any systematic drifts in the scan angle direction would indicate a potential change in RVS. The results of this study provide useful information on VIIRS RVS on-orbit stability performance.

MODIS Solar Diffuser On-Orbit Degradation Characterization Using Improved SDSM Screen Modeling

NASA Technical Reports Server (NTRS)

Chen, H.; Xiong, Xiaoxiong; Angal, Amit Avinash; Wang, Z.; Wu, A.

2016-01-01

The Solar Diffuser (SD) is used for the MODIS reflective solar bands (RSB) calibration. An on-board Solar Diffuser Stability Monitor (SDSM) tracks the degradation of its on-orbit bi-directional reflectance factor (BRF). To best match the SDSM detector signals from its Sun view and SD view, a fixed attenuation screen is placed in its Sun view path, where the responses show ripples up to 10%, much larger than design expectation. Algorithms have been developed since the mission beginning to mitigate the impacts of these ripples. In recent years, a look-up-table (LUT) based approach has been implemented to account for these ripples. The LUT modeling of the elevation and azimuth angles is constructed from the detector 9 (D9) of SDSM observations in the MODIS early mission. The response of other detectors is normalized to D9 to reduce the ripples observed in the sun-view data. The accuracy of all detectors degradation estimation depends on how well the D9 approximated. After multiple years of operation (Terra: 16 years; Aqua: 14 years), degradation behavior of all detectors can be monitored by their own. This paper revisits the LUT modeling and proposes a dynamic scheme to build a LUT independently for each detector. Further refinement in the Sun view screen characterization will be highlighted to ensure the degradation estimation accuracy. Results of both Terra and Aqua SD on-orbit degradation are derived from the improved modeling and curve fitting strategy.

Procedure for measuring simultaneously the solar and visible properties of glazing with complex internal or external structures.

PubMed

Gentle, A R; Smith, G B

2014-10-20

Accurate solar and visual transmittances of materials in which surfaces or internal structures are complex are often not easily amenable to standard procedures with laboratory-based spectrophotometers and integrating spheres. Localized "hot spots" of intensity are common in such materials, so data on small samples is unreliable. A novel device and simple protocols have been developed and undergone validation testing. Simultaneous solar and visible transmittance and reflectance data have been acquired for skylight components and multilayer polycarbonate roof panels. The pyranometer and lux sensor setups also directly yield "light coolness" in lumens/watt. Sample areas must be large, and, although mainly in sheet form, some testing has been done on curved panels. The instrument, its operation, and the simple calculations used are described. Results on a subset of diffuse and partially diffuse materials with no hot spots have been cross checked using 150 mm integrating spheres with a spectrophotometer and the Air Mass 1.5 spectrum. Indications are that results are as good or better than with such spheres for transmittance, but reflectance techniques need refinement for some sample types.

Mapping diffuse photosynthetically active radiation from satellite data in Thailand

NASA Astrophysics Data System (ADS)

Choosri, P.; Janjai, S.; Nunez, M.; Buntoung, S.; Charuchittipan, D.

2017-12-01

In this paper, calculation of monthly average hourly diffuse photosynthetically active radiation (PAR) using satellite data is proposed. Diffuse PAR was analyzed at four stations in Thailand. A radiative transfer model was used for calculating the diffuse PAR for cloudless sky conditions. Differences between the diffuse PAR under all sky conditions obtained from the ground-based measurements and those from the model are representative of cloud effects. Two models are developed, one describing diffuse PAR only as a function of solar zenith angle, and the second one as a multiple linear regression with solar zenith angle and satellite reflectivity acting linearly and aerosol optical depth acting in logarithmic functions. When tested with an independent data set, the multiple regression model performed best with a higher coefficient of variance R2 (0.78 vs. 0.70), lower root mean square difference (RMSD) (12.92% vs. 13.05%) and the same mean bias difference (MBD) of -2.20%. Results from the multiple regression model are used to map diffuse PAR throughout the country as monthly averages of hourly data.

Ionospheric Irregularities at Mars Probed by MARSIS Topside Sounding

NASA Astrophysics Data System (ADS)

Harada, Y.; Gurnett, D. A.; Kopf, A. J.; Halekas, J. S.; Ruhunusiri, S.

2018-01-01

The upper ionosphere of Mars contains a variety of perturbations driven by solar wind forcing from above and upward propagating atmospheric waves from below. Here we explore the global distribution and variability of ionospheric irregularities around the exobase at Mars by analyzing topside sounding data from the Mars Advanced Radar for Subsurface and Ionosphere Sounding (MARSIS) instrument on board Mars Express. As irregular structure gives rise to off-vertical echoes with excess propagation time, the diffuseness of ionospheric echo traces can be used as a diagnostic tool for perturbed reflection surfaces. The observed properties of diffuse echoes above unmagnetized regions suggest that ionospheric irregularities with horizontal wavelengths of tens to hundreds of kilometers are particularly enhanced in the winter hemisphere and at high solar zenith angles. Given the known inverse dependence of neutral gravity wave amplitudes on the background atmospheric temperature, the ionospheric irregularities probed by MARSIS are most likely associated with plasma perturbations driven by atmospheric gravity waves. Though extreme events with unusually diffuse echoes are more frequently observed for high solar wind dynamic pressures during some time intervals, the vast majority of the diffuse echo events are unaffected by varying solar wind conditions, implying limited influence of solar wind forcing on the generation of ionospheric irregularities. Combination of remote and in situ measurements of ionospheric irregularities would offer the opportunity for a better understanding of the ionospheric dynamics at Mars.

A general method for computing the total solar radiation force on complex spacecraft structures

NASA Technical Reports Server (NTRS)

Chan, F. K.

1981-01-01

The method circumvents many of the existing difficulties in computational logic presently encountered in the direct analytical or numerical evaluation of the appropriate surface integral. It may be applied to complex spacecraft structures for computing the total force arising from either specular or diffuse reflection or even from non-Lambertian reflection and re-radiation.

Indoor Light Performance of Coil Type Cylindrical Dye Sensitized Solar Cells.

PubMed

Kapil, Gaurav; Ogomi, Yuhei; Pandey, Shyam S; Ma, Tingli; Hayase, Shuzi

2016-04-01

A very good performance under low/diffused light intensities is one of the application areas in which dye-sensitized solar cells (DSSCs) can be utilized effectively compared to their inorganic silicon solar cell counterparts. In this article, we have investigated the 1 SUN and low intensity fluorescent light performance of Titanium (Ti)-coil based cylindrical DSSC (C-DSSC) using ruthenium based N719 dye and organic dyes such as D205 and Y123. Electrochemical impedance spectroscopic results were analyzed for variable solar cell performances. Reflecting mirror with parabolic geometry as concentrator was also utilized to tap diffused light for indoor applications. Fluorescent light at relatively lower illumination intensities (0.2 mW/cm2 to 0.5 mW/cm2) were used for the investigation of TCO-less C-DSSC performance with and without reflector geometry. Furthermore, the DSSC performances were analyzed and compared with the commercially available amorphous silicon based solar cell for indoor applications.

Inferring ultraviolet anatomical exposure patterns while distinguishing the relative contribution of radiation components

NASA Astrophysics Data System (ADS)

Vuilleumier, Laurent; Milon, Antoine; Bulliard, Jean-Luc; Moccozet, Laurent; Vernez, David

2013-05-01

Exposure to solar ultraviolet (UV) radiation is the main causative factor for skin cancer. UV exposure depends on environmental and individual factors, but individual exposure data remain scarce. While ground UV irradiance is monitored via different techniques, it is difficult to translate such observations into human UV exposure or dose because of confounding factors. A multi-disciplinary collaboration developed a model predicting the dose and distribution of UV exposure on the basis of ground irradiation and morphological data. Standard 3D computer graphics techniques were adapted to develop a simulation tool that estimates solar exposure of a virtual manikin depicted as a triangle mesh surface. The amount of solar energy received by various body locations is computed for direct, diffuse and reflected radiation separately. Dosimetric measurements obtained in field conditions were used to assess the model performance. The model predicted exposure to solar UV adequately with a symmetric mean absolute percentage error of 13% and half of the predictions within 17% range of the measurements. Using this tool, solar UV exposure patterns were investigated with respect to the relative contribution of the direct, diffuse and reflected radiation. Exposure doses for various body parts and exposure scenarios of a standing individual were assessed using erythemally-weighted UV ground irradiance data measured in 2009 at Payerne, Switzerland as input. For most anatomical sites, mean daily doses were high (typically 6.2-14.6 Standard Erythemal Dose, SED) and exceeded recommended exposure values. Direct exposure was important during specific periods (e.g. midday during summer), but contributed moderately to the annual dose, ranging from 15 to 24% for vertical and horizontal body parts, respectively. Diffuse irradiation explained about 80% of the cumulative annual exposure dose.

Two years comparative studies on biological effects of environmental UV radiation

NASA Astrophysics Data System (ADS)

Grof, P.; Ronto, Gyorgyi; Gaspar, S.; Berces, A.; Szabo, Laszlo D.

1994-07-01

A method has been developed for determination of the biologically effective UV dose based on T7 phage as biosensor. In field experiments clockwork driven telescope has been used for determining doses from direct and global (direct plus diffuse) solar radiation. On fine summer days at mid-latitude this arrangement allowed the following comparisons: measured doses from direct and global radiation obtained at the same time and measuring site reflecting the biological importance of diffuse radiation; direct and global radiation obtained at the same time and measuring site reflecting the biological importance of diffuse radiation; direct and global doses obtained at the same time on different measuring sites (downtown, suburb, outside the town) reflecting the differences caused by air quality; direct and global doses obtained on the same measuring place, in summertime of two different years reflecting the importance of the long-term measurements for estimating the biological risk caused by increased UV-B radiation; measured data and model calculations.

A hybrid HDRF model of GOMS and SAIL: GOSAIL

NASA Astrophysics Data System (ADS)

Dou, B.; Wu, S.; Wen, J.

2016-12-01

Understanding the surface reflectance anisotropy is the key facet in interpreting the features of land surface from remotely sensed information, which describes the property of land surface to reflect the solar radiation directionally. Most reflectance anisotropy models assumed the nature surface was illuminated only by the direct solar radiation, while the diffuse skylight becomes dominant especially for the over cast sky conditions and high rugged terrain. Correcting the effect of diffuse skylight on the reflectance anisotropy to obtain the intrinsic directional reflectance of land surface is highly desirable for remote sensing applications. This paper developed a hybrid HDRF model of GOMS and SAIL called GOSAIL model for discrete canopies. The accurate area proportions of four scene components are calculated by the GOMS model and the spectral signatures of scene components are provided by the SAIL model. Both the single scattering contribution and the multiple scattering contributions within and between the canopy and background under the clear and diffuse illumination conditions are considered in the GOSAIL model. The HDRF simulated by the 3-D Discrete Anisotropic Radiative Transfer (DART) model and the HDRF measurements over the 100m×100m mature pine stand at the Järvselja, Estonia are used for validating and evaluating the performance of proposed GOSAIL model. The comparison results indicate the GOSAIL model can accurately reproducing the angular feature of discrete canopy for both the clear and overcast atmospheric conditions. The GOSAIL model is promising for the land surface biophysical parameters retrieval (e.g. albedo, leaf area index) over the heterogeneous terrain.

Suomi-NPP VIIRS Solar Diffuser Stability Monitor Performance

NASA Technical Reports Server (NTRS)

Fulbright, Jon; Lei, Ning; Efremova, Boryana; Xiong, Xiaoxiong

2015-01-01

When illuminated by the Sun, the onboard solar diffuser (SD) panel provides a known spectral radiance source to calibrate the reflective solar bands of the Visible Infrared Imaging Radiometer Suite on the Suomi-NPP satellite. The SD bidirectional reflectance distribution function (BRDF) degrades over time due to solar exposure, and this degradation is measured using the SD stability monitor (SDSM). The SDSM acts as a ratioing radiometer, comparing solar irradiance measurements off the SD panel to those from a direct Sun view. We discuss the design and operations of the SDSM, the SDSM data analysis, including improvements incorporated since launch, and present the results through 1000 days after launch. After 1000 days, the band-dependent H-factors, a quantity describing the relative degradation of the BRDF of the SD panel since launch, range from 0.716 at 412 nanometers to 0.989 at 926 nanometers. The random uncertainty of these H-factors is about 0.1 percent, which is confirmed by the similar standard deviation values computed from the residuals of quadratic exponential fits to the H-factor time trends. The SDSM detector gains have temperature sensitivity of up to about 0.36 percent per kelvin, but this does not affect the derived H-factors. An initial error in the solar vector caused a seasonal bias to the H-factors of up to 0.5 percent. The total exposure of the SD panel to UV light after 1000 orbits is equivalent to about 100 hours of direct sunlight illumination perpendicular to the SD panel surface.

Ultrafast charge separation dynamics in opaque, operational dye-sensitized solar cells revealed by femtosecond diffuse reflectance spectroscopy

PubMed Central

Ghadiri, Elham; Zakeeruddin, Shaik M.; Hagfeldt, Anders; Grätzel, Michael; Moser, Jacques-E.

2016-01-01

Efficient dye-sensitized solar cells are based on highly diffusive mesoscopic layers that render these devices opaque and unsuitable for ultrafast transient absorption spectroscopy measurements in transmission mode. We developed a novel sub-200 femtosecond time-resolved diffuse reflectance spectroscopy scheme combined with potentiostatic control to study various solar cells in fully operational condition. We studied performance optimized devices based on liquid redox electrolytes and opaque TiO2 films, as well as other morphologies, such as TiO2 fibers and nanotubes. Charge injection from the Z907 dye in all TiO2 morphologies was observed to take place in the sub-200 fs time scale. The kinetics of electron-hole back recombination has features in the picosecond to nanosecond time scale. This observation is significantly different from what was reported in the literature where the electron-hole back recombination for transparent films of small particles is generally accepted to occur on a longer time scale of microseconds. The kinetics of the ultrafast electron injection remained unchanged for voltages between +500 mV and –690 mV, where the injection yield eventually drops steeply. The primary charge separation in Y123 organic dye based devices was clearly slower occurring in two picoseconds and no kinetic component on the shorter femtosecond time scale was recorded. PMID:27095505

Characterization of LANDSAT Panels Using the NIST BRDF Scale from 1100 nm to 2500 nm

NASA Technical Reports Server (NTRS)

Markham, Brian; Tsai, Benjamin K.; Allen, David W.; Cooksey, Catherine; Yoon, Howard; Hanssen, Leonard; Zeng, Jinan; Fulton, Linda; Biggar, Stuart; Markham, Brian

2010-01-01

Many earth observing sensors depend on white diffuse reflectance standards to derive scales of radiance traceable to the St Despite the large number of Earth observing sensors that operate in the reflective solar region of the spectrum, there has been no direct method to provide NIST traceable BRDF measurements out to 2500 rim. Recent developments in detector technology have allowed the NIST reflectance measurement facility to expand the operating range to cover the 250 nm to 2500 nm range. The facility has been modified with and additional detector using a cooled extended range indium gallium arsenide (Extended InGaAs) detector. Measurements were made for two PTFE white diffuse reflectance standards over the 1100 nm to 2500 nm region at a 0' incident and 45' observation angle. These two panels will be used to support the OLI calibration activities. An independent means of verification was established using a NIST radiance transfer facility based on spectral irradiance, radiance standards and a diffuse reflectance plaque. An analysis on the results and associated uncertainties will be discussed.

jasonSWIR Calibration of Spectralon Reflectance Factor

NASA Technical Reports Server (NTRS)

Georgiev, Georgi T.; Butler, James J.; Cooksey, Cahterine; Ding, Leibo; Thome, Kurtis J.

2011-01-01

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Factor (BRF) of laboratory-based diffusers used in their pre-flight and on-orbit radiometric calibrations. BRF measurements are required throughout the reflected-solar spectrum from the ultraviolet through the shortwave infrared. Spectralon diffusers are commonly used as a reflectance standard for bidirectional and hemispherical geometries. The Diffuser Calibration Laboratory (DCaL) at NASA's Goddard Space Flight Center is a secondary calibration facility with reflectance measurements traceable to those made by the Spectral Tri-function Automated Reference Reflectometer (STARR) facility at the National Institute of Standards and Technology (NIST). For more than two decades, the DCaL has provided numerous NASA projects with BRF data in the ultraviolet (UV), visible (VIS) and the Near infraRed (NIR) spectral regions. Presented in this paper are measurements of BRF from 1475nm to 1625nm obtained using an indium gallium arsenide detector and a tunable coherent light source. The sample was a 2 inch diameter, 99% white Spectralon target. The BRF results are discussed and compared to empirically generated data from a model based on NIST certified values of 6deg directional/hemispherical spectral reflectance factors from 900nm to 2500nm. Employing a new NIST capability for measuring bidirectional reflectance using a cooled, extended InGaAs detector, BRF calibration measurements of the same sample were also made using NIST's STARR from 1475nm to 1625nm at an incident angle of 0deg and at viewing angles of 40deg, 45deg, and 50deg. The total combined uncertainty for BRF in this ShortWave Infrared (SWIR) range is less than 1%. This measurement capability will evolve into a BRF calibration service in SWIR region in support of NASA remote sensing missions. Keywords: BRF, BRDF, Calibration, Spectralon, Reflectance, Remote Sensing.

Senegalese land surface change analysis and biophysical parameter estimation using NOAA AVHRR spectral data

NASA Technical Reports Server (NTRS)

Vukovich, Fred M.; Toll, David L.; Kennard, Ruth L.

1989-01-01

Surface biophysical estimates were derived from analysis of NOAA Advanced Very High Spectral Resolution (AVHRR) spectral data of the Senegalese area of west Africa. The parameters derived were of solar albedo, spectral visible and near-infrared band reflectance, spectral vegetative index, and ground temperature. Wet and dry linked AVHRR scenes from 1981 through 1985 in Senegal were analyzed for a semi-wet southerly site near Tambacounda and a predominantly dry northerly site near Podor. Related problems were studied to convert satellite derived radiance to biophysical estimates of the land surface. Problems studied were associated with sensor miscalibration, atmospheric and aerosol spatial variability, surface anisotropy of reflected radiation, narrow satellite band reflectance to broad solar band conversion, and ground emissivity correction. The middle-infrared reflectance was approximated with a visible AVHRR reflectance for improving solar albedo estimates. In addition, the spectral composition of solar irradiance (direct and diffuse radiation) between major spectral regions (i.e., ultraviolet, visible, near-infrared, and middle-infrared) was found to be insensitive to changes in the clear sky atmospheric optical depth in the narrow band to solar band conversion procedure. Solar albedo derived estimates for both sites were not found to change markedly with significant antecedent precipitation events or correspondingly from increases in green leaf vegetation density. The bright soil/substrate contributed to a high albedo for the dry related scenes, whereas the high internal leaf reflectance in green vegetation canopies in the near-infrared contributed to high solar albedo for the wet related scenes. The relationship between solar albedo and ground temperature was poor, indicating the solar albedo has little control of the ground temperature. The normalized difference vegetation index (NDVI) and the derived visible reflectance were more sensitive to antecedent rainfall amounts and green vegetation changes than were near-infrared changes. The information in the NDVI related to green leaf density changes primarily was from the visible reflectance. The contribution of the near-infrared reflectance to explaining green vegetation is largely reduced when there is a bright substrate.

Development of a high efficiency thin silicon solar cell

NASA Technical Reports Server (NTRS)

Lindmayer, J.; Wrigley, C. Y.

1977-01-01

A key to the success of this program was the breakthrough development of a technology for producing ultra-thin silicon slices which are very flexible, resilient, and tolerant of moderate handling abuse. Experimental topics investigated were thinning technology, gaseous junction diffusion, aluminum back alloying, internal reflectance, tantalum oxide anti-reflective coating optimization, slice flexibility, handling techniques, production rate limiting steps, low temperature behavior, and radiation tolerance.

Improvements of VIIRS and MODIS Solar Diffuser and Lunar Calibration

NASA Technical Reports Server (NTRS)

Xiong, Xiaoxiong; Butler, James J.; Lei, Ning; Sun, Junqiang; Fulbright, Jon; Wang, Zhipeng; McIntire, Jeff; Angal, Amit Avinash

2013-01-01

Both VIIRS and MODIS instruments use solar diffuser (SD) and lunar observations to calibrate their reflective solar bands (RSB). A solar diffuser stability monitor (SDSM) is used to track the SD on-orbit degradation. On-orbit observations have shown similar wavelength-dependent SD degradation (larger at shorter VIS wavelengths) and SDSM detector response degradation (larger at longer NIR wavelengths) for both VIIRS and MODIS instruments. In general, the MODIS scan mirror has experienced more degradation in the VIS spectral region whereas the VIIRS rotating telescope assembly (RTA) mirrors have seen more degradation in the NIR and SWIR spectral region. Because of this wavelength dependent mirror degradation, the sensor's relative spectral response (RSR) needs to be modulated. Due to differences between the solar and lunar spectral irradiance, the modulated RSR could have different effects on the SD and lunar calibration. In this paper, we identify various factors that should be considered for the improvements of VIIRS and MODIS solar and lunar calibration and examine their potential impact. Specifically, we will characterize and assess the calibration impact due to SD and SDSM attenuation screen transmission (uncertainty), SD BRF uncertainty and onorbit degradation, SDSM detector response degradation, and modulated RSR resulting from the sensor's optics degradation. Also illustrated and discussed in this paper are the calibration strategies implemented in the VIIRS and MODIS SD and lunar calibrations and efforts that could be made for future improvements.

Aerosol Optical Depth Retrievals From High-Resolution Commercial Satellite Imagery Over Areas of High Surface Reflectance

NASA Astrophysics Data System (ADS)

Vincent, D. A.; Nielsen, K. E.; Durkee, P. A.; Reid, J. S.

2005-12-01

The advancement and proliferation of high-resolution commercial imaging satellites presents a new opportunity for overland aerosol characterization. Current aerosol optical depth retrieval methods typically fail over areas with high surface reflectance, such as urban areas and deserts, since the upwelling radiance due to scattering by aerosols is small compared to the radiance resulting from surface reflection. The method proposed here uses shadows cast on the surface to exploit the differences between radiance from the adjacent shaded and unshaded areas of the scene. Shaded areas of the scene are primarily illuminated by diffuse irradiance that is scattered downward from the atmosphere, while unshaded areas are illuminated by both diffuse and direct solar irradiance. The first-order difference between the shaded and unshaded areas is the direct component. Given uniform surface reflectance for the shaded and unshaded areas, the difference in reflected radiance measured by a satellite sensor is related to the direct transmission of solar radiation and inversely proportional to total optical depth. Using an iterative approach, surface reflectance and mean aerosol reflectance can be partitioned to refine the retrieved total optical depth. Aerosol optical depth can then be determined from its contribution to the total atmospheric optical depth (following correction for molecular Rayleigh scattering). Intitial results based on QuickBird imagery and AERONET data collected during the United Arab Emirates Unified Aerosol Experiment (UAE2) indicate that aerosol optical depth retrievals are possible in the visible and near-infrared region with an accuracy of ~0.04.

SeaWiFS Postlaunch Technical Report Series. Volume 5; The SeaWiFS Solar Radiation-Based Calibration and the Transfer-to-Orbit Experiment

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Barnes, Robert A.; Eplee, Robert E., Jr.; Biggar, Stuart F.; Thome, Kurtis J.; Zalewski, Edward F.; Slater, Philip N.; Holmes, Alan W.

1999-01-01

The solar radiation-based calibration (SRBC) of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) was performed on 1 November 1993. Measurements were made outdoors in the courtyard of the instrument manufacturer. SeaWiFS viewed the solar irradiance reflected from the sensor's diffuser in the same manner as viewed on orbit. The calibration included measurements using a solar radiometer designed to determine the transmittances of principal atmospheric constituents. The primary uncertainties in the outdoor measurements are the transmission of the atmosphere and the reflectance of the diffuser. Their combined uncertainty is about 5 or 6%. The SRBC also requires knowledge of the extraterrestrial solar spectrum. Four solar models are used. When averaged over the responses of the SeaWiFS bands, the irradiance models agree at the 3.6% level, with the greatest difference for SeaWiFS band 8. The calibration coefficients from the SRBC are lower than those from the laboratory calibration of the instrument in 1997. For a representative solar model, the ratios of the SRBC coefficients to laboratory values average 0.962 with a standard deviation of 0.012. The greatest relative difference is 0.946 for band 8. These values are within the estimated uncertainties of the calibration measurements. For the transfer-to-orbit experiment, the measurements in the manufacturer's courtyard are used to predict the digital counts from the instrument on its first day on orbit (August 1, 1997). This experiment requires an estimate of the relative change in the diffuser response for the period between the launch of the instrument and its first solar measurements on orbit (September 9, 1997). In relative terms, the counts from the instrument on its first day on orbit averaged 1.3% higher than predicted, with a standard deviation of 1.2% and a greatest difference of 2.4% or band 7. The estimated uncertainty for the transfer-to-orbit experiment is about 3 or 4%.

Earth Probe Total Ozone Mapping Spectrometer (TOMS) Data Product User's Guide

NASA Technical Reports Server (NTRS)

McPeters, R.; Bhartia, P. K.; Krueger, A.; Herman, J.; Wellemeyer, C.; Seftor, C.; Jaross, G.; Torres, O.; Moy, L.; Labow, G.;

Degradation nonuniformity in the solar diffuser bidirectional reflectance distribution function.

PubMed

Sun, Junqiang; Chu, Mike; Wang, Menghua

2016-08-01

The assumption of angular dependence stability of the solar diffuser (SD) throughout degradation is critical to the on-orbit calibration of the reflective solar bands (RSBs) in many satellite sensors. Recent evidence has pointed to the contrary, and in this work, we present a thorough investigative effort into the angular dependence of the SD degradation for the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite and for the twin Moderate-resolution Imaging Spectroradiometer (MODIS) onboard Terra and Aqua spacecrafts. One common key step in the RSB calibration is the use of the SD degradation performance measured by an accompanying solar diffuser stability monitor (SDSM) as a valid substitute for the SD degradation factor in the direction of the RSB view. If SD degradations between these two respective directions do not maintain the same relative relationship over time, then the unmitigated use of the SDSM-measured SD degradation factor in the RSB calibration calculation will generate bias, and consequently, long-term drift in derived science products. We exploit the available history of the on-orbit calibration events to examine the response of the SDSM and the RSB detectors to the incident illumination reflecting off SD versus solar declination angle and show that the angular dependency, particularly at short wavelengths, evolves with respect to time. The generalized and the decisive conclusion is that the bidirectional reflectance distribution function (BRDF) of the SD degrades nonuniformly with respect to both incident and outgoing directions. Thus, the SDSM-based measurements provide SD degradation factors that are biased relative to the RSB view direction with respect to the SD. The analysis also reveals additional interesting phenomena, for example, the sharp behavioral change in the evolving angular dependence observed in Terra MODIS and SNPP VIIRS. For SNPP VIIRS the mitigation for this "SD degradation nonuniformity effect" with respect to angles relies on a "hybrid methodology" using lunar-based calibration to set the reliable long-term baseline. For MODIS, the use of earth targets in the major release Collection 6 to improve calibration coefficients and time-dependent response-versus-scan-angle characterization inherently averts the use of SD and its associated issues. The work further supports that having an open-close operational capability for the space view door can minimize SD degradation and its associated effects due to solar exposure, and thus provide long-term benefits for maintaining calibration and science data accuracy.

Fast determination of the current loss mechanisms in textured crystalline Si-based solar cells

NASA Astrophysics Data System (ADS)

Nakane, Akihiro; Fujimoto, Shohei; Fujiwara, Hiroyuki

2017-11-01

A quite general device analysis method that allows the direct evaluation of optical and recombination losses in crystalline silicon (c-Si)-based solar cells has been developed. By applying this technique, the current loss mechanisms of the state-of-the-art solar cells with ˜20% efficiencies have been revealed. In the established method, the optical and electrical losses are characterized from the analysis of an experimental external quantum efficiency (EQE) spectrum with very low computational cost. In particular, we have performed the EQE analyses of textured c-Si solar cells by employing the experimental reflectance spectra obtained directly from the actual devices while using flat optical models without any fitting parameters. We find that the developed method provides almost perfect fitting to EQE spectra reported for various textured c-Si solar cells, including c-Si heterojunction solar cells, a dopant-free c-Si solar cell with a MoOx layer, and an n-type passivated emitter with rear locally diffused solar cell. The modeling of the recombination loss further allows the extraction of the minority carrier diffusion length and surface recombination velocity from the EQE analysis. Based on the EQE analysis results, the current loss mechanisms in different types of c-Si solar cells are discussed.

Ground truth data for test sites (SL-4). [thermal radiation brightness temperature and solar radiation measurments

NASA Technical Reports Server (NTRS)

1974-01-01

Field measurements performed simultaneous with Skylab overpass in order to provide comparative calibration and performance evaluation measurements for the EREP sensors are presented. Wavelength region covered include: solar radiation (400 to 1300 nanometer), and thermal radiation (8 to 14 micrometer). Measurements consisted of general conditions and near surface meteorology, atmospheric temperature and humidity vs altitude, the thermal brightness temperature, total and diffuse solar radiation, direct solar radiation (subsequently analyzed for optical depth/transmittance), and target reflectivity/radiance. The particular instruments used are discussed along with analyses performed. Detailed instrument operation, calibrations, techniques, and errors are given.

Holographic spectrum-splitting optical systems for solar photovoltaics

NASA Astrophysics Data System (ADS)

Zhang, Deming

Solar energy is the most abundant source of renewable energy available. The relatively high cost prevents solar photovoltaic (PV) from replacing fossil fuel on a larger scale. In solar PV power generation the cost is reduced with more efficient PV technologies. In this dissertation, methods to improve PV conversion efficiency with holographic optical components are discussed. The tandem multiple-junction approach has achieved very high conversion efficiency. However it is impossible to manufacture tandem PV cells at a low cost due to stringent fabrication standards and limited material types that satisfy lattice compatibility. Current produced by the tandem multi-junction PV cell is limited by the lowest junction due to series connection. Spectrum-splitting is a lateral multi-junction concept that is free of lattice and current matching constraints. Each PV cell can be optimized towards full absorption of a spectral band with tailored light-trapping schemes. Holographic optical components are designed to achieve spectrum-splitting PV energy conversion. The incident solar spectrum is separated onto multiple PV cells that are matched to the corresponding spectral band. Holographic spectrum-splitting can take advantage of existing and future low-cost technologies that produces high efficiency thin-film solar cells. Spectrum-splitting optical systems are designed and analyzed with both transmission and reflection holographic optical components. Prototype holograms are fabricated and high optical efficiency is achieved. Light-trapping in PV cells increases the effective optical path-length in the semiconductor material leading to improved absorption and conversion efficiency. It has been shown that the effective optical path length can be increased by a factor of 4n2 using diffusive surfaces. Ultra-light-trapping can be achieved with optical filters that limit the escape angle of the diffused light. Holographic reflection gratings have been shown to act as angle-wavelength selective filters that can function as ultra-light-trapping filters. Results from an experimental reflection hologram are used to model the absorption enhancement factor for a silicon solar cell and light-trapping filter. The result shows a significant improvement in current generation for thin-film silicon solar cells under typical operating conditions.

Modeling the microstructure of surface by applying BRDF function

NASA Astrophysics Data System (ADS)

Plachta, Kamil

2017-06-01

The paper presents the modeling of surface microstructure using a bidirectional reflectance distribution function. This function contains full information about the reflectance properties of the flat surfaces - it is possible to determine the share of the specular, directional and diffuse components in the reflected luminous stream. The software is based on the authorial algorithm that uses selected elements of this function models, which allows to determine the share of each component. Basing on obtained data, the surface microstructure of each material can be modeled, which allows to determine the properties of this materials. The concentrator directs the reflected solar radiation onto the photovoltaic surface, increasing, at the same time, the value of the incident luminous stream. The paper presents an analysis of selected materials that can be used to construct the solar concentrator system. The use of concentrator increases the power output of the photovoltaic system by up to 17% as compared to the standard solution.

The solar ultraviolet B radiation protection provided by shading devices with regard to its diffuse component.

PubMed

Kudish, Avraham I; Harari, Marco; Evseev, Efim G

2011-10-01

The composition of the incident solar global ultraviolet B (UVB) radiation with regard to its beam and diffuse radiation fractions is highly relevant with regard to outdoor sun protection. This is especially true with respect to sun protection during leisure-time outdoor sun exposure at the shore and pools, where people tend to escape the sun under shade trees or different types of shading devices, e.g., umbrellas, overhangs, etc., believing they offer protection from the erythemal solar radiation. The degree of sun protection offered by such devices is directly related to the composition of the solar global UVB radiation, i.e., its beam and diffuse fractions. The composition of the incident solar global UVB radiation can be determined by measuring the global UVB (using Solar Light Co. Inc., Model 501A UV-Biometer) and either of its components. The beam component of the UVB radiation was determined by measuring the normal incidence beam radiation using a prototype, tracking instrument consisting of a Solar Light Co. Inc. Model 501A UV-Biometer mounted on an Eppley Solar Tracker Model St-1. The horizontal beam component of the global UVB radiation was calculated from the measured normal incidence using a simple geometric correlation and the diffuse component is determined as the difference between global and horizontal beam radiations. Horizontal and vertical surfaces positioned under a horizontal overhang/sunshade or an umbrella are not fully protected from exposure to solar global UVB radiation. They can receive a significant fraction of the UVB radiation, depending on their location beneath the shading device, the umbrella radius and the albedo (reflectance) of the surrounding ground surface in the case of a vertical surface. Shading devices such as an umbrella or horizontal overhang/shade provide relief from the solar global radiation and do block the solar global UVB radiation to some extent; nevertheless, a significant fraction of the solar global UVB radiation does penetrate this supposedly 'protective or comfort zone'. As a result, it is imperative to either apply sunscreen or cover up the exposed body surfaces even when under such shading devices. © 2011 John Wiley & Sons A/S.

Sweat Rate Prediction Equations for Outdoor Exercise with Transient Solar Radiation

DTIC Science & Technology

2012-01-01

AD] 15 Interchangeable variables gSL W/m2 Global solar load Direct weather station data; pyranometer values 25 Direct measurement from weather station ...Fanger equations 2, 4, 13, Direct or weather station values Rdif W Diffuse irradiance Rref W Reflected irradiance AD m2 Body surface area (BSA) from DuBois...assuming the given weather station uses standard meteorological measuring instru- ments. In the heat flow form expressed by Matthew et al. (25

Development of Surfaces Optically Suitable for Flat Solar Panels

NASA Technical Reports Server (NTRS)

Desmet, D.; Jason, A.

1978-01-01

Three areas of research in the development of flat solar panels are described. (1) A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces was developed. The reflectometer has a phase locked detection system. (2) A coating composed of strongly bound copper oxide that is formed by an etching process performed on an aluminum alloy with high copper content was also developed. Because of this one step fabrication process, fabrication costs are expected to be small. (3) A literature search was conducted and conclusions on the required optical properties of flat plate solar collectors are presented.

Prediction of moisture and temperature changes in composites during atmospheric exposure

NASA Technical Reports Server (NTRS)

Tompkins, S. S.; Tenney, D. R.; Unnan, J.

1978-01-01

The effects of variations in diffusion coefficients, surface properties of the composite, panel tilt, ground reflection, and geographical location on the moisture concentration profiles and average moisture content of composite laminates were studied analytically. A heat balance which included heat input due to direct and sky diffuse solar radiation, ground reflection, and heat loss due to reradiation and convection was used to determine the temperature of composites during atmospheric exposure. The equilibrium moisture content was assumed proportional to the relative humidity of the air in the boundary layer of the composite. Condensation on the surface was neglected. Histograms of composite temperatures were determined and compared with those for the ambient environment.

Response Versus Scan-Angle Corrections for MODIS Reflective Solar Bands Using Deep Convective Clouds

NASA Technical Reports Server (NTRS)

Bhatt, Rajendra; Angal, Amit; Doelling, David R.; Xiong, Xiaoxiong; Wu, Aisheng; Haney, Conor O.; Scarino, Benjamin R.; Gopalan, Arun

2016-01-01

The absolute radiometric calibration of the reflective solar bands (RSBs) of Aqua- and Terra-MODIS is performed using on-board calibrators. A solar diffuser (SD) panel along with a solar diffuser stability monitor (SDSM) system, which tracks the performance of the SD over time, provides the absolute reference for calibrating the MODIS sensors. MODIS also views the moon and deep space through its space view (SV) port for lunar-based calibration and computing the zero input radiance, respectively. The MODIS instrument views the Earths surface through a two-sided scan mirror, whose reflectance is a function of angle of incidence (AOI) and is described by response versus scan-angle (RVS). The RVS for both MODIS instruments was characterized prior to launch. MODIS also views the SD and the moon at two different assigned RVS positions. There is sufficient evidence that the RVS is changing on orbit over time and as a function of wavelength. The SD and lunar observation scans can only track the RVS variation at two RVS positions. Consequently, the MODIS Characterization Support Team (MCST) developed enhanced approaches that supplement the onboard calibrator measurements with responses from pseudo-invariant desert sites. This approach has been implemented in Level 1B (L1B) Collection 6 (C6) for selected short-wavelength bands. This paper presents an alternative approach of characterizing the mirror RVS to derive the time-dependent RVS correction factors for MODIS RSBs using tropical deep convective cloud (DCC) targets. An initial assessment of the DCC response from Aqua-MODIS band 1 C6 data indicates evidence of RVS artifacts, which are not uniform across the scans and are more prevalent in the left side Earth-view scans.

Response Versus Scan-Angle Corrections for MODIS Reflective Solar Bands Using Deep Convective Clouds

NASA Technical Reports Server (NTRS)

Bhatt, Rajendra; Angal, Amit; Doelling, David R.; Xiong, Xiaoxiong; Wu, Aisheng; Haney, Conor O.; Scarino, Benjamin R.; Gopalan, Arun

2016-01-01

The absolute radiometric calibration of the reflective solar bands (RSBs) of Aqua- and Terra-MODIS is performed using on-board calibrators. A solar diffuser (SD) panel along with a solar diffuser stability monitor (SDSM) system, which tracks the performance of the SD over time, provides the absolute reference for calibrating the MODIS sensors. MODIS also views the moon and deep space through its space view (SV) port for lunar-based calibration and computing the zero input radiance, respectively. The MODIS instrument views the Earth's surface through a two-sided scan mirror, whose reflectance is a function of angle of incidence (AOI) and is described by response versus scan-angle (RVS). The RVS for both MODIS instruments was characterized prior to launch. MODIS also views the SD and the moon at two different assigned RVS positions. There is sufficient evidence that the RVS is changing on orbit over time and as a function of wavelength. The SD and lunar observation scans can only track the RVS variation at two RVS positions. Consequently, the MODIS Characterization Support Team (MCST) developed enhanced approaches that supplement the onboard calibrator measurements with responses from pseudo-invariant desert sites. This approach has been implemented in Level 1B (L1B) Collection 6 (C6) for selected short-wavelength bands. This paper presents an alternative approach of characterizing the mirror RVS to derive the time-dependent RVS correction factors for MODIS RSBs using tropical deep convective cloud (DCC) targets. An initial assessment of the DCC response from Aqua-MODIS band 1 C6 data indicates evidence of RVS artifacts, which are not uniform across the scans and are more prevalent in the left side Earth-view scans.

Response versus scan-angle corrections for MODIS reflective solar bands using deep convective clouds

NASA Astrophysics Data System (ADS)

Bhatt, Rajendra; Angal, Amit; Doelling, David R.; Xiong, Xiaoxiong; Wu, Aisheng; Haney, Conor O.; Scarino, Benjamin R.; Gopalan, Arun

2016-05-01

The absolute radiometric calibration of the reflective solar bands (RSBs) of Aqua- and Terra-MODIS is performed using on-board calibrators. A solar diffuser (SD) panel along with a solar diffuser stability monitor (SDSM) system, which tracks the degradation of the SD over time, provides the baseline for calibrating the MODIS sensors. MODIS also views the moon and deep space through its space view (SV) port for lunar-based calibration and computing the background, respectively. The MODIS instrument views the Earth's surface using a two-sided scan mirror, whose reflectance is a function of the angle of incidence (AOI) and is described by response versus scan-angle (RVS). The RVS for both MODIS instruments was characterized prior to launch. MODIS also views the SD and the moon at two different AOIs. There is sufficient evidence that the RVS is changing on orbit over time and as a function of wavelength. The SD and lunar observation scans can only track the RVS variation at two AOIs. Consequently, the MODIS Characterization Support Team (MCST) developed enhanced approaches that supplement the onboard calibrator measurements with responses from the pseudo-invariant desert sites. This approach has been implemented in Level 1B (L1B) Collection 6 (C6) for select short-wavelength bands. This paper presents an alternative approach of characterizing the mirror RVS to derive the time-dependent RVS correction factors for MODIS RSBs using tropical deep convective cloud (DCC) targets. An initial assessment of the DCC response from Aqua-MODIS band 1 C6 data indicates evidence of RVS artifacts, which are not uniform across the scans and are more prevalent at the beginning of the earth-view scan.

Effects of positive ion implantation into antireflection coating of silicon solar cells

NASA Technical Reports Server (NTRS)

Middleton, A. E.; Harpster, J. W.; Collis, W. J.; Kim, C. K.

1971-01-01

The state of technological development of Si solar cells for highest obtained efficiency and radiation resistance is summarized. The various theoretical analyses of Si solar cells are reviewed. It is shown that factors controlling blue response are carrier diffusion length, surface recombination, impurity concentration profile in surface region, high level of surface impurity concentration (degeneracy), reflection coefficient of oxide, and absorption coefficient of Si. The theory of ion implantation of charge into the oxide antireflection coating is developed and side effects are discussed. The experimental investigations were directed at determining whether the blue response of Si solar cells could be improved by phosphorus ion charges introduced into the oxide antireflection coating.

Rugate filter for light-trapping in solar cells.

PubMed

Fahr, Stephan; Ulbrich, Carolin; Kirchartz, Thomas; Rau, Uwe; Rockstuhl, Carsten; Lederer, Falk

2008-06-23

We suggest a design for a coating that could be applied on top of any solar cell having at least one diffusing surface. This coating acts as an angle and wavelength selective filter, which increases the average path length and absorptance at long wavelengths without altering the solar cell performance at short wavelengths. The filter design is based on a continuous variation of the refractive index in order to minimize undesired reflection losses. Numerical procedures are used to optimize the filter for a 10 microm thick monocrystalline silicon solar cell, which lifts the efficiency above the Auger limit for unconcentrated illumination. The feasibility to fabricate such filters is also discussed, considering a finite available refractive index range.

Diffusion into new markets: evolving customer segments in the solar photovoltaics market

NASA Astrophysics Data System (ADS)

Sigrin, Ben; Pless, Jacquelyn; Drury, Easan

2015-08-01

The US residential solar market is growing quickly, and as solar adoption diffuses into new populations, later adopters may differ significantly from earlier ones. Using a unique household-level survey dataset including 1234 adopters and 790 non-adopters from San Diego County, California, we explore differences in attitudinal and socio-economic factors for three groups: (i) adopters and non-adopters; (ii) early and more recent adopters; (iii) consumers adopting via buying or leasing. Our results suggest that adopters overall have higher incomes, are more educated, live in larger homes, and expect to stay in their homes for longer than their non-adopting peers. They also differ in their expectations of electricity retail rate changes and the impact solar could have on their home resale value. When examining differences between early and more recent adopters, we find that recent adopters are more representative of general homeowners and more politically moderate. They are also increasingly installing solar to protect against future electricity price increases and to lower electricity costs as opposed to adopting strictly for environmental reasons. Furthermore, more recent adopters differ significantly from earlier adopters in the situations that prompted them to adopt. The findings demonstrate how solar markets are evolving, reflecting changes in the underlying drivers of consumer adoption as well as innovative solar marketing strategies.

Bifacial aspects of industrial n-Pasha solar cells

NASA Astrophysics Data System (ADS)

Van Aken, Bas B.; Tool, Kees; Kossen, Eric J.; Carr, Anna J.; Janssen, Gaby J. M.; Newman, Bonna K.; Romijn, Ingrid G.

2017-08-01

Bifacial photovoltaic (PV) modules make optimal use of diffuse and ground-reflected light. The gain in energy yield depends on both the local climatic conditions and the PV system layout. These determine the additional irradiance on the rear of the PV panels. The rear response of the (laminated) solar cell(s) determines how much additional energy this rear irradiance generates. Based on our experiments and simulations, the main parameters that determine the bifaciality factor of solar cells with a front side junction are the rear metal coverage, the base resistivity and the diffusion profile on the rear. These will be evaluated and discussed in this paper. Front-junction solar cells with low base resistivity have a lower short circuit current when illuminated from the rear due to enhanced recombination in the BSF. Stencil printed rear metallization yields a higher bifaciality factor compared to screen printed by reducing the metal coverage and consumption and maintaining the front side efficiency. For our optimized 239 cm2 bifacial cell we estimate that the output with 20% contributed by the rear side is equivalent to that of a 24.4% efficient monofacial cell.

Polarimetric phenomenology in the reflective regime: a case study using polarized hyperspectral data

NASA Astrophysics Data System (ADS)

Gibney, Mark

2016-05-01

Understanding the phenomenology of polarimetric data is necessary if we want to obtain the maximum benefit when we exploit that data. To first order, polarimetric phenomenology is driven by two things; the target material type (specular or diffuse) and the illuminating source (point (sun) or extended (body emission)). Polarimetric phenomenology can then be broken into three basic categories; ([specular material/sun source], [diffuse/sun], [specular/body]) where we have assigned body emission to the IR passband where materials are generally specular. The task of interest determines the category of interest since the task determines the dominant target material and the illuminating source (eg detecting diffuse targets under trees in VNIR = [diffuse/sun] category). In this paper, a specific case study for the important [diffuse/sun] category will be presented. For the reflective regime (0.3 - 3.0um), the largest polarimetric signal is obtained when the sun illuminates a significant portion of the material BRDF lobe. This naturally points us to problems whose primary target materials are diffuse since the BRDF lobe for specular materials is tiny (low probability of acquiring on the BRDF lobe) and glinty (high probability of saturating the sensor when on lobe). In this case study, we investigated signatures of solar illuminated diffuse paints acquired by a polarimetric hyperspectral sensor. We will discuss the acquisition, reduction and exploitation of that data, and use it to illustrate the primary characteristics of reflective polarimetric phenomenology.

Design of a Three-Layer Antireflection Coating for High Efficiency Indium Phosphide Solar Cells Using a Chemical Oxide as First Layer

NASA Technical Reports Server (NTRS)

Moulot, Jacques; Faur, Mircea; Faur, Maria; Goradia, Chandra; Goradia, Manju; Bailey, Sheila

1995-01-01

It is well known that the behavior of III-V compound based solar cells is largely controlled by their surface, since the majority of light generated carriers (63% for GaAs and 79% for InP) are created within 0.2 microns of the illuminated surface of the cell. Consequently, the always observed high surface recombination velocity (SRV) on these cells is a serious limiting factor for their high efficiency performance, especially for those with the p-n junction made by either thermal diffusion or ion implantation. A good surface passivation layer, ideally, a grown oxide as opposed to a deposited one, will cause a significant reduction in the SRV without adding interface problems, thus improving the performance of III-V compound based solar cells. Another significant benefit to the overall performance of the solar cells can be achieved by a substantial reduction of their large surface optical reflection by the use of a well designed antireflection (AR) coating. In this paper, we demonstrate the effectiveness of using a chemically grown, thermally and chemically stable oxide, not only for surface passivation but also as an integral part of a 3- layer AR coating for thermally diffused p(+)n InP solar cells. A phosphorus-rich interfacial oxide, In(PO3)3, is grown at the surface of the p(+) emitter using an etchant based on HNO3, o-H3PO4 and H2O2. This oxide has the unique properties of passivating the surface as well as serving as a fairly efficient antireflective layer yielding a measured record high AM0, 25 C, open-circuit voltage of 890.3 mV on a thermally diffused InP(Cd,S) solar cell. Unlike conventional single layer AR coatings such as ZnS, Sb2O3, SiO or double layer AR coatings such as ZnS/MgF2 deposited by e-beam or resistive evaporation, this oxide preserves the stoichiometry of the InP surface. We show that it is possible to design a three-layer AR coating for a thermally diffused InP solar cell using the In(PO3)3 grown oxide as the first layer and Al2O3, MgF2 or ZnS, MgF2 as the second and third layers respectively, so as to yield an overall theoretical reflectance of less than 2%. Since chemical oxides are readily grown on III-V semiconductor materials, the technique of using the grown oxide layer to both passivate the surface as well as serve as the first of a multilayer AR coating, should work well for essentially all III-V compound-based solar cells.

Design of a three-layer antireflection coating for high efficiency indium phosphide solar cells using a chemical oxide as first layer

NASA Technical Reports Server (NTRS)

Moulot, Jacques; Faur, M.; Faur, M.; Goradia, C.; Goradia, M.; Bailey, S.

1995-01-01

It is well known that the behavior of III-V compound based solar cells is largely controlled by their surface, since the majority of light generated carriers (63% for GaAs and 79% for InP) are created within 0.2 mu m of the surface of the illuminated cell. Consequently, the always observed high surface recombination velocity (SRV) on these cells is a serious limiting factor for their high efficiency performance, especially for those with p-n junction made by either thermal diffusion or ion implantation. A good surface passivation layer, ideally a grown oxide as opposed to a deposited one, will cause a significant reduction in the SRV without adding interface problems, thus improving the performance of III-V compound based solar cells. Another significant benefit to the overall performance of the solar cells can be achieved by a substantial reduction of their large surface optical reflection by the use of a well designed antireflection (AR) coating. In this paper, we demonstrate the effectiveness of using a chemically grown thermally and chemically stable oxide, not only for surface passivation but also as an integral part of a 3-layer AR coating for thermally diffused p+n InP solar cells. A phosphorus-rich interfacial oxide, In(PO3)3, is grown at the surface of the p+ emitter using an etchant based on HNO3, o-H3PO4 and H2O2. This oxide has the unique properties of passivating the surface as well as serving as an efficient antireflective layer yielding a measured record high AMO open-circuit voltage of 890.3 mV on a thermally diffused InP(Cd,S) solar cell. Unlike conventional single layer AR coatings such as ZnS, Sb2O3, SiO or double layer AR coatings such as ZnS/MgF2 deposited by e-beam or resistive evaporation, this oxide preserves the stoichiometry of the InP surface. We show that it is possible to design a three-layer AR coating for a thermally diffused InP solar cell using the In(PO3)3 grown oxide as the first layer and Al2O3 and MgF2 as the second and third layers respectively, so as to yield an overall theoretical reflectance of less than 2%. Since chemical oxides are readily grown on III-V semiconductors materials, the technique of using the grown oxide layer to both passivate the surface as well as serve as the first of a multilayer AR coating should work well for all III-V compound-based solar cells.

Reduction of skylight reflection effects in the above-water measurement of diffuse marine reflectance: comment.

PubMed

Krotkov, N A; Vasilkov, A P

2000-03-20

Use of a vertical polarizer has been suggested to reduce the effects of surface reflection in the above-water measurements of marine reflectance. We suggest using a similar technique for airborne or spaceborne sensors when atmospheric scattering adds its own polarization signature to the upwelling radiance. Our own theoretical sensitivity study supports the recommendation of Fougnie et al. [Appl. Opt. 38, 3844 (1999)] (40-50 degrees vertical angle and azimuth angle near 135 degrees, polarizer parallel to the viewing plane) for above-water measurements. However, the optimal viewing directions (and the optimal orientation of the polarizer) change with altitude above the sea surface, solar angle, and atmospheric vertical optical structure. A polarization efficiency function is introduced, which shows the maximal possible polarization discrimination of the background radiation for an arbitrary altitude above the sea surface, viewing direction, and solar angle. Our comment is meant to encourage broader application of airborne and spaceborne polarization sensors in remote sensing of water and sea surface properties.

An optically transparent metasurface for broadband microwave antireflection

NASA Astrophysics Data System (ADS)

Zhao, Jie; Zhang, Cheng; Cheng, Qiang; Yang, Jin; Cui, Tie Jun

2018-02-01

Metamaterial absorbers and diffusers provide powerful routes to decrease the backward reflection significantly with advantages of ultrathin profile and customized bandwidth. Simultaneous control of the absorption and scattering behaviors of the metamaterials which helps to improve the suppression capabilities of backward reflection, however, still remains a challenge. Aiming at this goal, we propose a metasurface constituted by two kinds of elements in a pseudorandom arrangement. By the use of indium tin oxide with moderate sheet resistance in the meta-atoms, enhanced absorption of energy can be achieved in a broad spectrum when interacted with illuminated waves. In the meanwhile, electromagnetic diffusion will be invoked from the destructive interference among the elements, giving rise to significant reduction of specular reflection as a result. Excellent agreements are observed between simulation and experiment with pronounced reflection suppression from 6.8 GHz to 19.4 GHz. In addition, the optical transparence of the patterns and substrates makes the proposed metasurface a promising candidate for future applications like photovoltaic solar cells and electromagnetic shielding glasses.

Urban UV environment in a sub-tropical megacity - A measurement and modelling study

NASA Astrophysics Data System (ADS)

Wai, Ka-Ming; Yu, Peter K. N.; Chan, Pok-Man

The variations of solar total UV (UVA + UVB) exposure rates in a megacity featured with high-rise buildings during summer months were measured and relevant model predictions were evaluated. The maximum pedestrian-level total solar UV exposure rate was less than the un-obstructed exposure rate at any time, attributing to the prevailing reduction in the diffuse solar radiation due to the obstruction effects of distant buildings. Comparing with the measurements, our coupled model well captured the spatial and temporal variations of the reduction of UV exposure rates. By measurements, large reduction in the solar total UV exposure rate down to 12% of un-obstructed exposure rate due to the building obstruction effects was found, agreeing with our previous simulation results and results from an Australian megacity. On the other hand, building reflection from reflective curtain walls could reach 23% of the un-obstructed solar total UV exposure rate at the ground level. This implied improper building design creating additional harmful effects of solar UV radiation on the environment. The coupled model was also applied to predict the urban UV exposure rates during a tropical-cyclone induced aerosol episode. A well-evaluated urban solar UV model is an important tool for sustainable urban design.

Radiometric Calibration of the Earth Observing System's Imaging Sensors

NASA Technical Reports Server (NTRS)

Slater, Philip N. (Principal Investigator)

1997-01-01

The work on the grant was mainly directed towards developing new, accurate, redundant methods for the in-flight, absolute radiometric calibration of satellite multispectral imaging systems and refining the accuracy of methods already in use. Initially the work was in preparation for the calibration of MODIS and HIRIS (before the development of that sensor was canceled), with the realization it would be applicable to most imaging multi- or hyper-spectral sensors provided their spatial or spectral resolutions were not too coarse. The work on the grant involved three different ground-based, in-flight calibration methods reflectance-based radiance-based and diffuse-to-global irradiance ratio used with the reflectance-based method. This continuing research had the dual advantage of: (1) developing several independent methods to create the redundancy that is essential for the identification and hopefully the elimination of systematic errors; and (2) refining the measurement techniques and algorithms that can be used not only for improving calibration accuracy but also for the reverse process of retrieving ground reflectances from calibrated remote-sensing data. The grant also provided the support necessary for us to embark on other projects such as the ratioing radiometer approach to on-board calibration (this has been further developed by SBRS as the 'solar diffuser stability monitor' and is incorporated into the most important on-board calibration system for MODIS)- another example of the work, which was a spin-off from the grant funding, was a study of solar diffuser materials. Journal citations, titles and abstracts of publications authored by faculty, staff, and students are also attached.

Diffusion into new markets: Evolving customer segments in the solar photovoltaics market

DOE PAGES

Sigrin, Ben; Pless, Jacquelyn; Drury, Easan

2015-08-03

The US residential solar market is growing quickly, and as solar adoption diffuses into new populations, later adopters may differ significantly from earlier ones. Using a unique household-level survey dataset including 1234 adopters and 790 non-adopters from San Diego County, California, we explore differences in attitudinal and socio-economic factors for three groups: (i) adopters and non-adopters; (ii) early and more recent adopters; (iii) consumers adopting via buying or leasing. Our results suggest that adopters overall have higher incomes, are more educated, live in larger homes, and expect to stay in their homes for longer than their non-adopting peers. They alsomore » differ in their expectations of electricity retail rate changes and the impact solar could have on their home resale value. When examining differences between early and more recent adopters, we find that recent adopters are more representative of general homeowners and more politically moderate. They are also increasingly installing solar to protect against future electricity price increases and to lower electricity costs as opposed to adopting strictly for environmental reasons. Furthermore, more recent adopters differ significantly from earlier adopters in the situations that prompted them to adopt. Lastly, the findings demonstrate how solar markets are evolving, reflecting changes in the underlying drivers of consumer adoption as well as innovative solar marketing strategies.« less

Diffusion into new markets: Evolving customer segments in the solar photovoltaics market

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sigrin, Ben; Pless, Jacquelyn; Drury, Easan

The US residential solar market is growing quickly, and as solar adoption diffuses into new populations, later adopters may differ significantly from earlier ones. Using a unique household-level survey dataset including 1234 adopters and 790 non-adopters from San Diego County, California, we explore differences in attitudinal and socio-economic factors for three groups: (i) adopters and non-adopters; (ii) early and more recent adopters; (iii) consumers adopting via buying or leasing. Our results suggest that adopters overall have higher incomes, are more educated, live in larger homes, and expect to stay in their homes for longer than their non-adopting peers. They alsomore » differ in their expectations of electricity retail rate changes and the impact solar could have on their home resale value. When examining differences between early and more recent adopters, we find that recent adopters are more representative of general homeowners and more politically moderate. They are also increasingly installing solar to protect against future electricity price increases and to lower electricity costs as opposed to adopting strictly for environmental reasons. Furthermore, more recent adopters differ significantly from earlier adopters in the situations that prompted them to adopt. Lastly, the findings demonstrate how solar markets are evolving, reflecting changes in the underlying drivers of consumer adoption as well as innovative solar marketing strategies.« less

Establishing BRDF calibration capabilities through shortwave infrared

NASA Astrophysics Data System (ADS)

Georgiev, Georgi T.; Butler, James J.; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2017-09-01

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Distribution Functions (BRDFs) of the laboratory and flight diffusers used in their pre-flight and on-orbit calibrations. This paper advances that initial work and presents a comparison of spectral Bidirectional Reflectance Distribution Function (BRDF) and Directional Hemispherical Reflectance (DHR) of Spectralon*, a common material for laboratory and onorbit flight diffusers. A new measurement setup for BRDF measurements from 900 nm to 2500 nm located at NASA Goddard Space Flight Center (GSFC) is described. The GSFC setup employs an extended indium gallium arsenide detector, bandpass filters, and a supercontinuum light source. Comparisons of the GSFC BRDF measurements in the shortwave infrared (SWIR) with those made by the National Institute of Standards and Technology (NIST) Spectral Tri-function Automated Reference Reflectometer (STARR) are presented. The Spectralon sample used in this study was 2 inch diameter, 99% white pressed and sintered Polytetrafluoroethylene (PTFE) target. The NASA/NIST BRDF comparison measurements were made at an incident angle of 0° and viewing angle of 45° . Additional BRDF data not compared to NIST were measured at additional incident and viewing angle geometries and are not presented here. The total combined uncertainty for the measurement of BRDF in the SWIR range made by the GSFC scatterometer is less than 1% (k = 1). This study is in support of the calibration of the Radiation Budget Instrument (RBI) and Visible Infrared Imaging Radiometer Suit (VIIRS) instruments of the Joint Polar Satellite System (JPSS) and other current and future NASA remote sensing missions operating across the reflected solar wavelength region.

ESTABLISHING BRDF CALIBRATION CAPABILITIES THROUGH SHORTWAVE INFRARED.

PubMed

Georgiev, Georgi T; Butler, James J; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2017-01-01

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Distribution Functions (BRDFs) of the laboratory and flight diffusers used in their pre-flight and on-orbit calibrations. This paper advances that initial work and presents a comparison of spectral Bidirectional Reflectance Distribution Function (BRDF) and Directional Hemispherical Reflectance (DHR) of Spectralon, a common material for laboratory and on-orbit flight diffusers. A new measurement setup for BRDF measurements from 900 nm to 2500 nm located at NASA Goddard Space Flight Center (GSFC) is described. The GSFC setup employs an extended indium gallium arsenide detector, bandpass filters, and a supercontinuum light source. Comparisons of the GSFC BRDF measurements in the shortwave infrared (SWIR) with those made by the National Institute of Standards and Technology (NIST) Spectral Tri-function Automated Reference Reflectometer (STARR) are presented. The Spectralon sample used in this study was 2 inch diameter, 99% white pressed and sintered Polytetrafluoroethylene (PTFE) target. The NASA/NIST BRDF comparison measurements were made at an incident angle of 0° and viewing angle of 45°. Additional BRDF data not compared to NIST were measured at additional incident and viewing angle geometries and are not presented here. The total combined uncertainty for the measurement of BRDF in the SWIR range made by the GSFC scatterometer is less than 1% ( k = 1). This study is in support of the calibration of the Radiation Budget Instrument (RBI) and Visible Infrared Imaging Radiometer Suit (VIIRS) instruments of the Joint Polar Satellite System (JPSS) and other current and future NASA remote sensing missions operating across the reflected solar wavelength region.

Spectralon BRDF and DHR Measurements in Support of Satellite Instruments Operating Through Shortwave Infrared

NASA Technical Reports Server (NTRS)

Georgiev, Georgi T.; Butler, James J.; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2016-01-01

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Distribution Functions (BRDFs) of the laboratory and flight diffusers used in their pre-flight and on-orbit calibrations. This paper advances that initial work and presents a comparison of spectral Bidirectional Reflectance Distribution Function (BRDF) and Directional Hemispherical Reflectance (DHR) of Spectralon*, a common material for laboratory and onorbit flight diffusers. A new measurement setup for BRDF measurements from 900 nm to 2500 nm located at NASA Goddard Space Flight Center (GSFC) is described. The GSFC setup employs an extended indium gallium arsenide detector, bandpass filters, and a supercontinuum light source. Comparisons of the GSFC BRDF measurements in the ShortWave InfraRed (SWIR) with those made by the NIST Spectral Trifunction Automated Reference Reflectometer (STARR) are presented. The Spectralon sample used in this study was 2 inch diameter, 99% white pressed and sintered Polytetrafluoroethylene (PTFE) target. The NASA/NIST BRDF comparison measurements were made at an incident angle of 0 deg and viewing angle of 45 deg. Additional BRDF data not compared to NIST were measured at additional incident and viewing angle geometries and are not presented here The total combined uncertainty for the measurement of BRDF in the SWIR range made by the GSFC scatterometer is less than 1% (k=1). This study is in support of the calibration of the Joint Polar Satellite System (JPSS) Radiation Budget Instrument (RBI) and Visible Infrared Imaging Radiometer Suite (VIIRS) of and other current and future NASA remote sensing missions operating across the reflected solar wavelength region.

Product of the SNPP VIIRS SD Screen Transmittance and the SD BRDF (RSB) From Both Yaw Maneuver and Regular On-Orbit Data

NASA Technical Reports Server (NTRS)

Lei, Ning; Xiong, Xiaoxiong

2016-01-01

To assure data quality, the Earth-observing Visible Infrared Imaging Radiometer Suite (VIIRS) regularly performs on-orbit radiometric calibrations of its 22 spectral bands. The primary calibration radiance source for the reflective solar bands (RSBs) is a sunlit solar diffuser (SD). During the calibration process, sunlight goes through a perforated plate (the SD screen) and then strikes the SD. The SD scattered sunlight is used for the calibration, with the spectral radiance proportional to the product of the SD screen transmittance and the SD bidirectional reflectance distribution function (BRDF). The BRDF is decomposed to the product of its value at launch and a numerical factor quantifying its change since launch. Therefore, the RSB calibration requires accurate knowledge of the product of the SD screen transmittance and the BRDF (RSB; launch time). Previously, we calculated the product with yaw maneuver data and found that the product had improved accuracy over the prelaunch one. With both yaw maneuver and regular on orbit data, we were able to improve the accuracy of the SDSM screen transmittance and the product for the solar diffuser stability monitor SD view. In this study, we use both yaw maneuver and a small portion of regular on-orbit data to determine the product for the RSB SD view.

Analysis of VIIRS TEB noise using solar diffuser measurements

NASA Astrophysics Data System (ADS)

Choi, Taeyoung; Cao, Changyong; Weng, Fuzhong

2015-09-01

The Soumi-NPP Visible Infrared Imaging Radiometer Suite (VIIRS) was launched on October 28th, 2011 and its Sensor Data Record (SDR) product reached maturity status in March of 2014. Although the VIIRS SDR products are declared at the validated maturity level, there remain issues such as residual stripings in some thermal bands along with the scan direction. These horizontal striping issues in the Thermal Emissive Bands (TEB) were reflected in the sea surface temperature (SST) products. The observed striping magnitude can reach to 0.2 K, especially at the band M14 and M15. As an independent source of calibration, the Solar Diffuser (SD) is utilized in this study. The SD is originally designed for the Reflective Solar Band (RSB), however, it is assumed to be thermally stable at the time of SD observation. For each detector, a linear slope is developed by Integrated Calibration and Validation System (ICVS), which is applied on converting digital number (DN) to radiance unit. After the conversion, detector based noise analyses in VIIRS band M15 and M16 are performed on in-scan and scan-by-scan SD responses. Since SD radiance varies within an orbit, the noise calculation must be derived from the neighborhood Allan deviation. The noise derived Allan deviation shows that detector 1 and 2 in band M15 and detector 9 in band M16 have higher noise content compared to other detectors.

Theoretical and experimental research in space photovoltaics

NASA Technical Reports Server (NTRS)

Faur, Mircea; Faur, Maria

1995-01-01

Theoretical and experimental research is outlined for indium phosphide solar cells, other solar cells for space applications, fabrication and performance measurements of shallow homojunction InP solar cells for space applications, improved processing steps and InP material characterization with applications to fabrication of high efficiency radiation resistant InP solar cells and other opto-electronic InP devices, InP solar cells fabricated by thermal diffusion, experiment-based predicted high efficiency solar cells fabricated by closed-ampoule thermal diffusion, radiation resistance of diffused junction InP solar cells, chemical and electrochemical characterization and processing of InP diffused structures and solar cells, and progress in p(+)n InP diffused solar cells.

BRDF Calibration of Sintered PTFE in the SWIR

NASA Technical Reports Server (NTRS)

Georgiev, Georgi T.; Butler, James J.

2009-01-01

Satellite instruments operating in the reflective solar wavelength region often require accurate and precise determination of the Bidirectional Reflectance Distribution Function (BRDF) of laboratory-based diffusers used in their pre-flight calibrations and ground-based support of on-orbit remote sensing instruments. The Diffuser Calibration Facility at NASA's Goddard Space Flight Center is a secondary diffuser calibration standard after NEST for over two decades, providing numerous NASA projects with BRDF data in the UV, Visible and the NIR spectral regions. Currently the Diffuser Calibration Facility extended the covered spectral range from 900 nm up to 1.7 microns. The measurements were made using the existing scatterometer by replacing the Si photodiode based receiver with an InGaAs-based one. The BRDF data was recorded at normal incidence and scatter zenith angles from 10 to 60 deg. Tunable coherent light source was setup. Broadband light source application is under development. Gray-scale sintered PTFE samples were used at these first trials, illuminated with P and S polarized incident light. The results are discussed and compared to empirically generated BRDF data from simple model based on 8 deg directional/hemispherical measurements.

Optimization of a Deep Convective Cloud Technique in Evaluating the Long-Term Radiometric Stability of MODIS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Mu, Qiaozhen; Wu, Aisheng; Xiong, Xiaoxiong; Doelling, David R.; Angal, Amit; Chang, Tiejun; Bhatt, Rajendra

2017-01-01

MODIS reflective solar bands are calibrated on-orbit using a solar diffuser and near-monthly lunar observations. To monitor the performance and effectiveness of the on-orbit calibrations, pseudo-invariant targets such as deep convective clouds (DCCs), Libya-4, and Dome-C are used to track the long-term stability of MODIS Level 1B product. However, the current MODIS operational DCC technique (DCCT) simply uses the criteria set for the 0.65- m band. We optimize several critical DCCT parameters including the 11- micrometer IR-band Brightness Temperature (BT11) threshold for DCC identification, DCC core size and uniformity to help locate DCCs at convection centers, data collection time interval, and probability distribution function (PDF) bin increment for each channel. The mode reflectances corresponding to the PDF peaks are utilized as the DCC reflectances. Results show that the BT11 threshold and time interval are most critical for the Short Wave Infrared (SWIR) bands. The Bidirectional Reflectance Distribution Function model is most effective in reducing the DCC anisotropy for the visible channels. The uniformity filters and PDF bin size have minimal impacts on the visible channels and a larger impact on the SWIR bands. The newly optimized DCCT will be used for future evaluation of MODIS on-orbit calibration by MODIS Characterization Support Team.

Tracking Solar Energy Conersion Unit Adapted For Field Assembly

DOEpatents

Kaminar, Neil R.; Ross, III, James G.; Carrie, Peter J.

2000-02-01

A modular solar energy collector having elongated V-shaped side walls formed by a pair of coplanar panels for each side wall. The upper panels, occupying most of the wall area are diffusely reflective, but the lower panels are specularly reflective. A Fresnel lens, having a snap fit relation to the side walls focuses some light on the lower specularly reflective panels which direct light to the solar cells at the base of the V-shaped walls. A heat sink provides support for the two panels with two opposed, upwardly extending wings terminating in opposed linear clips located near the lengthwise seam of the coplanar panels, each clip holding two coplanar panels in parallel alignment. The clips not only provide support for the panels, but also transfer heat to the remainder of the heat sink. The clips are shaped so that edges of the panels engage each clip by a snap fit, outside of the clip in one embodiment and inside of the clip in another embodiment. End caps are also formed with structures which snap to the wall panels. Since all junctions of components snap together, the collector of the present invention is easily assembled without specialized tools. Using side walls which are only partly specularly reflective permits a large angle of acceptance, yet provides an economical wall design because the entire wall need not be specularly reflective.

Spectral properties of plant leaves pertaining to urban landscape design of broad-spectrum solar ultraviolet radiation reduction

NASA Astrophysics Data System (ADS)

Yoshimura, Haruka; Zhu, Hui; Wu, Yunying; Ma, Ruijun

2010-03-01

Human exposure to harmful ultraviolet (UV) radiation has important public health implications. Actual human exposure to solar UV radiation depends on ambient UV irradiance, and the latter is influenced by ground reflection. In urban areas with higher reflectivity, UV exposure occurs routinely. To discover the solar UV radiation regulation mechanism of vegetation, the spectral reflectance and transmittance of plant leaves were measured with a spectrophotometer. Typically, higher plants have low leaf reflectance (around 5%) and essentially zero transmittance throughout the UV region regardless of plant species and seasonal change. Accordingly, incident UV radiation decreases to 5% by being reflected and is reduced to zero by passing through a leaf. Therefore, stratified structures of vegetation are working as another terminator of UV rays, protecting whole terrestrial ecosystems, while vegetation at waterfronts contributes to protect aquatic ecosystems. It is possible to protect the human population from harmful UV radiation by urban landscape design of tree shade and the botanical environment. Even thin but uniformly distributed canopy is effective in attenuating UV radiation. To intercept diffuse radiation, UV screening by vertical structures such as hedges should be considered. Reflectivity of vegetation is around 2%, as foliage surfaces reduce incident UV radiation via reflection, while also eliminating it by transmittance. Accordingly, vegetation reduces incident UV radiation to around 2% by reflection. Vegetation influence on ambient UV radiation is broad-spectrum throughout the UV region. Only trees provide cool UV protective shade. Urban landscapes aimed at abating urban heat islands integrated with a reduction of human UV over-exposure would contribute to mitigation of climate change.

On-Orbit Calibration and Performance of Aqua MODIS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Xiong, Xiaoxiong; Sun, Junqiang; Xie, Xiaobo; Barnes, William; Salomonson, Vincent

2009-01-01

Aqua MODIS has successfully operated on-orbit for more than 6 years since its launch in May 2002, continuously making global observations and improving studies of changes in the Earth's climate and environment. 20 of the 36 MODIS spectral bands, covering wavelengths from 0.41 to 2.2 microns, are the reflective solar bands (RSB). They are calibrated on-orbit using an on-board solar diffuser (SD) and a solar diffuser stability monitor (SDSM). In addition, regularly scheduled lunar observations are made to track the RSB calibration stability. This paper presents Aqua MODIS RSB on-orbit calibration and characterization activities, methodologies, and performance. Included in this study are characterizations of detector signal-to-noise ratio (SNR), short-term stability, and long-term response change. Spectral wavelength dependent degradation of the SD bidirectional reflectance factor (BRF) and scan mirror reflectance, which also varies with angle of incidence (AOI), are examined. On-orbit results show that Aqua MODIS onboard calibrators have performed well, enabling accurate calibration coefficients to be derived and updated for the Level 1B (L1B) production and assuring high quality science data products to be continuously generated and distributed. Since launch, the short-term response, on a scan-by-scan basis, has remained extremely stable for most RSB detectors. With the exception of band 6, there have been no new RSB noisy or inoperable detectors. Like its predecessor, Terra MODIS, launched in December 1999, the Aqua MODIS visible (VIS) spectral bands have experienced relatively large changes, with an annual response decrease (mirror side 1) of 3.6% for band 8 at 0.412 microns, 2.3% for band 9 at 0.443 microns, 1.6% for band 3 at 0.469 microns, and 1.2% for band 10 at 0.488 microns. For other RSB bands with wavelengths greater than 0.5 microns, the annual response changes are typically less than 0.5%. In general, Aqua MODIS optics degradation is smaller than Terra MODIS and the mirror side differences are much smaller. Overall, Aqua MODIS RSB on-orbit performance is better than Terra MODIS.

On the Spectral Hardening at gsim300 keV in Solar Flares

NASA Astrophysics Data System (ADS)

Li, G.; Kong, X.; Zank, G.; Chen, Y.

2013-05-01

It has long been noted that the spectra of observed continuum emissions in many solar flares are consistent with double power laws with a hardening at energies gsim300 keV. It is now widely believed that at least in electron-dominated events, the hardening in the photon spectrum reflects an intrinsic hardening in the source electron spectrum. In this paper, we point out that a power-law spectrum of electrons with a hardening at high energies can be explained by the diffusive shock acceleration of electrons at a termination shock with a finite width. Our suggestion is based on an early analytical work by Drury et al., where the steady-state transport equation at a shock with a tanh profile was solved for a p-independent diffusion coefficient. Numerical simulations with a p-dependent diffusion coefficient show hardenings in the accelerated electron spectrum that are comparable with observations. One necessary condition for our proposed scenario to work is that high-energy electrons resonate with the inertial range of the MHD turbulence and low-energy electrons resonate with the dissipation range of the MHD turbulence at the acceleration site, and the spectrum of the dissipation range ~k -2.7. A ~k -2.7 dissipation range spectrum is consistent with recent solar wind observations.

A Solar Receiver-Reactor with Specularly Reflecting Walls for High-Temperature Thermoelectrochemical and Thermochemical Processes

DTIC Science & Technology

1987-10-27

on the radiosity concept1 2 - t and was simply and quickly formulated when we assumed that the power distribution across each surface was uniform. Our...power per unit area leaving A,, its radiosity B,, consists of two components. The direct emission is kIwT1 4 . The diffusely t reflected portion of the...leaving Am, the radiosity Ba, is the radiation power arriving at the aperture from the concentrator. It is given by B2 = P/A 2 = IAA4-/A 2 , (5) where

The contribution of the diffuse light component to the topographic effect on remotely sensed data

NASA Technical Reports Server (NTRS)

Justice, C.; Holben, B.

1980-01-01

The topographic effect is measured by the difference between the global radiance from inclined surfaces as a function of their orientation relative to the sensor position and light source. The short wave radiant energy incident on a surface is composed of direct sunlight, scattered skylight, and light reflected from surrounding terrain. The latter two components are commonly known as the diffuse component. The contribution of the diffuse light component to the topographic effect was examined and the significance of this diffuse component with respect to two direct radiance models was assessed. Diffuse and global spectral radiances were measured for a series of slopes and aspects of a uniform and surface in the red and photographic infrared parts of the spectrum, using a nadir pointing two channel handheld radiometer. The diffuse light was found to produce a topographic effect which varied from the topographic effect for direct light. The topographic effect caused by diffuse light was found to increase slightly with solar elevation and wavelength for the channels examined. The correlations between data derived from two simple direct radiance simulation models and the field data were not significantly affected when the diffuse component was removed from the radiances. Radiances from a 60 percent reflective surface, assuming no atmospheric path radiance, the diffuse light topographic effect contributed a maximum range of 3 pixel values in simulated LANDSAT data from all aspects with slopes up to 30 degrees.

On-Orbit Noise Characterization for MODIS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Xiong, X.; Xie, X.; Angal, A.

2008-01-01

Since launch, the Moderate Resolution Imaging Spectroradiometer (MODIS) has operated successfully on-board the NASA Earth Observing System (EOS) Terra and EOS Aqua spacecraft. MODIS is a passive cross-track scanning radiometer that makes observations in 36 spectral bands with spectral wavelengths from visible (VIS) to long-wave infrared. MODIS bands 1-19 and 26 are the reflective solar bands (RSB) with wavelengths from 0.41 to 2.2 micrometers. They are calibrated on-orbit using an on-board solar diffuser (SD) and a SD stability monitor (SDSM) system. For MODIS RSB, the level 1B calibration algorithm produces top of the atmosphere reflectance factors and radiances for every pixel of the Earth view. The sensor radiometric calibration accuracy, specified at each spectral band's typical scene radiance, is 2% for the RSB reflectance factors and 5% for the RSB radiances. Also specified at the typical scene radiance is the detector signal-to-noise ratio (SNR), a key sensor performance parameter that directly impacts its radiometric calibration accuracy and stability, as well as the image quality. This paper describes an on-orbit SNR characterization approach developed to evaluate and track MODIS RSB detector performance. In order to perform on-orbit SNR characterization, MODIS RSB detector responses to the solar illumination reflected from the SD panel must be corrected for factors due to variations of the solar angles and the SD bi-directional reflectance factor. This approach enables RSB SNR characterization to be performed at different response levels for each detector. On-orbit results show that both Terra and Aqua MODIS RSB detectors have performed well since launch. Except for a few noisy or inoperable detectors which were identified pre-launch, most RSB detectors continue to meet the SNR design requirements and are able to maintain satisfactory short-term stability. A comparison of on-orbit noise characterization results with results derived from pre-launch calibration and characterization are also provided.

On-Orbit Performance and Calibration Improvements For the Reflective Solar Bands of Terra and Aqua MODIS

NASA Technical Reports Server (NTRS)

Angal, Amit; Xiong, Xiaoxiong; Wu, Aisheng; Chen, Hongda; Geng, Xu; Link, Daniel; Li, Yonghong; Wald, Andrew; Brinkmann, Jake

2016-01-01

Moderate Resolution Imaging Spectroradiometer (MODIS) is the keystone instrument for NASAs EOS Terra and Aqua missions, designed to extend and improve heritage sensor measurements and data records of the land, oceans and atmosphere. The reflective solar bands (RSB) of MODIS covering wavelengths from 0.41 micrometers to 2.2 micrometers, are calibrated on-orbit using a solar diffuser (SD), with its on-orbit bi-directional reflectance factor (BRF) changes tracked using a solar diffuser stability monitor (SDSM). MODIS is a scanning radiometer using a two-sided paddle-wheel mirror to collect earth view (EV) data over a range of (+/-)55 deg. off instrument nadir. In addition to the solar calibration provided by the SD and SDSM system, lunar observations at nearly constant phase angles are regularly scheduled to monitor the RSB calibration stability. For both Terra and Aqua MODIS, the SD and lunar observations are used together to track the on-orbit changes of RSB response versus scan angle (RVS) as the SD and SV port are viewed at different angles of incidence (AOI) on the scan mirror. The MODIS Level 1B (L1B) Collection 6 (C6) algorithm incorporated several enhancements over its predecessor Collection 5 (C5) algorithm. A notable improvement was the use of the earth-view (EV) response trends from pseudo-invariant desert targets to characterize the on-orbit RVS for select RSB (Terra bands 1-4, 8, 9 and Aqua bands 8, 9) and the time, AOI, and wavelength-dependent uncertainty. The MODIS Characterization Support Team (MCST) has been maintaining and enhancing the C6 algorithm since its first update in November, 2011 for Aqua MODIS, and February, 2012 for Terra MODIS. Several calibration improvements have been incorporated that include extending the EV-based RVS approach to other RSB, additional correction for SD degradation at SWIR wavelengths, and alternative approaches for on-orbit RVS characterization. In addition to the on-orbit performance of the MODIS RSB, this paper also discusses in detail the recent calibration improvements implemented in the MODIS L1B C6.

Self-organized broadband light trapping in thin film amorphous silicon solar cells.

PubMed

Martella, C; Chiappe, D; Delli Veneri, P; Mercaldo, L V; Usatii, I; Buatier de Mongeot, F

2013-06-07

Nanostructured glass substrates endowed with high aspect ratio one-dimensional corrugations are prepared by defocused ion beam erosion through a self-organized gold (Au) stencil mask. The shielding action of the stencil mask is amplified by co-deposition of gold atoms during ion bombardment. The resulting glass nanostructures enable broadband anti-reflection functionality and at the same time ensure a high efficiency for diffuse light scattering (Haze). It is demonstrated that the patterned glass substrates exhibit a better photon harvesting than the flat glass substrate in p-i-n type thin film a-Si:H solar cells.

Graded bandgap perovskite solar cells.

PubMed

Ergen, Onur; Gilbert, S Matt; Pham, Thang; Turner, Sally J; Tan, Mark Tian Zhi; Worsley, Marcus A; Zettl, Alex

2017-05-01

Organic-inorganic halide perovskite materials have emerged as attractive alternatives to conventional solar cell building blocks. Their high light absorption coefficients and long diffusion lengths suggest high power conversion efficiencies, and indeed perovskite-based single bandgap and tandem solar cell designs have yielded impressive performances. One approach to further enhance solar spectrum utilization is the graded bandgap, but this has not been previously achieved for perovskites. In this study, we demonstrate graded bandgap perovskite solar cells with steady-state conversion efficiencies averaging 18.4%, with a best of 21.7%, all without reflective coatings. An analysis of the experimental data yields high fill factors of ∼75% and high short-circuit current densities up to 42.1 mA cm -2 . The cells are based on an architecture of two perovskite layers (CH 3 NH 3 SnI 3 and CH 3 NH 3 PbI 3-x Br x ), incorporating GaN, monolayer hexagonal boron nitride, and graphene aerogel.

Evaluation of Detector-to-Detector and Mirror Side Differences for Terra MODIS Reflective Solar Bands Using Simultaneous MISR Observations

NASA Technical Reports Server (NTRS)

Wu, Aisheng; Xiong, Xiaoxiong; Angal, A.; Barnes, W.

2011-01-01

The Moderate Resolution Imaging Spectroradiometer (MODIS) is one of the five Earth-observing instruments on-board the National Aeronautics and Space Administration (NASA) Earth-Observing System(EOS) Terra spacecraft, launched in December 1999. It has 36 spectral bands with wavelengths ranging from 0.41 to 14.4 mm and collects data at three nadir spatial resolutions: 0.25 km for 2 bands with 40 detectors each, 0.5 km for 5 bands with 20 detectors each and 1 km for the remaining 29 bands with 10 detectors each. MODIS bands are located on four separate focal plane assemblies (FPAs) according to their spectral wavelengths and aligned in the cross-track direction. Detectors of each spectral band are aligned in the along-track direction. MODIS makes observations using a two-sided paddle-wheel scan mirror. Its on-board calibrators (OBCs) for the reflective solar bands (RSBs) include a solar diffuser (SD), a solar diffuser stability monitor (SDSM) and a spectral-radiometric calibration assembly (SRCA). Calibration is performed for each band, detector, sub-sample (for sub-kilometer resolution bands) and mirror side. In this study, a ratio approach is applied to MODIS observed Earth scene reflectances to track the detector-to-detector and mirror side differences. Simultaneous observed reflectances from the Multi-angle Imaging Spectroradiometer (MISR), also onboard the Terra spacecraft, are used with MODIS observed reflectances in this ratio approach for four closely matched spectral bands. Results show that the detector-to-detector difference between two adjacent detectors within each spectral band is typically less than 0.2% and, depending on the wavelengths, the maximum difference among all detectors varies from 0.5% to 0.8%. The mirror side differences are found to be very small for all bands except for band 3 at 0.44 mm. This is the band with the shortest wavelength among the selected matching bands, showing a time-dependent increase for the mirror side difference. This study is part of the effort by the MODIS Characterization Support Team (MCST) in order to track the RSB on-orbit performance for MODIS collection 5 data products. To support MCST efforts for future data re-processing, this analysis will be extended to include more spectral bands and temporal coverage.

In-depth investigation of spin-on doped solar cells with thermally grown oxide passivation

NASA Astrophysics Data System (ADS)

Ahmad, Samir Mahmmod; Cheow, Siu Leong; Ludin, Norasikin A.; Sopian, K.; Zaidi, Saleem H.

Solar cell industrial manufacturing, based largely on proven semiconductor processing technologies supported by significant advancements in automation, has reached a plateau in terms of cost and efficiency. However, solar cell manufacturing cost (dollar/watt) is still substantially higher than fossil fuels. The route to lowering cost may not lie with continuing automation and economies of scale. Alternate fabrication processes with lower cost and environmental-sustainability coupled with self-reliance, simplicity, and affordability may lead to price compatibility with carbon-based fuels. In this paper, a custom-designed formulation of phosphoric acid has been investigated, for n-type doping in p-type substrates, as a function of concentration and drive-in temperature. For post-diffusion surface passivation and anti-reflection, thermally-grown oxide films in 50-150-nm thickness were grown. These fabrication methods facilitate process simplicity, reduced costs, and environmental sustainability by elimination of poisonous chemicals and toxic gases (POCl3, SiH4, NH3). Simultaneous fire-through contact formation process based on screen-printed front surface Ag and back surface through thermally grown oxide films was optimized as a function of the peak temperature in conveyor belt furnace. Highest efficiency solar cells fabricated exhibited efficiency of ∼13%. Analysis of results based on internal quantum efficiency and minority carried measurements reveals three contributing factors: high front surface recombination, low minority carrier lifetime, and higher reflection. Solar cell simulations based on PC1D showed that, with improved passivation, lower reflection, and high lifetimes, efficiency can be enhanced to match with commercially-produced PECVD SiN-coated solar cells.

ERTS-1 anomalous dark patches

NASA Technical Reports Server (NTRS)

Strong, A. E. (Principal Investigator)

1973-01-01

The author has identified the following significant results. Through combined use of imagery from ERTS-1 and NOAA-2 satellites was found that when the sun elevation exceeds 55 degrees, the ERTS-1 imagery is subject to considerable contamination by sunlight even though the actual specular point is nearly 300 nautical miles from nadir. Based on sea surface wave slope information, a wind speed of 10 knots will theoretically provide approximately 0.5 percent incident solar reflectance under observed ERTS multispectral scanner detectors. This reflectance nearly doubles under the influence of a 20 knot wind. The most pronounced effect occurs in areas of calm water where anomalous dark patches are observed. Calm water at distances from the specular point found in ERTS scenes will reflect no solar energy to the multispectral scanner, making these regions stand out as dark areas in all bands in an ocean scene otherwise comprosed by a general diffuse sunlight from rougher ocean surfaces. Anomalous dark patches in the outer parts of the glitter zones may explain the unusual appearance of some scenes.

ESTABLISHING BRDF CALIBRATION CAPABILITIES THROUGH SHORTWAVE INFRARED

PubMed Central

Georgiev, Georgi T.; Butler, James J.; Thome, Kurt; Cooksey, Catherine; Ding, Leibo

2017-01-01

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Distribution Functions (BRDFs) of the laboratory and flight diffusers used in their pre-flight and on-orbit calibrations. This paper advances that initial work and presents a comparison of spectral Bidirectional Reflectance Distribution Function (BRDF) and Directional Hemispherical Reflectance (DHR) of Spectralon*, a common material for laboratory and on-orbit flight diffusers. A new measurement setup for BRDF measurements from 900 nm to 2500 nm located at NASA Goddard Space Flight Center (GSFC) is described. The GSFC setup employs an extended indium gallium arsenide detector, bandpass filters, and a supercontinuum light source. Comparisons of the GSFC BRDF measurements in the shortwave infrared (SWIR) with those made by the National Institute of Standards and Technology (NIST) Spectral Tri-function Automated Reference Reflectometer (STARR) are presented. The Spectralon sample used in this study was 2 inch diameter, 99% white pressed and sintered Polytetrafluoroethylene (PTFE) target. The NASA/NIST BRDF comparison measurements were made at an incident angle of 0° and viewing angle of 45°. Additional BRDF data not compared to NIST were measured at additional incident and viewing angle geometries and are not presented here. The total combined uncertainty for the measurement of BRDF in the SWIR range made by the GSFC scatterometer is less than 1% (k = 1). This study is in support of the calibration of the Radiation Budget Instrument (RBI) and Visible Infrared Imaging Radiometer Suit (VIIRS) instruments of the Joint Polar Satellite System (JPSS) and other current and future NASA remote sensing missions operating across the reflected solar wavelength region. PMID:29167593

Influence of Diffused Solar Radiation on the Solar Concentrating System of a Plant Shoot Configuration

NASA Astrophysics Data System (ADS)

Obara, Shin'ya

Investigation of a plant shoot configuration is used to obtain valuable information concerning the received light system. Additionally, analysis results concerning a plant shoot configuration interaction with direct solar radiation were taken from a past study. However, in order to consider a plant shoot as a received sunlight system, it is necessary to understand the received light characteristics of both direct solar radiation and diffused solar radiation. Under a clear sky, the ratio of direct solar radiation to diffused solar radiation is large. However, under a clouded sky, the amount of diffused solar radiation becomes larger. Therefore, in this paper, we investigate the received light characteristics of a plant shoot configuration under the influence of diffused solar radiation. As a result, we clarify the relationship between the amount of diffused solar radiation and the amount of received light as a function of the characteristics of the plant shoot configuration. In order to obtain diffused solar radiation, it is necessary to correspond to the radiation of the multi-directions. In the analysis, the characteristic of the difference in arrangement of the top leaf and the other leaf was obtained. Therefore, in analysis, leaves other than the top were distributed in the wide range.

Study of CdTe/CdS solar cell at low power density for low-illumination applications

NASA Astrophysics Data System (ADS)

Devi, Nisha; Aziz, Anver; Datta, Shouvik

2016-05-01

In this paper, we numerically investigate CdTe/CdS PV cell properties using a simulation program Solar Cell Capacitance Simulator in 1D (SCAPS-1D). A simple structure of CdTe PV cell has been optimized to study the effect of temperature, absorber thickness and work function at very low incident power. Objective of this research paper is to build an efficient and cost effective solar cell for portable electronic devices such as portable computers and cell phones that work at low incident power because most of such devices work at diffused and reflected sunlight. In this report, we simulated a simple CdTe PV cell at very low incident power, which gives good efficiency.

Preliminary Assessment of Suomi-NPP VIIRS On-orbit Radiometric Performance

NASA Technical Reports Server (NTRS)

Oudrari, Hassan; DeLuccia, Frank; McIntire, Jeff; Moyer, David; Chiang, Vincent; Xiong, Xiao-xiong; Butler, James

2012-01-01

The Visible-Infrared Imaging Radiometer Suite (VIIRS) is a key instrument on-board the Suomi National Polar-orbiting Partnership (NPP) spacecraft that was launched on October 28th 2011. VIIRS was designed to provide moderate and imaging resolution of most of the globe twice daily. It is a wide-swath (3,040 km) cross-track scanning radiometer with spatial resolutions of 370.and 740 m at nadir for imaging and moderate bands, respectively. It has 22 spectral bands covering the spectrum between 0.412 11m and 12.01 11m, including 14 reflective solar bands (RSB), 7 thermal emissive bands (TEB), and 1 day-night band (ON B). VIIRS observations are used to generate 22 environmental data products (EORs). This paper will briefly describe NPP VIIRS calibration strategies performed by the independent government team, for the initial on-orbit Intensive Calibration and Validation (ICV) activities. In addition, this paper will provide an early assessment of the sensor on-orbit radiometric performance, such as the sensor signal to noise ratios (SNRs), dual gain transition verification, dynamic range and linearity, reflective bands calibration based on the solar diffuser (SO) and solar diffuser stability monitor (SOSM), and emissive bands calibration based on the on-board blackbody calibration (OBC). A comprehensive set of performance metrics generated during the pre-launch testing program will be compared to VIIRS on-orbit early performance, and a plan for future cal/val activities and performance enhancements will be presented.

Assessment of the biophysical characteristics of rangeland community using scatterometer and optical measurements

NASA Technical Reports Server (NTRS)

Kanemasu, E. T.; Asrar, Ghassem; Myneni, Ranga; Martin, Robert, Jr.; Burnett, R. Bruce

1987-01-01

Research activities for the following study areas are summarized: single scattering of parallel direct and axially symmetric diffuse solar radiation in vegetative canopies; the use of successive orders of scattering approximations (SOSA) for treating multiple scattering in a plant canopy; reflectance of a soybean canopy using the SOSA method; and C-band scatterometer measurements of the Konza tallgrass prairie.

The physical characteristics of the surface of the satellites and rings of giant planets

NASA Astrophysics Data System (ADS)

Vidmachenko, A. P.; Morozhenko, O. V.

2017-10-01

The book gives the main results of the study of the optical characteristics of the field diffusely reflected radiation and physical characteristics of the surface of the satellites of giant planets and their rings. The publication is intended for teachers of higher educational institutions, students - graduate students and professionals who specialize in experimental physics and astrophysics and solar system surfaces.

Calibration Challenges and Improvements for Terra and Aqua MODIS Level-1B Data Product Qualit

NASA Astrophysics Data System (ADS)

Xiong, X.; Angal, A.; Chen, H.; Geng, X.; Li, Y.; Link, D.; Salomonson, V.; Twedt, K.; Wang, Z.; Wilson, T.; Wu, A.

2017-12-01

Terra and Aqua MODIS instruments launched in 1999 and 2002, respectively, have provided the remote sensing community and users worldwide a series of high quality long-term data records. They have enabled a broad range of scientific studies of the Earth's system and changes in its key geophysical and environmental parameters. To date, both MODIS instruments continue to operate nominally with all on-board calibrators (OBC) functioning properly. MODIS reflective solar bands (RSB) are currently calibrated by a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system, coupled with regularly scheduled lunar observations and trending results from selected ground reference targets. The thermal emissive bands (TEB) calibration is performed using an on-board blackbody (BB) on a scan-by-scan basis. The sensor's spectral and spatial characteristics are periodically tracked by the on-board spectroradiometric calibration assembly (SRCA). On-orbit changes in sensor responses or performance characteristics, often in non-deterministic ways, underscore the need for dedicated calibration efforts to be made over the course of the sensor's entire mission. For MODIS instruments, this task has been undertaken by the MODIS Characterization Support Team (MCST). In this presentation, we provide an overview of MODIS instrument operation and calibration activities with a focus on recent challenging issues. We describe the efforts made and methodologies developed to address various challenging issues, including on-orbit characterization of sensor response versus scan angle (RVS) and polarization sensitives in the reflective solar spectral region, and electronic crosstalk impact on sensor calibration. Also discussed are the latest improvements made into the MODIS Level-1B data products as well as lessons that could benefit other instruments (e.g. VIIRS) for their on-orbit calibration and characterization.

Transport Imaging of Multi-Junction and CIGS Solar Cell Materials

DTIC Science & Technology

2011-12-01

solar cells start with the material charge transport parameters, namely the charge mobility, lifetime and diffusion length . It is the goal of...every solar cell manufacturer to maintain high carrier lifetime so as to realize long diffusion lengths . Long diffusion lengths ensure that the charges...Thus, being able to accurately determine the diffusion length of any solar cell material proves advantageous by providing insights

Helioseismic Constraints on New Solar Models from the MoSEC Code

NASA Technical Reports Server (NTRS)

Elliott, J. R.

1998-01-01

Evolutionary solar models are computed using a new stellar evolution code, MOSEC (Modular Stellar Evolution Code). This code has been designed with carefully controlled truncation errors in order to achieve a precision which reflects the increasingly accurate determination of solar interior structure by helioseismology. A series of models is constructed to investigate the effects of the choice of equation of state (OPAL or MHD-E, the latter being a version of the MHD equation of state recalculated by the author), the inclusion of helium and heavy-element settling and diffusion, and the inclusion of a simple model of mixing associated with the solar tachocline. The neutrino flux predictions are discussed, while the sound speed of the computed models is compared to that of the sun via the latest inversion of SOI-NMI p-mode frequency data. The comparison between models calculated with the OPAL and MHD-E equations of state is particularly interesting because the MHD-E equation of state includes relativistic effects for the electrons, whereas neither MHD nor OPAL do. This has a significant effect on the sound speed of the computed model, worsening the agreement with the solar sound speed. Using the OPAL equation of state and including the settling and diffusion of helium and heavy elements produces agreement in sound speed with the helioseismic results to within about +.-0.2%; the inclusion of mixing slightly improves the agreement.

NREL Solar Radiation Research Laboratory (SRRL): Baseline Measurement System (BMS); Golden, Colorado (Data)

DOE Data Explorer

Stoffel, T.; Andreas, A.

1981-07-15

The SRRL was established at the Solar Energy Research Institute (now NREL) in 1981 to provide continuous measurements of the solar resources, outdoor calibrations of pyranometers and pyrheliometers, and to characterize commercially available instrumentation. The SRRL is an outdoor laboratory located on South Table Mountain, a mesa providing excellent solar access throughout the year, overlooking Denver. Beginning with the basic measurements of global horizontal irradiance, direct normal irradiance and diffuse horizontal irradiance at 5-minute intervals, the SRRL Baseline Measurement System now produces more than 130 data elements at 1-min intervals that are available from the Measurement & Instrumentation Data Center Web site. Data sources include global horizontal, direct normal, diffuse horizontal (from shadowband and tracking disk), global on tilted surfaces, reflected solar irradiance, ultraviolet, infrared (upwelling and downwelling), photometric and spectral radiometers, sky imagery, and surface meteorological conditions (temperature, relative humidity, barometric pressure, precipitation, snow cover, wind speed and direction at multiple levels). Data quality control and assessment include daily instrument maintenance (M-F) with automated data quality control based on real-time examinations of redundant instrumentation and internal consistency checks using NREL's SERI-QC methodology. Operators are notified of equipment problems by automatic e-mail messages generated by the data acquisition and processing system. Radiometers are recalibrated at least annually with reference instruments traceable to the World Radiometric Reference (WRR).

Impulsive solar X-ray bursts. III - Polarization, directivity, and spectrum of the reflected and total bremsstrahlung radiation from a beam of electrons directed toward the photosphere

NASA Technical Reports Server (NTRS)

Langer, S. H.; Petrosian, V.

1977-01-01

The paper presents the spectrum, directivity, and state of polarization of the bremsstrahlung radiation expected from a beam of high-energy electrons spiraling along radial magnetic field lines toward the photosphere. A Monte Carlo method is then described for evaluation of the spectrum, directivity, and polarization of X-rays diffusely reflected from stellar photospheres. The accuracy of the technique is evaluated through comparison with analytic results. The calculated characteristics of the incident X-rays are used to evaluate the spectrum, directivity, and polarization of the reflected and total X-ray fluxes. The results are compared with observations.

Non-Lambertian effects on remote sensing of surface reflectance and vegetation index

NASA Technical Reports Server (NTRS)

Lee, T. Y.; Kaufman, Y. J.

1986-01-01

This paper discusses the effects of non-Lambertian reflection from a homogeneous surface on remote sensing of the surface reflectance and vegetation index from a satellite. Remote measurement of the surface characteristics is perturbed by atmospheric scattering of sun light. This scattering tends to smooth the angular dependence of non-Lambertian surface reflectances, an effect that is not present in the case of Lambertian surfaces. This effect is calculated to test the validity of a Lambertian assumption used in remote sensing. For the three types of vegetations considered in this study, the assumption of Lambertian surface can be used satisfactorily in the derivation of surface reflectance from remotely measured radiance for a view angle outside the backscattering region. Within the backscattering region, however, the use of the assumption can result in a considerable error in the derived surface reflectance. Accuracy also deteriorates with increasing solar zenith angle. The angular distribution of the surface reflectance derived from remote measurements is smoother than that at the surface. The effect of surface non-Lambertianity on remote sensing of vegetation index is very weak. Since the effect is similiar in the visible and near infrared part of the solar spectrum for the vegetations treated in this study, it is canceled in deriving the vegetation index. The effect of the diffuse skylight on surface reflectance measurements at ground level is also discussed.

Glass diffusion source for constraining BSF region of a solar cell

DOEpatents

Lesk, I.A.; Pryor, R.A.; Coleman, M.G.

1982-08-27

The present invention is directed to a method of fabricating a solar cell comprising simultaneous diffusion of the p and n dopant materials into the solar cell substrate. The simultaneous diffusion process is preceded by deposition of a capping layer impervious to doping by thermal diffusion processes.

Core-shell silicon nanowire solar cells

PubMed Central

Adachi, M. M.; Anantram, M. P.; Karim, K. S.

2013-01-01

Silicon nanowires can enhance broadband optical absorption and reduce radial carrier collection distances in solar cell devices. Arrays of disordered nanowires grown by vapor-liquid-solid method are attractive because they can be grown on low-cost substrates such as glass, and are large area compatible. Here, we experimentally demonstrate that an array of disordered silicon nanowires surrounded by a thin transparent conductive oxide has both low diffuse and specular reflection with total values as low as < 4% over a broad wavelength range of 400 nm < λ < 650 nm. These anti-reflective properties together with enhanced infrared absorption in the core-shell nanowire facilitates enhancement in external quantum efficiency using two different active shell materials: amorphous silicon and nanocrystalline silicon. As a result, the core-shell nanowire device exhibits a short-circuit current enhancement of 15% with an amorphous Si shell and 26% with a nanocrystalline Si shell compared to their corresponding planar devices. PMID:23529071

Initial On-Orbit Radiometric Calibration of the Suomi NPP VIIRS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Lei, Ning; Wang, Zhipeng; Fulbright, Jon; Lee, Shihyan; McIntire, Jeff; Chiang, Vincent; Xiong, Jack

2012-01-01

The on-orbit radiometric response calibration of the VISible/Near InfraRed (VISNIR) and the Short-Wave InfraRed (SWIR) bands of the Visible/Infrared Imager/Radiometer Suite (VIIRS) aboard the Suomi National Polar-orbiting Partnership (NPP) satellite is carried out through a Solar Diffuser (SD). The transmittance of the SD screen and the SD's Bidirectional Reflectance Distribution Function (BRDF) are measured before launch and tabulated, allowing the VIIRS sensor aperture spectral radiance to be accurately determined. The radiometric response of a detector is described by a quadratic polynomial of the detector?s digital number (dn). The coefficients were determined before launch. Once on orbit, the coefficients are assumed to change by a common factor: the F-factor. The radiance scattered from the SD allows the determination of the F-factor. In this Proceeding, we describe the methodology and the associated algorithms in the determination of the F-factors and discuss the results.

BiOBr microspheres for photocatalytic degradation of an anionic dye

NASA Astrophysics Data System (ADS)

Mera, Adriana C.; Váldes, Héctor; Jamett, Fabiola J.; Meléndrez, M. F.

2017-03-01

BiOBr microspheres were obtained using a solvothermal synthesis route in the presence of ethylene glycol and KBr at 145 °C, for 18 h. BiOBr microspheres were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), nitrogen adsorption-desorption isotherms analysis, diffuse reflectance spectroscopy (DRS), and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Additionally, the theoretical and experimental isoelectric points (IEP) of BiOBr nanostructured microspheres were determined, and pH's influence on the degradation of an anionic dye (methyl orange) under simulated solar radiation was analyzed. Results show that 97% of methyl orange is removed at pH 2 after 60 min of photocatalytic reaction. Finally, DRIFTS studies permit the proposal of a surface reaction mechanism of the photocatalytic oxidation of MO using BiOBr microspheres.

InAlAs photovoltaic cell design for high device efficiency

DOE PAGES

Smith, Brittany L.; Bittner, Zachary S.; Hellstroem, Staffan D.; ...

2017-04-17

This study presents a new design for a single-junction InAlAs solar cell, which reduces parasitic absorption losses from the low band-gap contact layer while maintaining a functional window layer by integrating a selective etch stop. The etch stop is then removed prior to depositing an anti-reflective coating. The final cell had a 17.9% efficiency under 1-sun AM1.5 with an anti-reflective coating. Minority carrier diffusion lengths were extracted from external quantum efficiency data using physics-based device simulation software yielding 170 nm in the n-type emitter and 4.6 um in the p-type base, which is more than four times the diffusion lengthmore » previously reported for a p-type InAlAs base. In conclusion, this report represents significant progress towards a high-performance InAlAs top cell for a triple-junction design lattice-matched to InP.« less

UV-Vis-NIR luminescence properties and energy transfer mechanism of LiSrPO4:Eu2+, Pr3+ suitable for solar spectral convertor.

PubMed

Chen, Yan; Wang, Jing; Liu, Chunmeng; Tang, Jinke; Kuang, Xiaojun; Wu, Mingmei; Su, Qiang

2013-02-11

An efficient near-infrared (NIR) phosphor LiSrPO(4):Eu(2+), Pr(3+) is synthesized by solid-state reaction and systematically investigated using x-ray diffraction, diffuse reflection spectrum, photoluminescence spectra at room temperature and 3 K, and the decay curves. The UV-Vis-NIR energy transfer mechanism is proposed based on these results. The results demonstrate Eu(2+) can be an efficient sensitizer for harvesting UV photon and greatly enhancing the NIR emission of Pr(3+) between 960 and 1060 nm through efficient energy feeding by allowed 4f-5d absorption of Eu(2+) with high oscillator strength. Eu(2+)/Pr(3+) may be an efficient donor-acceptor pair as solar spectral converter for Si solar cells.

Ratioing methods for in-flight response calibration of space-based spectro-radiometers, operating in the solar spectral region

NASA Astrophysics Data System (ADS)

Lobb, Dan

2017-11-01

One of the most significant problems for space-based spectro-radiometer systems, observing Earth from space in the solar spectral band (UV through short-wave IR), is in achievement of the required absolute radiometric accuracy. Classical methods, for example using one or more sun-illuminated diffusers as reflectance standards, do not generally provide methods for monitoring degradation of the in-flight reference after pre-flight characterisation. Ratioing methods have been proposed that provide monitoring of degradation of solar attenuators in flight, thus in principle allowing much higher confidence in absolute response calibration. Two example methods are described. It is shown that systems can be designed for relatively low size and without significant additions to the complexity of flight hardware.

Study of CdTe/CdS solar cell at low power density for low-illumination applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Devi, Nisha, E-mail: nishatanwer1989@gmail.com; Aziz, Anver, E-mail: aaziz@jmi.ac.in; Datta, Shouvik

In this paper, we numerically investigate CdTe/CdS PV cell properties using a simulation program Solar Cell Capacitance Simulator in 1D (SCAPS-1D). A simple structure of CdTe PV cell has been optimized to study the effect of temperature, absorber thickness and work function at very low incident power. Objective of this research paper is to build an efficient and cost effective solar cell for portable electronic devices such as portable computers and cell phones that work at low incident power because most of such devices work at diffused and reflected sunlight. In this report, we simulated a simple CdTe PV cellmore » at very low incident power, which gives good efficiency.« less

Alternative Method of On-Orbit Response-Versus-Scan-Angle Characterization for MODIS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Chen, Hongda; Xiong, Xiaoxiong; Angal, Amit; Geng, Xu; Wu, Aisheng

2016-01-01

The moderate resolution imaging spectroradiometer (MODIS) has 20 reflective solar bands (RSB), covering a spectral range from 0.41 to 2.2 microns, which are calibrated on-orbit using its onboard calibrators, which include a solar diffuser, a solar diffuser stability monitor, and a spectroradiometric calibration assembly. A space view (SV) port is used to provide a background reference and also facilitates near-monthly lunar observations through a spacecraft roll. In every scan, the Earth's surface, SV, and onboard calibrators are viewed via a two-sided scan mirror, the reflectance of which depends on the angle of incidence (AOI) as well as the wavelength of the incident light. Response-versus-scan-angle (RVS) is defined as a dependence function of the scan mirror's reflectance over AOI. An initial RVS for each RSB was measured prelaunch for both Terra and Aqua MODIS. Algorithms have been developed to track the on-orbit RVS variation using the measurements from the onboard calibrators, supplemented with the earth view (EV) trends from pseudoinvariant desert targets obtained at different AOI. Since the mission beginning, the MODIS characterization support team (MCST) has dedicated efforts in evaluating approaches of characterizing the on-orbit RVS. A majority of the approaches focused on fitting the data at each AOI over time and then deriving the relative change at different AOI. The current version of the on-orbit RVS algorithm, as implemented in the collection 6 (C6) level-1B (L1B), is also based on the above rationale. It utilizes the EV response trends from the pseudoinvariant Libyan desert targets to supplement the gain derived from the onboard calibrators. The primary limitation of this approach is the assumption of the temporal stability of these desert sites. Consequently, MCST developed an approach that derives the on-orbit RVS change using measurements from a single desert site, combined with the on-orbit lunar measurements. In addition, the EV and onboard responses are fit first as a function of AOI before fitting temporally in order to eliminate the dependence on the stability of the desert site. Comprehensive comparisons are performed with current C6 RVS results for both Terra and Aqua MODIS. Results demonstrate that this alternative method provides a supplemental means to monitor the on-orbit RVS for MODIS RSB.

Alternative method of on-orbit response-versus-scan-angle characterization for MODIS reflective solar bands

NASA Astrophysics Data System (ADS)

Chen, Hongda; Xiong, Xiaoxiong; Angal, Amit; Geng, Xu; Wu, Aisheng

2016-04-01

The moderate resolution imaging spectroradiometer (MODIS) has 20 reflective solar bands (RSB), covering a spectral range from 0.41 to 2.2 μm, which are calibrated on-orbit using its onboard calibrators, which include a solar diffuser, a solar diffuser stability monitor, and a spectroradiometric calibration assembly. A space view (SV) port is used to provide a background reference and also facilitates near-monthly lunar observations through a spacecraft roll. In every scan, the Earth's surface, SV, and onboard calibrators are viewed via a two-sided scan mirror, the reflectance of which depends on the angle of incidence (AOI) as well as the wavelength of the incident light. Response-versus-scan-angle (RVS) is defined as a dependence function of the scan mirror's reflectance over AOI. An initial RVS for each RSB was measured prelaunch for both Terra and Aqua MODIS. Algorithms have been developed to track the on-orbit RVS variation using the measurements from the onboard calibrators, supplemented with the earth view (EV) trends from pseudoinvariant desert targets obtained at different AOI. Since the mission beginning, the MODIS characterization support team (MCST) has dedicated efforts in evaluating approaches of characterizing the on-orbit RVS. A majority of the approaches focused on fitting the data at each AOI over time and then deriving the relative change at different AOI. The current version of the on-orbit RVS algorithm, as implemented in the collection 6 (C6) level-1B (L1B), is also based on the above rationale. It utilizes the EV response trends from the pseudoinvariant Libyan desert targets to supplement the gain derived from the onboard calibrators. The primary limitation of this approach is the assumption of the temporal stability of these desert sites. Consequently, MCST developed an approach that derives the on-orbit RVS change using measurements from a single desert site, combined with the on-orbit lunar measurements. In addition, the EV and onboard responses are fit first as a function of AOI before fitting temporally in order to eliminate the dependence on the stability of the desert site. Comprehensive comparisons are performed with current C6 RVS results for both Terra and Aqua MODIS. Results demonstrate that this alternative method provides a supplemental means to monitor the on-orbit RVS for MODIS RSB.

Biomimetic light-harvesting funnels for re-directioning of diffuse light.

PubMed

Pieper, Alexander; Hohgardt, Manuel; Willich, Maximilian; Gacek, Daniel Alexander; Hafi, Nour; Pfennig, Dominik; Albrecht, Andreas; Walla, Peter Jomo

2018-02-14

Efficient sunlight harvesting and re-directioning onto small areas has great potential for more widespread use of precious high-performance photovoltaics but so far intrinsic solar concentrator loss mechanisms outweighed the benefits. Here we present an antenna concept allowing high light absorption without high reabsorption or escape-cone losses. An excess of randomly oriented pigments collects light from any direction and funnels the energy to individual acceptors all having identical orientations and emitting ~90% of photons into angles suitable for total internal reflection waveguiding to desired energy converters (funneling diffuse-light re-directioning, FunDiLight). This is achieved using distinct molecules that align efficiently within stretched polymers together with others staying randomly orientated. Emission quantum efficiencies can be >80% and single-foil reabsorption <0.5%. Efficient donor-pool energy funneling, dipole re-orientation, and ~1.5-2 nm nearest donor-acceptor transfer occurs within hundreds to ~20 ps. Single-molecule 3D-polarization experiments confirm nearly parallel emitters. Stacked pigment selection may allow coverage of the entire solar spectrum.

Earth Reflected Solar Radiation Incident upon an Arbitrarily Oriented Spinning Flat Plate

NASA Technical Reports Server (NTRS)

Cunningham, Fred G.

1963-01-01

A general derivation is given for the earth reflected solar radiation input to a flat plate--a solar cell paddle, for example--which is spinning about an axis coincident with the axis of symmetry of the satellite to which it is affixed. The resulting equations are written for the general case so that arbitrary orientations of the spin axis with respect to the earth-satellite line and arbitrary orientations of the normal to the plate with respect to the spin axis can be treated. No attempt is made to perform the resulting integrations because of the complexity of the equations; nor is there any attempt to delineate the integration limits for the general case. However, the equations governing these limits are given. The appendixes contain: the results, in graphical form, of two representative examples; the general computer program for the calculation is given in Fortran notation; and the results of a calculation of the distribution of albedo energy on the proposed Echo II satellite. The value of the mean solar constant used is 1.395 times 10 (sup 4) ergs per centimeters-squared per second; the mean albedo of the earth is assumed to be 0.34; and the earth is assumed to be a diffuse reflector.

Correlation of total, diffuse, and direct solar radiation

NASA Technical Reports Server (NTRS)

Buyco, E. H.; Namkoong, D.

1977-01-01

Present requirements for realistic solar energy system evaluations necessitate a comprehensive body of solar-radition data. The data should include both diffuse and direct solar radiation as well as their total on an hourly (or shorter) basis. In general, however, only the total solar radiation values were recorded. This report presents a correlation that relates the diffuse component of an hourly total solar radiation value to the total radiation ratio of the maximum value attainable. The data used were taken at the Blue Hill Observatory in Milton, Massachusetts, for the period 1952. The relation - in the form of the data plots - can be used in situations in which only the hourly total radiation data are available but the diffuse component is desired.

Impact of MODIS SWIR Band Calibration Improvements on Level-3 Atmospheric Products

NASA Technical Reports Server (NTRS)

Wald, Andrew; Levy, Robert; Angal, Amit; Geng, Xu; Xiong, Jack; Hoffman, Kurt

2016-01-01

The spectral reflectance measured by the MODIS reflective solar bands (RSB) is used for retrieving many atmospheric science products. The accuracy of these products depends on the accuracy of the calibration of the RSB. To this end, the RSB of the MODIS instruments are primarily calibrated on-orbit using regular solar diffuser (SD) observations. For lambda < 0.94 microns the SDs on-orbit bi-directional reflectance factor (BRF) change is tracked using solar diffuser stability monitor (SDSM) observations. For lambda > 0.94 microns, the MODIS Characterization Support Team (MCST) developed, in MODIS Collection 6 (C6), a time-dependent correction using observations from pseudo-invariant earth-scene targets. This correction has been implemented in C6 for the Terra MODIS 1.24 micron band over the entire mission, and for the 1.375 micron band in the forward processing. As the instruments continue to operate beyond their design lifetime of six years, a similar correction is planned for other short-wave infrared (SWIR) bands as well. MODIS SWIR bands are used in deriving atmosphere products, including aerosol optical thickness, atmospheric total column water vapor, cloud fraction and cloud optical depth. The SD degradation correction in Terra bands 5 and 26 impact the spectral radiance and therefore the retrieval of these atmosphere products. Here, we describe the corrections to Bands 5 (1.24 microns) and 26 (1.375 microns), and produce three sets (B5, B26 correction on/on, on/off, and off/off) of Terra-MODIS Level 1B (calibrated radiance product) data. By comparing products derived from these corrected and uncorrected Terra MODIS Level 1B (L1B) calibrations, dozens of L3 atmosphere products are surveyed for changes caused by the corrections, and representative results are presented. Aerosol and water vapor products show only small local changes, while some cloud products can change locally by > 10%, which is a large change.

Long-term calibration monitoring of Spectralon diffusers BRDF in the air-ultraviolet.

PubMed

Georgiev, Georgi T; Butler, James J

2007-11-10

Long-term calibration monitoring of the bidirectional reflectance distribution function (BRDF) of Spectralon diffusers in the air-ultraviolet is presented. Four Spectralon diffusers were monitored in this study. Three of the diffusers, designated as H1, H2, and H3, were used in the prelaunch radiance calibration of the Solar Backscatter Ultraviolet/2 (SBUV/2) satellite instruments on National Oceanic and Atmospheric Administration (NOAA) 14 and 16. A fourth diffuser, designated as the 400 diffuser, was used in the prelaunch calibration of the Ozone Mapping and Profiler Suite (OMPS) instrument scheduled for initial flight in 2009 on the National Polar Orbiting Environmental Satellite System Preparatory Project. The BRDF data of this study were obtained between 1994 and 2005 using the scatterometer located in the National Aeronautics and Space Administration Goddard Space Flight Center Diffuser Calibration Laboratory. The diffusers were measured at 13 wavelengths between 230 and 425 nm at the incident and scatter angles used in the prelaunch calibrations of SBUV/2 and OMPS. Spectral features in the BRDF of Spectralon are also discussed. The comparison shows how the air-ultraviolet BRDF of these Spectralon samples changed over time under clean room deployment conditions.

MODIS. Volume 2: MODIS level 1 geolocation, characterization and calibration algorithm theoretical basis document, version 1

NASA Technical Reports Server (NTRS)

Barker, John L.; Harnden, Joann M. K.; Montgomery, Harry; Anuta, Paul; Kvaran, Geir; Knight, ED; Bryant, Tom; Mckay, AL; Smid, Jon; Knowles, Dan, Jr.

1994-01-01

The EOS Moderate Resolution Imaging Spectrometer (MODIS) is being developed by NASA for flight on the Earth Observing System (EOS) series of satellites, the first of which (EOS-AM-1) is scheduled for launch in 1998. This document describes the algorithms and their theoretical basis for the MODIS Level 1B characterization, calibration, and geolocation algorithms which must produce radiometrically, spectrally, and spatially calibrated data with sufficient accuracy so that Global change research programs can detect minute changes in biogeophysical parameters. The document first describes the geolocation algorithm which determines geodetic latitude, longitude, and elevation of each MODIS pixel and the determination of geometric parameters for each observation (satellite zenith angle, satellite azimuth, range to the satellite, solar zenith angle, and solar azimuth). Next, the utilization of the MODIS onboard calibration sources, which consist of the Spectroradiometric Calibration Assembly (SRCA), Solar Diffuser (SD), Solar Diffuser Stability Monitor (SDSM), and the Blackbody (BB), is treated. Characterization of these sources and integration of measurements into the calibration process is described. Finally, the use of external sources, including the Moon, instrumented sites on the Earth (called vicarious calibration), and unsupervised normalization sites having invariant reflectance and emissive properties is treated. Finally, algorithms for generating utility masks needed for scene-based calibration are discussed. Eight appendices are provided, covering instrument design and additional algorithm details.

Chemical instability leads to unusual chemical-potential-independent defect formation and diffusion in perovskite solar cell material CH 3 NH 3 PbI 3

DOE PAGES

Ming, Wenmei; Chen, Shiyou; East China Normal Univ.; ...

2016-10-13

Methylammonium (MA) lead triiodide (MAPbI 3) has recently emerged as a promising solar cell material. But, MAPbI3 is known to have chemical instability, i.e., MAPbI3 is prone to decomposition into MAI and PbI 2 even at moderate temperatures (e.g. 330 K). Here, we show that the chemical instability, as reflected by the calculated negligible enthalpy of formation of MAPbI 3 (with respect to MAI and PbI 2), has an unusual and important consequence for defect properties, i.e., defect formation energies in low-carrier-density MAPbI 3 are nearly independent of the chemical potentials of constituent elements and thus can be uniquely determined. This allows straightforward calculations of defect concentrations and the activation energy of ionic conductivity (the sum of the formation energy and the diffusion barrier of the charged mobile defect) in MAPbI 3. Furthermore, the calculated activation energy for ionic conductivity due to Vmore » $$+\\atop{1}$$ diffusion is in excellent agreement with the experimental values, which demonstrates unambiguously that V$$+\\atop{1}$$ is the dominant diffusing defect and is responsible for the observed ion migration and device polarization in MAPbI3 solar cells. The calculated low formation energy of a Frenkel pair (V$$+\\atop{1}$$ -I$$-\\atop{i}$$ and low diffusion barriers of V$$+\\atop{1}$$ and Image I$$-\\atop{i}$$ suggest that the iodine ion migration and the resulting device polarization may occur even in single-crystal devices and grain-boundary-passivated polycrystalline thin film devices (which were previously suggested to be free from ion-migration-induced device polarization), leading to device degradation. Moreover, the device polarization due to the Frenkel pair (which has a relatively low concentration) may take a long time to develop and thus may avoid the appearance of the current–voltage hysteresis at typical scan rates.« less

Electrophoretic deposited TiO 2 pigment-based back reflectors for thin film solar cells

DOE PAGES

Bills, Braden; Morris, Nathan; Dubey, Mukul; ...

2015-01-16

Highly reflective coatings with strong light scattering effect have many applications in optical components and optoelectronic devices. This paper reports titanium dioxide (TiO 2) pigment-based reflectors that have 2.5 times higher broadband diffuse reflection than commercially produced aluminum or silver based reflectors and result in efficiency enhancements of a single-junction amorphous Si solar cell. Electrophoretic deposition is used to produce pigment-based back reflectors with high pigment density, controllable film thickness and site-specific deposition. Electrical conductivity of the pigment-based back reflectors is improved by creating electrical vias throughout the pigment-based back reflector by making holes using an electrical discharge / dielectricmore » breakdown approach followed by a second electrophoretic deposition of conductive nanoparticles into the holes. While previous studies have demonstrated the use of pigment-based back reflectors, for example white paint, on glass superstrate configured thin film Si solar cells, this work presents a scheme for producing pigment-based reflectors on complex shape and flexible substrates. Finally, mechanical durability and scalability are demonstrated on a continuous electrophoretic deposition roll-to-roll system which has flexible metal substrate capability of 4 inch wide and 300 feet long.« less

Model of bidirectional reflectance distribution function for metallic materials

NASA Astrophysics Data System (ADS)

Wang, Kai; Zhu, Jing-Ping; Liu, Hong; Hou, Xun

2016-09-01

Based on the three-component assumption that the reflection is divided into specular reflection, directional diffuse reflection, and ideal diffuse reflection, a bidirectional reflectance distribution function (BRDF) model of metallic materials is presented. Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection, the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection. This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials. Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.

A Synthesis of VIIRS Solar and Lunar Calibrations

NASA Technical Reports Server (NTRS)

Eplee, Robert E.; Turpie, Kevin R.; Meister, Gerhard; Patt, Frederick S.; Fireman, Gwyn F.; Franz, Bryan A.; McClain, Charles R.

2013-01-01

The NASA VIIRS Ocean Science Team (VOST) has developed two independent calibrations of the SNPP VIIRS moderate resolution reflective solar bands using solar diffuser and lunar observations through June 2013. Fits to the solar calibration time series show mean residuals per band of 0.078-0.10%. There are apparent residual lunar libration correlations in the lunar calibration time series that are not accounted for by the ROLO photometric model of the Moon. Fits to the lunar time series that account for residual librations show mean residuals per band of 0.071-0.17%. Comparison of the solar and lunar time series shows that the relative differences in the two calibrations are 0.12-0.31%. Relative uncertainties in the VIIRS solar and lunar calibration time series are comparable to those achieved for SeaWiFS, Aqua MODIS, and Terra MODIS. Intercomparison of the VIIRS lunar time series with those from SeaWiFS, Aqua MODIS, and Terra MODIS shows that the scatter in the VIIRS lunar observations is consistent with that observed for the heritage instruments. Based on these analyses, the VOST has derived a calibration lookup table for VIIRS ocean color data based on fits to the solar calibration time series.

Surface photovoltage method extended to silicon solar cell junction

NASA Technical Reports Server (NTRS)

Wang, E. Y.; Baraona, C. R.; Brandhorst, H. W., Jr.

1974-01-01

The conventional surface photovoltage (SPV) method is extended to the measurement of the minority carrier diffusion length in diffused semiconductor junctions of the type used in a silicon solar cell. The minority carrier diffusion values obtained by the SPV method agree well with those obtained by the X-ray method. Agreement within experimental error is also obtained between the minority carrier diffusion lengths in solar cell diffusion junctions and in the same materials with n-regions removed by etching, when the SPV method was used in the measurements.

Modeling the influence of the BRDF characteristics of vegetation on the retrieval of solar-induced chlorophyll fluorescence under different illumination conditions

NASA Astrophysics Data System (ADS)

Liu, Xinjie; Liu, Liangyun

2017-04-01

The Fraunhofer Line Discrimination (FLD) principle is the main approach used for the retrieval of solar-induced chlorophyll fluorescence (SIF). The basic assumption of the FLD principle is that the apparent reflectance spectra without SIF in-filling are smooth in the region of the absorption bands. However, in fact, this assumption is not valid due to the so-called "direct radiation in-filling" effect caused by the non-linear contribution of direct and diffuse radiation at the oxygen absorption bands, which are widely used for ground-based SIF retrieval. In this study, we first analyzed the physical mechanism of the direct radiation in-filling effect on the oxygen absorption bands and found that the bias in the SIF retrieval caused by the direct radiation in-filling effect at the O2-A band was less than 20% based on the use of a simulated dataset. Secondly, we established a simple correction model of the direct radiation in-filling effect. We found that the direct radiation in-filling effect at the O2-A band was directly proportional to the difference between the reflectance of the direct and diffuse radiation, and that the coefficient of proportionality was well correlated with the diffuse-to-global radiation ratio in the form of a quadratic function. The coefficient of determination (R-squared) for this correlation was 0.97. Finally, the model was validated using both simulated and field datasets. The validation results show that the bias in the SIF retrieval caused by the direct radiation in-filling effect can be efficiently corrected using the model proposed in this paper. This study thus provides a possible approach to estimating and correcting for the direct radiation-infilling effect using prior knowledge of the BRDF characteristics of direct and diffuse radiation for specific targets.

Perturbations of a close-earth satellite due to sunlight diffusely reflected from the earth. I - Uniform albedo

NASA Technical Reports Server (NTRS)

Lautman, D. A.

1977-01-01

A semianalytic method has been developed to calculate the radiation-pressure perturbations of a close-earth satellite due to sunlight reflected from the earth. The assumptions made are that the satellite is spherically symmetric and that the solar radiation is reflected from the earth according to Lambert's Law with uniform albedo. By using expressions for the components of the radiation-pressure force due to Lochry, the expressions for the perturbations of the elements were developed into series in the true anomaly. The perturbations within a given revolution can be obtained analytically by integrating with respect to v while holding all slowly varying quantities constant. The long-range perturbations are then obtained by accumulating the net perturbations at the end of each revolution.

Suomi satellite brings to light a unique frontier of nighttime environmental sensing capabilities

PubMed Central

Miller, Steven D.; Mills, Stephen P.; Elvidge, Christopher D.; Lindsey, Daniel T.; Lee, Thomas F.; Hawkins, Jeffrey D.

2012-01-01

Most environmental satellite radiometers use solar reflectance information when it is available during the day but must resort at night to emission signals from infrared bands, which offer poor sensitivity to low-level clouds and surface features. A few sensors can take advantage of moonlight, but the inconsistent availability of the lunar source limits measurement utility. Here we show that the Day/Night Band (DNB) low-light visible sensor on the recently launched Suomi National Polar-orbiting Partnership (NPP) satellite has the unique ability to image cloud and surface features by way of reflected airglow, starlight, and zodiacal light illumination. Examples collected during new moon reveal not only meteorological and surface features, but also the direct emission of airglow structures in the mesosphere, including expansive regions of diffuse glow and wave patterns forced by tropospheric convection. The ability to leverage diffuse illumination sources for nocturnal environmental sensing applications extends the advantages of visible-light information to moonless nights. PMID:22984179

Suomi NPP VIIRS solar diffuser screen transmittance model and its applications.

PubMed

Lei, Ning; Xiong, Xiaoxiong; Mcintire, Jeff

2017-11-01

The visible infrared imaging radiometer suite on the Suomi National Polar-orbiting Partnership satellite calibrates its reflective solar bands through observations of a sunlit solar diffuser (SD) panel. Sunlight passes through a perforated plate, referred to as the SD screen, before reaching the SD. It is critical to know whether the SD screen transmittance measured prelaunch is accurate. Several factors such as misalignments of the SD panel and the measurement apparatus could lead to errors in the measured transmittance and thus adversely impact on-orbit calibration quality through the SD. We develop a mathematical model to describe the transmittance as a function of the angles that incident light makes with the SD screen, and apply the model to fit the prelaunch measured transmittance. The results reveal that the model does not reproduce the measured transmittance unless the size of the apertures in the SD screen is quite different from the design value. We attribute the difference to the orientation alignment errors for the SD panel and the measurement apparatus. We model the alignment errors and apply our transmittance model to fit the prelaunch transmittance to retrieve the "true" transmittance. To use this model correctly, we also examine the finite source size effect on the transmittance. Furthermore, we compare the product of the retrieved "true" transmittance and the prelaunch SD bidirectional reflectance distribution function (BRDF) value to the value derived from on-orbit data to determine whether the prelaunch SD BRDF value is relatively accurate. The model is significant in that it can evaluate whether the SD screen transmittance measured prelaunch is accurate and help retrieve the true transmittance from the transmittance with measurement errors, consequently resulting in a more accurate sensor data product by the same amount.

Assessment of MODIS On-Orbit Calibration Using a Deep Convective Cloud Technique

NASA Technical Reports Server (NTRS)

Mu, Qiaozhen; Wu, Aisheng; Chang, Tiejun; Angal, Amit; Link, Daniel; Xiong, Xiaoxiong; Doelling, David R.; Bhatt, Rajendra

2016-01-01

The MODerate Resolution Imaging Spectroradiometer (MODIS) sensors onboard Terra and Aqua satellites are calibrated on-orbit with a solar diffuser (SD) for the reflective solar bands (RSB). The MODIS sensors are operating beyond their designed lifetime and hence present a major challenge to maintain the calibration accuracy. The degradation of the onboard SD is tracked by a solar diffuser stability monitor (SDSM) over a wavelength range from 0.41 to 0.94 micrometers. Therefore, any degradation of the SD beyond 0.94 micrometers cannot be captured by the SDSM. The uncharacterized degradation at wavelengths beyond this limit could adversely affect the Level 1B (L1B) product. To reduce the calibration uncertainties caused by the SD degradation, invariant Earth-scene targets are used to monitor and calibrate the MODIS L1B product. The use of deep convective clouds (DCCs) is one such method and particularly significant for the short-wave infrared (SWIR) bands in assessing their long-term calibration stability. In this study, we use the DCC technique to assess the performance of the Terra and Aqua MODIS Collection-6 L1B for RSB 1 3- 7, and 26, with spectral coverage from 0.47 to 2.13 micrometers. Results show relatively stable trends in Terra and Aqua MODIS reflectance for most bands. Careful attention needs to be paid to Aqua band 1, Terra bands 3 and 26 as their trends are larger than 1% during the study time period. We check the feasibility of using the DCC technique to assess the stability in MODIS bands 17-19. The assessment test on response versus scan angle (RVS) calibration shows substantial trend difference for Aqua band 1between different angles of incidence (AOIs). The DCC technique can be used to improve the RVS calibration in the future.

Influence of the Solar Cycle on Turbulence Properties and Cosmic-Ray Diffusion

NASA Astrophysics Data System (ADS)

Zhao, L.-L.; Adhikari, L.; Zank, G. P.; Hu, Q.; Feng, X. S.

2018-04-01

The solar cycle dependence of various turbulence quantities and cosmic-ray (CR) diffusion coefficients is investigated by using OMNI 1 minute resolution data over 22 years. We employ Elsässer variables z ± to calculate the magnetic field turbulence energy and correlation lengths for both the inwardly and outwardly directed interplanetary magnetic field (IMF). We present the temporal evolution of both large-scale solar wind (SW) plasma variables and small-scale magnetic fluctuations. Based on these observed quantities, we study the influence of solar activity on CR parallel and perpendicular diffusion using quasi-linear theory and nonlinear guiding center theory, respectively. We also evaluate the radial evolution of the CR diffusion coefficients by using the boundary conditions for different solar activity levels. We find that in the ecliptic plane at 1 au (1), the large-scale SW temperature T, velocity V sw, Alfvén speed V A , and IMF magnitude B 0 are positively related to solar activity; (2) the fluctuating magnetic energy density < {{z}+/- }2> , residual energy E D , and corresponding correlation functions all have an obvious solar cycle dependence. The residual energy E D is always negative, which indicates that the energy in magnetic fluctuations is larger than the energy in kinetic fluctuations, especially at solar maximum; (3) the correlation length λ for magnetic fluctuations does not show significant solar cycle variation; (4) the temporally varying shear source of turbulence, which is most important in the inner heliosphere, depends on the solar cycle; (5) small-scale fluctuations may not depend on the direction of the background magnetic field; and (6) high levels of SW fluctuations will increase CR perpendicular diffusion and decrease CR parallel diffusion, but this trend can be masked if the background IMF changes in concert with turbulence in response to solar activity. These results provide quantitative inputs for both turbulence transport models and CR diffusion models, and also provide valuable insight into the long-term modulation of CRs in the heliosphere.

Parameter optimization for surface flux transport models

NASA Astrophysics Data System (ADS)

Whitbread, T.; Yeates, A. R.; Muñoz-Jaramillo, A.; Petrie, G. J. D.

2017-11-01

Accurate prediction of solar activity calls for precise calibration of solar cycle models. Consequently we aim to find optimal parameters for models which describe the physical processes on the solar surface, which in turn act as proxies for what occurs in the interior and provide source terms for coronal models. We use a genetic algorithm to optimize surface flux transport models using National Solar Observatory (NSO) magnetogram data for Solar Cycle 23. This is applied to both a 1D model that inserts new magnetic flux in the form of idealized bipolar magnetic regions, and also to a 2D model that assimilates specific shapes of real active regions. The genetic algorithm searches for parameter sets (meridional flow speed and profile, supergranular diffusivity, initial magnetic field, and radial decay time) that produce the best fit between observed and simulated butterfly diagrams, weighted by a latitude-dependent error structure which reflects uncertainty in observations. Due to the easily adaptable nature of the 2D model, the optimization process is repeated for Cycles 21, 22, and 24 in order to analyse cycle-to-cycle variation of the optimal solution. We find that the ranges and optimal solutions for the various regimes are in reasonable agreement with results from the literature, both theoretical and observational. The optimal meridional flow profiles for each regime are almost entirely within observational bounds determined by magnetic feature tracking, with the 2D model being able to accommodate the mean observed profile more successfully. Differences between models appear to be important in deciding values for the diffusive and decay terms. In like fashion, differences in the behaviours of different solar cycles lead to contrasts in parameters defining the meridional flow and initial field strength.

Hyperspectral Sun Photometer for Atmospheric Characterization and Vicarious Calibrations

NASA Technical Reports Server (NTRS)

Pagnutti, Mary; Ryan, Robert; Holekamp, Kara

2008-01-01

A hyperspectral sun photometer and associated methods have been developed and demonstrated. Accurate sun photometer calibration is critical to properly measure the solar irradiance and characterize the atmosphere. Traditional sun photometer calibration requires solar observations over several hours. In contrast, the procedures for operating this photometer entail less data acquisition time and embody a more direct approach to calibration. The scientific value of the measurement data produced by this instrument is not adversely affected by atmospheric instability. In addition, this instrument yields hyperspectral data covering a large spectral range (350-2,500 nm) not available from most traditional sun photometers. The hyperspectral sun photometer components include (1) a commercially available spectroradiometer that has been laboratory-calibrated and (2) a commercially available reflectance standard panel that exhibits nearly Lambertian 99% reflectance. The spectroradiometer is positioned above, and aimed downward at, the panel. The procedure for operating this instrument calls for a series of measurements: one in which the panel is fully illuminated by the sun, one in which a shade is positioned between the panel and the sun, and two in which the shade is positioned to cast a shadow to either side of the panel. The total sequence of measurements can be performed in less than a minute. From these measurements, the total radiance, the diffuse radiance, and the direct solar radiance are calculated. The direct solar irradiance is calculated from the direct solar radiance and the known reflectance factor of the panel as a function of the solar zenith angle. Atmospheric characteristics are estimated from the optical depth at various wavelengths calculated from (1) the direct solar irradiance obtained as described above, (2) the air mass along a column from the measurement position to the Sun, and (3) the top-of-atmosphere solar irradiance. The instrumentation used to implement the sun photometer is the same as that used to characterize targets used in radiometric vicarious calibrations. Utilizing this type of sun photometer thus reduces the amount of instrumentation and labor required to perform these studies.

Eco-friendly synthesis of TiO2, Au and Pt doped TiO2 nanoparticles for dye sensitized solar cell applications and evaluation of toxicity

NASA Astrophysics Data System (ADS)

Gopinath, K.; Kumaraguru, S.; Bhakyaraj, K.; Thirumal, S.; Arumugam, A.

2016-04-01

Driven by the demand of pure TiO2, Au and Pt doped TiO2 NPs were successfully synthesized using Terminalia arjuna bark extract. The eco-friendly synthesized NPs were characterized by UV-Vis-DRS, ATR-FT-IR, PL, XRD, Raman, SEM with EDX and TEM analysis. The synthesized NPs were investigation for dye sensitized solar cell applications. UV-Vis-Diffused Reflectance Spectra clearly showed that the expected TiO2 inter band absorption below 306 nm, incorporation of gold shows surface plasma resonant (SPR) near 555 nm and platinum incorporated TiO2 NPs shows absorbance at 460 nm. The energy conversion efficiency for Au doped TiO2 NPs when compared to pure and Pt doped TiO2 NPs. In addition to that, Au noble metal present TiO2 matrix and an improve open-circuit voltage (Voc) of DSSC. Synthesized NPs was evaluated into antibacterial and antifungal activities by disk diffusion method. It is observed that NPs have not shown any activities in all tested bacterial and fungal strains. In this eco-friendly synthesis method to provide non toxic and environmental friendly nanomaterials can be used for solar energy device application.

Calibration Improvements in the Detector-to-Detector Differences for the MODIS Ocean Color Bands

NASA Technical Reports Server (NTRS)

Li, Yonghong; Angal, Amit; Wu, Aisheng; Geng, Xu; Link, Daniel; Xiong, Xiaoxiong

2016-01-01

The Moderate Resolution Imaging Spectroradiometer (MODIS), a major instrument within NASAs Earth Observation System missions, has operated for over 16 and 14 years onboard the Terra and Aqua satellites, respectively. Its reflective solar bands (RSB) covering a spectral range from 0.4 to 2.1 micrometers are primarily calibrated using the on-board solar diffuser(SD), with its on-orbit degradation monitored using the Solar Diffuser Stability Monitor. RSB calibrations are supplemented by near-monthly lunar measurements acquired from the instruments space-view port. Nine bands (bands 8-16) in the visible to near infrared spectral range from 0.412 to 0.866 micrometers are primarily used for ocean color observations.During a recent reprocessing of ocean color products, performed by the NASA Ocean Biology Processing Group, detector-to-detector differences of up to 1.5% were observed in bands 13-16 of Terra MODIS. This paper provides an overview of the current approach to characterize the MODIS detector-to-detector differences. An alternative methodology was developed to mitigate the observed impacts for bands 13-16. The results indicated an improvement in the detector residuals and in turn are expected to improve the MODIS ocean color products. This paper also discusses the limitations,subsequent enhancements, and the improvements planned for future MODIS calibration collections.

A down-shifting Eu3+-doped Y2WO6/TiO2 photoelectrode for improved light harvesting in dye-sensitized solar cells

NASA Astrophysics Data System (ADS)

Llanos, J.; Brito, I.; Espinoza, D.; Sekar, Ramkumar; Manidurai, P.

2018-02-01

Y1.86Eu0.14WO6 phosphors were prepared using a solid-state reaction method. Their optical properties were analysed, and they was mixed with TiO2, sintered, and used as a photoelectrode (PE) in dye-sensitized solar cells (DSSCs). The as-prepared photoelectrode was characterized by photoluminescence spectroscopy, diffuse reflectance, electrochemical impedance spectroscopy (EIS) and X-ray diffraction. The photoelectric conversion efficiency of the DSSC with TiO2:Y1.86Eu0.14WO6 (100:2.5) was 25.8% higher than that of a DSCC using pure TiO2 as PE. This high efficiency is due to the ability of the luminescent material to convert ultraviolet radiation from the sun to visible radiation, thus improving the solar light harvesting of the DSSC.

An assessment of silver copper sulfides for photovoltaic applications: theoretical and experimental insights.

PubMed

Savory, Christopher N; Ganose, Alex M; Travis, Will; Atri, Ria S; Palgrave, Robert G; Scanlon, David O

2016-08-28

As the worldwide demand for energy increases, low-cost solar cells are being looked to as a solution for the future. To attain this, non-toxic earth-abundant materials are crucial, however cell efficiencies for current materials are limited in many cases. In this article, we examine the two silver copper sulfides AgCuS and Ag 3 CuS 2 as possible solar absorbers using hybrid density functional theory, diffuse reflectance spectroscopy, XPS and Hall effect measurements. We show that both compounds demonstrate promising electronic structures and band gaps for high theoretical efficiency solar cells, based on Shockley-Queisser limits. Detailed analysis of their optical properties, however, indicates that only AgCuS should be of interest for PV applications, with a high theoretical efficiency. From this, we also calculate the band alignment of AgCuS against various buffer layers to aid in future device construction.

Dot-Projection Photogrammetry and Videogrammetry of Gossamer Space Structures

NASA Technical Reports Server (NTRS)

Pappa, Richard S.; Black, Jonathan T.; Blandino, Joseph R.; Jones, Thomas W.; Danehy, Paul M.; Dorrington, Adrian A.

2003-01-01

This paper documents the technique of using hundreds or thousands of projected dots of light as targets for photogrammetry and videogrammetry of gossamer space structures. Photogrammetry calculates the three-dimensional coordinates of each target on the structure, and videogrammetry tracks the coordinates versus time. Gossamer structures characteristically contain large areas of delicate, thin-film membranes. Examples include solar sails, large antennas, inflatable solar arrays, solar power concentrators and transmitters, sun shields, and planetary balloons and habitats. Using projected-dot targets avoids the unwanted mass, stiffness, and installation costs of traditional retroreflective adhesive targets. Four laboratory applications are covered that demonstrate the practical effectiveness of white-light dot projection for both static-shape and dynamic measurement of reflective and diffuse surfaces, respectively. Comparisons are made between dot-projection videogrammetry and traditional laser vibrometry for membrane vibration measurements. The paper closes by introducing a promising extension of existing techniques using a novel laser-induced fluorescence approach.

Experimental determination of the reference plane of shaped diffusers by solar ultraviolet measurements.

PubMed

Gröbner, Julian; Blumthaler, Mario

2007-01-01

The optical reference plane of a J1002 shaped dome diffuser from CMS-Schreder was determined using direct normal spectral solar UV irradiance measurements relative to a flat Teflon diffuser. The spectroradiometers were calibrated relative to the same irradiance standard. The optical reference plane of the shaped J1002 diffuser is 5.3 mm behind the top of the dome with an uncertainty of 1.0 mm. Solar UV irradiance measurements based on a lamp calibration using the top of the dome as the reference will overestimate the global solar irradiance by 2.1% for the usual calibration distance of 500 mm.

Comparison of modeled and typical meteorological year. Diffuse, direct, and tilted solar radiation values with measured data in a cloudy climate: Seattle-Tacoma data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Straub, D.; Baylon, D.; Smith, O.

1980-01-01

Four commonly used solar radiation models that determine the diffuse and direct components of the solar radiation on a horizontal surface are compared against measured data to determine their predictive and modeling applicability. The John Hay model is determined to underpredict the diffuse and the Pereira/Rabl model to overpredict the diffuse radiation. The daily Liu and Jordan correlation and the hourly Boes correlation are shown to be better predictors.

Design of a three-layer antireflection coating for high efficiency indium phosphide solar cells using a chemical oxide as first layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moulot, J.; Faur, M.; Faur, M.

1995-10-01

It is well known that the behavior of III-V compound based solar cells is largely controlled by their surface, since the majority of light generated carriers (63% for GaAs and 79% for InP) are created within 0.2 mu m of the surface of the illuminated cell. Consequently, the always observed high surface recombination velocity (SRV) on these cells is a serious limiting factor for their high efficiency performance, especially for those with p-n junction made by either thermal diffusion or ion implantation. A good surface passivation layer, ideally a grown oxide as opposed to a deposited one, will cause amore » significant reduction in the SRV without adding interface problems, thus improving the performance of III-V compound based solar cells. Another significant benefit to the overall performance of the solar cells can be achieved by a substantial reduction of their large surface optical reflection by the use of a well designed antireflection (AR) coating. In this paper, the authors demonstrate the effectiveness of using a chemically grown thermally and chemically stable oxide, not only for surface passivation but also as an integral part of a 3-layer AR coating for thermally diffused p+n InP solar cells. A phosphorus-rich interfacial oxide, In(PO3)3, is grown at the surface of the p+ emitter using an etchant based on HNO3, o-H3PO4 and H2O2. This oxide has the unique properties of passivating the surface as well as serving as an efficient antireflective layer yielding a measured record high AMO open-circuit voltage of 890.3 mV on a thermally diffused InP(Cd,S) solar cell. Unlike conventional single layer AR coatings such as ZnS, Sb2O3, SiO or double layer AR coatings such as ZnS/MgF2 deposited by e-beam or resistive evaporation, this oxide preserves the stoichiometry of the InP surface.« less

A first order theory of the p/+/-n-n/+/ edge-illuminated silicon solar cell at very high injection levels

NASA Technical Reports Server (NTRS)

Goradia, C.; Sater, B. L.

1977-01-01

A first order theory of the edge-illuminated p(+)-n-n(+) silicon solar cell under very high injection levels has been derived. The very high injection level illuminated J-V characteristic is derived for any general base width to diffusion length (W/L) ratio and it includes the minority carrier reflection by the n-n(+) high-low junction. The beneficial effects of the high-low junction are shown to be significant until extremely high injection levels are reached. The theoretical dependencies of Jsc and Voc on temperature, incident intensity, and base resistivity are derived and discussed in detail. Some experimental results are given and these are discussed in relation to the theory.

Monolithically interconnected silicon-film™ module technology

NASA Astrophysics Data System (ADS)

DelleDonne, E. J.; Ford, D. H.; Hall, R. B.; Ingram, A. E.; Rand, J. A.; Barnett, A. M.

1999-03-01

AstroPower is developing an advanced thin-silicon-based, photovoltaic module product. A low-cost monolithic interconnected device is being integrated into a module that combines the design and process features of advanced light trapped, thin-silicon solar cells. This advanced product incorporates a low-cost substrate, a nominally 50-μm thick grown silicon layer with minority carrier diffusion lengths exceeding the active layer thickness, light trapping due to back-surface reflection, and back-surface passivation. The thin silicon layer enables high solar cell performance and can lead to a module conversion efficiency as high as 19%. These performance design features, combined with low-cost manufacturing using relatively low-cost capital equipment, continuous processing and a low-cost substrate, will lead to high-performance, low-cost photovoltaic panels.

Process research of non-CZ silicon material

NASA Technical Reports Server (NTRS)

1983-01-01

High risk, high payoff research areas associated with the Westinghouse process for producing photovoltaic modules using non- CZ sheet material were investigated. All work was performed using dendritic web silicon. The following tasks are discussed and associated technical results are given: (1) determining the technical feasibility of forming front and back junctions in non-CT silicon using dopant techniques; (2) determining the feasibility of forming a liquid applied diffusion mask to replace the more costly chemical vapor deposited SiO2 diffusion mask; (3) determining the feasibility of applying liquid anti-reflective solutions using meniscus coating equipment; (4) studying the production of uniform, high efficiency solar cells using ion implanation junction formation techniques; and (5) quantifying cost improvements associated with process improvements.

A Tracking Sun Photometer Without Moving Parts

NASA Technical Reports Server (NTRS)

Strawa, Anthony W.

2012-01-01

This innovation is small, lightweight, and consumes very little electricity as it measures the solar energy attenuated by gases and aerosol particles in the atmosphere. A Sun photometer is commonly used on the Earth's surface, as well as on aircraft, to determine the solar energy attenuated by aerosol particles in the atmosphere and their distribution of sizes. This information is used to determine the spatial and temporal distribution of gases and aerosols in the atmosphere, as well as their distribution sizes. The design for this Sun photometer uses a combination of unique optics and a charge coupled device (CCD) array to eliminate moving parts and make the instrument more reliable. It could be selfcalibrating throughout the year. Data products would be down-welling flux, the direct-diffuse flux ratio, column abundance of gas phase constituents, aerosol optical depth at multiple-wavelengths, phase functions, cloud statistics, and an estimate of the representative size of atmospheric particles. These measurements can be used to obtain an estimate of aerosol size distribution, refractive index, and particle shape. Incident light is received at a light-reflecting (inner) surface, which is a truncated paraboloid. Light arriving from a hemispheric field of view (solid angle 2 steradians) enters the reflecting optic at an entrance aperture at, or adjacent to, the focus of the paraboloid, and is captured by the optic. Most of this light is reflected from an inner surface. The light proceeds substantially parallel to the paraboloid axis, and is detected by an array detector located near an exit aperture. Each of the entrance and exit apertures is formed by the intersection of the paraboloid with a plane substantially perpendicular to the paraboloid axis. Incident (non-reflected) light from a source of limited extent (the Sun) illuminates a limited area on the detector array. Both direct and diffuse illumination may be reflected, or not reflected, before being received on the detector array. As the Sun traverses a path in the sky over some time interval, the track of the Sun can be traced on the detector array. A suitably modified Sun photometer might be used to study the dynamics of an environment on another planet or satellite with an atmosphere.

Soiling of building envelope surfaces and its effect on solar reflectance. Part I: Analysis of roofing product databases

DOE PAGES

Sleiman, Mohamad; Ban-Weiss, George; Gilbert, Haley E.; ...

2011-12-01

The use of highly reflective “cool” roofing materials can decrease demand for air conditioning, mitigate the urban heat island effect, and potentially slow global warming. However, initially high roof solar reflectance can be degraded by natural soiling and weathering processes. We evaluated solar reflectance losses after three years of natural exposure reported in two separate databases: the Rated Products Directory of the US Cool Roof Rating Council (CRRC) and information reported by manufacturers to the US Environmental Protection Agency (EPA)’s ENERGY STAR® rating program. Many product ratings were culled because they were duplicative (within a database) or not measured. Amore » second, site-resolved version of the CRRC dataset was created by transcribing from paper records the site-specific measurements of aged solar reflectance in Florida, Arizona and Ohio. Products with high initial solar reflectance tended to lose reflectance, while those with very low initial solar reflectance tended to become more reflective as they aged. Within the site-resolved CRRC database, absolute solar reflectance losses for samples of medium-to-high initial solar reflectance were 2 - 3 times greater in Florida (hot and humid) than in Arizona (hot and dry); losses in Ohio (temperate but polluted) were intermediate. Disaggregating results by product type, factory-applied coating, field-applied coating, metal, modified bitumen, shingle, singleply membrane and tile, revealed that absolute solar reflectance losses were largest for fieldapplied coating, modified bitumen and single-ply membrane products, and smallest for factoryapplied coating and metal products.The 2008 Title 24 provisional aged solar reflectance formula overpredicts the measured aged solar reflectance of 0% to 30% of each product type in the culled public CRRC database. The rate of overprediction was greatest for field-applied coating and single-ply membrane products and least for factory-applied coating, shingle, and metal products. New product-specific formulas can be used to estimate provisional aged solar reflectance from initial solar reflectance pending measurement of aged solar reflectance. The appropriate value of soiling resistance varies by product type and is selected to attain some desired overprediction rate for the formula. The correlations for shingle products presented in this paper should not be used to predict aged solar reflectance or estimate provisional aged solar reflectance because the data set is too small and too limited in range of initial solar reflectance.« less

The solar vector error within the SNPP Common GEO code, the correction, and the effects on the VIIRS SDR RSB calibration

NASA Astrophysics Data System (ADS)

Fulbright, Jon; Anderson, Samuel; Lei, Ning; Efremova, Boryana; Wang, Zhipeng; McIntire, Jeffrey; Chiang, Kwofu; Xiong, Xiaoxiong

2014-11-01

Due to a software error, the solar and lunar vectors reported in the on-board calibrator intermediate product (OBC-IP) files for SNPP VIIRS are incorrect. The magnitude of the error is about 0.2 degree, and the magnitude is increasing by about 0.01 degree per year. This error, although small, has an effect on the radiometric calibration of the reflective solar bands (RSB) because accurate solar angles are required for calculating the screen transmission functions and for calculating the illumination of the Solar Diffuser panel. In this paper, we describe the error in the Common GEO code, and how it may be fixed. We present evidence for the error from within the OBC-IP data. We also describe the effects of the solar vector error on the RSB calibration and the Sensor Data Record (SDR). In order to perform this evaluation, we have reanalyzed the yaw-maneuver data to compute the vignetting functions required for the on-orbit SD RSB radiometric calibration. After the reanalysis, we find effect of up to 0.5% on the shortwave infrared (SWIR) RSB calibration.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Huafeng; Colabello, Diane M.; Sklute, Elizabeth C.

The absolute absorption coefficient, α(E), is a critical design parameter for devices using semiconductors for light harvesting associated with renewable energy production, both for classic technologies such as photovoltaics and for emerging technologies such as direct solar fuel production. While α(E) is well-known for many classic simple semiconductors used in photovoltaic applications, the absolute values of α(E) are typically unknown for the complex semiconductors being explored for solar fuel production due to the absence of single crystals or crystalline epitaxial films that are needed for conventional methods of determining α(E). In this work, a simple self-referenced method for estimating bothmore » the refractive indices, n(E), and absolute absorption coefficients, α(E), for loose powder samples using diffuse reflectance data is demonstrated. In this method, the sample refractive index can be deduced by refining n to maximize the agreement between the relative absorption spectrum calculated from bidirectional reflectance data (calculated through a Hapke transform which depends on n) and integrating sphere diffuse reflectance data (calculated through a Kubleka–Munk transform which does not depend on n). This new method can be quickly used to screen the suitability of emerging semiconductor systems for light-harvesting applications. The effectiveness of this approach is tested using the simple classic semiconductors Ge and Fe 2O 3 as well as the complex semiconductors La 2MoO 5 and La 4Mo 2O 11. The method is shown to work well for powders with a narrow size distribution (exemplified by Fe 2O 3) and to be ineffective for semiconductors with a broad size distribution (exemplified by Ge). As such, it provides a means for rapidly estimating the absolute optical properties of complex solids which are only available as loose powders.« less

The color of the Martian sky and its influence on the illumination of the Martian surface

USGS Publications Warehouse

Thomas, N.; Markiewicz, W.J.; Sablotny, R.M.; Wuttke, M.W.; Keller, H.U.; Johnson, J. R.; Reid, R.J.; Smith, R.H.

1999-01-01

The dust in the atmosphere above the Mars Pathfinder landing site produced a bright, red sky that increases in redness toward the horizon at midday. There is also evidence for an absorption band in the scattered light from the sky at 860 nm. A model of the sky brightness has been developed [Markiewicz et al., this issue] and tested against Imager for Mars Pathfinder (IMP) observations of calibration targets on the lander. The resulting model has been used to quantify the total diffuse flux onto a surface parallel to the local level for several solar elevation angles and optical depths. The model shows that the diffuse illumination in shadowed areas is strongly reddened while areas illuminated directly by the Sun (and the blue forward scattering peak) see a more solar-type spectrum, in agreement with Viking and IMP observations. Quantitative corrections for the reddening in shadowed areas are demonstrated. It is shown quantitatively that the unusual appearance of the rock Yogi (the east face of which appeared relatively blue in images taken during the morning but relatively red during the afternoon) can be explained purely by the changing illumination geometry. We conclude that any spectrophotometric analysis of surfaces on Mars must take into account the diffuse flux. Specifically, the reflectances of surfaces viewed under different illumination geometries cannot be investigated for spectral diversity unless a correction has been applied which removes the influence of the reddened diffuse flux. Copyright 1999 by the American Geophysical Union.

Investigation of back surface fields effect on bifacial solar cells

NASA Astrophysics Data System (ADS)

Sepeai, Suhaila; Sulaiman, M. Y.; Sopian, Kamaruzzaman; Zaidi, Saleem H.

2012-11-01

A bifacial solar cell, in contrast with a conventional monofacial solar cell, produces photo-generated current from both front and back sides. Bifacial solar cell is an attractive candidate for enhancing photovoltaic (PV) market competitiveness as well as supporting the current efforts to increase efficiency and lower material costs. This paper reports on the fabrication of bifacial solar cells using phosphorus-oxytrichloride (POCl3) emitter formation on p-type, nanotextured silicon (Si) wafer. Backside surface field was formed through Al-diffusion using conventional screen-printing process. Bifacial solar cells with a structure of n+pp+ with and without back surface field (BSF) were fabricated in which silicon nitride (SiN) anti reflection and passivation films were coated on both sides, followed by screen printing of Argentum (Ag) and Argentum/Aluminum (Ag/Al) on front and back contacts, respectively. Bifacial solar cells without BSF exhibited open circuit voltage (VOC) of 535 mV for front and 480 mV for back surface. With Al-alloyed BSF bifacial solar cells, the VOC improved to 580 mV for the front surface and 560 mV for the back surface. Simulation of bifacial solar cells using PC1D and AFORS software demonstrated good agreement with experimental results. Simulations showed that best bifacial solar cells are achieved through a combination of high lifetime wafer, low recombination back surface field, reduced contact resistance, and superior surface passivation.

Material Science for High-Efficiency Photovoltaics: From Advanced Optical Coatings to Cell Design for High-Temperature Applications

NASA Astrophysics Data System (ADS)

Perl, Emmett Edward

Solar cells based on III-V compound semiconductors are ideally suited to convert solar energy into electricity. The highest efficiency single-junction solar cells are made of gallium arsenide, and have attained an efficiency of 28.8%. Multiple III-V materials can be combined to construct multijunction solar cells, which have reached record efficiencies greater than 45% under concentration. III-V solar cells are also well suited to operate efficiently at elevated temperatures, due in large part to their high material quality. These properties make III-V solar cells an excellent choice for use in concentrator systems. Concentrator photovoltaic systems have attained module efficiencies that exceed 40%, and have the potential to reach the lowest levelized cost of electricity in sunny places like the desert southwest. Hybrid photovoltaic-thermal solar energy systems can utilize high-temperature III-V solar cells to simultaneously achieve dispatchability and a high sunlight-to-electricity efficiency. This dissertation explores material science to advance the state of III-V multijunction solar cells for use in concentrator photovoltaic and hybrid photovoltaic-thermal solar energy systems. The first half of this dissertation describes work on advanced optical designs to improve the efficiency of multijunction solar cells. As multijunction solar cells move to configurations with four or more subcells, they utilize a larger portion of the solar spectrum. Broadband antireflection coatings are essential to realizing efficiency gains for these state-of-the-art cells. A hybrid design consisting of antireflective nanostructures placed on top of multilayer interference-based optical coatings is developed. Antireflection coatings that utilize this hybrid approach yield unparalleled performance, minimizing reflection losses to just 0.2% on sapphire and 0.6% on gallium nitride for 300-1800nm light. Dichroic mirrors are developed for bonded 5-junction solar cells that utilize InGaN as a top junction. These designs maximize reflection of high-energy light for an InGaN top junction while minimizing reflection of low-energy light that would be absorbed by the lower four junctions. Increasing the reflectivity of high-energy photons enables a second pass of light through the InGaN cell, leading to increased absorption and a higher photocurrent. These optical designs enhanced the efficiency of a 2.65eV InGaN solar cell to a value of 3.3% under the AM0 spectrum, the highest reported efficiency for a standalone InGaN solar cell. The second half of the dissertation describes the development of III-V solar cells for high-temperature applications. As the operating temperature of a solar cell is increased, the ideal bandgap of the top junction increases. AlGaInP solar cells with bandgaps ranging from 1.9eV to 2.2eV are developed. A 2.03eV AlGaInP solar cell is demonstrated with a bandgap-voltage offset of 440mV, the lowest of any AlGaInP solar cell reported to date. Single-junction AlGaInP, GaInP, and GaAs solar cells designed for high-temperature operation are characterized up to a temperature of 400°C. The cell properties are compared to an analytical drift-diffusion model, and we find that a fundamental increase in the intrinsic carrier concentration, ni, dominates the temperature dependence of the dark currents, open-circuit voltage, and cell efficiency. These findings provide a valuable guide to the design of any system that requires high-temperature solar cell operation.

Direct-to-diffuse UV Solar Irradiance Ratio for a UV rotating Shadowband Spectroradiometer and a UV Multi-filter Rotating Shadowband Radiometer

NASA Astrophysics Data System (ADS)

Lantz, K.; Kiedron, P.; Petropavlovskikh, I.; Michalsky, J.; Slusser, J.

2008-12-01

. Two spectroradiometers reside that measure direct and diffuse UV solar irradiance are located at the Table Mountain Test Facility, 8 km north of Boulder, CO. The UV- Rotating Shadowband Spectrograph (UV-RSS) measures diffuse and direct solar irradiance from 290 - 400 nm. The UV Multi-Filter Rotating Shadowband Radiometer (UV-MFRSR) measures diffuse and direct solar irradiance in seven 2-nm wide bands, i.e. 300, 305, 311, 317, 325, and 368 nm. The purpose of the work is to compare radiative transfer model calculations (TUV) with the results from the UV-Rotating Shadowband Spectroradiometer (UV-RSS) and the UV-MFRSR to estimate direct-to-diffuse solar irradiance ratios (DDR) that are used to evaluate the possibility of retrieving aerosol single scattering albedo (SSA) under a variety of atmospheric conditions: large and small aerosol loading, large and small surface albedo. For the radiative transfer calculations, total ozone measurements are obtained from a collocated Brewer spectrophotometer.

The Role of Education and Training Programs in the Commercialization and Diffusion of Solar Energy Technologies.

ERIC Educational Resources Information Center

Burns, Barbara; And Others

The solar energy labor force is analyzed by identifying the importance of education and training in the commercialization and diffusion of solar technologies, discussing issues for planning and analysis of solar education and training efforts, and illustrating the range of programs and courses presently available. Four general perspectives are…

XMM-Newton Observations of Solar Wind Charge Exchange Emission

NASA Technical Reports Server (NTRS)

Snowden, S. L.; Collier, M. R.; Kuntz, K. D.

2004-01-01

We present an XMM-Newton spectrum of diffuse X-ray emission from within the solar system. The spectrum is dominated by O VII and O VIII lines at 0.57 keV and 0.65 keV, O VIII (and possibly Fe XVII) lines at approximately 0.8 keV, Ne IX lines at approximately 0.92 keV, and Mg XI lines at approximately 1.35 keV. This spectrum is consistent with what is expected from charge exchange emission between the highly ionized solar wind and either interstellar neutrals in the heliosphere or material from Earth's exosphere. The emission is clearly seen as a low-energy ( E less than 1.5 keV) spectral enhancement in one of a series of observations of the Hubble Deep Field North. The X-ray enhancement is concurrent with an enhancement in the solar wind measured by the ACE satellite. The solar wind enhancement reaches a flux level an order of magnitude more intense than typical fluxes at 1 AU, and has ion ratios with significantly enhanced higher ionization states. Whereas observations of the solar wind plasma made at a single point reflect only local conditions which may only be representative of solar wind properties with spatial scales ranging from less than half of an Earth radii (approximately 10 s) to 100 Earth radii, X-ray observations of solar wind charge exchange are remote sensing measurements which may provide observations which are significantly more global in character. Besides being of interest in its own right for studies of the solar system, this emission can have significant consequences for observations of more cosmological objects. It can provide emission lines at zero redshift which are of particular interest (e.g., O VII and O VIII) in studies of diffuse thermal emission, and which can therefore act as contamination in objects which cover the entire detector field of view. We propose the use of solar wind monitoring data, such as from the ACE and Wind spacecraft, as a diagnostic to screen for such possibilities.

Fabrication of solar light induced Fe-TiO{sub 2} immobilized on glass-fiber and application for phenol photocatalytic degradation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Shaohua, E-mail: linsh75@163.com; Zhang, Xiwang; Sun, Qinju

2013-11-15

Graphical abstract: - Highlights: • Fe-doped TiO{sub 2} immobilized on glass-fiber net were prepared by sol–gel method. • Fe inhibited the phase transition of TiO{sub 2} from anatase to rutile. • The optimal Fe doping dose was around 0.005 wt%. • The optimal calcination temperature was around 600 °C. - Abstract: Iron-doped anatase titanium dioxide catalysts coated on glass-fiber were successfully synthesized by a dip-coating sol–gel method. The prepared catalysts were characterized by scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy to understand the synthesis mechanism, and their photocatalytic activities weremore » evaluated by photodegradation of phenol under simulated solar irradiation. EDX analysis confirmed the existence of iron in the immobilized catalysts. XRD suggested that the phase transition of the catalysts from anatase to rutile were restrained, and almost pure anatase TiO{sub 2} could retain even the calcination temperature reached 800 °C. The UV-Vis diffuse reflectance spectroscopy of the catalysts showed a red shift and increased photoabsorbance in the visible range for all the doped samples. Iron loading and calcination temperature have obvious influences on photocatalytic activity. In this study, the optimal doping dose and calcination temperature were around 0.005 wt% and 600 °C, respectively.« less

Mechanisms limiting the performance of large grain polycrystalline silicon solar cells

NASA Technical Reports Server (NTRS)

Culik, J. S.; Alexander, P.; Dumas, K. A.; Wohlgemuth, J. W.

1984-01-01

The open-circuit voltage and short-circuit current of large-grain (1 to 10 mm grain diameter) polycrystalline silicon solar cells is determined by the minority-carrier diffusion length within the bulk of the grains. This was demonstrated by irradiating polycrystalline and single-crystal (Czochralski) silicon solar cells with 1 MeV electrons to reduce their bulk lifetime. The variation of short-circuit current with minority-carrier diffusion length for the polycrystalline solar cells is identical to that of the single-crystal solar cells. The open-circuit voltage versus short-circuit current characteristic of the polycrystalline solar cells for reduced diffusion lengths is also identical to that of the single-crystal solar cells. The open-circuit voltage of the polycrystalline solar cells is a strong function of quasi-neutral (bulk) recombination, and is reduced only slightly, if at all, by grain-boundary recombination.

SOLINS- SOLAR INSOLATION MODEL FOR COMPUTING AVAILABLE SOLAR ENERGY TO A SURFACE OF ARBITRARY ORIENTATION

NASA Technical Reports Server (NTRS)

Smith, J. H.

1994-01-01

This computer program, SOLINS, was developed to aid engineers and solar system designers in the accurate modeling of the average hourly solar insolation on a surface of arbitrary orientation. The program can be used to study insolation problems specific to residential and commercial applications where the amount of space available for solar collectors is limited by shadowing problems, energy output requirements, and costs. For tandem rack arrays, SOLINS will accommodate the use of augmentation reflectors built into the support structure to increase insolation values at the collector surface. As the use of flat plate solar collectors becomes more prevalent in the building industry, the engineer and designer must have the capability to conduct extensive sensitivity analyses on the orientation and location of solar collectors. SOLINS should prove to be a valuable aid in this area of engineering. SOLINS uses a modified version of the National Bureau of Standards model to calculate the direct, diffuse, and reflected components of total insolation on a tilted surface with a given azimuthal orientation. The model is based on the work of Liu and Jordan with corrections by Kusuda and Ishii to account for early morning and late afternoon errors. The model uses a parametric description of the average day solar climate to generate monthly average day profiles by hour of the insolation level on the collector surface. The model includes accommodation of user specified ground and landscape reflectivities at the collector site. For roof or ground mounted, tilted arrays, SOLINS will calculate insolation including the effects of shadowing and augmentation reflectors. The user provides SOLINS with data describing the array design, array orientation, the month, the solar climate parameter, the ground reflectance, and printout control specifications. For the specified array and environmental conditions, SOLINS outputs the hourly insolation the array will receive during an average day during the month specified, along with the total insolation the collector surface will receive over an average 24-hour period. This program is written in FORTRAN IV for batch execution and has been implemented on an IBM 370 computer with a central memory requirement of approximately 46K of 8 bit bytes. The SOLINS routines were developed in 1979.

Topographic Correction Module at Storm (TC@Storm)

NASA Astrophysics Data System (ADS)

Zaksek, K.; Cotar, K.; Veljanovski, T.; Pehani, P.; Ostir, K.

2015-04-01

Different solar position in combination with terrain slope and aspect result in different illumination of inclined surfaces. Therefore, the retrieved satellite data cannot be accurately transformed to the spectral reflectance, which depends only on the land cover. The topographic correction should remove this effect and enable further automatic processing of higher level products. The topographic correction TC@STORM was developed as a module within the SPACE-SI automatic near-real-time image processing chain STORM. It combines physical approach with the standard Minnaert method. The total irradiance is modelled as a three-component irradiance: direct (dependent on incidence angle, sun zenith angle and slope), diffuse from the sky (dependent mainly on sky-view factor), and diffuse reflected from the terrain (dependent on sky-view factor and albedo). For computation of diffuse irradiation from the sky we assume an anisotropic brightness of the sky. We iteratively estimate a linear combination from 10 different models, to provide the best results. Dependent on the data resolution, we mask shades based on radiometric (image) or geometric properties. The method was tested on RapidEye, Landsat 8, and PROBA-V data. Final results of the correction were evaluated and statistically validated based on various topography settings and land cover classes. Images show great improvements in shaded areas.

Variability of Solar Radiation under Cloud-Free Skies in China: The Role of Aerosols

NASA Technical Reports Server (NTRS)

Qian, Yun; Wang, Weiguo; Leung, L. ruby; Kaiser, Dale P.

2007-01-01

In this study, we analyzed long-term surface global and diffuse solar radiation, aerosol single scattering albedo (SSA), and relative humidity (RH) from China. Our analysis reveals that much of China experienced significant decreases in global solar radiation (GSR) and increases in diffuse solar radiation under cloud-free skies between the 1960s and 1980s. With RH and aerosol SSA being rather constant during that time period, we suggest that the increasing aerosol loading from emission of pollutants is responsible for the observed reduced GSR and increased diffuse radiation in cloud-free skies. Although pollutant emissions continue to increase after the 1980s, the increment of aerosol SSA since 1980s can partly explain the transition of GSR from a decreasing trend to no apparent trend around that time. Preliminary analysis is also provided on the potential role of RH in affecting the global and diffuse solar radiation reaching the earth surface.

Diffusion engineering of ions and charge carriers for stable efficient perovskite solar cells

NASA Astrophysics Data System (ADS)

Bi, Enbing; Chen, Han; Xie, Fengxian; Wu, Yongzhen; Chen, Wei; Su, Yanjie; Islam, Ashraful; Grätzel, Michael; Yang, Xudong; Han, Liyuan

2017-06-01

Long-term stability is crucial for the future application of perovskite solar cells, a promising low-cost photovoltaic technology that has rapidly advanced in the recent years. Here, we designed a nanostructured carbon layer to suppress the diffusion of ions/molecules within perovskite solar cells, an important degradation process in the device. Furthermore, this nanocarbon layer benefited the diffusion of electron charge carriers to enable a high-energy conversion efficiency. Finally, the efficiency on a perovskite solar cell with an aperture area of 1.02 cm2, after a thermal aging test at 85 °C for over 500 h, or light soaking for 1,000 h, was stable of over 15% during the entire test. The present diffusion engineering of ions/molecules and photo generated charges paves a way to realizing long-term stable and highly efficient perovskite solar cells.

Advanced materials for multilayer mirrors for extreme ultraviolet solar astronomy.

PubMed

Bogachev, S A; Chkhalo, N I; Kuzin, S V; Pariev, D E; Polkovnikov, V N; Salashchenko, N N; Shestov, S V; Zuev, S Y

2016-03-20

We provide an analysis of contemporary multilayer optics for extreme ultraviolet (EUV) solar astronomy in the wavelength ranges: λ=12.9-13.3  nm, λ=17-21  nm, λ=28-33  nm, and λ=58.4  nm. We found new material pairs, which will make new spaceborne experiments possible due to the high reflection efficiencies, spectral resolution, and long-term stabilities of the proposed multilayer coatings. In the spectral range λ=13  nm, Mo/Be multilayer mirrors were shown to demonstrate a better ratio of reflection efficiency and spectral resolution compared with the commonly used Mo/Si. In the spectral range λ=17-21  nm, a new multilayer structure Al/Si was proposed, which had higher spectral resolution along with comparable reflection efficiency compared with the commonly used Al/Zr multilayer structures. In the spectral range λ=30  nm, the Si/B₄C/Mg/Cr multilayer structure turned out to best obey reflection efficiency and long-term stability. The B₄C and Cr layers prevented mutual diffusion of the Si and Mg layers. For the spectral range λ=58  nm, a new multilayer Mo/Mg-based structure was developed; its reflection efficiency and long-term stability have been analyzed. We also investigated intrinsic stresses inherent for most of the multilayer structures and proposed possibilities for stress elimination.

Optical losses of solar mirrors due to atmospheric contamination at Liberal, Kansas and Oologah, Oklahoma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dake, L.S.; Lind, M.A.

An assessment is presented of the effect of outdoor exposure on mirrors located at two sites selected for potential solar cogeneration/repowering facilities: Liberal, Kansas and Oologah, Oklahoma. Mirror coupons were placed on tracking heliostat simulators located in the proposed heliostat fields and were removed periodically. The spectral hemispherical and diffuse reflectances of these coupons were measured. Representative samples were analyzed for the chemical composition of the dust particulates using SEM/EDX. Other samples were washed with a high pressure spray and recharacterized to determine the effects of the residual dust. Average specular reflectance losses over the entire test period (up tomore » 504 days) were 6 to 12%, with a range of 1 to 30%. Specular reflectance losses varied widely from day to day depending on local weather conditions. The losses due to scattering were 2 to 5 times greater than the losses due to absorptance. The average degradation rate over the first thirty days was an order of magnitude larger than the average degradation rate over the entire sampling period. Specular reflectance loss rates averaged 0.5% per day and greater between periods of natural cleaning. The chemical composition of the dust on the mirrors was characteristic of the indigenous soil, with some samples also showing the presence of sulfur and chlorine, possibly from cooling tower drift.« less

Diffusion length variation and proton damage coefficients for InP/In(x)Ga(1-x)As/GaAs solar cells

NASA Technical Reports Server (NTRS)

Jain, R. K.; Weinberg, I.; Flood, D. J.

1993-01-01

Indium phosphide solar cells are more radiation resistant than gallium arsenide and silicon solar cells, and their growth by heteroepitaxy offers additional advantages leading to the development of lighter, mechanically strong and cost-effective cells. Changes in heteroepitaxial InP cell efficiency under 0.5 and 3 MeV proton irradiations are explained by the variation in the minority-carrier diffusion length. The base diffusion length versus proton fluence is calculated by simulating the cell performance. The diffusion length damage coefficient K(L) is plotted as a function of proton fluence.

MODIS Instrument Operation and Calibration Improvements

NASA Technical Reports Server (NTRS)

Xiong, X.; Angal, A.; Madhavan, S.; Link, D.; Geng, X.; Wenny, B.; Wu, A.; Chen, H.; Salomonson, V.

2014-01-01

Terra and Aqua MODIS have successfully operated for over 14 and 12 years since their respective launches in 1999 and 2002. The MODIS on-orbit calibration is performed using a set of on-board calibrators, which include a solar diffuser for calibrating the reflective solar bands (RSB) and a blackbody for the thermal emissive bands (TEB). On-orbit changes in the sensor responses as well as key performance parameters are monitored using the measurements of these on-board calibrators. This paper provides an overview of MODIS on-orbit operation and calibration activities, and instrument long-term performance. It presents a brief summary of the calibration enhancements made in the latest MODIS data collection 6 (C6). Future improvements in the MODIS calibration and their potential applications to the S-NPP VIIRS are also discussed.

Diffuse Reflectance Spectroscopy Versus Mexameter(®) MX18 Measurements of Melanin and Erythema in an African Population.

PubMed

Wright, Caradee Y; Karsten, Aletta E; Wilkes, Marcus; Singh, Ann; du Plessis, Johan; Albers, Patricia N; Karsten, Petrus A

2016-07-01

Melanin provides protection against excess exposure to solar ultraviolet radiation (UVR) and related adverse health effects. Diffuse reflectance spectroscopy (DRS) can be used to calculate cutaneous melanin and erythema, but this is complex and has been mostly used for light-to-medium pigmented skin. Handheld reflectance spectrophotometers, such as the Mexameter(®) MX18, can also be used. We compared DRS-calculated melanin and erythema values with Mexameter melanin and erythema index values to understand how these techniques/measurements correlate in an African population of predominantly deeply pigmented skin. Five hundred and three participants comprised 68.5% self-identified Black African, 9.9% Indian/Asian, 18.4% White and 2.9% Colored. The majority of Black African (45%), Indian/Asian (34%) and Colored (53%) participants self-identified their skin as being "brown." Measured melanin levels increased with darker self-reported skin color. DRS-calculated and Mexameter melanin values demonstrated a positive correlation (Spearman rho = 0.87, P < 0.001). The results from both instruments showed erythema values were strongly correlated with their own melanin values. This finding is considered spurious and may result from the complexity of separating brown and red pigment when using narrowband reflectance techniques. Further work is needed to understand melanin, erythema and color in Black skin given sun-related health risks in vulnerable groups in Africa. © 2016 The American Society of Photobiology.

Inventory of File gdas1.t06z.sfluxgrbf06.grib2

Science.gov Websites

hour ave Visible Diffuse Downward Solar Flux [W/m^2] 036 surface NBDSF 0-6 hour ave Near IR Beam Downward Solar Flux [W/m^2] 037 surface NDDSF 0-6 hour ave Near IR Diffuse Downward Solar Flux [W/m^2] 038

Inventory of File gfs.t06z.sfluxgrbf06.grib2

Science.gov Websites

hour ave Visible Diffuse Downward Solar Flux [W/m^2] 036 surface NBDSF 0-6 hour ave Near IR Beam Downward Solar Flux [W/m^2] 037 surface NDDSF 0-6 hour ave Near IR Diffuse Downward Solar Flux [W/m^2] 038

Modification of UV absorption profile of polymer film reflectors to increase solar-weighted reflectance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jorgensen, Gary; Gee, Randall C.; White, David

Provided are reflective thin film constructions including a reduced number of layers, which provides for increased solar-weighted hemispherical reflectance and durability. Reflective films include those comprising an ultraviolet absorbing abrasion resistant coating over a metal layer. Also provided are ultraviolet absorbing abrasion resistant coatings and methods for optimizing the ultraviolet absorption of an abrasion resistant coating. Reflective films disclosed herein are useful for solar reflecting, solar collecting, and solar concentrating applications, such as for the generation of electrical power.

Laser doping of boron-doped Si paste for high-efficiency silicon solar cells

NASA Astrophysics Data System (ADS)

Tomizawa, Yuka; Imamura, Tetsuya; Soeda, Masaya; Ikeda, Yoshinori; Shiro, Takashi

2015-08-01

Boron laser doping (LD) is a promising technology for high-efficiency solar cells such as p-type passivated locally diffused solar cells and n-type Si-wafer-based solar cells. We produced a printable phosphorus- or boron-doped Si paste (NanoGram® Si paste/ink) for use as a diffuser in the LD process. We used the boron LD process to fabricate high-efficiency passivated emitter and rear locally diffused (PERL) solar cells. PERL solar cells on Czochralski Si (Cz-Si) wafers yielded a maximum efficiency of 19.7%, whereas the efficiency of a reference cell was 18.5%. Fill factors above 79% and open circuit voltages above 655 mV were measured. We found that the boron-doped area effectively performs as a local boron back surface field (BSF). The characteristics of the solar cell formed using NanoGram® Si paste/ink were better than those of the reference cell.

Arrangement, Dopant Source, And Method For Making Solar Cells

DOEpatents

Rohatgi, Ajeet; Krygowski, Thomas W.

1999-10-26

Disclosed is an arrangement, dopant source and method used in the fabrication of photocells that minimize handling of cell wafers and involve a single furnace step. First, dopant sources are created by depositing selected dopants onto both surfaces of source wafers. The concentration of dopant that is placed on the surface is relatively low so that the sources are starved sources. These sources are stacked with photocell wafers in alternating orientation in a furnace. Next, the temperature is raised and thermal diffusion takes place whereby the dopant leaves the source wafers and becomes diffused in a cell wafer creating the junctions necessary for photocells to operate. The concentration of dopant diffused into a single side of the cell wafer is proportional to the concentration placed on the respective dopant source facing the side of the cell wafer. Then, in the same thermal cycle, a layer of oxide is created by introducing oxygen into the furnace environment after sufficient diffusion has taken place. Finally, the cell wafers receive an anti-reflective coating and electrical contacts for the purpose of gathering electrical charge.

Near Field Imaging of Gallium Nitride Nanowires for Characterization of Minority Carrier Diffusion

DTIC Science & Technology

2009-12-01

diffusion length in nanowires is critical to potential applications in solar cells , spectroscopic sensing, and/or lasers and light emitting diodes (LED...technique has been successfully demonstrated with thin film solar cell materials [4, 5]. In these experiments, the diffusion length was measured using a...minority carrier diffusion length . This technique has been used in the near-field collection mode to image the diffusion of holes in n-type GaN

Effect of Ram and Zenith Exposure on the Optical Properties of Polymers in Space

NASA Technical Reports Server (NTRS)

Li, Yuachun; de Groh, Kim K.; Banks, Bruce A.; Leneghan, Halle; Asmar, Olivia

2017-01-01

The temperature of spacecraft is influenced by the solar absorptance and thermal emittance of the external spacecraft materials. Optical and thermal properties can degrade over time in the harsh low Earth orbital (LEO) space environment where spacecraft external materials are exposed to various forms of radiation, thermal cycling, and atomic oxygen. Therefore, it is important to test the durability of spacecraft materials in the space environment. One objective of the Polymers and Zenith Polymers Experiments was to determine the effect of LEO space exposure on the optical properties of various spacecraft polymers. These experiments were flown as part of the Materials International Space Station Experiment 7 (MISSE 7) mission on the exterior of the International Space Station (ISS) for 1.5 years. Samples were flown in ram, wake or zenith directions, receiving varying amounts of atomic oxygen and solar radiation exposure. Total and diffuse reflectance and transmittance of flight and corresponding control samples were obtained post-flight using a Cary 5000 UV-Vis-NIR Spectrophotometer. Integrated air mass zero solar absorptance (s) of the flight and control samples were computed from the total transmittance and reflectance, and compared. The optical data are compared with similar polymers exposed to space for four years as part of MISSE 2, and with atomic oxygen erosion data, to help understand the degradation of these polymers in the space environment. Results show that prolonged space exposure increases the solar absorptance of some materials. Knowing which polymers remain stable will benefit future spacecraft design.

An Earth Albedo Model: A Mathematical Model for the Radiant Energy Input to an Orbiting Spacecraft Due to the Diffuse Reflectance of Solar Radiation from the Earth Below

NASA Technical Reports Server (NTRS)

Flatley, Thomas W.; Moore, Wendy A.

1994-01-01

Past missions have shown that the earth's albedo can have a significant effect on the sun sensors used for spacecraft attitude control information. In response to this concern, an algorithm was developed to simulate this phenomenon, consisting of two parts, the physical model of albedo and its effect on the sun sensors. This paper contains the theoretical development of this model, practical operational notes, and its implementation in a FORTRAN subroutine.

Point Pairing Method Based on the Principle of Material Frame Indifference for the Characterization of Unknown Space Objects using Non-Resolved Photometry Data

DTIC Science & Technology

2013-09-01

provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if it does not display a currently valid OMB...the satellite. The material constitutive laws of interest are the bidirectional reflectance distribution functions ( BRDF ) for diffuse and specular...solar panel can be related to each other using the BRDF definition. This creates a set of three independent equations and three unknowns, which can be

A ratioing radiometer for use with a solar diffuser. [to monitor in-flight calibration of satellite sensors

NASA Technical Reports Server (NTRS)

Palmer, James M.; Slater, Philip N.

1991-01-01

The use of an on-board solar diffuser has been proposed to monitor the in-flight calibration of satellite sensors. This paper presents the preliminary specifications and design for a ratioing radiometer, to be used to determine the change in radiance of the solar diffuser. The issues involved in spectral channel selection are discussed and the effects of stray light are presented. An error analysis showing the benefit of the ratioing radiometer is included.

Characterization and Performance of the Suomi-NPP VIIRS Solar Diffuser Stability Monitor

NASA Technical Reports Server (NTRS)

Fulbright, Jon P.; Ning, Lei; Kwofu, Chiang; Xiaoxiong, Xiong

2012-01-01

We describe the on-orbit characterization and performance of the Solar Diffuser Stability Monitor (SDSM) on-board Suomi-NPP/VIIRS. This description includes the observing procedure of each SDSM event, the algorithms used to generate the Solar Diffuser degradation corrective factors, and the results for the mission to date. We will also compare the performance of the VIIRS SDSM and SD to the similar components operating on the MODIS instrument on the EOS Terra and Aqua satellites

THE SPATIO-TEMPORAL EVOLUTION OF SOLAR FLARES OBSERVED WITH AIA/SDO: FRACTAL DIFFUSION, SUB-DIFFUSION, OR LOGISTIC GROWTH?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aschwanden, Markus J., E-mail: aschwanden@lmsal.com

2012-09-20

We explore the spatio-temporal evolution of solar flares by fitting a radial expansion model r(t) that consists of an exponentially growing acceleration phase, followed by a deceleration phase that is parameterized by the generalized diffusion function r(t){proportional_to}{kappa}(t - t{sub 1}){sup {beta}/2}, which includes the logistic growth limit ({beta} = 0), sub-diffusion ({beta} = 0-1), classical diffusion ({beta} = 1), super-diffusion ({beta} = 1-2), and the linear expansion limit ({beta} = 2). We analyze all M- and X-class flares observed with Geostationary Operational Environmental Satellite and Atmospheric Imaging Assembly/Solar Dynamics Observatory (SDO) during the first two years of the SDO mission,more » amounting to 155 events. We find that most flares operate in the sub-diffusive regime ({beta} = 0.53 {+-} 0.27), which we interpret in terms of anisotropic chain reactions of intermittent magnetic reconnection episodes in a low plasma-{beta} corona. We find a mean propagation speed of v = 15 {+-} 12 km s{sup -1}, with maximum speeds of v{sub max} = 80 {+-} 85 km s{sup -1} per flare, which is substantially slower than the sonic speeds expected for thermal diffusion of flare plasmas. The diffusive characteristics established here (for the first time for solar flares) is consistent with the fractal-diffusive self-organized criticality model, which predicted diffusive transport merely based on cellular automaton simulations.« less

A data-led comparison of simple canopy radiative transfer models for the boreal forest

NASA Astrophysics Data System (ADS)

Reid, T.; Essery, R.; Rutter, N.; King, M.

2012-12-01

Given the computational complexity of numerical weather and climate models, it is worthwhile developing very simple parameterizations for processes such as the transmission of radiation through forest canopies. For this reason, the land surface schemes in global models, and most snow hydrological models, tend to use simple one-dimensional approaches based on Beer's Law or two-stream approximations. Such approaches assume a continuous canopy structure that may not be suitable for the varied, heterogeneous forest cover in boreal regions, especially in winter when snow in the canopy and on the ground may either block radiation or produce multiple reflections between the ground and the trees. There is great benefit in comparing models to real transmissivity values calculated from radiation measurements below and above Arctic canopies. In particular, there is a lack of data for leafless boreal deciduous forests, where canopy gaps are prevalent even at low solar elevation angles near the horizon. In this study, models are compared to radiation data collected in an area of boreal birch forest near Abisko, Sweden in March/April 2011 and mixed conifer forest at Sodankylä, Finland in March/April 2012. Arrays comprising ten shortwave pyranometers were deployed for periods of up to 50 days, under forest plots of varying canopy structures and densities. In addition, global and diffuse shortwave irradiances were recorded at nearby open sites representing the top-of-canopy conditions. A model is developed that explicitly accounts for both diffuse radiation and direct beam transmission on a 5-minute timestep, by using upward-looking hemispherical photographs taken from every pyranometer site. This model reproduces measured transmissivity, although with a slight underestimation, especially at low solar elevations - this could be attributed to multiple reflections that are not accounted for in the model. On the other hand, models based on Beer's Law tend to underestimate the canopy transmissivity significantly, especially for leafless birch canopies where the required assumption of a continuous canopy breaks down. These findings are important for the often sparse, heterogeneous forest cover in boreal regions, where forest edges and canopy gaps are plentiful. They could also have an impact on estimations of overall land surface albedo. Moreover, all models are sensitive to the partitioning of top-of-canopy radiation into its direct and diffuse components, which is complicated by the low solar elevations in the Arctic. More research is required to decide the best way of quantifying the diffuse fraction, using data alongside both physical and empirical models.

Light Trapping for Silicon Solar Cells: Theory and Experiment

NASA Astrophysics Data System (ADS)

Zhao, Hui

Crystalline silicon solar cells have been the mainstream technology for photovoltaic energy conversion since their invention in 1954. Since silicon is an indirect band gap material, its absorption coefficient is low for much of the solar spectrum, and the highest conversion efficiencies are achieved only in cells that are thicker than about 0.1 mm. Light trapping by total internal reflection is important to increase the optical absorption in silicon layers, and becomes increasingly important as the layers are thinned. Light trapping is typically characterized by the enhancement of the absorptance of a solar cell beyond the value for a single pass of the incident beam through an absorbing semiconductor layer. Using an equipartition argument, in 1982 Yablonovitch calculated an enhancement of 4n2 , where n is the refractive index. We have extracted effective light-trapping enhancements from published external quantum efficiency spectra in several dozen silicon solar cells. These results show that this "thermodynamic" enhancement has never been achieved experimentally. The reasons for incomplete light trapping could be poor anti-reflection coating, inefficient light scattering, and parasitic absorption. We report the light-trapping properties of nanocrystalline silicon nip solar cells deposited onto two types of Ag/ZnO backreflectors at United Solar Ovonic, LLC. We prepared the first type by first making silver nanparticles onto a stainless steel substrate, and then overcoating the nanoparticles with a second silver layer. The second type was prepared at United Solar using a continuous silver film. Both types were then overcoated with a ZnO film. The root mean square roughness varied from 27 to 61 nm, and diffuse reflectance at 1000 nm wavelength varied from 0.4 to 0.8. The finished cells have a thin, indium-tin oxide layer on the top that acts as an antireflection coating. For both backreflector types, the short-circuit photocurrent densities J SC for solar illumination were about 25 mA/cm2 for 1.5 micron cells. We also measured external quantum efficiency spectra and optical reflectance spectra, which were only slightly affected by the back reflector morphology. We performed a thermodynamic calculation for the optical absorptance in the silicon layer and the top oxide layer to explain the experimental results; the calculation is an extension of previous work by Stuart and Hall that incorporates the antireflection properties and absorption in the top oxide film. From our calculations and experimental measurements, we concluded that parasitic absorption in this film is the prominent reason for incomplete light trapping in these cells. To reduce the optical parasitic loss in the top oxide layer, we propose a bilayer design, and show the possible benefits to the photocurrent density.

Diffusion length variation in 0.5- and 3-MeV-proton-irradiated, heteroepitaxial indium phosphide solar cells

NASA Technical Reports Server (NTRS)

Jain, Raj K.; Weinberg, Irving; Flood, Dennis J.

1993-01-01

Indium phosphide (InP) solar cells are more radiation resistant than gallium arsenide (GaAs) and silicon (Si) solar cells, and their growth by heteroepitaxy offers additional advantages leading to the development of light weight, mechanically strong, and cost-effective cells. Changes in heteroepitaxial InP cell efficiency under 0.5- and 3-MeV proton irradiations have been explained by the variation in the minority-carrier diffusion length. The base diffusion length versus proton fluence was calculated by simulating the cell performance. The diffusion length damage coefficient, K(sub L), was also plotted as a function of proton fluence.

Recent progress in high-output-voltage silicon solar cells

NASA Technical Reports Server (NTRS)

Muelenberg, A.; Arndt, R. A.; Allison, J. F.; Weizer, V.

1980-01-01

The status of the technology associated with the development of high output voltage silicon solar cells is reported. The energy conversion efficiency of a double diffusion process is compared to that of a single diffusion process. The efficiency of a 0.1 ohm/cm solar cell is characterized both before and after covering.

Helium diffusion in the sun

NASA Technical Reports Server (NTRS)

Bahcall, J. N.; Pinsonneault, M. H.

1992-01-01

We calculate improved standard solar models using the new Livermore (OPAL) opacity tables, an accurate (exportable) nuclear energy generation routine which takes account of recent measurements and analyses, and the recent Anders-Grevesse determination of heavy element abundances. We also evaluate directly the effect of the diffusion of helium with respect to hydrogen on the calculated neutrino fluxes, on the primordial solar helium abundance, and on the depth of the convective zone. Helium diffusion increases the predicted event rates by about 0.8 SNU, or 11 percent of the total rate, in the chlorine solar neutrino experiment, by about 3.5 SNU, or 3 percent, in the gallium solar neutrino experiments, and by about 12 percent in the Kamiokande and SNO solar neutrino experiments. The best standard solar model including helium diffusion and the most accurate nuclear parameters, element abundances, and radiative opacity predicts a value of 8.0 SNU +/- 3.0 SNU for the C1-37 experiment and 132 +21/-17 SNU for the Ga - 71 experiment, where the uncertainties include 3 sigma errors for all measured input parameters.

Application of semiconductor diffusants to solar cells by screen printing

NASA Technical Reports Server (NTRS)

Evans, J. C., Jr.; Brandhorst, H. W., Jr.; Mazaris, G. A.; Scudder, L. R. (Inventor)

1978-01-01

Diffusants were applied onto semiconductor solar cell substrates, using screen printing techniques. The method was applicable to square and rectangular cells and can be used to apply dopants of opposite types to the front and back of the substrate. Then, simultaneous diffusion of both dopants can be performed with a single furnace pass.

Simultaneous junction formation

NASA Technical Reports Server (NTRS)

Campbell, R. B.

1984-01-01

High-risk, high-payoff improvements to a baseline process sequence of simultaneous junction formation of silicon solar cells are discussed. The feasibility of simultaneously forming front and back junctions of solar cells using liquid dopants on dendritic web silicon was studied. Simultaneous diffusion was compared to sequential diffusion. A belt furnace for the diffusion process was tested.

On the upstream boundary of electron foreshocks in the solar wind

NASA Technical Reports Server (NTRS)

Zimbardo, G.; Veltri, P.

1995-01-01

The upstream boundary of electron foreshocks is defined as the path of the fastest electrons reflected by collisionless shocks and moving along the magnetic field in the solar wind. Considerable levels of magnetic fluctuations are found in these regions of the solar wind, and their effect is to create both a broadening and a fine structure of the electron foreshock boundary. The magnetic structure is studied by means of a 3-D numerical simulation of a turbulent magnetic field. Enhanced, anomalous diffusion is found, (Delta x(exp 2)) varies as s(sup alpha), where alpha is greater than 1 for typical values of the parameters (here, Delta x(exp 2) is the mean square width of the tangent magnetic surface and s is the field line length). This corresponds to a Levy flight regime for the magnetic field line random walk, and allows very efficient electron propagation perpendicular to the magnetic field. Implications on the observations of planetary foreshocks and of the termination shock foreshock are considered.

The Origin of the Excess Near-Infrared Diffuse Sky Brightness: Population III Stars or Zodiacal Light?

NASA Technical Reports Server (NTRS)

Dwek, Eli

2006-01-01

The intensity of the diffuse 1 to 5 micron sky emission from which solar system and Galactic foregrounds have been subtracted is in excess of that expected from energy released by galaxies and stars that formed during the z < 5 redshift interval. The spectral signature of this excess near-infrared background light (NIRBL) component is almost identical to that of reflected sunlight from the interplanetary dust cloud, and could therefore be the result of the incomplete subtraction of this foreground emission component from the diffuse sky maps. Alternatively, this emission component could be extragalactic. Its spectral signature is consistent with that of redshifted continuum and recombination line emission from H-II regions formed by the first generation of very massive stars. In this talk I will present the implications of this excess emission for our understanding of the zodiacal dust cloud, the formation rate of Pop III stars, and the TeV gamma-ray opacity to nearby blazars.

Graphene oxide as a p-dopant and an anti-reflection coating layer, in graphene/silicon solar cells

NASA Astrophysics Data System (ADS)

Yavuz, S.; Kuru, C.; Choi, D.; Kargar, A.; Jin, S.; Bandaru, P. R.

2016-03-01

It is shown that coating graphene-silicon (Gr/Si) Schottky junction based solar cells with graphene oxide (GO) improves the power conversion efficiency (PCE) of the cells, while demonstrating unprecedented device stability. The PCE has been shown to be increased to 10.6% (at incident radiation of 100 mW cm-2) for the Gr/Si solar cell with an optimal GO coating thickness compared to 3.6% for a bare/uncoated Gr/Si solar cell. The p-doping of graphene by the GO, which also serves as an antireflection coating (ARC) has been shown to be a main contributing factor to the enhanced PCE. A simple spin coating process has been used to apply GO with thickness commensurate with an anti-refection coating (ARC) and indicates the suitability of the developed methodology for large-scale solar cell assembly.It is shown that coating graphene-silicon (Gr/Si) Schottky junction based solar cells with graphene oxide (GO) improves the power conversion efficiency (PCE) of the cells, while demonstrating unprecedented device stability. The PCE has been shown to be increased to 10.6% (at incident radiation of 100 mW cm-2) for the Gr/Si solar cell with an optimal GO coating thickness compared to 3.6% for a bare/uncoated Gr/Si solar cell. The p-doping of graphene by the GO, which also serves as an antireflection coating (ARC) has been shown to be a main contributing factor to the enhanced PCE. A simple spin coating process has been used to apply GO with thickness commensurate with an anti-refection coating (ARC) and indicates the suitability of the developed methodology for large-scale solar cell assembly. Electronic supplementary information (ESI) available: (i) Experimental methods, (ii) optical images of devices with and without graphene oxide (GO), (iii) comparison of the power conversion efficiency (PCE) due to the GO coating and nitric acid doping, (iv) specular and diffuse reflectance measurements, (v) stability data of pristine graphene/silicon (Gr/Si) solar cells. See DOI: 10.1039/c5nr09143h

Computing diffuse fraction of global horizontal solar radiation: A model comparison.

PubMed

Dervishi, Sokol; Mahdavi, Ardeshir

2012-06-01

For simulation-based prediction of buildings' energy use or expected gains from building-integrated solar energy systems, information on both direct and diffuse component of solar radiation is necessary. Available measured data are, however, typically restricted to global horizontal irradiance. There have been thus many efforts in the past to develop algorithms for the derivation of the diffuse fraction of solar irradiance. In this context, the present paper compares eight models for estimating diffuse fraction of irradiance based on a database of measured irradiance from Vienna, Austria. These models generally involve mathematical formulations with multiple coefficients whose values are typically valid for a specific location. Subsequent to a first comparison of these eight models, three better performing models were selected for a more detailed analysis. Thereby, the coefficients of the models were modified to account for Vienna data. The results suggest that some models can provide relatively reliable estimations of the diffuse fractions of the global irradiance. The calibration procedure could only slightly improve the models' performance.

Outdoor cultivation of temperature-tolerant Chlorella sorokiniana in a column photobioreactor under low power-input.

PubMed

Béchet, Quentin; Muñoz, Raul; Shilton, Andy; Guieysse, Benoit

2013-01-01

Temperature-tolerant Chlorella sorokiniana was cultivated in a 51-L column photobioreactor with a 1.1 m(2) illuminated area. The reactor was operated outdoors under tropical meteorological conditions (Singapore) without controlling temperature and the culture was mixed at a power input of 7.5 W/m(3) by sparging CO(2) -enriched air at 1.2 L/min (gas hold-up of 0.02). Biomass productivity averaged 10 ± 2.2 g/m(2) -day over six batch studies, yielding an average photosynthetic efficiency (PE) of 4.8 ± 0.5% of the total solar radiation (P = 0.05, N = 6). This demonstrates that temperature-tolerant microalgae can be cultivated at high PE under a mixing input sevenfold to ninefold lower than current operational guidelines (50-70 W/m(3)) and without the need for temperature control (the culture broth temperature reached 41 °C during operation). In this study, the PE value was determined based on the amount of solar radiation actually reaching the algae and this amount was estimated using a mathematical model fed with onsite solar irradiance data. This determination was found to be particularly sensitive to the value of the atmospheric diffusion coefficient, which generated a significant uncertainty in the PE calculation. The use of the mathematical model, however, confirmed that the vertical reactor geometry supported efficient photosynthesis by reducing the duration and intensity of photoinhibition events. The model also revealed that all three components of direct, diffuse, and reflected solar radiation were quantitatively important for the vertical column photobioreactor, accounting for 14%, 65%, and 21% of the total solar radiation reaching the culture, respectively. The accurate prediction of the discrete components of solar radiation reaching the algae as a function of climatic, geographic, and design parameters is therefore crucial to optimize the individual reactor geometry and the layout/spacing between the individual reactors in a reactor farm. Copyright © 2012 Wiley Periodicals, Inc.

Optimization and development of solar power system under diffused sunlight condition in rural areas with supercapacitor integration

NASA Astrophysics Data System (ADS)

Castelino, Roystan V.; Jana, Suman; Kumhar, Rajesh; Singh, Niraj K.

2018-04-01

The simulation and hardware based experiment in this presented paper shows a possibility of increasing the reliability of solar power under diffused condition by using super capacitor module. This experimental setup can be used in those areas where the sun light is intermittent and under the diffused radiation condition. Due to diffused radiation, solar PV cells operate very poorly, but by using this setup the power efficiency can be increased greatly. Sometimes dependent numerical models are used to measure the voltage and current response of the hardware setup in MATLAB Simulink based environment. To convert the scattered solar radiation to electricity using the conventional solar PV module, batteries have to be linked with the rapid charging or discharging device like super capacitor module. The conventional method consists of a charging circuit, which dumps the power if the voltage is below certain voltage level, but this circuit utilizes the entire power even if the voltage is low under diffused sun light conditions. There is no power dumped in this circuit. The efficiency and viability of this labscale experimental setup can be examined with further experiment and industrial model.

Reflection Matrix Method for Controlling Light After Reflection From a Diffuse Scattering Surface

DTIC Science & Technology

2016-12-22

reflective inverse diffusion, which was a proof-of-concept experiment that used phase modulation to shape the wavefront of a laser causing it to refocus...after reflection from a rough surface. By refocusing the light, reflective inverse diffusion has the potential to eliminate the complex radiometric model...photography. However, the initial reflective inverse diffusion experiments provided no mathematical background and were conducted under the premise that the

Steady state and time resolved optical characterization studies of Zn 2SnO 4 nanowires for solar cell applications

DOE PAGES

Yakami, Baichhabi R.; Poudyal, Uma; Nandyala, Shashank R.; ...

2016-10-25

Nanowires are a promising option for sensitized solar cells, sensors, and display technology. Most of the work thus far has focused on binary oxides for these nanowires, but ternary oxides have advantages in additional control of optical and electronic properties. Here, we report on the diffuse reflectance, Low Temperature and Room Temperature Photoluminescence (PL), PL excitation spectrum, and Time Resolved PL (TRPL) of Zinc Tin Oxide (ZTO) nanowires grown by Chemical Vapor Deposition. The PL from the ZTO nanowires does not exhibit any band gap or near gap emission, and the diffuse reflectance measurement confirms that these ZTO nanowires havemore » a direct forbidden transition. The broad PL spectrum reveals two Gaussian peaks centered at 1.86 eV (red) and 2.81 eV (blue), representing two distinct defect states or complexes. The PL spectra were further studied by the Time Resolved Emission Spectrum and intensity dependent PL and TRPL. The time resolved measurements show complex non-exponential decays at all wavelengths, indicative of defect to defect transitions, and the red emissive states decay much slower than the blue emissive states. The effects of annealing in air and vacuum are studied to investigate the origin of the defect states in the nanowires, showing that the blue states are related to oxygen vacancies. We propose an energy band model for the nanowires containing defect states within the band gap and the associated transitions between these states that are consistent with our measurements.« less

Steady state and time resolved optical characterization studies of Zn 2SnO 4 nanowires for solar cell applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yakami, Baichhabi R.; Poudyal, Uma; Nandyala, Shashank R.

Nanowires are a promising option for sensitized solar cells, sensors, and display technology. Most of the work thus far has focused on binary oxides for these nanowires, but ternary oxides have advantages in additional control of optical and electronic properties. Here, we report on the diffuse reflectance, Low Temperature and Room Temperature Photoluminescence (PL), PL excitation spectrum, and Time Resolved PL (TRPL) of Zinc Tin Oxide (ZTO) nanowires grown by Chemical Vapor Deposition. The PL from the ZTO nanowires does not exhibit any band gap or near gap emission, and the diffuse reflectance measurement confirms that these ZTO nanowires havemore » a direct forbidden transition. The broad PL spectrum reveals two Gaussian peaks centered at 1.86 eV (red) and 2.81 eV (blue), representing two distinct defect states or complexes. The PL spectra were further studied by the Time Resolved Emission Spectrum and intensity dependent PL and TRPL. The time resolved measurements show complex non-exponential decays at all wavelengths, indicative of defect to defect transitions, and the red emissive states decay much slower than the blue emissive states. The effects of annealing in air and vacuum are studied to investigate the origin of the defect states in the nanowires, showing that the blue states are related to oxygen vacancies. We propose an energy band model for the nanowires containing defect states within the band gap and the associated transitions between these states that are consistent with our measurements.« less

Long-Life Self-Renewing Solar Reflector Stack

DOEpatents

Butler, Barry Lynn

1997-07-08

A long-life solar reflector includes a solar collector substrate and a base layer bonded to a solar collector substrate. The first layer includes a first reflective layer and a first acrylic or transparent polymer layer covering the first reflective layer to prevent exposure of the first reflective layer. The reflector also includes at least one upper layer removably bonded to the first acrylic or transparent polymer layer of the base layer. The upper layer includes a second reflective layer and a second acrylic or transparent polymer layer covering the second reflective layer to prevent exposure of the second reflective layer. The upper layer may be removed from the base reflective layer to expose the base layer, thereby lengthening the useful life of the solar reflector. A method of manufacturing a solar reflector includes the steps of bonding a base layer to a solar collector substrate, wherein the base reflective layer includes a first reflective layer and a first transparent polymer or acrylic layer covering the first reflective layer; and removably bonding a first upper layer to the first transparent polymer or acrylic layer of the base layer. The first upper layer includes a second reflective layer and a second transparent polymer or acrylic layer covering the second reflective layer to prevent exposure of the second reflective layer.

Utilising shade to optimize UV exposure for vitamin D

NASA Astrophysics Data System (ADS)

Turnbull, D. J.; Parisi, A. V.

2008-01-01

Numerous studies have stated that humans need to utilise full sun radiation, at certain times of the day, to assist the body in synthesising the required levels of vitamin D3. The time needed to be spent in the full sun depends on a number of factors, for example, age, skin type, latitude, solar zenith angle. Current Australian guidelines suggest exposure to approximately 1/6 to 1/3 of a minimum erythemal dose (MED), depending on age, would be appropriate to provide adequate vitamin D3 levels. The aim of the study was to determine the exposure times to diffuse solar UV to receive exposures of 1/6 and 1/3 MED for a changing solar zenith angle in order to assess the possible role that diffuse UV (scattered radiation) may play in vitamin D3 effective UV exposures (UVD3). Diffuse and global erythemal UV measurements were conducted at five minute intervals over a twelve month period for a solar zenith angle range of 4° to 80° at a latitude of 27.6° S. For diffuse UV exposures of 1/6 and 1/3 MED, solar zenith angles smaller than 60° and 50° respectively can be utilised for exposure times of less than 10 min. Spectral measurements showed that, for a solar zenith angle of 40°, the UVA (315-400 nm) in the diffuse component of the solar UV is reduced by approximately 62% compared to the UVA in the global UV, whereas UVD3 wavelengths are only reduced by approximately 43%. At certain latitudes, diffuse UV under shade may play an important role in providing the human body with adequate levels of UVD3 (290-330 nm) radiation without experiencing the high levels of damaging UVA observed in full sun.

Utilising shade to optimize UV exposure for vitamin D

NASA Astrophysics Data System (ADS)

Turnbull, D. J.; Parisi, A. V.

2008-06-01

Numerous studies have stated that humans need to utilise full sun radiation, at certain times of the day, to assist the body in synthesising the required levels of vitamin D3. The time needed to be spent in the full sun depends on a number of factors, for example, age, skin type, latitude, solar zenith angle. Current Australian guidelines suggest exposure to approximately 1/6 to 1/3 of a minimum erythemal dose (MED), depending on age, would be appropriate to provide adequate vitamin D3 levels. The aim of the study was to determine the exposure times to diffuse solar UV to receive exposures of 1/6 and 1/3 MED for a changing solar zenith angle in order to assess the possible role that diffuse UV (scattered radiation) may play in vitamin D3 effective UV exposures (UVD3). Diffuse and global erythemal UV measurements were conducted at five minute intervals over a twelve month period for a solar zenith angle range of 4° to 80° at a latitude of 27.6° S. For a diffuse UV exposure of 1/3 MED, solar zenith angles smaller than approximately 50° can be utilised for exposure times of less than 10 min. Spectral measurements showed that, for a solar zenith angle of 40°, the UVA (315-400 nm) in the diffuse component of the solar UV is reduced by approximately 62% compared to the UVA in the global UV, whereas UVD3 wavelengths are only reduced by approximately 43%. At certain latitudes, diffuse UV under shade may play an important role in providing the human body with adequate levels of UVD3 (290-315 nm) radiation without experiencing the high levels of UVA observed in full sun.

Enhancement of Si solar cell efficiency using ZnO nanowires with various diameters

NASA Astrophysics Data System (ADS)

Gholizadeh, A.; Reyhani, A.; Parvin, P.; Mortazavi, S. Z.; Mehrabi, M.

2018-01-01

Here, Zinc Oxide nanowires are synthesized using thermal chemical vapor deposition of a Zn granulate source and used to enhance a significant Si-solar cell efficiency with simple and low cost method. The nanowires are grown in various O2 flow rates. Those affect the shape, yield, structure and the quality of ZnO nanowires according to scanning electron microscopy and x-ray diffraction analyses. This delineates that the ZnO nanostructure is dependent on the synthesis conditions. The photoluminescence spectroscopy of ZnO indicates optical emission at the Ultra-Violet and blue-green regions whose intensity varies as a function of diameter of ZnO nano-wires. The optical property of ZnO layer is measured by UV-visible and diffuse reflection spectroscopy that demonstrate high absorbance at 280-550 nm. Furthermore, the photovoltaic characterization of ZnO nanowires is investigated based on the drop casting on Si-solar cell. The ZnO nanowires with various diameters demonstrate different effects on the efficiency of Si-solar cells. We have shown that the reduction of the spectral reflectance and down-shifting process as well as the reduction of photon trapping are essential parameters on the efficiency of Si-solar cells. However, the latter is dominated here. In fact, the trapped photons during the electron-hole generation are dominant due to lessening the absorption rate in ZnO nano-wires. The results indicate that the mean diameters reduction of ZnO nanowires is also essential to improve the fill factor. The external and internal quantum efficiency analyses attest the efficiency improvement over the blue region which is related to the key parameters above.

Thermally stable and high reflectivity Al-doped silver thin films deposited by magnetron sputtering

NASA Astrophysics Data System (ADS)

Loka, Chadrasekhar; Lee, Kwang; Joo, Sin Yong; Lee, Kee-Sun

2018-03-01

Thermally stable, high reflectance thin film coatings are indispensable in optoelectronic devices, especially as a potential back reflector for LEDs and solar cells. The silver has the drawback of agglomerating easily and poor thermal stability, which is limiting its application as a highly reflective coating in various optoelectronic applications. In this study, improved thermal stability by modification of the Ag film into an Ag/Al-doped Ag structure has been confirmed. In this paper, the surface morphology, optical reflectance, and thermal stability of the Ag/Al-doped Ag are investigated. The Ag/Al-doped Ag/sapphire films showed excellent thermal stability after annealing the films at 523 K with the highest reflectance about ∼86% as compared to the pure Ag films. The grain growth analysis results revealed that the Al-doping is effective to restrain the severe grain growth of silver films. The Auger electron spectroscopy results revealed that the outer diffusion of aluminum and the formation of Al-O bond at the outermost silver layer which is beneficial to retard the Ag grain growth.

Photometric Lambert Correction for Global Mosaicking of HRSC Data

NASA Astrophysics Data System (ADS)

Walter, Sebastian; Michael, Greg; van Gasselt, Stephan; Kneissl, Thomas

2015-04-01

The High Resolution Stereo Camera (HRSC) is a push-broom image sensor onboard Mars Express recording the Martian surface in 3D and color. Being in orbit since 2004, the camera has obtained over 3,600 panchromatic image sequences covering about 70% of the planet's surface at 10-20 m/pixel. The composition of an homogenous global mosaic is a major challenge due to the strong elliptical and highly irregular orbit of the spacecraft, which often results in large variations of illumination and atmospheric conditions between individual images. For the purpose of a global mosaic in the full Nadir resolution of 12.5 m per pixel we present a first-order systematic photometric correction for the individual image sequences based on a Lambertian reflection model. During the radiometric calibration of the HRSC data, values for the reflectance scaling factor and the reflectance offset are added to the individual image labels. These parameters can be used for a linear transformation from the original DN values into spectral reflectance values. The spectral reflectance varies with the solar incidence angle, topography (changing the local incidence angle and therefore adding an exta geometry factor for each ground pixel), the bi-directional reflectance distribution function (BRDF) of the surface, and atmospheric effects. Mosaicking the spectral values together as images sometimes shows large brightness differences. One major contributor to the brightness differences between two images is the differing solar geometry due to the varying time of day when the individual images were obtained. This variation causes two images of the same or adjacent areas to have different image brightnesses. As a first-order correction for the varying illumination conditions and resulting brightness variations, the images are corrected for the solar incidence angle by assuming an ideal diffusely reflecting behaviour of the surface. This correction requires the calculation of the solar geometry for each image pixel by an image-to-ground function. For the calculations we are using the VICAR framework and the SPICE library. Under the Lambertian assumption, the reflectance diminishment resulting from an inclined Sun angle can be corrected by dividing the measured reflectance by the cosine of the illumination angle. After rectification of the corrected images, the individual images are mosaicked together. The overall visual impression shows a much better integration of the individual image sequences. The correction resolves the direct correlation between the reflectance and the incidence angles from the data. It does not account for topographic, atmospheric or BRDF influences to the measurements. Since the main purpose of the global HRSC image mosaic is the application for geomorphologic studies with a good visual impression of the albedo variations and the topography, the remaining distortions at the image seams can be equalized by non-reversible image matching techniques.

Incorporating photon recycling into the analytical drift-diffusion model of high efficiency solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lumb, Matthew P.; Naval Research Laboratory, Washington, DC 20375; Steiner, Myles A.

The analytical drift-diffusion formalism is able to accurately simulate a wide range of solar cell architectures and was recently extended to include those with back surface reflectors. However, as solar cells approach the limits of material quality, photon recycling effects become increasingly important in predicting the behavior of these cells. In particular, the minority carrier diffusion length is significantly affected by the photon recycling, with consequences for the solar cell performance. In this paper, we outline an approach to account for photon recycling in the analytical Hovel model and compare analytical model predictions to GaAs-based experimental devices operating close tomore » the fundamental efficiency limit.« less

A New Approach for Spectroradiometric Calibration Consistency on the Ground and in Space

NASA Technical Reports Server (NTRS)

Heath, Donald F.; Geprgoev. Geprgo

2013-01-01

A Space-based Calibration Transfer Spectroradiometer (SCATS) is combined with a ground calibration spectral albedo radiometric standard which consists of an opaque quartz glass Mie scattering diffuser (MSD) which has very good Lambertian scattering properties in both reflectance and transmittance modes. This system provides the capability for determining long term changes in the spectral albedo calibrations which operate in the solar reflective wavelength region. The spectral albedo calibration would be traceable to the SIRCUS and STARR NIST calibration facilities. The on-orbit radiometric standard is the Sun. The NIST traceable ground spectral albedo calibration is invariant between the ground and on-orbit over the instrument lifetime due to the use of a field of view defining mechanical baffle to differentiate between radiance and irradiance.

CRADA with United Solar Technologies and Pacific Northwest Laboratory (PNL-021): Thin film materialsfor low-cost high performance solar concentrators

NASA Astrophysics Data System (ADS)

Martin, P. M.; Affinito, J. D.; Gross, M. E.; Bennett, W. D.

1995-03-01

The objectives of this project were to develop and evaluate promising low-cost dielectric and polymer-protected thin-film reflective metal coatings to be applied to preformed continuously-curved solar reflector panels to enhance their solar reflectance, and to demonstrate protected solar reflective coatings on preformed solar concentrator panels. The opportunity for this project arose from a search by United Solar Technologies (UST) for organizations and facilities capable of applying reflective coatings to large preformed panels. PNL was identified as being uniquely qualified to participate in this collaborative project.

High Aspect Ratio Semiconductor Heterojunction Solar Cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Redwing, Joan; Mallouk, Tom; Mayer, Theresa

2013-05-17

The project focused on the development of high aspect ratio silicon heterojunction (HARSH) solar cells. The solar cells developed in this study consisted of high density vertical arrays of radial junction silicon microwires/pillars formed on Si substrates. Prior studies have demonstrated that vertical Si wire/pillar arrays enable reduced reflectivity and improved light trapping characteristics compared to planar solar cells. In addition, the radial junction structure offers the possibility of increased carrier collection in solar cells fabricated using material with short carrier diffusion lengths. However, the high junction and surface area of radial junction Si wire/pillar array devices can be problematicmore » and lead to increased diode leakage and enhanced surface recombination. This study investigated the use of amorphous hydrogenated Si in the form of a heterojunction-intrinsic-thin layer (HIT) structure as a junction formation method for these devices. The HIT layer structure has widely been employed to reduce surface recombination in planar crystalline Si solar cells. Consequently, it was anticipated that it would also provide significant benefits to the performance of radial junction Si wire/pillar array devices. The overall goals of the project were to demonstrate a HARSH cell with a HIT-type structure in the radial junction Si wire/pillar array configuration and to develop potentially low cost pathways to fabricate these devices. Our studies demonstrated that the HIT structure lead to significant improvements in the open circuit voltage (V oc>0.5) of radial junction Si pillar array devices compared to devices fabricated using junctions formed by thermal diffusion or low pressure chemical vapor deposition (LPCVD). In addition, our work experimentally demonstrated that the radial junction structure lead to improvements in efficiency compared to comparable planar devices for devices fabricated using heavily doped Si that had reduced carrier diffusion lengths. Furthermore, we made significant advances in employing the bottom-up vapor-liquid-solid (VLS) growth technique for the fabrication of the Si wire arrays. Our work elucidated the effects of growth conditions and substrate pattern geometry on the growth of large area Si microwire arrays grown with SiCl4. In addition, we also developed a process to grow p-type Si nanowire arrays using aluminum as the catalyst metal instead of gold. Finally, our work demonstrated the feasibility of growing vertical arrays of Si wires on non-crystalline glass substrates using polycrystalline Si template layers. The accomplishments demonstrated in this project will pave the way for future advances in radial junction wire array solar cells.« less

VIIRS reflective solar bands on-orbit calibration five-year update: extension and improvements

NASA Astrophysics Data System (ADS)

Sun, Junqiang; Wang, Menghua

2016-09-01

The Suomi National Polar-orbiting Partnership (SNPP) Visible Infrared Imaging Radiometer Suite (VIIRS) has been onorbit for almost five years. VIIRS has 22 spectral bands, among which fourteen are reflective solar bands (RSB) covering a spectral range from 0.410 to 2.25 μm. The SNPP VIIRS RSB have performed very well since launch. The radiometric calibration for the RSB has also reached a mature stage after almost five years since its launch. Numerous improvements have been made in the standard RSB calibration methodology. Additionally, a hybrid calibration method, which takes the advantages of both solar diffuser calibration and lunar calibration and avoids the drawbacks of the two methods, successfully finalizes the highly accurate calibration for VIIRS RSB. The successfully calibrated RSB data record significantly impacts the ocean color products, whose stringent requirements are especially sensitive to calibration accuracy, and helps the ocean color products to reach maturity and high quality. Nevertheless, there are still many challenge issues to be investigated for further improvements of the VIIRS sensor data records (SDR). In this presentation, the robust results of the RSB calibrations and the ocean product performance will be presented. The reprocessed SDR is now in more science tests, in addition to the ocean science tests already completed one year ago, readying to be the mission-long operational SDR.

Suomi NPP VIIRS Striping Analysis using Radiative Transfer Model Calculations

NASA Astrophysics Data System (ADS)

Wang, Z.; Cao, C.

2015-12-01

Modern satellite radiometers such as VIIRS have many detectors with slightly different relative spectral response (RSR). These differences can introduce artifacts such as striping in the imagery. In recent studies we have analyzed the striping pattern related to the detector level RSR difference in VIIRS Thermal Emissive Bands (TEB) M15 and M16, which includes line-by-line radiative transfer model (LBLRTM) detector level response study and onboard detector stability evaluation using the solar diffuser. Now we extend these analysis to the Reflective Solar Bands (RSB) using MODTRAN atmospheric radiative transfer model (RTM) for detector level radiance simulation. Previous studies analyzed the striping pattern in the images of VIIRS ocean color and reflectance in RSB, further studies about the root cause for striping are still needed. In this study, we will use the MODTRAN model at spectral resolution of 1 cm^-1 under different atmospheric conditions for VIIRS RSB, for example band M1 centered at 410nm which is used for Ocean Color product retrieval. The impact of detector level RSR difference, atmospheric dependency, and solar geometry on the striping in VIIRS SDR imagery will be investigated. The cumulative histogram method used successfully for the TEB striping analysis will be used to quantify the striping. These analysis help S-NPP and J1 to better understand the root cause for VIIRS image artifacts and reduce the uncertainties in geophysical retrievals to meet the user needs.

Solar energy distribution over Egypt using cloudiness from Meteosat photos

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mosalam Shaltout, M.A.; Hassen, A.H.

1990-01-01

In Egypt, there are 10 ground stations for measuring the global solar radiation, and five stations for measuring the diffuse solar radiation. Every day at noon, the Meteorological Authority in Cairo receives three photographs of cloudiness over Egypt from the Meteosat satellite, one in the visible, and two in the infra-red bands (10.5-12.5 {mu}m) and (5.7-7.1 {mu}m). The monthly average cloudiness for 24 sites over Egypt are measured and calculated from Meteosat observations during the period 1985-1986. Correlation analysis between the cloudiness observed by Meteosat and global solar radiation measured from the ground stations is carried out. It is foundmore » that, the correlation coefficients are about 0.90 for the simple linear regression, and increase for the second and third degree regressions. Also, the correlation coefficients for the cloudiness with the diffuse solar radiation are about 0.80 for the simple linear regression, and increase for the second and third degree regression. Models and empirical relations for estimating the global and diffuse solar radiation from Meteosat cloudiness data over Egypt are deduced and tested. Seasonal maps for the global and diffuse radiation over Egypt are carried out.« less

Research on gallium arsenide diffused junction solar cells

NASA Technical Reports Server (NTRS)

Borrego, J. M.; Ghandi, S. K.

1984-01-01

The feasibility of using bulk GaAs for the fabrication of diffused junction solar cells was determined. The effects of thermal processing of GaAs was studied, and the quality of starting bulk GaAs for this purpose was assessed. These cells are to be made by open tube diffusion techniques, and are to be tested for photovoltaic response under AMO conditions.

MODIS In-flight Calibration Methodologies

NASA Technical Reports Server (NTRS)

Xiong, X.; Barnes, W.

2004-01-01

MODIS is a key instrument for the NASA's Earth Observing System (EOS) currently operating on the Terra spacecraft launched in December 1999 and Aqua spacecraft launched in May 2002. It is a cross-track scanning radiometer, making measurements over a wide field of view in 36 spectral bands with wavelengths from 0.41 to 14.5 micrometers and providing calibrated data products for science and research communities in their studies of the Earth s system of land, oceans, and atmosphere. A complete suite of on-board calibrators (OBC) have been designed for the instruments in-flight calibration and characterization, including a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system for the radiometric calibration of the 20 reflective solar bands (RSB), a blackbody (BB) for the radiometric calibration of the 16 thermal emissive bands (TEB), and a spectro-radiometric calibration assembly (SRCA) for the spatial (all bands) and spectral (RSB only) characterization. This paper discusses MODIS in-flight Cali bration methodologies of using its on-board calibrators. Challenging issues and examples of tracking and correcting instrument on-orbit response changes are presented, including SD degradation (20% at 412nm, 12% at 466nm, and 7% at 530nm over four and a half years) and response versus scan angle changes (10%, 4%, and 1% differences between beginning of the scan and end of the scan at 412nm, 466nm, and 530nm) in the VIS spectral region. Current instrument performance and lessons learned are also provided.

Determination of the SNPP VIIRS SDSM Screen Relative Transmittance From Both Yaw Maneuver and Regular On-Orbit Data

NASA Technical Reports Server (NTRS)

Lei, Ning; Chen, Xuexia; Xiong, Xiaoxiong

2015-01-01

The Visible Infrared Imaging Radiometer Suiteaboard the Suomi National Polar-orbiting Partnership (SNPP) satellite performs radiometric calibration of its reflective solar bands primarily through observing a sunlit onboard solar diffuser (SD). The SD bidirectional reflectance distribution function(BRDF) degradation factor is determined by an onboard SD stability monitor (SDSM), which observes the Sun through a pinhole screen and the sunlit SD. The transmittance of the SDSM pinhole screen over a range of solar angles was determined prelaunch and used initially to determine the BRDF degradation factor.The degradation-factor-versus-time curves were found to have a number of very large unphysical undulations likely due to the inaccuracy in the prelaunch determined SDSM screen transmittance.To refine the SDSM screen transmittance, satellite yaw maneuvers were carried out. With the SDSM screen relative transmittance determined from the yaw maneuver data, the computed BRDFdegradation factor curves still have large unphysical ripples, indicating that the projected solar horizontal angular step size in the yaw maneuver data is too large to resolve the transmittance at a fine angular scale. We develop a methodology to use both the yaw maneuver and a small portion of regular on-orbit data to determine the SDSM screen relative transmittance at a fine angular scale. We determine that the error standard deviation of the calculated relative transmittance ranges from 0.00030 (672 nm) to 0.00092 (926 nm). With the newly determined SDSM screen relative transmittance, the computed BRDF degradation factor behaves much more smoothly over time.

Self-Referenced Method for Estimating Refractive Index and Absolute Absorption of Loose Semiconductor Powders

DOE PAGES

Huang, Huafeng; Colabello, Diane M.; Sklute, Elizabeth C.; ...

2017-04-23

The absolute absorption coefficient, α(E), is a critical design parameter for devices using semiconductors for light harvesting associated with renewable energy production, both for classic technologies such as photovoltaics and for emerging technologies such as direct solar fuel production. While α(E) is well-known for many classic simple semiconductors used in photovoltaic applications, the absolute values of α(E) are typically unknown for the complex semiconductors being explored for solar fuel production due to the absence of single crystals or crystalline epitaxial films that are needed for conventional methods of determining α(E). In this work, a simple self-referenced method for estimating bothmore » the refractive indices, n(E), and absolute absorption coefficients, α(E), for loose powder samples using diffuse reflectance data is demonstrated. In this method, the sample refractive index can be deduced by refining n to maximize the agreement between the relative absorption spectrum calculated from bidirectional reflectance data (calculated through a Hapke transform which depends on n) and integrating sphere diffuse reflectance data (calculated through a Kubleka–Munk transform which does not depend on n). This new method can be quickly used to screen the suitability of emerging semiconductor systems for light-harvesting applications. The effectiveness of this approach is tested using the simple classic semiconductors Ge and Fe 2O 3 as well as the complex semiconductors La 2MoO 5 and La 4Mo 2O 11. The method is shown to work well for powders with a narrow size distribution (exemplified by Fe 2O 3) and to be ineffective for semiconductors with a broad size distribution (exemplified by Ge). As such, it provides a means for rapidly estimating the absolute optical properties of complex solids which are only available as loose powders.« less

Diffuse reflectance relations based on diffusion dipole theory for large absorption and reduced scattering

NASA Astrophysics Data System (ADS)

Bremmer, Rolf H.; van Gemert, Martin J. C.; Faber, Dirk J.; van Leeuwen, Ton G.; Aalders, Maurice C. G.

2013-08-01

Diffuse reflectance spectra are used to determine the optical properties of biological samples. In medicine and forensic science, the turbid objects under study often possess large absorption and/or scattering properties. However, data analysis is frequently based on the diffusion approximation to the radiative transfer equation, implying that it is limited to tissues where the reduced scattering coefficient dominates over the absorption coefficient. Nevertheless, up to absorption coefficients of 20 m at reduced scattering coefficients of 1 and 11.5 mm-1, we observed excellent agreement (r2=0.994) between reflectance measurements of phantoms and the diffuse reflectance equation proposed by Zonios et al. [Appl. Opt. 38, 6628-6637 (1999)], derived as an approximation to one of the diffusion dipole equations of Farrell et al. [Med. Phys. 19, 879-888 (1992)]. However, two parameters were fitted to all phantom experiments, including strongly absorbing samples, implying that the reflectance equation differs from diffusion theory. Yet, the exact diffusion dipole approximation at high reduced scattering and absorption also showed agreement with the phantom measurements. The mathematical structure of the diffuse reflectance relation used, derived by Zonios et al. [Appl. Opt. 38, 6628-6637 (1999)], explains this observation. In conclusion, diffuse reflectance relations derived as an approximation to the diffusion dipole theory of Farrell et al. can analyze reflectance ratios accurately, even for much larger absorption than reduced scattering coefficients. This allows calibration of fiber-probe set-ups so that the object's diffuse reflectance can be related to its absorption even when large. These findings will greatly expand the application of diffuse reflection spectroscopy. In medicine, it may allow the use of blue/green wavelengths and measurements on whole blood, and in forensic science, it may allow inclusion of objects such as blood stains and cloth at crime scenes.

Radiation tolerance of low resistivity, high voltage silicon solar cells

NASA Technical Reports Server (NTRS)

Weizer, V. G.; Weinberg, I.; Swartz, C. K.

1984-01-01

The radiation tolerance of the following three low resistivity, high voltage silicon solar cells was investigated: (1) the COMSAT MSD (multi-step diffused) cell, (2) the MinMIS cell, and (3) the MIND cell. A description of these solar cells is given along with drawings of their configurations. The diffusion length damage coefficients for the cells were calculated and presented. Solar cell spectral response was also discussed. Cells of the MinMIS type were judged to be unsuitable for use in the space radiation environment.

The effect of diffusion induced lattice stress on the open-circuit voltage in silicon solar cells

NASA Technical Reports Server (NTRS)

Weizer, V. G.; Godlewski, M. P.

1984-01-01

It is demonstrated that diffusion induced stresses in low resistivity silicon solar cells can significantly reduce both the open-circuit voltage and collection efficiency. The degradation mechanism involves stress induced changes in both the minority carrier mobility and the diffusion length. Thermal recovery characteristics indicate that the stresses are relieved at higher temperatures by divacancy flow (silicon self diffusion). The level of residual stress in as-fabricated cells was found to be negligible in the cells tested.

On-orbit calibration of Visible Infrared Imaging Radiometer Suite reflective solar bands and its challenges using a solar diffuser.

PubMed

Sun, Junqiang; Wang, Menghua

2015-08-20

The reflective solar bands (RSBs) of the Visible Infrared Imaging Radiometer Suite (VIIRS) on board the Suomi National Polar-Orbiting Partnership satellite are calibrated by a solar diffuser (SD) panel whose performance is itself monitored by an accompanying solar diffuser stability monitor (SDSM). In this comprehensive work we describe the SD-based calibration algorithm of the RSBs, analyze the calibration data, and derive the performance results-the RSB calibration coefficients or F-factors-for the current three and a half years of mission. The application of the newly derived product of the SD bidirectional reflectance factor and the vignetting function for the SD screen and the newly derived SD degradation, so-called H-factors, effectively minimizes the artificial seasonal patterns in the RSB calibration coefficients due to the errors of these ingredient inputs. The full illumination region, the "sweet spot," during calibration events for SD view is carefully examined and selected to ensure high data quality and to reduce noise owing to non-fully illuminated samples. A time-dependent relative spectral response (RSR), coming from the large out-of-band contribution and the VIIRS optical system wavelength-dependent degradation, is derived from an iterative approach and applied in the SD calibration for each RSB. The result shows that VIIRS RSBs degrade much faster at near-infrared (NIR) and shortwave-infrared (SWIR) wavelength ranges due to the faster degradation of the rotating telescope assembly against the remaining part of the system. The gains of the VIIRS RSBs have degraded 2.0% (410 nm, Band M1), 0.2% (443 nm, Band M2), -0.3% (486 nm, Band M3), 0.2% (551 nm, Band M4), 6.2% (640 nm, Band I1), 11.0% (671 nm, Band M5), 21.3% (745 nm, Band M6), 35.8% (862 nm, Band I2), and 35.8% (862 nm, Band M7), respectively, since launch and 24.8% (1238 nm, Band M8), 18.5% (1378 nm, Band M9), 11.5% (1610 nm, Band I3), 11.5% (1610, Band M10), and 4.0% (2250 nm, Band M11), respectively, since 20 January 2012. It is established that the SD calibration accurately catches the on-orbit RSB degradation according to the instrument design and the calibration algorithm. However, due to the inherent nonuniform degradation of the SD affecting especially the short wavelength bands and the lack of capability of the SDSM calibration to catch degradation beyond 935 nm, the direct and the unmitigated application of the SD calibration result will introduce nonnegligible error into the calibration coefficients resulting in long-term drifts in the sensor data records and consequently the high-level products. We explicitly unveil the effect of the nonuniformity in SD degradation in the RSB calibration coefficients but also briefly discuss a critical yet simple mitigation to restore the accuracy of the calibration coefficients based on lunar observations. The methodology presented here thus remains intact as the cornerstone of the RSB calibration, and our derived RSB calibration coefficients represent the optimal result. This work has the most impact on the quality of the ocean color products that sensitively depend on the moderate visible and NIR bands (M1-M7), as well as the SWIR bands (M8, M10, and M11).

Solar receiver with integrated optics

NASA Astrophysics Data System (ADS)

Jiang, Lun; Winston, Roland

2012-10-01

The current challenge for PV/Thermal (PV/T) systems is the reduction of radiation heat loss. Compared to solar thermal selective coating, the solar cells cannot be used as an efficient thermal absorber due to their large emissivity of the encapsulation material. Many commercial PV/T products therefore require a high concentration (more than 10x) to reach an acceptable thermal efficiency for their receivers. Such a concentration system inevitably has to track or semi-track, which induces additional cost and collects only the direct radiation from the sun. We propose a new PV/T design using a vacuum encapsulated thin film cell to solve this problem. The proposed design also collects the diffuse sun light efficiently by using an external compound parabolic concentrator (XCPC). Since the transparent electrode (TCO) of thin film cell is inherently transparent in visible light and reflective beyond infrared, this design uses this layer instead of the conventional solar cell encapsulation as the outmost heat loss surface. By integrating such a vacuum design with a tube shaped absorber, we reduce the complexity of conducting the heat energy and electricity out of the device. A low concentration standalone non-tracking solar collector is proposed in this paper. We also analyzed the thermosyphon system configuration using heat transfer and ray tracing models. The economics of such a receiver are presented.

Centennial blooming of anoxygenic phototrophic bacteria in Qinghai Lake linked to solar and monsoon activities during the last 18,000 years

NASA Astrophysics Data System (ADS)

Ji, Junfeng; Balsam, William; Shen, Ji; Wang, Man; Wang, Hongtao; Chen, Jun

2009-06-01

The productivity of anoxygenic phototrophic bacteria (APB) can be inferred in the sediments of Qinghai Lake from the changing abundance of bacteriophaeophytin a (Bph- a). Using diffuse reflectance spectroscopy (DRS), we identified Bph- a in Qinghai Lake sediments from the late glacial period through the Holocene with a resolution of one sample every 30-50 years. The Bph- a profile of Qinghai Lake demonstrates that in the last 18,000 years APB were only present between 4.2 and 14 ka BP, a period of high rainfall and high summer solar insolation. All the APB blooming events correspond to times of enhanced freshwater influx as revealed by percent redness, an indicator of the input of iron oxide minerals. Our data suggest that solar insolation sets the stage for APB blooms, which are then promoted by increased summer monsoon rainfall and nutrients resulting in the development of a chemocline in the lake. The blooming of APB in Qinghai Lake appears as discrete centennial-scale APB events likely linked to solar activities. Our results suggest the presence of solar-induced, century-long, intense summer monsoon episodes in the middle and early Holocene and the late glacial period.

Microstructure and thermal stability of Cu/Zr0.3Al0.7N/Zr0.2Al0.8N/Al34O60N6 cermet-based solar selective absorbing coatings

NASA Astrophysics Data System (ADS)

Meng, Jian-ping; Guo, Rui-rui; Li, Hu; Zhao, Lu-ming; Liu, Xiao-peng; Li, Zhou

2018-05-01

Solar selective absorbing coatings play a valuable role in photo-thermal conversion for high efficiency concentrating solar power systems (CSP). In this paper, a novel Cu/Zr0.3Al0.7N/Zr0.2Al0.8N/Al34O60N6 cermet-based solar selective absorbing coating was successfully deposited by ion beam assisted deposition. The optical properties, microstructure and element distribution in depth were investigated by spectroscopic ellipsometry, UV-vis-NIR spectrophotometer, transmission electron microscope (TEM) and Auger electron spectroscopy (AES), respectively. A high absorptance of 0.953 and a low thermal emittance of 0.079 at 400 °C are obtained by the integral computation according to the whole reflectance from 300 nm to 28,800 nm. After annealing treatment at 400 °C (in vacuum) for 192 h, the deposited coating exhibits the high thermal stability. Whereas, the photothermal conversion efficiency decreases from 12.10 to 6.86 due to the emittance increase after annealing at 600 °C for 192 h. Meanwhile, the nitrogen atom in the Zr0.3Al0.7N sub-layer diffuses toward the adjacent sub-layer due to the spinodal decomposition of metastable c-ZrAlN and the phase transition from c-AlN to h-AlN, which leads to the composition of the Zr0.3Al0.7N sub-layer deviates the initial design. This phenomenon has a guide effect for the thermal-stability improvement of cermet coatings. Additionally, a serious diffusion between copper and silicon substrate also contributes to the emittance increase.

Separation of Electric Fields Into Potential and Inductive Parts, and Implications for Radial Diffusion

NASA Astrophysics Data System (ADS)

Chan, A. A.; Ilie, R.; Elkington, S. R.; Albert, J.; Huie, W.

2017-12-01

It has been traditional to separate radiation belt radial-diffusion coefficients into two contributions: an "electrostatic" diffusion coefficient, which is assumed to be due to a potential (non-inductive) electric field, and an "electromagnetic" diffusion coefficient , which is assumed to be due to the combined effect of an inductive electric field and the corresponding time-dependent magnetic field. One difficulty in implementing this separation when using magnetospheric fields obtained from measurements, or from MHD simulations, is that only the total electric field is given; the separation of the electric field into potential and inductive parts is not readily available. In this work we separate the electric field using a numerical method based on the Helmholtz decomposition of the total motional electric field calculated by the BATS-R-US MHD code. The inner boundary for the electric potential is based on the Ridley Ionospheric Model solution and we assume floating boundary conditions in the solar wind. Using different idealized solar wind drivers, including a solar wind density that is oscillating at a single frequency or with a broad spectrum of frequencies, we calculate potential and inductive electric fields, electric and magnetic power spectral densities, and corresponding radial diffusion coefficients. Simulations driven by idealized solar wind conditions show a clear separation of the potential and inductive contributions to the power spectral densities and diffusion coefficients. Simulations with more realistic solar wind drivers are underway to better assess the use of electrostatic and electromagnetic diffusion coefficients in understanding ULF wave-particle interactions in Earth's radiation belts.

Using Microporous Polytetrafluoroethylene Thin Sheets as a Flexible Solar Diffuser to Minimize Sunlight Glint to Cameras in Space

NASA Technical Reports Server (NTRS)

Choi, Michael K.

2016-01-01

An innovative design of using microporous PTFE thin sheets as a solar diffuser for MLI blankets or mechanical structure has been developed. It minimizes sunlight or stray-light glint to cameras when it is incident on these components in space. A microporous black PTFE thin sheet solar diffuser has been qualified for flight at NASA GSFC and installed to the TAGSAM arm MLI, OCAMS PolyCam sunshade MLI and SamCam motor riser MLI in the NASA OSIRIS-REx mission to meet the SamCam camera BRDF requirement.

Using microporous polytetrafluoroethylene thin sheets as a flexible solar diffuser to minimize sunlight glint to cameras in space

NASA Astrophysics Data System (ADS)

Choi, Michael K.

2016-09-01

An innovative design of using microporous PTFE thin sheets as a solar diffuser for MLI blankets or mechanical structure has been developed. It minimizes sunlight or stray-light glint to cameras when it is incident on these components in space. A microporous black PTFE thin sheet solar diffuser has been qualified for flight at NASA GSFC and installed to the TAGSAM arm MLI, OCAMS PolyCam sunshade MLI and SamCam motor riser MLI in the NASA OSIRIS-REx mission to meet the SamCam camera BRDF requirement.

Measurement and Modeling of the Optical Scattering Properties of Crop Canopies

NASA Technical Reports Server (NTRS)

Vanderbilt, V. C. (Principal Investigator)

1985-01-01

The specular reflection process is shown to be a key aspect of radiation transfer by plant canopies. Polarization measurements are demonstrated as the tool for determining the specular and diffuse portions of the canopy radiance. The magnitude of the specular fraction of the reflectance is significant compared to the magnitude of the diffuse fraction. Therefore, it is necessary to consider specularly reflected light in developing and evaluating light-canopy interaction models for wheat canopies. Models which assume leaves are diffuse reflectors correctly predict only the diffuse fraction of the canopy reflectance factor. The specular reflectance model, when coupled with a diffuse leaf model, would predict both the specular and diffuse portions of the reflectance factor. The specular model predicts and the data analysis confirms that the single variable, angle of incidence of specularly reflected sunlight on the leaf, explains much of variation in the polarization data as a function of view-illumination directions.

Consequences of using nonlinear particle trajectories to compute spatial diffusion coefficients. [for cosmic ray propagation in interstellar and interplanetary space

NASA Technical Reports Server (NTRS)

Goldstein, M. L.

1977-01-01

In a study of cosmic ray propagation in interstellar and interplanetary space, a perturbed orbit resonant scattering theory for pitch angle diffusion in a slab model of magnetostatic turbulence is slightly generalized and used to compute the diffusion coefficient for spatial propagation parallel to the mean magnetic field. This diffusion coefficient has been useful for describing the solar modulation of the galactic cosmic rays, and for explaining the diffusive phase in solar flares in which the initial anisotropy of the particle distribution decays to isotropy.

Magnetic Turbulence, Fast Magnetic Field line Diffusion and Small Magnetic Structures in the Solar Wind

NASA Astrophysics Data System (ADS)

Zimbardo, G.; Pommois, P.; Veltri, P.

2003-09-01

The influence of magnetic turbulence on magnetic field line diffusion has been known since the early days of space and plasma physics. However, the importance of ``stochastic diffusion'' for energetic particles has been challenged on the basis of the fact that sharp gradients of either energetic particles or ion composition are often observed in the solar wind. Here we show that fast transverse field line and particle diffusion can coexist with small magnetic structures, sharp gradients, and with long lived magnetic flux tubes. We show, by means of a numerical realization of three dimensional magnetic turbulence and by use of the concepts of deterministic chaos and turbulent transport, that turbulent diffusion is different from Gaussian diffusion, and that transport can be inhomogeneous even if turbulence homogeneously fills the heliosphere. Several diagnostics of field line transport and flux tube evolution are shown, and the size of small magnetic structures in the solar wind, like gradient scales and flux tube thickness, are estimated and compared to the observations.

An improved method to estimate reflectance parameters for high dynamic range imaging

NASA Astrophysics Data System (ADS)

Li, Shiying; Deguchi, Koichiro; Li, Renfa; Manabe, Yoshitsugu; Chihara, Kunihiro

2008-01-01

Two methods are described to accurately estimate diffuse and specular reflectance parameters for colors, gloss intensity and surface roughness, over the dynamic range of the camera used to capture input images. Neither method needs to segment color areas on an image, or to reconstruct a high dynamic range (HDR) image. The second method improves on the first, bypassing the requirement for specific separation of diffuse and specular reflection components. For the latter method, diffuse and specular reflectance parameters are estimated separately, using the least squares method. Reflection values are initially assumed to be diffuse-only reflection components, and are subjected to the least squares method to estimate diffuse reflectance parameters. Specular reflection components, obtained by subtracting the computed diffuse reflection components from reflection values, are then subjected to a logarithmically transformed equation of the Torrance-Sparrow reflection model, and specular reflectance parameters for gloss intensity and surface roughness are finally estimated using the least squares method. Experiments were carried out using both methods, with simulation data at different saturation levels, generated according to the Lambert and Torrance-Sparrow reflection models, and the second method, with spectral images captured by an imaging spectrograph and a moving light source. Our results show that the second method can estimate the diffuse and specular reflectance parameters for colors, gloss intensity and surface roughness more accurately and faster than the first one, so that colors and gloss can be reproduced more efficiently for HDR imaging.

High-Performance Dye-Sensitized Solar Cells Based on Morphology-Controllable Synthesis of ZnO–ZnS Heterostructure Nanocone Photoanodes

PubMed Central

Rouhi, Jalal; Mamat, Mohamad Hafiz; Ooi, C. H. Raymond; Mahmud, Shahrom; Mahmood, Mohamad Rusop

2015-01-01

High-density and well-aligned ZnO–ZnS core–shell nanocone arrays were synthesized on fluorine-doped tin oxide glass substrate using a facile and cost-effective two-step approach. In this synthetic process, the ZnO nanocones act as the template and provide Zn2+ ions for the ZnS shell formation. The photoluminescence spectrum indicates remarkably enhanced luminescence intensity and a small redshift in the UV region, which can be associated with the strain caused by the lattice mismatch between ZnO and ZnS. The obtained diffuse reflectance spectra show that the nanocone-based heterostructure reduces the light reflection in a broad spectral range and is much more effective than the bare ZnO nanocone and nanorod structures. Dye-sensitized solar cells based on the heterostructure ZnO–ZnS nanocones are assembled, and high conversion efficiency (η) of approximately 4.07% is obtained. The η improvement can be attributed primarily to the morphology effect of ZnO nanocones on light-trapping and effectively passivating the interface surface recombination sites of ZnO nanocones by coating with a ZnS shell layer. PMID:25875377

Diffusion lengths of silicon solar cells from luminescence images

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wuerfel, P.; Trupke, T.; Puzzer, T.

A method for spatially resolved measurement of the minority carrier diffusion length in silicon wafers and in silicon solar cells is introduced. The method, which is based on measuring the ratio of two luminescence images taken with two different spectral filters, is applicable, in principle, to both photoluminescence and electroluminescence measurements and is demonstrated experimentally by electroluminescence measurements on a multicrystalline silicon solar cell. Good agreement is observed with the diffusion length distribution obtained from a spectrally resolved light beam induced current map. In contrast to the determination of diffusion lengths from one single luminescence image, the method proposed heremore » gives absolute values of the diffusion length and, in comparison, it is much less sensitive to lateral voltage variations across the cell area as caused by local variations of the series resistance. It is also shown that measuring the ratio of two luminescence images allows distinguishing shunts or surface defects from bulk defects.« less

Coding metasurface for broadband microwave scattering reduction with optical transparency.

PubMed

Chen, Ke; Cui, Li; Feng, Yijun; Zhao, Junming; Jiang, Tian; Zhu, Bo

2017-03-06

Metasurfaces have promised great possibilities in full control of the electromagnetic wavefront by spatially manipulating the phase characteristics across the interface. Here, we report a scheme to realize broadband backward scattering reduction through diffusion-like microwave reflection by utilizing a flexible indium-tin-oxide (ITO)-based ultrathin coding metasurface (less than 0.1 wavelength thick) with high optical transparence. The diffusion-like scattering is caused by the destructive interference of the scattered far-field electromagnetic wave, which is further attributed to the randomly distributed reflection phases on the metasurface composed of pre-designed meta-atoms arranged with a computer-generated pseudorandom coding sequence. Both simulation and measurement on fabricated prototype sample have been carried out to validate its performance, demonstrating a polarization-independent broadband (nearly from 8 GHz to 15 GHz) 10 dB scattering reduction with good oblique performance. The excellent performances can also be preserved to conformal cases when the flexible metasurface is uniformly wrapped around a metallic cylinder. The proposed metasurface may create new opportunities to tailor the exotic microwave scattering features with simultaneously high transmittance in visible frequencies, which could provide crucial benefits in many practical uses, such as window and solar panel applications.

Crystal Structure, Magnetic and Optical Properties of Mn-Doped BiFeO₃ by Hydrothermal Synthesis.

PubMed

Zhang, Ning; Wei, Qinhua; Qin, Laishun; Chen, Da; Chen, Zhi; Niu, Feng; Wang, Jiangying; Huanag, Yuexiang

2017-01-01

In this paper, Mn doped BiFeO₃ were firstly synthesized by hydrothermal process. The influence of Mn doping on structural, optical and magnetic properties of BiFeO₃ was studied. The different amounts of Mn doping in BiFeO₃ were characterized by X-ray diffraction, Scanning Electron Microscope, Energy Dispersive X-ray Spectroscope, UV-Vis diffuse reflectance spectroscopy and magnetic measurements. The X-ray diffraction (XRD) patterns confirmed the formation of pure phase rhombohedral structure in BiFe(1−x) Mn (x) O₃ (x = 0.01, 0.03, 0.05, 0.07) samples. The morphologies and chemical compositions of as-prepared samples could be observed by Scanning Electron Microscope (SEM) and Energy Dispersive X-ray Spectroscope (EDS). A relative large saturated magnetization (Ms) of 0.53 emu/g for x = 0.07 sample was obtained at room temperature, which is considered to be Mn ions doping. UV-Vis diffuse reflectance spectroscopy showed strong absorption of light in the range of 200–1000 nm, indicating the optical band gap in the visible region for these samples. This implied that BiFe(1−x) Mn(x)O₃ may be a potential photocatalyst for utilizing solar energy.

A Babcock-Leighton Solar Dynamo Model with Multi-cellular Meridional Circulation in Advection- and Diffusion-dominated Regimes

NASA Astrophysics Data System (ADS)

Belucz, Bernadett; Dikpati, Mausumi; Forgács-Dajka, Emese

2015-06-01

Babcock-Leighton type-solar dynamo models with single-celled meridional circulation are successful in reproducing many solar cycle features. Recent observations and theoretical models of meridional circulation do not indicate a single-celled flow pattern. We examine the role of complex multi-cellular circulation patterns in a Babcock-Leighton solar dynamo in advection- and diffusion-dominated regimes. We show from simulations that the presence of a weak, second, high-latitude reverse cell speeds up the cycle and slightly enhances the poleward branch in the butterfly diagram, whereas the presence of a second cell in depth reverses the tilt of the butterfly wing to an antisolar type. A butterfly diagram constructed from the middle of convection zone yields a solar-like pattern, but this may be difficult to realize in the Sun because of magnetic buoyancy effects. Each of the above cases behaves similarly in higher and lower magnetic diffusivity regimes. However, our dynamo with a meridional circulation containing four cells in latitude behaves distinctly differently in the two regimes, producing solar-like butterfly diagrams with fast cycles in the higher diffusivity regime, and complex branches in butterfly diagrams in the lower diffusivity regime. We also find that dynamo solutions for a four-celled pattern, two in radius and two in latitude, prefer to quickly relax to quadrupolar parity if the bottom flow speed is strong enough, of similar order of magnitude as the surface flow speed.

A BABCOCK–LEIGHTON SOLAR DYNAMO MODEL WITH MULTI-CELLULAR MERIDIONAL CIRCULATION IN ADVECTION- AND DIFFUSION-DOMINATED REGIMES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Belucz, Bernadett; Forgács-Dajka, Emese; Dikpati, Mausumi, E-mail: bbelucz@astro.elte.hu, E-mail: dikpati@ucar.edu

Babcock–Leighton type-solar dynamo models with single-celled meridional circulation are successful in reproducing many solar cycle features. Recent observations and theoretical models of meridional circulation do not indicate a single-celled flow pattern. We examine the role of complex multi-cellular circulation patterns in a Babcock–Leighton solar dynamo in advection- and diffusion-dominated regimes. We show from simulations that the presence of a weak, second, high-latitude reverse cell speeds up the cycle and slightly enhances the poleward branch in the butterfly diagram, whereas the presence of a second cell in depth reverses the tilt of the butterfly wing to an antisolar type. A butterflymore » diagram constructed from the middle of convection zone yields a solar-like pattern, but this may be difficult to realize in the Sun because of magnetic buoyancy effects. Each of the above cases behaves similarly in higher and lower magnetic diffusivity regimes. However, our dynamo with a meridional circulation containing four cells in latitude behaves distinctly differently in the two regimes, producing solar-like butterfly diagrams with fast cycles in the higher diffusivity regime, and complex branches in butterfly diagrams in the lower diffusivity regime. We also find that dynamo solutions for a four-celled pattern, two in radius and two in latitude, prefer to quickly relax to quadrupolar parity if the bottom flow speed is strong enough, of similar order of magnitude as the surface flow speed.« less

Understanding Coupling of Global and Diffuse Solar Radiation with Climatic Variability

NASA Astrophysics Data System (ADS)

Hamdan, Lubna

Global solar radiation data is very important for wide variety of applications and scientific studies. However, this data is not readily available because of the cost of measuring equipment and the tedious maintenance and calibration requirements. Wide variety of models have been introduced by researchers to estimate and/or predict the global solar radiations and its components (direct and diffuse radiation) using other readily obtainable atmospheric parameters. The goal of this research is to understand the coupling of global and diffuse solar radiation with climatic variability, by investigating the relationships between these radiations and atmospheric parameters. For this purpose, we applied multilinear regression analysis on the data of National Solar Radiation Database 1991--2010 Update. The analysis showed that the main atmospheric parameters that affect the amount of global radiation received on earth's surface are cloud cover and relative humidity. Global radiation correlates negatively with both variables. Linear models are excellent approximations for the relationship between atmospheric parameters and global radiation. A linear model with the predictors total cloud cover, relative humidity, and extraterrestrial radiation is able to explain around 98% of the variability in global radiation. For diffuse radiation, the analysis showed that the main atmospheric parameters that affect the amount received on earth's surface are cloud cover and aerosol optical depth. Diffuse radiation correlates positively with both variables. Linear models are very good approximations for the relationship between atmospheric parameters and diffuse radiation. A linear model with the predictors total cloud cover, aerosol optical depth, and extraterrestrial radiation is able to explain around 91% of the variability in diffuse radiation. Prediction analysis showed that the linear models we fitted were able to predict diffuse radiation with efficiency of test adjusted R2 values equal to 0.93, using the data of total cloud cover, aerosol optical depth, relative humidity and extraterrestrial radiation. However, for prediction purposes, using nonlinear terms or nonlinear models might enhance the prediction of diffuse radiation.

Low-high junction theory applied to solar cells

NASA Technical Reports Server (NTRS)

Godlewski, M. P.; Baraona, C. R.; Brandhorst, H. W., Jr.

1973-01-01

Recent use of alloying techniques for rear contact formation has yielded a new kind of silicon solar cell, the back surface field (BSF) cell, with abnormally high open circuit voltage and improved radiation resistance. Several analytical models for open circuit voltage based on the reverse saturation current are formulated to explain these observations. The zero SRV case of the conventional cell model, the drift field model, and the low-high junction (LHJ) model can predict the experimental trends. The LHJ model applies the theory of the low-high junction and is considered to reflect a more realistic view of cell fabrication. This model can predict the experimental trends observed for BSF cells. Detailed descriptions and derivations for the models are included. The correspondences between them are discussed. This modeling suggests that the meaning of minority carrier diffusion length measured in BSF cells be reexamined.

Evaluation of surface energy and radiation balance systems on the Konza Prairie

NASA Technical Reports Server (NTRS)

Fritschen, Leo J.

1987-01-01

Four Surface Energy and Radiation Balance Systems (SERBS) were installed and operated for two weeks in Kansas during July of 1986. Surface energy and radiation balances were investigated on six sites on the Konza Prairie about 3 km south of Manhattan, Kansas. Measurements were made to allow the computation of these radiation components: total solar and diffuse radiation, reflected solar radiation, net radiation, and longwave radiation upward and downward. Measurements were made to allow the computation of the sensible and latent heat fluxes by the Bowen ratio method using differential psychrometers on automatic exchange mechanisms. The report includes a description of the experimental sites, data acquisition systems and sensors, data acquisitions system operating instructions, and software used for data acquisition and analysis. In addition, data listings and plots of the energy balance components for all days and systems are given.

Pt deposited TiO2 catalyst fabricated by thermal decomposition of titanium complex for solar hydrogen production

NASA Astrophysics Data System (ADS)

Truong, Quang Duc; Le, Thanh Son; Ling, Yong-Chien

2014-12-01

C, N codoped TiO2 catalyst has been synthesized by thermal decomposition of a novel water-soluble titanium complex. The structure, morphology, and optical properties of the synthesized TiO2 catalyst were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectroscopy. The photocatalytic activity of the Pt deposited TiO2 catalysts synthesized at different temperatures was evaluated by means of hydrogen evolution reaction under both UV-vis and visible light irradiation. The investigation results reveal that the photocatalytic H2 evolution rate strongly depended on the crystalline grain size as well as specific surface area of the synthesized catalyst. Our studies successfully demonstrate a simple method for the synthesis of visible-light responsive Pt deposited TiO2 catalyst for solar hydrogen production.

On the Angular Variation of Solar Reflectance of Snow

NASA Technical Reports Server (NTRS)

Chang, A. T. C.; Choudhury, B. J.

1979-01-01

Spectral and integrated solar reflectance of nonhomogeneous snowpacks were derived assuming surface reflection of direct radiation and subsurface multiple scattering. For surface reflection, a bidirectional reflectance distribution function derived for an isotropic Gaussian faceted surface was considered and for subsurface multiple scattering, an approximate solution of the radiative transfer equation was studied. Solar radiation incident on the snowpack was decomposed into direct and atmospherically scattered radiation. Spectral attenuation coefficients of ozone, carbon dioxide, water vapor, aerosol and molecular scattering were included in the calculation of incident solar radiation. Illustrative numerical results were given for a case of North American winter atmospheric conditions. The calculated dependence of spectrally integrated directional reflectance (or albedo) on solar elevation was in qualitative agreement with available observations.

A comparative study of p(+)n and n(+)p InP solar cells made by a closed ampoule diffusion

NASA Technical Reports Server (NTRS)

Faur, M.; Faur, M.; Flood, D. J.; Weinberg, I.; Brinker, D. J.; Goradia, C.; Fatemi, N.; Goradia, M.; Thesling, W.

1991-01-01

The purpose was to demonstrate the possibility of fabricating thermally diffused p(+)n InP solar cells having high open-circuit voltage without sacrificing the short circuit current. The p(+)n junctions were formed by closed-ampoule diffusion of Cd through a 3 to 5 nm thick anodic or chemical phosphorus-rich oxide cap layer grown on n-InP:S Czochralski LEC grown substrates. For solar cells made by thermal diffusion the p(+)n configuration is expected to have a higher efficiency than the n(+)p configuration. It is predicted that the AM0, BOL efficiencies approaching 19 percent should be readily achieved providing that good ohmic front contacts could be realized on the p(+) emitters of thickness lower than 1 micron.

Low cost solar array project. Cell and module formation research area. Process research of non-CZ silicon material

NASA Technical Reports Server (NTRS)

1983-01-01

Liquid diffusion masks and liquid dopants to replace the more expensive CVD SiO2 mask and gaseous diffusion processes were investigated. Silicon pellets were prepared in the silicon shot tower; and solar cells were fabricated using web grown where the pellets were used as a replenishment material. Verification runs were made using the boron dopant and liquid diffusion mask materials. The average of cells produced in these runs was 13%. The relationship of sheet resistivity, temperature, gas flows, and gas composition for the diffusion of the P-8 liquid phosphorus solution was investigated. Solar cells processed from web grown from Si shot material were evaluated, and results qualified the use of the material produced in the shot tower for web furnace feed stock.

Angular distribution of diffuse reflectance from incoherent multiple scattering in turbid media.

PubMed

Gao, M; Huang, X; Yang, P; Kattawar, G W

2013-08-20

The angular distribution of diffuse reflection is elucidated with greater understanding by studying a homogeneous turbid medium. We modeled the medium as an infinite slab and studied the reflection dependence on the following three parameters: the incident direction, optical depth, and asymmetry factor. The diffuse reflection is produced by incoherent multiple scattering and is solved through radiative transfer theory. At large optical depths, the angular distribution of the diffuse reflection with small incident angles is similar to that of a Lambertian surface, but, with incident angles larger than 60°, the angular distributions have a prominent reflection peak around the specular reflection angle. These reflection peaks are found originating from the scattering within one transport mean free path in the top layer of the medium. The maximum reflection angles for different incident angles are analyzed and can characterize the structure of angular distributions for different asymmetry factors and optical depths. The properties of the angular distribution can be applied to more complex systems for a better understanding of diffuse reflection.

Thermal characteristics of the lunar surface layer.

NASA Technical Reports Server (NTRS)

Cremers, C. J.; Birkebak, R. C.; White, J. E.

1972-01-01

The thermophysical properties of the fines from the Apollo 12 landing site have been determined as a function of their relevant parameters. These properties include the thermal conductivity, thermal diffusivity, directional reflectance and emittance. The density used was the same as that observed from the returned core-tube samples and so should be close to the true density of the surface layer at the Apollo 12 site. The measured properties are used to calculate the diurnal temperature variation of the moon's surface as well as for several depths below the surface. The maximum surface of 389 K is obtained at lunar noon while the minimum temperature of 86.1 K is obtained at sunrise. It is shown that the most significant effects on temperature, as compared with previous calculations, are caused by using the directional reflectance which controls the amount of solar energy absorption during the day in place of a constant hemispherical reflectance. The results are compared with previous analyses and remote measurements.

SNPP VIIRS RSB Earth View Reflectance Uncertainty

NASA Technical Reports Server (NTRS)

Lei, Ning; Twedt, Kevin; McIntire, Jeff; Xiong, Xiaoxiong

2017-01-01

The Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi National Polar-orbiting Partnership (SNPP) satellite uses its 14 reflective solar bands to passively collect solar radiant energy reflected off the Earth. The Level 1 product is the geolocated and radiometrically calibrated top-of- the-atmosphere solar reflectance. The absolute radiometric uncertainty associated with this product includes contributions from the noise associated with measured detector digital counts and the radiometric calibration bias. Here, we provide a detailed algorithm for calculating the estimated standard deviation of the retrieved top-of-the-atmosphere spectral solar radiation reflectance.

A simple theory of back surface field /BSF/ solar cells

NASA Technical Reports Server (NTRS)

Von Roos, O.

1978-01-01

A theory of an n-p-p/+/ junction is developed, entirely based on Shockley's depletion layer approximation. Under the further assumption of uniform doping the electrical characteristics of solar cells as a function of all relevant parameters (cell thickness, diffusion lengths, etc.) can quickly be ascertained with a minimum of computer time. Two effects contribute to the superior performance of a BSF cell (n-p-p/+/ junction) as compared to an ordinary solar cell (n-p junction). The sharing of the applied voltage among the two junctions (the n-p and the p-p/+/ junction) decreases the dark current and the reflection of minority carriers by the builtin electron field of the p-p/+/ junction increases the short-circuit current. The theory predicts an increase in the open-circuit voltage (Voc) with a decrease in cell thickness. Although the short-circuit current decreases at the same time, the efficiency of the cell is virtually unaltered in going from a thickness of 200 microns to a thickness of 50 microns. The importance of this fact for space missions where large power-to-weight ratios are required is obvious.

Photovoltaic characteristics of natural light harvesting dye sensitized solar cells

NASA Astrophysics Data System (ADS)

Hafez, H. S.; Shenouda, S. S.; Fadel, M.

2018-03-01

In this work of research, anthocyanin as a natural dye obtained from raspberry fruits, was used and tested as a photon harvesting/electron donating dye in titanium dioxide nanoparticle-based DSSCs. A working photoelectrode made from TiO2 nanoparticles with an average particle size (10-40 nm) that is coated on Florine doped tin-oxide substrate, was prepared via a simple and low cost hydrothermal method. A detailed structural and morphological analysis of the TiO2 photoactive electrode was investigated by X-ray diffraction (XRD), diffuse reflectance spectrometer, transmission electron microscope (TEM) and scanning electron microscope (SEM). Complete photovoltaic characteristics including (current, voltage, outpower, and responsivity) of the natural anthocyanin based dye sensitized solar cell have been investigated under different illumination intensity ranging from 10 to 100 mW.cm- 2. The cell responsivity and efficiency of the fabricated solar cell under different illumination intensity were found to be in the range (R = 15.6-23.8 mA.W- 1 and η = 0.13-0.25) at AM = 1.5 conditions. This study is important for enhancing the future applications of the promising DSSC technology.

Solar Skylight

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adamson, J. C.

1984-01-31

A reflective shutter rotates within a skylight housing in such a fashion as to control solar energy thereby providing a combination of heating, lighting, and ventilation. The skylight housing has three faces: a glazed southern face, a glazed northern face, and an open downwardly oriented face to the interior of the structure. Counter-weighted pivot arms support the shutter at either end causing the center of rotation to pass through the center of gravity. The shutter has three basic positions: In the first position, during the winter day, the shutter closes off the northern face, allowing solar energy to enter directlymore » into the supporting structure providing heat gain and daylighting. In the second position, during the winter night, the shutter closes off the open face to the interior, providing insulation between the structure and the skylight housing. In the third position, during the non-heating season, the shutter closes off the southern face blocking unwanted heat gain but allowing diffuse northern light to penetrate for daylighting. In this last position, a means is provided for ventilating by natural convection. The apparatus can be operated either manually or by motor.« less

Solar skylight

DOEpatents

Adamson, James C.

1984-01-01

A reflective shutter rotates within a skylight housing in such a fashion as to control solar energy thereby providing a combination of heating, lighting, and ventilation. The skylight housing has three faces: a glazed southern face, a glazed northern face, and an open downwardly oriented face to the interior of the structure. Counter-weighted pivot arms support the shutter at either end causing the center of rotation to pass through the center of gravity. The shutter has three basic positions: In the first position, during the winter day, the shutter closes off the northern face, allowing solar energy to enter directly into the supporting structure providing heat gain and daylighting. In the second position, during the winter night, the shutter closes off the open face to the interior, providing insulation between the structure and the skylight housing. In the third position, during the non-heating season, the shutter closes off the southern face blocking unwanted heat gain but allowing diffuse northern light to penetrate for daylighting. In this last position, a means is provided for ventilating by natural convection. The apparatus can be operated either manually or by motor.

The silicon on dust substrate path to make solar cells directly from a gaseous feedstock

NASA Astrophysics Data System (ADS)

Serra, J M; Pinto, C R; Silva, J A; Brito, M C; Maia Alves, J; Vallêra, A M

2009-04-01

In this paper, we present a silicon on dust substrate (SDS) process, a new method for the growth of silicon ribbons. As a demonstration of the concept, we also present results on solar cells made of these new silicon ribbons. SDS ribbons were obtained directly from a gaseous feedstock by a fast CVD step using silane. The resulting self-supported intrinsic ribbons were microcrystalline and porous. To make these ribbon films suitable for photovoltaic applications, a novel recrystallization with an in situ doping step was developed. To this purpose, the ribbons were sprayed with boric acid and then recrystallized by float zone melting. Simple solar cells were prepared by employing: aluminium back contacts, Ti/Pd/Ag front grid contacts, with no anti-reflective coating, doping optimization, passivation or gettering. The 1-sun I-V characteristics of the cells were: Voc ~ 530 mV and Jsc ~ 24 mA cm-2. The minority carrier diffusion length obtained from a spectral response at long wavelengths gave values of Ln ~ 70 µm.

An assessment of silver copper sulfides for photovoltaic applications: theoretical and experimental insights† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6ta03376h Click here for additional data file. Click here for additional data file.

PubMed Central

Savory, Christopher N.; Ganose, Alex M.; Travis, Will; Atri, Ria S.; Palgrave, Robert G.

2016-01-01

As the worldwide demand for energy increases, low-cost solar cells are being looked to as a solution for the future. To attain this, non-toxic earth-abundant materials are crucial, however cell efficiencies for current materials are limited in many cases. In this article, we examine the two silver copper sulfides AgCuS and Ag3CuS2 as possible solar absorbers using hybrid density functional theory, diffuse reflectance spectroscopy, XPS and Hall effect measurements. We show that both compounds demonstrate promising electronic structures and band gaps for high theoretical efficiency solar cells, based on Shockley–Queisser limits. Detailed analysis of their optical properties, however, indicates that only AgCuS should be of interest for PV applications, with a high theoretical efficiency. From this, we also calculate the band alignment of AgCuS against various buffer layers to aid in future device construction. PMID:27774149

Optical design of ZnO-based antireflective layers for enhanced GaAs solar cell performance.

PubMed

Lee, Hye Jin; Lee, Jae Won; Kim, Hee Jun; Jung, Dae-Han; Lee, Ki-Suk; Kim, Sang Hyeon; Geum, Dae-myeong; Kim, Chang Zoo; Choi, Won Jun; Baik, Jeong Min

2016-01-28

A series of hierarchical ZnO-based antireflection coatings with different nanostructures (nanowires and nanosheets) is prepared hydrothermally, followed by means of RF sputtering of MgF2 layers for coaxial nanostructures. Structural analysis showed that both ZnO had a highly preferred orientation along the 〈0001〉 direction with a highly crystalline MgF2 shell coated uniformly. However, a small amount of Al was present in nanosheets, originating from Al diffusion from the Al seed layer, resulting in an increase of the optical bandgap. Compared with the nanosheet-based antireflection coatings, the nanowire-based ones exhibited a significantly lower reflectance (∼2%) in ultraviolet and visible light wavelength regions. In particular, they showed perfect light absorption at wavelength less than approximately 400 nm. However, a GaAs single junction solar cell with nanosheet-based antireflection coatings showed the largest enhancement (43.9%) in power conversion efficiency. These results show that the increase of the optical bandgap of the nanosheets by the incorporation of Al atoms allows more photons enter the active region of the solar cell, improving the performance.

Process research of non-cz silicon material. Low cost solar array project, cell and module formation research area

NASA Technical Reports Server (NTRS)

1982-01-01

Liquid diffusion masks and liquid applied dopants to replace the CVD Silox masking and gaseous diffusion operations specified for forming junctions in the Westinghouse baseline process sequence for producing solar cells from dendritic web silicon were investigated.

Battle Keeps Solar Energy in Receiver

NASA Technical Reports Server (NTRS)

Mcdougal, A. R.; Hale, R. R.

1982-01-01

Mirror structure in solar concentrator reduces heat loss by reflection and reradiation. Baffle reflects entering rays back and forth in solar-concentrator receiver until they reach heat exchanger. Similarly, infrared energy reradiated by heat exchanger is prevented from leaving receiver. Surfaces of baffle and inside wall of receiver are polished and highly reflective at solar and infrared wavelengths.

Periodic orbits of solar sail equipped with reflectance control device in Earth-Moon system

NASA Astrophysics Data System (ADS)

Yuan, Jianping; Gao, Chen; Zhang, Junhua

2018-02-01

In this paper, families of Lyapunov and halo orbits are presented with a solar sail equipped with a reflectance control device in the Earth-Moon system. System dynamical model is established considering solar sail acceleration, and four solar sail steering laws and two initial Sun-sail configurations are introduced. The initial natural periodic orbits with suitable periods are firstly identified. Subsequently, families of solar sail Lyapunov and halo orbits around the L1 and L2 points are designed with fixed solar sail characteristic acceleration and varying reflectivity rate and pitching angle by the combination of the modified differential correction method and continuation approach. The linear stabilities of solar sail periodic orbits are investigated, and a nonlinear sliding model controller is designed for station keeping. In addition, orbit transfer between the same family of solar sail orbits is investigated preliminarily to showcase reflectance control device solar sail maneuver capability.

Deriving Polarization Properties of Desert-Reflected Solar Spectra with PARASOL Data

NASA Technical Reports Server (NTRS)

Sun, Wenbo; Baize, Rosemary R.; Lukashin, Constantine

2015-01-01

Reflected solar radiation from desert is strongly polarized by sand particles. To date, there is no reliable desert surface reflection model to calculate desert reflection matrix. In this study, the PARASOL data are used to retrieve physical properties of desert. These physical properties are then used in the ADRTM to calculate polarization of desert-reflected light for the whole solar spectra.

Acquisition of a High Performance Computer Cluster for Materials Research and Education

DTIC Science & Technology

2015-04-17

separation in all-organic and hybrid organic- inorganic solar cells. The outcome of the project 1. REPORT DATE (DD-MM-YYYY) 4. TITLE AND SUBTITLE 13...diffusion and interfacial charge separation in all-organic and hybrid organic- inorganic solar cells. The outcome of the project is the development...simulations to predict charge carrier mobilities, exciton diffusion and interfacial charge separation in all- organic and hybrid organic- inorganic solar

Local effects of partly-cloudy skies on solar and emitted radiation

NASA Technical Reports Server (NTRS)

Whitney, D. A.; Venable, D. D.

1982-01-01

A computer automated data acquisition system for atmospheric emittance, and global solar, downwelled diffuse solar, and direct solar irradiances is discussed. Hourly-integrated global solar and atmospheric emitted radiances were measured continuously from February 1981 and hourly-integrated diffuse solar and direct solar irradiances were measured continuously from October 1981. One-minute integrated data are available for each of these components from February 1982. The results of the correlation of global insolation with fractional cloud cover for the first year's data set. A February data set, composed of one-minute integrated global insolation and direct solar irradiance, cloud cover fractions, meteorological data from nearby weather stations, and GOES East satellite radiometric data, was collected to test the theoretical model of satellite radiometric data correlation and develop the cloud dependence for the local measurement site.

Particle acceleration at shocks in the inner heliosphere

NASA Astrophysics Data System (ADS)

Parker, Linda Neergaard

This dissertation describes a study of particle acceleration at shocks via the diffusive shock acceleration mechanism. Results for particle acceleration at both quasi-parallel and quasi-perpendicular shocks are presented to address the question of whether there are sufficient particles in the solar wind thermal core, modeled as either a Maxwellian or kappa- distribution, to account for the observed accelerated spectrum. Results of accelerating the theoretical upstream distribution are compared to energetic observations at 1 AU. It is shown that the particle distribution in the solar wind thermal core is sufficient to explain the accelerated particle spectrum downstream of the shock, although the shape of the downstream distribution in some cases does not follow completely the theory of diffusive shock acceleration, indicating possible additional processes at work in the shock for these cases. Results show good to excellent agreement between the theoretical and observed spectral index for one third to one half of both quasi-parallel and quasi-perpendicular shocks studied herein. Coronal mass ejections occurring during periods of high solar activity surrounding solar maximum can produce shocks in excess of 3-8 shocks per day. During solar minimum, diffusive shock acceleration at shocks can generally be understood on the basis of single independent shocks and no other shock necessarily influences the diffusive shock acceleration mechanism. In this sense, diffusive shock acceleration during solar minimum may be regarded as Markovian. By contrast, diffusive shock acceleration of particles at periods of high solar activity (e.g. solar maximum) see frequent, closely spaced shocks that include the effects of particle acceleration at preceding and following shocks. Therefore, diffusive shock acceleration of particles at solar maximum cannot be modeled on the basis of diffusive shock acceleration as a single, independent shock and the process is essentially non-Markovian. A multiple shock model is developed based in part on the box model of (Protheroe and Stanev, 1998; Moraal and Axford, 1983; Ball and Kirk, 1992; Drury et al. 1999) that accelerates particles at multiple shocks and decompresses the particles between shocks via two methods. The first method of decompression is based on the that used by Melrose and Pope (1993), which adiabatically decompresses particles between shocks. The second method solves the cosmic ray transport equation and adiabatically decompresses between shocks and includes the loss of particles through convection and diffusion. The transport method allows for the inclusion of a temporal variability and thus allows for a more representative frequency distribution of shocks. The transport method of decompression and loss is used to accelerate particles at seventy-three shocks in a thirty day time period. Comparisons with observations taken at 1 AU during the same time period are encouraging as the model is able to reproduce the observed amplitude of the accelerated particles and in part the variability. This work provides the basis for developing more sophisticated models that can be applied to a suite of observations

A numerical model for charge transport and energy conversion of perovskite solar cells.

PubMed

Zhou, Yecheng; Gray-Weale, Angus

2016-02-14

Based on the continuity equations and Poisson's equation, we developed a numerical model for perovskite solar cells. Due to different working mechanisms, the model for perovskite solar cells differs from that of silicon solar cells and Dye Sensitized Solar Cells. The output voltage and current are calculated differently, and in a manner suited in particular to perovskite organohalides. We report a test of our equations against experiment with good agreement. Using this numerical model, it was found that performances of solar cells increase with charge carrier's lifetimes, mobilities and diffusion lengths. The open circuit voltage (Voc) of a solar cell is dependent on light intensities, and charge carrier lifetimes. Diffusion length and light intensity determine the saturated current (Jsc). Additionally, three possible guidelines for the design and fabrication of perovskite solar cells are suggested by our calculations. Lastly, we argue that concentrator perovskite solar cells are promising.

Automated test-site radiometer for vicarious calibration

NASA Astrophysics Data System (ADS)

Li, Xin; Yin, Ya-peng; Liu, En-chao; Zhang, Yan-na; Xun, Li-na; Wei, Wei; Zhang, Zhi-peng; Qiu, Gang-gang; Zhang, Quan; Zheng, Xiao-bing

2014-11-01

In order to realize unmanned vicarious calibration, Automated Test-site Radiometer (ATR) was developed for surface reflectance measurements. ATR samples the spectrum from 400nm-1600 nm with 8 interference filters coupled with silicon and InGaAs detectors. The field of view each channel is 10 ° with parallel optical axis. One SWIR channel lies in the center and the other seven VNIR channels are on the circle of 4.8cm diameters which guarantee each channel to view nearly the same section of ground. The optical head as a whole is temperature controlled utilizing a TE cooler for greater stability and lower noise. ATR is powered by a solar panel and transmit its data through a BDS (China's BeiDou Navigation Satellite System) terminator for long-term measurements without personnel in site. ATR deployed in Dunhuang test site with ground field about 30-cm-diameter area for multi-spectral reflectance measurements. Other instruments at the site include a Cimel sunphotometer and a diffuser-to-globe irradiance meter for atmosphere observations. The methodology for band-averaged reflectance retrieval and hyperspectral reflectance fitting process are described. Then the hyperspectral reflectance and atmospheric parameters are put into 6s code to predict TOA radiance which compare with MODIS radiance.

VizieR Online Data Catalog: Solar wind 3D magnetohydrodynamic simulation (Chhiber+, 2017)

NASA Astrophysics Data System (ADS)

Chhiber, R.; Subedi, P.; Usmanov, A. V.; Matthaeus, W. H.; Ruffolo, D.; Goldstein, M. L.; Parashar, T. N.

2017-08-01

We use a three-dimensional magnetohydrodynamic simulation of the solar wind to calculate cosmic-ray diffusion coefficients throughout the inner heliosphere (2Rȯ-3au). The simulation resolves large-scale solar wind flow, which is coupled to small-scale fluctuations through a turbulence model. Simulation results specify background solar wind fields and turbulence parameters, which are used to compute diffusion coefficients and study their behavior in the inner heliosphere. The parallel mean free path (mfp) is evaluated using quasi-linear theory, while the perpendicular mfp is determined from nonlinear guiding center theory with the random ballistic interpretation. Several runs examine varying turbulent energy and different solar source dipole tilts. We find that for most of the inner heliosphere, the radial mfp is dominated by diffusion parallel to the mean magnetic field; the parallel mfp remains at least an order of magnitude larger than the perpendicular mfp, except in the heliospheric current sheet, where the perpendicular mfp may be a few times larger than the parallel mfp. In the ecliptic region, the perpendicular mfp may influence the radial mfp at heliocentric distances larger than 1.5au; our estimations of the parallel mfp in the ecliptic region at 1 au agree well with the Palmer "consensus" range of 0.08-0.3au. Solar activity increases perpendicular diffusion and reduces parallel diffusion. The parallel mfp mostly varies with rigidity (P) as P.33, and the perpendicular mfp is weakly dependent on P. The mfps are weakly influenced by the choice of long-wavelength power spectra. (2 data files).

Precipitation and Release of Solar Energetic Particles from the Solar Coronal Magnetic Field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Ming; Zhao, Lulu, E-mail: mzhang@fit.edu

Most solar energetic particles (SEPs) are produced in the corona. They propagate through complex coronal magnetic fields subject to scattering and diffusion across the averaged field lines by turbulence. We examine the behaviors of particle transport using a stochastic 3D focused transport simulation in a potential field source surface model of coronal magnetic field. The model is applied to an SEP event on 2010 February 7. We study three scenarios of particle injection at (i) the compact solar flare site, (ii) the coronal mass ejection (CME) shock, and (iii) the EUV wave near the surface. The majority of particles injectedmore » on open field lines are able to escape the corona. We found that none of our models can explain the observations of wide longitudinal SEP spread without perpendicular diffusion. If the perpendicular diffusion is about 10% of what is derived from the random walk of field lines at the rate of supergranular diffusion, particles injected at the compact solar flare site can spread to a wide range of longitude and latitude, very similar to the behavior of particles injected at a large CME shock. Stronger pitch-angle scattering results in a little more lateral spread by holding the particles in the corona for longer periods of time. Some injected particles eventually end up precipitating onto the solar surface. Even with a very small perpendicular diffusion, the pattern of the particle precipitation can be quite complicated depending on the detailed small-scale coronal magnetic field structures, which could be seen with future sensitive gamma-ray telescopes.« less

Precipitation and Release of Solar Energetic Particles from the Solar Coronal Magnetic Field

NASA Astrophysics Data System (ADS)

Zhang, Ming; Zhao, Lulu

2017-09-01

Most solar energetic particles (SEPs) are produced in the corona. They propagate through complex coronal magnetic fields subject to scattering and diffusion across the averaged field lines by turbulence. We examine the behaviors of particle transport using a stochastic 3D focused transport simulation in a potential field source surface model of coronal magnetic field. The model is applied to an SEP event on 2010 February 7. We study three scenarios of particle injection at (I) the compact solar flare site, (II) the coronal mass ejection (CME) shock, and (III) the EUV wave near the surface. The majority of particles injected on open field lines are able to escape the corona. We found that none of our models can explain the observations of wide longitudinal SEP spread without perpendicular diffusion. If the perpendicular diffusion is about 10% of what is derived from the random walk of field lines at the rate of supergranular diffusion, particles injected at the compact solar flare site can spread to a wide range of longitude and latitude, very similar to the behavior of particles injected at a large CME shock. Stronger pitch-angle scattering results in a little more lateral spread by holding the particles in the corona for longer periods of time. Some injected particles eventually end up precipitating onto the solar surface. Even with a very small perpendicular diffusion, the pattern of the particle precipitation can be quite complicated depending on the detailed small-scale coronal magnetic field structures, which could be seen with future sensitive gamma-ray telescopes.

A Maximum Likelihood Approach to Determine Sensor Radiometric Response Coefficients for NPP VIIRS Reflective Solar Bands

NASA Technical Reports Server (NTRS)

Lei, Ning; Chiang, Kwo-Fu; Oudrari, Hassan; Xiong, Xiaoxiong

2011-01-01

Optical sensors aboard Earth orbiting satellites such as the next generation Visible/Infrared Imager/Radiometer Suite (VIIRS) assume that the sensors radiometric response in the Reflective Solar Bands (RSB) is described by a quadratic polynomial, in relating the aperture spectral radiance to the sensor Digital Number (DN) readout. For VIIRS Flight Unit 1, the coefficients are to be determined before launch by an attenuation method, although the linear coefficient will be further determined on-orbit through observing the Solar Diffuser. In determining the quadratic polynomial coefficients by the attenuation method, a Maximum Likelihood approach is applied in carrying out the least-squares procedure. Crucial to the Maximum Likelihood least-squares procedure is the computation of the weight. The weight not only has a contribution from the noise of the sensor s digital count, with an important contribution from digitization error, but also is affected heavily by the mathematical expression used to predict the value of the dependent variable, because both the independent and the dependent variables contain random noise. In addition, model errors have a major impact on the uncertainties of the coefficients. The Maximum Likelihood approach demonstrates the inadequacy of the attenuation method model with a quadratic polynomial for the retrieved spectral radiance. We show that using the inadequate model dramatically increases the uncertainties of the coefficients. We compute the coefficient values and their uncertainties, considering both measurement and model errors.

Spectral data of specular reflectance, narrow-angle transmittance and angle-resolved surface scattering of materials for solar concentrators.

PubMed

Good, Philipp; Cooper, Thomas; Querci, Marco; Wiik, Nicolay; Ambrosetti, Gianluca; Steinfeld, Aldo

2016-03-01

The spectral specular reflectance of conventional and novel reflective materials for solar concentrators is measured with an acceptance angle of 17.5 mrad over the wavelength range 300-2500 nm at incidence angles 15-60° using a spectroscopic goniometry system. The same experimental setup is used to determine the spectral narrow-angle transmittance of semi-transparent materials for solar collector covers at incidence angles 0-60°. In addition, the angle-resolved surface scattering of reflective materials is recorded by an area-scan CCD detector over the spectral range 350-1050 nm. A comprehensive summary, discussion, and interpretation of the results are included in the associated research article "Spectral reflectance, transmittance, and angular scattering of materials for solar concentrators" in Solar Energy Materials and Solar Cells.

Formation and Diffusion of Metal Impurities in Perovskite Solar Cell Material CH 3NH 3PbI 3 : Implications on Solar Cell Degradation and Choice of Electrode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ming, Wenmei; Yang, Dongwen; Li, Tianshu

Solar cells based on methylammonium lead triiodide (MAPbI 3) have shown remarkable progress in recent years and have demonstrated efficiencies greater than 20%. However, the long-term stability of MAPbI 3-based solar cells has yet to be achieved. Besides the well-known chemical and thermal instabilities, significant native ion migration in lead halide perovskites leads to current–voltage hysteresis and photoinduced phase segregation. Recently, it is further revealed that, despite having excellent chemical stability, the Au electrode can cause serious solar cell degradation due to Au diffusion into MAPbI 3. In addition to Au, many other metals have been used as electrodes inmore » MAPbI 3 solar cells. However, how the external metal impurities introduced by electrodes affect the long-term stability of MAPbI 3 solar cells has rarely been studied. A comprehensive study of formation energetics and diffusion dynamics of a number of noble and transition metal impurities (Au, Ag, Cu, Cr, Mo, W, Co, Ni, Pd) in MAPbI 3 based on first-principles calculations is reported herein. The results uncover important general trends of impurity formation and diffusion in MAPbI 3 and provide useful guidance for identifying the optimal metal electrodes that do not introduce electrically active impurity defects in MAPbI 3 while having low resistivities and suitable work functions for carrier extraction.« less

Formation and Diffusion of Metal Impurities in Perovskite Solar Cell Material CH3NH3PbI3: Implications on Solar Cell Degradation and Choice of Electrode.

PubMed

Ming, Wenmei; Yang, Dongwen; Li, Tianshu; Zhang, Lijun; Du, Mao-Hua

2018-02-01

Solar cells based on methylammonium lead triiodide (MAPbI 3 ) have shown remarkable progress in recent years and have demonstrated efficiencies greater than 20%. However, the long-term stability of MAPbI 3 -based solar cells has yet to be achieved. Besides the well-known chemical and thermal instabilities, significant native ion migration in lead halide perovskites leads to current-voltage hysteresis and photoinduced phase segregation. Recently, it is further revealed that, despite having excellent chemical stability, the Au electrode can cause serious solar cell degradation due to Au diffusion into MAPbI 3 . In addition to Au, many other metals have been used as electrodes in MAPbI 3 solar cells. However, how the external metal impurities introduced by electrodes affect the long-term stability of MAPbI 3 solar cells has rarely been studied. A comprehensive study of formation energetics and diffusion dynamics of a number of noble and transition metal impurities (Au, Ag, Cu, Cr, Mo, W, Co, Ni, Pd) in MAPbI 3 based on first-principles calculations is reported herein. The results uncover important general trends of impurity formation and diffusion in MAPbI 3 and provide useful guidance for identifying the optimal metal electrodes that do not introduce electrically active impurity defects in MAPbI 3 while having low resistivities and suitable work functions for carrier extraction.

Formation and Diffusion of Metal Impurities in Perovskite Solar Cell Material CH 3NH 3PbI 3 : Implications on Solar Cell Degradation and Choice of Electrode

DOE PAGES

Ming, Wenmei; Yang, Dongwen; Li, Tianshu; ...

2017-12-27

Solar cells based on methylammonium lead triiodide (MAPbI 3) have shown remarkable progress in recent years and have demonstrated efficiencies greater than 20%. However, the long-term stability of MAPbI 3-based solar cells has yet to be achieved. Besides the well-known chemical and thermal instabilities, significant native ion migration in lead halide perovskites leads to current–voltage hysteresis and photoinduced phase segregation. Recently, it is further revealed that, despite having excellent chemical stability, the Au electrode can cause serious solar cell degradation due to Au diffusion into MAPbI 3. In addition to Au, many other metals have been used as electrodes inmore » MAPbI 3 solar cells. However, how the external metal impurities introduced by electrodes affect the long-term stability of MAPbI 3 solar cells has rarely been studied. A comprehensive study of formation energetics and diffusion dynamics of a number of noble and transition metal impurities (Au, Ag, Cu, Cr, Mo, W, Co, Ni, Pd) in MAPbI 3 based on first-principles calculations is reported herein. The results uncover important general trends of impurity formation and diffusion in MAPbI 3 and provide useful guidance for identifying the optimal metal electrodes that do not introduce electrically active impurity defects in MAPbI 3 while having low resistivities and suitable work functions for carrier extraction.« less

Formation and Diffusion of Metal Impurities in Perovskite Solar Cell Material CH3NH3PbI3: Implications on Solar Cell Degradation and Choice of Electrode

PubMed Central

Ming, Wenmei; Yang, Dongwen; Li, Tianshu

2017-01-01

Abstract Solar cells based on methylammonium lead triiodide (MAPbI3) have shown remarkable progress in recent years and have demonstrated efficiencies greater than 20%. However, the long‐term stability of MAPbI3‐based solar cells has yet to be achieved. Besides the well‐known chemical and thermal instabilities, significant native ion migration in lead halide perovskites leads to current–voltage hysteresis and photoinduced phase segregation. Recently, it is further revealed that, despite having excellent chemical stability, the Au electrode can cause serious solar cell degradation due to Au diffusion into MAPbI3. In addition to Au, many other metals have been used as electrodes in MAPbI3 solar cells. However, how the external metal impurities introduced by electrodes affect the long‐term stability of MAPbI3 solar cells has rarely been studied. A comprehensive study of formation energetics and diffusion dynamics of a number of noble and transition metal impurities (Au, Ag, Cu, Cr, Mo, W, Co, Ni, Pd) in MAPbI3 based on first‐principles calculations is reported herein. The results uncover important general trends of impurity formation and diffusion in MAPbI3 and provide useful guidance for identifying the optimal metal electrodes that do not introduce electrically active impurity defects in MAPbI3 while having low resistivities and suitable work functions for carrier extraction. PMID:29610728

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, X.; Florinski, V.

We present a new model that couples galactic cosmic-ray (GCR) propagation with magnetic turbulence transport and the MHD background evolution in the heliosphere. The model is applied to the problem of the formation of corotating interaction regions (CIRs) during the last solar minimum from the period between 2007 and 2009. The numerical model simultaneously calculates the large-scale supersonic solar wind properties and its small-scale turbulent content from 0.3 au to the termination shock. Cosmic rays are then transported through the background, and thus computed, with diffusion coefficients derived from the solar wind turbulent properties, using a stochastic Parker approach. Ourmore » results demonstrate that GCR variations depend on the ratio of diffusion coefficients in the fast and slow solar winds. Stream interfaces inside the CIRs always lead to depressions of the GCR intensity. On the other hand, heliospheric current sheet (HCS) crossings do not appreciably affect GCR intensities in the model, which is consistent with the two observations under quiet solar wind conditions. Therefore, variations in diffusion coefficients associated with CIR stream interfaces are more important for GCR propagation than the drift effects of the HCS during a negative solar minimum.« less

A fast calculating two-stream-like multiple scattering algorithm that captures azimuthal and elevation variations

NASA Astrophysics Data System (ADS)

Fiorino, Steven T.; Elmore, Brannon; Schmidt, Jaclyn; Matchefts, Elizabeth; Burley, Jarred L.

2016-05-01

Properly accounting for multiple scattering effects can have important implications for remote sensing and possibly directed energy applications. For example, increasing path radiance can affect signal noise. This study describes the implementation of a fast-calculating two-stream-like multiple scattering algorithm that captures azimuthal and elevation variations into the Laser Environmental Effects Definition and Reference (LEEDR) atmospheric characterization and radiative transfer code. The multiple scattering algorithm fully solves for molecular, aerosol, cloud, and precipitation single-scatter layer effects with a Mie algorithm at every calculation point/layer rather than an interpolated value from a pre-calculated look-up-table. This top-down cumulative diffusivity method first considers the incident solar radiance contribution to a given layer accounting for solid angle and elevation, and it then measures the contribution of diffused energy from previous layers based on the transmission of the current level to produce a cumulative radiance that is reflected from a surface and measured at the aperture at the observer. Then a unique set of asymmetry and backscattering phase function parameter calculations are made which account for the radiance loss due to the molecular and aerosol constituent reflectivity within a level and allows for a more accurate characterization of diffuse layers that contribute to multiple scattered radiances in inhomogeneous atmospheres. The code logic is valid for spectral bands between 200 nm and radio wavelengths, and the accuracy is demonstrated by comparing the results from LEEDR to observed sky radiance data.

Measurement and modeling of solar irradiance components on horizontal and tilted planes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Padovan, Andrea; Col, Davide del

2010-12-15

In this work new measurements of global and diffuse solar irradiance on the horizontal plane and global irradiance on planes tilted at 20 and 30 oriented due South and at 45 and 65 oriented due East are used to discuss the modeling of solar radiation. Irradiance data are collected in Padova (45.4 N, 11.9 E, 12 m above sea level), Italy. Some diffuse fraction correlations have been selected to model the hourly diffuse radiation on the horizontal plane. The comparison with the present experimental data shows that their prediction accuracy strongly depends on the sky characteristics. The hourly irradiance measurementsmore » taken on the tilted planes are compared with the estimations given by one isotropic and three anisotropic transposition models. The use of an anisotropic model, based on a physical description of the diffuse radiation, provides a much better accuracy, especially when measurements of the diffuse irradiance on the horizontal plane are not available and thus transposition models have to be applied in combination with a diffuse fraction correlation. This is particularly significant for the planes oriented away from South. (author)« less

Resolving the Origin of the Diffuse Soft X-ray Background

NASA Technical Reports Server (NTRS)

Smith, Randall K.; Foster, Adam R.; Edgar, Ricard J.; Brickhouse, Nancy S.; Sanders, Wilton T.

2012-01-01

In January 1993, the Diffuse X-ray Spectrometer (DXS) measured the first high-resolution spectrum of the diffuse soft X-ray background between 44-80A. A line-dominated spectrum characteristic of a 10(exp 6)K collisionally ionized plasma' was expected but while the observed spectrum was clearly line-dominated, no model would fit. Then in 2003 the Cosmic Hot Interstellar Plasma Spectrometer (CHIPS) launched and observed the diffuse extreme-ultraviolet (EUV) spectrum between 90- 265A. Although many emission lines were again expected; only Fe IX at 171.1A was detected. The discovery of X-rays from comets led to the realization that heavy ions (Z=6-28) in the solar wind will emit soft X-rays as the ions interact via charge exchange with neutral atoms in the heliosphere and geocorona. Using a new model for solar wind charge exchange (SWCX) emission, we show that the diffuse soft X-ray background can be understood as a combination of emission from charge exchange onto the slow and fast solar wind together with a more distant and diffuse hot (10(exp 6)K) plasma.

Sky radiance at a coastline and effects of land and ocean reflectivities

NASA Astrophysics Data System (ADS)

Kreuter, Axel; Blumthaler, Mario; Tiefengraber, Martin; Kift, Richard; Webb, Ann R.

2017-12-01

We present a unique case study of the spectral sky radiance distribution above a coastline. Results are shown from a measurement campaign in Italy involving three diode array spectroradiometers which are compared to 3-D model simulations from the Monte Carlo model MYSTIC. On the coast, the surrounding is split into two regions, a diffusely reflecting land surface and a water surface which features a highly anisotropic reflectance function. The reflectivities and hence the resulting radiances are a nontrivial function of solar zenith and azimuth angle and wavelength. We show that for low solar zenith angles (SZAs) around noon, the higher land albedo causes the sky radiance at 20° above the horizon to increase by 50 % in the near infrared at 850 nm for viewing directions towards the land with respect to the ocean. Comparing morning and afternoon radiances highlights the effect of the ocean's sun glint at high SZA, which contributes around 10 % to the measured radiance ratios. The model simulations generally agree with the measurements to better than 10 %. We investigate the individual effects of model input parameters representing land and ocean albedo and aerosols. Different land and ocean bi-directional reflectance functions (BRDFs) do not generally improve the model agreement. However, consideration of the uncertainties in the diurnal variation of aerosol optical depth can explain the remaining discrepancies between measurements and model. We further investigate the anisotropy effect of the ocean BRDF which is featured in the zenith radiances. Again, the uncertainty of the aerosol loading is dominant and obscures the modelled sun glint effect of 7 % at 650 nm. Finally, we show that the effect on the zenith radiance is restricted to a few kilometres from the coastline by model simulations along a perpendicular transect and by comparing the radiances at the coast to those measured at a site 15 km inland. Our findings are relevant to, for example, ground-based remote sensing of aerosol characteristics, since a common technique is based on sky radiance measurements along the solar almucantar.

Preliminary Results on Design and Implementation of a Solar Radiation Monitoring System

PubMed Central

Balan, Mugur C.; Damian, Mihai; Jäntschi, Lorentz

2008-01-01

The paper presents a solar radiation monitoring system, using two scientific pyranometers and an on-line computer home-made data acquisition system. The first pyranometer measures the global solar radiation and the other one, which is shaded, measure the diffuse radiation. The values of total and diffuse solar radiation are continuously stored into a database on a server. Original software was created for data acquisition and interrogation of the created system. The server application acquires the data from pyranometers and stores it into a database with a baud rate of one record at 50 seconds. The client-server application queries the database and provides descriptive statistics. A web interface allow to any user to define the including criteria and to obtain the results. In terms of results, the system is able to provide direct, diffuse and total radiation intensities as time series. Our client-server application computes also derivate heats. The ability of the system to evaluate the local solar energy potential is highlighted. PMID:27879746

Selective emitter solar cell formation by NH3 plasma nitridation and single diffusion

NASA Astrophysics Data System (ADS)

Wu, Yung-Hsien; Chen, Lun-Lun; Wu, Jia-Rong; Wu, Min-Lin

2010-01-01

A new and simple process for fabricating a selective emitter solar cell has been proposed. Lightly and heavily doped emitters could be concurrently formed after a single POCl3 diffusion step through the selective formation of SiNx, which serves as the diffusion barrier and can be grown by NH3 plasma nitridation of the Si surface. The desired phosphorus depth profile for the lightly and heavily doped region verifies the eligibility of this process. From the electrical characterization, the selective emitter solar cell fabricated by this process manifests a higher absolute conversion efficiency than a conventional one by 0.5%. It is the enhanced response to the short wavelength light and the reduced surface recombination that causes the considerable improvement in conversion efficiency which is beneficial to further hold the competitive advantage for solar cell manufacturers. Most importantly, the proposed process can be fully integrated into the conventional solar cell process in a mass-production laboratory.

Processes for producing low cost, high efficiency silicon solar cells

DOEpatents

Rohatgi, Ajeet; Chen, Zhizhang; Doshi, Parag

1996-01-01

Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.

Photonic Devices Based on Surface and Composition-Engineered Infrared Colloidal Nanocrystals

DTIC Science & Technology

2012-01-27

NQD/P3HT solar cells , the need for submicron-phase-separated polymer-NQD blends is therefore expressed by the limiting exciton diffusion length ...P3HT:PbSe are very critical in designing the PM-HJ solar cells : The thickness of P3HT should approximate to the thickness of exciton diffuse length in... cells , luminescent solar concentrators, light emitting diodes, lasers, photonic crystals, CdSe, PbSe, Germanium Jian Xu Pennsylvania State University

Analysis and evalaution in the production process and equipment area of the low-cost solar array project. [including modifying gaseous diffusion and using ion implantation

NASA Technical Reports Server (NTRS)

Goldman, H.; Wolf, M.

1979-01-01

The manufacturing methods for photovoltaic solar energy utilization are assessed. Economic and technical data on the current front junction formation processes of gaseous diffusion and ion implantation are presented. Future proposals, including modifying gaseous diffusion and using ion implantation, to decrease the cost of junction formation are studied. Technology developments in current processes and an economic evaluation of the processes are included.

Applicability of a Diffuse Reflectance Infrared Fourier Transform handheld spectrometer to perform in situ analyses on Cultural Heritage materials

NASA Astrophysics Data System (ADS)

Arrizabalaga, Iker; Gómez-Laserna, Olivia; Aramendia, Julene; Arana, Gorka; Madariaga, Juan Manuel

2014-08-01

This work studies the applicability of a Diffuse Reflectance Infrared Fourier Transform handheld device to perform in situ analyses on Cultural Heritage assets. This portable diffuse reflectance spectrometer has been used to characterise and diagnose the conservation state of (a) building materials of the Guevara Palace (15th century, Segura, Basque Country, Spain) and (b) different 19th century wallpapers manufactured by the Santa Isabel factory (Vitoria-Gasteiz, Basque Country, Spain) and by the well known Dufour and Leroy manufacturers (Paris, France), all of them belonging to the Torre de los Varona Castle (Villanañe, Basque Country, Spain). In all cases, in situ measurements were carried out and also a few samples were collected and measured in the laboratory by diffuse reflectance spectroscopy (DRIFT) in order to validate the information obtained by the handheld instrument. In the analyses performed in situ, distortions in the diffuse reflectance spectra can be observed due to the presence of specular reflection, showing the inverted bands caused by the Reststrahlen effect, in particular on those IR bands with the highest absorption coefficients. This paper concludes that the results obtained in situ by a diffuse reflectance handheld device are comparable to those obtained with laboratory diffuse reflectance spectroscopy equipment and proposes a few guidelines to acquire good spectra in the field, minimising the influence caused by the specular reflection.

Solar Energy Evolution and Diffusion Studies Webinars | Solar Research |

Science.gov Websites

video Download the transcript Agent-based Models of How Segregation and Peer Effects Influence Solar PV to estimate the relative influence of peer effects, cognitive factors, and economic factors in solar

Surface roughness effects on the solar reflectance of cool asphalt shingles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akbari, Hashem; Berdahl, Paul; Akbari, Hashem

2008-02-17

We analyze the solar reflectance of asphalt roofing shingles that are covered with pigmented mineral roofing granules. The reflecting surface is rough, with a total area approximately twice the nominal area. We introduce a simple analytical model that relates the 'micro-reflectance' of a small surface region to the 'macro-reflectance' of the shingle. This model uses a mean field approximation to account for multiple scattering effects. The model is then used to compute the reflectance of shingles with a mixture of different colored granules, when the reflectances of the corresponding mono-color shingles are known. Simple linear averaging works well, with smallmore » corrections to linear averaging derived for highly reflective materials. Reflective base granules and reflective surface coatings aid achievement of high solar reflectance. Other factors that influence the solar reflectance are the size distribution of the granules, coverage of the asphalt substrate, and orientation of the granules as affected by rollers during fabrication.« less

Optical and electrical studies of cerium mixed oxides

NASA Astrophysics Data System (ADS)

Sherly, T. R.; Raveendran, R.

2014-10-01

The fast development in nanotechnology makes enthusiastic interest in developing nanomaterials having tailor made properties. Cerium mixed oxide materials have received great attention due to their UV absorption property, high reactivity, stability at high temperature, good electrical property etc and these materials find wide applications in solid oxide fuel cells, solar control films, cosmetics, display units, gas sensors etc. In this study cerium mixed oxide compounds were prepared by co-precipitation method. All the samples were doped with Zn (II) and Fe (II). Preliminary characterizations such as XRD, SEM / EDS, TEM were done. UV - Vis, Diffuse reflectance, PL, FT-IR, Raman and ac conductivity studies of the samples were performed.

Light radiation pressure upon an optically orthotropic surface

NASA Astrophysics Data System (ADS)

Nerovny, Nikolay A.; Lapina, Irina E.; Grigorjev, Anton S.

2017-11-01

In this paper, we discuss the problem of determination of light radiation pressure force upon an anisotropic surface. The optical parameters of such a surface are considered to have major and minor axes, so the model is called an orthotropic model. We derive the equations for force components from emission, absorption, and reflection, utilizing a modified Maxwell's specular-diffuse model. The proposed model can be used to model a flat solar sail with wrinkles. By performing Bayesian analysis for example of a wrinkled surface, we show that there are cases in which an orthotropic model of the optical parameters of a surface may be more accurate than an isotropic model.

Quantifying the potential of III-V/Si partial concentrator by a statistical approach

NASA Astrophysics Data System (ADS)

Lee, Kan-Hua; Araki, Kenji; Ota, Yasuyuki; Nishioka, Kensuke; Yamaguchi, Masafumi

2017-09-01

We propose a theoretical framework for analyzing the energy yields of partial concentrators. A partial concentrator uses a concentrator cell to absorb the principal defracted or reflected light rays from its concentrator optics and a backplane cell to absorbs the diffused or defocused light. This concept can be applied to the concentrator system when accurate sun-tracking is not available, such as on a vehicle. This analysis framework provides a simplified way to describe the uncertainties of solar incidences dealt by partial concentrator. This help identified a clearer design criteria of partial concentrator in order to outperform the flat-panel PV or conventional CPV.

Near Earth Asteroid Scout Thrust and Torque Model

NASA Technical Reports Server (NTRS)

Heaton, Andrew; Ahmad, Naeem; Miller, Kyle

2017-01-01

The Near Earth Asteroid (NEA) Scout is a solar sail mission whose objective is to scout at least one Near Earth Asteroid in preparation for manned missions to asteroids. NEA Scout will use a solar sail as the primary means of propulsion. Thus it is important for mission planning to accurately characterize the thrust of the sail. Additionally, the solar sail creates a relatively large solar disturbance torque that must be mitigated. For early mission design studies a flat plate model of the solar sail with a fixed center of pressure was adequate, but as mission concepts and the sail design matured, greater fidelity was required. Here we discuss the progress to a three-dimensional sail model that includes the effects of tension and thermal deformation that has been derived from a large structural Finite Element Model (FEM) developed by the Langley Research Center. We have found that the deformed sail membrane affects torque relatively much more than thrust. We have also found that other than uncertainty over the precise shape, the effect of small (approximately millimeter scale) wrinkles on the diffusivity of the sail is the leading remaining source of uncertainty. We demonstrate that millimeter-scale wrinkles can be modeled analytically as a change in the fraction of specular reflection. Finally we discuss the implications of these results for the NEA Scout mission.

Flat-plate solar array project process development area: Process research of non-CZ silicon material

NASA Technical Reports Server (NTRS)

Campbell, R. B.

1986-01-01

Several different techniques to simultaneously diffuse the front and back junctions in dendritic web silicon were investigated. A successful simultaneous diffusion reduces the cost of the solar cell by reducing the number of processing steps, the amount of capital equipment, and the labor cost. The three techniques studied were: (1) simultaneous diffusion at standard temperatures and times using a tube type diffusion furnace or a belt furnace; (2) diffusion using excimer laser drive-in; and (3) simultaneous diffusion at high temperature and short times using a pulse of high intensity light as the heat source. The use of an excimer laser and high temperature short time diffusion experiment were both more successful than the diffusion at standard temperature and times. The three techniques are described in detail and a cost analysis of the more successful techniques is provided.

PVMirror: A New Concept for Tandem Solar Cells and Hybrid Solar Converters

DOE PAGES

Yu, Zhengshan J.; Fisher, Kathryn C.; Wheelwright, Brian M.; ...

2015-08-25

As the solar electricity market has matured, energy conversion efficiency and storage have joined installed system cost as significant market drivers. In response, manufacturers of flatplate silicon photovoltaic (PV) cells have pushed cell efficiencies above 25%—nearing the 29.4% detailed-balance efficiency limit— and both solar thermal and battery storage technologies have been deployed at utility scale. This paper introduces a new tandem solar collector employing a “PVMirror” that has the potential to both increase energy conversion efficiency and provide thermal storage. A PVMirror is a concentrating mirror, spectrum splitter, and light-to-electricity converter all in one: It consists of a curved arrangementmore » of PV cells that absorb part of the solar spectrum and reflect the remainder to their shared focus, at which a second solar converter is placed. A strength of the design is that the solar converter at the focus can be of a radically different technology than the PV cells in the PVMirror; another is that the PVMirror converts a portion of the diffuse light to electricity in addition to the direct light. Here, we consider two case studies—a PV cell located at the focus of the PVMirror to form a four-terminal PV–PV tandem, and a thermal receiver located at the focus to form a PV–CSP (concentrating solar thermal power) tandem—and compare the outdoor energy outputs to those of competing technologies. PVMirrors can outperform (idealized) monolithic PV–PV tandems that are under concentration, and they can also generate nearly as much energy as silicon flat-plate PV while simultaneously providing the full energy storage benefit of CSP.« less

CFS Products

Science.gov Websites

vddsf.xx.YYYYMMDDHH.daily.grb2 Not Available CFS Near IR Diffuse Downward Solar Flux Filename Inventory Available CFS Near IR Diffuse Downward Solar Flux Filename Inventory nddsf.xx.YYYYMMDDHH.daily.grb2 6hrly Image of NCEP logo For questions related to this website, send mail to Web Manager. NCEP/NCO Production

Improved backward ray tracing with stochastic sampling

NASA Astrophysics Data System (ADS)

Ryu, Seung Taek; Yoon, Kyung-Hyun

1999-03-01

This paper presents a new technique that enhances the diffuse interreflection with the concepts of backward ray tracing. In this research, we have modeled the diffuse rays with the following conditions. First, as the reflection from the diffuse surfaces occurs in all directions, it is impossible to trace all of the reflected rays. We confined the diffuse rays by sampling the spherical angle out of the reflected rays around the normal vector. Second, the traveled distance of reflected energy from the diffuse surface differs according to the object's property, and has a comparatively short reflection distance. Considering the fact that the rays created on the diffuse surfaces affect relatively small area, it is very inefficient to trace all of the sampled diffused rays. Therefore, we set a fixed distance as the critical distance and all the rays beyond this distance are ignored. The result of this research is that as the improved backward ray tracing can model the illumination effects such as the color bleeding effects, we can replace the radiosity algorithm under the limited environment.

Using Field Measurements to Assess Aging of Self-Cleaning High-Reflectance Paint

NASA Astrophysics Data System (ADS)

Takebayashi, Hideki; Tanabe, Junichiro; Aoyama, Taizo; Sonoda, Takeshi; Nakanishi, Yasushi

2017-08-01

Continuous field measurements were used to evaluate the aging of solar reflectance on self-cleaning coatings for roofs in comparison with conventional coatings that have no self-cleaning function. Solar reflectance on self-cleaning coatings decreases by about 6 % per year with annual variations, due to the adhesion of dirt. On the other hand, solar reflectance on conventional coatings greatly decreases, by approximately 18 % within four months of the coating's application, due to the adhesion of dirt. Then, it gradually recovers at a rate of about 4 % per year, with annual variations, due to degradation of the coating. It is due to degradation of the conventional coating that the difference of solar reflectance between the self-cleaning coating and the conventional coating becomes almost zero in two years. Both the adhesion of dirt and coating degradation by chalking affect the temporal change of solar reflectance with annual variation.

Validation of Radiometric Standards for the Laboratory Calibration of Reflected-Solar Earth Observing Satellite Instruments

NASA Technical Reports Server (NTRS)

Butler, James J.; Johnson, B. Carol; Rice, Joseph P.; Brown, Steven W.; Barnes, Robert A.

2007-01-01

Historically, the traceability of the laboratory calibration of Earth-observing satellite instruments to a primary radiometric reference scale (SI units) is the responsibility of each instrument builder. For the NASA Earth Observing System (EOS), a program has been developed using laboratory transfer radiometers, each with its own traceability to the primary radiance scale of a national metrology laboratory, to independently validate the radiances assigned to the laboratory sources of the instrument builders. The EOS Project Science Office also developed a validation program for the measurement of onboard diffuse reflecting plaques, which are also used as radiometric standards for Earth-observing satellite instruments. Summarized results of these validation campaigns, with an emphasis on the current state-of-the-art uncertainties in laboratory radiometric standards, will be presented. Future mission uncertainty requirements, and possible enhancements to the EOS validation program to ensure that those uncertainties can be met, will be presented.

Solar Sail Propulsion for Interplanetary Cubesats

NASA Technical Reports Server (NTRS)

Johnson, Les; Sobey, Alex; Sykes, Kevin

2015-01-01

NASA is developing two small satellite missions as part of the Advanced Exploration Systems (AES) Program, both of which will use a solar sail to enable their scientific objectives. Solar sails use sunlight to propel vehicles through space by reflecting solar photons from a large, mirror-like sail made of a lightweight, highly reflective material. This continuous photon pressure provides propellantless thrust, allowing for very high (Delta)V maneuvers on long-duration, deep space exploration. Since reflected light produces thrust, solar sails require no onboard propellant. Solar sail technology is rapidly maturing for space propulsion applications within NASA and around the world.

Smart, passive sun facing surfaces

DOEpatents

Hively, Lee M.

1996-01-01

An article adapted for selectively utilizing solar radiation comprises an absorptive surface and a reflective surface, the absorptive surface and the reflective surface oriented to absorb solar radiation when the sun is in a relatively low position, and to reflect solar radiation when the sun is in a relatively high position.

Smart, passive sun facing surfaces

DOEpatents

Hively, L.M.

1996-04-30

An article adapted for selectively utilizing solar radiation comprises an absorptive surface and a reflective surface, the absorptive surface and the reflective surface oriented to absorb solar radiation when the sun is in a relatively low position, and to reflect solar radiation when the sun is in a relatively high position. 17 figs.

The budget of biologically active ultraviolet radiation in the earth-atmosphere system

NASA Technical Reports Server (NTRS)

Frederick, John E.; Lubin, Dan

1988-01-01

This study applies the concept of a budget to describe the interaction of solar ultraviolet (UV) radiation with the earth-atmosphere system. The wavelength ranges of interest are the biologically relevant UV-B between 280 and 320 nm and the UV-A from 32000 to 400 nm. The Nimbus 7 solar backscattered ultraviolet (SBUV) instrument provides measurements of total column ozone and information concerning cloud cover which, in combination with a simple model of radiation transfer, define the fractions of incident solar irradiance absorbed in the atmosphere, reflected to space, and absorbed at the ground. Results for the month of July quantify the contribution of fractional cloud cover and cloud optical thickness to the radiation budget's three components. Scattering within a thick cloud layer makes the downward radiation field at the cloud base more isotropic than is the case for clear skies. For small solar zenith angles, typical of summer midday conditions, the effective pathlength of this diffuse irradiance through tropospheric ozone is greater than that under clear-sky conditions. The result is an enhanced absorption of UV-B radiation in the troposphere during cloud-covered conditions. Major changes in global cloud cover or cloud optical thicknesses could alter the ultraviolet radiation received by the biosphere by an amount comparable to that predicted for long-term trends in ozone.

Fabrication, characterization of two nano-composite CuO-ZnO working electrodes for dye-sensitized solar cell.

PubMed

Habibi, Mohammad Hossein; Karimi, Bahareh; Zendehdel, Mahmoud; Habibi, Mehdi

2013-12-01

Two kind of CuO-ZnO nanocomposite working electrodes were synthesized by sol-gel technology and applied in dye-sensitized solar cells (DSSCs). Their characteristics were studied by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and UV-Vis diffuse reflectance spectrum (DRS). CuO-ZnO nanocomposite thin films were prepared doctor blade technique on the fluorine-doped tin oxide (FTO) and used as working electrodes in dye sensitized solar cells (DSSC). Their photovoltaic behavior were compared with standard using D35 dye and an electrolyte containing [Co(bpy)3](PF6)2, [Co(pby)3](PF6)3, LiClO4, and 4-tert-butylpyridine (TBP). The ranges of short-circuit current (JSC) from 0.18 to 0.21 (mA/cm(2)), open-circuit voltage (VOC) from 0.24 to 0.55V, and fill factor from 0.34 to 0.39 were obtained for the DSSCs made using the working electrodes. The efficiency of the working electrodes after the addition of TBL was more than doubled. The light scattering and carrier transport properties of these composites promote the performance of dye-sensitized solar cells (DSSCs). Copyright © 2013 Elsevier B.V. All rights reserved.

Transmitting and reflecting diffuser. [for ultraviolet light

NASA Technical Reports Server (NTRS)

Keafer, L. S., Jr.; Burcher, E. E.; Kopia, L. P. (Inventor)

1973-01-01

A near-Lambertian diffuser is described which transmits and reflects ultraviolet light. An ultraviolet grade fused silica substrate is coated with vaporized fuse silica. The coating thickness is controlled, one thickness causing ultraviolet light to diffuse and another thickness causing ultraviolet light to reflect a near Lambertian pattern.

Laser process and corresponding structures for fabrication of solar cells with shunt prevention dielectric

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harley, Gabriel; Smith, David D.; Dennis, Tim

Contact holes of solar cells are formed by laser ablation to accommodate various solar cell designs. Use of a laser to form the contact holes is facilitated by replacing films formed on the diffusion regions with a film that has substantially uniform thickness. Contact holes may be formed to deep diffusion regions to increase the laser ablation process margins. The laser configuration may be tailored to form contact holes through dielectric films of varying thicknesses.

Application of the MOS-C-V technique to determine impurity concentrations and surface parameters on the diffused face of silicon solar cells

NASA Technical Reports Server (NTRS)

Weinberg, I.

1975-01-01

The feasibility of using the MOS C-V technique to obtain information regarding impurity and surface state concentrations on the diffused face of silicon solar cells with Ta2O5 coatings is studied. Results indicate that the MOS C-V technique yields useful information concerning surface parameters which contribute to the high, efficiency limiting, surface recombination velocities on the n+ surface of silicon solar cells.

Process and structures for fabrication of solar cells with laser ablation steps to form contact holes

DOEpatents

Harley, Gabriel; Smith, David D; Dennis, Tim; Waldhauer, Ann; Kim, Taeseok; Cousins, Peter John

2013-11-19

Contact holes of solar cells are formed by laser ablation to accomodate various solar cell designs. Use of a laser to form the contact holes is facilitated by replacing films formed on the diffusion regions with a film that has substantially uniform thickness. Contact holes may be formed to deep diffusion regions to increase the laser ablation process margins. The laser configuration may be tailored to form contact holes through dielectric films of varying thickness.

Low cost solar array project cell and module formation research area: Process research of non-CZ silicon material

NASA Technical Reports Server (NTRS)

1981-01-01

Liquid diffusion masks and liquid applied dopants to replace the CVD Silox masking and gaseous diffusion operations specified for forming junctions in the Westinghouse baseline process sequence for producing solar cells from dendritic web silicon were investigated. The baseline diffusion masking and drive processes were compared with those involving direct liquid applications to the dendritic web silicon strips. Attempts were made to control the number of variables by subjecting dendritic web strips cut from a single web crystal to both types of operations. Data generated reinforced earlier conclusions that efficiency levels at least as high as those achieved with the baseline back junction formation process can be achieved using liquid diffusion masks and liquid dopants. The deliveries of dendritic web sheet material and solar cells specified by the current contract were made as scheduled.

Diffused junction p(+)-n solar cells in bulk GaAs. II - Device characterization and modelling

NASA Technical Reports Server (NTRS)

Keeney, R.; Sundaram, L. M. G.; Rode, H.; Bhat, I.; Ghandhi, S. K.; Borrego, J. M.

1984-01-01

The photovoltaic characteristics of p(+)-n junction solar cells fabricated on bulk GaAs by an open tube diffusion technique are presented in detail. Quantum efficiency measurements were analyzed and compared to computer simulations of the cell structure in order to determine material parameters such as diffusion length, surface recombination velocity and junction depth. From the results obtained it is projected that proper optimization of the cell parameters can increase the efficiency of the cells to close to 20 percent.

Physical Limits of Solar Energy Conversion in the Earth System.

PubMed

Kleidon, Axel; Miller, Lee; Gans, Fabian

2016-01-01

Solar energy provides by far the greatest potential for energy generation among all forms of renewable energy. Yet, just as for any form of energy conversion, it is subject to physical limits. Here we review the physical limits that determine how much energy can potentially be generated out of sunlight using a combination of thermodynamics and observed climatic variables. We first explain how the first and second law of thermodynamics constrain energy conversions and thereby the generation of renewable energy, and how this applies to the conversions of solar radiation within the Earth system. These limits are applied to the conversion of direct and diffuse solar radiation - which relates to concentrated solar power (CSP) and photovoltaic (PV) technologies as well as biomass production or any other photochemical conversion - as well as solar radiative heating, which generates atmospheric motion and thus relates to wind power technologies. When these conversion limits are applied to observed data sets of solar radiation at the land surface, it is estimated that direct concentrated solar power has a potential on land of up to 11.6 PW (1 PW=10(15) W), whereas photovoltaic power has a potential of up to 16.3 PW. Both biomass and wind power operate at much lower efficiencies, so their potentials of about 0.3 and 0.1 PW are much lower. These estimates are considerably lower than the incoming flux of solar radiation of 175 PW. When compared to a 2012 primary energy demand of 17 TW, the most direct uses of solar radiation, e.g., by CSP or PV, have thus by far the greatest potential to yield renewable energy requiring the least space to satisfy the human energy demand. Further conversions into solar-based fuels would be reduced by further losses which would lower these potentials. The substantially greater potential of solar-based renewable energy compared to other forms of renewable energy simply reflects much fewer and lower unavoidable conversion losses when solar radiation is directly converted into renewable energy.

Trends in surface solar radiation in Spain since the 1980s: the role of the changes in the radiative effects of aerosols and clouds

NASA Astrophysics Data System (ADS)

Sanchez-Lorenzo, Arturo; Mateos, David; Wild, Martin; Calbó, Josep; Antón, Manuel; Enriquez-Alonso, Aaron; Sanchez-Romero, Alex

2014-05-01

There is a growing interest in the study of decadal variations in surface solar radiation, although the analyses of long-term time series in some areas with major gaps in observations, such as in Spain, are still pending. In the first part of this work, a previously published surface solar radiation dataset in Spain is described (for more details, see Sanchez-Lorenzo et al., 2013) based on the longest series with ground-based records of global and diffuse solar radiation, most of them starting in the early 1980s and ending in 2012. Particular emphasis is placed upon the homogenization of this dataset in order to ensure the reliability of the trends. The linear trend in the mean annual series of global solar radiation shows a significant increase since 1981 of 4.0 Wm-2 (or 2.4 %) per decade. These results are in line with the increase of global solar radiation (i.e. brightening period) reported at many worldwide observation sites (Wild, 2009). In addition, the annual mean diffuse solar radiation series shows a significant decrease during the last three decades, but it is disturbed by strong increases in 1983 and 1991-1992, which might reflect the effects of the El Chichón and Pinatubo volcanic eruptions as a result of enhanced scattering of the aerosols emitted during these large volcanic eruptions. As clouds and aerosols are the main sources of uncertainty in the determination of the energy balance of the Earth, there is a growing interest in the evaluation of their radiative effects and their impact on the decadal variability of the surface solar radiation. Hence, in the second part of this work, the changes of the combined radiative effects of clouds and aerosols in Spain since the 1980s are investigated (for more details, see Mateos et al., 2013). In particular, the global solar radiation data above mentioned and radiative transfer simulations fed with reanalysis data of ozone, water vapour and surface albedo, are used to evaluate the cloud and aerosol radiative effect (CARE) during the 1985-2010 period. The results show a significant decrease of CARE over Spain. Overall, the linear trend of the mean annual CARE series over Spain is 3.1 Wm-2 (or 5%) per decade, in line with those trends obtained for global solar radiation during the same period. Moreover, the radiative effects of water vapour and ozone have no significant trends during the study period. In conclusion, our study in Spain supports the hypothesis usually considered to explain the widespread surface solar radiation trends by changes in aerosols and clouds (Wild, 2009). Other atmospheric variables, such as ozone column or atmospheric water vapour play a minor, almost negligible, role on these trends. References: Mateos, D., Antón, M.,Sanchez-Lorenzo, A., Calbó, J., and Wild, M. (2013): Long-term changes in the radiative effects of aerosols and clouds in a mid-latitude region (1985-2010), Global and Planetary Change, 111, 288-295. Sanchez-Lorenzo, A., Calbó, J., and Wild, M. (2013): Global and diffuse solar radiation in Spain: building a homogeneous dataset and assessing their trends, Global and Planetary Change, 100, 343- 352. Wild, M. (2009): Global dimming and brightening: a review, Journal of Geophysical Research 114, D00D16.http://dx.doi.org/10.1029/2008JD011470.

Multifunctional microstructured polymer films for boosting solar power generation of silicon-based photovoltaic modules.

PubMed

Leem, Jung Woo; Choi, Minkyu; Yu, Jae Su

2015-02-04

We propose two-dimensional periodic conical micrograting structured (MGS) polymer films as a multifunctional layer (i.e., light harvesting and self-cleaning) at the surface of outer polyethylene terephthalate (PET) cover-substrates for boosting the solar power generation in silicon (Si)-based photovoltaic (PV) modules. The surface of ultraviolet-curable NOA63 MGS polymer films fabricated by the soft imprint lithography exhibits a hydrophobic property with water contact angle of ∼121° at no inclination and dynamic advancing/receding water contact angles of ∼132°/111° at the inclination angle of 40°, respectively, which can remove dust particles or contaminants on the surface of PV modules in real outdoor environments (i.e., self-cleaning). The NOA63 MGS film coated on the bare PET leads to the reduction of reflection as well as the enhancement of both the total and diffuse transmissions at wavelengths of 300-1100 nm, indicating lower solar weighted reflectance (RSW) of ∼8.2%, higher solar weighted transmittance (TSW) of ∼93.1%, and considerably improved average haze ratio (HAvg) of ∼88.3% as compared to the bare PET (i.e., RSW ≈ 13.5%, TSW ≈ 86.9%, and HAvg ≈ 9.1%), respectively. Additionally, it shows a relatively good durability at temperatures of ≤160 °C. The resulting Si PV module with the NOA63 MGS/PET has an enhanced power conversion efficiency (PCE) of 13.26% (cf., PCE = 12.55% for the reference PV module with the bare PET) due to the mainly improved short circuit current from 49.35 to 52.01 mA, exhibiting the PCE increment percentage of ∼5.7%. For light incident angle-dependent PV module current-voltage characteristics, superior solar energy conversion properties are also obtained in a broad angle range of 10-80°.

A method for optimizing the cosine response of solar UV diffusers

NASA Astrophysics Data System (ADS)

Pulli, Tomi; Kärhä, Petri; Ikonen, Erkki

2013-07-01

Instruments measuring global solar ultraviolet (UV) irradiance at the surface of the Earth need to collect radiation from the entire hemisphere. Entrance optics with angular response as close as possible to the ideal cosine response are necessary to perform these measurements accurately. Typically, the cosine response is obtained using a transmitting diffuser. We have developed an efficient method based on a Monte Carlo algorithm to simulate radiation transport in the solar UV diffuser assembly. The algorithm takes into account propagation, absorption, and scattering of the radiation inside the diffuser material. The effects of the inner sidewalls of the diffuser housing, the shadow ring, and the protective weather dome are also accounted for. The software implementation of the algorithm is highly optimized: a simulation of 109 photons takes approximately 10 to 15 min to complete on a typical high-end PC. The results of the simulations agree well with the measured angular responses, indicating that the algorithm can be used to guide the diffuser design process. Cost savings can be obtained when simulations are carried out before diffuser fabrication as compared to a purely trial-and-error-based diffuser optimization. The algorithm was used to optimize two types of detectors, one with a planar diffuser and the other with a spherically shaped diffuser. The integrated cosine errors—which indicate the relative measurement error caused by the nonideal angular response under isotropic sky radiance—of these two detectors were calculated to be f2=1.4% and 0.66%, respectively.

Applicability of a Diffuse Reflectance Infrared Fourier Transform handheld spectrometer to perform in situ analyses on Cultural Heritage materials.

PubMed

Arrizabalaga, Iker; Gómez-Laserna, Olivia; Aramendia, Julene; Arana, Gorka; Madariaga, Juan Manuel

2014-08-14

This work studies the applicability of a Diffuse Reflectance Infrared Fourier Transform handheld device to perform in situ analyses on Cultural Heritage assets. This portable diffuse reflectance spectrometer has been used to characterise and diagnose the conservation state of (a) building materials of the Guevara Palace (15th century, Segura, Basque Country, Spain) and (b) different 19th century wallpapers manufactured by the Santa Isabel factory (Vitoria-Gasteiz, Basque Country, Spain) and by the well known Dufour and Leroy manufacturers (Paris, France), all of them belonging to the Torre de los Varona Castle (Villanañe, Basque Country, Spain). In all cases, in situ measurements were carried out and also a few samples were collected and measured in the laboratory by diffuse reflectance spectroscopy (DRIFT) in order to validate the information obtained by the handheld instrument. In the analyses performed in situ, distortions in the diffuse reflectance spectra can be observed due to the presence of specular reflection, showing the inverted bands caused by the Reststrahlen effect, in particular on those IR bands with the highest absorption coefficients. This paper concludes that the results obtained in situ by a diffuse reflectance handheld device are comparable to those obtained with laboratory diffuse reflectance spectroscopy equipment and proposes a few guidelines to acquire good spectra in the field, minimising the influence caused by the specular reflection. Copyright © 2014 Elsevier B.V. All rights reserved.

Analysis of Al diffusion processes in TiN barrier layers for the application in silicon solar cell metallization

NASA Astrophysics Data System (ADS)

Kumm, J.; Samadi, H.; Chacko, R. V.; Hartmann, P.; Wolf, A.

2016-07-01

An evaporated Al layer is known as an excellent rear metallization for highly efficient solar cells, but suffers from incompatibility with a common solder process. To enable solar cell-interconnection and module integration, in this work the Al layer is complemented with a solder stack of TiN/Ti/Ag or TiN/NiV/Ag, in which the TiN layer acts as an Al diffusion barrier. X-ray photoelectron spectroscopy measurements prove that diffusion of Al through the stack and the formation of an Al2O3 layer on the stack's surface are responsible for a loss of solderability after a strong post-metallization anneal, which is often mandatory to improve contact resistance and passivation quality. An optimization of the reactive TiN sputter process results in a densification of the TiN layer, which improves its barrier quality against Al diffusion. However, measurements with X-ray diffraction and scanning electron microscopy show that small grains with vertical grain boundaries persist, which still offer fast diffusion paths. Therefore, the concept of stuffing is introduced. By incorporating oxygen into the grain boundaries of the sputtered TiN layer, Al diffusion is strongly reduced as confirmed by secondary ion mass spectroscopy profiles. A quantitative analysis reveals a one order of magnitude lower Al diffusion coefficient for stuffed TiN layers. This metallization system maintains its solderability even after strong post-metallization annealing at 425 °C for 15 min. This paper thus presents an industrially feasible, conventionally solderable, and long-term stable metallization scheme for highly efficient silicon solar cells.

Application of porous silicon in solar cell

NASA Astrophysics Data System (ADS)

Maniya, Nalin H.; Ashokan, Jibinlal; Srivastava, Divesh N.

2018-05-01

Silicon is widely used in solar cell applications with over 95% of all solar cells produced worldwide composed of silicon. Nanostructured thin porous silicon (PSi) layer acting as anti-reflecting coating is used in photovoltaic solar cells due to its advantages including simple and low cost fabrication, highly textured surfaces enabling lowering of reflectance, controllability of thickness and porosity of layer, and high surface area. PSi layers have previously been reported to reduce the reflection of light and replaced the conventional anti-reflective coating layers on solar cells. This can essentially improve the efficiency and decrease the cost of silicon solar cells. Here, we investigate the reflectance of different PSi layers formed by varying current density and etching time. PSi layers were formed by a combination of current density including 60 and 80 mA/cm2 and time for fabrication as 2, 4, 6, and 8 seconds. The fabricated PSi layers were characterized using reflectance spectroscopy and field emission scanning electron microscopy. Thickness and pore size of PSi layer were increased with increase in etching time and current density, respectively. The reflectance of PSi layers was decreased with increase in etching time until 6 seconds and increased again after 6 seconds, which was observed across both the current density. Reduction in reflectance indicates the increase of absorption of light by silicon due to the thin PSi layer. In comparison with the reflectance of silicon wafer, PSi layer fabricated at 80 mA/cm2 for 6 seconds gave the best result with reduction in reflectance up to 57%. Thus, the application of PSi layer as an effective anti-reflecting coating for the fabrication of solar cell has been demonstrated.

TASK 2.5.5 NATURAL EXPOSURE TESTING IN CALIFORNIA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, William A; Cheng, Mengdawn; New, Joshua Ryan

2010-03-01

Airborne particulate matter that settles on a roof can either reflect or absorb incoming solar radiation, dependent on the chemical content and size of the particles. These light scattering and absorption processes occur within a few microns of the surface, and can affect the solar reflectance of the roof. Wilkes et al. (2000) tested 24 different roof coatings on a low-slope test stand and observed about a 25% decrease in the solar reflectance of white-coated and aluminum-coated surfaces as the time of exposure increased; however, the decrease leveled off after 2 years. SPRI Inc. and its affiliates studied the effectmore » of climatic exposure on the surface properties of white thermoplastic single-ply membranes and determined that membranes lose from 30 to 50% of their reflectance over 3 years (Miller et al. 2002). The CMRC and its affiliates AISI, NamZAC, MBMA, MCA and NCCA exposed unpainted and painted metal roofing on both steep- and low-slope test roofs and found that after 3 years, the painted polyvinylidene fluoride (PVDF) metal roofs lost less than 5% of their original reflectance (Miller et al. 2004). The results of the three different weathering studies are very interesting in terms of their solar reflectance after 3 years of exposure. The white thermoplastic membrane and white ceramic coating with white topcoat had original reflectance measures that were about 20 percentage points higher than the painted metal; however, after 3-years of field exposure the solar reflectance of the painted metal exceeds that of the thermoplastic membrane and equals that of the coating. The long-term loss of reflectance appears driven by the ability of the particulate matter to cling to the roof and resist being washed off by wind and or rain. Miller et al. (2002) discovered that aerosol deposition introduced biomass of complex microbial consortia onto the test roofs and the combination of contaminants and biomass accelerated the loss of solar reflectance for the thermoplastic membranes and the roof coatings. Airborne contaminants and biomass were also detected on the painted metal roofs; however, the loss of solar reflectance was less than 5% for the painted metal roofs. The chemistry of the PVDF paint resin system uses similar organic film bonding to that responsible for Teflon , making it extremely chemical resistant and dirt shedding. Miller and Rudolph (2003) found the PVDF painted metals maintained solar reflectance even after 30 years of climatic exposure. Therefore the reduction of roof reflectance is closely related to the composition of the roof and to the chemical profile of the contaminants soiling the roof. Contaminants collected from samples of roof products exposed at seven California weathering sites were analyzed for elements and carbons to characterize the chemical profile of the particles soiling each roof sample and to identify those elements that degrade or enhance solar reflectance. The losses in solar reflectance varied from site to site and also varied at a give site based on the color of the coupon. The least drop in reflectance was observed in the alpine climate of McArthur while the largest drop occurred in sites near urban development. Light color samples were soiled after just one year of exposure. The darker color coupons did not show the same seasonal variations in solar reflectance as observed for the lighter colors. However, after an additional year of exposure the samples at all sites regained most of their solar reflectance due to rain and/or wind washing. The loss of reflectance appears cyclical with the onset of seasons having more rainfall. Solar reflectance of the cool pigmented coupons always exceeded that of the conventional pigmented coupons. Climatic soiling did not cause the cool pigmented roof coupons to lose any more solar reflectance than their conventional pigmented counterparts. The effect of roof slope appears to have more of an effect on lighter color roofs whose solar reflectance exceeds at least 0.5 and visually shows the accumulation of airborne contaminants. The thermal emittance remained invariant with time and location and was therefore not affected by climatic soiling. A thin-film deposition model was developed based on first principles, which simulates light interaction with a soiled substrate. This model was used in combination with the measured data to determine the solar absorptance and reflectance of particulate matter at each of the sites calculated using least squares fitting routines. Principal Component Analysis was used to determine the most important combinations of chemicals correlated with changes in solar absorption. Linear regression helped extract an approximate correlation using chromium, iron and elemental carbon concentrations. It appears that chromium ranks first, iron ranks second, and elemental carbon ranks third in importance to soil absorptance in the data« less

Uncertainty in vegetation products derived from field spectral measurements: an error budget approach

NASA Astrophysics Data System (ADS)

Anderson, K.; Dungan, J. L.

2008-12-01

One of the biggest challenges in the use of proximal remote sensing methods continues to be the accurate, reproducible characterisation of natural surface reflectance properties measured in the solar radiation environment. Complexities in such measurements arise from differences in instrument type, field-of-view, atmospheric conditions, solar illumination and measurement angles and uncertainty in the calibration of reference sources used. Three GER 1500 spectroradiometers were used to measure the reflectance of a short sward grass canopy. A full laboratory assessment was first carried out to characterise instrument uncertainty. Wavelength-dependent patterns in noise equivalent delta radiances (NEdL) were similar for all three instruments, (less than 1 W m-2 sr μm-1 in the range 400-1000 nm). The spectroradiometers were then used in the field, each in a single-beam configuration and two in a dual-field- of-view configuration to compare their field reproducibility to laboratory measurements. Hemispherical-conical reflectance factors (HCRF) were collected in clear sky conditions of a grass (Pennisetum clandestinum) canopy. Two measurement dates were used where skies were clean (diffuse-to-global (DG) irradiance ratios < 0.13) and stable (standard deviation in DG < 0.001). Spectra were collected at nadir during the two- hour period spanning solar noon with a 2° range in solar zenith angles. A reproducible method was used which enabled positioning of instruments to within 1° precision in the azimuthal direction and with no movement in zenithal position. Ten measurements were taken with each sensor head, from a calibrated optical grade Spectralon panel (99% reflecting), the grass target, and a control surface -- a grey, 75% Spectralon panel. After each sequence the sensor heads were changed. On each date, the sequence of measurements was repeated. Field results showed standard uncertainties (u) of less than 0.01 (SD in HCRF) for the grey panel and less than 0.015 for vegetation. The grey panel data showed a wavelength- dependent pattern, similar to the NEdL laboratory trend, but subsequent error propagation of laboratory- derived NEdL through to a reflectance factor showed that the laboratory characterisation was unable to account for all of the uncertainty measured in the field. Therefore the estimate of u gained from field data more closely represents the reproducibility of measurements where atmospheric, solar zenith and instrument-related uncertainties are combined. Results on vegetation u showed a stronger wavelength dependency with higher standard uncertainties beyond the vegetation red-edge than in visible wavelengths (maximum = 0.015 at 800 nm, and 0.004 at 550nm). The results demonstrate that standard uncertainties of field reflectance data have a spectral dependence and exceed laboratory-derived estimates of instrument "noise". Uncertainty of this type must be taken into account when statistically testing for differences in field spectra. Improved reporting of standard uncertainties from field experiments will foster progress in remote sensing science.

Fabrication of multijunction high voltage concentrator solar cells by integrated circuit technology

NASA Technical Reports Server (NTRS)

Valco, G. J.; Kapoor, V. J.; Evans, J. C., Jr.; Chai, A.-T.

1981-01-01

Standard integrated circuit technology has been developed for the design and fabrication of planar multijunction (PMJ) solar cell chips. Each 1 cm x 1 cm solar chip consisted of six n(+)/p, back contacted, internally series interconnected unit cells. These high open circuit voltage solar cells were fabricated on 2 ohm-cm, p-type 75 microns thick, silicon substrates. A five photomask level process employing contact photolithography was used to pattern for boron diffusions, phorphorus diffusions, and contact metallization. Fabricated devices demonstrated an open circuit voltage of 3.6 volts and a short circuit current of 90 mA at 80 AMl suns. An equivalent circuit model of the planar multi-junction solar cell was developed.

Thin n-i-p silicon solar cell

NASA Technical Reports Server (NTRS)

Meulenberg, A., Jr.; Allison, J. F.; Arndt, R. A.

1980-01-01

A space solar cell concept which combines high cell output with low diffusion length damage coefficients is presented for the purpose of reducing solar cell susceptibility to degradation from the radiation environment. High resistivity n-i-p silicon solar cells ranging from upward of 83 micron-cm were exposed to AM0 ultraviolet illumination. It is shown that high resistivity cells act as extrinsic devices under dark conditions and as intrinsic devices under AM0 illumination. Resistive losses in thin n-i-p cells are found to be comparable to those in low resistivity cells. Present voltage limitations appear to be due to generation and recombination in the diffused regions.

Solar System Connections to the Organic Material In the ISM

NASA Technical Reports Server (NTRS)

Pendleton, Yvonne J.

2003-01-01

The organic component of the interstellar medium (ISM) has relevance to the formation of the early solar nebula, since our solar system formed out of ISM material. Comparisons of near infrared spectra of the diffuse ISM dust with those of primitive solar system bodies (such as comets and meteorites) show a remarkable similarity, suggesting that perhaps some of the interstellar organic material made its way, unaltered, into our solar system. Tracing the interstellar organic material is necessary to understand how these materials may be important links in the development of prebiotic phenomena. Studies of the ISM reveal that the organic refractory component of the diffuse ISM is largely hydrocarbon in nature, possessing little N or O, with carbon distributed between the aromatic and aliphatic forms. There is a strong similarity in the near IR spectra of the diffuse ISM (the 3.4 micron hydrocarbon bands) and those seen in the Murchison and Orgueil meteorites, however, detailed comparisons at longer wavelengths reveal critical dissimilarities. Here we will present comparisons and discussion of relevant spectra. As we continue to explore, we will gain insight into the connection between planetesimals in the solar system and chemistry in the dusty space between the stars.

Diffuse reflectance spectroscopy of pre- and post-treated oral submucous fibrosis: an in vivo study

NASA Astrophysics Data System (ADS)

Sivabalan, S.; Ponranjini Vedeswari, C.; Jayachandran, S.; Koteeswaran, D.; Pravda, C.; Aruna, P.; Ganesan, S.

2010-02-01

Oral submucous fibrosis (OSF) is a high risk precancerous condition characterized by changes in the connective tissue fibers of the lamina propria and deeper parts leading to stiffness of the mucosa and restricted mouth opening, fibrosis of the lining mucosa of the upper digestive tract involving the oral cavity, oro- and hypo-pharynx and the upper two-thirds of the oesophagus. Optical reflectance measurements have been used to extract diagnostic information from a variety of tissue types, in vivo. We apply diffuse reflectance spectroscopy to quantitatively monitor tumour response to chemotherapy. Twenty patients with submucous fibrosis were diagnosed with diffuse reflectance spectroscopy and treated with the chemotherapy drug, Dexamethasone sodium phosphate and Hyaluronidase injection for seven weeks and after the treatment they were again subjected to the diffuse reflectance spectroscopy. The major observed spectral alterations on pre and post treated submucous fibrosis is an increase in the diffuse reflectance from 450 to 600 nm. Normal mucosa has showed higher reflectance when compared to the pre and post-treated cases. The spectral changes were quantified and correlated to conventional diagnostic results viz., maximum mouth opening, tongue protrusion and burning sensation. The results of this study suggest that the diffuse reflectance spectroscopy may also be considered as complementary optical techniques to monitor oral tissue transformation.

Photovoltaic Performance and Interface Behaviors of Cu(In,Ga)Se2 Solar Cells with a Sputtered-Zn(O,S) Buffer Layer by High-Temperature Annealing.

PubMed

Wi, Jae-Hyung; Kim, Tae Gun; Kim, Jeong Won; Lee, Woo-Jung; Cho, Dae-Hyung; Han, Won Seok; Chung, Yong-Duck

2015-08-12

We selected a sputtered-Zn(O,S) film as a buffer material and fabricated a Cu(In,Ga)Se2 (CIGS) solar cell for use in monolithic tandem solar cells. A thermally stable buffer layer was required because it should withstand heat treatment during processing of top cell. Postannealing treatment was performed on a CIGS solar cell in vacuum at temperatures from 300-500 °C to examine its thermal stability. Serious device degradation particularly in VOC was observed, which was due to the diffusion of thermally activated constituent elements. The elements In and Ga tend to out-diffuse to the top surface of the CIGS, while Zn diffuses into the interface of Zn(O,S)/CIGS. Such rearrangement of atomic fractions modifies the local energy band gap and band alignment at the interface. The notch-shape induced at the interface after postannealing could function as an electrical trap during electron transport, which would result in the reduction of solar cell efficiency.

Influence of diffuse reflectance measurement accuracy on the scattering coefficient in determination of optical properties with integrating sphere optics (a secondary publication).

PubMed

Horibe, Takuro; Ishii, Katsunori; Fukutomi, Daichi; Awazu, Kunio

2015-12-30

An estimation error of the scattering coefficient of hemoglobin in the high absorption wavelength range has been observed in optical property calculations of blood-rich tissues. In this study, the relationship between the accuracy of diffuse reflectance measurement in the integrating sphere and calculated scattering coefficient was evaluated with a system to calculate optical properties combined with an integrating sphere setup and the inverse Monte Carlo simulation. Diffuse reflectance was measured with the integrating sphere using a small incident port diameter and optical properties were calculated. As a result, the estimation error of the scattering coefficient was improved by accurate measurement of diffuse reflectance. In the high absorption wavelength range, the accuracy of diffuse reflectance measurement has an effect on the calculated scattering coefficient.

Development of lithium diffused radiation resistant solar cells, part 2

NASA Technical Reports Server (NTRS)

Payne, P. R.; Somberg, H.

1971-01-01

The work performed to investigate the effect of various process parameters on the performance of lithium doped P/N solar cells is described. Effort was concentrated in four main areas: (1) the starting material, (2) the boron diffusion, (3) the lithium diffusion, and (4) the contact system. Investigation of starting material primarily involved comparison of crucible grown silicon (high oxygen content) and Lopex silicon (low oxygen content). In addition, the effect of varying growing parameters of crucible grown silicon on lithium cell output was also examined. The objective of the boron diffusion studies was to obtain a diffusion process which produced high efficiency cells with minimal silicon stressing and could be scaled up to process 100 or more cells per diffusion. Contact studies included investigating sintering of the TiAg contacts and evaluation of the contact integrity.

Solar concentrator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Melchior, B.

1984-04-03

A solar concentrator comprises a solid block of a transparent material having a planar incident surface positioned to receive solar rays and, opposite this surface, a curved reflective surface so that the material of the block completely fills the space between these surfaces. At the incident surface an absorber is provided and the curvature of the reflective surface is such that it is at least partly parabolical and adapted to reflect solar rays traversing the body through the body again to the absorber.

Evaluation of Moderate-Resolution Imaging Spectroradiometer (MODIS) Snow Albedo Product (MCD43A) over Tundra

NASA Technical Reports Server (NTRS)

Wang, Zhuosen; Schaaf, Crystal B.; Chopping, Mark J.; Strahler, Alan H.; Wang, Jindi; Roman, Miguel O.; Rocha, Adrian V.; Woodcock, Curtis E.; Shuai, Yanmin

2012-01-01

This study assesses the MODIS standard Bidirectional Reflectance Distribution Function (BRDF)/Albedo product, and the daily Direct Broadcast BRDF/Albedo algorithm at tundra locations under large solar zenith angles and high anisotropic diffuse illumination and multiple scattering conditions. These products generally agree with ground-based albedo measurements during the snow cover period when the Solar Zenith Angle (SZA) is less than 70deg. An integrated validation strategy, including analysis of the representativeness of the surface heterogeneity, is performed to decide whether direct comparisons between field measurements and 500- m satellite products were appropriate or if the scaling of finer spatial resolution airborne or spaceborne data was necessary. Results indicate that the Root Mean Square Errors (RMSEs) are less than 0.047 during the snow covered periods for all MCD43 albedo products at several Alaskan tundra areas. The MCD43 1- day daily albedo product is particularly well suited to capture the rapidly changing surface conditions during the spring snow melt. Results also show that a full expression of the blue sky albedo is necessary at these large SZA snow covered areas because of the effects of anisotropic diffuse illumination and multiple scattering. In tundra locations with dark residue as a result of fire, the MODIS albedo values are lower than those at the unburned site from the start of snowmelt.

Applications of fourier transform infrared spectroscopy to surface analysis problems 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Powell, G.L.; Milosevic, M.

Applications of infrared spectroscopy to surface analysis are described in terms of the combined use of a number of techniques to solve specific surface analysis problems involving both qualitative and quantitative analysis of surface species. Emphasis is placed on the characterization of both the substrate and the surface species and the application of this to the monitoring of surface processes and the inspection of manufactured items. Lithium Hydride has been studied using remote analysis by diffuse reflectance in glove boxes containing very pure argon or controlled moisture levels with robot-operated gravimetric monitoring. These experiments are supported by internal reflectance andmore » diffuse reflectance measurements in spectrometer sample compartments to characterize the reactants. Beryllium oxide has been studied using an evacuable diffuse reflectance cell to determine the effects of vacuum baking reexposure to moisture on the surface hydroxyl species. Diffuse reflectance and emission measurements have been used to monitor the curing and reaction of environmental gases with composite materials such as graphite-expoxy structures. A direct comparison of diffuse reflectance and emission spectra was done using a barrel ellipsoid diffuse reflectance/emission detector and Spectropus optical transfer system. Grazing-incidence external-reflectance with p-polarized light was used to study the oxidation in room air of polished uranium coupons. The absorption band at 570 cm{sup {minus}1} was used to monitor the extent of oxidation with a resolution of approximately one monolayer of UO{sub 2} and to distinguish the parabolic, linear, and breakaway corrosion domains. External reflectance is compared with diffuse reflectance as a method for stain analysis and for measuring the effects of H{sub 2}O in UO{sub 2} corrosion films.« less

Applications of fourier transform infrared spectroscopy to surface analysis problems 2. Revision 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Powell, G.L.; Milosevic, M.

Applications of infrared spectroscopy to surface analysis are described in terms of the combined use of a number of techniques to solve specific surface analysis problems involving both qualitative and quantitative analysis of surface species. Emphasis is placed on the characterization of both the substrate and the surface species and the application of this to the monitoring of surface processes and the inspection of manufactured items. Lithium Hydride has been studied using remote analysis by diffuse reflectance in glove boxes containing very pure argon or controlled moisture levels with robot-operated gravimetric monitoring. These experiments are supported by internal reflectance andmore » diffuse reflectance measurements in spectrometer sample compartments to characterize the reactants. Beryllium oxide has been studied using an evacuable diffuse reflectance cell to determine the effects of vacuum baking reexposure to moisture on the surface hydroxyl species. Diffuse reflectance and emission measurements have been used to monitor the curing and reaction of environmental gases with composite materials such as graphite-expoxy structures. A direct comparison of diffuse reflectance and emission spectra was done using a barrel ellipsoid diffuse reflectance/emission detector and Spectropus optical transfer system. Grazing-incidence external-reflectance with p-polarized light was used to study the oxidation in room air of polished uranium coupons. The absorption band at 570 cm{sup {minus}1} was used to monitor the extent of oxidation with a resolution of approximately one monolayer of UO{sub 2} and to distinguish the parabolic, linear, and breakaway corrosion domains. External reflectance is compared with diffuse reflectance as a method for stain analysis and for measuring the effects of H{sub 2}O in UO{sub 2} corrosion films.« less

A Study of Fermi Acceleration of Suprathermal Solar Wind Ions

NASA Astrophysics Data System (ADS)

Freeman, Theodore James

The Wind spacecraft has observed numerous sunward bursts of ~2 MeV ions upstream of the Earth's bow shock. The bursts typically last several minutes at the highest energies, but they can last for tens of minutes at intermediate energies (tens to hundreds of keV). The MeV ions are not protons or alpha particles, and are probably oxygen ions. There are two possible sources of these particles: Fermi acceleration of solar wind ions, and ring current particles which have escaped from the Earth's magnetosphere. In this dissertation, Wind observations and numerical particle simulations of Fermi acceleration are presented which demonstrate that suprathermal solar wind O6+ ions are the most likely source of these bursts. Since the Fermi mechanism accelerates all ions to approximately the same ratio of energy to charge, H+ and He2+ ions are accelerated to much lower energies than O6+ ions. In this model, suprathermal ions are reflected between the bow shock and rotations in the interplanetary magnetic field (IMF) upstream of the shock, gaining energy due to the relative motion of the reflecting magnetic structures. Each burst either coincides with or is closely followed by a large IMF rotation. By using measured magnetic field data, the timing of the bursts detected by Wind is precisely reproduced in the simulation. The energy spectra observed by Wind are also reproduced by adding H+ , He2+ , and O6+ fluxes together, and assuming that there is an increase of ~2 orders of magnitude in the high energy tail of the solar wind oxygen distribution. An enhancement of this order of magnitude in CNO group ions was measured by the ion composition experiment on Wind in association with these bursts. An examination of the magnetospheric escape model shows that while escaping O+ ions can account for some features of the data, such as the longer bursts of intermediate energy ions, it cannot account for the short duration ~2 MeV bursts themselves, because O+ ions scatter diffusively in the solar wind. This study concludes by predicting that ion composition and charge state measurements will show these bursts to be solar wind O6+ ions.

Spectral reflectance properties of black chrome for use as a solar selective coating

NASA Technical Reports Server (NTRS)

Mcdonald, G. E.

1974-01-01

The NASA-Lewis Research Center has determined that a widely available commercially electroplated decorative finish known as black chrome has desirable solar selective properties. Black chrome electroplated coating has high absorbtance in the solar spectrum and low emissivity in the 250 F blackbody thermal spectrum. The spectral reflectance properties of a commercially prepared black chrome on steel have been measured. Values are presented for reflectance of the black chrome, and compared with the reflectance of black paint and with two available samples of black nickel which had been prepared for solar selective properties. The reflectance of black chrome, of the two black nickels, and of black paint integrated over the solar spectrum for air mass 2 were 0.132, 0.123, 0.133, and 0.033, respectively. The reflectance of the black chrome, two black nickels, and of the black paint integrated over the blackbody spectrum for 250 F from 3 to 15 microns are 0.912, 0.934, 0.891, and 0.033, respectively. These reflectance measurements indicate absorptivity-to-emissivity values of 9.8, 13.8, 8.0, and 1.00, respectively.

Power generating reflective-type liquid crystal displays using a reflective polariser and a polymer solar cell.

PubMed

Ho Huh, Yoon; Park, Byoungchoo

2015-06-23

We herein report the results of a study of a power generating reflective-type liquid crystal display (LCD), composed of a 90° twisted nematic (TN) LC cell attached to the top of a light-absorbing polymer solar cell (PSC), i.e., a Solar-LCD. The PSC consisted of a polymer bulk-heterojunction photovoltaic (PV) layer of poly[[9-(1-octylnonyl)-9H-carbazole-2,7-diyl]-2,5-thiophenediyl-2,1,3-benzothiadiazole-4,7-diyl-2,5-thiophenediyl] and [6,6]-phenyl C71 butyric acid methyl ester (PCDTBT:PCBM70), and showed a high power conversion efficiency of about 5%. In order to improve the visibility of the Solar-LCD, between the TN-LC and the PV cells we inserted a reflective polariser of a giant birefringent optical (GBO) film. The reflectivity from the Solar-LCD was observed to be considerably increased by more than 13-15% under illumination by visible light. The Solar-LCD also exhibited a significantly improved contrast ratio of more than 17-19. We believe there is a clear case for using such Solar-LCDs in new power-generating reflective-type displays; taken as a whole these results also demonstrate the possibility of their application in a number of energy-harvesting opto-electrical display devices.

Improved atmospheric 3D BSDF model in earthlike exoplanet using ray-tracing based method

NASA Astrophysics Data System (ADS)

Ryu, Dongok; Kim, Sug-Whan; Seong, Sehyun

2012-10-01

The studies on planetary radiative transfer computation have become important elements to disk-averaged spectral characterization of potential exoplanets. In this paper, we report an improved ray-tracing based atmospheric simulation model as a part of 3-D earth-like planet model with 3 principle sub-components i.e. land, sea and atmosphere. Any changes in ray paths and their characteristics such as radiative power and direction are computed as they experience reflection, refraction, transmission, absorption and scattering. Improved atmospheric BSDF algorithms uses Q.Liu's combined Rayleigh and aerosol Henrey-Greenstein scattering phase function. The input cloud-free atmosphere model consists of 48 layers with vertical absorption profiles and a scattering layer with their input characteristics using the GIOVANNI database. Total Solar Irradiance data are obtained from Solar Radiation and Climate Experiment (SORCE) mission. Using aerosol scattering computation, we first tested the atmospheric scattering effects with imaging simulation with HRIV, EPOXI. Then we examined the computational validity of atmospheric model with the measurements of global, direct and diffuse radiation taken from NREL(National Renewable Energy Laboratory)s pyranometers and pyrheliometers on a ground station for cases of single incident angle and for simultaneous multiple incident angles of the solar beam.

Preparation and characterization of Bi-doped TiO{sub 2} and its solar photocatalytic activity for the degradation of isoproturon herbicide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddy, Police Anil Kumar; Srinivas, Basavaraju; Kala, Pruthu

Highlights: {yields} Visible active Bi-TiO{sub 2} photocatalyst preparation and thorough charaterization. {yields} Bi-TiO{sub 2} shows high activity for isoproturon degradation under solar light irradiation. {yields} The spectral response of TiO{sub 2} shifts from UV to visible light region by Bi doping. {yields} Bi{sup 3+{delta}+} species are playing a vital role in minimizing e{sup -}/h{sup +} recombination. -- Abstract: Bi-doped TiO{sub 2} catalyst was prepared by sol-gel method and was characterized by thermo gravimetric analysis (TGA), X-ray diffraction spectra (XRD), X-ray photo electronic spectroscopy (XPS), UV-Vis diffused reflectance spectra (DRS), photoluminescence spectra (PLS), transmission electron microscopy (TEM), energy dispersive analysis ofmore » X-rays (EDAX) and BET surface area. The photocatalytic activity of the catalysts were evaluated for the degradation of isoproturon herbicide under solar light irradiation. The UV-Visible DRS of Bi-doped TiO{sub 2} showed red shift in optical absorption. The presence of Bi{sup 3+{delta}+} species are playing a vital role in minimizing the electron hole recombination resulting higher activity compared to bare TiO{sub 2}.« less

Photovoltaic characteristics of natural light harvesting dye sensitized solar cells.

PubMed

Hafez, H S; Shenouda, S S; Fadel, M

2018-03-05

In this work of research, anthocyanin as a natural dye obtained from raspberry fruits, was used and tested as a photon harvesting/electron donating dye in titanium dioxide nanoparticle-based DSSCs. A working photoelectrode made from TiO 2 nanoparticles with an average particle size (10-40nm) that is coated on Florine doped tin-oxide substrate, was prepared via a simple and low cost hydrothermal method. A detailed structural and morphological analysis of the TiO 2 photoactive electrode was investigated by X-ray diffraction (XRD), diffuse reflectance spectrometer, transmission electron microscope (TEM) and scanning electron microscope (SEM). Complete photovoltaic characteristics including (current, voltage, outpower, and responsivity) of the natural anthocyanin based dye sensitized solar cell have been investigated under different illumination intensity ranging from 10 to 100mW.cm -2 . The cell responsivity and efficiency of the fabricated solar cell under different illumination intensity were found to be in the range (R=15.6-23.8mA.W -1 and η=0.13-0.25) at AM=1.5 conditions. This study is important for enhancing the future applications of the promising DSSC technology. Copyright © 2017 Elsevier B.V. All rights reserved.

Electrospun Conjugated Polymer/Fullerene Hybrid Fibers: Photoactive Blends, Conductivity through Tunneling-AFM, Light Scattering, and Perspective for Their Use in Bulk-Heterojunction Organic Solar Cells

DOE PAGES

Yang, Zhenhua; Moffa, Maria; Liu, Ying; ...

2018-01-25

Hybrid conjugated polymer/fullerene filaments based on MEH-PPV/PVP/PCBM were prepared by electrospinning, and their properties were assessed by scanning electron, atomic and lateral-force, tunneling, and confocal microscopies, as well as by attenuated-total-reflection Fourier transform infrared spectroscopy, photoluminescence quantum yield, and spatially resolved fluorescence. Highlighted features include the ribbon shape of the realized fibers and the persistence of a network serving as a template for heterogeneous active layers in solar cell devices. A set of favorable characteristics is evidenced in this way in terms of homogeneous charge-transport behavior and formation of effective interfaces for diffusion and dissociation of photogenerated excitons. The interactionmore » of the organic filaments with light, exhibiting specific light-scattering properties of the nanofibrous mat, might also contribute to spreading incident radiation across the active layers, thus potentially enhancing photovoltaic performance. Finally, this method might be applied to other electron donor–electron acceptor material systems for the fabrication of solar cell devices enhanced by nanofibrillar morphologies embedding conjugated polymers and fullerene compounds.« less

Electrospun Conjugated Polymer/Fullerene Hybrid Fibers: Photoactive Blends, Conductivity through Tunneling-AFM, Light Scattering, and Perspective for Their Use in Bulk-Heterojunction Organic Solar Cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Zhenhua; Moffa, Maria; Liu, Ying

Hybrid conjugated polymer/fullerene filaments based on MEH-PPV/PVP/PCBM were prepared by electrospinning, and their properties were assessed by scanning electron, atomic and lateral-force, tunneling, and confocal microscopies, as well as by attenuated-total-reflection Fourier transform infrared spectroscopy, photoluminescence quantum yield, and spatially resolved fluorescence. Highlighted features include the ribbon shape of the realized fibers and the persistence of a network serving as a template for heterogeneous active layers in solar cell devices. A set of favorable characteristics is evidenced in this way in terms of homogeneous charge-transport behavior and formation of effective interfaces for diffusion and dissociation of photogenerated excitons. The interactionmore » of the organic filaments with light, exhibiting specific light-scattering properties of the nanofibrous mat, might also contribute to spreading incident radiation across the active layers, thus potentially enhancing photovoltaic performance. Finally, this method might be applied to other electron donor–electron acceptor material systems for the fabrication of solar cell devices enhanced by nanofibrillar morphologies embedding conjugated polymers and fullerene compounds.« less

Structural investigation of MF, RF and DC sputtered Mo thin films for backside photovoltaic electrode

NASA Astrophysics Data System (ADS)

Małek, Anna K.; Marszałek, Konstanty W.; Rydosz, Artur M.

2016-12-01

Recently photovoltaics attracts much attention of research and industry. The multidirectional studies are carried out in order to improve solar cells performance, the innovative materials are still searched and existing materials and technology are optimized. In the multilayer structure of CIGS solar cells molybdenum (Mo) layer is used as a back contact. Mo layers meet all requirements for back side electrode: low resistivity, good adhesion to the substrate, high optical reflection in the visible range, columnar structure for Na ions diffusion, formation of an ohmic contact with the ptype CIGS absorber layer, and high stability during the corrosive selenization process. The high adhesion to the substrate and low resistivity in single Mo layer is difficult to be achieved because both properties depend on the deposition parameters, particularly on working gas pressure. Therefore Mo bilayers are applied as a back contact for CIGS solar cells. In this work the Mo layers were deposited by medium frequency sputtering at different process parameters. The effect of substrate temperature within the range of 50°C-200°C and working gas pressure from 0.7 mTorr to 7 mTorr on crystalline structure of Mo layers was studied.

Realization of single-phase BaSi2 films by vacuum evaporation with suitable optical properties and carrier lifetime for solar cell applications

NASA Astrophysics Data System (ADS)

Hara, Kosuke O.; Nakagawa, Yoshihiko; Suemasu, Takashi; Usami, Noritaka

2015-07-01

We have realized BaSi2 films by a simple vacuum evaporation technique for solar cell applications. X-ray diffraction analysis shows that single-phase BaSi2 films are formed on alkali-free glass substrates at 500 and 600 °C while impurity phases coexist on quartz or soda-lime glass substrates or at a substrate temperature of 400 °C. The mechanism of film growth is discussed by analyzing the residue on the evaporation boat. An issue on the fabricated films is cracking due to thermal mismatch, as observed by secondary electron microscopy. Optical characterizations by transmittance and reflectance spectroscopy show that the evaporated films have high absorption coefficients, reaching 2 × 104 cm-1 for a photon energy of 1.5 eV, and have indirect absorption edges of 1.14-1.21 eV, which are suitable for solar cells. The microwave-detected photoconductivity decay measurement reveals that the carrier lifetime is approximately 0.027 µs, corresponding to the diffusion length of 0.84 µm, which suggests the potential effective usage of photoexcited carriers.

Preparation of Cu2ZnSnS4 nano-crystalline powder by mechano-chemical method

NASA Astrophysics Data System (ADS)

Alirezazadeh, Farzaneh; Sheibani, Saeed; Rashchi, Fereshteh

2018-01-01

Copper zinc tin sulfide (Cu2ZnSnS4, CZTS) is one of the most promising ceramic materials as an absorber layer in solar cells due to its suitable band gap, high absorption coefficient and non-toxic and environmental friendly constituent elements. In this work, nano-crystalline CZTS powder was synthesized by mechanical milling. Elemental powders of Cu, Zn, Sn and were mixed in atomic ratio of 2:1:1:4 according to the stoichiometry of Cu2ZnSnS4 and then milled in a planetary high energy ball mill under argon atmosphere. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffusion reflectance spectroscopy (DRS). XRD results confirm the formation of single-phase CZTS with kesterite structure after 20 h of milling. Also, the mean crystallite size was about 35 nm. SEM results show that after 20 h of milling, the product has a relatively uniform particle size distribution. Optical properties of the product indicate that the band gap of prepared CZTS is 1.6 eV which is near to the optimum value for photovoltaic solar cells showing as a light absorber material in solar energy applications.

The measurement and analysis of normal incidence solar UVB radiation and its application to the photoclimatherapy protocol for psoriasis at the Dead Sea, Israel.

PubMed

Kudish, Avraham I; Harari, Marco; Evseev, Efim G

2011-01-01

The broad-band normal incidence UVB beam radiation has been measured at Neve Zohar, Dead Sea basin, using a prototype tracking instrument composed of a Model 501A UV-Biometer mounted on an Eppley Solar Tracker Model St-1. The diffuse and beam fraction of the solar global UVB radiation have been determined using the concurrently measured solar global UVB radiation. The diffuse fraction was observed to exceed 80% throughout the year. The application of the results of these measurements to the possible revision of the photoclimatherapy protocol for psoriasis patients at the Dead Sea medical spas is now under investigation. The suggested revision would enable the sun-exposure treatment protocol to take advantage of the very high diffuse fraction by allowing the patient to receive the daily dose of UVB radiation without direct exposure to the sun, viz. receive the diffuse UVB radiation under a sunshade. This would require an increase in sun-exposure time intervals, as the UVB radiation intensity beneath a sunshade is less than that on an exposed surface. © 2010 The Authors. Photochemistry and Photobiology © 2010 The American Society of Photobiology.

Comparative radiation resistance, temperature dependence and performance of diffused junction indium phosphide solar cells

NASA Technical Reports Server (NTRS)

Weinberg, I.; Swartz, C. K.; Hart, R. E., Jr.; Ghandhi, S. K.; Borrego, J. M.

1987-01-01

Indium phosphide solar cells whose p-n junctions were processed by the open tube capped diffusion and by the closed tube uncapped diffusion of sulfur into Czochralski-grown p-type substrates are compared. Differences found in radiation resistance were attributed to the effects of increased base dopant concentration. Both sets of cells showed superior radiation resistance to that of gallium arsenide cells, in agreement with previous results. No correlation was, however, found between the open-circuit voltage and the temperature dependence of the maximum power.

The Characteristics of Thin Magnetic Flux Tubes in the Lower Solar Atmosphere Observed by Hinode/SOT in the G band and in Ca II H Bright Points

NASA Astrophysics Data System (ADS)

Xiong, Jianping; Yang, Yunfei; Jin, Chunlan; Ji, Kaifan; Feng, Song; Wang, Feng; Deng, Hui; Hu, Yu

2017-12-01

Photospheric bright points (PBPs) and chromospheric bright points (CBPs) reflect the cross sections of magnetic flux tubes at different heights of the lower solar atmosphere. We aim to study the fine 3D structures and transportation dynamics of the magnetic flux tubes using G-band and simultaneous Ca II H image-series from the Solar Optical Telescope (SOT) on board Hinode. A 3D track-while-detect method is proposed to detect and track PBPs and CBPs. The mean values of equivalent diameters, maximum intensity contrasts, transverse velocities, motion ranges, motion types, and diffusion indices of PBPs and CBPs are 180 ± 20 and 210 ± 30 km, 1.0+/- 0.1< {I}{QS\\_G}> and 1.2+/- 0.1< {I}{QS\\Ca}> , 1.6 ± 0.8 and 2.7 ± 1.4 km s‑1, 1.5 ± 0.6 and 1.7 ± 0.8, 0.8 ± 0.2 and 0.6 ± 0.2, and 1.7 ± 0.7 and 1.3 ± 0.7, respectively. Moreover, the ratios of each CBP characteristics to its corresponding PBP are derived to explore the change rates of the flux tubes. The corresponding ratios are 1.2 ± 0.2, 1.2 ± 0.1, 1.9 ± 0.1, 1.4 ± 0.3, 0.7 ± 0.2, and 0.9 ± 0.4, respectively. The statistical results imply that the majority magnetic flux tubes expand slightly with increasing solar height, look brighter than their surroundings, show a higher transverse velocity, a wider motion range, and a more erratic path, but the majority of the flux tubes diffuse slightly slower. The phenomenon might be explained by the conservation of momentum combined with a decrease in density. The more erratic path leads to a swing or twist of the flux tubes and therefore guides magnetohydrodynamic waves.

Photocatalytic activity of attapulgite-TiO2-Ag3PO4 ternary nanocomposite for degradation of Rhodamine B under simulated solar irradiation

NASA Astrophysics Data System (ADS)

He, Hongcai; Jiang, Zhuolin; He, Zhaoling; Liu, Tao; Li, Enzhu; Li, Bao-Wen

2018-01-01

An excellent ternary composite photocatalyst consisting of silver orthophosphate (Ag3PO4), attapulgite (ATP), and TiO2 was synthesized, in which heterojunction was formed between dissimilar semiconductors to promote the separation of photo-generated charges. The ATP/TiO2/Ag3PO4 composite was characterized by SEM, XRD, and UV-vis diffuse reflectance spectroscopy. The co-deposition of Ag3PO4 and TiO2 nanoparticles onto the surface of ATP forms a lath-particle structure. Compared with composite photocatalysts consisting of two phases, ATP/TiO2/Ag3PO4 ternary composite exhibits greatly improved photocatalytic activity for degradation of rhodamine B under simulated solar irradiation. Such ternary composite not only improves the stability of Ag3PO4, but also lowers the cost by reducing application amount of Ag3PO4, which provides guidance for the design of Ag3PO4- and Ag-based composites for photocatalytic applications.

A New Radiometric Calibration Paradigm for the OMPS Nadir Total Column and Profile Instruments

NASA Technical Reports Server (NTRS)

Heath, Donald; Georgiew, Georgi

2011-01-01

A fused silica Mie Scattering Diffuser (MSD) has been developed at Ball Aerospace & Technology Corp. that has measured characteristics which could be used to increase the accuracy of the spectral albedo calibration of the Ozone Mapping and Profiler Suite (OMPS) Nadir ozone total column and profile instrument by almost an order of magnitude. Measurements have been made of the optical characteristics on both natural and synthetic forms of fused silica MSDs. Preliminary measurements suggest that MSDs are useable in the solar reflective wavelength region from 250 nm to 3.7 m. To date synthetic and natural MSDs have been irradiated for 60 hours of UV radiation from a solar simulator, and synthetic MSDs have been irradiated with increasing doses of Co-60 gamma rays at 30, 500 krads up to 1.5 Mrads, and 30 krads of 200 MeV protons. The principal effects have been small loses in transmittance at wavelengths < 350 nm. The high energy particle irradiation measurements were provided by Neal Nickles and Dean Spieth.

Adsorptive and photocatalytic properties of S-doped SrTiO3 under simulated solar irradiation

NASA Astrophysics Data System (ADS)

Huynh, Phu Chi; Le, Vien Minh

2017-09-01

S-doped SrTiO3 (SSTO) nanoparticles were synthesized using the sol-gel method with Sr(NO3)2, n- Ti(OC4H9)4, and Thiourea as precursors. Several analytical techniques including XRD, SEM, BET were employed to characterize the physical properties of the product. High crystalline perovskite of SSTO powder was synthesized at 700 °C calcined temperature with the specific surface area of 20.71 m2/g. UV-Vis diffuse reflectance spectra results of STO and 5SSTO present band gap energy of 3.2 and 2.95 eV respectively. Photocatalytic activity was determined through the photodegradation of Congo Red at the initial concentrations of 70 ppm under simulated solar irradiation using 26W mercury lamp (120V - 60Hz). The decompositions of approximately 90.4% was obtained after 210 minutes of illumination. The photocatalyst was stable in aqueous solution that its photocatalytic activity was merely reduced by 9% even after 4 reusing iterations.

Back-junction back-contact n-type silicon solar cell with diffused boron emitter locally blocked by implanted phosphorus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Müller, Ralph, E-mail: ralph.mueller@ise.fraunhofer.de; Schrof, Julian; Reichel, Christian

2014-09-08

The highest energy conversion efficiencies in the field of silicon-based photovoltaics have been achieved with back-junction back-contact (BJBC) silicon solar cells by several companies and research groups. One of the most complex parts of this cell structure is the fabrication of the locally doped p- and n-type regions, both on the back side of the solar cell. In this work, we introduce a process sequence based on a synergistic use of ion implantation and furnace diffusion. This sequence enables the formation of all doped regions for a BJBC silicon solar cell in only three processing steps. We observed that implantedmore » phosphorus can block the diffusion of boron atoms into the silicon substrate by nearly three orders of magnitude. Thus, locally implanted phosphorus can be used as an in-situ mask for a subsequent boron diffusion which simultaneously anneals the implanted phosphorus and forms the boron emitter. BJBC silicon solar cells produced with such an easy-to-fabricate process achieved conversion efficiencies of up to 21.7%. An open-circuit voltage of 674 mV and a fill factor of 80.6% prove that there is no significant recombination at the sharp transition between the highly doped emitter and the highly doped back surface field at the device level.« less

Analysis of Al diffusion processes in TiN barrier layers for the application in silicon solar cell metallization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumm, J.; Samadi, H.; Chacko, R. V.

An evaporated Al layer is known as an excellent rear metallization for highly efficient solar cells, but suffers from incompatibility with a common solder process. To enable solar cell-interconnection and module integration, in this work the Al layer is complemented with a solder stack of TiN/Ti/Ag or TiN/NiV/Ag, in which the TiN layer acts as an Al diffusion barrier. X-ray photoelectron spectroscopy measurements prove that diffusion of Al through the stack and the formation of an Al{sub 2}O{sub 3} layer on the stack's surface are responsible for a loss of solderability after a strong post-metallization anneal, which is often mandatorymore » to improve contact resistance and passivation quality. An optimization of the reactive TiN sputter process results in a densification of the TiN layer, which improves its barrier quality against Al diffusion. However, measurements with X-ray diffraction and scanning electron microscopy show that small grains with vertical grain boundaries persist, which still offer fast diffusion paths. Therefore, the concept of stuffing is introduced. By incorporating oxygen into the grain boundaries of the sputtered TiN layer, Al diffusion is strongly reduced as confirmed by secondary ion mass spectroscopy profiles. A quantitative analysis reveals a one order of magnitude lower Al diffusion coefficient for stuffed TiN layers. This metallization system maintains its solderability even after strong post-metallization annealing at 425 °C for 15 min. This paper thus presents an industrially feasible, conventionally solderable, and long-term stable metallization scheme for highly efficient silicon solar cells.« less

Matrix operator theory of radiative transfer. 2: scattering from maritime haze.

PubMed

Kattawar, G W; Plass, G N; Catchings, F E

1973-05-01

Matrix operator theory is used to calculate the reflected and transmitted radiance of photons that have interacted with plane-parallel maritime haze layers. The results are presented for three solar zenith angles, three values of the surface albedo, and a range of optical thicknesses from very thin to very thick. The diffuse flux at the lower boundary and the cloud albedo are tabulated. The forward peak and other features in the single scattered phase function cause the radiance in many cases to be very different from that for Rayleigh scattering. In particular the variation of the radiance with both the zenith or nadir angle and the azimuthal angle is more marked and the relative limb darkening under very thick layers is greater for haze M than for Rayleigh scattering. The downward diffuse flux at the lower boundary for A = 0 is always greater and the cloud albedo is always less for haze M than for Rayleigh layers.

Gradient SiNO anti-reflective layers in solar selective coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ren, Zhifeng; Cao, Feng; Sun, Tianyi

A solar selective coating includes a substrate, a cermet layer having nanoparticles therein deposited on the substrate, and an anti-reflection layer deposited on the cermet layer. The cermet layer and the anti-reflection layer may each be formed of intermediate layers. A method for constructing a solar-selective coating is disclosed and includes preparing a substrate, depositing a cermet layer on the substrate, and depositing an anti-reflection layer on the cermet layer.

Use of ground-based telescopes in determining the composition of the surfaces of solar system objects

NASA Technical Reports Server (NTRS)

Mccord, T. B.; Adams, J. B.

1977-01-01

Recent evidence suggests that the way that the surfaces of the solar system objects reflect solar radiation is controlled by the composition and mineralogy of the surface materials. The way sunlight is reflected from the surface as a function of wavelength, i.e., the spectral reflectance, is the most important property. Laboratory efforts to use ground-based optical telescope measurements to determine the composition of the surfaces of the solar system objects are reviewed.

Atmospheric scattering corrections to solar radiometry

NASA Technical Reports Server (NTRS)

Box, M. A.; Deepak, A.

1979-01-01

Whenever a solar radiometer is used to measure direct solar radiation, some diffuse sky radiation invariably enters the detector's field of view along with the direct beam. Therefore, the atmospheric optical depth obtained by the use of Bouguer's transmission law (also called Beer-Lambert's law), that is valid only for direct radiation, needs to be corrected by taking account of the scattered radiation. This paper discusses the correction factors needed to account for the diffuse (i,e., singly and multiply scattered) radiation and the algorithms developed for retrieving aerosol size distribution from such measurements. For a radiometer with a small field of view (half-cone angle of less than 5 deg) and relatively clear skies (optical depths less than 0.4), it is shown that the total diffuse contribution represents approximately 1% of the total intensity.

Developments toward an 18% efficient silicon solar cell

NASA Technical Reports Server (NTRS)

Meulenberg, A., Jr.

1983-01-01

Limitations to increased open-circuit voltage were identified and experimentally verified for 0.1 ohm-cm solar cells with heavily doped emitters. After major reduction in the dark current contribution from the metal-silicon interface of the grid contacts, the surface recombination velocity of the oxide-silicon interface of shallow junction solar cells is the limiting factor. In deep junction solar cells, where the junction field does not aid surface collection, the emitter bulk is the limiting factor. Singly-diffused, shallow junction cells have been fabricated with open circuit voltages in excess of 645 mV. Double-diffusion shallow and deep junctions cells have displayed voltages above 650 mV. MIS solar cells formed on 0.1 ohm-cm substrates have exibited the lowest dark currents produced in the course of the contract work.

Predicting efficiency of solar cells based on transparent conducting electrodes

NASA Astrophysics Data System (ADS)

Kumar, Ankush

2017-01-01

Efficiency of a solar cell is directly correlated with the performance of its transparent conducting electrodes (TCEs) which dictates its two core processes, viz., absorption and collection efficiencies. Emerging designs of a TCE involve active networks of carbon nanotubes, silver nanowires and various template-based techniques providing diverse structures; here, voids are transparent for optical transmittance while the conducting network acts as a charge collector. However, it is still not well understood as to which kind of network structure leads to an optimum solar cell performance; therefore, mostly an arbitrary network is chosen as a solar cell electrode. Herein, we propose a new generic approach for understanding the role of TCEs in determining the solar cell efficiency based on analysis of shadowing and recombination losses. A random network of wires encloses void regions of different sizes and shapes which permit light transmission; two terms, void fraction and equivalent radius, are defined to represent the TCE transmittance and wire spacings, respectively. The approach has been applied to various literature examples and their solar cell performance has been compared. To obtain high-efficiency solar cells, optimum density of the wires and their aspect ratio as well as active layer thickness are calculated. Our findings show that a TCE well suitable for one solar cell may not be suitable for another. For high diffusion length based solar cells, the void fraction of the network should be low while for low diffusion length based solar cells, the equivalent radius should be lower. The network with less wire spacing compared to the diffusion length behaves similar to continuous film based TCEs (such as indium tin oxide). The present work will be useful for architectural as well as material engineering of transparent electrodes for improvisation of solar cell performance.

TURBULENCE IN THE SOLAR WIND MEASURED WITH COMET TAIL TEST PARTICLES

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeForest, C. E.; Howard, T. A.; Matthaeus, W. H.

2015-10-20

By analyzing the motions of test particles observed remotely in the tail of Comet Encke, we demonstrate that the solar wind undergoes turbulent processing enroute from the Sun to the Earth and that the kinetic energy entrained in the large-scale turbulence is sufficient to explain the well-known anomalous heating of the solar wind. Using the heliospheric imaging (HI-1) camera on board NASA's STEREO-A spacecraft, we have observed an ensemble of compact features in the comet tail as they became entrained in the solar wind near 0.4 AU. We find that the features are useful as test particles, via mean-motion analysismore » and a forward model of pickup dynamics. Using population analysis of the ensemble's relative motion, we find a regime of random-walk diffusion in the solar wind, followed, on larger scales, by a surprising regime of semiconfinement that we attribute to turbulent eddies in the solar wind. The entrained kinetic energy of the turbulent motions represents a sufficient energy reservoir to heat the solar wind to observed temperatures at 1 AU. We determine the Lagrangian-frame diffusion coefficient in the diffusive regime, derive upper limits for the small scale coherence length of solar wind turbulence, compare our results to existing Eulerian-frame measurements, and compare the turbulent velocity with the size of the observed eddies extrapolated to 1 AU. We conclude that the slow solar wind is fully mixed by turbulence on scales corresponding to a 1–2 hr crossing time at Earth; and that solar wind variability on timescales shorter than 1–2 hr is therefore dominated by turbulent processing rather than by direct solar effects.« less

An Overview of Suomi NPP VIIRS Calibration Maneuvers

NASA Technical Reports Server (NTRS)

Butler, James J.; Xiong, Xiaoxiong; Barnes, Robert A.; Patt, Frederick S.; Sun, Junqiang; Chiang, Kwofu

2012-01-01

The first Visible Infrared Imager Radiometer Suite (VIIRS) instrument was successfully launched on-board the Suomi National Polar-orbiting Partnership (SNPP) spacecraft on October 28, 2011. Suomi NPP VIIRS observations are made in 22 spectral bands, from the visible (VIS) to the long-wave infrared (LWIR), and are used to produce 22 Environmental Data Records (EDRs) with a broad range of scientific applications. The quality of these VIIRS EDRs strongly depends on the quality of its calibrated and geo-located Sensor Date Records (SDRs). Built with a strong heritage to the NASA's EOS MODerate resolution Imaging Spectroradiometer (MODIS) instrument, the VIIRS is calibrated on-orbit using a similar set of on-board calibrators (OBC), including a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system for the reflective solar bands (RSB) and a blackbody (BB) for the thermal emissive bands (TEB). On-orbit maneuvers of the SNPP spacecraft provide additional calibration and characterization data from the VIIRS instrument which cannot be obtained pre-launch and are required to produce the highest quality SDRs. These include multi-orbit yaw maneuvers for the characterization of SD and SDSM screen transmission, quasi-monthly roll maneuvers to acquire lunar observations to track sensor degradation in the visible through shortwave infrared, and a driven pitch-over maneuver to acquire multiple scans of deep space to determine TEB response versus scan angle (RVS). This paper pro-vides an overview of these three SNPP calibration maneuvers. Discussions are focused on their potential calibration and science benefits, pre-launch planning activities, and on-orbit scheduling and implementation strategies. Results from calibration maneuvers performed during the Intensive Calibration and Validation (ICV) period for the VIIRS sensor are illustrated. Also presented in this paper are lessons learned regarding the implementation of calibration spacecraft maneuvers on follow-on missions.

Postlaunch Assessment of the Response Versus Scan Angle for the Thermal Emissive Bands of Visible Infrared Imaging Radiometer Suite On-Board the Suomi National Polar-Orbiting Partnership Satellite

NASA Technical Reports Server (NTRS)

Wu, Aisheng; Xiong, Xiaoxiong; Chiang, Kwofu

2017-01-01

The visible infrared imaging radiometer suite (VIIRS) is a key sensor carried on the Suomi national polar-orbiting partnership (S-NPP) satellite, which was launched in October 2011. It has several on-board calibration components, including a solar diffuser and a solar diffuser stability monitor for the reflective solar bands, a V-groove blackbody for the thermal emissive bands (TEB), and a space view port for background subtraction. These on-board calibrators are located at fixed scan angles. The VIIRS response versus scan angle (RVS) was characterized prelaunch in lab ambient conditions and is currently used to characterize the on-orbit response for all scan angles relative to the calibrator scan angle. Since the RVS is vitally important to the quality of calibrated radiance products, several independent studies were performed to analyze the prelaunch RVS measurement data. A spacecraft level pitch maneuver was scheduled during the first 3 months of intensive Cal/Val. The S-NPP pitch maneuver provided a rare opportunity for VIIRS to make observations of deep space over the entire range of Earth view scan angles, which can be used to characterize the TEB RVS. This study provides our analysis of the pitch maneuver data and assessment of the derived TEB RVS by comparison with prelaunch results. In addition, the stability of the RVS after the first 5 years of operation is examined using observed brightness temperatures (BT) over a clear ocean at various angles of incidence (AOI). To reduce the impact of variations in the BT measurements, the daily overpasses collected over the ocean are screened for cloud contamination, normalized to the results obtained at the blackbody AOI, and averaged each year.

Early on-orbit calibration results from Aqua MODIS

NASA Astrophysics Data System (ADS)

Xiong, Xiaoxiong; Barnes, William L.

2003-04-01

Aqua MODIS, also known as the MODIS Flight Model 1 (FM1), was launched on May 4, 2002. It opened its nadir aperture door (NAD) on June 24, 2002, beginning its Earth observing mission. In this paper, we present early results from Aqua MODIS on-orbit calibration and characterization and assess the instrument's overall performance. MODIS has 36 spectral bands located on four focal plane assemblies (FPAs). Bands 1-19, and 26 with wavelengths from 0.412 to 2.1 microns are the reflective solar bands (RSB) that are calibrated on-orbit by a solar diffuser (SD). The degradation of the SD is tracked using a solar diffuser stability monitor (SDSM). The bands 20-25, and 27-36 with wavelengths from 3.75 to 14.5 microns are the thermal emissive bands (TEB) that are calibrated on-orbit by a blackbody (BB). Early results indicate that the on-orbit performance has been in good agreement with the predications determined from pre-launch measurements. Except for band 21, the low gain fire band, band 6, known to have some inoperable detectors from pre-launch characterization, and one noisy detector in band 36, all of the detectors' noise characterizations are within their specifications. Examples of the sensor's short-term and limited long-term responses in both TEB and RSB will be provided to illustrate the sensor's on-orbit stability. In addition, we will show some of the improvements that Aqua MODIS made over its predecessor, Terra MODIS (Protoflight Model - PFM), such as removal of the optical leak into the long-wave infrared (LWIR) photoconductive (PC) bands and reduction of electronic crosstalk and out-of-band (OOB) thermal leak into the short-wave infrared (SWIR) bands.

An Overview of Lunar Calibration and Characterization for the EOS Terra and Aqua MODIS

NASA Technical Reports Server (NTRS)

Xiong, X.; Salomonson, V. V.; Sun, J.; Chiang, K.; Xiong, S.; Humphries, S.; Barnes, W.; Guenther, B.

2004-01-01

The Moon can be used as a stable source for Earth-observing sensors on-orbit radiometric and spatial stability monitoring in the VIS and NIR spectral regions. It can also serve as a calibration transfer vehicle among multiple sensors. Nearly identical copies of the Moderate Resolution Imaging Spectroradiometer (MODE) have been operating on-board the NASA's Earth Observing System (EOS) Terra and Aqua satellites since their launches in December 1999 and May 2002, respectively. Terra and Aqua MODIS each make observations in 36 spectral bands covering the spectral range from 0.41 to 14.5 microns and are calibrated on-orbit by a set of on-board calibrations (OBCs) including: 1) a solar diffuser (SD), 2) a solar diffuser stability monitor (SDSM), 3) a blackbody (BB), and 4) a spectro-radiometric calibration assembly (SRCA). In addition to fully utilizing the OBCs, the Moon has been used extensively by both Terra and Aqua MODIS to support their on-orbit calibration and characterization. A 4 This paper provides an overview of applications of lunar calibration and characterization from the MODIS perspective, including monitoring radiometric calibration stability for the reflective solar bands (RSBs), tracking changes of the sensors response versus scan-angle (RVS), examining the sensors spatial performance , and characterizing optical leaks and electronic crosstalk among different spectral bands and detectors. On-orbit calibration consistency between the two MODIS instruments is also addressed. Based on the existing on-orbit time series of the Terra and Aqua MODIS lunar observations, the radiometric difference between the two sensors is less than +/-1% for the RSBs. This method provides a powerful means of performing calibration comparisons among Earth-observing sensors and assures consistent data and science products for the long-term studies of climate and environmental changes.

An overview of Suomi NPP VIIRS calibration maneuvers

NASA Astrophysics Data System (ADS)

Butler, James J.; Xiong, Xiaoxiong; Barnes, Robert A.; Patt, Frederick S.; Sun, Junqiang; Chiang, Kwofu

2012-09-01

The first Visible Infrared Imager Radiometer Suite (VIIRS) instrument was successfully launched on-board the Suomi National Polar-orbiting Partnership (SNPP) spacecraft on October 28, 2011. Suomi NPP VIIRS observations are made in 22 spectral bands, from the visible (VIS) to the long-wave infrared (LWIR), and are used to produce 22 Environmental Data Records (EDRs) with a broad range of scientific applications. The quality of these VIIRS EDRs strongly depends on the quality of its calibrated and geo-located Sensor Date Records (SDRs). Built with a strong heritage to the NASA's EOS MODerate resolution Imaging Spectroradiometer (MODIS) instrument, the VIIRS is calibrated on-orbit using a similar set of on-board calibrators (OBC), including a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system for the reflective solar bands (RSB) and a blackbody (BB) for the thermal emissive bands (TEB). Onorbit maneuvers of the SNPP spacecraft provide additional calibration and characterization data from the VIIRS instrument which cannot be obtained pre-launch and are required to produce the highest quality SDRs. These include multiorbit yaw maneuvers for the characterization of SD and SDSM screen transmission, quasi-monthly roll maneuvers to acquire lunar observations to track sensor degradation in the visible through shortwave infrared, and a driven pitch-over maneuver to acquire multiple scans of deep space to determine TEB response versus scan angle (RVS). This paper provides an overview of these three SNPP calibration maneuvers. Discussions are focused on their potential calibration and science benefits, pre-launch planning activities, and on-orbit scheduling and implementation strategies. Results from calibration maneuvers performed during the Intensive Calibration and Validation (ICV) period for the VIIRS sensor are illustrated. Also presented in this paper are lessons learned regarding the implementation of calibration spacecraft maneuvers on follow-on missions.

Injection of thermal and suprathermal seed particles into coronal shocks of varying obliquity

NASA Astrophysics Data System (ADS)

Battarbee, M.; Vainio, R.; Laitinen, T.; Hietala, H.

2013-10-01

Context. Diffusive shock acceleration in the solar corona can accelerate solar energetic particles to very high energies. Acceleration efficiency is increased by entrapment through self-generated waves, which is highly dependent on the amount of accelerated particles. This, in turn, is determined by the efficiency of particle injection into the acceleration process. Aims: We present an analysis of the injection efficiency at coronal shocks of varying obliquity. We assessed injection through reflection and downstream scattering, including the effect of a cross-shock potential. Both quasi-thermal and suprathermal seed populations were analysed. We present results on the effect of cross-field diffusion downstream of the shock on the injection efficiency. Methods: Using analytical methods, we present applicable injection speed thresholds that were compared with both semi-analytical flux integration and Monte Carlo simulations, which do not resort to binary thresholds. Shock-normal angle θBn and shock-normal velocity Vs were varied to assess the injection efficiency with respect to these parameters. Results: We present evidence of a significant bias of thermal seed particle injection at small shock-normal angles. We show that downstream isotropisation methods affect the θBn-dependence of this result. We show a non-negligible effect caused by the cross-shock potential, and that the effect of downstream cross-field diffusion is highly dependent on boundary definitions. Conclusions: Our results show that for Monte Carlo simulations of coronal shock acceleration a full distribution function assessment with downstream isotropisation through scatterings is necessary to realistically model particle injection. Based on our results, seed particle injection at quasi-parallel coronal shocks can result in significant acceleration efficiency, especially when combined with varying field-line geometry. Appendices are available in electronic form at http://www.aanda.org

Increased efficiency with surface texturing in ITO/InP solar cells

NASA Technical Reports Server (NTRS)

Jenkins, Phillip; Landis, Geoffrey A.; Fatemi, Navid; Li, Xiaonan; Scheiman, David; Bailey, Sheila

1992-01-01

Optimization of an InP solar cell with a V-grooved surface is discussed. Total internal reflection in the coverglass reduces surface reflection and can recover light reflected from the front metallization. Results from the first ITO/InP solar cells on low-angle V-grooved substrates are presented, showing a 5.8 percent increase in current.

Spectrophotometer-Integrating-Sphere System for Computing Solar Absorptance

NASA Technical Reports Server (NTRS)

Witte, William G., Jr.; Slemp, Wayne S.; Perry, John E., Jr.

1991-01-01

A commercially available ultraviolet, visible, near-infrared spectrophotometer was modified to utilize an 8-inch-diameter modified Edwards-type integrated sphere. Software was written so that the reflectance spectra could be used to obtain solar absorptance values of 1-inch-diameter specimens. A descriptions of the system, spectral reflectance, and software for calculation of solar absorptance from reflectance data are presented.

Impact of aerosols on solar energy production - Scenarios from the Sahel Zone

NASA Astrophysics Data System (ADS)

Neher, Ina; Meilinger, Stefanie; Crewell, Susanne

2017-04-01

Solar energy is one option to serve the rising global energy demand with low environmental impact. Building an energy system with a considerable share of solar power requires long-term investment and a careful investigation of potential sites. Therefore, understanding the impacts from varying regionally and locally determined meteorological conditions on solar energy production will influence energy yield projections. Aerosols reduce global solar radiation due to absorption and scattering and therewith solar energy yields. Depending on aerosol size distribution they reduce the direct component of the solar radiation and modify the direction of the diffuse component compared to standard atmospheric conditions without aerosols. The aerosol size distribution and composition in the atmosphere is highly variable due to meteorological and land surface conditions. A quantitative assessment of aerosol effects on solar power yields and its relation to land use change is of particular interest for developing countries countries when analyzing the potential of local power production. This study aims to identify the effect of atmospheric aerosols in three different land use regimes, namely desert, urban/polluted and maritime on the tilted plane of photovoltaic energy modules. Here we focus on the Sahel zone, i.e. Niamey, Niger (13.5 N;2.1 E), located at the edge of the Sahara where also detailed measurements of the atmospheric state are available over the year 2006. Guided by observations a model chain is used to determine power yields. The atmospheric aerosol composition will be defined by using the Optical Properties of Aerosols and Clouds (OPAC) library. Direct and diffuse radiation (up- and downward component) are then calculated by the radiative transfer model libRadtran which allows to calculate the diffuse component of the radiance from different azimuth and zenith angles. Then the diffuse radiance will be analytically transformed to an east, south and west facing module with different tilting angles (between 0° and 45°) from each direction and compared to the tilted diffuse radiation derived by the Perez-model (Loutzenhiser et al. 2007) which is widely used in the photovoltaic community. This will allow an assessment how well standard approaches work in tropical region under various aerosol conditions including strong dust outbreaks from the Sahara. This presentation will introduce the modeling chain to assess solar power yields for different photovoltaic modules in the Sahel zone and address their relative dependence on aerosol conditions.

Dynamics of Solar Energetic Particles in the Presence of a Shock Wave

NASA Astrophysics Data System (ADS)

Timofeev, V. E.; Petukhov, Ivan; Petukhov, Stanislav; Starodubtsev, Sergei

2003-07-01

From the analysis of problem solutions on the solar energetic particle propagation in the presence of a plane shock wave described by the diffusion convective transport equation, the condition and manifestations for the influence of a shock wave on the SEP propagation in the solar wind have been determined. Solar energetic particles (SEP) in gradual events are generated by shock waves (see, for example, [1] and references there). The SEP generation region is limited, on the whole, by the solar corona. Proton fluxes of 470 MeV to 21 GeV energies, a maximum of which occur at a time when the shock in the atmosphere of the Sun reaches heights equal to 5 10 solar radii [2] indicate to it. It is also confirmed by the significant advancing of the occurrence time of maximum in the SEP intensity with kinetic energies more than 10 MeV relative to the shock front arrival moment to Earth's orbit. model calculations for the particles acceleration by the diffusive mechanism in conditions, typical for the solar corona, show that the time taken to pass the solar atmosphere by the shock is quite sufficient to form the particle spectrum corresponding to the SEP characteristics observed [3,4]. Lee and Ryan [5] investigated the problem of SEP gradual event generation, propagation and confirmed the close association between the diffusive acceleration mechanism and SEP events. The absence of depending of particle diffusion coefficients on the energy is a lack of this model. As an extension of preceding investigations, in this work the temporal dynamics of the particle spectrum in the presence of a plane shock for diffusion coefficients depending on the particle energy and also their change in time is studied. The SEP event from a moment of arising of a shock to a moment of it's arrival on the Earth's orbit can be divided on two stages: the first stage (duration is ˜ 1 hour) is a generation of SEP in the solar corona, the second stage (duration is ˜ 1 day) is a propagation in interplanetary space in the presence of a shock. Here we consider the second stage only which as believed to be began with the injection of the particle spectrum formed during the first stage.

The Sun is a plasma diffuser that sorts atoms by mass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manuel, O., E-mail: omatumr@yahoo.com; Kamat, S. A.; Mozina, M.

2006-11-15

The Sun is a plasma diffuser that selectively moves light elements like H and He and the lighter isotopes of each element to its surface. The Sun formed on the collapsed core of a supernova (SN) and is composed mostly of elements made near the SN core (Fe, O, Ni, Si, and S), like the rocky planets and ordinary meteorites. Neutron emission from the central neutron star triggers a series of reactions that generate solar luminosity, solar neutrinos, solar mass fractionation, and an outpouring of hydrogen in the solar wind. Mass fractionation seems to have operated in the parent starmore » and likely occurs in other stars as well.« less

Diffusion lengths in irradiated N/P InP-on-Si solar cells

NASA Technical Reports Server (NTRS)

Wojtczuk, Steven; Colerico, Claudia; Summers, Geoffrey P.; Walters, Robert J.; Burke, Edward A.

1995-01-01

Indium phosphide (InP) solar cells are being made on silicon (Si) wafers (InP/Si) to take advantage of both the radiation-hardness properties of the InP solar cell and the light weight and low cost of Si wafers compared to InP or germanium (Ge) wafers. The InP/Si cell application is for long duration and/or high radiation orbit space missions. InP/Si cells have higher absolute efficiency after a high radiation dose than gallium arsenide (GaAs) or silicon (Si) solar cells. In this work, base electron diffusion lengths in the N/P cell are extracted from measured AM0 short-circuit photocurrent at various irradiation levels out to an equivalent 1 MeV fluence of 1017 1 MeV electrons/sq cm for a 1 sq cm 12% BOL InP/Si cell. These values are then checked for consistency by comparing measured Voc data with a theoretical Voc model that includes a dark current term that depends on the extracted diffusion lengths.

Energetic Particles from Outside our Solar System Increase Artist Concept

NASA Image and Video Library

2011-12-16

This artist concept shows NASA Voyager 1 spacecraft in a new region at the edge of our solar system where the amount of high-energy particles diffusing into our solar system from outside has increased.

Calibration procedure of Hukseflux SR25 to Establish the Diffuse Reference for the Outdoor Broadband Radiometer Calibration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reda, Ibrahim M.; Andreas, Afshin M.

2017-08-01

Accurate pyranometer calibrations, traceable to internationally recognized standards, are critical for solar irradiance measurements. One calibration method is the component summation method, where the pyranometers are calibrated outdoors under clear sky conditions, and the reference global solar irradiance is calculated as the sum of two reference components, the diffuse horizontal and subtended beam solar irradiances. The beam component is measured with pyrheliometers traceable to the World Radiometric Reference, while there is no internationally recognized reference for the diffuse component. In the absence of such a reference, we present a method to consistently calibrate pyranometers for measuring the diffuse component. Themore » method is based on using a modified shade/unshade method and a pyranometer with less than 0.5 W/m2 thermal offset. The calibration result shows that the responsivity of Hukseflux SR25 pyranometer equals 10.98 uV/(W/m2) with +/-0.86 percent uncertainty.« less

Silica-sol-based spin-coating barrier layer against phosphorous diffusion for crystalline silicon solar cells

PubMed Central

2014-01-01

The phosphorus barrier layers at the doping procedure of silicon wafers were fabricated using a spin-coating method with a mixture of silica-sol and tetramethylammonium hydroxide, which can be formed at the rear surface prior to the front phosphorus spin-on-demand (SOD) diffusion and directly annealed simultaneously with the front phosphorus layer. The optimization of coating thickness was obtained by changing the applied spin-coating speed; from 2,000 to 8,000 rpm. The CZ-Si p-type silicon solar cells were fabricated with/without using the rear silica-sol layer after taking the sheet resistance measurements, SIMS analysis, and SEM measurements of the silica-sol material evaluations into consideration. For the fabrication of solar cells, a spin-coating phosphorus source was used to form the n+ emitter and was then diffused at 930°C for 35 min. The out-gas diffusion of phosphorus could be completely prevented by spin-coated silica-sol film placed on the rear side of the wafers coated prior to the diffusion process. A roughly 2% improvement in the conversion efficiency was observed when silica-sol was utilized during the phosphorus diffusion step. These results can suggest that the silica-sol material can be an attractive candidate for low-cost and easily applicable spin-coating barrier for any masking purpose involving phosphorus diffusion. PMID:25520602

Silica-sol-based spin-coating barrier layer against phosphorous diffusion for crystalline silicon solar cells.

PubMed

Uzum, Abdullah; Fukatsu, Ken; Kanda, Hiroyuki; Kimura, Yutaka; Tanimoto, Kenji; Yoshinaga, Seiya; Jiang, Yunjian; Ishikawa, Yasuaki; Uraoka, Yukiharu; Ito, Seigo

2014-01-01

The phosphorus barrier layers at the doping procedure of silicon wafers were fabricated using a spin-coating method with a mixture of silica-sol and tetramethylammonium hydroxide, which can be formed at the rear surface prior to the front phosphorus spin-on-demand (SOD) diffusion and directly annealed simultaneously with the front phosphorus layer. The optimization of coating thickness was obtained by changing the applied spin-coating speed; from 2,000 to 8,000 rpm. The CZ-Si p-type silicon solar cells were fabricated with/without using the rear silica-sol layer after taking the sheet resistance measurements, SIMS analysis, and SEM measurements of the silica-sol material evaluations into consideration. For the fabrication of solar cells, a spin-coating phosphorus source was used to form the n(+) emitter and was then diffused at 930°C for 35 min. The out-gas diffusion of phosphorus could be completely prevented by spin-coated silica-sol film placed on the rear side of the wafers coated prior to the diffusion process. A roughly 2% improvement in the conversion efficiency was observed when silica-sol was utilized during the phosphorus diffusion step. These results can suggest that the silica-sol material can be an attractive candidate for low-cost and easily applicable spin-coating barrier for any masking purpose involving phosphorus diffusion.

Methods to Estimate Solar Radiation Dosimetry in Coral Reefs Using Remote Sensed, Modeled, and in Situ Data.

EPA Science Inventory

Solar irradiance has been increasingly recognized as an important determinant of bleaching in coral reefs, but measurements of solar radiation exposure within coral reefs have been relatively limited. Solar irradiance and diffuse down welling attenuation coefficients (Kd, m-1) we...

Spectral sea surface reflectance of skylight.

PubMed

Zhang, Xiaodong; He, Shuangyan; Shabani, Afshin; Zhai, Peng-Wang; Du, Keping

2017-02-20

In examining the dependence of the sea surface reflectance of skylight ρs on sky conditions, wind speed, solar zenith angle, and viewing geometry, Mobley [Appl. Opt.38, 7442 (1999).10.1364/AO.38.007442] assumed ρs is independent of wavelength. Lee et al. [Opt. Express18, 26313 (2010).10.1364/OE.18.026313] showed experimentally that ρs does vary spectrally due to the spectral difference of sky radiance coming from different directions, which was ignored in Mobley's study. We simulated ρs from 350 nm to 1000 nm by explicitly accounting for spectral variations of skylight distribution and Fresnel reflectance. Furthermore, we separated sun glint from sky glint because of significant differences in magnitude, spectrum and polarization state between direct sun light and skylight light. The results confirm that spectral variation of ρs(λ) mainly arises from the spectral distribution of skylight and would vary from slightly blueish due to normal dispersion of the refractive index of water, to neutral and then to reddish with increasing wind speeds and decreasing solar zenith angles. Polarization moderately increases sky glint by 8 - 20% at 400 nm but only by 0 - 10% at 1000 nm. Sun glint is inherently reddish and becomes significant (>10% of sky glint) when the sun is at the zenith with moderate winds or when the sea is roughened (wind speeds > 10 m s^-1) with solar zenith angles < 20°. We recommend a two-step procedure by first correcting the glint due to direct sun light, which is unpolarized, followed by removing the glint due to diffused and polarized skylight. The simulated ρs(λ) as a function of wind speeds, sun angles and aerosol concentrations for currently recommended sensor-sun geometry, i.e., zenith angle = 40° and azimuthal angle relative to the sun = 45°, is available upon request.

Holographic Solar Photon Thrusters

NASA Technical Reports Server (NTRS)

Johnson, Les; Matloff, Greg

2006-01-01

A document discusses a proposal to incorporate holographic optical elements into solar photon thrusters (SPTs). First suggested in 1990, SPTs would be systems of multiple reflective, emissive, and absorptive surfaces (solar sails) that would be attached to spacecraft orbiting the Earth to derive small propulsive forces from radiation pressures. An SPT according to the proposal would include, among other things, a main sail. One side of the sail would be highly emissive and would normally face away from the Earth. The other side would be reflective and would be covered by white-light holographic images that would alternately become reflective, transmissive, and absorptive with small changes in the viewing angle. When the spacecraft was at a favorable orbital position, the main sail would be oriented to reflect sunlight in a direction to maximize the solar thrust; when not in a favorable position, the main sail would be oriented to present a substantially absorptive/emissive aspect to minimize the solar drag. By turning the main sail slightly to alternate between the reflective and absorptive/ emissive extremes, one could achieve nearly a doubling or halving of the radiational momentum transfer and, hence, of the solar thrust.

Crystalline silicon photovoltaics via low-temperature TiO 2/Si and PEDOT/Si heterojunctions

NASA Astrophysics Data System (ADS)

Nagamatsu, Ken Alfred

The most important goals in developing solar cell technology are to achieve high power conversion efficiencies and lower costs of manufacturing. Solar cells based on crystalline silicon currently dominate the market because they can achieve high efficiency. However, conventional p-n junction solar cells require high-temperature diffusions of dopants, and conventional heterojunction cells based on amorphous silicon require plasma-enhanced deposition, both of which can add manufacturing costs. This dissertation investigates an alternative approach, which is to form crystalline-silicon-based solar cells using heterojunctions with materials that are easily deposited at low temperatures and without plasma enhancement, such as organic semiconductors and metal oxides. We demonstrate a heterojunction between the organic polymer, poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT), and crystalline silicon, which acts as a hole-selective contact and an alternative to a diffused p-n junction. We also present the use of a heterojunction between titanium dioxide and crystalline silicon as a passivating electron-selective contact. The Si/TiO2 heterojunction is demonstrated for the first time as a back-surface field in a crystalline silicon solar cell, and is incorporated into a PEDOT/Si device. The resulting PEDOT/Si/TiO2 solar cell represents an alternative to conventional silicon solar cells that rely on thermally-diffused junctions or plasma-deposited heterojunctions. Finally, we investigate the merits of using conductive networks of silver nanowires to enhance the photovoltaic performance of PEDOT/Si solar cells. The investigation of these materials and devices contributes to the growing body of work regarding crystalline silicon solar cells made with selective contacts.

Local effects of partly cloudy skies on solar and emitted radiations

NASA Technical Reports Server (NTRS)

Whitney, D. A.; Venable, D. D.

1981-01-01

Solar radiation measurements are made on a routine basis. Global solar, atmospheric emitted, downwelled diffuse solar, and direct solar radiation measurement systems are fully operational with the first two in continuous operation. Fractional cloud cover measurements are made from GOES imagery or from ground based whole sky photographs. Normalized global solar irradiance values for partly cloudy skies were correlated to fractional cloud cover.

Methods for quantitative infrared directional-hemispherical and diffuse reflectance measurements using an FTIR and a commercial integrating sphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blake, Thomas A.; Johnson, Timothy J.; Tonkyn, Russell G.

Infrared integrating sphere measurements of solid samples are important in providing reference data for contact, standoff and remote sensing applications. At the Pacific Northwest National Laboratory (PNNL) we have developed protocols to measure both the directional-hemispherical ( and diffuse (d) reflectances of powders, liquids, and disks of powders and solid materials using a commercially available, matte gold-coated integrating sphere and Fourier transform infrared spectrometer. Detailed descriptions of the sphere alignment and its use for making these reflectance measurements are given. Diffuse reflectance values were found to be dependent on the bidirectional reflection distribution function (BRDF) of the sample and themore » solid angle intercepted by the sphere’s specular exclusion port. To determine how well the sphere and protocols produce quantitative reflectance data, measurements were made of three diffuse and two specular standards prepared by the National institute of Standards and Technology (NIST, USA), LabSphere Infragold and Spectralon standards, hand-loaded sulfur and talc powder samples, and water. The five NIST standards behaved as expected: the three diffuse standards had a high degree of “diffuseness,” d/ = D > 0.9, whereas the two specular standards had D ≤ 0.03. The average absolute differences between the NIST and PNNL measurements of the NIST standards for both directional-hemispherical and diffuse reflectances are on the order of 0.01 reflectance units. Other quantitative differences between the PNNL-measured and calibration (where available) or literature reflectance values for these standards and materials are given and the possible origins of discrepancies are discussed. Random uncertainties and estimates of systematic uncertainties are presented. Corrections necessary to provide better agreement between the PNNL reflectance values as measured for the NIST standards and the NIST reflectance values for these same standards are also discussed.« less

Low cost solar energy collection system

NASA Technical Reports Server (NTRS)

Miller, C. G.; Stephans, J. B. (Inventor)

1977-01-01

A fixed, linear, ground-based primary reflector having an extended, curved sawtooth contoured surface covered with a metallized polymeric reflecting material, reflected solar energy to a movably supported collector that was kept at the concentrated line focus of the reflector primary. Efficient utilization leading to high temperatures from the reflected solar energy was obtained by cylindrical shaped secondary reflectors that directed off-angle energy to the absorber pipe.

Solar energy collection system

NASA Technical Reports Server (NTRS)

Miller, C. G.; Stephens, J. B. (Inventor)

1979-01-01

A fixed, linear, ground-based primary reflector having an extended curved sawtooth-contoured surface covered with a metalized polymeric reflecting material, reflects solar energy to a movably supported collector that is kept at the concentrated line focus reflector primary. The primary reflector may be constructed by a process utilizing well known freeway paving machinery. The solar energy absorber is preferably a fluid transporting pipe. Efficient utilization leading to high temperatures from the reflected solar energy is obtained by cylindrical shaped secondary reflectors that direct off-angle energy to the absorber pipe. A seriatim arrangement of cylindrical secondary reflector stages and spot-forming reflector stages produces a high temperature solar energy collection system of greater efficiency.

Backscatter of hard X-rays in the solar atmosphere. [Calculating the reflectance of solar x ray emission

NASA Technical Reports Server (NTRS)

Bai, T.; Ramaty, R.

1977-01-01

The solar photosphere backscatters a substantial fraction of the hard X rays from solar flares incident upon it. This reflection was studied using a Monte Carlo simulation which takes into account Compton scattering and photo-electric absorption. Both isotropic and anisotropic X ray sources are considered. The bremsstrahlung from an anisotropic distribution of electrons are evaluated. By taking the reflection into account, the inconsistency is removed between recent observational data regarding the center-to-limb variation of solar X ray emission and the predictions of models in which accelerated electrons are moving down toward the photosphere.

Solar Energy Evolution and Diffusion Studies: 2017-2019 | Solar Research |

Science.gov Websites

data fro-m existing LMI adopters to investigate non-economic motivations and barriers for getting solar the design and implementation of an experimental referral market pilot that will be embedded into the

Evaluation of the impact of atmospheric ozone and aerosols on the horizontal global/diffuse UV Index at Livorno (Italy)

NASA Astrophysics Data System (ADS)

Scaglione, Daniele; Giulietti, Danilo; Morelli, Marco

2016-08-01

A study was conducted at Livorno (Italy) to evaluate the impact of atmospheric aerosols and ozone on the solar UV radiation and its diffuse component at ground in clear sky conditions. Solar UV radiation has been quantified in terms of UV Index (UVI), following the ISO 17166:1999/CIE S007/E-1998 international standard. UVI has been calculated by exploiting the libRadtran radiative transfer modelling software as a function of both the Aerosols Optical Depth (AOD) and the Total Ozone Column (TOC). In particular AOD and TOC values have been remotely sensed by the Ozone Monitoring Instrument (OMI) on board the NASA's EOS (Earth Observing System) satellites constellation. An experimental confirmation was also obtained by exploiting global UVI ground-based measurements from the 26/9/14 to 12/8/15 and diffuse UVI ground-based measurements from the 17/5/15 to 12/8/15. For every considered value of Solar Zenith Angle (SZA) and atmospheric condition, estimates and measurements confirm that the diffuse component contributes for more than 50% on the global UV radiation. Therefore an exposure of human skin also to diffuse solar UV radiation can be potentially harmful for health and need to be accurately monitored, e.g. by exploiting innovative applications such as a mobile app with a satellite-based UV dosimeter that has been developed. Global and diffuse UVI variations due to the atmosphere are primarily caused by the TOC variations (typically cyclic): the maximum TOC variation detected by OMI in the area under study leads to a corresponding variation in global and diffuse UVI of about 50%. Aerosols in the area concerned, mainly of maritime nature, have instead weaker effects causing a maximum variation of the global and diffuse UVI respectively of 9% and 35% with an SZA of 20° and respectively of 13% and 10% with an SZA of 60°.

Synthesis, characterization and evaluation of the photocatalytic performance of Ag-CdMoO{sub 4} solar light driven plasmonic photocatalyst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adhikari, Rajesh; Malla, Shova; Gyawali, Gobinda

2013-09-01

Graphical abstract: - Highlights: • Ag-CdMoO{sub 4} solar light driven photocatalyst was successfully synthesized. • Photocatalyst exhibited strong absorption in the visible region. • Photocatalytic activity was significantly enhanced. • Enhanced activity was caused by the SPR effect induced by Ag nanoparticles. - Abstract: Ag-CdMoO{sub 4} plasmonic photocatalyst was synthesized in ethanol/water mixture by photo assisted co-precipitation method at room temperature. As synthesized powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller (BET) surface area analyzer. Photocatalytic activity was evaluated by performing the degradation experiment over methylenemore » blue (MB) and indigo carmine (IC) as model dyes under simulated solar light irradiation. The results revealed that the Ag-CdMoO{sub 4} showed the higher photocatalytic performance as compared to CdMoO{sub 4} nanoparticles. Dispersion of Ag nanoparticles over the surface of CdMoO{sub 4} nanoparticles causes the surface plasmon resonance (SPR) and enhances the broad absorption in the entire visible region of the solar spectrum. Hence, dispersion of Ag nanoparticles over CdMoO{sub 4} nanoparticles could be the better alternative to enhance the absorption of visible light by scheelite crystal family for effective photocatalysis.« less

Photocatalytic degradation of Orange G dye under solar light using nanocrystalline semiconductor metal oxide.

PubMed

Thennarasu, G; Kavithaa, S; Sivasamy, A

2011-08-01

The photocatalytic degradation of Orange G (OG) dye has been investigated using synthesised nanocrystalline ZnO as a photocatalyst and sunlight as the irradiation source. The formation of ZnO prepared from its precursor was confirmed through FT-IR and powder X-ray diffraction analyses. Surface morphology was characterised by scanning electron microscope and transmission electron microscope analysis. Band gap energy of synthesised nanocrystalline ZnO was calculated using diffuse reflectance spectroscopy (DRS). Different experimental parameters such as effects of pH, dye concentrations and mass of catalyst were standardised in order to achieve complete degradation of the dye molecules under solar light irradiation. The kinetics of oxidation of OG was also studied. The complete degradation of OG was evident after 90 min of irradiation at an initial pH of 6.86. The degradation of OG was confirmed by UV-Visible spectrophotometer, high-pressure liquid chromatography, ESI-Mass and chemical oxygen demand analyses. The adsorption of dye onto catalytic surface was analysed employing model equations such as Langmuir and Freundlich isotherms, and it was found that the Langmuir isotherm model best fitted the adsorption data. The solar photodegradation of OG followed pseudo-first-order kinetics. HPLC and ESI-Mass analyses of the degraded samples suggested that the dye molecules were readily degraded under solar irradiation with nanocrystalline ZnO.

Special report, diffuse reflectivity of the lunar surface

NASA Technical Reports Server (NTRS)

Fastie, W. G.

1972-01-01

The far ultraviolet diffuse reflectivity of samples of lunar dust material is determined. Equipment for measuring the diffuse reflectivity of materials (e.g. paint samples) is already in existence and requires only minor modification for the proposed experiment which will include the measurement of the polarizing properties of the lunar samples. Measurements can be made as a function of both illumination angle and angle of observation.

Solar radiation on Mars: Update 1991

NASA Technical Reports Server (NTRS)

Appelbaum, Joseph; Landis, Geoffrey A.

1991-01-01

Detailed information on solar radiation characteristics on Mars are necessary for effective design of future planned solar energy systems operating on the surface of Mars. A procedure and solar radiation related data are presented from which the daily variation of the global, direct beam and diffuse insolation on Mars are calculated. Given the optical depth of the Mars atmosphere, the global radiation is calculated from the normalized net flux function based on multiple wavelength and multiple scattering of the solar radiation. The direct beam was derived from the optical depth using Beer's law, and the diffuse component was obtained from the difference of the global and the direct beam radiation. The optical depths of the Mars atmosphere were derived from images taken of the Sun with a special diode on the cameras used on the two Viking Landers.

Damage and recovery characteristics of lithium-containing solar cells.

NASA Technical Reports Server (NTRS)

Faith, T. J.

1971-01-01

Damage and recovery characteristics were measured on lithium-containing solar cells irradiated by 1-MeV electrons. Empirical expressions for cell recovery time, diffusion-length damage coefficient immediately after irradiation, and diffusion-length damage coefficient after recovery were derived using results of short-circuit current, diffusion-length, and reverse-bias capacitance measurements. The damage coefficients were expressed in terms of a single lithium density parameter, the lithium gradient. A fluence dependence was also established, this dependence being the same for both the immediate-post-irradiation and post-recovery cases. Cell recovery rates were found to increase linearly with lithium gradient.

Diffused junction p(+)-n solar cells in bulk GaAs. I Fabrication and cell performance

NASA Technical Reports Server (NTRS)

Bhat, I.; Bhat, K. N.; Mathur, G.; Borrego, J. M.; Ghandhi, S. K.

1984-01-01

This paper describes the fabrication of solar cells made by a simple open tube p(+)-diffusion into bulk n-GaAs. In addition, cell performance is provided as an indicator of the quality of bulk GaAs for this application. Initial results using this technique (12.2 percent efficiency at AM1 for 0.5 sq cm cells) are promising, and indicate directions for materials improvement. It is shown that the introduction of the diffusant (zinc) with point defects significantly affects the material properties and results in an increase in current capability.

Application of the MOS C-V technique to determine impurity concentrations and surface parameters on the diffused face of silicon solar cells

NASA Technical Reports Server (NTRS)

Weinberg, I.

1975-01-01

An experimental and theoretical investigation of the feasibility of using the MOS C-V (capacitance-voltage) technique to determine impurity and surface state concentrations on the diffused face of Si solar cells with Ta2O5 coatings. Impurity concentration 10 A from the diffused surface is found to be 2.9 times 10 to the 20th power per cu cm. Charge density in surface and oxide states is 2.1 times 10 to the 13th power per sq cm. These data agree with theoretical predictions.-

Spectral reflectance properties of black chrome for use as a solar selective coating

NASA Technical Reports Server (NTRS)

Mcdonald, G. E.

1974-01-01

The NASA-Lewis Research Center has determined that a widely available commercially electroplated decorative finish known as black chrome has desirable solar selective properties. The spectral reflectance properties of a commercially prepared black chrome on steel were measured. Values are presented for reflectance of the black chrome, and compared with the reflectance of black paint (Nextel) and with two available samples of black nickel which had been prepared for solar selective properties. The reflectance of black chrome, of the two black nickels, and of black paint integrated over the solar spectrum for air mass 2 were 0.132, 0.123, 0.133, and 0.033, respectively. The reflectance of the black chrome, two black nickels, and of the black paint integrated over the blackbody spectrum for 250 F from 3 to 15 microns are 0.912, 0.934, 0.891, and 0.033, respectively. These reflectance measurements indicate absorptivity-to-emissivity values of 9.8, 13.8, 8.0, and 1.00, respectively.

Cosmic ray propagation in interplanetary space

NASA Technical Reports Server (NTRS)

Voelk, H. J.

1975-01-01

The validity of the test-particle picture, the approximation of static fields, and the spatial-diffusion approximation are discussed in a general way before specific technical assumptions are introduced. It is argued that the spatial-diffusion equation for the intensity per unit energy has a much wider range of applicability than the kinetic (Fokker-Planck) equation it is derived from. This gives strong weight to the phenomenological propagation theory. The general success (and possible failure at small energies) of the phenomenological theory for the modulation of galactic cosmic rays and solar events is described. Apparent effects such as the 'free boundary' are given disproportionate weight since they establish the connection with the detailed plasma physics of the solar wind. Greatest attention is paid to the pitch-angle diffusion theory. A general theory is presented which removes the well-known secularities of the quasi-linear approximation. The possible breakdown of any pitch-angle diffusion theory at very small energies is perhaps connected with the observed 'turn up' of the spectrum at low energies. A first attempt to derive the spatial dependence of the diffusion coefficient in the solar cavity, using such a divergence free scattering theory, is described and compared with recent observations out to 5 AU.

Directed Vertical Diffusion of Photovoltaic Active Layer Components into Porous ZnO-Based Cathode Buffer Layers.

PubMed

Kang, Jia-Jhen; Yang, Tsung-Yu; Lan, Yi-Kang; Wu, Wei-Ru; Su, Chun-Jen; Weng, Shih-Chang; Yamada, Norifumi L; Su, An-Chung; Jeng, U-Ser

2018-04-01

Cathode buffer layers (CBLs) can effectively further the efficiency of polymer solar cells (PSCs), after optimization of the active layer. Hidden between the active layer and cathode of the inverted PSC device configuration is the critical yet often unattended vertical diffusion of the active layer components across CBL. Here, a novel methodology of contrast variation with neutron and anomalous X-ray reflectivity to map the multicomponent depth compositions of inverted PSCs, covering from the active layer surface down to the bottom of the ZnO-based CBL, is developed. Uniquely revealed for a high-performance model PSC are the often overlooked porosity distributions of the ZnO-based CBL and the differential diffusions of the polymer PTB7-Th and fullerene derivative PC 71 BM of the active layer into the CBL. Interface modification of the ZnO-based CBL with fullerene derivative PCBEOH for size-selective nanochannels can selectively improve the diffusion of PC 71 BM more than that of the polymer. The deeper penetration of PC 71 BM establishes a gradient distribution of fullerene derivatives over the ZnO/PCBE-OH CBL, resulting in markedly improved electron mobility and device efficiency of the inverted PSC. The result suggests a new CBL design concept of progressive matching of the conduction bands. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Solar Energy Potential in a Changing Climate: Iberia and Azores Assessment Combining Dynamical and Statistical Downscaling Methods

NASA Astrophysics Data System (ADS)

Magarreiro, Clarisse de Lurdes Chapa

The proper characterization of solar radiation resource is essential for the design of any solar energy harnessing systems which aims its optimal performance. To this end, the solar resource is often quantified through solar radiation measurements at meteorological stations. Unfortunately radiation data recorded on the desired location is often inexistent. Furthermore, the actual existing solar radiation databases have also a limited temporal span and, more frequently than desired, missing values and non-uniform formats. Also, such databases consist almost entirely of global solar radiation; variables such as the nature of the solar energy (direct or diffuse) are rarely recorded. Atmospheric models can add value to solar energy applications by enabling solar resource assessments as they easily overcome the limited spatial and temporal coverage of irradiance measuring networks. Furthermore, climate models can be used for any region of the planet to assess the solar resource for not only present climate conditions but also to analyse its long-term past evolution and future tendency. Nowadays such models are a popular approach on the field of solar radiation forecasting but the quality evaluation of the solar radiation representation by such models is first of all a fundamental step to understand its usefulness. Having this in mind, in this thesis, a dynamical downscaling approach is used to evaluate simulated solar radiation at the Earth’s surface which will then enable the characterization of the solar resource. The model output is also combined with a statistical downscaling approach used in its simplest form to minimize the model biases. The work focuses primarily in the Iberian Peninsula as its large climate gradients are representative of diverse meteorological conditions, enabling therefore the adaptation of the presented methods to other regions. Then, following the same methodology, the solar resource of the Azores archipelago is also addressed. The Azores region is often neglected in solar resource assessments and solar resource maps of the Earth’s surface or even of Europe region. These methods are used to characterize the present climate renewable solar resource and analyse the impact of climate change on its projections for the end of the 21st century for both Iberia Peninsula and Azores archipelago. Atmospheric numerical models are however limited in the sense that they only provide global solar radiation, the direct normal radiation and diffuse components are not common outputs to the user. Given this, the separation of global radiation into its diffuse and direct components is analysed in this thesis through models of diffuse solar radiation fraction. One important characteristic of these models is that they are empirically derived from site-specific measurements and a model developed and validated in a very specific climate type region may not hold its suitability to other regions. This thesis focuses on the assessment of such models only for the Azores region which has not been object of this type of analysis before.

Standardization of Solar Mirror Reflectance Measurements - Round Robin Test: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyen, S.; Lupfert, E.; Fernandez-Garcia, A.

2010-10-01

Within the SolarPaces Task III standardization activities, DLR, CIEMAT, and NREL have concentrated on optimizing the procedure to measure the reflectance of solar mirrors. From this work, the laboratories have developed a clear definition of the method and requirements needed of commercial instruments for reliable reflectance results. A round robin test was performed between the three laboratories with samples that represent all of the commercial solar mirrors currently available for concentrating solar power (CSP) applications. The results show surprisingly large differences in hemispherical reflectance (sh) of 0.007 and specular reflectance (ss) of 0.004 between the laboratories. These differences indicate themore » importance of minimum instrument requirements and standardized procedures. Based on these results, the optimal procedure will be formulated and validated with a new round robin test in which a better accuracy is expected. Improved instruments and reference standards are needed to reach the necessary accuracy for cost and efficiency calculations.« less

Development of a spatially resolved reflectometer to monitor corrosion of solar reflectors

NASA Astrophysics Data System (ADS)

Sutter, Florian; Meyen, Stephanie; Heller, Peter; Pitz-Paal, Robert

2013-06-01

Solar reflectors for Concentrating Solar Power (CSP) concentrators require a high reflectance and high specularity over the whole solar spectrum. During their lifetime of at least 20 years, the reflectors must withstand harsh outdoor conditions without loosing their reflective properties. Currently, there are not many devices available to measure the specular reflectance. In this work a prototype of a specular reflectometer with spatial resolution has been developed. The major advantage of the prototype compared to other reflectometers is the possibility of measuring the specular reflectance on an extended measuring spot of more than 5 cm in diameter with a spatial resolution of 37 pixel/mm. Additionally, measurements can be taken at three different acceptance half angles (φ = 3.5, 6.0, and 12.5 mrad) and at three different wavelengths (λ = 410 nm, 500 nm, and 656 nm). This lab scale instrument can be employed to monitor degradation effects, such as corrosion spots, and evaluate their influence on the specular reflectance of solar mirror materials.

Inexpensive Meter for Total Solar Radiation

NASA Technical Reports Server (NTRS)

Laue, E. G.

1987-01-01

Pyranometer containing solar cells measures combined intensity of direct light from Sun and diffuse light from sky. Instrument includes polyethylene dome that diffuses entering light so output of light detectors does not vary significantly with changing angle of Sun during day. Not to be calibrated for response of each detector to Sun angle, and sensor outputs not corrected separately before summed and integrated. Aids in deciding on proper time to harvest crops.

[Application of BaSO4 diffuser plate in 250-400 nm spectral radiance calibration].

PubMed

Jia, Hui; Li, Fu-tian

2004-01-01

Sprayed BaSO4 diffuser plate is the most Lambertian surface actually used in spectral radiance calibration known by now. Its hemispheric reflectance and Bi-directional Reflectance Distribution Functions (BRDF) were measured in the experiment. Its diffuse characteristics were compared with Lambertian surface. In order to calibrate spectral radiance more accurately, the small variation of diffuser's BRDF with scattered angles and the nonuniformity of spectral irradiance on diffuser surface illuminated by the standard lamp should be considered. By integrating the radiation flux reflected by the element area and that entering the entrance slit within the viewing area of spectrometer, the measured spectral radiance can be calculated. Furthermore, the spectral radiance of Lambertian surface whose BRDF was derived from hemispheric reflectance was compared with that from the average of the measured BRDF.

Diffuse and specular characteristics of leaf reflectance

NASA Technical Reports Server (NTRS)

Grant, Lois

1987-01-01

In this paper, the evolution of current understanding of the mechanisms of leaf reflectance is reviewed. The use of measurements of polarized reflectance to separate leaf reflectance into diffuse and specular components is discussed. A section on the factors influencing leaf reflectance - leaf structure and physiological disturbances - is included along with discussion on the manner in which these influences are manifested.

Contamination and UV ageing of diffuser targets used in satellite inflight and ground reference test site calibrations

NASA Astrophysics Data System (ADS)

Vaskuri, Anna; Greenwell, Claire; Hessey, Isabel; Tompkins, Jordan; Woolliams, Emma

2018-02-01

Diffuser reflectance targets are key components in in-orbit calibrations and for verifying ground reference test sites. In this work, Spectralon, Diffusil, and Heraeus diffusers were exposed to exhaust gases and ultraviolet (UV) radiation in the ambient air conditions and their degradations were monitored by measuring changes in spectral reflectances. Spectralon is a state-of-the-art diffuser made of polytetrafluoroethylene, and Diffusil and Heraeus diffusers are made of fused silica with gas bubbles inside. Based on the contamination tests, Spectralon degrades faster than fused silica diffusers. For the samples exposed to contamination for 20 minutes, the 250 nm - 400 nm total diffuse spectral reflectance of Spectralon degraded 3-5 times more when exposed to petrol-like emission and 16-23 times more when exposed to diesel-like emission, compared with Diffusil. When the reflectance changes of Spectralon were compared with those of Heraeus, Spectralon degraded 3-4 times more when exposed to petrol-like emission for 20 minutes and 5-7 times more when exposed to diesel-like emission for 7.5 minutes. When the samples contaminated were exposed to UV radiation in the ambient air, their reflectance gradually restored back to the original level. In conclusion, fused silica diffusers are more resistant to hydrocarbon contaminants present in ground reference test sites, and thus more stable under UV radiation in the air.

Fast diffusion of native defects and impurities in perovskite solar cell material CH 3NH 3PbI 3

DOE PAGES

Yang, Dongwen; Ming, Wenmei; Shi, Hongliang; ...

2016-06-01

CH 3NH 3PbI 3-based solar cells have shown remarkable progress in recent years but have also suffered from structural, electrical, and chemical instabilities related to the soft lattices and the chemistry of these halides. One of the instabilities is ion migration, which may cause current–voltage hysteresis in CH 3NH 3PbI 3 solar cells. Significant ion diffusion and ionic conductivity in CH 3NH 3PbI 3 have been reported; their nature, however, remain controversial. In the literature, the use of different experimental techniques leads to the observation of different diffusing ions (either iodine or CH 3NH 3 ion); the calculated diffusion barriersmore » for native defects scatter in a wide range; the calculated defect formation energies also differ qualitatively. These controversies hinder the understanding and the control of the ion migration in CH 3NH 3PbI 3. In this paper, we show density functional theory calculations of both the diffusion barriers and the formation energies for native defects (V I +, MA i +, V MA –, and I i –) and the Au impurity in CH 3NH 3PbI 3. V I + is found to be the dominant diffusing defect due to its low formation energy and the low diffusion barrier. I i – and MA i + also have low diffusion barriers but their formation energies are relatively high. The hopping rate of V I + is further calculated taking into account the contribution of the vibrational entropy, confirming V I + as a fast diffuser. We discuss approaches for managing defect population and migration and suggest that chemically modifying surfaces, interfaces, and grain boundaries may be effective in controlling the population of the iodine vacancy and the device polarization. We further show that the formation energy and the diffusion barrier of Au interstitial in CH 3NH 3PbI 3 are both low. As a result, it is thus possible that Au can diffuse into CH3NH3PbI3 under bias in devices (e.g., solar cell, photodetector) with Au/CH 3NH 3PbI 3 interfaces and modify the electronic properties of CH 3NH 3PbI 3.« less

Fast diffusion of native defects and impurities in perovskite solar cell material CH 3NH 3PbI 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Dongwen; Ming, Wenmei; Shi, Hongliang

CH 3NH 3PbI 3-based solar cells have shown remarkable progress in recent years but have also suffered from structural, electrical, and chemical instabilities related to the soft lattices and the chemistry of these halides. One of the instabilities is ion migration, which may cause current–voltage hysteresis in CH 3NH 3PbI 3 solar cells. Significant ion diffusion and ionic conductivity in CH 3NH 3PbI 3 have been reported; their nature, however, remain controversial. In the literature, the use of different experimental techniques leads to the observation of different diffusing ions (either iodine or CH 3NH 3 ion); the calculated diffusion barriersmore » for native defects scatter in a wide range; the calculated defect formation energies also differ qualitatively. These controversies hinder the understanding and the control of the ion migration in CH 3NH 3PbI 3. In this paper, we show density functional theory calculations of both the diffusion barriers and the formation energies for native defects (V I +, MA i +, V MA –, and I i –) and the Au impurity in CH 3NH 3PbI 3. V I + is found to be the dominant diffusing defect due to its low formation energy and the low diffusion barrier. I i – and MA i + also have low diffusion barriers but their formation energies are relatively high. The hopping rate of V I + is further calculated taking into account the contribution of the vibrational entropy, confirming V I + as a fast diffuser. We discuss approaches for managing defect population and migration and suggest that chemically modifying surfaces, interfaces, and grain boundaries may be effective in controlling the population of the iodine vacancy and the device polarization. We further show that the formation energy and the diffusion barrier of Au interstitial in CH 3NH 3PbI 3 are both low. As a result, it is thus possible that Au can diffuse into CH3NH3PbI3 under bias in devices (e.g., solar cell, photodetector) with Au/CH 3NH 3PbI 3 interfaces and modify the electronic properties of CH 3NH 3PbI 3.« less

In vivo assessment of liver fibrosis using diffuse reflectance and fluorescence spectroscopy: a proof of concept.

PubMed

Fabila, Diego; de la Rosa, José Manuel; Stolik, Suren; Moreno, Edgard; Suárez-Álvarez, Karina; López-Navarrete, Giuliana; Guzmán, Carolina; Aguirre-García, Jesús; Acevedo-García, Christian; Kershenobich, David; Escobedo, Galileo

2012-12-01

A novel application of diffuse reflectance and fluorescence spectroscopy in the assessment of liver fibrosis is here reported. To induce different stages of liver fibrosis, a sufficient number of male Wistar rats were differentially exposed to chronic administration with carbon tetrachloride. Then, diffuse reflectance and fluorescence spectra were in vivo measured from the liver surface of each animal by a minimal invasive laparoscopic procedure. The liver fibrosis degree was conventionally determined by means of histological examination using the Mason's Trichrome stain, accompanied by hepatic expression of α-sma, and evaluation of the ALT/AST serum levels. The liver from rats exhibiting higher grades of fibrosis showed a significant increase in diffuse reflectance and fluorescence intensity when compared with control animals. At 365 nm, the diffuse reflectance spectrum exhibited an increase of 4 and 3-fold in mild and advanced fibrotic rats, respectively, when compared to the control group. Similarly, the fluorescence emission at 493 nm was 2-fold higher in fibrotic animals than in controls. By using fluorescence intensity, discrimination algorithms indicated 73% sensitivity and 94% specificity for recognition of hepatic fibrosis, while for diffuse reflectance, these values increased up to 85% and 100%, respectively. Taking into consideration there is a special need for developing new diagnostic approaches focused on detecting different stages of liver fibrosis with minimal invasiveness, these results suggest that diffuse reflectance and fluorescence spectroscopy could be worthy of further exploration in patients with liver disease. Copyright © 2012 Elsevier B.V. All rights reserved.

Understanding the role of silica nanospheres with their light scattering and energy barrier properties in enhancing the photovoltaic performance of ZnO based solar cells.

PubMed

Banik, Avishek; Ansari, Mohammad Shaad; Sahu, Tushar Kanta; Qureshi, Mohammad

2016-10-12

The present study discusses the design and development of a dye sensitized solar cell (DSSC) using a hybrid composite of ZnO nanoparticles (ZnO NP) and silica nanospheres (SiO 2 NS). A ≈22% enhancement in the overall power conversion efficiency (PCE, η) was observed for the device fabricated with a binary hybrid composite of 1 wt% SiO 2 NS and ZnO NP compared to the pristine ZnO NP device. A systematic investigation revealed the dual function of the silica nanospheres in enhancing the device efficacy compared to the bare ZnO NP based device. Sub-micron sized SiO 2 NS can boost the light harvesting efficiency of the photoanode by optical confinement, resulting in increased propagation length of the incident light by multiple internal reflections, which was confirmed by UV-Vis diffused reflectance spectroscopy. Electrochemical impedance spectroscopic (EIS) analysis showed a reduced recombination of photo-generated electrons to the I - /I 3 - redox shuttle in the case of the composite photoanode. The higher recombination resistance (R ct ) in the case of a 1 wt% composite indicates that the SiO 2 NS serves as a partial energy barrier layer to retard the interfacial recombination (back transfer) of photo-generated electrons at the working electrode/electrolyte interface, increasing the device efficiency.

Solar hydrogen and solar electricity using mesoporous materials

NASA Astrophysics Data System (ADS)

Mahoney, Luther

The development of cost-effective materials for effective utilization of solar energy is a major challenge for solving the energy problems that face the world. This thesis work relates to the development of mesoporous materials for solar energy applications in the areas of photocatalytic water splitting and the generation of electricity. Mesoporous materials were employed throughout the studies because of their favorable physico-chemical properties such as high surface areas and large porosities. The first project was related to the use of a cubic periodic mesoporous material, MCM-48. The studies showed that chromium loading directly affected the phase of mesoporous silica formed. Furthermore, within the cubic MCM-48 structure, the loading of polychromate species determined the concentration of solar hydrogen produced. In an effort to determine the potential of mesoporous materials, titanium dioxide was prepared using the Evaporation-Induced Self-Assembly (EISA) synthetic method. The aging period directly determined the amount of various phases of titanium dioxide. This method was extended for the preparation of cobalt doped titanium dioxide for solar simulated hydrogen evolution. In another study, metal doped systems were synthesized using the EISA procedure and rhodamine B (RhB) dye sensitized and metal doped titania mesoporous materials were evaluated for visible light hydrogen evolution. The final study employed various mesoporous titanium dioxide materials for N719 dye sensitized solar cell (DSSC) materials for photovoltaic applications. The materials were extensively characterized using powder X-ray diffraction (XRD), nitrogen physisorption, diffuse reflectance spectroscopy (DRS), UV-Vis spectroscopy, Fourier-Transform-Infrared Spectroscopy (FT-IR), Raman spectroscopy, chemisorption, photoluminescence (PL), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). In addition, photoelectrochemical measurements were completed using current-voltage (I-V) curves, external quantum efficiency (EQE) curves, electrochemical impedance spectroscopy (EIS), and transient spectroscopy. The thesis work presented provides a better understanding of the role of mesoporous materials for solar hydrogen and solar electricity production.

The angular distribution of diffusely backscattered light

NASA Astrophysics Data System (ADS)

Vera, M. U.; Durian, D. J.

1997-03-01

The diffusion approximation predicts the angular distribution of light diffusely transmitted through an opaque slab to depend only on boundary reflectivity, independent of scattering anisotropy, and this has been verified by experiment(M.U. Vera and D.J. Durian, Phys. Rev. E 53) 3215 (1996). Here, by contrast, we demonstrate that the angular distribution of diffusely backscattered light depends on scattering anisotropy as well as boundary reflectivity. To model this observation scattering anisotropy is added to the diffusion approximation by a discontinuity in the photon concentration at the source point that is proportional to the average cosine of the scattering angle. We compare the resulting predictions with random walk simulations and with measurements of diffusely backscattered intensity versus angle for glass frits and aqueous suspensions of polystyrene spheres held in air or immersed in a water bath. Increasing anisotropy and boundary reflectivity each tend to flatten the predicted distributions, and for different combinations of anisotropy and reflectivity the agreement between data and predictions ranges from qualitatively to quantitatively good.

Design and evaluation of an imaging spectrophotometer incorporating a uniform light source.

PubMed

Noble, S D; Brown, R B; Crowe, T G

2012-03-01

Accounting for light that is diffusely scattered from a surface is one of the practical challenges in reflectance measurement. Integrating spheres are commonly used for this purpose in point measurements of reflectance and transmittance. This solution is not directly applicable to a spectral imaging application for which diffuse reflectance measurements are desired. In this paper, an imaging spectrophotometer design is presented that employs a uniform light source to provide diffuse illumination. This creates the inverse measurement geometry to the directional illumination/diffuse reflectance mode typically used for point measurements. The final system had a spectral range between 400 and 1000 nm with a 5.2 nm resolution, a field of view of approximately 0.5 m by 0.5 m, and millimeter spatial resolution. Testing results indicate illumination uniformity typically exceeding 95% and reflectance precision better than 1.7%.

Soybean canopy reflectance as a function of view and illumination geometry

NASA Technical Reports Server (NTRS)

Ranson, K. J.; Vanderbilt, V. C.; Biehl, L. L.; Robinson, B. F.; Bauer, M. E.

1981-01-01

Reflectances were calculated from measurements at four wavelength bands through eight view azimuth and seven view zenith directions, for various solar zenith and azimuth angles over portions of three days, in an experimental characterization of a soybean field by means of its reflectances and physical and agronomic attributes. Results indicate that the distribution of reflectance from a soybean field is a function of the solar illumination and viewing geometry, wavelength, and row direction, as well as the state of canopy development. Shadows between rows were found to affect visible wavelength band reflectance to a greater extent than near-IR reflectance. A model describing reflectance variation as a function of projected solar and viewing angles is proposed, which approximates the visible wavelength band reflectance variations of a canopy with a well-defined row structure.

Descent imager/spectral radiometer (DISR) instrument aboard the Huygens probe of Titan

NASA Astrophysics Data System (ADS)

Tomasko, Martin G.; Doose, Lyn R.; Smith, Peter H.; Fellows, C.; Rizk, B.; See, C.; Bushroe, M.; McFarlane, E.; Wegryn, E.; Frans, E.; Clark, R.; Prout, M.; Clapp, S.

1996-10-01

The Huygen's probe of the atmosphere of Saturn's moon Titan includes one optical instrument sensitive to the wavelengths of solar radiation. The goals of this investigation fall into four broad areas: 1) the measurement of the profile of solar heating to support an improved understanding of the thermal balance of Titan and the role of the greenhouse effect in maintaining Titan's temperature structure; 2) the measurement of the size, vertical distribution, and optical properties of the aerosol and cloud particles in Titan's atmosphere to support studies of the origin, chemistry, life cycles, and role in the radiation balance of Titan played by these particles; 3) the composition of the atmosphere, particularly the vertical profile of the mixing ratio of methane, a condensable constituent in Titan's atmosphere; and 4) the physical state, composition, topography, and physical processes at work in determining the nature of the surface of Titan and its interaction with Titan's atmosphere. In order to accomplish these objectives, the Descent Imager/Spectral Radiometer (DISR) instrument makes extensive use of fiber optics to bring the light from several different sets of foreoptics to a silicon CCD detector, to a pair of InGaAs linear array detectors, and to three silicon photometers. Together these detectors permit DISR to make panoramic images of the clouds and surface of Titan, to measure the spectrum of upward and downward streaming sunlight from 350 to 1700 nm at a resolving power of about 200, to measure the reflection spectrum of >= 3000 locations on the surface, to measure the brightness and polarization of the solar aureole between 4 and 30 degrees from the sun at 500 and 935 nm, to separate the direct and diffuse downward solar flux at each wavelength measured, and to measure the continuous reflection spectrum of the ground between 850 and 1600 nm using an onboard lamp in the last 100 m of the descent.

Limiting loss mechanisms in 23% efficient silicon solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aberle, A.G.; Altermatt, P.P.; Heiser, G.

1995-04-01

The ``passivated emitter and rear locally diffused`` (PERL) silicon solar cell structure presently demonstrates the highest terrestrial performance of any silicon-based solar cell. This paper presents a detailed investigation of the limiting loss mechanisms in PERL cells exhibiting independently confirmed 1-sun efficiencies of up to 23.0%. Optical, resistive, and recombinative losses are all analyzed under the full range of solar cell operating conditions with the aid of two-dimensional (2D) device simulations. The analysis is based on measurements of the reflectance, quantum efficiency, dark and illuminated current--voltage ({ital I}--{ital V}) characteristics, and properties of the Si--SiO{sub 2} interfaces employed on thesemore » cells for surface passivation. Through the use of the 2D simulations, particular attention has been paid to the magnitudes of the spatially resolved recombination losses in these cells. It is shown that approximately 50% of the recombination losses at the 1-sun maximum power point occur in the base of the cells, followed by recombination losses at the rear and front oxidized surfaces (25% and {lt}25%, respectively). The relatively low fill factors of PERL cells are principally a result of resistive losses; however, the recombination behavior in the base and at the rear surface also contributes. This work predicts that the efficiency of 23% PERL cells could be increased by about 0.7% absolute if ohmic losses were eliminated, a further 1.1% absolute if there were no reflection losses at the nonmetallized front surface regions, about 2.0% by introducing ideal light trapping and eliminating shading losses due to the front metallization, and by about 3.7% absolute if the device had no defect-related recombination losses. New design rules for future efficiency improvements, evident from this analysis, are also presented. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.« less

Three-Axis Attitude Control of Solar Sails Utilising Reflectivity Control Devices

NASA Astrophysics Data System (ADS)

Theodorou, Theodoros

Solar sails are spacecraft that utilise the Solar Radiation Pressure, the force generated by impinging photons, to propel themselves. Conventional actuators are not suitable for controlling the attitude of solar sails therefore specific attitude control methods have been devised to tackle this. One of these methods is to change the centre of pressure with respect to the center of mass thus creating a torque. Reflectivity Control Devices (RCDs) have been proposed and successfully used to change the centre of pressure. Current methods that utilise RCDs have control authority over two axis only with no ability to control the torque about the normal of the sail surface. This thesis extends the state of the art and demonstrates 3-axis control by generating arbitrary torque vectors within a convex polyhedron. Two different RCD materials are considered, transmission and diffusion technologies both compatible with the proposed concept. A number of metrics have been developed which facilitate the comparison of different sail configurations. One of these metics is the sun map which is a graphic representation of the sun angles for which control authority is maintained. An iterative design process is presented which makes use of the metrics developed and aids in the design of a sail which meets the mission requirements and constraints. Moreover, the effects of different parameters on the performance of the proposed control concept are discussed. For example it is shown that by alternating the angle between the edge and middle RCDs the control authority increases. The concept's scalability has been investigated and a hybrid control scheme has been devised which makes use of both RCDs and reaction wheels. The RCDs are complemented by the reaction wheels to achieve higher slew rates while in turn the RCDs desaturate the reaction wheels. Finally, a number of simulations are conducted to verify the validity of the proposed concept.

Thermal implications of interactions between insulation, solar reflectance, and fur structure in the summer coats of diverse species of kangaroo.

PubMed

Dawson, Terence J; Maloney, Shane K

2017-04-01

Not all of the solar radiation that impinges on a mammalian coat is absorbed and converted into thermal energy at the coat surface. Some is reflected back to the environment, while another portion is reflected further into the coat where it is absorbed and manifested as heat at differing levels. Substantial insulation in a coat limits the thermal impact at the skin of solar radiation, irrespective where in the coat it is absorbed. In coats with low insulation, the zone where solar radiation is absorbed may govern the consequent heat load on the skin (HL-SR). Thin summer furs of four species of kangaroo from differing climatic zones were used to determine how variation in insulation and in coat spectral and structural characteristics influence the HL-SR. Coat depth, structure, and solar reflectance varied between body regions, as well as between species. The modulation of solar radiation and resultant heat flows in these coats were measured at low (1 m s -1 ) and high (6 m s -1 ) wind speeds by mounting them on a heat flux transducer/temperature-controlled plate apparatus in a wind tunnel. A lamp with a spectrum similar to solar radiation was used as a proxy for the sun. We established that coat insulation was largely determined by coat depth at natural fur lie, despite large variations in fibre density, fibre diameter, and fur mass. Higher wind speed decreased coat insulation, but depth still determined the overall level. A multiple regression analysis that included coat depth (insulation), fibre diameter, fibre density, and solar reflectance was used to determine the best predictors of HL-SR. Only depth and reflectance had significant impacts and both factors had negative weights, so, as either insulation or reflectance increased, HL-SR declined, the larger impact coming from coat reflectance. This reverses the pattern observed in deep coats where insulation dominates over effects of reflectance. Across all coats, as insulation declined, reflectance increased. An increase in reflectance in the thinnest coats was not the sole reason for the limited rise in HL-SR. Higher reflectance should increase the depth of penetrance of solar radiation, thus increasing HL-SR. But in M. antilopinus and Macropus rufus, which had the highest of coat reflectances, penetrance was relatively shallow. This effect appears due to high fibre density (M. rufus) and major modifications in the fibre structure (M. antilopinus). The differing adaptations likely relate to the habitats of these species, desert in the case of M. rufus and monsoon tropical woodland with M. antilopinus.

Including scattering within the room acoustics diffusion model: An analytical approach.

PubMed

Foy, Cédric; Picaut, Judicaël; Valeau, Vincent

2016-10-01

Over the last 20 years, a statistical acoustic model has been developed to predict the reverberant sound field in buildings. This model is based on the assumption that the propagation of the reverberant sound field follows a transport process and, as an approximation, a diffusion process that can be easily solved numerically. This model, initially designed and validated for rooms with purely diffuse reflections, is extended in the present study to mixed reflections, with a proportion of specular and diffuse reflections defined by a scattering coefficient. The proposed mathematical developments lead to an analytical expression of the diffusion constant that is a function of the scattering coefficient, but also on the absorption coefficient of the walls. The results obtained with this extended diffusion model are then compared with the classical diffusion model, as well as with a sound particles tracing approach considering mixed wall reflections. The comparison shows a good agreement for long rooms with uniform low absorption (α = 0.01) and uniform scattering. For a larger absorption (α = 0.1), the agreement is moderate, due to the fact that the proposed expression of the diffusion coefficient does not vary spatially. In addition, the proposed model is for now limited to uniform diffusion and should be extended in the future to more general cases.

Dispersion of the solar magnetic flux in the undisturbed photosphere as derived from SDO/HMI data

NASA Astrophysics Data System (ADS)

Abramenko, Valentina I.

2017-11-01

To explore the magnetic flux dispersion in the undisturbed solar photosphere, magnetograms acquired by Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamic Observatory (SDO) were utilized. Two areas, a coronal hole (CH) area and an area of super-granulation (SG) pattern, were analysed. We explored the displacement and separation spectra and the behaviour of the turbulent diffusion coefficient, K. The displacement and separation spectra are very similar to each other. Small magnetic elements (of size 3-100 squared pixels and the detection threshold of 20 Mx sm-2) in both CH and SG areas disperse in the same way and they are more mobile than the large elements (of size 20-400 squared pixels and the detection threshold of 130 Mx sm-2). The regime of super-diffusivity is found for small elements (γ ≈ 1.3 and K growing from ˜100 to ˜ 300 km2 s-1). Large elements in the CH area are scanty and show super-diffusion with γ ≈ 1.2 and K = (62-96) km2 s-1 on a rather narrow range of 500-2200 km. Large elements in the SG area demonstrate two ranges of linearity and two diffusivity regimes: sub-diffusivity on scales 900-2500 km with γ = 0.88 and K decreasing from ˜130 to ˜100 km2 s-1, and super-diffusivity on scales 2500-4800 km with γ ≈ 1.3 and K growing from ˜140 to ˜200 km2 s-1. A comparison of our results with the previously published shows that there is a tendency of saturation of the diffusion coefficient on large scales, I.e. the turbulent regime of super-diffusivity is gradually replaced by normal diffusion.

Acceleration of Particles Near Earth's Bow Shock

NASA Astrophysics Data System (ADS)

Sandroos, A.

2012-12-01

Collisionless shock waves, for example, near planetary bodies or driven by coronal mass ejections, are a key source of energetic particles in the heliosphere. When the solar wind hits Earth's bow shock, some of the incident particles get reflected back towards the Sun and are accelerated in the process. Reflected ions are responsible for the creation of a turbulent foreshock in quasi-parallel regions of Earth's bow shock. We present first results of foreshock macroscopic structure and of particle distributions upstream of Earth's bow shock, obtained with a new 2.5-dimensional self-consistent diffusive shock acceleration model. In the model particles' pitch angle scattering rates are calculated from Alfvén wave power spectra using quasilinear theory. Wave power spectra in turn are modified by particles' energy changes due to the scatterings. The new model has been implemented on massively parallel simulation platform Corsair. We have used an earlier version of the model to study ion acceleration in a shock-shock interaction event (Hietala, Sandroos, and Vainio, 2012).

Polycrystalline Silicon Thin-film Solar cells with Plasmonic-enhanced Light-trapping

PubMed Central

Varlamov, Sergey; Rao, Jing; Soderstrom, Thomas

2012-01-01

One of major approaches to cheaper solar cells is reducing the amount of semiconductor material used for their fabrication and making cells thinner. To compensate for lower light absorption such physically thin devices have to incorporate light-trapping which increases their optical thickness. Light scattering by textured surfaces is a common technique but it cannot be universally applied to all solar cell technologies. Some cells, for example those made of evaporated silicon, are planar as produced and they require an alternative light-trapping means suitable for planar devices. Metal nanoparticles formed on planar silicon cell surface and capable of light scattering due to surface plasmon resonance is an effective approach. The paper presents a fabrication procedure of evaporated polycrystalline silicon solar cells with plasmonic light-trapping and demonstrates how the cell quantum efficiency improves due to presence of metal nanoparticles. To fabricate the cells a film consisting of alternative boron and phosphorous doped silicon layers is deposited on glass substrate by electron beam evaporation. An Initially amorphous film is crystallised and electronic defects are mitigated by annealing and hydrogen passivation. Metal grid contacts are applied to the layers of opposite polarity to extract electricity generated by the cell. Typically, such a ~2 μm thick cell has a short-circuit current density (Jsc) of 14-16 mA/cm2, which can be increased up to 17-18 mA/cm2 (~25% higher) after application of a simple diffuse back reflector made of a white paint. To implement plasmonic light-trapping a silver nanoparticle array is formed on the metallised cell silicon surface. A precursor silver film is deposited on the cell by thermal evaporation and annealed at 23°C to form silver nanoparticles. Nanoparticle size and coverage, which affect plasmonic light-scattering, can be tuned for enhanced cell performance by varying the precursor film thickness and its annealing conditions. An optimised nanoparticle array alone results in cell Jsc enhancement of about 28%, similar to the effect of the diffuse reflector. The photocurrent can be further increased by coating the nanoparticles by a low refractive index dielectric, like MgF2, and applying the diffused reflector. The complete plasmonic cell structure comprises the polycrystalline silicon film, a silver nanoparticle array, a layer of MgF2, and a diffuse reflector. The Jsc for such cell is 21-23 mA/cm2, up to 45% higher than Jsc of the original cell without light-trapping or ~25% higher than Jsc for the cell with the diffuse reflector only. Introduction Light-trapping in silicon solar cells is commonly achieved via light scattering at textured interfaces. Scattered light travels through a cell at oblique angles for a longer distance and when such angles exceed the critical angle at the cell interfaces the light is permanently trapped in the cell by total internal reflection (Animation 1: Light-trapping). Although this scheme works well for most solar cells, there are developing technologies where ultra-thin Si layers are produced planar (e.g. layer-transfer technologies and epitaxial c-Si layers) 1 and or when such layers are not compatible with textures substrates (e.g. evaporated silicon) 2. For such originally planar Si layer alternative light trapping approaches, such as diffuse white paint reflector 3, silicon plasma texturing 4 or high refractive index nanoparticle reflector 5 have been suggested. Metal nanoparticles can effectively scatter incident light into a higher refractive index material, like silicon, due to the surface plasmon resonance effect 6. They also can be easily formed on the planar silicon cell surface thus offering a light-trapping approach alternative to texturing. For a nanoparticle located at the air-silicon interface the scattered light fraction coupled into silicon exceeds 95% and a large faction of that light is scattered at angles above critical providing nearly ideal light-trapping condition (Animation 2: Plasmons on NP). The resonance can be tuned to the wavelength region, which is most important for a particular cell material and design, by varying the nanoparticle average size, surface coverage and local dielectric environment 6,7. Theoretical design principles of plasmonic nanoparticle solar cells have been suggested 8. In practice, Ag nanoparticle array is an ideal light-trapping partner for poly-Si thin-film solar cells because most of these design principle are naturally met. The simplest way of forming nanoparticles by thermal annealing of a thin precursor Ag film results in a random array with a relatively wide size and shape distribution, which is particularly suitable for light-trapping because such an array has a wide resonance peak, covering the wavelength range of 700-900 nm, important for poly-Si solar cell performance. The nanoparticle array can only be located on the rear poly-Si cell surface thus avoiding destructive interference between incident and scattered light which occurs for front-located nanoparticles 9. Moreover, poly-Si thin-film cells do not requires a passivating layer and the flat base-shaped nanoparticles (that naturally result from thermal annealing of a metal film) can be directly placed on silicon further increases plasmonic scattering efficiency due to surface plasmon-polariton resonance 10. The cell with the plasmonic nanoparticle array as described above can have a photocurrent about 28% higher than the original cell. However, the array still transmits a significant amount of light which escapes through the rear of the cell and does not contribute into the current. This loss can be mitigated by adding a rear reflector to allow catching transmitted light and re-directing it back to the cell. Providing sufficient distance between the reflector and the nanoparticles (a few hundred nanometers) the reflected light will then experience one more plasmonic scattering event while passing through the nanoparticle array on re-entering the cell and the reflector itself can be made diffuse - both effects further facilitating light scattering and hence light-trapping. Importantly, the Ag nanoparticles have to be encapsulated with an inert and low refractive index dielectric, like MgF2 or SiO2, from the rear reflector to avoid mechanical and chemical damage 7. Low refractive index for this cladding layer is required to maintain a high coupling fraction into silicon and larger scattering angles, which are ensured by the high optical contrast between the media on both sides of the nanoparticle, silicon and dielectric 6. The photocurrent of the plasmonic cell with the diffuse rear reflector can be up to 45% higher than the current of the original cell or up to 25% higher than the current of an equivalent cell with the diffuse reflector only. PMID:22805108

The streaming of 1.3 - 2.3 MeV cosmic-ray protons during periods between prompt solar particle events. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Marshall, F. E.

1977-01-01

The anisotropy of 1.3 to 2.3 MeV protons in interplanetary space was measured using the Caltech electron/isotope spectrometer aboard IMP-7 for 317 6 hour periods from 72/273 to 74/2. Periods dominated by prompt solar particle events are not included. The convective and diffusive anisotropies were determined from the observed anisotropy using concurrent solar wind speed measurements and observed energy spectra. The diffusive flow of particles was found to be typically toward the sun, indicating a positive radial gradient in the particle density. This anisotropy was inconsistent with previously proposed sources of low energy proton increases seen at 1 AU which involve continual solar acceleration. The typical properties of this new component of low-energy cosmic rays were determined for this period which is near solar minimum.

Ion Acceleration by Multiple Reflections at Martian Bow Shock

NASA Astrophysics Data System (ADS)

Yamauchi, M.; Futaana, Y.; Fedorov, A.; Frahm, R. A.; Dubinin, E.; Lundin, R.; Sauvaud, J.-A.; Winningham, J. D.; Barabash, S.; Holmström, H.

2012-04-01

The ion mass analyzer (IMA) on board Mars Express revealed bundled structures of ions in the energy domain within a distance of a proton gyroradius from the Martian bow shock. Seven prominent traversals during 2005 were examined when the energy-bunched structure was observed together with pick-up ions of exospheric origin, the latter of which is used to determine the local magnetic field orientation from its circular trajectory in velocity space. These seven traversals include different bow shock configurations: (a) quasi-perpendicular shock with its specular direction of the solar wind more perpendicular to the magnetic field (QT), (b) quasi-perpendicular shock with its specular reflection direction of the solar wind more along the magnetic field (FS), and (c) quasi-parallel (QL) shock. In all seven cases, the velocity components of the energy-bunched structure are consistent with multiple specular reflections of the solar wind at the bow shock up to at least two reflections. The accelerated solar wind ions after two specular reflections have large parallel components with respect to the magnetic field for the QL shock whereas the field-aligned speed is much smaller than the perpendicular speed for the QT shock. The reflected ions escape into the solar wind when and only when the reflection is in the field-aligned direction.

Photovoltaic characteristics of diffused P/+N bulk GaAs solar cells

NASA Technical Reports Server (NTRS)

Borrego, J. M.; Keeney, R. P.; Bhat, I. B.; Bhat, K. N.; Sundaram, L. G.; Ghandhi, S. K.

1982-01-01

The photovoltaic characteristics of P(+)N junction solar cells fabricated on bulk GaAs by an open tube diffusion technique are described in this paper.Spectral response measurements were analyzed in detail and compared to a computer simulation in order to determine important material parameters. It is projected that proper optimization of the cell parameters can increase the efficiency of the cells from 12.2 percent to close to 20 percent.

Exciton delocalization incorporated drift-diffusion model for bulk-heterojunction organic solar cells

NASA Astrophysics Data System (ADS)

Wang, Zi Shuai; Sha, Wei E. I.; Choy, Wallace C. H.

2016-12-01

Modeling the charge-generation process is highly important to understand device physics and optimize power conversion efficiency of bulk-heterojunction organic solar cells (OSCs). Free carriers are generated by both ultrafast exciton delocalization and slow exciton diffusion and dissociation at the heterojunction interface. In this work, we developed a systematic numerical simulation to describe the charge-generation process by a modified drift-diffusion model. The transport, recombination, and collection of free carriers are incorporated to fully capture the device response. The theoretical results match well with the state-of-the-art high-performance organic solar cells. It is demonstrated that the increase of exciton delocalization ratio reduces the energy loss in the exciton diffusion-dissociation process, and thus, significantly improves the device efficiency, especially for the short-circuit current. By changing the exciton delocalization ratio, OSC performances are comprehensively investigated under the conditions of short-circuit and open-circuit. Particularly, bulk recombination dependent fill factor saturation is unveiled and understood. As a fundamental electrical analysis of the delocalization mechanism, our work is important to understand and optimize the high-performance OSCs.

Monte Carlo random walk simulation of electron transport in confined porous TiO{sub 2} as a promising candidate for photo-electrode of nano-crystalline solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Javadi, M.; Abdi, Y., E-mail: y.abdi@ut.ac.ir

2015-08-14

Monte Carlo continuous time random walk simulation is used to study the effects of confinement on electron transport, in porous TiO{sub 2}. In this work, we have introduced a columnar structure instead of the thick layer of porous TiO{sub 2} used as anode in conventional dye solar cells. Our simulation results show that electron diffusion coefficient in the proposed columnar structure is significantly higher than the diffusion coefficient in the conventional structure. It is shown that electron diffusion in the columnar structure depends both on the cross section area of the columns and the porosity of the structure. Also, wemore » demonstrate that such enhanced electron diffusion can be realized in the columnar photo-electrodes with a cross sectional area of ∼1 μm{sup 2} and porosity of 55%, by a simple and low cost fabrication process. Our results open up a promising approach to achieve solar cells with higher efficiencies by engineering the photo-electrode structure.« less

Dye adsorption mechanisms in TiO2 films, and their effects on the photodynamic and photovoltaic properties in dye-sensitized solar cells.

PubMed

Hwang, Kyung-Jun; Shim, Wang-Geun; Kim, Youngjin; Kim, Gunwoo; Choi, Chulmin; Kang, Sang Ook; Cho, Dae Won

2015-09-14

The adsorption mechanism for the N719 dye on a TiO2 electrode was examined by the kinetic and diffusion models (pseudo-first order, pseudo-second order, and intra-particle diffusion models). Among these methods, the observed adsorption kinetics are well-described using the pseudo-second order model. Moreover, the film diffusion process was the main controlling step of adsorption, which was analysed using a diffusion-based model. The photodynamic properties in dye-sensitized solar cells (DSSCs) were investigated using time-resolved transient absorption techniques. The photodynamics of the oxidized N719 species were shown to be dependent on the adsorption time, and also the adsorbed concentration of N719. The photovoltaic parameters (Jsc, Voc, FF and η) of this DSSC were determined in terms of the dye adsorption amounts. The solar cell performance correlates significantly with charge recombination and dye regeneration dynamics, which are also affected by the dye adsorption amounts. Therefore, the photovoltaic performance of this DSSC can be interpreted in terms of the adsorption kinetics and the photodynamics of oxidized N719.

Monte Carlo random walk simulation of electron transport in confined porous TiO2 as a promising candidate for photo-electrode of nano-crystalline solar cells

NASA Astrophysics Data System (ADS)

Javadi, M.; Abdi, Y.

2015-08-01

Monte Carlo continuous time random walk simulation is used to study the effects of confinement on electron transport, in porous TiO2. In this work, we have introduced a columnar structure instead of the thick layer of porous TiO2 used as anode in conventional dye solar cells. Our simulation results show that electron diffusion coefficient in the proposed columnar structure is significantly higher than the diffusion coefficient in the conventional structure. It is shown that electron diffusion in the columnar structure depends both on the cross section area of the columns and the porosity of the structure. Also, we demonstrate that such enhanced electron diffusion can be realized in the columnar photo-electrodes with a cross sectional area of ˜1 μm2 and porosity of 55%, by a simple and low cost fabrication process. Our results open up a promising approach to achieve solar cells with higher efficiencies by engineering the photo-electrode structure.

Solar energy potential in the United Arab Emirates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khalil, A.; Alnajjar, A.

1995-12-31

In the present study, the global, direct and diffuse components of solar radiation as well as temperature, relative humidity and wind speed have been continuously monitored and analyzed on hourly, daily and monthly basis. Experimental data is compared to the predictions of different theoretical models as functions of declination and hour angles. Correlations are obtained describing the variation of hourly, daily and monthly averages of total and diffuse solar radiation using polynomial expressions. Empirical correlations describing the dependence of the daily average diffuse to total radiation ratio on the clearness index are also obtained. Data of daily diffuse to totalmore » radiation ratio is compared to correlations obtained by other investigators. The comparison shows a reasonable agreement with some scatter due to the seasonal dependence of the correlation. Comparison of calculations with experimental measurements under clear sky conditions show excellent agreement with a maximum error of 8%. The measured ratio of hourly to daily insolation is in excellent agreement with the model of Hottel which is expressed as a function of the clearness index, hour and the sunset hour angles.« less

Solar Radiation Monitoring Station (SoRMS): Humboldt State University, Arcata, California (Data)

DOE Data Explorer

Wilcox, S.; Andreas, A.

2007-05-02

A partnership with HSU and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect solar data to support future solar power generation in the United States. The measurement station monitors global horizontal, direct normal, and diffuse horizontal irradiance to define the amount of solar energy that hits this particular location.

Calculations of the cosmic ray modulation in interplanetary space taking into account the possible dependence of the transport travel for the scattering of the particles and of the velocity of the solar winds on the angles they make with the helioequator plane: The case of isotropic diffusion

NASA Technical Reports Server (NTRS)

Dorman, L. I.; Kobilinski, Z.

1975-01-01

The modulation of galactic cosmic rays is studied by the magnetic heterogeneities stream on the assumption that the diffusion coefficient is reduced whereas the solar wind velocity is increased with the growth of the angle between the sun's rotation axis and the direction of solar plasma motion. The stationary plane problem of isotropic diffusion is solved as it applies to two cases: (1) with due account of particle retardation by the antiphermium mechanism; and (2) without an account of the above mechanism. This problem is solved by the grid method in the polar coordinate system. The results of the calculations are followed by a discussion of the method of solution and of the errors.

Low temperature Zn diffusion for GaSb solar cell structures fabrication

NASA Technical Reports Server (NTRS)

Sulima, Oleg V.; Faleev, Nikolai N.; Kazantsev, Andrej B.; Mintairov, Alexander M.; Namazov, Ali

1995-01-01

Low temperature Zn diffusion in GaSb, where the minimum temperature was 450 C, was studied. The pseudo-closed box (PCB) method was used for Zn diffusion into GaAs, AlGaAs, InP, InGaAs and InGaAsP. The PCB method avoids the inconvenience of sealed ampoules and proved to be simple and reproducible. The special design of the boat for Zn diffusion ensured the uniformality of Zn vapor pressure across the wafer surface, and thus the uniformity of the p-GaSb layer depth. The p-GaSb layers were studied using Raman scattering spectroscopy and the x-ray rocking curve method. As for the postdiffusion processing, an anodic oxidation was used for a precise thinning of the diffused GaSb layers. The results show the applicability of the PCB method for the large-scale production of the GaSb structures for solar cells.

A Model of Magnetic Braking of Solar Rotation that Satisfies Observational Constraints

NASA Astrophysics Data System (ADS)

Denissenkov, Pavel A.

2010-08-01

The model of magnetic braking of solar rotation considered by Charbonneau & MacGregor has been modified so that it is able to reproduce for the first time the rotational evolution of both the fastest and slowest rotators among solar-type stars in open clusters of different ages, without coming into conflict with other observational constraints, such as the time evolution of the atmospheric Li abundance in solar twins and the thinness of the solar tachocline. This new model assumes that rotation-driven turbulent diffusion, which is thought to amplify the viscosity and magnetic diffusivity in stellar radiative zones, is strongly anisotropic with the horizontal components of the transport coefficients strongly dominating over those in the vertical direction. Also taken into account is the poloidal field decay that helps to confine the width of the tachocline at the solar age. The model's properties are investigated by numerically solving the azimuthal components of the coupled momentum and magnetic induction equations in two dimensions using a finite element method.

Characterizing the reflectivity of handheld display devices.

PubMed

Liu, Peter; Badano, Aldo

2014-08-01

With increased use of handheld and tablet display devices for viewing medical images, methods for consistently measuring reflectivity of the devices are needed. In this note, the authors report on the characterization of diffuse reflections for handheld display devices including mobile phones and tablets using methods recommended by the American Association of Physicists in Medicine Task Group 18 (TG18). The authors modified the diffuse reflectance coefficient measurement method outlined in the TG18 report. The authors measured seven handheld display devices (two phones and five tablets) and three workstation displays. The device was attached to a black panel with Velcro. To study the effect of the back surface on the diffuse reflectance coefficient, the authors created Styrofoam masks with different size square openings and placed it in front of the device. Overall, for each display device, measurements of illuminance and reflected luminance on the display screen were taken. The authors measured with no mask, with masks of varying size, and with display-size masks, and calculated the corresponding diffuse reflectance coefficient. For all handhelds, the diffuse reflectance coefficient measured with no back panel were lower than measurements performed with a mask. The authors found an overall increase in reflectivity as the size of the mask decreases. For workstations displays, diffuse reflectance coefficients were higher when no back panel was used, and higher than with masks. In all cases, as luminance increased, illuminance increased, but not at the same rate. Since the size of handheld displays is smaller than that of workstation devices, the TG18 method suffers from a dependency on illumination condition. The authors show that the diffuse reflection coefficients can vary depending on the nature of the back surface of the illuminating box. The variability in the diffuse coefficient can be as large as 20% depending on the size of the mask. For all measurements, both luminance and illuminance increased as the size of the display window decreased. The TG18 method does not account for this variability. The authors conclude that the method requires a definitive description of the back panel used in the light source setup. The methods described in the TG18 document may need to be improved to provide consistent comparisons of desktop monitors, phones, and tablets.

Tissue differentiation by diffuse reflectance spectroscopy for automated oral and maxillofacial laser surgery: ex vivo pilot study

NASA Astrophysics Data System (ADS)

Zam, Azhar; Stelzle, Florian; Tangermann-Gerk, Katja; Adler, Werner; Nkenke, Emeka; Schmidt, Michael; Douplik, Alexandre

2010-02-01

Remote laser surgery lacks of haptic feedback during the laser ablation of tissue. Hence, there is a risk of iatrogenic damage or destruction of anatomical structures like nerves or salivary glands. Diffuse reflectance spectroscopy provides a straightforward and simple approach for optical tissue differentiation. We measured diffuse reflectance from seven various tissue types ex vivo. We applied Linear Discriminant Analysis (LDA) to differentiate the seven tissue types and computed the area under the ROC curve (AUC). Special emphasis was taken on the identification of nerves and salivary glands as the most crucial tissue for maxillofacial surgery. The results show a promise for differentiating tissues as guidance for oral and maxillofacial laser surgery by means of diffuse reflectance.

Radiometric calibration stability and inter-calibration of solar-band instruments in orbit using the moon

USGS Publications Warehouse

Stone, T.C.

2008-01-01

With the increased emphasis on monitoring the Earth's climate from space, more stringent calibration requirements are being placed on the data products from remote sensing satellite instruments. Among these are stability over decade-length time scales and consistency across sensors and platforms. For radiometer instruments in the solar reflectance wavelength range (visible to shortwave infrared), maintaining calibration on orbit is difficult due to the lack of absolute radiometric standards suitable for flight use. The Moon presents a luminous source that can be viewed by all instruments in Earth orbit. Considered as a solar diffuser, the lunar surface is exceedingly stable. The chief difficulty with using the Moon is the strong variations in the Moon's brightness with illumination and viewing geometry. This mandates the use of a photometric model to compare lunar observations, either over time by the same instrument or between instruments. The U.S. Geological Survey in Flagstaff, Arizona, under NASA sponsorship, has developed a model for the lunar spectral irradiance that explicitly accounts for the effects of phase, the lunar librations, and the lunar surface reflectance properties. The model predicts variations in the Moon's brightness with precision ???1% over a continuous phase range from eclipse to the quarter lunar phases. Given a time series of Moon observations taken by an instrument, the geometric prediction capability of the lunar irradiance model enables sensor calibration stability with sub-percent per year precision. Cross-calibration of instruments with similar passbands can be achieved with precision comparable to the model precision. Although the Moon observations used for intercomparison can be widely separated in phase angle and/or time, SeaWiFS and MODIS have acquired lunar views closely spaced in time. These data provide an example to assess inter-calibration biases between these two instruments.

Determining biological tissue optical properties via integrating sphere spatial measurements

DOEpatents

Baba, Justin S [Knoxville, TN; Letzen, Brian S [Coral Springs, FL

2011-01-11

An optical sample is mounted on a spatial-acquisition apparatus that is placed in or on an enclosure. An incident beam is irradiated on a surface of the sample and the specular reflection is allowed to escape from the enclosure through an opening. The spatial-acquisition apparatus is provided with a light-occluding slider that moves in front of the sample to block portions of diffuse scattering from the sample. As the light-occluding slider moves across the front of the sample, diffuse light scattered into the area of the backside of the light-occluding slider is absorbed by back side surface of the light-occluding slider. By measuring a baseline diffuse reflectance without a light-occluding slider and subtracting measured diffuse reflectance with a light-occluding slider therefrom, diffuse reflectance for the area blocked by the light-occluding slider can be calculated.

Solar concentrator with diffuser segments

NASA Astrophysics Data System (ADS)

Esparza, Diego; Moreno, Ivan

2011-08-01

Solar energy systems use concentrating optics with photovoltaic cells for optimizing the performance. Advanced concentrators are designed to maximize both the light collection and the spatial uniformity of radiation. This is important because irradiance uniformity is critical for all types of photovoltaic cells. This is difficult to achieve with traditional concentrators, which are built with polished optical surfaces. In this work we propose a new concept of solar concentrator which uses small diffuser segments in key points to increase the irradiation uniformity. We experimentally demonstrate this new concept by analyzing the effects on both efficiency and irradiance uniformity due to the incorporation of scattering ribbons in a compound parabolic concentrator.

A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levinson, Ronnen; Akbari, Hashem; Berdahl, Paul

The widespread use of solar-reflective roofing materials can save energy, mitigate urban heat islands and slow global warming by cooling the roughly 20% of the urban surface that is roofed. In this study we created prototype solar-reflective nonwhite concrete tile and asphalt shingle roofing materials using a two-layer spray coating process intended to maximize both solar reflectance and factory-line throughput. Each layer is a thin, quick-drying, pigmented latex paint based on either acrylic or a poly(vinylidene fluoride)/acrylic blend. The first layer is a titanium dioxide rutile white basecoat that increases the solar reflectance of a gray-cement concrete tile from 0.18more » to 0.79, and that of a shingle surfaced with bare granules from 0.06 to 0.62. The second layer is a 'cool' color topcoat with weak near-infrared (NIR) absorption and/or strong NIR backscattering. Each layer dries within seconds, potentially allowing a factory line to pass first under the white spray, then under the color spray. We combined a white basecoat with monocolor topcoats in various shades of red, brown, green and blue to prepare 24 cool color prototype tiles and 24 cool color prototypes shingles. The solar reflectances of the tiles ranged from 0.26 (dark brown; CIELAB lightness value L* = 29) to 0.57 (light green; L* = 76); those of the shingles ranged from 0.18 (dark brown; L* = 26) to 0.34 (light green; L* = 68). Over half of the tiles had a solar reflectance of at least 0.40, and over half of the shingles had a solar reflectance of at least 0.25.« less

Thin film coatings for improved alpha/epi

NASA Technical Reports Server (NTRS)

Krisl, M. E.; Sachs, I. M.

1985-01-01

New thin film coatings were developed for fused silica, ceria doped glass, and Corning 0211 microsheet which provide increased emissivity and/or decreased solar absorption. Emissivity is enhanced by suppression of the reststrahlen reflectance and solar absorption is reduced by externally reflecting the ultraviolet portion of the solar spectrum. Optical properties of these coatings make them suitable for both solar cell cover and thermal control mirror applications. Measurements indicate equivalent environmental performance to conventional solar cell cover and thermal control mirror products.

A New Fast Algorithm to Completely Account for Non-Lambertian Surface Reflection of The Earth

NASA Technical Reports Server (NTRS)

Qin, Wen-Han; Herman, Jay R.; Ahmad, Ziauddin; Einaudi, Franco (Technical Monitor)

2000-01-01

Surface bidirectional reflectance distribution function (BRDF) influences not only radiance just about the surface, but that emerging from the top of the atmosphere (TOA). In this study we propose a new, fast and accurate, algorithm CASBIR (correction for anisotropic surface bidirectional reflection) to account for such influences on radiance measured above TOA. This new algorithm is based on a 4-stream theory that separates the radiation field into direct and diffuse components in both upwelling and downwelling directions. This is important because the direct component accounts for a substantial portion of incident radiation under a clear sky, and the BRDF effect is strongest in the reflection of the direct radiation reaching the surface. The model is validated by comparison with a full-scale, vector radiation transfer model for the atmosphere-surface system. The result demonstrates that CASBIR performs very well (with overall relative difference of less than one percent) for all solar and viewing zenith and azimuth angles considered in wavelengths from ultraviolet to near-infrared over three typical, but very different surface types. Application of this algorithm includes both accounting for non-Lambertian surface scattering on the emergent radiation above TOA and a potential approach for surface BRDF retrieval from satellite measured radiance.

AMC-SWMO Countermeasures Study. Volume 1. Guide to How Countermeasures Affect Smart Weapons

DTIC Science & Technology

1993-06-01

low reflectivity) in a white background (high reflectivity). 4.1.2 IR Slanature Alteration Nonimaging IR signature alteration techniques involve...spots. These techniques can 4-5 SEEKER S......DETETEDSIGNAL AL CONTRAST BETWEEN TARGET AND BACKGROUND Ltgf-’ £tgt L(Ttgt )+ pjgt Lsky/sun/jl 0u Solar ...Reflected Lbklg: 4Okg L(1bkg ) + kg Lsky/sunvcloud Cloud/Sky Reflected Ground Reflected where, Target Emitted Solar Reflected L = integrated radiance

Solar Wind Strahl Broadening by Self-Generated Plasma Waves

NASA Technical Reports Server (NTRS)

Pavan, J.; Vinas, A. F.; Yoon, P. H.; Ziebell, L. F.; Gaelzer, R.

2013-01-01

This Letter reports on the results of numerical simulations which may provide a possible explanation for the strahl broadening during quiet solar conditions. The relevant processes involved in the broadening are due to kinetic quasi-linear wave-particle interaction. Making use of static analytical electron distribution in an inhomogeneous field, it is found that self-generated electrostatic waves at the plasma frequency, i.e., Langmuir waves, are capable of scattering the strahl component, resulting in energy and pitch-angle diffusion that broadens its velocity distribution significantly. The present theoretical results provide an alternative or complementary explanation to the usual whistler diffusion scenario, suggesting that self-induced electrostatic waves at the plasma frequency might play a key role in broadening the solar wind strahl during quiet solar conditions.

On the generation of solar spicules and Alfvénic waves

NASA Astrophysics Data System (ADS)

Martínez-Sykora, J.; De Pontieu, B.; Hansteen, V. H.; Rouppe van der Voort, L.; Carlsson, M.; Pereira, T. M. D.

2017-06-01

In the lower solar atmosphere, the chromosphere is permeated by jets known as spicules, in which plasma is propelled at speeds of 50 to 150 kilometers per second into the corona. The origin of the spicules is poorly understood, although they are expected to play a role in heating the million-degree corona and are associated with Alfvénic waves that help drive the solar wind. We compare magnetohydrodynamic simulations of spicules with observations from the Interface Region Imaging Spectrograph and the Swedish 1-m Solar Telescope. Spicules are shown to occur when magnetic tension is amplified and transported upward through interactions between ions and neutrals or ambipolar diffusion. The tension is impulsively released to drive flows, heat plasma (through ambipolar diffusion), and generate Alfvénic waves.

Broadband diffuse terahertz wave scattering by flexible metasurface with randomized phase distribution

PubMed Central

Zhang, Yin; Liang, Lanju; Yang, Jing; Feng, Yijun; Zhu, Bo; Zhao, Junming; Jiang, Tian; Jin, Biaobing; Liu, Weiwei

2016-01-01

Suppressing specular electromagnetic wave reflection or backward radar cross section is important and of broad interests in practical electromagnetic engineering. Here, we present a scheme to achieve broadband backward scattering reduction through diffuse terahertz wave reflection by a flexible metasurface. The diffuse scattering of terahertz wave is caused by the randomized reflection phase distribution on the metasurface, which consists of meta-particles of differently sized metallic patches arranged on top of a grounded polyimide substrate simply through a certain computer generated pseudorandom sequence. Both numerical simulations and experimental results demonstrate the ultralow specular reflection over a broad frequency band and wide angle of incidence due to the re-distribution of the incident energy into various directions. The diffuse scattering property is also polarization insensitive and can be well preserved when the flexible metasurface is conformably wrapped on a curved reflective object. The proposed design opens up a new route for specular reflection suppression, and may be applicable in stealth and other technology in the terahertz spectrum. PMID:27225031

Broadband diffuse terahertz wave scattering by flexible metasurface with randomized phase distribution.

PubMed

Zhang, Yin; Liang, Lanju; Yang, Jing; Feng, Yijun; Zhu, Bo; Zhao, Junming; Jiang, Tian; Jin, Biaobing; Liu, Weiwei

2016-05-26

Suppressing specular electromagnetic wave reflection or backward radar cross section is important and of broad interests in practical electromagnetic engineering. Here, we present a scheme to achieve broadband backward scattering reduction through diffuse terahertz wave reflection by a flexible metasurface. The diffuse scattering of terahertz wave is caused by the randomized reflection phase distribution on the metasurface, which consists of meta-particles of differently sized metallic patches arranged on top of a grounded polyimide substrate simply through a certain computer generated pseudorandom sequence. Both numerical simulations and experimental results demonstrate the ultralow specular reflection over a broad frequency band and wide angle of incidence due to the re-distribution of the incident energy into various directions. The diffuse scattering property is also polarization insensitive and can be well preserved when the flexible metasurface is conformably wrapped on a curved reflective object. The proposed design opens up a new route for specular reflection suppression, and may be applicable in stealth and other technology in the terahertz spectrum.

Effects of texturization due to chemical etching and laser on the optical properties of multicrystalline silicon for applications in solar cells

NASA Astrophysics Data System (ADS)

Vera, D.; Mass, J.; Manotas, M.; Cabanzo, R.; Mejia, E.

2016-02-01

In this work we carried out the texturization of surfaces of multicrystalline silicon type-p in order to decrease the reflection of light on the surface, using the chemical etching method and then a treatment with laser. In the first method, it was immersed in solutions of HF:HNO3:H2O, HF:HNO3:CH3COOH, HF:HNO3:H3PO4, in the proportion 14:01:05, during 30 seconds, 1, 2 and 3 minutes. Subsequently with a laser (ND:YAG) grids were generated beginning with parallel lines separated 50μm. The samples were analyzed by means of diffuse spectroscopy (UV-VIS) and scanning electron micrograph (SEM) before and after the laser treatment. The lowest result of reflectance obtained by HF:HNO3:H2O during 30 seconds, was of 15.5%. However, after applying the treatment with laser the reflectance increased to 17.27%. On the other hand, the samples treated (30 seconds) with acetic acid and phosphoric acid as diluents gives as a result a decrease in the reflectance values after applying the laser treatment from 21.97% to 17.79% and from 27.73% to 20.03% respectively. The above indicates that in some cases it is possible to decrease the reflectance using jointly the method of chemical etching and then a laser treatment.

Method for fabricating silicon cells

DOEpatents

Ruby, Douglas S.; Basore, Paul A.; Schubert, W. Kent

1998-08-11

A process for making high-efficiency solar cells. This is accomplished by forming a diffusion junction and a passivating oxide layer in a single high-temperature process step. The invention includes the class of solar cells made using this process, including high-efficiency solar cells made using Czochralski-grown silicon.

Mathematical and computational modeling simulation of solar drying Systems

USDA-ARS?s Scientific Manuscript database

Mathematical modeling of solar drying systems has the primary aim of predicting the required drying time for a given commodity, dryer type, and environment. Both fundamental (Fickian diffusion) and semi-empirical drying models have been applied to the solar drying of a variety of agricultural commo...

Development of a Multi-layer Anti-reflective Coating for Gallium Arsenide/Aluminum Gallium Arsenide Solar Cells

DTIC Science & Technology

2015-07-01

optical loss mechanism, which limits the efficiency of the PV device.1 Photon absorption needs to occur inside the solar cell active region (near the...Aluminum Gallium Arsenide Solar Cells by Kimberley A Olver Approved for public release; distribution unlimited...Development of a Multi-layer Anti-reflective Coating for Gallium Arsenide/Aluminum Gallium Arsenide Solar Cells by Kimberley A Olver

Utilization of visible to NIR light energy by Yb+3, Er+3 and Tm+3 doped BiVO4 for the photocatalytic degradation of methylene blue

NASA Astrophysics Data System (ADS)

Regmi, Chhabilal; Kshetri, Yuwaraj K.; Ray, Schindra Kumar; Pandey, Ramesh Prasad; Lee, Soo Wohn

2017-01-01

Lanthanide-doped BiVO4 semiconductors with efficient photocatalytic activities over a broad range of the solar light spectrum have been synthesized by the microwave hydrothermal method using ethylenediaminetetraacetic acid (EDTA). The structural, morphological, and optical properties of the as-synthesized samples were evaluated by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray powder diffraction (XRD), Raman spectroscopy, FT-IR spectroscopy, UV-vis diffuse reflectance spectroscopy (DRS), and photoluminescence spectroscopy (PL). The chemical compositions were analyzed by X-ray photoelectron spectroscopy (XPS). The toxicity of the samples was measured using Mus musculus skin melanoma cells (B16-F10 (ATCC® CRL-6475™)) and were found to be nontoxic for human cells. The photocatalytic efficiency of the prepared samples was evaluated by methylene blue (MB) degradation. The best photocatalytic activity was shown by BiVO4 with 6:3:3 mol percentage of Yb+3:Er+3:Tm+3 in all solar light spectrum. The synthesized samples possess low band gap energy and a hollow structure suitable for the better photocatalytic activity. The observed NIR photoactivity supports that the upconversion mechanism is involved in the overall photocatalytic process. Therefore, this approach provides a better alternative upconversion material for integral solar light absorption.

Effect of Few-Layered Graphene-Based CdO Nanocomposite-Enhanced Power Conversion Efficiency of Dye-Sensitized Solar Cell

NASA Astrophysics Data System (ADS)

Bykkam, Satish; Kalagadda, Bikshalu; Kalagadda, Venkateswara Rao; Ahmadipour, Mohsen; Chakra, Ch. Shilpa; Rajendar, V.

2018-01-01

A few-layered graphene (FLG)/cadmium oxide (CdO) nanocomposite was sucessfully prepared through ultrasonic-assisted synthesis. The morphology of FLG (1.0 wt.%, 2.0 wt.%, and 3.0 wt.%)/CdO nanocomposites were characterized using high-resolution transmission electron microscopy and field emission scanning electron microscopy techniques. The optical properties were studied with the help of UV-Vis diffuse reflectance spectroscopy and Raman spectroscopy, while the crystalline phases were analyzed using x-ray diffraction. The doctor blade method was used to deposit FLG/CdO nanocomposites on fluorine-doped tin oxide conductive glass substrates. The effect of FLG weight percentage (1.0 wt.%, 2.0 wt.%, and 3.0 wt.%) was studied on the power conversion efficiency of dye-sensitized solar cell applications. The photovoltaic characteristics, current density-voltage curves were measured with ruthenium (II)-based dye under air mass condition 1.5G, 100 m W m-2 of a solar simulator. The results showed that higher power conversion efficiency of 3.54% was achieved at the appropriate weight percentage of FLG (1.0 wt.%)/CdO nanocomposite, compared to the CdO and other nanocomposite working electrodes FLG (2.0 wt.%, and 3.0 wt.%)/CdO.

Sol-gel-Derived nano-sized double layer anti-reflection coatings (SiO2/TiO2) for low-cost solar cell fabrication.

PubMed

Lee, Seung Jun; Hur, Man Gyu; Yoon, Dae Ho

2013-11-01

We investigate nano-sized double layer anti-reflection coatings (ARCs) using a TiO2 and SiO2 sol-gel solution process for mono-crystalline silicon solar cells. The process can be easily adapted for spraying sol-gel coatings to reduce manufacturing cost. The spray-coated SiO2/TiO2 nano-sized double layer ARCs were deposited on mono-crystalline silicon solar cells, and they showed good optical properties. The spray coating process is a lower-cost fabrication process for large-scale coating than vacuum deposition processes such as PECVD. The measured average optical reflectance (300-1200 nm) was about approximately 8% for SiO2/TiO2 nano-sized double layer ARCs. The electrical parameters of a mono-crystalline silicon solar cell and reflection losses show that the SiO2/TiO2 stacks can improve cell efficiency by 0.2% compared to a non-coated mono-crystalline silicon solar cell. In the results, good correlation between theoretical and experimental data was obtained. We expect that the sol-gel spray-coated mono-crystalline silicon solar cells have high potential for low-cost solar cell fabrication.

Reduction in Recombination Current Density in Boron Doped Silicon Using Atomic Hydrogen

NASA Astrophysics Data System (ADS)

Young, Matthew Garett

The solar industry has grown immensely in recent years and has reached a point where solar energy has now become inexpensive enough that it is starting to emerge as a mainstream electrical generation source. However, recent economic analysis has suggested that for solar to become a truly wide spread source of electricity, the costs still need to plummet by a factor of 8x. This demands new and innovative concepts to help lower such cost. In pursuit of this goal, this dissertation examines the use of atomic hydrogen to lessen the recombination current density in the boron doped region of n-type silicon solar cells. This required the development of a boron diffusion process that maintained the bulk lifetime of n-type silicon such that the recombination current density could be extracted by photoconductance spectroscopy. It is demonstrated that by hydrogenating boron diffusions, the majority carrier concentration can be controlled. By using symmetrically diffused test structures with quinhydrone-methanol surface passivation the recombination current density of a hydrogenated boron profile is shown to be less than that of a standard boron profile, by as much as 30%. This is then applied to a modified industrial silicon solar cell process to demonstrate an efficiency enhancement of 0.4%.

Growth of Cu2ZnSnSe4 Film under Controllable Se Vapor Composition and Impact of Low Cu Content on Solar Cell Efficiency.

PubMed

Li, Jianjun; Wang, Hongxia; Wu, Li; Chen, Cheng; Zhou, Zhiqiang; Liu, Fangfang; Sun, Yun; Han, Junbo; Zhang, Yi

2016-04-27

It is a challenge to fabricate high quality Cu2ZnSnSe4 (CZTSe) film with low Cu content (Cu/(Zn + Sn) < 0.8). In this work, the growth mechanisms of CZTSe films under different Se vapor composition are investigated by DC-sputtering and a postselenization approach. The composition of Se vapor has important influence on the compactability of the films and the diffusion of elements in the CZTSe films. By adjusting the composition of Se vapor during the selenization process, an optimized two step selenization process is proposed and highly crystallized CZTSe film with low Cu content (Cu/(Zn + Sn) = 0.75) is obtained. Further study of the effect of Cu content on the morphology and photovoltaic performance of the corresponding CZTSe solar cells has shown that the roughness of the CZTSe absorber film increases when Cu content decreases. As a consequence, the reflection loss of CZTSe solar cells reduces dramatically and the short circuit current density of the cells improve from 34.7 mA/cm(2) for Cu/(Zn + Sn) = 0.88 to 38.5 mA/cm(2) for Cu/(Zn + Sn) = 0.75. In addition, the CZTSe solar cells with low Cu content show longer minority carrier lifetime and higher open circuit voltage than the high Cu content devices. A champion performance CZTSe solar cell with 10.4% efficiency is fabricated with Cu/(Zn + Sn) = 0.75 in the CZTSe film without antireflection coating.

Lowry Range Solar Station: Arapahoe County, Colorado (Data)

DOE Data Explorer

Yoder, M.; Andreas, A.

2008-05-30

A partnership with industry and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect solar data to support future solar power generation in the United States. The measurement station monitors global horizontal, direct normal, and diffuse horizontal irradiance to define the amount of solar energy that hits this particular location. The solar measurement instrumentation is also accompanied by meteorological monitoring equipment to provide scientists with a complete picture of the solar power possibilities.

Diffuse solar radiation and associated meteorological parameters in India

NASA Astrophysics Data System (ADS)

Bhattacharya, A. B.; Kar, S. K.; Bhattacharya, R.

1996-10-01

Solar diffuse radiation data including global radiation, shortwave and longwave balances, net radiation and sunshine hours have been extensively analyzed to study the variation of diffuse radiation with turbidity and cloud discharges appearing in the form of atmospherics over the tropics. Results of surface radiation measurements at Calcutta, Poona, Delhi and Madras are presented together with some meteorological parameters. The monthly values of diffuse radiation and the monthly ratios of diffuse to global solar radiation have been examined, with a special emphasis in relation to the noise level of atmospherics at Calcutta in the very low frequency band. The results exhibit some definite seasonal changes which appear to be in close agreement with one another. Acknowledgements. We gratefully appreciate the on-line DMSP database facility at APL (Newell et al., 1991) from which this study has benefited greatly. We wish to thank E. Friis-Christensen for his encouragement and useful discussions. A. Y. would like to thank the Danish Meteorological Institute, where this work was done, for its hospitality during his stay there and the Nordic Baltic Scholarship Scheme for its financial support of this stay. Topical Editor K.-H. Glassmeier thanks M. J. Engebretson and H. Lühr for their help in evaluating this paper.--> Correspondence to: A. Yahnin-->

Building global and diffuse solar radiation series and assessing decadal trends in Girona (NE Iberian Peninsula)

NASA Astrophysics Data System (ADS)

Calbó, Josep; González, Josep-Abel; Sanchez-Lorenzo, Arturo

2017-08-01

Measurement of solar radiation was initiated in Girona, northeast of the Iberian Peninsula, in the late 1980s. Initially, two pyranometers were installed, one of them equipped with a shadowband for measuring the diffuse component. Two other pyranometers currently exist, both ventilated and one of them shadowed, with a sphere, and a pyrheliometer for measuring direct radiation. Additional instruments for other shortwave and longwave components, clouds, and atmospheric aerosols have been installed in recent years. The station is subject to daily inspection, data are saved at high temporal resolution, and instruments are periodically calibrated, all in accordance with the directions of the Baseline Surface Radiation Network. The present paper describes how the entire series of global solar radiation (1987-2014) and diffuse radiation (1994-2014) were built, including the quality control process. Appropriate corrections to the diffuse component were made when a shadowband was employed to make measurements. Analysis of the series reveals that annual mean global irradiance presents a statistically significant increase of 2.5 W m-2 (1.4 %) decade-1 (1988-2014 period), mainly due to what occurs in summer (5.6 W m-2 decade-1). These results constitute the first assessment of solar radiation trends for the northeastern region of the Iberian Peninsula and are consistent with trends observed in the regional surroundings and also by satellite platforms, in agreement with the global brightening phenomenon. Diffuse radiation has decreased at -1.3 W m-2 (-2 %) decade-1 (1994-2014 period), which is a further indication of the reduced cloudiness and/or aerosol load causing the changes.

Ultra-broadband and planar sound diffuser with high uniformity of reflected intensity

NASA Astrophysics Data System (ADS)

Fan, Xu-Dong; Zhu, Yi-Fan; Liang, Bin; Yang, Jing; Yang, Jun; Cheng, Jian-Chun

2017-09-01

Schroeder diffusers, as a classical design of acoustic diffusers proposed over 40 years ago, play key roles in many practical scenarios ranging from architectural acoustics to noise control to particle manipulation. Despite the great success of conventional acoustic diffusers, it is still worth pursuing ideal acoustic diffusers that are essentially expected to produce perfect sound diffuse reflection within the unlimited bandwidth. Here, we propose a different mechanism for designing acoustic diffusers to overcome the basic limits in intensity uniformity and working bandwidth in the previous designs and demonstrate a practical implementation by acoustic metamaterials with dispersionless phase-steering capability. In stark contrast to the existing production of diffuse fields relying on random scattering of sound energy by using a specific mathematical number sequence of periodically distributed unit cells, we directly mold the reflected wavefront into the desired shape by precisely manipulating the local phases of individual subwavelength metastructures. We also benchmark our design via numerical simulation with a commercially available Schroeder diffuser, and the results verify that our proposed diffuser scatters incident acoustic energy into all directions more uniformly within an ultra-broad band regardless of the incident angle. Furthermore, our design enables further improvement of the working bandwidth just by simply downscaling each individual element. With ultra-broadband functionality and high uniformity of reflected intensity, our metamaterial-based production of the diffusive field opens a route to the design and application of acoustic diffusers and may have a significant impact on various fields such as architectural acoustics and medical ultrasound imaging/treatment.

Near-infrared diffuse reflection systems for chlorophyll content of tomato leaves measurement

NASA Astrophysics Data System (ADS)

Jiang, Huanyu; Ying, Yibin; Lu, Huishan

2006-10-01

In this study, two measuring systems for chlorophyll content of tomato leaves were developed based on near-infrared spectral techniques. The systems mainly consists of a FT-IR spectrum analyzer, optic fiber diffuses reflection accessories and data card. Diffuse reflectance of intact tomato leaves was measured by an optics fiber optic fiber diffuses reflection accessory and a smart diffuses reflection accessory. Calibration models were developed from spectral and constituent measurements. 90 samples served as the calibration sets and 30 samples served as the validation sets. Partial least squares (PLS) and principal component regression (PCR) technique were used to develop the prediction models by different data preprocessing. The best model for chlorophyll content had a high correlation efficient of 0.9348 and a low standard error of prediction RMSEP of 4.79 when we select full range (12500-4000 cm -1), MSC path length correction method by the log(1/R). The results of this study suggest that FT-NIR method can be feasible to detect chlorophyll content of tomato leaves rapidly and nondestructively.

Practical issues for using solar-reflective materials to mitigate urban heat islands

NASA Astrophysics Data System (ADS)

Bretz, Sarah; Akbari, Hashem; Rosenfeld, Arthur

Solar-reflective or high-albedo, alternatives to traditionally absorptive urban surfaces such as rooftops and roadways can reduce cooling energy use and improve urban air quality at almost no cost. This paper presents information to support programs that mitigate urban heat islands with solar-reflective surfaces: estimates of the achievable increase in albedo for a variety of surfaces, issues related to the selection of materials and costs and benefits of using them. As an example, we present data for Sacramento, California. In Sacramento, we estimate that 20% of the 96 square mile area is dark roofing and 10% is dark pavement. Based on the change in albedo that is achievable for these surfaces, the overall albedo of Sacramento could be increased by 18%, a change that would produce significant energy savings and increase comfort within the city. Roofing market data indicate which roofing materials should be targeted for incentive programs. In 1995, asphalt shingle was used for over 65% of residential roofing area in the U.S. and 6% of commercial. Built-up roofing was used for about 5% of residential roofing and about 30% of commercial roofing. Single-ply membranes covered about 9% of the residential roofing area and over 30% of the commercial area. White, solar-reflective alternatives are presently available for these roofing materials but a low- first-cost, solar-reflective alternative to asphalt shingles is needed to capture the sloped-roof market. Since incoming solar radiation has a large non-visible component, solar-reflective materials can also be produced in a variety of colors.

SeaWiFS technical report series. Volume 10: Modeling of the SeaWiFS solar and lunar observations

NASA Technical Reports Server (NTRS)

Woodward, Robert H.; Barnes, Robert A.; Mcclain, Charles R.; Esaias, Wayne E.; Barnes, William L.; Mecherikunnel, Ann T.; Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor)

1993-01-01

Post-launch stability monitoring of the Sea-viewing Wide Field-of-view Sensor (SeaWifs) will include periodic sweeps of both an onboard solar diffuser plate and the moon. The diffuser views will provide short-term checks and the lunar views will monitor long-term trends in the instrument's radiometric stability. Models of the expected sensor response to these observations were created on the SeaWiFS computer at the National Aeronautics and Space Administration's (NASA) Goddard Space Flight Center (GSFC) using the Interactive Data Language (IDL) utility with a graphical user interface (GUI). The solar model uses the area of intersecting circles to simulate the ramping of sensor response while viewing the diffuser. This model is compared with preflight laboratory scans of the solar diffuser. The lunar model reads a high-resolution lunar image as input. The observations of the moon are simulated with a bright target recovery algorithm that includes ramping and ringing functions. Tests using the lunar model indicate that the integrated radiance of the entire lunar surface provides a more stable quantity than the mean of radiances from centralized pixels. The lunar model is compared to ground-based scans by the SeaWiFS instrument of a full moon in December 1992. Quality assurance and trend analyses routines for calibration and for telemetry data are also discussed.

Impact of molybdenum out diffusion and interface quality on the performance of sputter grown CZTS based solar cells.

PubMed

Dalapati, Goutam Kumar; Zhuk, Siarhei; Masudy-Panah, Saeid; Kushwaha, Ajay; Seng, Hwee Leng; Chellappan, Vijila; Suresh, Vignesh; Su, Zhenghua; Batabyal, Sudip Kumar; Tan, Cheng Cheh; Guchhait, Asim; Wong, Lydia Helena; Wong, Terence Kin Shun; Tripathy, Sudhiranjan

2017-05-02

We have investigated the impact of Cu 2 ZnSnS 4 -Molybdenum (Mo) interface quality on the performance of sputter-grown Cu 2 ZnSnS 4 (CZTS) solar cell. Thin film CZTS was deposited by sputter deposition technique using stoichiometry quaternary CZTS target. Formation of molybdenum sulphide (MoS x ) interfacial layer is observed in sputter grown CZTS films after sulphurization. Thickness of MoS x layer is found ~142 nm when CZTS layer (550 nm thick) is sulphurized at 600 °C. Thickness of MoS x layer significantly increased to ~240 nm in case of thicker CZTS layer (650 nm) under similar sulphurization condition. We also observe that high temperature (600 °C) annealing suppress the elemental impurities (Cu, Zn, Sn) at interfacial layer. The amount of out-diffused Mo significantly varies with the change in sulphurization temperature. The out-diffused Mo into CZTS layer and reconstructed interfacial layer remarkably decreases series resistance and increases shunt resistance of the solar cell. The overall efficiency of the solar cell is improved by nearly five times when 600 °C sulphurized CZTS layer is applied in place of 500 °C sulphurized layer. Molybdenum and sulphur diffusion reconstruct the interface layer during heat treatment and play the major role in charge carrier dynamics of a photovoltaic device.

Thin film solar cells grown by organic vapor phase deposition

NASA Astrophysics Data System (ADS)

Yang, Fan

Organic solar cells have the potential to provide low-cost photovoltaic devices as a clean and renewable energy resource. In this thesis, we focus on understanding the energy conversion process in organic solar cells, and improving the power conversion efficiencies via controlled growth of organic nanostructures. First, we explain the unique optical and electrical properties of organic materials used for photovoltaics, and the excitonic energy conversion process in donor-acceptor heterojunction solar cells that place several limiting factors of their power conversion efficiency. Then, strategies for improving exciton diffusion and carrier collection are analyzed using dynamical Monte Carlo models for several nanostructure morphologies. Organic vapor phase deposition is used for controlling materials crystallization and film morphology. We improve the exciton diffusion efficiency while maintaining good carrier conduction in a bulk heterojunction solar cell. Further efficiency improvement is obtained in a novel nanocrystalline network structure with a thick absorbing layer, leading to the demonstration of an organic solar cell with 4.6% efficiency. In addition, solar cells using simultaneously active heterojunctions with broad spectral response are presented. We also analyze the efficiency limits of single and multiple junction organic solar cells, and discuss the challenges facing their practical implementations.

Methodology to estimate variations in solar radiation reaching densely forested slopes in mountainous terrain.

PubMed

Sypka, Przemysław; Starzak, Rafał; Owsiak, Krzysztof

2016-12-01

Solar radiation reaching densely forested slopes is one of the main factors influencing the water balance between the atmosphere, tree stands and the soil. It also has a major impact on site productivity, spatial arrangement of vegetation structure as well as forest succession. This paper presents a methodology to estimate variations in solar radiation reaching tree stands in a small mountain valley. Measurements taken in three inter-forest meadows unambiguously showed the relationship between the amount of solar insolation and the shading effect caused mainly by the contour of surrounding tree stands. Therefore, appropriate knowledge of elevation, aspect and tilt angles of the analysed planes had to be taken into consideration during modelling. At critical times, especially in winter, the diffuse and reflected components of solar radiation only reached some of the sites studied as the beam component of solar radiation was totally blocked by the densely forested mountain slopes in the neighbourhood. The cross-section contours and elevation angles of all obstructions are estimated from a digital surface model including both digital elevation model and the height of tree stands. All the parameters in a simplified, empirical model of the solar insolation reaching a given horizontal surface within the research valley are dependent on the sky view factor (SVF). The presented simplified, empirical model and its parameterisation scheme should be easily adaptable to different complex terrains or mountain valleys characterised by diverse geometry or spatial orientation. The model was developed and validated (R 2  = 0.92 , σ = 0.54) based on measurements taken at research sites located in the Silesian Beskid Mountain Range. A thorough understanding of the factors determining the amount of solar radiation reaching woodlands ought to considerably expand the knowledge of the water exchange balance within forest complexes as well as the estimation of site productivity.

Corrosion resistant solar mirror

DOEpatents

Medwick, Paul A.; Abbott, Edward E.

2016-07-19

A reflective article includes a transparent substrate having a first major surface and a second major surface. A base coat is formed over at least a portion of the second major surface. A primary reflective coating having at least one metallic layer is formed over at least a portion of the base coat. A protective coating is formed over at least a portion of the primary reflective coating. The article further includes a solar cell and an anode, with the solar cell connected to the metallic layer and the anode.

Method for fabricating silicon cells

DOEpatents

Ruby, D.S.; Basore, P.A.; Schubert, W.K.

1998-08-11

A process is described for making high-efficiency solar cells. This is accomplished by forming a diffusion junction and a passivating oxide layer in a single high-temperature process step. The invention includes the class of solar cells made using this process, including high-efficiency solar cells made using Czochralski-grown silicon. 9 figs.

Silicon-fiber blanket solar-cell array concept

NASA Technical Reports Server (NTRS)

Eliason, J. T.

1973-01-01

Proposed economical manufacture of solar-cell arrays involves parallel, planar weaving of filaments made of doped silicon fibers with diffused radial junction. Each filament is a solar cell connected either in series or parallel with others to form a blanket of deposited grids or attached electrode wire mesh screens.

Selective radiative cooling with MgO and/or LiF layers

DOEpatents

Berdahl, P.H.

1984-09-14

A selective radiation cooling material which is absorptive only in the 8 to 13 microns wavelength range is accomplished by placing ceramic magnesium oxide and/or polycrystalline lithium fluoride on an infrared-reflective substrate. The reflecting substrate may be a metallic coating, foil or sheet, such as aluminum, which reflects all atmospheric radiation from 0.3 to 8 microns, the magnesium oxide and lithium fluoride being nonabsorptive at those wavelengths. <10% of submicron voids in the material is permissible in which case the MgO and/or LiF layer is diffusely scattering, but still nonabsorbing, in the wavelength range of 0.3 to 8 microns. At wavelengths from 8 to 13 microns, the magnesium oxide and lithium fluoride radiate power through the ''window'' in the atmosphere, and thus remove heat from the reflecting sheet of material and the attached object to be cooled. At wavelengths longer than 13 microns, the magnesium oxide and lithium fluoride reflects the atmospheric radiation back into the atmosphere. This high reflectance is only obtained if the surface is sufficiently smooth: roughness on a scale of 1 micron is permissible but roughness on a scale of 10 microns is not. An infrared-transmitting cover or shield is mounted in spaced relationship to the material to reduce convective heat transfer. If this is utilized in direct sunlight, the infrared transmitting cover or shield should be opaque in the solar spectrum of 0.3 to 3 microns.

A Babcock-Leighton solar dynamo model with multi-cellular meridional circulation in advection- and diffusion-dominated regimes

NASA Astrophysics Data System (ADS)

Belucz, B.; Dikpati, M.; Forgacs-Dajka, E.

2014-12-01

Babcock-Leighton type solar dynamo models with single cell meridional circulation are successful in reproducing many solarcycle features, and recently such a model was applied for solarcycle 24 amplitude prediction. It seems that cycle 24 amplitudeforecast may not be validated. One of the reasons is the assumption of a single cell meridional circulation. Recent observations andtheoretical models of meridional circulation do not indicate a single-celledflow pattern. So it is nessecary to examine the role of complexmulti-cellular circulation patterns in a Babcock-Leighton solar dynamo model in the advection and diffusion dominated regimes.By simulating a Babcock-Leighton solar dynamo model with multi-cellularflow, we show that the presence of a weak, second, high-latitudereverse cell speeds up the cycle and slighty enhances the poleward branch in the butterfly diagram, whereas the presence of a second cellin depth reverses the tilt of the butterfly wing and leads to ananti-solar type feature. If, instead, the butterfly diagram isconstructed from the middle of the convection zone in that case, a solar-like pattern can be retrieved. All the above cases behavequalitatively similar in advection and diffusion-dominated regimes.However, our dynamo with a meridional circulation containing fourcells in latitude behaves distinctly different in the two regimes, producing a solar-like butterfly diagram with fast cycles indiffusion-dominated regime, and a complex branches in the butterflydiagram in the advection-dominated regime. Another interestingfinding from our studies is that a four-celled flow pattern containing two in radius and two in latitude always producesquadrupolar parity as the relaxed solution.

Hazard calculations of diffuse reflected laser radiation for the SELENE program

NASA Technical Reports Server (NTRS)

Miner, Gilda A.; Babb, Phillip D.

1993-01-01

The hazards from diffuse laser light reflections off water clouds, ice clouds, and fog and from possible specular reflections off ice clouds were assessed with the American National Standards (ANSI Z136.1-1986) for the free-electron-laser parameters under consideration for the Segmented Efficient Laser Emission for Non-Nuclear Electricity (SELENE) Program. Diffuse laser reflection hazards exist for water cloud surfaces less than 722 m in altitude and ice cloud surfaces less than 850 m in altitude. Specular reflections from ice crystals in cirrus clouds are not probable; however, any specular reflection is a hazard to ground observers. The hazard to the laser operators and any ground observers during heavy fog conditions is of such significant magnitude that the laser should not be operated in fog.

Improved algorithm for estimating optical properties of food and biological materials using spatially-resolved diffuse reflectance

USDA-ARS?s Scientific Manuscript database

In this research, the inverse algorithm for estimating optical properties of food and biological materials from spatially-resolved diffuse reflectance was optimized in terms of data smoothing, normalization and spatial region of reflectance profile for curve fitting. Monte Carlo simulation was used ...

Evaluation of Thermal Control Coatings and Polymeric Materials Exposed to Ground Simulated Atomic Oxygen and Vacuum Ultraviolet Radiation

NASA Technical Reports Server (NTRS)

Kamenetzky, R. R.; Vaughn, J. A.; Finckenor, M. M.; Linton, R. C.

1995-01-01

Numerous thermal control and polymeric samples with potential International Space Station applications were evaluated for atomic oxygen and vacuum ultraviolet radiation effects in the Princeton Plasma Physics Laboratory 5 eV Neutral Atomic Oxygen Facility and in the MSFC Atomic Oxygen Drift Tube System. Included in this study were samples of various anodized aluminum samples, ceramic paints, polymeric materials, and beta cloth, a Teflon-impregnated fiberglass cloth. Aluminum anodizations tested were black duranodic, chromic acid anodize, and sulfuric acid anodize. Paint samples consisted of an inorganic glassy black paint and Z-93 white paint made with the original PS7 binder and the new K2130 binder. Polymeric samples evaluated included bulk Halar, bulk PEEK, and silverized FEP Teflon. Aluminized and nonaluminized Chemfab 250 beta cloth were also exposed. Samples were evaluated for changes in mass, thickness, solar absorptance, and infrared emittance. In addition to material effects, an investigation was made comparing diffuse reflectance/solar absorptance measurements made using a Beckman DK2 spectroreflectometer and like measurements made using an AZ Technology-developed laboratory portable spectroreflectometer.

TiO2 nanosheets decorated with B4C nanoparticles as photocatalysts for solar fuel production under visible light irradiation

NASA Astrophysics Data System (ADS)

Zhang, Xiaojie; Yang, Jipeng; Cai, Tiancong; Zuo, Guoqiang; Tang, Changqing

2018-06-01

Boron carbide (B4C) nanoparticles-decorated anatase titanium dioxide (TiO2) nanosheets photocatalysts were synthesized by a hydrothermal method in the presence of hydrofluoric acid and characterized by field emission scanning electron microscope, high-resolution transmission electron microscope, UV-vis diffuse reflectance spectra, photoluminescence spectra, etc. With metallic Pt nanoparticles as a co-catalyst, the as-synthesized B4C/TiO2 composites were evaluated using photocatalytic CO2 or H2O reduction to solar fuels such as methane and hydrogen. Under either simulated sunlight or visible light irradiation, coupling p-type B4C with n-type anatase TiO2 significantly improved the photocatalytic performance. Both photoluminescence and transient photocurrent measurements indicated that the interfacial coupling effect between B4C and anatase TiO2 could significantly promote photo-excited charges separations. On the basis of measurements and literatures, a possible mechanism of excited charges transfer at the B4C-anatase TiO2 heterojunction interface during irradiation was deduced.

Studies on graphene zinc-oxide nanocomposites photoanodes for high-efficient dye-sensitized solar cells

NASA Astrophysics Data System (ADS)

Effendi, N. A. S.; Samsi, N. S.; Zawawi, S. A.; Hassan, O. H.; Zakaria, R.; Yahya, M. Z. A.; Ali, A. M. M.

2017-09-01

A dye-sensitized solar cells (DSSCs) using a nanocomposite (NC) semiconductor film, consisting of graphene layer and ZnO nanosheets (Gr-ZnO) is fabricated by electrodeposition process. The DSSCs based on Gr-ZnO NC were determined via electrochemical impedance spectra (EIS), UV-Visible diffused reflectance spectroscopy (UV-Vis), and photovoltaic performances J-V curves to substantiate the explanations. Impedance spectra shows that a smaller charge transport time constant occurs in DSSCs based on Gr-ZnO NC comparing to ZnO. This improved the electron collecting efficiency significantly, resulting in high open circuit voltage. Moreover, Gr-ZnO NC shows an efficient photoinduced charge separation and transportation can be achieved at the interface thus exhibit excellent potential for photocurrent generation compared with sole ZnO. Gr-ZnO NC obtained a maximum photocurrent response for an open-circuit voltage and a power conversion efficiency of 0.96 V and 7.01% respectively, which is doubled from sole ZnO. The fabricated Gr-ZnO NC cells show better performances compared to conventional ZnO structure reference cell.

Cloud regimes as phase transitions

NASA Astrophysics Data System (ADS)

Stechmann, Samuel; Hottovy, Scott

2017-11-01

Clouds are repeatedly identified as a leading source of uncertainty in future climate predictions. Of particular importance are stratocumulus clouds, which can appear as either (i) closed cells that reflect solar radiation back to space or (ii) open cells that allow solar radiation to reach the Earth's surface. Here we show that these clouds regimes - open versus closed cells - fit the paradigm of a phase transition. In addition, this paradigm characterizes pockets of open cells (POCs) as the interface between the open- and closed-cell regimes, and it identifies shallow cumulus clouds as a regime of higher variability. This behavior can be understood using an idealized model for the dynamics of atmospheric water as a stochastic diffusion process. Similar viewpoints of deep convection and self-organized criticality will also be discussed. With these new conceptual viewpoints, ideas from statistical mechanics could potentially be used for understanding uncertainties related to clouds in the climate system and climate predictions. The research of S.N.S. is partially supported by a Sloan Research Fellowship, ONR Young Investigator Award N00014-12-1-0744, and ONR MURI Grant N00014-12-1-0912.

Non-Metal Doped Titania Photocatalysts for the Degradation of Neonicotinoid Insecticides Under Visible Light Irradiation.

PubMed

Joseph, Amala Infant Joice; Thiripuranthagan, Sivakumar

2018-05-01

Recombination of e-/h+ pair, the major issue of any titania based photocatalytic material, is addressed here by doping non-metals such as C, N, B, F into the lattice of nano TiO2. The as-synthesised catalysts were characterized by using various instrumental techniques such as X-ray diffraction (XRD), UV-Diffuse reflectance spectroscopy (UV-DRS), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Nanosize of titania was confirmed by both XRD and TEM studies. Visible light inactivity of TiO2 is overcome by C, N, B, F doped titania catalysts in the degradation of neonicotinoid type insecticides namely imidacloprid (IMI) and thiamethoxam (TMX). The degradation efficiencies of the catalysts under different irradiations namely UV, visible and solar were compared. Among the catalysts, CNBF/TiO2 degraded IMI completely at 150, 240 and 330 min whereas TMX has been degraded completely at 210, 270 and 420 min under UV, solar and visible irradiations respectively. The recyclability test of CNBF/TiO2 confirmed its stability towards photocatalytic reaction.

Photocatalytic degradation of isoproturon herbicide over TiO2/Al-MCM-41 composite systems using solar light.

PubMed

Phanikrishna Sharma, M V; Durga Kumari, V; Subrahmanyam, M

2008-06-01

The present investigation covers immobilization of TiO2 using a simple solid state dispersion technique over mesoporous Al-MCM-41 support for the treatment of isoproturon herbicide. Catalysts are characterized by XRD, X-ray photo electron spectroscopy (XPS), surface area, UV-Vis diffused reflectance spectra (DRS), SEM and TEM. A detailed photocatalytic degradation study of isoproturon under solar light in aqueous suspensions is reported. The 10 wt% TiO2/Al-MCM-41 composite system found to be optimum with high degradation activity. The reaction follows pseudo-first order kinetics. The parameters like TiO2 loading over Al-MCM-41, amount of catalyst, concentration of substrate, pH effect, durability of the catalyst, activity comparison of TiO2 and Al-MCM-41 supported system are studied. The mineralization of isoproturon is monitored by TOC. Based on the degradation products detected through LC-MS, a plausible degradation mechanism is proposed. The data indicates that TiO2/Al-MCM-41 composite system is an effective photocatalyst for treatment of isoproturon in contaminated water.

The moon as a radiometric reference source for on-orbit sensor stability calibration

USGS Publications Warehouse

Stone, T.C.

2009-01-01

The wealth of data generated by the world's Earth-observing satellites, now spanning decades, allows the construction of long-term climate records. A key consideration for detecting climate trends is precise quantification of temporal changes in sensor calibration on-orbit. For radiometer instruments in the solar reflectance wavelength range (near-UV to shortwave-IR), the Moon can be viewed as a solar diffuser with exceptional stability properties. A model for the lunar spectral irradiance that predicts the geometric variations in the Moon's brightness with ???1% precision has been developed at the U.S. Geological Survey in Flagstaff, AZ. Lunar model results corresponding to a series of Moon observations taken by an instrument can be used to stabilize sensor calibration with sub-percent per year precision, as demonstrated by the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The inherent stability of the Moon and the operational model to utilize the lunar irradiance quantity provide the Moon as a reference source for monitoring radiometric calibration in orbit. This represents an important capability for detecting terrestrial climate change from space-based radiometric measurements.

Solar photocatalytic degradation of isoproturon over TiO2/H-MOR composite systems.

PubMed

Sharma, Mangalampalli V Phanikrishna; Durgakumari, Valluri; Subrahmanyam, Machiraju

2008-12-30

The photocatalytic degradation and mineralization of isoproturon herbicide was investigated in aqueous solution containing TiO2 over H-mordenite (H-MOR) photocatalysts under solar light. The catalysts are characterized by X-ray diffraction (XRD), UV-Vis diffused reflectance spectra (UV-Vis DRS), Fourier transform-infra red spectra (FT-IR) and scanning electron microscopy (SEM) techniques. The effect of TiO2, H-MOR support and different wt% of TiO2 over the support on the photocatalytic degradation and influence of parameters such as TiO2 loading, catalyst amount, pH and initial concentration of isoproturon on degradation are evaluated. 15wt% TiO2/H-MOR composite is found to be optimum. The degradation reaction follows pseudo-first order kinetics and is discussed in terms of Langmuir-Hinshelwood (L-H) kinetic model. The extent of isoproturon mineralization studied with chemical oxygen demand (COD) and total organic carbon (TOC) measurements and approximately 80% mineralization occurred in 5h. A plausible mechanism is proposed based on the intermediates identified by liquid chromatography-mass spectroscopy (LC-MS).