Diamond, aromatic, aliphatic components of interstellar dust grains: Random covalent networks in carbonaceous grains

NASA Astrophysics Data System (ADS)

Duley, W. W.

1995-05-01

A formalism based on the theory of random covalent networks (RCNs) in amorphous solids is developed for carbonaceous dust grains. RCN solutions provide optimized structures and relative compositions for amorphous materials. By inclusion of aliphatic, aromatic, and diamond clusters, solutions specific to interstellar materials can be obtained and compared with infrared spectral data. It is found that distinct RCN solutions corresponding to diffuse cloud and molecular cloud materials are possible. Specific solutions are derived for three representative objects: VI Cyg No. 12, NGC 7538 (IRS 9), and GC IRS 7. While diffuse cloud conditions with a preponderance of sp2 and sp3 bonded aliphatic CH species can be reproduced under a variety of RCN conditions, the presence of an abundant tertiary CH or diamond component is highly constrained. These solutions are related quantitatively to carbon depletions and can be used to provide a quantitative estimate of carbon in these various dust components. Despite the abundance of C6 aromatic rings in many RCN solutions, the infrared absorption due to the aromatic stretch at approximately 3.3 micrometers is weak under all conditions. The RCN formalism is shown to provide a useful method for tracing the evolutionary properties of interstellar carbonaceous grains.

Boundary Conditions for the Paleoenvironment: Chemical and Physical Processes in Dense Interstellar Clouds: Summary of Research

NASA Technical Reports Server (NTRS)

Irvine, William M.

1999-01-01

The basic theme of this program was the study of molecular complexity and evolution for the biogenic elements and compounds in interstellar clouds and in primitive solar system objects. Research included the detection and study of new interstellar and cometary molecules and investigation of reaction pathways for astrochemistry from a comparison of theory and observed molecular abundances. The latter includes studies of cold, dark clouds in which ion-molecule chemistry should predominate, searches for the effects of interchange of material between the gas and solid phases in interstellar clouds, unbiased spectral surveys of particular sources, and systematic investigation of the interlinked chemistry and physics of dense interstellar clouds. In addition, the study of comets has allowed a comparison between the chemistry of such minimally thermally processed objects and that of interstellar clouds, shedding light on the evolution of the biogenic elements during the process of solar system formation. One PhD dissertation on this research was completed by a graduate student at the University of Massachusetts. An additional 4 graduate students at the University of Massachusetts and 5 graduate students from other institutions participated in research supported by this grant, with 6 of these thus far receiving PhD degrees from the University of Massachusetts or their home institutions. Four postdoctoral research associates at the University of Massachusetts also participated in research supported by this grant, receiving valuable training.

Laboratory Investigations into the Spectra and Origin of Propylene Oxide: A Chiral Interstellar Molecule

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hudson, R. L.; Loeffler, M. J.; Yocum, K. M., E-mail: Reggie.Hudson@nasa.gov

Propylene oxide was recently identified in the interstellar medium, but few laboratory results are available for this molecule to guide current and future investigations. To address this situation, here we report infrared spectra, absorption coefficients, and band strengths of solid propylene oxide along with the first measurement of its refractive index and a calculation of its density, all for the amorphous solid form of the compound. We present the first experimental results showing a low-temperature formation pathway for propylene oxide near 10 K in interstellar ice analogs. Connections are drawn between our new results and the interstellar molecules propanal andmore » acetone, and predictions are made about several as yet unobserved vinyl alcohols and methylketene. Comparisons are given to earlier laboratory work and a few applications to interstellar and solar system astrochemistry are described.« less

Laboratory Measurements of Celestial Solids

NASA Technical Reports Server (NTRS)

Sievers, A. J.; Beckwith, S. V. W.

1997-01-01

Our experimental study has focused on laboratory measurements of the low temperature optical properties of a variety of astronomically significant materials in the infrared and mm-wave region of the spectrum. Our far infrared measurements of silicate grains with an open structure have produced a variety of unusual results: (1) the low temperature mass opacity coefficient of small amorphous 2MgO(central dot)SiO2 and MgO(central dot)2SiO2 grains are many times larger than the values previously used for interstellar grain material; (2) all of the amorphous silicate grains studied possess the characteristic temperature dependent signature associated with two level systems in bulk glass; and (3) a smaller but nonzero two level temperature dependence signature is also observed for crystalline particles, its physical origin is unclear. These laboratory measurements yield surprisingly large and variable values for the mm-wave absorption coefficients of small silicate particles similar to interstellar grains, and suggest that the bulk absorptivity of interstellar dust at these long wavelengths will not be well known without such studies. Furthermore, our studies have been useful to better understand the physics of the two level absorption process in amorphous and crystalline grains to gain confidence in the wide applicability of these results.

Search for water and life's building blocks in the universe: A summary

NASA Astrophysics Data System (ADS)

Ehrenfreund, Pascale; Kwok, Sun; Bergin, Edwin

2015-08-01

Water and organic compounds are essential ingredients for life on Earth and possibly elsewhere. In gaseous form water acts as a coolant that allows interstellar gas clouds to collapse to form stars, whereas water ice covers small dust particles that agglomerate to form planetesimals and planets. The variety of organic compounds identified in interstellar and circumstellar regions reflects complex reaction schemes in the gaseous and icy/solid state. Interstellar volatiles and refractory materials were processed and radially mixed within the protostellar disk from which our solar system formed. But the dynamic solar nebula was also a source for new materials and the search for water and life’s building blocks on terrestrial planets, most of the outer-solar-system satellites as well as small solar system bodies reveals exciting new findings. The analysis of small bodies and their fragments, meteorites and interplanetary dust particles, sheds lights onto the extraterrestrial delivery process of prebiotic molecules to young planets and the pathways to life’s origin on Earth and possibly elsewhere. We summarize the results of invited and contributed papers of this Focus Meeting which will allow us to better assess the habitability of objects in our solar system and provide constraints for exoplanets.

Organics and Ices in the Outer Solar System: Connections to the Interstellar Medium

NASA Technical Reports Server (NTRS)

Pendleton, Y. J.; Cruikshank, D. P.

2017-01-01

The solar nebula, that aggregate of gas and dust that formed the birthplace of the Sun, planets and plethora of small bodies comprising the Solar System, originated in a molecular cloud that is thought to have spawned numerous additional stars, some with their own planets and attendant small bodies. The question of the chemical and physical reprocessing of the original interstellar materials in the solar nebula has challenged both theory and observations. The acquisition and analysis of samples of comet and asteroid solids, and a growing suite of in-situ and close-up analyses of relatively unaltered small Solar System bodies now adds critical new dimensions to the study of the origin and evolution of the early solar nebula. Better understanding the original composition of the material from which our solar nebula formed, and the processing that material experienced, will aid in formulations of chemistry that might occur in other solar systems. While we seek to understand the compositional history of planetary bodies in our own Solar System, we will inevitably learn more about the materials that comprise exoplanets and their surrounding systems.

Low-temperature surface formation of NH3 and HNCO: hydrogenation of nitrogen atoms in CO-rich interstellar ice analogues

NASA Astrophysics Data System (ADS)

Fedoseev, G.; Ioppolo, S.; Zhao, D.; Lamberts, T.; Linnartz, H.

2015-01-01

Solid-state astrochemical reaction pathways have the potential to link the formation of small nitrogen-bearing species, like NH3 and HNCO, and prebiotic molecules, specifically amino acids. To date, the chemical origin of such small nitrogen-containing species is still not well understood, despite the fact that ammonia is an abundant constituent of interstellar ices towards young stellar objects and quiescent molecular clouds. This is mainly because of the lack of dedicated laboratory studies. The aim of this work is to experimentally investigate the formation routes of NH3 and HNCO through non-energetic surface reactions in interstellar ice analogues under fully controlled laboratory conditions and at astrochemically relevant temperatures. This study focuses on the formation of NH3 and HNCO in CO-rich (non-polar) interstellar ices that simulate the CO freeze-out stage in dark interstellar cloud regions, well before thermal and energetic processing start to become relevant. We demonstrate and discuss the surface formation of solid HNCO through the interaction of CO molecules with NH radicals - one of the intermediates in the formation of solid NH3 upon sequential hydrogenation of N atoms. The importance of HNCO for astrobiology is discussed.

Astrophysics with Extraterrestrial Materials

NASA Astrophysics Data System (ADS)

Nittler, Larry R.; Ciesla, Fred

2016-09-01

Extraterrestrial materials, including meteorites, interplanetary dust, and spacecraft-returned asteroidal and cometary samples, provide a record of the starting materials and early evolution of the Solar System. We review how laboratory analyses of these materials provide unique information, complementary to astronomical observations, about a wide variety of stellar, interstellar and protoplanetary processes. Presolar stardust grains retain the isotopic compositions of their stellar sources, mainly asymptotic giant branch stars and Type II supernovae. They serve as direct probes of nucleosynthetic and dust formation processes in stars, galactic chemical evolution, and interstellar dust processing. Extinct radioactivities suggest that the Sun's birth environment was decoupled from average galactic nucleosynthesis for some tens to hundreds of Myr but was enriched in short-lived isotopes from massive stellar winds or explosions shortly before or during formation of the Solar System. Radiometric dating of meteorite components tells us about the timing and duration over which solar nebula solids were assembled into the building blocks of the planets. Components of the most primitive meteoritical materials provide further detailed constraints on the formation, processing, and transport of material and associated timescales in the Sun's protoplanetary disk as well as in other forming planetary systems.

Solid State Pathways towards Molecular Complexity in Space

NASA Astrophysics Data System (ADS)

Linnartz, Harold; Bossa, Jean-Baptiste; Bouwman, Jordy; Cuppen, Herma M.; Cuylle, Steven H.; van Dishoeck, Ewine F.; Fayolle, Edith C.; Fedoseev, Gleb; Fuchs, Guido W.; Ioppolo, Sergio; Isokoski, Karoliina; Lamberts, Thanja; Öberg, Karin I.; Romanzin, Claire; Tenenbaum, Emily; Zhen, Junfeng

2011-12-01

It has been a long standing problem in astrochemistry to explain how molecules can form in a highly dilute environment such as the interstellar medium. In the last decennium more and more evidence has been found that the observed mix of small and complex, stable and highly transient species in space is the cumulative result of gas phase and solid state reactions as well as gas-grain interactions. Solid state reactions on icy dust grains are specifically found to play an important role in the formation of the more complex ``organic'' compounds. In order to investigate the underlying physical and chemical processes detailed laboratory based experiments are needed that simulate surface reactions triggered by processes as different as thermal heating, photon (UV) irradiation and particle (atom, cosmic ray, electron) bombardment of interstellar ice analogues. Here, some of the latest research performed in the Sackler Laboratory for Astrophysics in Leiden, the Netherlands is reviewed. The focus is on hydrogenation, i.e., H-atom addition reactions and vacuum ultraviolet irradiation of interstellar ice analogues at astronomically relevant temperatures. It is shown that solid state processes are crucial in the chemical evolution of the interstellar medium, providing pathways towards molecular complexity in space.

Modelling interstellar physics and chemistry: implications for surface and solid-state processes.

PubMed

Williams, David; Viti, Serena

2013-07-13

We discuss several types of regions in the interstellar medium of the Milky Way and other galaxies in which the chemistry appears to be influenced or dominated by surface and solid-state processes occurring on or in interstellar dust grains. For some of these processes, for example, the formation of H₂ molecules, detailed experimental and theoretical approaches have provided excellent fundamental data for incorporation into astrochemical models. In other cases, there is an astrochemical requirement for much more laboratory and computational study, and we highlight these needs in our description. Nevertheless, in spite of the limitations of the data, it is possible to infer from astrochemical modelling that surface and solid-state processes play a crucial role in astronomical chemistry from early epochs of the Universe up to the present day.

From Interstellar Polycyclic Aromatic Hydrocarbons and Ice to the Origin of Life

NASA Technical Reports Server (NTRS)

Allamandola, Louis

2004-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In the dense ISM, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is very well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. The first part of this talk will describe how infrared studies of interstellar space, combined with laboratory simulations, have revealed the composition of interstellar ices (the building blocks of comets) and the high abundance and nature of interstellar PAHs. The laboratory database has now enabled us to gain insight into the identities, abundances, and physical state of many interstellar materials. Within a dense molecular cloud, and especially in the presolar nebula, the materials frozen into the interstellar/precometary ices are photoprocessed by ultraviolet light and produce more complex molecules. The remainder of the presentation will focus on the photochemical evolution of these materials and the possible role of these compounds on the to the carbonaceous components of micrometeorites, they are likely to have been important sources of complex materials on the early Earth and their composition may be related to the origin of life.

Analysis of "Midnight" Tracks in the Stardust Interstellar Dust Collector: Possible Discovery of a Contemporary Interstellar Dust Grain

NASA Technical Reports Server (NTRS)

Westphal, A. J.; Allen, C.; Bajit, S.; Bastien, R.; Bechtel, H.; Bleuet, P.; Borg, J.; Brenker, F.; Bridges, J.; Brownlee, D. E.;

Variations on a theme - the evolution of hydrocarbon solids. I. Compositional and spectral modelling - the eRCN and DG models

NASA Astrophysics Data System (ADS)

Jones, A. P.

2012-04-01

Context. The compositional properties of hydrogenated amorphous carbons are known to evolve in response to the local conditions. Aims: We present a model for low-temperature, amorphous hydrocarbon solids, based on the microphysical properties of random and defected networks of carbon and hydrogen atoms, that can be used to study and predict the evolution of their properties in the interstellar medium. Methods: We adopt an adaptable and prescriptive approach to model these materials, which is based on a random covalent network (RCN) model, extended here to a full compositional derivation (the eRCN model), and a defective graphite (DG) model for the hydrogen poorer materials where the eRCN model is no longer valid. Results: We provide simple expressions that enable the determination of the structural, infrared and spectral properties of amorphous hydrocarbon grains as a function of the hydrogen atomic fraction, XH. Structural annealing, resulting from hydrogen atom loss, results in a transition from H-rich, aliphatic-rich to H-poor, aromatic-rich materials. Conclusions: The model predicts changes in the optical properties of hydrogenated amorphous carbon dust in response to the likely UV photon-driven and/or thermal annealing processes resulting, principally, from the radiation field in the environment. We show how this dust component will evolve, compositionally and structurally in the interstellar medium in response to the local conditions. Appendices A and B are available in electronic form at http://www.aanda.org

Detection of organic matter in interstellar grains.

PubMed

Pendleton, Y J

1997-06-01

Star formation and the subsequent evolution of planetary systems occurs in dense molecular clouds, which are comprised, in part, of interstellar dust grains gathered from the diffuse interstellar medium (DISM). Radio observations of the interstellar medium reveal the presence of organic molecules in the gas phase and infrared observational studies provide details concerning the solid-state features in dust grains. In particular, a series of absorption bands have been observed near 3.4 microns (approximately 2940 cm-1) towards bright infrared objects which are seen through large column densities of interstellar dust. Comparisons of organic residues, produced under a variety of laboratory conditions, to the diffuse interstellar medium observations have shown that aliphatic hydrocarbon grains are responsible for the spectral absorption features observed near 3.4 microns (approximately 2940 cm-1). These hydrocarbons appear to carry the -CH2- and -CH3 functional groups in the abundance ratio CH2/CH3 approximately 2.5, and the amount of carbon tied up in this component is greater than 4% of the cosmic carbon available. On a galactic scale, the strength of the 3.4 microns band does not scale linearly with visual extinction, but instead increases more rapidly for objects near the Galactic Center. A similar trend is noted in the strength of the Si-O absorption band near 9.7 microns. The similar behavior of the C-H and Si-O stretching bands suggests that these two components may be coupled, perhaps in the form of grains with silicate cores and refractory organic mantles. The ubiquity of the hydrocarbon features seen in the near infrared near 3.4 microns throughout out Galaxy and in other galaxies demonstrates the widespread availability of such material for incorporation into the many newly forming planetary systems. The similarity of the 3.4 microns features in any organic material with aliphatic hydrocarbons underscores the need for complete astronomical observational coverage in the 2-30 microns region, of lines of sight which sample dust in both dense and diffuse interstellar clouds, in order to uniquely specify the composition of interstellar organics. This paper reviews the information available from ground-based observations, although currently the Infrared Satellite Observatory is adding to our body of knowledge on this subject by providing more extensive wavelength coverage. The Murchison carbonaceous meteorite has also been used as an analog to the interstellar observations and has revealed a striking similarity between the light hydrocarbons in the meteorite and the ISM; therefore this review includes comparisons with the meteoritic analog as well as with relevant laboratory residues. Fundamental to the evolution of the biogenic molecules, to the process of planetary system formation, and perhaps to the origin of life, is the connection between the organic material found in the interstellar medium and that incorporated in the most primitive solar system bodies.

From Interstellar PAHs and Ices to the Origin of Life

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.; DeVincenzi, Donald L. (Technical Monitor)

2000-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In dense molecular clouds, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is very well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by earlier interstellar chemistry standards, is widespread throughout the Universe. The first part of this lecture will describe how infrared studies of interstellar space, combined with laboratory simulations, have revealed the composition of interstellar ices (the building blocks of comets) and the high abundance and nature of interstellar PAHs. The laboratory database has now enabled us to gain insight into the identities, concentrations, and physical state of many interstellar materials. Within a dense molecular cloud, and especially in the solar nebula during the star and planet formation stage, the materials frozen into interstellar/precometary ices are photoprocessed by ultraviolet light, producing more complex molecules. The remainder of the presentation will focus on the photochemical evolution of these materials and the possible role of these compounds on the early Earth. As these materials are thought to be the building blocks of comets and related to the carbonaceous components of micrometeorites, they are likely to have been important sources of complex organic materials on the early Earth and their composition may be related to the origin of life.

DDT_ldecin_2: Unraveling the enigmatic nature of the turbulent interaction zone between the circumstellar and interstellar medium around the well-known supergiant Beteleuse

NASA Astrophysics Data System (ADS)

Decin, L.

2011-01-01

Evolved stars are the birthplaces of the interstellar gas and solid dust particles. Such stars lose mass through a stellar wind, which is slow and dusty for cool giants and supergiants, or through impressive supernova explo- sions. However, recent observations with the PACS and SPIRE photometers reveal that the encounter between these slow and dusty winds and the interstellar medium is as spectacular as supernova explosions: multiple arcs, bar-like structures and different kind of instabilities (Rayleigh-Taylor and Kelvin-Helmholtz) are detected. The most outstanding example concerns the well-known supergiant Betelgeuse. However, with the current set of Herschel observations, it is impossible to dene the exact physical mechanism causing the observed infrared emission. We propose to obtain PACS [O I] and HIFI [C II] spectroscopic observations at different pointings in the turbulent wind interaction zone around Betelgeuse. The proposed DDT observations would only take 3.1 hr and would give the astronomical community the rst possibility to study spectroscopically the different dynam- ical and chemical processes partaking in the interaction zone between circumstellar and interstellar material. The derived spectroscopic information will be valuable to the whole community in preparation of OT2.

Four Interstellar Dust Candidates from the Stardust Interstellar Dust Collector

NASA Technical Reports Server (NTRS)

Westphal, A. J.; Allen, C.; Bajt, S.; Bechtel, H. A.; Borg, J.; Brenker, F.; Bridges, J.; Brownlee, D. E.; Burchell, M.; Burghammer, M.;

The Formation of Solid Particles from their Gas-Phase Molecular Precursors in Cosmic Environments with NASA Ames' COSmIC Facility

NASA Technical Reports Server (NTRS)

Salama, Farid

2014-01-01

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

Diamonds in dense molecular clouds - A challenge to the standard interstellar medium paradigm

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.; Tielens, A. G. G. M.; Herbst, T. M.

1993-01-01

Observations of a newly discovered infrared C-H stretching band indicate that interstellar diamond-like material appears to be characteristic of dense clouds. In sharp contrast, the spectral signature of dust in the diffuse interstellar medium is dominated by -CH2- and -CH3 groups. This dichotomy in the aliphatic organic component between the dense and diffuse media challenges standard assumptions about the processes occurring in, and interactions between, these two media. The ubiquity of this interstellar diamond-like material rules out models for meteoritic diamond formation in unusual circumstellar environments and implies that the formation of the diamond-like material is associated with common interstellar processes or stellar types.

The efficiency of photodissociation for molecules in interstellar ices

NASA Astrophysics Data System (ADS)

Kalvāns, J.

2018-05-01

Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average, general ratio between photodissociation coefficients for molecules in ice and gas. A 1D astrochemical model was utilized to simulate the chemical composition for a line of sight through a collapsing interstellar cloud core, whose interstellar extinction changes with time. At different extinctions, the calculated column densities of icy carbon oxides and ammonia (relative to water ice) were compared to observations. The latter were taken from literature data of background stars sampling ices in molecular clouds. The best-fit value for the solid/gas photodissociation coefficient ratio was found to be ≈0.3. In other words, gas-phase photodissociation rate coefficients have to be reduced by a factor of 0.3 before applying them to icy species. A crucial part of the model is a proper inclusion of cosmic-ray induced desorption. Observations sampling gas with total extinctions in excess of ≈22 mag were found to be uncorrelated to modelling results, possibly because of grains being covered with non-polar molecules.

Studies of solid carbon dioxide in interstellar ice analogs subject to thermal processing

NASA Astrophysics Data System (ADS)

White, Douglas W.

2010-09-01

Solid CO2 has been detected in many lines of sight in the interstellar medium from infrared observatories. Spectral profiles from space-based observatories have suggested that CO2 on icy grain mantles is mixed with other common molecules such as H2O and CH 3OH in interstellar regions and that thermal annealing has occurred. The vibrational mode at 658 cm-1 (15.2 mum) is suspected to be a powerful diagnostic tool as to the composition of species on icy grain mantles as well as thermal histories. However, previous studies have not systematically investigated ice composition and temperature. Laboratory spectra of interstellar ice analogs have been created in this study order to better understand the physical properties of solid CO2 in these interstellar environments. Existing databases of ice composition studies and effects of ice thermal history were updated in this study to include a more systematic approach. The 658 cm-1 (15.2 mum) bending mode feature of CO2 is examined here and the subsequent astrophysical implications stated. In the first set of experiments, 47 mixtures of H2O,CH3OH, andCO2 were slowly warmed and mid-infrared absorption spectra were recorded at 5K intervals. The second set of experiments involved examining the CO2 bending mode feature of 10 different CO2-containing ice mixtures at different temperatures where ice segregation was suspected. In these experiments, the ice mixtures were slowly heated to the desired temperature for increasing time intervals before cooling down and recording mid-IR absorption spectra. These studies may be used to analyze IR data from space-based observatories such as the Spitzer Space Telescope Infrared Spectrograph as well other future IR observations of the interstellar medium. Finally, mass spectroscopy measurements were taken from temperature programmed desorption (TPD) experiments performed on several binary mixtures of H2O + CO2 and CH 3OH + CO2. Physical properties such as desorption energy of CO2 can be determined from the TPD traces of these experiments. The work provided here addresses the physical properties of solid CO 2 thermally processed in ice mixtures in interstellar environments by laboratory simulations spectroscopically analyzed by mid-infrared absorption profiles and TPD.

On the Surface Formation of NH3 and HNCO in Dark Molecular Clouds - Searching for Wöhler Synthesis in the Interstellar Medium

NASA Astrophysics Data System (ADS)

Fedoseev, Gleb; Lamberts, Thanja; Linnartz, Harold; Ioppolo, Sergio; Zhao, Dongfeng

Despite its potential to reveal the link between the formation of simple species and more complex molecules (e.g., amino acids), the nitrogen chemistry of the interstellar medium (ISM) is still poorly understood. Ammonia (NH _{3}) is one of the few nitrogen-bearing species that have been observed in interstellar ices toward young stellar objects (YSOs) and quiescent molecular clouds. The aim of the present work is to experimentally investigate surface formation routes of NH _{3} and HNCO through non-energetic surface reactions in interstellar ice analogues under fully controlled laboratory conditions and at astrochemically relevant cryogenic temperatures. This study focuses on the formation of NH _{3} and HNCO in CO-rich (non-polar) interstellar ices that simulate the CO freeze-out stage in interstellar dark cloud regions, well before thermal and energetic processing start to become predominant. Our work confirms the surface formation of ammonia through the sequential addition of three hydrogen/deuterium atoms to a single nitrogen atom at low temperature. The H/D fractionation of the formed ammonia is also shown. Furthermore, we show the surface formation of solid HNCO through the interaction of CO molecules with NH radicals - one of the intermediates in the formation of solid NH _{3}. Finally, we discuss the implications of HNCO in astrobiology, as a possible starting point for the formation of more complex prebiotic species.

Invited papers presented to a workshop on thermodynamics and kinetics of dust formation in the space medium. [condensation, nucleation, and interstellar dust

NASA Technical Reports Server (NTRS)

Robertson, P. C.

1978-01-01

Abstracts of 25 papers relating to condensation processes in the early solar system are presented. Special emphasis is given to the transition of an initial vapor phase in the space medium, the characterization of condensation environments, and condensation processes in the space medium. The question of whether some fraction of the solar system solids (particularly exemplified by meteoritic solids) may be interstellar grains that gathered in the region of the proto-sun, rather than being products of local condensation is addressed.

Preliminary Results on the Gravitational Slingshot Effect and the Population of Hyperbolic Meteoroids at Earth

NASA Technical Reports Server (NTRS)

Wiegert, P. A.

2011-01-01

Interstellar meteoroids, solid particles arriving from outside our Solar System, are not easily distinguished from local meteoroids. A velocity above the escape velocity of the Sun is often used as an indicator of a possible interstellar origin. We demonstrate that the gravitational slingshot effect, resulting from the passage of local meteoroid near a planet, can produce hyperbolic meteoroids at the Earth s orbit with excess velocities comparable to those expected of interstellar meteoroids.

Chemical Evolution of Interstellar Dust into Planetary Materials

NASA Technical Reports Server (NTRS)

Fomenkova, M. N.; Chang, S.; DeVincenzi, Donald L. (Technical Monitor)

1995-01-01

Comets are believed to retain some interstellar materials, stored in fairly pristine conditions since-their formation. The composition and properties of cometary dust grains should reflect those of grains in the outer part of the protosolar nebula which, at least in part, were inherited from the presolar molecular cloud. However, infrared emission features in comets differ from their interstellar counterparts. These differences imply processing of interstellar material on its way to incorporation in comets, but C and N appear to be retained. Overall dust evolution from the interstellar medium (ISM) to planetary materials is accompanied by an increase in proportion of complex organics and a decrease in pure carbon phases. The composition of cometary dust grains was measured in situ during fly-by missions to comet Halley in 1986. The mass spectra of about 5000 cometary dust grains with masses of 5 x 10(exp -17) - 5 x 10(exp -12) g provide data about the presence and relative abundances of the major elements H, C, N, O,Na, Mg, Al, Si, S, Cl, K, Ca, Ti, Cr, Fe, Ni. The bulk abundances of major rock-forming elements integrated over all spectra were found to be solar within a factor of 2, while the volatile elements H, C, N, O in dust are depleted in respect to their total cosmic abundances. The abundances of C and N in comet dust are much closer to interstellar than to meteoritic and are higher than those of dust in the diffuse ISM. In dense molecular clouds dust grains are covered by icy mantles, the average composition of which is estimated to be H:C:N:O = 96:14:1:34. Up to 40% of elemental C and O may be sequestered in mantles. If we use this upper limit to add H, C, N and O as icy mantle material to the abundances residing in dust in the diffuse ISM, then the resulting values for H. C, and N match cometary abundances. Thus, ice mantles undergoing chemical evolution on grains in the dense ISM appear to have been transformed into less volatile and more complex organic residues wherein the H, C and N are largely retained and ultimately accreted in cometary dust. The abundance of O is about the same for cometary dust, meteorites and interstellar dust. In all these samples, most of O in a solid phase is bonded to silicates. In dense molecular clouds, the abundance of O in dust+mantles is significantly higher then in cometary dust. This difference may reflect the greater lability of oxygenated species toward astrophysical processing. Laboratory studies show that O-bearing functional groups in organic compounds tend to be relatively easily removed by heating and/or UV and particle irradiation . In Halley's coma, O-containing organic grains, being unstable, were located closest to the nucleus. The decomposition of the organic grain component in the coma provided a significant extended source contribution to O-containing gaseous species such as CO and H2CO.

Swift heavy ion irradiation of interstellar dust analogues. Small carbonaceous species released by cosmic rays

NASA Astrophysics Data System (ADS)

Dartois, E.; Chabot, M.; Pino, T.; Béroff, K.; Godard, M.; Severin, D.; Bender, M.; Trautmann, C.

2017-03-01

Context. Interstellar dust grain particles are immersed in vacuum ultraviolet (VUV) and cosmic ray radiation environments influencing their physicochemical composition. Owing to the energetic ionizing interactions, carbonaceous dust particles release fragments that have direct impact on the gas phase chemistry. Aims: The exposure of carbonaceous dust analogues to cosmic rays is simulated in the laboratory by irradiating films of hydrogenated amorphous carbon interstellar analogues with energetic ions. New species formed and released into the gas phase are explored. Methods: Thin carbonaceous interstellar dust analogues were irradiated with gold (950 MeV), xenon (630 MeV), and carbon (43 MeV) ions at the GSI UNILAC accelerator. The evolution of the dust analogues is monitored in situ as a function of fluence at 40, 100, and 300 K. Effects on the solid phase are studied by means of infrared spectroscopy complemented by simultaneously recording mass spectrometry of species released into the gas phase. Results: Specific species produced and released under the ion beam are analyzed. Cross sections derived from ion-solid interaction processes are implemented in an astrophysical context.

The molecular universe: from astronomy to laboratory astrophysics and back

NASA Astrophysics Data System (ADS)

van Dishoeck, Ewine

2015-08-01

Molecules are found in a wide range of astronomical environments, fromour Solar System to distant starburst galaxies at the highest redshifts. Thanks to the opening up of the infrared and (sub)millimeter wavelength regime, culminating with Herschel and ALMA, more than 180 different species have now been found throughout the various stages of stellar birth and death: diffuse and dense interstellar clouds, protostars and disks, the envelopes of evolved stars and planetary nebulae, and exo-planetary atmospheres. Molecules and solid-state features are now also routinely detected in the interstellar medium of external galaxies, near and far.There are many motivations for studying this molecular universe. From the chemical perspective, interstellar space provides a unique laboratory to study basic molecular processes under very different conditions from those normally found in a laboratory on Earth. For astronomers, molecules are unique probes of the many environments where they are found, providing information on density, temperature, dynamics, ionization fractions and magnetic fields. Molecules also play an important role in the cooling of clouds allowing them to collapse, including the formation of the very first stars and galaxies. Finally, the molecular composition is sensitive to the history of the material, and ultimately provides critical information on our origins.This talk will summarize a number of recent observational highlights and provide examples of cases where the availability of new laboratory data proved crucial in the analysis. This includes basic data such as spectroscopy and collisional rate coefficients, but also an improved understanding of photoprocesses in the gaseous and solid state. Much of the chemistry in star- and planet-forming regions is now thought to be driven by gas-grain chemistry rather than pure gas-phase chemistry, and a few examples of the close link between models and laboratory experiments will be given. In spite of lingering uncertainties, the future of molecular astrophysics is bright and will allow increased understanding of the journey of gas and solids from clouds to comets and planets.

Experimental interstellar organic chemistry: Preliminary findings

NASA Technical Reports Server (NTRS)

Khare, B. N.; Sagan, C.

1971-01-01

In a simulation of interstellar organic chemistry in dense interstellar clouds or on grain surfaces, formaldehyde, water vapor, ammonia and ethane are deposited on a quartz cold finger and ultraviolet-irradiated in high vacuum at 77K. The HCHO photolytic pathway which produces an aldehyde radical and a superthermal hydrogen atom initiates solid phase chain reactions leading to a range of new compounds, including methanol, ethanol, acetaldehyde, acetonitrile, acetone, methyl formate, and possibly formic acid. Higher nitriles are anticipated. Genetic relations among these interstellar organic molecules (e.g., the Cannizzaro and Tischenko reactions) must exist. Some of them, rather than being synthesized from smaller molecules, may be degradation products of larger organic molecules, such as hexamethylene tetramine, which are candidate consitituents of the interstellar grains. The experiments reported here may also be relevant to cometary chemistry.

Photochemistry of polycyclic aromatic hydrocarbons in cosmic water ice. II. Near UV/VIS spectroscopy and ionization rates

NASA Astrophysics Data System (ADS)

Bouwman, J.; Cuppen, H. M.; Steglich, M.; Allamandola, L. J.; Linnartz, H.

2011-05-01

Context. Mid-infrared emission features originating from polycyclic aromatic hydrocarbons (PAHs) are observed towards photon dominated regions in space. Towards dense clouds, however, these emission features are quenched. Observations of dense clouds show that many simple volatile molecules are frozen out on interstellar grains, forming thin layers of ice. Recently, observations have shown that more complex non-volatile species, presumably including PAHs, also freeze out and contribute to the ongoing solid-state chemistry. Aims: The study presented here aims at obtaining reaction rate data that characterize PAH photochemistry upon vacuum ultraviolet (VUV) irradiation in an interstellar H2O ice analogue to explore the potential impact of PAH:H2O ice reactions on overall interstellar ice chemistry. To this end, the experimental results are implemented in a chemical model under simple interstellar cloud conditions. Methods: Time-dependent near-UV/VIS spectroscopy on the VUV photochemistry of anthracene, pyrene, benzo[ghi]perylene and coronene containing interstellar H2O ice analogs is performed at 25 and 125 K, using an optical absorption setup. Results: Near-UV/VIS absorption spectra are presented for these four PAHs and their photoproducts including cationic species trapped in H2O ice. Oscillator strengths of the cation absorption bands are derived relative to the oscillator strength of the neutral parent PAH. The loss of the parent and growth of PAH photoproducts are measured as a function of VUV dose, yielding solid state reaction constants. The rate constants are used in an exploratory astrochemical model, to assess the importance of PAH:H2O ice photoprocessing in UV exposed interstellar environments, compared with the timescales in which PAH molecules are incorporated in interstellar ices. Conclusions: All four PAHs studied here are found to be readily ionized upon VUV photolysis when trapped in H2O ice and exhibit similar rates for ionization at astronomically relevant temperatures. Depending on the relative efficiency of H2O photodesorption and PAH photoionization in H2O ice, the latter may trigger a charge induced aromatic solid state chemistry, in which PAH cations play a central role.

Skating on thin ice: surface chemistry under interstellar conditions

NASA Astrophysics Data System (ADS)

Fraser, H.; van Dishoeck, E.; Tielens, X.

Solid CO2 has been observed towards both active star forming regions and quiescent clouds (Gerakines et. al. (1999)). The high abundance of CO2 in the solid phase, and its low abundance in the gas phase, support the idea that CO2 is almost exclusively formed in the solid state. Several possible formation mechanisms have been postulated (Ruffle &Herbst (2001): Charnley &Kaufman (2000)), and the detection of CO2 towards quiescent sources such as Elias 16 (Whittet et. al. (1998)) clearly suggests that CO2 can be produced in the absence of UV or electron mediated processes. The most likely route is via the surface reactions between O atoms, or OH radicals, and CO. The tools of modern surface- science offer us the potential to determine many of the physical and chemical attributes of icy interstellar grain mantles under highly controlled conditions, that closely mimic interstellar environments. The Leiden Surface Reaction Simulation Device ( urfreside) combines UHV (UltraS High Vacuum) surface science techniques with an atomic beam to study chemical reactions occurring on the SURFACE and in the BULK of interstellar ice grain mimics. By simultaneously combining two or more surface analysis techniques, the chemical kinetics, reaction mechanisms and activation energies can be determined directly. The experiment is aimed at identifying the key barrierless reactions and desorption pathways on and in H2 O and CO ices under interstellar conditions. The results from traditional HV (high vacuum) and UHV studies of the CO + O and CO + OH reactions will be presented in this paper. Charnley, S.B., & Kaufman, M.J., 2000, ApJ, 529, L111 Gerakines, P.A., 1999, ApJ, 522, 357 Ruffle, D.P., & Herbst, E., 2001, MNRAS, 324, 1054 Whittet, D.C.B., et.al., 1998, ApJ, 498, L159

Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots

NASA Astrophysics Data System (ADS)

Jones, A. P.

2016-12-01

The role and importance of nanoparticles for interstellar chemistry and beyond is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), focusing on their active surface chemistry, the effects of nitrogen doping and the natural selection of interesting nanoparticle sub-structures. Nanoparticle-driven chemistry, and in particular the role of intrinsic epoxide-type structures, could provide a viable route to the observed gas phase OH in tenuous interstellar clouds en route to becoming molecular clouds. The aromatic-rich moieties present in asphaltenes probably provide a viable model for the structures present within aromatic-rich interstellar carbonaceous grains. The observed doping of such nanoparticle structures with nitrogen, if also prevalent in interstellar dust, could perhaps have important and observable consequences for surface chemistry and the formation of precursor pre-biotic species.

Analogs of solid nanoparticles as precursors of aromatic hydrocarbons

NASA Astrophysics Data System (ADS)

Gadallah, K. A. K.; Mutschke, H.; Jäger, C.

2013-06-01

Context. Aromatic =CH and C=C vibrational bands have been observed within shocked interstellar regions, indicating the presence of aromatic emission carriers such as PAHs, which may have been created from adjacent molecular cloud material by interaction with a shock front. Aims: We investigate the evolution of the aromatic =CH and C=C vibrational modes at 3.3 and 6.2 μm wavelength in heated HAC materials, PAHs and mixed PAHs and HACs, respectively, aiming at an explanation of the evolution of carbonaceous dust grains in the shocked regions. Methods: Materials used in these analogs (HAC and PAH materials) were prepared by the laser ablation and the laser pyrolysis methods, respectively. The transmission electron microscopy (TEM) in high-resolution mode was used as an analytical technique to characterize the aromatic layers in HACs. Spectroscopic analysis was prformed in the mid-IR range. Results: A remarkable destruction of aliphatic structures in HACs has been observed with the thermal processing, while aromatic structures become dominating by increasing the diameters of the graphene layers. The aromatic bands at 3.3 and 6.2 μm, observed in the laboratory spectra of PAHs and of the combination of the PAHs and HAC materials, are also clearly observed in the spectrum of the heated HACs. These bands agree with those of aromatic bands observed in astronomical observations. Conclusions: Aromatization of HACs could be a pre-stage in the decomposition process of hydrocarbons that form PAH-clusters in such hot interstellar medium.

Exobiology and the origin of life. [organic compounds in planetary atmospheres and interstellar matter

NASA Technical Reports Server (NTRS)

Sagan, C.

1978-01-01

Research supported wholly or in part by NASA is summarized, Topics covered include the molecular analysis of ultraviolet-photoproduced organic solids synthesized under simulated Jovian conditions; the molecular analysis of organic solids produced by electrical discharge in reducing atmospheres; the organic chemistry of interstellar grains; the spectra of possible organic solids present as aerosols in planetary atmospheres; far infrared studies of organic polymers of possible astrophysical interest; organic dust synthesized in reducing environments by ultraviolet radiation or electric discharge; the diffusion of galactic civilizations; eavesdropping on galactic civilizations; Lander imaging as a detector of life on Mars; and continuing puzzles about Mars. Bibliographic data is included for four additional publications not supported by NASA grant, but related to the objectives of the program.

Identification of Crystalline Material in Two Interstellar Dust Candidates from the Stardust Mission

NASA Technical Reports Server (NTRS)

Gainsforth, Zack; Simionovici, Alexandra; Brenker, Frank E.; Schmitz, Sylvia; Burghammer, Manfred; Cloetens, Peter; Lemelle, Laurence; San Tresseras, Juan-Angel; Schoonjans, Tom; Silversmit, Geert;

Investigating nearby exoplanets via interstellar radar

NASA Astrophysics Data System (ADS)

Scheffer, Louis K.

2014-01-01

Interstellar radar is a potential intermediate step between passive observation of exoplanets and interstellar exploratory missions. Compared with passive observation, it has the traditional advantages of radar astronomy. It can measure surface characteristics, determine spin rates and axes, provide extremely accurate ranges, construct maps of planets, distinguish liquid from solid surfaces, find rings and moons, and penetrate clouds. It can do this even for planets close to the parent star. Compared with interstellar travel or probes, it also offers significant advantages. The technology required to build such a radar already exists, radar can return results within a human lifetime, and a single facility can investigate thousands of planetary systems. The cost, although too high for current implementation, is within the reach of Earth's economy.

Vibrational Spectroscopy after OSU - From C2- to Interstellar Polycyclic Aromatic Hydrocarbons

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.

2006-01-01

The composition of interstellar ice and dust provides insight into the chemical history of the interstellar medium and early solar system. It is now possible to probe this unique and unusual chemistry and determine the composition of these microscopic interstellar particles which are hundreds to many thousands of light years away thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of chemical composition, and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with giant, dark molecular clouds -the birthplace of stars and planets- and others in more tenuous, UV radiation rich regions are now available. The fundamentals of IR spectroscopy and what comparisons of astronomical IR spectra with laboratory spectra of materials prepared under realistic simulated interstellar conditions tell us about the components of these materials is the subject of this talk. These observations have shown that mixed molecular ices comprised of H2O, CH3OH, CO, NH3 and H2CO contain most of the molecular material in molecular clouds and that gas phase, ionized polycyclic aromatic hydrocarbons (PAHs) are widespread and surprisingly abundant throughout most of the interstellar medium.

Nucleation and particle coagulation experiments in microgravity

NASA Technical Reports Server (NTRS)

Nuth, J.

1987-01-01

Measurements of the conditions under which carbon, aluminum oxide, and silicon carbide smokes condense and of the morphology and crystal structure of the resulting grains are essential if the nature of the materials ejected into the interstellar medium and the nature of the grains which eventually became part of the proto solar nebular are to be understood. Little information is currently available on the vapor-solid phase transitions of refractory metals and solids. What little experimental data do exist are, however, not in agreement with currently accepted models of the nucleation process for more volatile materials. The major obstacle to performing such experiments in earth-based laboratories is the susceptibility of these systems to convection. Evaporation of refractory materials into a low-pressure environment with a carefully controlled temperature gradient will produce refractory smokes when the critical supersaturation of the system is exceeded. Measurement of the point at which nucleation occurs, via light scattering or extinction, can not only yield nucleation data but also, information on the chemical composition and crystal structure of the condensate. Experimental requirements are presented.

KSC-08pd2418

NASA Image and Video Library

2008-08-05

VANDENBERG AIR FORCE BASE, Calif. – At Vandenberg Air Force Base in California, the Star-27 kick motor and nozzle for NASA's Interstellar Boundary Explorer, or IBEX, spacecraft are “on top” and part of the IBEX flight system, known as the adapter cone, is in the foreground/bottom. The Star-27 motor has a silver tank that contains the solid propellant. The nozzle fits down inside the adapter cone. The IBEX satellite will make the first map of the boundary between the Solar System and interstellar space. IBEX is the first mission designed to detect the edge of the Solar System. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the Solar System and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the Solar System that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. IBEX is targeted for launch from the Pegasus XL rocket on Oct. 5. Photo credit: NASA/R. Bledsoe

Formation and Survival of Amino Acids in Space

NASA Technical Reports Server (NTRS)

Bernstein, M. P.; Sandford, S. A.; Allamandola, L. J.

2003-01-01

The detection of deuterium enrichments in meteoritic hydroxy and amino acids demonstrates that there is a connection between organic material in the interstellar medium and in piimitive meteorites. It has generally been assumed that such molecules formed via reactions of small deuterium enriched insterstellar precursors in liquid water on a large asteroidal or cometary parent body. We have recently show that the W photolysis of interstellar/presolar ices can produce the amino acids alanine, serine, and glycine, as well as hydroxy acids, and glycerol, all of which have been extracted from the Murchison meteorite. Thus, some of the probiologically interesting organic compounds compounds found in meteorites may have formed in presolar ice and have not solely been a product of parent body liquid water chemistry. We will report on our isotopic labeling studies of the mechanism of formation of these inteiesting compounds, and on astrophysically relevant kinetic studies UV photo-decomposition of amino acid precursors in the solid state. This is our first year of exobiology funding on this project.

Formation and Survival of Amino Acids in Space

NASA Technical Reports Server (NTRS)

Bernstein, M. P.; Sandford, S. A.; Allamandola, L. J.

2003-01-01

The detection of deuterium enrichments in meteoritic hydroxy and amino acids demonstrates that there is a connection between organic material in the interstellar medium and in primitive meteorites. It has generally been assumed that such molecules formed via reactions of small deuterium enriched insterstellar precursors in liquid water on a large asteroidal or cometary parent body. We have recently show that the W photolysis of interstellar/presolar ices can produce the amino acids alanine, serine, and glycine, as well as hydroxy acids, and glycerol, all of which have been extracted from the Murchison meteorite. Thus, some of the probiologically interesting organic compounds, compounds found in meteorites may have formed in presolar ice and have not solely been a product of parent body liquid water chemistry. We will report on our isotopic labeling studies of the mechanism of formation of these interesting compounds, and on astrophysically relevant kinetic studies UV photodecomposition of amino acid precursors in the solid state. This is our first year of exobiology funding on this project.

Irradiation of FeS: Implications for the Lifecycle of Sulfur in the Interstellar Medium and Presolar FeS Grains

NASA Technical Reports Server (NTRS)

Keller, Lindsay P.; Loeffler, M. J.; Christoffersen, R.; Dukes, C.; Rahman, Z.; Baragiola, R.

2010-01-01

Fe(Ni) sulfides are ubiquitous in chondritic meteorites and cometary samples where they are the dominant host of sulfur. Despite their abundance in these early solar system materials, their presence in interstellar and circumstellar environments is poorly understood. Fe-sulfides have been reported from astronomical observations of pre- and post-main sequence stars [1, 2] and occur as inclusions in bonafide circumstellar silicate grains [3, 4]. In cold, dense molecular cloud (MC) environments, sulfur is highly depleted from the gas phase [e.g. 5], yet observations of sulfur-bearing molecules in dense cores find a total abundance that is only a small fraction of the sulfur seen in diffuse regions [6], therefore the bulk of the depletion must reside in an abundant unobserved phase. In stark contrast, sulfur is essentially undepleted from the gas phase in the diffuse interstellar medium (ISM) [7-9], indicating that little sulfur is incorporated into solid grains in this environment. This is a rather puzzling observation unless Fe-sulfides are not produced in significant quantities in stellar outflows, or their lifetime in the ISM is very short due to rapid destruction. The main destruction mechanism is sputtering due to supernova shocks in the warm, diffuse ISM [10]. This process involves the reduction of Fe-sulfide with the production of Fe metal as a by-product and returning S to the gas phase. In order to test this hypothesis, we irradiated FeS and analyzed the resulting material using X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM).

Kinetic Monte Carlo simulations of water ice porosity: extrapolations of deposition parameters from the laboratory to interstellar space

NASA Astrophysics Data System (ADS)

Clements, Aspen R.; Berk, Brandon; Cooke, Ilsa R.; Garrod, Robin T.

2018-02-01

Using an off-lattice kinetic Monte Carlo model we reproduce experimental laboratory trends in the density of amorphous solid water (ASW) for varied deposition angle, rate and surface temperature. Extrapolation of the model to conditions appropriate to protoplanetary disks and interstellar dark clouds indicate that these ices may be less porous than laboratory ices.

Shock-wave processing of C60 in hydrogen

NASA Astrophysics Data System (ADS)

Biennier, L.; Jayaram, V.; Suas-David, N.; Georges, R.; Singh, M. Kiran; Arunan, E.; Kassi, S.; Dartois, E.; Reddy, K. P. J.

2017-03-01

Context. Interstellar carbonaceous particles and molecules are subject to intense shocks in astrophysical environments. Shocks induce a rapid raise in temperature and density which strongly affects the chemical and physical properties of both the gas and solid phases of the interstellar matter. Aims: The shock-induced thermal processing of C60 particles in hydrogen has been investigated in the laboratory under controlled conditions up to 3900 K with the help of a material shock-tube. Methods: The solid residues generated by the exposure of a C60/H2 mixture to a millisecond shock wave were collected and analyzed using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman micro-spectroscopy, and infrared micro-spectroscopy. The gaseous products were analyzed by Gas Chromatography and Cavity Ring Down Spectroscopy. Results: Volatile end-products appear above reflected shock gas temperatures of 2540 K and reveal the substantial presence of small molecules with one or two C atoms. These observations confirm the role played by the C2 radical as a major product of C60 fragmentation and less expectedly highlight the existence of a single C atom loss channel. Molecules with more than two carbon atoms are not observed in the post-shock gas. The analysis of the solid component shows that C60 particles are rapidly converted into amorphous carbon with a number of aliphatic bridges. Conclusions: The absence of aromatic CH stretches on the IR spectra indicates that H atoms do not link directly to aromatic cycles. The fast thermal processing of C60 in H2 over the 800-3400 K temperature range leads to amorphous carbon. The analysis hints at a collapse of the cage with the formation of a few aliphatic connections. A low amount of hydrogen is incorporated into the carbon material. This work extends the range of applications of shock tubes to studies of astrophysical interest.

Processing Mechanisms for Interstellar Ices: Connections to the Solar System

NASA Technical Reports Server (NTRS)

Pendleton, Y. J.; Cuzzi, Jeffrey N. (Technical Monitor)

1995-01-01

The organic component of the interstellar medium, which has revealed itself through the ubiquitous 3.4 micrometers hydrocarbon absorption feature, is widespread throughout the disk of our galaxy and has been attributed to dust grains residing in the diffuse interstellar medium. The absorption band positions near 3.4 micrometers are characteristic of C-H stretching vibrations in the -CH3 and -CH2- groups of saturated aliphatic hydrocarbons associated with perturbing chemical groups. The production of complex molecules is thought to occur within dense molecular clouds when ice-mantled grains are processed by various energetic mechanisms. Studies of the processing of interstellar ices and the subsequent production of organic residues have relevance to studies of ices in the solar system, because primitive, icy solar system bodies such as those in the Kuiper belt are likely reservoirs of organic material, either preserved from the interstellar medium or produced in situ. Connections between the interstellar medium and the early solar nebula have long been a source of interest. A comparison of the interstellar organics and the Murchison meteorite illustrates the importance of probing the interstellar connection to the solar system, because although the carbonaceous meteorites are undoubtedly highly processed, they do retain specific interstellar signatures (such as diamonds, SiC grains, graphite and enriched D/H). The organic component, while not proven interstellar, has a remarkable similarity to the interstellar organics observed in over a dozen sightlines through our galaxy. This paper compares spectra from laboratory organics produced through the processing of interstellar ice analog materials with the high resolution infrared observations of the interstellar medium in order to investigate the mechanisms (such as ion bombardment, plasma processing, and UV photolysis) that may be producing the organics in the ISM.

Observations of Nitrogen Fractionation in Prestellar Cores: Nitriles Tracing Interstellar Chemistry

NASA Technical Reports Server (NTRS)

Milam, S. N.; Charnley, S. B.

2012-01-01

Primitive materials provide important clues on the processes that occurred during the formation and early evolution of the Solar System. Space-based and ground-based observations of cometary comae show that comets appear to contain a mixture of the products of both interstellar and nebular chemistries. Significant 15-nitrogen enrichments have been measured in CN and HCN towards a number of comets and may suggest an origin of interstellar chemical fractionation. Additionally, large N-15 enhancements are found in meteorites and has also led to to the view that the N-15 traces material formed in the interstellar medium (ISM), although multiple sources cannot be excluded. Here, we show the results of observations of the nitrogen and carbon fractionation in prestellar cores for various N-bearing species to decipher the origin of primitive material isotopic enrichments.

Status of the Stardust ISPE and the Origin of Four Interstellar Dust Candidates

NASA Technical Reports Server (NTRS)

Westphal, A. J.; Allen, C.; Ansari, A.; Bajt, S.; Bastien, R. S.; Bassim, N.; Bechtel, H. A.; Borg, J.; Brenker, F. E.; Bridges, J.;

Composition, structure and chemistry of interstellar dust

NASA Technical Reports Server (NTRS)

Tielens, Alexander G. G. M.; Allamandola, Louis J.

1986-01-01

The observational constraints on the composition of the interstellar dust are analyzed. The dust in the diffuse interstellar medium consists of a mixture of stardust (amorphous silicates, amorphous carbon, polycyclic aromatic hydrocarbons, and graphite) and interstellar medium dust (organic refractory material). Stardust seems to dominate in the local diffuse interstellar medium. Inside molecular clouds, however, icy grain mantles are also important. The structural differences between crystalline and amorphous materials, which lead to differences in the optical properties, are discussed. The astrophysical consequences are briefly examined. The physical principles of grain surface chemistry are discussed and applied to the formation of molecular hydrogen and icy grain mantles inside dense molecular clouds. Transformation of these icy grain mantles into the organic refractory dust component observed in the diffuse interstellar medium requires ultraviolet sources inside molecular clouds as well as radical diffusion promoted by transient heating of the mantle. The latter process also returns a considerable fraction of the molecules in the grain mantle to the gas phase.

The Copernicus observations - Interstellar or circumstellar material. [UV spectra of early stars

NASA Technical Reports Server (NTRS)

Steigman, G.; Strittmatter, P. A.; Williams, R. E.

1975-01-01

It is suggested that the sharp absorption lines observed in the ultraviolet spectra of early-type stars by the Copernicus satellite may be entirely accounted for by the circumstellar material in the H II regions and associated transition zones around the observed stars. If this interpretation is correct, the Copernicus results yield little information on the state of any interstellar (as opposed to circumstellar) gas and, in particular, shed little light on the degree of element depletion in interstellar space.

Coordinated Microanalyses of Seven Particles of Probable Interstellar Origin from the Stardust Mission

NASA Technical Reports Server (NTRS)

Westphal, Andrew J.; Stroud, Rhonda M.; Bechtel, Hans A.; Brenker, Frank E.; Butterworth, Anna L.; Flynn, George J.; Frank, David R.; Gainsforth, Zack; Hillier, Jon K.; Postberg, Frank;

Website for the Astrochemistry Laboratory, Astrophysics Branch, Space Sciences Division

NASA Technical Reports Server (NTRS)

Sandford, Scott; DeVincenzi, D. (Technical Monitor)

2002-01-01

The Astrochemistry Laboratory in the Astrophysics Branch (SSA) of the Space Sciences Division at NASA's Ames Research Center specializes in the study of extraterrestrial materials and their analogs. The staff has pioneered laboratory studies of space environments including interstellar, cometary, and planetary ices, simulations of the so-called 'Unidentified' Infrared Emission Bands and Diffuse Interstellar Bands using PAHs (Polycyclic Aromatic Hydrocarbons) and PAH-related materials, and has extensive experience with low-temperature spectroscopy and astronomical observation. Important discoveries made by the Astrochemistry Group include: (1) The recognition that polycyclic aromatic hydrocarbons and their ions are common in space; (2) The identification of a major fraction of the known molecular species frozen in interstellar/pre-cometary ices; (3) The recognition that a significant fraction of the carbon in the interstellar medium is carried by both microdiamonds and organic materials; (4) The expansion of the types of molecules expected to be synthesized in interstellar/pre-cometary ices. These could be delivered to the early Earth (or other body) and influence the origin or early evolution of life.

Interstellar matrices: the chemical composition and evolution of interstellar ices as observed by ISO.

PubMed

d'Hendecourt, L; Dartois, E

2001-03-15

Matrix isolation techniques have been developed in the early sixties as a tool for studying the spectroscopic properties of out of equilibrium species (atoms, radicals, ions, reactive molecules), embedded in rare gas inert matrices at low temperatures. Cold interstellar grains surfaces are able to condense out gas phase molecules, routinely observed by radioastronomy. These grain 'mantles' can be considered as 'interstellar matrices'. However, these matrices are not clean and unreactive. They are made principally of dirty ices whose composition must be determined carefully to assess the importance of the solid state chemistry that takes place in the Interstellar Medium. Infrared spectroscopy, both in astronomy and in the laboratory, is the unique tool to determine the chemical composition of these ices. Astronomical spectra can directly be compared with laboratory ones obtained using classical matrix isolation techniques. Furthermore, dedicated experiments may be undertaken to further improve the understanding of the basic physico-chemical processes that take place in cosmic ices.

Measurements of the Activation Energies for Atomic Hydrogen Diffusion on Pure Solid CO

NASA Astrophysics Data System (ADS)

Kimura, Y.; Tsuge, M.; Pirronello, V.; Kouchi, A.; Watanabe, N.

2018-05-01

The diffusion of hydrogen atoms on dust grains is a key process in the formation of interstellar H2 and some hydrogenated molecules such as formaldehyde and methanol. We investigate the adsorption and diffusion of H atoms on pure solid CO as an analog of dust surfaces observed toward some cold interstellar regions. Using a combination of photostimulated desorption and resonance-enhanced multiphoton ionization methods to detect H atoms directly, the relative adsorption probabilities and diffusion coefficients of the H atoms are measured on pure solid CO at 8, 12, and 15 K. There is little difference between the diffusion coefficients of the hydrogen and deuterium atoms, indicating that the diffusion is limited by thermal hopping. The activation energies controlling the H-atom diffusion depend on the surface temperature, and values of 22, 30, and ∼37 meV were obtained for 8, 12, and 15 K, respectively.

Interstellar fossil Mg-26 and its possible relationship to excess meteoritic Mg-26

NASA Technical Reports Server (NTRS)

Clayton, Donald D.

1986-01-01

A plausible scenario is advanced for explainig a linear correlation found in some solar system solids between their Mg-26/Mg-24 isotopic ratios and their Al/Mg elemental abundance ratios. This scenario involves three stages: (1) the mechanical aggregation of an average ensemble of Al-bearing dust particles that is postulated to be modestly enriched in the Al/Mg abundance ratio because the aggregated particles themselves are; (2) the extraction, perhaps but not necessarily by hot distillation, of almost all Mg, leaving an aggregate with a large Al/Mg ratio and a large Mg-26 excess; and (3) the uptake of normal ambient Mg by the resulting hot Al-rich solid as it cools in Mg-rich vapor. A linear correlation in solids between their Mg-26/Mg-24 isotopic ratio and their aluminum enrichment may be a fossil correlation inherited from interstellar dust.

NO ICE HYDROGENATION: A SOLID PATHWAY TO NH{sub 2}OH FORMATION IN SPACE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Congiu, Emanuele; Dulieu, Francois; Chaabouni, Henda

2012-05-01

Icy dust grains in space act as catalytic surfaces onto which complex molecules form. These molecules are synthesized through exothermic reactions from precursor radicals and, mostly, hydrogen atom additions. Among the resulting products are species of biological relevance, such as hydroxylamine-NH{sub 2}OH-a precursor molecule in the formation of amino acids. In this Letter, laboratory experiments are described that demonstrate NH{sub 2}OH formation in interstellar ice analogs for astronomically relevant temperatures via successive hydrogenation reactions of solid nitric oxide (NO). Inclusion of the experimental results in an astrochemical gas-grain model proves the importance of a solid-state NO+H reaction channel as amore » starting point for prebiotic species in dark interstellar clouds and adds a new perspective to the way molecules of biological importance may form in space.« less

The Search for Interstellar Sulfide Grains

NASA Technical Reports Server (NTRS)

Keller, Lindsay P.; Messenger, Scott

2010-01-01

The lifecycle of sulfur in the galaxy is poorly understood. Fe-sulfide grains are abundant in early solar system materials (e.g. meteorites and comets) and S is highly depleted from the gas phase in cold, dense molecular cloud environments. In stark contrast, sulfur is essentially undepleted from the gas phase in the diffuse interstellar medium, indicating that little sulfur is incorporated into solid grains in this environment. It is widely believed that sulfur is not a component of interstellar dust grains. This is a rather puzzling observation unless Fe-sulfides are not produced in significant quantities in stellar outflows, or their lifetime in the ISM is very short due to rapid destruction. Fe sulfide grains are ubiquitous in cometary samples where they are the dominant host of sulfur. The Fe-sulfides (primarily pyrrhotite; Fe(1-x)S) are common, both as discrete 0.5-10 micron-sized grains and as fine (5-10 nm) nanophase inclusions within amorphous silicate grains. Cometary dust particles contain high abundances of well-preserved presolar silicates and organic matter and we have suggested that they should contain presolar sulfides as well. This hypothesis is supported by the observation of abundant Fe-sulfides grains in dust around pre- and post-main sequence stars inferred from astronomical spectra showing a broad 23 micron IR feature due to FeS. Fe-sulfide grains also occur as inclusions in bona fide circumstellar amorphous silicate grains and as inclusions within deuterium-rich organic matter in cometary dust samples. Our irradiation experiments show that FeS is far more resistant to radiation damage than silicates. Consequently, we expect that Fe sulfide stardust should be as abundant as silicate stardust in solar system materials.

Molecular Spectroscopy in Astrophysics: Interstellar PAHs

NASA Technical Reports Server (NTRS)

Salama, Farid; DeVincenzi, Donald L. (Technical Monitor)

2000-01-01

Polycyclic aromatic hydrocarbons (PAHs) are now considered to be an important and ubiquitous component of the organic material in space. PAHs are found in a large variety of extraterrestrial materials such as interplanetary dust particles (IDPs) and meteoritic materials. PAHs are also good candidates to account for the infrared emission bands (UIRs) and the diffuse interstellar optical absorption bands (DIBs) detected in various regions of the interstellar medium. The recent observations made with the Infrared Space Observatory (ISO) have confirmed the ubiquitous nature of the UIR bands and their carriers. PAHs are thought to form through chemical reactions in the outflow from carbon-rich stars in a process similar to soot formation. Once injected in the interstellar medium, PAHs are further processed by the interstellar radiation field, interstellar shocks and energetic particles. A long-term laboratory effort has been undertaken to measure the physical and chemical characteristics of these carbon molecules and their ions under experimental conditions that mimic the interstellar conditions. These measurements require collision-free conditions where the molecules and ions are cold and chemically isolated. The spectroscopy of PAHs under controlled conditions represents an essential diagnostic tool to study the evolution of extraterrestrial PAHs. The laboratory results will be discussed as well as the implications for astronomy and for molecular spectroscopy. A review of the data generated through laboratory simulations of space environments and the role these data have played in our current understanding of the properties of interstellar PAHs will be presented. We will also present the new generation of laboratory experiments that are currently being developed in order to provide a closer simulation of space environments and a better support to space missions.

Laboratory Astrochemistry: Interstellar PAH Analogs

NASA Technical Reports Server (NTRS)

Salama, Farid; DeVincenzi, Donald L. (Technical Monitor)

2000-01-01

Polycyclic aromatic hydrocarbons (PAHs) are now considered to be an important and ubiquitous component of the organic material in space. PAHs are found in a large variety of extraterrestrial materials such as interplanetary dust particles (IDPs) and meteoritic materials. PAHs are also good candidates to account for the infrared emission bands (UIRs) and the diffuse interstellar optical absorption bands (DIBs) detected in various regions of the interstellar medium. The recent observations made with the Infrared Space Observatory (ISO) have confirmed the ubiquitous nature of the UIR bands and their carriers. PAHs are though to form through chemical reactions in the outflow from carbon-rich stars in a process similar to soot formation. Once injected in the interstellar medium, PAHs are further processed by the interstellar radiation field, interstellar shocks and energetic particles. A major, dedicated, laboratory effort has been undertaken over the past years to measure the physical and chemical characteristics of these complex molecules and their ions under experimental conditions that mimic the interstellar conditions. These measurements require collision-free conditions where the molecules and ions are cold and chemically isolated. The spectroscopy of PAHs under controlled conditions represents an essential diagnostic tool to study the evolution of extraterrestrial PAHs. The Astrochemistry Laboratory program will be discussed through its multiple aspects: objectives, approach and techniques adopted, adaptability to the nature of the problem(s), results and implications for astronomy as well as for molecular spectroscopy. A review of the data generated through laboratory simulations of space environments and the role these data have played in our current understanding of the properties of interstellar PAHs will be presented. The discussion will also introduce the newest generation of laboratory experiments that are currently being developed in order to provide a closer simulation of space environments and a better support to space missions.

Laboratory Studies of Interstellar PAH Analogs

NASA Technical Reports Server (NTRS)

Salama, Farid; DeVincenzi, Donald (Technical Monitor)

2000-01-01

Polycyclic aromatic hydrocarbons (PAHs) are now considered to be an important and ubiquitous component of the organic material in space. PAHs are found in a large variety of extraterrestrial materials such as interplanetary dust particles (IDPs) and meteoritic materials. PAHs are also good candidates to account for the infrared emission bands (UIRs) and the diffuse interstellar optical absorption bands (DIBs) detected in various regions of the interstellar medium. The recent observations made with the Infrared Space Observatory (ISO) have confirmed the ubiquitous nature of the UIR bands and their carriers. PAHs are though to form through chemical reactions in the outflow from carbon-rich stars in a process similar to soot formation. Once injected in the interstellar medium, PAHs are further processed by the interstellar radiation field, interstellar shocks and energetic particles. A major, dedicated, laboratory effort has been undertaken over the past years to measure the physical and chemical characteristics of these complex molecules and their ions under experimental conditions that mimic the interstellar conditions. These measurements require collision-free conditions where the molecules and ions are cold and chemically isolated. The spectroscopy of PAHs under controlled conditions represents an essential diagnostic tool to study the evolution of extraterrestrial PAHs. The Astrochemistry Laboratory program will be discussed through its multiple aspects: objectives, approach and techniques adopted, adaptability to the nature of the problem(s), results and implications for astronomy as well as for molecular spectroscopy. A review of the data generated through laboratory simulations of space environments and the role these data have played in our current understanding of the properties of interstellar PAHs will be presented. The discussion will also introduce the newest generation of laboratory experiments that are currently being developed in order to provide a closer simulation of space environments and a better support to space missions.

Effect of Supernovae on the Local Interstellar Material

NASA Astrophysics Data System (ADS)

Frisch, Priscilla; Dwarkadas, Vikram V.

A range of astronomical data indicates that ancient supernovae created the galactic environment of the Sun and sculpted the physical properties of the interstellar medium near the heliosphere. In this paper, we review the characteristics of the local interstellar medium that have been affected by supernovae. The kinematics, magnetic field, elemental abundances, and configuration of the nearest interstellar material support the view that the Sun is at the edge of the Loop I superbubble, which has merged into the low-density Local Bubble. The energy source for the higher temperature X-ray-emitting plasma pervading the Local Bubble is uncertain. Winds from massive stars and nearby supernovae, perhaps from the Sco-Cen association, may have contributed radioisotopes found in the geologic record and galactic cosmic ray population. Nested supernova shells in the Orion and Sco-Cen regions suggest spatially distinct sites of episodic star formation. The heliosphere properties vary with the pressure of the surrounding interstellar cloud. A nearby supernova would modify this pressure equilibrium and thereby severely disrupt the heliosphere as well as the local interstellar medium.

Tholins - Organic chemistry of interstellar grains and gas

NASA Technical Reports Server (NTRS)

Sagan, C.; Khare, B. N.

1979-01-01

The paper discusses tholins, defined as complex organic solids formed by the interaction of energy - for example, UV light or spark discharge - with various mixtures of cosmically abundant gases - CH4, C2H6, NH3, H2O, HCHO, and H2S. It is suggested that tholins occur in the interstellar medium and are responsible for some of the properties of the interstellar grains and gas. Additional occurrences of tholins are considered. Tholins have been produced experimentally; 50 or so pyrolytic fragments of the brown, sometimes sticky substances have been identified by gas chromatography-mass spectrometry, and the incidence of these fragments in tholins produced by different procedures is reported.

Aluminum Foils of the Stardust Interstellar Collector: The Challenge of Recognizing Micrometer-sized Impact Craters made by Interstellar Grains

NASA Technical Reports Server (NTRS)

Kearsley, A. T.; Westphal, A. J.; Burchell, M. J.; Zolensky, Michael E.

2008-01-01

Preliminary Examination (PE) of the Stardust cometary collector revealed material embedded in aerogel and on aluminium (Al) foil. Large numbers of sub-micrometer impact craters gave size, structural and compositional information. With experience of finding and analyzing the picogram to nanogram mass remains of cometary particles, are we now ready for PE of the Interstellar (IS) collector? Possible interstellar particle (ISP) tracks in the aerogel are being identified by the stardust@home team. We are now assessing challenges facing PE of Al foils from the interstellar collector.

Interstellar and Solar Nebula Materials in Cometary Dust

NASA Technical Reports Server (NTRS)

Messenger, Scott; Nakamura-Messenger, Keiko; Keller, Lindsay; Nguyen, Ann; Clemett, Simon

2017-01-01

Laboratory studies of cometary dust collected in the stratosphere and returned from comet 81P/Wild 2 by the Stardust spacecraft have revealed ancient interstellar grains and molecular cloud organic matter that record a range of astrophysical processes and the first steps of planetary formation. Presolar materials are rarer meteorites owing to high temperature processing in the solar nebula and hydrothermal alteration on their asteroidal parent bodies. The greater preservation of presolar materials in comets is attributed to their low accretion temperatures and limited planetary processing. Yet, comets also contain a large complement of high temperature materials from the inner Solar System. Owing to the limited and biased sampling of comets to date, the proportions of interstellar and Solar System materials within them remains highly uncertain. Interstellar materials are identified by coordinated isotopic, mineralogical, and chemical measurements at the scale of individual grains. Chondritic porous interplanetary dust particles (CP IDPs) that likely derive from comets are made up of 0.1 - 10 micron-sized silicates, Fe-Ni-sulfides, oxides, and other phases bound by organic material. As much as 1% of the silicates are interstellar grains that have exotic isotopic compositions imparted by nucleosynthetic processes in their parent stars. Crystalline silicates in CP IDPs dominantly have normal isotopic compositions and probably formed in the Solar System. 81P samples include isotopically normal refractory minerals that resemble Ca-Al rich inclusions and chondrules common in meteorites. The origins of sub-micron amorphous silicates in IDPs are not certain, but at least a few % of them are interstellar grains. The remainder have isotopic compositions consistent with Solar System origins and elemental compositions that are inconsistent with interstellar grain properties, thus favoring formation in the solar nebula [4]. The organic component in comets and primitive meteorites has large enrichments in D/H and N-15/N-14 relative to terrestrial materials. These isotopic signatures are probably due to low temperature chemical processes in cold molecular clouds or the outermost reaches of the protoplanetary disk. The greatest isotopic anomalies are found in sub-micron organic nanoglobules that show chemical signatures of interstellar chemistry. The observation that cometary dust is mostly composed of isotopically normal minerals within isotopically anomalous organic matter is difficult to reconcile with the formation models of each component. The mineral component likely formed in high temperature processes in the inner Solar System, while the organic fraction shows isotopic and chemical signatures of formation near 10 K. Studying more primitive remnants of the Solar System starting materials would help in resolving this paradox. Comets formed across a vast expanse of the outer disk under differing thermal and collisional regimes, and some are likely to be better preserved than others. Finding truly pristine aggregates of presolar materials may require return of a pristine sample of comet nucleus material.

Laboratory simulation of interstellar grain chemistry and the production of complex organic molecules

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.; Valero, G. J.

1990-01-01

During the past 15 years considerable progress in observational techniques has been achieved in the middle infrared (5000 to 500 cm(-1), 2 to 20 microns m), the spectral region most diagnostic of molecular vibrations. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. By comparing these astronomical spectra with the spectra of laboratory ices one can determine the composition and abundance of the icy materials frozen on the cold (10K) dust grains present in the interior of molecular clouds. These grains and their ice mantles may well be the building blocks from which comets are made. As an illustration of the processes which can take place as an ice is irradiated and subsequently warmed, researchers present the infrared spectra of the mixture H2O:CH3OH:CO:NH3:C6H14 (100:50:10:10:10). Apart from the last species, the ratio of these compounds is representative of the simplest ices found in interstellar clouds. The last component was incorporated into this particular experiment as a tracer of the behavior of a non-aromatic hydrocarbon. The change in the composition that results from ultraviolet photolysis of this ice mixture using a UV lamp to simulate the interstellar radiation field is shown. Photolysis produces CO, CO2, CH4, HCO, H2CO, as well as a family of moderately volatile hydrocarbons. Less volatile carbonaceous materials are also produced. The evolution of the infrared spectrum of the ice as the sample is warmed up to room temperature is illustrated. Researchers believe that the changes are similar to those which occur as ice is ejected from a comet and warmed up by solar radiation. The warm-up sequence shows that the nitrile or iso-nitrile bearing compound produced during photolysis evaporates between 200 and 250K, suggesting that it is carried by a small molecular species. These molecules could be similar to the source material in Comet Halley that is ejected in grains into the coma, freed by sublimation, and photolyzed by solar radiation to produce the observed jets.

SWCX Emission from the Helium Focusing Cone - Preliminary Results

NASA Technical Reports Server (NTRS)

Snowden, S. L.; Kuntz, K. D.; Collier, M. R.

2008-01-01

Preliminary results from an XMM-Newton campaign to study solar wind charge exchange (SWCX) emission from the heliospheric focusing cone of interstellar helium are presented. The detections of enhanced O VII and O VIII emission from the cone are at the 2(sigma) and 4(sigma) levels. The solar wind charge exchange (SWCX) emission in the heliosphere not associated with distinct objects (e.g., comets and planets including exospheric material in and near Earth s magnetosheath) is proportional to the flux of the solar wind and the space density of neutral material. The neutral material originates in the interstellar medium (ISM) and passes through the solar system due to the relative motion of the Sun and the ISM. The flow of the neutral material through the solar system is strongly perturbed by the Sun both by gravity and by radiation pressure. Because of the relative radiative scattering cross sections and the effect of solar gravitation the density of interstellar hydrogen near the Sun is reduced while interstellar helium is gravitationally focused. This creates a helium focusing cone downstream of the Sun [e.g., 1, and references therein].

Interstellar and Planetary Analogs in the Laboratory

NASA Technical Reports Server (NTRS)

Salama, Farid

2013-01-01

We present and discuss the unique capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to investigate the interaction of ionizing radiation (UV, charged particles) with molecular species (neutral molecules, radicals and ions) and carbonaceous grains in the Solar System and in the Interstellar Medium (ISM). COSmIC stands for Cosmic Simulation Chamber, a laboratory chamber where interstellar and planetary analogs are generated, processed and analyzed. It is composed of a pulsed discharge nozzle (PDN) expansion that generates a free jet supersonic expansion in a plasma cavity coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a cavity ring down spectroscopy (CRDS) system for photonic detection and a Reflectron time-of-flight mass spectrometer (ReTOF-MS) for mass detection. This setup allows the study of molecules, ions and solids under the low temperature and high vacuum conditions that are required to simulate some interstellar, circumstellar and planetary physical environments providing new fundamental insights on the molecular level into the processes that are critical to the chemistry in the ISM, circumstellar and planet forming regions, and on icy objects in the Solar System. Recent laboratory results that were obtained using COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid particles from their gas-phase molecular precursors in environments as varied as circumstellar outflow and planetary atmospheres.

Stardust@home: A Massively Distributed Public Search for Interstellar Dust in the Stardust Interstellar Dust Collector

NASA Technical Reports Server (NTRS)

Westphal, Andrew J.; Butterworth, Anna L.; Snead, Christopher J.; Craig, Nahide; Anderson, David; Jones, Steven M.; Brownlee, Donald E.; Farnsworth, Richard; Zolensky, Michael E.

2005-01-01

In January 2006, the Stardust mission will return the first samples from a solid solar system body beyond the Moon. Stardust was in the news in January 2004, when it encountered comet Wild2 and captured a sample of cometary dust. But Stardust carries an equally important payload: the first samples of contemporary interstellar dust ever collected. Although it is known that interstellar (IS) dust penetrates into the inner solar system [2, 3], to date not even a single contemporary interstellar dust particle has been captured and analyzed in the laboratory. Stardust uses aerogel collectors to capture dust samples. Identification of interstellar dust impacts in the Stardust Interstellar Dust Collector probably cannot be automated, but will require the expertise of the human eye. However, the labor required for visual scanning of the entire collector would exceed the resources of any reasonably-sized research group. We are developing a project to recruit the public in the search for interstellar dust, based in part on the wildly popular SETI@home project, which has five million subscribers. We call the project Stardust@home. Using sophisticated chemical separation techniques, certain types of refractory ancient IS particles (so-called presolar grains) have been isolated from primitive meteorites (e.g., [4] ). Recently, presolar grains have been identified in Interplanetary Dust Particles[6]. Because these grains are not isolated chemically, but are recognized only by their unusual isotopic compositions, they are probably less biased than presolar grains isolated from meteorites. However, it is entirely possible that the typical interstellar dust particle is isotopically solar in composition. The Stardust collection of interstellar dust will be the first truly unbiased one.

Laboratory Studies on the Formation of Carbon-Bearing Molecules in Extraterrestrial Environments: From the Gas Phase to the Solid State

NASA Technical Reports Server (NTRS)

Jamieson, C. S.; Guo, Y.; Gu, X.; Zhang, F.; Bennett, C. J.; Kaiser, R. I.

2006-01-01

A detailed knowledge of the formation of carbon-bearing molecules in interstellar ices and in the gas phase of the interstellar medium is of paramount interest to understand the astrochemical evolution of extraterrestrial environments (1). This research also holds strong implications to comprehend the chemical processing of Solar System environments such as icy planets and their moons together with the atmospheres of planets and their satellites (2). Since the present composition of each interstellar and Solar System environment reflects the matter from which it was formed and the processes which have changed the chemical nature since the origin (solar wind, planetary magnetospheres, cosmic ray exposure, photolysis, chemical reactions), a detailed investigation of the physicochemical mechanisms altering the pristine environment is of paramount importance to grasp the contemporary composition. Once these underlying processes have been unraveled, we can identify those molecules, which belonged to the nascent setting, distinguish molecular species synthesized in a later stage, and predict the imminent chemical evolution of, for instance, molecular clouds. Laboratory experiments under controlled physicochemical conditions (temperature, pressure, chemical composition, high energy components) present ideal tools for simulating the chemical evolution of interstellar and Solar System environments. Here, laboratory experiments can predict where and how (reaction mechanisms; chemicals necessary) in extraterrestrial environments and in the interstellar medium complex, carbon bearing molecules can be formed on interstellar grains and in the gas phase. This paper overviews the experimental setups utilized in our laboratory to mimic the chemical processing of gas phase and solid state (ices) environments. These are a crossed molecular beams machine (3) and a surface scattering setup (4). We also present typical results of each setup (formation of amino acids, aldehydes, epoxides; synthesis of hydrogen terminated carbon chains as precursors to complex PAHs and to carbonaceous dust grains in general; nitriles as precursor to amino acids).

A possible answer to the mysterious non-detection of hydroxylamine in space: the thermal desorption mechanism

NASA Astrophysics Data System (ADS)

Jonusas, Mindaugas; Krim, Lahouari

2016-06-01

The presence of NH2OH, one of the main precursors in the formation of amino-acids, on dust grain mantles, may be the most obvious elucidation for the creation of large pre-biotic molecules in the interstellar medium. However, while many laboratory experimental studies, to simulate the icy grain chemistry in space, found that NH2OH molecules may be easily formed in solid phase with high abundances and then they should desorb, through a temperature-induced desorption into the gas phase, with the same high abundances; all the spatial observations conclude that NH2OH is not detected in gas phase within any of the explored astronomical sources. Such inconsistencies between laboratory experiment simulations and spatial observations lead our investigations towards this experimental study to see if there is any chemical transformation of NH2OH, occurring in the solid phase before the desorption processes of NH2OH from the mantle of interstellar icy grains. Our experimental results show that the heating of NH2OH-H2O ices lead to a decomposition of NH2OH into HNO, NH3 and O2, even before reaching its desorption temperature. We show through this work that the NH2OH non-detection from previous examined astronomical sources could mainly due to its high reactivity in solid phase on the icy interstellar grains.

Measuring the level of interstellar inheritance in the solar protoplanetary disk

NASA Astrophysics Data System (ADS)

Alexander, Conel M. O'd.; Nittler, Larry R.; Davidson, Jemma; Ciesla, Fred J.

2017-09-01

The timing and extent to which the initial interstellar material was thermally processed provide fundamental constraints for models of the formation and early evolution of the solar protoplanetary disk. We argue that the nonsolar (solar Δ17O ≈ -29‰) and near-terrestrial (Δ17O ≈ 0‰) O-isotopic compositions of the Earth and most extraterrestrial materials (Moon, Mars, asteroids, and comet dust) were established very early by heating of regions of the disk that were modestly enriched (dust/gas ≥ 5-10 times solar) in primordial silicates (Δ17O ≈ -29‰) and water-dominated ice (Δ17O ≈ 24‰) relative to the gas. Such modest enrichments could be achieved by grain growth and settling of dust to the midplane in regions where the levels of turbulence were modest. The episodic heating of the disk associated with FU Orionis outbursts were the likely causes of this early thermal processing of dust. We also estimate that at the time of accretion the CI chondrite and interplanetary dust particle parent bodies were composed of 5-10% of pristine interstellar material. The matrices of all chondrites included roughly similar interstellar fractions. Whether this interstellar material avoided the thermal processing experienced by most dust during FU Orionis outbursts or was accreted by the disk after the outbursts ceased to be important remains to be established.

Experimental and theoretical studies on the gas/solid/gas transformation cycle in extraterrestrial environments

NASA Astrophysics Data System (ADS)

Cottin, Hervé; Gazeau, Marie-Claire; Chaquin, Patrick; Raulin, François; Bénilan, Yves

2001-12-01

The ubiquity of molecular material in the universe, from hydrogen to complex organic matter, is the result of intermixed physicochemical processes that have occurred throughout history. In particular, the gas/solid/gas phase transformation cycle plays a key role in chemical evolution of organic matter from the interstellar medium to planetary systems. This paper focuses on two examples that are representative of the diversity of environments where such transformations occur in the Solar System: (1) the photolytic evolution from gaseous to solid material in methane containing planetary atmospheres and (2) the degradation of high molecular weight compounds into gas phase molecules in comets. We are currently developing two programs which couple experimental and theoretical studies. The aim of this research is to provide data necessary to build models in order to better understand (1) the photochemical evolution of Titan's atmosphere, through a laboratory program to determine quantitative spectroscopic data on long carbon chain molecules (polyynes) obtained in the SCOOP program (French acronym for Spectroscopy of Organic Compounds Oriented for Planetology), and (2) the extended sources in comets, through a laboratory program of quantitative studies of photochemical and thermal degradation processes on relevant polymers (e.g., Polyoxymethylene) by the SEMAPhOrE Cometaire program (French acronym for Experimental Simulation and Modeling Applied to Organic Chemistry in Cometary Environment).

Observations of Isotope Fractionation in Prestellar Cores: Interstellar Origin of Meteoritic Hot Spot?

NASA Technical Reports Server (NTRS)

Milam, S. N.; Charnley, S. B.

2011-01-01

Isotopically fractionated material is found in many solar system objects, including meteorites and comets. It is thought, in some cases, to trace interstellar material that was incorporated into the solar system without undergoing significant processing. Here, we show the results of models and observations of the nitrogen and carbon fractionation in proto-stellar cores.

Isotopic Fractionation in Primitive Material: Quantifying the Contribution of Interstellar Chemistry

NASA Technical Reports Server (NTRS)

Charnley, Steven

2010-01-01

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These models make several predictions that can be tested in the near future by molecular line observations, particularly with ALMA.

Stardust Interstellar Preliminary Examination VII: Synchrotron X-Ray Fluorescence Analysis of Six Stardust Interstellar Candidates Measured with the Advanced Photon Source 2-ID-D Microprobe

NASA Technical Reports Server (NTRS)

Allen, Carlton C.; Anderson, David; Bastien, Ron K.; Brenker, Frank E.; Flynn, George J.; Frank, David; Gainsforth, Zack; Sandford, Scott A.; Simionovici, Alexandre S.; Zolensky, Michael E.

2014-01-01

The NASA Stardust spacecraft exposed an aerogel collector to the interstellar dust passing through the solar system. We performed X-ray fluorescence element mapping and abundance measurements, for elements 19 < or = Z < or = 30, on six "interstellar candidates," potential interstellar impacts identified by Stardust@Home and extracted for analyses in picokeystones. One, I1044,3,33, showed no element hot-spots within the designated search area. However, we identified a nearby surface feature, consistent with the impact of a weak, high-speed particle having an approximately chondritic (CI) element abundance pattern, except for factor-of-ten enrichments in K and Zn and an S depletion. This hot-spot, containing approximately 10 fg of Fe, corresponds to an approximately 350 nm chondritic particle, small enough to be missed by Stardust@Home, indicating that other techniques may be necessary to identify all interstellar candidates. Only one interstellar candidate, I1004,1,2, showed a track. The terminal particle has large enrichments in S, Ti, Cr, Mn, Ni, Cu, and Zn relative to Fe-normalized CI values. It has high Al/Fe, but does not match the Ni/Fe range measured for samples of Al-deck material from the Stardust sample return capsule, which was within the field-of-view of the interstellar collector. A third interstellar candidate, I1075,1,25, showed an Al-rich surface feature that has a composition generally consistent with the Al-deck material, suggesting that it is a secondary particle. The other three interstellar candidates, I1001,1,16, I1001,2,17, and I1044,2,32, showed no impact features or tracks, but allowed assessment of submicron contamination in this aerogel, including Fe hot-spots having CI-like Ni/Fe ratios, complicating the search for CI-like interstellar/interplanetary dust.

Stardust Interstellar Preliminary Examination VII: Synchrotron X-ray fluorescence analysis of six Stardust interstellar candidates measured with the Advanced Photon Source 2-ID-D microprobe

NASA Astrophysics Data System (ADS)

Flynn, George J.; Sutton, Steven R.; Lai, Barry; Wirick, Sue; Allen, Carlton; Anderson, David; Ansari, Asna; Bajt, SašA.; Bastien, Ron K.; Bassim, Nabil; Bechtel, Hans A.; Borg, Janet; Brenker, Frank E.; Bridges, John; Brownlee, Donald E.; Burchell, Mark; Burghammer, Manfred; Butterworth, Anna L.; Changela, Hitesh; Cloetens, Peter; Davis, Andrew M.; Doll, Ryan; Floss, Christine; Frank, David; Gainsforth, Zack; Grün, Eberhard; Heck, Philipp R.; Hillier, Jon K.; Hoppe, Peter; Hudson, Bruce; Huth, Joachim; Hvide, Brit; Kearsley, Anton; King, Ashley J.; Leitner, Jan; Lemelle, Laurence; Leroux, Hugues; Leonard, Ariel; Lettieri, Robert; Marchant, William; Nittler, Larry R.; Ogliore, Ryan; Ong, Wei Ja; Postberg, Frank; Price, Mark C.; Sandford, Scott A.; Tresseras, Juan-Angel Sans; Schmitz, Sylvia; Schoonjans, Tom; Silversmit, Geert; Simionovici, Alexandre; Sol, Vicente A.; Srama, Ralf; Stadermann, Frank J.; Stephan, Thomas; Sterken, Veerle; Stodolna, Julien; Stroud, Rhonda M.; Trieloff, Mario; Tsou, Peter; Tsuchiyama, Akira; Tyliszczak, Tolek; Vekemans, Bart; Vincze, Laszlo; von Korff, Joshua; Westphal, Andrew J.; Wordsworth, Naomi; Zevin, Daniel; Zolensky, Michael E.

2014-09-01

The NASA Stardust spacecraft exposed an aerogel collector to the interstellar dust passing through the solar system. We performed X-ray fluorescence element mapping and abundance measurements, for elements 19 ≤ Z ≤ 30, on six "interstellar candidates," potential interstellar impacts identified by Stardust@Home and extracted for analyses in picokeystones. One, I1044,3,33, showed no element hot-spots within the designated search area. However, we identified a nearby surface feature, consistent with the impact of a weak, high-speed particle having an approximately chondritic (CI) element abundance pattern, except for factor-of-ten enrichments in K and Zn and an S depletion. This hot-spot, containing approximately 10 fg of Fe, corresponds to an approximately 350 nm chondritic particle, small enough to be missed by Stardust@Home, indicating that other techniques may be necessary to identify all interstellar candidates. Only one interstellar candidate, I1004,1,2, showed a track. The terminal particle has large enrichments in S, Ti, Cr, Mn, Ni, Cu, and Zn relative to Fe-normalized CI values. It has high Al/Fe, but does not match the Ni/Fe range measured for samples of Al-deck material from the Stardust sample return capsule, which was within the field-of-view of the interstellar collector. A third interstellar candidate, I1075,1,25, showed an Al-rich surface feature that has a composition generally consistent with the Al-deck material, suggesting that it is a secondary particle. The other three interstellar candidates, I1001,1,16, I1001,2,17, and I1044,2,32, showed no impact features or tracks, but allowed assessment of submicron contamination in this aerogel, including Fe hot-spots having CI-like Ni/Fe ratios, complicating the search for CI-like interstellar/interplanetary dust.

Hydrocarbons in the ISM: Their Evolution and the Grain-to-Molecule Transition

NASA Astrophysics Data System (ADS)

Jones, Anthony P.

The evolution of hydrocarbon grains in the ISM is determined, principally, by the effects of photo-processing (annealing) which lead to a progressive loss of hydrogen from the structure and an associated 'graphitisation' of the material. Eventually this 'graphitisation' results in a low-density, highly aromatic material that can disaggregate into its aromatic-rich molecular components. These changes are followed through the use of an extended random covalent network (RCN) model for the hydrocarbon structure. This type of 'top down' process could be a significant source of the large molecular infrared band carriers in photon dominated regions. On the basis of this simple model there should thus be a relationship between the small grain and large molecule infrared emission bands across, and within, astrophysical boundaries such as photo-dissociation regions. 1. Introduction Carbon is the most abundant dust-forming element in the ISM and a large fraction of this carbon is in the form of grains comprised, principally, of hydrocarbon materials, including those where the hydrogen content is minimal. Interstellar hydrocarbon grains include: graphite, hydrogenated amorphous aliphatic and/or aromatic hydrocarbons (a-C, a-C:H) and (nano)diamond. These hydrocarbon dusts play a pivotal role in determining, amongst other things, the interstellar extinction, the dust thermal emission and the photo-electric heating of the gas in the ISM. 2. Hydrocarbon grains in the ISM Hydrocarbon grains are formed in the circumstellar shells around C-rich evolved stars, in supernova ejecta and also in the ISM itself via accretion and solid-state chemistry. The physical and chemical properties of hydrocarbon grains are indeed complex and vary in response to the ambient conditions (density, temperature, radiation field, ...). For example they can undergo both chemical and physical processing (growth and changes in chemical composition through accretion and reaction, erosion via inertial or chemi-sputtering, photo-darkening or 'graphitisation', photo-disruption in intense radiation fields and fragmentation in interstellar shock waves). Recently, using laboratory simulations of carbon dust analogues, Dartois, Muñoz Caro, Deboffle, et al. (2004,2005) have shown that hydrogen-rich (> 50 atomic % H) hydrocarbon solids can explain the observed interstellar absorption bands at 3.4, 6.85 and 7.25 μm. They also show that the thermal annealing of this material is accompanied by an increase in the aromatic component, i.e., a 'graphitisation'. Such a transformation and evolution of interstellar hydrocarbons was proposed by Duley, Jones & Williams (1989) and Jones, Duley & Wiliams (1990). This photon-driven process, acting on the hydrogen-rich hydrocarbon grains in the ISM that originate predominantly from carbon-rich evolved stars, will lead to a progressive loss of hydrogen and an associated 'graphitisation' and 'openingup' of the structure. The end point of the 'graphitisation' process is then a low-density material that will disaggregate into its constituent aromatic molecular components and the necessarily-associated sp3 and sp2 carbon and hydrogen atom bridging structures, e.g., Duley (2000), Petrie, Stranger & Duley (2003). In this work we follow the 'graphitisation' process using a random covalent network (RCN) approach that extends the work of Jones (1990). To summarise, the RCN model characterises a series of hydrocarbons based upon the sp3/sp2 carbon atom ratio (R) and the atomic fraction of hydrogen (XH) within the material. This model allows an essentially one-parameter determination of the a-C:H structure and a prediction of the major infrared bands. We find that the large hydrocarbon grains, with temperatures in equilibrium with the local radiation field, will be rather hydrogen-rich and that the smaller grains, which undergo stochastic heating to high temperatures, will be converted into hydrogen-poorer and more graphitic materials. The photo-fragmentation of the smaller aromatic grains can be an important source of molecular aromatic species. The infrared spectrum of a given RCN hydrocarbon depends, principally, upon only its hydrogen content XH. The spectra predicted from this RCN model can then be compared with the interstellar absorption and emission bands in the 32 μm range. The compositional changes of a-C:H, and its constituent 'molecular' components, can then be mapped across a given region. 3. Conclusions The physics and chemistry of hydrocarbon grains is complex. Interstellar hydrocarbon grains will be a mixture of many different forms arising from many different sources and modified in many different regions of the ISM. Nevertheless, we can appreciate how this complex material evolves chemically, structurally and physically as a function of the ambient conditions through the use of a rather simple, and extended, RCN model. The transition/evolution of hydrocarbons in the ISM is, generally, from hydrogen-rich a-C:H, in the form of large grains formed around evolved stars, through to smaller, hydrogen-poor, low-density, aromatic a-C:H materials. The subsequent photo-fragmentation of the small aromatic grains could then be the origin of the aromatic emission band carriers within the ISM. We find that the spectral and physical properties of hydrocarbons in the ISM vary in a systematic way across, and also within, astrophysical environments. However, the history of the particles, prior to their incorporation into a given region, could also play a major role in determining their physical properties in that region. Thus, the evolution of hydrocarbon grains in the ISM will be size-, time- and history-dependent. It is therefore necessary that dust models take into account this complexity in predicting the properties of hydrocarbons in the ISM.

Decades-long changes of the interstellar wind through our solar system.

PubMed

Frisch, P C; Bzowski, M; Livadiotis, G; McComas, D J; Moebius, E; Mueller, H-R; Pryor, W R; Schwadron, N A; Sokół, J M; Vallerga, J V; Ajello, J M

2013-09-06

The journey of the Sun through the dynamically active local interstellar medium creates an evolving heliosphere environment. This motion drives a wind of interstellar material through the heliosphere that has been measured with Earth-orbiting and interplanetary spacecraft for 40 years. Recent results obtained by NASA's Interstellar Boundary Explorer mission during 2009-2010 suggest that neutral interstellar atoms flow into the solar system from a different direction than found previously. These prior measurements represent data collected from Ulysses and other spacecraft during 1992-2002 and a variety of older measurements acquired during 1972-1978. Consideration of all data types and their published results and uncertainties, over the three epochs of observations, indicates that the trend for the interstellar flow ecliptic longitude to increase linearly with time is statistically significant.

Interstellar grain chemistry and organic molecules

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.

1990-01-01

The detection of prominant infrared absorption bands at 3250, 2170, 2138, 1670 and 1470 cm(-1) (3.08, 4.61, 4.677, 5.99 and 6.80 micron m) associated with molecular clouds show that mixed molecular (icy) grain mantles are an important component of the interstellar dust in the dense interstellar medium. These ices, which contain many organic molecules, may also be the production site of the more complex organic grain mantles detected in the diffuse interstellar medium. Theoretical calculations employing gas phase as well as grain surface reactions predict that the ices should be dominated only by the simple molecules H2O, H2CO, N2, CO, O2, NH3, CH4, possibly CH3OH, and their deuterated counterparts. However, spectroscopic observations in the 2500 to 1250 cm(-1)(4 to 8 micron m) range show substantial variation from source reactions alone. By comparing these astronomical spectra with the spectra of laboratory-produced analogs of interstellar ices, one can determine the composition and abundance of the materials frozen on the grains in dense clouds. Experiments are described in which the chemical evolution of an interstellar ice analog is determined during irradiation and subsequent warm-up. Particular attention is paid to the types of moderately complex organic materials produced during these experiments which are likely to be present in interstellar grains and cometary ices.

Dust evolution, a global view: II. Top-down branching, nanoparticle fragmentation and the mystery of the diffuse interstellar band carriers

PubMed Central

2016-01-01

The origin of the diffuse interstellar bands (DIBs), one of the longest-standing mysteries of the interstellar medium (ISM), is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS). The likely nature of the DIB carriers and their evolution is here explored within the framework of the structures and sub-structures inherent to doped hydrogenated amorphous carbon grains in the ISM. Based on the natural aromatic-rich moieties (asphaltenes) recovered from coal and oil, the likely structure of their interstellar analogues is investigated within the context of the diffuse band problem. It is here proposed that the top-down evolution of interstellar carbonaceous grains, and, in particular, a-C(:H) nanoparticles, is at the heart of the formation and evolution of the DIB carriers and their associations with small molecules and radicals, such as C2, C3, CH and CN. It is most probable that the DIBs are carried by dehydrogenated, ionized, hetero-cyclic, olefinic and aromatic-rich moieties that form an integral part of the contiguous structure of hetero-atom-doped hydrogenated amorphous carbon nanoparticles and their daughter fragmentation products. Within this framework, it is proposed that polyene structures in all their variants could be viable DIB carrier candidates. PMID:28083089

Dust evolution, a global view: II. Top-down branching, nanoparticle fragmentation and the mystery of the diffuse interstellar band carriers

NASA Astrophysics Data System (ADS)

Jones, A. P.

2016-12-01

The origin of the diffuse interstellar bands (DIBs), one of the longest-standing mysteries of the interstellar medium (ISM), is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS). The likely nature of the DIB carriers and their evolution is here explored within the framework of the structures and sub-structures inherent to doped hydrogenated amorphous carbon grains in the ISM. Based on the natural aromatic-rich moieties (asphaltenes) recovered from coal and oil, the likely structure of their interstellar analogues is investigated within the context of the diffuse band problem. It is here proposed that the top-down evolution of interstellar carbonaceous grains, and, in particular, a-C(:H) nanoparticles, is at the heart of the formation and evolution of the DIB carriers and their associations with small molecules and radicals, such as C2, C3, CH and CN. It is most probable that the DIBs are carried by dehydrogenated, ionized, hetero-cyclic, olefinic and aromatic-rich moieties that form an integral part of the contiguous structure of hetero-atom-doped hydrogenated amorphous carbon nanoparticles and their daughter fragmentation products. Within this framework, it is proposed that polyene structures in all their variants could be viable DIB carrier candidates.

Dust evolution, a global view: III. Core/mantle grains, organic nano-globules, comets and surface chemistry

NASA Astrophysics Data System (ADS)

Jones, A. P.

2016-12-01

Within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), this work explores the surface processes and chemistry relating to core/mantle interstellar and cometary grain structures and their influence on the nature of these fascinating particles. It appears that a realistic consideration of the nature and chemical reactivity of interstellar grain surfaces could self-consistently and within a coherent framework explain: the anomalous oxygen depletion, the nature of the CO dark gas, the formation of `polar ice' mantles, the red wing on the 3 μm water ice band, the basis for the O-rich chemistry observed in hot cores, the origin of organic nano-globules and the 3.2 μm `carbonyl' absorption band observed in comet reflectance spectra. It is proposed that the reaction of gas phase species with carbonaceous a-C(:H) grain surfaces in the interstellar medium, in particular the incorporation of atomic oxygen into grain surfaces in epoxide functional groups, is the key to explaining these observations. Thus, the chemistry of cosmic dust is much more intimately related with that of the interstellar gas than has previously been considered. The current models for interstellar gas and dust chemistry will therefore most likely need to be fundamentally modified to include these new grain surface processes.

Microanalysis of Hypervelocity Impact Residues of Possible Interstellar Origin

NASA Technical Reports Server (NTRS)

Stroud, Rhonda M.; Achilles, Cheri; Allen, Carlton; Anasari, Asna; Bajt, Sasa; Bassim, Nabil; Bastien, Ron S.; Bechtel, H. A.; Borg, Janet; Brenker, Frank E.;

Organic Chemistry in Space

NASA Technical Reports Server (NTRS)

Charnley, Steven

2009-01-01

Astronomical observations, theoretical modeling, laboratory simulation and analysis of extraterrestrial material have enhanced our knowledge of the inventory of organic matter in the interstellar medium (ISM) and on small bodies such as comets and asteroids (Ehrenfreund & Charnley 2000). Comets, asteroids and their fragments, meteorites and interplanetary dust particles (IDPs), contributed significant amounts of extraterrestrial organic matter to the young Earth. This material degraded and reacted in a terrestrial prebiotic chemistry to form organic structures that may have served as building blocks for life on the early Earth. In this talk I will summarize our current understanding of the organic composition and chemistry of interstellar clouds. Molecules of astrobiological relevance include the building blocks of our genetic material: nucleic acids, composed of subunits such as N-heterocycles (purines and pyrimidines), sugars and amino acids. Signatures indicative of inheritance of pristine and modified interstellar material in comets and meteorites will also be discussed.

Formation of Nitrogen and Hydrogen-bearing Molecules in Solid Ammonia and Implications for Solar System and Interstellar Ices

NASA Astrophysics Data System (ADS)

Zheng, Weijun; Jewitt, David; Osamura, Yoshihiro; Kaiser, Ralf I.

2008-02-01

We irradiated solid ammonia (NH3) in the temperature range of 10-60 K with high-energy electrons to simulate the processing of ammonia-bearing ices in the interstellar medium and in the solar system. By monitoring the newly formed molecules online and in situ, the synthesis of hydrazine (N2H4), diazene (N2H2 isomers), hydrogen azide (HN3), the amino radical (NH2), molecular hydrogen (H2), and molecular nitrogen (N2) has been confirmed. Our results show that the production rates of hydrazine, diazene, hydrogen azide, molecular hydrogen, and molecular nitrogen are higher in amorphous ammonia than those in crystalline ammonia; this behavior is similar to the production of molecular hydrogen, molecular oxygen, and hydrogen peroxide found in electron-irradiated water ices. However, the formation of hydrazine in crystalline ammonia does not show any temperature dependence. Our experimental results give hints to the origin of molecular nitrogen in the Saturnian system and possibly in the atmospheres of proto-Earth and Titan; our research may also guide the search of hitherto unobserved nitrogen-bearing molecules in the interstellar medium and in our solar system.

Accurate oscillator strengths for ultraviolet lines of Ar I - Implications for interstellar material

NASA Technical Reports Server (NTRS)

Federman, S. R.; Beideck, D. J.; Schectman, R. M.; York, D. G.

1992-01-01

Analysis of absorption from interstellar Ar I in lightly reddened lines of sight provides information on the warm and hot components of the interstellar medium near the sun. The details of the analysis are limited by the quality of the atomic data. Accurate oscillator strengths for the Ar I lines at 1048 and 1067 A and the astrophysical implications are presented. From lifetimes measured with beam-foil spectroscopy, an f-value for 1048 A of 0.257 +/- 0.013 is obtained. Through the use of a semiempirical formalism for treating singlet-triplet mixing, an oscillator strength of 0.064 +/- 0.003 is derived for 1067 A. Because of the accuracy of the results, the conclusions of York and colleagues from spectra taken with the Copernicus satellite are strengthened. In particular, for interstellar gas in the solar neighborhood, argon has a solar abundance, and the warm, neutral material is not pervasive.

High-Resolution and Analytical TEM Investigation of Space Radiation Processing Effects in Primitive Solar System Materials and Airless Planetary Surface Environments

NASA Technical Reports Server (NTRS)

Christoffersen, R.; Rahman, Z.; Keller, L. P.; Dukes, C.; Baragiola, R.

2012-01-01

Energetic ions present in the diverse plasma conditions in space play a significant role in the formation and modification of solid phases found in environments ranging from the interstellar medium (ISM) to the surfaces of airless bodies such as asteroids and the Moon. These effects are often referred to as space radiation processing, a term that encompasses changes induced in natural space-exposed materials that may be only structural, such as in radiation-induced amorphization, or may involve ion-induced nanoscale to microscale chemical changes, as occurs in preferential sputtering and ion-beam mixing. Ion sputtering in general may also be responsible for partial or complete erosion of space exposed materials, in some instances possibly bringing about the complete destruction of free-floating solid grains in the ISM or in circumstellar nebular dust clouds. We report here on two examples of the application of high-resolution and analytical transmission electron microscopy (TEM) to problems in space radiation processing. The first problem concerns the role of space radiation processing in controlling the overall fate of Fe sulfides as hosts for sulfur in the ISM. The second problem concerns the known, but as yet poorly quantified, role of space radiation processing in lunar space weathering.

THE COMPOSITION OF INTERSTELLAR GRAINS TOWARD ζ OPHIUCHI: CONSTRAINING THE ELEMENTAL BUDGET NEAR THE DIFFUSE-DENSE CLOUD TRANSITION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poteet, Charles A.; Whittet, Douglas C. B.; Draine, Bruce T., E-mail: charles.poteet@gmail.com

2015-03-10

We investigate the composition of interstellar grains along the line of sight toward ζ Ophiuchi, a well-studied environment near the diffuse-dense cloud transition. A spectral decomposition analysis of the solid-state absorbers is performed using archival spectroscopic observations from the Spitzer Space Telescope and Infrared Space Observatory. We find strong evidence for the presence of sub-micron-sized amorphous silicate grains, principally comprised of olivine-like composition, with no convincing evidence of H{sub 2}O ice mantles. However, tentative evidence for thick H{sub 2}O ice mantles on large (a ≈ 2.8 μm) grains is presented. Solid-state abundances of elemental Mg, Si, Fe, and O aremore » inferred from our analysis and compared to standard reference abundances. We find that nearly all of the Mg and Si atoms along the line of sight reside in amorphous silicate grains, while a substantial fraction of the elemental Fe resides in compounds other than silicates. Moreover, we find that the total abundance of elemental O is largely inconsistent with the adopted reference abundances, indicating that as much as ∼156 ppm of interstellar O is missing along the line of sight. After taking into account additional limits on the abundance of elemental O in other O-bearing solids, we conclude that any missing reservoir of elemental O must reside on large grains that are nearly opaque to infrared radiation.« less

Dust That's Worth Keeping

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hazi, A

2006-01-25

Images taken of interstellar space often display a colorful canvas of portions of the electromagnetic spectrum. Dispersed throughout the images are interstellar clouds of dust and gas--remnants ejected from stars and supernovae over billions and billions of years. For more than 40 years, astronomers have observed that interstellar dust exhibits a consistent effect at a spectral wavelength of 2,175 angstroms, the equivalent of 5.7 electronvolts in energy on the electromagnetic spectrum. At this wavelength, light from stars is absorbed by dust in the interstellar medium, blocking the stars light from reaching Earth. The 2,175-angstrom feature, which looks like a bumpmore » on spectra, is the strongest ultraviolet-visible light spectral signature of interstellar dust and is visible along nearly every observational line of sight. Scientists have sought to solve the mystery of what causes the 2,175-angstrom feature by reproducing the effect in the laboratory. They speculated a number of possibilities, including fullerenes (buckyballs), nanodiamonds, and even interstellar organisms. However, none of these materials fits the data for the unique spectral feature. Limitations in the energy and spatial resolution achievable with electron microscopes and ion microprobes--the two main instruments used to study samples of dust--have also prevented scientists from finding the answer. A collaborative effort led by Livermore physicist John Bradley and funded by the National Aeronautics and Space Administration (NASA) has used a new-generation transmission electron microscope (TEM) and nanoscale ion microprobe to unlock the mystery. The Livermore group includes physicists Zu Rong Dai, Ian Hutcheon, Peter Weber, and Sasa Bajt and postdoctoral researchers Hope Ishii, Giles Graham, and Julie Smith. They collaborated with the University of California at Davis (UCD), Lawrence Berkeley National Laboratory, Washington University's Laboratory for Space Sciences in St. Louis, and NASA's Ames Research Center for their discovery. The team analyzed micrometer-size interplanetary dust particles (IDPs), each about one-tenth the diameter of a human hair. Within the particles, they found carriers of the 2,175-angstrom feature: organic carbon mixed with amorphous silicates (glass with embedded metals and sulfides, GEMS), two of the most common materials in interstellar space. Ishii says, ''Organic carbon and amorphous silicates are abundant in interstellar dust clouds, and abundant carriers are needed to account for the frequent astronomical observation of the 2,175-angstrom feature. It makes sense that this ubiquitous feature would come from common materials in interstellar space''. The group's results increase scientific understanding of the starting materials for the formation of the Sun, solar system, and life on Earth.« less

Dust That's Worth Keeping

NASA Technical Reports Server (NTRS)

Hazi, A.

2006-01-01

Images taken of interstellar space often display a colorful canvas of portions of the electromagnetic spectrum. Dispersed throughout the images are interstellar clouds of dust and gas--remnants ejected from stars and supernovae over billions and billions of years. For more than 40 years, astronomers have observed that interstellar dust exhibits a consistent effect at a spectral wavelength of 2,175 angstroms, the equivalent of 5.7 electronvolts in energy on the electromagnetic spectrum. At this wavelength, light from stars is absorbed by dust in the interstellar medium, blocking the stars light from reaching Earth. The 2,175-angstrom feature, which looks like a bump on spectra, is the strongest ultraviolet-visible light spectral signature of interstellar dust and is visible along nearly every observational line of sight. Scientists have sought to solve the mystery of what causes the 2,175-angstrom feature by reproducing the effect in the laboratory. They speculated a number of possibilities, including fullerenes (buckyballs), nanodiamonds, and even interstellar organisms. However, none of these materials fits the data for the unique spectral feature. Limitations in the energy and spatial resolution achievable with electron microscopes and ion microprobes--the two main instruments used to study samples of dust--have also prevented scientists from finding the answer. A collaborative effort led by Livermore physicist John Bradley and funded by the National Aeronautics and Space Administration (NASA) has used a new-generation transmission electron microscope (TEM) and nanoscale ion microprobe to unlock the mystery. The Livermore group includes physicists Zu Rong Dai, Ian Hutcheon, Peter Weber, and Sasa Bajt and postdoctoral researchers Hope Ishii, Giles Graham, and Julie Smith. They collaborated with the University of California at Davis (UCD), Lawrence Berkeley National Laboratory, Washington University's Laboratory for Space Sciences in St. Louis, and NASA's Ames Research Center for their discovery. The team analyzed micrometer-size interplanetary dust particles (IDPs), each about one-tenth the diameter of a human hair. Within the particles, they found carriers of the 2,175-angstrom feature: organic carbon mixed with amorphous silicates (glass with embedded metals and sulfides, GEMS), two of the most common materials in interstellar space. Ishii says, 'Organic carbon and amorphous silicates are abundant in interstellar dust clouds, and abundant carriers are needed to account for the frequent astronomical observation of the 2,175-angstrom feature. It makes sense that this ubiquitous feature would come from common materials in interstellar space'. The group's results increase scientific understanding of the starting materials for the formation of the Sun, solar system, and life on Earth.

Formation and Destruction Processes of Interstellar Dust: From Organic Molecules to carbonaceous Grains

NASA Technical Reports Server (NTRS)

Salama, F.; Biennier, L.

2004-01-01

The study of the formation and destruction processes of cosmic dust is essential to understand and to quantify the budget of extraterrestrial organic molecules. interstellar dust presents a continuous size distribution from large molecules, radicals and ions to nanometer-sized particles to micron-sized grains. The lower end of the dust size distribution is thought to be responsible for the ubiquitous spectral features that are seen in emission in the IR (UIBs) and in absorption in the visible (DIBs). The higher end of the dust-size distribution is thought to be responsible for the continuum emission plateau that is seen in the IR and for the strong absorption seen in the interstellar UV extinction curve. All these spectral signatures are characteristic of cosmic organic materials that are ubiquitous and present in various forms from gas-phase molecules to solid-state grains. Although dust with all its components plays an important role in the evolution of interstellar chemistry and in the formation of organic molecules, little is known on the formation and destruction processes of dust. Recent space observations in the UV (HST) and in the IR (ISO) help place size constraints on the molecular component of carbonaceous IS dust and indicate that small (ie., subnanometer) PAHs cannot contribute significantly to the IS features in the UV and in the IR. Studies of large molecular and nano-sized IS dust analogs formed from PAH precursors have been performed in our laboratory under conditions that simulate diffuse ISM environments (the particles are cold -100 K vibrational energy, isolated in the gas phase and exposed to a high-energy discharge environment in a cold plasma). The species (molecules, molecular fragments, ions, nanoparticles, etc) formed in the pulsed discharge nozzle (PDN) plasma source are detected with a high-sensitivity cavity ring-down spectrometer (CRDS). We will present new experimental results that indicate that nanoparticles are generated in the plasma. From these unique measurements, we derive information on the nature, the size and the structure of interstellar dust particles, the growth and the destruction processes of IS dust and the resulting budget of extraterrestrial organic molecules.

Speckles in interstellar radio-wave scattering

NASA Technical Reports Server (NTRS)

Desai, K. M.; Gwinn, C. R.; Reynolds, J.; King, E. A.; Jauncey, D.; Nicholson, G.; Flanagan, C.; Preston, R. A.; Jones, D. L.

1991-01-01

Observations of speckles in the scattering disk of the Vela pulsar are presented and speckle techniques for studying and circumventing scattering of radio waves by the turbulent interstellar plasma are discussed. The speckle pattern contains, in a hologrammatic fashion, complete information on the structure of the radio source as well as the distribution of the scattering material. Speckle observations of interstellar scattering of radio waves are difficult because of their characteristically short timescales and narrow bandwidths. Here, first observations are presented, taken at 13 cm wavelength with elements of the SHEVE VLBI network, of speckles in interstellar scattering.

Ultraviolet spectra of quenched carbonaceous composite derivatives: Comparison to the '217 nanometer' interstellar absorption feature

NASA Technical Reports Server (NTRS)

Sakata, Akira; Wada, Setsuko; Tokunaga, Alan T.; Narisawa, Takatoshi; Nakagawa, Hidehiro; Ono, Hiroshi

1994-01-01

QCCs (quenched carbonaceous composite) are amorphus carbonaceous material formed from a hydrocarbon plasma. We present the UV-visible spectra of 'filmy QCC; (obtained outside of the beam ejected from the hydrocarbon plasma) and 'dark QCC' (obtained very near to the beam) for comparison to the stellar extinction curve. When filmy QCC is heated to 500-700 C (thermally altered), the wavelength of the absorption maximum increases form 204 nm to 220-222 nm. The dark QCC has an absorption maximum at 217-222 nm. In addition, the thermally altered filmy QCC has a slope change at about 500 nm which resmbles that in the interstellar extinction curve. The resemblance of the extinction curve of the QCCs to that of the interstellar medium suggests that QCC derivatives may be representative of the type of interstellar material that produces the 217 nm interstellar medium feature. The peak extinction of the dark QCC is higher than the average interstellar extinction curve while that of the thermally altered filmy QCC is lower, so that a mixture of dark and thermally altered filmy QCC can match the peak extinction observed in the interstellar medium. It is shown from electron micrographs that most of the thermally altered flimy QCC is in the form of small grainy structure less than 4 nm in diameter. This shows that the structure unit causing the 217-222 nm feature in QCC is very small.

Isotope Fractionation in the Interstellar Medium

NASA Technical Reports Server (NTRS)

Charnley, Steven

2011-01-01

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These models make several predictions that can be tested in the near future by molecular line observations, particularly with ALMA.

Synchrotron FTIR Examination of Interplanetary Dust Particles: An Effort to Determine the Compounds and Minerals in Interstellar and Circumstellar Dust

NASA Technical Reports Server (NTRS)

Flynn, G. J.; Keller, L. P.

2002-01-01

Some interplanetary dust particles (IDPs), collected by NASA from the Earth's stratosphere, are the most primitive extraterrestrial material available for laboratory analysis. Many exhibit isotopic anomalies in H, N, and O, suggesting they contain preserved interstellar matter. We report the preliminary results of a comparison of the infrared absorption spectra of subunits of the IDPs with astronomical spectra of interstellar grains.

Pre-Biological Evolution of Organic Matter in the Universe

NASA Astrophysics Data System (ADS)

Wiebe, D. Z.

2017-05-01

Discovery of interstellar molecules has become one of the most prominent findings of 20th century. Initially (since late 1930-ies) only simple two-atom compounds have been known. However, the rapid development of radioastronomy during post-war years has allowed expanding this list significantly. Now, the number of known interstellar and circumstellar molecules approaches two hundred (not counting isomers and isotopologues). Among them we see both simple and quite complex molecules. The largest molecules with solid identification consist of 12 atoms (CH3OC2H5, C3H7CN). Nearly all molecules with more than five atoms represent are organic. More than once even discovery of the simplest amino acid (glycine) in the interstellar medium had been reported. While later all these reports has been refuted, there is no doubt that this is a purely technical problem, and there are no fundamental obstacles on a pathway to interstellar synthesis of simplest amino acids. Definitely, even more complex organic structures are present in the interstellar medium, like fullerenes and some kind of aromatic particles. Recently, this diversity quite often became an incentive to suggest that organic species might have arrived to Earth (and other forming planets) in a "ready-to-use" form. However, one has to remember that numerous factors causing effective molecule destruction are in action in the interstellar medium, in the vicinity of young stars, and in protoplanetary disks.

Dust evolution, a global view: III. Core/mantle grains, organic nano-globules, comets and surface chemistry

PubMed Central

2016-01-01

Within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), this work explores the surface processes and chemistry relating to core/mantle interstellar and cometary grain structures and their influence on the nature of these fascinating particles. It appears that a realistic consideration of the nature and chemical reactivity of interstellar grain surfaces could self-consistently and within a coherent framework explain: the anomalous oxygen depletion, the nature of the CO dark gas, the formation of ‘polar ice’ mantles, the red wing on the 3 μm water ice band, the basis for the O-rich chemistry observed in hot cores, the origin of organic nano-globules and the 3.2 μm ‘carbonyl’ absorption band observed in comet reflectance spectra. It is proposed that the reaction of gas phase species with carbonaceous a-C(:H) grain surfaces in the interstellar medium, in particular the incorporation of atomic oxygen into grain surfaces in epoxide functional groups, is the key to explaining these observations. Thus, the chemistry of cosmic dust is much more intimately related with that of the interstellar gas than has previously been considered. The current models for interstellar gas and dust chemistry will therefore most likely need to be fundamentally modified to include these new grain surface processes. PMID:28083090

Solid H2 in the interstellar medium

NASA Astrophysics Data System (ADS)

Füglistaler, A.; Pfenniger, D.

2018-06-01

Context. Condensation of H2 in the interstellar medium (ISM) has long been seen as a possibility, either by deposition on dust grains or thanks to a phase transition combined with self-gravity. H2 condensation might explain the observed low efficiency of star formation and might help to hide baryons in spiral galaxies. Aims: Our aim is to quantify the solid fraction of H2 in the ISM due to a phase transition including self-gravity for different densities and temperatures in order to use the results in more complex simulations of the ISM as subgrid physics. Methods: We used molecular dynamics simulations of fluids at different temperatures and densities to study the formation of solids. Once the simulations reached a steady state, we calculated the solid mass fraction, energy increase, and timescales. By determining the power laws measured over several orders of magnitude, we extrapolated to lower densities the higher density fluids that can be simulated with current computers. Results: The solid fraction and energy increase of fluids in a phase transition are above 0.1 and do not follow a power law. Fluids out of a phase transition are still forming a small amount of solids due to chance encounters of molecules. The solid mass fraction and energy increase of these fluids are linearly dependent on density and can easily be extrapolated. The timescale is below one second, the condensation can be considered instantaneous. Conclusions: The presence of solid H2 grains has important dynamic implications on the ISM as they may be the building blocks for larger solid bodies when gravity is included. We provide the solid mass fraction, energy increase, and timescales for high density fluids and extrapolation laws for lower densities.

The effect of catastrophic collisional fragmentation and diffuse medium accretion on a computational interstellar dust system

NASA Technical Reports Server (NTRS)

Liffman, Kurt

1990-01-01

The effects of catastrophic collisional fragmentation and diffuse medium accretion on a the interstellar dust system are computed using a Monte Carlo computer model. The Monte Carlo code has as its basis an analytic solution of the bulk chemical evolution of a two-phase interstellar medium, described by Liffman and Clayton (1989). The model is subjected to numerous different interstellar processes as it transfers from one interstellar phase to another. Collisional fragmentation was found to be the dominant physical process that shapes the size spectrum of interstellar dust. It was found that, in the diffuse cloud phase, 90 percent of the refractory material is locked up in the dust grains, primarily due to accretion in the molecular medium. This result is consistent with the observed depletions of silicon. Depletions were found to be affected only slightly by diffuse cloud accretion.

Evolution of Interstellar Grains

NASA Technical Reports Server (NTRS)

Allamandola, Lou J.; DeVincenzi, Donald L. (Technical Monitor)

1998-01-01

During the past two decades observations combined with laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the raw materials from which planets, comets and stars form. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by dust-grain and gas-phase reactions. Gaseous species striking the cold (10K) dust stick, forming an icy grain mantle. This accretion, coupled with UV photolysis, produces a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, H2, and perhaps some NH3 and H2CO, as well as more complex species. The evidence for these compounds, as well as carbon-rich materials, will be reviewed and the possible connections with comets and meteorites will be presented in the first part of the talk . The second part of the presentation will focus on interstellar/precometary ice photochemical evolution and the species likely to be found in comets. The chemical composition and photochemical evolution of realistic interstellar/pre-cometary ice analogs will be discussed. Ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and more complex molecules. When ices representative of interstellar grains and comets are exposed to UV radiation at low temperature a series of moderately complex organic molecules are formed in the ice including: CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), and R-C=N (nitriles). Several of these are already known to be in the interstellar medium, and their presence indicates the importance of grain processing. After warming to room temperature an organic residue remains. This is composed primarily of hexamethylenetetramine (HMT, C6H12N4), with lesser amounts of polyoxymethylene-related species (POMs), amides, and ketones. This is in sharp contrast to the organic residues produced by irradiating unrealistic interstellar ice analogs or thermally promoted polymerization-type reactions in unirradiated realistic ice mixtures.

Science From Beyond: NASA's Pioneer Plaque and the History of Interstellar Communication, 1957- 1972

NASA Astrophysics Data System (ADS)

Macauley, William

2012-05-01

In the late twentieth century, science and technology facilitated exploration beyond the Solar System and extended human knowledge through messages comprised of pictures and mathematical symbols, transmitted from radio telescopes and inscribed on material artifacts attached to spacecraft. ‘Interstellar communication' refers to collective efforts by scientists and co-workers to detect and transmit intelligible messages between humans and supposed extraterrestrial intelligence in remote star systems. Interstellar messages are designed to communicate universal knowledge without recourse to text, human linguistic systems or anthropomorphic content because it is assumed that recipients have no prior knowledge of humankind or the planet we inhabit. Scientists must therefore imagine how extraterrestrials will relate to human knowledge and culture. The production and transmission of interstellar messages became interdisciplinary design problems that involved collaboration and exchange of ideas between scientists, visual artists, and others. My proposed paper will review sociocultural aspects of interstellar communication since the late 1950s and focus on key issues regarding conception, design and production of a specific interstellar message launched into space during the early 1970s - NASA's Pioneer plaque. The paper will explore how research on the history of interstellar communication relates to previous historical and sociological studies on rhetorical aspects of visual representation and mathematics in scientific practice. In particular, I will explain how the notion of ‘inscription' is an appropriate conceptual tool for analyzing how scientists have used pictures to articulate and validate knowledge claims and scientific facts. I argue that scientific knowledge carried on interstellar messages such as the Pioneer plaque is constituted in material practices and inscription technologies that translate natural objects, agency and culture into legible forms. Graphical techniques for creating pictorial interstellar messages are enmeshed with contemporaneous methods for creating displays and images in routine scientific work, in fields such as radio astronomy and planetary science.

Radioastronomical Searches for Instellar Biomolecules

NASA Technical Reports Server (NTRS)

Kuan, Y.-J.; Huang, H.-C.; Charnley, S. B.; Markwick, A.; Botta, O.; Ehrenfreund, P.; Kisiel, Z.; Butner, H. M.

2003-01-01

Impacts of comets and asteroids could have delivered large amounts of organic matter to the early Earth. to retain a significant interstellar signature; observations of recent bright comets indicate that they have a molecular inventory consistent with their ices being largely unmodified interstellar material. Many simple organic molecules with biochemical significance observed in circumstellar envelopes and in molecular clouds, similar to that from which the Solar System formed, may have acted as the precursors of the more complex organics found in meteorites. Therefore, there is potentially a strong link between interstellar organics and prebiotic chemical evolution. Radioastronomical observations, particularly at millimeter wavelengths, allow us to determine the chemical composition and characteristics of the molecular inventory in interstellar space. Here we report some of our recent results from extensive astronomical searches for astrobiologically-important interstellar organics.

The molecular inventory around protostars: water, organic molecules, and the missing oxygen problem

NASA Astrophysics Data System (ADS)

Neufeld, David A.

2018-06-01

Massive star formation is accompanied by significant chemical evolution in the surrounding interstellar gas. Here, grains are heated up and icy mantles evaporate, releasing a rich inventory of water and organic molecules into the gas-phase within “hot core” regions surrounding massive protostars. Because molecules on the grain surface present broad infrared features without rotational structure, only the most abundant molecules can be identified unambiguously in the solid phase; once released into the gas-phase, however, where they are free to rotate, the constituents of grain mantles can be identified easily by means of rotational spectroscopy at millimeter and submillimeter wavelengths or through rovibrational spectroscopy in the mid-infrared. While observations of pure-rotational emission lines provide a broad view of hot core chemistry, absorption line spectroscopy of rovibrational transitions can probe the very hottest material closest to the protostar. With access to the mid-infrared spectral region from above 99% of Earth’s water vapor, SOFIA provides a unique platform for high-resolution rovibrational spectroscopy of water and organic molecules, many of which have vibrational transitions in the 5 – 8 micron spectral region that is unobservable from the ground. High spectral resolution is essential for disentangling the rotational structure and providing reliable measurements of the molecular column densities and temperatures. Future SOFIA observations will help elucidate the inventory of water and organic molecules around young protostars, and can address a puzzle related to the “oxygen budget” in the interstellar medium: surprisingly, the main interstellar reservoirs of the third-most abundant element in the Universe have yet to be identified.

THz Time-Domain Spectroscopy of Interstellar Ice Analogs

NASA Astrophysics Data System (ADS)

Ioppolo, Sergio; McGuire, Brett A.; de Vries, Xander; Carroll, Brandon; Allodi, Marco; Blake, Geoffrey

2015-08-01

The unambiguous identification of nearly 200 molecular species in different astronomical environments proves that our cosmos is a ‘Molecular Universe’. The cumulative outcome of recent observations, laboratory studies, and astrochemical models indicates that there is a strong interplay between the gas and the solid phase throughout the process of forming molecules in space. Observations of interstellar ices are generally limited to lines-of-sight along which infrared absorption spectroscopy is possible. Therefore, the identification of more complex prebiotic molecules in the mid-IR is difficult because of their low expected interstellar abundances and the overlap of their absorption features with those from the more abundant species. In the THz region, telescopes can detect Interstellar ices in emission or absorption against dust continuum. Thus, THz searches do not require a background point source. Moreover, since THz spectra are the fingerprint of inter- and intramolecular forces, complex species can present unique modes that do not overlap with those from simpler, more abundant molecules. THz modes are also sensitive to temperature and phase changes in the ice. Therefore, spectroscopy at THz frequencies has the potential to better characterize the physics and chemistry of the ISM. Currently, the Herschel Space Telescope, SOFIA, and ALMA databases contain a vast amount of new THz spectral data that require THz laboratory spectra for interpretation. The latter, however, are largely lacking. We have recently constructed a new THz time-domain spectroscopy system operating in the range between 0.3 - 7.5 THz. This work focuses on the laboratory investigation of the composition and structure of the most abundant interstellar ice analogs compared to some more complex species. Different temperatures, mixing ratios, and matrix isolation experiments will be shown. The ultimate goal of this research is to provide the scientific community with an extensive THz ice-database, which will allow quantitative studies of the ISM, and guide future astronomical observations of species in the solid phase.

Self-Assembling Amphiphilic Molecules: A Possible Relationship Between Interstellar Chemistry and Meteoritic Organics

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Dworkin, Jason P.; Deamer, David W.; Allamandola, Louis J.; DeVincenzi, Donald (Technical Monitor)

2001-01-01

Interstellar gas and dust comprise the primary material from which the solar system formed. Evidence that some of this material was organic in nature and survived incorporation into the protosolar nebula is provided by the presence of deuterium-enriched organics in meteorites and interplanetary dust particles. Once the inner planets had sufficiently cooled, late accretionary infall of meteoroids and cosmic dust must have seeded them with some of these complex organic compounds. Delivery of such extraterrestrial compounds may have contributed to the organic inventory necessary for the origin of life. Interstellar ices, the building blocks of comets, tie up a large fraction of the biogenic elements available in molecular clouds. In our efforts to understand their synthesis, chemical composition, and physical properties, we report here that a complex mixture of molecules is produced by ultraviolet (UV) photolysis of realistic, interstellar ice analogs, and that some of the components have properties relevant to the origin of life, including the ability to self-assemble into vesicular structures.

Ejection of rocky and icy material from binary star systems: implications for the origin and composition of 1I/`Oumuamua

NASA Astrophysics Data System (ADS)

Jackson, Alan P.; Tamayo, Daniel; Hammond, Noah; Ali-Dib, Mohamad; Rein, Hanno

2018-06-01

In single-star systems like our own Solar system, comets dominate the mass budget of bodies ejected into interstellar space, since they form further away and are less tightly bound. However, 1I/`Oumuamua, the first interstellar object detected, appears asteroidal in its spectra and lack of detectable activity. We argue that the galactic budget of interstellar objects like 1I/`Oumuamua should be dominated by planetesimal material ejected during planet formation in circumbinary systems, rather than in single-star systems or widely separated binaries. We further show that in circumbinary systems, rocky bodies should be ejected in comparable numbers to icy ones. This suggests that a substantial fraction of interstellar objects discovered in future should display an active coma. We find that the rocky population, of which 1I/`Oumuamua seems to be a member, should be predominantly sourced from A-type and late B-star binaries.

Molecular Diagnostics of the Interstellar Medium and Star Forming Regions

NASA Astrophysics Data System (ADS)

Hartquist, T. W.; Dalgarno, A.

1996-03-01

Selected examples of the use of observationally inferred molecular level populations and chemical compositions in the diagnosis of interstellar sources and processes important in them (and in other diffuse astrophysical sources) are given. The sources considered include the interclump medium of a giant molecular cloud, dark cores which are the progenitors of star formation, material responding to recent star formation and which may form further stars, and stellar ejecta (including those of supernovae) about to merge with the interstellar medium. The measurement of the microwave background, mixing of material between different nuclear burning zones in evolved stars and turbulent boundary layers (which are present in and influence the structures and evolution of all diffuse astrophysical sources) are treated.

Hydrocarbons on Saturns Satellites: Relationship to Interstellar Dust and the Solar Nebula

NASA Technical Reports Server (NTRS)

Cruikshank, D. P.

2012-01-01

To understand the origin and evolution of our Solar System, and the basic components that led to life on Earth, we study interstellar and planetary spectroscopic signatures. The possible relationship of organic material detected in carbonaceous meteorites, interplanetary dust particles (IDPs), comets and the interstellar medium have been the source of speculation over the years as the composition and processes that governed the early solar nebula have been explored to understand the extent to which primitive material survived or became processed. The Cassini VIMS has provided new data relevant to this problem. Three of Saturn's satellites, Phoebe, Iapetus, and Hyperion, are found to have aromatic and aliphatic hydrocarbons on their surfaces. The aromatic hydrocarbon signature (C-H stretching mode at 3.28 micrometers) is proportionally significantly stronger (relative to the aliphatic bands) than that seen in other Solar System bodies (e.g., comets) and materials (Stardust samples, IDPs, meteorites) and the distinctive sub-features of the 3.4 micrometer aliphatic band (CH2 and CH3 groups) are reminiscent of those widely detected throughout the diffuse ISM. Phoebe may be a captured object that originated in the region beyond the present orbit of Neptune, where the solar nebula contained a large fraction of original interstellar ice and dust that was less processed than material closer to the Sun. Debris from Phoebe now resident on Iapetus and Hyperion, as well as o Phoebe itself, thus presents a unique blend of hydrocarbons, amenable to comparisons with interstellar hydrocarbons and other Solar System materials. The dust ring surrounding Saturn, in which Phoebe is embedded, probably originated from a collision with Phoebe. Dust ring particles are the likely source of the organic-bearing materials, and perhaps the recently identified small particles of Fe detected on Saturn's satellites. Lab measurements of the absolute band strengths of representative aliphatic and aromatic molecules, together with measurements from the VIMS data, allow us to calculate the number of C atoms to find the relative abundances of C atoms in the two kinds of organic molecules. The strength of the prominent aromatic C-H stretch band relative to the aliphatic band complex in Phoebe and Iapetus indicates that the relative abundance of aromatic to aliphatic carbon is very large (greater than 200). In contract, the aromatic band is nearly imperceptible in spectra of interplanetary dust particles (IDP), returned samples from comet 91P/Wild 2, insoluable carbonaceous material in most meteorites, and the diffuse interstellar dust (DISM) (although aromatics are known in all these materials-here we consider only the spectroscopic signature)

The carbon budget in the outer solar nebula

NASA Technical Reports Server (NTRS)

Simonelli, Damon P.; Pollack, James B.; Mckay, Christopher P.; Reynolds, Ray T.; Summers, Audrey L.

1989-01-01

The compositional contrast between the giant-planet satellites and the significantly rockier Pluto/Charon system is indicative of different formation mechanisms; cosmic abundance calculations, in conjunction with an assumption of the Pluto/Charon system's direct formation from solar nebula condensates, strongly suggest that most of the carbon in the outer solar nebula was in CO form, in keeping with both the inheritance from the dense molecular clouds in the interstellar medium, and/or the Lewis and Prinn (1980) kinetic-inhibition model of solar nebula chemistry. Laboratory studies of carbonaceous chondrites and Comet Halley flyby studies suggest that condensed organic material, rather than elemental carbon, is the most likely candidate for the small percentage of the carbon-bearing solid in the outer solar nebula.

Following the Interstellar History of Carbon: From the Interiors of Stars to the Surfaces of Planets.

PubMed

Ziurys, L M; Halfen, D T; Geppert, W; Aikawa, Y

2016-12-01

The chemical history of carbon is traced from its origin in stellar nucleosynthesis to its delivery to planet surfaces. The molecular carriers of this element are examined at each stage in the cycling of interstellar organic material and their eventual incorporation into solar system bodies. The connection between the various interstellar carbon reservoirs is also examined. Carbon has two stellar sources: supernova explosions and mass loss from evolved stars. In the latter case, the carbon is dredged up from the interior and then ejected into a circumstellar envelope, where a rich and unusual C-based chemistry occurs. This molecular material is eventually released into the general interstellar medium through planetary nebulae. It is first incorporated into diffuse clouds, where carbon is found in polyatomic molecules such as H 2 CO, HCN, HNC, c-C 3 H 2 , and even C 60 + . These objects then collapse into dense clouds, the sites of star and planet formation. Such clouds foster an active organic chemistry, producing compounds with a wide range of functional groups with both gas-phase and surface mechanisms. As stars and planets form, the chemical composition is altered by increasing stellar radiation, as well as possibly by reactions in the presolar nebula. Some molecular, carbon-rich material remains pristine, however, encapsulated in comets, meteorites, and interplanetary dust particles, and is delivered to planet surfaces. Key Words: Carbon isotopes-Prebiotic evolution-Interstellar molecules-Comets-Meteorites. Astrobiology 16, 997-1012.

Laboratory investigation of the contribution of complex aromatic/aliphatic polycyclic hybrid molecular structures to interstellar ultraviolet extinction and infrared emission

NASA Technical Reports Server (NTRS)

Arnoult, K. M.; Wdowiak, T. J.; Beegle, L. W.

2000-01-01

We have demonstrated by experiment that, in an energetic environment, a simple polycyclic aromatic hydrocarbon (PAH) such as naphthalene will undergo chemical reactions that produce a wide array of more complex species (an aggregate). For a stellar wind of a highly evolved star (post-asymptotic giant branch [post-AGB]), this process would be in addition to what is expected from reactions occurring under thermodynamic equilibrium. A surprising result of that work was that produced in substantial abundance are hydrogenated forms that are hybrids of polycyclic aromatic and polycyclic alkanes. Infrared spectroscopy described here reveals a spectral character for these materials that has much in common with that observed for the constituents of circumstellar clouds of post-AGB stars. It can be demonstrated that a methylene (-CH2-) substructure, as in cycloalkanes, is the likely carrier of the 6.9 microns band emission of dust that has recently been formed around IRAS 22272+5433, NGC 7027, and CPD -56 8032. Ultraviolet spectroscopy previously done with a lower limit of 190 nm had revealed that this molecular aggregate can contribute to the interstellar extinction feature at 2175 angstroms. We have now extended our UV spectroscopy of these materials to 110 nm by a vacuum ultraviolet technique. That work, described here, reveals new spectral characteristics and describes how material newly formed during the late stages of stellar evolution could have produced an extinction feature claimed to exist at 1700 angstroms in the spectrum of HD 145502 and also how the newly formed hydrocarbon material would be transformed/aged in the general interstellar environment. The contribution of this molecular aggregate to the rise in interstellar extinction at wavelengths below 1500 angstroms is also examined. The panspectral measurements of the materials produced in the laboratory, using plasmas of H, He, N, and O to convert the simple PAH naphthalene to an aggregate of complex species, provide insight into possible molecular structure details of newly formed hydrocarbon-rich interstellar dust and its transformation into aged material that becomes resident in the interstellar medium. Specifically the presence of naphthalene-like and butadiene-like conjugated structures as chromophores for the 2175 angstroms ultraviolet extinction feature is indicated.

Formation and processing of organics in the early solar system.

PubMed

Kerridge, J F

1999-01-01

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei.

The Origins and Evolution of Molecules in Icy Solids

NASA Technical Reports Server (NTRS)

Hudson, Reggie L.; Moore, Marla H.

2010-01-01

Astronomical observations of the past few decades have revealed the existence of a variety of molecules in extraterrestrial ices. These molecules include H2O, CO, and CO2, and organics such as CH4, CH30H, and C2H6. Some ices are dominated by polar molecules, while non-polar species appear to dominate others. Observations, mainly in the radio and IR regions, have allowed the inference of other solid-phase molecules whose formation remains difficult to explain by gas-phase chemistry alone. Several laboratory research groups have reported on extensive experiments on the solid-phase reaction chemistry of icy materials, generally as initiated by either ionizing radiation or vacuum-UV photons. These experiments not only permit molecular identifications to be made from astronomical observations, but also allow predictions of yet unidentified molecules. This laboratory approach has evolved over more than 30 years with much of the earliest work focusing on complex mixtures thought to represent either cometary or interstellar ices. Although those early experiments documented a rich solid-state photo- and radiation chemistry, they revealed few details of reactions for particular molecules, partly due to the multi-component nature of the samples. Since then, model systems have been examined that allow the chemistry of individual species and specific reactions to be probed. Reactions involving most of the smaller astronomical molecules have now been studied and specific processes identified. Current laboratory work suggests that a variety of reactions occur in extraterrestrial ices, including acid-base processes, radical dimerizations, proton transfers, oxidations, reductions, and isomerizations. This workshop presentation will focus on chemical reactions relevant to solar system and interstellar ices. While most of the work will be drawn from that to which the speaker has contributed, results from other laboratories also will be included. Suggestions for future studies will be made, with an emphasis on some present deficiencies. The speaker's work has been generously supported by these NASA research programs: Cassini Data Analysis, Exobiology, Mars Fundamental Research, Outer Planets Research, Planetary Atmospheres, Planetary Geology and Geophysics, and the NASA Astrobiology Institute.

Stardust Interstellar Preliminary Examination (ISPE)

NASA Technical Reports Server (NTRS)

Westphal, A. J.; Allen, C.; Bajt, S.; Basset, R.; Bastien, R.; Bechtel, H.; Bleuet, P.; Borg, J.; Brenker F.; Bridges, J.

2009-01-01

In January 2006 the Stardust sample return capsule returned to Earth bearing the first solid samples from a primitive solar system body, C omet 81P/Wild2, and a collector dedicated to the capture and return o f contemporary interstellar dust. Both collectors were approximately 0.1m(exp 2) in area and were composed of aerogel tiles (85% of the co llecting area) and aluminum foils. The Stardust Interstellar Dust Col lector (SIDC) was exposed to the interstellar dust stream for a total exposure factor of 20 m(exp 2-) day during two periods before the co metary encounter. The Stardust Interstellar Preliminary Examination ( ISPE) is a three-year effort to characterize the collection using no ndestructive techniques. The ISPE consists of six interdependent proj ects: (1) Candidate identification through automated digital microsco py and a massively distributed, calibrated search (2) Candidate extr action and photodocumentation (3) Characterization of candidates thro ugh synchrotronbased FourierTranform Infrared Spectroscopy (FTIR), S canning XRay Fluoresence Microscopy (SXRF), and Scanning Transmission Xray Microscopy (STXM) (4) Search for and analysis of craters in f oils through FESEM scanning, Auger Spectroscopy and synchrotronbased Photoemission Electron Microscopy (PEEM) (5) Modeling of interstell ar dust transport in the solar system (6) Laboratory simulations of h ypervelocity dust impacts into the collecting media

Matrix isolation as a tool for studying interstellar chemical reactions

NASA Technical Reports Server (NTRS)

Ball, David W.; Ortman, Bryan J.; Hauge, Robert H.; Margrave, John L.

1989-01-01

Since the identification of the OH radical as an interstellar species, over 50 molecular species were identified as interstellar denizens. While identification of new species appears straightforward, an explanation for their mechanisms of formation is not. Most astronomers concede that large bodies like interstellar dust grains are necessary for adsorption of molecules and their energies of reactions, but many of the mechanistic steps are unknown and speculative. It is proposed that data from matrix isolation experiments involving the reactions of refractory materials (especially C, Si, and Fe atoms and clusters) with small molecules (mainly H2, H2O, CO, CO2) are particularly applicable to explaining mechanistic details of likely interstellar chemical reactions. In many cases, matrix isolation techniques are the sole method of studying such reactions; also in many cases, complexations and bond rearrangements yield molecules never before observed. The study of these reactions thus provides a logical basis for the mechanisms of interstellar reactions. A list of reactions is presented that would simulate interstellar chemical reactions. These reactions were studied using FTIR-matrix isolation techniques.

Organic Chemistry: From the Interstellar Medium to the Solar System

NASA Technical Reports Server (NTRS)

Sandford, Scott; Witteborn, Fred C. (Technical Monitor)

1997-01-01

This talk will review the various types of organic materials observed in different environments in the interstellar medium, discuss the processes by which these materials may have formed and been modified, and present the evidence supporting the contention that at least a fraction of this material survived incorporation, substantially unaltered, into our Solar System during its formation. The nature of this organic material is of direct interest to issues associated with the origin of life, both because this material represents a large fraction of the Solar System inventory of the biogenically-important elements, and because many of the compounds in this inventory have biogenic implications. Several specific examples of such molecules will be briefly discussed.

Delta II Stardust Mission Briefing

NASA Technical Reports Server (NTRS)

1999-01-01

An overview of the Stardust Mission is shown. NASA personnel is seen discussing and explaining the path of the probe. An animated clip is presented to demonstrate how the probe will collect interstellar dust materials, and space particles by using an aerogel. The animation also described the process by which the probe will take photographs of the comets from the on board camera. The dust samples and the photographs will be analyzed in order to learn more about interstellar materials.

Interstellar Antifreeze: Ethylene Glycol

NASA Technical Reports Server (NTRS)

Hollis, J. M.; Lovas, F. J.; Jewell, P. R.; Coudert, L. H.

2002-01-01

Interstellar ethylene glycol (HOCH2CH2,OH) has been detected in emission toward the Galactic center source Sagittarius B2(N-LMH) by means of several millimeter-wave rotational torsional transitions of its lowest energy conformer. The types and kinds of molecules found to date in interstellar clouds suggest a chemistry that favors aldehydes and their corresponding reduced alcohols-e.g., formaldehyde (H2CO)/methanol (CH3OH), acetaldehyde (CH3CHO)/ethanol (CH3CH2OH). Similarly, ethylene glycol is the reduced alcohol of glycolaldehyde (CH2OHCHO), which has also been detected toward Sgr B2(N-LMH). While there is no consensus as to how any such large complex molecules are formed in the interstellar clouds, atomic hydrogen (H) and carbon monoxide (CO) could form formaldehyde on grain surfaces, but such surface chemistry beyond that point is uncertain. However, laboratory experiments have shown that the gas-phase reaction of atomic hydrogen (H) and solid-phase CO at 10-20 K can produce formaldehyde and methanol and that alcohols and other complex molecules can be synthesized from cometary ice analogs when subject to ionizing radiation at 15 K. Thus, the presence of aldehyde/ reduced alcohol pairs in interstellar clouds implies that such molecules are a product of a low-temperature chemistry on grain surfaces or in grain ice mantles. This work suggests that aldehydes and their corresponding reduced alcohols provide unique observational constraints on the formation of complex interstellar molecules.

Dust Spectroscopy and the Nature of Grains

NASA Technical Reports Server (NTRS)

Tielens, A. G. G. M.

2006-01-01

Ground-based, air-borne and space-based, infrared spectra of a wide variety of objects have revealed prominent absorption and emission features due to large molecules and small dust grains. Analysis of this data reveals a highly diverse interstellar and circumstellar grain inventory, including both amorphous materials and highly crystalline compounds (silicates and carbon). This diversity points towards a wide range of physical and chemical birthsites as well as a complex processing of these grains in the interstellar medium. In this talk, I will review the dust inventory contrasting and comparing both the interstellar and circumstellar reservoirs. The focus will be on the processes that play a role in the lifecycle of dust in the interstellar medium.

The Exobiological Role of Interstellar Polycyclic Aromatic Hydrocarbons and Ices

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; DeVincenzi, Donald (Technical Monitor)

2002-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Before this time, the composition of interstellar dust was largely guessed-at, the presence of ices in interstellar clouds ignored, and the notion that large, gas phase, carbon rich molecules might be abundant and widespread throughout the interstellar medium (ISM) considered impossible. Today, the composition of dust in the ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these cold dust particles secrete mantles of mixed molecular ices whose compositions are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by the standards of interstellar chemistry, the telltale infrared spectral signature of which is now recognized throughout the Universe. In the first part of this talk, we will review the spectroscopic evidence that forms the basis for the currently accepted abundance and ubiquity of PANs in the ISM. We will then look at a few specific examples which illustrate how experimental and theoretical data can be applied to interpret the interstellar spectra and track how the PAN population evolves as it passes from its formation site in the circumstellar outflows of dying stars, through the various phases of the ISM, and into forniing planetary systems. Nevertheless, despite the fact that PANs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which this population can be dislodged from the precipitous thermodynamic well afforded by their extensive aromatic networks, they are of little Astrobiological significance. Consequently, for the remainder of the talk, we will consider the photochemical evolution of PANS under conditions similar to those found in the ISM and in proto-planetary systems with an eye toward means by which this rich repository of pre-biotic organic "ore" might be converted into materials of greater importance to Astrobiology.

Positron beam studies of solids and surfaces: A summary

NASA Astrophysics Data System (ADS)

Coleman, P. G.

2006-02-01

A personal overview is given of the advances in positron beam studies of solids and surfaces presented at the 10th International Workshop on Positron Beams, held in Doha, Qatar, in March 2005. Solids studied include semiconductors, metals, alloys and insulators, as well as biophysical systems. Surface studies focussed on positron annihilation-induced Auger electron spectroscopy (PAES), but interesting applications of positron-surface interactions in fields as diverse as semiconductor technology and studies of the interstellar medium serve to illustrate once again the breadth of scientific endeavour covered by slow positron beam investigations.

Identification of Possible Interstellar Dust Impact Craters on Stardust Foil I033N,1

NASA Astrophysics Data System (ADS)

Ansari, A.; ISPE Team; 29,000 Stardust@home Dusters

2011-12-01

The Interstellar Dust Collector onboard NASA's Stardust Mission - the first to return solid extraterrestrial material to Earth from beyond the Moon - was exposed to the interstellar dust stream for a total of 229 days prior to the spacecraft's return in 2006 [1]. Aluminum foils and aerogel tiles on the collector may have captured the first samples of contemporary interstellar dust. Interstellar Preliminary Examination (ISPE) focuses in part on crater identification and analysis of residue within the craters to determine the nature and origin of the impacting particles. Thus far, ISPE has focused on nine foils and found a total of 20 craters. The number density of impact craters on the foils exceeds by far estimates made from interstellar flux calculations [2]. To identify craters, foil I1033N,1 was scanned with the Field Museum's Evo 60 Scanning Electron Microscope (SEM) at a resolution of 52 nm/pixel with a 15 kV and 170-240 pA beam. Contamination was monitored according to the ISPE protocol: four 4 μm × 3 μm areas of C layers of different thicknesses on a Stardust-type Al foil were irradiated 20 times for 50 s each, while the C and Al signals were recorded with energy-dispersive X-ray spectroscopy (EDS). The C/Al ratio did not increase after 20 repetitions on each of the four areas. The same experiment repeated 7 months later yielded identical results. Thus, analysis with the SEM results in no detectable contamination. Crater candidates were manually selected from SEM images, then reimaged at higher resolution (17 nm/pixel) in order to eliminate false detections. The foil was then sent to Washington University for Auger Nanoprobe elemental analysis of crater 11_175 (diam. 1.1 μm), and to the Naval Research Laboratory for focused ion beam work and transmission electron microscopy and EDS. Twelve crater candidates (diam. 0.28 - 1.1 μm), both elliptical and circular, were identified. The number density of craters on foil 1033N is 15.8 cm^-2. Auger measurements of crater 11_175 revealed the presence of C, O, Al, Si, a small amount of Na, and possibly Ce and Zn [3] - both components of solar cell cover glass - indicating that this particular crater resulted from a particle that impacted the spacecraft's solar panels. TEM/EDS analysis determined the presence of solar cell glass.

Polycyclic Aromatic Hydrocarbons and the Diffuse Interstellar Bands: a Survey

NASA Technical Reports Server (NTRS)

Salama, F.; Galazutdinov, G. A.; Krelowski, J.; Allamandola, L. J.; Musaev, F. A.; DeVincenzi, Donald L. (Technical Monitor)

1999-01-01

We discuss the proposal relating the origin of some of the diffuse interstellar bands (DIBs) to neutral and ionized polycyclic aromatic hydrocarbons (PAHs) present in interstellar clouds. Laboratory spectra of several PAHs, isolated at low temperature in inert gas matrices, are compared with an extensive set of astronomical spectra of reddened, early type stars. From this comparison, it is concluded that PAN ions are good candidates to explain some of the DIBs. Unambiguous assignments are difficult, however, due to the shift in wavelengths and the band broadening induced in the laboratory spectra by the solid matrix. Definitive band assignments and, ultimately, the test of the of the proposal that PAH ions carry some of the DIB must await the availability of gas-phase measurements in the laboratory. The present assessment offers a guideline for future laboratory experiments by allowing the preselection of promising PAH molecules to be studied in jet expansions.

Interstellar/Precometary Organic Material and the Photochemical Evolution of Complex Organics

NASA Technical Reports Server (NTRS)

Allamandola, Lou J.; Bernstein, Max; Sandford, Scott; Witteborn, Fred (Technical Monitor)

1996-01-01

During the past two decades ground-, air-, and space-based infrared spectroscopic observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the raw materials from which planets, comets and stars form. Most interstellar material is concentrated in Large molecular clouds where simple molecules are formed by dust grain and gas phase reactions. Gaseous species striking the cold (10 K) dust will stick, forming an icy grain mantle. This accretion, coupled with energetic particle bombardment and UV photolysis, will produce a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, H2, and perhaps some NH3 and H2CO, as well as more complex species including nitriles and ketones or esters. The evidence for these compounds as well as carbon rich materials such as polycyclic aromatic hydrocarbons (PAHs), microdiamonds, and amorphous carbon will be reviewed and the possible connections with comets and meteorites will be presented in the first part of the talk. The second part of the presentation will focus on interstellar/precometary ice photochemical evolution. The chemical composition and photochemical evolution of realistic interstellar/pre-cometary ice analogs containing methanol will be discussed. ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and more complex molecules. Infrared spectroscopy, H-1 and C-13 nuclear magnetic resonance (NMR) spectroscopy, and gas chromatography-mass spectrometry demonstrate that when ices representative of interstellar grains and comets are exposed to UV radiation at low temperature a series of moderately complex organic molecules are formed in the ice including: CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), and R-C(integral)N (nitriles). Several of these are already known to be in the interstellar medium, and their presence indicates the importance of grain processing. After warming to room temperature what remains is an organic residue composed primarily of Hexamethylenetetramine (HMT, C6H12N4), with lesser amounts of polyoxymethylene related species (POMs), amides, and ketones. This is in sharp contrast to the organic residues produced by irradiating ices which do not contain methanol (unrealistic interstellar ice analogs) or thermally promoted polymerization-type reactions in unirradiated realistic ice mixtures. Here HMT is only a minor product in a residue dominated by a mixture of polyoxymethylene related species. The implications, for infrared astronomy and astrochemistry, of high concentrations of HMT in interstellar and cometary ices may be profound. The ultraviolet photolysis of HMT frozen in H20 ice produces the "XCN" band observed in the spectra of protostellar objects and laboratory ices, as well as carbon oxides and other nitriles. Thus, HMT may be a precursor of XCN in protostellar objects and a source of CN and CO in the tail of comets. Also, HMT is known to hydrolyze under acidic conditions to yield ammonia and formaldehyde as well as amino acids. Thus, HMT may have been a source of organic material delivered to the early earth by comets.

Charting the Interstellar Magnetic Field causing the Interstellar Boundary Explorer (IBEX) Ribbon of Energetic Neutral Atoms

NASA Astrophysics Data System (ADS)

Frisch, P. C.; Berdyugin, A.; Piirola, V.; Magalhaes, A. M.; Seriacopi, D. B.; Wiktorowicz, S. J.; Andersson, B.-G.; Funsten, H. O.; McComas, D. J.; Schwadron, N. A.; Slavin, J. D.; Hanson, A. J.; Fu, C.-W.

2015-12-01

The interstellar magnetic field (ISMF) near the heliosphere is a fundamental component of the solar galactic environment that can only be studied using polarized starlight. The results of an ongoing survey of the linear polarizations of local stars are analyzed with the goal of linking the ISMF that shapes the heliosphere to the nearby field in interstellar space. We present new results on the direction of the magnetic field within 40 pc obtained from analyzing polarization data using a merit function that determines the field direction that provides the best fit to the polarization data. Multiple magnetic components are identified, including a dominant interstellar field, {B}{POL}, that is aligned with the direction ℓ, b = 36.°2, 49.°0 (±16.°0). Stars tracing {B}{POL} have the same mean distance as stars that do not trace {B}{POL}, but show weaker average polarizations consistent with a smaller column density of polarizing material. {B}{POL} is aligned with the ISMF traced by the IBEX Ribbon to within {7.6}-7.6+14.9 degrees. The variations in the polarization position angle directions derived from the data that best match {B}{POL} indicate a low level of magnetic turbulence, ˜9° ± 1°. The direction of {B}{POL} is obtained after excluding polarization data tracing a separate magnetic structure that appears to be associated with interstellar dust deflected around the heliosphere. The velocities of local interstellar clouds relative to the Local Standard of Rest (LSR) increase with the angles between the LSR velocities and {B}{POL}, indicating that the kinematics of local interstellar material is ordered by the ISMF. The Loop I superbubble that extends close to the Sun contains dust that reddens starlight and whose distance is determined by the color excess E(B - V) of starlight. Polarizations caused by grains aligned with respect to {B}{POL} are consistent with the location of the Sun in the rim of the Loop I superbubble. An angle of {76.8}-27.6+23.5 between {B}{POL} and the bulk LSR velocity the local interstellar material indicates a geometry that is consistent with an expanding superbubble. The efficiency of grain alignment in the local interstellar medium has been assessed using stars where both polarization data and hydrogen column density data are available. Nearby stars appear to have larger polarizations than expected based on reddened sightlines, which is consistent with previous results, but uncertainties are large. Optical polarization and color excess E(B - V) data indicate the presence of nearby interstellar dust in the BICEP2 field. Color excess E(B - V) indicates an optical extinction of AV > 0.6 in the BICEP2 field, while the polarization data indicate that AV > 0.09 mag. The IBEX Ribbon ISMF extends to the boundaries of the BICEP2 region.

GEMS Revealed: Spectrum Imaging of Aggregate Grains in Interplanetary Dust

NASA Technical Reports Server (NTRS)

Keller, L. P.; Messenger, S.; Christoffersen, R.

2005-01-01

Anhydrous interplanetary dust particles (IDPs) of cometary origin contain abundant materials that formed in the early solar nebula. These materials were transported outward and subsequently mixed with molecular cloud materials and presolar grains in the region where comets accreted [1]. GEMS (glass with embedded metal and sulfides) grains are a major component of these primitive anhydrous IDPs, along with crystalline Mg-rich silicates, Fe-Ni sulfides, carbonaceous material, and other trace phases. Some GEMS grains (5%) are demonstrably presolar based on their oxygen isotopic compositions [2]. However, most GEMS grains are isotopically solar and have bulk chemical compositions that are incompatible with inferred compositions of interstellar dust, suggesting a solar system origin [3]. An alternative hypothesis is that GEMS grains represent highly irradiated interstellar grains whose oxygen isotopic compositions were homogenized through processing in the interstellar medium (ISM) [4]. We have obtained the first quantitative X-ray maps (spectrum images) showing the distribution of major and minor elements in individual GEMS grains. Nanometer-scale chemical maps provide critical data required to evaluate the differing models regarding the origin of GEMS grains.

Decoding IR Spectra of Cosmic Ices and Organics in the Laboratory

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.

2006-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty-five years thanks to significant developments in observational IR astronomy and dedicated laboratory experiments. Twenty-five years ago the composition of interstellar dust was largely guessed at. Today the composition of interstellar dust is reasonably well understood. In the diffuse interstellar medium (ISM) the dust population is mainly comprised of small grains of silicates and amorphous carbon. In dark molecular clouds, the birthplace of stars and planets, these cold refractory dust particles are coated with mixed molecular ices whose composition is reasonably well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. This extraordinary progress has been made possible by the close collaboration of laboratory experimentalists and theoreticians with IR astronomers using groundbased, air-borne, and orbiting telescopes.

Solar System Connections to the Organic Material In the ISM

NASA Technical Reports Server (NTRS)

Pendleton, Yvonne J.

2003-01-01

The organic component of the interstellar medium (ISM) has relevance to the formation of the early solar nebula, since our solar system formed out of ISM material. Comparisons of near infrared spectra of the diffuse ISM dust with those of primitive solar system bodies (such as comets and meteorites) show a remarkable similarity, suggesting that perhaps some of the interstellar organic material made its way, unaltered, into our solar system. Tracing the interstellar organic material is necessary to understand how these materials may be important links in the development of prebiotic phenomena. Studies of the ISM reveal that the organic refractory component of the diffuse ISM is largely hydrocarbon in nature, possessing little N or O, with carbon distributed between the aromatic and aliphatic forms. There is a strong similarity in the near IR spectra of the diffuse ISM (the 3.4 micron hydrocarbon bands) and those seen in the Murchison and Orgueil meteorites, however, detailed comparisons at longer wavelengths reveal critical dissimilarities. Here we will present comparisons and discussion of relevant spectra. As we continue to explore, we will gain insight into the connection between planetesimals in the solar system and chemistry in the dusty space between the stars.

Extraterrestrial Radiation Chemistry and Molecular Astronomy

NASA Technical Reports Server (NTRS)

Hudson, Reggie L.; Moore, Marla H.

2009-01-01

Astronomical observations of both solar system and interstellar regions have revealed a rich chemical inventory that includes most classes of organic molecules and selected inorganics. For example, gas-phase ethylene glycol and SOz have been observed by astronomers, while solidphase detections include OCS, H2O2 , and the cyanate anion.' All of these are found in environments that are, by earthly standards, exceedingly hostile: temperatures of 10 - 100 K, miniscule densities, and near-ubiquitous ionizing-radiation fields. Beyond the simplest chemical species, these conditions have made it difficult-to-impassible to account for the observed molecular abundances using gas-phase chemistry, suggesting solid-phase reactions play an important role. In extraterrestrial environments, cosmic rays, UV photons, and magnetospheric radiation all drive chemical reactions, even at cryogenic temperatures. To study this chemistry, radiation astrochemists conduct experiments on icy materials, frozen under vacuum and exposed to sources such as keV electrons and MeV protons. Compositional changes usually are followed with IR spectroscopy and, in selected cases, more-sensitive mass-spectral techniques. This talk will review some recent results on known and suspected extraterrestrial molecules and ions. Spectra and reaction pathways will be presented, and predictions made for interstellar chemistry and the chemistry of selected solar system objects. Some past radiation-chemical contributions, and future needs, will be explored.

Chemical Signatures of Interstellar Dusts Preserved in Primitive Chondrites and Inner Planets of the Solar System

NASA Technical Reports Server (NTRS)

Yin, Qing-Zhu

2002-01-01

We show that the inheritance of interstellar materials by the solar system is not only documented by the presence of presolar grains, various isotopic anomalies, but also expressed in the chemical element distribution in the inner solar system. Additional information is contained in the original extended abstract.

Chemistry between the stars

NASA Technical Reports Server (NTRS)

Gammon, R. H.

1976-01-01

A unit is presented for the secondary school teacher of physics, chemistry, astronomy, or earth sciences. Included are a list of reference materials, teaching aids, and projects. Discussion questions and a glossary are also provided. Concepts developed are: the nature of interstellar space, spectroscopy, molecular signals from space and interstellar molecules and other areas of astronomy.

Radical formation, chemical processing, and explosion of interstellar grains

NASA Technical Reports Server (NTRS)

Greenberg, J. M.

1976-01-01

The ultraviolet radiation in interstellar space is shown to create a sufficient steady-state density of free radicals in the grain mantle material consisting of oxygen, carbon, nitrogen, and hydrogen to satisfy the critical condition for initiation of chain reactions. The criterion for minimum critical particle size for maintaining the chain reaction is of the order of the larger grain sizes in a distribution satisfying the average extinction and polarization measures. The triggering of the explosion of interstellar grains leading to the ejection of complex interstellar molecules is shown to be most probable where the grains are largest and where radiation is suddenly introduced; i.e., in regions of new star formation. Similar conditions prevail at the boundaries between very dark clouds and H II regions. When the energy released by the chemical activity of the free radicals is inadequate to explode the grain, the resulting mantle material must consist of extremely large organic molecules which are much more resistant to the hostile environment of H II regions than the classical dirty-ice mantles made up of water, methane, and ammonia.

Assessment of the Interstellar Processes Leading to Deuterium Enrichment in Meteoritic Organics

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Bernstein, Max P.; Dworkin, Jason P.; DeVincenzi, Donald L. (Technical Monitor)

2001-01-01

The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low temperature gas phase ion-molecule reactions, low temperature gas-grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D-enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, 0, and N in the same compounds.

Nebular and Interstellar Materials in a Giant Cluster IDP of Probable Cometary Origin

NASA Technical Reports Server (NTRS)

Messenger, S.; Brownlee, D. E.; Joswiak, D. J.; Nguyen, A. N.

2015-01-01

Comets contain a complex mixture of materials with presolar and Solar System origins. Chondritic porous interplanetary dust particles (CP-IDPs) are associated with comets by their fragile nature, unequilibrated anhydrous mineralogy and high abundances of circumstellar grains and isotopically anomalous organic materials. Comet 81P/Wild 2 samples returned by the Stardust spacecraft contain presolar materials as well as refractory 16O-rich Ca-Al-rich inclusion- (CAI), chondrule-, and AOA-like materials. We are conducting coordinated chemical, mineralogical, and isotopic studies of a giant cluster CP-IDP (U2-20-GCA) to determine the proportions of inner Solar System and interstellar materials. We previously found that this IDP contains abundant presolar silicates (approx. 1,800 ppm) and 15N-rich hotspots [6].

PAH in the laboratory and interstellar space

NASA Technical Reports Server (NTRS)

Wdowiak, Thomas J.; Flickinger, Gregory C.; Boyd, David A.

1989-01-01

The theory that polycyclic aromatic hydrocarbons (PAHs) are a constituent of the interstellar medium, and a source of the IR emission bands at 3.3, 6.2, 7.7, 8.6, and 11.3 microns is being studied using PAH containing acid insoluble residue of the Orgueil CI meteorite and coal tar. FTIR spectra of Orgueil PAH material that has undergone thermal treatment, and a solvent insoluble fraction of coal tar that has been exposed to hydrogen plasma are presented. The UV excided luminescence spectrum of a solvent soluble coal tar film is also shown. Comparison of the lab measurements with observations appears to support the interstellar PAH theory, and shows the process of dehydrogenation expected to take place in the interstellar medium.

Urea, Glycolic Acid, and Glycerol in an Organic Residue Produced by Ultraviolet Irradiation of Interstellar/Pre-Cometary Ice Analogs

NASA Astrophysics Data System (ADS)

Nuevo, Michel; Bredehöft, Jan Hendrik; Meierhenrich, Uwe J.; d'Hendecourt, Louis; Thiemann, Wolfram H.-P.

2010-03-01

More than 50 stable organic molecules have been detected in the interstellar medium (ISM), from ground-based and onboard-satellite astronomical observations, in the gas and solid phases. Some of these organics may be prebiotic compounds that were delivered to early Earth by comets and meteorites and may have triggered the first chemical reactions involved in the origin of life. Ultraviolet irradiation of ices simulating photoprocesses of cold solid matter in astrophysical environments have shown that photochemistry can lead to the formation of amino acids and related compounds. In this work, we experimentally searched for other organic molecules of prebiotic interest, namely, oxidized acid labile compounds. In a setup that simulates conditions relevant to the ISM and Solar System icy bodies such as comets, a condensed CH3OH:NH3â = 1:1 ice mixture was UV irradiated at ˜80 K. The molecular constituents of the nonvolatile organic residue that remained at room temperature were separated by capillary gas chromatography and identified by mass spectrometry. Urea, glycolic acid, and glycerol were detected in this residue, as well as hydroxyacetamide, glycerolic acid, and glycerol amide. These organics are interesting target molecules to be searched for in space. Finally, tentative mechanisms of formation for these compounds under interstellar/pre-cometary conditions are proposed.

Micro-ion Traps for Detection of (Pre)-Biotic Organic Compounds on Comets

NASA Technical Reports Server (NTRS)

vanAmerom, Friso H. W.; Chaudhary, A.; Short, R. T.; Brinkerhoff, William; Glavin, Daniel; Mahaffy, Paul R.; Roman, Patrick A.

2013-01-01

Comets are currently believed to be a mixture of interstellar and nebular material. Many of the volatiles in comets are attributed to interstellar chemistry, because the same species of carbonaceous compounds are also observed in ices in interstellar molecular (ISM) clouds. Comets are thus likely to be a relatively pristine reservoir of primitive material and carbonaceous compounds in our solar system. They could be a major contributor to the delivery of prebiotic organic compounds, from which life emerged through impacts on early Earth. Mass spectrometers are very powerful tools to identify unknown chemicals, and much progress bas been made in miniaturizing mas spectrometers for space applications. Most miniatu rized mass spectrometers developed to date, however, are still relatively large, power hungry, complicated to assemble, and would have significant impact on space flight vehicle total payload and resource allocations.

Microcrystals and Amorphous Material in Comets and Primitive Meteorites: Keys to Understanding Processes in the Early Solar System

NASA Technical Reports Server (NTRS)

Nuth, J. A.; Brearley, A. J.; Scott, E. R. D.

2004-01-01

Comets, fine-grained matrices of chondrites, and chondritic interplanetary dust particles (IDPs) are each composed of both crystalline and amorphous silicates. The primitive solar nebula, in which comets and asteroids accreted, was formed from the collapsed core of a Giant Molecular Cloud, that, in turn, condensed from materials present in the interstellar medium (ISM). Despite observations that reveal the presence of crystalline magnesium silicate minerals in the shells of very high mass-loss-rate stars [1,2], typical silicate grains in the ISM are most likely to be amorphous, given their relatively long residence time in such a high radiation environment. An upper limit of 3% crystalline grains can be derived from their non-detection in spectra of ISM solids [3]. If the vast majority of grains that enter the primitive solar nebula are amorphous, then the observation of crystalline dust in comets and primitive chondrite matrices indicates the action of specific processes required to transform the amorphous starting materials into the crystals that are observed.

Evaporation in equilibrium, in vacuum, and in hydrogen gas

NASA Technical Reports Server (NTRS)

Nagahara, Hiroko

1993-01-01

Evaporation experiments were conducted for SiO2 in three different conditions: in equilibrium, in vacuum, and in hydrogen gas. Evaporation rate in vacuum is about two orders of magnitude smaller than that in equilibrium, which is consistent with previous works. The rate in hydrogen gas changes depending on hydrogen pressure. The rate at 10 exp -7 bar of hydrogen pressure is as small as that of free evaporation, but at 10 exp -5 bar of hydrogen pressure it is larger than that in equilibrium. In equilibrium and in vacuum, the evaporation rate is limited by decomposition of SiO2 on the crystal surface, but it is limited by a diffusion process for evaporation in hydrogen gas. Therefore, evaporation rate of minerals in the solar nebula can be shown neither by that in equilibrium nor by that in vacuum. The maximum temperature of the solar nebula at the midplane at 2-3 AU where chondrites are believed to have originated is calculated to be as low as 150 K, 1500 K, or in between them. The temperature is, in any case, not high enough for total evaporation of the interstellar materials. Therefore, evaporation of interstellar materials is one of the most important processes for the origin and fractionation of solid materials. The fundamental process of evaporation of minerals has been intensively studied for these several years. Those experiments were carried out either in equilibrium or in vacuum; however, evaporation in the solar nebula is in hydrogen (and much smaller amount of helium) gas. In order to investigate evaporation rate and compositional (including isotopic) fractionation during evaporation, vaporization experiments for various minerals in various conditions are conducted. At first, SiO2 was adopted for a starting material, because thermochemical data and its nature of congruent vaporization are well known. Experiments were carried out in a vacuum furnace system.

Extraterrestrial organic matter: a review

NASA Technical Reports Server (NTRS)

Irvine, W. M.

1998-01-01

We review the nature of the widespread organic material present in the Milky Way Galaxy and in the Solar System. Attention is given to the links between these environments and between primitive Solar System objects and the early Earth, indicating the preservation of organic material as an interstellar cloud collapsed to form the Solar System and as the Earth accreted such material from asteroids, comets and interplanetary dust particles. In the interstellar medium of the Milky Way Galaxy more than 100 molecular species, the bulk of them organic, have been securely identified, primarily through spectroscopy at the highest radio frequencies. There is considerable evidence for significantly heavier organic molecules, particularly polycyclic aromatics, although precise identification of individual species has not yet been obtained. The so-called diffuse interstellar bands are probably important in this context. The low temperature kinetics in interstellar clouds leads to very large isotopic fractionation, particularly for hydrogen, and this signature is present in organic components preserved in carbonaceous chondritic meteorites. Outer belt asteroids are the probable parent bodies of the carbonaceous chondrites, which may contain as much as 5% organic material, including a rich variety of amino acids, purines, pyrimidines, and other species of potential prebiotic interest. Richer in volatiles and hence less thermally processed are the comets, whose organic matter is abundant and poorly characterized. Cometary volatiles, observed after sublimation into the coma, include many species also present in the interstellar medium. There is evidence that most of the Earth's volatiles may have been supplied by a 'late' bombardment of comets and carbonaceous meteorites, scattered into the inner Solar System following the formation of the giant planets. How much in the way of intact organic molecules of potential prebiotic interest survived delivery to the Earth has become an increasingly debated topic over the last several years. The principal source for such intact organics was probably accretion of interplanetary dust particles of cometary origin.

Interstellar Isotopes: Prospects with ALMA

NASA Technical Reports Server (NTRS)

Charnley Steven B.

2010-01-01

Cold molecular clouds are natural environments for the enrichment of interstellar molecules in the heavy isotopes of H, C, N and O. Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets, that may trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. Models of the fractionation chemistry of H, C, N and O in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred, make several predictions that can be tested in the near future by molecular line observations. The range of fractionation ratios expected in different interstellar molecules will be discussed and the capabilities of ALMA for testing these models (e.g. in observing doubly-substituted isotopologues) will be outlined.

The XMM-Newton View of Wolf-Rayet Bubbles

NASA Astrophysics Data System (ADS)

Guerrero, M.; Toala, J.

2017-10-01

The powerful stellar winds of Wolf-Rayet (WR) stars blow large bubble into the circumstellar material ejected in previous phases of stellar evolution. The shock of those stellar winds produces X-ray-emitting hot plasmas which tells us about the diffusion of processed material onto the interstellar medium, about processes of heat conduction and turbulent mixing at the interface, about the late stages of stellar evolution, and about the shaping of the circumstellar environment, just before supernova explosions. The unique sensitivity of XMM-Newton has been key for the detection, mapping and spectral analysis of the X-ray emission from the hot bubbles around WR stars. These observations underscore the importance of the structure of the interstellar medium around massive stars, but they have also unveiled unknown phenomena, such as blowouts of hot gas into the interstellar medium or spatially-resolved spectral properties of the hot gas, which disclose inhomogeneous chemical abundances and physical properties across these bubbles.

Interaction of the Local Interstellar Medium with the Heliosphere: Role of the Interior and Exterior Magnetic Fields

NASA Technical Reports Server (NTRS)

Barnes, Aaron; DeVincenzi, Donald (Technical Monitor)

2000-01-01

A complete model of the global interaction between the solar wind and the local interstellar medium must take account of interstellar neutral atoms, interstellar ionized gas, solar and galactic magnetic fields, galactic and anomalous cosmic rays. For now, however, in view of the many uncertainties about conditions in the interstellar medium, etc., all models must be regarded as highly idealized and incomplete. In the present review I concentrate on the role of magnetic fields of solar and interstellar origin. The former, the interior field, has negligible influence on the unshocked solar wind; the immediate post-shock solar wind is probably low-beta, so that the interior magnetic field is still unimportant, but this situation changes as the plasma flows through the heliosheath, and a ridge of strong magnetic field may form to separate materials of polar and equatorial origin. The exterior (interstellar) field is likely to play an important role in determining the global morphology of the system outside the termination shock. If the exterior field is strong enough, it can compress the heliosphere (although exterior neutral and/or ionized hydrogen may play the dominant role). Even if the interstellar magnetic field does not provide the dominant pressure, its orientation can substantially affect the configuration of the heliosphere, especially the location and orientation of the heliospheric discontinuities. The configurations can be quite different for the situations in which the field and flow are (a) aligned or (b) transverse. Obliquity of the field produces asymmetry in the geometry of the system; in particular the noses of heliopause and interstellar bow shock are shifted away from the interstellar flow direction, and in opposite directions, due to the asymmetric draping of the magnetic field.

A study of birefringence in the interstellar medium in the direction of the Crab Nebula

NASA Technical Reports Server (NTRS)

Martin, P. G.; Angel, J. R. P.

1974-01-01

The interstellar medium may be regarded as a weak wave plate, the linear birefringence arising from the aligned grains which produce interstellar linear polarization. Using the Crab Nebula as a background source of linearly polarized light we have investigated this birefringence by measurements of circular polarization. The circular component is found to vary with the intrinsic linear polarization in a sinusoidal fashion characteristic of a wave plate with the orientation expected from independent measurements of the interstellar linear polarization in the same direction. Measurements of the wavelength dependence, together with the sense and magnitude of the circular polarization are interpreted as evidence for the dielectric nature of the interstellar grain materials. These observations provide a firm basis for a similar interpretation of the circular polarization of reddened stars. The observations of the stars can then be used to study the grain composition and the structure of the magnetic field in many directions in the Galaxy.

Interstellar polycyclic aromatic hydrocarbons - The infrared emission bands, the excitation/emission mechanism, and the astrophysical implications

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Tielens, G. G. M.; Barker, J. R.

1989-01-01

A comprehensive study of the PAH hypothesis is presented, including the interstellar, IR spectral features which have been attributed to emission from highly vibrationally excited PAHs. Spectroscopic and IR emission features are discussed in detail. A method for calculating the IR fluorescence spectrum from a vibrationally excited molecule is described. Analysis of interstellar spectrum suggests that the PAHs which dominate the IR spectra contain between 20 and 40 C atoms. The results are compared with results from a thermal approximation. It is found that, for high levels of vibrational excitation and emission from low-frequency modes, the two methods produce similar results. Also, consideration is given to the relationship between PAH molecules and amorphous C particles, the most likely interstellar PAH molecular structures, the spectroscopic structure produced by PAHs and PAH-related materials in the UV portion of the interstellar extinction curve, and the influence of PAH charge on the UV, visible, and IR regions.

Interaction of a supernova shock with two interstellar clouds

NASA Astrophysics Data System (ADS)

Hansen, J. F.; McKee, C. F.

2005-10-01

The interaction of supernova shocks and interstellar clouds is an important astrophysical phenomenon since it can result in stellar and planetary formation. Our experiments attempt to simulate this mass-loading as it occurs when a shock passes through interstellar clouds. We drive a strong shock using a 5 kJ laser into a foam-filled cylinder with embedded Al spheres (diameter D=120 μm) simulating interstellar clouds. The density ratio between Al and foam is ˜9. We have previously reported on the interaction between shock and a single cloud, and the ensuing Kelvin-Helmholtz and Widnall instabilities. We now report on experiments under way in which two clouds are placed side by side. Cloud separation (center to center) is either 1.2xD or 1.5xD. Initial results for 1.2xD show that cloud material merges and travels further downstream than in the single cloud case. For 1.5xD, material does not merge, but the clouds tilt toward each other. Work performed under the auspices of the Department of Energy by the Lawrence Livermore National Laboratory under contract number W-7405-ENG-48.

Self-assembling amphiphilic molecules: Synthesis in simulated interstellar/precometary ices

PubMed Central

Dworkin, Jason P.; Deamer, David W.; Sandford, Scott A.; Allamandola, Louis J.

2001-01-01

Interstellar gas and dust constitute the primary material from which the solar system formed. Near the end of the hot early phase of star and planet formation, volatile, less refractory materials were transported into the inner solar system as comets and interplanetary dust particles. Once the inner planets had sufficiently cooled, late accretionary infall seeded them with complex organic compounds [Oró, J. (1961) Nature (London) 190, 389–390; Delsemme, A. H. (1984) Origins Life 14, 51–60; Anders, E. (1989) Nature (London) 342, 255–257; Chyba, C. F. & Sagan, C. (1992) Nature (London) 355, 125–131]. Delivery of such extraterrestrial compounds may have contributed to the organic inventory necessary for the origin of life. Interstellar ices, the building blocks of comets, tie up a large fraction of the biogenic elements available in molecular clouds. In our efforts to understand their synthesis, chemical composition, and physical properties, we report here that a complex mixture of molecules is produced by UV photolysis of realistic, interstellar ice analogs, and that some of the components have properties relevant to the origin of life, including the ability to self-assemble into vesicular structures. PMID:11158552

A multifunctional setup to record FTIR and UV-vis spectra of organic molecules and their photoproducts in astronomical ices.

PubMed

Kofman, V; Witlox, M J A; Bouwman, J; Ten Kate, I L; Linnartz, H

2018-05-01

This article describes a new, multi-functional, high-vacuum ice setup that allows to record the in situ and real-time spectra of vacuum UV (VUV)-irradiated non-volatile molecules embedded in a low-temperature (10 K) amorphous solid water environment. Three complementary diagnostic tools-UV-visible (UV-vis) and Fourier Transform Infrared (FTIR) spectroscopy and temperature-programmed desorption quadrupole mass spectrometry-can be used to simultaneously study the physical and chemical behavior of the organic molecules in the ice upon VUV irradiation. The setup is equipped with a temperature-controlled sublimation oven that enables the controlled homogeneous deposition of solid species such as amino acids, nucleobases, and polycyclic aromatic hydrocarbons (PAHs) in ice mixtures prepared from precursor gases and/or liquids. The resulting ice is photo-processed with a microwave discharge hydrogen lamp, generating VUV radiation with a spectral energy distribution representative for the interstellar medium. The characteristics, performance, and future potential of the system are discussed by describing three different applications. First, a new method is introduced, which uses broadband interference transmission fringes recorded during ice deposition, to determine the wavelength-dependent refractive index, n λ , of amorphous solid water. This approach is also applicable to other solids, pure and mixed. Second, the UV-vis and FTIR spectroscopy of an VUV-irradiated triphenylene:water ice mixture is discussed, monitoring the ionization efficiency of PAHs in interstellar ice environments. The third and final example investigates the stability of solid glycine upon VUV irradiation by monitoring the formation of dissociation products in real time.

A multifunctional setup to record FTIR and UV-vis spectra of organic molecules and their photoproducts in astronomical ices

NASA Astrophysics Data System (ADS)

Kofman, V.; Witlox, M. J. A.; Bouwman, J.; ten Kate, I. L.; Linnartz, H.

2018-05-01

This article describes a new, multi-functional, high-vacuum ice setup that allows to record the in situ and real-time spectra of vacuum UV (VUV)-irradiated non-volatile molecules embedded in a low-temperature (10 K) amorphous solid water environment. Three complementary diagnostic tools—UV-visible (UV-vis) and Fourier Transform Infrared (FTIR) spectroscopy and temperature-programmed desorption quadrupole mass spectrometry—can be used to simultaneously study the physical and chemical behavior of the organic molecules in the ice upon VUV irradiation. The setup is equipped with a temperature-controlled sublimation oven that enables the controlled homogeneous deposition of solid species such as amino acids, nucleobases, and polycyclic aromatic hydrocarbons (PAHs) in ice mixtures prepared from precursor gases and/or liquids. The resulting ice is photo-processed with a microwave discharge hydrogen lamp, generating VUV radiation with a spectral energy distribution representative for the interstellar medium. The characteristics, performance, and future potential of the system are discussed by describing three different applications. First, a new method is introduced, which uses broadband interference transmission fringes recorded during ice deposition, to determine the wavelength-dependent refractive index, nλ, of amorphous solid water. This approach is also applicable to other solids, pure and mixed. Second, the UV-vis and FTIR spectroscopy of an VUV-irradiated triphenylene:water ice mixture is discussed, monitoring the ionization efficiency of PAHs in interstellar ice environments. The third and final example investigates the stability of solid glycine upon VUV irradiation by monitoring the formation of dissociation products in real time.

Fifteen Years of Laboratory Astrophysics at Ames

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.; Salama, F.; Hudgins, D. M.; Bernstein, M.; Goorvitch, David (Technical Monitor)

1998-01-01

Tremendous strides have been made in our understanding of interstellar material over the past fifteen years thanks to significant, parallel developments in two closely related areas: observational astronomy and laboratory astrophysics. Fifteen years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon-rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In the dense ISM, these cold dust particles are coated with mixed-molecular ices whose compositions are very well known. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the ISM. This great progress has only been made possible by the close collaboration of laboratory experimentalists with observers and theoreticians, all with the goal of applying their skills to astrophysical problems of direct interest to NASA programs. Such highly interdisciplinary collaborations ensure fundamental, in depth coverage of the wide-ranging challenges posed by astrophysics. These challenges include designing astrophysically focused experiments and data analysis, tightly coupled with astrophysical searches spanning 2 orders of magnitude in wavelength, and detailed theoretical modeling. The impact of our laboratory has been particularly effective as there is constant cross-talk and feedback between quantum theorists; theoretical astrophysicists and chemists; experimental physicists; organic, physical and petroleum chemists; and infrared and UV/Vis astronomers. In this paper, two examples of the Ames Program will be given. We have been involved in identifying 9 out of the 14 interstellar pre-cometary ice species known, determined their abundances and the physical nature of the ice structure. Details on our ice work are given in the paper by Sandford et al. Our group is among the pioneers of the PAH model. We built the theoretical framework, participated in the observations and developed the experimental techniques needed to test the model. We demonstrated that the ubiquitous infrared emission spectrum associated with many interstellar objects can be matched by laboratory spectra of neutral and positively charged PAHs and that PAHs were excellent candidates for the diffuse interstellar band (DIB) carriers. See Salama et al. and Hudgins et al.

Laser Induced Fluorescence Spectroscopy of Neutral and Ionized Polycyclic Aromatic Hydrocarbons in the Cosmic Simulation Chamber

NASA Technical Reports Server (NTRS)

Bejaoui, Salma; Salama, Farid; Contreras, Cesar; Sciamma O'Brien, Ella; Foing, Bernard; Pascale, Ehrenfreund

2015-01-01

Polycyclic aromatic hydrocarbon (PAH) molecules are considered the best carriers to account for the ubiquitous infrared emission bands. PAHs have also been proposed as candidates to explain the diffuse interstellar bands (DIBs), a series of absorption features seen on the interstellar extinction curve and are plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments. Extensive efforts have been devoted over the past two decades to characterize the physical and chemical properties of PAH molecules and ions in space. Absorption spectra of PAH molecules and ions trapped in solid matrices have been compared to the DIBs. Absorption spectra of several cold, isolated gas-phase PAHs have also been measured under experimental conditions that mimic the interstellar conditions. The purpose of this study is to provide a new dimension to the existing spectroscopic database of neutral and single ionized PAHs that is largely based on absorption spectra by adding emission spectroscopy data. The measurements are based on the laser induced fluorescence (LIF) technique and are performed with the Pulsed Discharge Nozzle (PDN) of the COSmIC laboratory facility at NASA Ames laboratory. The PDN generates a plasma in a free supersonic jet expansion to simulate the physical and the chemical conditions in interstellar environments. We focus, here, on the fluorescence spectra of large neutral PAHs and their cations where there is a lack of fluorescence spectroscopy data. The astronomical implications of the data (e.g., ERE) are examined.

Simulation of Infrared Spectra of Carbonaceous Grains

NASA Astrophysics Data System (ADS)

Dadswell, G.; Duley, W. W.

1997-02-01

Random covalent network (RCN) theory is applied to describe the infrared spectroscopic properties of carbonaceous solids with compositions containing a mixture of aromatic, aliphatic, and diamond-like hydrocarbons. Application of this technique to carbonaceous dust is equivalent to the synthesis of solids whose structure and bonding satisfy stoicheometry while minimizing strain energy. The result involves a range of compositions compatible with carbon bonding and the hydrogen concentration incorporated in the network. In general, only a limited range of compositions is available rather than the infinite number of possible compositions expected without the inclusion of these constraints. When compositions have been defined in this way, infrared spectra may be synthesized for comparison with astronomical spectra of interstellar carbonaceous solids. Such spectra contain components corresponding to absorption by CHn groups in which n = 1-3. We find, however, that additional spectral features, not included in our simple chemical model, must be present also in dust. We give plots of such spectra in the 3100-2800 cm-1 (3.2-3.6 μm) region for comparison with infrared spectra of interstellar dust. We have also developed an RCN formalism that incorporates oxygen into the carbon network as OH groups, and we show that this inclusion introduces a strong additional absorption band in the 3300 cm-1 (3.0 μm) region.

Hydrogen-deuterium substitution in solid ethanol by surface reactions at low temperatures

NASA Astrophysics Data System (ADS)

Oba, Yasuhiro; Osaka, Kazuya; Chigai, Takeshi; Kouchi, Akira; Watanabe, Naoki

2016-10-01

Ethanol (CH3CH2OH) is one of the most abundant complex organic molecules in star-forming regions. Despite its detection in the gas phase only, ethanol is believed to be formed by low-temperature grain-surface reactions. Methanol, the simplest alcohol, has been a target for observational, experimental, and theoretical studies in view of its deuterium enrichment in the interstellar medium; however, the deuterium chemistry of ethanol has not yet been an area of focus. Recently, deuterated dimethyl ether, a structural isomer of ethanol, was found in star-forming regions, indicating that deuterated ethanol can also be present in those environments. In this study, we performed laboratory experiments on the deuterium fractionation of solid ethanol at low temperatures through a reaction with deuterium (D) atoms at 10 K. Hydrogen (H)-D substitution, which increases the deuteration level, was found to occur on the ethyl group but not on the hydroxyl group. In addition, when deuterated ethanol (e.g. CD3CD2OD) solid was exposed to H atoms at 10 K, D-H substitution that reduced the deuteration level occurred on the ethyl group. Based on the results, it is likely that deuterated ethanol is present even under H-atom-dominant conditions in the interstellar medium.

Carbon atom clusters in random covalent networks: PAHs as an integral component of interstellar HAC

NASA Astrophysics Data System (ADS)

Jones, A. P.

1990-11-01

Using a random covalent network (RCN) model for the structure of hydrogenated amorphorous carbon (HAC) and the available laboratory data, it is shown that aromatic species are a natural consequence of the structure of amorphous carbons formed in the laboratory. Amorphous carbons in the interstellar medium are therefore likely to contain a significant fraction of Polycyclic aromatic hydrocarbons (PAH) species within the 'amorphous' matrix making up these materials. This aromatic component can be produced in situ during the accretion of gas phase carbon species on to grains in the interstellar medium under hydrogen-poor conditions, or subsequent to deposition as a result of photolysis (photodarkening). The fraction of interstellar carbon present in HAC in the form of PAHs, based upon a RCN model, is consistent with the observed Unidentified infrared (UIR) emission features.

Grain Spectroscopy

NASA Technical Reports Server (NTRS)

Allamandola, L. J.

1992-01-01

Our fundamental knowledge of interstellar grain composition has grown substantially during the past two decades thanks to significant advances in two areas: astronomical infrared spectroscopy and laboratory astrophysics. The opening of the mid-infrared, the spectral range from 4000-400 cm(sup -1) (2.5-25 microns), to spectroscopic study has been critical to this progress because spectroscopy in this region reveals more about a materials molecular composition and structure than any other physical property. Infrared spectra which are diagnostic of interstellar grain composition fall into two categories: absorption spectra of the dense and diffuse interstellar media, and emission spectra from UV-Vis rich dusty regions. The former will be presented in some detail, with the latter only very briefly mentioned. This paper summarized what we have learned from these spectra and presents 'doorway' references into the literature. Detailed reviews of many aspects of interstellar dust are given.

The Interstellar Ethics of Self-Replicating Probes

NASA Astrophysics Data System (ADS)

Cooper, K.

Robotic spacecraft have been our primary means of exploring the Universe for over 50 years. Should interstellar travel become reality it seems unlikely that humankind will stop using robotic probes. These probes will be able to replicate themselves ad infinitum by extracting raw materials from the space resources around them and reconfiguring them into replicas of themselves, using technology such as 3D printing. This will create a colonising wave of probes across the Galaxy. However, such probes could have negative as well as positive consequences and it is incumbent upon us to factor self-replicating probes into our interstellar philosophies and to take responsibility for their actions.

Nitrile versus isonitrile adsorption at interstellar grains surfaces. I. Hydroxylated surfaces

NASA Astrophysics Data System (ADS)

Bertin, M.; Doronin, M.; Fillion, J.-H.; Michaut, X.; Philippe, L.; Lattelais, M.; Markovits, A.; Pauzat, F.; Ellinger, Y.; Guillemin, J.-C.

2017-02-01

Context. Almost 20% of the 200 different species detected in the interstellar and circumstellar media present a carbon atom linked to nitrogen by a triple bond. Among these 37 molecules, 30 are nitrile R-CN compounds, the remaining seven belonging to the isonitrile R-NC family. How these species behave in presence of the grain surfaces is still an open question. Aims: In this contribution we investigate whether the difference between nitrile and isonitrile functional groups may induce differences in the adsorption energies of the related isomers at the surfaces of interstellar grains of different nature and morphologies. Methods: The question was addressed by means of a concerted experimental and theoretical study of the adsorption energies of CH3CN and CH3NC on the surface water ice and silica. The experimental determination of the molecule - surface interaction energies was carried out using temperature programmed desorption (TPD) under an ultra-high vacuum (UHV) between 70 and 160 K. Theoretically, the question was addressed using first principle periodic density functional theory (DFT) to represent the organized solid support. Results: The most stable isomer (CH3CN) interacts more efficiently with the solid support than the higher energy isomer (CH3NC) for water ice and silica. Comparing with the HCN and HNC pair of isomers, the simulations show an opposite behaviour, in which isonitrile HNC are more strongly adsorbed than nitrile HCN provided that hydrogen bonds are compatible with the nature of the model surface. Conclusions: The present study confirms that the strength of the molecule surface interaction between isomers is not related to their intrinsic stability but instead to their respective ability to generate different types of hydrogen bonds. Coupling TPD to first principle simulations is a powerful method for investigating the possible role of interstellar surfaces in the release of organic species from grains, depending on the environment.

"CHON" particles: The interstellar component of cometary dust

NASA Technical Reports Server (NTRS)

Lien, David J.

1998-01-01

Interstellar dust is characterized by strong absorption in the ultraviolet and the mid-IR. Current models of interstellar dust are based on three chemically distinct components: a form of carbon (usually graphite), a silicate, and a blend of polycyclic aromatic hydrocarbons or other carbonaceous material. Previous work using effective medium theories to understand the optical properties of cometary dust suggested that an amalgam of materials could reproduce the observed interstellar and cometary dust features. Recently, Lawler and Brownlee (1992) re-analyzed the PIA and PUMA-1 data sets from the Giotto flyby of P/Halley and discovered that the so-called "CHON" particles were actually composed of a blend of carbon-bearing and silicon-bearing materials. Based on effective medium theories, the absorption spectrum of such a material would display the spectral features of each of the components - strong UV absorption from the carbonaceous component and strong absorption in the IR from the silicate component. To test this idea, vapor-deposited samples were created using two different deposition techniques: sputtering with an argon RF magnetron and deposition from an argon plasma torch. Two different compositions were tested: a blend of graphite and silica in a 7:1 ratio and an amalgam of materials whose approximate composition matches the "CHON"-silicate abundances for the uncompressed PIA data set of Lawler and Brownlee: graphite, iron oxide, magnesium oxide, ammonium sulfate, calcium carbonate, and silica in mass ratios of 6:4.3:4:2.2:1:9. The samples were finely ground and pressed into 2" diameter disks using a 40 ton press. In all, four different experiments were performed: one with each of the compositions (C:SiO and "CHON") in both the RF magnetron and the plasma torch chambers. The RF magnetron created a uniform dark thin film on the substrate surface, and the plasma torch created a coating of small (<100 micron) diameter grey particles. The spectra of all four samples show a strong, broad absorption feature at around 220 nm as well as a strong but narrower absorption peak near 10 microns. The RF magnetron sputtered samples showed some sub-structure in the UV, and the peak of the absorption was shifted toward longer wavelengths. The UV absorption in the plasma torch deposited samples have no sub-structure, and the peak absorption is very near 220 nm. Strong absorption near 9 microns is seen in the spectra from both sample preparation techniques, and is consistent with the IR spectra of some terrestrial silicates. Other features, particularly at 6.2 and 8.6 microns, are seen in the interstellar medium. A strong feature near 2 microns is due to absorbed water in the sample. Based on the results of these experiments, there is evidence that a material with a composition similar to that detected in "CHON" particles in the coma of P/Halley have a spectral signature which reproduces the main absorption features of interstellar dust. This suggests that the "CHON" particles could be the interstellar component of cometary dust.

Analysis of the Organic Matter in Interplanetary Dust Particles: Clues to the Organic Matter in Comets, Asteroids, and Interstellar Grains

NASA Technical Reports Server (NTRS)

Flynn, G. J.; Keller, L. P.

2003-01-01

Reflection spectroscopy suggests the C- , P-, and D-types of asteroids contain abundant carbon, but these Vis-nearIR spectra are featureless, providing no information on the type(s) of carbonaceous matter. Infrared spectroscopy demonstrates that organic carbon is a significant component in comets and as grains or grain coatings in the interstellar medium. Most of the interplanetary dust particles (IDPs) recovered from the Earth s stratosphere are believed to be fragments from asteroids or comets, thus characterization of the carbon in IDPs provides the opportunity to determine the type(s) and abundance of organic matter in asteroids and comets. Some IDPs exhibit isotopic excesses of D and N-15, indicating the presence of interstellar material. The characterization of the carbon in these IDPs, and particularly any carbon spatially associated with the isotopic anomalies, provides the opportunity to characterize interstellar organic matter.

Polycyclic Aromatic Hydrocarbons and Astrophysics: The State of the Pah Model and a Possible Tracer of Nitrogen in Carbon-Rich Dust

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; Allamandola, Louis J.

2003-01-01

Over the past fifteen years, thanks to significant, parallel advancements in observational, experimental, and theoretical techniques, tremendous strides have been made in our understanding of the role aromatic materials play in the interstellar medium (ISM). Twenty years ago, the possible existence of an abundant population of large, carbon-rich molecules in the ISM was unthinkable. Today, the unmistakable spectroscopic signatures of polycyclic aromatic hydrocarbon molecules (PAHs) - shockingly large molecules by the standards of traditional interstellar chemistry - are recognized throughout the Universe. In this paper, we will examine the current state of the interstellar PAH model and its utility as a diagnostic tool to derive insight into the nature of the interstellar PAH population. As an example of this application, we will examine the results of our recent spectroscopic studies of polycyclic aromatic nitrogen heterocycles (PANHs)-PAHs with an atom of nitrogen substituted into the aromatic skeleton-and discuss a possible tracer of such species amongst the interstellar PAH emission bands in the latest observational data.

Iron hydrides formation in interstellar clouds

NASA Astrophysics Data System (ADS)

Bar-Nun, A.; Pasternak, M.; Barrett, P. H.

1980-07-01

A recent Moessbauer study with Fe-57 in a solid hydrogen or hydrogen-argon matrix demonstrated the formation of an iron hydride molecule (FeH2) at 2.5-5 K. Following this and other studies, the possible existence of iron hydride molecules in interstellar clouds is proposed. In clouds, the iron hydrides FeH and FeH2 would be formed only on grains, by encounters of H atoms or H2 molecules with Fe atoms which are adsorbed on the grains. The other transition metals, Sc, Ti, V, Cr, Mn, Co, N, Cd and also Cu and Ca form hydrides of the type M-H, which could be responsible, at least in part, for the depletion of these metals in clouds.

GEMS and New Pre-Accretionally Irradiated RELICT Grains in Interplanetary Dust - The Plot Thickens

NASA Astrophysics Data System (ADS)

Bradley, J.

1995-09-01

The hypothesis that GEMS (glass with embedded metal and sulfides) in interplanetary dust particles (IDPs) might be the long-sought interstellar silicate grains is undergoing close scrutiny [1-3]. GEMS are proposed to be interstellar because: (a) they are abundant in cometary IDPs; (b) they were irradiated prior to incorporation into IDPs; (c) both their size distribution and Oamorphous silicate" microstructures are consistent with those of interstellar silicates; (d) they contain nanometer-sized (superparamagnetic) alpha-iron inclusions, which provides a simple explanation for the observed interstellar grain alignment and polarization [4,5]. Challenges to the GEMS hypothesis include the following: (a) GEMS may have formed and been irradiated in the solar nebula rather than a presolar interstellar environment; (b) non-solar isotope abundances have yet to be measured in GEMS; (c) the irradiation regime required to produce the observed effects in GEMS might be incompatible with the interstellar medium; (b) relationships between GEMS and carbon (e.g. core/mantle) need clarification; (c) major element abundances in GEMS should be consistent with observed interstellar gas phase depletions [2,3]. GEMS may indeed have formed in the solar nebula, in which case they would be the oldest known solar nebula solids [2]. An interstellar origin for GEMS does not require detection of non-solar isotope abundances [6]. Irradiation experiments are in progress to simulate the properties of GEMS. The petrographic relationship between GEMS and carbon in IDPs is being investigated (by examining IDPs embedded and thin-sectioned in carbon-free media). Major element abundances in GEMS are being evaluated in terms on interstellar gas phase abundances. For example, sulfur is not highly depleted in the interstellar gas, implying that it must be significantly depleted in interstellar grains [3]. GEMS are significantly depleted in sulfur relative to solar abundances. Analytical electron microscopic studies of the local petrographic environment of GEMS in IDPs are continuing. There is evidence of a population of relict grains associated with GEMS. Some of these relict grains have distinctive compositions and they appear to have functioned as (pre-existing) depositional substrates while GEMS were being formed. Thus, it may be possible to begin to assign a chronology to the seemingly complex admixture of grains that make up the ultrafine-grained matrices of anhydrous chondritic IDPs. References: [1] Bradley J. P. (1994) Science, 265, 925-929. [2] Flynn G. J. (1994) Nature, 371, 287-288. [3] Martin P. G. (1995) Astrophys. J., 445, L63-L66. [4] Mathis J. S. (1986) Astrophys. J., 308, 281-287. [5] Mathis J. S. (1993) Rept. Prog. Phys., 56, 605-652. [6] Walker R. M. (1994) in Analysis of Interplanetary Dust (M. E. Zolensky et al., eds.), pp. 203-209, AIP Conf. Proc. 310.

Spectroscopy of prospective interstellar ions and radicals isolated in para-hydrogen matrices.

PubMed

Tsuge, Masashi; Tseng, Chih-Yu; Lee, Yuan-Pern

2018-02-21

para-Hydrogen (p-H 2 ) serves as a new host in matrix-isolation experiments for an investigation of species of astrochemical interest. Protonated and mono-hydrogenated species are produced upon electron bombardment during deposition of p-H 2 containing a precursor in a small proportion. The applications of this novel technique to generate protonated polycyclic aromatic hydrocarbons (H + PAH), protonated polycyclic nitrogen heterocycles (H + PANH), and their neutral counterparts, which are important in the identification of interstellar unidentified infrared emission bands, demonstrate its superiority over other methods. The clean production with little fragmentation, ease of distinction between protonated and neutral species, narrow lines and reliable relative infrared intensities of the lines, and broad coverage of the spectral range associated with this method enable us to assign the isomers unambiguously. The application of this method to the protonation of small molecules is more complicated partly because of the feasible fragmentation and reactions, and partly because of the possible proton sharing between the species of interest and H 2 , but, with isotopic experiments and secondary photolysis, definitive assignments are practicable. Furthermore, the true relative infrared intensities are critical to a comparison of experimental results with data from theoretical calculations. The spectra of a proton-shared species in solid p-H 2 might provide insight into a search for spectra of proton-bound species in interstellar media. Investigations of hydrogenated species involving the photolysis of Cl 2 or precursors of OH complement those using electron bombardment and provide an improved ratio of signal to noise. With careful grouping of observed lines after secondary photolysis and a comparison with theoretical predictions, various isomers of these species have been determined. This photolytic technique has been applied in an investigation of hydrogenated PAH and PANH, and the hydrogenation reactions of small molecules, which are important in interstellar ice and the evolution of life. The electronic transitions of molecules in solid p-H 2 have been little investigated. The matrix shift of the origins of transitions and the spectral width seem to be much smaller than those of noble-gas matrices; these features might facilitate a direct comparison of matrix spectra with diffuse interstellar bands, but further data are required to assess this possibility. The advantages and disadvantages of applying these techniques of p-H 2 matrix isolation to astrochemical research and their future perspectives are discussed.

Stardust Interstellar Preliminary Examination X: Impact Speeds and Directions of Interstellar Grains on the Stardust Dust Collector

NASA Technical Reports Server (NTRS)

Sterken, Veerle J.; Westphal, Andrew J.; Altobelli, Nicolas; Grun, Eberhard; Hillier, Jon K.; Postberg, Frank; Allen, Carlton; Stroud, Rhonda M.; Sandford, S. A.; Zolensky, Michael E.

2014-01-01

On the basis of an interstellar dust model compatible with Ulysses and Galileo observations, we calculate and predict the trajectories of interstellar dust (ISD) in the solar system and the distribution of the impact speeds, directions, and flux of ISD particles on the Stardust Interstellar Dust Collector during the two collection periods of the mission. We find that the expected impact velocities are generally low (less than 10 km per second) for particles with the ratio of the solar radiation pressure force to the solar gravitational force beta greater than 1, and that some of the particles will impact on the cometary side of the collector. If we assume astronomical silicates for particle material and a density of 2 grams per cubic centimeter, and use the Ulysses measurements and the ISD trajectory simulations, we conclude that the total number of (detectable) captured ISD particles may be on the order of 50. In companion papers in this volume, we report the discovery of three interstellar dust candidates in the Stardust aerogel tiles. The impact directions and speeds of these candidates are consistent with those calculated from our ISD propagation model, within the uncertainties of the model and of the observations.

ON THE INTERACTION OF ADENINE WITH IONIZING RADIATION: MECHANISTICAL STUDIES AND ASTROBIOLOGICAL IMPLICATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Evans, Nicholas L.; Ullrich, Susanne; Bennett, Chris J.

2011-04-01

The molecular inventory available on the prebiotic Earth was likely derived from both terrestrial and extraterrestrial sources. A complete description of which extraterrestrial molecules may have seeded early Earth is therefore necessary to fully understand the prebiotic evolution which led to life. Galactic cosmic rays (GCRs) are expected to cause both the formation and destruction of important biomolecules-including nucleic acid bases such as adenine-in the interstellar medium within the ices condensed on interstellar grains. The interstellar ultraviolet (UV) component is expected to photochemically degrade gas-phase adenine on a short timescale of only several years. However, the destruction rate is expectedmore » to be significantly reduced when adenine is shielded in dense molecular clouds or even within the ices of interstellar grains. Here, biomolecule destruction by the energetic charged particle component of the GCR becomes important as it is not fully attenuated. Presented here are results on the destruction rate of the nucleobase adenine in the solid state at 10 K by energetic electrons, as generated in the track of cosmic ray particles as they penetrate ices. When both UV and energetic charged particle destructive processes are taken into account, the half-life of adenine within dense interstellar clouds is found to be {approx}6 Myr, which is on the order of a star-forming molecular cloud. We also discuss chemical reaction pathways within the ices to explain the production of observed species, including the formation of nitriles (R-C{identical_to}N), epoxides (C-O-C), and carbonyl functions (R-C=O).« less

Physical Conditions in Shocked Interstellar Gas Interacting with the Supernova Remnant IC 443

NASA Astrophysics Data System (ADS)

Ritchey, Adam M.; Federman, Steven Robert; Jenkins, Edward B.; Caprioli, Damiano; Wallerstein, George

2018-06-01

We present the results of a detailed investigation into the physical conditions in interstellar material interacting with the supernova remnant IC 443. Our analysis is based on an examination of high-resolution HST/STIS spectra of two stars probing predominantly neutral gas located both ahead of and behind the supernova shock front. The pre-shock neutral gas is characterized by densities and temperatures typical of diffuse interstellar clouds, while the post-shock material exhibits a range of more extreme physical conditions, including high temperatures (>104 K) in some cases, which may require a sudden heating event to explain. The ionization level is enhanced in the high-temperature post-shock material, which could be the result of enhanced radiation from shocks or from an increase in cosmic-ray ionization. The gas-phase abundances of refractory elements are also enhanced in the high-pressure gas, suggesting efficient destruction of dust grains by shock sputtering. Observations of highly-ionized species at very high velocity indicate a post-shock temperature of 107 K for the hot X-ray emitting plasma of the remnant’s interior, in agreement with studies of thermal X-ray emission from IC 443.

Near-infrared absorption spectroscopy of interstellar hydrocarbon grains

NASA Astrophysics Data System (ADS)

Pendleton, Y. J.; Sandford, S. A.; Allamandola, L. J.; Tielens, A. G. G. M.; Sellgren, K.

1994-12-01

We present new 3600 - 2700/cm (2.8 - 3.7 micrometer) spectra of objects whose extinction is dominated by dust in the diffuse interstellar medium. The observations presented here augment an ongoing study of the organic component of the diffuse interstellar medium. These spectra contain a broad feature centered near 3300/cm (3.0 micrometers) and/or a feature with a more complex profile near 2950/cm (3.4 micrometers), the latter of which is attributed to saturated aliphatic hydrocarbons in interstellar grains and is the primary interest of this paper. As in our earlier work, the similarity of the absorption bands near 2950/cm (3.4 micrometers) along different lines of sight and the correlation of these features with interstellar extinction reveal that the carrier of this band lies in the dust in the diffuse interstellar medium (DISM). At least 2.5% of the cosmic carbon in the local interstellar medium and 4% toward the Galactic center is tied up in the carrier of the 2950/cm (3.4 micrometer) band. The spectral structure of the diffuse dust hydrocarbon C-H stretch absorption features is reasonably similar to UV photolyzed laboratory ice residues and is quite similar to the carbonaceous component of the Murchison meteorite. The similarity between the DISM and the meteoritic spectrum suggests that some of the interstellar material originally incorporated into the solar nebula may have survived relatively untouched in primitive solar system bodies. Comparisons of the DISM spectrum to hydrogenated amorphous carbon and quenched carbonaceous composite are also presented. The AV/tau ratio for the 2950/cm (3.4 micrometer) feature is lower toward the Galactic center than toward sources in the local solar neighborhood (approximately 150 for the Galactic center sources vs. approximately 250 for the local ISM sources). A similar trend has been observed previously for silicates in the diffuse medium by Roche & Aitken, suggesting that (1) the silicate and carbonaceous materials in the DISM may be physically correlated and (2) there is either dust compositional variation in the galaxy or galactic variation in the grain population density distribution. We also note a possible absorption feature near 3050/cm (3.28 micrometers), a wavelength position that is characteristic of polycyclic aromatic hydrocarbons (PAHs).

Near-infrared absorption spectroscopy of interstellar hydrocarbon grains

NASA Technical Reports Server (NTRS)

Pendleton, Y. J.; Sandford, S. A.; Allamandola, L. J.; Tielens, A. G. G. M.; Sellgren, K.

1994-01-01

We present new 3600 - 2700/cm (2.8 - 3.7 micrometer) spectra of objects whose extinction is dominated by dust in the diffuse interstellar medium. The observations presented here augment an ongoing study of the organic component of the diffuse interstellar medium. These spectra contain a broad feature centered near 3300/cm (3.0 micrometers) and/or a feature with a more complex profile near 2950/cm (3.4 micrometers), the latter of which is attributed to saturated aliphatic hydrocarbons in interstellar grains and is the primary interest of this paper. As in our earlier work, the similarity of the absorption bands near 2950/cm (3.4 micrometers) along different lines of sight and the correlation of these features with interstellar extinction reveal that the carrier of this band lies in the dust in the diffuse interstellar medium (DISM). At least 2.5% of the cosmic carbon in the local interstellar medium and 4% toward the Galactic center is tied up in the carrier of the 2950/cm (3.4 micrometer) band. The spectral structure of the diffuse dust hydrocarbon C-H stretch absorption features is reasonably similar to UV photolyzed laboratory ice residues and is quite similar to the carbonaceous component of the Murchison meteorite. The similarity between the DISM and the meteoritic spectrum suggests that some of the interstellar material originally incorporated into the solar nebula may have survived relatively untouched in primitive solar system bodies. Comparisons of the DISM spectrum to hydrogenated amorphous carbon and quenched carbonaceous composite are also presented. The A(sub V)/tau ratio for the 2950/cm (3.4 micrometer) feature is lower toward the Galactic center than toward sources in the local solar neighborhood (approximately 150 for the Galactic center sources vs. approximately 250 for the local ISM sources). A similar trend has been observed previously for silicates in the diffuse medium by Roche & Aitken, suggesting that (1) the silicate and carbonaceous materials in the DISM may be physically correlated and (2) there is either dust compositional variation in the galaxy or galactic variation in the grain population density distribution. We also note a possible absorption feature near 3050/cm (3.28 micrometers), a wavelength position that is characteristic of polycyclic aromatic hydrocarbons (PAHs).

HYDROCARBON MATERIALS OF LIKELY INTERSTELLAR ORIGIN FROM THE PARIS METEORITE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Merouane, S.; Djouadi, Z.; D'Hendecourt, L. Le Sergeant

2012-09-10

We have examined some grains from the Paris meteorite through infrared and Raman micro-spectroscopy in order to investigate their carbonaceous and mineralogical components. In the mid- as well as far-infrared regions, the raw and global spectra of Paris resemble those of CM meteorites. However, we have obtained rather peculiar infrared spectra for some aromatic-rich micron-sized fragments of Paris displaying a very good match between its organic signatures both in the 3.4 {mu}m and 6 {mu}m regions, and the ones observed from the diffuse interstellar medium infrared sources toward the Galactic center, suggesting that this meteorite may have indeed preserved somemore » organic matter of interstellar origin.« less

Probing the 9.7 μm Interstellar Silicate Extinction Profile through the Spitzer/IRS Spectroscopy of OB Stars

NASA Astrophysics Data System (ADS)

Shao, Zhenzhen; Jiang, B. W.; Li, Aigen; Gao, Jian; Lv, Zhangpan; Yao, Jiawen

2018-05-01

The 9.7 μm interstellar spectral feature, arising from the Si-O stretch of amorphous silicate dust, is the strongest extinction feature in the infrared (IR). In principle, the spectral profile of this feature could allow one to diagnose the mineralogical composition of interstellar silicate material. However, observationally, the 9.7 μm interstellar silicate extinction profile is not well determined. Here we utilize the Spitzer/IRS spectra of five early-type (one O- and four B-type) stars and compare them with that of unreddened stars of the same spectral type to probe the interstellar extinction of silicate dust around 9.7 μm. We find that, while the silicate extinction profiles all peak at ˜ 9.7 μm, two stars exhibit a narrow feature of FWHM ˜ 2.0 μm and three stars display a broad feature of FWHM ˜ 3.0 μm. We also find that the width of the 9.7 μm extinction feature does not show any environmental dependence. With a FWHM of ˜ 2.2 μm, the mean 9.7 μm extinction profile, obtained by averaging over our five stars, closely resembles that of the prototypical diffuse interstellar medium along the lines of sight toward Cyg OB2 No. 12 and WR 98a. Finally, an analytical formula is presented to parameterize the interstellar extinction in the IR at 0.9 μm ≲ λ ≲ 15 μm.

Ion Irradiation of H2-Laden Porous Water-ice Films: Implications for Interstellar Ices

NASA Astrophysics Data System (ADS)

Raut, U.; Mitchell, E. H.; Baragiola, R. A.

2015-10-01

To understand the effects of cosmic-ray (CR) impacts on interstellar icy grains immersed in H2 gas, we have irradiated porous water-ice films loaded with H2 with 100 keV H+. The ice films were exposed to H2 gas at different pressures following deposition and during irradiation. A net H2 loss is observed during irradiation due to competition between ion-induced sputtering and gas adsorption. The initial H2 loss cross-section, 4(1) × 10-14 cm2, was independent of film thickness, H2, and proton fluxes. In addition to sputtering, irradiation also closes nanopores, trapping H2 in the film with binding that exceeds physical absorption energies. As a result, 2%-7% H2 is retained in the ice following irradiation to high fluences. We find that the trapped H2 concentration increases with decreasing Φ, the ratio of ion to H2 fluxes, suggesting that as high as 8% solid H2 can be trapped in interstellar ice by CR or stellar wind impacts.

Photodesorption of Solid CO2 by Lyα

NASA Astrophysics Data System (ADS)

Bahr, D. A.; Baragiola, R. A.

2012-12-01

We measured desorption of atoms and molecules from films of solid carbon dioxide in an ultrahigh vacuum from 6 to 60 K under irradiation with Lyα (121.6 nm, 10.2 eV) photons, an important process in the balance between gas phase and condensed molecules in the interstellar medium. The measurements use microgravimetry and mass spectrometry during irradiation and temperature programmed desorption after irradiation. At low photon fluences, the desorption flux consists mainly of O atoms and, after ~1017 photons cm-2, it is dominated by CO with smaller amount of O2, C, and CO2, with the presence of O2 indicating solid-state chemical reactions. At high fluences (up to 1018 photons cm-2), the desorption yields saturate at values much higher than in previous studies. The yields (molecules/photon), derived assuming stoichiometric desorption, reach 0.014 at 6 K, growing to ~0.2 at 50 and 60 K. Warming the films during irradiation gives rise to pressure spikes that suggest desorption of trapped species in pores or at defects, possibly assisted by radical-induced reactions. Such an effect could be significant for radiation-processed CO2-coated interstellar grains that are heated by, i.e., cosmic ray impacts or grain-grain collisions. We discuss the experiments considering photochemical mechanisms and compare them to the results of ion irradiation.

Infrared observations and laboratory simulations of interstellar CH_4_ and SO_2_.

NASA Astrophysics Data System (ADS)

Boogert, A. C. A.; Schutte, W. A.; Helmich, F. P.; Tielens, A. G. G. M.; Wooden, D. H.

1997-02-01

Interstellar CH_4_ may consume a fair amount of the carbon budget in dense molecular clouds, but probably less than CO, CH_3_OH, and CO_2_. However, it can only be observed at wavelength regions in the infrared that are heavily affected by the earth atmosphere. With new space and airborne missions (e.g. ISO, SOFIA) in mind we have studied the near infrared absorption spectra of solid and gaseous CH_4_. We obtained laboratory spectra of the ν_4_ deformation mode (1302cm^-1^, 7.68μm) of solid CH_4_ in astrophysically relevant mixtures. We found that the peak position and width of this absorption band vary strongly as a function of molecular environment, compared to temperature and particle shape effects. Hence, observations of this feature will provide a powerful probe of the molecular composition of interstellar ices. Also the gas phase CH_4_ ro-vibrational spectrum of the same band has been calculated. Using observed physical conditions around the protostar W 33A, we show that unresolved gaseous CH_4_ lines are detectable (at the 2-5% level) at a resolution R>1000, when the column density N>=10^16^ cm^-2^. An astrophysically relevant molecule with a very strong transition in the same wavelength regime, is SO_2_. We studied the ν _3_ asymmetric stretching mode (1319 cm^-1^, 7.58 μm) of solid SO_2_ in several mixtures, revealing that the peak position, width and detailed profile of this band are very sensitive to the molecular environment. Besides probing the composition of ice mantles, observations of solid SO_2_ will provide important information on the sulfur budget locked up in grain mantles, which is currently poorly known. We compare the laboratory and calculated spectra of CH_4_ and SO_2_ with previously published ground based spectra and new airborne observations of young stellar objects in the 7-8μm region. W 33A, NGC 7538 : IRS1 and IRS9 show a feature near 7.68μm that is consistent with absorption by solid CH_4_ or the Q-branch of gaseous CH_4_. The column density of solid CH_4_ would be 0.3-4% of solid H_2_O, indicating that solid CH_4_ consumes 0.5+/-0.3% of the cosmic carbon abundance. A gaseous origin would imply a column density of at least this amount, being highly dependent on the assumed temperature of the absorbing gas. A second absorption feature is detected toward W 33A and NGC 7538 : IRS1 at 7.58 μm. The peak position and width of this feature are consistent with the ν_3_ mode of solid SO_2_ in a matrix of solid CH_3_OH or pure SO_2_. The derived column density is 0.1-1% of solid H_2_O, indicating that solid SO_2_ locks up 0.6-6% of the cosmic sulfur abundance. This study shows that 7-8μm spectroscopy of dense molecular clouds, using new airborne and space-based platforms, will provide valuable information on the composition of icy grain mantles and molecular cloud chemistry.

A speckle hologram of the interstellar plasma

NASA Technical Reports Server (NTRS)

Desai, K. M.; Gwinn, C. R.; Reynolds, J.; King, E. A.; Jauncey, D.; Flanagan, C.; Nicolson, G.; Preston, R. A.; Jones, D. L.

1992-01-01

Observations of a speckle hologram of scattering material along the line of sight to the Vela pulsar indicate that this material is concentrated in the Vela supernova remnant, deep within the Gum Nebula. The speckle hologram is observed through the amplitude and phase variations of the interferometric cross-power spectrum with time and frequency. These variations describe the density fluctuations of the interstellar plasma, in a holographic fashion. The decorrelation due to the phase variations of the speckles yields the angular size of the scattering disk; comparison with the bandwidth of their amplitude variations yields a characteristic distance from earth to the scattering material of 0.81 +/- 0.03 of the distance from earth to the pulsar. This result is consistent with theories of irregularities associated with particle acceleration in shocks in supernova remnants.

Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices

NASA Technical Reports Server (NTRS)

Wdowiak, Thomas J.; Robinson, Edward L.; Flickinger, Gregory C.; Boyd, David A.

1989-01-01

During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.

Simulating STARDUST: Reproducing Impacts of Interstellar Dust in the Laboratory

NASA Astrophysics Data System (ADS)

Postberg, F.; Srama, R.; Hillier, J. K.; Sestak, S.; Green, S. F.; Trieloff, M.; Grün, E.

2008-09-01

Our experiments are carried out to support the analysis of interstellar dust grains, ISDGs, brought to earth by the STARDUST mission. Since the very first investigations, it has turned out that the major problem of STARDUST particle analysis is the modification (partly even the destruction) during capture when particles impact the spacecraft collectors with a velocity of up to 20 km/s. While it is possible to identify, extract, and analyse cometary grains larger than a few microns in aerogel and on metal collector plates, the STARDUST team is not yet ready for the identification, extraction, and analysis of sub-micron sized ISDGs with impact speeds of up to 20 km/s. Reconstructing the original particle properties requires a simulation of this impact capture process. Moreover, due to the lack of laboratory studies of high speed impacts of micron scale dust into interstellar STARDUST flight spares, the selection of criteria for the identification of track candidates is entirely subjective. Simulation of such impact processes is attempted with funds of the FRONTIER program within the framework of the Heidelberg University initiative of excellence. The dust accelerator at the MPI Kernphysik is a facility unique in the world to perform such experiments. A critical point is the production of cometary and interstellar dust analogue material and its acceleration to very high speeds of 20 km/s, which has never before been performed in laboratory experiments. Up to now only conductive material was successfully accelerated by the 2 MV Van de Graaf generator of the dust accelerator facility. Typical projectile materials are Iron, Aluminium, Carbon, Copper, Silver, and the conducting hydrocarbon Latex. Ongoing research now enables the acceleration of any kind of rocky planetary and interstellar dust analogues (Hillier et al. 2008, in prep.). The first batch of dust samples produced with the new method consists of micron and submicron SiO2 grains. Those were successfully accelerated and provided impacts with speeds of over 20 km/s. Impact signals as well as high resolution impact ionisation mass spectra - which reflect the grain's composition - were evaluated. Thus, the tests allow studying of dynamic properties as well as a compositional analysis of the grains. The next step - the production and testing of meteoritic dust material - is already in progress. On basis of our successful experiments, we will comprehensively analyse and compare (in cooperation with the STARDUST team) both the initial starting material and the impact modified material, either captured by aerogel or metal foils, as well as the particle-target interaction along capture tracks. These experiments will be performed on a variety of possible starting materials, with varying major, minor and trace elements. The investigations will allow to reconstruct the initial particle mass, speed, chemical and mineralogical composition of particles before capture, with important implications for the nature of interstellar matter and early solar system processes. Furthermore, the impact spectra we obtain from our in-situ dust analyser with the same projectiles will be included in a data base for comparison with spectra obtained by the dust analyser CIDA onboard the STARDUST spacecraft.

Complex Organic Materials on Planetary Satellites and Other Small Bodies of the Solar System

NASA Technical Reports Server (NTRS)

Cruikshank, Dale P.

2006-01-01

The search for organic materials on small bodies of the Solar System is conducted spectroscopically from Earth-based telescopes and from spacecraft. Although the carbonaceous meteorites carry a significant inventory of complex organic solids, the sources of these meteorites have not been identified. Infrared spectra of a sample of the suspected sources, the C- and D-class asteroids, including new data from the Spitzer Space Telescope, show signatures of silicates, but none diagnostic of organic compounds. In the absence of discrete spectral features, the low albedos and colors in the visible and near-IR spectral regions are the principal links between the organic-bearing meteorites and the asteroids. While Pluto and a few trans-neptunian objects show spectral signatures of frozen CH4. Solid CH3OH has been identified on two Centaur objects in the outer Solar System. In some cases the red colors of those objects suggest the presence of tholins. The VIMS instrument aboard the Cassini spacecraft in orbit around Saturn has detected near-IR spectral features on at least three of Saturn's satellites that are indicative or suggestive of organic molecules. One entire hemisphere of the satellite Iapetus is covered with low-albedo material that shows a spectral signature of aromatic hydrocarbons (3.3 microns) and the -CH2 stretching mode bands of an aliphatic component. Organics absorbing at 3.44 microns are suspected in the region of the south pole of Enceladus, and also on the surface of Phoebe. Organic material may originate on icy bodies in the current epoch by various processes of energy deposition into native material, or they may fall to the surface from an external (probably cometary) source. Some organic material may be pre-solar, having originated in the interstellar medium before the formation of the Solar System. Using the techniques of remote sensing, its detection and analysis are slow and difficult.

The Origins of Polycyclic Aromatic Hydrocarbons: Are They Everywhere?

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Morrison, David (Technical Monitor)

1994-01-01

During the past 15 years considerable progress in observational techniques has been achieved in the middle-infrared region (5000-500 per centimeter, 2-20 micron), the region where most diagnostic molecular vibrations occur. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds and others at their edges, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas and solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. The two lectures will focus on the evidence that polycyclic aromatic hydrocarbons (PAHs) are an important, ubiquitous and abundant interstellar species. PAHs are. extremely stable species which can range in size from a few angstroms across to several hundred angstroms (PAHs are also the building blocks of amorphous carbon particles). This identification rests on the suggestive agreement between the laboratory spectra of PAHs with a set of IR emission bands which emanate from many different sources where ultraviolet starlight impinges on a "dusty" region. The picture is that individual PAHs are first pumped into highly vibrationally excited states and relax by fluorescence at their fundamental vibrational frequencies. That PAHs are a ubiquitous interstellar component has serious ramifications in other spectral regions as well, including the strong extinction in the ultraviolet, and the classic visible diffuse interstellar bands discovered more than 50 years ago (but unexplained to this day) The first part of the course will focus on the interpretation of astronomical spectra. The second lecture will start by showing how recent laboratory data on PAHs taken under realistic interstellar conditions has con borated the PAH hypothesis and led to great insight into the conditions in the PAH containing regions. This lecture will end by reviewing the ever-increasing evidence for interstellar PAHs in meteorites and interplanetary dust particles. This in conjunction with the recent suggestion that PAHs are abundant in Jupiter's atmosphere will make the point that "PAHs are Everywhere".

The Ultimate Destination: Choice of Interplanetary Exploration Path can define Future of Interstellar Spaceflight

NASA Astrophysics Data System (ADS)

Silin, D. V.

Manned interstellar spaceflight is facing multiple challenges of great magnitude; among them are extremely large distances and the lack of known habitable planets other than Earth. Many of these challenges are applicable to manned space exploration within the Solar System to the same or lesser degree. If these issues are resolved on an interplanetary scale, better position to pursue interstellar exploration can be reached. However, very little progress (if any) was achieved in manned space exploration since the end of Space Race. There is no lack of proposed missions, but all of them require considerable technological and financial efforts to implement while yielding no tangible benefits that would justify their costs. To overcome this obstacle highest priority in future space exploration plans should be assigned to the creation of added value in outer space. This goal can be reached if reductions in space transportation, construction and maintenance of space-based structures costs are achieved. In order to achieve these requirements several key technologies have to be mastered, such as near-Earth object mining, space- based manufacturing, agriculture and structure assembly. To keep cost and difficulty under control next exploration steps can be limited to nearby destinations such as geostationary orbit, low lunar orbit, Moon surface and Sun-Earth L1 vicinity. Completion of such a program will create a solid foundation for further exploration and colonization of the Solar System, solve common challenges of interplanetary and interstellar spaceflight and create useful results for the majority of human population. Another important result is that perception of suitable destinations for interstellar missions will change significantly. If it becomes possible to create habitable and self-sufficient artificial environments in the nearby interplanetary space, Earth-like habitable planets will be no longer required to expand beyond our Solar System. Large fraction of the stars in the observable Universe will become valid targets for interstellar missions.

Interstellar Alcohols

NASA Technical Reports Server (NTRS)

Charnley, S. B.; Kress, M. E.; Tielens, A. G. G. M.; Millar, T. J.

1995-01-01

We have investigated the gas-phase chemistry in dense cores where ice mantles containing ethanol and other alcohols have been evaporated. Model calculations show that methanol, ethanol, propanol, and butanol drive a chemistry leading to the formation of several large ethers and esters. Of these molecules, methyl ethyl ether (CH3OC2H5) and diethyl ether (C2H5)2O attain the highest abundances and should be present in detectable quantities within cores rich in ethanol and methanol. Gas-phase reactions act to destroy evaporated ethanol and a low observed abundance of gas-phase C,H,OH does not rule out a high solid-phase abundance. Grain surface formation mechanisms and other possible gas-phase reactions driven by alcohols are discussed, as are observing strategies for the detection of these large interstellar molecules.

Formation of cyanoallene (buta-2, 3-dienenitrile) in the interstellar medium: a quantum chemical and spectroscopic study

NASA Astrophysics Data System (ADS)

Singh, Amresh; Shivani; Misra, Alka; Tandon, Poonam

2014-03-01

The interstellar medium, filling the vast space between stars, is a rich reservoir of molecular material ranging from simple diatomic molecules to more complex, astrobiologically important molecules such as vinylcyanide, methylcyanodiaccetylene, cyanoallene, etc. Interstellar molecular cyanoallene is one of the most stable isomers of methylcynoacetylene. An attempt has been made to explore the possibility of forming cyanoallene in interstellar space by radical-radical and radical-molecule interaction schemes in the gaseous phase. The formation of cyanoallene starting from some simple, neutral interstellar molecules and radicals has been studied using density functional theory. The reaction energies and structures of the reactants and products show that the formation of cyanoallene is possible in the gaseous phase. Both of the considered reaction paths are totally exothermic and barrierless, thus giving rise to a high probability of occurrence. Rate constants for each step in the formation process of cyanoallene in both the reaction paths are estimated. A full vibrational analysis has been attempted for cyanoallene in the harmonic and anharmonic approximations. Anharmonic spectroscopic parameters such as rotational constants, rotation-vibration coupling constants and centrifugal distortion constants have been calculated.

Optical observations of nearby interstellar gas

NASA Astrophysics Data System (ADS)

Frisch, P. C.; York, D. G.

1984-11-01

Observations indicated that a cloud with a heliocentric velocity of approximately -28 km/s and a hydrogen column density that possibly could be on the order of, or greater than, 5 x 10 to the 19 power/square cm is located within the nearest 50 to 80 parsecs in the direction of Ophiuchus. This is a surprisingly large column density of material for this distance range. The patchy nature of the absorption from the cloud indicates that it may not be a feature with uniform properties, but rather one with small scale structure which includes local enhancements in the column density. This cloud is probably associated with the interstellar cloud at about the same velocity in front of the 20 parsec distant star alpha Oph (Frisch 1981, Crutcher 1982), and the weak interstellar polarization found in stars as near as 35 parsecs in this general region (Tinbergen 1982). These data also indicate that some portion of the -14 km/s cloud also must lie within the 100 parsec region. Similar observations of both Na1 and Ca2 interstellar absorption features were performed in other lines of sight. Similar interstellar absorption features were found in a dozen stars between 20 and 100 parsecs of the Sun.

Optical Observations of Nearby Interstellar Gas

NASA Technical Reports Server (NTRS)

Frisch, P. C.; York, D. G.

1984-01-01

Observations indicated that a cloud with a heliocentric velocity of approximately -28 km/s and a hydrogen column density that possibly could be on the order of, or greater than, 5 x 10 to the 19 power/square cm is located within the nearest 50 to 80 parsecs in the direction of Ophiuchus. This is a surprisingly large column density of material for this distance range. The patchy nature of the absorption from the cloud indicates that it may not be a feature with uniform properties, but rather one with small scale structure which includes local enhancements in the column density. This cloud is probably associated with the interstellar cloud at about the same velocity in front of the 20 parsec distant star alpha Oph (Frisch 1981, Crutcher 1982), and the weak interstellar polarization found in stars as near as 35 parsecs in this general region (Tinbergen 1982). These data also indicate that some portion of the -14 km/s cloud also must lie within the 100 parsec region. Similar observations of both Na1 and Ca2 interstellar absorption features were performed in other lines of sight. Similar interstellar absorption features were found in a dozen stars between 20 and 100 parsecs of the Sun.

Final Reports of the Stardust ISPE: Seven Probable Interstellar Dust Particles

NASA Technical Reports Server (NTRS)

Allen, Carlton; Sans Tresseras, Juan-Angel; Westphal, Andrew J.; Stroud, Rhonda M.; Bechtel, Hans A.; Brenker, Frank E.; Butterworth, Anna L.; Flynn, George J.; Frank, David R.; Gainsforth, Zack;

The Properties of the local Interstellar Medium and the Interaction of the Stellar Winds of epsilon Indi and lambda Andromedae with the Interstellar Environment

NASA Technical Reports Server (NTRS)

Wood, Brian E.; Alexander, William R.; Linsky, Jeffrey L.

1996-01-01

We present new observations of the Ly alpha lines of Epsilon Indi (K5 5) and A Andromedae (G8 4-3 + ?) These data were obtained by the Goddard High Resolution Spectrograph (GHRS) on the Hubble Space Telescope. Analysis of the interstellar H 1 and D 1 absorption lines reveals that the velocities and temperatures inferred from the H 1 lines are inconsistent with the parameters inferred from the D 1 lines, unless the H 1 absorption is assumed to be produced by two absorption components. One absorption component is produced by interstellar material. For both lines of sight observed, the velocity of this component is consistent with the velocity predicted by the local flow vector. For the Epsilon Indi data, the large velocity separation between the stellar emission and the interstellar absorption allows us to measure the H 1 column density independent of the shape of the intrinsic stellar Ly alpha profile. This approach permits us to quote an accurate column density and to assess its uncertainty with far more confidence than in previous analyses, for which the errors were dominated by uncertainties in the assumed stellar profiles.

Changes in interstellar atomic abundances from the galactic plane to the halo

NASA Technical Reports Server (NTRS)

Jenkins, E. B.

1982-01-01

A few, specially selected interstellar absorption lines were measured in the high resolution, far ultraviolet spectra of 200 O and B type stars observed by the International Ultraviolet Explorer (IUE). For lines of sight extending beyond about 500 pc from the galactic plane, the abundance of singly ionized iron atoms increases relative to singly ionized sulfur. However, the relative abundances of singly ionized sulfur, silicon and aluminum do not seem to change appreciably. An explanation for the apparent increase of iron is the partial sputtering of material off the surfaces of dust grains by interstellar shocks. Another possibility might be that the ejecta from type I supernovae enrich the low density medium in the halo with iron.

Interstellar clouds - From a dynamical perspective on their chemistry

NASA Technical Reports Server (NTRS)

Prasad, S. S.

1985-01-01

The possibility is examined that in the course of its dynamical evolution, a single mass of interstellar gas would exhibit properties of diffuse clouds, dense clouds and finally also of clouds perturbed by shocks or intense UV or X-ray radiation generated by a star of its own creation. This concept provides a common thread through the bewildering diversity of physical and chemical compositional properties shown by interstellar clouds. From this perspective, instead of being static objects, interstellar clouds are possibly incessantly evolving from initially diffuse to later dense state and then to star formation which ultimately restructures or disperses the remaining cloud material to begin the whole evolutionary process once again. Based on a simplified study of interstellar chemistry from a dynamical perspective, the ideas are presented as an heuristic: to encourage thought on the future direction of molecular astrophysics and the need to consider the chemical behavior of interstellar clouds in conjunction with, rather than in isolation from, their dynamical behavior. A physical basis must be sought for the semiempirical temperature formula which has been given a critical role in the collapse of diffuse clouds. Self-shielding effects in the chemistry of CO were neglected and this drawback should be removed; the ability of the model to explain the fractional abundances of more complex molecules, such as cyanopolyynes, should be examined.

Interstellar Processes Leading to Molecular Deuterium Enrichment and Their Detection

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Kliss, Mark (Technical Monitor)

2001-01-01

Large deuterium (D) enrichments in meteoritic materials indicate that interstellar organic materials survived incorporation into parent bodies within the forming Solar System. These enrichments are likelier due to one or more of four distinct astrochemical processes. These are (1) low temperature gas phase ion-molecule reactions; (2) low temperature gas-grain reactions; (3) gas phase unimolecular photodissociation, and (4) ultraviolet photolysis in D-enriched ice mantles. Each of these processes should be associated with molecular carriers having, distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.). These processes are reviewed and specific spectroscopic signatures for the detection of these processes in space are identified and described.

Theoretical studies of the solar atmosphere and interstellar pickup ions

NASA Technical Reports Server (NTRS)

1994-01-01

Solar atmosphere research activities are summarized. Specific topics addressed include: (1) coronal mass ejections and related phenomena; (2) parametric instabilities of Alfven waves; (3) pickup ions in the solar wind; and (4) cosmic rays in the outer heliosphere. Also included is a list of publications covering the following topics: catastrophic evolution of a force-free flux rope; maximum energy release in flux-rope models of eruptive flares; sheet approximations in models of eruptive flares; material ejection, motions of loops and ribbons of two-ribbon flares; dispersion relations for parametric instabilities of parallel-propagating; parametric instabilities of parallel-propagating Alfven waves; beat, modulation, and decay instabilities of a circularly-polarized Alfven wave; effects of time-dependent photoionization on interstellar pickup helium; observation of waves generated by the solar wind pickup of interstellar hydrogen ions; ion thermalization and wave excitation downstream of the quasi-perpendicular bowshock; ion cyclotron instability and the inverse correlation between proton anisotrophy and proton beta; and effects of cosmic rays and interstellar gas on the dynamics of a wind.

On the source of the dust extinction in type Ia supernovae and the discovery of anomalously strong Na I absorption

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, M. M.; Morrell, Nidia; Hsiao, E. Y.

High-dispersion observations of the Na I D λλ5890, 5896 and K I λλ7665, 7699 interstellar lines, and the diffuse interstellar band at 5780 Å in the spectra of 32 Type Ia supernovae are used as an independent means of probing dust extinction. We show that the dust extinction of the objects where the diffuse interstellar band at 5780 Å is detected is consistent with the visual extinction derived from the supernova colors. This strongly suggests that the dust producing the extinction is predominantly located in the interstellar medium of the host galaxies and not in circumstellar material associated with themore » progenitor system. One quarter of the supernovae display anomalously large Na I column densities in comparison to the amount of dust extinction derived from their colors. Remarkably, all of the cases of unusually strong Na I D absorption correspond to 'Blueshifted' profiles in the classification scheme of Sternberg et al. This coincidence suggests that outflowing circumstellar gas is responsible for at least some of the cases of anomalously large Na I column densities. Two supernovae with unusually strong Na I D absorption showed essentially normal K I column densities for the dust extinction implied by their colors, but this does not appear to be a universal characteristic. Overall, we find the most accurate predictor of individual supernova extinction to be the equivalent width of the diffuse interstellar band at 5780 Å, and provide an empirical relation for its use. Finally, we identify ways of producing significant enhancements of the Na abundance of circumstellar material in both the single-degenerate and double-degenerate scenarios for the progenitor system.« less

Infrared Spectroscopy of Carbonaceous-chondrite Inclusions in the Kapoeta Meteorite: Discovery of Nanodiamonds with New Spectral Features and Astrophysical Implications

NASA Astrophysics Data System (ADS)

Abdu, Yassir A.; Hawthorne, Frank C.; Varela, Maria E.

2018-03-01

We report the finding of nanodiamonds, coexisting with amorphous carbon, in carbonaceous-chondrite (CC) material from the Kapoeta achondritic meteorite by Fourier-transform infrared (FTIR) spectroscopy and micro-Raman spectroscopy. In the C–H stretching region (3100–2600 cm‑1), the FTIR spectrum of the Kapoeta CC material (KBr pellet) shows bands attributable to aliphatic CH2 and CH3 groups, and is very similar to IR spectra of organic matter in carbonaceous chondrites and the diffuse interstellar medium. Nanodiamonds, as evidenced by micro-Raman spectroscopy, were found in a dark region (∼400 μm in size) in the KBr pellet. Micro-FTIR spectra collected from this region are dramatically different from the KBr-pellet spectrum, and their C–H stretching region is dominated by a strong and broad absorption band centered at ∼2886 cm‑1 (3.47 μm), very similar to that observed in IR absorption spectra of hydrocarbon dust in dense interstellar clouds. Micro-FTIR spectroscopy also indicates the presence of an aldehyde and a nitrile, and both of the molecules are ubiquitous in dense interstellar clouds. In addition, IR peaks in the 1500–800 cm‑1 region are also observed, which may be attributed to different levels of nitrogen aggregation in diamonds. This is the first evidence for the presence of the 3.47 μm interstellar IR band in meteorites. Our results further support the assignment of this band to tertiary CH groups on the surfaces of nanodiamonds. The presence of the above interstellar bands and the absence of shock features in the Kapoeta nanodiamonds, as indicated by Raman spectroscopy, suggest formation by a nebular-condensation process similar to chemical-vapor deposition.

The spacing of the interstellar 6.2 and 7.7 micron emission features as an indicator of polycyclic aromatic hydrocarbon size

NASA Technical Reports Server (NTRS)

Hudgins, D. M.; Allamandola, L. J.

1999-01-01

A database of astrophysically relevant, infrared spectral measurements on a wide variety of neutral as well as positively and negatively charged polycyclic aromatic hydrocarbons (PAHs), ranging in size from C10H8 through C48H20, is now available to extend the interstellar PAH model. Beyond simply indicating general characteristics of the carriers, this collection of data now makes it possible to conduct a more thorough interpretation of the details of the interstellar spectra and thereby derive deeper insights into the nature of the emitting material and conditions in the emission zones. This Letter is the first such implementation of this spectral database. The infrared spectra of PAH cations, the main PAH form in the most energetic emission zones, are usually dominated by a few strong features in the 1650-1100 cm-1 (6.1-9.1 microns) region that tend to cluster the vicinity of the interstellar emission bands at 1610 and 1320 cm-1 (6.2 and 7.6 microns), but with spacings typically somewhat less than that observed in the canonical interstellar spectrum. However, the spectra in the database show that this spacing increases steadily with molecular size. Extrapolation of this trend indicates that PAHs in the 50-80 carbon atom size range are entirely consistent with the observed interstellar spacing. Furthermore, the profile of the 1610 cm-1 (6.2 microns) interstellar band indicates that PAHs containing as few as 20 carbon atoms contribute to this feature.

The Spacing of the Interstellar 6.2 Microns and 7.7 Microns Emission Features as an Indicator of PAH Size

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; Allamandola, L. J.; Mead, Susan (Technical Monitor)

1998-01-01

A database of astrophysically relevant, infrared spectral measurements on a wide variety of neutral as well as positively and negatively charged polycyclic aromatic hydrocarbons ranging in size from C10H8 through C48H20 is now available to extend the interstellar PAH model. Beyond simply indicating general characteristics of the carriers, this collection of data now makes it possible to conduct a more thorough interpretation of the details of the interstellar spectra and thereby derive deeper insights into the nature of the emitting material and conditions in the emission zones. This paper is the first such implementation of this spectral database. The infrared spectra of PAH cations, the main PAH form in the most energetic emission zones, are usually dominated by a few strong features in the 1650 - 1100 per centimeter (6.1 - 9.1 microns) region which tend to cluster in the vicinity of the interstellar emission bands at 1610 per centimeter and 1320 per centimeter (6.2 and 7.6 microns) but with spacings typically somewhat less than that observed in the canonical interstellar spectrum. However, the spectra in the database show that this spacing increases steadily with molecular size. Extrapolation of this trend indicates that PAHS in the 50 to 80 carbon atom size range are entirely consistent with the observed interstellar spacing. Furthermore, the profile of the 1610 per centimeter (6.2 microns) interstellar band indicates that PAHS containing as few as 20 carbon atoms contribute to this feature.

Organic solids produced by electrical discharge in reducing atmospheres - Tholin molecular analysis

NASA Technical Reports Server (NTRS)

Khare, B. N.; Sagan, C.; Zumberge, J. E.; Sklarew, D. S.; Nagy, B.

1981-01-01

The complex dark brown solid of a class called tholins, produced on passage of an electrical discharge through a roughly equimolar mixture of methane and ammonia with 2.6% water vapor, is analyzed by vacuum pyrolysis followed by gas chromatography and mass spectrometry. Pyrolyzates include a wide range of aliphatic and aromatic nitriles, alkanes, alkenes, aromatic hydrocarbons, pyrrole, and pyridine. This tholin is remarkably stable to 950 C. It and its degradation products are candidate constituents of planetary aerosols in the outer solar system and of the grains in the interstellar medium.

Copernicus studies of interstellar material in the Perseus II complex. III - The line of sight to Zeta Persei

NASA Technical Reports Server (NTRS)

Snow, T. P., Jr.

1977-01-01

Ultraviolet spectrophotometric data obtained with Copernicus are used to analyze the distribution, composition, density, temperature, and kinematics of the interstellar material along the line of sight to Zeta Persei. The far-UV extinction curve for the star is evaluated along with the kinematics of the interstellar gas, observations of atomic and molecular hydrogen, curves of growth for neutral and ionized species, atomic abundances and depletions, ionization equilibria, and observations of CO and OH lines. The results show that there are apparently three clouds along the line of sight to Zeta Persei: a main cloud at approximately +13 km/s which contains most of the material and forms all the neutral and molecular lines as well as most of the ionic lines, a second component at +22 km/s which must contribute to the strong UV lines of most ions, and a third component at roughly +2 km/s which gives rise to a strong Si III line at 1206 A. It is also found that the UV extinction curve has a somewhat steep far-UV rise, indicating the presence of a substantial number of small grains, and that about 30% of the hydrogen nuclei over the entire line of sight are in molecular form.

The future of Stardust science

NASA Astrophysics Data System (ADS)

Westphal, A. J.; Bridges, J. C.; Brownlee, D. E.; Butterworth, A. L.; de Gregorio, B. T.; Dominguez, G.; Flynn, G. J.; Gainsforth, Z.; Ishii, H. A.; Joswiak, D.; Nittler, L. R.; Ogliore, R. C.; Palma, R.; Pepin, R. O.; Stephan, T.; Zolensky, M. E.

2017-09-01

Recent observations indicate that >99% of the small bodies in the solar system reside in its outer reaches—in the Kuiper Belt and Oort Cloud. Kuiper Belt bodies are probably the best-preserved representatives of the icy planetesimals that dominated the bulk of the solid mass in the early solar system. They likely contain preserved materials inherited from the protosolar cloud, held in cryogenic storage since the formation of the solar system. Despite their importance, they are relatively underrepresented in our extraterrestrial sample collections by many orders of magnitude ( 1013 by mass) as compared with the asteroids, represented by meteorites, which are composed of materials that have generally been strongly altered by thermal and aqueous processes. We have only begun to scratch the surface in understanding Kuiper Belt objects, but it is already clear that the very limited samples of them that we have in our laboratories hold the promise of dramatically expanding our understanding of the formation of the solar system. Stardust returned the first samples from a known small solar system body, the Jupiter-family comet 81P/Wild 2, and, in a separate collector, the first solid samples from the local interstellar medium. The first decade of Stardust research resulted in more than 142 peer-reviewed publications, including 15 papers in Science. Analyses of these amazing samples continue to yield unexpected discoveries and to raise new questions about the history of the early solar system. We identify nine high-priority scientific objectives for future Stardust analyses that address important unsolved problems in planetary science.

Stardust Interstellar Preliminary Examination V: XRF Analyses of Interstellar Dust Candidates at ESRF ID13

NASA Technical Reports Server (NTRS)

Brenker, Frank E.; Westphal, Andrew J.; Simionovici, Alexandre S.; Flynn, George J.; Gainsforth, Zack; Allen, Carlton C.; Sanford, Scott; Zolensky, Michael E.; Bastien, Ron K.; Frank, David R.

2014-01-01

Here, we report analyses by synchrotron X-ray fluorescence microscopy of the elemental composition of eight candidate impact features extracted from the Stardust Interstellar Dust Collector (SIDC). Six of the features were unambiguous tracks, and two were crater-like features. Five of the tracks are so-called midnight tracks that is, they had trajectories consistent with an origin either in the interstellar dust stream or as secondaries from impacts on the Sample Return Capsule (SRC). In a companion paper reporting synchrotron X-ray diffraction analyses of ISPE candidates, we show that two of these particles contain natural crystalline materials: the terminal particle of track 30contains olivine and spinel, and the terminal particle of track 34 contains olivine. Here, we show that the terminal particle of track 30, Orion, shows elemental abundances, normalized to Fe, that are close to CI values, and a complex, fine-grained structure. The terminal particle of track 34, Hylabrook, shows abundances that deviate strongly from CI, but shows little fine structure and is nearly homogenous. The terminal particles of other midnight tracks, 29 and 37, had heavy element abundances below detection threshold. A third, track28, showed a composition inconsistent with an extraterrestrial origin, but also inconsistent with known spacecraft materials. A sixth track, with a trajectory consistent with secondary ejecta from an impact on one of the spacecraft solar panels, contains abundant Ce and Zn. This is consistent with the known composition of the glass covering the solar panel. Neither crater-like feature is likely to be associated with extraterrestrial materials. We also analyzed blank aerogel samples to characterize background and variability between aerogel tiles. We found significant differences in contamination levels and compositions, emphasizing the need for local background subtraction for accurate quantification.

Recent Advances in Organic Cosmochemistry

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Witteborn, Fred C. (Technical Monitor)

1994-01-01

The Astrochemistry Laboratory at NASA's Ames Research Center pursues a variety of activities, most of which center around the use of spectroscopy (ultraviolet to far-infrared) for the interpretation of astronomical and meteoritic data. One of our key activities is the study of the chemical and physical properties of cometary, interstellar, and planetary ice analogs and matrix-isolated molecules of astrophysical interest. As a result of these studies it is now known that a significant fraction of the carbon in the interstellar medium (ISM) is in reasonably complex forms, some of which are clearly of interest for exobiology. Examples of compounds known or suspected to be present in space include polycyclic aromatic hydrocarbons (PAHs), microdiamonds, an aliphatic-rich component found in the diffuse interstellar medium, and a variety of molecular species produced by the irradiation of mixed molecular ices in dense clouds. A number of the species produced by irradiation contain nitrogen and appear to offer an additional means of producing some of the amino acids found in meteorites. I will review these complex carbonaceous materials and discuss how they are connected with each other and the organic materials that ultimately ended up as part of our own Solar System. Specific points that will probably be covered include: (1) the composition of the ices in interstellar dense molecular clouds; (2) the more complex organic compounds produced when these ices are irradiated and/or warmed; (3) the detection of microdiamonds in space; (4) the discovery that aliphatic materials may constitute as much as 15% of all the carbon in the diffuse ISM, appears to be present everywhere in the galaxy, and yet seems to be present everywhere in the galaxy, and yet seems to be significantly concentrated towards the center of the galaxy.

Complex Organics from Laboratory Simulated Interstellar Ices

NASA Technical Reports Server (NTRS)

Dworkin, J. P.

2003-01-01

Many of the volatiles in interstellar dense clouds exist in ices surrounding dust grains. The low temperatures of these ices (T < 50 K) preclude most chemical reactions, but photolysis can drive reactions that produce a suite of new species, many of which are complex organics. We study the UV and proton radiation processing of interstellar ice analogs to explore links between interstellar chemistry, the organics in comets and meteorites, and the origin of life on Earth. The high D/H ratios in some interstellar species, and the knowledge that many of the organics in primitive meteorites are D-enriched, suggest that such links are plausible. Once identified, these species may serve as markers of interstellar heritage of cometary dust and meteorites. Of particular interest are our findings that UV photolysis of interstellar ice analogs produce molecules of importance in current living organisms, including quinones, amphiphiles, and amino acids. Quinones are essential in vital metabolic roles such as electron transport. Studies show that quinones should be made wherever polycyclic aromatic hydrocarbons are photolyzed in interstellar ices. In the case of anthracene-containing ices, we have observed the production of 9-anthrone and 9,10 anthraquinone, both of which have been observed in the Murchison meteorite. Amphiphiles are also made when mixed molecular ices are photolyzed. These amphiphiles self-assemble into fluorescent vesicles when placed in liquid water, as do Murchison extracts. Both have the ability to trap an ionic dye. Photolysis of plausible ices can also produce alanine, serine, and glycine as well as a number of small alcohols and amines. Flash heating of the room temperature residue generated by such experiments generates mass spectral distributions similar to those of IDPs. The detection of high D/H ratios in some interstellar molecular species, and the knowledge that many of the organics, such as hydroxy and amino acids, in primitive meteorites are D-enriched provides evidence for a connection between intact organic material in the interstellar medium and in meteorites. Thus, some of the oxidized aromatics, amphiphiles, amino acids, hydroxy acids, and other compounds found in meteorites may have had an interstellar ancestry and not solely a product of parent body aqueous alteration. Such compounds should also be targeted for searches of organics in cometary dust.

Nitrile versus isonitrile adsorption at interstellar grain surfaces. II. Carbonaceous aromatic surfaces

NASA Astrophysics Data System (ADS)

Bertin, M.; Doronin, M.; Michaut, X.; Philippe, L.; Markovits, A.; Fillion, J.-H.; Pauzat, F.; Ellinger, Y.; Guillemin, J.-C.

2017-12-01

Context. Almost 20% of the 200 different species detected in the interstellar and circumstellar media present a carbon atom linked to nitrogen by a triple bond. Of these 37 molecules, 30 are nitrile R-CN compounds, the remaining 7 belonging to the isonitrile R-NC family. How these species behave in their interactions with the grain surfaces is still an open question. Aims: In a previous work, we have investigated whether the difference between nitrile and isonitrile functional groups may induce differences in the adsorption energies of the related isomers at the surfaces of interstellar grains of various nature and morphologies. This study is a follow up of this work, where we focus on the adsorption on carbonaceous aromatic surfaces. Methods: The question is addressed by means of a concerted experimental and theoretical approach of the adsorption energies of CH3CN and CH3NC on the surface of graphite (with and without surface defects). The experimental determination of the molecule and surface interaction energies is carried out using temperature-programmed desorption in an ultra-high vacuum between 70 and 160 K. Theoretically, the question is addressed using first-principle periodic density functional theory to represent the organised solid support. Results: The adsorption energy of each compound is found to be very sensitive to the structural defects of the aromatic carbonaceous surface: these defects, expected to be present in a large numbers and great diversity on a realistic surface, significantly increase the average adsorption energies to more than 50% as compared to adsorption on perfect graphene planes. The most stable isomer (CH3CN) interacts more efficiently with the carbonaceous solid support than the higher energy isomer (CH3NC), however.

Interstellar dust spectra between 2.5 and 3.3 microns - A search for hydrated silicates

NASA Technical Reports Server (NTRS)

Knacke, R. F.; Mccorkle, S.; Puetter, R. C.; Erickson, E.

1985-01-01

Spectra in the 2.5-3.3 micron wavelength region of VI Cyg 12, AFGL 2205, and AFGL 2885 were obtained in a search for bound water, hydroxyl groups, and hydrated minerals in interstellar dust. No new absorption bands were found. Comparison of expected strengths of bands of serpentine and chlorite-like minerals with the data suggests that less than 25 percent and 50 percent, respectively, of the silicate in the grains is composed of these materials.

Composition, structure, and chemistry of interstellar dust

NASA Technical Reports Server (NTRS)

Tielens, A. G. G. M.; Allamandola, L. J.

1987-01-01

Different dust components present in the interstellar medium (IM) such as amorphous carbon, polycyclic aromatic hydrocarbons, and those IM components which are organic refractory grains and icy grain mantles are discussed as well as their relative importance. The physical properties of grain surface chemistry are discussed with attention given to the surface structure of materials, the adsorption energy and residence time of species on a grain surface, and the sticking probability. Consideration is also given to the contribution of grains to the gas-phase composition of molecular clouds.

Planetary atmospheres program

NASA Technical Reports Server (NTRS)

1982-01-01

Non-solar compositional models of the troposphere of Jupiter, halide cloud condensation and volatile element inventories on Venus, and shock-wave processing of interstellar cloud materials are discussed.

More on the lambda 2800 A 'interstellar extinction' feature

NASA Astrophysics Data System (ADS)

McLachlan, A.; Nandy, K.

1985-02-01

In a response made to a recent letter by Karim et al. (1984), it is shown that the examples of interstellar absorption at 2800 A that they attribute to proteinaceous material can all be attributed to overexposure of IUE detectors. It is pointed out that stars in the Large Magellanic Cloud show pronounced absorption at 2800 A which cannot be due to interstellar protein since there is no associated absorption at 2200 A; this lack of absorption cannot be due to presence of graphite, whose absorption is weak in the Cloud. The claim by Karim et al. that the spectra of eight stars show 2800 A absorption and that these spectra are saturation-free is considered, and it is shown that data processing problems at IUE ground stations make these spectra unreliable.

Formation of complex precursors of amino acids by irradiation of simulated interstellar media with heavy ions

NASA Astrophysics Data System (ADS)

Kobayashi, K.; Suzuki, N.; Taniuchi, T.; Kaneko, T.; Yoshida, S.

A wide variety of organic compounds have been detected in such extraterrestrial bodies as meteorites and comets Amino acids were identified in the extracts from Murchison meteorite and other carbonaceous chondrites It is hypothesized that these compounds are originally formed in ice mantles of interstellar dusts ISDs in molecular clouds by cosmic rays and ultraviolet light UV Formation of amino acid precursors by high energy protons or UV irradiation of simulated ISDs was reported by several groups The amino acid precursors were however not well-characterized We irradiated a frozen mixture of methanol ammonia and water with heavy ions to study possible organic compounds abiotically formed in molecular clouds by cosmic rays A mixture of methanol ammonia and water was irradiated with carbon beams 290 MeV u from a heavy ion accelerator HIMAC of National Institute of Radiological Sciences Japan Irradiation was performed either at room temperature liquid phase or at 77 K solid phase The products were characterized by gel filtration chromatography GFC FT-IR pyrolysis PY -GC MS etc Amino acids were analyzed by HPLC and GC MS after acid hydrolysis or the products Amino acids such as glycine and alanine were identified in the products in both the cases of liquid phase and solid phase irradiation Energy yields G-values of glycine were 0 014 liquid phase and 0 007 solid phase respectively Average molecular weights of the products were estimated as to 2300 in both the case Aromatic hydrocarbons N-containing heterocyclic

Near Earth Inner-Source and Interstellar Pickup Ions Observed with the Hot Plasma Composition Analyzer of the Magnetospheric Multiscale Mission Mms-Hpca

NASA Astrophysics Data System (ADS)

Gomez, R. G.; Fuselier, S. A.; Mukherjee, J.; Gonzalez, C. A.

2017-12-01

Pickup ions found near the earth are generally picked up in the rest frame of the solar wind, and propagate radially outward from their point of origin. While propagating, they simultaneously gyrate about the magnetic field. Pickup ions come in two general populations; interstellar and inner source ions. Interstellar ions originate in the interstellar medium, enter the solar system in a neutral charge state, are gravitationally focused on the side of the sun opposite their arrival direction and, are ionized when they travel near the sun. Inner-source ions originate at a location within the solar system and between the sun and the observation point. Both pickup ion populations share similarities in composition and charge states, so measuring of their dynamics, using their velocity distribution functions, f(v)'s, is absolutely essential to distinguishing them, and to determining their spatial and temporal origins. Presented here will be the results of studies conducted with the four Hot Plasma Composition Analyzers of the Magnetospheric Multiscale Mission (MMS-HPCA). These instruments measure the full sky (4π steradians) distribution functions of near earth plasmas at a 10 second cadence in an energy-to-charge range 0.001-40 keV/e. The instruments are also capable of parsing this combined energy-solid angle phase space with 22.5° resolution polar angle, and 11.25° in azimuthal angle, allowing for clear measurement of the pitch angle scattering of the ions.

Diatoms in comets

NASA Technical Reports Server (NTRS)

Hoover, R.; Hoyle, F.; Wallis, M. K.; Wickramasinghe, N. C.

1986-01-01

The fossil record of the microscopic algae classified as diatoms suggests they were injected to earth at the Cretaceous boundary. Not only could diatoms remain viable in the cometary environment, but also many species might replicate in illuminated surface layers or early interior layers of cometary ice. Presumably they reached the solar system on an interstellar comet as an already-evolved assemblage of organisms. Diatoms might cause color changes to comet nuclei while their outgassing decays and revives around highly elliptical orbits. Just as for interstellar absorption, high-resolution IR observations are capable of distinguishing whether the 10-micron feature arises from siliceous diatom material or mineral silicates. The 10-30-micron band and the UV 220-nm region can also provide evidence of biological material.

Interstellar holography

NASA Astrophysics Data System (ADS)

Walker, M. A.; Koopmans, L. V. E.; Stinebring, D. R.; van Straten, W.

2008-08-01

The dynamic spectrum of a radio pulsar is an in-line digital hologram of the ionized interstellar medium. It has previously been demonstrated that such holograms permit image reconstruction, in the sense that one can determine an approximation to the complex electric field values as a function of Doppler shift and delay, but to date the quality of the reconstructions has been poor. Here we report a substantial improvement in the method which we have achieved by simultaneous optimization of the thousands of coefficients that describe the electric field. For our test spectrum of PSRB0834+06 we find that the model provides an accurate representation of the data over the full 63dB dynamic range of the observations: residual differences between model and data are noise like. The advent of interstellar holography enables detailed quantitative investigation of the interstellar radio-wave propagation paths for a given pulsar at each epoch of observation. We illustrate this using our test data which show the scattering material to be structured and highly anisotropic. The temporal response of the medium exhibits a scattering tail which extends to beyond 100μs, and the centroid of the pulse at this frequency and this epoch of observation is delayed by approximately 15μs as a result of multipath propagation in the interstellar medium.

Polycyclic Aromatic Hydrocarbons

NASA Technical Reports Server (NTRS)

Salama, Farid

2010-01-01

Carbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of the carbonaceous materials. PAHs are the best-known candidates to account for the IR emission bands. They are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge is to reproduce in the laboratory the physical conditions that exist in the emission and absorption interstellar zones. The harsh physical conditions of the ISM -low temperature, collisionless, strong UV radiation fields- are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions and radicals are formed from the neutral precursors in an isolated environment at low temperature and probed with high-sensitivity cavity ringdown spectroscopy in the NUV-NIR range. Carbon nanoparticles are also formed during the short residence time of the precursors in the plasma and are characterized with time-offlight mass spectrometry. These experiments provide unique information on the spectra of large carbonaceous molecules and ions in the gas phase that can now be directly compared to interstellar and circumstellar observations (IR emission bands, DIBs, extinction curve). These findings also hold great potential for understanding the formation process of interstellar carbonaceous grains. We will review recent progress in the experimental and theoretical studies of PAHs, compare the laboratory data with astronomical observations and discuss the global implications.

Near-infrared spectroscopy of the proto-planetary nebula CRL 618 and the origin of the hydrocarbon dust component in the interstellar medium.

PubMed

Chiar, J E; Pendleton, Y J; Geballe, T R; Tielens, A G

1998-11-01

A new 2.8-3.8 micrometers spectrum of the carbon-rich protoplanetary nebula CRL 618 confirms the previous detection of a circumstellar 3.4 micrometers absorption feature in this object (Lequeux & Jourdain de Muizon). The high resolution and high signal-to-noise ratio of our spectrum allow us to derive the detailed profile of this absorption feature, which is very similar to that observed in the spectrum of the Galactic center and also resembles the strong 3.4 micrometers emission feature in some post-asymptotic giant branch stars. A weak 3.3 micrometers unidentified infrared band, marginally detected in the CRL 618 spectrum of Lequeux & Jourdain de Muizon, is present in our spectrum. The existence of the 3.4 micrometers feature implies the presence of relatively short-chained, aliphatic hydrocarbon materials (-CH2-/-CH3 approximately = 2-2.5) in the circumstellar environment around CRL 618. It also implies that the carriers of the interstellar 3.4 micrometers feature are produced at least in part in circumstellar material, and it calls into question whether any are produced by the processing of interstellar ices in dense interstellar clouds, as has been previously proposed. Other features in the spectrum are recombination lines of hydrogen, rotational and vibration-rotation lines of molecular hydrogen, and a broad absorption probably due to a blend of HCN and C2H2 bands.

Near-infrared spectroscopy of the proto-planetary nebula CRL 618 and the origin of the hydrocarbon dust component in the interstellar medium

NASA Technical Reports Server (NTRS)

Chiar, J. E.; Pendleton, Y. J.; Geballe, T. R.; Tielens, A. G.

1998-01-01

A new 2.8-3.8 micrometers spectrum of the carbon-rich protoplanetary nebula CRL 618 confirms the previous detection of a circumstellar 3.4 micrometers absorption feature in this object (Lequeux & Jourdain de Muizon). The high resolution and high signal-to-noise ratio of our spectrum allow us to derive the detailed profile of this absorption feature, which is very similar to that observed in the spectrum of the Galactic center and also resembles the strong 3.4 micrometers emission feature in some post-asymptotic giant branch stars. A weak 3.3 micrometers unidentified infrared band, marginally detected in the CRL 618 spectrum of Lequeux & Jourdain de Muizon, is present in our spectrum. The existence of the 3.4 micrometers feature implies the presence of relatively short-chained, aliphatic hydrocarbon materials (-CH2-/-CH3 approximately = 2-2.5) in the circumstellar environment around CRL 618. It also implies that the carriers of the interstellar 3.4 micrometers feature are produced at least in part in circumstellar material, and it calls into question whether any are produced by the processing of interstellar ices in dense interstellar clouds, as has been previously proposed. Other features in the spectrum are recombination lines of hydrogen, rotational and vibration-rotation lines of molecular hydrogen, and a broad absorption probably due to a blend of HCN and C2H2 bands.

ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) - Merging Observations and Laboratory Data

NASA Technical Reports Server (NTRS)

Salama, Farid

2016-01-01

The Diffuse Interstellar Bands (DIBs) are a set of 500 absorption bands that are detected in the spectra of stars with interstellar clouds in the line of sight. DIBs are found from the NUV to the NIR in the spectra of reddened stars spanning different interstellar environments in our local, and in other galaxies. DIB carriers are a significant part of the interstellar chemical inventory. They are stable and ubiquitous in a broad variety of environments and play a unique role in interstellar physics/chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics, and astrophysical modeling of line-of-sights. PAHs are among the molecular species that have been proposed as DIB carriers. We will present an assessment of the PAH-DIB model in view of the progress and the advances that have been achieved over the past years through a series of studies involving astronomical observations of DIBs, laboratory simulation of interstellar analogs for neutrals and ionized PAHs, theoretical calculations of PAH spectra and the modelization of diffuse and translucent interstellar clouds. We will present a summary of what has been learned from these complementary studies, the constraints that can now be derived for the PAHs as DIB carriers in the context of the PAH-DIB model and how these constraints can be applied to the EDIBLES project. The spectra of several neutral and ionized PAHs isolated in the gas phase at low temperature have been measured in the laboratory under experimental conditions that mimic interstellar conditions and are compared with an extensive set of astronomical spectra of reddened, early type stars. The comparisons of astronomical and laboratory data provide upper limits for the abundances of specific neutral PAH molecules and ions along specific lines-of-sight. Something that is not attainable from infrared observations alone. We present the characteristics of the laboratory facilities, MIS and COSmIC, that have been developed for this study and discuss the findings resulting from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. MIS stands for Matrix Isolation Spectroscopy, a well-proven technique for isolating cold molecular species in inert solid environments. COSmIC stands for Cosmic Simulation Chamber. It combines a supersonic free jet expansion with discharge plasma and high-sensitivity cavity ringdown spectroscopy and time-of-flight mass spectrometry detection tools for the generation and the detection of cold, isolated gas-phase molecules and ions under experimental conditions that closely mimic interstellar conditions. The column densities of the individual neutral PAH molecules and ions probed in these surveys are derived from the comparison of these unique laboratory data with high resolution, high S/N ratio astronomical observations. The comparisons of astronomical and laboratory data lead to clear and unambiguous conclusions regarding the expected abundances for PAHs of various sizes and charge states in the interstellar environments probed in the surveys. Band profile comparisons between laboratory and astronomical spectra lead to information regarding the molecular structures and characteristics associated with the DIB carriers in the corresponding lines-of-sight. These quantitative surveys of neutral and ionized PAHs in the optical range open the way for unambiguous quantitative searches of PAHs and complex organics in a variety of interstellar and circumstellar environments.

Interstellar Probe: The Next Step To Flight

NASA Astrophysics Data System (ADS)

McNutt, Ralph; Zurbuchen, Thomas H.

2016-07-01

In the years following the discovery of the solar wind, the term "heliosphere" was coined and defined as "the region of interplanetary space where the solar wind is flowing supersonically." In June 1971, with the development of the Pioneer probes to Jupiter and beyond well underway, a session of the American Astronautical Society meeting considered scientific exploration reaching beyond the solar system and into the interstellar medium. Despite many discussions, studies, and meetings since, the most recent held under the auspices of the Keck Institute for Space Studies (8-11 September 2014 and 13-15 January 2015), such missions have been relegated to the '"future" due to the large distances and solar system escape speeds contemplated for their execution. In the meantime, the Voyager Interstellar Mission (VIM), consisting of the twin Voyager spacecraft almost 40 years since their respective launches, are making inroads into this region beyond the termination shock of the solar wind, a new region of the solid bodies of the solar system has been opened by the New Horizons flyby of the Pluto system, and the Cassini Ion and Neutral CAmera (INCA) and Interstellar Boundary Explorer (IBEX) have remotely sensed neutral atoms that have provided significant clues to the global structure of the interaction of the solar wind and interstellar medium. It is now time for a dedicated mission to the regime beyond the solar system to explore our galactic environment. A first, near-term implementation can be carried out with the near-current flight system technology. What is also clear is that the high speeds required will limit the spacecraft to a relatively small mass of no more than ~500 kg, regardless of the propulsion details. The recent success of the New Horizons mission at the Pluto system illustrates that with modern technologies, such spacecraft sizes can still accommodate the means to produce paradigm-shifting science, providing for a compelling scientific mission. The Committee on Space Research (COSPAR) has recently established a new Panel on Interstellar Research (PIR) to consider the next steps toward finally making a dedicated Interstellar Probe mission a reality. Crucial tasks are to build consensus amongst the international scientific community for the appropriate scientific campaigns and measurements to be carried out for such a mission, taking into account the new and continuing results from the outer solar system and beyond by VIM, IBEX, New Horizons, and exoplanet observations and studies.

Speed Kills: Highly Relativistic Spaceflight Would be Fatal for People and Instruments

NASA Astrophysics Data System (ADS)

Edelstein, William; Edelstein, Arthur

2010-02-01

Stories, books and movies about space travel often describe journeys at near-light velocities. Such high speed is desirable, as the resulting relativistic time dilation reduces the duration of the trip, at least for the travelers, so that they can cover interstellar distances in a reasonable amount of time (by their own clocks) and live long enough to reach their destination. The relativistic rocket equation shows the enormous difficulty of achieving such velocities. As spaceship velocities approach the speed of light, interstellar hydrogen, although only present on average at a density of about 2 atoms per cm^3, impinges on the spacecraft and turns into intense radiation (Purcell, 1963) that would quickly kill passengers and destroy instrumentation. In addition, the energy loss of ionizing radiation passing through the ship's hull represents an increasing heat load which necessitates large expenditures of energy to cool the ship. Preventing this irradiation by the use of material or electromagnetic shields is a daunting and, as far as we know, unsolvable problem. The presence of interstellar hydrogen is yet another formidable obstacle to interstellar travel. )

The Capture of Interstellar Dust: The Pure Poynting-Robertson Case

NASA Technical Reports Server (NTRS)

Jackson, A. A.

2001-01-01

Ulysses and Galileo spacecraft have discovered interstellar dust particles entering the solar system. In general, particles trajectories not altered by Lorentz forces or radiation pressure should encounter the sun on open orbits. Under Newtonian forces alone these particles return to the interstellar medium. Dissipative forces, such as Poynting Robertson (PR) and corpuscular drag and non-dissipative Lorentz forces can modify open orbits to become closed. In particular, it is possible for the orbits of particles that pass close to the Sun to become closed due to PR drag. Further, solar irradiation will cause modification of the size of the dust particle by evaporation. The combination of these processes gives rise a class of capture orbits and bound orbits with evaporation. Considering only the case of pure PR drag a minimum impact parameter is derived for initial capture by Poynting-Robertson drag. Orbits in the solar radiation field are computed numerically accounting for evaporation with optical and material properties for ideal interstellar particles modeled. The properties of this kind of particle capture are discussed for the Sun but is applicable to other stars.

The Production of Amino Acids in Interstellar Ices: Implications for Meteoritic Organics

NASA Technical Reports Server (NTRS)

Sandford, A.; Bernstein, M. P.; Dworkin, J. P.; Cooper, G. W.; Allamandola, L. J.; DeVincenzi, D. (Technical Monitor)

2002-01-01

Indigenous amino acids have been detected in a number of meteorites, over 70 in the Murchison meteorite alone. It has been generally accepted that the amino acids in meteorites formed in liquid water on an asteroid or comet parent-body. However, the water in the Murchison meteorite, for example, was depleted of deuterium, making the distribution of deuterium in organic acids in Murchison difficult to explain. Similarly, occasional but consistent meteoritic biases for non-terrestrial L amino acids cannot be reasonably rationalized by liquid water parent-body reactions. We will present the results of a laboratory demonstration showing that the amino acids glycine, alanine, and serine should result from the UV (ultraviolet) photolysis of interstellar ice grains. This suggests that some meteoritic amino acids may be the result of interstellar ice photochemistry, rather than having formed by reactions in liquid water. We will describe some of the potential implications of these findings for the organic materials found in primitive meteorites, in particular how interstellar ice synthesis might more easily accommodate the presence and distribution of deuterium, and the meteoritic bias for L amino acids.

Laser ablated hydantoin: A high resolution rotational study.

PubMed

Alonso, Elena R; Kolesniková, Lucie; Alonso, José L

2017-09-28

Laser ablation techniques coupled with broadband and narrowband Fourier transform microwave spectroscopies have allowed the high resolution rotational study of solid hydantoin, an important target in astrochemistry as a possible precursor of glycine. The complicated hyperfine structure arising from the presence of two 14 N nuclei in non-equivalent positions has been resolved and interpreted in terms of the nuclear quadrupole coupling interactions. The results reported in this work provide a solid base for the interstellar searches of hydantoin in the astrophysical surveys. The values of the nuclear quadrupole coupling constants have been also discussed in terms of the electronic environment around the respective nitrogen atom.

Star Formation and the Solar System

NASA Technical Reports Server (NTRS)

Bally, John; Boss, Alan; Papanastassiou, Dimitri; Sandford, Scott; Sargent, Anneila

1988-01-01

We have seen that studies of nearby star-forming regions are beginning to reveal the first signs of protoplanetary disks. Studies of interstellar and interplanetary grains are starting to provide clues about the processing and incorporation of matter into the Solar System. Studies of meteorites have yielded isotopic anomalies which indicate that some of the grains and inclusions in these bodies are very primitive. Although we have not yet detected a true interstellar grain, some of these materials have not been extensively modified since their removal from the ISM. We are indeed close to seeing our interstellar heritage. The overlap between astronomical and Solar System studies is in its infancy. What future experiments, observations, and missions can be performed in the near future that will greatly enhance our understanding of star formation and the formation of the Solar System?

Interstellar organic matter in meteorites

NASA Technical Reports Server (NTRS)

Yang, J.; Epstein, S.

1983-01-01

Deuterium-enriched hydrogen is present in organic matter in such meteorites as noncarbonaceous chondrites. The majority of the unequilibrated primitive meteorites contain hydrogen whose D/H ratios are greater than 0.0003, requiring enrichment (relative to cosmic hydrogen) by isotope exchange reactions taking place below 150 K. The D/H values presented are the lower limits for the organic compounds derived from interstellar molecules, since all processes subsequent to their formation, including terrestrial contamination, decrease their D/H ratios. In contrast, the D/H ratios of hydrogen associated with hydrated silicates are relatively uniform for the meteorites analyzed. The C-13/C-12 ratios of organic matter, irrespective of D/H ratio, lie well within those observed for the earth. Present findings suggest that other interstellar material, in addition to organic matter, is preserved and is present in high D/H ratio meteorites.

Radical-induced chemistry from VUV photolysis of interstellar ice analogues containing formaldehyde

NASA Astrophysics Data System (ADS)

Butscher, Teddy; Duvernay, Fabrice; Danger, Grégoire; Chiavassa, Thierry

2016-09-01

Surface processes and radical chemistry within interstellar ices are increasingly suspected to play an important role in the formation of complex organic molecules (COMs) observed in several astrophysical regions and cometary environments. We present new laboratory experiments on the low-temperature solid state formation of complex organic molecules - glycolaldehyde, ethylene glycol, and polyoxymethylene - through radical-induced reactivity from VUV photolysis of formaldehyde in water-free and water-dominated ices. Radical reactivity and endogenous formation of COMs were monitored in situ via infrared spectroscopy in the solid state and post photolysis with temperature programmed desorption (TPD) using a quadripole mass spectrometer. We show the ability of free radicals to be stored when formed at low temperature in water-dominated ices, and to react with other radicals or on double bonds of unsaturated molecules when the temperature increases. It experimentally confirms the role of thermal diffusion in radical reactivity. We propose a new pathway for formaldehyde polymerisation induced by HCO radicals that might explain some observations made by the Ptolemy instrument on board the Rosetta lander Philae. In addition, our results seem to indicate that H-atom additions on H2CO proceed preferentially through CH2OH intermediate radicals rather than the CH3O radical.

Stardust Interstellar Preliminary Examination

NASA Astrophysics Data System (ADS)

Westphal, A.; Stardust Interstellar Preliminary Examation Team: http://www. ssl. berkeley. edu/~westphal/ISPE/

2011-12-01

A. J. Westphal, C. Allen, A. Ansari, S. Bajt, R. S. Bastien, H. A. Bechtel, J. Borg, F. E. Brenker, J. Bridges, D. E. Brownlee, M. Burchell, M. Burghammer, A. L. Butterworth, A. M. Davis, P. Cloetens, C. Floss, G. Flynn, D. Frank, Z. Gainsforth, E. Grün, P. R. Heck, J. K. Hillier, P. Hoppe, G. Huss, J. Huth, B. Hvide, A. Kearsley, A. J. King, B. Lai, J. Leitner, L. Lemelle, H. Leroux, R. Lettieri, W. Marchant, L. R. Nittler, R. Ogliore, F. Postberg, M. C. Price, S. A. Sandford, J.-A. Sans Tresseras, T. Schoonjans, S. Schmitz, G. Silversmit, A. Simionovici, V. A. Solé, R. Srama, T. Stephan, V. Sterken, J. Stodolna, R. M. Stroud, S. Sutton, M. Trieloff, P. Tsou, A. Tsuchiyama, T. Tyliszczak, B. Vekemans, L. Vincze, D. Zevin, M. E. Zolensky, >29,000 Stardust@home dusters ISPE author affiliations are at http://www.ssl.berkeley.edu/~westphal/ISPE/. In 2000 and 2002, a ~0.1m2 array of aerogel tiles and alumi-num foils onboard the Stardust spacecraft was exposed to the interstellar dust (ISD) stream for an integrated time of 200 days. The exposure took place in interplanetary space, beyond the orbit of Mars, and thus was free of the ubiquitous orbital debris in low-earth orbit that precludes effective searches for interstellar dust there. Despite the long exposure of the Stardust collector, <<100 ISD particles are expected to have been captured. The particles are thought to be ~1μm or less in size, and the total ISD collection is probably <10-6 by mass of the collection of cometary dust parti-cles captured in the Stardust cometary dust collector from the coma of the Jupiter-family comet Wild 2. Thus, although the first solid sample from the local interstellar medium is clearly of high interest, the diminutive size of the particles and the low numbers of particles present daunting challenges. Nevertheless, six recent developments have made a Preliminary Examination (PE) of this sample practical: (1) rapid automated digital optical scanning microscopy for three-dimensional imaging of the aerogel collector; (2) rapid automated digital scanning electron microscopy for imaging of the aluminum foils; (3) an effective, massively-distributed search by citizen scientists through the Internet; (4) extraction and sample preparation tech-niques for μm-sized particles in aerogel; (5) advances in capabili-ties of synchrotron infrared and X-ray microprobes that enable non-destructive analyses of sub-μm particles in situ in aerogel; and (6) the development of focused-ion beam (FIB) milling tech-niques for sample preparation. The Stardust Interstellar PE consists of six related projects: the identification of tracks through automated scanning microscopy and distributed searching by volunteers (Stardust@home); the extraction of tracks from aerogel in "picokeystones"; the analysis of tracks using synchrotron microprobes; the identifica-tion and analysis of impacts in aluminum foils; laboratory investigations of ISD analogs using an electrostatic dust accelerator; and modeling of ISD propagation in the heliosphere. To date we have identified four impacts in the aerogel collector and one on the foils of probable interstellar origin. We will report on our analyses and implications for the solid component of the local interstellar medium.

Pure iron grains are rare in the universe.

PubMed

Kimura, Yuki; Tanaka, Kyoko K; Nozawa, Takaya; Takeuchi, Shinsuke; Inatomi, Yuko

2017-01-01

The abundant forms in which the major elements in the universe exist have been determined from numerous astronomical observations and meteoritic analyses. Iron (Fe) is an exception, in that only depletion of gaseous Fe has been detected in the interstellar medium, suggesting that Fe is condensed into a solid, possibly the astronomically invisible metal. To determine the primary form of Fe, we replicated the formation of Fe grains in gaseous ejecta of evolved stars by means of microgravity experiments. We found that the sticking probability for the formation of Fe grains is extremely small; only a few atoms will stick per hundred thousand collisions so that homogeneous nucleation of metallic Fe grains is highly ineffective, even in the Fe-rich ejecta of type Ia supernovae. This implies that most Fe is locked up as grains of Fe compounds or as impurities accreted onto other grains in the interstellar medium.

Pure iron grains are rare in the universe

PubMed Central

Kimura, Yuki; Tanaka, Kyoko K.; Nozawa, Takaya; Takeuchi, Shinsuke; Inatomi, Yuko

2017-01-01

The abundant forms in which the major elements in the universe exist have been determined from numerous astronomical observations and meteoritic analyses. Iron (Fe) is an exception, in that only depletion of gaseous Fe has been detected in the interstellar medium, suggesting that Fe is condensed into a solid, possibly the astronomically invisible metal. To determine the primary form of Fe, we replicated the formation of Fe grains in gaseous ejecta of evolved stars by means of microgravity experiments. We found that the sticking probability for the formation of Fe grains is extremely small; only a few atoms will stick per hundred thousand collisions so that homogeneous nucleation of metallic Fe grains is highly ineffective, even in the Fe-rich ejecta of type Ia supernovae. This implies that most Fe is locked up as grains of Fe compounds or as impurities accreted onto other grains in the interstellar medium. PMID:28116359

Polycyclic aromatic hydrocarbons in the atmospheres of Titan and Jupiter

NASA Technical Reports Server (NTRS)

Sagan, Carl; Khare, B. N.; Thompson, W. R.; Mcdonald, G. D.; Wing, Michael R.; Bada, Jeffrey L.; Vo-Dinh, Tuan; Arakawa, E. T.

1993-01-01

PAHs are important components of the interstellar medium and carbonaceous chondrites, but have never been identified in the reducing atmospheres of the outer solar system. Incompletely characterized complex organic solids (tholins) produced by irradiating simulated Titan atmospheres reproduce well the observed UV/visible/IR optical constants of the Titan stratospheric haze. Titan tholin and a tholin generated in a crude simulation of the atmosphere of Jupiter are examined by two-step laser desorption/multiphoton ionization mass spectrometry. A range of two- to four-ring PAHs, some with one to four alkylation sites, are identified, with a net abundance of about 0.0001 g/g (grams per gram) of tholins produced. Synchronous fluorescence techniques confirm this detection. Titan tholins have proportionately more one- and two-ring PAHs than do Jupiter tholins, which in turn have more four-ring and larger PAHs. The four-ringed PAH chrysene, prominent in some discussions of interstellar grains, is found in Jupiter tholins.

A Test of the Interstellar Boundary EXplorer Ribbon Formation in the Outer Heliosheath

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gamayunov, Konstantin V.; Rassoul, Hamid; Heerikhuisen, Jacob, E-mail: kgamayunov@fit.edu

NASA’s Interstellar Boundary EXplorer ( IBEX ) mission is imaging energetic neutral atoms (ENAs) propagating to Earth from the outer heliosphere and local interstellar medium (LISM). A dominant feature in all ENA maps is a ribbon of enhanced fluxes that was not predicted before IBEX . While more than a dozen models of the ribbon formation have been proposed, consensus has gathered around the so-called secondary ENA model. Two classes of secondary ENA models have been proposed; the first class assumes weak scattering of the energetic pickup protons in the LISM, and the second class assumes strong but spatially localizedmore » scattering. Here we present a numerical test of the “weak scattering” version of the secondary ENA model using our gyro-averaged kinetic model for the evolution of the phase-space distribution of protons in the outer heliosheath. As input for our test, we use distributions of the primary ENAs from our MHD-plasma/kinetic-neutral model of the heliosphere-LISM interaction. The magnetic field spectrum for the large-scale interstellar turbulence and an upper limit for the amplitude of small-scale local turbulence (SSLT) generated by protons are taken from observations by Voyager 1 in the LISM. The hybrid simulations of energetic protons are also used to set the bounding wavenumbers for the spectrum of SSLT. Our test supports the “weak scattering” version. This makes an additional solid step on the way to understanding the origin and formation of the IBEX ribbon and thus to improving our understanding of the interaction between the heliosphere and the LISM.« less

THz and mid-IR spectroscopy of interstellar ice analogs: methyl and carboxylic acid groups.

PubMed

Ioppolo, S; McGuire, B A; Allodi, M A; Blake, G A

2014-01-01

A fundamental problem in astrochemistry concerns the synthesis and survival of complex organic molecules (COMs) throughout the process of star and planet formation. While it is generally accepted that most complex molecules and prebiotic species form in the solid phase on icy grain particles, a complete understanding of the formation pathways is still largely lacking. To take full advantage of the enormous number of available THz observations (e.g., Herschel Space Observatory, SOFIA, and ALMA), laboratory analogs must be studied systematically. Here, we present the THz (0.3-7.5 THz; 10-250 cm(-1)) and mid-IR (400-4000 cm(-1)) spectra of astrophysically-relevant species that share the same functional groups, including formic acid (HCOOH) and acetic acid (CH3COOH), and acetaldehyde (CH3CHO) and acetone ((CH3)2CO), compared to more abundant interstellar molecules such as water (H2O), methanol (CH3OH), and carbon monoxide (CO). A suite of pure and mixed binary ices are discussed. The effects on the spectra due to the composition and the structure of the ice at different temperatures are shown. Our results demonstrate that THz spectra are sensitive to reversible and irreversible transformations within the ice caused by thermal processing, suggesting that THz spectra can be used to study the composition, structure, and thermal history of interstellar ices. Moreover, the THz spectrum of an individual species depends on the functional group(s) within that molecule. Thus, future THz studies of different functional groups will help in characterizing the chemistry and physics of the interstellar medium (ISM).

Irradiated Benzene Ice Provides Clues to Meteoritic Organic Chemistry

NASA Technical Reports Server (NTRS)

Callahan, Michael Patrick; Gerakines, Perry Alexander; Martin, Mildred G.; Hudson, Reggie L.; Peeters, Zan

2013-01-01

Aromatic hydrocarbons account for a significant portion of the organic matter in carbonaceous chondrite meteorites, as a component of both the low molecular weight, solvent-extractable compounds and the insoluble organic macromolecular material. Previous work has suggested that the aromatic compounds in carbonaceous chondrites may have originated in the radiation-processed icy mantles of interstellar dust grains. Here we report new studies of the organic residue made from benzene irradiated at 19 K by 0.8 MeV protons. Polyphenyls with up to four rings were unambiguously identified in the residue by gas chromatography-mass spectrometry. Atmospheric pressure photoionization Fourier transform mass spectrometry was used to determine molecular composition, and accurate mass measurements suggested the presence of polyphenyls, partially hydrogenated polyphenyls, and other complex aromatic compounds. The profile of low molecular weight compounds in the residue compared well with extracts from the Murchison and Orgueil meteorites. These results are consistent with the possibility that solid phase radiation chemistry of benzene produced some of the complex aromatics found in meteorites.

Theory of Planetary System Formation

NASA Technical Reports Server (NTRS)

Cassen, Patrick

1996-01-01

Observations and theoretical considerations support the idea that the Solar System formed by the collapse of tenuous interstellar matter to a disk of gas and dust (the primitive solar nebula), from which the Sun and other components separated under the action of dissipative forces and by the coagulation of solid material. Thus, planets are understood to be contemporaneous byproducts of star formation. Because the circumstellar disks of new stars are easier to observe than mature planetary systems, the possibility arises that the nature and variety of planets might be studied from observations of the conditions of their birth. A useful theory of planetary system formation would therefore relate the properties of circumstellar disks both to the initial conditions of star formation and to the consequent properties of planets to those of the disk. Although the broad outlines of such a theory are in place, many aspects are either untested, controversial, or otherwise unresolved; even the degree to which such a comprehensive theory is possible remains unknown.

Education and Public Outreach for Stardust@home: An Interactive Internet-based Search for Interstellar Dust

NASA Astrophysics Data System (ADS)

Mendez, Bryan J.; Westphal, A. J.; Butterworth, A. L.; Craig, N.

2006-12-01

On January 15, 2006, NASA’s Stardust mission returned to Earth after nearly seven years in interplanetary space. During its journey, Stardust encountered comet Wild 2, collecting dust particles from it in a special material called aerogel. At two other times in the mission, aerogel collectors were also opened to collect interstellar dust. The Stardust Interstellar Dust Collector is being scanned by an automated microscope at the Johnson Space Center. There are approximately 700,000 fields of view needed to cover the entire collector, but we expect only a few dozen total grains of interstellar dust were captured within it. Finding these particles is a daunting task. We have recruited many thousands of volunteers from the public to aid in the search for these precious pieces of space dust trapped in the collectors. We call the project Stardust@home. Through Stardust@home, volunteers from the public search fields of view from the Stardust aerogel collector using a web-based Virtual Microscope. Volunteers who discover interstellar dust particles have the privilege of naming them. The interest and response to this project has been extraordinary. Many people from all walks of life are very excited about space science and eager to volunteer their time to contribute to a real research project such as this. We will discuss the progress of the project and the education and outreach activities being carried out for it.

Stardust@home: An Interactive Internet-based Search for Interstellar Dust

NASA Astrophysics Data System (ADS)

Mendez, B. J.; Westphal, A. J.; Butterworth, A. L.; Craig, N.

2006-12-01

On January 15, 2006, NASA's Stardust mission returned to Earth after nearly seven years in interplanetary space. During its journey, Stardust encountered comet Wild 2, collecting dust particles from it in a special material called aerogel. At two other times in the mission, aerogel collectors were also opened to collect interstellar dust. The Stardust Interstellar Dust Collector is being scanned by an automated microscope at the Johnson Space Center. There are approximately 700,000 fields of view needed to cover the entire collector, but we expect only a few dozen total grains of interstellar dust were captured within it. Finding these particles is a daunting task. We have recruited many thousands of volunteers from the public to aid in the search for these precious pieces of space dust trapped in the collectors. We call the project Stardust@home. Through Stardust@home, volunteers from the public search fields of view from the Stardust aerogel collector using a web-based Virtual Microscope. Volunteers who discover interstellar dust particles have the privilege of naming them. The interest and response to this project has been extraordinary. Many people from all walks of life are very excited about space science and eager to volunteer their time to contribute to a real research project such as this. We will discuss the progress of the project and the education and outreach activities being carried out for it.

Project Dragonfly: A feasibility study of interstellar travel using laser-powered light sail propulsion

NASA Astrophysics Data System (ADS)

Perakis, Nikolaos; Schrenk, Lukas E.; Gutsmiedl, Johannes; Koop, Artur; Losekamm, Martin J.

2016-12-01

Light sail-based propulsion systems are a candidate technology for interplanetary and interstellar missions due to their flexibility and the fact that no fuel has to be carried along. In 2014, the Initiative for Interstellar Studies (i4is) hosted the Project Dragonfly Design Competition, which aimed at assessing the feasibility of sending an interstellar probe propelled by a laser-powered light sail to another star system. We analyzed and designed a mission to the Alpha Centauri system, with the objective to carry out science operations at the destination. Based on a comprehensive evaluation of currently available technologies and possible locations, we selected a lunar architecture for the laser system. It combines the advantages of surface- and space-based systems, as it requires no station keeping and suffers no atmospheric losses. We chose a graphene-based sandwich material for the light sail because of its low density. Deceleration of the spacecraft sufficient for science operations at the target system is achieved using both magnetic and electric sails. Applying these assumptions in a simulation leads to the conclusion that 250 kg of scientific payload can be sent to Alpha Centauri within the Project Dragonfly Design Competition's constraints of 100 year travel duration and 100 GW laser beam power. This is only sufficient to fulfill parts of the identified scientific objectives, and therefore renders the usefulness of such a mission questionable. A better sail material or higher laser power would improve the acceleration behavior, an increase in the mission time would allow for larger spacecraft masses.

Detection of boron, cobalt, and other weak interstellar lines toward Zeta Ophiuchi

NASA Technical Reports Server (NTRS)

Federman, S. R.; Sheffer, Y.; Lambert, D. L.; Gilliland, R. L.

1993-01-01

Numerous weak lines from interstellar atomic species toward Zeta Ophiuchi were observed with the Goddard High-Resolution Spectrograph. Of particular note are the first interstellar detection of cobalt and the detection of boron in this sight line. These measurements provide estimates for the amount of depletion for the two elements. Boron, a volatile, and cobalt, a refractory element, display the depletion pattern found by Savage et al. (1992). The abundance of phosphorus in the H II region associated with the star was obtained from a detection of P III. Additional weak lines from S I, C I, Ni II, and Cu II were detected for the first time; these lines provide the basis for refinements in oscillator strength and column density. Analysis of the neutral sulfur data indicates that the atomic gas is more widely distributed than the molecular material in the main component.

Laboratory Spectroscopy of Large Carbon Molecules and Ions in Support of Space Missions

NASA Technical Reports Server (NTRS)

Salana, Farid; Tan, X.; Cami, J.; Remy, J.

2006-01-01

One of the major objectives of Laboratory Astrophysics is the optimization of data return from space missions by measuring spectra of atomic and molecular species in laboratory environments that mimic interstellar conditions (WhitePaper (2002, 2006)). Among interstellar species, PAHs are an important and ubiquitous component of carbon-bearing materials that represents a particularly difficult challenge for gas-phase laboratory studies. We present the absorption spectra of jet-cooled neutral and ionized PAHs and discuss the implications for astrophysics. The harsh physical conditions of the interstellar medium have been simulated in the laboratory. We are now, for the first time, in the position to directly compare laboratory spectra of PAHs and carbon nanoparticles with astronomical observations. This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems (HST/COS, FUSE, JWST, Spitzer).

KSC-02pd2057

NASA Image and Video Library

2002-10-25

KENNEDY SPACE CENTER, FLA. - At NASA's Space Launch Complex 2 (SLC-2), Vandenberg Air Force Base, Calif., the launch tower has been rolled back to reveal a Delta II rocket with its solid rocket boosters attached. The rocket will carry the ICESat and CHIPSat satellites into Earth orbits. The Ice, Cloud, and Land Elevation Satellite, or ICESat, is a 661-pound satellite known as Geoscience Laser Altimeter System (GLAS) that will revolutionize our understanding of ice and its role in global climate change and how we protect and understand our home planet. It will help scientists determine if the global sea level is rising or falling. It will look at the ice sheets that blanket the Earth's poles to see if they are growing or shrinking. It will assist in developing an understanding of how changes in the Earth's atmosphere and climate effect polar ice masses and global sea level. The Cosmic Hot Interstellar Plasma Spectrometer, or CHIPSat, a suitcase-size 131-pound satellite, will provide invaluable information into the origin, physical processes and properties of the hot gas contained in the interstellar medium. This can provide important clues about the formation and evolution of galaxies since the interstellar medium literally contains the seeds of future stars. The Delta II launch is scheduled for Jan. 11, 2003, between 4:45 p.m. - 5:30 p.m. PST.

Quantum tunneling observed without its characteristic large kinetic isotope effects.

PubMed

Hama, Tetsuya; Ueta, Hirokazu; Kouchi, Akira; Watanabe, Naoki

2015-06-16

Classical transition-state theory is fundamental to describing chemical kinetics; however, quantum tunneling is also important in explaining the unexpectedly large reaction efficiencies observed in many chemical systems. Tunneling is often indicated by anomalously large kinetic isotope effects (KIEs), because a particle's ability to tunnel decreases significantly with its increasing mass. Here we experimentally demonstrate that cold hydrogen (H) and deuterium (D) atoms can add to solid benzene by tunneling; however, the observed H/D KIE was very small (1-1.5) despite the large intrinsic H/D KIE of tunneling (≳ 100). This strong reduction is due to the chemical kinetics being controlled not by tunneling but by the surface diffusion of the H/D atoms, a process not greatly affected by the isotope type. Because tunneling need not be accompanied by a large KIE in surface and interfacial chemical systems, it might be overlooked in other systems such as aerosols or enzymes. Our results suggest that surface tunneling reactions on interstellar dust may contribute to the deuteration of interstellar aromatic and aliphatic hydrocarbons, which could represent a major source of the deuterium enrichment observed in carbonaceous meteorites and interplanetary dust particles. These findings could improve our understanding of interstellar physicochemical processes, including those during the formation of the solar system.

Quantum tunneling observed without its characteristic large kinetic isotope effects

PubMed Central

Hama, Tetsuya; Ueta, Hirokazu; Kouchi, Akira; Watanabe, Naoki

2015-01-01

Classical transition-state theory is fundamental to describing chemical kinetics; however, quantum tunneling is also important in explaining the unexpectedly large reaction efficiencies observed in many chemical systems. Tunneling is often indicated by anomalously large kinetic isotope effects (KIEs), because a particle’s ability to tunnel decreases significantly with its increasing mass. Here we experimentally demonstrate that cold hydrogen (H) and deuterium (D) atoms can add to solid benzene by tunneling; however, the observed H/D KIE was very small (1–1.5) despite the large intrinsic H/D KIE of tunneling (≳100). This strong reduction is due to the chemical kinetics being controlled not by tunneling but by the surface diffusion of the H/D atoms, a process not greatly affected by the isotope type. Because tunneling need not be accompanied by a large KIE in surface and interfacial chemical systems, it might be overlooked in other systems such as aerosols or enzymes. Our results suggest that surface tunneling reactions on interstellar dust may contribute to the deuteration of interstellar aromatic and aliphatic hydrocarbons, which could represent a major source of the deuterium enrichment observed in carbonaceous meteorites and interplanetary dust particles. These findings could improve our understanding of interstellar physicochemical processes, including those during the formation of the solar system. PMID:26034285

Cometary Materials Originating from Interstellar Ices: Clues from Laboratory Experiments

NASA Astrophysics Data System (ADS)

Fresneau, A.; Abou Mrad, N.; d'Hendecourt, L. LS; Duvernay, F.; Flandinet, L.; Orthous-Daunay, F.-R.; Vuitton, V.; Thissen, R.; Chiavassa, T.; Danger, G.

2017-03-01

We use laboratory experiments to derive information on the chemistry occurring during the evolution of astrophysical ices from dense molecular clouds to interplanetary objects. Through a new strategy that consists of coupling very high resolution mass spectrometry and infrared spectroscopy (FT-IR), we investigate the molecular content of the organic residues synthesized from different initial ice compositions. We also obtain information on the evolution of the soluble part of the residues after their over-irradiation. The results give insight into the role of water ice as a trapping and diluting agent during the chemical evolution. They also give information about the importance of the amount of ammonia in such ices, particularly regarding its competition with the carbon chemistry. All of these results allow us to build a first mapping of the evolution of soluble organic matter based on its chemical and physical history. Furthermore, our results suggest that interstellar ices should lead to organic materials enriched in heteroatoms that present similarities with cometary materials but strongly differ from meteoritic organic material, especially in their C/N ratios.

Life and the Universe: From Astrochemistry to Astrobiology

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.

2013-01-01

Great strides have been made in our understanding of interstellar material thanks to advances in infrared astronomy and laboratory astrophysics. Ionized polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by earlier astrochemical standards, are widespread and very abundant throughout much of the cosmos. In cold molecular clouds, the birthplace of planets and stars, interstellar atoms and molecules freeze onto extremely cold dust and ice particles forming mixed molecular ices dominated by simple species such as water, methanol, ammonia, and carbon monoxide. Within these clouds, and especially in the vicinity of star and planet forming regions, these ices and PAHs are processed by ultraviolet light and cosmic rays forming hundreds of far more complex species, some of biogenic interest. Eventually, these are delivered to primordial planets by comets and meteorites. As these materials are the building blocks of comets and related to carbonaceous micrometeorites, they are likely to be important sources of complex organic materials delivered to habitable planets (including the primordial Earth) and their composition may be related to the origin of life. This talk will focus on the chemical evolution of these cosmic materials and their relevance to astrobiology.

Far-infrared investigations of a methanol clathrate hydrate - Implications for astronomical observations

NASA Technical Reports Server (NTRS)

Hudson, Reggie L.; Moore, Marla H.

1993-01-01

Observations of nonterrestrial clathrate hydrates are still lacking despite the fact that clathrates first were suggested to exist in cometary and interstellar ices over 40 years ago. Spectroscopy, the most direct method of astronomical detection, has been hampered by the similarity of clathrate hydrate spectra to those of unenclathrated guest molecules and solid H2O. We have prepared a methanol (CH3OH) clathrate hydrate, using a recently published procedure, and have investigated its far-infrared spectrum. The spectrum is quite different from that of either unenclathrated CH3OH or solid H2O and so should be of value in astronomical searches for this clathrate.

The Evolution of Interstellar Gas: Massive Stars and the Dispersal of Neutral Material

NASA Technical Reports Server (NTRS)

Federman, Steven R.

2003-01-01

We studied the effects of newly formed O and B stars on their surrounding interstellar material through a combination of observations and theoretical modeling. The observational data came from measurements of absorption seen in the spectra of background, newly formed stars. Particular attention was given to stellar radiation which converts molecular to atomic material. Laboratory data on absorption cross sections relevant to the analysis and interpretation of carbon monoxide formed part of the effort. The grant supported Postdoctoral Fellows, Drs. Min Yan and Yaron Sheffer, and a laboratory technician. Though the students themselves were not supported. one M.S. Thesis and two Ph.D. dissertations from the University of Toledo were based on the research done under the grant. The research accomplished under this grant led directly to other funded programs. An observing proposal to study the chemistry of diffuse molecular clouds in the Large and Small Magellanic Clouds with ESO s Very Large Telescope was another example of a successful outcome of my LTSA program.

Implications for Planetary System Formation from Interstellar Object 1I/2017 U1 (‘Oumuamua)

NASA Astrophysics Data System (ADS)

Trilling, David E.; Robinson, Tyler; Roegge, Alissa; Chandler, Colin Orion; Smith, Nathan; Loeffler, Mark; Trujillo, Chad; Navarro-Meza, Samuel; Glaspie, Lori M.

2017-12-01

The recently discovered minor body 1I/2017 U1 (‘Oumuamua) is the first known object in our solar system that is not bound by the Sun’s gravity. Its hyperbolic orbit (eccentricity greater than unity) strongly suggests that it originated outside our solar system; its red color is consistent with substantial space weathering experienced over a long interstellar journey. We carry out a simple calculation of the probability of detecting such an object. We find that the observed detection rate of 1I-like objects can be satisfied if the average mass of ejected material from nearby stars during the process of planetary formation is ˜20 Earth masses, similar to the expected value for our solar system. The current detection rate of such interstellar interlopers is estimated to be 0.2 yr-1, and the expected number of detections over the past few years is almost exactly one. When the Large Synoptic Survey Telescope begins its wide, fast, deep all-sky survey, the detection rate will increase to 1 yr-1. Those expected detections will provide further constraints on nearby planetary system formation through a better estimate of the number and properties of interstellar objects.

On the Detectability of the X 2A" HSS, HSO, and HOS Radicals in the Interstellar Medium

NASA Astrophysics Data System (ADS)

Fortenberry, Ryan C.; Francisco, Joseph S.

2017-02-01

{\\tilde{X}}2A\\prime\\prime HSS has yet to be observed in the gas phase in the interstellar medium (ISM). HSS has been observed in cometary material and in high abundance. However, its agglomeration to such bodies or dispersal from them has not been observed. Similarly, HSO and HOS have not been observed in the ISM, either, even though models support their formation from reactions of known sulfur monoxide and hydrogen molecules, among other pathways. Consequently, this work provides high-level, quantum chemical rovibrational spectroscopic constants and vibrational frequencies in order to assist in interstellar searches for these radical molecules. Furthermore, the HSO-HOS isomerization energy is determined to be 3.63 kcal mol-1, in line with previous work, and the dipole moment of HOS is 36% larger at 3.87 D than HSO, making the less stable isomer more rotationally intense. Finally, the S-S bond strength in HSS is shown to be relatively weak at 30% of the typical disulfide bond energy. Consequently, HSS may degrade into SH and sulfur atoms, making any ISM abundance of HSS likely fairly low, as recent interstellar surveys have observed.

Interstellar proteins and the discovery of a new absorption feature at lambda = 2800 A

NASA Astrophysics Data System (ADS)

Karim, L. M.; Hoyle, F.; Wickramasinghe, N. C.

1983-07-01

In order to check the presence of biogenic materials in interstellar grains, the spectra of three early-type, heavily reddened stars recorded by the IUE were examined. These stars showed comparatively weak absorption at 2200 A, minimizing the effect of graphite grains. A broad absorption feature centered on 2800 A is discovered in HD 14250 and interpreted to be due to the amino acid tryptophan. Comparison of the spectrum with that of the calculated extinction behavior of graphite spheres of radii 0.02 microns suggests that the latter are not responsible for the observed spectrum.

Interstellar PAH Analogs in the Laboratory: Comparison with Astronomical Data

NASA Technical Reports Server (NTRS)

Salama, Farid

2005-01-01

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. PAHs are the best-known candidates to account for the IR emission bands (UIR bands) and PAH spectral features are now being used as new probes of the ISM. PAHs are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). In the model dealing with the interstellar spectral features, PAHs are present as a mixture of radicals, ions and neutral species. PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge for laboratory astrophysics is to reproduce (in a realistic way) the physical conditions that exist in the emission and/or absorption interstellar zones. An extensive laboratory program has been developed at NASA Ames to assess the physical and chemical properties of PAHs in such environments and to describe how they influence the radiation and energy balance in space and the interstellar chemistry. In particular, laboratory experiments provide measurements of the spectral characteristics of interstellar PAH analogs from the ultraviolet and visible range to the infrared range for comparison with astronomical data. This paper will focus on the recent progress made in the laboratory to measure the direct absorption spectra of neutral and ionized PAHs in the near-UV and visible range. Intrinsic band profiles and band positions of cold gas-phase PAHs can now be measured with high-sensitivity spectroscopy and directly compared to the astronomical data. Preliminary conclusions from the comparison of the laboratory data with astronomical observations will also be presented.

ION IRRADIATION OF ETHANE AND WATER MIXTURE ICE AT 15 K: IMPLICATIONS FOR THE SOLAR SYSTEM AND THE ISM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barros, A. L. F. de; Silveira, E. F da; Fulvio, D.

2016-06-20

Solid water has been observed on the surface of many different astronomical objects and is the dominant ice present in the universe, from the solar system (detected on the surface of some asteroids, planets and their satellites, trans-Neptunian objects [TNOs], comets, etc.) to dense cold interstellar clouds (where interstellar dust grains are covered with water-rich ices). Ethane has been detected across the solar system, from the atmosphere of the giant planets and the surface of Saturn’s satellite Titan to various comets and TNOs. To date, there were no experiments focused on icy mixtures of C{sub 2}H{sub 6} and H{sub 2}Omore » exposed to ion irradiation simulating cosmic rays, a case study for many astronomical environments in which C{sub 2}H{sub 6} has been detected. In this work, the radiolysis of a C{sub 2}H{sub 6}:H{sub 2}O (2:3) ice mixture bombarded by a 40 MeV{sup 58}Ni{sup 11+} ion beam is studied. The chemical evolution of the molecular species existing in the sample is monitored by a Fourier transform infrared spectrometer. The analysis of ethane, water, and molecular products in solid phase was performed. Induced chemical reactions in C{sub 2}H{sub 6}:H{sub 2}O ice produce 13 daughter molecular species. Their formation and dissociation cross sections are determined. Furthermore, atomic carbon, oxygen, and hydrogen budgets are determined and used to verify the stoichiometry of the most abundantly formed molecular species. The results are discussed in the view of solar system and interstellar medium chemistry. The study presented here should be regarded as a first step in laboratory works dedicated to simulate the effect of cosmic radiation on multicomponent mixtures involving C{sub 2}H{sub 6} and H{sub 2}O.« less

Reactions of Ground State Nitrogen Atoms N(4S) with Astrochemically-Relevant Molecules on Interstellar Dusts

NASA Astrophysics Data System (ADS)

Krim, Lahouari; Nourry, Sendres

2015-06-01

In the last few years, ambitious programs were launched to probe the interstellar medium always more accurately. One of the major challenges of these missions remains the detection of prebiotic compounds and the understanding of reaction pathways leading to their formation. These complex heterogeneous reactions mainly occur on icy dust grains, and their studies require the coupling of laboratory experiments mimicking the extreme conditions of extreme cold and dilute media. For that purpose, we have developed an original experimental approach that combine the study of heterogeneous reactions (by exposing neutral molecules adsorbed on ice to non-energetic radicals H, OH, N...) and a neon matrix isolation study at very low temperatures, which is of paramount importance to isolate and characterize highly reactive reaction intermediates. Such experimental approach has already provided answers to many questions raised about some astrochemically-relevant reactions occurring in the ground state on the surface of dust grain ices in dense molecular clouds. The aim of this new present work is to show the implication of ground state atomic nitrogen on hydrogen atom abstraction reactions from some astrochemically-relevant species, at very low temperatures (3K-20K), without providing any external energy. Under cryogenic temperatures and with high barrier heights, such reactions involving N(4S) nitrogen atoms should not occur spontaneously and require an initiating energy. However, the detection of some radicals species as byproducts, in our solid samples left in the dark for hours at 10K, proves that hydrogen abstraction reactions involving ground state N(4S) nitrogen atoms may occur in solid phase at cryogenic temperatures. Our results show the efficiency of radical species formation stemming from non-energetic N-atoms and astrochemically-relevant molecules. We will then discuss how such reactions, involving nitrogen atoms in their ground states, might be the first key step towards complex organic molecules production in the interstellar medium.

IRAS Colors of the Pleiades

NASA Technical Reports Server (NTRS)

Carey, Sean J.; Shipman, R. F.; Clark, F. O.

1996-01-01

We present large scale images of the infrared emission of the region around the Pleiades using the ISSA data product from the IRAS mission. Residual Zodiacal background and a discontinuity in the image due to the scanning strategy of the satellite necessitated special background subtraction methods. The 60/100 color image clearly shows the heating of the ambient interstellar medium by the cluster. The 12/100 and 25/100 images peak on the cluster as expected for exposure of small dust grains to an enhanced UV radiation field; however, the 25/100 color declines to below the average interstellar value at the periphery of the cluster. Potential causes of the color deficit are discussed. A new method of identifying dense molecular material through infrared emission properties is presented. The difference between the 100 micron flux density and the 60 micron flux density scaled by the average interstellar 60/100 color ratio (Delta I(sub 100) is a sensitive diagnostic of material with embedded heating sources (Delta I(sub 100) less than 0) and cold, dense cores (Delta I(sub 100) greater than 0). The dense cores of the Taurus cloud complex as well as Lynds 1457 are clearly identified by this method, while the IR bright but diffuse Pleiades molecular cloud is virtually indistinguishable from the nearby infrared cirrus.

CaFe interstellar clouds

NASA Astrophysics Data System (ADS)

Bondar, A.; Kozak, M.; Gnaciński, P.; Galazutdinov, G. A.; Beletsky, Y.; Krełowski, J.

2007-07-01

A new kind of interstellar cloud is proposed. These are rare (just a few examples among ~300 lines of sight) objects with the CaI 4227-Å, FeI 3720-Å and 3860-Å lines stronger than those of KI (near 7699 Å) and NaI (near 3302 Å). We propose the name `CaFe' for these clouds. Apparently they occupy different volumes from the well-known interstellar HI clouds where the KI and ultraviolet NaI lines are dominant features. In the CaFe clouds we have not found either detectable molecular features (CH, CN) or diffuse interstellar bands which, as commonly believed, are carried by some complex, organic molecules. We have found the CaFe clouds only along sightlines toward hot, luminous (and thus distant) objects with high rates of mass loss. In principle, the observed gas-phase interstellar abundances reflect the combined effects of the nucleosynthetic history of the material, the depletion of heavy elements into dust grains and the ionization state of these elements which may depend on irradiation by neighbouring stars. Based on data collected using the Maestro spectrograph at the Terskol 2-m telescope, Russia; and on data collected using the ESO Feros spectrograph; and on data obtained from the ESO Science Archive Facility acquired with the UVES spectrograph, Chile. E-mail: `arctur'@rambler.ru (AB); marizak@astri.uni.torun.pl (MK); pg@iftia.univ.gda.pl (PG); gala@boao.re.kr (GAG); ybialets@eso.org (YB); jacek@astri.uni.torun.pl (JK)

Carbonaceous Components in the Comet Halley Dust

NASA Technical Reports Server (NTRS)

Fomenkova, M. N.; Chang, S.; Mukhin, L. M.

1994-01-01

Cometary grains containing large amounts of carbon and/or organic matter (CHON) were discovered by in situ measurements of comet Halley dust composition during VEGA and GIOTTO flyby missions. In this paper, we report the classification of these cometary, grains by means of cluster analysis, discuss the resulting compositional groups, and compare them with substances observed or hypothesized in meteorites, interplanetary dust particles, and the interstellar medium. Grains dominated by carbon and/or organic matter (CHON grains) represent approx. 22% of the total population of measured cometary dust particles. They, usually contain a minor abundance of rock-forming elements as well. Grains having organic material are relatively more abundant in the vicinity of the nucleus than in the outer regions of the coma, which suggests decomposition of the organics in the coma environment. The majority of comet Halley organic particles are multicomponent mixtures of carbon phases and organic compounds. Possibly, the cometary CHON grains may be related to kerogen material of an interstellar origin in carbonaceous meteorites. Pure carbon grains, hydrocarbons and polymers of cyanopolyynes, and multi-carbon monoxides are present in cometary dust as compositionally simple and distinctive components among a variety of others. There is no clear evidence of significant presence of pure formaldehyde or HCN polymers in Halley dust particles. The diversity of types of cometary organic compounds is consistent with the inter-stellar dust model of comets and probably reflects differences in composition of precursor dust. Preservation of this heterogeneity among submicron particles suggest the gentle formation of cometary, nucleus by aggregation of interstellar dust in the protosolar nebula without complete mixing or chemical homogenization at the submicron level.

Kinetic Monte Carlo simulations of water ice porosity: extrapolations of deposition parameters from the laboratory to interstellar space.

PubMed

Clements, Aspen R; Berk, Brandon; Cooke, Ilsa R; Garrod, Robin T

2018-02-21

Dust grains in cold, dense interstellar clouds build up appreciable ice mantles through the accretion and subsequent surface chemistry of atoms and molecules from the gas. These mantles, of thicknesses on the order of 100 monolayers, are primarily composed of H 2 O, CO, and CO 2 . Laboratory experiments using interstellar ice analogues have shown that porosity could be present and can facilitate diffusion of molecules along the inner pore surfaces. However, the movement of molecules within and upon the ice is poorly described by current chemical kinetics models, making it difficult either to reproduce the formation of experimental porous ice structures or to extrapolate generalized laboratory results to interstellar conditions. Here we use the off-lattice Monte Carlo kinetics model MIMICK to investigate the effects that various deposition parameters have on laboratory ice structures. The model treats molecules as isotropic spheres of a uniform size, using a Lennard-Jones potential. We reproduce experimental trends in the density of amorphous solid water (ASW) for varied deposition angle, rate and surface temperature; ice density decreases when the incident angle or deposition rate is increased, while increasing temperature results in a more-compact water ice. The models indicate that the density behaviour at higher temperatures (≥80 K) is dependent on molecular rearrangement resulting from thermal diffusion. To reproduce trends at lower temperatures, it is necessary to take account of non-thermal diffusion by newly-adsorbed molecules, which bring kinetic energy both from the gas phase and from their acceleration into a surface binding site. Extrapolation of the model to conditions appropriate to protoplanetary disks, in which direct accretion of water from the gas-phase may be the dominant ice formation mechanism, indicate that these ices may be less porous than laboratory ices.

Photochemistry of PAHs in cosmic water ice. The effect of concentration on UV-VIS spectroscopy and ionization efficiency

NASA Astrophysics Data System (ADS)

Cuylle, Steven H.; Allamandola, Louis J.; Linnartz, Harold

2014-02-01

Context. Observations and models show that polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in the interstellar medium. Like other molecules in dense clouds, PAHs accrete onto interstellar dust grains, where they are embedded in an ice matrix dominated by water. In the laboratory, mixed molecular ices (not containing PAHs) have been extensively studied using Fourier transform infrared absorption spectroscopy. Experiments including PAHs in ices have started, however, the concentrations used are typically much higher than the concentrations expected for interstellar ices. Optical spectroscopy offers a sensitive alternative. Aims: We report an experimental study of the effect PAH concentration has on the electronic spectra and the vacuum UV (VUV) driven processes of PAHs in water-rich ices. The goal is to apply the outcome to cosmic ices. Methods: Optical spectroscopic studies allow us to obtain in-situ and quasi real-time electronic solid state spectra of two prototypical PAHs (pyrene and coronene) embedded in water ice under VUV photoprocessing. The study is carried out on PAH:H2O concentrations in the range of 1:30 000 to pure PAH, covering the temperature range from 12 to 125 K. Results: PAH concentration strongly influences the efficiency of PAH cation formation. At low concentrations, ionization efficiencies are over 60% dropping to about 15% at 1:1000. Increasing the PAH concentration reveals spectral broadening in neutral and cation PAH spectra attributed to PAH clustering inside the ice. At the PAH concentrations expected for interstellar ices, some 10 to 20% may be present as cations. The presence of PAHs in neutral and ion form will add distinctive absorption bands to cosmic ice optical spectra and this may serve as a tool to determine PAH concentrations.

Organic chemistry in space

NASA Technical Reports Server (NTRS)

Johnson, R. D.

1977-01-01

Organic cosmochemistry, organic materials in space exploration, and biochemistry of man in space are briefly surveyed. A model of Jupiter's atmosphere is considered, and the search for organic molecules in the solar system and in interstellar space is discussed. Materials and analytical techniques relevant to space exploration are indicated, and the blood and urine analyses performed on Skylab are described.

Workshop on Cometary Dust in Astrophysics

NASA Technical Reports Server (NTRS)

2003-01-01

The paper include contribution of each Lunar and Planetary Institute. Contents include the following: Mass flux in the ancient Earth-Moon system and benign implications for the origin of life on Earth. In-situ analysis of complex organic matter in cometary dust by ion microprobe. Pristine presolar silicon carbide. Infrared spectra of melilite solid solution. Comet observations with SIRTF. Ice and carbon chemistry in comets. The nature in interstellar dust. Modeling the infrared emission from protoplanetary dust disks.

The Chemical Composition and Gas-to-Dust Mass Ratio of Nearby Interstellar Matter

NASA Technical Reports Server (NTRS)

Frisch, Priscilla C.; Slavin, Jonathan D.

2003-01-01

We use recent results on interstellar gas toward nearby stars and interstellar by-products within the solar system to select among the equilibrium radiative transfer models of the nearest interstellar material presented in Slavin & Frisch. For the assumption that O/H - 400 parts per million, models 2 and 8 are found to yield good fits to available data on interstellar material inside and outside of the heliosphere, with the exception of the Ne abundance in the pickup ion and anomalous cosmic-ray populations. For these models, the interstellar medium (ISM) at the entry point to the heliosphere has n(H(sup 0)) = 0.202-0.208/cu cm, n(He(sup 0) = 0.0137-0.0152/cu cm, and ionizations X(H) = 0.29-0.30, X(He) = 0.47-0.51. These best models suggest that the chemical composition of the nearby ISM is approx.60%-70% subsolar if S is undepleted. Both H(0) and H(+) need to be included when evaluating abundances of ions found in warm diffuse clouds. Models 2 and 8 yield an H filtration factor of approx.0.46. Gas-to-dust mass ratios for the ISM toward epsilon CMa are R(sub gd) = 178-183 for solar abundances of Holweger or R(sub gd) = 611-657 for an interstellar abundance standard 70% solar. Direct observations of dust grains in the solar system by Ulysses and Galileo yield R(sub gd) appr0x. 115 for models 2 and 8, supporting earlier results (Frisch and coworkers). If the local ISM abundances are subsolar, then gas and dust are decoupled over small spatial scales. The inferred variation in R(sub gd) over parsec length scales is consistent with the fact that the ISM near the Sun is part of a dynamically active cluster of cloudlets flowing away from the Sco-Cen association. Observations toward stars within approx.500 pc show that R(sub gd) correlates with the percentage of the dust mass that is carried by iron, suggesting that an Fe-rich grain core (by mass) remains after grain destruction. Evidently large dust grains (>10(exp -13) g) and small dust grains (<10(exp -13) g) are not well mixed over parsec length spatial scales in the ISM. It also appears that very small C-dominated dust grains have been destroyed in the ISM within several parsecs of the Sun, since C appears to be essentially undepleted. However, if gas-dust coupling breaks down over the cloud lifetime, the missing mass arguments applied here to determine R(sub gd) and dust grain mineralogy are not appropriate.

Cosmic-Ray Source Composition Determined from ACE

NASA Technical Reports Server (NTRS)

Wiedenbeck, M.

2000-01-01

The cosmic rays arriving at Earth comprise a mix of material produced by stellar sources and ejected into the interstellar medium (primary cosmic rays) and particles produced by fragmentation of heavier nuclei during transport through the Galaxy.

Summative Evaluation Findings from the Interstellar Boundary Explorer (IBEX) Education and Public Outreach Program

NASA Astrophysics Data System (ADS)

Bartolone, L.; Nichols-Yehling, M.; Davis, H. B.; Davey, B.

2014-07-01

The Interstellar Boundary Explorer mission includes a comprehensive Education and Public Outreach (EPO) program in heliophysics that is overseen and implemented by the Adler Planetarium and evaluated by Technology for Learning Consortium, Inc. Several components of the IBEX EPO program were developed during the prime phase of the mission that were specifically designed for use in informal institutions, especially museums and planetaria. The program included a widely distributed planetarium show with accompanying informal education activities, printed posters, lithographs and other resources, funding for the development of the GEMS Space Science Sequence for Grades 6-8 curriculum materials, development of the IBEX mission website, development of materials for people with special needs, participation in the Heliophysics Educator Ambassador program, and support for the Space Explorers Afterschool Science Club for Chicago Public Schools. In this paper, we present an overview of the IBEX EPO program summative evaluation techniques and results for 2008 through 2012.

Survival of carbon grains in shocks

NASA Technical Reports Server (NTRS)

Seab, C. Gregory

1990-01-01

Supernova shocks play a significant part in the life of an interstellar grain. In a typical 10 to the 9th power year lifetime, a grain will be hit by an average of 10 shocks of 100 km s(sup -1) or greater velocity, and even more shocks of lower velocity. Evaluation of the results of this frequent shock processing is complicated by a number of uncertainties, but seems to give about 10 percent destruction of silicate grains and about half that for graphite grains. Because of the frequency of shocking, the mineralogy and sizes of the grain population is predominately determined by shock processing effects, and not by the initial grain nucleation and growth environment. One consequence of the significant role played by interstellar shocks is that a certain fraction (up to 5 percent) of the carbon should be transformed into the diamond phase. Diamond transformation is observed in the laboratory at threshold shock pressures easily obtainable in grain-grain collisions in supernova shocks. Yields for transforming graphite, amorphous carbon, glassy carbon, and other nearly pure carbon solids into diamond are quite high. Impurities up to at least the 10 percent level (for oxygen) are tolerated in the process. The typical size diamond expected from shock transformation agrees well with the observed sizes in the Lewis et al. findings in meteoritic material. Isotropic anomalies already contained in the grain are likely to be retained through the conversion process, while others may be implanted by the shock if the grain is close to the supernova. The meteoritic diamonds are likely to be the results of transformation of carbon grains in grain-grain collisions in supernova shock waves.

The formation of stellar systems from interstellar molecular clouds

NASA Technical Reports Server (NTRS)

Gehrz, R. D.; Black, D. C.; Solomon, P.M.

1984-01-01

The observational and theoretical study of regions of continuing star formation promises greater insight into the physical conditions and events associated with the formation of the solar system, and elucidates the role played by star formation in the evolutionary cycle which seems to dominate interstellar material's processing by successive generations of stars in the spiral galaxies. Novel astronomical methods incorporated by the new facilities scheduled for development in the 1980s may yield substantial advancements in star formation process theory; most significant among these efforts will be the identification and examination of the elusive protostellar collapse phase of both star and planetary system formation.

Efficient surface formation route of interstellar hydroxylamine through NO hydrogenation. II. The multilayer regime in interstellar relevant ices

NASA Astrophysics Data System (ADS)

Fedoseev, G.; Ioppolo, S.; Lamberts, T.; Zhen, J. F.; Cuppen, H. M.; Linnartz, H.

2012-08-01

Hydroxylamine (NH2OH) is one of the potential precursors of complex pre-biotic species in space. Here, we present a detailed experimental study of hydroxylamine formation through nitric oxide (NO) surface hydrogenation for astronomically relevant conditions. The aim of this work is to investigate hydroxylamine formation efficiencies in polar (water-rich) and non-polar (carbon monoxide-rich) interstellar ice analogues. A complex reaction network involving both final (N2O, NH2OH) and intermediate (HNO, NH2O., etc.) products is discussed. The main conclusion is that hydroxyl-amine formation takes place via a fast and barrierless mechanism and it is found to be even more abundantly formed in a water-rich environment at lower temperatures. In parallel, we experimentally verify the non-formation of hydroxylamine upon UV photolysis of NO ice at cryogenic temperatures as well as the non-detection of NC- and NCO-bond bearing species after UV processing of NO in carbon monoxide-rich ices. Our results are implemented into an astrochemical reaction model, which shows that NH2OH is abundant in the solid phase under dark molecular cloud conditions. Once NH2OH desorbs from the ice grains, it becomes available to form more complex species (e.g., glycine and β-alanine) in gas phase reaction schemes.

The interstellar boundary explorer (IBEX): Update at the end of phase B

NASA Astrophysics Data System (ADS)

McComas, D. J.; Allegrini, F.; Bartolone, L.; Bochsler, P.; Bzowski, M.; Collier, M.; Fahr, H.; Fichtner, H.; Frisch, P.; Funsten, H.; Fuselier, Steve; Gloeckler, G.; Gruntman, M.; Izmodenov, V.; Knappenberger, P.; Lee, M.; Livi, S.; Mitchell, D.; Möbius, E.; Moore, T.; Pope, S.; Reisenfeld, D.; Roelof, E.; Runge, H.; Scherrer, J.; Schwadron, N.; Tyler, R.; Wieser, M.; Witte, M.; Wurz, P.; Zank, G.

2006-09-01

The Interstellar Boundary Explorer (IBEX) mission will make the first global observations of the heliosphere's interaction with the interstellar medium. IBEX achieves these breakthrough observations by traveling outside of the Earth's magnetosphere in a highly elliptical orbit and taking global Energetic Neutral Atoms (ENA) images over energies from ~10 eV to 6 keV. IBEX's high-apogee (~50 RE) orbit enables heliospheric ENA measurements by providing viewing from far above the Earth's relatively bright magnetospheric ENA emissions. This high energy orbit is achieved from a Pegasus XL launch vehicle by adding the propulsion from an IBEX-supplied solid rocket motor and the spacecraft's hydrazine propulsion system. IBEX carries two very large-aperture, single-pixel ENA cameras that view perpendicular to the spacecraft's Sun-pointed spin axis. Each six months, the continuous spinning of the spacecraft and periodic re-pointing to maintain the sun-pointing spin axis naturally lead to global, all-sky images. Over the course of our NASA Phase B program, the IBEX team optimized the designs of all subsystems. In this paper we summarize several significant advances in both IBEX sensors, our expected signal to noise (and background), and our groundbreaking approach to achieve a very high-altitude orbit from a Pegasus launch vehicle for the first time. IBEX is in full scale development and on track for launch in June of 2008.

Infrared Observations of Hot Gas and Cold Ice Toward the Low Mass Protostar Elias 29

NASA Technical Reports Server (NTRS)

Boogert, A. C. A.; Tielens, A. G. G. M.; Ceccarelli, C.; Boonman, A. M. S.; vanDishoeck, E. F.; Keane, J. V.; Whittet, D. C. B.; deGraauw, T.

2000-01-01

We have obtained the full 1-200 micrometer spectrum of the low luminosity (36 solar luminosity Class I protostar Elias 29 in the rho Ophiuchi molecular cloud. It provides a unique opportunity to study the origin and evolution of interstellar ice and the interrelationship of interstellar ice and hot core gases around low mass protostars. We see abundant hot CO and H2O gas, as well as the absorption bands of CO, CO2, H2O and "6.85 micrometer" ices. We compare the abundances and physical conditions of the gas and ices toward Elias 29 with the conditions around several well studied luminous, high mass protostars. The high gas temperature and gas/solid ratios resemble those of relatively evolved high mass objects (e.g. GL 2591). However, none of the ice band profiles shows evidence for significant thermal processing, and in this respect Elias 29 resembles the least evolved luminous protostars, such as NGC 7538 : IRS9. Thus we conclude that the heating of the envelope of the low mass object Elias 29 is qualitatively different from that of high mass protostars. This is possibly related to a different density gradient of the envelope or shielding of the ices in a circumstellar disk. This result is important for our understanding of the evolution of interstellar ices, and their relation to cometary ices.

Prebiotic chemical evolution in the astrophysical context.

PubMed

Ziurys, L M; Adande, G R; Edwards, J L; Schmidt, D R; Halfen, D T; Woolf, N J

2015-06-01

An ever increasing amount of molecular material is being discovered in the interstellar medium, associated with the birth and death of stars and planetary systems. Radio and millimeter-wave astronomical observations, made possible by high-resolution laboratory spectroscopy, uniquely trace the history of gas-phase molecules with biogenic elements. Using a combination of both disciplines, the full extent of the cycling of molecular matter, from circumstellar ejecta of dying stars - objects which expel large amounts of carbon - to nascent solar systems, has been investigated. Such stellar ejecta have been found to exhibit a rich and varied chemical content. Observations demonstrate that this molecular material is passed onto planetary nebulae, the final phase of stellar evolution. Here the star sheds almost its entire original mass, becoming an ultraviolet-emitting white dwarf. Molecules such as H2CO, HCN, HCO(+), and CCH are present in significant concentrations across the entire age span of such nebulae. These data suggest that gas-phase polyatomic, carbon-containing molecules survive the planetary nebula phase and subsequently are transported into the interstellar medium, seeding the chemistry of diffuse and then dense clouds. The extent of the chemical complexity in dense clouds is unknown, hindered by the high spectral line density. Organic species such as acetamide and methyl amine are present in such objects, and NH2CHO has a wide Galactic distribution. However, organophosphorus compounds have not yet been detected in dense clouds. Based on carbon and nitrogen isotope ratios, molecular material from the ISM appears to become incorporated into solar system planetesimals. It is therefore likely that interstellar synthesis influences prebiotic chemistry on planet surfaces.

Laboratory Studies of Extraterrestrial Ices and PAHs: Making an Astrobiological Silk Purse Out of An Interstellar Sow's Ear

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; DeVincenzi, Donald (Technical Monitor)

2002-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Today, the composition of dust in the ISM is reasonably well constrained to cold, micron-sized particles of various refractory materials. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these particles secrete mantles of mixed molecular lees whose major components are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), whose telltale infrared signature I is now recognized throughout the Universe. However, of what significance is this scenario to the origin of life in our solar system--or any other? The major components of the icy materials observed in interstellar clouds and in our own solar system are uniformly quite simple. In addition, despite the fact that PAHs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which these materials can be transformed into more biochemically significant structures, they are of little Astrobiological significance. In this talk, we will begin with a brief review of the nature and abundance of the "raw" population of PAHs and PAH-related materials in the ISM. From there, we will move on to explore our laboratory simulations of the photochemical evolution of realistic mixed molecular ices under conditions which simulate those encountered in the ISM and in evolving planetary systems. Particular attention will be paid to the surprisingly complex array of organic species that are produced in these ices from such a deceptively simple inventory of starting materials. In addition, we will explore the chemistry of PAHs under these conditions and consider its potential for transforming that rich repository of pre-biotic organic "ore" into materials of greater importance to Astrobiology.

A survey of the properties of early-type galaxies

NASA Technical Reports Server (NTRS)

Bregman, Joel N.; Roberts, M. S.; Hogg, D. E.

1990-01-01

A compilation of the properties of elliptical and early disk galaxies was completed. In addition to material from the literature, such as Infrared Astronomy Satellite (IRAS) fluxes, the compilation includes recent measurements of HI and CO, as well as a review of the x ray properties by Forman and Jones. The data are used to evaluate the gas content of early systems and to search for correlations with x ray emission. The interstellar medium in early-type galaxies is generally dominated by hot interstellar gas (T approx. 10 to the 7th power K; c.f. the review by Fabbiano 1989 and references therein). In addition, a significant fraction of these galaxies show infrared emission (Knapp, et al., 1989), optical emission lines, and visible dust. Sensitive studies in HI and CO of a number of these galaxies have been completed recently, resulting in several detections, particularly of the later types. Researchers wish to understand the connection among these different forms of the interstellar medium, and to examine the theoretical picture of the fate of the hot gas. To do so, they compiled observations of several forms of interstellar matter for a well-defined sample of early-type galaxies. Here they present a statistical analysis of this data base and discuss the implications of the results.

Interferometric observations of large biologically interesting interstellar and cometary molecules

PubMed Central

Snyder, Lewis E.

2006-01-01

Interferometric observations of high-mass regions in interstellar molecular clouds have revealed hot molecular cores that have substantial column densities of large, partly hydrogen-saturated molecules. Many of these molecules are of interest to biology and thus are labeled “biomolecules.” Because the clouds containing these molecules provide the material for star formation, they may provide insight into presolar nebular chemistry, and the biomolecules may provide information about the potential of the associated interstellar chemistry for seeding newly formed planets with prebiotic organic chemistry. In this overview, events are outlined that led to the current interferometric array observations. Clues that connect this interstellar hot core chemistry to the solar system can be found in the cometary detection of methyl formate and the interferometric maps of cometary methanol. Major obstacles to understanding hot core chemistry remain because chemical models are not well developed and interferometric observations have not been very sensitive. Differentiation in the molecular isomers glycolaldehdye, methyl formate, and acetic acid has been observed, but not explained. The extended source structure for certain sugars, aldehydes, and alcohols may require nonthermal formation mechanisms such as shock heating of grains. Major advances in understanding the formation chemistry of hot core species can come from observations with the next generation of sensitive, high-resolution arrays. PMID:16894168

Interstellar Lithium and Rubidium in the Diffuse Gas Near IC 443

NASA Astrophysics Data System (ADS)

Ritchey, Adam M.; Taylor, C. J.; Federman, S. R.; Lambert, D. L.

2011-01-01

We present an analysis of interstellar lithium and rubidium from observations made with the Hobby-Eberly Telescope at McDonald Observatory of the Li I λ6707 and Rb I λ7800 absorption lines along four lines of sight through the supernova remnant IC 443. The observations probe interstellar material polluted by the ejecta of a core-collapse (Type II) supernova and can thus be used to constrain the contribution from massive stars to the synthesis of lithium and rubidium. Production of 7Li is expected to occur through neutrino spallation in the helium and carbon shells of the progenitor star during the terminal supernova explosion, while both 6Li and 7Li are synthesized via spallation and fusion reactions involving cosmic rays accelerated by the remnant. Gamma-ray emission from IC 443 provides strong evidence for the interaction of accelerated cosmic rays with the ambient atomic and molecular gas. Rubidium is also produced by massive stars through the weak s-process in the He- and C-burning shells and the r-process during core collapse. We examine interstellar 7Li/6Li isotope ratios as well as Li/K and Rb/K ratios along each line of sight, and discuss the implications of our results in the context of nucleosynthesis associated with Type II supernovae.

The third flight of CHESS: Preliminary analysis of interstellar H2 on the β1 Sco sightline

NASA Astrophysics Data System (ADS)

Kruczek, Nick; France, Kevin

2018-01-01

We describe the scientific motivation and technical development of the Colorado High-resolution Echelle Stellar Spectrograph (CHESS), focusing on the preliminary science results for the third launch of the payload (CHESS-3). CHESS is a far ultraviolet rocket-borne instrument designed to study the atomic-to-molecular transitions within translucent cloud regions in the interstellar medium. CHESS is an objective echelle spectrograph, which uses a mechanically-ruled echelle and a powered (f/12.4) cross-dispersing grating, and is designed to achieve a resolving power R > 100,000 over the band pass λλ 1000-1600 Å. CHESS-3 launched on 14 June 2017 aboard NASA/CU sounding rocket mission 36.323 UG. The target for the flight was β1 Sco, a B1V star with a sightline that is likely sampling translucent material. We present flight results of interstellar molecular hydrogen excitation, including initial measurements of the column density and temperature, on the sightline.

KSC-08pd1685

NASA Image and Video Library

2008-04-30

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, workers check the movement of the wing toward the Pegasus XL launch vehicle. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

KSC-08pd2410

NASA Image and Video Library

2008-07-30

VANDENBERG AIR FORCE BASE, Calif. – At Vandenberg Air Force Base in California, technicians follow the movement of NASA's Interstellar Boundary Explorer, or IBEX, mission spacecraft toward the mobile stand in the foreground. The IBEX satellite will make the first map of the boundary between the Solar System and interstellar space. IBEX is the first mission designed to detect the edge of the Solar System. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the Solar System and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the Solar System that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. IBEX is targeted for launch from the Pegasus XL rocket on Oct. 5. Photo credit: NASA

Deuterium enrichment of polycyclic aromatic hydrocarbons by photochemically induced exchange with deuterium-rich cosmic ices

NASA Technical Reports Server (NTRS)

Sandford, S. A.; Bernstein, M. P.; Allamandola, L. J.; Gillette, J. S.; Zare, R. N.

2000-01-01

The polycyclic aromatic hydrocarbon (PAH) coronene (C24H12) frozen in D2O ice in a ratio of less than 1 part in 500 rapidly exchanges its hydrogen atoms with the deuterium in the ice at interstellar temperatures and pressures when exposed to ultraviolet radiation. Exchange occurs via three different chemical processes: D atom addition, D atom exchange at oxidized edge sites, and D atom exchange at aromatic edge sites. Observed exchange rates for coronene (C24H12)-D2O and d12-coronene (C24D12)-H2O isotopic substitution experiments show that PAHs in interstellar ices could easily attain the D/H levels observed in meteorites. These results may have important consequences for the abundance of deuterium observed in aromatic materials in the interstellar medium and in meteorites. These exchange mechanisms produce deuteration in characteristic molecular locations on the PAHs that may distinguish them from previously postulated processes for D enrichment of PAHs.

Molecular and mass spectroscopic analysis of isotopically labeled organic residues

NASA Technical Reports Server (NTRS)

Mendoza-Gomez, Celia X.; Greenberg, J. Mayo; Mccain, P.; Ferris, J. P.; Briggs, R.; Degroot, M. S.; Schutte, Willem A.

1989-01-01

Experimental studies aimed at understanding the evolution of complex organic molecules on interstellar grains were performed. The photolysis of frozen gas mixtures of various compositions containing H2O, CO, NH3, and CH4 was studied. These species were chosen because of their astrophysical importance as deducted from observational as well as theoretical studies of ice mantles on interstellar grains. These ultraviolet photolyzed ices were warmed up in order to produce refractory organic molecules like the ones formed in molecular clouds when the icy mantles are being irradiated and warmed up either by a nearby stellar source or impulsive heating. The laboratory studies give estimates of the efficiency of production of such organic material under interstellar conditions. It is shown that the gradual carbonization of organic mantles in the diffuse cloud phase leads to higher and higher visual absorptivity - yellow residues become brown in the laboratory. The obtained results can be applied to explaining the organic components of comets and their relevance to the origin of life.

KSC-08pd2409

NASA Image and Video Library

2008-07-30

VANDENBERG AIR FORCE BASE, Calif. – At Vandenberg Air Force Base in California, technicians prepare a mobile stand to receive NASA's Interstellar Boundary Explorer, or IBEX, mission spacecraft. The IBEX satellite will make the first map of the boundary between the Solar System and interstellar space. IBEX is the first mission designed to detect the edge of the Solar System. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the Solar System and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the Solar System that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. IBEX is targeted for launch from the Pegasus XL rocket on Oct. 5. Photo credit: NASA

KSC-08pd1682

NASA Image and Video Library

2008-04-30

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, workers help guide a wing toward the Pegasus XL launch vehicle for a fit check. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

KSC-08pd1677

NASA Image and Video Library

2008-04-28

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, the wings of the Pegasus XL launch vehicle are checked for fit. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

KSC-08pd1686

NASA Image and Video Library

2008-04-30

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, workers check the fit of the wing on the Pegasus XL launch vehicle. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

KSC-08pd1683

NASA Image and Video Library

2008-04-30

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, workers help guide a wing toward the Pegasus XL launch vehicle in the background for a fit check. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

KSC-08pd1676

NASA Image and Video Library

2008-04-28

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, the wings of the Pegasus XL launch vehicle are checked for fit. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

KSC-08pd1684

NASA Image and Video Library

2008-04-30

VANDENBERG AIR FORCE BASE, Calif. – In Building 1555, workers help guide a wing toward the Pegasus XL launch vehicle in the background for a fit check. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. Photo credit: NASA/Randy Beaudoin

Constraints on cosmic silicates

NASA Astrophysics Data System (ADS)

Ossenkopf, V.; Henning, Th.; Mathis, J. S.

1992-08-01

Observational determinations of opacities of circumstellar silicates, relative to the peak value near 10 microns, are used to estimate the optical constants n and k, the real and imaginary parts of the index of refraction. Circumstellar dust is modified by processing within the interstellar medium. This leads to higher band strengths and a somewhat larger ratio of the opacities at the 18 and 10-micron peaks, compared with circumstellar silicates. By using an effective-medium theory, we calculate the effects of small spherical inclusions of various materials (various oxides, sulfides, carbides, amorphous carbon, and metallic iron) upon silicate opacities. Some of these can increase the absorption coefficient k in the 2-8 micron region appreciably, as is needed to reconcile laboratory silicate opacities with observations of both the interstellar medium and envelopes around late-type stars. We give tables of two sets of optical constants for warm oxygen-deficient and cool oxygen-rich silicates, representative for circumstellar and interstellar silicates. The required opacity in the 2-8 micron region is provided by iron and magnetite.

Experimental evidence for glycolaldehyde and ethylene glycol formation by surface hydrogenation of CO molecules under dense molecular cloud conditions

NASA Astrophysics Data System (ADS)

Fedoseev, G.; Cuppen, H. M.; Ioppolo, S.; Lamberts, T.; Linnartz, H.

2015-04-01

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO freeze-out stage in interstellar dark cloud regions, well before thermal and energetic processing become dominant. It is shown that along with the formation of H2CO and CH3OH - two well-established products of CO hydrogenation - also molecules with more than one carbon atom form. The key step in this process is believed to be the recombination of two HCO radicals followed by the formation of a C-C bond. The experimentally established reaction pathways are implemented into a continuous-time random-walk Monte Carlo model, previously used to model the formation of CH3OH on astrochemical time-scales, to study their impact on the solid-state abundances in dense interstellar clouds of glycolaldehyde and ethylene glycol.

Electronic Absorption Spectra of Mass-Selected Hydrocarbon Cations in Solid Neon: C_nH_4+ (n=5-8,10,12)

NASA Astrophysics Data System (ADS)

Nagy, A.; Fulara, J.; Garkusha, I.; Maier, J. P.

2011-05-01

Small, unsaturated hydrocarbons, C_nH_m (n,m≤6), play an important role in astrochemical models as they have been detected in various space objects such as the interstellar medium or envelopes of carbon-rich stars. Although identification of most of these species was based on rotational studies, they are candidate carriers of the infamous diffuse interstellar bands. It has been proposed that corresponding cationic species formed upon UV radiation may also be of astrophysical relevance; therefore, their optical spectra need to be determined. In this contribution, electronic absorption spectra of mass-selected C_nH_4+ (n=5-8,10,12) ions trapped in neon matrices are presented. The cations were produced in a hot-cathode discharge source, guided through a series of electrostatic lenses, mass filtered and co-deposited with excess of neon onto a rhodium-coated sapphire plate held at 6 K. In the same experiments, neutral species were generated from the cations by a photobleaching procedure.

Second LDEF Post-Retrieval Symposium Abstracts

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Compiler)

1992-01-01

These abstracts from the symposium represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science, (cosmic ray, interstellar gas, heavy ions, micrometeoroids, etc.), electronics, optics, and life science.

Synthesis of Large Molecules in Cometary Ice Analogs: Physical Properties Related to Self-Assembly Processes

NASA Technical Reports Server (NTRS)

Dworkin, Jason P.; Sandford, Scott A.; Deamer, David W.; Gillette, J. Seb; Zare, Richard N.; Allamandola, Louis J. (Technical Monitor)

1999-01-01

The combination of realistic laboratory simulations and infrared observations have revolutionized our understanding of interstellar dust and ice-the main component of comets. Since comets and carbonaceous micrometeorites may have been important sources of volatiles and carbon compounds on the early Earth, their organic composition may be related to the origin of life. Ices on grains in molecular clouds contain a variety of simple molecules. The D/H ratios of the comets Hale-Bopp and Hyakutake are consistent with a primarily interstellar ice mixture. Within the cloud and especially in the presolar nebula through the early solar system, these icy grains would have been photoprocessed by the ultraviolet producing more complex species such as hexamethylenetetramine, polyoxymethylenes, and simple keones. We reported at the 1999 Bioastronomy meeting laboratory simulations studied to identify the types of molecules which could have been generated in pre-cometary ices. Experiments were conducted by forming a realistic interstellar mixed-molecular ice (H2O, CH3OH, NH3 and CO) at approximately 10 K under high vacuum irradiated with UV light from a hydrogen plasma lamp. The gas mixture was typically 100:50:1:1, however when different ratios were used material with similar characteristics was still produced. The residue that remained after warming to room temperature was analyzed by HPLC, and by several mass spectrometric methods. This material contains a rich mixture of complex compounds with mass spectral profiles resembling those found in IDPs and meteorites. Surface tension measurements show that an amphiphilic component is also present. These species do not appear in various controls or in unphotolyzed samples. Residues from the simulations were also dispersed in aqueous media for microscopy. The organic material forms 10-40 gm diameter droplets that fluoresce at 300-450 nm under UV excitation. These droplets have a morphology and internal structure which appear strikingly similar to those produced by extracts of the Murchison meteorite. Together, these results suggest a link between organic material photochemically synthesized on the cold grains in dense, interstellar molecular clouds and compounds that may have contributed to the organic inventory of the primitive Earth. For example, the amphiphilic properties of such compounds permit self-assembly into the membranous boundary structures that required for the first forms of cellular life.

The Curators of the University of Missouri Modeling the Infrared Emission of C_60 in Space

NASA Astrophysics Data System (ADS)

Li, Aigen

Fullerenes are cage-like molecules of pure carbon, such as C_60, C_70, C_76, and C_84. C_60, also known as buckminsterfullerene, is the most stable fullerene and has a soccer- ball like structure. The presence of fullerenes in space has been suggested and observationally explored since their first synthesis in the laboratory in 1985 by Harry Kroto and his colleagues which earned them the 1996 Nobel prize in chemistry. C_60 (as well as C_70) has recently been detected in reflection nebulae, post-AGB stars, protoplanetary nebulae, planetary nebulae, Herbig Ae/Be stars, and young stellar objects through their characteristic infrared emission bands. The formation of C_60 in interstellar and circumstellar environments is not firmly established. Experimental studies have shown that C_60 can be made by gas-phase condensation (e.g. through vaporization of graphite) in a hydrogen-poor environment. In view of the simultaneous detection of C_60 and PAHs in hydrogen-rich interstellar and circumstellar regions, it has also been suggested that C_60 could be generated by the decomposition of hydrogenated amorphous carbon, or the destruction of PAHs, both induced by shocks and/or UV photoprocessing. The phase (gas or solid) and excitation mechanism of C_60 in interstellar and circumstellar conditions are also hotly debated in the literature. One model suggests that C_60 is attached to dust and emits in solid-phase at the equilibrium temperature of the dust. Another model suggests that C_60 is stochastically excited by UV photons and emits in the gas-phase. We prefer the latter model as in interstellar and circumstellar conditions the energy content of a C_60 molecule is often smaller than the energy of a single starlight photon and C_60 is expected to undergo stochastical heating. We propose a two-year project to model the vibrational excitation of C_60 and calculate its infrared emission spectra in a wide variety of regions (e.g. reflection nebulae excited by stars of a range of effective temperatures, protoplanetary nebulae, planetary nebulae, the diffuse interstellar medium, and protoplanetary disks around Herbig Ae/Be stars), using the ``exact-statistical'' method developed by Draine & Li (2001) for modeling the photoexcitation of PAHs. We will calculate the intensity of each vibrational band of C_60 excited by a given-type radiation field of a given radiation strength. These results will be tabulated and made available to the community through the PI's website. We will use the calculated C_60 band intensities to analyze the observed C_60 spectra. This will allow us to derive the C_60 abundance and the emitting condition (e.g. starlight intensities) of the regions where C_60 is observed. Similarly, the same research will be applied to C_70 as well. This research supports the NASA Strategic Subgoal 3C: Discover the origin, structure, evolution, and destiny of the universe.

Laser Induced Fluorescence Spectroscopy of Neutral and Ionized Polycyclic Aromatic Hydrocarbons in a Cosmic Simulation Chamber

NASA Astrophysics Data System (ADS)

Bejaoui, Salma; Salama, Farid

2015-08-01

Polycyclic aromatic hydrocarbon (PAH) molecules are considered the best carriers to account for the ubiquitous infrared emission bands. PAHs have also been proposed as candidates to explain the diffuse interstellar bands (DIBs), a series of absorption features seen on the interstellar extinction curve and are plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments. Extensive efforts have been devoted over the past two decades to characterize the physical and chemical properties of PAH molecules and ions in space. Absorption spectra of PAH molecules and ions trapped in solid matrices have been compared to the DIBs [1, 2]. Absorption spectra of several cold, isolated gas-phase PAHs have also been measured under experimental conditions that mimic the interstellar conditions [see 3 for a review]. The purpose of this study is to provide a new dimension to the existing spectroscopic database of neutral and single ionized PAHs that is largely based on absorption spectra by adding emission spectroscopy data. The measurements are based on the laser-induced fluorescence (LIF) technique [4] and are performed with the Pulsed Discharge Nozzle (PDN) of the COSmIC laboratory facility at NASA Ames laboratory. The PDN generates plasma in a free supersonic jet expansion to simulate the physical and the chemical conditions in interstellar environments. We focus, here, on the fluorescence spectra of large neutral PAHs and their cations where there is a lack of fluorescence spectroscopy data. The astronomical implications of the data (e.g., ERE) are examinedReferences[1] F. Salama, E. Bakes, L.J. Allamandola, A.G.G.M. Tielens, Astrophys. J., 458 (1996) p.621[2] F. Salama, The ISO Revolution, EDP Sciences, Les Ulis, France (1999) p.65[3] Salama F., In Organic Matter in Space, IAU Symposium 251, Kwok & Sandford Eds.Cambridge University Press,4, S251,(2008), p. 357 (2008) and references therein.[4] Salma Bejaoui, Xavier Mercier, Pascale Desgroux, Eric Therssen, Comb.& Fl, 161 (2014) p. 2479

From Dust to Planets: The Tale Told by Moderately Volatile Element Depletion (MOVED)

NASA Technical Reports Server (NTRS)

Yin, Qing-Zhu

2004-01-01

The pronounced depletion of moderately volatile elements (MOVE, that condense or evaporate at temperatures in the range 1350-650K) relative to the average solar composition is a characteristic feature in most primitive chondrites and bulk terrestrial planets. It differs from the composition of the Sun and from the materials further away from the Sun (CI chondrites). None of the remaining planets or even meteorites shows an enrichment of volatile elements that would balance the depletion in the inner Solar System. Whether this depletion occurred in solar nebular stage or in planetary formation stage has been the subject of long lasting debate. The search for mysterite initiated in 1973 continues today in search of lost planets. Here I show that the MOVED patterns demonstrate a clear connection between the rocky materials of the inner solar system and the interstellar dust. The inheritance of interstellar materials by the solar system is not only documented by the presence of presolar grains, various isotopic anomalies, but also expressed in the chemical element distribution in the inner solar system.

Evolution of a superbubble blastwave in a magnetized medium

NASA Technical Reports Server (NTRS)

Ferriere, Katia M.; Zweibel, Ellen G.; Maclow, Mordecai-Mark

1990-01-01

Researchers investigate the effects of interstellar magnetic fields on the evolution and structure of interstellar superbubbles, using both analytic and numerical magnetohydrodynamic (MHD) calculations. These cavities of hot gas, surrounded by shells of cold dense material preceded by a shock wave result from the combined action of stellar winds and supernova explosions in OB associations. If the medium in which a superbubble goes off is homogeneous and unmagnetized, the blast wave expands isotropically. As the interstellar gas flows through the shock, it cools significantly and gets strongly compressed such that thermal pressure remains approximately equal to ram pressure. Hence, the swept up material is confined to a very thin shell. However, if the ambient medium is permeated by a uniform magnetic field B sub o approx. 3 mu G (typical value for the interstellar matter (ISM)), the configuration loses its spherical symmetry, and, due to magnetic pressure, the shell of swept up material does not remain thin. Researchers found the following qualitative differences: (1) Except in the immediate vicinity of the magnetic poles, the shell is supported by magnetic pressure. (2) The refraction of field lines at the shock and the thermal pressure gradient along the shell both contribute to accelerating the gas toward the equator. The resulting mass flux considerably decreases the column density at the magnetic poles. (3) Away from the poles, magnetic tension in the shell causes the field lines (particularly the inner boundary) to elongate in the direction of B sub o. In contrast, the shock wave radius increases with increasing theta. (4) The reduced inertia of a parcel in the polar neighborhood makes it easier to decelerate, and accounts for the dimple which appears at the poles in numerical simulations. This dimple also results from the necessity to call on intermediate shocks in order to insure a smooth transition between a purely thermal shock at the poles and a magnetic shock in the rest of the shell. (5) The shock wave propagates faster than in the absence of magnetic field, except near the poles where the reduced mass of the shell allows it to be more efficiently decelerated.

Isotopic Anomalies in Primitive Solar System Matter: Spin-State-Dependent Fractionation of Nitrogen and Deuterium in Interstellar Clouds

NASA Technical Reports Server (NTRS)

Wirstrom, Eva S.; Charnley, Steven B.; Cordiner, Martin A.; Milam, Stefanie N.

2012-01-01

Organic material found in meteorites and interplanetary dust particles is enriched in D and N-15. This is consistent with the idea that the functional groups carrying these isotopic anomalies, nitriles and amines, were formed by ion-molecule chemistry in the protosolar nebula, Theoretical models of interstellar fractionation at low temperatures predict large enrichments in both D and N-15 and can account for the largest isotopic enrichments measured in carbonaceous meteorites. However, more recent measurements have shown that, in some primitive samples, a large N-15 enrichment does not correlate with one in D, and that some D-enriched primitive material displays little, if any, N-15 enrichment. By considering the spin-state dependence in ion-molecule reactions involving the ortho and para forms of H2, we show that ammonia and related molecules can exhibit such a wide range of fractionation for both N-15 and D in dense cloud cores. We also show that while the nitriles, HCN and HNC, contain the greatest N=15 enrichment, this is not expected to correlate with extreme D enrichment. These calculations therefore support the view that solar system N-15 and D isotopic anomalies have an interstellar heritage. We also compare our results to existing astronomical observations and briefly discuss future tests of this model.

Isotopic Anomalies in Primitive Solar System Matter: Spin-State Dependent Fractionation of Nitrogen and Deuterium in Interstellar Clouds

NASA Technical Reports Server (NTRS)

Wirstrom, Eva S.; Charnley, Steven B.; Cordiner, Martin A.; Milan, Stefanie N.

2012-01-01

Organic material found in meteorites and interplanetary dust particles is enriched in D and N-15, This is consistent with the idea that the functional groups carrying these isotopic anomalies, nitriles and amines, were formed by ion-molecule chemistry in the protosolar core. Theoretical models of interstellar fractionation at low temperatures predict large enrichments in both D and N-15 and can account for the largest isotop c enrichments measured in carbonaceous meteorites, However, more recent measurements have shown that, in some primitive samples, a large N-15 enrichment does not correlate with one in D, and that some D-enriched primitive material displays little, if any, N-15 enrichment. By considering the spin-state dependence in ion-molecule reactions involving the ortho and para forms of H2, we show that ammonia and related molecules can exhibit such a wide range of fractionation for both N-15 and D in dense cloud cores, We also show that while the nitriles, HCN and HNC, contain the greatest N-15 enrichment, this is not expected to correlate with extreme D emichment. These calculations therefore support the view that Solar System N-15 and D isotopic anomalies have an interstellar heritage, We also compare our results to existing astronomical observations and briefly discuss future tests of this model.

The use of kerogen data in understanding the properties and evolution of interstellar carbonaceous dust

NASA Astrophysics Data System (ADS)

Papoular, R.

2001-11-01

A number of authors have, in the past decade, pointed to the similarity of the 3.4-mu m band of kerogen with that of the Galactic Centre (GC). Kerogen is a family of solid terrestrial sedimentary materials essentially made of C, H and O interlocked in a disordered, more or less aliphatic, structure. Here, the most recent results of the astronomical literature and the rich quantitative geochemical literature are tapped with two purposes in mind: extend the analogy to the mid-IR bands and, based on these new constraints, quantitatively assess the properties of the carrier dust. It is shown that the great diversity of IR astronomical IS (interstellar) dust is paralleled by the changes in kerogen spectra as the material spontaneously and continuously evolves (aromatizes) in the earth. Since the composition and structure of kerogen are known all along its evolution, it is possible, by spectral analogy, to estimate these properties for the corresponding astronomical carriers. The Galactic Centre 3.4 mu m feature is thus found to correspond to an early stage of evolution, for which the composition in C, H and O and the structure of the corresponding kerogen are known and reported here. The role of oxygen in the subsequent evolution and its contribution to different bands are stressed. The above provides new arguments in favour of the 3.4-mu m band, as well as the observed accompanying mid-IR bands, being carried by kerogen-like dust born in CS (circumstellar) envelopes, mostly of AGB (asymptotic giant branch) objects. Subsequent dust evolution in composition and structure (aromatization) is fast enough that the unidentified infrared bands can already show up in well-developed planetary nebulae (PNe), as observed. A fraction of incompletely evolved dust can escape into the diffuse IS medium and molecular clouds. As a consequence, aliphatic and aromatic features can both be detected in the sky, in emission (Proto-PNe, PNe and PDRs (photo-dissociation regions)) as well as in absorption (dense molecular clouds and diffuse ISM). Changes in wavelength and band width with line of sight are explained by changes in the nature and number of chemical functional groups composing the carrier material. Predictions of the kerogen model in the UV and far IR are proposed for testing.

Use of Mini-Mag Orion and superconducting coils for near-term interstellar transportation

NASA Astrophysics Data System (ADS)

Lenard, Roger X.; Andrews, Dana G.

2007-06-01

Interstellar transportation to nearby star systems over periods shorter than the human lifetime requires speeds in the range of 0.1-0.15 c and relatively high accelerations. These speeds are not attainable using rockets, even with advanced fusion engines because at these velocities, the energy density of the spacecraft approaches the energy density of the fuel. Anti-matter engines are theoretically possible but current physical limitations would have to be suspended to get the mass densities required. Interstellar ramjets have not proven practicable, so this leaves beamed momentum propulsion or a continuously fueled Mag-Orion system as the remaining candidates. However, deceleration is also a major issue, but part of the Mini-Mag Orion approach assists in solving this problem. This paper reviews the state of the art from a Phases I and II SBIT between Sandia National Laboratories and Andrews Space, applying our results to near-term interstellar travel. A 1000 T crewed spacecraft and propulsion system dry mass at .1c contains ˜9×1021J. The author has generated technology requirements elsewhere for use of fission power reactors and conventional Brayton cycle machinery to propel a spacecraft using electric propulsion. Here we replace the electric power conversion, radiators, power generators and electric thrusters with a Mini-Mag Orion fission-fusion hybrid. Only a small fraction of fission fuel is actually carried with the spacecraft, the remainder of the propellant (macro-particles of fissionable material with a D-T core) is beamed to the spacecraft, and the total beam energy requirement for an interstellar probe mission is roughly 1020J, which would require the complete fissioning of 1000 ton of Uranium assuming 35% power plant efficiency. This is roughly equivalent to a recurring cost per flight of 3.0 billion dollars in reactor grade enriched uranium using today's prices. Therefore, interstellar flight is an expensive proposition, but not unaffordable, if the nonrecurring costs of building the power plant can be minimized.

[Petrological Analysis of Astrophysical Dust Analog Evolution

NASA Technical Reports Server (NTRS)

Rietmeijer, Frans J. M.

1997-01-01

This project "Petrological analysis of astrophysical dust analog evolution" was initiated to try to understand the vapor phase condensation, and the nature of the reaction products, in circumstellar environments, such as the solar nebula 4,500 Myrs ago, and in the interstellar medium. Telescope-based infrared [IR] spectroscopy offers a broad-scale inventory of the various types of dust in these environments but no details on small-scale variations in terms of chemistry and morphology and petrological phase relationships. Vapor phase condensation in these environments is almost certainly a non-equilibrium process. The main challenge to this research was to document the nature of this process that, based on astrophysical observations, seems to yield compositionally consistent materials. This observation may suggest a predictable character during non-equilibrium condensation. These astrophysical environments include two chemically distinct, that is, oxygen-rich and carbon-rich environments. The former is characterized by silicates the latter by carbon-bearing solids. According to cosmological models of stellar evolution circumstellar dust accreted into protoplanets wherein thermal and/or aqueous processes will alter the dust under initially, non-equilibrium conditions.

The Abundance and Distribution of Presolar Materials in Cluster IDPS

NASA Technical Reports Server (NTRS)

Messenger, Scott; Keller, Lindsay; Nakamura-Messenger, Keiko; Ito, Motoo

2007-01-01

Presolar grains and remnants of interstellar organic compounds occur in a wide range of primitive solar system materials, including meteorites, interplanetary dust particles (IDPs), and comet Wild-2 samples. Among the most abundant presolar phases are silicate stardust grains and molecular cloud material. However, these materials have also been susceptible to destruction and alteration during parent body and nebular processing. In addition to their importance as direct samples of remote and ancient astrophysical environments, presolar materials thus provide a measure of how well different primitive bodies have preserved the original solar system starting materials.

Deuterium Enrichment of PAHs by VUV Irradiation of Interstellar Ices

NASA Technical Reports Server (NTRS)

Bernstein, Max P.; Sandford, Scott A.; Allamandola, Louis J.; Gillette, J. Seb; Zare, Richard N.; DeVincenzi, Donald (Technical Monitor)

1998-01-01

Laboratory results demonstrate that polycyclic aromatic hydrocarbons (PAHs) rapidly exchange their hydrogen atoms with those of nearby molecules when they are frozen into low-temperature ices and exposed to vacuum ultraviolet radiation. As a result, PAHs quickly become deuterium-enriched when VUV irradiated in D-containing ices. This mechanism has important consequences for several astrophysical issues owing to the ubiquitous nature of PAHs in the interstellar medium. For example, this process may explain the deuterium enrichments found in PAHs in meteorites and interplanetary dust particles. These results also provide general predictions about the molecular siting of the deuterium on aromatic materials in meteorites if this process produced a significant fraction of their D-enrichment.

Stellar Content of the Young Supershell GSH 305+01-24

NASA Astrophysics Data System (ADS)

Kaltcheva, N.; Golev, V.

2013-06-01

We combine several multi-wavelength surveys (Wisconsin Halpha Mapper Northern Sky Survey, MSX Mid-IR Galactic Plane Survey, WISE All-Sky Data Release, CO survey of the Milky Way, and the Southern Galactic Plane HI Survey) with intermediate-band uvby photometry to investigate the correlation between the young stars and various interstellar components related to the GSH 305+01-24 supershell seen toward Centaurus. The region shows striking similarities between the stellar distribution and Hα and HI emission morphologies. We identity 161 O-B9 stars at an average distance modulus 11.09 ± 0.71 (s.d.) mag located within the supershell and study their interaction with the surrounding interstellar material.

Tunneling Rate Constants for H2CO+H on Amorphous Solid Water Surfaces

NASA Astrophysics Data System (ADS)

Song, Lei; Kästner, Johannes

2017-12-01

Formaldehyde (H2CO) is one of the most abundant molecules observed in the icy mantle covering interstellar grains. Studying its evolution can contribute to our understanding of the formation of complex organic molecules in various interstellar environments. In this work, we investigated the hydrogenation reactions of H2CO yielding CH3O, CH2OH, and the hydrogen abstraction resulting in H2+HCO on an amorphous solid water (ASW) surface using a quantum mechanics/molecular mechanics (QM/MM) model. The binding energies of H2CO on the ASW surface vary broadly, from 1000 to 9370 K. No correlation was found between binding energies and activation energies of hydrogenation reactions. Combining instanton theory with QM/MM modeling, we calculated rate constants for the Langmuir-Hinshelwood and the Eley-Rideal mechanisms for the three product channels of H+H2CO surface reactions down to 59 K. We found that the channel producing CH2OH can be ignored, owing to its high activation barrier leading to significantly lower rates than the other two channels. The ASW surface influences the reactivity in favor of formation of CH3O (branching ratio ˜80%) and hinders the H2CO dissociation into H2+HCO. In addition, kinetic isotope effects are strong in all reaction channels and vary strongly between the channels. Finally, we provide fits of the rate constants to be used in astrochemical models.

Infrared Spectrum of N-Oxidohydroxylamine [ONH(OH)] Produced in Reaction H + Hono in Solid Para-Hydrogen

NASA Astrophysics Data System (ADS)

Haupa, Karolina Anna; Lee, Yuan-Pern

2017-06-01

Hydrogenation reactions in the N/O chemical network are important for an understanding of the mechanism of formation of organic molecules in dark interstellar clouds, but many reactions remain unknown. We present the results of the reaction H + HONO in solid {para}-hydrogen ({p}-H_{2}) at 3.3 K investigated with infrared spectra. Two methods that produced hydrogen atoms were the irradiation of HONO molecules in {p}-H_{2} at 365 nm to produce OH radicals that reacted readily with nearby H_{2} to produce mobile H atoms, and irradiation of Cl_{2} molecules (co-deposited with HONO) in {p}-H_{2} at 405 nm to produce Cl atoms that reacted readily with nearby H_{2} to produce mobile H atoms. In both experiments, we assigned IR lines at 3549.6 (νb{1}), 1465.0 (νb{3}), 1372.2 (νb{4}), 895.6/898.5 (νb{6}), and 630.9 (νb{7}) \\wn to N-oxidohydroxylamine [ONH(OH)], the primary product of HONO hydrogenation. The assignments were derived according to the consideration of possible reactions and comparison of observed vibrational wavenumbers and their IR intensities with values predicted with the B3LYP/aug-cc-pVTZ method of quantum-chemical calculations. The agreement between observed and calculated D/H- and ^{15}N/^{14}N-isotopic ratios further supports these assignments. The role of this reaction in the N/O chemical network in dark interstellar clouds is discussed.

Chemical evolution in space--a source of prebiotic molecules.

PubMed

Greenberg, J M

1983-01-01

In Laboratory Astrophysics at Leiden University a laboratory analog for following the chemical evolution of interstellar dust in space shows that the dust contains the bulk of organic material in the universe. We follow the photoprocessing of low temperature (10 K) mixtures of ices subjected to vacuum ultraviolet radiation in simulation of interstellar conditions. The most important, but necessary, difference is in the time scales for photo-processing. One hour in the laboratory is equivalent to one thousand years in low density regions of space and as much as, or greater than, ten thousand to one million years in the depths of dense molecular clouds. The ultimate product of photoprocessing of grain material in the laboratory is a complex nonvolatile residue which is yellow in color and soluble in water and methanol. The molecular weight is greater than the mid-hundreds. The infrared absorption spectra indicate the presence of carboxylic acid and amino groups resembling those of other molecules of presumably prebiological significance produced by more classical methods. One of our residues, when subjected to high resolution mass spectroscopy gave a mass of 82 corresponding to C4H6H2 after release of CO2 and trace ammounts of urea suggesting amino pyroline rings. The deposit of prebiotic dust molecules occurred as many as 5 times in the first 500-700 million years on a primitive Earth by accretion during the passage of the solar system through a dense interstellar cloud. The deposition rate during each passage is estimated to be between 10(9) and 10(10) g per year during the million or so years of each passage; i.e., a total deposition of 1O(9)-10(10) metric tons of complex organic material per passage.

Connecting the Interstellar Gas and Dust Properties in Distant Galaxies Using Quasar Absorption Systems

NASA Technical Reports Server (NTRS)

Aller, Monique C.; Dwek, Eliahu; Kulkarni, Varsha P.; York, Donald G.; Welty, Daniel E.; Vladilo, Giovanni; Som, Debopam; Lackey, Kyle; Dwek, Eli; Beiranvand, Nassim;

Two-component scattering model and the electron density spectrum

NASA Astrophysics Data System (ADS)

Zhou, A. Z.; Tan, J. Y.; Esamdin, A.; Wu, X. J.

2010-02-01

In this paper, we discuss a rigorous treatment of the refractive scintillation caused by a two-component interstellar scattering medium and a Kolmogorov form of density spectrum. It is assumed that the interstellar scattering medium is composed of a thin-screen interstellar medium (ISM) and an extended interstellar medium. We consider the case that the scattering of the thin screen concentrates in a thin layer represented by a δ function distribution and that the scattering density of the extended irregular medium satisfies the Gaussian distribution. We investigate and develop equations for the flux density structure function corresponding to this two-component ISM geometry in the scattering density distribution and compare our result with the observations. We conclude that the refractive scintillation caused by this two-component ISM scattering gives a more satisfactory explanation for the observed flux density variation than does the single extended medium model. The level of refractive scintillation is strongly sensitive to the distribution of scattering material along the line of sight (LOS). The theoretical modulation indices are comparatively less sensitive to the scattering strength of the thin-screen medium, but they critically depend on the distance from the observer to the thin screen. The logarithmic slope of the structure function is sensitive to the scattering strength of the thin-screen medium, but is relatively insensitive to the thin-screen location. Therefore, the proposed model can be applied to interpret the structure functions of flux density observed in pulsar PSR B2111 + 46 and PSR B0136 + 57. The result suggests that the medium consists of a discontinuous distribution of plasma turbulence embedded in the interstellar medium. Thus our work provides some insight into the distribution of the scattering along the LOS to the pulsar PSR B2111 + 46 and PSR B0136 + 57.

A TALE OF TWO MYSTERIES IN INTERSTELLAR ASTROPHYSICS: THE 2175 A EXTINCTION BUMP AND DIFFUSE INTERSTELLAR BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiang, F. Y.; Zhong, J. X.; Li Aigen, E-mail: jxzhong@xtu.edu.cn, E-mail: lia@missouri.edu

2011-06-01

The diffuse interstellar bands (DIBs) are ubiquitous absorption spectral features arising from the tenuous material in the space between stars-the interstellar medium (ISM). Since their first detection nearly nine decades ago, over 400 DIBs have been observed in the visible and near-infrared wavelength range in both the Milky Way and external galaxies, both nearby and distant. However, the identity of the species responsible for these bands remains as one of the most enigmatic mysteries in astrophysics. An equally mysterious interstellar spectral signature is the 2175 A extinction bump, the strongest absorption feature observed in the ISM. Its carrier also remainsmore » unclear since its first detection 46 years ago. Polycyclic aromatic hydrocarbon (PAH) molecules have long been proposed as a candidate for DIBs as their electronic transitions occur in the wavelength range where DIBs are often found. In recent years, the 2175 A extinction bump is also often attributed to the {pi}-{pi}* transition in PAHs. If PAHs are indeed responsible for both the 2175 A extinction feature and DIBs, their strengths may correlate. We perform an extensive literature search for lines of sight for which both the 2175 A extinction feature and DIBs have been measured. Unfortunately, we found no correlation between the strength of the 2175 A feature and the equivalent widths of the strongest DIBs. A possible explanation might be that DIBs are produced by small free gas-phase PAH molecules and ions, while the 2175 A bump is mainly from large PAHs or PAH clusters in condensed phase so that there is no tight correlation between DIBs and the 2175 A bump.« less

Stardust Interstellar Preliminary Examination IV: Scanning Transmission X-Ray Microscopy Analyses of Impact Features in the Stardust Interstellar Dust Collector

NASA Technical Reports Server (NTRS)

Butterworth, Anna L.; Westphal, Andrew J.; Frank, David R.; Allen, Carlton C.; Bechtel, Hans A.; Sandford, Scott A.; Tsou, Peter; Zolensky, Michael E.

2014-01-01

We report the quantitative characterization by synchrotron soft X-ray spectroscopy of 31 potential impact features in the aerogel capture medium of the Stardust Interstellar Dust Collector. Samples were analyzed in aerogel by acquiring high spatial resolution maps and high energy-resolution spectra of major rock-forming elements Mg, Al, Si, Fe, and others. We developed diagnostic screening tests to reject spacecraft secondary ejecta and terrestrial contaminants from further consideration as interstellar dust candidates. The results support an extraterrestrial origin for three interstellar candidates: I1043,1,30 (Orion) is a 3 pg particle with Mg-spinel, forsterite, and an iron-bearing phase. I1047,1,34 (Hylabrook) is a 4 pg particle comprising an olivine core surrounded by low-density, amorphous Mg-silicate and amorphous Fe, Cr, and Mn phases. I1003,1,40 (Sorok) has the track morphology of a high-speed impact, but contains no detectable residue that is convincingly distinguishable from the background aerogel. Twenty-two samples with an anthropogenic origin were rejected, including four secondary ejecta from impacts on the Stardust spacecraft aft solar panels, nine ejecta from secondary impacts on the Stardust Sample Return Capsule, and nine contaminants lacking evidence of an impact. Other samples in the collection included I1029,1,6, which contained surviving solar system impactor material. Four samples remained ambiguous: I1006,2,18, I1044,2,32, and I1092,2,38 were too dense for analysis, and we did not detect an intact projectile in I1044,3,33. We detected no radiation effects from the synchrotron soft X-ray analyses; however, we recorded the effects of synchrotron hard X-ray radiation on I1043,1,30 and I1047,1,34.

Spectroscopy of neutral and ionized PAHs. From laboratory studies to astronomical observations

NASA Technical Reports Server (NTRS)

Salama, Farid

2005-01-01

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. PAHs are the best-known candidates to account for the IR emission bands (UIR bands) and PAH spectral features are now being used as new probes of the ISM. PAHs are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). In the model dealing with the interstellar spectral features, PAHs are present as a mixture of radicals, ions and neutral species. PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge for laboratory astrochemistry is to reproduce (in a realistic way) the physical conditions that are associated with the emission and absorption interstellar zones. An extensive laboratory program has been developed at NASA Ames to assess the physical and chemical properties of PAHs in such environments and to describe how they influence the radiation and energy balance in space and the interstellar chemistry. PAHs, neutrals and ions, are expanded through a pulsed discharge nozzle (PDN) and probed with high-sensitivity cavity ringdown spectroscopy (CRDS). These laboratory experiments provide unique information on the spectra of free, cold large carbon molecules and ions in the gas phase from the ultraviolet and visible range to the near-infrared range. Intrinsic band profiles and band positions of cold gas-phase PAHs can now be measured with high-sensitivity spectroscopy and directly compared to the astronomical data. Preliminary conclusions from the comparison of the laboratory data with astronomical observations of interstellar and circumstellar environments will also be discussed.

Editorial: Interstellar Boundary Explorer (IBEX): Direct Sampling of the Interstellar Medium

NASA Astrophysics Data System (ADS)

McComas, D. J.

2012-02-01

This special supplement issue of the Astrophysical Journal comprises six coordinated papers that provide the first detailed analyses of the direct sampling of interstellar neutral atoms by the Interstellar Boundary Explorer (IBEX). Interstellar atoms are the detritus of older stars—their stellar winds, novae, and supernovae—spread across the galaxy, which fill the vast interstellar space between the stars. The very local interstellar medium around the Sun is filled with both ionized and neutral atoms with approximately equal numbers, and occasional ionization, charge exchange, and recombination makes them a single interacting material over large distances. IBEX (McComas et al. 2009a) is a NASA Small Explorer mission with the sole, focused science objective to discover the global interaction between the solar wind and the interstellar medium; this objective has primarily been achieved by taking the first global energetic neutral atom (ENA) images, which provide detailed ENA fluxes and energy spectra over all look directions in space. IBEX was launched 2008 October 19 and subsequently maneuvered into a high-altitude, highly elliptical (~15,000 × 300,000 km), roughly week-long orbit. The payload comprises two very high sensitivity, single-pixel ENA cameras: IBEX-Hi (Funsten et al. 2009a), which measures ENAs from ~300 eV to 6 keV, and IBEX-Lo (Fuselier et al. 2009a), which measures ENAs from ~10 eV to 2 keV. The initial IBEX ENA results were published together in a special issue of Science magazine (McComas et al. 2009b; Funsten et al. 2009b; Fuselier et al. 2009b; Schwadron et al. 2009). Since then there have been numerous additional studies of the IBEX ENA observations of the heliosphere, as well as ENAs from the Moon and Earth's magnetosphere (see recent review by McComas et al. 2011 and references therein). Prior to IBEX, the only interstellar neutral atoms to be directly sampled were He, observed by the Ulysses spacecraft a decade ago (Witte et al. 1996; Witte 2004). The first paper published on IBEX observations of interstellar neutral atoms (Möbius et al. 2009) used observations from the spring of 2009, shortly after IBEX achieved its first long-term orbit; that study showed that IBEX is able to directly observe interstellar H and O in addition to He, but provided only limited analysis of these measurements. IBEX has now completed a second full annual season of neutral observations in 2010, which together with the independent 2009 observations provide data adequate to carry out the first round of detailed, quantitative analyses of the IBEX interstellar neutral observations. In this special supplement issue, the IBEX Science Team presents a coordinated series of six articles that focus on various synergistic aspects of these observations, their analyses, and their implications. A critical foundational paper in this volume, Hlond et al. (2012), analyzes the angular pointing knowledge of IBEX observations and demonstrates that the arrival direction knowledge of neutral atoms can be determined to ~0.1° in both spin angle and elevation. This is no mean feat for a Small Explorer mission designed to measure ENAs in 7° × 7° pixels, and largely at much higher energies than the direct interstellar neutrals. In addition, these authors demonstrate that the in-space (post-launch) bore sight of the IBEX-Lo instrument can achieve this accuracy with either the spacecraft's on board attitude control system or an independent Star Sensor that was designed and built directly into the IBEX-Lo instrument. Lee et al. (2012) derive the analytical solution for the hyperbolic trajectories of individual neutral atoms by using Liouville's theorem, including solar gravity and radiation pressure, photoionization and charge exchange, to produce interstellar neutral atom phase-space distributions. These distributions are then transformed into the IBEX reference frame and integrated over the IBEX-Lo instrumental acceptance to provide an analytic solution for the predicted fluid moments of the interstellar neutral atom distributions. This analytic solution for the interstellar neutral parameters provides the basis for a companion paper by Möbius et al. (2012), who analyze the IBEX He (and Ne+O) measurements using the Lee et al. analytic solutions. This approach allows for physical insights into the dominant physical processes, while in another related paper Bzowski et al. (2012) describe a detailed forward model of the interstellar helium from the edge of the heliosphere all the way through the IBEX instrument geometry. Together, these papers show that the prior values for the interstellar flow speed and direction from Ulysses are inconsistent with our new IBEX observations. Möbius et al. (2012) compare the He and O+Ne flow distributions for both 2009 and 2010 and find interstellar flow parameters of ecliptic longitude at ∞ = 79.0° + 3.0°/-3.5°, ecliptic latitude at ∞ = -4.9° ± 0.2°, ISM speed at ∞ = 23.5 + 3.0/-2.0 km s-1, and neutral He temperature = 5000-8200 K. They also find a combined O+Ne temperature of 5300-9000 K, consistent with an isothermal medium for He, O, and Ne. Bzowski et al. (2012) develop and extensively test a detailed forward model simulation of the interstellar He propagation, losses, and measurement in the IBEX-Lo instrument. These simulations start particles at 150 AU and include more detailed physics than the analytic solutions; they therefore complement the analytic method by allowing detailed mapping of the multi-dimensional space of possible solutions. These authors show that the IBEX results are not in statistical agreement with the Ulysses values and provide new best-fit values of ecliptic longitude 79.2°, ecliptic latitude of -5.1°, speed of ~22.8 km s-1, and He temperature is 6200 K. The values obtained with both complementary methods agree with each other and are in agreement with the flow vector of the local interstellar cloud obtained from studies of interstellar absorption (Redfield & Linsky 2008). Bzowski et al. also show evidence for a previously unknown and unanticipated secondary population of helium. Together, the Möbius et al. (2012) and Bzowski et al. (2012) results provide a new interstellar flow direction and a significantly lower velocity of the incoming gas and therefore significantly lower dynamic pressure on the heliosphere, which translates into a heliospheric interaction that is even less dominated by the external dynamic pressure and clearly lies squarely in the middle ground of astrospheres dominated by the external magnetic and dynamic pressures (McComas et al. 2009b). On another topic, Bochsler et al. (2012) report the first direct measurements of interstellar Ne and estimate the interstellar Ne/O abundance ratio, showing a gas-phase Ne/O ratio for the LISM of 0.27 ± 0.10. This value agrees with results obtained from pickup ion observations (Gloeckler & Geiss 2004; Gloeckler & Fisk 2007) and is significantly larger than the solar abundance ratio, indicating that the LISM is different than the Sun's formation region and/or that a substantial portion of the O in the LISM is tied up (and thus "hidden") in grains and/or ices. Finally, Saul et al. (2012) provide the first detailed analysis of the new interstellar H measurements from IBEX. These authors confirm that the arrival direction of interstellar H is offset from that of He. They further show a variation in the strength of the radiation pressure and thus a change in the apparent arrival direction of H penetrating to 1 AU between the first two years of IBEX observations; these results are consistent with solar cycle variations in the radiation pressure, which works opposite to the Sun's gravitational force to effect the penetration of H into the inner heliosphere. Together, these six studies provide the first detailed analyses of the multi-component local interstellar medium—a medium that both effects us by bounding and interacting with our heliosphere, and a medium that gives us a first direct glimpse of non-solar material from the rest of the galaxy.

Water Ice and Life's Roots in Space

NASA Technical Reports Server (NTRS)

Blake, David; Jenniskens, Peter; DeVincenzi, Donald L. (Technical Monitor)

2001-01-01

Nearly three decades ago as Voyager 2 spacecraft raced out of the Solar System. NASA engineers turned its camera arm around (at the request of the American astronomer Carl Sagan) to take a parting snapshot of Earth. Earth's image was a single pale blue pixel, its color caused by the Rayleigh scattering of sunlight in the water of our oceans. Earth is a water planet, and this is the color of life. No matter how far we travel on our planet, no matter how high or deep, if we find liquid water, we find some form of life that manages to survive there. And yet there is a cruel irony. Water in its solid crystalline form is hostile to life. Organisms can roost in geysers, wallow in brine and gulp down acid, but they cowered from ice. The rigid ordering of water molecules in ice crystals expels impurities and tears organic tissue beyond repair. In fact, about the only good thing you can say about ice is that it gets out of the way: Its low density ensures that it floats and leaves the water dwelling creatures in peace. Recent discoveries have caused us to rethink this basic premise. New lines of evidence both observational and experimental - suggest that prebiotic organic compounds are not only comfortable in, but in fact had their origin in a peculiar form of solid water ice that is ubiquitous in interstellar space, but completely absent from Earth. Only recently have we been able to create even submicroscopic quantities of this ice in terrestrial laboratories, yet it constitutes the most abundant form of water in the universe. Interstellar ice is a far cry from the ice we are so familiar with on Earth. This interstellar ice has no crystalline structure, and despite the fact that its temperature is a scant few degrees above absolute zero (where all molecular motion ceases), it is highly reactive and can flow like water when exposed to radiation. It is in fact this ice's similarity to liquid water that allows it to participate in the creation of the very first organic compounds.

Designing Effective EPO Products for Museums: Preliminary Evaluation Findings from the Interstellar Boundary Explorer (IBEX) EPO Program

NASA Astrophysics Data System (ADS)

Nichols, M.; Bartolone, L.; Baldassari, C.; Hoyer-Winfield, S.

2011-09-01

The Interstellar Boundary Explorer (IBEX) mission includes a comprehensive EPO program in astronomy and heliophysics that is overseen and implemented by the Adler Planetarium in Chicago, Illinois. Several EPO components were developed specifically for informal institutions, especially museums and planetaria. The program includes an internationally distributed planetarium show with accompanying informal educational materials. Our evaluator, the Program Evaluation and Research Group (PERG) at Lesley University, Cambridge, Massachusetts, assesses the effectiveness of the EPO program. In late 2009 through early 2010, more than 70 planetaria worldwide received the IBEX planetarium show. Of the many U.S. planetaria, the first 25 received the IBEX planetarium show and were offered the opportunity to receive, at no charge, accompanying informal education materials, including posters, lithographs, demonstration materials, lesson plans, and more. In Spring 2010, PERG staff conducted a study designed to gauge the effectiveness of the distribution process for the planetarium show, gather information on the professional development needs of the organizations, and document reactions of museum staff to the IBEX informal education materials and their usefulness as companion pieces to the planetarium show. In this paper, we will present preliminary findings of this particular study, in the hopes that future EPO work can make use of data in this report.

The Photoluminescence Efficiency of Extended Red Emission as a Constraint for Interstellar Dust

NASA Astrophysics Data System (ADS)

Smith, T. L.; Witt, A. N.

1999-12-01

The broad, 60 < FWHM < 100 nm, featureless luminescence band known as extended red emission (ERE) is seen in such diverse dusty astrophysical environments as reflection nebulae 17, planetary nebulae 3, HII regions (Orion) 12, a Nova 11, Galactic cirrus 14, a dark nebula 7, Galaxies 8,6 and the diffuse interstellar medium (ISM) 4. The band is confined between 540-950 nm, but the wavelength of peak emission varies from environment to environment, even within a given object. We have concluded that available data indicate that the wavelength of peak emission is longer and the efficiency of the luminescence is lower, the harder and denser the illuminating radiation field is 13. These general characteristics of ERE constrain the photoluminescence (PL) band and efficiency for laboratory analysis of dust analog materials. We have studied and present the PL band characteristics and efficiencies for a wide variety of dust analogs including hydrogenated amorphous carbon (HAC), Si-HAC alloys, nanodiamonds, silicon carbide nanoparticles, carbon nanoparticles and silicon nanoparticles. The PL efficiencies measured for HAC and Si-HAC alloys are consistent with dust estimates for reflection nebulae and planetary nebulae, but exhibit substantial photoluminescence below 540 nm which is not observed in astrophysical environments. Furthermore, all interstellar grains would need to consist of or be coated with these materials to match the ERE in terms of its quantum efficiency. Only the experimentally confirmed photoluminescence properties of silicon nanoparticles 1,2,5,9,10,15,16 match the ERE photoluminescence band constraints and fulfill the minimum photoluminescence efficiency predicted by Gordon et al. (1998) 4 without introducing unexpected spectral features in the diffuse ISM and without violating the abundance constraints on depleted interstellar silicon 18. This work has been supported by grants from NASA which we acknowledge with gratitude. 1. Credo, G.M., Mason, M.D., & Burrato, S.K. 1999, Appl. Phys. Lett., 74, 1978 2. Ehbrecht, M., Kohn, B., Huisken, F., Laguna, M.A. & Paillard, V. 1997, Phys. Rev. B, 56, 6958 3. Furton, D.G., & Witt, A.N. 1992, ApJ, 386, 587 4. Gordon, K.D., Witt, A.N., & Friedmann, B.C. 1998, ApJ, 498, 522 5. Lockwood, D.J., Lu, Z.H., & Baribeau, J.M. 1996, Phys. Rev. Lett., 76, 539 6. Majeed, A., Witt, A.N., & Boroson, T.A. 1999, Bull. AAS 3,886 7. Mattila, K. 1979, A&A, 78, 253 8. Perrin, J.M., Darbon, S., & Sivan, J.P. 1995, A&A, 304, L21 9. Schuppler, S. et al. 1994, Phys. Rev. B, 56, 6958 10. Schuppler, S. et al. 1995, Phys. Rev. B, 52, 4910 11. Scott, A.D., Evans, A., & Rawlings, J.M.C. 1994, MNRAS, 269, L21 12. Sivan, J.P., & Perrin, J.M. 1993, ApJ, 404, 258 13. Smith, T.L., Witt, A.N. & Gordon, K.D. 1999, BAAS 71.13 14. Szomoru, A., & Guhathakurta, P. 1998, ApJ, 494, L93 15. von Behren, J. van Buuren, T., Zacharias, M., Chimowitz, & E.H. Fauchet,P.M. 1998, Solid State Comm., 105, 317 16. Wilson, W.L., Szajowski, P.F., & Brus, L.E. 1993, Science, 262, 1242 17. Witt, A.N., & Boroson T.A. 1990, ApJ, 355, 182 18. Zubko, V.G. Smith, T.L., & Witt, A.N. 1999, ApJ, 511, L57

The influence of Oort clouds on the mass and chemical balance of the interstellar medium

NASA Technical Reports Server (NTRS)

Stern, S. Alan; Shull, J. Michael

1990-01-01

The contribution of stellar encounters and interstellar erosion to comet cloud mass injection to the ISM is calculated. It is shown that evaporative mass loss from passing stars and SNe results in an average Galactic mass injection rate of up to 10 to the -5th solar mass/yr if such clouds are frequent around solar-type stars. Cometary erosion by interstellar grains produces an injection rate of 10 to the -5th to 10 to the -4th solar mass/yr. An injection rate of 2 x 10 to the -5th solar mass/yr is calculated. Each of these rates could be increased by a factor of about 15 if the comet clouds contain a significant amount of smaller debris. It is concluded that the total mass injection rate of material to the ISM by comet clouds is small compared to other ISM mass injection sources. Comet cloud mass loss to the ISM could be responsible for a sizeable fraction of the metal and dust abundances of the ISM if Oort clouds are common.

Constraining the Origin of Impact Craters on Al Foils from the Stardust Interstellar Dust Collector

NASA Technical Reports Server (NTRS)

Stroud, Rhonda M.; Achilles, Cheri; Allen, Carlton; Ansari, Asna; Bajt, Sasa; Bassim, Nabil; Bastien, Ron S.; Bechtel, H. A.; Borg, Janet; Brenker, Frank E.;

COMPUTING THE DUST DISTRIBUTION IN THE BOW SHOCK OF A FAST-MOVING, EVOLVED STAR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Marle, A. J.; Meliani, Z.; Keppens, R.

2011-06-20

We study the hydrodynamical behavior occurring in the turbulent interaction zone of a fast-moving red supergiant star, where the circumstellar and interstellar material collide. In this wind-interstellar-medium collision, the familiar bow shock, contact discontinuity, and wind termination shock morphology form, with localized instability development. Our model includes a detailed treatment of dust grains in the stellar wind and takes into account the drag forces between dust and gas. The dust is treated as pressureless gas components binned per grain size, for which we use 10 representative grain size bins. Our simulations allow us to deduce how dust grains of varyingmore » sizes become distributed throughout the circumstellar medium. We show that smaller dust grains (radius <0.045 {mu}m) tend to be strongly bound to the gas and therefore follow the gas density distribution closely, with intricate fine structure due to essentially hydrodynamical instabilities at the wind-related contact discontinuity. Larger grains which are more resistant to drag forces are shown to have their own unique dust distribution, with progressive deviations from the gas morphology. Specifically, small dust grains stay entirely within the zone bound by shocked wind material. The large grains are capable of leaving the shocked wind layer and can penetrate into the shocked or even unshocked interstellar medium. Depending on how the number of dust grains varies with grain size, this should leave a clear imprint in infrared observations of bow shocks of red supergiants and other evolved stars.« less

IR spectra and properties of solid acetone, an interstellar and cometary molecule

NASA Astrophysics Data System (ADS)

Hudson, Reggie L.; Gerakines, Perry A.; Ferrante, Robert F.

2018-03-01

Mid-infrared spectra of amorphous and crystalline acetone are presented along with measurements of the refractive index and density for both forms of the compound. Infrared band strengths are reported for the first time for amorphous and crystalline acetone, along with IR optical constants. Vapor pressures and a sublimation enthalpy for crystalline acetone also are reported. Positions of 13C-labeled acetone are measured. Band strengths are compared to gas-phase values and to the results of a density-functional calculation. A 73% error in previous work is identified and corrected.

Organic solids produced by electrical discharges in reducing atmospheres: Molecular analysis

NASA Technical Reports Server (NTRS)

Khare, B. N.; Sagan, C.; Zumberge, J. E.; Sklarew, D.; Nagy, B.

1978-01-01

The complex brown polymer produced on passage of an electrical discharge through a mixture of methane, ammonia, and water, is analyzed by pyrolytic GC/MS. Pyrolyzates include a wide range of alkanes, alkenes, aromatic hydrocarbons, aliphatic and aromatic nitriles, pyrroles, and pyridine. Similar pyrolyzates are obtained from polypeptides and polynucleotides with hydrocarbon moieties. This polymer is remarkably stable up to 950 C; its degradation products are candidate constituents of planetary aerosols in the outer solar system and the grains and gas in the interstellar medium.

Experimental Studies of Hydrogenation and Other Reactions on Surfaces Under Astrophysically Relevant Conditions

NASA Technical Reports Server (NTRS)

Vidali, Gianfranco

1998-01-01

The goal of our project is to study hydrogen recombination reactions on solid surfaces under conditions that are relevant in astrophysics. Laboratory experiments were conducted using low-flux, cold atomic H and D beams impinging on a sample kept under ultra high vacuum conditions. Realistic analogues of interstellar dust grains were used. Our results show that current models for hydrogen recombination reactions have to be modified to take into account the role of activated diffusion of H on surfaces even at low temperature.

Chemistry Between The Stars.

ERIC Educational Resources Information Center

Gammon, Richard H.

This booklet is part of an American Astronomical Society curriculum project designed to provide teaching materials to teachers of secondary school chemistry, physics, and earth science. The following topics are covered: the physical conditions in interstellar space in comparison with those of the earth, particularly in regard to gas density,…

Infrared Spectra and Optical Constants of Elusive Amorphous Methane

NASA Technical Reports Server (NTRS)

Gerakines, Perry A.; Hudson, Reggie L.

2015-01-01

New and accurate laboratory results are reported for amorphous methane (CH4) ice near 10 K for the study of the interstellar medium (ISM) and the outer Solar System. Near- and mid-infrared (IR) data, including spectra, band strengths, absorption coefficients, and optical constants, are presented for the first time for this seldom-studied amorphous solid. The apparent IR band strength near 1300 cm(exp -1) (7.69 micrometer) for amorphous CH4 is found to be about 33% higher than the value long used by IR astronomers to convert spectral observations of interstellar CH4 into CH4 abundances. Although CH4 is most likely to be found in an amorphous phase in the ISM, a comparison of results from various laboratory groups shows that the earlier CH4 band strength at 1300 cm(exp -1) (7.69 micrometer) was derived from IR spectra of ices that were either partially or entirely crystalline CH4 Applications of the new amorphous-CH4 results are discussed, and all optical constants are made available in electronic form.

FIRST INFRARED BAND STRENGTHS FOR AMORPHOUS CO{sub 2}, AN OVERLOOKED COMPONENT OF INTERSTELLAR ICES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerakines, Perry A.; Hudson, Reggie L., E-mail: Reggie.Hudson@NASA.gov

2015-08-01

Solid carbon dioxide (CO{sub 2}) has long been recognized as a component of both interstellar and solar system ices, but a recent literature search has revealed significant qualitative and quantitative discrepancies in the laboratory spectra on which the abundances of extraterrestrial CO{sub 2} are based. Here we report new infrared (IR) spectra of amorphous CO{sub 2}-ice along with band intensities (band strengths) of four mid-IR absorptions, the first such results in the literature. A possible thickness dependence for amorphous-CO{sub 2} IR band shapes and positions also is investigated, and the three discordant reports of amorphous CO{sub 2} spectra in themore » literature are addressed. Applications of our results are discussed with an emphasis on laboratory investigations and results from astronomical observations. A careful comparison with earlier work shows that the IR spectra calculated from several databases for CO{sub 2} ices, all ices being made near 10 K, are not for amorphous CO{sub 2}, but rather for crystalline CO{sub 2} or crystalline-amorphous mixtures.« less

Copernicus spectra and infrared photometry of 42 Orionis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, H.M.; Snow, T.P. Jr.; Gehrz, R.D.

1977-04-01

The Orion sword star 42 Ori is embedded in a nebula north of and separated from the Orion nebula. The B1 V star is probably normal. Other members of the multiple remain poorly defined, and the nebula may exhibit some peculiarities that may depend on them. Copernicus ultraviolet spectra of the star are described here, especially in the form of tables of wavelength identifications. The properties of the interstellar material in the line of sight are also discussed. We present infrared photometry which suggests that 3 less than or equal to R less than or equal to 3.5 for themore » interstellar matter in the direction of 42 Ori. The IR photometry provides no evidence for companion stellar or circumstellar components.« less

Copernicus spectra and infrared photometry of 42 Orionis

NASA Technical Reports Server (NTRS)

Johnson, H. M.; Snow, T. P., Jr.; Gehrz, R. D.; Hackwell, J. A.

1977-01-01

The Orion sword star 42 Ori is embedded in a nebula north of and separated from the Orion nebula. The B1 V star is probably normal. Other members of the multiple remain poorly defined, and the nebula may exhibit some peculiarities that may depend on them. Copernicus ultraviolet spectra of the star are described here, especially in the form of tables of wavelength identifications. The properties of the interstellar material in the line of sight are also discussed. Infrared photometry is presented which suggests that the ratio of total to selective extinction ranges from 3 to 3.5 for the interstellar matter in the direction of 42 Ori. The IR photometry provides no evidence for companion stellar or circumstellar components.

Impacto ambiental de los remanentes de supernova

NASA Astrophysics Data System (ADS)

Dubner, G. M.

2015-08-01

The explosion of a supernovae (SN) represents the sudden injection of about ergs of thermal and mechanical energy in a small region of space, causing the formation of powerful shock waves that propagate through the interstellar medium at speeds of several thousands of km/s. These waves sweep, compress and heat the interstellar material that they encounter, forming the supernova remnants. Their evolution over thousands of years change forever, irreversibly, not only the physical but also the chemical properties of a vast region of space that can span hundreds of parsecs. This contribution briefly analyzes the impact of these explosions, discussing the relevance of some phenomena usually associated with SNe and their remnants in the light of recent theoretical and observational results.

Irradiation Effects in Fosterrite and the Nature of Interstellar Grains: A Coordinated Spectroscopy and Electron Microscopy Study

NASA Technical Reports Server (NTRS)

Keller, Lindsay P.; Christoffersen, R.

2007-01-01

Crystalline and amorphous silicates condense in the outflows of low mass evolved stars and massive red supergiant stars and are injected into the interstellar medium (ISM) where they are rendered almost completely amorphous by a multitude of destructive processes (e.g. shock, grain-grain collisions, and irradiation). Irradiation effects in particular may have played an important role in the genesis and modification of primitive grains in cometary dust, but unraveling those effects requires controlled experiments under appropriate conditions and with an emphasis on materials relevant to the ISM. Here we report our infrared (IR) microspectroscopy and trans-mission electron microscope (TEM) measurements on forsterite that was amorphized through irradiation by high energy heavy ions.

Side Group Addition to the PAH Coronene by UV Photolysis in Cosmic Ice Analogs

NASA Technical Reports Server (NTRS)

Bernstein, Max P.; Elsila, Jamie E.; Dworkin, Jason P.; Sandford, Scott A.; Allamandola, Louis J.; Zare, Richard N.; DeVincenzi, D. (Technical Monitor)

2002-01-01

Ultraviolet photolysis of various ice mixtures at low temperature and pressure caused the addition of amino (-NH2), methyl (-CH3), methoxy (-OCH3), and cyano (-CN) functional groups to the polycyclic aromatic hydrocarbon (PAH) coronene (C22H12). The implications of these results for interstellar and meteoritic chemistry are discussed. Previously only simple PAH photo-oxidation had been reported. This work represents the first experimental evidence that ice photochemistry may have contributed to aromatics bearing carbon and nitrogen containing side groups that are detected in primitive meteorites and interplanetary dust particles. Furthermore, these results suggest a wider range of modified PAHs should be expected in interstellar lees and materials predating solar system formation.

279 - Xanes Studies on UV-Irradiated Interstellar Ice Analogs: A Comparison to STARDUST Samples

NASA Technical Reports Server (NTRS)

Milam, Stefanie N.; Cody, George D.; Kilcoyne, A. L. David; Nuevo, Michel; Sandford, Scott A.; Stroud, Rhonda M.; DeGregorio, Bradley T.

2010-01-01

We present C-, N-, and O-XANES (X-ray Absorption Near-Edge Spectroscopy) results of organic residues produced in the laboratory from the UV irradiation of astrophysical ice analogs containing H20, CO, CH30H, NH31 in order to mimic processes that may occur in cold icy bodies of the outer Solar System, particularly in comets, Such analyses showed that laboratory-formed organic residues mainly consist of a solid phase and an oily phase. C-XANES analysis of the solid phase suggests a rich distribution of organic functionalities, among which carbonyl groups, C=C bonds, and alcohols are present. Results from N-XANES indicate the possible presence of amide, amine, and nitrile groups, The O-XANES spectra confirmed the a-bearing groups, These results are compared with the XANES spectra obtained from STARDUST cometary samples,

Exploring the Local Milky Way: M Dwarfs as Tracers of Galactic Populations

DTIC Science & Technology

2007-12-01

dark matter cos- mology have sought to recreate the infant Galaxy, tracing the formation and collapse of baryons within the dark matter halo (Brook...with dark matter halo and interstellar material contri- butions, and the potential is computed using the Poisson equa- tion. Stars are then evolved

LDEF: 69 Months in Space. First Post-Retrieval Symposium, part 2

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1992-01-01

A compilation of papers from the symposium is presented. The preliminary data analysis is presented of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, and micrometeoroid), electronics, optics, and life science.

Shedding light on the Type Ia supernova extinction puzzle: dust location found

NASA Astrophysics Data System (ADS)

Bulla, M.; Goobar, A.; Dhawan, S.

2018-06-01

The colour evolution of reddened Type Ia supernovae can place strong constraints on the location of dust and help address the question of whether the observed extinction stems from the interstellar medium or from circumstellar material surrounding the progenitor. Here we analyse BV photometry of 48 reddened Type Ia supernovae from the literature and estimate the dust location from their B - V colour evolution. We find a time-variable colour excess E(B - V) for 15 supernovae in our sample and constrain dust to distances between 0.013 and 45 pc (4 × 1016 - 1020 cm). For the remaining supernovae, we obtain a constant E(B - V) evolution and place lower limits on the dust distance from the explosion. In all the 48 supernovae, the inferred dust location is compatible with an interstellar origin for the extinction. This is corroborated by the observation that supernovae with relatively nearby dust (≲ 1 pc) are located close to the center of their host galaxy, in high-density dusty regions where interactions between the supernova radiation and interstellar clouds close by are likely to occur. For supernovae showing time-variable E(B - V), we identify a potential preference for low RV values, unusually strong sodium absorption and blue-shifted and time-variable absorption features. Within the interstellar framework, this brings evidence to a proposed scenario where cloud-cloud collisions induced by the supernova radiation pressure can shift the grain size distribution to smaller values and enhance the abundance of sodium in the gaseous phase.

Infrared Spectroscopy of the Dust in Comets and Relationships to Interstellar Dust

NASA Technical Reports Server (NTRS)

Hanner, Martha S.

2003-01-01

Infrared spectroscopy of the dust in comets reveals a complex mix of silicate materials, including both crystalline and non-crystalline components of both olivine (forsterite) and pyroxene composition. These various components do not necessarily share a common origin. Since comets formed in cold regions of the solar nebula, pre-solar grains in the nebula could have been accreted into comets with little alteration. Some of the cometary silicates may be of circumstellar (formed in circumstellar outflows of evolved stars) or interstellar (formed in dense region of the interstellar medium) origin. Spectral similarities to both circumstellar and interstellar silicates are seen in comet spectra. the short-period Kuiper Belt comets) show weak or no spectral features. The lack of features is generally explained as a particle size effect: the small silicate grains are embedded in larger, optically thick particles. However, compositional differences cannot be ruled out. For example, no unambiguous signature of forsterite has yet been seen in the spectrum of a short-period comet. Thus, the Stardust sample from short-period comet P/Wild 2 will be extremely valuable. Not only grain by grain composition and isotopic ratios but also grain morphology, irradiation history, and evidence of organic refractory mantles are important for understanding their origin. The relative abundance and distinguishing characteristics of the various crystalline and non-crystalline silicate components needs to be established. While some comets, such as Hale-Bopp, display a rich infrared spectrum, others (particularly

Deuterium and Oxygen Toward Feige 110: Results from the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission

NASA Technical Reports Server (NTRS)

Friedman, S. D.; Howk, J. C.; Chayer, P.; Tripp, T. M.; Hebrard, G.; Andre, M.; Oliveira, C.; Jenkins, E. B.; Moos, H. W.; Oegerle, William R.

2001-01-01

We present measurements of the column densities of interstellar D I and O I made with the Far Ultraviolet Spectroscopic Explorer (FUSE), and of H I made with the International Ultraviolet Explorer (IUE) toward the sdOB star Feige 110 [(l,b) = (74.09 deg., - 59.07 deg.); d = 179(sup +265, sub -67) pc; Z = -154(sup +57, Sub -227 pc). Our determination of the D I column density made use of curve of growth fitting and profile fitting analyses, while our O I column density determination used only curve of growth techniques. The H I column density was estimated by fitting the damping wings of the interstellar Ly(lpha) profile. We find log N(D I) = 15.47 +/- 0.06, log N(O I) = 16.73 +/- 0.10, and log N(H I) = 20.14(sup +0.13, sub -0.20) (all errors 2(sigma)). This implies D/H = (2.14 +/- 0.82) x 10(esp -5), D/O = (5.50(sup + 1.64, sub -133)) x 10(exp -2), and O/H = (3.89 +/- 1.67) x 10(exp -4). Taken with the FUSE results reported in companion papers and previous measurements of the local interstellar medium, this suggests the possibility of spatial variability in D/H for sight lines exceeding approx. 100 pc. This result may constrain models which characterize the mixing time and length scales of material in the local interstellar medium.

PSR B0329+54: substructure in the scatter-broadened image discovered with RadioAstron on baselines up to 330 000 km

NASA Astrophysics Data System (ADS)

Popov, Mikhail V.; Bartel, Norbert; Gwinn, Carl R.; Johnson, Michael D.; Andrianov, Andrey; Fadeev, Evgeny; Joshi, Bhal Chandra; Kardashev, Nikolay; Karuppusamy, Ramesh; Kovalev, Yuri Y.; Kramer, Michael; Rudnitskiy, Alexey; Shishov, Vladimir; Smirnova, Tatiana; Soglasnov, Vladimir A.; Zensus, J. Anton

2017-02-01

We have resolved the scatter-broadened image of PSR B0329+54 and detected a substructure within it. These results are not influenced by any extended structure of a source but instead are directly attributed to the interstellar medium. We obtained these results at 324 MHz with the ground-space interferometer RadioAstron, which included the Space Radio Telescope, ground-based Westerbork Synthesis Radio Telescope and 64-m Kalyazin Radio Telescope on baseline projections up to 330 000 km in 2013 November 22 and 2014 January 1 to 2. At short 15 000 to 35 000 km ground-space baseline projections, the visibility amplitude decreases with baseline length, providing a direct measurement of the size of the scattering disc of 4.8 ± 0.8 mas. At longer baselines, no visibility detections from the scattering disc would be expected. However, significant detections were obtained with visibility amplitudes of 3 to 5 per cent of the maximum scattered around a mean and approximately constant up to 330 000 km. These visibilities reflect a substructure from scattering in the interstellar medium and offer a new probe of ionized interstellar material. The size of the diffraction spot near Earth is 17 000 ± 3 000 km. With the assumption of turbulent irregularities in the plasma of the interstellar medium, we estimate that the effective scattering screen is located 0.6 ± 0.1 of the distance from the Earth towards the pulsar.

The Computational Science Education Reference Desk: A tool for increasing inquiry based learning in the science classroom

NASA Astrophysics Data System (ADS)

Joiner, D. A.; Stevenson, D. E.; Panoff, R. M.

2000-12-01

The Computational Science Reference Desk is an online tool designed to provide educators in math, physics, astronomy, biology, chemistry, and engineering with information on how to use computational science to enhance inquiry based learning in the undergraduate and pre college classroom. The Reference Desk features a showcase of original content exploration activities, including lesson plans and background materials; a catalog of websites which contain models, lesson plans, software, and instructional resources; and a forum to allow educators to communicate their ideas. Many of the recent advances in astronomy rely on the use of computer simulation, and tools are being developed by CSERD to allow students to experiment with some of the models that have guided scientific discovery. One of these models allows students to study how scientists use spectral information to determine the makeup of the interstellar medium by modeling the interstellar extinction curve using spherical grains of silicate, amorphous carbon, or graphite. Students can directly compare their model to the average interstellar extinction curve, and experiment with how small changes in their model alter the shape of the interstellar extinction curve. A simpler model allows students to visualize spatial relationships between the Earth, Moon, and Sun to understand the cause of the phases of the moon. A report on the usefulness of these models in two classes, the Computational Astrophysics workshop at The Shodor Education Foundation and the Conceptual Astronomy class at the University of North Carolina at Greensboro, will be presented.

Secondary Interstellar Oxygen in the Heliosphere: Numerical Modeling and Comparison with IBEX-Lo Data

NASA Astrophysics Data System (ADS)

Baliukin, I. I.; Izmodenov, V. V.; Möbius, E.; Alexashov, D. B.; Katushkina, O. A.; Kucharek, H.

2017-12-01

Quantitative analysis of the interstellar heavy (oxygen and neon) atom fluxes obtained by the Interstellar Boundary Explorer (IBEX) suggests the existence of the secondary interstellar oxygen component. This component is formed near the heliopause due to charge exchange of interstellar oxygen ions with hydrogen atoms, as was predicted theoretically. A detailed quantitative analysis of the fluxes of interstellar heavy atoms is only possible with a model that takes into account both the filtration of primary and the production of secondary interstellar oxygen in the boundary region of the heliosphere as well as a detailed simulation of the motion of interstellar atoms inside the heliosphere. This simulation must take into account photoionization, charge exchange with the protons of the solar wind and solar gravitational attraction. This paper presents the results of modeling interstellar oxygen and neon atoms through the heliospheric interface and inside the heliosphere based on a three-dimensional kinetic-MHD model of the solar wind interaction with the local interstellar medium and a comparison of these results with the data obtained on the IBEX spacecraft.

Summer School on Interstellar Processes: Abstracts of contributed papers

NASA Technical Reports Server (NTRS)

Hollenbach, D. J. (Editor); Thronson, H. A., Jr. (Editor)

1986-01-01

The Summer School on Interstellar Processes was held to discuss the current understanding of the interstellar medium and to analyze the basic physical processes underlying interstellar phenomena. Extended abstracts of the contributed papers given at the meeting are presented. Many of the papers concerned the local structure and kinematics of the interstellar medium and focused on such objects as star formation regions, molecular clouds, HII regions, reflection nebulae, planetary nebulae, supernova remnants, and shock waves. Other papers studied the galactic-scale structure of the interstellar medium either in the Milky Way or other galaxies. Some emphasis was given to observations of interstellar grains and

Interstellar Dust: Contributed Papers

NASA Technical Reports Server (NTRS)

Tielens, Alexander G. G. M. (Editor); Allamandola, Louis J. (Editor)

1989-01-01

A coherent picture of the dust composition and its physical characteristics in the various phases of the interstellar medium was the central theme. Topics addressed included: dust in diffuse interstellar medium; overidentified infrared emission features; dust in dense clouds; dust in galaxies; optical properties of dust grains; interstellar dust models; interstellar dust and the solar system; dust formation and destruction; UV, visible, and IR observations of interstellar extinction; and quantum-statistical calculations of IR emission from highly vibrationally excited polycyclic aromatic hydrocarbon (PAH) molecules.

Interstellar hydrogen bonding

NASA Astrophysics Data System (ADS)

Etim, Emmanuel E.; Gorai, Prasanta; Das, Ankan; Chakrabarti, Sandip K.; Arunan, Elangannan

2018-06-01

This paper reports the first extensive study of the existence and effects of interstellar hydrogen bonding. The reactions that occur on the surface of the interstellar dust grains are the dominant processes by which interstellar molecules are formed. Water molecules constitute about 70% of the interstellar ice. These water molecules serve as the platform for hydrogen bonding. High level quantum chemical simulations for the hydrogen bond interaction between 20 interstellar molecules (known and possible) and water are carried out using different ab-intio methods. It is evident that if the formation of these species is mainly governed by the ice phase reactions, there is a direct correlation between the binding energies of these complexes and the gas phase abundances of these interstellar molecules. Interstellar hydrogen bonding may cause lower gas abundance of the complex organic molecules (COMs) at the low temperature. From these results, ketenes whose less stable isomers that are more strongly bonded to the surface of the interstellar dust grains have been observed are proposed as suitable candidates for astronomical observations.

Four Interstellar Dust Candidates from the Stardust Interstellar Dust Collector

NASA Astrophysics Data System (ADS)

Westphal, A. J.; Allen, C.; Bajt, S.; Bechtel, H. A.; Borg, J.; Brenker, F.; Bridges, J.; Brownlee, D. E.; Burchell, M.; Burghammer, M.; Butterworth, A. L.; Cloetens, P.; Davis, A. M.; Floss, C.; Flynn, G. J.; Fougeray, P.; Frank, D.; Gainsforth, Z.; Grün, E.; Heck, P. R.; Hillier, J. K.; Hoppe, P.; Howard, L.; Hudson, B.; Huss, G. R.; Huth, J.; Kearsley, A.; King, A. J.; Lai, B.; Leitner, J.; Lemelle, L.; Leroux, H.; Lettieri, R.; Marchant, W.; Nittler, L. R.; Ogliore, R. C.; Postberg, F.; Price, M. C.; Sandford, S. A.; Sans Tresseras, J. A.; Schmitz, S.; Schoonjans, T.; Silversmit, G.; Simionovici, A.; Srama, R.; Stadermann, F. J.; Stephan, T.; Stodolna, J.; Stroud, R. M.; Sutton, S. R.; Toucoulou, R.; Trieloff, M.; Tsou, P.; Tsuchiyama, A.; Tyliczszak, T.; Vekemans, B.; Vincze, L.; Wordsworth, N.; Zevin, D.; Zolensky, M. E.; 29,000 Stardust@Home Dusters

2011-03-01

We report the discovery of two new interstellar dust candidates in the aerogel collectors of the Stardust Interstellar Dust Collector, and the analyses of these and two previously identified candidates.

The Interstellar Boundary Explorer (IBEX) - Time to Launch!

NASA Astrophysics Data System (ADS)

McComas, David

The Interstellar Boundary Explorer (IBEX) mission is scheduled to launch in mid-July 2008, right around the time of this COSPAR meeting. IBEX will make the first global observations of the heliosphere's interaction with the interstellar medium. IBEX achieves these breakthrough observations by traveling outside of the Earth's magnetosphere in a highly elliptical orbit and taking global Energetic Neutral Atoms (ENA) images with two very large aperture single pixel ENA cameras. IBEX-Lo makes measurements in 8 contiguous energy pass bands covering from ˜10 eV to 2 keV; IBEX-Hi similarly covers from ˜300 eV to 6 keV in 6 contiguous pass bands. IBEX's high-apogee (˜50RE ) orbit enables heliospheric ENA measurements by providing viewing from far outside the earth's relatively bright magnetospheric ENA emissions. The IBEX cameras view perpendicular to the spacecraft's sun-pointed spin axis. Each six months, the spacecraft spin and progression of the sun-pointing spin axis as the Earth moves around the Sun lead naturally to global, all-sky images. IBEX is the first mission to achieve a high altitude from a standard Pegasus launch vehicle. We accomplish this by adding the propulsion from an IBEX-supplied solid rocket motor and the spacecraft's hydrazine propulsion system. Additional information on IBEX is available at www.ibex.swri.edu. This talk, on behalf of the IBEX science and engineering teams, will summarize the IBEX science and mission and will provide an up-to-the-minute update on the status of the mission, including any new information on the launch and commissioning status.

Probing non polar interstellar molecules through their protonated form: Detection of protonated cyanogen (NCCNH+)★

PubMed Central

Agúndez, M.; Cernicharo, J.; de Vicente, P.; Marcelino, N.; Roueff, E.; Fuente, A.; Gerin, M.; Guélin, M.; Albo, C.; Barcia, A.; Barbas, L.; Bolaño, R.; Colomer, F.; Diez, M. C.; Gallego, J. D.; Gómez-González, J.; López-Fernández, I.; López-Fernández, J. A.; López-Pérez, J. A.; Malo, I.; Serna, J. M.; Tercero, F.

2015-01-01

Cyanogen (NCCN) is the simplest member of the series of dicyanopolyynes. It has been hypothesized that this family of molecules can be important constituents of interstellar and circumstellar media, although the lack of a permanent electric dipole moment prevents its detection through radioastronomical techniques. Here we present the first solid evidence of the presence of cyanogen in interstellar clouds through the detection of its protonated form toward the cold dark clouds TMC-1 and L483. Protonated cyanogen (NCCNH+) has been identified through the J = 5 – 4 and J = 10 – 9 rotational transitions using the 40m radiotelescope of Yebes and the IRAM 30m telescope. We derive beam averaged column densities for NCCNH+ of (8.6 ± 4.4) × 1010 cm−2 in TMC-1 and (3.9 ± 1.8) × 1010 cm−2 in L483, which translate to fairly low fractional abundances relative to H2, in the range (1-10) × 10−12. The chemistry of protonated molecules in dark clouds is discussed, and it is found that, in general terms, the abundance ratio between the protonated and non protonated forms of a molecule increases with increasing proton affinity. Our chemical model predicts an abundance ratio NCCNH+/NCCN of ~ 10−4, which implies that the abundance of cyanogen in dark clouds could be as high as (1-10) × 10−8 relative to H2, i.e., comparable to that of other abundant nitriles such as HCN, HNC, and HC3N. PMID:26543239

Millimeter and submillimeter wave spectra of 13C-glycolaldehydes

NASA Astrophysics Data System (ADS)

Haykal, I.; Motiyenko, R. A.; Margulès, L.; Huet, T. R.

2013-01-01

Context. Glycolaldehyde (CH2OHCHO) is the simplest sugar and an important intermediate in the path toward forming more complex biologically relevant molecules. Astronomical surveys of interstellar molecules, such as those available with the very sensitive ALMA telescope, require preliminary laboratory investigations of the microwave and submillimeter-wave spectra of molecular species including new isotopologs - to identify these in the interstellar media. Aims: To achieve the detection of the 13C isotopologs of glycolaldehyde in the interstellar medium, their rotational spectra in the millimeter and submillimeter-wave regions were studied. Methods: The spectra of 13CH2OHCHO and CH2OH13CHO were recorded in the 150-945 GHz spectral range in the laboratory using a solid-state submillimeter-wave spectrometer in Lille. The observed line frequencies were measured with an accuracy of 30 kHz up to 700 GHz and of 50 kHz above 700 GHz. We analyzed the spectra with a standard Watson Hamiltonian. Results: About 10 000 new lines were identified for each isotopolog. The spectroscopic parameters were determined for the ground- and the three lowest vibrational states up to 945 and 630 GHz. Previous microwave assignments of 13CH2OHCHO were not confirmed. Conclusions: The provided line-lists and sets of molecular parameters meet the needs for a first astrophysical search of 13C-glycolaldehydes. Full Tables 3 and 4 are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/549/A96

Cosmic ray processing of N2-containing interstellar ice analogues at dark cloud conditions

NASA Astrophysics Data System (ADS)

Fedoseev, G.; Scirè, C.; Baratta, G. A.; Palumbo, M. E.

2018-04-01

N2 is believed to lock considerable part of nitrogen elemental budget and, therefore, to be one of the most abundant ice constituent in cold dark clouds. This laboratory-based research utilizes high energetic processing of N2 containing interstellar ice analogues using 200 keV H+ and He+ ions that mimics cosmic ray processing of the interstellar icy grains. It aims to investigate the formation of (iso)cyanates and cyanides in the ice mantles at the conditions typical for cold dark clouds and prestellar cores. Investigation of cosmic ray processing as a chemical trigger mechanism is explained by the high stability of N2 molecules that are chemically inert in most of the atom- and radical-addition reactions and cannot be efficiently dissociated by cosmic ray induced UV-field. Two sets of experiments are performed to closer address solid-state chemistry occurring in two distinct layers of the ice formed at different stages of dark cloud evolution, i.e. `H2O-rich' and `CO-rich' ice layers. Formation of HNCO and OCN- is discussed in all of the performed experiments. Corresponding kinetic curves for HNCO and OCN- are obtained. Furthermore, a feature around 2092 cm-1 assigned to the contributions of 13CO, CN-, and HCN is analysed. The kinetic curves for the combined HCN/CN- abundance are derived. In turn, normalized formation yields are evaluated by interpolation of the obtained results to the low irradiation doses relevant to dark cloud stage. The obtained values can be used to interpret future observations towards cold dark clouds using James Webb Space Telescope.

Investigation of Celestial Solid Analogs

NASA Technical Reports Server (NTRS)

Sievers, A. J.

2003-01-01

Our far infrared studies of both hydrophobic and hydrophilic aerogel grains have demonstrated that the mm and sub-mm wave absorption produced by the fundamental two level systems (TLS) mechanism represents a more significant contribution for these open grain structures than for bulk amorphous silicate grains. We found that the region with the anomalous temperature dependence of the spectral index due to the TLS excitations can extend in a fluffy material up to 80 per cm, which is well beyond its typical upper limit for bulk glasses. Currently there is no theoretical explanation for this surprising result. The effects of reduced dimensionality on the optical properties of carbonaceous grains have been studied with a systematic investigation of carbon aerogels. This spectroscopic approach has permitted a more reliable determination of the single grain mass normalized absorption coefficient based on the experimentally determined characteristics of the fluffy material rather than on first principles calculations involving the bulk properties of the substance. Our finding is that the electrical connectivity of the material is the main factor affecting its far infrared absorption coefficient. Another one of the main constituents of the interstellar dust, amorphous ice, has been investigated in the mm-wave region both in the high (HDA) and low (LDA) density amorphous phases and as a function of impurities. We found that doping either phase with ionic (LiCl) or molecular (methanol) impurities decreases the difference in the mm-wave absorption coefficient between the HDA and LDA ice phases so that the HDA spectrum can be used as an analog for impure ice absorption in the far infrared spectral region.

Organic chemistry and biology of the interstellar medium

NASA Technical Reports Server (NTRS)

Sagan, C.

1973-01-01

Interstellar organic chemistry is discussed as the field of study emerging from the discovery of microwave lines of formaldehyde and of hydrogen cyanide in the interstellar medium. The reliability of molecular identifications and comparisons of interstellar and cometary compounds are considered, along with the degradational origin of simple organics. It is pointed out that the contribution of interstellar organic chemistry to problems in biology is not substantive but analogical. The interstellar medium reveals the operation of chemical processes which, on earth and perhaps on vast numbers of planets throughout the universe, led to the origin of life, but the actual molecules of the interstellar medium are unlikely to play any significant biological role.

Space Art "Stardust"

NASA Image and Video Library

2008-01-08

Artist Paul Henry Ramirez captured symbolically the Stardust mission in this peice titled "Stardust". The Stardust mission in January of 2006 completed a seven-year, 2.8 billion mile journey to fly by a comet and return samples to Earth. The material is a first sample of pristine cometary material which will increase human understanding of interstellar dust. Stardust, 2007. Acrylic Micaceous Iron Oxide, Aluminum and crystal, hologram glitter Mylar 20" round canvas. Copyrighted: For more information contact Curator, NASA Art Program.

Chemical Evolution of Interstellar Methanol Ice Analogs upon Ultraviolet Irradiation: The Role of the Substrate

NASA Astrophysics Data System (ADS)

Ciaravella, A.; Jiménez-Escobar, A.; Cosentino, G.; Cecchi-Pestellini, C.; Peres, G.; Candia, R.; Collura, A.; Barbera, M.; Di Cicca, G.; Varisco, S.; Venezia, A. M.

2018-05-01

An important issue in the chemistry of interstellar ices is the role of dust materials. In this work, we study the effect of an amorphous water-rich magnesium silicate deposited onto ZnSe windows on the chemical evolution of ultraviolet-irradiated methanol ices. For comparison, we also irradiate similar ices deposited onto bare ZnSe windows. Silicates are produced at relatively low temperatures exploiting a sol–gel technique. The chemical composition of the synthesized material reflects the forsterite stoichiometry. Si–OH groups and magnesium carbonates are incorporated during the process. The results show that the substrate material does affect the chemical evolution of the ice. In particular, the CO2/CO ratio within the ice is larger for methanol ices deposited onto the silicate substrate as a result of concurrent effects: the photolysis of carbonates present in the adopted substrate as a source of CO2, CO, and carbon and oxygen atoms; reactions of water molecules and hydroxyl radicals released from the substrate with the CO formed in the ice by the photolysis of the methanol ice; and changes in the structure and energy of the silicate surface by ultraviolet irradiation, leading to more favorable conditions for chemical reactions or catalysis at the grain surface. The results of our experiments allow such chemical effects contributed by the various substrate material components to be disentangled.

Time-dependent interstellar chemistry

NASA Technical Reports Server (NTRS)

Glassgold, A. E.

1985-01-01

Some current problems in interstellar chemistry are considered in the context of time-dependent calculations. The limitations of steady-state models of interstellar gas-phase chemistry are discussed, and attempts to chemically date interstellar clouds are reviewed. The importance of studying the physical and chemical properties of interstellar dust is emphasized. Finally, the results of a series of studies of collapsing clouds are described.

Properties of interstellar wind leading to shape morphology of the dust surrounding HD 61005

NASA Astrophysics Data System (ADS)

Pástor, P.

2017-08-01

Aims: A structure formed by dust particles ejected from the debris ring around HD 61005 is observed in the scattered light. The main aim here is to constrain interstellar wind parameters that lead to shape morphology in the vicinity of HD 61005 using currently available observational data for the debris ring. Methods: Equation of motion of 2 × 105 dust particles ejected from the debris ring under the action of the electromagnetic radiation, stellar wind, and interstellar wind is solved. A two-dimensional (2D) grid is placed in a given direction for accumulation of the light scattered on the dust particles in order to determine the shape morphology. The interaction of the interstellar wind and the stellar wind is considered. Results: Groups of unknown properties of the interstellar wind that create the observed morphology are determined. A relation between number densities of gas components in the interstellar wind and its relative velocity is found. Variations of the shape morphology caused by the interaction with the interstellar clouds of various temperatures are studied. When the interstellar wind velocity is tilted from debris ring axis a simple relation between the properties of the interstellar wind and an angle between the line of sight and the interstellar wind velocity exists. Dust particles that are most significantly influenced by stellar radiation move on the boundary of observed structure. Conclusions: Observed structure at HD 61005 can be explained as a result of dust particles moving under the action of the interstellar wind. Required number densities or velocities of the interstellar wind are much higher than that of the interstellar wind entering the solar system.

Deflection of the local interstellar dust flow by solar radiation pressure

NASA Technical Reports Server (NTRS)

Landgraf, M.; Augustsson, K.; Grun, E.; Gustafson, B. A.

1999-01-01

Interstellar dust grains intercepted by the dust detectors on the Ulysses and Galileo spacecrafts at heliocentric distances from 2 to 4 astronomical units show a deficit of grains with masses from 1 x 10(-17) to 3 x 10(-16) kilograms relative to grains intercepted outside 4 astronomical units. To divert grains out of the 2- to 4-astronomical unit region, the solar radiation pressure must be 1.4 to 1.8 times the force of solar gravity. These figures are consistent with the optical properties of spherical or elongated grains that consist of astronomical silicates or organic refractory material. Pure graphite grains with diameters of 0.2 to 0.4 micrometer experience a solar radiation pressure force as much as twice the force of solar gravity.

Ortho and parahydrogen in interstellar material

NASA Technical Reports Server (NTRS)

Reeves, R. R.; Harteck, P.

1979-01-01

The ortho/para molecular hydrogen ratio in the interstellar medium is considered. It is shown that the ortho/para ratio will be 3:1 in practically all chemical reactions, even at relatively low temperatures. Two examples of exothermic processes that will result in the formation of a 3:1 ortho:para ratio, corresponding to a high-temperature equilibrium, are examined: H2 formation via three-body or surface recombination and catalytic recombination involving electrons and H(-) ions. Gas-phase scrambling ion reactions are also discussed, and it is suggested that virtually all the H2 equilibrated via scrambling reactions involving H(+) and H3(+) ions should exist as parahydrogen in the J ? 0 quantum state. Arguments are given that deuterium cannot interfere with the long scrambling chain that results in parahydrogen formation.

The planetary and interstellar components of meteorites - A review

NASA Technical Reports Server (NTRS)

Marvin, Ursula B.

1987-01-01

Recent analyses show that, although most meteorites are collisional debris of asteroids, three meteorites collected on the Antarctic ice sheet were projected to earth from the highlands of the moon, and eight meteorites have chemical and isotopic compositions suggestive of derivation from Mars. Although meteorites are primarily of interest to planetary scientists for the abundance of clues they hold to the materials and processes that formed the solar system, they have begun to engage the attention of astrochemists because of isotopic and mineralogical indications that they contain interstellar components. Although each individual observation to this effect is inconclusive, the body of evidence is becoming ever more persuasive. This paper reviews the main classes of meteorites and their probable sources, with special emphasis on components that appear to be exotic to the solar system.

The abundance of interstellar oxygen toward Orion: Evidence for recent infall?

NASA Technical Reports Server (NTRS)

Meyer, David M.; Jura, M.; Hawkins, Isabel; Cardelli, Jason A.

1994-01-01

We present high S/N (greater than 800) Goddard High-Resolution Spectrograph (GHRS) observations of the weak interstellar O I lambda 1356 absorption in the low-density sight lines toward iota Ori and kappa Ori. By comparing these data with observations toward more reddened stars, we find no evidence of density-dependent depletion from the gas phase for oxygen. The derived total oxygen abundance (gas plus grains) towards iota Ori and kappa Ori is consistent with stellar and nebular determinations in Orion at a level that is one-half the solar value. We speculate that the O/H abundance ratio is lower in Orion compared to the Sun because the local Milky Way has suffered a recent infall of metal-poor material, perhaps from the Magellanic Stream.

Faraday rotation measure variations in the Cygnus region and the spectrum of interstellar plasma turbulence

NASA Technical Reports Server (NTRS)

Lazio, T. Joseph; Spangler, Steven R.; Cordes, James M.

1990-01-01

Linear polarization observations were made of eight double-lobed radio galaxies viewed through the galactic plane in the Cygnus region. These observations have been used to determine intra- and intersource rotation measure differences; in some cases, unambiguous rotation measures have been extracted. The rotation measures are dominated by foreground magnetoionic material. The differences in rotation measure between pairs of sources correlate with angular separation for separations from 10 arcsec to 1.5 deg. These rotation measure fluctuations are consistent with a model in which the electron density varies on roughly 0.1-200 pc scales. The amplitudes of these variations are, in turn, consistent with those electron density variations that cause diffractive interstellar scattering on scales less than 10 to the 11th cm.

Interstellar matter research with the Copernicus satellite

NASA Technical Reports Server (NTRS)

Spitzer, L., Jr.

1976-01-01

The use of the Copernicus satellite in an investigation of interstellar matter makes it possible to study absorption lines in the ultraviolet range which cannot be observed on the ground because of atmospheric absorption effects. A brief description is given of the satellite and the instrument used in the reported studies of interstellar matter. The results of the studies are discussed, giving attention to interstellar molecular hydrogen, the chemical composition of the interstellar gas, the coronal gas between the stars, and the interstellar abundance ratio of deuterium to hydrogen.

76 FR 8658 - Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-15

... Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes (IMSBC) Code..., the Coast Guard amended its regulations governing the carriage of solid hazardous materials in bulk to... hazardous bulk solid materials not addressed in the amended regulations. This notice announces that the...

Interstellar scintillation as the origin of the rapid radio variability of the quasar J1819+3845.

PubMed

Dennett-Thorpe, J; de Bruyn, A G

2002-01-03

The liberation of gravitational energy as matter falls onto a supermassive black hole at the centre of a galaxy is believed to explain the high luminosity of quasars. The variability of this emission from quasars and other types of active galactic nuclei can provide information on the size of the emitting regions and the physical process of fuelling the black hole. Some active galactic nuclei are variable at optical (and shorter) wavelengths, and display radio outbursts over years and decades. These active galactic nuclei often also show faster intraday variability at radio wavelengths. The origin of this rapid variability has been extensively debated, but a correlation between optical and radio variations in some sources suggests that both are intrinsic. This would, however, require radiation brightness temperatures that seem physically implausible, leading to the suggestion that the rapid variations are caused by scattering of the emission by the interstellar medium inside our Galaxy. Here we show that the rapid variations in the extreme case of quasar J1819+3845 (ref. 10) indeed arise from interstellar scintillation. The transverse velocity of the scattering material reveals the presence of plasma with a surprisingly high velocity close to the Solar System.

Molecular studies of Planetary Nebulae

NASA Astrophysics Data System (ADS)

Zhang, Yong

2017-10-01

Circumstellar envelopes (CEs) around evolved stars are an active site for the production of molecules. After evolving through the Asymptotic Giant Branch (AGB), proto-planetary nebula (PPN), to planetary nebula (PN) phases, CEs ultimately merge with the interstellar medium (ISM). The study of molecules in PNe, therefore, is essential to understanding the transition from stellar to interstellar materials. So far, over 20 molecular species have been discovered in PNe. The molecular composition of PNe is rather different from those of AGB and PPNe, suggesting that the molecules synthesized in PN progenitors have been heavily processed by strong ultraviolet radiation from the central star. Intriguingly, fullerenes and complex organic compounds having aromatic and aliphatic structures can be rapidly formed and largely survive during the PPN/PN evolution. The similar molecular compositions in PNe and diffuse clouds as well as the detection of C60 + in the ISM reinforce the view that the mass-loss from PNe can significantly enrich the ISM with molecular species, some of which may be responsible for the diffuse interstellar bands. In this contribution, I briefly summarize some recent observations of molecules in PNe, with emphasis on their implications on circumstellar chemistry.

KSC-08pd2042

NASA Image and Video Library

2008-07-09

VANDENBERG AIR FORCE BASE, Calif. -- Avionics shelf flatness and fillet gap measurements are conducted on the wing of a Pegasus rocket in Building 1555 at Vandenberg AFB. The testing was performed by workers from Advanced Digital Measuring Works using an API laser tracker. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. IBEX is targeted for launch in October 2008. Photo credit: NASA/Randy Beaudoin

KSC-08pd2043

NASA Image and Video Library

2008-07-11

VANDENBERG AIR FORCE BASE, Calif. -- Avionics shelf flatness and fillet gap measurements are conducted on the wing of a Pegasus rocket in Building 1555 at Vandenberg AFB. The testing was performed by workers from Advanced Digital Measuring Works using an API laser tracker. The Pegasus will launch NASA's Interstellar Boundary Explorer Mission, or IBEX, satellite from Kwajalein Island in the Marshall Islands, South Pacific. IBEX will make the first map of the boundary between the solar system and interstellar space. IBEX is the first mission designed to detect the edge of the solar system. As the solar wind from the sun flows out beyond Pluto, it collides with the material between the stars, forming a shock front. IBEX contains two neutral atom imagers designed to detect particles from the termination shock at the boundary between the solar system and interstellar space. IBEX also will study galactic cosmic rays, energetic particles from beyond the solar system that pose a health and safety hazard for humans exploring beyond Earth orbit. IBEX will make these observations from a highly elliptical orbit that takes it beyond the interference of the Earth's magnetosphere. IBEX is targeted for launch in October 2008. Photo credit: NASA/Randy Beaudoin

Third LDEF Post-Retrieval Symposium Abstracts

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Compiler)

1993-01-01

This volume is a compilation of abstracts submitted to the Third Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium. The abstracts represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, micrometeoroid, etc.), electronics, optics, and life science.

LDEF: 69 Months in Space. First Post-Retrieval Symposium, part 1

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1992-01-01

A compilation of papers from the symposium is presented. The papers represent the preliminary data analysis of the 57 experiments flown on the Long Duration Exposure Facility (LDEF). The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, and micrometeoroids), electronics, optics, and life sciences.

Angular Broadening of Intraday Variable AGNs II. Interstellar and Intergalactic Scattering

DTIC Science & Technology

2008-01-01

scin - tillators’’ and ‘‘nonscintillators.’’ Since the publication of that paper, it has been realized that some of the AGNs identified as...these results is obtained if the scin - tillation is produced from small ‘‘clumps’’ of scattering material, distributed throughout the Galactic disk. For

The interstellar C-H stretching band near 3.4 microns - Constraints on the composition of organic material in the diffuse interstellar medium

NASA Technical Reports Server (NTRS)

Sandford, S. A.; Allamandola, L. J.; Tielens, A. G. G. M.; Pendleton, Y.; Sellgren, K.

1991-01-01

The composition and history of dust in the diffuse ISM was studied using 3600-2700/cm absorption spectra of objects which have widely varying amounts of visual extinctions along different lines of sight. The 3300/cm and 2950/cm features are attributed to O-H and C-H stretching vibrations, respectively. The O-H feature in OH 32.8-0.3 is suggestive of circumstellar water ice and is probably not due to material in the diffuse ISM. The features in the 3100-2700/cm region are attributed either to C-H vibrations or to M stars. The spectra of the latter show a series of narrow features in this region that are identified with photospheric OH. Objects in which these bands are seen include OH 01-477, T629-5, and the Galactic center source IRS 7. The C-H stretch feature of diffuse ISM dust has subpeaks which fall within 5/cm of C-H stretching vibrations in the -CH2- and -CH3 groups of saturated aliphatic hydrocarbons.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nuth, Joseph A.; Kimura, Yuki; Lucas, Christopher

It has been suggested that carbonaceous grains are efficiently destroyed in the interstellar medium and must either reform in situ at very low pressures and temperatures or in an alternative environment more conducive to grain growth. Graphite whiskers have been discovered associated with high-temperature phases in meteorites such as calcium aluminum inclusions and chondrules, and it has been suggested that the expulsion of such material from protostellar nebulae could significantly affect the optical properties of the average interstellar grain population. We have experimentally studied the potential for Fischer-Tropsch and Haber-Bosch type reactions to produce organic materials in protostellar systems frommore » the abundant H{sub 2}, CO, and N{sub 2} reacting on the surfaces of available silicate grains. When graphite grains are repeatedly exposed to H{sub 2}, CO, and N{sub 2} at 875 K abundant graphite whiskers are observed to form on or from the surfaces of the graphite grains. In a dense, turbulent nebula, such extended whiskers are very likely to be broken off, and fragments could be ejected either in polar jets or by photon pressure after transport to the outer reaches of the nebula.« less

The Formation of Graphite Whiskers in the Primitive Solar Nebula

NASA Technical Reports Server (NTRS)

Nuth, Joseph A., III; Kimura, Yuki; Lucas, Christopher; Ferguson, Frank; Johnson, Natasha M.

2010-01-01

It has been suggested that carbonaceous grains are efficiently destroyed in the interstellar medium and must either reform in situ at very low pressures and temperatures or in an alternative environment more conducive to grain growth. Graphite whiskers have been discovered associated with high-temperature phases in meteorites such as calcium aluminum inclusions and chondrules, and it has been suggested that the expulsion of such material from proto stellar nebulae could significantly affect the optical properties of the average interstellar grain population. We have experimentally studied the potential for Fischer-Tropsch and Haber-Bosch type reactions to produce organic materials in protostellar systems from the abundant H2, CO, and N2 reacting on the surfaces of available silicate grains. When graphite grains are repeatedly exposed to H2, CO, and N2 at 875 K abundant graphite whiskers are observed to form on or from the surfaces of the graphite grains. In a dense, turbulent nebula, such extended whiskers are very likely to be broken off, and fragments could be ejected either in polar jets or by photon pressure after transport to the outer reaches of the nebula.

The Discovery of a Microarcsecond Quasar: J1819+3845.

PubMed

Dennett-Thorpe; de Bruyn AG

2000-02-01

We report on the discovery of a source that exhibits over 300% amplitude changes in radio flux density on the period of hours. This source, J1819+3845, is the most extremely variable extragalactic source known in the radio sky. We believe these properties are due to interstellar scintillation and show that the source must emit at least 55% of its flux density within a radius of fewer than 16 µas at 5 GHz. The apparent brightness temperature is greater than 5x1012 K, and the source may be explained by a relativistically moving source with a Doppler factor of approximately 15. The scattering occurs predominantly in material only a few tens of parsecs from the Earth, which explains its unusually rapid variability. If the source PKS 0405-385 is similarly affected by local scattering material, Doppler factors of approximately 1000 are not required to explain this source. The discovery of a second source whose properties are well modeled by interstellar scintillation strengthens the argument for this as the cause for much of the variation seen in intraday variables.

Outbursts in Symbiotic Binaries

NASA Technical Reports Server (NTRS)

Sonneborn, George (Technical Monitor); Kenyon, Scott J.

2004-01-01

Two models have been proposed for the outbursts of symbiotic stars. In the thermonuclear model, outbursts begin when the hydrogen burning shell of a hot white dwarf reaches a critical mass. After a rapid increase in the luminosity and effective temperature, the white dwarf evolves at constant luminosity to lower effective temperatures, remains at optical maximum for several years, and then returns to quiescence along a white dwarf cooling curve. In disk instability models, the brightness rises when the accretion rate from the disk onto the central white dwarf abruptly increases by factors of 5-20. After a few month to several year period at maximum, both the luminosity and the effective temperature of the disk decline as the system returns to quiescence. If most symbiotic stars undergo thermonuclear eruptions, then symbiotics are probably poor candidates for type I supernovae. However, they can then provide approx. 10% of the material which stars recycle back into the interstellar medium. If disk instabilities are the dominant eruption mechanism, symbiotics are promising type Ia candidates but recycle less material into the interstellar medium.

Chaotic Exchange of Solid Material Between Planetary Systems: Implications for Lithopanspermia

PubMed Central

Belbruno, Edward; Malhotra, Renu; Savransky, Dmitry

2012-01-01

Abstract We examined a low-energy mechanism for the transfer of meteoroids between two planetary systems embedded in a star cluster using quasi-parabolic orbits of minimal energy. Using Monte Carlo simulations, we found that the exchange of meteoroids could have been significantly more efficient than previously estimated. Our study is relevant to astrobiology, as it addresses whether life on Earth could have been transferred to other planetary systems in the Solar System's birth cluster and whether life on Earth could have been transferred from beyond the Solar System. In the Solar System, the timescale over which solid material was delivered to the region from where it could be transferred via this mechanism likely extended to several hundred million years (as indicated by the 3.8–4.0 Ga epoch of the Late Heavy Bombardment). This timescale could have overlapped with the lifetime of the Solar birth cluster (∼100–500 Myr). Therefore, we conclude that lithopanspermia is an open possibility if life had an early start. Adopting parameters from the minimum mass solar nebula, considering a range of planetesimal size distributions derived from observations of asteroids and Kuiper Belt objects and theoretical coagulation models, and taking into account Oort Cloud formation models, we discerned that the expected number of bodies with mass>10 kg that could have been transferred between the Sun and its nearest cluster neighbor could be of the order of 1014 to 3·1016, with transfer timescales of tens of millions of years. We estimate that of the order of 3·108·l (km) could potentially be life-bearing, where l is the depth of Earth's crust in kilometers that was ejected as the result of the early bombardment. Key Words: Extrasolar planets—Interplanetary dust—Interstellar meteorites—Lithopanspermia. Astrobiology 12, 754–774. PMID:22897115

Organic Analysis in the Miller Range 090657 CR2 Chondrite: Part 3 C and N Isotopic Imaging

NASA Technical Reports Server (NTRS)

Messenger, S.; Nakamura-Messenger, K.; Elsila, J. E.; Berger, E. L.; Burton, A. S.; Clemett, S. J.; Cao, T.

2016-01-01

Primitive carbonaceous chondrites contain a wide variety of organic material, ranging from soluble discrete molecules to insoluble nanoglobules of macro-molecular carbon. The relationship between the soluble organic molecules, macromolecular organic material, and host minerals are poorly understood. Large H, C and N isotopic anomalies suggest some organic components formed in low-T interstellar or outer Solar System environments. The highest isotope anomalies occur in m-scale inclusions in the most primitive materials, such as cometary dust and the least altered carbonaceous chondrites. Often, the hosts of these isotopically anomalous 'hotspots' are discrete organic nanoglobules that probably formed in the outermost reaches of the protosolar disk or cold molecular cloud. Molecular and isotopic studies of meteoritic organic matter are aimed at identifying the chemical properties and formation processes of interstellar organic materials and the subsequent chemical evolutionary pathways in various Solar System environments. The combination of soluble and insoluble analyses with in situ and bulk studies provides powerful constraints on the origin and evolution of organic matter in the Solar System. Using macroscale extraction and analysis techniques as well as microscale in situ observations we have been studying both insoluble and soluble organic material in primitive astromaterial samples. Here, we present results of bulk C and N isotopic measurements and coordinated in situ C and N isotopic imaging and mineralogical and textural studies of carbonaceous materials in a Cr2 carbonaceous chondrite. In accompanying abstracts we discuss the morphology and distribution of carbonaceous components and soluble organic species of this meteorite.

Radiation Effects in Hydrogen-Laden Porous Water Ice Films: Implications for Interstellar Ices

NASA Astrophysics Data System (ADS)

Raut, Ujjwal; Baragiola, Raul; Mitchell, Emma; Shi, Jianming

H _{2} is the dominant gas in the dense clouds of the interstellar medium (ISM). At densities of 10 (5) cm (-3) , an H _{2} molecule arrives at the surface of a 0.1 mum-sized, ice-covered dust grain once every few seconds [1]. At 10 K, H _{2} can diffuse into the pores of the ice mantle and adsorb at high-energy binding sites, loading the ice with hydrogen over the lifetime of the cloud. These icy grains are also impacted by galactic cosmic rays and stellar winds (in clouds with embedded protostar). Based on the available cosmic proton flux spectrum [2], we estimate a small impact rate of nearly 1 hit per year on a 0.1 μm sized grain, or 10 (-7) times the impact frequency of the neutral H _{2}. The energy deposited by such impacts can release the adsorbed H _{2} into the gas phase (impact desorption or sputtering). Recently, we have reported on a new process of ion-induced enhanced adsorption, where molecules from the gas phase are incorporated into the film when irradiation is performed in the presence of ambient gas [3]. The interplay between ion-induced ejection and adsorption can be important in determining the gas-solid balance in the ISM. To understand the effects of cosmic rays/stellar winds impacts on interstellar ice immersed in H _{2} gas, we have performed irradiation of porous amorphous ice films loaded with H _{2} through co-deposition or adsorption following growth. The irradiations were performed with 100 keV H (+) using fluxes of 10 (10) -10 (12) H (+) cm (-2) s (-1) at 7 K, in presence of ambient H _{2} at pressures ranging from 10 (-5) to 10 (-8) Torr. Our initial results show a net loss in adsorbed H _{2} during irradiation, from competing ion-induced ejection and adsorption. The H _{2} loss per ion decreases exponentially with fluence, with a cross-section of 10 (-13) cm (2) . In addition to hydrogen removal, irradiation also leads to trapping of H _{2} in the ice film, from closing of the pores during irradiation [4]. As a result, 2.6 percent H _{2} molar remains trapped in the ice even upon removal of ambient gas-phase H _{2}, and is stable to 170 K, where the ice film desorbs. We will describe the dependence of net loss of adsorbed hydrogen on important parameters such as ice film thickness and the ratio of ion flux (f) to H _{2} flux (F _{H}). Both fluxes are higher by orders of magnitude than interstellar values. However, the information obtained from these experiments, especially the behavior in the limit of low flux (f << F _{H}) should be relevant to the interstellar case. Furthermore, we will discuss the effects of the presence of H _{2} in radiation chemistry of water ice, in particular, the observed suppression in H _{2}O _{2} synthesis. References: 1.Tielens, A.G.G.M., The Physics and Chemistry of the Interstellar Medium. 2005: Cambridge University Press. 2.Webber, W.R. and S.M. Yushak, A measurement of the energy spectra and relative abundance of the cosmic-ray H and He isotopes over a broad energy range. Astrophysical Journal, 1983. 275: p. 391-404. 3.Shi, J., B.D. Teolis, and R.A. Baragiola, Irradiation-enhanced adsorption and trapping of O2 on nanoporous water ice. Physical Review B, 2009. 79(23): p. 235422. 4.Raut, U., et al., Compaction of microporous amorphous solid water by ion irradiation. Journal of Chemical Physics, 2007. 126(24): p. 244511.

New Large Interstellar Molecules Detected with the GBT

NASA Technical Reports Server (NTRS)

Hollis, Jan M.

2005-01-01

At present, more than 135 different molecules have been identified in interstellar clouds. The newest instrument in the interstellar molecule search arsenal is the recently commissioned Green Bank Telescope (GBT). In 2004, the large aldehydes propenal (CH2CHCHO) and propanal (CH3CH2CHO) were the first new interstellar molecules discovered with the GBT. At the same time, the GBT was used to observe interstellar glycolaldehyde (CH2OHCHO), which is the simplest possible aldehyde sugar; interstellar ethylene glycol (HOCH2CH2OH), which is the sugar alcohol of glycolaldehyde; and interstellar methylcyanodiacetylene (CH3C5N). These new GBT observations suggest that successive atomic addition reactions are common in the formation of larger related species. The observations will be presented and discussed.

A brief visit from a red and extremely elongated interstellar asteroid.

PubMed

Meech, Karen J; Weryk, Robert; Micheli, Marco; Kleyna, Jan T; Hainaut, Olivier R; Jedicke, Robert; Wainscoat, Richard J; Chambers, Kenneth C; Keane, Jacqueline V; Petric, Andreea; Denneau, Larry; Magnier, Eugene; Berger, Travis; Huber, Mark E; Flewelling, Heather; Waters, Chris; Schunova-Lilly, Eva; Chastel, Serge

2017-12-21

None of the approximately 750,000 known asteroids and comets in the Solar System is thought to have originated outside it, despite models of the formation of planetary systems suggesting that orbital migration of giant planets ejects a large fraction of the original planetesimals into interstellar space. The high predicted number density of icy interstellar objects (2.4 × 10 -4 per cubic astronomical unit) suggests that some should have been detected, yet hitherto none has been seen. Many decades of asteroid and comet characterization have yielded formation models that explain the mass distribution, chemical abundances and planetary configuration of the Solar System today, but there has been no way of telling whether the Solar System is typical of planetary systems. Here we report observations and analysis of the object 1I/2017 U1 ('Oumuamua) that demonstrate its extrasolar trajectory, and that thus enable comparisons to be made between material from another planetary system and from our own. Our observations during the brief visit by the object to the inner Solar System reveal it to be asteroidal, with no hint of cometary activity despite an approach within 0.25 astronomical units of the Sun. Spectroscopic measurements show that the surface of the object is spectrally red, consistent with comets or organic-rich asteroids that reside within the Solar System. Light-curve observations indicate that the object has an extremely oblong shape, with a length about ten times its width, and a mean radius of about 102 metres assuming an albedo of 0.04. No known objects in the Solar System have such extreme dimensions. The presence of 'Oumuamua in the Solar System suggests that previous estimates of the number density of interstellar objects, based on the assumption that all such objects were cometary, were pessimistically low. Planned upgrades to contemporary asteroid survey instruments and improved data processing techniques are likely to result in the detection of more interstellar objects in the coming years.

Abiogenic synthesis of nucleotides on the surface of small space bodies with high energy particles

NASA Astrophysics Data System (ADS)

Simakov, M. B.; Kuzicheva, E. A.; Antropov, A. E.; Dodonova, N. Ya

Abiotic formation of such complex biochemical compounds as nucleotides and oligopeptides on the surface of interstellar and interplanetary dust particles (IDP) by cosmic radiation was examined. In order to study the formation of organic compounds on IDPs, solid films prepared from nucleososide and inorganic phosphate were irradiated with high energy protons. Irradiated products were analyzed with HPLC. The natural nucleotides were detected. The main products were 5' AMP (3.2%) and 2'3' cAMP (2.7%). The results were compared with others experiments on the action of ultraviolet radiation with different wavelengths, γ-radiation and heat on solid mixtures of biologically significant compounds. The experiment on abiogenic synthesis of nucleotides on board of space satellite "BION-11" was compared also. The present results suggest that a considerable amount of complex biochemical compounds formed in extraterrestrial environments could have been supplied to the primitive earth before the origin of life.

Quantifying atom addition reactions on amorphous solid water: a review of recent laboratory advances

NASA Astrophysics Data System (ADS)

He, Jiao; Vidali, Gianfranco

2018-06-01

Complex organic molecules found in space are mostly formed on and in the ice mantle covering interstellar dust grains. In clouds where ionizing irradiation is insignificant, chemical reactions on the ice mantle are dominated by thermal processes. Modeling of grain surface chemistry requires detailed information from the laboratory, including sticking coefficients, binding energies, diffusion energy barriers, mechanism of reaction, and chemical desorption rates. In this talk, recent laboratory advances in obtaining these information would be reviewed. Specifically, this talk will focus on the efforts in our group in: 1) Determining the mechanism of atomic hydrogen addition reactions on amorphous solid water (ASW); 2) Measuring the chemical desorption coefficient of H+O3-->O2+OH using the time-resolved scattering technique; and 3) Measuring the diffusion energy barrier of volatile molecules on ASW. Further laboratory studies will be suggested.This research was supported by NSF Astronomy & Astrophysics Research Grant #1615897.

Hydrogen isotopic substitution of solid methylamine through atomic surface reactions at low temperatures: A potential contribution to the D/H ratio of methylamine in molecular clouds

NASA Astrophysics Data System (ADS)

Oba, Yasuhiro; Chigai, Takeshi; Osamura, Yoshihiro; Watanabe, Naoki; Kouchi, Akira

2014-01-01

We experimentally studied hydrogen (H)-deuterium (D) substitution reactions of solid methylamine (CH3NH2) under astrophysically relevant conditions. We also calculated the potential energy surface for the H-D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol-1, CH3NH2 reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H-D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.

The Diffuse Interstellar Bands: Solving a Century Old Problem

NASA Technical Reports Server (NTRS)

Salama, Farid

2017-01-01

The Diffuse Interstellar Bands (DIBs) are a set of apporoximately 500 absorption bands that are seen in the spectra of reddened stars (i.e., stars obscured by the presence of interstellar clouds in their line of sight). The first DIBs were detected in the visible over a century ago. Diffuse Interstellar Bands are now detected from the near ultraviolet to the near infrared in the spectra of reddened stars spanning a variety of interstellar environments in our local, and in other galaxies. Although DIB carriers are a significant part of the interstellar chemical inventory as they account for a noticeable fraction of the interstellar extinction, the nature of their carriers is still unknown over a century after the detection of the first bands. DIB carriers are stable and ubiquitous in a broad variety of interstellar environments and play a unique role in interstellar physics and chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics and astrochemistry, quantum chemistry calculations and astrophysical modeling of line-of-sights. In this review, we'll present and discuss the current state of this perplexing problem. We'll review the progress and the failures that have been encountered in the long quest for the identification of the carriers of these ubiquitous interstellar bands.

Calibration of impact ionization cosmic dust detectors: first tests to investigate how the dust density influences the signal

NASA Astrophysics Data System (ADS)

Jasmin Sterken, Veerle; Moragas-Klostermeyer, Georg; Hillier, Jon; Fielding, Lee; Lovett, Joseph; Armes, Steven; Fechler, Nina; Srama, Ralf; Bugiel, Sebastian; Hornung, Klaus

2016-10-01

Impact ionization experiments have been performed since more than 40 years for calibrating cosmic dust detectors. A linear Van de Graaff dust accelerator was used to accelerate the cosmic dust analogues of submicron to micron-size to speeds up to 80 km s^-1. Different materials have been used for calibration: iron, carbon, metal-coated minerals and most recently, minerals coated with conductive polymers. While different materials with different densities have been used for instrument calibration, a comparative analysis of dust impacts of equal material but different density is necessary: porous or aggregate-like particles are increasingly found to be present in the solar system: e.g. dust from comet 67P Churyumov-Gerasimenko [Fulle et al 2015], aggregate particles from the plumes of Enceladus [Gao et al 2016], and low-density interstellar dust [Westphal 2014 et al, Sterken et al 2015]. These recalibrations are relevant for measuring the size distributions of interplanetary and interstellar dust and thus mass budgets like the gas-to-dust mass ratio in the local interstellar cloud.We report about the calibrations that have been performed at the Heidelberg dust accelerator facility for investigating the influence of particle density on the impact ionization charge. We used the Cassini Cosmic Dust Analyzer for the target, and compared hollow versus compact silica particles in our study as a first attempt to investigate experimentally the influence of dust density on the signals obtained. Also, preliminary tests with carbon aerogel were performed, and (unsuccessful) attempts to accelerate silica aerogel. In this talk we explain the motivation of the study, the experiment set-up, the preparation of — and the materials used, the results and plans and recommendations for future tests.Fulle, M. et al 2015, The Astrophysical Journal Letters, Volume 802, Issue 1, article id. L12, 5 pp. (2015)Gao, P. et al 2016, Icarus, Volume 264, p. 227-238Westphal, A. et al 2014, Science, Volume 345, Issue 6198, pp. 786-791 (2014)Sterken, V.J. et al 2015, The Astrophysical Journal, Volume 812, Issue 2, article id. 141, 24 pp. (2015)

Solid materials for removing metals and fabrication method

DOEpatents

Coronado, Paul R.; Reynolds, John G.; Coleman, Sabre J.

2004-10-19

Solid materials have been developed to remove contaminating metals and organic compounds from aqueous media. The contaminants are removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the metals and the organics leaving a purified aqueous stream. The materials are sol-gel and or sol-gel and granulated activated carbon (GAC) mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards the contaminant(s). The contaminated solid materials can then be disposed of or the contaminant can be removed and the solids recycled.

iWander: Dynamics of interstellar wanderers

NASA Astrophysics Data System (ADS)

Zuluaga, Jorge I.; Sanchez-Hernandez, Oscar; Sucerquia, Mario; Ferrin, Ignacio

2018-01-01

iWander assesses the origin of interstellar small bodies such as asteroids and comets. It includes a series of databases and tools that can be used in general for studying the dynamics of an interstellar vagabond object (small‑body, interstellar spaceship and even stars).

15N Fractionation in Star-Forming Regions and Solar System Objects

NASA Technical Reports Server (NTRS)

Wirstrom, Eva; Milam, Stefanie; Adande, GIlles; Charnley, Steven; Cordiner, Martin

2015-01-01

A central issue for understanding the formation and evolution of matter in the early Solar System is the relationship between the chemical composition of star-forming interstellar clouds and that of primitive Solar System materials. The pristinemolecular content of comets, interplanetary dust particles and carbonaceous chondrites show significant bulk nitrogen isotopic fractionation relative to the solar value, 14N15N 440. In addition, high spatial resolution measurements in primitive materials locally show even more extreme enhancements of 14N15N 100.

Protostars are Nature's Chemical Factories

NASA Technical Reports Server (NTRS)

Nuth, Joseph A. III; Johnson, Natasha M.

2005-01-01

H(2-2), N2 and CO are the most abundant molecular constituents in astrophysical environments, including protostellar nebulae. Although some organic molecules may be produced on very long timescales by the irradiation of ices formed on the cold surfaces of interstellar grains and these molecules may be an important source of raw materials leading to the origin of life on Earth, pre-solar organics could be swamped by the efficient conversion of nebular H2, N2 and CO to simple organic materials.

LDEF: 69 Months in Space. Third Post-Retrieval Symposium, part 2

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1995-01-01

This volume is a compilation of papers presented at the Third Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium. The papers represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, micrometeoroid, etc.), electronics, optics, and life science. In addition, papers on preliminary data analysis of EURECA, EOIM-3, and other spacecraft are included. This second of three parts covers spacecraft construction materials.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bzowski, M.; Kubiak, M. A.; Sokol, J. M.

Because of its high ionization potential and weak interaction with hydrogen, neutral interstellar helium (NISHe) is almost unaffected at the heliospheric interface with the interstellar medium and freely enters the solar system. This second most abundant species provides some of the best information on the characteristics of the interstellar gas in the local interstellar cloud. The Interstellar Boundary Explorer (IBEX) is the second mission to directly detect NISHe. We present a comparison between recent IBEX NISHe observations and simulations carried out using a well-tested quantitative simulation code. Simulation and observation results compare well for times when measured fluxes are dominatedmore » by NISHe (and contributions from other species are small). Differences between simulations and observations indicate a previously undetected secondary population of neutral helium, likely produced by interaction of interstellar helium with plasma in the outer heliosheath. Interstellar neutral parameters are statistically different from previous in situ results obtained mostly from the GAS/Ulysses experiment, but they do agree with the local interstellar flow vector obtained from studies of interstellar absorption: the newly established flow direction is ecliptic longitude 79.{sup 0}2, latitude -5.{sup 0}1, the velocity is {approx}22.8 km s{sup -1}, and the temperature is 6200 K. These new results imply a markedly lower absolute velocity of the gas and thus significantly lower dynamic pressure on the boundaries of the heliosphere and different orientation of the Hydrogen Deflection Plane compared to prior results from Ulysses. A different orientation of this plane also suggests a new geometry of the interstellar magnetic field, and the lower dynamic pressure calls for a compensation by other components of the pressure balance, most likely a higher density of interstellar plasma and strength of interstellar magnetic field.« less

LOCAL INTERSTELLAR MEDIUM: SIX YEARS OF DIRECT SAMPLING BY IBEX

DOE Office of Scientific and Technical Information (OSTI.GOV)

McComas, D. J.; Fuselier, S. A.; Schwadron, N. A., E-mail: dmccomas@swri.edu, E-mail: sfuselier@swri.edu, E-mail: Nathan.schwadron@unh.edu

2015-10-15

The Interstellar Boundary Explorer (IBEX) has been directly observing neutral atoms from the local interstellar medium for the last six years (2009–2014). This paper ties together the 14 studies in this Astrophysical Journal Supplement Series Special Issue, which collectively describe the IBEX interstellar neutral results from this epoch and provide a number of other relevant theoretical and observational results. Interstellar neutrals interact with each other and with the ionized portion of the interstellar population in the “pristine” interstellar medium ahead of the heliosphere. Then, in the heliosphere's close vicinity, the interstellar medium begins to interact with escaping heliospheric neutrals. Inmore » this study, we compare the results from two major analysis approaches led by IBEX groups in New Hampshire and Warsaw. We also directly address the question of the distance upstream to the pristine interstellar medium and adjust both sets of results to a common distance of ∼1000 AU. The two analysis approaches are quite different, but yield fully consistent measurements of the interstellar He flow properties, further validating our findings. While detailed error bars are given for both approaches, we recommend that for most purposes, the community use “working values” of ∼25.4 km s{sup −1}, ∼75.°7 ecliptic inflow longitude, ∼ −5.°1 ecliptic inflow latitude, and ∼7500 K temperature at ∼1000 AU upstream. Finally, we briefly address future opportunities for even better interstellar neutral observations to be provided by the Interstellar Mapping and Acceleration Probe mission, which was recommended as the next major Heliophysics mission by the NRC's 2013 Decadal Survey.« less

Evolution of interstellar organic compounds under asteroidal hydrothermal conditions

NASA Astrophysics Data System (ADS)

Vinogradoff, V.; Bernard, S.; Le Guillou, C.; Remusat, L.

2018-05-01

Carbonaceous chondrites (CC) contain a diversity of organic compounds. No definitive evidence for a genetic relationship between these complex organic molecules and the simple organic molecules detected in the interstellar medium (ISM) has yet been reported. One of the many difficulties arises from the transformations of organic compounds during accretion and hydrothermal alteration on asteroids. Here, we report results of hydrothermal alteration experiments conducted on a common constituent of interstellar ice analogs, Hexamethylenetetramine (HMT - C6H12N4). We submitted HMT to asteroidal hydrothermal conditions at 150 °C, for various durations (up to 31 days) and under alkaline pH. Organic products were characterized by gas chromatography mass spectrometry, infrared spectroscopy and synchrotron-based X-ray absorption near edge structure spectroscopy. Results show that, within a few days, HMT has evolved into (1) a very diverse suite of soluble compounds dominated by N-bearing aromatic compounds (> 150 species after 31 days), including for instance formamide, pyridine, pyrrole and their polymers (2) an aromatic and N-rich insoluble material that forms after only 7 days of experiment and then remains stable through time. The reaction pathways leading to the soluble compounds likely include HMT dissociation, formose and Maillard-type reactions, e.g. reactions of sugar derivatives with amines. The present study demonstrates that, if interstellar organic compounds such as HMT had been accreted by chondrite parent bodies, they would have undergone chemical transformations during hydrothermal alteration, potentially leading to the formation of high molecular weight insoluble organic molecules. Some of the diversity of soluble and insoluble organic compounds found in CC may thus result from asteroidal hydrothermal alteration.

Organics In Meteorites

NASA Technical Reports Server (NTRS)

Chang, Sherwood

1996-01-01

The variety of classes of organic compounds that occur in carbonaceous meteorites suggests a rich pre-planetary chemistry with possible connections to interstellar, solar nebular and parent body processes. Structural diversity prevails within all classes examined in detail. Among amino acids for instance, all possible isomers are found up to species containing 4-6 carbon atoms, with abundances decreasing with increasing molecular weight. Such diversity seems limited to those carbonaceous meteorites which show evidence of having been exposed to liquid water; meteorites lacking such evidence also show much lower abundances and less structural diversity in their organic contents. This apparent dependency on water suggests a role for cometary ices in the chemical evolution of organic compounds on parent bodies. Measurements of the stable isotope compositions of C, H, N and S in classes of compounds and at the individual compound level show strong deviations from average chondritic values. These deviations are difficult to explain by solar system or parent body processes, and precedents for some of these isotopic anomalies exist in interstellar (e.g., high D/H ratios) and circumstellar chemistry. Therefore, presolar origins for much if not all of the meteoritic organic compounds (or their precursors) is a distinct possibility. In contrast, evidence of solar nebular origins is either lacking or suspect. Results from molecular and isotopic analyses of meteoritic organics, from laboratory simulations and from a model of interstellar grain reactions will be used to flesh out the hypothesis that this material originated with interstellar chemistry, was distributed within the early solar system as cometary ices, and was subsequently altered on meteorite parent bodies to yield the observed compounds.

Observational aspects of polycyclic aromatic hydrocarbon charging in the Interstellar Medium

NASA Technical Reports Server (NTRS)

Bakes, E. L. O.; Tielens, Alexander G. G. M.

1995-01-01

We have investigated the charging processes which affect small carbonaceous dust grains and polycyclic aromatic hydrocarbons (PAH's). Because of their high abundance, interstellar PAH molecules can dominate the charge balance of the interstellar medium (ISM), which controls the heating and cooling interstellar gas and interstellar chemistry. We present the results of our model, which compare well with observations and suggest further applications to both laboratory measurements and data obtainable from the KAO.

The violent interstellar medium

NASA Technical Reports Server (NTRS)

Mccray, R.; Snow, T. P., Jr.

1979-01-01

Observational evidence for high-velocity and high-temperature interstellar gas is reviewed. The physical processes that characterize this gas are described, including the ionization and emissivity of coronal gas, the behavior and appearance of high-velocity shocks, and interfaces between coronal gas and cooler interstellar gas. Hydrodynamical models for the action of supernova explosions and stellar winds on the interstellar medium are examined, and recent attempts to synthesize all the processes considered into a global model for the interstellar medium are discussed.

The interstellar depletion mystery, or where have all those atoms gone. [cosmic abundance as grain model evidence

NASA Technical Reports Server (NTRS)

Greenberg, J. M.

1974-01-01

The observed depletion of intermediate-weight elements O, C, and N from the interstellar medium is shown to be significantly greater than can be accounted for by accretion on interstellar dust. A number of possible explanations are presented, ranging from the existence in interstellar space of many 'snowballs' intermediate in size between dust grains and comets to the existence of many far more complicated interstellar molecules than have been detected.

Method and apparatus for semi-solid material processing

DOEpatents

Han, Qingyou [Knoxville, TN; Jian, Xiaogang [Knoxville, TN; Xu, Hanbing [Knoxville, TN; Meek, Thomas T [Knoxville, TN

2009-02-24

A method of forming a material includes the steps of: vibrating a molten material at an ultrasonic frequency while cooling the material to a semi-solid state to form non-dendritic grains therein; forming the semi-solid material into a desired shape; and cooling the material to a solid state. The method makes semi-solid castings directly from molten materials (usually a metal), produces grain size usually in the range of smaller than 50 .mu.m, and can be easily retrofitted into existing conventional forming machine.

Method and apparatus for semi-solid material processing

DOEpatents

Han, Qingyou [Knoxville, TN; Jian, Xiaogang [Knoxville, TN; Xu, Hanbing [Knoxville, TN; Meek, Thomas T [Knoxville, TN

2009-11-24

A method of forming a material includes the steps of: vibrating a molten material at an ultrasonic frequency while cooling the material to a semi-solid state to form non-dendritic grains therein; forming the semi-solid material into a desired shape; and cooling the material to a solid state. The method makes semi-solid castings directly from molten materials (usually a metal), produces grain size usually in the range of smaller than 50 .mu.m, and can be easily retrofitted into existing conventional forming maching.

Method and apparatus for semi-solid material processing

DOEpatents

Han, Qingyou [Knoxville, TN; Jian, Xiaogang [Knoxville, TN; Xu, Hanbing [Knoxville, TN; Meek, Thomas T [Knoxville, TN

2007-05-15

A method of forming a material includes the steps of: vibrating a molten material at an ultrasonic frequency while cooling the material to a semi-solid state to form non-dendritic grains therein; forming the semi-solid material into a desired shape; and cooling the material to a solid state. The method makes semi-solid castings directly from molten materials (usually a metal), produces grain size usually in the range of smaller than 50 .mu.m, and can be easily retrofitted into existing conventional forming machine.

LDEF: 69 Months in Space. Part 4: Second Post-Retrieval Symposium

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1993-01-01

A compilation of papers presented at the Second Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium are presented. The papers represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, micrometeoroid, etc.), electronics, optics, and life sciences.

LDEF: 69 Months in Space. Part 1: Second Post-Retrieval Symposium

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1993-01-01

A compilation of papers presented at the Second Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium is included. The papers represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, micrometeoroid, etc.), electronics, optics, and life sciences.

Exobiology and life science

NASA Technical Reports Server (NTRS)

Mckay, C. P.

1987-01-01

The following types of experiments for a proposed Space Station Microgravity Particle Research Facility are described: (1) biogenic elements in the interstellar medium; (2) organic material in the solar nebula; (3) volatiles in comets and icy planetesimals; (4) pre-biotic atmospheric chemistry; (5) analysis of cosmic dust particles; and (6) microbial exposure. The required capabilities and desired hardware for the facility are detailed.

LDEF: 69 Months in Space. Part 3: Second Post-Retrieval Symposium

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1993-01-01

Papers presented at the Second Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium are included. The papers represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, micrometeoroid, etc.), electronics, optics, and life science.

Investigating the interstellar dust through the Fe K-edge

NASA Astrophysics Data System (ADS)

Rogantini, D.; Costantini, E.; Zeegers, S. T.; de Vries, C. P.; Bras, W.; de Groot, F.; Mutschke, H.; Waters, L. B. F. M.

2018-01-01

Context. The chemical and physical properties of interstellar dust in the densest regions of the Galaxy are still not well understood. X-rays provide a powerful probe since they can penetrate gas and dust over a wide range of column densities (up to 1024 cm-2). The interaction (scattering and absorption) with the medium imprints spectral signatures that reflect the individual atoms which constitute the gas, molecule, or solid. Aims: In this work we investigate the ability of high resolution X-ray spectroscopy to probe the properties of cosmic grains containing iron. Although iron is heavily depleted into interstellar dust, the nature of the Fe-bearing grains is still largely uncertain. Methods: In our analysis we use iron K-edge synchrotron data of minerals likely present in the ISM dust taken at the European Synchrotron Radiation Facility. We explore the prospects of determining the chemical composition and the size of astrophysical dust in the Galactic centre and in molecular clouds with future X-ray missions. The energy resolution and the effective area of the present X-ray telescopes are not sufficient to detect and study the Fe K-edge, even for bright X-ray sources. Results: From the analysis of the extinction cross sections of our dust models implemented in the spectral fitting program SPEX, the Fe K-edge is promising for investigating both the chemistry and the size distribution of the interstellar dust. We find that the chemical composition regulates the X-ray absorption fine structures in the post edge region, whereas the scattering feature in the pre-edge is sensitive to the mean grain size. Finally, we note that the Fe K-edge is insensitive to other dust properties, such as the porosity and the geometry of the dust. The absorption, scattering, and extinction cross sections of the compounds are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/609/A22

Reaction of H + HONO in solid para-hydrogen: infrared spectrum of ˙ONH(OH).

PubMed

Haupa, Karolina Anna; Tielens, Alexander Godfried Gerardus Maria; Lee, Yuan-Pern

2017-06-21

Hydrogenation reactions in the N/O chemical network are important for an understanding of the mechanism of formation of organic molecules in dark interstellar clouds, but many reactions remain unknown. We present the results of the reaction H + HONO in solid para-hydrogen (p-H 2 ) at 3.3 K investigated with infrared spectra. Two methods that produced hydrogen atoms were the irradiation of HONO molecules in p-H 2 at 365 nm to produce OH radicals that reacted readily with nearby H 2 to produce mobile H atoms, and irradiation of Cl 2 molecules (co-deposited with HONO) in p-H 2 at 405 nm to produce Cl atoms that reacted, upon IR irradiation of the p-H 2 matrix, readily with nearby H 2 to produce mobile H atoms. In both experiments, we assigned IR lines at 3549.6 (ν 1 ), 1465.0 (ν 3 ), 1372.2 (ν 4 ), 898.5/895.6 (ν 6 ), and 630.9 (ν 7 ) cm -1 to hydroxy(oxido)-λ 5 -azanyl radical [˙ONH(OH)], the primary product of HONO hydrogenation. Two weak lines at 3603.4 and 991.0 cm -1 are tentatively assigned to the dihydroxy-λ 5 -azanyl radical, ˙N(OH) 2 . The assignments were derived according to the consideration of possible reactions and comparison of observed vibrational wavenumbers and their IR intensities with values predicted quantum-chemically with the B3LYP/aug-cc-pVTZ method. The agreement between observed and calculated D/H- and 15 N/ 14 N-isotopic ratios further supports these assignments. The role of this reaction in the N/O chemical network in dark interstellar clouds is discussed.

Solid materials for removing arsenic and method thereof

DOEpatents

Coronado, Paul R.; Coleman, Sabre J.; Sanner, Robert D.; Dias, Victoria L.; Reynolds, John G.

2010-09-28

Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

Solid materials for removing arsenic and method thereof

DOEpatents

Coronado, Paul R [Livermore, CA; Coleman, Sabre J [Oakland, CA; Sanner, Robert D [Livermore, CA; Dias, Victoria L [Livermore, CA; Reynolds, John G [San Ramon, CA

2008-07-01

Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

Gas-grain chemical models of star-forming molecular clouds as constrained by ISO and SWAS observations

NASA Astrophysics Data System (ADS)

Charnley, S. B.; Rodgers, S. D.; Ehrenfreund, P.

2001-11-01

We have investigated the gaseous and solid state molecular composition of dense interstellar material that periodically experiences processing in the shock waves associated with ongoing star formation. Our motivation is to confront these models with the stringent abundance constraints on CO2, H2O and O2, in both gas and solid phases, that have been set by ISO and SWAS. We also compare our results with the chemical composition of dark molecular clouds as determined by ground-based telescopes. Beginning with the simplest possible model needed to study molecular cloud gas-grain chemistry, we only include additional processes where they are clearly required to satisfy one or more of the ISO-SWAS constraints. When CO, N2 and atoms of N, C and S are efficiently desorbed from grains, a chemical quasi-steady-state develops after about one million years. We find that accretion of CO2 and H2O cannot explain the [CO2/H2O]ice ISO observations; as with previous models, accretion and reaction of oxygen atoms are necessary although a high O atom abundance can still be derived from the CO that remains in the gas. The observational constraints on solid and gaseous molecular oxygen are both met in this model. However, we find that we cannot explain the lowest H2O abundances seen by SWAS or the highest atomic carbon abundances found in molecular clouds; additional chemical processes are required and possible candidates are given. One prediction of models of this type is that there should be some regions of molecular clouds which contain high gas phase abundances of H2O, O2 and NO. A further consequence, we find, is that interstellar grain mantles could be rich in NH2OH and NO2. The search for these regions, as well as NH2OH and NO2 in ices and in hot cores, is an important further test of this scenario. The model can give good agreement with observations of simple molecules in dark molecular clouds such as TMC-1 and L134N. Despite the fact that S atoms are assumed to be continously desorbed from grain surfaces, we find that the sulphur chemistry independently experiences an ``accretion catastrophe''. The S-bearing molecular abundances cease to lie within the observed range after about 3 x 106 years and this indicates that there may be at least two efficient surface desorption mechanisms operating in dark clouds - one quasi-continous and the other operating more sporadically on this time-scale. We suggest that mantle removal on short time-scales is mediated by clump dynamics, and by the effects of star formation on longer time-scales. The applicability of this type of dynamical-chemical model for molecular cloud evolution is discussed and comparison is made with other models of dark cloud chemistry.

Mass, energy and material balances of SRF production process. Part 3: solid recovered fuel produced from municipal solid waste.

PubMed

Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

2015-02-01

This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream. © The Author(s) 2014.

75 FR 34682 - Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-18

...] RIN 1625-AB47 Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk... on June 17, 2010, entitled ``Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes (IMSBC) Code.'' This correction provides correct information with regard to the...

Interstellar molecules and dense clouds.

NASA Technical Reports Server (NTRS)

Rank, D. M.; Townes, C. H.; Welch, W. J.

1971-01-01

Current knowledge of the interstellar medium is discussed on the basis of recent published studies. The subjects considered include optical identification of interstellar molecules, radio molecular lines, interstellar clouds, isotopic abundances, formation and disappearance of interstellar molecules, and interstellar probing techniques. Diagrams are plotted for the distribution of galactic sources exhibiting molecular lines, for hydrogen molecule, hydrogen atom and electron abundances due to ionization, for the densities, velocities and temperature of NH3 in the direction of Sagitarius B2, for the lower rotational energy levels of H2CO, and for temporal spectral variations in masing H2O clouds of the radio source W49. Future applications of the maser and of molecular microscopy in this field are visualized.

Tumbling motion of 1I/`Oumuamua and its implications for the body's distant past

NASA Astrophysics Data System (ADS)

Drahus, Michał; Guzik, Piotr; Waniak, Wacław; Handzlik, Barbara; Kurowski, Sebastian; Xu, Siyi

2018-05-01

Models of the Solar System's evolution show that almost all the primitive material leftover from the formation of the planets was ejected to the interstellar space as a result of dynamical instabilities1. Accordingly, minor bodies should also be ejected from other planetary systems and should be abundant in the interstellar space2, giving hope for their direct detection and detailed characterization as they penetrate through the Solar System3,4. These expectations materialized on 19 October 2017 ut with the Panoramic Survey Telescope and Rapid Response System's discovery of 1I/`Oumuamua5. Here, we report homogeneous photometric observations of this body from Gemini North, which densely cover a total of 8.06 h over two nights. A combined ultra-deep image of 1I/`Oumuamua shows no signs of cometary activity, confirming the results from other, less sensitive searches6-9. Our data also show an enormous range of rotational brightness variations of 2.6 ± 0.2 mag, larger than ever observed in the population of small Solar System objects, suggesting a very elongated shape of the body. Most significantly, the light curve does not repeat exactly from one rotation cycle to another and its double-peaked periodicity of 7.56 ± 0.01 h from our data is inconsistent with earlier determinations6,7,10-12. These are clear signs of a tumbling motion, a remarkable characteristic of 1I/`Oumuamua's rotation that is consistent with a collision in the distant past. Bearing marks of a violent history, this first-known interstellar visitor tells us that collisional evolution of minor body populations in other planetary systems might be common.

Clustering in the stellar abundance space

NASA Astrophysics Data System (ADS)

Boesso, R.; Rocha-Pinto, H. J.

2018-03-01

We have studied the chemical enrichment history of the interstellar medium through an analysis of the n-dimensional stellar abundance space. This work is a non-parametric analysis of the stellar chemical abundance space. The main goal is to study the stars from their organization within this abundance space. Within this space, we seek to find clusters (in a statistical sense), that is, stars likely to share similar chemo-evolutionary history, using two methods: the hierarchical clustering and the principal component analysis. We analysed some selected abundance surveys available in the literature. For each sample, we labelled the group of stars according to its average abundance curve. In all samples, we identify the existence of a main enrichment pattern of the stars, which we call chemical enrichment flow. This flow is set by the structured and well-defined mean rate at which the abundances of the interstellar medium increase, resulting from the mixture of the material ejected from the stars and stellar mass-loss and interstellar medium gas. One of the main results of our analysis is the identification of subgroups of stars with peculiar chemistry. These stars are situated in regions outside of the enrichment flow in the abundance space. These peculiar stars show a mismatch in the enrichment rate of a few elements, such as Mg, Si, Sc and V, when compared to the mean enrichment rate of the other elements of the same stars. We believe that the existence of these groups of stars with peculiar chemistry may be related to the accretion of planetary material on to stellar surfaces or may be due to production of the same chemical element by different nucleosynthetic sites.

The interstellar N2 abundance towards HD 124314 from far-ultraviolet observations.

PubMed

Knauth, David C; Andersson, B-G; McCandliss, Stephan R; Moos, H Warren

2004-06-10

The abundance of interstellar molecular nitrogen (N2) is of considerable importance: models of steady-state gas-phase interstellar chemistry, together with millimetre-wavelength observations of interstellar N2H+ in dense molecular clouds predict that N2 should be the most abundant nitrogen-bearing molecule in the interstellar medium. Previous attempts to detect N2 absorption in the far-ultraviolet or infrared (ice features) have hitherto been unsuccessful. Here we report the detection of interstellar N2 at far-ultraviolet wavelengths towards the moderately reddened star HD 124314 in the constellation of Centaurus. The N2 column density is larger than expected from models of diffuse clouds and significantly smaller than expected for dense molecular clouds. Moreover, the N2 abundance does not explain the observed variations in the abundance of atomic nitrogen (N I) towards high-column-density sightlines, implying that the models of nitrogen chemistry in the interstellar medium are incomplete.

Copernicus observations of interstellar matter in the direction of HR 1099

NASA Technical Reports Server (NTRS)

Anderson, R. C.; Weiler, E. J.

1978-01-01

Results are reported for high-resolution Copernicus U1 and V2 scans of the bright RS CVn spectroscopic binary HR 1099. The observations reveal strong UV emission lines at L-alpha and Mg II h and k from the stars as well as interstellar H I and D I L-alpha absorption lines and interstellar Mg II h and k absorption in the direction of the binary system. Column densities, bulk velocities, and temperatures are derived for the interstellar features. A comparison of the derived number density of interstellar H I with data for the nearby star Epsilon Eri indicates an inhomogeneous distribution of interstellar hydrogen along the line of sight. The range of values obtained for the D/H ratio is shown to be consistent with results of other studies. A depletion factor of at least 5 with respect to the solar abundance is estimated for the interstellar magnesium.

Laboratory spectroscopy and astronomical significance of the fully-benzenoid PAH triphenylene and its cation

NASA Astrophysics Data System (ADS)

Kofman, V.; Sarre, P. J.; Hibbins, R. E.; ten Kate, I. L.; Linnartz, H.

2017-06-01

Triphenylene (C18H12) is a highly symmetric polycyclic aromatic hydrocarbon (PAH) molecule with a 'fully-benzenoid' electronic structure. This confers a high chemical stability compared with PAHs of similar size. Although numerous infrared and UV-vis experimental spectroscopic and theoretical studies of a wide range PAHs in an astrophysical context have been conducted, triphenylene and its radical cation have received almost no attention. There exists a huge body of spectroscopic evidence for neutral and ionised PAHs in astrophysical sources, obtained principally through detection of infrared emission features that are characteristic of PAHs as a chemical class. However, it has so far not proved possible to identify spectroscopically a single isolated PAH in space, although PAHs including triphenylene have been detected mass spectrometrically in meteorites. In this work we focus on recording laboratory electronic spectra of neutral and ionised triphenylene between 220 and 780 nm, trapped in H2O ice and solid argon at 12 K. The studies are motivated by the potential for spectroscopic astronomical detection of electronic absorption spectra of PAHs in ice mantles on interstellar grains as discussed by Linnartz (2014), and were performed also in a cold Ar matrix to provide guidance as to whether triphenylene (particularly in its singly positively ionised form) could be a viable candidate for any of the unidentified diffuse interstellar absorption bands. Based on the argon-matrix experimental results, comparison is made with previously unpublished astronomical spectra near 400 nm which contain broad interstellar absorption features consistent with the predictions from the laboratory matrix spectra, thus providing motivation for the recording of gas-phase electronic spectra of the internally cold triphenylene cation.

Differential adsorption of CHON isomers at interstellar grain surfaces

NASA Astrophysics Data System (ADS)

Lattelais, M.; Pauzat, F.; Ellinger, Y.; Ceccarelli, C.

2015-06-01

Context. The CHON generic chemical formula covers different isomers such as isocyanic acid (HNCO), cyanic acid (HOCN), fulminic acid (HCNO), and isofulminic acid (HONC); the first three have been identified in a large variety of environments in the interstellar medium (ISM). Several phenomena could be at the origin of the observed abundances, such as different pathways of formation and destruction involving gas phase reactions with different possible activation barriers and/or surface processes depending on the local temperature and the nature of the support. Aims: The scope of this article is to shed some light on the interaction of the CHON isomers with interstellar grains as a function of the nature of the surface and to determine the corresponding adsorption energies in order to find whether this phenomenon could play a role in the abundances observed in the ISM. Methods: The question was addressed by means of numerical simulations using first principle periodic density functional theory (DFT) to represent the grain support as a solid of infinite dimension. Results: Regardless of the nature of the model surface (water ice, graphene, silica), two different classes of isomers were identified: weakly bound (HNCO and HCNO) and strongly bound (HOCN and HONC), with the adsorption energies of the latter group being about twice those of the former. The range of the adsorption energies is (from highest to lowest) HOCN > HONC > HNCO > HCNO. They are totally disconnected from the relative stabilities, which range from HNCO > HOCN > HCNO > HONC. Conclusions: The possibility of hydrogen bonding is the discriminating factor in the trapping of CHON species on grain surfaces. Whatever the environment, differential adsorption is effective and its contribution to the molecular abundances should not be ignored. The theoretical adsorption energies provided here could be profitably used for a more realistic modeling of molecule-surfaces interactions.

Excess depletion of Al, Ca, Ti from interstellar gas

NASA Technical Reports Server (NTRS)

Clayton, D. D.

1986-01-01

Thermal condensation, cold sticking, and sputtering by interstellar shock are combined with a chemical memory of the condensation sequence to account for depletion of aluminum, calcium, and titanium in interstellar gas. The extra depletion of aluminum and calcium becomes an indicator of the structural history of the refractory parts of interstellar grains.

40 CFR 227.32 - Liquid, suspended particulate, and solid phases of a material.

Code of Federal Regulations, 2010 CFR

2010-07-01

... solid phases of a material. 227.32 Section 227.32 Protection of Environment ENVIRONMENTAL PROTECTION... MATERIALS Definitions § 227.32 Liquid, suspended particulate, and solid phases of a material. (a) For the... obtained above prior to centrifugation and filtration. The solid phase includes all material settling to...

40 CFR 227.32 - Liquid, suspended particulate, and solid phases of a material.

Code of Federal Regulations, 2011 CFR

2011-07-01

... solid phases of a material. 227.32 Section 227.32 Protection of Environment ENVIRONMENTAL PROTECTION... MATERIALS Definitions § 227.32 Liquid, suspended particulate, and solid phases of a material. (a) For the... obtained above prior to centrifugation and filtration. The solid phase includes all material settling to...

Where is the Most Likely Location Where the Secondary Interstellar Oxygen Atoms Are Created Around the Heliosheath?

NASA Astrophysics Data System (ADS)

Park, J.; Kucharek, H.; Szabo, A.; Paschalidis, N.; Grocer, A.; Jones, S.

2017-12-01

The secondary component of the interstellar neutral gas flow is originated from charge exchange between the undisturbed primary interstellar neutrals and the ions that have been deflected as they approach the heliopause. The secondary neutrals that are emitted from the interstellar ion flow through charge exchange carry information on the diverted flow and a fraction of them can travel to the Sun. Therefore, the secondary component of the interstellar neutrals is an excellent diagnostic tool to provide important information to constrain the shape of the heliopause. The presence of the secondary neutrals was predicted in the global heliospheric models and they are observed by Interstellar Boundary Explorer (IBEX) at Earth's orbit. Using the IBEX observations of neutral helium atoms, Kubiak et al. (2016, ApJS, 223, 25) approximated the parent distribution of the secondary interstellar He atoms (so-called Warm Breeze) with a homogeneous Maxwellian distribution function. Park et al. (2016, ApJ, 833, 130) analyzed IBEX observations of secondary interstellar helium and oxygen distributions at Earth's orbit. Lee et al. (2012, ApJS, 198, 10) constructed the heliospheric phase-space distribution function of an interstellar gas species in the Earth frame as a function of solar longitude. In this distribution, the authors assume that the distribution is a drifting Maxwellian at large distances from the Sun. In this study, we assume that a fraction of the secondary neutral atoms has a velocity vector toward the Sun and they can be described as a flow with a drifting Maxwellian distribution near the heliopause. Unlike the primary interstellar gas flow, the distribution of the secondary neutrals is expected to have a wide width and their bulk speeds are slower than the bulk speed of the primary interstellar gas flow. We compare Lee's distribution and IBEX observations of neutral oxygen atoms and then estimate the most likely direction where the secondary interstellar oxygen atoms are created near the heliopause.

Formation of doubly and triply bonded unsaturated compounds HCN, HNC, and CH2NH via N + CH4 low-temperature solid state reaction: from molecular clouds to solar system objects

NASA Astrophysics Data System (ADS)

Mencos, Alejandro; Krim, Lahouari

2018-06-01

We show in the current study carried out in solid phase at cryogenic temperatures that methane (CH4) ice exposed to nitrogen atoms is a source of two acids HCN, HNC, and their corresponding hydrogenated unsaturated species CH2NH, in addition to CH3, C2H6, CN-, and three nitrogen hydrides NH, NH2, and NH3. The solid state N + CH4 reaction taken in the ground state seems to be strongly temperature dependent. While at temperatures lower than 10 K only CH3, NH, NH2, and NH3 species formation is promoted due to CH bond dissociation and NH bond formation, stable compounds with CN bonds are formed at temperatures ranged between 10 and 40 K. Many of these reaction products, resulting from CH4 + N reaction, have already been observed in N2-rich regions such as the atmospheres of Titan, Kuiper belt objects, and molecular clouds of the interstellar medium. Our results show the power of the solid state N-atom chemistry in the transformation of simple astrochemical relevant species, such as CH4 molecules and N atoms into complex organic molecules which are also potentially prebiotic species.

Mineral associations and character of isotopically anomalous organic material in the Tagish Lake carbonaceous chondrite

NASA Astrophysics Data System (ADS)

Zega, Thomas J.; Alexander, Conel M. O.'D.; Busemann, Henner; Nittler, Larry R.; Hoppe, Peter; Stroud, Rhonda M.; Young, Andrea F.

2010-10-01

We report a coordinated analytical study of matrix material in the Tagish Lake carbonaceous chondrite in which the same small (⩽20 μm) fragments were measured by secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), electron energy-loss spectroscopy (EELS), and X-ray absorption near-edge spectroscopy (XANES). SIMS analysis reveals H and N isotopic anomalies (hotspots), ranging from hundreds to thousands of nanometers in size, which are present throughout the fragments. Although the differences in spatial resolution of the SIMS techniques we have used introduce some uncertainty into the exact location of the hotspots, in general, the H and N isotopic anomalies are spatially correlated with C enrichments, suggesting an organic carrier. TEM analysis, enabled by site-specific extraction using a focused-ion-beam scanning-electron microscope, shows that the hotspots contain an amorphous component, Fe-Ni sulfides, serpentine, and mixed-cation carbonates. TEM imaging reveals that the amorphous component occurs in solid and porous forms, EDS indicates that it contains abundant C, and EELS and XANES at the C K edge reveal that it is largely aromatic. This amorphous component is probably macromolecular C, likely the carrier of the isotopic anomalies, and similar to the material extracted from bulk samples as insoluble organic matter. However, given the large sizes of some of the hotspots, the disparity in spatial resolution among the various techniques employed in our study, and the phases with which they are associated, we cannot entirely rule out that some of the isotopic anomalies are carried by inorganic material, e.g., sheet silicates. The isotopic composition of the organic matter points to an initially primitive origin, quite possibly within cold interstellar clouds or the outer reaches of the solar protoplanetary disk. The association of organic material with secondary phases, e.g., serpentine and carbonates, suggests that the organic matter was susceptible to parent-body processing, and thus, isotopic dilution.

Solid expellant plasma generator

NASA Technical Reports Server (NTRS)

Stone, Nobie H. (Inventor); Poe, Garrett D. (Inventor); Rood, Robert (Inventor)

2010-01-01

An improved solid expellant plasma generator has been developed. The plasma generator includes a support housing, an electrode rod located in the central portion of the housing, and a mass of solid expellant material that surrounds the electrode rod within the support housing. The electrode rod and the solid expellant material are made of separate materials that are selected so that the electrode and the solid expellant material decompose at the same rate when the plasma generator is ignited. This maintains a point of discharge of the plasma at the interface between the electrode and the solid expellant material.

Materials research for passive solar systems: Solid-state phase-change materials

NASA Astrophysics Data System (ADS)

Benson, D. K.; Webb, J. D.; Burrows, R. W.; McFadden, J. D. O.; Christensen, C.

1985-03-01

A set of solid-state phase-change materials is being evaluated for possible use in passive solar thermal energy storage systems. The most promising materials are organic solid solutions of pentaerythritol (C5H12O4), pentaglycerinve (C5H12O3), and neopentyl glycol (C5H12O2). Solid solution mixtures of these compounds can be tailored so that they exhibit solid-to-solid phase transformations at any desired temperature between 25 C and 188 C, and have latent heats of transformation etween 20 and 70 cal/g. Transformation temperatures, specific heats, and latent heats of transformation have been measured for a number of these materials. Limited cyclic experiments suggest that the solid solutions are stable. These phase-change materials exhibit large amounts of undercooling; however, the addition of certain nucleating agents as particulate dispersions in the solid phase-change material greatly reduces this effect. Computer simulations suggest that the use of an optimized solid-state phase-change material in a Trombe wall could provide better performance than a concrete Trombe wall four times thicker and nine times heavier.

Identifying Organic Molecules in Space: The AstroBiology Explorer (ABE) Mission Concept

NASA Technical Reports Server (NTRS)

Ennico, K. A.; Sandford, S. A.; Allamandola, L.; Bregman, J.; Cohen, M.; Cruikshank, D.; Dumas, C.; Greene, T.; Hudgins, D.; Kwok, S.

2004-01-01

The AstroBiology Explorer (ABE) mission concept consists of a dedicated space observatory having a 60 cm class primary mirror cooled to T < 50 K equipped with medium resolution cross-dispersed spectrometers having cooled large format near- and mid-infrared detector arrays. Such a system would be capable of addressing outstanding problems in Astrochemistry and Astrophysics that are particularly relevant to Astrobiology and addressable via astronomical observation. The mission s observational program would make fundamental scientific progress in establishing the nature, distribution, formation and evolution of organic and other molecular materials in the following extra-terrestrial environments: 1) The Outflow of Dying Stars, 2) The Diffuse Interstellar Medium, 3) Dense Molecular Clouds, Star Formation Regions, and Young StellarPlanetary Systems, 4) Planets, Satellites, and Small Bodies within the Solar System, and 5 ) The Interstellar Media of Other Galaxies. ABE could make fundamental progress in all of these areas by conducting a 1 to 2 year mission to obtain a coordinated set of infrared spectroscopic observations over the 2.5-20 micron spectral range at a spectral resolution of R > 2000 of about 1500 objects including galaxies, stars, planetary nebulae, young stellar objects, and solar system objects. Keywords: Astrobiology, infrared, Explorers, interstellar organics, telescope, spectrometer, space, infrared detectors

Interstellar scintillations of PSR B1919+21: space-ground interferometry

NASA Astrophysics Data System (ADS)

Shishov, V. I.; Smirnova, T. V.; Gwinn, C. R.; Andrianov, A. S.; Popov, M. V.; Rudnitskiy, A. G.; Soglasnov, V. A.

2017-07-01

We carried out observations of pulsar PSR B1919+21 at 324 MHz to study the distribution of interstellar plasma in the direction of this pulsar. We used the RadioAstron (RA) space radio telescope, together with two ground telescopes: Westerbork (WB) and Green Bank (GB). The maximum baseline projection for the space-ground interferometer was about 60 000 km. We show that interstellar scintillation of this pulsar consists of two components: diffractive scintillations from inhomogeneities in a layer of turbulent plasma at a distance z1 = 440 pc from the observer or homogeneously distributed scattering material to the pulsar; and weak scintillations from a screen located near the observer at z2 = 0.14 ± 0.05 pc. Furthermore, in the direction to the pulsar we detected a prism that deflects radiation, leading to a shift in observed source position. We show that the influence of the ionosphere can be ignored for the space-ground baseline. Analysis of the spatial coherence function for the space-ground baseline (RA-GB) yielded a scattering angle in the observer plane of θscat = 0.7 mas. An analysis of the time-frequency correlation function for weak scintillations yielded an angle of refraction in the direction to the pulsar θref, 0 = 110 ms and a distance to the prism zprism ≤ 2 pc.

Experimental interstellar organic chemistry - Preliminary findings

NASA Technical Reports Server (NTRS)

Khare, B. N.; Sagan, C.

1973-01-01

Review of the results of some explicit experimental simulation of interstellar organic chemistry consisting in low-temperature high-vacuum UV irradiation of condensed simple gases known or suspected to be present in the interstellar medium. The results include the finding that acetonitrile may be present in the interstellar medium. The implication of this and other findings are discussed.

Comets, carbonaceous chondrites, and interstellar clouds: Condensation of carbon

NASA Technical Reports Server (NTRS)

Field, G. B.

1979-01-01

Comets, carbonaceous chondrites, and interstellar clouds are discussed in relation to information on interstellar dust. The formation and presence of carbon in stars, comets, and meteorites is investigated. The existence of graphite in the interstellar medium, though it is predicted from thermodynamic calculations, is questioned and the form of carbon contained in comets is considered.

Laboratory experiments on interstellar ice analogs: The sticking and desorption of small physisorbed molecules

NASA Technical Reports Server (NTRS)

Fuchs, G. W.; Acharyya, K.; Bisschop, S. E.; Oberg, K. I.; vanBroekhuizen, F. A.; Fraser, H. J.; Schlemmer, S.; vanDishoeck, E. F.; Linnartz, H.

2006-01-01

Molecular oxygen and nitrogen are difficult to observe since they are infrared inactive and radio quiet. The low O2 abundances found so far combined with general considerations of dense cloud conditions suggest molecular oxygen is frozen out at low temperatures (< 20 K) in the shielded inner regions of cloud cores. In solid form O2 and N2 can only be observed as adjuncts within other ice constituents, like CO. In this work we focus on fundamental properties of N2 and O2 in CO ice-gas systems, e.g. desorption characteristics and sticking probabilities at low temperatures for different ice morphologies.

Thermal and energetic processing of astrophysical ice analogues rich in SO2

NASA Astrophysics Data System (ADS)

Kaňuchová, Z.; Boduch, Ph.; Domaracka, A.; Palumbo, M. E.; Rothard, H.; Strazzulla, G.

2017-08-01

Context. Sulfur is an abundant element in the cosmos and it is thus an important contributor to astrochemistry in the interstellar medium and in the solar system. Astronomical observations of the gas and of the solid phases in the dense interstellar/circumstellar regions have evidenced that sulfur is underabundant. The hypothesis to explain such a circumstance is that it is incorporated in some species in the solid phase (I.e. as frozen gases and/or refractory solids) and/or in the gas phase, which for different reasons have not been observed so far. Aims: Here we wish to give a contribution to the field by studying the chemistry induced by thermal and energetic processing of frozen mixtures of sulfur dioxide (one of the most abundant sulfur-bearing molecules observed so far) and water. Methods: We present the results of a series of laboratory experiments concerning thermal processing of different H2O:SO2 mixtures and ion bombardment (30 keV He+) of the same mixtures. We used in situ Fourier transform infrared (FTIR) spectroscopy to investigate the induced effects. Results: The results indicate that ionic species such as HSO, HSO, and S2O are easily produced. Energetic processing also produces SO3 polymers and a sulfurous refractory residue. Conclusions: The produced ionic species exhibit spectral features in a region that, in astronomical spectra of dense molecular clouds, is dominated by strong silicate absorption. However, such a dominant feature is associated with some spectral features, some of which have not yet been identified. We suggest adding the sulfur-bearing ionic species to the list of candidates to help explain some of those features. In addition, we suggest that once expelled in the gas phase by sublimation, due to the temperature increase, and/or by non-thermal erosion those species would constitute a class of molecular ions not detected so far. We also suggest that molecular sulfur-bearing ions could be present on the surfaces and/or in the atmospheres of several objects in the solar system, for example icy satellites of the giant planets and comets.

LDEF: 69 Months in Space. Second Post-Retrieval Symposium, part 2

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1993-01-01

This document is a compilation of papers presented at the Second Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium. The papers represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, micrometeoroid, etc.), electronics, optics, and life science.

LDEF: 69 Months in Space. First Post-Retrieval Symposium, part 3

NASA Technical Reports Server (NTRS)

Levine, Arlene S. (Editor)

1992-01-01

A compilation of papers presented at the First Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium is presented. The papers represent the preliminary data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science (cosmic ray, interstellar gas, heavy ions, and micrometeoroid), electronics, optics, and life sciences.

Process for coal liquefaction using electrodeposited catalyst

DOEpatents

Moore, Raymond H.

1978-01-01

A process for the liquefaction of solid hydrocarbonaceous materials is disclosed. Particles of such materials are electroplated with a metal catalyst and are then suspended in a hydrocarbon oil and subjected to hydrogenolysis to liquefy the solid hydrocarbonaceous material. A liquid product oil is separated from residue solid material containing char and the catalyst metal. The catalyst is recovered from the solid material by electrolysis for reuse. A portion of the product oil can be employed as the hydrocarbon oil for suspending additional particles of catalyst coated solid carbonaceous material for hydrogenolysis.

IRAS 08572+3915: constraining the aromatic versus aliphatic content of interstellar HACs

NASA Astrophysics Data System (ADS)

Dartois, E.; Geballe, T. R.; Pino, T.; Cao, A.-T.; Jones, A.; Deboffle, D.; Guerrini, V.; Bréchignac, Ph.; D'Hendecourt, L.

2007-02-01

We analyze dust features present in the mid-infrared (Spitzer) and recently published L-band (UKIRT) spectra of the infrared galaxy IRAS 08572+3915. The line of sight toward the AGN nucleus crosses a high column density of carbonaceous dust whose characteristic absorption features appear clearly. They provide a real insight into the chemical environment of the diffuse interstellar medium. Thanks to the moderate redshift of IRAS 08572+3915, the wavelength of the aromatic CH stretching mode is free of major telluric lines, and a strong observational constraint of Hsp2 /Hsp3 ≤ 0.08 has been determined. This limit clearly shows that the bonding of hydrogen atoms in interstellar hydrogenated amorphous carbon is highly aliphatic. The presence of a broad absorption feature centered at 6.2 μm, probably arising from olefinic/aromatic structures, corresponds to the backbone of this carbonaceous material, which is the major carbon-containing component of the interstellar medium along this line of sight. Based on observations made with the Spitzer Space Telescope (GO-3336 program), which is operated by the Jet Propulsion Laboratory, California Institute of Technology under NASA contract 1407. Based on data obtained at the United Kingdom Infrared Telescope, which is operated by the Joint Astronomy Center on behalf of the UK Particle Physics and Astronomy Research Council. Part of this work has been financed by the french CNRS program "Physique et Chimie du Milieu Interstellaire" (PCMI-CNRS). TRG's esearch is supported by the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., on behalf of the international Gemini partnership of Argentina, Australia, Brazil, Canada, Chile, the United Kingdom, and the United States of America.

Multiple generations of grain aggregation in different environments preceded solar system body formation.

PubMed

Ishii, Hope A; Bradley, John P; Bechtel, Hans A; Brownlee, Donald E; Bustillo, Karen C; Ciston, James; Cuzzi, Jeffrey N; Floss, Christine; Joswiak, David J

2018-06-26

The solar system formed from interstellar dust and gas in a molecular cloud. Astronomical observations show that typical interstellar dust consists of amorphous ( a -) silicate and organic carbon. Bona fide physical samples for laboratory studies would yield unprecedented insight about solar system formation, but they were largely destroyed. The most likely repositories of surviving presolar dust are the least altered extraterrestrial materials, interplanetary dust particles (IDPs) with probable cometary origins. Cometary IDPs contain abundant submicron a- silicate grains called GEMS (glass with embedded metal and sulfides), believed to be carbon-free. Some have detectable isotopically anomalous a- silicate components from other stars, proving they are preserved dust inherited from the interstellar medium. However, it is debated whether the majority of GEMS predate the solar system or formed in the solar nebula by condensation of high-temperature (>1,300 K) gas. Here, we map IDP compositions with single nanometer-scale resolution and find that GEMS contain organic carbon. Mapping reveals two generations of grain aggregation, the key process in growth from dust grains to planetesimals, mediated by carbon. GEMS grains, some with a- silicate subgrains mantled by organic carbon, comprise the earliest generation of aggregates. These aggregates (and other grains) are encapsulated in lower-density organic carbon matrix, indicating a second generation of aggregation. Since this organic carbon thermally decomposes above ∼450 K, GEMS cannot have accreted in the hot solar nebula, and formed, instead, in the cold presolar molecular cloud and/or outer protoplanetary disk. We suggest that GEMS are consistent with surviving interstellar dust, condensed in situ, and cycled through multiple molecular clouds. Copyright © 2018 the Author(s). Published by PNAS.

Status of Solar Sail Propulsion Within NASA - Moving Toward Interstellar Travel

NASA Technical Reports Server (NTRS)

Johnson, Les

2015-01-01

NASA is developing solar sail propulsion for two near-term missions and laying the groundwork for their future use in deep space and interstellar precursor missions. Solar sails use sunlight to propel vehicles through space by reflecting solar photons from a large, mirror-like sail made of a lightweight, highly reflective material. This continuous photon pressure provides propellantless thrust, allowing for very high (Delta)V maneuvers on long-duration, deep space exploration. Since reflected light produces thrust, solar sails require no onboard propellant. The Near Earth Asteroid (NEA) Scout mission, managed by MSFC, will use the sail as primary propulsion allowing it to survey and image one or more NEA's of interest for possible future human exploration. Lunar Flashlight, managed by JPL, will search for and map volatiles in permanently shadowed Lunar craters using a solar sail as a gigantic mirror to steer sunlight into the shaded craters. The Lunar Flashlight spacecraft will also use the propulsive solar sail to maneuver into a lunar polar orbit. Both missions use a 6U cubesat architecture, a common an 85 sq m solar sail, and will weigh less than 12 kilograms. Both missions will be launched on the first flight of the Space Launch System in 2018. NEA Scout and Lunar Flashlight will serve as important milestones in the development of solar sail propulsion technology for future, more ambitious missions including the Interstellar Probe - a mission long desired by the space science community which would send a robotic probe beyond the edge of the solar system to a distance of 250 Astronomical Units or more. This paper will summarize the development status of NEA Scout and Lunar Flashlight and describe the next steps required to enable an interstellar solar sail capability.

Photochemical Concepts on the Origin of Biomolecular Asymmetry

NASA Astrophysics Data System (ADS)

Meierhenrich, Uwe J.; Thiemann, Wolfram H.-P.

2004-02-01

Biopolymers like DNA and proteins are strongly selective towards the chirality of their monomer units. The use of homochiral monomers is regarded as essential for the construction and function of biopolymers; the emergence of the molecular asymmetry is therefore considered as a fundamental step in Chemical Evolution. This work focuses on physicochemical mechanisms for the origin of biomolecular asymmetry. Very recently two groups, one from Allamandola at NASA Ames and the other from our Inter-European team, demonstrated simultaneously the spontaneous photoformation of a variety of chiral amino acid structures under simulated interstellar conditions. Since both groups used unpolarized light for the photoreaction the obtained amino acids turned out racemic as expected. The obtained experimental data support the assumption that tiny ice grains can furthermore play host to important asymmetric reactions when irradiated by interstellar circularly polarized ultraviolet light. It is possible that such ice grains could have become incorporated into the early cloud that formed our Solar System and ended up on Earth, assisting life to start. Several lines of evidence suggest that some of the building blocks of life were delivered to the primitive Earth via (micro-) meteoroids and/or comets. These results suggest that asymmetric interstellar photochemistry may have played a significant part in supplying Earth with some of the enantioenriched organic materials needed to trigger life. The search for the origin of biomolecular homochirality leads to a strong interest in the fields of asymmetric photochemistry with special emphasis on absolute asymmetric synthesis. We outline here the theoretical background on asymmetric interstellar ice photochemistry, summarize recent concepts and advances in the field, and discuss briefly its implications. The obtained data are crucial for the design of the enantioselective COSAC GC-MS experiment onboard the ROSETTA spacecraft to a comet to be launched in the very near future.

Organic Compounds Produced by Photolysis of Realistic Interstellar and Cometary Ice Analogs Containing Methanol

NASA Astrophysics Data System (ADS)

Bernstein, Max P.; Sandford, Scott A.; Allamandola, Louis J.; Chang, Sherwood; Scharberg, Maureen A.

1995-11-01

The infrared (IR) spectra of ultraviolet (UV) and thermally processed, methanol-containing interstellar/ cometary ice analogs at temperatures from 12 to 300 K are presented. Infrared spectroscopy, 1H and 13C nuclear magnetic resonance (NMR) spectroscopy, and gas chromatography-mass spectrometry indicate that CO (carbon monoxide), CO2 (carbon dioxide), CH4 (methane), HCO (the formyl radical), H2CO (formaldehyde), CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), and R-C=-N (nitriles) are formed. In addition, the organic materials remaining after photolyzed ice analogs have been warmed to room temperature contain (in rough order of decreasing abundance), (1) hexamethylenetetramine (HMT, C6H12N4), (2) ethers, alcohols, and compounds related to polyoxymethylene {POM, ( CH2O )n}, and (3) ketones {R-C(=O)-R'} and amides {H2NC(=O)-R}. Most of the carbon in these residues is thought to come from the methanol in the original ice. Deuterium and 13C isotopic labeling demonstrates that methanol is definitely the source of carbon in HMT. High concentrations of HMT in interstellar and cometary ices could have important astrophysical consequences. The ultraviolet photolysis of HMT frozen in H2O ice readily produces the "XCN" band observed in the spectra of protostellar objects and laboratory ices, as well as other nitriles. Thus, HMT may be a precursor of XCN and a source of CN in comets and the interstellar medium. Also, HMT is known to hydrolyze under acidic conditions to yield ammonia, formaldehyde, and amino acids. Thus, HMT may be a significant source of prebiogenic compounds on asteroidal parent bodies. A potential mechanism for the radiative formation of HMT in cosmic ices is outlined.

A conceptual design for cosmo-biology experiments in Earth's Orbit.

PubMed

Hashimoto, H; Greenberg, M; Brack, A; Colangeli, L; Horneck, G; Navarro-Gonzalez, R; Raulin, F; Kouchi, A; Saito, T; Yamashita, M; Kobayashi, K

1998-06-01

A conceptual design was developed for a cosmo-biology experiment. It is intended to expose simulated interstellar ice materials deposited on dust grains to the space environment. The experimental system consists of a cryogenic system to keep solidified gas sample, and an optical device to select and amplify the ultraviolet part of the solar light for irradiation. By this approach, the long lasting chemical evolution of icy species could be examined in a much shorter time of exposure by amplification of light intensity. The removal of light at longer wavelength, which is ineffective to induce photochemical reactions, reduces the heat load to the cryogenic system that holds solidified reactants including CO as a constituent species of interstellar materials. Other major hardware components were also defined in order to achieve the scientific objectives of this experiment. Those are a cold trap maintained at liquid nitrogen temperature to prevent the contamination of the sample during the exposure, a mechanism to exchange multiple samples, and a system to perform bake-out of the sample exposure chamber. This experiment system is proposed as a candidate payload implemented on the exposed facility of Japanese Experiment Module on International Space Station.

The evolution of organic matter in space.

PubMed

Ehrenfreund, Pascale; Spaans, Marco; Holm, Nils G

2011-02-13

Carbon, and molecules made from it, have already been observed in the early Universe. During cosmic time, many galaxies undergo intense periods of star formation, during which heavy elements like carbon, oxygen, nitrogen, silicon and iron are produced. Also, many complex molecules, from carbon monoxide to polycyclic aromatic hydrocarbons, are detected in these systems, like they are for our own Galaxy. Interstellar molecular clouds and circumstellar envelopes are factories of complex molecular synthesis. A surprisingly high number of molecules that are used in contemporary biochemistry on the Earth are found in the interstellar medium, planetary atmospheres and surfaces, comets, asteroids and meteorites and interplanetary dust particles. Large quantities of extra-terrestrial material were delivered via comets and asteroids to young planetary surfaces during the heavy bombardment phase. Monitoring the formation and evolution of organic matter in space is crucial in order to determine the prebiotic reservoirs available to the early Earth. It is equally important to reveal abiotic routes to prebiotic molecules in the Earth environments. Materials from both carbon sources (extra-terrestrial and endogenous) may have contributed to biochemical pathways on the Earth leading to life's origin. The research avenues discussed also guide us to extend our knowledge to other habitable worlds.

Evaluation of the Strecker synthesis as a source of amino acids on carbonaceous chondrites

NASA Technical Reports Server (NTRS)

Lerner, N. R.; Peterson, Etta; Chang, S.

1991-01-01

The Strecker synthesis (SS) has been proposed as the source of amino acids (AA) formed during aqueous alteration of carbonaceous chondrites. It is postulated that the aldehyde and ketone precursors of the meteoritic AA originated in interstellar syntheses and accreted on the meteorite parent body along with other reactant species in cometesimal ices. The SS has been run with formaldehyde, acetyldehyde, propionaldehyde, acetone, and methyl ketone as starting materials. To study the effect of minerals on the reaction, the SS was run in the presence and absence of dust from the Allende meteorite using deuterated aldehydes and ketones as starting materials. The products were studied by GC/MS. With the exception of glycine, the retention of deuterium in the AA was greater than 90 pct. Some D exchange with water does occur, however, and determination of the rate of exchange as a function of pH and temperature may allow some bounds to be placed on the duration of parent body aqueous alteration. The retention of D by the AA under conditions studied thus far is consistent with the model that a SS starting from interstellar aldehydes and ketones led to the production of meteoritic AA.

Direct Observations of Interstellar H, He, and O by the Interstellar Boundary Explorer (Invited)

NASA Astrophysics Data System (ADS)

Moebius, E.; Bochsler, P. A.; Bzowski, M.; Crew, G. B.; Funsten, H. O.; Fuselier, S. A.; Ghielmetti, A.; Heirtzler, D.; Izmodenov, V.; Kubiak, M.; Kucharek, H.; Lee, M. A.; Leonard, T.; McComas, D. J.; Petersen, L.; Saul, L. A.; Scheer, J.; Schwadron, N. A.; Witte, M.; Wurz, P.

2009-12-01

Due to the motion of the Sun relative to its neighborhood, the neutral gas of the local in-terstellar medium (LISM) flows through the inner heliosphere where it is subject to ioni-zation, the Sun’s gravity, and radiation pressure. Observing the resulting spatial distribu-tion and flow pattern of several interstellar gas species with UV backscatter, pickup ion, and neutral atom imaging techniques allows us to unravel the physical conditions of the LISM and its interaction with the heliosphere. Imaging of the neutral gas flow directly with energetic neutral atom (ENA) cameras yields the most accurate account of the ki-netic parameters of the interstellar gas, but so far this has been carried out only for He using Ulysses GAS. IBEX, which was launched in October 2008, provides the capability for simultaneous flow observations of several interstellar species with its triple-time-of-flight IBEX-Lo sensor. Because H and O are strongly affected by the heliospheric inter-face while He is not, a direct comparison between these species enables an independent assessment of the slowdown and heating processes in the outer heliosheath. Likewise, IBEX observations will constrain models of the heliospheric interaction and provide a test of the heliospheric asymmetry - recently inferred from Voyager and SOHO SWAN observations - that is seen as an indicator for the interstellar magnetic field direction. During the first half year of its mission IBEX has observed the interstellar He, O, and H flow. We will present an overview and preliminary analysis of these first interstellar mul-tispecies scans of the interstellar gas flow in spring and fall 2009.

Aliphatic Hydrocarbon Content of Interstellar Dust

NASA Astrophysics Data System (ADS)

Günay, B.; Schmidt, T. W.; Burton, M. G.; Afşar, M.; Krechkivska, O.; Nauta, K.; Kable, S. H.; Rawal, A.

2018-06-01

There is considerable uncertainty as to the amount of carbon incorporated in interstellar dust. The aliphatic component of the carbonaceous dust is of particular interest because it produces a significant 3.4 μm absorption feature when viewed against a background radiation source. The optical depth of the 3.4 μm absorption feature is related to the number of aliphatic carbon C-H bonds along the line of sight. It is possible to estimate the column density of carbon locked up in the aliphatic hydrocarbon component of interstellar dust from quantitative analysis of the 3.4 μm interstellar absorption feature providing that the absorption coefficient of aliphatic hydrocarbons incorporated in the interstellar dust is known. We report laboratory analogues of interstellar dust by experimentally mimicking interstellar/circumstellar conditions. The resultant spectra of these dust analogues closely match those from astronomical observations. Measurements of the absorption coefficient of aliphatic hydrocarbons incorporated in the analogues were carried out by a procedure combining FTIR and 13C NMR spectroscopies. The absorption coefficients obtained for both interstellar analogues were found to be in close agreement (4.76(8) × 10-18 cm group-1 and 4.69(14) × 10-18 cm group-1), less than half those obtained in studies using small aliphatic molecules. The results thus obtained permit direct calibration of the astronomical observations, providing rigorous estimates of the amount of aliphatic carbon in the interstellar medium.

Hubble views a spectacular supernova with interstellar material over 160,000 light-years away

NASA Image and Video Library

2017-12-08

This NASA/ESA Hubble Space Telescope image captures the remnants of a long-dead star. These rippling wisps of ionized gas, named DEM L316A, are located some 160,000 light-years away within one of the Milky Way’s closest galactic neighbors — the Large Magellanic Cloud (LMC). The explosion that formed DEM L316A was an example of an especially energetic and bright variety of supernova, known as a Type Ia. Such supernova events are thought to occur when a white dwarf star steals more material than it can handle from a nearby companion, and becomes unbalanced. The result is a spectacular release of energy in the form of a bright, violent explosion, which ejects the star’s outer layers into the surrounding space at immense speeds. As this expelled gas travels through the interstellar material, it heats up and ionizes it, producing the faint glow that Hubble’s Wide Field Camera 3 has captured here. The LMC orbits the Milky Way as a satellite galaxy and is the fourth largest in our group of galaxies, the Local Group. DEM L316A is not the only supernova remnant in the LMC; Hubble came across another one in 2010 with SNR 0509, and in 2013 it snapped SNR 0519. Image credit: ESA (European Space Agency)/Hubble & NASA, Y. Chu

Kramers-Kronig relations for interstellar polarization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, P.G.

1975-12-01

The difficulties encountered in using the Kramers-Kronig relations to predict the behavior of interstellar polarization are pointed out, while at the same time their value in an interpretive role is acknowledged. Observations of interstellar circular polarization lead to restrictions on the interstellar grain composition, and additional constraints should be possible through measurement of linear polarization in the infrared and the ultraviolet. (AIP)

Gas Phase Spectroscopy of Cold PAH Ions: Contribution to the Interstellar Extinction and the Diffuse Interstellar Bands

NASA Technical Reports Server (NTRS)

Biennier, L.; Salama, F.; Allamandola, L. J.; Scherer, J. J.; OKeefe, A.

2002-01-01

Polycyclic Aromatic Hydrocarbon molecules (PAHs) are ubiquitous in the interstellar medium (ISM) and constitute the building blocks of interstellar dust grains. Despite their inferred important role in mediating the energetic and chemical processes in thc ISM, their exact contribution to the interstellar extinction, and in particular to the diffuse interstellar bands (DIBs) remains unclear. The DIBs are spectral absorption features observed in the line of sight of stars that are obscured by diffuse interstellar clouds. More than 200 bands have been reported to date spanning from the near UV to the near IR with bandwidths ranging from 0.4 to 40 Angstroms (Tielens & Snow 1995). The present consensus is that the DIBs arise from free flying, gas-phase, organic molecules and/or ions that are abundant under the typical conditions reigning in the diffuse ISM. PAHs have been proposed as possible carriers (Allamandola et al. 1985; Leger & DHendecourt 1985). The PAH hypothesis is consistent with the cosmic abundance of Carbon and Hydrogen and with the required photostability of the DIB carriers against the strong VUV radiation field in the diffuse interstellar clouds. A significant fraction of PAHs is expected to be ionized in the diffuse ISM.

The ESO Diffuse Interstellar Band Large Exploration Survey (EDIBLES)

NASA Astrophysics Data System (ADS)

Cami, J.; Cox, N. L.; Farhang, A.; Smoker, J.; Elyajouri, M.; Lallement, R.; Bacalla, X.; Bhatt, N. H.; Bron, E.; Cordiner, M. A.; de Koter, A..; Ehrenfreund, P.; Evans, C.; Foing, B. H.; Javadi, A.; Joblin, C.; Kaper, L.; Khosroshahi, H. G.; Laverick, M.; Le Petit, F..; Linnartz, H.; Marshall, C. C.; Monreal-Ibero, A.; Mulas, G.; Roueff, E.; Royer, P.; Salama, F.; Sarre, P. J.; Smith, K. T.; Spaans, M.; van Loon, J. T..; Wade, G.

2018-03-01

The ESO Diffuse Interstellar Band Large Exploration Survey (EDIBLES) is a Large Programme that is collecting high-signal-to-noise (S/N) spectra with UVES of a large sample of O and B-type stars covering a large spectral range. The goal of the programme is to extract a unique sample of high-quality interstellar spectra from these data, representing different physical and chemical environments, and to characterise these environments in great detail. An important component of interstellar spectra is the diffuse interstellar bands (DIBs), a set of hundreds of unidentified interstellar absorption lines. With the detailed line-of-sight information and the high-quality spectra, EDIBLES will derive strong constraints on the potential DIB carrier molecules. EDIBLES will thus guide the laboratory experiments necessary to identify these interstellar “mystery molecules”, and turn DIBs into powerful diagnostics of their environments in our Milky Way Galaxy and beyond. We present some preliminary results showing the unique capabilities of the EDIBLES programme.

Raman Spectrum of Quenched Carbonaceous Composites

NASA Technical Reports Server (NTRS)

Wada, S.; Hayashi, S.; Miyaoka, H.; Tokunaga, A. T.

1996-01-01

Quenched Carbonaceous Composites (QCC's) are products from the ejecta of a hydrocarbon plasma. Two types of QCC, dark QCC and thermally-altered (heated) filmy QCC, have been shown to have a 220 nm absorption feature similar to that seen in the interstellar extinction curve. We present here Raman spectra of the QCCs and compare them with various carbonaceous materials to better understand the structure QCC. We find that structure of QCC is different from that of graphite and more similar to carbonaceous material found in some interplanetary dust particles and chondritic meteorites.

Stardust Interstellar Preliminary Examination II: Curating the Interstellar Dust Collector, Picokeystones, and Sources of Impact Tracks

NASA Technical Reports Server (NTRS)

Frank, David R.; Westphal, Andrew J.; Zolensky, Michael E.; Gainsforth, Zack; Butterworth, Anna L.; Bastien, Ronald K.; Allen, Carlton; Anderson, David; Bechtel, Hans A.; Sandford, Scott A.

2013-01-01

We discuss the inherent difficulties that arise during "ground truth" characterization of the Stardust interstellar dust collector. The challenge of identifying contemporary interstellar dust impact tracks in aerogel is described within the context of background spacecraft secondaries and possible interplanetary dust particles and beta-meteoroids. In addition, the extraction of microscopic dust embedded in aerogel is technically challenging. Specifically, we provide a detailed description of the sample preparation techniques developed to address the unique goals and restrictions of the Interstellar Preliminary Exam. These sample preparation requirements and the scarcity of candidate interstellar impact tracks exacerbate the difficulties. We also illustrate the role of initial optical imaging with critically important examples, and summarize the overall processing of the collection to date.

Thermodynamics and Charging of Interstellar Iron Nanoparticles

NASA Astrophysics Data System (ADS)

Hensley, Brandon S.; Draine, B. T.

2017-01-01

Interstellar iron in the form of metallic iron nanoparticles may constitute a component of the interstellar dust. We compute the stability of iron nanoparticles to sublimation in the interstellar radiation field, finding that iron clusters can persist down to a radius of ≃4.5 Å, and perhaps smaller. We employ laboratory data on small iron clusters to compute the photoelectric yields as a function of grain size and the resulting grain charge distribution in various interstellar environments, finding that iron nanoparticles can acquire negative charges, particularly in regions with high gas temperatures and ionization fractions. If ≳10% of the interstellar iron is in the form of ultrasmall iron clusters, the photoelectric heating rate from dust may be increased by up to tens of percent relative to dust models with only carbonaceous and silicate grains.

Is High Primordial Deuterium Consistent with Galactic Evolution?

NASA Astrophysics Data System (ADS)

Tosi, Monica; Steigman, Gary; Matteucci, Francesca; Chiappini, Cristina

1998-05-01

Galactic destruction of primordial deuterium is inevitably linked through star formation to the chemical evolution of the Galaxy. The relatively high present gas content and low metallicity suggest only modest D destruction. In concert with deuterium abundances derived from solar system and/or interstellar observations, this suggests a primordial deuterium abundance in possible conflict with data from some high-redshift, low-metallicity QSO absorbers. We have explored a variety of chemical evolution models including infall of processed material and early, supernovae-driven winds with the aim of identifying models with large D destruction that are consistent with the observations of stellar-produced heavy elements. When such models are confronted with data, we reconfirm that only modest destruction of deuterium (less than a factor of 3) is permitted. When combined with solar system and interstellar data, these results favor the low deuterium abundances derived for the QSO absorbers by Tytler et al.

Probing the chemical environments of early star formation: A multidisciplinary approach

NASA Astrophysics Data System (ADS)

Hardegree-Ullman, Emily Elizabeth

Chemical compositions of prestellar and protostellar environments in the dense interstellar medium are best quantified using a multidisciplinary approach. For my dissertation, I completed two projects to measure molecular abundances during the earliest phases of star formation. The first project investigates gas phase CO depletion in molecular cloud cores, the progenitors of star systems, using infrared photometry and molecular line spectroscopy at radio wavelengths. Hydrogenation of CO depleted onto dust is an important first step toward building complex organic molecules. The second project constrains polycyclic aromatic hydrocarbon (PAH) abundances toward young stellar objects (YSO). Band strengths measured from laboratory spectroscopy of pyrene/water ice mixtures were applied to estimate abundances from features attributed to PAHs in observational YSO spectra. PAHs represent a distinct but important component of interstellar organic material that is widely observed but not well quantified in star-forming regions.

The formation of stellar systems from interstellar molecular clouds.

PubMed

Gehrz, R D; Black, D C; Solomon, P M

1984-05-25

Star formation, a crucial link in the chain of events that led from the early expansion of the universe to the formation of the solar system, continues to play a major role in the evolution of many galaxies. Observational and theoretical studies of regions of ongoing star formation provide insight into the physical conditions and events that must have attended the formation of the solar system. Such investigations also elucidate the role played by star formation in the evolutionary cycle which appears to dominate the chemical processing of interstellar material by successive generations of stars in spiral galaxies like our own. New astronomical facilities planned for development during the 1980's could lead to significant advances in our understanding of the star formation process. Efforts to identify and examine both the elusive protostellar collapse phase of star formation and planetary systems around nearby stars will be especially significant.

Desorption from interstellar grains

NASA Technical Reports Server (NTRS)

Leger, A.; Jura, M.; Omont, A.

1985-01-01

Different desorption mechanisms from interstellar grains are considered to resolve the conflict between the observed presence of gaseous species in molecular clouds and their expected depletion onto grains. The physics of desorption is discussed with particular reference to the process of grain heating and the specific heat of the dust material. Impulsive heating by X-rays and cosmic rays is addressed. Spot heating of the grains by cosmic rays and how this can lead to desorption of mantles from very large grains is considered. It is concluded that CO depletion on grains will be small in regions with A(V) less than five from the cloud surface and n(H) less than 10,000, in agreement with observations and in contrast to expectations from pure thermal equilibrium. Even in very dense and obscured regions and in the absence of internal ultraviolet sources, the classical evaporation of CO or N2 and O2-rich mantles by cosmic rays is important.

Oxygen, Neon, and Iron X-Ray Absorption in the Local Interstellar Medium

NASA Technical Reports Server (NTRS)

Gatuzz, Efrain; Garcia, Javier; Kallman, Timothy R.; Mendoza, Claudio

2016-01-01

We present a detailed study of X-ray absorption in the local interstellar medium by analyzing the X-ray spectra of 24 galactic sources obtained with the Chandra High Energy Transmission Grating Spectrometer and the XMM-Newton Reflection Grating Spectrometer. Methods. By modeling the continuum with a simple broken power-law and by implementing the new ISMabs X-ray absorption model, we have estimated the total H, O, Ne, and Fe column densities towards the observed sources. Results. We have determined the absorbing material distribution as a function of source distance and galactic latitude longitude. Conclusions. Direct estimates of the fractions of neutrally, singly, and doubly ionized species of O, Ne, and Fe reveal the dominance of the cold component, thus indicating an overall low degree of ionization. Our results are expected to be sensitive to the model used to describe the continuum in all sources.

KSC-99pc0120

NASA Image and Video Library

1999-01-27

In the Payload Hazardous Servicing Facility, the Stardust spacecraft waits to be encased in a protective canister for its move to Launch Pad 17-A, Cape Canaveral Air Station, for launch preparations. Stardust is targeted for liftoff on Feb. 6 aboard a Boeing Delta II rocket for a close encounter with the comet Wild 2 in January 2004. Using a silicon-based substance called aerogel, Stardust will capture comet particles flying off the nucleus of the comet. The spacecraft also will bring back samples of interstellar dust. These materials consist of ancient pre-solar interstellar grains and other remnants left over from the formation of the solar system. Scientists expect their analysis to provide important insights into the evolution of the sun and planets and possibly into the origin of life itself. The collected samples will return to Earth in a sample return capsule to be jettisoned as Stardust swings by Earth in January 2006

High-resolution spectra of the 3.29 micron interstellar emission feature - A summary

NASA Technical Reports Server (NTRS)

Tokunaga, A. T.; Sellgren, K.; Smith, R. G.; Nagata, T.; Sakata, A.; Nakada, Y.

1991-01-01

High spectral resolution observations of the 3.29-micron interstellar emission feature show two types of profiles. Type 1 has a central wavelength of 3.289-micron and is observed in extended objects such as planetary nebulae and H II regions. Type 2 has a central wavelength of 3.296 microns and is observed around a small number of stellar sources. Type 2 has a full width at half-maximum of 0.020 micron; Type 1 has a broader FWHM, perhaps as much as 0.042 micron, but this is uncertain because of contamination by Pf(delta) emission. These profiles are tabulated for comparison to laboratory data. It is found that no proposed identification for the 3.29-micron emission feature definitely matches the observational spectra, although amorphous aromatic materials and heated polycyclic aromatic hydrocarbons tend to fit the best.

Small scale H I structure and the soft X-ray background

NASA Technical Reports Server (NTRS)

Jahoda, K.; Mccammon, D.; Lockman, F. J.

1986-01-01

The observed anticorrelation between diffuse soft X-ray flux and H I column density has been explained as absorption of soft X-rays produced in a hot galactic halo, assuming that the neutral interstellar material is sufficiently clumped to reduce the soft X-ray absorption cross section by a factor of two to three. A 21 cm emission line study of H I column density variations at intermediate and high galactic latitudes to 10' spatial resolution has been done. The results confirm conclusions from preliminary work at coarser resolution, and in combination with other data appear to rule out the hypothesis that clumping of neutral interstellar matter on any angular scale significantly reduces X-ray absorption cross sections in the 0.13 - 0.28 keV energy range. It is concluded therefore that the observed anticorrelation is not primarily a consequence of absorption of soft X-rays produced in a hot galactic halo.

Low Energy Electrons as Probing Tool for Astrochemical Reaction Mechanisms

NASA Astrophysics Data System (ADS)

Hendrik Bredehöft, Jan; Swiderek, Petra; Hamann, Thorben

The complexity of molecules found in space varies widely. On one end of the scale of molecular complexity is the hydrogen molecule H2 . Its formation from H atoms is if not understood than at least thoroughly investigated[1]. On the other side of said spectrum the precursors to biopolymers can be found, such as amino acids[2,3], sugars[4], lipids, cofactors[5], etc, and the kerogen-like organic polymer material in carbonaceous meteorites called "black stuff" [6]. These have also received broad attention in the last decades. Sitting in the middle between these two extremes are simple molecules that are observed by radio astronomy throughout the Universe. These are molecules like methane (CH4 ), methanol (CH3 OH), formaldehyde (CH2 O), hydrogen cyanide (HCN), and many many others. So far more than 40 such species have been identified.[7] They are often used in laboratory experiments to create larger complex molecules on the surface of simulated interstellar dust grains.[2,8] The mechanisms of formation of these observed starting materials for prebiotic chemistry is however not always clear. Also the exact mechanisms of formation of larger molecules in photochemical experiments are largely unclear. This is mostly due to the very complex chemistry going on which involves many different radicals and ions. The creation of radicals and ions can be studied in detail in laboratory simulations. They can be created in a setup mimicking interstellar grain chemistry using slow electrons. There is no free electron radiation in space. What can be found though is a lot of radiation of different sorts. There is electromagnetic radiation (UV light, X-Rays, rays, etc.) and there is particulate radiation as well in the form of high energy ions. This radiation can provide energy that drives chemical reactions in the ice mantles of interstellar dust grains. And while the multitude of different kinds of radiation might be a little confusing, they all have one thing in common: Upon hitting anything solid, they will create secondary electrons. These electrons are in fact the energy source needed to run interstellar chemistry. Slow electrons can in principle trigger three different primary processes in a molecule. The first is ionisation by electron impact (EI), which is used to create ions in mass spectrometry. In this process an electron hits a molecule M and knocks an outer shell electron to create a cation. This occurs whenever the electron energy is above the ionisation threshold of the target molecule. Another possibility is the attachment of a slow electron to a molecule to create an anion. This can occur at sharply defined resonance energies specific to the molecule M. A third possibility is to excite the molecule M to a neutral state M∗ .[9] M + e- -> M+ + 2 e- (Electron impact ionisation) M + e- -> M- (Electron attachment) M + e- -> M∗ + e- (Neutral excitation) The created states M+ , M- and M∗ are usually not stable states so they very often dissociate into ions and radicals, which can then further react with neighbouring molecules to form new chemical species. In these chemical reactions some products can be formed even at very low temperatures that would otherwise require a lot of thermal energy and/or special catalysts. The formation of ethylamine from ethylene and ammonia by hydroamination is one such example. The reaction is characterized by a high activation barrier caused by the electronic repulsion between the electron density rich C=C double bound and the lone pair electrons of ammo-nia. The reaction also has a highly negative entropy, so it becomes less favourable at higher temperatures, ruling out heat as a means to facilitate the reaction. In classical chemistry this problem is overcome by the use of catalysts. Unfortunately there still is no general catalyst for this kind of reaction. Recently it was shown that the reaction can efficiently be induced by low energy electron radiation.[10] One of the reaction partners is ionized and the reaction barrier is drastically lowered so that instant reaction between ethylene and ammonia occurs. This hydroamination reaction by means of low energy electrons or an analogous reaction mechanism could also help in clarifying the formation of the intermediate molecules observed in interstellar dust clouds. The formation for example of formamide from CO and NH3 could be facilitated by a very similar process. Formamide is a very interesting molecule in Astrochemistry as well as Astrobiology, since it is the smallest molecule with a peptide bond, the kind of bond that forms proteins from amino acids. Such ionisation-driven reactions leading to the formation of larger molecules appear to be more generally relevant than previously thought as will be discussed in this contribution. [1] Cazaux S., Caselli P., Tielens A.G.G.M., Le Bourlot J., Walmsley M: Molecular Hydrogen formation on grain surfaces. J of Phys. Conf. Series 6 (2005), 155-160 [2] Muñoz Caro G.M., Meierhenrich U.J., Schutte U.W., Barbier B., Arcones Segovia A., Rosen-n bauer H., Thiemann W.H.-P., Brack A. and Greenberg J.M.: Amino acids from ultraviolet irradiation of interstellar ice analogues. Nature 416 (2002), 403-406 [3] Bredehüft, J.H., Meierhenrich U.: Amino acid structures from UV irradiation of simulated interstellar ices. in Takenaka N. (ed): Recent Developments of Chemistry and Photochemistry in Ice. Transworld Research Network, Kerala, India (2008) [4] Cooper G., Kimmich N., Belisle W., Sarinana J., Brabham K. and Garrel L.: Carbonaceous meteorites as a source of sugar-related organic compounds for the early Earth. Nature 414 (2001), 879-883 [5] Meierhenrich U.J., Muñoz Caro G.M., Schutte W.A., Thiemann W.H.-P. Barbier B., Brack n A.: Precursors of biological cofactors from ultraviolet irradiation of circumstellar/interstellar ice analogs. Chemistry -A European Journal 11 (2005), 4895-4900 [6] Matthews C.N. and Minard R.D.: Hydrogen cyanide polymers, comets and the origin of life. Faraday Discuss., 133 (2006), 393-401 [7] Snow T.P. and Bierbaum V.M.: Ion chemistry in the interstellar medium. Ann. Rev. Analyt. Chem. 1 (2008), 229-259. [8] Nuevo M., Meierhenrich U.J., Muñoz Caro G.M., Dartois E., d'Hendecourt L., Deboffle D., n Auger G., Blanot D., Bredehüft J.H. and Nahon L.: The effects of circularly polarized light on amino acid enantiomers produced by the UV irradiation of interstellar ice analogs. AA 457 (2006), 741-751 [9] Shimamura I and Takayanagi K. (eds): Electron-Molecule Collisions. Plenum Press, New York, USA (1984) [10] Hamann T., Bühler E., Swiderek P.: Low-energy-electron-induced hydroamination of an alkene. Angew Chem Int Ed Engl. 48(25) (2009), 4643-4645.

Solid-phase materials for chelating metal ions and methods of making and using same

DOEpatents

Harrup, Mason K.; Wey, John E.; Peterson, Eric S.

2003-06-10

A solid material for recovering metal ions from aqueous streams, and methods of making and using the solid material, are disclosed. The solid material is made by covalently bonding a chelating agent to a silica-based solid, or in-situ condensing ceramic precursors along with the chelating agent to accomplish the covalent bonding. The chelating agent preferably comprises a oxime type chelating head, preferably a salicylaldoxime-type molecule, with an organic tail covalently bonded to the head. The hydrocarbon tail includes a carbon-carbon double bond, which is instrumental in the step of covalently bonding the tail to the silica-based solid or the in-situ condensation. The invented solid material may be contacted directly with aqueous streams containing metal ions, and is selective to ions such as copper (II) even in the presence of such ions as iron (III) and other materials that are present in earthen materials. The solid material with high selectivity to copper may be used to recover copper from mining and plating industry streams, to replace the costly and toxic solvent extraction steps of conventional copper processing.

Interstellar Probe: First Step to the Stars

NASA Astrophysics Data System (ADS)

McNutt, R. L., Jr.

2017-12-01

The idea of an "Interstellar Probe," a robotic spacecraft traveling into the nearby interstellar medium for the purpose of scientific investigation, dates to the mid-1960s. The Voyager Interstellar Mission (VIM), an "accidental" 40-year-old by-product of the Grand Tour of the solar system, has provided initial answers to the problem of the global heliospheric configuration and the details of its interface with interstellar space. But the twin Voyager spacecraft have, at most, only another decade of lifetime, and only Voyager 1 has emerged from the heliosheath interaction region. To understand the nature of the interaction, a near-term mission to the "near-by" interstellar medium with modern and focused instrumentation remains a compelling priority. Imaging of energetic neutral atoms (ENAs) by the Ion Neutral CAmera (INCA) on Cassini and from the Interstellar Boundary Explorer (IBEX) in Earth orbit have provided significant new insights into the global interaction region but point to discrepancies with our current understanding. Exploring "as far as possible" into "pristine" interstellar space can resolve these. Hence, reaching large heliocentric distances rapidly is a driver for an Interstellar Probe. Such a mission is timely; understanding the interstellar context of exoplanet systems - and perhaps the context for the emergence of life both here and there - hinges upon what we can discover within our own stellar neighborhood. With current spacecraft technology and high-capability launch vehicles, such as the Space Launch System (SLS), a small, but extremely capable spacecraft, could be dispatched to the near-by interstellar medium with at least twice the speed of the Voyagers. Challenges remain with payload mass and power constraints for optimized science measurements. Mission longevity, as experienced by, but not designed into, the Voyagers, communications capability, and radioisotope power system performance and lifetime are solvable engineering challenges. Such a robotic craft can be built, and could be built and launched soon - to enable our first deliberate step to the stars.

Laboratory Spectroscopy of Large Carbon Molecules and Ions in Support of Space Missions. A New Generation of Laboratory & Space Studies

NASA Technical Reports Server (NTRS)

Salama, Farid; Tan, Xiaofeng; Cami, Jan; Biennier, Ludovic; Remy, Jerome

2006-01-01

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. A long-standing and major challenge for laboratory astrophysics has been to measure the spectra of large carbon molecules in laboratory environments that mimic (in a realistic way) the physical conditions that are associated with the interstellar emission and absorption regions [1]. This objective has been identified as one of the critical Laboratory Astrophysics objectives to optimize the data return from space missions [2]. An extensive laboratory program has been developed to assess the properties of PAHs in such environments and to describe how they influence the radiation and energy balance in space. We present and discuss the gas-phase electronic absorption spectra of neutral and ionized PAHs measured in the UV-Visible-NIR range in astrophysically relevant environments and discuss the implications for astrophysics [1]. The harsh physical conditions of the interstellar medium characterized by a low temperature, an absence of collisions and strong VUV radiation fields - have been simulated in the laboratory by associating a pulsed cavity ringdown spectrometer (CRDS) with a supersonic slit jet seeded with PAHs and an ionizing, penning-type, electronic discharge. We have measured for the {\\it first time} the spectra of a series of neutral [3,4] and ionized [5,6] interstellar PAHs analogs in the laboratory. An effort has also been attempted to quantify the mechanisms of ion and carbon nanoparticles production in the free jet expansion and to model our simulation of the diffuse interstellar medium in the laboratory [7]. These experiments provide {\\it unique} information on the spectra of free, large carbon-containing molecules and ions in the gas phase. We are now, for the first time, in the position to directly compare laboratory spectral data on free, cold, PAH ions and carbon nano-sized carbon particles with astronomical observations in the UV-NIR range (interstellar UV extinction, DIBs in the NUV-NIR range). This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems Le., the "new frontier space missions" (Spitzer, HST, COS, JWST, SOFIA,...).

Diagnosing the Neutral Interstellar Gas Flow at 1 AU with IBEX-Lo

NASA Astrophysics Data System (ADS)

Möbius, E.; Kucharek, H.; Clark, G.; O'Neill, M.; Petersen, L.; Bzowski, M.; Saul, L.; Wurz, P.; Fuselier, S. A.; Izmodenov, V. V.; McComas, D. J.; Müller, H. R.; Alexashov, D. B.

2009-08-01

Every year in fall and spring the Interstellar Boundary Explorer (IBEX) will observe directly the interstellar gas flow at 1 AU over periods of several months. The IBEX-Lo sensor employs a powerful triple time-of-flight mass spectrometer. It can distinguish and image the O and He flow distributions in the northern fall and spring, making use of sensor viewing perpendicular to the Sun-pointing spin axis. To effectively image the narrow flow distributions IBEX-Lo has a high angular resolution quadrant in its collimator. This quadrant is employed selectively for the interstellar gas flow viewing in the spring by electrostatically shutting off the remainder of the aperture. The operational scenarios, the expected data, and the necessary modeling to extract the interstellar parameters and the conditions in the heliospheric boundary are described. The combination of two key interstellar species will facilitate a direct comparison of the pristine interstellar flow, represented by He, which has not been altered in the heliospheric boundary region, with a flow that is processed in the outer heliosheath, represented by O. The O flow distribution consists of a depleted pristine component and decelerated and heated neutrals. Extracting the latter so-called secondary component of interstellar neutrals will provide quantitative constraints for several important parameters of the heliosheath interaction in current global heliospheric models. Finding the fraction and width of the secondary component yields an independent value for the global filtration factor of species, such as O and H. Thus far filtration can only be inferred, barring observations in the local interstellar cloud proper. The direction of the secondary component will provide independent information on the interstellar magnetic field strength and orientation, which has been inferred from SOHO SWAN Ly- α backscattering observations and the two Voyager crossings of the termination shock.

Solid lithium ion conducting electrolytes and methods of preparation

DOEpatents

Narula, Chaitanya K; Daniel, Claus

2013-05-28

A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

Solid lithium ion conducting electrolytes and methods of preparation

DOEpatents

Narula, Chaitanya K.; Daniel, Claus

2015-11-19

A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

Interrelationships between interstellar and interplanetary grains

NASA Technical Reports Server (NTRS)

Clayton, D. D.

1986-01-01

The relationship between solar system dust (SSD) and interstellar dust particles (ISMD) is being reconsidered because of the discovery of isotopic anomalies in meteorites. Meteoritic, circumstellar/meteoritic, interstellar/meteoritic, planetary, and cometary data are reviewed.

Interstellar Travel

NASA Astrophysics Data System (ADS)

Rabayda, Adam; Keller, Luke

Interstellar space travel is a topic that is often dismissed as highly unlikely due to the vast distances involved and to considerable engineering and socioeconomic challenges. Some are left believing that it may be far from possible for us, as a species, to go anywhere beyond our solar system. We demonstrate not only the possibility of covering interstellar distances in decades or less, but also that interstellar travel is possible (in principle) with existing technology. For example: Using only special relativity and calculus, we calculated that an interstellar spacecraft could reach the Andromeda Galaxy (2.5 Million light-years from Earth) in just over 28 years at an acceleration of 9 . 81m/s , which would emulate Earth gravity. We also calculated that the energy required for interstellar space travel, often deemed impossible with current technology, is, in fact, possible through certain methods such as nuclear fusion.

THERMODYNAMICS AND CHARGING OF INTERSTELLAR IRON NANOPARTICLES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hensley, Brandon S.; Draine, B. T., E-mail: brandon.s.hensley@jpl.nasa.gov

Interstellar iron in the form of metallic iron nanoparticles may constitute a component of the interstellar dust. We compute the stability of iron nanoparticles to sublimation in the interstellar radiation field, finding that iron clusters can persist down to a radius of ≃4.5 Å, and perhaps smaller. We employ laboratory data on small iron clusters to compute the photoelectric yields as a function of grain size and the resulting grain charge distribution in various interstellar environments, finding that iron nanoparticles can acquire negative charges, particularly in regions with high gas temperatures and ionization fractions. If ≳10% of the interstellar ironmore » is in the form of ultrasmall iron clusters, the photoelectric heating rate from dust may be increased by up to tens of percent relative to dust models with only carbonaceous and silicate grains.« less

Is interstellar archeology possible?

NASA Astrophysics Data System (ADS)

Carrigan, Richard A.

2012-09-01

Searching for signatures of cosmic-scale archeological artifacts such as Dyson spheres is an interesting alternative to conventional radio SETI. Uncovering such an artifact does not require the intentional transmission of a signal on the part of the original civilization. This type of search is called interstellar archeology or sometimes cosmic archeology. A variety of interstellar archeology signatures is discussed including non-natural planetary atmospheric constituents, stellar doping, Dyson spheres, as well as signatures of stellar, and galactic-scale engineering. The concept of a Fermi bubble due to interstellar migration is reviewed in the discussion of galactic signatures. These potential interstellar archeological signatures are classified using the Kardashev scale. A modified Drake equation is introduced. With few exceptions interstellar archeological signatures are clouded and beyond current technological capabilities. However SETI for so-called cultural transmissions and planetary atmosphere signatures are within reach.

Solid State Division progress report, September 30, 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-04-01

Progress made during the 19 months from March 1, 1980, through September 30, 1981, is reported in the following areas: theoretical solid state physics (surfaces, electronic and magnetic properties, particle-solid interactions, and laser annealing); surface and near-surface properties of solids (plasma materials interactions, ion-solid interactions, pulsed laser annealing, and semiconductor physics and photovoltaic conversion); defects in solids (radiation effects, fracture, and defects and impurities in insulating crystals); transport properties of solids (fast-ion conductors, superconductivity, and physical properties of insulating materials); neutron scattering (small-angle scattering, lattice dynamics, and magnetic properties); crystal growth and characterization (nuclear waste forms, ferroelectric mateirals, high-temperature materials,more » and special materials); and isotope research materials. Publications and papers are listed. (WHK)« less

Engineered glass seals for solid-oxide fuel cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Surdoval, Wayne; Lara-Curzio, Edgar; Stevenson, Jeffry

2017-02-07

A seal for a solid oxide fuel cell includes a glass matrix having glass percolation therethrough and having a glass transition temperature below 650.degree. C. A deformable second phase material is dispersed in the glass matrix. The second phase material can be a compliant material. The second phase material can be a crushable material. A solid oxide fuel cell, a precursor for forming a seal for a solid oxide fuel cell, and a method of making a seal for a solid oxide fuel cell are also disclosed.

Presolar Materials in a Giant Cluster IDP of Probable Cometary Origin

NASA Technical Reports Server (NTRS)

Messenger, S.; Brownlee, D. E.; Joswiak, D. J.; Nguyen, A. N.

2015-01-01

Chondritic porous interplanetary dust particles (CP-IDPs) have been linked to comets by their fragile structure, primitive mineralogy, dynamics, and abundant interstellar materials. But differences have emerged between 'cometary' CP-IDPs and comet 81P/Wild 2 Stardust Mission samples. Particles resembling Ca-Al-rich inclusions (CAIs), chondrules, and amoeboid olivine aggregates (AOAs) in Wild 2 samples are rare in CP-IDPs. Unlike IDPs, presolar materials are scarce in Wild 2 samples. These differences may be due to selection effects, such as destruction of fine grained (presolar) components during the 6 km/s aerogel impact collection of Wild 2 samples. Large refractory grains observed in Wild 2 samples are also unlikely to be found in most (less than 30 micrometers) IDPs. Presolar materials provide a measure of primitive-ness of meteorites and IDPs. Organic matter in IDPs and chondrites shows H and N isotopic anomalies attributed to low-T interstellar or protosolar disk chemistry, where the largest anomalies occur in the most primitive samples. Presolar silicates are abundant in meteorites with low levels of aqueous alteration (Acfer 094 approximately 200 ppm) and scarce in altered chondrites (e.g. Semarkona approximately 20 ppm). Presolar silicates in minimally altered CP-IDPs range from approximately 400 ppm to 15,000 ppm, possibly reflecting variable levels of destruction in the solar nebula or statistical variations due to small sample sizes. Here we present preliminary isotopic and mineralogical studies of a very large CP-IDP. The goals of this study are to more accurately determine the abundances of presolar components of CP-IDP material for comparison with comet Wild 2 samples and meteorites. The large mass of this IDP presents a unique opportunity to accurately determine the abundance of pre-solar grains in a likely cometary sample.

The heliosphere's interstellar interaction: no bow shock.

PubMed

McComas, D J; Alexashov, D; Bzowski, M; Fahr, H; Heerikhuisen, J; Izmodenov, V; Lee, M A; Möbius, E; Pogorelov, N; Schwadron, N A; Zank, G P

2012-06-08

As the Sun moves through the local interstellar medium, its supersonic, ionized solar wind carves out a cavity called the heliosphere. Recent observations from the Interstellar Boundary Explorer (IBEX) spacecraft show that the relative motion of the Sun with respect to the interstellar medium is slower and in a somewhat different direction than previously thought. Here, we provide combined consensus values for this velocity vector and show that they have important implications for the global interstellar interaction. In particular, the velocity is almost certainly slower than the fast magnetosonic speed, with no bow shock forming ahead of the heliosphere, as was widely expected in the past.

Observations of interstellar zinc

NASA Technical Reports Server (NTRS)

Jura, M.; York, D.

1981-01-01

The International Ultraviolet Explorer observations of interstellar zinc toward 10 stars are examined. It is found that zinc is at most only slightly depleted in the interstellar medium; its abundance may serve as a tracer of the true metallicity in the gas. The local interstellar medium has abundances that apparently are homogeneous to within a factor of two, when integrated over paths of about 500 pc, and this result is important for understanding the history of nucleosynthesis in the solar neighborhood. The intrinsic errors in detecting weak interstellar lines are analyzed and suggestions are made as to how this error limit may be lowered to 5 mA per target observation.

Deflection of the Interstellar Neutral Hydrogen Flow Across the Heliospheric Interface: an Interstellar Magnetic Compass

NASA Astrophysics Data System (ADS)

Lallement, R.; Eric, Q.; Jean-Loup, B.; Dimitra, K.; Risto, P.

2005-05-01

Analyses of SOHO-SWAN observations show that the interstellar neutral H flow direction differs by about 4 degrees from the neutral He flow direction recently derived with an unprecedented accuracy using combined data sets (Mobius et al, 2004). The most likely explanation is a distortion of the heliospheric interface under the action of an inclined interstellar magnetic field, with imprints of the distorsion on the neutral H flow due to charge-transfer reactions between H atoms and ions. The direction of the ambient interstellar magnetic field and the heliospheric shape can be derived from the observed deviation. Implications for Voyager trajectories are discussed.

40 CFR 241.3 - Standards and procedures for identification of non-hazardous secondary materials that are solid...

Code of Federal Regulations, 2011 CFR

2011-07-01

... identification of non-hazardous secondary materials that are solid wastes when used as fuels or ingredients in...) SOLID WASTES SOLID WASTES USED AS FUELS OR INGREDIENTS IN COMBUSTION UNITS Identification of Non-Hazardous Secondary Materials That Are Solid Wastes When Used as Fuels or Ingredients in Combustion Units...

Voyager 1 Entering Interstellar Space Artist Concept

NASA Image and Video Library

2013-09-12

This artist concept depicts NASA Voyager 1 spacecraft entering interstellar space. Interstellar space is dominated by the plasma, or ionized gas, that was ejected by the death of nearby giant stars millions of years ago.

Interstellar Polycyclic Aromatic Compounds and Astrophysics

NASA Technical Reports Server (NTRS)

Hodgins, Douglas M.; DeVincenzi, Donald (Technical Monitor)

1999-01-01

Polycyclic aromatic compounds (PACs), a class of organic molecules whose structures are characterized by the presence of two or more fused aromatic rings, have been the subject of astrophysical interest for nearly two decades. Large by interstellar standards (from as few as 20 to perhaps as many as several hundred atoms), it has been suggested that these species are among the most abundant interstellar molecules impacting a wide range of astrophysical phenomena including: the ubiquitous family of infrared emission bands observed in an ever-increasing assortment of astronomical objects; the subtle but rich array of discrete visible/near-infrared interstellar molecular absorption features known as the diffuse interstellar bands (DIBs); the broad near-infrared quasi-continuum observed in a number of nebulae known as excess red emission (ERE); the interstellar ultraviolet extinction curve and broad '2200 Angstrom bump'; the heating/cooling mechanisms of interstellar clouds. Nevertheless, until recently a lack of good-quality laboratory spectroscopic data on PACs under astrophysically relevant conditions (i.e. isolated, ionized molecules; ionized molecular clusters, etc.) has hindered critical evaluation and extension of this model

Method of altering the effective bulk density of solid material and the resulting product

DOEpatents

Kool, Lawrence B.; Nolen, Robert L.; Solomon, David E.

1983-01-01

A method of adjustably tailoring the effective bulk density of a solid material in which a mixture comprising the solid material, a film-forming polymer and a volatile solvent are sprayed into a drying chamber such that the solvent evaporates and the polymer dries into hollow shells having the solid material captured within the shell walls. Shell density may be varied as a function of solid/polymer concentration, droplet size and drying temperature.

The isotopic composition of cosmic-ray calcium

NASA Technical Reports Server (NTRS)

Wiedenbeck, M. E.; George, J. S.; Binns, W. R.; Christian, E. R.; Cummings, A. C.; Davis, A. J.; Israel, M. H.; Leske, R. A.; Mewaldt, R. A.; Stone, E. C.;

Kant, Immanuel (1724-1804)

NASA Astrophysics Data System (ADS)

Murdin, P.

2000-11-01

German philosopher, born in Königsberg, published his view of the universe in General History of Nature and Theory of the Heavens (1755) in which he presented his nebular hypothesis of the formation of the solar system. It was much like the present theory that the Sun and planets formed from the condensation of a rotating disc of interstellar material. Kant identified the Milky Way as a lens-shap...

The LDEF benefits. [planned experiments

NASA Technical Reports Server (NTRS)

Kinard, W. H.

1982-01-01

The Long Duration Exposure Facility (LDEF) is described, and experiments planned for the first LDEF mission are discussed. Four of the eight involve scientific studies of interstellar gas, micrometeoroids, cosmic rays, and crystal growth in zero gravity, and four involve technology studies of the space environmental effects on solar cells, composite materials, thermal coatings, fiber optics, and electronic instruments. For each experiment, the objectives and methods are discussed.

Hot atoms in cosmic chemistry.

PubMed

Rossler, K; Jung, H J; Nebeling, B

1984-01-01

High energy chemical reactions and atom molecule interactions might be important for cosmic chemistry with respect to the accelerated species in solar wind, cosmic rays, colliding gas and dust clouds and secondary knock-on particles in solids. "Hot" atoms with energies ranging from a few eV to some MeV can be generated via nuclear reactions and consequent recoil processes. The chemical fate of the radioactive atoms can be followed by radiochemical methods (radio GC or HPLC). Hot atom chemistry may serve for laboratory simulation of the reactions of energetic species with gaseous or solid interstellar matter. Due to the effective measurement of 10(8)-10(10) atoms only it covers a low to medium dose regime and may add to the studies of ion implantation which due to the optical methods applied are necessarily in the high dose regime. Experimental results are given for the systems: C/H2O (gas), C/H2O (solid, 77 K), N/CH4 (solid, 77K) and C/NH3 (solid, 77 K). Nuclear reactions used for the generation of 2 to 3 MeV atoms are: N(p,alpha) 11C, 16O(p,alpha pn) 11C and 12C(d,n) 13N with 8 to 45 MeV protons or deuterons from a cyclotron. Typical reactions products are: CO, CO2, CH4, CH2O, CH3OH, HCOOH, NH3, CH3NH2, cyanamide, formamidine, guanidine etc. Products of hot reactions in solids are more complex than in corresponding gaseous systems, which underlines the importance of solid state reactions for the build-up of precursors for biomolecules in space. As one of the major mechanisms for product formation, the simultaneous or fast consecutive reactions of a hot carbon with two target molecules (reaction complex) is discussed.

What is Eating Ozone? Thermal Reactions between SO2 And O3: Implications for Icy Environments

NASA Technical Reports Server (NTRS)

Loeffler, Mark J.; Hudson, Reggie L.

2016-01-01

Laboratory studies are presented, showing for the first time that thermally driven reactions in solid H2O+SO2+O3 mixtures can occur below 150 K, with the main sulfur-containing product being bisulfate (HSO4(-)). Using a technique not previously applied to the low-temperature kinetics of either interstellar or solar system ice analogs, we estimate an activation energy of 32 kJ per mol for HSO4(-) formation. These results show that at the temperatures of the Jovian satellites, SO2 and O3 will efficiently react making detection of these molecules in the same vicinity unlikely. Our results also explain why O3 has not been detected on Callisto and why the SO2 concentration on Callisto appears to be highest on that world's leading hemisphere. Furthermore, our results predict that the SO2 concentration on Ganymede will be lowest in the trailing hemisphere, where the concentration of O3 is the highest. Our work suggests that thermal reactions in ices play a much more important role in surface and sub-surface chemistry than generally appreciated, possibly explaining the low abundance of sulfur-containing molecules and the lack of ozone observed in comets and interstellar ices.

KSC-02pd2049

NASA Image and Video Library

2002-10-24

KENNEDY SPACE CENTER, FLA. - On the launch tower on NASA's Space Launch Complex 2 (SLC-2), Vandenberg Air Force Base, Calif., a solid rocket booster is lifted into an upright position beside the Delta II rocket to which it will be attached. The rocket will carry the ICESat and CHIPSat satellites into Earth orbits. ICESat is a 661-pound satellite known as Geoscience Laser Altimeter System (GLAS) that will revolutionize our understanding of ice and its role in global climate change and how we protect and understand our home planet. It will help scientists determine if the global sea level is rising or falling. It will look at the ice sheets that blanket the Earth's poles to see if they are growing or shrinking. It will assist in developing an understanding of how changes in the Earth's atmosphere and climate effect polar ice masses and global sea level. CHIPSat, a suitcase-size 131-pound satellite, will provide invaluable information into the origin, physical processes and properties of the hot gas contained in the interstellar medium. This can provide important clues about the formation and evolution of galaxies since the interstellar medium literally contains the seeds of future stars. The Delta II launch is scheduled for Jan. 11 between 4:45 p.m. - 5:30 p.m. PST.

KSC-02pd2048

NASA Image and Video Library

2002-10-24

KENNEDY SPACE CENTER, FLA. - On the launch tower on NASA's Space Launch Complex 2 (SLC-2), Vandenberg Air Force Base, Calif., a solid rocket booster is lifted into an upright position as preparations continue to mate it to a Delta II rocket. The rocket will carry the ICESat and CHIPSat satellites into Earth orbits. ICESat is a 661-pound satellite known as Geoscience Laser Altimeter System (GLAS) that will revolutionize our understanding of ice and its role in global climate change and how we protect and understand our home planet. It will help scientists determine if the global sea level is rising or falling. It will look at the ice sheets that blanket the Earth's poles to see if they are growing or shrinking. It will assist in developing an understanding of how changes in the Earth's atmosphere and climate effect polar ice masses and global sea level. CHIPSat, a suitcase-size 131-pound satellite, will provide invaluable information into the origin, physical processes and properties of the hot gas contained in the interstellar medium. This can provide important clues about the formation and evolution of galaxies since the interstellar medium literally contains the seeds of future stars. The Delta II launch is scheduled for Jan. 11 between 4:45 p.m. - 5:30 p.m. PST.

Extragalactic interstellar extinction curves: Indicators of local physical conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cecchi-Pestellini, Cesare; Viti, Serena; Williams, David A., E-mail: cecchi-pestellini@astropa.unipa.it, E-mail: sv@star.ucl.ac.uk, E-mail: daw@star.ucl.ac.uk

Normalized interstellar extinction curves (ISECs) in the Milky Way and other galaxies show a variety of shapes. This variety is attributed to differences along different sight lines in the abundances of the several dust and gas components contributing to extinction. In this paper we propose that these abundance differences are not arbitrary but are a specific consequence of the physical conditions on those sight lines. If this proposal is correct, then it implies that ISECs contain information about physical conditions in the regions generating extinction. This may be particularly important for high redshift galaxies where information on the conditions maymore » be difficult to obtain. We adopt a model of extinction carriers in which the solid and gaseous components are not immutable but respond time-dependently to the local physics. We validate this model by fitting extinction curves measured on sight lines in the Magellanic Clouds and obtained for the gamma-ray burst afterglow GRB 080605. We present results for this model as follows: (1) we show that computed ISECs are controlled by a small number of physical parameters, (2) we demonstrate the sensitivity of computed ISECs to these parameters, (3) we compute as examples ISECs for particular galaxy types, and (4) we note that different galaxy types have different shapes of ISEC.« less

Peeling the astronomical onion.

PubMed

Rosu-Finsen, Alexander; Marchione, Demian; Salter, Tara L; Stubbing, James W; Brown, Wendy A; McCoustra, Martin R S

2016-11-23

Water ice is the most abundant solid in the Universe. Understanding the formation, structure and multiplicity of physicochemical roles for water ice in the cold, dense interstellar environments in which it is predominantly observed is a crucial quest for astrochemistry as these are regions active in star and planet formation. Intuitively, we would expect the mobility of water molecules deposited or synthesised on dust grain surfaces at temperatures below 50 K to be very limited. This work delves into the thermally-activated mobility of H 2 O molecules on model interstellar grain surfaces. The energy required to initiate this process is studied by reflection-absorption infrared spectroscopy of small quantities of water on amorphous silica and highly oriented pyrolytic graphite surfaces as the surface is annealed. Strongly non-Arrhenius behaviour is observed with an activation energy of 2 kJ mol -1 on the silica surface below 25 K and 0 kJ mol -1 on both surfaces between 25 and 100 K. The astrophysical implication of these results is that on timescales shorter than that estimated for the formation of a complete monolayer of water ice on a grain, aggregation of water ice will result in a non-uniform coating of water, hence leaving bare grain surface exposed. Other molecules can thus be formed or adsorbed on this bare surface.

KSC-02pd2047

NASA Image and Video Library

2002-10-24

KENNEDY SPACE CENTER, FLA. - On the launch tower on NASA's Space Launch Complex 2 (SLC-2), Vandenberg Air Force Base, Calif., a solid rocket booster is lifted into an upright position for mating to a Delta II rocket. The rocket will carry the ICESat and CHIPSat satellites into Earth orbits. ICESat is a 661-pound satellite known as Geoscience Laser Altimeter System (GLAS) that will revolutionize our understanding of ice and its role in global climate change and how we protect and understand our home planet. It will help scientists determine if the global sea level is rising or falling. It will look at the ice sheets that blanket the Earth's poles to see if they are growing or shrinking. It will assist in developing an understanding of how changes in the Earth's atmosphere and climate effect polar ice masses and global sea level. CHIPSat, a suitcase-size 131-pound satellite, will provide invaluable information into the origin, physical processes and properties of the hot gas contained in the interstellar medium. This can provide important clues about the formation and evolution of galaxies since the interstellar medium literally contains the seeds of future stars. The Delta II launch is scheduled for Jan. 11 between 4:45 p.m. - 5:30 p.m. PST.

49 CFR 173.212 - Non-bulk packagings for solid hazardous materials in Packing Group II.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 2 2011-10-01 2011-10-01 false Non-bulk packagings for solid hazardous materials... Hazardous Materials Other Than Class 1 and Class 7 § 173.212 Non-bulk packagings for solid hazardous materials in Packing Group II. (a) When § 172.101 of this subchapter specifies that a solid hazardous...

49 CFR 173.212 - Non-bulk packagings for solid hazardous materials in Packing Group II.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 2 2010-10-01 2010-10-01 false Non-bulk packagings for solid hazardous materials... Hazardous Materials Other Than Class 1 and Class 7 § 173.212 Non-bulk packagings for solid hazardous materials in Packing Group II. (a) When § 172.101 of this subchapter specifies that a solid hazardous...

49 CFR 173.213 - Non-bulk packagings for solid hazardous materials in Packing Group III.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 2 2010-10-01 2010-10-01 false Non-bulk packagings for solid hazardous materials... Hazardous Materials Other Than Class 1 and Class 7 § 173.213 Non-bulk packagings for solid hazardous materials in Packing Group III. (a) When § 172.101 of this subchapter specifies that a solid hazardous...