40 CFR 268.20 - Waste specific prohibitions-Dyes and/or pigments production wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land... contaminated with radioactive wastes mixed with this waste are prohibited from land disposal. (b) The... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of part 268 are...

40 CFR 268.20 - Waste specific prohibitions-Dyes and/or pigments production wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land... contaminated with radioactive wastes mixed with this waste are prohibited from land disposal. (b) The... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of part 268 are...

40 CFR 268.20 - Waste specific prohibitions-Dyes and/or pigments production wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land... contaminated with radioactive wastes mixed with this waste are prohibited from land disposal. (b) The... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of part 268 are...

40 CFR 268.20 - Waste specific prohibitions-Dyes and/or pigments production wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land... contaminated with radioactive wastes mixed with this waste are prohibited from land disposal. (b) The... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of part 268 are...

40 CFR 268.35 - Waste specific prohibitions-petroleum refining wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.35 Waste... contaminated with these radioactive mixed wastes, are prohibited from land disposal. (b) The requirements of... Universal Treatment Standard levels of § 268.48, the waste is prohibited from land disposal, and all...

40 CFR 268.39 - Waste specific prohibitions-spent aluminum potliners; reactive; and carbamate wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.39 Waste specific prohibitions—spent aluminum potliners; reactive; and carbamate...-U411 are prohibited from land disposal. In addition, soil and debris contaminated with these wastes are...

40 CFR 268.39 - Waste specific prohibitions-spent aluminum potliners; reactive; and carbamate wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.39 Waste specific prohibitions—spent aluminum potliners; reactive; and carbamate...-U411 are prohibited from land disposal. In addition, soil and debris contaminated with these wastes are...

40 CFR 268.39 - Waste specific prohibitions-spent aluminum potliners; reactive; and carbamate wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.39 Waste specific prohibitions—spent aluminum potliners; reactive; and carbamate...-U411 are prohibited from land disposal. In addition, soil and debris contaminated with these wastes are...

40 CFR 268.39 - Waste specific prohibitions-spent aluminum potliners; reactive; and carbamate wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.39 Waste specific prohibitions—spent aluminum potliners; reactive; and carbamate...-U411 are prohibited from land disposal. In addition, soil and debris contaminated with these wastes are...

40 CFR 268.39 - Waste specific prohibitions-spent aluminum potliners; reactive; and carbamate wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.39 Waste specific prohibitions—spent aluminum potliners; reactive; and carbamate...-U411 are prohibited from land disposal. In addition, soil and debris contaminated with these wastes are...

Analysis of the contaminants released from municipal solid waste landfill site: A case study.

PubMed

Samadder, S R; Prabhakar, R; Khan, D; Kishan, D; Chauhan, M S

2017-02-15

Release and transport of leachate from municipal solid waste landfills pose a potential hazard to both surrounding ecosystems and human populations. In the present study, soil, groundwater, and surface water samples were collected from the periphery of a municipal solid waste landfill (located at Ranital of Jabalpur, Madhya Pradesh, India) for laboratory analysis to understand the release of contaminants. The landfill does not receive any solid wastes for dumping now as the same is under a landfill closure plan. Groundwater and soil samples were collected from the bore holes of 15m deep drilled along the periphery of the landfill and the surface water samples were collected from the existing surface water courses near the landfill. The landfill had neither any bottom liner nor any leachate collection and treatment system. Thus the leachate generated from the landfills finds paths into the groundwater and surrounding surface water courses. Concentrations of various physico-chemical parameters including some toxic metals (in collected groundwater, soil, and surface water samples) and microbiological parameters (in surface water samples) were determined. The analyzed data were integrated into ArcGIS environment and the spatial distribution of the metals and other physic- chemical parameter across the landfill was extrapolated to observe the distribution. The statistical analysis and spatial variations indicated the leaching of metals from the landfill to the groundwater aquifer system. The study will help the readers and the municipal engineers to understand the release of contaminants from landfills for better management of municipal solid wastes. Copyright © 2016 Elsevier B.V. All rights reserved.

H. R. 3430: Food Contamination Prevention Act. Introduced in the House of Representatives, One Hundredth Congress, First Session, October 6, 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This bill was introduced in the House of Representatives on October 6, 1989 for the purpose of amending the Solid Waste Disposal Act to regulate the transportation in commerce of solid waste food by prohibiting certain vehicles from transporting both waste and food, and by requiring health and safety standards for certain vehicles used to transport certain waste and food. Hazardous waste, medical waste, and terminal waste cannot be transported in any vehicle that is also used to transport food, food additives, drugs, or cosmetics.

Cleanup Verification Package for the 618-8 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel

2006-08-10

This cleanup verification package documents completion of remedial action for the 618-8 Burial Ground, also referred to as the Solid Waste Burial Ground No. 8, 318-8, and the Early Solid Waste Burial Ground. During its period of operation, the 618-8 site is speculated to have been used to bury uranium-contaminated waste derived from fuel manufacturing, and construction debris from the remodeling of the 313 Building.

Effect of liquid-to-solid ratio on semi-solid Fenton process in hazardous solid waste detoxication.

PubMed

Hu, Li-Fang; Feng, Hua-Jun; Long, Yu-Yang; Zheng, Yuan-Ge; Fang, Cheng-Ran; Shen, Dong-Sheng

2011-01-01

The liquid-to-solid ratio (L/S) of semi-solid Fenton process (SSFP) designated for hazardous solid waste detoxication was investigated. The removal and minimization effects of o-nitroaniline (ONA) in simulate solid waste residue (SSWR) from organic arsenic industry was evaluated by total organic carbon (TOC) and ONA removal efficiency, respectively. Initially, Box-Behnken design (BBD) and response surface methodology (RSM) were used to optimize the key factors of SSFP. Results showed that the removal rates of TOC and ONA decreased as L/S increased. Subsequently, four target initial ONA concentrations including 100 mg kg(-1), 1 g kg(-1), 10 g kg(-1), and 100 gk g(-1) on a dry basis were evaluated for the effect of L/S. A significant cubic empirical model between the initial ONA concentration and L/S was successfully developed to predict the optimal L/S for given initial ONA concentration for SSFP. Moreover, an optimized operation strategy of multi-SSFP for different cases was determined based on the residual target pollutant concentration and the corresponding environmental conditions. It showed that the total L/S of multi-SSFP in all tested scenarios was no greater than 3.8, which is lower than the conventional slurry systems (L/S ≥ 5). The multi-SSFP is environment-friendly when it used for detoxication of hazardous solid waste contaminated by ONA and provides a potential method for the detoxication of hazardous solid waste contaminated by organics. Copyright © 2010 Elsevier Ltd. All rights reserved.

40 CFR 265.228 - Closure and post-closure care.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Section 265.228 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND... or operator must: (1) Remove or decontaminate all waste residues, contaminated containment system...

Assessment of sanitary landfill leachate characterizations and its impacts on groundwater at Alexandria.

PubMed

Hassan, Ahmed Hossam; Ramadan, Mohamed Hassan

2005-01-01

The total amount of solid waste generated in Alexandria is 2820 tons/d which increases to 3425 tons/day during summer. In the past, 77% of the collected solid wastes was open dumped. The open dumping sites did not have the minimum requirements for pollution control. Following the exacerbation of the problem, the Alexandria Governorate contracted a company to carry out the solid waste management. The contracted company transferred 75% of the daily generated solid wastes to a new constructed sanitary lanfill. The site receives a daily average of 1910 tons. The landfilling is performed by trench method in the form of cells. The produced leachate is discharged into two lined aerated lagoons. The biogas formed from biodegradation of landfilled solid wastes is burned and the produced heat is used for drying the lagoons leachate. The remaining residues are relandfilled. The study aims at assessment of the solid waste sanitary landfill leachate characterization and its impacts on the groundwater. The analysis of the collected data confirms that leachates from the landfill are severely contaminated with organics, salts, and heavy metals. The fluctuations in concentration levels of the different parameters were attributed to aging and thickness of waste layers, stage of decomposition, and re-landfilling of the concentrated residues from the drying lagoons. The concentrations of NH4-N (600 mg/l) indicated that the process of stabilization was still in the initial stages and attributed to the compaction process. The high BOD5 results (28,833 mg/l) indicated that the process of stabilization was in the initial stages which were very slow. The high COD results (45,240 mg/l) can be attributed to the compaction of the wastes which also retards the degradation of the solid wastes. The BOD and COD values indicated clearly severe contamination. The BOD5/COD ratio measured in the current study (0.64) indicated that the leachate of the present study was biodegradable and unstabilized, and required time and favourable conditions for anaerobic biodegradation. Heavy metals were lower compared with what have been observed in other countries. Re-landfilling of the residue after drying the leachate in lagoons and the short time of biodegradation in the landfill site were factors which effected the high strength of most of the parameters concentrations of the leachate. Assessment of groundwater contamination through piezometer wells around the active cells indicated that there was no contamination from the leachate to the groundwater surrounding the site. The study recommended emphasizing the importance of adjusting the biodegradation factors, the monitoring program, the prohibition of disposing heavy metals, determination of the leachate generation rate, and treatment of leachate.

40 CFR 267.111 - What general standards must I meet when I stop operating the unit?

Code of Federal Regulations, 2011 CFR

2011-07-01

... to protect human health and the environment, post-closure escape of hazardous waste, hazardous constituents, leachate, contaminated run-off, or hazardous waste decomposition products to the ground or... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE...

40 CFR 267.111 - What general standards must I meet when I stop operating the unit?

Code of Federal Regulations, 2010 CFR

2010-07-01

... to protect human health and the environment, post-closure escape of hazardous waste, hazardous constituents, leachate, contaminated run-off, or hazardous waste decomposition products to the ground or... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE...

Volume reduction of hot cell plastic wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dykes, F W; Henscheid, J P; Lewis, L C

1989-09-19

The disposal of radioactively-contaminated solid wastes has become a national crisis. In such circumstances, it is imperative that this waste be reduced to minimum volume and be packaged to prevent pollution of the environment. The majority of the solid waste generated at the hot cell under consideration is plastic lab ware. Cutting this waste into small pieces with a hot wire technique reduced the volume 66%. Melting the waste, although more time consuming, reduced the volume 90%. The hot wire technique can also be used to cut up damaged master slave manipulator boots, greatly reducing their disposal volume.

Alternative Processes for Water Reclamation and Solid Waste Processing in a Physical/chemical Bioregenerative Life Support System

NASA Technical Reports Server (NTRS)

Rogers, Tom D.

1990-01-01

Viewgraphs on alternative processes for water reclamation and solid waste processing in a physical/chemical-bioregenerative life support system are presented. The main objective is to focus attention on emerging influences of secondary factors (i.e., waste composition, type and level of chemical contaminants, and effects of microorganisms, primarily bacteria) and to constructively address these issues by discussing approaches which attack them in a direct manner.

40 CFR Appendix I to Part 257 - Maximum Contaminant Levels (MCLs)

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Maximum Contaminant Levels (MCLs) I Appendix I to Part 257 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Part 257—Maximum Contaminant Levels (MCLs) Maximum Contaminant Levels (MCLs) Promulgated Under the Safe...

Method for removing hydrocarbon contaminants from solid materials

DOEpatents

Bala, Gregory A.; Thomas, Charles P.

1995-01-01

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Method for removing hydrocarbon contaminants from solid materials

DOEpatents

Bala, G.A.; Thomas, C.P.

1995-10-03

A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

Apparatus for removing hydrocarbon contaminants from solid materials

DOEpatents

Bala, G.A.; Thomas, C.P.

1996-02-13

A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

Apparatus for removing hydrocarbon contaminants from solid materials

DOEpatents

Bala, Gregory A.; Thomas, Charles P.

1996-01-01

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

SOURCE ASSESSMENT: RECLAIMING OF WASTE SOLVENTS, STATE OF THE ART

EPA Science Inventory

This document reviews the state of the art of air emissions from the reclaiming of waste solvents. The composition, quantity, and rate of emissions are described. Waste solvents are organic dissolving agents which are contaminated with suspended and dissolved solids, organics, wa...

A pilot-scale steam autoclave system for treating municipal solid waste for recovery of renewable organic content: Operational results and energy usage

USDA-ARS?s Scientific Manuscript database

A pilot-scale (1800'kg per batch capacity) autoclave used in this study reduces municipal solid waste to a debris contaminated pulp product that is efficiently separated into its renewable organic content and non-renewable organic content fractions using a rotary trommel screen. The renewable organi...

Control of Effluent Gases from Solid Waste Processing using Impregnated Carbon Nanotubes

NASA Technical Reports Server (NTRS)

Li, Jing; Fisher, John; Wignarajah, Kanapathipillai

2005-01-01

One of the major problems associated with solid waste processing technologies is effluent contaminants that are released in gaseous forms from the processes. This is a concern in both biological as well as physicochemical solid waste processing. Carbon dioxide (CO2), the major gas released, does not present a serious problem and there are currently in place a number of flight-qualified technologies for CO2 removal. However, a number of other gases, in particular NOx, SO2, NH3, and various hydrocarbons (e.g. CH4) do present health hazards to the crew members in space habitats. In the present configuration of solid waste processing in the International Space Station (ISS), some of these gases are removed by the Trace Contaminant Control System (TCCS), demands a major resupply. Reduction of the resupply can be effective by using catalyst impregnated carbon nanotubes. For example, NO decomposition to N2 and O2 is thermodynamically favored. Data showing decomposition of NO on metal impregnated carbon nanotubes is presented. Comparisons are made of the existing TCCS systems with the carbon nanotube based technology for removing NOx based on mass/energy penalties.

ASSESSING DETOXIFICATION AND DEGRADATION OF WOOD PRESERVING AND PETROLEUM WASTES IN CONTAMINATED SOIL

EPA Science Inventory

This study was undertaken to evaluate in-situ soil bioremediation processes, including degradation and detoxification, for two types of wood preserving wastes and two types of petroleum refining wastes at high concentrations in an unacclimated soil. The soil solid phase, water so...

Assessment of mobility and bioavailability of contaminants in MSW incineration ash with aquatic and terrestrial bioassays.

PubMed

Ribé, V; Nehrenheim, E; Odlare, M

2014-10-01

Incineration of municipal solid waste (MSW) is a waste treatment method which can be sustainable in terms of waste volume reduction as well as a source of renewable energy. In the process fly and bottom ash is generated as a waste material. The ash residue may vary greatly in composition depending on the type of waste incinerated and it can contain elevated levels of harmful contaminants such as heavy metals. In this study, the ecotoxicity of a weathered, untreated incineration bottom ash was characterized as defined by the H14 criterion of the EU Waste Framework Directive by means of an elemental analysis, leaching tests followed by a chemical analysis and a combination of aquatic and solid-phase bioassays. The experiments were conducted to assess the mobility and bioavailability of ash contaminants. A combination of aquatic and terrestrial bioassays was used to determine potentially adverse acute effects of exposure to the solid ash and aqueous ash leachates. The results from the study showed that the bottom ash from a municipal waste incineration plant in mid-Sweden contained levels of metals such as Cu, Pb and Zn, which exceeded the Swedish EPA limit values for inert wastes. The chemical analysis of the ash leachates showed high concentrations of particularly Cr. The leachate concentration of Cr exceeded the limit value for L/S 10 leaching for inert wastes. Filtration of leachates prior to analysis may have underestimated the leachability of complex-forming metals such as Cu and Pb. The germination test of solid ash and ash leachates using T. repens showed a higher inhibition of seedling emergence of seeds exposed to the solid ash than the seeds exposed to ash leachates. This indicated a relatively low mobility of toxicants from the solid ash into the leachates, although some metals exceeded the L/S 10 leaching limit values for inert wastes. The Microtox® toxicity test showed only a very low toxic response to the ash leachate exposure, while the D. magna immobility test showed a moderately high toxic effect of the ash leachates. Overall, the results from this study showed an ecotoxic effect of the solid MSW bottom ash and the corresponding ash leachates. The material may therefore pose an environmental risk if used in construction applications. However, as the testing of the solid ash was rather limited and the ash leachate showed an unusually high leaching of Cr, further assessments are required in order to conclusively characterize the bottom ash studied herein as hazardous according to the H14 criterion. Copyright © 2014 Elsevier Ltd. All rights reserved.

Use of a CO{sub 2} pellet non-destructive cleaning system to decontaminate radiological waste and equipment in shielded hot cells at the Bettis Atomic Power Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bench, T.R.

1997-05-01

This paper details how the Bettis Atomic Power Laboratory modified and utilized a commercially available, solid carbon dioxide (CO{sub 2}) pellet, non-destructive cleaning system to support the disposition and disposal of radioactive waste from shielded hot cells. Some waste materials and equipment accumulated in the shielded hot cells cannot be disposed directly because they are contaminated with transuranic materials (elements with atomic numbers greater than that of uranium) above waste disposal site regulatory limits. A commercially available CO{sub 2} pellet non-destructive cleaning system was extensively modified for remote operation inside a shielded hot cell to remove the transuranic contaminants frommore » the waste and equipment without generating any secondary waste in the process. The removed transuranic contaminants are simultaneously captured, consolidated, and retained for later disposal at a transuranic waste facility.« less

Report: new guidelines for characterization of municipal solid waste: the Portuguese case.

PubMed

da Graça Madeira Martinho, Maria; Silveira, Ana Isabel; Fernandes Duarte Branco, Elsa Maria

2008-10-01

This report proposes a new set of guidelines for the characterization of municipal solid waste. It is based on an analysis of reference methodologies, used internationally, and a case study of Valorsul (a company that handles recovery and treatment of solid waste in the North Lisbon Metropolitan Area). In particular, the suggested guidelines present a new definition of the waste to be analysed, change the sampling unit and establish statistical standards for the results obtained. In these new guidelines, the sampling level is the waste collection vehicle and contamination and moisture are taken into consideration. Finally, focus is on the quality of the resulting data, which is essential for comparability of data between countries. These new guidelines may also be applicable outside Portugal because the methodology includes, besides municipal mixed waste, separately collected fractions of municipal waste. They are a response to the need for information concerning Portugal (e.g. Eurostat or OECD inquiries) and follow European Union municipal solid waste management policies (e.g. packaging waste recovery and recycling targets and the reduction of biodegradable waste going to landfill).

Critical evaluation of municipal solid waste composting and potential compost markets.

PubMed

Farrell, M; Jones, D L

2009-10-01

Mechanical biological treatment (MBT) of mixed waste streams is becoming increasingly popular as a method for treating municipal solid waste (MSW). Whilst this process can separate many recyclates from mixed waste, the resultant organic residue can contain high levels of heavy metals and physical and biological contaminants. This review assesses the potential end uses and sustainable markets for this organic residue. Critical evaluation reveals that the best option for using this organic resource is in land remediation and restoration schemes. For example, application of MSW-derived composts at acidic heavy metal contaminated sites has ameliorated soil pollution with minimal risk. We conclude that although MSW-derived composts are of low value, they still represent a valuable resource particularly for use in post-industrial environments. A holistic view should be taken when regulating the use of such composts, taking into account the specific situation of application and the environmental pitfalls of alternative disposal routes.

Pyrolysis of Plants After Phytoremediation of Contaminated Soil with Lead, Cadmium and Zinc.

PubMed

Özkan, Aysun; Günkaya, Zerrin; Banar, Müfide

2016-03-01

The aim of this study was to remediate lead (Pb), cadmium (Cd) and zinc (Zn) from contaminated soil and stabilize to pyrolysis solid product. To accomplish this, phytoremediation of soil contaminated with Pb, Cd and Zn by different plants (sunflower, corn and rape) was performed with and without ethylenediaminetetraacetic acid (EDTA). According to phytoremediation results, rape was the most effective plant with 72 %, 76 % and 77 % removal efficiency for Pb, Cd and Zn, respectively. Also, EDTA addition had no significant effect on translocation of the metals from roots to stems. According to pyrolysis results, Pb, Cd and Zn in the contaminated plants were stabilized in the ash/char fraction. In addition, the solid product can be safely landfilled as inert waste since its toxicity leaching value is lower than the limit values given in the Turkish Regulation on Landfilling of Wastes.

Solid waste management practices in wet coffee processing industries of Gidabo watershed, Ethiopia.

PubMed

Ulsido, Mihret D; Li, Meng

2016-07-01

The financial and social contributions of coffee processing industries within most coffee export-based national economies like Ethiopia are generally high. The type and amount of waste produced and the waste management options adopted by these industries can have negative effects on the environment. This study investigated the solid waste management options adopted in wet coffee processing industries in the Gidabo watershed of Ethiopia. A field observation and assessment were made to identify whether the operational characteristics of the industries have any effect on the waste management options that were practiced. The investigation was conducted on 125 wet coffee processing industries about their solid waste handling techniques. Focus group discussion, structured questionnaires, key informant interview and transect walks are some of the tools employed during the investigation. Two major types of wastes, namely hull-bean-pulp blended solid waste and wastewater rich in dissolved and suspended solids were generated in the industries. Wet mills, on average, released 20.69% green coffee bean, 18.58% water and 60.74% pulp by weight. Even though these wastes are rich in organic matter and recyclables; the most favoured solid waste management options in the watershed were disposal (50.4%) and industrial or household composting (49.6%). Laxity and impulsive decision are the driving motives behind solid waste management in Gidabo watershed. Therefore, to reduce possible contamination of the environment, wastes generated during the processing of red coffee cherries, such as coffee wet mill solid wastes, should be handled properly and effectively through maximisation of their benefits with minimised losses. © The Author(s) 2016.

Toxicity Assessment of Contaminated Soils of Solid Domestic Waste Landfill

NASA Astrophysics Data System (ADS)

Pasko, O. A.; Mochalova, T. N.

2014-08-01

The paper delivers the analysis of an 18-year dynamic pattern of land pollutants concentration in the soils of a solid domestic waste landfill. It also presents the composition of the contaminated soils from different areas of the waste landfill during its operating period. The authors calculate the concentrations of the following pollutants: chrome, nickel, tin, vanadium, lead, cuprum, zinc, cobalt, beryllium, barium, yttrium, cadmium, arsenic, germanium, nitrate ions and petrochemicals and determine a consistent pattern of their spatial distribution within the waste landfill area as well as the dynamic pattern of their concentration. Test-objects are used in experiments to make an integral assessment of the polluted soil's impact on living organisms. It was discovered that the soil samples of an animal burial site are characterized by acute toxicity while the area of open waste dumping is the most dangerous in terms of a number of pollutants. This contradiction can be attributed to the synergetic effect of the polluted soil, which accounts for the regularities described by other researchers.

Emerging contaminants at a closed and an operating landfill in Oklahoma

USGS Publications Warehouse

Andrews, William J.; Masoner, Jason R.; Cozzarelli, Isabelle M.

2012-01-01

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty-eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.

Transport and transportation pathways of hazardous chemicals from solid waste disposal.

PubMed Central

Van Hook, R I

1978-01-01

To evaluate the impact of hazardous chemicals in solid wastes on man and other organisms, it is necessary to have information about amounts of chemical present, extent of exposure, and chemical toxicity. This paper addresses the question of organism exposure by considering the major physical and biological transport pathways and the physicochemical and biochemical transformations that may occur in sediments, soils, and water. Disposal of solid wastes in both terrestrial and oceanic environments is considered. Atmospheric transport is considered for emissions from incineration of solid wastes and for wind resuspension of particulates from surface waste deposits. Solid wastes deposited in terrestrial environments are subject to leaching by surface and ground waters. Leachates may then be transported to other surface waters and drinking water aquifers through hydrologic transport. Leachates also interact with natural organic matter, clays, and microorganisms in soils and sediments. These interactions may render chemical constituents in leachates more or less mobile, possibly change chemical and physical forms, and alter their biological activity. Oceanic waste disposal practices result in migration through diffusion and ocean currents. Surface area-to-volume ratios play a major role in the initial distributions of chemicals in the aquatic environment. Sediments serve as major sources and sinks of chemical contaminants. Food chain transport in both aquatic and terrestrial environments results in the movement of hazardous chemicals from lower to higher positions in the food web. Bioconcentration is observed in both terrestrial and aquatic food chains with certain elements and synthetic organics. Bioconcentration factors tend to be higher for synthetic organics, and higher in aquatic than in terrestrial systems. Biodilution is not atypical in terrestrial environments. Synergistic and antagonistic actions are common occurrences among chemical contaminants and can be particularly important toxicity considerations in aquatic environments receiving runoff from several terrestrial sources. PMID:367772

40 CFR 264.603 - Post-closure care.

Code of Federal Regulations, 2011 CFR

2011-07-01

....603 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES... treatment or storage unit has contaminated soils or ground water that cannot be completely removed or...

Cleanup Verification Package for the 618-2 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

W. S. Thompson

2006-12-28

This cleanup verification package documents completion of remedial action for the 618-2 Burial Ground, also referred to as Solid Waste Burial Ground No. 2; Burial Ground No. 2; 318-2; and Dry Waste Burial Site No. 2. This waste site was used primarily for the disposal of contaminated equipment, materials and laboratory waste from the 300 Area Facilities.

Municipal solid waste management in Rasht City, Iran.

PubMed

Alavi Moghadam, M R; Mokhtarani, N; Mokhtarani, B

2009-01-01

Pollution and health risks generated by improper solid waste management are important issues concerning environmental management in developing countries. In most cities, the use of open dumps is common for the disposal of wastes, resulting in soil and water resource contamination by leachate in addition to odors and fires. Solid waste management infrastructure and services in developing countries are far from achieving basic standards in terms of hygiene and efficient collection and disposal. This paper presents an overview of current municipal solid waste management in Rasht city, Gilan Province, Iran, and provides recommendations for system improvement. The collected data of different MSW functional elements were based on data from questionnaires, visual observations of the authors, available reports and several interviews and meetings with responsible persons. Due to an increase in population and changes in lifestyle, the quantity and quality of MSW in Rasht city has changed. Lack of resources, infrastructure, suitable planning, leadership, and public awareness are the main challenges of MSW management of Rasht city. However, the present situation of solid waste management in this city, which generates more than 400tons/d, has been improved since the establishment of an organization responsible only for solid waste management. Source separation of wastes and construction of a composting plant are the two main activities of the Rasht Municipality in recent years.

Solid wastes from nuclear power production.

PubMed Central

Soule, H F

1978-01-01

Radioactivity in nuclear power effluents is negligible compared to that in retained wastes to be disposed of as solids. Two basic waste categories are those for which shallow disposal is accepted and those for which more extreme isolation is desired. The latter includes "high level" wastes and others contaminated with radionuclides with the unusual combined properties of long radioactive half-life and high specific radiotoxicity. The favored method for extreme isolation is emplacement in a deep stable geologic formation. Necessary technologies for waste treatment and disposal are considered available. The present program to implement these technologies is discussed, including the waste management significance of current policy on spent nuclear fuel reprocessing. Recent difficulties with shallow disposal of waste are summarized. PMID:738244

DEMONSTRATION BULLETIN: THE PLASMA CENTRIFUGAL FURNACE RETECH, INC.

EPA Science Inventory

The plasma centrifugal furnace is a thermal technology which uses the heat generated from a plasma torch to decontaminate metal and organic contaminated waste. This is accomplished by melting metal-bearing solids and, in the process, thermally destroying organic contaminants. The...

Techno-Economic Assessment of Recycling BOF Offgas Cleaning System Solid Wastes by Using Zinc-Free Scrap

NASA Astrophysics Data System (ADS)

Ma, Naiyang

High zinc concentration in basic oxygen furnace (BOF) steelmaking offgas (OG) cleaning system solid wastes is one of the main barriers for recycling of the solid wastes in sintering — blast furnace ironmaking process. One of the possible solutions is to utilize zinc-free scrap in BOF steelmaking so that the BOF OG solid wastes will not be contaminated with zinc and can be recycled through sintering — blast furnace ironmaking. This paper describes a model for helping to decide whether to use zinc-free scrap in a BOF process. A model computing marginal price increment of zinc-free scrap is developed. The marginal price increment is proportional to value change of the BOF OG solid wastes after and before using zinc-free scrap, to ratio of BOF solid waste rate to purchased galvanized scrap rate, and to price of galvanized scrap. Due to the variations of consumption rate of purchased galvanized scrap and home galvanized scrap, iron ore price, landfill cost, and price of purchased galvanized scrap, using zinc-free scrap in a BOF process might be economically feasible for some ironmaking and steelmaking plants or in some particular market circumstances.

Interaction between municipal solid waste leachate and Bauru aquifer system: a study case in Brazil.

PubMed

de Faria, Gabriel Messias Moura; Mondelli, Giulliana

2017-12-01

Leachate contamination is a chronic and urgent problem present in municipal solid waste (MSW) landfill. Geochemical mathematical models in this work was suitable to study the dynamics of the leachate from an MSW landfill located in the Midwest of Sao Paulo, Brazil, a region with high precipitation and temperature and rich in chalcophile compounds and lithophile compounds, despite contamination with nitrogenous compounds. After 13 years of local aquifer monitoring, some groundwater samplings in Feb. 2004, Aug. 2007, Nov. 2009, and Feb. 2014 were chosen to be simulated. The hydrolysis is the main process at the landfill, together with absorption, adsorption, complexation, dilution, cation exchange, and oxidation, besides nitrification, reoxidation, and reduction.

ONSITE ENGINEERING REPORT FOR SOLIDIFICATION/ STABILIZATION TREATMENT TESTING OF CONTAMINATED SOILS

EPA Science Inventory

The EPA's Office of Solid Waste and Emergency Response (OSWER) is currently developing land disposal restrictions (LDRs) for contaminated soil and debris (CS&D). The Office of Research and Development, through its Risk Reduction Engineering Laboratory (RREL), is providing support...

Overview of waste stabilization with cement.

PubMed

Batchelor, B

2006-01-01

Cement can treat a variety of wastes by improving physical characteristics (solidification) and reducing the toxicity and mobility of contaminants (stabilization). Potentially adverse waste-binder interactions are an important consideration because they can limit solidification. Stabilization occurs when a contaminant is converted from the dissolved (mobile) phase to a solid (immobile) phase by reactions, such as precipitation, sorption, or substitution. These reactions are often strongly affected by pH, so the presence of components of the waste that control pH are critical to stabilization reactions. Evaluating environmental impacts can be accomplished in a tiered strategy in which simplest approach would be to measure the maximum amount of contaminant that could be released. Alternatively, the sequence of release can be determined, either by microcosm tests that attempt to simulate conditions in the disposal zone or by mechanistic models that attempt to predict behavior using fundamental characteristics of the treated waste.

Organic compounds in re-circulated leachates of aerobic biological treated municipal solid waste.

PubMed

Franke, Matthias; Jandl, Gerald; Leinweber, Peter

2006-10-01

Biodegradation of organic matter is required to reduce the potential of municipal solid waste for producing gaseous emissions and leaching contaminants. Therefore, we studied leachates of an aerobic-treated waste from municipal solids and a sewage sludge mixture that were re-circulated to decrease the concentration of biodegradable organic matter in laboratory-scale reactors. After 12 months, the total organic C and biological and chemical oxygen demands were reduced, indicating the biodegradation of organic compounds in the leachates. Curie-point pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) and pyrolysis-field ionization mass spectrometry (Py-FIMS) revealed that phenols, alkylaromatic compounds, N-containing compounds and carbohydrates were the predominate compounds in the leachates and solid waste. Leachate re-circulation led to a higher thermal stability of the residual organic matter as indicated by temperature-resolved Py-FIMS. Admixture of sewage sludge to solid waste was less effective in removing organic compounds from the leachates. It resulted in drastic higher and more bio-resistant loads of organic matter in the leachates and revealed increased proportions of alkylaromatic compounds. The biodegradation of organic matter in leachates, re-circulated through municipal solid waste, offers the potential for improved aerobic waste treatments and should be investigated on a larger scale.

Characterisation of chemical composition and energy content of green waste and municipal solid waste from Greater Brisbane, Australia.

PubMed

Hla, San Shwe; Roberts, Daniel

2015-07-01

The development and deployment of thermochemical waste-to-energy systems requires an understanding of the fundamental characteristics of waste streams. Despite Australia's growing interest in gasification of waste streams, no data are available on their thermochemical properties. This work presents, for the first time, a characterisation of green waste and municipal solid waste in terms of chemistry and energy content. The study took place in Brisbane, the capital city of Queensland. The municipal solid waste was hand-sorted and classified into ten groups, including non-combustibles. The chemical properties of the combustible portion of municipal solid waste were measured directly and compared with calculations made based on their weight ratios in the overall municipal solid waste. The results obtained from both methods were in good agreement. The moisture content of green waste ranged from 29% to 46%. This variability - and the tendency for soil material to contaminate the samples - was the main contributor to the variation of samples' energy content, which ranged between 7.8 and 10.7MJ/kg. The total moisture content of food wastes and garden wastes was as high as 70% and 60%, respectively, while the total moisture content of non-packaging plastics was as low as 2.2%. The overall energy content (lower heating value on a wet basis, LHVwb) of the municipal solid waste was 7.9MJ/kg, which is well above the World Bank-recommended value for utilisation in thermochemical conversion processes. Copyright © 2015 Elsevier Ltd. All rights reserved.

Environmental aspects of lunar helium-3 mining

NASA Technical Reports Server (NTRS)

Kulcinski, G. L.; Cameron, E. N.; Carrier, W. D., III; Schmitt, H. H.

1992-01-01

Three potential detrimental effects of lunar He-3 mining have been identified; visual changes, atmospheric contamination, and solid waste disposal. The removal of small craters (less than 20 m diameter) and the change in the albedo of the surface may cause a slight darkening of the regolith. However, it is not expected that this change will be visible from the earth even with powerful telescopes. The release of lunar volatile gases and their effect on the lunar 'atmosphere' is expected to be both local and temporary (on the order of a few weeks from the time of release). The solution to solid waste disposal is to recycle as much as possible and to bury the nonrecyclable waste. The lack of wind and water means that the waste will stay localized indefinitely and cause no contamination of the environment. The positive benefits of using lunar He-3 in terrestrial fusion plants far outweigh the detrimental effects of mining. The reduction in radioactive waste, greenhouse and acid gases, and the reduction in terrestrial mining for fossil fuels could have a major impact on the quality of life in the 21st century.

Municipal solid waste management in Rasht City, Iran

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alavi Moghadam, M.R.; Mokhtarani, N.; Mokhtarani, B.

2009-01-15

Pollution and health risks generated by improper solid waste management are important issues concerning environmental management in developing countries. In most cities, the use of open dumps is common for the disposal of wastes, resulting in soil and water resource contamination by leachate in addition to odors and fires. Solid waste management infrastructure and services in developing countries are far from achieving basic standards in terms of hygiene and efficient collection and disposal. This paper presents an overview of current municipal solid waste management in Rasht city, Gilan Province, Iran, and provides recommendations for system improvement. The collected data ofmore » different MSW functional elements were based on data from questionnaires, visual observations of the authors, available reports and several interviews and meetings with responsible persons. Due to an increase in population and changes in lifestyle, the quantity and quality of MSW in Rasht city has changed. Lack of resources, infrastructure, suitable planning, leadership, and public awareness are the main challenges of MSW management of Rasht city. However, the present situation of solid waste management in this city, which generates more than 400 tons/d, has been improved since the establishment of an organization responsible only for solid waste management. Source separation of wastes and construction of a composting plant are the two main activities of the Rasht Municipality in recent years.« less

One-dimensional Spatial Distributions of Gamma-ray Emitting Contaminants in Field Lysimeters Using a Collimated Gamma-ray Spectroscopy System.

PubMed

Erdmann, Bryan J; Powell, Brian A; Kaplan, Daniel I; DeVol, Timothy A

2018-05-01

One-dimensional scans of gamma-ray emitting contaminants were conducted on lysimeters from the RadFLEX facility at the Savannah River Nationals Laboratory (SRNL). The lysimeters each contained a contamination source that was buried in SRNL soil. A source consisted of Cs, Co, Ba, and Eu incorporated either into a solid waste form (Portland cement and reducing grout) or applied to a filter paper for direct soil exposure. The lysimeters were exposed to natural environmental conditions for 3 to 4 y. The initial contaminant activities range from 4.0 to 9.0 MBq for the solid wasteforms and 0.25 to 0.47 MBq for the soil-incorporated source. The measurements were performed using a collimated high-purity germanium gamma-ray spectrometer with a spatial resolution of 2.5 mm. These scans showed downward mobility of Co and Ba when the radionuclides were incorporated directly into the SRNL soil. When radionuclides were incorporated into the solid waste forms positioned in the SRNL soil, Cs exhibited both upward and downward dispersion while the other radionuclides showed no movement. This dispersion was more significant for the Portland cement than the reducing grout wasteform. Europium-152 was the only radionuclide of those studied that showed no movement within the spatial resolution of the scanner from the original placement within the lysimeter. Understanding radionuclide movement in the environment is important for developing strategies for waste management and disposal.

INTERPRETATION OF SPLP RESULTS FOR ASSESSING RISK TO GROUNDWATER FROM LAND-APPLIED GRANULAR WASTE

EPA Science Inventory

Scientists and engineers often rely on results from the synthetic precipitation leaching procedure (SPLP) to assess the risk of groundwater contamination posed by the land application of granular solid wastes. The concentrations of pollutants in SPLP leachate can be measured and ...

Water treatment method

DOEpatents

Martin, Frank S.; Silver, Gary L.

1991-04-30

A method for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

Transuranic solid waste management programs. Progress report, July--December 1975

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1976-09-01

Progress is reported for three transuranic solid waste management programs funded at the Los Alamos Scientific Laboratory (LASL) by the Energy Research and Development Administration (ERDA) Division of Fuel Cycle and Production (NFCP). Under the Transuranic Waste Research and Development Program, continued studies have shown the potential attractiveness of fiber drums as an acceptable substitute for the current mild steel storage containers. Various fire retardants have been evaluated, with one indicating significant ability to inhibit fire propagation. Continued radiolysis studies, under laboratory and field conditions, continue to reaffirm earlier LASL results indicating no significant hazard from radiolytic reactions, assuming nomore » change in current allowable loadings. Care must be exercised to differentiate between radiolytic and chemical reactions. Other efforts have identified a modification of chemical processing to reduce the amounts of plutonium requiring retrievable storage. Studies are also in progress to enhance the sensitivity of the LASL MEGAS assay system. The Transuranic-Contaminated Solid Waste Treatment Development Facility building was 72 percent complete as of December 31, 1975, which is in accord with the existing schedule. Procurement of process components is also on schedule. Certain modifications to the facility have been made, and various pre-facility experiments on waste container handling and processing have been completed. The program for the Evaluation of Transuranic-Contaminated Radioactive Waste Disposal Areas continued development of various computer modules for simulation of radionuclide transport within the biosphere. In addition, program staff contributed to an ERDA document on radioactive waste management through the preparation of a report on burial of radioactive waste at ERDA-contractor and commercial sites.« less

Analytic Hierarchy and Economic Analysis of a Plasma Gasification System for Naval Air Station Oceana-Dam Neck

DTIC Science & Technology

2014-08-30

asbestos containing material, pathological wastes, contaminated soils, glass waste, hazardous fly ash, solvents, ceramic waste, incinerator ash, paints...industrial waste into synthetic gas (Syn-Gas) and slag . For this study, the focus will be on the disposal of municipal solid waste. However, there is...Chemical Reactor The two primary by-products resulting from the gasification process are molten slag , which is collected through a portal at the base

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alam, R.; Chowdhury, M.A.I.; Hasan, G.M.J.

Solid waste management (SWM) services have consistently failed to keep up with the vast amount of solid waste produced in urban areas. There is not currently an efficient system in place for the management, storage, collection, and transportation of solid waste. Kathmandu City, an important urban center of South Asia, is no exception. In Kathmandu Metropolitan City, solid waste generation is predicted to be 1091 m{sup 3}/d (245 tons/day) and 1155 m{sup 3}/d (260 tons/day) for the years 2005 and 2006, respectively. The majority (89%) of households in Kathmandu Metropolitan City are willing to segregate the organic and non-organic portionsmore » of their waste. Overall collection efficiency was 94% in 2003. An increase in waste collection occurred due to private sector involvement, the shutdown of the second transfer station near the airport due to local protest, a lack of funding to maintain trucks/equipment, a huge increase in plastic waste, and the willingness of people to separate their waste into separate bins. Despite a substantial increase in total expenditure, no additional investments were made to the existing development plan to introduce a modern disposal system due to insufficient funding. Due to the lack of a proper lining, raw solid waste from the existing dumping site comes in contact with river water directly, causing severe river contamination and deteriorating the quality of the water.« less

40 CFR 227.6 - Constituents prohibited as other than trace contaminants.

Code of Federal Regulations, 2011 CFR

2011-07-01

... included in the applicable marine water quality criteria, bioassay results on the liquid phase of the waste... possibility of danger associated -with their bioaccumulation in marine -organisms. (c) The potential for... of results of bioassays on liquid, suspended particulate, and solid phases of wastes according to...

DEMONSTRATION BULLETIN: X*TRAX MODEL 200 THERMAL DESORPTION SYSTEMS - CHEMICAL WASTE MANAGEMENT, INC.

EPA Science Inventory

The X*TRAX™ Mode! 200 Thermal Desorption System developed by Chemical Waste Management, Inc. (CWM), is a low-temperature process designed to separate organic contaminants from soils, sludges, and other solid media. The X*TRAX™ Model 200 is fully transportable and consists of thre...

Assessment of the environmental impact of landfill sites with open combustion located in arid regions by combined chemical and ecotoxicological studies.

PubMed

Wichmann, H; Kolb, M; Jopke, P; Schmidt, C; Alawi, M; Bahadir, M

2006-12-01

Two different waste disposal sites in Jordan were investigated in order to determine the environmental situation in context with waste disposal techniques. One landfill, located at Marka/Amman, had been closed about 25 years ago and covered with soil. Here, the waste had been actively open combusted and openings in the cover, still emitting smoke, indicated that waste was still smoldering inside the landfill's body. The second disposal site close to Ekeeder/Irbid is still operated. On this ground, the solid waste is not intentionally burned, although spontaneous fires frequently come up. Samples of waste, soil, and entrained dust were collected and analyzed. From the solid samples, respectively, their eluates, sum parameters, ecotoxicological effects as well as contents of elements/heavy metals and organic pollutants (PAH, PCDD/F) were determined. In general, the Ekeeder-samples were low-contaminated. The investigation of the Marka-samples showed higher contamination of the site's center, clearly being influenced by combustion processes. A significant contamination of the landfill's vicinity by its emissions could not be derived from the analytical data. Ecotoxicological investigations, applying a bio-test battery, revealed correlations with the sum parameters but not with the trace pollutants. Thus, the Marka-samples with the highest measured values of sum parameters caused adverse effects on three different test species, whereas other samples from Marka and Ekeeder had small or no effects. The results of these investigations depict the influence of different disposal techniques on the contamination situation of a landfill and they shall contribute to assess the conditions of other disposal sites in (semi)arid regions.

Bacterial community dynamics in surface flow constructed wetlands for the treatment of swine waste.

PubMed

Ibekwe, A M; Ma, J; Murinda, Shelton; Reddy, G B

2016-02-15

Constructed wetlands are generally used for the removal of waste from contaminated water. In the swine production system, wastes are traditionally flushed into an anaerobic lagoon which is then sprayed on agricultural fields. However, continuous spraying of lagoon wastewater on fields can lead to high N and P accumulations in soil or lead to runoff which may contaminate surface or ground water with pathogens and nutrients. In this study, continuous marsh constructed wetland was used for the removal of contaminants from swine waste. Using pyrosequencing, we assessed bacterial composition within the wetland using principal coordinate analysis (PCoA) which showed that bacterial composition from manure influent and lagoon water were significantly different (P=0.001) from the storage pond to the final effluent. Canonical correspondence analysis (CCA) showed that different bacterial populations were significantly impacted by ammonium--NH4 (P=0.035), phosphate--PO4(3-) (P=0.010), chemical oxygen demand--COD (P=0.0165), total solids--TS (P=0.030), and dissolved solids--DS (P=0.030) removal, with 54% of the removal rate explained by NH4+PO4(3-) according to a partial CCA. Our results showed that different bacterial groups were responsible for the composition of different wetland nutrients and decomposition process. This may be the major reason why most wetlands are very efficient in waste decomposition. Published by Elsevier B.V.

Virus occupational exposure in solid waste processing facilities.

PubMed

Carducci, Annalaura; Federigi, Ileana; Verani, Marco

2013-11-01

It is well known that workers involved in the management of solid waste are at risk of exposure to bioaerosol, which is generally studied in relation to bacteria, fungi, and endotoxins. However, to date, there have been no reports on the incidence of work-related infectious diseases. To determine if occupational exposure to viruses occurs upon exposure to waste-related activities, monitoring was carried out in a landfill, a waste recycling plant, an incineration plant, and a waste collection vehicles. Air and surfaces were sampled and analyzed for torque teno virus (TTV), human adenovirus (HAdV), norovirus, rotavirus, and enterovirus using polymerase chain reaction (PCR)-based techniques. Positivity was confirmed by sequencing and quantification with real-time PCR; infectivity was also tested for culturable viruses. Samples were analyzed in parallel for mean total bacterial and fungi counts in both the summer and winter. In total, 30% (12/40) of air and 13.5% (5/37) of surface samples collected in plants were positive for HAdV and TTV. Among the eight HAdV-positive samples, six (75%), revealed in landfill and recycling plant air and in incinerator and waste vehicles surfaces, were able to replicate in cell culture and were subsequently confirmed as infective. The frequency of detection of virus-positive samples was similar in both seasons, but with evident differences in the type of virus detected: TTV and HAdV were more frequently detected in the summer and winter, respectively. The area of highest viral contamination was the paper selection landfill. Fungi and bacterial contamination did not correlate with viral presence or concentration. In conclusion, we evidence that working with solid and liquid waste can lead to infectious viruses, included in Group 2 of the European Directive 90/679/CEE pathogens list; thus, further investigation on the sources and routes of contamination is needed in order to assess the occupational risk.

Integrated Management of all Historical, Operational and Future Decomissioning Solid ILW at Dounreay

DOE Office of Scientific and Technical Information (OSTI.GOV)

Graham, D.

This paper describes major components of the Dounreay Site Restoration Plan, DSRP to deal with the site's solid intermediate level waste, ILW legacy. Historic solid ILW exists in the Shaft (disposals between 1959 and 1977), the Wet Silo (operated between 1973 and 1998), and in operating engineered drummed storage. Significant further arisings are expected from future operations, post-operations clean out and decommissioning through to the completion of site restoration, expected to be complete by about 2060. The raw waste is in many solid forms and also incorporates sludge, some fissile material and hazardous chemical components. The aim of the Solidmore » ILW Project is to treat and condition all this waste to make it passively safe and in a form which can be stored for a substantial period, and then transported to the planned U.K. national deep repository for ILW disposal. The Solid ILW Project involves the construction of head works for waste retrieval operations at the Shaft and Wet Silo, a Waste Treatment Plant and a Conditioned Waste Store to hold the conditioned waste until the disposal facilities become available. In addition, there are infrastructure activities to enable the new construction: contaminated ground remediation, existing building demolition, underground and overground services diversion, sea cliff stabilization, and groundwater isolation at the Shaft.« less

Water treatment method

DOEpatents

Martin, F.S.; Silver, G.L.

1991-04-30

A method is described for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

Case studies in organic contaminant hydrogeology

NASA Astrophysics Data System (ADS)

Baker, John A.

1989-07-01

The effective management of domestic solid waste and hazardous, toxic, and radioactive waste is a major problem in the area of environmental geology and water sciences over the world. This series of case studies of organic contaminants from both solid and hazardous waste disposal facilities provides examples of these problems. The facilities were investigated to determine risks and liabilities before acquisition, to determine the site hydrogeologic conditions for design of appropriate groundwater monitoring plans, and/or to determine the potential for groundwater contamination. The results of these studies and investigations by Waste Management Inc. (WMI) and its consultants have shown certain relationships in the distribution of organic pollutants to the different geologic and hydrogeologic charac teristics of each facility. In each of the case studies, all 129 priority pollutants were analyzed in private wells and/or monitoring wells at the request of regulatory agencies. The 31 volatile organic compounds (VOCs) of the priority pollutant list were the majority of the organic compounds detected and these data are evaluated in each case study. The case studies are on disposal facilities located in glacial tills, carbonaceous weathered clay soils, weathered shale, limestone bedrock, dolomite bedrock, and alluvial and sedimentary deposits. A brief discussion of groundwater quality impacts and remedial measures also is included.

Outpatient radioiodine therapy for thyroid cancer: a safe nuclear medicine procedure.

PubMed

Willegaignon, José; Sapienza, Marcelo; Ono, Carla; Watanabe, Tomoco; Guimarães, Maria Inês; Gutterres, Ricardo; Marechal, Maria Helena; Buchpiguel, Carlos

2011-06-01

To evaluate the dosimetric effect of outpatient radioiodine therapy for thyroid cancer in members of a patient's family and their living environment, when using iodine-131 doses reaching 7.4 GBq. The following parameters were thus defined: (a) whole-body radiation doses to caregivers, (b) the production of contaminated solid waste, and (c) radiation potential and surface contamination within patients' living quarters. In total, 100 patients were treated on an outpatient basis, taking into consideration their acceptable living conditions, interests, and willingness to comply with medical and radiation safety guidelines. Both the caregivers and the radiation dose potentiality inside patients' residences were monitored by using thermoluminescent dosimeters. Surface contamination and contaminated solid wastes were identified and measured with a Geiger-Müller detector. A total of 90 monitored individuals received a mean dose of 0.27 (±0.28) mSv, and the maximum dose registered was 1.6 mSv. The mean value for the potential dose within all living quarters was 0.31 (±0.34) mSv, and the mean value per monitored surface was 5.58 Bq/cm(2) for all the 1659 points measured. The overall production of contaminated solid wastes was at a low level, being about 3 times less than the exemption level indicated by the International Atomic Energy Agency. This study indicates that the treatment of thyroid cancer by applying radioiodine activities up to 7.4 GBq, on an outpatient basis, is a safe procedure, especially when supervised by qualified professionals. This alternative therapy should be a topic for careful discussion considering the high potential for reducing costs in healthcare and improving patient acceptance.

RCRA Facility Investigation report for Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Volume 2. Sections 4 through 9

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1991-09-01

This report presents compiled information concerning a facility investigation of waste area group 6(WAG-6), of the solid waste management units (SWMU's) at Oak Ridge National Laboratory (ORNL). The WAG is a shallow ground disposal area for low-level radioactive wastes and chemical wastes. The report contains information on hydrogeological data, contaminant characterization, radionuclide concentrations, risk assessment and baseline human health evaluation including a toxicity assessment, and a baseline environmental evaluation.

Experimental evaluation of coal conversion solid waste residuals. Progress report, August 1-October 31, 1979

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neufeld, R. D.; Bern, J.; Erdogan, H.

1979-11-15

Activities are underway to investigate basic phenomena that would assist demonstration and commercial sized coal conversion facilities in the environmentally acceptable disposal of process solid waste residuals. The approach taken is to consider only those residuals coming from the conversion technology itself, i.e. from gasification, liquefaction, and hot-clean-up steps as well as residuals from the wastewater treatment train. Residuals from the coal mining and coal grinding steps will not be considered in detail since those materials are being handled in some manner in the private sector. Laboratory evalations have been conducted on solid waste samples of fly ash from anmore » existing Capman gasifier. ASTM-A and EPA-EP leaching procedures have been completed on sieved size fractions of the above wastes. Data indicate that smaller size fractions pose greater contamination potential than do larger size particles with a transition zone occurring at particle sizes of about 0.05 inches in diameter. Ames testing of such residuals is reported. Similar studies are under way with samples of H-Coal solid waste residuals.« less

Environmental risk assessment of the use of different organic wastes as soil amendments

NASA Astrophysics Data System (ADS)

Alvarenga, Paula; Palma, Patrícia; Mourinha, Clarisse; Farto, Márcia; Cunha-Queda, Ana Cristina; Natal-da-Luz, Tiago; Sousa, José Paulo

2013-04-01

The use of organic wastes in agriculture is considered a way of maintaining or restoring the quality of soils, enlarging the slow cycling soil organic carbon pool. However, a wide variety of undesired substances, such as potentially trace elements and organic contaminants, can have adverse effects on the environment. That fact was highlighted by the Proposal for a Soil Framework Directive, which recognized that "soil degradation or soil improvements have a major impact on other areas, (…) such as surface waters and groundwater, human health, climate change, protection of nature and biodiversity, and food safety". Taking that into account, the research project "ResOrgRisk" aims to assess the environmental risk involved in the use of different organic wastes as soil amendments, evidencing their benefits and constraints, and defining the most suitable tests to reach such assessment. The organic wastes selected for this purpose were: sewage sludge, limed, not limed, and co-composted with agricultural wastes, agro-industrial sludge, mixed municipal solid waste compost, compost produced from organic farming residues, and pig slurry digestate. Whereas threshold values for heavy metals in sludge used for agriculture have been set by the European Commission, actually there is no definitive European legislation for organic contaminants. Guide values for some organic contaminants (e.g. polychlorinated biphenyls - PCBs, and polycyclic aromatic hydrocarbons - PAHs) have been adopted at national level by many European countries, such as Portugal. These values should be taken into account when assessing the risk involved in the use of organic wastes as soil amendments. However, chemical analysis of organic waste often gives scarce information because it does not include possible interactions between chemicals. Furthermore, an exhaustive identification and quantification of all substances is impractical. In this study, ecotoxicological tests (comprising solid and aquatic phases) were performed to obtain an integrated assessment on the effects of all contaminants from each organic waste, as a whole, to terrestrial systems. The results for the chemical and ecotoxicological characterization of the organic wastes selected in this study will be discussed, emphasizing the potential benefits and the risks of their use as soil amendments.

Cytogenetic effects of leachates from tannery solid waste on the somatic cells of Vicia faba.

PubMed

Chandra, Saurabh; Chauhan, L K S; Pande, P N; Gupta, S K

2004-04-01

The contamination of surface- and groundwater by the leaching of solid wastes generated by industrial activities as a result of water runoff and rainfall is a matter of great concern. The leachates from tannery solid waste (TSW), a major environmental pollutant, were examined for their possible genotoxic effects on the somatic cells of Vicia faba. Leachates were prepared from solid wastes procured from leather-tanning industrial sites, and V. faba seedlings were exposed to three test concentrations, 2.5%, 5%, and 10%, through soil and aqueous media for 5 days. The root tips examined for cytogenetic damage revealed that leachate of TSW significantly inhibited the mitotic index and induced significantly frequent chromosomal and mitotic aberrations (CA/MA) in a dose-dependent manner. The chemical analysis of TSW samples revealed that the chief constituents were chromium and nickel, which may cause genetic abnormalities. The frequency of aberrations was found to be higher in the root meristematic cells of Vicia faba exposed through the aqueous medium than those exposed through the soil medium. The results of the present study indicated that contamination of potable water bodies by leachates of TSW may cause genotoxicity. For the biomonitoring of complex mixtures of toxicants with the V. faba bioassay, the use of the aqueous medium seems to be a more promising method than the use of the soil medium. Copyright 2004 Wiley Periodicals, Inc. Environ Toxicol 19: 129-133, 2004.

Acute and Chronic Toxicity of Soluble Fractions of Industrial Solid Wastes on Daphnia magna and Vibrio fischeri

PubMed Central

Flohr, Letícia; de Castilhos Júnior, Armando Borges; Matias, William Gerson

2012-01-01

Industrial wastes may produce leachates that can contaminate the aquatic ecosystem. Toxicity testing in acute and chronic levels is essential to assess environmental risks from the soluble fractions of these wastes, since only chemical analysis may not be adequate to classify the hazard of an industrial waste. In this study, ten samples of solid wastes from textile, metal-mechanic, and pulp and paper industries were analyzed by acute and chronic toxicity tests with Daphnia magna and Vibrio fischeri. A metal-mechanic waste (sample MM3) induced the highest toxicity level to Daphnia magna(CE50,48 h = 2.21%). A textile waste induced the highest toxicity level to Vibrio fischeri (sample TX2, CE50,30 min = 12.08%). All samples of pulp and paper wastes, and a textile waste (sample TX2) induced chronic effects on reproduction, length, and longevity of Daphnia magna. These results could serve as an alert about the environmental risks of an inadequate waste classification method. PMID:22619632

Acute and chronic toxicity of soluble fractions of industrial solid wastes on Daphnia magna and Vibrio fischeri.

PubMed

Flohr, Letícia; de Castilhos Júnior, Armando Borges; Matias, William Gerson

2012-01-01

Industrial wastes may produce leachates that can contaminate the aquatic ecosystem. Toxicity testing in acute and chronic levels is essential to assess environmental risks from the soluble fractions of these wastes, since only chemical analysis may not be adequate to classify the hazard of an industrial waste. In this study, ten samples of solid wastes from textile, metal-mechanic, and pulp and paper industries were analyzed by acute and chronic toxicity tests with Daphnia magna and Vibrio fischeri. A metal-mechanic waste (sample MM3) induced the highest toxicity level to Daphnia magna(CE(50,48 h) = 2.21%). A textile waste induced the highest toxicity level to Vibrio fischeri (sample TX2, CE(50,30 min) = 12.08%). All samples of pulp and paper wastes, and a textile waste (sample TX2) induced chronic effects on reproduction, length, and longevity of Daphnia magna. These results could serve as an alert about the environmental risks of an inadequate waste classification method.

Integral recycling of municipal solid waste incineration (MSWI) bottom ash fines (0-2mm) and industrial powder wastes by cold-bonding pelletization.

PubMed

Tang, P; Brouwers, H J H

2017-04-01

The cold-bonding pelletizing technique is applied in this study as an integrated method to recycle municipal solid waste incineration (MSWI) bottom ash fines (BAF, 0-2mm) and several other industrial powder wastes. Artificial lightweight aggregates are produced successfully based on the combination of these solid wastes, and the properties of these artificial aggregates are investigated and then compared with others' results reported in literature. Additionally, methods for improving the aggregate properties are suggested, and the corresponding experimental results show that increasing the BAF amount, higher binder content and addition of polypropylene fibres can improve the pellet properties (bulk density, crushing resistance, etc.). The mechanisms regarding to the improvement of the pellet properties are discussed. Furthermore, the leaching behaviours of contaminants from the produced aggregates are investigated and compared with Dutch environmental legislation. The application of these produced artificial lightweight aggregates are proposed according to their properties. Copyright © 2017 Elsevier Ltd. All rights reserved.

Opportunities for Cost Effective Disposal of Radioactively Contaminated Solid Waste on the Oak Ridge Reservation, Oak Ridge, TN - 13045

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeMonia, Brian; Dunning, Don; Hampshire John

2013-07-01

Department of Energy (DOE) requirements for the release of non-real property, including solid waste, containing low levels of residual radioactive materials are specified in DOE Order 458.1 and associated guidance. Authorized limits have been approved under the requirements of DOE Order 5400.5, predecessor to DOE Order 458.1, to permit disposal of solid waste containing low levels of residual radioactive materials at solid waste landfills located within the DOE Oak Ridge Reservation (ORR). Specifically, volumetric concentration limits for disposal of solid waste at Industrial Landfill V and at Construction/Demolition Landfill VII were established in 2003 and 2007, respectively, based on themore » requirements in effect at that time, which included: an evaluation to ensure that radiation doses to the public would not exceed 25 mrem/year and would be as low as reasonably achievable (ALARA), with a goal of a few mrem/year or less (in fact, these authorized limits actually were derived to meet a dose constraint of 1 mrem/year); an evaluation of compliance with groundwater protection requirements; and reasonable assurance that the proposed disposal is not likely to result in a future requirement for remediation of the landfill. Prior to approval as DOE authorized limits, these volumetric concentration limits were coordinated with the Tennessee Department of Environment and Conservation (TDEC) and documented in a Memorandum of Understanding (MOU) between the TDEC Division of Radiological Health and the TDEC Division of Solid Waste Management. These limits apply to the disposal of soil and debris waste generated from construction, maintenance, environmental restoration, and decontamination and decommissioning (D and D) activities on the DOE Oak Ridge Reservation. The approved site-specific authorized limits were incorporated in the URS/CH2M Oak Ridge LLC (UCOR) waste profile system that authorizes disposal of special wastes at either of the RCRA Subtitle D landfills. However, a recent DOE assessment found that implementation of the site-specific authorized limits for volumetrically contaminated waste was potentially limited due in part to confusion regarding the applicability of volumetric concentration limits and/or surface activity limits to specific wastes. This paper describes recent efforts to update the authorized limits for Industrial Landfill V and Construction/Demolition Landfill VII and to improve the procedures for implementation of these criteria. The approved authorized limits have been evaluated and confirmed to meet the current requirements of DOE Order 458.1, which superseded DOE Order 5400.5 in February 2011. In addition, volumetric concentration limits have been developed for additional radionuclides, and site-specific authorized limits for wastes with surface contamination have been developed. Implementing procedures have been revised to clarify the applicability of volumetric concentration limits and surface activity limits, and to allow the use of non-destructive waste characterization methods. These changes have been designed to promote improved utilization of available disposal capacity of the onsite disposal facilities within the DOE Oak Ridge Reservation. In addition, these changes serve to bring the waste acceptance requirements at these DOE onsite landfills into greater consistency with the requirements for commercial/ public landfills under the TDEC Bulk Survey for Release (BSFR) program, including two public RCRA Subtitle D landfills in close proximity to the DOE Oak Ridge Reservation. (authors)« less

Integrated geophysical characterisation of Sunyani municipal solid waste disposal site using magnetic gradiometry, magnetic susceptibility survey and electrical resistivity tomography

NASA Astrophysics Data System (ADS)

Appiah, Isaac; Wemegah, David Dotse; Asare, Van-Dycke Sarpong; Danuor, Sylvester K.; Forson, Eric Dominic

2018-06-01

Non-invasive geophysical investigation using magnetic gradiometry, magnetic susceptibility survey and electrical resistivity tomography (ERT) was carried out on the Sunyani Municipal Assembly (SMA) solid waste disposal (SWD) site. The study was aimed at delineating the physical boundaries and the area extent of the waste deposit, mapping the distribution of the waste at the site, detecting and delineating zones of leachate contamination and its preferential migration pathways beneath the waste deposit and its surroundings. The results of both magnetic susceptibility and gradiometric methods displayed in anomaly maps clearly delineated the physical boundaries of the waste deposit with an approximate area extent of 82,650 m2 that are characterised by high magnetic susceptibilities between 426 × 10-5 SI and 9890 × 10-5 SI. They also revealed high magnetic anomalies erratically distributed within the waste deposit attributable to its heterogeneous and uncontrolled nature. The high magnetic anomalies outside the designated waste boundaries were also attributed to indiscriminate deposition of the waste. Similarly, the ERT sections delineated and characterised zones of leachate contamination beneath the waste body and its close surroundings as well as pathways for leachate migration with low resistivity signatures up to 43.9 Ωm. In spite of the successes reported herein using the ERT, this research also revealed that the ERT is less effective in estimating the thickness of the waste deposit in unlined SWD sites due to leachate infiltration into the ground beneath it that masks the resistivities of the top level ground and makes it indistinguishable from the waste body.

Research and Development of a New Waste Collection Bin to Facilitate Education in Plastic Recycling

ERIC Educational Resources Information Center

Chow, Cheuk-fai; So, Wing-Mui Winnie; Cheung, Tsz-Yan

2016-01-01

Plastic recycling has been an alternative method for solid waste management apart from landfill and incineration. However, recycling quality is affected when all plastics are discarded into a single recycling bin that increases cross contaminations and operation cost to the recycling industry. Following the engineering design process, a new…

RCRA Facility Investigation report for Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Volume 3. Appendixes 1 through 8

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1991-09-01

This report presents compiled information concerning a facility investigation of waste area group 6(WAG-6), of the solid waste management units (SWMU'S) at Oak Ridge National Laboratory (ORNL). The WAG is a shallow ground disposal area for low-level radioactive wastes and chemical wastes. The report contains information on hydrogeological data, contaminant characterization, radionuclide concentrations, risk assessment from doses to humans and animals and associated cancer risks, exposure via food chains, and historical data. (CBS)

Superfund record of decision (EPA Region 2): Hercules Incorporated (Gibbstown Plant), Solid Waste Disposal Area, Operable Unit 3, Greenwich Township, Gloucester County, NJ, January 22, 1966

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-10-01

This decision document presents the selected remedial action for the Solid Waste Disposal Area (SWDA) - Operable Unit 3, Hercules Incorporated, Higgins Plant (hereinafter Hercules site or site), in Greenwhich Township, Gloucester County, New Jersey. The Record of Decision (ROD) addresses all contaminated media at the SWDA portion of the site including soil and ground water. The selected remedy is a modified version of the `In-Place Containment` remedy of the Porposed Plan.

Stabilization/solidification of an alkyd paint waste by carbonation of waste-lime based formulations.

PubMed

Arce, R; Galán, B; Coz, A; Andrés, A; Viguri, J R

2010-05-15

The application of solvent-based paints by spraying in paint booths is extensively used in a wide range of industrial activities for the surface treatment of a vast array of products. The wastes generated as overspray represent an important environmental and managerial problem mainly due to the hazardous characteristics of the organic solvent, rendering it necessary to appropriately manage this waste. In this paper a solidification/stabilization (S/S) process based on accelerated carbonation was investigated as an immobilization pre-treatment prior to the disposal, via landfill, of an alkyd solvent-based paint waste coming from the automotive industry; the purpose of this S/S process was to immobilize the contaminants and reduce their release into the environment. Different formulations of paint waste with lime, lime-coal fly-ash and lime-Portland cement were carbonated to study the effect of the water/solid ratio and carbonation time on the characteristics of the final product. To assess the efficiency of the studied S/S process, metals, anions and dissolved organic carbon (DOC) were analyzed in the leachates obtained from a battery of compliance and characterization leaching tests. Regarding the carbonation of paint waste-lime formulations, a mathematical expression has been proposed to predict the results of the leachability of DOC from carbonated mixtures working at water/solid ratios from 0.2 to 0.6. However, lower DOC concentrations in leachates (400mg/kg DOC in L/S=10 batch leaching test) were obtained when carbonation of paint waste-lime-fly-ash mixtures was used at 10h carbonation and water to solid ratio of 0.2. The flammability characteristics, the total contents of contaminants and the contaminant release rate in compliance leaching tests provide evidence for a final product suitable for deposition in non-hazardous landfills. The characterization of this carbonated sample using a dynamic column leaching test shows a high stabilization of metals, partial immobilization of Cl(-), SO(4)(2-), F(-) and limited retention of DOC. However, the obtained results improve the previous findings obtained after the paint waste S/S using uncarbonated formulations and would be a useful pre-treatment technique of the alkyd paint waste prior to its disposal in a landfill. Copyright (c) 2009 Elsevier B.V. All rights reserved.

75 FR 18550 - Notice of Lodging of Consent Decree Under the Comprehensive Environmental Response, Compensation...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-12

..., and calls for covering contaminated soil at OU3 with a cap that complies with Ohio solid waste... soil and soil vapor; and a combination of dredging, off- site disposal and/or capping of contaminated.... Comments should be addressed to the Assistant Attorney General, Environment and Natural [[Page 18551...

Investigation of Contaminated Ground Water at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina, 2006-2007

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.; Lowery, Mark A.; Conlon, Kevin J.; Harrelson, Larry G.

2008-01-01

The U.S. Geological Survey investigated natural and engineered remediation of chlorinated volatile organic compound (VOC) ground-water contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina, beginning in 2000. The primary contaminants of interest in the study are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. The permeable reactive barrier (PRB) along the main axis of the contaminant plume appears to be actively removing contamination. In contrast to the central area of the PRB, the data from the southern end of the PRB indicate that contaminants are moving around the PRB. Concentrations in wells 12MW-10S and 12MW-03S, upgradient from the PRB, showed a general decrease in VOC concentrations. VOC concentrations in some wells in the forest showed a sharp increase, followed by a decrease. In 2007, the VOC concentrations began to increase in well 12MW-12S, downgradient from the PRB and thought to be unaffected by the PRB. The VOC-concentration changes in the forest, such as at well 12MW-12S, may represent lateral shifting of the plume in response to changes in ground-water-flow direction or may represent movement of a contamination pulse through the forest.

Understanding Our Energy Footprint: Undergraduate Chemistry Laboratory Investigation of Environmental Impacts of Solid Fossil Fuel Wastes

ERIC Educational Resources Information Center

Berger, Michael; Goldfarb, Jillian L.

2017-01-01

Engaging undergraduates in the environmental consequences of fossil fuel usage primes them to consider their own anthropogenic impact, and the benefits and trade-offs of converting to renewable fuel strategies. This laboratory activity explores the potential contaminants (both inorganic and organic) present in the raw fuel and solid waste…

Bioremediation of oil-contaminated soil using Candida catenulata and food waste.

PubMed

Joo, Hung-Soo; Ndegwa, Pius M; Shoda, Makoto; Phae, Chae-Gun

2008-12-01

Even though petroleum-degrading microorganisms are widely distributed in soil and water, they may not be present in sufficient numbers to achieve contaminant remediation. In such cases, it may be useful to inoculate the polluted area with highly effective petroleum-degrading microbial strains to augment the exiting ones. In order to identify a microbial strain for bioaugmentation of oil-contaminated soil, we isolated a microbial strain with high emulsification and petroleum hydrocarbon degradation efficiency of diesel fuel in culture. The efficacy of the isolated microbial strain, identified as Candida catenulata CM1, was further evaluated during composting of a mixture containing 23% food waste and 77% diesel-contaminated soil including 2% (w/w) diesel. After 13 days of composting, 84% of the initial petroleum hydrocarbon was degraded in composting mixes containing a powdered form of CM1 (CM1-solid), compared with 48% of removal ratio in control reactor without inoculum. This finding suggests that CM1 is a viable microbial strain for bioremediation of oil-contaminated soil with food waste through composting processes.

Health risk assessment as an approach to manage an old landfill and to propose integrated solid waste treatment: A case study in Italy.

PubMed

Paladino, O; Massabò, M

2017-10-01

The aim of the present paper is to show how an approach based on human health risk analysis can be used as a decisional tool for the evaluation of impacts on population and for deciding between different waste treatment processes. The situation in which the increasing production of solid wastes cannot be confined in the old existing Municipal Solid Waste landfill (settled in Genoa, Liguria Region, Italy) is used as a case study. Risk assessment for human health due to air, surface water, groundwater and soil contamination is performed in different scenarios for the old landfill and compared with alternative Waste-to-Energy management solutions that consider thermal treatment by gasification of the total waste or gasification of the dry fraction coupled with anaerobic digestion of the wet fraction, plus biogas combustion with or without sludge and bottom ash/slag disposal in the old landfill. Hazard Index (HI) and Cancer Risk (CR) in case of operating landfill and under the suspected situation of failure of the sealing system, were respectively 1.15 and 1.1∗10 -7 . Unacceptable HI were found due to groundwater contamination, while HI due to river pollution was slightly under the threshold. Vegetables ingestion was the most important pathway and ammonia the most responsible of toxic adverse effects. Fish ingestion and dermal contact with contaminated water were found to be the most important exposure pathways for carcinogenic risk, due mainly to BTEX. HI and CR in the supposed scenario of total waste gasification were respectively 9.4∗10 -1 and 1.1∗10 -5 while they were respectively 3.2∗10 -1 and 6∗10 -6 in case of gasification of the dry fraction. CR in both scenarios was over the threshold mainly due to dioxins, where milk and meat ingestion were found to be the highest risk pathways. Inhalation resulted as the highest not-carcinogenic risk exposure pathway, mainly due to NOx. Decision making was made by weighing up the different scenarios, and results suggested to definitively close the landfill and to eliminate gasification of the total waste as a possible waste treatment process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Passive PE Sampling in Support of In Situ Remediation of Contaminated Sediments

DTIC Science & Technology

2015-08-01

elements: • Expendable items: including materials such as stainless steel mixing bowls/spoons, decontamination supplies (buckets, brushes, distilled...PE samplers. Traditional sediment sampling equipment would include items such as decontamination fluids, stainless steel mixing bowls and spoons...hazardous/hazardous wastes (excess sediment, decontamination fluids). There is not expected to be a big difference in solid waste disposal costs

Hazardous Waste Minimization Assessment: Fort Carson, CO

DTIC Science & Technology

1991-01-01

microorganisms ( bacteria , fungi, etc.) to decompose and/or bioaccumulate the contaminants in wastes. As a HAZMIN technique, treatment, unlike source...Water is analyzed for fecal coliform bacteria , residual chlorine, 5-day biochemical oxygen demand (BOD5), suspended solids (SS), chemical oxygen demand...manufacturer Kinsbursky Bros. Supply (714) 738-8516 North Lemon Street Recycler, Spent batteries X Anaheim, CA 92801 Lubrication Co. of America (213

U.S. ENVIRONMENTAL PROTECTION AGENCY RESEARCH AND TECHNICAL SUPPORT NEEDS RELATED TO CONCEPTUAL MODEL DEVELOPMENT FOR SUBSURFACE REACTIVE TRANSPORT MODELING OF INORGANIC CONTAMINANTS, RADIONUCLIDES, AND NUTRIENTS

EPA Science Inventory

EPA's Office of Research and Development is responsible to EPA's Office of Solid Waste to provide research and technical support for waste site closures and the development of technical guidance in support of environmental regulations and programmatic policies. ORD is also respo...

TRIBAL LEADERS ENVIRONMENTAL SUMMIT

EPA Science Inventory

This annual conference includes general and breakout sessions relating to science or environmental management in such areas as solid waste, community planning, environmental education, contaminants, capacity building and more. The October 2000 Tribal Summit was held in Anchorage...

Green remediation and recycling of contaminated sediment by waste-incorporated stabilization/solidification.

PubMed

Wang, Lei; Tsang, Daniel C W; Poon, Chi-Sun

2015-03-01

Navigational/environmental dredging of contaminated sediment conventionally requires contained marine disposal and continuous monitoring. This study proposed a green remediation approach to treat and recycle the contaminated sediment by means of stabilization/solidification enhanced by the addition of selected solid wastes. With an increasing amount of contaminated sediment (20-70%), the 28-d compressive strength of sediment blocks decreased from greater than 10MPa to slightly above 1MPa. For augmenting the cement hydration, coal fly ash was more effective than lime and ground seashells, especially at low sediment content. The microscopic and spectroscopic analyses showed varying amounts of hydration products (primarily calcium hydroxide and calcium silicate hydrate) in the presence of coal fly ash, signifying the influence of pozzolanic reaction. To facilitate the waste utilization, cullet from beverage glass bottles and bottom ashes from coal combustion and waste incineration were found suitable to substitute coarse aggregate at 33% replacement ratio, beyond which the compressive strength decreased accordingly. The mercury intrusion porosimetry analysis indicated that the increase in the total pore area and average pore diameter were linearly correlated with the decrease of compressive strength due to waste replacement. All the sediment blocks complied with the acceptance criteria for reuse in terms of metal leachability. These results suggest that, with an appropriate mixture design, contaminated sediment and waste materials are useful resources for producing non-load-bearing masonry units or fill materials for construction uses. Copyright © 2014 Elsevier Ltd. All rights reserved.

Air modelling as an alternative to sampling for low-level radioactive airborne releases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morgenstern, M.Y.; Hueske, K.

1995-05-01

This paper describes our efforts to assess the effect of airborne releases at one DOE laboratory using air modelling based on historical data. Among the facilities affected by these developments is Los Alamos National Laboratory (LANL) in New Mexico. RCRA, as amended by the Hazardous and Solid Waste Amendments (HSWA) in 1984, requires all facilities which involve the treatment, storage, and disposal of hazardous waste obtain a RCRA/HSWA waste facility permit. LANL complied with CEARP by initiating a process of identifying potential release sites associated with LANL operations prior to filing a RCRA/HSWA permit application. In the process of preparingmore » the RCRA/HSWA waste facility permit application to the U.S. Environmental Protection Agency (EPA), a total of 603 Solid Waste Management Units (SWMUs) were identified as part of the requirements of the HSWA Module VIH permit requirements. The HSWA Module VIII permit requires LANL to determine whether there have been any releases of hazardous waste or hazardous constituents from SWMUs at the facility dating from the 1940`s by performing a RCRA Facility Investigation to address known or suspected releases from specified SWMUs to affected media (i.e. soil, groundwater, surface water, and air). Among the most troublesome of the potential releases sites are those associated with airborne radioactive releases. In order to assess health risks associated with radioactive contaminants in a manner consistent with exposure standards currently in place, the DOE and LANL have established Screening Action Levels (SALs) for radioactive soil contamination. The SALs for each radionuclide in soil are derived from calculations based on a residential scenario in which individuals are exposed to contaminated soil via inhalation and ingestion as well as external exposure to gamma emitters in the soil. The applicable SALs are shown.« less

Environmental projects. Volume 14: Removal of contaminated soil and debris

NASA Technical Reports Server (NTRS)

Kushner, Len

1992-01-01

Numerous diverse activities at the Goldstone Deep Space Communications Complex (GDSCC) are carried out in support of six parabolic dish antennas. Some of these activities can result in possible spills or leakages of hazardous materials and wastes stored both above ground in steel drums and below ground in underground storage tanks (UST's). These possible leaks or spills, along with the past practice of burial of solid debris and waste in trenches and pits, could cause local subsurface contamination of the soil. In 1987, the Jet Propulsion Laboratory (JPL), retained Engineering-Science, Inc. (E-S), Pasadena, California, to identify the specific local areas within the GDSCC with subsurface soil contamination. The E-S study determined that some of the soils at the Apollo Site and the Mars Site were contaminated with hydrocarbons, while soil at a nonhazardous waste dumpsite at the Mojave Base site was contaminated with copper. This volume is a JPL-expanded version of the PE209 E-S report, and it also reports that all subsurface contaminated soils at the GDSCC were excavated, removed, and disposed of in an environmentally acceptable way, and the excavations were backfilled and covered in accordance with accepted Federal, State, and local environmental rules and regulations.

RCRA facility investigation and risk assessment, McAlester Army Ammunition Plant, McAlester, Oklahoma. Supplemental phase 2 RFI report, Solid Waste Management Units 32 and 33

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1994-11-30

This report presents the results of the Supplemental Phase 2 Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) conducted for Solid Waste Management Units (SWMU) Number 32 and Number 33 at McAlester Army Ammunition Plant (MCAAP). The supplemental action of the RFI was conducted as part of the actions required in connection with the application for a RCRA permit for the management of hazardous waste at MCAAP. The objective of this Supplemental Phase 2 RFI is to collect and analyze soil samples from Solid Waste Management Unit (SWMU) 32 and SWMU 33 for dioxins/dibenzofurans. The purpose of this reportmore » is to describe the procedures used to perform the Supplemental Phase 2 RFI to present and assess the results obtained in terms of the nature and extent of any contamination found, to present the results of human health and ecological risk assessments, and to recommend future actions.« less

Mobilization and transport of pollutants in an abandoned dump in tropical conditions

NASA Astrophysics Data System (ADS)

Pelinson, Natalia; Shinzato, Marjolly; Wendland, Edson

2017-04-01

The valuation and treatment techniques of municipal solid waste (MSW) in developing countries are not sufficiently developed, and therefore, the volume of waste destined for disposal still presents significant amounts. In Brazil, the more common practice of final destination is the deposition on the soil, due to its simple operation and low cost compared to other techniques. One of the most serious negative environmental impacts in the irregular disposal of solid waste is the contamination of soil and groundwater by waste leachates. The final disposal in dumps is forbidden by Brazilian law since 2010, nevertheless, the public administration is not prepared to monitor waste disposal areas and the risk of contamination of water. In this sense, a research has been developed in an abandoned dump installed over an outcrop of the Botucatu Formation, which is part of the Guarani Aquifer System (SAG) and therefore, is an area of high water vulnerability. In this dump, an old gully was used as a final waste disposal area for urban, construction and demolition, medical and industrial waste from 1980 to 1996. Since the end of the deposition, the waste body is kept with inefficient hydraulic control. The water infiltration due to rainfall promotes the mobility of contaminant in the deposit. The present water quality in the dump has been monitored through physical and chemical analysis of samples collected in the unsaturated zone (inside the waste mass using vacuum lysimeters) and in the saturated zone (monitoring wells). The rainfall variation observed in the years 2014 (dry year) and 2015 (wet year) contributed significantly to evaluate the mobilization of pollutants within the dump. The reduction of the water volume that infiltrates the waste mass affected the quality of the leachate collected in the lysimeters. The groundwater collected in monitoring wells outside the dump area presents low turbidity values (<1.50 NTU) in relation to wells located downstream of the dump showed values greater than 10, a similar behavior was observed for the conductivity (>1000 µS.cma-1 in leachate) and chlorides values (>800 mg.L-1). Contaminated water flows through the bottom of the dump. In addition, this research also indicates amendments of surface water downstream of the dump area.

Behavior of cesium in municipal solid waste incineration.

PubMed

Oshita, Kazuyuki; Aoki, Hiroshi; Fukutani, Satoshi; Shiota, Kenji; Fujimori, Takashi; Takaoka, Masaki

2015-05-01

As a result of the Fukushima Daiichi Nuclear Power Plant accident on March 11, 2011 in Japan radioactive nuclides, primarily (134)Cs and (137)Cs were released, contaminating municipal solid waste and sewage sludge in the area. Although stabilizing the waste and reducing its volume is an important issue differing from Chernobyl nuclear power plant accident, secondary emission of radioactive nuclides as a result of any intermediate remediation process is of concern. Unfortunately, there is little research on the behavior of radioactive nuclides during waste treatment. This study focuses on waste incineration in an effort to clarify the behavior of radioactive nuclides, specifically, refuse-derived fuel (RDF) with added (133)Cs (stable nuclide) or (134)Cs (radioactive nuclide) was incinerated in laboratory- and pilot-scale experiments. Next, thermogravimetric (TG) and differential thermal analysis (DTA) of stable Cs compounds, as well as an X-ray absorption fine structure (XAFS) analysis of Cs concentrated in the ashes were performed to validate the behavior and chemical forms of Cs during the combustion. Our results showed that at higher temperatures and at larger equivalence ratios, (133)Cs was distributed to the bottom ash at lower concentration, and the influence of the equivalence ratio was more significant at lower temperatures. (134)Cs behaved in a similar fashion as (133)Cs. We found through TG-DTA and XAFS analysis that a portion of Cs in RDF vaporizes and is transferred to fly ash where it exists as CsCl in the MSW incinerator. We conclude that Cs-contaminated municipal solid wastes could be incinerated at high temperatures resulting in a small amount of fly ash with a high concentration of radioactive Cs, and a bottom ash with low concentrations. Copyright © 2015 Elsevier Ltd. All rights reserved.

A study of the impact of moist-heat and dry-heat treatment processes on hazardous trace elements migration in food waste.

PubMed

Chen, Ting; Jin, Yiying; Qiu, Xiaopeng; Chen, Xin

2015-03-01

Using laboratory experiments, the authors investigated the impact of dry-heat and moist-heat treatment processes on hazardous trace elements (As, Hg, Cd, Cr, and Pb) in food waste and explored their distribution patterns for three waste components: oil, aqueous, and solid components. The results indicated that an insignificant reduction of hazardous trace elements in heat-treated waste-0.61-14.29% after moist-heat treatment and 4.53-12.25% after dry-heat treatment-and a significant reduction in hazardous trace elements (except for Hg without external addition) after centrifugal dehydration (P < 0.5). Moreover, after heat treatment, over 90% of the hazardous trace elements in the waste were detected in the aqueous and solid components, whereas only a trace amount of hazardous trace elements was detected in the oil component (<0.01%). In addition, results indicated that heat treatment process did not significantly reduce the concentration of hazardous trace elements in food waste, but the separation process for solid and aqueous components, such as centrifugal dehydration, could reduce the risk considerably. Finally, combined with the separation technology for solid and liquid components, dry-heat treatment is superior to moist-heat treatment on the removal of external water-soluble ionic hazardous trace elements. An insignificant reduction of hazardous trace elements in heat-treated waste showed that heat treatment does not reduce trace elements contamination in food waste considerably, whereas the separation process for solid and aqueous components, such as centrifugal dehydration, could reduce the risk significantly. Moreover, combined with the separation technology for solid and liquid components, dry-heat treatment is superior to moist-heat treatment for the removal of external water-soluble ionic hazardous trace elements, by exploring distribution patterns of trace elements in three waste components: oil, aqueous, and solid components.

The French Mess Nucleaire

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, M.B.

1994-07-01

Nuclear weapons production has contaminated parts of France, and measures to counter this contamination may be as much cover-up as cleanup. The nuclear weapons industry is trying to remedy some of the problems it created. But until France lifts military secrecy from weapons production matters that affect the environment, the public has no way to gauge the cleanup. No institution outside the Atomic Energy Commission (CEA) and the Ministry of Defense has control over waste disposal, decontamination, and dismantlement at military nuclear sites. The major generators of weapons production waste in France are the CEA and Cogema, one of itsmore » many subsidiaries. Regular operations in military production sites produce environmental contamination. The authors also discuss some accidents causing further contamination. The clean-up measures that the industry is known to be taking, diluting the waste and minimizing the amount of waste, are suspect. The earth`s atmosphere has been considered a prime medium for diluting waste by open air burning of radioactive materials. Releases of mercury to the atmosphere, 260 kilograms per year as of 1984, contributed to water pollution as rain washed the mercury out of the air. Ocean dumping was the CEA`s answer to disposal of sold as well as liquid wastes. Injection liquids into the soil has been a temptation at sites not near substantial bodies of water. Burial of solid wastes has been common. The nuclear industry and the military must make public where and in what form wastes are stored. They must allow independent experts and institutions to examine their research, fabrication, and waste disposal sites. 48 refs.« less

Municipal solid waste leachate impact on metabolic activity of wheat (Triticum aestivum L.) seedlings.

PubMed

Awasthi, Abhishek Kumar; Pandey, Akhilesh Kumar; Khan, Jamaluddin

2017-07-01

Municipal solid waste (MSW) contains contaminants that could possibly leach out and pollute the soil, water sources. In this investigation, the MSW leachate toxicity was evaluated using wheat seedling plant bioassay. The eco-toxicity activities of leachate at several time intervals were explored, and the toxicity of these leachates on wheat (Triticum aestivum L.) seed germination and chlorophyll a and chlorophyll b (Chl a and Chl b) levels were determined. The findings showed that leachate can affect the metabolic activity of the wheat plant. Therefore, in order to protect the environment, the polluted leachate should be treated.

Photochemical oxidation: A solution for the mixed waste dilemma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prellberg, J.W.; Thornton, L.M.; Cheuvront, D.A.

1995-12-31

Numerous technologies are available to remove organic contamination from water or wastewater. A variety of techniques also exist that are used to neutralize radioactive waste. However, few technologies can satisfactorily address the treatment of mixed organic/radioactive waste without creating unacceptable secondary waste products or resulting in extremely high treatment costs. An innovative solution to the mixed waste problem is on-site photochemical oxidation. Liquid-phase photochemical oxidation has a long- standing history of successful application to the destruction of organic compounds. By using photochemical oxidation, the organic contaminants are destroyed on-site leaving the water, with radionuclides, that can be reused or disposedmore » of as appropriate. This technology offers advantages that include zero air emissions, no solid or liquid waste formation, and relatively low treatment cost. Discussion of the photochemical process will be described, and several case histories from recent design testing, including cost analyses for the resulting full-scale installations, will be presented as examples.« less

Contamination movement around a permeable reactive barrier at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina, 2009

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.; Conlon, Kevin J.

2010-01-01

The ability to monitor the fate and behavior of the plume in the forest is severely limited because the present axis of maximum contamination in that area bypasses all but one of the existing monitoring wells (12MW-12S). Moreover, the 2009 data indicate that there are no optimally placed sentinel wells in the probable path of contaminant transport. Thus the monitoring network is no longer adequate to monitor the groundwater contamination downgradient from the PRB.

A long-term comparative assessment of human health risk to leachate-contaminated groundwater from heavy metal with different liner systems.

PubMed

Mishra, Harshit; Karmakar, Subhankar; Kumar, Rakesh; Kadambala, Praneeth

2018-01-01

The handling and management of municipal solid waste (MSW) are major challenges for solid waste management in developing countries. Open dumping is still the most common waste disposal method in India. However, landfilling also causes various environmental, social, and human health impacts. The generation of heavily polluted leachate is a major concern to public health. Engineered barrier systems (EBSs) are commonly used to restrict potentially harmful wastes by preventing the leachate percolation to groundwater and overflow to surface water bodies. The EBSs are made of natural (e.g., soil, clay) and/or synthetic materials such as polymeric materials (e.g., geomembranes, geosynthetic clay liners) by arranging them in layers. Various studies have estimated the human health risk from leachate-contaminated groundwater. However, no studies have been reported to compare the human health risks, particularly due to the leachate contamination with different liner systems. The present study endeavors to quantify the human health risk to contamination from MSW landfill leachate using multiple simulations for various EBSs. To quantify the variation in health risks to groundwater consumption to the child and adult populations, the Turbhe landfill of Navi Mumbai in India has been selected. The leachate and groundwater samples were collected continuously throughout January-September in 2015 from the landfill site, and heavy metal concentrations were analyzed using an inductively coupled plasma system. The LandSim 2.5 Model, a landfill simulator, was used to simulate the landfill activities for various time slices, and non-carcinogenic human health risk was determined for selected heavy metals. Further, the uncertainties associated with multiple input parameters in the health risk model were quantified under a Monte Carlo simulation framework.

A comparison between ultraviolet disinfection and copper alginate beads within a vortex bioreactor for the deactivation of bacteria in simulated waste streams with high levels of colour, humic acid and suspended solids.

PubMed

Thomas, Simon F; Rooks, Paul; Rudin, Fabian; Atkinson, Sov; Goddard, Paul; Bransgrove, Rachel M; Mason, Paul T; Allen, Michael J

2014-01-01

We show in this study that the combination of a swirl flow reactor and an antimicrobial agent (in this case copper alginate beads) is a promising technique for the remediation of contaminated water in waste streams recalcitrant to UV-C treatment. This is demonstrated by comparing the viability of both common and UV-C resistant organisms in operating conditions where UV-C proves ineffective - notably high levels of solids and compounds which deflect UV-C. The swirl flow reactor is easy to construct from commonly available plumbing parts and may prove a versatile and powerful tool in waste water treatment in developing countries.

Prospects of effective microorganisms technology in wastes treatment in Egypt.

PubMed

Shalaby, Emad A

2011-06-01

Sludge dewatering and treatment may cost as much as the wastewater treatment. Usually large proportion of the pollutants in wastewater is organic. They are attacked by saprophytic microorganisms, i.e. organisms that feed upon dead organic matter. Activity of organisms causes decomposition of organic matter and destroys them, where the bacteria convert the organic matter or other constituents in the wastewater to new cells, water, gases and other products. Demolition activities, including renovation/remodeling works and complete or selective removal/demolishing of existing structures either by man-made processes or by natural disasters, create an extensive amount of wastes. These demolition wastes are characterized as heterogeneous mixtures of building materials that are usually contaminated with chemicals and dirt. In developing countries, it is estimated that demolition wastes comprise 20% to 30% of the total annual solid wastes. In Egypt, the daily quantity of construction and demolition (C&D) waste has been estimated as 10 000 tones. That is equivalent to one third of the total daily municipal solid wastes generated per day in Egypt. The zabbaliin have since expanded their activities and now take the waste they collect back to their garbage villages where it is sorted into recyclable components: paper, plastics, rags, glass, metal and food. The food waste is fed to pigs and the other items are sold to recycling centers. This paper summarizes the wastewater and solid wastes management in Egypt now and future.

Leachate plume delineation and lithologic profiling using surface resistivity in an open municipal solid waste dumpsite, Sri Lanka.

PubMed

Wijesekara, Hasintha Rangana; De Silva, Sunethra Nalin; Wijesundara, Dharani Thanuja De Silva; Basnayake, Bendict Francis Antony; Vithanage, Meththika Suharshini

2015-01-01

This study presents the use of direct current resistivity techniques (DCRT) for investigation and characterization of leachate-contaminated subsurface environment of an open solid waste dumpsite at Kandy, Sri Lanka. The particular dumpsite has no liner and hence the leachate flows directly to the nearby river via subsurface and surface channels. For the identification of possible subsurface flow paths and the direction of the leachate, DCRT (two-dimensional, three-dimensional and vertical electrical sounding) have been applied. In addition, the physico-chemical parameters such as pH, electrical conductivity (EC), alkalinity, hardness, chloride, chemical oxygen demand (COD) and total organic carbon (TOC) of leachate collected from different points of the solid waste dumping area and leachate drainage channel were analysed. Resistivity data confirmed that the leachate flow is confined to the near surface and no separate plume is observed in the downstream area, which may be due to the contamination distribution in the shallow overburden thickness. The stratigraphy with leachate pockets and leachate plume movements was well demarcated inside the dumpsite via low resistivity zones (1-3 Ωm). The recorded EC, alkalinity, hardness and chloride contents in leachate were averaged as 14.13 mS cm⁻¹, 3236, 2241 and 320 mg L⁻¹, respectively, which confirmed the possible causes for low resistivity values. This study confirms that DCRT can be effectively utilized to assess the subsurface characteristics of the open dumpsites to decide on corridor placement and depth of permeable reactive barriers to reduce the groundwater contamination.

An overview on characterization, utilization and leachate analysis of biomedical waste incinerator ash.

PubMed

Rajor, Anita; Xaxa, Monika; Mehta, Ratika; Kunal

2012-10-15

Solid waste management is one of the major global environmental issues, as there is continuous increase in industrial globalization and generation of waste. Solid wastes encompass the heterogeneous mass of throwaways from the urban community as well as the homogeneous accumulations of agricultural, industrial and mineral wastes. Biomedical waste pose a significant impact on health and environment. A proper waste management system should be required to dispose hazardous biomedical waste and incineration should be the best available technology to reduce the volume of this hazardous waste. The incineration process destroys pathogens and reduces the waste volume and weight but leaves a solid material called biomedical waste ash as residue which increases the levels of heavy metals, inorganic salts and organic compounds in the environment. Disposal of biomedical waste ash in landfill may cause contamination of groundwater as metals are not destroyed during incineration. The limited space and the high cost for land disposal led to the development of recycling technologies and the reuse of ash in different systems. In order to minimize leaching of its hazardous components into the environment several studies confirmed the successful utilization of biomedical waste ash in agriculture and construction sector. This paper presents the overview on the beneficial use of ash in agriculture and construction materials and its leachate characteristics. This review also stressed on the need to further evaluate the leachate studies of the ashes and slag for their proper disposal and utilization. Copyright © 2012 Elsevier Ltd. All rights reserved.

[Environmental and occupational problems in the utilization of industrial and home waste].

PubMed

Rusakov, N V; Rakhmanin, Iu A

2002-01-01

One of the acute hygienic problems of today is handling industrial and consumer wastes stored in Russia in the amount of 30 milliard tons; 30 million of solid garbage and 120 million tons of industrial wastes being formed. There are 4 garbage-handling and 10 garbage disposal plants built in the country. A third of them don't operate now. An absence of the initial selection in garbage collection causes the situation when only 3% of solid garbage is being processed. There is no state unified wastes recycling and utilizing system, no training of personnel to work out special technologies and do this work. Special attention should be given to medical wastes dangerous for the epidemiological situation, since they contain pathogenic microorganisms and helminth eggs; they may as well be contaminated by toxic and radioactive chemicals. A complex solution of the problems of industrial and consumer wastes handling is of vital importance for human health protection and protection of environment.

Reclamation of heavy metals from contaminated soil using organic acid liquid generated from food waste: removal of Cd, Cu, and Zn, and soil fertility improvement.

PubMed

Dai, Shijin; Li, Yang; Zhou, Tao; Zhao, Youcai

2017-06-01

Food waste fermentation generates complicated organic and acidic liquids with low pH. In this work, it was found that an organic acid liquid with pH 3.28 and volatile low-molecular-weight organic acid (VLMWOA) content of 5.2 g/L could be produced from food wastes after 9-day fermentation. When the liquid-to-solid ratio was 50:1, temperature was 40 °C, and contact time was 0.5-1 day, 92.9, 78.8, and 52.2% of the Cd, Cu, and Zn in the contaminated soil could be washed out using the fermented food waste liquid, respectively. The water-soluble, acid-soluble, and partly reducible heavy metal fractions can be removed after 0.5-day contact time, which was more effective than that using commercially available VLMWOAs (29-72% removal), as the former contained microorganisms and adequate amounts of nutrients (nitrogen, phosphorous, and exchangeable Na, K, and Ca) which favored the washing process of heavy metals. It is thus suggested that the organic acid fractions from food waste has a considerable potential for reclaiming contaminated soil while improving soil fertility.

Superfund record of decision (EPA Region 4): Paducah Gaseous Diffusion Plant (USDOE), Operable Unit 15, Paducah, KY, August 10, 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-12-01

This decision document presents the remedial action for the Solid Waste Management Unit (SWMU) 91 of the Waste Area Group (WAG) 27 at the Paducah Gaseous Diffusion Plant (PGDP) near Paducah, Kentucky. The primary objective of this remedial action is to reduce the level of TCE-contaminated soil thereby reducing the potential future concentrations in ground water that could pose a threat to human health and the environment at the POE (i.e., the DOE property boundary). The potential for migration of the contamination from the soil of the off-site aquifer is the concern associated with the SWMU.

Ecotoxicity of wastes in avoidance tests with Enchytraeus albidus, Enchytraeus crypticus and Eisenia fetida (Oligochaeta).

PubMed

Kobeticová, Klára; Hofman, Jakub; Holoubek, Ivan

2010-04-01

Contact bioassays are important for testing the ecotoxicity of solid materials. However, survival and reproduction tests are often not practical due to their duration which may last for several weeks. Avoidance tests with soil invertebrates may offer an alternative or extension to the classic test batteries due to their short duration (days rather than weeks) and due to a sensitive sub-acute endpoint (behavior). (a) to evaluate the effects of three solid industrial wastes (incineration ash, contaminated wood chips and contaminated soil) on three Oligochaeta species (enchytraeids Enchytraeusalbidus, Enchytraeus crypticus and earthworm Eisenia fetida) in avoidance tests; (b) to compare the sensitivity among the species and to compare results of avoidance test to reproduction tests; (c) to elucidate if measuring the weight in the earthworm avoidance test could be reasonable additional endpoint. Avoidance mostly increased with the increasing percent of waste in the mixture showing a dose-response curve. E. fetida was the most sensitive species and E. crypticus the least one. An additional endpoint, (changes in weight after two-day exposure) was not found to be more sensitive than avoidance reaction, but it confirmed that earthworms staying in the highest concentrations of the waste mixture were affected showing apparent weight reduction. Our results indicate that avoidance tests with earthworms and enchytraeids are feasible for waste testing. Copyright 2009 Elsevier Ltd. All rights reserved.

DEMONSTRATION BULLETIN: MICROFILTRATION TECHNOLOGY EPOC WATER, INC.

EPA Science Inventory

The EPOC mbrofiltratbn technology is designed to remove suspended solids that are 0.1 microns in diameter or larger from liquid wastes. Wastewaters containing dissolved metals are treated by chemical precipitation, so that the metal contamination present is greater than or equal...

40 CFR 264.178 - Closure.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Closure. 264.178 Section 264.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR... from the containment system. Remaining containers, liners, bases, and soil containing or contaminated...

Review and Implementation of Technology for Solid Radioactive Waste Volume Reduction

DTIC Science & Technology

1999-10-15

were shifted to Project 1.1 for spent nuclear fuel cask development to accelerate that project. Those funds should be repaid to Project 1.3 in the... transported between the shipyards such as Nerpa, and other intermediate storage sites such as Gremikha and Andreeva Bay. At these sites the largest...waste source and allow pretreatment unit operations using commercially available technologies of contaminant assaying, cutting/shearing, sorting

Sustainable disposal of municipal solid waste: post bioreactor landfill polishing.

PubMed

Batarseh, Eyad S; Reinhart, Debra R; Berge, Nicole D

2010-11-01

Sustainable disposal of municipal solid waste (MSW) requires assurance that contaminant release will be minimized or prevented within a reasonable time frame before the landfill is abandoned so that the risk of contamination release is not passed to future generations. This could be accomplished through waste acceptance criteria such as those established by the European Union (EU) that prohibit land disposal of untreated organic matter. In the EU, mechanical, biological and/or thermal pretreatment of MSW is therefore necessary prior to landfilling which is complicated and costly. In other parts of the world, treatment within highly engineered landfills is under development, known as bioreactor landfills. However, the completed bioreactor landfill still contains material, largely nonbiodegradable carbon and ammonia that may be released to the environment over the long-term. This paper provides a conceptual analysis of an approach to ensure landfill sustainability by the rapid removal of these remaining materials, leachate treatment and recirculation combined with aeration. The analysis in this paper includes a preliminary experimental evaluation using real mature leachate and waste samples, a modeling effort using a simplified mass balance approach and input parameters from real typical bioreactor cases, and a cost estimate for the suggested treatment method. Copyright © 2010 Elsevier Ltd. All rights reserved.

Leachates draining from controlled municipal solid waste landfill: Detailed geochemical characterization and toxicity tests.

PubMed

Mavakala, Bienvenu K; Le Faucheur, Séverine; Mulaji, Crispin K; Laffite, Amandine; Devarajan, Naresh; Biey, Emmanuel M; Giuliani, Gregory; Otamonga, Jean-Paul; Kabatusuila, Prosper; Mpiana, Pius T; Poté, John

2016-09-01

Management of municipal solid wastes in many countries consists of waste disposal into landfill without treatment or selective collection of solid waste fractions including plastics, paper, glass, metals, electronic waste, and organic fraction leading to the unsolved problem of contamination of numerous ecosystems such as air, soil, surface, and ground water. Knowledge of leachate composition is critical in risk assessment of long-term impact of landfills on human health and the environment as well as for prevention of negative outcomes. The research presented in this paper investigates the seasonal variation of draining leachate composition and resulting toxicity as well as the contamination status of soil/sediment from lagoon basins receiving leachates from landfill in Mpasa, a suburb of Kinshasa in the Democratic Republic of the Congo. Samples were collected during the dry and rainy seasons and analyzed for pH, electrical conductivity, dissolved oxygen, soluble ions, toxic metals, and were then subjected to toxicity tests. Results highlight the significant seasonal difference in leachate physicochemical composition. Affected soil/sediment showed higher values for toxic metals than leachates, indicating the possibility of using lagoon system for the purification of landfill leachates, especially for organic matter and heavy metal sedimentation. However, the ecotoxicity tests demonstrated that leachates are still a significant source of toxicity for terrestrial and benthic organisms. Therefore, landfill leachates should not be discarded into the environment (soil or surface water) without prior treatment. Interest in the use of macrophytes in lagoon system is growing and toxic metal retention in lagoon basin receiving systems needs to be fully investigated in the future. This study presents useful tools for evaluating landfill leachate quality and risk in lagoon systems which can be applied to similar environmental compartments. Copyright © 2016 Elsevier Ltd. All rights reserved.

A framework for assessment and characterisation of municipal solid waste landfill leachate: an application to the Turbhe landfill, Navi Mumbai, India.

PubMed

Mishra, Harshit; Rathod, Merwan; Karmakar, Subhankar; Kumar, Rakesh

2016-06-01

Rapid industrialisation, growing population and changing lifestyles are the root causes for the generation of huge amounts of solid waste in developing countries. In India, disposal of municipal solid waste (MSW) through open dumping is the most common waste disposal method. Unfortunately, leachate generation from landfill is high due to the prolonged and prominent monsoon season in India. As leachate generation rate is high in most of the tropical countries, long-term and extensive monitoring efforts are expected to evaluate actual environmental pollution potential due to leachate contamination. However, the leachate characterisation involves a comprehensive process, which has numerous shortcomings and uncertainties possibly due to the complex nature of landfilling process, heterogeneous waste characteristics, widely varying hydrologic conditions and selection of analytes. In order to develop a sustainable MSW management strategy for protecting the surface and ground water resources, particularly from MSW landfill leachate contamination, assessment and characterisation of leachate are necessary. Numerous studies have been conducted in the past to characterise leachate quality from various municipal landfills; unfortunately, none of these propose a framework or protocol. The present study proposes a generic framework for municipal landfill leachate assessment and characterisation. The proposed framework can be applied to design any type of landfill leachate quality monitoring programme and also to facilitate improved leachate treatment activities. A landfill site located at Turbhe, Navi Mumbai, India, which had not been investigated earlier, has been selected as a case study. The proposed framework has been demonstrated on the Turbhe landfill site which is a comparatively new and the only sanitary landfill in Navi Mumbai.

Emission of nanoparticles during combustion of waste biomass in fireplace

NASA Astrophysics Data System (ADS)

Drastichová, Vendula; Krpec, Kamil; Horák, Jiří; Hopan, František; Kubesa, Petr; Martiník, Lubomír; Koloničný, Jan; Ochodek, Tadeáš; Holubčík, Michal

2014-08-01

Contamination of air by solid particles is serious problem for human health and also environment. Small particles in nano-sizes are more dangerous than same weight of larger size. Negative effect namely of the solid particles depends on (i) number, (ii) specific surface area (iii) respirability and (iv) bonding of others substances (e.g. PAHs, As, Cd, Zn, Cu etc.) which are higher for smaller (nano-sizes) particles compared to larger one. For this reason mentioned above this contribution deals with measuring of amount, and distribution of nanoparticles produced form combustion of waste city biomass in small combustion unit with impactor DLPI.

A Comparison between Ultraviolet Disinfection and Copper Alginate Beads within a Vortex Bioreactor for the Deactivation of Bacteria in Simulated Waste Streams with High Levels of Colour, Humic Acid and Suspended Solids

PubMed Central

Thomas, Simon F.; Rooks, Paul; Rudin, Fabian; Atkinson, Sov; Goddard, Paul; Bransgrove, Rachel M.; Mason, Paul T.; Allen, Michael J.

2014-01-01

We show in this study that the combination of a swirl flow reactor and an antimicrobial agent (in this case copper alginate beads) is a promising technique for the remediation of contaminated water in waste streams recalcitrant to UV-C treatment. This is demonstrated by comparing the viability of both common and UV-C resistant organisms in operating conditions where UV-C proves ineffective - notably high levels of solids and compounds which deflect UV-C. The swirl flow reactor is easy to construct from commonly available plumbing parts and may prove a versatile and powerful tool in waste water treatment in developing countries. PMID:25541706

Exploring strategies to remove contaminants from subsurface plumes: iron-bearing materials and calcite

NASA Astrophysics Data System (ADS)

Lawter, A.; Qafoku, N. P.; Garcia, W.; Lee, B.; Freedman, V. L.

2017-12-01

At the Hanford site in eastern Washington, depending on the particular waste site, radionuclide (Tc99/I129) laden liquid waste was not of a sufficient volume to carry the contamination through the vadose zone to the groundwater. Contaminants are therefore retained in the vadose zone, which represents a continuous source of these contaminants to groundwater through flux created by precipitation recharge. Deployment of treatment technologies in the vadose zone that will intercept flow from vadose zone recharge and sequester contaminants is needed for future groundwater protection. In this study, first we tested zero valent iron (ZVI) and sulfur modified iron (SMI) to determine the feasibility of using these materials to intercept Tc migrating from the vadose zone into the groundwater. Secondly, this study focused on testing the ZVI and SMI in conjunction with several potential amendments needed for capture of additional contaminants present (e.g., IO3) to immobilize contaminants both individually and combined. Previous testing has shown removal of IO3 by incorporation into calcite; these experiments test the effect of ZVI/SMI on the efficiency of the removal of IO3 by calcite and vice versa. Preliminary results have shown strong removal of high Tc concentrations (i.e., 22 ppm or 44 ppm) at solid to solution ratios of 1 g to 100 mL, but when the solid and the Tc concentration was scaled down to more field relevant conditions (i.e., 0.42 ppm), the Tc removal was slower and the amount of Tc removed (per gram of Fe solid) was decreased. In some tests, results indicated that there is no interference from IO3 on Tc removal, but presence of ZVI/SMI has a negative impact on the removal of IO3 by calcite incorporation, likely due to the fast reduction of iodate to iodide by the ZVI/SMI (iodide is usually not incorporated into calcite).

Particle transport in porous media

NASA Astrophysics Data System (ADS)

Corapcioglu, M. Yavuz; Hunt, James R.

The migration and capture of particles (such as colloidal materials and microorganisms) through porous media occur in fields as diversified as water and wastewater treatment, well drilling, and various liquid-solid separation processes. In liquid waste disposal projects, suspended solids can cause the injection well to become clogged, and groundwater quality can be endangered by suspended clay and silt particles because of migration to the formation adjacent to the well bore. In addition to reducing the permeability of the soil, mobile particles can carry groundwater contaminants adsorbed onto their surfaces. Furthermore, as in the case of contamination from septic tanks, the particles themselves may be pathogens, i.e., bacteria and viruses.

Heavy element accumulation in Evernia prunastri lichen transplants around a municipal solid waste landfill in central Italy.

PubMed

Nannoni, Francesco; Santolini, Riccardo; Protano, Giuseppe

2015-09-01

This paper presents the results of a biomonitoring study to evaluate the environmental impact of airborne emissions from a municipal solid waste landfill in central Italy. Concentrations of 11 heavy elements, as well as photosynthetic efficiency and cell membrane integrity were measured in Evernia prunastri lichens transplanted for 4months in 17 monitoring sites around the waste landfill. Heavy element contents were also determined in surface soils. Analytical data indicated that emissions from the landfill affected Cd, Co, Cr, Cu, Ni, Pb, Sb and Zn concentrations in lichens transplanted within the landfill and along the fallout direction. In these sites moderate to severe accumulation of these heavy elements in lichens was coupled with an increase in cell membrane damage and decrease in photosynthetic efficiency. Nevertheless, results indicated that landfill emissions had no relevant impact on lichens, as heavy element accumulation and weak stress symptoms were detected only in lichen transplants from sites close to solid waste. The appropriate management of this landfill poses a low risk of environmental contamination by heavy elements. Copyright © 2015 Elsevier Ltd. All rights reserved.

MINERALOGICAL PRESERVATION OF SOLID SAMPLES COLLECTED FROM ANOXIC SUBSURFACE ENVIRONMENTS

EPA Science Inventory

Remedial technologies utilized at hazardous waste sites for the treatment of metal and metalloid contaminants often take advantage of reduction-oxidation (redox) processes to reach ground water clean up goals. This is because redox reactions, in many cases, govern the biogeochem...

40 CFR 257.25 - Assessment monitoring program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Assessment monitoring program. 257.25 Section 257.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA... unit caused the contamination, or that the statistically significant increase resulted from error in...

Prospects of effective microorganisms technology in wastes treatment in Egypt

PubMed Central

Shalaby, Emad A

2011-01-01

Sludge dewatering and treatment may cost as much as the wastewater treatment. Usually large proportion of the pollutants in wastewater is organic. They are attacked by saprophytic microorganisms, i.e. organisms that feed upon dead organic matter. Activity of organisms causes decomposition of organic matter and destroys them, where the bacteria convert the organic matter or other constituents in the wastewater to new cells, water, gases and other products. Demolition activities, including renovation/remodeling works and complete or selective removal/demolishing of existing structures either by man-made processes or by natural disasters, create an extensive amount of wastes. These demolition wastes are characterized as heterogeneous mixtures of building materials that are usually contaminated with chemicals and dirt. In developing countries, it is estimated that demolition wastes comprise 20% to 30% of the total annual solid wastes. In Egypt, the daily quantity of construction and demolition (C&D) waste has been estimated as 10 000 tones. That is equivalent to one third of the total daily municipal solid wastes generated per day in Egypt. The zabbaliin have since expanded their activities and now take the waste they collect back to their garbage villages where it is sorted into recyclable components: paper, plastics, rags, glass, metal and food. The food waste is fed to pigs and the other items are sold to recycling centers. This paper summarizes the wastewater and solid wastes management in Egypt now and future. PMID:23569767

Problems in shallow land disposal of solid low-level radioactive waste in the united states

USGS Publications Warehouse

Stevens, P.R.; DeBuchananne, G.D.

1976-01-01

Disposal of solid low-level wastes containing radionuclides by burial in shallow trenches was initiated during World War II at several sites as a method of protecting personnel from radiation and isolating the radionuclides from the hydrosphere and biosphere. Today, there are 11 principal shallow-land burial sites in the United States that contain a total of more than 1.4 million cubic meters of solid wastes contaminated with a wide variety of radionuclides. Criteria for burial sites have been few and generalized and have contained only minimal hydrogeologic considerations. Waste-management practices have included the burial of small quantities of long-lived radionuclides with large volumes of wastes contaminated with shorter-lived nuclides at the same site, thereby requiring an assurance of extremely long-time containment for the entire disposal site. Studies at 4 of the 11 sites have documented the migration of radionuclides. Other sites are being studied for evidence of containment failure. Conditions at the 4 sites are summarized. In each documented instance of containment failure, ground water has probably been the medium of transport. Migrating radionuclides that have been identified include90Sr,137Cs,106Ru,239Pu,125Sb,60Co, and3H. Shallow land burial of solid wastes containing radionuclides can be a viable practice only if a specific site satisfies adequate hydrogeologic criteria. Suggested hydrogeologic criteria and the types of hydrogeologic data necessary for an adequate evaluation of proposed burial sites are given. It is mandatory that a concomitant inventory and classification be made of the longevity, and the physical and chemical form of the waste nuclides to be buried, in order that the anticipated waste types can be matched to the containment capability of the proposed sites. Ongoing field investigations at existing sites will provide data needed to improve containment at these sites and help develop hydrogeologic criteria for new sites. These studies have necessitated the development of special drilling, sampling, well construction, and testing techniques. A recent development in borehole geophysical techniques is downhole spectral gammaray analysis which not only locates but identifies specific radionuclides in the subsurface. Field investigations are being supplemented by laboratory studies of the hydrochemistry of the transuranic elements, the kinetics of solid-liquid phase interactions, and the potential complexing of radionuclides with organic compounds and solvents which mobilize normally highly sorbable nuclides. Theoretical studies of digital predictive solute transport models are being implemented to assure their availability for application to problems and processes identified in the field and laboratory. ?? 1976 International Association of Engineering Geology.

Recovery of MSWI and soil washing residues as concrete aggregates.

PubMed

Sorlini, Sabrina; Abbà, Alessandro; Collivignarelli, Carlo

2011-02-01

The aim of the present work was to study if municipal solid waste incinerator (MSWI) residues and aggregates derived from contaminated soil washing could be used as alternative aggregates for concrete production. Initially, chemical, physical and geometric characteristics (according to UNI EN 12620) of municipal solid waste incineration bottom ashes and some contaminated soils were evaluated; moreover, the pollutants release was evaluated by means of leaching tests. The results showed that the reuse of pre-treated MSWI bottom ash and washed soil is possible, either from technical or environmental point of view, while it is not possible for the raw wastes. Then, the natural aggregate was partially and totally replaced with these recycled aggregates for the production of concrete mixtures that were characterized by conventional mechanical and leaching tests. Good results were obtained using the same dosage of a high resistance cement (42.5R calcareous Portland cement instead of 32.5R); the concrete mixture containing 400 kg/m(3) of washed bottom ash and high resistance cement was classified as structural concrete (C25/30 class). Regarding the pollutants leaching, all concrete mixtures respected the limit values according to the Italian regulation. Copyright © 2010 Elsevier Ltd. All rights reserved.

Pharmaceuticals, hormones, anthropogenic waste indicators, and total estrogenicity in liquid and solid samples from municipal sludge stabilization and dewatering

USGS Publications Warehouse

Furlong, Edward T.; Gray, James L.; Quanrud, David M.; Teske, Sondra S.; Werner, Stephen L.; Esposito, Kathleen; Marine, Jeremy; Ela, Wendell P.; Zaugg, Steven D.; Phillips, Patrick J.; Stinson, Beverley

2012-01-01

The ubiquitous presence of pharmaceuticals and other emerging contaminants, or trace organic compounds, in surface water has resulted in research and monitoring efforts to identify contaminant sources to surface waters and to better understand loadings from these sources. Wastewater treatment plant discharges have been identified as an important point source of trace organic compounds to surface water and understanding the transport and transformation of these contaminants through wastewater treatment process is essential to controlling their introduction to receiving waters.

Soil Management Plan for the Oak Ridge Y-12 National Security Complex Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2005-03-02

This Soil Management Plan applies to all activities conducted under the auspices of the National Nuclear Security Administration (NNSA) Oak Ridge Y-12 National Security Complex (Y-12) that involve soil disturbance and potential management of waste soil. The plan was prepared under the direction of the Y-12 Environmental Compliance Department of the Environment, Safety, and Health Division. Soil disturbances related to maintenance activities, utility and building construction projects, or demolition projects fall within the purview of the plan. This Soil Management Plan represents an integrated, visually oriented, planning and information resource tool for decision making involving excavation or disturbance of soilmore » at Y-12. This Soil Management Plan addresses three primary elements. (1) Regulatory and programmatic requirements for management of soil based on the location of a soil disturbance project and/or the regulatory classification of any contaminants that may be present (Chap. 2). Five general regulatory or programmatic classifications of soil are recognized to be potentially present at Y-12; soil may fall under one or more these classifications: (a) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) pursuant to the Oak Ridge Reservation (ORR) Federal Facilities Agreement; (b) Resource Conservation and Recovery Act (RCRA); (c) RCRA 3004(u) solid waste managements units pursuant to the RCRA Hazardous and Solid Waste Amendments Act of 1984 permit for the ORR; (d) Toxic Substances and Control Act-regulated soil containing polychlorinated biphenyls; and (e) Radiologically contaminated soil regulated under the Atomic Energy Act review process. (2) Information for project planners on current and future planned remedial actions (RAs), as prescribed by CERCLA decision documents (including the scope of the actions and remedial goals), land use controls implemented to support or maintain RAs, RCRA post-closure regulatory requirements for former waste management units, legacy contamination source areas and distribution of contamination in soils, and environmental infrastructure (e.g., caps, monitoring systems, etc.) that is in place or planned in association with RAs. (3) Regulatory considerations and processes for management and disposition of waste soil upon generation, including regulatory drivers, best management practices (BMPs), waste determination protocols, waste acceptance criteria, and existing waste management procedures and BMPs for Y-12. This Soil Management Plan provides information to project planners to better coordinate their activities with other organizations and programs with a vested interest in soil disturbance activities at Y-12. The information allows project managers and maintenance personnel to evaluate and anticipate potential contaminant levels that may be present at a proposed soil disturbance site prior to commencement of activities and allows a more accurate assessment of potential waste management requirements.« less

Doublet tracer tests to determine the contaminant flushing properties of a municipal solid waste landfill.

PubMed

Woodman, N D; Rees-White, T C; Beaven, R P; Stringfellow, A M; Barker, J A

2017-08-01

This paper describes a programme of research investigating horizontal fluid flow and solute transport through saturated municipal solid waste (MSW) landfill. The purpose is to inform engineering strategies for future contaminant flushing. Solute transport between injection/abstraction well pairs (doublets) is investigated using three tracers over five separate tests at well separations between 5m and 20m. Two inorganic tracers (lithium and bromide) were used, plus the fluorescent dye tracer, rhodamine-WT. There was no evidence for persistent preferential horizons or pathways at the inter-well scale. The time for tracer movement to the abstraction wells varied with well spacing as predicted for a homogeneous isotropic continuum. The time for tracer movement to remote observation wells was also as expected. Mobile porosity was estimated as ~0.02 (~4% of total porosity). Good fits to the tracer breakthrough data were achieved using a dual-porosity model, with immobile regions characterised by block diffusion timescales in the range of about one to ten years. This implies that diffusional exchanges are likely to be very significant for engineering of whole-site contaminant flushing and possibly rate-limiting. Copyright © 2017. Published by Elsevier B.V.

Doublet tracer tests to determine the contaminant flushing properties of a municipal solid waste landfill

NASA Astrophysics Data System (ADS)

Woodman, N. D.; Rees-White, T. C.; Beaven, R. P.; Stringfellow, A. M.; Barker, J. A.

2017-08-01

This paper describes a programme of research investigating horizontal fluid flow and solute transport through saturated municipal solid waste (MSW) landfill. The purpose is to inform engineering strategies for future contaminant flushing. Solute transport between injection/abstraction well pairs (doublets) is investigated using three tracers over five separate tests at well separations between 5 m and 20 m. Two inorganic tracers (lithium and bromide) were used, plus the fluorescent dye tracer, rhodamine-WT. There was no evidence for persistent preferential horizons or pathways at the inter-well scale. The time for tracer movement to the abstraction wells varied with well spacing as predicted for a homogeneous isotropic continuum. The time for tracer movement to remote observation wells was also as expected. Mobile porosity was estimated as 0.02 ( 4% of total porosity). Good fits to the tracer breakthrough data were achieved using a dual-porosity model, with immobile regions characterised by block diffusion timescales in the range of about one to ten years. This implies that diffusional exchanges are likely to be very significant for engineering of whole-site contaminant flushing and possibly rate-limiting.

40 CFR 280.66 - Corrective action plan.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Corrective action plan. 280.66 Section 280.66 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... additional information or to develop and submit a corrective action plan for responding to contaminated soils...

40 CFR 264.603 - Post-closure care.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Post-closure care. 264.603 Section 264.603 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... treatment or storage unit has contaminated soils or ground water that cannot be completely removed or...

COULOMETRIC DETERMINATION OF TOTAL SULFUR AND REDUCED INORGANIC SULFUR FRACTIONS IN ENVIRONMENTAL SAMPLES

EPA Science Inventory

Evaluation of the solid-phase partitioning of sulfur is frequently an important analytical component of risk assessments at hazardous waste sites because minerals containing reduced-sulfur can significantly affect the transport and fate of organic and inorganic contaminants in na...

Fresh organic matter of municipal solid waste enhances phytoextraction of heavy metals from contaminated soil.

PubMed

Salati, S; Quadri, G; Tambone, F; Adani, F

2010-05-01

In this study, the ability of the organic fraction of municipal solid wastes (OFMSW) to enhance heavy metal uptake of maize shoots compared with ethylenediamine disuccinic acid (EDDS) was tested on soil contaminated with heavy metals. Soils treated with OFMSW and EDDS significantly increased the concentration of heavy metals in maize shoots (increments of 302%, 66%, 184%, 169%, and 23% for Cr, Cu, Ni, Zn, and Pb with respect to the control and increments of 933%, 482%, 928%, 428%, and 5551% for soils treated with OFMSW and EDDS, respectively). In soil treated with OFMSW, metal uptake was favored because of the high presence of dissolved organic matter (DOM) (41.6x than soil control) that exhibited ligand properties because of the high presence of carboxylic acids. Because of the toxic effect of EDDS on maize plants, soil treated with OFMSW achieved the highest extraction of total heavy metals. Copyright 2009 Elsevier Ltd. All rights reserved.

Radioactive Water Treatment at a United States Environmental Protection Agency Superfund Site - 12322

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beckman, John C.

2012-07-01

A water treatment system at a United States Environmental Protection Agency (USEPA) Superfund site impacted by radiological contaminants is used to treat water entering the site. The United States Army Corps of Engineers (USACE) is actively managing the remedial action for the USEPA using contracts to support the multiple activities on site. The site is where former gas mantle production facilities operated around the turn of the century. The manufacturing facilities used thorium ores to develop the mantles and disposed of off-specification mantles and ore residuals in the surrounding areas. During Site remedial actions, both groundwater and surface water comesmore » into contact with contaminated soils and must be collected and treated at an on-site treatment facility. The radionuclides thorium and radium with associated progeny are the main concern for treatment. Suspended solids, volatile organic compounds, and select metals are also monitored during water treatment. The water treatment process begins were water is pumped to a collection tank where debris and grit settle out. Stored water is pumped to a coagulant tank containing poly-aluminum chloride to collect dissolved solids. The water passes into a reaction tube where aspirated air is added or reagent added to remove Volatile Organic Compounds (VOC'S) by mass transfer and convert dissolved iron to a solid. The water enters the flocculent polymer tank to drop solids out. The flocculated water overflows to a fluidized bed contact chamber to increase precipitation. Flocculation is where colloids of material drop out of suspension and settle. The settled solids are periodically removed and disposed of as radioactive waste. The water is passed through filters and an ion exchange process to extract the radionuclides. Several million liters of water are processed each year from two water treatment plants servicing different areas of the remediation site. Ion exchange resin and filter material are periodically replaced and disposed of as radioactive waste. A total of 0.85 m{sup 3} of waste sludge per year requires disposal on average, in addition to another 6.6 m{sup 3} of waste cartridge filters. All water discharges are regulated by a state of New Jersey Pollutant Discharge Elimination System Permit implemented by the Federal Water Pollution Control Act (Clean Water Act). Laboratory analyses are required to satisfy requirements of the state NPDES permit. Specific monitoring parameters and discharge rates will be provided. Use of the water treatment systems drastically reduces the amount of contaminated water requiring solidification and water disposal to near zero. Millions of liters of potentially contaminated water from excavation activities is treated and released within permit limits. A small volume of solid radioactive waste (21 cubic meters) is generated annually from water treatment process operations. Management of ground and surface water is effectively controlled in remediation areas by the use of sumps, erosion control measures and pumping of water to storage vessels. Continued excavations can be made as water impacting the site is effectively controlled. (authors)« less

Development of advanced fluid-bed agglomeration and cyclonic incineration for simultaneous waste disposal and energy recovery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rehmat, A.; Khinkis, M.

The Institute of Gas Technology (IGT) is currently developing a two-stage fluidized-bed/cyclonic agglomerating incineration system for waste disposal that is based on combining the fluidized-bed agglomeration/incineration and cyclonic combustion techologies. Both technologies have been developed individually at IGT over many years. This combination has resulted in a unique and extremely flexible incinerator for solid, liquid, and gaseous wastes including municipal sludges. The system can operate over a wide range of conditions in the first stage, from low temperature (desorption) to high temperature (agglomeration), including gasification of wastes. In the combined system, solid, liquid, and gaseous organic wastes are incinerated withmore » ease and great efficiency (>99.99% destruction and removal efficiency (DRE)), while solid inorganic contaminants contained within a glassy matrix are rendered benign and suitable for disposal in an ordinary landfill. The heat generated within the incinerator can be recovered using the state-of-the-art boilers. The development of the two-stage incinerator is a culmination of extensive research and development efforts on each stage of the incinerator. The variety of data obtained with solid, liquid, and gaseous wastes for both stages includes agglomeration of ash, incineration and reclamation of used blast grit and foundry sand, partial combustion of carbonaceous fuels, in-situ desulfurization, combustion of low-Btu gases, incineration of industrial wastewater, and incineration of carbon tetrachloride. 5 refs., 7 figs., 12 tabs.« less

Environmental Baseline Survey for Proposed Land Use Permit Modification for Expansion of the Dynamic Explosive Test Site (DETS) 9940 Main Complex Parking Lot.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peek, Dennis W.

The approach was to perform a document search, supplemented by a visual site inspection, to identify potential environmental contamination associated with the property. Factors evaluated included hazardous substances; petroleum products and derivatives; environmental restoration sites; areas of concern; storage tanks; oil/water separators; grease traps; wash racks; waste tanks; pesticides; military munitions/ordnance; medical or bio-hazardous waste; radioactive waste; solid/municipal waste; indoor air quality; groundwater; wastewater treatment, collection, and disposal/discharge; drinking water quality; utilities; asbestos; polychlorinated biphenyls (PCBs); radon; lead-based paint; cultural resources; floodplains; and natural/biological resources.

40 CFR 258.55 - Assessment monitoring program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Assessment monitoring program. 258.55 Section 258.55 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA... days; or (2) May demonstrate that a source other than a MSWLF unit caused the contamination, or that...

Trace contaminant concentration affects mineral transformation and pollutant fate in hydroxide-weathered Hanford sediments.

PubMed

Perdrial, Nicolas; Rivera, Nelson; Thompson, Aaron; O'Day, Peggy A; Chorover, Jon

2011-12-15

Prior work has shown that when silicaceous sediments are infused with caustic radioactive waste, contaminant fate is tightly coupled to ensuing mineral weathering reactions. However, the effects of local aqueous geochemical conditions on these reactions are poorly studied. Thus, we varied contaminant concentration and pCO(2) during the weathering of previously uncontaminated Hanford sediments over 6 months and 1 year in a solution of caustic waste (pH 13, high ionic strength). Co-contaminants Sr, Cs and I were added at "low" (Cs/Sr: 10(-5)m; I: 10(-7)m) and "high" (Cs/Sr: 10(-3)m; I: 10(-5)m) concentrations, and headspace was held at atmospheric or undetectable (<10ppmv) CO(2) partial pressure. Solid phase characterization revealed the formation of the zeolite chabazite in "high" samples, whereas feldspathoids, sodalite and cancrinite, were formed preferentially in "low" samples. Sr, Cs and I were sequestered in all reacted sediments. Native calcite dissolution in the CO(2)-free treatment drove the formation of strätlingite (Ca(2)Al(2)SiO(7)·8H(2)O) and diminished availability of Si and Al for feldspathoid formation. Results indicate that pCO(2) and contaminant concentrations strongly affect contaminant speciation in waste-weathered sediments, and are therefore likely to impact reaction product stability under any remediation scenario. Copyright © 2011 Elsevier B.V. All rights reserved.

Technical Requirements for On-Site Thermal Desorption of Solid Media Contaminated with Hazardous Chlorinated Organics

DTIC Science & Technology

1997-09-18

scrubbers , detectable dioxin/furans may occur, since dioxin/furans are much more soluble in organics than in water. Carbon adsorption is frequently...air pollution control device is required. Acid gases may be controlled by using a wet or dry scrubber or by using a coated baghouse. Operating...unit: 1. exit treated waste temperature; 2. baghouse pressure drop, venturi pressure drop, or drop in liquid/gas ratio; 3. waste feed rate; 4

Task 3 - Pyrolysis of Plastic Waste. Semiannual report, November 1, 1996--March 31, 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ness, Robert O.; Aulich, Ted R.

1997-12-31

Over the last 50 years, the U.S. Department of Energy (DOE) has produced a wide variety of radioactive wastes from activities associated with nuclear defense and nuclear power generation. These wastes include low-level radioactive solid wastes, mixed wastes, and transuranic (TRU) wastes. A portion of these wastes consists of high- organic-content materials, such as resins, plastics, and other polymers; synthetic and natural rubbers; cellulosic-based materials; and oils, organic solvents, and chlorinated organic solvents. Many of these wastes contain hazardous and/or pyrophoric materials in addition to radioactive species. Physical forms of the waste include ion-exchange resins used to remove radioactive elementsmore » from nuclear reactor cooling water, lab equipment and tools (e.g., measurement and containment vessels, hoses, wrappings, equipment coverings and components, and countertops), oil products (e.g., vacuum pump and lubrication oils), bags and other storage containers (for liquids, solids, and gases), solvents, gloves, lab coats and anti-contamination clothing, and other items. Major polymer and chemical groups found in high-organic-content radioactive wastes include polyvinyl chloride (PVC), low-density polyethylene (LDPE), polypropylene (PP), Teflon(TM), polystyrene (PS), nylon, latex, polyethylene terephthalate (PET), vinyl, high-density polyethylene (HDPE), polycarbonate, nitriles, Tygon(R), butyl, and Tyvec(R).« less

Mercury contamination and potential impacts from municipal waste incinerator on Samui Island, Thailand.

PubMed

Muenhor, Dudsadee; Satayavivad, Jutamaad; Limpaseni, Wongpun; Parkpian, Preeda; Delaune, R D; Gambrell, R P; Jugsujinda, Aroon

2009-03-01

In recent years, mercury (Hg) pollution generated by municipal waste incinerators (MWIs) has become the subject of serious public concern. On Samui Island, Thailand, a large-scale municipal waste incinerator has been in operation for over 7 years with a capacity of 140 tons/day for meeting the growing demand for municipal waste disposal. This research assessed Hg contamination in environmental matrices adjacent to the waste incinerating plant. Total Hg concentrations were determined in municipal solid waste, soil and sediment within a distance of 100 m to 5 km from the incinerator operation in both wet and dry seasons. Hg analyses conducted in municipal solid waste showed low levels of Hg ranging between 0.15-0.56 mg/kg. The low level was due to the type of waste incinerator. Waste such as electrical appliances, motors and spare parts, rubber tires and hospital wastes are not allowed to feed into the plant. As a result, low Hg levels were also found in fly and bottom ashes (0.1-0.4 mg/kg and

Behavior of radioactive cesium during incineration of radioactively contaminated wastes from decontamination activities in Fukushima.

PubMed

Fujiwara, Hiroshi; Kuramochi, Hidetoshi; Nomura, Kazutaka; Maeseto, Tomoharu; Osako, Masahiro

2017-11-01

Large volumes of decontamination wastes (DW) generated by off-site decontamination activities in Fukushima Prefecture have been incinerated since 2015. The behavior of radioactive cesium during incineration of DW was investigated at a working incineration plant. The incineration discharged bottom ash (BA) and fly ash (FA) with similar levels of radiocesium, and the leachability of the radiocesium from both types of ash was very low (<1%). These results are significantly different from those obtained for the incineration of contaminated municipal solid waste (CMSW) reported in earlier studies. The source of radiocesium in DW-FA is chiefly small particles derived from DW and DW-BA blown into the flue gas, not the deposition of gaseous synthesized radiocesium compounds on the surfaces of ash particles in the flue gas as observed in CMSW incineration. This source difference causes the behavior of radiocesium during waste incineration to differ between DW and CMSW. Copyright © 2017 Elsevier Ltd. All rights reserved.

Preliminary investigation of processes that affect source term identification. Environmental Restoration Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wickliff, D.S.; Solomon, D.K.; Farrow, N.D.

Solid Waste Storage Area (SWSA) 5 is known to be a significant source of contaminants, especially tritium ({sup 3}H), to the White Oak Creek (WOC) watershed. For example, Solomon et al. (1991) estimated the total {sup 3}H discharge in Melton Branch (most of which originates in SWSA 5) for the 1988 water year to be 1210 Ci. A critical issue for making decisions concerning remedial actions at SWSA 5 is knowing whether the annual contaminant discharge is increasing or decreasing. Because (1) the magnitude of the annual contaminant discharge is highly correlated to the amount of annual precipitation (Solomon etmore » al., 1991) and (2) a significant lag may exist between the time of peak contaminant release from primary sources (i.e., waste trenches) and the time of peak discharge into streams, short-term stream monitoring by itself is not sufficient for predicting future contaminant discharges. In this study we use {sup 3}H to examine the link between contaminant release from primary waste sources and contaminant discharge into streams. By understanding and quantifying subsurface transport processes, realistic predictions of future contaminant discharge, along with an evaluation of the effectiveness of remedial action alternatives, will be possible. The objectives of this study are (1) to characterize the subsurface movement of contaminants (primarily {sup 3}H) with an emphasis on the effects of matrix diffusion; (2) to determine the relative strength of primary vs secondary sources; and (3) to establish a methodology capable of determining whether the {sup 3}H discharge from SWSA 5 to streams is increasing or decreasing.« less

Preliminary investigation of processes that affect source term identification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wickliff, D.S.; Solomon, D.K.; Farrow, N.D.

Solid Waste Storage Area (SWSA) 5 is known to be a significant source of contaminants, especially tritium ({sup 3}H), to the White Oak Creek (WOC) watershed. For example, Solomon et al. (1991) estimated the total {sup 3}H discharge in Melton Branch (most of which originates in SWSA 5) for the 1988 water year to be 1210 Ci. A critical issue for making decisions concerning remedial actions at SWSA 5 is knowing whether the annual contaminant discharge is increasing or decreasing. Because (1) the magnitude of the annual contaminant discharge is highly correlated to the amount of annual precipitation (Solomon etmore » al., 1991) and (2) a significant lag may exist between the time of peak contaminant release from primary sources (i.e., waste trenches) and the time of peak discharge into streams, short-term stream monitoring by itself is not sufficient for predicting future contaminant discharges. In this study we use {sup 3}H to examine the link between contaminant release from primary waste sources and contaminant discharge into streams. By understanding and quantifying subsurface transport processes, realistic predictions of future contaminant discharge, along with an evaluation of the effectiveness of remedial action alternatives, will be possible. The objectives of this study are (1) to characterize the subsurface movement of contaminants (primarily {sup 3}H) with an emphasis on the effects of matrix diffusion; (2) to determine the relative strength of primary vs secondary sources; and (3) to establish a methodology capable of determining whether the {sup 3}H discharge from SWSA 5 to streams is increasing or decreasing.« less

Electrolytic decontamination of conductive materials

NASA Astrophysics Data System (ADS)

Campbell, George M.; Nelson, Timothy O.; Parker, John L.; Getty, Richard H.; Hergert, Tom R.; Lindahl, Kirk A.; Peppers, Larry G.

1994-10-01

Using the electrolytic method, we have demonstrated removal of Pu and Am from contaminated conductive material. At EG and G /Rocky Flats, we electrolytically decontaminated stainless steel. Results from this work show removal of fixed contamination, including the following geometries: planar, large radius, bolt holes, glove ports, and protruding studs. More specifically, fixed contamination was reduced from levels ranging from greater than 1 000 000 counts per minute (cpm) down to levels ranging from 1500 to 250 cpm using the electrolytic method. More recently, the electrolytic work has continued at Los Alamos National Laboratory as a joint project with EG and G/Rocky Flats. Impressively, electrolytic decontamination of Pu /Am from U surfaces (10 sq cm per side) shows decreases in swipable contamination from 500 000-1 500 000 disintegrations per minute (dpm) down to 0-2 dpm. Moreover, the solid waste product of the electrolytic method is reduced in volume by more than 50 times compared with the liquid waste produced by the previous U decontamination method -- a hot concentrated acid spray leach process.

Water-quality reconnaissance of the north Dade County solid-waste facility, Florida

USGS Publications Warehouse

McKenzie, D.J.

1982-01-01

A water-quality sampling reconnaissance of the north Dade County solid-waste disposal facility (landfill) near Carol City, Florida, was conducted during 1977-78. The purpose of the reconnaissance was to determine selected quality characteristics of the surface- and ground-water of the landfill and contiguous area; and to assess, generally, if leachate produced by the decomposition of landfill wastes was adversely impacting the downgradient water quality. Sampling results indicated that several water-quality characteristics were present in landfill ground water at significantly higher levels than in ground water upgradient or downgradient from the landfill. Moreover, many of these water-quality characteristics were found at slightly higher levels at down gradient site 5 than at upgradient site 1 which suggested that some downgradient movement of landfill leachate had occurred. For example, chloride and alkalinity in ground water had average concentrations of 20 and 290 mg/L at background wells (site 1), 144 and 610 mg/L at landfill wells (sites 2 and 4), and 29 and 338 mg/L at downgradient wells (site 5). A comparison of the 1977-78 sampling results with the National Primary and Secondary Drinking Water Regulations indicated that levels of iron and color in ground water of the study area frequently exceeded national maximum contaminant levels, dissolved solids, turbidity, lead, and manganese occasionally exceeded regulations. Concentrations of iron and levels of color and turbidity in some surface water samples also exceeded National maximum contaminant levels. (USGS)

Solid waste from leather industry as adsorbent of organic dyes in aqueous-medium.

PubMed

Oliveira, Luiz C A; Gonçalves, Maraísa; Oliveira, Diana Q L; Guerreiro, Mário C; Guilherme, Luiz R G; Dallago, Rogério M

2007-03-06

The industrial tanning of leather usually produces considerable amounts of chromium-containing solid waste and liquid effluents and raises many concerns on its environmental effect as well as on escalating landfill costs. Actually, these shortcomings are becoming increasingly a limiting factor to this industrial activity that claims for alternative methods of residue disposals. In this work, it is proposed a novel alternative destination of the solid waste, based on the removal of organic contaminants from the out coming aqueous-residue. The adsorption isotherm pattern for the wet blue leather from the Aurea tanning industry in Erechim-RS (Brazil) showed that these materials present high activity on adsorbing the reactive red textile dye as well as other compounds. The adsorbent materials were characterized by IR spectroscopy and SEM and tested for the dye adsorption (reactive textile and methylene blue dyes). The concentrations of dyes were measured by UV-vis spectrophotometry and the chromium extraction from leather waste was realized by basic hydrolysis and determined by atomic absorption. As a low cost abundant adsorbent material with high adsorption ability on removing dye methylene blue (80mgg(-1)) and textile dye reactive red (163mgg(-1)), the leather waste is revealed to be a interesting alternative relatively to more costly adsorbent materials.

Heavy Metal Veggies: A Decision Case for Environmental and Nutrition Education.

ERIC Educational Resources Information Center

Schramm, J.; And Others

1994-01-01

One alternative to continued landfilling or incineration is the development of municipal solid waste (MSW) composting facilities. This case study permits students to examine issues associated with environmental contamination by MSW and to make decisions based on agricultural, environmental, economic, food safety, and ethical considerations. The…

Co-pyrolysis of swine manure with agricultural plastic waste: Laboratory-scale study

USDA-ARS?s Scientific Manuscript database

Manure-derived biochar is the solid product resulting from pyrolysis of animal manures. It has considerable potential both to improve soil quality with high levels of nutrients and to reduce contaminants in water and soil. However, the combustible gas produced from manure pyrolysis generally does no...

Interactions between earthworms and arsenic in the soil environment: a review.

PubMed

Langdon, Caroline J; Piearce, Trevor G; Meharg, Andrew A; Semple, Kirk T

2003-01-01

Chemical pollution of the environment has become a major source of concern. In particular, many studies have investigated the impact of pollution on biota in the environment. Studies on metalliferous contaminated mine spoil wastes have shown that some soil organisms have the capability to become resistant to metal/metalloid toxicity. Earthworms are known to inhabit arsenic-rich metalliferous soils and, due to their intimate contact with the soil, in both the solid and aqueous phases, are likely to accumulate contaminants present in mine spoil. Earthworms that inhabit metalliferous contaminated soils must have developed mechanisms of resistance to the toxins found in these soils. The mechanisms of resistance are not fully understood; they may involve physiological adaptation (acclimation) or be genetic. This review discusses the relationships between earthworms and arsenic-rich mine spoil wastes, looking critically at resistance and possible mechanisms of resistance, in relation to soil edaphic factors and possible trophic transfer routes.

Assessment of the impact of landfill on groundwater quality: a case study of the Pirana site in western India.

PubMed

Singh, Umesh Kumar; Kumar, Manish; Chauhan, Rita; Jha, Pawan Kumar; Ramanathan, Al; Subramanian, V

2008-06-01

In present study focus has been given on estimating quality and toxicity of waste with respect to heavy metals and its impact on groundwater quality, using statistical and empirical relationships between different hydrochemical data, so that easy monitoring may be possible which in turn help the sustainable management of landfill site and municipal solid waste. Samples of solid waste, leachate and groundwater were analyzed to evaluate the impact of leachates on groundwater through the comparison of their hydrochemical nature. Results suggest the existence of an empirical relationship between some specific indicator parameters like heavy metals of all three above mentioned sample type. Further, K/Mg ratio also indicates three groundwater samples heavily impacted from leachate contamination. A good number of samples are also showing higher values for NO(3)(-) and Pb than that of World Health Organization (WHO) drinking water regulation. Predominance of Fe and Zn in both groundwater and solid waste samples may be due to metal plating industries in the area. Factor analysis is used as a tool to explain observed relation between numerous variables in term of simpler relation, which may help to deduce the strength of relation. Positive loading of most of the factors for heavy metal clearly shows landfill impact on ground water quality especially along the hydraulic gradient. Cluster analysis, further substantiates the impact of landfill. Two major groups of samples obtained from cluster analysis suggest that one group comprises samples that are severely under the influence of landfill and contaminated leachates along the groundwater flow direction while other assorted with samples without having such influence.

Identification of Important Parameter from Leachate Solid Waste Landfill on Water Quality, Case Study of Pesanggrahan River

NASA Astrophysics Data System (ADS)

Yanidar, R.; Hartono, D. M.; Moersidik, S. S.

2018-03-01

Cipayung Landfill takes waste generation from Depok City approximately ± 750 tons/day of solid waste. The south and west boundaries of the landfill is Pesanggarahan River which 200m faraway. The objectives of this study are to indicate an important parameter which greatly affects the water quality of Pesanggrahan River and purpose the dynamic model for improving our understanding of the dynamic behavior that captures the interactions and feedbacks important parameter in river in order to identify and assess the effects of the treated leachate from final solid waste disposal activity as it responds to changes over time in the river. The high concentrations of BOD and COD are not the only cause significantly affect the quality of the pesanggrahan water, it also because the river has been contaminated in the upstream area. It need the water quality model to support the effectiveness calculation of activities for preventing a selected the pollutant sources the model should be developed for simulating and predicting the trend of water quality performance in Pesanggrahan River which can potentially be used by policy makers in strategic management to sustain river water quality as raw drinking water.

A review of groundwater contamination near municipal solid waste landfill sites in China.

PubMed

Han, Zhiyong; Ma, Haining; Shi, Guozhong; He, Li; Wei, Luoyu; Shi, Qingqing

2016-11-01

Landfills are the most widely used method for municipal solid waste (MSW) disposal method in China. However, these facilities have caused serious groundwater contamination due to the leakage of leachate. This study, analyzed 32 scientific papers, a field survey and an environmental assessment report related to groundwater contamination caused by landfills in China. The groundwater quality in the vicinity of landfills was assessed as "very bad" by a comprehensive score (FI) of 7.85 by the Grading Method in China. Variety of pollutants consisting of 96 groundwater pollutants, 3 organic matter indicators, 2 visual pollutants and 6 aggregative pollutants had been detected in the various studies. Twenty-two kinds of pollutants were considered to be dominant. According to the Kruskal-Wallis test and the median test, groundwater contamination differed significantly between regions in China, but there were no significant differences between dry season and wet season measurements, except for some pollutants in a few landfill sites. Generally, the groundwater contamination appeared in the initial landfill stage after five years and peaked some years afterward. In this stage, the Nemerow Index (PI) of groundwater increased exponentially as landfill age increased at some sites, but afterwards decreased exponentially with increasing age at others. After 25years, the groundwater contamination was very low at selected landfills. The PI values of landfills decreased exponentially as the pollutant migration distance increased. Therefore, the groundwater contamination mainly appeared within 1000m of a landfill and most of serious groundwater contamination occurred within 200m. The results not only indicate that the groundwater contamination near MSW landfills should be a concern, but also are valuable to remediate the groundwater contamination near MSW landfills and to prevent the MSW landfill from secondary pollutions, especially for developing countries considering the similar situation of MSW disposal. Copyright © 2016 Elsevier B.V. All rights reserved.

Characterization of municipal solid waste from the main landfills of Havana city

DOE Office of Scientific and Technical Information (OSTI.GOV)

Espinosa Llorens, Ma. del C; Lopez Torres, Matilde; Alvarez, Haydee

The city of Havana, the political, administrative and cultural centre of Cuba, is also the centre of many of the economic activities of the nation: industries, services, scientific research and tourism. All of these activities contribute to the generation of municipal solid waste (MSW), which also impact other Cuban cities. Inadequate handling of waste and the lack of appropriate and efficient solutions for its final disposal and treatment increase the risk and possibility of contamination. The main difficulty in the development of a system of management of MSW lies in the lack of knowledge of the chemical composition of themore » waste that is generated in the country as a whole, and especially in Havana, where solid waste management decisions are made. The present study characterizes MSW in Havana city during 2004. The Calle 100, Guanabacoa and Ocho Vias landfills were selected for physical-chemical characterization of MSW, as they are the three biggest landfills in the city. A total of 16 indicators were measured, and weather conditions were recorded. As a result, the necessary information regarding the physical-chemical composition of the MSW became available for the first time in Cuba. The information is essential for making decisions regarding the management of waste and constitutes a valuable contribution to the Study on Integrated Management Plan of MSW in Havana.« less

Characterization of municipal solid waste from the main landfills of Havana city.

PubMed

Espinosa Lloréns, Ma Del C; Torres, Matilde López; Alvarez, Haydee; Arrechea, Alexis Pellón; García, Jorge Alejandro; Aguirre, Susana Díaz; Fernández, Alejandro

2008-01-01

The city of Havana, the political, administrative and cultural centre of Cuba, is also the centre of many of the economic activities of the nation: industries, services, scientific research and tourism. All of these activities contribute to the generation of municipal solid waste (MSW), which also impact other Cuban cities. Inadequate handling of waste and the lack of appropriate and efficient solutions for its final disposal and treatment increase the risk and possibility of contamination. The main difficulty in the development of a system of management of MSW lies in the lack of knowledge of the chemical composition of the waste that is generated in the country as a whole, and especially in Havana, where solid waste management decisions are made. The present study characterizes MSW in Havana city during 2004. The Calle 100, Guanabacoa and Ocho Vías landfills were selected for physical-chemical characterization of MSW, as they are the three biggest landfills in the city. A total of 16 indicators were measured, and weather conditions were recorded. As a result, the necessary information regarding the physical-chemical composition of the MSW became available for the first time in Cuba. The information is essential for making decisions regarding the management of waste and constitutes a valuable contribution to the Study on Integrated Management Plan of MSW in Havana.

Cesium Speciation in Dust from Municipal Solid Waste and Sewage Sludge Incineration by Synchrotron Radiation Micro-X-ray Analysis.

PubMed

Shiota, Kenji; Takaoka, Masaki; Fujimori, Takashi; Oshita, Kazuyuki; Terada, Yasuko

2015-11-17

The chemical behavior of Cs in waste incineration processes is important to consider when disposing of radionuclide-contaminated waste from the Fukushima Daiichi nuclear power plant accident in Japan. To determine the speciation of Cs, we attempted the direct speciation of trace amounts of stable Cs in the dust from municipal solid waste incineration (MSWI) and sewage sludge incineration (SSI) by micro-X-ray fluorescence (μ-XRF) and micro-X-ray absorption fine structure (μ-XAFS) at the SPring-8 facility. The μ-XRF results revealed that locally produced Cs was present in MSWI and SSI dust within the cluster size range of 2-10 μm. The μ-XAFS analysis confirmed that the speciation of Cs in MSWI dust was similar to that of CsCl, while in SSI dusts it was similar to pollucite. The solubility of Cs was considered to be influenced by the exact Cs species present in incineration residue.

FFRRO Program Information

EPA Pesticide Factsheets

This asset includes information related to Cleanups at Federal Facilities. Information is provided about contaminated federal facility sites in specific communities, with access to technical fact sheets and tools and resources to help government agencies and their contractors fulfill cleanup obligations. EPA's federal facility information is easily accessible to ensure effective stakeholder involvement and accountability at federal facilities.Multiple federal statutes establish requirements for EPA and other federal agencies to protect health and the human environment through cleanups at Federal Facilities, including the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) of 1980, which was amended by the Superfund Amendments and Reauthorization Act (SARA) in 1986; the Defense Authorization Amendments and Base Realignment and Closure Acts (BRAC) of 1998 and the Defense Base Closure and Realignment Act of 1990; and the Resource Conservation and Recovery Act (RCRA), as amended by the Hazardous and Solid Waste Amendments of 1984 (HS WA) including Subtitle C (hazardous waste), Subtitle D (solid waste), Subtitle I (underground storage tanks), and Subtitle J (Medical Waste Tracking Act of 1988).

Methods and apparatus for catalytic hydrothermal gasification of biomass

DOEpatents

Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

2012-08-14

Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

Method for reclaiming waste lubricating oils

DOEpatents

Whisman, Marvin L.; Goetzinger, John W.; Cotton, Faye O.

1978-01-01

A method for purifying and reclaiming used lubricating oils containing additives such as detergents, antioxidants, corrosion inhibitors, extreme pressure agents and the like and other solid and liquid contaminants by preferably first vacuum distilling the used oil to remove water and low-boiling contaminants, and treating the dried oil with a solvent mixture of butanol, isopropanol and methylethyl ketone which causes the separation of a layer of sludge containing contaminants, unspent additives and oxidation products. After solvent recovery, the desludged oil is then subjected to conventional lubricating oil refining steps such as distillation followed by decolorization and deodorization.

Speciation of mercury in sludge solids: washed sludge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bannochie, C. J.; Lourie, A. P.

2017-10-24

The objective of this applied research task was to study the type and concentration of mercury compounds found within the contaminated Savannah River Site Liquid Waste System (SRS LWS). A method of selective sequential extraction (SSE), developed by Eurofins Frontier Global Sciences1,2 and adapted by SRNL, utilizes an extraction procedure divided into seven separate tests for different species of mercury. In the SRNL’s modified procedure four of these tests were applied to a washed sample of high level radioactive waste sludge.

A review of the technological solutions for the treatment of oily sludges from petroleum refineries.

PubMed

da Silva, Leonardo Jordão; Alves, Flávia Chaves; de França, Francisca Pessôa

2012-10-01

The activities of the oil industry have several impacts on the environment due to the large amounts of oily wastes that are generated. The oily sludges are a semi-solid material composed by a mixture of clay, silica and iron oxides contaminated with oil, produced water and the chemicals used in the production of oil. Nowadays both the treatment and management of these waste materials is essential to promote sustainable management of exploration and exploitation of natural resources. Biological, physical and chemical processes can be used to reduce environmental contamination by petroleum hydrocarbons to acceptable levels. The choice of treatment method depends on the physical and chemical properties of the waste as well as the availability of facilities to process these wastes. Literature provides some operations for treatment of oily sludges, such as landfilling, incineration, co-processing in clinkerization furnaces, microwave liquefaction, centrifugation, destructive distillation, thermal plasma, low-temperature conversion, incorporation in ceramic materials, development of impermeable materials, encapsulation and biodegradation in land farming, biopiles and bioreactors. The management of the technology to be applied for the treatment of oily wastes is essential to promote proper environmental management, and provide alternative methods to reduce, reuse and recycle the wastes.

Enviromental impact of a hospital waste incineration plant in Krakow (Poland).

PubMed

Gielar, Agnieszka; Helios-Rybicka, Edeltrauda

2013-07-01

The environmental impact of a hospital waste incineration plant in Krakow was investigated. The objective of this study was to assess the degree of environmental effect of the secondary solid waste generated during the incineration process of medical waste. The analysis of pollution of the air emissions and leaching test of ashes and slag were carried out. The obtained results allowed us to conclude that (i) the hospital waste incineration plant significantly solves the problems of medical waste treatment in Krakow; (ii) the detected contaminant concentrations were generally lower than the permissible values; (iii) the generated ashes and slag contained considerable concentrations of heavy metals, mainly zinc, and chloride and sulfate anions. Ashes and slag constituted 10-15% of the mass of incinerated wastes; they are more harmful for the environment when compared with untreated waste, and after solidification they can be deposited in the hazardous waste disposal.

Clinical laboratory waste management in Shiraz, Iran.

PubMed

Askarian, Mehrdad; Motazedian, Nasrin; Palenik, Charles John

2012-06-01

Clinical laboratories are significant generators of infectious waste, including microbiological materials, contaminated sharps, and pathologic wastes such as blood specimens and blood products. Most waste produced in laboratories can be disposed of in the general solid waste stream. However, improper management of infectious waste, including mixing general wastes with infectious wastes and improper handling or storage, could lead to disease transmission. The aim of this study was to assess waste management processes used at clinical laboratories in Shiraz, Iran. One hundred and nine clinical laboratories participated In this cross sectional study, Data collection was by questionnaire and direct observation. Of the total amount of waste generated, 52% (by weight) was noninfectious domestic waste, 43% was non-sharps infectious waste and 5% consisted of sharps. There was no significant relationship between laboratory staff or manager education and the score for quality of waste collection and disposal at clinical laboratories. Improvements in infectious waste management processes should involve clearer, more uniformly accepted definitions of infectious waste and increased staff training.

The influence of baking fuel on residues of polycyclic aromatic hydrocarbons and heavy metals in bread.

PubMed

Ahmed, M T; Abdel Hadi el-S; el-Samahy, S; Youssof, K

2000-12-30

The influence of fuel type used to bake bread on the spectrum and concentrations of some polycyclic aromatic hydrocarbons and heavy metals in baked bread was assessed. Bread samples were collected from different bakeries operated by either electricity, solar, mazot or solid waste and their residue content of PAHs and heavy metals was assessed. The total concentration of PAHs detected in mazot, solar, solid waste and electricity operated bakeries had an average of 320.6, 158.4, 317.3 and 25.5 microgkg(-1), respectively. Samples collected from mazot, solar and solid waste operated bakeries have had a wide spectrum of PAHs, in comparison to that detected in bread samples collected from electricity operated bakeries. Lead had the highest concentrations in the four groups of bread samples, followed by nickel, while the concentrations of zinc and cadmium were the least. The concentration of lead detected in bread samples produced from mazot, solar, solid waste and electricity fueled bakeries were 1375.5, 1114, 1234, and 257.3 microgkg(-1), respectively. Estimated daily intake of PAHs based on bread consumption were 48.2, 28.5, 80. 1, and 4.8 microg per person per day for bread produced in bakeries using mazot, solar, solid waste and electricity, respectively. Meanwhile, the estimated daily intake of benzo (a) pyrene were 3.69, 2.65, 8.1, and 0.81 microg per person per day for bread sample baked with mazot, solar, solid waste and electricity, respectively. The daily intake of lead, based on bread consumption was 291, 200.5, 222, and 46.31 microg per person per day for bread sample baked with mazot, solar, solid waste and electricity, respectively. The present work has indicated the comparatively high level of daily intake of benzo (a) pyrene and lead in comparison to levels reported from many other countries and those recommended by international regulatory bodies. It is probable that residues detected in bread samples are partially cereal-borne but there is strong evidence that the process of baking and the gases emitted are responsible for most of the contamination load.

A sustainable biorefinery to convert agricultural residues into value-added chemicals.

PubMed

Liu, Zhiguo; Liao, Wei; Liu, Yan

2016-01-01

Animal wastes are of particular environmental concern due to greenhouse gases emissions, odor problem, and potential water contamination. Anaerobic digestion (AD) is an effective and widely used technology to treat them for bioenergy production. However, the sustainability of AD is compromised by two by-products of the nutrient-rich liquid digestate and the fiber-rich solid digestate. To overcome these limitations, this paper demonstrates a biorefinery concept to fully utilize animal wastes and create a new value-added route for animal waste management. The studied biorefinery includes an AD, electrocoagulation (EC) treatment of the liquid digestate, and fungal conversion of the solid fiber into a fine chemical-chitin. Animal wastes were first treated by an AD to produce methane gas for energy generation to power the entire biorefinery. The resulting liquid digestate was treated by EC to reclaim water. Enzymatic hydrolysis and fungal fermentation were then applied on the cellulose-rich solid digestate to produce chitin. EC water was used as the processing water for the fungal fermentation. The results indicate that the studied biorefinery converts 1 kg dry animal wastes into 17 g fungal biomass containing 12 % of chitin (10 % of glucosamine), and generates 1.7 MJ renewable energy and 8.5 kg irrigation water. This study demonstrates an energy positive and freshwater-free biorefinery to simultaneously treat animal wastes and produce a fine chemical-chitin. The sustainable biorefinery concept provides a win-win solution for agricultural waste management and value-added chemical production.

Planetary Protection Considerations for Life Support and Habitation Systems

NASA Technical Reports Server (NTRS)

Barta, Daniel J.; Hogan, John A.

2010-01-01

Life support systems for future human missions beyond low Earth orbit may include a combination of existing hardware components and advanced technologies. Discipline areas for technology development include atmosphere revitalization, water recovery, solid waste management, crew accommodations, food production, thermal systems, environmental monitoring, fire protection and radiation protection. Life support systems will be influenced by in situ resource utilization (ISRU), crew mobility and the degree of extravehicular activity. Planetary protection represents an additional set of requirements that technology developers have generally not considered. Planetary protection guidelines will affect the kind of operations, processes, and functions that can take place during future exploration missions, including venting and discharge of liquids and solids, ejection of wastes, use of ISRU, requirements for cabin atmospheric trace contaminant concentrations, cabin leakage and restrictions on what materials, organisms, and technologies that may be brought on missions. Compliance with planetary protection requirements may drive development of new capabilities or processes (e.g. in situ sterilization, waste containment, contaminant measurement) and limit or prohibit certain kinds of operations or processes (e.g. unfiltered venting). Ultimately, there will be an effect on mission costs, including the mission trade space. Planetary protection requirements need to be considered early in technology development programs. It is expected that planetary protection will have a major impact on technology selection for future missions.

Approach to the vadose zone monitoring in hazardous and solid waste disposal facilities

NASA Astrophysics Data System (ADS)

Twardowska, Irena

2004-03-01

In the solid waste (SW)disposal sites, in particular at the unlined facilities, at the remediated or newly-constructed units equipped with novel protective/reactive permeable barriers or at lined facilities with leachate collection systems that are prone to failure, the vadose zone monitoring should comprise besides the natural soil layer beneath the landfill, also the anthropogenic vadose zone, i.e. the waste layer and pore solutions in the landfill. The vadose zone screening along the vertical profile of SW facilities with use of direct invasive soil-core and soil-pore liquid techniques shows vertical downward redistribution of inorganic (macroconstituents and heavy metals) and organic (PAHs) contaminant loads in water infiltrating through the waste layer. These loads can make ground water down-gradient of the dump unfit for any use. To avoid damage of protective/reactive permeable barriers and liners, an installation of stationary monitoring systems along the waste layer profile during the construction of a landfill, which are amenable to generate accurate data and information in a near-real time should be considered including:(i) permanent samplers of pore solution, with a periodic pump-induced transport of collected solution to the surface, preferably with instant field measurements;(ii)chemical sensors with continuous registration of critical parameters. These techniques would definitely provide an early alert in case when the chemical composition of pore solution percolating downward the waste profile shows unfavorable transformations, which indicate an excessive contaminant load approaching ground water. The problems concerning invasive and stationary monitoring of the vadose zone in SW disposal facilities will be discussed at the background of results of monitoring data and properties of permeable protective/reactive barriers considered for use.

Changes in bacterial community of anthracene bioremediation in municipal solid waste composting soil*

PubMed Central

Zhang, Shu-ying; Wang, Qing-feng; Wan, Rui; Xie, Shu-guang

2011-01-01

Polycyclic aromatic hydrocarbons (PAHs) are common contaminants in a municipal solid waste (MSW) composting site. Knowledge of changes in microbial structure is useful to identify particular PAH degraders. However, the microbial community in the MSW composting soil and its change associated with prolonged exposure to PAHs and subsequent biodegradation remain largely unknown. In this study, anthracene was selected as a model compound. The bacterial community structure was investigated using terminal restriction fragment length polymorphism (TRFLP) and 16S rRNA gene clone library analysis. The two bimolecular tools revealed a large shift of bacterial community structure after anthracene amendment and subsequent biodegradation. Genera Methylophilus, Mesorhizobium, and Terrimonas had potential links to anthracene biodegradation, suggesting a consortium playing an active role. PMID:21887852

Contamination by perfluorinated compounds in water near waste recycling and disposal sites in Vietnam.

PubMed

Kim, Joon-Woo; Tue, Nguyen Minh; Isobe, Tomohiko; Misaki, Kentaro; Takahashi, Shin; Viet, Pham Hung; Tanabe, Shinsuke

2013-04-01

There are very few reports on the contamination by perfluorinated chemicals (PFCs) in the environment of developing countries, especially regarding their emission from waste recycling and disposal sites. This is the first study on the occurrence of a wide range of PFCs (17 compounds) in ambient water in Vietnam, including samples collected from a municipal dumping site (MD), an e-waste recycling site (ER), a battery recycling site (BR) and a rural control site. The highest PFC concentration was found in a leachate sample from MD (360 ng/L). The PFC concentrations in ER and BR (mean, 57 and 16 ng/L, respectively) were also significantly higher than those detected in the rural control site (mean, 9.4 ng/L), suggesting that municipal solid waste and waste electrical and electronic equipment are potential contamination sources of PFCs in Vietnam. In general, the most abundant PFCs were perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluoroundecanoic acid (PFUDA; <1.4-100, <1.2-100, and <0.5-20 ng/L, respectively). Interestingly, there were specific PFC profiles: perfluoroheptanoic acid and perfluorohexanoic acid (88 and 77 ng/L, respectively) were almost as abundant as PFOA in MD leachate (100 ng/L), whereas PFNA was prevalent in ER and BR (mean, 17 and 6.2 ng/L, respectively) and PFUDA was the most abundant in municipal wastewater (mean, 5.6 ng/L), indicating differences in PFC contents in different waste materials.

40 CFR 257.3-4 - Ground water.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified in...

40 CFR 257.3-4 - Ground water.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified in...

ELECTRIC POWER GENERATION USING A PHOSPHORIC ACID FUEL CELL ON A MUNICIPAL SOLID WASTE LANDFILL GAS STREAM

EPA Science Inventory

The report gives results of tests to verify the performance of a landfill gas pretreatment unit (GPU) and a phorsphoric acid fuel cell system. The complete system removes contaminants from landfill gas and produces electricity for on-site use or connection to an electric grid. Th...

40 CFR 257.3-4 - Ground water.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified in...

40 CFR 257.3-4 - Ground water.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified in...

40 CFR 257.3-4 - Ground water.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified in...

Waste minimization charges up recycling of spent lead-acid batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Queneau, P.B.; Troutman, A.L.

Substantial strides are being made to minimize waste generated form spent lead-acid battery recycling. The Center for Hazardous Materials Research (Pittsburgh) recently investigated the potential for secondary lead smelters to recover lead from battery cases and other materials found at hazardous waste sites. Primary and secondary lead smelters in the U.S. and Canada are processing substantial tons of lead wastes, and meeting regulatory safeguards. Typical lead wastes include contaminated soil, dross and dust by-products from industrial lead consumers, tetraethyl lead residues, chemical manufacturing by-products, leaded glass, china clay waste, munitions residues and pigments. The secondary lead industry also is developingmore » and installing systems to convert process inputs to products with minimum generation of liquid, solid and gaseous wastes. The industry recently has made substantial accomplishments that minimize waste generation during lead production from its bread and butter feedstock--spent lead-acid batteries.« less

Separation of motor oils, oily wastes and hydrocarbons from contaminated water by sorption on chrome shavings.

PubMed

Gammoun, A; Tahiri, S; Albizane, A; Azzi, M; Moros, J; Garrigues, S; de la Guardia, M

2007-06-25

In this paper, the ability of chrome shavings to remove motor oils, oily wastes and hydrocarbons from water has been studied. To determine amount of hydrocarbons sorbed on tanned wastes, a FT-NIR methodology was used and a multivariate calibration based on partial least squares (PLS) was employed for data treatment. The light density, porous tanned waste granules float on the surface of water and remove hydrocarbons and oil films. Wastes fibers from tannery industry have high sorption capacity. These tanned solid wastes are capable of absorbing many times their weight in oil or hydrocarbons (6.5-7.6g of oil and 6.3g of hydrocarbons per gram of chrome shavings). The removal efficiency of the pollutants from water is complete. The sorption of pollutants is a quasi-instantaneous process.

Investigation of Contaminated Groundwater at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina, 2008

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.

2009-01-01

The U.S. Geological Survey and the Naval Facilities Engineering Command Southeast investigated natural and engineered remediation of chlorinated volatile organic compound (VOC) groundwater contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina, beginning in 2000. The primary contaminants of interest in the study are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. Engineered remediation aspects at the site consist of a zero-valent-iron permeable reactive barrier (PRB) installed in December 2002 intercepting the contamination plume and a phytoremediation test stand of loblolly pine trees planted in the source area in May 2003. The U.S. Geological Survey planted an additional phytoremediation test stand of loblolly pine trees on the upgradient side of the southern end of the PRB in February 2008. At least once during the summer, however, the trees were inadvertently mowed during lawn cutting activity. The PRB along the main axis of the contaminant plume appears to be actively removing contamination. In contrast to the central area of the PRB, the data from the southern end of the PRB indicate that contaminants are moving around the PRB. Concentrations in wells upgradient from the PRB showed a general decrease in VOC concentrations. VOC concentrations in some wells in the forest downgradient from the PRB showed a sharp increase in 2005, followed by a decrease in 2006. Farther downgradient in the forest, the VOC concentrations began to increase in 2007 and continued to increase into 2008. The VOC-concentration changes in groundwater beneath the forest appear to indicate movement of a groundwater-contaminant pulse through the forest. It also is possible that the data may represent lateral shifting of the plume in response to changes in groundwater-flow direction.

Methods of vitrifying waste with low melting high lithia glass compositions

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

2001-01-01

The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

LANL OPERATING EXPERIENCE WITH THE WAND AND HERCULES PROTOTYPE SYSTEMS

DOE Office of Scientific and Technical Information (OSTI.GOV)

K. M. GRUETZMACHER; C. L. FOXX; S. C. MYERS

2000-09-01

The Waste Assay for Nonradioactive Disposal (WAND) and the High Efficiency Radiation Counters for Ultimate Low Emission Sensitivity (HERCULES) prototype systems have been operating at Los Alamos National Laboratory's (LANL's) Solid Waste Operation's (SWO'S) non-destructive assay (NDA) building since 1997 and 1998, respectively. These systems are the cornerstone of the verification program for low-density Green is Clean (GIC) waste at the Laboratory. GIC waste includes all non-regulated waste generated in radiological controlled areas (RCAS) that has been actively segregated as clean (i.e., nonradioactive) through the use of waste generator acceptable knowledge (AK). The use of this methodology alters LANL's pastmore » practice of disposing of all room trash generated in nuclear facilities in radioactive waste landfills. Waste that is verified clean can be disposed of at the Los Alamos County Landfill. It is estimated that 50-90% of the low-density room trash from radioactive material handling areas at Los Alamos might be free of contamination. This approach avoids the high cost of disposal of clean waste at a radioactive waste landfill. It also reduces consumption of precious space in the radioactive waste landfill where disposal of this waste provides no benefit to the public or the environment. Preserving low level waste (LLW) disposal capacity for truly radioactive waste is critical in this era when expanding existing radioactive waste landfills or permitting new ones is resisted by regulators and stakeholders. This paper describes the operating experience with the WAND and HERCULES since they began operation at SWO. Waste for verification by the WAND system has been limited so far to waste from the Plutonium Facility and the Solid Waste Operations Facility. A total of461 ft3 (13.1 m3) of low-density shredded waste and paper have been verified clean by the WAND system. The HERCULES system has been used to verify waste from four Laboratory facilities. These are the Solid Waste Operations Facility, the TA-48 Chemistry Facility, the Shops Facility, and the Environmental Facility. A total of 3150 ft3 (89.3 m3) of low-density waste has been verified clean by the HERCULES system.« less

Good Housekeeping Implementation for Improving Efficiency in Cassava Starch Industry (Case Study : Margoyoso District, Pati Regency)

NASA Astrophysics Data System (ADS)

Aji, Wijayanto Setyo; Purwanto; Suherman, S.

2018-02-01

Cassava starch industry is one of the leading small-medium enterprises (SMEs) in Pati Regency. Cassava starch industry released waste that reduces the quantity of final product and potentially contamined the environment. This study was conducted to observe the feasibility of good housekeeping implementation to reduce waste and at the same time improve efficiency of production process. Good housekeeping opportunities are consideration by three aspect, technical, economy and environmental. Good housekeeping opportunities involved water conservation and waste reduction. These included reuse of water in washing process, improving workers awareness in drying section and packaging section. Implementation of these opportunities can reduce water consumption, reduce wastewater and solid waste generation also increased quantity of final product.

Proposal for MSW contaminant classification applied to a tropical aquifer.

PubMed

de Faria, Gabriel Messias Moura; Mondelli, Giulliana

2018-04-01

Groundwater is a natural resource exploited worldwide causing danger due to the lixiviation of waste deposited, which presents high potential degradation. Internationally, regulation aims for the maintenance of the quality of this resource. But the local lithology, mainly in countries with tropical weather, was not considered. This paper has an objective to propose two methodologies of contaminant identification of municipal solid waste (MSW) considering the Brazilian regulation, the local lithology and the temporal aspect. The study site is located in the midwest of São Paulo, at the Marília Formation, Bauru Aquifer, which presents sandstone rich in calcite. At first, the historic monitoring data accumulated between 2002 and 2015 were statistically organized. Then, methodologies of classification of major constituents and contamination method were developed. After these analyses, the compounds that possibly cause anomaly in the local environment are Al, As, Ba, Ca, Cd, Co, Cr, Cu, phosphatic, nitrogenous, and sulfated compounds, Fe, K, Mn, Ni, and Pb. Some of these have lithogenic genesis typical of tropical environment, and others come from the disposed waste. Despite different approaches, both methods demonstrate efficiency in identifying the pollutants presenting distinctions among themselves in conjunction with actual local regulation and the lithogenic source of certain compounds.

Region 9 Renewable Energy

EPA Pesticide Factsheets

Renewable energy production is expected to increase significantly in the next 25 years. The U.S. Environmental Protection Agency (EPA) Office of Solid Waste and Emergency Response (OSWER) Center for Program Analysis (OCPA) has initiated the RE-Powering America's Land Initiative to demonstrate the enormous potential that contaminated land and mining sites provide for developing renewable energy in the U.S.

Cleanup Verification Package for the 118-F-7, 100-F Miscellaneous Hardware Storage Vault

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel

2006-11-02

This cleanup verification package documents completion of remedial action for the 118-F-7, 100-F Miscellaneous Hardware Storage Vault. The site consisted of an inactive solid waste storage vault used for temporary storage of slightly contaminated reactor parts that could be recovered and reused for the 100-F Area reactor operations.

Research Animal Holding Facility Prevents Space Lab Contamination

NASA Technical Reports Server (NTRS)

Savage, P. D., Jr.; Jahns, G. C.; Dalton, B. P.; Hogan, R. P.; Wray, A. E.

1991-01-01

Healthy environment for both rodents and human researchers maintained. Research animal holding facility (RAHF) and rodent cage prevent solid particles (feces, food bits, hair), micro-organisms, ammonia, and odors from escaping into outside environment during spaceflight. Rodent cage contains compartments for two animals. Provides each drinking-water dispenser, feeding alcove, and activity-monitoring port. Feeding and waste trays removable.

Successful remediation of four uranium calibration pits at Technical Area II, Sandia National Laboratories, Albuquerque, New Mexico, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conway, R.; Wade, M.; Tharp, T.

1994-12-31

The first remediation of an Environmental Restoration (ER) Project site at Sandia National Laboratories (SNL) was successfully conducted in May and June 1994 at Technical Area II. The removal action involved four Uranium Calibration Pits (UCPs) filled with radioactive or hazardous materials. The concrete culvert pits were used to test and calibrate borehole radiometric logging tools for uranium exploration. The removal action consisted of excavating and containerizing the pit contents and contaminated soil beneath the culverts, removing the four culverts, and backfilling the excavation. Each UCP removal had unique complexities. Sixty 208-L drums of solid radioactive waste and eight 208-Lmore » drums of liquid hazardous waste were generated during the VCM. Two of the concrete culverts will be disposed as radioactive waste and two as solid waste. Uranium-238 was detected in UCP-2 ore material at 746 pci/g, and at 59 pci/g in UCP-1 silica sand. UCP-4 was empty; sludge from UCP-3 contained 122 mg/L (ppm) chromium.« less

Evaluation of landfill leachate in arid climate-a case study.

PubMed

Al-Yaqout, A F; Hamoda, M F

2003-08-01

Generation of leachate from municipal solid waste (MSW) landfill in arid regions has long been neglected on the assumption that minimal leachate could be formed in the absence of precipitation. Therefore, a case study was conducted at two unlined MSW landfills, of different ages, in the state of Kuwait in order to determine the chemical characteristics of leachate and examine the mechanism of leachate formation. Leachate quality data were collected from both active and old (closed) landfills where co-disposal of MSW and other solid and liquid wastes is practiced. The analysis of data confirms that leachates from both landfills are severely contaminated with organics, salts and heavy metals. However, the organic strength of the leachate collected from the old landfill was reduced due to waste decomposition and continuous gas flaring. A significant degree of variability was encountered and factors which may influence leachate quality were identified and discussed. A water balance at the landfill site was assessed and a conceptual model was presented which accounts for leachate generation due to rising water table, capillary water and moisture content of the waste.

Forming artificial soils from waste materials for mine site rehabilitation

NASA Astrophysics Data System (ADS)

Yellishetty, Mohan; Wong, Vanessa; Taylor, Michael; Li, Johnson

2014-05-01

Surface mining activities often produce large volumes of solid wastes which invariably requires the removal of significant quantities of waste rock (overburden). As mines expand, larger volumes of waste rock need to be moved which also require extensive areas for their safe disposal and containment. The erosion of these dumps may result in landform instability, which in turn may result in exposure of contaminants such as trace metals, elevated sediment delivery in adjacent waterways, and the subsequent degradation of downstream water quality. The management of solid waste materials from industrial operations is also a key component for a sustainable economy. For example, in addition to overburden, coal mines produce large amounts of waste in the form of fly ash while sewage treatment plants require disposal of large amounts of compost. Similarly, paper mills produce large volumes of alkaline rejected wood chip waste which is usually disposed of in landfill. These materials, therefore, presents a challenge in their use, and re-use in the rehabilitation of mine sites and provides a number of opportunities for innovative waste disposal. The combination of solid wastes sourced from mines, which are frequently nutrient poor and acidic, with nutrient-rich composted material produced from sewage treatment and alkaline wood chip waste has the potential to lead to a soil suitable for mine rehabilitation and successful seed germination and plant growth. This paper presents findings from two pilot projects which investigated the potential of artificial soils to support plant growth for mine site rehabilitation. We found that pH increased in all the artificial soil mixtures and were able to support plant establishment. Plant growth was greatest in those soils with the greatest proportion of compost due to the higher nutrient content. These pot trials suggest that the use of different waste streams to form an artificial soil can potentially be used in mine site rehabilitation where there is a nutrient-rich source of waste.

Compendium of ordinances for groundwater protection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-08-01

Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage inmore » agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.« less

Effects of open dumping of MSW on metal contamination of soil, plants, and earthworms in Ranchi, Jharkhand, India.

PubMed

Singh, Monika; Verma, Mohini; Kumar, R Naresh

2018-02-13

Influence of open dumping of municipal solid wastes (MSW) on metal contamination of soil, plants, and earthworms in Ranchi, Jharkhand, India, was studied over 6-month period. Dumpsite in the study area exists in two sections, old section where waste dumping has stopped and new section where wastes are currently disposed. Soil around dumpsite had high concentration of Co, Cr, Cu, Pb, and Zn than that at control site. Geoaccumulation index indicated uncontaminated to moderate level of soil contamination at old dumpsite and soil at new dumpsite was found to be uncontaminated. Parthenium hysterophorus, Lantana camara, and Calotropis procera were the main plants found in patchy distribution around dumpsite. Plants exhibited almost similar levels of metal concentration in roots and shoots. P. hysterophorus and L. camara showed high bioaccumulation capacity and low translocation capacity. C. procera showed moderate bioaccumulation capacity and high translocation capacity as the concentration of metals was higher in the shoot. P. hysterophorus and L. camara due to higher bioaccumulation capacity and lower translocation capacity appear to be suitable for phytostabilization of metal-contaminated soil. Earthworms present at the dumpsite showed high concentration of Cr, Cu, Pb, and Zn with bioconcentration factor > 1. Results highlights that soil contamination due to metals is occurring at the dumpsite which is also leading to transfer of metals to plants and earthworms which can pose serious risk to environment and human health. The plants identified can be used for decontamination of metals from the dumpsite.

Temporal trends and risk assessment of polychlorinated biphenyls and heavy metals in a solid waste site in Taizhou, China.

PubMed

Zhang, Quan; Zhu, Jianqiang; Ye, Jingjia; Qian, Yi; Chen, Fang; Wang, Jinghua; Zhao, Meirong

2016-01-01

The solid wastes generated during the production of chemicals are important sources of polychlorinated biphenyls (PCBs) and heavy metals. However, few studies have been conducted regarding long-term monitoring of the risks and states of PCBs and heavy metal pollution from these sources. Herein, we reported the concentrations and risks posed by these pollutants at a chemical solid waste storage site in Taizhou, China, based on data collected before (in 2006) and after clearing the solid waste (in 2013). We examined the concentrations of 24 PCBs, including ten dioxin-like-PCB (DL-PCB) congeners (PCB77, 105, 114, 118, 123, 126, 156, 167, 169, and 189). Our data showed that the mean ∑24PCB concentrations in the soil, water, and plant samples were 6902.90 ng/g, 1637.58 ng/L, and 33.95 ng/g, respectively, in 2013. Furthermore, Cr was the most prevalent contaminant. The hazard quotient (HQ) values showed that Pb posed the highest risk in the soil samples, followed by Hg. The results of the reporter gene assay showed that soil extracts from S1, S2, S3, S4, S5, S6, and S9 exhibited potential estrogenic activities. A comparison of the data showed that the PCB pollution in some sites of this area was still serious. The data provided here are fundamentally useful for policy makers to regulate this type of storage site.

Depositional history of organic contaminants on the Palos Verdes Shelf, California

USGS Publications Warehouse

Eganhouse, R.P.; Pontolillo, J.

2000-01-01

During more than 60 years, sedimentation on the Palos Verdes Shelf has been dominated by time-varying inputs of municipal wastewater from the Los Angeles County Sanitation Districts (LACSD) and debris from the Portuguese Bend Landslide (PBL). The present study examines the depositional history of wastewater-derived organic contaminants at a site approximately 6-8 km downcurrent from the outfall system. Sediments at this location are impacted by contributions from both sources, but the relative influence of the sources has changed over time. Two classes of hydrophobic organic contaminants (chlorinated hydrocarbons, long-chain alkylbenzenes) were determined in sediment cores collected in 1981 and 1992. Using molecular stratigraphy, we determined average sedimentation rates (cm/year) and mass accumulation rates (g cm-2 year-1) for the following periods: 1955-1965, 1965-1971, 1971-1981 and 1981-1992. The results show that sedimentation and mass accumulation rates increased from 1955 to 1971 and decreased from 1971 to 1981. These trends are consistent with historical information on the emission of suspended solids from the outfall system, indicating that the discharge of wastes dominated sedimentation at the site during this period. In the 1980s and early 1990s, however, mass accumulation rates increased in spite of continually decreasing emissions of wastewater solids. Several lines of evidence indicate that this increase was due to mobilization of debris from the PBL during and after unusually strong winter storms in the 1980s. As a result, heavily contaminated sediments deposited during the years of greatest waste emissions (i.e. 1950-1970) have been buried to greater sub-bottom depths, thereby reducing their availability for mobilization to the overlying water column. These results highlight the dynamic nature of sedimentation in contaminated coastal ecosystems and its importance to the long-term fate and effects of toxic substances.

Ecological and human health risk assessment of heavy metal contamination in soil of a municipal solid waste dump in Uyo, Nigeria.

PubMed

Ihedioha, J N; Ukoha, P O; Ekere, N R

2017-06-01

The study assessed the levels of some heavy metals in soils in the vicinity of a municipal solid waste dumpsite with a view to providing information on the extent of contamination, ecological risk of metals in the soils and human health risk to the residents in Uyo. Soil samples were collected in rainy and dry seasons and analyzed for metals (Pb, Cd, Zn, Mn, Cr, Ni and Fe) using atomic absorption spectrometry. The concentrations of heavy metals (mg/kg) at the dumpsite in rainy season were Pb (9.90), Zn (137), Ni (12.56), Cr (3.60), Cd (9.05) and Mn (94.00), while in dry season, the concentrations were Pb (11.80), Zn (146), Ni (11.82), Cr (4.05), Cd (12.20) and Mn (91.20). The concentrations of metals in the studied sites were higher than that of the control site (P < 0.05). Pollution indices studies revealed that soil samples from dumpsite and distances from 10 and 20 m east of the dumpsite were highly polluted with cadmium. Ecological risk assessment carried out showed that cadmium contributed 98-99 % of the total potentially ecological risk. No probable health risk was observed as the total hazard index of all the metals was less than one. However, children were found to be more susceptible to heavy metal contamination than adult.

The application of zero-valent iron nanoparticles for the remediation of a uranium-contaminated waste effluent.

PubMed

Dickinson, Michelle; Scott, Thomas B

2010-06-15

Zero-valent iron nanoparticles (INP) were investigated as a remediation strategy for a uranium-contaminated waste effluent from AWE, Aldermaston. Nanoparticles were introduced to the effluent, under both oxic and anoxic conditions, and allowed to react for a 28-d period during which the liquid and nanoparticle solids were periodically sampled. Analysis of the solution indicated that under both conditions U was removed to <1.5% of its initial concentration within 1h of introduction and remained at similar concentrations until approximately 48 h. A rapid release of Fe into solution was also recorded during this initial period; attributed to the limited partial dissolution of the INP. XPS analyses of the reacted nanoparticulate solids between 1 and 48 h showed an increased Fe(III):Fe(II) ratio, consistent with the detection of iron oxidation products (akaganeite and magnetite) by XRD and FIB. XPS analysis also recorded uranium on the recovered particulates indicating the chemical reduction of U(VI) to U(IV) within 1h. Following the initial retention period U-dissolution of U was recorded from 48 h, and attributed to reoxidation. The efficient uptake and retention of U on the INP for periods up to 48 h provide proof that INP may be effectively used for the remediation of complex U-contaminated effluents. Copyright 2010 Elsevier B.V. All rights reserved.

Experimental evidence of colloids and nanoparticles presence from 25 waste leachates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hennebert, Pierre, E-mail: pierre.hennebert@ineris.fr; Avellan, Astrid; Yan, Junfang

Highlights: • This work is the first assessment of colloids in waste leachates. • Analytical methods are proposed and discussed. • All the waste have at least one element in colloidal form, and some elements are always colloidal. • Man-made nanoparticles are observed. • It can change the interpretation of leachate elemental concentration. - Abstract: The potential colloids release from a large panel of 25 solid industrial and municipal waste leachates, contaminated soil, contaminated sediments and landfill leachates was studied. Standardized leaching, cascade filtrations and measurement of element concentrations in the microfiltrate (MF) and ultrafiltrate (UF) fraction were used tomore » easily detect colloids potentially released by waste. Precautions against CO{sub 2} capture by alkaline leachates, or bacterial re-growth in leachates from wastes containing organic matter should be taken. Most of the colloidal particles were visible by transmission electron microscopy with energy dispersion spectrometry (TEM–EDS) if their elemental MF concentration is greater than 200 μg l{sup −1}. If the samples are dried during the preparation for microscopy, neoformation of particles can occur from the soluble part of the element. Size distribution analysis measured by photon correlation spectroscopy (PCS) were frequently unvalid, particularly due to polydispersity and/or too low concentrations in the leachates. A low sensitivity device is required, and further improvement is desirable in that field. For some waste leachates, particles had a zeta potential strong enough to remain in suspension. Mn, As, Co, Pb, Sn, Zn had always a colloidal form (MF concentration/UF concentration > 1.5) and total organic carbon (TOC), Fe, P, Ba, Cr, Cu, Ni are partly colloidal for more than half of the samples). Nearly all the micro-pollutants (As, Ba, Co, Cr, Cu, Mo, Ni, Pb, Sb, Sn, V and Zn) were found at least once in colloidal form greater than 100 μg l{sup −1}. In particular, the colloidal forms of Zn were always by far more concentrated than its dissolved form. The TEM–EDS method showed various particles, including manufactured nanoparticles (organic polymer, TiO{sub 2}, particles with Sr, La, Ce, Nd). All the waste had at least one element detected as colloidal. The solid waste leachates contained significant amount of colloids different in elemental composition from natural ones. The majority of the elements were in colloidal form for wastes of packaging (3), a steel slag, a sludge from hydrometallurgy, composts (2), a dredged sediment (#18), an As contaminated soil and two active landfill leachates. These results showed that cascade filtration and ICP elemental analysis seems valid methods in this field, and that electronic microscopy with elemental detection allows to identify particles. Particles can be formed from dissolved elements during TEM sample preparation and cross-checking with MF and UF composition by ICP is useful. The colloidal fraction of leachate of waste seems to be a significant source term, and should be taken into account in studies of emission and transfer of contaminants in the environment. Standardized cross-filtration method could be amended for the presence of colloids in waste leachates.« less

Immobilization of metal wastes by reaction with H2S in anoxic basins: concept and elaboration.

PubMed

Schuiling, R D

2013-10-01

Metal wastes are produced in large quantities by a number of industries. Their disposal in isolated waste deposits is certain to cause many subsequent problems, because every material will sooner or later return to the geochemical cycle. The sealing of disposal sites usually starts to leak, often within a short time after the disposal site has been filled. The contained heavy metals are leached from the waste deposit and will contaminate the soil and the groundwater. It is evident that storage as metal sulfides in a permanently anoxic environment is the only safe way to handle metal wastes. The world's largest anoxic basin, the Black Sea, can serve as a georeactor. The metal wastes are sustainably transformed into harmless and immobile solids. These are incorporated in the lifeless bottom muds, where they are stored for millions of years.

Physical-Chemical Solid Waste Processing for Space Missions at Ames Research Center

NASA Technical Reports Server (NTRS)

Fisher, John W.; Pisharody, Suresh; Moran, Mark; Wignarajah, K.; Tleimat, Maher; Pace, Greg

2001-01-01

As space missions become longer in duration and reach out to more distant locations such as Mars, solids waste processing progresses from storage technologies to reclamation technologies. Current low Earth orbit technologies consist of store-and dispose to space or return to Earth. Fully regenerative technologies recycle wastes. The materials reclaimed from waste can be used to provide the basic materials to support plant growth for food including carbon dioxide, water, and nutrients. Other products can also be reclaimed from waste such as hydrocarbons and activated carbon. This poster describes development at Ames Research Center of a process to make activated carbon from space mission wastes and to make an incineration system that produces clean flue gas. Inedible biomass and feces contain hydrocarbons in a form that can be pyrolyzed and converted to activated carbon. The activated carbon can then be used to clean up contaminants from various other life support systems; in particular, the activated carbon can be used regeneratively to remove NOx from incinerator flue gas. Incinerator flue gas can also be cleaned up by the use of reductive and oxidative catalysts. A catalytic incinerator flue gas cleanup system has been developed at ARC that produces flue gas clean enough (with the exception of carbon dioxide) to meet the Space Minimum Allowable Concentration limits for human exposure.

Insights into metals in individual fine particles from municipal solid waste using synchrotron radiation-based micro-analytical techniques.

PubMed

Zhu, Yumin; Zhang, Hua; Shao, Liming; He, Pinjing

2015-01-01

Excessive inter-contamination with heavy metals hampers the application of biological treatment products derived from mixed or mechanically-sorted municipal solid waste (MSW). In this study, we investigated fine particles of <2mm, which are small fractions in MSW but constitute a significant component of the total heavy metal content, using bulk detection techniques. A total of 17 individual fine particles were evaluated using synchrotron radiation-based micro-X-ray fluorescence and micro-X-ray diffraction. We also discussed the association, speciation and source apportionment of heavy metals. Metals were found to exist in a diffuse distribution with heterogeneous intensities and intense hot-spots of <10 μm within the fine particles. Zn-Cu, Pb-Fe and Fe-Mn-Cr had significant correlations in terms of spatial distribution. The overlapped enrichment, spatial association, and the mineral phases of metals revealed the potential sources of fine particles from size-reduced waste fractions (such as scraps of organic wastes or ceramics) or from the importation of other particles. The diverse sources of heavy metal pollutants within the fine particles suggested that separate collection and treatment of the biodegradable waste fraction (such as food waste) is a preferable means of facilitating the beneficial utilization of the stabilized products. Copyright © 2014. Published by Elsevier B.V.

Low melting high lithia glass compositions and methods

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

2004-11-02

The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

Low melting high lithia glass compositions and methods

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

2003-10-07

The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

Low melting high lithia glass compositions and methods

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

2000-01-01

The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

Ferrate treatment for removing chromium from high-level radioactive tank waste.

PubMed

Sylvester, P; Rutherford, L A; Gonzalez-Martin, A; Kim, J; Rapko, B M; Lumetta, G J

2001-01-01

A method has been developed for removing chromium from alkaline high-level radioactive tank waste. Removing chromium from these wastes is critical in reducing the volume of waste requiring expensive immobilization and deep geologic disposition. The method developed is based on the oxidation of insoluble chromium(III) compounds to soluble chromate using ferrate. This method could be generally applicable to removing chromium from chromium-contaminated solids, when coupled with a subsequent reduction of the separated chromate back to chromium(III). The tests conducted with a simulated Hanford tank sludge indicate that the chromium removal with ferrate is more efficient at 5 M NaOH than at 3 M NaOH. Chromium removal increases with increasing Fe(VI)/Cr(II) molar ratio, but the chromium removal tends to level out for Fe(VI)/ Cr(III) greaterthan 10. Increasingtemperature leadsto better chromium removal, but higher temperatures also led to more rapid ferrate decomposition. Tests with radioactive Hanford tank waste generally confirmed the simulant results. In all cases examined, ferrate enhanced the chromium removal, with a typical removal of around 60-70% of the total chromium present in the washed sludge solids. The ferrate leachate solutions did not contain significant concentrations of transuranic elements, so these solutions could be disposed as low-activity waste.

Recovering and recycling Hg from chlor-alkali plant wastewater sludge

NASA Astrophysics Data System (ADS)

Twidwell, L. G.; Thompson, R. J.

2001-01-01

Montana Tech of the University of Montana and Universal Dynamics of British Columbia have developed a hydrometallurgical process for recovering and recycling mercury from chlorine plant wastewater sludge materials (U.S. Environmental Protection Agency [EPA]hazardous-waste classification K106). The hydrometallurgical process is also applicable for the treatment of mercury-contaminated soils (EPA hazardous waste classification D009) and other mercury-bearing waste materials. The process, which is capable of lowering the mercury content in the K106 solids from 10% to <50 mg/kg Hg, has been commercialized and utilized at three U.S. plants. This paper describes the fundamental chemistry of the process, the flowsheet being used, and operating plant case histories.

Process for preparing lubricating oil from used waste lubricating oil

DOEpatents

Whisman, Marvin L.; Reynolds, James W.; Goetzinger, John W.; Cotton, Faye O.

1978-01-01

A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

Effect of solid waste landfill organic pollutants on groundwater in three areas of Sicily (Italy) characterized by different vulnerability.

PubMed

Indelicato, Serena; Orecchio, Santino; Avellone, Giuseppe; Bellomo, Sergio; Ceraulo, Leopoldo; Di Leonardo, Rossella; Di Stefano, Vita; Favara, Rocco; Candela, Esterina Gagliano; La Pica, Leonardo; Morici, Sabina; Pecoraino, Giovannella; Pisciotta, Antonino; Scaletta, Claudio; Vita, Fabio; Vizzini, Salvatrice; Bongiorno, David

2017-07-01

The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below the legal threshold. Overall, the Fl/Fl + Py diagnostic ratio revealed that PAHs had a petrogenic origin. VOC levels, except for two notable exceptions near Palermo landfill, were always below the legal limit. As concerns PCB levels, several samples were found positive with levels exceeding the legal limits. It is worth noting that the % PCB distribution differs from that of commercial compositions. In parallel, some samples of groundwater containing PCDDs and PCDFs exceeding the legal threshold were also found. Among the 17 congeners monitored, the most abundant were the highest molecular weight ones.

X-231B technology demonstration for in situ treatment of contaminated soil: Contaminant characterization and three dimensional spatial modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, O.R.; Siegrist, R.L.; Mitchell, T.J.

1993-11-01

Fine-textured soils and sediments contaminated by trichloroethylene (TCE) and other chlorinated organics present a serious environmental restoration challenge at US Department of Energy (DOE) sites. DOE and Martin Marietta Energy Systems, Inc. initiated a research and demonstration project at Oak Ridge National Laboratory. The goal of the project was to demonstrate a process for closure and environmental restoration of the X-231B Solid Waste Management Unit at the DOE Portsmouth Gaseous Diffusion Plant. The X-231B Unit was used from 1976 to 1983 as a land disposal site for waste oils and solvents. Silt and clay deposits beneath the unit were contaminatedmore » with volatile organic compounds and low levels of radioactive substances. The shallow groundwater was also contaminated, and some contaminants were at levels well above drinking water standards. This document begins with a summary of the subsurface physical and contaminant characteristics obtained from investigative studies conducted at the X-231B Unit prior to January 1992 (Sect. 2). This is then followed by a description of the sample collection and analysis methods used during the baseline sampling conducted in January 1992 (Sect. 3). The results of this sampling event were used to develop spatial models for VOC contaminant distribution within the X-231B Unit.« less

Food waste management using an electrostatic separator with corona discharge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lai, Koonchun; Teh, Pehchiong; Lim, Sooking

In Malaysia, municipal solid waste contains a high portion of organic matters, typically contributed by food waste. It is estimated that about 45% of the municipal waste are food waste, followed by the non-food waste such as plastics, metals, glass and others. Food waste, while being properly sorted and contamination free from non-food waste, can be reused (e.g. fertiliser) instead of being landfilled. Therefore, recycling of food waste is crucial not only from the view point of waste management, but also with respect to the reduction of resource losses and greenhouse gases emission. A new waste separation process involved foodmore » particles, non-food particles and electrostatic discharge was investigated in this study. The empirical results reveal that the corona electrostatic separation is an environmental-friendly way in recovering foods from municipal waste. The efficiency of the separator, under same operating conditions, varies with the particle size of the food and non-food particles. The highest efficiency of 82% is recorded for the particle sizes between 1.5 and 3.0 mm.« less

Food waste management using an electrostatic separator with corona discharge

NASA Astrophysics Data System (ADS)

Lai, Koonchun; Lim, Sooking; Teh, Pehchiong

2015-05-01

In Malaysia, municipal solid waste contains a high portion of organic matters, typically contributed by food waste. It is estimated that about 45% of the municipal waste are food waste, followed by the non-food waste such as plastics, metals, glass and others. Food waste, while being properly sorted and contamination free from non-food waste, can be reused (e.g. fertiliser) instead of being landfilled. Therefore, recycling of food waste is crucial not only from the view point of waste management, but also with respect to the reduction of resource losses and greenhouse gases emission. A new waste separation process involved food particles, non-food particles and electrostatic discharge was investigated in this study. The empirical results reveal that the corona electrostatic separation is an environmental-friendly way in recovering foods from municipal waste. The efficiency of the separator, under same operating conditions, varies with the particle size of the food and non-food particles. The highest efficiency of 82% is recorded for the particle sizes between 1.5 and 3.0 mm.

Study of water recovery and solid waste processing for aerospace and domestic applications. Volume 2: Final report

NASA Technical Reports Server (NTRS)

Guarneri, C. A.; Reed, A.; Renman, R. E.

1972-01-01

The manner in which current and advanced technology can be applied to develop practical solutions to existing and emerging water supply and waste disposal problems is evaluated. An overview of water resource factors as they affect new community planning, and requirements imposed on residential waste treatment systems are presented. The results of equipment surveys contain information describing: commercially available devices and appliances designed to conserve water; devices and techniques for monitoring water quality and controlling back contamination; and advanced water and waste processing equipment. System concepts are developed and compared on the basis of current and projected costs. Economic evaluations are based on community populations of from 2,000 to 250,000. The most promising system concept is defined in sufficient depth to initiate detailed design.

Application of Geographic Information System and Remotesensing in effective solid waste disposal sites selection in Wukro town, Tigray, Ethiopia

NASA Astrophysics Data System (ADS)

Mohammedshum, A. A.; Gebresilassie, M. A.; Rulinda, C. M.; Kahsay, G. H.; Tesfay, M. S.

2014-11-01

Identifying solid waste disposal sites and appropriately managing them is a challenging task to many developing countries. This is a critical problem too in Ethiopia in general and in Wukro town in particular. The existing site for Wukro town is not sufficient in its capacity and it is damaging the environment due to its location, and the type of waste dumped, while the surrounding area is being irrigated. Due to the swift expansion and urbanization developments in Wukro town, it badly needs to develop controlled solid waste dumping site to prevent several contamination problems. This study was conducted first, to assess the existing waste management strategies in Wukro town; and second, to find out the potential waste disposal sites for the town, using GIS and Remote Sensing techniques. The study exploited the Multi-Criteria Evaluation (MCE) methods to combine necessary factors considered for dumping site selection. The selected method also uses various geographical data including remote sensing data, with GIS spatial analysis tools. Accordingly, site suitability maps for each of the factors were developed in a GIS environment. Results indicate that 12 dumping sites were appropriate and they were further ranked against their suitability in terms of wind direction, proximity to settlement area and distance from the center of the town. Finally, two sites are the best suitable for dumping site. This study indicated that the application of Geographic Information System and Remote Sensing techniques are efficient and low cost tools to study and select appropriate dumping site so as to facilitate decision making processes.

Elevated concentrations of U and co-occurring metals in abandoned mine wastes in a northeastern Arizona Native American community

DOE PAGES

Blake, Johanna M.; Avasarala, Sumant; Artyushkova, Kateryna; ...

2015-07-09

The chemical interactions of U and co-occurring metals in abandoned mine wastes in a Native American community in northeastern Arizona were investigated using spectroscopy, microscopy and aqueous chemistry. The concentrations of U (67–169 μg L –1) in spring water samples exceed the EPA maximum contaminant limit of 30 μg L –1. Elevated U (6,614 mg kg –1), V (15,814 mg kg –1), and As (40 mg kg –1) concentrations were detected in mine waste solids. Spectroscopy (XPS and XANES) solid analyses identified U (VI), As (-I and III) and Fe (II, III). Linear correlations for the release of U vsmore » V and As vs Fe were observed for batch experiments when reacting mine waste solids with 10 mM ascorbic acid (~pH 3.8) after 264 h. The release of U, V, As, and Fe was at least 4-fold lower after reaction with 10 mM bicarbonate (~pH 8.3). These results suggest that U–V mineral phases similar to carnotite [K 2(UO 2) 2V 2O 8] and As–Fe-bearing phases control the availability of U and As in these abandoned mine wastes. Elevated concentrations of metals are of concern due to human exposure pathways and exposure of livestock currently ingesting water in the area. This study contributes to understanding the occurrence and mobility of metals in communities located close to abandoned mine waste sites.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blake, Johanna M.; Avasarala, Sumant; Artyushkova, Kateryna

The chemical interactions of U and co-occurring metals in abandoned mine wastes in a Native American community in northeastern Arizona were investigated using spectroscopy, microscopy and aqueous chemistry. The concentrations of U (67–169 μg L –1) in spring water samples exceed the EPA maximum contaminant limit of 30 μg L –1. Elevated U (6,614 mg kg –1), V (15,814 mg kg –1), and As (40 mg kg –1) concentrations were detected in mine waste solids. Spectroscopy (XPS and XANES) solid analyses identified U (VI), As (-I and III) and Fe (II, III). Linear correlations for the release of U vsmore » V and As vs Fe were observed for batch experiments when reacting mine waste solids with 10 mM ascorbic acid (~pH 3.8) after 264 h. The release of U, V, As, and Fe was at least 4-fold lower after reaction with 10 mM bicarbonate (~pH 8.3). These results suggest that U–V mineral phases similar to carnotite [K 2(UO 2) 2V 2O 8] and As–Fe-bearing phases control the availability of U and As in these abandoned mine wastes. Elevated concentrations of metals are of concern due to human exposure pathways and exposure of livestock currently ingesting water in the area. This study contributes to understanding the occurrence and mobility of metals in communities located close to abandoned mine waste sites.« less

Integrated, flexible, and rapid geophysical surveying

NASA Astrophysics Data System (ADS)

Miller, S. F.; McGinnis, L. D.; Thompson, M. D.; Tome, C.

Aberdeen Proving Ground (APG) is currently managing a comprehensive Installation Restoration Program involving more than 360 solid-waste managing units contained within 13 study areas. The Edgewood area and two landfills in the Aberdeen area appear on the National Priority List under the Comprehensive Environmental Response, Compensation, and Liability Act. Therefore, APG has entered into an interagency agreement with the US Environmental Protection Agency to address the listed areas. The West Branch of the Canal Creek area, located within the Edgewood area, is one of the areas that requires a Source Definition Study because there is an ongoing release of volatile organic compounds into the creek. A report prepared in 1989 included a list of 29 potentially contaminated buildings in the Edgewood area. Sixteen of the buildings contain known contaminants, nine buildings contain unknown contaminants, and four of the buildings are potentially clean. The EAI report recommended that a sampling and monitoring program be established to verify contamination levels in and around each building. Thirteen of the potentially contaminated buildings are in the West Branch of the Canal Creek area and are potential sources of volatile organic compounds. Operations have ceased, and the buildings have been abandoned, but processing equipment, sumps, drains, ventilation systems, and underground storage tanks remain. These appurtenances may contain liquid, solid, or vapor contaminants of unknown nature.

Co-pyrolysis of swine manure with agricultural plastic waste: laboratory-scale study.

PubMed

Ro, Kyoung S; Hunt, Patrick G; Jackson, Michael A; Compton, David L; Yates, Scott R; Cantrell, Keri; Chang, SeChin

2014-08-01

Manure-derived biochar is the solid product resulting from pyrolysis of animal manures. It has considerable potential both to improve soil quality with high levels of nutrients and to reduce contaminants in water and soil. However, the combustible gas produced from manure pyrolysis generally does not provide enough energy to sustain the pyrolysis process. Supplementing this process may be achieved with spent agricultural plastic films; these feedstocks have large amounts of available energy. Plastic films are often used in soil fumigation. They are usually disposed in landfills, which is wasteful, expensive, and environmentally unsustainable. The objective of this work was to investigate both the energetics of co-pyrolyzing swine solids with spent plastic mulch films (SPM) and the characteristics of its gas, liquid, and solid byproducts. The heating value of the product gas from co-pyrolysis was found to be much higher than that of natural gas; furthermore, the gas had no detectable toxic fumigants. Energetically, sustaining pyrolysis of the swine solids through the energy of the product gas could be achieved by co-pyrolyzing dewatered swine solids (25%m/m) with just 10% SPM. If more than 10% SPM is used, the co-pyrolysis would generate surplus energy which could be used for power generation. Biochars produced from co-pyrolyzing SPM and swine solid were similar to swine solid alone based on the surface area and the (1)H NMR spectra. The results of this study demonstrated the potential of using pyrolysis technology to manage two prominent agricultural waste streams (SPM and swine solids) while producing value-added biochar and a power source that could be used for local farm operations. Published by Elsevier Ltd.

Investigating aquifer contamination and groundwater quality in eastern Terai region of Nepal.

PubMed

Mahato, Sanjay; Mahato, Asmita; Karna, Pankaj Kumar; Balmiki, Nisha

2018-05-21

This study aims at assessing the groundwater quality of the three districts of Eastern Terai region of Nepal viz. Morang, Jhapa, Sunsari using physicochemical characteristics and statistical approach so that possible contamination of water reservoir can be understood. pH, temperature, conductivity, turbidity, color, total dissolved solids, fluorides, ammonia, nitrates, chloride, total hardness, calcium hardness, calcium, magnesium, total alkalinity, iron, manganese, arsenic have to be analyzed to know the present status of groundwater quality. Results revealed that the value of analyzed parameters were within the acceptable limits for drinking water recommended by World Health Organization except for pH, turbidity, ammonia and iron. As per Nepal Drinking Water Quality Standards, fluoride and manganese too were not complying with the permissible limit. Electrical conductivity, total dissolved solids, chloride, total hardness, calcium hardness, manganese, and total alkalinity show good positive correlation with major water quality parameters. Calcium, magnesium, total hardness, calcium hardness and total alkalinity greatly influences total dissolved solids and electrical conductivity. ANOVA, Tukey, and clustering highlight the significance of three districts. Groundwater can be considered safe, but there is always a chance of contamination through chemical wastes in the heavily industrialized area of Morang and Sunsari Industrial corridor.

Contaminated groundwater characterization at the Chalk River Laboratories, Ontario, Canada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schilk, A.J.; Robertson, D.E.; Thomas, C.W.

1993-03-01

The licensing requirements for the disposal of low-level radioactive waste (10 CFR 61) specify the performance objectives and technical requisites for federal and commercial land disposal facilities, the ultimate goal of which is to contain the buried wastes so that the general population is adequately protected from harmful exposure to any released radioactive materials. A major concern in the operation of existing and projected waste disposal sites is subterranean radionuclide transport by saturated or unsaturated flow, which could lead to the contamination of groundwater systems as well as uptake by the surrounding biosphere, thereby directly exposing the general public tomore » such materials. Radionuclide transport in groundwater has been observed at numerous commercial and federal waste disposal sites [including several locations within the waste management area of Chalk River Laboratories (CRL)], yet the physico-chemical processes that lead to such migration are still not completely understood. In an attempt to assist in the characterization of these processes, an intensive study was initiated at CRL to identify and quantify the mobile radionuclide species originating from three separate disposal sites: (a) the Chemical Pit, which has received aqueous wastes containing various radioisotopes, acids, alkalis, complexing agents and salts since 1956, (b) the Reactor Pit, which has received low-level aqueous wastes from a reactor rod storage bay since 1956, and (c) the Waste Management Area C, a thirty-year-old series of trenches that contains contaminated solid wastes from CRL and various regional medical facilities. Water samples were drawn downgradient from each of the above sites and passed through a series of filters and ion-exchange resins to retain any particulate and dissolved or colloidal radionuclide species, which were subsequently identified and quantified via radiochemical separations and gamma spectroscopy. These groundwaters were also analyzed for anions, trace metals, Eh, pH, alkalinity and dissolved oxygen.« less

A Remote Absorption Process for Disposal of Evaporate and Reverse Osmosis Concentrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brunsell, D.A.

2008-07-01

Many commercial nuclear plants and DOE facilities generate secondary waste streams consisting of evaporator bottoms and reverse osmosis (RO) concentrate. Since liquids are not permitted in disposal facilities, these waste streams must be converted to dry solids, either by evaporation to dried solids or by solidification to liquid-free solids. Evaporation of the liquid wastes reduces their volume, but requires costly energy and capital equipment. In some cases, concentration of the contaminants during drying can cause the waste to exceed Class A waste for nuclear utilities or exceed DOE transuranic limits. This means that disposal costs will be increased, or that,more » when the Barnwell, SC disposal site closes to waste outside of the Atlantic Compact in July 2008, the waste will be precluded from disposal for the foreseeable future). Solidification with cement agents requires less energy and equipment than drying, but results in a volume increase of 50-100%. The doubling or tripling of waste weight, along with the increased volume, sharply increases shipping and disposal costs. Confronted with these unattractive alternatives, Diversified Technologies Services (DTS), in conjunction with selected nuclear utilities and D and D operations at Rocky Flats, undertook an exploratory effort to convert this liquid wastewater to a solid without using cement. This would avoid the bulking effect of cement, and permit the waste to be disposed of the Energy Solutions facility in Utah as well as some DOE facilities. To address the need for an attractive alternative to drying and cement solidification, a test program was developed using a polymer absorbent media to convert the concentrate streams to a liquid-free waste form that meets the waste acceptance criteria of the pertinent burial sites. Two approaches for mixing the polymer with the liquid were tested: mechanical mixing and in-situ incorporation. As part of this test program, a process control program (PCP) was developed that is 100% scalable from a concentrate test sample as small as 50 grams to full-scale processing of 100 cubic foot containers or larger. In summary: The absorption process offers utilities a viable and less costly alternative to on-site drying or solidification of concentrates. The absorption process can be completed by site personnel or by a vendor as a turnkey service. The process is suitable for multiple types of waste, including RO and evaporator concentrates, sludges, and other difficult to process waters and wet solids. (author)« less

Residual waste from Hanford tanks 241-C-203 and 241-C-204. 1. Solids characterization.

PubMed

Krupka, Kenneth M; Schaef, Herbert T; Arey, Bruce W; Heald, Steve M; Deutsch, William I; Lindberg, Michael J; Cantrell, Kirk J

2006-06-15

Bulk X-ray diffraction (XRD), synchrotron X-ray microdiffraction (microXRD), and scanning electron microscopy/ energy-dispersive X-ray spectroscopy (SEM/EDS) were used to characterize solids in residual sludge from single-shell underground waste tanks C-203 and C-204 at the U.S. Department of Energy's Hanford Site in southeastern Washington state. Cejkaite [Na4(UO2)(CO3)3] was the dominant crystalline phase in the C-203 and C-204 sludges. This is one of the few occurrences of cejkaite reported in the literature and may be the first documented occurrence of this phase in radioactive wastes from DOE sites. Characterization of residual solids from water leach and selective extraction tests indicates that cejkaite has a high solubility and a rapid rate of dissolution in water at ambient temperature and that these sludges may also contain poorly crystalline Na2U207 [or clarkeite Na[(UO2)O(OH)](H2O)0-1] as well as nitratine (soda niter, NaNO3), goethite [alpha-FeO(OH)], and maghemite (gamma-Fe2O3). Results of the SEM/EDS analyses indicate that the C-204 sludge also contains a solid that lacks crystalline form and is composed of Na, Al, P, O, and possibly C. Other identified solids include Fe oxides that often also contain Cr and Ni and occur as individual particles, coatings on particles, and botryoidal aggregates; a porous-looking material (or an aggregate of submicrometer particles) that typically contain Al, Cr, Fe, Na, Ni, Si, U, P, O, and C; Si oxide (probably quartz); and Na-Al silicate(s). The latter two solids probably represent minerals from the Hanford sediment, which were introduced into the tank during prior sampling campaigns or other tank operation activities. The surfaces of some Fe-oxide particles in residual solids from the water leach and selective extraction tests appear to have preferential dissolution cavities. If these Fe oxides contain contaminants of concern, then the release of these contaminants into infiltrating water would be limited by the dissolution rates of these Fe oxides, which in general have lowto very low solubilities and slow dissolution rates at near neutral to basic pH values under oxic conditions.

[Causes of drinking-water contamination in rain-fed cisterns in three villages in Ramallah and Al-Bireh District, Palestine].

PubMed

Al-Khatib, Issam A; Orabi, Moammar

2004-05-01

We studied the biological characteristics of drinking-water in three villages in Ramallah and al-Bireh district, by testing the total coliforms. Water samples were collected from rain-fed cisterns between October and November 2001. The results show that 87% of tested samples of drinking-water were highly contaminated and in need of coagulation, filtration and disinfection based on the World Health Organization guidelines for drinking-water, and 10.5% had low contamination and were in need of treatment by disinfection only. Only 2.5% of the tested samples were not contaminated and were suitable for drinking without treatment. The main cause of drinking-water con tamination was the presence of cesspits, wastewater and solid waste dumping sites near the cisterns.

Secondary Waste Form Down Selection Data Package – Ceramicrete

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cantrell, Kirk J.; Westsik, Joseph H.

2011-08-31

As part of high-level waste pretreatment and immobilized low activity waste processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed in the Integrated Disposal Facility. Currently, four waste forms are being considered for stabilization and solidification of the liquid secondary wastes. These waste forms are Cast Stone, Ceramicrete, DuraLith, and Fluidized Bed Steam Reformer. The preferred alternative will be down selected from these four waste forms. Pacific Northwest National Laboratorymore » is developing data packages to support the down selection process. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilization and solidification of the liquid secondary wastes. The information included will be based on information available in the open literature and from data obtained from testing currently underway. This data package is for the Ceramicrete waste form. Ceramicrete is a relatively new engineering material developed at Argonne National Laboratory to treat radioactive and hazardous waste streams (e.g., Wagh 2004; Wagh et al. 1999a, 2003; Singh et al. 2000). This cement-like waste form can be used to treat solids, liquids, and sludges by chemical immobilization, microencapsulation, and/or macroencapsulation. The Ceramicrete technology is based on chemical reaction between phosphate anions and metal cations to form a strong, dense, durable, low porosity matrix that immobilizes hazardous and radioactive contaminants as insoluble phosphates and microencapsulates insoluble radioactive components and other constituents that do not form phosphates. Ceramicrete is a type of phosphate-bonded ceramic, which are also known as chemically bonded phosphate ceramics. The Ceramicrete binder is formed through an acid-base reaction between calcined magnesium oxide (MgO; a base) and potassium hydrogen phosphate (KH{sub 2}PO{sub 4}; an acid) in aqueous solution. The reaction product sets at room temperature to form a highly crystalline material. During the reaction, the hazardous and radioactive contaminants also react with KH{sub 2}PO{sub 4} to form highly insoluble phosphates. In this data package, physical property and waste acceptance data for Ceramicrete waste forms fabricated with wastes having compositions that were similar to those expected for secondary waste effluents, as well as secondary waste effluent simulants from the Hanford Tank Waste Treatment and Immobilization Plant were reviewed. With the exception of one secondary waste form formulation (25FA+25 W+1B.A. fabricated with the mixed simulant did not meet the compressive strength requirement), all the Ceramicrete waste forms that were reviewed met or exceeded Integrated Disposal Facility waste acceptance criteria.« less

Recovering lead from cupel waste generated in gold analysis by Pb-Fire assay.

PubMed

Cerceau, Cristiane Isaac; Carvalho, Cornélio de Freitas; Rabelo, Ana Carolina Silveira; Dos Santos, Cláudio Gouvea; Gonçalves, Sabrina Mayra Dias; Varejão, Eduardo Vinícius Vieira

2016-12-01

Because of its precision and accuracy, Pb-Fire assay is the most employed method for gold analysis in geological materials. At the second stage of the method, namely cupellation, lead is oxidized to PbO which is absorbed by the cupel, leading to metallic gold as a tiny bend at the bottom of the recipient. After cupellation, cupel becomes highly contaminated with lead, making its disposal a serious risk of environmental contamination. In the present work, a leaching process for removing lead from cupel waste is proposed, which allowed for removing 96% of PbO by weight. After a precipitation step, 92.0% of lead was recovered from leachates in the form of PbSO 4 . Lead in the solid wastes left by the extraction was above the limit established by Brazilian legislation and these were classified as non-hazardous. Finally, secondary effluents generated after the precipitation step presented lead content more than twenty times lower than that of leachates from cupel waste. Tons of cupel waste are annually generated from gold analysis by Pb-Fire assay. Thus, the proposed method can contribute to prevent the discharge of high amounts of lead into the environment. Also, recovery of lead can help to partially meet the industrial demand for lead compounds. Copyright © 2016 Elsevier Ltd. All rights reserved.

Chemical Characterization of an Envelope B/D Sample from Hanford Tank 241-AZ-102

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hay, M.S.

2000-08-23

A sample from Hanford waste tank 241-AZ-102 was received at the Savannah River Technology Center (SRTC) and chemically characterized. The sample containing supernate and a small amount of sludge solids was analyzed as-received. The filtered supernatant liquid, the total dried solids of the sample, and the washed insoluble solids obtained from filtration of the sample were analyzed. A mass balance calculation of the three fractions of the sample analyzed indicate the analytical results appear relatively self-consistent for major components of the sample. However, some inconsistency was observed between results were more than one method of determination was employed and formore » species present in low concentrations. The actinides isotopes, plutonium, americium, and curium, present analytical challenges due to the low concentration of these species and the potential for introduction of small amounts of contamination during sampling handling resulting in large uncertainties. A direct comparison to previous analyses of material from tank 241-AZ-102 showed good agreement with the filtered supernatant liquid. However, the comparison of solids data showed poor agreement. The poor agreement shown between the current results for the solids samples and previous analyses most likely results from the uncertainties associated with obtaining small solids samples from a large non-homogenized waste tank.« less

Fate of selected microorganisms when introduced as cross-contamination inocula into simulated food trash compartment waste

NASA Astrophysics Data System (ADS)

Strayer, Richard; Hummerick, Mary; Richards, Jeffrey; Birmele, Michele; Roberts, Michael

AdHocReviewCycleID-309796538 NewReviewCycle EmailSubjectPlease review this (?today?) AuthorEm Richard F. (KSC)[DYNAMAC CORP] ReviewingToolsShownOnceurn:schemas-microsoft-com:office:smart One goal of Exploration Life Support solid waste processing is to stabilize wastes for storage, mitigate crew risks, and enable resource recovery. Food and crew fecal wastes contain easily biodegraded organic components that support microbial growth. Our objective is to determine a baseline for the fate of selected microbes in wastes prior to processing treatments. Challenge microbes, including human-associated pathogens, were added to unsterilized, simulated food trash solid waste containing a mixed microbial community. The fate of the microbial community and challenge microbes was determined over a 6 week time course of waste storage. Challenge microbes were selected from a list of microorganisms common to residual food or fecal wastes and included: Escherichia coli, Salmonella enterica serovar typhimurium, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger (a common mold), and Bacillus pumilus SAFR-032, a spore-forming bacterium previously isolated from spacecraft assembly facilities selected for its resistance to heat, uv, and desiccation. The trash model simulant contained 80% food trash (food waste and containers) and 20% hygiene wipes. Cultures of challenge microbes were grown overnight on Nutrient Agar (Difco), harvested, re-suspended in physiological saline, and diluted to achieve the desired optical density for inoculation. The six organisms were pooled and inoculated into the simulated food wastes and packaging before manual mixing. Inoculated simulated waste was stored in custom FlexfoilTM gas sampling bags (SKC, Inc.) which were then connected to a gas analysis system designed to supply fresh air to each bag to maintain O2 above 1%. Bag headspace was monitored for CO2 (PP Systems) and O2 (Maxtec). Total microbes were quantified by microscopic direct counts and general cultivation-based methods. Detection and enumeration of challenge microbes was accomplished by cultivation-based microbiological methods with specific selective media and by molecular methods using quantitative stocktickerPCR (qPCR) with stocktickerDNA primers specific for each challenge organism. stocktickerDNA was extracted and purified from residual wastes with a stocktickerDNA isolation kit (Mo Bio), and quantified (NanoDrop) from standard curves prepared from pure culture isolates of each challenge organism. QPCR was conducted on a Roche LightCycler 480 using the Roche stocktickerSYBR Green Master Mix Kit. The identity of all challenge microbes in recovered isolates was verified by stocktickerDNA sequencing (stocktickerABI 3130 Genetic Analyzer - Applied Biosystems). To date, concentrations of challenge microbial populations at concentrations ranging from ˜107 - 108 have been added to simulated food waste and extracted either immediately after mixing or after 1 week of storage. Cultivation-based counts indicated that 5 of 6 challenge microbes could be recovered from simulated food wastes after inoculation for both concentrations. Only S. enterica serovar typhimurium could not be detected at week 0 for the 107 inoculum. Between week 0 and 1, challenge microbes increased in density: S. aureus, E. coli, and P. aeruginosa increasing up to 4 orders of magnitude from the 107 inoculum. Molecular results for the week 0 and week 1 stored samples indicated that the relative concentrations of target stocktickerDNA for the challenge microbes had increased between 1 and 3 orders of magnitude. These preliminary studies demonstrate that potential problems regarding pathogens as cross-contaminants from other waste streams could develop during storage of space mission solid wastes. Ongoing studies are examining longer storage times up to 6 weeks. The results can be used to determine requirements and criteria for waste treatment prior to storage and provides a means of testing the ability of treatment technologies to limit contaminant survival and proliferation.

Method for treating materials for solidification

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Martin, Hollis L.

1995-01-01

A method for treating materials such as wastes for solidification to form a solid, substantially nonleachable product. Addition of reactive silica rather than ordinary silica to the material when bringing the initial molar ratio of its silica constituent to a desired ratio within a preselected range increases the solubility and retention of the materials in the solidified matrix. Materials include hazardous, radioactive, mixed, and heavy metal species. Amounts of other constituents of the material, in addition to its silica content are also added so that the molar ratio of each of these constituents is within the preselected ranges for the final solidified product. The mixture is then solidified by cement solidification or vitrification. The method can be used to treat a variety of wastes, including but not limited to spent filter aids from waste water treatment, waste sludges, combinations of spent filter aids and waste sludges, combinations of supernate and waste sludges, incinerator ash, incinerator offgas blowdown, combinations of incinerator ash and offgas blowdown, cementitious wastes and contaminated soils.

Applied technology for mine waste water decontamination in the uranium ores extraction from Romania

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bejenaru, C.; Filip, G.; Vacariu, V.T.

1996-12-31

The exploitation of uranium ores in Romania is carried out in underground mines. In all exploited uranium deposits, mine waste waters results and will still result after the closure of uranium ore extraction activity. The mine waters are radioactively contaminated with uranium and its decay products being a hazard both for underground waters as for the environment. This paper present the results of research work carried out by authors for uranium elimination from waste waters as the problems involved during the exploitation process of the existent equipment as its maintenance in good experimental conditions. The main waste water characteristics aremore » discussed: solids as suspension, uranium, radium, mineral salts, pH, etc. The moist suitable way to eliminate uranium from mine waste waters is the ion exchange process based on ion exchangers in fluidized bed. A flowsheet is given with main advantages resulted.« less

Preinvestigation evaluation of corrective measure technologies for the Badger Army Ammunition Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benioff, P.A.; Tsai, S.Y.

1989-02-01

This report briefly describes and evaluates the suitability of corrective measure technologies for possible use at the solid waste management units (SWMUs) at the Badger Army Ammunition Plant (BAAP), near Baraboo, Wisconsin. Corrective measure technologies considered for contaminated soils include excavation plus on- or off-site disposal in landfills or by incineration, use of solidification or stabilization methods, and in-situ methods such as bioreclamation and chemical or physical methods. Technologies considered for treatment of contaminated groundwater include groundwater pumping followed by discharge or treatment by air stripping and use of subsurface barriers. 5 refs., 1 tab.

Assessment and quantification of plastics waste generation in major 60 cities of India.

PubMed

Nalini, R; Srinivasulu, B; Shit, Subhas C; Nigam, Suneel Kumar; Akolkar, A B; Dwivedfi, R K

2013-04-01

Polymers or plastics materials registered rapid growth in 1970s, 1980s and 1990s at the rate of 2-2.5 times the GDP growth in India. The demand for plastic raw material got more than doubled from 3.3 Million Metric Ton to 6.8 Million Metric Tons in 2010 attributed mainly to rapid urbanization, spread of retail chains, plastics based packaging from grocery to food and vegetable products to cosmetics and consumer items. Plastics packages have its merits over many of conventional materials in the related sector but unless they are collected back effectively after their use to go into recycling process, they become an eyesore in the stream of Municipal Solid Waste (MSW) due to high visibility. As the synthetic and conventional plastics are non-biodegradable in nature, these remain in the dump yards/ landfills for several years, if not collected properly. Due to non- biodegradability, plastics waste remains in the environment for several years, if not collected and disposing plastics wastes at landfills are unsafe since toxic chemicals leach out into the soil and as they contaminate soil and underground water quality. The municipal solid waste also increasing day-by-day due to the inefficient source collection, segregation and transmission of plastics waste for recycling and reusing. In order to find out the realistic plastics waste generation, a study on assessment and quantification of plastics waste has been carried out by CPCB in collaboration with CIPET on selected 60 major cities of India.

The use of spent mushroom compost to enhance the ability of Atriplex halimus to phytoremediate contaminated mine soils.

PubMed

Frutos, Iván; García-Delgado, Carlos; Cala, Victoria; Gárate, Agustin; Eymar, Enrique

2017-05-01

The mushroom cultivation industry produces a huge amount of spent mushroom compost (SMC), a wide world agricultural organic waste which causes serious environmental problems. However, this cheap organic waste could be useful in the remediation of contaminated soils. The aim of this work was to assess the potential of SMC in combination with the native shrub Atriplex halimus, to phytoremediate two mine soils contaminated with Cd, Pb and Cu. Firstly, to minimize metal availability in the soil, the optimal doses of SMC were determined. Secondly, a phytoremediation assay in greenhouse conditions was carried out to test the effects of A. halimus in combination with SMC at different doses. The results showed the ability of SMC to reduce soil acidity, the mobility of the metals and the enhancement of A. halimus growth. SMC promoted metal immobilization in the root of A. halimus and decreased the translocation from the roots to the shoots. The combination of SMC amendment and A. halimus produced phytostabilization of the metals in the mine soils assayed. In conclusion, SMC represents an adequate organic solid waste which in combination with A. halimus can reduce the adverse impact caused by the high mobility of metals in acid mine soils.

[Recent advance in solidification/stabilization technology for the remediation of heavy metals-contaminated soil].

PubMed

Hao, Han-zhou; Chen, Tong-bin; Jin, Meng-gui; Lei, Mei; Liu, Cheng-wu; Zu, Wen-pu; Huang, Li-mi

2011-03-01

Remediation of heavy metals-contaminated soil is still a difficulty and a hotspot of international research projects. At present, the technologies commonly adopted for the remediation of contaminated sites mainly include excavation, solidification/stabilization (S/S), soil washing, soil vapor extraction (SVE), thermal treatment, and bioremediation. Based on the S/S technical guidelines of Unite State Environmental Protection Agency (EPA) and United Kingdom Environment Agency (EA) and the domestic and foreign patents, this paper introduced the concepts of S/S and its development status at home and abroad, and discussed its future development directions. Solidification refers to a process that binds contaminated media with a reagent, changing the media's physical properties via increasing its compressive strength, decreasing its permeability, and encapsulating the contaminants to form a solid material. Stabilization refers to the process that involves a chemical reaction which reduces the leachability of a waste, chemically immobilizes the waste and reduces its solubility, making the waste become less harmful or less mobile. S/S technology includes cement solidification, lime pozzolanic solidification, plastic materials stabilization, vitrification, and regent-based stabilization. Stabilization (or immobilization) treatment processes convert contaminants to less mobile forms through chemical or thermal interactions. In stabilization technology, the aim of adding agents is to change the soil physical and chemical properties through pH control technology, redox potential technology, precipitation techniques, adsorption technology, and ion-exchange technology that change the existing forms of heavy metals in soil, and thus, reduce the heavy metals bioavailability and mobility. This review also discussed the S/S evaluation methods, highlighted the need to enhance S/S technology in the molecular bonding, soil polymers, and formulation of China's S/S technical guidelines.

POP-contaminated sites from HCH production in Sabiñánigo, Spain.

PubMed

Fernández, J; Arjol, M A; Cacho, C

2013-04-01

In 2009, hexachlorocyclohexane (HCH) isomers (α-HCH, β-HCH, and γ-HCH [lindane]) were listed as persistent organic pollutants (POP) in the Stockholm Convention. Accordingly, the legacy of HCH/lindane production with the associated large HCH waste deposits has become recognized as an issue of global concern and is addressed in the implementation of the Convention. The current paper gives an overview of the major contaminated sites from lindane production of the INQUINOSA Company. This company operated from 1975 to 1988 in the city of Sabiñánigo, Spain. HCH production resulted in the production of approximately 115,000 tonnes of waste isomers which were mainly dumped in two unlined landfills. These two landfill sites, together with the former production site, are recognized sources of environmental pollution. Assessment and remediation activities at these sites are described. A dense nonaqueous phase liquid (DNAPL) contaminated inter alia with HCH isomers, benzene, chlorobenzenes, and chlorophenols as the main contaminants and an associated contaminated groundwater plume have been discovered at both landfill/dumpsites and at the former production site. The approximately 4,000 t of DNAPLs constitute a serious risk for the environment due to the proximity of the Gállego River. Since 2004, more than 20 tonnes of this DNAPL has been extracted using "pump and treat" techniques. The Aragon Regional Government and the Spanish Environmental Ministry are taking action, focusing on the treatment of DNAPL and on the transfer of the large quantities of solid POP wastes to a new landfill. A range of laboratory tests has been performed in order to plan the aquifer remediation.

Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps associated with uranium exploration and mining, Browns Hole, Utah

USGS Publications Warehouse

Marston, Thomas M.; Beisner, Kimberly R.; Naftz, David L.; Snyder, Terry

2012-01-01

During August of 2008, 35 solid-phase samples were collected from abandoned uranium waste dumps, undisturbed geologic background sites, and adjacent streambeds in Browns Hole in southeastern Utah. The objectives of this sampling program were (1) to assess impacts on human health due to exposure to radium, uranium, and thorium during recreational activities on and around uranium waste dumps on Bureau of Land Management lands; (2) to compare concentrations of trace elements associated with mine waste dumps to natural background concentrations; (3) to assess the nonpoint source chemical loading potential to ephemeral and perennial watersheds from uranium waste dumps; and (4) to assess contamination from waste dumps to the local perennial stream water in Muleshoe Creek. Uranium waste dump samples were collected using solid-phase sampling protocols. Solid samples were digested and analyzed for major and trace elements. Analytical values for radium and uranium in digested samples were compared to multiple soil screening levels developed from annual dosage calculations in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act's minimum cleanup guidelines for uranium waste sites. Three occupancy durations for sites were considered: 4.6 days per year, 7.0 days per year, and 14.0 days per year. None of the sites exceeded the radium soil screening level of 96 picocuries per gram, corresponding to a 4.6 days per year exposure. Two sites exceeded the radium soil screening level of 66 picocuries per gram, corresponding to a 7.0 days per year exposure. Seven sites exceeded the radium soil screening level of 33 picocuries per gram, corresponding to a 14.0 days per year exposure. A perennial stream that flows next to the toe of a uranium waste dump was sampled, analyzed for major and trace elements, and compared with existing aquatic-life and drinking-water-quality standards. None of the water-quality standards were exceeded in the stream samples.

Assessment of groundwater quality by unsaturated zone study due to migration of leachate from Abloradjei waste disposal site, Ghana

NASA Astrophysics Data System (ADS)

Egbi, Courage Davidson; Akiti, Tetteh Thomas; Osae, Shiloh; Dampare, Samuel Boakye; Abass, Gibrilla; Adomako, Dickson

2017-05-01

Leachate generated by open solid waste disposal sites contains substances likely to contaminate groundwater. The impact of potential contaminants migrating from leachate on groundwater can be quantified by monitoring their concentration and soil properties at specific points in the unsaturated zone. In this study, physical and chemical analyses were carried out on leachate, soil and water samples within the vicinity of the municipal solid waste disposal site at Abloradjei, a suburb of Accra, Ghana. The area has seen a massive increase in population and the residents depend on groundwater as the main source of water supply. Results obtained indicate alkaline pH for leachate and acidic conditions for unsaturated zone water. High EC values were recorded for leachate and unsaturated zone water. Major ions (Ca2+, Na+, Mg2+, K+, NO3 -, SO4 2-, Cl-, PO4 3- were analysed in leachate, unsaturated zone water, soil solution and groundwater while trace metals (Al, Fe, Cu, Zn, Pb) were analysed in both soil and extracted soil solution. Concentrations of major ions were high in all samples indicating possible anthropogenic origin. Mean % gravel, % sand, % clay, bulk density, volumetric water content and porosity were 28.8, 63.93, 6.6, 1 g cm-3, 35 and 62.7 %, respectively. Distribution of trace elements showed Kd variation of Al > Cu > Fe > Pb > Zn in the order of sequential increasing solubility. It was observed that the quality of groundwater is not suitable for drinking.

Analysis of waste management issues arising from a field study evaluating decontamination of a biological agent from a building.

PubMed

Lemieux, P; Wood, J; Drake, J; Minamyer, S; Silvestri, E; Yund, C; Nichols, T; Ierardi, M; Amidan, B

2016-01-01

The Bio-response Operational Testing and Evaluation (BOTE) Project was a cross-government effort designed to operationally test and evaluate a response to a biological incident (release of Bacillus anthracis [Ba] spores, the causative agent for anthrax) from initial public health and law enforcement response through environmental remediation. The BOTE Project was designed to address site remediation after the release of a Ba simulant, Bacillus atrophaeus spp. globigii (Bg), within a facility, drawing upon recent advances in the biological sampling and decontamination areas. A key component of response to a biological contamination incident is the proper management of wastes and residues, which is woven throughout all response activities. Waste is generated throughout the response and includes items like sampling media packaging materials, discarded personal protective equipment, items removed from the facility either prior to or following decontamination, aqueous waste streams, and materials generated through the application of decontamination technologies. The amount of residual contaminating agent will impact the available disposal pathways and waste management costs. Waste management is an integral part of the decontamination process and should be included through "Pre-Incident" response planning. Overall, the pH-adjusted bleach decontamination process generated the most waste from the decontamination efforts, and fumigation with chlorine dioxide generated the least waste. A majority of the solid waste generated during pH-adjusted bleach decontamination was the nonporous surfaces that were removed, bagged, decontaminated ex situ, and treated as waste. The waste during the two fumigation rounds of the BOTE Project was associated mainly with sampling activities. Waste management activities may represent a significant contribution to the overall cost of the response/recovery operation. This paper addresses the waste management activities for the BOTE field test. Management of waste is a critical element of activities dealing with remediation of buildings and outdoor areas following a biological contamination incident. Waste management must be integrated into the overall remediation process, along with sampling, decontamination, resource management, and other important response elements, rather than being a stand-alone activity. The results presented in this paper will provide decision makers and emergency planners at the federal/state/tribal/local level information that can be used to integrate waste management into an overall systems approach to planning and response activities.

Contamination and restoration of groundwater aquifers.

PubMed Central

Piver, W T

1993-01-01

Humans are exposed to chemicals in contaminated groundwaters that are used as sources of drinking water. Chemicals contaminate groundwater resources as a result of waste disposal methods for toxic chemicals, overuse of agricultural chemicals, and leakage of chemicals into the subsurface from buried tanks used to hold fluid chemicals and fuels. In the process, both the solid portions of the subsurface and the groundwaters that flow through these porous structures have become contaminated. Restoring these aquifers and minimizing human exposure to the parent chemicals and their degradation products will require the identification of suitable biomarkers of human exposure; better understandings of how exposure can be related to disease outcome; better understandings of mechanisms of transport of pollutants in the heterogeneous structures of the subsurface; and field testing and evaluation of methods proposed to restore and cleanup contaminated aquifers. In this review, progress in these many different but related activities is presented. PMID:8354172

Stabilization of cesium in alkali-activated municipal solid waste incineration fly ash and a pyrophyllite-based system.

PubMed

Shiota, Kenji; Nakamura, Takafumi; Takaoka, Masaki; Aminuddin, Siti Fatimah; Oshita, Kazuyuki; Fujimori, Takashi

2017-11-01

Environmentally sound treatments are required to dispose of municipal solid waste incineration fly ash (MSWIFA) contaminated with radioactive cesium (Cs) from the Fukushima Daiichi nuclear power plant accident in Japan. This study focuses on the stabilization of Cs using an alkali-activated MSWIFA and pyophyllite-based system. Three composite solid products were synthesized after mixtures of raw materials (dehydrated pyrophyllite, MSWIFA, 14 mol/L aqueous sodium hydroxide, and sodium silicate solution) were cured at 105 °C for 24 h. Three types of MSWIFAs were prepared as raw fly ash, raw fly ash with 0.1% CsCl, and raw fly ash with 40% CsCl to understand the stabilization mechanism of Cs. Cs stabilization in two solid products was successful, with less than 6.9% leaching observed from two types tests, and was partly successful for the solid product with the highest concentration of Cs. X-ray diffraction showed that all of the solid products produced several crystalline phases, and that pollucite was formed in the highest Cs concentration product. The X-ray absorption fine structure and scanning electron microscopy with X-ray analysis suggested that most Cs species formed pollucite in the two solid products from MSWIFA with added CsCl. This system provides a technique for the direct stabilization of Cs in MSWIFA. Copyright © 2017 Elsevier Ltd. All rights reserved.

Impact of leachate on groundwater pollution due to non-engineered municipal solid waste landfill sites of erode city, Tamil Nadu, India

PubMed Central

2012-01-01

Leachate and groundwater samples were collected from Vendipalayam, Semur and Vairapalayam landfill sites in Erode city, Tamil Nadu, India, to study the possible impact of leachate percolation on groundwater quality. Concentrations of various physicochemical parameters including heavy metals (Cd, Cr, Cu, Fe, Ni, Pb, Fe and Zn) were determined in leachate samples and are reported. The concentrations of Cl-, NO3-, SO42-, NH4+ were found to be in considerable levels in the groundwater samples particularly near to the landfill sites, likely indicating that groundwater quality is being significantly affected by leachate percolation. Further they were proved to be the tracers for groundwater contamination near Semur and Vendipalayam dumpyards. The presence of contaminants in groundwater particularly near the landfill sites warns its quality and thus renders the associated aquifer unreliable for domestic water supply and other uses. Although some remedial measures are suggested to reduce further groundwater contamination via leachate percolation, the present study demands for the proper management of waste in Erode city. PMID:23369323

Use of bioassays for testing soils and/or sediments contaminated by mining activities

NASA Astrophysics Data System (ADS)

Pérez-Sirvent, C.; Martínez-Sánchez, M. J.; García-Lorenzo, M. L.; Molina, J.

2009-04-01

Ecotoxicity tests measure the bioavailability of the contaminants and the effects of the chemically not measured toxic compounds on the members of the soil community. Therefore, ecotoxicological testing may be a useful approach for assessing the toxicity as a complement to chemical analysis. They are solid phase tests based on terrestrial methods and tests performed on water extracts using aquatic test protocols. The extent and degree of heavy metal contamination around mines may vary depending on geochemical characteristics, the mineralization of tailings, physico-chemical conditions and the processes used to extract metals. Portman Bay was subject to mining from the time of the Roman Empire to 1991 when the activity ceased. Since 1957, the wastes from mining operations were discharged directly into the sea. These wastes mainly consisted of clay, quartz, siderite, magnetite, remains of sphalerite, pyrite and galena and residues of the chemical reagents used in floatation. In our study two methods of environmental toxicological tests were compared and applied to sediments of the Portman Bay (SE, Spain): the standardized toxicological test based on inhibition of luminescence employing Microtox

APPLICATION, PERFORMANCE, AND COSTS OF ...

EPA Pesticide Factsheets

A critical review of biological treatment processes for remediation of contaminated soils is presented. The focus of the review is on documented cost and performance of biological treatment technologies demonstrated at full- or field-scale. Some of the data were generated by the U.S. Environmental Protection Agency's (EPA's) Bioremediation in the Field Program, jointly supported by EPA's Office of Research and Development, EPA's Office of Solid Waste and Emergency Waste, and the EPA Regions through the Superfund Innovative Technology Evaluation Program (SITE) Program. Military sites proved to be another fertile data source. Technologies reviewed in this report include both ex-situ processes, (land treatment, biopile/biocell treatment, composting, and bioslurry reactor treatment) and in-situ alternatives (conventional bioventing, enhanced or cometabolic bioventing, anaerobic bioventing, bioslurping, phytoremediation, and natural attenuation). Targeted soil contaminants at the documented sites were primarily organic chemicals, including BTEX, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), chlorinated aliphatic hydrocarbons (CAHs), organic solvents, polychlorinated biphenyls (PCBs), pesticides, dioxin, and energetics. The advantages, limitations, and major cost drivers for each technology are discussed. Box and whisker plots are used to summarize before and after concentrations of important contaminant groups for those technologies consider

Public health assessment for Plymouth Avenue Landfill, Deland, Volusia County, Florida, Region 4. Cerclis No. FLD984167569. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-08-24

The Plymouth Avenue Landfill is about 1.75 miles west of the City of DeLand in rural western Volusia County, Florida. From 1971 to 1988 it was a Class I landfill and received all types of nonhazardous industrial and municipal solid waste. From June 1978 to October 1980, the landfill reportedly received 4,500 gallons per week of process waste slurry from the Brunswick Corporation. The authors selected the following contaminants of concern: barium, chromium, 1,2-dichloroethene, iron, nitrate, sulfate, and vinyl chloride. Ingestion of ground water is a past completed human exposure pathway. Concentrations of the contaminants of concern found so farmore » are unlikely to have caused illness in the nearby residents. Analysis of water samples has been inadequate, however, to assess the public health threat from ingestion of sulfate, giardia, or vinyl chloride. Based on the information currently available, the authors classify the public health hazard at this landfill as indeterminate. Groundwater sampling is needed to determine the extent of vinyl chloride contamination.« less

PCDD/Fs atmospheric deposition fluxes and soil contamination close to a municipal solid waste incinerator.

PubMed

Vassura, Ivano; Passarini, Fabrizio; Ferroni, Laura; Bernardi, Elena; Morselli, Luciano

2011-05-01

Bulk depositions and surface soil were collected in a suburban area, near the Adriatic Sea, in order to assess the contribution of a municipal solid waste incinerator to the area's total contamination with polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDDs and PCDFs). Samples were collected at two sites, situated in the area most affected by plant emissions (according to the results of the Calpuff air dispersion model), and at an external site, considered as a reference. Results show that the studied area is subject to low contamination, as far as these compounds are concerned. Deposition fluxes range from 14.3 pg m(-2)d(-1) to 89.9 pg m(-2)d(-1) (0.75 pg-TEQ m(-2)d(-1) to 3.73 pg-TEQ m(-2)d(-1)) and no significant flow differences are observed among the three monitored sites. Total soil concentration amounts to 93.8 ng kg(-1) d.w. and 1.35 ng-TEQ kg(-1)d.w, on average, and confirms a strong homogeneity in the studied area. Furthermore, from 2006 to 2009, no PCDD/Fs enrichment in the soil was noticed. Comparing the relative congener distributions in environmental samples with those found in stack emissions from the incineration plant, significant differences are observed in the PCDD:PCDF ratio and in the contribution of the most chlorinated congeners. From this study we can conclude that the incineration plant is not the main source of PCDD/Fs in the studied area, which is apparently characterized by a homogeneous and widespread contamination situation, typical of an urban area. Copyright © 2011 Elsevier Ltd. All rights reserved.

A pilot-scale steam autoclave system for treating municipal solid waste for recovery of renewable organic content: Operational results and energy usage.

PubMed

Holtman, Kevin M; Bozzi, David V; Franqui-Villanueva, Diana; Offeman, Richard D; Orts, William J

2016-05-01

A pilot-scale (1800 kg per batch capacity) autoclave used in this study reduces municipal solid waste to a debris contaminated pulp product that is efficiently separated into its renewable organic content and non-renewable organic content fractions using a rotary trommel screen. The renewable organic content can be recovered at nearly 90% efficiency and the trommel rejects are also much easier to sort for recovery. This study provides the evaluation of autoclave operation, including mass and energy balances for the purpose of integration into organic diversion systems. Several methods of cooking municipal solid waste were explored from indirect oil heating only, a combination of oil and direct steam during the same cooking cycle, and steam only. Gross energy requirements averaged 1290 kJ kg(-1) material in vessel, including the weight of free water and steam added during heating. On average, steam recovery can recoup 43% of the water added and 30% of the energy, supplying on average 40% of steam requirements for the next cook. Steam recycle from one vessel to the next can reduce gross energy requirements to an average of 790 kJ kg(-1). © The Author(s) 2016.

HIGH TEMPERATURE TREATMENT OF INTERMEDIATE-LEVEL RADIOACTIVE WASTES - SIA RADON EXPERIENCE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sobolev, I.A.; Dmitriev, S.A.; Lifanov, F.A.

2003-02-27

This review describes high temperature methods of low- and intermediate-level radioactive waste (LILW) treatment currently used at SIA Radon. Solid and liquid organic and mixed organic and inorganic wastes are subjected to plasma heating in a shaft furnace with formation of stable leach resistant slag suitable for disposal in near-surface repositories. Liquid inorganic radioactive waste is vitrified in a cold crucible based plant with borosilicate glass productivity up to 75 kg/h. Radioactive silts from settlers are heat-treated at 500-700 0C in electric furnace forming cake following by cake crushing, charging into 200 L barrels and soaking with cement grout. Variousmore » thermochemical technologies for decontamination of metallic, asphalt, and concrete surfaces, treatment of organic wastes (spent ion-exchange resins, polymers, medical and biological wastes), batch vitrification of incinerator ashes, calcines, spent inorganic sorbents, contaminated soil, treatment of carbon containing 14C nuclide, reactor graphite, lubricants have been developed and implemented.« less

Trends in sustainable landfilling in Malaysia, a developing country.

PubMed

Fauziah, S H; Agamuthu, P

2012-07-01

In Malaysia, landfills are being filled up rapidly due to the current daily generation of approximately 30,000 tonnes of municipal solid waste. This situation creates the crucial need for improved landfilling practices, as sustainable landfilling technology is yet to be achieved here. The objective of this paper is to identify and evaluate the development and trends in landfilling practices in Malaysia. In 1970, the disposal sites in Malaysia were small and prevailing waste disposal practices was mere open-dumping. This network of relatively small dumps, typically located close to population centres, was considered acceptable for a relatively low population of 10 million in Malaysia. In the 1980s, a national programme was developed to manage municipal and industrial wastes more systematically and to reduce adverse environmental impacts. The early 1990s saw the privatization of waste management in many parts of Malaysia, and the establishment of the first sanitary landfills for MSW and an engineered landfill (called 'secure landfill' in Malaysia) for hazardous waste. A public uproar in 2007 due to contamination of a drinking water source from improper landfilling practices led to some significant changes in the government's policy regarding the country's waste management strategy. Parliament passed the Solid Waste and Public Cleansing Management (SWPCM) Act 2007 in August 2007. Even though the Act is yet to be implemented, the government has taken big steps to improve waste management system further. The future of the waste management in Malaysia seems somewhat brighter with a clear waste management policy in place. There is now a foundation upon which to build a sound and sustainble waste management and disposal system in Malaysia.

40 CFR 257.3 - Criteria for classification of solid waste disposal facilities and practices.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities and Practices § 257.3 Criteria for classification of solid waste disposal facilities and practices. Solid waste disposal facilities or practices...

40 CFR 257.3 - Criteria for classification of solid waste disposal facilities and practices.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities and Practices § 257.3 Criteria for classification of solid waste disposal facilities and practices. Solid waste disposal facilities or practices...

Integrated, flexible, and rapid geophysical surveying

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, S.F.; McGinnis, L.D.; Thompson, M.D.

1993-01-01

Aberdeen Proving Ground (APG), in the state of Maryland (Figure 1), is currently managing a comprehensive Installation Restoration Program involving more than 360 solid-waste managing units contained within 13 study areas. The Edgewood area and two landfills in the Aberdeen area appear on the National Priority List under the Comprehensive Environmental Response, Compensation, and Liability Act. Therefore, APG has entered into an interagency agreement with the US Environmental Protection Agency to address the listed areas. The West Branch of the Canal Creek area (Figure 1), located within the Edgewood area, is one of the areas that requires a Source Definitionmore » Study because there is an ongoing release of volatile organic compounds into the creek. A report prepared by EAI Corporation (1989) included a list of 29 potentially contaminated buildings in the Edgewood area. Sixteen of the buildings contain known contaminants, nine buildings contain unknown contaminants, and four of the buildings are potentially clean. The EAI report recommended that a sampling and monitoring program be established to verify contamination levels in and around each building. Thirteen of the potentially contaminated buildings are in the West Branch of the Canal Creek area and are potential sources of volatile organic compounds. Operations have ceased and the buildings have been abandoned, but processing equipment, sumps, drains, ventilation systems, and underground storage tanks remain. These appurtenances may contain liquid, solid, or vapor contaminants of unknown nature.« less

Integrated, flexible, and rapid geophysical surveying

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, S.F.; McGinnis, L.D.; Thompson, M.D.

1993-03-01

Aberdeen Proving Ground (APG), in the state of Maryland (Figure 1), is currently managing a comprehensive Installation Restoration Program involving more than 360 solid-waste managing units contained within 13 study areas. The Edgewood area and two landfills in the Aberdeen area appear on the National Priority List under the Comprehensive Environmental Response, Compensation, and Liability Act. Therefore, APG has entered into an interagency agreement with the US Environmental Protection Agency to address the listed areas. The West Branch of the Canal Creek area (Figure 1), located within the Edgewood area, is one of the areas that requires a Source Definitionmore » Study because there is an ongoing release of volatile organic compounds into the creek. A report prepared by EAI Corporation (1989) included a list of 29 potentially contaminated buildings in the Edgewood area. Sixteen of the buildings contain known contaminants, nine buildings contain unknown contaminants, and four of the buildings are potentially clean. The EAI report recommended that a sampling and monitoring program be established to verify contamination levels in and around each building. Thirteen of the potentially contaminated buildings are in the West Branch of the Canal Creek area and are potential sources of volatile organic compounds. Operations have ceased and the buildings have been abandoned, but processing equipment, sumps, drains, ventilation systems, and underground storage tanks remain. These appurtenances may contain liquid, solid, or vapor contaminants of unknown nature.« less

Measurement of polychlorinated biphenyls in solid waste such as transformer insulation paper by supercritical fluid extraction and gas chromatography electron capture detection.

PubMed

Chikushi, Hiroaki; Fujii, Yuka; Toda, Kei

2012-09-21

In this work, a method for measuring polychlorinated biphenyls (PCBs) in contaminated solid waste was investigated. This waste includes paper that is used in electric transformers to insulate electric components. The PCBs in paper sample were extracted by supercritical fluid extraction and analyzed by gas chromatography-electron capture detection. The recoveries with this method (84-101%) were much higher than those with conventional water extraction (0.08-14%), and were comparable to those with conventional organic solvent extraction. Limit of detection was 0.0074 mg kg(-1) and measurable up to 2.5 mg kg(-1) for 0.5 g of paper sample. Data for real insulation paper by the proposed method agreed well with those by the conventional organic solvent extraction. Extraction from wood and concrete was also investigated and good performance was obtained as well as for paper samples. The supercritical fluid extraction is simpler, faster, and greener than conventional organic solvent extraction. Copyright © 2012 Elsevier B.V. All rights reserved.

Decontamination of uranium-contaminated waste oil using supercritical fluid and nitric acid.

PubMed

Sung, Jinhyun; Kim, Jungsoo; Lee, Youngbae; Seol, Jeunggun; Ryu, Jaebong; Park, Kwangheon

2011-07-01

The waste oil used in nuclear fuel processing is contaminated with uranium because of its contact with materials or environments containing uranium. Under current law, waste oil that has been contaminated with uranium is very difficult to dispose of at a radioactive waste disposal site. To dispose of the uranium-contaminated waste oil, the uranium was separated from the contaminated waste oil. Supercritical R-22 is an excellent solvent for extracting clean oil from uranium-contaminated waste oil. The critical temperature of R-22 is 96.15 °C and the critical pressure is 49.9 bar. In this study, a process to remove uranium from the uranium-contaminated waste oil using supercritical R-22 was developed. The waste oil has a small amount of additives containing N, S or P, such as amines, dithiocarbamates and dialkyldithiophosphates. It seems that these organic additives form uranium-combined compounds. For this reason, dissolution of uranium from the uranium-combined compounds using nitric acid was needed. The efficiency of the removal of uranium from the uranium-contaminated waste oil using supercritical R-22 extraction and nitric acid treatment was determined.

Solid Waste Management Plan. Revision 4

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-04-26

The waste types discussed in this Solid Waste Management Plan are Municipal Solid Waste, Hazardous Waste, Low-Level Mixed Waste, Low-Level Radioactive Waste, and Transuranic Waste. The plan describes for each type of solid waste, the existing waste management facilities, the issues, and the assumptions used to develop the current management plan.

Compost: Brown gold or toxic trouble?

USGS Publications Warehouse

Kovacic, D.A.; Cahill, R.A.; Bicki, T.J.

1992-01-01

Limited data are available regarding the occurrence of potentially hazardous constituents in raw, uncomposted yard wastes, partially composted yard wastes, and finished compost (15, 16). Environmental monitoring at composting operations or facilities is lacking, and currently published research on the environmental fate of composted yard waste constituents is extremely limited. The cost of thoroughly investigating the fate of toxicants in yard waste may seem needlessly expensive, but it is much less than the cost of cleaning up contaminated sites and groundwater. Could yard waste compost sites become Superfund sites? The cost of a thorough testing program throughout the United States may be several million dollars, but that is only a fraction of the funds spent initiating and developing yard waste composting facilities, let alone the potentially much greater cost of environmental remediation. There is still time to address these problems and to develop sound state and federal guidelines for siting and operating yard waste compost facilities. The rush to implement landfill alternatives such as composting should not be the major driving force in determining legislation governing solid waste management. ?? 1991 American Chemical Society.

36 CFR 13.1008 - Solid waste disposal.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Solid waste disposal. 13.1008... § 13.1008 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be...

36 CFR 13.1604 - Solid waste disposal.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Solid waste disposal. 13.1604... Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be located within one...

36 CFR 13.1118 - Solid waste disposal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1118... Provisions § 13.1118 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may...

36 CFR 13.1604 - Solid waste disposal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1604... Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be located within one...

36 CFR 13.1912 - Solid waste disposal.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Solid waste disposal. 13.1912....1912 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be located...

36 CFR 13.1008 - Solid waste disposal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1008... § 13.1008 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be...

36 CFR 13.1118 - Solid waste disposal.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Solid waste disposal. 13.1118... Provisions § 13.1118 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may...

On-Site Incineration of Contaminated Soil: A Study into U.S. Navy Applications

DTIC Science & Technology

1991-08-01

venturi scrubber Minimum water flow rate and p1l to absorber Minimum water/alkaline reagent flow to dry scrubber Minimum particulate scrubber blowdown...remove hydrochloric acid and sulfur dioxide from flue gases using, for example, wet scrubbers and limestone adsorption towers, respectively. Modified...Reagent preparation 8) Bllending 26) Fugitive emission control 9) Pretreatment 27) Scrubber liquid cooling 10) Blended and pretreated solid waste

Proven Alternatives for Aboveground Treatment of Arsenic in Groundwater

DTIC Science & Technology

2002-10-01

Contaminant of Concern by Mediaa Media Number of Sites Groundwater 380 Soil 372 Sediment 154 Surface Water 86 Debris 77 Sludge 45 Solid Waste 30 Leachate ...issue paper does not address three technologies that have been used to treat water containing arsenic: • Biological treatment • Phytoremediation ...arsenic in water, and no aboveground treatments of groundwater conducted at full scale were found. Phytoremediation and electrokinetics are not

Contamination valuation of soil and groundwater source at anaerobic municipal solid waste landfill site.

PubMed

Aziz, Shuokr Qarani; Maulood, Yousif Ismael

2015-12-01

The present work aimed to determine the risks that formed landfill leachate from anaerobic Erbil Landfill Site (ELS) poses on groundwater source and to observe the effects of disposed municipal solid waste (MSW) on soil properties. The study further aims to fill the gap in studies on the effects of disposed MSW and produced leachate on the groundwater characteristics and soil quality at ELS, Iraq. Soil, leachate, and groundwater samples were collected from ELS for use as samples in this study. Unpolluted groundwater samples were collected from an area outside of the landfill. Field and laboratory experiments for the soil samples were conducted. Chemical analyses for the soil samples such as organic matter, total salts, and SO4 (=) were also performed. Raw leachate and groundwater samples were analyzed using physical and chemical experiments. The yields for sorptivity, steady-state infiltration rate, and hydraulic conductivity of the soil samples were 0.0006 m/√s, 0.00004 m/s, and 2.17 × 10(-5) m/s, respectively. The soil at ELS was found to be light brown clayey gravel with sand and light brown gravely lean clay layers with low permeability. Unprocessed leachate analysis identified the leachate as stabilized. Findings showed that the soil and groundwater at the anaerobic ELS were contaminated.

Ground-penetrating radar (GPR) responses for sub-surface salt contamination and solid waste: modeling and controlled lysimeter studies.

PubMed

Wijewardana, Y N S; Shilpadi, A T; Mowjood, M I M; Kawamoto, K; Galagedara, L W

2017-02-01

The assessment of polluted areas and municipal solid waste (MSW) sites using non-destructive geophysical methods is timely and much needed in the field of environmental monitoring and management. The objectives of this study are (i) to evaluate the ground-penetrating radar (GPR) wave responses as a result of different electrical conductivity (EC) in groundwater and (ii) to conduct MSW stratification using a controlled lysimeter and modeling approach. A GPR wave simulation was carried out using GprMax2D software, and the field test was done on two lysimeters that were filled with sand (Lysimeter-1) and MSW (Lysimeter-2). A Pulse EKKO-Pro GPR system with 200- and 500-MHz center frequency antennae was used to collect GPR field data. Amplitudes of GPR-reflected waves (sub-surface reflectors and water table) were studied under different EC levels injected to the water table. Modeling results revealed that the signal strength of the reflected wave decreases with increasing EC levels and the disappearance of the subsurface reflection and wave amplitude reaching zero at higher EC levels (when EC >0.28 S/m). Further, when the EC level was high, the plume thickness did not have a significant effect on the amplitude of the reflected wave. However, it was also found that reflected signal strength decreases with increasing plume thickness at a given EC level. 2D GPR profile images under wet conditions showed stratification of the waste layers and relative thickness, but it was difficult to resolve the waste layers under dry conditions. These results show that the GPR as a non-destructive method with a relatively larger sample volume can be used to identify highly polluted areas with inorganic contaminants in groundwater and waste stratification. The current methods of MSW dumpsite investigation are tedious, destructive, time consuming, costly, and provide only point-scale measurements. However, further research is needed to verify the results under heterogeneous aquifer conditions and complex dumpsite conditions.

Global capacity, potentials and trends of solid waste research and management.

PubMed

Nwachukwu, Michael A; Ronald, Mersky; Feng, Huan

2017-09-01

In this study, United States, China, India, United Kingdom, Nigeria, Egypt, Brazil, Italy, Germany, Taiwan, Australia, Canada and Mexico were selected to represent the global community. This enabled an overview of solid waste management worldwide and between developed and developing countries. These are countries that feature most in the International Conference on Solid Waste Technology and Management (ICSW) over the past 20 years. A total of 1452 articles directly on solid waste management and technology were reviewed and credited to their original country of research. Results show significant solid waste research potentials globally, with the United States leading by 373 articles, followed by India with 230 articles. The rest of the countries are ranked in the order of: UK > Taiwan > Brazil > Nigeria > Italy > Japan > China > Canada > Germany >Mexico > Egypt > Australia. Global capacity in solid waste management options is in the order of: Waste characterisation-management > waste biotech/composting > waste to landfill > waste recovery/reduction > waste in construction > waste recycling > waste treatment-reuse-storage > waste to energy > waste dumping > waste education/public participation/policy. It is observed that the solid waste research potential is not a measure of solid waste management capacity. The results show more significant research impacts on solid waste management in developed countries than in developing countries where economy, technology and society factors are not strong. This article is targeted to motivate similar study in each country, using solid waste research articles from other streamed databases to measure research impacts on solid waste management.

Supercritical fluid extraction

DOEpatents

Wai, Chien M.; Laintz, Kenneth

1994-01-01

A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

Long-Term (2002-2015) Changes in Mercury Contamination in NE Brazil Depicted by the Mangrove Oyster Crassostraea rhizophorae (Guilding, 1828).

PubMed

Rios, J H L; Marins, R V; Oliveira, K F; Lacerda, L D

2016-10-01

Mercury concentrations in oysters from four estuaries in northeastern Brazil varied following source changes during the past 13 years. Concentrations were higher in urban estuaries relative to rural areas, but decreased in the 13-years interval following improvements in solid wastes disposal and sewage treatment. In rural estuaries, the one located in an environmental protection area showed no changes in Hg concentrations in the period. However, in the Jaguaribe estuary, remobilization from soils and sediments due to regional environmental changes, increased Hg concentrations in oysters to values similar to the most contaminated metropolitan sites.

Integrated models for solid waste management in tourism regions: Langkawi Island, Malaysia.

PubMed

Shamshiry, Elmira; Nadi, Behzad; Mokhtar, Mazlin Bin; Komoo, Ibrahim; Hashim, Halimaton Saadiah; Yahaya, Nadzri

2011-01-01

The population growth, changing consumption patterns, and rapid urbanization contribute significantly to the growing volumes of solid waste that are generated in urban settings. As the rate of urbanization increases, demand on the services of solid waste management increases. The rapid urban growth in Langkawi Island, Malaysia, combined with the increasing rates of solid waste production has provided evidence that the traditional solid waste management practices, particularly the methods of waste collection and disposal, are inefficient and quite nonsustainable. Accordingly, municipal managers and planners in Langkawi need to look for and adopt a model for solid waste management that emphasizes an efficient and sustainable management of solid wastes in Langkawi Island. This study presents the current practices of solid waste management in Langkawi Island, describes the composition of the solid waste generated in that area, and presents views of local residents and tourist on issues related to solid waste management like the aesthetic value of the island environment. The most important issue of this paper is that it is the first time that integrated solid waste management is investigated in the Langkawi Island.

Integrated Models for Solid Waste Management in Tourism Regions: Langkawi Island, Malaysia

PubMed Central

Shamshiry, Elmira; Nadi, Behzad; Bin Mokhtar, Mazlin; Komoo, Ibrahim; Saadiah Hashim, Halimaton; Yahaya, Nadzri

2011-01-01

The population growth, changing consumption patterns, and rapid urbanization contribute significantly to the growing volumes of solid waste that are generated in urban settings. As the rate of urbanization increases, demand on the services of solid waste management increases. The rapid urban growth in Langkawi Island, Malaysia, combined with the increasing rates of solid waste production has provided evidence that the traditional solid waste management practices, particularly the methods of waste collection and disposal, are inefficient and quite nonsustainable. Accordingly, municipal managers and planners in Langkawi need to look for and adopt a model for solid waste management that emphasizes an efficient and sustainable management of solid wastes in Langkawi Island. This study presents the current practices of solid waste management in Langkawi Island, describes the composition of the solid waste generated in that area, and presents views of local residents and tourist on issues related to solid waste management like the aesthetic value of the island environment. The most important issue of this paper is that it is the first time that integrated solid waste management is investigated in the Langkawi Island. PMID:21904559

Transformation of arsenic in the presence of cow dung and arsenic sludge disposal and management strategy in Bangladesh

NASA Astrophysics Data System (ADS)

Rahman, Mohammad Azizur; Jalil, Md. Abdul; Ali, M. Ashraf

2014-10-01

With increasing use of arsenic (As) removal units for treatment of As-contaminated groundwater in rural Bangladesh, concerns have been raised regarding safe disposal of the As-rich wastes from such units and possible contamination of the environment. In the absence of any clear guideline for safe disposal of wastes generated from As removal units, the wastes are usually disposed of in the open environment, often on cow dung beds in the backyard. Short term (up to 6 weeks) batch experiments performed in this study suggest that bio-chemical (e.g., bio-methylation) processes in the presence of only fresh cow dung may lead to a significant removal of As, both from aqueous solution and As-rich treatment wastes. Arsenic removal appears to increase with decreasing As to cow dung weight ratio. This study also suggests that arsenate transforms to arsenite before removal from aqueous As solution in the presence of cow dung. In most cases majority of As removal takes place during first few days. Removal of As under cap-open (to facilitate aerobic condition) and cap-closed conditions (to facilitate aerobic condition) were found to be similar. No significant variation was observed in the removal As from aqueous solution and from treatment wastes (As bound to iron solids). This study concludes that disposal of As-rich treatment wastes to cow dung pits could be an effective option of As sludge disposal and management in rural areas of Bangladesh.

INDEPENDENT TECHNICAL REVIEW OF THE FOCUSED FEASIBILITY STUDY AND PROPOSED PLAN FOR DESIGNATED SOLID WASTE MANAGEMENT UNITS CONTRIBUTING TO THE SOUTHWEST GROUNDWATER PLUME AT THE PADUCAH GASEOUS DIFFUSION PLANT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Looney, B.; Eddy-Dilek, C.; Amidon, M.

2011-05-31

The U. S. Department of Energy (DOE) is currently developing a Proposed Plan (PP) for remediation of designated sources of chlorinated solvents that contribute contamination to the Southwest (SW) Groundwater Plume at the Paducah Gaseous Diffusion Plant (PGDP), in Paducah, KY. The principal contaminants in the SW Plume are trichloroethene (TCE) and other volatile organic compounds (VOCs); these industrial solvents were used and disposed in various facilities and locations at PGDP. In the SW plume area, residual TCE sources are primarily in the fine-grained sediments of the Upper Continental Recharge System (UCRS), a partially saturated zone that delivers contaminants downwardmore » into the coarse-grained Regional Gravel Aquifer (RGA). The RGA serves as the significant lateral groundwater transport pathway for the plume. In the SW Plume area, the four main contributing TCE source units are: (1) Solid Waste Management Unit (SWMU) 1 / Oil Landfarm; (2) C-720 Building TCE Northeast Spill Site (SWMU 211A); (3) C-720 Building TCE Southeast Spill Site (SWMU 211B); and (4) C-747 Contaminated Burial Yard (SWMU 4). The PP presents the Preferred Alternatives for remediation of VOCs in the UCRS at the Oil Landfarm and the C-720 Building spill sites. The basis for the PP is documented in a Focused Feasibility Study (FFS) (DOE, 2011) and a Site Investigation Report (SI) (DOE, 2007). The SW plume is currently within the boundaries of PGDP (i.e., does not extend off-site). Nonetheless, reasonable mitigation of the multiple contaminant sources contributing to the SW plume is one of the necessary components identified in the PGDP End State Vision (DOE, 2005). Because of the importance of the proposed actions DOE assembled an Independent Technical Review (ITR) team to provide input and assistance in finalizing the PP.« less

Reclamation with Recovery of Radionuclides and Toxic Metals from Contaminated Materials, Soils, and Wastes

NASA Technical Reports Server (NTRS)

Francis, A. J.; Dodge, C. J.

1993-01-01

A process has been developed at Brookhaven National Laboratory (BNL) for the removal of metals and radionuclides from contaminated materials, soils, and waste sites. In this process, citric acid, a naturally occurring organic complexing agent, is used to extract metals such as Ba, Cd, Cr, Ni, Zn, and radionuclides Co, Sr, Th, and U from solid wastes by formation of water soluble, metal-citrate complexes. Citric acid forms different types of complexes with the transition metals and actinides, and may involve formation of a bidentate, tridentate, binuclear, or polynuclear complex species. The extract containing radionuclide/metal complex is then subjected to microbiological degradation followed by photochemical degradation under aerobic conditions. Several metal citrate complexes are biodegraded, and the metals are recovered in a concentrated form with the bacterial biomass. Uranium forms binuclear complex with citric acid and is not biodegraded. The supernatant containing uranium citrate complex is separated and upon exposure to light, undergoes rapid degradation resulting in the formation of an insoluble, stable polymeric form of uranium. Uranium is recovered as a precipitate (polyuranate) in a concentrated form for recycling or for appropriate disposal. This treatment process, unlike others which use caustic reagents, does not create additional hazardous wastes for disposal and causes little damage to soil which can then be returned to normal use.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nichols, Ralph L.; Seitz, Roger R.; Dixon, Kenneth L.

The Waste Treatment and Immobilization Plant (WTP) at Hanford is being constructed to treat 56 million gallons of radioactive waste currently stored in underground tanks at the Hanford site. Operation of the WTP will generate several solid secondary waste (SSW) streams including used process equipment, contaminated tools and instruments, decontamination wastes, high-efficiency particulate air filters (HEPA), carbon adsorption beds, silver mordenite iodine sorbent beds, and spent ion exchange resins (IXr) all of which are to be disposed in the Integrated Disposal Facility (IDF). An applied research and development program was developed using a phased approach to incrementally develop the informationmore » necessary to support the IDF PA with each phase of the testing building on results from the previous set of tests and considering new information from the IDF PA calculations. This report contains the results from the exploratory phase, Phase 1 and preliminary results from Phase 2. Phase 3 is expected to begin in the fourth quarter of FY17.« less

Superfund Record of Decision (EPA Region 7): Vogel Paint and Wax, Maurice, IA. (First remedial action), September 1989. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1989-09-20

The Vogel Paint and Wax (VPW) site is an approximately two-acre disposal area two miles southwest of the town of Maurice, in Sioux County, Iowa. Adjacent land uses are primarily agricultural; however, several private residences are within one-quarter mile of the site. A surficial sand and gravel aquifer underlies the site and supplies nearby private wells and the Southern Sioux County Rural Water System, located a mile and one half southeast of the site. Paint sludge, resins, solvents, and other paint-manufacturing wastes were disposed of at the site between 1971 and 1979. VPW records indicate that approximately 43,000 gallons ofmore » aliphatic and aromatic hydrocarbons and 6,000 pounds of metals waste were buried at the site. The primary contaminants of concern affecting the soil and ground water are VOCs including benzene, toluene, and xylenes; and metals including chromium and lead. The selected remedial action for this site includes excavation of contaminated soil and separation of solid and liquid wastes; onsite bioremediation of 3,000 cubic yards of the contaminated soil in a fully contained surface impoundment unit, or onsite thermal treatment if soil contains high metal content; and stabilization of treated soil, if necessary to prevent leaching of metals, followed by disposal in the excavated area.« less

Role of organic amendments on enhanced bioremediation of heavy metal(loid) contaminated soils.

PubMed

Park, Jin Hee; Lamb, Dane; Paneerselvam, Periyasamy; Choppala, Girish; Bolan, Nanthi; Chung, Jae-Woo

2011-01-30

As land application becomes one of the important waste utilization and disposal practices, soil is increasingly being seen as a major source of metal(loid)s reaching food chain, mainly through plant uptake and animal transfer. With greater public awareness of the implications of contaminated soils on human and animal health there has been increasing interest in developing technologies to remediate contaminated sites. Bioremediation is a natural process which relies on soil microorganisms and higher plants to alter metal(loid) bioavailability and can be enhanced by addition of organic amendments to soils. Large quantities of organic amendments, such as manure compost, biosolid and municipal solid wastes are used as a source of nutrients and also as a conditioner to improve the physical properties and fertility of soils. These organic amendments that are low in metal(loid)s can be used as a sink for reducing the bioavailability of metal(loid)s in contaminated soils and sediments through their effect on the adsorption, complexation, reduction and volatilization of metal(loid)s. This review examines the mechanisms for the enhanced bioremediation of metal(loid)s by organic amendments and discusses the practical implications in relation to sequestration and bioavailability of metal(loid)s in soils. Copyright © 2010 Elsevier B.V. All rights reserved.

Airborne microorganisms from waste containers.

PubMed

Jedlicka, Sabrina S; Stravitz, David M; Lyman, Charles E

2012-01-01

In physician's offices and biomedical labs, biological waste is handled every day. This waste is disposed of in waste containers designed for holding red autoclave bags. The containers used in these environments are closed hands-free containers, often with a step pedal. While these containers protect the user from surface-borne microorganisms, the containers may allow airborne microorganisms to escape via the open/close mechanism because of the air current produced upon open/close cycles. In this study, the air current was shown to be sufficient to allow airborne escape of microorganisms held in the container, including Aspergillus niger. However, bacterial cultures, such as Escherichia coli and Lactococcus lactis did not escape. This may be due to the choice of bacterial cultures and the absence of solid waste, such as dust or other particulate matter in the waste containers, that such strains of bacteria could travel on during aerosolization. We compared these results to those obtained using a re-designed receptacle, which mimimizes air currents, and detected no escaping microorganisms. This study highlights one potential source of airborne contamination in labs, hospitals, and other environments that dispose of biological waste.

The management of arsenic wastes: problems and prospects.

PubMed

Leist, M; Casey, R J; Caridi, D

2000-08-28

Arsenic has found widespread use in agriculture and industry to control a variety of insect and fungicidal pests. Most of these uses have been discontinued, but residues from such activities, together with the ongoing generation of arsenic wastes from the smelting of various ores, have left a legacy of a large number of arsenic-contaminated sites. The treatment and/or removal of arsenic is hindered by the fact that arsenic has a variety of valence states. Arsenic is most effectively removed or stabilized when it is present in the pentavalent arsenate form. For the removal of arsenic from wastewater, coagulation, normally using iron, is the preferred option. The solidification/stabilization of arsenic is not such a clear-cut process. Factors such as the waste's interaction with the additives (e.g. iron or lime), as well as any effect on the cement matrix, all impact on the efficacy of the fixation. Currently, differentiation between available solidification/stabilization processes is speculative, partly due to the large number of differing leaching tests that have been utilized. Differences in the leaching fluid, liquid-to-solid ratio, and agitation time and method all impact significantly on the arsenic leachate concentrations. This paper reviews options available for dealing with arsenic wastes, both solid and aqueous through an investigation of the methods available for the removal of arsenic from wastewater as well as possible solidification/stabilization options for a variety of waste streams.

Contamination of soils and groundwater with new organic micropollutants: A review

NASA Astrophysics Data System (ADS)

Vodyanitskii, Yu. N.; Yakovlev, A. S.

2016-05-01

The input of organic micro- and nanopollutants to the environment has grown in recent years. This vast class of substances is referred to as emerging micropollutants, and includes organic chemicals of industrial, agricultural, and municipal provenance. There are three main sources of emerging pollutants coming to the environment, i.e., (1) upon soil fertilization with sewage and sewage sludge; (2) soil irrigation with reclaimed wastewater and (3) due to filtration from municipal landfills of solid wastes. These pollutants contaminate soil, affect its inhabitants; they are also consumed by plants and penetrate to the groundwater. The pharmaceuticals most strongly affect the biota (microorganisms, earthworms, etc.). The response of microorganisms in the contaminated soil is controlled not only by the composition and the number of emerging pollutants but also by the geochemical environment.

Heat Melt Compaction as an Effective Treatment for Eliminating Microorganisms from Solid Waste

NASA Technical Reports Server (NTRS)

Hummerick, Mary P.; Strayer, Richard; McCoy, LaShelle; Richard, Jeffrey; Ruby, Anna; Wheeler, Raymond

2012-01-01

One of the technologies being tested at Ames Research Center as part of the logistics and repurposing project is heat melt compaction (HMC) of solid waste to reduce volume, remove water and render a biologically stable and safe product. Studies at Kennedy Space Center have focused on the efficacy of the heat melt compaction process for killing microorganisms in waste and specific compacter operation protocols, i.e., time and temperature, required to achieve a sterile, stable product. The work reported here includes a controlled study to examine the survival and potential re-growth of specific microorganisms over a 6-month period of storage after heating and compaction. Before heating and compaction, ersatz solid wastes were inoculated with Bacillus amyloliquefaciens and Rhodotorula mucilaginosa, previously isolated from recovered space shuttle mission food and packaging waste. Compacted HMC tiles were sampled for microbiological analysis at time points between 0 and 180 days of storage in a controlled environment chamber. In addition, biological indicator strips containing spores of Bacillus atrophaeus and Ceo bacillus stearothermophilus were imbedded in trash to assess the efficacy of the HMC process to achieve sterilization. Analysis of several tiles compacted at 180 C for times of 40 minutes to over 2 hours detected organisms in all tile samples with the exception of one exposed to 180 C for approximately 2 hours. Neither of the inoculated organisms was recovered, and the biological indicator strips were negative for growth in all tiles indicating at least local sterilization of tile areas. The findings suggest that minimum time/temperature combination is required for complete sterilization. Microbial analysis of tiles processed at lower temperatures from 130 C-150 C at varying times will be discussed, as well as analysis of the bacteria and fungi present on the compactor hardware as a result of exposure to the waste and the surrounding environment. The two organisms inoculated into the waste were among those isolated and identified from the HMC surfaces indicating the possibility of cross contamination.

Leaching, geochemical modelling and field verification of a municipal solid waste and a predominantly non-degradable waste landfill.

PubMed

van der Sloot, H A; Kosson, D S; van Zomeren, A

2017-05-01

In spite of the known heterogeneity, wastes destined for landfilling can be characterised for their leaching behaviour by the same protocols as soil, contaminated soil, sediments, sludge, compost, wood, waste and construction products. Characterisation leaching tests used in conjunction with chemical speciation modelling results in much more detailed insights into release controlling processes and factors than single step batch leaching tests like TCLP (USEPA) and EN12457 (EU Landfill Directive). Characterisation testing also can provide the potential for mechanistic impact assessments by making use of a chemical speciation fingerprint (CSF) derived from pH dependence leaching test results. This CSF then forms the basis for subsequent chemical equilibrium and reactive transport modelling to assess environmental impact in a landfill scenario under relevant exposure conditions, including conditions not readily evaluated through direct laboratory testing. This approach has been applied to municipal solid waste (MSW) and predominantly non-degradable waste (PNW) that is representative of a significant part of waste currently being landfilled. This work has shown that a multi-element modelling approach provides a useful description of the release from each of these matrices because relevant release controlling properties and parameters (mineral dissolution/precipitation, sorption on Fe and Al oxides, clay interaction, interaction with dissolved and particulate organic carbon and incorporation in solid solutions) are taken into consideration. Inclusion of dissolved and particulate organic matter in the model is important to properly describe release of the low concentration trace constituents observed in the leachate. The CSF allows the prediction of release under different redox and degradation conditions in the landfill by modifying the redox status and level of dissolved and particulate organic matter in the model runs. The CSF for MSW provides a useful starting point for comparing leachate data from other MSW landfills. Copyright © 2016 Elsevier Ltd. All rights reserved.

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.30 Non-waste determinations and variances from classification as a solid waste. In...

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.30 Non-waste determinations and variances from classification as a solid waste. In...

A review on thermal and catalytic pyrolysis of plastic solid waste (PSW).

PubMed

Al-Salem, S M; Antelava, A; Constantinou, A; Manos, G; Dutta, A

2017-07-15

Plastic plays an important role in our daily lives due to its versatility, light weight and low production cost. Plastics became essential in many sectors such as construction, medical, engineering applications, automotive, aerospace, etc. In addition, economic growth and development also increased our demand and dependency on plastics which leads to its accumulation in landfills imposing risk on human health, animals and cause environmental pollution problems such as ground water contamination, sanitary related issues, etc. Hence, a sustainable and an efficient plastic waste treatment is essential to avoid such issues. Pyrolysis is a thermo-chemical plastic waste treatment technique which can solve such pollution problems, as well as, recover valuable energy and products such as oil and gas. Pyrolysis of plastic solid waste (PSW) has gained importance due to having better advantages towards environmental pollution and reduction of carbon footprint of plastic products by minimizing the emissions of carbon monoxide and carbon dioxide compared to combustion and gasification. This paper presents the existing techniques of pyrolysis, the parameters which affect the products yield and selectivity and identify major research gaps in this technology. The influence of different catalysts on the process as well as review and comparative assessment of pyrolysis with other thermal and catalytic plastic treatment methods, is also presented. Copyright © 2017 Elsevier Ltd. All rights reserved.

Investigation of Ground-Water Contamination at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina

USGS Publications Warehouse

Vroblesky, Don A.; Casey, Clifton C.; Petkewich, Matthew D.; Lowery, Mark A.; Conlon, Kevin J.; Harrelson, Larry G.

2007-01-01

The U.S. Geological Survey and the Naval Facilities Engineering Command Southeast investigated natural and engineered remediation of chlorinated volatile organic compound ground-water contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina. The primary contaminants of interest are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. In general, the hydrogeology of Solid Waste Management Unit 12 consists of a surficial aquifer, composed of sand to clayey sand, overlain by dense clay that extends from about land surface to a depth of about 8 to 10 feet and substantially limits local recharge. During some months in the summer, evapotranspiration and limited local recharge result in ground-water level depressions in the forested area near wells 12MW-12S and 12MW-17S, seasonally reflecting the effects of evapotranspiration. Changes in surface-water levels following Hurricane Gaston in 2004 resulted in a substantial change in the ground-water levels at the site that, in turn, may have caused lateral shifting of the contaminant plume. Hydraulic conductivity, determined by slug tests, is higher along the axis of the plume in the downgradient part of the forests than adjacent to the plume, implying that there is some degree of lithologic control on the plume location. Hydraulic conductivity, hydraulic gradient, sulfur-hexafluoride measurements, and historical data indicate that ground-water flow rates are substantially slower in the forested area relative to upgradient areas. The ground-water contamination, consisting of chlorinated volatile organic compounds, extends eastward in the surficial aquifer from the probable source area near a former underground storage tank. Engineered remediation approaches include a permeable reactive barrier and phytoremediation. The central part of the permeable reactive barrier along the main axis of the contaminant plume appears to be actively removing contamination; however, ground-water contamination is moving around the southern end of the permeable reactive barrier. Changes in the contaminant concentrations along the path of ground-water transport reflect a complex variety of influences. Potential influences include dechlorination, sorption and desorption, transpirative removal by trees, lateral shifting of the plume, and the presence of zones of differing concentrations possibly reflecting one or more pulse releases of contamination from the source area. Near the source area at well 12MW-10S, volatile organic compound concentrations of cis-1,2-dichlorothene, vinyl chloride, 1,1-dichloroethane, and 1,1,1-trichloroethane continued an irregular decline, while tetrachloroethene and 1,1-dichloroethene showed marked fluctuations in concentration during 2005 and 2006. Volatile organic compound concentrations at well 12MW-03S continued to show decreasing concentrations with the June 2006 concentrations being the lowest yet recorded at that well for several volatile organic compounds. Concentration and delta carbon 13 data indicate that in the upgradient part of the plume, tetrachloroethene is being degraded to trichloroethene, which is being degraded to cis-1,2-dichloroethene, and cis-1,2-dichloroethene is accumulating faster than it is being depleted. Ground-water volatile organic compound concentrations also changed in some wells in the forested area in the midpart of the plume. Increasing tetrachloroethene and decreasing trichloroethene and 1,1-dichloroethene concentrations were observed at wells 12MW-05S and 12MW-29S, possibly reflecting a lateral shift in the axis of the contamination plume or an advancing contamination pulse. Substantial decreases in contamination occur in the forested area downgradient from well 12MW-05S. Probable major loss mechanisms in this area include evapotranspiration and sorption.

A review of hydrologic and geologic conditions related to the radioactive solid-waste burial grounds at Oak Ridge National Laboratory, Tennessee

USGS Publications Warehouse

Webster, D.A.

1976-01-01

Solid waste contaminated by radioactive matter has been buried in the vicinity of Oak Ridge National Laboratory since 1944. By 1973, an estimated six million cubic feet of such material had been placed in six burial grounds in two valleys. The practice initially was thought of as a safe method for permanently removing these potentially hazardous substances from man's surroundings, but is now que.3tionable at this site because of known leaching of contaminants from the waste, transport in ground water, and release to the terrestrial and fluvial environments. This review attempts to bring together in a single document information from numerous published and unpublished sources regarding the past criteria used for selecting the Oak Ridge burial-ground sites, the historical development and conditions of these facilities as of 1974, the geologic framework of the Laboratory area and the movement of water and water-borne contaminants in that area, the effects of sorption and ion exchange upon radionuclide transport, and a description and evaluation of the existing monitoring system. It is intended to assist Atomic Energy Commission (now Energy Research and Development Administration) officials in the formulation of managerial decisions concerning the burial grounds and present monitoring methods. Sites for the first three burial grounds appear to have been chosen during and shortly after World War II on the basis of such factors as safety, security, and distance from sources of waste origin. By 1950, geologic criteria had been introduced, and in the latter part of that decade, geohydrologic criteria were considered. While no current criteria have been defined, it becomes evident from the historical record that the successful containment of radionuclides below land surface for long periods of time is dependent upon a complex interrelationship between many geologic, hydrologic, and geochemical controls, and any definition of criteria must include consideration of these factors. For the most part, the burial grounds have been developed by a simple cut and fill procedure similar to the operation of a municipal landfill. Low permeability of the residuum, high rainfall, shallow depth to ground water, the excavation of trenches below the water table, and other practices, have contributed to a condition of waste leaching in probably all of the burial grounds. Despite these conditions, only very small concentrations of radionuclides have been found in wells or otherwise attributed to the initial three, small sites in Bethel Valley. This fact, however, may be due in part to the scant extent of site monitoring of those burial grounds for transport of radionuclides in ground water, and to the discharge of liquid radioactive waste to the drainage in concentrations that probably would have masked the presence of contaminants derived from these burial grounds. In comparison to the Bethel Valley sites, larger amounts of radioactive contaminants have been found in wells, seeps, trench overflow, and the drainages that drain Burial Grounds 4 and 5 in Melton Valley. The movement of radionuclides from the trenches to the drainages show that the latter sites are not suitable for the retention of all contaminants under existing conditions, and invalidates the operational concept of long-term or permanent retention of all radionuclides in the geologic environment. The transport of many radioactive ions leached from the waste has been retarded by the very high sorptive and ion exchange capacity of the residuum with which the radionuclides have had contact. Not all radionuclides, though, will be retained in the subsurface by adsorption, absorption, or ion exchange. Among those radioactive contaminants that may be problematical with respect to trench burial at Oak Ridge are tritium and other negatively-charged nuclides, positively-charged radionuclides included in some of the complexed molecules, radioactive ions that have chemical properties si

Classification methodology for tritiated waste requiring interim storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cana, D.; Dall'ava, D.; Decanis, C.

2015-03-15

Fusion machines like the ITER experimental research facility will use tritium as fuel. Therefore, most of the solid radioactive waste will result not only from activation by 14 MeV neutrons, but also from contamination by tritium. As a consequence, optimizing the treatment process for waste containing tritium (tritiated waste) is a major challenge. This paper summarizes the studies conducted in France within the framework of the French national plan for the management of radioactive materials and waste. The paper recommends a reference program for managing this waste based on its sorting, treatment and packaging by the producer. It also recommendsmore » setting up a 50-year temporary storage facility to allow for tritium decay and designing future disposal facilities using tritiated radwaste characteristics as input data. This paper first describes this waste program and then details an optimized classification methodology which takes into account tritium decay over a 50-year storage period. The paper also describes a specific application for purely tritiated waste and discusses the set-up expected to be implemented for ITER decommissioning waste (current assumption). Comparison between this optimized approach and other viable detritiation techniques will be drawn. (authors)« less

Environmental Control and Life Support Systems for Mars Exploration: Issues and Concerns for Planetary Protection and the Protection of Science

NASA Astrophysics Data System (ADS)

Barta, Daniel J.; Lange, Kevin; Anderson, Molly; Vonau, Walter

2016-07-01

Planetary protection represents an additional set of requirements that generally have not been considered by developers of technologies for Environmental Control and Life Support Systems (ECLSS). Forward contamination concerns will affect release of gases and discharge of liquids and solids, including what may be left behind after planetary vehicles are abandoned upon return to Earth. A crew of four using a state of the art ECLSS could generate as much as 4.3 metric tons of gaseous, liquid and solid wastes and trash during a 500-day surface stay. These may present issues and concerns for both planetary protection and planetary science. Certainly, further closure of ECLSS systems will be of benefit by greater reuse of consumable products and reduced generation of waste products. It can be presumed that planetary protection will affect technology development by constraining how technologies can operate: limiting or prohibiting certain kinds of operations or processes (e.g. venting); necessitating that other kinds of operations be performed (e.g. sterilization; filtration of vent lines); prohibiting what can be brought on a mission (e.g. extremophiles); creating needs for new capabilities/ technologies (e.g. containment). Although any planned venting could include filtration to eliminate micro-organisms from inadvertently exiting the spacecraft, it may be impossible to eliminate or filter habitat structural leakage. Filtration will add pressure drops impacting size of lines and ducts, affect fan size and energy requirements, and add consumable mass. Technologies that may be employed to remove biomarkers and microbial contamination from liquid and solid wastes prior to storage or release may include mineralization technologies such as incineration, super critical wet oxidation and pyrolysis. These technologies, however, come with significant penalties for mass, power and consumables. This paper will estimate the nature and amounts of materials generated during Mars transit and surface stays that may be impacted by planetary protection requirements or be controlled for the protection of planetary science.

Evaluation of the effectiveness and mechanisms of acetaminophen and methylene blue dye adsorption on activated biochar derived from municipal solid wastes.

PubMed

Sumalinog, Divine Angela G; Capareda, Sergio C; de Luna, Mark Daniel G

2018-03-15

The adsorption potential and governing mechanisms of emerging contaminants, i.e. acetaminophen or acetyl-para-aminophenol (APAP) and methylene blue (MB) dye, on activated carbon derived from municipal solid waste were investigated in this work. Results showed that MB adsorption was significantly more effective, with a maximum removal of 99.9%, than APAP adsorption (%R max  = 63.7%). MB adsorption was found to be unaffected by pH change, while the adsorption capacity of APAP drastically dropped by about 89% when the pH was adjusted from pH 2 to 12. Surface reactions during APAP adsorption was dominated by both physical and chemical interactions, with the kinetic data showing good fit in both pseudo-first order (R 2  = 0.986-0.997) and pseudo-second order (R 2 >0.998) models. On the other hand, MB adsorption was best described by the pseudo-second order model, with R 2 >0.981, denoting that chemisorption controlled the process. Electrostatic attractions and chemical reactions with oxygenated surface functional groups (i.e., -OH and -COOH) govern the adsorption of APAP and MB on the activated biochar. Thermodynamic study showed that APAP and MB adsorption were endothermic with positive ΔH° values of 16.5 and 74.7 kJ mol -1 , respectively. Negative ΔG° values obtained for APAP (-3.7 to -5.1 kJ mol -1 ) and MB (-11.4 to -17.1 kJ mol -1 ) implied that the adsorption onto the activated biochar was spontaneous and feasible. Overall, the study demonstrates the effectiveness of activated biochar from municipal solid wastes as alternative adsorbent for the removal of acetaminophen and methylene blue dye from contaminated waters. Copyright © 2018 Elsevier Ltd. All rights reserved.

An ecotoxic risk assessment of residue materials produced by the plasma pyrolysis/vitrification (PP/V) process.

PubMed

Lapa, N; Santos, Oliveira J F; Camacho, S L; Circeo, L J

2002-01-01

Plasma is the fourth state of matter, following the three states of solid, liquid and gas. Experience has amply demonstrated that solids exposed to the oxygen-deficient plasma flame are converted to liquid, and liquid exposed to the same flame is converted to gas. A low amount of vitrified solid residue material usually remains at the end of this process. Plasma pyrolysis/vitrification (PP/V) has been demonstrated as a safe, efficient, cost-effective technology for the treatment of wastes, including hazardous wastes. Besides the low amounts of gaseous byproducts that PP/V produces, the solid vitrified residue presents a low leachability of pollutants. Studies have been performed in many countries in order to assess the leachability of chemical substances. But from the results of identified studies, none has reported results on the ecotoxicological properties of the leachates. The aim of this study was to contribute to the assessment of ecotoxic risk of four different vitrified materials. Vitrified samples of contaminated soils, municipal solid wastes, and incinerator bottom ashes were submitted to the European leaching pre-standard test number prEN 12457-2. The leachates were analyzed for 22 chemical parameters. The biological characterization comprised the assessment of bioluminescence inhibition of Photobacterium phosphoreum bacterium, growth inhibition of Pseudokirchneriella subcapitata algae and the germination inhibition of Lactuca sativa vegetable. The chemical and ecotoxicological results were analyzed according to the French proposal of Criteria on the Evaluation Methods of Waste Toxicity (CEMWT) and a Toxicity Classification System (TCS). The chemical and ecotoxicological results indicated a low leachability of pollutants and a low toxicity level of leachates. All samples studied were as below the TCS class 1 level (no significant toxicity observed) and as non-ecotoxic for CEMWT. Therefore, the environmental ecotoxic risk of the analyzed vitrified samples was determined to be very low.

Municipal Solid Waste Management: Recycling, Resource Recovery, and Landfills. LC Science Tracer Bullet.

ERIC Educational Resources Information Center

Meikle, Teresa, Comp.

Municipal solid waste refers to waste materials generated by residential, commercial, and institutional sources, and consists predominantly of paper, glass, metals, plastics, and food and yard waste. Within the definition of the Solid Waste Disposal Act, municipal solid waste does not include sewage sludge or hazardous waste. The three main…

Arsenic Remediation Enhancement Through Chemical Additions to Pump and Treat Operations

NASA Astrophysics Data System (ADS)

Wovkulich, K.; Mailloux, B. J.; Stute, M.; Simpson, H. J.; Keimowitz, A. R.; Powell, A.; Lacko, A.; Chillrud, S. N.

2008-12-01

Arsenic is a contaminant found at more than 500 US Superfund sites. Since pump and treat technologies are widely used for remediation of contaminated groundwater, increasing the efficiency of contaminant removal at such sites should allow limited financial resources to clean up more sites. The Vineland Chemical Company Superfund site is extensively contaminated with arsenic after waste arsenic salts were stored and disposed of improperly for much of the company's 44 year manufacturing lifetime. Despite approximately eight years of pump and treat remediation, arsenic concentrations in the recovery wells can still be greater than 1000 ppb. The arsenic concentrations in the groundwater remain high because of slow desorption of arsenic from contaminated aquifer solids. Extrapolation of laboratory column experiments suggest that continuing the current groundwater remediation practice based on flushing ambient groundwater through the system may require on the order of hundreds of years to clean the site. However, chemical additions of phosphate or oxalic acid into the aquifer could decrease the remediation time scale substantially. Laboratory results from a soil column experiment using input of 10 mM oxalic acid suggest that site clean up of groundwater could be decreased to as little as four years. Pilot scale forced gradient field experiments will help establish whether chemical additions can be effective for increasing arsenic mobilization from aquifer solids and thus substantially decrease pump and treat clean up time.

Health assessment for Cimarron Mining Corporation, Carrizozo, Lincoln County, New Mexico, Region 6. CERCLIS No. NMD980749378. Preliminary report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-05-09

The Cimarron Mining Corporation, an Update 7 National Priorities List site, is located in the southeastern section of Carrizozo, Lincoln County, New Mexico. From 1979 to 1982 the site was operated as a milling operation where precious metals were extracted from crushed iron ore by using either sodium cyanide or potassium cyanide mixed with a metal stripper in a leaching process. Currently the site is inactive; however, drums of sodium/potassium cyanide and solid metal stripping and recovery compounds remain on-site. Preliminary environmental monitoring data indicate chromium, cyanide, lead, and nitrate contamination of on-site groundwater, and cyanide contamination of on-site soil,more » tailings, and wastes. The most likely pathways for contaminant transport to off-site areas appear to be those associated with groundwater and soil. Pathways for human exposure to site-associated contaminants include ingestion of contaminated groundwater and soil and inhalation of contaminated dusts. The site is of potential public health concern because of possible human exposure to site contaminants.« less

Modeling of urban solid waste management system: The case of Dhaka city

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sufian, M.A.; Bala, B.K.

2007-07-01

This paper presents a system dynamics computer model to predict solid waste generation, collection capacity and electricity generation from solid waste and to assess the needs for waste management of the urban city of Dhaka, Bangladesh. Simulated results show that solid waste generation, collection capacity and electricity generation potential from solid waste increase with time. Population, uncleared waste, untreated waste, composite index and public concern are projected to increase with time for Dhaka city. Simulated results also show that increasing the budget for collection capacity alone does not improve environmental quality; rather an increased budget is required for both collectionmore » and treatment of solid wastes of Dhaka city. Finally, this model can be used as a computer laboratory for urban solid waste management (USWM) policy analysis.« less

Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics.

PubMed

Gug, JeongIn; Cacciola, David; Sobkowicz, Margaret J

2015-01-01

Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette sample composition was similar to biomass fuels but had significant advantages due to addition of waste plastics that have high energy content compared to other waste types. Addition of PP and HDPE presented better benefits than addition of PET due to lower softening temperature and lower oxygen content. It should be noted that while harmful emissions such as dioxins, furans and mercury can result from burning plastics, WTE facilities have been able to control these emissions to meet US EPA standards. This research provides a drop-in coal replacement that reduces demand on landfill space and replaces a significant fraction of fossil-derived fuel with a renewable alternative. Copyright © 2014 Elsevier Ltd. All rights reserved.

Contamination of water due to major industries and open refuse dumping in the steel city of Orissa--a case study.

PubMed

Mishra, P C; Behera, P C; Patel, R K

2005-04-01

Contamination of ground water is common in the areas surrounded by industrial refuse dumping sites and the probability of contamination is more where dumping is done in low lying areas and the rate of percolation through the soil is high. In order to assess the ground water pollution by leachate around the refuse dumping site, eighteen wells were selected for study. Few wells are nearer to the dumps, few are far away and others are in between. Also an attempt has been made to evaluate the effect of industrial effluents on the ground and surface water due to Integrated Rourkela Steel Plant and other major industries. From the analytical data of physico-chemical parameters, it is indicated that the river water is contaminated mainly due to the industrial and municipal effluents and the ground water of some of the analyzed areas is contaminated due to municipal and industrial solid waste dumping.

Removal of arsenic, phosphates and ammonia from well water using electrochemical/chemical methods and advanced oxidation: a pilot plant approach.

PubMed

Orescanin, Visnja; Kollar, Robert; Nad, Karlo; Halkijevic, Ivan; Kuspilic, Marin; Findri Gustek, Stefica

2014-01-01

The purpose of this work was to develop a pilot plant purification system and apply it to groundwater used for human consumption, containing high concentrations of arsenic and increased levels of phosphates, ammonia, mercury and color. The groundwater used was obtained from the production well in the Vinkovci County (Eastern Croatia). Due to a complex composition of the treated water, the purification system involved a combined electrochemical treatment, using iron and aluminum electrode plates with simultaneous ozonation, followed by a post-treatment with UV, ozone and hydrogen peroxide. The removal of the contaminant with the waste sludge collected during the electrochemical treatment was also tested. The combined electrochemical and advanced oxidation treatment resulted in the complete removal of arsenic, phosphates, color, turbidity, suspended solids and ammonia, while the removal of other contaminants of interest was up to 96.7%. Comparable removal efficiencies were obtained by using waste sludge as a coagulant.

Water quality assessment for groundwater around a municipal waste dumpsite.

PubMed

Kayode, Olusola T; Okagbue, Hilary I; Achuka, Justina A

2018-04-01

The dataset for this article contains geostatistical analysis of the level to which groundwater quality around a municipal waste dumpsite located in Oke-Afa, Oshodi/Isolo area of Lagos state, southwestern has been compromised for drinking. Groundwater samples were collected from eight hand-dug wells and two borehole wells around or near the dumpsite. The pH, turbidity, salinity, conductivity, total hydrocarbon, total dissolved solids (TDS), dissolved oxygen, chloride, Sulphate (SO 4 ), Nitrate (NO 3 ) and Phosphate (PO 4 ) were determined for the water samples and compared with World Health Organization (WHO) drinking water standard. Notably, the turbidity, TDS, chloride and conductivity of some of the samples were above the WHO acceptable limits. Also, high quantities of heavy metals such as Aluminum and Barium were also present as shown from the data. The dataset can provide insights into the health implications of the contaminants especially when the mean concentration levels of the contaminants are above the recommended WHO drinking water standard.

DEMETERRES project: development of innovative technologies for removing radionuclides from contaminated solid and liquid matrices

NASA Astrophysics Data System (ADS)

Chagvardieff, Pierre; Barré, Yves; Blin, Virginie; Faure, Sylvain; Fornier, Anne; Grange, Didier; Grandjean, Agnès; Guiderdoni, Emmanuel; Henner, Pascale; Siroux, Brice; Leybros, Antoine; Messalier, Marc; Paillard, Hervé; Prévost, Thierry; Rennesson, Malvina; Sarrobert, Catherine; Vavasseur, Alain; Véry, Anne-Aliénor

2017-09-01

As part of the « post-accidental » management, the DEMETERRES project (RSNR PIA) proposes to develop innovative and environmentally friendly methods for removal of cesium and strontium from soils and liquid matrices in order to rehabilitate them for an agricultural use while minimizing the volume of generated wastes in accordance with the nuclear waste existing processes. Complementary approaches are used: they are based on physico-chemical technologies (such as foams flotation, supercritical CO2 extraction, extractants in fluidized bed reactor …) and biological ones (bioextractants, phytoextraction) which concepts are described. These researches aim to design innovative and performing extractants in term of selectivity and to achieve the pilot reactor phase for each of them. These pilots will group in a network to provide a technological platform lasting the project, to which will be attached an available network of experts. The respective advances of these researches are presented, completed of tests initiated in Japan on contaminated soils through partnerships.

Electrodialytic remediation of municipal solid waste incineration residues using different membranes.

PubMed

Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M

2017-02-01

In the present work, three different commercial membrane brands were used in an identical electrodialytic cell setup and operating conditions, in order to reduce the leaching of metals and salt anions of two types of municipal solid waste incineration residues: air pollution control residues of a semi-dry flue-gas cleaning system and fly ashes from a plant with wet flue-gas cleaning system. The results showed a general reduction of the leaching in both residues after ED remediation. For the following elements, the leaching was found to be different after ED treatment depending on the membrane used, with statistical significance: • Air pollution control residues of the semi-dry flue-gas cleaning system: Cr, Cu, Ni, Pb, Zn; • Fly ashes from a plant with wet flue-gas cleaning system: Al, Ba, Cu, Ni, Zn, Cl, SO 4 . Final leaching values for some elements and membranes, but not the majority, were below than those of certified coal fly ash (e.g. Al or Cr), a material which is commonly used in construction materials; at the same time, some of these values were reduced to below the Danish law thresholds on the use of contaminated soil in constructions. These results show the potential of ED as a technology to upgrade municipal solid waste incineration residues. Copyright © 2016 Elsevier Ltd. All rights reserved.

Ecotoxicological impact of MSW landfills: assessment of teratogenic effects by means of an adapted FETAX assay.

PubMed

de Lapuente, J; González-Linares, J; Pique, E; Borràs, M

2014-01-01

The introduction of chemical products into the environment can cause long-term effects on the ecosystems. Increasing efforts are being made to determine the extent of contamination in particularly affected areas using diverse methods to assess the ecotoxicological impact. We used a modified Frog Embrio Toxicity Assay-Xenopus method to determine the extent of toxicological load in different sample soils obtained near three municipal solid waste landfills in Catalonia (Spain). The results show that the Garraf landfill facility produces more embryotoxic damage to the surroundings, than the others ones: Can Mata landfill and Montferrer-Castellbó landfill. The aim of this work is to demonstrate how different management of complex sources of contamination as the controlled dumping sites can modulate the presence of toxics in the environment and their effects and through this, help determine the safer way to treat these wastes. To this effect some conceptual modifications have been made on the established American Society for Testing and Materials protocol. The validity of the new model, both as to model of calculation as to protocol, has been demonstrated in three different sites with complex sources of contamination.

Key parameters for behaviour related to source separation of household organic waste: A case study in Hanoi, Vietnam.

PubMed

Kawai, Kosuke; Huong, Luong Thi Mai

2017-03-01

Proper management of food waste, a major component of municipal solid waste (MSW), is needed, especially in developing Asian countries where most MSW is disposed of in landfill sites without any pretreatment. Source separation can contribute to solving problems derived from the disposal of food waste. An organic waste source separation and collection programme has been operated in model areas in Hanoi, Vietnam, since 2007. This study proposed three key parameters (participation rate, proper separation rate and proper discharge rate) for behaviour related to source separation of household organic waste, and monitored the progress of the programme based on the physical composition of household waste sampled from 558 households in model programme areas of Hanoi. The results showed that 13.8% of 558 households separated organic waste, and 33.0% discharged mixed (unseparated) waste improperly. About 41.5% (by weight) of the waste collected as organic waste was contaminated by inorganic waste, and one-third of the waste disposed of as organic waste by separators was inorganic waste. We proposed six hypothetical future household behaviour scenarios to help local officials identify a final or midterm goal for the programme. We also suggested that the city government take further actions to increase the number of people participating in separating organic waste, improve the accuracy of separation and prevent non-separators from discharging mixed waste improperly.

Application of constructed wetlands to the treatment of leachates from a municipal solid waste landfill in Ibadan, Nigeria.

PubMed

Aluko, Olufemi Oludare; Sridhar, M K C

2005-06-01

Leachates are wastewater generated principally from landfills and solid waste disposal sites. Leachates emanating from municipal wastes are a major source of surface and groundwater pollution worldwide. Globally, leachates have been implicated in low yield of farm produce, developmental anomalies, low birth weights, leukemia incidence, and other cancers in communities around the site. They have also been implicated in hazards to the environment, loss of biodiversity, and contamination of water sources. At Aba-Eku in Nigeria, leachates are being discharged into the Omi Stream without treatment. A study was conducted on a method of leachate treatment that passes the leachate through constructed wetlands using Ipomoea aquatica (Forsk), a locally available plant found close to the landfill site. The aim of the study was to evolve a sustainable and cost-effective method of treatment whose effluents can be discharged into the Omi Stream with no or minimal impact. The study was descriptive and analytical in design. Samples were collected and analyzed with standard methods for pH, suspended solids (SS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), ammonia, nitrate, and trace metals. Raw leachates were turbid and amber in color and contained suspended solids (197.5 mg/L), ammonia (610.9 mg/L), lead (1.64 mg/L), iron (198.10 mg/L), and manganese (23.20 mg/L). When the leachates were passed through the constructed wetland with eight hours' detention time, effluents showed significant reductions in suspended solids (81.01 percent), BOD (86.03 percent), and ammonia (97.77 percent). The study shows that a constructed wetland is a feasible tool for the treatment of leachates before their disposal into the environment in Nigeria and can help safeguard environmental quality.

Solid State Characterizations of Long-Term Leached Cast Stone Monoliths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Asmussen, Robert M.; Pearce, Carolyn I.; Parker, Kent E.

This report describes the results from the solid phase characterization of six Cast Stone monoliths from the extended leach tests recently reported on (Serne et al. 2016),that were selected for characterization using multiple state-of-the-art approaches. The Cast Stone samples investigated were leached for > 590 d in the EPA Method 1315 test then archived for > 390 d in their final leachate. After reporting the long term leach behavior of the monoliths (containing radioactive 99Tc and stable 127I spikes and for original Westsik et al. 2013 fabricated monoliths, 238U), it was suggested that physical changes to the waste forms andmore » a depleting inventory of contaminants of potential concern may mean that effective diffusivity calculations past 63 d should not be used to accurately represent long-term waste form behavior. These novel investigations, in both length of leaching time and application of solid state techniques, provide an initial arsenal of techniques which can be utilized to perform such Cast Stone solid phase characterization work, which in turn can support upcoming performance assessment maintenance. The work was performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to characterize several properties of the long- term leached Cast Stone monolith samples.« less

TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

James T. Cobb, Jr.

2003-09-12

Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatmentmore » with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.« less

Arsenic waste management: a critical review of testing and disposal of arsenic-bearing solid wastes generated during arsenic removal from drinking water.

PubMed

Clancy, Tara M; Hayes, Kim F; Raskin, Lutgarde

2013-10-01

Water treatment technologies for arsenic removal from groundwater have been extensively studied due to widespread arsenic contamination of drinking water sources. Central to the successful application of arsenic water treatment systems is the consideration of appropriate disposal methods for arsenic-bearing wastes generated during treatment. However, specific recommendations for arsenic waste disposal are often lacking or mentioned as an area for future research and the proper disposal and stabilization of arsenic-bearing waste remains a barrier to the successful implementation of arsenic removal technologies. This review summarizes current disposal options for arsenic-bearing wastes, including landfilling, stabilization, cow dung mixing, passive aeration, pond disposal, and soil disposal. The findings from studies that simulate these disposal conditions are included and compared to results from shorter, regulatory tests. In many instances, short-term leaching tests do not adequately address the range of conditions encountered in disposal environments. Future research directions are highlighted and include establishing regulatory test conditions that align with actual disposal conditions and evaluating nonlandfill disposal options for developing countries.

COLLOID-FACILITATED TRANSPORT OF RADIONUCLIDES THROUGH THE VADOSE ZONE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flury, Markus

2003-09-14

Contaminants have leaked into the vadose zone at the USDOE Hanford reservation. It is important to understand the fate and transport of these contaminants to design remediation strategies and long-term waste management plans at the Hanford reservation. Colloids may play an important role in fate and transport of strongly sorbing contaminants, such as Cs or Pu. This project seeks to improve the basic understanding of colloid and colloid-facilitated transport of contaminants in the vadose zone. The specific objectives addressed are: (1) Determine the structure, composition, and surface charge characteristics of colloidal particles formed under conditions similar to those occurring duringmore » leakage of waste typical of Hanford tank supernatants into soils and sediments surrounding the tanks. (2) Characterize the mutual interactions between colloids, contaminant, and soil matrix in batch experiments under various ionic strength and pH conditions. We will investigate the nature of the solid-liquid interactions and the kinetics of the reactions. (3) Evaluate mobility of colloids through soil under different degrees of water saturation and solution chemistry (ionic strength and pH). (4) Determine the potential of colloids to act as carriers to transport the contaminant through the vadose zone and verify the results through comparison with field samples collected under leaking tanks. (5) Improve conceptual characterization of colloid-contaminant-soil interactions and colloid-facilitated transport for implementation into reactive chemical transport models. This project was in part supported by an NSF-IGERT grant to Washington State University. The IGERT grant provided funding for graduate student research and education, and two graduate students were involved in the EMSP project. The IGERT program also supported undergraduate internships. The project is part of a larger EMSP program to study fate and transport of contaminants under leaking Hanford waste tanks. The project has close relations to the following EMSP projects: Project: 70126, Interfacial Soil Chemistry of Radionuclides in the Unsaturated Zone (PI: Jon Chorover) Project: 70070, Reactivity of Primary Soil Minerals and Secondary Precipitates (PI: Kathy Nagy) Cesium Transport in Hanford Sediments: Application of an Experimentally Based Cation Exchange Model (PI: Susan Carroll and Carl Steefel).« less

Developing a Planting Medium from Solid Waste Compost and Construction and Demolition Rubble for Use in Quarry Rehabilitation

NASA Astrophysics Data System (ADS)

Assaf, E. A.

2015-12-01

The combination of construction, demolition and excavation (CDE) waste along with the increase in solid waste generation has put a major stress on Lebanon and on the management of its solid waste. Compounding this problem are the issues of quarries closure and rehabilitation and a decrease in forest and vegetative cover. This research aims to provide an integrated solution to the stated problem by developing a "soil mix" derived from a mélange of the organic matter of the solid waste (compost), the CDE waste, and soil. Excavation and construction debris were ground to several sizes and mixed with compost and soil at different ratios. Replicates of these mixes and a set of control (regular soil) were used. In this mix, native and indicator plants are planted (in pots). The plant species used are Mathiolla crassifolia and Zea mays (Corn). Results have shown successful growth of both corn and Mathiolla seedlings in the mixes with higher amounts of construction rubble and compost i.e. Rubble: Soil: Compost Ratio of 2:1:1 and 1:0:1. However treatments with no compost and with less quantities of rubble demonstrated the inability of the soil used to sustain plant growth alone (1:1:1 and 1:1:0). Last but not least, the control consisting of soil only ended up being the weakest mix with yellow corn leaves and small Mathiolla seedlings fifty days after planting and fertilizing. Additionally, soil analysis, rubble and compost analysis were conducted. The samples were tested for heavy metals, nutrient availability and values of pH and EC. No contamination has been reported and an abundance of macronutrients and micronutrients was documented for the soil and compost. High alkalinity is due to the presence of concrete and the high percentage of Calcium Carbonate in Lebanese soils. Accordingly, the most adequate mixes for planting are treatments A (2:1:1) and B (1:0:1) and they should be pursued for a pilot scale study to test their potential use in quarry rehabilitation and eventually urban agriculture.

Process for treating waste water having low concentrations of metallic contaminants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Looney, Brian B; Millings, Margaret R; Nichols, Ralph L

A process for treating waste water having a low level of metallic contaminants by reducing the toxicity level of metallic contaminants to an acceptable level and subsequently discharging the treated waste water into the environment without removing the treated contaminants.

Radioactive waste disposal implications of extending Part IIA of the Environmental Protection Act to cover radioactively contaminated land.

PubMed

Nancarrow, D J; White, M M

2004-03-01

A short study has been carried out of the potential radioactive waste disposal issues associated with the proposed extension of Part IIA of the Environmental Protection Act 1990 to include radioactively contaminated land, where there is no other suitable existing legislation. It was found that there is likely to be an availability problem with respect to disposal at landfills of the radioactive wastes arising from remediation. This is expected to be principally wastes of high volume and low activity (categorised as low level waste (LLW) and very low level waste (VLLW)). The availability problem results from a lack of applications by landfill operators for authorisation to accept LLW wastes for disposal. This is apparently due to perceived adverse publicity associated with the consultation process for authorisation coupled with uncertainty over future liabilities. Disposal of waste as VLLW is limited both by questions over volumes that may be acceptable and, more fundamentally, by the likely alpha activity of wastes (originating from radium and thorium operations). Authorised on-site disposal has had little attention in policy and guidance in recent years, but may have a part to play, especially if considered commercially attractive. Disposal at BNFL's near surface disposal facility for LLW at Drigg is limited to wastes for which there are no practical alternative disposal options (and preference has been given to operational type wastes). Therefore, wastes from the radioactively contaminated land (RCL) regime are not obviously attractive for disposal to Drigg. Illustrative calculations have been performed based on possible volumes and activities of RCL arisings (and assuming Drigg's future volumetric disposal capacity is 950,000 m3). These suggest that wastes arising from implementing the RCL regime, if all disposed to Drigg, would not represent a significant fraction of the volumetric capacity of Drigg, but could have a significant impact on the radiological capacity with respect to 226Ra plus 232Th. The government's decision-making programme for managing solid radioactive wastes in the UK may possibly achieve a general consensus that the use of landfill for LLW from the RCL regime has a fundamental role to play. However, this is unlikely to change the situation within the next few years. No new national facility arising from this programme is likely to be available during the first decade of the operation of a new RCL regime. Hence it appears that Drigg will need to play an important role for some years to come.

Method of draining water through a solid waste site without leaching

DOEpatents

Treat, Russell L.; Gee, Glendon W.; Whyatt, Greg A.

1993-01-01

The present invention is a method of preventing water from leaching solid waste sites by preventing atmospheric precipitation from contacting waste as the water flows through a solid waste site. The method comprises placing at least one drain hole through the solid waste site. The drain hole is seated to prevent waste material from entering the drain hole, and the solid waste site cover material is layered and graded to direct water to flow toward the drain hole and to soil beneath the waste site.

Method of draining water through a solid waste site without leaching

DOEpatents

Treat, R.L.; Gee, G.W.; Whyatt, G.A.

1993-02-02

The present invention is a method of preventing water from leaching solid waste sites by preventing atmospheric precipitation from contacting waste as the water flows through a solid waste site. The method comprises placing at least one drain hole through the solid waste site. The drain hole is seated to prevent waste material from entering the drain hole, and the solid waste site cover material is layered and graded to direct water to flow toward the drain hole and to soil beneath the waste site.

Urban Environmental Education Project, Curriculum Module VI: Solid Waste - Trash or Treasure?

ERIC Educational Resources Information Center

Biglan, Barbara

Included in this module are four activities dealing with issues of solid waste disposal relative to urban concerns. Included activities are: (1) sources and composition of solid waste; (2) a "garbage game"; (3) disposal options for solid waste; and (4) an example county plan for solid waste disposal. Also included are an overview, teacher…

76 FR 16538 - Solid Waste Rail Transfer Facilities

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-24

... circumstances. Upon receiving a land-use-exemption permit issued by the Board, a solid waste rail transfer... new application for a land-use-exemption permit if the rail line associated with the solid waste rail... transportation of solid waste by rail. (2) The Board will not grant a land-use-exemption permit for a solid waste...

Test-trench studies in the Amargosa Desert, southern Nevada: Results and application of information to landfill covers in arid environments

USGS Publications Warehouse

Andraski, Brian J.; Reynolds, Timothy D.; Morris, Randall C.

1997-01-01

As arid sites in the western United States are increasingly sought for disposal of the Nation's hazardous wastes and as volumes of locally generated wastes increase, concern about the potential effect of contaminants on environmental quality is being raised. Studies at the U.S. Geological Survey's Amargosa Desert research site near Beatty, Nevada are being done to evaluate mechanisms that can affect waste isolation in an arid environment. Precipitation at the site averages about 108 mm yr-1. Results have shown that, under undisturbed conditions, the naturally stratified soils in combination with native plants are effective in limiting the potential for percolation of precipitation. Under nonvegetated waste-site conditions, data indicated the accumulation and shallow, but continued, penetration of infiltrated water, However, water potentials below the test trenches and below the 2-m depth for nonvegetated soil indicated the persistence of an upward driving force for water flow during the 5-yr test period. General trends in trench-cover subsidence suggested a positive relation with cumulative precipitation, but subsidence did not appear to have a measurable effect on the water balance. Erosion rates were inversely related to near-surface rock-fragment content. Results suggest that the ultimate fate of contaminants buried at properly managed solid-waste sites may be determined largely by the interactions among climate and the surface-cover features of the disposal facility, and how these factors change with time.

Biomethane Production as an Alternative Bioenergy Source from Codigesters Treating Municipal Sludge and Organic Fraction of Municipal Solid Wastes

PubMed Central

Ersahin, M. Evren; Yangin Gomec, Cigdem; Dereli, R. Kaan; Arikan, Osman; Ozturk, Izzet

2011-01-01

Energy recovery potential of a mesophilic co-digester treating OFMSW and primary sludge at an integrated biomethanization plant was investigated based on feasibility study results. Since landfilling is still the main solid waste disposal method in Turkey, land scarcity will become one of the most important obstacles. Restrictions for biodegradable waste disposal to sanitary landfills in EU Landfill Directive and uncontrolled long-term contamination with gas emissions and leachate necessitate alternative management strategies due to rapid increase in MSW production. Moreover, since energy contribution from renewable resources will be required more in the future with increasing oil prices and dwindling supplies of conventional energy sources, the significance of biogas as a renewable fuel has been increased in the last decade. Results indicated that almost 93% of annual total cost can be recovered if 100% renewable energy subsidy is implemented. Besides, considering the potential revenue when replacing transport fuels, about 26 heavy good vehicles or 549 cars may be powered per year by the biogas produced from the proposed biomethanization plant (PE = 100,000; XPS = 61 g TS/PE·day; XSS-OFMSW = 50 g TS/PE·day). PMID:21274432

Electron transfer from a solid-state electrode assisted by methyl viologen sustains efficient microbial reductive dechlorination of TCE.

PubMed

Aulenta, Federico; Catervi, Alessandro; Majone, Mauro; Panero, Stefania; Reale, Priscilla; Rossetti, Simona

2007-04-01

The ability to transfer electrons, via an extracellular path, to solid surfaces is typically exploited by microorganisms which use insoluble electron acceptors, such as iron-or manganese-oxides or inert electrodes in microbial fuel cells. The reverse process, i.e., the use of solid surfaces or electrodes as electron donors in microbial respirations, although largely unexplored, could potentially have important environmental applications, particularly for the removal of oxidized pollutants from contaminated groundwater or waste streams. Here we show, for the first time, that an electrochemical cell with a solid-state electrode polarized at -500 mV (vs standard hydrogen electrode), in combination with a low-potential redox mediator (methyl viologen), can efficiently transfer electrochemical reducing equivalents to microorganisms which respire using chlorinated solvents. By this approach, the reductive transformation of trichloroethene, a toxic yet common groundwater contaminant, to harmless end-products such as ethene and ethane could be performed. Furthermore, using a methyl-viologen-modified electrode we could even demonstrate that dechlorinating bacteria were able to accept reducing equivalents directly from the modified electrode surface. The innovative concept, based on the stimulation of dechlorination reactions through the use of solid-state electrodes (we propose for this process the acronym BEARD: Bio-Electrochemically Assisted Reductive Dechlorination), holds promise for in situ bioremediation of chlorinated-solvent-contaminated groundwater, and has several potential advantages over traditional approaches based on the subsurface injection of organic compounds. The results of this study raise the possibility that immobilization of selected redox mediators may be a general strategy for stimulating and controlling a range of microbial reactions using insoluble electrodes as electron donors.

Using DRASTIC'' to improve the accuracy of a geographical information system used for solid waste disposal facility siting: A case study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Padgett, D.A.

Beginning in 1989, the citizens and commissioners of Alachua County, Florida began to develop a siting plan for a new solid waste disposal facility (SWDF). Through a cooperative effort with a private consulting firm, several evaluative criteria were selected and then translated into parameters for a geographical information system (GIS). Despite efforts to avoid vulnerable hydrogeology, the preferred site selected was in close proximity to the well field supplying Gainesville, Florida, home to approximately 75 percent of the county's population. The results brought forth a wave of protests from local residents claiming that leachate from the proposed SWDF would contaminatemore » their drinking water. In this study, DRASTIC'' was applied in order to improve the accuracy and defensibility of the aquifer protection-based GIS parameters. DRASTIC'', a method for evaluating ground water contamination potential, is an acronym which stands for Depth to Water, Net Recharge, Aquifer Media, Soil Media, Topography, Impact of Vadose Zone Media, and Conductivity (Hydraulic)''.« less

Environmental Remediation and Conversion of Carbon Dioxide (CO2) into Useful Green Products by Accelerated Carbonation Technology

PubMed Central

Lim, Mihee; Han, Gi-Chun; Ahn, Ji-Whan; You, Kwang-Suk

2010-01-01

This paper reviews the application of carbonation technology to the environmental industry as a way of reducing carbon dioxide (CO2), a green house gas, including the presentation of related projects of our research group. An alternative technology to very slow natural carbonation is the co-called ‘accelerated carbonation’, which completes its fast reaction within few hours by using pure CO2. Carbonation technology is widely applied to solidify or stabilize solid combustion residues from municipal solid wastes, paper mill wastes, etc. and contaminated soils, and to manufacture precipitated calcium carbonate (PCC). Carbonated products can be utilized as aggregates in the concrete industry and as alkaline fillers in the paper (or recycled paper) making industry. The quantity of captured CO2 in carbonated products can be evaluated by measuring mass loss of heated samples by thermo-gravimetric (TG) analysis. The industrial carbonation technology could contribute to both reduction of CO2 emissions and environmental remediation. PMID:20195442

Evaluation of gasification and novel thermal processes for the treatment of municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Niessen, W.R.; Marks, C.H.; Sommerlad, R.E.

1996-08-01

This report identifies seven developers whose gasification technologies can be used to treat the organic constituents of municipal solid waste: Energy Products of Idaho; TPS Termiska Processor AB; Proler International Corporation; Thermoselect Inc.; Battelle; Pedco Incorporated; and ThermoChem, Incorporated. Their processes recover heat directly, produce a fuel product, or produce a feedstock for chemical processes. The technologies are on the brink of commercial availability. This report evaluates, for each technology, several kinds of issues. Technical considerations were material balance, energy balance, plant thermal efficiency, and effect of feedstock contaminants. Environmental considerations were the regulatory context, and such things as composition,more » mass rate, and treatability of pollutants. Business issues were related to likelihood of commercialization. Finally, cost and economic issues such as capital and operating costs, and the refuse-derived fuel preparation and energy c onversion costs, were considered. The final section of the report reviews and summarizes the information gathered during the study.« less

Leaching behaviour of municipal solid waste incineration bottom ash: From granular material to monolithic concrete.

PubMed

Sorlini, Sabrina; Collivignarelli, Maria Cristina; Abbà, Alessandro

2017-09-01

The aim of this work was to assess the leaching behaviour of the bottom ash derived from municipal solid waste incineration (MSWI) used in concrete production. In particular, the release of pollutants was evaluated by the application of different leaching tests, both on granular materials and monolithic samples (concrete mixtures cast with bottom ash). The results confirmed that, according to Italian regulations, unwashed bottom ashes present critical issues for the use as alternative aggregates in the construction sector due to the excessive release of pollutants; instead, the leachate from washed bottom ashes was similar to natural aggregates. The concentration of pollutants in the leachate from concrete mixtures was lower than regulation limits for reuse. The crushing process significantly influenced the release of pollutants: this behaviour was due both to the increase in surface area and the release of contaminants from cement. Moreover, the increase in contact time (up to 64 days) involved more heavy metals to be released.

Simulation of municipal solid waste degradation in aerobic and anaerobic bioreactor landfills.

PubMed

Patil, Bhagwan Shamrao; C, Agnes Anto; Singh, Devendra Narain

2017-03-01

Municipal solid waste generation is huge in growing cities of developing nations such as India, owing to the rapid industrial and population growth. In addition to various methods for treatment and disposal of municipal solid waste (landfills, composting, bio-methanation, incineration and pyrolysis), aerobic/anaerobic bioreactor landfills are gaining popularity for economical and effective disposal of municipal solid waste. However, efficiency of municipal solid waste bioreactor landfills primarily depends on the municipal solid waste decomposition rate, which can be accelerated through monitoring moisture content and temperature by using the frequency domain reflectometry probe and thermocouples, respectively. The present study demonstrates that these landfill physical properties of the heterogeneous municipal solid waste mass can be monitored using these instruments, which facilitates proper scheduling of the leachate recirculation for accelerating the decomposition rate of municipal solid waste.

40 CFR 240.201 - Solid wastes excluded.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Solid wastes excluded. 240.201 Section 240.201 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.201 Solid...

40 CFR 240.201 - Solid wastes excluded.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Solid wastes excluded. 240.201 Section 240.201 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.201 Solid...

40 CFR 240.200 - Solid wastes accepted.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Solid wastes accepted. 240.200 Section 240.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.200 Solid...

40 CFR 240.200 - Solid wastes accepted.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Solid wastes accepted. 240.200 Section 240.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.200 Solid...

40 CFR 258.4 - Research, development, and demonstration permits.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS General § 258.4 Research, development, and... include such terms and conditions at least as protective as the criteria for municipal solid waste... and quantities of municipal solid waste and non-hazardous wastes which the State Director deems...

40 CFR 256.22 - Recommendations for State regulatory powers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste... prohibit new open dumps and close or upgrade all existing open dumps. (a) Solid waste disposal standards... solid waste disposal facility. These procedures should include identification of future land use or the...

40 CFR 258.4 - Research, development, and demonstration permits.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS General § 258.4 Research, development, and... include such terms and conditions at least as protective as the criteria for municipal solid waste... and quantities of municipal solid waste and non-hazardous wastes which the State Director deems...

40 CFR 256.22 - Recommendations for State regulatory powers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste... prohibit new open dumps and close or upgrade all existing open dumps. (a) Solid waste disposal standards... solid waste disposal facility. These procedures should include identification of future land use or the...

40 CFR 256.21 - Requirements for State regulatory powers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste... be adequate to enforce solid waste disposal standards which are equivalent to or more stringent than the criteria for classification of solid waste disposal facilities (40 CFR part 257). Such authority...

40 CFR 256.21 - Requirements for State regulatory powers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste... be adequate to enforce solid waste disposal standards which are equivalent to or more stringent than the criteria for classification of solid waste disposal facilities (40 CFR part 257). Such authority...

36 CFR 6.5 - Solid waste disposal sites in operation on September 1, 1984.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Solid waste disposal sites in..., DEPARTMENT OF THE INTERIOR SOLID WASTE DISPOSAL SITES IN UNITS OF THE NATIONAL PARK SYSTEM § 6.5 Solid waste disposal sites in operation on September 1, 1984. (a) The operator of a solid waste disposal site in...

36 CFR 6.5 - Solid waste disposal sites in operation on September 1, 1984.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal sites in..., DEPARTMENT OF THE INTERIOR SOLID WASTE DISPOSAL SITES IN UNITS OF THE NATIONAL PARK SYSTEM § 6.5 Solid waste disposal sites in operation on September 1, 1984. (a) The operator of a solid waste disposal site in...

36 CFR 6.5 - Solid waste disposal sites in operation on September 1, 1984.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Solid waste disposal sites in..., DEPARTMENT OF THE INTERIOR SOLID WASTE DISPOSAL SITES IN UNITS OF THE NATIONAL PARK SYSTEM § 6.5 Solid waste disposal sites in operation on September 1, 1984. (a) The operator of a solid waste disposal site in...

36 CFR 6.5 - Solid waste disposal sites in operation on September 1, 1984.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 36 Parks, Forests, and Public Property 1 2012-07-01 2012-07-01 false Solid waste disposal sites in..., DEPARTMENT OF THE INTERIOR SOLID WASTE DISPOSAL SITES IN UNITS OF THE NATIONAL PARK SYSTEM § 6.5 Solid waste disposal sites in operation on September 1, 1984. (a) The operator of a solid waste disposal site in...

36 CFR 6.5 - Solid waste disposal sites in operation on September 1, 1984.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Solid waste disposal sites in..., DEPARTMENT OF THE INTERIOR SOLID WASTE DISPOSAL SITES IN UNITS OF THE NATIONAL PARK SYSTEM § 6.5 Solid waste disposal sites in operation on September 1, 1984. (a) The operator of a solid waste disposal site in...

Greenhouse gas emissions from solid waste in Beijing: The rising trend and the mitigation effects by management improvements.

PubMed

Yu, Yongqiang; Zhang, Wen

2016-04-01

Disposal of solid waste poses great challenges to city managements. Changes in solid waste composition and disposal methods, along with urbanisation, can certainly affect greenhouse gas emissions from municipal solid waste. In this study, we analysed the changes in the generation, composition and management of municipal solid waste in Beijing. The changes of greenhouse gas emissions from municipal solid waste management were thereafter calculated. The impacts of municipal solid waste management improvements on greenhouse gas emissions and the mitigation effects of treatment techniques of greenhouse gas were also analysed. Municipal solid waste generation in Beijing has increased, and food waste has constituted the most substantial component of municipal solid waste over the past decade. Since the first half of 1950s, greenhouse gas emission has increased from 6 CO2-eq Gg y(-1)to approximately 200 CO2-eq Gg y(-1)in the early 1990s and 2145 CO2-eq Gg y(-1)in 2013. Landfill gas flaring, landfill gas utilisation and energy recovery in incineration are three techniques of the after-emission treatments in municipal solid waste management. The scenario analysis showed that three techniques might reduce greenhouse gas emissions by 22.7%, 4.5% and 9.8%, respectively. In the future, if waste disposal can achieve a ratio of 4:3:3 by landfill, composting and incineration with the proposed after-emission treatments, as stipulated by the Beijing Municipal Waste Management Act, greenhouse gas emissions from municipal solid waste will decrease by 41%. © The Author(s) 2016.

Selection and Evaluation of Chemical Indicators for Waste Stream Identification

NASA Astrophysics Data System (ADS)

DeVita, W. M.; Hall, J.

2015-12-01

Human and animal wastes pose a threat to the quality of groundwater, surface water and drinking water. This is especially of concern for private and public water supplies in agricultural areas of Wisconsin where land spreading of livestock waste occurs on thin soils overlaying fractured bedrock. Current microbial source tracking (MST) methods for source identification requires the use of polymerase chain reaction (PCR) techniques. Due to cost, these tests are often not an option for homeowners, municipalities or state agencies with limited resources. The Water and Environmental Analysis Laboratory sought to develop chemical methods to provide lower cost processes to determine sources of fecal waste using fecal sterols, pharmaceuticals (human and veterinary) and human care/use products in ground and surface waters using solid phase extraction combined with triple quadrupole mass spectrometry. The two separate techniques allow for the detection of fecal sterol and other chemical markers in the sub part per billion-range. Fecal sterol ratios from published sources were used to evaluate drinking water samples and wastewater from onsite waste treatment systems and municipal wastewater treatment plants. Pharmaceuticals and personal care products indicative of human waste included: acetaminophen, caffeine, carbamazepine, cotinine, paraxanthine, sulfamethoxazole, and the artificial sweeteners; acesulfame, saccharin, and sucralose. The bovine antibiotic sulfamethazine was also targeted. Well water samples with suspected fecal contamination were analyzed for fecal sterols and PPCPs. Results were compared to traditional MST results from the Wisconsin State Laboratory of Hygiene. Chemical indicators were found in 6 of 11 drinking water samples, and 5 of 11 were in support of MST results. Lack of detection of chemical indicators in samples contaminated with fecal waste supports the need for confirmatory methods and advancement of chemical indicator detection technologies.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gug, JeongIn, E-mail: Jeongin_gug@student.uml.edu; Cacciola, David, E-mail: david_cacciola@student.uml.edu; Sobkowicz, Margaret J., E-mail: Margaret_sobkowiczkline@uml.edu

Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW)more » is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette sample composition was similar to biomass fuels but had significant advantages due to addition of waste plastics that have high energy content compared to other waste types. Addition of PP and HDPE presented better benefits than addition of PET due to lower softening temperature and lower oxygen content. It should be noted that while harmful emissions such as dioxins, furans and mercury can result from burning plastics, WTE facilities have been able to control these emissions to meet US EPA standards. This research provides a drop-in coal replacement that reduces demand on landfill space and replaces a significant fraction of fossil-derived fuel with a renewable alternative.« less

40 CFR 256.23 - Requirements for closing or upgrading open dumps.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid... classification of existing solid waste disposal facilities according to the criteria. This classification shall... solid waste disposal facility; (2) The availability of State regulatory and enforcement powers; and (3...

40 CFR 256.23 - Requirements for closing or upgrading open dumps.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid... classification of existing solid waste disposal facilities according to the criteria. This classification shall... solid waste disposal facility; (2) The availability of State regulatory and enforcement powers; and (3...

Evaluation of municipal solid waste management in egyptian rural areas.

PubMed

El-Messery, Mamdouh A; Ismail, Gaber A; Arafa, Anwaar K

2009-01-01

A two years study was conducted to evaluate the solid waste management system in 143 villages representing the Egyptian rural areas. The study covers the legal responsibilities, service availability, environmental impacts, service providers, financial resources, private sector participation and the quality of collection services. According to UN reports more than 55% of Egyptian population lives in rural areas. A drastic change in the consumption pattern altered the quantity and quality of the generated solid wastes from these areas. Poor solid waste management systems are stigmata in most of the Egyptian rural areas. This causes several environmental and health problems. It has been found that solid waste collection services cover only 27% of the surveyed villages, while, the statistics show that 75% of the surveyed villages are formally covered. The service providers are local villager units, private contractors and civil community associations with a percentage share 71%, 24% and 5% respectively. The operated services among these sectors were 25%, 71% and 100% respectively. The share of private sector in solid waste management in rural areas is still very limited as a result of the poverty of these communities and the lack of recyclable materials in their solid waste. It has been found that direct throwing of solid waste on the banks of drains and canals as well as open dumping and uncontrolled burning of solid waste are the common practice in most of the Egyptian rural areas. The available land for landfill is not enough, pitiable designed, defectively constructed and unreliably operated. Although solid waste generated in rural areas has high organic contents, no composting plant was installed. Shortage in financial resources allocated for valorization of solid waste management in the Egyptian rural areas and lower collection fees are the main points of weakness which resulted in poor solid waste management systems. On the other hand, the farmer's participation in solid waste management through the composting of organic matter and using of food waste as an animal feed are considered strength points. However, throwing of solid waste on the banks of water streams, open dumping and uncontrolled burning of solid waste are environmental damaging behaviors that need to be changed. Integrated solid waste management in the Egyptian rural areas is not yet among the priorities of the Egyptian government.

Methane generation from waste materials

DOEpatents

Samani, Zohrab A.; Hanson, Adrian T.; Macias-Corral, Maritza

2010-03-23

An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

40 CFR 264.101 - Corrective action for solid waste management units.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Corrective action for solid waste... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Releases From Solid Waste Management Units § 264.101 Corrective action for...

40 CFR 266.205 - Standards applicable to the storage of solid waste military munitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... solid waste military munitions. 266.205 Section 266.205 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the storage of solid waste military munitions. (a) Criteria for hazardous waste regulation of...

40 CFR 266.203 - Standards applicable to the transportation of solid waste military munitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... transportation of solid waste military munitions. 266.203 Section 266.203 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the transportation of solid waste military munitions. (a) Criteria for hazardous waste...

40 CFR 264.101 - Corrective action for solid waste management units.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Corrective action for solid waste... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Releases From Solid Waste Management Units § 264.101 Corrective action for...

40 CFR 266.205 - Standards applicable to the storage of solid waste military munitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... solid waste military munitions. 266.205 Section 266.205 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the storage of solid waste military munitions. (a) Criteria for hazardous waste regulation of...

40 CFR 266.203 - Standards applicable to the transportation of solid waste military munitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... transportation of solid waste military munitions. 266.203 Section 266.203 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the transportation of solid waste military munitions. (a) Criteria for hazardous waste...

40 CFR 266.203 - Standards applicable to the transportation of solid waste military munitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... transportation of solid waste military munitions. 266.203 Section 266.203 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the transportation of solid waste military munitions. (a) Criteria for hazardous waste...

40 CFR 266.203 - Standards applicable to the transportation of solid waste military munitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... transportation of solid waste military munitions. 266.203 Section 266.203 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the transportation of solid waste military munitions. (a) Criteria for hazardous waste...

40 CFR 266.203 - Standards applicable to the transportation of solid waste military munitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... transportation of solid waste military munitions. 266.203 Section 266.203 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... applicable to the transportation of solid waste military munitions. (a) Criteria for hazardous waste...

Life cycle modelling of environmental impacts of application of processed organic municipal solid waste on agricultural land (EASEWASTE).

PubMed

Hansen, Trine Lund; Bhander, Gurbakhash S; Christensen, Thomas Højlund; Bruun, Sander; Jensen, Lars Stoumann

2006-04-01

A model capable of quantifying the potential environmental impacts of agricultural application of composted or anaerobically digested source-separated organic municipal solid waste (MSW) is presented. In addition to the direct impacts, the model accounts for savings by avoiding the production and use of commercial fertilizers. The model is part of a larger model, Environmental Assessment of Solid Waste Systems and Technology (EASEWASTE), developed as a decision-support model, focusing on assessment of alternative waste management options. The environmental impacts of the land application of processed organic waste are quantified by emission coefficients referring to the composition of the processed waste and related to specific crop rotation as well as soil type. The model contains several default parameters based on literature data, field experiments and modelling by the agro-ecosystem model, Daisy. All data can be modified by the user allowing application of the model to other situations. A case study including four scenarios was performed to illustrate the use of the model. One tonne of nitrogen in composted and anaerobically digested MSW was applied as fertilizer to loamy and sandy soil at a plant farm in western Denmark. Application of the processed organic waste mainly affected the environmental impact categories global warming (0.4-0.7 PE), acidification (-0.06 (saving)-1.6 PE), nutrient enrichment (-1.0 (saving)-3.1 PE), and toxicity. The main contributors to these categories were nitrous oxide formation (global warming), ammonia volatilization (acidification and nutrient enrichment), nitrate losses (nutrient enrichment and groundwater contamination), and heavy metal input to soil (toxicity potentials). The local agricultural conditions as well as the composition of the processed MSW showed large influence on the environmental impacts. A range of benefits, mainly related to improved soil quality from long-term application of the processed organic waste, could not be generally quantified with respect to the chosen life cycle assessment impact categories and were therefore not included in the model. These effects should be considered in conjunction with the results of the life cycle assessment.

The potential of household solid waste reduction in Sukomanunggal District, Surabaya

NASA Astrophysics Data System (ADS)

Warmadewanthi, I. D. A. A.; Kurniawati, S.

2018-01-01

The rapid population growth affects the amount of waste generated. Sukomanunggal Subdistrict is the densest area in West Surabaya which has a population of 100,602 inhabitants with a total area of 11.2 km2. The population growth significantly affects the problem of limited land for landfill facilities (final processing sites). According to the prevailing regulations, solid waste management solutions include the solid waste reduction and management. This study aims to determine the potential reduction of household solid waste at the sources. Household solid waste samplings were performed for eight consecutive days. The samples were then analyzed to obtain the generation rate, density, and composition so that the household solid waste reduction potential for the next 20 years could be devised. Results of the analysis showed that the value of waste is 0.27 kg/person/day, while the total household solid waste generation amounted to 27,162.58 kg/day or 187.70 m3/day. Concerning the technical aspects, the current solid waste reduction in Sukomanunggal Subdistrict has reached 2.1% through the application of waste bank, composting, and scavenging activities at the dumping sites by the garbage collectors. In the year of 2036, the potential reduction of household solid waste in Sukomanunggal Subdistrict has been estimated to reach 28.0%.

40 CFR 240.101 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Solid wastes means garbage, refuse, sludges, and other discarded solid materials resulting from... common water pollutants. (z) Special wastes means nonhazardous solid wastes requiring handling other than... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL...

40 CFR 257.3-7 - Air.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities... residential, commercial, institutional or industrial solid waste. This requirement does not apply to...

40 CFR 257.3-7 - Air.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities... residential, commercial, institutional or industrial solid waste. This requirement does not apply to...

40 CFR 258.16 - Closure of existing municipal solid waste landfill units.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Location Restrictions § 258.16 Closure of existing municipal solid waste landfill units. (a) Existing MSWLF units that cannot make the... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Closure of existing municipal solid...

40 CFR 258.16 - Closure of existing municipal solid waste landfill units.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Location Restrictions § 258.16 Closure of existing municipal solid waste landfill units. (a) Existing MSWLF units that cannot make the... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Closure of existing municipal solid...

40 CFR 260.33 - Procedures for variances from classification as a solid waste, for variances to be classified as...

Code of Federal Regulations, 2011 CFR

2011-07-01

... classification as a solid waste, for variances to be classified as a boiler, or for non-waste determinations. 260.33 Section 260.33 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... from classification as a solid waste, for variances to be classified as a boiler, or for non-waste...

40 CFR 260.33 - Procedures for variances from classification as a solid waste, for variances to be classified as...

Code of Federal Regulations, 2010 CFR

2010-07-01

... classification as a solid waste, for variances to be classified as a boiler, or for non-waste determinations. 260.33 Section 260.33 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... from classification as a solid waste, for variances to be classified as a boiler, or for non-waste...

Possible global environmental impacts of solid waste practices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, M.M.; Holter, G.M.; DeForest, T.J.

1994-09-01

Pollutants resulting from the management of solid waste have been shown to affect the air, land, oceans, and waterways. In addition, solid wastes have other, more indirect impacts such as reduction in feedstocks of natural resources, because useful materials are disposed of rather than recycled. The objective of this study is to evaluate solid waste management practices that have negative implications on the global environment and develop recommendations for reducing such impacts. Recommendations identifying needed changes are identified that will reduce global impacts of solid waste practices in the future. The scope of this study includes the range of non-hazardousmore » solid wastes produced within our society, including municipal solid waste (MSW) and industrial solid waste (ISW), as well as industry-specific wastes from activities such as construction, demolition, and landclearing. Most solid waste management decisions continue to be made and implemented at very local levels, predominantly with a short-term focus to respond to relatively immediate pressures of landfill shortages, funding problems, political considerations, and the like. In this rush to address immediate local problems, little consideration is being given to potential impacts, either short- or long-term, at the national or global level resulting from solid waste management practices. More and more, the cumulative impacts from local decisions concerning solid waste management are beginning to manifest themselves in broader, longer-term impacts than are being addressed by the decision-makers or, at the very least, are presenting a greater and greater potential for such impacts.« less

Stock flow diagram analysis on solid waste management in Malaysia

NASA Astrophysics Data System (ADS)

Zulkipli, Faridah; Nopiah, Zulkifli Mohd; Basri, Noor Ezlin Ahmad; Kie, Cheng Jack

2016-10-01

The effectiveness on solid waste management is a major importance to societies. Numerous generation of solid waste from our daily activities has risked for our communities. These due to rapid population grow and advance in economic development. Moreover, the complexity of solid waste management is inherently involved large scale, diverse and element of uncertainties that must assist stakeholders with deviating objectives. In this paper, we proposed a system dynamics simulation by developing a stock flow diagram to illustrate the solid waste generation process and waste recycle process. The analysis highlights the impact on increasing the number of population toward the amount of solid waste generated and the amount of recycled waste. The results show an increment in the number of population as well as the amount of recycled waste will decrease the amount of waste generated. It is positively represent the achievement of government aim to minimize the amount of waste to be disposed by year 2020.

Forecasting municipal solid waste generation using prognostic tools and regression analysis.

PubMed

Ghinea, Cristina; Drăgoi, Elena Niculina; Comăniţă, Elena-Diana; Gavrilescu, Marius; Câmpean, Teofil; Curteanu, Silvia; Gavrilescu, Maria

2016-11-01

For an adequate planning of waste management systems the accurate forecast of waste generation is an essential step, since various factors can affect waste trends. The application of predictive and prognosis models are useful tools, as reliable support for decision making processes. In this paper some indicators such as: number of residents, population age, urban life expectancy, total municipal solid waste were used as input variables in prognostic models in order to predict the amount of solid waste fractions. We applied Waste Prognostic Tool, regression analysis and time series analysis to forecast municipal solid waste generation and composition by considering the Iasi Romania case study. Regression equations were determined for six solid waste fractions (paper, plastic, metal, glass, biodegradable and other waste). Accuracy Measures were calculated and the results showed that S-curve trend model is the most suitable for municipal solid waste (MSW) prediction. Copyright © 2016 Elsevier Ltd. All rights reserved.

Fine granular of shredded waste tyre for road kerb application as improvised road furniture

NASA Astrophysics Data System (ADS)

Munikanan, Vikneswaran; Yahya, Muhamad Azani; Yusof, Mohammed Alias; Radzi, Muhammad Haris Fauzan

2018-02-01

Solid waste management in Malaysia was still in a backward stage. Population growth, urbanization and rapid industrialization led to an increase in the solid waste generated by society. Solid waste management is one of the main problems faced by the community, especially in the city. Solid waste management costs of the collection, collecting, transporting waste to the landfill, is very high. The quantity of solid waste should be reduced in order to reduce government spending. Moreover, improper solid waste management caused a negative impact on people and the environment. Method of recycling is one of the best alternatives to reduce the number of solid waste. Therefore, this study was to identify methods of recycling used tires to be used in civil engineering. This study was conducted to determine the effectiveness and properties of rubber from used tires to be add in the road kerb design.

Field testing of particulate matter continuous emission monitors at the DOE Oak Ridge TSCA incinerator. Toxic Substances Control Act.

PubMed

Dunn, James E; Davis, Wayne T; Calcagno, James A; Allen, Marshall W

2002-01-01

A field study to evaluate the performance of three commercially available particulate matter (PM) continuous emission monitors (CEMs) was conducted in 1999-2000 at the US Department of Energy (DOE) Toxic Substances Control Act (TSCA) Incinerator. This study offers unique features that are believed to enhance the collective US experience with PM CEMs. The TSCA Incinerator is permitted to treat PCB-contaminated RCRA hazardous low-level radioactive wastes. The air pollution control system utilizes MACT control technology and is comprised of a rapid quench, venturi scrubber, packed bed scrubber, and two ionizing wet scrubbers in series, which create a saturated flue gas that must be conditioned by the CEMs prior to measurement. The incinerator routinely treats a wide variety of wastes including high and low BTU organic liquids, aqueous, and solid wastes. The various possible combinations for treating liquid and solid wastes may present a challenge in establishing a single, acceptable correlation relationship for individual CEMs. The effect of low-level radioactive material present in the waste is a unique site-specific factor not evaluated in previous tests. The three systems chosen for evaluation were two beta gauge devices and a light scattering device. The performance of the CEMs was evaluated using the requirements in draft Environmental Protection Agency (EPA) Performance Specification 11 (PS11) and Procedure 2. The results of Reference Method 5i stack tests for establishing statistical correlations between the reference method data and the CEMs responses are discussed.

Rehabilitation of El Yahoudia dumping site, Tunisia.

PubMed

Zaïri, M; Ferchichi, M; Ismaïl, A; Jenayeh, M; Hammami, H

2004-01-01

As in all developing countries, cities in Tunisia face serious problems of environmental pollution caused mainly by the inadequate and inefficient final disposal of their generated solid wastes. The Tunisian government launched a development program including the construction of landfills in the main cities and the closure of the contaminated sites issued from solid wastes landrising practice. The project of the Henchir El Yahoudia landfill restoration is the first experience in this programme. It has been suggested to convert the site to a green park and to implement an ornamental plant nursery. The whole surface of the landfill is approximately 100 ha from which 30 ha have been already transformed to an urban recreational area and the remaining 70 ha have to be characterized for the project extension. A field investigation by boring was conducted in order to define the geological and the hydrogeological conditions, the vertical and horizontal wastes layer extension, content and degree of decomposition and the composition and quantities of leachate and landfill gas. Representative samples of waste, soil, groundwater and leachate were collected for laboratory analyses. Several of these borings were converted to piezometers to define the flow regime in the site. The results showed that the biogas (CH4, H2S, and CO2), leachate and waste, distribution in the site is mainly affected by the temporal variation of the site operating method. The underlying fissured clay layer facilitated leachate infiltration into the groundwater where high BOD, COD and nitrogen concentrations were registered.

Towards Sustainable Ambon Bay: Evaluation of Solid Waste Management in Ambon City

NASA Astrophysics Data System (ADS)

Maryati, S.; Miharja, M.; Iscahyono, A. F.; Arsallia, S.; Humaira, AN S.

2017-07-01

Ambon Bay is a strategic area in the context of regional economic development, however it also faced environmental problems due to economic development and the growth of population. One of the environmental problems in the Ambon Bay is the growing solid waste which in turn lowers the quality of the water. The purpose of this study is to evaluate solid waste management in the Ambon City and propose recommendation in order to reduce solid waste in the Ambon Bay. The analytical method used is descriptive analysis by comparing a number of criteria based on the concept of solid waste management in coastal region with the current conditions of solid waste management in Ambon City. Criteria for waste management are divided into generation, storage, collection, transport, transfer and disposal. From the results of analysis, it can be concluded that the components of solid waste management at transport, transfer, and disposal level are generally still adequate, but solid waste management at source, storage and collection level have to be improved.

Deterioration of groundwater quality in the vicinity of an active open-tipping site in West Malaysia

NASA Astrophysics Data System (ADS)

Rahim, Bahaa-Eldin E. A.; Yusoff, I.; Samsudin, A. R.; Yaacob, W. Z. W.; Rafek, A. G. M.

2010-06-01

There is an urgent need for characterization of leachate arising from waste disposal to ensure a corresponding effective leachate management policy. Field and laboratory studies have been carried out to investigate the impact of municipal landfill leachate on the underlying groundwater at a site in West Malaysia. The solid waste was disposed of directly onto an unprotected natural soil formation. This situation was made worse by the shallow water table. The hydrochemical composition of groundwater in the vicinity of the site (background) is a dilute mixed cation, bicarbonate water. The high ionic balance error of ~13.5% reveals that the groundwater body underneath the site was a highly contaminated leachate rather than contaminated groundwater. Elevated concentration of chloride (355.48 mg/L), nitrate (10.40 mg/L as NO3), nitrite (14.59 mg/L), ammoniacal-N (11.61 mg/L), sodium (227.56 mg/L), iron (0.97 mg/L), and lead (0.32 mg/L) measured downgradient indicate that the contamination plume has migrated further away from the site. In most cases, the concentration of these contamination indicators, together with the ranges of sodium percentage (66.3-89.9%) and sodium adsorption ratio (10.1-19.7%), were found to be considerably higher than the limit values of safe water for both domestic and irrigation purposes, respectively.

Investigating the effect of compression on solute transport through degrading municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woodman, N.D., E-mail: n.d.woodman@soton.ac.uk; Rees-White, T.C.; Stringfellow, A.M.

2014-11-15

Highlights: • The influence of compression on MSW flushing was evaluated using 13 tracer tests. • Compression has little effect on solute diffusion times in MSW. • Lithium tracer was conservative in non-degrading waste but not in degrading waste. • Bromide tracer was conservative, but deuterium was not. - Abstract: The effect of applied compression on the nature of liquid flow and hence the movement of contaminants within municipal solid waste was examined by means of thirteen tracer tests conducted on five separate waste samples. The conservative nature of bromide, lithium and deuterium tracers was evaluated and linked to themore » presence of degradation in the sample. Lithium and deuterium tracers were non-conservative in the presence of degradation, whereas the bromide remained effectively conservative under all conditions. Solute diffusion times into and out of less mobile blocks of waste were compared for each test under the assumption of dominantly dual-porosity flow. Despite the fact that hydraulic conductivity changed strongly with applied stress, the block diffusion times were found to be much less sensitive to compression. A simple conceptual model, whereby flow is dominated by sub-parallel low permeability obstructions which define predominantly horizontally aligned less mobile zones, is able to explain this result. Compression tends to narrow the gap between the obstructions, but not significantly alter the horizontal length scale. Irrespective of knowledge of the true flow pattern, these results show that simple models of solute flushing from landfill which do not include depth dependent changes in solute transport parameters are justified.« less

Reprint of: Pyrolysis technologies for municipal solid waste: A review

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Dezhen, E-mail: chendezhen@tongji.edu.cn; Yin, Lijie; Wang, Huan

2015-03-15

Highlights: • MSW pyrolysis reactors, products and environmental impacts are reviewed. • MSW pyrolysis still has to deal with flue gas emissions and products’ contamination. • Definition of standardized products is suggested to formalize MSW pyrolysis technology. • Syngas is recommended to be the target product for single MSW pyrolysis technology. - Abstract: Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis inmore » regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO{sub 2} and NH{sub 3}, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested.« less

Radionuclides in shallow groundwater at Solid Waste Storage Area 5 North, Oak Ridge National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ashwood, T.L.; Marsh, J.D. Jr.

1994-04-01

This report presents a compilation of groundwater monitoring data from Solid Waste Storage Area (SWSA) 5 North at Oak Ridge National Laboratory (ORNL) between November 1989 and September 1993. Monitoring data were collected as part of the Active Sites Environmental Monitoring Program that was implemented in 1989 in response to DOE Order 5820.2A. SWSA 5 North was established for the retrievable storage of transuranic (TRU) wastes in 1970. Four types of storage have been used within SWSA 5 North: bunkers, vaults, wells, and trenches. The fenced portion of SWSA 5 North covers about 3.7 ha (9 acres) in the Whitemore » Oak Creek watershed south of ORNL. The area is bounded by White Oak Creek and two ephemeral tributaries of White Oak Creek. Since 1989, groundwater has been monitored in wells around SWSA 5 North. During that time, elevated gross alpha contamination (reaching as high as 210 Bq/L) has consistently been detected in well 516. This well is adjacent to burial trenches in the southwest corner of the area. Water level measurements in wells 516 and 518 suggest that water periodically inundates the bottom of some of those trenches. Virtually all of the gross alpha contamination is generated by Curium 244 and Americium 241. A special geochemical investigation of well 516 suggests that nearly all of the Curium 44 and Americium 241 is dissolved or associated with dissolved organic matter. These are being transported at the rate of about 2 m/year from the burial trenches, through well 516, to White Oak Creek, where Curium 244 has been detected in a few bank seeps. Concentrations at these seeps are near detection levels (<1 Bq/L).« less

Pyrolysis technologies for municipal solid waste: A review

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Dezhen, E-mail: chendezhen@tongji.edu.cn; Yin, Lijie; Wang, Huan

2014-12-15

Highlights: • MSW pyrolysis reactors, products and environmental impacts are reviewed. • MSW pyrolysis still has to deal with flue gas emissions and products’ contamination. • Definition of standardized products is suggested to formalize MSW pyrolysis technology. • Syngas is recommended to be the target product for single MSW pyrolysis technology. - Abstract: Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis inmore » regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO{sub 2} and NH{sub 3}, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested.« less

Sources, interactions, and ecological impacts of organic contaminants in water, soil, and sediment: an introduction to the special series.

PubMed

Pignatello, Joseph J; Katz, Brian G; Li, Hui

2010-01-01

Agricultural and urban activities result in the release of a large number of organic compounds that are suspected of impacting human health and ecosystems: herbicides, insecticides, human and veterinary pharmaceuticals, natural and synthetic hormones, personal care products, surfactants, plasticizers, fire retardants, and others. Sorbed reservoirs of these compounds in soil represent a potentially chronic source of water contamination. This article is an introduction to a series of technical papers stemming from a symposium at the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America 2008 Annual Meeting, which was held jointly with The Geological Society of America, The Gulf Coast Association of Geological Scientists, and the Houston Geological Society, under one of the Joint Meeting's overarching themes: Emerging Trace Contaminants in Surface and Ground Water Generated from Waste Water and Solid Waste Application. The symposium emphasized the role of soils as sources, sinks, and reaction catalysts for these contaminants and the occurrence and fate of these contaminants in surface and underground water supplies. Topics covered included novel advances in analytical techniques, transport of infectious agents, occurrence and fate of veterinary pharmaceuticals, characterization of sorption mechanism, biotic and abiotic transformation reactions, the role of soil components, occurrence and fate in wastewater treatment systems, transport of engineered nanoparticles, groundwater contamination resulting from urban runoff, and issues in water reuse. Overviews of the reports, trends, gaps in our knowledge, and topics for further research are presented in this special series of papers. The technical papers in this special series reflect current gains in knowledge and simultaneously underscore how poorly we are able to predict the fate and, hence, the associated risk to ecological and human receptors of these contaminants.

Vertical Extent of 100 Area Vadose Zone Contamination of Metals at the Hanford Site

NASA Astrophysics Data System (ADS)

Khaleel, R.; Mehta, S.

2012-12-01

The 100 Area is part of the U.S. Department of Energy Hanford Site in southeastern Washington and borders the Columbia River. The primary sources of contamination in the area are associated with the operation of nine former production reactors, the last one shutting down in 1988. The area is undergoing a CERCLA remedial investigation (RI) that will provide data to support final cleanup decisions. During reactor operations, cooling water contaminated with radioactive and hazardous chemicals was discharged to both the adjacent Columbia River and infiltration cribs and trenches. Contaminated solid wastes were disposed of in burial grounds; the estimated Lead-Cadmium used as "reactor poison" and disposed of in 100 Area burial grounds is 1103 metric tons, of which up to 1059 metric tons are Lead and 44 metric tons are Cadmium. We summarize vadose zone site characterization data for the recently drilled boreholes, including the vertical distribution of concentration profiles for metals (i.e., Lead, Arsenic and Mercury) under the near neutral pH and oxygenated conditions. The deep borehole measurements targeted in the RI work plan were identified with a bias towards locating contaminants throughout the vadose zone and targeted areas at or near the waste sites; i.e., the drilling as well as the sampling was biased towards capturing contamination within the "hot spots." Unlike non-reactive contaminants such as tritium, Arsenic, Mercury and Lead are known to have a higher distribution coefficient (Kd), expected to be relatively immobile, and have a long residence time within the vadose zone. However, a number of sediment samples located close to the water table exceed the background concentrations for Lead and Arsenic. Three conceptual models are postulated to explain the deeper than expected penetration for the metals.

Corrosion susceptibility of steel drums containing cemented intermediate level nuclear wastes

NASA Astrophysics Data System (ADS)

Duffó, Gustavo S.; Farina, Silvia B.; Schulz, Fátima M.; Marotta, Francesca

2010-10-01

Cementation processes are used as immobilization techniques for low or intermediate level radioactive waste for economical and safety reasons and for being a simple operation. In particular, ion-exchange resins commonly used for purification of radioactive liquid waste from nuclear reactors are immobilized before being stored to improve the leach resistance of the waste matrix and to maintain mechanical stability. Combustible solid radioactive waste can be incinerated and the resulting ashes can also be immobilized before storage. The immobilized resins and ashes are then contained in steel drums that may undergo corrosion depending on the presence of certain contaminants. The work described in this paper was aimed at evaluating the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins and incineration ashes containing different concentrations of aggressive species (mostly chloride and sulphate ions). A special type of specimen was designed to simulate the cemented waste in the drum. The evolution of the corrosion potential and the corrosion current density of the steel, as well as the electrical resistivity of the matrix were monitored over a time period of 1 year. The results show the deleterious effect of chloride on the expected lifespan of the waste containers.

40 CFR 267.101 - What must I do to address corrective action for solid waste management units?

Code of Federal Regulations, 2012 CFR

2012-07-01

... action for solid waste management units? 267.101 Section 267.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE FACILITIES OPERATING UNDER A STANDARDIZED PERMIT Releases from Solid Waste Management Units § 267.101 What...

40 CFR 267.101 - What must I do to address corrective action for solid waste management units?

Code of Federal Regulations, 2014 CFR

2014-07-01

... action for solid waste management units? 267.101 Section 267.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE FACILITIES OPERATING UNDER A STANDARDIZED PERMIT Releases from Solid Waste Management Units § 267.101 What...

40 CFR 267.101 - What must I do to address corrective action for solid waste management units?

Code of Federal Regulations, 2013 CFR

2013-07-01

... action for solid waste management units? 267.101 Section 267.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE FACILITIES OPERATING UNDER A STANDARDIZED PERMIT Releases from Solid Waste Management Units § 267.101 What...

40 CFR 267.101 - What must I do to address corrective action for solid waste management units?

Code of Federal Regulations, 2011 CFR

2011-07-01

... action for solid waste management units? 267.101 Section 267.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE FACILITIES OPERATING UNDER A STANDARDIZED PERMIT Releases from Solid Waste Management Units § 267.101 What...

40 CFR 267.101 - What must I do to address corrective action for solid waste management units?

Code of Federal Regulations, 2010 CFR

2010-07-01

... action for solid waste management units? 267.101 Section 267.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE FACILITIES OPERATING UNDER A STANDARDIZED PERMIT Releases from Solid Waste Management Units § 267.101 What...

Management of solid waste

NASA Astrophysics Data System (ADS)

Thompson, W. T.; Stinton, L. H.

1980-04-01

Compliance with the latest regulatory requirements addressing disposal of radioactive, hazardous, and sanitary solid waste criteria in the selection, design, and operation of solid waste management facilities. Due to the state of flux of these regulatory requirements from EPA and NRC, several waste management options were of solid waste. The current regulatory constraints and the design and operational requirements for construction of both storage and disposal facilities for use in management of DOE-ORO solid waste are highlighted. Capital operational costs are included for both disposal and storage options.

Risk element sorption/desorption characteristics of dry olive residue: a technique for the potential immobilization of risk elements in contaminated soils.

PubMed

Hovorka, Miloš; Száková, Jiřina; García-Sánchez, Mercedes; Acebal, Mercedes Blanc; García-Romera, Inmaculada; Tlustoš, Pavel

2016-11-01

Olive oil production is one of the most relevant agroindustrial activities in the Mediterranean region and generates a huge amount of both solid and semi-solid wastes, the uncontrolled disposal of which might lead to serious environmental problems. Due to its organic matter and mineral nutrient content, the waste material can be applied to agricultural soil as a fertilizer. However, due to its high organic matter content, dry olive residue (DOR), commonly called "alperujo," has the potential to immobilize risk elements in contaminated soils. The main objective of this study was to assess the possible effect of DOR on sorption of risk elements such as cadmium (Cd), lead (Pb), and zinc (Zn) in the soil. A set of batch sorption experiments were carried out to assess the ability of DOR to adsorb Cd, Pb, and Zn where the effect of the preceding biotransformation of DOR by four species of fungi: Penicillium chrysogenum, Coriolopsis floccosa, Bjerkhandera adusta, and Chondrostereum purpureum was compared. The Freundlich and Langmuir sorption isotherms were calculated to assess the sorption characteristics of both transformed and non-transformed DOR. The results showed good potential sorption capacity of DOR, especially for Pb and to a lesser extent for Cd and Zn. Better sorption characteristics were reported for the biotransformed DOR samples, which are expected to show higher humification of the organic matter. However, the desorption experiments showed weakness and instability of the DOR-bound elements, especially in the case of Zn. Thus, future research should aim to verify the DOR sorption pattern in contaminated soil as well as the potential stabilization of the DOR element bounds where the increase of the pH levels of the DOR samples needs to be taken into account.

Determination of lead and cadmium concentration limits in agricultural soil and municipal solid waste compost through an approach of zero tolerance to food contamination.

PubMed

Saha, Jayanta Kumar; Panwar, N R; Singh, M V

2010-09-01

Cadmium and lead are important environmental pollutants with high toxicity to animals and human. Soils, though have considerable metal immobilizing capability, can contaminate food chain via plants grown upon them when their built-up occurs to a large extent. Present experiment was carried out with the objective of quantifying the limits of Pb and Cd loading in soil for the purpose of preventing food chain contamination beyond background concentration levels. Two separate sets of pot experiment were carried out for these two heavy metals with graded levels of application doses of Pb at 0.4-150 mg/kg and Cd at 0.02-20 mg/kg to an acidic light textured alluvial soil. Spinach crop was grown for 50 days on these treated soils after a stabilization period of 2 months. Upper limit of background concentration levels (C(ul)) of these metals were calculated through statistical approach from the heavy metals concentration values in leaves of spinach crop grown in farmers' fields. Lead and Cd concentration limits in soil were calculated by dividing C(ul) with uptake response slope obtained from the pot experiment. Cumulative loading limits (concentration limits in soil minus contents in uncontaminated soil) for the experimental soil were estimated to be 170 kg Pb/ha and 0.8 kg Cd/ha. Based on certain assumptions on application rate and computed cumulative loading limit values, maximum permissible Pb and Cd concentration values in municipal solid waste (MSW) compost were proposed as 170 mg Pb/kg and 0.8 mg Cd/kg, respectively. In view of these limiting values, about 56% and 47% of the MSW compost samples from different cities are found to contain Pb and Cd in the safe range.

Detection of Pollution Caused by Solid Wastes

NASA Technical Reports Server (NTRS)

Golueke, Clarence G.

1971-01-01

To develop a means of detecting pollution, it s necessary to know something about the source and nature of the pollution. The type of pollution rising from solid wastes differs considerably from hat from liquid wastes or that from gaseous wastes ni its effect on the immediate environment. It may be "defined" by a series of negatives. When solid wastes are discarded on land, the resulting pollution is not land pollution in the sense of air and water pollution. For one thing, the solid wastes do not become a "part" of the land in that the wastes are neither intimately mixed nor homogenized into the land as are liquid and gaseous wastes into their respective media. The waste particles retain not only their chemical identity but also their visible (i.e., physical) characteristics. When buried, for example, the soil is under, above, and around the solids, because the wastes are there as discrete units. Secondly, solid wastes neither diffuse nor are they carried from the place at which they were deposited. In other words they remain stationary, providing of course the disposal site is land and not moving water. In a given area, solid wastes be not distributed uniformly over that area. Even the solid wastes falling into the specification of letter meets these specifications. In contrast liquid and gaseous wastes become intimately mixed, homogenized, and even dissolved in their media. Because solid wastes remain stationary, pollution constituted by their presence is highly localized and heavily concentrated, even to the extent that the pollution could be termed "micro" when compared to the macro-pollution arising from liquid and gasequs wastes.

40 CFR 257.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities... demolition (C&D) landfill means a solid waste disposal facility subject to the requirements of subparts A or...

Salmon Site Remedial Investigation Report, Exhibit 5

DOE Office of Scientific and Technical Information (OSTI.GOV)

USDOE /NV

1999-09-01

This Salmon Site Remedial Investigation Report provides the results of activities initiated by the U.S. Department of Energy (DOE) to determine if contamination at the Salmon Site poses a current or future risk to human health and the environment. These results were used to develop and evaluate a range of risk-based remedial alternatives. Located in Lamar County, Mississippi, the Salmon Site was used by the U.S. Atomic Energy Commission (predecessor to the DOE) between 1964 and 1970 for two nuclear and two gas explosions conducted deep underground in a salt dome. The testing resulted in the release of radionuclides intomore » the salt dome. During reentry drilling and other site activities, liquid and solid wastes containing radioactivity were generated resulting in surface soil and groundwater contamination. Most of the waste and contaminated soil and water were disposed of in 1993 during site restoration either in the cavities left by the tests or in an injection well. Other radioactive wastes were transported to the Nevada Test Site for disposal. Nonradioactive wastes were disposed of in pits at the site and capped with clean soil and graded. The preliminary investigation showed residual contamination in the Surface Ground Zero mud pits below the water table. Remedial investigations results concluded the contaminant concentrations detected present no significant risk to existing and/or future land users, if surface institutional controls and subsurface restrictions are maintained. Recent sampling results determined no significant contamination in the surface or shallow subsurface. The test cavity resulting from the experiments is contaminated and cannot be economically remediated with existing technologies. The ecological sampling did not detect biological uptake of contaminants in the plants or animals sampled. Based on the current use of the Salmon Site, the following remedial actions were identified to protect both human health and the environment: (1) the installation of a water supply system that will provide potable water to the site and residence in the proximity to the site; (2) continued maintenance of surface institutional controls and subsurface restrictions; and (3) continue to implement the long-term hydrologic monitoring program. The Salmon Site will be relinquished the State of Mississippi as mandated by Public Law 104-201-September 23, 1996, to be used as a demonstration forest/wildlife refuge. Should the land use change in the future and/or monitoring information indicates a change in the site conditions, the DOE will reassess the risk impacts to human health and the environment.« less

Salmon Site Remedial Investigation Report, Main Body

DOE Office of Scientific and Technical Information (OSTI.GOV)

US DOE /NV

1999-09-01

This Salmon Site Remedial Investigation Report provides the results of activities initiated by the U.S. Department of Energy (DOE) to determine if contamination at the Salmon Site poses a current or future risk to human health and the environment. These results were used to develop and evaluate a range of risk-based remedial alternatives. Located in Lamar County, Mississippi, the Salmon Site was used by the U.S. Atomic Energy Commission (predecessor to the DOE) between 1964 and 1970 for two nuclear and two gas explosions conducted deep underground in a salt dome. The testing resulted in the release of radionuclides intomore » the salt dome. During reentry drilling and other site activities, liquid and solid wastes containing radioactivity were generated resulting in surface soil and groundwater contamination. Most of the waste and contaminated soil and water were disposed of in 1993 during site restoration either in the cavities left by the tests or in an injection well. Other radioactive wastes were transported to the Nevada Test Site for disposal. Nonradioactive wastes were disposed of in pits at the site and capped with clean soil and graded. The preliminary investigation showed residual contamination in the Surface Ground Zero mud pits below the water table. Remedial investigations results concluded the contaminant concentrations detected present no significant risk to existing and/or future land users, if surface institutional controls and subsurface restrictions are maintained. Recent sampling results determined no significant contamination in the surface or shallow subsurface. The test cavity resulting from the experiments is contaminated and cannot be economically remediated with existing technologies. The ecological sampling did not detect biological uptake of contaminants in the plants or animals sampled. Based on the current use of the Salmon Site, the following remedial actions were identified to protect both human health and the environment: (1) the installation of a water supply system that will provide potable water to the site and residence in the proximity to the site; (2) continued maintenance of surface institutional controls and subsurface restrictions; and (3) continue to implement the long-term hydrologic monitoring program. The Salmon Site will be relinquished the State of Mississippi as mandated by Public Law 104-201-September 23, 1996, to be used as a demonstration forest/wildlife refuge. Should the land use change in the future and/or monitoring information indicates a change in the site conditions, the DOE will reassess the risk impacts to human health and the environment.« less

Salmon Site Remedial Investigation Report, Exhibit 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

USDOE NV

1999-09-01

This Salmon Site Remedial Investigation Report provides the results of activities initiated by the U.S. Department of Energy (DOE) to determine if contamination at the Salmon Site poses a current or future risk to human health and the environment. These results were used to develop and evaluate a range of risk-based remedial alternatives. Located in Lamar County, Mississippi, the Salmon Site was used by the U.S. Atomic Energy Commission (predecessor to the DOE) between 1964 and 1970 for two nuclear and two gas explosions conducted deep underground in a salt dome. The testing resulted in the release of radionuclides intomore » the salt dome. During reentry drilling and other site activities, liquid and solid wastes containing radioactivity were generated resulting in surface soil and groundwater contamination. Most of the waste and contaminated soil and water were disposed of in 1993 during site restoration either in the cavities left by the tests or in an injection well. Other radioactive wastes were transported to the Nevada Test Site for disposal. Nonradioactive wastes were disposed of in pits at the site and capped with clean soil and graded. The preliminary investigation showed residual contamination in the Surface Ground Zero mud pits below the water table. Remedial investigations results concluded the contaminant concentrations detected present no significant risk to existing and/or future land users, if surface institutional controls and subsurface restrictions are maintained. Recent sampling results determined no significant contamination in the surface or shallow subsurface. The test cavity resulting from the experiments is contaminated and cannot be economically remediated with existing technologies. The ecological sampling did not detect biological uptake of contaminants in the plants or animals sampled. Based on the current use of the Salmon Site, the following remedial actions were identified to protect both human health and the environment: (1) the installation of a water supply system that will provide potable water to the site and residence in the proximity to the site; (2) continued maintenance of surface institutional controls and subsurface restrictions; and (3) continue to implement the long-term hydrologic monitoring program. The Salmon Site will be relinquished the State of Mississippi as mandated by Public Law 104-201-September 23, 1996, to be used as a demonstration forest/wildlife refuge. Should the land use change in the future and/or monitoring information indicates a change in the site conditions, the DOE will reassess the risk impacts to human health and the environment.« less

A review on current status of municipal solid waste management in India.

PubMed

Gupta, Neha; Yadav, Krishna Kumar; Kumar, Vinit

2015-11-01

Municipal solid waste management is a major environmental issue in India. Due to rapid increase in urbanization, industrialization and population, the generation rate of municipal solid waste in Indian cities and towns is also increased. Mismanagement of municipal solid waste can cause adverse environmental impacts, public health risk and other socio-economic problem. This paper presents an overview of current status of solid waste management in India which can help the competent authorities responsible for municipal solid waste management and researchers to prepare more efficient plans. Copyright © 2015. Published by Elsevier B.V.

MINE WASTE TECHNOLOGY PROGRAM; PHOSPHATE STABILIZATION OF HEAVY METALS CONTAMINATED MINE WASTE YARD SOILS, JOPLIN, MISSOURI NPL SITE

EPA Science Inventory

This document summarizes the results of Mine Waste Technology Project 22-Phosphate Stabilization of Heavy Metals-Contaminated Mine Waste Yard Soils. Mining, milling, and smelting of ores near Joplin, Missouri, have resulted in heavy metal contamination of the area. The Joplin s...

Canine scent detection and microbial source tracking of human waste contamination in storm drains.

PubMed

Van De Werfhorst, Laurie C; Murray, Jill L S; Reynolds, Scott; Reynolds, Karen; Holden, Patricia A

2014-06-01

Human fecal contamination of surface waters and drains is difficult to diagnose. DNA-based and chemical analyses of water samples can be used to specifically quantify human waste contamination, but their expense precludes routine use. We evaluated canine scent tracking, using two dogs trained to respond to the scent of municipal wastewater, as a field approach for surveying human fecal contamination. Fecal indicator bacteria, as well as DNA-based and chemical markers of human waste, were analyzed in waters sampled from canine scent-evaluated sites (urban storm drains and creeks). In the field, the dogs responded positively (70% and 100%) at sites for which sampled waters were then confirmed as contaminated with human waste. When both dogs indicated a negative response, human waste markers were absent. Overall, canine scent tracking appears useful for prioritizing sampling sites for which DNA-based and similarly expensive assays can confirm and quantify human waste contamination.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Metin, E.; Eroeztuerk, A.; Neyim, C

This paper provides a general overview of solid waste data and management practices employed in Turkey during the last decade. Municipal solid waste statistics and management practices including waste recovery and recycling initiatives have been evaluated. Detailed data on solid waste management practices including collection, recovery and disposal, together with the results of cost analyses, have been presented. Based on these evaluations basic cost estimations on collection and sorting of recyclable solid waste in Turkey have been provided. The results indicate that the household solid waste generation in Turkey, per capita, is around 0.6 kg/year, whereas municipal solid waste generationmore » is close to 1 kg/year. The major constituents of municipal solid waste are organic in nature and approximately 1/4 of municipal solid waste is recyclable. Separate collection programmes for recyclable household waste by more than 60 municipalities, continuing in excess of 3 years, demonstrate solid evidence for public acceptance and continuing support from the citizens. Opinion polls indicate that more than 80% of the population in the project regions is ready and willing to participate in separate collection programmes. The analysis of output data of the Material Recovery Facilities shows that, although paper, including cardboard, is the main constituent, the composition of recyclable waste varies strongly by the source or the type of collection point.« less

Phytoremediation Potential of Duckweed (Lemna minor L.) On Steel Wastewater.

PubMed

Saha, Priyanka; Banerjee, Angela; Sarkar, Supriya

2015-01-01

An eco-friendly and cost effective technique- phytoremediation was used to remediate contaminants from waste water. This study demonstrated that phytoremediation ability of duckweed (Lemna minor L.) to remove chloride, sulphate from Biological Oxygen Treatment (BOT) waste water of coke oven plant. The BOT water quality was assessed by analyzing physico-biochemical characters--pH, Biological oxygen demand (BOD), Chemical oxygen demand (COD), total dissolved solids (TDS) and elemental concentration. It was observed that an increase in pH value indicated an improvement of water quality. The experimental results showed that, duckweed effectively removed 30% chloride, 16% sulphate and 14% TDS from BOT waste water, which suggested its ability in phytoremediation for removal of chloride and sulphate from BOT waste water. A maximum increase of 30% relative growth rate of duckweed was achieved after 21 days of experiment. Thus, it was concluded that duckweed, an aquatic plant, can be considered for treatment of the effluent discharged from the coke oven plant.

Heavy equipment maintenance wastes and environmental management in the mining industry.

PubMed

Guerin, Turlough F

2002-10-01

Maintenance wastes, if not managed properly, represent significant environmental issues for mining operations. Petroleum hydrocarbon liquid wastes were studied at an Australian site and a review of the literature and technology vendors was carried out to identify oil/water separation technologies. Treatment technologies and practices for managing oily wastewater, used across the broader mining industry in the Asia-Pacific region, were also identified. Key findings from the study were: (1) primary treatment is required to remove grease oil contamination and to protect secondary oily wastewater treatment systems from being overloaded; (2) selection of an effective secondary treatment system is dependent on influent oil droplet size and concentration, suspended solids concentration, flow rates (and their variability), environmental conditions, maintenance schedules and effectiveness, treatment targets and costs; and (3) oily wastewater treatment systems, based on mechanical separation, are favoured over those that are chemically based, as they simplify operational requirements. Source reduction, through housekeeping, equipment and reagent modifications, and segregation and/or consolidation of hydrocarbon waste streams, minimizes treatment costs, safety and environmental impact.

Modeling of Cr contamination in the agricultural lands of three villages near the leather industry in Kasur, Pakistan, using statistical and GIS techniques.

PubMed

Shafiq, Muhammad; Shaukat, Tahira; Nazir, Aisha; Bareen, Firdaus-E-

2017-08-01

Kasur is one of the hubs of leather industry in the Punjab, Pakistan, where chrome tanning method of leather processing is extensively being used. Chromium (Cr) accumulation levels in the irrigation water, soil, and seasonal vegetables were studied in three villages located in the vicinity of wastewater treatment plant and solid waste dumping site operated by the Kasur Tanneries Waste Management Agency (KTWMA). The data was interpreted using analysis of variance (ANOVA), clustering analysis (CA), and principal component analysis (PCA). Interpolated surface maps for Cr were generated using the actual data obtained for the 30 sampling sites in each of the three villages for irrigation water, soil, and seasonal vegetables. The level of contamination in the three villages was directly proportional to their distance from KTWMA wastewater treatment plant and the direction of water runoff. The highest level of Cr contamination in soil (mg kg -1 ) was observed at Faqeeria Wala (37.67), intermediate at Dollay Wala (30.33), and the least in Maan (25.16). A gradational variation in Cr accumulation was observed in the three villages from contaminated wastewater having the least contamination level (2.02-4.40 mg L -1 ), to soil (25.16-37.67 mg kg -1 ), and ultimately in the seasonal vegetable crops (156.67-248.33 mg kg -1 ) cultivated in the region, having the highest level of Cr contamination above the permissible limit. The model used not only predicted the current situation of Cr contamination in the three villages but also indicated the trend of magnification of Cr contamination from irrigation water to soil and to the base of the food chain. Among the multiple causes of Cr contamination of vegetables, soil irrigation with contaminated groundwater was observed to be the dominant one.

Developing a master plan for hospital solid waste management: A case study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karamouz, Mohammad; Zahraie, Banafsheh; Kerachian, Reza

2007-07-01

Disposal of about 1750 tons of solid wastes per day is the result of a rapid population growth in the province of Khuzestan in the south west of Iran. Most of these wastes, especially hospital solid wastes which have contributed to the pollution of the environment in the study area, are not properly managed considering environmental standards and regulations. In this paper, the framework of a master plan for managing hospital solid wastes is proposed considering different criteria which are usually used for evaluating the pollution of hospital solid waste loads. The effectiveness of the management schemes is also evaluated.more » In order to rank the hospitals and determine the share of each hospital in the total hospital solid waste pollution load, a multiple criteria decision making technique, namely analytical hierarchy process (AHP), is used. A set of projects are proposed for solid waste pollution control and reduction in the proposed framework. It is partially applied for hospital solid waste management in the province of Khuzestan, Iran. The results have shown that the hospitals located near the capital city of the province, Ahvaz, produce more than 43% of the total hospital solid waste pollution load of the province. The results have also shown the importance of improving management techniques rather than building new facilities. The proposed methodology is used to formulate a master plan for hospital solid waste management.« less

A comparison of landfill leachates based on waste composition.

PubMed

Moody, Chris M; Townsend, Timothy G

2017-05-01

Samples of leachate were collected from fourteen landfills in the state of Florida, United States that contained primarily putrescible waste (municipal solid waste, MSW, and yard waste), MSW incinerator (MSWI) ash, or a combination of both. Assessment of leachates included trace metals, anions, and nutrients in order to create a mass balance of total dissolved solids (TDS). As expected from previously literature, MSW leached a complex matrix of contaminants while MSWI ash leachate TDS was more than 98% metallic salts. The pH of the MSWI ash leachate samples was slightly acidic or neutral in character, which is contradictory to the results commonly reported in the literature. The cause of this is hypothesized to be a short-circuiting of rainfall in the landfill due to low hydraulic conductivities reported in ash landfills. The difference in pH likely contributed to the findings with respect to MSWI ash-characteristic trace metals in leachates such as aluminum. The authors have concluded that the research findings in this study are an indication of the differences between laboratory leachate quality studies and the conditions encountered in the field. In addition, a characterization of organic matter using qualitative and quantitative analyses determined that COD is not an accurate indicator of organic matter in leachates from landfills with a significant fraction of MSWI ash. Copyright © 2016 Elsevier Ltd. All rights reserved.

Landfill area estimation based on integrated waste disposal options and solid waste forecasting using modified ANFIS model.

PubMed

Younes, Mohammad K; Nopiah, Z M; Basri, N E Ahmad; Basri, H; Abushammala, Mohammed F M; Younes, Mohammed Y

2016-09-01

Solid waste prediction is crucial for sustainable solid waste management. The collection of accurate waste data records is challenging in developing countries. Solid waste generation is usually correlated with economic, demographic and social factors. However, these factors are not constant due to population and economic growth. The objective of this research is to minimize the land requirements for solid waste disposal for implementation of the Malaysian vision of waste disposal options. This goal has been previously achieved by integrating the solid waste forecasting model, waste composition and the Malaysian vision. The modified adaptive neural fuzzy inference system (MANFIS) was employed to develop a solid waste prediction model and search for the optimum input factors. The performance of the model was evaluated using the root mean square error (RMSE) and the coefficient of determination (R(2)). The model validation results are as follows: RMSE for training=0.2678, RMSE for testing=3.9860 and R(2)=0.99. Implementation of the Malaysian vision for waste disposal options can minimize the land requirements for waste disposal by up to 43%. Copyright © 2015 Elsevier Ltd. All rights reserved.

40 CFR 258.20 - Procedures for excluding the receipt of hazardous waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... of hazardous waste. 258.20 Section 258.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Operating Criteria § 258.20 Procedures..., regulated hazardous waste means a solid waste that is a hazardous waste, as defined in 40 CFR 261.3, that is...

40 CFR 258.20 - Procedures for excluding the receipt of hazardous waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... of hazardous waste. 258.20 Section 258.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Operating Criteria § 258.20 Procedures..., regulated hazardous waste means a solid waste that is a hazardous waste, as defined in 40 CFR 261.3, that is...

Microbial Characterization of Solid-Wastes Treated with Heat Melt Compaction Technology

NASA Technical Reports Server (NTRS)

Strayer, Richard F.; Hummerick, Mary E.; Richards, Jeffrey T.; McCoy, LaShelle E.; Roberts, Michael S.; Wheeler, Raymond M.

2011-01-01

The research purpose of the project was to determine the fate of microorganisms in space-generated solid wastes after processing by a Heat Melt Compactor (HMC), which is a candidate solid waste treatment technology. Five HMC product disks were generated at Ames Research Center (ARC), Waste Management Systems element. The feed for two was simulated space-generated trash and feed for three was Volume F compartment wet waste returned on STS 130. Conventional microbiological methods were used to detect and enumerate microorganisms in HMC disks and in surface swab samples of HMC hardware before and after operation. Also, biological indicator test strips were added to the STS trash prior to compaction to test if HMC processing conditions, 150 C for approx 3 hr and dehydration, were sufficient to eliminate the test bacteria on the strips. During sample acquisition at KSC, the HMC disk surfaces were sanitized with 70% alcohol to prevent contamination of disk interiors. Results from microbiological assays indicated that numbers of microbes were greatly reduced but not eliminated by the 70% alcohol. Ten 1.25 cm diameter cores were aseptically cut from each disk to sample the disk interior. The core material was run through the microbial characterization analyses after dispersal in sterile diluent. Low counts of viable bacteria (5 to 50 per core) were found but total direct counts were 6 to 8 orders of magnitude greater. These results indicate that the HMC operating conditions might not be sufficient for complete waste sterilization, but the vast majority of microbes present in the wastes were dead or non-cultivable after HMC treatment. The results obtained from analyses of the commercial spore test strips that had been added fo the wastes prior to HMC operation further indicated that the HMC was sterilizing the wastes. Nearly all strips were recovered from the HMC disks and all of these were negative for spore growth when run through the manufacturer's protocol. The 10(exp 6) or so spores impregnated into the strips were no longer viable. Control test strips, i.e., not exposed to the HMC conditions, were all strongly positive. All isolates from the cultivable counts were identified, leading to one concern: several were identified as Staphylococcus aureus, a human pathogen. The project reported here provides microbial characterization support to the Waste Management Systems element of the Life Support and Habitation Systems program.

Fate and transport of phenol in a packed bed reactor containing simulated solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saquing, Jovita M., E-mail: jmsaquing@gmail.com; Knappe, Detlef R.U., E-mail: knappe@ncsu.edu; Barlaz, Morton A., E-mail: barlaz@ncsu.edu

Highlights: Black-Right-Pointing-Pointer Anaerobic column experiments were conducted at 37 Degree-Sign C using a simulated waste mixture. Black-Right-Pointing-Pointer Sorption and biodegradation model parameters were determined from batch tests. Black-Right-Pointing-Pointer HYDRUS simulated well the fate and transport of phenol in a fully saturated waste column. Black-Right-Pointing-Pointer The batch biodegradation rate and the rate obtained by inverse modeling differed by a factor of {approx}2. Black-Right-Pointing-Pointer Tracer tests showed the importance of hydrodynamic parameters to improve model estimates. - Abstract: An assessment of the risk to human health and the environment associated with the presence of organic contaminants (OCs) in landfills necessitates reliable predictivemore » models. The overall objectives of this study were to (1) conduct column experiments to measure the fate and transport of an OC in a simulated solid waste mixture, (2) compare the results of column experiments to model predictions using HYDRUS-1D (version 4.13), a contaminant fate and transport model that can be parameterized to simulate the laboratory experimental system, and (3) determine model input parameters from independently conducted batch experiments. Experiments were conducted in which sorption only and sorption plus biodegradation influenced OC transport. HYDRUS-1D can reasonably simulate the fate and transport of phenol in an anaerobic and fully saturated waste column in which biodegradation and sorption are the prevailing fate processes. The agreement between model predictions and column data was imperfect (i.e., within a factor of two) for the sorption plus biodegradation test and the error almost certainly lies in the difficulty of measuring a biodegradation rate that is applicable to the column conditions. Nevertheless, a biodegradation rate estimate that is within a factor of two or even five may be adequate in the context of a landfill, given the extended retention time and the fact that leachate release will be controlled by the infiltration rate which can be minimized by engineering controls.« less

76 FR 63252 - Hazardous and Solid Waste Management System: Identification and Listing of Special Wastes...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-12

...-2011-0392; FRL-9476-6] RIN 2050-AE81 Hazardous and Solid Waste Management System: Identification and... Protection Agency (Agency or EPA) in conjunction with the proposed rule: Hazardous and Solid Waste Management...-0392. (4) Mail: Send two copies of your comments to Hazardous and Solid Waste Management System...

Structure and Thermochemistry of Perrhenate Sodalite and Mixed Guest Perrhenate/Pertechnetate Sodalite

DOE PAGES

Pierce, Eric M.; Lilova, Kristina; Missimer, David M.; ...

2016-12-05

Here we report that treatment and immobilization of technetium-99 ( 99Tc) contained in reprocessed nuclear waste and present in contaminated subsurface systems represents a major environmental challenge. One potential approach to managing this highly mobile and long-lived radionuclide is immobilization into micro- and meso-porous crystalline solids, specifically sodalite. We synthesized and characterized the structure of perrhenate sodalite, Na 8[AlSiO 4]6(ReO 4) 2, and the structure of a mixed guest perrhenate/pertechnetate sodalite, Na 8[AlSiO 4] 6(ReO 4) 2-x(TcO 4) x. Perrhenate was used as a chemical analogue for pertechnetate. Bulk analyses of each solid confirm a cubic sodalite-type structure (Pmore » $$\\overline{43}$$n, No. 218 space group) with rhenium and technetium in the 7+ oxidation state. High-resolution nanometer scale characterization measurements provide first-of-a-kind evidence that the ReO 4 – anions are distributed in a periodic array in the sample, nanoscale clustering is not observed, and the ReO 4 – anion occupies the center of the sodalite β-cage in Na8[AlSiO4]6(ReO4)2. We also demonstrate, for the first time, that the TcO4– anion can be incorporated into the sodalite structure. Lastly, thermochemistry measurements for the perrhenate sodalite were used to estimate the thermochemistry of pertechnetate sodalite based on a relationship between ionic potential and the enthalpy and Gibbs free energy of formation for previously measured oxyanion-bearing feldspathoid phases. The results collected in this study suggest that micro- and mesoporous crystalline solids maybe viable candidates for the treatment and immobilization of 99Tc present in reprocessed nuclear waste streams and contaminated subsurface environments.« less

Some recent developments in spacecraft environmental control/life support subsystems

NASA Technical Reports Server (NTRS)

Gillen, R. J.; Olcott, T. M.

1974-01-01

The subsystems considered include a flash evaporator for heat rejection, a regenerable carbon dioxide and humidity control subsystem, an iodinating subsystem for potable water, a cabin contaminant control subsystem, and a wet oxidation subsystem for processing spacecraft wastes. The flash evaporator discussed is a simple unit which efficiently controls life support system temperatures over a wide range of heat loads. For certain advanced spacecraft applications the control of cabin carbon dioxide and humidity can be successfully achieved by a regenerable solid amine subsystem.

Possibilities of municipal solid waste incinerator fly ash utilisation.

PubMed

Hartmann, Silvie; Koval, Lukáš; Škrobánková, Hana; Matýsek, Dalibor; Winter, Franz; Purgar, Amon

2015-08-01

Properties of the waste treatment residual fly ash generated from municipal solid waste incinerator fly ash were investigated in this study. Six different mortar blends with the addition of the municipal solid waste incinerator fly ash were evaluated. The Portland cement replacement levels of the municipal solid waste incinerator fly ash used were 25%, 30% and 50%. Both, raw and washed municipal solid waste incinerator fly ash samples were examined. According to the mineralogical composition measurements, a 22.6% increase in the pozzolanic/hydraulic properties was observed for the washed municipal solid waste incinerator fly ash sample. The maximum replacement level of 25% for the washed municipal solid waste incinerator fly ash in mortar blends was established in order to preserve the compressive strength properties. Moreover, the leaching characteristics of the crushed mortar blend was analysed in order to examine the immobilisation of its hazardous contents. © The Author(s) 2015.

Red mud application in construction industry: review of benefits and possibilities

NASA Astrophysics Data System (ADS)

Lima, M. S. S.; Thives, L. P.; Haritonovs, V.; Bajars, K.

2017-10-01

Red mud is a waste originated in the processing of bauxite into aluminium, which properties of high alkalinity make it cumulatively stored, occupying increasing deforested areas. Annually, it is estimated that approximately 117 million tons of red mud are generated in the world, with no prospect of use, what represents an imminent risk of pollution prone to contamination. Nevertheless, environmental liabilities caused by red mud affect not only the environment, but also the companies responsible for the waste, which will be subject to highest fee payments. Although there are studies that prove the feasibility of using this solid waste in the constitution of ceramic materials, there are no large-scale applications. This study seeks to evaluate the possibilities of red mud application in construction industry, focusing into two main areas: cement production/ceramic material and road construction. Backgrounds from other researchers were taken into consideration and analysed according environmental, economic and technical feasibilities.

40 CFR 241.3 - Standards and procedures for identification of non-hazardous secondary materials that are solid...

Code of Federal Regulations, 2011 CFR

2011-07-01

... identification of non-hazardous secondary materials that are solid wastes when used as fuels or ingredients in...) SOLID WASTES SOLID WASTES USED AS FUELS OR INGREDIENTS IN COMBUSTION UNITS Identification of Non-Hazardous Secondary Materials That Are Solid Wastes When Used as Fuels or Ingredients in Combustion Units...

Solid Waste Activity Packet for Teachers.

ERIC Educational Resources Information Center

Illinois Univ., Urbana. Cooperative Extension Service.

This solid waste activity packet introduces students to the solid waste problem in Illinois. Topics explore consumer practices in the market place, packaging, individual and community garbage generation, and disposal practices. The activities provide an integrated approach to incorporating solid waste management issues into subject areas. The…

78 FR 20073 - Adequacy of Oregon's Municipal Solid Waste Landfill Permit Program

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-03

...] Adequacy of Oregon's Municipal Solid Waste Landfill Permit Program AGENCY: Environmental Protection Agency... Oregon's approved Municipal Solid Waste Landfill Program. On March 22, 2004, EPA issued final regulations... Oregon's Municipal Solid Waste Landfill permit program to allow for Research, Development, and...

Medium term municipal solid waste generation prediction by autoregressive integrated moving average

DOE Office of Scientific and Technical Information (OSTI.GOV)

Younes, Mohammad K.; Nopiah, Z. M.; Basri, Noor Ezlin A.

2014-09-12

Generally, solid waste handling and management are performed by municipality or local authority. In most of developing countries, local authorities suffer from serious solid waste management (SWM) problems and insufficient data and strategic planning. Thus it is important to develop robust solid waste generation forecasting model. It helps to proper manage the generated solid waste and to develop future plan based on relatively accurate figures. In Malaysia, solid waste generation rate increases rapidly due to the population growth and new consumption trends that characterize the modern life style. This paper aims to develop monthly solid waste forecasting model using Autoregressivemore » Integrated Moving Average (ARIMA), such model is applicable even though there is lack of data and will help the municipality properly establish the annual service plan. The results show that ARIMA (6,1,0) model predicts monthly municipal solid waste generation with root mean square error equals to 0.0952 and the model forecast residuals are within accepted 95% confident interval.« less

Medium term municipal solid waste generation prediction by autoregressive integrated moving average

NASA Astrophysics Data System (ADS)

Younes, Mohammad K.; Nopiah, Z. M.; Basri, Noor Ezlin A.; Basri, Hassan

2014-09-01

Generally, solid waste handling and management are performed by municipality or local authority. In most of developing countries, local authorities suffer from serious solid waste management (SWM) problems and insufficient data and strategic planning. Thus it is important to develop robust solid waste generation forecasting model. It helps to proper manage the generated solid waste and to develop future plan based on relatively accurate figures. In Malaysia, solid waste generation rate increases rapidly due to the population growth and new consumption trends that characterize the modern life style. This paper aims to develop monthly solid waste forecasting model using Autoregressive Integrated Moving Average (ARIMA), such model is applicable even though there is lack of data and will help the municipality properly establish the annual service plan. The results show that ARIMA (6,1,0) model predicts monthly municipal solid waste generation with root mean square error equals to 0.0952 and the model forecast residuals are within accepted 95% confident interval.

Examples of Disposition Alternatives for WTP Solid Secondary Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seitz, R.

The Hanford Waste Treatment and Immobilization Plant is planned to produce a variety of solid secondary wastes that will require disposal at the Integrated Disposal Facility on the Hanford Site. Solid secondary wastes include a variety of waste streams that are a result of waste treatment and processing activities.

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Non-waste determinations and variances from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking...

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Non-waste determinations and variances from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking...

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Non-waste determinations and variances from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking...

RCRA, superfund and EPCRA hotline training module. Introduction to: Solid waste programs updated July 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-07-01

The module focuses on EPA`s efforts in two areas: municipal and industrial solid waste. The garbage that is managed by the local governments is known as municipal solid waste (MSW). Garbage excluded from hazardous waste regulation but not typically collected by local governments is commonly known as industrial solid waste. This category includes domestic sewage and other wastewater treatment sludge, demolition and construction wastes, agricultural and mining residues, combustion ash, and industrial process wastes.

The solid waste dilemma

USGS Publications Warehouse

Amey, E.B.; Russell, J.A.; Hurdelbrink, R.J.

1996-01-01

In 1976, the U.S. Congress enacted the Resource Conservation and Recovery Act (RCRA) to further address the problem of increasing industrial and municipal waste. The main objectives of RCRA were to responsibly manage hazardous and solid waste and to procure materials made from recovered wastes. To fulfill these objectives, four main programs of waste management were developed. These programs were defined under Subtitle C, the Hazardous Waste Program; Subtitle D, the Solid Waste Program; Subtitle I, the Underground Storage Tank Program; and Subtitle J, the Medical Waste Program. Subtitle D illustrates the solid waste dilemma occurring in the United States. Under this program, states are encouraged to develop and implement their own waste management plans. These plans include the promotion of recycling solid wastes and the closing and upgrading of all environmentally unsound dumps. ?? 1996 International Association for Mathematical Geology.

40 CFR 268.7 - Testing, tracking, and recordkeeping requirements for generators, treaters, and disposal facilities.

Code of Federal Regulations, 2013 CFR

2013-07-01

... and some soils are contaminated by such hazardous wastes. These treatment standards are also found in § 268.40, and are described in detail in § 268.42, Table 1. These wastes, and soils contaminated with... waste or soil contaminated with a waste, that displays a hazardous characteristic of ignitability...

40 CFR 268.7 - Testing, tracking, and recordkeeping requirements for generators, treaters, and disposal facilities.

Code of Federal Regulations, 2010 CFR

2010-07-01

... and some soils are contaminated by such hazardous wastes. These treatment standards are also found in § 268.40, and are described in detail in § 268.42, Table 1. These wastes, and soils contaminated with... waste or soil contaminated with a waste, that displays a hazardous characteristic of ignitability...

40 CFR 268.7 - Testing, tracking, and recordkeeping requirements for generators, treaters, and disposal facilities.

Code of Federal Regulations, 2011 CFR

2011-07-01

... and some soils are contaminated by such hazardous wastes. These treatment standards are also found in § 268.40, and are described in detail in § 268.42, Table 1. These wastes, and soils contaminated with... waste or soil contaminated with a waste, that displays a hazardous characteristic of ignitability...

40 CFR 268.7 - Testing, tracking, and recordkeeping requirements for generators, treaters, and disposal facilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... and some soils are contaminated by such hazardous wastes. These treatment standards are also found in § 268.40, and are described in detail in § 268.42, Table 1. These wastes, and soils contaminated with... waste or soil contaminated with a waste, that displays a hazardous characteristic of ignitability...

40 CFR 268.7 - Testing, tracking, and recordkeeping requirements for generators, treaters, and disposal facilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... and some soils are contaminated by such hazardous wastes. These treatment standards are also found in § 268.40, and are described in detail in § 268.42, Table 1. These wastes, and soils contaminated with... waste or soil contaminated with a waste, that displays a hazardous characteristic of ignitability...

Enhanced bioremediation of 4-nonylphenol and cadmium co-contaminated sediment by composting with Phanerochaete chrysosporium inocula.

PubMed

Xu, Piao; Lai, Cui; Zeng, Guangming; Huang, Danlian; Chen, Ming; Song, Biao; Peng, Xin; Wan, Jia; Hu, Liang; Duan, Abing; Tang, Wangwang

2018-02-01

Composting is identified as an effective approach for solid waste disposal. The bioremediation of 4-nonylphenol (4NP) and cadmium (Cd) co-contaminated sediment was investigated by composting with Phanerochaete chrysosporium (P. chrysosporium) inocula. P. chrysosporium inocula and proper C/N ratios (25.51) accelerated the composting process accompanied with faster total organic carbon loss, 4NP degradation and Cd passivation. Microbiological analysis demonstrated that elevated activities of lignocellulolytic enzymes and sediment enzymes was conducive to organic chemical transformation. Bacterial community diversity results illustrated that Firmicutes and Proteobacteria were predominant species during the whole composting process. Aerobic cellulolytic bacteria and organic degrading species played significant roles. Toxicity characteristic leaching procedure (TCLP) extraction and germination indices results indicated the efficient detoxification of 4NP and Cd co-contaminated sediment after 120 days of composting. Overall, results demonstrated that P. chrysosporium enhanced composting was available for the bioremediation of 4NP and Cd co-contaminated sediment. Copyright © 2017 Elsevier Ltd. All rights reserved.

System for chemically digesting low level radioactive, solid waste material

DOEpatents

Cowan, Richard G.; Blasewitz, Albert G.

1982-01-01

An improved method and system for chemically digesting low level radioactive, solid waste material having a high through-put. The solid waste material is added to an annular vessel (10) substantially filled with concentrated sulfuric acid. Concentrated nitric acid or nitrogen dioxide is added to the sulfuric acid within the annular vessel while the sulfuric acid is reacting with the solid waste. The solid waste is mixed within the sulfuric acid so that the solid waste is substantilly fully immersed during the reaction. The off gas from the reaction and the products slurry residue is removed from the vessel during the reaction.

The Tompkins County Solid Waste Annual Fee: Background and overview

DOE Office of Scientific and Technical Information (OSTI.GOV)

Penniman, P.W.

1995-05-01

This report outlines the development by Tompkins County of a new revenue source for solid waste programs -- The Solid Waste Annual Fee. Over the past two decades in New York State, regulatory demands and the decline in available landfill space have combined to cause a rapid escalation in the cost of solid waste disposal. While the New York State Department of Environmental Conservation (NYSDEC) has implemented tighter regulations for the siting of solid waste landfills, they have also mandated the permitting or closure of all existing landfills in the state. The result is that all communities have been requiredmore » to invest millions of dollars in landfill siting, closure and solid waste processing facilities. In addition, programs for reducing and recycling solid wastes have been mandated to reduce the outflow to landfills. Until recent years, solid waste services in most New York counties have been funded almost entirely through a collection of property taxes. During the past six years, fiscal stress has stimulated a movement toward funding solid waste programs by other means. Alternatives to the property tax include: (1) special assessment taxes or fees; (2) user charges (including tipping fees); and (3) intergovernment grants.« less

Solid materials for removing metals and fabrication method

DOEpatents

Coronado, Paul R.; Reynolds, John G.; Coleman, Sabre J.

2004-10-19

Solid materials have been developed to remove contaminating metals and organic compounds from aqueous media. The contaminants are removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the metals and the organics leaving a purified aqueous stream. The materials are sol-gel and or sol-gel and granulated activated carbon (GAC) mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards the contaminant(s). The contaminated solid materials can then be disposed of or the contaminant can be removed and the solids recycled.

Effects of the opening of the Qinghai-Tibet Railway on municipal solid waste management generation in Lhasa.

PubMed

Ding, Xu-Tong; Wang, Ji-Hua

2018-03-01

Lhasa, the capital of Tibet, is located on the Tibetan Plateau. Accelerated economic development and flourishing tourism resulting from the opening of the Qinghai-Tibet Railway (QTR) have increased solid waste generation and contamination in recent years. Using data from Lhasa Statistical Yearbooks and previous studies, this study estimates the future population of permanent residents and tourists using the least squares method to extrapolate the population from 2015-2025, and evaluates the effects of the QTR on municipal solid waste (MSW) generation in Lhasa and estimates future MSW generation. There were approximately 1.35 million tourists in 2008 when the QTR had been operating for 2 years and MSW generation was approximately 470 tons per day. The amount of MSW generated increased dramatically with time after opening the QTR. This study estimates that MSW generation will reach 962 tons per day in 2025. Due to the existence of the QTR, increasing numbers of people are traveling to Lhasa, and tourism has driven the development of the local economy. During the studies, the proportion of MSW produced by tourists increased from 2.99% to 20.06%, and it is estimated that it will increase to 33.49% in 2025. If the current trend continues, Lhasa will face significant challenges from garbage disposal. This study analyzes the current situation of urban garbage treatment in Lhasa, and it suggests several options for improvement to MSW generation, transportation equipment, disposal, and resource recycling.

State of municipal solid waste management in Delhi, the capital of India.

PubMed

Talyan, Vikash; Dahiya, R P; Sreekrishnan, T R

2008-01-01

Delhi is the most densely populated and urbanized city of India. The annual growth rate in population during the last decade (1991-2001) was 3.85%, almost double the national average. Delhi is also a commercial hub, providing employment opportunities and accelerating the pace of urbanization, resulting in a corresponding increase in municipal solid waste (MSW) generation. Presently the inhabitants of Delhi generate about 7000tonnes/day of MSW, which is projected to rise to 17,000-25,000tonnes/day by the year 2021. MSW management has remained one of the most neglected areas of the municipal system in Delhi. About 70-80% of generated MSW is collected and the rest remains unattended on streets or in small open dumps. Only 9% of the collected MSW is treated through composting, the only treatment option, and rest is disposed in uncontrolled open landfills at the outskirts of the city. The existing composting plants are unable to operate to their intended treatment capacity due to several operational problems. Therefore, along with residue from the composting process, the majority of MSW is disposed in landfills. In absence of leachate and landfill gas collection systems, these landfills are a major source of groundwater contamination and air pollution (including generation of greenhouse gases). This study describes and evaluates the present state of municipal solid waste management in Delhi. The paper also summarizes the proposed policies and initiatives of the Government of Delhi and the Municipal Corporation of Delhi to improve the existing MSW management system.

Effects of biochars produced from solid organic municipal waste on soil quality parameters

USDA-ARS?s Scientific Manuscript database

New, value-added uses for solid organic waste are needed for environmental and economic sustainability. Fortunately, value-added biochars can be produced from mixed organic solid waste, thereby addressing solid waste management issues, and enabling long-term carbon sequestration. We hypothesize that...

40 CFR 240.206-3 - Recommended procedures: Operations.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended... spillages occur, emptying the solid waste storage area at least weekly, and routinely cleaning the remainder of the facility. (b) Solid waste and residue should not be allowed to accumulate at the facility for...

40 CFR 266.202 - Definition of solid waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Definition of solid waste. 266.202 Section 266.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... MANAGEMENT FACILITIES Military Munitions § 266.202 Definition of solid waste. (a) A military munition is not...

78 FR 5350 - Adequacy of Massachusetts Municipal Solid Waste Landfill Permit Program

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-25

...] Adequacy of Massachusetts Municipal Solid Waste Landfill Permit Program AGENCY: Environmental Protection... modification of its approved Municipal Solid Waste Landfill Program. On March 22, 2004, EPA issued final... solid waste landfills by approved states. On December 7, 2012 Massachusetts submitted an application to...

40 CFR 266.202 - Definition of solid waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Definition of solid waste. 266.202 Section 266.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... MANAGEMENT FACILITIES Military Munitions § 266.202 Definition of solid waste. (a) A military munition is not...

The removal of lead and nickel from the composted municipal waste and sewage sludge using nanoscale zero-valent iron fixed on quartz.

PubMed

Ghasemzadeh, Parisa; Bostani, Amir

2017-11-01

Reducing the concentration of heavy metals including lead (Pb) and nickel (Ni) in organic contaminants such as municipal wastes and sewage sludge is of health and environmental importance. Nanoscale zero-valent iron (NZVI) particles can effectively remove heavy metals from contaminated aqueous and solid media. It was accordingly hypothesized that it is possible to recycle and detoxify organic waste materials containing heavy metals using NZVI and NZVI fixed on quartz (QNZVI). The objective was to investigate the effects of NZVI type, concentration (2% and 5%) and contact time on the removal of Pb and Ni from raw compost, compost fermented with beet molasses, and leachate using a factorial design. The results indicated the significant reduction of DTPA- Pb and DTPA-Ni concentration, in all the organic compounds treated with NZVI and QNZVI (P= 0.01), compared with control. Increased concentration of NZVI in all treatments, increased the rate of DTPA-Pb and DTPA-Ni (P= 0.01) at 113.1% and 180% for Pb (NZVI at 2% and 5%), and at 16.3% and 23.3% for Ni, irrespective of the NZVI type. The reducing trend of extractable Pb and Ni in all the organic compounds was the same, quick reduction at the beginning, followed by a negligible rate. The highest reduction rates for Pb (at one hour) and Ni (at 672h) were equal to 72.93% and 23.27%, respectively. NZVI at 2% was more efficient than NZVI at 5%. There were not any significant differences between NZVI and QNZVI on the removal of Pb and Ni from the organic contaminants. It is possible to immobilize and reduce the concentration of heavy metals such as Pb and Ni in organic contaminants using NZVI, which is affected by NZVI properties, concentration, and contact time, as well as by organic contaminant type. Copyright © 2017 Elsevier Inc. All rights reserved.

Toward zero waste events: Reducing contamination in waste streams with volunteer assistance.

PubMed

Zelenika, Ivana; Moreau, Tara; Zhao, Jiaying

2018-06-01

Public festivals and events generate a tremendous amount of waste, especially when they involve food and drink. To reduce contamination across waste streams, we evaluated three types of interventions at a public event. In a randomized control trial, we examined the impact of volunteer staff assistance, bin tops, and sample 3D items with bin tops, on the amount of contamination and the weight of the organics, recyclable containers, paper, and garbage bins at a public event. The event was the annual Apple Festival held at the University of British Columbia, which was attended by around 10,000 visitors. We found that contamination was the lowest in the volunteer staff condition among all conditions. Specifically, volunteer staff reduced contamination by 96.1% on average in the organics bin, 96.9% in the recyclable containers bin, 97.0% in the paper bin, and 84.9% in the garbage bin. Our interventions did not influence the weight of the materials in the bins. This finding highlights the impact of volunteers on reducing contamination in waste streams at events, and provides suggestions and implications for waste management for event organizers to minimize contamination in all waste streams to achieve zero waste goals. Copyright © 2018. Published by Elsevier Ltd.

Quantitative analysis of impact of awareness-raising activities on organic solid waste separation behaviour in Balikpapan City, Indonesia.

PubMed

Murase, Noriaki; Murayama, Takehiko; Nishikizawa, Shigeo; Sato, Yuriko

2017-10-01

Many cities in Indonesia are under pressure to reduce solid waste and dispose of it properly. In response to this pressure, the Japan International Cooperation Agency and the Indonesian Government have implemented a solid waste separation and collection project to reduce solid waste in the target area (810 households) of Balikpapan City. We used a cluster randomised controlled trial method to measure the impact of awareness-raising activities that were introduced by the project on residents' organic solid waste separation behaviour. The level of properly separated organic solid waste increased by 6.0% in areas that conducted awareness-raising activities. Meanwhile, the level decreased by 3.6% in areas that did not conduct similar activities. Therefore, in relative comparison, awareness-raising increased the level by 9.6%. A comparison among small communities in the target area confirmed that awareness-raising activities had a significant impact on organic solid waste separation. High frequencies of monitoring at waste stations and door-to-door visits by community members had a positive impact on organic solid waste separation. A correlation between the proximity of environmental volunteers' houses to waste stations and a high level of separation was also confirmed. The awareness-raising activities introduced by the project led to a significant increase in the separation of organic solid waste.

Innovative approach to facilitate reuse of nonhazardous industrial solid waste as building material

DOE Office of Scientific and Technical Information (OSTI.GOV)

St-Laurent, S.G.; Boutin, A.

1997-12-31

The steel industry generates large volumes of inorganic nonhazardous solid waste. During the last five years, Quebec`s steel industry has developed new technologies to recover metal from slags and tailings. Since these processes recover 10 to 30 percent of the metal, large volumes of nonhazardous residues still need to be recycled or disposed of. In order to encourage recycling initiatives, le Ministere de l`Environnement et de la Faune du Quebec (MEF) (Quebec`s Ministry of Environment and Wildlife) established guidelines for the management of nonhazardous industrial solid waste. The aim of these guidelines is to propose a test procedure to evaluatemore » the quality of the material and to define material classes based on their potential for reuse. The evaluation procedure is based on standard tests, generally used for the evaluation of stabilized and solidified hazardous waste. The protocol includes an analysis of the total content of metals in the residue, the determination of the acid neutralization capacity and the prediction of the acid generation potential when the residue contains significant levels of sulfides. The protocol includes three different leachate tests in order to evaluate the mobility of contaminants present in the residue. The leaching procedures are: (1) an equilibrium extraction with water, (2) a modified TCLP extraction, and (3) an acid rain simulation effect extraction. A method is actually under development to collect leachate from a material pile subject to 18 months of rainfall. Materials are categorized into different classes according to their test results. Various potential reuse options are associated with material classes. Evaluation criteria were defined by using water quality standards and results obtained by testing reference construction material supplied by the Quebec`s Ministere des Transports (Ministry of Transportation).« less

Method for recovery of hydrocarbons form contaminated soil or refuse materials

DOEpatents

Ignasiak, Teresa; Turak, Ali A.; Pawlak, Wanda; Ignasiak, Boleslaw L.; Guerra, Carlos R.; Zwillenberg, Melvin L.

1991-01-01

A method is provided for separating an inert solid substantially inorganic fraction comprising sand or soil from a tarry or oily organic matter in a feedstock. The feedstock may be contaminated soil or tarry waste. The feedstock is combined with pulverized coal and water. The ratio (oil or tar to dry weight of coal) of about 1.0:10 to about 4.0:10 at a temperature in the range of 60.degree.-95.degree. C. The mixture is agitated, the coarse particles are removed, and up to about 0.10% by weight (based on weight of coal) of a frothing agent is added. The mixture is then subjected to flotation, and the froth is removed from the mixture.

Solid-waste management in Jalandhar city and its impact on community health

PubMed Central

Puri, Avinash; Kumar, Manoj; Johal, Eonkar

2008-01-01

In this study, solid-waste management practices were evaluated in order to find out its link with occurrence of vector-borne disease. Strategies for solid-waste management were employed as practical model to solve the problems regarding pollution which is originated by solid-waste. PMID:20040983

Energy and solid/hazardous waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1981-12-01

This report addresses the past and potential future solid and hazardous waste impacts from energy development, and summarizes the major environmental, legislation applicable to solid and hazardous waste generation and disposal. A glossary of terms and acronyms used to describe and measure solid waste impacts of energy development is included. (PSB)

76 FR 270 - Alaska: Adequacy of Alaska Municipal Solid Waste Landfill Permit Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-04

...] Alaska: Adequacy of Alaska Municipal Solid Waste Landfill Permit Program AGENCY: Environmental Protection... approved Municipal Solid Waste Landfill (MSWLF) permit program. The approved modification allows the State..., EPA issued a final rule (69 FR 13242) amending the Municipal Solid Waste Landfill (MSWLF) criteria in...

40 CFR 1.47 - Office of Solid Waste and Emergency Response.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 1 2011-07-01 2011-07-01 false Office of Solid Waste and Emergency... ORGANIZATION AND GENERAL INFORMATION Headquarters § 1.47 Office of Solid Waste and Emergency Response. The Office of Solid Waste and Emergency Response (OSWER), under the supervision of the Assistant...

75 FR 53220 - Adequacy of New Hampshire Municipal Solid Waste Landfill Permit Program

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-31

...] Adequacy of New Hampshire Municipal Solid Waste Landfill Permit Program AGENCY: Environmental Protection... approved municipal solid waste landfill (MSWLF) program. The approved modification allows the State to..., and demonstration (RD&D) permits to be issued to certain municipal solid waste landfills by approved...

75 FR 53268 - Adequacy of New Hampshire Municipal Solid Waste Landfill Permit Program

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-31

...] Adequacy of New Hampshire Municipal Solid Waste Landfill Permit Program AGENCY: Environmental Protection... modification of its approved Municipal Solid Waste Landfill Program. On March 22, 2004, EPA issued final... solid waste landfills by approved states. On June 28, 2010 New Hampshire submitted an application to EPA...

40 CFR 62.14353 - Standards for municipal solid waste landfill emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Standards for municipal solid waste... POLLUTANTS Federal Plan Requirements for Municipal Solid Waste Landfills That Commenced Construction Prior to... municipal solid waste landfill emissions. (a) The owner or operator of a designated facility having a design...

77 FR 65875 - Adequacy of Arizona Municipal Solid Waste Landfill Permit Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-31

... Municipal Solid Waste Landfill Permit Program AGENCY: Environmental Protection Agency (EPA). ACTION: Notice... modification to Arizona's municipal solid waste landfill (MSWLF) permit program to allow the State to issue... amending the municipal solid waste landfill criteria at 40 CFR 258.4 to allow for Research, Development...

40 CFR 256.24 - Recommendations for closing or upgrading open dumps.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste Disposal Programs § 256.24 Recommendations for closing or upgrading open dumps. (a) All... feasibility of resource recovery or resource conservation to reduce the solid waste volume entering a facility...

40 CFR 62.14353 - Standards for municipal solid waste landfill emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 8 2011-07-01 2011-07-01 false Standards for municipal solid waste... POLLUTANTS Federal Plan Requirements for Municipal Solid Waste Landfills That Commenced Construction Prior to... municipal solid waste landfill emissions. (a) The owner or operator of a designated facility having a design...

40 CFR 1.47 - Office of Solid Waste and Emergency Response.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Office of Solid Waste and Emergency... ORGANIZATION AND GENERAL INFORMATION Headquarters § 1.47 Office of Solid Waste and Emergency Response. The Office of Solid Waste and Emergency Response (OSWER), under the supervision of the Assistant...

40 CFR 256.24 - Recommendations for closing or upgrading open dumps.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste Disposal Programs § 256.24 Recommendations for closing or upgrading open dumps. (a) All... feasibility of resource recovery or resource conservation to reduce the solid waste volume entering a facility...

40 CFR 721.10667 - Slimes and sludges, aluminum and iron casting, wastewater treatment, solid waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... casting, wastewater treatment, solid waste. 721.10667 Section 721.10667 Protection of Environment... iron casting, wastewater treatment, solid waste. (a) Chemical substance and significant new uses... and iron casting, wastewater treatment, solid waste (PMN P-12-560; CAS No. 1391739-82-4; chemical...

40 CFR 721.10667 - Slimes and sludges, aluminum and iron casting, wastewater treatment, solid waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... casting, wastewater treatment, solid waste. 721.10667 Section 721.10667 Protection of Environment... iron casting, wastewater treatment, solid waste. (a) Chemical substance and significant new uses... and iron casting, wastewater treatment, solid waste (PMN P-12-560; CAS No. 1391739-82-4; chemical...

40 CFR 62.14353 - Standards for municipal solid waste landfill emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... POLLUTANTS Federal Plan Requirements for Municipal Solid Waste Landfills That Commenced Construction Prior to... 40 Protection of Environment 9 2013-07-01 2013-07-01 false Standards for municipal solid waste... municipal solid waste landfill emissions. (a) The owner or operator of a designated facility having a design...

77 FR 69769 - Solid Waste Rail Transfer Facilities

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-21

.... SUMMARY: These final rules govern land-use-exemption permits for solid waste rail transfer facilities. The... ``land-use-exemption permits'' in certain circumstances. Under the CRA, a solid waste rail transfer... grants a land-use-exemption permit for a solid waste rail transfer facility, such permit would only...

Heat Melt Compaction as an Effective Treatment for Eliminating Microorganisms from Solid Waste

NASA Technical Reports Server (NTRS)

Hummerick, Mary P.; Strayer, Richard F.; McCoy, Lashelle E.; Richards, Jeffrey T.; Ruby, Anna Maria; Wheeler, Ray; Fisher, John

2013-01-01

One of the technologies being tested at Ames Research Center as part of the logistics and repurposing project is heat melt compaction (HMC) of solid waste to reduce volume, remove water and render a biologically stable and safe product. Studies at Kennedy Space Center have focused on the efficacy of the heat melt compaction process for killing microorganisms in waste and specific compacter operation protocols, i.e., time and temperature required to achieve a sterile, stable product. The work. reported here includes a controlled study to examine the survival and potential re-growth of specific microorganisms over a 6-month period of storage after heating and compaction. Before heating and compaction, ersatz solid wastes were inoculated with Bacillus amyloliquefaciens and Rhodotorula mucilaginosa, previously isolated from recovered space shuttle mission food and packaging waste. Compacted HMC tiles were sampled for microbiological analysis at time points between 0 and 180 days of storage in a controlled environment chamber. In addition, biological indicator strips containing spores of Bacillus atrophaeus and Geobacillus stearothermophilus were imbedded in trash to assess the efficacy of the HMC process to achieve sterilization. Analysis of several tiles compacted at 180deg C for times of 40 minutes to over 2 hours detected organisms in all tile samples with the exception of one exposed to 180deg C for approximately 2 hours. Neither of the inoculated organisms was recovered, and the biological indicator strips were negative for growth in all tiles indicating at least local sterilization of tile areas. The findings suggest that minimum time/temperature combination is required for complete sterilization. Microbial analysis of tiles processed at lower temperatures from 130deg C-150deg C at varying times will be discussed, as well as analysis of the bacteria and fungi present on the compactor hardware as a result of exposure to the waste and the surrounding environment. The two organisms inoculated into the waste were among those isolated and identified from the HMC surfaces indicating the possibility of cross contamination.

A novel multiple batch extraction test to assess contaminant mobilization from porous waste materials

NASA Astrophysics Data System (ADS)

Iden, S. C.; Durner, W.; Delay, M.; Frimmel, F. H.

2009-04-01

Contaminated porous materials, like soils, dredged sediments or waste materials must be tested before they can be used as filling materials in order to minimize the risk of groundwater pollution. We applied a multiple batch extraction test at varying liquid-to-solid (L/S) ratios to a demolition waste material and a municipal waste incineration product and investigated the release of chloride, sulphate, sodium, copper, chromium and dissolved organic carbon from both waste materials. The liquid phase test concentrations were used to estimate parameters of a relatively simple mass balance model accounting for equilibrium partitioning. The model parameters were estimated within a Bayesian framework by applying an efficient MCMC sampler and the uncertainties of the model parameters and model predictions were quantified. We tested isotherms of the linear, Freundlich and Langmuir type and selected the optimal isotherm model by use of the Deviance Information Criterion (DIC). Both the excellent fit to the experimental data and a comparison between the model-predicted and independently measured concentrations at the L/S ratios of 0.25 and 0.5 L/kg demonstrate the applicability of the model for almost all studied substances and both waste materials. We conclude that batch extraction tests at varying L/S ratios provide, at moderate experimental cost, a powerful complement to established test designs like column leaching or single batch extraction tests. The method constitutes an important tool in risk assessments, because concentrations at soil water contents representative for the field situation can be predicted from easier-to-obtain test concentrations at larger L/S ratios. This helps to circumvent the experimental difficulties of the soil saturation extract and eliminates the need to apply statistical approaches to predict such representative concentrations which have been shown to suffer dramatically from poor correlations.

Technical report for a fluidless directional drilling system demonstrated at Solid Waste Storage Area 6 shallow buried waste sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The purpose of the research was to demonstrate a fluidless directional drilling and monitoring system (FDD) specifically tailored to address environmental drilling concerns for shallow buried wasted. The major concerns are related to worker exposure, minimizing waste generation, and confining the spread of contamination. The FDD is potentially applicable to Environmental Restoration (ER) activities for the Oak Ridge National Laboratory Waste Area Grouping 6 (WAG 6) shallow buried waste disposed in unlined trenches. Major ER activities for directional drilling are to develop a drilling system for leachate collection directly beneath trenches, and to provide localized control over leachate release tomore » the environment. Other ER FDD activities could include vadose zone and groundwater monitoring of contaminant transport. The operational constraints pointed the research in the direction of purchasing a steerable impact hammer, or mole, manufactured by Steer-Rite Ltd. of Racine, Wisconsin. This drill was selected due to the very low cost ($25,000) associated with procuring the drill, steering module, instrumentation and service lines. The impact hammer is a self propelled drill which penetrates the soil by compacting cut material along the sidewalls of the borehole. Essentially, it forces its way through the subsurface. Although the pneumatic hammer exhausts compressed air which must be handled at the borehole collar, it does not generate soil cuttings or liquids. This is the basis for the term fluidless. A stub casing muffler was attached to the entrance hole for controlling exhaust gas and any airborne releases. Other environmental compliance modifications made to the equipment included operating the tool without lubrication, and using water instead of hydraulic fluid to actuate the steering fins on the tool.« less

Effect of fermentation time of mixture of solid and liquid wastes from tapioca industry to percentage reduction of TSS (Total Suspended Solids)

NASA Astrophysics Data System (ADS)

Pandia, S.; Tanata, S.; Rachel, M.; Octiva, C.; Sialagan, N.

2018-02-01

The waste from tapioca industry is as an organic waste that contains many important compounds such as carbohydrate, protein, and glucose. This research as aimed to know the effect of fermentation time from solid waste combined with waste-water from the tapioca industry to percentage reduction of TSS. The study was started by mixing the solid and liquid wastes from tapioca industry at a ratio of 70:30, 60:40, 50:50, 40:60, and 30:70 (w/w) with a starter from solid waste of cattle in a batch anaerobic digester. The percentage reduction of TSS was 72.2289 at a ratio by weight of the composition of solid and liquid wastes from tapioca industry was 70:30 after 30 days of fermentation time.

Examining of solid waste generation and community awareness between city center and suburban area in Medan City, Indonesia

NASA Astrophysics Data System (ADS)

Khair, H.; Putri, C. N.; Dalimunthe, R. A.; Matsumoto, T.

2018-02-01

Municipal solid waste (MSW) management is still an issue in many cities in Indonesia including Medan. Understanding the waste generation, its characteristic and communities involvement could provide effective solid waste management. This research compares waste generation from people who live in the city center and suburban area. The research also examines the willingness and participation of community about environmental aspect, especially solid waste management. The method of waste generation used Indonesian Nasional Standard 19-3964-1994. The city center generates 0.295 kg/person/day of solid waste and 0.180 kg/person/day for suburbs. The result showed that there are the common amount of waste compositions between the city center and suburban area. The majority waste composition was an organic fraction. Questionnaires were distributed to examine the community awareness. The descriptive statistic used to analyze the data. The result showed that people living in the city center are slightly higher in community awareness than in the suburb. This paper highlights that area of living could give some effect to solid waste generation, waste composition and rate of awareness.

Village environs as source of nitrate contamination in groundwater: a case study in basaltic geo-environment in central India.

PubMed

Reddy, D V; Nagabhushanam, P; Peters, Edward

2011-03-01

Nitrate is one of the common contaminants in the present day groundwaters resulting from increased population associated with poor sanitary conditions in the habitat area and increased agricultural activity. The hydrochemical measurements on water samples from a virgin watershed, situated in the basaltic geo-environment, have become necessary as the groundwater is the only source of drinking water for the villagers of the area. High preferential recharge conditions prevail in the area due to fractures in the solid basaltic lava flows. Instead of dilution due to fresh recharge, the post-monsoon hydrochemical concentrations in the groundwater are observed to have increased probably due to fast migration of pollutants to the aquifer through preferential recharge. As a result, the deep aquifer waters are more contaminated with hazardous nitrate than the shallow waters. Further, the village environ wells are more polluted with nitrate than the agriculture areas which could be attributed to the unhygienic sanitary conditions and livestock waste dump pits in the villages. This study suggests proper management of the sewage system and creation of suitable dump yard for the livestock and household waste to minimize the level of nitrate pollution in the well waters of village environs.

Multiple-tracer tests for contaminant transport process identification in saturated municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woodman, N.D., E-mail: n.d.woodman@soton.ac.uk; Rees-White, T.C.; Stringfellow, A.M.

2015-04-15

Highlights: • Multiple tracers were applied to saturated MSW to test dual-porosity properties. • Lithium demonstrated to be non-conservative as a tracer. • 260 mm diameter column too small to test transport properties of MSW. • The classical advection-dispersion mode was rejected due to high dispersivity. • Characteristic diffusion times did not vary with the tracer. - Abstract: Two column tests were performed in conditions emulating vertical flow beneath the leachate table in a biologically active landfill to determine dominant transport mechanisms occurring in landfills. An improved understanding of contaminant transport process in wastes is required for developing better predictionsmore » about potential length of the long term aftercare of landfills, currently measured in timescales of centuries. Three tracers (lithium, bromide and deuterium) were used. Lithium did not behave conservatively. Given that lithium has been used extensively for tracing in landfill wastes, the tracer itself and the findings of previous tests which assume that it has behaved conservatively may need revisiting. The smaller column test could not be fitted with continuum models, probably because the volume of waste was below a representative elemental volume. Modelling compared advection-dispersion (AD), dual porosity (DP) and hybrid AD–DP models. Of these models, the DP model was found to be the most suitable. Although there is good evidence to suggest that diffusion is an important transport mechanism, the breakthrough curves of the different tracers did not differ from each other as would be predicted based on the free-water diffusion coefficients. This suggested that solute diffusion in wastes requires further study.« less

RCRA Facility Investigation report for Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Volume 1. Sections 1 through 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1991-09-01

WAG 6 comprises a shallow land burial facility used for disposal of low-level radioactive wastes (LLW) and, until recently, chemical wastes. As such, the site is subject to regulation under RCRA and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). To comply with these regulations, DOE, in conjunction with the Environmental Protection Agency (EPA) and the Tennessee Department of Environment and Conservation (TDEC), developed a strategy for closure and remediation of WAG 6 by 1997. A key component of this strategy was to complete an RFI by September 1991. The primary objectives of the RFI were to evaluate themore » site's potential human health and environmental impacts and to develop a preliminary list of alternatives to mitigate these impacts. The WAG 6 one of three solid waste management units evaluated Oak Ridge National Laboratory (ORNL) existing waste disposal records and sampling data and performed the additional sampling and analysis necessary to: describe the nature and extent of contamination; characterize key contaminant transport pathways; and assess potential risks to human health and the environment by developing and evaluating hypothetical receptor scenarios. Estimated excess lifetime cancer risks as a result for exposure to radionuclides and chemicals were quantified for each hypothetical human receptor. For environmental receptors, potential impacts were qualitatively assessed. Taking into account regulatory requirements and base line risk assessment results, preliminary site closure and remediation objectives were identified, and a preliminary list of alternatives for site closure and remediation was developed.« less

Evaluating the operational risks of biomedical waste using failure mode and effects analysis.

PubMed

Chen, Ying-Chu; Tsai, Pei-Yi

2017-06-01

The potential problems and risks of biomedical waste generation have become increasingly apparent in recent years. This study applied a failure mode and effects analysis to evaluate the operational problems and risks of biomedical waste. The microbiological contamination of biomedical waste seldom receives the attention of researchers. In this study, the biomedical waste lifecycle was divided into seven processes: Production, classification, packaging, sterilisation, weighing, storage, and transportation. Twenty main failure modes were identified in these phases and risks were assessed based on their risk priority numbers. The failure modes in the production phase accounted for the highest proportion of the risk priority number score (27.7%). In the packaging phase, the failure mode 'sharp articles not placed in solid containers' had the highest risk priority number score, mainly owing to its high severity rating. The sterilisation process is the main difference in the treatment of infectious and non-infectious biomedical waste. The failure modes in the sterilisation phase were mainly owing to human factors (mostly related to operators). This study increases the understanding of the potential problems and risks associated with biomedical waste, thereby increasing awareness of how to improve the management of biomedical waste to better protect workers, the public, and the environment.

Tanks Focus Area annual report FY2000

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2000-12-01

The U.S. Department of Energy (DOE) continues to face a major radioactive waste tank remediation effort with tanks containing hazardous and radioactive waste resulting from the production of nuclear materials. With some 90 million gallons of waste in the form of solid, sludge, liquid, and gas stored in 287 tanks across the DOE complex, containing approximately 650 million curies, radioactive waste storage tank remediation is the nation's highest cleanup priority. Differing waste types and unique technical issues require specialized science and technology to achieve tank cleanup in an environmentally acceptable manner. Some of the waste has been stored for overmore » 50 years in tanks that have exceeded their design lives. The challenge is to characterize and maintain these contents in a safe condition and continue to remediate and close each tank to minimize the risks of waste migration and exposure to workers, the public, and the environment. In 1994, the DOE's Office of Environmental Management (EM) created a group of integrated, multiorganizational teams focusing on specific areas of the EM cleanup mission. These teams have evolved into five focus areas managed within EM's Office of Science and Technology (OST): Tanks Focus Area (TFA); Deactivation and Decommissioning Focus Area; Nuclear Materials Focus Area; Subsurface Contaminants Focus Area; and Transuranic and Mixed Waste Focus Area.« less

Rapid indentification of organic contaminants in pretreated waste water using AOTF near-IR spectometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eilert, A.J.; Danley, W.J.; Wang, Xiaolu

1995-12-31

A near-infrared analyzer utilizing state-of-the-art acousto-optic tunable filter (AOTF) spectrometry with digital wavelength control and high D* extended-range INGaAs TE-cooled detector provides excellent wavelength repeatability (better than 0.02 nm) and very high signal-to-noise ration. Because the AOTF dispersive element is completely solid-state (no-moving parts), as is the entire spectrometer, the instrument is small, rugged and very reliable. Using this spectrometer, methods employing chemometrics have been developed and applied to measure organic contaminants such as gasoline and a variety of jet fuels in water. Qualitative identification of contaminants was achieved with discriminant analysis software developed specifically for this task. Both themore » technique of grouping sample spectra into specific clusters based of Mahalanobis distances and that of matching each spectrum with the most representative member of the appropriate group of calibration spectra were used to identify contaminants. After initial classification, appropriate qualitative chemometric calibrations may be applied to more accurately assess the level of contamination. The instrument will be used to evaluate ground water supplies.« less

Anaerobic digestion of municipal solid waste: Technical developments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rivard, C.J.

1996-01-01

The anaerobic biogasification of organic wastes generates two useful products: a medium-Btu fuel gas and a compost-quality organic residue. Although commercial-scale digestion systems are used to treat municipal sewage wastes, the disposal of solid organic wastes, including municipal solid wastes (MSW), requires a more cost-efficient process. Modern biogasification systems employ high-rate, high-solids fermentation methods to improve process efficiency and reduce capital costs. The design criteria and development stages are discussed. These systems are also compared with conventional low-solids fermentation technology.

ASSESSMENT OF RADIOACTIVE AND NON-RADIOACTIVE CONTAMINANTS FOUND IN LOW LEVEL RADIOACTIVE WASTE STREAMS

DOE Office of Scientific and Technical Information (OSTI.GOV)

R.H. Little, P.R. Maul, J.S.S. Penfoldag

2003-02-27

This paper describes and presents the findings from two studies undertaken for the European Commission to assess the long-term impact upon the environment and human health of non-radioactive contaminants found in various low level radioactive waste streams. The initial study investigated the application of safety assessment approaches developed for radioactive contaminants to the assessment of nonradioactive contaminants in low level radioactive waste. It demonstrated how disposal limits could be derived for a range of non-radioactive contaminants and generic disposal facilities. The follow-up study used the same approach but undertook more detailed, disposal system specific calculations, assessing the impacts of bothmore » the non-radioactive and radioactive contaminants. The calculations undertaken indicated that it is prudent to consider non-radioactive, as well as radioactive contaminants, when assessing the impacts of low level radioactive waste disposal. For some waste streams with relatively low concentrations of radionuclides, the potential post-closure disposal impacts from non-radioactive contaminants can be comparable with the potential radiological impacts. For such waste streams there is therefore an added incentive to explore options for recycling the materials involved wherever possible.« less

Dose potential of sludge contaminated and/or TRU contaminated waste in B-25s for tornado and straight wind events

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aponte, C.I.

F and H Tank Farms generate supernate and sludge contaminated Low-Level Waste. The waste is collected, characterized, and packaged for disposal. Before the waste can be disposed of, however, it must be properly characterized. Since the radionuclide distribution in typical supernate is well known, its characterization is relatively straight forward and requires minimal effort. Non-routine waste, including potentially sludge contaminated, requires much more effort to effectively characterize. The radionuclide distribution must be determined. In some cases the waste can be contaminated by various sludge transfers with unique radionuclide distributions. In these cases, the characterization can require an extensive effort. Evenmore » after an extensive characterization effort, the container must still be prepared for shipping. Therefore a significant amount of time may elapse from the time the waste is generated until the time of disposal. During the time it is possible for a tornado or high wind scenario to occur. The purpose of this report is to determine the effect of a tornado on potential sludge contaminated waste, or Transuranic (TRU) waste in B-25s [large storage containers], to evaluate the potential impact on F and H Tank Farms, and to help establish a B-25 control program for tornado events.« less

Factors influencing household participation in solid waste management (Case study: Waste Bank Malang)

NASA Astrophysics Data System (ADS)

Maryati, S.; Arifiani, N. F.; Humaira, A. N. S.; Putri, H. T.

2018-03-01

Solid waste management is very important measure in order to reduce the amount of waste. One of solid waste management form in Indonesia is waste banks. This kind of solid waste management required high level of participation of the community. The objective of this study is to explore factors influencing household participation in waste banks. Waste bank in Malang City (WBM) was selected as case study. Questionnaires distribution and investigation in WBM were conducted to identify problems of participation. Quantitative analysis was used to analyze the data. The research reveals that education, income, and knowledge about WBM have relationship with participation in WBM.

Environmental and health impacts of household solid waste handling and disposal practices in third world cities: the case of the Accra Metropolitan Area, Ghana.

PubMed

Boadi, Kwasi Owusu; Kuitunen, Markku

2005-11-01

Inadequate provision of solid waste management facilities in Third World cities results in indiscriminate disposal and unsanitary environments, which threatens the health of urban residents. The study reported here examined household-level waste management and disposal practices in the Accra Metropolitan Area, Ghana. The residents of Accra currently generate large amounts of solid waste, beyond the management capabilities of the existing waste management system. Because the solid waste infrastructure is inadequate, over 80 percent of the population do not have home collection services. Only 13.5 percent of respondents are served with door-to-door collection of solid waste, while the rest dispose of their waste at communal collection points, in open spaces, and in waterways. The majority of households store their waste in open containers and plastic bags in the home. Waste storage in the home is associated with the presence of houseflies in the kitchen (r = .17, p < .0001). The presence of houseflies in the kitchen during cooking is correlated with the incidence of childhood diarrhea (r = .36, p < .0001). Inadequate solid waste facilities result in indiscriminate burning and burying of solid waste. There is an association between waste burning and the incidence of respiratory health symptoms among adults (r = .25, p < .0001) and children (r = .22, p < .05). Poor handling and disposal of waste are major causes of environmental pollution, which creates breeding grounds for pathogenic organisms, and the spread of infectious diseases. Improving access to solid waste collection facilities and services will help achieve sound environmental health in Accra.

40 CFR 445.2 - General definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... saturation which has been contaminated by activities associated with waste disposal. (b) Contaminated storm water means storm water which comes in direct contact with landfill wastes, the waste handling and... a landfill that may produce contaminated storm water include (but are not limited to): the open face...

40 CFR 445.2 - General definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... saturation which has been contaminated by activities associated with waste disposal. (b) Contaminated storm water means storm water which comes in direct contact with landfill wastes, the waste handling and... a landfill that may produce contaminated storm water include (but are not limited to): the open face...

Finite element analysis of ion transport in solid state nuclear waste form materials

NASA Astrophysics Data System (ADS)

Rabbi, F.; Brinkman, K.; Amoroso, J.; Reifsnider, K.

2017-09-01

Release of nuclear species from spent fuel ceramic waste form storage depends on the individual constituent properties as well as their internal morphology, heterogeneity and boundary conditions. Predicting the release rate is essential for designing a ceramic waste form, which is capable of effectively storing the spent fuel without contaminating the surrounding environment for a longer period of time. To predict the release rate, in the present work a conformal finite element model is developed based on the Nernst Planck Equation. The equation describes charged species transport through different media by convection, diffusion, or migration. And the transport can be driven by chemical/electrical potentials or velocity fields. The model calculates species flux in the waste form with different diffusion coefficient for each species in each constituent phase. In the work reported, a 2D approach is taken to investigate the contributions of different basic parameters in a waste form design, i.e., volume fraction, phase dispersion, phase surface area variation, phase diffusion co-efficient, boundary concentration etc. The analytical approach with preliminary results is discussed. The method is postulated to be a foundation for conformal analysis based design of heterogeneous waste form materials.

Inhibiting localized corrosion during storage of dilute SRP wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oblath, S.B.; Congdon, J.W.

1986-01-01

High-level radioactive waste will be incorporated in borosilicate glass in the Defense Waste Processing Facility (DWPF) at the Savannah River Plant (SRP). As part of this process, large volumes of inorganic salt wastes will be decontaminated for disposal as low-level waste. The principal contaminants, /sup 137/Cs and /sup 90/Sr, are removed by treatment with sodium tetraphenylborate and sodium titanate. The resulting solids will be slurried with a dilute salt solution and stored in existing carbon steel tanks for several years prior to processing and disposal. Initial tests indicated a tendency for localized corrosion of the tanks. An investigation, using nonradioactivemore » simulants for the expected solution compositions, identified inhibitors which would protect the steel. Changes in solution compositions over time, due to radiolytic effects, were also accounted for by the simulants. Six inhibitors were identified which would protect the steel tanks. The effects these inhibitors would have on later processing steps in the DWPF were then evaluated. After this process, only sodium nitrite remained as an inhibitor that was both effective and compatible with the DWPF. The use of this inhibitor has been demonstrated on a real waste slurry.« less

High Efficiency Particulate Air (HEPA) Filter Generation, Characterization, and Disposal Experiences at the Oak Ridge National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coffey, D. E.

2002-02-28

High Efficiency Particulate Air filtration is an essential component of the containment and ventilation systems supporting the research and development activities at the Oak Ridge National Laboratory. High Efficiency Particulate Air filters range in size from 7.6cm (3 inch) by 10.2 cm (4 inch) cylindrical shape filters to filter array assemblies up to 2.1 m (7 feet) high by 1.5 m (5 feet) wide. Spent filters are grouped by contaminates trapped in the filter media and become one of the components in the respective waste stream. Waste minimization and pollution prevention efforts are applied for both radiological and non-radiological applications.more » Radiological applications include laboratory hoods, glove boxes, and hot cells. High Efficiency Particulate Air filters also are generated from intake or pre-filtering applications, decontamination activities, and asbestos abatement applications. The disposal avenues include sanitary/industrial waste, Resource Conservation and Recovery Act and Toxic Substance Control Act, regulated waste, solid low-level waste, contact handled transuranic, and remote handled transuranic waste. This paper discusses characterization and operational experiences associated with the disposal of the spent filters across multiple applications.« less

Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering

DOEpatents

Vijayan, S.; Wong, C.F.; Buckley, L.P.

1994-11-22

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is recycled until the target is achieved. 1 fig.

Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering

DOEpatents

Vijayan, Sivaraman; Wong, Chi F.; Buckley, Leo P.

1994-01-01

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is recycled until the target is achieved.

Application of Vadose Zone Monitoring Technology for Characterization of Leachate Generation in Landfills

NASA Astrophysics Data System (ADS)

aharoni, imri; dahan, ofer

2016-04-01

Ground water contamination due to landfill leachate percolation is considered the most severe environmental threat related to municipal solid waste landfills. Natural waste degradation processes in landfills normally produce contaminated leachates up to decades after the waste has been buried. Studies have shown that understanding the mechanisms which govern attenuation processes and the fate of pollutants in the waste and in the underlying unsaturated zone is crucial for evaluation of environmental risks and selection of a restoration strategy. This work focuses on a closed landfill in the coastal plain of Israel that was active until 2002 without any lining infrastructure. A vadose zone monitoring system (VMS) that was implemented at the site enables continuous measurements across the waste body (15 m thick) and underlying sandy vadose zone (16 m thick). Data collected by the VMS included continuous measurements of water content as well as chemical composition of the leachates across the entire waste and vadose zone cross section. Results indicated that winter rain percolated through the waste, generating wetting waves which were observed across the waste and unsaturated sediment from land surface until groundwater at 31 m bls. Quick percolation and high fluxes were observed in spite of the clay cover that was implemented at the site as part of the rehabilitation scheme. The results show that the flow pattern is controlled by a preferential mechanism within the waste body. Specific sections showed rapid fluxes in response to rain events, while other sections remained unaffected. In the underlying sandy vadose zone the flow pattern exhibited characteristics of matrix flow. Yet, some sections received higher fluxes due to the uneven discharge of leachates from the overlying waste body. Water samples collected from the waste layer indicate production of highly polluted leachates over 14 years after the landfill was closed. The chemical composition within the waste body shows extreme variability between sampling ports with respect to DOC (407-31,464 mg/L), BOD/COD ratios (0.07-0.55), Fe2+ (6.8-1154 mg/L), NH4+ (68-2924 mg/L) and heavy metal concentrations. The results show for the first time the magnitude of heterogeneity inside a single landfill unit. Waste degradation hot-spots creating concentrated aggressive 'acid phase' leachates exist only 2m away from a 'stable methanogenic' environment which create basic and less polluted leachates. In the underlying vadose zone, contaminant concentrations decrease significantly especially with respect to organic matter and metals. The results suggest that biogeochemical attenuation processes are taking place in the deep unsaturated zone, changing the chemical characteristics of the solute before reaching the groundwater. On the other hand, the chemical composition is highly affected by the distribution of fluxes coming from the above waste layer.

40 CFR 266.205 - Standards applicable to the storage of solid waste military munitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... solid waste military munitions. 266.205 Section 266.205 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Military Munitions § 266.205 Standards...

40 CFR 266.205 - Standards applicable to the storage of solid waste military munitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... solid waste military munitions. 266.205 Section 266.205 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Military Munitions § 266.205 Standards...

40 CFR 266.205 - Standards applicable to the storage of solid waste military munitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... solid waste military munitions. 266.205 Section 266.205 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Military Munitions § 266.205 Standards...