Monte Carlo calculation of skyshine'' neutron dose from ALS (Advanced Light Source)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Moin-Vasiri, M.
1990-06-01
This report discusses the following topics on skyshine'' neutron dose from ALS: Sources of radiation; ALS modeling for skyshine calculations; MORSE Monte-Carlo; Implementation of MORSE; Results of skyshine calculations from storage ring; and Comparison of MORSE shielding calculations.
Sun, R K
1990-12-01
To investigate the radiation effect of neutrons near the Advanced Light Source (ALS) at Lawrence Berkeley Laboratory (LBL) with respect to the neutron dose equivalents in nearby occupied areas and at the site boundary, the neutron transport code MORSE, from Oak Ridge National Laboratory (ORNL), was used. These dose equivalents result from both skyshine neutrons transported by air scattering and direct neutrons penetrating the shielding. The ALS neutron sources are a 50-MeV linear accelerator and its transfer line, a 1.5-GeV booster, a beam extraction line, and a 1.9-GeV storage ring. The most conservative total occupational-dose-equivalent rate in the center of the ALS mezzanine, 39 m from the ALS center, was found to be 1.14 X 10(-3) Sv y-1 per 2000-h "occupational" year, and the total environmental-dose-equivalent rate at the ALS boundary, 125 m from the ALS center, was found to be 3.02 X 10(-4) Sv y-1 per 8760-h calendar year. More realistic dose-equivalent rates, using the nominal (expected) storage-ring current, were calculated to be 1.0 X 10(-4) Sv y-1 and 2.65 X 10(-5) Sv y-1 occupational year and calendar year, respectively, which are much lower than the DOE reporting levels.
ALS superbend magnet performance
DOE Office of Scientific and Technical Information (OSTI.GOV)
Marks, Steve; Zbasnik, John; Byrne, Warren
2001-12-10
The Lawrence Berkeley National Laboratory has been engaged in the design, construction and testing of four superconducting dipoles (Superbends) that are installed in three arcs of the Advanced Light Source (ALS), with the fourth magnet as a spare. This represents a major upgrade to the ALS providing an enhanced flux and brightness at photon energies above 10 keV. In preparation for installation, an extensive set of tests and measurements have been conducted to characterize the magnetic and cryogenic performance of the Superbends and to fiducialize them for accurate placement in the ALS storage ring. The magnets are currently installed, andmore » the storage ring is undergoing final commissioning. This paper will present the results of magnetic and cryogenic testing.« less
Tracking the 10Be-26Al source-area signal in sediment-routing systems of arid central Australia
NASA Astrophysics Data System (ADS)
Struck, Martin; Jansen, John D.; Fujioka, Toshiyuki; Codilean, Alexandru T.; Fink, David; Fülöp, Réka-Hajnalka; Wilcken, Klaus M.; Price, David M.; Kotevski, Steven; Fifield, L. Keith; Chappell, John
2018-05-01
Sediment-routing systems continuously transfer information and mass from eroding source areas to depositional sinks. Understanding how these systems alter environmental signals is critical when it comes to inferring source-area properties from the sedimentary record. We measure cosmogenic 10Be and 26Al along three large sediment-routing systems ( ˜ 100 000 km2) in central Australia with the aim of tracking downstream variations in 10Be-26Al inventories and identifying the factors responsible for these variations. By comparing 56 new cosmogenic 10Be and 26Al measurements in stream sediments with matching data (n = 55) from source areas, we show that 10Be-26Al inventories in hillslope bedrock and soils set the benchmark for relative downstream modifications. Lithology is the primary determinant of erosion-rate variations in source areas and despite sediment mixing over hundreds of kilometres downstream, a distinct lithological signal is retained. Post-orogenic ranges yield catchment erosion rates of ˜ 6-11 m Myr-1 and silcrete-dominant areas erode as slow as ˜ 0.2 m Myr-1. 10Be-26Al inventories in stream sediments indicate that cumulative-burial terms increase downstream to mostly ˜ 400-800 kyr and up to ˜ 1.1 Myr. The magnitude of the burial signal correlates with increasing sediment cover downstream and reflects assimilation from storages with long exposure histories, such as alluvial fans, desert pavements, alluvial plains, and aeolian dunes. We propose that the tendency for large alluvial rivers to mask their 10Be-26Al source-area signal differs according to geomorphic setting. Signal preservation is favoured by (i) high sediment supply rates, (ii) high mean runoff, and (iii) a thick sedimentary basin pile. Conversely, signal masking prevails in landscapes of (i) low sediment supply and (ii) juxtaposition of sediment storages with notably different exposure histories.
Towards a 4{sup th} generation storage ring at the Canadian Light Source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dallin, Les; Wurtz, Ward
2016-07-27
Demands from beamline scientists for more brilliant sources of synchrotron radiation have resulted in the emergence of 4{sup th} generation (diffraction-limited) storage rings. The practical development of the multi-bend achromat (MBA) concept by MAX IV lab has spurred many synchrotron light sources around the world to develop similar machines. For existing facilities two options are available: upgrading existing machines or building a new structure. The Canadian Light Source (CLS) has explored both options. For a new low emittance source in the existing CLS tunnel a decrease in electron energy would be required. A machine similar to the ALS upgrade couldmore » be contemplated. To achieve low emittance at our present energy of 2.9 GeV a new storage ring is desirable. Several options have been investigated. These designs use extremely strong focusing magnets to achieve extremely low emittances in compact lattice achromats.« less
NASA Technical Reports Server (NTRS)
Rice, R. C.; Reynolds, J. L.
1976-01-01
Fatigue, fatigue-crack-propagation, and fracture data compiled and stored on magnetic tape are documented. Data for 202 and 7075 aluminum alloys, Ti-6Al-4V titanium alloy, and 300M steel are included in the compilation. Approximately 4,500 fatigue, 6,500 fatigue-crack-propagation, and 1,500 fracture data points are stored on magnetic tape. Descriptions of the data, an index to the data on the magnetic tape, information on data storage format on the tape, a listing of all data source references, and abstracts of other pertinent test information from each data source reference are included.
Comportement d'une source karstique soumise à une sécheresse prolongée : la source Bittit (Maroc)
NASA Astrophysics Data System (ADS)
Amraoui, Fouad; Razack, Moumtaz; Bouchaou, Lhoussaine
2004-09-01
The behaviour of a karstic spring (Bittit spring, Middle Atlas, Morocco) subjected to a prolonged drought (>20 yr), is analysed using spring hydrographs analysis methods and correlation and spectral methods. Two series of discharges, corresponding to a normal rainfall period and a drought period, are analysed. The results show that the karstic system is inertial, with very significant storage. However, in spite of the great regulating capacity of the storage, the long drought period significantly reduced the spring discharges, due to less diversified inputs, and to the karstic system storage depletion. To cite this article: F. Amraoui et al., C. R. Geoscience 336 (2004).
Evaluation of actuator energy storage and power sources for spacecraft applications
NASA Technical Reports Server (NTRS)
Simon, William E.; Young, Fred M.
1993-01-01
The objective of this evaluation is to determine an optimum energy storage/power source combination for electrical actuation systems for existing (Solid Rocket Booster (SRB), Shuttle) and future (Advanced Launch System (ALS), Shuttle Derivative) vehicles. Characteristic of these applications is the requirement for high power pulses (50-200 kW) for short times (milliseconds to seconds), coupled with longer-term base or 'housekeeping' requirements (5-16 kW). Specific study parameters (e.g., weight, volume, etc.) as stated in the proposal and specified in the Statement of Work (SOW) are included.
Structural Characterization of Metal Hydrides for Energy Applications
NASA Astrophysics Data System (ADS)
George, Lyci
Hydrogen can be an unlimited source of clean energy for future because of its very high energy density compared to the conventional fuels like gasoline. An efficient and safer way of storing hydrogen is in metals and alloys as hydrides. Light metal hydrides, alanates and borohydrides have very good hydrogen storage capacity, but high operation temperatures hinder their application. Improvement of thermodynamic properties of these hydrides is important for their commercial use as a source of energy. Application of pressure on materials can have influence on their properties favoring hydrogen storage. Hydrogen desorption in many complex hydrides occurs above the transition temperature. Therefore, it is important to study the physical properties of the hydride compounds at ambient and high pressure and/or high temperature conditions, which can assist in the design of suitable storage materials with desired thermodynamic properties. The high pressure-temperature phase diagram, thermal expansion and compressibility have only been evaluated for a limited number of hydrides so far. This situation serves as a main motivation for studying such properties of a number of technologically important hydrides. Focus of this dissertation was on X-ray diffraction and Raman spectroscopy studies of Mg2FeH6, Ca(BH4) 2, Mg(BH4)2, NaBH4, NaAlH4, LiAlH4, LiNH2BH3 and mixture of MgH 2 with AlH3 or Si, at different conditions of pressure and temperature, to obtain their bulk modulus and thermal expansion coefficient. These data are potential source of information regarding inter-atomic forces and also serve as a basis for developing theoretical models. Some high pressure phases were identified for the complex hydrides in this study which may have better hydrogen storage properties than the ambient phase. The results showed that the highly compressible B-H or Al-H bonds and the associated bond disordering under pressure is responsible for phase transitions observed in brorohydrides or alanates. Complex hydrides exhibited very high compressibility suggesting possibility to destabilize them with pressure. With high capacity and favorable thermodynamics, complex hydrides are suitable for reversible storage. Further studies are required to overcome the kinetic barriers in complex hydrides by catalytic addition. A comparative study of the hydride properties with that of the constituting metal, and their inter relationships were carried out with many interesting features.
Commissioning of BL 7.2, the new diagnostic beam line at the ALS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sannibale, Fernando; Baum, Dennis; Biocca, Alan
2004-06-29
BL 7.2 is a new beamline at the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory (LBNL) dedicated to electron beam diagnostics. The system, which is basically a hard x-ray pinhole camera, was installed in the storage ring in August 2003 and commissioning with the ALS electron beam followed immediately after. In this paper the commissioning results are presented together with the description of the relevant measurements performed for the beamline characterization.
Survey and Alighment for the ALS Project at LBL Berkeley
DOE Office of Scientific and Technical Information (OSTI.GOV)
Keller, R.; Lauritzen, T.; /LBL, Berkeley
2005-08-12
The Advanced Light Source (ALS), now under construction at Lawrence Berkeley Laboratory, is a synchrotron radiation source of the third generation designed to produce extremely bright photon beams in the UV and soft X-ray regions. Its main accelerator components are a 1-1.9 GeV electron storage ring with 196.8 m circumference and 12 super-periods, a 1.5 GeV booster synchrotron with 75.0 m circumference and 4 super-periods, and a 50 MeV linac, as shown in Fig. 1. The storage ring has particularly tight positioning tolerances for lattice magnets and other components to assure the required operational characteristics. The general survey and alignmentmore » concept for the ALS is based on a network of fixed monuments installed in the building floor, to which all component positions are referred. Measurements include electronic distance measurements and separate sightings for horizontal and vertical directions, partially with automated electronic data capture. Most of the data processing is accomplished by running a customized version of PC-GEONET. It provides raw data storage, data reduction, and the calculation of adjusted coordinates, as well as an option for error analysis. PC-GEONET has also been used to establish an observation plan for the monuments and calculate their expected position accuracies, based on approximate coordinates. Additionally, for local survey tasks, the commercial software package ECDS is used. In this paper, the ALS survey and alignment strategy and techniques are presented and critically discussed. First experiences with the alignment of the linac and booster components are described.« less
NASA Astrophysics Data System (ADS)
Lynn, K. J.; Costa Rodriguez, F.; Shea, T.; Garcia, M. O.
2015-12-01
Kilauea is generally characterized by its modern effusive activity, but the past 2500 years were dominated by cycles of explosive and effusive eruptions lasting 100's of years (Swanson et al. 2012). These different eruption styles may reflect variable volatile contents in the source that control magma ascent rate and storage durations (e.g., Sides et al. 2014). A detailed petrological study of the dominantly explosive Keanakako'i tephras (1500-1820 CE) was undertaken to better understand the storage and transport conditions preceding high-energy eruptions. Here, we focus on preliminary results for olivine from the 1500 CE Basal Reticulite (>600 m fountain; May et al. 2015). Olivine major (Fe, Mg), minor (Mn, Ca, Ni) and trace (Li, Na, Al, P, Sc, Ti, V, Cr, Co, Zn) element traverses and 2D maps were collected for 10 crystals and reveal two major populations. The dominant population has homogeneous Fo89 and Fo87 cores with thin (3-12 μm) rims of intermediate composition (Fo87.5-88.5). Normal, reverse, and complex trace element zoning (Al, P, Ti, Cr) is prominent in these otherwise homogenous (Fo, Ni, Ca, Mn) crystals. 2D maps reveal early skeletal growth and the progressive decrease of Cr from core to rim suggests olivine and Cr-spinel crystallization, which should produce significant Fo zoning. Absence of Fo zoning could imply significant storage time in a reservoir allowing homogenization. The majority of rim compositions are out of equilibrium with adhering glass, and Fe-Mg modeling indicates that their residence within the carrier melt was of a few days. A second population consists of strongly zoned (normal and reverse) crystals with a wide range of core Fo (78 to 89) and Fo82-84 rims. Timescales from Fe-Mg zoning are up to 1 year, and may record storage histories before interaction with the carrier melt. The diversity in olivine zoning suggests at least two stages of magma mixing, and a more complex evolution for the magmas that fed the reticulite eruptions than a simple closed-system and fast transport of a volatile-rich magma from the source to the surface.
Mineral Carbonation Potential of CO2 from Natural and Industrial-based Alkalinity Sources
NASA Astrophysics Data System (ADS)
Wilcox, J.; Kirchofer, A.
2014-12-01
Mineral carbonation is a Carbon Capture and Storage (CSS) technology where gaseous CO2 is reacted with alkaline materials (such as silicate minerals and alkaline industrial wastes) and converted into stable and environmentally benign carbonate minerals (Metz et al., 2005). Here, we present a holistic, transparent life cycle assessment model of aqueous mineral carbonation built using a hybrid process model and economic input-output life cycle assessment approach. We compared the energy efficiency and the net CO2 storage potential of various mineral carbonation processes based on different feedstock material and process schemes on a consistent basis by determining the energy and material balance of each implementation (Kirchofer et al., 2011). In particular, we evaluated the net CO2 storage potential of aqueous mineral carbonation for serpentine, olivine, cement kiln dust, fly ash, and steel slag across a range of reaction conditions and process parameters. A preliminary systematic investigation of the tradeoffs inherent in mineral carbonation processes was conducted and guidelines for the optimization of the life-cycle energy efficiency are provided. The life-cycle assessment of aqueous mineral carbonation suggests that a variety of alkalinity sources and process configurations are capable of net CO2 reductions. The maximum carbonation efficiency, defined as mass percent of CO2 mitigated per CO2 input, was 83% for CKD at ambient temperature and pressure conditions. In order of decreasing efficiency, the maximum carbonation efficiencies for the other alkalinity sources investigated were: olivine, 66%; SS, 64%; FA, 36%; and serpentine, 13%. For natural alkalinity sources, availability is estimated based on U.S. production rates of a) lime (18 Mt/yr) or b) sand and gravel (760 Mt/yr) (USGS, 2011). The low estimate assumes the maximum sequestration efficiency of the alkalinity source obtained in the current work and the high estimate assumes a sequestration efficiency of 85%. The total CO2 storage potential for the alkalinity sources considered in the U.S. ranges from 1.3% to 23.7% of U.S. CO2 emissions, depending on the assumed availability of natural alkalinity sources and efficiency of the mineral carbonation processes.
Wronski, Zbigniew S; Varin, Robert A; Czujko, Tom
2009-07-01
In this study we discuss a process of mechanical activation employed in place of chemical or thermal activation to improve the mobility and reactivity of hydrogen atoms and ions in nanomaterials for energy applications: rechargeable batteries and hydrogen storage for fuel cell systems. Two materials are discussed. Both are used or intended for use in power sources. One is nickel hydroxide, Ni(OH)2, which converts to oxyhydroxide in the positive Ni electrode of rechargeable metal hydride batteries. The other is a complex hydride, Mg(AIH4)2, intended for use in reversible, solid-state hydrogen storage for fuel cells. The feature shared by these unlikely materials (hydroxide and hydride) is a sheet-like hexagonal crystal structure. The mechanical activation was conducted in high-energy ball mills. We discuss and demonstrate that the mechanical excitation of atoms and ions imparted on these powders stems from the same class of phenomena. These are (i) proliferation of structural defects, in particular stacking faults in a sheet-like structure of hexagonal crystals, and (ii) possible fragmentation of a faulted structure into a mosaic of layered nanocrystals. The hydrogen atoms bonded in such nanocrystals may be inserted and abstracted more easily from OH- hydroxyl group in Ni(OH)2 and AlH4- hydride complex in Mg(AlH4)2 during hydrogen charge and discharge reactions. However, the effects of mechanical excitation imparted on these powders are different. While the Ni(OH)2 powder is greatly activated for cycling in batteries, the Mg(AlH4)2 complex hydride phase is greatly destabilized for use in reversible hydrogen storage. Such a "synchronic" view of the structure-property relationship in respect to materials involved in hydrogen energy storage and conversion is supported in experiments employing X-ray diffraction (XRD), differential scanning calorimetry (DSC) and direct imaging of the structure with a high-resolution transmission-electron microscope (HREM), as well as in property characterization.
Noise reduction efforts for the ALS infrared beamlines
DOE Office of Scientific and Technical Information (OSTI.GOV)
Scarvie, Tom; Andresen, Nord; Baptiste, Ken
2003-08-10
The quality of infrared microscopy and spectroscopy data collected at synchrotron based sources is strongly dependent on signal-to-noise. We have successfully identified and suppressed several noise sources affecting Beamlines 1.4.2, 1.4.3, and 1.4.4 at the Advanced Light Source (ALS), resulting in a significant increase in the quality of FTIR spectra obtained. In this paper, we present our methods of noise source analysis, the negative effect of noise on the infrared beam quality, and the techniques used to reduce the noise. These include reducing the phase noise in the storage ring radio-frequency (RF) system, installing an active mirror feedback system, analyzingmore » and changing physical mounts to better isolate portions of the beamline optics from low-frequency environmental noise, and modifying the input signals to the main ALS RF system. We also discuss the relationship between electron beam energy oscillations at a point of dispersion and infrared beamline noise.« less
Noise Reduction Efforts for the ALS Infrared Beamlines
DOE Office of Scientific and Technical Information (OSTI.GOV)
Scarvie, Tom; Andresen, Nord; Baptiste, Ken
2004-05-12
The quality of infrared microscopy and spectroscopy data collected at synchrotron based sources is strongly dependent on signal-to-noise. We have successfully identified and suppressed several noise sources affecting Beamlines 1.4.2, 1.4.3, and 1.4.4 at the Advanced Light Source (ALS), resulting in a significant increase in the quality of FTIR spectra obtained. In this paper, we present our methods of noise source analysis, the negative effect of noise on the infrared beam quality, and the techniques used to reduce the noise. These include reducing the phase noise in the storage ring radio-frequency (RF) system, installing an active mirror feedback system, analyzingmore » and changing physical mounts to better isolate portions of the beamline optics from low-frequency environmental noise, and modifying the input signals to the main ALS RF system. We also discuss the relationship between electron beam energy oscillations at a point of dispersion and infrared beamline noise.« less
Recent Beam Measurements and New Instrumentation at the Advanced Light Source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sannibale, F.; Baptiste, K.; Barry, W.
2012-04-11
The Advanced Light Source (ALS) in Berkeley was the first of the soft x-ray third generation light source ever built, and since 1993 has been in continuous and successful operation serving a large community of users in the VUV and soft x-ray community. During these years the storage ring underwent through several important upgrades that allowed maintaining the performance of this veteran facility at the forefront. The ALS beam diagnostics and instrumentation have followed a similar path of innovation and upgrade and nowadays include most of the modem and last generation devices and technologies that are commercially available and usedmore » in the recently constructed third generation light sources. In this paper we will not focus on such already widely known systems, but we will concentrate our effort in the description of some measurements techniques, instrumentation and diagnostic systems specifically developed at the ALS and used during the last few years.« less
RECENT BEAM MEASUREMENTS AND NEW INSTRUMENTATION AT THE ADVANCED LIGHT SOURCE
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sannibale, Fernando; Baptiste, Kenneth; Barry, Walter
2008-05-05
The Advanced Light Source (ALS) in Berkeley was the first of the soft x-ray third generation light source ever built, and since 1993 has been in continuous and successful operation serving a large community of users in the VUV and soft x-ray community. During these years the storage ring underwent through several important upgrades that allowed maintaining the performance of this veteran facility at the forefront. The ALS beam diagnostics and instrumentation have followed a similar path of innovation and upgrade and nowadays include most of the modem and last generation devices and technologies that are commercially available and usedmore » in the recently constructed third generation light sources. In this paper we will not focus on such already widely known systems, but we will concentrate our effort in the description of some measurements techniques, instrumentation and diagnostic systems specifically developed at the ALS and used during the last few years.« less
Superbend era begins swiftly at the ALS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Robinson, Art; Tamura, Lori
2001-11-29
The successful installation and commissioning of high-field superconducting bend magnets (superbends) in three curved sectors of ALS storage ring was the first time the magnet lattice of an operating synchrotron light source has been retrofitted in this fundamental way. As a result, the ALS now offers an expanded spectral range well into the hard x-ray region without compromising either the number of undulators or their high brightness in the soft x-ray region for which the ALS design was originally optimized. In sum, when the superbend-enhanced ALS started up for user operations in October 2001, it marked the beginning of amore » new era in its history.« less
Aluminum in erythropoietin formulations: lyophilized versus liquid forms.
Veiga, Marlei; Bohrer, Denise; Noremberg, Simone; Mattiazzi, Patricia; do Nascimento, Paulo C; de Carvalho, Leandro M
2013-01-01
Erythropoietin (EPO) formulations may comprise aluminum (Al) as a contaminant. Due to the toxicity of Al in chronic kidney disease patients, possible sources of Al were investigated. Since EPO formulations are stored in container-closure systems made of glass and rubber, and both contain Al, formulation ingredients may enable its leaching into the solution during shelf-life. Individual solutions of formulation ingredients were stored in new glass vials and in contact with the rubber stopper and kept at 4 ± 2 °C. For 12 months, aliquots of each solution were collected for analysis. Fifteen commercial samples of EPO were analyzed for their Al content. Aluminum was determined by atomic absorption spectrometry. Glass and rubber are sources of Al for EPO formulations. Storage assay showed that citrate and phosphate (used as buffers) extracted high amounts of Al from the container/closure parts. The most important difference, however, was found when comparing liquid and lyophilized samples. While in liquid forms the Al level reached 943 μg/L, in lyophilized forms the level did not exceed 20 μg/L. The container system was also confirmed as a source of Al in reconstituted lyophilized samples. Al in reconstituted samples stored in their own vials increased 19-fold in 12 months. Lyophilized powders stored for 2 years in glass vials contained less Al than in 1 month after dissolution. The difference in the Al measured in liquid forms of EPO and in lyophilized powders suggests that the latter would be the best pharmaceutical form for CKD patients.
Attention and Trust Biases in the Design of Augmented Reality Displays
2000-04-01
storage, selective attention , and their mutual constraints within the human information processing system. Psychological Bulletin, 104(2), 163-191...the pilots’ attention at the cost of processing other information in the far domain beyond the symbology, i.e., attentional tunneling (Fadden et al...need to select between two sources of information, attention is allocated to the one which facilitates the user’s task. When only a single source of
Wilhelm, M; Ohnesorge, F K
1990-01-01
The influence of storage temperature, vessel type, and treatment on alterations of aluminum (Al) concentrations in serum, urine, and dialysis fluid samples was studied at three different concentrations for each sample over an 18-month period. Furthermore, the influence of acidification on Al levels in tap water, urine, and dialysis fluid samples was studied over a four-month period. Al was measured by atomic absorption spectrometry. Sample storage in glass vessels was unsuitable, whereas only minor alterations of Al levels were observed with storage in polypropylene tubes, polystyrene tubes, and Monovettes. By using appropriate plastic containers, acid washing of the vessels showed no improvement. Frozen storage was superior compared with 4 degrees C, whereas storage at -80 degrees C offered no advantage compared with storage at -20 degrees C. Acidification of tap water samples was necessary to stabilize Al levels during storage. No striking effect of acidification on Al levels in urine and dialysis fluid samples was found. It is concluded that longterm storage of serum, urine, tap water, and dialysis fluid samples is possible if appropriate conditions are used.
What is the main driver of atmospheric CO2 dynamic: ocean or permafrost?
NASA Astrophysics Data System (ADS)
Zimov, S. A.; Zimov, N.
2010-12-01
Majority have assumed that during the Last Deglaciation (LD) ocean was a strong source of carbon (C) transporting hundreds of gigatons of C into the terrestrial and atmospheric storages. Increase in the δ13C of foraminifera shells during the LD by 0.3-0.4 per mil considered as an evidence of such a source. However terrestrial and oceanic branches of the biological carbon cycle have very similar carbon isotopic signatures and carbon storage capacities. So the same δ13C increase could be caused by an oceanic bio-productivity increase and the increase of C in bottom sediments (Brovkin et al. 2002). Additionally it has been shown experimentally that at 90 ppmv increase in atmospheric CO2, due to changes in the concentration of carbonate ions in sea water, would cause the δ13C of foraminifera shells to increase by at least 0.25-0.5 per mil (Spero et al. 1997). At all stable parameters to equilibrate for 90 ppm CO2 increase in the atmosphere ocean inorganic C reservoir should have increased by 1800 Gt C (Sigman et al. 2000). Therefore it is very hard to find a mechanism which would allow ocean in LD to release carbon instead of absorbing it, and such a mechanism haven’t been found so far. Methane (CH4) produced by steppe-tundra biome (ST) soil thawing has a unique isotopic signal depleted in all isotopes. Inclusion of this source into a model of the atmospheric methane isotope budget allowed us to reconstruct the dynamics of methane’s main sources. Results indicated that thawing of ST soils during the deglaciation, were the largest methane source and resulted in 255 Gt C emitted in the form of CH4 to the atmosphere (Zimov, see AGU 2010). When soil turns anaerobic only minor portion of soil C converts into CH4. Bigger portion of ST didn’t turn anaerobic at all and all decomposing C was turned into CO2. Besides that part of the soil CH4 flux was consumed by methanotrophs. Therefore C storage in ST soils were many times higher then CH4 emission into the atmosphere. In LD bigger portion of ST soils thawed and after drainage and aeration lost its carbon. Based on field experiments we calculated the portion of total ST soils C which transforms into CH4, and using the model describing the C accumulation in ST soils (Zimov et al. 2009) estimated that at CH4 emission of 255 Gt C , emission of CO2 was ~3000 Gt C. From this follows that for the duration of glaciation C storage in ocean strongly reduced. As follows from CH4 dynamic most intensive C release from permafrost was in Bolling-Allerod and Pre-Boreal, but at that time increased ocean ventilation and bioproductivity (Skinner et al. 2010). Depleted with C Ocean absorbed CO2 from atmosphere and compensated for emission from permafrost so rise in atmospheric CO2 concentrations didn’t occur at that time.
Atmospheric Hydrogen (H2) Concentrations from the CSIRO GASLAB Flask Sampling Network (1992 - 2001)
Steele, L. P. [Commonwealth Scientific and Industrial Research Organization (CSIRO), Atmospheric Research, Aspendale, Victoria, Australia; Krummel, P. B. [Commonwealth Scientific and Industrial Research Organization (CSIRO), Atmospheric Research, Aspendale, Victoria, Australia; Langenfelds, R. L. [Commonwealth Scientific and Industrial Research Organization (CSIRO), Atmospheric Research, Aspendale, Victoria, Australia
2003-01-01
Air samples from nine sites were collected from the CSIRO GASLAB Flask Sampling Network for the purpose of monitoring the atmospheric hydrogen (H2) concentrations. The listed data were obtained from flask air samples returned to the CSIRO GASLAB for analysis. Typical sample storage times ranged from days to weeks for some sites (e.g., Cape Grim) to as much as one year for Macquarie Island and the Antarctic sites. Experiments carried out to test for any change in sample H22 mixing ratio during storage have shown no consistent and systematic drift in these flask types over test periods of several months to years (Cooper et al., 1999). An annual cycle of H2 is evident, reflecting the seasonal nature of some of the major sources and sinks (Novelli et al., 1999).
An aluminium nitride light-emitting diode with a wavelength of 210 nanometres.
Taniyasu, Yoshitaka; Kasu, Makoto; Makimoto, Toshiki
2006-05-18
Compact high-efficiency ultraviolet solid-state light sources--such as light-emitting diodes (LEDs) and laser diodes--are of considerable technological interest as alternatives to large, toxic, low-efficiency gas lasers and mercury lamps. Microelectronic fabrication technologies and the environmental sciences both require light sources with shorter emission wavelengths: the former for improved resolution in photolithography and the latter for sensors that can detect minute hazardous particles. In addition, ultraviolet solid-state light sources are also attracting attention for potential applications in high-density optical data storage, biomedical research, water and air purification, and sterilization. Wide-bandgap materials, such as diamond and III-V nitride semiconductors (GaN, AlGaN and AlN; refs 3-10), are potential materials for ultraviolet LEDs and laser diodes, but suffer from difficulties in controlling electrical conduction. Here we report the successful control of both n-type and p-type doping in aluminium nitride (AlN), which has a very wide direct bandgap of 6 eV. This doping strategy allows us to develop an AlN PIN (p-type/intrinsic/n-type) homojunction LED with an emission wavelength of 210 nm, which is the shortest reported to date for any kind of LED. The emission is attributed to an exciton transition, and represents an important step towards achieving exciton-related light-emitting devices as well as replacing gas light sources with solid-state light sources.
Influence of elevated Fe, Zn, and Cd on uptake and translocation of mineral elements in common bean
USDA-ARS?s Scientific Manuscript database
Common bean is an important crop plant and source of human health related macro- and micronutrients. Common bean uptake these nutrients from the soil environment and transport them to various storage tissues using proteins and genes located in different tissues (Phan-Thein et al. 2010). However, alo...
Bader, Markus
2018-01-01
This paper presents three acceptability experiments investigating German verb-final clauses in order to explore possible sources of sentence complexity during human parsing. The point of departure was De Vries et al.'s (2011) generalization that sentences with three or more crossed or nested dependencies are too complex for being processed by the human parsing mechanism without difficulties. This generalization is partially based on findings from Bach et al. (1986) concerning the acceptability of complex verb clusters in German and Dutch. The first experiment tests this generalization by comparing two sentence types: (i) sentences with three nested dependencies within a single clause that contains three verbs in a complex verb cluster; (ii) sentences with four nested dependencies distributed across two embedded clauses, one center-embedded within the other, each containing a two-verb cluster. The results show that sentences with four nested dependencies are judged as acceptable as control sentences with only two nested dependencies, whereas sentences with three nested dependencies are judged as only marginally acceptable. This argues against De Vries et al.'s (2011) claim that the human parser can process no more than two nested dependencies. The results are used to refine the Verb-Cluster Complexity Hypothesis of Bader and Schmid (2009a). The second and the third experiment investigate sentences with four nested dependencies in more detail in order to explore alternative sources of sentence complexity: the number of predicted heads to be held in working memory (storage cost in terms of the Dependency Locality Theory [DLT], Gibson, 2000) and the length of the involved dependencies (integration cost in terms of the DLT). Experiment 2 investigates sentences for which storage cost and integration cost make conflicting predictions. The results show that storage cost outweighs integration cost. Experiment 3 shows that increasing integration cost in sentences with two degrees of center embedding leads to decreased acceptability. Taken together, the results argue in favor of a multifactorial account of the limitations on center embedding in natural languages. PMID:29410633
Bader, Markus
2017-01-01
This paper presents three acceptability experiments investigating German verb-final clauses in order to explore possible sources of sentence complexity during human parsing. The point of departure was De Vries et al.'s (2011) generalization that sentences with three or more crossed or nested dependencies are too complex for being processed by the human parsing mechanism without difficulties. This generalization is partially based on findings from Bach et al. (1986) concerning the acceptability of complex verb clusters in German and Dutch. The first experiment tests this generalization by comparing two sentence types: (i) sentences with three nested dependencies within a single clause that contains three verbs in a complex verb cluster; (ii) sentences with four nested dependencies distributed across two embedded clauses, one center-embedded within the other, each containing a two-verb cluster. The results show that sentences with four nested dependencies are judged as acceptable as control sentences with only two nested dependencies, whereas sentences with three nested dependencies are judged as only marginally acceptable. This argues against De Vries et al.'s (2011) claim that the human parser can process no more than two nested dependencies. The results are used to refine the Verb-Cluster Complexity Hypothesis of Bader and Schmid (2009a). The second and the third experiment investigate sentences with four nested dependencies in more detail in order to explore alternative sources of sentence complexity: the number of predicted heads to be held in working memory (storage cost in terms of the Dependency Locality Theory [DLT], Gibson, 2000) and the length of the involved dependencies (integration cost in terms of the DLT). Experiment 2 investigates sentences for which storage cost and integration cost make conflicting predictions. The results show that storage cost outweighs integration cost. Experiment 3 shows that increasing integration cost in sentences with two degrees of center embedding leads to decreased acceptability. Taken together, the results argue in favor of a multifactorial account of the limitations on center embedding in natural languages.
NASA Astrophysics Data System (ADS)
Hippe, Kristina; Lupker, Maarten; Gordijn, Tiemen; Ivy-Ochs, Susan; Kober, Florian; Christl, Marcus; Wacker, Lukas; Hajdas, Irka; Wieler, Rainer
2017-04-01
Sediment storage is a critical component of fluvial sedimentary systems. By interrupting transport processes, intermittent sediment storage can effectively decouple source from sink and buffer the transmission of signals of environmental change (e.g., in climate, vegetation, human impact) through the fluvial system. Combined in situ cosmogenic 14C-10Be analysis in fluvial sediment provides a unique method to simultaneously assess sediment transit times (in situ 14C signal) and long-term sediment production rates from bedrock erosion (10Be signal). The key is the much shorter half-life of in situ 14C compared to 10Be which causes a rapid decrease of the in situ 14C concentration when sediment is buried during sediment storage and creates an offset to 10Be. Here, we use the in situ 14C-10Be chronometer to determine changes in surface erosion and estimate absolute rates of sediment transfer in a catchment on the Bolivian Altiplano. Previous research in the study area has found a significant offset in the in situ 14C-10Be inventories from river sediments with much lower in situ 14C concentrations than expected from the 10Be content for steady-state conditions. This offset has been interpreted to reflect sediment storage over the past 11-20 ka [1]. Additional analyses of in situ 14C and 10Be in a dense network of sediment samples from the main channel and tributaries agree with previous data and yield very low in situ 14C concentrations that suggest an increase in storage duration by a few ka with downstream distance. However, analyses of in situ 14C-10Be in hilltop samples from the eroding source area reveal an almost as large offset as in the river sediments. Such complex in situ 14C-10Be inventories in the source area have a severe impact on the quantification of sediment storage times and strongly challenge previous data interpretation. The most straightforward explanation for the in situ 14C-10Be offset at hilltop locations is a change in denudation rate during the Holocene. Using a simple model of a rapid, one-step denudation rate change, a minimum increase by a factor of 30-40 at about 4-6 ka ago is required to approach the measured in situ 14C-10Be concentrations. This corresponds to the Mid-Holocene shift towards wetter climate in the Eastern Andes as proposed from paleolake deposits [2]. Assuming that fluvial sediments inherit a complex 10Be-14C signal from the source area, the estimated duration of total sediment storage reduces to 1-5 ka and is, thus, much shorter than previously assumed. These time spans correlate well with ages of 2-3 ka obtained for fluvial terraces in the study area by radiocarbon and 10Be depth profile dating. Our data allows tracing the spatial pattern of sediment storage and quantify individual storage durations during source-to-sink sediment transfer through the catchment. We further highlight the potential of the in situ 14C-10Be chronometer to determine the magnitude and timing of changes in surface erosion in the past and, thus, to identify transience in eroding landscapes. [1] Hippe et al., 2012 - Geomorphology 179 - pp. 58-70. [2] Rigsby et al., 2005 - J Quaternary Sci 20 - pp. 671-691.
Slow Orbit Feedback at the ALS Using Matlab
DOE Office of Scientific and Technical Information (OSTI.GOV)
Portmann, G.
1999-03-25
The third generation Advanced Light Source (ALS) produces extremely bright and finely focused photon beams using undulatory, wigglers, and bend magnets. In order to position the photon beams accurately, a slow global orbit feedback system has been developed. The dominant causes of orbit motion at the ALS are temperature variation and insertion device motion. This type of motion can be removed using slow global orbit feedback with a data rate of a few Hertz. The remaining orbit motion in the ALS is only 1-3 micron rms. Slow orbit feedback does not require high computational throughput. At the ALS, the globalmore » orbit feedback algorithm, based on the singular valued decomposition method, is coded in MATLAB and runs on a control room workstation. Using the MATLAB environment to develop, test, and run the storage ring control algorithms has proven to be a fast and efficient way to operate the ALS.« less
Cosmogenic nuclide budgeting of floodplain sediment transfer
NASA Astrophysics Data System (ADS)
Wittmann, H.; von Blanckenburg, F.
2009-08-01
Cosmogenic nuclides produced in quartz may either decay or accumulate while sediment is moved through a river basin. A change in nuclide concentration resulting from storage in a floodplain is potentially important in large drainage basins in which sediment is prone to repeated burial and remobilization as a river migrates through its floodplain. We have modeled depth- and time-dependent cosmogenic nuclide concentration changes for 10Be, 26Al, and 14C during sediment storage and mixing in various active floodplain settings ranging from confined, shallow rivers with small floodplains to foreland-basin scale floodplains traversed by deep rivers. Floodplain storage time, estimated from channel migration rates, ranges from 0.4 kyr for the Beni River basin (Bolivia) to 7 kyr for the Amazon River basin, while floodplain storage depth, estimated from channel depth, ranges from 1 to 25 m. For all modeled active floodplain settings, the long-lived nuclides 10Be and 26Al show neither significant increase in nuclide concentration from irradiation nor decrease from decay. We predict a hypothetical response time after which changes in 10Be or 26Al concentrations become analytically resolvable. This interval ranges from 0.07 to 2 Myr and exceeds in all cases the typical residence time of sediment in a floodplain. Due to the much shorter half life of 14C, nuclide concentrations modeled for the in situ-produced variety of this nuclide are, however, sensitive to floodplain storage on residence times of < 20 kyr. The cosmogenic nuclide composition of old deposits in currently inactive floodplains that have been isolated for periods of millions of years from the river that once deposited them is predicted to either increase or decrease in 10Be and 26Al concentration, depending on the depositional depth. These conditions can be evaluated using the 26Al/ 10Be ratio that readily discloses the depth and duration of storage. We illustrate these models with examples from the Amazon basin. As predicted, modern bedload collected from an Amazon tributary, the Bolivian Beni River, shows no systematic change in nuclide concentration as sediment is moved through 500 km of floodplain by river meandering. In contrast, in the central Amazon floodplain currently untouched by the modern river system, low 26Al/ 10Be ratios account for minimum burial depths of 5 to 10 m for a duration of > 5 Myr. The important result of this analysis is that in all likely cases of active floodplains, cosmogenic 10Be and 26Al concentrations remain virtually unchanged over the interval sediment usually spends in the basin. Thus, spatially-averaged denudation rates of the sediment-producing area can be inferred throughout the entire basin, provided that nuclide production rates are scaled for the altitudes of the sediment-producing area only, because floodplain storage does not modify nuclide concentrations introduced from the sediment source area.
Quantifying Preferential Flow and Seasonal Storage in an Unsaturated Fracture-Facial Domain
NASA Astrophysics Data System (ADS)
Nimmo, J. R.; Malek-Mohammadi, S.
2012-12-01
Preferential flow through deep unsaturated zones of fractured rock is hydrologically important to a variety of contaminant transport and water-resource issues. The unsaturated zone of the English Chalk Aquifer provides an important opportunity for a case study of unsaturated preferential flow in isolation from other flow modes. The chalk matrix has low hydraulic conductivity and stays saturated, owing to its fine uniform pores and the wet climate of the region. Therefore the substantial fluxes observed in the unsaturated chalk must be within fractures and interact minimally with matrix material. Price et al. [2000] showed that irregularities on fracture surfaces provide a significant storage capacity in the chalk unsaturated zone, likely accounting for volumes of water required to explain unexpected dry-season water-table stability during substantial continuing streamflow observed by Lewis et al. [1993] In this presentation we discuss and quantify the dynamics of replenishment and drainage of this unsaturated zone fracture-face storage domain using a modification of the source-responsive model of Nimmo [2010]. This model explains the processes in terms of two interacting flow regimes: a film or rivulet preferential flow regime on rough fracture faces, active on an individual-storm timescale, and a regime of adsorptive and surface-tension influences, resembling traditional diffuse formulations of unsaturated flow, effective mainly on a seasonal timescale. The modified model identifies hydraulic parameters for an unsaturated fracture-facial domain lining the fractures. Besides helping to quantify the unsaturated zone storage described by Price et al., these results highlight the importance of research on the topic of unsaturated-flow relations within a near-fracture-surface domain. This model can also facilitate understanding of mechanisms for reinitiation of preferential flow after temporary cessation, which is important in multi-year preferential flow through deep unsaturated zones [Pruess, 1999]. Lewis, M.A., H.K. Jones, D.M.J. Macdonald, M. Price, J.A. Barker, T.R. Shearer, A.J. Wesselink, and D.J. Evans (1993), Groundwater storage in British aquifers--Chalk, National Rivers Authority R&D Note, 169, Bristol, UK. Nimmo, J.R. (2010), Theory for Source-Responsive and Free-Surface Film Modeling of Unsaturated Flow, Vadose Zone Journal, 9(2), 295-306, doi:10.2136/vzj2009.0085. Price, M., R.G. Low, and C. McCann (2000), Mechanisms of water storage and flow in the unsaturated zone of the Chalk aquifer, Journal of Hydrology, 233(1-4), 54-71. Pruess, K. (1999), A mechanistic model for water seepage through thick unsaturated zones in fractured rocks of low matrix permeability, Water Resources Research, 35(4), 1039-1051.
Advanced light source master oscillator
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lo, C.C.; Taylor, B.; Baptiste, K.
1989-03-01
The Master Oscillator of the Advanced Light Source operates at a frequency of 499.654 MHz which is the 328th harmonic of the storage ring. The oscillator is capable of providing up to a maximum of {plus minus} 500 KHz frequency deviation for various experimental purposes. Provisions for external signal injection as well as using an external signal source have been designed into the unit. A power distribution system has also been included to provide signals for various parts of the ALS machine and user requirements. The Master Oscillator is made up with modules housed in a Euro chassis. 4 refs.,more » 7 figs.« less
NASA Astrophysics Data System (ADS)
Lu, Xinhua; Mao, Bing; Dong, Bingjiang
2018-01-01
Xia et al. (2017) proposed a novel, fully implicit method for the discretization of the bed friction terms for solving the shallow-water equations. The friction terms contain h-7/3 (h denotes water depth), which may be extremely large, introducing machine error when h approaches zero. To address this problem, Xia et al. (2017) introduces auxiliary variables (their equations (37) and (38)) so that h-4/3 rather than h-7/3 is calculated and solves a transformed equation (their equation (39)). The introduced auxiliary variables require extra storage. We implemented an analysis on the magnitude of the friction terms to find that these terms on the whole do not exceed the machine floating-point number precision, and thus we proposed a simple-to-implement technique by splitting h-7/3 into different parts of the friction terms to avoid introducing machine error. This technique does not need extra storage or to solve a transformed equation and thus is more efficient for simulations. We also showed that the surface reconstruction method proposed by Xia et al. (2017) may lead to predictions with spurious wiggles because the reconstructed Riemann states may misrepresent the water gravitational effect.
NASA Astrophysics Data System (ADS)
Milliner, C. W. D.; Materna, K.; Burgmann, R.; Fu, Y.; Bekaert, D. P.; Moore, A. W.; Adhikari, S.
2017-12-01
The Global Positioning System (GPS) measures elastic ground motions due to variations in terrestrial water mass. Such measurements have been used to successfully study variations of hydrological loading over monthly-to-yearly timescales; e.g., seasonal changes in water storage in California (Argus et al., 2014), 3-year drought of Western US (Borsa et al., 2014) and monthly water storage change in the Pacific Northwest (Fu et al., 2015). However, inferring water storage variations from single loading events over daily-to-weekly timescales presents a major challenge, due to the relatively higher level of noise and systematic errors, such as common mode errors (CME). This makes geodetic investigations of transient hydrologic events, such as major hurricanes, particularly difficult. By using daily vertical GPS timeseries we resolve the spatial and temporal evolution of water loading from Hurricane Harvey across the Gulf coast by applying multiple network correction methods, which helps to isolate the hydrological loading signal. Using 340 GPS stations distributed across the southern US, we mitigate for the effects of spatially correlated CME by firstly removing vertical contributions from atmospheric and non-ocean tidal loading, and secondly correcting the residual positions for changes in translation, rotation and scaling using a Helmert transformation. Our results show a maximum subsidence of 1.8 cm occurring around Houston, and a clear migration of land subsidence from Corpus Christi to western Louisiana over a 7-day period, consistent with the movement of Harvey itself. We also present preliminary results using the Network Inversion Filter (Bekaert et al., 2016), in which we use a Kalman filter approach to describe the time-varying water mass in a stochastic sense. Although our results are preliminary, we find removal of systematic sources of noise can help reveal hydrological loading signals due to extreme, transient events, that would typically go missed by other spatially and temporally coarser methods (e.g., GRACE), providing valuable constraints on large and sudden changes to the hydrosphere.
High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides
DOE Office of Scientific and Technical Information (OSTI.GOV)
Daniel A. Mosher; Xia Tang; Ronald J. Brown
2007-07-27
This final report describes the motivations, activities and results of the hydrogen storage independent project "High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides" performed by the United Technologies Research Center under the Department of Energy Hydrogen Program, contract # DE-FC36-02AL67610. The objectives of the project were to identify and address the key systems technologies associated with applying complex hydride materials, particularly ones which differ from those for conventional metal hydride based storage. This involved the design, fabrication and testing of two prototype systems based on the hydrogen storage material NaAlH4. Safety testing, catalysis studies, heat exchangermore » optimization, reaction kinetics modeling, thermochemical finite element analysis, powder densification development and material neutralization were elements included in the effort.« less
Diagnostic Systems Plan for the Advanced Light Source Top-OffUpgrade
DOE Office of Scientific and Technical Information (OSTI.GOV)
Barry, Walter; Chin, Mike; Robin, David
2005-05-10
The Advanced Light Source (ALS) will soon be upgraded to enable top-off operations [1], in which electrons are quasi-continuously injected to produce constant stored beam current. The upgrade is structured in two phases. First, we will upgrade our injector from 1.5 GeV to 1.9 GeV to allow full energy injection and will start top-off operations. In the second phase, we will upgrade the Booster Ring (BR) with a bunch cleaning system to allow high bunch purity top-off injection. A diagnostics upgrade will be crucial for success in both phases of the top-off project, and our plan for it is describedmore » in this paper. New booster ring diagnostics will include updated beam position monitor (BPM) electronics, a tune monitoring system, and a new scraper. Two new synchrotron light monitors and a beam stop will be added to the booster-to-storage ring transfer line (BTS), and all the existing beam current monitors along the accelerator chain will be integrated into a single injection efficiency monitoring application. A dedicated bunch purity monitor will be installed in the storage ring (SR). Together, these diagnostic upgrades will enable smooth commissioning of the full energy injector and a quick transition to high quality top-off operation at the ALS.« less
Physical properties of ZrC/Al2O3 imbedded heat storage woven fabrics
NASA Astrophysics Data System (ADS)
Kim, S. J.; Song, M. K.; Seo, K. O.; Kim, H. A.
2017-10-01
This study investigated different physical properties of ZrC/Al2O3 imbedded heat storage woven fabrics. ZrC and Al2O3 imbedded heat storage PET filaments were spun on the pilot spinning equipment, respectively. Various physical properties of ceramic imbedded fabrics made of ZrC and Al2O3 imbedded filaments were measured and compared with those of the regular PET woven fabric. The surface temperatures of the ZrC and Al2O3 imbedded fabrics were higher than that of the regular fabric. Water absorption rate of ceramic imbedded fabrics was better than that of the regular fabric and drying property was inferior to that of regular fabric. Breathability by water vapour resistance(Ref) of ZrC imbedded fabric was superior to that of regular fabric. Heat keepability rates of the ceramic imbedded fabrics were higher than that of the regular fabrics, which revealed a good heat storage property of the ZrC/Al2O3 imbedded fabrics.
Case study - Dynamic pressure-limited capacity and costs of CO2 storage in the Mount Simon sandstone
Anderson, Steven T.; Jahediesfanjani, Hossein
2017-01-01
Widespread deployment of carbon capture and storage (CCS) is likely necessary to be able to satisfy baseload electricity demand, to maintain diversity in the energy mix, and to achieve climate and other objectives at the lowest cost. If all of the carbon dioxide (CO2) emissions from stationary sources (such as fossil-fuel burning power plants, and other industrial plants) in the United States needed to be captured and stored, it could be possible to store only a small fraction of this CO2 in oil and natural gas reservoirs, including as a result of CO2 utilization for enhanced oil recovery. The vast majority would have to be stored in saline-filled reservoirs (Dahowski et al., 2005). Given a lack of long-term commercial-scale CCS projects, there is considerable uncertainty in the risks, dynamic capacity, and their cost implications for geologic storage of CO2. Pressure buildup in the storage reservoir is expected to be a primary source of risk associated with CO2 storage, and could severely limit CO2 injection rates (dynamic storage capacities). Most cost estimates for commercial-scale deployment of CCS estimate CO2 storage costs under assumed availability of a theoretical capacity to store tens, hundreds, or even thousands of gigatons of CO2, without considering geologic heterogeneities, pressure limitations, or the time dimension. This could lead to underestimation of the costs of CO2 storage (Anderson, 2017). This paper considers the impacts of pressure limitations and geologic heterogeneity on the dynamic CO2 storage capacity and storage (injection) costs. In the U.S. Geological Survey (USGS)’s National Assessment of Geologic CO2 Storage Resources (USGS, 2013), the mean estimate of the theoretical storage capacity in the Mount Simon Sandstone was about 94 billion metric tons of CO2. However, our results suggest that the pressure-limited capacity after 50 years of injection could be only about 4% of the theoretical geologic storage capacity in this formation. Because this is far less than emissions of CO2 from stationary sources in the region around the Mount Simon Sandstone, the costs to accommodate the potential annual demand for CO2 storage in this formation could be significantly greater than current estimates. Our results could have implications for how long and to what extent decision makers can expect to be able to deploy CCS before transitioning to other low- or zero-carbon energy technologies.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Luo, Yiqi
The project was conducted during the period from 7/1/2012 to 6/30/2017 with three major tasks: (1) data synthesis and development of data assimilation (DA) techniques to constrain modeled ecosystem feedback to climate change; (2) applications of DA techniques to improve process models at different scales from ecosystem to regions and the globe; and 3) improvements of modeling soil carbon (C) dynamics by land surface models. During this period, we have synthesized published data from soil incubation experiments (e.g., Chen et al., 2016; Xu et al., 2016; Feng et al., 2016), global change experiments (e.g., Li et al., 2013; Shi etmore » al., 2015, 2016; Liang et al., 2016) and fluxnet (e.g., Niu et al., 2012., Xia et al., 2015; Li et al., 2016). These data have been organized into multiple data products and have been used to identify general mechanisms and estimate parameters for model improvement. We used the data sets that we collected and the DA techniques to improve model performance of both ecosystem models and global land models. The objectives are: 1) to improve model simulations of litter and soil carbon storage (e.g., Schädel et al., 2013; Hararuk and Luo, 2014; Hararuk et al., 2014; Liang et al., 2015); 2) to explore the effects of CO 2, warming and precipitation on ecosystem processes (e.g., van Groenigen et al., 2014; Shi et al., 2015, 2016; Feng et al., 2017); and 3) to estimate parameters variability in different ecosystems (e.g., Li et al., 2016). We developed a traceability framework, which was based on matrix approaches and decomposed the modeled steady-state terrestrial ecosystem carbon storage capacity into four can trace the difference in ecosystem carbon storage capacity among different biomes to four traceable components: net primary productivity (NPP), baseline C residence times, environmental scalars and climate forcing (Xia et al., 2013). With this framework, we can diagnose the differences in modeled carbon storage across ecosystems, biomes, and models. This framework has been successfully implemented by several global land models, such as CABLE (Xia et al., 2013), LPJ-GUESS (Ahlström et al., 2015), CLM (Hararuk et al., 2014; Huang et al., 2017, submitted; Shi et al., 2017, submitted), and ORCHIDEE (Huang et al., 2017, unpublished). Moreover, we have identified the theoretical foundation of the determinants of transient C storage dynamics by adding another term, C storage potential, to the steady-state traceability framework (Luo et al., 2017). The theoretical foundation of transient C storage dynamics has been applied to develop a transient traceability framework to explore the traceable components of transient C storage dynamics responded to the rising CO 2 and climate change in the two contrasting ecosystem types Duke needleleaved forest and Harvard deciduous broadleaved forest (Jiang et al., 2017, in revision). Overall, with the data synthesis, data assimilation techniques, and the steady-state and transient traceability frameworks, we have greatly improved land process models for predicting responses and feedback of terrestrial C dynamics to global change. The matrix approaches has the potential to be applied in theoretical research on nitrogen and phosphorus cycle, and therefore, the coupling of carbon-nitrogen-phosphorus.« less
Storing hydrogen in the form of light alloy hydrides
NASA Technical Reports Server (NTRS)
Freund, E.; Gillerm, C.
1981-01-01
Different hydrides are investigated to find a system with a sufficiently high storage density (at least 3%). The formation of hydrides with light alloys is examined. Reaction kinetics for hydride formation were defined and applied to the systems Mg-Al-H, Mg-Al-Cu-H, Ti-Al-H, Ti-Al-Cu-H, and Ti-Al-Ni-H. Results indicate that the addition of Al destabilizes MgH2 and TiH2 hydrides while having only a limited effect on the storage density.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Levitas, Valery I.; McCollum, Jena; Pantoya, Michelle L.
Stress relaxation in aluminum micron-scale particles covered by alumina shell after pre-stressing by thermal treatment and storage was measured using X-ray diffraction with synchrotron radiation. Pre-stressing was produced by annealing Al particles at 573K followed by fast cooling. While averaged dilatational strain in Al core was negligible for untreated particles, it was measured at 4.40×10 -5 and 2.85×10 -5 after 2 and 48 days of storage. Consistently, such a treatment leads to increase in flame propagation speed for Al+CuO mixture by 37% and 25%, respectively. Analytical model for creep in alumna shell and stress relaxation in Al core-alumina shellmore » structure is developed and activation energy and pre-exponential multiplier are estimated. The effect of storage temperature and annealing temperature on the kinetics of stress relaxation was evaluated theoretically. These results provide estimates for optimizing Al reactivity with the holding time at annealing temperature and allowable time for storage of Al particles for various environmental temperatures.« less
Levitas, Valery I.; McCollum, Jena; Pantoya, Michelle L.; ...
2016-05-30
Stress relaxation in aluminum micron-scale particles covered by alumina shell after pre-stressing by thermal treatment and storage was measured using X-ray diffraction with synchrotron radiation. Pre-stressing was produced by annealing Al particles at 573K followed by fast cooling. While averaged dilatational strain in Al core was negligible for untreated particles, it was measured at 4.40×10 -5 and 2.85×10 -5 after 2 and 48 days of storage. Consistently, such a treatment leads to increase in flame propagation speed for Al+CuO mixture by 37% and 25%, respectively. Analytical model for creep in alumna shell and stress relaxation in Al core-alumina shellmore » structure is developed and activation energy and pre-exponential multiplier are estimated. The effect of storage temperature and annealing temperature on the kinetics of stress relaxation was evaluated theoretically. These results provide estimates for optimizing Al reactivity with the holding time at annealing temperature and allowable time for storage of Al particles for various environmental temperatures.« less
Solid Aluminum Borohydrides for Prospective Hydrogen Storage.
Dovgaliuk, Iurii; Safin, Damir A; Tumanov, Nikolay A; Morelle, Fabrice; Moulai, Adel; Černý, Radovan; Łodziana, Zbigniew; Devillers, Michel; Filinchuk, Yaroslav
2017-12-08
Metal borohydrides are intensively researched as high-capacity hydrogen storage materials. Aluminum is a cheap, light, and abundant element and Al 3+ can serve as a template for reversible dehydrogenation. However, Al(BH 4 ) 3 , containing 16.9 wt % of hydrogen, has a low boiling point, is explosive on air and has poor storage stability. A new family of mixed-cation borohydrides M[Al(BH 4 ) 4 ], which are all solid under ambient conditions, show diverse thermal decomposition behaviors: Al(BH 4 ) 3 is released for M=Li + or Na + , whereas heavier derivatives evolve hydrogen and diborane. NH 4 [Al(BH 4 ) 4 ], containing both protic and hydridic hydrogen, has the lowest decomposition temperature of 35 °C and yields Al(BH 4 ) 3 ⋅NHBH and hydrogen. The decomposition temperatures, correlated with the cations' ionic potential, show that M[Al(BH 4 ) 4 ] species are in the most practical stability window. This family of solids, with convenient and versatile properties, puts aluminum borohydride chemistry in the mainstream of hydrogen storage research, for example, for the development of reactive hydride composites with increased hydrogen content. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
New chemical sources of energy: A theoretical study
NASA Astrophysics Data System (ADS)
Chaban, Galina
The research presented in this dissertation employs methods of quantum chemistry for the search of highly energetic chemical compounds that can have applications as possible energy sources. The areas of research include: (1) improvement of orbital optimization methods for different types of wavefunctions which leads to substantial savings of computer time and memory; (2) predicting new high energy isomers for singlet and triplet states of Nsb3F and their kinetic stability with respect to isomerisation and dissociation reactions; (3) estimation of minimum energy reaction paths for dissociation reactions of high energy isomers of Nsb2Osb2 including potential energy barriers and minimum energy crossing points between the closest singlet and triplet states; (4) investigation of thermodynamic and kinetic stability of Van der Waals complexes M-Hsb2 (M = Li, Be, B, C, Na, Mg, Al, Si) that can play an important role in improvement of energetic properties of hydrogen based rocket fuels; (5) mapping of the potential energy surface for AlHsb2 compound in the region of crossing between sp2Bsb2 and sp2Asb1 electronic states and predicting the kinetic stability of Al complex, which suggests that Al may be among the promising candidates for inclusion into solid hydrogen for the purpose of energy storage.
2015-01-01
The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum-based metal–organic frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized: namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOF platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm3 (STP)/cm3 (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOF pore structure and functionality to the gas storage properties, to better understand the structure–property relationship, we performed a molecular simulation study and evaluated the methane storage performance of the Al-soc-MOF platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOF-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOF-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes under a wide range of pressure and temperature conditions. PMID:26364990
Alezi, Dalal; Belmabkhout, Youssef; Suyetin, Mikhail; Bhatt, Prashant M; Weseliński, Łukasz J; Solovyeva, Vera; Adil, Karim; Spanopoulos, Ioannis; Trikalitis, Pantelis N; Emwas, Abdul-Hamid; Eddaoudi, Mohamed
2015-10-21
The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum-based metal-organic frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized: namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOF platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm(3) (STP)/cm(3) (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOF pore structure and functionality to the gas storage properties, to better understand the structure-property relationship, we performed a molecular simulation study and evaluated the methane storage performance of the Al-soc-MOF platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOF-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOF-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes under a wide range of pressure and temperature conditions.
NASA Astrophysics Data System (ADS)
AlAnezi, Ghunaim; Kasahara, Junzo; AlDamegh, Khaled S.; Lafouza, Omar; AlYousef, Khaled; Almalki, Fahad; Nishiyama, Eichiro
2015-04-01
We have developed the time lapse technology for EOR (enhanced oil recovery) and CCS (Carbon Capture and Storage) using a very stable and continuous seismic source called ACROSS (Accurately Controlled Routinely Operated Signal System) with multi-geophones. Since 2011, we have tested this technology in the context of carbonate rocks in Saudi Arabia. The Al Wasee water pumping site approximately 120 km east of Riyadh city has been selected as a trail-site. The intention is to observe the changes in aquifers induced by pumping operations. One ACROSS source unit was installed at the Al Wasee site in December 2011 and we are continuing the field test. The instrument has been operated from 10 to 50 Hz with 40 tons-f at 50 Hz. Using alternatively clockwise and counter-clockwise rotations we can synthesize vertical and horizontal forces, respectively. 31 3C-geophones in 2 km x 3 km area and four nearby 3Cgeophones have been used to monitor the seismic changes from pumping the water. The one and half month data between December 2012 and February 2013 show continuous and clear change of observed waveforms for all 31 stations while the source signature did not change. The change is closest and fastest at the station #42. The cause of continuous change with time is interpreted as pumping of water by 64 wells located in this field.
NASA Astrophysics Data System (ADS)
Hugelius, G.; Ahlström, A.; Loisel, J.; Harden, J. W.
2017-12-01
Soils provide numerous and indispensable services to ecological systems and human societies. As human populations and human land use changes, the capacity of soils to maintain these services may also change. To investigate this we provide the first global scale study based on the soil service index (SSI; see presentations by Harden et al. and Loisel et al. in this session for more details). In this index multiple soil services are numerically or quantitatively assessed, normalized to a unit-less scale for purposes of intercomparability. Soil services assessed under the SSI include organic matter and/or organic carbon storage; plant productivity; CO2 or GHG exchange with the atmosphere; water storage capacity; and nutrient storage and/or availability. The SSI may be applied at any scale. Here we present a first global application of the SSI and provide broad-scale analyses of soil service spatial distributions. We assess how the SSI will change under projected changes in human societies populations and human land use (following representative concentration pathway scenarios). Present and future potential utilization and vulnerability of soil resources are analyzed in the context of human population distributions and its projected changes. The SSI is designed to be broadly useful across scientific, governance and resource management organizations. To exemplify this, the parameterization of this is global soil service estimate is based on only open source input data.
Why do magmas stall? Insights from petrologic and geodetic data
NASA Astrophysics Data System (ADS)
Zimmer, M. M.; Plank, T.; Freymueller, J.; Hauri, E. H.; Larsen, J. F.; Nye, C. J.
2007-12-01
Magmas stall at various depths in the crust due to their internal properties (magma viscosity, buoyancy) and external crustal controls (local stress regime, wallrock strength). Annen et al. (JPet 2006) propose a petrological model in which buoyant magma ascends through the crust until the depth of water saturation, after which it crystallizes catastrophically and stalls due to the large increase in magma viscosity. Magmas may erupt from this storage region, or viscous death may result in pluton formation. In order to test this model, and constrain magma storage depths, we combine petrological and geodetic data for several active volcanoes along the Aleutian-Alaska arc. We analyzed glassy, primarily olivine-hosted melt inclusions by SIMS in tephra samples for their pre-eruptive volatile contents, which can be related to the depth of entrapment via pressure-dependent H2O-CO2 solubility models (e.g., VolatileCalc). Melt inclusions are not in equilibrium with pure water vapor (all will contain S and C species), but >50% of the inclusion population are in equilibrium with a vapor containing >85% H2O. Geodetic data (InSAR, GPS) record surface deformation related to volcano inflation/deflation, and can be inverted to solve for the depths of volume change (magma storage) in the crust. In the Aleutians, we find that the maximum melt inclusion trapping depths and geodetic depths correlate, suggesting both techniques record crustal magma storage and crystallization. Melt inclusions from the 1997 Okmok eruption are trapped at ≤3 km; deformation during the eruption and subsequent inflation occurred at 3±0.5 km (Miyagi et al., EPSL 2004; Lu & Masterlark, JGR 2005). At Akutan, melt inclusions and GPS data indicate magma storage at ~5-7 km. Inclusions from flank cones of Makushin yield depths of 7 km, similar to inflation observed beneath the main edifice (6.8 km, Lu et al., JGR 2002). Pleistocene inclusions from Augustine volcano indicate magma storage at 10-18 km, in accord with a deep magma source proposed for the 2006 eruption. Melt inclusions from Shishaldin are trapped at depths up to 4 km, coincident with the base of the conduit (Vergnoille & Caplan Auerbach, BVolc 2006). Other volcanoes record similar depths of melt inclusion entrapment and deformation, including Mt. St. Helens, Irazú, Soufriere Hills, Vesuvius, and Etna. Clearly, crystallization will occur where magmas stall, cool, and degas, so it may not be surprising that the depths of deformation correlate with the depths of melt inclusion entrapment. But the question of why magmas stall at various depths remains. In the Aleutians, maximum H2O contents of melt inclusions (from 2 wt% at Shishaldin to 7 wt% at Augustine) negatively correlate with measures of the degree of mantle melting (Ti6.0 and Y6.0), which is expected if water drives mantle melting beneath arcs (e.g. Kelley et al. JGR 2006; Portnyagin et al EPSL 2007). Thus, if magmas stall near the depths where they reach H2O-saturation, as predicted by Annen et al. and observed here, then magma chamber and pluton depths may ultimately be controlled by the primary magmatic water contents set in the mantle.
Entropy, pricing and productivity of pumped-storage
NASA Astrophysics Data System (ADS)
Karakatsanis, Georgios; Tyralis, Hristos; Tzouka, Katerina
2016-04-01
Pumped-storage constitutes today a mature method of bulk electricity storage in the form of hydropower. This bulk electricity storability upgrades the economic value of hydropower as it may mitigate -or even neutralize- stochastic effects deriving from various geophysical and socioeconomic factors, which produce numerous load balance inefficiencies due to increased uncertainty. Pumped-storage further holds a key role for unifying intermittent renewable (i.e. wind, solar) units with controllable non-renewable (i.e. nuclear, coal) fuel electricity generation plants into integrated energy systems. We develop a set of indicators for the measurement of performance of pumped-storage, in terms of the latter's energy and financial contribution to the energy system. More specifically, we use the concept of entropy in order to examine: (1) the statistical features -and correlations- of the energy system's intermittent components and (2) the statistical features of electricity demand prediction deviations. In this way, the macroeconomics of pumped-storage emerges naturally from its statistical features (Karakatsanis et al. 2014). In addition, these findings are combined to actual daily loads. Hence, not only the amount of energy harvested from the pumped-storage component is expected to be important, but the harvesting time as well, as the intraday price of electricity varies significantly. Additionally, the structure of the pumped-storage market proves to be a significant factor as well for the system's energy and financial performance (Paine et al. 2014). According to the above, we aim at postulating a set of general rules on the productivity of pumped-storage for (integrated) energy systems. Keywords: pumped-storage, storability, economic value of hydropower, stochastic effects, uncertainty, energy systems, entropy, intraday electricity price, productivity References 1. Karakatsanis, Georgios et al. (2014), Entropy, pricing and macroeconomics of pumped-storage systems, Vienna, Austria, April 27 - May 2 2014, "The Face of the Earth - Process and Form", European Geophysical Union General Assembly 2. Paine, Nathan et al. (2014), Why market rules matter: Optimizing pumped hydroelectric storage when compensation rules differ, Energy Economics 46, 10-19
A closed-loop photon beam control study for the Advanced Light Source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Portmann, G.; Bengtsson, J.
1993-05-01
The third generation Advanced Light Source (ALS) will produce extremely bright photon beams using undulators and wigglers. In order to position the photon beams accurate to the micron level, a closed-loop feedback system is being developed. Using photon position monitors and dipole corrector magnets, a closed-loop system can automatically compensate for modeling uncertainties and exogenous disturbances. The following paper will present a dynamics model for the perturbations of the closed orbit of the electron beam in the ALS storage ring including the vacuum chamber magnetic field penetration effects. Using this reference model, two closed-loop feedback algorithms will be compared --more » a classical PI controller and a two degree-of-freedom approach. The two degree-of-freedom method provides superior disturbance rejection while maintaining the desired performance goals. Both methods will address the need to gain schedule the controller due to the time varying dynamics introduced by changing field strengths when scanning the insertion devices.« less
NASA Astrophysics Data System (ADS)
Francois, Baptiste; Hingray, Benoit; Creutin, Jean-Dominique; Raynaud, Damien; Borga, Marco; Vautard, Robert
2015-04-01
Climate related energy sources like solar-power, wind-power and hydro-power are important contributors to the transitions to a low-carbon economy. Past studies, mainly based on solar and wind powers, showed that the power from such energy sources fluctuates in time and space following their driving climatic variables. However, when combining different energy sources together, their intermittent feature is smoothed, resulting to lower time variability of the produced power and to lower storage capacity required for balancing. In this study, we consider solar, wind and hydro energy sources in a 100% renewable Europe using a set of 12 regions following two climate transects, the first one going from the Northern regions (Norway, Finland) to the Southern ones (Greece, Andalucía, Tunisia) and the second one going from the oceanic climate (West of France, Galicia) to the continental one (Romania, Belorussia). For each of those regions, we combine wind and solar irradiance data from the Weather Research and Forecasting Model (Vautard et al., 2014), temperature data from the European Climate Assessment & Dataset (Haylock et al., 2008) and runoff from the Global Runoff Data Center (GRDC, 1999) for estimating solar-power, wind-power, run-of-the-river hydro-power and the electricity demand over a time period of 30 years. The use of this set of 12 regions across Europe allows integrating knowledge about time and space variability for each different energy sources. We then assess the optimal share of each energy sources, aiming to decrease the time variability of the regional energy balance at different time scales as well as the energy storage required for balancing within each region. We also evaluate how energy transport among regions contributes for smoothing out both the energy balance and the storage requirement. The strengths of this study are i) to handle with run-of-the-river hydro power in addition to wind and solar energy sources and ii) to carry out this analysis over a long time period while past studies, to our knowledge, have used less than 10 year time period. References: Vautard, R., Thais, F., Tobin, I., Bréon, F.-M., de Lavergne, J.-G.D., Colette, A., Yiou, P., and Ruti, P.M. (2014). Regional climate model simulations indicate limited climatic impacts by operational and planned European wind farms. Nat. Commun. 5, 3196. Haylock, M.R., Hofstra, N., Tank, A.M.G.K., Klok, E.J., Jones, P.D., New, M., 2008. A European daily high-resolution gridded data set of surface temperature and precipitation for 1950-2006. J. Geophys. Res.-Atmos. 113. doi:10.1029/2008JD010201 GRDC (Global Runoff Data Center), 1999. Long-term mean monthly discharges of selected GRDC stations, Global Runoff Data Centre, Koblenz, Germany.
Mathematical models as tools for probing long-term safety of CO2 storage
DOE Office of Scientific and Technical Information (OSTI.GOV)
Pruess, Karsten; Birkholzer, Jens; Zhou, Quanlin
Subsurface reservoirs being considered for storing CO{sub 2} include saline aquifers, oil and gas reservoirs, and unmineable coal seams (Baines and Worden, 2004; IPCC, 2005). By far the greatest storage capacity is in saline aquifers (Dooley et al., 2004), and our discussion will focus primarily on CO{sub 2} storage in saline formations. Most issues for safety and security of CO{sub 2} storage arise from the fact that, at typical temperature and pressure conditions encountered in terrestrial crust, CO{sub 2} is less dense than aqueous fluids. Accordingly, CO{sub 2} will experience an upward buoyancy force in most subsurface environments, and willmore » tend to migrate upwards whenever (sub-)vertical permeable pathways are available, such as fracture zones, faults, or improperly abandoned wells (Bachu, 2008; Pruess, 2008a, b; Tsang et al., 2008). CO{sub 2} injection will increase fluid pressures in the target formation, thereby altering effective stress distributions, and potentially triggering movement along fractures and faults that could increase their permeability and reduce the effectiveness of a caprock in containing CO{sub 2} (Rutqvist et al., 2008; Chiaramonte et al., 2008). Induced seismicity as a consequence of fluid injection is also a concern (Healy et al., 1968; Raleigh et al., 1976; Majer et al., 2007). Dissolution of CO{sub 2} in the aqueous phase generates carbonic acid, which may induce chemical corrosion (dissolution) of minerals with associated increase in formation porosity and permeability, and may also mediate sequestration of CO{sub 2} as solid carbonate (Gaus et al., 2008). Chemical dissolution of caprock minerals could promote leakage of CO{sub 2} from a storage reservoir (Gherardi et al., 2007). Chemical dissolution and geomechanical effects could reinforce one another in compromising CO{sub 2} containment. Additional issues arise from the potential of CO{sub 2} to mobilize hazardous chemical species (Kharaka et al., 2006), and from migration of the large amounts of brine that would be mobilized by industrial-scale CO{sub 2} injection (Nicot et al., 2008; Birkholzer et al., 2008a, b).« less
Confined NaAlH4 nanoparticles inside CeO2 hollow nanotubes towards enhanced hydrogen storage.
Gao, Qili; Xia, Guanglin; Yu, Xuebin
2017-10-05
NaAlH 4 has been widely regarded as a potential hydrogen storage material due to its favorable thermodynamics and high energy density. The high activation energy barrier and high dehydrogenation temperature, however, significantly hinder its practical application. In this paper, CeO 2 hollow nanotubes (HNTs) prepared by a simple electrospinning technique are adopted as functional scaffolds to support NaAlH 4 nanoparticles (NPs) towards advanced hydrogen storage performance. The nanoconfined NaAlH 4 inside CeO 2 HNTs, synthesized via the infiltration of molten NaAlH 4 into the CeO 2 HNTs under high hydrogen pressure, exhibited significantly improved dehydrogenation properties compared with both bulk and ball-milled CeO 2 HNTs-catalyzed NaAlH 4 . The onset dehydrogenation temperature of the NaAlH 4 @CeO 2 composite was reduced to below 100 °C, with only one main dehydrogenation peak appearing at 130 °C, which is 120 °C and 50 °C lower than for its bulk counterpart and for the ball-milled CeO 2 HNTs-catalyzed NaAlH 4 , respectively. Moreover, ∼5.09 wt% hydrogen could be released within 30 min at 180 °C, while only 1.6 wt% hydrogen was desorbed from the ball-milled NaAlH 4 under the same conditions. This significant improvement is mainly attributed to the synergistic effects contributed by the CeO 2 HNTs, which could act as not only a structural scaffold to fabricate and confine the NaAlH 4 NPs, but also as an effective catalyst to enhance the hydrogen storage performance of NaAlH 4 .
NASA Astrophysics Data System (ADS)
Kelly, Stephen Thomas
Hydrogen makes an attractive energy carrier for many reasons. It is an abundant chemical fuel that can be produced from a wide variety of sources and stored for very long periods of time. When used in a fuel cell, hydrogen emits only water at the point of use, making it very attractive for mobile applications such as in an automobile. Metal hydrides are promising candidates for on-board reversible hydrogen storage in mobile applications due to their very high volumetric storage capacities---in most cases exceeding even that of liquid hydrogen. The United States Department of Energy (DOE) has set fuel system targets for an automotive hydrogen storage system, but as of yet no single material meets all the requirements. In particular, slow reaction kinetics and/or inappropriate thermodynamics plague many metal hydride hydrogen storage materials. In order to engineer a practical material that meets the DOE targets, we need a detailed understanding of the kinetic and thermodynamic properties of these materials during the phase change. In this work I employed sputter deposited thin films as a platform to study materials with highly controlled chemistry, microstructure and catalyst placement using thin film characterization techniques such as in situ x-ray diffraction (XRD) and neutron reflectivity. I observed kinetic limitations in the destabilized Mg2Si system due to the slow diffusion of the host Mg and Si atoms while forming separate MgH2 and Si phases. Conversely, I observed that the presence of Al in the Mg/Al system inhibits hydrogen diffusion while the host Mg and Al atoms interdiffuse readily, allowing the material to fall into a kinetic and/or thermodynamic trap by forming intermetallic compounds such as Mg17Al 12. By using in situ XRD to analyze epitaxial Mg films grown on (001) oriented Al2O3 substrates I observed hydride growth consistent with a model of a planar hydride layer growing into an existing metal layer. Subsequent film cycling changes the hydrogen absorption and desorption kinetics and degrades the material texture. Cycling the films to greater hydrogen loading accelerates the changes to the kinetics and material texture. In addition to in situ XRD experiments, in situ neutron reflectivity experiments on epitaxial Mg films exposed to hydrogen gas reveal details about the microstructural development of the growing hydride layer as the film absorbs and releases hydrogen. Small (10 wt%) additions of Ti to epitaxial Mg films during growth result in metastable solid solution films of Ti in Mg that deposit epitaxially on (001) Al2O3 substrates with epitaxy similar to the pure Mg films. These metastable alloy films absorb hydrogen faster than pure Mg films under identical conditions. Subsequent film cycling results in altered reaction kinetics and a transition to a different kinetic mechanism during desorption than for pure Mg films.
Reduced electron back-injection in Al2O3/AlOx/Al2O3/graphene charge-trap memory devices
NASA Astrophysics Data System (ADS)
Lee, Sejoon; Song, Emil B.; Min Kim, Sung; Lee, Youngmin; Seo, David H.; Seo, Sunae; Wang, Kang L.
2012-12-01
A graphene charge-trap memory is devised using a single-layer graphene channel with an Al2O3/AlOx/Al2O3 oxide stack, where the ion-bombarded AlOx layer is intentionally added to create an abundance of charge-trap sites. The low dielectric constant of AlOx compared to Al2O3 reduces the potential drop in the control oxide Al2O3 and suppresses the electron back-injection from the gate to the charge-storage layer, allowing the memory window of the device to be further extended. This shows that the usage of a lower dielectric constant in the charge-storage layer compared to that of the control oxide layer improves the memory performance for graphene charge-trap memories.
Zhang, Xin; Liu, Yongfeng; Wang, Ke; Li, You; Gao, Mingxia; Pan, Hongge
2015-12-21
A nanocrystalline CeO2@C-containing NaAlH4 composite is successfully synthesized in situ by hydrogenating a NaH-Al mixture doped with CeO2@C. Compared with NaAlH4 , the as-prepared CeO2@C-containing NaAlH4 composite, with a minor amount of excess Al, exhibits significantly improved hydrogen storage properties. The dehydrogenation onset temperature of the hydrogenated [NaH-Al-7 wt % CeO2@C]-0.04Al sample is 77 °C lower than that of the pristine sample because of a reduced kinetic barrier. More importantly, the dehydrogenated sample absorbs ∼4.7 wt % hydrogen within 35 min at 100°C and 10 MPa of hydrogen. Compositional and structural analyses reveal that CeO2 is converted to CeH2 during ball milling and that the newly formed CeH2 works with the excess of Al to synergistically improve the hydrogen storage properties of NaAlH4. Our findings will aid in the rational design of novel catalyst-doped complex hydride systems with low operating temperatures, fast kinetics, and long-term cyclability. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Computational study of pristine and titanium-doped sodium alanates for hydrogen storage applications
NASA Astrophysics Data System (ADS)
Dathar, Gopi Krishna Phani
The emphasis of this research is to study and elucidate the underlying mechanisms of reversible hydrogen storage in pristine and Ti-doped sodium aluminum hydrides using molecular modeling techniques. An early breakthrough in using complex metal hydrides as hydrogen storage materials is from the research on sodium alanates by Bogdanovic et al., in 1997 reporting reversible hydrogen storage is possible at moderate temperatures and pressures in transition metal doped sodium alanates. Anton reported titanium salts as the best catalysts compared to all other transition metal salts from his further research on transition metal doped sodium alanates. However, a few questions remained unanswered regarding the role of Ti in reversible hydrogen storage of sodium alanates with improved thermodynamics and kinetics of hydrogen desorption. The first question is about the position of transition metal dopants in the sodium aluminum hydride lattice. The position is investigated by identifying the possible sites for titanium dopants in NaAlH4 lattice and studying the structure and dynamics of possible compounds resulting from titanium doping in sodium alanates. The second question is the role of titanium dopants in improved thermodynamics of hydrogen desorption in Ti-doped NaAlH4. Though it is accepted in the literature that formation of TiAl alloys (Ti-Al and TiAl3) is favorable, reaction pathways are not clearly established. Furthermore, the source of aluminum for Ti-Al alloy formation is not clearly understood. The third question in this area is the role of titanium dopants in improved kinetics of hydrogen absorption and desorption in Ti-doped sodium alanates. This study is directed towards addressing the three longstanding questions in this area. Thermodynamic and kinetic pathways for hydrogen desorption in pristine NaAlH4 and formation of Ti-Al alloys in Ti-doped NaAlH 4, are elucidated to understand the underlying mechanisms of hydrogen desorption. Density functional theory formalism as implemented in CASTEP (Cambridge Serial Total Energy Package) is used to study the structure and energetics of pristine and Ti-doped sodium alanates. From investigations of various models of sodium alanates with Ti dopants, it is shown that the difference between the energy required for Ti→SNa (Ti-substituted Na at the lattice site on the surface) and Ti→TI (Ti placed on top of the surface interstitial SI site) is 0.003 eV atom-1, and is minimal compared to other models. Since less energy is required for Ti→S Na and Ti→TI, these two sites (SNa and T I) would be preferred by the Ti dopants. In Ti→SNa model, Ti is coordinated to two aluminum and seven hydrogen atoms resulting in the possible formation of a TiAl2H7 complex. At elevated temperatures (423 and 448 K), the number of aluminum atoms coordinating with titanium in the complex increase from two (at distances in the 2.6-2.7 A range) to five (at distances in the 2.6-2.7 A range). Besides the formation of a Ti-Al-H complex, Al-Al association (with a 2.97 A bond length) is also seen from the DFT-MD results. In the case of Ti→TI, Ti is coordinated to two aluminum and two hydrogen atoms resulting in the possible formation of a TiAl2H2 complex. TiAl2 H2 complex becomes TiAl3H6 and TiAl 3H7 at elevated temperatures of 423 and 448 K, respectively. The investigation of thermodynamics pathways in Ti-doped sodium alanates illustrates a three step reaction pathway to the formation of TiAl3 (Ti and AlH3 after the first reaction, TiAl after the second and finally TiAl3). This investigation also suggests aluminum in its +3 oxidation state present in aluminum hydride species is responsible in the formation of Ti-Al alloys. From kinetics studies, the proposed mechanism is related to transition from AlH4- to AlH6 3-. The rate limiting step is determined to be associated with hydrogen evolution from association of AlH3 species nucleating aluminum phase. This step is 15 kJ/mol higher than the nearest highest barrier in the reaction path related to transition from AlH52- to AlH63-. From the DFT-MD simulations, it is observed that the titanium dopants are present on the surface during the entire simulation time and exhibit the role in catalytic splitting of hydrogen from surrounding AlH4 groups. Besides the catalytic role, Ti dopants also form bonds with Al, and we also see that the AlH4 groups on the surface and that are present in the sub-surface layers are drawn towards the Ti dopants. This association of Al around titanium indicates the initiation of Al nucleation site facilitated by Ti dopants residing on the surface.
NASA Astrophysics Data System (ADS)
Inoue, T.; Yurimoto, H.
2012-12-01
Water is the most important volatile component in the Earth, and affects the physicochemical properties of mantle minerals, e.g. density, elastic property, electrical conductivity, thermal conductivity, rheological property, melting temperature, melt composition, element partitioning, etc. So many high pressure experiments have been conducted so far to determine the effect of water on mantle minerals. To clarify the maximum water storage capacity in nominally anhydrous mantle minerals in the mantle transition zone and lower mantle is an important issue to discuss the possibility of the existence of water reservoir in the Earth mantle. So we have been clarifying the maximum water storage capacity in mantle minerals using MA-8 type (KAWAI-type) high pressure apparatus and SIMS (secondary ion mass spectroscopy). Upper mantle mineral, olivine can contain ~0.9 wt% H2O in the condition just above 410 km discontinuity in maximum (e.g. Chen et al., 2002; Smyth et al., 2006). On the other hand, mantle transition zone mineral, wadsleyite and ringwoodite can contain significant amount (about 2-3 wt.%) of H2O (e.g. Inoue et al., 1995, 1998, 2010; Kawamoto et al., 1996; Ohtani et al., 2000). But the lower mantle mineral, perovskite can not contain significant amount of H2O, less than ~0.1 wt% (e.g. Murakami et al., 2002; Inoue et al., 2010). In addition, garnet and stishovite also can not contain significant amount of H2O (e.g. Katayama et al., 2003; Mookherjee and Karato, 2010; Litasov et al., 2007). On the other hand, the water storage capacities of mantle minerals are supposed to be significantly coupled with Al by a substitution with Mg2+, Si4+ or Mg2+ + Si4+, because Al3+ is the trivalent cation, and H+ is the monovalent cation. To clarify the degree of the substitution, the water contents and the chemical compositions of Al-bearing minerals in the mantle transition zone and the lower mantle were also determined in the Al-bearing systems with H2O. We will introduce the recent results on the maximum water storage capacities in nominally anhydrous minerals in the mantle transition zone and lower mantle from the high pressure experimental point of view.
NASA Astrophysics Data System (ADS)
Rehmer, Donald E.
Analysis of results from a mathematical programming model were examined to 1) determine the least cost options for infrastructure development of geologic storage of CO2 in the Illinois Basin, and 2) perform an analysis of a number of CO2 emission tax and oil price scenarios in order to implement development of the least-cost pipeline networks for distribution of CO2. The model, using mixed integer programming, tested the hypothesis of whether viable EOR sequestration sites can serve as nodal points or hubs to expand the CO2 delivery infrastructure to more distal locations from the emissions sources. This is in contrast to previous model results based on a point-to- point model having direct pipeline segments from each CO2 capture site to each storage sink. There is literature on the spoke and hub problem that relates to airline scheduling as well as maritime shipping. A large-scale ship assignment problem that utilized integer linear programming was run on Excel Solver and described by Mourao et al., (2001). Other literature indicates that aircraft assignment in spoke and hub routes can also be achieved using integer linear programming (Daskin and Panayotopoulos, 1989; Hane et al., 1995). The distribution concept is basically the reverse of the "tree and branch" type (Rothfarb et al., 1970) gathering systems for oil and natural gas that industry has been developing for decades. Model results indicate that the inclusion of hubs as variables in the model yields lower transportation costs for geologic carbon dioxide storage over previous models of point-to-point infrastructure geometries. Tabular results and GIS maps of the selected scenarios illustrate that EOR sites can serve as nodal points or hubs for distribution of CO2 to distal oil field locations as well as deeper saline reservoirs. Revenue amounts and capture percentages both show an improvement over solutions when the hubs are not allowed to come into the solution. Other results indicate that geologic storage of CO2 into saline aquifers does not come into solutions selected by the model until the CO 2 emissions tax approaches 50/tonne. CO2 capture and storage begins to occur when the oil price is above 24.42 a barrel based on the constraints of the model. The annual storage capacity of the basin is nearly maximized when the net price of oil is as low as 40 per barrel and the CO2 emission tax is 60/tonne. The results from every subsequent scenario that was examined by this study demonstrate that EOR utilizing anthropogenically captured CO2 will earn net revenue, and thus represents an economically viable option for CO2 storage in the Illinois Basin.
Mechanic: The MPI/HDF code framework for dynamical astronomy
NASA Astrophysics Data System (ADS)
Słonina, Mariusz; Goździewski, Krzysztof; Migaszewski, Cezary
2015-01-01
We introduce the Mechanic, a new open-source code framework. It is designed to reduce the development effort of scientific applications by providing unified API (Application Programming Interface) for configuration, data storage and task management. The communication layer is based on the well-established Message Passing Interface (MPI) standard, which is widely used on variety of parallel computers and CPU-clusters. The data storage is performed within the Hierarchical Data Format (HDF5). The design of the code follows core-module approach which allows to reduce the user’s codebase and makes it portable for single- and multi-CPU environments. The framework may be used in a local user’s environment, without administrative access to the cluster, under the PBS or Slurm job schedulers. It may become a helper tool for a wide range of astronomical applications, particularly focused on processing large data sets, such as dynamical studies of long-term orbital evolution of planetary systems with Monte Carlo methods, dynamical maps or evolutionary algorithms. It has been already applied in numerical experiments conducted for Kepler-11 (Migaszewski et al., 2012) and νOctantis planetary systems (Goździewski et al., 2013). In this paper we describe the basics of the framework, including code listings for the implementation of a sample user’s module. The code is illustrated on a model Hamiltonian introduced by (Froeschlé et al., 2000) presenting the Arnold diffusion. The Arnold web is shown with the help of the MEGNO (Mean Exponential Growth of Nearby Orbits) fast indicator (Goździewski et al., 2008a) applied onto symplectic SABAn integrators family (Laskar and Robutel, 2001).
A THEORETICAL INVESTIGATION OF RADIOLYTIC H2 GENERATION FROM SOLIDS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Westbrook, M.; Sindelar, R.; Fisher, D.
2012-02-01
Hydrogen generation from materials in nuclear materials storage is of critical interest due to the potential for pressurization and/or flammability issues. Studies have focused on aqueous systems or those with minor amounts of physisorbed water, since conventional knowledge identifies the radiolytic decomposition of water as the source of H{sub 2} gas. Furthermore, the approach to characterize gas generation is typically strictly empirical, relying on determination of G-values from which production in systems is estimated. Interestingly, exploratory work at SRNL1 on gamma exposure to fully-dried solids with chemically-bound water that are typical of those produced on aluminium-clad nuclear fuel in reactormore » and post-discharge storage has shown a profound production of hydrogen (as the sole gaseous species) from fully dried boehmite ({gamma}-AlOOH or Al{sub 2}O{sub 3} {center_dot} H{sub 2}O) powders and no observable hydrogen from gibbsite ({gamma}-Al(OH){sub 3} or Al{sub 2}O{sub 3} {center_dot} 3H{sub 2}O) under gamma irradiation from cobalt-60. This observation is significant in that gibbsite is known to thermally decompose at 80 C whereas boehmite is stable to 400 C. Radiation damage can have various effects on solids, including heating, bond breaking, and rearrangements in the bonding structure. For example, a molecule can be ionized resulting in the generation of free electrons which can, in turn, ionize another molecule. Alternately, reactive radical species such as {lg_bullet}OH or cation species may be formed, which can go on to change bonding structures.« less
Beam position monitor gate functionality implementation and applications
Cheng, Weixing; Ha, Kiman; Li, Yongjun; ...
2018-06-14
We introduce a novel technique to implement gate functionality for the beam position monitors (BPM) at the National Synchrotron Light Source II (NSLS-II). The functionality, now implemented in FPGA, allows us to acquire two separated bunch-trains’ synchronized turn-by-turn (TBT) data simultaneously with the NSLS-II in-house developed BPM system. The gated position resolution is improved about 3 times by narrowing the sampling width. Experimentally we demonstrated that the machine lattice could be transparently characterized with the gated TBT data of a short diagnostic bunch-train Cheng et al., 2017; Li et al., 2017. Other applications, for example, precisely characterizing storage ring impedance/wake-fieldmore » through recording the beam positions of two separated bunch trains has been experimentally demonstrated.« less
Beam position monitor gate functionality implementation and applications
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cheng, Weixing; Ha, Kiman; Li, Yongjun
We introduce a novel technique to implement gate functionality for the beam position monitors (BPM) at the National Synchrotron Light Source II (NSLS-II). The functionality, now implemented in FPGA, allows us to acquire two separated bunch-trains’ synchronized turn-by-turn (TBT) data simultaneously with the NSLS-II in-house developed BPM system. The gated position resolution is improved about 3 times by narrowing the sampling width. Experimentally we demonstrated that the machine lattice could be transparently characterized with the gated TBT data of a short diagnostic bunch-train Cheng et al., 2017; Li et al., 2017. Other applications, for example, precisely characterizing storage ring impedance/wake-fieldmore » through recording the beam positions of two separated bunch trains has been experimentally demonstrated.« less
Soil type and texture impacts on soil organic carbon accumulation in a sub-tropical agro-ecosystem
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gonçalves, Daniel Ruiz Potma; Sa, Joao Carlos de Moraes; Mishra, Umakant
Soil organic carbon (C) plays a fundamental role in tropical and subtropical soil fertility, agronomic productivity, and soil health. As a tool for understand ecosystems dynamics, mathematical models such as Century have been used to assess soil's capacity to store C in different environments. However, as Century was initially developed for temperate ecosystems, several authors have hypothesized that C storage may be underestimated by Century in Oxisols. We tested the hypothesis that Century model can be parameterized for tropical soils and used to reliably estimate soil organic carbon (SOC) storage. The aim of this study was to investigate SOC storagemore » under two soil types and three textural classes and quantify the sources and magnitude of uncertainty using the Century model. The simulation for SOC storage was efficient and the mean residue was 10 Mg C ha -1 (13%) for n = 91. However, a different simulation bias was observed for soil with <600 g kg -1 of clay was 16.3 Mg C ha -1 (18%) for n = 30, and at >600 g kg -1 of clay, was 4 Mg C ha -1 (5%) for n = 50, respectively. The results suggest a non-linear effect of clay and silt contents on C storage in Oxisols. All types of soil contain nearly 70% of Fe and Al oxides in the clay fraction and a regression analysis showed an increase in model bias with increase in oxides content. Consequently, inclusion of mineralogical control of SOC stabilization by Fe and Al (hydro) oxides may improve results of Century model simulations in soils with high oxides contents« less
Xie, Haifeng; Zhu, Ye; Chen, Chen; Gu, Ning; Zhang, Feimin
2011-10-01
To examine the availability of sol-gel processed silica coating for alumina-based ceramic bonding, and determine which silica sol concentration was appropriate for silica coating. Sixty disks of In-Ceram alumina ceramic were fabricated and randomly divided into 5 main groups. The disks received 5 different surface conditioning treatments: Group Al, sandblasted; Group AlC, sandblasted + silane coupling agent applied; Groups Al20C, Al30C, and Al40C, sandblasted, silica coating via sol-gel process prepared using 20 wt%, 30 wt%, and 40 wt% silica sols, and then silane coupling agent applied. Before bonding, one-step adhesives were applied on pre-prepared ceramic surfaces of all groups. Then, 60 dentin specimens were prepared and conditioned with phosphoric acid and one-step adhesive. Ceramic disks of all groups were cemented to dentin specimens with dual-curing resin cements. Fracture strength was determined at 24 h and after 20 days of storage in water. Groups Al20C, Al30C, and Al40C revealed significantly higher fracture strength than groups Al and AlC. No statistically significant difference in fracture strength was found between groups Al and AlC, or among groups Al20C, Al30C, and Al40C. Fracture strength values of all the groups did not change after 20 days of water storage. Sol-gel processed silica coating can enhance fracture strength of In-Ceram alumina ceramic after bonding to dentin, and different silica sol concentrations produced the same effects. Twenty days of water storage did not decrease the fracture strength.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bonato, Leo, E-mail: leo.bonato@tu-berlin.de; Sala, Elisa M.; Stracke, Gernot
2015-01-26
A GaP n{sup +}p-diode containing In{sub 0.5}Ga{sub 0.5}As quantum dots (QDs) and an AlP barrier is characterized electrically, together with two reference samples: a simple n{sup +}p-diode and an n{sup +}p-diode with AlP barrier. Localization energy, capture cross-section, and storage time for holes in the QDs are determined using deep-level transient spectroscopy. The localization energy is 1.14(±0.04) eV, yielding a storage time at room temperature of 230(±60) s, which marks an improvement of 2 orders of magnitude compared to the former record value in QDs. Alternative material systems are proposed for still higher localization energies and longer storage times.
Bancroft, Tyler D; Hogeveen, Jeremy; Hockley, William E; Servos, Philip
2014-01-01
In a previous study, Harris et al. (2002) found disruption of vibrotactile short-term memory after applying single-pulse transcranial magnetic stimulation (TMS) to primary somatosensory cortex (SI) early in the maintenance period, and suggested that this demonstrated a role for SI in vibrotactile memory storage. While such a role is compatible with recent suggestions that sensory cortex is the storage substrate for working memory, it stands in contrast to a relatively large body of evidence from human EEG and single-cell recording in primates that instead points to prefrontal cortex as the storage substrate for vibrotactile memory. In the present study, we use computational methods to demonstrate how Harris et al.'s results can be reproduced by TMS-induced activity in sensory cortex and subsequent feedforward interference with memory traces stored in prefrontal cortex, thereby reconciling discordant findings in the tactile memory literature.
NASA Astrophysics Data System (ADS)
Romero, Dulce G.; Ho, Pei-Chun
2008-03-01
Nano-sized particles and clusters have promising electrical, chemical, and magnetic properties as compared to the bulk materials. Due to their reduced dimensionality, it makes their physical properties significantly different from the bulk material. The nano-sized materials have great potential for technical applications, such as, magnetic information storage, imaging, medical devices, and magnetic refrigeration. In this report, we will present the preliminary results on the growth and characterization of rare-earth metallic nanoparticles of Gd and Nd synthesized by the inverse micelle method [1]. These results will be compared to the bulk properties of Gd and Nd, as well as, to those exhibited by metallic nanoparticles, such as Co (by inverse micelle), and Gd (by laser evaporation cluster source), which have been found to show superparamagnetic behavior, enhanced magnetization, and self-organization [2-4]. [1] X.M. Lin, et al. Langmuir. 14, 7140 (1998). [2] D.C. Douglass, et al. Phys. Rev. B. 47, 19 (1993). [3] C. Petit, et al. Advanced Materials. 10, 259 (1998). [4] J.P. Chen, et al. Phys. Rev. B. 51, 11527 (1995).
NASA Astrophysics Data System (ADS)
Fleckenstein, J. H.; Yang, J.; Heidbuchel, I.; Musolff, A.
2017-12-01
Catchment-scale transit time distributions (TTDs) for discharge and residence time distributions (RTDs) of the water in storage are promising tools to characterize the discharge and mixing behavior of a catchment. TTDs and RTDs are dynamic in time, influenced by dynamic rainfall and evapotranspiration forcing, as well as changing groundwater storage in the catchment. In order to understand the links between the dynamics of TTDs and catchment mixing in an agricultural catchment in central Germany, a 3D hydrological model was set up using the fully coupled surface-subsurface numerical code HydroGeoSphere. The transient model is calibrated using discharge and groundwater level measurements, and is run for a period of 10 years from 1997 to 2007. A particle tracking tool was implemented in HydroGeoSphere to track the movement of water parcels in the subsurface, outputting TTDs of discharge and RTDs of groundwater storage at daily intervals. Results show the strong variability of the median age of discharge and median age of the water in storage, in response to the overall wetness of the catchment. Computed fractional StorAge Selection (fSAS, van der Velde et al. 2012, Rinaldo et al. 2015) functions suggest systematic changes in the preference of the catchment to discharge water of a certain age ranges from storage over the seasons: In the wet period, youngest water in storage is preferentially selected, and the preference shifts gradually to older water in storage when the catchment transitions into periods of post-wet, dry and pre-wet. Those changes are driven by distinct shifts in the dominant flow paths from deeper, slow flow paths during dry periods to faster shallow flow paths during the wet season. Changes in the shape of the fSAS functions are quantified in terms of changes in the two parameters of the Beta functions, which are used to approximate the fSAS functions. This provides an opportunity to generate quasi-continuous fSAS functions over the course of a year for the catchment. Our results provide new insights into the dynamics of TTDs and fSAS functions for a complex real-world catchment and can help to interpret the associated solute exports to the stream.
2012-06-19
ISS031-E-143143 (19 June 2012) --- Al Jubayl, Saudi Arabia at night is featured in this image photographed by an Expedition 31 crew member on the International Space Station. The city of Al Jubayl (or Jubail) is located on the Saudi Arabian coastline of the Persian Gulf. The city has a history extending back more than 7,000 years, but since 1975 it has been associated with the heavy industries of petrochemical refining and production, fertilizer production and steel works. At night, these industrial areas form a brightly lit region (center) to the south of the residential and commercial center of Al Jubayl (characterized by green-gray lighting). An artificial peninsula extending into the Persian Gulf to the northeast hosts supertanker docks and petroleum storage facilities. The Persian Gulf to the north and northeast is devoid of lights; likewise, the open desert to the south-southeast provides a stark contrast to the well-lit urban and industrial areas. A bright circle of light located within the heavy industrial area (center) cannot be resolved in this photograph, but is likely a concentration of lights associated with ongoing processing or construction activities. The approximate scale of the feature ? hundreds of meters in diameter ? is consistent with multiple stationary light sources, particularly if the light from those sources is accentuated due to the camera?s low light settings.
Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-21
... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Houston Pipe Line Company LP--Bammel Storage, Docket No. PR10-51- 000, et. al.; Notice of Baseline Filings July 14, 2010. Houston Pipe Line..., 2010, respectively the applicants listed above submitted their baseline filing of its Statement of...
NASA Technical Reports Server (NTRS)
Mcdaniel, R. H.; Bradford, E. W.; Lewis, J. H.; Wattier, J. B.
1973-01-01
Specimens fabricated from structural materials that were candidates for certain NERVA applications were irradiated in liquid nitrogen (LN2), liquid hydrogen (LH2), water, and air. The specimens irradiated in LN2 were stored in LN2 and finally tested in LN2, or at some higher temperature in a few instances. The specimens irradiated in LH2 underwent an unplanned warmup while in storage so this portion of the test was lost; some specimens were tested in LN2 but none were tested in LH2. The Ground Test Reactor was the radiation source. The test specimens consisted mainly of tensile and fracture toughness specimens of several different materials, but other types of specimens such as tear, flexure, springs, and lubricant were also irradiated. Materials tested include Hastelloy X, Al, Ni steel, steel, Be, ZrC, Ti-6Al-4V, CuB, and Ti-5Al-2.5Sn.
Destabilized and catalyzed borohydride for reversible hydrogen storage
Mohtadi, Rana F [Northville, MI; Nakamura, Kenji [Toyota, JP; Au, Ming [Martinez, GA; Zidan, Ragaiy [Alken, SC
2012-01-31
A process of forming a hydrogen storage material, including the steps of: providing a first material of the formula M(BH.sub.4).sub.X, where M is an alkali metal or an alkali earth metal, providing a second material selected from M(AlH.sub.4).sub.x, a mixture of M(AlH.sub.4).sub.x and MCl.sub.x, a mixture of MCl.sub.x and Al, a mixture of MCl.sub.x and AlH.sub.3, a mixture of MH.sub.x and Al, Al, and AlH.sub.3. The first and second materials are combined at an elevated temperature and at an elevated hydrogen pressure for a time period forming a third material having a lower hydrogen release temperature than the first material and a higher hydrogen gravimetric density than the second material.
DFT investigations of hydrogen storage materials
NASA Astrophysics Data System (ADS)
Wang, Gang
Hydrogen serves as a promising new energy source having no pollution and abundant on earth. However the most difficult problem of applying hydrogen is to store it effectively and safely, which is smartly resolved by attempting to keep hydrogen in some metal hydrides to reach a high hydrogen density in a safe way. There are several promising metal hydrides, the thermodynamic and chemical properties of which are to be investigated in this dissertation. Sodium alanate (NaAlH4) is one of the promising metal hydrides with high hydrogen storage capacity around 7.4 wt. % and relatively low decomposition temperature of around 100 °C with proper catalyst. Sodium hydride is a product of the decomposition of NaAlH4 that may affect the dynamics of NaAlH4. The two materials with oxygen contamination such as OH- may influence the kinetics of the dehydriding/rehydriding processes. Thus the solid solubility of OH - groups (NaOH) in NaAlH4 and NaH is studied theoretically by DFT calculations. Magnesium boride [Mg(BH4)2] is has higher hydrogen capacity about 14.9 wt. % and the decomposition temparture of around 250 °C. However one flaw restraining its application is that some polyboron compounds like MgB12H12 preventing from further release of hydrogen. Adding some transition metals that form magnesium transition metal ternary borohydride [MgaTMb(BH4)c] may simply the decomposition process to release hydrogen with ternary borides (MgaTMbBc). The search for the probable ternary borides and the corresponding pseudo phase diagrams as well as the decomposition thermodynamics are performed using DFT calculations and GCLP method to present some possible candidates.
Status and Impacts of Arctic Freshwater Export
NASA Astrophysics Data System (ADS)
Haine, T. W. N.
2017-12-01
Large freshwater anomalies clearly exist in the Arctic Ocean. For example, liquid freshwater has accumulated in the Beaufort Gyre in the decade of the 2000s compared to 1980-2000, with an extra ≈5000 km3—about 25%—being stored. The sources of freshwater to the Arctic from precipitation and runoff have increased between these periods (most of the evidence comes from models). Despite flux increases from 2001 to 2011, it is uncertain if the marine freshwater source through Bering Strait for the 2000s has changed, as observations in the 1980s and 1990s are incomplete. The marine freshwater fluxes draining the Arctic through Fram and Davis straits are also insignificantly different. In this way, the balance of sources and sinks of freshwater to the Arctic, Canadian Arctic Archipelago (CAA), and Baffin Bay shifted to about 1200±730 km3yr-1 freshening the region, on average, during the 2000s. The observed accumulation of liquid freshwater is consistent with this increased supply and the loss of freshwater from sea ice (Figure, right). Evidence exists that such discharges can impact the Atlantic meridional overturning circulation, and hence Atlantic sector climate. Nevertheless, it appears that the observed AMOC variability since 2004, when high quality measurements began, is not attributable to anthropogenic influence. This work is based on, and updated from, Haine et al. (2015), Carmack et al. (2016), and Haine (2016). Haine, T. W. N. Ocean science: Vagaries of Atlantic overturning. Nature Geoscience, 9, 479-480, 10.1038/ngeo2748, 2016. T. W. N. Haine et al., Arctic Freshwater Export: Status, Mechanisms, and Prospects, Global Planetary Change, 125, 13-35, 10.1016/j.glopacha.2014.11.013, 2015. E. Carmack et al., Fresh water and its role in the Arctic Marine System: sources, disposition, storage, export, and physical and biogeochemical consequences in the Arctic and global oceans. J. G. Res. Biogeosciences, 10.1002/2015JG003140, 2016.
Oblique view of rear and south sides of ammunition storage ...
Oblique view of rear and south sides of ammunition storage buildings 4403 and 4404, view towards the north without scale - Fort McClellan Ammunition Storage Area, Building No. 4403, Second Avenue (Magazine Road), Anniston, Calhoun County, AL
Oblique view of rear and south sides of ammunition storage ...
Oblique view of rear and south sides of ammunition storage buildings 4404 and 4405, view towards the north with scale - Fort McClellan Ammunition Storage Area, Building No. 4404, Second Avenue (Magazine Road), Anniston, Calhoun County, AL
Oblique view of rear and south sides of ammunition storage ...
Oblique view of rear and south sides of ammunition storage buildings 4404 and 4405, view towards the north without scale - Fort McClellan Ammunition Storage Area, Building No. 4404, Second Avenue (Magazine Road), Anniston, Calhoun County, AL
Federal Register 2010, 2011, 2012, 2013, 2014
2010-11-29
... Transportation, LLC, Enstor Katy Storage and Transportation, LP, et al.; Notice of Baseline Filings November 18... a revised baseline filing of their Statement of Operating Conditions for services provided under...
Thin Film Photovoltaic Cells on Flexible Substrates Integrated with Energy Storage
2011-11-30
mV[19]. In 2008, Katagiri et al ’ obtained an efficiency of 6.7% by Physical vapor methods[20]. In 2010, Mitzi et al reported an efficiency of 9.6...Films 517 (2009) 2455. [21] T.K. Todorov, K.B. Reuter, D.B. Mitzi , Adv Mater 22 (2010) El 56. 3. Energy Storage: Ultracapacitors - Professor Rastogi
303-K Storage Facility closure plan. Revision 2
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1993-12-15
Recyclable scrap uranium with zircaloy-2 and copper silicon alloy, uranium-titanium alloy, beryllium/zircaloy-2 alloy, and zircaloy-2 chips and fines were secured in concrete billets (7.5-gallon containers) in the 303-K Storage Facility, located in the 300 Area. The beryllium/zircaloy-2 alloy and zircaloy-2 chips and fines are designated as mixed waste with the characteristic of ignitability. The concretion process reduced the ignitability of the fines and chips for safe storage and shipment. This process has been discontinued and the 303-K Storage Facility is now undergoing closure as defined in the Resource Conservation and Recovery Act (RCRA) of 1976 and the Washington Administrative Codemore » (WAC) Dangerous Waste Regulations, WAC 173-303-040. This closure plan presents a description of the 303-K Storage Facility, the history of materials and waste managed, and the procedures that will be followed to close the 303-K Storage Facility. The 303-K Storage Facility is located within the 300-FF-3 (source) and 300-FF-5 (groundwater) operable units, as designated in the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) (Ecology et al. 1992). Contamination in the operable units 300-FF-3 and 300-FF-5 is scheduled to be addressed through the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 remedial action process. Therefore, all soil remedial action at the 304 Facility will be conducted as part of the CERCLA remedial action of operable units 300-FF-3 and 300-FF-5.« less
A Study of Single Pass Ion Effects at the ALS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Byrd, J.M.; Thomson, J.; /LBL, Berkeley
2011-09-13
We report the results of experiments on a 'fast beam-ion instability' at the Advanced Light Source (ALS). This ion instability, which can arise even when the ions are not trapped over multiple beam passages, will likely be important for many future accelerators. In our experiments, we filled the ALS storage ring with helium gas, raising the pressure approximately two orders of magnitude above the nominal pressure. With gaps in the bunch train large enough to avoid conventional (multi-turn) ion trapping, we observed a factor of 2-3 increase in the vertical beam size along with coherent beam oscillations which increased alongmore » the bunch train. Ion trapping has long been recognized as a potential limitation in electron storage rings. The ions, generated by beam-gas collisions, become trapped in the negative potential of the beam and accumulate over multiple beam passages. The trapped ions are then observed to cause a number of deleterious effects such as an increasing beam phase space, a broadening and shifting of the beam transverse oscillation frequencies (tunes), collective beam instabilities, and beam lifetime reductions. All of these effects are of concern for the next generation of accelerators, such as the B-factories or damping rings for future linear colliders, which will store high beam currents with closely spaced bunches and ultra-low beam emittances. One of the standard solutions used to prevent ion trapping is to include a gap in the bunch train which is long compared to the bunch spacing. In this case, the ions are first strongly-focused by the passing electron bunches and then over-focused in the gap. With a sufficiently large gap, the ions can be driven to large amplitudes where they form a diffuse halo and do not affect the beam. In this paper, we describe experiments that study a new regime of transient ion instabilities predicted to arise in future electron storage rings, and linacs with bunch trains. These future rings and linacs, which will be operated with higher beam currents, small transverse beam emittances, and long bunch trains, will use ion clearing gaps to prevent conventional ion trapping. But, while the ion clearing gap may suppress the conventional ion instabilities, it will not suppress a transient beam-ion instability where ions generated and trapped during the passage of a single train lead to a fast instability. While both conventional and transient ion instabilities have the same origin, namely ions produced by the beam, they have different manifestations and, more importantly, the new transient instability can arise even after the conventional ion instability is cured. This new instability is called the 'Fast Beam-Ion Instability' (FBII). In many future rings, the FBII is predicted to have very fast growth rates, much faster than the damping rates of existing and proposed transverse feedback systems, and thus is a potential limitation. To study the FBII, we performed experiments at the ALS, a 1.5 GeV electron storage ring. At the nominal ALS pressure of about 0.24 nTorr, the FBII is not evident. To study the instability, we intentionally added helium gas to the storage-ring vacuum system until the residual gas pressure was increased about 80 nTorr. This brought the predicted growth rate of the instability at least an order of magnitude above the growth rate of conventional multibunch instabilities driven by the RF cavities and above the damping rate of the transverse feedback system (TFB) in the ALS and, thereby, established conditions very similar to those in a future storage ring. We then filled the ring with a relatively short train of bunches, suppressing conventional ion instabilities. In the following, we will first briefly describe This paper describes the experiment and results in more detail.« less
Dovgaliuk, Iurii; Jepsen, Lars H; Safin, Damir A; Łodziana, Zbigniew; Dyadkin, Vadim; Jensen, Torben R; Devillers, Michel; Filinchuk, Yaroslav
2015-10-05
The first Al-based amidoborane Na[Al(NH2 BH3 )4 ] was obtained through a mechanochemical treatment of the NaAlH4 -4 AB (AB=NH3 BH3 ) composite releasing 4.5 wt % of pure hydrogen. The same amidoborane was also produced upon heating the composite at 70 °C. The crystal structure of Na[Al(NH2 BH3 )4 ], elucidated from synchrotron X-ray powder diffraction and confirmed by DFT calculations, contains the previously unknown tetrahedral ion [Al(NH2 BH3 )4 ](-) , with every NH2 BH3 (-) ligand coordinated to aluminum through nitrogen atoms. Combination of complex and chemical hydrides in the same compound was possible due to both the lower stability of the AlH bonds compared to the BH ones in borohydride, and due to the strong Lewis acidity of Al(3+) . According to the thermogravimetric analysis-differential scanning calorimetry-mass spectrometry (TGA-DSC-MS) studies, Na[Al(NH2 BH3 )4 ] releases in two steps 9 wt % of pure hydrogen. As a result of this decomposition, which was also supported by volumetric studies, the formation of NaBH4 and amorphous product(s) of the surmised composition AlN4 B3 H(0-3.6) were observed. Furthermore, volumetric experiments have also shown that the final residue can reversibly absorb about 27 % of the released hydrogen at 250 °C and p(H2 )=150 bar. Hydrogen re-absorption does not regenerate neither Na[Al(NH2 BH3 )4 ] nor starting materials, NaAlH4 and AB, but rather occurs within amorphous product(s). Detailed studies of the latter one(s) can open an avenue for a new family of reversible hydrogen storage materials. Finally, the NaAlH4 -4 AB composite might become a starting point towards a new series of aluminum-based tetraamidoboranes with improved hydrogen storage properties such as hydrogen storage density, hydrogen purity, and reversibility. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A new storage-ring light source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chao, Alex
2015-06-01
A recently proposed technique in storage ring accelerators is applied to provide potential high-power sources of photon radiation. The technique is based on the steady-state microbunching (SSMB) mechanism. As examples of this application, one may consider a high-power DUV photon source for research in atomic and molecular physics or a high-power EUV radiation source for industrial lithography. A less challenging proof-of-principle test to produce IR radiation using an existing storage ring is also considered.
NASA Astrophysics Data System (ADS)
Kies, Alexander; von Bremen, Lüder; Schyska, Bruno; Chattopadhyay, Kabitri; Lorenz, Elke; Heinemann, Detlev
2016-04-01
The transition of the European power system from fossil generation towards renewable sources is driven by different reasons like decarbonisation and sustainability. Renewable power sources like wind and solar have, due to their weather dependency, fluctuating feed-in profiles, which make their system integration a difficult task. To overcome this issue, several solutions have been investigated in the past like the optimal mix of wind and PV [1], the extension of the transmission grid or storages [2]. In this work, the optimal distribution of wind turbines and solar modules in Europe is investigated. For this purpose, feed-in data with an hourly temporal resolution and a spatial resolution of 7 km covering Europe for the renewable sources wind, photovoltaics and hydro was used. Together with historical load data and a transmission model , a simplified pan-European power power system was simulated. Under cost assumptions of [3] the levelized cost of electricity (LCOE) for this simplified system consisting of generation, consumption, transmission and backup units is calculated. With respect to the LCOE, the optimal distribution of generation facilities in Europe is derived. It is shown, that by optimal placement of renewable generation facilities the LCOE can be reduced by more than 10% compared to a meta study scenario [4] and a self-sufficient scenario (every country produces on average as much from renewable sources as it consumes). This is mainly caused by a shift of generation facilities towards highly suitable locations, reduced backup and increased transmission need. The results of the optimization will be shown and implications for the extension of renewable shares in the European power mix will be discussed. The work is part of the RESTORE 2050 project (Wuppertal Institute, Next Energy, University of Oldenburg), that is financed by the Federal Ministry of Education and Research (BMBF, Fkz. 03SFF0439A). [1] Kies, A. et al.: Kies, Alexander, et al. "Investigation of balancing effects in long term renewable energy feed-in with respect to the transmission grid." Advances in Science and Research 12.1 (2015): 91-95, doi:10.5194/asr-12-91-2015 [2] Heide, Dominik, et al. "Reduced storage and balancing needs in a fully renewable European power system with excess wind and solar power generation." Renewable Energy 36.9 (2011): 2515-2523 [3] Rodriguez, R.A.: Weather-driven power transmission in a highly renewable European electricity network, PhD Thesis, Aarhus University, November 2014 [4] Pfluger, B. et al.: Tangible ways towards climate protection in the European Union (EU long-term scenarios 2050), Fraunhofer ISI, Karlsruhe, September 2011
Soil Organic Carbon Transport in Headwater Tributaries of the Amazon River Traced by Branched GDGTs
NASA Astrophysics Data System (ADS)
Kirkels, F.; Peterse, F.; Ponton, C.; Feakins, S. J.; West, A. J.
2016-12-01
Transfer of soil organic carbon from land to sea by rivers plays a key role in the global carbon cycle by enabling long-term storage upon deposition in the marine environment, and generates archives of paleoinformation. Specific soil bacterial membrane lipids (branched glycerol dialkyl glycerol tetraethers, brGDGTs) can trace soil inputs to a river. BrGDGT distributions relate to soil pH and mean annual air temperature and can be inferred by a novel calibration [1]. In the Amazon Fan, down-core changes in brGDGTs have been used for paleoclimate reconstructions [2]. However, the effects of fluvial sourcing and transport on brGDGT signals in sedimentary deposits are largely unknown. In this study, we investigated the implications of upstream dynamics and hydrological variability (wet/dry season) on brGDGT distributions carried by the Madre de Dios River (Peru), a tributary of the upper Amazon River. The Madre de Dios basin covers a 4.5 km elevation gradient draining the eastern flank of the Andes to the Amazonian floodplains [3], along which we examined organic and mineral soils, and river suspended particulate matter (SPM). BrGDGT signals of SPM indicate sourcing of soils within the catchment, with concentrations increasing downstream indicating accumulation of this biomarker. River depth profiles demonstrated uniform brGDGT distributions and concentrations, suggesting no preferential transport and that brGDGTs are well-mixed in the river. These findings add to prior studies on brGDGTs in the downstream Amazon River [4, 5]. Our study highlights the importance of the upstream drainage basin to constrain the source of brGDGTs in rivers, to better interpret climate reconstructions with this proxy. [1] De Jonge et al. (2014) Geochim Cosmochim Act 141, 97-112 [2] Bendle et al. (2010) Geochem Geoph Geosy 11 [3] Ponton et al. (2014) Geophys. Res. Lett 41, 6420-6427. [4] Kim et al. (2012) Geochim Cosmochim Act 90, 163-180. [5] Zell et al. (2013) Front Microbio 4, 228.
Fort McClellan, ammunition storage building 4404. Planar view of rear ...
Fort McClellan, ammunition storage building 4404. Planar view of rear (west) side, view towards the east northeast without scale - Fort McClellan Ammunition Storage Area, Building No. 4404, Second Avenue (Magazine Road), Anniston, Calhoun County, AL
Hydrogen-bond memory and water-skin supersolidity resolving the Mpemba paradox.
Zhang, Xi; Huang, Yongli; Ma, Zengsheng; Zhou, Yichun; Zhou, Ji; Zheng, Weitao; Jiang, Qing; Sun, Chang Q
2014-11-14
The Mpemba paradox, that is, hotter water freezes faster than colder water, has baffled thinkers like Francis Bacon, René Descartes, and Aristotle since B.C. 350. However, a commonly accepted understanding or theoretical reproduction of this effect remains challenging. Numerical reproduction of observations, shown herewith, confirms that water skin supersolidity [Zhang et al., Phys. Chem. Chem. Phys., DOI: ] enhances the local thermal diffusivity favoring heat flowing outwardly in the liquid path. Analysis of experimental database reveals that the hydrogen bond (O:H-O) possesses memory to emit energy at a rate depending on its initial storage. Unlike other usual materials that lengthen and soften all bonds when they absorb thermal energy, water performs abnormally under heating to lengthen the O:H nonbond and shorten the H-O covalent bond through inter-oxygen Coulomb coupling [Sun et al., J. Phys. Chem. Lett., 2013, 4, 3238]. Cooling does the opposite to release energy, like releasing a coupled pair of bungees, at a rate of history dependence. Being sensitive to the source volume, skin radiation, and the drain temperature, the Mpemba effect proceeds only in the strictly non-adiabatic 'source-path-drain' cycling system for the heat "emission-conduction-dissipation" dynamics with a relaxation time that drops exponentially with the rise of the initial temperature of the liquid source.
UFD Storage and Transportation - Transportation Working Group Report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Maheras, Steven J.; Ross, Steven B.
2011-08-01
The Used Fuel Disposition (UFD) Transportation Task commenced in October 2010. As its first task, Pacific Northwest National Laboratory (PNNL) compiled a list of structures, systems, and components (SSCs) of transportation systems and their possible degradation mechanisms during extended storage. The list of SSCs and the associated degradation mechanisms [known as features, events, and processes (FEPs)] were based on the list of used nuclear fuel (UNF) storage system SSCs and degradation mechanisms developed by the UFD Storage Task (Hanson et al. 2011). Other sources of information surveyed to develop the list of SSCs and their degradation mechanisms included references suchmore » as Evaluation of the Technical Basis for Extended Dry Storage and Transportation of Used Nuclear Fuel (NWTRB 2010), Transportation, Aging and Disposal Canister System Performance Specification, Revision 1 (OCRWM 2008), Data Needs for Long-Term Storage of LWR Fuel (EPRI 1998), Technical Bases for Extended Dry Storage of Spent Nuclear Fuel (EPRI 2002), Used Fuel and High-Level Radioactive Waste Extended Storage Collaboration Program (EPRI 2010a), Industry Spent Fuel Storage Handbook (EPRI 2010b), and Transportation of Commercial Spent Nuclear Fuel, Issues Resolution (EPRI 2010c). SSCs include items such as the fuel, cladding, fuel baskets, neutron poisons, metal canisters, etc. Potential degradation mechanisms (FEPs) included mechanical, thermal, radiation and chemical stressors, such as fuel fragmentation, embrittlement of cladding by hydrogen, oxidation of cladding, metal fatigue, corrosion, etc. These degradation mechanisms are discussed in Section 2 of this report. The degradation mechanisms have been evaluated to determine if they would be influenced by extended storage or high burnup, the need for additional data, and their importance to transportation. These categories were used to identify the most significant transportation degradation mechanisms. As expected, for the most part, the transportation importance was mirrored by the importance assigned by the UFD Storage Task. A few of the more significant differences are described in Section 3 of this report« less
Contribution of aluminum from packaging materials and cooking utensils to the daily aluminum intake.
Müller, J P; Steinegger, A; Schlatter, C
1993-10-01
Migration of aluminum (Al) from packaging materials and cooking utensils into foods and beverages was determined at intervals during cooking or during storage by graphite furnace atomic absorption spectroscopy. High amounts of Al migrated into acidic products such as mashed tomatoes during normal processing in normal, non-coated Al pans. After 60 min cooking an Al content of 10-15 mg/kg was measured in tomato sauce. Surprisingly, the Al concentration was also increased up to 2.6 mg/L after boiling tap water for 15 min in Al pans. Storage of Coca-Cola in internally lacquered Al cans resulted in Al levels below 0.25 mg/L. In contrast, non-coated Al camping bottles containing lime blossom tea acidified with lemon juice released up to 7 mg Al/L within 5 days. The Al concentration in coffee was lower than that of the tap water used in its preparation, even if prepared in Al heaters. In Switzerland, where most pans nowadays are made of stainless steel or teflon-coated Al, the average contribution for the use of Al utensils to the daily Al intake of 2-5 mg from the diet is estimated to be less than 0.1 mg.
Magnetic measurements of the 10 T superconducting wiggler for the SPring-8 storage ring
NASA Astrophysics Data System (ADS)
Batrakov, A.; Borovikov, V.; Bekhtenev, E.; Fedurin, M.; Hara, M.; Karpov, G.; Kuzin, M.; Mezentsev, N.; Miahara, Y.; Shimada, T.; Shkaruba, V.; Soutome, K.; Tzumaki, K.
2001-07-01
In 1999, in the frame of the project ISTC #767 "Budker INP/RIKEN Slow Positron Source", the Budker Institute of Nuclear Physics had made a 10 T Three-pole Superconducting Wiggler. The wiggler will be the keystone of this project by its installation on the SPring-8 storage ring for powerful gamma ray generation ( λ c=450 keV ), that will be used for slow positron production ( Nγ( ɛ>1 MeV)˜10 15, γ/s I e=0.1 A ). A. Ando et al., Proposal of the high magnetic field super conducting WLS for slow positron source at SPring-8, presented at SR1 '97 Conference. In January, 2000, the wiggler was transported to SPring-8, where the last test and measurements were carried out in collaboration with Japan. In this article, the results of measurements of the magnetic field, finding the magnetic field amplitude by an NMR probe, the definition of feed current relations by stretch current wire method, the calibration of a Hall probe in the high magnetic field, and the measurement of the magnetic field profile by a Hall probe are presented.
NASA Technical Reports Server (NTRS)
1991-01-01
The MD Image System, a true-color image processing system that serves as a diagnostic aid and tool for storage and distribution of images, was developed by Medical Image Management Systems, Huntsville, AL, as a "spinoff from a spinoff." The original spinoff, Geostar 8800, developed by Crystal Image Technologies, Huntsville, incorporates advanced UNIX versions of ELAS (developed by NASA's Earth Resources Laboratory for analysis of Landsat images) for general purpose image processing. The MD Image System is an application of this technology to a medical system that aids in the diagnosis of cancer, and can accept, store and analyze images from other sources such as Magnetic Resonance Imaging.
Effect of Al substitution on the microstructure and lithium storage performance of nickel hydroxide
NASA Astrophysics Data System (ADS)
Li, Yanwei; Pan, Guanlin; Xu, Wenqiang; Yao, Jinhuan; Zhang, Lingzhi
2016-03-01
Al-substituted Ni(OH)2 samples with Al3+/Ni2+ mole ratio of 0%, 10% and 20% have been prepared by a very facile chemical co-precipitation method. The microstructure of the prepared samples are analyzed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric analysis (TGA), and Field emission scanning electron microscopy (FESEM). The results reveal that the pure Ni(OH)2 sample is β-Ni(OH)2 with nanosheets hierarchical structure; the sample with 10% Al is mixed phase α/β-Ni(OH)2 with hybrid nanosheets/nanoparticles hierarchical structure; the sample with 20% Al is α-Ni(OH)2 with irregular nanoparticles hierarchical structure. The lithium storage performances of the prepared samples are characterized by cyclic voltammograms (CV), electrochemical impedance spectroscopy (EIS), and charge-discharge tests. The results demonstrate that Al substitution could improve the lithium storage performances of nickel hydroxide. In particular, the mixed phase α/β-Ni(OH)2 with 10% Al exhibited the highest electrochemical activity, the best rate performance, and superior cycling stability. For example, after 30 charge/discharge cycles under a current density of 200 mA g-1, the mixed phase α/β-Ni(OH)2 with 10% Al can still deliver a specific discharge capacity of 964 mAh g-1, much higher than of for the α-Ni(OH)2 with 20% Al (681 mAh g-1) and the pure Ni(OH)2 (419 mAh g-1).
Energy storage requirements of dc microgrids with high penetration renewables under droop control
Weaver, Wayne W.; Robinett, Rush D.; Parker, Gordon G.; ...
2015-01-09
Energy storage is a important design component in microgrids with high penetration renewable sources to maintain the system because of the highly variable and sometimes stochastic nature of the sources. Storage devices can be distributed close to the sources and/or at the microgrid bus. In addition, storage requirements can be minimized with a centralized control architecture, but this creates a single point of failure. Distributed droop control enables a completely decentralized architecture but, the energy storage optimization becomes more difficult. Our paper presents an approach to droop control that enables the local and bus storage requirements to be determined. Givenmore » a priori knowledge of the design structure of a microgrid and the basic cycles of the renewable sources, we found that the droop settings of the sources are such that they minimize both the bus voltage variations and overall energy storage capacity required in the system. This approach can be used in the design phase of a microgrid with a decentralized control structure to determine appropriate droop settings as well as the sizing of energy storage devices.« less
Reed, Sasha C.
2017-01-01
Nitrogen (N) availability strongly influences the structure and function of ecosystems (e.g. Vitousek & Howarth, 1991), but only a relatively small number of microbial groups have the ability to convert the N2 in our atmosphere into biologically available forms.This process, N2 fixation, is the dominant source of new N to the biosphere outside of anthropogenic inputs (Vitousek et al., 2013).Some N2-fixing microorganisms live independently on plant leaves, on decomposing organic material, and in soil (Reed et al.,2011), while others have co-evolved with a few higher plant taxa to form symbioses that fix N2 in root nodules (e.g. Sprent & Raven,1985). The relationship between these legumes and their root nodule symbionts (rhizobia) is one of the most well studied plant –microbe symbioses. Yet, many important questions about the controls, interactions, and implications of legume N2 fixation remain unanswered. In this issue of New Phytologist (pp. 690–699),Wolf, Funk, & Menge elegantly address a fundamental set of questions about N2 fixation in their examination of how herbaceous legumes, their symbionts, and external N availability interact to govern legume access and storage of N.
Microencapsulation of metal-based phase change material for high-temperature thermal energy storage.
Nomura, Takahiro; Zhu, Chunyu; Sheng, Nan; Saito, Genki; Akiyama, Tomohiro
2015-03-13
Latent heat storage using alloys as phase change materials (PCMs) is an attractive option for high-temperature thermal energy storage. Encapsulation of these PCMs is essential for their successful use. However, so far, technology for producing microencapsulated PCMs (MEPCMs) that can be used above 500°C has not been established. Therefore, in this study, we developed Al-Si alloy microsphere MEPCMs covered by α-Al2O3 shells. The MEPCM was prepared in two steps: (1) the formation of an AlOOH shell on the PCM particles using a boehmite treatment, and (2) heat-oxidation treatment in an O2 atmosphere to form a stable α-Al2O3 shell. The MEPCM presented a melting point of 573°C and latent heat of 247 J g(-1). The cycling performance showed good durability. These results indicated the possibility of using MEPCM at high temperatures. The MEPCM developed in this study has great promise in future energy and chemical processes, such as exergy recuperation and process intensification.
Microencapsulation of Metal-based Phase Change Material for High-temperature Thermal Energy Storage
NASA Astrophysics Data System (ADS)
Nomura, Takahiro; Zhu, Chunyu; Sheng, Nan; Saito, Genki; Akiyama, Tomohiro
2015-03-01
Latent heat storage using alloys as phase change materials (PCMs) is an attractive option for high-temperature thermal energy storage. Encapsulation of these PCMs is essential for their successful use. However, so far, technology for producing microencapsulated PCMs (MEPCMs) that can be used above 500°C has not been established. Therefore, in this study, we developed Al-Si alloy microsphere MEPCMs covered by α-Al2O3 shells. The MEPCM was prepared in two steps: (1) the formation of an AlOOH shell on the PCM particles using a boehmite treatment, and (2) heat-oxidation treatment in an O2 atmosphere to form a stable α-Al2O3 shell. The MEPCM presented a melting point of 573°C and latent heat of 247 J g-1. The cycling performance showed good durability. These results indicated the possibility of using MEPCM at high temperatures. The MEPCM developed in this study has great promise in future energy and chemical processes, such as exergy recuperation and process intensification.
Mineralogy of the Hydrous Lower Mantle
NASA Astrophysics Data System (ADS)
Shim, S. H.; Chen, H.; Leinenweber, K. D.; Kunz, M.; Prakapenka, V.; Bechtel, H.; Liu, Z.
2017-12-01
The hydrous ringwoodite inclusions found in diamonds suggest water storage in the mantle transition zone. However, water storage in the lower mantle remains unclear. Bridgmanite and magnesiowustite appear to have very little storage capacity for water. Here, we report experimental results indicating significant changes in the lower-mantle mineralogy under the presence of water. We have synthesized Mg2SiO4 ringwoodite with 2 wt% water in multi-anvil press at 20 GPa and 1573 K at ASU. The hydrous ringwoodite sample was then loaded to diamond anvil cells with Ar or Ne as a pressure medium. We heated the pure hydrous ringwoodite samples at lower-mantle pressure using a CO2 laser heating system at ASU. We measured X-ray diffraction patterns at the GSECARS sector of the Advanced Photon Source (APS) and 12.2.2 sector of the Advanced Light Source (ALS). For the separate Pt-mixed samples, we have conducted in situ heating at the beamlines using near IR laser heating systems. We measured the infrared spectra of the heated samples at high pressure and after pressure quench at 1.4.4 sector of ALS. In the in situ experiments with hydrous ringwoodite + Pt mixture as a starting material, we found formation of stishovite together with bridgmanite and periclase during heating with a near IR laser beams at 1300-2500 K and 35-66 GPa. However, some hydrous ringwoodite still remains even after a total of 45 min of heating. In contrast, the hydrous ringwoodite samples heated without Pt by CO2 laser beams are transformed completely to bridgmanite, periclase and stishovite at 31-55 GPa and 1600-1900 K. We have detected IR active OH mode of stishovite from the samples heated at lower-mantle pressures. The unit-cell volume of stishovite measured after pressure quench is greater than that of dry stishovite by 0.3-0.6%, supporting 0.5-1 wt% of H2O in stishovite in these samples. Stishovite is a thermodynamically forbidden phase in the dry lower mantle because of the existence of periclase and bridgmanite. However, our results indicate that stishovite can exist together with periclase and bridgmanite when water is present, because water is stored in stishovite. Therefore, water-rich parts of the lower mantle, such as regions with subducting slabs, would have distinct mineralogy from their dry counterparts, containing stishovite as a water storage mineral.
Energy storage connection system
Benedict, Eric L.; Borland, Nicholas P.; Dale, Magdelena; Freeman, Belvin; Kite, Kim A.; Petter, Jeffrey K.; Taylor, Brendan F.
2012-07-03
A power system for connecting a variable voltage power source, such as a power controller, with a plurality of energy storage devices, at least two of which have a different initial voltage than the output voltage of the variable voltage power source. The power system includes a controller that increases the output voltage of the variable voltage power source. When such output voltage is substantially equal to the initial voltage of a first one of the energy storage devices, the controller sends a signal that causes a switch to connect the variable voltage power source with the first one of the energy storage devices. The controller then causes the output voltage of the variable voltage power source to continue increasing. When the output voltage is substantially equal to the initial voltage of a second one of the energy storage devices, the controller sends a signal that causes a switch to connect the variable voltage power source with the second one of the energy storage devices.
Mei, Xueyi; Yan, Qinghua; Lu, Peng; Wang, Junya; Cui, Yuhan; Nie, Yu; Umar, Ahmad; Wang, Qiang
2017-01-01
Pt/K2CO3/MgAlOx–reduced graphene oxide (Pt/K/MgAlOx–rGO) hybrids were synthesized, characterized and tested as a promising NOx storage and reduction (NSR) catalyst. Mg–Al layered double hydroxides (LDHs) were grown on rGO via in situ hydrothermal crystallization. The structure and morphology of samples were thoroughly characterized using various techniques. Isothermal NOx adsorption tests indicated that MgAlOx–rGO hybrid exhibited better NOx trapping performance than MgAlOx, from 0.44 to 0.61 mmol · g−1, which can be attributed to the enhanced particle dispersion and stabilization. In addition, a series of MgAlOx–rGO loaded with 2 wt% Pt and different loadings (5, 10, 15, and 20 wt%) of K2CO3 (denoted as Pt/K/MgAlOx–rGO) were obtained by sequential impregnation. The influence of 5% H2O on the NOx storage capacity of MgAlOx–rGO loaded with 2 wt% Pt and 10% K2CO3 (2Pt/10 K/MgAlOx–rGO) catalyst was also evaluated. In all, the 2Pt/10 K/MgAlOx–rGO catalyst not only exhibited high thermal stability and NOx storage capacity of 1.12 mmol · g−1, but also possessed excellent H2O resistance and lean–rich cycling performance, with an overall 78.4% of NOx removal. This work provided a new scheme for the preparation of highly dispersed MgAlOx–rGO hybrid based NSR catalysts. PMID:28205630
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ge, Qingfeng
2014-08-31
This major part of this proposal is simulating hydrogen interactions in the complex metal hydrides. Over the period of DOE BES support, key achievements include (i) Predicted TiAl 3Hx as a precursor state for forming TiAl 3 through analyzing the Ti-doped NaAlH 4 and demonstrated its catalytic role for hydrogen release; (ii) Explored the possibility of forming similar complex structures with other 3d transition metals in NaAlH 4 as well as the impact of such complex structures on hydrogen release/uptake; (iii) Demonstrated the role of TiAl 3 in hydriding process; (iv) Predicted a new phase of NaAlH 4 that linksmore » to Na3AlH6 using first-principles metadynamics; (v) Examined support effect on hydrogen release from supported/encapsulated NaAlH 4; and (vi) Expanded research scope beyond hydrogen storage. The success of our research is documented by the peer-reviewed publications.« less
Cole, Jacqueline M.; Cramer, Alisha J.; Zeidler, Anita
2015-07-15
The identification of inorganic materials, which are able to encapsulate environmentally important small molecules or ions via host-guest interactions, is crucial for the design and development of next-generation energy sources and for storing environmental waste. Especially sought after are molecular sponges with the ability to incorporate CO 2, gas pollutants, or nuclear waste materials such as UO 2 and PuO 2 oxides or U, Pu, Sr 2+ or Cs + ions. Porous framework structures promise very attractive prospects for applications in environmental technologies, if they are able to incorporate CH 4 for biogas energy applications, or to store H 2,more » which is important for fuel cells e.g. in the automotive industry. All of these applications should benefit from the host being resistant to extreme conditions such as heat, nuclear radiation, rapid gas expansion, or wear and tear from heavy gas cycling. As inorganic tungstates are well known for their thermal stability, and their rigid open-framework networks, the potential of Na 2O-Al 2O 3-WO 3 and Na 2O-WO 3 phases for such applications was evaluated. To this end, all known experimentally-determined crystal structures with the stoichiometric formula M aM’ bW cO d (M = any element) are surveyed together with all corresponding theoretically calculated Na aAl bW cO d and Na xW yO z structures that are statistically likely to form. Network descriptors that categorize these host structures are used to reveal topological patterns in the hosts, including the nature of porous cages which are able to accommodate a certain type of guest; this leads to the classification of preferential structure types for a given environmental storage application. Crystal structures of two new tungstates NaAlW 2O 8 (1) and NaAlW 3O 11 (2) and one updated structure determination of Na 2W 2O 7 (3) are also presented from in-house X-ray diffraction studies, and their potential merits for environmental applications are assessed against those of this larger data-sourced survey. Altogether, results show that tungstate structures with three-nodal topologies are most frequently able to accommodate CH 4 or H 2, while CO 2 appears to be captured by a wide range of nodal structure types. The computationally generated host structures appear systematically smaller than the experimentally determined structures. For the structures of 1 and 2, potential applications in nuclear waste storage seem feasible.« less
COKE STORAGE HOPPER LOCATED OUTSIDE THE MALLEABLE FOUNDRY SHOWING LOADING ...
COKE STORAGE HOPPER LOCATED OUTSIDE THE MALLEABLE FOUNDRY SHOWING LOADING DEVICE THAT USED A SKIP CAR TO FILL THE HOPPER FROM UNDERGROUND GRAVITY-FED STORAGE AREAS FROM INCOMING RAILROAD CARS. - Stockham Pipe & Fittings Company, 4000 Tenth Avenue North, Birmingham, Jefferson County, AL
NASA Astrophysics Data System (ADS)
Potthoff, Martin; Wichern, Florian; Dyckmans, Jens; Joergensen, Rainer Georg
2016-04-01
Earthworms deeply interact with the processes of soil organic matter turnover in soil. Stabilization of carbon by soil aggregation and in the humus fraction of SOM are well known processes related to earthworm activity and burrowing. However, recent research on priming effects showed inconsistent effects for the impact of earthworm activity. Endogeic earthworms can induce apparent as well as true positive priming effects. The main finding is almost always that earthworm increase the CO2 production from soil. The sources of this carbon release can vary and seem to depend on a complex interaction of quantity and quality of available carbon sources including added substrates like straw or other compounds, food preferences and feeding behavior of earthworms, and soil properties. Referring to recent studies on earthworm effects on soil carbon storage and release (mainly Eck et al. 2015 Priming effects of Aporrectodea caliginosa on young rhizodeposits and old soil organic matter following wheat straw addition, European Journal of Soil Biology 70:38-45; Zareitalabad et al. 2010 Decomposition of 15N-labelled maize leaves in soil affected by endogeic geophagous Aporrectodea caliginosa, Soil Biology and Biochemistry 42(2):276-282; and Potthoff et al. 2001 Short-term effects of earthworm activity and straw amendment on the microbial C and N turnover in a remoistened arable soil after summer drought, Soil Biology and Biochemistry 33(4):583-591) we summaries the knowledge on earthworms and priming and come up with a conceptual approach and further research needs.
Oscillatory hydraulic testing as a strategy for NAPL source zone monitoring: Laboratory experiments
NASA Astrophysics Data System (ADS)
Zhou, YaoQuan; Cardiff, Michael
2017-05-01
Non-aqueous phase liquids (NAPLs) have a complex mode of transport in heterogeneous aquifers, which can result in pools and lenses of NAPLs (the "source zone") that are difficult to detect and can cause long-term contamination via slow dissolution into groundwater (the "dissolved plume"). Characterizing the extent and evolution of NAPL contamination within the source zone is a useful strategy for designing and adapting appropriate remedial actions at many contaminated sites. As a NAPL flows into a given aquifer volume, the effective hydraulic conductivity (K) and specific storage (Ss) of the volume changes associated with the viscosity and compressibility of the impinging fluid, meaning that NAPL movement may be detectable with hydraulic testing. Recently, the use of oscillatory pumping tests - in which sinusoidal pumping variations are implemented and oscillatory pressure changes are detected at monitoring locations - has been suggested as a low-impact hydraulic testing strategy for characterizing aquifer properties (Cardiff et al., 2013; Zhou et al., 2016). Here, we investigate this strategy in an experimental laboratory sandbox where dyed vegetable oil is injected and allowed to migrate as a NAPL. Initial qualitative analyses demonstrate that measurable changes in pressure signal amplitude and phase provide clear evidence for NAPL plume emplacement and migration. Using the approach developed in Zhou et al. (2016), we then apply tomographic analyses to estimate the location of effective K changes (representing fluid changes) and their movement throughout time. This approach provides a method for monitoring ongoing NAPL movement without net extraction or injection of fluid, making it advantageous in field remediation applications.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kim, Do Heui; Mudiyanselage, Kumudu K.; Szanyi, Janos
2013-10-25
We have investigated nitrate formation and decomposition processes, and measured NOx storage performance on Pt-K2O/Al2O3 catalysts as a function of potassium loading. After NO2 adsorption at room temperature, ionic and bidentate nitrates were observed by fourier transform infra-red (FTIR) spectroscopy. The ratio of the former to the latter species increased with increasing potassium loading up to 10 wt%, and then stayed almost constant with additional K, demonstrating a clear dependence of loading on the morphology of the K species. Although both K2O(10)/Al2O3 and K2O(20)/Al2O3 samples have similar nitrate species after NO2 adsorption, the latter has more thermally stable nitrate speciesmore » as evidenced by FTIR and NO2 temperature programmed desorption (TPD) results. With regard to NOx storage performance, the temperature of maximum NOx uptake (Tmax) is 573 K up to a potassium loading of 10 wt%. As the potassium loading increases from 10 wt% to 20 wt%, Tmax shifted from 573 K to 723 K. Moreover, the amount of NO uptake (38 cm3 NOx/g catal) at Tmax increased more than three times, indicating that efficiency of K in storing NOx is enhanced significantly at higher temperature, in good agreement with the NO2 TPD and FTIR results. Thus, a combination of characterization and NOx storage performance results demonstrates an unexpected effect of potassium loading on nitrate formation and decomposition processes; results important for developing Pt-K2O/Al2O3 for potential applications as high temperature NOx storage-reduction catalysts.« less
A Review of Recent Research on Mechanics of Multifunctional Materials and Structures
2010-03-15
electrical and/or thermal conductivity, sensing and actuation, energy harvesting/storage, self - healing capability, and electromagnetic interference...conductivity 13 3.2 Sensing and actuation 15 3.3 Energy harvesting/storage 21 3.4 Self - healing capability 25 3.5...earlier by Zou, et al. [12]. Recent developments in self - healing polymeric materials were reviewed by Wu, et al. [13]. Articles on energy harvesting for
Effects of packaging materials on storage quality of peanut kernels
Fu, Xiaoji; Xing, Shengping; Xiong, Huiwei; Min, Hua; Zhu, Xuejing; He, Jialin; Mu, Honglei
2018-01-01
In order to obtain optimum packaging materials for peanut kernels, the effects of four types of packaging materials on peanut storage quality (coat color, acid value, germination rate, relative damage, and prevention of aflatoxin contamination) were examined. The results showed that packaging materials had a major influence on peanut storage quality indexes. The color of the peanut seed coat packaged in the polyester/aluminum/polyamide/polyethylene (PET/AL/PA/PE) composite film bag did not change significantly during the storage period. Color deterioration was slower with polyamide/polyethylene (PA/PE) packaging materials than with polyethylene (PE) film bags and was slower in PE bags than in the woven bags. The use of PET/AL/PA/PE and PA/PE bags maintained peanut quality and freshness for more than one year and both package types resulted in better germination rates. There were significant differences between the four types of packaging materials in terms of controlling insect pests. The peanuts packaged in the highly permeable woven bags suffered serious invasion from insect pests, while both PET/AL/PA/PE and PA/PE bags effectively prevented insect infection. Peanuts stored in PET/AL/PA/PE and PA/PE bags were also better at preventing and controlling aflatoxin contamination. PMID:29518085
DOE Office of Scientific and Technical Information (OSTI.GOV)
Brasser, Thomas; Hertes, Uwe; Meyer, Thorsten
2013-07-01
Within the scope of 'Nuclear Security of Radioactive Sources', the German government implemented the modernization of Ukrainian State Production Company's transport and storage facility for radioactive sources (TSF) in Kiev. The overall management of optimizing the physical protection of the storage facility (including the construction of a hot cell for handling the radioactive sources) is currently carried out by the German Federal Foreign Office (AA). AA jointly have assigned Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) mbH, Germany's leading expert institution in the area of nuclear safety and waste management, to implement the project and to ensure transparency by financial andmore » technical monitoring. Sealed radioactive sources are widely used in industry, medicine and research. Their life cycle starts with the production and finally ends with the interim/long-term storage of the disused sources. In Ukraine, IZOTOP is responsible for all radioactive sources throughout their life cycle. IZOTOP's transport and storage facility (TSF) is the only Ukrainian storage facility for factory-fresh radioactive sources up to an activity of about 1 million Ci (3.7 1016 Bq). The TSF is specially designed for the storage and handling of radioactive sources. Storage began in 1968, and is licensed by the Ukrainian state authorities. Beside the outdated state of TSF's physical protection and the vulnerability of the facility linked with it, the lack of a hot cell for handling and repacking radioactive sources on the site itself represents an additional potential hazard. The project, financed by the German Federal Foreign Office, aims to significantly improve the security of radioactive sources during their storage and handling at the TSF site. Main tasks of the project are a) the modernization of the physical protection of the TSF itself in order to prevent any unauthorized access to radioactive sources as well as b) the construction of a hot cell to reduce the number of transports of radioactive sources within the city of Kiev. In future, the new established hot cell at IZOTOP's transport and storage facility will be useful for identification and characterization of orphan/disused radioactive sources. The projects implemented are performed in accordance with international recommendations (e. g. IAEA) and national normative documents and will make a crucial contribution towards an improved safety and security management of radioactive sources in Ukraine. (authors)« less
NASA Astrophysics Data System (ADS)
Duan, Jianguo; Hu, Guorong; Cao, Yanbing; Tan, Chaopu; Wu, Ceng; Du, Ke; Peng, Zhongdong
2016-09-01
LiNi1-x-yCoxAlyO2 is a commonly used Ni-rich cathode material because of its relatively low cost, excellent rate capability and high gravimetric energy density. Surface modification is an efficient way to overcome the shortcomings of Ni-rich cathodes such as poor cycling stability and poor thermal stability. A high-powered concentration-gradient cathode material with an average composition of LiNi0.815Co0.15Al0.035O2 (LGNCAO) has been successfully synthesized by using spherical concentration-gradient Ni0.815Co0.15Al0.035(OH)2 (GNCA)as the starting material. An efficient design of the Al3+ precipitation method is developed, which enables obtaining spherical GNCA with ∼10 μm particle size and high tap density. In LGNCAO, the nickel and cobalt concentration decreases gradually whereas the aluminum concentration increases from the centre to the outer layer of each particle. Electrochemical performance and storage properties of LGNCAO have been investigated comparatively. The LGNCAO displays better electrochemical performance and improved storage stability than LNCAO.
Monetizing Leakage Risk of Geologic CO2 Storage using Wellbore Permeability Frequency Distributions
NASA Astrophysics Data System (ADS)
Bielicki, Jeffrey; Fitts, Jeffrey; Peters, Catherine; Wilson, Elizabeth
2013-04-01
Carbon dioxide (CO2) may be captured from large point sources (e.g., coal-fired power plants, oil refineries, cement manufacturers) and injected into deep sedimentary basins for storage, or sequestration, from the atmosphere. This technology—CO2 Capture and Storage (CCS)—may be a significant component of the portfolio of technologies deployed to mitigate climate change. But injected CO2, or the brine it displaces, may leak from the storage reservoir through a variety of natural and manmade pathways, including existing wells and wellbores. Such leakage will incur costs to a variety of stakeholders, which may affect the desirability of potential CO2 injection locations as well as the feasibility of the CCS approach writ large. Consequently, analyzing and monetizing leakage risk is necessary to develop CCS as a viable technological option to mitigate climate change. Risk is the product of the probability of an outcome and the impact of that outcome. Assessment of leakage risk from geologic CO2 storage reservoirs requires an analysis of the probabilities and magnitudes of leakage, identification of the outcomes that may result from leakage, and an assessment of the expected economic costs of those outcomes. One critical uncertainty regarding the rate and magnitude of leakage is determined by the leakiness of the well leakage pathway. This leakiness is characterized by a leakage permeability for the pathway, and recent work has sought to determine frequency distributions for the leakage permeabilities of wells and wellbores. We conduct a probabilistic analysis of leakage and monetized leakage risk for CO2 injection locations in the Michigan Sedimentary Basin (USA) using empirically derived frequency distributions for wellbore leakage permeabilities. To conduct this probabilistic risk analysis, we apply the RISCS (Risk Interference of Subsurface CO2 Storage) model (Bielicki et al, 2013a, 2012b) to injection into the Mt. Simon Sandstone. RISCS monetizes leakage risk by combining 3D geospatial data with fluid-flow simulations from the ELSA (Estimating Leakage Semi-Analytically) model (e.g., Celia and Nordbotten, 2006) and the Leakage Impact Valuation (LIV) method (Pollak et al, 2013; Bielicki et al, 2013). We extend RISCS to iterate ELSA semi-analytic modeling simulations by drawing values from the frequency distribution of leakage permeabilities. The iterations assign these values to existing wells in the basin, and the probabilistic risk analysis thus incorporates the uncertainty of the extent of leakage. We show that monetized leakage risk can vary significantly over tens of kilometers, and we identify "hot spots" favorable to CO2 injection based on the monetized leakage risk for each potential location in the basin.
Hydrogen adsorption in metal-decorated silicon carbide nanotubes
NASA Astrophysics Data System (ADS)
Singh, Ram Sevak; Solanki, Ankit
2016-09-01
Hydrogen storage for fuel cell is an active area of research and appropriate materials with excellent hydrogen adsorption properties are highly demanded. Nanotubes, having high surface to volume ratio, are promising storage materials for hydrogen. Recently, silicon carbide nanotubes have been predicted as potential materials for future hydrogen storage application, and studies in this area are ongoing. Here, we report a systematic study on hydrogen adsorption properties in metal (Pt, Ni and Al) decorated silicon carbide nanotubes (SiCNTs) using first principles calculations based on density functional theory. The hydrogen adsorption properties are investigated by calculations of adsorption energy, electronic band structure, density of states (DOS) and Mulliken charge population analysis. Our findings show that hydrogen adsorptions on Pt, Ni and Al-decorated SiCNTs undergo spontaneous exothermic reactions with significant modulation of electronic structure of SiCNTs in all cases. Importantly, according to the Mulliken charge population analysis, dipole-dipole interaction causes chemisorptions of hydrogen in Pt, Ni and Al decorated SiCNTs with formation of chemical bonds. The study is a platform for the development of metal decorated SiCNTs for hydrogen adsorption or hydrogen storage application.
The Physics and Applications of High Brightness Electron Beams
NASA Astrophysics Data System (ADS)
Palumbo, Luigi; Rosenzweig, J.; Serafini, Luca
2007-09-01
Plenary sessions. RF deflector based sub-Ps beam diagnostics: application to FEL and advanced accelerators / D. Alesini. Production of fermtosecond pulses and micron beam spots for high brightness electron beam applications / S.G. Anderson ... [et al.]. Wakefields of sub-picosecond electron bunches / K.L.F. Bane. Diamond secondary emitter / I. Ben-Zvi ... [et al.]. Parametric optimization for an X-ray free electron laser with a laser wiggler / R. Bonifacio, N. Piovella and M.M. Cola. Needle cathodes for high-brightness beams / C.H. Boulware ... [et al.]. Non linear evolution of short pulses in FEL cascaded undulators and the FEL harmonic cascade / L. Giannessi and P. Musumeci. High brightness laser induced multi-meV electron/proton sources / D. Giulietti ... [et al.]. Emittance limitation of a conditioned beam in a strong focusing FEL undulator / Z. Huang, G. Stupakov and S. Reiche. Scaled models: space-charge dominated electron storage rings / R.A. Kishek ... [et al.]. High brightness beam applications: energy recovered linacs / G.A. Krafft. Maximizing brightness in photoinjectors / C. Limborg-Deprey and H. Tomizawa. Ultracold electron sources / O.J. Luiten ... [et al.]. Scaling laws of structure-based optical accelerators / A. Mizrahi, V. Karagodsky and L. Schächter. High brightness beams-applications to free-electron lasers / S. Reiche. Conception of photo-injectors for the CTF3 experiment / R. Roux. Superconducting RF photoinjectors: an overview / J. Sekutowicz. Status and perspectives of photo injector developments for high brightness beams / F. Stephan. Results from the UCLA/FNLP underdense plasma lens experiment / M.C. Thompson ... [et al.]. Medical application of multi-beam compton scattering monochromatic tunable hard X-ray source / M. Uesaka ... [et al.]. Design of a 2 kA, 30 fs RF-photoinjector for waterbag compression / S.B. Van Der Geer, O.J. Luiten and M.J. De Loos. Proposal for a high-brightness pulsed electron source / M. Zolotorev ... [et al.]. -- Working Group 1. Summary of working group 1 on electron sources / M. Ferrario and G. Gatti. Design and RF measurements of an X-band accelerating structure for the SPARC project / D. Alesini ... [et al.]. Mitigation of RF gun breakdown by removal of tuning rods in high field regions / A.M. Cook... [et al.]. Measurements of quantum efficiency of Mg films produced by pulsed laser ablation deposition for application to bright electron sources / G. Gatti ... [et al.]. The S-band 1.6 cell RF gun correlated energy spread dependence on Pi and 0 mode relative amplitude / F. Schmerge ... [et al.]. RF gun photo-emission model for metal cathodes including time dependent emission / J.F. Schmerge ... [et al.]. Superconducting photocathodes / J. Smedley ... [et al.]. -- Working Group 2. Summary of Working Group 2: diagnostics and beam manipulation / G. Travish. Observation of coherent edge radiation emitted by a 100 Femtosecond compressed electron beam / G. Andonian, M, Dunning, E. Hemsing, J. B. Rosenzweig ... [et al.]. PARMELA simulations for PITZ: first machine studies and interpretation of measurements / M. Boscolo ... [et al.]. The LCLS single-shot relative bunch length monitor system / M.P. Dunning ... [et al.]. Beam shaping and permanent magnet quadrupole focusing with applications to the plasma wakefield accelerator / R.J. England ... [et al.]. Commissioning of the SPARC movable emittance meter and its first operation at PITZ / D. Filippetto... [et al.]. Experimental testing of dynamically optimized photoelectron beams / J.B. Rosenzweig ... [et al.]. Synchronization between the laser and electron beam in a photocathode RF gun / A. Sakumi ... [et al.]. Method of bunch radiation photochronography with 10 Femtosecond and less resolution / A. Tron and I. Merinov -- Working Group 3. New challenges in theory and modeling-summary for working group 3. L. Giannessi. Resonant modes in a 1.6 cells RF gun / M. Ferrario and C. Ronsivalle. Emittance degradation due to wake fields in a high brightness photoinjector / M. Ferrario, V. Fusco, M. Migliorati and L. Palumbo. Simulations of coherent synchroton radiation effects in electron machines / M. Migliorati, A, Schiavi and G. Dattoli. QFEL: A numerical code for multi-dimensional simulation of free electron lasers in the quantum regime / A. Schiavi ... [et al.]. First simulations results on laser pulse jitter and microbunching instability at Saprxino / M. Boscolo ... [et al.]. -- Working Group 4. Working group 4 summary: applications of high brightness beams to advanced accelerators and light sources / M. Uesaka and A. Rossi. Study of transverse effects in the production of X-rays with free-electron laser based on an optical ondulator / A. Bacci ... [et al.]. Channeling projects at LNF: from crystal undulators to capillary waveguides / S.B. Dabagov ... [et al.]. Mono-Energetic electron generation and plasma diagnosis experiments in a laser plasma cathode / K. Kinoshita ... [et al.]. A high-density electron beam and quad-scan measurements at Pleiades Thompson X-ray source / J.K. Lim ... [et al.]. Laser pulse circulation system for compact monochromatic tunable hard X-ray source / H. Ogino ... [et al.]. Limits on production of narrow band photons from inverse compton scattering / J. Rosenzweig and O. Williams. Preliminary results from the UCLA/SLAC ultra-high gradient Cerenkov wakefield accelerator experiment / M.C. Thompson ... [et al.]. Status of the polarized nonlinear inverse compton scattering experiment at UCLA / O. Williams... [et al.]. Coupling laser power into a slab-symmetric accelerator structure / R.B. Yoder and J.B. Rosenzweig.
Structure of aging Al-Li-Cu-Zr-Sc-Ag alloy after severe plastic deformation and long-term storage
NASA Astrophysics Data System (ADS)
Kaigorodova, L. I.; Rasposienko, D. Yu.; Pushin, V. G.; Pilyugin, V. P.; Smirnov, S. V.
2015-11-01
Structural and phase transformations in commercial aging aluminum-lithium Al-1.2 Li-3.2 Cu-0.09 Zr-0.11 Sc-0.4 Ag-0.3 Mg alloy have been studied after severe plastic deformation by high-pressure torsion (at a pressure of 4 GPa with 1, 5, and 10 revolutions of the anvil) and natural aging (roomtemperature storage) for 1 week and 2 years. It has been found that, in this case, the process of static recrystallization is achieved in the alloy, the degree of which increases with an increasing degree of deformation and time of storage.
GENERAL VIEW LOOKING NORTHEAST FROM ATOP A STORAGE TANK, LOOKING ...
GENERAL VIEW LOOKING NORTHEAST FROM ATOP A STORAGE TANK, LOOKING AT THE CATALYZER BUILDINGS. NOTE CIRCULAR FOUNDATION FOR AMMONIA STORAGE TANK AND THE LIQUID AIR BUILDING IN THE UPPPER RIGHT CORNER OF PHOTO. - United States Nitrate Plant No. 2, Reservation Road, Muscle Shoals, Muscle Shoals, Colbert County, AL
NASA Astrophysics Data System (ADS)
Lacey, Ian; Adam, Jérôme; Centers, Gary P.; Gevorkyan, Gevork S.; Nikitin, Sergey M.; Smith, Brian V.; Yashchuk, Valeriy V.
2017-09-01
The research and development work on the Advanced Light Source (ALS) upgrade to a diffraction limited storage ring light source, ALS-U, has brought to focus the need for near-perfect x-ray optics, capable of delivering light to experiments without significant degradation of brightness and coherence. The desired surface quality is characterized with residual (after subtraction of an ideal shape) surface slope and height errors of <50-100 nrad (rms) and <1-2 nm (rms), respectively. The ex-situ metrology that supports the optimal usage of the optics at the beamlines has to offer even higher measurement accuracy. At the ALS X-Ray Optics Laboratory, we are developing a new surface slope profiler, the Optical Surface Measuring System (OSMS), capable of two-dimensional (2D) surface-slope metrology at an absolute accuracy below the above optical specification. In this article we provide the results of comprehensive characterization of the key elements of the OSMS, a NOM-like high-precision granite gantry system with air-bearing translation and a custom-made precision air-bearing stage for tilting and flipping the surface under test. We show that the high performance of the gantry system allows implementing an original scanning mode for 2D mapping. We demonstrate the efficiency of the developed 2D mapping via comparison with 1D slope measurements performed with the same hyperbolic test mirror using the ALS developmental long trace profiler. The details of the OSMS design and the developed measuring techniques are also provided.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wickliff, D.S.; Solomon, D.K.; Farrow, N.D.
Solid Waste Storage Area (SWSA) 5 is known to be a significant source of contaminants, especially tritium ({sup 3}H), to the White Oak Creek (WOC) watershed. For example, Solomon et al. (1991) estimated the total {sup 3}H discharge in Melton Branch (most of which originates in SWSA 5) for the 1988 water year to be 1210 Ci. A critical issue for making decisions concerning remedial actions at SWSA 5 is knowing whether the annual contaminant discharge is increasing or decreasing. Because (1) the magnitude of the annual contaminant discharge is highly correlated to the amount of annual precipitation (Solomon etmore » al., 1991) and (2) a significant lag may exist between the time of peak contaminant release from primary sources (i.e., waste trenches) and the time of peak discharge into streams, short-term stream monitoring by itself is not sufficient for predicting future contaminant discharges. In this study we use {sup 3}H to examine the link between contaminant release from primary waste sources and contaminant discharge into streams. By understanding and quantifying subsurface transport processes, realistic predictions of future contaminant discharge, along with an evaluation of the effectiveness of remedial action alternatives, will be possible. The objectives of this study are (1) to characterize the subsurface movement of contaminants (primarily {sup 3}H) with an emphasis on the effects of matrix diffusion; (2) to determine the relative strength of primary vs secondary sources; and (3) to establish a methodology capable of determining whether the {sup 3}H discharge from SWSA 5 to streams is increasing or decreasing.« less
Preliminary investigation of processes that affect source term identification
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wickliff, D.S.; Solomon, D.K.; Farrow, N.D.
Solid Waste Storage Area (SWSA) 5 is known to be a significant source of contaminants, especially tritium ({sup 3}H), to the White Oak Creek (WOC) watershed. For example, Solomon et al. (1991) estimated the total {sup 3}H discharge in Melton Branch (most of which originates in SWSA 5) for the 1988 water year to be 1210 Ci. A critical issue for making decisions concerning remedial actions at SWSA 5 is knowing whether the annual contaminant discharge is increasing or decreasing. Because (1) the magnitude of the annual contaminant discharge is highly correlated to the amount of annual precipitation (Solomon etmore » al., 1991) and (2) a significant lag may exist between the time of peak contaminant release from primary sources (i.e., waste trenches) and the time of peak discharge into streams, short-term stream monitoring by itself is not sufficient for predicting future contaminant discharges. In this study we use {sup 3}H to examine the link between contaminant release from primary waste sources and contaminant discharge into streams. By understanding and quantifying subsurface transport processes, realistic predictions of future contaminant discharge, along with an evaluation of the effectiveness of remedial action alternatives, will be possible. The objectives of this study are (1) to characterize the subsurface movement of contaminants (primarily {sup 3}H) with an emphasis on the effects of matrix diffusion; (2) to determine the relative strength of primary vs secondary sources; and (3) to establish a methodology capable of determining whether the {sup 3}H discharge from SWSA 5 to streams is increasing or decreasing.« less
Advanced control for ground source heat pump systems
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hughes, Patrick; Gehl, Anthony C.; Liu, Xiaobing
Ground source heat pumps (GSHP), also known as geothermal heat pumps (GHP), are proven advanced HVAC systems that utilize clean and renewable geothermal energy, as well as the massive thermal storage capacity of the ground, to provide space conditioning and water heating for both residential and commercial buildings. GSHPs have higher energy efficiencies than conventional HVAC systems. It is estimated, if GSHPs achieve a 10% market share in the US, in each year, 0.6 Quad Btu primary energy consumption can be saved and 36 million tons carbon emissions can be avoided (Liu et al. 2017). However, the current market sharemore » of GSHPs is less than 1%. The foremost barrier preventing wider adoption of GSHPs is their high installation costs. To enable wider adoption of GSHPs, the costeffectiveness of GSHP applications must be improved.« less
Microencapsulation of Metal-based Phase Change Material for High-temperature Thermal Energy Storage
Nomura, Takahiro; Zhu, Chunyu; Sheng, Nan; Saito, Genki; Akiyama, Tomohiro
2015-01-01
Latent heat storage using alloys as phase change materials (PCMs) is an attractive option for high-temperature thermal energy storage. Encapsulation of these PCMs is essential for their successful use. However, so far, technology for producing microencapsulated PCMs (MEPCMs) that can be used above 500°C has not been established. Therefore, in this study, we developed Al-Si alloy microsphere MEPCMs covered by α-Al2O3 shells. The MEPCM was prepared in two steps: (1) the formation of an AlOOH shell on the PCM particles using a boehmite treatment, and (2) heat-oxidation treatment in an O2 atmosphere to form a stable α-Al2O3 shell. The MEPCM presented a melting point of 573°C and latent heat of 247 J g−1. The cycling performance showed good durability. These results indicated the possibility of using MEPCM at high temperatures. The MEPCM developed in this study has great promise in future energy and chemical processes, such as exergy recuperation and process intensification. PMID:25766648
Facile Synthesis and Superior Catalytic Activity of Nano-TiN@N-C for Hydrogen Storage in NaAlH4.
Zhang, Xin; Ren, Zhuanghe; Lu, Yunhao; Yao, Jianhua; Gao, Mingxia; Liu, Yongfeng; Pan, Hongge
2018-05-09
Herein, we synthesize successfully ultrafine TiN nanoparticles (<3 nm in size) embedded in N-doped carbon nanorods (nano-TiN@N-C) by a facile one-step calcination process. The prepared nano-TiN@N-C exhibits superior catalytic activity for hydrogen storage in NaAlH 4 . Adding 7 wt % nano-TiN@N-C induces more than 100 °C reduction in the onset dehydrogenation temperature of NaAlH 4 . Approximately 4.9 wt % H 2 is rapidly released from the 7 wt % nano-TiN@N-C-containing NaAlH 4 at 140 °C within 60 min, and the dehydrogenation product is completely hydrogenated at 100 °C within 15 min under 100 bar of hydrogen, exhibiting significantly improved desorption/absorption kinetics. No capacity loss is observed for the nano-TiN@N-C-containing sample within 25 de-/hydrogenation cycles because nano-TiN functions as an active catalyst instead of a precursor. A severe structural distortion with extended bond lengths and reduced bond strengths for Al-H bonding when the [AlH 4 ] - group adsorbs on the TiN cluster is demonstrated for the first time by density functional theory calculations, which well-explains the reduced de-/hydrogenation temperatures of the nano-TiN@N-C-containing NaAlH 4 . These findings provide new insights into designing and synthesizing high-performance catalysts for hydrogen storage in complex hydrides.
NASA Astrophysics Data System (ADS)
Wang, Q.; Song, Z. T.; Liu, W. L.; Lin, C. L.; Wang, T. H.
2004-05-01
Monolayer-isolated silver (Ag) nanodots with the average diameter down to 7 nm are synthesized on Al 2O 3/Si substrate by vacuum electron-beam evaporation followed by annealing at 400 °C in N 2 ambient. Metal-insulator-silicon (MIS) structures with Ag nanodots embedded in Al 2O 3 gate dielectric are fabricated. Clear electron storage effect with the flatband voltage shift of 1.3 eV is observed through capacitance-conductance and conductance-voltage measurements. Our results demonstrate the feasibility of applying Ag nanodots for nanocrystal floating-gate memory devices.
Simple protocols for oblivious transfer and secure identification in the noisy-quantum-storage model
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schaffner, Christian
2010-09-15
We present simple protocols for oblivious transfer and password-based identification which are secure against general attacks in the noisy-quantum-storage model as defined in R. Koenig, S. Wehner, and J. Wullschleger [e-print arXiv:0906.1030]. We argue that a technical tool from Koenig et al. suffices to prove security of the known protocols. Whereas the more involved protocol for oblivious transfer from Koenig et al. requires less noise in storage to achieve security, our ''canonical'' protocols have the advantage of being simpler to implement and the security error is easier control. Therefore, our protocols yield higher OT rates for many realistic noise parameters.more » Furthermore, a proof of security of a direct protocol for password-based identification against general noisy-quantum-storage attacks is given.« less
40 CFR Table 4 to Subpart U of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Group 1 Storage Vessels at New Sources... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 4 Table 4 to Subpart U of Part 63—Group 1 Storage Vessels at New Sources Vessel...
40 CFR Table 4 to Subpart U of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Group 1 Storage Vessels at New Sources... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 4 Table 4 to Subpart U of Part 63—Group 1 Storage Vessels at New Sources Vessel...
40 CFR Table 4 to Subpart U of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Group 1 Storage Vessels at New Sources... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 4 Table 4 to Subpart U of Part 63—Group 1 Storage Vessels at New Sources Vessel...
40 CFR Table 4 to Subpart U of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Group 1 Storage Vessels at New Sources... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 4 Table 4 to Subpart U of Part 63—Group 1 Storage Vessels at New Sources Vessel...
40 CFR Table 4 to Subpart U of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Group 1 Storage Vessels at New Sources... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 4 Table 4 to Subpart U of Part 63—Group 1 Storage Vessels at New Sources Vessel...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Weber, Jonah M.; Chin, Michael
2002-04-30
The Control System for the Advanced Light Source (ALS) at Lawrence Berkeley National Lab (LBNL) uses in-house designed IndustryPack(registered trademark) (IP) modules contained in compact PCI (cPCI) crates with 16-bit analog I/O to control instrumentation. To make the IP modules interchangeable, each module is calibrated for gain and offset compensation. We initially developed a method of verifying and calibrating the IP modules in a lab bench test environment using a PC with LabVIEW. The subsequent discovery that the ADCs have significant drift characteristics over periods of days of installed operation prompted development of an ''in-situ'' calibration process--one in which themore » IP modules can be calibrated without removing them from the cPCI crates in the storage ring. This paper discusses the original LabVIEW PC calibration and the migration to the proposed in-situ EPICS control system calibration.« less
NASA Astrophysics Data System (ADS)
Kim, Ho-Sung; Kim, Jeon Min; Kim, Tae-Won; Oh, Ik-Hyun; Choi, Jeon; Park, Choong Nyeon
2008-08-01
Hydrogen storage alloys based on LmNi4.2Co0.2Mn0.3Al0.3 were fabricated to study the equilibrium hydrogen pressure and electrochemical performance. The surface morphology and structure of the alloys were analyzed by SEM and XRD, and then the hydrogenation behaviors of all alloys were evaluated by PCT and electrochemical half-cell. We studied the hydrogenation behavior of the Lm-based alloy with changes in composition elements such as Mn, Al, and Co and investigated the optimal design for Lm-based alloy in a sealed battery system. As a result of studying the hydrogenation characterization of alloys with the substitution elements, hydrogen storage alloys such as LmNi3.75Co0.15Mn0.5Al0.3 and LmNi3.5Co0.5Mn0.5Al0.5 were obtained to correspond with the characteristics of a sealed battery with a higher capacity, long life cycle, lower internal pressure, and lower battery cost. The capacity preservation rate of LmNi3.5Co0.5Mn0.5Al0.5 was greatly improved to 92.7% (255 mAh/g) at 60 cycles, indicating a low equilibrium hydrogen pressure of 0.03 atm in PCT devices.
Radioactive Waste Management and Nuclear Facility Decommissioning Progress in Iraq - 13216
DOE Office of Scientific and Technical Information (OSTI.GOV)
Al-Musawi, Fouad; Shamsaldin, Emad S.; Jasim, Hadi
2013-07-01
Management of Iraq's radioactive wastes and decommissioning of Iraq's former nuclear facilities are the responsibility of Iraq's Ministry of Science and Technology (MoST). The majority of Iraq's former nuclear facilities are in the Al-Tuwaitha Nuclear Research Center located a few kilometers from the edge of Baghdad. These facilities include bombed and partially destroyed research reactors, a fuel fabrication facility and radioisotope production facilities. Within these facilities are large numbers of silos, approximately 30 process or waste storage tanks and thousands of drums of uncharacterised radioactive waste. There are also former nuclear facilities/sites that are outside of Al-Tuwaitha and these includemore » the former uranium processing and waste storage facility at Jesira, the dump site near Adaya, the former centrifuge facility at Rashdiya and the former enrichment plant at Tarmiya. In 2005, Iraq lacked the infrastructure needed to decommission its nuclear facilities and manage its radioactive wastes. The lack of infrastructure included: (1) the lack of an organization responsible for decommissioning and radioactive waste management, (2) the lack of a storage facility for radioactive wastes, (3) the lack of professionals with experience in decommissioning and modern waste management practices, (4) the lack of laws and regulations governing decommissioning or radioactive waste management, (5) ongoing security concerns, and (6) limited availability of electricity and internet. Since its creation eight years ago, the MoST has worked with the international community and developed an organizational structure, trained staff, and made great progress in managing radioactive wastes and decommissioning Iraq's former nuclear facilities. This progress has been made, despite the very difficult implementing conditions in Iraq. Within MoST, the Radioactive Waste Treatment and Management Directorate (RWTMD) is responsible for waste management and the Iraqi Decommissioning Directorate (IDD) is responsible for decommissioning activities. The IDD and the RWTMD work together on decommissioning projects. The IDD has developed plans and has completed decommissioning of the GeoPilot Facility in Baghdad and the Active Metallurgical Testing Laboratory (LAMA) in Al-Tuwaitha. Given this experience, the IDD has initiated work on more dangerous facilities. Plans are being developed to characterize, decontaminate and decommission the Tamuz II Research Reactor. The Tammuz Reactor was destroyed by an Israeli air-strike in 1981 and the Tammuz II Reactor was destroyed during the First Gulf War in 1991. In addition to being responsible for managing the decommissioning wastes, the RWTMD is responsible for more than 950 disused sealed radioactive sources, contaminated debris from the first Gulf War and (approximately 900 tons) of naturally-occurring radioactive materials wastes from oil production in Iraq. The RWTMD has trained staff, rehabilitated the Building 39 Radioactive Waste Storage building, rehabilitated portions of the French-built Radioactive Waste Treatment Station, organized and secured thousands of drums of radioactive waste organized and secured the stores of disused sealed radioactive sources. Currently, the IDD and the RWTMD are finalizing plans for the decommissioning of the Tammuz II Research Reactor. (authors)« less
Conceptual design report: Nuclear materials storage facility renovation. Part 6, Alternatives study
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
1995-07-14
The Nuclear Materials Storage Facility (NMSF) at the Los Alamos National Laboratory (LANL) was a Fiscal Year (FY) 1984 line-item project completed in 1987 that has never been operated because of major design and construction deficiencies. This renovation project, which will correct those deficiencies and allow operation of the facility, is proposed as an FY 97 line item. The mission of the project is to provide centralized intermediate and long-term storage of special nuclear materials (SNM) associated with defined LANL programmatic missions and to establish a centralized SNM shipping and receiving location for Technical Area (TA)-55 at LANL. Based onmore » current projections, existing storage space for SNM at other locations at LANL will be loaded to capacity by approximately 2002. This will adversely affect LANUs ability to meet its mission requirements in the future. The affected missions include LANL`s weapons research, development, and testing (WRD&T) program; special materials recovery; stockpile survelliance/evaluation; advanced fuels and heat sources development and production; and safe, secure storage of existing nuclear materials inventories. The problem is further exacerbated by LANL`s inability to ship any materials offsite because of the lack of receiver sites for material and regulatory issues. Correction of the current deficiencies and enhancement of the facility will provide centralized storage close to a nuclear materials processing facility. The project will enable long-term, cost-effective storage in a secure environment with reduced radiation exposure to workers, and eliminate potential exposures to the public. This report is organized according to the sections and subsections outlined by Attachment 111-2 of DOE Document AL 4700.1, Project Management System. It is organized into seven parts. This document, Part VI - Alternatives Study, presents a study of the different storage/containment options considered for NMSF.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Szanyi, Janos; Kwak, Ja Hun; Kim, Do Heui
2007-03-29
The effect of water on the morphology of BaO/Al2O3-based NOx storage materials was investigated using Fourier transform infrared spectroscopy, temperature programmed desorption, and time-resolved synchrotron X-ray diffraction techniques. The results of this multi-spectroscopy study reveal that, in the presence of water, surface Ba-nitrates convert to bulk nitrates, and water facilitates the formation of large Ba(NO3)2 particles. This process is completely reversible, i.e. after the removal of water from the storage material a significant fraction of the bulk nitrates re-convert to surface nitrates. NO2 exposure of a H2O-containing (wet) BaO/Al2O3 sample results in the formation of nitrites and bulk nitrates exclusively,more » i.e. no surface nitrates form. After further exposure to NO2, the nitrites completely convert to bulk nitrates. The amount of NOx taken up by the storage material is, however, essentially unaffected by the presence of water, regardless of whether the water was dosed prior to or after NO2 exposure. Based on the results of this study we are now able to explain most of the observations reported in the literature on the effect of water on NOx uptake on similar storage materials.« less
El Gabaly Marquez, Farid; Talin, Albert Alec
2018-04-17
Devices and methods for non-volatile analog data storage are described herein. In an exemplary embodiment, an analog memory device comprises a potential-carrier source layer, a barrier layer deposited on the source layer, and at least two storage layers deposited on the barrier layer. The memory device can be prepared to write and read data via application of a biasing voltage between the source layer and the storage layers, wherein the biasing voltage causes potential-carriers to migrate into the storage layers. After initialization, data can be written to the memory device by application of a voltage pulse between two storage layers that causes potential-carriers to migrate from one storage layer to another. A difference in concentration of potential carriers caused by migration of potential-carriers between the storage layers results in a voltage that can be measured in order to read the written data.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mammoli, Andrea A.; Lavrova, Olga; Arellano, Brian
The present invention is an apparatus and method for delivering energy using a renewable resource. The method includes providing a photovoltaic energy source and applying energy storage to the photovoltaic energy source via a battery storage unit. The energy output from the photovoltaic energy source and the battery system is controlled using a battery control system. The battery control system predicts peak load, develops a schedule that includes when to begin discharging power and when to stop discharging power, shifts power to the battery storage unit when excess power is available, and prioritizes the functionality of the battery storage unitmore » and the photovoltaic energy source.« less
Near-Infrared Imaging for Spatial Mapping of Organic Content in Petroleum Source Rocks
NASA Astrophysics Data System (ADS)
Mehmani, Y.; Burnham, A. K.; Vanden Berg, M. D.; Tchelepi, H.
2017-12-01
Natural gas from unconventional petroleum source rocks (shales) plays a key role in our transition towards sustainable low-carbon energy production. The potential for carbon storage (in adsorbed state) in these formations further aligns with efforts to mitigate climate change. Optimizing production and development from these resources requires knowledge of the hydro-thermo-mechanical properties of the rock, which are often strong functions of organic content. This work demonstrates the potential of near-infrared (NIR) spectral imaging in mapping the spatial distribution of organic content with O(100µm) resolution on cores that can span several hundred feet in depth (Mehmani et al., 2017). We validate our approach for the immature oil shale of the Green River Formation (GRF), USA, and show its applicability potential in other formations. The method is a generalization of a previously developed optical approach specialized to the GRF (Mehmani et al., 2016a). The implications of this work for spatial mapping of hydro-thermo-mechanical properties of excavated cores, in particular thermal conductivity, are discussed (Mehmani et al., 2016b). References:Mehmani, Y., A.K. Burnham, M.D. Vanden Berg, H. Tchelepi, "Quantification of organic content in shales via near-infrared imaging: Green River Formation." Fuel, (2017). Mehmani, Y., A.K. Burnham, M.D. Vanden Berg, F. Gelin, and H. Tchelepi. "Quantification of kerogen content in organic-rich shales from optical photographs." Fuel, (2016a). Mehmani, Y., A.K. Burnham, H. Tchelepi, "From optics to upscaled thermal conductivity: Green River oil shale." Fuel, (2016b).
Global scale groundwater flow model
NASA Astrophysics Data System (ADS)
Sutanudjaja, Edwin; de Graaf, Inge; van Beek, Ludovicus; Bierkens, Marc
2013-04-01
As the world's largest accessible source of freshwater, groundwater plays vital role in satisfying the basic needs of human society. It serves as a primary source of drinking water and supplies water for agricultural and industrial activities. During times of drought, groundwater sustains water flows in streams, rivers, lakes and wetlands, and thus supports ecosystem habitat and biodiversity, while its large natural storage provides a buffer against water shortages. Yet, the current generation of global scale hydrological models does not include a groundwater flow component that is a crucial part of the hydrological cycle and allows the simulation of groundwater head dynamics. In this study we present a steady-state MODFLOW (McDonald and Harbaugh, 1988) groundwater model on the global scale at 5 arc-minutes resolution. Aquifer schematization and properties of this groundwater model were developed from available global lithological model (e.g. Dürr et al., 2005; Gleeson et al., 2010; Hartmann and Moorsdorff, in press). We force the groundwtaer model with the output from the large-scale hydrological model PCR-GLOBWB (van Beek et al., 2011), specifically the long term net groundwater recharge and average surface water levels derived from routed channel discharge. We validated calculated groundwater heads and depths with available head observations, from different regions, including the North and South America and Western Europe. Our results show that it is feasible to build a relatively simple global scale groundwater model using existing information, and estimate water table depths within acceptable accuracy in many parts of the world.
NASA Astrophysics Data System (ADS)
Tatomir, Alexandru Bogdan A. C.; Sauter, Martin
2017-04-01
A number of theoretical approaches estimating the interfacial area between two fluid phases are available (Schaffer et al.,2013). Kinetic interface sensitive (KIS) tracers are used to describe the evolution of fluid-fluid interfaces advancing in two phase porous media systems (Tatomir et al., 2015). Initially developed to offer answers about the supercritical (sc)CO2 plume movement and the efficiency of trapping in geological carbon storage reservoirs, KIS tracers are tested in dynamic controlled laboratory conditions. N-octane and water, analogue to a scCO2 - brine system, are used. The KIS tracer is dissolved in n-octane, which is injected as the non-wetting phase in a fully water saturated porous media column. The porous system is made up of spherical glass beads with sizes of 100-250 μm. Subsequently, the KIS tracer follows a hydrolysis reaction over the n-octane - water interface resulting in an acid and phenol which are both water soluble. The fluid-fluid interfacial area is described numerically with the help of constitutive-relationships derived from the Brooks-Corey model. The specific interfacial area is determined numerically from pore scale calculations, or from different literature sources making use of pore network model calculations (Joekar-Niasar et al., 2008). This research describes the design of the laboratory setup and compares the break-through curves obtained with the forward model and in the laboratory experiment. Furthermore, first results are shown in the attempt to validate the immiscible two phase flow reactive transport numerical model with dynamic laboratory column experiments. Keywords: Fluid-fluid interfacial area, KIS tracers, model validation, CCS, geological storage of CO2
Chaudhuri, Santanu; Graetz, Jason; Ignatov, Alex; Reilly, James J; Muckerman, James T
2006-09-06
We report the results of an experimental and theoretical study of hydrogen storage in sodium alanate (NaAlH(4)). Reversible hydrogen storage in this material is dependent on the presence of 2-4% Ti dopant. Our combined study shows that the role of Ti may be linked entirely to Ti-containing active catalytic sites in the metallic Al phase present in the dehydrogenated NaAlH(4). The EXAFS data presented here show that dehydrogenated samples contain a highly disordered distribution of Ti-Al distances with no long-range order beyond the second coordination sphere. We have used density functional theory techniques to calculate the chemical potential of possible Ti arrangements on an Al(001) surface for Ti coverages ranging from 0.125 to 0.5 monolayer (ML) and have identified those that can chemisorb molecular hydrogen via spontaneous or only moderately activated pathways. The chemisorption process exhibits a characteristic nodal symmetry property for the low-barrier sites: the incipient doped surface-H(2) adduct's highest occupied molecular orbital (HOMO) incorporates the sigma antibonding molecular orbital of hydrogen, allowing the transfer of charge density from the surface to dissociate the molecular hydrogen. This work also proposes a plausible mechanism for the transport of an aluminum hydride species back into the NaH lattice that is supported by Car-Parrinello molecular dynamics (CPMD) simulations of the stability and mobility of aluminum clusters (alanes) on Al(001). As an experimental validation of the proposed role of titanium and the subsequent diffusion of alanes, we demonstrate experimentally that AlH(3) reacts with NaH to form NaAlH(4) without any requirement of a catalyst or hydrogen overpressure.
40 CFR Table 6 to Subpart G of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Group 1 Storage Vessels at New Sources.... 63, Subpt. G, Table 6 Table 6 to Subpart G of Part 63—Group 1 Storage Vessels at New Sources Vessel capacity(cubic meters) Vapor pressure a (kilopascals) 38 ≤ capacity<151 ≥13.1 151 ≤ capacity ≥0.7 a Maximum...
40 CFR Table 6 to Subpart G of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Group 1 Storage Vessels at New Sources.... 63, Subpt. G, Table 6 Table 6 to Subpart G of Part 63—Group 1 Storage Vessels at New Sources Vessel capacity(cubic meters) Vapor pressure a (kilopascals) 38 ≤ capacity<151 ≥13.1 151 ≤ capacity ≥0.7 a Maximum...
40 CFR Table 6 to Subpart G of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Group 1 Storage Vessels at New Sources.... 63, Subpt. G, Table 6 Table 6 to Subpart G of Part 63—Group 1 Storage Vessels at New Sources Vessel capacity(cubic meters) Vapor pressure a (kilopascals) 38 ≤ capacity<151 ≥13.1 151 ≤ capacity ≥0.7 a Maximum...
40 CFR Table 6 to Subpart G of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Group 1 Storage Vessels at New Sources.... 63, Subpt. G, Table 6 Table 6 to Subpart G of Part 63—Group 1 Storage Vessels at New Sources Vessel capacity(cubic meters) Vapor pressure a (kilopascals) 38 ≤ capacity<151 ≥13.1 151 ≤ capacity ≥0.7 a Maximum...
40 CFR Table 6 to Subpart G of... - Group 1 Storage Vessels at New Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Group 1 Storage Vessels at New Sources.... 63, Subpt. G, Table 6 Table 6 to Subpart G of Part 63—Group 1 Storage Vessels at New Sources Vessel capacity(cubic meters) Vapor pressure a (kilopascals) 38 ≤capacity<151 ≥13.1 151 ≤capacity ≥0.7 a Maximum...
Short x-ray pulse generation using deflecting cavities at the Advanced Photon Source.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sajaev, V.; Borland, M.; Chae, Y.-C.
2007-11-11
Storage-ring-based third-generation light sources can provide intense radiation pulses with durations as short as 100 ps. However, there is growing interest within the synchrotron radiation user community in performing experiments with much shorter X-ray pulses. Zholents et al. [Nucl. Instr. and Meth. A 425 (1999) 385] recently proposed using RF orbit deflection to generate sub-ps X-ray pulses. In this scheme, two deflecting cavities are used to deliver a longitudinally dependent vertical kick to the beam. An optical slit can then be used to slice out a short part of the radiation pulse. Implementation of this scheme is planned for onemore » APS beamline in the near future. In this paper, we summarize our feasibility study of this method and the expected X-ray beam parameters. We find that a pulse length of less than two picoseconds can be achieved.« less
Coastal aquifers: Scientific advances in the face of global environmental challenges
NASA Astrophysics Data System (ADS)
Post, Vincent E. A.; Werner, Adrian D.
2017-08-01
Coastal aquifers embody the subsurface transition between terrestrial and marine systems, and form the almost invisible pathway for tremendous volumes of freshwater that flow to the ocean. Changing conditions of the earth's landscapes and oceans can disrupt the fragile natural equilibrium between fresh and saltwater that exists in coastal zones. Among these, over-abstraction of groundwater is considered the leading man-made cause of seawater intrusion. Moreover, many of the world's largest urban settings, where sources of contamination are profuse, have been built over the freshwater in coastal aquifers. Thus, coastal aquifers are important receptors of human impacts to water on Earth (Michael et al., 2017). This Special Issue on 'Investigation and Management of Coastal Aquifers' contains current scientific advances on the topic, dealing with the storage and quality of water, affected by stressors ranging in scale from point source contamination to global climate change.
Evolution of Root Zone Storage after Land Use Change
NASA Astrophysics Data System (ADS)
Nijzink, R.; Hutton, C.; Capell, R.; Pechlivanidis, I.; Hrachowitz, M.; Savenije, H.
2015-12-01
It has been acknowledged for some time that a coupling exists between vegetation, climate and hydrological processes (e.g. Eagleson, 1982a, Rodriguez-Iturbe,2001 ). Recently, Gao et al.(2014) demonstrated that one of the core parameters of hydrological functioning, the catchment-scale root zone water storage capacity, can be estimated based on climate data alone. It was shown that ecosystems develop root zone storage capacities that allow vegetation to bridge droughts with return periods of about 20 years. As a consequence, assuming that the evaporative demand determines the root zone storage capacity, land use changes, such as deforestation, should have an effect on the development of this capacity . In this study it was tested to which extent deforestation affects root zone storage capacities. To do so, four different hydrological models were calibrated in a moving window approach after deforestation occurred. In this way, model based estimates of the storage capacity in time were obtained. This was compared with short term estimates of root zone storage capacities based on a climate based method similar to Gao et al.(2014). In addition, the equilibrium root zone storage capacity was determined with the total time series of an unaffected control catchment. Preliminary results indicate that models tend to adjust their storage capacity to the values found by the climate based method. This is strong evidence that the root zone storage is determined by the evaporative demand of vegetation. Besides, root zones storage capacities develop towards an equilibrium value where the ecosystem is in balance, further highlighting the evolving, time dynamic character of hydrological systems.
A one-dimensional diffusion model was used to investigate the effects of dense non-aqueous phase liquid (DNAPL) source zone dissolution and remediation on the storage and release of contaminants from aquitards. Source zone dissolution was represented by a power-law source depleti...
46 CFR 112.05-5 - Emergency power source.
Code of Federal Regulations, 2013 CFR
2013-10-01
... with § 112.05-1(c). Table 112.05-5(a) Size of vessel and service Type of emergency power source or... power source (automatically connected storage battery or an automatically started generator) 36 hours.1... power source (automatically connected storage battery or an automatically started generator) 8 hours or...
46 CFR 112.05-5 - Emergency power source.
Code of Federal Regulations, 2012 CFR
2012-10-01
... with § 112.05-1(c). Table 112.05-5(a) Size of vessel and service Type of emergency power source or... power source (automatically connected storage battery or an automatically started generator) 36 hours.1... power source (automatically connected storage battery or an automatically started generator) 8 hours or...
46 CFR 112.05-5 - Emergency power source.
Code of Federal Regulations, 2014 CFR
2014-10-01
... with § 112.05-1(c). Table 112.05-5(a) Size of vessel and service Type of emergency power source or... power source (automatically connected storage battery or an automatically started generator) 36 hours.1... power source (automatically connected storage battery or an automatically started generator) 8 hours or...
Wang, Lei; Wang, Dong; Dong, Xin Yi; Zhang, Zhi Jun; Pei, Xian Feng; Chen, Xin Jiang; Chen, Biao; Jin, Jian
2011-03-28
An innovative strategy of fabricating electrode material by layered assembling two kinds of one-atom-thick sheets, carboxylated graphene oxide (GO) and Co-Al layered double hydroxide nanosheet (Co-Al LDH-NS) for the application as a pseudocapacitor is reported. The Co-Al LDH-NS/GO composite exhibits good energy storage properties.
Destabilisation of complex hydrides through size effects.
Christian, Meganne; Aguey-Zinsou, Kondo-Francois
2010-12-01
Nanoparticles of NaAlH4, LiAlH4 and LiBH4 were prepared by encapsulating their respective hydrides within carbon nanotubes by a wet chemical approach. The resulting confinement had a profound effect on the overall hydrogen storage properties of these hydrides, with NaAlH4 and LiAlH4 releasing hydrogen from room temperature, for example.
Wei, Lei; Liu, Qi-Xuan; Zhu, Bao; Liu, Wen-Jun; Ding, Shi-Jin; Lu, Hong-Liang; Jiang, Anquan; Zhang, David Wei
2016-12-01
Highly powered electrostatic capacitors based on nanostructures with a high aspect ratio are becoming critical for advanced energy storage technology because of their high burst power and energy storage capability. We report the fabrication process and the electrical characteristics of high capacitance density capacitors with three-dimensional solid-state nanocapacitors based on a ZnO nanowire template. Stand-up ZnO nanowires are grown face down on p-type Si substrates coated with a ZnO seed layer using a hydrothermal method. Stacks of AlZnO/Al2O3/AlZnO are then deposited sequentially on the ZnO nanowires using atomic layer deposition. The fabricated capacitor has a high capacitance density up to 92 fF/μm(2) at 1 kHz (around ten times that of the planar capacitor without nanowires) and an extremely low leakage current density of 3.4 × 10(-8) A/cm(2) at 2 V for a 5-nm Al2O3 dielectric. Additionally, the charge-discharge characteristics of the capacitor were investigated, indicating that the resistance-capacitance time constants were 550 ns for both the charging and discharging processes and the time constant was not dependent on the voltage. This reflects good power characteristics of the fabricated capacitors. Therefore, the current work provides an exciting strategy to fabricate low-cost and easily processable, high capacitance density capacitors for energy storage.
Picosecond, tunable, high-brightness hard x-ray inverse Compton source at Duke storage ring
NASA Astrophysics Data System (ADS)
Litvinenko, Vladimir N.; Wu, Ying; Burnham, Bentley; Barnett, Genevieve A.; Madey, John M. J.
1995-09-01
We suggest a state-of-the art x-ray source using a compact electron storage ring with modest energy (less than 1 GeV) and a high power mm-wave as an undulator. A source of this type has x-ray energies and brightness comparable with third generation synchrotron light sources while it can be very compact and fit in a small university or industrial laboratory or hospital. We propose to operate an isochronous mm-wave FEL and a hard x-ray inverse Compton source at the Duke storage ring to test this concept. Resonant FEL conditions for the mm- wave will be provided by the off-axis interaction with an electromagnetic wave. A special optical resonator with holes for the e-beam is proposed for pumping a hard x-ray inverse Compton source with very high brightness. Simulation results of mm-wave FEL operation of the Duke storage ring are discussed. Expected performance of mm-wave FEL and hard x-ray inverse Compton source are presented.
10 CFR 34.21 - Limits on external radiation levels from storage containers and source changers.
Code of Federal Regulations, 2014 CFR
2014-01-01
... 10 Energy 1 2014-01-01 2014-01-01 false Limits on external radiation levels from storage... INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment § 34.21 Limits on external radiation levels from storage containers and source changers. The maximum...
10 CFR 34.21 - Limits on external radiation levels from storage containers and source changers.
Code of Federal Regulations, 2012 CFR
2012-01-01
... 10 Energy 1 2012-01-01 2012-01-01 false Limits on external radiation levels from storage... INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment § 34.21 Limits on external radiation levels from storage containers and source changers. The maximum...
10 CFR 34.21 - Limits on external radiation levels from storage containers and source changers.
Code of Federal Regulations, 2011 CFR
2011-01-01
... 10 Energy 1 2011-01-01 2011-01-01 false Limits on external radiation levels from storage... INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment § 34.21 Limits on external radiation levels from storage containers and source changers. The maximum...
10 CFR 34.21 - Limits on external radiation levels from storage containers and source changers.
Code of Federal Regulations, 2010 CFR
2010-01-01
... 10 Energy 1 2010-01-01 2010-01-01 false Limits on external radiation levels from storage... INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment § 34.21 Limits on external radiation levels from storage containers and source changers. The maximum...
10 CFR 34.21 - Limits on external radiation levels from storage containers and source changers.
Code of Federal Regulations, 2013 CFR
2013-01-01
... 10 Energy 1 2013-01-01 2013-01-01 false Limits on external radiation levels from storage... INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment § 34.21 Limits on external radiation levels from storage containers and source changers. The maximum...
Oblique view of front (east) and south sides of ammunition ...
Oblique view of front (east) and south sides of ammunition storage buildings 4403 and 4404, view towards the northwest without scale - Fort McClellan Ammunition Storage Area, Building No. 4403, Second Avenue (Magazine Road), Anniston, Calhoun County, AL
Interior planar view of doors to railroad platform at rear ...
Interior planar view of doors to railroad platform at rear of ammunition storage building 4403, view towards the west westside with scale - Fort McClellan Ammunition Storage Area, Building No. 4403, Second Avenue (Magazine Road), Anniston, Calhoun County, AL
Super-dry reforming of methane intensifies CO2 utilization via Le Chatelier's principle.
Buelens, Lukas C; Galvita, Vladimir V; Poelman, Hilde; Detavernier, Christophe; Marin, Guy B
2016-10-28
Efficient CO 2 transformation from a waste product to a carbon source for chemicals and fuels will require reaction conditions that effect its reduction. We developed a "super-dry" CH 4 reforming reaction for enhanced CO production from CH 4 and CO 2 We used Ni/MgAl 2 O 4 as a CH 4 -reforming catalyst, Fe 2 O 3 /MgAl 2 O 4 as a solid oxygen carrier, and CaO/Al 2 O 3 as a CO 2 sorbent. The isothermal coupling of these three different processes resulted in higher CO production as compared with that of conventional dry reforming, by avoiding back reactions with water. The reduction of iron oxide was intensified through CH 4 conversion to syngas over Ni and CO 2 extraction and storage as CaCO 3 CO 2 is then used for iron reoxidation and CO production, exploiting equilibrium shifts effected with inert gas sweeping (Le Chatelier's principle). Super-dry reforming uses up to three CO 2 molecules per CH 4 and offers a high CO space-time yield of 7.5 millimole CO per second per kilogram of iron at 1023 kelvin. Copyright © 2016, American Association for the Advancement of Science.
Attenuation of contaminants of coal pile leachate by interaction with subsoil
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ghuman, G.S.; Denham, M.E.
1996-09-01
Increased use of coal as energy source has resulted in its greater outdoor storage at electrical generation sites. Coal pile runoff (CPR) with its high concentrations of Fe, Al and sulfate leaches into subsoil and may adversely affect the quality of groundwater. During the summer, 1995, this study was conducted to determine the removal of CPR contaminants by subsoil around D-area electric plant at Savannah River Site (SRS). Groundwater samples from five monitoring wells were analyzed for physical and chemical parameters. Hydrolab Surveyor, TOC Analyzer, Dionex Ion Chromatograph and ICP-ES instruments were used for analysis. Results showed appreciable removal ofmore » CPR contaminants, sulfate, Fe, Al, Cr, Mn and Ni by the upper subsoil near the pile. The reductions in the concentrations of major contaminants in the distant wells relative to the near wells were from 12,947 to 1293 mg/L for sulfate, from 3.138 to 42 mg/L for Fe, and from 593 to 119 mg/L for Al. The study revealed the capacity of soil system to retain toxic elements of CPR leachate, which may lead to remedial actions.« less
Groundwater and Terrestrial Water Storage
NASA Technical Reports Server (NTRS)
Rodell, Matthew; Chambers, Don P.; Famiglietti, James S.
2014-01-01
Terrestrial water storage (TWS) comprises groundwater, soil moisture, surface water, snow,and ice. Groundwater typically varies more slowly than the other TWS components because itis not in direct contact with the atmosphere, but often it has a larger range of variability onmultiannual timescales (Rodell and Famiglietti, 2001; Alley et al., 2002). In situ groundwaterdata are only archived and made available by a few countries. However, monthly TWSvariations observed by the Gravity Recovery and Climate Experiment (GRACE; Tapley et al.,2004) satellite mission, which launched in 2002, are a reasonable proxy for unconfinedgroundwater at climatic scales.
40 CFR Table 3 to Subpart Ppp of... - Group 1 Storage Vessels at Existing and New Affected Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 12 2014-07-01 2014-07-01 false Group 1 Storage Vessels at Existing...—Group 1 Storage Vessels at Existing and New Affected Sources Vessel capacity(cubic meters) Vapor Pressure a (kilopascals) 75 ≤capacity pressure of total...
40 CFR Table 3 to Subpart Ppp of... - Group 1 Storage Vessels at Existing and New Affected Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Group 1 Storage Vessels at Existing...—Group 1 Storage Vessels at Existing and New Affected Sources Vessel capacity(cubic meters) Vapor Pressure a (kilopascals) 75 ≤ capacity pressure of...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Szanyi,J.; Kwak, J.; Kim, D.
2007-01-01
The effect of water on the morphology of BaO/Al{sub 2}O{sub 3}-based NO{sub x} storage materials was investigated using Fourier transform infrared spectroscopy, temperature programmed desorption, and time-resolved synchrotron X-ray diffraction techniques. The results of this multispectroscopy study reveal that in the presence of water surface Ba-nitrates convert to bulk nitrates and water facilitates the formation of large Ba(NO{sub 3}){sub 2} particles. The conversion of surface to bulk Ba-nitrates is completely reversible (i.e., after the removal of water from the storage material a significant fraction of the bulk nitrates reconverts to surface nitrates). NO{sub 2} exposure of a H{sub 2}O-containing (wet)more » BaO/Al{sub 2}O{sub 3} sample results in the formation of nitrites and bulk nitrates exclusively (i.e., no surface nitrates form). After further exposure to NO{sub 2}, the nitrites completely convert to bulk nitrates. The amount of NO{sub x} taken up by the storage material, however, is essentially unaffected by the presence of water regardless of whether the water was dosed prior to or after NO{sub 2} exposure. On the basis of the results of this study, we are now able to explain most of the observations reported in the literature on the effect of water on NO{sub x} uptake on similar storage materials.« less
Large energy storage efficiency of the dielectric layer of graphene nanocapacitors.
Bezryadin, A; Belkin, A; Ilin, E; Pak, M; Colla, Eugene V; Hubler, A
2017-12-08
Electric capacitors are commonly used in electronic circuits for the short-term storage of small amounts of energy. It is desirable however to use capacitors to store much larger energy amounts to replace rechargeable batteries. Unfortunately existing capacitors cannot store sufficient energy to be able to replace common electrochemical energy storage systems. Here we examine the energy storage capabilities of graphene nanocapacitors, which are tri-layer devices involving an Al film, Al 2 O 3 dielectric layer, and a single layer of carbon atoms, i.e., graphene. This is a purely electronic capacitor and therefore it can function in a wide temperature interval. The capacitor shows a high dielectric breakdown electric field strength, of the order of 1000 kV mm -1 (i.e., 1 GV m -1 ), which is much larger than the table value of the Al 2 O 3 dielectric strength. The corresponding energy density is 10-100 times larger than the energy density of a common electrolytic capacitor. Moreover, we discover that the amount of charge stored in the dielectric layer can be equal or can even exceed the amount of charge stored on the capacitor plates. The dielectric discharge current follows a power-law time dependence. We suggest a model to explain this behavior.
Large energy storage efficiency of the dielectric layer of graphene nanocapacitors
NASA Astrophysics Data System (ADS)
Bezryadin, A.; Belkin, A.; Ilin, E.; Pak, M.; Colla, Eugene V.; Hubler, A.
2017-12-01
Electric capacitors are commonly used in electronic circuits for the short-term storage of small amounts of energy. It is desirable however to use capacitors to store much larger energy amounts to replace rechargeable batteries. Unfortunately existing capacitors cannot store sufficient energy to be able to replace common electrochemical energy storage systems. Here we examine the energy storage capabilities of graphene nanocapacitors, which are tri-layer devices involving an Al film, Al2O3 dielectric layer, and a single layer of carbon atoms, i.e., graphene. This is a purely electronic capacitor and therefore it can function in a wide temperature interval. The capacitor shows a high dielectric breakdown electric field strength, of the order of 1000 kV mm-1 (i.e., 1 GV m-1), which is much larger than the table value of the Al2O3 dielectric strength. The corresponding energy density is 10-100 times larger than the energy density of a common electrolytic capacitor. Moreover, we discover that the amount of charge stored in the dielectric layer can be equal or can even exceed the amount of charge stored on the capacitor plates. The dielectric discharge current follows a power-law time dependence. We suggest a model to explain this behavior.
Aluminum elution and precipitation in glass vials: effect of pH and buffer species.
Ogawa, Toru; Miyajima, Makoto; Wakiyama, Naoki; Terada, Katsuhide
2015-02-01
Inorganic extractables from glass vials may cause particle formation in the drug solution. In this study, the ability of eluting Al ion from borosilicate glass vials, and tendencies of precipitation containing Al were investigated using various pHs of phosphate, citrate, acetate and histidine buffer. Through heating, all of the buffers showed that Si and Al were eluted from glass vials in ratios almost the same as the composition of borosilicate glass, and the amounts of Al and Si from various buffer solutions at pH 7 were in the following order: citrate > phosphate > acetate > histidine. In addition, during storage after heating, the Al concentration at certain pHs of phosphate and acetate buffer solution decreased, suggesting the formation of particles containing Al. In citrate buffer, Al did not decrease in spite of the high elution amount. Considering that the solubility profile of aluminum oxide and the Al eluting profile of borosilicate glass were different, it is speculated that Al ion may be forced to leach into the buffer solution according to Si elution on the surface of glass vials. When Al ions were added to the buffer solutions, phosphate, acetate and histidine buffer showed a decrease of Al concentration during storage at a neutral range of pHs, indicating the formation of particles containing Al. In conclusion, it is suggested that phosphate buffer solution has higher possibility of forming particles containing Al than other buffer solutions.
Thomas A. Buscheck
2015-06-01
This data submission is for Phase 2 of Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations, which focuses on multi-fluid (CO2 and brine) geothermal energy production and diurnal bulk energy storage in geologic settings that are suitable for geologic CO2 storage. This data submission includes all data used in the Geosphere Journal article by Buscheck et al (2016). All assumptions are discussed in that article.
Metal Hydride Heat Storage Technology for Directed Energy Weapon Systems
2007-11-16
high thermal conductivity materials for heat transfer enhancement. In addition, the PCMs ’ low heat storage density requires excessively large system...capacity as compared to the PCMs . For example, Ca0.2M0.8Ni5, a commercial hydride, has a heat storage density of 853.3MJ/m³ in raw material condition...Huston and Sandrock, 1980], while paraffin (Calwax 130), a common organic PCM has a heat storage capacity of 177.5MJ/m³ [Al-Hallaj and Selman, 2000]. The
NASA Astrophysics Data System (ADS)
Becker, V.; Myrttinen, A.; Mayer, B.; Barth, J. A.
2012-12-01
Stable carbon isotope ratios (δ13C) are a powerful tool for inferring carbon sources and mixing ratios of injected and baseline CO2 in storage reservoirs. Furthermore, CO2 releasing and consuming processes can be deduced if the isotopic compositions of end-members are known. At low CO2 pressures (pCO2), oxygen isotope ratios (δ18O) of CO2 usually assume the δ18O of the water plus a temperature-dependent isotope fractionation factor. However, at very high CO2 pressures as they occur in CO2 storage reservoirs, the δ18O of the injected CO2 may in fact change the δ18O of the reservoir brine. Hence, changing δ18O of brine constitutes an additional tracer for reservoir-internal carbon dynamics and allows the determination of the amount of free phase CO2 present in the reservoir (Johnson et al. 2011). Further systematic research to quantify carbon and oxygen isotope fractionation between the involved inorganic carbon species (CO2, H2CO3, HCO3-, CO32-, carbonate minerals) and kinetic and equilibrium isotope effects during gas-water-rock interactions is necessary because p/T conditions and salinities in CO2 storage reservoirs may exceed the boundary conditions of typical environmental isotope applications, thereby limiting the accuracy of stable isotope monitoring approaches in deep saline formations (Becker et al. 2011). In doing so, it is crucial to compare isotopic patterns observed in laboratory experiments with artificial brines to similar experiments with original fluids from representative field sites to account for reactions of dissolved inorganic carbon (DIC) with minor brine components. In the CO2ISO-LABEL project, funded by the German Ministry for Education and Research, multiple series of laboratory experiments are conducted to determine the influence of pressure, temperature and brine composition on the δ13C of DIC and the δ18O of brines in water-CO2-rock reactions with special focus placed on kinetics and stable oxygen and carbon isotope fractionation factors. Laboratory experiments with original reservoir fluids from CO2 storage reservoirs in Canada using supercritical fluid extraction reactors are being conducted at temperatures of up to 200 °C and CO2 pressures of up to 20 MPa. Preliminary results show that equilibration times for δ18O in high saline waters increase by an order of magnitude compared to fresh water, with exact times depending on CO2 partial pressure, stirring and the contact area between the phases. References Becker, V. et al., 2011. Predicting δ13CDIC dynamics in CCS: A scheme based on a review of inorganic carbon chemistry under elevated pressures and temperatures. International Journal of Greenhouse Gas Control, 5, pp.1250-1258. Johnson, G. et al., 2011. Using oxygen isotope ratios to quantitatively assess trapping mechanisms during CO2 injection into geological reservoirs: The Pembina case study. Chemical Geology, 283(3-4), pp.185-193.
Microbial Source Module (MSM): Documenting the Science ...
The Microbial Source Module (MSM) estimates microbial loading rates to land surfaces from non-point sources, and to streams from point sources for each subwatershed within a watershed. A subwatershed, the smallest modeling unit, represents the common basis for information consumed and produced by the MSM which is based on the HSPF (Bicknell et al., 1997) Bacterial Indicator Tool (EPA, 2013b, 2013c). Non-point sources include numbers, locations, and shedding rates of domestic agricultural animals (dairy and beef cows, swine, poultry, etc.) and wildlife (deer, duck, raccoon, etc.). Monthly maximum microbial storage and accumulation rates on the land surface, adjusted for die-off, are computed over an entire season for four land-use types (cropland, pasture, forest, and urbanized/mixed-use) for each subwatershed. Monthly point source microbial loadings to instream locations (i.e., stream segments that drain individual sub-watersheds) are combined and determined for septic systems, direct instream shedding by cattle, and POTWs/WWTPs (Publicly Owned Treatment Works/Wastewater Treatment Plants). The MSM functions within a larger modeling system that characterizes human-health risk resulting from ingestion of water contaminated with pathogens. The loading estimates produced by the MSM are input to the HSPF model that simulates flow and microbial fate/transport within a watershed. Microbial counts within recreational waters are then input to the MRA-IT model (Soller et
Energy Storage Requirements & Challenges for Ground Vehicles
2010-03-18
Titinate Evaluation Cell Evaluation Battery Aging Phenomenon Battery SOC/SOH Determination Modeling ARM 100 LiIon APU Lion Cell Evaluation Cell...Advanced Batteries Fuels Th er m al Ma na ge m en t Radiators Heat Recovery Thermal Interface Materials Phase Change Cooling Advanced Electronics...in all energy storage Energy Storage Team Mission Battery Technology Evaluation Lab Module Test & Eval Cell Test & Eval 6UNCLASSIFIED Pacing Vehicle
Vacancy-mediated dehydrogenation of sodium alanate
Gunaydin, Hakan; Houk, Kendall N.; Ozoliņš, Vidvuds
2008-01-01
Clarification of the mechanisms of hydrogen release and uptake in transition-metal-doped sodium alanate, NaAlH4, a prototypical high-density complex hydride, has fundamental importance for the development of improved hydrogen-storage materials. In this and most other modern hydrogen-storage materials, H2 release and uptake are accompanied by long-range diffusion of metal species. Using first-principles density-functional theory calculations, we have determined that the activation energy for Al mass transport via AlH3 vacancies is Q = 85 kJ/mol·H2, which is in excellent agreement with experimentally measured activation energies in Ti-catalyzed NaAlH4. The activation energy for an alternate decomposition mechanism via NaH vacancies is found to be significantly higher: Q = 112 kJ/mol·H2. Our results suggest that bulk diffusion of Al species is the rate-limiting step in the dehydrogenation of Ti-doped samples of NaAlH4 and that the much higher activation energies measured for uncatalyzed samples are controlled by other processes, such as breaking up of AlH4− complexes, formation/dissociation of H2 molecules, and/or nucleation of the product phases. PMID:18299582
Total x-ray power measurements in the Sandia LIGA program.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Malinowski, Michael E.; Ting, Aili
2005-08-01
Total X-ray power measurements using aluminum block calorimetry and other techniques were made at LIGA X-ray scanner synchrotron beamlines located at both the Advanced Light Source (ALS) and the Advanced Photon Source (APS). This block calorimetry work was initially performed on the LIGA beamline 3.3.1 of the ALS to provide experimental checks of predictions of the LEX-D (LIGA Exposure- Development) code for LIGA X-ray exposures, version 7.56, the version of the code in use at the time calorimetry was done. These experiments showed that it was necessary to use bend magnet field strengths and electron storage ring energies different frommore » the default values originally in the code in order to obtain good agreement between experiment and theory. The results indicated that agreement between LEX-D predictions and experiment could be as good as 5% only if (1) more accurate values of the ring energies, (2) local values of the magnet field at the beamline source point, and (3) the NIST database for X-ray/materials interactions were used as code inputs. These local magnetic field value and accurate ring energies, together with NIST database, are now defaults in the newest release of LEX-D, version 7.61. Three dimensional simulations of the temperature distributions in the aluminum calorimeter block for a typical ALS power measurement were made with the ABAQUS code and found to be in good agreement with the experimental temperature data. As an application of the block calorimetry technique, the X-ray power exiting the mirror in place at a LIGA scanner located at the APS beamline 10 BM was measured with a calorimeter similar to the one used at the ALS. The overall results at the APS demonstrated the utility of calorimetry in helping to characterize the total X-ray power in LIGA beamlines. In addition to the block calorimetry work at the ALS and APS, a preliminary comparison of the use of heat flux sensors, photodiodes and modified beam calorimeters as total X-ray power monitors was made at the ALS, beamline 3.3.1. This work showed that a modification of a commercially available, heat flux sensor could result in a simple, direct reading beam power meter that could be a useful for monitoring total X-ray power in Sandia's LIGA exposure stations at the ALS, APS and Stanford Synchrotron Radiation Laboratory (SSRL).« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Raman, Santhanam; Xi, Xiaomei; Ye, Xiang-Rong
A method of pre-doping an anode of an energy storage device can include immersing the anode and a dopant source in an electrolyte, and coupling a substantially constant current between the anode and the dopant source. A method of pre-doping an anode of an energy storage device can include immersing the anode and a dopant source in an electrolyte, and coupling a substantially constant voltage across the anode and the dopant source. An energy storage device can include an anode having a lithium ion pre-doping level of about 60% to about 90%.
King, Stagg; Harden, Jennifer; Manies, Kristen L.; Munster, Jennie; White, L. Douglas
2002-01-01
Soils in Alaska, and in high latitude terrestrial ecosystems in general, contain significant amounts of organic carbon, most of which is believed to have accumulated since the start of the Holocene about 10 ky before present. High latitude soils are estimated to contain 30-40% of terrestrial soil carbon (Melillo et al., 1995; McGuire and Hobbie, 1997), or ~ 300-400 Gt C (Gt = 1015 g), which equals about half of the current atmospheric burden of carbon. Boreal forests in particular are estimated to have more soil carbon than any other terrestrial biome (Post et al., 1982; Chapin and Matthews, 1993). The relations among net primary production, soil carbon storage, recurrent fire disturbance, nutrients, the hydrologic cycle, permafrost and geomorphology are poorly understood in boreal forest. Fire disturbance has been suggested to play a key role in the interactions among the complex biogeochemical processes influencing carbon storage in boreal forest soils (Harden et al., 2000; Zhuang et al., 2002). There has been an observed increase in fire disturbance in North American boreal black spruce (Picea mariana) forests in recent decades (Murphy et al., 1999; Kasichke et al., 2000), concurrent with increases in Alaskan boreal and arctic surface temperatures and warming of permafrost (Osterkamp and Romanofsky, 1999). Understanding the role of fire in long term carbon storage and how recent changes in fire frequency and severity may influence future high latitude soil carbon pools is necessary for those working to understand or mitigate the effects of global climate change.
NASA Astrophysics Data System (ADS)
Janzen, Meghan S.; Galindo-Uribarri, Alfredo; Liu, Yuan; Mills, Gerald D.; Romero-Romero, Elisa; Stracener, Daniel W.
2015-10-01
We present results and discuss the use of aluminum nitride as a promising source material for Accelerator Mass Spectrometry (AMS) and Radioactive Ion Beams (RIBs) science applications of 26Al isotopes. The measurement of 26Al in geological samples by AMS is typically conducted on Al2O3 targets. However, Al2O3 is not an ideal source material because it does not form a prolific beam of Al- required for measuring low-levels of 26Al. Multiple samples of aluminum oxide (Al2O3), aluminum nitride (AlN), mixed Al2O3-AlN as well as aluminum fluoride (AlF3) were tested and compared using the ion source test facility and the stable ion beam (SIB) injector platform at the 25-MV tandem electrostatic accelerator at Oak Ridge National Laboratory. Negative ion currents of atomic and molecular aluminum were examined for each source material. It was found that pure AlN targets produced substantially higher beam currents than the other materials and that there was some dependence on the exposure of AlN to air. The applicability of using AlN as a source material for geological samples was explored by preparing quartz samples as Al2O3 and converting them to AlN using a carbothermal reduction technique, which involved reducing the Al2O3 with graphite powder at 1600 °C within a nitrogen atmosphere. The quartz material was successfully converted to AlN. Thus far, AlN proves to be a promising source material and could lead towards increasing the sensitivity of low-level 26Al AMS measurements. The potential of using AlN as a source material for nuclear physics is also very promising by placing 26AlN directly into a source to produce more intense radioactive beams of 26Al.
Janzen, Meghan S.; Galindo-Uribarri, Alfredo; Liu, Yuan; ...
2015-06-29
In this paper, we present results and discuss the use of aluminum nitride as a promising source material for Accelerator Mass Spectrometry (AMS) and Radioactive Ion Beams (RIBs) science applications of 26Al isotopes. The measurement of 26Al in geological samples by AMS is typically conducted on Al 2O 3 targets. However, Al 2O 3 is not an ideal source material because it does not form a prolific beam of Al - required for measuring low-levels of 26Al. Multiple samples of aluminum oxide (Al 2O 3), aluminum nitride (AlN), mixed Al 2O 3–AlN as well as aluminum fluoride (AlF 3) weremore » tested and compared using the ion source test facility and the stable ion beam (SIB) injector platform at the 25-MV tandem electrostatic accelerator at Oak Ridge National Laboratory. Negative ion currents of atomic and molecular aluminum were examined for each source material. It was found that pure AlN targets produced substantially higher beam currents than the other materials and that there was some dependence on the exposure of AlN to air. The applicability of using AlN as a source material for geological samples was explored by preparing quartz samples as Al 2O 3 and converting them to AlN using a carbothermal reduction technique, which involved reducing the Al 2O 3 with graphite powder at 1600°C within a nitrogen atmosphere. The quartz material was successfully converted to AlN. Thus far, AlN proves to be a promising source material and could lead towards increasing the sensitivity of low-level 26Al AMS measurements. In conclusion, the potential of using AlN as a source material for nuclear physics is also very promising by placing 26AlN directly into a source to produce more intense radioactive beams of 26Al.« less
Multiple layer optical memory system using second-harmonic-generation readout
Boyd, Gary T.; Shen, Yuen-Ron
1989-01-01
A novel optical read and write information storage system is described which comprises a radiation source such as a laser for writing and illumination, the radiation source being capable of radiating a preselected first frequency; a storage medium including at least one layer of material for receiving radiation from the radiation source and capable of being surface modified in response to said radiation source when operated in a writing mode and capable of generating a pattern of radiation of the second harmonic of the preselected frequency when illuminated by the radiation source at the preselected frequency corresponding to the surface modifications on the storage medium; and a detector to receive the pattern of second harmonic frequency generated.
Dehydriding properties of Ti or/and Zr-doped sodium aluminum hydride prepared by ball-milling
NASA Astrophysics Data System (ADS)
Xiao, Xue-Zhang; Chen, Li-Xin; Wang, Xin-Hua; Li, Shou-Quan; Hang, Zhou-Ming; Chen, Chang-Pin; Wang, Qi-Dong
2007-12-01
The NaAlH4 complex is attracting great attention for its potential applications in hydrogen-powered fuel-cell vehicles due to its high hydrogen storage capacity and suitable thermodynamic properties. However, its practicable hydrogen storage capacity presently obtained is less than the theoretical capacity (5.6 wt.%). To improve the hydrogen capacity, we chose metallic Ti or/and Zr powder as catalyst dopants, and prepared the sodium aluminum hydride by hydrogenation of ball-milled NaH/Al mixture containing 10 mol% dopants with different proportions of Ti and Zr, and then investigated the effects on their hydrogen storage (dehydriding) properties. The results showed that different catalyst dopants affected the dehydriding properties greatly. The catalysis of metal Ti as a catalyst dopant alone on dehydriding kinetics for the entire dehydrogenation process of ball-milled (NaH/Al) composite was higher than that of adopting Zr alone. The synergistic catalytic effect of Ti and Zr together as co-dopants on the dehydrogenation process of (NaH/Al) composite was higher than that using only Ti or Zr as dopant individually. The composite doped with proper proportion of Ti and Zr together (8 mol% Ti+ 2 mol% Zr) as co-dopants exhibited the highest dehydriding kinetic property and desorption capacity.
Modelling challenges for battery materials and electrical energy storage
NASA Astrophysics Data System (ADS)
Muller, Richard P.; Schultz, Peter A.
2013-10-01
Many vital requirements in world-wide energy production, from the electrification of transportation to better utilization of renewable energy production, depend on developing economical, reliable batteries with improved performance characteristics. Batteries reduce the need for gasoline and liquid hydrocarbons in an electrified transportation fleet, but need to be lighter, longer-lived and have higher energy densities, without sacrificing safety. Lighter and higher-capacity batteries make portable electronics more convenient. Less expensive electrical storage accelerates the introduction of renewable energy to electrical grids by buffering intermittent generation from solar or wind. Meeting these needs will probably require dramatic changes in the materials and chemistry used by batteries for electrical energy storage. New simulation capabilities, in both methods and computational resources, promise to fundamentally accelerate and advance the development of improved materials for electric energy storage. To fulfil this promise significant challenges remain, both in accurate simulations at various relevant length scales and in the integration of relevant information across multiple length scales. This focus section of Modelling and Simulation in Materials Science and Engineering surveys the challenges of modelling for energy storage, describes recent successes, identifies remaining challenges, considers various approaches to surmount these challenges and discusses the potential of these methods for future battery development. Zhang et al begin with atoms and electrons, with a review of first-principles studies of the lithiation of silicon electrodes, and then Fan et al examine the development and use of interatomic potentials to the study the mechanical properties of lithiated silicon in larger atomistic simulations. Marrocchelli et al study ionic conduction, an important aspect of lithium-ion battery performance, simulated by molecular dynamics. Emerging high-throughput methods allow rapid screening of promising new candidates for battery materials, illustrated for Li-ion olivine phosphates by Hajiyani et al . This collection includes descriptions of new techniques to model the chemistry at an electrode-electrolyte interface; Gunceler et al demonstrate coupling an electronic description of the electrode chemistry with the fluid electrolyte in a joint density functional theory method. Bridging to longer length scales to probe mechanical properties and transport, Preiss et al present a proof-of-concept phase field approach for a permeation model at an electrochemical interface, An and Jiang examine finite element simulations for transient deformation and transport in electrodes, and Haftabaradaran et al study the application of an analytical model to investigate the critical thickness for fracture in thick film electrodes. The focus section concludes with a study by Chung et al which combines modelling and experiment, examining the validity of the Bruggeman relation for porous electrodes. All of the papers were peer-reviewed following the standard procedure established by the Editorial Board of Modelling and Simulation in Materials Science and Engineering .
Integrating new Storage Technologies into EOS
NASA Astrophysics Data System (ADS)
Peters, Andreas J.; van der Ster, Dan C.; Rocha, Joaquim; Lensing, Paul
2015-12-01
The EOS[1] storage software was designed to cover CERN disk-only storage use cases in the medium-term trading scalability against latency. To cover and prepare for long-term requirements the CERN IT data and storage services group (DSS) is actively conducting R&D and open source contributions to experiment with a next generation storage software based on CEPH[3] and ethernet enabled disk drives. CEPH provides a scale-out object storage system RADOS and additionally various optional high-level services like S3 gateway, RADOS block devices and a POSIX compliant file system CephFS. The acquisition of CEPH by Redhat underlines the promising role of CEPH as the open source storage platform of the future. CERN IT is running a CEPH service in the context of OpenStack on a moderate scale of 1 PB replicated storage. Building a 100+PB storage system based on CEPH will require software and hardware tuning. It is of capital importance to demonstrate the feasibility and possibly iron out bottlenecks and blocking issues beforehand. The main idea behind this R&D is to leverage and contribute to existing building blocks in the CEPH storage stack and implement a few CERN specific requirements in a thin, customisable storage layer. A second research topic is the integration of ethernet enabled disks. This paper introduces various ongoing open source developments, their status and applicability.
Comparing models of seasonal deformation to horizontal and vertical PBO GPS data
NASA Astrophysics Data System (ADS)
Bartlow, N. M.; Fialko, Y. A.; van Dam, T. M.
2015-12-01
GPS monuments around the world exhibit seasonal displacements in both the horizontal and vertical direction with amplitudes on the order of centimeters. For analysis of tectonic signals, researchers typically fit and remove a sine function with an annual period, and sometimes an additional sine function with a semiannual period. As interest grows in analyzing small-amplitude, long-period deformation signals it becomes more important to accurately correct for seasonal variations. It is well established that the vertical component of seasonal GPS signals is largely due to continental water storage cycles (e.g. van Dam et al., GRL, 2001). Other recognized sources of seasonal loading include atmospheric pressure loading and oceanic loading due to non-steric changes in ocean height (e.g. van Dam et al., J. Geodesy, 2012). Here we attempt to build a complete physical model of seasonal loading by considering all of these sources (continental water storage, atmospheric pressure, and oceanic loading) and comparing our model to horizontal and vertical GPS data in the Western US. Atmospheric loading effects are computed from the National Center for Environmental Prediction 6-hourly global reanalysis surface pressure fields; the terrestrial water loading and ocean loading models are generated using SPOTL (Some Programs for Ocean Tide Loading; Agnew, SIO Technical Report, 2012) and parameters from NASA's Land Data Assimilation Systems and the Estimating the Circulation and Climate of the Ocean model, version 4. We find that with a few exceptions, our seasonal loading model predicts the correct phases but underestimates the amplitudes of vertical seasonal loads, and is a generally poor fit to the observed horizontal seasonal signals. This implies that our understanding of the driving mechanisms behind seasonal variations in the GPS data is still incomplete and needs to be improved before physics-based models can be used as an effective correction tool for the GPS timeseries.
Proposed BioRepository platform solution for the ALS research community.
Sherman, Alex; Bowser, Robert; Grasso, Daniela; Power, Breen; Milligan, Carol; Jaffa, Matthew; Cudkowicz, Merit
2011-01-01
ALS is a rare disorder whose cause and pathogenesis is largely unknown ( 1 ). There is a recognized need to develop biomarkers for ALS to better understand the disease, expedite diagnosis and to facilitate therapy development. Collaboration is essential to obtain a sufficient number of samples to allow statistically meaningful studies. The availability of high quality biological specimens for research purposes requires the development of standardized methods for collection, long-term storage, retrieval and distribution of specimens. The value of biological samples to scientists and clinicians correlates with the completeness and relevance of phenotypical and clinical information associated with the samples ( 2 , 3 ). While developing a secure Web-based system to manage an inventory of multi-site BioRepositories, algorithms were implemented to facilitate ad hoc parametric searches across heterogeneous data sources that contain data from clinical trials and research studies. A flexible schema for a barcode label was introduced to allow association of samples to these data. The ALSBank™ BioRepository platform solution for managing biological samples and associated data is currently deployed by the Northeast ALS Consortium (NEALS). The NEALS Consortium and the Massachusetts General Hospital (MGH) Neurology Clinical Trials Unit (NCTU) support a network of multiple BioBanks, thus allowing researchers to take advantage of a larger specimen collection than they might have at an individual institution. Standard operating procedures are utilized at all collection sites to promote common practices for biological sample integrity, quality control and associated clinical data. Utilizing this platform, we have created one of the largest virtual collections of ALS-related specimens available to investigators studying ALS.
46 CFR 112.05-5 - Emergency power source.
Code of Federal Regulations, 2011 CFR
2011-10-01
... generator must be either a diesel engine or a gas turbine. [CGD 74-125A, 47 FR 15267, Apr. 8, 1982, as... power source (automatically connected storage battery or an automatically started generator) 36 hours.1... power source (automatically connected storage battery or an automatically started generator) 8 hours or...
46 CFR 112.05-5 - Emergency power source.
Code of Federal Regulations, 2010 CFR
2010-10-01
... generator must be either a diesel engine or a gas turbine. [CGD 74-125A, 47 FR 15267, Apr. 8, 1982, as... power source (automatically connected storage battery or an automatically started generator) 36 hours.1... power source (automatically connected storage battery or an automatically started generator) 8 hours or...
Chemical bridges for enhancing hydrogen storage by spillover and methods for forming the same
Yang, Ralph T.; Li, Yingwei; Qi, Gongshin; Lachawiec, Jr., Anthony J.
2012-12-25
A composition for hydrogen storage includes a source of hydrogen atoms, a receptor, and a chemical bridge formed between the source and the receptor. The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.
Bayesian analysis of energy and count rate data for detection of low count rate radioactive sources.
Klumpp, John; Brandl, Alexander
2015-03-01
A particle counting and detection system is proposed that searches for elevated count rates in multiple energy regions simultaneously. The system analyzes time-interval data (e.g., time between counts), as this was shown to be a more sensitive technique for detecting low count rate sources compared to analyzing counts per unit interval (Luo et al. 2013). Two distinct versions of the detection system are developed. The first is intended for situations in which the sample is fixed and can be measured for an unlimited amount of time. The second version is intended to detect sources that are physically moving relative to the detector, such as a truck moving past a fixed roadside detector or a waste storage facility under an airplane. In both cases, the detection system is expected to be active indefinitely; i.e., it is an online detection system. Both versions of the multi-energy detection systems are compared to their respective gross count rate detection systems in terms of Type I and Type II error rates and sensitivity.
NASA Technical Reports Server (NTRS)
Savin, D. W.; Gwinner, G.; Schwalm, D.; Wolf, A.; Mueller, A.; Schippers, S.
2002-01-01
Low temperature dielectronic recombination (DR) is the dominant recombination mechanism for most ions in X-ray photoionized cosmic plasmas. Reliably modeling and interpreting spectra from these plasmas requires accurate low temperature DR rate Coefficients. Of particular importance are the DR rate coefficients for the iron L-shell ions (Fe XVII-Fe XXIV). These ions are predicted to play an important role in determining the thermal structure and line emission of X-ray photoionized plasmas, which form in the media surrounding accretion powered sources such as X-ray binaries (XRBs), active galactic nuclei (AGN), and cataclysmic variables (Savin et al., 2000). The need for reliable DR data of iron L-shell ions has become particularly urgent after the launches of Chandra and XMM-Newton. These satellites are now providing high-resolution X-ray spectra from a wide range of X-ray photoionized sources. Interpreting the spectra from these sources requires reliable DR rate coefficients. However, at the temperatures relevant, for X-ray photoionized plasmas, existing theoretical DR rate coefficients can differ from one another by factors of two to orders of magnitudes.
Li, Xiaoying; Voss, Paul L; Chen, Jun; Sharping, Jay E; Kumar, Prem
2005-05-15
We demonstrate storage of polarization-entangled photons for 125 micros, a record storage time to date, in a 25-km-long fiber spool, using a telecommunications-band fiber-based source of entanglement. With this source we also demonstrate distribution of polarization entanglement over 50 km by separating the two photons of an entangled pair and transmitting them individually over separate 25-km fibers. The measured two-photon fringe visibilities were 82% in the storage experiment and 86% in the distribution experiment. Preservation of polarization entanglement over such long-distance transmission demonstrates the viability of all-fiber sources for use in quantum memories and quantum logic gates.
Physics issues in diffraction limited storage ring design
NASA Astrophysics Data System (ADS)
Fan, Wei; Bai, ZhengHe; Gao, WeiWei; Feng, GuangYao; Li, WeiMin; Wang, Lin; He, DuoHui
2012-05-01
Diffraction limited electron storage ring is considered a promising candidate for future light sources, whose main characteristics are higher brilliance, better transverse coherence and better stability. The challenge of diffraction limited storage ring design is how to achieve the ultra low beam emittance with acceptable nonlinear performance. Effective linear and nonlinear parameter optimization methods based on Artificial Intelligence were developed for the storage ring physical design. As an example of application, partial physical design of HALS (Hefei Advanced Light Source), which is a diffraction limited VUV and soft X-ray light source, was introduced. Severe emittance growth due to the Intra Beam Scattering effect, which is the main obstacle to achieve ultra low emittance, was estimated quantitatively and possible cures were discussed. It is inspiring that better performance of diffraction limited storage ring can be achieved in principle with careful parameter optimization.
Whey powders are a rich source and excellent storage matrix for dairy bacteriophages.
Wagner, Natalia; Brinks, Erik; Samtlebe, Meike; Hinrichs, Jörg; Atamer, Zeynep; Kot, Witold; Franz, Charles M A P; Neve, Horst; Heller, Knut J
2017-01-16
Thirteen whey powders and 5 whey powder formulations were screened for the presence of dairy bacteriophages using a representative set of 8 acid-producing Lactococcus lactis and 5 Streptococcus thermophilus, and 8 flavour-producing Leuconostoc pseudomesenteroides and Leuconostoc mesenteroides strains. Lytic L. lactis phages were detected in all samples, while S. thermophilus and Leuconostoc phages were present in 50% or 40% of the samples, respectively. Maximal phage titers were 6×10 7 plaque-forming units (pfu)/g of whey powder for L. lactis phages, 1×10 7 pfu/g for Leuconostoc phages and 1×10 5 pfu/g for S. thermophilus phages. In total, 55 phages were isolated and characterized. Thirty one of the 33 lactococcal phages tested belonged to the wide-spread 936 phage group. In the course of this study, a PCR detection method for Leuconostoc phages (Ali et al., 2013) was adapted to new phage isolates. Furthermore, a remarkably high stability of phages in whey powder samples was documented during a long-term storage period of 4 years. Copyright © 2016 Elsevier B.V. All rights reserved.
Favorable Decision Upholding Radioactive/Hazardous Mixed Waste Storage Civil Enforcement Policy
This page contains a copy of the U.S. Court of Appeals (District of Columbia Circuit) decision in Edison Electric Institute, et al. v. EPA, No. 91-1586, which upheld the EPA's August 29, 1991, radioactive/hazardous 'mixed waste' storage civil enforcement policy
Belosludov, Rodion V; Rhoda, Hannah M; Zhdanov, Ravil K; Belosludov, Vladimir R; Kawazoe, Yoshiyuki; Nemykin, Victor N
2017-08-02
Correction for 'Conceptual design of tetraazaporphyrin- and subtetraazaporphyrin-based functional nanocarbon materials: electronic structures, topologies, optical properties, and methane storage capacities' by Rodion V. Belosludov et al., Phys. Chem. Chem. Phys., 2016, 18, 13503-13518.
40 CFR Table 3 to Subpart U of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 3 Table 3 to Subpart U of Part 63—Group 1 Storage Vessels at Existing...
40 CFR Table 3 to Subpart U of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 3 Table 3 to Subpart U of Part 63—Group 1 Storage Vessels at Existing...
40 CFR Table 2 to Subpart Jjj of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 2 Table 2 to Subpart JJJ of Part 63—Group 1 Storage Vessels...
40 CFR Table 2 to Subpart Jjj of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 12 2014-07-01 2014-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 2 Table 2 to Subpart JJJ of Part 63—Group 1 Storage Vessels...
40 CFR Table 2 to Subpart Jjj of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 2 Table 2 to Subpart JJJ of Part 63—Group 1 Storage Vessels at...
40 CFR Table 4 to Subpart Jjj of... - Group 1 Storage Vessels at New Affected Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Group 1 Storage Vessels at New... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 4 Table 4 to Subpart JJJ of Part 63—Group 1 Storage Vessels...
40 CFR Table 3 to Subpart U of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 3 Table 3 to Subpart U of Part 63—Group 1 Storage Vessels at Existing...
40 CFR Table 3 to Subpart U of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 3 Table 3 to Subpart U of Part 63—Group 1 Storage Vessels at Existing...
40 CFR Table 4 to Subpart Jjj of... - Group 1 Storage Vessels at New Affected Sources
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Group 1 Storage Vessels at New... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 4 Table 4 to Subpart JJJ of Part 63—Group 1 Storage Vessels at...
40 CFR Table 2 to Subpart Jjj of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 12 2012-07-01 2011-07-01 true Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 2 Table 2 to Subpart JJJ of Part 63—Group 1 Storage Vessels at...
40 CFR Table 4 to Subpart Jjj of... - Group 1 Storage Vessels at New Affected Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 12 2014-07-01 2014-07-01 false Group 1 Storage Vessels at New... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 4 Table 4 to Subpart JJJ of Part 63—Group 1 Storage Vessels...
40 CFR Table 3 to Subpart U of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins Pt. 63, Subpt. U, Table 3 Table 3 to Subpart U of Part 63—Group 1 Storage Vessels at Existing...
40 CFR Table 2 to Subpart Jjj of... - Group 1 Storage Vessels at Existing Affected Sources
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Group 1 Storage Vessels at Existing... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 2 Table 2 to Subpart JJJ of Part 63—Group 1 Storage Vessels at...
Beam dynamics and expected performance of Sweden's new storage-ring light source: MAX IV
NASA Astrophysics Data System (ADS)
Leemann, S. C.; Andersson, Å.; Eriksson, M.; Lindgren, L.-J.; Wallén, E.; Bengtsson, J.; Streun, A.
2009-12-01
MAX IV will be Sweden’s next-generation high-performance synchrotron radiation source. The project has recently been granted funding and construction is scheduled to begin in 2010. User operation for a broad and international user community should commence in 2015. The facility is comprised of two storage rings optimized for different wavelength ranges, a linac-based short-pulse facility and a free-electron laser for the production of coherent radiation. The main radiation source of MAX IV will be a 528 m ultralow emittance storage ring operated at 3 GeV for the generation of high-brightness hard x rays. This storage ring was designed to meet the requirements of state-of-the-art insertion devices which will be installed in nineteen 5 m long dispersion-free straight sections. The storage ring is based on a novel multibend achromat design delivering an unprecedented horizontal bare lattice emittance of 0.33 nm rad and a vertical emittance below the 8 pm rad diffraction limit for 1 Å radiation. In this paper we present the beam dynamics considerations behind this storage-ring design and detail its expected unique performance.
Last chance for carbon capture and storage
NASA Astrophysics Data System (ADS)
Scott, Vivian; Gilfillan, Stuart; Markusson, Nils; Chalmers, Hannah; Haszeldine, R. Stuart
2013-02-01
Anthropogenic energy-related CO2 emissions are higher than ever. With new fossil-fuel power plants, growing energy-intensive industries and new sources of fossil fuels in development, further emissions increase seems inevitable. The rapid application of carbon capture and storage is a much heralded means to tackle emissions from both existing and future sources. However, despite extensive and successful research and development, progress in deploying carbon capture and storage has stalled. No fossil-fuel power plants, the greatest source of CO2 emissions, are using carbon capture and storage, and publicly supported demonstration programmes are struggling to deliver actual projects. Yet, carbon capture and storage remains a core component of national and global emissions-reduction scenarios. Governments have to either increase commitment to carbon capture and storage through much more active market support and emissions regulation, or accept its failure and recognize that continued expansion of power generation from burning fossil fuels is a severe threat to attaining objectives in mitigating climate change.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Conrad, Mark; Bill, Markus
2008-08-01
The nitrogen ({delta}{sup 15}N) and oxygen ({delta}{sup 18}O) isotopic compositions of nitrate in the environment are primarily a function of the source of the nitrate. The ranges of isotopic compositions for nitrate resulting from common sources are outlined in Figure 1 from Kendall (1998). As noted on Figure 1, processes such as microbial metabolism can modify the isotopic compositions of the nitrate, but the effects of these processes are generally predictable. At Hanford, nitrate and other nitrogenous compounds were significant components of most of the chemical processes used at the site. Most of the oxygen in nitrate chemicals (e.g., nitricmore » acid) is derived from atmospheric oxygen, giving it a significantly higher {delta}{sup 18}O value (+23.5{per_thousand}) than naturally occurring nitrate that obtains most of its oxygen from water (the {delta}{sup 18}O of Hanford groundwater ranges from -14{per_thousand} to -18{per_thousand}). This makes it possible to differentiate nitrate from Hanford site activities from background nitrate at the site (including most fertilizers that might have been used prior to the Department of Energy plutonium production activities at the site). In addition, the extreme thermal and chemical conditions that occurred during some of the waste processing procedures and subsequent waste storage in select single-shell tanks resulted in unique nitrate isotopic compositions that can be used to identify those waste streams in soil and groundwater at the site (Singleton et al., 2005; Christensen et al., 2007). This report presents nitrate isotope data for soil and groundwater samples from the Hanford 200 Areas and discusses the implications of that data for potential sources of groundwater contamination.« less
Raman Spectroscopy of Water-rich Stishovite and Dense High-Pressure Silica up to 55 GPa
NASA Astrophysics Data System (ADS)
Nisr, C.; Shim, S. H.; Leinenweber, K. D.; Chizmeshya, A. V.
2017-12-01
Recent studies have shown that mineral phases such as δ-AlOOH, (Mg,Si)OOH, (Mg,Si,Al)OOH, (Al,Si)O2 and SiO2 with rutile-type or modified rutile-type crystal structures can store large amounts of water and be stable at high pressure and high temperature relevant to the Earth's lower mantle. The Al-H charge coupled substitution has been proposed to explain the large storage capacity of these phases. However, the substitution cannot explain the large water storage found in pure stishovite (Spektor et al., 2011). Instead, an octahedral version of hydrogarnet-like substitution has been proposed for the incorporation of hydrogen in pure stishovite. We have performed Raman spectroscopy measurements on pure hydrous stishovite with 3.2 wt% water up to 55 GPa. At ambient pressure, we found that the OH stretching mode frequencies range between those of low-water aluminous stishovite and δ-AlOOH, suggesting an intermediate strength of hydrogen bonding between these two phases. In the lattice mode range, we observe modes similar to the IR-active modes of anhydrous stishovite after decompression to 1 bar, suggesting Si defects in the crystal structure that activate the inactive modes. Our data show a series of changes at pressures between 24 and 28 GPa, supporting our observation of a phase transition (likely to the CaCl2 type) in X-Ray diffraction measurements (Nisr et al., 2017, JGR). We found that the OH mode of hydrous stishovite has a positive frequency shift with an increase in pressure. The behavior is the opposite to that found in δ-AlOOH, indicating that the OH incorporation mechanism in hydrous silica is different from that of aluminous low-water stishovite and δ-AlOOH, likely through direct substitution (Si ⇄ 4H+). Because the mantle hydrous phases would have complex compositions, our study suggests that the direct substitution should also be considered together with the Al substitution for the deep mantle storage of water.
Characterization of neutron sources from spent fuel casks. [Skyshine
DOE Office of Scientific and Technical Information (OSTI.GOV)
Parks, C.V.; Pace, J.V. III
1987-01-01
In the interim period prior to the acceptance of spent fuel for disposal by the USDOE, utilities are beginning to choose dry cask storage as an alternative to pool re-racking, transshipments, or new pool construction. In addition, the current MRS proposal calls for interim dry storage of consolidated spent fuel in concrete casks. As part of the licensing requirements for these cask storage facilities, calculations are typically necessary to determine the yearly radiation dose received at the site boundary. Unlike wet facilities, neutron skyshine can be an important contribution to the total boundary dose from a dry storage facility. Calculationmore » of the neutron skyshine is in turn heavily dependent on the source characteristics and source model selected for the analysis. This paper presents the basic source characteristics of the spent fuel stored in dry casks and discusses factors that must be considered in evaluating and modeling the radiation sources for the subsequent skyshine calculation. 4 refs., 1 tab.« less
NASA Astrophysics Data System (ADS)
Sauer, M.; Bergamaschi, B. A.; Smith, R. A.; Zhu, Z.; Shih, J.
2012-12-01
Flux of nutrients and sediments to the coastal zone varies in response to land-use modification, reservoir construction, management action and population change. It is anticipated that future changes in the flux of these components in response to climate and terrestrial processes will affect carbon (C) burial in the coastal ocean. Coastal oceans store appreciable amounts of C as a result of river inflows: coastal primary production is enhanced by inputs of terrestrially derived nutrients, and C burial is controlled by terrestrial sediment supply. Assessing the capacity and changes to coastal C preservation, therefore, requires estimation of (1) riverine nutrient and sediment delivery to the coastal ocean, and (2) the enhanced C production and sediment deposition in the coastal ocean. The United States Geological Survey (USGS) has embarked on a congressionally-mandated nationwide effort to assess the future effects of climate and land use and land cover change (LULC) on C storage. The USGS has developed alternative scenarios for changes in US LULC from 2006 to 2100 based on the Intergovernmental Panel on Climate Change (IPCC) climate, economic, and demographic scenarios (Sohl et al 2012). These spatially-detailed scenarios provide inputs to national-scale SPARROW watershed models of total nitrogen, total phosphorus, total organic C (TOC), and suspended sediment (Smith et al 1997; Schwarz et al, 2006). The watershed models, in turn, provide inputs of nutrients, TOC, and sediment to a coupled model of coastal transport, production, and sedimentation. This coastal modelling component includes particulate C sedimentation and burial estimated as functions of bathymetry and pycnocline depth (Armstrong, et al 2002; Dunne et al 2007). River borne fluxes of TOC to US Pacific coastal waters under baseline conditions (1992) were 1.59 TgC/yr. Projected future (2050) fluxes under a regionally-downscaled LULC scenario aligned with the IPCC A2 scenario were similar (1.61TgC/yr). C storage in coastal environments as influenced by terrestrial processes represents a significant sink for C in comparison to terrestrial biomass C sinks, and is significantly sensitive to changes in LULC and population. The estimated rate of storage in Pacific coastal waters was 2.0 TgC/yr under baseline conditions. Projection of land use and population changes through 2050 associated with the IPCC A2 scenario had a small effect on coastal C storage processes, reducing C storage by 4% over baseline conditions. Results of this modeling exercise indicate that the size of the C sink associated with terrestrial exports is substantial and sensitive to anthropogenic activity. Thus, future assessments of how terrestrial policy and management actions may alter C storage should include an evaluation of the effects prospective alterations in terrestrial processes have on coastal C storage.
Design Study of an MBA Lattice for the Advanced Photon Source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Decker, Glenn
2014-11-02
Recent interest in ultra-low-emittance designs for storage-ring-based synchrotron light sources has spurred a focused design effort on a multi-bend achromat (MBA) storage ring replacement for the Advanced Photon Source (APS). The APS is relatively large (1104 m circumference) and, as such, an upgrade to a fourth-generation storage ring holds the potential for a two to three order of magnitude enhancement of X-ray brightness due to the approximate inverse cubic scaling of emittance with the number of dipole bend magnets.
NASA Astrophysics Data System (ADS)
Bliznakov, S.; Lefterova, E.; Dimitrov, N.; Petrov, K.; Popov, A.
AB 5-type hydrogen storage alloys with MmNi 4.4- xCo 0.6Al x (Mm-mischmetal) composition are synthesized, structurally and thermodynamically characterized, and electrochemically tested in 6 M KOH electrolyte. It is shown that an increase of the Al content in the alloy results in expansion of both the alloy lattice cell size and the unit cell volume. These structural changes lead to decrease of the plateau pressure and increase of the plateau width in the pressure-composition-temperature desorption isotherms. Improvement of the specific electrode capacity is also registered with the increase of the cell parameters. In addition to that the higher Al content is found to enhance the stability of the alloy components' hydrides. Maximum discharge capacity of 278 mAh g -1 is measured with an electrode made from a MmNi 3.6Co 0.6Al 0.8 alloy. Cycle life tests of the accordingly prepared electrodes suggest a stability that is comparable to the stability of commercially available hydrogen storage electrodes.
19. NBS SUIT LAB. STORAGE SHELF WITH LIQUID COOLING VENTILATION ...
19. NBS SUIT LAB. STORAGE SHELF WITH LIQUID COOLING VENTILATION GARMENT (LCVG), SUIT GLOVES, WAIST INSERTS, UPPER AND LOWER ARMS (LEFT, FROM TOP TO BOTTOM), LOWER TORSO ASSEMBLIES (LTA) (MIDDLE RIGHT TO LOWER RIGHT). - Marshall Space Flight Center, Neutral Buoyancy Simulator Facility, Rideout Road, Huntsville, Madison County, AL
Weathering controls on mechanisms of carbon storage in grassland soils
Masiello, C.A.; Chadwick, O.A.; Southon, J.; Torn, M.S.; Harden, J.W.
2004-01-01
On a sequence of soils developed under similar vegetation, temperature, and precipitation conditions, but with variations in mineralogical properties, we use organic carbon and 14C inventories to examine mineral protection of soil organic carbon. In these soils, 14C data indicate that the creation of slow-cycling carbon can be modeled as occurring through reaction of organic ligands with Al3+ and Fe3+ cations in the upper horizons, followed by sorption to amorphous inorganic Al compounds at depth. Only one of these processes, the chelation Al3+ and Fe3+ by organic ligands, is linked to large carbon stocks. Organic ligands stabilized by this process traverse the soil column as dissolved organic carbon (both from surface horizons and root exudates). At our moist grassland site, this chelation and transport process is very strongly correlated with the storage and long-term stabilization of soil organic carbon. Our 14C results show that the mechanisms of organic carbon transport and storage at this site follow a classic model previously believed to only be significant in a single soil order (Spodosols), and closely related to the presence of forests. The presence of this process in the grassland Alfisol, Inceptisol, and Mollisol soils of this chronosequence suggests that this process is a more significant control on organic carbon storage than previously thought. Copyright 2004 by the American Geophysical Union.
OpenElectrophy: An Electrophysiological Data- and Analysis-Sharing Framework
Garcia, Samuel; Fourcaud-Trocmé, Nicolas
2008-01-01
Progress in experimental tools and design is allowing the acquisition of increasingly large datasets. Storage, manipulation and efficient analyses of such large amounts of data is now a primary issue. We present OpenElectrophy, an electrophysiological data- and analysis-sharing framework developed to fill this niche. It stores all experiment data and meta-data in a single central MySQL database, and provides a graphic user interface to visualize and explore the data, and a library of functions for user analysis scripting in Python. It implements multiple spike-sorting methods, and oscillation detection based on the ridge extraction methods due to Roux et al. (2007). OpenElectrophy is open source and is freely available for download at http://neuralensemble.org/trac/OpenElectrophy. PMID:19521545
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gschneidner, Jr., Karl A.; Schmidt, Frederick A.
A carbothermic reduction method is provided for reducing a La-, Ce-, MM-, and/or Y-containing oxide in the presence of carbon and a source of a reactant element comprising Si, Ge, Sn, Pb, As, Sb, Bi, and/or P to form an intermediate alloy material including a majority of La, Ce, MM, and/or Y and a minor amount of the reactant element. The intermediate material is useful as a master alloy for in making negative electrode materials for a metal hydride battery, as hydrogen storage alloys, as master alloy additive for addition to a melt of commercial Mg and Al alloys, steels,more » cast irons, and superalloys; or in reducing Sm.sub.2O.sub.3 to Sm metal for use in Sm--Co permanent magnets.« less
40 CFR Table 3 to Subpart Ppp of... - Group 1 Storage Vessels at Existing and New Affected Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 12 2012-07-01 2011-07-01 true Group 1 Storage Vessels at Existing and... Polyether Polyols Production Pt. 63, Subpt. PPP, Table 3 Table 3 to Subpart PPP of Part 63—Group 1 Storage Vessels at Existing and New Affected Sources Vessel capacity(cubic meters) Vapor Pressure a (kilopascals...
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Group 1 Storage Vessels at Existing... Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 3 Table 3 to Subpart JJJ of Part 63—Group 1 Storage Vessels at Existing Affected Sources Producing the Listed Thermoplastics...
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 12 2012-07-01 2011-07-01 true Group 1 Storage Vessels at Existing... Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 3 Table 3 to Subpart JJJ of Part 63—Group 1 Storage Vessels at Existing Affected Sources Producing the Listed Thermoplastics...
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 12 2014-07-01 2014-07-01 false Group 1 Storage Vessels at Existing... Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 3 Table 3 to Subpart JJJ of Part 63—Group 1 Storage Vessels at Existing Affected Sources Producing the Listed...
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Group 1 Storage Vessels at Existing... Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 3 Table 3 to Subpart JJJ of Part 63—Group 1 Storage Vessels at Existing Affected Sources Producing the Listed Thermoplastics...
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Group 1 Storage Vessels at Existing... Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 3 Table 3 to Subpart JJJ of Part 63—Group 1 Storage Vessels at Existing Affected Sources Producing the Listed...
40 CFR Table 3 to Subpart Ppp of... - Group 1 Storage Vessels at Existing and New Affected Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Group 1 Storage Vessels at Existing and... Polyether Polyols Production Pt. 63, Subpt. PPP, Table 3 Table 3 to Subpart PPP of Part 63—Group 1 Storage Vessels at Existing and New Affected Sources Vessel capacity(cubic meters) Vapor Pressure a (kilopascals...
Advances in lasers and optical micro-nano-systems
NASA Astrophysics Data System (ADS)
Laurell, F.; Fazio, E.
2010-09-01
Lasers represent a well consolidated technology: nevertheless, research in this field remains very active and productive, in both basic and applied directions. At the moment significant attention is given to those sources that bring together high power and compactness. Such high power lasers find important applications for material treatments and such applications are presented by Ehsani et al and Saiedeh Saghafi et al, in the treatment of dielectric thin films (Alteration of optical and morphological properties of polycarbonate illuminated by visible/IR laser beams) or of biological tissues like pistachio seeds (Investigating the effects of laser beams (532 and 660 nm) in annihilation of pistachio mould fungus using spectrophotometry analysis). In particular the latter paper show how laser sources can find very important applications in new domains, preserving goods and food without the need for preservatives or pesticides by simply sterilizing them using light. Optical Micro and Nano Systems presents a new domain for exploration. In this framework this special issue is very attractive, because it assembles papers reporting new results in three directions: new techniques for monitoring integrated micro- and nano-systems, new integrated systems and novel high performance metamaterial configurations. Integrated micro-components can be monitored and controlled using reflectance measurements as presented by Piombini et al (Toward the reflectance measurement of micro components). Speckle formation during laser beam reflection can also be a very sophisticated tool for detecting ultra-precise displacements, as presented by Filter et al (High resolution displacement detection with speckles : accuracy limits in linear displacement speckle metrology). Three dimensional integrated optical structures is indeed a big challenge and a peculiarity of photonics, they can be formed through traditional holography or using more sophisticated and novel ! technologies. Thus, special manipulation of the writing-reading optical beam can push holography toward storages at higher data densities, as presented by Norihiko Ishii et al (Wavefront compensation method using novel index in holographic data storage). Along a similar direction Furlan et al describe a very innovative technique for producing optical traps using novel Devil micro-lenses (Volumetric multiple optical traps produced by Devil's lenses). Vynnyk et al presented an interesting application of electron microscopy for monitoring sub-micrometric structures in 3D configurations (3D-measurement with the stereo scanning electron microscope on sub-micrometer structure). Finally, S. Rao et al present two interesting papers on integrated structures compatible with silicon technology: one describes the realisation of low-loss waveguides using amorphous silicon, a relatively novel material with many applications in very different domains (Low-loss amorphous silicon waveguid! es grown by PECVD on indium tin oxide), and one on the realisation of a electrically drivable device with affective compatibility with CMOS technology (Electro-optical modulating multistack device based on the CMOS-compatible technology of amorphous silicon). We hope that this special issue of the Journal of the European Optical Society will reflect the interest of the European Scientific Community toward these fundamental and applied topics and will demonstrate to readers some of the actual directions of research. We express our full appreciation to the authors that participated to this initiative which acts only as a primer for the vast amount of work now being undertaken in laser physics and applications in micro- and nano-systems. We would like to give a special thank to the paper reviewers for their important role in the paper selection process and all the journal staff for their very professional support, dedication and energy, which made this special issue feasible.
High Coulombic efficiency aluminum-ion battery using an AlCl3-urea ionic liquid analog electrolyte.
Angell, Michael; Pan, Chun-Jern; Rong, Youmin; Yuan, Chunze; Lin, Meng-Chang; Hwang, Bing-Joe; Dai, Hongjie
2017-01-31
In recent years, impressive advances in harvesting renewable energy have led to a pressing demand for the complimentary energy storage technology. Here, a high Coulombic efficiency (∼99.7%) Al battery is developed using earth-abundant aluminum as the anode, graphite as the cathode, and a cheap ionic liquid analog electrolyte made from a mixture of AlCl 3 and urea in a 1.3:1 molar ratio. The battery displays discharge voltage plateaus around 1.9 and 1.5 V (average discharge = 1.73 V) and yielded a specific cathode capacity of ∼73 mAh g -1 at a current density of 100 mA g -1 (∼1.4 C). High Coulombic efficiency over a range of charge-discharge rates and stability over ∼150-200 cycles was easily demonstrated. In situ Raman spectroscopy clearly showed chloroaluminate anion intercalation/deintercalation of graphite (positive electrode) during charge-discharge and suggested the formation of a stage 2 graphite intercalation compound when fully charged. Raman spectroscopy and NMR suggested the existence of AlCl 4 - , Al 2 Cl 7 - anions and [AlCl 2 ·(urea) n ] + cations in the AlCl 3 /urea electrolyte when an excess of AlCl 3 was present. Aluminum deposition therefore proceeded through two pathways, one involving Al 2 Cl 7 - anions and the other involving [AlCl 2 ·(urea) n ] + cations. This battery is a promising prospect for a future high-performance, low-cost energy storage device.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J
UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. Themore » assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 LiAlH4Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration of the alanate from alkali hydride, Al and hydrogen, was hampering reversibility. The reverse reaction was then studied for the same phase diagram, starting with LiH, NaH, and MgH2, and Al. The study was extended to phase diagrams including KH and CaH2 as well. The observed hydrogen storage capacity in the Al hexahydrides was less than 4 wt. %, well short of DOE targets. The HT assay came on line and after certification with studies on NaAlH4, was first applied to the LiNH2 - LiBH4 - MgH2 phase diagram. The 60-point study elucidated trends within the system locating an optimum material of 0.6 LiNH2 0.3 MgH2 0.1 LiBH4 that stored about 4 wt. % H2 reversibly and operated below 220 °C. Also present was the phase Li4(NH2)3BH4, which had been discovered in the LiNH2 -LiBH4 system. This new ternary formulation performed much better than the well-known 2 LiNH2MgH2 system by 50 °C in the HT assay. The Li4(NH2)3BH4 is a low melting ionic liquid under our test conditions and facilitates the phase transformations required in the hydrogen storage reaction, which no longer relies on a higher energy solid state reaction pathway. Further study showed that the 0.6 LiNH2 0.3 MgH2 0.1 LiBH4 formulation was very stable with respect to ammonia and diborane desorption, the observed desorption was from hydrogen. This result could not have been anticipated and was made possible by the efficiency of HT combinatorial methods. Investigation of the analogous LiNH2 LiBH4 CaH2 phase diagram revealed new reversible hydrogen storage materials 0.625 LiBH4 + 0.375 CaH2 and 0.375 LiNH2 + 0.25 LiBH4 + 0.375 CaH2 operating at 1 wt. % reversible hydrogen below 175 °C. Powder x-ray diffraction revealed a new structure for the spent materials which had not been previously observed. While the storage capacity was not impressive, an important aspect is that it boron appears to participate in a low temperature reversible reaction. The last major area of study also focused on activating boron-based materials in order to exploit the tremendous gravimetric capacity of LiBH4. A number of LiNH2 LiBH4 transition metal (TM) systems were investigated for the following reasons. No additional leads were discovered in this system. Another major project activity was the assembly of a high throughput synthesis system. The automated synthesizer was set up in a glovebox and was capable of handling liquids and powders and carrying out sealed block syntheses up to 250 °C. Unfortunately, the synthesizer could not handle the delivery of the fine powders required fro hydrogen storage applications. Although the powder delivery system was overhauled and redesigned several times, this problem was never remedied.« less
NASA Astrophysics Data System (ADS)
Pfister, Laurent; Klaus, Julian; Hissler, Christophe; François Iffly, Jean; Gourdol, Laurent; Martinez-Carreras, Nuria; McDonnell, Jeffrey J.
2014-05-01
Recent hydrological process research focussed on how much water a catchment can store and how these catchments store and release water. Storage can be a valuable metric for catchment description, inter-comparison, and classification. Further storage controls catchment mixing, non-linearities in rainfall-runoff transformation and eco-hydrological processes. Various methods exist to determine catchment storage (e.g. natural tracer, soil moisture and groundwater data, hydrological models). Today it remains unclear what parts of the catchment storage are measured with the different models. Here we present a new hydrometric approach to answer the question how much water a catchment can store. We tested our approach in a dense hydro-climatological monitoring network that encompasses 16 recording streamgauges and 21 pluviographs in the Alzette River basin in Luxembourg (Europe). Catchment scales are ranging from 0.47 to 285 km2 and they have clean- and mixed combinations of distinct geologies ranging from schists to marls, sandstone, dolomite and limestone. Previous investigations in the area of interest have shown that geology largely controls winter runoff coefficients. Here, we focus at how catchment geology is ultimately affecting catchment storage. We used the approach of Sayama et al. (2011) to compute catchment dynamic storage changes for each winter season over the period 2002-2012 (based on precipitation as input; discharge and evapotranspiration as output). We determined dynamic storage changes for each winter semester (October to March) in all 16 catchments over the period 2002-2012. At the beginning of each hydrological winter season, all catchments showed similar trends in storage change. A few weeks into the winter season, catchments with lowest permeability (e.g. marls) started to plateau. The highest storage values were reached several months later in the season in catchments dominated by permeable substrate (e.g. sandstone). For most catchments, we found strong correlations between baseflow prior to the recharge period (i.e. at initiation of the total storage calculations) and the seasonal maximum value of the total storage change calculations. In order to determine the maximum storage potential for each catchment, we fitted a trendline through the annual 'initial baseflow - maximum storage' populations. By extrapolating these trendlines to zero flow conditions, we obtained the maximum storage potential. Our results show that these maximum storage values clearly tend to be larger in catchments dominated by permeable substrate, compared to areas underlain by impermeable bedrock. In the latter, average filling ratios were found to be substantially higher (exceeding 80%) than in catchments dominated by permeable substrate (approximately 40%). These findings were confirmed by average seasonal winter runoff coefficients that are substantially higher in catchments dominated by impermeable bedrock (Pfister et al., in prep.). Our new approach allows a fast assessment of storage potential in catchments based on discharge, precipitation and evapotranspiration data. Pfister L. et al. 2014: Catchment storage, baseflow isotope signatures and basin geology: Is there a connection? In preparation. Sayama, T., McDonnell, J.J., Dhakal, A., Sullivan, K., 2011. How much water can a watershed store ? Hydrological Processes 25, 3899-3908.
Watershed nitrogen and phosphorus balance: The upper Potomac River basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jaworski, N.A.; Groffman, P.M.; Keller, A.A.
1992-01-01
Nitrogen and phosphorus mass balances were estimated for the portion of the Potomac River basin watershed located above Washington, D.C. The total nitrogen (N) balance included seven input source terms, six sinks, and one 'change-in-storage' term, but was simplified to five input terms and three output terms. The phosphorus (P) baance had four input and three output terms. The estimated balances are based on watershed data from seven information sources. Major sources of nitrogen are animal waste and atmospheric deposition. The major sources of phosphorus are animal waste and fertilizer. The major sink for nitrogen is combined denitrification, volatilization, andmore » change-in-storage. The major sink for phosphorus is change-in-storage. River exports of N and P were 17% and 8%, respectively, of the total N and P inputs. Over 60% of the N and P were volatilized or stored. The major input and output terms on the budget are estimated from direct measurements, but the change-in-storage term is calculated by difference. The factors regulating retention and storage processes are discussed and research needs are identified.« less
Single-Photon Ionization Soft-X-Ray Laser Mass Spectrometry of Potential Hydrogen Storage Materials
NASA Astrophysics Data System (ADS)
Dong, F.; Bernstein, E. R.; Rocca, J. J.
A desk-top size capillary discharge 46.9 nm lasear is applied in the gas phase study of nanoclusters. The high photon energy allows for single-photon ionization mass spectrometry with reduced cluster fragmentation. In the present studies, neutral Al m C n and Al m C n H x cluster are investigation for the first time. Single photon ionization through 46.9 nm, 118 nm, 193 nm lasers is used to detect neutral cluster distributions through time of flight mass spectrometry. Al m C n clusters are generated through laser ablation of a mixture of Al and C powders pressed into a disk. An oscillation of the vertical ionization energies (VIEs) of Al m C n clusters is observed in the experiments. The VIEs of Al m C n clusters changes as a function of the numbers of Al and C atoms in the clusters. Al m C n H x clusters are generated through an Al ablation plasma-hydrocarbon reaction, an Al-C ablation plasma reacting with H2 gas, or through cold Al m C n clusters reacting with H2 gas in a fast flow reactor. DFT and ab inito calculations are carried out to explore the structures, IEs, and electronic structures of Al m C n H x clusters. C=C bonds are favored for the lowest energy structures for Al m C n clusters. Be m C n H x are generated through a beryllium ablation plasma-hydrocarbon reaction and detected by single photon ionization of 193 nm laser. Both Al m C n H x and Be m C n H x are considered as potential hydrogen storage materials.
Bauer, Thomas; Martin, Claudia; Eck, Markus; Wörner, Antje
2015-01-01
Summary Thermal energy storage (TES) is capable to reduce the demand of conventional energy sources for two reasons: First, they prevent the mismatch between the energy supply and the power demand when generating electricity from renewable energy sources. Second, utilization of waste heat in industrial processes by thermal energy storage reduces the final energy consumption. This review focuses mainly on material aspects of alkali nitrate salts. They include thermal properties, thermal decomposition processes as well as a new method to develop optimized salt systems. PMID:26199853
Pfleger, Nicole; Bauer, Thomas; Martin, Claudia; Eck, Markus; Wörner, Antje
2015-01-01
Thermal energy storage (TES) is capable to reduce the demand of conventional energy sources for two reasons: First, they prevent the mismatch between the energy supply and the power demand when generating electricity from renewable energy sources. Second, utilization of waste heat in industrial processes by thermal energy storage reduces the final energy consumption. This review focuses mainly on material aspects of alkali nitrate salts. They include thermal properties, thermal decomposition processes as well as a new method to develop optimized salt systems.
A SCR Model Calibration Approach with Spatially Resolved Measurements and NH 3 Storage Distributions
Song, Xiaobo; Parker, Gordon G.; Johnson, John H.; ...
2014-11-27
The selective catalytic reduction (SCR) is a technology used for reducing NO x emissions in the heavy-duty diesel (HDD) engine exhaust. In this study, the spatially resolved capillary inlet infrared spectroscopy (Spaci-IR) technique was used to study the gas concentration and NH 3 storage distributions in a SCR catalyst, and to provide data for developing a SCR model to analyze the axial gaseous concentration and axial distributions of NH 3 storage. A two-site SCR model is described for simulating the reaction mechanisms. The model equations and a calculation method was developed using the Spaci-IR measurements to determine the NH 3more » storage capacity and the relationships between certain kinetic parameters of the model. Moreover, a calibration approach was then applied for tuning the kinetic parameters using the spatial gaseous measurements and calculated NH3 storage as a function of axial position instead of inlet and outlet gaseous concentrations of NO, NO 2, and NH 3. The equations and the approach for determining the NH 3 storage capacity of the catalyst and a method of dividing the NH 3 storage capacity between the two storage sites are presented. It was determined that the kinetic parameters of the adsorption and desorption reactions have to follow certain relationships for the model to simulate the experimental data. Finally, the modeling results served as a basis for developing full model calibrations to SCR lab reactor and engine data and state estimator development as described in the references (Song et al. 2013a, b; Surenahalli et al. 2013).« less
NASA Astrophysics Data System (ADS)
Medici, Chiara; Wade, Andrew; Frances, Felix
2010-05-01
Nitrogen is present in both terrestrial and aquatic ecosystems and research is needed to understand its storage, transportation and transformations in river catchments world-wide because of its importance in controlling plant growth and freshwater trophic status (Vitousek et al. 2009; Chu et al. 2008; Schlesinger et al 2006; Ocampo et al. 2006; Green et al., 2004; Arheimer et al., 1996). Numerous mathematical models have been developed to describe the nitrogen dynamics, but there is a substantial gap between the outputs now expected from these models and what modellers are able to provide with scientific justification (McIntyre et al., 2005). In fact, models will always necessarily be simplification of reality; hence simplifying assumptions are sources of uncertainty that must be well understood for an accurate model results interpretation. Therefore, estimating prediction uncertainties in water quality modelling is becoming increasingly appreciated (Dean et al., 2009, Kruger et al., 2007, Rode et al., 2007). In this work the lumped LU4-N model (Medici et al., 2008; Medici et al., EGU2009-7497) is subjected to an extensive regionalised sensitivity analysis (GSA, based on Monte Carlo simulations) in application to the Fuirosos catchment, Catalonia. The main results are: 1) the hydrological model is greatly affected by the maximum static storage water content (Hu_max), which defines the amount of water held in soil that can leave the catchment only by evapotranspiration. Thus, it defines also the amount of water not retained that is free to move and supplies the other model tanks; 2) the use of several objective functions in order to take into account different hydrograph characteristic helped to constrain parameter values; 3) concerning nitrogen, to obtain a sufficient level of behavioural parameter sets for the statistical analysis, not very severe criteria could be adopted; 4) stream water concentrations are sensitive to the shallow aquifer parameters, especially the nitrification constant (Knitr-aquif) and also to the certain soil parameters, like the mineralization constant (Kmin), the annual maximum ammonium uptake (MaxUPNH4) and the mineralization, nitrification and immobilisation thresholds (Umin, Unitr and Uimmob). Moreover the results give a clear indication that the hydrological model greatly affects the streamwater nitrate and ammonium concentrations; 5) result shows that the LU4-N model succeeded in achieving near-optimum fits simultaneously to flow and nitrate, but not ammonium; 6) however, the optimum flow model has not produced a near-optimum nitrate model. The analysis of this result indicated that calibrating the flow-related parameters first, then calibrating the remaining parameters instead of calibrating all parameters together, may not be the best strategy as pointed out for another study by McIntyre et al., 2005 ; 7) a final analysis seems also to support the idea that to obtain a satisfactory nitrogen simulation necessarily the flow should be acceptably represented, which lead to the conclusion that observed stream concentrations may indirectly help to calibrated the rainfall-runoff model, or at least the parameters to which they are sensitive.
Method of making AlInSb by metal-organic chemical vapor deposition
Biefeld, Robert M.; Allerman, Andrew A.; Baucom, Kevin C.
2000-01-01
A method for producing aluminum-indium-antimony materials by metal-organic chemical vapor deposition (MOCVD). This invention provides a method of producing Al.sub.X In.sub.1-x Sb crystalline materials by MOCVD wherein an Al source material, an In source material and an Sb source material are supplied as a gas to a heated substrate in a chamber, said Al source material, In source material, and Sb source material decomposing at least partially below 525.degree. C. to produce Al.sub.x In.sub.1-x Sb crystalline materials wherein x is greater than 0.002 and less than one.
The potential of geological storage of CO2 in Austria: a techno-economic assessment
NASA Astrophysics Data System (ADS)
Brüstle, Anna Katharina; Welkenhuysen, Kris; Bottig, Magdalena; Piessens, Kris; Ramirez, Andrea; Swenner, Rudy
2014-05-01
An impressive two-third or about 40GWh/y of electricity in Austria is produced from renewable energy sources, in particular hydro energy. For the remaining part the country depends on fossil fuels, which together with iron & steel production form the most CO2 intensive industries in Austria with a combined emission of just over 20Mt/y. According to the IEA, CO2 capture and geological storage (CCS) can reduce the global CO2 emission until 2050 by 17%. A correct assessment of CCS needs to start with the storage potential. Prior to this study, only general estimates of the theoretical capacity of Austrian reservoirs were available, thus, up until now, the realistic potential for CCS technology has not been assessed. Both for policy and industry, an assessment of the matched capacity is required, which is the capacity that actually will be used in CCS projects. This hurdle can be taken by applying a recently developed methodology (Welkenhuysen et al., 2013). This policy support system (PSS) consists of two parts, PSS Explorer and PSS III simulator. In brief, the methodology is based on expert judgements of potential reservoirs. These assessments can provide the best available data, including the expert's experience and possibly confidential data, without disclosing specific data. The geo-techno-economic calculation scheme PSS Explorer uses the expert input to calculate for each individual reservoir an assessment of the practical capacity (as probability density functions), in function of an acceptable price for storage. This practical capacity can then be used by the techno-economic PSS III simulator to perform advanced source-sink matching until 2050 and thus provide the matched reservoir capacity. The analysed reservoirs are 7 active or abandoned oil and gas reservoirs in Austria. The simulation of the electricity and iron & steel sector of Austria resulted in the estimation of the geological storage potential, taking into account geological, technological and economic uncertainties. Results indicate a significant potential for CCS in Austria and a very high probability for any CO2 storage activity. The assessment of the average practical capacity of the whole country is 120Mt at 15€/tCO2 of storage budget, while the average matched national capacity is 40Mt. Concerning the individual reservoirs, reservoir development probabilities generally lie between 20 and 30%. These numbers served as basis for a reservoir exploration ranking. Compared to current emissions, total storage capacity is at the low end, which is likely the main technical limiting factor for CCS deployment in Austria. Also, current policy seems not in favour of CCS. Storage capacity is however high enough to provide a significant contribution to the reduction of CO2 emissions in the country, in the order of a few million tonnes per year. Opportunities to combine CO2 geological storage and geothermal energy seem promising, but require additional evaluation. Welkenhuysen, K., Ramirez, A., Swennen, R. & Piessens, K., 2013. Ranking potential CO2 storage reservoirs: an exploration priority list for Belgium. International Journal of Greenhouse Gas Control, 17, p. 431-449
NASA Astrophysics Data System (ADS)
Brach, Marcin; Chormański, Jarosław
2014-05-01
The exact determination of water storage capacity in river valley is an important issue for hydrologists, ecologist and flood modellers. In case of natural river valley, the dense and complexity vegetation of the natural ecosystems can influence the proper identification of the water storage. Methods considered to be sufficient in other cases (urbanized, agricultural) may not produce correct results. Sedge communities in natural river valleys form characteristic tussocks, built from the species roots, other organic material and silt or mud. They are formed due to partial flooding during the inundation, so the plants can survive in hard, anaerobic conditions. They can growth even up to 0.5 meters, which is not so visible due to very dense vegetation in the valleys. These tussocks form a microtopography or a river valley. Currently, the most commonly used technology to register the terrain topography is an Airborne Laser Scanning (ALS), but in the case of the tussocks and the dense vegetation it generates high errors on elevation in the areas of the sedges (Carex appropinquata). This study concerns the Upper Biebrza Valley which is located in the northeastern Poland. For purpose of our work we used Terrestrial Laser Scanner (TLS) technology to determine microtopography of selected fields. Before measurements, the green part of the sedge was cut in selected measurements fields. It make possible to register only tussocks shape. Next, step was collection of the airborne ALS data of the valley with density of 8 points/sq m. The experimental field was divided on two sub-fields: one was cut and scanned using TLS before ALS collection, while the second after. Data collected as ALS and the TLS were then compared. The accuracy of the ALS data depends on the land cover of an area, while TLS accuracy is around 2 millimeters (when georeferenced it depends on the accuracy of reference points - in our case it was made using GPS RTK which gave us accuracy of few centimeters). The analysis shown that differences between ALS measurements and TLS on leaf free area is on average of 5 centimeters, while on areas which were not mowed it grows up to 0,5 m. Thanks to this studies we were able to determine water storage possibilities of valley while considering the tussocks shape.
Energy storage cell impedance measuring apparatus, methods and related systems
Morrison, John L.; Morrison, William H.; Christophersen, Jon P.
2017-12-26
Energy storage cell impedance testing devices, circuits, and related methods are disclosed. An energy storage cell impedance measuring device includes a sum of sinusoids (SOS) current excitation circuit including differential current sources configured to isolate a ground terminal of the differential current sources from a positive terminal and a negative terminal of an energy storage cell. A method includes applying an SOS signal comprising a sum of sinusoidal current signals to the energy storage cell with the SOS current excitation circuit, each of the sinusoidal current signals oscillating at a different one of a plurality of different frequencies. The method also includes measuring an electrical signal at a positive terminal and a negative terminal of the energy storage cell, and computing an impedance of the energy storage cell at each of the plurality of different frequencies using the measured electrical signal.
40 CFR Table 5 to Subpart G of... - Group 1 Storage Vessels at Existing Sources
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Group 1 Storage Vessels at Existing Sources 5 Table 5 to Subpart G of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for...
40 CFR Table 5 to Subpart G of... - Group 1 Storage Vessels at Existing Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Group 1 Storage Vessels at Existing Sources 5 Table 5 to Subpart G of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for...
40 CFR Table 5 to Subpart G of... - Group 1 Storage Vessels at Existing Sources
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Group 1 Storage Vessels at Existing Sources 5 Table 5 to Subpart G of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for...
40 CFR Table 5 to Subpart G of... - Group 1 Storage Vessels at Existing Sources
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Group 1 Storage Vessels at Existing Sources 5 Table 5 to Subpart G of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for...
40 CFR Table 5 to Subpart G of... - Group 1 Storage Vessels at Existing Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Group 1 Storage Vessels at Existing Sources 5 Table 5 to Subpart G of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for...
40 CFR 61.270 - Applicability and designation of sources.
Code of Federal Regulations, 2011 CFR
2011-07-01
... for Benzene Emissions From Benzene Storage Vessels § 61.270 Applicability and designation of sources. (a) The source to which this subpart applies is each storage vessel that is storing benzene having a... Benzene, ASTM D835-85 for Refined Benzene-485, ASTM D2359-85a or 93 for Refined Benzene-535, and ASTM...
40 CFR 61.270 - Applicability and designation of sources.
Code of Federal Regulations, 2014 CFR
2014-07-01
... for Benzene Emissions From Benzene Storage Vessels § 61.270 Applicability and designation of sources. (a) The source to which this subpart applies is each storage vessel that is storing benzene having a... Benzene, ASTM D835-85 for Refined Benzene-485, ASTM D2359-85a or 93 for Refined Benzene-535, and ASTM...
40 CFR 61.270 - Applicability and designation of sources.
Code of Federal Regulations, 2010 CFR
2010-07-01
... for Benzene Emissions From Benzene Storage Vessels § 61.270 Applicability and designation of sources. (a) The source to which this subpart applies is each storage vessel that is storing benzene having a... Benzene, ASTM D835-85 for Refined Benzene-485, ASTM D2359-85a or 93 for Refined Benzene-535, and ASTM...
40 CFR 61.270 - Applicability and designation of sources.
Code of Federal Regulations, 2012 CFR
2012-07-01
... for Benzene Emissions From Benzene Storage Vessels § 61.270 Applicability and designation of sources. (a) The source to which this subpart applies is each storage vessel that is storing benzene having a... Benzene, ASTM D835-85 for Refined Benzene-485, ASTM D2359-85a or 93 for Refined Benzene-535, and ASTM...
40 CFR 61.270 - Applicability and designation of sources.
Code of Federal Regulations, 2013 CFR
2013-07-01
... for Benzene Emissions From Benzene Storage Vessels § 61.270 Applicability and designation of sources. (a) The source to which this subpart applies is each storage vessel that is storing benzene having a... Benzene, ASTM D835-85 for Refined Benzene-485, ASTM D2359-85a or 93 for Refined Benzene-535, and ASTM...
Functional anion concept: effect of fluorine anion on hydrogen storage of sodium alanate.
Yin, Li-Chang; Wang, Ping; Kang, Xiang-Dong; Sun, Cheng-Hua; Cheng, Hui-Ming
2007-03-28
Doping NaAlH(4) with Ti-catalyst has produced a promising hydrogen storage system that can be reversibly operated at moderate temperature conditions. Of the various dopant precursors, TiCl(3) was well recognized due to its pronounced catalytic effect on the reversible dehydrogenation processes of sodium aluminium hydrides. Quite recently we experimentally found that TiF(3) was even better than TiCl(3) in terms of the critical hydrogen storage properties of the doped hydrides, in particular the dehydriding performance at Na(3)AlH(6)/NaH + Al step at moderate temperature. We present here the DFT calculation results of the TiF(3) or TiCl(3) doped Na(3)AlH(6). Our computational studies have demonstrated that F(-) and Cl(-) anions differ substantially from each other with regard to the state and function in the doped sodium aluminium hydride. In great contrast to the case of chloride doping where Cl(-) anion constitutes the "dead weight" NaCl, the fluoride doping results in a substitution of H(-) by F(-) anion in the hydride lattice and accordingly, a favorable thermodynamics adjustment. These results well explain the observed dehydriding performance associated with TiF(3)/TiCl(3)-doping. More significantly, the coupled computational and experimental efforts allow us to put forward a "functional anion" concept. This renews the current mechanism understanding in the catalytically enhanced sodium alanate.
NASA Astrophysics Data System (ADS)
Ke, Xiang; Zhou, Xiang; Hao, Gaozi; Xiao, Lei; Liu, Jie; Jiang, Wei
2017-06-01
One of the challenges for the application of energetic materials is their energy-retaining capabilities after long-term storage. In this study, we report a facile method to fabricate superhydrophobic Al/Fe2O3 nanothermite film by combining electrophoretic deposition and surface modification technologies. Different concentrations of dispersion solvents and additives are investigated to optimize the deposition parameters. Meanwhile, the dependence of deposition rates on nanoparticle concentrations is also studied. The surface morphology and chemical composition are characterized by field-emission scanning electron microscopy, X-ray diffraction, X-ray energy-dispersive spectroscopy, and X-ray photoelectron spectroscopy. A static contact angles as high as 156° shows the superhydrophobicity of the nanothermite film. Natural and accelerated aging tests are performed and the thermal behavior is analyzed. Thermal analysis shows that the surface modification contributes to significantly improved energy-release characteristics for both fresh and aged samples, which is supposed to be attributed to the preignition reaction between Al2O3 shell and FAS-17. Superhydrophobic Al/Fe2O3 nanothermite film exhibits excellent long-time storage stability with 83.4% of energy left in natural aging test and 60.5% in accelerated aging test. This study is instructive to the practical applications of nanothermites, especially in highly humid environment.
NASA Astrophysics Data System (ADS)
Giorio, C.; King, A. C. F.; Wolff, E. W.; Kalberer, M.; Thomas, E. R.; Mulvaney, R.
2016-12-01
Records of inorganic gases and particles trapped in ice core layers have provided some of the most important insights to our understanding of climate of the last 800,000 years. Organic compounds within the ice, however, are an un-tapped reservoir of information. In particular, two groups of compounds emitted from the terrestrial biosphere, fatty acids and terpene secondary oxidation aerosols (SOAs), display characteristics required for ice core paleoclimate reconstruction; emission rates depend on atmospheric states (e.g. temperature), compounds survive long-distance transport in the atmosphere to high altitudes and latitudes (Grannas et al., 2004; Fu et al., 2013 among others), and are shown to survive in ice layers up to 450 yrs old for fatty acids in Greenland (Kawamura et al., 1996) and 350 yrs for SOAs in Alaska (Pokhrel et al., 2015). Here, we aim to develop a single method for quantification of all compounds of interest over longer timescales and further locations using liquid chromatography (LC) ultrahigh resolution mass spectrometry (LTQ Orbitrap). Initial quantification of compound contamination from sources such as drilling fluids and storage bags, diffusing through outer ice core surfaces, suggests compound contamination is limited to the outer few mm's of ice over periods of a few months. Detection limits were in the order of 1-5 ppb for the compounds of interest, leading to the trial of pre-concentration methods using stir bar sorbtive extraction (SBSE) to facilitate detection of ppt concentration levels, as expected for these types of compounds based on previous analysis of snow samples (Pokhrel et al., 2015). Detection of these compounds seems highly viable, with promise for long-term records being achieved in the near future. Fu et al.(2013) Biogeosciences, 10(2), 653-667; Grannas et al.(2004) Global Biogeochem. Cycles, 18, GB1006; Kawamura et al.(1996) Geophys. Res. Lett., 23(19), 2665-2668; Pokhrel et al.(2015) Atmos. Environ., 130, 105-112.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Pretzsch, Gunter; Salewski, Peter; Sogalla, Martin
2013-07-01
The German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU) on behalf of the Government of the Federal Republic of Germany supports the State Nuclear Regulatory Inspectorate of Ukraine (SNRIU) in enhancement of nuclear safety and radiation protection and strengthening of the physical protection. One of the main objectives of the agreement concluded by these parties in 2008 was the retrieval and safe interim storage of disused orphan high radioactive sealed sources in Ukraine. At present, the Ukrainian National Registry does not account all high active radiation sources but only for about 70 - 80 %. GRSmore » in charge of BMU to execute the program since 2008 concluded subcontracts with the waste management and interim storage facilities RADON at different regions in Ukraine as well with the waste management and interim storage facility IZOTOP at Kiev. Below selected examples of removal of high active Co-60 and Cs-137 sources from irradiation facilities at research institutes are described. By end of 2012 removal and safe interim storage of 12.000 disused radioactive sealed sources with a total activity of more than 5,7.10{sup 14} Bq was achieved within the frame of this program. The German support program will be continued up to the end of 2013 with the aim to remove and safely store almost all disused radioactive sealed sources in Ukraine. (authors)« less
Copeland, Curtis C; Beers, Benjamin B; Thompson, Meghan R; Fitzgerald, Relana P; Barrett, Leah J; Sevilleja, Jesus E; Alencar, Sayonara; Lima, Aldo A M; Guerrant, Richard L
2009-06-01
Worldwide, contaminated drinking water poses a major health threat, particularly to child development. Diarrhoea represents a large part of the water-related disease burden and enteric infections have been linked to nutritional and growth shortfalls as well as long-term physical and cognitive impairment in children. Previous studies detailed the frequency of infection and the consequences for child health in a shanty town in north-east Brazil. To determine the frequency of contaminated water, we measured faecal contamination in primary drinking water samples from 231 randomly selected households. Risk for contamination was compared across source and storage types. Nearly a third of the study households (70/231: 30.3%) had contaminated drinking water; the source with the highest frequency of contamination was well water (23/24: 95.8%). For tap water, the type of storage had a significant effect on the susceptibility to contamination (chi(2) = 12.090; p = 0.007). The observed pattern of contamination demonstrated the relative potential contributions of both source and storage. With evidence that supports the inclusion of source and storage in water quality surveys, this study, like others, suggests that contaminated drinking water in storage vessels may be an important factor for the documented diarrhoea disease burden in the Brazilian shanty town.
Monitoring fossil fuel sources of methane in Australia
NASA Astrophysics Data System (ADS)
Loh, Zoe; Etheridge, David; Luhar, Ashok; Hibberd, Mark; Thatcher, Marcus; Noonan, Julie; Thornton, David; Spencer, Darren; Gregory, Rebecca; Jenkins, Charles; Zegelin, Steve; Leuning, Ray; Day, Stuart; Barrett, Damian
2017-04-01
CSIRO has been active in identifying and quantifying methane emissions from a range of fossil fuel sources in Australia over the past decade. We present here a history of the development of our work in this domain. While we have principally focused on optimising the use of long term, fixed location, high precision monitoring, paired with both forward and inverse modelling techniques suitable either local or regional scales, we have also incorporated mobile ground surveys and flux calculations from plumes in some contexts. We initially developed leak detection methodologies for geological carbon storage at a local scale using a Bayesian probabilistic approach coupled to a backward Lagrangian particle dispersion model (Luhar et al. JGR, 2014), and single point monitoring with sector analysis (Etheridge et al. In prep.) We have since expanded our modelling techniques to regional scales using both forward and inverse approaches to constrain methane emissions from coal mining and coal seam gas (CSG) production. The Surat Basin (Queensland, Australia) is a region of rapidly expanding CSG production, in which we have established a pair of carefully located, well-intercalibrated monitoring stations. These data sets provide an almost continuous record of (i) background air arriving at the Surat Basin, and (ii) the signal resulting from methane emissions within the Basin, i.e. total downwind methane concentration (comprising emissions including natural geological seeps, agricultural and biogenic sources and fugitive emissions from CSG production) minus background or upwind concentration. We will present our latest results on monitoring from the Surat Basin and their application to estimating methane emissions.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Luo, Jinyong; Gao, Feng; Kim, Do Heui
2014-03-31
The effects of K loading and thermal aging on the structural properties and high temperature performance of Pt/K/Al2O3 lean NOx trap (LNT) catalysts were investigated using in situ X-ray diffraction (XRD), temperature-programmed decomposition/desorption of NOx (NOx-TPD), transmission electron microscopy (TEM), NO oxidation and NOx storage tests. In situ XRD results demonstrate that KNO3 becomes extremely mobile on the Al2O3 surface, and experiences complex transformations between orthorhombic and rhombohedral structures, accompanied by sintering, melting and thermal decomposition upon heating. NOx storage results show an optimum K loading around 10% for the best performance at high temperatures. At lower K loadings wheremore » the majority of KNO3 stays as a surface layer, the strong interaction between KNO3 and Al2O3 promotes KNO3 decomposition and deteriorates high-temperature performance. At K loadings higher than 10%, the performance drop is not caused by NOx diffusion limitations as for the case of barium-based LNTs, but rather from the blocking of Pt sites by K species, which adversely affects NO oxidation. Thermal aging at 800 ºC severely deactivates the Pt/K/Al2O3 catalysts due to Pt sintering. However, in the presence of potassium, some Pt remains in a dispersed and oxidized form. These Pt species interact strongly with K and, therefore, do not sinter. After a reduction treatment, these Pt species remain finely dispersed, contributing to a partial recovery of NOx storage performance.« less
Industrial-scale storage of CO2 in saline sedimentary basins will cause zones of elevated pressure, larger than the CO2 plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards al...
Sodium-based hydrides for thermal energy applications
NASA Astrophysics Data System (ADS)
Sheppard, D. A.; Humphries, T. D.; Buckley, C. E.
2016-04-01
Concentrating solar-thermal power (CSP) with thermal energy storage (TES) represents an attractive alternative to conventional fossil fuels for base-load power generation. Sodium alanate (NaAlH4) is a well-known sodium-based complex metal hydride but, more recently, high-temperature sodium-based complex metal hydrides have been considered for TES. This review considers the current state of the art for NaH, NaMgH3- x F x , Na-based transition metal hydrides, NaBH4 and Na3AlH6 for TES and heat pumping applications. These metal hydrides have a number of advantages over other classes of heat storage materials such as high thermal energy storage capacity, low volume, relatively low cost and a wide range of operating temperatures (100 °C to more than 650 °C). Potential safety issues associated with the use of high-temperature sodium-based hydrides are also addressed.
Code of Federal Regulations, 2010 CFR
2010-07-01
... Categories Priority Number 1 Source Category 1. Synthetic Organic Chemical Manufacturing Industry (SOCMI) and Volatile Organic Liquid Storage Vessels and Handling Equipment (a) SOCMI unit processes (b) Volatile organic liquid (VOL) storage vessels and handling equipment (c) SOCMI fugitive sources (d) SOCMI secondary...
Acorn storage alternatives tested on Oregon white oak
Warren D. Devine; Constance A. Harrington; Joseph M. Kraft
2010-01-01
We assessed various combinations of storage factors: bag type, temperature, duration, and antifungal pre-storage treatments for white oak acorn storage, using Oregon white oak (Quercus garryana Douglas ex Hook. [Fagaceae]) acorns from 7 seed sources. Acorn viability remained high (84%), even after 2 y of refrigerated storage, but the majority of...
40 CFR 63.1432 - Storage vessel provisions.
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Storage vessel provisions. 63.1432....1432 Storage vessel provisions. (a) For each storage vessel located at an affected source, the owner or operator shall comply with the HON storage vessel requirements of §§ 63.119 through 63.123 and the HON leak...
Deichsel, Katharina; Schrammel, Nadine; Aurich, Jörg; Aurich, Christine
2016-04-01
Increasing day length in spring stimulates reproductive functions in horses. In this study, we have analysed the effect of artificial long days on the quality of cooled-stored and cryopreserved semen in Shetland stallions. Stallions of the treatment group (AL, n = 8) were exposed to 16 h light and 8h darkness from 15th December to 20th March while control stallions (CON, n = 7) were kept under natural photoperiod. Semen was collected once weekly and processed for cooled-storage and cryopreservation once per month. Total and progressive motility and percentage of membrane intact spermatozoa were analysed at 24, 48 and 72 h of cooled-storage and after freezing-thawing, respectively. Total and progressive motility and membrane integrity decreased during cooled-storage for 72 h in each month and both groups (p < 0.001). All these parameters were lower in CON versus AL stallions (p < 0.05) and the decrease was more pronounced in group CON (storage time x group p < 0.05). Differences between groups decreased throughout the observation period from January (p < 0.05 between groups) to July (e.g. total motility after 72 h of cooled-storage in January for group AL 80 ± 3 and group CON 49 ± 12%, respective values in July, 83 ± 2 and 72 ± 6%). Neither total and progressive motility nor percentage of membrane-intact and morphologically defect spermatozoa in frozen-thawed semen differed between groups and months. In conclusion, motility of cooled-stored semen was reduced in January and increased in stallions kept under a long day light programme for at least 30 days. Copyright © 2016 Elsevier B.V. All rights reserved.
Magmatic plumbing system of Kilauea Volcano: Insights from Petrologic and Geochemical Monitoring
NASA Astrophysics Data System (ADS)
Garcia, M. O.; Pietruszka, A. J.; Marske, J.; Greene, A.; Lynn, K. J.
2016-12-01
Monitoring the petrology and geochemistry of lavas from active volcanoes in near realtime affords the opportunity to formulate and evaluate models for magma transport, mixing, and storage to help predict eruption scenarios with greater confidence and better understand magmatic plumbing systems (e.g., Poland et al. 2012, Nat. Geosci. 5, 295-300). Continous petrologic and geochemical monitoring of two ongoing eruptions at the summit and east rift zone of Kilauea Volcano on the Island of Hawaii have revealed much about the dynamics of magmatic processes. When the composition of lava shifted to a more MgO-rich composition in April 1983, we predicted that the Puu Oo eruption would not be short-lived. We had no idea it would continue for over 33 years. Subsequent changes in lava composition have highlighted the interplay between mixing pockets of rift-zone stored magma with new mantle-derived magma and the cooling-induced crystal fractionation during brief (usually days) eruption hiatuses. Surprisingly, the mantle derived magma has continued to change in composition including several 10-year cycles in Pb isotope ratios superimposed on a progressive depletion in highly incompatible elements (Greene et al. 2013, G3, doi: 10.1002/ggge.20285). These compositional trends are contrary to those observed for sustained basaltic eruptions on continents and argue for melt extraction from a multi-component source with 1-3 km wide heterogeneities. Compositional zoning within olivine phenocrysts, created by diffusive re-equilibration, also provide insights into magma mixing, storage, and transport at Kilauea. Timescales modeling of Fe-Mg and Ni concentration gradients within Puu Oo olivine indicate that crystals can be stored at magmatic temperatures for months to a few years before eruption (Shea et al. 2015, Geology 43, 935-938). Kilauea's ongoing eruptions continue to provide a dynamic laboratory for positing and testing models for the generation and evolution of basaltic magma.
NASA Astrophysics Data System (ADS)
Rosenberg, R. A.; McDowell, M. W.; Ma, Q.; Harkay, K. C.
2003-09-01
It is well known that exposure to an accelerator environment can cause ``conditioning'' of the vacuum chamber surfaces. In order to understand the manner in which the surface structure might influence the production of gases and electrons in the accelerator, such surfaces should be studied both before and after exposure to accelerator conditions. Numerous studies have been performed on representative materials prior to being inserted into an accelerator, but very little has been done on materials that have ``lived'' in the accelerator for extended periods. In the present work, we mounted Al and Cu coupons at different positions in a section of the Advanced Photon Source storage ring and removed them following exposures ranging from 6 to 18 months. X-ray photoelectron spectroscopy (XPS) of the surface was performed before and after exposure. Changes were observed that depended on the location and whether the coupon was facing the chamber interior or chamber wall. These results will be presented and compared to XPS and secondary electron yield data obtained from laboratory measurements meant to simulate the accelerator conditions.
Operation mode switchable charge-trap memory based on few-layer MoS2
NASA Astrophysics Data System (ADS)
Hou, Xiang; Yan, Xiao; Liu, Chunsen; Ding, Shijin; Zhang, David Wei; Zhou, Peng
2018-03-01
Ultrathin layered two-dimensional (2D) semiconductors like MoS2 and WSe2 have received a lot of attention because of their excellent electrical properties and potential applications in electronic devices. We demonstrate a charge-trap memory with two different tunable operation modes based on a few-layer MoS2 channel and an Al2O3/HfO2/Al2O3 charge storage stack. Our device shows excellent memory properties under the traditional three-terminal operation mode. More importantly, unlike conventional charge-trap devices, this device can also realize the memory performance with just two terminals (drain and source) because of the unique atomic crystal electrical characteristics. Under the two-terminal operation mode, the erase/program current ratio can reach up to 104 with a stable retention property. Our study indicates that the conventional charge-trap memory cell can also realize the memory performance without the gate terminal based on novel two dimensional materials, which is meaningful for low power consumption and high integration density applications.
Specific storage volumes: A useful tool for CO2 storage capacity assessment
Brennan, S.T.; Burruss, R.C.
2006-01-01
Subsurface geologic strata have the potential to store billions of tons of anthropogenic CO2; therefore, geologic carbon sequestration can be an effective mitigation tool used to slow the rate at which levels of atmospheric CO2 are increasing. Oil and gas reservoirs, coal beds, and saline reservoirs can be used for CO2 storage; however, it is difficult to assess and compare the relative storage capacities of these different settings. Typically, CO2 emissions are reported in units of mass, which are not directly applicable to comparing the CO2 storage capacities of the various storage targets. However, if the emission values are recalculated to volumes per unit mass (specific volume) then the volumes of geologic reservoirs necessary to store CO2 emissions from large point sources can be estimated. The factors necessary to convert the mass of CO2 emissions to geologic storage volume (referred to here as Specific Storage Volume or 'SSV') can be reported in units of cubic meters, cubic feet, and petroleum barrels. The SSVs can be used to estimate the reservoir volume needed to store CO2 produced over the lifetime of an individual point source, and to identify CO2 storage targets of sufficient size to meet the demand from that given point source. These storage volumes also can then be projected onto the land surface to outline a representative "footprint," which marks the areal extent of storage. This footprint can be compared with the terrestrial carbon sequestration capacity of the same land area. The overall utility of this application is that the total storage capacity of any given parcel of land (from surface to basement) can be determined, and may assist in making land management decisions. ?? Springer Science+Business Media, LLC 2006.
Source-sink-storage relationships of conifers
DOE Office of Scientific and Technical Information (OSTI.GOV)
Luxmoore, R.J.; Oren, R.; Sheriff, D.W.
1995-07-01
Irradiance, air temperature, saturation vapor pressure deficit, and soil temperature vary in association with Earth`s daily rotation, inducing significant hourly changes in the rates of plant physiological processes. These processes include carbon fixation in photosynthesis, sucrose translocation, and carbon utilization in growth, storage, and respiration. The sensitivity of these physiological processes to environmental factors such as temperature, soil water availability, and nutrient supply reveals differences that must be viewed as an interactive whole in order to comprehend whole-plant responses to the environment. Integrative frameworks for relationships between plant physiological processes are needed to provide syntheses of plant growth and development.more » Source-sink-storage relationships, addressed in this chapter, provide one framework for synthesis of whole-plant responses to external environmental variables. To address this issue, some examples of carbon assimilation and utilization responses of five conifer species to environmental factors from a range of field environments are first summarized. Next, the interactions between sources, sinks, and storages of carbon are examined at the leaf and tree scales, and finally, the review evaluates the proposition that processes involved with carbon utilization (sink activity) are more sensitive to the supply of water and nutrients (particularly nitrogen) than are the processes of carbon gain (source activity) and carbon storage. The terms {open_quotes}sink{close_quotes} and {open_quotes}source{close_quotes} refer to carbon utilization and carbon gain, respectively. The relative roles of stored carbon reserves and of current photosynthate in meeting sink demand are addressed. Discussions focus on source-sink-storage relationships within the diurnal, wetting-drying, and annual cycles of conifer growth and development, and some discussion of life cycle aspects is also presented.« less
High Coulombic efficiency aluminum-ion battery using an AlCl3-urea ionic liquid analog electrolyte
Angell, Michael; Pan, Chun-Jern; Rong, Youmin; Yuan, Chunze; Lin, Meng-Chang; Hwang, Bing-Joe; Dai, Hongjie
2017-01-01
In recent years, impressive advances in harvesting renewable energy have led to a pressing demand for the complimentary energy storage technology. Here, a high Coulombic efficiency (∼99.7%) Al battery is developed using earth-abundant aluminum as the anode, graphite as the cathode, and a cheap ionic liquid analog electrolyte made from a mixture of AlCl3 and urea in a 1.3:1 molar ratio. The battery displays discharge voltage plateaus around 1.9 and 1.5 V (average discharge = 1.73 V) and yielded a specific cathode capacity of ∼73 mAh g−1 at a current density of 100 mA g−1 (∼1.4 C). High Coulombic efficiency over a range of charge–discharge rates and stability over ∼150–200 cycles was easily demonstrated. In situ Raman spectroscopy clearly showed chloroaluminate anion intercalation/deintercalation of graphite (positive electrode) during charge–discharge and suggested the formation of a stage 2 graphite intercalation compound when fully charged. Raman spectroscopy and NMR suggested the existence of AlCl4−, Al2Cl7− anions and [AlCl2·(urea)n]+ cations in the AlCl3/urea electrolyte when an excess of AlCl3 was present. Aluminum deposition therefore proceeded through two pathways, one involving Al2Cl7− anions and the other involving [AlCl2·(urea)n]+ cations. This battery is a promising prospect for a future high-performance, low-cost energy storage device. PMID:28096353
Counting the Photons: Determining the Absolute Storage Capacity of Persistent Phosphors
Rodríguez Burbano, Diana C.; Capobianco, John A.
2017-01-01
The performance of a persistent phosphor is often determined by comparing luminance decay curves, expressed in cd/m2. However, these photometric units do not enable a straightforward, objective comparison between different phosphors in terms of the total number of emitted photons, as these units are dependent on the emission spectrum of the phosphor. This may lead to incorrect conclusions regarding the storage capacity of the phosphor. An alternative and convenient technique of characterizing the performance of a phosphor was developed on the basis of the absolute storage capacity of phosphors. In this technique, the phosphor is incorporated in a transparent polymer and the measured afterglow is converted into an absolute number of emitted photons, effectively quantifying the amount of energy that can be stored in the material. This method was applied to the benchmark phosphor SrAl2O4:Eu,Dy and to the nano-sized phosphor CaS:Eu. The results indicated that only a fraction of the Eu ions (around 1.6% in the case of SrAl2O4:Eu,Dy) participated in the energy storage process, which is in line with earlier reports based on X-ray absorption spectroscopy. These findings imply that there is still a significant margin for improving the storage capacity of persistent phosphors. PMID:28773228
Characteristics of phase-change materials containing oxide nano-additives for thermal storage.
Teng, Tun-Ping; Yu, Chao-Chieh
2012-11-06
In this study, the authors report the production of nanocomposite-enhanced phase-change materials (NEPCMs) using the direct-synthesis method by mixing paraffin with alumina (Al2O3), titania (TiO2), silica (SiO2), and zinc oxide (ZnO) as the experimental samples. Al2O3, TiO2, SiO2, and ZnO were dispersed into three concentrations of 1.0, 2.0, and 3.0 wt.%. Through heat conduction and differential scanning calorimeter experiments to evaluate the effects of varying concentrations of the nano-additives on the heat conduction performance and thermal storage characteristics of NEPCMs, their feasibility for use in thermal storage was determined. The experimental results demonstrate that TiO2 is more effective than the other additives in enhancing both the heat conduction and thermal storage performance of paraffin for most of the experimental parameters. Furthermore, TiO2 reduces the melting onset temperature and increases the solidification onset temperature of paraffin. This allows the phase-change heat to be applicable to a wider temperature range, and the highest decreased ratio of phase-change heat is only 0.46%, compared to that of paraffin. Therefore, this study demonstrates that TiO2, added to paraffin to form NEPCMs, has significant potential for enhancing the thermal storage characteristics of paraffin.
USDA-ARS?s Scientific Manuscript database
Aims: Nitrogen is a critical element in industrial fermentation media. This study investigated the influence of various nitrogen sources on blastospore production, tolerance to anhydrobiosis stress, and storage stability using two strains of the cosmopolitan insect pathogenic fungus Beauveria bassia...
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Group 1 Storage Vessels at New Affected Sources Producing the Listed Thermoplastics 5 Table 5 to Subpart JJJ of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Group 1 Storage Vessels at New Affected Sources Producing the Listed Thermoplastics 5 Table 5 to Subpart JJJ of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 12 2014-07-01 2014-07-01 false Group 1 Storage Vessels at New Affected Sources Producing the Listed Thermoplastics 5 Table 5 to Subpart JJJ of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Group 1 Storage Vessels at New Affected Sources Producing the Listed Thermoplastics 5 Table 5 to Subpart JJJ of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 12 2012-07-01 2011-07-01 true Group 1 Storage Vessels at New Affected Sources Producing the Listed Thermoplastics 5 Table 5 to Subpart JJJ of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...
40 CFR 63.1404 - Storage vessel provisions.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Storage vessel provisions. 63.1404... Standards for Hazardous Air Pollutant Emissions: Manufacture of Amino/Phenolic Resins § 63.1404 Storage vessel provisions. (a) Emission standards. For each storage vessel located at a new affected source that...
40 CFR 63.1404 - Storage vessel provisions.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Storage vessel provisions. 63.1404... Standards for Hazardous Air Pollutant Emissions: Manufacture of Amino/Phenolic Resins § 63.1404 Storage vessel provisions. (a) Emission standards. For each storage vessel located at a new affected source that...
Molecular dynamical simulations of melting Al nanoparticles using a reaxff reactive force field
NASA Astrophysics Data System (ADS)
Liu, Junpeng; Wang, Mengjun; Liu, Pingan
2018-06-01
Molecular dynamics simulations were performed to study thermal properties and melting points of Al nanoparticles by using a reactive force field under canonical (NVT) ensembles. Al nanoparticles (particle size 2–4 nm) were considered in simulations. A combination of structural and thermodynamic parameters such as the Lindemann index, heat capacities, potential energy and radial-distribution functions was employed to decide melting points. We used annealing technique to obtain the initial Al nanoparticle model. Comparison was made between ReaxFF results and other simulation results. We found that ReaxFF force field is reasonable to describe Al cluster melting behavior. The linear relationship between particle size and melting points was found. After validating the ReaxFF force field, more attention was paid on thermal properties of Al nanoparticles with different defect concentrations. 4 nm Al nanoparticles with different defect concentrations (5%–20%) were considered in this paper. Our results revealed that: the melting points are irrelevant with defect concentration at a certain particle size. The extra storage energy of Al nanoparticles is proportional to nanoparticles’ defect concentration, when defect concentration is 5%–15%. While the particle with 20% defect concentration is similar to the cluster with 10% defect concentration. After melting, the extra energy of all nanoparticles decreases sharply, and the extra storage energy is nearly zero at 600 K. The centro-symmetry parameter analysis shows structure evolution of different models during melting processes.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Houssainy, Sammy; Janbozorgi, Mohammad; Kavehpour, Pirouz
Compressed Air Energy Storage (CAES) can potentially allow renewable energy sources to meet electricity demands as reliably as coal-fired power plants. However, conventional CAES systems rely on the combustion of natural gas, require large storage volumes, and operate at high pressures, which possess inherent problems such as high costs, strict geological locations, and the production of greenhouse gas emissions. A novel and patented hybrid thermal-compressed air energy storage (HT-CAES) design is presented which allows a portion of the available energy, from the grid or renewable sources, to operate a compressor and the remainder to be converted and stored in themore » form of heat, through joule heating in a sensible thermal storage medium. The HT-CAES design incudes a turbocharger unit that provides supplementary mass flow rate alongside the air storage. The hybrid design and the addition of a turbocharger have the beneficial effect of mitigating the shortcomings of conventional CAES systems and its derivatives by eliminating combustion emissions and reducing storage volumes, operating pressures, and costs. Storage efficiency and cost are the two key factors, which upon integration with renewable energies would allow the sources to operate as independent forms of sustainable energy. The potential of the HT-CAES design is illustrated through a thermodynamic optimization study, which outlines key variables that have a major impact on the performance and economics of the storage system. The optimization analysis quantifies the required distribution of energy between thermal and compressed air energy storage, for maximum efficiency, and for minimum cost. This study provides a roundtrip energy and exergy efficiency map of the storage system and illustrates a trade off that exists between its capital cost and performance.« less
Management of Ir-192 Disused Sealed Sources with Long-Lived Radioactive Contaminants
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dellamano, Jose Claudio; Ferreira, Robson de Jesus; Potiens, Ademar Jose Jr.
2015-07-01
Iridium-192 sealed sources are the most widely used sealed source in industrial applications in Brazil. They are not recyclable and in the end of the useful life, they are discarded as radioactive waste. The recommended management strategy of this waste is decay in storage and disposal as exempt waste because the half-life is only 73.8 days. Presently, thousands of Ir- 192 sources are under storage waiting release. Surprisingly, sources that were under storage for more than ten years and for which no measurable contact dose rate was expected still present significant remaining radioactivity. The examination of the gamma spectra ofmore » these sources showed the presence of Co-60 and the gamma emission lines from the Ir-192m2 isomer, the metastable isotope with half-life of 241 years, which is also formed by the irradiation of natural iridium. The aim of the study reported in this paper is to characterize the Ir-192 disused sources under interim storage at the Radioactive Waste Management Department, considering the presence of minor contaminants in the irradiated iridium and the fraction of the total initial activity of the sources that is attributable to that metastable isotope. The radioactive inventories at the end of the irradiation and after the decay period were predicted using the Scale 6.0 code and the results were compared with activity measurements of the disused sources by gamma spectrometry. (authors)« less
Chou, C C; Cheng, S J
2000-11-01
This study was conducted to investigate the alteration of some characteristics of E. coli O157:H7 subjected to various periods of storage at -5, -18 and -28 degrees C. Results revealed that the low-temperature treatments increased the susceptibility of E. coli O157:H7 to crystal violet, bile salt, sodium chloride and ethanol. In general, the susceptibility of E. coli O157:H7 subjected to storage at -18 degrees C increased most significantly. The susceptibility of E. coli O157:H7 to the tested agents increased as the period of low-temperature storage extended, regardless of storage temperature. Among the various nitrogen and carbon sources tested, tryptone and soytone were the most effective nitrogen sources, while glucose and maltose were the most effective carbon sources for the growth of the low-temperature stressed cells. When growing the stressed E. coli O157:H7 in media containing the same nitrogen source or carbon source, their lag period increased as the time of frozen storage increased. It was also noted that in general, the recovery of the low-temperature stressed E. coli O157:H7 was highest on tryptic soy agar followed by Modified eosin methylene blue agar, while recovery on MaConkey sorbitol agar and Modified MaConkey sorbitol agar was lowest.
40 CFR 63.1314 - Storage vessel provisions.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Storage vessel provisions. 63.1314... Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins § 63.1314 Storage vessel provisions. (a) This section applies to each storage vessel that is assigned to an affected source, as...
40 CFR 63.484 - Storage vessel provisions.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Storage vessel provisions. 63.484... Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins § 63.484 Storage vessel provisions. (a) This section applies to each storage vessel that is assigned to an affected source, as...
40 CFR 63.1432 - Storage vessel provisions.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Storage vessel provisions. 63.1432... Standards for Hazardous Air Pollutant Emissions for Polyether Polyols Production § 63.1432 Storage vessel provisions. (a) For each storage vessel located at an affected source, the owner or operator shall comply...
40 CFR 63.484 - Storage vessel provisions.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Storage vessel provisions. 63.484... Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins § 63.484 Storage vessel provisions. (a) This section applies to each storage vessel that is assigned to an affected source, as...
40 CFR 63.484 - Storage vessel provisions.
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Storage vessel provisions. 63.484... Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins § 63.484 Storage vessel provisions. (a) This section applies to each storage vessel that is assigned to an affected source, as...
40 CFR 63.484 - Storage vessel provisions.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Storage vessel provisions. 63.484... Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins § 63.484 Storage vessel provisions. (a) This section applies to each storage vessel that is assigned to an affected source, as...
40 CFR 63.1314 - Storage vessel provisions.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Storage vessel provisions. 63.1314... Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins § 63.1314 Storage vessel provisions. (a) This section applies to each storage vessel that is assigned to an affected source, as...
40 CFR 63.1432 - Storage vessel provisions.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Storage vessel provisions. 63.1432... Standards for Hazardous Air Pollutant Emissions for Polyether Polyols Production § 63.1432 Storage vessel provisions. (a) For each storage vessel located at an affected source, the owner or operator shall comply...
Code of Federal Regulations, 2013 CFR
2013-01-01
... devices, transport and storage containers, associated equipment, source changers, and survey instruments... changers, and survey instruments. (a) The licensee shall perform visual and operability checks on survey... condition, that the sources are adequately shielded, and that required labeling is present. Survey...
Code of Federal Regulations, 2011 CFR
2011-01-01
... devices, transport and storage containers, associated equipment, source changers, and survey instruments... changers, and survey instruments. (a) The licensee shall perform visual and operability checks on survey... condition, that the sources are adequately shielded, and that required labeling is present. Survey...
Code of Federal Regulations, 2014 CFR
2014-01-01
... devices, transport and storage containers, associated equipment, source changers, and survey instruments... changers, and survey instruments. (a) The licensee shall perform visual and operability checks on survey... condition, that the sources are adequately shielded, and that required labeling is present. Survey...
Code of Federal Regulations, 2012 CFR
2012-01-01
... devices, transport and storage containers, associated equipment, source changers, and survey instruments... changers, and survey instruments. (a) The licensee shall perform visual and operability checks on survey... condition, that the sources are adequately shielded, and that required labeling is present. Survey...
Code of Federal Regulations, 2010 CFR
2010-01-01
... devices, transport and storage containers, associated equipment, source changers, and survey instruments... changers, and survey instruments. (a) The licensee shall perform visual and operability checks on survey... condition, that the sources are adequately shielded, and that required labeling is present. Survey...
40 CFR Table 9 to Subpart Uuuu of... - Recordkeeping Requirements
Code of Federal Regulations, 2010 CFR
2010-07-01
... process affected source records of nitrogen unloading and storage systems or nitrogen unloading systems records certifying that a nitrogen unloading and storage system or nitrogen unloading system is in use. 9. an existing or new viscose process affected source records of material balances all pertinent data...
40 CFR Table 9 to Subpart Uuuu of... - Recordkeeping Requirements
Code of Federal Regulations, 2012 CFR
2012-07-01
... process affected source records of nitrogen unloading and storage systems or nitrogen unloading systems records certifying that a nitrogen unloading and storage system or nitrogen unloading system is in use. 9. an existing or new viscose process affected source records of material balances all pertinent data...
40 CFR Table 9 to Subpart Uuuu of... - Recordkeeping Requirements
Code of Federal Regulations, 2013 CFR
2013-07-01
... process affected source records of nitrogen unloading and storage systems or nitrogen unloading systems records certifying that a nitrogen unloading and storage system or nitrogen unloading system is in use. 9. an existing or new viscose process affected source records of material balances all pertinent data...
40 CFR Table 9 to Subpart Uuuu of... - Recordkeeping Requirements
Code of Federal Regulations, 2014 CFR
2014-07-01
... process affected source records of nitrogen unloading and storage systems or nitrogen unloading systems records certifying that a nitrogen unloading and storage system or nitrogen unloading system is in use. 9. an existing or new viscose process affected source records of material balances all pertinent data...
40 CFR Table 9 to Subpart Uuuu of... - Recordkeeping Requirements
Code of Federal Regulations, 2011 CFR
2011-07-01
... process affected source records of nitrogen unloading and storage systems or nitrogen unloading systems records certifying that a nitrogen unloading and storage system or nitrogen unloading system is in use. 9. an existing or new viscose process affected source records of material balances all pertinent data...
40 CFR 61.130 - Applicability, designation of sources, and delegation of authority.
Code of Federal Regulations, 2012 CFR
2012-07-01
... National Emission Standard for Benzene Emissions from Coke By-Product Recovery Plants § 61.130... each of the following sources at furnace and foundry coke by-product recovery plants: tar decanters... tanks, light-oil storage tanks, and excess ammonia-liquor storage tanks at furnace coke by-product...
40 CFR 61.130 - Applicability, designation of sources, and delegation of authority.
Code of Federal Regulations, 2013 CFR
2013-07-01
... National Emission Standard for Benzene Emissions from Coke By-Product Recovery Plants § 61.130... each of the following sources at furnace and foundry coke by-product recovery plants: tar decanters... tanks, light-oil storage tanks, and excess ammonia-liquor storage tanks at furnace coke by-product...
40 CFR 61.130 - Applicability, designation of sources, and delegation of authority.
Code of Federal Regulations, 2011 CFR
2011-07-01
... National Emission Standard for Benzene Emissions from Coke By-Product Recovery Plants § 61.130... each of the following sources at furnace and foundry coke by-product recovery plants: tar decanters... tanks, light-oil storage tanks, and excess ammonia-liquor storage tanks at furnace coke by-product...
40 CFR 61.130 - Applicability, designation of sources, and delegation of authority.
Code of Federal Regulations, 2014 CFR
2014-07-01
... National Emission Standard for Benzene Emissions from Coke By-Product Recovery Plants § 61.130... each of the following sources at furnace and foundry coke by-product recovery plants: tar decanters... tanks, light-oil storage tanks, and excess ammonia-liquor storage tanks at furnace coke by-product...
10 CFR 34.23 - Locking of radiographic exposure devices, storage containers and source changers.
Code of Federal Regulations, 2014 CFR
2014-01-01
... 10 Energy 1 2014-01-01 2014-01-01 false Locking of radiographic exposure devices, storage containers and source changers. 34.23 Section 34.23 Energy NUCLEAR REGULATORY COMMISSION LICENSES FOR INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment...
10 CFR 34.23 - Locking of radiographic exposure devices, storage containers and source changers.
Code of Federal Regulations, 2010 CFR
2010-01-01
... 10 Energy 1 2010-01-01 2010-01-01 false Locking of radiographic exposure devices, storage containers and source changers. 34.23 Section 34.23 Energy NUCLEAR REGULATORY COMMISSION LICENSES FOR INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment...
10 CFR 34.23 - Locking of radiographic exposure devices, storage containers and source changers.
Code of Federal Regulations, 2013 CFR
2013-01-01
... 10 Energy 1 2013-01-01 2013-01-01 false Locking of radiographic exposure devices, storage containers and source changers. 34.23 Section 34.23 Energy NUCLEAR REGULATORY COMMISSION LICENSES FOR INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment...
10 CFR 34.23 - Locking of radiographic exposure devices, storage containers and source changers.
Code of Federal Regulations, 2012 CFR
2012-01-01
... 10 Energy 1 2012-01-01 2012-01-01 false Locking of radiographic exposure devices, storage containers and source changers. 34.23 Section 34.23 Energy NUCLEAR REGULATORY COMMISSION LICENSES FOR INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment...
10 CFR 34.23 - Locking of radiographic exposure devices, storage containers and source changers.
Code of Federal Regulations, 2011 CFR
2011-01-01
... 10 Energy 1 2011-01-01 2011-01-01 false Locking of radiographic exposure devices, storage containers and source changers. 34.23 Section 34.23 Energy NUCLEAR REGULATORY COMMISSION LICENSES FOR INDUSTRIAL RADIOGRAPHY AND RADIATION SAFETY REQUIREMENTS FOR INDUSTRIAL RADIOGRAPHIC OPERATIONS Equipment...
40 CFR 61.130 - Applicability, designation of sources, and delegation of authority.
Code of Federal Regulations, 2010 CFR
2010-07-01
... National Emission Standard for Benzene Emissions from Coke By-Product Recovery Plants § 61.130... each of the following sources at furnace and foundry coke by-product recovery plants: tar decanters... tanks, light-oil storage tanks, and excess ammonia-liquor storage tanks at furnace coke by-product...
NASA Astrophysics Data System (ADS)
Sutanudjaja, Edwin H.; van Beek, Ludovicus P. H.; Wada, Yoshihide; Wisser, Dominik; de Graaf, Inge E. M.; Straatsma, Menno W.; Bierkens, Marc F. P.
2014-05-01
PCR-GLOBWB (PCRaster Global Water Balance) is a grid-based global hydrological model developed at the Department of Physical Geography, Utrecht University. For each grid cell, PCR-GLOBWB simulates moisture storage in vertically stacked soil layers, as well as the water exchange to the atmosphere and underlying groundwater reservoir. Exchange to the atmosphere comprises of precipitation, evaporation and transpiration, as well as snow accumulation and melt. All fluxes are all simulated by considering vegetation phenology and sub-grid variations in elevation, land cover and soil saturation. The model includes physically-based schemes for runoff-infiltration partitioning, interflow, groundwater recharge and baseflow, as well as river routing of discharge. Here we present and summarize the latest developments of PCR-GLOBWB. The new version of the model, PCR-GLOBWB 2.0, now runs at a spatial resolution of 5 arc min (about 10 km at the equator) and supersedes the previous generation of the model (30 arc min PCR-GLOBWB 1.0, van Beek et al., 2011). PCR-GLOBWB 2.0 consolidates all components that have been introduced since PCR-GLOWB 1.0 was first published (2011). Examples of these new components are: A comprehensive water demand and irrigation module (Wada et al., 2012). A dynamic attribution and return flow of water demand to surface water and groundwater resources (de Graaf et al., 2013). An advanced surface water routing scheme with wetland, lakes and floodplains of variable extent, thus simulating flooding and flood wave attenuation (Winsemius et al., 2013). An online scheme for dynamic withdrawal, allocation and consumptive use of groundwater and surface water resources, including a progressive introduction of reservoirs (Wada et al., 2013). Further development will include the inclusion of a dynamic reservoir operation/optimization scheme and a MODFLOW lateral groundwater flow module (Sutanudjaja et al., 2011; Sutanudjaja et al., 2014). Also, scripts used for deriving the parameterization from global data sources for the original model have been coupled with the model, resulting in a near-scalable model that facilitates its application for different domains and at varying resolutions. Results are very promising. When comparing simulated discharges to those observed by GRDC stations, the coefficient-of-determination is high. Human impacts, altering the seasonal and inter-annual variability of terrestrial water storage (TWS) signals, are well simulated by PCR-GLOBWB 2.0 and evident in the validation of simulated TWS with GRACE satellite observation (Tapley et al., 2004). Moreover, the simulation results of PCR-GLOBWB 2.0 compare well to several other remote sensing products, such as the soil moisture datasets of ERS/MetOp (Wagner et al., 1999) and AMSR-E (de Jeu and Owe, 2003), as well as the GLEAM evaporation product (Miralles et al., 2011). References: de Graaf et al., Advances in Water Resources (2013), http://dx.doi.org/10.1016/j.advwatres.2013.12.002 de Jeu and Owe, International Journal of Remote Sensing (2003), http://dx.doi.org/10.1080/0143116031000095934 Miralles et al., Hydrology and Earth System Sciences (2011), http://dx.doi.org/10.5194/hess-15-967-2011 Sutanudjaja et al., Hydrology and Earth System Sciences (2011), http://dx.doi.org/10.5194/hess-15-2913-2011 Sutanudjaja et al., Water Resources Research (2014), http://dx.doi.org/10.1002/2013WR013807 Tapley et al., Science (2004), http://dx.doi.org/10.1126/science.1099192 van Beek et al., Water Resources Research (2011), http://dx.doi.org/10.1029/2010WR009791 Wada et al., Water Resources Research (2012), http://dx.doi.org/10.1029/2011WR010562 Wada et al., Earth System Dynamics Discussion (2013), http://dx.doi.org/10.5194/esdd-4-355-2013 Wagner et al., Remote Sensing of Environment (1999), http://dx.doi.org/10.1016/S0034-4257(99)00036-X Winsemius et al., Hydrology and Earth System Sciences (2013), http://dx.doi.org/10.5194/hess-17-1871-2013
Unicomb, Leanne; Arnold, Benjamin F.; Colford Jr., John M.; Luby, Stephen P.
2015-01-01
Background Shallow tubewells are the primary drinking water source for most rural Bangladeshis. Fecal contamination has been detected in tubewells, at low concentrations at the source and at higher levels at the point of use. We conducted a randomized controlled trial to assess whether improving the microbiological quality of tubewell drinking water by household water treatment and safe storage would reduce diarrhea in children <2 years in rural Bangladesh. Methods We randomly assigned 1800 households with a child aged 6-18 months (index child) into one of three arms: chlorine plus safe storage, safe storage and control. We followed households with monthly visits for one year to promote the interventions, track their uptake, test participants’ source and stored water for fecal contamination, and record caregiver-reported child diarrhea prevalence (primary outcome). To assess reporting bias, we also collected data on health outcomes that are not expected to be impacted by our interventions. Findings Both interventions had high uptake. Safe storage, alone or combined with chlorination, reduced heavy contamination of stored water. Compared to controls, diarrhea in index children was reduced by 36% in the chlorine plus safe storage arm (prevalence ratio, PR = 0.64, 0.55-0.73) and 31% in the safe storage arm (PR = 0.69, 0.60-0.80), with no difference between the two intervention arms. One limitation of the study was the non-blinded design with self-reported outcomes. However, the prevalence of health outcomes not expected to be impacted by water interventions did not differ between study arms, suggesting minimal reporting bias. Conclusions Safe storage significantly improved drinking water quality at the point of use and reduced child diarrhea in rural Bangladesh. There was no added benefit from combining safe storage with chlorination. Efforts should be undertaken to implement and evaluate long-term efforts for safe water storage in Bangladesh. Trial Registration ClinicalTrials.gov NCT01350063 PMID:25816342
High-Capacity Hydrogen-Based Green-Energy Storage Solutions For The Grid Balancing
NASA Astrophysics Data System (ADS)
D'Errico, F.; Screnci, A.
One of the current main challenges in green-power storage and smart grids is the lack of effective solutions for accommodating the unbalance between renewable energy sources, that offer intermittent electricity supply, and a variable electricity demand. Energy management systems have to be foreseen for the near future, while they still represent a major challenge. Integrating intermittent renewable energy sources, by safe and cost-effective energy storage systems based on solid state hydrogen is today achievable thanks to recently some technology breakthroughs. Optimized solid storage method made of magnesium-based hydrides guarantees a very rapid absorption and desorption kinetics. Coupled with electrolyzer technology, high-capacity storage of green-hydrogen is therefore practicable. Besides these aspects, magnesium has been emerging as environmentally friend energy storage method to sustain integration, monitoring and control of large quantity of GWh from high capacity renewable generation in the EU.
High-Capacity Hydrogen-Based Green-Energy Storage Solutions for the Grid Balancing
NASA Astrophysics Data System (ADS)
D'Errico, F.; Screnci, A.
One of the current main challenges in green-power storage and smart grids is the lack of effective solutions for accommodating the unbalance between renewable energy sources, that offer intermittent electricity supply, and a variable electricity demand. Energy management systems have to be foreseen for the near future, while they still represent a major challenge. Integrating intermittent renewable energy sources, by safe and cost-effective energy storage systems based on solid state hydrogen is today achievable thanks to recently some technology breakthroughs. Optimized solid storage method made of magnesium-based hydrides guarantees a very rapid absorption and desorption kinetics. Coupled with electrolyzer technology, high-capacity storage of green-hydrogen is therefore practicable. Besides these aspects, magnesium has been emerging as environmentally friend energy storage method to sustain integration, monitoring and control of large quantity of GWh from high capacity renewable generation in the EU.
Stavila, Vitalie; Bhakta, Raghunandan K; Alam, Todd M; Majzoub, Eric H; Allendorf, Mark D
2012-11-27
We demonstrate that NaAlH(4) confined within the nanopores of a titanium-functionalized metal-organic framework (MOF) template MOF-74(Mg) can reversibly store hydrogen with minimal loss of capacity. Hydride-infiltrated samples were synthesized by melt infiltration, achieving loadings up to 21 wt %. MOF-74(Mg) possesses one-dimensional, 12 Å channels lined with Mg atoms having open coordination sites, which can serve as sites for Ti catalyst stabilization. MOF-74(Mg) is stable under repeated hydrogen desorption and hydride regeneration cycles, allowing it to serve as a "nanoreactor". Confining NaAlH(4) within these pores alters the decomposition pathway by eliminating the stable intermediate Na(3)AlH(6) phase observed during bulk decomposition and proceeding directly to NaH, Al, and H(2), in agreement with theory. The onset of hydrogen desorption for both Ti-doped and undoped nano-NaAlH(4)@MOF-74(Mg) is ∼50 °C, nearly 100 °C lower than bulk NaAlH(4). However, the presence of titanium is not necessary for this increase in desorption kinetics but enables rehydriding to be almost fully reversible. Isothermal kinetic studies indicate that the activation energy for H(2) desorption is reduced from 79.5 kJ mol(-1) in bulk Ti-doped NaAlH(4) to 57.4 kJ mol(-1) for nanoconfined NaAlH(4). The structural properties of nano-NaAlH(4)@MOF-74(Mg) were probed using (23)Na and (27)Al solid-state MAS NMR, which indicates that the hydride is not decomposed during infiltration and that Al is present as tetrahedral AlH(4)(-) anions prior to desorption and as Al metal after desorption. Because of the highly ordered MOF structure and monodisperse pore dimensions, our results allow key template features to be identified to ensure reversible, low-temperature hydrogen storage.
Hydridable material for the negative electrode in a nickel-metal hydride storage battery
Knosp, Bernard; Bouet, Jacques; Jordy, Christian; Mimoun, Michel; Gicquel, Daniel
1997-01-01
A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##
Water quality risks of 'improved' water sources: evidence from Cambodia.
Shaheed, A; Orgill, J; Ratana, C; Montgomery, M A; Jeuland, M A; Brown, J
2014-02-01
The objective of this study was to investigate the quality of on-plot piped water and rainwater at the point of consumption in an area with rapidly expanding coverage of 'improved' water sources. Cross-sectional study of 914 peri-urban households in Kandal Province, Cambodia, between July-August 2011. We collected data from all households on water management, drinking water quality and factors potentially related to post-collection water contamination. Drinking water samples were taken directly from a subsample of household taps (n = 143), stored tap water (n = 124), other stored water (n = 92) and treated stored water (n = 79) for basic water quality analysis for Escherichia coli and other parameters. Household drinking water management was complex, with different sources used at any given time and across seasons. Rainwater was the most commonly used drinking water source. Households mixed different water sources in storage containers, including 'improved' with 'unimproved' sources. Piped water from taps deteriorated during storage (P < 0.0005), from 520 cfu/100 ml (coefficient of variation, CV: 5.7) E. coli to 1100 cfu/100 ml (CV: 3.4). Stored non-piped water (primarily rainwater) had a mean E. coli count of 1500 cfu/100 ml (CV: 4.1), not significantly different from stored piped water (P = 0.20). Microbial contamination of stored water was significantly associated with observed storage and handling practices, including dipping hands or receptacles in water (P < 0.005), and having an uncovered storage container (P = 0.052). The microbial quality of 'improved' water sources in our study area was not maintained at the point of consumption, possibly due to a combination of mixing water sources at the household level, unsafe storage and handling practices, and inadequately treated piped-to-plot water. These results have implications for refining international targets for safe drinking water access as well as the assumptions underlying global burden of disease estimates, which posit that 'improved' sources pose minimal risks of diarrhoeal diseases. © 2013 John Wiley & Sons Ltd.
NASA Astrophysics Data System (ADS)
Robinson, J. M.; Barker, S.; Schipper, L. A.
2017-12-01
Carbon storage in soil is a balance between photosynthesis and respiration, however, not all C compounds decompose equally in soil. Soil C consists of several fractions of C ranging from, accessible C (rapidly cycling) to stored or protected C (slow cycling). The key to increasing C storage is through the transfer of soil C from this accessible fraction, where it can be easily lost through microbial degradation, into the more stable fraction. With the increasing use of isotope enrichment techniques, 13C may be used to trace the movement of newly incorporated carbon in soil and examine how land management practises affect carbon storage. A laboratory method was developed to rapidly analyse soil respired CO2 for δ13C to determine the temperature sensitivity of newly incorporated 13C enriched carbon. A Horotiu silt loam (2 mm sieved, 60% MWHC) was mixed with 13C enriched ryegrass/clover plant matter in Hungate tubes and incubated for 5 hours at 20 temperatures( 4 - 50 °C) using a temperature gradient method (Robinson J. M., et al, (2017) Biogeochemistry, 13, 101-112). The respired CO2 was analysed using a modified Los Gatos, Off-axis ICOS carbon dioxide analyser. This method was able to analyse the δ13C signature of respired CO2 as long as a minimum concentration of CO2 was produced per tube. Further analysis used a two-component mixing model to separate the CO2 into source components to determine the contribution of added C and soil to total respiration. Preliminary data showed the decomposition of the two sources of C were both temperature dependant. Overall this method is a relatively quick and easy way to analyse δ13C of respired soil CO2 samples, and will allow for the testing of the effects of multiple variables on the decomposition of carbon fractions in future use.
Next generation molten NaI batteries for grid scale energy storage
NASA Astrophysics Data System (ADS)
Small, Leo J.; Eccleston, Alexis; Lamb, Joshua; Read, Andrew C.; Robins, Matthew; Meaders, Thomas; Ingersoll, David; Clem, Paul G.; Bhavaraju, Sai; Spoerke, Erik D.
2017-08-01
Robust, safe, and reliable grid-scale energy storage continues to be a priority for improved energy surety, expanded integration of renewable energy, and greater system agility required to meet modern dynamic and evolving electrical energy demands. We describe here a new sodium-based battery based on a molten sodium anode, a sodium iodide/aluminum chloride (NaI/AlCl3) cathode, and a high conductivity NaSICON (Na1+xZr2SixP3-xO12) ceramic separator. This NaI battery operates at intermediate temperatures (120-180 °C) and boasts an energy density of >150 Wh kg-1. The energy-dense NaI-AlCl3 ionic liquid catholyte avoids lifetime-limiting plating and intercalation reactions, and the use of earth-abundant elements minimizes materials costs and eliminates economic uncertainties associated with lithium metal. Moreover, the inherent safety of this system under internal mechanical failure is characterized by negligible heat or gas production and benign reaction products (Al, NaCl). Scalability in design is exemplified through evolution from 0.85 to 10 Ah (28 Wh) form factors, displaying lifetime average Coulombic efficiencies of 99.45% and energy efficiencies of 81.96% over dynamic testing lasting >3000 h. This demonstration promises a safe, cost-effective, and long-lifetime technology as an attractive candidate for grid scale storage.
7 CFR 58.143 - Raw product storage.
Code of Federal Regulations, 2013 CFR
2013-01-01
... 7 Agriculture 3 2013-01-01 2013-01-01 false Raw product storage. 58.143 Section 58.143 Agriculture... Procedures § 58.143 Raw product storage. (a) All milk shall be held and processed under conditions and at... source shall not be used for the manufacture of dairy products. Bulk milk in storage tanks within the...
7 CFR 58.143 - Raw product storage.
Code of Federal Regulations, 2014 CFR
2014-01-01
... 7 Agriculture 3 2014-01-01 2014-01-01 false Raw product storage. 58.143 Section 58.143 Agriculture... Procedures § 58.143 Raw product storage. (a) All milk shall be held and processed under conditions and at... source shall not be used for the manufacture of dairy products. Bulk milk in storage tanks within the...
NASA Astrophysics Data System (ADS)
Tatomir, Alexandru Bogdan A. C.; Flemisch, Bernd; Class, Holger; Helmig, Rainer; Sauter, Martin
2017-04-01
Geological storage of CO2 represents one viable solution to reduce greenhouse gas emission in the atmosphere. Potential leakage of CO2 storage can occur through networks of interconnected fractures. The geometrical complexity of these networks is often very high involving fractures occurring at various scales and having hierarchical structures. Such multiphase flow systems are usually hard to solve with a discrete fracture modelling (DFM) approach. Therefore, continuum fracture models assuming average properties are usually preferred. The multiple interacting continua (MINC) model is an extension of the classic double porosity model (Warren and Root, 1963) which accounts for the non-linear behaviour of the matrix-fracture interactions. For CO2 storage applications the transient representation of the inter-porosity two phase flow plays an important role. This study tests the accuracy and computational efficiency of the MINC method complemented with the multiple sub-region (MSR) upscaling procedure versus the DFM. The two phase flow MINC simulator is implemented in the free-open source numerical toolbox DuMux (www.dumux.org). The MSR (Gong et al., 2009) determines the inter-porosity terms by solving simplified local single-phase flow problems. The DFM is considered as the reference solution. The numerical examples consider a quasi-1D reservoir with a quadratic fracture system , a five-spot radial symmetric reservoir, and a completely random generated fracture system. Keywords: MINC, upscaling, two-phase flow, fractured porous media, discrete fracture model, continuum fracture model
Characteristics of phase-change materials containing oxide nano-additives for thermal storage
2012-01-01
In this study, the authors report the production of nanocomposite-enhanced phase-change materials (NEPCMs) using the direct-synthesis method by mixing paraffin with alumina (Al2O3), titania (TiO2), silica (SiO2), and zinc oxide (ZnO) as the experimental samples. Al2O3, TiO2, SiO2, and ZnO were dispersed into three concentrations of 1.0, 2.0, and 3.0 wt.%. Through heat conduction and differential scanning calorimeter experiments to evaluate the effects of varying concentrations of the nano-additives on the heat conduction performance and thermal storage characteristics of NEPCMs, their feasibility for use in thermal storage was determined. The experimental results demonstrate that TiO2 is more effective than the other additives in enhancing both the heat conduction and thermal storage performance of paraffin for most of the experimental parameters. Furthermore, TiO2 reduces the melting onset temperature and increases the solidification onset temperature of paraffin. This allows the phase-change heat to be applicable to a wider temperature range, and the highest decreased ratio of phase-change heat is only 0.46%, compared to that of paraffin. Therefore, this study demonstrates that TiO2, added to paraffin to form NEPCMs, has significant potential for enhancing the thermal storage characteristics of paraffin. PMID:23127224
The Power of the Rhythm of Tree Stems
NASA Astrophysics Data System (ADS)
Steppe, K.
2015-12-01
On annual and monthly scales, a remarkable close relationship has been shown between net ecosystem productivity (NEP) measured by eddy covariance and stem diameter variations (SDV) measured with automated point dendrometers in a Swiss subalpine Norway spruce forest (Zweifel et al. 2010). Causality for the close NEP-SDV relationship is poorly understood, but radial stem growth has been suggested to play a crucial role. Despite its huge ecological implications, and being 'hot' in anatomical, ecophysiologial, and ecological disciplines, radial stem growth in trees remains poorly understood (Steppe et al. 2015). While high-resolution SDV mirror a source of tree physiological information, unambiguous interpretation of dendrometer readings is more complicated than it appears at first sight, with a great potential still waiting to be discovered (De Swaef et al. 2015, Zweifel 2015). Also an integrative framework to assess impacts of climate on stem growth is still lacking, although such a theory is very much needed to predict annual tree growth patterns as well as future production and carbon sequestration potential of forests (Steppe et al. 2015). In this keynote lecture, I will present the major fluxes and pools of water and carbon inside a stem segment of a tree. I will examine diel dynamics in radial stem growth from underlying water and carbon mechanisms under wet and dry conditions, distinguishing between known patterns and processes, and more speculative ones. Discussions will be based on observations in the different research disciplines, but also result from mechanistic plant models aiming at integration. Based on this, I will show missing pieces that might be critical to build an integrative theory to understand causes and consequences of tree stem growth. Addressing these key-missing pieces of information may help improving quantification of terrestrial ecosystem carbon uptake and storage. ReferencesDe Swaef et al. (2015) Tree Physiology (in press). Steppe et al. (2015) Trends in Plant Science 20: 335-343. Zweifel et al. (2010) New Phytologist 187: 819-830. Zweifel (2015) Plant, Cell & Environment (in press).
Antihydrogen Trapped in the ALPHA Experiment
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bowe, Paul David
2011-02-25
In 2010 the ALPHA collaboration succeeded in trapping antihydrogen atoms for the first time.[i] Stored antihydrogen promises to be a unique tool for making high precision measurements of the structure of this first anti-atom. Achieving this milestone presented several substantial experimental challenges and this talk will describe how they were overcome. The unique design features of the ALPHA apparatus will be explained. These allow a high intensity positron source and an antiproton imaging detector similar to the one used in the ATHENA[iii] experiment to be combined with an innovative magnet design of the anti-atom trap. This seeks to minimise themore » perturbations to trapped charged particles which may cause particle loss and heating[iv]. The diagnostic techniques used to measure the diameter, number, density, and temperatures of both plasmas will be presented as will the methods developed to actively compress and cool of both plasma species to sizes and temperatures [v],[vi], [vii] where trapping attempts with a reasonable chance of success can be tried. The results of the successful trapping experiments will be outlined as well as some subsequent experiments to improve the trapping rate and storage time. [i] 'Trapped antihydrogen' G.B. Andresen et al., Nature 468, 673 (2010) [ii]'A Magnetic Trap for Antihydrogen Confinement' W. Bertsche et al., Nucl. Instr. Meth. Phys. Res. A566, 746 (2006) [iii] Production and detection of cold antihydrogen atoms M.Amoretti et al., Nature 419, 456 (2002). [iv]' Antihydrogen formation dynamics in a multipolar neutral anti-atom trap' G.B. Andresen et al., Phys. Lett. B 685, 141 (2010) [v]' Evaporative Cooling of Antiprotons to Cryogenic Temperatures', G.B. Andresen et al. Phys. Rev. Lett 105, 013003 (2010) [vi]'Compression of Antiproton Clouds for Antihydrogen Trapping' G. B. Andresen et al. Phys. Rev. Lett 100, 203401 (2008) [vii] 'Autoresonant Excitation of Antiproton Plasmas' G.B. Andresen et al., Phys. Rev. Lett. 106, 025002 (2011)« less
Antihydrogen Trapped in the ALPHA Experiment
Bowe, Paul David
2017-12-18
In 2010 the ALPHA collaboration succeeded in trapping antihydrogen atoms for the first time.[i] Stored antihydrogen promises to be a unique tool for making high precision measurements of the structure of this first anti-atom. Achieving this milestone presented several substantial experimental challenges and this talk will describe how they were overcome. The unique design features of the ALPHA apparatus will be explained. These allow a high intensity positron source and an antiproton imaging detector similar to the one used in the ATHENA[iii] experiment to be combined with an innovative magnet design of the anti-atom trap. This seeks to minimise the perturbations to trapped charged particles which may cause particle loss and heating[iv]. The diagnostic techniques used to measure the diameter, number, density, and temperatures of both plasmas will be presented as will the methods developed to actively compress and cool of both plasma species to sizes and temperatures [v],[vi], [vii] where trapping attempts with a reasonable chance of success can be tried. The results of the successful trapping experiments will be outlined as well as some subsequent experiments to improve the trapping rate and storage time. [i] 'Trapped antihydrogen' G.B. Andresen et al., Nature 468, 673 (2010) [ii]'A Magnetic Trap for Antihydrogen Confinement' W. Bertsche et al., Nucl. Instr. Meth. Phys. Res. A566, 746 (2006) [iii] Production and detection of cold antihydrogen atoms M.Amoretti et al., Nature 419, 456 (2002). [iv]' Antihydrogen formation dynamics in a multipolar neutral anti-atom trap' G.B. Andresen et al., Phys. Lett. B 685, 141 (2010) [v]' Evaporative Cooling of Antiprotons to Cryogenic Temperatures', G.B. Andresen et al. Phys. Rev. Lett 105, 013003 (2010) [vi]'Compression of Antiproton Clouds for Antihydrogen Trapping' G. B. Andresen et al. Phys. Rev. Lett 100, 203401 (2008) [vii] 'Autoresonant Excitation of Antiproton Plasmas' G.B. Andresen et al., Phys. Rev. Lett. 106, 025002 (2011)
Sulfuric acid-sulfur heat storage cycle
Norman, John H.
1983-12-20
A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.
Zhou, Wenzhi; He, Shutao; Naconsie, Maliwan; Ma, Qiuxiang; Zeeman, Samuel C; Gruissem, Wilhelm; Zhang, Peng
2017-08-29
Regulation of storage root development by source strength remains largely unknown. The cassava storage root delay (srd) T-DNA mutant postpones storage root development but manifests normal foliage growth as wild-type plants. The SRD gene was identified as an orthologue of α-glucan, water dikinase 1 (GWD1), whose expression is regulated under conditions of light/dark cycles in leaves and is associated with storage root development. The GWD1-RNAi cassava plants showed both retarded plant and storage root growth, as a result of starch excess phenotypes with reduced photosynthetic capacity and decreased levels of soluble saccharides in their leaves. These leaves contained starch granules having greatly increased amylose content and type C semi-crystalline structures with increased short chains that suggested storage starch. In storage roots of GWD1-RNAi lines, maltose content was dramatically decreased and starches with much lower phosphorylation levels showed a drastically reduced β-amylolytic rate. These results suggested that GWD1 regulates transient starch morphogenesis and storage root growth by decreasing photo-assimilation partitioning from the source to the sink and by starch mobilization in root crops.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vogt, B.M.; Sorensen, J.H.
The CSEPP (Chemical Stockpile Emergency Preparedness Program) was created to improve emergency planning and response capabilities at the eight sites around the country that store chemical weapons. These weapons are scheduled to be destroyed in the near future. In preparation of the Draft Programmatic Environmental Impact Statement (DPEIS) for the Chemical Stockpile Disposal Program (CSDP), it was proposed that the Army mitigate accidents through an enhanced community emergency preparedness program at the eight storage sites. In 1986, the Army initiated the development of an Emergency Response Concept Plan (ERCP) for the CSDP, one of 12 technical support studies conducted duringmore » preparation of the Final Programmatic Environmental Impact Statement (FPEIS). The purpose of this document is to provide a fairly comprehensive source book on risk, risk management, risk communication research and recommended risk communication practices. It does not merely summarize each publication in the risk communication literature, but attempts to synthesize them along the lines of a set of organizing principles. Furthermore, it is not intended to duplicate other guidance manuals (such as Covello et al.`s manual on risk comparison). The source book was developed for the CSEPP in support of the training module on risk communications. Although the examples provided are specific to CSEPP, its use goes beyond that of CSEPP as the findings apply to a broad spectrum of risk communication topics. While the emphasis is on communication in emergency preparedness and response specific to the CSEPP, the materials cover other non-emergency communication settings. 329 refs.« less
Geissbühler, Lukas; Zavattoni, Simone; Barbato, Maurizio; Zanganeh, Giw; Haselbacher, Andreas; Steinfeld, Aldo
2015-01-01
Combined sensible/latent heat storage allows the heat-transfer fluid outflow temperature during discharging to be stabilized. A lab-scale combined storage consisting of a packed bed of rocks and steel-encapsulated AlSi(12) was investigated experimentally and numerically. Due to the small tank-to-particle diameter ratio of the lab-scale storage, void-fraction variations were not negligible, leading to channeling effects that cannot be resolved in 1D heat-transfer models. The void-fraction variations and channeling effects can be resolved in 2D models of the flow and heat transfer in the storage. The resulting so-called bypass fraction extracted from the 2D model was used in the 1D model and led to good agreement with experimental measurements.
Lu, Jun [Salt Lake City, UT; Fang, Zhigang Zak [Salt Lake City, UT; Sohn, Hong Yong [Salt Lake City, UT
2012-04-03
As a promising clean fuel for vehicles, hydrogen can be used for propulsion, either directly or in fuel cells. Hydrogen storage compositions having high storage capacity, good dehydrogenation kinetics, and hydrogen release and uptake reactions which are reversible are disclosed and described. Generally a hydrogen storage composition of a metal aluminum hexahydride and a metal amide can be used. A combined system (Li.sub.3AIH.sub.6/3LiNH.sub.2) with a very high inherent hydrogen capacity (7.3 wt %) can be carried out at moderate temperatures, and with approximately 95% of that inherent hydrogen storage capacity (7.0%) is reversible over repeated cycling of release and uptake.
Dehydration of δ-AlOOH in the lower mantle
NASA Astrophysics Data System (ADS)
Piet, H.; Shim, S. H.; Tappan, J.; Leinenweber, K. D.; Greenberg, E.; Prakapenka, V. B.
2017-12-01
Hydrous phase δ-AlOOH is an important candidate for water transport and storage in the Earth's deep mantle [1]. Knowing the conditions, under which it is stable and dehydrated, is therefore important for understanding the water transportation to the deep mantle or even to the core. A few experimental studies [1, 2] have shown that δ-AlOOH may be stable in cold descending slabs while it is dehydrated into a mixture of corundum and water under normal mantle conditions, up to 25 GPa. A subsequent study [3] reported the stability of δ-AlOOH in cold descending slabs to the core-mantle boundary conditions (2300 K at 135 GPa). However, the dehydration of δ-AlOOH has not bee directly observed in the experiments conducted at pressures above 25 GPa. We have synthesized δ-AlOOH from diaspore and Al(OH)3 in multi-anvil press at ASU. The sample was mixed with Au for coupling with near IR laser beams and loaded in diamond-anvil cells. We performed the laser-heated diamond anvil cell experiments at the 13IDD beamline of the Advanced Photon Source and ASU. At APS, we measured X-ray diffraction patterns at in situ high pressure and temperature. We observed the appearance of the corundum diffraction lines at 1700-2000 K and 55-90 GPa, indicating the dehydration of δ-AlOOH to Al2O3+ H2O. We found that the transition occurs over a broad range of temperature (500 K). We also observed that the dehydration of δ-AlOOH was accompanied by sudden change in laser coupling, most likely due to the release of fluids. The property change also helps us to determine the dehydration at ASU without in situ XRD. Our new experimental results indicate that δ-AlOOH would be stable in most subducting slabs in the deep mantle. However, because the dehydration occurs very close to the temperatures expected for the lower mantle, its stability is uncertain in the normal mantle. [1] Ohtani et al. 2001, Stability field of new hydrous phase, delta-AlOOH, Geophysical Research Letters 28, 3991-3993. [2] Sano et al. 2004, In situ XRD of dehydration of AlSiO3OH and d-AlOOH, JPCS 65, 1547-1554. [3] Sano et al. 2008, Aluminous hydrous mineral d-AlOOH as a carrier of hydrogen into the core-mantle boundary, Geophysical Research Letters 35, L03303.
Carbon storage in forests and peatlands of Russia
V.A. Alexeyev; R.A. Birdsey; [Editors
1998-01-01
Contains information about carbon storage in the vegetation, soils, and peatlands of Russia. Estimates of carbon storage in forests are derived from statistical data from the 1988 national forest inventory of Russia and from other sources. Methods are presented for converting data on timber stock into phytomass of tree stands, and for estimating carbon storage in...
Hydrogen storage material and process using graphite additive with metal-doped complex hydrides
Zidan, Ragaiy [Aiken, SC; Ritter, James A [Lexington, SC; Ebner, Armin D [Lexington, SC; Wang, Jun [Columbia, SC; Holland, Charles E [Cayce, SC
2008-06-10
A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.
Porras, Rachel C.; Hicks Pries, Caitlin E.; McFarlane, Karis J.; ...
2017-05-13
Soil organic carbon (SOC) can be stabilized via association with iron (Fe) and aluminum (Al) minerals. Fe and Al can be strong predictors of SOC storage and turnover in soils with relatively high extractable metals content and moderately acidic to circumneutral pH. Here we test whether pedogenic Fe and Al influence SOC content and turnover in soils with low Fe and Al content and acidic pH. In soils from four sites spanning three soil orders, we quantified the amount of Fe and Al in operationally-defined poorly crystalline and organically-complexed phases using selective chemical dissolution applied to the soil fraction containingmore » mineral-associated carbon. We evaluated the correlations of Fe and Al concentrations, mean annual precipitation (MAP), mean annual temperature (MAT), and pH with SOC content and 14C-based turnover times. We found that poorly crystalline Fe and Al content predicted SOC turnover times (p < 0.0001) consistent with findings of previous studies, while organically-complexed Fe and Al content was a better predictor of SOC concentration (p < 0.0001). Greater site-level MAP (p < 0.0001) and colder site-level MAT (p < 0.0001) were correlated with longer SOC turnover times but were not correlated with SOC content. Our results suggest that poorly crystalline Fe and Al effectively slow the turnover of SOC in these acidic soils, even when their combined content in the soil is less than 2% by mass. However, in the strongly acidic Spodosol, organo-metal complexes tended to be less stable resulting in a more actively cycling mineral-associated SOC pool.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Porras, Rachel C.; Hicks Pries, Caitlin E.; McFarlane, Karis J.
Soil organic carbon (SOC) can be stabilized via association with iron (Fe) and aluminum (Al) minerals. Fe and Al can be strong predictors of SOC storage and turnover in soils with relatively high extractable metals content and moderately acidic to circumneutral pH. Here we test whether pedogenic Fe and Al influence SOC content and turnover in soils with low Fe and Al content and acidic pH. In soils from four sites spanning three soil orders, we quantified the amount of Fe and Al in operationally-defined poorly crystalline and organically-complexed phases using selective chemical dissolution applied to the soil fraction containingmore » mineral-associated carbon. We evaluated the correlations of Fe and Al concentrations, mean annual precipitation (MAP), mean annual temperature (MAT), and pH with SOC content and 14C-based turnover times. We found that poorly crystalline Fe and Al content predicted SOC turnover times (p < 0.0001) consistent with findings of previous studies, while organically-complexed Fe and Al content was a better predictor of SOC concentration (p < 0.0001). Greater site-level MAP (p < 0.0001) and colder site-level MAT (p < 0.0001) were correlated with longer SOC turnover times but were not correlated with SOC content. Our results suggest that poorly crystalline Fe and Al effectively slow the turnover of SOC in these acidic soils, even when their combined content in the soil is less than 2% by mass. However, in the strongly acidic Spodosol, organo-metal complexes tended to be less stable resulting in a more actively cycling mineral-associated SOC pool.« less
National Synchrotron Light Source II storage ring vacuum systems
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hseuh, Hsiao-Chaun, E-mail: hseuh@bnl.gov; Hetzel, Charles; Leng, Shuwei
2016-05-15
The National Synchrotron Light Source II, completed in 2014, is a 3-GeV synchrotron radiation (SR) facility at Brookhaven National Laboratory and has been in steady operation since. With a design electron current of 500 mA and subnanometer radians horizontal emittance, this 792-m circumference storage ring is providing the highest flux and brightness x-ray beam for SR users. The majority of the storage ring vacuum chambers are made of extruded aluminium. Chamber sections are interconnected using low-impedance radiofrequency shielded bellows. SR from the bending magnets is intercepted by water-cooled compact photon absorbers resided in the storage ring chambers. This paper presents themore » design of the storage ring vacuum system, the fabrication of vacuum chambers and other hardware, the installation, the commissioning, and the continuing beam conditioning of the vacuum systems.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1992-06-01
Proposed action is to construct at BNL a 5,600-ft[sup 2] support building, install and operate a prototypic 200 MeV accelerator and a prototypic 700 MeV storage ring within, and to construct and operate a 15 kV substation to power the building. The accelerator and storage ring would comprise the x-ray lithography source or XLS.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1992-06-01
Proposed action is to construct at BNL a 5,600-ft{sup 2} support building, install and operate a prototypic 200 MeV accelerator and a prototypic 700 MeV storage ring within, and to construct and operate a 15 kV substation to power the building. The accelerator and storage ring would comprise the x-ray lithography source or XLS.
NASA Technical Reports Server (NTRS)
Juday, Richard D. (Inventor)
1998-01-01
An apparatus is disclosed for reading and/or writing information or to from an optical recording medium having a plurality of information storage layers. The apparatus includes a dynamic holographic optical element configured to focus light on the optical recording medium. a control circuit arranged to supply a drive signal to the holographic optical element, and a storage device in communication with the control circuit and storing at least a first drive signal and a second drive signal. The holographic optical element focusses light on a first one of the plurality of information storage layers when driven by the first drive signal on a second one of the plurality of information storage layers when driven by the second drive signal. An optical switch is also disclosed for connecting at least one light source in a source array to at least one light receiver in a receiver array. The switch includes a dynamic holographic optical element configured to receive light from the source array and to transmit light to the receiver array, a control circuit arranged to supply a drive signal to the holographic optical element, and a storage device in communication with the control circuit and storing at least a first drive signal and a second drive signal. The holographic optical element connects a first light source in the source array to a first light receiver in the receiver array when driven by the first drive signal and the holographic optical element connects the first light source with the first light receiver and a second light receiver when driven by the second drive signal.
C-band radar observes water level change in swamp forests
Lu, Zhong; Crane, Mike; Kwoun, Oh-Ig; Wells, Christopher J.; Rykhus, Russ
2005-01-01
Wetlands cover more than 4% of the Earth's land surface and interact with hydrologic, biogeochemical, and sediment transport processes that are fundamental in understanding ecological and climatic changes [Alsdorf et al, 2003; Prigent et al., 2001 ; Melack and Forsberg, 2000;Dunne et al., 1998]. Measurement of water level changes in wetlands, and consequently of changes in water storage capacity, provides a required input for hydrologic models, and is required to comprehensively assess flood hazards [e.g., Coe, 1998].
Tunable Mechanical Behavior of Synthetic Organogels as Biofidelic Tissue Simulants
2013-01-01
leather , silicone elastomers, soap, lard, and clay (Appleby- Thomas et al., 2011; Jussila et al., 2005; Merkle et al., 2008). In most cases, the tissue...and throughout all experiments reported herein. 2.2. Rheology To measure the shear storage modulus G′, loss modulus G″, and loss tangent tan δ (i.e...magnitude and rate dependence of G′, G″, and tan δ Solvent has a significant impact on the modulus of these gels in two ways: (1) the solvent will
Power conversion apparatus and method
Su, Gui-Jia [Knoxville, TN
2012-02-07
A power conversion apparatus includes an interfacing circuit that enables a current source inverter to operate from a voltage energy storage device (voltage source), such as a battery, ultracapacitor or fuel cell. The interfacing circuit, also referred to as a voltage-to-current converter, transforms the voltage source into a current source that feeds a DC current to a current source inverter. The voltage-to-current converter also provides means for controlling and maintaining a constant DC bus current that supplies the current source inverter. The voltage-to-current converter also enables the current source inverter to charge the voltage energy storage device, such as during dynamic braking of a hybrid electric vehicle, without the need of reversing the direction of the DC bus current.
CarbonSAFE Illinois - Macon County
DOE Office of Scientific and Technical Information (OSTI.GOV)
Whittaker, Steve
CarbonSAFE Illinois is a a Feasibility study to develop an established geologic storage complex in Macon County, Illinois, for commercial-scale storage of industrially sourced CO2. Feasibility activities are focused on the Mt. Simon Storage Complex; a step-out well will be drilled near existing storage sites (i.e., the Midwest Geological Sequestration Consortium’s Illinois Basin – Decatur Project and the Illinois Industrial Carbon Capture and Storage Project) to further establish commercial viability of this complex and to evaluate EOR potential in a co-located oil-field trend. The Archer Daniels Midland facility (ethanol plant), City Water, Light, and Power in Springfield, Illinois (coal-fired powermore » station), and other regional industries are potential sources of anthropogenic CO2 for storage at this complex. Site feasibility will be evaluated through drilling results, static and dynamic modeling, and quantitative risk assessment. Both studies will entail stakeholder engagement, consideration of infrastructure requirements, existing policy, and business models. Project data will help calibrate the National Risk Assessment Partnership (NRAP) Toolkit to better understand the risks of commercial-scale carbon storage.« less
NASA Astrophysics Data System (ADS)
Lee, Pui Fai
2007-12-01
Nanocrystals (NC) embedded in dielectrics have attracted a great deal of attention recently because they can potentially be applied in nonvolatile, high-speed, high-density and low-power memory devices. This device benefits from a relatively low operating voltage, high endurance, fast write-erase speeds and better immunity to soft errors. The nanocrystal materials suitable for such an application can be either metals or semiconductors. Recent studies have shown that high-k dielectrics, instead of SiO2 , for the tunneling layer in nanocrystal floating gate memory can improve the trade-off between data retention and program efficiency due to the unique band alignment of high-k dielectrics in the programming and retention modes. In this project, HfAlO has been selected as the high- k dielectric for the nanocrystal floating gate memory structure. The trilayer structure (HfAlO/Ge-NC/HfAlO) on Si was fabricated by PLD. Results revealed that relatively low substrate temperature and growth rate are favourable for the formation of smaller-size Ge nanocrystals. Effects of size/density of the Ge nanocrystal, the tunneling and control oxide layer thicknesses and the oxygen partial pressure during their growth on the charge storage and charge retention characteristics have also been studied. The island structure of the Ge nanocrystal suggests that the growth is based on the Volmer-Webber mode. The self-organized Ge nanocrystals so formed were uniform in size (5--20 nm diameter) and distribution with a density approaching 1012--1013cm-2. Flat-band voltage shift (DeltaVFB) of about 3.6 V and good retention property have been achieved. By varying aggregation distance, sputtering gas pressure and ionization power of the nanocluster source, nanoclusters of Ge with different sizes can be formed. The memory effect of the trilayer structure so formed with 10 nm Ge nanoclusters are manifested by the counter-clockwise hysteresis loop in the C-V curves and a maximum flat-band voltage shift of 5.0 V has been achieved. For comparison purposes, metal nanocrystals have also been investigated by utilizing both of the physical deposition methods as mentioned above. Silver (Ag) nanocrystals with size of 10--40 nm have been embedded in HfAlO matrix in the trilayer capacitor structure and a flat-band voltage shift of 2.0 V has been achieved.
USDA-ARS?s Scientific Manuscript database
Manure storages, and in particular those storing digested manure, are a source of ammonia (NH3) emissions. Permeable manure storage covers can reduce NH3 emissions, however performance can decline as they degrade. Thermochemical conversion of biomass through pyrolysis and steam treatment could incre...
Bulk Diffusion via a ``kick-out'' method for Lithium in the decomposition reaction LiAlH4/Li3AlH6
NASA Astrophysics Data System (ADS)
Rolih, Biljana; Ozolins, Vidvuds; Ozolins Team
2013-03-01
In the pursuit to find a practical system for hydrogen storage, complex metal hydrides have long been considered as viable candidates due to their high hydrogen content. However, some of the challenges faced with these types of systems are poor thermodynamics or kinetics. The underlying mechanisms, and their limiting processes, for the decomposition of these materials need to be understood. From experimental work on the decomposition of hydrogen storage materials, it has been suggested that bulk diffusion of metal species is the bottleneck for hydrogen release. In this work is the dehydrogenation we investigated the system LiAlH4 LiAlH6 with favorable hydrogen release (5.3 wt %), at moderate temperatures. Using first-principles density functional theory we found the defects facilitating mass transport by calculating individual formation energies, highest concentrations, and activation barriers for defect mobility. The mass transport of Lithium is found to be mediated by a ``kick-out'' mechanism. The results are used to further our understanding of the fundamental mechanism of mass transport and evaluate the possibility of kinetics as the limiting process in this reaction.
Nonvolatile semiconductor memory having three dimension charge confinement
Dawson, L. Ralph; Osbourn, Gordon C.; Peercy, Paul S.; Weaver, Harry T.; Zipperian, Thomas E.
1991-01-01
A layered semiconductor device with a nonvolatile three dimensional memory comprises a storage channel which stores charge carriers. Charge carriers flow laterally through the storage channel from a source to a drain. Isolation material, either a Schottky barrier or a heterojunction, located in a trench of an upper layer controllably retains the charge within the a storage portion determined by the confining means. The charge is retained for a time determined by the isolation materials' nonvolatile characteristics or until a change of voltage on the isolation material and the source and drain permit a read operation. Flow of charge through an underlying sense channel is affected by the presence of charge within the storage channel, thus the presences of charge in the memory can be easily detected.
Lee, Inkyu; Park, Jinwoo; Moon, Il
2017-12-01
This paper describes data of an integrated process, cryogenic energy storage system combined with liquefied natural gas (LNG) regasification process. The data in this paper is associated with the article entitled "Conceptual Design and Exergy Analysis of Combined Cryogenic Energy Storage and LNG Regasification Processes: Cold and Power Integration" (Lee et al., 2017) [1]. The data includes the sensitivity case study dataset of the air flow rate and the heat exchanging feasibility data by composite curves. The data is expected to be helpful to the cryogenic energy process development.
Efficacy of adaptation measures to future water scarcity on a global scale
NASA Astrophysics Data System (ADS)
Yoshikawa, S.; Kanae, S.
2015-12-01
Water supply sources for all sector are critically important for agricultural and industrial productivity. The current rapid increase in water use is considered unsustainable and threatens human life. In our previous study (Yoshikawa et al., 2014 in HESS), we estimated the time-varying dependence of water requirements from water supply sources during past and future periods using the global water resources model, H08. The sources of water requirements were specified using four categories: rivers, large reservoirs, medium-size reservoirs, and non-local non-renewable blue water (NNBW). We also estimated ΔNNBW which is defined as an increase in NNBW from the past to the future. From the results, we could require the further development of water supply sources in order to sustain future water use. For coping with water scarcity using ΔNNBW, there is need for adaptation measure. To address adaptation measures, we need to set adaptation options which can be divided between 'Supply enhancement' and 'Demand management'. The supply enhancement includes increased storage, groundwater development, inter-basin transfer, desalination and re-use urban waste water. Demand management is defined as a set of actions controlling water demand by reducing water loss, increasing water productivity, and water re-allocation. In this study, we focus on estimating further future water demand under taking into account of several adaptation measures using H08 model.
National Synchrotron Light Source II storage ring vacuum systems
Hseuh, Hsiao-Chaun; Hetzel, Charles; Leng, Shuwei; ...
2016-04-05
The National Synchrotron Light Source II, completed in 2014, is a 3-GeV synchrotron radiation (SR) facility at Brookhaven National Laboratory and has been in steady operation since. With a design electron current of 500 mA and subnanometer radians horizontal emittance, this 792-m circumference storage ring is providing the highest flux and brightness x-ray beam for SR users. Also, the majority of the storage ring vacuum chambers are made of extruded aluminium. Chamber sections are interconnected using low-impedance radiofrequency shielded bellows. SR from the bending magnets is intercepted by water-cooled compact photon absorbers resided in the storage ring chambers. Finally, thismore » paper presents the design of the storage ring vacuum system, the fabrication of vacuum chambers and other hardware, the installation, the commissioning, and the continuing beam conditioning of the vacuum systems.« less
Thermal energy storage for the Stirling engine powered automobile
NASA Technical Reports Server (NTRS)
Morgan, D. T. (Editor)
1979-01-01
A thermal energy storage (TES) system developed for use with the Stirling engine as an automotive power system has gravimetric and volumetric storage densities which are competitive with electric battery storage systems, meets all operational requirements for a practical vehicle, and can be packaged in compact sized automobiles with minimum impact on passenger and freight volume. The TES/Stirling system is the only storage approach for direct use of combustion heat from fuel sources not suitable for direct transport and use on the vehicle. The particular concept described is also useful for a dual mode TES/liquid fuel system in which the TES (recharged from an external energy source) is used for short duration trips (approximately 10 miles or less) and liquid fuel carried on board the vehicle used for long duration trips. The dual mode approach offers the potential of 50 percent savings in the consumption of premium liquid fuels for automotive propulsion in the United States.
Grams, Paul E.; Buscombe, Daniel D.; Topping, David J.; Hazel, Joseph E.; Kaplinski, Matt
2015-01-01
The magnitude and pfattern of streamflow and sediment supply of the Colorado River in Grand Canyon (Figure 1) has been affected by the existence and operations of Glen Canyon Dam since filling of Lake Powell Reservoir began in March 1963. In the subsequent 30 years, fine sediment was scoured from the downstream channel (Topping et al., 2000; Grams et al., 2007), resulting in a decline in the number and size of sandbars in the eastern half of Grand Canyon National Park (Wright et al., 2005; Schmidt et al., 2004). The Glen Canyon Dam Adaptive Management Program (GCDAMP) administered by the U.S. Department of Interior oversees efforts to manage the Colorado River ecosystem downstream from Glen Canyon Dam. One of the goals of the GCDAMP is to maintain and increase the number and size of sandbars in this context of a limited sand supply. Management actions to benefit sandbars have included curtailment of daily streamflow fluctuations, which occur for hydropower generation, and implementation of controlled floods, also called high-flow experiments.Studies of controlled floods, defined as intentional releases that exceed the maximum discharge capacity of the Glen Canyon Dam powerplant, implemented between 1996 and 2008, have demonstrated that these events cause increases in sandbar size throughout Marble and Grand Canyons (Hazel et al., 2010; Schmidt and Grams, 2011; Mueller et al., 2014), although the magnitude of response is spatially variable (Hazel et al., 1999; 2010). Controlled floods may build some sandbars at the expense of erosion of sand from other, upstream, sandbars (Schmidt, 1999). To increase the frequency and effectiveness of sandbar building, the U.S. Department of Interior adopted a “high-flow experimental protocol” to implement controlled floods regularly under conditions of enriched sand supply (U.S. Department of Interior, 2012). Because the supply of sand available to build sandbars has been substantially reduced by Glen Canyon Dam (Topping et al., 2000) and depends entirely on infrequent tributary floods, monitoring of both sandbars and gross sand storage (the sand budget) is required to evaluate whether the high-flow protocol is having the intended effect of increasing sandbar size without progressively depleting sand from the system.There are many challenges associated with monitoring sand storage and active sand deposits in a river system as large and complex as the 450-km segment of the Colorado River between Glen Canyon Dam and Lake Mead. Previous studies have demonstrated the temporal variation in sand storage associated with sand-supply limitation (Topping et al., 2000) and the spatial variability in the amount of sand stored in eddies and the channel associated with channel hydraulics (Grams et al., 2013). In this study, we report on companion measurements of sand flux and morphologic change to quantify, for the first time, the relation between changes in sand mass balance, changes in within-channel sand storage, and changes in sandbars comprehensively for a 50-km river segment of the Colorado River in lower Marble Canyon within Grand Canyon National Park.We show that, when measured over the scale of a 50-km river segment, these complementary measurements of the sand budget agree within measurement uncertainty and provide a rare opportunity to integrate the temporally rich sand-flux record with the spatially rich morphologic measurements. Both methods show that sediment was evacuated from lower Marble Canyon over the 3-year study period. The flux-based budget shows the timing of changes in storage relative to dam-release patterns, while the morphologic measurements depict the spatial distribution of erosion and deposition among different depositional settings.
In-Storage Embedded Accelerator for Sparse Pattern Processing
2016-09-13
computation . As a result, a very small processor could be used and still make full use of storage device bandwidth. When the host software sends...Rean Griffith, Anthony D. Joseph, Randy Katz, Andy Konwinski, Gunho Lee et al. "A view of cloud computing ."Communications of the ACM 53, no. 4 (2010...Laboratory, * MIT Computer Science & Artificial Intelligence Laboratory Abstract— We present a novel system architecture for sparse pattern
Cryo-Milling and the Hydrogen Storage Properties of NaAlH4
NASA Astrophysics Data System (ADS)
Feller, Kevin; Dobbins, Tabbetha
2013-03-01
High energy ball milling of metal hydrides is a common way to both introduce catalysts (e.g. TiCl3) and to simultaneously increase the surface area. Both catalysis and increased surface area improve hydrogen storage capacity of the material. Nanostructuring of hydrides by depositing them into mesoporous templates (such as anodized alumina, MOFs, and SBA-15) has become a common way to increase surface area. However, the mesoporous template does not add hydrogen storage capacity--and thus, tends to decreased overall storage weight percent for the nanostructured hydride material. As with most materials, hydrides become brittle at low temperatures and will tend to fracture more readily. We will process Sodium Aluminum Hydride (NaAlH4) using cryogenic high energy ball milling using an in-house modified chamber SPEX Certiprep M8000 mixer/mill in order to gain a nanostructured hydride without mesoporous template material. Details of the modified mixer mill design will be presented. Ultimately, our planned future work is to study the resultant material using x-ray diffraction (Scherrer method for crystallite size), absorption/desorption temperature programmed desorption (TPD), and ultrasmall-angle x-ray scattering (USAXS) microstructural quantification to understand the role of cryomilling on enhancing the material's ability to store (and release) hydrogen.
40 CFR 60.113 - Monitoring of operations.
Code of Federal Regulations, 2011 CFR
2011-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.115a - Monitoring of operations.
Code of Federal Regulations, 2010 CFR
2010-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.115a - Monitoring of operations.
Code of Federal Regulations, 2012 CFR
2012-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.113 - Monitoring of operations.
Code of Federal Regulations, 2013 CFR
2013-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.115a - Monitoring of operations.
Code of Federal Regulations, 2013 CFR
2013-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.113 - Monitoring of operations.
Code of Federal Regulations, 2014 CFR
2014-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.113 - Monitoring of operations.
Code of Federal Regulations, 2012 CFR
2012-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.115a - Monitoring of operations.
Code of Federal Regulations, 2014 CFR
2014-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.115a - Monitoring of operations.
Code of Federal Regulations, 2011 CFR
2011-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
40 CFR 60.113 - Monitoring of operations.
Code of Federal Regulations, 2010 CFR
2010-07-01
... petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. (b) Available data on the typical Reid vapor pressure and the maximum... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels...
Modeling biotic uptake by periphyton and transient hyporrheic storage of nitrate in a natural stream
Kim, Brian K.A.; Jackman, Alan P.; Triska, Frank J.
1992-01-01
To a convection-dispersion hydrologic transport model we coupled a transient storage submodel (Bencala, 1984) and a biotic uptake submodel based on Michaelis-Menten kinetics (Kim et al., 1990). Our purpose was threefold: (1) to simulate nitrate retention in response to change in load in a third-order stream, (2) to differentiate biotic versus hydrologie factors in nitrate retention, and (3) to produce a research tool whose properties are consistent with laboratory and field observations. Hydrodynamic parameters were fitted from chloride concentration during a 20-day chloride-nitrate coinjection (Bencala, 1984), and biotic uptake kinetics were based on flume studies by Kim et al. (1990) and Triska et al. (1983). Nitrate concentration from the 20-day coinjection experiment served as a base for model validation. The complete transport retention model reasonably predicted the observed nitrate concentration. However, simulations which lacked either the transient storage submodel or the biotic uptake submodel poorly predicted the observed nitrate concentration. Model simulations indicated that transient storage in channel and hyporrheic interstices dominated nitrate retention within the first 24 hours, whereas biotic uptake dominated thereafter. A sawtooth function for Vmax ranging from 0.10 to 0.17 μg NO3-N s−1 gAFDM−1 (grams ash free dry mass) slightly underpredicted nitrate retention in simulations of 2–7 days. This result was reasonable since uptake by other nitrate-demanding processes were not included. The model demonstrated how ecosystem retention is an interaction between physical and biotic processes and supports the validity of coupling separate hydrodynamic and reactive submodels to established solute transport models in biological studies of fluvial ecosystems.
Status of a standard for neutron skyshine calculation and measurement
DOE Office of Scientific and Technical Information (OSTI.GOV)
Westfall, R.M.; Wright, R.Q.; Greenborg, J.
1990-01-01
An effort has been under way for several years to prepare a draft standard, ANS-6.6.2, Calculation and Measurement of Direct and Scattered Neutron Radiation from Contained Sources Due to Nuclear Power Operations. At the outset, the work group adopted a three-phase study involving one-dimensional analyses, a measurements program, and multi-dimensional analyses. Of particular interest are the neutron radiation levels associated with dry-fuel storage at reactor sites. The need for dry storage has been investigated for various scenarios of repository and monitored retrievable storage (MRS) facilities availability with the waste stream analysis model. The concern is with long-term integrated, low-level dosesmore » at long distances from a multiplicity of sources. To evaluate the conservatism associated with one-dimensional analyses, the work group has specified a series of simple problems. Sources as a function of fuel exposure were determined for a Westinghouse 17 x 17 pressurized water reactor assembly with the ORIGEN-S module of the SCALE system. The energy degradation of the 35 GWd/ton U sources was determined for two generic designs of dry-fuel storage casks.« less
On the shock response of cubic metals
NASA Astrophysics Data System (ADS)
Bourne, N. K.; Gray, G. T.; Millett, J. C. F.
2009-11-01
The response of four cubic metals to shock loading is reviewed in order to understand the effects of microstructure on continuum response. Experiments are described that link defect generation and storage mechanisms at the mesoscale to observations in the bulk. Four materials were reviewed; these were fcc nickel, the ordered fcc intermetallic Ni3Al, the bcc metal tantalum, and two alloys based on the intermetallic phase TiAl; Ti-46.5Al-2Cr-2Nb and Ti-48Al-2Cr-2Nb-1B. The experiments described are in two groups: first, equation of state and shear strength measurements using Manganin stress gauges and, second, postshock microstructural examinations and measurement of changes in mechanical properties. The behaviors described are linked through the description of time dependent plasticity mechanisms to the final states achieved. Recovered targets displayed dislocation microstructures illustrating processes active during the shock-loading process. Reloading of previously shock-prestrained samples illustrated shock strengthening for the fcc metals Ni and Ni3Al while showing no such effect for bcc Ta and for the intermetallic TiAl. This difference in effective shock hardening has been related, on the one hand, to the fact that bcc metals have fewer available slip systems that can operate than fcc crystals and to the observation that the lower symmetry materials (Ta and TiAl) both possess high Peierls stress and thus have higher resistances to defect motion in the lattice under shock-loading conditions. These behaviors, compared between these four materials, illustrate the role of defect generation, transport, storage, and interaction in determining the response of materials to shock prestraining.
Characteristics of Pt-K/MgAl2O4 lean NOx trap catalysts
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kim, Do Heui; Mudiyanselage, Kumudu K.; Szanyi, Janos
2012-04-30
We report the various characteristics of Pt-K/MgAl{sub 2}O{sub 4} lean NOx trap (LNT) catalysts including the effect of K loading on nitrate formation/decomposition, NOx storage activity and durability. Upon the adsorption of NO{sub 2} on K/MgAl{sub 2}O{sub 4} samples, potassium nitrates formed on Mg-related sites in MgAl{sub 2}O{sub 4} support are observed, in addition to the typical two potassium nitrates (ionic and bidentate) formed also on Al{sub 2}O{sub 3} supported sample. Based on NO{sub 2} TPD and FTIR results, the Mg-bound KNO{sub 3} thermally decompose at higher temperature than Al-bound KNO{sub 3}, implying its superior thermal stability. At a potassiummore » loading of 5wt%, the temperature of maximum NOx uptake (T{sub max}) is 300 C. Increasing the potassium loading from 5wt% to 10 wt%, the T{sub max} gradually shifted from 300 C to 450 C, indicating the dependence of T{sub max} on the potassium loading. However, increase in potassium loading above 10 wt% only gives rise to the reduction in the overall NOx storage capacity. This work also underlines the obstacles these materials have prior to their practical application (e.g., durability and sulfur poisoning/ removal). This work provides fundamental understanding of Pt-K/MgAl{sub 2}O{sub 4}-based lean NOx trap catalysts, which could be good candidates for high temperature LNT applications.« less
NASA Astrophysics Data System (ADS)
Solanki, Ketan Subhash
Hybrid supercapacitors (HSC) have been extensively investigated for enhanced charge storage capacity (Yoo, et al. 2014). Although Li-ion batteries are known for high energy density, but their limited power density has driven the research toward developing hybrid supercapacitors (Jayalakshmi and Balasubramanian 2008). They combine non-faradic properties of electric double layer capacitors (EDLC) and faradic properties of pseudocapacitors to provide high energy density without compromising high Power density (Yoo, et al. 2014) (Lukatskaya, Dunn and Gogotsi 2016). In HSC, one electrode will store energy by double layer mechanism whereas the other stores through redox intercalation or surface redox reactions (Lukatskaya, Dunn and Gogotsi 2016) (Karthikeyan, et al. 2010). In this study, we have examined the electrochemical characteristics of vanadium pentoxide (V2O5) and activated carbon (AC) in an aqueous multivalent aluminum nitrate (nonhydrate, Al(NO3)3) electrolyte for viable electrode applications in battery-type hybrid supercapacitors, also known as supercapattery. A Specific capacitance of 340 Fg -1 was obtained at a scanning rate of 10 mV/s. Although this configuration showed promising storage and cyclability capability but the voltage for intercalation of Al3+ ions occurred below zero voltage. Hence, right selection of electrodes for such configurations may help in obtaining intercalation and de-intercalation voltages above zero volt and thereby result in a viable practical application with better performance.
NASA Astrophysics Data System (ADS)
Prieur, Anne; Bonnet, Jean-François; Combarnous, Michel
2004-11-01
The role of forest ecosystems in the regulation of greenhouse effect at the global scale is developed here, from two points of view, sometimes considered as opposed: carbon storage and wood production for energy. A nomenclature is proposed to understand all the various mechanisms implied in carbon storage. A comparison is made between the effects on carbon emissions of storage alone and storage with wood fuel production. Use of wood energy is proved to be a 'bonus' that could optimise, in the middle and long terms, the use of fossil fuel reserves. To cite this article: A. Prieur et al., C. R. Geoscience 336 (2004).
Da Silva, David; Qin, Liangchun; DeBuse, Carolyn; DeJong, Theodore M
2014-09-01
Developing a conceptual and functional framework for simulating annual long-term carbohydrate storage and mobilization in trees has been a weak point for virtually all tree models. This paper provides a novel approach for solving this problem using empirical field data and details of structural components of simulated trees to estimate the total carbohydrate stored over a dormant season and available for mobilization during spring budbreak. The seasonal patterns of mobilization and storage of non-structural carbohydrates in bark and wood of the scion and rootstock crowns of the trunks of peach (Prunus persica) trees were analysed subsequent to treatments designed to maximize differences in source-sink behaviour during the growing season. Mature peach trees received one of three treatments (defruited and no pruning, severe pruning to 1·0 m, and unthinned with no pruning) in late winter, just prior to budbreak. Selected trees of each treatment were harvested at four times (March, June, August and November) and slices of trunk and root crown tissue above and below the graft union were removed for carbohydrate analysis. Inner bark and xylem tissues from the first to fifth rings were separated and analysed for non-structural carbohydrates. Data from these experiments were then used to estimate the amount of non-structural carbohydrates available for mobilization and to parameterize a carbohydrate storage sub-model in the functional-structural L-PEACH model. The mass fraction of carbohydrates in all sample tissues decreased from March to June, but the decrease was greatest in the severely pruned and unthinned treatments. November carbohydrate mass fractions in all tissues recovered to values similar to those in the previous March, except in the older xylem rings of the severely pruned and unthinned treatment. Carbohydrate storage sink capacity in trunks was empirically estimated from the mean maximum measured trunk non-structural carbohydrate mass fractions. The carbohydrate storage source available for mobilization was estimated from these maximum mass fractions and the early summer minimum mass fractions remaining in these tissues in the severe treatments that maximized mobilization of stored carbohydrates. The L-PEACH sink-source carbohydrate distribution framework was then used along with simulated tree structure to successfully simulate annual carbohydrate storage sink and source behaviour over years. The sink-source concept of carbohydrate distribution within a tree was extended to include winter carbohydrate storage and spring mobilization by considering the storage sink and source as a function of the collective capacity of active xylem and phloem tissue of the tree, and its annual behaviour was effectively simulated using the L-PEACH functional-structural plant model.
Hydrogen: A Promising Fuel and Energy Storage Solution - Continuum
Magazine | NREL Hydrogen: A Promising Fuel and Energy Storage Solution Fuel cell electric Ainscough, NREL Hydrogen: A Promising Fuel and Energy Storage Solution Electrolysis-generated hydrogen may provide a solution to fluctuations in renewable-sourced energy. As electricity from renewable resources
40 CFR 429.100 - Applicability; description of the wet storage subcategory.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Applicability; description of the wet... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS TIMBER PRODUCTS PROCESSING POINT SOURCE CATEGORY Wet Storage Subcategory § 429.100 Applicability; description of the wet storage subcategory. This subpart applies to...
40 CFR 429.100 - Applicability; description of the wet storage subcategory.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Applicability; description of the wet... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS TIMBER PRODUCTS PROCESSING POINT SOURCE CATEGORY Wet Storage Subcategory § 429.100 Applicability; description of the wet storage subcategory. This subpart applies to...
NASA Astrophysics Data System (ADS)
Kabuth, Alina; Dahmke, Andreas; Hagrey, Said Attia al; Berta, Márton; Dörr, Cordula; Koproch, Nicolas; Köber, Ralf; Köhn, Daniel; Nolde, Michael; Tilmann Pfeiffer, Wolf; Popp, Steffi; Schwanebeck, Malte; Bauer, Sebastian
2016-04-01
Within the framework of the transition to renewable energy sources ("Energiewende"), the German government defined the target of producing 60 % of the final energy consumption from renewable energy sources by the year 2050. However, renewable energies are subject to natural fluctuations. Energy storage can help to buffer the resulting time shifts between production and demand. Subsurface geological structures provide large potential capacities for energy stored in the form of heat or gas on daily to seasonal time scales. In order to explore this potential sustainably, the possible induced effects of energy storage operations have to be quantified for both specified normal operation and events of failure. The ANGUS+ project therefore integrates experimental laboratory studies with numerical approaches to assess subsurface energy storage scenarios and monitoring methods. Subsurface storage options for gas, i.e. hydrogen, synthetic methane and compressed air in salt caverns or porous structures, as well as subsurface heat storage are investigated with respect to site prerequisites, storage dimensions, induced effects, monitoring methods and integration into spatial planning schemes. The conceptual interdisciplinary approach of the ANGUS+ project towards the integration of subsurface energy storage into a sustainable subsurface planning scheme is presented here, and this approach is then demonstrated using the examples of two selected energy storage options: Firstly, the option of seasonal heat storage in a shallow aquifer is presented. Coupled thermal and hydraulic processes induced by periodic heat injection and extraction were simulated in the open-source numerical modelling package OpenGeoSys. Situations of specified normal operation as well as cases of failure in operational storage with leaking heat transfer fluid are considered. Bench-scale experiments provided parameterisations of temperature dependent changes in shallow groundwater hydrogeochemistry. As a second example, the option of seasonal hydrogen storage in a deep saline aquifer is considered. The induced thermal and hydraulic multiphase flow processes were simulated. Also, an integrative approach towards geophysical monitoring of gas presence was evaluated by synthetically applying these monitoring methods to the synthetic, however realistically defined numerical storage scenarios. Laboratory experiments provided parameterisations of geochemical effects caused by storage gas leakage into shallow aquifers in cases of sealing failure. Ultimately, the analysis of realistically defined scenarios of subsurface energy storage within the ANGUS+ project allows a quantification of the subsurface space claimed by a storage operation and its induced effects. Acknowledgments: This work is part of the ANGUS+ project (www.angusplus.de) and funded by the German Federal Ministry of Education and Research (BMBF) as part of the energy storage initiative "Energiespeicher".
Permeability and storage ability of inorganic X12Y12 fullerenes for lithium atom and ion
NASA Astrophysics Data System (ADS)
Munsif, Sajida; Ayub, Khurshid
2018-04-01
In the current study, permeability and storage ability (exohedral and endohedral) of inorganic fullerenes X12Y12 (X = B, Al and Y = N, P) for lithium atom/ion (Li/Li+) is studied theoretically at M05-2X method. The translation of Li/Li+ through Al12P12 nano-cages is not only a kinetically feasible process but also has very high separation ratio in the favor of lithium atom over lithium ion. Adsorption/encapsulation energies of alkali metal on/in nano-cages show strong correlation with the size of the nano-cage. The percent changes in H-L gap for Li+-X12Y12 are about 1-25%, whereas the corresponding changes for Li-X12Y12 are 30-72%.
Electrical and Electrorheological Properties of Alumina/Natural Rubber (STR XL) Composites
Tangboriboon, Nuchnapa; Uttanawanit, Nuttapot; Longtong, Mean; Wongpinthong, Piraya; Sirivat, Anuvat; Kunanuruksapong, Ruksapong
2010-01-01
The electrorheological properties (ER) of natural rubber (XL)/alumina (Al2O3) composites were investigated in oscillatory shear mode under DC electrical field strengths between 0 to 2 kV/mm. SEM micrographs indicate a mean particle size of 9.873 ± 0.034 µm and particles that are moderately dispersed in the matrix. The XRD patterns indicate Al2O3 is of the β-phase polytype which possesses high ionic conductivity. The storage modulus (G′) of the composites, or the rigidity, increases by nearly two orders of magnitude, with variations in particle volume fraction and electrical field strength. The increase in the storage modulus is caused the ionic polarization of the alumina particles and the induced dipole moments set up in the natural rubber matrix.
NASA Astrophysics Data System (ADS)
Pugh, C.; Reed, D. E.; Desai, A. R.; Sulman, B. N.
2016-12-01
Wetlands play a disproportionately large role in the global carbon budget, and individual wetlands can fluctuate between carbon sinks and sources depending on factors such as hydrology, biogeochemistry, and land use. Although much research has been done on wetland biogeochemical cycles, there is a lack of experimental evidence concerning how changes in wetland hydrology influence these cycles over interannual timescales. Over a seven-year period, Sulman et al. (2009) found that a drought-induced declining water table at a shrub wetland in northern Wisconsin coincided with increased ecosystem respiration (ER) and gross ecosystem productivity (GEP) (Sulman et al. 2009). Since then, however, the average water table level at this site has begun to increase, thus allowing a unique opportunity to explore how wetland carbon storage is impacted by water table recovery. With the addition of three more years of eddy covariance observations post recovery and new methane flux observations, we found that water table level no longer had a significant correlation with GEP, ER, or methane flux. Air temperature, however, had a strong correlation with all three. Average methane flux stayed relatively constant under 14 °C, before increasing an order of magnitude from 3.7 nmol m-2 s-1 in April to 36 nmol m-2 s-1 in July. These results suggest that, over decadal timescales, temperature, rather than water level, is a stronger limiting factor for both aerobic and anaerobic respiration in shrub fen wetlands. Wetlands play a disproportionately large role in the global carbon budget, and individual wetlands can fluctuate between carbon sinks and sources depending on factors such as hydrology, biogeochemistry, and land use. Although much research has been done on wetland biogeochemical cycles, there is a lack of experimental evidence concerning how changes in wetland hydrology influence these cycles over interannual timescales. Over a seven-year period, Sulman et al. (2009) found that a drought-induced declining water table at a shrub wetland in northern Wisconsin coincided with increased ecosystem respiration (ER) and gross ecosystem productivity (GEP) (Sulman et al. 2009). Since then, however, the average water table level at this site has begun to increase, thus allowing a unique opportunity to explore how wetland carbon storage is impacted by water table recovery. With the addition of three more years of eddy covariance observations post recovery and new methane flux observations, we found that water table level no longer had a significant correlation with GEP, ER, or methane flux. Air temperature, however, had a strong correlation with all three. Average methane flux stayed relatively constant under 14 °C, before increasing an order of magnitude from 3.7 nmol m-2 s-1 in April to 36 nmol m-2 s-1 in July. These results suggest that, over decadal timescales, temperature, rather than water level, is a stronger limiting factor for both aerobic and anaerobic respiration in shrub fen wetlands.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nelson, P.A.; Yao, N.P.; Steunenberg, R.K.
1977-04-01
These batteries are being developed for electric vehicle propulsion and for stationary energy storage applications. The present battery cells, which operate at 400 to 450/sup 0/C, are of a vertically oriented, prismatic design with a central positive electrode of FeS or FeS/sub 2/, two facing negative electrodes of lithium--aluminum alloy, and an electrolyte of molten LiCl--KCl. Testing and evaluation of industrially fabricated cells is continuing. During this period, Li--Al/FeS and Li--Al/FeS/sub 2/ cells from Eagle-Picher Industries were tested, and tests of Li--Al/FeS cells from Gould Inc. were initiated. The cells are tested individually and in parallel and series battery configurations.more » These tests provide information on the effects of cell design modifications and alternative materials. Improved electrode and cell designs are being developed and tested at ANL, and the more promising designs are incorporated in the industrially fabricated cells. Among the concepts receiving major attention are carbon-bonded positive electrodes, scaled-up stationary energy storage cell designs, additives to extend electrode lifetime, and alternative electrode separators. The materials development efforts include the development of a new lightweight electrical feedthrough; investigations of new separator materials (e.g.,Y/sub 2/O/sub 3/ powder, Y/sub 2/O/sub 3/ felt, and porous, rigid ceramics); corrosion tests of materials for cell components; and postoperative examinations of cells. The cell chemistry studies were directed to discharge mechanisms of FeS electrodes, emf measurements of the LiAl/FeS/sub 2/ couple at various states of discharge, and studies of other transition-metal sulfides as positive-electrode materials. The advanced battery effort mainly concerned the use of calcium alloys for negative electrode and transition metal sulfides or oxides for the positive electrode. 13 figures, 18 tables.« less
A Critical Review of the Impacts of Leaking CO 2 Gas and Brine on Groundwater Quality
DOE Office of Scientific and Technical Information (OSTI.GOV)
Qafoku, Nikolla; Zheng, Liange; Bacon, Diana H.
2015-09-30
Geological carbon sequestration (GCS) is a global carbon emission reduction strategy involving the capture of CO 2 emitted from fossil fuel burning power plants, as well as the subsequent injection of the captured CO 2 gas into deep saline aquifers or depleted oil and gas reservoirs. A critical question that arises from the proposed GCS is the potential impacts of CO 2 injection on the quality of drinking-water systems overlying CO 2 sequestration storage sites. Although storage reservoirs are evaluated and selected based on their ability to safely and securely store emplaced fluids, leakage of CO 2 from storage reservoirsmore » is a primary risk factor and potential barrier to the widespread acceptance of geologic CO 2 sequestration (OR Harvey et al. 2013; Y-S Jun et al. 2013; DOE 2007). Therefore, a systematic understanding of how CO 2 leakage would affect the geochemistry of potable aquifers, and subsequently control or affect elemental and contaminant release via sequential and/or simultaneous abiotic and biotic processes and reactions is vital.« less
Werbrouck, Eva; Van Gansbeke, Dirk; Vanreusel, Ann; De Troch, Marleen
2016-01-01
The utilization of storage lipids and their associated fatty acids (FA) is an important means for organisms to cope with periods of food shortage, however, little is known about the dynamics and FA mobilization in benthic copepods (order Harpacticoida). Furthermore, lipid depletion and FA mobilization may depend on the ambient temperature. Therefore, we subjected the temperate copepod Platychelipus littoralis to several intervals (3, 6 and 14 days) of food deprivation, under two temperatures in the range of the normal habitat temperature (4, 15 °C) and under an elevated temperature (24 °C), and studied the changes in FA composition of storage and membrane lipids. Although bulk depletion of storage FA occurred after a few days of food deprivation under 4 °C and 15 °C, copepod survival remained high during the experiment, suggesting the catabolization of other energy sources. Ambient temperature affected both the degree of FA depletion and the FA mobilization. In particular, storage FA were more exhausted and FA mobilization was more selective under 15 °C compared with 4 °C. In contrast, depletion of storage FA was limited under an elevated temperature, potentially due to a switch to partial anaerobiosis. Food deprivation induced selective DHA retention in the copepod's membrane, under all temperatures. However, prolonged exposure to heat and nutritional stress eventually depleted DHA in the membranes, and potentially induced high copepod mortality. Storage lipids clearly played an important role in the short-term response of the copepod P. littoralis to food deprivation. However, under elevated temperature, the use of storage FA as an energy source is compromised.
NASA Astrophysics Data System (ADS)
Escalas, M.; Queralt, P.; Ledo, J.; Marcuello, A.
2012-04-01
Magnetotelluric (MT) method is a passive electromagnetic technique, which is currently used to characterize sites for the geological storage of CO2. These later ones are usually located nearby industrialized, urban or farming areas, where man-made electromagnetic (EM) signals contaminate the MT data. The identification and characterization of the artificial EM sources which generate the so-called "cultural noise" is an important challenge to obtain the most reliable results with the MT method. The polarization attributes of an EM signal (tilt angle, ellipticity and phase difference between its orthogonal components) are related to the character of its source. In a previous work (Escalas et al. 2011), we proposed a method to distinguish natural signal from cultural noise in the raw MT data. It is based on the polarization analysis of the MT time-series in the time-frequency domain, using a wavelet scheme. We developed an algorithm to implement the method, and was tested with both synthetic and field data. In 2010, we carried out a controlled-source electromagnetic (CSEM) experiment in the Hontomín site (the Research Laboratory on Geological Storage of CO2 in Spain). MT time-series were contaminated at different frequencies with the signal emitted by a controlled artificial EM source: two electric dipoles (1 km long, arranged in North-South and East-West directions). The analysis with our algorithm of the electric field time-series acquired in this experiment was successful: the polarization attributes of both the natural and artificial signal were obtained in the time-frequency domain, highlighting their differences. The processing of the magnetic field time-series acquired in the Hontomín experiment has been done in the present work. This new analysis of the polarization attributes of the magnetic field data has provided additional information to detect the contribution of the artificial source in the measured data. Moreover, the joint analysis of the polarization attributes of the electric and magnetic field has been crucial to fully characterize the properties and the location of the noise source. Escalas, M., Queralt, P., Ledo, J., Marcuello, A., 2011. Identification of cultural noise sources in magnetotelluric data: estimating polarization attributes in the time-frequency domain using wavelet analysis. Geophysical Research Abstracts Vol. 13, EGU2011-6085. EGU General Assembly 2011.
Erosion of an ancient mountain range, the Great Smoky Mountains, North Carolina and Tennessee
Matmon, A.; Bierman, P.R.; Larsen, J.; Southworth, S.; Pavich, M.; Finkel, R.; Caffee, M.
2003-01-01
Analysis of 10Be and 26Al in bedrock (n=10), colluvium (n=5 including grain size splits), and alluvial sediments (n=59 including grain size splits), coupled with field observations and GIS analysis, suggest that erosion rates in the Great Smoky Mountains are controlled by subsurface bedrock erosion and diffusive slope processes. The results indicate rapid alluvial transport, minimal alluvial storage, and suggest that most of the cosmogenic nuclide inventory in sediments is accumulated while they are eroding from bedrock and traveling down hill slopes. Spatially homogeneous erosion rates of 25 - 30 mm Ky-1 are calculated throughout the Great Smoky Mountains using measured concentrations of cosmogenic 10Be and 26Al in quartz separated from alluvial sediment. 10Be and 26Al concentrations in sediments collected from headwater tributaries that have no upstream samples (n=18) are consistent with an average erosion rate of 28 ?? 8 mm Ky-1, similar to that of the outlet rivers (n=16, 24 ?? 6 mm Ky-1), which carry most of the sediment out of the mountain range. Grain-size-specific analysis of 6 alluvial sediment samples shows higher nuclide concentrations in smaller grain sizes than in larger ones. The difference in concentrations arises from the large elevation distribution of the source of the smaller grains compared with the narrow and relatively low source elevation of the large grains. Large sandstone clasts disaggregate into sand-size grains rapidly during weathering and downslope transport; thus, only clasts from the lower parts of slopes reach the streams. 26Al/10Be ratios do not suggest significant burial periods for our samples. However, alluvial samples have lower 26Al/10Be ratios than bedrock and colluvial samples, a trend consistent with a longer integrated cosmic ray exposure history that includes periods of burial during down-slope transport. The results confirm some of the basic ideas embedded in Davis' geographic cycle model, such as the reduction of relief through slope processes, and of Hack's dynamic equilibrium model such as the similarity of erosion rates across different lithologies. Comparing cosmogenic nuclide data with other measured and calculated erosion rates for the Appalachians, we conclude that rates of erosion, integrated over varying time periods from decades to a hundred million years are similar, the result of equilibrium between erosion and isostatic uplift in the southern Appalachian Mountains.
The Stellar-mass Black Hole IGR J17091-3624 is in an Active State
NASA Astrophysics Data System (ADS)
Miller, J. M.; Reynolds, M. T.; Cenko, B.; Kennea, J.
2018-02-01
IGR J17091-3624 is a recurrent transient source, and a strong black hole candidate. The source has shown many of the same X-ray timing behaviors and "states" as GRS 1915+105 (e.g., Altamirano et al. 2011, Court et al. 2017), as well as relativistic disk reflection and strong winds (Reis et al. 2012, Xu et al. 2017; King et al. 2012).
Improved control strategy for wind-powered refrigerated storage of apples
DOE Office of Scientific and Technical Information (OSTI.GOV)
Baldwin, J.D.C.
1979-01-01
The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance was also conducted. The results of these tests have been presented. An improved control strategy was developed tomore » improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment.« less
Vacuum system for room temperature X-ray lithography source (XLS)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schuchman, J.C.
1988-09-30
A prototype room-temperature X-Ray Lithography Source (XLS)was proposed to be built at Brookhaven National Laboratory as part of a technology-transfer- to-American-industry program. The overall machine comprises a full energy linac, a 170 meter long transport line, and a 39 meter circumference storage ring. The scope of this paper will be limited to describing the storage ring vacuum system. (AIP)
Vacuum system for room temperature X-ray lithography source (XLS)
NASA Astrophysics Data System (ADS)
Schuchman, J. C.
1988-09-01
A prototype room-temperature X-Ray Lithography Source (XLS)was proposed to be built at Brookhaven National Laboratory as part of a technology-transfer- to-American-industry program. The overall machine comprises a full energy linac, a 170 meter long transport line, and a 39 meter circumference storage ring. The scope of this paper will be limited to describing the storage ring vacuum system. (AIP)
Safe arming system for two-explosive munitions
Jaroska, Miles F.; Niven, William A.; Morrison, Jasper J.
1978-01-01
A system for safely and positively detonating high-explosive munitions, including a source of electrical signals, a split-phase square-loop transformer responsive solely to a unique series of signals from the source for charging an energy storage circuit through a voltage doubling circuit, and a spark-gap trigger for initiating discharge of the energy in the storage circuit to actuate a detonator and thereby fire the munitions.
2015-10-13
Fabrication (3) Integrate Membrane & (4) Fill with Hydrogen Shaped Al Aluminum Oxide Nanocapillary Array CNT Coated Pore Wall Complete Gas Storage...nanocapillary arrays are produced through aluminum anodization . The nanocapillary arrays are capped with either a PEM or an alkaline (anion) exchange...24,600 psi) Circumferential Stress Proportional to Pore radius Wall thickness Aluminum AAO AAO /CNT Nanocapillary Array (Not to scale
Control Strategy: Wind Energy Powered Variable Chiller with Thermal Ice Storage
2014-12-01
New York, 2013. [8] A. Togelou et al., “Wind power forecasting in the absence of historical data,” IEEE trans. on sustainable energy, vol. 3, no...WIND ENERGY POWERED VARIABLE CHILLER WITH THERMAL ICE STORAGE by Rex A. Boonyobhas December 2014 Thesis Advisor: Anthony J. Gannon Co...AND DATES COVERED December 20 14 Master ’s Thesis 4. TITLE AND SUBTITLE 5. FUNDING NUMBERS CONTROL STRATEGY: WIND ENERGY POWERED VARIABLE CHILLER
[Arginase Level in Suspended Red Blood Cells Storaged for Different Time].
Fan, Li-Ping; Huang, Hao-Bo; Wei, Shi-Jin; Fu, Dan-Hui; Zeng, Feng; Huang, Qing-Hua; Hong, Jin-Quan
2015-10-01
To explore the effect of storage time on arginase level, and the possible source of arginase in suspended red blood cells (RBC). The arginase and myeloperoxidase (MPO) levels in suspended RBC and control plasma were detected by ELISA. The free hemoglobin level in suspended RBC and control plasma were detected by colorimetric method. The relationship between arginase level, MPO level and free hemoglobin level in suspended RBC was analyzed by the related methods. The arginase and free hemoglobin levels in suspended RBC were higher than those in control plasma. Otherwise, MPO level was not significantly different between suspended RBC and control plasma. All of them did not increase along with prolonging of storage time. There was not a significant correlation between arginase level and free hemoglobin level in suspended RBC of different storage time (r = 0.03), but arginase level positively correlated with MPO level in the suspended RBC of different storage time (r = 0.76). The arginase level in suspended RBC storaged for different time increases significantly, but not along with prolonging of storage time. The main possible source of arginase in the suspended RBC is the residual white blood cell, especially neutrophils.
NASA Astrophysics Data System (ADS)
Popp, Steffi; Beyer, Christof; Dahmke, Andreas; Bauer, Sebastian
2016-04-01
In urban regions, with high population densities and heat demand, seasonal high temperature heat storage in the shallow subsurface represents an attractive and efficient option for a sustainable heat supply. In fact, the major fraction of energy consumed in German households is used for room heating and hot water production. Especially in urbanized areas, however, the installation of high temperature heat storage systems is currently restricted due to concerns on negative influences on groundwater quality caused e.g. by possible interactions between heat storages and subsurface contaminants, which are a common problem in the urban subsurface. Detailed studies on the overall impact of the operation of high temperature heat storages on groundwater quality are scarce. Therefore, this work investigates possible interactions between groundwater temperature changes induced by heat storage via borehole heat exchangers and subsurface contaminations by numerical scenario analysis. For the simulation of non-isothermal groundwater flow, and reactive transport processes the OpenGeoSys code is used. A 2D horizontal cross section of a shallow groundwater aquifer is assumed in the simulated scenario, consisting of a sandy sediment typical for Northern Germany. Within the aquifer a residual trichloroethene (TCE) contaminant source zone is present. Temperature changes are induced by a seasonal heat storage placed within the aquifer with scenarios of maximum temperatures of 20°C, 40°C and 60°C, respectively, during heat injection and minimum temperatures of 2°C during heat extraction. In the scenario analysis also the location of the heat storage relative to the TCE source zone and plume was modified. Simulations were performed in a homogeneous aquifer as well as in a set of heterogeneous aquifers with hydraulic conductivity as spatially correlated random fields. In both cases, results show that the temperature increase in the heat plume and the consequential reduction of water viscosity lead to locally increased groundwater flow. Depending on the positioning of the heat storage relative to the TCE contamination, groundwater fluxes hence may be induced to increase within or partially bypass the TCE source zone. At the same time, TCE solubility decreases between 10 and 40 °C, which reduces TCE emission and almost compensates for the effects of a temperature induced increase of groundwater flow through the source zone. In total, the numerical simulations thus show only minor influences of the heat plume on the TCE emission compared to a thermally undisturbed aquifer. Acknowledgments: This work is part of the ANGUS+ project (www.angusplus.de) and funded by the German Federal Ministry of Education and Research (BMBF) as part of the energy storage initiative "Energiespeicher".
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for coal processing and conveying equipment, coal storage systems, transfer and loading systems, and open storage piles. 60.254... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Coal Preparation...
40 CFR 412.46 - New source performance standards (NSPS).
Code of Federal Regulations, 2014 CFR
2014-07-01
... designed open manure storage structure. For those CAFOs where 100 years of local weather data for the CAFO... based upon a site-specific evaluation of the CAFO's open surface manure storage structure. The NPDES... the case of any CAFO using an open surface manure storage structure for which the Director establishes...
40 CFR 412.46 - New source performance standards (NSPS).
Code of Federal Regulations, 2013 CFR
2013-07-01
... designed open manure storage structure. For those CAFOs where 100 years of local weather data for the CAFO... based upon a site-specific evaluation of the CAFO's open surface manure storage structure. The NPDES... the case of any CAFO using an open surface manure storage structure for which the Director establishes...
40 CFR 412.46 - New source performance standards (NSPS).
Code of Federal Regulations, 2012 CFR
2012-07-01
... designed open manure storage structure. For those CAFOs where 100 years of local weather data for the CAFO... based upon a site-specific evaluation of the CAFO's open surface manure storage structure. The NPDES... the case of any CAFO using an open surface manure storage structure for which the Director establishes...
Magnetic field sources and their threat to magnetic media
NASA Technical Reports Server (NTRS)
Jewell, Steve
1993-01-01
Magnetic storage media (tapes, disks, cards, etc.) may be damaged by external magnetic fields. The potential for such damage has been researched, but no objective standard exists for the protection of such media. This paper summarizes a magnetic storage facility standard, Publication 933, that ensures magnetic protection of data storage media.
40 CFR 63.545 - What are my standards for fugitive dust sources?
Code of Federal Regulations, 2013 CFR
2013-07-01
.... (4) Battery storage area. (5) Equipment maintenance. (6) Material storage areas. (7) Material... achieve 99.97 percent capture efficiency for 0.3 micron particles in a manner that does not generate... 40 CFR 302.4). (4) Battery storage areas. You must inspect any batteries that are not stored in a...
40 CFR 63.545 - What are my standards for fugitive dust sources?
Code of Federal Regulations, 2012 CFR
2012-07-01
.... (4) Battery storage area. (5) Equipment maintenance. (6) Material storage areas. (7) Material... achieve 99.97 percent capture efficiency for 0.3 micron particles in a manner that does not generate... 40 CFR 302.4). (4) Battery storage areas. You must inspect any batteries that are not stored in a...
40 CFR 63.545 - What are my standards for fugitive dust sources?
Code of Federal Regulations, 2014 CFR
2014-07-01
.... (4) Battery storage area. (5) Equipment maintenance. (6) Material storage areas. (7) Material... achieve 99.97 percent capture efficiency for 0.3 micron particles in a manner that does not generate... 40 CFR 302.4). (4) Battery storage areas. You must inspect any batteries that are not stored in a...
Rajwanshi, P; Singh, V; Gupta, M K; Kumari, V; Shrivastav, R; Ramanamurthy, M; Dass, S
1997-01-30
Studies were conducted in order to assess the level of aluminium (Al) in samples of Indian tea, coffee, toothpaste, paan masala (mouth freshener) and baking powder. Leaching of Al from cookware while preparing tea and coffee was also studied. Experiments were also conducted to study the sequential leaching of Al from cookware by preparing tea and coffee in the presence of standard size Al sheets (coupons). A small amount of Al was found to have leached from coupons during preparation of tea. Tea leaves, were found to be a rich source of Al and a maximum of 2.2% Al is extracted in tea infusions. Coffee powder on the other hand was not found to be a rich source of Al. Baking powder was found to be a rich source of Al and 1 kg of cake prepared with 1-3 teaspoon of baking powder may contain 2-12.7 mg of Al in each serving (25 g). Toothpaste also contains a significant quantity of Al, more so, when packed in Al tubes. Ingestion pattern of Al from these items by humans is also discussed.
Proximity of residence to an old mineral storage site in Chile and blood lead levels in children.
Lisboa, Loreto; Klarián, José; Campos, Rosario Toro; Iglesias, Verónica
2016-01-01
Evidence suggests that an old mineral storage site removed in 1998 due to high lead content, remains as a source of exposure in the city of Antofagasta, Chile. The aim was to determine the association between blood lead levels in children and the residential proximity to the old mineral storage site. A cross sectional study was conducted with 185 children aged 7 to 16 years. The outcome variable was blood lead levels measured in 2005. The exposure variable was the distance between the current residence and the old mineral storage site. The distance was measured in meters by Geographic Information System (GIS). The median blood lead level in 2005 was 3.3μg/dL (interquartile range ‒ IQR: 2.0-4.3). A significant inverse association was found between the residential distance to the old mineral storage site and the blood lead levels in children, after adjusting by confounders (β: -0.04; 95%CI: -0.09; -0.01). This result suggests that the old mineral storage site continues to be a source of lead exposure for the children living nearby.
NASA Astrophysics Data System (ADS)
Pan, Yuepeng; Liu, Yongwen; Wentworth, Gregory R.; Zhang, Lin; Zhao, Yuanhong; Li, Yi; Liu, Xuejun; Du, Enzai; Fang, Yunting; Xiao, Hongwei; Ma, Hongyuan; Wang, Yuesi
2017-03-01
In a publication in Atmospheric Environment (http://dx.doi.org/10.1016/j.atmosenv.2015.10.081), Gu et al. (2015) estimated that "the total nitrogen (N) deposition in 2010 was 2.32 g N m-2 yr-1" in China. This value is comparable with previous estimations based on a synthesized dataset of wet/bulk inorganic N deposition observations, which underestimates the total N deposition since their algorithm (equations (2) and (3) in their paper) does not account for dry deposition of NH3, HNO3, NOx and wet/dry deposition of HONO and organic nitrogen (e.g. amines, amides, PAN). Indeed, Gu et al. (2015) mixed the terminology of wet/bulk deposition and total deposition. Another flawed assumption by Gu et al. (2015) is that all inorganic N in precipitation estimated by their algorithm originates from fertilizer and coal combustion. This is incorrect and almost certainly causes biases in the spatial and temporal distribution of estimated wet/bulk inorganic N deposition (Fig. 5 in their paper), further considering the fact that they neglected important N sources like livestock and they did not consider the nonlinearity between various sources and deposition. Besides the input data on N deposition, the model validation (Sect. 2.3.2) described in their paper also requires clarification because the detailed validation information about the time series of observational dataset versus modeling results was not given. As a result of these combined uncertainties in their estimation of N deposition and the lack of detail for model-measurement comparison, their estimates of the impacts of N deposition on carbon storage in Chinese forests may need further improvement. We suggest the clarification of the terminology regarding N deposition, especially for wet deposition, bulk deposition, gaseous and particulate dry deposition or total deposition since the accurate distinction between these terms is crucial to investigating and estimating the effects of N deposition on ecosystems.
A high resolution global scale groundwater model
NASA Astrophysics Data System (ADS)
de Graaf, I. E.; Sutanudjaja, E.; Van Beek, L. P.; Bierkens, M. F.
2013-12-01
As the world's largest accessible source of freshwater, groundwater plays a vital role in satisfying the basic needs of human society. It serves as a primary source of drinking water and also supplies water for agricultural and industrial activities. During times of drought, the large natural groundwater storage provides a buffer against water shortage and sustains flows to rivers and wetlands, supporting ecosystem habitats and biodiversity. Yet, the current generation of global scale hydrological models (GHMs) do not include a groundwater flow component, although it is a crucial part of the hydrological cycle. Thus, a realistic physical representation of the groundwater system that allows for the simulation of groundwater head dynamics and lateral flows is essential for GHMs that increasingly run at finer resolution. In this study we present a transient global groundwater model with a resolution of 5 arc-minutes (approximately 10 km at the equator) using MODFLOW (McDonald and Harbaugh, 1988). Aquifer schematization and properties of this groundwater model were developed from available global lithological maps and datasets (Dürr et al., 2005; Gleeson et al., 2010; Hartmann and Moosdorf, 2013) combined with information about e.g. aquifer thickness and presence of less permeable, impermeable, and semi-impermeable layers. For the parameterization, we relied entirely on available global datasets and did not calibrate the model so that it can equally be expanded to data poor environments. We forced the groundwater model with the output from the global hydrological model PCR-GLOBWB (van Beek et al., 2011), specifically the net groundwater recharge and average surface water levels derived from routed channel discharge. We validated simulated groundwater heads with observations, from North America and Australia, resulting in a coefficient of determination of 0.8 and 0.7 respectively. This shows that it is feasible to build a global groundwater model using best available global information, and estimated water table depths are within acceptable accuracy in many parts of the world.
Global, continental and regional water balance estimates from HYPE catchment modelling
NASA Astrophysics Data System (ADS)
Arheimer, Berit; Andersson, Jafet; Crochemore, Louise; Donnelly, Chantal; Gustafsson, David; Hasan, Abdoulghani; Isberg, Kristina; Pechlivanidis, Ilias; Pimentel, Rafael; Pineda, Luis
2017-04-01
In the past, catchment modelling mainly focused on simulating the lumped hydrological cycle at local to regional domains with high precision in a specific point of a river. Today, the level of maturity in hydrological process descriptions, input data and methods for parameter constraints makes it possible to apply these models also for multi-basins over large domains, still using the catchment modellers approach with high demands on agreement with observed data. HYPE is a process-oriented, semi-distributed and open-source model concept that is developed and used operationally in Sweden since a decade. Its finest calculation unit is hydrological response units (HRUs) in a catchment and these are assumed to give the same rainfall-runoff response. HRUs are normally made up of similar land cover and management, combined with soil type or elevation. Water divides are retrieved from topography and calculations are integrated for catchments, which can be of different spatial resolution and are coupled along the river network. In each catchment, HYPE calculates the water balance of a given time-step separately for various hydrological storages, such glaciers, active soil, groundwater, river channels, wetlands, floodplains, and lakes. The model is calibrated in a step-wise manner (following the water path-ways) against various sources additional data sources, including in-situ observations, Earth Observation products, soft information and expert judgements (Arheimer et al., 2012; Donnelly et al, 2016; Pechlivanidis and Arheimer 2015). Both the HYPE code and the model set-ups (i.e. input data and parameter values) are frequently released in new versions as they are continuously improved and updated. This presentation will show the results of aggregated water-balance components over large domains, such as the Arctic basin, the European continent, the Indian subcontinent and the Niger River basin. These can easily be compared to results from other kind of large-scale modelling approaches. The presentation will also show model performance vs observed data from river gauges and other data sources at local and regional scale. Finally, the results will be compared to a first model run of a world-wide HYPE covering all earth surfaces except from the Antarctic. The World-Wide HYPE has a resolution for calculation and evaluation of on average <1000 km2. References: Arheimer, B. et al. 2012. Water and nutrient simulations using the HYPE …. Hydrology research 43(4):315-329. Donnelly, C et al., 2016. Using flow signatures ….. Hydr. Sciences Journal 61(2):255-273, doi: 10.1080/02626667.2015.1027710 Pechlivanidis, I. G. and Arheimer, B. 2015. Large-scale hydrological modelling …, Hydrol. Earth Syst. Sci., 19, 4559-4579, doi:10.5194/hess-19-4559-2015
Scalable cloud without dedicated storage
NASA Astrophysics Data System (ADS)
Batkovich, D. V.; Kompaniets, M. V.; Zarochentsev, A. K.
2015-05-01
We present a prototype of a scalable computing cloud. It is intended to be deployed on the basis of a cluster without the separate dedicated storage. The dedicated storage is replaced by the distributed software storage. In addition, all cluster nodes are used both as computing nodes and as storage nodes. This solution increases utilization of the cluster resources as well as improves fault tolerance and performance of the distributed storage. Another advantage of this solution is high scalability with a relatively low initial and maintenance cost. The solution is built on the basis of the open source components like OpenStack, CEPH, etc.
NASA Astrophysics Data System (ADS)
Wettermark, G.
1980-10-01
Energy storage problems are explored. Tomorrow's energy sources will provide a continuous flow of energy. Matching supply and demand will necessitate a wide range of storage capabilities. For storing heat thermochemical and economic solutions may take advantage of the various options inherent in this kind of storage, namely heat pumping, transport of heat and direct conversion to other desired forms of energy such as electricity and mechanical work. There is a need to regularly summarize the knowledge and research in the field of thermochemical energy storage in different parts of the world.
A 1kW EUV source for lithography based on FEL emission in a compact storage ring
NASA Astrophysics Data System (ADS)
Feser, Michael; Ruth, Ron; Loewen, Rod
2017-10-01
EUV has long been hailed as the next generation lithography technology. Its adoption into high volume manufacturing (HVM), however, has been delayed several technology nodes due to technical issues, many of which can be attributed to the EUV source performance. Today's EUV lithography scanners are powered by laser produce plasma (LPP) sources. They have issues with power scaling beyond 300 W, reliability and contamination. Free Electron Lasers (FELs) have been considered as an alternative EUV source. Advantages of accelerator based sources are the maturity of the accelerator technology, lack of debris/contamination, and ability to provide high power. Industry turned away from this technology because of the requirement to feed up to 10 scanners from one linear FEL to make it economically feasible, the large footprint, and generation of radioactive byproducts. All of these issues are overcome in the presented concept using a compact storage ring with steady-state FEL lasing action. At 1 kW output power, comparable cost and footprint to an LPP source, this source is ideally suited for use on a single scanner and promises reliable, contamination free operation. FEL action in the storage ring is sustained by operating the FEL well below the saturation regime and preserving the equilibrium low emittance and energy distribution of the ring.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cochran, J.R.; Danneels, J.; Kenagy, W.D.
The Al Tuwaitha nuclear complex near Baghdad contains a significant number of nuclear facilities from Saddam Hussein's dictatorship. Because of past military operations, lack of upkeep and looting there is now an enormous radioactive waste problem at Al Tuwaitha. Al Tuwaitha contains uncharacterised radioactive wastes, yellow cake, sealed radioactive sources, and contaminated metals. The current security situation in Iraq hampers all aspects of radioactive waste management. Further, Iraq has never had a radioactive waste disposal facility, which means that ever increasing quantities of radioactive waste and material must be held in guarded storage. The Iraq Nuclear Facility Dismantlement and Disposalmore » Program (the NDs Program) has been initiated by the U.S. Department of State (DOS) to assist the Government of Iraq (GOI) in eliminating the threats from poorly controlled radioactive materials, while building human capacities so that the GOI can manage other environmental cleanups in their country. The DOS has funded the International Atomic Energy Agency (IAEA) to provide technical assistance to the GOI via a Technical Cooperation Project. Program coordination will be provided by the DOS, consistent with U.S. and GOI policies, and Sandia National Laboratories will be responsible for coordination of participants and for providing waste management support. Texas Tech University will continue to provide in-country assistance, including radioactive waste characterization and the stand-up of the Iraq Nuclear Services Company. The GOI owns the problems in Iraq and will be responsible for the vast majority of the implementation of the NDs Program. (authors)« less
Multi-port, optically addressed RAM
NASA Technical Reports Server (NTRS)
Johnston, Alan R. (Inventor); Nixon, Robert H. (Inventor); Bergman, Larry A. (Inventor); Esener, Sadik (Inventor)
1989-01-01
A random access memory addressing system utilizing optical links between memory and the read/write logic circuits comprises addressing circuits including a plurality of light signal sources, a plurality of optical gates including optical detectors associated with the memory cells, and a holographic optical element adapted to reflect and direct the light signals to the desired memory cell locations. More particularly, it is a multi-port, binary computer memory for interfacing with a plurality of computers. There are a plurality of storage cells for containing bits of binary information, the storage cells being disposed at the intersections of a plurality of row conductors and a plurality of column conductors. There is interfacing logic for receiving information from the computers directing access to ones of the storage cells. There are first light sources associated with the interfacing logic for transmitting a first light beam with the access information modulated thereon. First light detectors are associated with the storage cells for receiving the first light beam, for generating an electrical signal containing the access information, and for conducting the electrical signal to the one of the storage cells to which it is directed. There are holographic optical elements for reflecting the first light beam from the first light sources to the first light detectors.
Doped calcium manganites for advanced high-temperature thermochemical energy storage
Babiniec, Sean M.; Coker, Eric N.; Miller, James E.; ...
2015-12-16
Developing efficient thermal storage for concentrating solar power plants is essential to reducing the cost of generated electricity, extending or shifting the hours of operation, and facilitating renewable penetration into the grid. Perovskite materials of the CaB xMn 1-xO 3-δ family, where B = Al or Ti, promise improvements in cost and energy storage density over other perovskites currently under investigation. Thermogravimetric analysis of the thermal reduction and reoxidation of these materials was used to extract equilibrium thermodynamic parameters. Lastly, the results demonstrate that these novel thermochemical energy storage media display the highest reaction enthalpy capacity for perovskites reported tomore » date, with a reaction enthalpy of 390 kJ/kg, a 56% increase over previously reported compositions.« less
General Conformity Training Modules: Appendix A Sample Emissions Calculations
Appendix A of the training modules gives example calculations for external and internal combustion sources, construction, fuel storage and transfer, on-road vehicles, aircraft operations, storage piles, and paved roads.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Luo, Jinyong; Gao, Feng; Karim, Ayman M.
MgAlOx mixed oxides were employed as supports for potassium-based lean NOx traps (LNTs) targeted for high temperature applications. Effects of support compositions, K/Pt loadings, thermal aging and catalyst regeneration on NOx storage capacity were systematically investigated. The catalysts were characterized by XRD, NOx-TPD, TEM, STEM-HAADF and in-situ XAFS. The results indicate that MgAlOx mixed oxides have significant advantages over conventional gamma-Al2O3-supports for LNT catalysts, in terms of high temperature NOx trapping capacity and thermal stability. First, as a basic support, MgAlOx stabilizes stored nitrates (in the form of KNO3) to much higher temperatures than mildly acidic gamma-Al2O3. Second, MgAlOx minimizesmore » Pt sintering during thermal aging, which is not possible for gamma-Al2O3 supports. Notably, combined XRD, in-situ XAFS and STEM-HAADF results indicate that Pt species in the thermally aged Pt/MgAlOx samples are finely dispersed in the oxide matrix as isolated atoms. This strong metal-support interaction stabilizes Pt and minimizes the extent of sintering. However, such strong interactions result in Pt oxidation via coordination with the support so that NO oxidation activity can be adversely affected after aging which, in turn, decreases NOx trapping ability for these catalysts. Interestingly, a high-temperature reduction treatment regenerates essentially full NOx trapping performance. In fact, regenerated Pt/K/MgAlOx catalyst exhibits much better NOx trapping performance than fresh Pt/K/Al2O3 LNTs over the entire temperature range investigated here. In addition to thermal aging, Pt/K loading effects were systemically studied over the fresh samples. The results indicate that NOx trapping is kinetically limited at low temperatures, while thermodynamically limited at high temperatures. A simple conceptual model was developed to explain the Pt and K loading effects on NOx storage. An optimized K loading, which allows balancing between the stability of nitrates and exposed Pt surface, gives the best NOx trapping capability.« less
MTR BASEMENT. DOORWAY TO SOURCE STORAGE VAULT IS AT CENTER ...
MTR BASEMENT. DOORWAY TO SOURCE STORAGE VAULT IS AT CENTER OF VIEW; TO DECONTAMINATION ROOM, AT RIGHT. PART OF MAZE ENTRY IS VISIBLE INSIDE VAULT DOORWAY. INL NEGATIVE NO. 7763. Unknown Photographer, photo was dated as 3/30/1953, but this was probably an error. The more likely date is 3/30/1952. - Idaho National Engineering Laboratory, Test Reactor Area, Materials & Engineering Test Reactors, Scoville, Butte County, ID
NASA Astrophysics Data System (ADS)
Bouaziz, Laurène; Hegnauer, Mark; Schellekens, Jaap; Sperna Weiland, Frederiek; ten Velden, Corine
2017-04-01
In many countries, data is scarce, incomplete and often not easily shared. In these cases, global satellite and reanalysis data provide an alternative to assess water resources. To assess water resources in Azerbaijan, a completely distributed and physically based hydrological wflow-sbm model was set-up for the entire Kura basin. We used SRTM elevation data, a locally available river map and one from OpenStreetMap to derive the drainage direction network at the model resolution of approximately 1x1 km. OpenStreetMap data was also used to derive the fraction of paved area per cell to account for the reduced infiltration capacity (c.f. Schellekens et al. 2014). We used the results of a global study to derive root zone capacity based on climate data (Wang-Erlandsson et al., 2016). To account for the variation in vegetation cover over the year, monthly averages of Leaf Area Index, based on MODIS data, were used. For the soil-related parameters, we used global estimates as provided by Dai et al. (2013). This enabled the rapid derivation of a first estimate of parameter values for our hydrological model. Digitized local meteorological observations were scarce and available only for limited time period. Therefore several sources of global meteorological data were evaluated: (1) EU-WATCH global precipitation, temperature and derived potential evaporation for the period 1958-2001 (Harding et al., 2011), (2) WFDEI precipitation, temperature and derived potential evaporation for the period 1979-2014 (by Weedon et al., 2014), (3) MSWEP precipitation (Beck et al., 2016) and (4) local precipitation data from more than 200 stations in the Kura basin were available from the NOAA website for a period up to 1991. The latter, together with data archives from Azerbaijan, were used as a benchmark to evaluate the global precipitation datasets for the overlapping period 1958-1991. By comparing the datasets, we found that monthly mean precipitation of EU-WATCH and WFDEI coincided well with NOAA stations and that MSWEP slightly overestimated precipitation amounts. On a daily basis, there were discrepancies in the peak timing and magnitude between measured precipitation and the global products. A bias between EU-WATCH and WFDEI temperature and potential evaporation was observed and to model the water balance correctly, it was needed to correct EU-WATCH to WFDEI mean monthly values. Overall, the available sources enabled rapid set-up of a hydrological model including the forcing of the model with a relatively good performance to assess water resources in Azerbaijan with a limited calibration effort and allow for a similar set-up anywhere in the world. Timing and quantification of peak volume remains a weakness in global data, making it difficult to be used for some applications (flooding) and for detailed calibration. Selecting and comparing different sources of global meteorological data is important to have a reliable set which improves model performance. - Beck et al., 2016. MSWEP: 3-hourly 0.25° global gridded precipitation (1979-2014) by merging gauge, satellite, and reanalysis data. Hydrol. Earth Syst. Sci. Discuss. - Dai Y. et al. ,2013. Development of a China Dataset of Soil Hydraulic Parameters Using Pedotransfer Functions for Land Surface Modeling. Journal of Hydrometeorology - Harding, R. et al., 2011., WATCH: Current knowledge of the Terrestrial global water cycle, J. Hydrometeorol. - Schellekens, J. et al., 2014. Rapid setup of hydrological and hydraulic models using OpenStreetMap and the SRTM derived digital elevation model. Environmental Modelling&Software - Wang-Erlandsson L. et al., 2016. Global Root Zone Storage Capacity from Satellite-Based Evaporation. Hydrology and Earth System Sciences - Weedon, G. et al., 2014. The WFDEI meteorological forcing data set: WATCH Forcing Data methodology applied to ERA-Interim reanalysis data, Water Resources Research.
Influence of Different Aluminum Sources on the NH3 Gas-Sensing Properties of ZnO Thin Films
NASA Astrophysics Data System (ADS)
Ozutok, Fatma; Karaduman, Irmak; Demiri, Sani; Acar, Selim
2018-02-01
Herein we report Al-doped ZnO films (AZO) deposited on the ZnO seed layer by chemical bath deposition method. Al powder, Al oxide and Al chloride were used as sources for the deposition process and investigated for their different effects on the NH3 gas-sensing performance. The morphological and microstructural properties were investigated by employing x-ray powder diffraction, scanning electron microscopy analysis and energy-dispersive x-ray spectroscopy. The characterization studies showed that the AZO thin films are crystalline and exhibit a hexagonal wurtzite structure. Ammonia (NH3) gas-sensing measurements of AZO films were performed at different concentration levels and different operation temperatures from 50°C to 210°C. The sample based on powder-Al source showed a higher response, selectivity and short response/recovery time than the remaining samples. The powder Al sample exhibited 33% response to 10-ppm ammonia gas at 190°C, confirming a strong dependence on the dopant source type.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Byrd, J.M.; Hao, Z.; Martin, M.C.
2004-07-01
Interaction of an electron beam with a femtosecond laser pulse co-propagating through a wiggler at the ALS produces large modulation of the electron energies within a short {approx}100 fs slice of the electron bunch. Propagating around the storage ring, this bunch develops a longitudinal density perturbation due to the dispersion of electron trajectories. The length of the perturbation evolves with a distance from the wiggler but is much shorter than the electron bunch length. This perturbation causes the electron bunch to emit short pulses of temporally and spatially coherent infrared light which are automatically synchronized to the modulating laser. Themore » intensity and spectra of the infrared light were measured in two storage ring locations for a nominal ALS lattice and for an experimental lattice with the higher momentum compaction factor. The onset of instability stimulated by laser e-beam interaction had been discovered. The infrared signal is now routinely used as a sensitive monitor for a fine tuning of the laser beam alignment during data accumulation in the experiments with femtosecond x-ray pulses.« less
Evaluation of Domain-Specific Collaboration Interfaces for Team Command and Control Tasks
2012-05-01
Technologies 1.1.1. Virtual Whiteboard Cognitive theories relating the utilization, storage, and retrieval of verbal and spatial information, such as...AE Spatial emergent SE Auditory linguistic AL Spatial positional SP Facial figural FF Spatial quantitative SQ Facial motive FM Tactile figural...driven by the auditory linguistic (AL), short-term memory (STM), spatial attentive (SA), visual temporal (VT), and vocal process (V) subscales. 0
70. INTERIOR VIEW OF AMMONIUM NITRATE HOUSE, LOOKING AT AMMONIUM ...
70. INTERIOR VIEW OF AMMONIUM NITRATE HOUSE, LOOKING AT AMMONIUM NITRATE IN STORAGE. APRIL 18, 1919. - United States Nitrate Plant No. 2, Reservation Road, Muscle Shoals, Muscle Shoals, Colbert County, AL
The interaction of NO2 with BaO: from cooperative adsorption to Ba(NO3)2 formation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yi, Cheol-Woo W.; Kwak, Ja Hun; Szanyi, Janos
2007-10-25
The effect of water on the morphology of BaO/Al2O3-based NOx storage materials was investigated using Fourier transform infrared spectroscopy, temperature programmed desorption, and time-resolved synchrotron X-ray diffraction techniques. The results of this multi-spectroscopy study reveal that, in the presence of water, surface Ba-nitrates convert to bulk nitrates, and water facilitates the formation of large Ba(NO3)2 particles. The conversion of surface to bulk Ba-nitrates is completely reversible, i.e. after the removal of water from the storage material a significant fraction of the bulk nitrates re-convert to surface nitrates. NO2 exposure of a H2O-containing (wet) BaO/Al2O3 sample results in the formation ofmore » nitrites and bulk nitrates exclusively, i.e. no surface nitrates form. After further exposure to NO2, the nitrites completely convert to bulk nitrates. The amount of NOx taken up by the storage material is, however, essentially unaffected by the presence of water, regardless of whether the water was dosed prior to or after NO2 exposure. Based on the results of this study we are now able to explain most of the observations reported in the literature on the effect of water on NOx uptake on similar storage materials.« less
Brooks, Kriston P.; Sprik, Samuel J.; Tamburello, David A.; ...
2018-04-07
The U.S. Department of Energy (DOE) developed a vehicle Framework model to simulate fuel cell-based light-duty vehicle operation for various hydrogen storage systems. This transient model simulates the performance of the storage system, fuel cell, and vehicle for comparison to Technical Targets established by DOE for four drive cycles/profiles. Chemical hydrogen storage models have been developed for the Framework for both exothermic and endothermic materials. Despite the utility of such models, they require that material researchers input system design specifications that cannot be estimated easily. To address this challenge, a design tool has been developed that allows researchers to directlymore » enter kinetic and thermodynamic chemical hydrogen storage material properties into a simple sizing module that then estimates system parameters required to run the storage system model. Additionally, the design tool can be used as a standalone executable file to estimate the storage system mass and volume outside of the Framework model. Here, these models will be explained and exercised with the representative hydrogen storage materials exothermic ammonia borane (NH 3BH 3) and endothermic alane (AlH 3).« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Brooks, Kriston P.; Sprik, Samuel J.; Tamburello, David A.
The U.S. Department of Energy (DOE) developed a vehicle Framework model to simulate fuel cell-based light-duty vehicle operation for various hydrogen storage systems. This transient model simulates the performance of the storage system, fuel cell, and vehicle for comparison to Technical Targets established by DOE for four drive cycles/profiles. Chemical hydrogen storage models have been developed for the Framework for both exothermic and endothermic materials. Despite the utility of such models, they require that material researchers input system design specifications that cannot be estimated easily. To address this challenge, a design tool has been developed that allows researchers to directlymore » enter kinetic and thermodynamic chemical hydrogen storage material properties into a simple sizing module that then estimates system parameters required to run the storage system model. Additionally, the design tool can be used as a standalone executable file to estimate the storage system mass and volume outside of the Framework model. Here, these models will be explained and exercised with the representative hydrogen storage materials exothermic ammonia borane (NH 3BH 3) and endothermic alane (AlH 3).« less
ERIC Educational Resources Information Center
Huang, Ying; Huang, Qiang; Chen, Xun; Wu, Xihong; Li, Liang
2009-01-01
Perceptual integration of the sound directly emanating from the source with reflections needs both temporal storage and correlation computation of acoustic details. We examined whether the temporal storage is frequency dependent and associated with speech unmasking. In Experiment 1, a break in correlation (BIC) between interaurally correlated…
Harvest impacts on soil carbon storage in temperate forests
L.E. Nave; E.D. Vance; C.W. Swanston; P.S. Curtis
2010-01-01
Forest soil carbon (C) storage is a significant component of the global C cycle, and is important for sustaining forest productivity. Although forest management may have substantial impacts on soil C storage, experimental data from forest harvesting studies have not been synthesized recently. To quantify the effects of harvesting on soil C, and to identify sources of...
Hildebrand, Richard J.; Wozniak, John J.
2001-01-01
A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.
CHEMICAL STORAGE: MYTHS VERSUS REALITY
DOE Office of Scientific and Technical Information (OSTI.GOV)
Simmons, F
A large number of resources explaining proper chemical storage are available. These resources include books, databases/tables, and articles that explain various aspects of chemical storage including compatible chemical storage, signage, and regulatory requirements. Another source is the chemical manufacturer or distributor who provides storage information in the form of icons or color coding schemes on container labels. Despite the availability of these resources, chemical accidents stemming from improper storage, according to recent reports (1) (2), make up almost 25% of all chemical accidents. This relatively high percentage of chemical storage accidents suggests that these publications and color coding schemes althoughmore » helpful, still provide incomplete information that may not completely mitigate storage risks. This manuscript will explore some ways published storage information may be incomplete, examine the associated risks, and suggest methods to help further eliminate chemical storage risks.« less
The periodic very young source EC 53 reached its maximum brightness
NASA Astrophysics Data System (ADS)
Giannini, T.; Antoniucci, S.; Lorenzetti, D.; Harutyunyan, A.; Licchelli, D.; Munari, U.
2018-06-01
In the framework of our EXor monitoring program dubbed EXORCISM (EXOR OptiCal and Infrared Systematic Monitoring - Antoniucci et al. 2013 PPVI, Lorenzetti et al. 2007 ApJ 665, 1182; Lorenzetti et al. 2009 ApJ 693, 1056), we observed the object EC53 recently signaled by Johnston et al. (ATel #11614) as a strongly embedded source showing a sub-mm luminosity burst, They also provide H- and K-band observations detecting this brightness increase also in the near-IR, in the scattered light by the nebula surrounding a compact source, invisible at those wavelengths.
Organic carbon storage and benthic consumption in sediments of northern fjords (60-80°N)
NASA Astrophysics Data System (ADS)
Włodarska-Kowalczuk, Maria; Zaborska, Agata; Jankowska, Emilia; Mazurkiewicz, Mikołaj
2017-04-01
Fjords have been recently recognized as hotspots of organic carbon storage, with organic carbon burial rates one hundred times larger than the global ocean average, accounting for 11% of global annual marine carbon burial (Smith et al. (2015) Nature Geoscience 8: 450-453). The organic carbon production and processing in coastal waters and sediments are controlled by environmental settings that are likely to be reshaped in the course of the global warming. The fastest and strongest changes are to occur in polar regions. In the present study we compare organic carbon stocks, accumulation and burial in temperate (Raunefjorden, Ullsfjorden, Balsfjorden) and Arctic (Hornsund, Kongsfjorden, Rijpfjorden) fjords located along the latitudinal/thermal gradient from the southern Norway (60 °N) to North of Svalbard (80 °N). The sediment cores were collected at 3 to 5 stations within the central basin at 150-300 m in each fjord during r/v Helmer Hansen and r/v Oceania cruises in 2014 and 2015. Vertical patterns of grain size and organic matter content and sources (Corg concentration, stable isotope δ13C signature, photosynthetic pigments concentration) have been analyzed. Sediment accumulation rates have been estimated with use of 210Pb dating method. Fresh carbon accumulation rate was estimated based on organic carbon concentration is surface sediments and mass sediment accumulation rate. The variability in metazoan productivity and carbon consumption (calculated based on the macro- and meiobenthic species biomass spectra in samples collected at the same stations) was also assessed to explore the patterns of biological controls of carbon storage in sediments. Carbon burial was estimated by multiplying organic carbon concentration in deepest sampled sediments and mass sediment accumulation rate. The effects of contrasting hydrological regimes and biological activity on the carbon storage in the studied fjords are discussed from the perspective of possible effects of climate warming driven changes on the Arctic fjordic sedimentary systems.
NASA Astrophysics Data System (ADS)
Kühn, Michael; Streibel, Martin; Nakaten, Natalie; Kempka, Thomas
2014-05-01
Massive roll-out of renewable energy production units (wind turbines and solar panels) leads to date to excess energy which cannot be consumed at the time of production. So far, long-term storage is proposed via the so called 'power-to-gas' technology. Energy is transferred to methane gas and subsequently combusted for power production - 'power-to-gas-to-power' (PGP) - when needed. PGP profits from the existing infrastructure of the gas market and could be deployed immediately. However, major shortcoming is the production of carbon dioxide (CO2) from renewables and its emission into the atmosphere. We present an innovative idea which is a decarbonised extension of the PGP technology. The concept is based on a closed carbon cycle: (1) Hydrogen (H2) is generated from renewable energy by electrolysis and (2) transformed into methane (CH4) with CO2 taken from an underground geological storage. (3) CH4 produced is stored in a second storage underground until needed and (4) combusted in a combined-cycled power plant on site. (5) CO2 is separated during energy production and re-injected into the storage formation. We studied a show case for the cities Potsdam and Brandenburg/Havel in the Federal State of Brandenburg in Germany to determine the energy demand of the entire process chain and the costs of electricity (COE) using an integrated techno-economic modelling approach (Nakaten et al. 2014). Taking all of the individual process steps into account, the calculation shows an overall efficiency of 27.7 % (Streibel et al. 2013) with total COE of 20.43 euro-cents/kWh (Kühn et al. 2013). Although the level of efficiency is lower than for pump and compressed air storage, the resulting costs are similar in magnitude, and thus competitive on the energy storage market. The great advantage of the concept proposed here is that, in contrast to previous PGP approaches, this process is climate-neutral due to CO2 utilisation. For that purpose, process CO2 is temporally stored in an underground reservoir. If existing locations in Europe, where natural gas storage in porous formations is performed, were to be extended by CO2 storage sites, a significant quantity of wind and solar energy produced could be stored as methane. The overall process chain is in this case carbon neutral. Kühn M., Nakaten N., Streibel M., Kempka T. (2013) Klimaneutrale Flexibilisierung regenerativer Überschussenergie mit Untergrundspeichern. ERDÖL ERDGAS KOHLE 129(10), 348-352. Nakaten, N., Schlüter, R., Azzam, R., Kempka, T. (2014) Development of a techno-economic model for dynamic calculation of COE, energy demand and CO2 emissions of an integrated UCG-CCS process, Energy (in press). doi: 10.1016/j.energy.2014.01.014 Streibel M., Nakaten N., Kempka T., Kühn M. (2013) Analysis of an integrated carbon cycle for storage of renewables. Energy Procedia 40, 202-211. doi: 10.1016/j.egypro.2013.08.024.
NASA Technical Reports Server (NTRS)
Nola, F. J.
1985-01-01
Energy-storage system has 20 year lifetime. Electrical power source consisting of flywheel and electronic control system stores solar energy. Flywheel developed for space vehicles features good weight-to-energy storage ratios and used as control gyroscope for maneuvering.
DOE Office of Scientific and Technical Information (OSTI.GOV)
LaFreniere, L. M.; Environmental Science Division
In 1997, low levels of carbon tetrachloride (below the maximum contaminant level [MCL] of 5 {micro}g/L) were detected in groundwater at Inman, Kansas, by the Kansas Department of Health and Environment (KDHE). The 1997 KDHE sampling was conducted under the U.S. Department of Agriculture (USDA) private well sampling program. The Commodity Credit Corporation (CCC), a USDA agency, operated a grain storage facility in Inman from 1954 to 1965. Carbon tetrachloride is the contaminant of primary concern at sites associated with former CCC/USDA grain storage operations. Inman is located in southwest McPherson County, approximately 10 mi southwest of the city ofmore » McPherson (Figure 1.1). To determine whether the former CCC/USDA facility at Inman is a potential contaminant source and its possible relationship to the contamination in groundwater, the CCC/USDA has agreed to conduct an investigation at Inman, in accordance with the Intergovernmental Agreement between the KDHE and the Farm Service Agency of the USDA. For this work plan, Argonne compiled historical data related to the previous investigations and grain storage operations at Inman. Through a review of documents acquired from all available sources, other potential contaminant source areas (in addition to the former CCC/USDA facility) have been identified as (1) the commercial grain storage structures northwest of Inman, along the railroad right-of-way, and (2) small former private grain storage facilities west of Main Street and near the former CCC/USDA facility at the southern edge of Inman (Figure 1.2). Previous investigations and the potential source areas are discussed in Section 2.« less
NSLS-II storage ring insertion device and front-end commissioning and operation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, G., E-mail: gwang@bnl.gov; Shaftan, T.; Amundsen, C.
The National Synchrotron Light Source II (NSLS-II) is a state of the art 3 GeV third generation light source at Brookhaven National Laboratory. During spring/ summer of 2014, the storage ring was commissioned up to 50 mA without insertion devices. In the fall of 2014, we began commissioning of the project beamlines, which included seven insertion devices on six ID ports. Beamlines IXS, HXN, CSX-1, CSX-2, CHX, SRX, and XPD-1 consist of elliptically polarized undulator (EPU), damping wigglers (DW) and in-vacuum undulators (IVU) covering from VUV to hard x-ray range. In this paper, experience with commissioning and operation is discussed.more » We focus on reaching storage ring performance with IDs, including injection, design emittance, compensation of orbit distortions caused by ID residual field, source point stability, beam alignment and tools for control, monitoring and protection of the ring chambers from ID radiation.« less
A compact radiation source for digital subtractive angiography
NASA Astrophysics Data System (ADS)
Wiedemann, H.; Baltay, M.; Carr, R.; Hernandez, M.; Lavender, W.
1994-08-01
Beam requirements for 33 keV radiation used in digital subtraction angiography have been established through extended experimentation first at Stanford and later at the National Synchrotron Light Source in Brookhaven. So far research and development of this medical procedure to image coronary blood vessels have been undertaken on large high energy electron storage rings. With progress in this diagnostic procedure, it is interesting to look for an optimum concept for providing a 33 keV radiation source which would fit into the environment of a hospital. A variety of competing effects and technologies to produce 33 keV radiation are available, but none of these processes provides the combination of sufficient photon flux and monochromaticity except for synchrotron radiation from an electron storage ring. The conceptual design of a compact storage ring optimized to fit into a hospital environment and producing sufficient 33 keV radiation for digital subtraction radiography will be discussed.
Apparatus for safeguarding a radiological source
Bzorgi, Fariborz M
2014-10-07
A tamper detector is provided for safeguarding a radiological source that is moved into and out of a storage location through an access porthole for storage and use. The radiological source is presumed to have an associated shipping container approved by the U.S. Nuclear Regulatory Commission for transporting the radiological source. The tamper detector typically includes a network of sealed tubing that spans at least a portion of the access porthole. There is an opening in the network of sealed tubing that is large enough for passage therethrough of the radiological source and small enough to prevent passage therethrough of the associated shipping cask. Generally a gas source connector is provided for establishing a gas pressure in the network of sealed tubing, and a pressure drop sensor is provided for detecting a drop in the gas pressure below a preset value.
Design of a setup for 252Cf neutron source for storage and analysis purpose
NASA Astrophysics Data System (ADS)
Hei, Daqian; Zhuang, Haocheng; Jia, Wenbao; Cheng, Can; Jiang, Zhou; Wang, Hongtao; Chen, Da
2016-11-01
252Cf is a reliable isotopic neutron source and widely used in the prompt gamma ray neutron activation analysis (PGNAA) technique. A cylindrical barrel made by polymethyl methacrylate contained with the boric acid solution was designed for storage and application of a 5 μg 252Cf neutron source. The size of the setup was optimized with Monte Carlo code. The experiments were performed and the results showed the doses were reduced with the setup and less than the allowable limit. The intensity and collimating radius of the neutron beam could also be adjusted through different collimator.
Da Silva, David; Qin, Liangchun; DeBuse, Carolyn; DeJong, Theodore M.
2014-01-01
Background and Aims Developing a conceptual and functional framework for simulating annual long-term carbohydrate storage and mobilization in trees has been a weak point for virtually all tree models. This paper provides a novel approach for solving this problem using empirical field data and details of structural components of simulated trees to estimate the total carbohydrate stored over a dormant season and available for mobilization during spring budbreak. Methods The seasonal patterns of mobilization and storage of non-structural carbohydrates in bark and wood of the scion and rootstock crowns of the trunks of peach (Prunus persica) trees were analysed subsequent to treatments designed to maximize differences in source–sink behaviour during the growing season. Mature peach trees received one of three treatments (defruited and no pruning, severe pruning to 1·0 m, and unthinned with no pruning) in late winter, just prior to budbreak. Selected trees of each treatment were harvested at four times (March, June, August and November) and slices of trunk and root crown tissue above and below the graft union were removed for carbohydrate analysis. Inner bark and xylem tissues from the first to fifth rings were separated and analysed for non-structural carbohydrates. Data from these experiments were then used to estimate the amount of non-structural carbohydrates available for mobilization and to parameterize a carbohydrate storage sub-model in the functional–structural L-PEACH model. Key Results The mass fraction of carbohydrates in all sample tissues decreased from March to June, but the decrease was greatest in the severely pruned and unthinned treatments. November carbohydrate mass fractions in all tissues recovered to values similar to those in the previous March, except in the older xylem rings of the severely pruned and unthinned treatment. Carbohydrate storage sink capacity in trunks was empirically estimated from the mean maximum measured trunk non-structural carbohydrate mass fractions. The carbohydrate storage source available for mobilization was estimated from these maximum mass fractions and the early summer minimum mass fractions remaining in these tissues in the severe treatments that maximized mobilization of stored carbohydrates. The L-PEACH sink–source carbohydrate distribution framework was then used along with simulated tree structure to successfully simulate annual carbohydrate storage sink and source behaviour over years. Conclusions The sink–source concept of carbohydrate distribution within a tree was extended to include winter carbohydrate storage and spring mobilization by considering the storage sink and source as a function of the collective capacity of active xylem and phloem tissue of the tree, and its annual behaviour was effectively simulated using the L-PEACH functional–structural plant model. PMID:24674986
67. INTERIOR VIEW OF THE NEUTRALIZER BUILDING, LOOKING AT CONDENSERS, ...
67. INTERIOR VIEW OF THE NEUTRALIZER BUILDING, LOOKING AT CONDENSERS, NEUTRALIZERS AND STORAGE TANKS, APRIL 11, 1919. - United States Nitrate Plant No. 2, Reservation Road, Muscle Shoals, Muscle Shoals, Colbert County, AL
Meteorite Source Regions as Revealed by the Near-Earth Object Population
NASA Astrophysics Data System (ADS)
Binzel, Richard P.; DeMeo, Francesca E.; Burt, Brian J.; Polishook, David; Burbine, Thomas H.; Bus, Schelte J.; Tokunaga, Alan; Birlan, Mirel
2014-11-01
Spectroscopic and taxonomic information is now available for 1000 near-Earth objects, having been obtained through both targeted surveys (e.g. [1], [2], [3]) or resulting from all-sky surveys (e.g. [4]). We determine their taxonomic types in the Bus-DeMeo system [5] [6] and subsequently examine meteorite correlations based on spectral analysis (e.g. [7],[8]). We correlate our spectral findings with the source region probabilities calculated using the methods of Bottke et al. [9]. In terms of taxonomy, very clear sources are indicated: Q-, Sq-, and S-types most strongly associated with ordinary chondrite meteorites show clear source signatures through the inner main-belt. V-types are relatively equally balanced between nu6 and 3:1 resonance sources, consistent with the orbital dispersion of the Vesta family. B- and C-types show distinct source region preferences for the outer belt and for Jupiter family comets. A Jupiter family comet source predominates for the D-type near-Earth objects, implying these "asteroidal" bodies may be extinct or dormant comets [10]. Similarly, near-Earth objects falling in the spectrally featureless "X-type" category also show a strong outer belt and Jupiter family comet source region preference. Finally the Xe-class near-Earth objects, which most closely match the spectral properties of enstatite achondrite (aubrite) meteorites seen in the Hungaria region[11], show a source region preference consistent with a Hungaria origin by entering near-Earth space through the Mars crossing and nu6 resonance pathways. This work supported by the National Science Foundation Grant 0907766 and NASA Grant NNX10AG27G.[1] Lazzarin, M. et al. (2004), Mem. S. A. It. Suppl. 5, 21. [2] Thomas, C. A. et al. (2014), Icarus 228, 217. [3] Tokunaga, A. et al. (2006) BAAS 38, 59.07. [4] Hasselmann, P. H., Carvano, J. M., Lazzaro, D. (2011) NASA PDS, EAR-A-I0035-5-SDSSTAX-V1.0. [5] Bus, S.J., Binzel, R.P. (2002). Icarus 158, 146. [6] DeMeo, F.E. et al. (2009), Icarus 202, 160. [7] Dunn et al. (2010) Icarus 208, 789. [8] Dunn et al. (2013) Icarus 222, 273. [9] Bottke, W.F. et al. (2002), Icarus 156, 399. [10] DeMeo, F., Binzel, R. P. (2007) Icarus 194, 436. [11] Gaffey, M. J. et al. (1992) Icarus 100, 95.
Galvanic high energy cells with molten salt electrolytes
NASA Astrophysics Data System (ADS)
Borger, W.; Kappus, W.; Kunze, D.; Laig-Hoerstebrock, H.; Panesar, H.; Sterr, G.
1981-02-01
Engineering scale LiAl/LiCl Kcl/FeS electrochemical storage cells were developed for electric vehicle propulsion and peak current compensation. More than 300 deep cycles and 50 Whr/kg in 100 Ahr cells and up to 100 deep cycles and more than 80 Whr/kg in 200 Ahr cells were demonstrated. Separator development for LiAl/FeS cells was focused on ceramic powders. The aluminum nitride powder separator is promising for LiAl/FeS cells. The further development of these cells includes the enhancement of energy density and lifetime as well as ceramic powder separators.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Thomas, G.J.; Guthrie, S.E.
1998-08-01
A summary of the hydride development efforts for the current program year (FY98) are presented here. The Mg-Al-Zn alloy system was studied at low Zn levels (2--4 wt%) and midrange Al contents (40--60 wt%). Higher plateau pressures were found with Al and Zn alloying in Mg and, furthermore, it was found that the hydrogen desorption kinetics were significantly improved with small additions of Zn. Results are also shown here for a detailed study of the low temperature properties of Mg{sub 2}NiH{sub 4}, and a comparison made between conventional melt cast alloy and the vapor process material.
Comparative Proteomic Analysis of Aluminum Tolerance in Tibetan Wild and Cultivated Barleys
Dai, Huaxin; Cao, Fangbin; Chen, Xianhong; Zhang, Mian; Ahmed, Imrul Mosaddek; Chen, Zhong-Hua; Li, Chengdao; Zhang, Guoping; Wu, Feibo
2013-01-01
Aluminum (Al) toxicity is a major limiting factor for plant production in acid soils. Wild barley germplasm is rich in genetic diversity and may provide elite genes for crop Al tolerance improvement. The hydroponic-experiments were performed to compare proteomic and transcriptional characteristics of two contrasting Tibetan wild barley genotypes Al- resistant/tolerant XZ16 and Al-sensitive XZ61 as well as Al-resistant cv. Dayton. Results showed that XZ16 had less Al uptake and translocation than XZ61 and Dayton under Al stress. Thirty-five Al-tolerance/resistance-associated proteins were identified and categorized mainly in metabolism, energy, cell growth/division, protein biosynthesis, protein destination/storage, transporter, signal transduction, disease/defense, etc. Among them, 30 were mapped on barley genome, with 16 proteins being exclusively up-regulated by Al stress in XZ16, including 4 proteins (S-adenosylmethionine-synthase 3, ATP synthase beta subunit, triosephosphate isomerase, Bp2A) specifically expressed in XZ16 but not Dayton. The findings highlighted the significance of specific-proteins associated with Al tolerance, and verified Tibetan wild barley as a novel genetic resource for Al tolerance. PMID:23691047
Safety and security of radioactive sources in industrial radiography in Bangladesh
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mollah, A. S.; Nazrul, M. Abdullah
2013-07-01
Malicious use of radioactive sources can involve dispersal of that material through an explosive device. There has been recognition of the threat posed by the potential malicious misuse of NDT radioactive source by terrorists. The dispersal of radioactive material using conventional explosives, referred to as a 'dirty bomb', could create considerable panic, disruption and area access denial in an urban environment. However, as it is still a relatively new topic among regulators, users, and transport and storage operators worldwide, international assistance and cooperation in developing the necessary regulatory and security infrastructure is required. The most important action in reducing themore » risk of radiological terrorism is to increase the security of radioactive sources. This paper presents safety and security considerations for the transport and site storage of the industrial radiography sources as per national regulations entitled 'Nuclear Safety and Radiation Control Rules-1997'.The main emphasis was put on the stages of some safety and security actions in order to prevent theft, sabotage or other malicious acts during the transport of the packages. As a conclusion it must be mentioned that both safety and security considerations are very important aspects that must be taking in account for the transport and site storage of radioactive sources used in the practice of industrial radiography. (authors)« less
National Synchrotron Light Source annual report 1991
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hulbert, S.L.; Lazarz, N.M.
1992-04-01
This report discusses the following research conducted at NSLS: atomic and molecular science; energy dispersive diffraction; lithography, microscopy and tomography; nuclear physics; UV photoemission and surface science; x-ray absorption spectroscopy; x-ray scattering and crystallography; x-ray topography; workshop on surface structure; workshop on electronic and chemical phenomena at surfaces; workshop on imaging; UV FEL machine reviews; VUV machine operations; VUV beamline operations; VUV storage ring parameters; x-ray machine operations; x-ray beamline operations; x-ray storage ring parameters; superconducting x-ray lithography source; SXLS storage ring parameters; the accelerator test facility; proposed UV-FEL user facility at the NSLS; global orbit feedback systems; and NSLSmore » computer system.« less
2012-01-01
example, probiotics (Kailasapathy, 2002; Rokka and Rantamäki, 2010), folic acid (Madziva et al., 2006) and ascorbic acid (Wijaya et al., 2011...Kailasapathy, K. 2002. Microencapsulation of Probiotic Bacteria: Technology and Potential Applications. Current Issues in Intestinal Microbiology, 3: 39-48...Re´, M. I. 1998. Microencapsulation by spray drying. Drying Technology, 16:1195–1236. Rokka, S., and Rantamäki, P. 2010. Protecting probiotic
Finding X-ray counterparts for unidentified sources in the 105 months BAT survey - 1
NASA Astrophysics Data System (ADS)
Stephen, J. B.; Bassani, L.; Malizia, A.; Masetti, N.; Ubertini, P.
2018-02-01
We provide X-ray counterparts for the unidentified Swift/BAT sources listed in the 105 month catalogue (Oh et al. 2018, ApJS in press). These associations were found by cross-correlating the list of U1,U2 and U3 sources with the ROSAT Bright (RASSBSC, Voges et al. 1999, A & A, 349, 389) and the XMM-Newton Slew (XMMSlew, Saxton et al. 2008, A & A, 480, 611) catalogues.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Narlesky, Joshua E; Padilla, Dennis D; Watts, Joe
2009-01-01
Throughout the 1960s and 1970s, the former Soviet Union produced and exported Plutonium-Beryllium (PuBe) neutron sources to various Eastern European countries. The Russian sources consist of an intermetallic compound of plutonium and beryllium encapsulated in an inner welded, sealed capsule and consisting of a body and one or more covers. The amount of plutonium in the sources ranges from 0.002 g up to 15 g. A portion of the sources was originally exported to East Germany. A portion of these sources were acquired by Los Alamos National Laboratory (LANL) in the late 1990s for destruction in the Offsite Source Recoverymore » Program. When the OSRP was canceled, the remaining 88 PuBe neutron sources were packaged and stored in a 55-gal drum at T A-55. This storage configuration is no longer acceptable for PuBe sources, and the sources must either be repackaged or disposed of. Repackaging would place the sources into Hagan container, and depending on the dose rates, some sources may be packaged individually increasing the footprint and cost of storage. In addition, each source will be subject to leak-checking every six months. Leaks have already been detected in some of the sources, and due to the age of these sources, it is likely that additional leaks may be detected over time, which will increase the overall complexity of handling and storage. Therefore, it was decided that the sources would be disposed of at the Waste Isolation Pilot Plant (WIPP) due to the cost and labor associated with continued storage at TA-55. However, the plutonium in the sources is of Russian origin and needs to be preserved for research purposes. Therefore, it is important that a representative sample of the sources retained and archived for future studies. This report describes the criteria used to obtain a representative sample of the sources. Nine Russian PuBe neutron sources have been selected out of a collection of 77 sources for inclusion in the NMIP archive. Selection criteria were developed so that the largest sources that are representative of the collection are included. One representative source was chosen for every 20 sources in the collection, and effort was made to preserve sources unique to the collection. In total, four representative sources and five unique sources were selected for the archive. The archive samples contain 40 grams of plutonium with an isotopic composition similar to that of weapon grade material and three grams of plutonium with an isotopic composition similar to that of reactor grade plutonium.« less
VizieR Online Data Catalog: Catalog of 316 K giant candidates (Rebull+, 2015)
NASA Astrophysics Data System (ADS)
Rebull, L. M.; Carlberg, J. K.; Gibbs, J. C.; Deeb, J. E.; Larsen, E.; Black, D. V.; Altepeter, S.; Bucksbee, E.; Cashen, S.; Clarke, M.; Datta, A.; Hodgson, E.; Lince, M.
2015-11-01
There are 82 targets published in de la Reza et al. (1997ApJ...482L..77D). There are 86 K giants reported in Carlberg et al. 2012 (cat. J/ApJ/757/109). We compiled 149 additional targets that have been identified either consistently or at one time as confirmed or possible Li-rich K giants, but not included in either the de la Reza et al. (1997ApJ...482L..77D) or the Carlberg et al. 2012 (cat. J/ApJ/757/109) samples. They include targets from Adamow et al. 2014 (cat. J/A+A/569/A55), Anthony-Twarog et al. (2013ApJ...767L..19A), Carney et al. (1998AJ....116.2984C), Carlberg et al. (2015ApJ...802....7C), Castilho et al. 2000 (cat. J/A+A/364/674), Drake et al. (2002AJ....123.2703D), Fekel & Watson (1998AJ....116.2466F), Hill & Pasquini (1999A&A...348L..21H), Jasniewicz et al. (1999A&A...342..831J), Kirby et al. (2012ApJ...752L..16K), Kraft et al. (1999ApJ...518L..53K), Kumar et al. (2011ApJ...730L..12K) and references therein, Liu et al. (2014ApJ...785...94L), Luck & Heiter 2007 (cat. J/AJ/133/2464), Martell & Shetrone (2013MNRAS.430..611M), Monaco et al. (2014A&A...564L...6M), Pilachowski et al. (2003AJ....125..794P), Ruchti et al. (2011ApJ...743..107R), Silva Aguirre et al. (2014ApJ...784L..16A), Smith et al. (1999ApJ...516L..73S), and Torres et al. (2000IAUS..198..320T). Our complete list of 316 targets with position, photometric, and abundance data appears in Table1. We obtained positions for these targets, most of which are quite bright in the optical, primarily from SIMBAD, though literature was consulted for fainter sources as required. Detailed notes on the sources we suspect are subject to source confusion appear in Table4. Table6 contains notes on the entire set of sources. (3 data files).
Wilson, Colin J N; Morgan, Daniel J; Charlier, Bruce L A; Barker, Simon J
2017-12-22
Rubin et al (Reports, 16 June 2017, p. 1154) proposed that gradients in lithium abundance in zircons from a rhyolitic eruption in New Zealand reflected short-lived residence at magmatic temperatures interleaved with long-term "cold" (<650°C) storage. Important issues arise with the interpretation of these lithium gradients and consequent crystal thermal histories that raise concerns about the validity of this conclusion. Copyright © 2017, American Association for the Advancement of Science.
Modeling and Optimizing Green Microgrids at Remote U.S. Navy Islands
2017-12-01
storage, and controls. All of these components work together as a system solution to serve a nearby load, such as a wind turbine and a storage battery...includes five diesel generators of varying capacities and seven 100kW wind turbines . The diesel genset specifics are shown in Table 1. They typically...run at only 30% of nominal capacity, while they are most efficient at 70% (Anderson et al. 2017). The wind turbines are all Northwind 100 kW models
1986-01-01
7 O-AI6 175 TWO- 1NENSION L SIGNAL PROCESSING AD STORAGE AND IA-1 ATLANTA SCHOOL OF ELECTRICAL ENGINEERING.. ULRSSIFIED R SCHAFER ET AL. SI JAN... ELECTRICAL ENGINEERING L’- ATLANTA, GEORGIA 30332 .’ -.. .. ~ i 4 2 i 2 " , I IT= J ., . 4 2.~ i1 ov--.,-w. A -A *- t . . . SECURITY CLASSIFICATION O0...School of Electrical Engineering Atlanta, Georgia 30332 Research Triangle Park, NC 27709 •e. NAME OP PUNOINGMSONSORING 0b. OPPIC SYMBOL L PROCUREMENT
Infrared Dyes For Optical Storage
NASA Astrophysics Data System (ADS)
Jipson, V. B.; Jones, C. R.
1981-06-01
There is current interest in developing optical storage materials that can be written with GaAlAs lasers. Dyes which absorb strongly at those wavelengths are potential candidates for this application due to their attractive thermal properties. Through optical and thermal modelling, the properties that are necessary if they are to be writeable at energies of <=1 nJ are examined. A specific class of infrared absorbing dyes, squarylium, is discussed and preliminary data on optical characteristics, writing energy, and stability are presented.
Code of Federal Regulations, 2010 CFR
2010-01-01
... 10 Energy 1 2010-01-01 2010-01-01 false General license for possession and storage of byproduct material as defined in this part. 40.26 Section 40.26 Energy NUCLEAR REGULATORY COMMISSION DOMESTIC LICENSING OF SOURCE MATERIAL General Licenses § 40.26 General license for possession and storage of...
40 CFR Table 4 to Subpart Jjj of... - Group 1 Storage Vessels at New Affected Sources
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Group 1 Storage Vessels at New Affected... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 4 Table 4 to Subpart JJJ of Part 63—Group 1 Storage Vessels at New Affected...
Code of Federal Regulations, 2012 CFR
2012-07-01
... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...
Code of Federal Regulations, 2014 CFR
2014-07-01
... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...
Code of Federal Regulations, 2010 CFR
2010-07-01
... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...
Code of Federal Regulations, 2013 CFR
2013-07-01
... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...
Code of Federal Regulations, 2011 CFR
2011-07-01
... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...
The effect of storage temperature and duration on northern red oak acorn viability and vigour
Thomas L. Noland; Andree E. Morneault; Daniel C. Dey; Dave Deugo
2013-01-01
Three separate collections of Ontario sources of northern red oak (Quercus rubra L.) acorns were made to determine the effects of long-term cold storage at +2°C, -1°C, and -2°C on their viability and vigour. We measured acorn moisture content, percent germination during storage, speed of germination and total germination...
40 CFR Table 4 to Subpart Jjj of... - Group 1 Storage Vessels at New Affected Sources
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 12 2012-07-01 2011-07-01 true Group 1 Storage Vessels at New Affected... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins Pt. 63, Subpt. JJJ, Table 4 Table 4 to Subpart JJJ of Part 63—Group 1 Storage Vessels at New Affected...
NASA Astrophysics Data System (ADS)
Huang, Bin; Li, Xinhai; Wang, Zhixing; Guo, Huajun; Shen, Li; Wang, Jiexi
2014-04-01
The degradation of Ni-rich LiNi0.8Co0.15Al0.05O2 cathode material is successfully suppressed via a facile in situ oxidizing-coating method. KMnO4 is used as not only a Mn source but also an oxidant. X-ray diffraction (XRD) and scanning electron microscope (SEM) results demonstrate that the structure and morphology of the KMnO4-pretreated sample are the same as the pristine one. X-ray photoelectron spectroscopy (XPS) confirms that the valence state of Mn is +4 and the Ni3+ ions are partly reduced to Ni2+ when the material is doped with Mn4+. Besides, the Mn4+ ions are proved to distribute uniformly on the surface of the materials particles through energy dispersive spectrometer (EDS) and EDS elemental mapping. And it is confirmed that the concentration of Ni in the outer layer is reduced by the Mn-surface-modification. From the electrochemical characterizations, it is confirmed that the presence of tetravalent Mn at the surface can suppress the capacity fading during charge-discharge cycles, even under elevated temperature and overcharge conditions, and can prevent the material from deterioration during storage in air.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cochran, John Russell
The Al Tuwaitha nuclear complex near Baghdad contains a number of facilities from Saddam Hussan's nuclear weapons program. Past military operations, lack of upkeep and looting have created an enormous radioactive waste problem at the Al Tuwaitha complex, which contains various, uncharacterized radioactive wastes, yellow cake, sealed radioactive sources, and contaminated metals that must be constantly guarded. Iraq has never had a radioactive waste disposal facility and the lack of a disposal facility means that ever increasing quantities of radioactive material must be held in guarded storage. The Iraq Nuclear Facility Dismantlement and Disposal Program (the NDs Program) has beenmore » initiated by the U.S. Department of State (DOS) to assist the Government of Iraq (GOI) in eliminating the threats from poorly controlled radioactive materials, while building human capacities so that the GOI can manage other environmental cleanups in their country. The DOS is funding the IAEA to provide technical assistance via Technical Cooperation projects. Program coordination will be provided by the DOS, consistent with GOI policies, and Sandia National Laboratories will be responsible for coordination of participants and waste management support. Texas Tech University will continue to provide in-country assistance, including radioactive waste characterization and the stand-up of the Iraq Nuclear Services Company. The GOI owns the problems in Iraq and will be responsible for implementation of the NDs Program.« less
Storage nitrogen co-ordinates leaf expansion and photosynthetic capacity in winter oilseed rape
Liu, Tao; Ren, Tao; White, Philip J; Cong, Rihuan
2018-01-01
Abstract Storage nitrogen (N) is a buffer pool for maintaining leaf growth and synthesizing photosynthetic proteins, but the dynamics of its forms within the life cycle of a single leaf and how it is influenced by N supply remain poorly understood. A field experiment was conducted to estimate the influence of N supply on leaf growth, photosynthetic characteristics, and N partitioning inthe sixth leaf of winter oilseed rape (Brassica napus L.) from emergence through senescence. Storage N content (Nstore) decreased gradually along with leaf expansion. The relative growth rate based on leaf area (RGRa) was positively correlated with Nstore during leaf expansion. The water-soluble protein form of storage N was the main N source for leaf expansion. After the leaves fully expanded, the net photosynthetic rate (An) followed a linear–plateau response to Nstore, with An stabilizing at the highest value above a threshold and declining below the threshold. Non-protein and SDS (detergent)-soluble protein forms of storage N were the main N sources for maintaining photosynthesis. For the leaf N economy, storage N is used for co-ordinating leaf expansion and photosynthetic capacity. N supply can improve Nstore, thereby promoting leaf growth and biomass. PMID:29669007
Magnetically switched power supply system for lasers
NASA Technical Reports Server (NTRS)
Pacala, Thomas J. (Inventor)
1987-01-01
A laser power supply system is described in which separate pulses are utilized to avalanche ionize the gas within the laser and then produce a sustained discharge to cause the gas to emit light energy. A pulsed voltage source is used to charge a storage device such as a distributed capacitance. A transmission line or other suitable electrical conductor connects the storage device to the laser. A saturable inductor switch is coupled in the transmission line for containing the energy within the storage device until the voltage level across the storage device reaches a predetermined level, which level is less than that required to avalanche ionize the gas. An avalanche ionization pulse generating circuit is coupled to the laser for generating a high voltage pulse of sufficient amplitude to avalanche ionize the laser gas. Once the laser gas is avalanche ionized, the energy within the storage device is discharged through the saturable inductor switch into the laser to provide the sustained discharge. The avalanche ionization generating circuit may include a separate voltage source which is connected across the laser or may be in the form of a voltage multiplier circuit connected between the storage device and the laser.
Liu, Leili; Li, Jie; Zhang, Lingyao; Tian, Siyu
2018-01-15
MgH 2 , Mg 2 NiH 4 , and Mg 2 CuH 3 were prepared, and their structure and hydrogen storage properties were determined through X-ray photoelectron spectroscopy and thermal analyzer. The effects of MgH 2 , Mg 2 NiH 4 , and Mg 2 CuH 3 on the thermal decomposition, burning rate, and explosive heat of ammonium perchlorate-based composite solid propellant were subsequently studied. Results indicated that MgH 2 , Mg 2 NiH 4 , and Mg 2 CuH 3 can decrease the thermal decomposition peak temperature and increase the total released heat of decomposition. These compounds can improve the effect of thermal decomposition of the propellant. The burning rates of the propellant increased using Mg-based hydrogen storage materials as promoter. The burning rates of the propellant also increased using MgH 2 instead of Al in the propellant, but its explosive heat was not enlarged. Nonetheless, the combustion heat of MgH 2 was higher than that of Al. A possible mechanism was thus proposed. Copyright © 2017. Published by Elsevier B.V.
Flexible operation of thermal plants with integrated energy storage technologies
NASA Astrophysics Data System (ADS)
Koytsoumpa, Efthymia Ioanna; Bergins, Christian; Kakaras, Emmanouil
2017-08-01
The energy system in the EU requires today as well as towards 2030 to 2050 significant amounts of thermal power plants in combination with the continuously increasing share of Renewables Energy Sources (RES) to assure the grid stability and to secure electricity supply as well as to provide heat. The operation of the conventional fleet should be harmonised with the fluctuating renewable energy sources and their intermittent electricity production. Flexible thermal plants should be able to reach their lowest minimum load capabilities while keeping the efficiency drop moderate as well as to increase their ramp up and down rates. A novel approach for integrating energy storage as an evolutionary measure to overcome many of the challenges, which arise from increasing RES and balancing with thermal power is presented. Energy storage technologies such as Power to Fuel, Liquid Air Energy Storage and Batteries are investigated in conjunction with flexible power plants.
RF System Requirements for a Medium-Energy Electron-Ion Collider (MEIC) at JLab
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rimmer, Robert A; Hannon, Fay E; Guo, Jiquan
2015-09-01
JLab is studying options for a medium energy electron-ion collider that could fit on the JLab site and use CEBAF as a full-energy electron injector. A new ion source, linac and booster would be required, together with collider storage rings for the ions and electrons. In order to achieve the maximum luminosity these will be high-current storage rings with many bunches. We present the high-level RF system requirements for the storage rings, ion booster ring and high-energy ion beam cooling system, and describe the technology options under consideration to meet them. We also present options for staging that might reducemore » the initial capital cost while providing a smooth upgrade path to a higher final energy. The technologies under consideration may also be useful for other proposed storage ring colliders or ultimate light sources.« less
NASA Astrophysics Data System (ADS)
Pyne, Moinak
This thesis aspires to model and control, the flow of power in a DC microgrid. Specifically, the energy sources are a photovoltaic system and the utility grid, a lead acid battery based energy storage system and twenty PEV charging stations as the loads. Theoretical principles of large scale state space modeling are applied to model the considerable number of power electronic converters needed for controlling voltage and current thresholds. The energy storage system is developed using principles of neural networks to facilitate a stable and uncomplicated model of the lead acid battery. Power flow control is structured as a hierarchical problem with multiple interactions between individual components of the microgrid. The implementation is done using fuzzy logic with scheduling the maximum use of available solar energy and compensating demand or excess power with the energy storage system, and minimizing utility grid use, while providing multiple speeds of charging the PEVs.
[Medical image compression: a review].
Noreña, Tatiana; Romero, Eduardo
2013-01-01
Modern medicine is an increasingly complex activity , based on the evidence ; it consists of information from multiple sources : medical record text , sound recordings , images and videos generated by a large number of devices . Medical imaging is one of the most important sources of information since they offer comprehensive support of medical procedures for diagnosis and follow-up . However , the amount of information generated by image capturing gadgets quickly exceeds storage availability in radiology services , generating additional costs in devices with greater storage capacity . Besides , the current trend of developing applications in cloud computing has limitations, even though virtual storage is available from anywhere, connections are made through internet . In these scenarios the optimal use of information necessarily requires powerful compression algorithms adapted to medical activity needs . In this paper we present a review of compression techniques used for image storage , and a critical analysis of them from the point of view of their use in clinical settings.
NASA Astrophysics Data System (ADS)
Treble, P. C.; Baker, A.; Fairchild, I. J.; Bradley, C.; Mahmud, K.; Andersen, M. S.; Meredith, K.; Mariethoz, G.
2015-12-01
Golgotha Cave is located in a forested catchment in SW Australia where evapotranspiration losses from the vadose-zone are high and forest biomass has been disturbed by fire. The cave has been continuously monitored since 2005 and this extensive dataset has been used to quantify key processes determining dripwater hydrology and chemistry (Mahmud et al., 2015; Treble et al., 2013; 2015). In this paper we present a synthesis of these findings and derive a conceptual model to illustrate the main hydrochemical processes that will impact cave dripwater in similar environments. We applied mass-balance techniques to quantify sources (water/rock interactions and aerosol) and sinks (prior calcite precipitation and biomass uptake). Mass-balance results suggest that transpiration and elemental sequestration into biomass modifies dripwater ion concentrations. The vegetation uptake impacts dripwater Mg, K and SO4, with the largest impact on SO4, estimated to be up to 60% at some drip sites. Overall, our findings suggest that varying amounts of transpiration by deeply-rooted trees contribute significantly to spatial and temporal variability in dripwater solute concentrations. This is in addition to the partitioning of infiltrating water between characteristic flow pathways. Applying principal components analysis, we identify a common long-term rising trend in dripwater Cl, Mg, K, Ca, Sr and Si. We assess whether the long-term trends in dripwater solutes are driven by post-fire biomass recovery and/or the impacts of a drying climate in SW Australia.ReferencesMahmud et al. (2015), Terrestrial Lidar Survey and Morphological Analysis to Identify Infiltration Properties in the Tamala Limestone, Western Australia, doi:10.1109/JSTARS.2015.2451088. Treble et al. (2013), An isotopic and modelling study of flow paths and storage in Quaternary calcarenite, doi:10.1016/J.Quascirev.2012.12.015. Treble et al. (2015), Impacts of cave air ventilation and in-cave prior calcite precipitation on Golgotha Cave dripwater chemistry, doi:10.1016/J.Quascirev.2015.06.001.
Transuranic sealed source recovery project.
Tompkins, J A; Pearson, M W
2001-11-01
If you have transuranic sealed sources (239Pu, 238Pu, or 241Am) that have no potential for recycle or commercial disposal, the Off Site Source Recovery Project at LANL can assist in recovering the sealed sources from your facility to a DOE storage site.
NASA Astrophysics Data System (ADS)
Rouhani, S. F. B. B.; Schaaf, C.; Douglas, E. M.; Choate, J. S.; Yang, Y.; Kim, J.
2014-12-01
The movement of Dissolved Organic Carbon (DOC) from terrestrial system into aquatic system plays an important role for carbon sequestration in ecosystems and affects the formation of soil organic matters.Carbon cycling, storage, and transport to marine systems have become critical issues in global-change science, especially with regard to northern latitudes (Freeman et al., 2001; Benner et al., 2004). DOC, as an important composition of the carbon cycling, leaches from the terrestrial watersheds is a large source of marine DOC. The Penobscot River basin in north-central Maine is the second largest watershed in New England, which drains in to Gulf of Maine. Approximately 89% of the watershed is forested (Griffith and Alerich, 1996).Studying temporal and spatial changes in DOC export can help us to understand terrestrial carbon cycling and to detect any shifts from carbon sink to carbon source or visa versa in northern latitude forested ecosystems.Despite for the importance of understanding carbon cycling in terrestrial and aquatic biogeochemistry, the Doc export, especially the combination of DOC production from bio-system and DOC transportation from the terrestrial in to stream has been lightly discussed in most conceptual or numerical models. The Regional Hydro-Ecological Simulation System (RHESSys), which has been successfully applied in many study sites, is a physical process based terrestrial model that has the ability to simulate both the source and transportation of DOC by combining both hydrological and ecological processes. The focus of this study is on simulating the DOC concentration and flux from the land to the water using RHESSys in the Penobscot watershed. The simulated results will be compared with field measurement of DOC from the watershed to explore the spatial and temporal DOC export pattern. This study will also enhance our knowledge to select sampling locations properly and also improve our understanding on DOC production and transportation in terrestrial forest ecosystem.
Long-Period Ground Motion due to Near-Shear Earthquake Ruptures
NASA Astrophysics Data System (ADS)
Koketsu, K.; Yokota, Y.; Hikima, K.
2010-12-01
Long-period ground motion has become an increasingly important consideration because of the recent rapid increase in the number of large-scale structures, such as high-rise buildings and large oil storage tanks. Large subduction-zone earthquakes and moderate to large crustal earthquakes can generate far-source long-period ground motions in distant sedimentary basins with the help of path effects. Near-fault long-period ground motions are generated, for the most part, by the source effects of forward rupture directivity (Koketsu and Miyake, 2008). This rupture directivity effect is the maximum in the direction of fault rupture when a rupture velocity is nearly equal to shear wave velocity around a source fault (Dunham and Archuleta, 2005). The near-shear rupture was found to occur during the 2008 Mw 7.9 Wenchuan earthquake at the eastern edge of the Tibetan plateau (Koketsu et al., 2010). The variance of waveform residuals in a joint inversion of teleseismic and strong motion data was the minimum when we adopted a rupture velocity of 2.8 km/s, which is close to the shear wave velocity of 2.6 km/s around the hypocenter. We also found near-shear rupture during the 2010 Mw 6.9 Yushu earthquake (Yokota et al., 2010). The optimum rupture velocity for an inversion of teleseismic data is 3.5 km/s, which is almost equal to the shear wave velocity around the hypocenter. Since, in addition, supershear rupture was found during the 2001 Mw 7.8 Central Kunlun earthquake (Bouchon and Vallee, 2003), such fast earthquake rupture can be a characteristic of the eastern Tibetan plateau. Huge damage in Yingxiu and Beichuan from the 2008 Wenchuan earthquake and damage heavier than expected in the county seat of Yushu from the medium-sized Yushu earthquake can be attributed to the maximum rupture directivity effect in the rupture direction due to near-shear earthquake ruptures.
NASA Astrophysics Data System (ADS)
Bilbro, Griff L.; Hou, Danqiong; Yin, Hong; Trew, Robert J.
2009-02-01
We have quantitatively modeled the conduction current and charge storage of an HFET in terms its physical dimensions and material properties. For DC or small-signal RF operation, no adjustable parameters are necessary to predict the terminal characteristics of the device. Linear performance measures such as small-signal gain and input admittance can be predicted directly from the geometric structure and material properties assumed for the device design. We have validated our model at low-frequency against experimental I-V measurements and against two-dimensional device simulations. We discuss our recent extension of our model to include a larger class of electron velocity-field curves. We also discuss the recent reformulation of our model to facilitate its implementation in commercial large-signal high-frequency circuit simulators. Large signal RF operation is more complex. First, the highest CW microwave power is fundamentally bounded by a brief, reversible channel breakdown in each RF cycle. Second, the highest experimental measurements of efficiency, power, or linearity always require harmonic load pull and possibly also harmonic source pull. Presently, our model accounts for these facts with an adjustable breakdown voltage and with adjustable load impedances and source impedances for the fundamental frequency and its harmonics. This has allowed us to validate our model for large signal RF conditions by simultaneously fitting experimental measurements of output power, gain, and power added efficiency of real devices. We show that the resulting model can be used to compare alternative device designs in terms of their large signal performance, such as their output power at 1dB gain compression or their third order intercept points. In addition, the model provides insight into new device physics features enabled by the unprecedented current and voltage levels of AlGaN/GaN HFETs, including non-ohmic resistance in the source access regions and partial depletion of the 2DEG in the drain access region.
Early spectra of the gravitational wave source GW170817: Evolution of a neutron star merger
NASA Astrophysics Data System (ADS)
Shappee, B. J.; Simon, J. D.; Drout, M. R.; Piro, A. L.; Morrell, N.; Prieto, J. L.; Kasen, D.; Holoien, T. W.-S.; Kollmeier, J. A.; Kelson, D. D.; Coulter, D. A.; Foley, R. J.; Kilpatrick, C. D.; Siebert, M. R.; Madore, B. F.; Murguia-Berthier, A.; Pan, Y.-C.; Prochaska, J. X.; Ramirez-Ruiz, E.; Rest, A.; Adams, C.; Alatalo, K.; Bañados, E.; Baughman, J.; Bernstein, R. A.; Bitsakis, T.; Boutsia, K.; Bravo, J. R.; Di Mille, F.; Higgs, C. R.; Ji, A. P.; Maravelias, G.; Marshall, J. L.; Placco, V. M.; Prieto, G.; Wan, Z.
2017-12-01
Two neutron stars merging together generate a gravitational wave signal and have also been predicted to emit electromagnetic radiation. When the gravitational wave event GW170817 was detected, astronomers rushed to search for the source using conventional telescopes (see the Introduction by Smith). Coulter et al. describe how the One-Meter Two-Hemispheres (1M2H) collaboration was the first to locate the electromagnetic source. Drout et al. present the 1M2H measurements of its optical and infrared brightness, and Shappee et al. report their spectroscopy of the event, which is unlike previously detected astronomical transient sources. Kilpatrick et al. show how these observations can be explained by an explosion known as a kilonova, which produces large quantities of heavy elements in nuclear reactions.
Swope Supernova Survey 2017a (SSS17a), the optical counterpart to a gravitational wave source
NASA Astrophysics Data System (ADS)
Coulter, D. A.; Foley, R. J.; Kilpatrick, C. D.; Drout, M. R.; Piro, A. L.; Shappee, B. J.; Siebert, M. R.; Simon, J. D.; Ulloa, N.; Kasen, D.; Madore, B. F.; Murguia-Berthier, A.; Pan, Y.-C.; Prochaska, J. X.; Ramirez-Ruiz, E.; Rest, A.; Rojas-Bravo, C.
2017-12-01
Two neutron stars merging together generate a gravitational wave signal and have also been predicted to emit electromagnetic radiation. When the gravitational wave event GW170817 was detected, astronomers rushed to search for the source using conventional telescopes (see the Introduction by Smith). Coulter et al. describe how the One-Meter Two-Hemispheres (1M2H) collaboration was the first to locate the electromagnetic source. Drout et al. present the 1M2H measurements of its optical and infrared brightness, and Shappee et al. report their spectroscopy of the event, which is unlike previously detected astronomical transient sources. Kilpatrick et al. show how these observations can be explained by an explosion known as a kilonova, which produces large quantities of heavy elements in nuclear reactions.
Limits to the availability of groundwater in Africa
NASA Astrophysics Data System (ADS)
Edmunds, W. Mike
2012-06-01
The recent paper on Africa's groundwater by MacDonald et al (2012) has attracted much attention. This is good news, especially since groundwater has been widely ignored, misunderstood or abused, as a fundamental global resource. This important paper goes a long way to raising the profile of groundwater in Africa by providing first-order estimates of the available storage (taking account of saturated aquifer thickness and porosity) as well as mapping expected water yields (aquifer productivity) in that continent. Reliable estimates of groundwater resources can now be set against the far more widely reported surface water availability. The constraints of the methodology used to compile these maps are duly acknowledged, and are well within the hydrogeological state-of-the-art. The paper is backed by carefully reviewed sources of data and a considerable effort has been made to incorporate the extensive grey literature. It is important that this benchmark study is received with the acclaim it deserves. However, the headline—that groundwater storage is some 100 times the annual renewable surface waters—could be misconstrued as implying that groundwater is an abundant new resource, which it is not. Whilst groundwater is key to sustainable development, renewability and accessibility issues need to be addressed. The paper may therefore be seized upon to justify unsustainable groundwater exploitation, or to provide an argument against funding to NGOs and others, for water provision for needy communities. Some constraints that must be taken into account are elaborated here. The conclusions of the paper (MacDonald et al 2012) demonstrate that modest yields of groundwater are quite widely available at accessible depths and sufficient to sustain small communities and their development, but larger yields (>5 l s-1) suitable for urban development or major agricultural schemes are unlikely outside of the sedimentary terrain. The availability and accessibility of groundwater over much of Africa, therefore, is favourable to rural rather than urban development. One of the real opportunities presented in the paper is that groundwater should be more widely used for a revolution in rural development. To this end, the use of managed aquifer recharge (MAR), coupled with other forms of rainwater harvesting, can also locally conserve and augment groundwater resources and offer obvious advantages over building surface water storage. The large sedimentary aquifers of Africa contain some 0.66 million km3 in storage (MacDonald et al 2012); but most of this water (0.44 M km3) is contained beneath eight Saharan countries (see table 1, MacDonald et al 2012). This includes the Nubian Sandstone aquifer system, underlying Egypt, Libya, Sudan and Chad. In Libya this immense high yielding aquifer may be over 2.5 km thick (Pallas 1980) but considerable depths to the water table make for costly development. Water in Libya is currently being extracted (mined) from remote inland areas for transmission to the coast, from wells typically 300-500 m deep with estimated well-field lifetimes unlikely to exceed 50 years (Pallas and Salem 2001). This and the other Saharan aquifers are accessible only to a very small fraction of the African population. Groundwater extraction and transmission is possible only with the energy provided from the proximity of fossil fuels; large water transfer schemes are energy intensive and for most areas of Africa not an economic option, having also social and ecological consequences (Matete and Hassan 2005). Moreover a steady decline in water tables (typically from 0.5 to 2 m yr) has been taking place widely in semi-arid areas globally, mostly due to abstraction exceeding recharge, with consequences for both human requirements and ecosystems. Thus a major limiting factor is the need to identify whether the stored groundwater is a renewable or a non-renewable resource. In the case of deep basins such as the Saharan aquifers this water can be shown, from numerous studies, to be almost entirely non-renewable, 'fossil' water, recharged under wetter early Holocene or late Pleistocene climates, prior to onset of a more arid climate around 4500 years BP (Edmunds et al 2004). Small amounts of modern recharge (for example in the Atlas Mountains or Tibesti) are insufficient to have an impact on the drawdown of distant well fields. It is critical, therefore, to base resource estimates for any development on knowledge of the locally renewable amounts from rainfall and to consider mining palaeo-reserves only as a last resort. Hydrogeological techniques are available to quantify modern recharge (Scanlon and Cook 2002, Scanlon et al 2006) and rates can vary widely according to rock type and landscape; reliance on modelled estimates alone could be misleading. Water quality is also a limiting factor in quantifying usable fresh groundwater storage. In addition to the regional or local problems caused by fluoride, in areas of East and West Africa (MacDonald et al 2012), salinity, above all, will restrict the total usable storage for domestic use and food production, most notably in semi-arid or arid areas. Groundwater salinity arises from various sources, including lithologies containing evaporite minerals, residual sea water (especially in continental coastal margins) and evapotranspiration. As a general rule, salinity increases with depth (older waters tend to more saline), but an additional problem arises where salinity has built up due to aridification over several millennia. Playas and sebkhats are surface expressions of this salinity accumulation from surface water or groundwater discharge, but clearance of native vegetation also increases recharge and leads to salinity increase (George et al 1997). Near-surface salt accumulation may be drawn down into cones of depression in areas of development. One of the largest artesian aquifers, the Continental Intercalaire of Algeria and Tunisia, has groundwater discharge with a salinity of 1-3 g l-1, locally as high as 7 g l-1 in the Tunisian Chotts (Edmunds et al 2003, Zammouri et al 2007), limiting water for irrigated agriculture. The volumes of non-saline and groundwater in the total storage therefore need to be considered as part of the storage. References Edmunds W M, Dodo A, Djoret D, Gasse F, Gaye C B, Goni I B, Travi Y, Zouari K and Zuppi G M 2004 Groundwater as an archive of climatic and environmental change. The PEP-III traverse Past Climate Variability through Europe and Africa (Developments in Palaeoenvironmental Research Series) ed R W Battarbee, F Gasse and C E Stickley (Dordrecht: Kluwer) pp 279-306 Edmunds W M, Guendouz A H, Mamou A, Moulla A S, Shand P and Zouari K 2003 Groundwater evolution in the Continental Intercalaire aquifer of Southern Algeria and Tunisia: trace element and isotopic indicators Appl. Geochem. 18 805-22 George R, McFarlane D and Nulsen R 1997 Salinity threatens the viability of agriculture and ecosystems in Western Australia Hydrogeol. J. 5 6-21 MacDonald A M, Bonsor H C, O'Dochartaigh B E and Taylor R G 2012 Quantitative maps of groundwater resources in Africa Environ. Res. Lett. 7 024009 Matete M and Hassan R 2005 Anecological economics framework for assessing environmental flows: the case of inter-basin water transfers in Lesotho Glob. Planet. Change 47 193-200 Pallas P 1980 Water resources of the Socialist People's Libyan Arab Jamahariya The Geology of Libya vol 2, ed M J Salem and M T Busrewil (London: Academic) pp 539-94 Pallas P and Salem O 2001 Water resources utilisation and management of the Socialist People's Arab Jamahiriya Regional Aquifer Systems in Arid Zones—Managing Non-Renewable Resources (IHP-V Technical Documents in Hydrology) (Paris: UNESCO) pp 147-72 Scanlon B R and Cook P G 2002 Preface: theme issue on groundwater recharge Hydrogeol. J. 10 3-4 and following papers Scanlon B R, Keese K E, Flint A L, Flint L E, Gaye C B, Edmunds W M and Simmers I 2006 Global synthesis of groundwater recharge in semi-arid and arid regions Hydrol. Process. 20 3335-70 Zammouri M, Siegfried T, El-Fahem T, Kriâa S and Kinzelbach W 2007 Salinization of groundwater in the Nefzawaoases region, Tunisia: results of a regional-scale hydrogeologic approach Hydrogeol. J. 15 1357-75
Seasonal Thermal Energy Storage Program
NASA Technical Reports Server (NTRS)
Minor, J. E.
1980-01-01
The Seasonal Thermal Energy Storage (STES) Program designed to demonstrate the storage and retrieval of energy on a seasonal basis using heat or cold available from waste or other sources during a surplus period is described. Factors considered include reduction of peak period demand and electric utility load problems and establishment of favorable economics for district heating and cooling systems for commercialization of the technology. The initial thrust of the STES Program toward utilization of ground water systems (aquifers) for thermal energy storage is emphasized.
Customized electric power storage device for inclusion in a microgrid
Goldsmith, Steven Y.; Wilson, David; Robinett, III, Rush D.
2017-08-01
An electric power storage device included in a microgrid is described herein. The electric power storage device has at least one of a charge rate, a discharge rate, or a power retention capacity that has been customized for the microgrid. The at least one of the charge rate, the discharge rate, or the power retention capacity of the electric power storage device is computed based at least in part upon specified power source parameters in the microgrid and specified load parameters in the microgrid.
The Status of the Taiwan Photon Source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kuo, C. C.; Wang, J. P.; Chen, J. R.
2010-06-23
NSRRC has been operating a 1.5 GeV synchrotron light source, the Taiwan Light Source (TLS), for over 15 years and has established a large user community. For the future development of synchrotron radiation research in Taiwan, a feasibility study report to construct a 3.0 GeV low-emittance storage ring, the Taiwan Photon Source (TPS), was issued in July 2005. The government approval of the TPS project was obtained in December 2007 and the machine will be built at current site of NSRRC. The project has progressed steadily since and reached several major milestones now: the architect firm has finished the sitemore » plan and civil design, the accelerator design has been fixed, and purchase of long-lead items begins its course. The TPS storage ring has a circumference of 518.4 meters with a concentric booster of 496.8 meters. The storage ring adopted a 24-cell double-bend structure with a 1.6 nm-rad natural emittance. There are six 12-m and eighteen 7-m ID straights. For user research, five new beamlines have been selected for the Phase I operations: the micro protein crystallography, the materials sub-micron diffraction, the inelastic soft x-ray scattering, the coherent x-ray scattering, and the nano probe beamlines. The civil construction is getting ready to start. The commissioning of the TPS storage ring is targeted for 2013.« less
Benchmarking of MCNP for calculating dose rates at an interim storage facility for nuclear waste.
Heuel-Fabianek, Burkhard; Hille, Ralf
2005-01-01
During the operation of research facilities at Research Centre Jülich, Germany, nuclear waste is stored in drums and other vessels in an interim storage building on-site, which has a concrete shielding at the side walls. Owing to the lack of a well-defined source, measured gamma spectra were unfolded to determine the photon flux on the surface of the containers. The dose rate simulation, including the effects of skyshine, using the Monte Carlo transport code MCNP is compared with the measured dosimetric data at some locations in the vicinity of the interim storage building. The MCNP data for direct radiation confirm the data calculated using a point-kernel method. However, a comparison of the modelled dose rates for direct radiation and skyshine with the measured data demonstrate the need for a more precise definition of the source. Both the measured and the modelled dose rates verified the fact that the legal limits (<1 mSv a(-1)) are met in the area outside the perimeter fence of the storage building to which members of the public have access. Using container surface data (gamma spectra) to define the source may be a useful tool for practical calculations and additionally for benchmarking of computer codes if the discussed critical aspects with respect to the source can be addressed adequately.
Principles for timing at spallation neutron sources based on developments at LANSCE
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nelson, R. O.; Merl, R. B.; Rose, C. R.
2001-01-01
Due to AC-power-grid frequency fluctuations, the designers for accelerator-based spallation-neutron facilities have worked to optimize the conflicting demands of accelerator and neutron chopper performance. For the first time, we are able to quantitatively access the tradeoffs between these two constraints and design or upgrade a facility to optimize total system performance using powerful new simulation techniques. We have modeled timing systems that integrate chopper controllers and chopper hardware and built new systems. Thus, at LANSCE, we now operate multiple chopper systems and the accelerator as simple slaves to a single master-timing-reference generator. Based on this experience we recommend that spallationmore » neutron sources adhere to three principles. First, timing for pulsed sources should be planned starting with extraction at a fixed phase and working backwards toward the leading edge of the beam pulse. Second, accelerator triggers and storage ring extraction commands from neutron choppers offer only marginal benefits to accelerator-based spallation sources. Third, the storage-ring RF should be phase synchronized with neutron choppers to provide extraction without the one orbit timing uncertainty.« less
Evidence for Increased Carbon Storage in the Mid-Depth South Atlantic During the Last Deglaciation
NASA Astrophysics Data System (ADS)
Lacerra, M.; Lund, D. C.; Yu, J.
2016-12-01
Carbon isotope anomalies were a ubiquitous feature in the mid-depth Atlantic during Heinrich Stadial 1 (HS1, 14.5-17.5 kyr BP) yet their cause is a matter of ongoing debate. New evidence points towards North Atlantic processes as the source of the δ13C anomalies, with the most likely driver being weakening of the Atlantic Meridional Overturning Circulation (AMOC) (1, 2). Model simulations suggest that slowing of the AMOC 1) minimizes sinking of high δ13C surface water in the North Atlantic, and 2) increases the residence time of deep water, leading to the accumulation of isotopically light respired carbon (3). The simulated tracer field shows the largest anomalies in the North Atlantic and progressively smaller anomalies in the tropical and South Atlantic, similar to observations. Here, we assess the accumulation of carbon in the mid-depth South Atlantic using foraminiferal B/Ca, a proxy for [CO32-] (which is inversely related to ΣCO2) (4). Using two high resolution records from the Brazil Margin, we show that [CO32-] decreased by 23±6 μmol/kg during HS1 and 15±7 μmol/kg during the Younger Dryas (YD, 11.5-12.9 kyr BP), synchronous with the apparent AMOC weakening recorded in 231Pa/230Th records (5). The [CO32-] response at the Brazil Margin is smaller than at 12°N (6), implying there was a north-south gradient in [CO32-] signals during HS1. The implied millennial scale increases in ΣCO2 are consistent with model results of AMOC shutdown, suggesting the mid-depth Atlantic acted as a temporary reservoir of stored carbon during both HS1 and the YD. On longer time-scales, changes in [CO32-] at the Brazil Margin likely reflect exchange with an atmosphere with progressively higher pCO2. Our results suggest that mid-depth δ13C anomalies were partly due to increased carbon storage, meaning δ13C behaved non-conservatively during the deglaciation. Our results also imply that mechanisms responsible for rising atmospheric CO2levels must have counteracted increased carbon sequestration in the mid-depth Atlantic. 1) Lund et al., 2015, Paleoceanography, 30, 1-18. 2) Oppo et al., 2015, Paleoceanography, 30, 353-368. 3) Schmittner & Lund, 2015, Clim. Past, 11, 135-152. 4) Yu & Elderfield, 2007, Earth Planet. Sci. Lett., 258, 73-86. 5) McManus et al., 2004, Nature,428, 834-837. 6) Yu et al., 2010, Science, 330, 1084-1087.
NASA Astrophysics Data System (ADS)
Fontana, Robert E.; Decad, Gary M.
2018-05-01
This paper describes trends in the storage technologies associated with Linear Tape Open (LTO) Tape cartridges, hard disk drives (HDD), and NAND Flash based storage devices including solid-state drives (SSD). This technology discussion centers on the relationship between cost/bit and bit density and, specifically on how the Moore's Law perception that areal density doubling and cost/bit halving every two years is no longer being achieved for storage based components. This observation and a Moore's Law Discussion are demonstrated with data from 9-year storage technology trends, assembled from publically available industry reporting sources.
4. VIEW SOUTHWEST COMPONENTS TEST LAB TEST BAY DETAIL SHOWING ...
4. VIEW SOUTHWEST COMPONENTS TEST LAB TEST BAY DETAIL SHOWING EMERGENCY SHOWER, AND EYEWASH, AND OBSERVATION WINDOW. STORAGE TANKS ON ROOF. - Marshall Space Flight Center, East Test Area, Components Test Laboratory, Huntsville, Madison County, AL
19. FIRST FLOOR LEVEL BELOW ICE FREEZING TANKS AND LOWER ...
19. FIRST FLOOR LEVEL BELOW ICE FREEZING TANKS AND LOWER LEVEL OF ICE DUMP AND LIFT WHERE FROZEN ICE IS BROUGHT INTO STORAGE. - Atlantic Ice & Coal Company, 135 Prince Street, Montgomery, Montgomery County, AL
NASA Astrophysics Data System (ADS)
Baei, Mohammad T.; Koohi, Maryam; Shariati, Minoo
2018-05-01
The stability, geometry, and electronic properties of C20 and its AlnPnC20-2n heterofullerenic derivatives where n = 1-10 are probed, at density functional theory (DFT). Vibrational frequency calculations show that exclusive of Al6P6C8 and Al10P8C2, other species are true minima. Exploring of the optimized structures demonstrates the shrinkage of Cdbnd C double bonds to compensate for the longer Csbnd Al, Csbnd P and Alsbnd P single bonds. The calculated binding energy, HOMO-LUMO gap and nucleus independent chemical shift at the cage center (NICS (0)) of Al1P1C18 shows it the most stable structure. While substituting of 1, 2, 3, 4, 6, and 7 Alsbnd P units enhances kinetic stability of the resulting heterofullerenes against electronic excitations via increasing their HOMO-LUMO gap, doping of 5, 8, 9, and 10 Alsbnd P units increases the conductivity of heterofullerenes through decreasing their band gap. Substitutional doping leads to a high point charge upon the surfaces of all derivatives, especially the highest delocalization on Al6P6C8, with range of -2.056 to -1.261 charged carbons, +1.493 to +1.586 charged aluminums, and +0.513 to +0.801 charged phosphor atoms, followed by Al4P4C12. These high charge distributions on the surfaces of the studied analogous can develop their storage capacity and henceforth characterize them worthy of investigation for hydrogen storage. Also, Al1P1C18, Al2P2C16, and Al10P10 are shown as the most aromatic and anti-aromatic nanocages with NICS (0) of -41.60, -39.82, and +22.59 ppm, respectively, compared to C20 (-19.61 ppm). The computed higher dipole moment of Al1P1C18 and Al5P5C10 (4.06 and 3.29 Debye, respectively) exhibits higher reactivity potential and greater affinity of them to more polar solvents. Thus, in both gas phase and polar solvent, Al1P1C18 structure is expected to be stabilized to a greater extent than the other species, which has been confirmed by the thermodynamic and kinetic data.
Thermal storage/discharge performances of Cu-Si alloy for solar thermochemical process
NASA Astrophysics Data System (ADS)
Gokon, Nobuyuki; Yamaguchi, Tomoya; Cho, Hyun-seok; Bellan, Selvan; Hatamachi, Tsuyoshi; Kodama, Tatsuya
2017-06-01
The present authors (Niigata University, Japan) have developed a tubular reactor system using novel "double-walled" reactor/receiver tubes with carbonate molten-salt thermal storage as a phase change material (PCM) for solar reforming of natural gas and with Al-Si alloy thermal storage as a PCM for solar air receiver to produce high-temperature air. For both of the cases, the high heat capacity and large latent heat (heat of solidification) of the PCM phase circumvents the rapid temperature change of the reactor/receiver tubes at high temperatures under variable and uncontinuous characteristics of solar radiation. In this study, we examined cyclic properties of thermal storage/discharge for Cu-Si alloy in air stream in order to evaluate a potentiality of Cu-Si alloy as a PCM thermal storage material. Temperature-increasing performances of Cu-Si alloy are measured during thermal storage (or heat-charge) mode and during cooling (or heat-discharge) mode. A oxidation state of the Cu-Si alloy after the cyclic reaction was evaluated by using electron probe micro analyzer (EPMA).
Aquifer thermal energy storage. International symposium: Proceedings
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
1995-05-01
Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste ormore » by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.« less
NASA Technical Reports Server (NTRS)
Denson, J. R.; Toy, A.
1974-01-01
Compatibility data for aluminum alloy 2219-T87 and titanium alloy Ti-6Al-4V were obtained while these alloys were exposed to both liquid and vapor fluorine and FLOX at -320 F + or -10 F. These data were obtained using a new low cost compatibility method which incorporates totally sealed containers and double dogbone test specimens and propellants in the simultaneous exposure to vapor and liquid phases. The compatibility investigation covered a storage period in excess of one year. Pitting was more severe in the 2219-T87 aluminum alloy than in the Ti-6Al-4V titanium alloy for both fluorine and FLOX exposure. The degree of chemical attack is more severe in the presence of FLOX than in fluorine and phase. The mechanical properties of the two alloys were not affected by storage in either of the two propellants.
A Universal Organic Cathode for Ultrafast Lithium- and Multivalent Metal Batteries.
Fan, Xiulin; Wang, Fei; Ji, Xiao; Wang, Ruixing; Gao, Tao; Hou, Singyuk; Chen, Ji; Deng, Tao; Li, Xiaogang; Chen, Long; Luo, Chao; Wang, Luning; Wang, Chunsheng
2018-04-27
Low-cost multivalent battery chemistries (Mg 2+ , Al 3+ ) have been extensively investigated for large-scale energy storage applications. However, their commercialization is plagued by the poor power density and cycle life of cathodes. A universal polyimides@CNT (PI@CNT) cathode is now presented that can reversibly store various cations with different valences (Li + , Mg 2+ , Al 3+ ) at an extremely fast rate. The ion-coordination charge storage mechanism of PI@CNT is systemically investigated. Full cells using PI@CNT cathodes and corresponding metal anodes exhibit long cycle life (>10000 cycles), fast kinetics (>20 C), and wide operating temperature range (-40 to 50 °C), making the low-cost industrial polyimides universal cathodes for different multivalent metal batteries. The stable ion-coordinated mechanism opens a new foundation for the development of high-energy and high-power multivalent batteries. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Optical classification of 8 INTEGRAL sources
NASA Astrophysics Data System (ADS)
Masetti, N.; Morelli, L.; Palazzi, E.; Stephen, J.; Bazzano, A.; Dean, A. J.; Walter, R.; Minniti, D.
2006-03-01
On 20-22 March 2006 we used the R-C spectrograph of the CTIO 1.5m telescope in Cerro Tololo (Chile) to get optical spectra of the putative counterparts of 8 X-ray sources discovered by INTEGRAL (see Bird et al. 2006, ApJ, 636, 765; Halpern 2005, ATel #572; Kuiper et al. 2006, ATel #684; Sazonov et al. 2005, A&A, 444, L37; Revnivtsev et al. 2006, Astron. Lett., 32, 145).