40 CFR 464.25 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting... Maximum for monthly average kg/1000 kkg (pounds per million pounds) of metal poured Copper (T) 0.0307 0... any 1 day Maximum for monthly average kg/1,000 kkg (pounds per million pounds) of metal poured Copper...

40 CFR 415.361 - Specialized definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... AND STANDARDS INORGANIC CHEMICALS MANUFACTURING POINT SOURCE CATEGORY Copper Salts Production... shall apply to this subpart. (b) The term product shall mean copper salts. (c) The term copper shall mean the total copper present in the process wastewater stream exiting the wastewater treatment system...

40 CFR 415.361 - Specialized definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... AND STANDARDS INORGANIC CHEMICALS MANUFACTURING POINT SOURCE CATEGORY Copper Salts Production... shall apply to this subpart. (b) The term product shall mean copper salts. (c) The term copper shall mean the total copper present in the process wastewater stream exiting the wastewater treatment system...

40 CFR 421.50 - Applicability: Description of the primary electrolytic copper refining subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... primary electrolytic copper refining subcategory. 421.50 Section 421.50 Protection of Environment... POINT SOURCE CATEGORY Primary Electrolytic Copper Refining Subcategory § 421.50 Applicability: Description of the primary electrolytic copper refining subcategory. The provisions of this subpart apply to...

40 CFR 421.50 - Applicability: Description of the primary electrolytic copper refining subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... primary electrolytic copper refining subcategory. 421.50 Section 421.50 Protection of Environment... POINT SOURCE CATEGORY Primary Electrolytic Copper Refining Subcategory § 421.50 Applicability: Description of the primary electrolytic copper refining subcategory. The provisions of this subpart apply to...

40 CFR 421.41 - Specialized definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting Subcategory § 421.41... waste streams covered by Subparts E—Primary Electrolytic Copper Refining and/or Subpart I—Metallurgical...

40 CFR 421.41 - Specialized definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting Subcategory § 421.41... waste streams covered by Subparts E—Primary Electrolytic Copper Refining and/or Subpart I—Metallurgical...

40 CFR 464.26 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting Subcategory § 464.26... million pounds) of metal poured Copper (T) 0.0307 0.0168 Lead (T) 0.0211 0.0104 Zinc (T) 0.0303 0.0116 TTO... kkg (pounds per million pounds) of metal poured Copper (T) 0.928 0.506 Lead (T) 0.639 0.314 Zinc (T) 0...

40 CFR 415.360 - Applicability; description of the copper salts production subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Applicability; description of the copper salts production subcategory. 415.360 Section 415.360 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS INORGANIC CHEMICALS MANUFACTURING POINT SOURCE CATEGORY Copper Salts Production...

40 CFR 464.23 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting... copper, lead, zinc, and total phenols. For non-continuous discharges, annual average mass limitations and... for monthly average kg/1,000 kkg (pounds per million pounds) of metal poured Copper (T) 0.0307 .0168...

40 CFR 464.23 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting... copper, lead, zinc, and total phenols. For non-continuous discharges, annual average mass limitations and... for monthly average kg/1,000 kkg (pounds per million pounds) of metal poured Copper (T) 0.0307 .0168...

40 CFR 437.16 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS THE CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY Metals Treatment... standards: Standards for antimony, arsenic, cadmium, chromium, cobalt, copper, lead, mercury, nickel, silver...

40 CFR 437.15 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS THE CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY Metals Treatment..., cadmium, chromium, cobalt, copper, lead, mercury, nickel, silver, tin, titanium, vanadium, and zinc are...

40 CFR 464.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Zinc Casting Subcategory § 464.46... million pounds) of metal poured Copper (T) 0.0344 0.0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 TTO... million pounds) of metal poured Copper (T) 0.0066 0.0036 Lead (T) 0.0046 0.0022 Zinc (T) 0.0066 0.0025...

40 CFR 464.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Zinc Casting Subcategory § 464.46... million pounds) of metal poured Copper (T) 0.0344 0.0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 TTO... million pounds) of metal poured Copper (T) 0.0066 0.0036 Lead (T) 0.0046 0.0022 Zinc (T) 0.0066 0.0025...

40 CFR 421.66 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources... GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper Subcategory...

40 CFR 421.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources... GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting...

40 CFR 421.44 - Standards of performance for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Standards of performance for new sources. 421.44 Section 421.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper...

40 CFR 466.43 - New source performance standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false New source performance standards. 466.43 Section 466.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory § 466.43...

40 CFR 421.64 - Standards of performance for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Standards of performance for new sources. 421.64 Section 421.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper...

40 CFR 466.43 - New source performance standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false New source performance standards. 466.43 Section 466.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory § 466.43...

40 CFR 421.64 - Standards of performance for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Standards of performance for new sources. 421.64 Section 421.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper...

40 CFR 421.44 - Standards of performance for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Standards of performance for new sources. 421.44 Section 421.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper...

40 CFR 415.364 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for existing... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS INORGANIC CHEMICALS MANUFACTURING POINT SOURCE CATEGORY Copper Salts Production Subcategory § 415.364 Pretreatment standards for existing sources (PSES). (a) Except as...

40 CFR 466.45 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Pretreatment standards for new sources. 466.45 Section 466.45 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory § 466.45...

40 CFR 466.45 - Pretreatment standards for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Pretreatment standards for new sources. 466.45 Section 466.45 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory § 466.45...

40 CFR 464.25 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting... existing sources. (a) Casting Quench Operations. PSES Pollutant or pollutant property Maximum for any 1 day... monitoring) 1.2 0.399 (b) Direct Chill Casting Operations. PSES Pollutant or pollutant property Maximum for...

40 CFR 437.14 - New source performance standards (NSPS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... GUIDELINES AND STANDARDS THE CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY Metals Treatment and Recovery....0522 Cobalt 0.182 0.0703 Copper 0.659 0.216 Lead 1.32 0.283 Mercury 0.000641 0.000246 Nickel 0.794 0...

40 CFR 421.84 - Standards of performance for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Zinc... achieve the following new source performance standards: (a) Subpart H—Zinc Reduction Furnace Wet Air.../kg (pounds per million pounds) of zinc reduced Cadmium .334 .134 Copper 2.135 1.018 Lead .467 .217...

40 CFR 464.26 - Pretreatment standards for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting Subcategory § 464.26... and achieve the following pretreatment standards for new sources. (a) Casting Quench Operations. PSNS... 0.0335 0.0109 Oil and grease (for alternate monitoring) 1.2 0.399 (b) Direct Chill Casting...

40 CFR 464.42 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Zinc... for copper, lead, zinc, total phenols, oil and grease, and TSS. For non-continuous dischargers, annual... metal poured Copper (T) 0.0344 0.0187 Lead (T) 0.0353 0.0174 Zinc (T) 0.0509 0.0192 Oil and grease 1.34...

40 CFR 464.42 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Zinc... for copper, lead, zinc, total phenols, oil and grease, and TSS. For non-continuous dischargers, annual... metal poured Copper (T) 0.0344 0.0187 Lead (T) 0.0353 0.0174 Zinc (T) 0.0509 0.0192 Oil and grease 1.34...

40 CFR 471.75 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... CATEGORY Uranium Forming Subcategory § 471.75 Pretreatment standards for new sources (PSNS). Except as... standards for new sources (PSNS). The mass of wastewater pollutants in uranium forming process wastewater... (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0.003 Chromium 0.013 0.005 Copper 0.044...

40 CFR 471.75 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... CATEGORY Uranium Forming Subcategory § 471.75 Pretreatment standards for new sources (PSNS). Except as... standards for new sources (PSNS). The mass of wastewater pollutants in uranium forming process wastewater... (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0.003 Chromium 0.013 0.005 Copper 0.044...

40 CFR 471.75 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... CATEGORY Uranium Forming Subcategory § 471.75 Pretreatment standards for new sources (PSNS). Except as... standards for new sources (PSNS). The mass of wastewater pollutants in uranium forming process wastewater... (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0.003 Chromium 0.013 0.005 Copper 0.044...

40 CFR 461.34 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2012 CFR

2012-07-01

...) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory....039 0.021 Lead 0.008 0.004 (4) Subpart C—Battery Wash—(Detergent)—PSES. Pollutant or pollutant... in trucked batteries English units—pounds per 1,000,000 pounds of lead in trucked batteries Copper 0...

40 CFR 461.34 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2013 CFR

2013-07-01

...) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory....039 0.021 Lead 0.008 0.004 (4) Subpart C—Battery Wash—(Detergent)—PSES. Pollutant or pollutant... in trucked batteries English units—pounds per 1,000,000 pounds of lead in trucked batteries Copper 0...

40 CFR 461.34 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2014 CFR

2014-07-01

...) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory....039 0.021 Lead 0.008 0.004 (4) Subpart C—Battery Wash—(Detergent)—PSES. Pollutant or pollutant... in trucked batteries English units—pounds per 1,000,000 pounds of lead in trucked batteries Copper 0...

40 CFR 440.105 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2012 CFR

2012-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum Ores Subcategory § 440.105 Effluent limitations...

40 CFR 440.105 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2014 CFR

2014-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum Ores Subcategory § 440.105 Effluent limitations...

40 CFR 440.105 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2013 CFR

2013-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum Ores Subcategory § 440.105 Effluent limitations...

40 CFR 440.105 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2011 CFR

2011-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum Ores Subcategory § 440.105 Effluent limitations representing...

40 CFR 421.67 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true [Reserved] 421.67 Section 421.67 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper Subcategory § 421.67 [Reserved] ...

40 CFR 466.44 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false [Reserved] 466.44 Section 466.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory § 466.44 [Reserved] ...

40 CFR 421.55 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true [Reserved] 421.55 Section 421.55 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Electrolytic Copper Refining Subcategory § 421...

40 CFR 421.57 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true [Reserved] 421.57 Section 421.57 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Electrolytic Copper Refining Subcategory § 421...

40 CFR 466.44 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false [Reserved] 466.44 Section 466.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory § 466.44 [Reserved] ...

40 CFR 421.67 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true [Reserved] 421.67 Section 421.67 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper Subcategory § 421.67 [Reserved] ...

40 CFR 421.57 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true [Reserved] 421.57 Section 421.57 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Electrolytic Copper Refining Subcategory § 421...

40 CFR 421.55 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true [Reserved] 421.55 Section 421.55 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Electrolytic Copper Refining Subcategory § 421...

40 CFR 440.101 - [Reserved

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 31 2013-07-01 2013-07-01 false [Reserved] 440.101 Section 440.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum...

40 CFR 440.101 - [Reserved

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 31 2012-07-01 2012-07-01 false [Reserved] 440.101 Section 440.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum...

40 CFR 440.101 - [Reserved

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 30 2014-07-01 2014-07-01 false [Reserved] 440.101 Section 440.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum...

40 CFR 421.61 - Specialized definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Specialized definitions. 421.61 Section 421.61 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper Subcategory § 421.61...

40 CFR 421.47 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true [Reserved] 421.47 Section 421.47 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting Subcategory § 421.47 [Reserved] ...

40 CFR 421.61 - Specialized definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Specialized definitions. 421.61 Section 421.61 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Secondary Copper Subcategory § 421.61...

40 CFR 421.47 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true [Reserved] 421.47 Section 421.47 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting Subcategory § 421.47 [Reserved] ...

40 CFR 421.45 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true [Reserved] 421.45 Section 421.45 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting Subcategory § 421.45 [Reserved] ...

40 CFR 421.45 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true [Reserved] 421.45 Section 421.45 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS NONFERROUS METALS MANUFACTURING POINT SOURCE CATEGORY Primary Copper Smelting Subcategory § 421.45 [Reserved] ...

40 CFR 63.11158 - What definitions apply to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

...? 63.11158 Section 63.11158 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Secondary Copper Smelting Area...

40 CFR 63.11158 - What definitions apply to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

...? 63.11158 Section 63.11158 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Secondary Copper Smelting Area...

40 CFR 63.11158 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

...? 63.11158 Section 63.11158 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Secondary Copper Smelting Area...

40 CFR 440.101 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false [Reserved] 440.101 Section 440.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum Ores...

40 CFR 440.101 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false [Reserved] 440.101 Section 440.101 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper, Lead, Zinc, Gold, Silver, and Molybdenum Ores...

40 CFR 63.1454 - What notifications must I submit and when?

Code of Federal Regulations, 2011 CFR

2011-07-01

... when? 63.1454 Section 63.1454 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting Notifications, Reports...

40 CFR 437.14 - New source performance standards (NSPS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... GUIDELINES AND STANDARDS THE CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY Metals Treatment and Recovery....3 Metal Parameters Antimony 0.111 0.0312 Arsenic 0.0993 0.0199 Cadmium 0.782 0.163 Chromium 0.167 0.0522 Cobalt 0.182 0.0703 Copper 0.659 0.216 Lead 1.32 0.283 Mercury 0.000641 0.000246 Nickel 0.794 0...

40 CFR 461.35 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory § 461.35...—pounds per 1,000,000 pounds of lead used Copper 0.026 0.012 Lead 0.005 0.002 (4) Subpart C—Battery Wash... Maximum for monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000...

77 FR 41075 - Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-12

..., and Sulfur Recovery Units. VVV Publicly Owned X X X X Treatment Works. XXX Ferroalloys X X X X... Ceramics X X X X Manufacturing. LLLLL Asphalt Roofing X X X X and Processing. MMMMM Flexible X X X X... Source X Standards for Aluminum, Copper, and Other Nonferrous Foundries. AAAAAAA Asphalt X Processing and...

40 CFR 461.35 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

...) EFFLUENT GUIDELINES AND STANDARDS BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory § 461.35...—pounds per 1,000,000 pounds of lead used Copper 0.026 0.012 Lead 0.005 0.002 (4) Subpart C—Battery Wash... Maximum for monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000...

40 CFR 466.41-466.42 - [Reserved

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false [Reserved] 466.41-466.42 Section 466.41-466.42 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory §§ 466.41...

40 CFR 468.03 - Monitoring and reporting requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Monitoring and reporting requirements. 468.03 Section 468.03 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS COPPER FORMING POINT SOURCE CATEGORY General Provisions § 468.03 Monitoring and...

40 CFR 466.41-466.42 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false [Reserved] 466.41-466.42 Section 466.41-466.42 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PORCELAIN ENAMELING POINT SOURCE CATEGORY Copper Basis Material Subcategory §§ 466.41...

40 CFR 468.04 - Compliance date for PSES.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Compliance date for PSES. 468.04 Section 468.04 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS COPPER FORMING POINT SOURCE CATEGORY General Provisions § 468.04 Compliance date for...

40 CFR 63.1456 - What records must I keep and how long must I keep my records?

Code of Federal Regulations, 2011 CFR

2011-07-01

... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting... affiliation for each indoor process monitor participating in the performance test; (v) Copies of all visible...

40 CFR 63.1456 - What records must I keep and how long must I keep my records?

Code of Federal Regulations, 2010 CFR

2010-07-01

... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting... affiliation for each indoor process monitor participating in the performance test; (v) Copies of all visible...

40 CFR 63.1453 - How do I demonstrate continuous compliance with the emission limitations, work practice standards...

Code of Federal Regulations, 2011 CFR

2011-07-01

... compliance with the emission limitations, work practice standards, and operation and maintenance requirements... (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting Continuous...

40 CFR 63.1453 - How do I demonstrate continuous compliance with the emission limitations, work practice standards...

Code of Federal Regulations, 2013 CFR

2013-07-01

... compliance with the emission limitations, work practice standards, and operation and maintenance requirements... (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting...

40 CFR 63.1455 - What reports must I submit and when?

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting Notifications, Reports and Records § 63... 40 Protection of Environment 12 2011-07-01 2009-07-01 true What reports must I submit and when? 63...

40 CFR 440.105 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS ORE MINING AND DRESSING POINT SOURCE CATEGORY Copper...

40 CFR 464.43 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Zinc Casting... copper, lead, zinc, and total phenols. For non-continuous dischargers, annual average mass limitations....0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 Maximum for any 1 day Maximum for monthly average...

40 CFR 464.43 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Zinc Casting... copper, lead, zinc, and total phenols. For non-continuous dischargers, annual average mass limitations....0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 Maximum for any 1 day Maximum for monthly average...

40 CFR 421.60 - Applicability: Description of the secondary copper subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... secondary copper subcategory. 421.60 Section 421.60 Protection of Environment ENVIRONMENTAL PROTECTION... CATEGORY Secondary Copper Subcategory § 421.60 Applicability: Description of the secondary copper..., processing, and remelting of new and used copper scrap and residues to produce copper metal and copper alloys...

40 CFR 421.60 - Applicability: Description of the secondary copper subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... secondary copper subcategory. 421.60 Section 421.60 Protection of Environment ENVIRONMENTAL PROTECTION... CATEGORY Secondary Copper Subcategory § 421.60 Applicability: Description of the secondary copper..., processing, and remelting of new and used copper scrap and residues to produce copper metal and copper alloys...

40 CFR 461.32 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2012 CFR

2012-07-01

...) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory... lead used Copper 0.039 0.021 Lead 0.008 0.004 Iron 0.030 0.010 (4) Subpart C—Battery Wash (Detergent... Maximum for monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000...

40 CFR 461.32 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2014 CFR

2014-07-01

...) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory... lead used Copper 0.039 0.021 Lead 0.008 0.004 Iron 0.030 0.010 (4) Subpart C—Battery Wash (Detergent... Maximum for monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000...

40 CFR 461.32 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2013 CFR

2013-07-01

...) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory... lead used Copper 0.039 0.021 Lead 0.008 0.004 Iron 0.030 0.010 (4) Subpart C—Battery Wash (Detergent... Maximum for monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000...

40 CFR Figure 1 to Subpart Qqq of... - Data Summary Sheet for Determination of Average Opacity

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Data Summary Sheet for Determination of... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Primary Copper Smelting Pt. 63, Subpt. QQQ, Fig. 1 Figure 1 to Subpart QQQ of Part 63—Data Summary Sheet for Determination of...

40 CFR 461.32 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory § 461.32... Copper 0.039 0.021 Lead 0.008 0.004 Iron 0.030 0.010 (4) Subpart C—Battery Wash (Detergent). BAT Effluent... monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000,000 pounds...

40 CFR 461.32 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2011 CFR

2011-07-01

...) EFFLUENT GUIDELINES AND STANDARDS BATTERY MANUFACTURING POINT SOURCE CATEGORY Lead Subcategory § 461.32... Copper 0.039 0.021 Lead 0.008 0.004 Iron 0.030 0.010 (4) Subpart C—Battery Wash (Detergent). BAT Effluent... monthly average Metric units—mg/kg of lead in trucked batteries English units—pounds per 1,000,000 pounds...

40 CFR 437.11 - Effluent limitations attainable by the application of the best practicable control technology...

Code of Federal Regulations, 2010 CFR

2010-07-01

... CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY Metals Treatment and Recovery § 437.11 Effluent limitations... (2) (2) TSS 60.0 31.0 Metal Parameters Antimony 0.249 0.206 Arsenic 0.162 0.104 Cadmium 0.474 0.0962 Chromium 15.5 3.07 Cobalt 0.192 0.124 Copper 4.14 1.06 Lead 1.32 0.283 Mercury 0.00234 0.000739 Nickel 3.95...

40 CFR 471.71 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2012 CFR

2012-07-01

... SOURCE CATEGORY Uranium Forming Subcategory § 471.71 Effluent limitations representing the degree of... off-pounds) of uranium extruded Cadium 0.117 0.052 Chromium 0.152 0.062 Copper 0.654 0.344 Lead 0.145 0.069 Nickel 0.661 0.437 Fluoride 20.5 9.08 Molybdenum 2.28 1.18 Oil and grease 6.88 4.13 TSS 14.1 6...

40 CFR 471.71 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2014 CFR

2014-07-01

... SOURCE CATEGORY Uranium Forming Subcategory § 471.71 Effluent limitations representing the degree of... off-pounds) of uranium extruded Cadium 0.117 0.052 Chromium 0.152 0.062 Copper 0.654 0.344 Lead 0.145 0.069 Nickel 0.661 0.437 Fluoride 20.5 9.08 Molybdenum 2.28 1.18 Oil and grease 6.88 4.13 TSS 14.1 6...

40 CFR 471.71 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2013 CFR

2013-07-01

... SOURCE CATEGORY Uranium Forming Subcategory § 471.71 Effluent limitations representing the degree of... off-pounds) of uranium extruded Cadium 0.117 0.052 Chromium 0.152 0.062 Copper 0.654 0.344 Lead 0.145 0.069 Nickel 0.661 0.437 Fluoride 20.5 9.08 Molybdenum 2.28 1.18 Oil and grease 6.88 4.13 TSS 14.1 6...

Basewide Groundwater Operable Unit. Groundwater Operable Unit Remedial Investigation/Feasibility Study Report. Volume 2

DTIC Science & Technology

1994-06-01

Boron -- - .- Cadmium (3.9) (1.1) 1.4a,c 0 .55a.b Chromium , Hexavalent (16) lid _______ Chromium , Trivalent 1,700 21016li Cobalt -- -- .- Copper (18...same time period as those for VOCs should be used, if possible. Response: Four figures have been prepared showing the lead, nickel, chromium , manganese...equipment proposed at the GWTP, and the only NSPS source category that might be considered applicable to the existing thermal fume incinerator is Subpart E

40 CFR 415.364 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2012 CFR

2012-07-01

... sulfate, copper chloride, copper iodide, or copper nitrate which introduces pollutants into a publicly... for existing sources (PSES): Subpart AJ—Copper Sulfate, Copper Chloride, Copper Iodide, Copper Nitrate...

40 CFR 415.364 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... sulfate, copper chloride, copper iodide, or copper nitrate which introduces pollutants into a publicly... for existing sources (PSES): Subpart AJ—Copper Sulfate, Copper Chloride, Copper Iodide, Copper Nitrate...

40 CFR 415.364 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2014 CFR

2014-07-01

... sulfate, copper chloride, copper iodide, or copper nitrate which introduces pollutants into a publicly... for existing sources (PSES): Subpart AJ—Copper Sulfate, Copper Chloride, Copper Iodide, Copper Nitrate...

40 CFR 415.364 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

... sulfate, copper chloride, copper iodide, or copper nitrate which introduces pollutants into a publicly... for existing sources (PSES): Subpart AJ—Copper Sulfate, Copper Chloride, Copper Iodide, Copper Nitrate...

The Nature and Use of Copper Reserve and Resource Data

USGS Publications Warehouse

Cox, Dennis P.; Wright, Nancy A.; Coakley, George J.

1981-01-01

Copper reserve, resource, and production data can be combined to produce disaggregated resource estimates and trends and, when combined with demand forecasts, can be used to predict future exploration and development requirements. Reserve estimates are subject to uncertainties due mainly to incomplete exploration and rapidly changing economic conditions. United States' reserve estimates in the past have been low mainly because knowledge of the magnitude of very large porphyry-copper deposits has been incomplete. Present estimates are considerably more reliable because mining firms tend to drill out deposits fully before mining and to release their reserve estimates to the public. The sum of reserves and past production yields an estimate of the total ore, total metal contained in ore, and average grade of ore originally in each of the deposits known in the United States. For most deposits, estimates of total copper in ore are low relative to the total copper in mineralized rock, and many estimates are strongly affected by the economic behavior of mining firms. A better estimate of the real distribution of copper contained in deposits can be obtained by combining past production data with resource estimates. Copper resource data are disaggregated into categories that include resources in undeveloped deposits similar to those mined in the past, resources in mines closed because of unfavorable economic conditions, resources in deep deposits requiring high-cost mining methods, arid resources in deposits located in areas where environmental restrictions have contributed to delays in development. The largest resource is located in the five largest porphyry deposits. These deposits are now being mined but the resources are not included in the present mining plan. Resources in this last category will not contribute to supply until some future time when ores presently being mined are depleted. A high correlation exists between total copper contained in deposits and annual production from deposits. This correlation can be used to predict roughly the potential production from undeveloped deposits. Large deposits annually produce relatively less metal per ton of copper contained than do medium and small deposits. Dividing reserves by annual production gives a depletion date for each copper mine. The sum of annual production capacity of all mines not yet depleted at any year of interest gives the minimum production capacity for that year. A graph of minimum production capacity by year combined with curves representing potential capacity from undeveloped identified resources can be compared with various demand scenarios to yield a measure of copper requirements from new sources. Since 1950 reserves have been developed in the United States at a rate of about 1 million tons of copper per year. Since 1960 the number of deposits developed per 10-year period has greatly increased without a commensurate increase in tonnage of copper. This is in part due to the fact that recent exploration successes have been increasingly represented by smaller and (or) lower grade deposits containing less metal.

40 CFR 421.52 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORY Primary Electrolytic Copper Refining Subcategory § 421.52 Effluent limitations guidelines...,000 lb of product) Total suspended solids 0.100 0.050 Copper 0.0017 0.0008 Cadmium 0.00006 0.00003...

40 CFR 421.52 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORY Primary Electrolytic Copper Refining Subcategory § 421.52 Effluent limitations guidelines...,000 lb of product) Total suspended solids 0.100 0.050 Copper 0.0017 0.0008 Cadmium 0.00006 0.00003...

40 CFR 63.11147 - What are the standards and compliance requirements for existing sources not using batch copper...

Code of Federal Regulations, 2010 CFR

2010-07-01

... requirements for existing sources not using batch copper converters? 63.11147 Section 63.11147 Protection of... Hazardous Air Pollutants for Primary Copper Smelting Area Sources Standards and Compliance Requirements § 63.11147 What are the standards and compliance requirements for existing sources not using batch copper...

40 CFR 63.11147 - What are the standards and compliance requirements for existing sources not using batch copper...

Code of Federal Regulations, 2011 CFR

2011-07-01

... requirements for existing sources not using batch copper converters? 63.11147 Section 63.11147 Protection of... Hazardous Air Pollutants for Primary Copper Smelting Area Sources Standards and Compliance Requirements § 63.11147 What are the standards and compliance requirements for existing sources not using batch copper...

40 CFR Table 1 to Subpart Zzzzzz... - Applicability of General Provisions to Aluminum, Copper, and Other Nonferrous Foundries Area Sources

Code of Federal Regulations, 2010 CFR

2010-07-01

... Aluminum, Copper, and Other Nonferrous Foundries Area Sources 1 Table 1 to Subpart ZZZZZZ of Part 63... Standards for Hazardous Air Pollutants: Area Source Standards for Aluminum, Copper, and Other Nonferrous... Provisions to Aluminum, Copper, and Other Nonferrous Foundries Area Sources As required in § 63.11555, “What...

40 CFR Table 1 to Subpart Zzzzzz... - Applicability of General Provisions to Aluminum, Copper, and Other Nonferrous Foundries Area Sources

Code of Federal Regulations, 2011 CFR

2011-07-01

... Aluminum, Copper, and Other Nonferrous Foundries Area Sources 1 Table 1 to Subpart ZZZZZZ of Part 63... Standards for Hazardous Air Pollutants: Area Source Standards for Aluminum, Copper, and Other Nonferrous... Provisions to Aluminum, Copper, and Other Nonferrous Foundries Area Sources As required in § 63.11555, “What...

Fluoride Alters Serum Elemental (Calcium, Magnesium, Copper, and Zinc) Homeostasis Along with Erythrocyte Carbonic Anhydrase Activity in Fluorosis Endemic Villages and Restores on Supply of Safe Drinking Water in School-Going Children of Nalgonda District, India.

PubMed

Khandare, Arjun L; Validandi, Vakdevi; Boiroju, Naveen

2018-02-17

The present study aimed to determine the serum trace elements (copper (Cu), zinc (Zn), calcium (Ca), magnesium (Mg)) along with erythrocyte carbonic anhydrase (CA) activity and effect of intervention with safe drinking water for 5 years in the school children of fluorosis endemic area. For this purpose, three categories of villages were selected based on drinking water fluoride (F): Category I (control, F = 1.68 mg/L), category II (affected F = 3.77 mg/L), and category III (intervention village) where initial drinking water F was 4.51 mg/L, and since the last 5 years, they were drinking water containing < 1.0 mg/L F. The results revealed that urinary F was significantly (P < 0.05) higher in category II compared to categories I and III. A significant (P < 0.05) increase in serum Cu and Mg was observed in category II compared to category I. Serum Zn and Ca was significantly (P < 0.05) decreased in categories II and III compared to category I. The erythrocyte CA activity was decreased in the category II compared to category I. However, in the category III, erythrocyte CA activity was comparable to the control group. In conclusion, F exposure altered elemental homeostasis which has restored to some extent on intervention by safe drinking water for 5 years in school-going children.

Speciation of heavy metals Cu, Ni and Zn by modified BCR sequential extraction procedure in sediments from Banten Bay, Banten Province, Indonesia

NASA Astrophysics Data System (ADS)

Lestari; Budiyanto, F.; Hindarti, D.

2018-02-01

Banten Bay is categorized as a marine area that is busy with marine tourism activities, settlements and also industries. One potential impact of the condition is the occurrence of pollution from both industrial and domestic sources, erosion and sedimentation in the coastal environment. Samples were collected from 25 representative stations in April 2016. Chemical speciation of three heavy metals (Cu, Ni, and Zn) was studied using a modified sequential extraction procedure proposed by the European Standard, Measurements and Testing (SM&T) program, formerly the Community Bureau of Reference (BCR). The aims of this study are to determine geochemical speciation of 4 bounds of metal: acid-soluble, reducible, oxidizable and residual, and to assess their impacts in the sediments of Banten Bay, Indonesia. The result shows that the percentage of Copper (45.90-83.75%), Nickel (18.28-65.66%), and Zinc (30.45-79.51%) were mostly accumulated in residual fraction of the total concentrations. The Risk Assessment Code (RAC) reveals that about 0-7.07% of Copper and 1.11-24.35 % of Zinc at sites exist in exchangeable fraction and therefore, they are in low risk category. While 7.34-34.90 of Ni at sites exists in exchangeable fraction and therefore, it is in medium risk category to aquatic environment.

Investigation of reliability attributes and accelerated stress factors on terrestrial solar cells

NASA Technical Reports Server (NTRS)

Lathrop, J. W.

1982-01-01

The accelerated stress test results obtained on all terrestrial solar cells since the inception of the program are summarized. Tested cells were grouped according to the method used to form the conductive metallization layer: solder dipped, vacuum deposited, screen printed, and copper plated. Although metallization systems within each group were quite similar, they differed in numerous details according to the procedures employed by each manufacturer. Test results were summarized for all cells according to both electrical degradation and catastrophic mechanical changes. These results indicated a variability within each metallization category which was dependent on the manufacturer. Only one manufacturer was represented in the copper plated category and, although these showed no signs of detrimental copper diffusion during high temperature testing, their metallization was removed easily during high humidity pressure cooker testing. Preliminary testing of encapsulated cells showed no major differences between encapsulated and unencapsulated cells when subjected to accelerated testing.

Copper content in lake sediments as a tracer of urban emissions: evaluation through a source-transport-storage model.

PubMed

Cui, Qing; Brandt, Nils; Sinha, Rajib; Malmström, Maria E

2010-06-01

A coupled source-transport-storage model was developed to determine the origin and path of copper from materials/goods in use in the urban drainage area and the fate of copper in local recipient lakes. The model was applied and tested using five small lakes in Stockholm, Sweden. In the case of the polluted lakes Råcksta Träsk, Trekanten and Långsjön, the source strengths of copper identified by the model were found to be well linked with independently observed copper contents in the lake sediments through the model. The model results also showed that traffic emissions, especially from brake linings, dominated the total load in all five cases. Sequential sedimentation and burial proved to be the most important fate processes of copper in all lakes, except Råcksta Träsk, where outflow dominated. The model indicated that the sediment copper content can be used as a tracer of the urban diffuse copper source strength, but that the response to changes in source strength is fairly slow (decades). Major uncertainties in the source model were related to management of stormwater in the urban area, the rate of wear of brake linings and weathering of copper roofs. The uncertainty of the coupled model is in addition affected mainly by parameters quantifying the sedimentation and bury processes, such as particulate fraction, settling velocity of particles, and sedimentation rate. As a demonstration example, we used the model to predict the response of the sediment copper level to a decrease in the copper load from the urban catchment in one of the case study lakes. Copyright (c) 2010 Elsevier B.V. All rights reserved.

Metal lost and found: dissipative uses and releases of copper in the United States 1975-2000.

PubMed

Lifset, Reid J; Eckelman, Matthew J; Harper, E M; Hausfather, Zeke; Urbina, Gonzalo

2012-02-15

Metals are used in a variety of ways, many of which lead to dissipative releases to the environment. Such releases are relevant from both a resource use and an environmental impact perspective. We present a historical analysis of copper dissipative releases in the United States from 1975 to 2000. We situate all dissipative releases in copper's life cycle and introduce a conceptual framework by which copper dissipative releases may be categorized in terms of intentionality of use and release. We interpret our results in the context of larger trends in production and consumption and government policies that have served as drivers of intentional copper releases from the relevant sources. Intentional copper releases are found to be both significant in quantity and highly variable. In 1975, for example, the largest source of intentional releases was from the application of copper-based pesticides, and this decreased more than 50% over the next 25 years; all other sources of intentional releases increased during that period. Overall, intentional copper releases decreased by approximately 15% from 1975 to 2000. Intentional uses that are unintentionally released such as copper from roofing, increased by the same percentage. Trace contaminant sources such as fossil fuel combustion, i.e., sources where both the use and the release are unintended, increased by nearly 50%. Intentional dissipative uses are equivalent to 60% of unintentional copper dissipative releases and more than five times that from trace sources. Dissipative copper releases are revealed to be modest when compared to bulk copper flows in the economy, and we introduce a metric, the dissipation index, which may be considered an economy-wide measure of resource efficiency for a particular substance. We assess the importance of dissipative releases in the calculation of recycling rates, concluding that the inclusion of dissipation in recycling rate calculations has a small, but discernible, influence, and should be included in such calculations. Copyright © 2011 Elsevier B.V. All rights reserved.

40 CFR 141.88 - Monitoring requirements for lead and copper in source water.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the basis of tap samples collected in accordance with § 141.86 shall collect lead and copper source... value or be considered one-half the PQL. (b) Monitoring frequency after system exceeds tap water action level. Any system which exceeds the lead or copper action level at the tap shall collect one source...

40 CFR 468.13 - New source performance standards (NSPS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... copper alloy hot rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy hot... for monthly average Metric units—mg/off-kg of copper or copper alloy cold rolled English units—pounds... copper or copper alloy drawn English units—pounds per 1,000,000 off-pounds of copper or copper alloy...

Effects of copper source and concentration on in vitro phytate phosphorus hydrolysis by phytase.

PubMed

Pang, Yanfang; Applegate, Todd J

2006-03-08

Five copper (Cu) sources were studied at pH 2.5, 5.5, and 6.5 to determine how Cu affects phytate phosphorus (PP) hydrolysis by phytase at concentrations up to 500 mg/kg diet (60 min, 40-41 degrees C). Subsequently, Cu solubility with and without sodium phytate was measured. Adding Cu inhibited PP hydrolysis at pH 5.5 and pH 6.5 (P < 0.05). This inhibition was greater with higher concentrations of Cu. Tri-basic copper chloride and copper lysinate inhibited PP hydrolysis much less than copper sulfate pentahydrate, copper chloride, and copper citrate (P < 0.05). A strong negative relationship was observed between PP hydrolysis and soluble Cu at pH 5.5 (r = -0.76, P < 0.0001) and 6.5 (r = -0.54, P < 0.0001). In conclusion, pH, Cu concentration, and source influenced PP hydrolysis by phytase in vitro and were related to the amount of soluble Cu and the formation of insoluble copper-phytin complexes.

40 CFR 468.14 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

... for monthly average Metric units—mg/off-kg of copper or copper alloy hot rolled English units—pounds... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.166... copper or copper alloy drawn English units—pounds per 1,000,000 off-pounds of copper or copper alloy...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2013 CFR

2013-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2012 CFR

2012-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2014 CFR

2014-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2011 CFR

2011-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR 468.15 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

...-pounds of copper or copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0.062 Lead 0.010 0.0092... English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.140 0.056... copper alloy drawn English units—pounds per 1,000,000 off-pounds of copper or copper alloy drawn Chromium...

40 CFR 468.15 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... average Metric units—mg/off-kg of copper or copper alloy hot rolled English units—pounds per 1,000,000 off... English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.140 0.056... copper alloy drawn English units—pounds per 1,000,000 off-pounds of copper or copper alloy drawn Chromium...

Loading estimates of lead, copper, cadmium, and zinc in urban runoff from specific sources.

PubMed

Davis, A P; Shokouhian, M; Ni, S

2001-08-01

Urban stormwater runoff is being recognized as a substantial source of pollutants to receiving waters. A number of investigators have found significant levels of metals in runoff from urban areas, especially in highway runoff. As an initiatory study, this work estimates lead, copper, cadmium, and zinc loadings from various sources in a developed area utilizing information available in the literature, in conjunction with controlled experimental and sampling investigations. Specific sources examined include building siding and roofs; automobile brakes, tires, and oil leakage; and wet and dry atmospheric deposition. Important sources identified are building siding for all four metals, vehicle brake emissions for copper and tire wear for zinc. Atmospheric deposition is an important source for cadmium, copper, and lead. Loadings and source distributions depend on building and automobile density assumptions and the type of materials present in the area examined. Identified important sources are targeted for future comprehensive mechanistic studies. Improved information on the metal release and distributions from the specific sources, along with detailed characterization of watershed areas will allow refinements in the predictions.

Forensic discrimination of copper wire using trace element concentrations.

PubMed

Dettman, Joshua R; Cassabaum, Alyssa A; Saunders, Christopher P; Snyder, Deanna L; Buscaglia, JoAnn

2014-08-19

Copper may be recovered as evidence in high-profile cases such as thefts and improvised explosive device incidents; comparison of copper samples from the crime scene and those associated with the subject of an investigation can provide probative associative evidence and investigative support. A solution-based inductively coupled plasma mass spectrometry method for measuring trace element concentrations in high-purity copper was developed using standard reference materials. The method was evaluated for its ability to use trace element profiles to statistically discriminate between copper samples considering the precision of the measurement and manufacturing processes. The discriminating power was estimated by comparing samples chosen on the basis of the copper refining and production process to represent the within-source (samples expected to be similar) and between-source (samples expected to be different) variability using multivariate parametric- and empirical-based data simulation models with bootstrap resampling. If the false exclusion rate is set to 5%, >90% of the copper samples can be correctly determined to originate from different sources using a parametric-based model and >87% with an empirical-based approach. These results demonstrate the potential utility of the developed method for the comparison of copper samples encountered as forensic evidence.

40 CFR 141.88 - Monitoring requirements for lead and copper in source water.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Monitoring requirements for lead and copper in source water. 141.88 Section 141.88 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Control of Lead and Copper § 141.88 Monitoring requirements for...

Copper-based nanomaterials for environmental decontamination - An overview on technical and toxicological aspects.

PubMed

Khalaj, Mohammadreza; Kamali, Mohammadreza; Khodaparast, Zahra; Jahanshahi, Akram

2018-02-01

Synthesis of the various types of engineered nanomaterials has gained a huge attention in recent years for various applications. Copper based nanomaterials are a branch of this category seem to be able to provide an efficient and cost-effective way for the treatment of the persistent effluents. The present work aimed to study the various parameters may involve in the overall performance of the copper based nanomaterials for environmental clean-up purposes. To this end, the related characteristics of copper based nanomaterials and their effects on the nanomaterials reactivity and the environmental and operating parameters have been critically reviewed. Toxicological study of the copper based nanomaterials has been also considered as a factor with high importance for the selection of a typical nanomaterial with optimum performance and minimum environmental and health subsequent effects. Copyright © 2017 Elsevier Inc. All rights reserved.

Investigation of the effects of dietary protein source on copper and zinc bioavailability in rainbow trout

USDA-ARS?s Scientific Manuscript database

Limited research has examined the effects that dietary protein sources have on copper (Cu) and Zinc (Zn) absorption, interactions and utilization in rainbow trout. Therefore, the objective of the first trial was to determine what effect protein source (plant vs. animal based), Cu source (complex vs....

40 CFR 468.13 - New source performance standards (NSPS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0.062 Lead 0.010 0.0092 Nickel 0.056 0.038 Zinc... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.140... copper or copper alloy drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0...

40 CFR 468.13 - New source performance standards (NSPS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0.062 Lead 0.010 0.0092 Nickel 0.056 0.038 Zinc... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.140... copper or copper alloy drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0...

40 CFR 468.13 - New source performance standards (NSPS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0.062 Lead 0.010 0.0092 Nickel 0.056 0.038 Zinc... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.140... copper or copper alloy drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0...

Copper economy in Chlamydomonas: Prioritized allocation and reallocation of copper to respiration vs. photosynthesis

PubMed Central

Kropat, Janette; Gallaher, Sean D.; Urzica, Eugen I.; Nakamoto, Stacie S.; Strenkert, Daniela; Tottey, Stephen; Mason, Andrew Z.; Merchant, Sabeeha S.

2015-01-01

Inorganic elements, although required only in trace amounts, permit life and primary productivity because of their functions in catalysis. Every organism has a minimal requirement of each metal based on the intracellular abundance of proteins that use inorganic cofactors, but elemental sparing mechanisms can reduce this quota. A well-studied copper-sparing mechanism that operates in microalgae faced with copper deficiency is the replacement of the abundant copper protein plastocyanin with a heme-containing substitute, cytochrome (Cyt) c6. This switch, which is dependent on a copper-sensing transcription factor, copper response regulator 1 (CRR1), dramatically reduces the copper quota. We show here that in a situation of marginal copper availability, copper is preferentially allocated from plastocyanin, whose function is dispensable, to other more critical copper-dependent enzymes like Cyt oxidase and a ferroxidase. In the absence of an extracellular source, copper allocation to Cyt oxidase includes CRR1-dependent proteolysis of plastocyanin and quantitative recycling of the copper cofactor from plastocyanin to Cyt oxidase. Transcriptome profiling identifies a gene encoding a Zn-metalloprotease, as a candidate effecting copper recycling. One reason for the retention of genes encoding both plastocyanin and Cyt c6 in algal and cyanobacterial genomes might be because plastocyanin provides a competitive advantage in copper-depleted environments as a ready source of copper. PMID:25646490

Effects of light and copper ions on volatile aldehydes of milk and milk fractions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jeno, W.; Bassette, R.; Crang, R.E.

1988-09-01

Raw, laboratory-pasteurized and plant-pasteurized homogenized milks were exposed to copper ions (5 ppm), to sunlight or fluorescent light and the effects determined on the composition of volatile aldehydes. The greatest change due to copper treatment was an increase in n-hexanal; acetaldehyde showed the least response in each of the sources of milk. The responses were similar from all three sources of milk with laboratory-pasteurized milk samples showing the greatest responses for each aldehyde analyzed. Similar milk samples exposed to sunlight also showed an increase in volatile aldehydes from all milk sources but with the greatest response being acetaldehyde and n-pentanalmore » components. The milk fraction most susceptible to changes in the presence of light was neutralized whey, whereas resuspended cream was most susceptible to copper exposure. Overall, dialyzed whey appeared to be influenced more than other milk fractions by both light and copper ions.« less

Tamil Chola Bronzes and Swamimalai Legacy: Metal Sources and Archaeotechnology

NASA Astrophysics Data System (ADS)

Srinivasan, Sharada

2016-08-01

This review explores the great copper alloy image casting traditions of southern India from archaeometallurgical and ethnometallurgical perspectives. The usefulness of lead isotope ratio and compositional analysis in the finger-printing and art historical study of more than 130 early historic, Pallava, Chola, later Chola, and Vijayanagara sculptures (fifth-eighteenth centuries) is highlighted, including Nataraja, Buddha, Parvati, and Rama images made of copper, leaded bronze, brass, and gilt copper. Image casting traditions at Swamimalai in Tamil Nadu are compared with artistic treatises and with the technical examination of medieval bronzes, throwing light on continuities and changes in foundry practices. Western Indian sources could be pinpointed for a couple of medieval images from lead isotope analysis. Slag and archaeometallurgical investigations suggest the exploitation of some copper and lead-silver sources in the Andhra and Karnataka regions in the early historic Satavahana period and point to probable copper sources for the medieval images in Karnataka, Tamil Nadu, and Andhra Pradesh. The general lower iron content in southern Indian bronzes perhaps renders the proximal copper-magnetite reserves of Seruvila in Sri Lanka as a less likely source. Given the lack of lead deposits in Sri Lanka, however, the match of the lead isotope signatures of a well-known Ceylonese Buddhist Tara in British Museum with a Buddha image from Nagapattinam in Tamil Nadu may underscore ties between the island nation and the southern Indian Tamil regions.

The Role of Grain Size on Neutron Irradiation Response of Nanocrystalline Copper

PubMed Central

Mohamed, Walid; Miller, Brandon; Porter, Douglas; Murty, Korukonda

2016-01-01

The role of grain size on the developed microstructure and mechanical properties of neutron irradiated nanocrystalline copper was investigated by comparing the radiation response of material to the conventional micrograined counterpart. Nanocrystalline (nc) and micrograined (MG) copper samples were subjected to a range of neutron exposure levels from 0.0034 to 2 dpa. At all damage levels, the response of MG-copper was governed by radiation hardening manifested by an increase in strength with accompanying ductility loss. Conversely, the response of nc-copper to neutron irradiation exhibited a dependence on the damage level. At low damage levels, grain growth was the primary response, with radiation hardening and embrittlement becoming the dominant responses with increasing damage levels. Annealing experiments revealed that grain growth in nc-copper is composed of both thermally-activated and irradiation-induced components. Tensile tests revealed minimal change in the source hardening component of the yield stress in MG-copper, while the source hardening component was found to decrease with increasing radiation exposure in nc-copper. PMID:28773270

Anthropogenic Sources of Arsenic and Copper to Sediments of a Suburban Lake, 1964-1998

NASA Astrophysics Data System (ADS)

Rice, K. C.; Conko, K. M.; Hornberger, G. M.

2002-05-01

Nonpoint-source pollution from urbanization is becoming a widespread problem. Long-term monitoring data are necessary to document geochemical processes in urban settings and changes in sources of chemical contaminants over time. In the absence of long-term data, lake-sediment cores can be used to reconstruct past processes, because they serve as integrators of sources of pollutants from the contributing airshed and catchment. Lake Anne is a 10.9-ha man-made lake in a 235-ha suburban catchment in Reston, Virginia, with a population density of 1,116 people/km2. Three sediment cores, collected in 1996 and 1997, indicate increasing concentrations of arsenic and copper since 1964, when the lake was formed. The cores were compared to a core collected from a forested catchment in the same airshed that showed no increases in concentrations of these elements. Neither an increase in atmospheric deposition nor diagenesis and remobilization were responsible for the trends in the Lake Anne cores. Mass balances of sediment, arsenic, and copper were calculated using 1998 data on precipitation, streamwater, road runoff, and a laboratory leaching experiment on pressure-treated lumber. Sources of arsenic to the lake in 1998 were in-lake leaching of pressure-treated lumber (52%) and streamwater (47%). Road runoff was a greater (93%) source of copper than leaching of pressure-treated lumber (4%). Atmospheric deposition was an insignificant source (<3%) of both elements. Urbanization of the catchment was confirmed as a major cause of the increasing arsenic and copper in the lake cores through an annual historical reconstruction of the deposition of sediment, arsenic, and copper to the lake for 1964-1997. Aerial photography indicated that the area of roads and parking lots in the catchment increased to 26% by 1997 and that the number of docks on the lake also increased over time. The increased mass of arsenic and copper in the lake sediments corresponded to the increased amount of pressure-treated lumber in the lake, and the mass of copper also corresponded to the increase in paved surfaces in the catchment.

Biogeochemical spatio-temporal transformation of copper in Aspergillus niger colonies grown on malachite with different inorganic nitrogen sources.

PubMed

Fomina, Marina; Bowen, Andrew D; Charnock, John M; Podgorsky, Valentin S; Gadd, Geoffrey M

2017-03-01

This work elucidates spatio-temporal aspects of the biogeochemical transformation of copper mobilized from malachite (Cu 2 (CO 3 )(OH) 2 ) and bioaccumulated within Aspergillus niger colonies when grown on different inorganic nitrogen sources. It was shown that the use of either ammonium or nitrate determined how copper was distributed within the colony and its microenvironment and the copper oxidation state and succession of copper coordinating ligands within the biomass. Nitrate-grown colonies yielded ∼1.7× more biomass, bioaccumulated ∼7× less copper, excreted ∼1.9× more oxalate and produced ∼1.75× less water-soluble copper in the medium in contrast to ammonium-grown colonies. Microfocus X-ray absorption spectroscopy revealed that as the mycelium matured, bioaccumulated copper was transformed from less stable and more toxic Cu(I) into less toxic Cu(II) which was coordinated predominantly by phosphate/malate ligands. With time, a shift to oxalate coordination of bioaccumulated copper occurred in the central older region of ammonium-grown colonies. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.

Copper in diet

MedlinePlus

Diet - copper ... yeast are also sources of copper in the diet. ... day 9 to 13 years: 700 mcg/day Adolescents and adults Males and ... eat a balanced diet that contains a variety of foods from the ...

Copper complexes as a source of redox active MRI contrast agents.

PubMed

Dunbar, Lynsey; Sowden, Rebecca J; Trotter, Katherine D; Taylor, Michelle K; Smith, David; Kennedy, Alan R; Reglinski, John; Spickett, Corinne M

2015-10-01

The study reports an advance in designing copper-based redox sensing MRI contrast agents. Although the data demonstrate that copper(II) complexes are not able to compete with lanthanoids species in terms of contrast, the redox-dependent switch between diamagnetic copper(I) and paramagnetic copper(II) yields a novel redox-sensitive contrast moiety with potential for reversibility.

Case study of complaints on drinking water quality: relationship to copper content?

PubMed

Pizarro, Fernando; Araya, Magdalena; Vásquez, Marcela; Lagos, Gustavo; Olivares, Manuel; Méndez, Marco A; Leyton, Bárbara; Reyes, Arturo; Letelier, Victoria; Uauy, Ricardo

2007-05-01

Several families of Talca city, Chile complained to health authorities for what they attributed to consumption of copper (Cu)-contaminated drinking water. We assessed the situation 6-12 mo after the initiation of complaints by characterizing the symptoms reported, the chemistry of drinking water, and the Cu concentration in stagnant drinking water. After completing a census, 1778 households accepted participation and were categorized as follows: category 1, Cu plumbing for tap water and dwellers reporting health complaints (HC); category 2, Cu plumbing for tap water and dwellers reporting no HC; category 3, plastic plumbing for tap water and dwellers reporting no HC. Questionnaires recorded characteristics of households and symptoms presented by each member of the family in the last 3 mo. The Cu concentration in drinking water was measured in a subsample of 80 homes with Cu pipes. In category 1, participants presented significantly more abdominal pain, diarrhea, and/or vomiting (gastrointestinal [GI] symptoms) in comparison to category 3 and to categories 2 plus 3. The stagnant Cu concentrations measured in drinking water in all houses studied were below the US Environmental Protection Agency guideline value (<1.3 mg Cu/L). In summary, data obtained by interviews suggested that individuals in some areas of Talca city were suffering more GI symptoms potentially related to Cu excess, but measurement of Cu concentration in stagnant tap waters ruled out the association between Cu exposure and GI symptom reports at the time of this study. The dose-response curves for GI symptoms and Cu exposure now available were crucial in the analyses of results.

40 CFR 468.14 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.045 0.018 Copper 0.195 0.103... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.166... drawn Chromium 0.037 0.015 Copper 0.161 0.085 Lead 0.012 0.011 Nickel 0.163 0.107 Zinc 0.124 0.051 TTO 0...

40 CFR 468.14 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2013 CFR

2013-07-01

... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.045... alloy cold rolled Chromium 0.166 0.068 Copper 0.720 0.379 Lead 0.056 0.049 Nickel 0.727 0.481 Zinc 0.553... copper or copper alloy drawn Chromium 0.037 0.015 Copper 0.161 0.085 Lead 0.012 0.011 Nickel 0.163 0.107...

40 CFR 468.14 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2014 CFR

2014-07-01

... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.045... alloy cold rolled Chromium 0.166 0.068 Copper 0.720 0.379 Lead 0.056 0.049 Nickel 0.727 0.481 Zinc 0.553... copper or copper alloy drawn Chromium 0.037 0.015 Copper 0.161 0.085 Lead 0.012 0.011 Nickel 0.163 0.107...

40 CFR 468.14 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2012 CFR

2012-07-01

... rolled English units—pounds per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.045... alloy cold rolled Chromium 0.166 0.068 Copper 0.720 0.379 Lead 0.056 0.049 Nickel 0.727 0.481 Zinc 0.553... copper or copper alloy drawn Chromium 0.037 0.015 Copper 0.161 0.085 Lead 0.012 0.011 Nickel 0.163 0.107...

Transcriptional response of Erwinia amylovora to copper shock: in vivo role of the copA gene.

PubMed

Águila-Clares, Begoña; Castiblanco, Luisa F; Quesada, José Miguel; Penyalver, Ramón; Carbonell, Juan; López, María M; Marco-Noales, Ester; Sundin, George W

2018-01-01

Fire blight is a devastating plant disease caused by the bacterium Erwinia amylovora, and its control is frequently based on the use of copper-based compounds whose mechanisms of action are not well known. Consequently, in this article, we investigate the response of E. amylovora to copper shock by a whole-genome microarray approach. Transcriptional analyses showed that, in the presence of copper, 23 genes were increased in expression; these genes were classified mainly into the transport and stress functional categories. Among them, the copA gene was strongly induced and regulated in a finely tuned manner by copper. Mutation of copA, soxS, arcB, yjcE, ygcF, yhhQ, galF and EAM_3469 genes revealed that tolerance to copper in E. amylovora can be achieved by complex physiological mechanisms, including: (i) the control of copper homeostasis through, at least, the extrusion of Cu(I) by a P-type ATPase efflux pump CopA; and (ii) the overcoming of copper toxicity caused by oxidative stress by the expression of several reactive oxygen species (ROS)-related genes, including the two major transcriptional factors SoxS and ArcB. Furthermore, complementation analyses demonstrated the important role of copA for copper tolerance in E. amylovora, not only in vitro, but also in inoculated pear shoots. © 2016 BSPP AND JOHN WILEY & SONS LTD.

Production of brown and black pigments by using flotation waste from copper slag.

PubMed

Ozel, Emel; Turan, Servet; Coruh, Semra; Ergun, Osman Nuri

2006-04-01

One of the major problems in copper-producing countries is the treatment of the large amount of copper slag or copper flotation waste generated from copper slag which contains significant amounts of heavy metals such as Cu, Zn, Pb and Co. Dumping or disposal of such large quantities of flotation waste from copper slag causes environmental and space problems. In this study, the treatment of flotation waste from copper slag by a thermal method and its use as an iron source in the production of inorganic brown and black pigments that are used in the ceramic industry were investigated. The pigments were produced by calcining different amounts of flotation waste and chromite, Cr2O3, ZnO and CoO mixtures. The pigments obtained were added to transparent ceramic glazes and porcelainized tile bodies. Their colours were defined by L*a*b* measurements with a spectrophotometer. The results showed that flotation waste from copper slag could be used as an iron source to produce brown and black pigments in both ceramic body and glazes.

Serum Copper Status in School-Age Children and Pregnant Women in China Nutrition and Health Survey 2010-2012.

PubMed

Liu, Xiaobing; Piao, Jianhua; Zhang, Yu; Li, Min; Li, Weidong; Yang, Lichen; Yang, Xiaoguang

2016-10-01

Serum copper is an insensitive but reliable biomarker reflecting the change of copper nutritional status in both depleted and replete populations. The current study aimed to establish the reference values of serum copper in school-age children and pregnant women in China and to explore the adequate range of serum copper for both these two categories of people. A multistage, stratified, random sampling combined with probability proportionate to regional size sampling method was employed. A total of 4019 subjects (2736 school-age children and 1283 pregnant women) were selected from China Nutrition and Health Survey 2010-2012 (CNHS 2010-2012). The concentration of serum copper was determined by sector field inductively coupled plasma mass spectrometry (SF-ICP-MS). The adequate range of serum copper was determined by the logistic sigmoid saturation curve of the median derivatives. The median concentration of serum copper was 1140.9 μg/L with a range of 746.7-1677.6 μg/L for school-age children and 1933.4 μg/L with a range of 947.4-3391.4 μg/L for pregnant women. The adequate range of serum copper was 905.7-1440.7 μg/L for school-age children and 1308.8-2537.8 μg/L for pregnant women. These parameters represent an essential prerequisite for the assessment of copper nutritional status, as well as nutrition interventions.

40 CFR 468.15 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2014 CFR

2014-07-01

...—pounds per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0... Chromium 0.140 0.056 Copper 0.485 0.231 Lead 0.037 0.034 Nickel 0.208 0.140 Zinc 0.386 0.159 TTO 0.128 0... copper alloy drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0.031 Zinc 0...

40 CFR 468.15 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

...—pounds per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0... Chromium 0.140 0.056 Copper 0.485 0.231 Lead 0.037 0.034 Nickel 0.208 0.140 Zinc 0.386 0.159 TTO 0.128 0... copper alloy drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0.031 Zinc 0...

40 CFR 468.15 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2012 CFR

2012-07-01

...—pounds per 1,000,000 off-pounds of copper or copper alloy hot rolled Chromium 0.038 0.015 Copper 0.131 0... Chromium 0.140 0.056 Copper 0.485 0.231 Lead 0.037 0.034 Nickel 0.208 0.140 Zinc 0.386 0.159 TTO 0.128 0... copper alloy drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0.031 Zinc 0...

Computational studies on nonlinear optical property of novel Wittig-based Schiff-base ligands and copper(II) complex

NASA Astrophysics Data System (ADS)

Rajasekhar, Bathula; Patowary, Nidarshana; K. Z., Danish; Swu, Toka

2018-07-01

Hundred and forty-five novel molecules of Wittig-based Schiff-base (WSB), including copper(II) complex and precursors, were computationally screened for nonlinear optical (NLO) properties. WSB ligands were derived from various categories of amines and aldehydes. Wittig-based precursor aldehydes, (E)-2-hydroxy-5-(4-nitrostyryl)benzaldehyde (f) and 2-hydroxy-5-((1Z,3E)-4-phenylbuta-1,3-dien-1-yl) benzaldehyde (g) were synthesised and spectroscopically confirmed. Schiff-base ligands and copper(II) complex were designed, optimised and their NLO property was studied using GAUSSIAN09 computer program. For both optimisation and hyperpolarisability (finite-field approach) calculations, Density Functional Theory (DFT)-based B3LYP method was applied with LANL2DZ basis set for metal ion and 6-31G* basis set for C, H, N, O and Cl atoms. This is the first report to present the structure-activity relationship between hyperpolarisability (β) and WSB ligands containing mono imine group. The study reveals that Schiff-base ligands of the category N-2, which are the ones derived from the precursor aldehyde, 2-hydroxy-5-(4nitro-styryl)benzaldehyde and pre-polarised WSB coordinated with Cu(II), encoded as Complex-1 (β = 14.671 × 10-30 e.s.u) showed higher β values over other categories, N-1 and N-3, i.e. WSB derived from precursor aldehydes, 2-hydroxy-5-styrylbenzaldehyde and 2-hydroxy-5-((1Z,3E)-4-phenylbuta-1,3-dien-1-yl)benzaldehyde, respectively. For the first time here we report the geometrical isomeric effect on β value.

"Twin copper source" growth of metal-organic framework membrane: Cu(3)(BTC)(2) with high permeability and selectivity for recycling H(2).

PubMed

Guo, Hailing; Zhu, Guangshan; Hewitt, Ian J; Qiu, Shilun

2009-02-11

In this communication, the copper net supported Cu(3)(BTC)(2) membranes have been successfully synthesized by means of a "twin copper source" technique. Separation studies on gaseous mixtures (H(2)/CO(2), H(2)/CH(4), and H(2)/N(2)) using the membrane revealed that the membrane possesses high permeability and selectivity for H(2) over CO(2), N(2), and CH(4). Compared with the conventional zeolite membranes, the copper net supported Cu(3)(BTC)(2) membrane exhibited high permeation flux in gas separation. Such highly efficient copper net supported Cu(3)(BTC)(2) membranes could be used to separate, recycle, and reuse H(2) exhausted from steam reforming natural gas.

Glutamate-Mediated Primary Somatosensory Cortex Excitability Correlated with Circulating Copper and Ceruloplasmin

PubMed Central

Tecchio, Franca; Assenza, Giovanni; Zappasodi, Filippo; Mariani, Stefania; Salustri, Carlo; Squitti, Rosanna

2011-01-01

Objective. To verify whether markers of metal homeostasis are related to a magnetoencephalographic index representative of glutamate-mediated excitability of the primary somatosensory cortex. The index is identified as the source strength of the earliest component (M20) of the somatosensory magnetic fields (SEFs) evoked by right median nerve stimulation at wrist. Method. Thirty healthy right-handed subjects (51 ± 22 years) were enrolled in the study. A source reconstruction algorithm was applied to assess the amount of synchronously activated neurons subtending the M20 and the following SEF component (M30), which is generated by two independent contributions of gabaergic and glutamatergic transmission. Serum copper, ceruloplasmin, iron, transferrin, transferrin saturation, and zinc levels were measured. Results. Total copper and ceruloplasmin negatively correlated with the M20 source strength. Conclusion. This pilot study suggests that higher level of body copper reserve, as marked by ceruloplasmin variations, parallels lower cortical glutamatergic responsiveness. PMID:22145081

Dietary fructose but not starch is responsible for hyperlipidemia associated with copper deficiency in rats: effect of high-fat diet.

PubMed

Fields, M; Lewis, C G

1999-02-01

To test the hypothesis that copper deficiency in rats may be hyperlipidemic only when the diets consumed contain nutrients which contribute to blood lipids such as fructose and high fat. Weanling male Sprague Dawley rats were fed diets which contained either starch or fructose as their sole carbohydrate source. The diets were either inadequate (0.6 microg Cu/g) or adequate (6.0 microg Cu/g) in copper and contained either high (300 g/kg) or low (60 g/kg) fat. At the end of the 4th week the rats were killed. Livers were analyzed for copper content. Plasma was analyzed for cholesterol and triglyceride concentrations. High-fat diet did not increase blood lipids in rats fed a copper-deficient diet containing starch. In contrast, the combination of high-fat diet with fructose increased blood triglycerides and fructose with copper deficiency resulted in a significant increases in blood cholesterol. Hyperlipidemia of copper deficiency in rats is dependent on synergistic effects between dietary fructose and copper deficiency and fructose and amount of dietary fat. Hyperlipidemia does not develop if starch is the main source of dietary carbohydrate in a copper-deficient diet even if a high-fat diet is fed.

Economic and toxicological aspects of copper industry in Katanga, DR Congo.

PubMed

Kalenga, John Ngoy

2013-02-01

The Katanga province is well known for its copper and cobalt reserves. During the early 2000s a boom of mining projects in Katanga brought again hope for better future to Congolese people. The paper aims to evaluate the impact of recent production recovery on economy and environment. We collected primary and secondary sources on copper industry for economic analysis. We use results of laboratory analysis conducted at the Congolese Office of Control by provincial division of environment for toxicological analysis. The comparison of heavy metal concentration to standards shows that mining industry is the main source of environmental pollution in Katanga. Copper industry generates income for economic growth of the region.

40 CFR 468.13 - New source performance standards (NSPS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... rolled Chromium 0.038 0.015 Copper 0.131 0.062 Lead 0.010 0.0092 Nickel 0.056 0.038 Zinc 0.105 0.043 Oil... per 1,000,000 off-pounds of copper or copper alloy cold rolled Chromium 0.140 0.056 Copper 0.485 0.231... drawn Chromium 0.031 0.012 Copper 0.108 0.051 Lead 0.0085 0.0076 Nickel 0.046 0.031 Zinc 0.086 0.035 Oil...

Method of fabricating a catalytic structure

DOEpatents

Rollins, Harry W [Idaho Falls, ID; Petkovic, Lucia M [Idaho Falls, ID; Ginosar, Daniel M [Idaho Falls, ID

2009-09-22

A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.

Temporal and spatial variations of copper, cadmium, lead, and zinc in Ten Mile Creek in South Florida, USA.

PubMed

Yang, Yuangen; He, Zhenli; Lin, Youjian; Phlips, Edward J; Stoffella, Peter J; Powell, Charles A

2009-01-01

Lead (Pb), zinc (Zn), copper (Cu), and cadmium (Cd) often seriously deteriorate water quality. Spatial and temporal fluctuations of the metal concentrations in the Ten Mile Creek (Florida) (TMC) were monitored on a weekly basis at 7 sampling sites, from June 2005 to September 2007. River sediment samples were also collected from these sites in April, June, and October 2006 and January 2007, and analyzed for water, Mehlich 1 (M1), and Mehlich 3 (M3)-extractable metals (Mehlich, 1953, 1984), to examine the role of sediments as sources or sinks of the metals. The concentrations of lead, zinc, copper, and cadmium in the water samples were

78 FR 15947 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Comment...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-13

... Chloride and Copolymer Production, Primary Copper Smelting, Secondary Copper Smelting, and Primary... www.regulations.gov . Title: NESHAP for Area Sources: Polyvinyl Chloride and Copolymer Production.... Respondents/Affected Entities: Owners or operators of polyvinyl chloride and copolymer, primary copper smelter...

Porphyry copper deposit model: Chapter B in Mineral deposit models for resource assessment

USGS Publications Warehouse

Ayuso, Robert A.; Barton, Mark D.; Blakely, Richard J.; Bodnar, Robert J.; Dilles, John H.; Gray, Floyd; Graybeal, Fred T.; Mars, John L.; McPhee, Darcy K.; Seal, Robert R.; Taylor, Ryan D.; Vikre, Peter G.; John, David A.

2010-01-01

This report contains a revised descriptive model of porphyry copper deposits (PCDs), the world's largest source (about 60 percent) and resource (about 65 percent) of copper and a major source of molybdenum, gold and silver. Despite relatively low grades (average 0.44 percent copper in 2008), PCDs have significant economic and societal impacts due to their large size (commonly hundreds of millions to billions of metric tons), long mine lives (decades), and high production rates (billions of kilograms of copper per year). The revised model describes the geotectonic setting of PCDs, and provides extensive regional- to deposit-scale descriptions and illustrations of geological, geochemical, geophysical, and geoenvironmental characteristics. Current genetic theories are reviewed and evaluated, knowledge gaps are identified, and a variety of exploration and assessment guides are presented. A summary is included for users seeking overviews of specific topics.

Exploring the life cycle management of industrial solid waste in the case of copper slag.

PubMed

Song, Xiaolong; Yang, Jianxin; Lu, Bin; Li, Bo

2013-06-01

Industrial solid waste has potential impacts on soil, water and air quality, as well as human health, during its whole life stages. A framework for the life cycle management of industrial solid waste, which integrates the source reduction process, is presented and applied to copper slag management. Three management scenarios of copper slag are developed: (i) production of cement after electric furnace treatment, (ii) production of cement after flotation, and (iii) source reduction before the recycling process. A life cycle assessment is carried out to estimate the environmental burdens of these three scenarios. Life cycle assessment results showed that the environmental burdens of the three scenarios are 2710.09, 2061.19 and 2145.02 Pt respectively. In consideration of the closed-loop recycling process, the environmental performance of the flotation approach excelled that of the electric furnace approach. Additionally, although flash smelting promotes the source reduction of copper slag compared with bath smelting, it did not reduce the overall environmental burdens resulting from the complete copper slag management process. Moreover, it led to the shifting of environmental burdens from ecosystem quality damage and resources depletion to human health damage. The case study shows that it is necessary to integrate the generation process into the whole life cycle of industrial solid waste, and to make an integrated assessment for quantifying the contribution of source reduction, rather than to simply follow the priority of source reduction and the hierarchy of waste management.

Untreated runoff quality from roof and road surfaces in a low intensity rainfall climate.

PubMed

Charters, Frances J; Cochrane, Thomas A; O'Sullivan, Aisling D

2016-04-15

Sediment and heavy metals in stormwater runoff are key pollutants of urban waterways, and their presence in stormwater is driven by climatic factors such as rainfall intensity. This study describes the total suspended solids (TSS) and heavy metal concentrations found in runoff from four different urban surfaces within a residential/institutional catchment, in a climate where rainfall is typically of low intensity (<5.1mm·h(-1)). The results were compared to untreated runoff quality from a compilation of international studies. The road runoff had the highest TSS concentrations, while copper and galvanized roof runoff had the highest copper and zinc concentrations, respectively. Pollutant concentrations were found to be significantly different between surfaces; quantification and prediction of pollutant contributions from urban surfaces should thus take account of the different surface materials, instead of being aggregated into more generalized categories such as land use. The TSS and heavy metal concentrations were found to be at the low to medium end of ranges observed internationally, except for total copper and zinc concentrations generated by dissolution of copper and galvanized roofing material respectively; these concentrations were at least as high as those reported internationally. TSS wash-off from the roofs was seen to be a source-limited process, where all available TSS is washed off during the rain event despite the low intensity rainfall, whereas both road TSS and heavy metals wash-off from roof and road surfaces appeared to all be transport-limited and therefore some carryover of pollutants occurs between rain events. A first flush effect was seen from most surfaces for TSS, but not for heavy metals. This study demonstrates that in low intensity rainfall climates, quantification of untreated runoff quality from key individual surface types in a catchment are needed to enable development of targeted and appropriately sized stormwater treatment systems. Copyright © 2016 Elsevier B.V. All rights reserved.

40 CFR 98.160 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.160 Definition of the source category. (a) A hydrogen production source category consists of facilities that produce hydrogen gas sold as a product to other entities. (b) This source category comprises process units that produce hydrogen by...

40 CFR 98.160 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.160 Definition of the source category. (a) A hydrogen production source category consists of facilities that produce hydrogen gas sold as a product to other entities. (b) This source category comprises process units that produce hydrogen by...

40 CFR 98.160 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.160 Definition of the source category. (a) A hydrogen production source category consists of facilities that produce hydrogen gas sold as a product to other entities. (b) This source category comprises process units that produce hydrogen by...

40 CFR 98.160 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.160 Definition of the source category. (a) A hydrogen production source category consists of facilities that produce hydrogen gas sold as a product to other entities. (b) This source category comprises process units that produce hydrogen by...

40 CFR 98.160 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.160 Definition of the source category. (a) A hydrogen production source category consists of facilities that produce hydrogen gas sold as a product to other entities. (b) This source category comprises process units that produce hydrogen by...

Long-distance connections in the Copper Age: New evidence from the Alpine Iceman’s copper axe

PubMed Central

Angelini, Ivana; Kaufmann, Günther; Canovaro, Caterina; Dal Sasso, Gregorio; Villa, Igor Maria

2017-01-01

25 years after the discovery in the Ötztal Italian Alps, the 5,300-year-old mummy keeps providing key information on human biological and medical conditions, aspects of everyday life and societal organization in the Copper Age. The hand axe found with the body of the Alpine Iceman is one of the rare copper objects that is firmly dated to the early Copper Age because of the radiocarbon dating of the axe wooden shaft. Here we report the measurement of the lead isotope ratios of the copper blade. The results unambiguously indicate that the source of the metal is the ore-rich area of Southern Tuscany, despite ample evidence that Alpine copper ore sources were known and exploited at the time. The experimental results are discussed within the framework of all the available coeval archaeometallurgical data in Central-Southern Europe: they show that the Alps were a neat cultural barrier separating distinct metal circuits. The direct evidence of raw metal or object movement between Central Italy and the Alps is surprising and provides a new perspective on long-distance relocation of goods and relationships between the early Copper Age cultures in the area. The result is in line with the recent investigations re-evaluating the timing and extent of copper production in Central Italy in the 4th millennium BC. PMID:28678801

Long-distance connections in the Copper Age: New evidence from the Alpine Iceman's copper axe.

PubMed

Artioli, Gilberto; Angelini, Ivana; Kaufmann, Günther; Canovaro, Caterina; Dal Sasso, Gregorio; Villa, Igor Maria

2017-01-01

25 years after the discovery in the Ötztal Italian Alps, the 5,300-year-old mummy keeps providing key information on human biological and medical conditions, aspects of everyday life and societal organization in the Copper Age. The hand axe found with the body of the Alpine Iceman is one of the rare copper objects that is firmly dated to the early Copper Age because of the radiocarbon dating of the axe wooden shaft. Here we report the measurement of the lead isotope ratios of the copper blade. The results unambiguously indicate that the source of the metal is the ore-rich area of Southern Tuscany, despite ample evidence that Alpine copper ore sources were known and exploited at the time. The experimental results are discussed within the framework of all the available coeval archaeometallurgical data in Central-Southern Europe: they show that the Alps were a neat cultural barrier separating distinct metal circuits. The direct evidence of raw metal or object movement between Central Italy and the Alps is surprising and provides a new perspective on long-distance relocation of goods and relationships between the early Copper Age cultures in the area. The result is in line with the recent investigations re-evaluating the timing and extent of copper production in Central Italy in the 4th millennium BC.

Influence of electron donors and copper concentration on geochemical and mineralogical processes under conditions of biological sulphate reduction

NASA Astrophysics Data System (ADS)

Wolicka, Dorota; Borkowski, Andrzej

2014-03-01

Sulphidogenous microorganism communities were isolated from soil polluted by crude oil. The study was focused on determining the influence of 1) copper (II) concentration on the activity of selected microorganism communities and 2) the applied electron donor on the course and evolution of mineral-forming processes under conditions favouring growth of sulphate-reducing bacteria (SRB). The influence of copper concentration on the activity of selected microorganism communities and the type of mineral phases formed was determined during experiments in which copper (II) chloride at concentrations of 0.1, 0.2, 0.5 and 0.7 g/L was added to SRB cultures. The experiments were performed in two variants: with ethanol (4 g/L) or lactate (4 g/L) as the sole carbon source. In order to determine the taxonomic composition of the selected microorganism communities, the 16S rRNA method was used. Results of this analysis confirmed the presence of Desulfovibrio, Desulfohalobium, Desulfotalea, Thermotoga, Solibacter, Gramella, Anaeromyxobacter and Myxococcus sp. in the stationary cultures. The post-culture sediments contained covelline (CuS) and digenite (Cu9S5 ). Based on the results, it can be stated that the type of carbon source applied during incubation plays a crucial role in determining the mineral composition of the post-culture sediments. Thus, regardless of the amount of copper ion introduced to a culture with lactate as the sole carbon source, no copper sulphide was observed in the post-culture sediments. Cultures with ethanol as the sole carbon source, on the other hand, yielded covelline or digenite in all post-culture sediments.

Quantification of metal loads by tracer injection and synoptic sampling in Daisy Creek and the Stillwater River, Park County, Montana, August 1999

USGS Publications Warehouse

Nimick, David A.; Cleasby, Thomas E.

2001-01-01

A metal-loading study using tracer-injection and synoptic-sampling methods was conducted in Daisy Creek and a short reach of the Stillwater River during baseflow in August 1999 to quantify the metal inputs from acid rock drainage in the New World Mining District near Yellowstone National Park and to examine the downstream transport of these metals into the Stillwater River. Loads were calculated for many mainstem and inflow sites by combining streamflow determined using the tracer-injection method with concentrations of major ions and metals that were determined in synoptic water-quality samples. Water quality and aquatic habitat in Daisy Creek have been affected adversely by drainage derived from waste rock and adit discharge at the McLaren Mine as well as from natural weathering of pyrite-rich mineralized rock that comprises and surrounds the ore zones. However, the specific sources and transport pathways are not well understood. Knowledge of the main sources and transport pathways of metals and acid can aid resource managers in planning and conducting effective and cost-efficient remediation activities. The metals cadmium, copper, lead, and zinc occur at concentrations that are sufficiently elevated to be potentially lethal to aquatic life in Daisy Creek and to pose a toxicity risk in part of the Stillwater River. Copper is of most concern in Daisy Creek because it occurs at higher concentrations than the other metals. Acidic surface inflows had dissolved concentrations as high as 20.6 micrograms per liter (?g/L) cadmium, 26,900 ?g/L copper, 76.4 ?g/L lead, and 3,000 ?g/L zinc. These inflows resulted in maximum dissolved concentrations in Daisy Creek of 5.8 ?g/L cadmium, 5,790 ?g/L copper, 3.8 ?g/L lead, and 848 ?g/L zinc. Significant copper loading to Daisy Creek occurred only in the upper half of the stream. Sources included subsurface inflow and right-bank (mined side) surface inflows. Copper loads in left-bank (unmined side) surface inflows were negligible. Most (71 percent) of the total copper loading in the study reach occurred along a 341-foot reach near the stream?s headwaters. About 53 percent of the total copper load was contributed by five surface inflows that drain a manganese bog and the southern part of the McLaren Mine. Copper loading from subsurface inflow was substantial, contributing 46 percent of the total dissolved copper load to Daisy Creek. More than half of this subsurface copper loading occurred downstream from the reaches that received significant surface loading. Flow through the shallow subsurface appears to be the main copper-transport pathway from the McLaren Mine and surrounding altered and mineralized bedrock to Daisy Creek during base-flow conditions. Little is known about the source of acid and copper in this subsurface flow. However, possible sources include the mineralized rocks of Fisher Mountain upgradient of the McLaren Mine area, the surficial waste rock at the mine, and the underlying pyritic bedrock.

Threat Identification Parameters for a Stolen Category 1 Radioactive Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ussery, Larry Eugene; Winkler, Ryan; Myers, Steven Charles

2016-02-18

Radioactive sources are used very widely for research and practical applications across medicine, industry, government, universities, and agriculture. The risks associated with these sources vary widely depending on the specific radionuclide used to make the source, source activity, and its chemical and physical form. Sources are categorized by a variety of classification schemes according to the specific risk they pose to the public. This report specifically addresses sources that are classified in the highest category for health risk (category 1). Exposure to an unshielded or lightly shielded category 1 source is extremely dangerous to life and health and can bemore » fatal in relatively short exposure times measured in seconds to minutes. A Category 1 source packaged according to the guidelines dictated by the NRC and U.S. Department of Transportation will typically be surrounded by a large amount of dense shielding material, but will still exhibit a significant dose rate in close proximity. Detection ranges for Category 1 gamma ray sources can extend beyond 5000 ft, but will depend mostly on the source isotope and activity, and the level of shielding around the source. Category 1 sources are easy to detect, but difficult to localize. Dose rates in proximity to an unshielded Category 1 source are extraordinarily high. At distances of a few hundred feet, the functionality of many commonly used handheld instruments will be extremely limited for both the localization and identification of the source. Radiation emitted from a Category 1 source will scatter off of both solid material (ground and buildings) and the atmosphere, a phenomenon known as skyshine. This scattering affects the ability to easily localize and find the source.« less

Effects of a copper-tolerant grass (Agrostis capillaris) on the ecosystem of a copper-contaminated arable soil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boon, G.T.; Bouwman, L.A.; Bloem, J.

1998-10-01

To test how a dysfunctioning ecosystem of a severely metal-polluted soil responds to renewed plant growth, a pot experiment was conducted with soil from an experimental arable field with pH and copper gradients imposed 13 years ago. In this experiment, four pH/copper combinations from this field were either planted with a pH- and copper-resistant grass cultivar or remained fallow. During a 10-week period, the dynamics of the microbial activity and of the abundances of bacteria, protozoa. and nematodes were measured, as were the dynamics of several chemical soil parameters. After 13 years of copper, which had resulted in severely reducedmore » crop growth, no effects were observed on bacterial numbers, respiration, or protozoan numbers, but bacterial growth was strongly reduced in the low pH plots, and even more so in low pH plots enriched with copper. Of the organisms, only nematodes were negatively affected under conditions of high copper load at low pH. In these plots, numbers belonging to all feeding categories were strongly reduced. Planting of a copper-tolerant grass variety, Agrostis capillaris L. var. Parys Mountain, resulted within 10 weeks in faster bacterial growth and more protozoa and bacterivorous nematodes in comparison with fallow controls; these effects were markedly strongest in the acidic, copper-enriched soils. During incubation, fungivorous nematodes increased in all treatments, in fallow and in planted pots and in the pots with high-copper, low-pH soil. The results of this experiment suggest that introduction of plant growth is one of the major causes of increased biological activity in acidic contaminated soils. Planting such soils with metal-tolerant plant species can reestablish the necessary food base to support soil organism growth, and this can lead to numerous positive effects, reversing the loss of soil functions due to the high copper levels under acidic conditions.« less

Copper hazards to fish, wildlife and invertebrates: a synoptic review

USGS Publications Warehouse

Eisler, Ronald

1998-01-01

Selective review and synthesis of the technical literature on copper and copper salts in the environment and their effects primarily on fishes, birds, mammals, terrestrial and aquatic invertebrates, and other natural resources. The subtopics include copper sources and uses; chemical and biochemical properties; concentrations of copper in field collections of abiotic materials and living organisms; effects of copper deficiency; lethal and sublethal effects on terrestrial plants and invertebrates, aquatic organisms, birds and mammals, including effects on survival, growth, reproduction, behavior, metabolism, carcinogenicity, matagenicity, and teratogenicity; proposed criteria for the protection of human health and sensitive natural resources; and recommendations for additional research.

Assessment and modification of an ion source grid design in KSTAR neutral beam system.

PubMed

Lee, Dong Won; Shin, Kyu In; Jin, Hyung Gon; Choi, Bo Guen; Kim, Tae-Seong; Jeong, Seung Ho

2014-02-01

A new 2 MW NB (Neutral Beam) ion source for supplying 3.5 MW NB heating for the KSTAR campaign was developed in 2012 and its grid was made from OFHC (Oxygen Free High Conductivity) copper with rectangular cooling channels. However, the plastic deformation such as a bulging in the plasma grid of the ion source was found during the overhaul period after the 2012 campaign. A thermal-hydraulic and a thermo-mechanical analysis using the conventional code, ANSYS, were carried out and the thermal fatigue life assessment was evaluated. It was found that the thermal fatigue life of the OFHC copper grid was about 335 cycles in case of 0.165 MW/m(2) heat flux and it gave too short fatigue life to be used as a KSTAR NB ion source grid. To overcome the limited fatigue life of the current design, the following methods were proposed in the present study: (1) changing the OHFC copper to CuCrZr, copper-alloy or (2) adopting a new design with a pure Mo metal grid and CuCrZr tubes. It is confirmed that the proposed methods meet the requirements by performing the same assessment.

Copper atomic-scale transistors.

PubMed

Xie, Fangqing; Kavalenka, Maryna N; Röger, Moritz; Albrecht, Daniel; Hölscher, Hendrik; Leuthold, Jürgen; Schimmel, Thomas

2017-01-01

We investigated copper as a working material for metallic atomic-scale transistors and confirmed that copper atomic-scale transistors can be fabricated and operated electrochemically in a copper electrolyte (CuSO 4 + H 2 SO 4 ) in bi-distilled water under ambient conditions with three microelectrodes (source, drain and gate). The electrochemical switching-on potential of the atomic-scale transistor is below 350 mV, and the switching-off potential is between 0 and -170 mV. The switching-on current is above 1 μA, which is compatible with semiconductor transistor devices. Both sign and amplitude of the voltage applied across the source and drain electrodes ( U bias ) influence the switching rate of the transistor and the copper deposition on the electrodes, and correspondingly shift the electrochemical operation potential. The copper atomic-scale transistors can be switched using a function generator without a computer-controlled feedback switching mechanism. The copper atomic-scale transistors, with only one or two atoms at the narrowest constriction, were realized to switch between 0 and 1 G 0 ( G 0 = 2e 2 /h; with e being the electron charge, and h being Planck's constant) or 2 G 0 by the function generator. The switching rate can reach up to 10 Hz. The copper atomic-scale transistor demonstrates volatile/non-volatile dual functionalities. Such an optimal merging of the logic with memory may open a perspective for processor-in-memory and logic-in-memory architectures, using copper as an alternative working material besides silver for fully metallic atomic-scale transistors.

Factors Affecting the Supply of Strategic Raw Materials with Particular Reference to the Aerospace Manufacturing Industry

DTIC Science & Technology

1984-04-01

element, recovered from the working of many porphyry copper deposits. As copper capacity i» now far beyond requirements, molybdenum should not be in...Source» Cobalt is mostly recovered aa a by-product of copper and nickel mining but world production is highly localised. Total annual production is...aluminium alloy containing lithium, copper and magnesium is under test. Por corrosion resistance there can be an Interchange with niobium. However

40 CFR 142.19 - EPA review of State implementation of national primary drinking water regulations for lead and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... national primary drinking water regulations for lead and copper. 142.19 Section 142.19 Protection of... implementation of national primary drinking water regulations for lead and copper. (a) Pursuant to the procedures... control or source water treatment requirements for lead or copper and may issue an order establishing...

40 CFR 142.19 - EPA review of State implementation of national primary drinking water regulations for lead and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... national primary drinking water regulations for lead and copper. 142.19 Section 142.19 Protection of... implementation of national primary drinking water regulations for lead and copper. (a) Pursuant to the procedures... control or source water treatment requirements for lead or copper and may issue an order establishing...

40 CFR 471.103 - New source performance standards (NSPS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... mg/off-kg (pounds per million off-pounds) of powder metallurgy parts steam treated Copper 0.151 0.079... million off-pounds) of powder metallurgy parts tumbled, burnished, or cleaned Copper 0.836 0.440 Cyanide 0... off-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005...

40 CFR 471.105 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... mg/off-kg (pounds per million off-pounds) of powder metallurgy parts steam treated Copper 0.151 0.079... million off-pounds) of powder metallurgy parts tumbled, burnished, or cleaned Copper 0.836 0.440 Cyanide 0... off-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005...

Weathering of sulfidic shale and copper mine waste: Secondary minerals and metal cycling in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA

USGS Publications Warehouse

Hammarstrom, J.M.; Seal, R.R.; Meier, A.L.; Jackson, J.C.

2003-01-01

Metal cycling via physical and chemical weathering of discrete sources (copper mines) and regional (non-point) sources (sulfide-rich shale) is evaluated by examining the mineralogy and chemistry of weathering products in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA. The elements in copper mine waste, secondary minerals, stream sediments, and waters that are most likely to have negative impacts on aquatic ecosystems are aluminum, copper, zinc, and arsenic because these elements locally exceed toxicity guidelines for surface waters or for stream sediments. Acid-mine drainage has not developed in streams draining inactive copper mines. Acid-rock drainage and chemical weathering processes that accompany debris flows or human disturbances of sulfidic rocks are comparable to processes that develop acid-mine drainage elsewhere. Despite the high rainfall in the mountain range, sheltered areas and intermittent dry spells provide local venues for development of secondary weathering products that can impact aquatic ecosystems.

40 CFR 98.330 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.330 Definition of the source category. The zinc production source category consists of zinc smelters and secondary zinc recycling facilities. ...

40 CFR 98.330 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.330 Definition of the source category. The zinc production source category consists of zinc smelters and secondary zinc recycling facilities. ...

Growth response, blood characteristics and copper accumulation in organs of broilers fed on diets supplemented with organic and inorganic dietary copper sources.

PubMed

Jegede, A V; Oduguwa, O O; Bamgbose, A M; Fanimo, A O; Nollet, L

2011-02-01

1. A 56-d experiment was conducted to study the comparative influence of organic and inorganic dietary copper (Cu) sources on growth, blood characteristics and copper accumulation in organs of broilers. 2. A total of 480 Arbor-Acre unsexed broilers were fed on diets containing copper sulphate (CuSO(4)) or copper proteinate (Cu Pro) at concentrations of 50, 100 or 150 mg/kg of Cu supplementation. The birds were given a broiler starter diet from 1-28 d and a broiler finisher diet from 29-56 d which contained 30·8 mg/kg and 41·1 mg/kg basal copper concentration respectively. Growth performance, blood characteristics and Cu accumulation in organs of the broilers were measured. 3. At 28 d, Cu Pro-fed birds had improved feed conversion ratio compared with CuSO(4). At 56 d, birds fed on Cu Pro diets had significantly greater body weight than CuSO(4)-fed birds. Birds fed on CuSO(4) supplemented diets had significantly better feed conversion efficiency. Feed consumptions for the two Cu sources were not significantly different. At no stage did the concentration of added Cu affect the productive traits measured. 4. Cu Pro supplementation increased haemoglobin concentration but reduced plasma triglyceride and plasma cholesterol. Plasma cholesterol decreased as Cu concentration increased. 5. There was a greater accumulation of Cu in the blood, heart, lung, liver and bone of broilers fed on Cu Pro than in those receiving CuSO(4). The liver Cu concentration increased as dietary Cu concentration increased. 6. Cu Pro was more effective in promoting growth and reducing blood cholesterol, and was more bio-available in the organs of broilers.

40 CFR 421.326 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... uranium processed in the refinery Chromium (total) 27.14 11.00 Copper 93.88 44.74 Nickel 40.34 27.14... uranium processed in the refinery Chromium (total) 1.689 0.685 Copper 5.844 2.785 Nickel 2.511 1.689... per million pounds) of uranium processed in the refinery Chromium (total) 2.357 0.955 Copper 8.152 3...

40 CFR 421.326 - Pretreatment standards for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... uranium processed in the refinery Chromium (total) 27.14 11.00 Copper 93.88 44.74 Nickel 40.34 27.14... uranium processed in the refinery Chromium (total) 1.689 0.685 Copper 5.844 2.785 Nickel 2.511 1.689... per million pounds) of uranium processed in the refinery Chromium (total) 2.357 0.955 Copper 8.152 3...

40 CFR 471.104 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

... (pounds per million off-pounds) of powder metallurgy part steam treated Copper 1.51 0.792 Cyanide 0.230 0...-pounds) of powder metallurgy parts tumbled, burnished, or cleaned Copper 8.36 4.40 Cyanide 1.28 0.528...-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005 0.002...

Substance flow analysis as a tool for urban water management.

PubMed

Chèvre, N; Guignard, C; Rossi, L; Pfeifer, H-R; Bader, H-P; Scheidegger, R

2011-01-01

Human activity results in the production of a wide range of pollutants that can enter the water cycle through stormwater or wastewater. Among others, heavy metals are still detected in high concentrations around urban areas and their impact on aquatic organisms is of major concern. In this study, we propose to use a substance flow analysis as a tool for heavy metals management in urban areas. We illustrate the approach with the case of copper in Lausanne, Switzerland. The results show that around 1,500 kg of copper enter the aquatic compartment yearly. This amount contributes to sediment enrichment, which may pose a long-term risk for benthic organisms. The major sources of copper in receiving surface water are roofs and catenaries of trolleybuses. They represent 75% of the total input of copper into the urban water system. Actions to reduce copper pollution should therefore focus on these sources. Substance flow analysis also highlights that copper enters surface water mainly during rain events, i.e., without passing through any treatment procedure. A reduction in pollution could also be achieved by improving stormwater management. In conclusion, the study showed that substance flow analysis is a very effective tool for sustainable urban water management.

40 CFR 98.340 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Municipal Solid Waste Landfills § 98.340 Definition of the source category. (a) This source category applies to municipal solid waste (MSW) landfills that accepted... of the following sources at municipal solid waste (MSW) landfills: Landfills, landfill gas collection...

Copper atomic-scale transistors

PubMed Central

Kavalenka, Maryna N; Röger, Moritz; Albrecht, Daniel; Hölscher, Hendrik; Leuthold, Jürgen

2017-01-01

We investigated copper as a working material for metallic atomic-scale transistors and confirmed that copper atomic-scale transistors can be fabricated and operated electrochemically in a copper electrolyte (CuSO4 + H2SO4) in bi-distilled water under ambient conditions with three microelectrodes (source, drain and gate). The electrochemical switching-on potential of the atomic-scale transistor is below 350 mV, and the switching-off potential is between 0 and −170 mV. The switching-on current is above 1 μA, which is compatible with semiconductor transistor devices. Both sign and amplitude of the voltage applied across the source and drain electrodes (U bias) influence the switching rate of the transistor and the copper deposition on the electrodes, and correspondingly shift the electrochemical operation potential. The copper atomic-scale transistors can be switched using a function generator without a computer-controlled feedback switching mechanism. The copper atomic-scale transistors, with only one or two atoms at the narrowest constriction, were realized to switch between 0 and 1G 0 (G 0 = 2e2/h; with e being the electron charge, and h being Planck’s constant) or 2G 0 by the function generator. The switching rate can reach up to 10 Hz. The copper atomic-scale transistor demonstrates volatile/non-volatile dual functionalities. Such an optimal merging of the logic with memory may open a perspective for processor-in-memory and logic-in-memory architectures, using copper as an alternative working material besides silver for fully metallic atomic-scale transistors. PMID:28382242

Development and validation of a lead emission inventory for the Greater Cairo area

PubMed Central

Safar, Zeinab; Labib, Mounir W.; Gertler, Alan W.

2013-01-01

Studies that investigate the environmental health risks to Cairo residents invariably conclude that lead is one of the area’s major health hazards. The Cairo Air Improvement Project (CAIP), which was implemented by a team led by Chemonics International, funded by USAID in partnership with the Egyptian Environmental Affairs Agency (EEAA), started developing a lead emission inventory for the greater Cairo (GC) area in 1998. The inventory contains a list by major source of the annual lead emissions in the GC area. Uses of the inventory and associated database include developing effective regulatory and control strategies, assessing emissions trends, and conducting modeling exercises. This paper describes the development of the current lead emissions inventory (1999–2010), along with an approach to develop site specific emission factors and measurements to validate the inventory. This paper discusses the major sources of lead in the GC area, which include lead smelters, Mazout (heavy fuel oil) combustion, lead manufacturing batteries factories, copper foundries, and cement factories. Included will be the trend in the lead emissions inventory with regard to the production capacity of each source category. In addition, the lead ambient measurements from 1999 through 2010 are described and compared with the results of Source Attribution Studies (SAS) conducted in 1999, 2002, and 2010. Due to EEAA/CAIP efforts, a remarkable decrease in more than 90% in lead emissions was attained for 2007. PMID:25685523

40 CFR 98.310 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Titanium Dioxide Production § 98.310 Definition of the source category. The titanium dioxide production source category consists of facilities that use the chloride process to produce titanium dioxide. ...

40 CFR 98.310 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Titanium Dioxide Production § 98.310 Definition of the source category. The titanium dioxide production source category consists of facilities that use the chloride process to produce titanium dioxide. ...

40 CFR 98.310 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Titanium Dioxide Production § 98.310 Definition of the source category. The titanium dioxide production source category consists of facilities that use the chloride process to produce titanium dioxide. ...

40 CFR 98.310 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Titanium Dioxide Production § 98.310 Definition of the source category. The titanium dioxide production source category consists of facilities that use the chloride process to produce titanium dioxide. ...

40 CFR 98.310 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Titanium Dioxide Production § 98.310 Definition of the source category. The titanium dioxide production source category consists of facilities that use the chloride process to produce titanium dioxide. ...

Copper toxicity in the crab, Scylla serrata, copper levels in tissues and regulation after exposure to a copper-rich medium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arumugam, M.; Ravindranath, M.H.

1987-10-01

In the decapod crustaceans copper is distributed in various tissues. In these animals the tissue copper generally exists in four forms; ionic, bound to proteins, lipids and membrane. In the estuarine crab Scylla serrata, the haemolymph copper exists only in association with proteins, whereas in the hepatopancreas it exists in all the four forms and in gills it exists in all the forms except in combination with lipids. Although food is the major source of copper in decapod crustaceans evidence indicate that copper may be directly obtained from the environment. It was postulated earlier that in Scylla serrata the haemolymphmore » and hepatopancreas may be involved in copper regulation. In the present work the authors have studied the nature and levels of copper in different tissues after exposing the crabs to copper-rich medium. The results indicate the relative importance of various tissues in accumulation an the possible mechanisms of regulation of the environmental copper. Besides, as a pre-requisite for studies of this kind, the toxic levels for different forms of copper were estimated since the form of toxicant is known to influence the toxicity to the decapod crustaceans.« less

31 CFR 100.11 - Exchange of bent and partial coins.

Code of Federal Regulations, 2013 CFR

2013-07-01

... partial coins shall be presented separately by denomination category in lots of at least one pound for... redeemed at the face value equivalent of copper one cent coins. (c) Redemption site. Bent and partial coins will be redeemed only at the United States Mint, P.O. Box 400, Philadelphia, PA 19105. Coins are...

United States copper metal and scrap use and trade patterns, 1995‒2014

USGS Publications Warehouse

Goonan, Thomas G.

2016-06-17

This report considers changes to the copper and copper scrap industries of the United States. For the study period, 1995 through 2014, U.S. refined copper production from all sources (primary and secondary materials) decreased from 2.28 million metric tons (Mt) of copper to 1.05 Mt (a 54 percent decrease). During the same period, U.S. copper scrap net exports increased from 0.203 Mt to 0.737 Mt (a 263 percent increase and a compound annual growth rate of about 7.0 percent per year). Copper and copper scrap prices (in constant 2014 dollars) rose such that 2014 prices were about 48 percent greater than 1995 prices. From 1995 through 2014, Chinese imports of copper scrap from the United States grew from 0.061 Mt to 0.569 Mt (an increase of about 830 percent and a compound annual growth rate of about 12.5 percent per year). In 2011, Chinese imports of U.S. copper scrap peaked at 0.745 Mt of contained copper. In 1995, Chinese imports of U.S. copper scrap accounted for 17 percent of U.S. copper scrap exports. By 2014, Chinese imports accounted for 69 percent of U.S. copper scrap exports (by weight), and Chinese imports of U.S. copper scrap were valued at $1.45 billion.

Spatial database for a global assessment of undiscovered copper resources: Chapter Z in Global mineral resource assessment

USGS Publications Warehouse

Dicken, Connie L.; Dunlap, Pamela; Parks, Heather L.; Hammarstrom, Jane M.; Zientek, Michael L.; Zientek, Michael L.; Hammarstrom, Jane M.; Johnson, Kathleen M.

2016-07-13

As part of the first-ever U.S. Geological Survey global assessment of undiscovered copper resources, data common to several regional spatial databases published by the U.S. Geological Survey, including one report from Finland and one from Greenland, were standardized, updated, and compiled into a global copper resource database. This integrated collection of spatial databases provides location, geologic and mineral resource data, and source references for deposits, significant prospects, and areas permissive for undiscovered deposits of both porphyry copper and sediment-hosted copper. The copper resource database allows for efficient modeling on a global scale in a geographic information system (GIS) and is provided in an Esri ArcGIS file geodatabase format.

New configuration for efficient and durable copper coating on the outer surface of a tube

DOE PAGES

Ahmad, Irfan; Chapman, Steven F.; Velas, Katherine M.; ...

2017-03-27

A well-adhered copper coating on stainless steel power coupler parts is required in superconducting radio frequency (SRF) accelerators. Radio frequency power coupler parts are complex, tubelike stainless steel structures, which require copper coating on their outer and inner surfaces. Conventional copper electroplating sometimes produces films with inadequate adhesion strength for SRF applications. Electroplating also requires a thin nickel strike layer under the copper coating, whose magnetic properties can be detrimental to SRF applications. Coaxial energetic deposition (CED) and sputtering methods have demonstrated efficient conformal coating on the inner surfaces of tubes but coating the outer surface of a tube ismore » challenging because these coating methods are line of sight. When the substrate is off axis and the plasma source is on axis, only a small section of the substrate’s outer surface is exposed to the source cathode. The conventional approach is to rotate the tube to achieve uniformity across the outer surface. This method results in poor film thickness uniformity and wastes most of the source plasma. Alameda Applied Sciences Corporation (AASC) has developed a novel configuration called hollow external cathode CED (HEC-CED) to overcome these issues. HEC-CED produces a film with uniform thickness and efficiently uses all eroded source material. Furthermore, the Cu film deposited on the outside of a stainless steel tube using the new HEC-CED configuration survived a high pressure water rinse adhesion test. HEC-CED can be used to coat the outside of any cylindrical structure.« less

New configuration for efficient and durable copper coating on the outer surface of a tube

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahmad, Irfan; Chapman, Steven F.; Velas, Katherine M.

A well-adhered copper coating on stainless steel power coupler parts is required in superconducting radio frequency (SRF) accelerators. Radio frequency power coupler parts are complex, tubelike stainless steel structures, which require copper coating on their outer and inner surfaces. Conventional copper electroplating sometimes produces films with inadequate adhesion strength for SRF applications. Electroplating also requires a thin nickel strike layer under the copper coating, whose magnetic properties can be detrimental to SRF applications. Coaxial energetic deposition (CED) and sputtering methods have demonstrated efficient conformal coating on the inner surfaces of tubes but coating the outer surface of a tube ismore » challenging because these coating methods are line of sight. When the substrate is off axis and the plasma source is on axis, only a small section of the substrate’s outer surface is exposed to the source cathode. The conventional approach is to rotate the tube to achieve uniformity across the outer surface. This method results in poor film thickness uniformity and wastes most of the source plasma. Alameda Applied Sciences Corporation (AASC) has developed a novel configuration called hollow external cathode CED (HEC-CED) to overcome these issues. HEC-CED produces a film with uniform thickness and efficiently uses all eroded source material. Furthermore, the Cu film deposited on the outside of a stainless steel tube using the new HEC-CED configuration survived a high pressure water rinse adhesion test. HEC-CED can be used to coat the outside of any cylindrical structure.« less

Sediment-hosted stratabound copper deposit model: Chapter M in Mineral deposit model for resource assessment

USGS Publications Warehouse

Hayes, Timothy S.; Cox, Dennis P.; Bliss, James D.; Piatak, Nadine M.; Seal, Robert R.

2015-01-01

This report contains a descriptive model of sediment-hosted stratabound copper (SSC) deposits that supersedes the model of Cox and others (2003). This model is for use in assessments of mineral resource potential. SSC deposits are the second most important sources of copper in the world behind porphyry copper deposits. Around 20 percent of the copper in the world is produced from this class of deposits. They are also the most important sources of cobalt in the world, and they are fourth among classes of ore deposits in production of silver. SSC deposits are the basis of the economies of three countries: Democratic Republic of Congo, Poland, and Zambia. This report provides a description of the key features of SSC deposits; it identifies their tectonic-sedimentary environments; it illustrates geochemical, geophysical, and geoenvironmental characteristics of SSC deposits; it reviews and evaluates hypotheses on how these deposits formed; it presents exploration and assessment guides; and it lists some gaps in our knowledge about the SSC deposits. A summary follows that provides overviews of many subjects concerning SSC deposits.

Lead isotope compositions of Late Cretaceous and early Tertiary igneous rocks and sulfide minerals in Arizona: Implications for the sources of plutons and metals in porphyry copper deposits

USGS Publications Warehouse

Bouse, R.M.; Ruiz, J.; Titley, S.R.; Tosdal, R.M.; Wooden, J.L.

1999-01-01

Porphyry copper deposits in Arizona are genetically associated with Late Cretaceous and early Tertiary igneous complexes that consist of older intermediate volcanic rocks and younger intermediate to felsic intrusions. The igneous complexes and their associated porphyry copper deposits were emplaced into an Early Proterozoic basement characterized by different rocks, geologic histories, and isotopic compositions. Lead isotope compositions of the Proterozoic basement rocks define, from northwest to southeast, the Mojave, central Arizona, and southeastern Arizona provinces. Porphyry copper deposits are present in each Pb isotope province. Lead isotope compositions of Late Cretaceous and early Tertiary plutons, together with those of sulfide minerals in porphyry copper deposits and of Proterozoic country rocks, place important constraints on genesis of the magmatic suites and the porphyry copper deposits themselves. The range of age-corrected Pb isotope compositions of plutons in 12 Late Cretaceous and early Tertiary igneous complexes is 206Pb/204Pb = 17.34 to 22.66, 207Pb/204Pb = 15.43 to 15.96, and 208Pb/204Pb = 37.19 to 40.33. These Pb isotope compositions and calculated model Th/U are similar to those of the Proterozoic rocks in which the plutons were emplaced, thereby indicating that Pb in the younger rocks and ore deposits was inherited from the basement rocks and their sources. No Pb isotope differences distinguish Late Cretaceous and early Tertiary igneous complexes that contain large economic porphyry copper deposits from less rich or smaller deposits that have not been considered economic for mining. Lead isotope compositions of Late Cretaceous and early Tertiary plutons and sulfide minerals from 30 metallic mineral districts, furthermore, require that the southeastern Arizona Pb province be divided into two subprovinces. The northern subprovince has generally lower 206Pb/204Pb and higher model Th/U, and the southern subprovince has higher 206Pb/204Pb and lower model Th/U. These Pb isotope differences are inferred to result from differences in their respective post-1.7 Ga magmatic histories. Throughout Arizona, Pb isotope compositions of Late Cretaceous and early Tertiary plutons and associated sulfide minerals are distinct from those of Jurassic plutons and also middle Tertiary igneous rocks and sulfide minerals. These differences most likely reflect changes in tectonic setting and magmatic sources. Within Late Cretaceous and early Tertiary igneous complexes that host economic porphyry copper deposits, there is commonly a decrease in Pb isotope composition from older to younger plutons. This decrease in Pb isotope values with time suggests an increasing involvement of crust with lower U/Pb than average crust in the source(s) of Late Cretaceous and early Tertiary magmas. Lead isotope compositions of the youngest porphyries in the igneous complexes are similar to those in most sulfide minerals within the associated porphyry copper deposit. This Pb isotope similarity argues for a genetic link between them. However, not all Pb in the sulfide minerals in porphyry copper deposits is magmatically derived. Some sulfide minerals, particularly those that are late stage, or distal to the main orebody, or in Proterozoic or Paleozoic rocks, have elevated Pb isotope compositions displaced toward the gross average Pb isotope composition of the local country rocks. The more radiogenic isotopic compositions argue for a contribution of Pb from those rocks at the site of ore deposition. Combining the Pb isotope data with available geochemical, isotopic, and petrologic data suggests derivation of the young porphyry copper-related plutons, most of their Pb, and other metals from a hybridized lower continental crustal source. Because of the likely involvement of subduction-related mantle-derived basaltic magma in the hybridized lower crustal source, an indiscernible mantle contribution is probable in the porphyry magmas. Clearly, in addition

An Investigation of Low Biofouling Copper-charged Membranes

NASA Astrophysics Data System (ADS)

Asapu, Sunitha

Water is essential for the survival of life on Earth, but pollutants in water can cause dangerous diseases and fatalities. The need for purified water has been increasing with increasing world population; however, natural sources of water such as rivers, lakes and streams, are progressively falling shorter and shorter of meeting water needs. The provision of clean, drinkable water to people is a key factor for the development of novel and alternative water purification technologies, such as membrane separations. Nanofiltration (NF) is a membrane separations technology that purifies water from lower quality sources, such as brackish water, seawater and wastewater. During the filtration of such sources, materials that are rejected by the membrane may accumulate on the surface of the membrane to foul it. Such materials include organic and inorganic matter, colloids, salts and microorganisms. The former four can often be controlled via pretreatment; however, the accumulation of microorganisms is more problematic to membranes. Biofouling is the accumulation and growth of microorganisms on the surface of membranes and on feed spacers. After attachment, microorganisms excrete extracellular polymeric substances (EPS), which form a matrix around the organism's outer surface as biofilm. These biofilms are detrimental and result in irreversible membrane fouling. Copper and silver ions inactivate the bacterial cells and prevent the DNA replication in microbial cells. Previous studies using copper-charged feed spacers have shown the ability of copper to control biofouling without a significant amount of copper leaching from copper-charged polypropylene (PP) feed spacers during crossflow filtration. Also, filtration using unmodified speed facers experienced almost 70% flux decline, while filtration using copper-charged feed spacers displayed only 25% flux decline. These intriguing results led to the hypothesis that the polymer chemistry could be extrapolated to produce membranes with increased biofouling resistance. The goal of this project was to develop low-biofouling nanofiltration cellulose acetate (CA) membranes through functionalization with metal chelating ligands charged with biocidal metal ions, i.e. copper ions. To this end, glycidyl methacrylate (GMA), an epoxy, was used to attach a chelating agent, iminodiacetic acid (IDA) to facilitate the charging of copper to the membrane surface. Both CA and CA-GMA membranes were cast using the phase-inversion method. The CA-GMA membranes were then charged with copper ions to make them low biofouling. Pore size distribution analysis of CA and copper charged membranes were conducted using various molecular weights of polyethylene glycol (PEG). CA and copper-charged membranes were characterized using Fourier Transform Infrared (FTIR), contact angle to measure hydrophilicity changes, and using scanning electron microscope (SEM) coupled with X-ray energy dispersive spectroscopy EDS to monitor copper leaching. Permeation experiments were conducted with distilled (DI) water, protein solutions, and synthetic brackish water containing microorganisms. The DI water permeation of the copper-charged membranes was initially lower than the CA membranes. The membranes were then subjected to bovine serum albumin (BSA) and lipase filtration. The copper-charged membranes showed higher pure water flux values for both proteins as compared to CA membranes. The rejection of BSA and lipase was the same for both the copper charged and CA membranes. The filtration with the synthetic brackish water showed that copper-charged membranes had higher flux values as compared to CA membranes, and biofouling analysis showed more bacteria on the CA membranes as compared to copper-charged membranes. Therefore, the copper-charged membranes made here have shown a potential to be used as low-biofouling membranes in the future.

Chalcopyrite—bearer of a precious, non-precious metal

USGS Publications Warehouse

Kimball, Bryn E.

2013-01-01

The mineral chalcopyrite (CuFeS2) is the world's most abundant source of copper, a metal component in virtually every piece of electrical equipment. It is the main copper mineral in several different ore deposit types, the most important of which are porphyry deposits. Chalcopyrite is unstable at the Earth's surface, so it weathers from sulphide outcrops and mine waste piles, contributing acid and dissolved copper to what is known as acid rock drainage. If not prevented, dissolved copper from chalcopyrite weathering will be transported downstream, potentially harming ecosystems along the way. Pristine areas are becoming targets for future copper supply as we strive to meet ever-increasing demands for copper by developed and developing nations. Additionally, our uses for copper are expanding to include technology such as solar energy production. This has lead to the processing of increasingly lower grade ores, which is possible, in part, due to advances in bio-leaching (i.e. metal extraction catalysed by micro-organisms). Although copper is plentiful, it is still a nonrenewable resource. Future copper supply promises to fall short of demand and the volatility of the copper market may continue if we do not prioritize copper use and improve copper recycling and ore extraction efficiency.

In vitro Solubility of Copper(II) Sulfate and Dicopper Chloride Trihydroxide for Pigs.

PubMed

Park, C S; Kim, B G

2016-11-01

This study was conducted to determine the solubility of copper (Cu) in two sources of copper(II) sulfate (CuSO 4 ) including monohydrate and pentahydrate and three sources of dicopper chloride trihydroxide (dCCTH) including α-form (dCCTH-α), β-form (dCCTH-β), and a mixture of α- and β-form (dCCTH-αβ) at different pH and a 3-step in vitro digestion assay for pigs. In Exp. 1, Cu sources were incubated in water-based buffers at pH 2.0, 3.0, 4.8, and 6.8 for 4 h using a shaking incubator at 39°C. The CuSO 4 sources were completely dissolved within 15 min except at pH 6.8. The solubility of Cu in dCCTH-α was greater (p<0.05) than dCCTH-β but was not different from dCCTH-αβ during 3-h incubation at pH 2.0 and during 2-h incubation at pH 3.0. At pH 4.8, there were no significant differences in solubility of Cu in dCCTH sources. Copper in dCCTH sources were non-soluble at pH 6.8. In Exp. 2, the solubility of Cu was determined during the 3-step in vitro digestion assay for pigs. All sources of Cu were completely dissolved in step 1 which simulated digestion in the stomach. In Exp. 3, the solubility of Cu in experimental diets including a control diet and diets containing 250 mg/kg of additional Cu from five Cu sources was determined during the in vitro digestion assay. The solubility of Cu in diets containing additional Cu sources were greater (p<0.05) than the control diet in step 1. In conclusion, the solubility of Cu was influenced by pH of digesta but was not different among sources based on the in vitro digestion assay.

In vitro Solubility of Copper(II) Sulfate and Dicopper Chloride Trihydroxide for Pigs

PubMed Central

Park, C. S.; Kim, B. G.

2016-01-01

This study was conducted to determine the solubility of copper (Cu) in two sources of copper(II) sulfate (CuSO4) including monohydrate and pentahydrate and three sources of dicopper chloride trihydroxide (dCCTH) including α-form (dCCTH-α), β-form (dCCTH-β), and a mixture of α- and β-form (dCCTH-αβ) at different pH and a 3-step in vitro digestion assay for pigs. In Exp. 1, Cu sources were incubated in water-based buffers at pH 2.0, 3.0, 4.8, and 6.8 for 4 h using a shaking incubator at 39°C. The CuSO4 sources were completely dissolved within 15 min except at pH 6.8. The solubility of Cu in dCCTH-α was greater (p<0.05) than dCCTH-β but was not different from dCCTH-αβ during 3-h incubation at pH 2.0 and during 2-h incubation at pH 3.0. At pH 4.8, there were no significant differences in solubility of Cu in dCCTH sources. Copper in dCCTH sources were non-soluble at pH 6.8. In Exp. 2, the solubility of Cu was determined during the 3-step in vitro digestion assay for pigs. All sources of Cu were completely dissolved in step 1 which simulated digestion in the stomach. In Exp. 3, the solubility of Cu in experimental diets including a control diet and diets containing 250 mg/kg of additional Cu from five Cu sources was determined during the in vitro digestion assay. The solubility of Cu in diets containing additional Cu sources were greater (p<0.05) than the control diet in step 1. In conclusion, the solubility of Cu was influenced by pH of digesta but was not different among sources based on the in vitro digestion assay. PMID:27456425

An in-situ phosphorus source for the synthesis of Cu 3P and the subsequent conversion to Cu 3PS 4 nanoparticle clusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sheets, Erik J.; Stach, Eric A.; Yang, Wei -Chang

2015-09-20

The search for alternative earth abundant semiconducting nanocrystals for sustainable energy applications has brought forth the need for nanoscale syntheses beyond bulk synthesis routes. Of particular interest are metal phosphides and derivative I-V-VI chalcogenides including copper phosphide (Cu 3P) and copper thiophosphate (Cu 3PS 4). Herein, we report a one-pot, solution-based synthesis of Cu 3P nanocrystals utilizing an in-situ phosphorus source: phosphorus pentasulfide (P 2S 5) in trioctylphosphine (TOP). By injecting this phosphorus source into a copper solution in oleylamine (OLA), uniform and size controlled Cu 3P nanocrystals with a phosphorous-rich surface are synthesized. The subsequent reaction of the Cumore » 3P nanocrystals with decomposing thiourea forms nanoscale Cu 3PS 4 particles having p-type conductivity and an effective optical band gap of 2.36 eV.« less

40 CFR 98.200 - Definition of source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Magnesium Production § 98.200 Definition of source category. The magnesium production and processing source category consists of the following processes: (a) Any process in which magnesium metal is produced through smelting (including electrolytic smelting), refining...

40 CFR 98.200 - Definition of source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Magnesium Production § 98.200 Definition of source category. The magnesium production and processing source category consists of the following processes: (a) Any process in which magnesium metal is produced through smelting (including electrolytic smelting), refining...

40 CFR 98.200 - Definition of source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Magnesium Production § 98.200 Definition of source category. The magnesium production and processing source category consists of the following processes: (a) Any process in which magnesium metal is produced through smelting (including electrolytic smelting), refining...

40 CFR 98.200 - Definition of source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Magnesium Production § 98.200 Definition of source category. The magnesium production and processing source category consists of the following processes: (a) Any process in which magnesium metal is produced through smelting (including electrolytic smelting), refining...

40 CFR 464.36 - Pretreatment standards for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... metal poured Copper (T) 0.0129 0.0071 Lead (T) 0.0237 0.0116 Zinc (T) 0.0437 0.0165 (2) Applicable to...) of metal poured Copper (T) 0.0129 0.0071 Lead (T) 0.0353 0.0174 Zinc (T) 0.0656 0.025 (b) Casting... million pounds) of metal poured Copper (T) 0.0138 0.0076 Lead (T) 0.0252 0.0124 Zinc (T) 0.0466 0.0176 TTO...

40 CFR 464.36 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... metal poured Copper (T) 0.0129 0.0071 Lead (T) 0.0237 0.0116 Zinc (T) 0.0437 0.0165 (2) Applicable to...) of metal poured Copper (T) 0.0129 0.0071 Lead (T) 0.0353 0.0174 Zinc (T) 0.0656 0.025 (b) Casting... million pounds) of metal poured Copper (T) 0.0138 0.0076 Lead (T) 0.0252 0.0124 Zinc (T) 0.0466 0.0176 TTO...

40 CFR 63.5485 - Am I subject to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... manufacturing includes both the Miscellaneous Viscose Processes source category and the Cellulose Ethers Production source category. The Miscellaneous Viscose Processes source category includes all of the operations that use the viscose process. These operations include the cellulose food casing, rayon...

Biliary copper excretion by hepatocyte lysosomes in the rat. Major excretory pathway in experimental copper overload

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gross, J.B. Jr.; Myers, B.M.; Kost, L.J.

1989-01-01

We investigated the hypothesis that lysosomes are the main source of biliary copper in conditions of hepatic copper overload. We used a rat model of oral copper loading and studied the relationship between the biliary output of copper and lysosomal hydrolases. Male Sprague-Dawley rats were given tap water with or without 0.125% copper acetate for up to 36 wk. Copper loading produced a 23-fold increase in the hepatic copper concentration and a 30-65% increase in hepatic lysosomal enzyme activity. Acid phosphatase histochemistry showed that copper-loaded livers contained an increased number of hepatocyte lysosomes; increased copper concentration of these organelles wasmore » confirmed directly by both x ray microanalysis and tissue fractionation. The copper-loaded rats showed a 16-fold increase in biliary copper output and a 50-300% increase in biliary lysosomal enzyme output. In the basal state, excretory profiles over time were similar for biliary outputs of lysosomal enzymes and copper in the copper-loaded animals but not in controls. After pharmacologic stimulation of lysosomal exocytosis, biliary outputs of copper and lysosomal hydrolases in the copper-loaded animals remained coupled: injection of colchicine or vinblastine produced an acute rise in the biliary output of both lysosomal enzymes and copper to 150-250% of baseline rates. After these same drugs, control animals showed only the expected increase in lysosomal enzyme output without a corresponding increase in copper output. We conclude that the hepatocyte responds to an increased copper load by sequestering excess copper in an increased number of lysosomes that then empty their contents directly into bile. The results provide direct evidence that exocytosis of lysosomal contents into biliary canaliculi is the major mechanism for biliary copper excretion in hepatic copper overload.« less

A pyrazolyl-based thiolato single-source precursor for the selective synthesis of isotropic copper-deficient copper(I) sulfide nanocrystals: synthesis, optical and photocatalytic activity

NASA Astrophysics Data System (ADS)

Mondal, Gopinath; Santra, Ananyakumari; Bera, Pradip; Acharjya, Moumita; Jana, Sumanta; Chattopadhyay, Dipankar; Mondal, Anup; Seok, Sang Il; Bera, Pulakesh

2016-10-01

Hexagonal copper-deficient copper(I) sulfide (Cu2- x S, x = 0.03, 0.2) nanocrystals (NCs) are synthesized from a newly prepared single-source precursor (SP), [Cu(bdpa)2][CuCl2], where bdpa is benzyl 3,5-dimethyl-pyrazole-1-carbodithioate. The SP is crystallized with space group Pī and possesses a distorted tetrahedron structure with a CuN2S2 chromophore where the central copper is in +1 oxidation state. Distortion in copper(I) structure and the low decomposition temperature of SP make it favorable for the low-temperature solvent-assisted selective growth of high-copper content sulfides. The nucleation and growth of Cu2- x S ( x = 0.03, 0.2) are effectively controlled by the SP and the solvent in the solvothermal decomposition process. During decomposition, fragment benzyl thiol (PhCH2SH) from SP effectively passivates the nucleus leading to spherical nanocrystals. Further, solvent plays an important role in the selective thermochemical transformation of CuI-complex to Cu2- x S ( x = 0.03, 0.2) NCs. The chelating binders (solvent) like ethylene diamine (EN) and ethylene glycol (EG) prefer to form spherical Cu1.97S nanoparticles (djurleite), whereas nonchelating hydrazine hydrate (HH) shows the tendency to furnish hexagonal platelets of copper-deficient Cu1.8S. The optical band gap values (2.25-2.50 eV) show quantum confinement effect in the structure. The synthesized NCs display excellent catalytic activity ( 87 %) toward photodegradation of organic dyes like Congo Red (CR) and Methylene Blue (MB).

All-inorganic large-area low-cost and durable flexible perovskite solar cells using copper foil as a substrate.

PubMed

Abdollahi Nejand, B; Nazari, P; Gharibzadeh, S; Ahmadi, V; Moshaii, A

2017-01-05

Here, a low-cost perovskite solar cell using CuI and ZnO as the respective inorganic hole and electron transport layers is introduced. Copper foil is chosen as a cheap and low-weight conductive substrate which has a similar work function to ITO. Besides, copper foil is an interesting copper atom source for the growth of the upper cuprous iodide layer on copper foil. A spray coating of a transparent silver nanowire electrode is used as a top contact. The prepared device shows a maximum power conversion efficiency of 12.80% and long-term durability providing an environmentally and market friendly perovskite solar cell.

Geochemical prospecting for copper and nickel in the Wulgai and Tor Tangi areas southeast of Hindubagh, Quetta Division, Pakistan

USGS Publications Warehouse

Stanin, S. Anthony; Wahid, M.A.; Khan, Shamsher

1975-01-01

Showings of magnetite, copper, and possible nickel mineralization in the Hindubagh chromite mining district are near Wulgai and Tor Tangi. Several hundred samples of clastic material from dry streambeds in these areas were sieved for the minus-80-mesh fraction and analyzed for copper using 2, 2'-biquinoline and for nickel using alpha-furildioxime. The copper threshold is 75 ppm, and the nickel threshold is 400 ppm. A geochemical map has been prepared that shows nine areas of anomalously high copper and six areas of high nickel. The nickel anomalies may represent secondary dispersion patterns derived from the erosion of nickeliferous ultramafic rocks of the Hindubagh intrusive complex. Copper showings in and near four of the anomalous copper areas indicate that detailed geological investigation and detailed geochemical sampling of rocks, soil, and unconsolidated clastic material are required to determine the source of the anomalies.

Optimization of chemical displacement deposition of copper on porous silicon.

PubMed

Bandarenka, Hanna; Redko, Sergey; Nenzi, Paolo; Balucani, Marco; Bondarenko, Vitaly

2012-11-01

Copper (II) sulfate was used as a source of copper to achieve uniform distribution of Cu particles deposited on porous silicon. Layers of the porous silicon were formed by electrochemical anodization of Si wafers in a mixture of HF, C3H7OH and deionized water. The well-known chemical displacement technique was modified to grow the copper particles of specific sizes. SEM and XRD analysis revealed that the outer surface of the porous silicon was covered with copper particles of the crystal orientation inherited from the planes of porous silicon skeleton. The copper crystals were found to have the cubic face centering elementary cell. In addition, the traces of Cu2O cubic primitive crystalline phases were identified. The dimensions of Cu particles were determined by the Feret's analysis of the SEM images. The sizes of the particles varied widely from a few to hundreds of nanometers. A phenomenological model of copper deposition was proposed.

40 CFR 98.70 - Definition of source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.70 Definition of source category. The ammonia manufacturing source category comprises the process units listed in paragraphs (a) and (b) of this section. (a) Ammonia manufacturing processes in which ammonia is manufactured from a fossil...

40 CFR 98.70 - Definition of source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.70 Definition of source category. The ammonia manufacturing source category comprises the process units listed in paragraphs (a) and (b) of this section. (a) Ammonia manufacturing processes in which ammonia is manufactured from a fossil...

40 CFR 98.70 - Definition of source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.70 Definition of source category. The ammonia manufacturing source category comprises the process units listed in paragraphs (a) and (b) of this section. (a) Ammonia manufacturing processes in which ammonia is manufactured from a fossil...

40 CFR 98.70 - Definition of source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.70 Definition of source category. The ammonia manufacturing source category comprises the process units listed in paragraphs (a) and (b) of this section. (a) Ammonia manufacturing processes in which ammonia is manufactured from a fossil...

40 CFR 98.70 - Definition of source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.70 Definition of source category. The ammonia manufacturing source category comprises the process units listed in paragraphs (a) and (b) of this section. (a) Ammonia manufacturing processes in which ammonia is manufactured from a fossil...

40 CFR 98.40 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.40 Definition of the source category. (a) The electricity generation source category comprises electricity generating units that are subject to the requirements of the Acid Rain Program and any other electricity generating units that are...

40 CFR 98.40 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.40 Definition of the source category. (a) The electricity generation source category comprises electricity generating units that are subject to the requirements of the Acid Rain Program and any other electricity generating units that are...

40 CFR 98.40 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.40 Definition of the source category. (a) The electricity generation source category comprises electricity generating units that are subject to the requirements of the Acid Rain Program and any other electricity generating units that are...

40 CFR 98.40 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.40 Definition of the source category. (a) The electricity generation source category comprises electricity generating units that are subject to the requirements of the Acid Rain Program and any other electricity generating units that are...

40 CFR 98.40 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.40 Definition of the source category. (a) The electricity generation source category comprises electricity generating units that are subject to the requirements of the Acid Rain Program and any other electricity generating units that are...

40 CFR 98.50 - Definition of source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Definition of source category. 98.50 Section 98.50 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Adipic Acid Production § 98.50 Definition of source category...

40 CFR 98.350 - Definition of source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Industrial Wastewater Treatment § 98.350 Definition of source category. (a) This source category consists of anaerobic processes used to treat industrial wastewater and industrial wastewater treatment sludge at facilities that perform the operations listed in this paragraph. (1...

40 CFR 98.350 - Definition of source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Industrial Wastewater Treatment § 98.350 Definition of source category. (a) This source category consists of anaerobic processes used to treat industrial wastewater and industrial wastewater treatment sludge at facilities that perform the operations listed in this paragraph. (1...

40 CFR 98.350 - Definition of source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Industrial Wastewater Treatment § 98.350 Definition of source category. (a) This source category consists of anaerobic processes used to treat industrial wastewater and industrial wastewater treatment sludge at facilities that perform the operations listed in this paragraph. (1...

40 CFR 98.350 - Definition of source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Industrial Wastewater Treatment § 98.350 Definition of source category. (a) This source category consists of anaerobic processes used to treat industrial wastewater and industrial wastewater treatment sludge at facilities that perform the operations listed in this paragraph. (1...

40 CFR 98.50 - Definition of source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Definition of source category. 98.50 Section 98.50 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Adipic Acid Production § 98.50 Definition of source category...

Selective LPCVD growth of graphene on patterned copper and its growth mechanism

NASA Astrophysics Data System (ADS)

Zhang, M.; Huang, B.-C.; Wang, Y.; Woo, J. C. S.

2016-12-01

Copper-catalyzed graphene low-pressure chemical-vapor deposition (LPCVD) growth has been regarded as a viable solution towards its integration to CMOS technology, and the wafer-bonding method provides a reliable alternative for transferring the selective graphene grown on a patterned metal film for IC manufacturing. In this paper, selective LPCVD graphene growth using patterned copper dots has been studied. The Raman spectra of grown films have demonstrated large dependence on the growth conditions. To explain the results, the growth mechanisms based on surface adsorption and copper-vapor-assisted growth are investigated by the comparison between the blanket copper films with/without the additional copper source. The copper vapor density is found to be critical for high-quality graphene growth. In addition, the copper-vapor-assisted growth is also evidenced by the carbon deposition on the SiO2 substrate of the patterned-copper-dot sample and chamber wall during graphene growth. This growth mechanism explains the correlation between the growth condition and Raman spectrum for films on copper dots. The study on the copper-catalyzed selective graphene growth on the hard substrate paves the way for the synthesis and integration of the 2D material in VLSI.

Hydrogeochemical prospecting for porphyry copper deposits in the tropical-marine climate of Puerto Rico

USGS Publications Warehouse

Miller, W.R.; Ficklin, W.H.; Learned, R.E.

1982-01-01

A hydrogeochemical survey utilizing waters from streams and springs was conducted in the area of two known porphyry copper deposits in the tropical-marine climate of westcentral Puerto Rico. The most important pathfinder for regional hydrogeochemical surveys is sulfate which reflects the associated pyrite mineralization. Because of increased mobility due to intense chemical weathering and the low pH environment, dissolved copper can also be used as a pathfinder for regional surveys and has the advantage of distinguishing barren pyrite from pyrite associated with copper mineralization. For follow-up surveys, the most important pathfinders are copper, sulfate, pH, zinc, and fluoride. High concentrations of dissolved copper and moderate concentrations of sulfate is a diagnostic indication of nearby sources of copper minerals. An understanding of the geochemical processes taking place in the streambeds and the weathering environment, such as the precipitation of secondary copper minerals, contributes to the interpretation of the geochemical data and the selection of the most favorable areas for further exploration. ?? 1982.

Diagnostic Sampling to Reveal Hidden Lead and Copper Health Risks

EPA Science Inventory

Lead, copper and other metallic contamination sources in premise drinking water plumbing systems, are unevenly distributed and are usually hidden from thought, view, or both. Many sampling protocols exist, each with some set of implicit assumptions governing its applicability to...

Development and tests of molybdenum armored copper components for MITICA ion source

NASA Astrophysics Data System (ADS)

Pavei, Mauro; Böswirth, Bernd; Greuner, Henri; Marcuzzi, Diego; Rizzolo, Andrea; Valente, Matteo

2016-02-01

In order to prevent detrimental material erosion of components impinged by back-streaming positive D or H ions in the megavolt ITER injector and concept advancement beam source, a solution based on explosion bonding technique has been identified for producing a 1 mm thick molybdenum armour layer on copper substrate, compatible with ITER requirements. Prototypes have been recently manufactured and tested in the high heat flux test facility Garching Large Divertor Sample Test Facility (GLADIS) to check the capability of the molybdenum-copper interface to withstand several thermal shock cycles at high power density. This paper presents both the numerical fluid-dynamic analyses of the prototypes simulating the test conditions in GLADIS as well as the experimental results.

Development and tests of molybdenum armored copper components for MITICA ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pavei, Mauro, E-mail: mauro.pavei@igi.cnr.it; Marcuzzi, Diego; Rizzolo, Andrea

2016-02-15

In order to prevent detrimental material erosion of components impinged by back-streaming positive D or H ions in the megavolt ITER injector and concept advancement beam source, a solution based on explosion bonding technique has been identified for producing a 1 mm thick molybdenum armour layer on copper substrate, compatible with ITER requirements. Prototypes have been recently manufactured and tested in the high heat flux test facility Garching Large Divertor Sample Test Facility (GLADIS) to check the capability of the molybdenum-copper interface to withstand several thermal shock cycles at high power density. This paper presents both the numerical fluid-dynamic analysesmore » of the prototypes simulating the test conditions in GLADIS as well as the experimental results.« less

Development and tests of molybdenum armored copper components for MITICA ion source.

PubMed

Pavei, Mauro; Böswirth, Bernd; Greuner, Henri; Marcuzzi, Diego; Rizzolo, Andrea; Valente, Matteo

2016-02-01

In order to prevent detrimental material erosion of components impinged by back-streaming positive D or H ions in the megavolt ITER injector and concept advancement beam source, a solution based on explosion bonding technique has been identified for producing a 1 mm thick molybdenum armour layer on copper substrate, compatible with ITER requirements. Prototypes have been recently manufactured and tested in the high heat flux test facility Garching Large Divertor Sample Test Facility (GLADIS) to check the capability of the molybdenum-copper interface to withstand several thermal shock cycles at high power density. This paper presents both the numerical fluid-dynamic analyses of the prototypes simulating the test conditions in GLADIS as well as the experimental results.

40 CFR 98.60 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Definition of the source category. 98.60 Section 98.60 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Aluminum Production § 98.60 Definition of the source category...

40 CFR 98.80 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Definition of the source category. 98.80 Section 98.80 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.80 Definition of the source category...

40 CFR 98.60 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Definition of the source category. 98.60 Section 98.60 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Aluminum Production § 98.60 Definition of the source category...

40 CFR 98.80 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Definition of the source category. 98.80 Section 98.80 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.80 Definition of the source category...

The effect of verbal context on olfactory neural responses.

PubMed

Bensafi, Moustafa; Croy, Ilona; Phillips, Nicola; Rouby, Catherine; Sezille, Caroline; Gerber, Johannes; Small, Dana M; Hummel, Thomas

2014-03-01

Odor names refer usually to "source" object categories. For example, the smell of rose is often described with its source category (flower). However, linguistic studies suggest that odors can also be named with labels referring to categories of "practices". This is the case when rose odor is described with a verbal label referring to its use in fragrance practices ("body lotion," cosmetic for example). It remains unknown whether naming an odor by its practice category influences olfactory neural responses differently than that observed when named with its source category. The aim of this study was to investigate this question. To this end, functional MRI was used in a within-subjects design comparing brain responses to four different odors (peach, chocolate, linden blossom, and rose) under two conditions whereby smells were described either (1) with their source category label (food and flower) or (2) with a practice category label (body lotion). Both types of labels induced activations in secondary olfactory areas (orbitofrontal cortex), whereas only the source label condition induced activation in the cingulate cortex and the insula. In summary, our findings offer a new look at olfactory perception by indicating differential brain responses depending on whether odors are named according to their source or practice category. Copyright © 2012 Wiley Periodicals, Inc.

40 CFR 421.315 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia (as N) 25.990 11.430 Cobalt 0.538 0.236 Tungsten 0.679 0... tungsten produced Copper 3.291 1.569 Nickel 1.414 0.951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111... per million pounds) of tungsten produced Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600...

40 CFR 421.315 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia (as N) 25.990 11.430 Cobalt 0.538 0.236 Tungsten 0.679 0... tungsten produced Copper 3.291 1.569 Nickel 1.414 0.951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111... per million pounds) of tungsten produced Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600...

40 CFR 421.315 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia (as N) 25.990 11.430 Cobalt 0.538 0.236 Tungsten 0.679 0... tungsten produced Copper 3.291 1.569 Nickel 1.414 0.951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111... per million pounds) of tungsten produced Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600...

40 CFR 421.315 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia (as N) 25.990 11.430 Cobalt 0.538 0.236 Tungsten 0.679 0... tungsten produced Copper 3.291 1.569 Nickel 1.414 0.951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111... per million pounds) of tungsten produced Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600...

40 CFR 421.315 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia (as N) 25.990 11.430 Cobalt 0.538 0.236 Tungsten 0.679 0... tungsten produced Copper 3.291 1.569 Nickel 1.414 0.951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111... per million pounds) of tungsten produced Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600...

40 CFR 471.75 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0.003 Chromium 0.013 0.005 Copper 0.044... treated Cadmium 0.006 0.003 Chromium 0.012 0.005 Copper 0.040 0.019 Lead 0.009 0.004 Nickel 0.017 0.012...-pounds) of uranium surface treated Cadmium 0.006 0.002 Chromium 0.010 0.004 Copper 0.035 0.017 Lead 0.008...

40 CFR 471.75 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0.003 Chromium 0.013 0.005 Copper 0.044... treated Cadmium 0.006 0.003 Chromium 0.012 0.005 Copper 0.040 0.019 Lead 0.009 0.004 Nickel 0.017 0.012...-pounds) of uranium surface treated Cadmium 0.006 0.002 Chromium 0.010 0.004 Copper 0.035 0.017 Lead 0.008...

The Landforms of Granitic Rocks: An Annotated Bibliography

DTIC Science & Technology

1990-05-01

major sources of copper , tin, silver, gold, and many other valuable commodities. They are naturally highly radioactive, particularly at depth, and are...et al., 1978). Kesel (1977) cited sheeting and spalling as the major process in central Arizona . Crystal growth, usually salt or ice, is a common...quarries; and 4) aplite veins and dikes. Tin is found on Dartmoor, but copper is common only around the edges. Tin and copper lodes run east-west and

[Spatiotemporal variation characteristics of heavy metals pollution in the water, soil and sediments environment of the Lean River-Poyang Lake Wetland].

PubMed

Jian, Min-Fei; Li, Ling-Yu; Xu, Peng-Fei; Chen, Pu-Qing; Xiong, Jian-Qiu; Zhou, Xue-Ling

2014-05-01

Overlying water, sediments, surface soils in the typical wetland areas of Lean River and Poyang Lake which were rich in non-ferrous metal mineral resources on both sides of the river, were chosen for monitoring heavy metals including copper, lead and cadmium of base flow in average season, flood season, and dry season in 2012. Statistical analysis methods were coupled to characterize the spatiotemporal variation of heavy metals pollution and identify the main sources. The results indicated that the concentrations of copper were the highest in all samples of each sampling sites in the Lean River-Poyang Lake wetland. And the content values of copper, lead and cadmium in different samples of different sampling sites also showed that the content values of copper were higher than those of lead, and the content values of lead were also higher than those of cadmium. The results also showed that the heavy metals pollution of copper, lead and cadmium in flood season was the heaviest whereas the heavy metals pollution in dry season was comparatively light. The results of the contents of the three kinds of heavy metals elements in different sampling sites of the watersheds of lean River showed that the contents of copper in the samples from the upstream sampling sites of Lean River were higher than those of other samples from other sites. And the contents of lead in the samples from the downstream sampling sites of Lean River were higher than those of other samples from other sampling sites. The contents of cadmium in the samples from the midstream sampling sites of Lean River were higher than those of other samples from other sites. The first principal component representing copper pollution explained 36. 99% of the total variance of water quality. The second principal component concerning representing lead pollution explained 30. 12% of the total variance. The correlation analysis results showed that there were significant positive correlations among the contents of copper in sediments and the contents of copper in overlying water. And there was also significant positive correlation between the contents of copper in sediments and the contents of copper in the surface soils. And the correlation analysis showed that there were significant positive correlations among the contents of cadmium in sediments and the contents of cadmium in surface soils. The above results reflected that the copper pollution or cadmium sources of water, soil and sediments were consistent, which were mainly from heavy metal acidic waste of mining emissions. The correlations between other components were not very obvious, which reflected the sources of pollutants were different.

40 CFR 98.80 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.80 Definition of the source category. The cement production source category consists of each kiln and each in-line kiln/raw mill at any portland cement manufacturing facility including alkali bypasses, and includes kilns and in-line kiln/raw...

40 CFR 98.80 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.80 Definition of the source category. The cement production source category consists of each kiln and each in-line kiln/raw mill at any portland cement manufacturing facility including alkali bypasses, and includes kilns and in-line kiln/raw...

40 CFR 98.80 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.80 Definition of the source category. The cement production source category consists of each kiln and each in-line kiln/raw mill at any portland cement manufacturing facility including alkali bypasses, and includes kilns and in-line kiln/raw...

40 CFR 98.150 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING HCFC-22 Production and HFC-23 Destruction § 98.150 Definition of the source category. The HCFC-22 production and HFC-23 destruction source category consists of HCFC-22 production processes and HFC-23 destruction processes. (a) An HCFC-22 production process...

40 CFR 98.150 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING HCFC-22 Production and HFC-23 Destruction § 98.150 Definition of the source category. The HCFC-22 production and HFC-23 destruction source category consists of HCFC-22 production processes and HFC-23 destruction processes. (a) An HCFC-22 production process...

40 CFR 98.180 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Lead Production § 98.180 Definition of the source category. The lead production source category consists of primary lead smelters and secondary lead smelters. A primary lead smelter is a facility engaged in the production of lead metal from lead sulfide ore...

77 FR 15990 - Proposed Confidentiality Determinations for the Petroleum and Natural Gas Systems Source Category...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-19

... Proposed Confidentiality Determinations for the Petroleum and Natural Gas Systems Source Category, and... the Petroleum and Natural Gas Systems Source Category, and Amendments to Table A-7, of the Greenhouse... on the proposed rule titled ``Proposed Confidentiality Determinations for the Petroleum and Natural...

Interlot variations of transition temperature range and force delivery in copper-nickel-titanium orthodontic wires.

PubMed

Pompei-Reynolds, Renée C; Kanavakis, Georgios

2014-08-01

The manufacturing process for copper-nickel-titanium archwires is technique sensitive. The primary aim of this investigation was to examine the interlot consistency of the mechanical properties of copper-nickel-titanium wires from 2 manufacturers. Wires of 2 sizes (0.016 and 0.016 × 0.022 in) and 3 advertised austenite finish temperatures (27°C, 35°C, and 40°C) from 2 manufacturers were tested for transition temperature ranges and force delivery using differential scanning calorimetry and the 3-point bend test, respectively. Variations of these properties were analyzed for statistical significance by calculating the F statistic for equality of variances for transition temperature and force delivery in each group of wires. All statistical analyses were performed at the 0.05 level of significance. Statistically significant interlot variations in austenite finish were found for the 0.016 in/27°C (P = 0.041) and 0.016 × 0.022 in/35°C (P = 0.048) wire categories, and in austenite start for the 0.016 × 0.022 in/35°C wire category (P = 0.01). In addition, significant variations in force delivery were found between the 2 manufacturers for the 0.016 in/27°C (P = 0.002), 0.016 in/35.0°C (P = 0.049), and 0.016 × 0.022 in/35°C (P = 0.031) wires. Orthodontic wires of the same material, dimension, and manufacturer but from different production lots do not always have similar mechanical properties. Clinicians should be aware that copper-nickel-titanium wires might not always deliver the expected force, even when they come from the same manufacturer, because of interlot variations in the performance of the material. Copyright © 2014 American Association of Orthodontists. Published by Mosby, Inc. All rights reserved.

Leaded electronic waste is a possible source material for lead-contaminated jewelry.

PubMed

Weidenhamer, Jeffrey D; Clement, Michael L

2007-10-01

Highly leaded jewelry, often imported from China, remains widely available in the United States. Leaded electronic waste is exported from the United States to several Asian countries where solder is recovered and circuit boards are stripped of parts in small workshops. To assess whether electronic waste is being recycled into the jewelry, lead, tin and copper content of highly leaded jewelry samples were determined by atomic absorption spectrometry. Sixteen jewelry items previously determined to contain 20-80% lead by weight were analyzed. Samples were digested in nitric acid for analysis of lead and copper, and in aqua regia for analysis of tin. Six samples contained significant amounts of tin, from 20.8% to 29.9% by weight. In addition, copper was a significant minor component of five of these samples (up to 4% by weight). Copper (present at 10-40% by weight in circuit boards) was shown to rapidly move into heated lead-tin solder. The combined lead-tin-copper content of these six items ranges from 93.5% to 100%, suggestive of a solder-based source material. These results are consistent with the hypothesis that recycled circuit board solders are being used to produce some of the heavily leaded imported jewelry sold in the United States. Should this hypothesis be substantiated, it suggests that environmental policies to protect children's health must address both proper recycling of source materials as well as restrictions of the lead content in consumer goods.

Copper Recycling in the United States in 2004

USGS Publications Warehouse

Goonan, Thomas G.

2009-01-01

As one of a series of reports that describe the recycling of metal commodities in the United States, this report discusses the flow of copper from production through distribution and use, with particular emphasis on the recycling of industrial scrap (new scrap1) and used products (old scrap) in the year 2004. This materials flow study includes a description of copper supply and demand for the United States to illustrate the extent of copper recycling and to identify recycling trends. Understanding how materials flow from a source through disposition can aid in improving the management of natural resource delivery systems. In 2004, the U.S. refined copper supply was 2.53 million metric tons (Mt) of refined unalloyed copper. With adjustment for refined copper exports of 127,000 metric tons (t) of copper, the net U.S. refined copper supply was 2.14 Mt of copper. With this net supply and a consumer inventory decrease of 9,000 t of refined copper, 2.42 Mt of refined copper was consumed by U.S. semifabricators (brass mills, wire rod mills, ingot makers, and foundries and others) in 2004. In addition to the 2.42 Mt of refined copper consumed in 2004, U.S. copper semifabricators consumed 853,000 t of copper contained in recycled scrap. Furthermore, 61,000 t of copper contained in scrap was consumed by noncopper alloy makers, for example, steelmakers and aluminum alloy makers. Old scrap recycling efficiency for copper was estimated to be 43 percent of theoretical old scrap supply, the recycling rate for copper was 30 percent of apparent supply, and the new-scrap-to-old-scrap ratio for U.S. copper product production was 3.2 (76:24).

Ferric Oxide Mediated Formation of PCDD/Fs from 2-Monochlorophenol

PubMed Central

Nganai, Shadrack; Lomnicki, Slawo; Dellinger, Barry

2012-01-01

The copper oxide, surface-mediated formation of polychlorinated dibenzop-dioxins and dibenzofurans (PCDD/F) from precursors such as chlorinated phenols is considered to be a major source of PCDD/F emissions from combustion sources. In spite of being present at 2–50x higher concentrations than copper oxide, virtually no studies of the iron oxide-mediated formation of PCDD/F have been reported in the literature. We have performed packed bed, flow reactor studies of the reaction of 50 ppm gas phase 2-monochlorophenol (2-MCP) over a surface of 5% iron oxide on silica over a temperature range of 200–500 °C. Dibenzo-p-dioxin (DD), 1-monochlorodibenzo-p-dioxin (1-MCDD), 4,6-dichlorodibenzofuran (4,6-DCDF), and dibenzofuran (DF) were formed in maximum yields of 0.1, 0.2, 0.3, and 0.4 %, respectively. The yield of PCDD/F over iron oxide peaked at temperatures 50–100 °C higher in temperature than over copper oxide. The maximum yields of DD, 1-MCDD and 4,6-DCDF were 2x and 5x higher over iron oxide, respectively, than over copper oxide, while DF was not observed at all for copper oxide. The resulting PCDD/PCDF ratio was 0.39 versus 1.2 observed for iron oxide and copper oxide, respectively, which is in agreement with PCDD to PCDF ratios in full-scale combustors that are typically ≪1. The combination of 2–50x higher concentrations of iron oxide than copper oxide in most full-scale combustors and 2.5x higher yields of PCDD/F observed in the laboratory, suggest that iron oxide may contribute as much as 5–125x more than copper oxide to the emissions of PCDD/F from full-scale combustors. PMID:19238966

CONDITION ASSESSMENT FOLLOWING TMDL IMPLEMENTATION USING CHEMICAL SPECIATION AND VOLUNTEER MONITORING

EPA Science Inventory

The Connecticut Department of Environmental Protection developed a Total Maximum Daily Load (TMDL) for copper toxicity in Steel Brook, Watertown /Oakville, CT in 1999. The analysis identified two major sources of copper to the waters of Steele Brook, but did not include extensiv...

Somatic and Functional Status of Boys from Various Social and Environmental Categories

ERIC Educational Resources Information Center

Domaradzki, Jaroslaw; Ignasiak, Zofia; Slawinska, Teresa

2009-01-01

Study aim: To assess the somatic and fitness status of adolescent boys from polluted industrial areas. Material and methods: A group of 313 boys aged 11-15 years from 5 villages located in the copper mine area in South-Western Poland were classified by the degree of lead and cadmium pollution (high--very high) and by parents' education…

40 CFR 421.92 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORY Metallurgical Acid Plants Subcategory § 421.92 Effluent limitations guidelines representing the...): Subpart I—Metallurgical Acid Plant Pollutant or pollutant property BPT effluent limitations Maximum for... Cadmium 0.180 0.090 Copper 5.000 2.000 Lead 1.800 0.790 Zinc 3.600 0.900 Fluoride 1 212.800 121.000...

40 CFR 421.92 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORY Metallurgical Acid Plants Subcategory § 421.92 Effluent limitations guidelines representing the...): Subpart I—Metallurgical Acid Plant Pollutant or pollutant property BPT effluent limitations Maximum for... Cadmium 0.180 0.090 Copper 5.000 2.000 Lead 1.800 0.790 Zinc 3.600 0.900 Fluoride 1 212.800 121.000...

Nurse Practitioners Experience With Herbal Therapy

DTIC Science & Technology

2000-05-01

and massage therapy, but herbal remedies and aromatherapy and all those things that are coming out: the magnets, the magnetic braces and the copper...potential adverse effects of herbal therapy have been well documented in the literature, but provider response to this phenomenon has not been well...identified nine theme categories related to knowledge, safety, validity and effectiveness , responsibility, time, cost, complementary vs. Western medicine

The effect of copper from water and food: changes of serum nonceruloplasmin copper and brain's amyloid-beta in mice.

PubMed

Wu, Min; Han, Feifei; Gong, Weisha; Feng, Lifang; Han, Jianzhong

2016-09-14

Copper is an essential element and also produces adverse health consequences when overloaded. Food and water are the main sources of copper intake, however few studies have been conducted to investigate the difference between the ways of its intake in water and food in animals. In this study, copper was fed to mice with food as well as water (two groups: water and diet) for three months at concentrations of 6, 15 and 30 ppm. The copper concentration in water was adjusted for keeping the same amount during its intake in food. The experimental studies show a slow growth rate, lower hepatic reduced glutathione (GSH)/superoxide dismutase (SOD) activity and higher serum 'free' copper in the water group. The brain's soluble amyloid-beta 1-42 (Aβ42) of the water group was significantly higher than that of the diet group at the levels of 6 and 15 ppm. In conclusion, copper in the water group significantly increased the soluble Aβ42 in the brain and the 'free' copper in the serum, decreased the growth rate and hepatic GSH/SOD activity. The research studies carried out suggest that the copper in water is more 'toxic' than copper in diet and may increase the risk of Alzheimer's disease (AD).

The mammalian phosphate carrier SLC25A3 is a mitochondrial copper transporter required for cytochrome c oxidase biogenesis

PubMed Central

Boulet, Aren; Vest, Katherine E.; Maynard, Margaret K.; Gammon, Micah G.; Russell, Antoinette C.; Mathews, Alexander T.; Cole, Shelbie E.; Zhu, Xinyu; Phillips, Casey B.; Kwong, Jennifer Q.; Dodani, Sheel C.; Leary, Scot C.; Cobine, Paul A.

2018-01-01

Copper is required for the activity of cytochrome c oxidase (COX), the terminal electron-accepting complex of the mitochondrial respiratory chain. The likely source of copper used for COX biogenesis is a labile pool found in the mitochondrial matrix. In mammals, the proteins that transport copper across the inner mitochondrial membrane remain unknown. We previously reported that the mitochondrial carrier family protein Pic2 in budding yeast is a copper importer. The closest Pic2 ortholog in mammalian cells is the mitochondrial phosphate carrier SLC25A3. Here, to investigate whether SLC25A3 also transports copper, we manipulated its expression in several murine and human cell lines. SLC25A3 knockdown or deletion consistently resulted in an isolated COX deficiency in these cells, and copper addition to the culture medium suppressed these biochemical defects. Consistent with a conserved role for SLC25A3 in copper transport, its heterologous expression in yeast complemented copper-specific defects observed upon deletion of PIC2. Additionally, assays in Lactococcus lactis and in reconstituted liposomes directly demonstrated that SLC25A3 functions as a copper transporter. Taken together, these data indicate that SLC25A3 can transport copper both in vitro and in vivo. PMID:29237729

A baseline study on the concentration of trace elements in the surface sediments off Southwest coast of Tamil Nadu, India.

PubMed

Godson, Prince S; Magesh, N S; Peter, T Simon; Chandrasekar, N; Krishnakumar, S; Vincent, Salom Gnana Thanga

2018-01-01

Forty two surface sediment samples were collected in order to document baseline elemental concentration along the Southwest coast of Tamil Nadu, India. The elements detected were Manganese (Mn), Zinc (Zn), Iron (Fe), Copper (Cu), Nickel (Ni) and Lead (Pb). The concentration of Fe and Mn was primarily controlled by the riverine input. The source of Pb and Zn is attributed to leaded petrol and anti-biofouling paints. The calculated index (EF, Igeo and CF) suggests that the sediments of the study area are significantly enriched with all elements except Pb. The contamination factor showed the order of Mn>Zn>Fe>Cu>Ni>Pb. The sediment pollution index (SPI) revealed that the sediments belonged to low polluted to dangerous category. The correlation matrix and dendrogram showed that the elemental distribution was chiefly controlled by riverine input as well as anthropogenic activity in the coast. Copyright © 2017 Elsevier Ltd. All rights reserved.

Copper in the sediment and sea surface microlayer near a fallowed, open-net fish farm.

PubMed

Loucks, Ronald H; Smith, Ruth E; Fisher, Clyde V; Fisher, E Brian

2012-09-01

Sediment and sea surface microlayer samples near an open-net salmon farm in Nova Scotia, were analysed for copper. Copper is a constituent of the feed and is an active ingredient of anti-foulants. The salmon farm was placed in fallow after 15 years of production. Sampling was pursued over 27 months. Elevated copper concentrations in the sediments indicated the farm site as a source. Bubble flotation due to gas-emitting sediments from eutrophication is a likely process for accumulating copper in the sea surface microlayer at enriched concentrations. Elevated and enriched concentrations in the sea surface microlayer over distance from the farm site led, as a result of wind-drift, to an enlarged farm footprint. The levels of copper in both sediments and sea surface microlayer exceeded guidelines for protection of marine life. Over the 27 months period, copper levels persisted in the sediments and decreased gradually in the sea surface microlayer. Copyright © 2012 Elsevier Ltd. All rights reserved.

Copper signaling in the brain and beyond.

PubMed

Ackerman, Cheri M; Chang, Christopher J

2018-03-30

Transition metals have been recognized and studied primarily in the context of their essential roles as structural and metabolic cofactors for biomolecules that compose living systems. More recently, an emerging paradigm of transition-metal signaling, where dynamic changes in transitional metal pools can modulate protein function, cell fate, and organism health and disease, has broadened our view of the potential contributions of these essential nutrients in biology. Using copper as a canonical example of transition-metal signaling, we highlight key experiments where direct measurement and/or visualization of dynamic copper pools, in combination with biochemical, physiological, and behavioral studies, have deciphered sources, targets, and physiological effects of copper signals.

Copper in household drinking water in the city of Zagreb, Croatia.

PubMed

Pizent, Alica; Butković, Sanja

2010-09-01

Copper concentration was estimated in tap water samples obtained from 70 households in Zagreb, serviced by a public water supply system. First-draw and flushed samples of tap water were collected in the morning and total copper concentration was determined by graphite furnace atomic absorption spectrometry with Zeeman-effect background correction. We also estimated the contribution of plumbing material to copper concentrations in tap water. In households with copper pipes, median and range copper values were 310 μg L-1 [(27 to 632) μg L-1] in first-draw samples and 16 μg L-1 [(5 to 52) μg L-1] in flushed samples. Corresponding values for households with galvanised pipes were 140 μg L-1 [(11 to 289) μg L-1] and 8 μg L-1 [(1 to 42) μg L-1], respectively. Copper concentrations in household tap water in Zagreb were far below the proposed safe limits set by the Croatian and WHO regulations and EPA standards, and drinking water in Zagreb is not a significant source of copper exposure.

Evolution of a Heavy Metal Homeostasis/Resistance Island Reflects Increasing Copper Stress in Enterobacteria

PubMed Central

Staehlin, Benjamin M.; Gibbons, John G.; Rokas, Antonis; O’Halloran, Thomas V.; Slot, Jason C.

2016-01-01

Copper homeostasis in bacteria is challenged by periodic elevation of copper levels in the environment, arising from both natural sources and human inputs. Several mechanisms have evolved to efflux copper from bacterial cells, including the cus (copper sensing copper efflux system), and pco (plasmid-borne copper resistance system) systems. The genes belonging to these two systems can be physically clustered in a Copper Homeostasis and Silver Resistance Island (CHASRI) on both plasmids and chromosomes in Enterobacteria. Increasing use of copper in agricultural and industrial applications raises questions about the role of human activity in the evolution of novel copper resistance mechanisms. Here we present evidence that CHASRI emerged and diversified in response to copper deposition across aerobic and anaerobic environments. An analysis of diversification rates and a molecular clock model suggest that CHASRI experienced repeated episodes of elevated diversification that could correspond to peaks in human copper production. Phylogenetic analyses suggest that CHASRI originated in a relative of Enterobacter cloacae as the ultimate product of sequential assembly of several pre-existing two-gene modules. Once assembled, CHASRI dispersed via horizontal gene transfer within Enterobacteriaceae and also to certain members of Shewanellaceae, where the original pco module was replaced by a divergent pco homolog. Analyses of copper stress mitigation suggest that CHASRI confers increased resistance aerobically, anaerobically, and during shifts between aerobic and anaerobic environments, which could explain its persistence in facultative anaerobes and emergent enteric pathogens. PMID:26893455

Concentrations and sources of cadmium, copper, lead and zinc in house dust in Christchurch, New Zealand.

PubMed

Kim, N; Fergusson, J

1993-09-30

The amounts (microgram m-2) and concentrations (microgram g-1) of cadmium, copper, lead and zinc have been measured in house dust in Christchurch, New Zealand. For 120 houses surveyed the geometric mean concentrations of the four metals are 4.24 micrograms g-1, 165 micrograms g-1, 573 micrograms g-1 and 10,400 micrograms g-1, respectively. In addition eleven variables, such as house age, carpet wear and traffic density, were recorded for each property and the results analysed with respect to their effects on the amounts and concentrations of the four elements. The amounts of all the metals were highly correlated with the overall dustiness of the houses, which was found to be predominantly determined by the degree of carpet wear. No one dominant source of cadmium was identified, although several minor sources including carpet wear, galvanized iron roofs and red/orange/yellow coloured carpets were implicated. Petrol lead and lead-based paints were identified as significant sources of lead in house dust. Rubber carpet underlays or backings were identified as a significant source of zinc, with some contribution from galvanized iron roofs. Road traffic and probably the existence of a fire place appear to contribute to the copper levels.

The evaluation of sources of knowledge underlying different conceptual categories.

PubMed

Gainotti, Guido; Spinelli, Pietro; Scaricamazza, Eugenia; Marra, Camillo

2013-01-01

According to the "embodied cognition" theory and the "sensory-motor model of semantic knowledge": (a) concepts are represented in the brain in the same format in which they are constructed by the sensory-motor system and (b) various conceptual categories differ according to the weight of different kinds of information in their representation. In this study, we tried to check the second assumption by asking normal elderly subjects to subjectively evaluate the role of various perceptual, motor and language-mediated sources of knowledge in the construction of different semantic categories. Our first aim was to rate the influence of different sources of knowledge in the representation of animals, plant life and artifact categories, rather than in living and non-living beings, as many previous studies on this subject have done. We also tried to check the influence of age and stimulus modality on these evaluations of the "sources of knowledge" underlying different conceptual categories. The influence of age was checked by comparing results obtained in our group of elderly subjects with those obtained in a previous study, conducted with a similar methodology on a sample of young students. And the influence of stimulus modality was assessed by presenting the stimuli in the verbal modality to 50 subjects and in the pictorial modality to 50 other subjects. The distinction between "animals" and "plant life" in the "living" categories was confirmed by analyzing their prevalent sources of knowledge and by a cluster analysis, which allowed us to distinguish "plant life" items from animals. Furthermore, results of the study showed: (a) that our subjects considered the visual modality as the main source of knowledge for all categories taken into account; and (b) that in biological categories the next most important source of information was represented by other perceptual modalities, whereas in artifacts it was represented by the actions performed with them. Finally, age and stimulus modality did not significantly influence judgment of relevance of the sources of knowledge involved in the construction of different conceptual categories.

40 CFR 98.3 - What are the general monitoring, reporting, recordkeeping and verification requirements of this...

Code of Federal Regulations, 2010 CFR

2010-07-01

... CO2) aggregated for all GHG from all applicable source categories in subparts C through JJ of this... emissions of biogenic CO2 aggregated for all applicable source categories in subparts C through JJ of this part. (iii) Annual emissions from each applicable source category in subparts C through JJ of this part...

26 CFR 1.904(b)-1 - Special rules for capital gains and losses.

Code of Federal Regulations, 2011 CFR

2011-04-01

... in the passive category, and a $2,000 capital loss from sources within the United States. A's capital... sources outside the United States in the passive category by $2,000 ($3,000 of capital gain net income... adjustment, A has $4,000 of capital gain from sources outside the United States in the passive category and...

26 CFR 1.904(b)-1 - Special rules for capital gains and losses.

Code of Federal Regulations, 2010 CFR

2010-04-01

... in the passive category, and a $2,000 capital loss from sources within the United States. A's capital... sources outside the United States in the passive category by $2,000 ($3,000 of capital gain net income... adjustment, A has $4,000 of capital gain from sources outside the United States in the passive category and...

Use of the Biotic Ligand Model to predict metal toxicity to aquatic biota in areas of differing geology

USGS Publications Warehouse

Smith, Kathleen S.

2005-01-01

This work evaluates the use of the biotic ligand model (BLM), an aquatic toxicity model, to predict toxic effects of metals on aquatic biota in areas underlain by different rock types. The chemical composition of water, soil, and sediment is largely derived from the composition of the underlying rock. Geologic source materials control key attributes of water chemistry that affect metal toxicity to aquatic biota, including: 1) potentially toxic elements, 2) alkalinity, 3) total dissolved solids, and 4) soluble major elements, such as Ca and Mg, which contribute to water hardness. Miller (2002) compiled chemical data for water samples collected in watersheds underlain by ten different rock types, and in a mineralized area in western Colorado. He found that each rock type has a unique range of water chemistry. In this study, the ten rock types were grouped into two general categories, igneous and sedimentary. Water collected in watersheds underlain by sedimentary rock has higher mean pH, alkalinity, and calcium concentrations than water collected in watersheds underlain by igneous rock. Water collected in the mineralized area had elevated concentrations of calcium and sulfate in addition to other chemical constituents. Miller's water-chemistry data were used in the BLM (computer program) to determine copper and zinc toxicity to Daphnia magna. Modeling results show that waters from watersheds underlain by different rock types have characteristic ranges of predicted LC 50 values (a measurement of aquatic toxicity) for copper and zinc, with watersheds underlain by igneous rock having lower predicted LC 50 values than watersheds underlain by sedimentary rock. Lower predicted LC 50 values suggest that aquatic biota in watersheds underlain by igneous rock may be more vulnerable to copper and zinc inputs than aquatic biota in watersheds underlain by sedimentary rock. For both copper and zinc, there is a trend of increasing predicted LC 50 values with increasing dissolved organic carbon (DOC) concentrations. Predicted copper LC 50 values are extremely sensitive to DOC concentrations, whereas alkalinity appears to have an influence on zinc toxicity at alkalinities in excess of about 100 mg/L CaCO 3 . These findings show promise for coupling the BLM (computer program) with measured water-chemistry data to predict metal toxicity to aquatic biota in different geologic settings and under different scenarios. This approach may ultimately be a useful tool for mine-site planning, mitigation and remediation strategies, and ecological risk assessment.

Molecular Cloning and Characteristic Features of a Novel Extracellular Tyrosinase from Aspergillus niger PA2.

PubMed

Agarwal, Pragati; Singh, Jyoti; Singh, R P

2017-05-01

Aspergillus niger PA2, a novel strain isolated from waste effluents of food industry, is a potential extracellular tyrosinase producer. Enzyme activity and L-DOPA production were maximum when glucose and peptone were employed as C source and nitrogen source respectively in the medium and enhanced notably when the copper was supplemented, thus depicting the significance of copper in tyrosinase activity. Tyrosinase-encoding gene from the fungus was cloned, and amplification of the tyrosinase gene yielded a 1127-bp DNA fragment and 374 amino acid residue long product that encoded for a predicted protein of 42.3 kDa with an isoelectric point of 4.8. Primary sequence analysis of A. niger PA2 tyrosinase had shown that it had approximately 99% identity with that of A. niger CBS 513.88, which was further confirmed by phylogenetic analysis. The inferred amino acid sequence of A. niger tyrosinase contained two putative copper-binding sites comprising of six histidines, a characteristic feature for type-3 copper proteins, which were highly conserved in all tyrosinases throughout the Aspergillus species. When superimposed onto the tertiary structure of A. oryzae tyrosinase, the conserved residues from both the organisms occupied same spatial positions to provide a di-copper-binding peptide groove.

40 CFR 421.32 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORY Secondary Aluminum Smelting Subcategory § 421.32 Effluent limitations guidelines representing the... to the provisions of this subpart and which uses aluminum fluoride in its magnesium removal process... Fluoride 0.4 Ammonia (as N) 0.01 Aluminum 1.0 Copper 0.003 COD 1.0 pH (1) 1 Within the range of 7.5 to 9.0. ...

40 CFR 471.72 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2014 CFR

2014-07-01

... CATEGORY Uranium Forming Subcategory § 471.72 Effluent limitations representing the degree of effluent... Maximum for monthly average mg/off-kg (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0... extruded or forged uranium heat treated Cadmium 0.006 0.003 Chromium 0.012 0.005 Copper 0.040 0.019 Lead 0...

40 CFR 471.72 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2012 CFR

2012-07-01

... CATEGORY Uranium Forming Subcategory § 471.72 Effluent limitations representing the degree of effluent... Maximum for monthly average mg/off-kg (pounds per million off-pounds) of uranium extruded Cadmium 0.007 0... extruded or forged uranium heat treated Cadmium 0.006 0.003 Chromium 0.012 0.005 Copper 0.040 0.019 Lead 0...

The mammalian phosphate carrier SLC25A3 is a mitochondrial copper transporter required for cytochrome c oxidase biogenesis.

PubMed

Boulet, Aren; Vest, Katherine E; Maynard, Margaret K; Gammon, Micah G; Russell, Antoinette C; Mathews, Alexander T; Cole, Shelbie E; Zhu, Xinyu; Phillips, Casey B; Kwong, Jennifer Q; Dodani, Sheel C; Leary, Scot C; Cobine, Paul A

2018-02-09

Copper is required for the activity of cytochrome c oxidase (COX), the terminal electron-accepting complex of the mitochondrial respiratory chain. The likely source of copper used for COX biogenesis is a labile pool found in the mitochondrial matrix. In mammals, the proteins that transport copper across the inner mitochondrial membrane remain unknown. We previously reported that the mitochondrial carrier family protein Pic2 in budding yeast is a copper importer. The closest Pic2 ortholog in mammalian cells is the mitochondrial phosphate carrier SLC25A3. Here, to investigate whether SLC25A3 also transports copper, we manipulated its expression in several murine and human cell lines. SLC25A3 knockdown or deletion consistently resulted in an isolated COX deficiency in these cells, and copper addition to the culture medium suppressed these biochemical defects. Consistent with a conserved role for SLC25A3 in copper transport, its heterologous expression in yeast complemented copper-specific defects observed upon deletion of PIC2 Additionally, assays in Lactococcus lactis and in reconstituted liposomes directly demonstrated that SLC25A3 functions as a copper transporter. Taken together, these data indicate that SLC25A3 can transport copper both in vitro and in vivo . © 2018 by The American Society for Biochemistry and Molecular Biology, Inc.

Towards a thermally regenerative all-copper redox flow battery.

PubMed

Peljo, Pekka; Lloyd, David; Doan, Nguyet; Majaneva, Marko; Kontturi, Kyösti

2014-02-21

An all-copper redox flow battery based on strong complexation of Cu(+) with acetonitrile is demonstrated, exhibiting reasonable battery performance. More interestingly, the battery can be charged by heat sources of 100 °C, by distilling off the acetonitrile. This destabilizes the Cu(+) complex, leading to recovery of the starting materials.

Examination of commercially available copper oxide wire particles in combination with albendazole for control of gastrointestinal nematodes in lambs

USDA-ARS?s Scientific Manuscript database

Alternatives to synthetic anthelmintics remain critical due to the prevalence of anthelmintic resistance. The objective of the experiment was to determine the efficacy of copper oxide wire particles (COWP) from three commercial sources to control Haemonchus contortus in lambs. Naturally infected Ka...

Copper-catalyzed α-amination of aliphatic aldehydes.

PubMed

Tian, Jie-Sheng; Loh, Teck-Peng

2011-05-21

A highly efficient copper-catalyzed α-amination of aliphatic aldehydes for the synthesis of α-amino acetals using secondary amines with readily removable protecting groups as a nitrogen source was developed. This reaction can be operated under very mild conditions, affording the desired products in moderate to good yields. © The Royal Society of Chemistry 2011

The deep structure of a sea-floor hydrothermal deposit

USGS Publications Warehouse

Zierenberg, R.A.; Fouquet, Y.; Miller, D.J.; Bahr, J.M.; Baker, P.A.; Bjerkgard, T.; Brunner, C.A.; Duckworth, R.C.; Gable, R.; Gieskes, J.; Goodfellow, W.D.; Groschel-Becker, H. M.; Guerin, G.; Ishibashi, J.; Iturrino, G.; James, R.H.; Lackschewitz, K.S.; Marquez, L.L.; Nehlig, P.; Peter, J.M.; Rigsby, C.A.; Schultheiss, P.; Shanks, Wayne C.; Simoneit, B.R.T.; Summit, M.; Teagle, D.A.H.; Urbat, M.; Zuffa, G.G.

1998-01-01

Hydrothermal circulation at the crests of mid-ocean ridges plays an important role in transferring heat from the interior of the Earth. A consequence of this hydrothermal circulation is the formation of metallic ore bodies known as volcanic-associated massive sulphide deposits. Such deposits, preserved on land, were important sources of copper for ancient civilizations and continue to provide a significant source of base metals (for example, copper and zinc). Here we present results from Ocean Drilling Program Leg 169, which drilled through a massive sulphide deposit on the northern Juan de Fuca spreading centre and penetrated the hydrothermal feeder zone through which the metal-rich fluids reached the sea floor. We found that the style of feeder-zone mineralization changes with depth in response to changes in the pore pressure of the hydrothermal fluids and discovered a stratified zone of high-grade copper-rich replacement mineralization below the massive sulphide deposit. This copper-rich zone represents a type of mineralization not previously observed below sea-floor deposits, and may provide new targets for land-based mineral exploration.

Storm water runoff measurements of copper from a naturally patinated roof and from a parking space. Aspects on environmental fate and chemical speciation.

PubMed

Odnevall Wallinder, I; Hedberg, Y; Dromberg, P

2009-12-01

Release of copper from a naturally aged copper roof on a shopping centre building in a suburban site of Stockholm has been measured during different rain events after its interaction with the internal drainage system and storm drains made of cast iron and concrete. Concentrations of copper removed by means of urban storm water from a nearby parking space have been determined for comparison. Predictions and measurements of the chemical speciation of released copper are discussed compared to the total concentration, and to threshold values for freshwater and drinking water. The results clearly illustrate that the major part of the released copper from the roof is readily retained already during transport through the internal drainage system of the building, a pathway that also changes the chemical speciation of released copper and its bioavailable fraction. Most copper, not retained by cast iron and concrete surfaces, was strongly complexed to organic matter. The median concentration of free cupric ions and weak copper complexes was less than, or within the range of reported no effect concentrations, NOECs, of copper in surface waters. The parking space contributed with significantly higher and time-dependent concentrations of total copper compared to measured concentrations of copper from the roof after the interaction with the drainage system. Most copper in the surface runoff water was strongly complexed with organic matter, hence reducing the bioavailable fraction significantly to concentrations within the NOEC range. Dilution with other sources of urban storm water will reduce the released concentration of copper even further. The results illustrate that already the internal drainage system and the storm drains made of cast iron and concrete act as efficient sinks for released copper which means that any installation of additional infiltration devices is redundant.

Aortic sudanophilia an zinc-copper ratios in the liver of vervet monkeys fed different types of dietary fibre.

PubMed

Klevay, L M; Mendelsohn, D; Vanderwatt, J J; Davidson, L M; Kritchevsky, D

1981-04-18

Vervet monkeys (Cercopithecus aethiops pygerethrus) were fed a semipurified diet containing 40% sucrose, 25% casein, 14% hydrogenated coconut oil and 15% fibre for 6 months. Alfalfa, cellulose, or wheat straw was the source of the fibre. All the diets led to aortic sudanophilia, but the group fed wheat straw had the highest copper level in the liver and the least sudanophilia. The order to severity of the sudanophilia, the ratio of zinc to copper in the fibers, and the ratio of zinc to copper in the liver were: alfalfa-fed group greater than cellulose-fed group greater than wheat straw-fed group. These findings, which may have resulted from the relatively large amount of copper in the wheat straw, are consonant with observations on lipid metabolism in other species.

40 CFR 98.400 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.400 Definition of the source category. This supplier category consists of natural gas liquids fractionators and local natural gas distribution companies. (a) Natural gas liquids fractionators are installations that...

40 CFR 98.400 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.400 Definition of the source category. This supplier category consists of natural gas liquids fractionators and local natural gas distribution companies. (a) Natural gas liquids fractionators are installations that...

40 CFR 98.400 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.400 Definition of the source category. This supplier category consists of natural gas liquids fractionators and local natural gas distribution companies. (a) Natural gas liquids fractionators are installations that...

40 CFR 98.400 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.400 Definition of the source category. This supplier category consists of natural gas liquids fractionators and local natural gas distribution companies. (a) Natural gas liquids fractionators are installations that...

40 CFR 98.400 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.400 Definition of the source category. This supplier category consists of natural gas liquids fractionators and local natural gas distribution companies. (a) Natural gas liquids fractionators are installations that...

Emission of PCDD/Fs and dioxin-like PCBs from metallurgy industries in S. Korea.

PubMed

Yu, Byeong-Woon; Jin, Guang-Zhu; Moon, Young-Hoon; Kim, Min-Kwan; Kyoung, Jong-Dai; Chang, Yoon-Seok

2006-01-01

The metallurgy industry and municipal waste incinerators are considered the main sources of polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) in many countries. This study investigated the emission factors and total emissions of PCDD/Fs and dioxin-like polychlorinated biphenyls (PCBs) emitted from metallurgy industries (including ferrous and nonferrous foundries) in Korea. The toxic equivalency (TEQ) emission factor of PCDD/Fs was the highest for secondary copper production, at 24451 ng I-TEQ/ton. The total estimated emissions of PCDD/Fs from these sources were 35.259 g I-TEQ/yr, comprising 0.088 g I-TEQ/yr from ferrous foundries, 31.713 g I-TEQ/yr from copper production, 1.716 g I-TEQ/yr from lead production, 0.111 g I-TEQ/yr from zinc production, and 1.631 g I-TEQ/yr from aluminum production. The total estimated annual amounts of dioxin-like PCBs emitted from these sources were 13.260 g WHO-TEQ/yr, comprising 0.014 g WHO-TEQ/yr from ferrous foundries, 12.675 g WHO-TEQ/yr from copper production, 0.170 g WHO-TEQ/yr from lead production, 0.017 g WHO-TEQ/yr from zinc production, and 0.384 g WHO-TEQ/yr from aluminum production. The highest emission factor was found for secondary copper smelting, at 9770 ng WHO-TEQ/ton.

Increased iron supplied through Fet3p results in replicative life span extension of Saccharomyces cerevisiae under conditions requiring respiratory metabolism.

PubMed

Botta, Gabriela; Turn, Christina S; Quintyne, Nicholas J; Kirchman, Paul A

2011-10-01

We have previously shown that copper supplementation extends the replicative life span of Saccharomyces cerevisiae when grown under conditions forcing cells to respire. We now show that copper's effect on life span is through Fet3p, a copper containing enzyme responsible for high affinity transport of iron into yeast cells. Life span extensions can also be obtained by supplementing the growth medium with 1mM ferric chloride. Extension by high iron levels is still dependent on the presence of Fet3p. Life span extension by iron or copper requires growth on media containing glycerol as the sole carbon source, which forces yeast to respire. Yeast grown on glucose containing media supplemented with iron show no extension of life span. The iron associated with cells grown in media supplemented with copper or iron is 1.4-1.8 times that of cells grown without copper or iron supplementation. As with copper supplementation, iron supplementation partially rescues the life span of superoxide dismutase mutants. Cells grown with copper supplementation display decreased production of superoxide as measured by dihydroethidium staining. Copyright © 2011 Elsevier Inc. All rights reserved.

Investigation of the possibility of copper recovery from the flotation tailings by acid leaching.

PubMed

Antonijević, M M; Dimitrijević, M D; Stevanović, Z O; Serbula, S M; Bogdanovic, G D

2008-10-01

The flotation tailings pond of the Bor Copper Mine poses a great ecological problem not only for the town of Bor but also for the surrounding soils and watercourses. Since the old flotation tailings contain about 0.2% of copper on the average, we investigated their leaching with sulphuric acid in the absence and presence of an oxidant. The aim was to determine the leaching kinetics of copper and iron as affected by various factors such as: the pH value of the leach solution, stirring speed, pulp density, particle size, concentration of ferric ions, temperature and time for leaching. The average copper and iron recovery obtained was from 60% to 70% and from 2% to 3%, respectively. These results indicate that the old flotation tailings pond represents an important source of secondary raw material for the extraction of copper and that it should be valorized rather than land reclamation. At the end of the paper, a mechanism of dissolution of copper and iron minerals from the tailings was described.

Laser-Induced, Local Oxidation of Copper Nanoparticle Films During Raman Measurements

NASA Astrophysics Data System (ADS)

Hight Walker, Angela R.; Cheng, Guangjun; Calizo, Irene

2011-03-01

The optical properties of gold and silver nanoparticles and their films have been thoroughly investigated as surface enhanced Raman scattering (SERS) substrates and chemical reaction promoters. Similar to gold and silver nanoparticles, copper nanoparticles exhibit distinct plasmon absorptions in the visible region. The work on copper nanoparticles and their films is limited due to their oxidization in air. However, their high reactivity actually provides an opportunity to exploit the laser-induced thermal effect and chemical reactions of these nanoparticles. Here, we present our investigation of the local oxidation of a copper nanoparticle film induced by a visible laser source during Raman spectroscopic measurements. The copper nanoparticle film is prepared by drop-casting chemically synthesized copper colloid onto silicon oxide/silicon substrate. The local oxidation induced by visible lasers in Raman spectroscopy is monitored with the distinct scattering peaks for copper oxides. Optical microscopy and scanning electron microscopy have been used to characterize the laser-induced morphological changes in the film. The results of this oxidation process with different excitation wavelengths and different laser powers will be presented.

Organic Complexation of Dissolved Copper and Iron from Shipboard Incubations in the Central California Current System: Investigating the Impacts of Light Conditions and Phytoplankton Growth on Iron- and Copper-Binding Ligand Characteristics

NASA Astrophysics Data System (ADS)

Mellett, T.; Parker, C.; Brown, M.; Coale, T.; Duckham, C.; Chappell, D.; Maldonado, M. T.; Bruland, K. W.; Buck, K. N.

2016-02-01

Two shipboard incubation experiments were carried out in July of 2014 to investigate potential sources and sinks of iron- and copper-binding organic ligands in the surface ocean. Seawater for the experiments was collected from the central California Current System (cCCS) and incubated under varying light conditions and in the presence and absence of natural phytoplankton communities. Incubation treatments were sampled over a period of up to 3 days for measurements of total dissolved copper and iron, and for the concentration and conditional stability constants of copper- and iron-binding organic ligands. Dissolved copper and iron were determined by inductively coupled plasma-mass spectrometry (ICP-MS) following preconcentration on a Nobias PA1 resin. Organic ligand characteristics for iron and copper were determined using a method of competitive ligand exchange-absorptive cathodic stripping voltammetry (CLE-ACSV) with the added competing ligand salicylaldoxime. Trends in ligand concentrations and conditional stability constants across the different treatments and over the course of the incubation experiments will be presented.

40 CFR 421.54 - Standards of performance for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Standards of performance for new... Electrolytic Copper Refining Subcategory § 421.54 Standards of performance for new sources. Any new source subject to this subpart shall achieve the following new source performance standards: (a) Subpart E...

40 CFR 421.54 - Standards of performance for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Standards of performance for new... Electrolytic Copper Refining Subcategory § 421.54 Standards of performance for new sources. Any new source subject to this subpart shall achieve the following new source performance standards: (a) Subpart E...

40 CFR 421.54 - Standards of performance for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Standards of performance for new... Electrolytic Copper Refining Subcategory § 421.54 Standards of performance for new sources. Any new source subject to this subpart shall achieve the following new source performance standards: (a) Subpart E...

40 CFR 421.54 - Standards of performance for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 30 2012-07-01 2012-07-01 false Standards of performance for new... Electrolytic Copper Refining Subcategory § 421.54 Standards of performance for new sources. Any new source subject to this subpart shall achieve the following new source performance standards: (a) Subpart E...

40 CFR 421.54 - Standards of performance for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 29 2014-07-01 2012-07-01 true Standards of performance for new... Electrolytic Copper Refining Subcategory § 421.54 Standards of performance for new sources. Any new source subject to this subpart shall achieve the following new source performance standards: (a) Subpart E...

Mental representation of normal subjects about the sources of knowledge in different semantic categories and unique entities.

PubMed

Gainotti, Guido; Ciaraffa, Francesca; Silveri, Maria Caterina; Marra, Camillo

2009-11-01

According to the "sensory-motor model of semantic knowledge," different categories of knowledge differ for the weight that different "sources of knowledge" have in their representation. Our study aimed to evaluate this model, checking if subjective evaluations given by normal subjects confirm the different weight that various sources of knowledge have in the representation of different biological and artifact categories and of unique entities, such as famous people or monuments. Results showed that the visual properties are considered as the main source of knowledge for all the living and nonliving categories (as well as for unique entities), but that the clustering of these "sources of knowledge" is different for biological and artifacts categories. Visual data are, indeed, mainly associated with other perceptual (auditory, olfactory, gustatory, and tactual) attributes in the mental representation of living beings and unique entities, whereas they are associated with action-related properties and tactile information in the case of artifacts.

Novel materials for electronic device fabrication using ink-jet printing technology

NASA Astrophysics Data System (ADS)

Kumashiro, Yasushi; Nakako, Hideo; Inada, Maki; Yamamoto, Kazunori; Izumi, Akira; Ishihara, Masamichi

2009-11-01

Novel materials and a metallization technique for the printed electronics were studied. Insulator inks and conductive inks were investigated. For the conductive ink, the nano-sized copper particles were used as metallic sources. These particles were prepared from a copper complex by a laser irradiation process in the liquid phase. Nano-sized copper particles were consisted of a thin copper oxide layer and a metal copper core wrapped by the layer. The conductive ink showed good ink-jettability. In order to metallize the printed trace of the conductive ink on a substrate, the atomic hydrogen treatment was carried out. Atomic hydrogen was generated on a heated tungsten wire and carried on the substrate. The temperature of the substrate was up to 60 °C during the treatment. After the treatment, the conductivity of a copper trace was 3 μΩ cm. It was considered that printed wiring boards can be easily fabricated by employing the above materials.

Characterization of polycyclic aromatic hydrocarbons in soil close to secondary copper and aluminum smelters.

PubMed

Hu, Jicheng; Wu, Jing; Zha, Xiaoshuo; Yang, Chen; Hua, Ying; Wang, Ying; Jin, Jun

2017-04-01

A total of 35 surface soil samples around two secondary copper smelters and one secondary aluminum smelter were collected and analyzed for 16 USEPA priority polycyclic aromatic hydrocarbons (PAHs). The concentrations of PAHs were highest when the soil sample sites were closest to the secondary copper smelters. And, a level gradient of PAHs was observed in soil samples according to the distance from two secondary copper smelters, respectively. The results suggested that PAH concentrations in surrounding soils may be influenced by secondary copper smelters investigated, whereas no such gradient was observed in soils around the secondary aluminum smelter. Further analysis revealed that PAH patterns in soil samples also showed some difference between secondary copper and aluminum smelter, which may be attributed to the difference in their fuel and smelting process. PAH patterns and diagnostic ratios indicated that biomass burning may be also an important source of PAHs in the surrounding soil in addition to the emissions from the plants investigated.

40 CFR 471.104 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2012 CFR

2012-07-01

... atomized Copper 9.58 5.040 Cyanide 1.46 0.605 Lead 2.12 1.01 (b) Sizing spent emulsions. Subpart J—PSES... process watewater pollutants. (g) Sawing or grinding spent emulsions. Subpart J—PSES Pollutant or...-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005 0.002...

40 CFR 471.104 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2014 CFR

2014-07-01

... atomized Copper 9.58 5.040 Cyanide 1.46 0.605 Lead 2.12 1.01 (b) Sizing spent emulsions. Subpart J—PSES... process watewater pollutants. (g) Sawing or grinding spent emulsions. Subpart J—PSES Pollutant or...-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005 0.002...

40 CFR 471.104 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2013 CFR

2013-07-01

... atomized Copper 9.58 5.040 Cyanide 1.46 0.605 Lead 2.12 1.01 (b) Sizing spent emulsions. Subpart J—PSES... process watewater pollutants. (g) Sawing or grinding spent emulsions. Subpart J—PSES Pollutant or...-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005 0.002...

40 CFR 471.104 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... atomized Copper 9.58 5.040 Cyanide 1.46 0.605 Lead 2.12 1.01 (b) Sizing spent emulsions. Subpart J—PSES... process watewater pollutants. (g) Sawing or grinding spent emulsions. Subpart J—PSES Pollutant or...-pounds) of powder metallurgy parts sawed or ground with emulsions Copper 0.035 0.018 Cyanide 0.005 0.002...

40 CFR 421.154 - Standards of performance for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... ore as beryllium Beryllium 1,842.000 831.000 Chromium (total) 831.000 336.900 Copper 2,875.000 1,370... pounds) of beryllium carbonate produced from beryl ore as beryllium Beryllium 180.4 81.4 Chromium (total... beryllium carbonate produced as beryllium Beryllium 175.900 79.370 Chromium (total) 79.370 32.180 Copper 274...

40 CFR 63.11158 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Sources Other Requirements and Information § 63.11158 What definitions apply to this subpart? Terms used in this subpart are defined in the CAA, in 40 CFR 63.2, and in this section as follows: Anode copper means copper that is cast into anodes and refined in an electrolytic process to produce high purity...

40 CFR 63.11158 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Sources Other Requirements and Information § 63.11158 What definitions apply to this subpart? Terms used in this subpart are defined in the CAA, in 40 CFR 63.2, and in this section as follows: Anode copper means copper that is cast into anodes and refined in an electrolytic process to produce high purity...

Different dietary lifestyles and serum zinc and copper in women of reproductive age

DOE Office of Scientific and Technical Information (OSTI.GOV)

Breskin, M.W.; Worthington-Roberts, B.S.; Monsen, E.R.

1986-03-01

Nutrient intakes and biochemical measures of zinc and copper were compared in non-pregnant young women representing different dietary lifestyles, viz, those who habitually ate red meat (RM), fish or poultry (FP), or lacto-ovo-vegetarian (LV) sources of protein. All were in good health and concerned about their diets; none was using supplements or oral contraceptives. Three-day food records were analyzed for nutrient content. Serum and drinking water samples were assayed for zinc and copper (AAS), and serum, for ceruloplasmin (RID). Sign. diff. in dietary Zn or Cu content were not reflected by serum(Zn) or (Cu), but the incidence of serum(Zn)

46 CFR 183.352 - Battery categories.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Battery categories. 183.352 Section 183.352 Shipping...) ELECTRICAL INSTALLATION Power Sources and Distribution Systems § 183.352 Battery categories. This section applies to batteries installed to meet the requirements of § 183.310 for secondary sources of power to...

46 CFR 129.353 - Battery categories.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Battery categories. 129.353 Section 129.353 Shipping... INSTALLATIONS Power Sources and Distribution Systems § 129.353 Battery categories. This section applies to batteries installed to meet the requirements of § 129.310(a) for secondary sources of power to vital loads...

46 CFR 183.352 - Battery categories.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 7 2011-10-01 2011-10-01 false Battery categories. 183.352 Section 183.352 Shipping...) ELECTRICAL INSTALLATION Power Sources and Distribution Systems § 183.352 Battery categories. This section applies to batteries installed to meet the requirements of § 183.310 for secondary sources of power to...

46 CFR 129.353 - Battery categories.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 4 2011-10-01 2011-10-01 false Battery categories. 129.353 Section 129.353 Shipping... INSTALLATIONS Power Sources and Distribution Systems § 129.353 Battery categories. This section applies to batteries installed to meet the requirements of § 129.310(a) for secondary sources of power to vital loads...

46 CFR 129.353 - Battery categories.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 4 2012-10-01 2012-10-01 false Battery categories. 129.353 Section 129.353 Shipping... INSTALLATIONS Power Sources and Distribution Systems § 129.353 Battery categories. This section applies to batteries installed to meet the requirements of § 129.310(a) for secondary sources of power to vital loads...

46 CFR 129.353 - Battery categories.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 4 2013-10-01 2013-10-01 false Battery categories. 129.353 Section 129.353 Shipping... INSTALLATIONS Power Sources and Distribution Systems § 129.353 Battery categories. This section applies to batteries installed to meet the requirements of § 129.310(a) for secondary sources of power to vital loads...

46 CFR 183.352 - Battery categories.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 7 2012-10-01 2012-10-01 false Battery categories. 183.352 Section 183.352 Shipping...) ELECTRICAL INSTALLATION Power Sources and Distribution Systems § 183.352 Battery categories. This section applies to batteries installed to meet the requirements of § 183.310 for secondary sources of power to...

46 CFR 129.353 - Battery categories.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 4 2014-10-01 2014-10-01 false Battery categories. 129.353 Section 129.353 Shipping... INSTALLATIONS Power Sources and Distribution Systems § 129.353 Battery categories. This section applies to batteries installed to meet the requirements of § 129.310(a) for secondary sources of power to vital loads...

46 CFR 183.352 - Battery categories.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 7 2013-10-01 2013-10-01 false Battery categories. 183.352 Section 183.352 Shipping...) ELECTRICAL INSTALLATION Power Sources and Distribution Systems § 183.352 Battery categories. This section applies to batteries installed to meet the requirements of § 183.310 for secondary sources of power to...

46 CFR 183.352 - Battery categories.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 7 2014-10-01 2014-10-01 false Battery categories. 183.352 Section 183.352 Shipping...) ELECTRICAL INSTALLATION Power Sources and Distribution Systems § 183.352 Battery categories. This section applies to batteries installed to meet the requirements of § 183.310 for secondary sources of power to...

Relationship between assimilable-nutrient content and physicochemical properties of topsoil

NASA Astrophysics Data System (ADS)

Tkaczyk, Przemysław; Bednarek, Wiesław; Dresler, Sławomir; Krzyszczak, Jaromir; Baranowski, Piotr; Sławiński, Cezary

2017-10-01

In the years 2008-2011, an environmental study was conducted for Polish soils, focusing on the south-eastern Poland soils, as they exhibit significant acidification. This study aimed at assessing the current pHKCl and the supply of basic macro- (P, K, Mg and S-SO4) and microelements (B, Cu, Fe, Mn and Zn) in the collected soil samples, and also at determining their relationship with the soil agronomic category, humus content and pH class. Soil reaction and humus and macronutrient content were positively correlated with the amount of colloidal clay and particles < 0.02 mm. In the majority of cases, the macro-element content in the soil was positively correlated with soil pH and humus content. As for microelements, a usually significant and positive correlation was found between the soil agronomic category and the content of manganese, iron and zinc, whereas for the content of boron and copper, no such relationship was observed. A significant and positive correlation between soil reaction and the content of manganese, iron and boron was also found. Such correlations were not observed in relation to copper and zinc content. Statistical analysis indicated that the content of boron and manganese depended to the greatest extent on the investigated physicochemical properties.

Effects of roof and rainwater characteristics on copper concentrations in roof runoff.

PubMed

Bielmyer, Gretchen K; Arnold, W Ray; Tomasso, Joseph R; Isely, Jeff J; Klaine, Stephen J

2012-05-01

Copper sheeting is a common roofing material used in many parts of the world. However, copper dissolved from roof sheeting represents a source of copper ions to watersheds. Researchers have studied and recently developed a simple and efficient model to predict copper runoff rates. Important input parameters include precipitation amount, rain pH, and roof angle. We hypothesized that the length of a roof also positively correlates with copper concentration (thus, runoff rates) on the basis that runoff concentrations should positively correlate with contact time between acidic rain and the copper sheet. In this study, a novel system was designed to test and model the effects of roof length (length of roof from crown to the drip edge) on runoff copper concentrations relative to rain pH and roof angle. The system consisted of a flat-bottom copper trough mounted on an apparatus that allowed run length and slope to be varied. Water of known chemistry was trickled down the trough at a constant rate and sampled at the bottom. Consistent with other studies, as pH of the synthetic rainwater decreased, runoff copper concentrations increased. At all pH values tested, these results indicated that run length was more important in explaining variability in copper concentrations than was the roof slope. The regression equation with log-transformed data (R(2) = 0.873) accounted for slightly more variability than the equation with untransformed data (R(2) = 0.834). In log-transformed data, roof angle was not significant in predicting copper concentrations.

Bismesitoylphosphinic Acid (BAPO-OH): A Ligand for Copper Complexes and Four-Electron Photoreductant for the Preparation of Copper Nanomaterials.

PubMed

Beil, Andreas; Müller, Georgina; Käser, Debora; Hattendorf, Bodo; Li, Zhongshu; Krumeich, Frank; Rosenthal, Amos; Rana, Vijay Kumar; Schönberg, Hartmut; Benkő, Zoltán; Grützmacher, Hansjörg

2018-05-16

Bismesitoylphosphinic acid, (HO)PO(COMes) 2 (BAPO-OH), is an efficient photoinitiator for free-radical polymerizations of olefins in aqueous phase. Described here are the structures of various copper(II) and copper(I) complexes with BAPO-OH as the ligand. The complex Cu II (BAPO-O) 2 (H 2 O) 2 is photoactive, and under irradiation with UV light in aqueous phase, it serves as a source of metallic copper in high purity and yield (>80 %). Simultaneously, the radical polymerization of acrylates can be initiated and allows the preparation of nanoparticle/polymer nanocomposites in which the metallic Cu nanoparticles are protected against oxidation. The determination of the stoichiometry of the photoreductions suggests an almost quantitative conversion from Cu II into Cu 0 with half an equivalent of BAPO-OH, which serves as a four-electron photoreductant. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Discrete Cu(i) complexes for azide-alkyne annulations of small molecules inside mammalian cells.

PubMed

Miguel-Ávila, Joan; Tomás-Gamasa, María; Olmos, Andrea; Pérez, Pedro J; Mascareñas, José L

2018-02-21

The archetype reaction of "click" chemistry, namely, the copper-promoted azide-alkyne cycloaddition (CuAAC), has found an impressive number of applications in biological chemistry. However, methods for promoting intermolecular annulations of exogenous, small azides and alkynes in the complex interior of mammalian cells, are essentially unknown. Herein we demonstrate that isolated, well-defined copper(i)-tris(triazolyl) complexes featuring designed ligands can readily enter mammalian cells and promote intracellular CuAAC annulations of small, freely diffusible molecules. In addition to simplifying protocols and avoiding the addition of "non-innocent" reductants, the use of these premade copper complexes leads to more efficient processes than with the alternative, in situ made copper species prepared from Cu(ii) sources, tris(triazole) ligands and sodium ascorbate. Under the reaction conditions, the well-defined copper complexes exhibit very good cell penetration properties, and do not present significant toxicities.

Copper, lead and zinc concentrations of human breast milk as affected by maternal dietary practices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Umoren, J.; Kies, C.

1986-03-01

Maternal dietary practices have been found to affect the concentrations of some nutrients in human breast milk. Lead toxicity is a concern in young children. Lead, copper and zinc are thought to compete for intestinal absorption sites. The objective of the current project was to compare copper, lead and zinc contents of breast milk from practicing lacto-vegetarian and omnivore, lactating women at approximately four months post-partum. Analyses were done by atomic absorption spectrophotometry using a carbon rod attachment. Copper concentrations were higher in milk samples from lacto-ovo-vegetarians. Milk samples from the omnivores had the highest lead and zinc concentrations. Leadmore » and copper concentrations in milk were negatively correlated. The higher zinc concentrations in the milk of the omnivore women may have been related to better utilization of zinc from meat than from plant food sources.« less

Graphite fiber/copper matrix composites for space power heat pipe fin applications

NASA Astrophysics Data System (ADS)

McDanels, David L.; Baker, Karl W.; Ellis, David L.

1991-01-01

High specific thermal conductivity (thermal conductivity divided by density) is a major design criterion for minimizing system mass for space power systems. For nuclear source power systems, graphite fiber reinforced copper matrix (Gr/Cu) composites offer good potential as a radiator fin material operating at service temperatures above 500 K. Specific thermal conductivity in the longitudinal direction is better than beryllium and almost twice that of copper. The high specific thermal conductivity of Gr/Cu offers the potential of reducing radiator mass by as much as 30 percent. Gr/Cu composites also offer the designer a range of available properties for various missions and applications. The properties of Gr/Cu are highly anisotropic. Longitudinal elastic modulus is comparable to beryllium and about three times that of copper. Thermal expansion in the longitudinal direction is near zero, while it exceeds that of copper in the transverse direction.

40 CFR 141.83 - Source water treatment requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Source water treatment requirements. 141.83 Section 141.83 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Control of Lead and Copper § 141.83 Source...

40 CFR 141.83 - Source water treatment requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Source water treatment requirements. 141.83 Section 141.83 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Control of Lead and Copper § 141.83 Source...

40 CFR 141.83 - Source water treatment requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Source water treatment requirements. 141.83 Section 141.83 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Control of Lead and Copper § 141.83 Source...

40 CFR 141.83 - Source water treatment requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Source water treatment requirements. 141.83 Section 141.83 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Control of Lead and Copper § 141.83 Source...

40 CFR 141.83 - Source water treatment requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Source water treatment requirements. 141.83 Section 141.83 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Control of Lead and Copper § 141.83 Source...

Identification of sources of aerosol particles in three locations in eastern Botswana

NASA Astrophysics Data System (ADS)

Chimidza, S.; Moloi, K.

2000-07-01

Airborne particles have been collected using a dichotomous virtual impactor at three different locations in the eastern part of Botswana: Serowe, Selibe-Phikwe, and Francistown. The particles were separated into two fractions (fine and coarse). Sampling at the three locations was done consecutively during the months of July and August, which are usually dry and stable. The sampling time for each sample was 12 hours during the day. For elemental composition, energy-dispersive x-ray fluorescence technique was used. Correlations and principal component analysis with varimax rotation were used to identify major sources of aerosol particles. In all the three places, soil was found to be the main source of aerosol particles. A copper-nickel mine and smelter at Selibe-Phikwe was found to be not only a source of copper and nickel particles in Selibe-Phikwe but also a source of these particles in far places like Serowe. In Selibe-Phikwe and Francistown, car exhaust was found to be the major source of fine particles of lead and bromine.

40 CFR 63.1103 - Source category-specific applicability, definitions, and requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... compliance schedule for the carbon black production and acetylene decomposition carbon black production... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source...

40 CFR 63.1103 - Source category-specific applicability, definitions, and requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... compliance schedule for the carbon black production and acetylene decomposition carbon black production... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source...

40 CFR 63.1103 - Source category-specific applicability, definitions, and requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... compliance schedule for the carbon black production and acetylene decomposition carbon black production... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source...

40 CFR 63.1103 - Source category-specific applicability, definitions, and requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... compliance schedule for the carbon black production and acetylene decomposition carbon black production... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source...

Post-blasting seismicity in Rudna copper mine, Poland - source parameters analysis.

NASA Astrophysics Data System (ADS)

Caputa, Alicja; Rudziński, Łukasz; Talaga, Adam

2017-04-01

The really important hazard in Polish copper mines is high seismicity and corresponding rockbursts. Many methods are used to reduce the seismic hazard. Among others the most effective is preventing blasting in potentially hazardous mining panels. The method is expected to provoke small moderate tremors (up to M2.0) and reduce in this way a stress accumulation in the rockmass. This work presents an analysis, which deals with post-blasting events in Rudna copper mine, Poland. Using the Full Moment Tensor (MT) inversion and seismic spectra analysis, we try to find some characteristic features of post blasting seismic sources. Source parameters estimated for post-blasting events are compared with the parameters of not-provoked mining events that occurred in the vicinity of the provoked sources. Our studies show that focal mechanisms of events which occurred after blasts have similar MT decompositions, namely are characterized by a quite strong isotropic component as compared with the isotropic component of not-provoked events. Also source parameters obtained from spectral analysis show that provoked seismicity has a specific source physics. Among others, it is visible from S to P wave energy ratio, which is higher for not-provoked events. The comparison of all our results reveals a three possible groups of sources: a) occurred just after blasts, b) occurred from 5min to 24h after blasts and c) not-provoked seismicity (more than 24h after blasting). Acknowledgements: This work was supported within statutory activities No3841/E-41/S/2016 of Ministry of Science and Higher Education of Poland.

Source and Assessment of Metal Pollution at Khetri Copper Mine Tailings and Neighboring Soils, Rajasthan, India.

PubMed

Punia, Anita; Siddaiah, N Siva; Singh, Saurabh K

2017-11-01

We present here the results of the study on metal pollution by identifying source, abundance and distribution in soil and tailings of Khetri copper complex (KCC) mines, Rajasthan India. The region is highly contaminated by copper (Cu) with higher values in the soil near overburden material (1224 mg/kg) and tailings (111 mg/kg). The average Cu (231 mg/kg) concentration of soil is ~9, 5 and 32 times higher than upper crust, world average shale (WAS) and local background soil (LS), respectively. However this reaches to ~82, 46 and 280 times higher in case of tailing when compared. The correlation and principal component analysis for soil reveals that the source of Cu, Zn, Co, Ni, Mn and Fe is mining and Pb and Cd could be result of weathering of parent rocks and other anthropogenic activities. The source for Cr in soil is both mining activities and weathering of parent rocks. The values of index of geo-accumulation (I geo ) and pollution load index for soil using LS as background are higher compared to values calculated using WAS. The metal rich sulphide bearing overburden material as well as tailings present in the open environment at KCC mines region warrants a proper management to minimize their impact on the environment.

Waters in Croatia between practice and needs: public health challenge.

PubMed

Vitale, Ksenija; Marijanović Rajcić, Marija; Senta, Ankica

2002-08-01

To describe waters monitoring in Croatia and legislation status for their evaluation, and to present health-relevant data and long-term analysis of the Drava river water, which is used in drinking water production. Survey of databanks of various Croatian institutions related to waters, and physical and chemical analysis of 13 surface water pollutants, applying HRN ISO laboratory methods. Since 1992 until 2000, water systems had 10% of contaminated samples, whereas local community and private water sources had 30% of such samples. Since 1981, 84 waterborne epidemics have been registered, affecting 7,581 people with predominantly gastrointestinal problems. The Drava river monitoring revealed that lead, cadmium, and mercury concentrations have constantly exceeded, whereas nickel and copper remained within allowed values for the Drava river to be classified into the second category of surface waters. Both nitrates and nitrites have been increasing with time, nitrates exceeding and nitrites remaining within guideline values. Total phosphorus and nitrogen concentrations also increased with time, still being below allowed maximum values. Chemical oxygen demand has been decreasing. Alkalinity has been satisfactory. Salt burden has been increasing. Both drinking water quality assessment and surface water monitoring in Croatia use less parameters then recommended by World Health Organization or signed conventions. The quality of Drava water has been improving, but still does not fully conform to the second category of surface water. More parameters should be used in its monitoring, as recommended by EU conventions and laws.

IDENTIFICATION AND CHARACTERIZATION OF MISSING AND UNACCOUNTED FOR AREA SOURCE CATEGORIES

EPA Science Inventory

The report identifies and characterizes missing or unaccounted for area source categories. Area source emissions of particulate matter (TSP), sulfur dioxide (SO2), oxides of nitrogen (NOx), reactive volatile organic compounds (VOCs), and carbon monoxide (CO) are estimated annuall...

40 CFR 471.55 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... surface treated Copper 15.5 7.38 Nickel 6.66 4.48 Fluoride 720 320 Molybdenum 60.9 27.0 (n) Alkaline... monthly average mg/off-kg (pounds per million off-pounds) of refractory metals alkaline cleaned Copper 0.428 0.204 Nickel 0.184 0.124 Fluoride 19.9 8.82 Molybdenum 1.68 0.745 (o) Alkaline cleaning rinse...

40 CFR 471.55 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... surface treated Copper 15.5 7.38 Nickel 6.66 4.48 Fluoride 720 320 Molybdenum 60.9 27.0 (n) Alkaline... monthly average mg/off-kg (pounds per million off-pounds) of refractory metals alkaline cleaned Copper 0.428 0.204 Nickel 0.184 0.124 Fluoride 19.9 8.82 Molybdenum 1.68 0.745 (o) Alkaline cleaning rinse...

40 CFR 471.85 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... Copper 0.459 0.219 Cyanide 0.072 0.029 Zinc 0.365 0.151 (j) Alkaline cleaning spent baths. Subpart H—PSNS... million off-pounds) of zinc alkaline cleaned Chromium 0.002 0.0006 Copper 0.005 0.002 Cyanide 0.0007 0.0003 Zinc 0.004 0.002 (k) Alkaline cleaning rinse. Subpart H—PSNS Pollutant or pollutant property...

40 CFR 471.55 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... surface treated Copper 15.5 7.38 Nickel 6.66 4.48 Fluoride 720 320 Molybdenum 60.9 27.0 (n) Alkaline... monthly average mg/off-kg (pounds per million off-pounds) of refractory metals alkaline cleaned Copper 0.428 0.204 Nickel 0.184 0.124 Fluoride 19.9 8.82 Molybdenum 1.68 0.745 (o) Alkaline cleaning rinse...

40 CFR 471.55 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... surface treated Copper 15.5 7.38 Nickel 6.66 4.48 Fluoride 720 320 Molybdenum 60.9 27.0 (n) Alkaline... monthly average mg/off-kg (pounds per million off-pounds) of refractory metals alkaline cleaned Copper 0.428 0.204 Nickel 0.184 0.124 Fluoride 19.9 8.82 Molybdenum 1.68 0.745 (o) Alkaline cleaning rinse...

40 CFR 471.55 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... surface treated Copper 15.5 7.38 Nickel 6.66 4.48 Fluoride 720 320 Molybdenum 60.9 27.0 (n) Alkaline... monthly average mg/off-kg (pounds per million off-pounds) of refractory metals alkaline cleaned Copper 0.428 0.204 Nickel 0.184 0.124 Fluoride 19.9 8.82 Molybdenum 1.68 0.745 (o) Alkaline cleaning rinse...

40 CFR 471.85 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... Copper 0.459 0.219 Cyanide 0.072 0.029 Zinc 0.365 0.151 (j) Alkaline cleaning spent baths. Subpart H—PSNS... million off-pounds) of zinc alkaline cleaned Chromium 0.002 0.0006 Copper 0.005 0.002 Cyanide 0.0007 0.0003 Zinc 0.004 0.002 (k) Alkaline cleaning rinse. Subpart H—PSNS Pollutant or pollutant property...

Brazing copper to dispersion-strengthened copper

NASA Astrophysics Data System (ADS)

Ryding, David G.; Allen, Douglas; Lee, Richard H.

1996-11-01

The advanced photon source is a state-of-the-art synchrotron light source that will produce intense x-ray beams, which will allow the study of smaller samples and faster reactions and processes at a greater level of detail than has ben possible to date. The beam is produced by using third- generation insertion devices in a 7-GeV electron/positron storage ring that is 1,104 meters in circumference. The heat load from these intense high-power devices is very high, and certain components must sustain total heat loads of 3 to 15 kW and heat fluxes of 30 W/mm$_2). Because the beams will cycle on and off many times, thermal shock and fatigue will be a problem. High heat flux impinging on a small area causes a large thermal gradient that results in high stress. GlidCop, a dispersion-strengthened copper, is the desired design material because of its high thermal conductivity and superior mechanical properties as compared to copper and its alloys. GlidCop is not amenable to joining by fusion welding, and brazing requires diligence because of high diffusivity. Brazing procedures were developed using optical and scanning electron microscopy.

Copper as an antibacterial material in different facilities.

PubMed

Inkinen, J; Mäkinen, R; Keinänen-Toivola, M M; Nordström, K; Ahonen, M

2017-01-01

The present study was performed in real life settings in different facilities (hospital, kindergarten, retirement home, office building) with copper and copper alloy touch surface products (floor drain lids, toilet flush buttons, door handles, light switches, closet touch surfaces, corridor hand rails, front door handles and toilet support rails) in parallel to reference products. Pure copper surfaces supported lower total bacterial counts (16 ± 45 vs 105 ± 430 CFU cm -2 , n = 214, P < 0·001) and a lower occurrence of Staphylococcus aureus (2·6 vs 14%, n = 157, P < 0·01) and Gram-negatives (21 vs 34%, n = 214, P < 0·05) respectively than did reference surfaces, whereas the occurrence of enterococci (15%, n = 214, P > 0·05) was similar. The studied products could be assigned to three categories according to their bacterial loads as follows (P < 0·001): floor drain lids (300 ± 730 CFU cm -2 , n = 32), small area touch surfaces (8·0 ± 7·1 to 62 ± 160 CFU cm -2 , n = 90) and large area touch surfaces (1·1 ± 1·1 to 1·7 ± 2·4 CFU cm -2 , n = 92). In conclusion, copper touch surface products can function as antibacterial materials to reduce the bacterial load, especially on frequently touched small surfaces. The efficiency of copper as an antimicrobial material has been noted in laboratory studies and in the hospital environment. The present study further shows that copper exerted an antibacterial effect in different facilities, i.e. in a hospital, a kindergarten, an office building and in a retirement home for the elderly. The study suggests that copper has potential use as an antibacterial material and therefore might serve as a means to lower the incidence of transmission of infectious agents from inanimate surfaces in different facilities, with everyday functions. © 2016 The Society for Applied Microbiology.

Osmium isotope constraints on ore metal recycling in subduction zones

PubMed

McInnes; McBride; Evans; Lambert; Andrew

1999-10-15

Veined peridotite xenoliths from the mantle beneath the giant Ladolam gold deposit on Lihir Island, Papua New Guinea, are 2 to 800 times more enriched in copper, gold, platinum, and palladium than surrounding depleted arc mantle. Gold ores have osmium isotope compositions similar to those of the underlying subduction-modified mantle peridotite source region, indicating that the primary origin of the metals was the mantle. Because the mantle is relatively depleted in gold, copper, and palladium, tectonic processes that enhance the advective transport and concentration of these fluid soluble metals may be a prerequisite for generating porphyry-epithermal copper-gold deposits.

Storing Drinking-water in Copper pots Kills Contaminating Diarrhoeagenic Bacteria

PubMed Central

Sudha, V.B. Preethi; Ganesan, Sheeba; Pazhani, G.P.; Ramamurthy, T.; Nair, G.B.

2012-01-01

Microbially-unsafe water is still a major concern in most developing countries. Although many water-purification methods exist, these are expensive and beyond the reach of many people, especially in rural areas. Ayurveda recommends the use of copper for storing drinking-water. Therefore, the objective of this study was to evaluate the effect of copper pot on microbially-contaminated drinking-water. The antibacterial effect of copper pot against important diarrhoeagenic bacteria, including Vibrio cholerae O1, Shigella flexneri 2a, enterotoxigenic Escherichia coli, enteropathogenic E. coli, Salmonella enterica Typhi, and Salmonella Paratyphi is reported. When drinking-water (pH 7.83±0.4; source: ground) was contaminated with 500 CFU/mL of the above bacteria and stored in copper pots for 16 hours at room temperature, no bacteria could be recovered on the culture medium. Recovery failed even after resuscitation in enrichment broth, followed by plating on selective media, indicating loss of culturability. This is the first report on the effect of copper on S. flexneri 2a, enteropathogenic E. coli, and Salmonella Paratyphi. After 16 hours, there was a slight increase in the pH of water from 7.83 to 7.93 in the copper pots while the other physicochemical parameters remained unchanged. Copper content (177±16 ppb) in water stored in copper pots was well within the permissible limits of the World Health Organization. Copper holds promise as a point-of-use solution for microbial purification of drinking-water, especially in developing countries. PMID:22524115

Storing drinking-water in copper pots kills contaminating diarrhoeagenic bacteria.

PubMed

Sudha, V B Preethi; Ganesan, Sheeba; Pazhani, G P; Ramamurthy, T; Nair, G B; Venkatasubramanian, Padma

2012-03-01

Microbially-unsafe water is still a major concern in most developing countries. Although many water-purification methods exist, these are expensive and beyond the reach of many people, especially in rural areas. Ayurveda recommends the use of copper for storing drinking-water. Therefore, the objective of this study was to evaluate the effect of copper pot on microbially-contaminated drinking-water. The antibacterial effect of copper pot against important diarrhoeagenic bacteria, including Vibrio cholerae O1, Shigella flexneri 2a, enterotoxigenic Escherichia coli, enteropathogenic E. coli, Salmonella enterica Typhi, and Salmonella Paratyphi is reported. When drinking-water (pH 7.83 +/- 0.4; source: ground) was contaminated with 500 CFU/mL of the above bacteria and stored in copper pots for 16 hours at room temperature, no bacteria could be recovered on the culture medium. Recovery failed even after resuscitation in enrichment broth, followed by plating on selective media, indicating loss of culturability. This is the first report on the effect of copper on S. flexneri 2a, enteropathogenic E. coli, and Salmonella Paratyphi. After 16 hours, there was a slight increase in the pH of water from 7.83 to 7.93 in the copper pots while the other physicochemical parameters remained unchanged. Copper content (177 +/- 16 ppb) in water stored in copper pots was well within the permissible limits of the World Health Organization. Copper holds promise as a point-of-use solution for microbial purification of drinking-water, especially in developing countries.

Determination of factors responsible for the bioweathering of copper minerals from organic-rich copper-bearing Kupferschiefer black shale.

PubMed

Włodarczyk, Agnieszka; Szymańska, Agata; Skłodowska, Aleksandra; Matlakowska, Renata

2016-04-01

The aim of this study was to investigate the bioweathering of copper minerals present in the alkaline, copper-bearing and organic-rich Kupferschiefer black shale through the action of a consortium of indigenous lithobiontic, heterotrophic, neutrophilic bacteria isolated from this sedimentary rock. The involvement of microorganisms in the direct/enzymatic bioweathering of fossil organic matter of the rock was confirmed. As a result of bacterial activity, a spectrum of various organic compounds such as urea and phosphoric acid tributyl ester were released from the rock. These compounds indirectly act on the copper minerals occurring in the rock and cause them to weather. This process was reflected in the mobilization of copper, iron and sulfur and in changes in the appearance of copper minerals observed under reflected light. The potential role of identified enzymes in biodegradation of fossil organic matter and role of organic compounds released from black shale as a result of this process in copper minerals weathering was discussed. The presented results provide a new insight into the role of chemical compounds released by bacteria during fossil organic matter bioweathering potentially important in the cycling of copper and iron deposited in the sedimentary rock. The originality of the described phenomenon lies in the fact that the bioweathering of fossil organic matter and, consequently, of copper minerals occur simultaneously in the same environment, without any additional sources of energy, electrons and carbon. Copyright © 2016 Elsevier Ltd. All rights reserved.

40 CFR 98.340 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Municipal Solid Waste Landfills § 98.340 Definition of the..., construction and demolition landfills, or industrial landfills. (c) This source category consists of the following sources at municipal solid waste (MSW) landfills: Landfills, landfill gas collection systems, and...

Properties of thermal air plasma with admixing of copper and carbon

NASA Astrophysics Data System (ADS)

Fesenko, S.; Veklich, A.; Boretskij, V.; Cressault, Y.; Gleizes, A.; Teulet, Ph

2014-11-01

This paper deals with investigations of air plasma with admixing of copper and carbon. Model plasma source unit with real breaking arc was used for the simulation of real discharges, which can be occurred during sliding of Cu-C composite electrodes on copper wire at electromotive vehicles. The complex technique of plasma property studies is developed. From one hand, the radial profiles of temperature and electron density in plasma of electric arc discharge in air between Cu-C composite and copper electrodes in air flow were measured by optical spectroscopy techniques. From another hand, the radial profiles of electric conductivity of plasma mixture were calculated by solution of energy balance equation. It was assumed that the thermal conductivity of air plasma is not depending on copper or carbon vapor admixtures. The electron density is obtained from electric conductivity profiles by calculation in assumption of local thermodynamic equilibrium in plasma. Computed in such way radial profiles of electron density in plasma of electric arc discharge in air between copper electrodes were compared with experimentally measured profiles. It is concluded that developed techniques of plasma diagnostics can be reasonably used in investigations of thermal plasma with copper and carbon vapors.

RESIDUAL RISK ASSESSMENT: MAGNETIC TAPE ...

EPA Pesticide Factsheets

This document describes the residual risk assessment for the Magnetic Tape Manufacturing source category. For stationary sources, section 112 (f) of the Clean Air Act requires EPA to assess risks to human health and the environment following implementation of technology-based control standards. If these technology-based control standards do not provide an ample margin of safety, then EPA is required to promulgate addtional standards. This document describes the methodology and results of the residual risk assessment performed for the Magnetic Tape Manufacturing source category. The results of this analyiss will assist EPA in determining whether a residual risk rule for this source category is appropriate.

The impact of tertiary wastewater treatment on copper and zinc complexation.

PubMed

Constantino, C; Gardner, M; Comber, S D W; Scrimshaw, M D; Ellor, B

2015-01-01

Tightening quality standards for European waters has seen a move towards enhanced wastewater treatment technologies such as granulated organic carbon treatment and ozonation. Although these technologies are likely to be successful in degrading certain micro-organic contaminants, these may also destroy compounds which would otherwise complex and render metals significantly less toxic. This study examined the impact of enhanced tertiary treatment on the capacity of organic compounds within sewage effluents to complex copper and zinc. The data show that granulated organic carbon treatment removes a dissolved organic carbon (DOC) fraction that is unimportant to complexation such that no detrimental impact on complexation or metal bioavailability is likely to occur from this treatment type. High concentrations of ozone (>1 mg O3/mg DOC) are, however, likely to impact the complexation capacity for copper although this is unlikely to be important at the concentrations of copper typically found in effluent discharges or in rivers. Ozone treatment did not affect zinc complexation capacity. The complexation profiles of the sewage effluents show these to contain a category of non-humic ligand that appears unaffected by tertiary treatment and which displays a high affinity for zinc, suggesting these may substantially reduce the bioavailability of zinc in effluent discharges. The implication is that traditional metal bioavailability assessment approaches such as the biotic ligand model may overestimate zinc bioavailability in sewage effluents and effluent-impacted waters.

40 CFR 437.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... Recovery § 437.26 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7 or...: Standards for chromium, cobalt, copper, lead, tin, zinc, carbazole, n-decane, bis(2-ethylhexyl) phthalate...

40 CFR 437.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... Recovery § 437.26 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7 or...: Standards for chromium, cobalt, copper, lead, tin, zinc, carbazole, n-decane, bis(2-ethylhexyl) phthalate...

The Role of External Sources of Information in Children's Evaluative Food Categories

ERIC Educational Resources Information Center

Nguyen, Simone P.

2012-01-01

Evaluative food categories are value-laden assessments, which reflect the healthfulness and palatability of foods (e.g. healthy/unhealthy, yummy/yucky). In a series of three studies, this research examines how 3- to 4-year-old children (N?=?147) form evaluative food categories based on input from external sources of information. The results…

40 CFR 98.110 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Definition of the source category. 98.110 Section 98.110 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ferroalloy Production § 98.110 Definition of the source...

Preparation and characterization of copper telluride thin films by modified chemical bath deposition (M-CBD) method

NASA Astrophysics Data System (ADS)

Pathan, H. M.; Lokhande, C. D.; Amalnerkar, D. P.; Seth, T.

2003-09-01

Copper telluride thin films were deposited using modified chemical method using copper(II) sulphate; pentahydrate [CuSO 4·5H 2O] and sodium tellurite [Na 2TeO 3] as cationic and anionic sources, respectively. Modified chemical method is based on the immersion of the substrate into separately placed cationic and anionic precursors. The preparative conditions such as concentration, pH, immersion time, immersion cycles, etc. were optimized to get good quality copper telluride thin films at room temperature. The films have been characterized for structural, compositional, optical and electrical transport properties by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), Rutherford back scattering (RBS), optical absorption/transmission, electrical resistivity and thermoemf measurement techniques.

The derivation of water quality criteria of copper in Biliu River

NASA Astrophysics Data System (ADS)

Zheng, Hongbo; Jia, Xinru

2018-03-01

Excessive copper in water can be detrimental to the health of human and aquatic life. China has promulgated Environmental Quality Standards for Surface Water to control water pollution, but uniform standard values may cause under-protection or over-protection. Therefore, the basic research work on water quality criteria of water source or reservoir is urgently needed. This study deduces the acute and chronic Water Quality Criteria (WQC) of copper in Biliu River by Species Sensitivity Distribution method (SSD). The result shows that BiDoseResp is the most suitable model and the acute and chronic water quality benchmark of copper are 10.72 µg•L-1 and 5.86 µg•L-1. This study provides basis for the construction of water quality standard of Liaoning and the environmental management of Biliu River.

Meta-evaporite in the Carajás mineral province, northern Brazil

NASA Astrophysics Data System (ADS)

Riehl, Walter; Cabral, Alexandre Raphael

2018-05-01

Evidence for connecting evaporite-sourced high-salinity fluids with iron-oxide-copper-gold (IOCG) deposits in the Carajás mineral province has solely been based on boron-isotope compositions of tourmaline. Presence of meta-evaporitic rocks remains unrecognised. Here, we report laminated albitite, tourmalinite and banded albite-phlogopite rock, intercepted by exploratory drilling in a clastic metasedimentary sequence. These rocks represent evaporite precursors. Their location in the copper-gold prospects Açaí and Angélica, in the westernmost part of the Carajás mineral province, indicates that (i) evaporite-sourced fluids were regional and (ii) evaporite-bearing metasedimentary sequences may have been an important source of high-salinity fluids and/or sulfur for the IOCG deposits of the Carajás mineral province.

Production of Copper as a Complex Mining and Metallurgical Processing System in Polish Copper Mines of the Legnica-Glogów Copper Belt

NASA Astrophysics Data System (ADS)

Malewski, Jerzy

2017-12-01

Geological and technological conditions of Cu production in the Polish copper mines of the Legnica-Glogów Copper Belt are presented. Cu production is recognized as a technological fractal consisting of subsystems for mineral exploration, ore extraction and processing, and metallurgical treatment. Qualitative and quantitative models of these operations have been proposed, including estimation of their costs of process production. Numerical calculations of such a system have been performed, which allow optimize the system parameters according to economic criteria under variable Cu mineralization in the ore deposit. The main objective of the study is to develop forecasting tool for analysis of production efficiency in domestic copper mines based on available sources of information. Such analyses are primarily of social value, allowing for assessment of the efficiency of management of local mineral resources in the light of current technological and market constraints. At the same time, this is a concept of the system analysis method to manage deposit exploitation on operational and strategic level.

Laser multiplexing system

DOEpatents

Johnson, Steve A.; English, Jr., Ronald Edward; White, Ronald K.

2001-01-01

A plurality of copper lasers, as radiant power sources, emits a beam of power carrying radiation. A plurality of fiber injection assemblies receives power from the plurality of copper lasers and injects such power into a plurality of fibers for individually transmitting the received power to a plurality of power-receiving devices. The power-transmitting fibers of the system are so arranged that power is delivered therethrough to each of the power-receiving devices such that, even if a few of the radiant power sources and/or fibers fail, the power supply to any of the power receiving devices will not completely drop to zero but will drop by the same proportionate amount.

[The use of individual protective devices for decreasing the microbial contamination of the inhaled air].

PubMed

Sedov, A V; Akin'shin, A V; Tregub, T I

1995-01-01

The work was aimed to justify application of gas masks and respirators with autonomous air source fo lower bacterial contamination of inhaled air. The studies also covered possible catch of bacteria by cotton and filters FPP-15-1.5, those composed of antimicrobial materials, containing furagin or copper ions. As the studies proved, for lower bacterial contaminations of inhaled air one can apply autonomous air source apparatus with filters made of Petrianov tissue, antimicrobial tissue (containing furagin or copper ions), as they reduce fungal content of the air. Such filters are self-disinfecting, but do not influence total contamination of the air.

40 CFR 421.125 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 (b) Subpart L—Film... Zinc .990 .408 Ammonia (as N) 129.300 56.840 (c) Subpart L—Precipitation and Filtration of Film... mg/troy ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000...

40 CFR 421.125 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 (b) Subpart L—Film... Zinc .990 .408 Ammonia (as N) 129.300 56.840 (c) Subpart L—Precipitation and Filtration of Film... mg/troy ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000...

40 CFR 421.125 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 (b) Subpart L—Film... Zinc .990 .408 Ammonia (as N) 129.300 56.840 (c) Subpart L—Precipitation and Filtration of Film... mg/troy ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000...

40 CFR 421.125 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 (b) Subpart L—Film... Zinc .990 .408 Ammonia (as N) 129.300 56.840 (c) Subpart L—Precipitation and Filtration of Film... mg/troy ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000...

Improving the two-step remediation process for CCA-treated wood. Part II, Evaluating bacterial nutrient sources

Treesearch

Carol A. Clausen

2004-01-01

Remediation processes for recovery and reuse of chromated-copper-arsenate-(CCA) treated wood are not gaining wide acceptance because they are more expensive than landfill disposal. One reason is the high cost of the nutrient medium used to culture the metal tolerant bacterium, Bacillus licheniformis, which removes 70-100% of the copper, chromium, and arsenic from CCA-...

Statistical analysis of influence of soil source on leaching of arsenic and copper from CCA-C treated wood

Treesearch

Patricia Lebow; Richard Ziobro; Linda Sites; Tor Schultz; David Pettry; Darrel Nicholas; Stan Lebow; Pascal Kamdem; Roger Fox; Douglas Crawford

2006-01-01

Leaching of wood preservatives affects the long-term efficacy and environmental impact of treated wood. Soil properties and wood characteristicscan affectleaching of woad preservatives, but these effects are not well understood. This paper reports a statistical analysis of the effects of soil and wood properties on leaching of arsenic (As) and copper (Cu) from southern...

40 CFR 471.85 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... Chromium 0.133 0.054 Copper 0.459 0.219 Cyanide 0.072 0.029 Zinc 0.365 0.151 (j) Alkaline cleaning spent... mg/off-kg (pounds per million off-pounds) of zinc alkaline cleaned Chromium 0.002 0.0006 Copper 0.005 0.002 Cyanide 0.0007 0.0003 Zinc 0.004 0.002 (k) Alkaline cleaning rinse. Subpart H—PSNS Pollutant...

40 CFR 471.85 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... Chromium 0.133 0.054 Copper 0.459 0.219 Cyanide 0.072 0.029 Zinc 0.365 0.151 (j) Alkaline cleaning spent... mg/off-kg (pounds per million off-pounds) of zinc alkaline cleaned Chromium 0.002 0.0006 Copper 0.005 0.002 Cyanide 0.0007 0.0003 Zinc 0.004 0.002 (k) Alkaline cleaning rinse. Subpart H—PSNS Pollutant...

40 CFR 471.85 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... Chromium 0.133 0.054 Copper 0.459 0.219 Cyanide 0.072 0.029 Zinc 0.365 0.151 (j) Alkaline cleaning spent... mg/off-kg (pounds per million off-pounds) of zinc alkaline cleaned Chromium 0.002 0.0006 Copper 0.005 0.002 Cyanide 0.0007 0.0003 Zinc 0.004 0.002 (k) Alkaline cleaning rinse. Subpart H—PSNS Pollutant...

Normalization of a collimated 14.7 MeV neutron source in a neutron spectrometry system for benchmark experiments

NASA Astrophysics Data System (ADS)

Ofek, R.; Tsechanski, A.; Shani, G.

1988-05-01

In the present study a method used to normalize a collimated 14.7 MeV neutron beam is introduced. It combined a measurement of the fast neutron scalar flux passing through the collimator, using a copper foil activation, with a neutron transport calculation of the foil activation per unit source neutron, carried out by the discrete-ordinates transport code DOT 4.2. The geometry of the collimated neutron beam is composed of a D-T neutron source positioned 30 cm in front of a 6 cm diameter collimator, through a 120 cm thick paraffin wall. The neutron flux emitted from the D-T source was counted by an NE-213 scintillator, simultaneously with the irradiation of the copper foil. Thus, the determination of the normalization factor of the D-T source is used for an absolute flux calibration of the NE-213 scintillator. The major contributions to the uncertainty in the determination of the normalization factor, and their origins, are discussed.

Investigating relationships between biomarkers of exposure and environmental copper and manganese levels in house dusts from a Portuguese industrial city.

PubMed

Reis, A P; Costa, S; Santos, I; Patinha, C; Noack, Y; Wragg, J; Cave, M; Sousa, A J

2015-08-01

This study reports on data obtained from a pilot survey focusing on house dust and toenail metal(loids) concentrations in residents living in the industrial city of Estarreja. The study design hereby described aims at investigating relationships between human toenails and both copper and manganese levels in settled house dusts. A total of 21 households and 30 individuals were recruited for the pilot study: 19 households corresponding to 27 residents living near the industrial complex, forming the exposed group, plus 2 households and 3 residents from residential areas with no anticipated environmental contaminants that were used for comparison. Factorial analysis was used for source identification purposes. Investigation on the potential influence of environmental factors over copper and manganese levels in the toenails was carried out via questionnaire data and multiple correspondence analysis. The results show that copper concentrations are more elevated in the indoor dusts, while manganese concentrations are more elevated in the outdoor dust samples. The geometrical relationships in the datasets suggest that the backyard soil is a probable source of manganese to the indoor dust. Copper and manganese contents in the toenail clippings are more elevated in children than in adults, but the difference between the two age groups is not statistically significant (p > 0.05). Investigation of environmental factors influencing the exposure-biomarker association indicates a probable relationship between manganese contents in indoor dust and manganese levels in toenail clippings, a result that is partially supported by the bioaccessibility estimates. However, for copper, no relationship was found between indoor dusts and the biomarkers of exposure.

40 CFR Table 2 to Subpart B of... - MON Source Categories

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 9 2010-07-01 2010-07-01 false MON Source Categories 2 Table 2 to Subpart B of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Control Technology Determinations for Major Sources in Accordance With Clean Air Act Sections, Sections...

40 CFR 141.88 - Monitoring requirements for lead and copper in source water.

Code of Federal Regulations, 2013 CFR

2013-07-01

..., and collection methods: (i) Groundwater systems shall take a minimum of one sample at every entry... to install source water treatment under § 141.83(b)(2). (i) A water system using only groundwater...

40 CFR 141.88 - Monitoring requirements for lead and copper in source water.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., and collection methods: (i) Groundwater systems shall take a minimum of one sample at every entry... to install source water treatment under § 141.83(b)(2). (i) A water system using only groundwater...

40 CFR 141.88 - Monitoring requirements for lead and copper in source water.

Code of Federal Regulations, 2012 CFR

2012-07-01

..., and collection methods: (i) Groundwater systems shall take a minimum of one sample at every entry... to install source water treatment under § 141.83(b)(2). (i) A water system using only groundwater...

Using water-quality profiles to characterize seasonal water quality and loading in the upper Animas River basin, southwestern Colorado

USGS Publications Warehouse

Leib, Kenneth J.; Mast, M. Alisa; Wright, Winfield G.

2003-01-01

One of the important types of information needed to characterize water quality in streams affected by historical mining is the seasonal pattern of toxic trace-metal concentrations and loads. Seasonal patterns in water quality are estimated in this report using a technique called water-quality profiling. Water-quality profiling allows land managers and scientists to assess priority areas to be targeted for characterization and(or) remediation by quantifying the timing and magnitude of contaminant occurrence. Streamflow and water-quality data collected at 15 sites in the upper Animas River Basin during water years 1991?99 were used to develop water-quality profiles. Data collected at each sampling site were used to develop ordinary least-squares regression models for streamflow and constituent concentrations. Streamflow was estimated by correlating instantaneous streamflow measured at ungaged sites with continuous streamflow records from streamflow-gaging stations in the subbasin. Water-quality regression models were developed to estimate hardness and dissolved cadmium, copper, and zinc concentrations based on streamflow and seasonal terms. Results from the regression models were used to calculate water-quality profiles for streamflow, constituent concentrations, and loads. Quantification of cadmium, copper, and zinc loads in a stream segment in Mineral Creek (sites M27 to M34) was presented as an example application of water-quality profiling. The application used a method of mass accounting to quantify the portion of metal loading in the segment derived from uncharacterized sources during different seasonal periods. During May, uncharacterized sources contributed nearly 95 percent of the cadmium load, 0 percent of the copper load (or uncharacterized sources also are attenuated), and about 85 percent of the zinc load at M34. During September, uncharacterized sources contributed about 86 percent of the cadmium load, 0 percent of the copper load (or uncharacterized sources also are attenuated), and about 52 percent of the zinc load at M34. Characterized sources accounted for more of the loading gains estimated in the example reach during September, possibly indicating the presence of diffuse inputs during snowmelt runoff. The results indicate that metal sources in the upper Animas River Basin may change substantially with season, regardless of the source.

Micropollutants in urban watersheds : substance flow analysis as management tool

NASA Astrophysics Data System (ADS)

Rossi, L.; Copin, P. J.; Barry, A. D.; Bader, H.-P.; Scheidegger, R.; Chèvre, N.

2009-04-01

Micropollutants released by cities into water are of increasing concern as they are suspected of inducing long-term effects on both aquatic organisms and humans (eg., hormonally active substances). Substances found in the urban water cycle have different sources in the urban area and different fates in this cycle. For example, the pollutants emitted from traffic, like copper or PAHs get to surface water during rain events often without any treatment. Pharmaceuticals resulting from human medical treatments get to surface water mainly through wastewater treatment plants, where they are only partly treated and eliminated. One other source of contamination in urban areas for these compounds are combined sewer overflows (CSOs). Once in the receiving waters (lakes, rivers, groundwater), these substances may re-enter the cycle through drinking water. It is therefore crucial to study the behaviour of micropollutants in the urban water cycle and to get flexible tools for urban water management. Substance flow analysis (SFA) has recently been proposed as instrument for water pollution management in urban water systems. This kind of analysis is an extension of material flow analysis (MFA) originally developed in the economic sector and later adapted to regional investigations. In this study, we propose to test the application of SFA for a large number of classes of micropollutants to evaluate its use for urban water management. We chose the city of Lausanne as case study since the receiving water of this city (Lake Geneva) is an important source of drinking water for the surrounding population. Moreover a profound system-knowledge and many data were available, both on the sewer system and the water quality. We focus our study on one heavy metal (copper) and four pharmaceuticals (diclofenac, ibuprofen, carbamazepine and naproxen). Results conducted on copper reveals that around 1500 kg of copper enter the aquatic compartment yearly. This amount contributes to sediment enrichment, which may pose a long-term risk for the benthic organisms. The major sources (total of 73%) of copper in receiving surface water are roofs and contact lines of trolleybuses. Thus technical solutions have to be found to manage this specific source of contamination. Application of SFA approach to four pharmaceuticals reveals that CSOs represent an important source of contamination: Between 14% (carbamazepine) and 61% (ibuprofen) of the total annual loads of Lausanne city to the Lake are due to CSOs. These results will help in defining the best management strategy to limit Lake Geneva contamination. SFA is thus a promising tool for integrated urban water management.

26 CFR 1.904(f)-2T - Recapture of overall foreign losses (temporary).

Code of Federal Regulations, 2010 CFR

2010-04-01

... $500 balance in the general category overall foreign loss account or $300 foreign source income in the... in the general category is recharacterized as U.S. source income. The balance in Y's general category..., see § 1.904(f)-2(a) and (b). (c) Section 904(f)(1) recapture—(1) In general. In a year in which a...

The carbonaceous phyllite rock-hosted Pedra Verde copper mine, Borborema Province, Brazil: Stable isotope constraints, structural controls and metallogenic evolution

NASA Astrophysics Data System (ADS)

da Silva Nogueira de Matos, José Henrique; Saraiva dos Santos, Ticiano José; Virgínia Soares Monteiro, Lena

2017-12-01

The Pedra Verde Copper Mine is located in the Viçosa do Ceará municipality, State of Ceará, NE Brazil. The copper mineralization is hosted by the Pedra Verde Phyllite, which is a carbonaceous chlorite-calcite phyllite with subordinate biotite. It belongs to the Neoproterozoic Martinópole Group of the Médio Coreaú Domain, Borborema Province. The Pedra Verde deposit is stratabound and its ore zoning is conspicuous, according to the following sequence, from bottom to top: marcasite/pyrite, native silver, chalcopyrite, bornite, chalcocite, native copper and hematite. Barite and carbonaceous material are reported in ore zones. Zoning reflects the ore formation within a redox boundary developed due to the interaction between oxidized copper- and sulfate-bearing fluids and the reduced phyllite. Structural control on mineralization is evidenced by the association of the ore minerals with veins, hinge folds, shadow pressures, and mylonitic foliation. It was mainly exercised by a dextral transcurrent shear zone developed during the third deformational stage identified in the Médio Coreaú Domain between 590 Ma and 570 Ma. This points to the importance of epigenetic, post-metamorphic deformational events for ore formation. Oxygen isotopic composition (δ18OH2O = 8.94 to 11.28‰, at 250 to 300 °C) estimated for the hydrothermal fluids in equilibrium with calcite indicates metamorphic or evolved meteoric isotopic signatures. The δ13CPDB values (-2.60 to -9.25‰) obtained for hydrothermal calcite indicate mixing of carbon sources derived from marine carbonate rocks and carbonaceous material. The δ34SCDT values (14.88 to 36.91‰) of sulfides suggest evaporites as sulfate sources or a closed system in relation to SO42- availability to form H2S. Carbonaceous matter had a key role in thermochemical sulfate processes and sulfide precipitation. The Pedra Verde Copper Mine is considered the first stratabound meta-sedimentary rock-hosted copper deposit described in Brazil and shares similarities with the syn-orogenic copper deposits of the Congo-Zambian Copperbelt formed during the Gondwana amalgamation.

Multi-keV x-ray sources from metal-lined cylindrical hohlraums

NASA Astrophysics Data System (ADS)

Jacquet, L.; Girard, F.; Primout, M.; Villette, B.; Stemmler, Ph.

2012-08-01

As multi-keV x-ray sources, plastic hohlraums with inner walls coated with titanium, copper, and germanium have been fired on Omega in September 2009. For all the targets, the measured and calculated multi-keV x-ray power time histories are in a good qualitative agreement. In the same irradiation conditions, measured multi-keV x-ray conversion rates are ˜6%-8% for titanium, ˜2% for copper, and ˜0.5% for germanium. For titanium and copper hohlraums, the measured conversion rates are about two times higher than those given by hydroradiative computations. Conversely, for the germanium hohlraum, a rather good agreement is found between measured and computed conversion rates. To explain these findings, multi-keV integrated emissivities calculated with RADIOM [M. Busquet, Phys. Fluids 85, 4191 (1993)], the nonlocal-thermal-equilibrium atomic physics model used in our computations, have been compared to emissivities obtained from different other models. These comparisons provide an attractive way to explain the discrepancies between experimental and calculated quantitative results.

RESIDUAL RISK ASSESSMENT: ETHYLENE OXIDE ...

EPA Pesticide Factsheets

This document describes the residual risk assessment for the Ethylene Oxide Commercial Sterilization source category. For stationary sources, section 112 (f) of the Clean Air Act requires EPA to assess risks to human health and the environment following implementation of technology-based control standards. If these technology-based control standards do not provide an ample margin of safety, then EPA is required to promulgate addtional standards. This document describes the methodology and results of the residual risk assessment performed for the Ethylene Oxide Commercial Sterilization source category. The results of this analyiss will assist EPA in determining whether a residual risk rule for this source category is appropriate.

Multiple Sources of Prescription Payment and Risky Opioid Therapy Among Veterans.

PubMed

Becker, William C; Fenton, Brenda T; Brandt, Cynthia A; Doyle, Erin L; Francis, Joseph; Goulet, Joseph L; Moore, Brent A; Torrise, Virginia; Kerns, Robert D; Kreiner, Peter W

2017-07-01

Opioid overdose and other related harms are a major source of morbidity and mortality among US Veterans, in part due to high-risk opioid prescribing. We sought to determine whether having multiple sources of payment for opioids-as a marker for out-of-system access-is associated with risky opioid therapy among veterans. Cross-sectional study examining the association between multiple sources of payment and risky opioid therapy among all individuals with Veterans Health Administration (VHA) payment for opioid analgesic prescriptions in Kentucky during fiscal year 2014-2015. Source of payment categories: (1) VHA only source of payment (sole source); (2) sources of payment were VHA and at least 1 cash payment [VHA+cash payment(s)] whether or not there was a third source of payment; and (3) at least one other noncash source: Medicare, Medicaid, or private insurance [VHA+noncash source(s)]. Our outcomes were 2 risky opioid therapies: combination opioid/benzodiazepine therapy and high-dose opioid therapy, defined as morphine equivalent daily dose ≥90 mg. Of the 14,795 individuals in the analytic sample, there were 81.9% in the sole source category, 6.6% in the VHA+cash payment(s) category, and 11.5% in the VHA+noncash source(s) category. In logistic regression, controlling for age and sex, persons with multiple payment sources had significantly higher odds of each risky opioid therapy, with those in the VHA+cash having significantly higher odds than those in the VHA+noncash source(s) group. Prescribers should examine the prescription monitoring program as multiple payment sources increase the odds of risky opioid therapy.

Mitochondrial Copper Metabolism and Delivery to Cytochrome c Oxidase

PubMed Central

Horn, Darryl; Barrientos, Antoni

2010-01-01

Summary Metals are essential elements of all living organisms. Among them, copper is required for a multiplicity of functions including mitochondrial oxidative phosphorylation and protection against oxidative stress. Here we will focus on describing the pathways involved in the delivery of copper to cytochrome c oxidase (COX), a mitochondrial metalloenzyme acting as the terminal enzyme of the mitochondrial respiratory chain. The catalytic core of COX is formed by three mitochondrially-encoded subunits and contains three copper atoms. Two copper atoms bound to subunit 2 constitute the CuA site, the primary acceptor of electrons from ferrocytochrome c. The third copper, CuB, is associated with the high-spin heme a3 group of subunit 1. Recent studies, mostly performed in the yeast Saccharomyces cerevisiae, have provided new clues about 1- the source of the copper used for COX metallation; 2- the roles of Sco1p and Cox11p, the proteins involved in the direct delivery of copper to the CuA and CuB sites, respectively; 3- the action mechanism of Cox17p, a copper chaperone that provides copper to Sco1p and Cox11p; 4- the existence of at least four Cox17p homologues carrying a similar twin CX9C domain suggestive of metal binding, Cox19p, Cox23p, Pet191p and Cmc1p, that could be part of the same pathway; and 5- the presence of a disulfide relay system in the intermembrane space of mitochondria that mediates import of proteins with conserved cysteines motifs such as the CX9C characteristic of Cox17p and its homologues. The different pathways are reviewed and discussed in the context of both mitochondrial COX assembly and copper homeostasis. PMID:18459161

Influence of copper ions on the viability and cytotoxicity of Pseudomonas aeruginosa under conditions relevant to drinking water environments.

PubMed

Dwidjosiswojo, Zenyta; Richard, Jessica; Moritz, Miriam M; Dopp, Elke; Flemming, Hans-Curt; Wingender, Jost

2011-11-01

Copper plumbing materials can be the source of copper ions in drinking water supplies. The aim of the current study was to investigate the influence of copper ions on the viability and cytotoxicity of the potential pathogen Pseudomonas aeruginosa that presents a health hazard when occurring in building plumbing systems. In batch experiments, exposure of P. aeruginosa (10(6)cells/mL) for 24h at 20°C to copper-containing drinking water from domestic plumbing systems resulted in a loss of culturability, while total cell numbers determined microscopically did not decrease. Addition of the chelator diethyldithiocarbamate (DDTC) to copper-containing water prevented the loss of culturability. When suspended in deionized water with added copper sulfate (10 μM), the culturability of P. aeruginosa decreased by more than 6 log units, while total cell counts, the concentration of cells with intact cytoplasmic membranes, determined with the LIVE/DEAD BacLight kit, and the number of cells with intact 16S ribosomal RNA, determined by fluorescent in situ hybridization, remained unchanged. When the chelator DDTC was added to copper-stressed bacteria, complete restoration of culturability was observed to occur within 14 d. Copper-stressed bacteria were not cytotoxic towards Chinese hamster ovary (CHO-9) cells, while untreated and resuscitated bacteria caused an almost complete decrease of the concentration of viable CHO-9 cells within 24 h. Thus, copper ions in concentrations relevant to drinking water in plumbing systems seem to induce a viable but non-culturable (VBNC) state in P. aeruginosa accompanied by a loss of culturability and cytotoxicity, and VBNC cells can regain both culturability and cytotoxicity, when copper stress is abolished. Copyright © 2011 Elsevier GmbH. All rights reserved.

Discrete Cu(i) complexes for azide–alkyne annulations of small molecules inside mammalian cells† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc04643j

PubMed Central

Miguel-Ávila, Joan; Tomás-Gamasa, María; Olmos, Andrea

2018-01-01

The archetype reaction of “click” chemistry, namely, the copper-promoted azide–alkyne cycloaddition (CuAAC), has found an impressive number of applications in biological chemistry. However, methods for promoting intermolecular annulations of exogenous, small azides and alkynes in the complex interior of mammalian cells, are essentially unknown. Herein we demonstrate that isolated, well-defined copper(i)–tris(triazolyl) complexes featuring designed ligands can readily enter mammalian cells and promote intracellular CuAAC annulations of small, freely diffusible molecules. In addition to simplifying protocols and avoiding the addition of “non-innocent” reductants, the use of these premade copper complexes leads to more efficient processes than with the alternative, in situ made copper species prepared from Cu(ii) sources, tris(triazole) ligands and sodium ascorbate. Under the reaction conditions, the well-defined copper complexes exhibit very good cell penetration properties, and do not present significant toxicities. PMID:29675241

Iron and copper release in drinking-water distribution systems.

PubMed

Shi, Baoyou; Taylor, James S

2007-09-01

A large-scale pilot study was carried out to evaluate the impacts of changes in water source and treatment process on iron and copper release in water distribution systems. Finished surface waters, groundwaters, and desalinated waters were produced with seven different treatment systems and supplied to 18 pipe distribution systems (PDSs). The major water treatment processes included lime softening, ferric sulfate coagulation, reverse osmosis, nanofiltration, and integrated membrane systems. PDSs were constructed from PVC, lined cast iron, unlined cast iron, and galvanized pipes. Copper pipe loops were set up for corrosion monitoring. Results showed that surface water after ferric sulfate coagulation had low alkalinity and high sulfates, and consequently caused the highest iron release. Finished groundwater treated by conventional method produced the lowest iron release but the highest copper release. The iron release of desalinated water was relatively high because of the water's high chloride level and low alkalinity. Both iron and copper release behaviors were influenced by temperature.

Differential toxicity of copper, zinc, and lead during the embryonic development of Chasmagnathus granulatus (Brachyura, Varunidae).

PubMed

Lavolpe, Mariano; Greco, Laura López; Kesselman, Daniela; Rodríguez, Enrique

2004-04-01

Ovigerous females of the estuarine crab Chasmagnathus granulatus were exposed to copper (0.01 and 1 mg/L), zinc (0.05, 1, and 10 mg/L), or lead (0.01 and 1 mg/L) during early, late, or whole embryonic development. None of the assayed heavy metals produced a significant mortality of females, neither a decrease in the number of hatched larvae nor a decrease in the egg incubation time, but several morphological abnormalities were detected in hatched larvae. The abnormalities were classified in three categories: eye, body pigmentary, and body morphological abnormalities. Those larvae with eye and body pigmentary abnormalities, particularly those involving retinal pigments and chromatophores, showed the highest incidence by exposure to the assayed metals. In addition, embryos were more susceptible to copper and zinc during the late period of development, whereas the effect of lead was greater during the early period of embryogenesis. Some teratogenic effects observed in C. granulatus embryos exposed to heavy metals, particularly the hypertrophy and hypopigmentation of eyes observed in the laboratory at a lead concentration as low as that reported for the natural environment, could be considered as sensitive biomarkers for this kind of pollutant.

40 CFR 471.71 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORY Uranium Forming Subcategory § 471.71 Effluent limitations representing the degree of effluent... uranium extruded Cadium 0.117 0.052 Chromium 0.152 0.062 Copper 0.654 0.344 Lead 0.145 0.069 Nickel 0.661 0.437 Fluoride 20.5 9.08 Molybdenum 2.28 1.18 Oil and grease 6.88 4.13 TSS 14.1 6.71 pH (1) (1) 1...

40 CFR 471.71 - Effluent limitations representing the degree of effluent reduction attainable by the application...

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORY Uranium Forming Subcategory § 471.71 Effluent limitations representing the degree of effluent... uranium extruded Cadium 0.117 0.052 Chromium 0.152 0.062 Copper 0.654 0.344 Lead 0.145 0.069 Nickel 0.661 0.437 Fluoride 20.5 9.08 Molybdenum 2.28 1.18 Oil and grease 6.88 4.13 TSS 14.1 6.71 pH (1) (1) 1...

Flow Charts for Determining Your Requirements: Nine Metal Fabrication and Finishing Source Categories Area Sources National Emission Standards for Hazardous Air Pollutants (NESHAP) Subpart XXXXXX

EPA Pesticide Factsheets

This page contains a July 2008 document that has flow charts to help determine if this National Emission Standards for Hazardous Air Pollutants (NESHAP) rule for Nine metal Fabrication and Finishing Area Source Categories applies to your facility.

Compendium of National Data Sources on Higher Education.

ERIC Educational Resources Information Center

Rodriguez, Esther M., Ed.; Lenth, Charles S., Ed.

This compendium provides a guide to data collections in higher education focusing on sources that are national in scope, and updated and made available on a regular or periodic basis including surveys, data bases, reports, and statistical digests. These sources are divided into nine broad categories, each category contains separate entries for…

40 CFR 421.124 - Standards of performance for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 Total suspended solids... Zinc .990 .408 Ammonia (as N) 129.300 56.840 Total suspended solids 14.550 11.640 pH (1) (1) 1 Within... ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000 3,374.000...

40 CFR 421.316 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

.../kg (pounds per million pounds) of tungsten scrap washed Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia....951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111 Tungsten 8.947 3.985 (c) Tungsten post-leaching... Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600 301.400 Cobalt 14.194 6.223 Tungsten 17.900...

40 CFR 421.316 - Pretreatment standards for new sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

.../kg (pounds per million pounds) of tungsten scrap washed Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia....951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111 Tungsten 8.947 3.985 (c) Tungsten post-leaching... Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600 301.400 Cobalt 14.194 6.223 Tungsten 17.900...

40 CFR 421.124 - Standards of performance for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 Total suspended solids... Zinc .990 .408 Ammonia (as N) 129.300 56.840 Total suspended solids 14.550 11.640 pH (1) (1) 1 Within... ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000 3,374.000...

40 CFR 421.124 - Standards of performance for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 Total suspended solids... Zinc .990 .408 Ammonia (as N) 129.300 56.840 Total suspended solids 14.550 11.640 pH (1) (1) 1 Within... ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000 3,374.000...

40 CFR 421.316 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

.../kg (pounds per million pounds) of tungsten scrap washed Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia....951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111 Tungsten 8.947 3.985 (c) Tungsten post-leaching... Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600 301.400 Cobalt 14.194 6.223 Tungsten 17.900...

40 CFR 421.124 - Standards of performance for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... stripping Copper 64.450 30.720 Zinc 51.360 21.150 Ammonia (as N) 6,712.000 2,951.000 Total suspended solids... Zinc .990 .408 Ammonia (as N) 129.300 56.840 Total suspended solids 14.550 11.640 pH (1) (1) 1 Within... ounce of silver precipitated Copper 73.690 35.120 Zinc 58.720 24.180 Ammonia (as N) 7,674.000 3,374.000...

40 CFR 421.316 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

.../kg (pounds per million pounds) of tungsten scrap washed Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia....951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111 Tungsten 8.947 3.985 (c) Tungsten post-leaching... Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600 301.400 Cobalt 14.194 6.223 Tungsten 17.900...

40 CFR 421.316 - Pretreatment standards for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

.../kg (pounds per million pounds) of tungsten scrap washed Copper 0.250 0.119 Nickel 0.107 0.072 Ammonia....951 Ammonia (as N) 342.700 150.700 Cobalt 7.096 3.111 Tungsten 8.947 3.985 (c) Tungsten post-leaching... Copper 6.583 3.137 Nickel 2.829 1.903 Ammonia (as N) 685.600 301.400 Cobalt 14.194 6.223 Tungsten 17.900...

A Designer Fluid For Aluminum Phase Change Devices. Performance Enhancement in Copper Heat Pipes Performance Enhancement in Copper Heat Pipes. Volume 3

DTIC Science & Technology

2016-11-17

out dynamics of a designer fluid were investigated experimentally in a flat grooved heat pipe. Generated coatings were observed during heat pipe... experimental temperature distributions matched well. Uncertainties in the closure properties were the major source of error. 15. SUBJECT TERMS...72  Results and Discussion ( Experimental Results for IAS 2 in Grooved Wick #1

Palladium-Catalyzed, Copper(I)-Mediated Coupling of Boronic Acids and Benzylthiocyanate. A Cyanide-Free Cyanation of Boronic Acids

PubMed Central

Zhang, Zhihui; Liebeskind, Lanny S.

2008-01-01

A new method for the synthesis of nitriles is described. As a complement to the classic cyanation of aryl halides using cyanide sources and a transition metal catalyst, the palladium-catalyzed cross-coupling of thiocyanates with boronic acids in the presence of copper(I) thiophene-2-carboxylate (CuTC) affords nitriles in good to excellent yields. PMID:16956219

Pollutant fate and spatio-temporal variability in the choptank river estuary: Factors influencing water quality

USGS Publications Warehouse

Whitall, D.; Hively, W.D.; Leight, A.K.; Hapeman, C.J.; McConnell, L.L.; Fisher, T.; Rice, C.P.; Codling, E.; McCarty, G.W.; Sadeghi, A.M.; Gustafson, A.; Bialek, K.

2010-01-01

Restoration of the Chesapeake Bay, the largest estuary in the United States, is a national priority. Documentation of progress of this restoration effort is needed. A study was conducted to examine water quality in the Choptank River estuary, a tributary of the Chesapeake Bay that since 1998 has been classified as impaired waters under the Federal Clean Water Act. Multiple water quality parameters (salinity, temperature, dissolved oxygen, chlorophyll a) and analyte concentrations (nutrients, herbicide and herbicide degradation products, arsenic, and copper) were measured at seven sampling stations in the Choptank River estuary. Samples were collected under base flow conditions in the basin on thirteen dates between March 2005 and April 2008. As commonly observed, results indicate that agriculture is a primary source of nitrate in the estuary and that both agriculture and wastewater treatment plants are important sources of phosphorus. Concentrations of copper in the lower estuary consistently exceeded both chronic and acute water quality criteria, possibly due to use of copper in antifouling boat paint. Concentrations of copper in the upstream watersheds were low, indicating that agriculture is not a significant source of copper loading to the estuary. Concentrations of herbicides (atrazine, simazine, and metolachlor) peaked during early-summer, indicating a rapid surface-transport delivery pathway from agricultural areas, while their degradation products (CIAT, CEAT, MESA, and MOA) appeared to be delivered via groundwater transport. Some in-river processing of CEAT occurred, whereas MESA was conservative. Observed concentrations of herbicide residues did not approach established levels of concern for aquatic organisms. Results of this study highlight the importance of continued implementation of best management practices to improve water quality in the estuary. This work provides a baseline against which to compare future changes in water quality and may be used to design future monitoring programs needed to assess restoration strategy efficacy.

Effects of supplementation with two sources and two levels of copper on meat lipid oxidation, meat colour and superoxide dismutase and glutathione peroxidase enzyme activities in Nellore beef cattle.

PubMed

Correa, Lísia Bertonha; Zanetti, Marcus Antonio; Del Claro, Gustavo Ribeiro; de Paiva, Fernanda Alves; da Luz e Silva, Saulo; Netto, Arlindo Saran

2014-10-28

In the present study, thirty-five Nellore bulls were used to determine the effects of two levels and two sources (organic and inorganic) of Cu supplementation on the oxidative stability of lipids, measured by the thiobarbituric acid-reactive substance (TBARS) test, meat colour and superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) enzyme activities. The following treatments were used: (1) control (C) - basal diet without supplementation of Cu (7 mg Cu/kg DM); (2) I10 - basal diet supplemented with 10 mg Cu/kg DM in the form of copper sulphate (inorganic form); (3) I40 - basal diet supplemented with 40 mg Cu/kg DM in the form of copper sulphate; (4) O10 - basal diet supplemented with 10 mg Cu/kg DM in the form of copper proteinate (organic form); (5) O40 - basal diet supplemented with 40 mg Cu/kg DM in the form of copper proteinate. Lipid oxidation was determined in meat samples exposed to display, modified atmosphere (MA) and vacuum packaging (VC) conditions and in liver samples using the TBARS test. These samples were also evaluated for meat discolouration after exposure to air. The activities of SOD and GSH-Px enzymes were determined in liver samples. In display, MA and VC conditions, the TBARS values of samples from animals supplemented with 40 mg Cu/kg DM were lower than those of samples from control animals. There was no effect of treatment on the colour variables (L*, a*, b*). There was also no significant effect of treatment on hepatic TBARS concentrations and GSH-Px activity. Supplementation with Cu at 40 mg/kg, regardless of the source, induced higher hepatic SOD activity compared with the control treatment. In conclusion, Cu supplementation improved the oxidative stability of lipids in samples exposed to display, MA and VC conditions, demonstrating the antioxidant effect of this mineral.

Dealloying of gold–copper alloy nanowires: From hillocks to ring-shaped nanopores

PubMed Central

Chauvin, Adrien; Delacôte, Cyril; Boujtita, Mohammed; Angleraud, Benoit; Ding, Junjun; Choi, Chang-Hwan; Tessier, Pierre-Yves

2016-01-01

Summary We report on a novel fabrication approach of metal nanowires with complex surface. Taking advantage of nodular growth triggered by the presence of surface defects created intentionally on the substrate as well as the high tilt angle between the magnetron source axis and the normal to the substrate, metal nanowires containing hillocks emerging out of the surface can be created. The approach is demonstrated for several metals and alloys including gold, copper, silver, gold–copper and gold–silver. We demonstrate that applying an electrochemical dealloying process to the gold–copper alloy nanowire arrays allows for transforming the hillocks into ring-like shaped nanopores. The resulting porous gold nanowires exhibit a very high roughness and high specific surface making of them a promising candidate for the development of SERS-based sensors. PMID:27826510

Heavy metal enrichment and ecological risk assessment of surface sediments in Khorramabad River, West Iran.

PubMed

Rastmanesh, F; Safaie, S; Zarasvandi, A R; Edraki, M

2018-04-11

The ecological health of rivers has often been threatened in urbanized catchments due to the expansion of industrial activities and the population growth. Khorramabad River which flows through Khorramabad city, west of Iran, is an example of such settings. The river water is used for agricultural purposes downstream. In this study, the effect of Khorramabad city on heavy metal and metalloid (Cu, Pb, Zn, Ni, Cr, and As) loads in Khorramabad River sediments was investigated. To evaluate sediment pollution and potential adverse biological effects, surface sediment samples were collected at selected locations along the river and were characterized for their geochemical properties. Contamination factor (CF), pollution load index (PLI), and ecological risk assessment (RI) were calculated. Also, sediment quality guidelines (SQGs) were used to screen contaminants of concern in the study area. The results showed that sediments were moderately polluted, with stations located in more densely populated areas showing higher pollution indicators. Copper, Zn, and Pb sources could be attributed to urban wastewater, whereas Ni, Cr, and As had both natural and anthropogenic sources. Moreover, ecological risk assessments showed that sediments could be classified in the category of low risk. The results of the present study showed the effect of anthropogenic activities on heavy metal loads of the river sediments and these findings can be used to mitigate potential impacts on the environment and human health.

Determination of instream metal loads using tracer-injection and synoptic-sampling techniques in Wightman Fork, southwestern Colorado, September 1997

USGS Publications Warehouse

Ortiz, Roderick F.; Bencala, Kenneth E.

2001-01-01

Spatial determinations of the metal loads in Wightman Fork can be used to identify potential source areas to the stream. In September 1997, a chloride tracer-injection study was done concurrently with synoptic water-quality sampling in Wightman Fork near the Summitville Mine site. Discharge was determined and metal concentrations at 38 sites were used to generate mass-load profiles for dissolved aluminum, copper, iron, manganese, and zinc. The U.S. Environmental Protection Agency had previously identified these metals as contaminants of concern.Metal loads increased substantially in Wightman Fork near the Summitville Mine. A large increase occurred along a 60-meter reach that is north of the North Waste Dump and generally corresponds to a region of radial faults. Metal loading from this reach was equivalent to 50 percent or more of the dissolved aluminum, copper, iron, manganese, and zinc load upstream from the outfall of the Summitville Water Treatment Facility (SWTF). Overall, sources along the entire reach upstream from the SWTF were equivalent to 15 percent of the iron, 33 percent of the copper and manganese, 58 percent of the zinc, and 66 percent of the aluminum load leaving the mine site. The largest increases in metal loading to Wightman Fork occurred as a result of inflow from Cropsy Creek. Aluminum, iron, manganese, and zinc loads from Cropsy Creek were equivalent to about 40 percent of the specific metal load leaving the mine site. Copper, iron, and manganese loads from Cropsy Creek were nearly as large or larger than the load from sources upstream from the SWTF.

Molecular and biochemical characterization of a unique mutation in CCS, the human copper chaperone to superoxide dismutase

PubMed Central

Huppke, Peter; Brendel, Cornelia; Korenke, Georg Christoph; Marquardt, Iris; Donsante, Anthony; Yi, Ling; Hicks, Julia D.; Steinbach, Peter J.; Wilson, Callum; Elpeleg, Orly; Møller, Lisbeth Birk; Christodoulou, John; Kaler, Stephen G.; Gärtner, Jutta

2012-01-01

Copper is a trace metal that readily gains and donates electrons, a property that renders it desirable as an enzyme cofactor but dangerous as a source of free radicals. To regulate cellular copper metabolism, an elaborate system of chaperones and transporters has evolved, although no human copper chaperone mutations have been described to date. We describe a child from a consanguineous family who inherited a homozygous mutations in the SLC33A1, encoding an acetyl CoA transporter, and in CCS, encoding the copper chaperone for superoxide dismutase. The CCS mutation, p.Arg163Trp, predicts substitution of a highly conserved arginine residue at position 163 with tryptophan in domain II of CCS, which interacts directly with SOD1. Biochemical analyses of the patient’s fibroblasts, mammalian cell transfections, immunoprecipitation assays, and Lys7Δ (CCS homolog) yeast complementation support the pathogenicity of the mutation. Expression of CCS was reduced and binding of CCS to SOD1 impaired. As a result this mutation causes reduced SOD1 activity and may impair other mechanisms important for normal copper homeostasis. CCS-Arg163Trp represents the primary example of a human mutation in a gene coding for a copper chaperone. PMID:22508683

Dioxins reformation and destruction in secondary copper smelting fly ash under ball milling

PubMed Central

Cagnetta, Giovanni; Hassan, Mohammed Mansour; Huang, Jun; Yu, Gang; Weber, Roland

2016-01-01

Secondary copper recovery is attracting increasing interest because of the growth of copper containing waste including e-waste. The pyrometallurgical treatment in smelters is widely utilized, but it is known to produce waste fluxes containing a number of toxic pollutants due to the large amount of copper involved, which catalyses the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (“dioxins”). Dioxins are generated in secondary copper smelters on fly ash as their major source, resulting in highly contaminated residues. In order to assess the toxicity of this waste, an analysis of dioxin-like compounds was carried out. High levels were detected (79,090 ng TEQ kg−1) in the ash, above the Basel Convention low POPs content (15,000 ng TEQ kg−1) highlighting the hazardousness of this waste. Experimental tests of high energy ball milling with calcium oxide and silica were executed to assess its effectiveness to detoxify such fly ash. Mechanochemical treatment obtained 76% dioxins reduction in 4 h, but longer milling time induced a partial de novo formation of dioxins catalysed by copper. Nevertheless, after 12 h treatment the dioxin content was substantially decreased (85% reduction) and the copper, thanks to the phenomena of incorporation and amorphization that occur during milling, was almost inactivated. PMID:26975802

Exopolysaccharides favor the survival of Erwinia amylovora under copper stress through different strategies.

PubMed

Ordax, Mónica; Marco-Noales, Ester; López, María M; Biosca, Elena G

2010-09-01

Erwinia amylovora causes fire blight, a destructive disease of rosaceous plants very difficult to control. We demonstrated that copper, employed to control plant diseases, induces the "viable-but-nonculturable" (VBNC) state in E. amylovora. Moreover, it was previously reported that copper increases production of its main exopolysaccharide (EPS), amylovoran. In this work, the copper-complexing ability of amylovoran and levan, other major EPS of E. amylovora, was demonstrated. Following this, EPS-deficient mutants were used to determine the role of these EPSs in survival of this bacterium in AB mineral medium with copper, compared to their wild type strain and AB without copper. Total, viable and culturable counts of all strains were monitored for six months. With copper, a larger fraction of the viable population of EPS mutants entered into the VBNC state, and earlier than their wild type strain, showing the contribution of both EPSs to long-term survival in a culturable state. Further, we demonstrated that both EPSs can be used as carbon source by E. amylovora under deprivation conditions. Overall, these previously unreported functions of amylovoran and levan provide survival advantages for E. amylovora, which could contribute to its enhanced persistence in nature. Copyright 2010 Elsevier Masson SAS. All rights reserved.

Dioxins reformation and destruction in secondary copper smelting fly ash under ball milling

NASA Astrophysics Data System (ADS)

Cagnetta, Giovanni; Hassan, Mohammed Mansour; Huang, Jun; Yu, Gang; Weber, Roland

2016-03-01

Secondary copper recovery is attracting increasing interest because of the growth of copper containing waste including e-waste. The pyrometallurgical treatment in smelters is widely utilized, but it is known to produce waste fluxes containing a number of toxic pollutants due to the large amount of copper involved, which catalyses the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (“dioxins”). Dioxins are generated in secondary copper smelters on fly ash as their major source, resulting in highly contaminated residues. In order to assess the toxicity of this waste, an analysis of dioxin-like compounds was carried out. High levels were detected (79,090 ng TEQ kg-1) in the ash, above the Basel Convention low POPs content (15,000 ng TEQ kg-1) highlighting the hazardousness of this waste. Experimental tests of high energy ball milling with calcium oxide and silica were executed to assess its effectiveness to detoxify such fly ash. Mechanochemical treatment obtained 76% dioxins reduction in 4 h, but longer milling time induced a partial de novo formation of dioxins catalysed by copper. Nevertheless, after 12 h treatment the dioxin content was substantially decreased (85% reduction) and the copper, thanks to the phenomena of incorporation and amorphization that occur during milling, was almost inactivated.

Yeast and Mammalian Metallothioneins Functionally Substitute for Yeast Copper-Zinc Superoxide Dismutase

NASA Astrophysics Data System (ADS)

Tamai, Katherine T.; Gralla, Edith B.; Ellerby, Lisa M.; Valentine, Joan S.; Thiele, Dennis J.

1993-09-01

Copper-zinc superoxide dismutase catalyzes the disproportionation of superoxide anion to hydrogen peroxide and dioxygen and is thought to play an important role in protecting cells from oxygen toxicity. Saccharomyces cerevisiae strains lacking copper-zinc superoxide dismutase, which is encoded by the SOD1 gene, are sensitive to oxidative stress and exhibit a variety of growth defects including hypersensitivity to dioxygen and to superoxide-generating drugs such as paraquat. We have found that in addition to these known phenotypes, SOD1-deletion strains fail to grow on agar containing the respiratory carbon source lactate. We demonstrate here that expression of the yeast or monkey metallothionein proteins in the presence of copper suppresses the lactate growth defect and some other phenotypes associated with SOD1-deletion strains, indicating that copper metallothioneins substitute for copper-zinc superoxide dismutase in vivo to protect cells from oxygen toxicity. Consistent with these results, we show that yeast metallothionein mRNA levels are dramatically elevated under conditions of oxidative stress. Furthermore, in vitro assays demonstrate that yeast metallothionein, purified or from whole-cell extracts, exhibits copper-dependent antioxidant activity. Taken together, these data suggest that both yeast and mammalian metallothioneins may play a direct role in the cellular defense against oxidative stress by functioning as antioxidants.

77 FR 29935 - 2012 Technical Corrections, Clarifying and Other Amendments to the Greenhouse Gas Reporting Rule...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-21

...The EPA is proposing to amend specific provisions of the Greenhouse Gas Reporting Rule to provide greater clarity and flexibility to facilities subject to reporting emissions from certain source categories. These source categories will report greenhouse gas (GHG) data for the first time in September of 2012. The proposed changes are not expected to significantly change the overall calculation and monitoring requirements of the Greenhouse Gas Reporting Rule or add additional requirements for reporters, but are expected to correct errors and clarify existing requirements in order to facilitate accurate and timely reporting. The EPA is also proposing confidentiality determinations for four new data elements for the fluorinated gas production source category of the Greenhouse Gas Reporting Rule. Lastly, we are proposing an amendment to Table A-7 of the general provisions to add a data element used as an input to an emission equation in the fluorinated gas production source category.

SAD phasing of a structure based on cocrystallized iodides using an in-house Cu Kalpha X-ray source: effects of data redundancy and completeness on structure solution.

PubMed

Yogavel, Manickam; Gill, Jasmita; Mishra, Prakash Chandra; Sharma, Amit

2007-08-01

Superoxide dismutase (SOD) from Potentilla atrosanguinea (Wall. ex. Lehm.) was crystallized using 20% PEG 3350 and 0.2 M ammonium iodide and diffraction data were collected to 2.36 A resolution using an in-house Cu Kalpha X-ray source. Analyses show that data with a redundancy of 3.2 were sufficient to determine the structure by the SAD technique using the iodine anomalous signal. This redundancy is lower than that in previous cases in which protein structures were determined using iodines for phasing and in-house copper X-ray sources. Cocrystallization of proteins with halide salts such as ammonium iodide in combination with copper-anode X-ray radiation can therefore serve as a powerful and easy avenue for structure solution.

Soil microcosm for testing the effects of chemical pollutants on soil fauna communities and trophic structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parmelee, R.W.; Wentsel, R.S.; Phillips, C.T.

1993-08-01

A microcosm technique is presented that uses community and trophic-level analysis of soil nematodes and microarthropods to determine the effects of chemicals on soil systems. Forest soil was treated with either copper, p-nitrophenol, or trinitrotoluene. Nematodes were sorted into bacterivore, fungivore, herbivore, and omnivore-predator trophic groups, and a hatchling category. Microarthropods were sorted to the acarine suborders Prostigmata, Mesostigmata, and Oribatida; the insectan order Collembola; and a miscellaneous group. Omnivore-predator nematodes and meso-stigmatid and oribatid mites were the groups most sensitive to copper and were significantly reduced at levels as low as 100 [mu]g g[sup [minus]1] copper. Total nematode andmore » microarthropod numbers declined above 200 [mu]g g[sup [minus]1] copper. Trophic structure analysis suggested that high sensitivity of nematode predators to intermediate levels of copper reduced predation on herbivore nematodes and resulted in greater numbers of nematodes compared to controls. p-Nitrophenol was very toxic to the nematode community, and all trophic groups were significantly reduced above 20 [mu]g g[sup [minus]1]. However, there was no effect of p-nitrophenol on microarthropods. Trinitrotoluene had no significant negative effect on total abundance of either groups of soil fauna, but oribatids were significantly reduced at 200 [mu]g g[sup [minus]1]. The results demonstrated that soil nematodes and microarthropods were sensitive indicators of environmental contaminants and that trophic-structure and community analysis has the potential to detect more subtle indirect effects of chemicals on soil food-web structure. The authors conclude that microcosms with field communities of soil microfauna offer high resolution of the ecotoxicological effects of chemicals in complex soil systems.« less

A Feature-Reinforcement-Based Approach for Supporting Poly-Lingual Category Integration

NASA Astrophysics Data System (ADS)

Wei, Chih-Ping; Chen, Chao-Chi; Cheng, Tsang-Hsiang; Yang, Christopher C.

Document-category integration (or category integration for short) is fundamental to many e-commerce applications, including information integration along supply chains and information aggregation by intermediaries. Because of the trend of globalization, the requirement for category integration has been extended from monolingual to poly-lingual settings. Poly-lingual category integration (PLCI) aims to integrate two document catalogs, each of which consists of documents written in a mix of languages. Several category integration techniques have been proposed in the literature, but these techniques focus only on monolingual category integration rather than PLCI. In this study, we propose a feature-reinforcement-based PLCI (namely, FR-PLCI) technique that takes into account the master documents of all languages when integrating source documents (in the source catalog) written in a specific language into the master catalog. Using the monolingual category integration (MnCI) technique as a performance benchmark, our empirical evaluation results show that our proposed FR-PLCI technique achieves better integration accuracy than MnCI does in both English and Chinese category integration tasks.

Effect of Post Treatment For Cu-Cr Source/Drain Electrodes on a-IGZO TFTs.

PubMed

Hu, Shiben; Fang, Zhiqiang; Ning, Honglong; Tao, Ruiqiang; Liu, Xianzhe; Zeng, Yong; Yao, Rihui; Huang, Fuxiang; Li, Zhengcao; Xu, Miao; Wang, Lei; Lan, Linfeng; Peng, Junbiao

2016-07-27

We report a high-performance amorphous Indium-Gallium-Zinc-Oxide (a-IGZO) thin-film transistor (TFT) with new copper-chromium (Cu-Cr) alloy source/drain electrodes. The TFT shows a high mobility of 39.4 cm 2 ·V - 1 ·s - 1 a turn-on voltage of -0.8 V and a low subthreshold swing of 0.47 V/decade. Cu diffusion is suppressed because pre-annealing can protect a-IGZO from damage during the electrode sputtering and reduce the copper diffusion paths by making film denser. Due to the interaction of Cr with a-IGZO, the carrier concentration of a-IGZO, which is responsible for high mobility, rises.

Effect of Post Treatment For Cu-Cr Source/Drain Electrodes on a-IGZO TFTs

PubMed Central

Hu, Shiben; Fang, Zhiqiang; Ning, Honglong; Tao, Ruiqiang; Liu, Xianzhe; Zeng, Yong; Yao, Rihui; Huang, Fuxiang; Li, Zhengcao; Xu, Miao; Wang, Lei; Lan, Linfeng; Peng, Junbiao

2016-01-01

We report a high-performance amorphous Indium-Gallium-Zinc-Oxide (a-IGZO) thin-film transistor (TFT) with new copper-chromium (Cu-Cr) alloy source/drain electrodes. The TFT shows a high mobility of 39.4 cm2·V−1·s−1 a turn-on voltage of −0.8 V and a low subthreshold swing of 0.47 V/decade. Cu diffusion is suppressed because pre-annealing can protect a-IGZO from damage during the electrode sputtering and reduce the copper diffusion paths by making film denser. Due to the interaction of Cr with a-IGZO, the carrier concentration of a-IGZO, which is responsible for high mobility, rises. PMID:28773743

Application of classification-tree methods to identify nitrate sources in ground water

USGS Publications Warehouse

Spruill, T.B.; Showers, W.J.; Howe, S.S.

2002-01-01

A study was conducted to determine if nitrate sources in ground water (fertilizer on crops, fertilizer on golf courses, irrigation spray from hog (Sus scrofa) wastes, and leachate from poultry litter and septic systems) could be classified with 80% or greater success. Two statistical classification-tree models were devised from 48 water samples containing nitrate from five source categories. Model I was constructed by evaluating 32 variables and selecting four primary predictor variables (??15N, nitrate to ammonia ratio, sodium to potassium ratio, and zinc) to identify nitrate sources. A ??15N value of nitrate plus potassium 18.2 indicated inorganic or soil organic N. A nitrate to ammonia ratio 575 indicated nitrate from golf courses. A sodium to potassium ratio 3.2 indicated spray or poultry wastes. A value for zinc 2.8 indicated poultry wastes. Model 2 was devised by using all variables except ??15N. This model also included four variables (sodium plus potassium, nitrate to ammonia ratio, calcium to magnesium ratio, and sodium to potassium ratio) to distinguish categories. Both models were able to distinguish all five source categories with better than 80% overall success and with 71 to 100% success in individual categories using the learning samples. Seventeen water samples that were not used in model development were tested using Model 2 for three categories, and all were correctly classified. Classification-tree models show great potential in identifying sources of contamination and variables important in the source-identification process.

Retention of atmospheric Cu, Ni, Cd and Zn in an ombrotrophic peat profile near the Outokumpu Cu-Ni mine, SE-Finland

NASA Astrophysics Data System (ADS)

Rausch, N.; Nieminen, T. M.; Ukonmaanaho, L.; Cheburkin, A.; Krachler, M.; Shotyk, W.

2003-05-01

Peat cores taken from ombrotrophic bogs are widely used to reconstruct historical records of atmospheric lead and mercury déposition[1, 2]. In this study, the retention of copper, nickel, cadmium and zinc in peat bogs are studied by comparing high resolution, age dated concentration profiles with emissions from the main local source, the Outokumpu copper-nickel mine. An ombrotrophic peat core was taken from the vicinity of Outokumpu, E Finland. Copper and zinc concentrations of dry peat were measured by XRF, cadmium and nickel by GF-AAS, and sample ages by 210Pb. Only copper and nickel show enhanced concentrations in layers covering the mining period, indicating a retention of these elements. However, the more detailed comparison of ore production rates and concentrations in age-dated samples show clearly that only copper is likely to be permanently fixed, while nickel doesn't reflect the mining activity. Even though copper is retained in the upper part of the profile, a possible redeposition of this element by secondary processes (e.g., water table fluctuations) can not be excluded. This question will be resolved by further investigations, e.g. by pore water profiles.

Sensorimotor Cortex Reorganization in Alzheimer's Disease and Metal Dysfunction: A MEG Study

PubMed Central

Salustri, C.; Tecchio, F.; Zappasodi, F.; Tomasevic, L.; Ercolani, M.; Moffa, F.; Cassetta, E.; Rossini, P. M.; Squitti, R.

2013-01-01

Objective. To verify whether systemic biometals dysfunctions affect neurotransmission in living Alzheimer's disease (AD) patients. Methods. We performed a case-control study using magnetoencephalography to detect sensorimotor fields of AD patients, at rest and during median nerve stimulation. We analyzed position and amount of neurons synchronously activated by the stimulation in both hemispheres to investigate the capability of the primary somatosensory cortex to reorganize its circuitry disrupted by the disease. We also assessed systemic levels of copper, ceruloplasmin, non-Cp copper (i.e., copper not bound to ceruloplasmin), peroxides, transferrin, and total antioxidant capacity. Results. Patients' sensorimotor generators appeared spatially shifted, despite no change of latency and strength, while spontaneous activity sources appeared unchanged. Neuronal reorganization was greater in moderately ill patients, while delta activity increased in severe patients. Non-Cp copper was the only biological variable appearing to be associated with patient sensorimotor transmission. Conclusions. Our data strengthen the notion that non-Cp copper, not copper in general, affects neuronal activity in AD. Significance. High plasticity in the disease early stages in regions controlling more commonly used body parts strengthens the notion that physical and cognitive activities are protective factors against progression of dementia. PMID:24416615

Bioextraction of Copper from Printed Circuit Boards: Influence of Initial Concentration of Ferrous Iron

NASA Astrophysics Data System (ADS)

Yamane, Luciana Harue; Espinosa, Denise Crocce Romano; Tenório, Jorge Alberto Soares

Printed circuit boards are found in all electric and electronic equipment and are particularly problematic to recycle because of the heterogeneous mix of organic material, metals, and fiberglass. Additionally, printed circuit boards can be considered a secondary source of copper and bacterial leaching can be applied to copper recovery. This study investigated the influence of initial concentration of ferrous iron on bacterial leaching to recover copper from printed circuit boards using Acidithiobacillus ferrooxidans-LR. Printed circuit boards from computers were comminuted using a hammer mill. The powder obtained was magnetically separated and the non magnetic material used in this study. A shake flask study was carried out on the non magnetic material using a rotary shaker at 30°C, 170 rpm and different initial concentrations of ferrous iron (gL-1): 6.75; 13.57 and 16.97. Abiotic controls were also run in parallel. The monitored parameters were pH, Eh, ferrous iron concentration and copper extraction (spectroscopy of atomic absorption). The results showed that using initial concentration of ferrous iron of 6.75gL-1 were extracted 99% of copper by bacterial leaching.

How Will Copper Contamination Constrain Future Global Steel Recycling?

PubMed

Daehn, Katrin E; Cabrera Serrenho, André; Allwood, Julian M

2017-06-06

Copper in steel causes metallurgical problems, but is pervasive in end-of-life scrap and cannot currently be removed commercially once in the melt. Contamination can be managed to an extent by globally trading scrap for use in tolerant applications and dilution with primary iron sources. However, the viability of long-term strategies can only be evaluated with a complete characterization of copper in the global steel system and this is presented in this paper. The copper concentration of flows along the 2008 steel supply chain is estimated from a survey of literature data and compared with estimates of the maximum concentration that can be tolerated in steel products. Estimates of final steel demand and scrap supply by sector are taken from a global stock-saturation model to determine when the amount of copper in the steel cycle will exceed that which can be tolerated. Best estimates show that quantities of copper arising from conventional scrap preparation can be managed in the global steel system until 2050 assuming perfectly coordinated trade and extensive dilution, but this strategy will become increasingly impractical. Technical and policy interventions along the supply chain are presented to close product loops before this global constraint.

Effects of copper and arsenic stress on the development of Norway spruce somatic embryos and their visualization with the environmental scanning electron microscope.

PubMed

Đorđević, Biljana; Neděla, Vilém; Tihlaříková, Eva; Trojan, Václav; Havel, Ladislav

2018-05-18

Somatic embryogenesis is an important biotechnological technique which can be used in studies associated with environmental stress. Four embryogenic cell lines of Norway spruce were grown on media enriched with copper and arsenic in concentration ranges 50-500 μM and 10-50 μM, respectively. The effects were observed during subsequent stages of somatic embryogenesis, the characteristics evaluated being proliferation potential, average number of somatic embryos obtained per g/fresh weight, morphology of developed somatic embryos, metal uptake, and microanalysis of macro- and micronutrients uptake. Copper and arsenic at higher concentrations significantly reduced the growth of early somatic embryos. In almost all treatments, the cell line V-1-3 showed the best performance compared with the other lines tested. Environmental scanning electron microscopy was used to visualize and identify morphological abnormalities in the development of somatic embryos. Abnormalities observed were classified into several categories: meristemless somatic embryos, somatic embryos with disrupted meristem, reduced number of cotyledons, single cotyledon and fused cotyledons. With the application of a low temperature method for the environmental scanning electron microscope, samples were stabilized and whole meristems could be investigated in their native state. As far as we are aware, this is the first report of the effect of copper and arsenic during the process of somatic embryogenesis and the first to evaluate the content of macro and micronutrients uptake in Norway spruce. Copyright © 2018 Elsevier B.V. All rights reserved.

Ecological risk assessment of copper and cadmium in surface waters of Chesapeake Bay watershed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hall, L.W. Jr.; Scott, M.C.; Killen, W.D.

1998-06-01

This ecological risk assessment was designed to characterize risk of copper and cadmium exposure in the Chesapeake Bay watershed by comparing the probability distributions of environmental exposure concentrations with the probability distributions of species response data determined from laboratory studies. The overlap of these distributions was a measure of risk to aquatic life. Dissolved copper and cadmium exposure data were available from six primary data sources covering 102 stations in 18 basins in the Chesapeake Bay watershed from 1985 through 1996. Highest environmental concentrations of copper (based on 90th percentiles) were reported in the Chesapeake and Delaware (C and D)more » Canal, Choptank River, Middle River, and Potomac River; the lowest concentrations of copper were reported in the lower and middle mainstem Chesapeake Bay and Nanticoke River. Based on the calculation of 90th percentiles, cadmium concentrations were highest in the C and D Canal, Potomac River, Upper Chesapeake Bay, and West Chesapeake watershed. Lowest environmental concentrations of cadmium were reported in the lower and middle mainstem Chesapeake Bay and Susquehanna River. The ecological effects data used for this risk assessment were derived primarily from acute copper and cadmium laboratory toxicity tests conducted in both fresh water and salt water; chronic data were much more limited. The 10th percentile (concentration protecting 90% of the species) for all species derived from the freshwater acute copper toxicity database was 8.3 {micro}g/L. For acute saltwater copper data, the 10th percentile for all species was 6.3 {micro}g/L copper. The acute 10th percentile for all saltwater species was 31.7 {micro}g/L cadmium. Highest potential ecological risk from copper exposures was reported in the C and D Canal area of the northern Chesapeake Bay watershed.« less

Efficient removal of copper from wastewater by using mechanically activated calcium carbonate.

PubMed

Hu, Huimin; Li, Xuewei; Huang, Pengwu; Zhang, Qiwu; Yuan, Wenyi

2017-12-01

Copper removal from aqueous solution is necessary from the stances of both environmental protection and copper resource recycling. It is important to develop a new chemical precipitation method suitable for removing copper particularly at low concentration as the case of waste mine water, with regards to the various problems related to the current precipitation methods by using strong alkalis or soluble sulfides. In this research, we studied a possible chemical precipitation of copper ions at concentration around 60 mg/L or lower by cogrinding copper sulfate in water with calcium carbonate (CaCO 3 ) using wet stirred ball milling. With the aid of ball milling, copper precipitation as a basic sulfate (posnjakite: Cu 4 (SO 4 ) (OH) 6 ·H 2 O) occurred at a very high copper removal rate of 99.76%, to reduce the residual copper concentration in the solution less than 0.5 mg/L, reaching the discharge limit, even with the addition amount of CaCO 3 as a stoichiometric ratio of CaCO 3 /Cu 2+ at 1:1. It is more interesting to notice that, at the same conditions, other heavy metals such as Ni, Mn, Zn and Cd do not precipitate obviously just with CaCO 3 addition at CaCO 3 /M 2+ at 1:1 so that the precipitate without the impurities can be processed as good source to recover copper. This newly proposed concept can be further developed to treat wastewaters with other metals to serve both purposes of environmental purification and resource recovery in a similar way. Copyright © 2017 Elsevier Ltd. All rights reserved.

The effects of copper on blood and biochemical parameters of rainbow trout (Oncorhynchus mykiss)

USGS Publications Warehouse

Dethloff, G.M.; Schlenk, D.; Khan, S.; Bailey, H.C.

1999-01-01

Metals are released into aquatic systems from many sources, often at sublethal concentrations. The effects of sublethal concentrations of metals on fish are not entirely understood. The objective of this study was to determine the hematological and biochemical effects of a range of copper concentrations (6.4, 16.0, 26.9 ??g Cu/L) on rainbow trout (Oncorhynchus mykiss) over a prolonged period of time. Trout were exposed to copper, and, at intervals of 3, 7, 14, and 21 days, selected parameters were evaluated. Hemoglobin, hematocrit, plasma glucose, and plasma cortisol levels were elevated in trout exposed to 26.9 ??g Cu/L at day 3 and then returned to levels comparable to control fish. Plasma protein and lactate levels were not significantly altered in trout from any copper treatment. Hepatic copper concentration and hepatic metallothionein mRNA expression were consistently elevated in trout exposed to 26.9 ??g Cu/L. Both of these parameters stabilized by day 3, with only hepatic copper concentration showing a further increase at day 21. Hepatic copper concentration and hepatic metallothionein mRNA expression appear to be robust indicators of copper exposure. Most blood-based parameters evaluated appear to be associated with a transitory, nonspecific stress response. The return of elevated hematological and biochemical parameters to control levels after 3 days and thestabilization of hepatic metallothionein mRNA expression and copper concentration over a similar time period suggested acclimation to dissolved copper at 26.9 ??g/L. Further analysis of the data on blood-based parameters indicated that certain parameters (hemoglobin, hematocrit, plasma glucose, plasma cortisol) may be useful in field monitoring.

Copper (II) Removal In Anaerobic Continuous Column Reactor System By Using Sulfate Reducing Bacteria

NASA Astrophysics Data System (ADS)

Bilgin, A.; Jaffe, P. R.

2017-12-01

Copper is an essential element for the synthesis of the number of electrons carrying proteins and the enzymes. However, it has a high level of toxicity. In this study; it is aimed to treat copper heavy metal in anaerobic environment by using anaerobic continuous column reactor. Sulfate reducing bacteria culture was obtained in anaerobic medium using enrichment culture method. The column reactor experiments were carried out with bacterial culture obtained from soil by culture enrichment method. The system is operated with continuous feeding and as parallel. In the first rector, only sand was used as packing material. The first column reactor was only fed with the bacteria nutrient media. The same solution was passed through the second reactor, and copper solution removal was investigated by continuously feeding 15-600 mg/L of copper solution at the feeding inlet in the second reactor. When the experiment was carried out by adding the 10 mg/L of initial copper concentration, copper removal in the rate of 45-75% was obtained. In order to determine the use of carbon source during copper removal of mixed bacterial cultures in anaerobic conditions, total organic carbon TOC analysis was used to calculate the change in carbon content, and it was calculated to be between 28% and 75%. When the amount of sulphate is examined, it was observed that it changed between 28-46%. During the copper removal, the amounts of sulphate and carbon moles were equalized and more sulfate was added by changing the nutrient media in order to determine the consumption of sulphate or carbon. Accordingly, when the concentration of added sulphate is increased, it is calculated that between 35-57% of sulphate is spent. In this system, copper concentration of up to 15-600 mg / L were studied.

Statistical Inference in the Learning of Novel Phonetic Categories

ERIC Educational Resources Information Center

Zhao, Yuan

2010-01-01

Learning a phonetic category (or any linguistic category) requires integrating different sources of information. A crucial unsolved problem for phonetic learning is how this integration occurs: how can we update our previous knowledge about a phonetic category as we hear new exemplars of the category? One model of learning is Bayesian Inference,…

Copper-catalyzed intermolecular and regioselective aminofluorination of styrenes: facile access to β-fluoro-N-protected phenethylamines.

PubMed

Saavedra-Olavarría, Jorge; Arteaga, Gean C; López, Jhon J; Pérez, Edwin G

2015-02-25

A copper-catalyzed regio- and intermolecular aminofluorination of styrenes has been developed. In this reaction Ph-I=N-Ts and Et3N·3HF act as nitrogen and fluorine sources, respectively. The obtained β-fluoro-N-Ts-phenethylamines can be N-alkylated with subsequent deprotection affording the corresponding β-fluoro-N-alkylated phenethylamines, which are interesting building blocks for compounds acting on neuronal targets.

Copper-catalyzed aerobic oxidative synthesis of α-ketoamides from methyl ketones, amines and NIS at room temperature.

PubMed

Zhang, Juan; Wei, Ying; Lin, Shaoxia; Liang, Fushun; Liu, Pengjun

2012-12-14

A simple, efficient and practical copper-catalyzed aerobic oxidative synthesis of α-ketoamides from aryl methyl ketones, aliphatic amines and N-iodosuccinimide (NIS) has been developed. The one-pot reaction may proceed smoothly at room temperature in the open air. The possible mechanism for the formation of α-ketoamides was proposed. Molecular oxygen in air functions as both an oxidant and an oxygen source.

40 CFR 464.34 - New source performance standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... scrubbed) effluent standards for copper, lead, zinc, total phenols, oil and grease, and TSS. For non...) 0.0129 0.0071 Lead (T) 0.0237 0.0116 Zinc (T) 0.0437 0.0165 Oil and grease 1.34 0.446 TSS 0.67 0.536... average Annual average 1 (mg/l) 2 (mg/l) 2 Copper (T) 0.29 0.16 0.0029 Lead (T) 0.53 0.26 0.0067 Zinc (T...

40 CFR 464.34 - New source performance standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... scrubbed) effluent standards for copper, lead, zinc, total phenols, oil and grease, and TSS. For non...) 0.0129 0.0071 Lead (T) 0.0237 0.0116 Zinc (T) 0.0437 0.0165 Oil and grease 1.34 0.446 TSS 0.67 0.536... average Annual average 1 (mg/l) 2 (mg/l) 2 Copper (T) 0.29 0.16 0.0029 Lead (T) 0.53 0.26 0.0067 Zinc (T...

Enantioselective and regiodivergent copper-catalyzed conjugate addition of trialkylaluminium reagents to extended nitro-Michael acceptors.

PubMed

Tissot, Matthieu; Müller, Daniel; Belot, Sébastien; Alexakis, Alexandre

2010-06-18

The first highly enantioselective and regiodivergent conjugate addition of trialkylaluminium reagents to nitrodienes and nitroenynes is described. By a design of the substrate and a fine-tuning of the reaction conditions, it is possible to selectively form the 1,4- or 1,6-adduct. The same combination of catalyst, copper source, and a ferrocene-based phosphine ligand afforded enantioselectivities up to 95% and 91%, respectively.

40 CFR 60.16 - Priority list.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Categories Priority Number 1 Source Category 1. Synthetic Organic Chemical Manufacturing Industry (SOCMI) and Volatile Organic Liquid Storage Vessels and Handling Equipment (a) SOCMI unit processes (b) Volatile organic liquid (VOL) storage vessels and handling equipment (c) SOCMI fugitive sources (d) SOCMI secondary...

Removal of lead, cadmium, zinc, and copper from industrial wastewater by carbon developed from walnut, hazelnut, almond, pistachio shell, and apricot stone.

PubMed

Kazemipour, Maryam; Ansari, Mehdi; Tajrobehkar, Shabnam; Majdzadeh, Majdeh; Kermani, Hamed Reihani

2008-01-31

In this work, adsorption of copper (Cu), zinc (Zn), lead (Pb), and cadmium (Cd) that exist in industrial wastewater onto the carbon produced from nutshells of walnut, hazelnut, pistachio, almond, and apricot stone has been investigated. All the agricultural shell or stone used were ground, sieved to a defined size range, and carbonized in an oven. Time and temperature of heating were optimized at 15 min and 800 degrees C, respectively, to reach maximum removal efficiency. Removal efficiency was optimized regarding to the initial pH, flow rate, and dose of adsorbent. The maximum removal occurred at pH 6-10, flow rate of 3 mL/min, and 0.1g of the adsorbent. Capacity of carbon sources for removing cations will be considerably decreased in the following times of passing through them. Results showed that the cations studied significantly can be removed by the carbon sources. Efficiency of carbon to remove the cations from real wastewater produced by copper industries was also studied. Finding showed that not only these cations can be removed considerably by the carbon sources noted above, but also removing efficiency are much more in the real samples. These results were in adoption to those obtained by standard mixture synthetic wastewater.

77 FR 49489 - Oil and Natural Gas Sector: New Source Performance Standards and National Emission Standards for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-16

...This action finalizes the review of new source performance standards for the listed oil and natural gas source category. In this action the EPA revised the new source performance standards for volatile organic compounds from leaking components at onshore natural gas processing plants and new source performance standards for sulfur dioxide emissions from natural gas processing plants. The EPA also established standards for certain oil and gas operations not covered by the existing standards. In addition to the operations covered by the existing standards, the newly established standards will regulate volatile organic compound emissions from gas wells, centrifugal compressors, reciprocating compressors, pneumatic controllers and storage vessels. This action also finalizes the residual risk and technology review for the Oil and Natural Gas Production source category and the Natural Gas Transmission and Storage source category. This action includes revisions to the existing leak detection and repair requirements. In addition, the EPA has established in this action emission limits reflecting maximum achievable control technology for certain currently uncontrolled emission sources in these source categories. This action also includes modification and addition of testing and monitoring and related notification, recordkeeping and reporting requirements, as well as other minor technical revisions to the national emission standards for hazardous air pollutants. This action finalizes revisions to the regulatory provisions related to emissions during periods of startup, shutdown and malfunction.

Heavy metal pollution among autoworkers. II. Cadmium, chromium, copper, manganese, and nickel.

PubMed Central

Clausen, J; Rastogi, S C

1977-01-01

Garages and auto-repair workshops may be polluted with other heavy metals besides lead. Blood of autoworkers with high lead content was analysed for cadmium, chromium, copper manganese, nickel, ALAD activity and carboxyhaemoglobin level. Cadmium and copper levels in blood of autoworkers were comparable with those of the control subjects while chroimium and nickel levels were significantly higher (P less than 0-01 for both metals), and scattered raised values of manganese were found. There was no significant mutual correlation between levels of various heavy metals determined in whole blood. High copper levels were slightly related to decreasing ALAD activity (P less than 0-1). Nineteen per cent of autoworkers were found to have an abnormally blood level of carboxyhaemoglobin. The amount of particulate heavy metal in autoworkshop air was not related to biochemical abnormalities found in the autoworkers. Various sources of pollution of these heavy metals in autoworkshops are discussed. PMID:71915

Copper(II) binding by dissolved organic matter: Importance of the copper-to-dissolved organic matter ratio and implications for the Biotic Ligand Model

USGS Publications Warehouse

Craven, Alison M.; Aiken, George R.; Ryan, Joseph N.

2012-01-01

The ratio of copper to dissolved organic matter (DOM) is known to affect the strength of copper binding by DOM, but previous methods to determine the Cu2+–DOM binding strength have generally not measured binding constants over the same Cu:DOM ratios. In this study, we used a competitive ligand exchange–solid-phase extraction (CLE-SPE) method to determine conditional stability constants for Cu2+–DOM binding at pH 6.6 and 0.01 M ionic strength over a range of Cu:DOM ratios that bridge the detection windows of copper-ion-selective electrode and voltammetry measurements. As the Cu:DOM ratio increased from 0.0005 to 0.1 mg of Cu/mg of DOM, the measured conditional binding constant (cKCuDOM) decreased from 1011.5 to 105.6 M–1. A comparison of the binding constants measured by CLE-SPE with those measured by copper-ion-selective electrode and voltammetry demonstrates that the Cu:DOM ratio is an important factor controlling Cu2+–DOM binding strength even for DOM isolates of different types and different sources and for whole water samples. The results were modeled with Visual MINTEQ and compared to results from the biotic ligand model (BLM). The BLM was found to over-estimate Cu2+ at low total copper concentrations and under-estimate Cu2+ at high total copper concentrations.

Morphogenesis of nanostructures in glancing angle deposition of metal thin film coatings

NASA Astrophysics Data System (ADS)

Brown, Timothy James

Atomic vapors condensed onto solid surfaces form a remarkable category of condensed matter materials, the so-called thin films, with a myriad of compositions, morphological structures, and properties. The dynamic process of atomic condensation exhibits self-assembled pattern formation, producing morphologies with atomic-scale three- dimensional structures of seemingly limitless variety. This study attempts to shed new light on the dynamical growth processes of thin film deposition by analyzing in detail a previously unreported specific distinct emergent structure, a crystalline triangular-shaped spike that grows within copper and silver thin films. I explored the deposition parameters that lead to the growth of these unique structures, referred to as "nanospikes", fabricating approximately 55 thin films and used scanning electron microscopy and x-ray diffraction analysis. The variation of parameters include: vapor incidence angle, film thickness, substrate temperature, deposition rate, deposition material, substrate, and source-to-substrate distance. Microscopy analysis reveals that the silver and copper films deposited at glancing vapor incidence angles, 80 degrees and greater, have a high degree of branching interconnectivity between adjacent inclined nanorods. Diffraction analysis reveals that the vapor incidence angle influences the sub-populations of crystallites in the films, producing two different [110] crystal texture orientations. I hypothesize that the growth of nanospikes from nanorods is initiated by the stochastic arrival of vapor atoms and photons emitted from the deposition source at small diameter nanorods, and then driven by localized heating from vapor condensation and photon absorption. Restricted heat flow due to nanoscale thermal conduction maintains an elevated local temperature at the nanorod, enhancing adatom diffusion and enabling fast epitaxial crystal growth, leading to the formation and growth of nanospikes. Electron microscopy and x-ray diffraction analysis, and comparisons to related scientific literature, support this hypothesis. I also designed a highly modular ultrahigh vacuum deposition chamber, capable of concurrently mounting several different pieces of deposition equipment, that allows for a high degree of control of the growth dynamics of deposited thin films. I used the newly designed chamber to fabricate tailor-made nanostructured tantalum films for use in ultracapacitors, for the Cabot Corporation.

Modeling the formation of porphyry-copper ores

USGS Publications Warehouse

Ingebritsen, Steven E.

2012-01-01

Porphyry-copper ore systems, the source of much of the world's copper and molybdenum, form when metal-bearing fluids are expelled from shallow, degassing magmas. On page 1613 of this issue, Weis et al. (1) demonstrate that self-organizing processes focus metal deposition. Specifically, their simulation studies indicate that ores develop as consequences of dynamic variations in rock permeability driven by injection of volatile species from rising magmas. Scenarios with a static permeability structure could not reproduce key field observations, whereas dynamic permeability responses to magmatic-fluid injection localized a metal-precipitation front where enrichment by a factor of 103 could be achieved [for an overview of their numerical-simulation model CSMP++, see (2)].

Development document for proposed effluent-limitations guidelines and standards for shipbuilding and repair. Point-source category

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-12-01

The document contains a discussion of the technical rationale for effluent limitations guidelines for the Shipbuilding and Repair Point Source Category, and the control and treatment technologies which form the basis for these guidelines.

Dry atmospheric deposition rates of metals along a coastal transect in southern California

NASA Astrophysics Data System (ADS)

Sabin, Lisa D.; Schiff, Kenneth C.

While recent studies indicate atmospheric deposition is a significant source of metals to the Santa Monica Bay and coastal river systems of the Los Angeles area, the spatial extent of the atmospheric source along the entire southern California coast has not been measured in 30 years. This study provides measurements of dry atmospheric deposition of chromium, copper, lead, nickel and zinc at eight sites located along the coast between Santa Barbara and San Diego, and compares these data to historic measurements from the 1970s. Median dry deposition fluxes across sites ranged between 0.23 and 3.6 (chromium), 0.21 and 5.4 (nickel), 0.52 and 14 (lead), 0.89 and 29 (copper), and 4.8 and 160 (zinc) μg m -2 day -1. Differences in metal dry deposition rates observed between sites were dominated by proximity to urban areas and/or other nearby sources, with the highest metal fluxes observed near the Los Angeles Harbor (LAH) and San Diego Bay (SDB) sites. Compared with data from the 1970s, lead fluxes were typically one to two orders of magnitude lower in the present study (2006), indicating atmospheric sources of this metal have decreased over the past three decades in southern California. Chromium fluxes were also lower in 2006 compared with the 1970s, although to a lesser extent than for lead. In contrast, copper and zinc fluxes were typically within the same order of magnitude between the two time periods, with some higher measurements observed in 2006 compared with the 1970s at the LAH and SDB sites. This result indicates atmospheric sources of copper and zinc have not decreased over the past three decades in southern California, and have increased near our harbor/urban sites. Differences in sampling conditions (e.g., Santa Ana winds) and measurement techniques may also explain, in part, the differences observed in metal flux rates for these time periods. However, these limitations were most important for those metals with the smallest difference in flux rates measured in the 1970s vs. 2006 (e.g., chromium).

Identifying Marine Copper-Binding Ligands in Seawater

NASA Astrophysics Data System (ADS)

Whitby, H.; Hollibaugh, J. T.; Maldonado, M. T.; Ouchi, S.; van den Berg, S. M.

2016-02-01

Complexation reactions are important because they affect the bioavailability of trace metals such as copper and iron. For example, organic complexation can determine whether copper is a limiting or a toxic micronutrient at natural levels. Copper competes with iron for complexing ligands, and when iron is limiting, copper can also substitute for iron in some metabolic pathways. The speciation of copper can be measured using complexing capacity titrations, which provide the concentration of individual ligand classes (L1, L2 etc.) and the complex stabilities (log K). Using methods recently developed in our laboratory, we show that the ligands within these classes can be measured independently of titrations, thus confirming the titration method and simultaneously identifying the ligands within each class. Thiols were identified as the L1 ligand class and humic compounds as the weaker L2 class in samples from coastal Georgia, USA, collected monthly from April to December. Log K values of the ligand complexes were consistent with values expected for thiols and humic substances. Recent results from culture studies and from samples collected along Line P, a coastal - oceanic transect in the HNLC region of the NE subarctic Pacific, will be presented in comparison to the estuarine results. This comparison will help to broaden our perspective on copper complexation and the ligands responsible, furthering our understanding of ligand sources and life cycles.

Photoinduced, Copper-Catalyzed Carbon-Carbon Bond Formation with Alkyl Electrophiles: Cyanation of Unactivated Secondary Alkyl Chlorides at Room Temperature.

PubMed

Ratani, Tanvi S; Bachman, Shoshana; Fu, Gregory C; Peters, Jonas C

2015-11-04

We have recently reported that, in the presence of light and a copper catalyst, nitrogen nucleophiles such as carbazoles and primary amides undergo C-N coupling with alkyl halides under mild conditions. In the present study, we establish that photoinduced, copper-catalyzed alkylation can also be applied to C-C bond formation, specifically, that the cyanation of unactivated secondary alkyl chlorides can be achieved at room temperature to afford nitriles, an important class of target molecules. Thus, in the presence of an inexpensive copper catalyst (CuI; no ligand coadditive) and a readily available light source (UVC compact fluorescent light bulb), a wide array of alkyl halides undergo cyanation in good yield. Our initial mechanistic studies are consistent with the hypothesis that an excited state of [Cu(CN)2](-) may play a role, via single electron transfer, in this process. This investigation provides a rare example of a transition metal-catalyzed cyanation of an alkyl halide, as well as the first illustrations of photoinduced, copper-catalyzed alkylation with either a carbon nucleophile or a secondary alkyl chloride.

Utilization of flotation wastes of copper slag as raw material in cement production.

PubMed

Alp, I; Deveci, H; Süngün, H

2008-11-30

Copper slag wastes, even if treated via processes such as flotation for metal recovery, still contain heavy metals with hazardous properties posing environmental risks for disposal. This study reports the potential use of flotation waste of a copper slag (FWCS) as iron source in the production of Portland cement clinker. The FWCS appears a suitable raw material as iron source containing >59% Fe(2)O(3) mainly in the form of fayalite (Fe(2)SiO(4)) and magnetite (Fe(3)O(4)). The clinker products obtained using the FWCS from the industrial scale trial operations over a 4-month period were characterised for the conformity of its chemical composition and the physico-mechanical performance of the resultant cement products was evaluated. The data collected for the clinker products produced using an iron ore, which is currently used as the cement raw material were also included for comparison. The results have shown that the chemical compositions of all the clinker products including those of FWCS are typical of a Portland cement clinker. The mechanical performance of the standard mortars prepared from the FWCS clinkers were found to be similar to those from the iron ore clinkers with the desired specifications for the industrial cements e.g. CEM I type cements. Furthermore, the leachability tests (TCLP and SPLP) have revealed that the mortar samples obtained from the FWCS clinkers present no environmental problems while the FWCS could act as the potential source of heavy metal contamination. These findings suggest that flotation wastes of copper slag (FWCS) can be readily utilised as cement raw material due to its availability in large quantities at low cost with the further significant benefits for waste management/environmental practices of the FWCS and the reduced production and processing costs for cement raw materials.

Integrated miniature fluorescent probe to leverage the sensing potential of ZnO quantum dots for the detection of copper (II) ions.

PubMed

Ng, Sing Muk; Wong, Derrick Sing Nguong; Phung, Jane Hui Chiun; Chin, Suk Fun; Chua, Hong Siang

2013-11-15

Quantum dots are fluorescent semiconductor nanoparticles that can be utilised for sensing applications. This paper evaluates the ability to leverage their analytical potential using an integrated fluorescent sensing probe that is portable, cost effective and simple to handle. ZnO quantum dots were prepared using the simple sol-gel hydrolysis method at ambient conditions and found to be significantly and specifically quenched by copper (II) ions. This ZnO quantum dots system has been incorporated into an in-house developed miniature fluorescent probe for the detection of copper (II) ions in aqueous medium. The probe was developed using a low power handheld black light as excitation source and three photo-detectors as sensor. The sensing chamber placed between the light source and detectors was made of 4-sided clear quartz windows. The chamber was housed within a dark compartment to avoid stray light interference. The probe was operated using a microcontroller (Arduino Uno Revision 3) that has been programmed with the analytical response and the working algorithm of the electronics. The probe was sourced with a 12 V rechargeable battery pack and the analytical readouts were given directly using a LCD display panel. Analytical optimisations of the ZnO quantum dots system and the probe have been performed and further described. The probe was found to have a linear response range up to 0.45 mM (R(2)=0.9930) towards copper (II) ion with a limit of detection of 7.68×10(-7) M. The probe has high repeatable and reliable performance. Copyright © 2013 Elsevier B.V. All rights reserved.

Water and sediment study of the Snake River watershed, Colorado, Oct. 9-12, 2001

USGS Publications Warehouse

Fey, D.L.; Church, S.E.; Unruh, D.M.; Bove, D.J.

2002-01-01

The Snake River watershed, located upstream from Dillon Reservoir in the central mountains of Colorado, has been affected by historical base-metal mining. Trout stocked in the Snake River for recreational purposes do not survive through the winter. Sediment cores analyzed by previous investigators from the reservoir revealed elevated concentrations of base metals and mercury. We collected 36 surface water samples (filtered and unfiltered) and 38 streambed-sediment samples from streams in the Snake River watershed. Analyses of the sediment and water samples show that concentrations of several metals exceed aquatic life standards in one or both media. Ribbon maps showing dissolved concentrations of zinc, cadmium, copper, and manganese in water (0.45-micron filtered and corrected for the ameliorating effect of hardness), and copper, cadmium, and zinc in sediment indicate reaches where toxic effects on trout would be expected and stream reaches where toxicity standards for rainbow, brown, and brook trout are exceeded. Instantaneous loads for sulfate, strontium, iron, cadmium, copper, and zinc were calculated from 0.45-micron-filtered water concentrations and discharge measurements were made at each site. Sulfate and strontium behave conservatively, whereas copper, cadmium, and zinc are reactive. The dissolved copper load entering the reservoir is less than 20 percent of the value calculated from some upper reaches; copper is transferred to suspended and or streambed sediment by sorption to iron oxyhydroxides. Higher percentages of zinc and cadmium reach the reservoir in dissolved form; however, load calculations indicate that some of these metals are also precipitated out of solution. The most effective remediation activities should be concentrated on reducing the dissolved loads of zinc, cadmium, and copper in two reaches of lower Peru Creek between the confluence with the Snake River and Cinnamon Gulch. We analyzed all streambed sediment for mercury and selected streambed-sediment and reservoir core samples for lead isotope signatures. Results indicate that the mercury anomaly in the reservoir sediment was not from any known source in the Snake River, Blue River, or Tenmile Creek watersheds. Its source remains an enigma.

40 CFR 98.190 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Lime Manufacturing § 98.190 Definition of the source category. (a) Lime manufacturing plants (LMPs) engage in the manufacture of a lime product (e.g., calcium oxide, high-calcium quicklime, calcium hydroxide, hydrated lime, dolomitic quicklime, dolomitic hydrate, or...

Proposed Approval of California Air Plan Revision; Yolo-Solano Air Quality Management District; VOC Source Categories; Negative Declarations

EPA Pesticide Factsheets

EPA is taking final action to approve a revision to the YSAQMD portion of the California SIP concerning YSAQMD negative declarations for several VOC source categories included in its RACT State Implementation Plan Analysis.

Residual Risk Assessment for the Ferroalloys Source Category in Support of the September Supplemental Proposal

EPA Pesticide Factsheets

This document contains the methods and the results of baseline risk assessments (i.e., after the implementation of the MACT standard) and the results of the post-control scenario risk assessment performed for the ferroalloys source category.

28 CFR 25.4 - Record source categories.

Code of Federal Regulations, 2010 CFR

2010-07-01

....4 Judicial Administration DEPARTMENT OF JUSTICE DEPARTMENT OF JUSTICE INFORMATION SYSTEMS The National Instant Criminal Background Check System § 25.4 Record source categories. It is anticipated that... to the NICS Index. Information in the NCIC and III systems that will be searched during a background...

Reply to ``Comment on `Relation between copper {ital L} x-ray fluorescence and 2{ital p} x-ray photoelectron spectroscopies` ``

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawai, J.; Maeda, K.; Nakajima, K.

1995-08-15

Ohno`s preceding Comment [Phys. Rev. B 52, 6127 (1995)] was based on experimental raw spectra of copper {ital L} x-ray emission. The Cu {ital L} x-ray emission spectra were, however, heavily smeared by the self-absorption effect, which was a source of contradiction. The electronic structure of divalent copper oxide was calculated placing one core hole and two 3{ital d} holes, with the result that the spectator 3{ital d} holes were delocalized in the adiabatic limit. This implies that the spectator 3{ital d} hole produced by the {ital L}{sub 1,2}{ital L}{sub 3}{ital M}{sub 4,5} Coster-Kronig transition preceding the {ital L}{sub 3}-{italmore » M} x-ray emission will be mostly delocalized at the time of the {ital L}{sub 3}-{ital M} x-ray emission, and thus the spectator satellite will be weaker than is expected for the free atom. Ohno did not consider this delocalization, which was another source of contradiction.« less

CuO nanoparticles encapsulated inside Al-MCM-41 mesoporous materials via direct synthetic route

PubMed Central

Huo, Chengli; Ouyang, Jing; Yang, Huaming

2014-01-01

Highly ordered aluminum-containing mesoporous silica (Al-MCM-41) was prepared using attapulgite clay mineral as a Si and Al source. Mesoporous complexes embedded with CuO nanoparticles were subsequently prepared using various copper sources and different copper loadings in a direct synthetic route. The resulting CuO/Al-MCM-41 composite possessed p6mm hexagonally symmetry, well-developed mesoporosity, and relatively high BET surface area. In comparison to pure silica, these mesoporous materials embedded with CuO nanoparticles exhibited smaller pore diameter, thicker pore wall, and enhanced thermal stability. Long-range order in the aforementioned samples was observed for copper weight percentages as high as 30%. Furthermore, a significant blue shift of the absorption edge for the samples was observed when compared with that of bulk CuO. H2-TPR measurements showed that the direct-synthesized CuO/Al-MCM-41 exhibited remarkable redox properties compared to the post-synthesized samples, and most of the CuO nanoparticles were encapsulated within the mesoporous structures. The possible interaction between CuO and Al-MCM-41 was also investigated. PMID:24419589

Heavy metals in the atmosphere coming from a copper smelter in Chile

NASA Astrophysics Data System (ADS)

Romo-Kröger, C. M.; Morales, J. R.; Dinator, M. I.; Llona, F.; Eaton, L. C.

The Chilean mine El Teniente is the world's largest underground copper mine. It operates a giant smelter at Caletones (34° 7' S, 70° 27' W) and we have found it is the major source of air contamination in the region. In August 1991 a special circumstance occurred due to a labor strike, with total cessation of activities. A time series analysis of airborne particles collected at a site about 13 km from the smelter was performed in a period including the strike. The PIXE method and other techniques were used to analyse fine (<2.5 μm) and coarse (2.5-15 μm) particles on Nuclepore filters. S, Cu, Zn and As were quite enriched in normal working periods relative to the strike period. Elemental characterization of soil samples by radioactive source analysis demonstrated that this group of elements did not come from airborne soil dust. Cluster analyses of the interelement correlation matrices, resulting from PIXE data, showed one group (Si, K, Ca, Fe) with main origin in soil and another group (S, Cu, Zn, As) coming from the copper smelter.

Laramide alteration of proterozoic diabase: A likely contributor of copper to porphyry systems in the dripping spring mountains area, Southeastern Arizona

USGS Publications Warehouse

Force, E.R.

1998-01-01

Proterozoic diabase of the Dripping Spring range occurs as sills in the Proterozoic Apache Group and the Troy Quartzite and as intrusive sheets in basement rocks. The aggregate thickness of the diabase sills and intrusive sheets averages about 450 m in the part of the range showing little mid-Tertiary extension. Laramide alteration is of two types, dominated by chlorite and actinolite, respectively, and formed mostly from clinopyroxene. Actinolite-dominated assemblages are higher in Na and Ca. Hydrothermal biotite is common in the central areas of both alteration types. Laramide alteration forms two distribution patterns: a subequant pattern centered on Laramide intrusions and small porphyry deposits, characterized by actinolitic alteration, and a more extensive branching linear pattern that follows Laramide structures, centered on the larger Ray porphyry deposit, extending toward other Laramide districts and showing both alteration types. Alteration has apparently mobilized copper and other metals from diabase. The freshest diabase samples average about 120 ppm copper with little variation. In chloritic alteration, about 100 ppm of this copper is expelled in the most completely altered rocks. In actinolitic alteration, diabase may either gain or lose copper during alteration. Chloritic alteration constitutes roughly 70 percent of the diabase alteration in the study area, where alteration averages 41 percent complete. This implies liberation of about 9 ?? 106 tons (t) copper from diabase alteration, significantly less than the 16 ?? 106 t copper in Laramide mineral deposits of the superdistrict (Ray, Superior, Chilito, Christmas). However, diabase alteration may have been a significant component of the supply of copper to the Laramide mineral districts of the area. Synmineral magmatic sources of copper are not documented in this area. The distribution of Proterozoic diabase coincides with the central part of the southeastern Arizona copper province, which may thus owe much copper availability to an unusual abundance of diabase. However, many unanswered questions remain about metal supply from altering diabase.

Estimated freshwater withdrawals in Texas, 1990

USGS Publications Warehouse

Lurry, Dee L.

1994-01-01

This report presents 1990 freshwater withdrawal estimates for Texas by source and category. Withdrawal source is either ground water or surface water. Withdrawal categories include: self-supplied irrigation, thermoelectric-power generation, water supply, industrial and mining, and other (domestic, commercial, livestock). Withdrawal data are aggregated by county, major aquifer, and principal river basin. Only the four major categories of irrigation, thermoelectric-power generation, water supply, and industrial and mining are illustrated in this report, although all data are tabulated.

Cytoplasmic Copper Detoxification in Salmonella Can Contribute to SodC Metalation but Is Dispensable during Systemic Infection

PubMed Central

Fenlon, Luke A.

2017-01-01

ABSTRACT Salmonella enterica serovar Typhimurium is a leading cause of foodborne disease worldwide. Severe infections result from the ability of S. Typhimurium to survive within host immune cells, despite being exposed to various host antimicrobial factors. SodCI, a copper-zinc-cofactored superoxide dismutase, is required to defend against phagocytic superoxide. SodCII, an additional periplasmic superoxide dismutase, although produced during infection, does not function in the host. Previous studies suggested that CueP, a periplasmic copper binding protein, facilitates acquisition of copper by SodCII. CopA and GolT, both inner membrane ATPases that pump copper from the cytoplasm to the periplasm, are a source of copper for CueP. Using in vitro SOD assays, we found that SodCI can also utilize CueP to acquire copper. However, both SodCI and SodCII have a significant fraction of activity independent of CueP and cytoplasmic copper export. We utilized a series of mouse competition assays to address the in vivo role of CueP-mediated SodC activation. A copA golT cueP triple mutant was equally as competitive as the wild type, suggesting that sufficient SodCI is active to defend against phagocytic superoxide independent of CueP and cytoplasmic copper export. We also confirmed that a strain containing a modified SodCII, which is capable of complementing a sodCI deletion, was fully virulent in a copA golT cueP background competed against the wild type. These competitions also address the potential impact of cytoplasmic copper toxicity within the phagosome. Our data suggest that Salmonella does not encounter inhibitory concentrations of copper during systemic infection. IMPORTANCE Salmonella is a leading cause of gastrointestinal disease worldwide. In severe cases, Salmonella can cause life-threatening systemic infections, particularly in very young children, the elderly, or people who are immunocompromised. To cause disease, Salmonella must survive the hostile environment inside host immune cells, a location in which most bacteria are killed. Our work examines how one particular metal, copper, is acquired by Salmonella to activate a protein important for survival within immune cells. At high levels, copper itself can inhibit Salmonella. Using a strain of Salmonella that cannot detoxify intracellular copper, we also addressed the in vivo role of copper as an antimicrobial agent. PMID:28924031

Cytoplasmic Copper Detoxification in Salmonella Can Contribute to SodC Metalation but Is Dispensable during Systemic Infection.

PubMed

Fenlon, Luke A; Slauch, James M

2017-12-15

Salmonella enterica serovar Typhimurium is a leading cause of foodborne disease worldwide. Severe infections result from the ability of S Typhimurium to survive within host immune cells, despite being exposed to various host antimicrobial factors. SodCI, a copper-zinc-cofactored superoxide dismutase, is required to defend against phagocytic superoxide. SodCII, an additional periplasmic superoxide dismutase, although produced during infection, does not function in the host. Previous studies suggested that CueP, a periplasmic copper binding protein, facilitates acquisition of copper by SodCII. CopA and GolT, both inner membrane ATPases that pump copper from the cytoplasm to the periplasm, are a source of copper for CueP. Using in vitro SOD assays, we found that SodCI can also utilize CueP to acquire copper. However, both SodCI and SodCII have a significant fraction of activity independent of CueP and cytoplasmic copper export. We utilized a series of mouse competition assays to address the in vivo role of CueP-mediated SodC activation. A copA golT cueP triple mutant was equally as competitive as the wild type, suggesting that sufficient SodCI is active to defend against phagocytic superoxide independent of CueP and cytoplasmic copper export. We also confirmed that a strain containing a modified SodCII, which is capable of complementing a sodCI deletion, was fully virulent in a copA golT cueP background competed against the wild type. These competitions also address the potential impact of cytoplasmic copper toxicity within the phagosome. Our data suggest that Salmonella does not encounter inhibitory concentrations of copper during systemic infection. IMPORTANCE Salmonella is a leading cause of gastrointestinal disease worldwide. In severe cases, Salmonella can cause life-threatening systemic infections, particularly in very young children, the elderly, or people who are immunocompromised. To cause disease, Salmonella must survive the hostile environment inside host immune cells, a location in which most bacteria are killed. Our work examines how one particular metal, copper, is acquired by Salmonella to activate a protein important for survival within immune cells. At high levels, copper itself can inhibit Salmonella Using a strain of Salmonella that cannot detoxify intracellular copper, we also addressed the in vivo role of copper as an antimicrobial agent. Copyright © 2017 American Society for Microbiology.

Eyetracking Reveals Multiple-Category Use in Induction

ERIC Educational Resources Information Center

Chen, Stephanie Y.; Ross, Brian H.; Murphy, Gregory L.

2016-01-01

Category information is used to predict properties of new category members. When categorization is uncertain, people often rely on only one, most likely category to make predictions. Yet studies of perception and action often conclude that people combine multiple sources of information near-optimally. We present a perception-action analog of…

40 CFR 51.117 - Additional provisions for lead.

Code of Federal Regulations, 2010 CFR

2010-07-01

... requirements apply to lead. To the extent they conflict, there requirements are controlling over those of the... the following point sources of lead: Primary lead smelters, Secondary lead smelters, Primary copper... or more batteries per day. Any other stationary source that actually emits 25 or more tons per year...

40 CFR 440.104 - New source performance standards (NSPS).

Code of Federal Regulations, 2011 CFR

2011-07-01

..., in-situ leach or vat-leach processes to extract copper from ores or ore waste materials. The Agency... Molybdenum Ores Subcategory § 440.104 New source performance standards (NSPS). Except as provided in subpart... technology (BADT): (a) The concentration of pollutants discharged in mine drainage from mines that produce...