South Atlantic sag basins: new petroleum system components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henry, S.G.; Mello, M.R.

Newly discovered pre-salt source rocks, reservoirs and seals need to be included as components to the petroleum systems of both sides of the South Atlantic. These new components lie between the pre-salt rift strata and the Aptian salt layers, forming large, post-rift, thermal subsidence sag basins. These are differentiated from the older rift basins by the lack of syn-rift faulting and a reflector geometry that is parallel to the base salt regional unconformity rather than to the Precambrian basement. These basins are observed in deep water regions overlying areas where both the mantle and the crust have been involved inmore » the extension. This mantle involvement creates post-rift subsiding depocenters in which deposition is continuous while proximal rift-phase troughs with little or no mantle involvement are bypassed and failed to accumulate potential source rocks during anoxic times. These features have been recognized in both West African Kwanza Basin and in the East Brasil Rift systems. The pre-salt source rocks that are in the West African sag basins were deposited in lacustrine brackish to saline water environment and are geochemically distinct from the older, syn-rift fresh to brackish water lakes, as well as from younger, post-salt marine anoxic environments of the drift phase. Geochemical analyses of the source rocks and their oils have shown a developing source rock system evolving from isolated deep rift lakes to shallow saline lakes, and culminating with the infill of the sag basin by large saline lakes to a marginally marine restricted gulf. Sag basin source rocks may be important in the South Atlantic petroleum system by charging deep-water prospects where syn-rift source rocks are overmature and the post-salt sequences are immature.« less

Burial History, Thermal Maturity, and Oil and Gas Generation History of Source Rocks in the Bighorn Basin, Wyoming and Montana

USGS Publications Warehouse

Roberts, Laura N.R.; Finn, Thomas M.; Lewan, Michael D.; Kirschbaum, Mark A.

2008-01-01

Burial history, thermal maturity, and timing of oil and gas generation were modeled for seven key source-rock units at eight well locations throughout the Bighorn Basin in Wyoming and Montana. Also modeled was the timing of cracking to gas of Phosphoria Formation-sourced oil in the Permian Park City Formation reservoirs at two well locations. Within the basin boundary, the Phosphoria is thin and only locally rich in organic carbon; it is thought that the Phosphoria oil produced from Park City and other reservoirs migrated from the Idaho-Wyoming thrust belt. Other petroleum source rocks include the Cretaceous Thermopolis Shale, Mowry Shale, Frontier Formation, Cody Shale, Mesaverde and Meeteetse Formations, and the Tertiary (Paleocene) Fort Union Formation. Locations (wells) selected for burial history reconstructions include three in the deepest parts of the Bighorn Basin (Emblem Bench, Red Point/Husky, and Sellers Draw), three at intermediate depths (Amoco BN 1, Santa Fe Tatman, and McCulloch Peak), and two at relatively shallow locations (Dobie Creek and Doctor Ditch). The thermal maturity of source rocks is greatest in the deep central part of the basin and decreases to the south, east, and north toward the basin margins. The Thermopolis and Mowry Shales are predominantly gas-prone source rocks, containing a mix of Type-III and Type-II kerogens. The Frontier, Cody, Mesaverde, Meeteetse, and Fort Union Formations are gas-prone source rocks containing Type-III kerogen. Modeling results indicate that in the deepest areas, (1) the onset of petroleum generation from Cretaceous rocks occurred from early Paleocene through early Eocene time, (2) peak petroleum generation from Cretaceous rocks occurred during Eocene time, and (3) onset of gas generation from the Fort Union Formation occurred during early Eocene time and peak generation occurred from late Eocene to early Miocene time. Only in the deepest part of the basin did the oil generated from the Thermopolis and Mowry Shales start generating gas from secondary cracking, which occurred in the late Eocene to Miocene. Also, based on modeling results, gas generation from the cracking of Phosphoria oil reservoired in the Park City Formation began in the late Eocene in the deep part of the basin but did not anywhere reach peak generation.

System and method for investigating sub-surface features of a rock formation with acoustic sources generating coded signals

DOEpatents

Vu, Cung Khac; Nihei, Kurt; Johnson, Paul A; Guyer, Robert; Ten Cate, James A; Le Bas, Pierre-Yves; Larmat, Carene S

2014-12-30

A system and a method for investigating rock formations includes generating, by a first acoustic source, a first acoustic signal comprising a first plurality of pulses, each pulse including a first modulated signal at a central frequency; and generating, by a second acoustic source, a second acoustic signal comprising a second plurality of pulses. A receiver arranged within the borehole receives a detected signal including a signal being generated by a non-linear mixing process from the first-and-second acoustic signal in a non-linear mixing zone within the intersection volume. The method also includes-processing the received signal to extract the signal generated by the non-linear mixing process over noise or over signals generated by a linear interaction process, or both.

Geochemistry of the Neoproterozoic metabasic rocks from the Negele area, southern Ethiopia: Tectonomagmatic implications

NASA Astrophysics Data System (ADS)

Yihunie, Tadesse; Adachi, Mamoru; Yamamoto, Koshi

2006-03-01

Neoproterozoic metabasic rocks along with metasediments and ultramafic rocks constitute the Kenticha and Bulbul lithotectonic domains in the Negele area. They occur as amphibolite and amphibole schist in the Kenticha, and amphibole schist and metabasalt in the Bulbul domains. These rocks are dominantly basaltic in composition and exhibit low-K tholeiitic characteristics. They are slightly enriched in large ion lithophile (LIL) and light rare earth (LRE) elements and depleted in high field strength (HFS) and heavy rare earth (HRE) elements. They exhibit chemical characteristics similar to back-arc basin and island-arc basalts, but include a few samples with slightly higher Y, Zr and Nb contents. Initial Sr isotopic ratios and ɛNd values for the Kenticha metabasic rocks range from 0.7048 to 0.7051 and from 4.7 to 9.6 whereas for the Bulbul metabasic rocks they range from 0.7032 to 0.7055 and from -0.1 to 5.5, respectively. The trace elements and Sr-Nd isotope compositions of samples from the Kenticha and Bulbul domains suggest similar, but isotopically heterogeneous magma sources. The magma is inferred to have derived from depleted source with a contribution from an enriched mantle source component.

Modified method for estimating petroleum source-rock potential using wireline logs, with application to the Kingak Shale, Alaska North Slope

USGS Publications Warehouse

Rouse, William A.; Houseknecht, David W.

2016-02-11

In 2012, the U.S. Geological Survey completed an assessment of undiscovered, technically recoverable oil and gas resources in three source rocks of the Alaska North Slope, including the lower part of the Jurassic to Lower Cretaceous Kingak Shale. In order to identify organic shale potential in the absence of a robust geochemical dataset from the lower Kingak Shale, we introduce two quantitative parameters, $\\Delta DT_\\bar{x}$ and $\\Delta DT_z$, estimated from wireline logs from exploration wells and based in part on the commonly used delta-log resistivity ($\\Delta \\text{ }log\\text{ }R$) technique. Calculation of $\\Delta DT_\\bar{x}$ and $\\Delta DT_z$ is intended to produce objective parameters that may be proportional to the quality and volume, respectively, of potential source rocks penetrated by a well and can be used as mapping parameters to convey the spatial distribution of source-rock potential. Both the $\\Delta DT_\\bar{x}$ and $\\Delta DT_z$ mapping parameters show increased source-rock potential from north to south across the North Slope, with the largest values at the toe of clinoforms in the lower Kingak Shale. Because thermal maturity is not considered in the calculation of $\\Delta DT_\\bar{x}$ or $\\Delta DT_z$, total organic carbon values for individual wells cannot be calculated on the basis of $\\Delta DT_\\bar{x}$ or $\\Delta DT_z$ alone. Therefore, the $\\Delta DT_\\bar{x}$ and $\\Delta DT_z$ mapping parameters should be viewed as first-step reconnaissance tools for identifying source-rock potential.

Geology, thermal maturation, and source rock geochemistry in a volcanic covered basin: San Juan sag, south-central Colorado

USGS Publications Warehouse

Gries, R.R.; Clayton, J.L.; Leonard, C.

1997-01-01

The San Juan sag, concealed by the vast San Juan volcanic field of south-central Colorado, has only recently benefited from oil and gas wildcat drilling and evaluations. Sound geochemical analyses and maturation modeling are essential elements for successful exploration and development. Oil has been produced in minor quantities from an Oligocene sill in the Mancos Shale within the sag, and major oil and gas production occurs from stratigraphically equivalent rocks in the San Juan basin to the south-west and in the Denver basin to the northeast. The objectives of this study were to identify potential source rocks, assess thermal maturity, and determine hydrocarbon-source bed relationships. Source rocks are present in the San Juan sag in the upper and lower Mancos Shale (including the Niobrara Member), which consists of about 666 m (2184 ft) of marine shale with from 0.5 to 3.1 wt. % organic carbon. Pyrolysis yields (S1 + S2 = 2000-6000 ppm) and solvent extraction yields (1000-4000 ppm) indicate that some intervals within the Mancos Shale are good potential source rocks for oil, containing type II organic matter, according to Rock-Eval pyrolysis assay. Oils produced from the San Juan sag and adjacent part of the San Juan basin are geochemically similar to rock extracts obtained from these potential source rock intervals. Based on reconstruction of the geologic history of the basin integrated with models of organic maturation, we conclude that most of the source rock maturation occurred in the Oligocene and Miocene. Little to no maturation took place during Laramide subsidence of the basin, when the Animas and Blanco Basin formations were deposited. The timing of maturation is unlike that of most Laramide basins in the Rocky Mountain region, where maturation occurred as a result of Paleocene and Eocene basin fill. The present geothermal gradient in the San Juan sag is slightly higher (average 3.5??C/100 m; 1.9??F/100 ft) than the regional average for southern Rocky Mountain basins; however, although the sag contains intrusives and a volcanic cover, the gradient is significantly lower than that reported for parts of the adjacent San Juan basin (4.7??C/100 m; 2.6??F/100 ft). Burial depth appears to be a more important controlling factor in the thermal history of the source rocks than local variations in the geothermal gradient due to volcanic activity. Interestingly, the thick overburden of volcanic rocks appears to have provided the necessary burial depth for maturation.

Chemometric differentiation of crude oil families in the San Joaquin Basin, California

USGS Publications Warehouse

Peters, Kenneth E.; Coutrot, Delphine; Nouvelle, Xavier; Ramos, L. Scott; Rohrback, Brian G.; Magoon, Leslie B.; Zumberge, John E.

2013-01-01

Chemometric analyses of geochemical data for 165 crude oil samples from the San Joaquin Basin identify genetically distinct oil families and their inferred source rocks and provide insight into migration pathways, reservoir compartments, and filling histories. In the first part of the study, 17 source-related biomarker and stable carbon-isotope ratios were evaluated using a chemometric decision tree (CDT) to identify families. In the second part, ascendant hierarchical clustering was applied to terpane mass chromatograms for the samples to compare with the CDT results. The results from the two methods are remarkably similar despite differing data input and assumptions. Recognized source rocks for the oil families include the (1) Eocene Kreyenhagen Formation, (2) Eocene Tumey Formation, (3–4) upper and lower parts of the Miocene Monterey Formation (Buttonwillow depocenter), and (5–6) upper and lower parts of the Miocene Monterey Formation (Tejon depocenter). Ascendant hierarchical clustering identifies 22 oil families in the basin as corroborated by independent data, such as carbon-isotope ratios, sample location, reservoir unit, and thermal maturity maps from a three-dimensional basin and petroleum system model. Five families originated from the Eocene Kreyenhagen Formation source rock, and three families came from the overlying Eocene Tumey Formation. Fourteen families migrated from the upper and lower parts of the Miocene Monterey Formation source rocks within the Buttonwillow and Tejon depocenters north and south of the Bakersfield arch. The Eocene and Miocene families show little cross-stratigraphic migration because of seals within and between the source rocks. The data do not exclude the possibility that some families described as originating from the Monterey Formation actually came from source rock in the Temblor Formation.

Sedimentary records of the Yangtze Block (South China) and their correlation with equivalent Neoproterozoic sequences on adjacent continents

NASA Astrophysics Data System (ADS)

Wang, Wei; Zhou, Mei-Fu

2012-07-01

The Neoproterozoic Danzhou Group, composed of siliciclastic sedimentary rocks interbedded with minor carbonate and volcanic rocks in the southeastern Yangtze Block, South China, is thought to be related to the breakup of Rodinia. Detrital zircon ages constrain the deposition of the Danzhou Group at ~ 770 Ma and ~ 730 Ma. The Danzhou Group contains dominant Neoproterozoic detrital zircon grains (~ 740-900 Ma) with two major age groups at ~ 740-790 Ma and ~ 810-830 Ma, suggesting the detritus was largely sourced from the widely distributed Neoproterozoic igneous plutons within the Yangtze Block. The sedimentary rocks from the lower Danzhou Group, including sandstones, siltstone and pelitic rocks, have UCC-like chemical signatures, representing mixed products of primary sources. The upper Danzhou Group received more recycled materials because the rocks have relatively higher Zr/Sc ratios, Hf contents and a greater influx of Pre-Neoproterozoic zircons. All of the rocks have high La/Sc, low Sc/Th and Co/Th ratios, consistent with sources dominantly composed of granitic to dioritic end-members from the western and northwestern Yangtze Block. Chemical compositions do not support significant contributions of mafic components. Most Neoproterozoic zircons have positive ɛHf(t) (0-17) indicative of sediments derived mainly from the western and northwestern Yangtze Block. The uni-modal Neoproterozoic zircons and felsic igneous source rocks for the Danzhou Group suggest that the Yangtze Block was an independent continent in the peripheral part of Rodinia.

Stone Quarries and Sourcing in the Carolina Slate Belt

DTIC Science & Technology

2006-04-01

a hilltop with a localized outcrop of small boulders of andesite porphyry . A revisit revealed that the site had recently been destroyed by...rocks are dacitic and include flows, tuffs, breccias, and porphyries . Metasedimentary rocks are metamudstone and fine metasandstone. The Uwharrie...Rocks of this zone, from Shingle Trap, Hattaway, and Sugarloaf Mountains, are mainly light to dark gray metadacite porphyry or metadacitic

SOURCES OF INFORMATION ON ROCK PHYSICS. CURRENT LITERATURE, FEBRUARY 28, 1962

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burgin, L.

1962-02-28

A literature review on the field of rock physics, rock mechanics, wave propagation and other related subjects is presented. The 206 references, wtth abstracts, are included under the following categories: physical properties, rock deformation, loading, engineering applications, seismology, wave propagation, and instruments and methods. In each section the articles are arranged alphabetically according to author. The titles are from material which was made available at the Colorado School of Mines, Arthur Lakes Library during February 1962. (M.C.G.)

National Assessment of Oil and Gas Project: petroleum systems and geologic assessment of oil and gas in the Southwestern Wyoming Province, Wyoming, Colorado and Utah

USGS Publications Warehouse

,

2005-01-01

The U.S. Geological Survey (USGS) completed an assessment of the undiscovered oil and gas potential of the Southwestern Wyoming Province of southwestern Wyoming, northwestern Colorado, and northeastern Utah (fig. 1). The USGS Southwestern Wyoming Province for this assessment included the Green River Basin, Moxa arch, Hoback Basin, Sandy Bend arch, Rock Springs uplift, Great Divide Basin, Wamsutter arch, Washakie Basin, Cherokee ridge, and the Sand Wash Basin. The assessment of the Southwestern Wyoming Province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation, and migration), reservoir rocks (sequence stratigraphy, petrophysical properties), and hydrocarbon traps (trap types, formation, and timing). Using this geologic framework, the USGS defined 9 total petroleum systems (TPS) and 23 assessment units (AU) within these TPSs, and quantitatively estimated the undiscovered oil and gas resources within 21 of the 23 AUs.

Nanoscale Compositional Relations in Lunar Rock Patina: Deciphering Sources for Patina Components on an Apollo 17 Station 6 Boulder

NASA Technical Reports Server (NTRS)

Christoffersen, R.; Noble, S. K.; Keller, L. P.

2014-01-01

Space weathering on the Moon and other airless bodies modifies the surfaces of regolith grains as well as the space-exposed surfaces of larger rocks and boulders. As space weathering witness plates, rocks and boulders are distinguished from regolith grains based on their ability to persist as physically intact substrates over longer time scales before being disaggregated by impact processes. Because lunar surfaces, including exposed rocks, quickly develop an optically thick layer of patina, it is important to understand the compositional relationship between patinas and their underlying rock substrates, particularly to support remote-sensing of rocky lunar terrains. Based on analytical TEM techniques, supported by focused ion beam (FIB) cross-sectioning, we have begun to systematize the multi-layer microstructural complexity of patinas on rock samples with a range of space exposure histories. Our on-going work has particularly focused on lunar rock 76015, both because it has a long (approx. 22 my) exposure history, and because its surface was exposed to patina development approximately 1 m off the regolith surface on a boulder in the Apollo 17 Station 6 boulder field. Potential sources for the 76015 patina therefore include impact-melted and vaporized material derived from the local rock substrate, as well as from the mix of large boulders and regolith in the Station 6 area. While similar, there are differences in the mineralogy and chemistry of the rocks and regolith at Station 6. We were interested to see if these, or other sources, could be distinguished in the average composition, as well as the compositional nanostratigraphy of the 76015 patina. To date we have acquired a total of 9 TEM FIB cross-sections from the 76015 patina, giving us reasonable confidence of being able to arrive at an integrated average for the patina major element composition based on analytical TEM methods.

Geochemistry of approximately 1.9 Ga sedimentary rocks from northeastern Labrador, Canada

NASA Technical Reports Server (NTRS)

Hayashi, K. I.; Fujisawa, H.; Holland, H. D.; Ohmoto, H.

1997-01-01

Fifty-eight rock chips from fifteen samples of sedimentary rocks from the Ramah Group (approximately 1.9 Ga) in northeastern Labrador, Canada, were analyzed for major and minor elements, including C and S, to elucidate weathering processes on the Earth's surface about 1.9 Ga ago. The samples come from the Rowsell Harbour, Reddick Bight, and Nullataktok Formations. Two rock series, graywackes-gray shales of the Rowsell Harbour, Reddick Bight and Nullataktok Formations, and black shales of the Nullataktok Formation, are distinguishable on the basis of lithology, mineralogy, and major and trace element chemistry. The black shales show lower concentrations than the graywackes-gray shales in TiO2 (0.3-0.7 wt% vs. 0.7-1.8 wt%), Al2O3 (9.5-20.1 wt% vs. 13.0-25.0 wt%), and sigma Fe (<1 wt% vs. 3.8-13.9 wt% as FeO). Contents of Zr, Th, U, Nb, Ce, Y, Rb, Y, Co, and Ni are also lower in the black shales. The source rocks for the Ramah Group sediments were probably Archean gneisses with compositions similar to those in Labrador and western Greenland. The major element chemistry of source rocks for the Ramah Group sedimentary rocks was estimated from the Al2O3/TiO2 ratios of the sedimentary rocks and the relationship between the major element contents (e.g., SiO2 wt%) and Al2O3/TiO2 ratios of the Archean gneisses. This approach is justified, because the Al/Ti ratios of shales generally retain their source rock values; however, the Zr/Al, Zr/Ti, and Cr/Ni ratios fractionate during the transport of sediments. The measured SiO2 contents of shales in the Ramah Group are generally higher than the estimated SiO2 contents of source rocks by approximately 5 wt%. This correction may also have to be applied when estimating average crustal compositions from shales. Two provenances were recognized for the Ramah Group sediments. Provenance I was comprised mostly of rocks of bimodal compositions, one with SiO2 contents approximately 45 wt% and the other approximately 65 wt%, and was the source for most sedimentary rocks of the Ramah Group, except for black shales of the Nullataktok Formation. The black shales were apparently derived from Provenance II that was comprised mostly of felsic rocks with SiO2 contents approximately 65 wt%. Comparing the compositions of the Ramah Group sedimentary rocks and their source rocks, we have recognized that several major elements, especially Ca and Mg, were lost almost entirely from the source rocks during weathering and sedimentation. Sodium and potassium were also leached almost entirely during the weathering of the source rocks. However, significant amounts of Na were added to the black shales and K to all the rock types during diagenesis and/or regional metamorphism. The intensity of weathering of source rocks for the Ramah Group sediments was much higher than that of typical Phanerozoic sediments, possibly because of a higher PCO2 in the Proterozoic atmosphere. Compared to the source rock values, the Fe3+/Ti ratios of many of the graywackes and gray shales of the Ramah Group are higher, the Fe2+/Ti ratios are lower, and the sigma Fe/Ti ratios are the same. Such characteristics of the Fe geochemistry indicate that these sedimentary rocks are comprised of soils formed by weathering of source rocks under an oxygen-rich atmosphere. The atmosphere about 1.9 Ga was, therefore, oxygen rich. Typical black shales of Phanerozoic age exhibit positive correlations between the organic C contents and the concentrations of S, U, and Mo, because these elements are enriched in oxygenated seawater and are removed from seawater by organic matter in sediments. However, such correlations are not found in the Ramah Group sediments. Black shales of the Ramah Group contain 1.7-2.8 wt% organic C, but are extremely depleted in sigma Fe (<1 wt% as FeO), S (<0.3 wt%), U (approximately l ppm), Mo (<5 ppm), Ni (<2 ppm), and Co (approximately 0 ppm). This lack of correlation, however, does not imply that the approximately 1.9 Ga atmosphere-ocean system was anoxic. Depletion of these elements from the Ramah Group sediments may have occurred during diagenesis.

Geochemistry, palynology, and regional geology of worldclass Upper Devonian source rocks in the Madre de Dios basin, Bolivia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Conrad, K.T.; Carpenter, D.G.

Recent exploration drilling indicates the existence of world-class source rock in the Madre de Dios basin, Bolivia. In the Pando-1 X and -2X wells, over 200 m of poorly bioturbated, organic-rich (TOC = 3-16 wt.%) prodelta to shelf mudstones in the Frasnian-Famennian Tomachi Formation contain oil-prone organic matter (hydrogen index = 400-600 mg HC/g TOC). Our calculated source prolificity indices for this interval in these wells (SPI = 15-18 tons of hydrocarbons per square meter of source rock) exceed that for the Upper Jurassic in Central Saudi Arabia. The Tomachi interval is lithologically equivalent to the Colpacucho Formation in themore » northern Altiplano, the Iquiri Formation in the Cordillera Oriental, and is coeval with other excellent source rocks in North America, Africa, and Eurasia. All of these rocks were deposited under conditions favorable for accumulation of organic matter, including a global highstand and high productivity. However, the Madre de Dios basin was situated at high latitude during the Late Devonian and some of the deposits are interpreted to be of glacial origin, indicating conditions not generally associated with organic-rich deposition. A biomarker and palynological study of Upper Devonian rocks in the Pando-1X well suggests deposition under conditions similar to certain modern fjords. High productivity resulted in preservation of abundant organic matter in the bottom sediments despite a cold, toxic water column. Low-sulfur crude oil produced from the Pando-1X well is geochemically similar to, but more mature than, extracts from associated organic-rich Tomachi samples, and was generated from deeper equivalents of these rocks.« less

Assessment of Coalbed Gas Resources in Cretaceous and Tertiary Rocks on the North Slope, Alaska, 2006

USGS Publications Warehouse

Roberts, Steve; Barker, Charles E.; Bird, Kenneth J.; Charpentier, Ronald R.; Cook, Troy; Houseknecht, David W.; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.

2006-01-01

The North Slope of Alaska is a vast area of land north of the Brooks Range, extending from the Chukchi Sea eastward to the Canadian border. This Arctic region is known to contain extensive coal deposits; hypothetical coal resource estimates indicate that nearly 4 trillion short tons of coal are in Cretaceous and Tertiary rocks. Because of the large volume of coal, other studies have indicated that this region might also have potential for significant coalbed gas resources. The present study represents the first detailed assessment of undiscovered coalbed gas resources beneath the North Slope by the USGS. The assessment is based on the total petroleum system (TPS) concept. Geologic elements within a TPS relate to hydrocarbon source rocks (maturity, hydrocarbon generation, migration), the characteristics of reservoir rocks, and trap and seal formation. In the case of coalbed gas, the coal beds serve as both source rock and reservoir. The Brookian Coalbed Gas Composite TPS includes coal-bearing rocks in Cretaceous and Tertiary strata underlying the North Slope and adjacent Alaska State waters. Assessment units (AUs) within the TPS (from oldest to youngest) include the Nanushuk Formation Coalbed Gas AU, the Prince Creek and Tuluvak Formations Coalbed Gas AU, and the Sagavanirktok Formation Coalbed Gas AU.

Temperature and petroleum generation history of the Wilcox Formation, Louisiana

USGS Publications Warehouse

Pitman, Janet K.; Rowan, Elisabeth Rowan

2012-01-01

A one-dimensional petroleum system modeling study of Paleogene source rocks in Louisiana was undertaken in order to characterize their thermal history and to establish the timing and extent of petroleum generation. The focus of the modeling study was the Paleocene and Eocene Wilcox Formation, which contains the youngest source rock interval in the Gulf Coast Province. Stratigraphic input to the models included thicknesses and ages of deposition, lithologies, amounts and ages of erosion, and ages for periods of nondeposition. Oil-generation potential of the Wilcox Formation was modeled using an initial total organic carbon of 2 weight percent and an initial hydrogen index of 261 milligrams of hydrocarbon per grams of total organic carbon. Isothermal, hydrous-pyrolysis kinetics determined experimentally was used to simulate oil generation from coal, which is the primary source of oil in Eocene rocks. Model simulations indicate that generation of oil commenced in the Wilcox Formation during a fairly wide age range, from 37 million years ago to the present day. Differences in maturity with respect to oil generation occur across the Lower Cretaceous shelf edge. Source rocks that are thermally immature and have not generated oil (depths less than about 5,000 feet) lie updip and north of the shelf edge; source rocks that have generated all of their oil and are overmature (depths greater than about 13,000 feet) are present downdip and south of the shelf edge. High rates of sediment deposition coupled with increased accommodation space at the Cretaceous shelf margin led to deep burial of Cretaceous and Tertiary source rocks and, in turn, rapid generation of petroleum and, ultimately, cracking of oil to gas.

Total Petroleum Systems of the North Carpathian Province of Poland, Ukraine, Czech Republic, and Austria

USGS Publications Warehouse

Pawlewicz, Mark

2006-01-01

Three total petroleum systems were identified in the North Carpathian Province (4047) that includes parts of Poland, Ukraine, Austria, and the Czech Republic. They are the Isotopically Light Gas Total Petroleum System, the Mesozoic-Paleogene Composite Total Petroleum System, and the Paleozoic Composite Total Petroleum System. The Foreland Basin Assessment Unit of the Isotopically Light Gas Total Petroleum System is wholly contained within the shallow sedimentary rocks of Neogene molasse in the Carpathian foredeep. The biogenic gas is generated locally as the result of bacterial activity on dispersed organic matter. Migration is also believed to be local, and gas is believed to be trapped in shallow stratigraphic traps. The Mesozoic-Paleogene Composite Total Petroleum System, which includes the Deformed Belt Assessment Unit, is structurally complex, and source rocks, reservoirs, and seals are juxtaposed in such a way that a single stratigraphic section is insufficient to describe the geology. The Menilite Shale, an organic-rich rock widespread throughout the Carpathian region, is the main hydrocarbon source rock. Other Jurassic to Cretaceous formations also contribute to oil and gas in the overthrust zone in Poland and Ukraine but in smaller amounts, because those formations are more localized than the Menilite Shale. The Paleozoic Composite Total Petroleum System is defined on the basis of the suspected source rock for two oil or gas fields in western Poland. The Paleozoic Reservoirs Assessment Unit encompasses Devonian organic-rich shale believed to be a source of deep gas within the total petroleum system. East of this field is a Paleozoic oil accumulation whose source is uncertain; however, it possesses geochemical similarities to oil generated by Upper Carboniferous coals. The undiscovered resources in the North Carpathian Province are, at the mean, 4.61 trillion cubic feet of gas and 359 million barrels of oil. Many favorable parts of the province have been extensively explored for oil and gas. The lateral and vertical variability of the structure, the distribution and complex geologic nature of source rocks, and the depths of potential exploration targets, as well as the high degree of exploration, all indicate that future discoveries in this province are likely to be numerous but in small fields.

Distribution and geological sources of selenium in environmental materials in Taoyuan County, Hunan Province, China.

PubMed

Ni, Runxiang; Luo, Kunli; Tian, Xinglei; Yan, Songgui; Zhong, Jitai; Liu, Maoqiu

2016-06-01

The selenium (Se) distribution and geological sources in Taoyuan County, China, were determined by using hydride generation atomic fluorescence spectrometry on rock, soil, and food crop samples collected from various geological regions within the county. The results show Se contents of 0.02-223.85, 0.18-7.05, and 0.006-5.374 mg/kg in the rock, soil, and food crops in Taoyuan County, respectively. The region showing the highest Se content is western Taoyuan County amid the Lower Cambrian and Ediacaran black rock series outcrop, which has banding distributed west to east. A relatively high-Se environment is found in the central and southern areas of Taoyuan County, where Quaternary Limnetic sedimentary facies and Neoproterozoic metamorphic volcanic rocks outcrop, respectively. A relatively low-Se environment includes the central and northern areas of Taoyuan County, where Middle and Upper Cambrian and Ordovician carbonate rocks and Cretaceous sandstones and conglomerates outcrop. These results indicate that Se distribution in Taoyuan County varies markedly and is controlled by the Se content of the bedrock. The Se-enriched Lower Cambrian and Ediacaran black rock series is the primary source of the seleniferous environment observed in Taoyuan County. Potential seleniferous environments are likely to be found near outcrops of the Lower Cambrian and Ediacaran black rock series in southern China.

A four-dimensional petroleum systems model for the San Joaquin Basin Province, California: Chapter 12 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Peters, Kenneth E.; Magoon, Leslie B.; Lampe, Carolyn; Scheirer, Allegra Hosford; Lillis, Paul G.; Gautier, Donald L.

2008-01-01

A calibrated numerical model depicts the geometry and three-dimensional (3-D) evolution of petroleum systems through time (4-D) in a 249 x 309 km (155 x 192 mi) area covering all of the San Joaquin Basin Province of California. Model input includes 3-D structural and stratigraphic data for key horizons and maps of unit thickness, lithology, paleobathymetry, heat flow, original total organic carbon, and original Rock-Eval pyrolysis hydrogen index for each source rock. The four principal petroleum source rocks in the basin are the Miocene Antelope shale of Graham and Williams (1985; hereafter referred to as Antelope shale), the Eocene Kreyenhagen Formation, the Eocene Tumey formation of Atwill (1935; hereafter referred to as Tumey formation), and the Cretaceous to Paleocene Moreno Formation. Due to limited Rock-Eval/total organic carbon data, the Tumey formation was modeled using constant values of original total organic carbon and original hydrogen index. Maps of original total organic carbon and original hydrogen index were created for the other three source rocks. The Antelope shale was modeled using Type IIS kerogen kinetics, whereas Type II kinetics were used for the other source rocks. Four-dimensional modeling and geologic field evidence indicate that maximum burial of the three principal Cenozoic source rocks occurred in latest Pliocene to Holocene time. For example, a 1-D extraction of burial history from the 4-D model in the Tejon depocenter shows that the bottom of the Antelope shale source rock began expulsion (10 percent transformation ratio) about 4.6 Ma and reached peak expulsion (50 percent transformation ratio) about 3.6 Ma. Except on the west flank of the basin, where steep dips in outcrop and seismic data indicate substantial uplift, little or no section has been eroded. Most petroleum migration occurred during late Cenozoic time in distinct stratigraphic intervals along east-west pathways from pods of active petroleum source rock in the Tejon and Buttonwillow depocenters to updip sandstone reservoirs. Satisfactory runs of the model required about 18 hours of computation time for each simulation using parallel processing on a Linux-based cluster.

A molecular and isotopic study of the organic matter from the Paris Basin, France

NASA Technical Reports Server (NTRS)

Lichtfouse, E.; Albrecht, P.; Behar, F.; Hayes, J. M.

1994-01-01

Thirteen Liassic sedimentary rocks of increasing depth and three petroleums from the Paris Basin were studied for 13C/12C isotopic compositions and biological markers, including steranes, sterenes, methylphenanthrenes, methylanthracenes, and triaromatic steroids. The isotopic compositions of n-alkanes from mature sedimentary rocks and petroleums fall in a narrow range (2%), except for the deepest Hettangian rock and the Trias petroleum, for which the short-chain n-alkanes are enriched and depleted in 13C, respectively. Most of the molecular parameters increase over the 2000-2500 m depth range, reflecting the transformation of the organic matter at the onset of petroleum generation. In this zone, carbonate content and carbon isotopic composition of carbonates, as well as molecular parameters, are distinct for the Toarcian and Hettangian source rocks and suggest a migration of organic matter from these two formations. Two novel molecular parameters were defined for this task: one using methyltriaromatic steroids from organic extracts; the other using 1-methylphenanthrene and 2-methylanthracene from kerogen pyrolysates. The anomalous high maturity of the Dogger petroleum relative to the maturity-depth trend of the source rocks is used to estimate the minimal vertical distance of migration of the organic matter from the source rock to the reservoir.

Reconnaissance studies of potential petroleum source rocks in the Middle Jurassic Tuxedni Group near Red Glacier, eastern slope of Iliamna Volcano

USGS Publications Warehouse

Stanley, Richard G.; Herriott, Trystan M.; LePain, David L.; Helmold, Kenneth P.; Peterson, C. Shaun

2013-01-01

Previous geological and organic geochemical studies have concluded that organic-rich marine shale in the Middle Jurassic Tuxedni Group is the principal source rock of oil and associated gas in Cook Inlet (Magoon and Anders, 1992; Magoon, 1994; Lillis and Stanley, 2011; LePain and others, 2012; LePain and others, submitted). During May 2009 helicopter-assisted field studies, 19 samples of dark-colored, fine-grained rocks were collected from exposures of the Red Glacier Formation of the Tuxedni Group near Red Glacier, about 70 km west of Ninilchik on the eastern flank of Iliamna Volcano (figs. 1 and 3). The rock samples were submitted to a commercial laboratory for analysis by Rock-Eval pyrolysis and to the U.S. Geological Survey organic geochemical laboratory in Denver, Colorado, for analysis of vitrinite reflectance. The results show that values of vitrinite reflectance (percent Ro) in our samples average about 2 percent, much higher than the oil window range of 0.6–1.3 percent (Johnsson and others, 1993). The high vitrinite reflectance values indicate that the rock samples experienced significant heating and furthermore suggest that these rocks may have generated oil and gas in the past but no longer have any hydrocarbon source potential. The high thermal maturity of the rock samples may have resulted from (1) the thermaleffects of igneous activity (including intrusion by igneous rocks), (2) deep burial beneath Jurassic, Cretaceous, and Tertiary strata that were subsequently removed by uplift and erosion, or (3) the combined effects of igneous activity and burial.

Hydrogeologic and geospatial data for the assesment of focused recharge to the Carbonate-Rock Aquifer in Genesee County, New York

USGS Publications Warehouse

Reddy, James E.; Kappel, William M.

2010-01-01

Existing hydrogeologic and geospatial data useful for the assessment of focused recharge to the carbonate-rock aquifer in the central part of Genesee County, NY, were compiled from numerous local, State, and Federal agency sources. Data sources utilized in this pilot study include available geospatial datasets from Federal and State agencies, interviews with local highway departments and the Genesee County Soil and Water Conservation District, and an initial assessment of karst features through the analysis of ortho-photographs, with minimal field verification. The compiled information is presented in a series of county-wide and quadrangle maps. The county-wide maps present generalized hydrogeologic conditions including distribution of geologic units, major faults, and karst features, and bedrock-surface and water-table configurations. Ten sets of quadrangle maps of the area that overlies the carbonate-rock aquifer present more detailed and additional information including distribution of bedrock outcrops, thin and (or) permeable soils, and karst features such as sinkholes and swallets. Water-resource managers can utilize the information summarized in this report as a guide to their assessment of focused recharge to, and the potential for surface contaminants to reach the carbonate-rock aquifer.

The influence of geology and land use on arsenic in stream sediments and ground waters in New England, USA

USGS Publications Warehouse

Robinson, G.R.; Ayotte, J.D.

2006-01-01

Population statistics for As concentrations in rocks, sediments and ground water differ by geology and land use features in the New England region, USA. Significant sources of As in the surficial environment include both natural weathering of rocks and anthropogenic sources such as arsenical pesticides that were commonly applied to apple, blueberry and potato crops during the first half of the 20th century in the region. The variation of As in bedrock ground water wells has a strong positive correlation with geologic features at the geologic province, lithology group, and bedrock map unit levels. The variation of As in bedrock ground water wells also has a positive correlation with elevated stream sediment and rock As chemistry. Elevated As concentrations in bedrock wells do not correlate with past agricultural areas that used arsenical pesticides on crops. Stream sediments, which integrate both natural and anthropogenic sources, have a strong positive correlation of As concentrations with rock chemistry, geologic provinces and ground water chemistry, and a weaker positive correlation with past agricultural land use. Although correlation is not sufficient to demonstrate cause-and-effect, the statistics favor rock-based As as the dominant regional source of the element in stream sediments and ground water in New England. The distribution of bedrock geology features at the geologic province, lithology group and map unit level closely correlate with areas of elevated As in ground water, stream sediments, and rocks. ?? 2006 Elsevier Ltd. All rights reserved.

Source-rock geochemistry of the San Joaquin Basin Province, California: Chapter 11 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Peters, Kenneth E.; Magoon, Leslie B.; Valin, Zenon C.; Lillis, Paul G.

2007-01-01

Source-rock thickness and organic richness are important input parameters required for numerical modeling of the geohistory of petroleum systems. Present-day depth and thickness maps for the upper Miocene Monterey Formation, Eocene Tumey formation of Atwill (1935), Eocene Kreyenhagen Formation, and Cretaceous-Paleocene Moreno Formation source rocks in the San Joaquin Basin were determined using formation tops data from 266 wells. Rock-Eval pyrolysis and total organic carbon data (Rock-Eval/TOC) were collected for 1,505 rock samples from these source rocks in 70 wells. Averages of these data for each well penetration were used to construct contour plots of original total organic carbon (TOCo) and original hydrogen index (HIo) in the source rock prior to thermal maturation resulting from burial. Sufficient data were available to construct plots of TOCo and HIo for all source-rock units except the Tumey formation of Atwill (1935). Thick, organic-rich, oil-prone shales of the upper Miocene Monterey Formation occur in the Tejon depocenter in the southern part of the basin with somewhat less favorable occurrence in the Southern Buttonwillow depocenter to the north. Shales of the upper Miocene Monterey Formation generated most of the petroleum in the San Joaquin Basin. Thick, organic-rich, oil-prone Kreyenhagen Formation source rock occurs in the Buttonwillow depocenters, but it is thin or absent in the Tejon depocenter. Moreno Formation source rock is absent from the Tejon and Southern Buttonwillow depocenters, but thick, organic-rich, oil-prone Moreno Formation source rock occurs northwest of the Northern Buttonwillow depocenter adjacent to the southern edge of Coalinga field.

Total petroleum systems of the Bonaparte Gulf Basin area, Australia; Jurassic, Early Cretaceous-Mesozoic; Keyling, Hyland Bay-Permian; Milligans-Carboniferous, Permian

USGS Publications Warehouse

Bishop, M.G.

1999-01-01

The Bonaparte Gulf Basin Province (USGS #3910) of northern Australia contains three important hydrocarbon source-rock intervals. The oldest source-rock interval and associated reservoir rocks is the Milligans-Carboniferous, Permian petroleum system. This petroleum system is located at the southern end of Joseph Bonaparte Gulf and includes both onshore and offshore areas within a northwest to southeast trending Paleozoic rift that was initiated in the Devonian. The Milligans Formation is a Carboniferous marine shale that sources accumulations of both oil and gas in Carboniferous and Permian deltaic, marine shelf carbonate, and shallow to deep marine sandstones. The second petroleum system in the Paleozoic rift is the Keyling, Hyland Bay-Permian. Source rocks include Lower Permian Keyling Formation delta-plain coals and marginal marine shales combined with Upper Permian Hyland Bay Formation prodelta shales. These source-rock intervals provide gas and condensate for fluvial, deltaic, and shallow marine sandstone reservoirs primarily within several members of the Hyland Bay Formation. The Keyling, Hyland Bay-Permian petroleum system is located in the Joseph Bonaparte Gulf, north of the Milligans-Carboniferous, Permian petroleum system, and may extend northwest under the Vulcan graben sub-basin. The third and youngest petroleum system is the Jurassic, Early Cretaceous-Mesozoic system that is located seaward of Joseph Bonaparte Gulf on the Australian continental shelf, and trends southwest-northeast. Source-rock intervals in the Vulcan graben sub-basin include deltaic mudstones of the Middle Jurassic Plover Formation and organic-rich marine shales of the Upper Jurassic Vulcan Formation and Lower Cretaceous Echuca Shoals Formation. These intervals produce gas, oil, and condensate that accumulates in, shallow- to deep-marine sandstone reservoirs of the Challis and Vulcan Formations of Jurassic to Cretaceous age. Organic-rich, marginal marine claystones and coals of the Plover Formation (Lower to Upper Jurassic), combined with marine claystones of the Flamingo Group and Darwin Formation (Upper Jurassic to Lower Cretaceous) comprise the source rocks for the remaining area of the system. These claystones and coals source oil, gas, and condensate accumulations in reservoirs of continental to marine sandstones of the Plover Formation and Flamingo Group. Shales of the regionally distributed Lower Cretaceous Bathurst Island Group and intraformational shales act as seals for hydrocarbons trapped in anticlines and fault blocks, which are the major traps of the province. Production in the Bonaparte Gulf Basin Province began in 1986 using floating production facilities, and had been limited to three offshore fields located in the Vulcan graben sub-basin. Cumulative production from these fields totaled more than 124 million barrels of oil before the facilities were removed after production fell substantially in 1995. Production began in 1998 from three offshore wells in the Zone of Cooperation through floating production facilities. After forty years of exploration, a new infrastructure of pipelines and facilities are planned to tap already discovered offshore reserves and to support additional development.

Mineral and energy resources of the BLM Roswell Resource Area, east-central New Mexico

USGS Publications Warehouse

Bartsch-Winkler, Susan B.

1992-01-01

The sedimentary formations of the Roswell Resource Area have significant mineral and energy resources. Some of the pre-Pennsylvanian sequences in the Northwestern Shelf of the Permian Basin are oil and gas reservoirs, and Pennsylvanian rocks in Tucumcari basin are reservoirs of oil and gas as well as source rocks for oil and gas in Triassic rocks. Pre-Permian rocks also contain minor deposits of uranium and vanadium, limestone, and associated gases. Hydrocarbon reservoirs in Permian rocks include associated gases such as carbon dioxide, helium, and nitrogen. Permian rocks are mineralized adjacent to the Lincoln County porphyry belt, and include deposits of copper, uranium, manganese, iron, polymetallic veins, and Mississippi-valley-type (MVT) lead-zinc. Industrial minerals in Permian rocks include fluorite, barite, potash, halite, polyhalite, gypsum, anhydrite, sulfur, limestone, dolomite, brine deposits (iodine and bromine), aggregate (sand), and dimension stone. Doubly terminated quartz crystals, called "Pecos diamonds" and collected as mineral specimens, occur in Permian rocks along the Pecos River. Mesozoic sedimentary rocks are hosts for copper, uranium, and small quantities of gold-silver-tellurium veins, as well as significant deposits of oil and gas, COa, asphalt, coal, and dimension stone. Mesozoic rocks contain limited amounts of limestone, gypsum, petrified wood, dinosaur remains, and clays. Tertiary rocks host ore deposits commonly associated with intrusive rocks, including platinum group elements, iron skarns, manganese, uranium and vanadium, molybdenum, polymetallic vein deposits, gold-silver- tellurium veins, and thorium-rare earth veins. Museum-quality quartz crystals in Lincoln County were formed in association with intrusive rocks in the Lincoln County porphyry belt. Industrial minerals in Tertiary rocks include fluorite, vein- and bedded-barite, caliche, limestone, and aggregate. Tertiary and Quaternary sediments host important placer deposits of gold and titanium, and minor silver, uranium occurrences, as well as important industrial commodities, including caliche, limestone and dolomite, and aggregate (sand). Quaternary basalt contains sub-ore-grade uranium, scoria, and clay deposits.

Mineral and energy resources of the Roswell Resource Area, East-Central New Mexico

USGS Publications Warehouse

Bartsch-Winkler, Susan B.; Donatich, Alessandro J.

1995-01-01

The sedimentary formations of the Roswell Resource Area have significant mineral and energy resources. Some of the pre-Pennsylvanian sequences in the Northwestern Shelf of the Permian Basin are oil and gas reservoirs, and Pennsylvanian rocks in Tucumcari Basin are reservoirs of oil and gas as well as source rocks for oil and gas in Triassic rocks. Pre-Permian rocks also contain minor deposits of uranium and vanadium, limestone, and gases. Hydrocarbon reservoirs in Permian rocks include associated gases such as carbon dioxide, helium, and nitrogen. Permian rocks are mineralized adjacent to the Lincoln County porphyry belt, and include deposits of copper, uranium, manganese, iron, polymetallic veins, and Mississippi-Valley-type lead-zinc. Industrial minerals in Permian rocks include fluorite, barite, potash, halite, polyhalite, gypsum, anhydrite, sulfur, limestone, dolomite, brine deposits (iodine and bromine), aggregate (sand), and dimension stone. Doubly terminated quartz crystals, called 'Pecos diamonds' and collected as mineral specimens, occur in Permian rocks along the Pecos River. Mesozoic sedimentary rocks are hosts for copper, uranium, and small quantities of gold-silver-tellurium veins, as well as significant deposits of oil and gas, carbon dioxide, asphalt, coal, and dimension stone. Mesozoic rocks contain limited amounts of limestone, gypsum, petrified wood, and clay. Tertiary rocks host ore deposits commonly associated with intrusive rocks, including platinum-group elements, iron skarns, manganese, uranium and vanadium, molybdenum, polymetallic vein deposits, gold-silver-tellurium veins, and thorium-rare-earth veins. Museum-quality quartz crystals are associated with Tertiary intrusive rocks. Industrial minerals in Tertiary rocks include fluorite, vein- and bedded-barite, caliche, limestone, and aggregate. Tertiary and Quaternary sediments host important placer deposits of gold and titanium, and occurrences of silver and uranium. Important industrial commodities include caliche, limestone and dolomite, and aggregate. Quaternary basalt contains sub-ore-grade uranium, scoria, and clay deposits.

Coupled petrological-geodynamical modeling of a compositionally heterogeneous mantle plume

NASA Astrophysics Data System (ADS)

Rummel, Lisa; Kaus, Boris J. P.; White, Richard W.; Mertz, Dieter F.; Yang, Jianfeng; Baumann, Tobias S.

2018-01-01

Self-consistent geodynamic modeling that includes melting is challenging as the chemistry of the source rocks continuously changes as a result of melt extraction. Here, we describe a new method to study the interaction between physical and chemical processes in an uprising heterogeneous mantle plume by combining a geodynamic code with a thermodynamic modeling approach for magma generation and evolution. We pre-computed hundreds of phase diagrams, each of them for a different chemical system. After melt is extracted, the phase diagram with the closest bulk rock chemistry to the depleted source rock is updated locally. The petrological evolution of rocks is tracked via evolving chemical compositions of source rocks and extracted melts using twelve oxide compositional parameters. As a result, a wide variety of newly generated magmatic rocks can in principle be produced from mantle rocks with different degrees of depletion. The results show that a variable geothermal gradient, the amount of extracted melt and plume excess temperature affect the magma production and chemistry by influencing decompression melting and the depletion of rocks. Decompression melting is facilitated by a shallower lithosphere-asthenosphere boundary and an increase in the amount of extracted magma is induced by a lower critical melt fraction for melt extraction and/or higher plume temperatures. Increasing critical melt fractions activates the extraction of melts triggered by decompression at a later stage and slows down the depletion process from the metasomatized mantle. Melt compositional trends are used to determine melting related processes by focusing on K2O/Na2O ratio as indicator for the rock type that has been molten. Thus, a step-like-profile in K2O/Na2O might be explained by a transition between melting metasomatized and pyrolitic mantle components reproducible through numerical modeling of a heterogeneous asthenospheric mantle source. A potential application of the developed method is shown for the West Eifel volcanic field.

40 CFR 436.20 - Applicability; description of the crushed stone subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS MINERAL MINING AND PROCESSING POINT SOURCE CATEGORY Crushed... stone and riprap. This subpart includes all types of rock and stone. Rock and stone that is crushed or broken prior to the extraction of a mineral are elsewhere covered. The processing of calcite, however, in...

40 CFR 436.20 - Applicability; description of the crushed stone subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) MINERAL MINING AND PROCESSING POINT SOURCE CATEGORY... stone and riprap. This subpart includes all types of rock and stone. Rock and stone that is crushed or broken prior to the extraction of a mineral are elsewhere covered. The processing of calcite, however, in...

40 CFR 436.20 - Applicability; description of the crushed stone subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) MINERAL MINING AND PROCESSING POINT SOURCE CATEGORY... stone and riprap. This subpart includes all types of rock and stone. Rock and stone that is crushed or broken prior to the extraction of a mineral are elsewhere covered. The processing of calcite, however, in...

40 CFR 436.20 - Applicability; description of the crushed stone subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS MINERAL MINING AND PROCESSING POINT SOURCE CATEGORY Crushed... stone and riprap. This subpart includes all types of rock and stone. Rock and stone that is crushed or broken prior to the extraction of a mineral are elsewhere covered. The processing of calcite, however, in...

40 CFR 436.20 - Applicability; description of the crushed stone subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) MINERAL MINING AND PROCESSING POINT SOURCE CATEGORY... stone and riprap. This subpart includes all types of rock and stone. Rock and stone that is crushed or broken prior to the extraction of a mineral are elsewhere covered. The processing of calcite, however, in...

The Filmmaker as Humanist: An Interview with Tim Robbins on the Making of "Cradle Will Rock".

ERIC Educational Resources Information Center

Mason, Terrence C.

2000-01-01

Presents an interview with Tim Robbins that focuses on the making of the film "Cradle Will Rock." Robbins offers his perspectives on issues such as the power of art to convey important social messages and sources of violence in schools. Includes resources for teachers. (CMK)

System and method for investigating sub-surface features of a rock formation using compressional acoustic sources

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vu, Cung Khac; Skelt, Christopher; Nihei, Kurt

A system and method for investigating rock formations outside a borehole are provided. The method includes generating a first compressional acoustic wave at a first frequency by a first acoustic source; and generating a second compressional acoustic wave at a second frequency by a second acoustic source. The first and the second acoustic sources are arranged within a localized area of the borehole. The first and the second acoustic waves intersect in an intersection volume outside the borehole. The method further includes receiving a third shear acoustic wave at a third frequency, the third shear acoustic wave returning to themore » borehole due to a non-linear mixing process in a non-linear mixing zone within the intersection volume at a receiver arranged in the borehole. The third frequency is equal to a difference between the first frequency and the second frequency.« less

The information content of high-frequency seismograms and the near-surface geologic structure of "hard rock" recording sites

USGS Publications Warehouse

Cranswick, E.

1988-01-01

Due to hardware developments in the last decade, the high-frequency end of the frequency band of seismic waves analyzed for source mechanisms has been extended into the audio-frequency range (>20 Hz). In principle, the short wavelengths corresponding to these frequencies can provide information about the details of seismic sources, but in fact, much of the "signal" is the site response of the nearsurface. Several examples of waveform data recorded at "hard rock" sites, which are generally assumed to have a "flat" transfer function, are presented to demonstrate the severe signal distortions, including fmax, produced by near-surface structures. Analysis of the geology of a number of sites indicates that the overall attenuation of high-frequency (>1 Hz) seismic waves is controlled by the whole-path-Q between source and receiver but the presence of distinct fmax site resonance peaks is controlled by the nature of the surface layer and the underlying near-surface structure. Models of vertical decoupling of the surface and nearsurface and horizontal decoupling of adjacent sites on hard rock outcrops are proposed and their behaviour is compared to the observations of hard rock site response. The upper bound to the frequency band of the seismic waves that contain significant source information which can be deconvolved from a site response or an array response is discussed in terms of fmax and the correlation of waveform distortion with the outcrop-scale geologic structure of hard rock sites. It is concluded that although the velocity structures of hard rock sites, unlike those of alluvium sites, allow some audio-frequency seismic energy to propagate to the surface, the resulting signals are a highly distorted, limited subset of the source spectra. ?? 1988 Birkha??user Verlag.

High resolution study of petroleum source rock variation, Lower Cretaceous (Hauterivian and Barremian) of Mikkelsen Bay, North Slope, Alaska

USGS Publications Warehouse

Keller, Margaret A.; Macquaker, Joe H.S.; Lillis, Paul G.

2001-01-01

Open File Report 01-480 was designed as a large format poster for the Annual Meeting of the American Association of Petroleum Geologists and the Society for Sedimentary Geology in Denver Colorado in June 2001. It is reproduced here in digital format to make widely available some unique images of mudstones. The images include description, interpretation, and Rock-Eval data that resulted from a high-resolution study of petroleum source rock variation of the Lower Cretaceous succession of the Mobil-Phillips Mikkelsen Bay State #1 well on the North Slope of Alaska. Our mudstone samples with Rock-Eval data plus color images are significant because they come from one of the few continuously cored and complete intervals of the Lower Cretaceous succession on the North Slope. This succession, which is rarely preserved in outcrop and very rarely cored in the subsurface, is considered to include important petroleum source rocks that have not previously been described nor explained Another reason these images are unique is that the lithofacies variability within mudstone dominated successions is relatively poorly known in comparison with that observed in coarser clastic and carbonate successions. They are also among the first published scans of thin sections of mudstone, and are of excellent quality because the sections are well made, cut perpendicular to bedding, and unusually thin, 20 microns. For each of 15 samples, we show a thin section scan (cm scale) and an optical photomicrograph (mm scale) that illustrates the variability present. Several backscattered SEM images are also shown. Rock-Eval data for the samples can be compared with the textures and mineralogy present by correlating sample numbers and core depth.

Oxidation state inherited from the magma source and implications for mineralization: Late Jurassic to Early Cretaceous granitoids, Central Lhasa subterrane, Tibet

NASA Astrophysics Data System (ADS)

Cao, MingJian; Qin, KeZhang; Li, GuangMing; Evans, Noreen J.; McInnes, Brent I. A.; Li, JinXiang; Zhao, JunXing

2018-03-01

Arc magmas are more oxidized than mid-ocean ridge basalts; however, there is continuing debate as to whether this higher oxidation state is inherited from the source magma or developed during late-stage magmatic differentiation processes. Well-constrained Late Jurassic to Early Cretaceous arc-related intermediate to felsic rocks derived from distinct magma sources provide us with a good opportunity to resolve this enigma. A series of granitoids from the western Central Lhasa subterrane were analyzed for whole-rock magnetic susceptibility, Fe2O3/FeO ratios, and trace elements in zircon. Compared to Late Jurassic samples (1.8 ± 2.0 × 10-4 emu g-1 oe-1, Fe3+/Fetotal = 0.32 ± 0.07, zircon Ce4+/Ce3+* = 15.0 ± 13.4), Early Cretaceous rocks show higher whole-rock magnetic susceptibility (5.8 ± 2.5 × 10-4 emu g-1 oe-1), Fe3+/Fetotal ratios (0.43 ± 0.04), and zircon Ce4+/Ce3+* values (23.9 ± 22.3). In addition, positive correlations among whole-rock magnetic susceptibility, Fe3+/Fetotal ratios, and zircon Ce4+/Ce3+* reveal a slight increase in oxidation state from fO2 = QFM to NNO in the Late Jurassic to fO2 = ˜NNO in the Early Cretaceous. Obvious linear correlation between oxidation indices (whole-rock magnetic susceptibility, zircon Ce4+/Ce3+*) and source signatures (zircon ɛHf(t), TDM C ages) indicates that the oxidation state was predominantly inherited from the source with only a minor contribution from magmatic differentiation. Thus, the sources for both the Late Jurassic and Early Cretaceous rocks were probably influenced by mantle wedge-derived magma, contributing to the increased fO2. Compared to ore-forming rocks at giant porphyry Cu deposits, the relatively low oxidation state (QFM to NNO) and negative ɛHf(t) (-16 to 0) of the studied granitoids implies relative infertility. However, this study demonstrates two potential fast and effective indices ( fO2 and ɛHf(t)) to evaluate the fertility of granitoids for porphyry-style mineralization. In an exploration context for the west Central Lhasa subterrane, features indicative of potential fertility might include more oxidized, positive ɛHf(t), young rocks (<130 Ma).

Assessment of Undiscovered Oil and Gas Resources of the Uinta-Piceance Province of Colorado and Utah, 2002

USGS Publications Warehouse

,

2002-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the UintaPiceance Province of northwestern Colorado and northeastern Utah (fig. 1). The assessment of the Uinta-Piceance Province is geology based and uses the Total Petroleum System concept. The geologic elements of Total Petroleum Systems include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy, petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined five Total Petroleum Systems and 20 Assessment Units within these Total Petroleum Systems, and quantitatively estimated the undiscovered oil and gas resources within each Assessment Unit (table 1).

The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam on board Curiosity: Potassic Sedimentary Rocks, Gale Crater

DOE PAGES

Le Deit, L.; Mangold, N.; Forni, O.; ...

2016-05-13

The Mars Science Laboratory rover Curiosity encountered potassium-rich clastic sedimentary rocks at two sites in Gale Crater, the waypoints Cooperstown and Kimberley. These rocks include several distinct meters thick sedimentary outcrops ranging from fine sandstone to conglomerate, interpreted to record an ancient fluvial or fluvio-deltaic depositional system. Furthermore, from ChemCam Laser-Induced Breakdown Spectroscopy (LIBS) chemical analyses, this suite of sedimentary rocks has an overall mean K 2O abundance that is more than 5 times higher than that of the average Martian crust. The combined analysis of ChemCam data with stratigraphic and geographic locations then reveals that the mean K 2Omore » abundance increases upward through the stratigraphic section. Chemical analyses across each unit can be represented as mixtures of several distinct chemical components, i.e., mineral phases, including K-bearing minerals, mafic silicates, Fe-oxides, and Fe-hydroxide/oxyhydroxides. Possible K-bearing minerals include alkali feldspar (including anorthoclase and sanidine) and K-bearing phyllosilicate such as illite. Mixtures of different source rocks, including a potassium-rich rock located on the rim and walls of Gale Crater, are the likely origin of observed chemical variations within each unit. Physical sorting may have also played a role in the enrichment in K in the Kimberley formation. The occurrence of these potassic sedimentary rocks provides additional evidence for the chemical diversity of the crust exposed at Gale Crater.« less

The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam on board Curiosity: Potassic Sedimentary Rocks, Gale Crater

DOE Office of Scientific and Technical Information (OSTI.GOV)

Le Deit, L.; Mangold, N.; Forni, O.

The Mars Science Laboratory rover Curiosity encountered potassium-rich clastic sedimentary rocks at two sites in Gale Crater, the waypoints Cooperstown and Kimberley. These rocks include several distinct meters thick sedimentary outcrops ranging from fine sandstone to conglomerate, interpreted to record an ancient fluvial or fluvio-deltaic depositional system. Furthermore, from ChemCam Laser-Induced Breakdown Spectroscopy (LIBS) chemical analyses, this suite of sedimentary rocks has an overall mean K 2O abundance that is more than 5 times higher than that of the average Martian crust. The combined analysis of ChemCam data with stratigraphic and geographic locations then reveals that the mean K 2Omore » abundance increases upward through the stratigraphic section. Chemical analyses across each unit can be represented as mixtures of several distinct chemical components, i.e., mineral phases, including K-bearing minerals, mafic silicates, Fe-oxides, and Fe-hydroxide/oxyhydroxides. Possible K-bearing minerals include alkali feldspar (including anorthoclase and sanidine) and K-bearing phyllosilicate such as illite. Mixtures of different source rocks, including a potassium-rich rock located on the rim and walls of Gale Crater, are the likely origin of observed chemical variations within each unit. Physical sorting may have also played a role in the enrichment in K in the Kimberley formation. The occurrence of these potassic sedimentary rocks provides additional evidence for the chemical diversity of the crust exposed at Gale Crater.« less

The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam Onboard Curiosity

USGS Publications Warehouse

Le Deit, Laetitia; Mangold, Nicolas; Forni, Olivier; Cousin, Agnes; Lasue, Jeremie; Schröder, Susanne; Wiens, Roger C.; Sumner, Dawn Y.; Fabre, Cecile; Stack, Katherine M.; Anderson, Ryan; Blaney, Diana L.; Clegg, Samuel M.; Dromart, Gilles; Fisk, Martin; Gasnault, Olivier; Grotzinger, John P.; Gupta, Sanjeev; Lanza, Nina; Le Mouélic, Stephane; Maurice, Sylvestre; McLennan, Scott M.; Meslin, Pierre-Yves; Nachon, Marion; Newsom, Horton E.; Payre, Valerie; Rapin, William; Rice, Melissa; Sautter, Violaine; Treiman, Alan H.

2016-01-01

The Mars Science Laboratory rover Curiosity encountered potassium-rich clastic sedimentary rocks at two sites in Gale Crater, the waypoints Cooperstown and Kimberley. These rocks include several distinct meters thick sedimentary outcrops ranging from fine sandstone to conglomerate, interpreted to record an ancient fluvial or fluvio-deltaic depositional system. From ChemCam Laser-Induced Breakdown Spectroscopy (LIBS) chemical analyses, this suite of sedimentary rocks has an overall mean K2O abundance that is more than 5 times higher than that of the average Martian crust. The combined analysis of ChemCam data with stratigraphic and geographic locations reveals that the mean K2O abundance increases upward through the stratigraphic section. Chemical analyses across each unit can be represented as mixtures of several distinct chemical components, i.e., mineral phases, including K-bearing minerals, mafic silicates, Fe-oxides, and Fe-hydroxide/oxyhydroxides. Possible K-bearing minerals include alkali feldspar (including anorthoclase and sanidine) and K-bearing phyllosilicate such as illite. Mixtures of different source rocks, including a potassium-rich rock located on the rim and walls of Gale Crater, are the likely origin of observed chemical variations within each unit. Physical sorting may have also played a role in the enrichment in K in the Kimberley formation. The occurrence of these potassic sedimentary rocks provides additional evidence for the chemical diversity of the crust exposed at Gale Crater.

Hydrocarbon potential evaluation of the source rocks from the Abu Gabra Formation in the Sufyan Sag, Muglad Basin, Sudan

NASA Astrophysics Data System (ADS)

Qiao, Jinqi; Liu, Luofu; An, Fuli; Xiao, Fei; Wang, Ying; Wu, Kangjun; Zhao, Yuanyuan

2016-06-01

The Sufyan Sag is one of the low-exploration areas in the Muglad Basin (Sudan), and hydrocarbon potential evaluation of source rocks is the basis for its further exploration. The Abu Gabra Formation consisting of three members (AG3, AG2 and AG1 from bottom to top) was thought to be the main source rock formation, but detailed studies on its petroleum geology and geochemical characteristics are still insufficient. Through systematic analysis on distribution, organic matter abundance, organic matter type, organic matter maturity and characteristics of hydrocarbon generation and expulsion of the source rocks from the Abu Gabra Formation, the main source rock members were determined and the petroleum resource extent was estimated in the study area. The results show that dark mudstones are the thickest in the AG2 member while the thinnest in the AG1 member, and the thickness of the AG3 dark mudstone is not small either. The AG3 member have developed good-excellent source rock mainly with Type I kerogen. In the Southern Sub-sag, the AG3 source rock began to generate hydrocarbons in the middle period of Bentiu. In the early period of Darfur, it reached the hydrocarbon generation and expulsion peak. It is in late mature stage currently. The AG2 member developed good-excellent source rock mainly with Types II1 and I kerogen, and has lower organic matter abundance than the AG3 member. In the Southern Sub-sag, the AG2 source rock began to generate hydrocarbons in the late period of Bentiu. In the late period of Darfur, it reached the peak of hydrocarbon generation and its expulsion. It is in middle mature stage currently. The AG1 member developed fair-good source rock mainly with Types II and III kerogen. Throughout the geological evolution history, the AG1 source rock has no effective hydrocarbon generation or expulsion processes. Combined with basin modeling results, we have concluded that the AG3 and AG2 members are the main source rock layers and the Southern Sub-sag is the main source kitchen in the study area. The AG3 and AG2 source rocks have supplied 58.1% and 41.9% of the total hydrocarbon generation, respectively, and 54.9% and 45.1% of the total hydrocarbon expulsion, respectively. Their hydrocarbon expulsion efficiency ratios are 71.0% and 62.3%, respectively. The Southern Sub-sag has supplied more than 90% of the total amounts of hydrocarbon generation and its expulsion.

MX Siting Investigation. Geotechnical Evaluation. Detailed Aggregate Resources Study. Pahroc Study Area, Nevada.

DTIC Science & Technology

1981-06-05

source is a fairly limited outcrop of calcareous sandstone classified as dolomite rock (Do). Class RBIb Sources: Pour basin-fill sources within the study...Paleozoic rocks consist of limestone, dolomite , and quartzite with interbedded sandstone and shale. These units are generally exposed along the northern...categories simplify discussion and presentation without altering the conclusions of the study. 2.2.1 Rock Units Dolomite rocks (Do) and carbonate rocks

The geochemistry of primitive volcanic rocks of the Ankaratra volcanic complex, and source enrichment processes in the genesis of the Cenozoic magmatism in Madagascar

NASA Astrophysics Data System (ADS)

Melluso, L.; Cucciniello, C.; le Roex, A. P.; Morra, V.

2016-07-01

The Ankaratra volcanic complex in central Madagascar consists of lava flows, domes, scoria cones, tuff rings and maars of Cenozoic age that are scattered over 3800 km2. The mafic rocks include olivine-leucite-nephelinites, basanites, alkali basalts and hawaiites, and tholeiitic basalts. Primitive samples have high Mg# (>60), high Cr and Ni concentrations; their mantle-normalized patterns peak at Nb and Ba, have troughs at K, and smoothly decrease towards the least incompatible elements. The Ankaratra mafic rocks show small variation in Sr-Nd-Pb isotopic compositions (e.g., 87Sr/86Sr = 0.70377-0.70446, 143Nd/144Nd = 0.51273-0.51280, 206Pb/204Pb = 18.25-18.87). These isotopic values differ markedly from those of Cenozoic mafic lavas of northern Madagascar and the Comoro archipelago, typical Indian Ocean MORB and oceanic basalt end-members. The patterns of olivine nephelinitic magmas can be obtained through 3-10% partial melting of a mantle source that was enriched by a Ca-rich alkaline melt, and that contained garnet, carbonates and phlogopite. The patterns of tholeiitic basalts can be obtained after 10-12% partial melting of a source enriched with lower amounts of the same alkaline melt, in the spinel- (and possibly amphibole-) facies mantle, hence in volumes where carbonate is not a factor. The significant isotopic change from the northernmost volcanic rocks of Madagascar and those in the central part of the island implicates a distinct source heterogeneity, and ultimately assess the role of the continental lithospheric mantle as source region. The source of at least some volcanic rocks of the still active Comoro archipelago may have suffered the same time-integrated geochemical and isotopic evolution as that of the northern Madagascar volcanic rocks.

Alaskan North Slope petroleum systems

USGS Publications Warehouse

Magoon, L.B.; Lillis, P.G.; Bird, K.J.; Lampe, C.; Peters, K.E.

2003-01-01

Six North Slope petroleum systems are identified, described, and mapped using oil-to-oil and oil-to-source rock correlations, pods of active source rock, and overburden rock packages. To map these systems, we assumed that: a) petroleum source rocks contain 3.2 wt. % organic carbon (TOC); b) immature oil-prone source rocks have hydrogen indices (HI) >300 (mg HC/gm TOC); c) the top and bottom of the petroleum (oil plus gas) window occur at vitrinite reflectance values of 0.6 and 1.0% Ro, respectively; and d) most hydrocarbons are expelled within the petroleum window. The six petroleum systems we have identified and mapped are: a) a southern system involving the Kuna-Lisburne source rock unit that was active during the Late Jurassic and Early Cretaceous; b) two western systems involving source rock in the Kingak-Blankenship, and GRZ-lower Torok source rock units that were active during the Albian; and c) three eastern systems involving the Shublik-Otuk, Hue Shale and Canning source rock units that were active during the Cenozoic. The GRZ-lower Torok in the west is correlative with the Hue Shale to the east. Four overburden rock packages controlled the time of expulsion and gross geometry of migration paths: a) a southern package of Early Cretaceous and older rocks structurally-thickened by early Brooks Range thrusting; b) a western package of Early Cretaceous rocks that filled the western part of the foreland basin; c) an eastern package of Late Cretaceous and Paleogene rocks that filled the eastern part of the foreland basin; and d) an offshore deltaic package of Neogene rocks deposited by the Colville, Canning, and Mackenzie rivers. This petroleum system poster is part of a series of Northern Alaska posters on modeling. The poster in this session by Saltus and Bird present gridded maps for the greater Northern Alaskan onshore and offshore that are used in the 3D modeling poster by Lampe and others. Posters on source rock units are by Keller and Bird as well as Peters and others. Sandstone and shale compaction properties used in sedimentary basin modeling are covered in a poster by Rowan and others. The results of this modeling exercise will be used in our next Northern Alaska oil and gas resource assessment.

Radiogenic heat production in sedimentary rocks of the Gulf of Mexico Basin, south Texas

USGS Publications Warehouse

McKenna, T.E.; Sharp, J.M.

1998-01-01

Radiogenic heat production within the sedimentary section of the Gulf of Mexico basin is a significant source of heat. Radiogenic heat should be included in thermal models of this basin (and perhaps other sedimentary basins). We calculate that radiogenic heat may contribute up to 26% of the overall surface heat-flow density for an area in south Texas. Based on measurements of the radioactive decay rate of ??-particles, potassium concentration, and bulk density, we calculate radiogenic heat production for Stuart City (Lower Cretaceous) limestones, Wilcox (Eocene) sandstones and mudrocks, and Frio (Oligocene) sandstones and mudrocks from south Texas. Heat production rates range from a low of 0.07 ?? 0.01 ??W/m3 in clean Stuart City limestones to 2.21 ?? 0.24??W/m3 in Frio mudrocks. Mean heat production rates for Wilcox sandstones, Frio sandstones, Wilcox mudrocks, and Frio mudrocks are 0.88, 1.19, 1.50, and 1.72 ??W/m3, respectively. In general, the mudrocks produce about 30-40% more heat than stratigraphically equivalent sandstones. Frio rocks produce about 15% more heat than Wilcox rocks per unit volume of clastic rock (sandstone/mudrock). A one-dimensional heat-conduction model indicates that this radiogenic heat source has a significant effect on subsurface temperatures. If a thermal model were calibrated to observed temperatures by optimizing basal heat-flow density and ignoring sediment heat production, the extrapolated present-day temperature of a deeply buried source rock would be overestimated.Radiogenic heat production within the sedimentary section of the Gulf of Mexico basin is a significant source of heat. Radiogenic heat should be included in thermal models of this basin (and perhaps other sedimentary basins). We calculate that radiogenic heat may contribute up to 26% of the overall surface heat-flow density for an area in south Texas. Based on measurements of the radioactive decay rate of ??-particles, potassium concentration, and bulk density, we calculate radiogenic heat production for Stuart City (Lower Cretaceous) limestones, Wilcox (Eocene) sandstones and mudrocks, and Frio (Oligocene) sandstones and mudrocks from south Texas. Heat production rates range from a low of 0.07??0.01 ??W/m3 in clean Stuart City limestones to 2.21??0.24 ??W/m3 in Frio mudrocks. Mean heat production rates for Wilcox sandstones, Frio sandstones, Wilcox mudrocks, and Frio mudrocks are 0.88, 1.19, 1.50, and 1.72 ??W/m3, respectively. In general, the mudrocks produce about 30-40% more heat than stratigraphically equivalent sandstones. Frio rocks produce about 15% more heat than Wilcox rocks per unit volume of clastic rock (sandstone/mudrock). A one-dimensional heat-conduction model indicates that this radiogenic heat source has a significant effect on subsurface temperatures. If a thermal model were calibrated to observed temperatures by optimizing basal heat-flow density and ignoring sediment heat production, the extrapolated present-day temperature of a deeply buried source rock would be overestimated.

Sm-Nd and Rb-Sr isotopic systematics of the Pea Ridge Fe-P deposit and related rocks, southeast Missouri

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marikos, M.A.; Barton, M.D.

1993-03-01

Pea ridge is a discordant Middle Proterozoic Fe-P deposit hosted in rhyolite tuffs and flows of the 1.4--1.5 Ga St. Francois terrane. Host rocks and the deposit are cut by basalt and aplite/pegmatite dikes. The deposit overlies a blind pluton which is partially surrounded by a trachytic ring complex. In the deposit, which is mined for Fe, early Qtz+Amph+Mag+Ap rock is cut by Mag+Ap+Qtz rock. Subsequently, portions of the deposit and host rocks were brecciated, oxidized and silicified to produce a complex suite of rocks enriched in Hem+Qtz+Ksp+Mu. Late breccia pipes/dikes cut the complex and were mineralized with Bar+Ksp+Flu+Chl+Cc+REE-phosphates. Sm/Ndmore » and Rb/Sr isotopic systematics have been studied to: (1) constrain source(s) of igneous rocks and deposit components, (2) refine ages of magmatism, mineralization, and later hydrothermal activity, (3) begin regional comparison of isotopic systematics in SE Missouri Fe deposits, and (4) complement ongoing Missouri DGLS/USGS studies. Fourteen combined Sm-Nd and Rb-Sr analyses were done on materials including two host rhyolites, two nearby trachytes, two gneiss samples representing plausible basement, two intramineral dikes, and six samples of mineralization.« less

1-D/3-D geologic model of the Western Canada Sedimentary Basin

USGS Publications Warehouse

Higley, D.K.; Henry, M.; Roberts, L.N.R.; Steinshouer, D.W.

2005-01-01

The 3-D geologic model of the Western Canada Sedimentary Basin comprises 18 stacked intervals from the base of the Devonian Woodbend Group and age equivalent formations to ground surface; it includes an estimated thickness of eroded sediments based on 1-D burial history reconstructions for 33 wells across the study area. Each interval for the construction of the 3-D model was chosen on the basis of whether it is primarily composed of petroleum system elements of reservoir, hydrocarbon source, seal, overburden, or underburden strata, as well as the quality and areal distribution of well and other data. Preliminary results of the modeling support the following interpretations. Long-distance migration of hydrocarbons east of the Rocky Mountains is indicated by oil and gas accumulations in areas within which source rocks are thermally immature for oil and (or) gas. Petroleum systems in the basin are segmented by the northeast-trending Sweetgrass Arch; hydrocarbons west of the arch were from source rocks lying near or beneath the Rocky Mountains, whereas oil and gas east of the arch were sourced from the Williston Basin. Hydrocarbon generation and migration are primarily due to increased burial associated with the Laramide Orogeny. Hydrocarbon sources and migration were also influenced by the Lower Cretaceous sub-Mannville unconformity. In the Peace River Arch area of northern Alberta, Jurassic and older formations exhibit high-angle truncations against the unconformity. Potential Paleozoic though Mesozoic hydrocarbon source rocks are in contact with overlying Mannville Group reservoir facies. In contrast, in Saskatchewan and southern Alberta the contacts are parallel to sub-parallel, with the result that hydrocarbon source rocks are separated from the Mannville Group by seal-forming strata within the Jurassic. Vertical and lateral movement of hydrocarbons along the faults in the Rocky Mountains deformed belt probably also resulted in mixing of oil and gas from numerous source rocks in Alberta.

Geochemistry of Eagle Ford group source rocks and oils from the first shot field area, Texas

USGS Publications Warehouse

Edman, Janell D.; Pitman, Janet K.; Hammes, Ursula

2010-01-01

Total organic carbon, Rock-Eval pyrolysis, and vitrinite reflectance analyses performed on Eagle Ford Group core and cuttings samples from the First Shot field area, Texas demonstrate these samples have sufficient quantity, quality, and maturity of organic matter to have generated oil. Furthermore, gas chromatography and biomarker analyses performed on Eagle Ford Group oils and source rock extracts as well as weight percent sulfur analyses on the oils indicate the source rock facies for most of the oils are fairly similar. Specifically, these source rock facies vary in lithology from shales to marls, contain elevated levels of sulfur, and were deposited in a marine environment under anoxic conditions. It is these First Shot Eagle Ford source facies that have generated the oils in the First Shot Field. However, in contrast to the generally similar source rock facies and organic matter, maturity varies from early oil window to late oil window in the study area, and these maturity variations have a pronounced effect on both the source rock and oil characteristics. Finally, most of the oils appear to have been generated locally and have not experienced long distance migration. 

Oil-source correlations between the Mississippian Heath Shales and the reservoired oils in the Pennsylvanian Tyler Sands, Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cole, G.A.; Drozd, R.J.; Daniel, J.A.

The Mississippi Heath Formation exposed in Fergus County, central Montana, is comprised predominantly of nearshore, marine, black, calcareous shales and carbonates with minor anhydrite and coal beds. The black shales and limestones have been considered as sources for shale oil via Fischer Assay and pyrolysis analysis. These shales are potential source units for the oils reservoired in the overlying Pennsylvanian Tyler Formation sands located 50 mi (80 km) to the east of the Fergus County Heath sediment studied. Heath Formation rocks from core holes were selectively sampled in 2-ft increments and analyzed for their source rock characteristics. Analyses include percentmore » total organic carbon (%TOC), Rock-Eval pyrolysis, pyrolysis-gas chromatography, and characterization of the total soluble extracts using carbon isotopes and gas chromatography-mass Spectrometry. Results indicated that the Heath was an excellent potential source unit that contained oil-prone, organic-rich (maximum of 17.6% TOC), calcareous, black shale intervals. The Heath and Tyler formations also contained intervals dominated by gas-prone, organic-rich shales of terrestrial origin. Three oils from the Tyler Formation sands in Musselshell and Rosebud counties were characterized by similar methods as the extracts. The oils were normally mature, moderate API gravity, moderate sulfur, low asphaltene crudes. Oil to source correlations between the Heath shale extracts and the oils indicated the Heath was an excellent candidate source rock for the Tyler reservoired oils. Conclusions were based on excellent matches between the carbon isotopes of the oils and the kerogen-kerogen pyrolyzates, and from the biomarkers.« less

Evolving Mantle Sources in Postcollisional Early Permian-Triassic Magmatic Rocks in the Heart of Tianshan Orogen (Western China)

NASA Astrophysics Data System (ADS)

Tang, Gong-Jian; Cawood, Peter A.; Wyman, Derek A.; Wang, Qiang; Zhao, Zhen-Hua

2017-11-01

Magmatism postdating the initiation of continental collision provides insight into the late stage evolution of orogenic belts including the composition of the contemporaneous underlying subcontinental mantle. The Awulale Mountains, in the heart of the Tianshan Orogen, display three types of postcollisional mafic magmatic rocks. (1) A medium to high K calc-alkaline mafic volcanic suite (˜280 Ma), which display low La/Yb ratios (2.2-11.8) and a wide range of ɛNd(t) values from +1.9 to +7.4. This suite of rocks was derived from melting of depleted metasomatized asthenospheric mantle followed by upper crustal contamination. (2) Mafic shoshonitic basalts (˜272 Ma), characterized by high La/Yb ratios (14.4-20.5) and more enriched isotope compositions (ɛNd(t) = +0.2 - +0.8). These rocks are considered to have been generated by melting of lithospheric mantle enriched by melts from the Tarim continental crust that was subducted beneath the Tianshan during final collisional suturing. (3) Mafic dikes (˜240 Ma), with geochemical and isotope compositions similiar to the ˜280 Ma basaltic rocks. This succession of postcollision mafic rock types suggests there were two stages of magma generation involving the sampling of different mantle sources. The first stage, which occurred in the early Permian, involved a shift from depleted asthenospheric sources to enriched lithospheric mantle. It was most likely triggered by the subduction of Tarim continental crust and thickening of the Tianshan lithospheric mantle. During the second stage, in the middle Triassic, there was a reversion to more asthenospheric sources, related to postcollision lithospheric thinning.

SUMMARY REVIEW OF HEALTH EFFECTS ASSOCIATED WITH HYDROGEN FLUORIDE AND RELATED COMPOUNDS: HEALTH ISSUE ASSESSMENT

EPA Science Inventory

The major natural sources of airborne hydrogen fluoride (HF) are volcanic activity, ocean spray, and crustal weathering of fluoride-containing rocks. Anthropogenic sources include emissions from industrial operations such as aluminum and fluorocarbon production, and uranium proce...

Hydrocarbon source rock potential of the Karoo in Zimbabwe

NASA Astrophysics Data System (ADS)

Hiller, K.; Shoko, U.

1996-07-01

The hydrocarbon potential of Zimbabwe is tied to the Karoo rifts which fringe the Zimbabwe Craton, i.e. the Mid-Zambezi basin/rift and the Mana Pools basin in the northwest, the Cabora Bassa basin in the north and the Tuli-Bubye and Sabi-Runde basins in the south. Based on the geochemical investigation of almost one thousand samples of fine clastic Karoo sediments, a concise source rock inventory has been established showing the following features. No marine source rocks have been identified. In the Mid-Zambezi area and Cabora Bassa basin, the source rocks are gas-prone, carbonaceous to coaly mudstones and coal of Lower Karoo age. In the Cabora Bassa basin, similar gas-prone source rocks occur in the Upper Karoo (Angwa Alternations Member). These kerogen type III source rocks are widespread and predominantly immature to moderately mature. In the southern basins, the Lower Karoo source rocks are gas-prone; in addition some have a small condensate potential. Most of the samples are, however, overmature due to numerous dolerite intrusions. Samples with a mixed gas, condensate and oil potential (mainly kerogen types II and III) were identified in the Lower Karoo (Coal Measure and Lower Madumabisa Mudstone Formations) of the Mid-Zambezi basin, and in the Louver Karoo (Mkanga Formation) and Upper Karoo (Upper Angwa Alternations Member Formation) of the Cabora Bassa basin. The source rocks, with a liquid potential, are also immature to moderately mature and were deposited in swamp, paludal and lacustrine environments of limited extent.

Source rock potential in Pakistan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raza, H.A.

1991-03-01

Pakistan contains two sedimentary basins: Indus in the east and Balochistan in the west. The Indus basin has received sediments from precambrian until Recent, albeit with breaks. It has been producing hydrocarbons since 1914 from three main producing regions, namely, the Potwar, Sulaisman, and Kirthar. In the Potwar, oil has been discovered in Cambrian, Permian, Jurassic, and Tertiary rocks. Potential source rocks are identified in Infra-Cambrian, Permian, Paleocene, and Eocene successions, but Paleocene/Eocene Patala Formation seems to be the main source of most of the oil. In the Sulaiman, gas has been found in Cretaceous and Tertiary; condensate in Cretaceousmore » rocks. Potential source rocks are indicated in Cretaceous, Paleocene, and Eocene successions. The Sembar Formation of Early Cretaceous age appears to be the source of gas. In the Kirthar, oil and gas have been discovered in Cretaceous and gas has been discovered in paleocene and Eocene rocks. Potential source rocks are identified in Kirthar and Ghazij formations of Eocene age in the western part. However, in the easter oil- and gas-producing Badin platform area, Union Texas has recognized the Sembar Formation of Early Cretaceous age as the only source of Cretaceous oil and gas. The Balochistan basin is part of an Early Tertiary arc-trench system. The basin is inadequately explored, and there is no oil or gas discovery so far. However, potential source rocks have been identified in Eocene, Oligocene, Miocene, and Pliocene successions based on geochemical analysis of surface samples. Mud volcanoes are present.« less

Mesozoic non-marine petroleum source rocks determined by palynomorphs in the Tarim Basin, Xinjiang, northwestern China

USGS Publications Warehouse

Jiang, D.-X.; Wang, Y.-D.; Robbins, E.I.; Wei, J.; Tian, N.

2008-01-01

The Tarim Basin in Northwest China hosts petroleum reservoirs of Cambrian, Ordovician, Carboniferous, Triassic, Jurassic, Cretaceous and Tertiary ages. The sedimentary thickness in the basin reaches about 15 km and with an area of 560000 km2, the basin is expected to contain giant oil and gas fields. It is therefore important to determine the ages and depositional environments of the petroleum source rocks. For prospective evaluation and exploration of petroleum, palynological investigations were carried out on 38 crude oil samples collected from 22 petroleum reservoirs in the Tarim Basin and on additionally 56 potential source rock samples from the same basin. In total, 173 species of spores and pollen referred to 80 genera, and 27 species of algae and fungi referred to 16 genera were identified from the non-marine Mesozoic sources. By correlating the palynormorph assemblages in the crude oil samples with those in the potential source rocks, the Triassic and Jurassic petroleum source rocks were identified. Furthermore, the palynofloras in the petroleum provide evidence for interpretation of the depositional environments of the petroleum source rocks. The affinity of the miospores indicates that the petroleum source rocks were formed in swamps in brackish to lacustrine depositional environments under warm and humid climatic conditions. The palynomorphs in the crude oils provide further information about passage and route of petroleum migration, which is significant for interpreting petroleum migration mechanisms. Additionally, the thermal alternation index (TAI) based on miospores indicates that the Triassic and Jurassic deposits in the Tarim Basin are mature petroleum source rocks. ?? Cambridge University Press 2008.

Integrated exploration workflow in the south Middle Magdalena Valley (Colombia)

NASA Astrophysics Data System (ADS)

Moretti, Isabelle; Charry, German Rodriguez; Morales, Marcela Mayorga; Mondragon, Juan Carlos

2010-03-01

The HC exploration is presently active in the southern part of the Middle Magdalena Valley but only moderate size discoveries have been made up to date. The majority of these discoveries are at shallow depth in the Tertiary section. The structures located in the Valley are faulted anticlines charged by lateral migration from the Cretaceous source rocks that are assumed to be present and mature eastward below the main thrusts and the Guaduas Syncline. Upper Cretaceous reservoirs have also been positively tested. To reduce the risks linked to the exploration of deeper structures below the western thrusts of the Eastern Cordillera, an integrated study was carried out. It includes the acquisition of new seismic data, the integration of all surface and subsurface data within a 3D-geomodel, a quality control of the structural model by restoration and a modeling of the petroleum system (presence and maturity of the Cretaceous source rocks, potential migration pathways). The various steps of this workflow will be presented as well as the main conclusions in term of source rock, deformation phases and timing of the thrust emplacement versus oil maturation and migration. Our data suggest (or confirm) The good potential of the Umir Fm as a source rock. The early (Paleogene) deformation of the Bituima Trigo fault area. The maturity gap within the Cretaceous source rock between the hangingwall and footwall of the Bituima fault that proves an initial offset of Cretaceous burial in the range of 4.5 km between the Upper Cretaceous series westward and the Lower Cretaceous ones eastward of this fault zone. The post Miocene weak reactivation as dextral strike slip of Cretaceous faults such as the San Juan de Rio Seco fault that corresponds to change in the Cretaceous thickness and therefore in the depth of the thrust decollement.

Petrogenesis and tectonics of the Acasta Gneiss Complex derived from integrated petrology and 142Nd and 182W extinct nuclide-geochemistry

NASA Astrophysics Data System (ADS)

Reimink, Jesse R.; Chacko, Thomas; Carlson, Richard W.; Shirey, Steven B.; Liu, Jingao; Stern, Richard A.; Bauer, Ann M.; Pearson, D. Graham; Heaman, Larry M.

2018-07-01

The timing and mechanisms of continental crust formation represent major outstanding questions in the Earth sciences. Extinct-nuclide radioactive systems offer the potential to evaluate the temporal relations of a variety of differentiation processes on the early Earth, including crust formation. Here, we investigate the whole-rock 182W/184W and 142Nd/144Nd ratios and zircon Δ17O values of a suite of well-studied and lithologically-homogeneous meta-igneous rocks from the Acasta Gneiss Complex, Northwest Territories, Canada, including the oldest-known zircon-bearing rocks on Earth. In the context of previously published geochemical data and petrogenetic models, the new 142Nd/144Nd data indicate that formation of the Hadean-Eoarchean Acasta crust was ultimately derived from variable sources, both in age and composition. Although 4.02 Ga crust was extracted from a nearly bulk-Earth source, heterogeneous μ142Nd signatures indicate that Eoarchean rocks of the Acasta Gneiss Complex were formed by partial melting of hydrated, Hadean-age mafic crust at depths shallower than the garnet stability field. By ∼3.6 Ga, granodioritic-granitic rocks were formed by partial melting of Archean hydrated mafic crust that was melted at greater depth, well into the garnet stability field. Our 182W results indicate that the sources to the Acasta Gneiss Complex had homogeneous, high-μ182W on the order of +10 ppm-a signature ubiquitous in other Eoarchean terranes. No significant deviation from the terrestrial mass fractionation line was found in the triple oxygen isotope (16O-17O-18O) compositions of Acasta zircons, confirming homogeneous oxygen isotope compositions in Earth's mantle by 4.02 Ga.

Anisotropy of magnetic susceptibility of silicic rocks from quarries in the vicinity of São Marcos, Rio Grande do Sul, South Brazil: Implications for emplacement mechanisms

NASA Astrophysics Data System (ADS)

Cañón-Tapia, Edgardo; Raposo, M. Irene B.

2018-04-01

The Paraná-Etendeka Large Igneous Province includes acid volcanic rocks that can be found throughout its extension. Several aspects concerning those rocks remain controversial, including their mechanism of emplacement and location of their eruptive sources. Opening of several quarries of dimension stone near the city of Sao Marcos, Rio Grande do Sul, Brazil, offers a unique opportunity to study in detail the acid products. Here, we present the results of a study of the anisotropy of magnetic susceptibility (AMS) completed in some rocks that had been interpreted as the roots of volcanic conduits. Our results, and reexamination of the textural features of the rocks, lead to a reinterpretation that suggests that these rocks were emplaced subaerially, and involved assimilation and remelting of clastic components of previous products. Due to the inferred conditions of emplacement, it is unlikely that the eruptive vents are located far from the area of study, therefore ruling out the long-travelled nature of these products.

Geochemistry and geodynamics of the Mawat mafic complex in the Zagros Suture zone, northeast Iraq

NASA Astrophysics Data System (ADS)

Azizi, Hossein; Hadi, Ayten; Asahara, Yoshihiro; Mohammad, Youssef Osman

2013-12-01

The Iraqi Zagros Orogenic Belt includes two separate ophiolite belts, which extend along a northwest-southeast trend near the Iranian border. The outer belt shows ophiolite sequences and originated in the oceanic ridge or supra-subduction zone. The inner belt includes the Mawat complex, which is parallel to the outer belt and is separated by the Biston Avoraman block. The Mawat complex with zoning structures includes sedimentary rocks with mafic interbedded lava and tuff, and thick mafic and ultramafic rocks. This complex does not show a typical ophiolite sequences such as those in Penjween and Bulfat. The Mawat complex shows evidence of dynamic deformation during the Late Cretaceous. Geochemical data suggest that basic rocks have high MgO and are significantly depleted in LREE relative to HREE. In addition they show positive ɛ Nd values (+5 to+8) and low 87Sr/86Sr ratios. The occurrence of some OIB type rocks, high Mg basaltic rocks and some intermediate compositions between these two indicate the evolution of the Mawat complex from primary and depleted source mantle. The absence of a typical ophiolite sequence and the presence of good compatibility of the source magma with magma extracted from the mantle plume suggests that a mantle plume from the D″ layer is more consistent as the source of this complex than the oceanic ridge or supra-subduction zone settings. Based on our proposed model the Mawat basin represents an extensional basin formed during the Late Paleozoic to younger along the Arabian passive margin oriented parallel to the Neo-Tethys oceanic ridge or spreading center. The Mawat extensional basin formed without creation of new oceanic basement. During the extension, huge volumes of mafic lava were intruded into this basin. This basin was squeezed between the Arabian Plate and Biston Avoraman block during the Late Cretaceous.

Relationship of oil seep in Kudat Peninsula with surrounding rocks based on geochemical analysis

NASA Astrophysics Data System (ADS)

Izzati Azman, Nurul; Nur Fathiyah Jamaludin, Siti

2017-10-01

This study aims to investigate the relation of oil seepage at Sikuati area with the structural and petroleum system of Kudat Peninsula. The abundance of highly carbonaceous rocks with presence of lamination in the Sikuati Member outcrop at Kudat Peninsula may give an idea on the presence of oil seepage in this area. A detailed geochemical analysis of source rock sample and oil seepage from Sikuati area was carried out for their characterization and correlation. Hydrocarbon propectivity of Sikuati Member source rock is poor to good with Total Organic Carbon (TOC) value of 0.11% to 1.48%. and also categorized as immature to early mature oil window with Vitrinite Reflectance (VRo) value of 0.43% to 0.50 %Ro. Based on biomarker distribution, from Gas Chromatography (GC) and Gas Chromatography-Mass Spectrometry (GC-MS) analysis, source rock sample shows Pr/Ph, CPI and WI of 2.22 to 2.68, 2.17 to 2.19 and 2.46 to 2.74 respectively indicates the source rock is immature and coming from terrestrial environment. The source rock might be rich in carbonaceous material organic matter resulting from planktonic/bacterial activity which occurs at fluvial to fluvio-deltaic environment. Overall, the source rock from outcrop level of Kudat Peninsula is moderately prolific in term of prospectivity and maturity. However, as go far deeper beneath the surface, we can expect more activity of mature source rock that generate and expulse hydrocarbon from the subsurface then migrating through deep-seated fault beneath the Sikuati area.

Alteration of immature sedimentary rocks on Earth and Mars. Recording Aqueous and Surface-atmosphere Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cannon, Kenneth M.; Mustard, John F.; Salvatore, Mark R.

The rock alteration and rind formation in analog environments like Antarctica may provide clues to rock alteration and therefore paleoclimates on Mars. Clastic sedimentary rocks derived from basaltic sources have been studied in situ by martian rovers and are likely abundant on the surface of Mars. Moreover, how such rock types undergo alteration when exposed to different environmental conditions is poorly understood compared with alteration of intact basaltic flows. Here we characterize alteration in the chemically immature Carapace Sandstone from Antarctica, a terrestrial analog for martian sedimentary rocks. We employ a variety of measurements similar to those used on previousmore » and current Mars missions. Laboratory techniques included bulk chemistry, powder X-ray diffraction (XRD), hyperspectral imaging and X-ray absorption spectroscopy. Through these methods we find that primary basaltic material in the Carapace Sandstone is pervasively altered to hydrated clay minerals and palagonite as a result of water–rock interaction. A thick orange rind is forming in current Antarctic conditions, superimposing this previous aqueous alteration signature. The rind exhibits a higher reflectance at visible-near infrared wavelengths than the rock interior, with an enhanced ferric absorption edge likely due to an increase in Fe 3+ of existing phases or the formation of minor iron (oxy)hydroxides. This alteration sequence in the Carapace Sandstone results from decreased water–rock interaction over time, and weathering in a cold, dry environment, mimicking a similar transition early in martian history. This transition may be recorded in sedimentary rocks on Mars through a similar superimposition mechanism, capturing past climate changes at the hand sample scale. These results also suggest that basalt-derived sediments could have sourced significant volumes of hydrated minerals on early Mars due to their greater permeability compared with intact igneous rocks.« less

Metabasalts as sources of metals in orogenic gold deposits

NASA Astrophysics Data System (ADS)

Pitcairn, Iain K.; Craw, Dave; Teagle, Damon A. H.

2015-03-01

Although metabasaltic rocks have been suggested to be important source rocks for orogenic gold deposits, the mobility of Au and related elements (As, Sb, Se, and Hg) from these rocks during alteration and metamorphism is poorly constrained. We investigate the effects of increasing metamorphic grade on the concentrations of Au and related elements in a suite of metabasaltic rocks from the Otago and Alpine Schists, New Zealand. The metabasaltic rocks in the Otago and Alpine Schists are of MORB and WPB affinity and are interpreted to be fragments accreted from subducting oceanic crust. Gold concentrations are systematically lower in the higher metamorphic grade rocks. Average Au concentrations vary little between sub-greenschist (0.9 ± 0.5 ppb) and upper greenschist facies (1.0 ± 0.5 ppb), but decrease significantly in amphibolite facies samples (0.21 ± 0.07 ppb). The amount of Au depleted from metabasaltic rocks during metamorphism is on a similar scale to that removed from metasedimentary rocks in Otago. Arsenic concentrations increase with metamorphic grade with the metabasaltic rocks acting as a sink rather than a source of this element. The concentrations of Sb and Hg decrease between sub-greenschist and amphibolite facies but concentration in amphibolite facies rocks are similar to those in unaltered MORB protoliths and therefore unaltered oceanic crust cannot be a net source of Sb and Hg in a metamorphic environment. The concentrations of Au, As, Sb, and Hg in oceanic basalts that have become integrated into the metamorphic environment may be heavily influenced by the degree of seafloor alteration that occurred prior to metamorphism. We suggest that metasedimentary rocks are much more suitable source rocks for fluids and metals in orogenic gold deposits than metabasaltic rocks as they show mobility during metamorphism of all elements commonly enriched in this style of deposit.

Rock fall simulation at Timpanogos Cave National Monument, American Fork Canyon, Utah, USA

USGS Publications Warehouse

Harp, E.L.; Dart, R.L.; Reichenbach, P.

2011-01-01

Rock fall from limestone cliffs at Timpanogos Cave National Monument in American Fork Canyon east of Provo, Utah, is a common occurrence. The cave is located in limestone cliffs high on the southern side of the canyon. One fatality in 1933 led to the construction of rock fall shelters at the cave entrance and exit in 1976. Numerous rock fall incidents, including a near miss in 2000 in the vicinity of the trail below the cave exit, have led to a decision to extend the shelter at the cave exit to protect visitors from these ongoing rock fall events initiating from cliffs immediately above the cave exit. Three-dimensional rock fall simulations from sources at the top of these cliffs have provided data from which to assess the spatial frequencies and velocities of rock falls from the cliffs and to constrain the design of protective measures to reduce the rock fall hazard. Results from the rock fall simulations are consistent with the spatial patterns of rock fall impacts that have been observed at the cave exit site. ?? 2011 Springer-Verlag.

Rock fall simulation at Timpanogos Cave National Monument, American Fork Canyon, Utah, USA

USGS Publications Warehouse

Harp, Edwin L.; Dart, Richard L.; Reichenbach, Paola

2011-01-01

Rock fall from limestone cliffs at Timpanogos Cave National Monument in American Fork Canyon east of Provo, Utah, is a common occurrence. The cave is located in limestone cliffs high on the southern side of the canyon. One fatality in 1933 led to the construction of rock fall shelters at the cave entrance and exit in 1976. Numerous rock fall incidents, including a near miss in 2000 in the vicinity of the trail below the cave exit, have led to a decision to extend the shelter at the cave exit to protect visitors from these ongoing rock fall events initiating from cliffs immediately above the cave exit. Three-dimensional rock fall simulations from sources at the top of these cliffs have provided data from which to assess the spatial frequencies and velocities of rock falls from the cliffs and to constrain the design of protective measures to reduce the rock fall hazard. Results from the rock fall simulations are consistent with the spatial patterns of rock fall impacts that have been observed at the cave exit site.

Gold in placer deposits

USGS Publications Warehouse

Yeend, Warren; Shawe, Daniel R.; Wier, Kenneth L.

1989-01-01

Man most likely first obtained gold from placer deposits, more than 6,000 years ago. Placers account for more than two-thirds of the total world gold supply, and roughly half of that mined in the States of California, Alaska, Montana, and Idaho.Placer deposits result from weathering and release of gold from lode deposits, transportation of the gold, and concentration of the gold dominantly in stream gravels. Unless preserved by burial, a placer subsequently may be eroded, and either dispersed or reconcentrated.California has produced more than 40 million troy ounces of gold from placers, both modern and fossil (Tertiary). The source of the great bulk of the gold is numerous quartz veins and mineralized zones of the Mother Lode and related systems in the western Sierra Nevada region. The gold-bearing lodes were emplaced in Carboniferous and Jurassic metamorphic rocks intruded by small bodies of Jurassic and Cretaceous igneous rocks. Mineralization occurred probably in Late Cretaceous time. Significant amounts of placer gold also were mined along the Salmon and Trinity Rivers in northern California. Source of the gold is lode deposits in Paleozoic and Mesozoic metamorphic rocks that were intruded by Mesozoic igneous rocks.Alaska has produced roughly 21 million ounces of gold from placer deposits. Most (about 13 million ounces) has come from the interior region, including 7,600,000 ounces from the Fairbanks district and 1,300,000 ounces from the Iditarod district. Lode sources are believed to be mostly quartz veins in Precambrian or Paleozoic metamorphic rocks intruded by small igneous bodies near Fairbanks, and shear zones in Tertiary(?) quartz monzonite stocks at Iditarod. The Seward Peninsula has produced more than 6 million ounces of placer gold, including about 4,000,000 ounces from the Nome district. Most of the gold was derived from raised beach deposits. Source of the gold probably is Tertiary-mineralized faults and joints in metamorphic rocks of late Precambrian age.The Helena-Last Chance district, Montana, produced nearly 1 million ounces of gold from placers that were derived from lode deposits in the contact zones of the Cretaceous Boulder batholith granitic rocks intruded into upper Precambrian, Paleozoic, and Mesozoic sedimentary rocks. The Virginia City-Alder Gulch district, Montana, produced more than 2,600,000 ounces of gold, nearly all from placer deposits derived from quartz veins of uncertain age in Archean gneisses and schists. The Boise basin district, Idaho, produced about 2,300,000 ounces of gold, mostly derived from quartz veins in quartz monzonite of the Cretaceous Idaho batholith.

Marine and nonmarine gas-bearing rocks in Upper Cretaceous Blackhawk and Neslen Formations, eastern Uinta Basin, Utah: sedimentology, diagenesis, and source rock potential

USGS Publications Warehouse

Pitman, Janet K.; Franczyk, K.J.; Anders, D.E.

1987-01-01

Thermogenic gas was generated from interbedded humic-rich source rocks. The geometry and distribution of hydrocarbon source and reservoir rocks are controlled by depositional environment. The rate of hydrocarbon generation decreased from the late Miocene to the present, owing to widespread cooling that occurred in response to regional uplift and erosion associated with the development of the Colorado Plateau. -from Authors

The Natural Radiation Environment, Understanding the Atom Series.

ERIC Educational Resources Information Center

Kastner, Jacob

The somatic and genetic effects of naturally occurring radiation are described in this illustrated booklet. Internal sources of radiation from food, water, and air and external sources including radioisotopes in rock, brick, water, and air and cosmic radiation are tabulated. Detection methods are described, and their use in biological and physical…

Overview of the potential and identified petroleum source rocks of the Appalachian basin, eastern United States: Chapter G.13 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Coleman, James L.; Ryder, Robert T.; Milici, Robert C.; Brown, Stephen; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

The Appalachian basin is the oldest and longest producing commercially viable petroleum-producing basin in the United States. Source rocks for reservoirs within the basin are located throughout the entire stratigraphic succession and extend geographically over much of the foreland basin and fold-and-thrust belt that make up the Appalachian basin. Major source rock intervals occur in Ordovician, Devonian, and Pennsylvanian strata with minor source rock intervals present in Cambrian, Silurian, and Mississippian strata.

Petroleum geology and resources of the Dnieper-Donets Basin, Ukraine and Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

The Dnieper-Donets basin is almost entirely in Ukraine, and it is the principal producer of hydrocarbons in that country. A small southeastern part of the basin is in Russia. The basin is bounded by the Voronezh high of the Russian craton to the northeast and by the Ukrainian shield to the southwest. The basin is principally a Late Devonian rift that is overlain by a Carboniferous to Early Permian postrift sag. The Devonian rift structure extends northwestward into the Pripyat basin of Belarus; the two basins are separated by the Bragin-Loev uplift, which is a Devonian volcanic center. Southeastward, the Dnieper-Donets basin has a gradational boundary with the Donbas foldbelt, which is a structurally inverted and deformed part of the basin. The sedimentary succession of the basin consists of four tectono-stratigraphic sequences. The prerift platform sequence includes Middle Devonian to lower Frasnian, mainly clastic, rocks that were deposited in an extensive intracratonic basin. 1 The Upper Devonian synrift sequence probably is as thick as 4?5 kilometers. It is composed of marine carbonate, clastic, and volcanic rocks and two salt formations, of Frasnian and Famennian age, that are deformed into salt domes and plugs. The postrift sag sequence consists of Carboniferous and Lower Permian clastic marine and alluvial deltaic rocks that are as thick as 11 kilometers in the southeastern part of the basin. The Lower Permian interval includes a salt formation that is an important regional seal for oil and gas fields. The basin was affected by strong compression in Artinskian (Early Permian) time, when southeastern basin areas were uplifted and deeply eroded and the Donbas foldbelt was formed. The postrift platform sequence includes Triassic through Tertiary rocks that were deposited in a shallow platform depression that extended far beyond the Dnieper-Donets basin boundaries. A single total petroleum system encompassing the entire sedimentary succession is identified in the Dnieper-Donets basin. Discovered reserves of the system are 1.6 billion barrels of oil and 59 trillion cubic feet of gas. More than one-half of the reserves are in Lower Permian rocks below the salt seal. Most of remaining reserves are in upper Visean-Serpukhovian (Lower Carboniferous) strata. The majority of discovered fields are in salt-cored anticlines or in drapes over Devonian horst blocks; little exploration has been conducted for stratigraphic traps. Synrift Upper Devonian carbonate reservoirs are almost unexplored. Two identified source-rock intervals are the black anoxic shales and carbonates in the lower Visean and Devonian sections. However, additional source rocks possibly are present in the deep central area of the basin. The role of Carboniferous coals as a source rock for gas is uncertain; no coal-related gas has been identified by the limited geochemical studies. The source rocks are in the gas-generation window over most of the basin area; consequently gas dominates over oil in the reserves. Three assessment units were identified in the Dnieper-Donets Paleozoic total petroleum system. The assessment unit that contains all discovered reserves embraces postrift Carboniferous and younger rocks. This unit also contains the largest portion of undiscovered resources, especially gas. Stratigraphic and combination structural and stratigraphic traps probably will be the prime targets for future exploration. The second assessment unit includes poorly known synrift Devonian rocks. Carbonate reef reservoirs along the basin margins probably will contain most of the undiscovered resources. The third assessment unit is an unconventional, continuous, basin-centered gas accumulation in Carboniferous low-permeability clastic rocks. The entire extent of this accumulation is unknown, but it occupies much of the basin area. Resources of this assessment unit were not estimated quantitatively.

Simulation of ground-water flow to assess geohydrologic factors and their effect on source-water areas for bedrock wells in Connecticut

USGS Publications Warehouse

Starn, J. Jeffrey; Stone, Janet Radway

2005-01-01

Generic ground-water-flow simulation models show that geohydrologic factors?fracture types, fracture geometry, and surficial materials?affect the size, shape, and location of source-water areas for bedrock wells. In this study, conducted by the U.S. Geological Survey in cooperation with the Connecticut Department of Public Health, ground-water flow was simulated to bedrock wells in three settings?on hilltops and hillsides with no surficial aquifer, in a narrow valley with a surficial aquifer, and in a broad valley with a surficial aquifer?to show how different combinations of geohydrologic factors in different topographic settings affect the dimensions and locations of source-water areas in Connecticut. Three principal types of fractures are present in bedrock in Connecticut?(1) Layer-parallel fractures, which developed as partings along bedding in sedimentary rock and compositional layering or foliation in metamorphic rock (dips of these fractures can be gentle or steep); (2) unroofing joints, which developed as strain-release fractures parallel to the land surface as overlying rock was removed by erosion through geologic time; and (3) cross fractures and joints, which developed as a result of tectonically generated stresses that produced typically near-vertical or steeply dipping fractures. Fracture geometry is defined primarily by the presence or absence of layering in the rock unit, and, if layered, by the angle of dip in the layering. Where layered rocks dip steeply, layer-parallel fracturing generally is dominant; unroofing joints also are typically well developed. Where layered rocks dip gently, layer-parallel fracturing also is dominant, and connections among these fractures are provided only by the cross fractures. In gently dipping rocks, unroofing joints generally do not form as a separate fracture set; instead, strain release from unroofing has occurred along gently dipping layer-parallel fractures, enhancing their aperture. In nonlayered and variably layered rocks, layer-parallel fracturing is absent or poorly developed; fracturing is dominated by well-developed subhorizontal unroofing joints and steeply dipping, tectonically generated fractures and (or) cooling joints. Cross fractures (or cooling joints) in nonlayered and variably layered rocks have more random orientations than in layered rocks. Overall, nonlayered or variably layered rocks do not have a strongly developed fracture direction. Generic ground-water-flow simulation models showed that fracture geometry and other geohydrologic factors affect the dimensions and locations of source-water areas for bedrock wells. In general, source-water areas to wells reflect the direction of ground-water flow, which mimics the land-surface topography. Source-water areas to wells in a hilltop setting were not affected greatly by simulated fracture zones, except for an extensive vertical fracture zone. Source-water areas to wells in a hillside setting were not affected greatly by simulated fracture zones, except for the combination of a subhorizontal fracture zone and low bedrock vertical hydraulic conductivity, as might be the case where an extensive subhorizontal fracture zone is not connected or is poorly connected to the surface through vertical fractures. Source-water areas to wells in a narrow valley setting reflect complex ground-water-flow paths. The typical flow path originates in the uplands and passes through either till or bedrock into the surficial aquifer, although only a small area of the surficial aquifer actually contributes water to the well. Source-water areas in uplands can include substantial areas on both sides of a river. Source-water areas for wells in this setting are affected mainly by the rate of ground-water recharge and by the degree of anisotropy. Source-water areas to wells in a broad valley setting (bedrock with a low angle of dip) are affected greatly by fracture properties. The effect of a given fracture is to channel the

Characterization of rock thermal conductivity by high-resolution optical scanning

USGS Publications Warehouse

Popov, Y.A.; Pribnow, D.F.C.; Sass, J.H.; Williams, C.F.; Burkhardt, H.

1999-01-01

We compared thress laboratory methods for thermal conductivity measurements: divided-bar, line-source and optical scanning. These methods are widely used in geothermal and petrophysical studies, particularly as applied to research on cores from deep scientific boreholes. The relatively new optical scanning method has recently been perfected and applied to geophysical problems. A comparison among these methods for determining the thermal conductivity tensor for anisotropic rocks is based on a representative collection of 80 crystalline rock samples from the KTB continental deep borehole (Germany). Despite substantial thermal inhomogeneity of rock thermal conductivity (up to 40-50% variation) and high anisotropy (with ratios of principal values attaining 2 and more), the results of measurements agree very well among the different methods. The discrepancy for measurements along the foliation is negligible (<1%). The component of thermal conductivity normal to the foliation reveals somewhat larger differences (3-4%). Optical scanning allowed us to characterize the thermal inhomogeneity of rocks and to identify a three-dimensional anisotropy in thermal conductivity of some gneiss samples. The merits of optical scanning include minor random errors (1.6%), the ability to record the variation of thermal conductivity along the sample, the ability to sample deeply using a slow scanning rate, freedom from constraints for sample size and shape, and quality of mechanical treatment of the sample surface, a contactless mode of measurement, high speed of operation, and the ability to measure on a cylindrical sample surface. More traditional methods remain superior for characterizing bulk conductivity at elevated temperature.Three laboratory methods including divided-bar, line-source and optical scanning are widely applied in geothermal and petrophysical studies. In this study, these three methods were compared for determining the thermal conductivity tensor for anisotropic rocks. For this study, a representative collection of 80 crystalline rock samples from the KTB continental deep borehole was used. Despite substantial thermal inhomogeneity of rock thermal conductivity and high anisotropy, measurement results were in excellent agreement among the three methods.

Total petroleum systems of the Paleozoic and Jurassic, Greater Ghawar Uplift and adjoining provinces of central Saudi Arabia and northern Arabian-Persian Gulf

USGS Publications Warehouse

Pollastro, Richard M.

2003-01-01

Oil of the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS is sourced by organic-rich, marine carbonates of the Jurassic Tuwaiq Mountain and Hanifa Formations. These source rocks were deposited in two of three intraplatform basins during the Jurassic and, where thermally mature, have generated a superfamily of oils with distinctive geochemical characteristics. Oils were generated and expelled from these source rocks beginning in the Cretaceous at about 75 Ma. Hydrocarbon production is from 3 cyclic carbonate-rock reservoirs of the Arab Formation that are sealed by overlying anhydrite. Several giant and supergiant fields, including the world's largest oil field at Ghawar, Saudi Arabia, produce mostly from the Arab carbonate-rock reservoirs. Two assessment units are also recognized in the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS that are similarly related to structural trap style and presence of underlying Infracambrian salt: (1) an onshore Horst-Block Anticlinal Oil AU, and (2) a mostly offshore Salt-Involved Structural Oil AU. The mean total volume of undiscovered resource for the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS is estimated at about 49 billion barrels of oil equivalent (42 billion barrels of oil, 34 trillion feet of gas, and 1.4 billion barrels of natural gas liquids).

Petroleum Systems and Assessment of Undiscovered Oil and Gas in the Raton Basin - Sierra Grande Uplift Province, Colorado and New Mexico - USGS Province 41

USGS Publications Warehouse

Higley, Debra K.

2007-01-01

Introduction The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas resources of the Raton Basin-Sierra Grande Uplift Province of southeastern Colorado and northeastern New Mexico (USGS Province 41). The Cretaceous Vermejo Formation and Cretaceous-Tertiary Raton Formation have production and undiscovered resources of coalbed methane. Other formations in the province exhibit potential for gas resources and limited production. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define two total petroleum systems and five assessment units. All five assessment units were quantitatively assessed for undiscovered gas resources. Oil resources were not assessed because of the limited potential due to levels of thermal maturity of petroleum source rocks.

Assessment of undiscovered oil and gas resources of the Williston Basin Province of North Dakota, Montana, and South Dakota, 2010

USGS Publications Warehouse

,

2011-01-01

Using a geology-based assessment method, the U.S. Geological Survey estimated mean undiscovered volumes of 3.8 billion barrels of undiscovered oil, 3.7 trillion cubic feet of associated/dissolved natural gas, and 0.2 billion barrels of undiscovered natural gas liquids in the Williston Basin Province, North Dakota, Montana, and South Dakota. The U.S. Geological Survey (USGS) recently completed a comprehensive oil and gas assessment of the Williston Basin, which encompasses more than 90 million acres in parts of North Dakota, eastern Montana, and northern South Dakota. The assessment is based on the geologic elements of each total petroleum system (TPS) defined in the province, including hydrocarbon source rocks (source-rock maturation, hydrocarbon generation, and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined 11 TPS and 19 Assessment Units (AU).

National Assessment of Oil and Gas Project: Petroleum Systems and Geologic Assessment of Undiscovered Oil and Gas, Hanna, Laramie, and Shirley Basins Province, Wyoming

USGS Publications Warehouse

U.S. Geological Survey Hanna, Laramie

2007-01-01

INTRODUCTION The purpose of the U.S. Geological Survey?s (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Hanna, Laramie, and Shirley Basins Province in Wyoming and northeastern Colorado. The assessment is based on the geologic elements of each total petroleum system (TPS) defined in the province, including hydrocarbon source rocks (source-rock maturation, hydrocarbon generation, and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined three TPSs and seven assessment units (AUs) within them; undiscovered resources for three of the seven AUs were quantitatively assessed.

Executive Summary -- assessment of undiscovered oil and gas resources of the San Joaquin Basin Province of California, 2003: Chapter 1 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Gautier, Donald L.; Scheirer, Allegra Hosford; Tennyson, Marilyn E.; Peters, Kenneth E.; Magoon, Leslie B.; Lillis, Paul G.; Charpentier, Ronald R.; Cook, Troy A.; French, Christopher D.; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.

2007-01-01

In 2003, the U.S. Geological Survey (USGS) completed an assessment of the oil and gas resource potential of the San Joaquin Basin Province of California (fig. 1.1). The assessment is based on the geologic elements of each Total Petroleum System defined in the province, including hydrocarbon source rocks (source-rock type and maturation and hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined five total petroleum systems and ten assessment units within these systems. Undiscovered oil and gas resources were quantitatively estimated for the ten assessment units (table 1.1). In addition, the potential was estimated for further growth of reserves in existing oil fields of the San Joaquin Basin.

Jurassic-Cretaceous Composite Total Petroleum System and Geologic Assessment of Oil and Gas Resources of the North Cuba Basin, Cuba

USGS Publications Warehouse

,

2008-01-01

The purpose of the U.S. Geological Survey's (USGS) World Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the world. The U.S. Geological Survey (USGS) completed an assessment of the undiscovered oil and gas potential of the North Cuba Basin. The assessment is based on the geologic elements of the total petroleum system (TPS) defined in the province, including petroleum source rocks (source-rock maturation, generation, and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and petroleum traps (Trap formation and timing). Using this geologic framework, the USGS defined a Jurassic-Cretaceous Total Petroleum System in the North Cuba Basin Province. Within this TPS, three assessment units were defined and assessed for undiscovered oil and gas resources.

Aquifer-nomenclature guidelines

USGS Publications Warehouse

Laney, R.L.; Davidson, C.B.

1986-01-01

Guidelines and recommendations for naming aquifers are presented to assist authors of geohydrological reports in the United States Geological Survey, Water Resources Division. The hierarchy of terms that is used for water- yielding rocks from largest to smallest is aquifer system, aquifer, and zone. If aquifers are named, the names should be derived from lithologic terms, rock-stratigraphic units, or geographic names. The following items are not recommended as sources of aquifer names: time-stratigraphic names, relative position, alphanumeric designations, depositional environment, depth of occurrence, acronyms, and hydrologic conditions. Confining units should not be named unless doing so clearly promotes understanding of a particular aquifer system. Sources of names for confining units are similar to those for aquifer names, i.e. lithologic terms, rock-stratigraphic units or geographic names. Examples of comparison charts and tables that are used to define the geohydrologic framework are included. Aquifers are defined in 11 hypothetical examples that characterize geohydrologic settings throughout the country. (Author 's abstract)

Zircon U-Pb ages and Hf isotopic compositions indicate multiple sources for Grenvillian detrital zircon deposited in western Laurentia

NASA Astrophysics Data System (ADS)

Howard, Amanda L.; Farmer, G. Lang; Amato, Jeffrey M.; Fedo, Christopher M.

2015-12-01

Combined U-Pb ages and Hf isotopic data from 1.0 Ga to 1.3 Ga (Grenvillian) detrital zircon in Neoproterozoic and Cambrian siliciclastic sedimentary rocks in southwest North America, and from igneous zircon in potential Mesoproterozoic source rocks, are used to better assess the provenance of detrital zircon potentially transported across Laurentia in major river systems originating in the Grenville orogenic highlands. High-precision hafnium isotopic analyses of individual ∼1.1 Ga detrital zircon from Neoproterozoic siliciclastic sedimentary rocks in Sonora, northern Mexico, reveal that these zircons have low εHf (0) (-22 to -26) and were most likely derived from ∼1.1 Ga granitic rocks embedded in local Mojave Province Paleoproterozoic crust. In contrast, Grenvillian detrital zircons in Cambrian sedimentary rocks in Sonora, the Great Basin, and the Mojave Desert, have generally higher εHf (0) (-15 to -21) as demonstrated both by high precision solution-based, and by lower precision laser ablation, ICPMS data and were likely derived from more distal sources further to the east/southeast in Laurentia. Comparison to new and existing zircon U-Pb geochronology and Hf isotopic data from Grenvillian crystalline rocks from the Appalachian Mountains, central and west Texas, and from Paleoproterozoic terranes throughout southwest North America reveals that zircon in Cambrian sandstones need not entirely represent detritus transported across the continent from Grenville province rocks in the vicinity of the present-day southern Appalachian Mountains. Instead, these zircons could have been derived from more proximal, high εHf (0), ∼1.1 Ga, crystalline rocks such as those exposed today in the Llano Uplift in central Texas and in the Franklin Mountains of west Texas. Regardless of the exact source(s) of the Grenvillian detrital zircon, new and existing whole-rock Nd isotopic data from Neoproterozoic to Cambrian siliciclastic sedimentary rocks in the Mojave Desert demonstrate that the occurrences of higher εHf (0), Grenvillian detrital zircons are decoupled from the sources of the bulk of the sedimentary detritus in which the zircons are entrained. The Cambrian Wood Canyon Formation and the underlying ;off craton; Neoproterozoic Johnnie Formation and Stirling Quartzite all contain higher εHf (0), Grenvillian detrital zircon, in some cases as the dominant detrital zircon population. However, only portions of the Wood Canyon Formation have whole rock Nd isotopic compositions consistent with a bulk sediment source in ∼1.1 Ga sources rocks. Whole rock Nd isotopic compositions of the remaining portions of this unit, and all of the Johnnie Formation and Stirling Quartzite, require bulk sediment sources principally in Paleoproterozoic continental crust. We consider the observed decoupling in the sources of Grenvillian detrital zircon and bulk sediment in the Wood Canyon Formation and underlying siliciclastic sediments as a demonstration that detrital zircon U-Pb and Hf isotopic data alone can provide an incomplete picture of the source of sediments that comprise a given siliciclastic stratigraphic unit.

Large-scale removal of lithosphere underneath the North China Craton in the Early Cretaceous: Geochemical constraints from volcanic lavas in the Bohai Bay Basin

NASA Astrophysics Data System (ADS)

Sun, Jing; Liu, Zheng; Zhang, Shuai; Li, Xiaoguang; Qi, Jiafu

2017-11-01

Cratons are generally considered as the most stable tectonic units on the Earth. Rare magmatism, seismic activity, and intracrustal ductile deformation occur in them. However, several cratons experienced entirely different fates, including the North China Craton (NCC), and were subsequently destroyed. Geodynamic mechanisms and timing of the cratonic destruction are strongly debated. In this paper, we investigate a suite of Mesozoic intermediate to felsic volcanic rocks which are collected from boreholes in the Liaohe Depression of the Bohai Bay Basin the eastern NCC. These volcanic rocks have Precambrian basement-like Sr-Nd isotopic characteristics, consistent with derivation from the lower continental crust underneath the NCC. The Late Jurassic ( 165 Ma) intermediate volcanic rocks don't exhibit markedly negative Eu anomalies, which require a source beyond the plagioclase stability field. And the low heavy rare earth elements (HREEs) contents of these samples indicate that their source has garnet as residue. The Early Cretaceous ( 122 Ma) felsic volcanic rocks are depleted in HREEs but with remarkable Eu anomalies, suggesting that their source have both garnet and plagioclase. The crust thicknesses, estimated from the geochemistry of the intermediate and felsic rocks, are ≥ 50 km at 165 Ma and 30-50 km at 122 Ma, respectively. The crustal thinning is attributed to lithospheric delamination beneath the NCC. Our results combined with previous studies imply that the large-scale lithospheric removal occurred in the Early Cretaceous, between 140 and 120 Ma.

Fluorine, fluorite, and fluorspar in central Colorado

USGS Publications Warehouse

Wallace, Alan R.

2010-01-01

Fluorine (F) is a widespread element that was deposited in a variety of rocks, minerals, and geologic environments in central Colorado. It occurs as a trace element, as a major component of the mineral fluorite (CaFs), and as a major economic source of fluorine in fluorspar deposits, which are massive concentrations of fluorite. This study has compiled available geochemical analyses of rocks, both unmineralized and mineralized, to determine the distribution of fluorine in specific age-lithologic categories, ranging from 1.8-giga-annum (Ga) metamorphic rocks to modern soils, throughout central Colorado. It also draws upon field studies of fluorine-rich mineral deposits, including fluorspar deposits, to decipher the nearly two-billion-year-long geologic history of fluorine in the study area, with implications for mineral-resource evaluations and exploration. The resulting compilation provides an important inventory of the naturally occurring levels and sources of fluorine that ultimately weather, erode, and become part of surface waters that are used for domestic water supplies in densely populated areas along the Colorado Front Range. Most commonly, fluorine is a trace element in virtually all rocks in the region. In the 3,798 unmineralized rocks that were analyzed for fluorine in the study area, the average fluorine content was 1,550 parts per million (ppm). The median was 640 ppm, nearly identical to the average crustal abundance of 650 ppm, and some high-fluorine rocks in the Pikes Peak area skewed the average to a value much greater than the median. Most unmineralized age-lithologic rock suites, including Proterozoic metamorphic rocks, 1.7- and 1.4-Ga granitic batholiths, Cambrian igneous rocks, Phanerozoic sedimentary rocks, and Laramide and Tertiary igneous rocks, had median fluorine values of 400 to 740 ppm fluorine. In all suites, however, a small number of analyzed samples contained more than 1 percent (10,000 ppm) fluorine. The 1.1-Ga plutonic rocks related to the Pikes Peak batholith had a mean fluorine content of 1,700 ppm, and primary magmatic fluorite and fluorite-bearing pegmatites are common throughout that igneous mass. Fluorine was deposited in many types of economic mineral deposits in central Colorado, and it currently is a significant trace element in some thermal springs. In the fluorspar deposits, fluorine contents were as high as 37 percent. Some fluorine-rich porphyry systems, such as Jamestown, had fluorine values that ranged from 200 ppm to nearly 37 percent fluorine, and veins in other deposits contained hydrothermal fluorite, although it was not ubiquitous. For the 495 samples from non-fluorspar mining districts (and excluding Jamestown), however, the median fluorine content was 990 ppm. This is above the crustal average but still relatively modest compared to the fluorspar deposits, and it indicates that the majority of the mineralizing systems in central Colorado did not deposit large amounts of fluorine. Nevertheless, the fluorine- and fluorite-rich mineral deposits could be used as guides for the evaluation and discovery of related but concealed porphyry and epithermal base- and precious-metal deposits. The Cenozoic geologic history of central Colorado included multiple periods during which fluorine-bearing rocks and mineral deposits were exposed, weathered, and eroded. This protracted history has released fluorine into soils and regoliths, and modern rainfall and snowmelt interact with these substrates to add fluorine to the hydrosphere. This study did not evaluate the fluorine contents of water or make any predictions about what areas might be major sources for dissolved fluorine. However, the abundant data that are available on fluorine in surface water and ground water can be coupled with the results of this study to provide additional insight into natural sources of fluorine in domestic drinking water.

Variations in the sterane carbon number distributions of marine source rock derived crude oils through geological time

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grantham, P.J.; Wakefield, L.L.

1988-01-01

The analysis of the sterane data of a large set of crude oils (414) derived from marine carbonate (27) and siliciclastic source rocks (14) where influences of terrestrial or lacustrine derived organic matter can reasonably be excluded, shows that there are increases in the relative content of C/sub 28/ steranes and decreases in the relative content of C/sub 29/ steranes through geological time. There are no consistent variations in the relative content of C/sub 27/ steranes through time. With one major exception (a Proterozoic oil from Oman), Paleozoic and older crude oils are thus generally characterized by strong predominances ofmore » C/sub 29/ steranes and low relative concentrations of C/sub 28/ steranes. Significantly higher proportions of C/sub 28/ steranes and lower proportions of C/sub 29/ steranes occur in oils derived from Jurassic and Upper Cretaceous source rocks. These changes through time do not appear to reflect the chemical evolution of the sterols of one particular variety of marine organism: the increase in C/sub 28/ steranes may be related to the increased diversification of phytoplantonic assemblages in the Jurassic and Cretaceous. Possible sources of the C/sub 28/ sterols necessary for the observed changes in crude oil steranes includes diatoms, coccolithophores and dinoflagellates. Although the technique does not give an accurate means of determining the age of the source rock of a crude oil it is possible to distinguish younger crudes derived from the Upper Cretaceous and Tertiary from Palaeozoic and older crudes.« less

A Model of the Chicxulub Impact Basin Based on Evaluation of Geophysical Data, Well Logs, and Drill Core Samples

NASA Technical Reports Server (NTRS)

Sharpton, Virgil L.; Marin, Luis E.; Carney, John D.; Lee, Scott; Ryder, Graham; Schuraytz, Benjamin C.; Sikora, Paul; Spudis, Paul D.

1996-01-01

Abundant evidence now shows that the buried Chicxulub structure in northern Yucatan, Mexico, is indeed the intensely sought-after source of the ejecta found world-wide at the Cretaceous-Tertiary (K/T) boundary. In addition to large-scale concentric patterns in gravity and magnetic data over the structure, recent analyses of drill-core samples reveal a lithological assemblage similar to that observed at other terrestrial craters. This assemblage comprises suevite breccias, ejecta deposit breccias (Bunte Breccia equivalents), fine-grained impact melt rocks, and melt-matrix breccias. All these impact-produced lithologies contain diagnostic evidence of shock metamorphism, including planar deformation features in quartz, feldspar, and zircons; diaplectic glasses of quartz and feldspar; and fused mineral melts and whole-rock melts. In addition, elevated concentrations of Ir, Re, and Os, in meteoritic relative proportions, have been detected in some melt-rock samples from the center of the structure. Isotopic analyses, magnetization of melt-rock samples, and local stratigraphic constraints identify this crater as the source of K/T boundary deposits.

Geochemical signature of provenance, tectonics and chemical weathering in the Quaternary flood plain sediments of the Hindon River, Gangetic plain, India

NASA Astrophysics Data System (ADS)

Mondal, M. E. A.; Wani, H.; Mondal, Bulbul

2012-09-01

The Ganga basin in the Himalayan foreland is a part of the world's largest area of modern alluvial sedimentation. Flood plain sediments of the Hindon River of the Gangetic plain have been analyzed for sediment texture, major and trace elements including rare earth elements (REEs). The results have been used to characterize the source rock composition and to understand the intensity of chemical weathering, tectonics and their interplay in the Hindon flood plain. The sediments of the Hindon flood plain dominantly consist of sand sized particles with little silt and clay. The geochemistry of the Hindon sediments has been compared to the Siwalik mudstone of the Siwalik Group (Siwaliks). The Siwalik sedimentary rocks like sandstones, mudstones and conglomerates are the known source rocks for the Hindon flood plain sediments. Mudstone geochemistry has been considered best to represent the source rock characteristics. The UCC (Upper Continental Crust) normalized major and trace elements of the Hindon flood plain sediments are very similar to the Siwalik mudstone except for Th and Cr. Furthermore, the average chondrite normalized REE pattern of the Hindon flood plain sediments is similar to the Siwalik mudstone. Textural immaturity, K/Rb ratios and the average CIA (Chemical Index of Alteration) and PIA (Plagioclase Index of Alteration) values of the Hindon flood plain sediments indicate that the sediments have not been affected by chemical weathering. Our study suggests that the active tectonics of the Himalayas and monsoon climate enhances only physical erosion of the source rocks (Siwaliks) rather than the chemical alteration. These factors help the Hindon sediments to retain their parental and tectonic signature even after recycling.

Temperature and composition of carbonate cements record early structural control on cementation in a nascent deformation band fault zone: Moab Fault, Utah, USA

NASA Astrophysics Data System (ADS)

Hodson, Keith R.; Crider, Juliet G.; Huntington, Katharine W.

2016-10-01

Fluid-driven cementation and diagenesis within fault zones can influence host rock permeability and rheology, affecting subsequent fluid migration and rock strength. However, there are few constraints on the feedbacks between diagenetic conditions and structural deformation. We investigate the cementation history of a fault-intersection zone on the Moab Fault, a well-studied fault system within the exhumed reservoir rocks of the Paradox Basin, Utah, USA. The fault zone hosts brittle structures recording different stages of deformation, including joints and two types of deformation bands. Using stable isotopes of carbon and oxygen, clumped isotope thermometry, and cathodoluminescence, we identify distinct source fluid compositions for the carbonate cements within the fault damage zone. Each source fluid is associated with different carbonate precipitation temperatures, luminescence characteristics, and styles of structural deformation. Luminescent carbonates appear to be derived from meteoric waters mixing with an organic-rich or magmatic carbon source. These cements have warm precipitation temperatures and are closely associated with jointing, capitalizing on increases in permeability associated with fracturing during faulting and subsequent exhumation. Earlier-formed non-luminescent carbonates have source fluid compositions similar to marine waters, low precipitation temperatures, and are closely associated with deformation bands. The deformation bands formed at shallow depths very early in the burial history, preconditioning the rock for fracturing and associated increases in permeability. Carbonate clumped isotope temperatures allow us to associate structural and diagenetic features with burial history, revealing that structural controls on fluid distribution are established early in the evolution of the host rock and fault zone, before the onset of major displacement.

The Nahuel Niyeu basin: A Cambrian forearc basin in the eastern North Patagonian Massif

NASA Astrophysics Data System (ADS)

Greco, Gerson A.; González, Santiago N.; Sato, Ana M.; González, Pablo D.; Basei, Miguel A. S.; Llambías, Eduardo J.; Varela, Ricardo

2017-11-01

Early Paleozoic basement of the eastern North Patagonian Massif includes low- and high grade metamorphic units, which consist mainly of alternating paraderived metamorphic rocks (mostly derived from siliciclastic protoliths) with minor intercalations of orthoderived metamorphic rocks. In this contribution we provide a better understanding of the tectonic setting in which the protoliths of these units were formed, which adds to an earlier suggested idea. With this purpose, we studied the metasedimentary rocks of the low-grade Nahuel Niyeu Formation from the Aguada Cecilio area combining mapping and petrographic analysis with U-Pb geochronology and characterization of detrital zircon grains. The results and interpretations of this unit, together with published geological, geochronological and geochemical information, allow us to interpret the sedimentary and igneous protoliths of all metamorphic units from the massif as formed in a forearc basin at ∼520-510 Ma (Nahuel Niyeu basin). It probably was elongated in the ∼NW-SE direction, and would have received detritus from a proximal source area situated toward its northeastern side (present coordinates). The basin might be related to an extensional tectonic regime. Most likely source rocks were: (1) 520-510 Ma, acidic volcanic rocks (an active magmatic arc), (2) ∼555->520 Ma, acidic plutonic and volcanic rocks (earlier stages of the same arc), and (3) latest Ediacaran-Terreneuvian, paraderived metamorphic rocks (country rocks of the arc). We evaluate the Nahuel Niyeu basin considering the eastern North Patagonian Massif as an autochthonous part of South America, adding to the discussion of the origin of Patagonia.

Regional and temporal variability of melts during a Cordilleran magma pulse: Age and chemical evolution of the jurassic arc, eastern mojave desert, California

USGS Publications Warehouse

Barth, A.P.; Wooden, J.L.; Miller, David; Howard, Keith A.; Fox, Lydia; Schermer, Elizabeth R.; Jacobson, C.E.

2017-01-01

Intrusive rock sequences in the central and eastern Mojave Desert segment of the Jurassic Cordilleran arc of the western United States record regional and temporal variations in magmas generated during the second prominent pulse of Mesozoic continental arc magmatism. U/Pb zircon ages provide temporal control for describing variations in rock and zircon geochemistry that reflect differences in magma source components. These source signatures are discernible through mixing and fractionation processes associated with magma ascent and emplacement. The oldest well-dated Jurassic rocks defining initiation of the Jurassic pulse are a 183 Ma monzodiorite and a 181 Ma ignimbrite. Early to Middle Jurassic intrusive rocks comprising the main stage of magmatism include two high-K calc-alkalic groups: to the north, the deformed 183–172 Ma Fort Irwin sequence and contemporaneous rocks in the Granite and Clipper Mountains, and to the south, the 167–164 Ma Bullion sequence. A Late Jurassic suite of shoshonitic, alkali-calcic intrusive rocks, the Bristol Mountains sequence, ranges in age from 164 to 161 Ma and was emplaced as the pulse began to wane. Whole-rock and zircon trace-element geochemistry defines a compositionally coherent Jurassic arc with regional and secular variations in melt compositions. The arc evolved through the magma pulse by progressively greater input of old cratonic crust and lithospheric mantle into the arc magma system, synchronous with progressive regional crustal thickening.

An open source GIS-based tool to integrate the fragmentation mechanism in rockfall propagation

NASA Astrophysics Data System (ADS)

Matas, Gerard; Lantada, Nieves; Gili, Josep A.; Corominas, Jordi

2015-04-01

Rockfalls are frequent instability processes in road cuts, open pit mines and quarries, steep slopes and cliffs. Even though the stability of rock slopes can be determined using analytical approaches, the assessment of large rock cliffs require simplifying assumptions due to the difficulty of working with a large amount of joints, the scattering of both the orientations and strength parameters. The attitude and persistency of joints within the rock mass define the size of kinematically unstable rock volumes. Furthermore the rock block will eventually split in several fragments during its propagation downhill due its impact with the ground surface. Knowledge of the size, energy, trajectory… of each block resulting from fragmentation is critical in determining the vulnerability of buildings and protection structures. The objective of this contribution is to present a simple and open source tool to simulate the fragmentation mechanism in rockfall propagation models and in the calculation of impact energies. This tool includes common modes of motion for falling boulders based on the previous literature. The final tool is being implemented in a GIS (Geographic Information Systems) using open source Python programming. The tool under development will be simple, modular, compatible with any GIS environment, open source, able to model rockfalls phenomena correctly. It could be used in any area susceptible to rockfalls with a previous adjustment of the parameters. After the adjustment of the model parameters to a given area, a simulation could be performed to obtain maps of kinetic energy, frequency, stopping density and passing heights. This GIS-based tool and the analysis of the fragmentation laws using data collected from recent rockfall have being developed within the RockRisk Project (2014-2016). This project is funded by the Spanish Ministerio de Economía y Competitividad and entitled "Rockfalls in cliffs: risk quantification and its prevention"(BIA2013-42582-P).

Constraints on the magmatic evolution of the oceanic crust from plagiogranite intrusions in the Oman ophiolite

NASA Astrophysics Data System (ADS)

Haase, Karsten M.; Freund, Sarah; Beier, Christoph; Koepke, Jürgen; Erdmann, Martin; Hauff, Folkmar

2016-05-01

We present major and trace element as well as Sr, Nd, and Hf isotope data on a suite of 87 plutonic rock samples from 27 felsic crustal intrusions in seven blocks of the Oman ophiolite. The rock compositions of the sample suite including associated more mafic rocks range from 48 to 79 wt% SiO2, i.e. from gabbros to tonalites. The samples are grouped into a Ti-rich and relatively light rare earth element (LREE)-enriched P1 group [(Ce/Yb) N > 0.7] resembling the early V1 lavas, and a Ti-poor and LREE-depleted P2 group [(Ce/Yb) N < 0.7] resembling the late-stage V2 lavas. Based on the geochemical differences and in agreement with previous structural and petrographic models, we define phase 1 (P1) and phase 2 (P2) plutonic rocks. Felsic magmas in both groups formed by extensive fractional crystallization of olivine, clinopyroxene, plagioclase, apatite, and Ti-magnetite from mafic melts. The incompatible element compositions of P1 rocks overlap with those from mid-ocean ridges but have higher Ba/Nb and Th/Nb trending towards the P2 rock compositions and indicating an influence of a subducting slab. The P2 rocks formed from a more depleted mantle source but show a more pronounced slab signature. These rocks also occur in the southern blocks (with the exception of the Tayin block) of the Oman ophiolite implying that the entire ophiolite formed above a subducting slab. Initial Nd and Hf isotope compositions suggest an Indian-MORB-type mantle source for the Oman ophiolite magmas. Isotope compositions and high Th/Nb in some P2 rocks indicate mixing of a melt from subducted sediment into this mantle.

Attenuation Model Using the Large-N Array from the Source Physics Experiment

NASA Astrophysics Data System (ADS)

Atterholt, J.; Chen, T.; Snelson, C. M.; Mellors, R. J.

2017-12-01

The Source Physics Experiment (SPE) consists of a series of chemical explosions at the Nevada National Security Site. SPE seeks to better characterize the influence of subsurface heterogeneities on seismic wave propagation and energy dissipation from explosions. As a part of this experiment, SPE-5, a 5000 kg TNT equivalent chemical explosion, was detonated in 2016. During the SPE-5 experiment, a Large-N array of 996 geophones (half 3-component and half z-component) was deployed. This array covered an area that includes loosely consolidated alluvium (weak rock) and weathered granite (hard rock), and recorded the SPE-5 explosion as well as 53 weight drops. We use these Large-N recordings to develop an attenuation model of the area to better characterize how geologic structures influence source energy partitioning. We found a clear variation in seismic attenuation for different rock types: high attenuation (low Q) for alluvium and low attenuation (high Q) for granite. The attenuation structure correlates well with local geology, and will be incorporated into the large simulation effort of the SPE program to validate predictive models. (LA-UR-17-26382)

Estimating thermal maturity in the Eagle Ford Shale petroleum system using gas gravity data

USGS Publications Warehouse

Birdwell, Justin E.; Kinney, Scott A.

2017-01-01

Basin-wide datasets that provide information on the geochemical properties of petroleum systems, such as source rock quality, product composition, and thermal maturity, are often difficult to come by or assemble from publically available data. When published studies are available and include these kinds of properties, they generally have few sampling locations and limited numbers and types of analyses. Therefore, production-related data and engineering parameters can provide useful proxies for geochemical properties that are often widely available across a play and in some states are reported in publically available or commercial databases. Gas-oil ratios (GOR) can be calculated from instantaneous or cumulative production data and can be related to the source rock geochemical properties like kerogen type (Lewan and Henry, 1999) and thermal maturity (Tian et al., 2013; U.S. Energy Information Administration [EIA], 2014). Oil density or specific gravity (SG), often reported in American Petroleum Institute units (°API = 141.5 /SG – 131.5), can also provide information on source rock thermal maturity, particularly when combined with GOR values in unconventional petroleum systems (Nesheim, 2017).

The Kingak shale of northern Alaska-regional variations in organic geochemical properties and petroleum source rock quality

USGS Publications Warehouse

Magoon, L.B.; Claypool, G.E.

1984-01-01

The Kingak Shale, a thick widespread rock unit in northern Alaska that ranges in age from Early Jurassic through Early Cretaceous, has adequate to good oil source rock potential. This lenticular-shaped rock unit is as much as 1200 m thick near the Jurassic shelf edge, where its present-day burial depth is about 5000 m. Kingak sediment, transported in a southerly direction, was deposited on the then marine continental shelf. The rock unit is predominantly dark gray Shale with some interbeds of thick sandstone and siltstone. The thermal maturity of organic matter in the Kingak Shale ranges from immature (2.0%R0) in the Colville basin toward the south. Its organic carbon and hydrogen contents are highest in the eastern part of northern Alaska south of and around the Kuparuk and Prudhoe Bay oil fields. Carbon isotope data of oils and rock extracts indicate that the Kingak Shale is a source of some North Slope oil, but is probably not the major source. ?? 1984.

System and method for investigating sub-surface features and 3D imaging of non-linear property, compressional velocity VP, shear velocity VS and velocity ratio VP/VS of a rock formation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vu, Cung Khac; Skelt, Christopher; Nihei, Kurt

A system and a method for generating a three-dimensional image of a rock formation, compressional velocity VP, shear velocity VS and velocity ratio VP/VS of a rock formation are provided. A first acoustic signal includes a first plurality of pulses. A second acoustic signal from a second source includes a second plurality of pulses. A detected signal returning to the borehole includes a signal generated by a non-linear mixing process from the first and second acoustic signals in a non-linear mixing zone within an intersection volume. The received signal is processed to extract the signal over noise and/or signals resultingmore » from linear interaction and the three dimensional image of is generated.« less

Detailed Aggregate Resources Study, Dry Lake Valley, Nevada.

DTIC Science & Technology

1981-05-29

LOCAL SAND SOURCES IGENERALLY CYLINDERS. DRYING SHRINKAGE I COLLECTED WITHIN A FEW MILES OF CORRESPONDING LEDGE-ROCK SOURCES) SUPPLIED FINE MENS...COMPRESSIVE AND TENSILE STh LEDGE-ROCK SOURCES SUPPLIED COARSE AGGREGATES; LOCAL SAND SOURCES IGENERALLY CYLINDERS. DRYING SHRINKAGE COLLECTED WITHIN A FEW

Subducted slab-plume interaction traced by magnesium isotopes in the northern margin of the Tarim Large Igneous Province

NASA Astrophysics Data System (ADS)

Cheng, Zhiguo; Zhang, Zhaochong; Xie, Qiuhong; Hou, Tong; Ke, Shan

2018-05-01

Incorporation of subducted slabs may account for the geochemical and isotopic variations of large igneous provinces (LIPs). However, the mechanism and process by which subducted slabs are involved into magmas is still highly debated. Here, we report a set of high resolution Mg isotopes for a suite of alkaline and Fe-rich rocks (including basalts, mafic-ultramafic layered intrusions, diabase dykes and mantle xenoliths in the kimberlitic rocks) from Tarim Large Igneous Province (TLIP). We observed that δ26 Mg values of basalts range from -0.29 to - 0.45 ‰, -0.31 to - 0.42 ‰ for mafic-ultramafic layered intrusions, -0.28 to - 0.31 ‰ for diabase dykes and -0.29 to - 0.44 ‰ for pyroxenite xenoliths from the kimberlitic rocks, typically lighter than the normal mantle source (- 0.25 ‰ ± 0.04, 2 SD). After carefully precluding other possibilities, we propose that the light Mg isotopic compositions and high FeO contents should be ascribed to the involvement of recycled sedimentary carbonate rocks and pyroxenite/eclogite. Moreover, from basalts, through layered intrusions to diabase dykes, (87Sr/86Sr)i values and δ18OV-SMOW declined, whereas ε (Nd) t and δ26 Mg values increased with progressive partial melting of mantle, indicating that components of carbonate rock and pyroxenite/eclogite in the mantle sources were waning over time. In combination with the previous reported Mg isotopes for carbonatite, nephelinite and kimberlitic rocks in TLIP, two distinct mantle domains are recognized for this province: 1) a lithospheric mantle source for basalts and mafic-ultramafic layered intrusions which were modified by calcite/dolomite and eclogite-derived high-Si melts, as evidenced by enriched Sr-Nd-O and light Mg isotopic compositions; 2) a plume source for carbonatite, nephelinite and kimberlitic rocks which were related to magnesite or periclase/perovskite involvement as reflected by depleted Sr-Nd-O and extremely light Mg isotopes. Ultimately, our study suggests that subducted slabs could make important contributions to LIP generation, and establishes a potential linkage between plate tectonics and mantle plume.

Apollo Lunar Sample Integration into Google Moon: A New Approach to Digitization

NASA Technical Reports Server (NTRS)

Dawson, Melissa D.; Todd, nancy S.; Lofgren, Gary E.

2011-01-01

The Google Moon Apollo Lunar Sample Data Integration project is part of a larger, LASER-funded 4-year lunar rock photo restoration project by NASA s Acquisition and Curation Office [1]. The objective of this project is to enhance the Apollo mission data already available on Google Moon with information about the lunar samples collected during the Apollo missions. To this end, we have combined rock sample data from various sources, including Curation databases, mission documentation and lunar sample catalogs, with newly available digital photography of rock samples to create a user-friendly, interactive tool for learning about the Apollo Moon samples

Detrital rutile geochemistry and thermometry from the Dabie orogen: Implications for source-sediment links in a UHPM terrane

NASA Astrophysics Data System (ADS)

Liu, Lei; Xiao, Yilin; Wörner, G.; Kronz, A.; Simon, K.; Hou, Zhenhui

2014-08-01

This study explores the potential of detrital rutile geochemistry and thermometry as a provenance tracer in rocks from the Central Dabie ultrahigh-pressure metamorphic (UHPM) zone in east-central China that formed during Triassic continental collision. Trace element data of 176 detrital rutile grains selected from local river sediments and 91 rutile grains from distinct bedrocks in the Shuanghe and Bixiling areas, obtained by both electron microprobe (EMP) and in situ LA-ICP-MS analyses, suggest that geochemical compositions and thermometry of detrital rutiles are comparable to those from their potential source rocks. After certification of the Cr-Nb discrimination method for the Central Dabie UHPM zone, we show that 29% of the detrital rutiles in the Shuanghe area were derived from metamafic sources whereas in the Bixiling area that it is up to 76%. Furthermore, the proportion of distinct types of detrital rutiles combined with modal abundances of rutile in metapelites and metamafic bedrocks can be used to estimate the proportion of different source lithologies. Based on this method the proportion of mafic source rocks was estimated to ∼10% at Shuanghe and >60% at Bixiling, respectively, which is consistent with the proportions of eclogite (the major rutile-bearing metamafic rock) distribution in the field. Therefore, the investigation of detrital rutiles is a potential way to evaluate the proportion of metamafic rocks and even to prospect for metamafic bodies in UHPM terranes. Zr-in-rutile temperatures were calculated at different pressures and compared with temperatures derived from rock-in rutiles and garnet-clinopyroxene Fe-Mg thermometers. Temperatures calculated for detrital rutiles range from 606 °C to 707 °C and 566 °C to 752 °C in Shuanghe and Bixiling, respectively, at P = 3 GPa with an average temperatures of ca. 630 °C for both areas. These temperature averages and ranges are similar to those calculated for rutiles from surrounding source rocks. Combined with comparable Zr distribution characteristics between detrital and source rock rutiles, demonstrating a close source-sediment link for rutiles from clastic and rock in UHPM terranes. Thus rutiles can be accurate tracers of source rock lithologies in sedimentary provenance studies even at a small regional scale. In Bixiling, Nb/Ta ratios of metamafic and metapelitic detrital rutiles fall between 11.0 to 27.3 and 7.7 to 20.5, respectively. In contrast, in Shuanghe, these ratios are highly variable, ranging from 10.9 to 71.0 and 7.6 to 87.1, respectively. When ignoring four outlier compositions with extremely high Nb/Ta in Shuanghe, a distinct clustering of Nb/Ta ratios in rutiles is shown: metapelitic detrital rutiles have Nb/Ta of 7-40 vs. metamafic detrital rutiles with Nb/Ta = 11-25. The Nb/Ta characteristics in detrital rutiles from both areas may reflect the degree of fluid-rock interaction during metamorphism and/or different source lithologies. Therefore, the trace element compositions in detrital rutiles can accurately trace the lithology, proportion and fluid-rock interaction of different source rocks.

A comparison of the rates of hydrocarbon generation from Lodgepole, False Bakken, and Bakken formation petroleum source rocks, Williston Basin, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jarvie, D.M.; Elsinger, R.J.; Inden, R.F.

1996-06-01

Recent successes in the Lodgepole Waulsortian Mound play have resulted in the reevaluation of the Williston Basin petroleum systems. It has been postulated that hydrocarbons were generated from organic-rich Bakken Formation source rocks in the Williston Basin. However, Canadian geoscientists have indicated that the Lodgepole Formation is responsible for oil entrapped in Lodgepole Formation and other Madison traps in portions of the Canadian Williston Basin. Furthermore, geoscientists in the U.S. have recently shown oils from mid-Madison conventional reservoirs in the U.S. Williston Basin were not derived from Bakken Formation source rocks. Kinetic data showing the rate of hydrocarbon formation frommore » petroleum source rocks were measured on source rocks from the Lodgepole, False Bakken, and Bakken Formations. These results show a wide range of values in the rate of hydrocarbon generation. Oil prone facies within the Lodgepole Formation tend to generate hydrocarbons earlier than the oil prone facies in the Bakken Formation and mixed oil/gas prone and gas prone facies in the Lodgepole Formation. A comparison of these source rocks using a geological model of hydrocarbon generation reveals differences in the timing of generation and the required level of maturity to generate significant amounts of hydrocarbons.« less

Shale characterization in mass transport complex as a potential source rock: An example from onshore West Java Basin, Indonesia

NASA Astrophysics Data System (ADS)

Nugraha, A. M. S.; Widiarti, R.; Kusumah, E. P.

2017-12-01

This study describes a deep-water slump facies shale of the Early Miocene Jatiluhur/Cibulakan Formation to understand its potential as a source rock in an active tectonic region, the onshore West Java. The formation is equivalent with the Gumai Formation, which has been well-known as another prolific source rock besides the Oligocene Talang Akar Formation in North West Java Basin, Indonesia. The equivalent shale formation is expected to have same potential source rock towards the onshore of Central Java. The shale samples were taken onshore, 150 km away from the basin. The shale must be rich of organic matter, have good quality of kerogen, and thermally matured to be categorized as a potential source rock. Investigations from petrography, X-Ray diffractions (XRD), and backscattered electron show heterogeneous mineralogy in the shales. The mineralogy consists of clay minerals, minor quartz, muscovite, calcite, chlorite, clinopyroxene, and other weathered minerals. This composition makes the shale more brittle. Scanning Electron Microscope (SEM) analysis indicate secondary porosities and microstructures. Total Organic Carbon (TOC) shows 0.8-1.1 wt%, compared to the basinal shale 1.5-8 wt%. The shale properties from this outcropped formation indicate a good potential source rock that can be found in the subsurface area with better quality and maturity.

Geologic Assessment of Undiscovered, Technically Recoverable Coalbed-Gas Resources in Cretaceous and Tertiary Rocks, North Slope and Adjacent State Waters, Alaska

USGS Publications Warehouse

Roberts, Stephen B.

2008-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered, technically recoverable coalbed-gas resources in Cretaceous and Tertiary rocks underlying the North Slope and adjacent State waters of Alaska (USGS Northern Alaska Province 5001). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Northern Alaska Province, the USGS used this geologic framework to define one composite coalbed gas total petroleum system and three coalbed gas assessment units within the petroleum system, and quantitatively estimated the undiscovered coalbed-gas resources within each assessment unit.

Geologic map of the Valdez D-1 and D-2 quadrangles (Mount Wrangell Volcano), Alaska

USGS Publications Warehouse

Richter, D.H.; McGimsey, R.G.; Labay, Keith A.; Lanphere, M.A.; Moore, R.B.; Nye, C.J.; Rosenkrans, D.S.; Winkler, G.R.

2016-04-29

This study was directed toward Mount Wrangell volcano and the older Wrangell volcanic field rocks that underlie the volcano. These older lavas include the Chetaslina lavas (867 ka–1,650 ka) and a basaltic andesite–dacite center (1,590 ka–1,640 ka) whose source areas are not well defined. Older Paleozoic and Mesozoic sedimentary, igneous, and metamorphic rocks of the Wrangellia terrane underlie the entire Wrangell volcanic field.

Total petroleum systems of the Pelagian Province, Tunisia, Libya, Italy, and Malta; the Bou Dabbous, Tertiary and Jurassic-Cretaceous composite

USGS Publications Warehouse

Klett, T.R.

2001-01-01

Undiscovered conventional oil and gas resources were assessed within total petroleum systems of the Pelagian Province (2048) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Pelagian Province is located mainly in eastern Tunisia and northwestern Libya. Small portions of the province extend into Malta and offshore Italy. Although several petroleum systems may exist, only two ?composite? total petroleum systems were identified. Each total petroleum system comprises a single assessment unit. These total petroleum systems are called the Bou Dabbous?Tertiary and Jurassic-Cretaceous Composite, named after the source-rock intervals and reservoir-rock ages. The main source rocks include mudstone of the Eocene Bou Dabbous Formation; Cretaceous Bahloul, Lower Fahdene, and M?Cherga Formations; and Jurassic Nara Formation. Known reservoirs are in carbonate rocks and sandstone intervals throughout the Upper Jurassic, Cretaceous, and Tertiary sections. Traps for known accumulations include fault blocks, low-amplitude anticlines, high-amplitude anticlines associated with reverse faults, wrench fault structures, and stratigraphic traps. The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Pelagian Province are as follows: [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids] Total Petroleum System MMBO BCFG MMBNGL Bou Dabbous?Tertiary 667 2,746 64 Jurassic-Cretaceous Composite 403 2,280 27

Oils and hydrocarbon source rocks of the Baltic syneclise

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kanev, S.; Margulis, L.; Bojesen-Koefoed, J.A.

Prolific source rock horizons of varying thickness, having considerable areal extent, occur over the Baltic syneclise. These source sediments are rich and have excellent petroleum generation potential. Their state of thermal maturity varies form immature in the northeastern part of the syneclise to peak generation maturity in the southwestern part of the region-the main kitchen area. These maturity variations are manifest in petroleum composition in the region. Hence, mature oils occur in the Polish and Kaliningrad areas, immature oils in small accumulations in Latvian and central Lithuanian onshore areas, and intermediate oils in areas between these extremes. The oil accumulationsmore » probably result from pooling of petroleum generated from a number of different source rocks at varying levels of thermal maturity. Hence, no single source for petroleum occurrences in the Baltic syneclise may be identified. The paper describes the baltic syneclise, source rocks, thermal maturity and oils and extracts.« less

Kerogen maturation and incipient graphitization of hydrocarbon source rocks in the Arkoma Basin, Oklahoma and Arkansas: A combined petrographic and Raman spectrometric study

USGS Publications Warehouse

Spotl, C.; Houseknecht, D.W.; Jaques, R.C.

1998-01-01

Dispersed kerogen of the Woodford-Chattanooga and Atoka Formations from the subsurface of the Arkoma Basin show a wide range of thermal maturities (0.38 to 6.1% R(o)) indicating thermal conditions ranging from diagenesis to incipient rock metamorphism. Raman spectral analysis reveals systematic changes of both the first- and second-order spectrum with increasing thermal maturity. These changes include a pronounced increase in the D/O peak height ratio accompanied by a narrowing of the D peak, a gradual decrease in the D/O peak width ratio, and a shift of both peaks toward higher wave numbers. Second-order Raman peaks, though less intensive, also show systematic peak shifting as a function of R(o). These empirical results underscore the high potential of Raman spectrometry as a fast and reliable geothermometer of mature to supermature hydrocarbon source rocks, and as an indicator of thermal maturity levels within the anchizone.Dispersed kerogen of the Woodford-Chattanooga and Atoka Formations from the subsurface of the Arkoma Basin show a wide range of thermal maturities (0.38 to 6.1% Ro) indicating thermal conditions ranging from diagenesis to incipient rock metamorphism. Raman spectral analysis reveals systematic changes of both the first- and second-order spectrum with increasing thermal maturity. These changes include a pronounced increase in the D/O peak height ratio accompanied by a narrowing of the D peak, a gradual decrease in the D/O peak width ratio, and a shift of both peaks toward higher wave numbers. Second-order Raman peaks, though less intensive, also show systematic peak shifting as a function of Ro. These empirical results underscore the high potential of Raman spectrometry as a fast and reliable geothermometer of mature to supermature hydrocarbon source rocks, and as an indicator of thermal maturity levels within the anchizone.

Burial history, thermal maturity, and oil and gas generation history of petroleum systems in the Wind River Basin Province, central Wyoming: Chapter 6 in Petroleum systems and geologic assessment of oil and gas resources in the Wind River Basin Province, Wyoming

USGS Publications Warehouse

Roberts, Laura N.R.; Finn, Thomas M.; Lewan, Michael D.; Kirschbaum, Mark A.

2007-01-01

Burial history, thermal maturity, and timing of oil and gas generation were modeled for eight key source rock units at nine well locations throughout the Wind River Basin Province. Petroleum source rocks include the Permian Phosphoria Formation, the Cretaceous Mowry Shale, Cody Shale, and Mesaverde, Meeteetse, and Lance Formations, and the Tertiary (Paleocene) Fort Union Formation, including the Waltman Shale Member. Within the province boundary, the Phosphoria is thin and only locally rich in organic carbon. Phosphoria oil produced from reservoirs in the province is thought to have migrated from the Wyoming and Idaho thrust belt. Locations (wells) selected for burial history reconstructions include three in the deepest parts of the province (Adams OAB-17, Bighorn 1-5, and Coastal Owl Creek); three at intermediate depths (Hells Half Acre, Shell 33X-10, and West Poison Spider); and three at relatively shallow locations (Young Ranch, Amoco Unit 100, and Conoco-Coal Bank). The thermal maturity of source rocks is greatest in the deep northern and central parts of the province and decreases to the south and east toward the basin margins. The results of the modeling indicate that, in the deepest areas, (1) peak petroleum generation from Cretaceous rocks occurred from Late Cretaceous through middle Eocene time, and (2) onset of oil generation from the Waltman Shale Member occurred from late Eocene to early Miocene time. Based on modeling results, gas generation from the cracking of Phosphoria oil reservoired in the Park City Formation reached a peak in the late Paleocene/early Eocene (58 to 55 Ma) only in the deepest parts of the province. The Mowry Shale and Cody Shale (in the eastern half of the basin) contain a mix of Type-II and Type-III kerogens. Oil generation from predominantly Type-II source rocks of these units in the deepest parts of the province reached peak rates during the latest Cretaceous to early Eocene (65 to 55 Ma). Only in these areas of the basin did these units reach peak gas generation from the cracking of oil, which occurred in the early to middle Eocene (55 to 42 Ma). Gas-prone source rocks of the Mowry and Cody Shales (predominantly Type-III kerogen), and the Mesaverde, Meeteetse, Lance, and Fort Union Formations (Type –III kerogen) reached peak gas generation in the latest Cretaceous to late Eocene (67 to 38 Ma) in the deepest parts of the province. Gas generation from the Mesaverde source rocks started at all of the modeled locations but reached peak generation at only the deepest locations and at the Hells Half Acre location in the middle Paleocene to early Eocene (59 to 48 Ma). Also at the deepest locations, peak gas generation occurred from the late Paleocene to the early Eocene (57 to 49 Ma) for the Meeteetse Formation, and during the Eocene for the Lance Formation (55 to 48 Ma) and the Fort Union Formation (44 to 38 Ma). The Waltman Shale Member of the Fort Union Formation contains Type-II kerogen. The base of the Waltman reached a level of thermal maturity to generate oil only at the deep-basin locations (Adams OAB-17 and Bighorn 1-5 locations) in the middle Eocene to early Miocene (36 to 20 Ma).

Integrated system for investigating sub-surface features of a rock formation

DOEpatents

Vu, Cung Khac; Skelt, Christopher; Nihei, Kurt; Johnson, Paul A.; Guyer, Robert; Ten Cate, James A.; Le Bas, Pierre -Yves; Larmat, Carene S.

2015-08-18

A system for investigating non-linear properties of a rock formation around a borehole is provided. The system includes a first sub-system configured to perform data acquisition, control and recording of data; a second subsystem in communication with the first sub-system and configured to perform non-linearity and velocity preliminary imaging; a third subsystem in communication with the first subsystem and configured to emit controlled acoustic broadcasts and receive acoustic energy; a fourth subsystem in communication with the first subsystem and the third subsystem and configured to generate a source signal directed towards the rock formation; and a fifth subsystem in communication with the third subsystem and the fourth subsystem and configured to perform detection of signals representative of the non-linear properties of the rock formation.

Hydrocarbon source potential of the Tanezzuft Formation, Murzuq Basin, south-west Libya: An organic geochemical approach

NASA Astrophysics Data System (ADS)

El Diasty, W. Sh.; El Beialy, S. Y.; Anwari, T. A.; Batten, D. J.

2017-06-01

A detailed organic geochemical study of 20 core and cuttings samples collected from the Silurian Tanezzuft Formation, Murzuq Basin, in the south-western part of Libya has demonstrated the advantages of pyrolysis geochemical methods for evaluating the source-rock potential of this geological unit. Rock-Eval pyrolysis results indicate a wide variation in source richness and quality. The basal Hot Shale samples proved to contain abundant immature to early mature kerogen type II/III (oil-gas prone) that had been deposited in a marine environment under terrigenous influence, implying good to excellent source rocks. Strata above the Hot Shale yielded a mixture of terrigenous and marine type III/II kerogen (gas-oil prone) at the same maturity level as the Hot Shale, indicating the presence of only poor to fair source rocks.

Mass Dependent Fractionation of Hg Isotopes in Source Rocks, Mineral Deposits and Spring Waters of the California Coast Ranges, USA

NASA Astrophysics Data System (ADS)

Smith, C. N.; Kesler, S. E.; Blum, J. D.; Rytuba, J. J.

2007-12-01

We present here the first study of the isotopic composition of Hg in rocks, ore deposits, and active hydrothermal systems from the California Coast Ranges, one of Earth's largest Hg-depositing systems. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of Hg deposits, hot-spring deposits that form at shallow depths (<300 m) and silica-carbonate deposits that extend to greater depths (200 to 1000 m), as well as active springs and geothermal systems that release Hg to the present surface. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of Hg than volcanic rocks of the Clear Lake Volcanic Field. Mean Hg isotope compositions for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate Hg deposits have similar average isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the Hg deposits have a greater variance than the country rocks. Precipitates from dilute spring and saline thermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate there is little or no isotopic fractionation during release of Hg from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of Hg in deposits, especially in their uppermost parts. Boiling of hydrothermal fluids is likely the most important process causing of the observed Hg isotope fractionation. This should result in the release of Hg with low δ202Hg values into the atmosphere from the top of these hydrothermal systems and a consequent enrichment in heavy Hg isotopes in the upper crust through time.

Petroleum source potential of the Lower Cretaceous mudstone succession of the NPRA and Colville Delta area, North Slope Alaska, based on sonic and resistivity logs

USGS Publications Warehouse

Keller, Margaret A.; Bird, Kenneth J.

2003-01-01

Resource assessment of the North Slope of Alaska by the U. S. Geological Survey includes evaluation of the petroleum source potential of Mesozoic and Cenozoic rocks using the delta log R technique (Passey and others, 1990). Porosity and resistivity logs are used in combination with thermal maturity data to produce a continuous profile of total organic carbon content in weight % (TOC). From the pattern and amount of TOC in the profile produced, the depositional setting and thus the petroleum source-rock potential (kerogen type) of the organic matter can be inferred and compared to interpretations from other data such as Rock-Eval pyrolysis. TOC profiles determined by this technique for the contiguous interval of pebble shale unit, Hue Shale (including the Gamma Ray Zone or GRZ), and lower part of the Torok Formation indicate important potential for petroleum generation in the Tunalik 1, Inigok 1, N. Inigok 1, Kuyanak 1, Texaco Colville Delta 1, Nechelik 1, and Bergschrund 1 wells of the western North Slope region. TOC profiles suggest that this interval contains both type II and III kerogens – consistent with proposed depositional models -- and is predominantly greater than 2 wt. % TOC (cut-off used for effective source potential). Average TOC for the total effective section of the pebble shale unit + Hue Shale ranges from 2.6 to 4.1 wt % TOC (values predominantly 2-8% TOC) over 192-352 ft. Source potential for the lower Torok Formation, which also has interbedded sandstone and lean mudstone, is good to negligible in these 7 wells.

Insight into subdecimeter fracturing processes during hydraulic fracture experiment in Äspö hard rock laboratory, Sweden

NASA Astrophysics Data System (ADS)

Kwiatek, Grzegorz; Martínez-Garzón, Patricia; Plenkers, Katrin; Leonhardt, Maria; Zang, Arno; Dresen, Georg; Bohnhoff, Marco

2017-04-01

We analyze the nano- and picoseismicity recorded during a hydraulic fracturing in-situ experiment performed in Äspö Hard Rock Laboratory, Sweden. The fracturing experiment included six fracture stages driven by three different water injection schemes (continuous, progressive and pulse pressurization) and was performed inside a 28 m long, horizontal borehole located at 410 m depth. The fracturing process was monitored with two different seismic networks covering a wide frequency band between 0.01 Hz and 100000 Hz and included broadband seismometers, geophones, high-frequency accelerometers and acoustic emission sensors. The combined seismic network allowed for detection and detailed analysis of seismicity with moment magnitudes MW<-4 (source sizes approx. on cm scale) that occurred solely during the hydraulic fracturing and refracturing stages. We relocated the seismicity catalog using the double-difference technique and calculated the source parameters (seismic moment, source size, stress drop, focal mechanism and seismic moment tensors). The physical characteristics of induced seismicity are compared to the stimulation parameters and to the formation parameters of the site. The seismic activity varies significantly depending on stimulation strategy with conventional, continuous stimulation being the most seismogenic. We find a systematic spatio-temporal migration of microseismic events (propagation away and towards wellbore injection interval) and temporal transitions in source mechanisms (opening - shearing - collapse) both being controlled by changes in fluid injection pressure. The derived focal mechanism parameters are in accordance with the local stress field orientation, and signify the reactivation of pre-existing rock flaws. The seismicity follows statistical and source scaling relations observed at different scales elsewhere, however, at an extremely low level of seismic efficiency.

Rock-Eval pyrolysis and vitrinite reflectance results from the Sheep Creek 1 well, Susitna basin, south-central Alaska

USGS Publications Warehouse

Stanley, Richard G.; Lillis, Paul G.; Pawlewicz, Mark J.; Haeussler, Peter J.

2014-01-01

We used Rock-Eval pyrolysis and vitrinite reflectance to examine the petroleum source potential of rock samples from the Sheep Creek 1 well in the Susitna basin of south-central Alaska. The results show that Miocene nonmarine coal, carbonaceous shale, and mudstone are potential sources of hydrocarbons and are thermally immature with respect to the oil window. In the samples that we studied, coals are more organic-rich and more oil-prone than carbonaceous shales and silty mudstones, which appear to be potential sources of natural gas. Lithologically similar rocks may be present in the deeper parts of the subsurface Susitna basin located west of the Sheep Creek 1 well, where they may have been buried deeply enough to generate oil and (or) gas. The Susitna basin is sparsely drilled and mostly unexplored, and no commercial production of hydrocarbons has been obtained. However, the existence of potential source rocks of oil and gas, as shown by our Rock-Eval results, suggests that undiscovered petroleum accumulations may be present in the Susitna basin.

Petrology and geochemistry of mafic magmatic rocks from the Sarve-Abad ophiolites (Kurdistan region, Iran): Evidence for interaction between MORB-type asthenosphere and OIB-type components in the southern Neo-Tethys Ocean

NASA Astrophysics Data System (ADS)

Saccani, Emilio; Allahyari, Khalil; Rahimzadeh, Bahman

2014-05-01

The Sarve-Abad (Sawlava) ophiolites crop out in the Main Zagros Thrust Zone and represent remnants of the Mesozoic southern Neo-Tethys Ocean that was located between the Arabian shield and Sanandaj-Sirjan continental block. They consist of several incomplete ophiolitic sequences including gabbroic bodies, a dyke complex, and pillow lava sequences. These rocks generally range from sub-alkaline to transitional character. Mineral chemistry and whole-rock geochemistry indicate that they have compositions akin to enriched-type mid-ocean ridge basalts (E-MORB) and plume-type MORB (P-MORB). Nonetheless, the different depletion degrees in heavy rare earth elements (HREE), which can be observed in both E-MORB like and P-MORB like rocks enable two main basic chemical types of rocks to be distinguished as Type-I and Type-II. Type-I rocks are strongly depleted in HREE (YbN < ~ 6), whereas Type-II rocks are moderately depleted in HREE (YbN > 9.0). Petrogenetic modeling shows that Type-I rocks originated from 7 to 16% polybaric partial melting of a MORB-type mantle source, which was significantly enriched by plume-type components. These rocks resulted from the mixing of variable fractions of melts generated in garnet-facies and the spinel-facies mantle. In contrast, Type-II rocks originated from 5 to 8% partial melting in the spinel-facies of a MORB-type source, which was moderately enriched by plume-type components. A possible tectono-magmatic model for the generation of the southern Neo-Tethys oceanic crust implies that the continental rift and subsequent oceanic spreading were associated with uprising of MORB-type asthenospheric mantle featuring plume-type component influences decreasing from deep to shallow mantle levels. These deep plume-type components were most likely inherited from Carboniferous mantle plume activity that was associated with the opening of Paleo-Tethys in the same area.

Coal-rock interface detector

NASA Technical Reports Server (NTRS)

Rose, S. D.; Crouch, C. E.; Jones, E. W. (Inventor)

1979-01-01

A coal-rock interface detector is presented which employs a radioactive source and radiation sensor. The source and sensor are separately and independently suspended and positioned against a mine surface of hydraulic pistons, which are biased from an air cushioned source of pressurized hydraulic fluid.

Studying physical properties of deformed intact and fractured rocks by micro-scale hydro-mechanical-seismicity model

NASA Astrophysics Data System (ADS)

Raziperchikolaee, Samin

The pore pressure variation in an underground formation during hydraulic stimulation of low permeability formations or CO2 sequestration into saline aquifers can induce microseismicity due to fracture generation or pre-existing fracture activation. While the analysis of microseismic data mainly focuses on mapping the location of fractures, the seismic waves generated by the microseismic events also contain information for understanding of fracture mechanisms based on microseismic source analysis. We developed a micro-scale geomechanics, fluid-flow and seismic model that can predict transport and seismic source behavior during rock failure. This model features the incorporation of microseismic source analysis in fractured and intact rock transport properties during possible rock damage and failure. The modeling method considers comprehensive grains and cements interaction through a bonded-particle-model. As a result of grain deformation and microcrack development in the rock sample, forces and displacements in the grains involved in the bond breakage are measured to determine seismic moment tensor. In addition, geometric description of the complex pore structure is regenerated to predict fluid flow behavior of fractured samples. Numerical experiments are conducted for different intact and fractured digital rock samples, representing various mechanical behaviors of rocks and fracture surface properties, to consider their roles on seismic and transport properties of rocks during deformation. Studying rock deformation in detail provides an opportunity to understand the relationship between source mechanism of microseismic events and transport properties of damaged rocks to have a better characterizing of fluid flow behavior in subsurface formations.

Post-collisional magmatism in the Late Miocene Rodna-Bârgău district (East Carpathians, Romania): Geochemical constraints and petrogenetic models

NASA Astrophysics Data System (ADS)

Fedele, Lorenzo; Seghedi, Ioan; Chung, Sun-Lin; Laiena, Fabio; Lin, Te-Hsien; Morra, Vincenzo; Lustrino, Michele

2016-12-01

Post-collisional magmatism in the Late Miocene Rodna-Bârgău subvolcanic district (East Carpathians) gave rise to a wide variety of rock compositions, allowing recognition of four groups of calcalkaline rocks with distinctive petrography, mineral chemistry, whole-rock geochemistry and Sr-Nd-Hf isotope features. New U-Pb zircon datings, together with literature data, indicate that the emplacement of the four rock groups was basically contemporaneous in the 11.5-8 Ma time span. The low potassium group (LKG) includes the most abundant lithotypes of the area, ranging from basaltic andesite to dacite, characterized by K-poor tschermakitic amphibole, weak enrichment in LILE and LREE, relatively low 87Sr/86Sr, coupled with relatively high 143Nd/144Nd and 176Hf/177Hf. The high potassium group (HKG) includes amphibole-bearing microgabbro, amphibole andesite and amphibole- and biotite dacite, with K-richer magnesio-hastingsite to hastingsite amphibole, more marked enrichments in incompatible elements, higher 87Sr/86Sr and lower 143Nd/144Nd and 176Hf/177Hf. These two main rock groups seem to have originated from similar juxtaposed mantle sources, with the HKG possibly related to slightly more enriched domains (with higher H2O reflected by the higher modal amphibole) with respect to LKG (with higher plagioclase/amphibole ratios). The evolution of the two rock series involved also open-system processes, taking place mainly in the upper crust for the HKG, in the lower crust for LKG magmas. In addition, limited occurrences of generally younger strongly evolved peraluminous rhyolites and microgranites (Acid group) and sialic-dominated "leucocratic" andesites and dacites (LAD group) were also recognized to the opposite outermost areas of the district. These two latter rock groups were generated by the melting of a basic metamorphic crustal source (respectively in hydrous and anhydrous conditions), favored by the heat released by mantle melts from the adjoining central area. The peculiar distribution of the products of the four rock groups in well defined sectors argues for a strong control of the local crustal tectonic regime on magmatism, influenced by the change from a transpressional to trastensional stage.

Shale: an overlooked option for US nuclear waste disposal

USGS Publications Warehouse

Neuzil, Christopher E.

2014-01-01

Toss a dart at a map of the United States and, more often than not, it will land where shale can be found underground. A drab, relatively featureless sedimentary rock that historically attracted little interest, shale (as used here, the term includes clay and a range of clay-rich rocks) is entering Americans’ consciousness as a new source of gas and oil. But shale may also offer something entirely different—the ability to safely and permanently house high-level nuclear waste.

Kaersutite-bearing xenoliths and megacrysts in volcanic rocks from the Funk Seamount in the souhtwest Indian Ocean

NASA Technical Reports Server (NTRS)

Reid, Arch M.; Le Roex, Anton P.

1988-01-01

The petrography, mineral chemistry, and whole-rock compositions of volcanic rocks dredged from the Funk Seamount, located 60 km NW of Marion Island in the southwestern Indian Ocean, are presented together with the mineral chemistry of their inclusions. On the basis of these characteristics, the possible relationships between the Funk Seamount's volcanic rocks and the megacrysts and xenoliths in these rocks are discussed. It is argued that the Funk Seamount lavas derive from a similar mantle source region as that of the Marion Island and Prince Edward Island hotspot lavas. The geochemical signature of these lavas implies derivation from a source that is enriched (e.g., in Ti, K, P, and Nb) over the depleted mantle source regions for the adjacent mid-ocean ridge basalts.

Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

USGS Publications Warehouse

Unruh, Daniel M.; Lund, Karen; Kuntz, Mel A.; Snee, Lawrence W.

2008-01-01

Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

Mapping the petroleum system - An investigative technique to explore the hydrocarbon fluid system

USGS Publications Warehouse

Magoon, L.B.; Dow, W.G.

2000-01-01

Creating a petroleum system map includes a series of logical steps that require specific information to explain the origin in time and space of discovered hydrocarbon occurrences. If used creatively, this map provides a basis on which to develop complementary plays and prospects. The logical steps include the characterization of a petroleum system (that is, to identify, map, and name the hydrocarbon fluid system) and the summary of these results on a folio sheet. A petroleum system map is based on the understanding that there are several levels of certainty from "guessing" to "knowing" that specific oil and gas accumulations emanated from a particular pod of active source rock. Levels of certainty start with the close geographic proximity of two or more accumulations, continues with the close stratigraphic proximity, followed by the similarities in bulk properties, and then detailed geochemical properties. The highest level of certainty includes the positive geochemical correlation of the hydrocarbon fluid in the accumulations to the extract of the active source rock. A petroleum system map is created when the following logic is implemented. Implementation starts when the oil and gas accumulations of a petroleum province are grouped stratigraphically and geographically. Bulk and geochemical properties are used to further refine the groups through the determination of genetically related oil and gas types. To this basic map, surface seeps and well shows are added. Similarly, the active source rock responsible for these hydrocarbon occurrences are mapped to further define the extent of the system. A folio sheet constructed for a hypothetical case study of the Deer-Boar(.) petroleum system illustrates this methodology.

Unconventional shallow biogenic gas systems

USGS Publications Warehouse

Shurr, G.W.; Ridgley, J.L.

2002-01-01

Unconventional shallow biogenic gas falls into two distinct systems that have different attributes. Early-generation systems have blanketlike geometries, and gas generation begins soon after deposition of reservoir and source rocks. Late-generation systems have ringlike geometries, and long time intervals separate deposition of reservoir and source rocks from gas generation. For both types of systems, the gas is dominantly methane and is associated with source rocks that are not thermally mature. Early-generation biogenic gas systems are typified by production from low-permeability Cretaceous rocks in the northern Great Plains of Alberta, Saskatchewan, and Montana. The main area of production is on the southeastern margin of the Alberta basin and the northwestern margin of the Williston basin. The huge volume of Cretaceous rocks has a generalized regional pattern of thick, non-marine, coarse clastics to the west and thinner, finer grained marine lithologies to the east. Reservoir rocks in the lower part tend to be finer grained and have lower porosity and permeability than those in the upper part. Similarly, source beds in the units have higher values of total organic carbon. Patterns of erosion, deposition, deformation, and production in both the upper and lower units are related to the geometry of lineament-bounded basement blocks. Geochemical studies show that gas and coproduced water are in equilibrium and that the fluids are relatively old, namely, as much as 66 Ma. Other examples of early-generation systems include Cretaceous clastic reservoirs on the southwestern margin of Williston basin and chalks on the eastern margin of the Denver basin. Late-generation biogenic gas systems have as an archetype the Devonian Antrim Shale on the northern margin of the Michigan basin. Reservoir rocks are fractured, organic-rich black shales that also serve as source rocks. Although fractures are important for production, the relationships to specific geologic structures are not clear. Large quantities of water are coproduced with the gas, and geochemical data indicate that the water is fairly fresh and relatively young. Current thinking holds that biogenic gas was generated, and perhaps continues to be, when glacial meltwater descended into the plumbing system provided by fractures. Other examples of late-generation systems include the Devonian New Albany Shale on the eastern margin of the Illinois basin and the Tertiary coalbed methane production on the northwestern margin of the Powder River basin. Both types of biogenic gas systems have a similar resource development history. Initially, little technology is used, and gas is consumed locally; eventually, sweet spots are exploited, widespread unconventional reservoirs are developed, and transport of gas is interstate or international. However, drilling and completion techniques are very different between the two types of systems. Early-generation systems have water-sensitive reservoir rocks, and consequently water is avoided or minimized in drilling and completion. In contrast, water is an important constituent of late-generation systems; gas production is closely tied to dewatering the system during production. Existing production and resource estimates generally range from 10 to 100 tcf for both types of biogenic gas systems. Although both system types are examples of relatively continuous accumulations, the geologic frameworks constrain most-economic production to large geologic structures on the margins of basins. Shallow biogenic gas systems hold important resources to meet the increased domestic and international demands for natural gas.

Petroleum Systems and Geologic Assessment of Oil and Gas Resources in the Wind River Basin Province, Wyoming

USGS Publications Warehouse

,

2007-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Wind River Basin Province which encompasses about 4.7 million acres in central Wyoming. The assessment is based on the geologic elements of each total petroleum system (TPS) defined in the province, including hydrocarbon source rocks (source-rock maturation, hydrocarbon generation, and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined three TPSs: (1) Phosphoria TPS, (2) Cretaceous-Tertiary TPS, and (3) Waltman TPS. Within these systems, 12 Assessment Units (AU) were defined and undiscovered oil and gas resources were quantitatively estimated within 10 of the 12 AUs.

Measurements of I-129 in meteorites and lunar rock by tandem accelerator mass spectrometry

NASA Technical Reports Server (NTRS)

Nizhiizumi, K.; Arnold, J. R.; Elmore, D.; Gove, H. E.; Honda, M.

1983-01-01

Precise measurements of the half-life of I-129 in three different meteorites and one lunar surface rock are reported. The meteorite source of I-129 was produced by cosmic ray secondary neutron reactions on Te, while the source in lunar materials in spallation on barium and rare earth elements. The Abee, Allende, and Dhajala meteorites were examined, together with the lunar rock 14310. Details of the process used to extract the iodine are provided. The Abee and Allende samples exhibited a production of 0.5 atom/min per gm of Te from the (n,2n) reaction and 0.05 atom/min/gm for the (n,gamma) reaction. The I-129 is concluded to be a viable tool for long-lived cosmogenic nuclide studies. Further work to extend the data to include the constancy of the cosmic ray flux, the meteorite bombardment history, and the cosmic exposure age dating by means of the I-129 and Xe-129 method is indicated.

Petroleum Systems and Geologic Assessment of Undiscovered Oil and Gas, Navarro and Taylor Groups, Western Gulf Province, Texas

USGS Publications Warehouse

,

2006-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas potential of the Late Cretaceous Navarro and Taylor Groups in the Western Gulf Province in Texas (USGS Province 5047). The Navarro and Taylor Groups have moderate potential for undiscovered oil resources and good potential for undiscovered gas resources. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and five assessment units. Five assessment units were quantitatively assessed for undiscovered oil and gas resources.

National Assessment of Oil and Gas Project: Geologic Assessment of Undiscovered Oil and Gas Resources of the Eastern Great Basin Province, Nevada, Utah, Idaho, and Arizona

USGS Publications Warehouse

,

2007-01-01

Introduction The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Eastern Great Basin Province of eastern Nevada, western Utah, southeastern Idaho, and northwestern Arizona. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and three assessment units. All three assessment units were quantitatively assessed for undiscovered oil and gas resources.

Qualitative and quantitative analysis of Dibenzofuran, Alkyldibenzofurans, and Benzo[b]naphthofurans in crude oils and source rock extracts

USGS Publications Warehouse

Meijun Li,; Ellis, Geoffrey S.

2015-01-01

Dibenzofuran (DBF), its alkylated homologues, and benzo[b]naphthofurans (BNFs) are common oxygen-heterocyclic aromatic compounds in crude oils and source rock extracts. A series of positional isomers of alkyldibenzofuran and benzo[b]naphthofuran were identified in mass chromatograms by comparison with internal standards and standard retention indices. The response factors of dibenzofuran in relation to internal standards were obtained by gas chromatography-mass spectrometry analyses of a set of mixed solutions with different concentration ratios. Perdeuterated dibenzofuran and dibenzothiophene are optimal internal standards for quantitative analyses of furan compounds in crude oils and source rock extracts. The average concentration of the total DBFs in oils derived from siliciclastic lacustrine rock extracts from the Beibuwan Basin, South China Sea, was 518 μg/g, which is about 5 times that observed in the oils from carbonate source rocks in the Tarim Basin, Northwest China. The BNFs occur ubiquitously in source rock extracts and related oils of various origins. The results of this work suggest that the relative abundance of benzo[b]naphthofuran isomers, that is, the benzo[b]naphtho[2,1-d]furan/{benzo[b]naphtho[2,1-d]furan + benzo[b]naphtho[1,2-d]furan} ratio, may be a potential molecular geochemical parameter to indicate oil migration pathways and distances.

FNF Construction Inc. Window Rock Airport Project: Coverage Under General Air Quality Permit for New or Modified Minor Source Cement Batch Plants in Indian Country

EPA Pesticide Factsheets

Approved Request for Coverage under General Air Quality Permit for New or Modified Minor Source Cement Batch Plants in Indian Country for FNF Construction Inc. Window Rock Airport Soil Cement Mixing Plant Project, Beacon Road, Window Rock, Arizona 86515.

On the original igneous source of Martian fines

NASA Technical Reports Server (NTRS)

Baird, A. K.; Clark, B. C.

1981-01-01

The composition of the silicate portion of Martian regolith fines indicates derivation of the fines from mafic to ultramafic rocks, probably rich in pyroxene. Rock types similar in chemical and mineralogical composition include terrestrial Archean basalts and certain achondrite meteorites. If these igneous rocks weathered nearly isochemically, the nontronitic clays proposed earlier as an analog to Martian fines could be formed. Flood basalts of pyroxenitic lavas may be widespread and characteristic of early volcanism on Mars, analogous to maria flood basalts on the moon and early Precambrian basaltic komatiites on earth. Compositional differences between lunar, terrestrial, and Martian flood basalts may be related to differences in planetary sizes and mantle compositions of the respective planetary objects.

Mineral and whole-rock compositions of seawater-dominated hydrothermal alteration at the Arctic volcanogenic massive sulfide prospect, Alaska

USGS Publications Warehouse

Schmidt, J.M.

1988-01-01

The Arctic volcanogenic massive sulfide prospect, located in the Ambler mineral district of northwestern Alaska, includes three types of hydrothermally altered rocks overlying, underlying, and interlayered with semimassive sulfide mineralization. Hydrothermal alteration of wall rocks and deposition of sulfide and gangue minerals were contemporaneous with Late Devonian of Early Mississippian basalt-rhyolite volcanism. Alteration developed asymmetrically around a linear fissure, suggesting fracture control of ore fluids rather than a point source. Microprobe analyses of phyllosilicates from the Arctic area indicate two discrete mineral populations. These differences in mineral chemistry are the result of differences in protolith composition caused by hydrothermal alteration-metasomatism. -from Author

Effects of smectite on the oil-expulsion efficiency of the Kreyenhagen Shale, San Joaquin Basin, California, based on hydrous-pyrolysis experiments

USGS Publications Warehouse

Lewan, Michael D.; Dolan, Michael P.; Curtis, John B.

2014-01-01

The amount of oil that maturing source rocks expel is expressed as their expulsion efficiency, which is usually stated in milligrams of expelled oil per gram of original total organic carbon (TOCO). Oil-expulsion efficiency can be determined by heating thermally immature source rocks in the presence of liquid water (i.e., hydrous pyrolysis) at temperatures between 350°C and 365°C for 72 hr. This pyrolysis method generates oil that is compositionally similar to natural crude oil and expels it by processes operative in the subsurface. Consequently, hydrous pyrolysis provides a means to determine oil-expulsion efficiencies and the rock properties that influence them. Smectite in source rocks has previously been considered to promote oil generation and expulsion and is the focus of this hydrous-pyrolysis study involving a representative sample of smectite-rich source rock from the Eocene Kreyenhagen Shale in the San Joaquin Basin of California. Smectite is the major clay mineral (31 wt. %) in this thermally immature sample, which contains 9.4 wt. % total organic carbon (TOC) comprised of type II kerogen. Compared to other immature source rocks that lack smectite as their major clay mineral, the expulsion efficiency of the Kreyenhagen Shale was significantly lower. The expulsion efficiency of the Kreyenhagen whole rock was reduced 88% compared to that of its isolated kerogen. This significant reduction is attributed to bitumen impregnating the smectite interlayers in addition to the rock matrix. Within the interlayers, much of the bitumen is converted to pyrobitumen through crosslinking instead of oil through thermal cracking. As a result, smectite does not promote oil generation but inhibits it. Bitumen impregnation of the rock matrix and smectite interlayers results in the rock pore system changing from water wet to bitumen wet. This change prevents potassium ion (K+) transfer and dissolution and precipitation reactions needed for the conversion of smectite to illite. As a result, illitization only reaches 35% to 40% at 310°C for 72 hr and remains unchanged to 365°C for 72 hr. Bitumen generation before or during early illitization in these experiments emphasizes the importance of knowing when and to what degree illitization occurs in natural maturation of a smectite-rich source rock to determine its expulsion efficiency. Complete illitization prior to bitumen generation is common for Paleozoic source rocks (e.g., Woodford Shale and Retort Phosphatic Shale Member of the Phosphoria Formation), and expulsion efficiencies can be determined on immature samples by hydrous pyrolysis. Conversely, smectite is more common in Cenozoic source rocks like the Kreyenhagen Shale, and expulsion efficiencies determined by hydrous pyrolysis need to be made on samples that reflect the level of illitization at or near bitumen generation in the subsurface.

Sulfur species in source rock bitumen before and after hydrous pyrolysis determined by X-ray absorption near-edge structure

USGS Publications Warehouse

Bolin, Trudy B.; Birdwell, Justin E.; Lewan, Michael; Hill, Ronald J.; Grayson, Michael B.; Mitra-Kirtley, Sudipa; Bake, Kyle D.; Craddock, Paul R.; Abdallah, Wael; Pomerantz, Andrew E.

2016-01-01

The sulfur speciation of source rock bitumen (chloroform-extractable organic matter in sedimentary rocks) was examined using sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy for a suite of 11 source rocks from around the world. Sulfur speciation was determined for both the native bitumen in thermally immature rocks and the bitumen produced by thermal maturation of kerogen via hydrous pyrolysis (360 °C for 72 h) and retained within the rock matrix. In this study, the immature bitumens had higher sulfur concentrations than those extracted from samples after hydrous pyrolysis. In addition, dramatic and systematic evolution of the bitumen sulfur moiety distributions following artificial thermal maturation was observed consistently for all samples. Specifically, sulfoxide sulfur (sulfur double bonded to oxygen) is abundant in all immature bitumen samples but decreases substantially following hydrous pyrolysis. The loss in sulfoxide sulfur is associated with a relative increase in the fraction of thiophene sulfur (sulfur bonded to aromatic carbon) to the extent that thiophene is the dominant sulfur form in all post-pyrolysis bitumen samples. This suggests that sulfur moiety distributions might be used for estimating thermal maturity in source rocks based on the character of the extractable organic matter.

High-frequency lunar teleseismic events

NASA Technical Reports Server (NTRS)

Nakamura, Y.; Dorman, J.; Duennebier, F.; Ewing, M.; Lammlein, D.; Latham, G.

1974-01-01

A small number of seismic signals, including some of the strongest observed to date, have been identified as representing a fourth principal category of natural lunar seismic events with characteristics distinct from those produced by normal meteoroid impacts, deep moonquakes, and thermal moonquakes. These signals are much richer in high frequencies than other events observed at comparable distances, and display relatively impulsive P- and S-wave beginnings, indicating negligible seismic-wave scattering near the source. Source depths of these events may range between 0 and perhaps 300 km. These and other characteristics could represent either (1) meteoroids impacting upon outcrops of competent lunar crystal rock, (2) rare impacting objects that penetrate to competent rock below a scattering zone, or (3) shallow tectonic moonquakes.

Chapter 5: Geologic Assessment of Undiscovered Petroleum Resources in the Waltman Shale Total Petroleum System,Wind River Basin Province, Wyoming

USGS Publications Warehouse

Roberts, Steve B.; Roberts, Laura N.R.; Cook, Troy

2007-01-01

The Waltman Shale Total Petroleum System encompasses about 3,400 square miles in the Wind River Basin Province, Wyoming, and includes accumulations of oil and associated gas that were generated and expelled from oil-prone, lacustrine shale source rocks in the Waltman Shale Member of the Paleocene Fort Union Formation. Much of the petroleum migrated and accumulated in marginal lacustrine (deltaic) and fluvial sandstone reservoirs in the Shotgun Member of the Fort Union, which overlies and intertongues with the Waltman Shale Member. Additional petroleum accumulations derived from Waltman source rocks are present in fluvial deposits in the Eocene Wind River Formation overlying the Shotgun Member, and also might be present within fan-delta deposits included in the Waltman Shale Member, and in fluvial sandstone reservoirs in the uppermost part of the lower member of the Fort Union Formation immediately underlying the Waltman. To date, cumulative production from 53 wells producing Waltman-sourced petroleum exceeds 2.8 million barrels of oil and 5.8 billion cubic feet of gas. Productive horizons range from about 1,770 feet to 5,800 feet in depth, and average about 3,400 to 3,500 feet in depth. Formations in the Waltman Shale Total Petroleum System (Fort Union and Wind River Formations) reflect synorogenic deposition closely related to Laramide structural development of the Wind River Basin. In much of the basin, the Fort Union Formation is divided into three members (ascending order): the lower unnamed member, the Waltman Shale Member, and the Shotgun Member. These members record the transition from deposition in dominantly fluvial, floodplain, and mire environments in the early Paleocene (lower member) to a depositional setting characterized by substantial lacustrine development (Waltman Shale Member) and contemporaneous fluvial, and marginal lacustrine (deltaic) deposition (Shotgun Member) during the middle and late Paleocene. Waltman Shale Member source rocks have total organic carbon values ranging from 0.93 to 6.21 weight percent, averaging about 2.71 weight percent. The hydrocarbon generative potential of the source rocks typically exceeds 2.5 milligrams of hydrocarbon per gram of rock and numerous samples had generative potentials exceeding 6.0 milligrams of hydrocarbon per gram of rock. Waltman source rocks are oil prone, and contain a mix of Type-II and Type-III kerogen, indicating organic input from a mix of algal and terrestrial plant matter, or a mix of algal and reworked or recycled material. Thermal maturity at the base of the Waltman Shale Member ranges from a vitrinite reflectance value of less than 0.60 percent along the south basin margin to projected values exceeding 1.10 percent in the deep basin west of Madden anticline. Burial history reconstructions for three wells in the northern part of the Wind River Basin indicate that the Waltman Shale Member was well within the oil window (Ro equal to or greater than 0.65 percent) by the time of maximum burial about 15 million years ago; maximum burial depths exceeded 10,000 feet. Onset of oil generation calculated for the base of the Waltman Shale member took place from about 49 million years ago to about 20 million years ago. Peak oil generation occurred from about 31 million years ago to 26 million years ago in the deep basin west of Madden anticline. Two assessment units were defined in the Waltman Shale Total Petroleum System: the Upper Fort Union Sandstones Conventional Oil and Gas Assessment Unit (50350301) and the Waltman Fractured Shale Continuous Oil Assessment Unit (50350361). The conventional assessment unit primarily relates to the potential for undiscovered petroleum accumulations that are derived from source rocks in the Waltman Shale Member and trapped within sandstone reservoirs in the Shotgun Member (Fort Union Formation) and in the lower part of the overlying Wind River Formation. The potential for Waltman-sourced oil accumulations in fan-delta depos

40 CFR 436.180 - Applicability; description of the phosphate rock subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... phosphate rock subcategory. 436.180 Section 436.180 Protection of Environment ENVIRONMENTAL PROTECTION... SOURCE CATEGORY Phosphate Rock Subcategory § 436.180 Applicability; description of the phosphate rock... bearing rock, ore or earth for the phosphate content. [43 FR 9809, Mar. 10, 1978] ...

40 CFR 436.180 - Applicability; description of the phosphate rock subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... phosphate rock subcategory. 436.180 Section 436.180 Protection of Environment ENVIRONMENTAL PROTECTION... SOURCE CATEGORY Phosphate Rock Subcategory § 436.180 Applicability; description of the phosphate rock... bearing rock, ore or earth for the phosphate content. [43 FR 9809, Mar. 10, 1978] ...

40 CFR 436.180 - Applicability; description of the phosphate rock subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... phosphate rock subcategory. 436.180 Section 436.180 Protection of Environment ENVIRONMENTAL PROTECTION... SOURCE CATEGORY Phosphate Rock Subcategory § 436.180 Applicability; description of the phosphate rock... bearing rock, ore or earth for the phosphate content. [43 FR 9809, Mar. 10, 1978] ...

Hydrocarbon Source Rocks in the Deep River and Dan River Triassic Basins, North Carolina

USGS Publications Warehouse

Reid, Jeffrey C.; Milici, Robert C.

2008-01-01

This report presents an interpretation of the hydrocarbon source rock potential of the Triassic sedimentary rocks of the Deep River and Dan River basins, North Carolina, based on previously unpublished organic geochemistry data. The organic geochemical data, 87 samples from 28 drill holes, are from the Sanford sub-basin (Cumnock Formation) of the Deep River basin, and from the Dan River basin (Cow Branch Formation). The available organic geochemical data are biased, however, because many of the samples collected for analyses by industry were from drill holes that contained intrusive diabase dikes, sills, and sheets of early Mesozoic age. These intrusive rocks heated and metamorphosed the surrounding sediments and organic matter in the black shale and coal bed source rocks and, thus, masked the source rock potential that they would have had in an unaltered state. In places, heat from the intrusives generated over-mature vitrinite reflectance (%Ro) profiles and metamorphosed the coals to semi-anthracite, anthracite, and coke. The maximum burial depth of these coal beds is unknown, and depth of burial may also have contributed to elevated thermal maturation profiles. The organic geochemistry data show that potential source rocks exist in the Sanford sub-basin and Dan River basin and that the sediments are gas prone rather than oil prone, although both types of hydrocarbons were generated. Total organic carbon (TOC) data for 56 of the samples are greater than the conservative 1.4% TOC threshold necessary for hydrocarbon expulsion. Both the Cow Branch Formation (Dan River basin) and the Cumnock Formation (Deep River basin, Sanford sub-basin) contain potential source rocks for oil, but they are more likely to have yielded natural gas. The organic material in these formations was derived primarily from terrestrial Type III woody (coaly) material and secondarily from lacustrine Type I (algal) material. Both the thermal alteration index (TAI) and vitrinite reflectance data (%Ro) indicate levels of thermal maturity suitable for generation of hydrocarbons. The genetic potential of the source rocks in these Triassic basins is moderate to high and many source rock sections have at least some potential for hydrocarbon generation. Some data for the Cumnock Formation indicate a considerably higher source rock potential than the basin average, with S1 + S2 data in the mid-20 mg HC/g sample range, and some hydrocarbons have been generated. This implies that the genetic potential for all of these strata may have been higher prior to the igneous activity. However, the intergranular porosity and permeability of the Triassic strata are low, which makes fractured reservoirs more attractive as drilling targets. In some places, gravity and magnetic surveys that are used to locate buried intrusive rock may identify local thermal sources that have facilitated gas generation. Alternatively, awareness of the distribution of large intrusive igneous bodies at depth may direct exploration into other areas, where thermal maturation is less than the limits of hydrocarbon destruction. Areas prospective for natural gas also contain large surficial clay resources and any gas discovered could be used as fuel for local industries that produce clay products (principally brick), as well as fuel for other local industries.

Measurement of Thermal Properties of Rocks at Temperature up to 1,000°C with Transient Plane Source Techniques

NASA Astrophysics Data System (ADS)

Kim, S. K.; Lee, Y.

2017-12-01

A set of devices that can measure thermal properties of rocks over a temperature range from room temperature up to 1,000°C with transient plane source techniques (also known as a Hot Disk method) is introduced. It consists of a main control system (e.g., TPS 2500 S from Hot Disk), mica-insulated sensor, tubular furnace, N2 gas supplier, and pressure regulator. The TPS 2500 S is the core instrument designed for precise analysis of thermal transport properties including thermal conductivity, thermal diffusivity, and volumetric heat capacity. The mica-insulated sensor is composed of an insulated nickel double spiral, which is utilized for both transient heating and precise temperature reading; a mica insulator protects the sensor against mechanical and thermal damage at high temperatures. The tubular furnace can hold two rock core samples of 50-mm-diameter and 25-mm-height with increasing temperatures up to 1,000°C. N2 gas supplier and pressure regulator are used to keep the inside the furnace away from oxygen. Thermal properties of most rocks and minerals vary with increasing temperatures. Experimental measurements of thermal properties at high temperatures have been made mostly using laser flash, needle probe, and divided bar methods in the previous researches, and no previous measurements with the Hot Disk method have been reported yet. We report thermal conductivities, thermal diffusivities, and volumetric heat capacities determined by a transient plane heat source method for fused silica and mafic rock samples using the introduced transient plane source apparatus. The thermal properties of fused silica have been measured mainly over the temperature range from ambient temperature to 500°C. The results seem to agree moderately with the previously reported values by Birch and Clark (Am. J. Sci., 1940). We now check the possible causes of measurement errors in our measurements and prepare to measure thermal properties of the mafic rock samples at temperatures up to 1,000°C using the hot disk method.

World Map Showing Surface and Subsurface Distribution, and Lithologic Character of Middle and Late Neoproterozoic Rocks

USGS Publications Warehouse

Stewart, John H.

2007-01-01

INTRODUCTION The map was prepared to outline the basic information on where Neoproterozoic rocks are present in the World, and of the lithologic character of these rocks. The information provides a better understanding of major Neoproterozoic tectonic subdivisions useful in paleogeographic and plate tectonic reconstructions. The time frame of the map is within the middle and late Neoproterozoic from approximately 870 to 540 Ma and is after widespread Mesoproterozoic Grenville-age collisional events that are considered to have formed the hypothetical supercontinent of Rodinia. Much of the time represented by the map is interpreted to be during the fragmentation of Rodinia. The recognition of Neoproterozoic rocks is commonly difficult because of limited isotopic or paloeontological dating. Thus, some rocks shown on the map could be older or younger than the age indicated. However, at the scale of the map the the problem may be minor. Enough information seems to be available to indicate the general age of the rocks. Many of the successions contain diamictite deposits considered to be glaciogenic and dated as middle or late Neoproterozoic. These deposits thus show a rough correlation of middle and late Neoproterozoic rocks of the world. The map is a Richardson map projection, except for Antarctica which is a polar projection. The map was prepared from about 650 references, shown in the text linked below under 'Sources of Information', used to outline distribution patterns, determine rock types, and provide information on the regional and local geologic framework of the rocks. The focus of the references is on the geologic information needed to prepare the map. Other information, such as plate tectonic reconstructions or paleomagnetic studies is generally not included. The 'Sources of Information' lists references alphabetically for each of 14 regions. In brackets is a code for each area. These codes provide help in locating the specific regions in the references.

Mercury isotope constraints on the source for sediment-hosted lead-zinc deposits in the Changdu area, southwestern China

NASA Astrophysics Data System (ADS)

Xu, Chunxia; Yin, Runsheng; Peng, Jiantang; Hurley, James P.; Lepak, Ryan F.; Gao, Jianfeng; Feng, Xinbin; Hu, Ruizhong; Bi, Xianwu

2018-03-01

The Lanuoma and Cuona sediment-hosted Pb-Zn deposits hosted by Upper Triassic limestone and sandstone, respectively, are located in the Changdu area, SW China. Mercury concentrations and Hg isotopic compositions from sulfide minerals and potential source rocks (e.g., the host sedimentary rocks and the metamorphic basement) were investigated to constrain metal sources and mineralization processes. In both deposits, sulfide minerals have higher mercury (Hg) concentrations (0.35 to 1185 ppm) than the metamorphic basement rocks (0.05 to 0.15 ppm) and sedimentary rocks (0.02 to 0.08 ppm). Large variations of mass-dependent fractionation (3.3‰ in δ202Hg) and mass-independent fractionation (0.3‰ in Δ199Hg) of Hg isotopes were observed. Sulfide minerals have Hg isotope signatures that are similar to the hydrothermal altered rocks around the deposit, and similar to the metamorphic basement, but different from barren sedimentary rocks. The variation of Δ199Hg suggests that Hg in sulfides was mainly derived from the underlying metamorphic basement. Mercury isotopes could be a geochemical tracer in understanding metal sources in hydrothermal ore deposits.

The Complex Stratigraphy of the Highland Crust in the Serenitatis Region of the Moon Inferred from Mineral Fragment Chemistry

NASA Technical Reports Server (NTRS)

Ryder, Graham; Norman, Marc D.; Taylor, G. Jeffrey

1997-01-01

Large impact basins are natural drill holes into the Moon, and their ejecta carries unique information about the rock types and stratigraphy of the lunar crust. We have conducted an electron microprobe study of mineral fragments in the poikilitic melt breccias collected from the Taurus Mountains at the Apollo 17 landing site. These breccias are virtually unanimously agreed to be impact melt produced in the Serenitatis impact event. They contain lithic fragments and much more abundant mineral fragments of crustal origin. We have made precise microprobe analyses of minor element abundances in fragments of olivine, pyroxene, and plagioclase to provide new information on the possible source rocks and the crustal stratigraphy in the Serenitatis region. These data were also intended to elucidate the nature of the cryptic geochemical component in breccias such as these with low-K Fra Mauro basalt compositions. We chose the finest-grained (i.e., most rapidly quenched) breccias for study, to avoid reacted and partly assimilated fragments as much as possible. Most of the mineral fragments appear to have been derived from rocks that would fall into the pristine igneous Mg-suite as represented by lithic fragments in the Apollo collection, or reasonable extensions of it. Gabbroic rocks were more abundant in the target stratigraphy than is apparent from the Apollo sample collection. Some pyroxene and plagiociase, but probably not much olivine, could be derived from feldspathic granulites, which are metamorphosed polymict breccias. Some mineral fragments are from previously unknown rocks. These include highly magnesian olivines (up to Fo(sub 94)), possibly volcanic in origin, that exacerbate the difficulty in explaining highly magnesian rocks in the lunar crust. It appears that some part of the lunar interior has an mg*(= 100 x Mg/(Mg/Fe) atomic) greater than the conventional bulk Moon value of 80-84. Other volcanic rocks, including mare basalts, and rapidly- cooled impact melt rocks do not contribute significantly to the fragment population. Nor do ferroan anorthosites contribute more than a tiny part of even the plagiociase fragment population. A few mineral fragments that are consistent with the cryptic low-K Fra Mauro chemical component were found, and these appear to be from gabbroic sources. The mineral fragment populations cannot be mixed in their observed proportions to produce the whole rock composition, because the fragments are more refractory and deficient in Ti, P, and alkalis. A preferential contribution to the melt from a rock similar to sodic ferrogabbro can partly resolve the discrepancy. The population of mineral fragments requires a very diverse population of igenous rocks that are not all related to each other, demonstrating the existence of a complex crust built of numerous separate igneous plutons. Many of these plutons may have crystallized at shallow depths. The chemical composition of the melt breccias, in combination with the mineral fragment data and an understanding of the cratering process, suggests that the deepest crust sampled by the Serenitatis impace (not necessarily the deepest crust) was basaltic in composition, including KREEP and gabbroic rocks like sodic ferrogabbro, and lacking abundant olivine-rich material. These were overlain by Mg-suite rocks of varied types, including norites and troctolites that supplied most of the olivine mineral fragments. Granulities, which are metamorphosed and more feldspathic breccias, were abundant near the surface. Remote sensing indicates that the entire Serenitatis region lacks ferroan anorthosite, consistent with the results of our study.

Assessment of hydrocarbon source rock potential of Polish bituminous coals and carbonaceous shales

USGS Publications Warehouse

Kotarba, M.J.; Clayton, J.L.; Rice, D.D.; Wagner, M.

2002-01-01

We analyzed 40 coal samples and 45 carbonaceous shale samples of varying thermal maturity (vitrinite reflectance 0.59% to 4.28%) from the Upper Carboniferous coal-bearing strata of the Upper Silesian, Lower Silesian, and Lublin basins, Poland, to evaluate their potential for generation and expulsion of gaseous and liquid hydrocarbons. We evaluated source rock potential based on Rock-Eval pyrolysis yield, elemental composition (atomic H/C and O/C), and solvent extraction yields of bitumen. An attempt was made to relate maceral composition to these source rock parameters and to composition of the organic matter and likely biological precursors. A few carbonaceous shale samples contain sufficient generation potential (pyrolysis assay and elemental composition) to be considered potential source rocks, although the extractable hydrocarbon and bitumen yields are lower than those reported in previous studies for effective Type III source rocks. Most samples analysed contain insufficient capacity for generation of hydrocarbons to reach thresholds required for expulsion (primary migration) to occur. In view of these findings, it is improbable that any of the coals or carbonaceous shales at the sites sampled in our study would be capable of expelling commercial amounts of oil. Inasmuch as a few samples contained sufficient generation capacity to be considered potential source rocks, it is possible that some locations or stratigraphic zones within the coals and shales could have favourable potential, but could not be clearly delimited with the number of samples analysed in our study. Because of their high heteroatomic content and high amount of asphaltenes, the bitumens contained in the coals are less capable of generating hydrocarbons even under optimal thermal conditions than their counterpart bitumens in the shales which have a lower heteroatomic content. Published by Elsevier Science B.V.

Neoproterozoic rift basins and their control on the development of hydrocarbon source rocks in the Tarim Basin, NW China

NASA Astrophysics Data System (ADS)

Zhu, Guang-You; Ren, Rong; Chen, Fei-Ran; Li, Ting-Ting; Chen, Yong-Quan

2017-12-01

The Proterozoic is demonstrated to be an important period for global petroleum systems. Few exploration breakthroughs, however, have been obtained on the system in the Tarim Basin, NW China. Outcrop, drilling, and seismic data are integrated in this paper to focus on the Neoproterozoic rift basins and related hydrocarbon source rocks in the Tarim Basin. The basin consists of Cryogenian to Ediacaran rifts showing a distribution of N-S differentiation. Compared to the Cryogenian basins, those of the Ediacaran are characterized by deposits in small thickness and wide distribution. Thus, the rifts have a typical dual structure, namely the Cryogenian rifting and Ediacaran depression phases that reveal distinct structural and sedimentary characteristics. The Cryogenian rifting basins are dominated by a series of grabens or half grabens, which have a wedge-shaped rapid filling structure. The basins evolved into Ediacaran depression when the rifting and magmatic activities diminished, and extensive overlapping sedimentation occurred. The distributions of the source rocks are controlled by the Neoproterozoic rifts as follows. The present outcrops lie mostly at the margins of the Cryogenian rifting basins where the rapid deposition dominates and the argillaceous rocks have low total organic carbon (TOC) contents; however, the source rocks with high TOC contents should develop in the center of the basins. The Ediacaran source rocks formed in deep water environment of the stable depressions evolving from the previous rifting basins, and are thus more widespread in the Tarim Basin. The confirmation of the Cryogenian to Ediacaran source rocks would open up a new field for the deep hydrocarbon exploration in the Tarim Basin.

Reconnaissance stratigraphic studies in the Susitna basin, Alaska, during the 2014 field season

USGS Publications Warehouse

LePain, David L.; Stanley, Richard G.; Harun, Nina T.; Helmold, Kenneth P.; Tsigonis, Rebekah

2015-01-01

The Susitna basin is a poorly-understood Cenozoic successor basin immediately north of Cook Inlet in south-central Alaska (Kirschner, 1994). The basin is bounded by the Castle Mountain fault and Cook Inlet basin on the south, the Talkeetna Mountains on the east, the Alaska Range on the north, and the Alaska–Aleutian Range on the west (fig. 2-1). The Cenozoic fill of the basin includes coal-bearing nonmarine rocks that are partly correlative with Paleogene strata in the Matanuska Valley and Paleogene and Neogene formations in Cook Inlet (Stanley and others, 2013, 2014). Mesozoic sedimentary rocks are present in widely-scattered uplifts in and around the margins of the basin; these rocks differ significantly from Mesozoic rocks in the forearc basin to the south. Mesozoic strata in the Susitna region were likely part of a remnant ocean basin that preceded the nonmarine Cenozoic basin (Trop and Ridgway, 2007). The presence of coal-bearing strata similar to units that are proven source rocks for microbial gas in Cook Inlet (Claypool and others, 1980) suggests the possibility of a similar system in the Susitna basin (Decker and others, 2012). In 2011 the Alaska Division of Geological & Geophysical Surveys (DGGS) and Alaska Division of Oil and Gas, in collaboration with the U.S. Geological Survey, initiated a study of the gas potential of the Susitna basin (Gillis and others, 2013). This report presents a preliminary summary of the results from 14 days of helicopter-supported field work completed in the basin in August 2014. The goals of this work were to continue the reconnaissance stratigraphic work begun in 2011 aimed at understanding reservoir and seal potential of Tertiary strata, characterize the gas source potential of coals, and examine Mesozoic strata for source and reservoir potential

Investigation and hazard assessment of the 2003 and 2007 Staircase Falls rock falls, Yosemite National Park, California, USA

USGS Publications Warehouse

Wieczorek, G.F.; Stock, Gregory M.; Reichenbach, P.; Snyder, J.B.; Borchers, J.W.; Godt, J.W.

2008-01-01

Since 1857 more than 600 rock falls, rock slides, debris slides, and debris flows have been documented in Yosemite National Park, with rock falls in Yosemite Valley representing the majority of the events. On 26 December 2003, a rock fall originating from west of Glacier Point sent approximately 200 m 3 of rock debris down a series of joint-controlled ledges to the floor of Yosemite Valley. The debris impacted talus near the base of Staircase Falls, producing fragments of flying rock that struck occupied cabins in Curry Village. Several years later on 9 June 2007, and again on 26 July 2007, smaller rock falls originated from the same source area. The 26 December 2003 event coincided with a severe winter storm and was likely triggered by precipitation and/or frost wedging, but the 9 June and 26 July 2007 events lack recognizable triggering mechanisms. We investigated the geologic and hydrologic factors contributing to the Staircase Falls rock falls, including bedrock lithology, weathering, joint spacing and orientations, and hydrologic processes affecting slope stability. We improved upon previous geomorphic assessment of rock-fall hazards, based on a shadow angle approach, by using STONE, a three-dimensional rock-fall simulation computer program. STONE produced simulated rock-fall runout patterns similar to the mapped extent of the 2003 and 2007 events, allowing us to simulate potential future rock falls from the Staircase Falls detachment area. Observations of recent rock falls, mapping of rock debris, and simulations of rock fall runouts beneath the Staircase Falls detachment area suggest that rock-fall hazard zones extend farther downslope than the extent previously defined by mapped surface talus deposits.

The Birth of a Cratonic Core: Petrologic Evolution of the Hadean-Eoarchean Acasta Gneiss Complex

NASA Astrophysics Data System (ADS)

Reimink, J. R.; Chacko, T.; Davies, J.; Pearson, D. G.; Stern, R. A.; Heaman, L. M.; Carlson, R.; Shirey, S. B.

2016-12-01

Granitoid magmatism within the 4.02-3.6 Ga Acasta Gneiss Complex records distinct whole-rock compositional changes during the building the Slave Craton. Previously1,2 we suggested that these signatures implied petrologic changes from initiation of evolved crust formation in an Iceland-like setting to partial melting of hydrated mafic crust at increasing depth through time, culminating in relatively voluminous magmatism at 3.6 Ga. Increasing La/Yb in these rocks suggest increasing depth of melting (and increasing residual garnet content) with time, ending in emplacement of rocks comparable to other Archean TTG suites3, with both high pressure (high La/Yb) and low pressure (low La/Yb) rocks represented at 3.6 Ga. Data from rocks with variable La/Yb that crystallized 3.6 Ga allow us to evaluate potential mechanisms for formation of rocks of this age such as subduction/accretion or intracrustal melting/delamination. Despite major and trace element compositional and age variability, zircon oxygen isotope compositions from a wide variety of rocks are extremely consistent (+6.0-6.5 ‰ from 3.9-2.9 Ga), implying a similar source, one that had been altered by surface waters1. Potential source rocks include the upper portion of oceanic crust, which contains a large portion of mafic crust that had been altered at low temperatures (e.g., 4). Paired whole rock and zircon radiogenic isotopic data are especially sensitive to the extent of pre-existing felsic material in the region, as well as the longevity of primary, basaltic rocks prior to their reworking into more evolved crust. New paired zircon Hf and whole rock Nd isotope data collected from these samples show variably unradiogenic signatures and allow an exploration of similarities and disparities between crust formation in the Acasta Gneiss Complex and other Paleoarchean-Mesoarchean crustal blocks. [1] Reimink et al., 2016. Precambrian Research 281, 453-472. [2] Reimink et al., 2014 Nature Geoscience 7, 529-533. [3] Moyen and Martin, 2012 Lithos 148, 312-348. [4] Eiler, J.M., 2001 Reviews in Mineralogy and Geochemistry 43, 319-364.

Vapor Transport Through Fractures and Other High-Permeability Paths: Its Role in the Drift Scale Test at Yucca Mountain, Nevada

NASA Astrophysics Data System (ADS)

Mukhopadhyay, S.; Tsang, Y. W.

2001-12-01

Heating unsaturated fractured tuff sets off a series of complicated thermal-hydrological (TH) processes, which result in large-scale redistribution of moisture in the host rock. Moisture redistribution arises from boiling of water near heat sources, transport of vapor away from those heat sources, condensation of that vapor in cooler rock, and subsequent gravity drainage of condensate through fractures. Vapor transport through high-permeability paths, which include both the fractures in the rock and other conduits, contributes to the evolution of these TH processes in two ways. First, the highly permeable natural fractures provide easy passage for vapor away from the heat sources. Second, these fractures and other highly permeable conduits allow vapor (and the associated energy) to escape the rock through open boundaries of the test domain. The overall impact of vapor transport on the evolution of the TH processes can be more easily understood in the context of the Drift Scale Test (DST), the largest ever in situ heater test in unsaturated fractured tuff. The DST, in which a large volume of rock has been heated for four years now, is located in the middle nonlithophysal (Tptpmn) stratigraphic unit of Yucca Mountain, Nevada. The fractured tuff in Tptpmn contains many well-connected fractures. In the DST, heating is provided by nine cannister heaters placed in a five-meter-diameter Heated Drift (HD) and fifty wing heaters installed orthogonal to the axis of the HD. The test has many instrumentation boreholes, some of which are not sealed by packers or grout and may provide passage for vapor and energy. Of these conduits, the boreholes housing the wing heaters are most important for vapor transport because of their proximity to heat sources. While part of the vapor generated by heating moves away from the heat sources through the fractures and condenses elsewhere in the rock, the rest of the vapor, under gas-pressure difference, enters the HD by way of the high-permeability wing heater boreholes and escapes the test block through an open bulkhead that connects the HD to the outside world. We show that this vapor transport makes a significant difference in the validation of numerical models against TH processes in the DST. A huge volume of data, including changes in temperature and saturation of the rock, has been collected from the DST. Sophisticated conceptual and numerical models, based on the TOUGH2 simulator, have been developed to analyze these data and to help develop a better understanding of various aspects of coupled TH processes in unsaturated fractured tuff. In general, these models have predicted a close match between measured and simulated results, indicating a good representation of the underlying physical processes. However, there are subtle differences in the predictions from these models. Of particular interest here are two models: One in which vapor transport was considered through the natural fractures only, and the other in which vapor transport through the boreholes housing the wing heaters was included in addition to that through natural fractures. Direct statistical comparison of simulated and measured temperatures from more than 1,700 sensors yielded a mean error of 3-4oC for the first model, indicating that less heat was retained in the test block than that predicted by the model. On the other hand, a similar statistical comparison yielded a mean error of 1-2oC for the second model, suggesting that inclusion of vapor loss through the boreholes produces results closer to the measured data.

Carboniferous volcanic rocks associated with back-arc extension in the western Chinese Tianshan, NW China: Insight from temporal-spatial character, petrogenesis and tectonic significance

NASA Astrophysics Data System (ADS)

Su, Wenbo; Cai, Keda; Sun, Min; Wan, Bo; Wang, Xiangsong; Bao, Zihe; Xiao, Wenjiao

2018-06-01

The Yili-Central Tianshan Block, as a Late Paleozoic major continental silver of the Central Asian Orogenic Belt, holds a massive volume of Carboniferous volcanic rocks, occurring as subparallel magmatic belts. However, the petrogenesis and tectonic implications of these volcanic rocks remain enigmatic. This study compiled isotopic age data for mapping their temporal-spatial character, and conducted petrogenetic study of these magmatic belts, aiming to understand their tectonic implications. Our compiled dataset reveals four magmatic belts in the Yili-Central Tianshan Block, including the Keguqinshan-Tulasu belt and the Awulale belt in the north, and the Wusun Mountain belt and the Haerk-Nalati belt in the south. In addition, our new zircon U-Pb dating results define two significant Early Carboniferous eruptive events (ca. 355-350 Ma and 325 Ma) in the Wusun Mountain belt. Volcanic rocks of the early significant eruptive event (ca. 355-350 Ma) in the Wusun Mountain comprise basalt, trachy-andesite, andesite, dacite and rhyolite, which are similar to the typical rock assemblage of a continental arc. Their positive εNd(t) values (+0.3 to +1.5) and relatively high Th/Yb and Nb/Yb ratios suggest the derivation from a mantle source with additions of slab-derived components. The gabbroic dykes and rhyolites of the late volcanic event (ca. 325 Ma) form a bimodal rock association, and they show alkaline features, with relatively low Th/Yb and Th/Nb ratios, and higher positive εNd(t) values (εNd(t) = +3.3-+5.0). It is interpreted that the gabbroic dykes and rhyolites may have been derived from mantle and juvenile crustal sources, respectively. The isotopic and trace elemental variations with time elapse of the Wusun Mountain magmatic belt show an important clue for strengthening depletion of the magma sources. Considering the distinctive temporal-spatial character of the Carboniferous volcanic rocks, two separate subduction systems in the southern and northern margins of the Yili-Central Tianshan Block were suggested to be the causes for extensive emplacements of the igneous products, which may be in an association with synchronous subduction of the South Tianshan and the North Tianshan oceanic plates, respectively. In this tectonic context, the Carboniferous magmatic rocks of the Wusun Mountain may be a tectonic response to the change in magma sources due to back-arc propagation in the western Chinese Tianshan.

Maps showing thermal maturity of Upper Cretaceous marine shales in the Wind River Basin, Wyoming

USGS Publications Warehouse

Finn, Thomas M.; Pawlewicz, Mark J.

2013-01-01

The Wind River Basin is a large Laramide (Late Cretaceous through Eocene) structural and sedimentary basin that encompasses about 7,400 square miles in central Wyoming. The basin is bounded by the Washakie Range, Owl Creek, and southern Bighorn Mountains on the north, the Casper arch on the east and northeast, the Granite Mountains on the south, and the Wind River Range on the west. Important conventional and unconventional oil and gas resources have been discovered and produced from reservoirs ranging in age from Mississippian through Tertiary. It has been suggested that various Upper Cretaceous marine shales are the principal hydrocarbon source rocks for many of these accumulations. Numerous source rock studies of various Upper Cretaceous marine shales throughout the Rocky Mountain region have led to the conclusion that these rocks have generated, or are capable of generating, oil and (or) gas. With recent advances and success in horizontal drilling and multistage fracture stimulation there has been an increase in exploration and completion of wells in these marine shales in other Rocky Mountain Laramide basins that were traditionally thought of only as hydrocarbon source rocks. Important parameters that control hydrocarbon production from shales include: reservoir thickness, amount and type of organic matter, and thermal maturity. The purpose of this report is to present maps and a structural cross section showing levels of thermal maturity, based on vitrinite reflectance (Ro), for Upper Cretaceous marine shales in the Wind River Basin.

Evidence for Seismogenic Hydrogen Gas, a Potential Microbial Energy Source on Earth and Mars.

PubMed

McMahon, Sean; Parnell, John; Blamey, Nigel J F

2016-09-01

The oxidation of molecular hydrogen (H2) is thought to be a major source of metabolic energy for life in the deep subsurface on Earth, and it could likewise support any extant biosphere on Mars, where stable habitable environments are probably limited to the subsurface. Faulting and fracturing may stimulate the supply of H2 from several sources. We report the H2 content of fluids present in terrestrial rocks formed by brittle fracturing on fault planes (pseudotachylites and cataclasites), along with protolith control samples. The fluids are dominated by water and include H2 at abundances sufficient to support hydrogenotrophic microorganisms, with strong H2 enrichments in the pseudotachylites compared to the controls. Weaker and less consistent H2 enrichments are observed in the cataclasites, which represent less intense seismic friction than the pseudotachylites. The enrichments agree quantitatively with previous experimental measurements of frictionally driven H2 formation during rock fracturing. We find that conservative estimates of current martian global seismicity predict episodic H2 generation by Marsquakes in quantities useful to hydrogenotrophs over a range of scales and recurrence times. On both Earth and Mars, secondary release of H2 may also accompany the breakdown of ancient fault rocks, which are particularly abundant in the pervasively fractured martian crust. This study strengthens the case for the astrobiological investigation of ancient martian fracture systems. Deep biosphere-Faults-Fault rocks-Seismic activity-Hydrogen-Mars. Astrobiology 16, 690-702.

Late Mesozoic-Cenozoic intraplate magmatism in Central Asia and its relation with mantle diapirism: Evidence from the South Khangai volcanic region, Mongolia

NASA Astrophysics Data System (ADS)

Yarmolyuk, Vladimir V.; Kudryashova, Ekaterina A.; Kozlovsky, Alexander M.; Lebedev, Vladimir A.; Savatenkov, Valery M.

2015-11-01

The South Khangai volcanic region (SKVR) comprises fields of Late Mesozoic-Cenozoic volcanic rocks scattered over southern and central Mongolia. Evolution of the region from the Late Jurassic to the Late Cenozoic includes 13 successive igneous episodes that are more or less evenly distributed in time. Major patterns in the distribution of different-aged volcanic complexes were controlled by a systematic temporal migration of volcanic centers over the region. The total length of their trajectory exceeds 1600 km. Principle characteristics of local magmatism are determined. The composition of igneous rocks varies from basanites to rhyolites (predominantly, high-K rocks), with geochemistry close to that of OIB. The rock composition, however, underwent transformations in the Mesozoic-Cenozoic. Rejuvenation of mafic rocks is accompanied by decrease in the contents of HREE and increase of Nb and Ta. According to isotope data, the SKVR magmatic melts were derived from three isotope sources that differed in the Sr, Nd, and Pb isotopic compositions and successively alternated in time. In the Early Cretaceous, the predominant source composition was controlled by interaction of the EMII- and PREMA-type mantle materials. The PREMA-type mantle material dominated quantitatively in the Late Cretaceous and initial Early Cenozoic. From the latest Early Cenozoic to Late Cenozoic, the magma source also contained the EMI-type material along with the PREMA-type. The structural fabric, rock composition, major evolutionary pattern, and inner structure of SKVR generally comply with the criteria used to distinguish the mantle plume-related regions. Analogous features can be seen in other regions of recent volcanism in Central Asia (South Baikal, Udokan, Vitim, and Tok Stanovik). The structural autonomy of these regions suggests that distribution of the Late Mesozoic-Cenozoic volcanism in Central Asia was controlled by a group of relatively small hot finger-type mantle plumes associated with the common hot mantle field of Central Asia.

Restoration of Circum-Arctic Upper Jurassic source rock paleolatitude based on crude oil geochemistry

USGS Publications Warehouse

Peters, K.E.; Ramos, L.S.; Zumberge, J.E.; Valin, Z.C.; Scotese, C.R.

2008-01-01

Tectonic geochemical paleolatitude (TGP) models were developed to predict the paleolatitude of petroleum source rock from the geochemical composition of crude oil. The results validate studies designed to reconstruct ancient source rock depositional environments using oil chemistry and tectonic reconstruction of paleogeography from coordinates of the present day collection site. TGP models can also be used to corroborate tectonic paleolatitude in cases where the predicted paleogeography conflicts with the depositional setting predicted by the oil chemistry, or to predict paleolatitude when the present day collection locality is far removed from the source rock, as might occur due to long distance subsurface migration or transport of tarballs by ocean currents. Biomarker and stable carbon isotope ratios were measured for 496 crude oil samples inferred to originate from Upper Jurassic source rock in West Siberia, the North Sea and offshore Labrador. First, a unique, multi-tiered chemometric (multivariate statistics) decision tree was used to classify these samples into seven oil families and infer the type of organic matter, lithology and depositional environment of each organofacies of source rock [Peters, K.E., Ramos, L.S., Zumberge, J.E., Valin, Z.C., Scotese, C.R., Gautier, D.L., 2007. Circum-Arctic petroleum systems identified using decision-tree chemometrics. American Association of Petroleum Geologists Bulletin 91, 877-913]. Second, present day geographic locations for each sample were used to restore the tectonic paleolatitude of the source rock during Late Jurassic time (???150 Ma). Third, partial least squares regression (PLSR) was used to construct linear TGP models that relate tectonic and geochemical paleolatitude, where the latter is based on 19 source-related biomarker and isotope ratios for each oil family. The TGP models were calibrated using 70% of the samples in each family and the remaining 30% of samples were used for model validation. Positive relationships exist between tectonic and geochemical paleolatitude for each family. Standard error of prediction for geochemical paleolatitude ranges from 0.9?? to 2.6?? of tectonic paleolatitude, which translates to a relative standard error of prediction in the range 1.5-4.8%. The results suggest that the observed effect of source rock paleolatitude on crude oil composition is caused by (i) stable carbon isotope fractionation during photosynthetic fixation of carbon and (ii) species diversity at different latitudes during Late Jurassic time. ?? 2008 Elsevier Ltd. All rights reserved.

Classes of organic molecules targeted by a methanogenic microbial consortium grown on sedimentary rocks of various maturities

PubMed Central

Meslé, Margaux; Dromart, Gilles; Haeseler, Frank; Oger, Philippe M.

2015-01-01

Organic-rich shales are populated by methanogenic consortia that are able to degrade the fossilized organic matter into methane gas. To identify the organic fraction effectively degraded, we have sequentially depleted two types of organic-rich sedimentary rocks, shale, and coal, at two different maturities, by successive solvent extractions to remove the most soluble fractions (maltenes and asphaltenes) and isolate kerogen. We show the ability of the consortia to produce methane from all rock samples, including those containing the most refractory organic matter, i.e., the kerogen. Shales yielded higher methane production than lignite and coal. Mature rocks yielded more methane than immature rocks. Surprisingly, the efficiency of the consortia was not influenced by the removal of the easily biodegradable fractions contained in the maltenes and asphaltenes. This suggests that one of the limitations of organic matter degradation in situ may be the accessibility to the carbon and energy source. Indeed, bitumen has a colloidal structure that may prevent the microbial consortia from reaching the asphaltenes in the bulk rock. Solvent extractions might favor the access to asphaltenes and kerogen by modifying the spatial organization of the molecules in the rock matrix. PMID:26136731

Petroleum geochemistry of oil and gas from Barbados: Implications for distribution of Cretaceous source rocks and regional petroleum prospectivity

USGS Publications Warehouse

Hill, R.J.; Schenk, C.J.

2005-01-01

Petroleum produced from the Barbados accretionary prism (at Woodbourne Field on Barbados) is interpreted as generated from Cretaceous marine shale deposited under normal salinity and dysoxic conditions rather than from a Tertiary source rock as previously proposed. Barbados oils correlate with some oils from eastern Venezuela and Trinidad that are positively correlated to extracts from Upper Cretaceous La Luna-like source rocks. Three distinct groups of Barbados oils are recognized based on thermal maturity, suggesting petroleum generation occurred at multiple levels within the Barbados accretionary prism. Biodegradation is the most significant process affecting Barbados oils resulting in increased sulfur content and decreased API gravity. Barbados gases are interpreted as thermogenic, having been co-generated with oil, and show mixing with biogenic gas is limited. Gas biodegradation occurred in two samples collected from shallow reservoirs at the Woodbourne Field. The presence of Cretaceous source rocks within the Barbados accretionary prism suggests that greater petroleum potential exists regionally, and perhaps further southeast along the passive margin of South America. Likewise, confirmation of a Cretaceous source rock indicates petroleum potential exists within the Barbados accretionary prism in reservoirs that are deeper than those from Woodbourne Field.

A New Biomarker Proxy for Palaeo-pCO2 Reconstruction in Ancient Sediments

NASA Astrophysics Data System (ADS)

Pancost, R. D.; Magness, S.; Maxwell, J. R.

2001-12-01

The carbon isotopic composition of marine organic matter has commonly been used in chemostratigraphy or as a proxy for ancient pCO2 levels. Both of these goals require that the source of organic matter be well defined, and in the case of palaeo-pCO2 investigations, the organic matter must be derived ultimately from aquatic photoautotrophs. However, additional sources, including terrestrial biomass, heterotrophs, or bacteria, can also contribute to total organic carbon (TOC). In the past decade, numerous workers have attempted to refine organic carbon isotope records using the isotopic composition of individual compounds (biomarkers) rather than the TOC. The appeal of this approach is that by examining specific biomarkers, a signal diagnostic for photoautotrophic organisms can be obtained. For compound-specific isotope analyses to be most effective, the compounds analysed must have a relatively specific source. Among the most commonly used biomarkers in palaeo-pCO2 investigations are alkenones, long-chain ketones derived exclusively from certain species of haptophyte algae. However, alkenones are absent in rocks older than the Jurassic and either absent or present in low abundances in rocks older than the Miocene. Thus, in older rocks, other biomarkers, including steranes (derived from eukaryotic sterols), phytane (presumably derived from chlorophyll), and n-alkanes (derived from algal macromolecules), are used. Unfortunately, these compounds can have alternative sources and become less reliable as isotopic proxies for photoautotrophs with increasing thermal maturity and complexity of the hydrocarbon distribution. Here we propose the use of a maleimides (1H-pyrrole-2,5-diones) as a new biomarker class for evaluating past changes in photoautotroph carbon isotopic compositions. Maleimides have three key advantages over other biomarkers in ancient rocks. First, they are degradation products of chlorophyll and have no known alternative origins in marine sediments. Second, because of their unique structure, they can be readily isolated from other organic components facilitating the determination of accurate carbon isotope ratios. Finally, the pyrrole structure is relatively stable insuring that maleimides survive even in thermally mature rocks. We have applied the analysis of maleimides to investigations of sediments from the Kupferschiefer (Permian), Vena del Gesso (Messinian) and Livello Bonarelli (Cenomanian-Turonian boundary) formations. In all three cases, the carbon isotopic compositions of selected maleimides exhibit shifts predicted by either carbonate or other biomarker carbon isotope profiles.

Publications - GMC 209 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 209 Publication Details Title: Source rock potential and geochemical characterization of OCS Y Reference DGSI, Inc., 1993, Source rock potential and geochemical characterization of OCS Y-0943-1 (Aurora

Hydrocarbon Reservoir Identification in Volcanic Zone by using Magnetotelluric and Geochemistry Information

NASA Astrophysics Data System (ADS)

Firda, S. I.; Permadi, A. N.; Supriyanto; Suwardi, B. N.

2018-03-01

The resistivity of Magnetotelluric (MT) data show the resistivity mapping in the volcanic reservoir zone and the geochemistry information for confirm the reservoir and source rock formation. In this research, we used 132 data points divided with two line at exploration area. We used several steps to make the resistivity mapping. There are time series correction, crosspower correction, then inversion of Magnetotelluric (MT) data. Line-2 and line-3 show anomaly geological condition with Gabon fault. The geology structure from the resistivity mapping show the fault and the geological formation with the geological rock data mapping distribution. The geochemistry information show the maturity of source rock formation. According to core sample analysis information, we get the visual porosity for reservoir rock formation in several geological structure. Based on that, we make the geological modelling where the potential reservoir and the source rock around our interest area.

Fluid-rock interactions during UHP metamorphism: A review of the Dabie-Sulu orogen, east-central China

NASA Astrophysics Data System (ADS)

Zhang, Z. M.; Shen, K.; Liou, J. G.; Dong, X.; Wang, W.; Yu, F.; Liu, F.

2011-08-01

Comprehensive review on the characteristics of petrology, oxygen isotope, fluid inclusion and nominally anhydrous minerals (NAMs) for many Dabie-Sulu ultrahigh-pressure (UHP) metamorphic rocks including drill-hole core samples reveals that fluid has played important and multiple roles during complicated fluid-rock interactions attending the subduction and exhumation of supracrustal rocks. We have identified several distinct stages of fluid-rock interactions as follows: (1) The Neoproterozoic supercrustal protoliths of UHP rocks experienced variable degrees of hydration through interactions with cold meteoric water with extremely low oxygen isotope compositions during Neoproterozoic Snow-ball Earth time. (2) A series of dehydration reactions took place during Triassic subduction of the Yangtze plate beneath the Sino-Korean plate; the released fluid entered mainly into volatile-bearing high-pressure (HP) and UHP minerals, such as phengite, zoisite-epidote, talc, lawsonite and magnesite, as well as into UHP NAMs, such as garnet, omphacite and rutile. (3) Silicate-rich supercritical fluid (hydrous melt) existed during the UHP metamorphism at mantle depths >100 km which mobilized many normally fluid-immobile elements and caused unusual element fractionation. (4) The fluid exsolved from the NAMs during the early exhumation of the Dabie-Sulu terrane was the main source for HP hydrate retrogression and generation of HP veins. (5) Local amphibolite-facies retrogression at crustal depths took place by infiltration of aqueous fluid of various salinities possibly derived from an external source. (6) The greenschist-facies overprinting and low-pressure (LP) quartz veins were generated by fluid flow along ductile shear zones and brittle faults during late-stage uplift of the UHP terrane.

77 FR 62267 - Proposed Extension of Existing Information Collection; Gamma Radiation Surveys

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-12

... Extension of Existing Information Collection; Gamma Radiation Surveys AGENCY: Mine Safety and Health...-9440 (voice); or 202-693-9441 (facsimile). SUPPLEMENTARY INFORMATION: I. Background Gamma radiation... debilitating occupational diseases. Natural sources include rocks, soils, and ground water. Gamma radiation...

Preliminary source rock evaluation and hydrocarbon generation potential of the early Cretaceous subsurface shales from Shabwah sub-basin in the Sabatayn Basin, Western Yemen

NASA Astrophysics Data System (ADS)

Al-Matary, Adel M.; Hakimi, Mohammed Hail; Al Sofi, Sadam; Al-Nehmi, Yousif A.; Al-haj, Mohammed Ail; Al-Hmdani, Yousif A.; Al-Sarhi, Ahmed A.

2018-06-01

A conventional organic geochemical study has been performed on the shale samples collected from the early Cretaceous Saar Formation from the Shabwah oilfields in the Sabatayn Basin, Western Yemen. The results of this study were used to preliminary evaluate the potential source-rock of the shales in the Saar Formation. Organic matter richness, type, and petroleum generation potential of the analysed shales were assessed. Total organic carbon content and Rock- Eval pyrolysis results indicate that the shale intervals within the early Cretaceous Saar Formation have a wide variation in source rock generative potential and quality. The analysed shale samples have TOC content in the range of 0.50 and 5.12 wt% and generally can be considered as fair to good source rocks. The geochemical results of this study also indicate that the analysed shales in the Saar Formation are both oil- and gas-prone source rocks, containing Type II kerogen and mixed Types II-III gradient to Type III kerogen. This is consistent with Hydrogen Index (HI) values between 66 and 552 mg HC/g TOC. The temperature-sensitive parameters such as vitrinite reflectance (%VRo), Rock-Eval pyrolysis Tmax and PI reveal that the analysed shale samples are generally immature to early-mature for oil-window. Therefore, the organic matter has not been altered by thermal maturity thus petroleum has not yet generated. Therefore, exploration strategies should focus on the known deeper location of the Saar Formation in the Shabwah-sub-basin for predicting the kitchen area.

Incremental growth of an upper crustal, A-type pluton, Argentina: Evidence of a re-used magma pathway

NASA Astrophysics Data System (ADS)

Alasino, Pablo H.; Larrovere, Mariano A.; Rocher, Sebastián; Dahlquist, Juan A.; Basei, Miguel A. S.; Memeti, Valbone; Paterson, Scott; Galindo, Carmen; Macchioli Grande, Marcos; da Costa Campos Neto, Mario

2017-07-01

Carboniferous igneous activity in the Sierra de Velasco (NW Argentina) led to the emplacement of several magmas bodies at shallow levels (< 2 kbar). One of these, the San Blas intrusive complex formed over millions of years (≤ 2-3 m.y.) through three periods of magma additions that are characterized by variations in magma sources and emplacement style. The main units, mostly felsic granitoids, have U-Pb zircon crystallization ages within the error range. From older to younger (based on cross-cutting relationships) intrusive units are: (1) the Asha unit (340 ± 7 Ma): a tabular to funnel-shaped intrusion emplaced during a regional strain field dominated by WSW-ENE shortening with contacts discordant to regional host-rock structures; (2) the San Blas unit (344 ± 2 Ma): an approximate cylindrical-shaped intrusion formed by multiple batches of magmas, with a roughly concentric fabric pattern and displacement of the host rock by ductile flow of about 35% of shortening; and (3) the Hualco unit (346 ± 6 Ma): a small body with a possible mushroom geometry and contacts concordant to regional host-rock structures. The magma pulses making up these units define two groups of A-type granitoids. The first group includes the peraluminous granitic rocks of the Asha unit generated mostly by crustal sources (εNdt = - 5.8 and εHft in zircon = - 2.9 to - 4.5). The second group comprises the metaluminous to peraluminous granitic rocks of the youngest units (San Blas and Hualco), which were formed by a heterogeneous mixture between mantle and crustal sources (εNdt = + 0.6 to - 4.8 and εHft in zircon = + 3 to - 6). Our results provide a comprehensive view of the evolution of an intrusive complex formed from multiple non-consanguineous magma intrusions that utilized the same magmatic plumbing system during downward transfer of host materials. As the plutonic system matures, the ascent of magmas is governed by the visco-elastic flow of host rock that for younger batches include older hot magma mush. The latter results in ductile downward flow of older, during rise of younger magma. Such complexes may reflect the plutonic portion of volcanic centers where chemically distinct magmas are erupted.

Publications - GMC 324 | Alaska Division of Geological & Geophysical

Science.gov Websites

. 1, which includes an HC-Show (Hydrocarbon-Show) Evaluation from core (989', 997.25', and 1625') and Source-Rock Evaluation from cuttings (10880'-11010') and from core(10992') Authors: Huizinga, B.J . Oumalik No. 1, which includes an HC-Show (Hydrocarbon-Show) Evaluation from core (989', 997.25', and 1625

Clastic metasediments of the Early Proterozoic Broken Hill Group, New South Wales, Australia: Geochemistry, provenance, and metallogenic significance

USGS Publications Warehouse

Slack, J.F.; Stevens, B.P.J.

1994-01-01

Whole-rock analyses of samples of pelite, psammite, and psammopelite from the Early Proterozoic Broken Hill Group (Willyama Supergroup) in the Broken Hill Block, New South Wales, Australia, reveal distinctive geochemical signatures. Major-element data show high Al2O3 and K2O, low MgO and Na2O, and relatively high Fe2O3T MgO ratios, compared to average Early Proterozoic clastic metasediments. High field strength elements (HFSE) are especially abundant, including Nb (most 15-27 ppm), Ta (most 1.0-2.2 ppm), Th (17-36 ppm), Hf (4-15 ppm), and Zr (most 170-400 ppm); Y (33-74 ppm) is also high. Concentrations of ferromagnesian elements are generally low (Sc = < 20 ppm, Ni = ??? 62 ppm, Co = <26 ppm; Cr = most < 100 ppm). Data for rare earth elements (REEs) show high abundances of light REEs (LaCN = 116-250 ?? chondrite; LaCN = 437 in one sample), high LaCN YbCN ratios (5.6-13.9), and large negative Eu anomalies ( Eu Eu* = 0.32-0.57). The geochemical data indicate derivation of the metasedimentary rocks of the Broken Hill Group by the erosion mainly of felsic igneous (or meta-igneous) rocks. High concentrations of HFSE, Y, and REEs in the metasediments suggest a provenance dominanted by anorogenic granites and(or) rhyolites, including those with A-type chemistry. Likely sources of the metasediments were the rhyolitic to rhyodacitic protoliths of local quartz + feldspar ?? biotite ?? garnet gneisses (e.g., Potosi-type gneiss) that occur within the lower part of the Willyama Supergroup, or chemically similar basement rocks in the region; alternative sources may have included Early Proterozoic anorogenic granites and(or) rhyolites in the Mount Isa and(or) Pine Creek Blocks of northern Australia, or in the Gawler craton of South Australia. Metallogenic considerations suggest that the metasediments of the Broken Hill Block formed enriched source rocks during the generation of pegmatite-hosted deposits and concentrations of La, Ce, Nb, Ta, Th, and Sn in the region. Li, Be, B, W, and U in pegmatite minerals of the district may have been acquired during granulite-facies metamorphism of the local metasediments. ?? 1994.

Stratigraphic variations in the biomarker distribution of the Moreno Formation: Their correlation with San Joaquin basin oils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bac, M.G.; Schulein, B.J.

1990-05-01

Variability in the biomarker compositions of petroleums is typically employed in the recognition and distinction of contributions from different source rocks. We demonstrate that the fluctuations in the biomarker distributions of different intervals within a single source rock sequence appear to account for specific compositional differences in a suite of oils from the San Joaquin basin California. Rock-Eval pyrolysis studies of a 100-m-thick immature, laminated, marine shale sequence within the Upper Cretaceous lo lower Paleocene portion of the Moreno Formation reveals TOC (total organic carbon) contents consistently around 2% and moderate hydrogen indices (i.e., 175-300 mg HC/g org. C) characteristicsmore » suggestive of a uniform depositional sequence with source rock potential. Analyses of the extractable aliphatic hydrocarbons of cored samples taken at approximately 10-m intervals from the sequence reveal significant variability in biomarker distributions. Such differences are exemplified by the triterpenoids (as seen in m/z 191 chromatograms from GC-MS and GC-MS/MS analyses) where the dominant component fluctuates from a 17{alpha}(h),21{beta}(H)-30-norhopane to 28,30-l8{alpha}(H)-bisnorhopane to 20S and 20R danunar-13(17)-enes. Some components are dominant in one interval, but are not detected in others, suggesting discrete stratigraphic variations in the biomarker characteristics of the Moreno. Similar discrepancies in biomarker distributions are evident in the aliphatic hydrocarbons of the suite of oils. The three petroleums reservoired in the San Carlos sandstone member of the Lodo Formation which directly overlies the Moreno, reflect biomarker contributions from a Moreno source, including compound distributions, and the occurrence of both alkanes (e.g., 28.30-bisnorhopane) and alkenes (e.g.. danunarenes and diasterenes).« less

Timing of oil and gas generation of petroleum systems in the Southwestern Wyoming Province

USGS Publications Warehouse

Roberts, L.N.R.; Lewan, M.D.; Finn, T.M.

2004-01-01

Burial history, thermal maturity, and timing of petroleum generation were modeled for eight key source-rock horizons at seven locations throughout the Southwestern Wyoming Province. The horizons are the bases of the Lower Permian Phosphoria Formation, the Upper Cretaceous Mowry Shale, Niobrara Formation, Baxter Shale (and equivalents), upper part of the Mesaverde Group, Lewis Shale, Lance Formation, and the Tertiary (Paleocene) Fort Union Formation. Burial history locations include three in the deepest parts of the province (Adobe Town in the Washakie Basin, Eagles Nest in the Great Divide Basin, and Wagon Wheel in the northern Green River Basin); two at intermediate basin depths (Federal 31-1 and Currant, Creek in the central and southern parts of the Green River Basin, respectively); and two relatively shallow locations (Bear 1 on the southeastern margin of the Sand Wash Basin and Bruff 2 on the Moxa arch). An overall ranking of the burial history locations in order of decreasing thermal maturity is Adobe Town > Eagles Nest > Wagon Wheel > Currant Creek > Federal 31-1 > Bear-1 > Bruff 2. The results of the models indicate that peak petroleum generation from Cretaceous oil- and gas-prone source rocks in the deepest parts of the province occurred from Late Cretaceous through middle Eocene. At the modeled locations, peak oil generation from source rocks of the Phosphoria Formation, which contain type-IIS kerogen, occurred in the Late Cretaceous (80 to 73 million years ago (Ma)). Gas generation from the cracking of Phosphoria oil reached a peak in the late Paleocene (57 Ma) only in the deepest parts of the province. The Mowry Shale, Niobrara Formation, and Baxter Shale (and equivalents) contain type-IIS or a mix of type-II and type-III kerogens. Oil generation from these units, in the deepest parts of the province, reached peak rates during the latest Cretaceous to early Paleocene (66 to 61 Ma). Only at these deepest locations did these units reach peak gas generation from the cracking of oil, which occurred in the early to late Eocene (52 to 41 Ma). For the Mesaverde Group, which also contains a mix of type-II and type-III kerogen, peak oil generation occurred only in the deepest parts of the province during middle Eocene (50 to 41 Ma). Only at Adobe Town did cracking of oil occur and gas generation reach peak in the earliest Oligocene (33 Ma). Gas-prone source rocks (type-III kerogen) of the Mowry and Baxter (and equivalents) Shales reached peak gas generation in the latest Cretaceous (66 Ma) in the deepest parts of the province. At the shallower Bear 1 location, the Mancos Shale (Baxter equivalent) source rocks reached peak gas generation at about this same time. Gas generation from the gas-prone Mesaverde source rocks started at all of the modeled locations, but reached peak generation at only the deepest locations in the early Eocene (54 to 49 Ma). The Lewis Shale, Lance Formation, and Fort Union Formation all contain gas-prone source rocks with type-III kerogen. Peak generation of gas from the Lewis Shale occurred only at Eagles Nest and Adobe Town in the early Eocene (52 Ma). Source rocks of the Lance reached peak gas generation only at the deepest locations during the middle Eocene (48 to 45 Ma) and the Fort Union reached peak gas generation only at Adobe Town also in the middle Eocene (44 Ma).

The post-collisional late Variscan ferroan granites of southern Sardinia (Italy): Inferences for inhomogeneity of lower crust

NASA Astrophysics Data System (ADS)

Conte, Aida Maria; Cuccuru, Stefano; D'Antonio, Massimo; Naitza, Stefano; Oggiano, Giacomo; Secchi, Francesco; Casini, Leonardo; Cifelli, Francesca

2017-12-01

The post-collisional late Variscan magmatism of Sardinia-Corsica batholith attained a peak at about 290 Ma. In southern Sardinia, in the frontal part of the Variscan orogenic wedge, this magmatism is represented by three suites of granitoids, here defined as GS1, GS2 and GS3. GS1, GS2 and GS3 are slightly peraluminous and F-bearing granitoids; GS1 and GS3 granites show in addition a ferroan character, whereas GS2 rocks range from magnesian to ferroan, from granodiorites to leucogranites. From magnetic susceptibility data, GS1 and GS2 belong to the ilmenite series, whereas GS3 is a slightly oxidized rock-suite plotting on the ilmenite/magnetite series boundary. Each rock-suite shows distinctive characters, in terms of petrography, petrochemistry, rock associations, as well as metallogenic signature of the related fluids. The distinction among rock-suite types is made on the basis of both mafic and characteristic accessory minerals. Siderophyllitic dark mica as the only mafic phase, and accessory xenotime (Y) characterize the GS1 rocks; GS2 mineral associations include biotite ± hornblende + allanite + magnetite; GS3 rocks show an association of hastingsite + annite + allanite + magnetite. Chemical variations in the studied samples suggest different magmatic evolution of independent magmas. Pb, Sr and Nd isotopic data constrain the origin of magmas to lower crustal sources. Chemical composition of rocks and dark micas meet those of liquids experimentally obtained by low degrees of partial melting of different meta-igneous deep crustal sources, felsic for GS1 rock-types and more mafic for GS3 rock-types. GS1 intrusions show granophile-type (Sn-W-Mo) metallogenic signatures, very low magnetic susceptibility, and Nd model ages (referred to the Depleted Mantle - TDM) of 2.3 Ga, coherent with a possible derivation from an old (early Proterozoic-Neoarchean), reduced and weathered basement, tectonically buried under Variscan covers. A definite deep crustal inhomogeneity is mirrored by GS3 granites, whose compositional and isotopic features indicate a younger (Nd model age: 1.6 Ga) tonalitic amphibolite source. Overall, the peculiarities of the studied granitoids suggest further compositional differences in the deep crust between southern and northern portion of the Sardinia-Corsica Variscan transect. Late Variscan lithospheric delamination appears as the most reliable mechanism that may have determined the high thermal regime that triggered partial melting of the crust. The close field association, at 290 Ma, of tholeiitic dike swarms and ferroan granitoids, supports this inference.

Gigantic landslides versus glacial deposits: on origin of large hummock deposits in Alai Valley, Northern Pamir

NASA Astrophysics Data System (ADS)

Reznichenko, Natalya

2015-04-01

As glaciers are sensitive to local climate, their moraines position and ages are used to infer past climates and glacier dynamics. These chronologies are only valid if all dated moraines are formed as the result of climatically driven advance and subsequent retreat. Hence, any accurate palaeoenvironmental reconstruction requires thorough identification of the landform genesis by complex approach including geomorphological, sedimentological and structural landform investigation. Here are presented the implication of such approach for the reconstruction of the mega-hummocky deposits formation both of glacial and landslide origin in the glaciated Alai Valley of the Northern Pamir with further discussion on these and similar deposits validity for palaeoclimatic reconstructions. The Tibetan Plateau valleys are the largest glaciated regions beyond the ice sheets with high potential to provide the best geological record of glacial chronologies and, however, with higher probabilities of the numerous rock avalanche deposits including those that were initially considered of glacial origin (Hewitt, 1999). The Alai Valley is the largest intermountain depression in the upper reaches of the Amudarja River basin that has captured numerous unidentified extensive hummocky deposits descending from the Zaalai Range of Northern Pamir, covering area in more than 800 km2. Such vast hummocky deposits are usually could be formed either: 1) glacially by rapid glacial retreat due to the climate signal or triggered a-climatically glacial changes, such as glacial surge or landslide impact, or 2) during the landslide emplacement. Combination of sediment tests on agglomerates forming only in rock avalanche material (Reznichenko et al., 2012) and detailed geomorphological and sedimentological descriptions of these deposits allowed reconstructing the glacial deposition in the Koman and Lenin glacial catchments with identification of two gigantic rock avalanches and their relation to this glacial deposits. Here are presented a new data on: parameters, extent and probable source for Lenin rock avalanche, travelled 24 km from the back wall of the Lenin Glacier over the glacial Achiktash hummock deposit covering more than 35 km2; updated data on Koman rock avalanche deposit, such as its extend and source; the first reconstruction of the Achiktash glacial material deposition with proposed landscape evolution during recent Quaternary in respect to the large landslide in the catchment. Hewitt, K., 1999. Quaternary moraines vs. catastrophic rock avalanches in the Karakoram Himalaya, Northern Pakistan. Quaternary Research, v. 51, p. 220-237. Reznichenko, N.V., Davies, T.R.H., Shulmeister, J. and Larsen S.H, 2012. A new technique for identifying rock-avalanche-sourced sediment in moraines and some paleoclimatic implications. Geology, v. 40, p. 319-322.

Elemental geochemistry of sedimentary rocks at Yellowknife Bay, Gale crater, Mars.

PubMed

McLennan, S M; Anderson, R B; Bell, J F; Bridges, J C; Calef, F; Campbell, J L; Clark, B C; Clegg, S; Conrad, P; Cousin, A; Des Marais, D J; Dromart, G; Dyar, M D; Edgar, L A; Ehlmann, B L; Fabre, C; Forni, O; Gasnault, O; Gellert, R; Gordon, S; Grant, J A; Grotzinger, J P; Gupta, S; Herkenhoff, K E; Hurowitz, J A; King, P L; Le Mouélic, S; Leshin, L A; Léveillé, R; Lewis, K W; Mangold, N; Maurice, S; Ming, D W; Morris, R V; Nachon, M; Newsom, H E; Ollila, A M; Perrett, G M; Rice, M S; Schmidt, M E; Schwenzer, S P; Stack, K; Stolper, E M; Sumner, D Y; Treiman, A H; VanBommel, S; Vaniman, D T; Vasavada, A; Wiens, R C; Yingst, R A

2014-01-24

Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from an approximately average martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved, indicating arid, possibly cold, paleoclimates and rapid erosion and deposition. The absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low-temperature, circumneutral pH, rock-dominated aqueous conditions. Analyses of diagenetic features (including concretions, raised ridges, and fractures) at high spatial resolution indicate that they are composed of iron- and halogen-rich components, magnesium-iron-chlorine-rich components, and hydrated calcium sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. The geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.

Vitrinite equivalent reflectance of Silurian black shales from the Holy Cross Mountains, Poland

NASA Astrophysics Data System (ADS)

Smolarek, Justyna; Marynowski, Leszek; Spunda, Karol; Trela, Wiesław

2014-12-01

A number of independent methods have been used to measure the thermal maturity of Silurian rocks from the Holy Cross Mountains in Poland. Black shales are characterized by diverse TOC values varying from 0.24-7.85%. Having calculated vitrinite equivalent reflectance using three different formulas, we propose that the most applicable values for the Silurian rocks are those based on Schmidt et al. (2015) equation. Based on this formula, the values range from % 0.71 VReqvVLR (the vitrinite equivalent reflectance of the vitrinite-like macerals) to % 1.96 VReqvVLR. Alternative, complementary methods including Rock Eval pyrolysis and parameters based on organic compounds (CPI, Pr/n-C17, Ph/n-C18, MPI1, and MDR) from extracts did not prove adequate as universal thermal maturity indicators. We have confirmed previous suggestions that Llandovery shales are the most likely Silurian source rocks for the generation of hydrocarbons in the HCM.

40Ar/39Ar Data for White Mica, Biotite, and K-Feldspar Samples from Low-Grade Metamorphic Rocks in the Westminster Terrane and Adjacent Rocks, Maryland

USGS Publications Warehouse

Kunk, Michael J.; McAleer, Ryan J.

2008-01-01

This report contains reduced 40Ar/39Ar data of white mica and K-feldspar mineral separates and matrix of a whole rock phyllite, all from low-grade metamorphic rocks of the Westminster terrane and adjacent strata in central Maryland. This report presents these data in a preliminary form, but in more detail than can be accommodated in todays professional journals. Also included in this report is information on the location of the samples and a brief description of the samples. The data contained herein are not interpreted in a geological context, and care should be taken by readers unfamiliar with argon isotopic data in the use of these results; many of the individual apparent ages are not geologically meaningful. This report is primarily a detailed source document for subsequent publications that will integrate these data into a geological context.

Compilation of new and previously published geochemical and modal data for Mesoproterozoic igneous rocks of the St. Francois Mountains, southeast Missouri

USGS Publications Warehouse

du Bray, Edward A.; Day, Warren C.; Meighan, Corey J.

2018-04-16

The purpose of this report is to present recently acquired as well as previously published geochemical and modal petrographic data for igneous rocks in the St. Francois Mountains, southeast Missouri, as part of an ongoing effort to understand the regional geology and ore deposits of the Mesoproterozoic basement rocks of southeast Missouri, USA. The report includes geochemical data that is (1) newly acquired by the U.S. Geological Survey and (2) compiled from numerous sources published during the last fifty-five years. These data are required for ongoing petrogenetic investigations of these rocks. Voluminous Mesoproterozoic igneous rocks in the St. Francois Mountains of southeast Missouri constitute the basement buried beneath Paleozoic sedimentary rock that is over 600 meters thick in places. The Mesoproterozoic rocks of southeast Missouri represent a significant component of approximately 1.4 billion-year-old (Ga) igneous rocks that crop out extensively in North America along the southeast margin of Laurentia and subsequent researchers suggested that iron oxide-copper deposits in the St. Francois Mountains are genetically associated with ca. 1.4 Ga magmatism in this region. The geochemical and modal data sets described herein were compiled to support investigations concerning the tectonic setting and petrologic processes responsible for the associated magmatism.

Isotopic and trace element compositions of upper mantle and lower crustal xenoliths, Cima volcanic field, California: Implications for evolution of the subcontinental lithospheric mantle

USGS Publications Warehouse

Mukasa, S.B.; Wilshire, H.G.

1997-01-01

Ultramafic and mafic xenoliths from the Cima volcanic field, southern California, provide evidence of episodic modification of the upper mantle and underplating of the crust beneath a portion of the southern Basin and Range province. The upper mantle xenoliths include spinel peridotite and anhydrous and hydrous pyroxenite, some cut by igneous-textured pyroxenite-gabbro veins and dikes and some by veins of amphibole ?? plagioclase. Igneous-textured pyroxenites and gabbros like the dike rocks also occur abundantly as isolated xenoliths inferred to represent underplated crust. Mineral and whole rock trace element compositions among and within the different groups of xenoliths are highly variable, reflecting multiple processes that include magma-mantle wall rock reactions, episodic intrusion and it filtration of basaltic melts of varied sources into the mantle wall rock, and fractionation. Nd, Sr, and Pb isotopic compositions mostly of clinopyroxene and plagioclase mineral separates show distinct differences between mantle xenoliths (??Nd = -5.7 to +3.4; 87Sr/86Sr = 0.7051 - 0.7073; 206Pb/204Pb = 19.045 - 19.195) and the igneous-textured xenoliths (??Nd = +7.7 to +11.7; 87Sr/86Sr = 0.7027 - 0.7036 with one carbonate-affected outlier at 0.7054; and 206Pb/204Pb = 18.751 - 19.068), so that they cannot be related. The igneous-textured pyroxenites and gabbros are similar in their isotopic compositions to the host basaltic rocks, which have ??Nd of+5.1 to +9.3; 87Sr/86Sr of 0.7028 - 0.7050, and 206Pb/204Pb of 18.685 - 21.050. The igneous-textured pyroxenites and gabbros are therefore inferred to be related to the host rocks as earlier cogenetic intrusions in the mantle and in the lower crust. Two samples of peridotite, one modally metasomatized by amphibole and the other by plagioclase, have isotopic compositions intermediate between the igneous-textured xenoliths and the mantle rock, suggesting mixing, but also derivation of the metasomatizing magmas from two separate and distinct sources. Sm-Nd two-mineral "isochrons" yield apparent ages for petrographically identical rocks believed to be coeval ranging from -0 to 113 ?? 26 Ma, indicating the unreliability of dating these rocks with this method. Amphibole and plagioclase megacrysts are isotopically like the host basalts and probably originate by mechanical breakup of veins comagmatic with the host basaltic rocks. Unlike other Basin and Range localities, Cima Cr-diopside group isotopic compositions do not overlap with those of the host basalts. Copyright 1997 by the American Geophysical Union.

Death as portrayed to adolescents through top 40 rock and roll music.

PubMed

Plopper, B L; Ness, M E

1993-01-01

Rock and roll music, an important influential communication source, provides adolescents with messages about death in our society. The first 37 years of Top 40 rock songs (1955-1991) were examined, and songs that included a past death or an impending death were identified. The popularity of the songs, cause of death, gender of the deceased, and relationships among characters were determined. Analysis of song content was conducted, with specific emphasis on attitudes toward and means of coping with death. Results indicate that death songs comprise a disproportionately popular subset of Top 40 music, males dominate the obituaries, and grieving responses are restricted. Findings are discussed from a sociocultural perspective, with attention to their significance for adolescents.

Modeling deformation processes of salt caverns for gas storage due to fluctuating operation pressures

NASA Astrophysics Data System (ADS)

Böttcher, N.; Nagel, T.; Goerke, U.; Khaledi, K.; Lins, Y.; König, D.; Schanz, T.; Köhn, D.; Attia, S.; Rabbel, W.; Bauer, S.; Kolditz, O.

2013-12-01

In the course of the Energy Transition in Germany, the focus of the country's energy sources is shifting from fossil to renewable and sustainable energy carriers. Since renewable energy sources, such as wind and solar power, are subjected to annual, seasonal, and diurnal fluctuations, the development and extension of energy storage capacities is a priority in German R&D programs. Common methods of energy storage are the utilization of subsurface caverns as a reservoir for natural or artificial fuel gases, such as hydrogen, methane, or the storage of compressed air. The construction of caverns in salt rock is inexpensive in comparison to solid rock formations due to the possibility of solution mining. Another advantage of evaporite as a host material is the self-healing capacity of salt rock. Gas caverns are capable of short-term energy storage (hours to days), so the operating pressures inside the caverns are fluctuating periodically with a high number of cycles. This work investigates the influence of fluctuating operation pressures on the stability of the host rock of gas storage caverns utilizing numerical models. Therefore, we developed a coupled Thermo-Hydro-Mechanical (THM) model based on the finite element method utilizing the open-source software platform OpenGeoSys. Our simulations include the thermodynamic behaviour of the gas during the loading/ unloading of the cavern. This provides information on the transient pressure and temperature distribution on the cavern boundary to calculate the deformation of its geometry. Non-linear material models are used for the mechanical analysis, which describe the creep and self-healing behavior of the salt rock under fluctuating loading pressures. In order to identify the necessary material parameters, we perform experimental studies on the mechanical behaviour of salt rock under varying pressure and temperature conditions. Based on the numerical results, we further derive concepts for monitoring THM quantities in the vicinity of the cavern. These programs will allow detecting changes of the host rock properties during the construction and operation of the storage facility. The developed model will be used by public authorities for land use planning issues.

Evaluation of kinetic uncertainty in numerical models of petroleum generation

USGS Publications Warehouse

Peters, K.E.; Walters, C.C.; Mankiewicz, P.J.

2006-01-01

Oil-prone marine petroleum source rocks contain type I or type II kerogen having Rock-Eval pyrolysis hydrogen indices greater than 600 or 300-600 mg hydrocarbon/g total organic carbon (HI, mg HC/g TOC), respectively. Samples from 29 marine source rocks worldwide that contain mainly type II kerogen (HI = 230-786 mg HC/g TOC) were subjected to open-system programmed pyrolysis to determine the activation energy distributions for petroleum generation. Assuming a burial heating rate of 1??C/m.y. for each measured activation energy distribution, the calculated average temperature for 50% fractional conversion of the kerogen in the samples to petroleum is approximately 136 ?? 7??C, but the range spans about 30??C (???121-151??C). Fifty-two outcrop samples of thermally immature Jurassic Oxford Clay Formation were collected from five locations in the United Kingdom to determine the variations of kinetic response for one source rock unit. The samples contain mainly type I or type II kerogens (HI = 230-774 mg HC/g TOC). At a heating rate of 1??C/m.y., the calculated temperatures for 50% fractional conversion of the Oxford Clay kerogens to petroleum differ by as much as 23??C (127-150??C). The data indicate that kerogen type, as defined by hydrogen index, is not systematically linked to kinetic response, and that default kinetics for the thermal decomposition of type I or type II kerogen can introduce unacceptable errors into numerical simulations. Furthermore, custom kinetics based on one or a few samples may be inadequate to account for variations in organofacies within a source rock. We propose three methods to evaluate the uncertainty contributed by kerogen kinetics to numerical simulations: (1) use the average kinetic distribution for multiple samples of source rock and the standard deviation for each activation energy in that distribution; (2) use source rock kinetics determined at several locations to describe different parts of the study area; and (3) use a weighted-average method that combines kinetics for samples from different locations in the source rock unit by giving the activation energy distribution for each sample a weight proportional to its Rock-Eval pyrolysis S2 yield (hydrocarbons generated by pyrolytic degradation of organic matter). Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

Publications - GMC 54 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS GMC 54 Publication Details Title: Source rock evaluation/TAI for ARCO Itkillik River Unit #1 information. Bibliographic Reference Texaco, Inc., [n.d.], Source rock evaluation/TAI for ARCO Itkillik River

Publications - GMC 249 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 249 Publication Details Title: Source rock geochemical and visual kerogen data from cuttings Reference Unknown, 1995, Source rock geochemical and visual kerogen data from cuttings (2,520-8,837') of the

Slow Impacts on Strong Targets Bring on the Heat

NASA Astrophysics Data System (ADS)

Melosh, H. J.; Ivanov, B. A.

2018-03-01

An important new paper by Kurosawa and Genda (2017, https://doi.org/10.1002/2017GL076285) reports a previously overlooked source of heating in low velocity meteorite impacts. Plastic deformation of the pressure-strengthened rocks behind the shock front dissipates energy, which appears as heat in addition to that generated across the shock wave itself. This heat source has surprisingly escaped explicit attention for decades: First, because it is minimized in the geometry typically chosen for laboratory experiments; and second because it is most important in rocks, and less so for the metals usually used in experiments. Nevertheless, modern numerical computer codes that include strength do compute this heating correctly. This raises the philosophical question of whether we can claim to understand some process just because our computer codes compute the results correctly.

Hydrocarbons in recent sediment of the Monterey Bay National Marine Sanctuary

USGS Publications Warehouse

Kvenvolden, K.A.; Hostettler, F.D.; Rosenbauer, R.W.; Lorenson, T.D.; Castle, W.T.; Sugarman, S.

2002-01-01

A complex mixture of hydrocarbons is present in the recent sediment of the Monterey Bay National Marine Sanctuary. Eighteen samples from the continental shelf between San Francisco and Monterey contain aliphatic and aromatic hydrocarbons showing biological contributions from both marine and terrigenous sources, with the terrigenous indicators more pronounced near Monterey. Of particular interest, however, is a low-level background of petroleum-related compounds, including 28,30-bisnorhopane and 18??+??(H)-oleanane, which are characteristic of many crude oils from the Monterey Formation of California. Thus, the sediments are overprinted by a regional chemical signature which may be derived from eroded Monterey Formation rocks and from onshore and offshore seeps releasing petroleum from Monterey Formation source rocks. ?? 2002 Elsevier Science B.V. All rights reserved.

Geology and sequence stratigraphy of undiscovered oil and gas resources in conventional and continuous petroleum systems in the Upper Cretaceous Eagle Ford Group and related strata, U.S. Gulf Coast Region

USGS Publications Warehouse

Dubiel, Russell F.; Pearson, Ofori N.; Pitman, Janet K.; Pearson, Krystal M.; Kinney, Scott A.

2012-01-01

The U.S. Geological Survey (USGS) recently assessed the technically recoverable undiscovered oil and gas onshore and in State waters of the Gulf Coast region of the United States. The USGS defined three assessment units (AUs) with potential undiscovered conventional and continuous oil and gas resources in Upper Cretaceous (Cenomanian to Turonian) strata of the Eagle Ford Group and correlative rocks. The assessment is based on geologic elements of a total petroleum system, including hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and traps (formation, timing, and seals). Conventional oil and gas undiscovered resources are in updip sandstone reservoirs in the Upper Cretaceous Tuscaloosa and Woodbine Formations (or Groups) in Louisiana and Texas, respectively, whereas continuous oil and continuous gas undiscovered resources reside in the middip and downdip Upper Cretaceous Eagle Ford Shale in Texas and the Tuscaloosa marine shale in Louisiana. Conventional resources in the Tuscaloosa and Woodbine are included in the Eagle Ford Updip Sandstone Oil and Gas AU, in an area where the Eagle Ford Shale and Tuscaloosa marine shale display vitrinite reflectance (Ro) values less than 0.6%. The continuous Eagle Ford Shale Oil AU lies generally south of the conventional AU, is primarily updip of the Lower Cretaceous shelf edge, and is defined by thermal maturity values within shales of the Eagle Ford and Tuscaloosa that range from 0.6 to 1.2% Ro. Similarly, the Eagle Ford Shale Gas AU is defined downdip of the shelf edge where source rocks have Ro values greater than 1.2%. For undiscovered oil and gas resources, the USGS assessed means of: 1) 141 million barrels of oil (MMBO), 502 billion cubic feet of natural gas (BCFG), and 4 million barrels of natural gas liquids (MMBNGL) in the Eagle Ford Updip Sandstone Oil and Gas AU; 2) 853 MMBO, 1707 BCFG, and 34 MMBNGL in the Eagle Ford Shale Oil AU; and 3) 50,219 BCFG and 2009 MMBNGL in the Eagle Ford Shale Gas AU.

The origin of oil in the Cretaceous succession from the South Pars Oil Layer of the Persian Gulf

NASA Astrophysics Data System (ADS)

Rahmani, Omeid; Aali, Jafar; Junin, Radzuan; Mohseni, Hassan; Padmanabhan, Eswaran; Azdarpour, Amin; Zarza, Sahar; Moayyed, Mohsen; Ghazanfari, Parviz

2013-07-01

The origin of the oil in Barremian-Hauterivian and Albian age source rock samples from two oil wells (SPO-2 and SPO-3) in the South Pars oil field has been investigated by analyzing the quantity of total organic carbon (TOC) and thermal maturity of organic matter (OM). The source rocks were found in the interval 1,000-1,044 m for the Kazhdumi Formation (Albian) and 1,157-1,230 m for the Gadvan Formation (Barremian-Hauterivian). Elemental analysis was carried out on 36 samples from the source rock candidates (Gadvan and Kazhdumi formations) of the Cretaceous succession of the South Pars Oil Layer (SPOL). This analysis indicated that the OM of the Barremian-Hauterivian and Albian samples in the SPOL was composed of kerogen Types II and II-III, respectively. The average TOC of analyzed samples is less than 1 wt%, suggesting that the Cretaceous source rocks are poor hydrocarbon (HC) producers. Thermal maturity and Ro values revealed that more than 90 % of oil samples are immature. The source of the analyzed samples taken from Gadvan and Kazhdumi formations most likely contained a content high in mixed plant and marine algal OM deposited under oxic to suboxic bottom water conditions. The Pristane/nC17 versus Phytane/nC18 diagram showed Type II-III kerogen of mixture environments for source rock samples from the SPOL. Burial history modeling indicates that at the end of the Cretaceous time, pre-Permian sediments remained immature in the Qatar Arch. Therefore, lateral migration of HC from the nearby Cretaceous source rock kitchens toward the north and south of the Qatar Arch is the most probable origin for the significant oils in the SPOL.

Microseismic Precursory Characteristics of Rock Burst Hazard in Mining Areas Near a Large Residual Coal Pillar: A Case Study from Xuzhuang Coal Mine, Xuzhou, China

NASA Astrophysics Data System (ADS)

Cao, An-ye; Dou, Lin-ming; Wang, Chang-bin; Yao, Xiao-xiao; Dong, Jing-yuan; Gu, Yu

2016-11-01

Identification of precursory characteristics is a key issue for rock burst prevention. The aim of this research is to provide a reference for assessing rock burst risk and determining potential rock burst risk areas in coal mining. In this work, the microseismic multidimensional information for the identification of rock bursts and spatial-temporal pre-warning was investigated in a specific coalface which suffered high rock burst risk in a mining area near a large residual coal pillar. Firstly, microseismicity evolution prior to a disastrous rock burst was qualitatively analysed, and the abnormal clustering of seismic sources, abnormal variations in daily total energy release, and event counts can be regarded as precursors to rock burst. Secondly, passive tomographic imaging has been used to locate high seismic activity zones and assess rock burst hazard when the coalface passes through residual pillar areas. The results show that high-velocity or velocity anomaly regions correlated well with strong seismic activities in future mining periods and that passive tomography has the potential to describe, both quantitatively and periodically, hazardous regions and assess rock burst risk. Finally, the bursting strain energy index was further used for short-term spatial-temporal pre-warning of rock bursts. The temporal sequence curve and spatial contour nephograms indicate that the status of the danger and the specific hazardous zones, and levels of rock burst risk can be quantitatively and rapidly analysed in short time and in space. The multidimensional precursory characteristic identification of rock bursts, including qualitative analysis, intermediate and short-time quantitative predictions, can guide the choice of measures implemented to control rock bursts in the field, and provides a new approach to monitor and forecast rock bursts in space and time.

Mineralogy and source rock evaluation of the marine Oligo-Miocene sediments in some wells in the Nile Delta and North Sinai, Egypt

NASA Astrophysics Data System (ADS)

El sheikh, Hassan; Faris, Mahmoud; Shaker, Fatma; Kumral, Mustafa

2016-06-01

This paper aims to study the mineralogical composition and determine the petroleum potential of source rocks of the Oligocene-Miocene sequence in the Nile Delta and North Sinai districts. The studied interval in the five wells can be divided into five rock units arranged from the top to base; Qawasim, Sidi Salem, Kareem, Rudeis, and Qantara formations. The bulk rock mineralogy of the samples was investigated using X-Ray Diffraction technique (XRD). The results showed that the sediments of the Nile Delta area are characterized by the abundance of quartz and kaolinite with subordinate amounts of feldspars, calcite, gypsum, dolomite, and muscovite. On the other hand, the data of the bulk rock analysis at the North Sinai wells showed that kaolinite, quartz, feldspar and calcite are the main constituents associated with minor amounts of dolomite, gypsum, mica, zeolite, and ankerite. Based on the organic geochemical investigations (TOC and Rock-Eval pyrolysis analyses), all studied formations in both areas are thermally immature but in the Nile delta area, Qawasim, Sidi Salem and Qantara formations (El-Temsah-2 Well) are organically-rich and have a good petroleum potential (kerogen Type II-oil-prone), while Rudeis Formation is a poor petroleum potential source rock (kerogen Type III-gas-prone). In the North Sinai area, Qantara Formation has a poor petroleum potential (kerogen Type III-gas-prone) and Sidi Salem Formation (Bardawil-1 Well) is a good petroleum potential source rock (kerogen Type II-oil-prone).

Petroleum systems of the Southeast Tertiary basins and Marbella area, Southeast Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuentes, F.

1996-08-01

This study was done in an area where insufficient organic-rich rocks were available for a reliable oil-source rock correlation. However, oil-rock correlations, molecular characteristics of key horizons, paleofacies maps, maturation and potential migration pathways suggest the Tithonian as a major source rock. Moreover, there is good evidence of high quality source rocks in Oxfordian, Kimmeridgian, Middle-Upper Cretaceous and Paleogene (mainly in the Eocene). Plays were identified in Upper Jurassic oolitic sequences, Early-Middle Cretaceus carbonate platform rocks and breccias, Late Cretaceous basinal fracture carbonates, Paleogene carbonates and breccias, Early-Middle Miocene mounds and submarine fans and isolated carbonate platform sediments and Miocene-Recentmore » turbidites. Seal rocks are shaly carbonates and anhydrites from Tithonian, basinal carbonates and anhydrites from Middle-Upper Cretaceous, basinal carbonates and marls from Upper Cretaceous and Paleogene shales, and bathyal shales from Early Miocene-Recent. The first phase of oil migration from upper Jurassic-Early Cretaceous source rocks occurred in the Early-Middle Cretaceous. In the Upper Cretaceous the Chortis block collided with Chiapas, and as a result mild folding and some hydrocarbons were emplaced to the structural highs. The main phase of structuration and folding of the Sierra de Chiapas started in the Miocene, resulting in well-defined structural traps. Finally, in Plio-Pleistocene the Chortis block was separated, the major compressional period finished and the southern portion of Sierra de Chiapas was raised isostatically. As a result of major subsidence, salt withdrawal and increased burial depth, conditions were created for the generation of liquid hydrocarbons from the Paleogene shales.« less

Hydrocarbon potential of Morocco

DOE Office of Scientific and Technical Information (OSTI.GOV)

Achnin, H.; Nairn, A.E.M.

1988-08-01

Morocco lies at the junction of the African and Eurasian plates and carries a record of their movements since the end of the Precambrian. Four structural regions with basins and troughs can be identified: Saharan (Tarfaya-Ayoun and Tindouf basins); Anti-Atlas (Souss and Ouarzazate troughs and Boudnib basin); the Essaouria, Doukkala, Tadla, Missour, High Plateau, and Guercif basins; and Meseta and Rif (Rharb and Pre-Rif basins). The targets in the Tindouf basin are Paleozoic, Cambrian, Ordovician (clastics), Devonian (limestones), and Carboniferous reservoirs sourced primarily by Silurian shales. In the remaining basins, excluding the Rharb, the reservoirs are Triassic detritals, limestones atmore » the base of the Lias and Dogger, Malm detritals, and sandy horizons in the Cretaceous. In addition to the Silurian, potential source rocks include the Carboniferous and Permo-Carboniferous shales and clays; Jurassic shales, marls, and carbonates; and Cretaceous clays. In the Rharb basin, the objectives are sand lenses within the Miocene marls. The maturation level of the organic matter generally corresponds to oil and gas. The traps are stratigraphic (lenses and reefs) and structural (horsts and folds). The seals in the pre-Jurassic rocks are shales and evaporites; in the younger rocks, shales and marl. Hydrocarbon accumulations have been found in Paleozoic, Triassic, Liassic, Malm, and Miocene rocks.« less

Preliminary investigation of cement materials in the Taif area, Saudi Arabia

USGS Publications Warehouse

Martin, Conrad

1970-01-01

A preliminary investigation of possible sources of cement rock in the Taft area was made during the latter part of August 1968. Adequate deposits of limestone, clay, quartz conglomerate and sandstone, and pisolitic iron ore, yet no gypsum, were located to support a Cement plant should it prove feasible to establish one in this area. These materials, made up mostly of Tertiary and later sediments, crop out in isolated, inconspicuous low hills in a north- trending belt, 10 to 15 kilometers wide, lying about 90 kilometers to-the east of At Taft. The belt extends for more than 90 kilometers from the vicinity of Jabal 'An in the south to the crushed rock pits at Radwan and beyond in the north. The area is readily accessible either from the Talf-Riyadh highway or from the Taif-Bishah road presently under construction. The limestone, which is quite pure and dense in some localities but dolomitic, argillaceous, and cherty in others, occurs in a variety of colors and would make suitable decorative building stone. The volcanic rocks of the Harrat Hadan, lying directly to the east of the limestone belt, include volcanic ash beds some of which may have been altered to bentonitlc clays. Others may have been lithified and might be suitable for light-weight aggregate. These possibilities remain to be investigated. Precambrian metamorphic rocks lying directly to the south and southeast of Taif were also investigated as possible cement rock sources, but no suitable material was found here.

Total Petroleum Systems of the Carpathian - Balkanian Basin Province of Romania and Bulgaria

USGS Publications Warehouse

Pawlewicz, Mark

2007-01-01

The U.S. Geological Survey defined the Moesian Platform Composite Total Petroleum System and the Dysodile Schist-Tertiary Total Petroleum System, which contain three assessment units, in the Carpathian-Balkanian Basin Province of Romania and Bulgaria. The Moesian Platform Assessment Unit, contained within the Moesian Platform Composite Total Petroleum System, is composed of Mesozoic and Cenozoic rocks within the Moesian platform region of southern Romania and northern Bulgaria and also within the Birlad depression in the northeastern platform area. In Romania, hydrocarbon sources are identified as carbonate rocks and bituminous claystones within the Middle Devonian, Middle Jurassic, Lower Cretaceous, and Neogene stratigraphic sequences. In the Birlad depression, Neogene pelitic strata have the best potential for generating hydrocarbons. In Bulgaria, Middle and Upper Jurassic shales are the most probable hydrocarbon sources. The Romania Flysch Zone Assessment Unit in the Dysodile Schist-Tertiary Total Petroleum System encompasses three structural and paleogeographic subunits within the Pre-Carpathian Mountains region: (1) the Getic depression, a segment of the Carpathian foredeep; (2) the flysch zone of the eastern Carpathian Mountains (also called the Marginal Fold nappe); and (3) the Miocene zone (also called the Sub-Carpathian nappe). Source rocks are interpreted to be Oligocene dysodile schist and black claystone, along with Miocene black claystone and marls. Also part of the Dysodile Schist-Tertiary Total Petroleum System is the Romania Ploiesti Zone Assessment Unit, which includes a zone of diapir folds. This zone lies between the Rimnicu Sarat and Dinibovita valleys and between the folds of the inner Carpathian Mountains and the external flanks of the Carpathian foredeep. The Oligocene Dysodile Schist is considered the main hydrocarbon source rock and Neogene black marls and claystones are likely secondary sources; all are thought to be at their maximum thermal maturation. Undiscovered resources in the Carpathian-Balkanian Basin Province are estimated, at the mean, to be 2,076 billion cubic feet of gas, 1,013 million barrels of oil, and 116 million barrels of natural gas liquids.

Nd, Sr and O isotopic study of the petrogenesis of two syntectonic members of the New Hampshire Plutonic Series

NASA Astrophysics Data System (ADS)

Lathrop, A. S.; Blum, Joel D.; Chamberlain, C. Page

1996-07-01

Nd, Sr and O isotope systematics were used to investigate the petrogenesis of two adjacent plutons of the Bethlehem Gneiss (BG) and the Kinsman Quartz Monzonite (KQM), exposed within the Central Maine Terrane (CMT) of New England. Both are Acadian-aged (≈413 Ma) synmetamorphic and syntectonic members of the New Hampshire Plutonic Series (NHPS). Potential source rocks analyzed for this study include Silurian and Devonian metasedimentary rocks of the CMT, and Ordovician metasedimentary rocks and granitic gneisses of the Bronson Hill Anticlinorium (BHA), which border the CMT to the west. The ɛSr(413), ɛNd(413) and δ18O values for the KQM range from 56.3 to 120.0, 2.8 to -6.4, and 7.6‰ to 12.9‰, respectively; values for the BG range from 7.4 to 144.7, 0.6 to -9.3, and 8.3‰ to 11.3‰, respectively; and values for possible source rocks range from 38.1 to 654.2, -10.7 to 5.4, and 6.2‰ to 14.1‰, respectively. Both the BG and KQM have extremely heterogeneous initial isotopic compositions consistent with mixing of multiple crustal source rocks, and neither contains a volumetrically significant (i.e., ≥10%) mantlederived component. Overlapping values of ɛNd(413), ɛSr(413) and δ18O values for both the BG and KQM samples resemble values for metasedimentary host rocks of the CMT and BHA. We observe no systematic correlations between ɛNd and ɛSr values for either the BG or the KQM. The ɛSr and δ18O values for the BG do not form any simple mixing trends, nor is there any direct correlation between the isotopic compositions of contact BG samples and their adjacent host rocks, in contrast to our observations for the KQM (Lathrop et al. 1994). We propose that the KQM and BG magmas were generated through anatexis of metasedimentary rocks from both the BHA and CMT in response to crystal thickening during the Acadian orogeny. Melting may have been initiated within CMT metasediments in response to high heat production in these mid-crustal rocks combined with crustal thickening, whereas melting of BHA rocks with normal crustal heat production, which were located at lower-crustal levels than CMT rocks, is likely to have been driven by crustal thickening alone. Following upward advection of mobile BHA magmas, BHA- and CMT-derived magmas may have mingled during complex Acadian deformation in the CMT, thus accounting for the isotopic similarities we observe between the BG and the KQM.

Chapter 1: Executive Summary - 2003 Assessment of Undiscovered Oil and Gas Resources in the Upper Cretaceous Navarro and Taylor Groups, Western Gulf Province, Gulf Coast Region, Texas

USGS Publications Warehouse

,

2006-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Upper Cretaceous Navarro and Taylor Groups in the Western Gulf Province of the Gulf Coast region (fig. 1) as part of a national oil and gas assessment effort (USGS Navarro and Taylor Groups Assessment Team, 2004). The assessment of the petroleum potential of the Navarro and Taylor Groups was based on the general geologic elements used to define a total petroleum system (TPS), including hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined five assessment units (AU) in the Navarro and Taylor Groups as parts of a single TPS, the Smackover-Austin-Eagle Ford Composite TPS: Travis Volcanic Mounds Oil AU, Uvalde Volcanic Mounds Gas and Oil AU, Navarro-Taylor Updip Oil and Gas AU, Navarro-Taylor Downdip Gas and Oil AU, and Navarro-Taylor Slope-Basin Gas AU (table 1).

Evaluating Re-Os systematics in organic-rich sedimentary rocks in response to petroleum generation using hydrous pyrolysis experiments

USGS Publications Warehouse

Rooney, A.D.; Selby, D.; Lewan, M.D.; Lillis, P.G.; Houzay, J.-P.

2012-01-01

Successful application of the 187Re–187Os geochronometer has enabled the determination of accurate and precise depositional ages for organic-rich sedimentary rocks (ORS) as well as establishing timing constraints of petroleum generation. However, we do not fully understand the systematics and transfer behaviour of Re and Os between ORS and petroleum products (e.g., bitumen and oil). To more fully understand the behaviour of Re–Os systematics in both source rocks and petroleum products we apply hydrous pyrolysis to two immature hydrocarbon source rocks: the Permian Phosphoria Formation (TOC = 17.4%; Type II-S kerogen) and the Jurassic Staffin Formation (TOC = 2.5%; Type III kerogen). The laboratory-based hydrous pyrolysis experiments were carried out for 72 h at 250, 300, 325 and 350 °C. These experiments provided us with whole rock, extracted rock and bitumen and in some cases expelled oil and asphaltene for evaluation of Re–Os isotopic and elemental abundance. The data from these experiments demonstrate that the majority (>95%) of Re and Os are housed within extracted rock and that thermal maturation does not result in significant transfer of Re or Os from the extracted rock into organic phases. Based on existing thermodynamic data our findings suggest that organic chelating sites have a greater affinity for the quadravalent states of Re and Os than sulphides. Across the temperature range of the hydrous pyrolysis experiments both whole rock and extracted rock 187Re/188Os ratios show small variations (3.3% and 4.7%, for Staffin, respectively and 6.3% and 4.9% for Phosphoria, respectively). Similarly, the 187Os/188Os ratios show only minor variations for the Staffin and Phosphoria whole rock and extracted rock samples (0.6% and 1.4% and 1.3% and 2.2%). These isotopic data strongly suggest that crude oil generation through hydrous pyrolysis experiments does not disturb the Re–Os systematics in ORS as supported by various studies on natural systems. The elemental abundance data reveal limited transfer of Re and Os into the bitumen from a Type III kerogen in comparison to Type II-S kerogen (0.02% vs. 3.7%), suggesting that these metals are very tightly bound in Type III kerogen structure. The 187Os/188Os data from the pyrolysis generated Phosphoria bitumens display minor variation (4%) across the experimental temperatures, with values similar to that of the source rock. This indicates that the isotopic composition of the bitumen reflects the isotopic composition of the source rock at the time of petroleum generation. These data further support the premise that the Os isotopic composition of oils and bitumens can be used to fingerprint petroleum deposits to specific source rocks. Oil generated through the hydrous pyrolysis experiments does not contain appreciable quantities of Re or Os (~120 and ~3 ppt, respectively), in contrast to natural oils (2–50 ppb and 34–288 ppt for Re and Os, respectively), which may suggest that kinetic parameters are fundamental to the transfer of Re and Os from source rocks to oils. From this we hypothesise that, at the temperatures employed in hydrous pyrolysis, Re and Os are assimilated into the extracted rock as a result of cross-linking reactions.

Evaluating Re-Os systematics in organic-rich sedimentary rocks in response to petroleum generation using hydrous pyrolysis experiments

NASA Astrophysics Data System (ADS)

Rooney, Alan D.; Selby, David; Lewan, Michael D.; Lillis, Paul G.; Houzay, Jean-Pierre

2012-01-01

Successful application of the 187Re-187Os geochronometer has enabled the determination of accurate and precise depositional ages for organic-rich sedimentary rocks (ORS) as well as establishing timing constraints of petroleum generation. However, we do not fully understand the systematics and transfer behaviour of Re and Os between ORS and petroleum products (e.g., bitumen and oil). To more fully understand the behaviour of Re-Os systematics in both source rocks and petroleum products we apply hydrous pyrolysis to two immature hydrocarbon source rocks: the Permian Phosphoria Formation (TOC = 17.4%; Type II-S kerogen) and the Jurassic Staffin Formation (TOC = 2.5%; Type III kerogen). The laboratory-based hydrous pyrolysis experiments were carried out for 72 h at 250, 300, 325 and 350 °C. These experiments provided us with whole rock, extracted rock and bitumen and in some cases expelled oil and asphaltene for evaluation of Re-Os isotopic and elemental abundance. The data from these experiments demonstrate that the majority (>95%) of Re and Os are housed within extracted rock and that thermal maturation does not result in significant transfer of Re or Os from the extracted rock into organic phases. Based on existing thermodynamic data our findings suggest that organic chelating sites have a greater affinity for the quadravalent states of Re and Os than sulphides. Across the temperature range of the hydrous pyrolysis experiments both whole rock and extracted rock 187Re/188Os ratios show small variations (3.3% and 4.7%, for Staffin, respectively and 6.3% and 4.9% for Phosphoria, respectively). Similarly, the 187Os/188Os ratios show only minor variations for the Staffin and Phosphoria whole rock and extracted rock samples (0.6% and 1.4% and 1.3% and 2.2%). These isotopic data strongly suggest that crude oil generation through hydrous pyrolysis experiments does not disturb the Re-Os systematics in ORS as supported by various studies on natural systems. The elemental abundance data reveal limited transfer of Re and Os into the bitumen from a Type III kerogen in comparison to Type II-S kerogen (0.02% vs. 3.7%), suggesting that these metals are very tightly bound in Type III kerogen structure. The 187Os/188Os data from the pyrolysis generated Phosphoria bitumens display minor variation (4%) across the experimental temperatures, with values similar to that of the source rock. This indicates that the isotopic composition of the bitumen reflects the isotopic composition of the source rock at the time of petroleum generation. These data further support the premise that the Os isotopic composition of oils and bitumens can be used to fingerprint petroleum deposits to specific source rocks. Oil generated through the hydrous pyrolysis experiments does not contain appreciable quantities of Re or Os (∼120 and ∼3 ppt, respectively), in contrast to natural oils (2-50 ppb and 34-288 ppt for Re and Os, respectively), which may suggest that kinetic parameters are fundamental to the transfer of Re and Os from source rocks to oils. From this we hypothesise that, at the temperatures employed in hydrous pyrolysis, Re and Os are assimilated into the extracted rock as a result of cross-linking reactions.

Environmentally Friendly, Rheoreversible, Hydraulic-fracturing Fluids for Enhanced Geothermal Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shao, Hongbo; Kabilan, Senthil; Stephens, Sean A.

Cost-effective creation of high-permeability reservoirs inside deep crystalline bedrock is the primary challenge for the feasibility of enhanced geothermal systems (EGS). Current reservoir stimulation entails adverse environmental impacts and substantial economic costs due to the utilization of large volumes of water “doped” with chemicals including rheology modifiers, scale and corrosion inhibitors, biocides, friction reducers among others where, typically, little or no information of composition and toxicity is disclosed. An environmentally benign, CO2-activated, rheoreversible fracturing fluid has recently been developed that significantly enhances rock permeability at effective stress significantly lower than current technology. We evaluate the potential of this novel fracturingmore » fluid for application on geothermal sites under different chemical and geomechanical conditions, by performing laboratory-scale fracturing experiments with different rock sources under different confining pressures, temperatures, and pH environments. The results demonstrate that CO2-reactive aqueous solutions of environmentally amenable Polyallylamine (PAA) represent a highly versatile fracturing fluid technology. This fracturing fluid creates/propagates fracture networks through highly impermeable crystalline rock at significantly lower effective stress as compared to control experiments where no PAA was present, and permeability enhancement was significantly increased for PAA compared to conventional hydraulic fracturing controls. This was evident in all experiments, including variable rock source/type, operation pressure and temperature (over the entire range for EGS applications), as well as over a wide range of formation-water pH values. This versatile novel fracturing fluid technology represents a great alternative to industrially available fracturing fluids for cost-effective and competitive geothermal energy production.« less

Lunar "dunite", "pyroxenite" and "anorthosite"

USGS Publications Warehouse

Wilshire, H.G.; Jackson, E.D.

1972-01-01

Monomineralic aggregates of olivine, clinopyroxene, orthopyroxene and plagioclase with granoblastic textures are widespread minor constituents of Apollo 14 breccias. Recrystallization is commonly incomplete within these aggregates, leaving relict material that clearly indicates single-mineral-grain sources for the aggregates. The aggregates are not, therefore, properly characterized by igneous rock names, nor can any conclusions regarding differentiation be drawn from them. Average sizes of the aggregates indicate source rocks with grain sizes mostly larger than 1 to 5 mm, a few clasts of which occur in the breccias; the proportions of the different types of aggregates suggest dominantly feldspathic source rocks. ?? 1972.

Geochemical constraints on the petrogenesis of the pyroclastic rocks in Abakaliki basin (Lower Benue Rift), Southeastern Nigeria

NASA Astrophysics Data System (ADS)

Chukwu, Anthony; Obiora, Smart C.

2018-05-01

The pyroclastic rocks in the Cretaceous Abakaliki basin occur mostly as oval-shaped bodies, consisting of lithic/lava and vitric fragments. They are commonly characterized by parallel and cross laminations, as well contain xenoliths of shale, mudstone and siltstones from the older Asu River Group of Albian age. The rocks are basic to ultrabasic in composition, comprising altered alkali basalts, altered tuffs, minor lapillistones and agglomerates. The mineral compositions are characterized mainly by laths of calcic plagioclase, pyroxene (altered), altered olivines and opaques. Calcite, zeolite and quartz represent the secondary mineral constituents. Geochemically, two groups of volcaniclastic rocks, are distinguished: alkaline and tholeiitic rocks, both represented by fresh and altered rock samples. The older alkali basalts occur within the core of the Abakaliki anticlinorium while the younger tholeiites occur towards the periphery. Though most of the rocks are moderate to highly altered [Loss on ignition (LOI, 3.43-22.07 wt. %)], the use of immobile trace element such as Nb, Zr, Y, Hf, Ti, Ta and REEs reflect asthenospheric mantle source compositions. The rocks are enriched in incompatible elements and REEs (∑REE = 87.98-281.0 ppm for alkaline and 69.45-287.99 ppm for tholeiites). The ratios of La/Ybn are higher in the alkaline rocks ranging from 7.69 to 31.55 compared to the tholeiitic rocks which range from 4.4 to 16.89 and indicating the presence of garnet-bearing lherzolite in the source mantle. The spidergrams and REEs patterns along with Zr/Nb, Ba/Nb, Rb/Nb ratios suggest that the rocks were generated by a mantle plume from partial melting of mixed enriched mantle sources (HIMU, EMI and EMII) similar to the rocks of the south Atlantic Ocean such as St. Helena (alkaline rocks) and Ascension rocks (tholeiitic rocks). The rocks were formed in a within-plate setting of the intra-continental rift type similar to other igneous rocks in the Benue Rift and are not related to any subduction event as previously suggested.

Assessment of undiscovered hydrocarbon resources of sub-Saharan Africa

USGS Publications Warehouse

Brownfield, Michael E.

2016-01-01

The assessment was geology-based and used the total petroleum system (TPS) concept. The geologic elements of a TPS are hydrocarbon source rocks (source rock maturation and hydrocarbon generation and migration), reservoir rocks (quality and distribution), and traps where hydrocarbon accumulates. Using these geologic criteria, 16 conventional total petroleum systems and 18 assessment units in the 13 provinces were defined. The undiscovered, technically recoverable oil and gas resources were assessed for all assessment units.

Large-N Over the Source Physics Experiment (SPE) Phase I and Phase II Test Beds

NASA Astrophysics Data System (ADS)

Snelson, C. M.; Carmichael, J. D.; Mellors, R. J.; Abbott, R. E.

2014-12-01

One of the current challenges in the field of monitoring and verification is source discrimination of low-yield nuclear explosions from background seismicity, both natural and anthropogenic. Work is underway at the Nevada National Security Site to conduct a series of chemical explosion experiments using a multi-institutional, multi-disciplinary approach. The goal of this series of experiments, called the Source Physics Experiments (SPE), is to refine the understanding of the effect of earth structures on source phenomenology and energy partitioning in the source region, the transition of seismic energy from the near field to the far field, and the development of S waves observed in the far field. To fully explore these problems, the SPE series includes tests in both hard and soft rock geologic environments. The project comprises a number of activities, which range from characterizing the shallow subsurface to acquiring new explosion data from both the near field (<100 m) and the far field (>100 m). SPE includes a series of planned explosions (with different yields and depths of burials), which are conducted in the same hole and monitored by a diverse set of sensors recording characteristics of the explosions, ground-shock, seismo-acoustic energy propagation. This presentation focuses on imaging the full 3D wavefield over hard rock and soft rock test beds using a large number of seismic sensors. This overview presents statistical analyses of optimal sensor layout required to estimate wavefield discriminants and the planned deployment for the upcoming experiments. This work was conducted under Contract No. DE-AC52-06NA25946 with the U.S. Department of Energy. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Geology of the Plumtree area, Spruce Pine district, North Carolina

USGS Publications Warehouse

Brobst, Donald Albert

1953-01-01

This report describes the results of study and geologic mapping (1:12,000) in the 70-square-mile Plumtree area in the northeastern part of the Spruce Pine pegmatite district, on the Blue Ridge upland in western North Carolina. The district has been the chief domestic source of feldspar and sheet mica. The mining belt just west of the Blue Ridge Front trends northeast and is 25 miles long and 10 miles wide. The center of the Plumtree area lies 10 miles northeast of Spruce Pine pegmatite district, on the Blue Ridge upland in western North Carolina. The district has been the chief domestic source of feldspar and sheet mica. The mining belt just west of the Blue Ridge Front trends northeast and is 25 miles long and 10 miles wide. The center of the Plumtree area lies 10 miles northeast of Spruce Pine and includes parts of Mitchell and Avery Counties shown on the portions of the 7.5-minute Spruce Pine, Linville Falls, Newland, North Carolina, and Carvers Gap, North Carolina and Tennessee quadrangle. The topography varies from rugged mountains to rounded or flat topped hills near the entrenched, meandering master streams. Old erosion surfaces are approximately 600,1,100, 1,500, and 2,500 feet above the present master stream level. The area is in late youth or early maturity after rejuvenation.. The regionally metamorphosed rocks of the amophibolite facies form three mappable units: mica gneiss, mica schist, and hornblende rock. These rocks, perhaps of Precambrian age, are intimately interlayered with thicknesses of the individual layers ranging from less than one inch to several tons of feet. Field relationships and chemical data suggest that the mica (Carolina-type) rocks were derived from sandstones, graywackes, and shales and that the hornblende-rich (Roan-type) layers were derived from impure carbonate rocks. The igneous rocks include alaskite and associated pegmatite of early Paleozoic age (?), dunite and associated soapstone of a prepegmatite age, and a few diabasic dikes of post-pegmatite age (Triassic?). The alaskite and pegmatite have similar bulk compositions, notably low in iron (0.3 percent). The major constituents in order of decreasing abundance are plagioclase, perthitic microcline, quartz, and muncovite. All of these minerals, as well as clay deposits derived from the weathering of alaskite under old terraces, have economic value. The zoned pegmatites contain fewer zones which are less complex mineralogically than those in the pegmatites of many other areas. These essentially unmetamorphosed bodies were intruded approximately at the peak of the regional metamorphism. Their emplacement was controlled by local structure and rock type. The source of this igneous material may have been the mobilized portions of the Cranberry gneiss which underlies the area. The dunite bodies were intruded early in the metamorphic cycle. The bodies are commonly zoned: from the wall rock inwards (1) talc-antrophyllite-serpentine fringe, (3) serpentinized dunite, (3) granular olivine core. Dunite, chromite, vermiculite, and anthophyllite are the major economic commodities. Extensive hydrothermal alteration of dunite bodies produced soapstone. The area is the northeast end of a southwest plunging synclinorium about 20 miles wide with the steeper limb on the northwest side. There are three structural zones: zone I on the northwest is characterized by the northeast-trending isoclinal folds with steep southeast dips; zone II on the southwest includes an area of rocks with low and variable dip; zone III is the complex central core. In the extreme northeast zones I and II have an indistinct boundary where they coalesce along the rim of the synclinorium. Six stratigraphic units are exposed totaling approximately 10,500 feet of metamorphic rocks. Small scale structural features include a foliation, and a lineation in the planes of the foliation. Minor folding reflects the trends of the major structures. There are randomly orient

Petroleum system of the Shelf Rift Basin, East China Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cunningham, A.C.; Armentrout, J.M.; Prebish, M.

1996-12-31

The Tertiary section of the Oujioang and Quiontang Depressions of the East China Sea Basin consists of at least eight rift-related depositional sequences identified seismically by regionally significant onlap and truncation surfaces. These sequences are calibrated by several wells including the Wenzhou 6-1-1 permitting extrapolation of petroleum system elements using seismic facies analysis. Gas and condensate correlated to non-marine source rocks and reservoired in sandstone at the Pinghu field to the north of the study area provides an known petroleum system analogue. In the Shelf Rift Basin, synrift high-amplitude parallel reflections within the graben axes correlate with coaly siltstone stratamore » and are interpreted as coastal plain and possibly lacustrine facies with source rock potential. Synrift clinoform seismic facies prograding from the northwest footwall correlate with non-marine to marginal marine conglomerate, sandstone and siltstone, and are interpreted as possible delta or fan-delta facies with reservoir potential although porosity and permeability is low within the Wenzhou 6-1-1 well. Post-rift thermal sag sequences are characterized by parallel and relatively continuous seismic reflections and locally developed clinoform packages. These facies correlate with porous and permeable marine sandstone and siltstone. Shales of potential sealing capacity occur within marine flooding intervals of both the synrift and post-rift sequences. Traps consist of differentially rotated synrift fill, and post-rift inversion anticlines. Major exploration risk factors include migration from the synrift coaly source rocks to the post-rift porous and permeable sandstones, and seismic imaging and drilling problems associated with extensive Tertiary igneous intrusions.« less

Petroleum system of the Shelf Rift Basin, East China Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cunningham, A.C.; Armentrout, J.M.; Prebish, M.

1996-01-01

The Tertiary section of the Oujioang and Quiontang Depressions of the East China Sea Basin consists of at least eight rift-related depositional sequences identified seismically by regionally significant onlap and truncation surfaces. These sequences are calibrated by several wells including the Wenzhou 6-1-1 permitting extrapolation of petroleum system elements using seismic facies analysis. Gas and condensate correlated to non-marine source rocks and reservoired in sandstone at the Pinghu field to the north of the study area provides an known petroleum system analogue. In the Shelf Rift Basin, synrift high-amplitude parallel reflections within the graben axes correlate with coaly siltstone stratamore » and are interpreted as coastal plain and possibly lacustrine facies with source rock potential. Synrift clinoform seismic facies prograding from the northwest footwall correlate with non-marine to marginal marine conglomerate, sandstone and siltstone, and are interpreted as possible delta or fan-delta facies with reservoir potential although porosity and permeability is low within the Wenzhou 6-1-1 well. Post-rift thermal sag sequences are characterized by parallel and relatively continuous seismic reflections and locally developed clinoform packages. These facies correlate with porous and permeable marine sandstone and siltstone. Shales of potential sealing capacity occur within marine flooding intervals of both the synrift and post-rift sequences. Traps consist of differentially rotated synrift fill, and post-rift inversion anticlines. Major exploration risk factors include migration from the synrift coaly source rocks to the post-rift porous and permeable sandstones, and seismic imaging and drilling problems associated with extensive Tertiary igneous intrusions.« less

Detrital Zircons From the Jack Hills and Mount Narryer, Western Australia: Geochronological, Morphological, and Geochemical Evidence for Diverse >4000 Ma Source Rocks

NASA Astrophysics Data System (ADS)

Crowley, J. L.; Myers, J. S.; Sylvester, P. J.; Cox, R. A.

2004-05-01

Detrital zircons from all major clastic units in the Jack Hills and Mount Narryer metasedimentary belts, Western Australia, were analyzed for morphology, internal zoning, inclusion mineralogy, age, and trace element concentrations (latter two obtained by laser-ablation microprobe ICPMS). The results show that zircons were derived from a wide diversity of rocks, including previously described, >4000 Ma grains that are older than any known terrestrial rocks. In three metaconglomerate samples from the western Jack Hills, 4200-3800 Ma zircons ("old grains") comprise 14% of the population, 3800-3600 Ma grains form only 2%, and 3550-3250 Ma zircons ("young grains") are dominant with a significant peak at 3380 Ma. Old and young grains are interpreted as being from similar rock types because they are indistinguishable in trace element concentrations, size (several hundred microns), morphology (subequant, typically fragmented), internal zoning (typically both oscillatory and sector), and U concentration (50-200 ppm). Many of these properties suggest an intermediate plutonic source, whereas an evolved granitic source was previously interpreted from rare-earth element and oxygen isotope data. Detrital zircons in quartzites and metaconglomerates at Mount Narryer differ significantly from zircons from the western Jack Hills. Old grains comprise only 3% (most of which are 4200-4100 Ma), 3800-3600 Ma zircons form 31%, and there are peaks at 3650, 3600, and 3500 Ma. Old and young grains have similar properties that suggest granitic sources, such as elongate prismatic morphology, oscillatory zoning, high U concentrations (100-600 ppm), and xenotime and monazite inclusions. Trace element concentrations are broadly similar to those in Jack Hills zircons, with notable exceptions being generally higher U, smaller Ce and Eu anomalies, and lower Nb/Ta. It is considered unlikely that Jack Hills zircons were derived from granitic gneisses that surround the metasedimentary belts because only a few detrital grains match gneiss zircons in age, morphology, and U concentration. The sources were probably distal, or perhaps destroyed or removed from the region during Neoarchean tectonism. In contrast, Mount Narryer zircons are similar to gneiss zircons, suggesting they were derived from the gneisses, which may include a minor, currently undiscovered 4200-4100 Ma granitic component. Such diversity in age and nature of Hadean detrital zircons is compelling evidence that Earth's crust was heterogeneous by 4200 Ma.

Expectations of Rock Music Consumption for Entertainment and Information Relative to the Active Involvement of the User.

ERIC Educational Resources Information Center

Rouner, Donna; Noyes, Amy

Before examining potentially negative effects of rock music on adolescents, it is necessary to demonstrate links between adolescent motivations for consuming rock music and active involvement relative to that use and also to consider how much rock listeners rely on rock music as a source for information about values, beliefs, and social…

Factors controlling the regional distribution of vanadium in ground water

USGS Publications Warehouse

Wright, Michael T.; Belitz, Kenneth

2010-01-01

Although the ingestion of vanadium (V) in drinking water may have possible adverse health effects, there have been relatively few studies of V in groundwater. Given the importance of groundwater as a source of drinking water in many areas of the world, this study examines the potential sources and geochemical processes that control the distribution of V in groundwater on a regional scale. Potential sources of V to groundwater include dissolution of V rich rocks, and waste streams from industrial processes. Geochemical processes such as adsorption/desorption, precipitation/dissolution, and chemical transformations control V concentrations in groundwater. Based on thermodynamic data and laboratory studies, V concentrations are expected to be highest in samples collected from oxic and alkaline groundwater. However, the extent to which thermodynamic data and laboratory results apply to the actual distribution of V in groundwater is not well understood. More than 8400 groundwater samples collected in California were used in this study. Of these samples, high (> or = 50 μg/L) and moderate (25 to 49 μg/L) V concentrations were most frequently detected in regions where both source rock and favorable geochemical conditions occurred. The distribution of V concentrations in groundwater samples suggests that significant sources of V are mafic and andesitic rock. Anthropogenic activities do not appear to be a significant contributor of V to groundwater in this study. High V concentrations in groundwater samples analyzed in this study were almost always associated with oxic and alkaline groundwater conditions, which is consistent with predictions based on thermodynamic data.

The significance of pre-existing, deeply weathered crystalline rock in interpreting the effects of glaciation in the Minnesota River valley, U.S.A.

USGS Publications Warehouse

Patterson, C.J.; Boerboom, Terrence

1999-01-01

Minnesota is largely underlain by Precambrian crystalline bedrock that was weathered to an average depth of 30 m prior to Late Cretaceous time. The fresh-rock-weathered-rock interface is irregular, with as much as 45 m of relief. Weathering exploited joints, locally isolating meter-sized volumes of rock known as corestones. Variable amounts of residuum were removed through glaciation to leave (1) saprolite overlain by an in-situ Late Cretaceous soil profile; (2) partially eroded saprolite; and (3) undulating fresh rock surfaces (commonly mantled by rounded boulders) that display striae and glacial or fluvial polish. Significant subglacial erosion of fresh bedrock is not required to form smoothly undulating bedrock surfaces with closed depressions; they may also form through removal of weathered bedrock and exposure of the weathering front. Large rounded boulders are not always shaped during transport; they may represent chemically rounded corestones resting at or near the bedrock source. Unambiguous evidence for glacial erosion includes striae and streamlining of bedrock parallel to striae. Polish on rock can be created fluvially, and smoothed grooves and ridges in the rock may be chemically produced. Many rounded boulders found in glacial till and strewn on bedrock surfaces probably originated as corestones.

Petroleum generation and migration in the Mesopotamian Basin and Zagros fold belt of Iraq: Results from a basin-modeling study

USGS Publications Warehouse

Pitman, Janet K.; Steinshouer, D.; Lewan, M.D.

2004-01-01

A regional 3-D total petroleum-system model was developed to evaluate petroleum generation and migration histories in the Mesopotamian Basin and Zagros fold belt in Iraq. The modeling was undertaken in conjunction with Middle East petroleum assessment studies conducted by the USGS. Regional structure maps, isopach and facies maps, and thermal maturity data were used as input to the model. The oil-generation potential of Jurassic source-rocks, the principal known source of the petroleum in Jurassic, Cretaceous, and Tertiary reservoirs in these regions, was modeled using hydrous pyrolysis (Type II-S) kerogen kinetics. Results showed that oil generation in source rocks commenced in the Late Cretaceous in intrashelf basins, peak expulsion took place in the late Miocene and Pliocene when these depocenters had expanded along the Zagros foredeep trend, and generation ended in the Holocene when deposition in the foredeep ceased. The model indicates that, at present, the majority of Jurassic source rocks in Iraq have reached or exceeded peak oil generation and most rocks have completed oil generation and expulsion. Flow-path simulations demonstrate that virtually all oil and gas fields in the Mesopotamian Basin and Zagros fold belt overlie mature Jurassic source rocks (vertical migration dominated) and are situated on, or close to, modeled migration pathways. Fields closest to modeled pathways associated with source rocks in local intrashelf basins were charged earliest from Late Cretaceous through the middle Miocene, and other fields filled later when compression-related traps were being formed. Model results confirm petroleum migration along major, northwest-trending folds and faults, and oil migration loss at the surface.

Variability over time in the sources of South Portuguese Zone turbidites: evidence of denudation of different crustal blocks during the assembly of Pangaea

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Ribeiro, C.; Vilallonga, F.; Chichorro, M.; Drost, K.; Silva, J. B.; Albardeiro, L.; Hofmann, M.; Linnemann, U.

2014-07-01

This study combines geochemical and geochronological data in order to decipher the provenance of Carboniferous turbidites from the South Portuguese Zone (SW Iberia). Major and trace elements of 25 samples of graywackes and mudstones from the Mértola (Visean), Mira (Serpukhovian), and Brejeira (Moscovian) Formations were analyzed, and 363 U-Pb ages were obtained on detrital zircons from five samples of graywackes from the Mira and Brejeira Formations using LA-ICPMS. The results indicate that turbiditic sedimentation during the Carboniferous was marked by variability in the sources, involving the denudation of different crustal blocks and a break in synorogenic volcanism. The Visean is characterized by the accumulation of immature turbidites (Mértola Formation and the base of the Mira Formation) inherited from a terrane with intermediate to mafic source rocks. These source rocks were probably formed in relation to Devonian magmatic arcs poorly influenced by sedimentary recycling, as indicated by the almost total absence of pre-Devonian zircons typical of the Gondwana and/or Laurussia basements. The presence of Carboniferous grains in Visean turbidites indicates that volcanism was active at this time. Later, Serpukhovian to Moscovian turbiditic sedimentation (Mira and Brejeira Formations) included sedimentary detritus derived from felsic mature source rocks situated far from active magmatism. The abundance of Precambrian and Paleozoic zircons reveals strong recycling of the Gondwana and/or Laurussia basements. A peri-Gondwanan provenance is indicated by zircon populations with Neoproterozoic (Cadomian-Avalonian and Pan-African zircon-forming events), Paleoproterozoic, and Archean ages. The presence of late Ordovician and Silurian detrital zircons in Brejeira turbidites, which have no correspondence in the Gondwana basement of SW Iberia, indicates Laurussia as their most probable source.

Osmium Isotopic Evolution of the Mantle Sources of Precambrian Ultramafic Rocks

NASA Astrophysics Data System (ADS)

Gangopadhyay, A.; Walker, R. J.

2006-12-01

The Os isotopic composition of the modern mantle, as recorded collectively by ocean island basalts, mid- oceanic ridge basalts (MORB) and abyssal peridotites, is evidently highly heterogeneous (γ Os(I) ranging from <-10 to >+25). One important question, therefore, is how and when the Earth's mantle developed such large-scale Os isotopic heterogeneities. Previous Os isotopic studies of ancient ultramafic systems, including komatiites and picrites, have shown that the Os isotopic heterogeneity of the terrestrial mantle can be traced as far back as the late-Archean (~ 2.7-2.8 Ga). This observation is based on the initial Os isotopic ratios obtained for the mantle sources of some of the ancient ultramafic rocks determined through analyses of numerous Os-rich whole-rock and/or mineral samples. In some cases, the closed-system behavior of these ancient ultramafic rocks was demonstrated via the generation of isochrons of precise ages, consistent with those obtained from other radiogenic isotopic systems. Thus, a compilation of the published initial ^{187}Os/^{188}Os ratios reported for the mantle sources of komatiitic and picritic rocks is now possible that covers a large range of geologic time spanning from the Mesozoic (ca. 89 Ma Gorgona komatiites) to the Mid-Archean (e.g., ca. 3.3 Ga Commondale komatiites), which provides a comprehensive picture of the Os isotopic evolution of their mantle sources through geologic time. Several Precambrian komatiite/picrite systems are characterized by suprachondritic initial ^{187}Os/^{188}Os ratios (e.g., Belingwe, Kostomuksha, Pechenga). Such long-term enrichments in ^{187}Os of the mantle sources for these rocks may be explained via recycling of old mafic oceanic crust or incorporation of putative suprachondritic outer core materials entrained into their mantle sources. The relative importance of the two processes for some modern mantle-derived systems (e.g., Hawaiian picrites) is an issue of substantial debate. Importantly, however, the high-precision initial Os isotopic compositions of the majority of ultramafic systems show strikingly uniform initial ^{187}Os/^{188}Os ratios, consistent with their derivation from sources that had Os isotopic evolution trajectory very similar to that of carbonaceous chondrites. In addition, the Os isotopic evolution trajectories of the mantle sources for most komatiites show resolvably lower average Re/Os than that estimated for the Primitive Upper Mantle (PUM), yet significantly higher than that obtained in some estimates for the modern convecting upper mantle, as determined via analyses of abyssal peridotites. One possibility is that most of the komatiites sample mantle sources that are unique relative to the sources of abyssal peridotites and MORB. Previous arguments that komatiites originate via large extents of partial melting of relatively deep upper mantle, or even lower mantle materials could, therefore, implicate a source that is different from the convecting upper mantle. If so, this source is remarkably uniform in its long-term Re/Os, and it shows moderate depletion in Re relative to the PUM. Alternatively, if the komatiites are generated within the convective upper mantle through relatively large extents of partial melting, they may provide a better estimate of the Os isotopic composition of the convective upper mantle than that obtained via analyses of MORB, abyssal peridotites and ophiolites.

Archaean tectonic systems: A view from igneous rocks

NASA Astrophysics Data System (ADS)

Moyen, Jean-François; Laurent, Oscar

2018-03-01

This work examines the global distribution of Archaean and modern igneous rock's compositions, without relying on preconceptions about the link between rock compositions and tectonic sites (in contrast with "geotectonic" diagrams). Rather, Archaean and modern geochemical patterns are interpreted and compared in terms of source and melting conditions. Mafic rocks on the modern Earth show a clear chemical separation between arc and non-arc rocks. This points to the first order difference between wet (arc) and dry (mid-ocean ridges and hotspots) mantle melting. Dry melts are further separated in depleted (MORB) and enriched (OIB) sources. This three-fold pattern is a clear image of the ridge/subduction/plume system that dominates modern tectonics. In contrast, Archaean mafic and ultramafic rocks are clustered in an intermediate position, between the three main modern types. This suggests that the Archaean mantle had lesser amounts of clearly depleted or enriched portions; that true subductions were rare; and that the distinction between oceanic plateaus and ridges may have been less significant. Modern granitic rocks dominantly belong to two groups: arc-related granitoids, petrologically connected to arc basalts; and collision granitoids, related to felsic sources. In contrast, the Archaean record is dominated by the TTG suite that derives from an alkali-rich mafic source (i.e. altered basalt). The geochemical diversity of the TTG suite points to a great range of melting depths, from ca. 5 to > 20 kbar. This reveals the absence of large sedimentary accumulations, again the paucity of modern-like arc situations, and the importance played by reworking of an earlier basaltic shell, in a range of settings (including some proto-subduction mechanisms). Nonetheless, granitoids in each individual region show a progressive transition towards more modern-looking associations of arc-like and peraluminous granites. Collectively, the geochemical evidence suggests an Archaean Earth with somewhat different tectonic systems. In particular, the familiar distinction between collision, arcs, ridges and hotspots seems to blur in the Archaean. Rather, the large-scale geochemical pattern reveals a long-lived, altered and periodically resurfaced basaltic crust. This protocrust is reworked, through a range of processes occurring at various depths that correspond to a progressive stabilization of burial systems and the establishment of true subductions. A punctuated onset of global plate tectonics is unlikely to have occurred, but rather short-term episodes of proto-subduction in the late Archaean evolved over time into longer-term, more stable style of plate tectonics as mantle temperature decayed.

Tectonics, basin analysis and organic geochemical attributes of Permian through Mesozoic deposits and their derivative oils of the Turpan-Hami basin, northwestern China

NASA Astrophysics Data System (ADS)

Greene, Todd Jeremy

The Turpan-Hami basin is a major physiographic and geologic feature of northwest China, yet considerable uncertainty exists as to the timing of its inception, its late Paleozoic and Mesozoic tectonic history, and the relationship of its petroleum systems to those of the nearby Junggar basin. Mesozoic sedimentary fades, regional unconformities, sediment dispersal patterns, and sediment compositions within the Turpan-Hami and southern Junggar basins suggest that these basins were initially separated between Early Triassic and Early Jurassic time. Prior to separation, Upper Permian profundal lacustrine and fan-delta fades and Triassic coarse-grained braided-fluvial/alluvial fades were deposited across a contiguous Junggar-Turpan-Hami basin. Permian through Triassic fades were derived mainly from the Tian Shan to the south as indicated by northward-directed paleocurrent directions and geochemical provenance of granitoid cobbles. Lower through Middle Jurassic strata begin to reflect ponded coal-forming, lake-plain environments within the Turpan-Hami basin. A sharp change in sedimentary-lithic-rich Lower Jurassic sandstone followed by a return to lithic volcanic-rich Middle Jurassic sandstone points to the initial uplift and unroofing of the largely andesitic Bogda Shan range, which first shed its sedimentary cover as it emerged to become the partition between the Turpan-Hami and southern Junggar basins. In Turpan-Hami, source rock age is one of three major statistically significant discriminators of effective source rocks in the basin. A newly developed biomarker parameter appears to track conifer evolution and can distinguish Permian rocks and their correlative oils from Jurassic coals and mudrocks, and their derivative oils. Source fades is a second key control on petroleum occurrence and character. By erecting rock-to-oil correlation models, the biomarker parameters separate oil families into end-member groups: Group 1 oils---Lower/Middle Jurassic peatland/swamp fades, Group 2 oils---Lower/Middle Jurassic marginal lacustrine fades, and Group 3 oils---Upper Permian lacusbine fades. Burial history exercises a third major control on petroleum in the Turpan-Hami basin. While relatively uninterrupted deep burial in the Tabei Depression exhausted Upper Permian source rocks and brought Lower/Middle Jurassic rocks well into the oil generative window, Late Jurassic uplift in the Tainan Depression eroded much of the Lower/Middle Jurassic section and preserved Upper Permian sourced oils as biodegraded, relict, heavy oils.* *This dissertation includes a CD that is multimedia (contains text and other applications that are not available in a printed format). The CD requires the following applications: Adobe Acrobat, UNIX.

The system controlling the composition of clastic sediments

USGS Publications Warehouse

Johnsson, Mark J.

1993-01-01

The composition of clastic sediments and rocks is controlled by a complex suite of parameters operating during pedogenesis, erosion, transport, deposition, and burial. The principal first-order parameters include source rock composition, modification by chemical weathering, mechanical disaggregation and abrasion, authigenic inputs, hydrodynamic sorting, and diagenesis. Each of these first-order parameters is influenced to varying degrees by such factors as the tectonic settings of the source region, transportational system and depositional environment, climate, vegetation, relief, slope, and the nature and energy of transportational and depositional systems. These factors are not independent; rather a complicated web of interrelationships and feedback mechanisms causes many factors to be modulated by others. Accordingly, processes controlling the composition of clastic sediments are best viewed as constituting a system, and in evaluating compositional information the dynamics of the system must be considered as whole.

Anisotropy of Magnetic Susceptibility of Silicic Rocks From Quarries in the Vicinity of São Marcos, Rio Grande Do Sul, South Brazil: Implications for Emplacement Mechanisms.

NASA Astrophysics Data System (ADS)

Canon-Tapia, E.; Raposo, M. I. B.

2017-12-01

The Paraná-Etendeka Large Igneous Province includes felsic volcanic rocks whose mechanism of emplacement and location of their eruptive sources are controversial. Opening of several quarries of dimension stone near the city of Sao Marcos, Rio Grande do Sul, Brazil, offers a unique opportunity to study in detail some of those products. Here, we present the results of a study of the anisotropy of magnetic susceptibility (AMS) completed in some rocks that had been interpreted as the roots of volcanic conduits. Our results, and reexamination of the textural features of the rocks, lead to a reinterpretation that suggests that these rocks were emplaced subaerially, and involved assimilation and remelting of clastic components of previous lavas. The extremely high eruption temperatures of the lavas promoted the development of peperite-like textures and mixing patterns similar to those observed in plutonic environments. Due to the inferred conditions of emplacement, it is unlikely that the eruptive vents are located far from the area of study, therefore ruling out the long-travelled nature of these products.

8. Photographic copy of photograph. (Source: Department of Interior. Bureau ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. Photographic copy of photograph. (Source: Department of Interior. Bureau of Reclamation. Bitterroot Project History 1931-1962. National Archives, Denver, RG 115, Accession #115-90-039, Box 243) Photographer unknown. View of original rock-fill crib diversion structure, September 13, 1949. Diversion and head works for big ditch on Rock Creek. - Bitter Root Irrigation Project, Rock Creek Diversion Dam, One mile east of Como Dam, west of U.S. Highway 93, Darby, Ravalli County, MT

Extraction of Iodine from Source Rock and Oil for Radioiodine Dating Final Report CRADA No. TC-1550-98

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moran, J. E.; Summa, L.

This was a collaborative effort between the University of California, Lawrence Livermore National Laboratory (LLNL) and Exxon Production Research Company (EPR) to develop improved techniques for extracting, concentrating, and measuring iodine from large volumes of source rock and oil. The purpose of this project was to develop a technique for measuring total iodine extracted from rock, obtain isotopic ratios, and develop age models for samples provided by EPR.

Resources for a lunar base: Rocks, minerals, and soil of the Moon

NASA Technical Reports Server (NTRS)

Taylor, Lawrence A.

1992-01-01

The rocks and minerals of the Moon will be included among the raw materials used to construct a lunar base. The lunar regolith, the fragmental material present on the surface of the Moon, is composed mostly of disaggregated rocks and minerals, but also includes glassy fragments fused together by meteorite impacts. The finer fraction of the regolith (i.e., less than 1 cm) is informally referred to as soil. The soil is probably the most important portion of the regolith for use at a lunar base. For example, soil can be used as insulation against cosmic rays, for lunar ceramics and abodes, or for growing plants. The soil contains abundant solar-wind-implanted elements as well as various minerals, particularly oxide phases, that are of potential economic importance. For example, these components of the soil are sources of oxygen and hydrogen for rocket fuel, helium for nuclear energy, and metals such as Fe, Al, Si, and Ti.

Terrigenous sediment supply along the Chilean continental margin: modern regional patterns of texture and composition

NASA Astrophysics Data System (ADS)

Lamy, F.; Hebbeln, D.; Wefer, G.

The regional patterns of texture and composition of modern continental slope and pelagic sediments off Chile between 25°S and 43°S reflect the latitudinal segmentation of geological, morphological, and climatic features of the continental hinterland. Grain-size characteristics are controlled by the grain-size of source rocks, the weathering regime, and mode of sediment input (eolian off northern Chile vs fluvial further south). Bulk-mineral assemblages reveal a low grade of maturity. Regional variations are governed by the source-rock composition of the different geological terranes and the relative source-rock contribution of the Coastal Range and Andes, as controlled by the continental hydrology. The relative abundance of clay minerals is also predominantly influenced by the source-rock composition and partly by continental smectite neoformation. Latitudinal variations of illite crystallinities along the Chilean continental slope (and west of the Peru-Chile trench) clearly reflect modifications of the weathering regime which correspond to the strong climatic zonation of Chile.

Critical elements in sediment-hosted deposits (clastic-dominated Zn-Pb-Ag, Mississippi Valley-type Zn-Pb, sedimentary rock-hosted Stratiform Cu, and carbonate-hosted Polymetallic Deposits): A review: Chapter 12

USGS Publications Warehouse

Marsh, Erin; Hitzman, Murray W.; Leach, David L.

2016-01-01

Some sediment-hosted base metal deposits, specifically the clastic-dominated (CD) Zn-Pb deposits, carbonate-hosted Mississippi Valley-type (MVT) deposits, sedimentary-rock hosted stratiform copper deposits, and carbonate-hosted polymetallic (“Kipushi type”) deposits, are or have been important sources of critical elements including Co, Ga, Ge, and Re. The generally poor data concerning trace element concentrations in these types of sediment-hosted ores suggest that there may be economically important concentrations of critical elements yet to be recognized.

Lower Paleozoic Through Archean Detrital Zircon Ages From Metasedimentary Rocks of the Nome Group, Seward Peninsula, Alaska

NASA Astrophysics Data System (ADS)

Amato, J. M.; Miller, E. L.; Gehrels, G.

2003-12-01

Metamorphic rocks of Seward Peninsula have been divided into two groups based on their metamorphic grade and history: The Nome Group and the Kigluaik Group. Although it is sometime been assumed that the higher structural position of the Nome Group versus the Kigluaik Group indicates the Kigluaik Group is older, this relationship and the age of the protoliths of these rocks has never been well-established. The Nome Group includes (delete the) lower grade blueschist and greenschist facies rocks which are widespread across the Seward Peninsula (delete) Rock types include pelitic schist, more mafic chlorite-white mica-albite schist, marble, quartzite, and metabasite. An early metamorphic event (pre-120 Ma) occurred at high pressure and relatively low temperature, and is everywhere overprinted by younger deformation and greenschist facies Rare eclogite facies assemblages are preserved in metabasites, and garnet-glaucophane in some of the pelitic schists. The Kigluaik Group includes upper greenschist to granulite facies rocks that are exposed in the core of a gneiss dome. They record a younger event (~91 Ma) that occurred at higher temperatures and resulted in partial thermal overprinting of the Nome Group and upper greenschist to granulite facies assemblages forming in the Kigluaik Group. The Kigluaik Group and equivalent rocks in the Bendeleben and Darby Mountains represent at least in part similar protoliths to many of the units in the Nome Group (Till and Dumoulin, 1994). The boundary between the rocks of the Nome Group and those clearly affected by the second metamorphic event is placed arbitrarily at the "Biotite-in" isograd along the flanks of the gneiss dome. In order to assess the protolith ages and source rock ages for these units, detrital zircon ages were obtained from three samples from the Nome Group, with Kigluaik Group ages forthcoming. LA-MC-ICPMS U/Pb isotope analysis was used for dating. Two samples were collected from the western Kigluaik Mountains near Eldorado Creek and one further south along the Feather River. Each sample yielded 90-105 analyses and all uncertainties are 1 sigma. Chlorite schist MC-74 has a range of ages from the two youngest grains at 484 +/- 18 Ma and 510 +/- 7 Ma to 2984 +/- 2 Ma. Chlorite schist LMC-30 has a youngest grain at 521 +/- 2 Ma and an oldest grain of 2027 +/- 12. Quartz-mica schist LMC-58 also has a youngest grain at 521 +/- 2 Ma and an oldest grain of 2655 +/- 7 Ma. All three therefore have lower Paleozoic zircons, suggesting Lower Cambrian or younger depositional ages. Combining the data from all three rocks results in peaks on a cumulative probability plot at (in descending order of importance): 600 Ma, 683 Ma, 1593 Ma, 522 Ma, and 2985 Ma, with several smaller peaks between 774-1540 Ma and 1685-1960 Ma. Published ages from Nome Group orthogneisses are 680 Ma, suggesting the samples so far analyzed are likely in part sourced from local basement rocks that were eroded to provide ~680 Ma detrital zircons to sedimentary protoliths of part of the Nome Group.

S-type granitic magmas—petrogenetic issues, models and evidence

NASA Astrophysics Data System (ADS)

Clemens, J. D.

2003-04-01

Despite a perception that it represents a perverse divergence, it is perfectly possible to believe in the existence of S- and I-type granites (and the implications for the nature of their protoliths), and to disbelieve in the applicability of the restite-unmixing model for chemical variation in granitic magmas. White and Chappell erected the S-I classification with impeccable validity. The isotopic evidence demands contrasting source reservoirs for S- and I-type granitic magmas. However, the major advance was not the classification, but the recognition that highly contrasting parental materials must be involved in the genesis of granitic magmas. The restite-unmixing model is commonly seen as a companion to the S-I classification, but it is really a separate issue. This model implies that the compositions of granites 'image' those of their source rocks in a simple way. However, there are other equally valid models that can explain the data, and none of them represents a unique solution. The most cogent explanation for the high-grade metasedimentary enclaves in most S-type granites is that they represent mid-crustal xenoliths; restitic enclaves are either rare or absent. Inherited zircons in S-type rocks are certainly restitic. However, the occurrence of a substantial restitic zircon population does not imply an equally substantial restitic component in the rest of the rock. Zircon and zirconium behaviours are controlled by disequilibrium and kinetics, and Zr contents of granitic rocks can rarely be used to infer magma temperatures. Since the dominant ages among inherited zircons in Lachlan Fold Belt (LFB) S-type granites are Ordovician and Proterozoic, it seems likely that crust of this age, but geochemically different from the exposed rocks, not only underlies much of the LFB but also forms a component in the granite magma sources. The evidence is overwhelming that the dark, microgranular enclaves that occur in both S- and I-type granites are igneous in origin. They represent globules of quenched, more mafic magma mingled and modified by exchange with the host granitic magma. However, magma mixing does not appear to be a significant process affecting the chemical evolution of the host magmas. Likewise, the multicomponent mixing models erected for some granitic rock suites are mathematically nonunique and, in some cases, violate constraints from isotopic studies. S- and I-type magmas commonly retain their distinct identities. This suggests limited source mixing, limited magma mixing and limited wall-rock assimilation. Though intermediate types certainly exist, they are probably relatively minor in volume. Crystal fractionation probably plays the major role in the differentiation of very many granitic magmas, including most S-types, especially those emplaced at high crustal levels or in the volcanic environment. Minor mechanisms include magma mixing, wall-rock assimilation and restite unmixing. Isotopic variations within plutons and in granite suites could be caused by source heterogeneities, magma mixing, assimilation and even by isotopic disequilibrium. However, source heterogeneity, coupled with the inefficiency of magma mixing is probably the major cause of observed heterogeneity. Normal geothermal gradients are seldom sufficient to provide the necessary heat for partial melting of the crust, and crustal thickening likewise fails to provide sufficient heat. Generally, the mantle must be the major heat source. This might be provided through mantle upwelling and crustal thinning, and possibly through the intra- and underplating of mafic magmas. Upper crustal extension seems to have been common in regions undergoing granitic magmatism. Migmatites probably provide poor analogues of granite source regions because they are mostly formed by fluid-present reactions. Granitic magmas are mostly formed by fluid-absent processes. Where we do see rare evidence for arrested fluid-absent partial melting, the melt fraction is invariably concentrated into small shear zones, veinlets and small dykes. Thus, it seems likely that dyking is important in transporting granitic magma on a variety of scales and at many crustal levels. However, one major missing link in the chain is the mechanism by which melt fractions, in small-scale segregations occurring over a wide area, can be gathered and focused to efficiently feed much wider-spaced major magma conduits. Answers may lie in the geometry of the melting zones and in the tendency of younger propagating fractures to curve toward and merge with older ones. Self-organization almost certainly plays a role.

Petroleum source-rock potentials of the cretaceous transgressive-regressive sedimentary sequences of the Cauvery Basin

NASA Astrophysics Data System (ADS)

Chandra, Kuldeep; Philip, P. C.; Sridharan, P.; Chopra, V. S.; Rao, Brahmaji; Saha, P. K.

The present work is an attempt to contribute to knowledge on the petroleum source-rock potentials of the marine claystones and shales of basins associated with passive continental margins where the source-rock developments are known to have been associated with the anoxic events in the Mesozoic era. Data on three key exploratory wells from three major depressions Ariyallur-Pondicherry, Thanjavur and Nagapattinam of the Cauvery Basin are described and discussed. The average total organic carbon contents of the transgressive Pre-Albian-Cinomanian and Coniacian/Santonian claystones/shales range from 1.44 and 1.16%, respectively. The transgressive/regressive Campanian/Maastrichtian claystones contain average total organic carbon varying from 0.62 to 1.19%. The kerogens in all the studied stratigraphic sequences are classified as type-III with Rock-Eval hydrogen indices varying from 30 to 275. The nearness of land masses to the depositional basin and the mainly clastic sedimentation resulted in accumulation and preservation of dominantly type-III kerogens. The Pre-Albian to Cinomanian sequences of peak transgressive zone deposited in deep marine environments have kerogens with a relatively greater proportion of type-II components with likely greater contribution of planktonic organic matters. The global anoxic event associated with the Albian-Cinomanian marine transgression, like in many other parts of the world, has pervaded the Cauvery Basin and favoured development of good source-rocks with type-III kerogens. The Coniacian-Campanian-Maastrichtian transgressive/regressive phase is identified to be relatively of lesser significance for development of good quality source-rocks.

Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA

NASA Astrophysics Data System (ADS)

Smith, Christopher N.; Kesler, Stephen E.; Blum, Joel D.; Rytuba, James J.

2008-05-01

We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300 m) and silica-carbonate deposits that extend to depths of 1000 m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions ( δ202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ± 0.5‰) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO 2 vapor or reduction and volatilization of Hg (0) in the near-surface environment are likely the most important processes causing the observed Hg isotope fractionation. This should result in the release of mercury with low δ202Hg values into the atmosphere from the top of these hydrothermal systems. Estimates of mass balance suggest that residual Hg reservoirs are not measurably enriched in heavy Hg isotopes as a result of this process because only a small amount of Hg (< 4%) leaves actively ore-forming systems.

Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA

USGS Publications Warehouse

Smith, C.N.; Kesler, S.E.; Blum, J.D.; Rytuba, J.J.

2008-01-01

We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300??m) and silica-carbonate deposits that extend to depths of 1000??m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions (??202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although ??202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean ??202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ?? 0.5???) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO2 vapor or reduction and volatilization of Hg(0) in the near-surface environment are likely the most important processes causing the observed Hg isotope fractionation. This should result in the release of mercury with low ??202Hg values into the atmosphere from the top of these hydrothermal systems. Estimates of mass balance suggest that residual Hg reservoirs are not measurably enriched in heavy Hg isotopes as a result of this process because only a small amount of Hg (< 4%) leaves actively ore-forming systems. ?? 2008 Elsevier B.V. All rights reserved.

Petroleum geology and resources of the Nepa-Botuoba High, Angara-Lena Terrace, and Cis-Patom Foredeep, southeastern Siberian Craton, Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

Three structural provinces of this report, the Nepa-Botuoba High, the Angara-Lena Terrace, and the Cis-Patom Foredeep, occupy the southeastern part of the Siberian craton northwest of the Baikal-Patom folded region (fig. 1). The provinces are similar in many aspects of their history of development, stratigraphic composition, and petroleum geology characteristics. The sedimentary cover of the provinces overlies the Archean?Lower Proterozoic basement of the Siberian craton. Over most of the area of the provinces, the basement is covered by Vendian (uppermost Proterozoic, 650?570 Ma) clastic and carbonate rocks. Unlike the case in the more northwestern areas of the craton, older Riphean sedimentary rocks here are largely absent and they appear in the stratigraphic sequence only in parts of the Cis-Patom Foredeep province. Most of the overlying sedimentary section consists of Cambrian and Ordovician carbonate and clastic rocks, and it includes a thick Lower Cambrian salt-bearing formation. Younger rocks are thin and are present only in marginal areas. 1 A single total petroleum system (TPS) embraces all three provinces. The TPS is unique in two aspects: (1) its rich hydro-carbon reserves are derived from Precambrian source rocks and (2) preservation of oil and gas fields is extremely long owing to the presence of the Lower Cambrian undeformed salt seal. Discovered reserves of the TPS are about 2 billion barrels of oil and more than 30 trillion cubic feet of gas. The stratigraphic distribution of oil and gas reserves is narrow; all fields are in Vendian to lowermost Cambrian clastic and carbonate reservoirs that occur below Lower Cambrian salt. Both structural and stratigraphic traps are known. Source rocks are absent in the sedimentary cover of the provinces, with the possible exception of a narrow zone on the margin of the Cis-Patom Foredeep province. Source rocks are interpreted here to be Riphean and Vendian organic-rich shales of the Baikal-Patom folded region. These rocks presently are deformed and metamorphosed, but they generated oil and gas before the deformation occurred in Late Silurian and Devonian time. Generated hydrocarbons migrated updip onto the craton margin. The time of migration and formation of fields is constrained by the deposition of Lower Cambrian salt and by the Late Silurian or Devonian metamorphism of source rocks. This time frame indicates that the TPS is one of the oldest petroleum systems in the world. All three provinces are exploration frontiers, and available geologic data are limited; therefore, only one assessment unit has been identified. The largest undiscovered hydrocarbon resources are expected to be in Vendian clastic reservoirs in both structural and stratigraphic traps of the Nepa-Botuoba High province. The petroleum potential of Vendian?lowermost Cambrian carbonate reservoirs is smaller. Nevertheless, these reservoirs may contain significant resources. Gas is expected to dominate over oil in the resource base.

Alteration of fault rocks by CO2-bearing fluids with implications for sequestration

NASA Astrophysics Data System (ADS)

Luetkemeyer, P. B.; Kirschner, D. L.; Solum, J. G.; Naruk, S.

2011-12-01

Carbonates and sulfates commonly occur as primary (diagenetic) pore cements and secondary fluid-mobilized veins within fault zones. Stable isotope analyses of calcite, formation fluid, and fault zone fluids can help elucidate the carbon sources and the extent of fluid-rock interaction within a particular reservoir. Introduction of CO2 bearing fluids into a reservoir/fault system can profoundly affect the overall fluid chemistry of the reservoir/fault system and may lead to the enhancement or degradation of porosity within the fault zone. The extent of precipitation and/or dissolution of minerals within a fault zone can ultimately influence the sealing properties of a fault. The Colorado Plateau contains a number of large carbon dioxide reservoirs some of which leak and some of which do not. Several normal faults within the Paradox Basin (SE Utah) dissect the Green River anticline giving rise to a series of footwall reservoirs with fault-dependent columns. Numerous CO2-charged springs and geysers are associated with these faults. This study seeks to identify regional sources and subsurface migration of CO2 to these reservoirs and the effect(s) faults have on trap performance. Data provided in this study include mineralogical, elemental, and stable isotope data for fault rocks, host rocks, and carbonate veins that come from two localities along one fault that locally sealed CO2. This fault is just tens of meters away from another normal fault that has leaked CO2-charged waters to the land surface for thousands of years. These analyses have been used to determine the source of carbon isotopes from sedimentary derived carbon and deeply sourced CO2. XRF and XRD data taken from several transects across the normal faults are consistent with mechanical mixing and fluid-assisted mass transfer processes within the fault zone. δ13C range from -6% to +10% (PDB); δ18O values range from +15% to +24% (VSMOW). Geochemical modeling software is used to model the alteration productions of fault rocks from fluids of various chemistries coming from several different reservoirs within an active CO2-charged fault system. These results are compared to data obtained in the field.

Lead in the Getchell-Turquoise ridge Carlin-type gold deposits from the perspective of potential igneous and sedimentary rock sources in Northern Nevada: Implications for fluid and metal sources

USGS Publications Warehouse

Tosdal, R.M.; Cline, J.S.; Fanning, C.M.; Wooden, J.L.

2003-01-01

Lead isotope compositions of bulk mineral samples (fluorite, orpiment, and realgar) determined using conventional techniques and of ore-stage arsenian pyrite using the Sensitive High Resolution Ion-Microprobe (SHRIMP) in the Getchell and Turquoise Ridge Carlin-type gold deposits (Osgood Mountains) require contribution from two different Pb sources. One Pb source dominates the ore stage. It has a limited Pb isotope range characterized by 208Pb/206Pb values of 2.000 to 2.005 and 207Pb/206Pb values of 0.8031 to 0.8075, as recorded by 10-??m-diameter spot SHRIMP analyses of ore-stage arsenian pyrite. These values approximately correspond to 206Pb/204Pb of 19.3 to 19.6, 207Pb/204Pb of 15.65 to 15.75, and 208Pb/204Pb of 39.2 to 39.5. This Pb source is isotopically similar to that in average Neoproterozoic and Cambrian elastic rocks but not to any potential magmatic sources. Whether those clastic rocks provided Pb to the ore fluid cannot be unequivocally proven because their Pb isotope compositions over the same range as in ore-stage arsenian pyrite are similar to those of Ordovician to Devonian siliciclastic and calcareous rocks. The Pb source in the calcareous rocks most likely is largely detrital minerals, since that detritus was derived from the same sources as the detritus in the Neoproterozoic and Cambrian clastic rocks. The second Pb source is characterized by a large range of 206Pb/204Pb values (18-34) with a limited range of 208Pb/204Pb values (38.1-39.5), indicating low but variable Th/U and high and variable U/Pb values. The second Pb source dominates late and postore-stage minerals but is also found in preore sulfide minerals. These Pb isotope characteristics typify Ordovician to Devonian siliciclastic and calcareous rocks around the Carlin trend in northeast Nevada. Petrologically similar rocks host the Getchell and Turquoise Ridge deposits. Lead from the second source was either contributed from the host sedimentary rock sequences or brought into the hydrothermal system by oxidized ground water as the system collapsed. Late ore- and postore-stage sulfide minerals (pyrite, orpiment, and stibnite) from the Betze-Post and Meikle deposits in the Carlin trend and from the Jerritt Canyon mining district have Pb isotope characteristics similar to those determined in Getchell and Turquoise Ridge. This observation suggests that the Pb isotope compositions of their ore fluids may be similar to those at Getchell and Turquoise Ridge. Two models can explain the Pb isotope compositions of the ore-stage arsenian pyrite versus the late ore or postore sulfide minerals. In either model, Pb from the Ordovician to Devonian siliciclastic and calcareous rock source enters the hydrothermal system late in the ore stage but not to any extent during the main stage of ore deposition. In one model, ore-stage Pb was derived from a source with Pb isotope compositions similar to those of the Neoproterozoic and Cambrian clastic sequence, transported as part of the ore fluid and then deposited in the ore-stage arsenian pyrite and fluorite. The second model is based on the observation that the Pb isotope characteristics of the ore-stage minerals also are found in some Ordovician to Devonian calcareous and siliciclastic rocks. Hence, ore-stage Pb could have been derived locally and simply concentrated during the ore stage. Critical to the second model is the removal of all high 206Pb/204Pb (>20) material during alteration. It Also requires the retention of only the low 206Pb/204Pb component of the Ordovician to Devonian sedimentary rocks. This critical step is possible only if the high 206Pb/204Pb values are contained in readily dissolvable mineral phases, whereas the low 206Pb/204Pb values are found only in refractory minerals that released Pb during a final alteration stage just prior deposition of auriferous arsenian pyrite. Distinguishing between Pb transported with the ore fluid or inherited from the site of mineral deposition is not straightforward

Two Distinct Sets of Magma Sources in Cretaceous Rocks From Magnet Cove, Prairie Creek, and Other Igneous Centers of the Arkansas Alkaline Province, USA

NASA Astrophysics Data System (ADS)

Duke, G. I.; Carlson, R. W.; Eby, G. N.

2008-12-01

Two distinct sets of magma sources from the Arkansas alkaline province (~106-89 Ma) are revealed by Sr-Nd-Pb isotopic compositions of olivine lamproites vs. other alkalic rock types, including carbonatite, ijolite, lamprophyres, tephrite, malignite, jacupirangite, phonolite, trachyte, and latite. Isotopic compositions of diamond-bearing olivine lamproites from Prairie Creek and Dare Mine Knob point to Proterozoic lithosphere as an important source, and previous Re-Os isotopic data indicate derivation from subcontinental mantle lithosphere. Both sources were probably involved in lamproite generation. Magnet Cove carbonatites and other alkalic magmas were likely derived from an asthenospheric source. Lamproite samples are isotopically quite different from other rock types in Sr-Nd-Pb isotopic space. Although three lamproite samples from Prairie Creek have a large range of SiO2 contents (40-60 wt %), initial values of ɛNd (-10 to -13), 206Pb/204Pb (16.61-16.81), 207Pb/204Pb (15.34-15.36), and 208Pb/204Pb (36.57-36.76) are low and similar. Only 87Sr/86Sr(i) displays a wide range in the Prairie Creek lamproites (0.70627-0.70829). A fourth lamproite from Dare Mine Knob has the most negative ɛNd(i) of -19. Lamproite isotope values show a significant crustal component and isotopically overlap subalkalic rhyolites from the Black Hills (SD), which assimilated Proterozoic crust. Six samples of carbonatite, ijolite, and jacupirangite from Magnet Cove and Potash Sulphur Springs exhibit the most depleted Sr-Nd isotopic signatures of all samples. For these rock types, 87Sr/86Sr(i) is 0.70352 - 0.70396, and ɛNd(i) is +3.8 - +4.3. Eight other rock types have a narrow range of ɛNd(i) (+1.9 - +3.7), but a wide range of 87Sr/86Sr(i) (0.70424 - 0.70629). These 14 samples comprise a fairly tight cluster of Pb isotopic values: 206Pb/204Pb (18.22-19.23), 207Pb/204Pb (15.54-15.62), and 208Pb/204Pb (38.38-38.94), suggesting very little crustal assimilation. They are most similar to EM-2 (sub-group of OIB). Published ages of crustal amphibolite xenoliths from the Prairie Creek lamproite are Proterozoic (~1.32- 1.47 Ga), in keeping with isotopic evidence for crustal assimilation, including Tdm = 1.3-1.7 Ga. Published ages of lamproite (~106 Ma) indicate that these magmas intruded first, whereas carbonatites and other alkalic magmas were later (~102 to ~89 Ma). Asthenospheric upwelling first melted lithospheric mantle and crust, producing lamproitic magmas; asthenospheric magmas followed as swelling of the lithosphere ensued.

Clay mineralogy, strontium and neodymium isotope ratios in the sediments of two High Arctic catchments (Svalbard)

NASA Astrophysics Data System (ADS)

Hindshaw, Ruth S.; Tosca, Nicholas J.; Piotrowski, Alexander M.; Tipper, Edward T.

2018-03-01

The identification of sediment sources to the ocean is a prerequisite to using marine sediment cores to extract information on past climate and ocean circulation. Sr and Nd isotopes are classical tools with which to trace source provenance. Despite considerable interest in the Arctic Ocean, the circum-Arctic source regions are poorly characterised in terms of their Sr and Nd isotopic compositions. In this study we present Sr and Nd isotope data from the Paleogene Central Basin sediments of Svalbard, including the first published data of stream suspended sediments from Svalbard. The stream suspended sediments exhibit considerable isotopic variation (ɛNd = -20.6 to -13.4; 87Sr / 86Sr = 0.73421 to 0.74704) which can be related to the depositional history of the sedimentary formations from which they are derived. In combination with analysis of the clay mineralogy of catchment rocks and sediments, we suggest that the Central Basin sedimentary rocks were derived from two sources. One source is Proterozoic sediments derived from Greenlandic basement rocks which are rich in illite and have high 87Sr / 86Sr and low ɛNd values. The second source is Carboniferous to Jurassic sediments derived from Siberian basalts which are rich in smectite and have low 87Sr / 86Sr and high ɛNd values. Due to a change in depositional conditions throughout the Paleogene (from deep sea to continental) the relative proportions of these two sources vary in the Central Basin formations. The modern stream suspended sediment isotopic composition is then controlled by modern processes, in particular glaciation, which determines the present-day exposure of the formations and therefore the relative contribution of each formation to the stream suspended sediment load. This study demonstrates that the Nd isotopic composition of stream suspended sediments exhibits seasonal variation, which likely mirrors longer-term hydrological changes, with implications for source provenance studies based on fixed end-members through time.

Provenance from zircon U-Pb age distributions in crustally contaminated granitoids

NASA Astrophysics Data System (ADS)

Bahlburg, Heinrich; Berndt, Jasper

2016-05-01

The basement of sedimentary basins is often entirely covered by a potentially multi-stage basin fill and therefore removed from direct observation and sampling. Melts intruding through the basin stratigraphy at a subsequent stage in the geological evolution of a region may assimilate significant volumes of country rocks. This component may be preserved in the intrusive body either as xenoliths or it may be reflected only by the age spectrum of incorporated zircons. Here we present the case of an Ordovician calc-alkaline intrusive belt in NW Argentina named the "Faja Eruptiva de la Puna Oriental" (Faja Eruptiva), which in the course of intrusion sampled the unexposed and unknown basement of the Ordovician basin in this region, and parts of the basin stratigraphy. We present new LA-ICP-MS U-Pb ages on zircons from 9 granodiorites and granites of the Faja Eruptiva. The main part of the Faja Eruptiva intruded c. 445 Ma in the Late Ordovician. The zircon ages obtained from the intrusive rocks have a large spread between 2683.5 ± 21.6 and 440.0 ± 4.9 Ma and reflect the underlying crust and may be interpreted in several ways. The inherited zircons may have been derived from the oldest known unit in the region, the thick siliciclastic turbidite successions of the upper Neoproterozoic-lower Cambrian Puncoviscana Formation, which is inferred to represent the basement of the NW Argentina. The basement to the Puncoviscana Formation is not known. Alternatively, the inherited zircons may reflect the geochronological structure of the entire unexposed Early Paleozoic crust underlying this region of which the Puncoviscana Formation was only one component. This crust likely contained rocks pertaining to and detritus derived from earlier orogenic cycles of the southwestern Amazonia craton, including sources of Early Meso- and Paleoproterozoic age. Detritus derived, in turn, from the Faja Eruptiva intrusive belt reflects the origin of the granitoids as well as the inherited geochronological and isotope geochemical structure of either the basement and/or distant sources having supplied material to the basement rocks. If unrecognized, sediment formed from such granitoid sources may erroneously be used to infer the exposure of, and direct detrital contributions from, a variety of older source rocks in fact not directly involved in the studied source-sink system.

Using Muons to Image the Subsurface.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bonal, Nedra; Cashion, Avery Ted; Cieslewski, Grzegorz

Muons are subatomic particles that can penetrate the earth 's crust several kilometers and may be useful for subsurface characterization . The absorption rate of muons depends on the density of the materials through which they pass. Muons are more sensitive to density variation than other phenomena, including gravity, making them beneficial for subsurface investigation . Measurements of muon flux rate at differing directions provide density variations of the materials between the muon source (cosmic rays and neutrino interactions) and the detector, much like a CAT scan. Currently, muon tomography can resolve features to the sub-meter scale. This work consistsmore » of three parts to address the use of muons for subsurface characterization : 1) assess the use of muon scattering for estimating density differences of common rock types, 2 ) using muon flux to detect a void in rock, 3) measure muon direction by designing a new detector. Results from this project lay the groundwork for future directions in this field. Low-density objects can be detected by muons even when enclosed in high-density material like lead, and even small changes in density (e.g. changes due to fracturing of material) can be detected. Rock density has a linear relationship with muon scattering density per rock volume when this ratio is greater than 0.10 . Limitations on using muon scattering to assess density changes among common rock types have been identified. However, other analysis methods may show improved results for these relatively low density materials. Simulations show that muons can be used to image void space (e.g. tunnels) within rock but experimental results have been ambiguous. Improvements are suggested to improve imaging voids such as tunnels through rocks. Finally, a muon detector has been designed and tested to measure muon direction, which will improve signal-to-noise ratio and help address fundamental questions about the source of upgoing muons .« less

Magnetic and gravity gradiometry framework for Mesoproterozoic iron oxide-apatite and iron oxide-copper-gold deposits, southeast Missouri, USA

USGS Publications Warehouse

McCafferty, Anne E.; Phillips, Jeffrey; Driscoll, Rhonda L.

2016-01-01

High-resolution airborne magnetic and gravity gradiometry data provide the geophysical framework for evaluating the exploration potential of hidden iron oxide deposits in Mesoproterozoic basement rocks of southeast Missouri. The data are used to calculate mineral prospectivity for iron oxide-apatite (IOA) ± rare earth element (REE) and iron oxide-copper-gold (IOCG) deposits. Results delineate the geophysical footprints of all known iron oxide deposits and reveal several previously unrecognized prospective areas. The airborne data are also inverted to three-dimensional density and magnetic susceptibility models over four concealed deposits at Pea Ridge (IOA ± REE), Boss (IOCG), Kratz Spring (IOA), and Bourbon (IOCG). The Pea Ridge susceptibility model shows a magnetic source that is vertically extensive and traceable to a depth of greater than 2 km. A smaller density source, located within the shallow Precambrian basement, is partly coincident with the magnetic source at Pea Ridge. In contrast, the Boss models show a large (625-m-wide), vertically extensive, and coincident dense and magnetic stock with shallower adjacent lobes that extend more than 2,600 m across the shallow Precambrian paleosurface. The Kratz Spring deposit appears to be a smaller volume of iron oxides and is characterized by lower density and less magnetic rock compared to the other iron deposits. A prospective area identified south of the Kratz Spring deposit shows the largest volume of coincident dense and nonmagnetic rock in the subsurface, and is interpreted as prospective for a hematite-dominant lithology that extends from the top of the Precambrian to depths exceeding 2 km. The Bourbon deposit displays a large bowl-shaped volume of coincident high density and high-magnetic susceptibility rock, and a geometry that suggests the iron mineralization is vertically restricted to the upper parts of the Precambrian basement. In order to underpin the evaluation of the prospectivity and three-dimensional models, an extensive statistical summary of density and apparent magnetic susceptibility measurements is presented that includes data on several hundred samples taken from the deposits, altered wall rocks, and unaltered country rocks.

An integrated study of geochemistry and mineralogy of the Upper Tukau Formation, Borneo Island (East Malaysia): Sediment provenance, depositional setting and tectonic implications

NASA Astrophysics Data System (ADS)

Nagarajan, Ramasamy; Roy, Priyadarsi D.; Kessler, Franz L.; Jong, John; Dayong, Vivian; Jonathan, M. P.

2017-08-01

An integrated study using bulk chemical composition, mineralogy and mineral chemistry of sedimentary rocks from the Tukau Formation of Borneo Island (Sarawak, Malaysia) is presented in order to understand the depositional and tectonic settings during the Neogene. Sedimentary rocks are chemically classified as shale, wacke, arkose, litharenite and quartz arenite and consist of quartz, illite, feldspar, rutile and anatase, zircon, tourmaline, chromite and monazite. All of them are highly matured and were derived from a moderate to intensively weathered source. Bulk and mineral chemistries suggest that these rocks were recycled from sedimentary to metasedimentary source regions with some input from granitoids and mafic-ultramafic rocks. The chondrite normalized REE signature indicates the presence of felsic rocks in the source region. Zircon geochronology shows that the samples were of Cretaceous and Triassic age. Comparable ages of zircon from the Tukau Formation sedimentary rocks, granitoids of the Schwaner Mountains (southern Borneo) and Tin Belt of the Malaysia Peninsular suggest that the principal provenance for the Rajang Group were further uplifted and eroded during the Neogene. Additionally, presence of chromian spinels and their chemistry indicate a minor influence of mafic and ultramafic rocks present in the Rajang Group. From a tectonic standpoint, the Tukau Formation sedimentary rocks were deposited in a passive margin with passive collisional and rift settings. Our key geochemical observation on tectonic setting is comparable to the regional geological setting of northwestern Borneo as described in the literature.

Pre-Elsonian mafic magmatism in the Nain Igneous Complex, Labrador: the bridges layered intrusion

USGS Publications Warehouse

Ashwal, L.D.; Wiebe, R.A.; Wooden, J.L.; Whitehouse, M.J.; Snyder, Diane

1992-01-01

Decades of work on the pristine, unmetamorphosed, and well exposed anorthositic, mafic and granitic rocks of the Nain igneous complex, Labrador, have led to the conclusion that all plutonic rocks in that area were emplaced in a short time intercal at about 1300 ?? 10 Ma). We report here new isotopic data for mafic intrusive rocks that appear to have crystallized several hundred Ma earlier than the bulk of the plutonic activity in the Nain complex. The Bridges layered intrusion (BLI) is a small (15-20 km2) lens of layered mafic rocks about 1.5 km thick, surrounded and intruded by anorthositic, leuconoritic and leucotroctolitic plutons in the middle of the coastal section of the Nain igneous complex. BLI shows very well developed magmatic structures, including channel scours, slump structures, and ubiquitous modally graded layering. Most rocks, however, show granular textures indicative of recrystallization, presumably caused by emplacement of younger anorthositic rocks. BLI contains cumulate rocks with slightly more primitive mineral compositions (An60-83, Fo66-71) than those of other mafic intrusions in the Nain igneous complex, including Kiglapait. SmNd isotopic data for 7 BLI whole-rocks ranging in composition between olivine melagabbro and olivine leucogabbro yield an age of 1667 ?? 75 Ma, which we interpret as the time of primary crystallization. The internal isotopic systematics of the BLI have been reset, probably by intrusion of adjacent anorthositic plutons. A SmNd mineral isochron (plag, whole-rock, mafics) for a BLI olivine melagabbro gives an age of 1283 ?? 22 Ma, equivalent within error of a mineral array (plag, whole-rock, opx, cpx) for an adjacent, igneous-textured, leuconorite vein (1266 ?? 152 Ma). The initial Nd ratio for BLI corresponds to ??{lunate}Nd = -3.18 ?? 0.44. Other whole-rock samples, however, some with vein-like alteration (Chlorite, serpentine, amphiboles), show ??{lunate}Nd values as low as -9.1, suggesting variable contamination by direct assimilation of early Archean crustal rocks and/or by fluids that have interacted with such crust. Adjacent anorthositic rocks also show variable ??{lunate}Nd some as low as -14.7, implying larger degrees if crustal assimilation, perhaps by parental magmas during lower crustal ponding prior to emplacement. These contamination effects preclude straightforward determination of the isotopic character of mantle sources for both BLI and the anorthositic rocks. ?? 1992.

Birth and demise of the Rheic Ocean magmatic arc(s): Combined U-Pb and Hf isotope analyses in detrital zircon from SW Iberia siliciclastic strata

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Gutíerrez-Alonso, G.; Murphy, J. B.; Drost, K.; Gama, C.; Silva, J. B.

2017-05-01

Paleozoic continental reconstructions indicate that subduction of Rheic oceanic lithosphere led to collision between Laurussia and Gondwana which was a major event in the formation of the Ouachita-Appalachian-Variscan orogenic belt and the amalgamation of Pangea. However, arc systems which record Rheic Ocean subduction are poorly preserved. The preservation of Devonian detrital zircon in Late Devonian-Early Carboniferous siliciclastic rocks of SW Iberia, rather than arc-related igneous rocks indicates that direct evidence of the arc system may have been largely destroyed by erosion. Here we report in-situ detrital zircon U-Pb isotopic analyses of Late Devonian-Early Carboniferous siliciclastic rocks from the Pulo do Lobo Zone, which is a reworked Late Paleozoic suture zone located between Laurussia and Gondwana. Detrital zircon age spectra from the Pulo do Lobo Zone Frasnian formations show striking similarities, revealing a wide range of ages dominated by Neoproterozoic and Paleoproterozoic grains sourced from rocks typical of peri-Gondwanan terranes, such as Avalonia, the Meguma terrane and the Ossa-Morena Zone. Pulo do Lobo rocks also include representative populations of Mesoproterozoic and Early Silurian zircons that are typical of Avalonia and the Meguma terrane which are absent in the Ossa-Morena Zone. The Famennian-Tournaisian formations from the Pulo do Lobo Zone, however, contain more abundant Middle-Late Devonian zircon indicating the contribution from a previously unrecognized source probably related to the Rheic Ocean magmatic arc(s). The Middle-Late Devonian to Early Carboniferous zircon ages from the siliciclastic rocks of SW Iberia (South Portuguese, Pulo do Lobo and Ossa-Morena zones) have a wide range in εHfT values (- 8.2 to + 8.3) indicating the likely crystallization from magmas formed in a convergent setting. The missing Rheic Ocean arc was probably built on a Meguma/Avalonia type basement. We propose for the Pulo do Lobo Zone that the Frasnian sedimentation occurred through the opening of a back-arc basin formed along the Laurussian active margin during Rheic Ocean subduction, as has been recently proposed for the Rhenohercynian Zone in Central Europe. Detrital zircon ages in the Frasnian siliciclastic rocks indicate provenance in the Meguma terrane, Avalonia and Devonian Rheic Ocean arc(s). As a result of back-arc basin inversion, the Frasnian formations underwent deformation, metamorphism and denudation and were unconformably overlain by Famennian to Visean siliciclastic strata (including the Phyllite-Quartzite Formation of the South Portuguese Zone). The Latest Devonian-Early Carboniferous detritus were probably shed to the Pulo do Lobo Zone (Represa and Santa Iria formations) by recycling of Devonian siliciclastic rocks, from the South Portuguese Zone (Meguma terrane) and from a new distinct source with Baltica/Laurentia derivation (preserved in the Horta da Torre Formation and Alajar Mélange).

AnisoVis: a MATLAB™ toolbox for the visualisation of elastic anisotropy

NASA Astrophysics Data System (ADS)

Healy, D.; Timms, N.; Pearce, M. A.

2016-12-01

The elastic properties of rocks and minerals vary with direction, and this has significant consequences for their physical response to acoustic waves and natural or imposed stresses. This anisotropy of elasticity is well described mathematically by 4th rank tensors of stiffness or compliance. These tensors are not easy to visualise in a single diagram or graphic, and visualising Poisson's ratio and shear modulus presents a further challenge in that their anisotropy depends on two principal directions. Students and researchers can easily underestimate the importance of elastic anisotropy. This presentation describes an open source toolbox of MATLAB scripts that aims to visualise elastic anisotropy in rocks and minerals. The code produces linked 2-D and 3-D representations of the standard elastic constants, such as Young's modulus, Poisson's ratio and shear modulus, all from a simple GUI. The 3-D plots can be manipulated by the user (rotated, panned, zoomed), to encourage investigation and a deeper understanding of directional variations in the fundamental properties. Examples are presented of common rock forming minerals, including those with negative Poisson's ratio (auxetic behaviour). We hope that an open source code base will encourage further enhancements from the rock physics and wider geoscience communities. Eventually, we hope to generate 3-D prints of these complex and beautiful natural surfaces to provide a tactile link to the underlying physics of elastic anisotropy.

Towards the challenging REE exploration in Indonesia

NASA Astrophysics Data System (ADS)

Setiawan, Iwan

2018-02-01

Rare earth elements (REE) are the seventeen elements, including fifteen from 57La to 71Lu, in addition to 21Sc and 39Y. In rock-forming minerals, rare earth elements typically occur in compounds as trivalent cations in carbonates, oxides, phosphates, and silicates. The REE occur in a wide range of rock types: igneous, sedimentary and metamorphic rocks. REE are one of the critical metals in the world. Their occurrences are important to supply the world needs on high technology materials. Indonesia has a lot of potential sources of REE that are mainly from residual tin mining processes in Bangka islands, which are associated with radioactive minerals e.g. monazite and xenotime. However, the REE from monazite and xenotime are difficult to extract and contain high radioactivity. Granitoids are widely distributed in Sumatra, Sulawesi, Kalimantan and Papua. They also have a very thick weathering crusts. Important REE-bearing minerals are allanite and titanite. Their low susceptibilities during weathering result an economically potential REE concentration. I-/A- type granitoids and their weathered crusts are important REE sources in Indonesia. Unfortunately, their distribution and genesis have not been deeply studied. Future REE explorations challenge are mainly of the granitoids their weathered crusts. Geochemical and mineralogical characterization of type of granitoids and their weathered crusts, the hydrothermally altered rocks, and clear REE regulation will help discover REE deposits in Indonesia.

Volcanostratigraphy, petrography and petrochemistry of Late Cretaceous volcanic rocks from the Görele area (Giresun, NE Turkey)

NASA Astrophysics Data System (ADS)

Oguz, Simge; Aydin, Faruk; Baser, Rasim

2015-04-01

In this study, we have reported for lithological, petrographical and geochemical features of late Cretaceous volcanic rocks from the Çanakçı and the Karabörk areas in the south-eastern part of Görele (Giresun, NE Turkey) in order to investigate their origin and magmatic evolution. Based on the previous ages and recent volcano-stratigraphic studies, the late Cretaceous time in the study area is characterized by an intensive volcanic activity that occurred in two different periods. The first period of the late Cretaceous volcanism (Cenomanian-Santonian; 100-85 My), conformably overlain by Upper Jurassic-Lower Cretaceous massive carbonates (Berdiga Formation), is represented by bimodal units consisting of mainly mafic rock series (basaltic-andesitic lavas and hyaloclastites, dikes and sills) in the lower part (Çatak Formation), and felsic rock series (dacitic lavas and hyaloclastites, crystal- and pyrite-bearing tuffs) in the upper part (Kızılkaya Formation). The second period of the late Cretaceous volcanism (Santonian-Late Campanian; 85-75 Ma) is also represented by bimodal character and again begins with mafic rock suites (basaltic-basaltic andesitic lavas and hyaloclastites) in the lower part (Çağlayan Formation), and grades upward into felsic rock suites (biotite-bearing rhyolitic lavas, ignimbrites and hyaloclastites) through the upper part (Tirebolu Formation). These bimodal units are intercalated with volcanic conglomerates-sandstones, claystones, marl and red pelagic limestones throughout the volcanic sequence, and the felsic rock series have a special important due to hosting of volcanogenic massive sulfide deposits in the region. All volcano-sedimentary units are covered by Tonya Formation (Late Campanian-Paleocene) containing calciturbidites, biomicrites and clayey limestones. The mafic rocks in the two volcanic periods generally include basalt, basaltic andesite and minor andesite, whereas felsic volcanics of the first period mainly consists of dacite but those of the second period have biotite-bearing rhyolite. The basalts and basaltic andesites exhibit subaphyric to porphyritic texture with phenocrysts of calcic plagioclase and augite in a fine-grained to microcrystalline groundmass, consisting of plag+cpx+mag. Andesite samples display a porphyritic texture with phenocrysts of calcic to sodic plagioclase and augite in a hyalopilitic matrix of plag+cpx±amph+mag. Zircon and magnetite are common accessory minerals, whereas chlorite, epidote and calcite are typical alteration products. On the other hand, the dacitic and rhyolitic rocks commonly show a porphyritic texture with predominant feldspar, quartz and some biotite phenocrysts. The microgranular to felsophyric groundmass is mainly composed of aphanitic plagioclase, K-feldspar and quartz. Accessory minerals include zircon, apatite and magnetite. Typical alteration minerals include late-formed sericite, albite and clay minerals. Late Cretaceous mafic and felsic volcanic rocks have a largely sub-alkaline character with typical arc geochemical signatures. N-MORB-normalised multi-element patterns show that all rock samples are enriched in LILEs (e.g. Rb, Ba, Th) but depleted in Nb and Ti. The chondrite-normalized REE patterns are concave shapes with low to medium enrichment, suggesting a common mantle source for the studied bimodal rock series. All geochemical data reflecting typical characteristics of subduction-related magmas are commonly attributed to a depleted mantle source, which has been previously enriched by fluids or sediments. Acknowledgments This work was supported by the Scientific and Technological Research Council of Turkey (TUBITAK, grant 112Y365)

The role of magmas in the formation of hydrothermal ore deposits

USGS Publications Warehouse

Hedenquist, Jeffrey W.; Lowenstern, Jacob B.

1994-01-01

Magmatic fluids, both vapour and hypersaline liquid, are a primary source of many components in hydrothermal ore deposits formed in volcanic arcs. These components, including metals and their ligands, become concentrated in magmas in various ways from various sources, including subducted oceanic crust. Leaching of rocks also contributes components to the hydrothermal fluid—a process enhanced where acid magmatic vapours are absorbed by deeply circulating meteoric waters. Advances in understanding the hydrothermal systems that formed these ore deposits have come from the study of their active equivalents, represented at the surface by hot springs and volcanic fumaroles.

The ubiquitous nature of accessory calcite in granitoid rocks: Implications for weathering, solute evolution, and petrogenesis

USGS Publications Warehouse

White, A.F.; Schulz, M.S.; Lowenstern, J. B.; Vivit, D.V.; Bullen, T.D.

2005-01-01

Calcite is frequently cited as a source of excess Ca, Sr and alkalinity in solutes discharging from silicate terrains yet, no previous effort has been made to assess systematically the overall abundance, composition and petrogenesis of accessory calcite in granitoid rocks. This study addresses this issue by analyzing a worldwide distribution of more than 100 granitoid rocks. Calcite is found to be universally present in a concentration range between 0.028 to 18.8 g kg-1 (mean = 2.52 g kg-1). Calcite occurrences include small to large isolated anhedral grains, fracture and cavity infillings, and sericitized cores of plagioclase. No correlation exists between the amount of calcite present and major rock oxide compositions, including CaO. Ion microprobe analyses of in situ calcite grains indicate relatively low Sr (120 to 660 ppm), negligible Rb and 87Sr/86Sr ratios equal to or higher than those of coexisting plagioclase. Solutes, including Ca and alkalinity produced by batch leaching of the granitoid rocks (5% CO2 in DI water for 75 d at 25??C), are dominated by the dissolution of calcite relative to silicate minerals. The correlation of these parameters with higher calcite concentrations decreases as leachates approach thermodynamic saturation. In longer term column experiments (1.5 yr), reactive calcite becomes exhausted, solute Ca and Sr become controlled by feldspar dissolution and 87Sr/ 86Sr by biotite oxidation. Some accessory calcite in granitoid rocks is related to intrusion into carbonate wall rock or produced by later hydrothermal alteration. However, the ubiquitous occurrence of calcite also suggests formation during late stage (subsolidus) magmatic processes. This conclusion is supported by petrographic observations and 87Sr/86Sr analyses. A review of thermodynamic data indicates that at moderate pressures and reasonable CO2 fugacities, calcite is a stable phase at temperatures of 400 to 700??C. Copyright ?? 2005 Elsevier Ltd.

Petrologic variations in Apollo 16 surface soils

NASA Technical Reports Server (NTRS)

Houck, K. J.

1982-01-01

Source rock, maturation history and intrasite variation data are derived for the Apollo 16 regolith by comparing modal analyses of 15 surface soils with rake and rock sample data. Triangular source rock component plots show that Apollo 16 soils have similar source rocks that are well homogenized throughout the site. The site can be divided into three soil petrographic provinces. Central site soils are mature, well homogenized, and enriched in glass. They are probably the most typical Cayley Plains materials present. North Ray soils are immature to submature, containing North Ray ejecta. South Ray soils are mature, but contain small amounts of fresh impact melts and plagioclase, due perhaps to the breakdown of blocky South Ray ejecta. The different compositions and physical properties of North and South Ray ejecta support the hypothesis that the latter event excavated Cayley material, while the former excavated Descartes materials.

Sedimentary rock-hosted Au deposits of the Dian-Qian-Gui area, Guizhou, and Yunnan Provinces, and Guangxi District, China

USGS Publications Warehouse

Peters, S.G.; Jiazhan, H.; Zhiping, L.; Chenggui, J.

2007-01-01

Sedimentary rock-hosted Au deposits in the Dian-Qian-Gui area in southwest China are hosted in Paleozoic and early Mesozoic sedimentary rocks along the southwest margin of the Yangtze (South China) Precambrian craton. Most deposits have characteristics similar to Carlin-type Au deposits and are spatially associated, on a regional scale, with deposits of coal, Sb, barite, As, Tl, and Hg. Sedimentary rock-hosted Au deposits are disseminated stratabound and(or) structurally controlled. The deposits have many similar characteristics, particularly mineralogy, geochemistry, host rock, and structural control. Most deposits are associated with structural domes, stratabound breccia bodies, unconformity surfaces or intense brittle-ductile deformation zones, such as the Youjiang fault system. Typical characteristics include impure carbonate rock or calcareous and carbonaceous host rock that contains disseminated pyrite, marcasite, and arsenopyrite-usually with ??m-sized Au, commonly in As-rich rims of pyrite and in disseminations. Late realgar, orpiment, stibnite, and Hg minerals are spatially associated with earlier forming sulfide minerals. Minor base-metal sulfides, such as galena, sphalerite, chalcopyrite, and Pb-Sb-As-sulphosalts also are present. The rocks locally are silicified and altered to sericite-clay (illite). Rocks and(or) stream-sediment geochemical signatures typically include elevated concentrations of As, Sb, Hg, Tl, and Ba. A general lack of igneous rocks in the Dian-Qian-Gui area implies non-pluton-related, ore forming processes. Some deposits contain evidence that sources of the metal may have originated in carbonaceous parts of the sedimentary pile or other sedimentary or volcanic horizons. This genetic process may be associated with formation and mobilization of petroleum and Hg in the region and may also be related to As-, Au-, and Tl-bearing coal horizons. Many deposits also contain textures and features indicative of strong structural control by tectonic domes or shear zones and also suggest syndeformational ore deposition, possibly related to the Youjiang fault system. Several sedimentary rock-hosted Au deposits in the Dian-Qian-Gui area also are of the red earth-type and Au grades have been concentrated and enhanced during episodes of deep weathering. ?? 2006 Elsevier B.V. All rights reserved.

Growing Pebbles and Conceptual Prisms - Understanding the Source of Student Misconceptions about Rock Formation.

ERIC Educational Resources Information Center

Kusnick, Judi

2002-01-01

Analyzes narrative essays--stories of rock formation--written by pre-service elementary school teachers. Reports startling misconceptions among preservice teachers on pebbles that grow, human involvement in rock formation, and sedimentary rocks forming as puddles as dry up, even though these students had completed a college level course on Earth…

Evidence for Seismogenic Hydrogen Gas, a Potential Microbial Energy Source on Earth and Mars

NASA Astrophysics Data System (ADS)

McMahon, Sean; Parnell, John; Blamey, Nigel J. F.

2016-09-01

The oxidation of molecular hydrogen (H2) is thought to be a major source of metabolic energy for life in the deep subsurface on Earth, and it could likewise support any extant biosphere on Mars, where stable habitable environments are probably limited to the subsurface. Faulting and fracturing may stimulate the supply of H2 from several sources. We report the H2 content of fluids present in terrestrial rocks formed by brittle fracturing on fault planes (pseudotachylites and cataclasites), along with protolith control samples. The fluids are dominated by water and include H2 at abundances sufficient to support hydrogenotrophic microorganisms, with strong H2 enrichments in the pseudotachylites compared to the controls. Weaker and less consistent H2 enrichments are observed in the cataclasites, which represent less intense seismic friction than the pseudotachylites. The enrichments agree quantitatively with previous experimental measurements of frictionally driven H2 formation during rock fracturing. We find that conservative estimates of current martian global seismicity predict episodic H2 generation by Marsquakes in quantities useful to hydrogenotrophs over a range of scales and recurrence times. On both Earth and Mars, secondary release of H2 may also accompany the breakdown of ancient fault rocks, which are particularly abundant in the pervasively fractured martian crust. This study strengthens the case for the astrobiological investigation of ancient martian fracture systems.

Age and speciation of iodine in groundwater and mudstones of the Horonobe area, Hokkaido, Japan: Implications for the origin and migration of iodine during basin evolution

NASA Astrophysics Data System (ADS)

Togo, Yoko S.; Takahashi, Yoshio; Amano, Yuki; Matsuzaki, Hiroyuki; Suzuki, Yohey; Terada, Yasuko; Muramatsu, Yasuyuki; Ito, Kazumasa; Iwatsuki, Teruki

2016-10-01

This paper reports the concentration, speciation and isotope ratio (129I/127I) of iodine from both groundwater and host rocks in the Horonobe area, northern Hokkaido, Japan, to clarify the origin and migration of iodine in sedimentary rocks. Cretaceous to Quaternary sedimentary rocks deposited nearly horizontally in Tenpoku Basin and in the Horonobe area were uplifted above sea level during active tectonics to form folds and faults in the Quaternary. Samples were collected from the Pliocene Koetoi and late Miocene Wakkanai formations (Fms), which include diatomaceous and siliceous mudstones. The iodine concentration in groundwater, up to 270 μmol/L, is significantly higher than that of seawater, with the iodine enrichment factor relative to seawater reaching 800-1500. The iodine concentration in the rocks decreases from the Koetoi to Wakkanai Fms, suggesting that iodine was released into the water from the rocks of deeper formations. The iodine concentration in the rocks is sufficiently high for forming iodine-rich groundwater as found in this area. X-ray absorption near edge structure (XANES) analysis shows that iodine exists as organic iodine and iodide (I-) in host rocks, whereas it exists mainly as I- in groundwater. The isotope ratio is nearly constant for iodine in the groundwater, at [0.11-0.23] × 10-12, and it is higher for iodine in rocks, at [0.29-1.1] × 10-12, giving iodine ages of 42-60 Ma and 7-38 Ma, respectively. Some iodine in groundwater must have originated from Paleogene and even late Cretaceous Fms, which are also considered as possible sources of oil and gas, in view of the old iodine ages of the groundwater. The iodine ages of the rocks are older than the depositional ages, implying that the rocks adsorbed some iodine from groundwater, which was sourced from greater depths. The iodine concentration in groundwater decreases with decreasing chlorine concentration due to mixing of iodine-rich connate water and meteoric water. A likely scenario is that iodine-rich brine formed during the long-term basin evolution from the Cretaceous to Quaternary and that this brine was diluted by mixing with meteoric water during uplifting and denudation of the area.

Evaluation of hydrocarbon potential

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cashman, P.H.; Trexler, J.H. Jr.

1992-09-30

Task 8 is responsible for assessing the hydrocarbon potential of the Yucca Mountain vincinity. Our main focus is source rock stratigraphy in the NTS area in southern Nevada. (In addition, Trexler continues to work on a parallel study of source rock stratigraphy in the oil-producing region of east central Nevada, but this work is not funded by Task 8.) As a supplement to the stratigraphic studies, we are studying the geometry and kinematics of deformation at NTS, particularly as these pertain to reconstructing Paleozoic stratigraphy and to predicting the nature of the Late Paleozoic rocks under Yucca Mountain. Our stratigraphicmore » studies continue to support the interpretation that rocks mapped as the {open_quotes}Eleana Formation{close_quotes} are in fact parts of two different Mississippian units. We have made significant progress in determining the basin histories of both units. These place important constraints on regional paleogeographic and tectonic reconstructions. In addition to continued work on the Eleana, we plan to look at the overlying Tippipah Limestone. Preliminary TOC and maturation data indicate that this may be another potential source rock.« less

Provenance and tectonic setting of the Neoproterozoic clastic rocks hosting the Banana Zone Cu-Ag mineralisation, northwest Botswana

NASA Astrophysics Data System (ADS)

Kelepile, Tebogo; Bineli Betsi, Thierry; Franchi, Fulvio; Shemang, Elisha; Suh, Cheo Emmanuel

2017-05-01

Petrographic and geochemical data were combined in order to decipher the petrogenesis of the Neoproterozoic sedimentary succession associated with the Banana Zone Cu-Ag mineralisation (northwest Botswana), in the Kalahari Copperbelt. The investigated Neoproterozoic sedimentary succession is composed of two formations including the Ngwako Pan and the D'kar Formations. The Ngwako Pan Formation is made up of continental siliciclastic sediments, mainly sandstones interbedded with siltstones and mudstones, whereas the D'kar Formation is comprised of shallow marine laminated siltstones, sandstones and mudstones, with subordinate limestone. Copper-Ag mineralisation is essentially confined at the base of the D'kar Formation, which bears reduced organic components, likely to have controlled Cu-Ag precipitation. Sandstones of both the Ngwako Pan and the D'kar Formations are arkoses and subarkoses, composed of quartz (Q), feldspars (F) and lithic fragments (L). Moreover, geochemically the sandstones are considered as potassic and classified as arkoses. On the other hand, mudrocks of the D'kar Formation are finely laminated and are dominated by muscovite, sericite, chlorite and quartz. The modified chemical index of weathering (CIW‧) values indicated an intense chemical weathering of the source rock. The dominance of detrital quartz and feldspar grains coupled with Al2O3/TiO2 ratios (average 29.67 and 24.52 for Ngwako Pan and D'kar Formations, respectively) and Ni and Cr depletion in the sandstones, suggest a dominant felsic source. However, high concentrations of Ni and Cr and a low Al2O3/TiO2 ratio (<20) in the mudrocks of the D'kar Formation indicate a mixed source. Provenance of the investigated sandstones and mudrocks samples is further supported by the REE patterns, the size of Eu anomaly as well as La/Co, Th/Co, Th/Cr and Cr/Th ratios, which show a felsic source for the sandstones of both the Ngwako Pan and D'kar Formations and an intermediate source for the mudrocks of the D'kar Formation. Detrital modes (QFL diagrams) and geochemical characteristics of the sandstones of both the Ngwako Pan and D'kar Formations indicate that the detritus were probably supplied from a heavily weathered felsic continental block and deposited in a continental rift setting (passive margin) in a humid environment. The source rocks might have been the Palaeoproterozoic basement rocks (granitoids and granitic gneiss) and the Mesoproterozoic Kgwebe volcanic rocks exposed north of the study area.

Hydrogeochemical Investigations of Historic Mining Districts, Central Western Slope of Colorado, Including Influence on Surface-Water Quality

USGS Publications Warehouse

Nash, J. Thomas

2002-01-01

This report describes reconnaissance hydrogeochemical investigations of 22 mining districts on the Western Slope of Colorado in the Gunnison and Uncompahgre National Forests and adjacent public lands administered by the Bureau of Land Management. Sources and fates of contaminants from historic mines, mine waste, and mill tailings are interpreted from chemical analyses for 190 samples of surface waters; 185 samples of mined rocks, mill tailings, and altered rocks; and passive leach analyses of 116 samples of those mineralized materials. Short reaches of several headwater streams show relatively low level effects of historic mining; the headwaters of the Uncompahgre River are highly contaminated by mines and unmined altered rocks in the Red Mountain district. There is encouraging evidence that natural processes attenuate mine-related contamination in most districts.

New insight on petroleum system modeling of Ghadames basin, Libya

NASA Astrophysics Data System (ADS)

Bora, Deepender; Dubey, Siddharth

2015-12-01

Underdown and Redfern (2008) performed a detailed petroleum system modeling of the Ghadames basin along an E-W section. However, hydrocarbon generation, migration and accumulation changes significantly across the basin due to complex geological history. Therefore, a single section can't be considered representative for the whole basin. This study aims at bridging this gap by performing petroleum system modeling along a N-S section and provides new insights on source rock maturation, generation and migration of the hydrocarbons using 2D basin modeling. This study in conjunction with earlier work provides a 3D context of petroleum system modeling in the Ghadames basin. Hydrocarbon generation from the lower Silurian Tanezzuft formation and the Upper Devonian Aouinet Ouenine started during the late Carboniferous. However, high subsidence rate during middle to late Cretaceous and elevated heat flow in Cenozoic had maximum impact on source rock transformation and hydrocarbon generation whereas large-scale uplift and erosion during Alpine orogeny has significant impact on migration and accumulation. Visible migration observed along faults, which reactivated during Austrian unconformity. Peak hydrocarbon expulsion reached during Oligocene for both the Tanezzuft and the Aouinet Ouenine source rocks. Based on modeling results, capillary entry pressure driven downward expulsion of hydrocarbons from the lower Silurian Tanezzuft formation to the underlying Bir Tlacsin formation observed during middle Cretaceous. Kinetic modeling has helped to model hydrocarbon composition and distribution of generated hydrocarbons from both the source rocks. Application of source to reservoir tracking technology suggest some accumulations at shallow stratigraphic level has received hydrocarbons from both the Tanezzuft and Aouinet Ouenine source rocks, implying charge mixing. Five petroleum systems identified based on source to reservoir correlation technology in Petromod*. This Study builds upon the original work of Underdown and Redfern, 2008 and offers new insights and interpretation of the data.

Metallogeny of the midcontinent rift system of North America

USGS Publications Warehouse

Nicholson, S.W.; Cannon, W.F.; Schulz, K.J.

1992-01-01

The 1.1 Ga Midcontinent rift system of North America is one of the world's major continental rifts and hosts a variety of mineral deposits. The rocks and mineral deposits of this 2000 km long rift are exposed only in the Lake Superior region. In the Lake Superior region, the rift cuts across Precambrian basement terranes ranging in age from ??? 1850 Ma to more than 3500 Ma. Where exposed, the rift consists of widespread tholeiitic basalt flows with local interlayered rhyolite and clastic sedimentary rocks. Beneath the center of Lake Superior the volcanic and sedimentary rocks are more than 30 km deep as shown by recent seismic reflection profiles. This region hosts two major classes of mineral deposits, magmatic and hydrothermal. All important mineral production in this region has come from hydrothermal deposits. Rift-related hydrothermal deposits include four main types: (1) native copper deposits in basalts and interflow sediments; (2) sediment-hosted copper sulfide and native copper; (3) copper sulfide veins and lodes hosted by rift-related volcanic and sedimentary rocks; and (4) polymetallic (five-element) veins in the surrounding Archean country rocks. The scarcity of sulfur within the rift rocks resulted in the formation of very large deposits of native metals. Where hydrothermal sulfides occur (i.e., shale-hosted copper sulfides), the source of sulfur was local sedimentary rocks. Magmatic deposits have locally supported exploration and minor production, but most are subeconomic presently. These deposits occur in intrusions exposed near the margins of the rift and include CuNiPGE and TiFe (V) in the Duluth Complex, U-REE-Nb in small carbonatites, and breccia pipes resulting from local hydrothermal activity around small felsic intrusions. Mineralization associated with some magmatic bodies resulted from the concentration of incompatible elements during fractional crystallization. Most of the sulfide deposits in intrusions, however, contain sulfur derived from country rocks; the interaction between magma and country rocks was important in generation of the magmatic CuNi sulfide deposits. A mantle plume origin has been proposed for the formation of the Midcontinent rift. More than 1 million km3 of mafic magma was erupted in the rift and a comparable volume of mafic intrusions are inferred beneath the rift, providing a ready and structurally confined supply of mafic source rocks that were available for leaching of metals by basinal brines. These brines were heated by a steep geothermal gradient that resulted from the melting and underplating of magma derived from the plume. Hydrothermal deposits were emplaced for at least 30-40 m.y. after rift magmatism and extension ceased. This time lag may reflect either the time required to heat deeply buried rocks and fluids within the rift, or may be due to the timing of post-rift compression that may have provided the driving mechanism for expulsion of hydrothermal fluids from deep portions of the rift. ?? 1992.

Geological evolution of the Neoproterozoic Bemarivo Belt, northern Madagascar

USGS Publications Warehouse

Thomas, Ronald J.; De Waele, B.; Schofield, D.I.; Goodenough, K.M.; Horstwood, M.; Tucker, R.; Bauer, W.; Annells, R.; Howard, K. J.; Walsh, G.; Rabarimanana, M.; Rafahatelo, J.-M.; Ralison, A.V.; Randriamananjara, T.

2009-01-01

The broadly east-west trending, Late Neoproterozoic Bemarivo Belt in northern Madagascar has been re-surveyed at 1:100 000 scale as part of a large multi-disciplinary World Bank-sponsored project. The work included acquisition of 14 U-Pb zircon dates and whole-rock major and trace element geochemical data of representative rocks. The belt has previously been modelled as a juvenile Neoproterozoic arc and our findings broadly support that model. The integrated datasets indicate that the Bemarivo Belt is separated by a major ductile shear zone into northern and southern "terranes", each with different lithostratigraphy and ages. However, both formed as Neoproterozoic arc/marginal basin assemblages that were translated southwards over the north-south trending domains of "cratonic" Madagascar, during the main collisional phase of the East African Orogeny at ca. 540 Ma. The older, southern terrane consists of a sequence of high-grade paragneisses (Sahantaha Group), which were derived from a Palaeoproterozoic source and formed a marginal sequence to the Archaean cratons to the south. These rocks are intruded by an extensive suite of arc-generated metamorphosed plutonic rocks, known as the Antsirabe Nord Suite. Four samples from this suite yielded U-Pb SHRIMP ages at ca. 750 Ma. The northern terrane consists of three groups of metamorphosed supracrustal rocks, including a possible Archaean sequence (Betsiaka Group: maximum depositional age approximately 2477 Ma) and two volcano-sedimentary sequences (high-grade Milanoa Group: maximum depositional age approximately 750 Ma; low grade Daraina Group: extrusive age = 720-740 Ma). These supracrustal rocks are intruded by another suite of arc-generated metamorphosed plutonic rocks, known as the Manambato Suite, 4 samples of which gave U-Pb SHRIMP ages between 705 and 718 Ma. Whole-rock geochemical data confirm the calc-alkaline, arc-related nature of the plutonic rocks. The volcanic rocks of the Daraina and Milanoa groups also show characteristics of arc-related magmatism, but include both calc-alkaline and tholeiitic compositions. It is not certain when the two Bemarivo terranes were juxtaposed, but ages from metamorphic rims on zircon suggest that both the northern and southern terranes were accreted to the northern cratonic margin of Madagascar at about 540-530 Ma. Terrane accretion included the assembly of the Archaean Antongil and Antananarivo cratons and the high-grade Neoproterozoic Anaboriana Belt. Late- to post-tectonic granitoids of the Maevarano Suite, the youngest plutons of which gave ca. 520 Ma ages, intrude all terranes in northern Madagascar showing that terrane accretion was completed by this time. ?? 2009 Natural Environment Research Council (NERC).

Impacts on water quality and biota from natural acid rock drainage in Colorado's Lake Creek watershed

USGS Publications Warehouse

Bird, D.A.; Sares, Matthew A.; Policky, Greg A.; Schmidt, Travis S.; Church, Stan E.

2006-01-01

Colorado's Lake Creek watershed hosts natural acid rock drainage that significantly impacts surface water, streambed sediment, and aquatic life. The source of the ARD is a group of iron-rich springs that emerge from intensely hydrothermally altered, unexploited, low-grade porphyry copper mineralization in the Grizzly Peak Caldera. Source water chemistry includes pH of 2.5 and dissolved metal concentrations of up to 277 mg/L aluminum, 498 mg/L iron, and 10 mg/L copper. From the hydrothermally altered area downstream for 27 kilometers to Twin Lakes Reservoir, metal concentrations in streambed sediment are elevated and the watershed experiences locally severe adverse impacts to aquatic life due to the acidic, metal-laden water. The water and sediment quality of Twin Lakes Reservoir is sufficiently improved that the reservoir supports a trout fishery, and remnants of upstream ARD are negligible.

The Bolivian source rocks: Sub Andean Zone-Madre de Dios-Chaco

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moretti, I.; Montemurro, G.; Aguilera, E.

A complete study of source rocks has been carried out in the Bolivian foothills and foreland (Sub Andean Zone, Chaco and Madre de Dios) in order to quantify the petroleum potential of the area. Besides the classical mid-Devonian source rocks (Tequeje Formation in the north, Limoncito Formation in the center and Los Monos Formation in the south), others are important: the Tomachi Formation (late Devonian) in the north and the Copacabana Formation (Upper Carboniferous-lower Permian) in the northern Sub Andean Zone. Both show an excellent potential with S{sub 2} over 50 mg HC/g and average values higher than 10 mgmore » HC/g over few hundred meters. The Latest Cretaceous Flora Formation present locally a high potential but is very thin. Almost all the source rocks matured during the Neogene due to the subsidence in the Andean foreland and in the piggyback basins, and are thus involved on the current petroleum system. Silurian and Lower Paleozoic units also contain thick shale beds, but these source rocks were mature before the Jurassic in the south of the country. In the center, the Silurian is not nowadays overmature and may play an important role. The different zones are compared based on their Source Potential Index which indicates that the richest areas are the northern Sub Andean Zone and the Madre de Dios basin with SPI greater than 10 t/m{sup 2}. Since these two areas remain almost unexplored, these results allow us to be optimistic about the possibilities for future exploration.« less

Geochemical characterization of the siliciclastic rocks of Chitravati Group, Cuddapah Supergroup: Implications for provenance and depositional environment

NASA Astrophysics Data System (ADS)

Somasekhar, V.; Ramanaiah, S.; Sarma, D. Srinivasa

2018-06-01

Petrological and geochemical studies have been carried out on Pulivendla and Gandikota Quartzite from Chitravati Group of Cuddapah Supergroup to decipher the provenance and depositional environment. Both the units are texturally mature with sub-rounded to well-rounded and moderately to well-sorted grains. Majority of the framework grains are quartz, in the form of monocrystalline quartz, followed by feldspars (K-feldspar and plagioclase), mica, rock fragments, heavy minerals, with minor proportion of the matrix and cement. Based on major element geochemical classification diagram, Pulivendla Quartzite is considered as quartz-arenite and arkose to sub-arkose, whereas Gandikota Quartzite falls in the field of lith-arenite and arkose to sub-arkose. Weathering indices like CIA, PIA, CIW, ICV, Th/U ratio and A-CN-K ternary diagram suggest moderate to intense chemical weathering of the source rocks of these quartzites. Whole rock geochemistry of quartzites indicate that they are primarily from the first-cycle sediments, along with some minor recycled components. Also their sources were mostly intermediate-felsic igneous rocks of Archean age. The tectonic discrimination plots, Th-Sc-Zr/10 of both these formations reflect active to passive continental margin setting. Chondrite-normalized rare earth element (REE) patterns, and various trace element ratios like Cr/Th, Th/Co, La/Sc and Th/Cr indicate dominantly felsic source with minor contribution from mafic source. Th/Sc ratios of Pulivendla and Gandikota Quartzite are in close proximity with average values of 2.83, 3.45 respectively, which is higher than AUCC (Th/Sc=0.97), demonstrating that the contributions from more alkali source rocks than those that contributed to AUCC.

Assessment of unconvential (tight) gas resources in Upper Cook Inlet Basin, South-central Alaska

USGS Publications Warehouse

Schenk, Christopher J.; Nelson, Philip H.; Klett, Timothy R.; Le, Phuong A.; Anderson, Christopher P.; Schenk, Christopher J.

2015-01-01

A geologic model was developed for the assessment of potential Mesozoic tight-gas resources in the deep, central part of upper Cook Inlet Basin, south-central Alaska. The basic premise of the geologic model is that organic-bearing marine shales of the Middle Jurassic Tuxedni Group achieved adequate thermal maturity for oil and gas generation in the central part of the basin largely due to several kilometers of Paleogene and Neogene burial. In this model, hydrocarbons generated in Tuxedni source rocks resulted in overpressure, causing fracturing and local migration of oil and possibly gas into low-permeability sandstone and siltstone reservoirs in the Jurassic Tuxedni Group and Chinitna and Naknek Formations. Oil that was generated either remained in the source rock and subsequently was cracked to gas which then migrated into low-permeability reservoirs, or oil initially migrated into adjacent low-permeability reservoirs, where it subsequently cracked to gas as adequate thermal maturation was reached in the central part of the basin. Geologic uncertainty exists on the (1) presence of adequate marine source rocks, (2) degree and timing of thermal maturation, generation, and expulsion, (3) migration of hydrocarbons into low-permeability reservoirs, and (4) preservation of this petroleum system. Given these uncertainties and using known U.S. tight gas reservoirs as geologic and production analogs, a mean volume of 0.64 trillion cubic feet of gas was assessed in the basin-center tight-gas system that is postulated to exist in Mesozoic rocks of the upper Cook Inlet Basin. This assessment of Mesozoic basin-center tight gas does not include potential gas accumulations in Cenozoic low-permeability reservoirs.

Lead (Pb) Isotope Baselines for Studies of Ancient Human Migration and Trade in the Maya Region.

PubMed

Sharpe, Ashley E; Kamenov, George D; Gilli, Adrian; Hodell, David A; Emery, Kitty F; Brenner, Mark; Krigbaum, John

2016-01-01

We examined the potential use of lead (Pb) isotopes to source archaeological materials from the Maya region of Mesoamerica. The main objectives were to determine if: 1) geologic terrains throughout the Maya area exhibit distinct lead isotope ratios (206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb), and 2) a combination of lead and strontium ratios can enhance sourcing procedures in the Mesoamerica region. We analyzed 60 rock samples for lead isotope ratios and a representative subset of samples for lead, uranium, and thorium concentrations across the Maya region, including the Northern Lowlands of the Mexican Yucatan Peninsula, the Southern Lowlands of Guatemala and Belize, the Volcanic Highlands, the Belizean Maya Mountains, and the Metamorphic Province/Motagua Valley. Although there is some overlap within certain sub-regions, particularly the geologically diverse Metamorphic Province, lead isotopes can be used to distinguish between the Northern Lowlands, the Southern Lowlands, and the Volcanic Highlands. The distinct lead isotope ratios in the sub-regions are related to the geology of the Maya area, exhibiting a general trend in the lowlands of geologically younger rocks in the north to older rocks in the south, and Cenozoic volcanic rocks in the southern highlands. Combined with other sourcing techniques such as strontium (87Sr/86Sr) and oxygen (δ18O), a regional baseline for lead isotope ratios can contribute to the development of lead isoscapes in the Maya area, and may help to distinguish among geographic sub-regions at a finer scale than has been previously possible. These isotope baselines will provide archaeologists with an additional tool to track the origin and movement of ancient humans and artifacts across this important region.

Lead (Pb) Isotope Baselines for Studies of Ancient Human Migration and Trade in the Maya Region

PubMed Central

Kamenov, George D.; Gilli, Adrian; Hodell, David A.; Emery, Kitty F.; Brenner, Mark; Krigbaum, John

2016-01-01

We examined the potential use of lead (Pb) isotopes to source archaeological materials from the Maya region of Mesoamerica. The main objectives were to determine if: 1) geologic terrains throughout the Maya area exhibit distinct lead isotope ratios (206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb), and 2) a combination of lead and strontium ratios can enhance sourcing procedures in the Mesoamerica region. We analyzed 60 rock samples for lead isotope ratios and a representative subset of samples for lead, uranium, and thorium concentrations across the Maya region, including the Northern Lowlands of the Mexican Yucatan Peninsula, the Southern Lowlands of Guatemala and Belize, the Volcanic Highlands, the Belizean Maya Mountains, and the Metamorphic Province/Motagua Valley. Although there is some overlap within certain sub-regions, particularly the geologically diverse Metamorphic Province, lead isotopes can be used to distinguish between the Northern Lowlands, the Southern Lowlands, and the Volcanic Highlands. The distinct lead isotope ratios in the sub-regions are related to the geology of the Maya area, exhibiting a general trend in the lowlands of geologically younger rocks in the north to older rocks in the south, and Cenozoic volcanic rocks in the southern highlands. Combined with other sourcing techniques such as strontium (87Sr/86Sr) and oxygen (δ18O), a regional baseline for lead isotope ratios can contribute to the development of lead isoscapes in the Maya area, and may help to distinguish among geographic sub-regions at a finer scale than has been previously possible. These isotope baselines will provide archaeologists with an additional tool to track the origin and movement of ancient humans and artifacts across this important region. PMID:27806065

Understanding Sulfur Systematics in Large Igneous Provinces Using Sulfur Isotopes

NASA Astrophysics Data System (ADS)

Novikova, S.; Edmonds, M.; Turchyn, A. V.; Maclennan, J.; Svensen, H.; Frost, D. J.; Yallup, C.

2013-12-01

The eruption of the Siberian Traps coincided with perhaps the greatest environmental catastrophe in Earth's history, at the Permo-Triassic boundary. The source and magnitude of the volatile emissions, including sulfur, associated with the eruption remain poorly understood yet were critical in forcing environmental change. Two of the primary questions are how much sulfur gases were emitted during the eruptions and from where they were sourced. Primary melts carry dissolved sulfur from the mantle. Magmas ponding in sills and ascending through dykes may also assimilate sulfur from country rocks, as well as heat the country rocks and generate fluids through contact metamorphism. If the magmas interacted thermally, for prolonged periods, with sulfur-rich country rocks then it is probable that the sulfur budget of these eruptions might have been augmented considerably. This is exactly what we have shown recently for a basaltic sill emplaced in oil shale that fed eruptions of the British Tertiary Province, where surrounding sediments showed extensive desulfurization (Yallup et al. Geoch. Cosmochim. Acta, online, 2013). In the current study sulfur isotopes and trace element abundances are used to discriminate sulfur sources and to model magmatic processes for a suite of Siberian Traps sill and lava samples. Our bulk rock and pyrite geochemical analyses illustrate clearly their high abundance of 34S over 32S. The high 34S/32S has been noted previously and linked to assimilation of sulfur from sediments but may alternatively be inherited from the mantle plume source. With the aim of investigating the sulfur isotopic signature in the melt prior to devolatilization, we use secondary ion mass spectrometry (SIMS), for which a specific set of glass standards was synthesised. In order to understand how sulfur isotopes fractionate during degassing we have also conducted a parallel study of well-characterized tephras from Kilauea Volcano, where sulfur degassing behavior is well known.

Petrology of basalts from Loihi Seamount, Hawaii

NASA Astrophysics Data System (ADS)

Hawkins, James; Melchior, John

1983-12-01

Loihi Seamount is the southeasternmost active volcano of the Emperor-Hawaii linear volcanic chain. It comprises a spectrum of basalt compositional varieties including basanite, alkali basalt, transitional basalt and tholeiite. Samples from four dredge collections made on Scripps Institution of Oceanography Benthic Expedition in October 1982 are tholeiite. The samples include highly vesicular, olivine-rich basalt and dense glass-rich pillow fragments containing olivine and augite phenocrysts. Both quartz-normative and olivine-normative tholeiites are present. Minor and trace element data indicate relatively high abundances of low partition coefficient elements (e.g., Ti, K, P. Rb, Ba, Zr) and suggest that the samples were derived by relatively small to moderate extent of partial melting, of an undepleted mantle source. Olivine composition, MgO, Cr and Ni abundances, and Mg/(Mg+Fe), are typical of moderately fractionated to relatively unfractionated "primary" magmas. The variations in chemistry between samples cannot be adequately explained by low-pressure fractional crystallization but can be satisfied by minor variations in extent of melting if a homogeneous source is postulated. Alternatively, a heterogeneous source with variable abundances of certain trace elements, or mixing of liquids, may have been involved. Data for 3He/ 4He, presented in a separate paper, implies a mantle plume origin for the helium composition of the Loihi samples. There is little variation in the helium isotope ratio for samples having different compositions and textures. The helium data are not distinctive enough to unequivocally separate the magma sources for the tholeiitic rocks from the other rock types such as Loihi alkalic basalts and the whole source region for Loihi may have a nearly uniform helium compositions even though other element abundances may be variable. Complex petrologic processes including variable melting, fractional crystallization and magma mixing may have blurred original helium isotopic signatures.

Distribution of organic carbon and petroleum source rock potential of Cretaceous and lower Tertiary carbonates, South Florida Basin: preliminary results

USGS Publications Warehouse

Palacas, James George

1978-01-01

Analyses of 134 core samples from the South Florida Basin show that the carbonates of Comanchean age are relatively richer in average organic carbon (0.41 percent) than those of Coahuilan age (0.28 percent), Gulfian age (0.18 percent) and Paleocene age (0.20 percent). They are also nearly twice as rich as the average world, wide carbonate (average 0.24 percent). The majority of carbonates have organic carbons less than 0.30 percent but the presence of many relatively organic rich beds composed of highly bituminous, argillaceous, highly stylolitic, and algal-bearing limestones and dolomites accounts for the higher percentage of organic carbon in some of the stratigraphic units. Carbonate rocks that contain greater than 0.4 percent organic carbon and that might be considered as possible petroleum sources were noted in almost each subdivision of the Coahuilan and Comanchean Series but particularly the units of Fredericksburg 'B', Trinity 'A', Trinity 'F', and Upper Sunniland. Possible source rocks have been ascribed by others to the Lower Sunniland, but lack of sufficient samples precluded any firm assessment in this initial report. In the shallower section of the basin, organic-rich carbonates containing as much as 3.2 percent organic carbon were observed in the lowermost part of the Gulfian Series and carbonate rocks with oil staining or 'dead' and 'live oil' were noted by others in the uppermost Gulfian and upper Cedar Keys Formation. It is questionable whether these shallower rocks are of sufficient thermal maturity to have generated commercial oil. The South Florida basin is still sparsely drilled and produces only from the Sunniland Limestone at an average depth of 11,500 feet (3500 m). Because the Sunniland contains good reservoir rocks and apparently adequate source rocks, and because the success rate of new oil field discoveries has increased in recent years, the chances of finding additional oil reserves in the Sunniland are promising. Furthermore, the presence of possible source rocks in many of the other stratigraphic units, in particular, the Fredericksburg, should give further impetus to exploring for other productive horizons.

Geochemistry and source waters of rock glacier outflow, Colorado Front Range

USGS Publications Warehouse

Williams, M.W.; Knauf, M.; Caine, N.; Liu, F.; Verplanck, P.L.

2006-01-01

We characterize the seasonal variation in the geochemical and isotopic content of the outflow of the Green Lake 5 rock glacier (RG5), located in the Green Lakes Valley of the Colorado Front Range, USA. Between June and August, the geochemical content of rock glacier outflow does not appear to differ substantially from that of other surface waters in the Green Lakes Valley. Thus, for this alpine ecosystem at this time of year there does not appear to be large differences in water quality among rock glacier outflow, glacier and blockslope discharge, and discharge from small alpine catchments. However, in September concentrations of Mg2+ in the outflow of the rock glacier increased to more than 900 ??eq L-1 compared to values of less than 40 ??eq L-1 at all the other sites, concentrations of Ca2+ were greater than 4,000 ??eq L-1 compared to maximum values of less than 200 ??eq L-1 at all other sites, and concentrations of SO42- reached 7,000 ??eq L-1, compared to maximum concentrations below 120 ??eq L-1 at the other sites. Inverse geochemical modelling suggests that dissolution of pyrite, epidote, chlorite and minor calcite as well as the precipitation of silica and goethite best explain these elevated concentrations of solutes in the outflow of the rock glacier. Three component hydrograph separation using end-member mixing analysis shows that melted snow comprised an average of 30% of RG5 outflow, soil water 32%, and base flow 38%. Snow was the dominant source water in June, soil water was the dominant water source in July, and base flow was the dominant source in September. Enrichment of ?? 18O from - 10??? in the outflow of the rock glacier compared to -20??? in snow and enrichment of deuterium excess from +17.5??? in rock glacier outflow compared to +11??? in snow, suggests that melt of internal ice that had undergone multiple melt/freeze episodes was the dominant source of base flow. Copyright ?? 2005 John Wiley & Sons, Ltd.

HOWARD FORK ACID ROCK DRAINAGE SOURCE INTERCEPTION STUDY; HOWARD FORK OF THE SAN MIGUEL RIVER NEAR OPHIR, COLORADO

EPA Science Inventory

This project proposes to analyze regional hydrogeology as it relates to mine workings which discharge significant heavy metals into the Howard Fork of the San Miguel River and recommend strategies to intercept and divert water away from mineralized zones. The study also includes...

Geologic Assessment of Undiscovered Gas Resources of the Eastern Oregon and Washington Province

USGS Publications Warehouse

U.S. Geological Survey Eastern Oregon and Washington Province Assessment Team, (compiler)

2008-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered oil and gas potential of the Eastern Oregon and Washington Province of Oregon and Washington (USGS Province 5005). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Eastern Oregon and Washington Province, the USGS used this geologic framework to define one total petroleum system and two assessment units within the total petroleum system, and quantitatively estimated the undiscovered gas resources within each assessment unit.

Extended 3{beta}-alkyl steranes and 3-alkyl triaromatic steroids in crude oils and rock extracts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dahl, J.; Moldowan, J.M.; Summons, R.E.

1995-09-01

In oils and Precambian- to Miocene-age source rocks from varying depositional environments, we have conclusively identified several novel 3-alkyl sterane and triaromatic steroid series, including (1) 3{beta}-n-pentyl steranes, (2) 3{beta}-isopentyl steranes, (3) 3{beta}-n-hexyl steranes, (4) 3{beta}-n-hepatyl steranes, (5) 3,4-dimethyl steranes, (6) 3{beta}-butyl,4-methyl steranes, (7) triaromatic 3-n-pentyl steroids, and (8) triaromatic 3-isopentyl steroids. We have also tentatively identified additional homologs with 3-alkyl substituents as large as C{sub 11}. The relative abundances of these compounds vary substantially between samples, as indicated by (1) the ratio of 3{beta}-n-pentyl steranes to 3{beta}-isopentyl steranes and (2) the ratio of 3-n-pentyl triaromatic steroids to 3-isopentyl triaromaticmore » steroids. These data suggest possible utility for these parameters as tools for oil-source rock correlations and reconstruction of depositional environments. Although no 3-alkyl steroid natural products are currently known, several lines of evidence suggest that 3{beta}-alkyl steroids result from bacterial side-chain additions to diagenetic {delta}{sup 2}-sterenes.« less

Petroleum systems and geologic assessment of undiscovered oil and gas, Cotton Valley group and Travis Peak-Hosston formations, East Texas basin and Louisiana-Mississippi salt basins provinces of the northern Gulf Coast region. Chapters 1-7.

USGS Publications Warehouse

,

2006-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas potential of the Cotton Valley Group and Travis Peak and Hosston Formations in the East Texas Basin and Louisiana-Mississippi Salt Basins Provinces in the Gulf Coast Region (USGS Provinces 5048 and 5049). The Cotton Valley Group and Travis Peak and Hosston Formations are important because of their potential for natural gas resources. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and eight assessment units. Seven assessment units were quantitatively assessed for undiscovered oil and gas resources.

The modern atmospheric background dust load: Recognition in Central Asian snowpack, and compositional constraints

USGS Publications Warehouse

Hinkley, T.; Pertsiger, F.; Zavjalova, L.

1997-01-01

Dusts in strata of snowpack in the Alai-Pamir range, Kirghizstan, Central Asia, have chemical compositions that are in the same restricted range as those of the dusts found in snowpacks at three other locations: central south Greenland, the St. Elias range (Alaska), and coastal Antarctica, where special-type local dust sources certainly cannot dominate. This similarity at the four widely separated sites appears to indicate that there is a modern atmospheric background dust that is the same on a regional, hemispheric, or global scale. The common compositional range is that of average crustal rock, or of moderately ferromagnesian volcanic rock. It is not that of carbonate, nor highly siliciceous rocks. Previously, the existence of an atmospheric background dust has been postulated only on the basis of its particle size distribution, and only from observations in polar regions. The present study partially determines the chemical composition of the background dust, and confirms its existence in snowpack at four localities worldwide, including the center of the earth's largest continent where dusts of local source have considerable influence. U.S. copyright. Published in 1997 by the American Geophysical Union.

Hydrogen in rocks: an energy source for deep microbial communities

NASA Technical Reports Server (NTRS)

Freund, Friedemann; Dickinson, J. Thomas; Cash, Michele

2002-01-01

To survive in deep subsurface environments, lithotrophic microbial communities require a sustainable energy source such as hydrogen. Though H2 can be produced when water reacts with fresh mineral surfaces and oxidizes ferrous iron, this reaction is unreliable since it depends upon the exposure of fresh rock surfaces via the episodic opening of cracks and fissures. A more reliable and potentially more voluminous H2 source exists in nominally anhydrous minerals of igneous and metamorphic rocks. Our experimental results indicate that H2 molecules can be derived from small amounts of H2O dissolved in minerals in the form of hydroxyl, OH- or O3Si-OH, whenever such minerals crystallized in an H2O-laden environment. Two types of experiments were conducted. Single crystal fracture experiments indicated that hydroxyl pairs undergo an in situ redox conversion to H2 molecules plus peroxy links, O3Si/OO\\SiO3. While the peroxy links become part of the mineral structure, the H2 molecules diffused out of the freshly fractured mineral surfaces. If such a mechanism occurred in natural settings, the entire rock column would become a volume source of H2. Crushing experiments to facilitate the outdiffusion of H2 were conducted with common crustal igneous rocks such as granite, andesite, and labradorite. At least 70 nmol of H2/g diffused out of coarsely crushed andesite, equivalent at standard pressure and temperature to 5,000 cm3 of H2/m3 of rock. In the water-saturated, biologically relevant upper portion of the rock column, the diffusion of H2 out of the minerals will be buffered by H2 saturation of the intergranular water film.

Egret-Hibernia(!), a significant petroleum system, northern Grand Banks area, offshore eastern Canada

USGS Publications Warehouse

Magoon, L.B.; Hudson, T.L.; Peters, K.E.

2005-01-01

Egret-Hibernia(!) is a well-explored petroleum system (3.25 billion barrels oil equivalent [BOE]) located in the Jeanne d'Arc Basin on the Labrador - Newfoundland shelf. Rifting and sediment fill began in the Late Triassic. Egret source rock was deposited in the Late Jurassic at about 153 Ma. After this time, alternating reservoir rock and seal rock were deposited with some syndepositional faulting. By the end of the Early Cretaceous, faults and folds had formed numerous structural traps. For the next 100 m.y., overburden rock thermally matured the source rock when it reached almost 4 km (2.5 mi) burial depth. For 2 km (1.25 mi) below this depth, oil and gas were expelled, until the source was depleted. The expelled petroleum migrated updip to nearby faulted, anticlinal traps, where much of it migrated across faults and upsection to the Hibernia Formation (44% recoverable oil) and Avalon Formation (28%). Accumulation size decreased, and gas content increased from west to east, independent of trap size. These changes correspond to a decrease in source rock richness and quality from west to east. Almost all (96%) of the discovered petroleum resides in the Lower Cretaceous or older reservoir rock units. All accumulations found to date are normally pressured in structural traps. Fifty-two exploration wells found eighteen discoveries. Their size ranges from 1.2 to 0.01 billion BOE. Most discoveries were made between 1979 and 1991. The discovery cycle began with larger accumulations and progressed to smaller accumulations. The estimated sizes of the larger accumulations have grown since 1990. Estimated mean value for undiscovered hydrocarbons is 3.8 billion BOE, thereby raising the ultimate size of Egret-Hibernia(!) to 6.19 billion BOE. Copyright ?? 2005. The American Association of Petroleum Geologists. All rights reserved.

Hitherto unknown shear rupture mechanism as a source of instability in intact hard rocks at highly confined compression

NASA Astrophysics Data System (ADS)

Tarasov, Boris G.

2014-05-01

Today, frictional shear resistance along pre-existing faults is considered to be the lower limit on rock shear strength for confined conditions corresponding to the seismogenic layer. This paper introduces a recently identified shear rupture mechanism providing a paradoxical feature of hard rocks - the possibility of shear rupture propagation through the highly confined intact rock mass at shear stress levels significantly less than frictional strength. In the new mechanism, the rock failure associated with consecutive creation of small slabs (known as ‘domino-blocks') from the intact rock in the rupture tip is driven by a fan-shaped domino structure representing the rupture head. The fan-head combines such unique features as: extremely low shear resistance, self-sustaining stress intensification, and self-unbalancing conditions. Due to this the failure process caused by the mechanism is very dynamic and violent. This makes it impossible to directly observe and study the mechanism and can explain why the mechanism has not been detected before. This paper provides physical motivation for the mechanism, based upon side effects accompanying the failure process. Physical and mathematical models of the mechanism presented in the paper explain unique and paradoxical features of the mechanism. The new shear rupture mechanism allows a novel point of view for understanding the nature of spontaneous failure processes in hard rocks including earthquakes.

Extracting real-crack properties from non-linear elastic behaviour of rocks: abundance of cracks with dominating normal compliance and rocks with negative Poisson ratios

NASA Astrophysics Data System (ADS)

Zaitsev, Vladimir Y.; Radostin, Andrey V.; Pasternak, Elena; Dyskin, Arcady

2017-09-01

Results of examination of experimental data on non-linear elasticity of rocks using experimentally determined pressure dependences of P- and S-wave velocities from various literature sources are presented. Overall, over 90 rock samples are considered. Interpretation of the data is performed using an effective-medium description in which cracks are considered as compliant defects with explicitly introduced shear and normal compliances without specifying a particular crack model with an a priori given ratio of the compliances. Comparison with the experimental data indicated abundance (˜ 80 %) of cracks with the normal-to-shear compliance ratios that significantly exceed the values typical of conventionally used crack models (such as penny-shaped cuts or thin ellipsoidal cracks). Correspondingly, rocks with such cracks demonstrate a strongly decreased Poisson ratio including a significant (˜ 45 %) portion of rocks exhibiting negative Poisson ratios at lower pressures, for which the concentration of not yet closed cracks is maximal. The obtained results indicate the necessity for further development of crack models to account for the revealed numerous examples of cracks with strong domination of normal compliance. Discovering such a significant number of naturally auxetic rocks is in contrast to the conventional viewpoint that occurrence of a negative Poisson ratio is an exotic fact that is mostly discussed for artificial structures.

Application of uniaxial confining-core clamp with hydrous pyrolysis in petrophysical and geochemical studies of source rocks at various thermal maturities

USGS Publications Warehouse

Lewan, Michael D.; Birdwell, Justin E.; Baez, Luis; Beeney, Ken; Sonnenberg, Steve

2013-01-01

Understanding changes in petrophysical and geochemical parameters during source rock thermal maturation is a critical component in evaluating source-rock petroleum accumulations. Natural core data are preferred, but obtaining cores that represent the same facies of a source rock at different thermal maturities is seldom possible. An alternative approach is to induce thermal maturity changes by laboratory pyrolysis on aliquots of a source-rock sample of a given facies of interest. Hydrous pyrolysis is an effective way to induce thermal maturity on source-rock cores and provide expelled oils that are similar in composition to natural crude oils. However, net-volume increases during bitumen and oil generation result in expanded cores due to opening of bedding-plane partings. Although meaningful geochemical measurements on expanded, recovered cores are possible, the utility of the core for measuring petrophysical properties relevant to natural subsurface cores is not suitable. This problem created during hydrous pyrolysis is alleviated by using a stainless steel uniaxial confinement clamp on rock cores cut perpendicular to bedding fabric. The clamp prevents expansion just as overburden does during natural petroleum formation in the subsurface. As a result, intact cores can be recovered at various thermal maturities for the measurement of petrophysical properties as well as for geochemical analyses. This approach has been applied to 1.7-inch diameter cores taken perpendicular to the bedding fabric of a 2.3- to 2.4-inch thick slab of Mahogany oil shale from the Eocene Green River Formation. Cores were subjected to hydrous pyrolysis at 360 °C for 72 h, which represents near maximum oil generation. One core was heated unconfined and the other was heated in the uniaxial confinement clamp. The unconfined core developed open tensile fractures parallel to the bedding fabric that result in a 38 % vertical expansion of the core. These open fractures did not occur in the confined core, but short, discontinuous vertical fractures on the core periphery occurred as a result of lateral expansion.

Implications of Late Cretaceous U-Pb zircon ages of granitic intrusions cutting ophiolitic and volcanogenic rocks for the assembly of the Tauride allochthon in SE Anatolia (Helete area, Kahramanmaraş Region, SE Turkey)

NASA Astrophysics Data System (ADS)

Nurlu, Nusret; Parlak, Osman; Robertson, Alastair; von Quadt, Albrecht

2016-01-01

An assemblage of NE-SW-trending, imbricate thrust slices (c. 26 km E-W long × 6.3 km N-S) of granitic rocks, basic-felsic volcanogenic rocks (Helete volcanics), ophiolitic rocks (Meydan ophiolite) and melange (Meydan melange) is exposed near the Tauride thrust front in SE Anatolia. The volcanogenic rocks were previously assumed to be Eocene because of associated Nummulitic limestones. However, ion probe U-Pb dating of zircons extracted from the intrusive granitic rocks yielded ages of 92.9 ± 2.2-83.1 ± 1.5 Ma (Cenomanian-Campanian). The Helete volcanic unit and the overlying Meydan ophiolitic rocks both are intruded by granitic rocks of similar age and composition. Structurally underlying ophiolite-related melange includes similar-aged, but fragmented granitic intrusions. Major, trace element and rare earth element analyses coupled with electron microprobe analysis of the granitic rocks show that they are metaluminus to peraluminus and calc-alkaline in composition. A magmatic arc setting is inferred from a combination of tectonomagmatic discrimination, ocean ridge granite-normalized multi-element patterns and biotite geochemistry. Sr-Nd-Pb isotope data further suggest that the granitoid rocks were derived from variably mixed mantle and crustal sources. Granitic rocks cutting the intrusive rocks are inferred to have crystallized at ~5-16 km depth. The volcanogenic rocks and granitic rocks originated in a supra-subduction zone setting that was widely developed throughout SE Anatolia. Initial tectonic assembly took place during the Late Cretaceous probably related to northward subduction and accretion beneath the Tauride continent (Keban and Malatya platforms). Initial tectonic assembly was followed by exhumation and then transgression by shelf-depth Nummulitic limestones during Mid-Eocene, as documented in several key outcrops. Final emplacement onto the Arabian continental margin took place during the Early Miocene.

Geochemistry of the Archean Yellowknife Supergroup

NASA Astrophysics Data System (ADS)

Jenner, G. A.; Fryer, B. J.; McLennan, S. M.

1981-07-01

The Archean Yellowknife Supergroup (Slave Structural Province. Canada) is composed of a thick sequence of supracrustal rocks, which differs from most Archean greenstone belts in that it contains a large proportion ( ~ 80%) of sedimentary rocks. Felsic volcanics of the Banting Formation are characterized by HREE depletion without Eu-anomalies, indicating an origin by small degrees of partial melting of a mafic source, with minor garnet in the residua. Granitic rocks include synkinematic granites [HREE-depleted; low ( 87Sr /86Sr ) I], post-kinematic granites [negative Eu-anomalies, high ( 87Sr /86Sr ) I] and granitic gneisses with REE patterns similar to the post-kinematic granites. Sedimentary rocks (turbidites) of the Burwash and Walsh Formations have similar chemical compositions and were derived from 20% mafic-intermediate volcanics, 55% felsic volcanics and 25% granitic rocks. Jackson Lake Formation lithic wackes can be divided into two groups with Group A derived from 50% mafic-intermediate volcanics and 50% felsic volcanics and Group B, characterized by HREE depletion, derived almost exclusively from felsic volcanics. REE patterns of Yellowknife sedimentary rocks are similar to other Archean sedimentary REE patterns, although they have higher La N/Yb N. These patterns differ significantly from typical post-Archean sedimentary REE patterns, supporting the idea that Archean exposed crust had a different composition than the present day exposed crust.

The Influence of Lithology on the Formation of Reaction Infiltration Instabilities in Mantle Rocks

NASA Astrophysics Data System (ADS)

Pec, M.; Holtzman, B. K.; Zimmerman, M. E.; Kohlstedt, D. L.

2017-12-01

The formation of oceanic plates requires extraction of large volumes of melt from the mantle. Several lines of evidence suggest that melt extraction is rapid and, therefore, necessitates high-permeability pathways. Such pathways may form as a result of melt-rock reactions. We report the results of a series of Darcy-type experiments designed to study the development of channels due to melt-solid reactions in mantle lithologies. We sandwiched a partially molten rock between a melt source and a porous sink and annealed it at high pressure (P = 300 MPa) and high temperatures (T = 1200° or 1250°C) with a controlled pressure gradient (∂P/∂z = 0-100 MPa/mm). To study the influence of lithology on the channel formation, we synthesized partially molten rocks of harzburgitic (40:40:20 Ol - Opx - basalt), wehrlitic (40:40:20 Ol - Cpx - basalt) and lherzolitic (65:25:10 Ol - Opx - Cpx) composition. The melt source was a disk of alkali basalt. In all experiments, irrespective of the exact mineralogy, melt - undersaturated in silica - from the source dissolved pyroxene in the partially molten rock and precipitated olivine ( Fo82), thereby forming a dunite reaction layer at the interface between the source and the partially molten rock. In samples annealed under a small pressure gradient, the reaction layer was roughly planar. However, if the velocity of melt due to porous flow exceeded 0.1 µm/s, the reaction layer locally protruded into the partially molten rock forming finger-like, melt-rich channels in rocks of wehrlitic and harzburgitic composition. The lherzolitic rocks were generally impermeable to the melt except at highest-pressure gradients where a narrow fracture developed, forming a dyke which drained the melt reservoir. Three-dimensional reconstructions using micro-CT images revealed clear differences between the dyke (a narrow, through-going planar feature) and the channels formed by reactive infiltration (multiple sinuous finger-like features). Apparently, the fraction of soluble minerals together with the melt fraction in the partially molten rock control whether dykes or reactive channels develop. Our experiments demonstrate that melt-rock reactions can lead to channelization in mantle lithologies, and the observed lithological transformations broadly agree with those observed in nature

Origin of sulfur for elemental sulfur concentration in salt dome cap rocks, Gulf Coast Basin, USA

NASA Astrophysics Data System (ADS)

Hill, J. M.; Kyle, R.; Loyd, S. J.

2017-12-01

Calcite cap rocks of the Boling and Main Pass salt domes contain large elemental sulfur accumulations. Isotopic and petrographic data indicate complex histories of cap rock paragenesis for both domes. Whereas paragenetic complexity is in part due to the open nature of these hydrodynamic systems, a comprehensive understanding of elemental sulfur sources and concentration mechanisms is lacking. Large ranges in traditional sulfur isotope compositions (δ34S) among oxidized and reduced sulfur-bearing phases has led some to infer that microbial sulfate reduction and/or influx of sulfide-rich formation waters occurred during calcite cap rock formation. Ultimately, traditional sulfur isotope analyses alone cannot distinguish among local microbial or exogenous sulfur sources. Recently, multiple sulfur isotope (32S, 33S, 34S, 36S) studies reveal small, but measurable differences in mass-dependent behavior of microbial and abiogenic processes. To distinguish between the proposed sulfur sources, multiple-sulfur-isotope analyses have been performed on native sulfur from the Boling and Main Pass cap rocks. Similarities or deviations from equilibrium relationships indicate which pathways were responsible for native sulfur precipitation. Pathway determination provides insight into Gulf Coast cap rock development and potentially highlights the conditions that led to anomalous sulfur enrichment in Boling and Main Pass Domes.

New insights on timing of oil and gas generation in the central Gulf Coast interior zone based on hydrous-pyrolysis kinetic parameters

USGS Publications Warehouse

Lewan, Michael D.; Dutton, Shirley P.; Ruppel, Stephen C.; Hentz, Tucker F.

2002-01-01

Timing of oil and gas generation from Turonian and Smackover source rocks in the central Gulf CoastInterior Zone was determined in one-dimensional burial-history curves (BHCs) using hydrous-pyrolysis kinetic parameters. The results predict that basal Smackover source-rock intervals with Type-IIS kerogen completed oil generation between 121 and 99 Ma, and Turonian source-rocks with Type-II kerogen remain immature over most of the same area. The only exception to the latter occurs in the northwestern part of the Mississippi salt basin, where initial stages of oil generation have started as a result of higher thermal gradients. This maturity difference between Turonian and Smackover source rocks is predicted with present-day thermal gradients. Predicted oil generation prior to the Sabine and Monroe uplifts suggests that a significant amount of the oil emplaced in Cretaceous reservoirs of these uplifts would have been lost during periods of erosion. Hydrous-pyrolysis kineticparameters predict that cracking of Smackover oil to gas started 52 Ma, which postdates major uplift and erosional events of the Sabine and Monroe uplifts. This generated gas would accumulate and persist in these uplift areas as currently observed. The predicted timing of oil and gas generation with hydrous-pyrolysis kinetic parameters is in accordance with the observed scarcity of oil from Turonian source rocks, predominance of gas accumulations on the Sabine and Monroe uplifts, and predominance of oil accumulations along the northern rim of the Interior Zone.

Pb, Sr, and Nd isotopic compositions of a suite of Late Archean, igneous rocks, eastern Beartooth Mountains: implications for crust-mantle evolution

USGS Publications Warehouse

Wooden, J.L.; Mueller, P.A.

1988-01-01

A series of compositionally diverse, Late Archean rocks (2.74-2.79 Ga old) from the eastern Beartooth Mountains, Montana and Wyoming, U.S.A., have the same initial Pb, Sr, and Nd isotopic ratios. Lead and Sr initial ratios are higher and Nd initial ratios lower than would be expected for rocks derived from model mantle sources and strongly indicate the involvement of an older crustal reservoir in the genesis of these rocks. Crustal contamination during emplacement can be ruled out for a variety of reasons. Instead a model involving subduction of continental detritus and contamination of the overlying mantle as is often proposed for modern subduction environments is preferred. This contaminated mantle would have all the isotopic characteristics of mantle enriched by internal mantle metasomatism but would require no long-term growth or changes in parent to daughter element ratios. This contaminated mantle would make a good source for some of the Cenozoic mafic volcanics of the Columbia River, Snake River Plain, and Yellowstone volcanic fields that are proposed to come from ancient, enriched lithospheric mantle. The isotopic characteristics of the 2.70 Ga old Stillwater Complex are a perfect match for the proposed contaminated mantle which provides an alternative to crustal contamination during emplacement. The Pb isotopic characteristics of the Late Archean rocks of the eastern Beartooth Mountains are similar to those of other Late Archean rocks of the Wyoming Province and suggest that Early Archean, upper crustal rocks were common in this terrane. The isotopic signatures of Late Archean rocks in the Wyoming Province are distinctive from those of other Archean cratons in North America which are dominated by a MORB-like, Archean mantle source (Superior Province) and/or a long-term depleted crustal source (Greenland). ?? 1988.

Uranium enrichment in lacustrine oil source rocks of the Chang 7 member of the Yanchang Formation, Erdos Basin, China

NASA Astrophysics Data System (ADS)

Yang, Hua; Zhang, Wenzheng; Wu, Kai; Li, Shanpeng; Peng, Ping'an; Qin, Yan

2010-09-01

The oil source rocks of the Chang 7 member of the Yanchang Formation in the Erdos Basin were deposited during maximum lake extension during the Late Triassic and show a remarkable positive uranium anomaly, with an average uranium content as high as 51.1 μg/g. Uranium is enriched together with organic matter and elements such as Fe, S, Cu, V and Mo in the rocks. The detailed biological markers determined in the Chang 7 member indicate that the lake water column was oxidizing during deposition of the Chang 7 member. However, redox indicators for sediments such as S 2- content, V/Sc and V/(V + Ni) ratios demonstrate that it was a typical anoxic diagenetic setting. The contrasted redox conditions between the water column and the sediment with a very high content of organic matter provided favorable physical and chemical conditions for syngenetic uranium enrichment in the oil source rocks of the Chang 7 member. Possible uranium sources may be the extensive U-rich volcanic ash that resulted from contemporaneous volcanic eruption and uranium material transported by hydrothermal conduits into the basin. The uranium from terrestrial clastics was unlike because uranium concentration was not higher in the margin area of basin where the terrestrial material input was high. As indicated by correlative analysis, the oil source rocks of the Chang 7 member show high gamma-ray values for radioactive well log data that reflect a positive uranium anomaly and are characterized by high resistance, low electric potential and low density. As a result, well log data can be used to identify positive uranium anomalies and spatial distribution of the oil source rocks in the Erdos Basin. The estimation of the total uranium reserves in the Chang 7 member attain 0.8 × 10 8 t.

Seismological evidence for monsoon induced micro to moderate earthquake sequence beneath the 2011 Talala, Saurashtra earthquake, Gujarat, India

NASA Astrophysics Data System (ADS)

Singh, A. P.; Mishra, O. P.

2015-10-01

In order to understand the processes involved in the genesis of monsoon induced micro to moderate earthquakes after heavy rainfall during the Indian summer monsoon period beneath the 2011 Talala, Saurashtra earthquake (Mw 5.1) source zone, we assimilated 3-D microstructures of the sub-surface rock materials using a data set recorded by the Seismic Network of Gujarat (SeisNetG), India. Crack attributes in terms of crack density (ε), the saturation rate (ξ) and porosity parameter (ψ) were determined from the estimated 3-D sub-surface velocities (Vp, Vs) and Poisson's ratio (σ) structures of the area at varying depths. We distinctly imaged high-ε, high-ξ and low-ψ anomalies at shallow depths, extending up to 9-15 km. We infer that the existence of sub-surface fractured rock matrix connected to the surface from the source zone may have contributed to the changes in differential strain deep down to the crust due to the infiltration of rainwater, which in turn induced micro to moderate earthquake sequence beneath Talala source zone. Infiltration of rainwater during the Indian summer monsoon might have hastened the failure of the rock by perturbing the crustal volume strain of the causative source rock matrix associated with the changes in the seismic moment release beneath the surface. Analyses of crack attributes suggest that the fractured volume of the rock matrix with high porosity and lowered seismic strength beneath the source zone might have considerable influence on the style of fault displacements due to seismo-hydraulic fluid flows. Localized zone of micro-cracks diagnosed within the causative rock matrix connected to the water table and their association with shallow crustal faults might have acted as a conduit for infiltrating the precipitation down to the shallow crustal layers following the fault suction mechanism of pore pressure diffusion, triggering the monsoon induced earthquake sequence beneath the source zone.

Coal-type gas provinces in China and their geochemical characteristics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Xiaobao; Xu Yonghang; Shen Ping

1996-12-31

The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH{sub 4} content ofthe gases there is 83 -90%, with {delta}{sup 13}C{sub 1} -35.5 {approximately} -39.9{per_thousand}, and {delta}{sup 13}C{sub 2} -24.0 {approximately} -26.8{per_thousand}. Themore » {delta}{sup 13}C of condensate oils associated with the gases ranges from -25.4{per_thousand} to -26.8{per_thousand}. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The {delta}{sup 13}C{sub 1} of the gases there is -37.9 {approximately} -37. l{per_thousand}, with the {delta}{sup 13}C of condensate oil accompanying them - 25.1 {approximately} -26.6{per_thousand}. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH{sub 4} content of the gases there varies from 60 to 90%, with {delta}{sup 13}C{sub 1} from - 38.7 to -43.7{per_thousand} and {delta} {sup 13}C{sub 2} from -25.9{per_thousand} to -29.9{per_thousand}. The {delta} {sup 13}C of light oils and condensate oils accompanying the gases changes from 24.3{per_thousand} to 27.8{per_thousand}.« less

Coal-type gas provinces in China and their geochemical characteristics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Xiaobao; Xu Yonghang; Shen Ping

1996-01-01

The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH[sub 4] content ofthe gases there is 83 -90%, with [delta][sup 13]C[sub 1] -35.5 [approximately] -39.9[per thousand], and [delta][sup 13]C[sub 2] -24.0 [approximately] -26.8[permore » thousand]. The [delta][sup 13]C of condensate oils associated with the gases ranges from -25.4[per thousand] to -26.8[per thousand]. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The [delta][sup 13]C[sub 1] of the gases there is -37.9 [approximately] -37. l[per thousand], with the [delta][sup 13]C of condensate oil accompanying them - 25.1 [approximately] -26.6[per thousand]. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH[sub 4] content of the gases there varies from 60 to 90%, with [delta][sup 13]C[sub 1] from - 38.7 to -43.7[per thousand] and [delta] [sup 13]C[sub 2] from -25.9[per thousand] to -29.9[per thousand]. The [delta] [sup 13]C of light oils and condensate oils accompanying the gases changes from 24.3[per thousand] to 27.8[per thousand].« less

Re-Os systematics of komatiites and komatiitic basalts at Dundonald Beach, Ontario, Canada: Evidence for a complex alteration history and implications of a late-Archean chondritic mantle source

NASA Astrophysics Data System (ADS)

Gangopadhyay, Amitava; Sproule, Rebecca A.; Walker, Richard J.; Lesher, C. Michael

2005-11-01

Osmium isotopic compositions, and Re and Os concentrations have been examined in one komatiite unit and two komatiitic basalt units at Dundonald Beach, part of the 2.7 Ga Kidd-Munro volcanic assemblage in the Abitibi greenstone belt, Ontario, Canada. The komatiitic rocks in this locality record at least three episodes of alteration of Re-Os elemental and isotope systematics. First, an average of 40% and as much as 75% Re may have been lost due to shallow degassing during eruption and/or hydrothermal leaching during or immediately after emplacement. Second, the Re-Os isotope systematics of whole rock samples with 187Re/ 188Os ratios >1 were reset at ˜2.5 Ga, possibly due to a regional metamorphic event. Third, there is evidence for relatively recent gain and loss of Re in some rocks. Despite the open-system behavior, some aspects of the Re-Os systematics of these rocks can be deciphered. The bulk distribution coefficient for Os (D Ossolid/liquid) for the Dundonald rocks is ˜3 ± 1 and is well within the estimated D values obtained for komatiites from the nearby Alexo area and stratigraphically-equivalent komatiites from Munro Township. This suggests that Os was moderately compatible during crystal-liquid fractionation of the magmas parental to the Kidd-Munro komatiitic rocks. Whole-rock samples and chromite separates with low 187Re/ 188Os ratios (<1) yield a precise chondritic average initial 187Os/ 188Os ratio of 0.1083 ± 0.0006 (γ Os = 0.0 ± 0.6) for their well-constrained ˜2715 Ma crystallization age. The chondritic initial Os isotopic composition of the mantle source for the Dundonald rocks is consistent with that determined for komatiites in the Alexo area and in Munro Township, suggesting that the mantle source region for the Kidd-Munro volcanic assemblage had evolved with a long-term chondritic Re/Os before eruption. The chondritic initial Os isotopic composition of the Kidd-Munro komatiites is indistinguishable from that of the projected contemporaneous convective upper mantle. The uniform chondritic Os isotopic composition of the Kidd-Munro komatiites contrasts with the typical large-scale Os isotopic heterogeneity in the mantle sources for ca. 89 Ma komatiites from the Gorgona Island, arc-related rocks and present-day ocean island basalts. This suggests that the Kidd-Munro komatiites sampled a late-Archean mantle source region that was significantly more homogeneous with respect to Re/Os relative to most modern mantle-derived rocks.

Intrusive Rock Database for the Digital Geologic Map of Utah

USGS Publications Warehouse

Nutt, C.J.; Ludington, Steve

2003-01-01

Digital geologic maps offer the promise of rapid and powerful answers to geologic questions using Geographic Information System software (GIS). Using modern GIS and database methods, a specialized derivative map can be easily prepared. An important limitation can be shortcomings in the information provided in the database associated with the digital map, a database which is often based on the legend of the original map. The purpose of this report is to show how the compilation of additional information can, when prepared as a database that can be used with the digital map, be used to create some types of derivative maps that are not possible with the original digital map and database. This Open-file Report consists of computer files with information about intrusive rocks in Utah that can be linked to the Digital Geologic Map of Utah (Hintze et al., 2000), an explanation of how to link the databases and map, and a list of references for the databases. The digital map, which represents the 1:500,000-scale Geologic Map of Utah (Hintze, 1980), can be obtained from the Utah Geological Survey (Map 179DM). Each polygon in the map has a unique identification number. We selected the polygons identified on the geologic map as intrusive rock, and constructed a database (UT_PLUT.xls) that classifies the polygons into plutonic map units (see tables). These plutonic map units are the key information that is used to relate the compiled information to the polygons on the map. The map includes a few polygons that were coded as intrusive on the state map but are largely volcanic rock; in these cases we note the volcanic rock names (rhyolite and latite) as used in the original sources Some polygons identified on the digital state map as intrusive rock were misidentified; these polygons are noted in a separate table of the database, along with some information about their true character. Fields may be empty because of lack of information from references used or difficulty in finding information. The information in the database is from a variety of sources, including geologic maps at scales ranging from 1:500,000 to 1:24,000, and thesis monographs. The references are shown twice: alphabetically and by region. The digital geologic map of Utah (Hintze and others, 2000) classifies intrusive rocks into only 3 categories, distinguished by age. They are: Ti, Tertiary intrusive rock; Ji, Upper to Middle Jurassic granite to quartz monzonite; and pCi, Early Proterozoic to Late Archean intrusive rock. Use of the tables provided in this report will permit selection and classification of those rocks by lithology and age. This database is a pilot study by the Survey and Analysis Project of the U.S. Geological Survey to characterize igneous rocks and link them to a digital map. The database, and others like it, will evolve as the project continues and other states are completed. We release this version now as an example, as a reference, and for those interested in Utah plutonic rocks.

Determining the spatial altitude of the hydraulic fractures.

NASA Astrophysics Data System (ADS)

Khamiev, Marsel; Kosarev, Victor; Goncharova, Galina

2016-04-01

Mathematical modeling and numerical simulation are the most widely used approaches for the solving geological problems. They imply software tools which are based on Monte Carlo method. The results of this project presents shows the possibility of using PNL tool to determine fracturing location. The modeled media is a homogeneous rock (limestone) cut by a vertical borehole (d=216 mm) with metal casing 9 mm thick. The cement sheath is 35 mm thick. The borehole is filled with fresh water. The rock mass is cut by crack, filled with a mixture of doped (gadolinium oxide Gd2O3) proppant (75%) and water (25%). A pulse neutron logging (PNL) tool is used for quality control in hydraulic fracturing operations. It includes a fast neutron source (so-called "neutron generator") and a set of thermal (or epithermal) neutron-sensing devices, forming the so-called near (ND) and far (FD) detectors. To evaluate neutron properties various segments (sectors) of the rock mass, the detector must register only neutrons that come from this very formation. It's possible if detecting block includes some (6 for example) thermal neutron detectors arranged circumferentially inside the tool. As a result we get few independent well logs, each accords with define rock sector. Afterwards synthetic logs processing we can determine spatial position of the hydraulic fracture.

Dynamics of the Bingham Canyon rock avalanches (Utah, USA) resolved from topographic, seismic, and infrasound data: Bingham Canyon Rock Avalanches

DOE PAGES

Moore, Jeffrey R.; Pankow, Kristine L.; Ford, Sean R.; ...

2017-03-01

The 2013 Bingham Canyon Mine rock avalanches represent one of the largest cumulative landslide events in recorded U.S. history and provide a unique opportunity to test remote analysis techniques for landslide characterization. We combine aerial photogrammetry surveying, topographic reconstruction, numerical runout modeling, and analysis of broadband seismic and infrasound data to extract salient details of the dynamics and evolution of the multiphase landslide event. Our results reveal a cumulative intact rock source volume of 52 Mm 3, which mobilized in two main rock avalanche phases separated by 1.5 h. We estimate that the first rock avalanche had 1.5–2 times greatermore » volume than the second. Each failure initiated by sliding along a gently dipping (21°), highly persistent basal fault before transitioning to a rock avalanche and spilling into the inner pit. The trajectory and duration of the two rock avalanches were reconstructed using runout modeling and independent force history inversion of intermediate-period (10–50 s) seismic data. Intermediate- and shorter-period (1–50 s) seismic data were sensitive to intervals of mass redirection and constrained finer details of the individual slide dynamics. Back projecting short-period (0.2–1 s) seismic energy, we located the two rock avalanches within 2 and 4 km of the mine. Further analysis of infrasound and seismic data revealed that the cumulative event included an additional 11 smaller landslides (volumes ~10 4–10 5 m 3) and that a trailing signal following the second rock avalanche may result from an air-coupled Rayleigh wave. These results demonstrate new and refined techniques for detailed remote characterization of the dynamics and evolution of large landslides.« less

Coupling geodynamic with thermodynamic modelling for reconstructions of magmatic systems

NASA Astrophysics Data System (ADS)

Rummel, Lisa; Kaus, Boris J. P.; White, Richard

2016-04-01

Coupling geodynamic with petrological models is fundamental for understanding magmatic systems from the melting source in the mantle to the point of magma crystallisation in the upper crust. Most geodynamic codes use very simplified petrological models consisting of a single, fixed, chemistry. Here, we develop a method to better track the petrological evolution of the source rock and corresponding volcanic and plutonic rocks by combining a geodynamic code with a thermodynamic model for magma generation and evolution. For the geodynamic modelling a finite element code (MVEP2) solves the conservation of mass, momentum and energy equations. The thermodynamic modelling of phase equilibria in magmatic systems is performed with pMELTS for mantle-like bulk compositions. The thermodynamic dependent properties calculated by pMELTS are density, melt fraction and the composition of the liquid and solid phase in the chemical system: SiO2-TiO2-Al2O3-Fe2O3-Cr2O3-FeO-MgO-CaO-Na2O-K2O-P2O5-H2O. In order to take into account the chemical depletion of the source rock with increasing melt extraction events, calculation of phase diagrams is performed in two steps: 1) With an initial rock composition density, melt fraction as well as liquid and solid composition are computed over the full upper mantle P-T range. 2) Once the residual rock composition (equivalent to the solid composition after melt extraction) is significantly different from the initial rock composition and the melt fraction is lower than a critical value, the residual composition is used for next calculations with pMELTS. The implementation of several melt extraction events take the change in chemistry into account until the solidus is shifted to such high temperatures that the rock cannot be molten anymore under upper mantle conditions. An advantage of this approach is that we can track the change of melt chemistry with time, which can be compared with natural constraints. In the thermo-mechanical code the thermodynamic dependent properties from pre-computed phase diagrams are carried by each particle using marker-in-cell method . Thus the physical and chemical properties can change locally as a function of previous melt extraction events, pressure and temperature conditions. After each melt extraction event, the residual rock composition is compared with the bulk composition of previous computed phase diagrams, so that the used phase diagram is replaced by the phase diagram with the closest bulk chemistry. In the thermo-mechanical code, the melt is extracted directly to the surface as volcanites and within the crust as plutonites. The density of the crust and new generated crust is calculated with the thermodynamic modelling tool Perple_X. We have investigated the influence of several input parameters on the magma composition to compare it with real rock samples from Eifel (West-Germany). In order to take the very inhomogeneous chemistry of European mantle into account, we include not only primitive mantle but also metasomatised mantle fragments in the melting source of a plume (Eifel plume).

A program to calculate pulse transmission responses through transversely isotropic media

NASA Astrophysics Data System (ADS)

Li, Wei; Schmitt, Douglas R.; Zou, Changchun; Chen, Xiwei

2018-05-01

We provide a program (AOTI2D) to model responses of ultrasonic pulse transmission measurements through arbitrarily oriented transversely isotropic rocks. The program is built with the distributed point source method that treats the transducers as a series of point sources. The response of each point source is calculated according to the ray-tracing theory of elastic plane waves. The program could offer basic wave parameters including phase and group velocities, polarization, anisotropic reflection coefficients and directivity patterns, and model the wave fields, static wave beam, and the observed signals for pulse transmission measurements considering the material's elastic stiffnesses and orientations, sample dimensions, and the size and positions of the transmitters and the receivers. The program could be applied to exhibit the ultrasonic beam behaviors in anisotropic media, such as the skew and diffraction of ultrasonic beams, and analyze its effect on pulse transmission measurements. The program would be a useful tool to help design the experimental configuration and interpret the results of ultrasonic pulse transmission measurements through either isotropic or transversely isotropic rock samples.

Building the 3D Geological Model of Wall Rock of Salt Caverns Based on Integration Method of Multi-source data

NASA Astrophysics Data System (ADS)

Yongzhi, WANG; hui, WANG; Lixia, LIAO; Dongsen, LI

2017-02-01

In order to analyse the geological characteristics of salt rock and stability of salt caverns, rough three-dimensional (3D) models of salt rock stratum and the 3D models of salt caverns on study areas are built by 3D GIS spatial modeling technique. During implementing, multi-source data, such as basic geographic data, DEM, geological plane map, geological section map, engineering geological data, and sonar data are used. In this study, the 3D spatial analyzing and calculation methods, such as 3D GIS intersection detection method in three-dimensional space, Boolean operations between three-dimensional space entities, three-dimensional space grid discretization, are used to build 3D models on wall rock of salt caverns. Our methods can provide effective calculation models for numerical simulation and analysis of the creep characteristics of wall rock in salt caverns.

The fate of diamondoids in coals and sedimentary rocks

USGS Publications Warehouse

Wei, Z.; Moldowan, J.M.; Jarvie, D.M.; Hill, R.

2006-01-01

Diamondoids were detected in the extracts of a series of coals and rocks varying in maturity, lithology, source input, and depositional environment. At the same maturity level, diamondoids are generally about a magnitude more abundant in source rocks than in coals. The concentrations of diamondoids are maturity dependent. However, while diamondoids become more abundant with the increasing thermal maturity, a diminution in diamondoid concentrations is observed at the maturity value of about Ro = 4.0% in both coals and rocks. The occurrence of diamantane destruction at 550 ??C during pyrolysis suggests that diamondoids may be eventually destroyed at high temperatures in the Earth. Here we propose three main phases of diamondoid life in nature: diamondoid generation (phase I, Ro 4.0%). ?? 2006 Geological Society of America.

Assessment of potential oil and gas resources in source rocks of the Alaska North Slope, 2012

USGS Publications Warehouse

Houseknecht, David W.; Rouse, William A.; Garrity, Christopher P.; Whidden, Katherine J.; Dumoulin, Julie A.; Schenk, Christopher J.; Charpentier, Ronald R.; Cook, Troy A.; Gaswirth, Stephanie B.; Kirschbaum, Mark A.; Pollastro, Richard M.

2012-01-01

The U.S. Geological Survey estimated potential, technically recoverable oil and gas resources for source rocks of the Alaska North Slope. Estimates (95-percent to 5-percent probability) range from zero to 2 billion barrels of oil and from zero to nearly 80 trillion cubic feet of gas.

Source-rock evaluation of outcrop samples from Vanuatu (Malakula, Espiritu Santo, Maewo, and Pentecost)

USGS Publications Warehouse

Buchbinder, Binyamin; Halley, Robert B.

1988-01-01

The samples collected for the present study represent only a portion of the sedimentary column in the various sedimentary basins of Vanuatu.  The characterize only the outer margins of the sedimentary basins and do not necessarily reflect the source-rock potential of the deeper (offshore) parts of the basins.

Publications - GMC 325 | Alaska Division of Geological & Geophysical

Science.gov Websites

(Hydrocarbon-Show) evaluation for 4 Husky Oil NPR Operations Inc. wells, and Source-Rock evaluation for 4 Husky Oil NPR Operations Inc. wells Authors: Huizinga, B.J. Publication Date: Jan 2006 Publisher: Alaska ) evaluation for 4 Husky Oil NPR Operations Inc. wells, and Source-Rock evaluation for 4 Husky Oil NPR

Evidence for Cambrian petroleum source rocks in the Rome trough of West Virginia and Kentucky, Appalachian basin: Chapter G.8 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Ryder, Robert T.; Harris, David C.; Gerome, Paul; Hainsworth, Timothy J.; Burruss, Robert A.; Lillis, Paul G.; Jarvie, Daniel M.; Pawlewicz, Mark J.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

The bitumen extract from the Rogersville Shale compares very closely with oils or condensates from Cambrian reservoirs in the Carson Associates No. 1 Kazee well, Homer gas field, Elliott County, Ky.; the Inland No. 529 White well, Boyd County, Ky.; and the Miller No. 1 well, Wolfe County, Ky. These favorable oil-source rock correlations suggest a new petroleum system in the Appalachian basin that is characterized by a Conasauga Group source rock and Rome Formation and Conasauga Group reservoirs. This petroleum system probably extends along the Rome trough from eastern Kentucky to at least central West Virginia.

Petroleum systems of the San Joaquin Basin Province -- geochemical characteristics of gas types: Chapter 10 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Lillis, Paul G.; Warden, Augusta; Claypool, George E.; Magoon, Leslie B.

2008-01-01

The San Joaquin Basin Province is a petroliferous basin filled with predominantly Late Cretaceous to Pliocene-aged sediments, with organic-rich marine rocks of Late Cretaceous, Eocene, and Miocene age providing the source of most of the oil and gas. Previous geochemical studies have focused on the origin of the oil in the province, but the origin of the natural gas has received little attention. To identify and characterize natural gas types in the San Joaquin Basin, 66 gas samples were analyzed and combined with analyses of 15 gas samples from previous studies. For the purpose of this resource assessment, each gas type was assigned to the most likely petroleum system. Three general gas types are identified on the basis of bulk and stable carbon isotopic composition—thermogenic dry (TD), thermogenic wet (TW) and biogenic (B). The thermogenic gas types are further subdivided on the basis of the δ13C values of methane and ethane and nitrogen content into TD-1, TD-2, TD-Mixed, TW-1, TW-2, and TW-Mixed. Gas types TD-1 and TD-Mixed, a mixture of biogenic and TD-1 gases, are produced from gas fields in the northern San Joaquin Basin. Type TD-1 gas most likely originated from the Late Cretaceous to Paleocene Moreno Formation, a gas-prone source rock. The biogenic component of the TD-Mixed gas existed in the trap prior to the influx of thermogenic gas. For the assessment, these gas types were assigned to the Winters- Domengine Total Petroleum System, but subsequent to the assessment were reclassified as part of the Moreno-Nortonville gas system. Dry thermogenic gas produced from oil fields in the southern San Joaquin Basin (TD-2 gas) most likely originated from the oil-prone source rock of Miocene age. These samples have low wetness values due to migration fractionation or biodegradation. The thermogenic wet gas types (TW-1, TW-2, TW-Mixed) are predominantly associated gas produced from oil fields in the southern and central San Joaquin Basin. Type TW-1 gas most likely originates from source rocks within the Eocene Kreyenhagen Formation or the Eocene Tumey formation of Atwill (1935). Type TW-2 gas most likely originates from the Miocene Monterey Formation and equivalents. TW-Mixed gas is likely a mixture of biogenic and wet thermogenic gas (TW-1 or TW-2) derived from source rocks mentioned above. The thermogenic wet gas types are included in the corresponding Eocene or Miocene total petroleum systems. Type B gas is a dry, nonassociated gas produced from the Pliocene San Joaquin Formation in the central and southern San Joaquin Basin. This gas type most likely originated from Pliocene marine source rocks as a product of methanogenesis, and defines the Neogene Nonassociated Gas Total Petroleum System.

Accretionary history of the Altai-Mongolian terrane: perspectives from granitic zircon U-Pb and Hf-isotope data

NASA Astrophysics Data System (ADS)

Cai, Keda; Sun, Min; Xiao, Wenjiao

2014-05-01

The Central Asian Orogenic Belt (CAOB) consists of many tectonic terranes with distinct origin and complicated evolutionary history. Understanding of individual block is crucial to reconstruct the geodynamic history of the gigantic accetionary collage. This study presents zircon U-Pb ages and Hf isotopes for the granitoid rocks in the Russian Altai mountain range (including Gorny Altai, Altai-Mongolian terrane and CTUS suture zone between them), in order to clarify the timing of granitic magmatism, source nature, continental crustal growth and tectonic evolution. Our dating results suggest that granitic magmatism of the Russian Altai mountain range occurred in three major episodes including 445~429 Ma, 410~360 Ma and ~241 Ma. Most of the zircons within the Paleozoic granitoids present comparable positive ɛHf(t) values and Neoproterozoic crustal model ages, which favor the interpretation that the juvenile crustal materials produced in the early stage of CAOB were probably dominant sources for the Paleozoic magmatism in the region. The inference is also supported by widespread occurrence of short-lived juvenile materials including ophiolites, seamount relics and arc assemblages in the north CAOB. Consequently, the Paleozoic massive granitic rocks maybe not represent continental crustal growth at the time when they were emplaced, but rather record reworking of relatively juvenile Proterozoic crustal rocks although mantle-derived mafic magma was possibly involved to sever as heat engine during granitic magma generation. The Early Triassic granitic intrusion may be product in an intra-plate environment, as the case of same type rocks in the adjacent areas. The positive ɛHf(t) values (1.81~7.47) and corresponding Hf model ages (0.80~1.16 Ga) together with evidence of petrology are consistent with the interpretation that the parental magma of the Triassic granitic intrusion was produced from enriched mantle-derived sources under an usually high temperature condition which is likely due to basaltic magma that underplated the lower crust. Our data combined with evidence of the regional geology enable us to conclude that the Gorny Altai and Altai-Mongolian terranes possibly have similar tectonic natures, but represent two separate accretionary systems before Devonian collision. The accretion and amalgamation processes resulted in the Paleozoic granitoid magmatism and caused the two terranes to merge as a composite tectonic domain at the Siberian continental margin.

Total Petroleum Systems of the Northwest Shelf, Australia: The Dingo-Mungaroo/Barrow and the Locker-Mungaroo/Barrow

USGS Publications Warehouse

Bishop, Michele G.

1999-01-01

The Northwest Shelf Province (U.S.G.S. #3948) of Australia contains two important hydrocarbon source-rock intervals and numerous high quality reservoir intervals. These are grouped into two petroleum systems, Dingo-Mungaroo/Barrow and Locker-Mungaroo/Barrow, where the Triassic Mungaroo Formation and the Early Cretaceous Barrow Group serve as the major reservoir rocks for the Jurassic Dingo Claystone and Triassic Locker Shale source rocks. The primary source rock, Dingo Claystone, was deposited in restricted marine conditions during the Jurassic subsidence of a regional sub-basin trend. The secondary source rock, Locker Shale, was deposited in terrestrially-influenced, continental seaway conditions during the Early Triassic at the beginning of the breakup of Pangea. These systems share potential reservoir rocks of deep-water, proximal and distal deltaic, marginal marine, and alluvial origins, ranging in age from Late Triassic through Cretaceous. Interformational seals and the regional seal, Muderong Shale, along with structural and stratigraphic traps account for the many types of hydrocarbon accumulations in this province. In 1995, the Northwest Shelf produced 42% of the hydrocarbon liquids in Australia, and in 1996 surpassed the Australian Bass Straits production, with 275,000 barrels per day (bpd) average. This region is the major producing province of Australia. Known reserves as of 1995 are estimated at 11.6 billion of barrels of oil equivalent (BBOE)(Klett and others, 1997) . Although exploration has been conducted since 1955, many types of prospects have not been targeted and major reserves continue to be discovered.

Earth's first stable continents did not form by subduction

NASA Astrophysics Data System (ADS)

Johnson, Tim; Brown, Michael; Gardiner, Nicholas; Kirkland, Christopher; Smithies, Hugh

2017-04-01

The geodynamic setting in which Earth's first stable cratonic nuclei formed remains controversial. Most exposed Archaean continental crust comprises rocks of the tonalite-trondhjemite-granodiorite (TTGs) series that were produced from partial melting of low magnesium basaltic source rocks and have 'arc-like' trace element signatures that resemble continental crust produced in modern supra-subduction zone settings. The East Pilbara Terrane, Western Australia, is amongst the oldest fragments of preserved continental crust of Earth. Low magnesium basalts of the Paleoarchaean Coucal Formation, at the base of the Pilbara Supergroup, have trace element compositions consistent with the putative source rocks for TTGs. These basalts may be remnants of the ≥35 km-thick pre-3.5 Ga plateau-like basaltic crust that is predicted to have formed if mantle temperatures were much hotter than today. Using phase equilibria modelling of an average uncontaminated Coucal basalt, we confirm their suitability as TTG source rocks. The results suggest that TTGs formed by 20-30% melting along high geothermal gradients (≥700 °C/GPa), which accord with apparent geotherms recorded by >95% of Archaean rocks worldwide. Moreover, the trace element composition of the Coucal basalts demonstrates that they were derived from an earlier generation of mafic/ultramafic rocks, and that the arc-like signature in Archaean TTGs was inherited through an ancestral source lineage. The protracted multistage process required for production and stabilisation of Earth's first continents, coupled with the high geothermal gradients, are incompatible with modern-style subduction and favour a stagnant lid regime in the early Archaean.

Modeling KBOs Charon, Orcus and Salacia by means of a new equation of state for porous icy bodies

NASA Astrophysics Data System (ADS)

Malamud, U.; Prialnik, D.

2015-10-01

We use a one-dimensional adaptive-grid thermal evolution code to model intermediate sized Kuiper belt objects Charon, Orcus and Salacia and compare their measured bulk densities with those resulting from evolutionary calculations at the end of 4.6 Gyr. Our model assumes an initial homogeneous composition of mixed ice and rock, and follows the multiphase flow of water through the porous rocky medium, consequent differentiation and aqueous chemical alterations in the rock. Heating sources include long-lived radionuclides, serpentinization reactions, release of gravitational potential energy due to compaction, and crystallization of amorphous ice. The density profile is calculated by assuming hydrostatic equilibrium to be maintained through changes in composition, pressure and temperature. To this purpose, we construct an equation of state suitable for porous icy bodies with radii of a few hundred km, based on the best available empirical studies of ice and rock compaction, and on comparisons with rock porosities in Earth analog and Solar System silicates. We show that the observed bulk densities can be reproduced by assuming the same set of initial and physical parameters, including the same rock/ice mass ratio for all three bodies. We conclude that the mass of the object uniquely determines the evolution of porosity, and thus explains the observed differences in bulk density. The final structure of all three objects is differentiated, with an inner rocky core, and outer ice-enriched mantle. The degree of differentiation, too, is determined by the object's mass.

Modeling Kuiper belt objects Charon, Orcus and Salacia by means of a new equation of state for porous icy bodies

NASA Astrophysics Data System (ADS)

Malamud, Uri; Prialnik, Dina

2015-01-01

We use a one-dimensional adaptive-grid thermal evolution code to model Kuiper belt objects Charon, Orcus and Salacia and compare their measured bulk densities with those resulting from evolutionary calculations at the end of 4.6 Gyr. Our model assumes an initial homogeneous composition of mixed ice and rock, and follows the multiphase flow of water through the porous rocky medium, consequent differentiation and aqueous chemical alterations in the rock. Heating sources include long-lived radionuclides, serpentinization reactions, release of gravitational potential energy due to compaction, and crystallization of amorphous ice. The density profile is calculated by assuming hydrostatic equilibrium to be maintained through changes in composition, pressure and temperature. To this purpose, we construct an equation of state suitable for porous icy bodies with radii of a few hundred km, based on the best available empirical studies of ice and rock compaction, and on comparisons with rock porosities in Earth analog and Solar System silicates. We show that the observed bulk densities can be reproduced by assuming the same set of initial and physical parameters, including the same rock/ice mass ratio for all three bodies. We conclude that the mass of the object uniquely determines the evolution of porosity, and thus explains the observed differences in bulk density. The final structure of all three objects is differentiated, with an inner rocky core, and outer ice-enriched mantle. The degree of differentiation, too, is determined by the object's mass.

Uzbek licensing round brings geology, potential into focus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heafford, A.P.; Lichtman, G.S.

1993-08-09

Uzbekistan is a Central Asian Republic that declared independence from the former Soviet Union in 1991. Uzbekistan produces about 18 million bbl/year of oil and 40 bcf/year of gas. It is the third largest gas producer in the Commonwealth of Independent States and imports oil. The Uzbek government and oil and gas industry are offering exploration acreage for foreign participation via competitive bid. Acreage on offer includes fields for development and unproven-underexplored areas. Terms awaiting approval by the Cabinet of Ministers provide financial incentives for rapid development of existing reserves, creation of required infrastructure, and long term investment growth. Licensemore » areas concentrate on acreage where western equipment and technology can bring new reserves economically on line in the near future. National oil company Uzbekneftegaz was created in 1992 to oversee the extraction, transport, and refining of hydrocarbons in Uzbekistan. The paper describes some of the fields and infrastructure in place, the structural geology, stratigraphy, petroleum distribution, source rocks, reservoir rocks, cap rocks, traps, and hydrocarbon composition, which includes oil, gases, and gas condensates.« less

Oil geochemistry of the northern Llanos Basin, Colombia. A model for migration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramon, J.C.; Dzou, L.

1996-12-31

The chemical composition of 23 crude oils and one oil seep from Llanos Basin, Colombia were studied in detail by geochemical methods in order to understand their genetic relationship. A filling history model is proposed to explain the observed composition variations in Llanos Basin oils. Geochemical fingerprinting indicates that there are six families of crude oils. The biomarker compositions have been used to identify characteristics of the source rocks. The Llanos oils contain marine algal- derived {open_quotes}C30 steranes{close_quotes} (i.e., 24-n-propylcholestanes), which are diagnostic for oils generated from marine Cretaceous source rocks. A significant HC-contribution from a Tertiary source is alsomore » indicated by the presence of high concentration of the {open_quotes}flowering plant{close_quotes}-markers oleanane, bicadinanes and oleanoids. Low DBT/Phen, %sulfur values and high diasteranes concentration indicate that the source rock is clay-rich. Biomarker maturity parameters indicate a wide range of source-rock thermal maturities from early to late oil window. Heavy biodegradation has been particularly common among the first oils to fill reservoirs in central Llanos oil fields. The older altered heavy oils were mixed with a second pulse of oil explaining the wide range of oil gravities measured in the central Llanos Basin.« less

Marine petroleum source rocks and reservoir rocks of the Miocene Monterey Formation, California, U.S.A

USGS Publications Warehouse

Isaacs, C.M.

1988-01-01

The Miocene Monterey Formation of California, a biogenous deposit derived mainly from diatom debris, is important both as a petroleum source and petroleum reservoir. As a source, the formation is thought to have generated much of the petroleum in California coastal basins, which are among the most prolific oil provinces in the United States. Oil generated from the Monterey tends to be sulfur-rich and heavy (<20° API), and has chemical characteristics that more closely resemble immature source extracts than "normal" oil. Thermal-maturity indicators in Monterey kerogens appear to behave anomalously, and several lines of evidence indicate that the oil is generated at lower than expected levels of organic metamorphism. As a reservoir, the Monterey is important due both to conventional production from permeable sandstone beds and to fracture production from fine-grained rocks with low matrix permeability. Fractured reservoirs are difficult to identify, and conventional well-log analysis has not proven to be very useful in exploring for and evaluating these reservoirs. Lithologically similar rocks are broadly distributed throughout the Circum-Pacific region, but their petroleum potential is unlikely to be realized without recognition of the distinctive source and reservoir characteristics of diatomaceous strata and their diagenetic equivalents.

Rock flows

NASA Technical Reports Server (NTRS)

Matveyev, S. N.

1986-01-01

Rock flows are defined as forms of spontaneous mass movements, commonly found in mountainous countries, which have been studied very little. The article considers formations known as rock rivers, rock flows, boulder flows, boulder stria, gravel flows, rock seas, and rubble seas. It describes their genesis as seen from their morphological characteristics and presents a classification of these forms. This classification is based on the difference in the genesis of the rubbly matter and characterizes these forms of mass movement according to their source, drainage, and deposit areas.

Campanian-Maastrichtian phosphorites of Iraq

NASA Astrophysics Data System (ADS)

Al-Bassam, K. S.; Al-Dahan, A. A.; Jamil, A. K.

1983-08-01

Bedded marine sedimentary phosphate rocks of Campanian-Maastrichtian age are exposed in the Western Desert of Iraq, forming part of the Tethyan phosphate province. The studied phosphorites are found in three horizons within carbonate rocks; they are mostly pelletal in texture, associated with bone fragments and detrital quartz grains, and cemented by calcite or chert. The mineralogy of the phosphate is dominated by carbonate-fluorapatite. The phosphate and the associated carbonate rocks are relatively enriched with Cr, Ni, Cu, Zn, V, and organic matter. The apatite is enriched with isotopically light carbon and heavy sulfur. The mode of phosphorite formation seems to have included syngenetic deposition of phosphate under reducing, slightly alkaline conditions in shallow marine environment. Decomposition of organic phosphatic remnants appear to have been the local source of phosphorus enrichment. However, the major tectonic and paleogeographic development of the Tethys Sea during Upper Cretaceous have probably played an important role in providing suitable setting for large scale formation of phosphorite.

Measurement and models of bent KAP(001) crystal integrated reflectivity and resolution (invited)

NASA Astrophysics Data System (ADS)

Loisel, G. P.; Wu, M.; Stolte, W.; Kruschwitz, C.; Lake, P.; Dunham, G. S.; Bailey, J. E.; Rochau, G. A.

2016-11-01

The Advanced Light Source beamline-9.3.1 x-rays are used to calibrate the rocking curve of bent potassium acid phthalate (KAP) crystals in the 2.3-4.5 keV photon-energy range. Crystals are bent on a cylindrically convex substrate with a radius of curvature ranging from 2 to 9 in. and also including the flat case to observe the effect of bending on the KAP spectrometric properties. As the bending radius increases, the crystal reflectivity converges to the mosaic crystal response. The X-ray Oriented Programs (xop) multi-lamellar model of bent crystals is used to model the rocking curve of these crystals and the calibration data confirm that a single model is adequate to reproduce simultaneously all measured integrated reflectivities and rocking-curve FWHM for multiple radii of curvature in both 1st and 2nd order of diffraction.

Measurement and models of bent KAP(001) crystal integrated reflectivity and resolution (invited)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Loisel, G. P., E-mail: gploise@sandia.gov; Wu, M.; Lake, P.

2016-11-15

The Advanced Light Source beamline-9.3.1 x-rays are used to calibrate the rocking curve of bent potassium acid phthalate (KAP) crystals in the 2.3-4.5 keV photon-energy range. Crystals are bent on a cylindrically convex substrate with a radius of curvature ranging from 2 to 9 in. and also including the flat case to observe the effect of bending on the KAP spectrometric properties. As the bending radius increases, the crystal reflectivity converges to the mosaic crystal response. The X-ray Oriented Programs (XOP) multi-lamellar model of bent crystals is used to model the rocking curve of these crystals and the calibration datamore » confirm that a single model is adequate to reproduce simultaneously all measured integrated reflectivities and rocking-curve FWHM for multiple radii of curvature in both 1st and 2nd order of diffraction.« less

Fine-grained rutile in the Gulf of Maine: Diagenetic origin, source rocks, and sedimentary environment of deposition

USGS Publications Warehouse

Valentine, P.C.; Commeau, J.A.

1990-01-01

The Gulf of Maine, an embayment of the New England margin, is floored by shallow, glacially scoured basins that are partly filled with late Pleistocene and Holocene silt and clay containing 0.7 to 1.0 wt percent TiO2 chiefly in the form of silt-size rutile. Much of the rutile in the Gulf of Maine mud probably formed diagenetically in poorly cemented Carboniferous and Triassic coarse-grained sedimentary rocks of Nova Scotia and New Brunswick after the dissolution of titanium-rich detrital minerals (ilmenite, ilmenomagnetite). The diagenesis of rutile in coarse sedimentary rocks (especially arkose and graywacke) followed by erosion, segregation, and deposition (and including recycling of fine-grained rutile from shales) can serve as a model for predicting and prospecting for unconsolidated deposits of fine-grained TiO2. -from Authors

40 CFR 60.404 - Test methods and procedures.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock.../ton) of phosphate rock feed. cs=concentration of particulate matter, g/dscm (g/dscf). Qsd=volumetric flow rate of effluent gas, dscm/hr (dscf/hr). P=phosphate rock feed rate, Mg/hr (ton/hr). K=conversion...

40 CFR 60.404 - Test methods and procedures.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock.../ton) of phosphate rock feed. cs = concentration of particulate matter, g/dscm (g/dscf). Qsd = volumetric flow rate of effluent gas, dscm/hr (dscf/hr). P=phosphate rock feed rate, Mg/hr (ton/hr). K...

40 CFR 60.404 - Test methods and procedures.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock.../ton) of phosphate rock feed. cs=concentration of particulate matter, g/dscm (g/dscf). Qsd=volumetric flow rate of effluent gas, dscm/hr (dscf/hr). P=phosphate rock feed rate, Mg/hr (ton/hr). K=conversion...

40 CFR 60.402 - Standard for particulate matter.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock... subpart shall cause to be discharged into the atmosphere: (1) From any phosphate rock dryer any gases which: (i) Contain particulate matter in excess of 0.030 kilogram per megagram of phosphate rock feed (0...

40 CFR 60.402 - Standard for particulate matter.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock... subpart shall cause to be discharged into the atmosphere: (1) From any phosphate rock dryer any gases which: (i) Contain particulate matter in excess of 0.030 kilogram per megagram of phosphate rock feed (0...

40 CFR 60.404 - Test methods and procedures.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock.../ton) of phosphate rock feed. cs=concentration of particulate matter, g/dscm (g/dscf). Qsd=volumetric flow rate of effluent gas, dscm/hr (dscf/hr). P=phosphate rock feed rate, Mg/hr (ton/hr). K=conversion...

40 CFR 60.402 - Standard for particulate matter.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock... subpart shall cause to be discharged into the atmosphere: (1) From any phosphate rock dryer any gases which: (i) Contain particulate matter in excess of 0.030 kilogram per megagram of phosphate rock feed (0...

40 CFR 60.404 - Test methods and procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock.../ton) of phosphate rock feed. cs=concentration of particulate matter, g/dscm (g/dscf). Qsd=volumetric flow rate of effluent gas, dscm/hr (dscf/hr). P=phosphate rock feed rate, Mg/hr (ton/hr). K=conversion...

40 CFR 60.402 - Standard for particulate matter.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock... subpart shall cause to be discharged into the atmosphere: (1) From any phosphate rock dryer any gases which: (i) Contain particulate matter in excess of 0.030 kilogram per megagram of phosphate rock feed (0...

40 CFR 60.402 - Standard for particulate matter.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Phosphate Rock... subpart shall cause to be discharged into the atmosphere: (1) From any phosphate rock dryer any gases which: (i) Contain particulate matter in excess of 0.030 kilogram per megagram of phosphate rock feed (0...

Geologic Map of Baranof Island, southeastern Alaska

USGS Publications Warehouse

Karl, Susan M.; Haeussler, Peter J.; Himmelberg, Glen R.; Zumsteg, Cathy L.; Layer, Paul W.; Friedman, Richard M.; Roeske, Sarah M.; Snee, Lawrence W.

2015-01-01

This map updates the geology of Baranof Island based on fieldwork, petrographic analyses, paleontologic ages, and isotopic ages. These new data provide constraints on depositional and metamorphic ages of lithostratigraphic rock units and the timing of structures that separate them. Kinematic analyses and thermobarometric calculations provide insights on the regional tectonic processes that affected the rocks on Baranof Island. The rocks on Baranof Island are components of a Paleozoic to Early Tertiary oceanic volcanic arc complex, including sedimentary and volcanic rocks that were deposited on and adjacent to the arc complex, deformed, and accreted. The arc complex consists of greenschist to amphibolite facies Paleozoic metavolcanic and metasedimentary rocks overlain by lower-grade Triassic metasedimentary and metavolcanic rocks and intruded by Jurassic calc-alkaline plutons. The Paleozoic rocks correlate well in age and lithology with rocks of the Sicker and Buttle Lake Groups of the Wrangellia terrane on Vancouver Island and differ from rocks of the Skolai Group that constitute basement to type-Wrangellia in the Wrangell Mountains. The Jurassic intrusive rocks are correlative with plutons that intrude the Wrangellia terrane on Vancouver Island but are lacking in the Wrangell Mountains. The rocks accreted beneath the arc complex are referred to as the Baranof Accretionary Complex in this report and are correlated with the Chugach Accretionary Complex of southern and southeastern Alaska and with the Pacific Rim Complex on Vancouver Island. Stratigraphic correlations between upper- and lower-plate rocks on Baranof Island and western Chichagof Island with rocks on Haida Gwaii and Vancouver Island, in addition to correlative ages of intrusive rocks and restorations of the Fairweather-Queen Charlotte, Chatham Strait, and Peril Strait Faults that define the Baranof-Chichagof block, suggest Baranof Island was near Vancouver Island at the time of initiation of arc magmatism in the Early Jurassic. Early Eocene plutons that intruded the accretionary complex outboard of the arc on Baranof Island are attributed to anatectic melting of trench sediments resulting from subduction of a spreading center. Oligocene intrusive rocks on Baranof Island correlate in age and composition with intrusive rocks in the Kano Plutonic Suite on Haida Gwaii, and similar magmatic sources are inferred.

Distribution, richness, quality, and thermal maturity of source rock units on the North Slope of Alaska

USGS Publications Warehouse

Peters, K.E.; Bird, K.J.; Keller, M.A.; Lillis, P.G.; Magoon, L.B.

2003-01-01

Four source rock units on the North Slope were identified, characterized, and mapped to better understand the origin of petroleum in the area: Hue-gamma ray zone (Hue-GRZ), pebble shale unit, Kingak Shale, and Shublik Formation. Rock-Eval pyrolysis, total organic carbon analysis, and well logs were used to map the present-day thickness, organic quantity (TOC), quality (hydrogen index, HI), and thermal maturity (Tmax) of each unit. To map these units, we screened all available geochemical data for wells in the study area and assumed that the top and bottom of the oil window occur at Tmax of ~440° and 470°C, respectively. Based on several assumptions related to carbon mass balance and regional distributions of TOC, the present-day source rock quantity and quality maps were used to determine the extent of fractional conversion of the kerogen to petroleum and to map the original organic richness prior to thermal maturation.

Effects of Host-rock Fracturing on Elastic-deformation Source Models of Volcano Deflation.

PubMed

Holohan, Eoghan P; Sudhaus, Henriette; Walter, Thomas R; Schöpfer, Martin P J; Walsh, John J

2017-09-08

Volcanoes commonly inflate or deflate during episodes of unrest or eruption. Continuum mechanics models that assume linear elastic deformation of the Earth's crust are routinely used to invert the observed ground motions. The source(s) of deformation in such models are generally interpreted in terms of magma bodies or pathways, and thus form a basis for hazard assessment and mitigation. Using discontinuum mechanics models, we show how host-rock fracturing (i.e. non-elastic deformation) during drainage of a magma body can progressively change the shape and depth of an elastic-deformation source. We argue that this effect explains the marked spatio-temporal changes in source model attributes inferred for the March-April 2007 eruption of Piton de la Fournaise volcano, La Reunion. We find that pronounced deflation-related host-rock fracturing can: (1) yield inclined source model geometries for a horizontal magma body; (2) cause significant upward migration of an elastic-deformation source, leading to underestimation of the true magma body depth and potentially to a misinterpretation of ascending magma; and (3) at least partly explain underestimation by elastic-deformation sources of changes in sub-surface magma volume.

Minor and trace element geochemistry of volcanic rocks dredged from the Galapagos spreading center: role of crystal fractionation and mantle heterogeneity.

USGS Publications Warehouse

Clague, D.A.; Frey, F.A.; Thompson, G.; Rindge, S.

1981-01-01

A wide range of rock types (abyssal tholeiite, Fe-Ti-rich basalt, andesite, and rhyodacite) were dredged from near 95oW and 85oW on the Galapagos spreading center. Computer modeling of major element compositions has shown that these rocks could be derived from common parental magmas by successive degrees of fractional crystallization. However, the P2O5/K2O ratio implies distinct mantle source compositions for the two areas. These source regions also have different rare earth element (REE) abundance patterns. The sequence of fractionated lavas differs for the two areas and indicates earlier fractionation of apatite and titanomagnetite in the lavas from 95oW. The mantle source regions for these two areas are interpreted to be depleted in incompatible (and volatile?) elements, although the source region beneath 95oW is less severely depleted in La and K. -Authors

U.S.A. National Surface Rock Density Map - Part 2

NASA Astrophysics Data System (ADS)

Winester, D.

2016-12-01

A map of surface rock densities over the USA has been developed by the NOAA-National Geodetic Survey (NGS) as part of its Gravity for the Redefinition of the American Vertical Datum (GRAV-D) Program. GRAV-D is part of an international effort to generate a North American gravimetric geoid for use as the vertical datum reference surface. As a part of modeling process, it is necessary to eliminate from the observed gravity data the topographic and density effects of all masses above the geoid. However, the long-standing tradition in geoid modeling, which is to use an average rock density (e.g. 2.67 g/cm3), does not adequately represent the variety of lithologies in the USA. The U.S. Geological Survey has assembled a downloadable set of surface geologic formation maps (typically 1:100,000 to 1:500, 000 scale in NAD27) in GIS format. The lithologies were assigned densities typical of their rock type (Part 1) and these variety of densities were then rasterized and averaged over one arc-minute areas. All were then transformed into WGS84 datum. Thin layers of alluvium and some water bodies (interpreted to be less than 40 m thick) have been ignored in deference to underlying rocks. Deep alluvial basins have not been removed, since they represent significant fraction of local mass. The initial assumption for modeling densities will be that the surface rock densities extend down to the geoid. If this results in poor modeling, variable lithologies with depth can be attempted. Initial modeling will use elevations from the SRTM DEM. A map of CONUS densities is presented (denser lithologies are shown brighter). While a visual map at this scale does show detailed features, digital versions are available upon request. Also presented are some pitfalls of using source GIS maps digitized from variable reference sources, including the infamous `state line faults.'

High-temperature, large-volume, lavalike ash-flow tuffs without calderas in southwestern Idaho

USGS Publications Warehouse

Ekren, E.B.; McIntyre, David H.; Bennett, Earl H.

1984-01-01

Rhyolitic rocks were erupted from vents in and adjacent to the Owyhee Mountains and Owyhee Plateau of southwestern Idaho from 16 m.y. ago to about 10 m.y. ago. They were deposited on a highly irregular surface developed on a variety of basement rocks that include granitic rocks of Cretaceous age, quartz latite and rhyodacite tuffs and lava flows of Eocene age, andesitic and basaltic lava flows of Oligocene age, and latitic and basaltic lava flows of early Miocene age. The rhyolitic rocks are principally welded tuffs that, regardless of their source, have one feature in common-namely internal characteristics indicating en-masse, viscous lavalike flowage. The flowage features commonly include considerable thicknesses of flow breccia at the bases of various cooling units. On the basis of the tabular nature of the rhyolitic deposits, their broad areal extents, and the local preservation of pyroclastic textures at the bases, tops, and distal ends of some of the deposits, we have concluded that the rocks were emplaced as ash flows at extremely high temperatures and that they coalesced to liquids before final emplacement and cooling. Temperatures of l090?C and higher are indicated by iron-titanium oxide compositions. Rhyolites that are about 16 m.y. old are preserved mostly in the downdropped eastern and western flanks of the Silver City Range and they are inferred to have been erupted from the Silver City Range. They rarely contain more than about 2 percent phenocrysts that consist of quartz and subequal amounts of plagioclase and alkali feldspar; commonly, they contain biotite, and they are the only rhyolitic rocks in the area to do so. The several rhyolitic units that are 14 m.y. to about 10 m.y. old contain only pyroxene-principally ferriferous and intermediate pigeonites-as mafic constituents. The rhyolites of the Silver City Range comprise many cooling units, none of which can be traced for great distances. Rocks erupted from the Owyhee Plateau include two sequences that were traced over areas having diameters of about 100 km. These two sheets are the herein-named Swisher Mountain Tuff, which is about 13.8 m.y. old, and the Little Jacks Tuff, which is about 10 m.y. old. The Swisher Mountain Tuff was erupted from the Juniper Mountain volcanic center, a gentle dome that is not bounded by arcuate faults indicative of cauldron subsidence. The tuff is 200 m thick over a considerable area in and adjacent to its source. It apparently thins gradually toward its distal edges, and it is inferred to be uniformly distributed around its source at Juniper Mountain. The unit contains vitrophyres at various intervals from base to top, and, although the vitrophyres are, in general, flow layered and commonly flow brecciated, they occasionally contain well-defined pumice clasts. The vitrophyres indicate compound cooling, and, near the distal edges of the sheet, some of them probably represent complete cooling breaks. The Little Jacks Tuff onlaps the Swisher Mountain Tuff in expo sures east of Juniper Mountain, and it is inferred to have been erupted from a source on the part of the Owyhee Plateau that lies just east of the area studied. This inferred source area, like that at Juniper Mountain, is also expressed today as a gentle dome without structural features indicative of cauldron subsidence. The Little Jacks Tuff, in most exposures in the deep canyons of the Plateau, consists of at least four cooling units, and, in places in the eastern part of the studied area near the source area, it possibly comprises as many as six. Although there is no obvious evidence of erosion between the various cooling units, magnetic polarity measurements indicate that there were at least two magnetic reversals during the eruption interval of the Little Jacks Tuff. Like the Swisher Mountain Tuff, the Little Jacks has flattened pumice clasts in a few outcrops-principally at the bases of the various cooling units. The two tuff sequences are calc-a

Diatremes of the Hopi Buttes, Arizona; chemical and statistical analyses

USGS Publications Warehouse

Wenrich, K.J.; Mascarenas, J.F.

1982-01-01

Lacustrine sediments deposited in maar lakes of the Hopi Buttes diatremes are hosts for uranium mineralization of as much as 1500 ppm. The monchiquites and limburgite turfs erupted from the diatremes are distinguished from normal alkalic basalts of the Colorado Plateau by their extreme silica undersaturation and high water, TiO2, and P2O5 contents. Many trace elements are also unusually abundant, including Ag, As, Ba, Be, Ce, Dy, Eu, F, Gd, Hf, La, Nd, Pb, Rb, Se, Sm, Sn, Sr, Ta, Tb, Th, U, V, Zn, and Zr. The lacustrine sediments, which consist predominantly of travertine and clastic rocks, are the hosts for syngenetic and epigenetic uranium mineralization of as much as 1500 ppm uranium. Fission track maps show the uranium to be disseminated within the travertine and clastic rocks, and although microprobe analyses have not, as yet, revealed discrete uranium-bearing phases, the clastic rocks show a correlation of high Fe, Ti, and P with areas of high U. Correlation coefficients show that for the travertines, clastics, and limburgite ruffs, Mo, As, Sr, Co, and V appear to have the most consistent and strongest correlations with uranium. Many elements, including many of the rare-earth elements, that are high in these three rocks are also high in the monchiquites, as compared to the average crustal abundance for the respective rock type. This similar suite of anomalous elements, which includes such immobile elements as the rare earths, suggests that Fluids which deposited the travertines were related to the monchiquitic magma. The similar age of about 5 m.y. for both the lake beds and the monchiquites also appears to support this source for the mineralizing fluids.

Questa baseline and pre-mining ground-water quality investigation. 19. Leaching characteristics of composited materials from mine waste-rock piles and naturally altered areas near Questa, New Mexico

USGS Publications Warehouse

Smith, Kathleen S.; Hageman, Philip L.; Briggs, Paul H.; Sutley, Stephen J.; McCleskey, R. Blaine; Livo, K. Eric; Verplanck, Philip L.; Adams, Monique G.; Gemery-Hill, Pamela A.

2007-01-01

The goal of this study is to compare and contrast the leachability of metals and the acidity from individual mine waste-rock piles and natural erosional scars in the study area near Questa, New Mexico. Surficial multi-increment (composite) samples less than 2 millimeters in diameter from five waste-rock piles, nine erosional-scar areas, a less-altered site, and a tailings slurry-pipe sample were analyzed for bulk chemistry and mineralogy and subjected to two back-to-back leaching procedures. The first leaching procedure, the U.S. Geological Survey Field Leach Test (FLT), is a short-duration leach (5-minute shaking and 10-minute settling) and is intended to leach readily soluble materials. The FLT was immediately followed by an 18-hour, end-over-end rotation leaching procedure. Comparison of results from the back-to-back leaching procedures can provide information about reactions that may take place upon migration of leachates through changing geochemical conditions (for example, pH changes), both within the waste-rock and scar materials and away from the source materials. For the scar leachates, the concentrations of leachable metals varied substantially between the scar areas sampled. The scar leachates have low pH (pH 3.2-4.1). Under these low-pH conditions, cationic metals are solubilized and mobile, but anionic species, such as molybdenum, are less soluble and less mobile. Generally, metal concentrations in the waste-rock leachates did not exceed the upper range of those metal concentrations in the erosional-scar leachates. One exception is molybdenum, which is notably higher in the waste-rock leachates compared with the scar leachates. Most of the waste-rock leachates were at least mildly acidic (pH 3.0-6.2). The pH values in the waste-rock leachates span a large pH range that includes some pH-dependent solubility and metal-attenuation reactions. An increase in pH with leaching time and agitation indicates that there is pH-buffering capacity in some of the waste-rock piles. As pH increased in the waste-pile leachates, concentrations of several metals decreased with increasing time and agitation. Similar pH-dependent reactions may take place upon migration of the leachates in the waste-rock piles. Bulk chemistry, mineralogy, and leachate sulfur-isotope data indicate that the Capulin and Sugar Shack West waste-rock piles are compositionally different from the younger Sugar Shack South, Sugar Shack Middle, and Old Sulphur Gulch piles. The Capulin and Sugar Shack West piles have the lowest-pH leachates (pH 3.0-4.1) of the waste-pile samples, and the source material for the Capulin and Sugar Shack West piles appears to be similar to the source material for the erosional-scar areas. Calcite dissolution, in addition to gypsum dissolution, appears to produce the calcium and sulfate concentrations in leachates from the Sugar Shack South, Sugar Shack Middle, and Old Sulphur Gulch piles.

Geochemical typification of kimberlite and related rocks of the North Anabar region, Yakutia

NASA Astrophysics Data System (ADS)

Kargin, A. V.; Golubeva, Yu. Yu.

2017-11-01

The results of geochemical typification of kimberlites and related rocks (alneites and carbonatites) of the North Anabar region are presented with consideration of the geochemical specification of their source and estimation of their potential for diamonds. The content of representative trace elements indicates the predominant contribution of an asthenospheric component (kimberlites and carbonatites) in their source, with a subordinate contribution of vein metasomatic formations containing Cr-diopside and ilmenite. A significant contribution of water-bearing potassium metasomatic parageneses is not recognized. According to the complex of geochemical data, the studied rocks are not industrially diamondiferous.

Visualizing petroleum systems with a combination of GIS and multimedia technologies: An example from the West Siberia Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walsh, D.B.; Grace, J.D.

1996-12-31

Petroleum system studies provide an ideal application for the combination of Geographic Information System (GIS) and multimedia technologies. GIS technology is used to build and maintain the spatial and tabular data within the study region. Spatial data may comprise the zones of active source rocks and potential reservoir facies. Similarly, tabular data include the attendant source rock parameters (e.g. pyroloysis results, organic carbon content) and field-level exploration and production histories for the basin. Once the spatial and tabular data base has been constructed, GIS technology is useful in finding favorable exploration trends, such as zones of high organic content, maturemore » source rocks in positions adjacent to sealed, high porosity reservoir facies. Multimedia technology provides powerful visualization tools for petroleum system studies. The components of petroleum system development, most importantly generation, migration and trap development typically span periods of tens to hundreds of millions of years. The ability to animate spatial data over time provides an insightful alternative for studying the development of processes which are only captured in {open_quotes}snapshots{close_quotes} by static maps. New multimedia-authoring software provides this temporal dimension. The ability to record this data on CD-ROMs and allow user- interactivity further leverages the combination of spatial data bases, tabular data bases and time-based animations. The example used for this study was the Bazhenov-Neocomian petroleum system of West Siberia.« less

Visualizing petroleum systems with a combination of GIS and multimedia technologies: An example from the West Siberia Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walsh, D.B.; Grace, J.D.

1996-01-01

Petroleum system studies provide an ideal application for the combination of Geographic Information System (GIS) and multimedia technologies. GIS technology is used to build and maintain the spatial and tabular data within the study region. Spatial data may comprise the zones of active source rocks and potential reservoir facies. Similarly, tabular data include the attendant source rock parameters (e.g. pyroloysis results, organic carbon content) and field-level exploration and production histories for the basin. Once the spatial and tabular data base has been constructed, GIS technology is useful in finding favorable exploration trends, such as zones of high organic content, maturemore » source rocks in positions adjacent to sealed, high porosity reservoir facies. Multimedia technology provides powerful visualization tools for petroleum system studies. The components of petroleum system development, most importantly generation, migration and trap development typically span periods of tens to hundreds of millions of years. The ability to animate spatial data over time provides an insightful alternative for studying the development of processes which are only captured in [open quotes]snapshots[close quotes] by static maps. New multimedia-authoring software provides this temporal dimension. The ability to record this data on CD-ROMs and allow user- interactivity further leverages the combination of spatial data bases, tabular data bases and time-based animations. The example used for this study was the Bazhenov-Neocomian petroleum system of West Siberia.« less

Late Jurassic – early Cretaceous inversion of rift structures, and linkage of petroleum system elements across post-rift unconformity, U.S. Chukchi Shelf, arctic Alaska

USGS Publications Warehouse

Houseknecht, David W.; Connors, Christopher D.

2015-01-01

Oil-prone source rocks, reservoir-quality sandstone, migration pathways, and structural closure are linked intimately across the Jurassic unconformity, which reflects inversion. Thus, all these key petroleum systems elements were in place when Triassic source rocks entered the oil generation window during Cretaceous–Cenozoic stratigraphic burial.

Structural evolution and petroleum productivity of the Baltic basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ulmishek, G.F.

The Baltic basin is an oval depression located in the western part of the Russian craton; it occupies the eastern Baltic Sea and adjacent onshore areas. The basin contains more than 5,000 m of sedimentary rocks ranging from latest Proterozoic to Tertiary in age. These rocks consist of four tectonostratigraphic sequences deposited during major tectonic episodes of basin evolution. Principal unconformities separate the sequences. The basin is underlain by a rift probably filled with Upper Proterozoic rocks. Vendian and Lower Cambrian rocks (Baikalian sequence) form two northeast-trending depressions. The principal stage of the basin development was during deposition of amore » thick Middle Cambrian-Lower Devonian (Caledonian) sequence. This stage was terminated by the most intense deformations in the basin history. The Middle Devonian-Carboniferous (Hercynian) and Permian-Tertiary (Kimmerian-Alpine) tectonic and depositional cycles only slightly modified the basin geometry and left intact the main structural framework of underlying rocks. The petroleum productivity of the basin is related to the Caledonian tectonostratigraphic sequence that contains both source rocks and reservoirs. However, maturation of source rocks, migration of oil, and formation of fields took place mostly during deposition of the Hercynian sequence.« less

Families of miocene monterey crude oil, seep, and tarball samples, coastal California

USGS Publications Warehouse

Peters, K.E.; Hostettler, F.D.; Lorenson, T.D.; Rosenbauer, R.J.

2008-01-01

Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs to better assess their origins and distributions in coastal California. These samples were used to construct a chemometric (multivariate statistical) decision tree to classify 288 additional samples. The results identify three tribes of 13C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl and lower calcareous-siliceous members of the Monterey Formation at Naples Beach near Santa Barbara. An attempt to correlate these families to rock extracts from these members in the nearby COST (continental offshore stratigraphic test) (OCS-Cal 78-164) well failed, at least in part because the rocks are thermally immature. Geochemical similarities among the oil tribes and their widespread distribution support the prograding margin model or the banktop-slope-basin model instead of the ridge-and-basin model for the deposition of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher plant input. Tribe 2 contains four oil families with traits intermediate between tribes 1 and 3, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey source rock favored petroleum generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. In a test of the decision tree, 10 tarball samples collected from beaches in Monterey and San Mateo counties in early 2007 were found to originate from natural seeps representing different organofacies of Monterey Formation source rock instead from one anthropogenic pollution event. The seeps apparently became more active because of increased storm activity. Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.

Digital Bedrock Compilation: A Geodatabase Covering Forest Service Lands in California

NASA Astrophysics Data System (ADS)

Elder, D.; de La Fuente, J. A.; Reichert, M.

2010-12-01

This digital database contains bedrock geologic mapping for Forest Service lands within California. This compilation began in 2004 and the first version was completed in 2005. Second publication of this geodatabase was completed in 2010 and filled major gaps in the southern Sierra Nevada and Modoc/Medicine Lake/Warner Mountains areas. This digital map database was compiled from previously published and unpublished geologic mapping, with source mapping and review from California Geological Survey, the U.S. Geological Survey and others. Much of the source data was itself compilation mapping. This geodatabase is huge, containing ~107,000 polygons and ~ 280,000 arcs. Mapping was compiled from more than one thousand individual sources and covers over 41,000,000 acres (~166,000 km2). It was compiled from source maps at various scales - from ~ 1:4,000 to 1:250,000 and represents the best available geologic mapping at largest scale possible. An estimated 70-80% of the source information was digitized from geologic mapping at 1:62,500 scale or better. Forest Service ACT2 Enterprise Team compiled the bedrock mapping and developed a geodatabase to store this information. This geodatabase supports feature classes for polygons (e.g, map units), lines (e.g., contacts, boundaries, faults and structural lines) and points (e.g., orientation data, structural symbology). Lookup tables provide detailed information for feature class items. Lookup/type tables contain legal values and hierarchical groupings for geologic ages and lithologies. Type tables link coded values with descriptions for line and point attributes, such as line type, line location and point type. This digital mapping is at the core of many quantitative analyses and derivative map products. Queries of the database are used to produce maps and to quantify rock types of interest. These include the following: (1) ultramafic rocks - where hazards from naturally occurring asbestos are high, (2) granitic rocks - increased erosion hazards, (3) limestone, chert, sedimentary rocks - paleontological resources (Potential Fossil Yield Classification maps), (4) calcareous rocks (cave resources, water chemistry), and (5) lava flows - lava tubes (more caves). Map unit groupings (e.g., belts, terranes, tectonic & geomorphic provinces) can also be derived from the geodatabase. Digital geologic mapping was used in ground water modeling to predict effects of tunneling through the San Bernardino Mountains. Bedrock mapping is used in models that characterize watershed sediment regimes and quantify anthropogenic influences. When combined with digital geomorphology mapping, this geodatabase helps to assess landslide hazards.

Petrographic and geochemical data for Cenozoic volcanic rocks of the Bodie Hills, California and Nevada

USGS Publications Warehouse

du Bray, Edward A.; John, David A.; Box, Stephen E.; Vikre, Peter G.; Fleck, Robert J.; Cousens, Brian L.

2013-04-23

Petrographic and geochemical data for Cenozoic volcanic rocks of the Bodie Hills, California and Nevada // // This report presents petrographic and geochemical data for samples collected during investigations of Tertiary volcanism in the Bodie Hills of California and Nevada. Igneous rocks in the area are principally 15–6 Ma subduction-related volcanic rocks of the Bodie Hills volcanic field but also include 3.9–0.1 Ma rocks of the bimodal, post-subduction Aurora volcanic field. Limited petrographic results for local basement rocks, including Mesozoic granitoid rocks and their metamorphic host rocks, are also included in the compilation. The petrographic data include visual estimates of phenocryst abundances as well as other diagnostic petrographic criteria. The geochemical data include whole-rock major oxide and trace element data, as well as limited whole-rock isotopic data.

Petrography and geochemistry of clastic rocks within the Inthanon zone, northern Thailand: Implications for Paleo-Tethys subduction and convergence

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Kunii, Miyuki; Hisada, Ken-ichiro; Ueno, Katsumi; Kamata, Yoshihito; Srichan, Weerapan; Charusiri, Punya; Charoentitirat, Thasinee; Watarai, Megumi; Adachi, Yoshiko; Kurihara, Toshiyuki

2012-11-01

The provenance, source rock compositions, and sediment supply system for a convergence zone of the Paleo-Tethys were reconstructed based on the petrography and geochemistry of clastic rocks of the Inthanon Zone, northern Thailand. The clastic rocks are classified into two types based on field and microscopic observations, the modal composition of sandstone, and mineral compositions: (1) lithic sandstone and shale within mélange in a Permo-Triassic accretionary complex; and (2) Carboniferous quartzose sandstone and mudstone within the Sibumasu Block. Geochemical data indicate that the clastic rocks of the mélange were derived from continental island arc and continental margin settings, which correspond to felsic volcanic rocks within the Sukhothai Zone and quartz-rich fragments within the Indochina Block, respectively. The results of a mixing model indicate the source rocks were approximately 35% volcanic rocks of the Sukhothai Zone and 65% craton sandstone and upper continental crust of the Indochina Block. In contrast, Carboniferous quartzose sedimentary rocks within the Sibumasu Block originated from a continental margin, without a contribution from volcanic rocks. In terms of Paleo-Tethys subduction, a continental island arc in the Sukhothai Zone evolved in tandem with Late Permian-Triassic forearc basins and volcanic activity during the Middle-early Late Triassic. The accretionary complex formed contemporaneously with the evolution of continental island arc during the Permo-Triassic, supplied with sediment from the Sukhothai Zone and the Indochina Block.

The potential source of lead in the Permian Kupferschiefer bed of Europe and some selected Paleozoic mineral deposits in the Federal Republic of Germany

USGS Publications Warehouse

Wedepohl, K.H.; Delevaux, M.H.; Doe, B.R.

1978-01-01

New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed. ?? 1978 Springer-Verlag.

The influence of shale depositional fabric on the kinetics of hydrocarbon generation through control of mineral surface contact area on clay catalysis

NASA Astrophysics Data System (ADS)

Rahman, Habibur M.; Kennedy, Martin; Löhr, Stefan; Dewhurst, David N.; Sherwood, Neil; Yang, Shengyu; Horsfield, Brian

2018-01-01

Accurately assessing the temperature and hence the depth and timing of hydrocarbon generation is a critical step in the characterization of a petroleum system. Clay catalysis is a potentially significant modifier of hydrocarbon generation temperature, but experimental studies of clay catalysis show inconsistent or contradictory results. This study tests the hypothesis that source rock fabric itself is an influence on clay mineral catalysis as it controls the extent to which organic matter and clay minerals are physically associated. Two endmember clay-organic fabrics distinguish the source rocks studied: (1) a particulate fabric where organic matter is present as discrete, >5 μm particles and (2) a nanocomposite fabric in which amorphous organic matter is associated with clay mineral surfaces at sub-micron scale. High-resolution electron imaging and bulk geochemical characterisation confirm that samples of the Miocene Monterey Formation (California) are representative of the nanocomposite source rock endmember, whereas samples from the Permian Stuart Range Formation (South Australia) represent the particulate source rock endmember. Kinetic experiments are performed on paired whole rock and kerogen isolate samples from these two formations using open system, non-isothermal pyrolysis at three different heating rates (0.7, 2 and 5 K/min) to determine the effects of the different shale fabrics on hydrocarbon generation kinetics. Extrapolation to a modelled geological heating rate shows a 20 °C reduction in the onset temperature of hydrocarbon generation in Monterey Formation whole rock samples relative to paired kerogen isolates. This result is consistent with the Monterey Formations's nanocomposite fabric where clay catalysis can proceed because reactive clay minerals are intimately associated with organic matter. By contrast, there is no significant difference in the modelled hydrocarbon generation temperature of paired whole rock and kerogen isolates from the Stuart Range Formation. This is consistent with its particulate fabric, where relatively large, discrete organic particles have limited contact with the mineral matrix and the clay minerals are mainly diagenetic and physically segregated within pores. While heating rate may have a control on mineral matrix effects, this result shows that the extent to which organic matter and clay minerals are physically associated could have a significant effect on the timing of hydrocarbon generation, and is a function of the depositional environment and detrital vs diagenetic origin of clay minerals in source rocks.

Dynamics of the Bingham Canyon rock avalanches (Utah, USA) resolved from topographic, seismic, and infrasound data

NASA Astrophysics Data System (ADS)

Moore, Jeffrey R.; Pankow, Kristine L.; Ford, Sean R.; Koper, Keith D.; Hale, J. Mark; Aaron, Jordan; Larsen, Chris F.

2017-03-01

The 2013 Bingham Canyon Mine rock avalanches represent one of the largest cumulative landslide events in recorded U.S. history and provide a unique opportunity to test remote analysis techniques for landslide characterization. Here we combine aerial photogrammetry surveying, topographic reconstruction, numerical runout modeling, and analysis of broadband seismic and infrasound data to extract salient details of the dynamics and evolution of the multiphase landslide event. Our results reveal a cumulative intact rock source volume of 52 Mm3, which mobilized in two main rock avalanche phases separated by 1.5 h. We estimate that the first rock avalanche had 1.5-2 times greater volume than the second. Each failure initiated by sliding along a gently dipping (21°), highly persistent basal fault before transitioning to a rock avalanche and spilling into the inner pit. The trajectory and duration of the two rock avalanches were reconstructed using runout modeling and independent force history inversion of intermediate-period (10-50 s) seismic data. Intermediate- and shorter-period (1-50 s) seismic data were sensitive to intervals of mass redirection and constrained finer details of the individual slide dynamics. Back projecting short-period (0.2-1 s) seismic energy, we located the two rock avalanches within 2 and 4 km of the mine. Further analysis of infrasound and seismic data revealed that the cumulative event included an additional 11 smaller landslides (volumes 104-105 m3) and that a trailing signal following the second rock avalanche may result from an air-coupled Rayleigh wave. Our results demonstrate new and refined techniques for detailed remote characterization of the dynamics and evolution of large landslides.

HYDROCARBON SOURCE ROCK EVALUATION OF MIDDLE PROTEROZOIC SOLOR CHURCH FORMATION, NORTH AMERICAN MID-CONTINENT RIFT SYSTEM, RICE COUNTY, MINNESOTA.

USGS Publications Warehouse

Hatch, J.R.; Morey, G.B.

1985-01-01

Hydrocarbon source rock evaluation of the Middle Proterozoic Solor Church Formation (Keweenawan Supergroup) as sampled in the Lonsdale 65-1 well, Rice County, shows that: the rocks are organic matter lean; the organic matter is thermally post-mature, probably near the transition between the wet gas phase of catagenesis and metagenesis; and the rocks have minimal potential for producing additional hydrocarbons. The observed thermal maturity of the organic matter requires significantly greater burial depths, a higher geothermal gradient, or both. It is likely, that thermal maturation of the organic matter in the Solor Church took place relatively early, and that any hydrocarbons generated during this early phase were probably lost prior to deposition of the overlying formation.

Age and source of terrigenous rocks of the turan group of the bureya terrane of the eastern part of the central Asian foldbelt: Results of geochemical (Sm-Nd) and geochronological (U-Pb LA-ICP-MS) studies

NASA Astrophysics Data System (ADS)

Sorokin, A. A.; Smirnov, Yu. V.; Kotov, A. B.; Kovach, V. P.

2014-06-01

According to Sm-Nd isotopic-geochemical studies, the t Nd(DM) of the terrigenous rocks of the Turan Group of the Bureya terrane is 1.4-1.5 Ga and their sources are Precambrian rocks and (or) younger effusive rocks, the formation of which is related to the reworking of the Late Precambrian continental crust. The U-Pb LA-ICP-MS geochronological studies indicate dominant Vendian-Cambrian (588-483 Ma) and Late Riphean (865-737 Ma) detrital zircons. Our data point to their accumulation at the beginning of the Paleozoic rather than in the Precambrian as is accepted in modern stratigraphic schemes.

Petroleum surface oil seeps from Palaeoproterozoic petrified giant oilfield

NASA Astrophysics Data System (ADS)

Melezhik, V.; Fallick, A.; Filippov, M.; Lepland, A.; Rychanchik, D.; Deines, Yu.; Medvedev, P.; Romashkin, A.; Strauss, H.

2009-04-01

Evidence of petroleum generation and migration has been previously reported from rocks dating as early as 3.25 Ga. Micron-size carbonaceous streaks and bitumen micronodules were found in abundance in Archaean rocks across the Pilbara craton in Australia suggesting pervasive petroleum generation and migration. However, none of the Archaean petroleum deposits has been reported to be preserved in quantity due to destructive effects of deformation and thermal obliteration during metamorphism. During the Palaeoproterozoic, unprecedented accumulation of Corg-rich rocks worldwide, known as the 2.0 Ga Shunga Event, occurred during the early stage of progressive oxidation of terrestrial environments, and in the aftermath of the Lomagundi-Jatuli isotopic event, which based on the magnitude and duration of positive d13C was the greatest perturbation of the global carbon cycle in Earth history. C. 2.0 Ga Zaonezhskaya Formation (ZF) rocks from the Onega Basin in Russian Fennoscandia contain evidence for substantial accumulation and preservation of organic matter (up to 75 wt.-% total organic carbon) with an estimated original petroleum potential comparable to a modern supergiant oilfield. The basin contains a uniquely preserved petrified oilfield including evidence of oil traps and oil migration pathways. Here, we report the discovery of the surface expression of a migration pathway, along which petroleum was flowing from the sub-surface. This surface oil seep, the first occurrence ever reported from the Palaeoproterozoic, appears as originally bitumen clasts redeposited in Palaeoproterozoic lacustrine turbidites of the Kondopozhskaya Formation. The d13Corg of clastic pyrobitumen ranges between -35.4 and -36.0 per mill (n = 14) which is within the range of interbed- and vein-trapped fossil oil (-46 and -24 per mill), suggesting similar source. Biogenic organic matter, whose isotopic composition was modified during thermal maturation, is the likely source for the migrated hydrocarbon. Oil seeps, being a very common attribute of almost every major petroleum-producing province in the world, highlight the scale of oil generation and migration in the Onega Basin. The large d13C variability in interbed-trapped pyrobitumen and in organic matter (OM) of the ZF can be entirely explained neither by isotopic fractionation during petroleum generation nor by metamorphic processes, thus it might reflect a primary feature. The source material could have had a wide range of compositions that could have reacted in various ways to the subsequent maturation and alteration. We tentatively suggest that small-scale pyrobitumen accumulations may reflect the initial isotope heterogeneity of the source. In contrast, the seeps d13C are homogeneous, thus perhaps reflecting a large-scale migration and accumulation of composite oil produced by mixing and homogenisation of various oil sources. However, the low H/C of OM and pyrobitumens suggests that the source rock's various components with apparent diversity of original d13C have been over-matured. Although these values are compatible with being the source of the seeps, robust source-reservoir correlation cannot be made. In the evolutionary context, it is significant that the 2.0 Ga OM-rich rocks and generation of supergiant oilfields occurred in the aftermath of the Lomagundi-Jatuli isotopic event, and during the course of the early stage of oxidation of the terrestrial atmosphere. Whether enhanced biomass or change in the preservation potential caused such unprecedented OM accumulation and large-scale oil generation remains to be investigated.

Medial moraines of glaciers of the Copper River Basin, Alaska: Discrete landslides dominate over other sources

NASA Astrophysics Data System (ADS)

Kargel, J. S.; Fischer, L.; Furfaro, R.; Huggel, C.; Korup, O.; Leonard, G. J.; Uhlmann, M.; Wessels, R. L.; Wolfe, D. F.

2009-12-01

Medial moraines are visually dominant structures of most large valley glaciers in the Copper River Basin (CRB), Alaska. Areally extensive but thin (usually <20 cm) accumulations of debris pose challenges for glacier mapping based on multispectral imagery, as done, for instance, in the GLIMS project. The sources of this material include large discrete landslides from wallrocks and from lateral moraines; diffuse contributions from rock falls and talus creep; rocks delivered via snow and ice avalanches; ingestion of lateral moraines along tributary convergences; and basal erosional debris. Evidence indicates that in CRB glaciers, discrete large avalanches predominate as the major contributors of moraine mass. Subglacial erosional debris is predominantly pulverized to small grain sizes and flushed. Many large, young avalanches exist on CRB glaciers. Evidence from colorimetry indicates that many medial moraines actually are landslides that have been sheared and swept downglacier, thus mimicking the form of other types of medial moraines formed where tributaries coalesce and flow down valley. Landcover classification of ASTER imagery, qualitative observations from air photos, and semiquantitative field-based estimations of rock color types indicate that on Allen Glacier, and other CRB glaciers, landslides are the sources of most medial moraines. On Allen and Root Glacier, for example, we see very few boulders with obvious signs of basal abrasion, whereas nearly all boulders exhibit signs of irregular fracture, for example in landslides. Such landslides have large effects on the thermal and mass balance of CRB glaciers, sometimes opposing or in other cases accentuating the effects of global/regional climate change. Considering the link between landslides and seismicity, and that Magnitude 8-9 earthquakes may occur nearby only about once a century, which is also the characteristic response time of large glaciers to climate shifts, seismicity must be considered along with climate change induced glacier responses in the CRB. Ultimately, climate has the final word, and already this is evident in the glacier record. Glacial flour is probably almost entirely from bed erosion. We will present estimates of the contributions of landslides and subglacially pulverized glacial rock flour to the overall rock mass budget of Allen Glacier. Each of the components of the rock mass budget differs in its probable distribution on the surface and within a typical glacier. We will present some preliminary empirical determinations of the influence of various thicknesses of supraglacial rock debris on the local mass balance of Allen Glacier; the net zero influence is exhibited for debris thicknesses on the order of 1 cm of fine debris or ~50% coverage by cobbles or boulders.

Meta-evaporite in the Carajás mineral province, northern Brazil

NASA Astrophysics Data System (ADS)

Riehl, Walter; Cabral, Alexandre Raphael

2018-05-01

Evidence for connecting evaporite-sourced high-salinity fluids with iron-oxide-copper-gold (IOCG) deposits in the Carajás mineral province has solely been based on boron-isotope compositions of tourmaline. Presence of meta-evaporitic rocks remains unrecognised. Here, we report laminated albitite, tourmalinite and banded albite-phlogopite rock, intercepted by exploratory drilling in a clastic metasedimentary sequence. These rocks represent evaporite precursors. Their location in the copper-gold prospects Açaí and Angélica, in the westernmost part of the Carajás mineral province, indicates that (i) evaporite-sourced fluids were regional and (ii) evaporite-bearing metasedimentary sequences may have been an important source of high-salinity fluids and/or sulfur for the IOCG deposits of the Carajás mineral province.

Sabzevar Ophiolite, NE Iran: Progress from embryonic oceanic lithosphere into magmatic arc constrained by new isotopic and geochemical data

NASA Astrophysics Data System (ADS)

Moghadam, Hadi Shafaii; Corfu, Fernando; Chiaradia, Massimo; Stern, Robert J.; Ghorbani, Ghasem

2014-12-01

The poorly known Sabzevar-Torbat-e-Heydarieh ophiolite belt (STOB) covers a large region in NE Iran, over 400 km E-W and almost 200 km N-S. The Sabzevar mantle sequence includes harzburgite, lherzolite, dunite and chromitite. Spinel Cr# (100Cr/(Cr + Al)) in harzburgites and lherzolites ranges from 44 to 47 and 24 to 26 respectively. The crustal sequence of the Sabzevar ophiolite is dominated by supra-subduction zone (SSZ)-type volcanic as well as plutonic rocks with minor Oceanic Island Basalt (OIB)-like pillowed and massive lavas. The ophiolite is covered by Late Campanian to Early Maastrichtian (~ 75-68 Ma) pelagic sediments and four plagiogranites yield zircon U-Pb ages of 99.9, 98.4, 90.2 and 77.8 Ma, indicating that the sequence evolved over a considerable period of time. Most Sabzevar ophiolitic magmatic rocks are enriched in Large Ion Lithophile Elements (LILEs) and depleted in High Field Strength Elements (HFSEs), similar to SSZ-type magmatic rocks. They (except OIB-type lavas) have higher Th/Yb and plot far away from mantle array and are similar to arc-related rocks. Subordinate OIB-type lavas show Nb-Ta enrichment with high Light Rare Earth Elements (LREE)/Heavy Rare Earth Elements (HREE) ratio, suggesting a plume or subcontinental lithosphere signature in their source. The ophiolitic rocks have positive εNd (t) values (+ 5.4 to + 8.3) and most have high 207Pb/204Pb, indicating a significant contribution of subducted sediments to their mantle source. The geochemical and Sr-Nd-Pb isotope characteristics suggest that the Sabzevar magmatic rocks originated from a Mid-Ocean Ridge Basalt (MORB)-type mantle source metasomatized by fluids or melts from subducted sediments, implying an SSZ environment. We suggest that the Sabzevar ophiolites formed in an embryonic oceanic arc basin between the Lut Block to the south and east and the Binalud mountains (Turan block) to the north, and that this small oceanic arc basin existed from at least mid-Cretaceous times. Intraoceanic subduction began before the Albian (100-113 Ma) and was responsible for generating Sabzevar SSZ-related magmas, ultimately forming a magmatic arc between the Sabzevar ophiolites to the north and the Cheshmeshir and Torbat-e-Heydarieh ophiolites to the south-southeast.

Publications - GMC 72 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS GMC 72 Publication Details Title: Organic carbon, rock-eval pyrolysis, kerogen type, maturation , and vitrinite reflectance geochemical data, and a source rock evaluation for the Exxon OCS-Y-0280-1 publication sales page for more information. Bibliographic Reference Texaco, Inc., 1987, Organic carbon, rock

Glaciation of alpine valleys: The glacier - debris-covered glacier - rock glacier continuum

NASA Astrophysics Data System (ADS)

Anderson, Robert S.; Anderson, Leif S.; Armstrong, William H.; Rossi, Matthew W.; Crump, Sarah E.

2018-06-01

Alpine ice varies from pure ice glaciers to partially debris-covered glaciers to rock glaciers, as defined by the degree of debris cover. In many low- to mid-latitude mountain ranges, the few bare ice glaciers that do exist in the present climate are small and are found where snow is focused by avalanches and where direct exposure to radiation is minimized. Instead, valley heads are more likely to be populated by rock glaciers, which can number in the hundreds. These rock-cloaked glaciers represent some of the most identifiable components of the cryosphere today in low- to mid-latitude settings, and the over-steepened snouts pose an often overlooked hazard to travel in alpine terrain. Geomorphically, rock glaciers serve as conveyor belts atop which rock is pulled away from the base of cliffs. In this work, we show how rock glaciers can be treated as an end-member case that is captured in numerical models of glaciers that include ice dynamics, debris dynamics, and the feedbacks between them. Specifically, we focus on the transition from debris-covered glaciers, where the modern equilibrium line altitude (ELA) intersects the topography, to rock glaciers, where the modern ELA lies above the topography. On debris-covered glaciers (i.e., glaciers with a partial rock mantle), rock delivered to the glacier from its headwall, or from sidewall debris swept into the glacier at tributary junctions, travels englacially to emerge below the ELA. There it accumulates on the surface and damps the rate of melt of underlying ice. This allows the termini of debris-covered glaciers to extend beyond debris-free counterparts, thereby decreasing the ratio of accumulation area to total area of the glacier (AAR). In contrast, rock glaciers (i.e., glaciers with a full rock mantle) occur where and when the environmental ELA rises above the topography. They require avalanches and rockfall from steep headwalls. The occurrence of rock glaciers reflects this dependence on avalanche sources because they are most common on lee sides of ridges and peaks where wind-blown snow enhances the strength of the avalanche source. To maintain positive mass balance, the avalanche cone developed in the winter must be sufficiently thick not to melt entirely in the summer, thus providing an ice accumulation area for the rock glacier. In the absence of rockfall, this would support a short cirque glacier. The presence of debris, however, facilitates the development of rock glaciers with lengths of hundreds of meters, thicknesses of tens of meters, and speeds of meters per year that are well described by numerical models. Numerical models are used to explore the alpine glacier response to its climate history. In warming climates, a debris-covered glacier can transform into a much shorter rock glacier, leaving in its wake a thinning ice-cored moraine. Rock glaciers will persist in landscapes well beyond debris-free counterparts because they have much longer response times to climate change. The headwaters of alpine basins with steep headwalls will therefore oscillate between glacier and rock glacier occupation over glacial-interglacial cycles, maintaining a means by which rock from the headwall can be conveyed away. This enhances the asymmetry of alpine ridgelines, with downwind valleys biting deeply into the range crests, as originally noted by G.K. Gilbert.

Data acquisition and processing system and method for investigating sub-surface features of a rock formation

DOEpatents

Vu, Cung Khac; Nihei, Kurt; Johnson, Paul A; Guyer, Robert; Ten Cate, James A; Le Bas, Pierre-Yves; Larmat, Carene S

2015-01-27

A system and a method includes generating a first signal at a first frequency; and a second signal at a second frequency. Respective sources are positioned within the borehole and controllable such that the signals intersect in an intersection volume outside the borehole. A receiver detects a difference signal returning to the borehole generated by a non-linear mixing process within the intersection volume, and records the detected signal and stores the detected signal in a storage device and records measurement parameters including a position of the first acoustic source, a position of the second acoustic source, a position of the receiver, elevation angle and azimuth angle of the first acoustic signal and elevation angle and azimuth angle of the second acoustic signal.

Fractal Nature of Porosity in Volcanic Tight Reservoirs of the Santanghu Basin and its Relationship to Pore Formation Processes

NASA Astrophysics Data System (ADS)

Wang, Weiming; Wang, Zhixuan; Chen, Xuan; Long, Fei; Lu, Shuangfang; Liu, Guohong; Tian, Weichao; Su, Yue

In this paper, in a case study of Santanghu Basin in China, the morphological characteristics and size distribution of nanoscale pores in the volcanic rocks of the Haerjiawu Formation were investigated using the results of low temperature nitrogen adsorption experiments. This research showed that within the target layer, a large number of nanoscale, eroded pores showed an “ink bottle” morphology with narrow pore mouths and wide bodies. The fractal dimension of pores increases gradually with increasing depth. Moreover, as fractal dimension increases, BET-specific surface area gradually increases, average pore diameter decreases and total pore volume gradually increases. The deeper burial of the Haerjiawu volcanic rocks in the Santanghu Basin leads to more intense erosion by organic acids derived from the basin’s source rocks. Furthermore, the internal surface roughness of these corrosion pores results in poor connectivity. As stated above, the corrosion process is directly related to the organic acids generated by the source rock of the interbedded volcanic rocks. The deeper the reservoir, the more the organic acids being released from the source rock. However, due to the fact that the Haerjiawu volcanic rocks are tight reservoirs and have complicated pore-throat systems, while organic acids dissolve unstable minerals such as feldspars which improve the effective reservoir space; the dissolution of feldspars results in the formation of new minerals, which cannot be expelled from the tight reservoirs. They are instead precipitated in the fine pore throats, thereby reducing pore connectivity, while enhancing reservoir micro-preservation conditions.

Thermal maturity patterns (conodont color alteration index and vitrinite reflectance) in Upper Ordovician and Devonian rocks of the Appalachian basin: a major revision of USGS Map I-917-E using new subsurface collections: Chapter F.1 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Repetski, John E.; Ryder, Robert T.; Weary, David J.; Harris, Anita G.; Trippi, Michael H.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

The conodont color alteration index (CAI) introduced by Epstein and others (1977) and Harris and others (1978) is an important criterion for estimating the thermal maturity of Ordovician to Mississippian rocks in the Appalachian basin. Consequently, the CAI isograd maps of Harris and others (1978) are commonly used by geologists to characterize the thermal and burial history of the Appalachian basin and to better understand the origin and distribution of oil and gas resources in the basin. The main objectives of this report are to present revised CAI isograd maps for Ordovician and Devonian rocks in the Appalachian basin and to interpret the geologic and petroleum resource implications of these maps. The CAI isograd maps presented herein complement, and in some areas replace, the CAI-based isograd maps of Harris and others (1978) for the Appalachian basin. The CAI data presented in this report were derived almost entirely from subsurface samples, whereas the CAI data used by Harris and others (1978) were derived almost entirely from outcrop samples. Because of the different sampling methods, there is little geographic overlap of the two data sets. The new data set is mostly from the Allegheny Plateau structural province and most of the data set of Harris and others (1978) is from the Valley and Ridge structural province, east of the Allegheny structural front (fig. 1). Vitrinite reflectance, based on dispersed vitrinite in Devonian black shale, is another important parameter for estimating the thermal maturity in pre-Pennsylvanian-age rocks of the Appalachian basin (Streib, 1981; Cole and others, 1987; Gerlach and Cercone, 1993; Rimmer and others, 1993; Curtis and Faure, 1997). This chapter also presents a revised percent vitrinite reflectance (%R0) isograd map based on dispersed vitrinite recovered from selected Devonian black shales. The Devonian black shales used for the vitrinite studies reported herein also were analyzed by RockEval pyrolysis and total organic carbon (TOC) content in weight percent. Although the RockEval and TOC data are included in this chapter (table 1), they are not shown on the maps. The revised CAI isograd and percent vitrinite reflectance isograd maps cover all or parts of Kentucky, New York, Ohio, Pennsylvania, Virginia, and West Virginia (fig. 1), and the following three stratigraphic intervals: Upper Ordovician carbonate rocks, Lower and Middle Devonian carbonate rocks, and Middle and Upper Devonian black shales. These stratigraphic intervals were chosen for the following reasons: (1) they represent target reservoirs for much of the oil and gas exploration in the Appalachian basin; (2) they are stratigraphically near probable source rocks for most of the oil and gas; (3) they include geologic formations that are nearly continuous across the basin; (4) they contain abundant carbonate grainstone-packstone intervals, which give a reasonable to good probability of recovery of conodont elements from small samples of drill cuttings; and (5) the Middle and Upper Devonian black shale contains large amounts of organic matter for RockEval, TOC, and dispersed vitrinite analyses. Thermal maturity patterns of the Upper Ordovician Trenton Limestone are of particular interest here, because they closely approximate the thermal maturity patterns in the overlying Upper Ordovician Utica Shale, which is the probable source rock for oil and gas in the Upper Cambrian Rose Run Sandstone (sandstone), Upper Cambrian and Lower Ordovician Knox Group (Dolomite), Lower and Middle Ordovician Beekmantown Group (dolomite or Dolomite), Upper Ordovician Trenton and Black River Limestones, and Lower Silurian Clinton/Medina sandstone (Cole and others, 1987; Jenden and others, 1993; Laughrey and Baldassare, 1998; Ryder and others, 1998; Ryder and Zagorski, 2003). The thermal maturity patterns of the Lower Devonian Helderberg Limestone (Group), Middle Devonian Onondaga Limestone, and Middle Devonian Marcellus Shale-Upper Devonian Rhine street Shale Member-Upper Devonian Ohio Shale are of interest, because they closely approximate the thermal maturity patterns in the Marcellus Shale, Upper Devonian Rhinestreet Shale Member, and Upper Devonian Huron Member of the Ohio Shale, which are the most important source rocks for oil and gas in the Appalachian basin (de Witt and Milici, 1989; Klemme and Ulmishek, 1991). The Marcellus, Rhinestreet, and Huron units are black-shale source rocks for oil and (or) gas in the Lower Devonian Oriskany Sandstone, the Upper Devonian sandstones, the Middle and Upper Devonian black shales, and the Upper Devonian-Lower Mississippian(?) Berea Sandstone (Patchen and others, 1992; Roen and Kepferle, 1993; Laughrey and Baldassare, 1998).

Ages and petrogenesis of Jurassic and Cretaceous intrusive rocks in the Matsu Islands: Implications for lower crust modification beneath southeastern China

NASA Astrophysics Data System (ADS)

Chen, Jing-Yuan; Yang, Jin-Hui; Ji, Wei-Qiang

2017-12-01

Major and trace element, whole-rock Sr-, Nd- and Hf-isotope, zircon U-Pb age and Hf-O isotope data are reported for the intrusive rocks from the Matsu Islands in the coastal area of southeastern (SE) China, in order to study the ages, sources and petrogenesis of these rocks and evolution of the lower crust. The rocks include gneissic granite, massive granite, brecciated granite and diabase. Secondary ion mass spectrometer (SIMS) zircon U-Pb dating reveals that the rocks in the Matsu Islands were emplaced at ∼160 Ma, ∼130 Ma and ∼94 Ma. The Jurassic granites (∼160 Ma) have high SiO2 (74.1-74.5 wt%) and K2O + Na2O (8.32-8.33 wt%) contents and high Rb/Sr ratios of 0.6-1.2 and (La/Yb)CN ratios of 12.6-19.4. Their relatively high initial 87Sr/86Sr ratios (0.7074-0.7101), variable and negative εNd(t) values (-9.2 to -5.4), and variable zircon εHf(t) (-17.0 to +5.2) and δ18O (4.7-8.1‰) values indicate they were mainly derived from an ancient lower crustal source, but with involvement of high εHf(t) and low δ18O materials. The Early Cretaceous diabase (∼130 Ma) has SiO2 content of 56.5 wt%, relatively high MgO concentration, low initial 87Sr/86Sr ratio and negative εNd(t) value, similar to geochemical features of other Cretaceous mafic rocks in the coastal area of SE China. Zircons from the diabase have high εHf(t) values (-5.5 to +0.2) and relatively low δ18O values of 4.2-5.0‰. These characteristics indicate that the parental magma of the diabase was generated by partial melting of enriched lithospheric mantle, which have been metasomatised by altered oceanic crust-derived low-δ18O fluids. For the Cretaceous granitoids (∼130 Ma and 94 Ma), they have relatively low SiO2 (68.0-71.3 wt%) and K2O + Na2O (5.30-7.55 wt%) contents and low Rb/Sr ratios and (La/Yb)CN ratios of 5.8-7.1. They have low initial 87Sr/86Sr ratios (0.7071-0.7082), homogeneous εNd(t) (-4.3 to -4.5) and relatively high zircon εHf(t) values (-3.7 to +1.2) and low δ18O values (4.6-5.9‰). Their isotopic compositions are similar to those of the diabases in this study as well as other Cretaceous mafic rocks in the coastal area of SE China, suggesting that the sources of the Cretaceous granitoids might be the newly formed lower crust related to the underplated mafic rocks. Whole-rock geochemical, Sr-Nd and zircon Hf-O isotopic compositions indicate that the Jurassic granitoids are most likely generated by partial melting of relatively ancient basement rocks, whereas the Cretaceous granitoids were generated by partial melting of relatively young lower crustal rocks with addition of mantle-derived magma. This distinction implies that the pre-existing ancient lower crust beneath the coastal area of SE China has been modified by large-scale mafic magma underplating. Therefore, underplating of mantle-derived mafic magma would result in modification of the pre-existing ancient lower crust and formation of the relatively juvenile lower crust.

A CO2-Silica Geothermometer for Low Temperature Geothermal Resource Assessment, with Application to Resources in the Safford Basin, Arizona

DOE Office of Scientific and Technical Information (OSTI.GOV)

Witcher, James C.; Stone, Claudia

1983-11-01

Geothermics is the study of the earth's heat energy, it's affect on subsurface temperature distribution, it's physical and chemical sources, and it's role in dynamic geologic processes. The term, geothermometry, is applied to the determination of equilibrium temperatures of natural chemical systems, including rock, mineral, and liquid phases. An assemblage of minerals or a chemical system whose phase composition is a function of temperature and pressure can be used as a geothermometer. Thus a geothermometer is useful to determine the formation temperature of rock or the last equilibrium temperature of a flowing aqueous solution such as ground water and hydrothermalmore » fluids.« less

Geophysical well-log analysis of fractured crystalline rocks at East Bull Lake, Ontario, Canada

USGS Publications Warehouse

Paillet, Frederick L.; Hess, A.E.

1986-01-01

Various conventional geophysical borehole measurements were made in conjunction with measurements using a recently designed, low-frequency, acoustic-waveform probe and slow velocity flowmeter for characterization of a fractured mafic intrusion in southern Ontario, Canada. Conventional geophysical measurements included temperature, caliper, gamma, acoustic, single-point resistance, and acoustic televiewer logs. Hole stability problems prevented the use of neutron and gamma-gamma logs, because these logs require that a radioactive source be lowered into the borehole. Measurements were made in three boreholes as much as 850 m deep and penetrating a few tens of meters into granitic basement. All rocks within the mafic intrusion were characterized by minimal gamma radiation and acoustic velocities of about 6.9 km/sec. The uniformity of the acoustic velocities and the character of acoustic-waveform logs made with a conventional high-frequency logging source correlated with the density of fractures evident on televiewer logs. Sample intervals of high-frequency waveform logs were transformed into interpretations of effective fracture opening using a recent model for acoustic attenuation in fractured rocks. The new low-frequency sparker source did not perform as expected at depths below 250 m because of previously unsuspected problems with source firing under large hydrostatic heads. A new heat-pulse, slow velocity flowmeter was used to delineate in detail the flow regime indicated in a general way by temperature logs. The flowmeter measurements indicated that water was entering 2 of the boreholes at numerous fractures above a depth of 200 m, with flow in at least 2 of the boreholes exiting through large isolated fractures below a depth of 400 m. (Author 's abstract)

3D thermal history and maturity modelling of the Levant Basin and Margin

NASA Astrophysics Data System (ADS)

Daher, Samer Bou; Ducros, Mathieu; Michel, Pauline; Nader, Fadi H.; Littke, Ralf

2015-04-01

The gas discoveries recorded in the Levant Basin in the last decade have redirected the industrial and academic communities' interest to this frontier basin and its surroundings. The reported gas in Miocene reservoirs has been assumed to be derived from biogenic sources, although little data has been published so far. The thickness of the sedimentary column and the presence of direct hydrocarbon indicators (DHI) observed in the seismic data suggest the presence of promising prospective thermogenic petroleum systems in deeper intervals in the Levant Basin and along its Margin. In this study we present a large scale 3D thermal history and maturity model of the Levant Basin and Margin, integrating all available calibration data, source rock information collected from onshore Lebanon, and published data. In the first part we will present the main input and assumptions that were made in terms of thicknesses, lithologies, and boundary conditions. In the second part we will discuss the analysed source rocks, their petroleum generation potential and their kinetics. In the third part we will present modelling results including depth maps for key isotherms in addition to transformation ratio and vitrinite reflectance maps for proven and speculative source rocks at different time steps. This will provide a comprehensive assessment of the potential thermogenic petroleum systems in the study area, and allow us to illustrate and discuss the differences between the basinal, marginal, and onshore part of the study area as well as the potential of the northern vis a vis the southern offshore Levant Basin. This model will also allow us to analyse the sensitivity of the system to the various poorly constrained parameters in frontier basins (e.g. crustal thickness, rifting phases, lithologies) and thus identify the most critical data to be collected for future exploration and de-risking strategies.

Eocene-Miocene igneous activity in Provence (SE France): 40Ar/39Ar data, geochemical-petrological constraints and geodynamic implications

NASA Astrophysics Data System (ADS)

Lustrino, Michele; Fedele, Lorenzo; Agostini, Samuele; Di Vincenzo, Gianfranco; Morra, Vincenzo

2017-09-01

Provence (SE France) was affected by two main phases of sporadic igneous activity during the Cenozoic. New 40Ar/39Ar laser step-heating data constrain the beginning of the oldest phase to late Eocene (40.82 ± 0.73 Ma), with activity present until early Miocene ( 20 Ma). The products are mainly andesites, microdiorites, dacites and basaltic andesites mostly emplaced in the Agay-Estérel area. Major- and trace-element constraints, together with Srsbnd Ndsbnd Pb isotopic ratios suggest derivation from a sub-continental lithosphere mantle source variably modified by subduction-related metasomatic processes. The compositions of these rocks overlap those of nearly coeval (emplaced 38-15 Ma) late Eocene-middle Miocene magmatism of Sardinia. The genesis of dacitic rocks cannot be accounted for by simple fractional crystallization alone, and may require interaction of evolved melts with lower crustal lithologies. The youngest phase of igneous activity comprises basaltic volcanic rocks with mildly sodic alkaline affinity emplaced in the Toulon area 10 Myr after the end of the previous subduction-related phase. These rocks show geochemical and isotopic characteristics akin to magmas emplaced in intraplate tectonic settings, indicating a sub-lithospheric HiMu + EM-II mantle source for the magmas, melting approximately in the spinel/garnet-lherzolite transition zone. New 40Ar/39Ar laser step-heating ages place the beginning of the volcanic activity in the late Miocene-Pliocene (5.57 ± 0.09 Ma). The emplacement of "anorogenic" igneous rocks a few Myr after rocks of orogenic character is a common feature in the Cenozoic districts of the Central-Western Mediterranean area. The origin of such "anorogenic" rocks can be explained with the activation of different mantle sources not directly modified by subduction-related metasomatic processes, possibly located in the sub-lithospheric mantle, and thus unrelated to the shallower lithospheric mantle source of the "orogenic" magmatism.

Three-dimensional distribution of igneous rocks near the Pebble porphyry Cu-Au-Mo deposit in southwestern Alaska: constraints from regional-scale aeromagnetic data

USGS Publications Warehouse

Anderson, Eric D.; Zhou, Wei; Li, Yaoguo; Hitzman, Murray W.; Monecke, Thomas; Lang, James R.; Kelley, Karen D.

2014-01-01

Aeromagnetic data helped us to understand the 3D distribution of plutonic rocks near the Pebble porphyry copper deposit in southwestern Alaska, USA. Magnetic susceptibility measurements showed that rocks in the Pebble district are more magnetic than rocks of comparable compositions in the Pike Creek–Stuyahok Hills volcano-plutonic complex. The reduced-to-pole transformation of the aeromagnetic data demonstrated that the older rocks in the Pebble district produce strong magnetic anomaly highs. The tilt derivative transformation highlighted northeast-trending lineaments attributed to Tertiary volcanic rocks. Multiscale edge detection delineated near-surface magnetic sources that are mostly outward dipping and coalesce at depth in the Pebble district. The total horizontal gradient of the 10-km upward-continued magnetic data showed an oval, deep magnetic contact along which porphyry deposits occur. Forward and inverse magnetic modeling showed that the magnetic rocks in the Pebble district extend to depths greater than 9 km. Magnetic inversion was constrained by a near-surface, 3D geologic model that is attributed with measured magnetic susceptibilities from various rock types in the region. The inversion results indicated that several near-surface magnetic sources with moderate susceptibilities converge with depth into magnetic bodies with higher susceptibilities. This deep magnetic source appeared to rise toward the surface in several areas. An isosurface value of 0.02 SI was used to depict the magnetic contact between outcropping granodiorite and nonmagnetic sedimentary host rocks. The contact was shown to be outward dipping. At depths around 5 km, nearly the entire model exceeded the isosurface value indicating the limits of nonmagnetic host material. The inversion results showed the presence of a relatively deep, northeast-trending magnetic low that parallels lineaments mapped by the tilt derivative. This deep low represents a strand of the Lake Clark fault.

National Assessment of Oil and Gas Project: Petroleum systems and assessment of undiscovered oil and gas in the Denver Basin Province, Colorado, Kansas, Nebraska, South Dakota, and Wyoming - USGS Province 39

USGS Publications Warehouse

Higley, Debra K.

2007-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas resources of the Denver Basin Province (USGS Province 39), Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Petroleum is produced in the province from sandstone, shale, and limestone reservoirs that range from Pennsylvanian to Upper Cretaceous in age. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define seven total petroleum systems and twelve assessment units. Nine of these assessment units were quantitatively assessed for undiscovered oil and gas resources. Gas was not assessed for two coal bed methane assessment units due to lack of information and limited potential; oil resources were not assessed for the Fractured Pierre Shale Assessment Unit due to its mature development status.

Natural Offshore Oil Seepage and Related Tarball Accumulation on the California Coastline - Santa Barbara Channel and the Southern Santa Maria Basin: Source Identification and Inventory

USGS Publications Warehouse

Lorenson, T.D.; Hostettler, Frances D.; Rosenbauer, Robert J.; Peters, Kenneth E.; Dougherty, Jennifer A.; Kvenvolden, Keith A.; Gutmacher, Christina E.; Wong, Florence L.; Normark, William R.

2009-01-01

Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The seafloor was mapped by sidescan sonar, and numerous lines of high -resolution seismic surveys were conducted over areas of interest. Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. These samples were used to construct a chemometric fingerprint (multivariate statistics) decision tree to classify 288 additional samples, including tarballs of unknown origin collected from Monterey and San Mateo County beaches after a storm in early 2007. A subset of 9 of 23 active offshore platform oils and one inactive platform oil representing a few oil reservoirs from the western Santa Barbara Channel were used in this analysis, and thus this model is not comprehensive and the findings are not conclusive. The platform oils included in this study are from west to east: Irene, Hildago, Harvest, Hermosa, Heritage, Harmony, Hondo, Holly, Platform A, and Hilda (now removed). The results identify three 'tribes' of 13C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl, and lower calcareous-siliceous members of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher-plant input. Tribe 2 contains four oil families with intermediate traits, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher-plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey Formation source rock favored generation from all thre

Dynamics of the Yellowstone hydrothermal system

USGS Publications Warehouse

Hurwitz, Shaul; Lowenstern, Jacob B.

2014-01-01

The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

Origin and evolution of the alkalic ultramafic rocks in the Coyote Peak diatreme, Humboldt County, California

USGS Publications Warehouse

Morgan, J.W.; Czamanske, G.K.; Gregory, Wandless A.

1985-01-01

Instrumental-neutron-activation analyses are reported for two uncontaminated rocks, a phlogopite-rich clot, and two contaminated rocks from the Coyote Peak diatreme, northwestern California. These data, combined with Nd, Sr, and Pb isotopic evidence, have been modeled to a multi-stage evolution for the uncontaminated rocks. Fertile mantle material (refractory elements 2.5?? chondritic abundances; Rb/Sr = 0.029 by weight) was depleted about 900 m.y. ago by congruent melting and removal of ~4% basaltic liquid; this depleted residue provided the source rock from which the Coyote Peak magma was ultimately derived. About 66 m.y. ago, the depleted mantle residue was incongruently melted in the presence of H2O and CO2 at a total pressure > 26 kb to yield ~0.5% of a Si-poor, Ca-rich melt. This melt then metasomatized depleted garnet-free harzburgite in the upper mantle at about 26 kb to produce a rock similar to phlogopite-bearing wehrlite. About 29 m.y. ago, this rock was subjected to an increase in pressure to >26 kb and incongruently melted to give ~0.5% of a second-stage melt resembling olivine melilitite in composition. Enroute to the surface, about 28% olivine and 2% titanomagnetite were lost from the highly fluid melt. Coarse-grained phlogopite-rich clots in the uncontaminated rocks apparently crystallized from a latestage liquid derived from the uncontaminated melt. Contaminated rocks appear to be the result of partial assimilation of, and dilution by, ~14% Franciscan graywacke country rock. The diatreme was emplaced near a converging plate margin where young hot oceanic mantle and crust of the Juan de Fuca plate was probably subducting obliquely beneath a thin lip of the North American plate. The unusual chemistry of the rocks may be the result of this complex tectonic setting which could also have included local strike-slip and extensional environments within the two plates pierced by the diatreme. ?? 1985.

9. Photographic copy of photograph. (Source: National Archives Photo Collection, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. Photographic copy of photograph. (Source: National Archives Photo Collection, Denver, NN-366-114, Box 12, Photo 4464) Rebuilt Rock Creek Diversion Dam. Intake structure for canal is at left with suliceway and overflow section to right. April 24, 1950. - Bitter Root Irrigation Project, Rock Creek Diversion Dam, One mile east of Como Dam, west of U.S. Highway 93, Darby, Ravalli County, MT

Strontium and neodymium isotopic evidence for the heterogeneous nature and development of the mantle beneath Afar (Ethiopia)

NASA Astrophysics Data System (ADS)

Betton, P. J.; Civetta, L.

1984-11-01

Neodymium isotope and REE analyses of recent volcanic rocks and spinel lherzolite nodules from the Afar area are reported. The 143Nd/ 144Nd ratios of the volcanic rocks range from 0.51286 to 0.51304, similar to the range recorded from Iceland. However, the 87Sr/ 86Sr ratios display a distinctly greater range (0.70328-0.70410) than those reported from the primitive rocks of Iceland. Whole rock samples and mineral separates from the spinel lherzolite nodules exhibit uniform 143Nd/ 144Nd ratios (ca. 0.5129) but varied 87Sr/ 86Sr ratios in the range 0.70427-0.70528. The Sr sbnd Nd isotope variations suggest that the volcanic rocks may have been produced by mixing between two reservoirs with distinct isotopic compositions. Two possible magma reservoirs in this area are the source which produced the "MORB-type" volcanics in the Red Sea and Gulf of Aden and the anomalous source represented by the nodule suite. The isotopic composition of the volcanics is compatible with mixing between these two reservoirs. It is shown that the anomalous source with a high 87Sr/ 86Sr ratio cannot have been produced by simple processes of partial melting and mixing within normal mantle. Instead the high 87Sr/ 86Sr is equated with a fluid phase. A primitive cognate fluid, subducted seawater or altered oceanic lithosphere may have been responsible for the generation of the source with a high 87Sr/ 86Sr ratio.

Geochemical Analysis of Parasequences within the Productive Middle Member of the Eagle Ford Formation at Lozier Canyon near Del Rio, Texas

NASA Astrophysics Data System (ADS)

Shane, Timothy E.

The middle member of the Eagle Ford formation is a heterogeneous, carbonate-shale unit that is a focus of unconventional oil and gas exploration in southern Texas. Exploration results have been mixed because of the apparent heterogeneity of the member. In this study, the extent of heterogeneities in the Eagle Ford on the "bedding-scale" were examined by evaluating changes in organic and inorganic geochemistry. Samples were collected vertically in outcrop covering four non-consecutive parasequences. These samples were analyzed using a Rock Eval 6 Analyzer(TM) to determine source rock generative potential and a Niton(TM) XRF to evaluate inorganic geochemistry to identify changes in paleoredox conditions, paleoproductivity, and clastic influx. From pyrolysis data, it is determined that Parasequence 1 potentially displays an increase in source rock potential, Parasequence 2 potentially displays a constant source rock potential, and Parasequences 3 and 4 potentially display overall decreases in source rock potential during deposition. From the inferred paleoredox conditions, paleoproductivity, and clastic influx, it is determined that Parasequence 1 experienced a potential increase in oxygen abundance, Parasequence 2 experienced a potential decrease in oxygen abundance, and Parasequences 3 and 4 potentially experienced increases in oxygen abundance during deposition. It is concluded that geochemical heterogeneities do exist on a bedding scale within the parasequences of the middle member of the Eagle Ford. Additional comprehensive sampling and analysis is recommended in the future in order to tie these data to subsurface data for economic application.

Reducing Disaster Vulnerability Through Science and Technology

DTIC Science & Technology

2003-07-01

engineering design. Source: “Massive Alaska Earthquake Rocks the Mainland,” Volcano Watch, Hawaiian Volcano Observatory, November 14, 2002, http... volcanoes , and landslides ■ Disease epidemics ■ Technological disasters, including critical infrastructure threats, oil and chemical spills, and building...risk reduction can enhance protection of buildings even in these high-risk areas. Volcanoes The United States is among the most volcanically active

Characterization of anthropogenic and natural sources of acid rock drainage at the Cinnamon Gulch abandoned mine land inventory site, Summit County, Colorado

USGS Publications Warehouse

Bird, D.A.

2003-01-01

Colorado's Cinnamon Gulch releases acid rock drainage (ARD) from anthropogenic and natural sources. In 2001, the total discharge from Cinnamon Gulch was measured at 1.02 cfs (29 L/s) at base flow and 4.3 cfs (122 L/s) at high flow (spring runoff). At base flow, natural sources account for 98% of the discharge from the watershed, and about 96% of the chemical loading. At high flow, natural sources contribute 96% of discharge and 92 to 95% of chemical loading. The pH is acidic throughout the Cinnamon Gulch watershed, ranging from 2.9 to 5.4. At baseflow, nearly all of the trace metals analyzed in the 18 samples exceeded state hardness-dependent water quality standards for aquatic life. Maximum dissolved concentrations of selected constituents included 16 mg/ L aluminum, 15 mg/L manganese, 40 mg/L iron, 2 mg/L copper, 560 ??g/L lead, 8.4 mg/L zinc, and 300 mg/L sulfate. Average dissolved concentrations of selected metals at baseflow were 5.5 mg/L aluminum, 5.5 mg/L manganese, 14 ??g/L cadmium, 260 ??g/L copper, 82 ??g/L lead, and 2.8 mg/L zinc.

Chlorine-36 tracing of salinity sources in the Dry Valleys of Victoria Land, Antarctica

NASA Astrophysics Data System (ADS)

Carlson, Catherine A.; Phillips, Fred M.; Elmore, David; Bentley, Harold W.

1990-02-01

Chlorine-36 was used to trace the origins of salts in six saline lakes in the Dry Valleys of Southern Victoria Land, Antarctica. Characteristic 36Cl signatures were estimated for the various potential chloride sources, which include atmospheric deposition, rock weathering, seawater, and deep ground water. 36Cl /Cl ratios were measured in natural waters and salts from the Dry Valleys. Dilute lake waters (Cl - < 100 mg/l) were found to have 36Cl /Cl ratios in the range 100 × 10 -15 to 1,700 × 10 -15, whereas saline waters (Cl - > 1000 mg/l) had ratios in the range 9 × 10 -15 to 40 × 10 -15. Simple mixing models were employed to quantify the relative contributions of the various chloride sources to Lake Vanda and Don Juan Pond. These results show that Lake Vanda has received its chloride from both deep ground water and the Onyx River. Don Juan Pond has received nearly all its chloride from deep ground water, probably ultimately from rock-water interaction. Deep ground water is the principal source of chloride to the lakes of Wright Valley. However, preliminary data suggest that marine-derived salts or relict sea water may be a significant source of chloride to the lakes of Taylor Valley, implying a possible recent marine invasion that did not affect Wright Valley.

Thermomechanical controls on magma supply and volcanic deformation: application to Aira caldera, Japan.

PubMed

Hickey, James; Gottsmann, Joachim; Nakamichi, Haruhisa; Iguchi, Masato

2016-09-13

Ground deformation often precedes volcanic eruptions, and results from complex interactions between source processes and the thermomechanical behaviour of surrounding rocks. Previous models aiming to constrain source processes were unable to include realistic mechanical and thermal rock properties, and the role of thermomechanical heterogeneity in magma accumulation was unclear. Here we show how spatio-temporal deformation and magma reservoir evolution are fundamentally controlled by three-dimensional thermomechanical heterogeneity. Using the example of continued inflation at Aira caldera, Japan, we demonstrate that magma is accumulating faster than it can be erupted, and the current uplift is approaching the level inferred prior to the violent 1914 Plinian eruption. Magma storage conditions coincide with estimates for the caldera-forming reservoir ~29,000 years ago, and the inferred magma supply rate indicates a ~130-year timeframe to amass enough magma to feed a future 1914-sized eruption. These new inferences are important for eruption forecasting and risk mitigation, and have significant implications for the interpretations of volcanic deformation worldwide.

Thermomechanical controls on magma supply and volcanic deformation: application to Aira caldera, Japan

PubMed Central

Hickey, James; Gottsmann, Joachim; Nakamichi, Haruhisa; Iguchi, Masato

2016-01-01

Ground deformation often precedes volcanic eruptions, and results from complex interactions between source processes and the thermomechanical behaviour of surrounding rocks. Previous models aiming to constrain source processes were unable to include realistic mechanical and thermal rock properties, and the role of thermomechanical heterogeneity in magma accumulation was unclear. Here we show how spatio-temporal deformation and magma reservoir evolution are fundamentally controlled by three-dimensional thermomechanical heterogeneity. Using the example of continued inflation at Aira caldera, Japan, we demonstrate that magma is accumulating faster than it can be erupted, and the current uplift is approaching the level inferred prior to the violent 1914 Plinian eruption. Magma storage conditions coincide with estimates for the caldera-forming reservoir ~29,000 years ago, and the inferred magma supply rate indicates a ~130-year timeframe to amass enough magma to feed a future 1914-sized eruption. These new inferences are important for eruption forecasting and risk mitigation, and have significant implications for the interpretations of volcanic deformation worldwide. PMID:27619897

Decarboxylation of Carbon Compounds as a Potential Source for CO2 and CO Observed by SAM at Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Eigenbrode, J. L.; Bower, H.; Archer, P. Jr.

2014-01-01

Martian carbon was detected in the Sheepbed mudtsone at Yellowknife Bay, Gale Crater, Mars by the Sample Analysis at Mars (SAM) instrument onboard Curiosity, the rover of the Mars Science Laboratory missio]. The carbon was detected as CO2 thermally evolved from drilled and sieved rock powder that was delivered to SAM as a <150-micron-particle- size fraction. Most of the CO2 observed in the Cumberland (CB) drill hole evolved between 150deg and 350deg C. In the John Klein (JK) drill hole, the CO2 evolved up to 500deg C. Hypotheses for the source of the the CO2 include the breakdown of carbonate minerals reacting with HCl released from oxychlorine compounds, combustion of organic matter by O2 thermally evolved from the same oxychlorine minerals, and the decarboxylation of organic molecules indigenous to the martian rock sample. Here we explore the potential for the decarboxylation hypothesis.

Preliminary Aeromagnetic Map of Joshua Tree National Park and Vicinity, Southern California

USGS Publications Warehouse

Langenheim, V.E.; Hill, P.L.

2010-01-01

This aeromagnetic map of Joshua Tree National Park and vicinity is intended to promote further understanding of the geology and structure in the region by serving as a basis for geophysical interpretations and by supporting geological mapping, water-resource investigations, and various topical studies. Local spatial variations in the Earth's magnetic field (evident as anomalies on aeromagnetic maps) reflect the distribution of magnetic minerals, primarily magnetite, in the underlying rocks. In many cases the volume content of magnetic minerals can be related to rock type, and abrupt spatial changes in the amount of magnetic minerals commonly mark lithologic or structural boundaries. Bodies of mafic and ultramafic rocks tend to produce the most intense magnetic anomalies, but such generalizations must be applied with caution because rocks with more felsic compositions, or even some sedimentary units, also can cause measurable magnetic anomalies. The database includes two ASCII files containing new aeromagnetic data and two ASCII files with point locations of the local maximum horizontal gradient derived from the aeromagnetic data. This metadata file describes the horizontal gradient locations derived from new and existing aeromagnetic data. This aeromagnetic map identifies magnetic features as a basis for geophysical interpretations; the gradients help define the edges of magnetic sources. This database updates geophysical information originally presented in smaller-scale formats and includes detailed aeromagnetic data collected by EON Geosciences, Inc.

Lead isotope compositions of Late Cretaceous and early Tertiary igneous rocks and sulfide minerals in Arizona: Implications for the sources of plutons and metals in porphyry copper deposits

USGS Publications Warehouse

Bouse, R.M.; Ruiz, J.; Titley, S.R.; Tosdal, R.M.; Wooden, J.L.

1999-01-01

Porphyry copper deposits in Arizona are genetically associated with Late Cretaceous and early Tertiary igneous complexes that consist of older intermediate volcanic rocks and younger intermediate to felsic intrusions. The igneous complexes and their associated porphyry copper deposits were emplaced into an Early Proterozoic basement characterized by different rocks, geologic histories, and isotopic compositions. Lead isotope compositions of the Proterozoic basement rocks define, from northwest to southeast, the Mojave, central Arizona, and southeastern Arizona provinces. Porphyry copper deposits are present in each Pb isotope province. Lead isotope compositions of Late Cretaceous and early Tertiary plutons, together with those of sulfide minerals in porphyry copper deposits and of Proterozoic country rocks, place important constraints on genesis of the magmatic suites and the porphyry copper deposits themselves. The range of age-corrected Pb isotope compositions of plutons in 12 Late Cretaceous and early Tertiary igneous complexes is 206Pb/204Pb = 17.34 to 22.66, 207Pb/204Pb = 15.43 to 15.96, and 208Pb/204Pb = 37.19 to 40.33. These Pb isotope compositions and calculated model Th/U are similar to those of the Proterozoic rocks in which the plutons were emplaced, thereby indicating that Pb in the younger rocks and ore deposits was inherited from the basement rocks and their sources. No Pb isotope differences distinguish Late Cretaceous and early Tertiary igneous complexes that contain large economic porphyry copper deposits from less rich or smaller deposits that have not been considered economic for mining. Lead isotope compositions of Late Cretaceous and early Tertiary plutons and sulfide minerals from 30 metallic mineral districts, furthermore, require that the southeastern Arizona Pb province be divided into two subprovinces. The northern subprovince has generally lower 206Pb/204Pb and higher model Th/U, and the southern subprovince has higher 206Pb/204Pb and lower model Th/U. These Pb isotope differences are inferred to result from differences in their respective post-1.7 Ga magmatic histories. Throughout Arizona, Pb isotope compositions of Late Cretaceous and early Tertiary plutons and associated sulfide minerals are distinct from those of Jurassic plutons and also middle Tertiary igneous rocks and sulfide minerals. These differences most likely reflect changes in tectonic setting and magmatic sources. Within Late Cretaceous and early Tertiary igneous complexes that host economic porphyry copper deposits, there is commonly a decrease in Pb isotope composition from older to younger plutons. This decrease in Pb isotope values with time suggests an increasing involvement of crust with lower U/Pb than average crust in the source(s) of Late Cretaceous and early Tertiary magmas. Lead isotope compositions of the youngest porphyries in the igneous complexes are similar to those in most sulfide minerals within the associated porphyry copper deposit. This Pb isotope similarity argues for a genetic link between them. However, not all Pb in the sulfide minerals in porphyry copper deposits is magmatically derived. Some sulfide minerals, particularly those that are late stage, or distal to the main orebody, or in Proterozoic or Paleozoic rocks, have elevated Pb isotope compositions displaced toward the gross average Pb isotope composition of the local country rocks. The more radiogenic isotopic compositions argue for a contribution of Pb from those rocks at the site of ore deposition. Combining the Pb isotope data with available geochemical, isotopic, and petrologic data suggests derivation of the young porphyry copper-related plutons, most of their Pb, and other metals from a hybridized lower continental crustal source. Because of the likely involvement of subduction-related mantle-derived basaltic magma in the hybridized lower crustal source, an indiscernible mantle contribution is probable in the porphyry magmas. Clearly, in addition

Petrogenesis of metaultramafic rocks from the Quadrilátero Ferrífero and adjacent terrains, Minas Gerais, Brazil: Two events of ultramafic magmatism?

NASA Astrophysics Data System (ADS)

da Fonseca, Gabriela Magalhães; Jordt-Evangelista, Hanna; Queiroga, Gláucia Nascimento

2018-03-01

In the worldwide known Quadrilátero Ferrífero and the adjacent terrains, southeastern Brazil, many serpentinite and soapstone quarries, and some rare bodies of metaultramafic rocks that partially preserve minerals or textures from the original igneous protolith can be found. It is not known if the protoliths and the ages of the metaultramafic rocks found in the Quadrilátero Ferrífero (and its oriental basement) and Mineiro Belt regions are the same or if they represent distinct magmatic episodes. The petrogenetic investigation, specially concerning the REE contents, aimed to gather informations about the type of magmatism and the mantle source in order to compare the metaultramafic rocks of both regions. The interpretation of the data concerning petrography, mineral chemistry and geochemistry shows that the metaultramafic rocks are similar to komatiitic peridotites, with MgO contents > 22 wt % and TiO2 < 0.9 wt %. The plot of the REE for the lithotypes found in the Quadrilátero Ferrífero shows decrease in LREE possibly reflecting the depletion of the mantle source. On the other hand the samples from the Mineiro Belt are enriched in LREE suggesting a mantle source enriched in these elements. This enrichment may have been caused by mantle metassomatism that occurred during accretion of the Paleoproterozoic magmatic arc that generated the Mineiro belt. In this paper, we therefore suggest two periods of ultramafic magmatism. The first one found in the Archean basement of the Quadrilátero Ferrífero, with a depleted mantle source. The second occurred in the Paleoproterozoic basement of the Mineiro belt, having a metassomatized mantle as source.

Maturation history modeling of Sufyan Depression, northwest Muglad Basin, Sudan

NASA Astrophysics Data System (ADS)

Wang, Ying; Liu, Luofu; An, Fuli; Wang, Hongmei; Pang, Xiongqi

2016-08-01

The Sufyan Depression is located in the northwest of Muglad Basin and is considered as a favorable exploration area by both previous studies and present oil shows. In this study, 16 wells are used or referred, the burial history model was built with new seismic, logging and well data, and the thermal maturity (Ro, %) of proved AG source rocks was predicted based on heat flow calculation and EASY %Ro modeling. The results show that the present heat flow range is 36 mW/m2∼50 mW/m2 (average 39 mW/m2) in 13 wells and 15 mW/m2∼55 mW/m2 in the whole depression. Accordingly, the geothermal gradient is 20 °C/km∼26 °C/km and 12 °C/km∼30 °C/km, respectively. The paleo-heat flow has three peaks, namely AG-3 period, lower Bentiu period and Early Paleogene, with the value decreases from the first to the last, which is corresponding to the tectonic evolution history. Corresponding to the heat flow distribution feature, the AG source rocks become mature earlier and have higher present marurity in the south area. For AG-2_down and AG-3_up source rocks that are proved to be good-excellent, most of them are mature with Ro as 0.5%-1.1%. But they can only generate plentiful oil and gas to charge reservoirs in the middle and south areas where their Ro is within 0.7%-1.1%, which is consistent with the present oil shows. Besides, the oil shows from AG-2_down reservoir in the middle area of the Sufyan Depression are believed to be contributed by the underlying AG-3_up source rock or the source rocks in the south area.

Terrestrial tight oil reservoir characteristics and Graded Resource Assessment in China

NASA Astrophysics Data System (ADS)

Wang, Shejiao; Wu, Xiaozhi; Guo, Giulin

2016-04-01

The success of shale/tight plays and the advanced exploitation technology applied in North America have triggered interest in exploring and exploiting tight oil in China. Due to the increased support of exploration and exploitation，great progress has been made in Erdos basin, Songliao basin, Junggar basin, Santanghu basin, Bohai Bay basin, Qaidam Basin, and Sichuan basin currently. China's first tight oil field has been found in Erdos basin in 2015, called xinanbian oil field, with over one hundred million tons oil reserves and one million tons of production scale. Several hundred million tons of tight oil reserve has been found in other basins, showing a great potential in China. Tight oil in China mainly developed in terrestrial sedimentary environment. According to the relations of source rock and reservoir, the source-reservoir combination of tight oil can be divided into three types, which are bottom generating and top storing tight oil,self- generating and self-storing tight oil，top generating and bottom storing tight oil. The self- generating and self-storing tight oil is the main type discovered at present. This type of tight oil has following characteristics:(1) The formation and distribution of tight oil are controlled by high quality source rocks. Terrestrial tight oil source rocks in China are mainly formed in the deep to half deep lacustrine facies. The lithology includes dark mudstone, shale, argillaceous limestone and dolomite. These source rocks with thickness between 20m-150m, kerogen type mostly I-II, and peak oil generation thermal maturity(Ro 0.6-1.4%), have great hydrocarbon generating potential. Most discovered tight oil is distributed in the area of TOC greater than 2 %.( 2) the reservoir with strong heterogeneity is very tight. In these low porosity and permeability reservoir,the resources distribution is controlled by the physical property. Tight sandstone, carbonate and hybrid sedimentary rocks are three main tight reservoir types in China. The porosity is 2-14%(average 5-10%)and the permeability is less than 1mD. The laboratory test and exploration practice confirmed that the oil content was positively related to physical property. The higher the porosity, the better the oil content will have. (3) Source rock and reservoir are superimposed. From the contact relationship of source rock and reservoir, the reservoir developed in the source rock has the advantage of capturing oil and gas, so the oil saturation can be as high as 70-80%. (4) The increased pressure caused by hydrocarbon generation and the connected fracture are the key factors for tight oil accumulation. The Fuyu tight oil formed underling source rock in Songliao Basin is a good example. The fracture system is the key factor for tight oil accumulation. Considering the strong heterogeneity of terrestrial tight oil reservoir in china, we create hierarchical resource abundance analogy, EUR analogy, cell element volumetric methods to evaluate tight oil resource potential. In order to find exploration "sweet spots", establishing tight oil resource classification evaluation standards are key steps to objectively evaluate tight oil resource distribution. The resource classification evaluation standards are established by the relationship analysis between reservoir properties and oil properties, and the correlation analysis between production, resource abundance, and reservoir thickness. The first-grade tight oil resource, which is recently available and can easily be developed, has following main parameters: the porosity is greater than 8%, thickness is over 10m, resource abundance is above 150,000 tons / km2, and pressure coefficient is greater than 1.3; The second-grade tight oil resource is currently unavailable, but with advanced technology can expected to be developed. The main parameters are as following: the porosity is 5% -8%, thickness is less than 5-10m, resource abundance is 50000-150000 tons / km2, the pressure coefficient is 1.0 to 1.3; The third-grade resource has poor quality, need long-term to be effective explored, has following main parameters: porosity is less than 5%, the thickness is less than 5m, resource abundance is less than 50,000 tons / km2, the pressure coefficient is less than 1.0. Using created resource evaluation methods, the tight oil resources has been calculated in china. The first-grade recoverable resource of tight oil is about 610 million tons. The second-grade recoverable resource is 450 million tons. And the third-grade recoverable resource is 400 million tons. The first-grade and second-grade recoverable resources are mainly distributed in the Ordos basin, Bohai Bay basin, Songliao basin, Junggar basin, and Qaidam Basin. The third-grade resources are mainly distributed in Sichuan and Santanghu basin.

Geochemical characteristics of igneous rocks associated with epithermal mineral deposits—A review

USGS Publications Warehouse

du Bray, Edward A.

2017-01-01

Newly synthesized data indicate that the geochemistry of igneous rocks associated with epithermal mineral deposits varies extensively and continuously from subalkaline basaltic to rhyolitic compositions. Trace element and isotopic data for these rocks are consistent with subduction-related magmatism and suggest that the primary source magmas were generated by partial melting of the mantle-wedge above subducting oceanic slabs. Broad geochemical and petrographic diversity of individual igneous rock units associated with epithermal deposits indicate that the associated magmas evolved by open-system processes. Following migration to shallow crustal reservoirs, these magmas evolved by assimilation, recharge, and partial homogenization; these processes contribute to arc magmatism worldwide.Although epithermal deposits with the largest Au and Ag production are associated with felsic to intermediate composition igneous rocks, demonstrable relationships between magmas having any particular composition and epithermal deposit genesis are completely absent because the composition of igneous rock units associated with epithermal deposits ranges from basalt to rhyolite. Consequently, igneous rock compositions do not constitute effective exploration criteria with respect to identification of terranes prospective for epithermal deposit formation. However, the close spatial and temporal association of igneous rocks and epithermal deposits does suggest a mutual genetic relationship. Igneous systems likely contribute heat and some of the fluids and metals involved in epithermal deposit formation. Accordingly, deposit formation requires optimization of source metal contents, appropriate fluid compositions and characteristics, structural features conducive to hydrothermal fluid flow and confinement, and receptive host rocks, but not magmas with special compositional characteristics.

Provenance analysis on detrital zircons from the back-arc Arivechi basin: Implications for the Upper Cretaceous tectonic evolution of northern Sonora and southern Arizona

NASA Astrophysics Data System (ADS)

Rodríguez-Castañeda, José Luis; Ortega-Rivera, Amabel; Roldán-Quintana, Jaime; Espinoza-Maldonado, Inocente Guadalupe

2018-07-01

In the Arivechi region of eastern Sonora, northwestern Mexico, mountainous exposures of Upper Cretaceous rocks that contain monoliths within coarse sedimentary debris are enigmatic, in a province of largely Late Cretaceous continental-margin arc rocks. The rocks sequence in the study area are grouped in two Upper Cretaceous units: the lower Cañada de Tarachi and the younger El Potrero Grande. Detrital zircons collected from three samples of the Cañada de Tarachi and El Potrero Grande units have been analyzed for U-Pb ages to constrain their provenance. These ages constrain the age of the exposed rocks and provide new insights into the geological evolution of eastern Sonora Cretaceous rocks. The detrital zircon age populations determined for the Cañada de Tarachi and El Potrero Grande units contain distinctive Precambrian, Paleozoic, and Mesozoic zircon ages that provide probable source areas which are discussed in detail constraining the tectonic evolution of the region. Comparison of these knew ages with published data suggests that the source terranes, that supplied zircons to the Arivechi basin, correlate with Proterozoic, Paleozoic and Mesozoic domains in southern California and Baja California, northern Sonora, southern Arizona and eastern Chihuahua. The provenance variation is vital to constrain the source of the Cretaceous rocks in eastern Sonora and support a better understanding of the Permo-Triassic Cordilleran Magmatic Arc in the southwestern North America.

Tectonics of Chukchi Sea Shelf sedimentary basins and its influence on petroleum systems

NASA Astrophysics Data System (ADS)

Agasheva, Mariia; Antonina, Stoupakova; Anna, Suslova; Yury, Karpov

2016-04-01

The Chukchi Sea Shelf placed in the East Arctic offshore of Russia between East Siberian Sea Shelf and North Slope Alaska. The Chukchi margin is considered as high petroleum potential play. The major problem is absence of core material from drilling wells in Russian part of Chukchi Shelf, hence strong complex geological and geophysical analyses such as seismic stratigraphy interpretation should be provided. In addition, similarity to North Slope and Beaufort Basins (North Chukchi) and Hope Basin (South Chukchi) allow to infer the resembling sedimentary succession and petroleum systems. The Chukchi Sea Shelf include North and South Chukchi Basins, which are separated by Wrangel-Herald Arch and characterized by different opening time. The North Chukchi basin is formed as a general part of Canada Basin opened in Early Cretaceous. The South Chukchi Basin is characterized by a transtensional origin of the basin, this deformation related to motion on the Kobuk Fault [1]. Because seismic reflections follow chronostratigraphic correlations, it is possible to achieve stratigraphic interpretation. The main seismic horizons were indicated as: PU, JU, LCU, BU, mBU marking each regional unconformities. Reconstruction of main tectonic events of basin is important for building correct geological model. Since there are no drilling wells in the North and South Chukchi basins, source rocks could not be proven. Referring to the North Chukchi basin, source rocks equivalents of Lower Cretaceous Pebble Shale Formation, Lower Jurassic Kingdak shales and Upper Triassic Shublik Formation (North Slope) is possible exhibited [2]. In the South Chukchi, it is possible that Cretaceous source rocks could be mature for hydrocarbon generation. Erosions and uplifts that could effect on hydrocarbon preservation was substantially in Lower Jurassic and Early Cretaceous periods. Most of the structures may be connected with fault and stratigraphy traps. The structure formed at Wrangel-Herald Arch to North-Chukchi through similar to well-known structure in Norwegian part of Barents Sea - Loppa High. In South Chukchi basin, the seismic wave shows interesting structures akin to diaper fold. Inversion-related anticlines and stratigraphic pinch-outs traps could presence in Cretaceous-Cenozoic cross section. As a result, we gathered and analyzed source rocks and reservoir analogs and gained improved sedimentary models in Eastern Russian Shelfs (Laptev, East Siberian and Chukchi Seas). Appropriate tectonic conditions, proven by well testing source rocks in North Slope and high thickness of basins suggest a success of hydrocarbon exploration in Russian part of Chukchi Sea Shelf. [1] Verzhbitsky V. E., S. D. Sokolov, E. M. Frantzen, A. Little, M. I. Tuchkova, and L.I. Lobkovsky, 2012, The South Chukchi Sedimentary Basin (Chukchi Sea, Russian Arctic): Age, structural pattern,and hydrocarbon potential, in D. Gao, ed., Tectonics and sedimentation: Implications for petroleum systems: AAPG Memoir 100, p.267-290. [2] Peters K. E., Magoon L. B., Bird K. J., Valin Z. C., Keller M. A. North Slope, Alaska: Source rock distribution, richness, thermal maturity, and petroleum charge AAPG Bulletin, V. 90, No. 2 (February 2006), 2006, P. 261-292.

Origin of the ca. 50 Ma Linzizong shoshonitic volcanic rocks in the eastern Gangdese arc, southern Tibet

NASA Astrophysics Data System (ADS)

Liu, An-Lin; Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Wang, Rui; Dai, Jin-Gen; Zheng, Yuan-Chuan; Zhang, Liang-Liang

2018-04-01

The origin of the Eocene shoshonitic rocks within the upper part of the extensive Linzizong volcanic succession (i.e., the Pana Formation) in the Gangdese arc, southern Tibet remains unclear, inhibiting the detailed investigations on the crust-mantle interaction and mantle dynamics that operate the generation of the coeval magmatic flare-up in the arc. We report mineral composition, zircon U-Pb age and zircon Hf isotope, whole-rock element and Sr-Nd-Hf isotope data for the Pana Formation volcanic rocks from Pangduo, eastern Gangdese arc in southern Tibet. The Pana volcanic rocks from Pangduo include basalts, basaltic andesites, and dacites. SIMS and LA-ICPMS zircon U-Pb dating indicates that the Pangduo dacites were erupted at 50 ± 1 Ma, representing the volcanic equivalent of the coeval Gangdese Batholith that define a magmatic flare-up at 51 ± 1 Ma. The Pangduo volcanic rocks are exclusively shoshonitic, differing from typical subduction-related calc-alkaline volcanic rocks. The basalts have positive whole-rock ƐNd(t) (+1.7) and ƐHf(t) (+3.8) with high Zr abundances (121-169 ppm) and Zr/Y ratios (4.3-5.2), most likely derived from the partial melting of an enriched garnet-bearing lithospheric mantle that was metasomatized by subduction-related components with input from asthenosphere. Compared to the basalts, similar trace elemental patterns and decreased whole-rock ƐNd(t) (-3.5 to -3.3) and ƐHf(t) (-2.5 to -1.6) of the basaltic andesites can be attributed to the input of the ancient basement-derived material of the central Lhasa subterrane into the basaltic magmas. The coherent whole-rock Sr-Nd-Hf isotopic compositions ((87Sr/86Sr)i = 0.7064-0.7069, ƐNd(t) = -6.0 to -5.2, ƐHf(t) = -5.6 to -5.0) and varying zircon ƐHf(t) (-6.0 to +4.1) of the dacites can be interpreted by the partial melting of a hybrid lower crust source (juvenile and ancient lower crust) with incorporation of basement-derived components. Calculations of zircon-Ti temperature and whole-rock zircon saturation temperature of the dacites, and clinopyroxene crystallization temperature of the basalts suggest that the Pangduo volcanic rocks are most likely derived from the high-temperature melting of the lithosphere (including lithospheric mantle and overlying continental crust) as a result of the slab breakoff of the Neo-Tethyan oceanic lithosphere.

Relationships between data from Rock-Eval pyrolysis and proximate, ultimate, petrographic, and physical analyses of 142 diverse U.S. coal samples

USGS Publications Warehouse

Bostick, N.H.; Daws, T.A.

1994-01-01

Basic research on coal and oil shale led to automated pyrolysis analysis of petroleum source rocks; most widely used is the Rock-Eval equipment. In order to interpret Rock-Eval analyses in relation to traditional coal data, we analyzed 142 commercial coals with diverse rank, age, maceral and sulfur contents, for most regions of the United States. We compared the Rock-Eval data with traditional industrial coal data, including volatile matter, calorific value, hydrogen and oxygen content, free swelling index, and vitrinite reflectance. We found: (1) there is a close relationship between Tmax and vitrinite reflectance in the ranges 420-590??C Tmax and 0.4-3%Romax of most coals. (2) A close relationship between Tmax and volatile matter (%VM) extends through the entire sample range, including low-rank samples with 35-70% VM, a range where %VM is not considered to be a useful rank parameter. (3) TOC of medium- and high-rank coals is seriously under-measured by Rock-Eval; TOC of low-rank coals (less than 0.8%Romax) is close to "dry basis" carbon from ultimate analysis. (4) The direct relationships between oxygen index (OI) and %O and between hydrogen index (HI) and %H are clear, though only broadly defined. However, there is virtually no band of concentrated data points on the HI versus OI pseudo-Van Krevelen diagram comparable to the "development line" on the H/C versus O/C diagram. (5) There are systematic relationships between Rock-Eval and industrial coal parameters such as calorific value and FSI, but much standardization would be needed before Rock-Eval could find a place in the coal industry. Tests with blends of coal and quartz sand and with various loads of coal alone showed that the amount of organic matter in the Rock-Eval load greatly influences results. Total load in the crucible, if largely inert, plays a small role, however. Increasing absolute or relative coal content causes under-evaluation of Rock-Eval TOC and over-rating of hydrogen. Blends of several coals yielded hydrogen and oxygen indexes related proportionally to the properties of the individual coals, but Tmax is not raised by addition of high-rank coal until over 40% is added. ?? 1994.

Trace elements as quantitative probes of differentiation processes in planetary interiors

NASA Technical Reports Server (NTRS)

Drake, M. J.

1980-01-01

The characteristic trace element signature that each mineral in the source region imparts on the magma constitutes the conceptual basis for trace element modeling. It is shown that abundances of trace elements in extrusive igneous rocks may be used as petrological and geochemical probes of the source regions of the rocks if differentiation processes, partition coefficients, phase equilibria, and initial concentrations in the source region are known. Although compatible and incompatible trace elements are useful in modeling, the present review focuses primarily on examples involving the rare-earth elements.

Mesozoic–Cenozoic Climate and Neotectonic Events as Factors in Reconstructing the Thermal History of the Source-Rock Bazhenov Formation, Arctic Region, West Siberia, by the Example of the Yamal Peninsula

NASA Astrophysics Data System (ADS)

Isaev, V. I.; Iskorkina, A. A.; Lobova, G. A.; Starostenko, V. I.; Tikhotskii, S. A.; Fomin, A. N.

2018-03-01

Schemes and criteria are developed for using the measured and modeled geotemperatures for studying the thermal regime of the source rock formations, as well as the tectonic and sedimentary history of sedimentary basins, by the example of the oil fields of the Yamal Peninsula. The method of paleotemperature modeling based on the numerical solution of the heat conduction equation for a horizontally layered solid with a movable upper boundary is used. The mathematical model directly includes the climatic secular trend of the Earth's surface temperature as the boundary condition and the paleotemperatures determined from the vitrinite reflectance as the measurement data. The method does not require a priori information about the nature and intensities of the heat flow from the Earth's interior; the flow is determined by solving the inverse problem of geothermy with a parametric description of the of the sedimentation history and the history of the thermophysical properties of the sedimentary stratum. The rate of sedimentation is allowed to be zero and negative which provides the possibility to take into account the gaps in sedimentation and denudation. The formation, existence, and degradation of the permafrost stratum and ice cover are taken into account as dynamical lithological-stratigraphic complexes with anomalously high thermal conductivity. It is established that disregarding the paleoclimatic factors precludes an adequate reconstruction of thermal history of the source-rock deposits. Revealing and taking into account the Late Eocene regression provided the computationally optimal and richest thermal history of the source-rock Bazhenov Formation, which led to more correct volumetric-genetic estimates of the reserves. For estimating the hydrocarbon reserves in the land territories of the Arctic region of West Siberia by the volumetric-genetic technique, it is recommended to use the Arctic secular trend of temperatures and take into account the dynamics of the Neoplesitocene permafrost layers 300-600 m thick. Otherwise, the calculated hydrocarbon reserves could be underestimated by up to 40%.

Petroleum prospects for offshore sedimentary basins in the eastern Papua New Guinea and Solomon Islands regions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bruns, T.R.; Vedder, J.G.

Intra-arc basins in the Buka-Bougainville region of Papua New Guinea and in the Solomon Islands contain thick sedimentary sequences that may be prospective for petroleum. The Queen Emma basin, between Bougainville and New Ireland, contains as much as 8 km of deformed Oligocene and younger strata. The Central Solomons Trough, which underlies New Georgia Sound, is a composite intra-arc basin that contains late Oligocene and younger strata as much as 7 km thick. Farther east, beneath Indispensable Strait, the down-faulted Indispensable basin locally contains as much as 5.4 km of Miocene( ) and younger strata, and the offshore part ofmore » Mbokokimbo basin off eastern Guadalcanal includes 6 km or more of late Miocene and younger strata. All of these basins have some of the attributes necessary to generate and trap petroleum. Structural and stratigraphic traps are common, including faulted anticlines, sedimentary wedges, and carbonate reefs and reef-derived deposits on submarine ridges and along the basin margins. The thickness of the basin deposits ensures that some strata are buried deeply enough to be within the thermal regime required for hydrocarbon generation. However, little source or reservoir rock information is available because of the lack of detailed surface and subsurface stratigraphy. Moreover, much of the basin sediment is likely to consist of volcaniclastic material, derived from uplifted volcanogenic rocks surrounding the basins, and may be poor in source and reservoir rocks. Until additional stratigraphic information is available, analysis of the petroleum potential of these basins is a matter of conjecture.« less

The influence of spreading rate, basement composition, fluid chemistry and chimney morphology on the formation of gold-rich SMS deposits at slow and ultraslow mid-ocean ridges

NASA Astrophysics Data System (ADS)

Knight, Robert D.; Roberts, Stephen; Webber, Alexander P.

2018-01-01

Seafloor massive sulphide (SMS) deposits are variably enriched in precious metals including gold. However, the processes invoked to explain the formation of auriferous deposits do not typically apply to mid-ocean ridge settings. Here, we show a statistically significant, negative correlation between the average gold concentration of SMS deposits with spreading rate, at non-sedimented mid-ocean ridges. Deposits located at slow spreading ridges (20-40 mm/a) have average gold concentrations of between 850 and 1600 ppb; however, with increasing spreading rate (up to 140 mm/a), gold concentrations gradually decrease to between 50 and 150 ppb. This correlation of gold content with spreading rate may be controlled by the degree and duration of fluid-rock interaction, which is a function of the heat flux, crustal structure (faulting) and the permeability of the source rocks. Deposits at ultraslow ridges, including ultramafic-hosted deposits, are particularly enriched in gold. This is attributed to the higher permeability of the ultramafic source rocks achieved by serpentinisation and the inherent porosity of serpentine minerals, combined with relatively high gold concentrations in peridotite compared with mid-ocean ridge basalt. Variations in fluid chemistry, such as reducing conditions and the potential for increased sulphur availability at ultramafic-hosted sites, may also contribute to the high concentrations observed. Beehive chimneys, which offer more favourable conditions for gold precipitation, may be more prevalent at ultramafic-hosted sites due to diffuse low-velocity venting compared with more focussed venting at basalt-hosted sites.

Ground-based hyperspectral imaging and terrestrial laser scanning for fracture characterization in the Mississippian Boone Formation

NASA Astrophysics Data System (ADS)

Sun, Lei; Khan, Shuhab D.; Sarmiento, Sergio; Lakshmikantha, M. R.; Zhou, Huawei

2017-12-01

Petroleum geoscientists have been using cores and well logs to study source rocks and reservoirs, however, the inherent discontinuous nature of these data cannot account for horizontal heterogeneities. Modern exploitation requires better understanding of important source rocks and reservoirs at outcrop scale. Remote sensing of outcrops is becoming a first order tool for reservoir analog studies including horizontal heterogeneities. This work used ground-based hyperspectral imaging, terrestrial laser scanning (TLS), and high-resolution photography to study a roadcut of the Boone Formation at Bella Vista, northwest Arkansas, and developed an outcrop model for reservoir analog analyses. The petroliferous Boone Formation consists of fossiliferous limestones interbedded with chert of early Mississippian age. We used remote sensing techniques to identify rock types and to collect 3D geometrical data. Mixture tuned matched filtering classification of hyperspectral data show that the outcrop is mostly limestones with interbedded chert nodules. 1315 fractures were classified according to their strata-bounding relationships, among these, larger fractures are dominantly striking in ENE - WSW directions. Fracture extraction data show that chert holds more fractures than limestones, and both vertical and horizontal heterogeneities exist in chert nodule distribution. Utilizing ground-based remote sensing, we have assembled a virtual outcrop model to extract mineral composition as well as fracture data from the model. We inferred anisotropy in vertical fracture permeability based on the dominancy of fracture orientations, the preferential distribution of fractures and distribution of chert nodules. These data are beneficial in reservoir analogs to study rock mechanics and fluid flow, and to improve well performances.

Geological sources of fluoride and acceptable intake of fluoride in an endemic fluorosis area, southern Iran.

PubMed

Battaleb-Looie, Sedigheh; Moore, Farid; Jacks, Gunnar; Ketabdari, Mohammad Reza

2012-10-01

The present study is the first attempt to put forward possible source(s) of fluoride in the Dashtestan area, Bushehr Province, southern Iran. In response to reports on the high incidence of dental fluorosis, 35 surface and groundwater samples were collected and analysed for fluoride. The results indicate that dissolved fluoride in the study area is above the maximum permissible limit recommended by the World Health Organization (WHO). An additional 35 soil and rock samples were also collected and analysed for fluoride, and rock samples were subjected to petrographic investigations and X-ray diffraction. The results of these analyses show that the most likely source for fluoride in the groundwater is from clay minerals (chlorite) and micas (muscovite, sericite, and biotite) in the soils and rocks in the area. We also note that due to the high average temperatures all year round and excessive water consumption in the area, the optimum fluoride dose level should be lower than that recommended by the WHO.

Boninite-like intraplate magmas from Manihiki Plateau require ultra-depleted and enriched source components

PubMed Central

Golowin, Roman; Portnyagin, Maxim; Hoernle, Kaj; Hauff, Folkmar; Gurenko, Andrey; Garbe-Schönberg, Dieter; Werner, Reinhard; Turner, Simon

2017-01-01

The Ontong Java and Manihiki oceanic plateaus are believed to have formed through high-degree melting of a mantle plume head. Boninite-like, low-Ti basement rocks at Manihiki, however, imply a more complex magma genesis compared with Ontong Java basement lavas that can be generated by ∼30% melting of a primitive mantle source. Here we show that the trace element and isotope compositions of low-Ti Manihiki rocks can best be explained by re-melting of an ultra-depleted source (possibly a common mantle component in the Ontong Java and Manihiki plume sources) re-enriched by ≤1% of an ocean-island-basalt-like melt component. Unlike boninites formed via hydrous flux melting of refractory mantle at subduction zones, these boninite-like intraplate rocks formed through adiabatic decompression melting of refractory plume material that has been metasomatized by ocean-island-basalt-like melts. Our results suggest that caution is required before assuming all Archaean boninites were formed in association with subduction processes. PMID:28181497

The upper limit of maturity of natural gas generation and its implication for the Yacheng formation in the Qiongdongnan Basin, China

NASA Astrophysics Data System (ADS)

Su, Long; Zheng, Jianjing; Chen, Guojun; Zhang, Gongcheng; Guo, Jianming; Xu, Yongchang

2012-08-01

Vitrinite reflectance (VR, Ro%) measurements from residual kerogen of pyrolysis experiments were performed on immature Maoming Oil Shale substituted the samples for the gas-prone source rocks of Yacheng formation of the Qiongdongnan Basin in the South China Sea. The work was focused on determination an upper limit of maturity for gas generation (ULMGG) or "the deadline of natural gas generation". Ro values at given temperatures increase with increasing temperature and prolonged heating time, but ΔRo-value, given a definition of the difference of all values for VR related to higher temperature and adjacent lower temperature in open-system non-isothermal experiment at the heating rate of 20 °C/min, is better than VR. And representative examples are presented in this paper. It indicates that the range of natural gas generation for Ro in the main gas generation period is from 0.96% to 2.74%, in which ΔRo is in concordance with the stage for the onset and end of the main gas generation period corresponding to 0.02% up to 0.30% and from 0.30% up to 0.80%, respectively. After the main gas generation period of 0.96-2.74%, the evolution of VR approach to the ULMGG of the whole rock for type II kerogen. It is equal to 4.38% of VR, where the gas generation rates change little with the increase of maturation, ΔRo is the maximum of 0.83% corresponding to VR of 4.38%Ro, and the source rock does not nearly occur in the end process of hydrocarbon gas generation while Ro is over 4.38%. It shows that it is the same the ULMGG from the whole rock for type II kerogen as the method with both comparison and kinetics. By comparing to both the conclusions of pyrolysis experiments and the data of VR from the source rock of Yacheng formation on a series of selected eight wells in the shallow-water continental shelf area, it indicate that the most hydrocarbon source rock is still far from reaching ULMGG from the whole rock for type II kerogen. The source rock of Yacheng formation in the local areas of the deepwater continental slope basin have still preferable natural gas generative potential, especially in the local along the central depression belt (namely the Ledong, Lingshui, Songnan and Baodao sags from southwest to northeast) from the depocenter to both the margin and its adjacent areas. It help to evaluate the resource potential for oil and gas of the hydrocarbon source rock in the deepwater continental slope of the Qiongdongnan Basin or other basins with lower exploration in the northern of the South China Sea and to reduce the risk in exploration.

Geochemical and multi-isotopic ( 87Sr/ 86Sr, 143Nd/ 144Nd, 238U/ 235U) perspectives of sediment sources, depositional conditions, and diagenesis of the Marcellus Shale, Appalachian Basin, USA

DOE PAGES

Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.; ...

2017-10-25

Here, we investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from –7.8 to –6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from amore » well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns.« less

Geochemical and multi-isotopic ( 87Sr/ 86Sr, 143Nd/ 144Nd, 238U/ 235U) perspectives of sediment sources, depositional conditions, and diagenesis of the Marcellus Shale, Appalachian Basin, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.

Here, we investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from –7.8 to –6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from amore » well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns.« less

Generation of felsic rocks of bimodal volcanic suites from thinned and rifted continental margins: Geochemical and Nd, Sr, Pb-isotopic evidence from Haida Gwaii, British Columbia, Canada

NASA Astrophysics Data System (ADS)

Dostal, Jaroslav; Hamilton, Tark S.; Shellnutt, J. Gregory

2017-11-01

The compositionally bimodal volcanic rocks of the Eocene-Miocene Masset Formation from Queen Charlotte basin, Haida Gwaii, British Columbia, Canada, underlie an area greater than 5000 km2 where their exposed sections are up to 1.6 km thick. The suite of mafic and felsic rocks (dacites and rhyolites) that erupted closely spaced in time, in both submarine and subaerial conditions, was associated with significant crustal extension and thin continental crust ( 19-24 km thick), with volcanism persisting for 35 Ma (from 46 to 11 Ma). Predominant mafic types (mafic:felsic 2:1) are moderately enriched mid-ocean-ridge-like basalts that were derived by a partial melting of a heterogeneous spinel peridotite source. Felsic rocks are plagioclase-phyric, two pyroxene-bearing, mainly peraluminous types which have Nd, Pb and Sr isotopic compositions overlapping those of basalts including high positive ƐNd(t) values (up to >+6). The chondrite-normalized REE patterns show light REE enrichment but flat heavy REE along with a variable negative Eu anomaly. Mineralogy, major and trace elements, Nd-Sr-Pb isotopic data and model calculations using MELTS are consistent with a derivation of felsic rocks from the basalts by fractional crystallization. The intercalation of basaltic and felsic rocks suggests the existence of separate, simultaneously active plumbing and feeder systems and relatively stable magma chamber(s) to generate large volumes of differentiated felsic magmas by fractional crystallization. The Masset rocks provide an example for the generation of felsic magmas of bimodal volcanic suites during rifting along a thinned continental margin. Appendix 1b Representative analyses of minerals of the Masset Formation felsic rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moore, Jeffrey R.; Pankow, Kristine L.; Ford, Sean R.

The 2013 Bingham Canyon Mine rock avalanches represent one of the largest cumulative landslide events in recorded U.S. history and provide a unique opportunity to test remote analysis techniques for landslide characterization. We combine aerial photogrammetry surveying, topographic reconstruction, numerical runout modeling, and analysis of broadband seismic and infrasound data to extract salient details of the dynamics and evolution of the multiphase landslide event. Our results reveal a cumulative intact rock source volume of 52 Mm 3, which mobilized in two main rock avalanche phases separated by 1.5 h. We estimate that the first rock avalanche had 1.5–2 times greatermore » volume than the second. Each failure initiated by sliding along a gently dipping (21°), highly persistent basal fault before transitioning to a rock avalanche and spilling into the inner pit. The trajectory and duration of the two rock avalanches were reconstructed using runout modeling and independent force history inversion of intermediate-period (10–50 s) seismic data. Intermediate- and shorter-period (1–50 s) seismic data were sensitive to intervals of mass redirection and constrained finer details of the individual slide dynamics. Back projecting short-period (0.2–1 s) seismic energy, we located the two rock avalanches within 2 and 4 km of the mine. Further analysis of infrasound and seismic data revealed that the cumulative event included an additional 11 smaller landslides (volumes ~10 4–10 5 m 3) and that a trailing signal following the second rock avalanche may result from an air-coupled Rayleigh wave. These results demonstrate new and refined techniques for detailed remote characterization of the dynamics and evolution of large landslides.« less

A chemical and thermodynamic model of oil generation in hydrocarbon source rocks

NASA Astrophysics Data System (ADS)

Helgeson, Harold C.; Richard, Laurent; McKenzie, William F.; Norton, Denis L.; Schmitt, Alexandra

2009-02-01

Thermodynamic calculations and Gibbs free energy minimization computer experiments strongly support the hypothesis that kerogen maturation and oil generation are inevitable consequences of oxidation/reduction disproportionation reactions caused by prograde metamorphism of hydrocarbon source rocks with increasing depth of burial.These experiments indicate that oxygen and hydrogen are conserved in the process.Accordingly, if water is stable and present in the source rock at temperatures ≳25 but ≲100 °C along a typical US Gulf Coast geotherm, immature (reduced) kerogen with a given atomic hydrogen to carbon ratio (H/C) melts incongruently with increasing temperature and depth of burial to produce a metastable equilibrium phase assemblage consisting of naphthenic/biomarker-rich crude oil, a type-II/III kerogen with an atomic hydrogen/carbon ratio (H/C) of ˜1, and water. Hence, this incongruent melting process promotes diagenetic reaction of detritus in the source rock to form authigenic mineral assemblages.However, in the water-absent region of the system CHO (which is extensive), any water initially present or subsequently entering the source rock is consumed by reaction with the most mature kerogen with the lowest H/C it encounters to form CO 2 gas and a new kerogen with higher H/C and O/C, both of which are in metastable equilibrium with one another.This hydrolytic disproportionation process progressively increases both the concentration of the solute in the aqueous phase, and the oil generation potential of the source rock; i.e., the new kerogen can then produce more crude oil.Petroleum is generated with increasing temperature and depth of burial of hydrocarbon source rocks in which water is not stable in the system CHO by a series of irreversible disproportionation reactions in which kerogens with higher (H/C)s melt incongruently to produce metastable equilibrium assemblages consisting of crude oil, CO 2 gas, and a more mature (oxidized) kerogen with a lower H/C which in turn melts incongruently with further burial to produce more crude oil, CO 2 gas, and a kerogen with a lower H/C and so forth.The petroleum generated in the process progresses from heavy naphthenic crude oils at low temperatures to mature petroleum at ˜150 °C. For example, the results of Computer Experiment 27 (see below) indicate that the overall incongruent melting reaction in the water-absent region of the system C-H-O at 150 °C and a depth of ˜4.3 km of an immature type-II/III kerogen with a bulk composition represented by C 292H 288O 12(c) to produce a mature (oxidized) kerogen represented by C 128H 68O 7(c), together with a typical crude oil with an average metastable equilibrium composition corresponding to C 8.8H 16.9 (C 8.8H 16.9(l)) and CO 2 gas (CO 2(g)) can be described by writing CHO (kerogen,H/C=0.99O/C=0.041) →1.527CHO(kerogen,H/C=0.53O/C=0.055) +10.896CH(crude oil,H/C=1.92)+0.656CO which corresponds to a disproportionation reaction in the source rock representing the sum of a series of oxidation/reduction conservation reactions. Consideration of the stoichiometries of incongruent melting reactions analogous to Reaction (A) for reactant kerogens with different (H/C)s and/or atomic oxygen to carbon ratios (O/C)s, together with crude oil compositions corresponding to Gibbs free energy minima at specified temperatures and pressures permits calculation of the volume of oil (mole of reactant organic carbon (ROC)) -1 that can be generated in, as well as the volume of oil (mol ROC) -1 which exceeds the volume of kerogen pore space produced that must be expelled from hydrocarbon source rocks as a function of temperature, pressure, and the H/C and O/C of the reactant kerogen. These volumes and the reaction coefficients (mol ROC) -1 of the product kerogen, crude oil, and CO 2 gas in the incongruent melting reaction are linear functions of the H/C and O/C of the reactant kerogen at a given temperature and pressure. The slopes of the isopleths can be computed from power functions of temperature along a typical US Gulf Coast geotherm. All of these reactions and relations are consistent with the well-known observations that (1) the relative abundance of mature kerogen increases, and that of immature kerogen decreases with increasing burial of hydrocarbon source rocks and (2) that the volume of oil generated in a given source rock increases with increasing weight percent total organic carbon (TOC) and the H/C and (to a lesser extent) the O/C of the immature kerogen. They are also compatible with preservation of biomarkers and other polymerized hydrocarbons during the incongruent melting process. It can be deduced from Reaction (A) that nearly 11 mol of crude oil are produced from one mole of the reactant kerogen (rk), which increases to ˜39.5 mol (mol rk) -1 as the carbon content and H/C of the reactant kerogen increase to that in the hydrogen-rich type-I kerogen represented by C 415H 698O 22(c). The secondary porosities created in source rocks by Reaction (A) and others like it are of the order of 75-80 vol % of the oil generated, which requires expulsion of the remainder, together with the CO 2 gas produced by the reaction. The expulsion of the CO 2 gas and excess crude oil from the hydrocarbon source rock is facilitated by their buoyancy and the fact that the pressure in the source rocks is ⩾ the fluid pressure in the adjoining formations during progressive generation of the volume of crude oil that exceeds the kerogen pore volume produced by the incongruent melting process. The expelled CO 2 gas lowers the pH of the surrounding formation waters, which promotes the development of secondary porosity and diagenetic reaction of detrital silicates to form authigenic mineral assemblages. Hence, the expulsion process facilitates initial upward migration of the oil, which is further enhanced by expansion of the oil and its reaction with H 2O at the oil-water interface to generate methane gas. Mass transfer calculations indicate that the minimal volume of crude oil expelled into these formations is comparable to, or exceeds the volume of oil produced and in proven reserves in major oil fields such as the North Sea, the Paris and Los Angeles Basins, and those in Kuwait, Saudi Arabia, and elsewhere in the Middle East. For example, taking account of the average weight percent ( W%) organic carbon in the immature kerogen (3.4 wt%) with an average H/C of ˜1.04 in the hydrocarbon source rocks in Saudi Arabia, which have an average thickness of ˜43 m, it can be shown (see below) that all of the oil (and oil equivalent of natural gas) produced and in proven reserves in Saudi Arabia (374 billion barrels of oil or ˜1.9 million barrels of oil km -2) can be accounted for by minimal expulsion from the source rocks of oil generated at ˜125 °C solely by the incongruent melting process. Computer experiments indicate that this process can also account for all the petroleum that can be, and has been generated in the world's hydrocarbon source rocks. Of the latter, as much as 75-80% may still remain in these rocks.

Origins of cryptic variation in the Ediacaran-Fortunian rhyolitic ignimbrites of the Saldanha Bay Volcanic Complex, Western Cape, South Africa

NASA Astrophysics Data System (ADS)

Clemens, J. D.; Stevens, G.; Frei, D.; Joseph, C. S. A.

2017-12-01

The Saldanha eruption centre, on the West Coast of South Africa, consists of 542 Ma, intracaldera, S-type, rhyolite ignimbrites divided into the basal Saldanha Ignimbrite and the partly overlying Jacob's Bay Ignimbrite. Depleted-mantle Nd model ages suggest magma sources younger than the Early Mesoproterozoic, and located within the Neoproterozoic Malmesbury Group and Swartland complex metasedimentary and metavolcanic rocks that form the regional basement. The Sr isotope systematics suggest that the dominant source rocks were metavolcaniclastic rocks and metagreywackes, and that the magmas formed from separate batches extracted from the same heterogeneous source. No apparent magma mixing trends relate the Saldanha to the Jacob's Bay Ignimbrites, or either of these to the magmas that formed the Plankiesbaai or Tsaarsbank Ignimbrites in the neighbouring Postberg eruption centre. The magmas were extracted from their source rocks carrying small but significant proportions of peritectic and restitic accessory minerals. Variations in the content of this entrained crystal cargo were responsible for most of the chemical variations in the magmas. Although we cannot construct a cogent crystal fractionation model to relate these groups of magmas, at least some crystal fractionation occurred, as an overlay on the primary signal due to peritectic assemblage entrainment (PAE). Thus, the causes of the cryptic chemical variation among the ignimbrite magmas of the Saldanha centre are variable, but dominated by the compositions of the parent melts and PAE. The preservation of clear, source-inherited chemical signatures, in individual samples, calls into question the common interpretation of silicic calderas as having been formed in large magma reservoirs, with magma compositions shaped by magma mingling, mixing, and fractional crystallization. The Saldanha rocks suggest a more intimate connection between source and erupted magma, and perhaps indicate that silicic magmas are too viscous to be significantly modified by magma-chamber processes.

Rock fall dynamics and deposition: an integrated analysis of the 2009 Ahwiyah Point rock fall, Yosemite National Park, USA.

USGS Publications Warehouse

Valerie L. Zimmer,; Collins, Brian D.; Greg M. Stock,; Nicholas Sitar,

2012-01-01

We analyzed a combination of airborne and terrestrial LiDAR, high-resolution photography, seismic, and acoustic data in order to gain insights into the initiation, dynamics, and talus deposition of a complex rock fall. A large (46 700 m3) rock fall originated from near Ahwiyah Point in eastern Yosemite Valley and fell a total of 730 m to the valley floor on 28 March 2009. Analyses of remote sensing, seismic, and acoustic data were integrated to reconstruct the rock fall, which consisted of (1) the triggering of a 25 400 m3 rock block in an area of intersecting and sometimes highly weathered joint planes, (2) the sliding and subsequent ballistic trajectory of the block from a steeply dipping ledge, (3) dislodging of additional rock from the cliff surface from beneath the rock fall source area, (4) a mid-cliff ledge impact that detached a volume of rock nearly equivalent in volume to the initial block, (5) sliding of the deteriorating rock mass down the remainder of the cliff, and (6) final impact at the base of the cliff that remobilized the existing talus downward and outward and produced an airblast that knocked down hundreds of trees. The depositional geomorphology indicates that the porosity of the fresh talus is significantly lower than that expected for typical blocky talus slopes, likely because the rock debris from this event was pulverized into smaller, more poorly sorted fragments and densified via dynamic compaction when compared to less energetic, fragmental-type rock falls. These results suggest that accumulation of individual rock-fall boulders tends to steepen talus slopes, whereas large, energetic rock falls tend to flatten them. Detachment and impact signals were recorded by seismic and acoustic instruments and highlight the potential use of this type of instrumentation for generalized rock fall monitoring, while LiDAR and photography data were able to quantify the cliff geometry, rock fall volume, source and impact locations, and geomorphological changes to the cliff and talus.

Rheological stratification of the Hormuz Salt Formation in Iran - microstructural study of the dirty and pure rock salts from the Kuh-e-Namak (Dashti) salt diapir

NASA Astrophysics Data System (ADS)

Závada, Prokop; Desbois, Guillaume; Urai, Janos; Schulmann, Karel; Rahmati, Mahmoud; Lexa, Ondrej; Wollenberg, Uwe

2014-05-01

Significant viscosity contrasts displayed in flow structures of a mountain namakier (Kuh-e-Namak - Dashti), between 'weak' terrestrial debris bearing rock salt types and 'strong' pure rock salt types are questioned for deformation mechanisms using detailed quantitative microstructural study including crystallographic preferred orientation (CPO) mapping of halite grains. While the solid impurity rich ("dirty") rock salts contain disaggregated siltstone and dolomite interlayers, "clean" salts (debris free) reveal microscopic hematite and remnants of abundant fluid inclusions in non-recrystallized cores of porphyroclasts. Although flow in both, the recrystallized dirty and clean salt types is accommodated by combined mechanisms of pressure-solution creep (PS), grain boundary sliding (GBS) and dislocation creep accommodated grain boundary migration (GBM), their viscosity contrasts are explained by significantly slower rates of intergranular diffusion and piling up of dislocations at hematite inclusions in clean salt types. Porphyroclasts of clean salts deform by semi-brittle and plastic mechanisms with intra-crystalline damage being induced also by fluid inclusions that explode in the crystals at high fluid pressures. Boudins of clean salt types with coarse grained and original sedimentary microstructure suggest that clean rock salts are associated with dislocation creep dominated power law flow in the source layer and the diapiric stem. Rheological contrasts between both rock salt classes apply in general for the variegated and terrestrial debris rich ("dirty") Lower Hormuz and the "clean" rock salt forming the Upper Hormuz, respectively, and suggest that large strain rate gradients likely exist along horizons of mobilized salt types of different composition and microstructure.

Iron-oxide Magnetic, Morphologic, and Compositional Tracers of Sediment Provenance and Ice Sheet Extent in the ANDRILL AND-1B Drill Core, Ross Sea, Antarctica (Invited)

NASA Astrophysics Data System (ADS)

Brachfeld, S. A.; Pinzon, J.; Darley, J. S.; Sagnotti, L.; Kuhn, G.; Florindo, F.; Wilson, G. S.; Ohneiser, C.; Monien, D.; Joseph, L. H.

2013-12-01

The first drilling season of the Antarctic Drilling Program (ANDRILL) recovered a 13.57 million year Miocene through Pleistocene record of paleoclimate change (core AND-1B) within the Ross Sea. The magnetic mineral assemblage records the varying contributions of biological productivity, changing sediment sources, the emergence of volcanic centers, and post-depositional diagenesis. Characterization of bedrock samples from the McMurdo Volcanic Group (MVG) and Transantarctic Mountain (TAM) lithologic units allows us to construct fingerprints for the major source rocks bordering the Ross Sea, and identify their signatures within the AND-1B sediment. Key parameters that can be traced from source rock to sediment for the MVG-derived sediment include a 100-200 C order-disorder transition, titanomaghemite grains with homogenous textures but with substantial Al and Mg content, Fe-spinels with substantial Al, Cr, Mg, and Ti content, and titanomagnetite host grains with 1-3 swarms of ilmenite lamellae (both with variable amounts of oxidation). Distinctive signatures in TAM lithologies include low S-ratios in Koettlitz Group gneisses and Fe-sulfides with magnetite intergrowths in Byrd Glacier basement samples. The Cambrian Granite Harbor Intrusive Complex is characterized by coarse, homogeneous Mn-bearing ilmenite and nearly pure magnetite. The Jurassic dolerites and basalts of the Ferrar Group contain pseudo single domain to stable single domain-sized Fe-oxides with low-Ti content and homogeneous textures. Cu-Fe sulfides are also present in the Ferrar Group. Diamictites in the Pliocene-Pleistocene section of the AND-1B drill core contains Fe-oxide assemblages with MVG-type rock magnetic and textural characteristics, while the Miocene diamictites contain TAM-type signatures. These observations can be explained by increased ice flow from the west during the Miocene and/or the absence of MVG volcanic centers, which had not yet reached a significant size. During the Pliocene and Pleistocene, ice flow was from the south, entraining sediment from MVG volcanic centers south of the drill site. This work demonstrates the utility of using the combination of rock magnetic and electron microscopy signatures of Fe-oxides and Fe-sulfides to serve as provenance tracers in both ice proximal and distal sedimentary units, aiding in the study of ice sheet dynamics, and the identification of ice rafted debris sources and dispersal patterns in the Ross Sea sector of Antarctica.

Isotopic composition of Pb in ore deposits of the Betic Cordillera, Spain; origin and relationship to other European deposits

USGS Publications Warehouse

Arribas , Antonio; Tosdal, Richard M.

1994-01-01

The Betic Cordillera in southern Spain is a complex Alpine fold belt that resulted from the Cretaceous through Cenozoic collision of Africa with Europe. The region is illustrative of one of the characteristics of the Alpine-Mediterranean orogen: the occurrence over a limited area of mineral deposits with a wide variety of host rocks, mineralization ages, and styles. The metamorphic basement in the Betic zone is characterized by a nappe structure of superimposed tectonostratigraphic units and consists of lower Paleozoic to Lower Triassic clastic metasedimentary rocks. This is overlain by Middle to Upper Triassic platform carbonate rocks with abundant strata-bound F-Pb-Zn-(Ba) deposits (e.g., Sierra de Gador, Sierra Alhamilla). Cretaceous to Paleogene subduction-related compression in southeastern Spain was followed by Miocene postcollisional extension and resulted in the formation of the Almeria-Cartagena volcanic belt and widespread hydrothermal activity and associated polymetallic mineralization. Typical Miocene hydrothermal deposits include volcanic-hosted Au (e.g., Rodalquilar) and Ag-rich base metal (e.g., Cabo de Gata, Mazarron) deposits as well as complex polymetallic veins, mantos, and irregular replacement bodies which are hosted by Paleozoic and Mesozoic metamorphic rocks and Neogene sedimentary and volcanic rocks (e.g., Cartagena, Sierra Almagrera, Sierra del Aguilon, Loma de Bas).Lead isotope compositions were measured on sulfide samples from nine ore districts and from representative fresh samples of volcanic and basement rock types of the region. The results have been used to evaluate ore-forming processes in southeastern Spain with emphasis on the sources of metals. During a Late Triassic mineralizing event, Pb was leached from Paleozoic clastic metasedimentary rocks and incorporated in galena in strata-bound F-Pb-Zn-(Ba) deposits ( 206 Pb/ 204 Pb = 18.332 + or - 12, 207Pb/ 204 Pb = 15.672 + or - 12, 208 Pb/ 204 Pb = 38.523 + or - 46). The second episode of mineralization was essentially contemporaneous (late Miocene) throughout the region and did not involve remobilization of less radiogenic Triassic ore Pb. Lead isotope data indicate a dominantly Paleozoic metasedimentary source for polymetallic vein- and manto-type deposits that formed by hydrothermal circulation through the Betic basement, driven by Miocene intrusions ( 206 Pb/ 204 Pb = 18.747 + or - 20, 207 Pb/ 204Pb = 15.685 + or - 9, 208 /Pb/ 204 Pb = 39.026 + or - 37). Lead in Au-(Cu-Te-Sn) ores is isotopically indistinguishable from that of the calc-alkalic volcanic host ( 206 Pb/ 204 Pb = 18.860 + or - 9, 207 Pb/ 204 Pb = 15.686 + or - 8, 208 Pb/ 204 Pb = 38.940 + or - 27). In contrast, the Pb in volcanic-hosted Pb-Zn-Cu-(Ag-Au) veins was derived from Paleozoic metamorphic and Miocene volcanic rocks ( 206 Pb/ 204 Pb = 18.786 + or - 5, 207 Pb/ 204 Pb = 15.686 + or - 2, 208 Pb/ 204 Pb = 38.967 + or - 9).A comparison of the Pb isotope data from southeastern Spain with published data from selected Pb-Zn deposits in southern Europe (including Les Malines, L'Argentiere, and the Alpine, Iglesiente-Sulcis, and Montagne Noire districts) indicates the importance of a metasedimentary basement as a common source of ore Pb.

Hydrogeological Characterization of the Upper Camp Bird III Rock Glacier in the San Juan Mountains, Colorado Using Electromagnetic Induction

NASA Astrophysics Data System (ADS)

Granados-Aguilar, R.; Giardino, J. R.; Everett, M. E.; Pondthai, P.; Ramsey, C. E.; Mmasa, D.; Witek, M.; Rodriguez, R.

2017-12-01

Global change is the set of variations in environmental conditions that significantly impact the Earth systems. Climate, sea level, land-use/land-cover, and atmospheric composition changes are the most recognized environmental global changes. Impacts of climatic variability can include decreased rainfall, snowpack, shorter snow seasons, and changes in the timing, frequency, and intensity of precipitation events in some areas of the world, whereas other regions can suffer from the opposite effects leading to events such as landslides, flooding and extraordinary snowfall. The proposed research intends to provide a characterization of the internal structure, including water storages, pathways, and thresholds, as well as an estimation of the volume of ice stored within a rock glacier to evaluate its potential as a freshwater resources. The area of study corresponds to the third level of Camp Bird Mine in Ouray, Colorado. The tongue-shaped active rock glacier of interest, Upper Camp Bird III, has not been previously studied in detail. The predominant lithologies in the study area are Mesozoic and Cenozoic. Orogenic events caused alteration of sedimentary and intrusive igneous rock as mineral rich, hydrothermal fluids deposited economically valuable minerals in the region. Traditional geological and geomorphological mapping techniques will be complemented with the use of unmanned aerial vehicles (UAV). To obtain a detailed representation of the internal structure and determine the boundaries between resistive (rocks, sediment, and ice) and conductive materials (water and ore deposits) of the rock glacier, time-domain and frequency-domain methods will be implemented. The G-TEM by Geonics Ltd. is an innovative controlled-source time-domain electromagnetic induction system. Using the G-TEM, the distribution of electrical conductivity in the subsurface can be mapped in order to characterize the internal structure of the rock glacier from 5-10 m depth and below. The EM Profiler is a frequency-domain electromagnetic induction system that will be used for the investigation of the uppermost layers of the rock glacier. For the proposed research, the use of two different systems will provide continuity across the data sets and will help validate the measurements recorded with the new equipment.

Obtaining higher-accuracy estimates of water-rich rocks and water-poor sand dunes on Mars in active neutron experiments

NASA Astrophysics Data System (ADS)

Gabriel, T. S. J.; Hardgrove, C.; Litvak, M. L.; Nowicki, S.; Mitrofanov, I. G.; Boynton, W. V.; Fedosov, F.; Golovin, D.; Jun, I.; Mischna, M.; Tate, C. G.; Moersch, J.; Harshman, K.; Kozyrev, A.; Malakhov, A. V.; Mokrousov, M.; Nikiforov, S.; Sanin, A. B.; Vostrukhin, A.; Thompson, L. M.

2017-12-01

The Dynamic Albedo of Neutrons (DAN) experiment on the Mars Science Laboratory Curiosity Rover delivers high-energy (14.1 MeV) pulses of neutrons into the surface when operating in "active" mode. Neutrons are moderated in the subsurface and return to two detectors to provide a time-of-flight profile in 64 time-bins in epithermal and thermal energy ranges. Results are compared to simulations of the experiment in the Monte Carlo N-Particle Transport Code where several aspects are modeled including the DAN detectors, neutron source, rover components, and underlying rock. Models can be improved by increasing the fidelity of the rock geochemistry as informed by instruments including the Alpha Particle X-Ray Spectrometer (APXS). Furthermore, increasing the fidelity of the rock morphology in models is enabled by the suite of imaging instruments on the rover.To rapidly interpret DAN data a set of pre-simulated generic rock density and bulk geochemistry models are compared to several DAN active observations. While, to first order, this methodology provides an indication of significant geochemical changes in the subsurface, higher-fidelity models should be used to provide accurate constraints on water content, depth of geologic layers, or abundance of neutron absorbers. For example, in high-silicon, low-iron rocks observed along the rover's traverse, generic models can differ by several wt%H2O from models that use APXS measurements of nearby drill samples. Accurate measurements of high-silicon targets are necessary in outlining the extent of aqueous alteration and hydrothermal activity in Gale Crater. Additionally, we find that for DAN active experiments over sand dunes best-fit models can differ by greater than 0.5 wt%HO when the upper layer density is reduced by 0.6 g/cm3 to account for the low-bulk density of sand. In areas where the rock geochemistry differs little from generic models the difference in results is expectedly less disparate. We report refined wt%HO values for high-silicon, aqueously-altered rock and comparatively dry sand dunes along the rover traverse. We also outline the methodology for providing accurate geochemical and morphological constraints using DAN active measurements.

Explosion Source Characteristics in Frozen and Unfrozen Rock

DTIC Science & Technology

2008-09-30

Alaska in August 2006 to provide empirical data on seismically -estimated yield from explosions it frozen rock Iaboratory studies have demonstrated that...can alter seismic yield. Central Alaska has abrupt lateral boundaries in discontinuous permafrost, and we detonated 3 shots in frozen, saturated rock...SUBJECT TERMS Seismic attenuation, Seismic propagation, Seismic characterization 16. SECURITY CLASSIFICATION OF: 17. LIMITATION 18. NUMBER 19a. NAME

Quarries of Culture: An Ethnohistorical and Environmental Account of Sacred Sites and Rock Formations in Southern California's Mission Indian Country

ERIC Educational Resources Information Center

Karr, Steven M.

2005-01-01

Sacred sites and Rock Formations throughout Southern California's India Country are described by Indians as ancestral markers, origin and place-name locales, areas of deity habitation, and power sources. Early ethnographers were keen to record the traditional stories and meanings related to them by their Native collaborators. Rock formations…

Source rock potential of middle cretaceous rocks in Southwestern Montana

USGS Publications Warehouse

Dyman, T.S.; Palacas, J.G.; Tysdal, R.G.; Perry, W.J.; Pawlewicz, M.J.

1996-01-01

The middle Cretaceous in southwestern Montana is composed of a marine and nonmarine succession of predominantly clastic rocks that were deposited along the western margin of the Western Interior Seaway. In places, middle Cretaceous rocks contain appreciable total organic carbon (TOC), such as 5.59% for the Mowry Shale and 8.11% for the Frontier Formation in the Madison Range. Most samples, however, exhibit less than 1.0% TOC. The genetic or hydrocarbon potential (S1+S2) of all the samples analyzed, except one, yield less than 1 mg HC/g rock, strongly indicating poor potential for generating commercial amounts of hydrocarbons. Out of 51 samples analyzed, only one (a Thermopolis Shale sample from the Snowcrest Range) showed a moderate petroleum potential of 3.1 mg HC/g rock. Most of the middle Cretaceous samples are thermally immature to marginally mature, with vitrinite reflectance ranging from about 0.4 to 0.6% Ro. Maturity is high in the Pioneer Mountains, where vitrinite reflectance averages 3.4% Ro, and at Big Sky Montana, where vitrinite reflectance averages 2.5% Ro. At both localities, high Ro values are due to local heat sources, such as the Pioneer batholith in the Pioneer Mountains.

Felsenkeller shallow-underground accelerator laboratory for nuclear astrophysics

NASA Astrophysics Data System (ADS)

Bemmerer, D.; Cowan, T. E.; Gohl, S.; Ilgner, C.; Junghans, A. R.; Reinhardt, T. P.; Rimarzig, B.; Reinicke, S.; Röder, M.; Schmidt, K.; Schwengner, R.; Stöckel, K.; Szücs, T.; Takács, M.; Wagner, A.; Wagner, L.; Zuber, K.

2015-05-01

Favored by the low background in underground laboratories, low-background accelerator-based experiments are an important tool to study nuclear reactions involving stable charged particles. This technique has been used for many years with great success at the 0.4 MV LUNA accelerator in the Gran Sasso laboratory in Italy, proteced from cosmic rays by 1400 m of rock. However, the nuclear reactions of helium and carbon burning and the neutron source reactions for the astrophysical s-process require higher beam energies than those available at LUNA. Also the study of solar fusion reactions necessitates new data at higher energies. As a result, in the present NuPECC long range plan for nuclear physics in Europe, the installation of one or more higher-energy underground accelerators is strongly recommended. An intercomparison exercise has been carried out using the same HPGe detector in a typical nuclear astrophysics setup at several sites, including the Dresden Felsenkeller underground laboratory. It was found that its rock overburden of 45m rock, together with an active veto against the remaining muon flux, reduces the background to a level that is similar to the deep underground scenario. Based on this finding, a used 5 MV pelletron tandem with 250 μA upcharge current and external sputter ion source has been obtained and transported to Dresden. Work on an additional radio-frequency ion source on the high voltage terminal is underway. The project is now fully funded. The installation of the accelerator in the Felsenkeller is expected for the near future. The status of the project and the planned access possibilities for external users will be reported.

Sulfur, carbon, hydrogen, and oxygen isotope geochemistry of the Idaho cobalt belt

USGS Publications Warehouse

Johnson, Craig A.; Bookstrom, Arthur A.; Slack, John F.

2012-01-01

Cobalt-copper ± gold deposits of the Idaho cobalt belt, including the deposits of the Blackbird district, have been analyzed for their sulfur, carbon, hydrogen, and oxygen isotope compositions to improve the understanding of ore formation. Previous genetic hypotheses have ranged widely, linking the ores to the sedimentary or diagenetic history of the host Mesoproterozoic sedimentary rocks, to Mesoproterozoic or Cretaceous magmatism, or to metamorphic shearing. The δ34S values are nearly uniform throughout the Blackbird dis- trict, with a mean value for cobaltite (CoAsS, the main cobalt mineral) of 8.0 ± 0.4‰ (n = 19). The data suggest that (1) sulfur was derived at least partly from sedimentary sources, (2) redox reactions involving sulfur were probably unimportant for ore deposition, and (3) the sulfur was probably transported to sites of ore for- mation as H2S. Hydrogen and oxygen isotope compositions of the ore-forming fluid, which are calculated from analyses of biotite-rich wall rocks and tourmaline, do not uniquely identify the source of the fluid; plausible sources include formation waters, metamorphic waters, and mixtures of magmatic and isotopically heavy meteoric waters. The calculated compositions are a poor match for the modified seawaters that form vol- canogenic massive sulfide (VMS) deposits. Carbon and oxygen isotope compositions of siderite, a mineral that is widespread, although sparse, at Blackbird, suggest formation from mixtures of sedimentary organic carbon and magmatic-metamorphic carbon. The isotopic compositions of calcite in alkaline dike rocks of uncertain age are consistent with a magmatic origin. Several lines of evidence suggest that siderite postdated the emplacement of cobalt and copper, so its significance for the ore-forming event is uncertain. From the stable isotope perspective, the mineral deposits of the Idaho cobalt belt contrast with typical VMS and sedimentary exhalative deposits. They show characteristics of deposit types that form in deeper environments and could be related to metamorphic processes or magmatic processes, although the isotopic evidence for magmatic components is relatively weak.

Chemistry and origin of Miocene and Eocene oils and tars in the onshore and offshore Santa Cruz Basins, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kornacki, A.S.; McNeil, R.I.

1996-12-31

The Santa Cruz (La Honda) Basin is a small {open_quote}slice{close_quote} of the San Joaquin Basin that has been displaced c. 300 km to the northwest by the San Andreas Fault. The poorly-explored offshore area that now lies within the Monterey Bay NMS includes portions of the Outer Santa Cruz and Bodega basins. A modest amount (c. 1.3 MM bbl) of variable-quality oil has been produced from Eocene and Pliocene pay zones in the La Honda Field. Much smaller amounts of light oil ({ge}40{degrees} API) have been produced from three other fields (Oil Creek; Moody Gulch; Half Moon Bay). Large tarmore » deposits also outcrop near the city of Santa Cruz. Proven source rocks in this basin include the Eocene Twobar Shale and three Miocene units: the Lambert Shale, Monterey Formation, and the Santa Cruz Mudstone. A high-gravity oil sample from the Oil Creek Field contains isotopically-light carbon ({delta}{sup 13}C = - 28.2 per mil) and has a relatively high pristane/phytane ratio. This oil was generated at high temperature (c. 140{degrees}C) by pre-Miocene source rocks (probably the Twobar Shale). The presence of isotopically-heavy carbon in all other oil and tar samples demonstrates they were generated by Miocene source rocks. But the C{sub 7} oil-generation temperatures, sulfur content, vanadium/nickel ratios, and biomarker chemistry of these Miocene oils are significantly different than in Monterey oils from the prolific Santa Maria Basin (SMB). The sulfur content (8.0 wt%) and V-Ni chemistry of tarry petroleum recovered in the P-036-1 well (Outer Santa Cruz Basin) resembles the chemistry of very heavy (<15{degrees}API) oils generated by phosphatic Monterey shales in the SMB.« less

Chemistry and origin of Miocene and Eocene oils and tars in the onshore and offshore Santa Cruz Basins, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kornacki, A.S.; McNeil, R.I.

1996-01-01

The Santa Cruz (La Honda) Basin is a small [open quote]slice[close quote] of the San Joaquin Basin that has been displaced c. 300 km to the northwest by the San Andreas Fault. The poorly-explored offshore area that now lies within the Monterey Bay NMS includes portions of the Outer Santa Cruz and Bodega basins. A modest amount (c. 1.3 MM bbl) of variable-quality oil has been produced from Eocene and Pliocene pay zones in the La Honda Field. Much smaller amounts of light oil ([ge]40[degrees] API) have been produced from three other fields (Oil Creek; Moody Gulch; Half Moon Bay).more » Large tar deposits also outcrop near the city of Santa Cruz. Proven source rocks in this basin include the Eocene Twobar Shale and three Miocene units: the Lambert Shale, Monterey Formation, and the Santa Cruz Mudstone. A high-gravity oil sample from the Oil Creek Field contains isotopically-light carbon ([delta][sup 13]C = - 28.2 per mil) and has a relatively high pristane/phytane ratio. This oil was generated at high temperature (c. 140[degrees]C) by pre-Miocene source rocks (probably the Twobar Shale). The presence of isotopically-heavy carbon in all other oil and tar samples demonstrates they were generated by Miocene source rocks. But the C[sub 7] oil-generation temperatures, sulfur content, vanadium/nickel ratios, and biomarker chemistry of these Miocene oils are significantly different than in Monterey oils from the prolific Santa Maria Basin (SMB). The sulfur content (8.0 wt%) and V-Ni chemistry of tarry petroleum recovered in the P-036-1 well (Outer Santa Cruz Basin) resembles the chemistry of very heavy (<15[degrees]API) oils generated by phosphatic Monterey shales in the SMB.« less

FracPaQ: A MATLAB™ toolbox for the quantification of fracture patterns

NASA Astrophysics Data System (ADS)

Healy, David; Rizzo, Roberto E.; Cornwell, David G.; Farrell, Natalie J. C.; Watkins, Hannah; Timms, Nick E.; Gomez-Rivas, Enrique; Smith, Michael

2017-02-01

The patterns of fractures in deformed rocks are rarely uniform or random. Fracture orientations, sizes, and spatial distributions often exhibit some kind of order. In detail, relationships may exist among the different fracture attributes, e.g. small fractures dominated by one orientation, larger fractures by another. These relationships are important because the mechanical (e.g. strength, anisotropy) and transport (e.g. fluids, heat) properties of rock depend on these fracture attributes and patterns. This paper describes FracPaQ, a new open source, cross-platform toolbox to quantify fracture patterns, including distributions in fracture attributes and their spatial variation. Software has been developed to quantify fracture patterns from 2-D digital images, such as thin section micrographs, geological maps, outcrop or aerial photographs or satellite images. The toolbox comprises a suite of MATLAB™ scripts based on previously published quantitative methods for the analysis of fracture attributes: orientations, lengths, intensity, density and connectivity. An estimate of permeability in 2-D is made using a parallel plate model. The software provides an objective and consistent methodology for quantifying fracture patterns and their variations in 2-D across a wide range of length scales, rock types and tectonic settings. The implemented methods presented are inherently scale independent, and a key task where applicable is analysing and integrating quantitative fracture pattern data from micro-to macro-scales. The toolbox was developed in MATLAB™ and the source code is publicly available on GitHub™ and the Mathworks™ FileExchange. The code runs on any computer with MATLAB installed, including PCs with Microsoft Windows, Apple Macs with Mac OS X, and machines running different flavours of Linux. The application, source code and sample input files are available in open repositories in the hope that other developers and researchers will optimise and extend the functionality for the benefit of the wider community.

Undiscovered petroleum resources for the Woodford Shale and Thirteen Finger Limestone-Atoka Shale assessment units, Anadarko Basin

USGS Publications Warehouse

Higley, Debra K.

2011-01-01

In 2010 the U.S. Geological Survey assessed undiscovered oil and gas resources for the Anadarko Basin Province of Colorado, Kansas, Oklahoma, and Texas. The assessment included three continuous (unconventional) assessment units (AU). Mean undiscovered resources for the (1) Devonian Woodford Shale Gas AU are about 16 trillion cubic feet of gas (TCFG) and 192 million barrels of natural gas liquids (MMBNGL), (2) Woodford Shale Oil AU are 393 million barrels of oil (MMBO), 2 TCFG, and 59 MMBNGL, and (3) Pennsylvanian Thirteen Finger Limestone-Atoka Shale Gas AU are 6.8 TCFG and 82 MMBNGL. The continuous gas AUs are mature for gas generation within the deep basin of Oklahoma and Texas. Gas generation from the Woodford Shale source rock started about 335 Ma, and from the Thirteen Finger Limestone-Atoka Shale AU about 300 Ma. Maturation results are based on vitrinite reflectance data, and on 1D and 4D petroleum system models that calculated vitrinite reflectance (Ro), and Rock-Eval and hydrous pyrolysis transformation (HP) ratios through time for petroleum source rocks. The Woodford Shale Gas AU boundary and sweet spot were defined mainly on (1) isopach thickness from well-log analysis and published sources; (2) estimated ultimate recoverable production from existing, mainly horizontal, wells; and (3) levels of thermal maturation. Measured and modeled Ro ranges from about 1.2% to 5% in the AU, which represents marginally mature to overmature for gas generation. The sweet spot included most of the Woodford that was deposited within eroded channels in the unconformably underlying Hunton Group. The Thirteen Finger Limestone-Atoka Shale Gas AU has no known production in the deep basin. This AU boundary is based primarily on the gas generation window, and on thickness and distribution of organic-rich facies from these mainly thin shale and limestone beds. Estimates of organic richness were based on well-log signatures and published data.

Origin and accumulation mechanisms of petroleum in the Carboniferous volcanic rocks of the Kebai Fault zone, Western Junggar Basin, China

NASA Astrophysics Data System (ADS)

Chen, Zhonghong; Zha, Ming; Liu, Keyu; Zhang, Yueqian; Yang, Disheng; Tang, Yong; Wu, Kongyou; Chen, Yong

2016-09-01

The Kebai Fault zone of the West Junggar Basin in northwestern China is a unique region to gain insights on the formation of large-scale petroleum reservoirs in volcanic rocks of the western Central Asian Orogenic Belt. Carboniferous volcanic rocks are widespread in the Kebai Fault zone and consist of basalt, basaltic andesite, andesite, tuff, volcanic breccia, sandy conglomerate and metamorphic rocks. The volcanic oil reservoirs are characterized by multiple sources and multi-stage charge and filling history, characteristic of a complex petroleum system. Geochemical analysis of the reservoir oil, hydrocarbon inclusions and source rocks associated with these volcanic rocks was conducted to better constrain the oil source, the petroleum filling history, and the dominant mechanisms controlling the petroleum accumulation. Reservoir oil geochemistry indicates that the oil contained in the Carboniferous volcanic rocks of the Kebai Fault zone is a mixture. The oil is primarily derived from the source rock of the Permian Fengcheng Formation (P1f), and secondarily from the Permian Lower Wuerhe Formation (P2w). Compared with the P2w source rock, P1f exhibits lower values of C19 TT/C23 TT, C19+20TT/ΣTT, Ts/(Ts + Tm) and ααα-20R sterane C27/C28 ratios but higher values of TT C23/C21, HHI, gammacerane/αβ C30 hopane, hopane (20S) C34/C33, C29ββ/(ββ + αα), and C29 20S/(20S + 20R) ratios. Three major stages of oil charge occurred in the Carboniferous, in the Middle Triassic, Late Triassic to Early Jurassic, and in the Middle Jurassic to Late Jurassic periods, respectively. Most of the oil charged during the first stage was lost, while moderately and highly mature oils were generated and accumulated during the second and third stages. Oil migration and accumulation in the large-scale stratigraphic reservoir was primarily controlled by the top Carboniferous unconformity with better porosity and high oil enrichment developed near the unconformity. Secondary dissolution pores and fractures are the two major reservoir storage-space types in the reservoirs. Structural highs and reservoirs near the unconformity are two favorable oil accumulation places. The recognition of the large-scale Carboniferous volcanic reservoirs in the Kebai Fault zone and understanding of the associated petroleum accumulation mechanisms provide new insights for exploring various types of volcanic reservoir plays in old volcanic provinces, and will undoubtedly encourage future oil and gas exploration of deeper strata in the region and basins elsewhere with similar settings.

Quantification of metal loads by tracer injection and synoptic sampling in Daisy Creek and the Stillwater River, Park County, Montana, August 1999

USGS Publications Warehouse

Nimick, David A.; Cleasby, Thomas E.

2001-01-01

A metal-loading study using tracer-injection and synoptic-sampling methods was conducted in Daisy Creek and a short reach of the Stillwater River during baseflow in August 1999 to quantify the metal inputs from acid rock drainage in the New World Mining District near Yellowstone National Park and to examine the downstream transport of these metals into the Stillwater River. Loads were calculated for many mainstem and inflow sites by combining streamflow determined using the tracer-injection method with concentrations of major ions and metals that were determined in synoptic water-quality samples. Water quality and aquatic habitat in Daisy Creek have been affected adversely by drainage derived from waste rock and adit discharge at the McLaren Mine as well as from natural weathering of pyrite-rich mineralized rock that comprises and surrounds the ore zones. However, the specific sources and transport pathways are not well understood. Knowledge of the main sources and transport pathways of metals and acid can aid resource managers in planning and conducting effective and cost-efficient remediation activities. The metals cadmium, copper, lead, and zinc occur at concentrations that are sufficiently elevated to be potentially lethal to aquatic life in Daisy Creek and to pose a toxicity risk in part of the Stillwater River. Copper is of most concern in Daisy Creek because it occurs at higher concentrations than the other metals. Acidic surface inflows had dissolved concentrations as high as 20.6 micrograms per liter (?g/L) cadmium, 26,900 ?g/L copper, 76.4 ?g/L lead, and 3,000 ?g/L zinc. These inflows resulted in maximum dissolved concentrations in Daisy Creek of 5.8 ?g/L cadmium, 5,790 ?g/L copper, 3.8 ?g/L lead, and 848 ?g/L zinc. Significant copper loading to Daisy Creek occurred only in the upper half of the stream. Sources included subsurface inflow and right-bank (mined side) surface inflows. Copper loads in left-bank (unmined side) surface inflows were negligible. Most (71 percent) of the total copper loading in the study reach occurred along a 341-foot reach near the stream?s headwaters. About 53 percent of the total copper load was contributed by five surface inflows that drain a manganese bog and the southern part of the McLaren Mine. Copper loading from subsurface inflow was substantial, contributing 46 percent of the total dissolved copper load to Daisy Creek. More than half of this subsurface copper loading occurred downstream from the reaches that received significant surface loading. Flow through the shallow subsurface appears to be the main copper-transport pathway from the McLaren Mine and surrounding altered and mineralized bedrock to Daisy Creek during base-flow conditions. Little is known about the source of acid and copper in this subsurface flow. However, possible sources include the mineralized rocks of Fisher Mountain upgradient of the McLaren Mine area, the surficial waste rock at the mine, and the underlying pyritic bedrock.

A review of silver-rich mineral deposits and their metallogeny

USGS Publications Warehouse

Graybeal, Frederick T.; Vikre, Peter

2010-01-01

Mineral deposits with large inventories or high grades of silver are found in four genetic groups: (1) volcanogenic massive sulfide (VMS), (2) sedimentary exhalative (SEDEX), (3) lithogene, and, (4) magmatichydrothermal. Principal differences between the four groups relate to source rocks and regions, metal associations, process and timing of mineralization, and tectonic setting. These four groups may be subdivided into specific metal associations on ternary diagrams based on relative metal contents. The VMS deposits rarely contain more than 15,600 t Ag (500 Moz). Grades average 33 g/t Ag. Variable Ag- Pb-Zn-Cu-Au ± Sn concentrations are interpreted as having been derived both from shallow plutons and by leaching of the volcanic rock pile in regions of thin or no continental crust and the mineralization is syngenetic. Higher silver grades are associated with areas of abundant felsic volcanic rocks. The SEDEX deposits rarely contain more than 15,600 t Ag (500 Moz). Grades average 46 g/t Ag. Silver, lead, and zinc in relatively consistent proportions are leached from sedimentary rocks filling rift-related basins, where the continental crust is thin, and deposited as syngenetic to diagenetic massive sulfides. Pre-mineral volcanic rocks and their detritus may occur deep within the basin and gold is typically absent. Lithogene silver-rich deposits are epigenetic products of varying combinations of compaction, dewatering, meteoric water recharge, and metamorphism of rift basin-related clastic sedimentary and interbedded volcanic rocks. Individual deposits may contain more than 15,600 t Ag (500 Moz) at high grades. Ores are characterized by four well-defined metal associations, including Ag, Ag-Pb-Zn, Ag-Cu, and Ag-Co-Ni-U. Leaching, transport, and deposition of metals may occur both in specific sedimentary strata and other rock types adjacent to the rift. Multiple mineralizing events lasting 10 to 15 m.y., separated by as much as 1 b.y., may occur in a single basin. Gold is absent at economic levels. The magmatic-hydrothermal silver-rich deposits are epigenetic and related to cordilleran igneous and volcanic suites. Six magmatic-hydrothermal districts each contain more than 31,000 t Ag (1,000 Moz) with grades of veins >600 g/t Ag. Mineralization occurs as veins, massive sulfides in carbonate rocks, and disseminated deposits including porphyry silver deposits, a proposed exploration model. Most deposits are epithermal with low-sulfidation alteration assemblages. Deposits are often telescoped and well-zoned. All large and high-grade magmatic-hydrothermal deposits appear confined to regions of relatively thick continental crust above Cenozoic consuming plate margins on the eastern side of the Pacific Rim. Silver in these deposits may be partly derived by hydrothermal leaching of rocks under or adjacent to the deposits.Specific metal associations in SEDEX and lithogene deposits may reflect confinement of fluid flow to and derivation of metals from specific source rock types. Variable metal associations in VMS and magmatichydrothermal deposits may reflect derivation of metals from a more diverse suite of rocks by convecting hydrothermal systems and processes related to the generation of magma. The discovery rate for silver-rich deposits has accelerated during the past decade, with new deposit types, metal associations, and exploration models being identified that provide numerous exploration and research opportunities.

A new petroleum system in offshore Campeche, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Limon, M.

1996-08-01

A new petroleum system in the Sonda de Campeche of Mexico has been recently defined. This system is entirely Oxfordian in age, comprising eolian and beach sandstone reservoirs overlain by evaporates, which provide the seal, and in turn, overlain by organically rich, low energy carbonate mudstones, which are source rocks. This petroleum system was created during the late stages of opening of the Gulf of Mexico. The source rocks are composed of an algal mudstone overlying the evaporite sequence. Geochemistry, isotopic and biomarkers analyses allowed us to identify the Oxfordian source rock and also to obtain an excellent correlation withmore » the Oxfordian oils reservoired in the discoveries. Oxfordian sandstones in the Sonda de Campeche exhibit excellent reservoir quality, ranging from 6 to 26% porosity and 2 to 2730 md permeability. The porosity is principally secondary due to the dissolution of dolomite, anhydrite and cement, but intergranular porosity can also be observed. The tectonic evolution of the Gulf of Mexico in the Sonda de Campeche produced three types of traps (1) faulted blocks of {open_quotes}domino{close_quotes} style, developed during the extensional stage; (2) faulted anticlines formed during the Middle Miocene compressive event; and (3) traps related to diapirism of salt of the Middle Miocene-Pleistocene. The seal rocks are mainly composed by Oxfordian evaporates. Oil generation was initiated in the Middle Miocene following the compressional stage. The potential source rocks reached maturity beneath a thick Tertiary overburden in downthrown fault blocks and expelled hydrocarbons which migrated in a predominantly vertical direction. The oils do not show any diagnostic evidence of bacterial alteration.« less

A new petroleum system in offshore Campeche, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gonzalez, R.; Cruz, P.; Limon, M.

1995-08-01

A new petroleum system in the Sonda de Campeche of Mexico has been recently defined. This system is entirely Oxfordian in age, comprising eolian and beach sandstone reservoirs overlain by evaporites, which provide the seal, and in turn, overlain by organically rich, low energy carbonate mudstones, which are source rocks. This petroleum system was created during the late stages of opening of the Gulf of Mexico. The source rocks are composed of an algal mudstone overlying the evaporite sequence. Geochemistry, isotopic and biomarkers analyses allowed us to identify the Oxfordian source rock and also to obtain an excellent correlation withmore » the oils Oxfordian reservoired in the discoveries. Oxfordian sandstones in the Sonda de Campeche exhibit excellent reservoir quality, ranging from 6 to 26% porosity and 2 to 2730 md permeability. The porosity is principally secondary due to the dissolution of dolomite anhydrite and cement but intergranular porosity can also be observed. The tectonic evolution of the Gulf of Mexico, in the Sonda de Campeche produced three types of traps (1) faulted blocks of {open_quotes}domino{close_quotes} style, developed during the extensional stage; (2) faulted anticlines formed during the Middle Miocene compressive event; and (3) traps related to diapirism of salt of the Middle Miocene-Pleistocene. The seal rocks are mainly composed by Oxfordian evaporates. Oil generation was initiated in the Middle Miocene following the compressional stage. The potential source rocks reached maturity beneath a thick Tertiary overburden in downthrown fault blocks and expelled hydrocarbons which migrated in a predominantly vertical direction. The oils do not show any diagnostic evidence of bacterial alteration.« less

Emplacement of rock avalanche material across saturated sediments, Southern Alp, New Zealand

NASA Astrophysics Data System (ADS)

Dufresne, A.; Davies, T. R.; McSaveney, M. J.

2012-04-01

The spreading of material from slope failure events is not only influenced by the volume and nature of the source material and the local topography, but also by the materials encountered in the runout path. In this study, evidence of complex interactions between rock avalanche and sedimentary runout path material were investigated at the 45 x 106 m3 long-runout (L: 4.8 km) Round Top rock avalanche deposit, New Zealand. It was sourced within myolinitic schists of the active strike-slip Alpine Fault. The narrow and in-failure-direction elongate source scarp is deep-seated, indicating slope failure was triggered by strong seismic activity. The most striking morphological deposit features are longitudinal ridges aligned radially to source. Trenching and geophysical surveys show bulldozed and sheared substrate material at ridge termini and laterally displaced sedimentary strata. The substrate failed at a minimum depth of 3 m indicating a ploughing motion of the ridges into the saturated material below. Internal avalanche compression features suggest deceleration behind the bulldozed substrate obstacle. Contorted fabric in material ahead of the ridge document substrate disruption by the overriding avalanche material deposited as the next down-motion hummock. Comparison with rock avalanches of similar volume but different emplacement environments places Round Top between longer runout avalanches emplaced over e.g. playa lake sediments and those with shorter travel distances, whose runout was apparently retarded by topographic obstacles or that entrained high-friction debris. These empirical observations indicate the importance of runout path materials on tentative trends in rock avalanche emplacement dynamics and runout behaviour.

Depositional environment and distribution of Late Cretaceous [open quotes]source rocks[close quotes] from Costa Rica to West Africa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erlich, R.N.; Sofer, Z.; Pratt, L.M.

1993-02-01

Late Cretaceous [open quotes]source rocks[close quotes] from Costa Rica, western and eastern Venezuela, and Trinidad were studied using organic and inorganic geochemistry, biostratigraphy, and sedimentology in order to determine their depositional environments. Bulk mineralogy and major element geochemistry for 304 samples were combined with Rock Eval data and extract biomaker analysis to infer the types and distributions of the various Late Cretaceous productivity systems represented in the dataset. When data from this study are combined with published and proprietary data from offshore West Africa, Guyana/Suriname, and the central Caribbean, they show that these Late Cretaceous units can be correlated bymore » their biogeochemical characteristics to establish their temporal and spatial relationships. Paleogeographic maps constructed for the early to late Cenomanian, Turonian, Coniacian to middle Santonian, and late Santonian to latest Campanian show that upwelling and excessive fluvial runoff were probably the dominant sources of nutrient supply to the coastal productivity systems. The late Santonian to Maastrichtian rocks examined in this study indicate that organic material was poorly preserved after deposition, even though biologic productivity remained constant or changed only slightly. A rapid influx of oxygenated bottom water may have occurred following the opening of a deep water connection between the North and South Atlantic oceans, and/or separation of India from Africa and the establishment of an Antarctic oceanic connection. This study suggests that the most important factors that controlled source rock quality in northern South America were productivity, preservation, degree of clastic dilution, and subsurface diagenesis.« less

Cumberland batholith, Trans-Hudson Orogen, Canada: Petrogenesis and implications for Paleoproterozoic crustal and orogenic processes

NASA Astrophysics Data System (ADS)

Whalen, Joseph B.; Wodicka, Natasha; Taylor, Bruce E.; Jackson, Garth D.

2010-06-01

Large volume, plutonic belts, such as the ˜ 221,000 km 2, ca. 1.865-1.845 Ga Cumberland batholith (CB) of the Trans-Hudson Orogen in Canada, are major components of Paleoproterozoic orogenic belts. In many cases, they have been interpreted as continental arc batholiths. The petrogenesis and tectonic context of the CB and implications for crustal growth and recycling are interpreted herein based on a 900 km geochemical-isotopic (Nd-O) transect across it and into granitoid plutons within bounding Archean cratons in central and southern Baffin Island. The mainly granulite grade CB, emplaced over an age span of between 14 and 24 Ma, consists mainly of high-K to shoshonitic monzogranite and granodiorite, but also includes low- and medium-K granitoid rocks. Metaluminous to slightly peraluminous compositions and δ 18O (VSMOW) values (+ 6 to + 10‰) indicate derivation from infracrustal (I-type) sources. ɛ Nd 1.85 Ga signatures (- 12 to - 2) of both mafic and felsic units suggest a dominance of evolved sources. Isotopic signatures in the interior of the CB (- 2 to - 7) are more radiogenic than those within Archean domains in central (- 8 to - 15) and southern (- 5 to - 19) Baffin Island. The isotopic transect is interpreted as 'imaging' an accreted microcontinental block (Meta Incognita) and bounding Archean cratons. The CB includes granites of arc, within-plate (A-type) and post-collisional affinity and volumetrically minor mafic rocks with both arc and non-arc features. (La/Yb) CN and Sr/Y values range from < 1 to 225 and < 1 to 611, respectively. In these respects, some CB granitoid rocks resemble Paleozoic adakitic granites, interpreted as partial melts of greatly thickened crust within post-collisional settings, such as Tibet. Thus, the CB likely encompasses various non-consanguineous magmatic suites generated at deep- to mid-crustal depths. Although CB granitoid rocks undoubtedly had important crustal sources, it is hard to assess the relative contribution of mantle-derived magmas. The CB is best interpreted as a post-accretion batholith resulting from large-scale lithospheric mantle delamination followed by the upwelling of hot asthenospheric mantle leading to voluminous crustal partial melting. Contributors to crustal instability which may have facilitated such delamination included: (a) a collage of recently assembled small cratons underlain by hot, weak lithosphere with mantle-depth structural breaks within this segment of the Trans-Hudson Orogen; (b) the gabbro-eclogite phase transformation, and (c) a greatly thickened crustal section (> 60 km), as evidenced by adakitic granites.

Image analysis for quantification of bacterial rock weathering.

PubMed

Puente, M Esther; Rodriguez-Jaramillo, M Carmen; Li, Ching Y; Bashan, Yoav

2006-02-01

A fast, quantitative image analysis technique was developed to assess potential rock weathering by bacteria. The technique is based on reduction in the surface area of rock particles and counting the relative increase in the number of small particles in ground rock slurries. This was done by recording changes in ground rock samples with an electronic image analyzing process. The slurries were previously amended with three carbon sources, ground to a uniform particle size and incubated with rock weathering bacteria for 28 days. The technique was developed and tested, using two rock-weathering bacteria Pseudomonas putida R-20 and Azospirillum brasilense Cd on marble, granite, apatite, quartz, limestone, and volcanic rock as substrates. The image analyzer processed large number of particles (10(7)-10(8) per sample), so that the weathering capacity of bacteria can be detected.

Sequence and petrogenesis of the Jurassic volcanic rocks (Yeba Formation) in the Gangdese arc, southern Tibet: Implications for the Neo-Tethyan subduction

NASA Astrophysics Data System (ADS)

Liu, Zhi-Chao; Ding, Lin; Zhang, Li-Yun; Wang, Chao; Qiu, Zhi-Li; Wang, Jian-Gang; Shen, Xiao-Li; Deng, Xiao-Qin

2018-07-01

The Yeba Formation volcanic rocks in the Gangdese arc recorded important information regarding the early history of the Neo-Tethyan subduction. To explore their magmatic evolution and tectonic significance, we performed a systematic petrological, geochronological and geochemical study on these volcanic rocks. Our data indicated that the Yeba Formation documents a transition from andesite-dominated volcanism (which started before 182 Ma and continued until 176 Ma) to bimodal volcanism ( 174-168 Ma) in the earliest Middle Jurassic. The early-stage andesite-dominated volcanics are characterized by various features of major and trace elements and are interpreted as the products of interactions between mantle-derived arc magmas and lower crustal melts. Their positive εNd(t) and εHf(t) values suggest a significant contribution of asthenosphere-like mantle. The late-stage bimodal volcanism is dominated by felsic rocks with subordinate basalts. Geochemical signatures of the basalts indicate a composite magma source that included a "subduction component", an asthenosphere-like upper mantle domain and an ancient subcontinental lithospheric mantle component. The felsic rocks of the late stage were produced mainly by the melting of juvenile crust, with some ancient crustal materials also involved. We suggest that the occurrence and preservation of the Yeba Formation volcanic rocks were tied to a tectonic switch from contraction to extension in the Gangdese arc, which probably resulted from slab rollback of the subducting Neo-Tethyan oceanic slab during the Jurassic.

Geologically Controlled Isotope-Time Patterns Reveal Early Differentiation and Crust Formation Processes

NASA Astrophysics Data System (ADS)

Bennett, V. C.; Nutman, A. P.

2014-12-01

The mechanisms of continental crust production and evolution in the early Earth remain controversial, as are questions of the relative roles of early differentiation versus subsequent tectonic procssing in creating Earth's chemical signatures. Here we present geologic observations integrated with whole rock major, trace element and Sm-Nd isotopic signatures and combined with U-Pb and Lu-Hf isotopic compositions of zircon populations from the same rocks, from the most extensive early rock record comprising the 3.9 Ga to 3.6 Ga terranes of southwest Greenland. These data reveal repeated patterns of formation of juvenile TTG crust and associated mafic and ultramafic rocks in convergent margin settings followed by formation of more evolved granites [1]. Our new zircon Lu-Hf data from rare 3.6-3.7 Ga tonalites within the Itsaq Gneiss Complex, obtained from single component, non-migmatitic gneisses with simple zircon populations, limited within sample Hf isotopic variability and accurate U-Pb ages, now document extraction of juvenile tonalites from a near chondritic mantle source between 3.9 Ga and 3.6 Ga. The more evolved, granitic rocks in each area show slightly negative initial ɛHf in accord with crustal reworking of the older (3.8-3.9 Ga) gniesses. There is no evidence for Hadean material in the sources of the granitoids. The Hf isotope-time patterns are consistent with juvenile crust production from a mantle source that experienced only modest amounts of prior crustal extraction. They are distinct from those predicted by reprocessing of an enriched Hadean mafic crust, as has been proposed for this region [2] and for the source of the Hadean Jack Hills zircons [3]. The well-documented, time decreasing, positive 142Nd anomalies [e.g., 4] from these rocks are further evidence of crustal derivation from a convecting mantle source, rather than reworking of an enriched mafic lithosphere. The 143Nd isotopic -time patterns are more complex, reflecting the interplay between early Sm/Nd fractionation processes as required by the 142Nd data, juvenile crustal growth and in some cases geologic disturbance of the whole rock Sm-Nd system. [1] Nutman, et al, (2013) Amer. Jour. Sci. 313, 877-911. [2] Naeraa et al.. (2012) Nature 485, 627-631. [3] Kemp et al., (2010) EPSL 296, 45-56. [4] Bennett et al., (20070 Science 318, 1907.

Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin

USGS Publications Warehouse

Lewan, M.D.; Henry, M.E.; Higley, D.K.; Pitman, Janet K.

2002-01-01

The New Albany-Chesterian petroleum system of the Illinois basin is a well-constrained system from which petroleum charges and losses were quantified through a material-balance assessment. This petroleum system has nearly 90,000 wells penetrating the Chesterian section, a single New Albany Shale source rock accounting for more than 99% of the produced oil, well-established stratigraphic and structural frameworks, and accessible source rock samples at various maturity levels. A hydrogen index (HI) map based on Rock-Eval analyses of source rock samples of New Albany Shale defines the pod of active source rock and extent of oil generation. Based on a buoyancy-drive model, the system was divided into seven secondary-migration catchments. Each catchment contains a part of the active pod of source rock from which it derives a petroleum charge, and this charge is confined to carrier beds and reservoirs within these catchments as accountable petroleum, petroleum losses, or undiscovered petroleum. A well-constrained catchment with no apparent erosional or leakage losses is used to determine an actual petroleum charge from accountable petroleum and residual migration losses. This actual petroleum charge is used to calibrate the other catchments in which erosional petroleum losses have occurred. Petroleum charges determined by laboratory pyrolysis are exaggerated relative to the actual petroleum charge. Rock-Eval charges are exaggerated by a factor of 4-14, and hydrouspyrolysis charges are exaggerated by a factor of 1.7. The actual petroleum charge provides a more meaningful material balance and more realistic estimates of petroleum losses and remaining undiscovered petroleum. The total petroleum charge determined for the New Albany-Chesterian system is 78 billion bbl, of which 11.4 billion bbl occur as a accountable in place petroleum, 9 billion bbl occur as residual migration losses, and 57.6 billion bbl occur as erosional losses. Of the erosional losses, 40 billion bbl were lost from two catchments that have highly faulted and extensively eroded sections. Anomalies in the relationship between erosional losses and degree of erosion suggest there is potential for undiscovered petroleum in one of the catchments. These results demonstrate that a material-balance assessment of migration catchments provides a useful means to evaluate and rank areas within a petroleum system. The article provides methodologies for obtaining more realistic petroleum charges and losses that can be applied to less data-rich petroleum systems.

Organic geochemistry and petrology of oil source rocks, Carpathian Overthrust region, southeastern Poland - Implications for petroleum generation

USGS Publications Warehouse

Kruge, M.A.; Mastalerz, Maria; Solecki, A.; Stankiewicz, B.A.

1996-01-01

The organic mailer rich Oligocene Menilite black shales and mudstones are widely distributed in the Carpathian Overthrust region of southeastern Poland and have excellent hydrocarbon generation potential, according to TOC, Rock-Eval, and petrographic data. Extractable organic matter was characterized by an equable distribution of steranes by carbon number, by varying amounts of 28,30-dinor-hopane, 18??(H)-oleanane and by a distinctive group of C24 ring-A degraded triterpanes. The Menilite samples ranged in maturity from pre-generative to mid-oil window levels, with the most mature in the southeastern portion of the study area. Carpathian petroleum samples from Campanian Oligocene sandstone reservoirs were similar in biomarker composition to the Menilite rock extracts. Similarities in aliphatic and aromatic hydrocarbon distributions between petroleum asphaltene and source rock pyrolyzates provided further evidence genetically linking Menilite kerogens with Carpathian oils.

Mountain glaciation drives rapid oxidation of rock-bound organic carbon

PubMed Central

Horan, Kate; Hilton, Robert G.; Selby, David; Ottley, Chris J.; Gröcke, Darren R.; Hicks, Murray; Burton, Kevin W.

2017-01-01

Over millions of years, the oxidation of organic carbon contained within sedimentary rocks is one of the main sources of carbon dioxide to the atmosphere, yet the controls on this emission remain poorly constrained. We use rhenium to track the oxidation of rock-bound organic carbon in the mountain watersheds of New Zealand, where high rates of physical erosion expose rocks to chemical weathering. Oxidative weathering fluxes are two to three times higher in watersheds dominated by valley glaciers and exposed to frost shattering processes, compared to those with less glacial cover; a feature that we also observe in mountain watersheds globally. Consequently, we show that mountain glaciation can result in an atmospheric carbon dioxide source during weathering and erosion, as fresh minerals are exposed for weathering in an environment with high oxygen availability. This provides a counter mechanism against global cooling over geological time scales. PMID:28983510

Sedimentary Processes on Earth, Mars, Titan, and Venus

NASA Astrophysics Data System (ADS)

Grotzinger, J. P.; Hayes, A. G.; Lamb, M. P.; McLennan, S. M.

The production, transport and deposition of sediment occur to varying degrees on Earth, Mars, Venus, and Titan. These sedimentary processes are significantly influenced by climate that affects production of sediment in source regions (weathering), and the mode by which that sediment is transported (wind vs. water). Other, more geological, factors determine where sediments are deposited (topography and tectonics). Fluvial and marine processes dominate Earth both today and in its geologic past, aeolian processes dominate modern Mars although in its past fluvial processes also were important, Venus knows only aeolian processes, and Titan shows evidence of both fluvial and aeolian processes. Earth and Mars also feature vast deposits of sedimentary rocks, spanning billions of years of planetary history. These ancient rocks preserve the long-term record of the evolution of surface environments, including variations in climate state. On Mars, sedimentary rocks record the transition from wetter, neutral-pH weathering, to brine-dominated low-pH weathering, to its dry current state.

A science plan for a comprehensive assessment of water supply in the region underlain by fractured rock in Maryland

USGS Publications Warehouse

Fleming, Brandon J.; Hammond, Patrick A.; Stranko, Scott A.; Duigon, Mark T.; Kasraei, Saeid

2012-01-01

The fractured rock region of Maryland, which includes land areas north and west of the Interstate 95 corridor, is the source of water supply for approximately 4.4 million Marylanders, or approximately 76 percent of the State's population. Whereas hundreds of thousands of residents rely on wells (both domestic and community), millions rely on surface-water sources. In this region, land use, geology, topography, water withdrawals, impoundments, and other factors affect water-flow characteristics. The unconfined groundwater systems are closely interconnected with rivers and streams, and are affected by seasonal and climatic variations. During droughts, groundwater levels drop, thereby decreasing well yields, and in some cases, wells have gone dry. Low ground-water levels contribute to reduced streamflows, which in turn, can lead to reduced habitat for aquatic life. Increased demand, over-allocation, population growth, and climate change can affect the future sustainability of water supplies in the region of Maryland underlain by fractured rock. In response to recommendations of the 2008 Advisory Committee on the Management and Protection of the State's Water Resources report, the Maryland Department of the Environment's Water Supply Program, the Maryland Geological Survey, the Maryland Department of Natural Resources, Monitoring and Non-Tidal Assessment (MANTA) Division, and the U.S. Geological Survey have developed a science plan for a comprehensive assessment that will provide new scientific information, new data analysis, and new tools for the State to better manage water resources in the fractured rock region of Maryland. The science plan lays out five goals for the comprehensive assessment: (1) develop tools for the improved management and investigation of groundwater and surface-water resources; (2) characterize factors affecting reliable yields of individual groundwater and surface-water supplies; (3) investigate impacts on nearby water withdrawal users caused by groundwater and surface-water withdrawals; (4) assess the role of streamflow and water withdrawals on the ecological integrity of streams; and (5) improve understanding of the distribution of water-quality conditions in fractured rock aquifers. To accomplish these goals, accurate data collection, review, and analysis are needed, including the study of "Research Watersheds" that can provide detailed information about the potential effects that climate change and water withdrawals may have on groundwater, streamflow, and aquatic life. The assessment planning started in 2009 and is being conducted with close interagency coordination. A Fractured Rock Aquifer Information System is currently (2012) undergoing initial development. Other major tasks that will be performed include the development of work plans for each science goal, the estimation of daily streamflow at ungaged streams, and the design and implementation of Research Watersheds. Finally, scenarios will be modeled to evaluate current water allocation permitting methodologies, investigate effects on nearby water withdrawal users caused by groundwater and surface-water withdrawals, and assess the potential impacts of climate change on water resources. Desktop and Web-based tools will be developed in order to meet the diverse research needs of the assessment. These tools, including the Fractured Rock Aquifer Information System will be continuously improved during the assessment to store relevant groundwater and surface-water data in spatially referenced databases, estimate streamflows, locate higher-yielding wells, estimate the impacts of withdrawals on nearby users, and assess the cumulative impacts of withdrawals on the aquatic resource. Tools will be developed to serve the needs of many audiences, including water resource managers, water suppliers, planners, policymakers, and other scientific investigators.

Popping Rocks Revealed: Investigations from 14°N on the Mid-Atlantic Ridge

NASA Astrophysics Data System (ADS)

Wanless, V. D.; Jones, M.; Kurz, M. D.; Soule, S. A.; Fornari, D. J.; Bendana, S.; Mittelstaedt, E. L.

2017-12-01

The popping rock, recovered in dredge 2πD43 in 1985, is commonly considered to be one of the most representative samples of undegassed upper mantle, based on high volatile and noble gas abundances. While this basalt is used to reconstruct mantle volatile contents and CO2 fluxes from mid-ocean ridges (MOR), the origin of the popping rock has remained ambiguous due to a lack of geologic context. Here, we present results from the first combined geochemical, geophysical, and geologic investigation of popping rocks from 14N on the Mid-Atlantic Ridge. By combining lava compositions with high-resolution bathymetric maps, we show that the popping rocks are confined to a single geographic area, at the transition between magmatic and tectonic segments. Fifteen popping rocks were collected in situ using the Alvin submersible in 2016. X-ray microtomography indicates that these lavas have variable vesicle abundances; including the highest vesicularities (>19%) recorded for any MOR basalt. Dissolved CO2 contents (163-175 ppm) are similar to proximal non-popping rocks and are in equilibrium at their eruption depths (>3600 m); however, total CO2 contents (based on vesicularity, dissolved CO2, and vesicle gas contents) are higher than non-popping rocks, ranging from 2800-14150 ppm. The popping rocks have average 3He/4He ratios of 8.17 ± 0.1 Ra and 4He concentrations of 1.84e-5 to 7.67e-5 cc/g STP. Compared to non-popping lavas, the popping rocks have a narrow range of major and trace element concentrations, suggesting little to no crystallization occurred during ascent or eruption. REE patterns and trace element ratios are indistinguishable in the popping rocks (La/Sm = 2.89 ± 0.05), indicating similar mantle sources and extents of melting. Based on lava compositions and spatial distribution, we suggest that the popping rocks at 14N were produced under similar magmatic conditions and erupted over short timescales, perhaps during a series of closely timed eruptions.

Petroleum systems of the Northwest Java Province, Java and offshore southeast Sumatra, Indonesia

USGS Publications Warehouse

Bishop, Michele G.

2000-01-01

Mature, synrift lacustrine shales of Eocene to Oligocene age and mature, late-rift coals and coaly shales of Oligocene to Miocene age are source rocks for oil and gas in two important petroleum systems of the onshore and offshore areas of the Northwest Java Basin. Biogenic gas and carbonate-sourced gas have also been identified. These hydrocarbons are trapped primarily in anticlines and fault blocks involving sandstone and carbonate reservoirs. These source rocks and reservoir rocks were deposited in a complex of Tertiary rift basins formed from single or multiple half-grabens on the south edge of the Sunda Shelf plate. The overall transgressive succession was punctuated by clastic input from the exposed Sunda Shelf and marine transgressions from the south. The Northwest Java province may contain more than 2 billion barrels of oil equivalent in addition to the 10 billion barrels of oil equivalent already identified.

Three ancient Montana fluvial systems: Pennsylvanian Tyler, Lower Cretaceous Muddy, and Upper Cretaceous Eagle - their reservoir and source rock distribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shepard, B.

The importance of using Holocene geology as a model in mapping reservoir and source rock distribution is demonstrated in three Montana river-related systems: alluvial valley, barrier bar, and distributary channel-prodelta. The Pennsylvanian Tyler Formation was deposited by a westward-flowing meandering-stream system controlled by an east-west-trending rift valley, and surrounded by backswamp deposits. It is underlain by its probable hydrocarbon source, the marine Mississippian Heath shale and limestone, and overlain locally by the lagoonal Pennsylvanian Bear Gulch Limestone. To date, about 90 million bbl of recoverable oil have been found in Tyler sands. The oil-producing Lower Cretaceous Muddy sandstones in themore » northern Powder River basin are considered to be barrier bars, encased in organic-rich shales, which are most probably the source rock. The Upper Cretaceous Eagle Sandstone in north-central Montana is a distributary channel system, similar to that of the modern Mississippi, which dumped highly carbonaceous materials into an organic-rich delta system. The Eagle now contains possibly enormous amounts of biogenic methane. By using Galveston Island and the modern Mississippi delta as models, in conjunction with employing electric log shapes and porosity logs, it is possible to map ancient fluvial patterns in the study areas. One can then predict the location of possible hydrocarbon accumulations in porous and permeable sand bodies, along with their encasing hydrocarbon source rocks.« less

Petrogenesis of ore-bearing porphyry in non-subduction setting: a case study of the Eocene potassic intrusions in the western Yangtze Block

NASA Astrophysics Data System (ADS)

Liu, Zheng; Liao, Shi-Yong; Zhou, Qing; Zhang, Xin

2018-05-01

In the western Yangtze Block, abundant Eocene ( 38-34 Ma) potassic adakite-like intrusions and associated porphyry copper deposits are exposed in non-subduction setting, including Machangjing, Beiya, Binchuan, Habo and Tongchang intrusions. All these ore-bearing porphyries share many geochemical characteristics of adakite such as depletion in heavy rare earth elements (HREEs), enrichment in Sr and Ba, absence of negative Eu anomalies, high SiO2, Al2O3, Sr/Y, La/Yb and low Y, Yb contents. They also exhibit affinities of potassic rocks, e.g., alkali-rich, high K2O/Na2O ratios and enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs). Their Sr-Nd isotopic ratios are similar to coeval shoshonitic lamprophyres. Geochemical data indicate that they were probably produced by partial melting of newly underplated potassic rocks sourced from a modified and enriched lithospheric mantle. These underplated rocks have elevated oxygen fugacity, water and copper contents, with high metallogenic potential. We propose that all the studied potassic rocks were emplaced in a post-collisional setting, associated with the local removal of lithospheric mantle.

Analysis of Shublik Formation rocks from Mt. Michelson quadrangle, Alaska

USGS Publications Warehouse

Detterman, Robert L.

1970-01-01

Analysis of 88 samples from the Shublik formation on Fire Creek, Mt. Michelson Quadrangle, Alaska, are presented in tabular form. The results include the determination of elements by semiquantitative spectrographic analysis, phosphate by X-ray fluorescence, carbon dioxide by acid decomposable carbonate, total carbon by induction furnace, carbonate carbon by conversion using the conversion factor of 0.2727 for amount of carbon in carbon dioxide, and organic carbon by difference. A seven- cycle semilogarithmic chart presents the data graphically and illustrates the range, mode, and mean for some of the elements. The chart shows, also, the approximate concentration of the same elements in rocks similar to the black shale and limestone of the Shublik Formation. Each sample represents 5 feet of section and is composed of rock chips taken at 1 - foot intervals. The samples are keyed into a stratigraphic column of the formation. Rocks of the Shublik Formation contain anomalously high concentrations of some of the elements. These same elements might be expected to be high in some of the petroleum from northern Alaska if the Shublik Formation is a source for this petroleum. Several of the stratigraphic intervals may represent, also, a low-grade phosphate deposit.

Geochemistry, Nd-Pb Isotopes, and Pb-Pb Ages of the Mesoproterozoic Pea Ridge Iron Oxide-Apatite–Rare Earth Element Deposit, Southeast Missouri

USGS Publications Warehouse

Ayuso, Robert A.; Slack, John F.; Day, Warren C.; McCafferty, Anne E.

2016-01-01

Iron oxide-apatite and iron oxide-copper-gold deposits occur within ~1.48 to 1.47 Ga volcanic rocks of the St. Francois Mountains terrane near a regional boundary separating crustal blocks having contrasting depleted-mantle Sm-Nd model ages (TDM). Major and trace element analyses and Nd and Pb isotope data were obtained to characterize the Pea Ridge deposit, improve identification of exploration targets, and better understand the regional distribution of mineralization with respect to crustal blocks. The Pea Ridge deposit is spatially associated with felsic volcanic rocks and plutons. Mafic to intermediate-composition rocks are volumetrically minor. Data for major element variations are commonly scattered and strongly suggest element mobility. Ratios of relatively immobile elements indicate that the felsic rocks are evolved subalkaline dacite and rhyolite; the mafic rocks are basalt to basaltic andesite. Granites and rhyolites display geochemical features typical of rocks produced by subduction. Rare earth element (REE) variations for the rhyolites are diagnostic of rocks affected by hydrothermal alteration and associated REE mineralization. The magnetite-rich rocks and REE-rich breccias show similar REE and mantle-normalized trace element patterns.Nd isotope compositions (age corrected) show that: (1) host rhyolites have ɛNd from 3.44 to 4.25 and TDM from 1.51 to 1.59 Ga; (2) magnetite ore and specular hematite rocks display ɛNd from 3.04 to 4.21 and TDM from 1.6 to 1.51 Ga, and ɛNd from 2.23 to 2.81, respectively; (3) REE-rich breccias have ɛNd from 3.04 to 4.11 and TDM from 1.6 to 1.51 Ga; and (4) mafic to intermediate-composition rocks range in ɛNd from 2.35 to 3.66 and in TDM from 1.66 to 1.56. The ɛNd values of the magnetite and specular hematite samples show that the REE mineralization is magmatic; no evidence exists for major overprinting by younger, crustal meteoric fluids, or by externally derived Nd. Host rocks, breccias, and magnetite ore shared a common origin from a similar source.Lead isotope ratios are diverse: (1) host rhyolite has 206Pb/204Pb from 24.261 to 50.091; (2) Pea Ridge and regional galenas have 206Pb/204Pb from 16.030 to 33.548; (3) REE-rich breccia, magnetite ore, and specular hematite rock are more radiogenic than galena; (4) REE-rich breccias have high 206Pb/204Pb (38.122–1277.61) compared to host rhyolites; and (5) REE-rich breccias are more radiogenic than magnetite ore and specular-hematite rock, having 206Pb/204Pb up to 230.65. Radiogenic 207Pb/206Pb age estimates suggest the following: (1) rhyolitic host rocks have ages of ~1.50 Ga, (2) magnetite ore is ~1.44 Ga, and (3) REE-rich breccias are ~1.48 Ga. These estimates are broadly consistent and genetically link the host rhyolite, REE-rich breccia, and magnetite ore as being contemporaneous.Alteration style and mineralogical or textural distinctions among the magnetite-rich rocks and REE-rich breccias do not correlate with different isotopic sources. In our model, magmatic fluids leached metals from the coeval felsic rocks (rhyolites), which provided the metal source reflected in the compositions of the REE-rich breccias and mineralized rocks. This model allows for the likelihood of contributions from other genetically related felsic and intermediate to more mafic rocks stored deeper in the crust. The deposit thus records an origin as a magmatic-hydrothermal system that was not affected by Nd and Pb remobilization processes, particularly if these processes also triggered mixing with externally sourced metal-bearing fluids. The Pea Ridge deposit was part of a single, widespread, homogeneous mixing system that produced a uniform isotopic composition, thus representing an excellent example of an igneous-dominated system that generated coeval magmatism and REE mineralization. Geochemical features suggest that components in the Pea Ridge deposit originated from sources in an orogenic margin. Basaltic magmatism produced by mantle decompression melting provided heat for extracting melts from the middle or lower crust. Continual addition of mafic magmas to the base of the subcontinental lithosphere, in a back-arc setting, remelted calc-alkaline rocks enriched in metals that were stored in the crust.The St. Francois Mountains terrane is adjacent to the regional TDM line (defined at a value of 1.55 Ga) that separates ~1600 Ma basement to the west, from younger basements to the east. Data for Pea Ridge straddle the TDM values proposed for the line. The Sm-Nd isotope system has been closed since formation of the deposit and the original igneous signatures have not been affected by cycles of alteration or superimposed mineralizing events. No evidence exists for externally derived Nd or Sm. The source region for metals within the Pea Ridge deposit had a moderate compositional variation and the REE-rich breccias and mineralized rocks are generally isotopically homogeneous. The Pea Ridge deposit thus constitutes a distinctive isotopic target for use as a model in identifying other mineralized systems that may share the same metal source in the St. Francois Mountains terrane and elsewhere in the eastern Granite-Rhyolite province.

Geology and total petroleum systems of the West-Central Coastal province (7203), West Africa

USGS Publications Warehouse

Brownfield, Michael E.; Charpentier, Ronald R.

2006-01-01

The West-Central Coastal Province of the Sub-Saharan Africa Region consists of the coastal and offshore areas of Cameroon, Equatorial Guinea, Gabon, Democratic Republic of the Congo, Republic of the Congo, Angola (including the disputed Cabinda Province), and Namibia. The area stretches from the east edge of the Niger Delta south to the Walvis Ridge. The West-Central Coastal Province includes the Douala, Kribi-Campo, Rio Muni, Gabon, Congo, Kwanza, Benguela, and Namibe Basins, which together form the Aptian salt basin of equatorial west Africa. The area has had significant exploration for petroleum; more than 295 oil fields have been discovered since 1954. Since 1995, several giant oil fields have been discovered, especially in the deep-water area of the Congo Basin. Although many total petroleum systems may exist in the West-Central Coastal Province, only four major total petroleum systems have been defined. The area of the province north of the Congo Basin contains two total petroleum systems: the Melania-Gamba Total Petroleum System, consisting of Lower Cretaceous source and reservoir rocks, and the Azile-Senonian Total Petroleum System, consisting of Albian to Turonian source rocks and Cretaceous reservoir rocks. Two assessment units are defined in the West-Central Coastal Province north of the Congo Basin: the Gabon Subsalt and the Gabon Suprasalt Assessment Units. The Congo Basin contains the Congo Delta Composite Total Petroleum System, consisting of Lower Cretaceous to Tertiary source and reservoir rocks. The Central Congo Delta and Carbonate Platform and the Central Congo Turbidites Assessment Units are defined in the Congo Delta Composite Total Petroleum System. The area south of the Congo Basin contains the Cuanza Composite Total Petroleum System, consisting of Lower Cretaceous to Tertiary source and reservoir rocks. The Cuanza-Namibe Assessment Unit is defined in the Cuanza Composite Total Petroleum System. The U.S. Geological Survey (USGS) assessed the potential for undiscovered conventional oil and gas resources in this province as part of its World Petroleum Assessment 2000. The USGS estimated a mean of 29.7 billion barrels of undiscovered conventional oil, 88.0 trillion cubic feet of gas, and 4.2 billion barrels of natural gas liquids. Most of the hydrocarbon potential remains in the offshore waters of the province in the Central Congo Turbidites Assessment Unit. Large areas of the offshore parts of the Kwanza, Douala, Kribi-Campo, and Rio Muni Basins are underexplored, considering their size, and current exploration activity suggests that the basins have hydrocarbon potential. Since about 1995, the offshore part of the Congo Basin has become a major area for new field discoveries and for hydrocarbon exploration, and many deeper water areas in the basin have excellent hydrocarbon potential. Gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Controls on size and occurrence of the largest sub-aerial landslide on Earth: Seymareh (Saidmarreh) landslide, Zagros fold-thrust belt, Iran

NASA Astrophysics Data System (ADS)

Roberts, N. J.; Evans, S. G.

2009-12-01

Gigantic (> 1 Gm3) landslides are high-magnitude, low-frequency extremes of mass movements. They are important factors in topographic evolution and hazard in mountain regions due to their magnitude. However, few examples exist for study because of their infrequency. Consequently, controls on the location and size gigantic landslides remain poorly understood. Re-examination of the Seymareh (Saidmarreh) rock avalanche, Zagros fold-thrust belt, shows it to be the largest sub-aerial landslide on Earth (initial failure volume 38 Gm3), thus representing the upper magnitude limit for terrestrial landslides. Detailed examination of the source area (including orbital remote sensing, geotechnical investigation and structural mapping) provides new insights into controls on the size and mobility of gigantic landslides. The gigantic Early Holocene rockslide initiated on the northeast limb of Kabir Kuh, the largest anticline in the Zagros fold-thrust belt, and involved the simultaneous failure of a rock mass measuring 15 km along strike. The rockslide transformed into a rock avalanche that ran-out 19.0 km, filling two adjacent valleys and overtopping an intervening low mountain ridge. The failure involved 220 m of competent jointed limestone (Asmari Formation) underlain by 580 m of weaker mudrock-dominated units. Geologic structure, geomechanical strength and topography of the source slope strongly controlled failure initiation. Extreme landslide dimensions resulted in part from extensive uniform pre-failure stability, produced by structural and topographic features related to the large scale of the Kabir Kuh anticline. High continuity bedding planes determined the large lateral extent along strike. Bedding normal joints, the breached nature of the anticline and fluvial undercutting at the slope toe accommodated expansive lateral, headscarp and toe release, respectively, necessary for extensive failure. Geomechanically weak units at depth aided the penetration of the failure surface into the source slope while low bedding dip (ca. 19°) allowed kinematic freedom of a particularly thick sequence to move downslope. Prevention of gradual rockmass removal by smaller-magnitude, more frequent denudation ensured its preservation for later simultaneous failure. The overall failure surface (11°) cut across weaker beds and finally breached the Asmari carapace by break-out at the base of the source slope. Relative relief of the source slope on Kabir Kuh was modest (1350 m on average) indicating that uniform structural and topographic conditions along strike, shallow bedding dips, and the geomechnical properties of the source rock mass were more important in determining the magnitude of the landslide that forms the upper magnitude limit for subaerial landslides.

The New Albany Shale Petroleum System, Illinois Basin - Data and Map Image Archive from the Material-Balance Assessment

USGS Publications Warehouse

Higley, Debra K.; Henry, M.E.; Lewan, M.D.; Pitman, Janet K.

2003-01-01

The data files and explanations presented in this report were used to generate published material-balance approach estimates of amounts of petroleum 1) expelled from a source rock, and the sum of 2) petroleum discovered in-place plus that lost due to 3) secondary migration within, or leakage or erosion from a petroleum system. This study includes assessment of cumulative production, known petroleum volume, and original oil in place for hydrocarbons that were generated from the New Albany Shale source rocks.More than 4.00 billion barrels of oil (BBO) have been produced from Pennsylvanian-, Mississippian-, Devonian-, and Silurian-age reservoirs in the New Albany Shale petroleum system. Known petroleum volume is 4.16 BBO; the average recovery factor is 103.9% of the current cumulative production. Known petroleum volume of oil is 36.22% of the total original oil in place of 11.45 BBO. More than 140.4 BBO have been generated from the Upper Devonian and Lower Mississippian New Albany Shale in the Illinois Basin. Approximately 86.29 billion barrels of oil that was trapped south of the Cottage Grove fault system were lost by erosion of reservoir intervals. The remaining 54.15 BBO are 21% of the hydrocarbons that were generated in the basin and are accounted for using production data. Included in this publication are 2D maps that show the distribution of production for different formations versus the Rock-Eval pyrolysis hydrogen-indices (HI) contours, and 3D images that show the close association between burial depth and HI values.The primary vertical migration pathway of oil and gas was through faults and fractures into overlying reservoir strata. About 66% of the produced oil is located within the generative basin, which is outlined by an HI contour of 400. The remaining production is concentrated within 30 miles (50 km) outside the 400 HI contour. The generative basin is subdivided by contours of progressively lower hydrogen indices that represent increased levels of thermal maturity and generative capacity of New Albany Shale source rocks. The generative basin was also divided into seven oil-migration catchments. The catchments were determined using a surface-flow hydrologic model with contoured HI values as input to the model.

Modelling the role of magmatic intrusions in the post-breakup thermal evolution of Volcanic Passive Margins

NASA Astrophysics Data System (ADS)

Peace, Alexander; McCaffrey, Ken; Imber, Jonny; van Hunen, Jeroen; Hobbs, Richard; Gerdes, Keith

2013-04-01

Passive margins are produced by continental breakup and subsequent seafloor spreading, leaving a transition from continental to oceanic crust. Magmatism is associated with many passive margins and produces diagnostic criteria that include 1) abundant breakup related magmatism resulting in a thick igneous crust, 2) a high velocity zone in the lower crust and 3) seaward dipping reflectors (SDRs) in seismic studies. These Volcanic Passive Margins (VPMs) represent around 75% of the Atlantic passive margins, but beyond this high level description, these magma-rich settings remain poorly understood and present numerous challenges to petroleum exploration. In VPMs the extent to which the volume, timing, location and emplacement history of magma has played a role in controlling heat flow and thermal evolution during margin development remains poorly constrained. Reasons for this include; 1) paucity of direct heat flow and thermal gradient measurements at adequate depth ranges across the margins, 2) poor onshore exposure 3) highly eroded flood basalts and 4) poor seismic imaging beneath thick offshore basalt sequences. As a result, accurately modelling the thermal history of the basins located on VPMs is challenging, despite the obvious importance for determining the maturation history of potential source rocks in these settings. Magmatism appears to have affected the thermal history of the Vøring Basin on the Norwegian VPM, in contrast the effects on the Faeroe-Shetland Basin was minimal. The more localised effects in the Faeroe-Shetland Basin compared to Vøring Basin may be explained by the fact that the main reservoir sandstones appear to be synchronous with thermal uplift along the basin margin and pulsed volcanism, indicating that the bulk of the magmatism occurred at the basin extremities in the Faeroe-Shetland Basin, where its effect on source maturation was lessened. Our hypothesis is that source maturation occurs as a result of regional temperature and pressure increases, and the effects of even a large singular magmatic event are small beyond the immediate vicinity, therefore quantifying cumulative regional heat flow is of utmost importance. The apparently complex relationships between source rock maturation and magmatism are not limited to the north-east Atlantic margins. Other VPMs of interest include the regions between West Greenland and Eastern Canada (Labrador Sea, Davis Strait and Baffin Bay), East Greenland, NW Australia, Western India and segments of the Western African and Eastern South American margins. This project utilises 1D numerical modelling of magmatic intrusions into a sedimentary column to gain an understanding into the thermal influence of post-breakup magmatic activity on source rock maturation in representative VPMs. Considerations include the timing, periodicity of intrusions, thickness, spacing and background heat in the basin.

Petrology of the Northern Anabar alkaline-ultramafic rocks (the Siberian Craton, Russia) and the role of metasomatized lithospheric mantle in their genesis

NASA Astrophysics Data System (ADS)

Kargin, Alexey; Golubeva, Yulia; Demonterova, Elena

2017-04-01

The southeastern margin of the Anabar shield (the Siberian Craton) in Mesozoic was characterized by intense alkaline-ultramafic (include diamondiferous kimberlite) magmatism. This zone is located within the Archean-Proterozoic Hapchan terrane and includes several fields of alkaline-ultramafic rocks that formed during three main episodes (Zaytsev and Smelov, 2010; Sun et al., 2014): Late Triassic (235-205 Ma), Middle-Late Jurassic (171-149 Ma), Cretaceous (105 Ma). Following the revised classification scheme of Tappe et al. (2005), the alkaline-ultramafic rocks of the Anabar region were identified, correspondingly, as 1) Late Triassic aillikites, damtjernites, and orangeites; 2) Middle-Late Jurassic silicocarbonatites and 3) Cretaceous carbonatites. According to mineralogical, geochemical and isotopic (Sm-Nd, Rb-Sr) data on the alkaline-ultramafic rocks of the Anabar region, the following scheme of the mantle source evolution is suggested: 1). Ascent of the asthenospheric (or plume) material to the base of the lithospheric mantle containing numerous carbonate- and phlogopite-rich veins in Late Triassic led to the generation of orangeite and aillikite magmas; 2). Evolution of aillikite magmas during their ascent and interaction with the surrounding lithospheric mantle (e.g. mantle-rock assimilation and/or melt differentiation) resulted in the accumulation of Mg-Si components in alkaline-ultramafic magmas and was accompanied by a change in liquidus minerals (from apatite-carbonate to olivine and Ca-silicate). Exsolution of carbonate-rich fluid at this stage was responsible for the formation of damtjernite magmas. 3). The tectonothermal activation within the Anabar region in Jurassic was marked by the generation of silicocarbonatitic magmas. Their geochemical composition suggests decreasing abundance of phlogopite-rich veins in the lithospheric mantle source. 4). In Cretaceous, the alkaline-ultramafic magmatism shifted into the central part of the Hapchan terrane where produced several carbonatite pipes and dykes. Their geochemical composition indicates the predominance of the carbonate component in the source region and a decrease of the thickness of the lithospheric mantle. This study was supported by Russian Science Foundation №16-17-10068. Tappe S., Foley S.F., Jenner G.A. et al. 2006. Genesis of Ultramafic Lamprophyres and Carbonatites at Aillik Bay, Labrador: a Consequence of Incipient Lithospheric Thinning beneath the North Atlantic Craton // J. Petrology. V. 47 (7). P. 1261-1315. Sun J., Liu C.Z., Tappe S. et al. 2014. Repeated kimberlite magmatism beneath Yakutia and its relationship to Siberian flood volcanism: Insights from in situ U-Pb and Sr-Nd perovskite isotope analysis // Earth Planet. Sci. Lett. V. 404. P. 283-295. Zaytsev A.I., Smelov A.P., 2010. Isotope Geochronology of Kimberlite Formation Rocks from Yakutian Province // Publication of the Institute of Diamonds Geology, Siberian branch of the Russian Academy of Sciences, Yakutsk (107 pp. (in Russian)).

Lithological Influences on Occurrence of High-Fluoride Waters in The Central Kenya Rift

NASA Astrophysics Data System (ADS)

Olaka, L. A.; Musolff, A.; Mulch, A.; Olago, D.; Odada, E. O.

2013-12-01

Within the East African rift, groundwater recharge results from the complex interplay of geology, land cover, geomorphology, climate and on going volcano-tectonic processes across a broad range of spatial and temporal scales. The interrelationships between these factors create complex patterns of water availability, reliability and quality. The hydrochemical evolution of the waters is further complex due to the different climatic regimes and geothermal processes going on in this area. High fluoridic waters within the rift have been reported by few studies, while dental fluorosis is high among the inhabitants of the rift. The natural sources of fluoride in waters can be from weathering of fluorine bearing minerals in rocks, volcanic or fumarolic activities. Fluoride concentration in water depends on a number of factors including pH, temperature, time of water-rock formation contact and geochemical processes. Knowledge of the sources and dispersion of fluoride in both surface and groundwaters within the central Kenya rift and seasonal variations between wet and dry seasons is still poor. The Central Kenya rift is marked by active tectonics, volcanic activity and fumarolic activity, the rocks are majorly volcanics: rhyolites, tuffs, basalts, phonolites, ashes and agglomerates some are highly fractured. Major NW-SE faults bound the rift escarpment while the rift floor is marked by N-S striking faults We combine petrographic, hydrochemistry and structural information to determine the sources and enrichment pathways of high fluoridic waters within the Naivasha catchment. A total of 120 water samples for both the dry season (January-February2012) and after wet season (June-July 2013) from springs, rivers, lakes, hand dug wells, fumaroles and boreholes within the Naivasha catchment are collected and analysed for fluoride, physicochemical parameters and stable isotopes (δ2 H, δ18 O) in order to determine the origin and evolution of the waters. Additionally, 30 soil and rock samples were also collected and analysed for fluoride, and rock samples were subjected to petrographic investigations and X-ray diffraction. The fluoride levels in surface and groundwater for the dry season range from 0.019 - 50.14 mg/L, on average above the WHO permissible limit. The high fluoride occurs both in the lake and groundwater. Preliminary petrographic studies show considerable fluoride in micas. The study is on-going and plans to present the relative abundances of fluoride in the lithology as the sources and the fluoride enrichment pathways of the groundwater within the Central Kenya rift.

Geochemical and Isotopic Evidences of the Magmatic Sources in the Eastern Sector of the Trans-Mexican Volcanic Belt: Xihuingo-Chichicuautla Volcanic Field

NASA Astrophysics Data System (ADS)

Valadez, S.; Martinez-serrano, R.; Juarez-Lopez, K.; Solis-Pichardo, G.; Perez-Arvizu, O.

2011-12-01

The study of magmatism in the Trans-Mexican Volcanic Belt (TMVB) has great importance due to several features such as its obliquity with respect to the Middle American Trench and its petrological and geochemical variability, which are not common in most typical volcanic arcs. Although several papers have contributed significantly to the understanding of most important magmatic processes in this province, there are still several questions such as the characterization of magmatic sources. In the present work, we provide new stratigraphic, petrographic, geochemical and Sr, Nd and Pb isotopic data as well as some K-Ar age determinations from the Xihuingo-Chichicuautla volcanic field (XCVF), located at the eastern part of the TMVB, with the aim to identify the magmatic sources that produced the main volcanic rocks. The volcanic structures in the XCVF are divided in two main groups according to the petrographic and geochemical compositions: 1) dacitic domes, andesitic lava flows and some dacitic-rhyolitic ignimbrites and 2) scoria cones, shield volcanoes and associated lava flows of basalt to basaltic-andesite composition. Distribution of most volcanic structures is probably controlled by NE-SW fault and fractures system. This fault system was studied by other authors who established that volcanic activity started ca. 13.5 Ma ago, followed by a volcanic hiatus of ca. 10 Ma, and the late volcanic activity began ca. 3 to 1 Ma. In this work we dated 2 rock samples by K-Ar method, which yielded ages of 402 and 871 Ka, which correspond to the most recent volcanic activity in this study area. The volcanic rocks of the XCVF display compositions from basalts to rhyolites but in general all rocks show trace element patterns typical of magmatic arcs. However, we can identify two main magmatic sources: a depleted magmatic source represented by dacitic-andesitic rocks which present a LILE enrichment with respect to HFSE indicating that a magmatic source was modified by fluids derived from the subduction processes. These magmas probably suffered fractional crystallization and minor assimilation in the continental crust. Sr, Nd isotopic compositions for this first group display the most radiogenic values (87Sr/86Sr from 0.7046 to 0.7047 and ɛNd from 2.2 to 2.8). The second source for the basaltic-andesite and basalt could be associated with an enriched mantle. These rocks present a minor LILE enrichment with respect to HSFE, and Sr and Nd isotopic values less radiogenic than the felsic rocks of the first group (87Sr/86Sr from 0.7040 to 0.7045 and ɛNd from 3.1 to 4.8). According to these evidences we can establish that the magmas emplaced in the study area were produced from a heterogeneous mantle source with complex magmatic processes combined with different interaction degrees between the magmas and continental crust.

Sr and Nd isotope composition of the metamorphic, sedimentary and ultramafic xenoliths of Lanzarote (Canary Islands): Implications for magma sources

NASA Astrophysics Data System (ADS)

Aparicio, Alfredo; Tassinari, Colombo C. G.; García, Roberto; Araña, Vicente

2010-01-01

The lavas produced by the Timanfaya eruption of 1730-1736 (Lanzarote, Canary Islands) contain a great many sedimentary and metamorphic (metasedimentary), and mafic and ultramafic plutonic xenoliths. Among the metamorphosed carbonate rocks (calc-silicate rocks [CSRs]) are monomineral rocks with forsterite or wollastonite, as well as rocks containing olivine ± orthopyroxene ± clinopyroxene ± plagioclase; their mineralogical compositions are identical to those of the mafic (gabbros) and ultramafic (dunite, wherlite and lherzolite) xenoliths. The 87Sr/ 86Sr (around 0.703) and 143Nd/ 144Nd (around 0.512) isotope ratios of the ultramafic and metasedimentary xenoliths are similar, while the 147Sm/ 144Nd ratios show crustal values (0.13-0.16) in the ultramafic xenoliths and mantle values (0.18-0.25) in some CSRs. The apparent isotopic anomaly of the metamorphic xenoliths can be explained in terms of the heat source (basaltic intrusion) inducing strong isotopic exchange ( 87Sr/ 86Sr and 143Nd/ 144Nd) between metasedimentary and basaltic rocks. Petrofabric analysis also showed a possible relationship between the ultramafic and metamorphic xenoliths.

Petrogenesis of Cretaceous volcanic-intrusive complex from the giant Yanbei tin deposit, South China: Implication for multiple magma sources, tin mineralization, and geodynamic setting

NASA Astrophysics Data System (ADS)

Li, Qian; Zhao, Kui-Dong; Lai, Pan-Chen; Jiang, Shao-Yong; Chen, Wei

2018-01-01

The giant Yanbei tin ore deposit is the largest porphyry-type tin deposit in South China. The orebodies are hosted by the granite porphyry in the central part of the Yanbei volcanic basin in southern Jiangxi Province. The Yanbei volcanic-intrusive complex mainly consists of dacitic-rhyolitic volcanic rocks, granite, granite porphyry and diabase dikes. In previous papers, the granite porphyry was considered as subvolcanic rocks, which came from the same single magma chamber with the volcanic rocks. In this study, zircon U-Pb ages and Hf isotope data, as well as whole-rock geochemical and Sr-Nd isotopic compositions of different magmatic units in the Yanbei complex are reported. Geochronologic results show that various magmatic units have different formation ages. The dacite yielded a zircon U-Pb age of 143 ± 1 Ma, and the granite porphyry has the emplacement age of 138 ± 1 Ma. Diabase dikes which represented the final stage of magmatism, yielded a zircon U-Pb age of 128 ± 1 Ma. Distinctive whole rock Sr-Nd and zircon Hf isotopic compositions suggest that these magmatic units were derived from different magma sources. The volcanic rocks were mainly derived from the partial melting of Paleoproterozoic metasedimentary rocks without additions of mantle-derived magma. The granite porphyry has an A-type geochemical affinity, and was derived from remelting of Paleo-Mesoproterozoic crustal source with involvement of a subordinate mantle-derived magma. The granite porphyry is also a typical stanniferous granite with high F (4070-6090 ppm) and Sn (7-39 ppm) contents. It underwent strongly crystal fractionation of plagioclase, K-feldspar, and accessory minerals (like apatite, Fe-Ti oxides), which may contribute to the tin mineralization. The diabase was derived by partial melting of enriched lithospheric mantle which had been metasomatised by slab-derived fluids. The change of magmatic sources reflected an increasing extensional tectonic environment, perhaps induced by slab rollback of subducted paleo-Pacific plate.

Simulation of Mechanical Processes in Gas Storage Caverns for Short-Term Energy Storage

NASA Astrophysics Data System (ADS)

Böttcher, Norbert; Nagel, Thomas; Kolditz, Olaf

2015-04-01

In recent years, Germany's energy management has started to be transferred from fossil fuels to renewable and sustainable energy carriers. Renewable energy sources such as solar and wind power are subjected by fluctuations, thus the development and extension of energy storage capacities is a priority in German R&D programs. This work is a part of the ANGUS+ Project, funded by the federal ministry of education and research, which investigates the influence of subsurface energy storage on the underground. The utilization of subsurface salt caverns as a long-term storage reservoir for fossil fuels is a common method, since the construction of caverns in salt rock is inexpensive in comparison to solid rock formations due to solution mining. Another advantage of evaporate as host material is the self-healing behaviour of salt rock, thus the cavity can be assumed to be impermeable. In the framework of short-term energy storage (hours to days), caverns can be used as gas storage reservoirs for natural or artificial fuel gases, such as hydrogen, methane, or compressed air, where the operation pressures inside the caverns will fluctuate more frequently. This work investigates the influence of changing operation pressures at high frequencies on the stability of the host rock of gas storage caverns utilizing numerical models. Therefore, we developed a coupled Thermo-Hydro-Mechanical (THM) model based on the finite element method utilizing the open-source software platform OpenGeoSys. The salt behaviour is described by well-known constitutive material models which are capable of predicting creep, self-healing, and dilatancy processes. Our simulations include the thermodynamic behaviour of gas storage process, temperature development and distribution on the cavern boundary, the deformation of the cavern geometry, and the prediction of the dilatancy zone. Based on the numerical results, optimal operation modes can be found for individual caverns, so the risk of host rock damage can be minimized. Furthermore, the model can be used to design efficient monitoring programs to detect possible variations of the host rock due construction and operation of the storage facility. The developed model will be used by public authorities for land use planning issues.

Clumped isotopologue constraints on the origin of methane at seafloor hot springs

NASA Astrophysics Data System (ADS)

Wang, David T.; Reeves, Eoghan P.; McDermott, Jill M.; Seewald, Jeffrey S.; Ono, Shuhei

2018-02-01

Hot-spring fluids emanating from deep-sea vents hosted in unsedimented ultramafic and mafic rock commonly contain high concentrations of methane. Multiple hypotheses have been proposed for the origin(s) of this methane, ranging from synthesis via reduction of aqueous inorganic carbon (∑CO2) during active fluid circulation to leaching of methane-rich fluid inclusions from plutonic rocks of the oceanic crust. To further resolve the process(es) responsible for methane generation in these systems, we determined the relative abundances of several methane isotopologues (including 13CH3D, a "clumped" isotopologue containing two rare isotope substitutions) in hot-spring source fluids sampled from four geochemically-distinct hydrothermal vent fields (Rainbow, Von Damm, Lost City, and Lucky Strike). Apparent equilibrium temperatures retrieved from methane clumped isotopologue analyses average 310-42+53 °C, with no apparent relation to the wide range of fluid temperatures (96-370 °C) and chemical compositions (pH, [H2], [∑CO2], [CH4]) represented. Combined with very similar bulk stable isotope ratios (13C/12C and D/H) of methane across the suite of hydrothermal fluids, all available geochemical and isotopic data suggest a common mechanism of methane generation at depth that is disconnected from active fluid circulation. Attainment of equilibrium amongst methane isotopologues at temperatures of ca. 270-360 °C is compatible with the thermodynamically-favorable reduction of CO2 to CH4 at temperatures at or below ca. 400 °C under redox conditions characterizing intrusive rocks derived from sub-ridge melts. Collectively, the observations support a model where methane-rich aqueous fluids, known to be trapped in rocks of the oceanic lithosphere, are liberated from host rocks during hydrothermal circulation and perhaps represent the major source of methane venting with thermal waters at unsedimented hydrothermal fields. The results also provide further evidence that water-rock reactions occurring at temperatures lower than 200 °C do not contribute significantly to the quantities of methane venting at mid-ocean ridge hot springs.

The Mapping X-ray Fluorescence Spectrometer (MapX)

NASA Astrophysics Data System (ADS)

Sarrazin, P.; Blake, D. F.; Marchis, F.; Bristow, T.; Thompson, K.

2017-12-01

Many planetary surface processes leave traces of their actions as features in the size range 10s to 100s of microns. The Mapping X-ray Fluorescence Spectrometer (MapX) will provide elemental imaging at 100 micron spatial resolution, yielding elemental chemistry at a scale where many relict physical, chemical, or biological features can be imaged and interpreted in ancient rocks on planetary bodies and planetesimals. MapX is an arm-based instrument positioned on a rock or regolith with touch sensors. During an analysis, an X-ray source (tube or radioisotope) bombards the sample with X-rays or alpha-particles / gamma-rays, resulting in sample X-ray Fluorescence (XRF). X-rays emitted in the direction of an X-ray sensitive CCD imager pass through a 1:1 focusing lens (X-ray micro-pore Optic (MPO)) that projects a spatially resolved image of the X-rays onto the CCD. The CCD is operated in single photon counting mode so that the energies and positions of individual X-ray photons are recorded. In a single analysis, several thousand frames are both stored and processed in real-time. Higher level data products include single-element maps with a lateral spatial resolution of 100 microns and quantitative XRF spectra from ground- or instrument- selected Regions of Interest (ROI). XRF spectra from ROI are compared with known rock and mineral compositions to extrapolate the data to rock types and putative mineralogies. When applied to airless bodies and implemented with an appropriate radioisotope source for alpha-particle excitation, MapX will be able to analyze biogenic elements C, N, O, P, S, in addition to the cations of the rock-forming elements >Na, accessible with either X-ray or gamma-ray excitation. The MapX concept has been demonstrated with a series of lab-based prototypes and is currently under refinement and TRL maturation.

Petrogenesis and tectonic implications of Early Cretaceous volcanic rocks from Lingshan Island in the Sulu Orogenic Belt

NASA Astrophysics Data System (ADS)

Meng, Yuanku; Santosh, M.; Li, Rihui; Xu, Yang; Hou, Fanghui

2018-07-01

The Dabie-Sulu orogenic belt in eastern China marks the boundary between the Yangtze Block and the North China Block. Here we investigate a suite of volcanic rocks from Lingshan Island in the Sulu belt comprising rhyolite, trachyte, trachyandesite and basaltic trachyandesite. We present petrological, geochemical and zircon Usbnd Pb ages and Hfsbnd O isotope data with a view to gain insights on the petrogenesis and tectonic implications. SHRIMP II analyses of zircon grains from the rhyolite yield 206Pb/238U age of 127.6 ± 1.3 Ma and LA-MC-ICP-MS dating show 126.3 ± 1.2 Ma and 127.3 ± 1.1 Ma, together constraining the eruption time as Early Cretaceous. LA-MC-ICP-MS analyses of zircon grains from the andesitic rocks yield 206Pb/238U ages of 129.0 ± 1.6 Ma, 129.8 ± 1.5 Ma and 130.9 ± 1.0 Ma. Geochemically, the rhyolite shows shoshonitic features with low MgO and Cr, but high Na2O + K2O. The zircon grains from these rocks yield negative εHf(t) values and low δ18O values, and these together with the presence of Neoproterozoic inherited zircons suggest that the magma source involved melting of the Yangtze crust. The andesitic rocks, including basaltic trachyandesite, trachyandesite and trachyte, show a wide range of SiO2, Mg# values, and Cr, enriched in LILE and LREE, depleted in HFSE (Nb, Ta and Ti), and have significantly negative zircon εHf(t) values, suggesting derivation from subcontinental lithosphere mantle that was metasomatized by felsic melts. Our results, integrated with those from previous studies suggest heterogeneous magma involving the mixing of mantle and crustal sources within an extensional setting in the Early Cretaceous.

Nitrate and selected pesticides in ground water of the Mid-Atlantic region

USGS Publications Warehouse

Ator, Scott W.; Ferrari, Matthew J.

1997-01-01

Data from more than 850 sites were compiled and analyzed to document the occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region as part of the Mid-Atlantic Integrated Assessment program of the U.S. Environmental Protection Agency. Only those data collected by the U.S. Geological Survey as part of regional networks between October 1985 and September 1996 (inclusive) were used in the analyses, and the data were examined to ensure analytical results are not biased toward sites at the same location or sites sampled multiple times during this period. Regional data are available for most of the Mid-Atlantic region but large spatial gaps in available data do exist. Nitrate was detected in nearly three-quarters of the samples for which it was analyzed, commonly at levels that suggest anthropogenic sources. Ten percent of samples contained nitrate at concentrations exceeding the Federal Maximum Contaminant Level (MCL) of 10 milligrams per liter as nitrogen. Pesticide compounds (including atrazine, metolachlor, prometon, simazine, and desethylatrazine, an atrazine degradate) were detected in about half of the samples for which they were analyzed, but rarely at concentrations exceeding established MCL?s. The most commonly detected pesticide compounds were desethylatrazine and atrazine. The occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region is related to land cover and rock type. Likely sources of nitrate and pesticides to ground water include agricultural and urban land-use practices; rock type affects the movement of these compounds into and through the ground-water system. Nitrate concentrations in the compiled data set are significantly higher in ground water in agricultural areas than in urban or forested areas, but concentrations in areas of row crops are statistically indistinguishable from those in areas of pastures. Detection frequencies of atrazine, desethylatrazine, and simazine are indistinguishable among urban areas, row crops, and pastures. Prometon was most commonly detected in ground water in urban areas. Ground-water samples from forested areas typically contained the lowest concentrations of nitrate and detection frequencies of pesticides. Concentrations of nitrate and detection frequencies of pesticides were significantly higher in samples from carbonate rocks than in those from any other rock type. Most areas of the Mid-Atlantic region that are underlain by carbonate rocks have been developed for agricultural or urban use and the solution channels that are typical of carbonate rocks allow for relatively rapid transport of surficial contaminants throughout the ground-water system. Nitrate concentrations in unconsolidated aquifers were among the lowest for all rock types, possibly because of denitrification in organic-rich subsoils and shallow sediments.

Geochronology of archean gneisses in the Lake Helen area, Southwestern Big Horn Mountains, Wyoming

USGS Publications Warehouse

Arth, Joseph G.; Barker, F.; Stern, T.W.

1980-01-01

The RbSr and UPb methods were used to study gneisses in the 7 1 2-minute Lake Helen quadrangle of the Big Horn Mountains, Wyoming. Two episodes of magmatism, deformation and metamorphism occurred during the Archean. Trondhjemitic to tonalitic orthogneisses and amphibolite of the first episode (E-1) are cut by a trondhjemite pluton and a calc-alkaline intrusive series of the second episode (E-2). The E-2 series includes hornblende-biotite quartz diorite, biotite tonalite, biotite granodiorite and biotite granite. A RbSr whole-rock isochron for E-1 gneisses indicates an age of 3007 ?? 34 Ma (1 sigma) and an initial 87Sr/86Sr of 0.7001 ?? 0.0001. UPb determination on zircon from E-1 gneisses yield a concordia intercept age of 2947 ?? 50 Ma. The low initial ratio suggests that the gneisses had no significant crustal history prior to metamorphism, and that the magmas from which they formed had originated from a mafic source. A RbSr whole-rock isochron for E-2 gneisses gives an age of 2801 ?? 31 Ma. The 87Sr/86Sr initial ration is 0.7015 ?? 0.0002 and precludes the existence of the rocks for more than 150 Ma prior to metamorphism. The E-2 magmas may have originated from melting of E-1 gneisses or from a more mafic source. ?? 1980.

X-Ray Diffraction on Mars: Scientific Discoveries Made by the CheMin Instrument

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Blake, D. F.; Ming, D. W.; Bristow, T. F.

2017-01-01

The Mars Science Laboratory Curiosity landed in Gale crater in August 2012 with the goal to identify and characterize habitable environments on Mars. Curiosity has been studying a series of sedimentary rocks primarily deposited in fluviolacustrine environments approximately 3.5 Ga. Minerals in the rocks and soils on Mars can help place further constraints on these ancient aqueous environments, including pH, salinity, and relative duration of liquid water. The Chemistry and Mineralogy (CheMin) X-ray diffraction and X-ray fluorescence instrument on Curiosity uses a Co X-ray source and charge-coupled device detector in transmission geometry to collect 2D Debye-Scherrer ring patterns of the less than 150 micron size fraction of drilled rock powders or scooped sediments. With an angular range of approximately 2.52deg 20 and a 20 resolution of approximately 0.3deg, mineral abundances can be quantified with a detection limit of approximately 1-2 wt. %. CheMin has returned quantitative mineral abundances from 16 mudstone, sandstone, and aeolian sand samples so far. The mineralogy of these samples is incredibly diverse, suggesting a variety of depositional and diagenetic environments and different source regions for the sediments. Results from CheMin have been essential for reconstructing the geologic history of Gale crater and addressing the question of habitability on ancient Mars.

[Phosphate solubilization of Aureobasidium pullulan F4 and its mechanism].

PubMed

Wang, Dan; Zhan, Jing; Sun, Qing-Ye

2014-07-01

The Aureobasidium pullulans F4 was isolated from the rhizosphere of Hippochaete ramosissimum in Tongguanshan mine wasteland in Tongling City, Anhui Province. Liquid culture was conducted with four kinds of phosphorus sources, calcium phosphate, aluminum phosphate, ferric phosphate and rock phosphate to determine the pH, dissolved phosphorus, phosphorus in the bacteria and organic acid in the solution. The results showed that the phosphate solubilization by A. pullulans F4 varied with phosphorus sources, which decreased in order of aluminum phosphate > ferric phosphate, calcium phosphate > rock phosphate. The amounts of dissolved phosphorus in the different treatments were all higher than 200 mg x L(-1). The pH of the medium dropped immediately in 48 h, and the aluminum phosphate and ferric phosphate treatments showed a greater decrease in pH than the calcium phosphate and rock phosphate treatments. The organic acid synthesized by A. pullulans F4 included oxalic acid, citric acid and tartaric acid, and oxalic acid, among which oxalic acid was the dominated component. The phosphate dissolving capacity of A. pullulans F4 showed no significant correlation with organic acid, but significantly correlated with the pH. The available phosphorus was significantly improved with the combined application of A. pullulans F4 and glucose, suggesting A. pullulans F4 was a potent candidate for remediation of copper mine wastelands.

Distinct Igneous APXS Rock Compositions on Mars from Pathfinder, MER and MSL

NASA Technical Reports Server (NTRS)

Gellert, Ralf; Arvidson, Raymond; Clark, Benton, III; Ming, Douglas W.; Morris, Richard V.; Squyres, Steven W.; Yen, Albert S.

2015-01-01

The alpha particle x-ray spectrometer (APXS) on all four Mars Rovers returned geochemical data from about 1000 rocks and soils along the combined traverses of over 50 kilometers. Here we discuss rocks likely of igneous origin, which might represent source materials for the soils and sediments identified along the traverses. Adirondack-type basalts, abundant in the plains of Gusev Crater, are primitive, olivine bearing basalts. They resemble in composition the basaltic soils encountered at all landing sites, except the ubiquitous elevated S, Cl and Zn in soils. They have been postulated to represent closely the average Martian crust composition. The recently identified new Martian meteorite Black Beauty has similar overall geochemical composition, very distinct from the earlier established SNC meteorites. The rim of the Noachian crater Endeavour, predating the sulfate-bearing Burns formation at Meridiani Planum, also resembles closely the composition of Adirondack basalts. At Gale Crater, the MSL Curiosity rover identified a felsic rock type exemplified by the mugearitic float rock JakeM, which is widespread along the traverse at Gale. While a surprise at that time, possibly related more evolved, alkaline rocks had been previously identified on Mars. Spirit encountered the Wishstone rocks in the Columbia Hills with approx. 6% Na2O+K2O, 15 % Al2O3 and low 12% FeO. Pathfinder rocks with elevated K and Na and >50% SiO2 were postulated to be andesitic. Recently Opportunity encountered the rock JeanBaptisteCharbonneau with >15% Al2O3, >50% SiO2 and approx. 10% FeO. A common characteristic all these rocks is the very low abundance of Cr, Ni and Zn, and an Fe/Mn ratio of about 50, indicating an unaltered Fe mineralogy. Beside these likely igneous rock types, which occurred always in several rocks, a few unique rocks were encountered, e.g. Bounce Rock, a pyroxene-bearing ejecta rock fragment resembling the Shergottite EETA 79001B meteorite. The APXS data can be used to relate the findings of all 4 landing sites, constrain the water to rock ratio of sediments or imply source rock provenance. Beyond that the capability to quantify important volatile elements like P, S, Cl, and Br have provided new insights into the chemistry and the environment present during the formation of the sediments.

Ages and origins of rocks of the Killingworth dome, south-central Connecticut: Implications for the tectonic evolution of southern New England

USGS Publications Warehouse

Aleinikoff, J.N.; Wintsch, R.P.; Tollo, R.P.; Unruh, D.M.; Fanning, C.M.; Schmitz, M.D.

2007-01-01

The Killingworth dome of south-central Connecticut occurs at the southern end of the Bronson Hill belt. It is composed of tonalitic and trondhjemitic orthogneisses (Killingworth complex) and bimodal metavolcanic rocks (Middletown complex) that display calc-alkaline affinities. Orthogneisses of the Killingworth complex (Boulder Lake gneiss, 456 ?? 6 Ma; Pond Meadow gneiss, ???460 Ma) were emplaced at about the same time as eruption and deposition of volcanic-sedimentary rocks of the Middletown complex (Middletown Formation, 449 ?? 4 Ma; Higganum gneiss, 459 ?? 4 Ma). Hidden Lake gneiss (339 ?? 3 Ma) occurs as a pluton in the core of the Killingworth dome, and, on the basis of geochemical and isotopic data, is included in the Killingworth complex. Pb and Nd isotopic data suggest that the Pond Meadow, Boulder Lake, and Hidden Lake gneisses (Killingworth complex) resulted from mixing of Neoproterozoic Gander terrane sources (high 207Pb/204Pb and intermediate ??Nd) and less radiogenic (low 207Pb/204Pb and low ??Nd) components, whereas Middletown Formation and Higganum gneiss (Middletown complex) were derived from mixtures of Gander basement and primitive (low 207Pb/204Pb and high ??Nd) sources. The less radiogenic component for the Killingworth complex is similar in isotopic composition to material from Laurentian (Grenville) crust. However, because published paleomagnetic and paleontologic data indicate that the Gander terrane is peri-Gondwanan in origin, the isotopic signature of Killingworth complex rocks probably was derived from Gander basement that contained detritus from non-Laurentian sources such as Amazonia, Baltica, or Oaxaquia. We suggest that the Killingworth complex formed above an east-dipping subduction zone on the west margin of the Gander terrane, whereas the Middletown complex formed to the east in a back-arc rift environment. Subsequent shortening, associated with the assembly of Pangea in the Carboniferous, resulted in Gander cover terranes over the Avalon terrane in the west; and in the Middletown complex over the Killingworth complex in the east. Despite similarities of emplacement age, structural setting, and geographic continuity of the Killingworth dome with Oliverian domes in central and northern New England, new and published isotopic data suggest that the Killingworth and Middletown complexes were derived from Gander crust, and are not part of the Bronson Hill arc that was derived from Laurentian crust. The trace of the Ordovician Iapetan suture (the Red Indian line) between rocks of Laurentian and Ganderian origin probably extends from Southwestern New Hampshire west of the Pelham dome of northcentral Massachusetts and is coverd by Mesozoic rocks of the Hartford basin.

Excess europium content in Precambrian sedimentary rocks and continental evolution

NASA Technical Reports Server (NTRS)

Jakes, P.; Taylor, S. R.

1974-01-01

It is proposed that the europium excess in Precambrian sedimentary rocks, relative to those of younger age, is derived from volcanic rocks of ancient island arcs, which were the source materials for the sediments. Precambrian sedimentary rocks and present-day volcanic rocks of island arcs have similar REE patterns, total REE abundances, and excess Eu, relative to the North American shale composite. The present upper crustal REE pattern, as exemplified by that of sediments, is depleted in Eu, relative to chondrites. This depletion is considered to be a consequence of development of a granodioritic upper crust by partial melting in the lower crust, which selectively retains europium.

Generalized surficial geologic map of the Fort Irwin area, San Bernadino: Chapter B in Geology and geophysics applied to groundwater hydrology at Fort Irwin, California

USGS Publications Warehouse

Miller, David M.; Menges, Christopher M.; Lidke, David J.; Buesch, David C.

2014-01-01

The geology and landscape of the Fort Irwin area, typical of many parts of the Mojave Desert, consist of rugged mountains separated by broad alluviated valleys that form the main coarse-resolution features of the geologic map. Crystalline and sedimentary rocks, Mesozoic and older in age, form most of the mountains with lesser accumulations of Miocene sedimentary and volcanic rocks. In detail, the area exhibits a fairly complex distribution of surficial deposits resulting from diverse rock sources and geomorphology that has been driven by topographic changes caused by recent and active faulting. Depositional environments span those typical of the Mojave Desert: alluvial fans on broad piedmonts, major intermittent streams along valley floors, eolian sand dunes and sheets, and playas in closed valleys that lack through-going washes. Erosional environments include rocky mountains, smooth gently sloping pediments, and badlands in readily eroded sediment. All parts of the landscape, from regional distribution of mountains, valleys, and faults to details of degree of soil development in surface materials, are portrayed by the surficial geologic map. Many of these attributes govern infiltration and recharge, and the surface distribution of permeable rock units such as Miocene sedimentary and volcanic rocks provides a basis for evaluating potential groundwater storage. Quaternary faults are widespread in the Fort Irwin area and include sinistral, east-striking faults that characterize the central swath of the area and the contrasting dextral, northwest-striking faults that border the east and west margins. Bedrock distribution and thickness of valley-fill deposits are controlled by modern and past faulting, and faults on the map help to identify targets for groundwater exploration.

Petrophysical Rock Typing of Unconventional Shale Plays: A Case Study for the Niobrara Formation of the Denver-Julesburg (DJ) Basin

NASA Astrophysics Data System (ADS)

Kamruzzaman, A.; Prasad, M.

2015-12-01

The hydrocarbon-rich mudstone rock layers of the Niobrara Formation were deposited in the shallow marine environment and have evolved as overmature oil- or gas-prone source and reservoir rocks. The hydrocarbon production from its low-porosity, nano-darcy permeability and interbedded chalk-marl reservoir intervals is very challenging. The post-diagenetic processes have altered the mineralogy and pore structure of its sourcing and producing rock units. A rock typing analysis in this play can help understand the reservoir heterogeneity significantly. In this study, a petrophysical rock typing workflow is presented for the Niobrara Formation by integrating experimental rock properties with geologic lithofacies classification, well log data and core study.Various Niobrara lithofacies are classified by evaluating geologic depositional history, sequence stratigraphy, mineralogy, pore structure, organic content, core texture, acoustic properties, and well log data. The experimental rock measurements are conducted on the core samples recovered from a vertical well from the Wattenberg Field of the Denver-Julesburg (DJ) Basin. Selected lithofacies are used to identify distinct petrofacies through the empirical analysis of the experimental data-set. The grouped petrofacies are observed to have unique mineralogical properties, pore characteristics, and organic contents and are labelled as discrete Niobrara rock types in the study area.Micro-textural image analysis (FESEM) is performed to qualitatively examine the pore size distribution, pore types and mineral composition in the matrix to confirm the classified rock units. The principal component analysis and the cluster analysis are carried out to establish the certainty of the selected rock types. Finally, the net-to-pay thicknesses of these rock units are compared with the cumulative production data from the field to further validate the chosen rock types.For unconventional shale plays, the rock typing information can be used to locate hydrocarbon sweetspots, facilitate the placement of the horizontal section of the wells along the sweetspots, and can augment engineers' abilities on suitable well placement considerations. It can also help enhancing the effectiveness of the hydraulic fracture stimulation and completion operation.

Change of Conditions of the Formation of the Karelian Province of the Baltic Shield Continental Crust during Transition from Meso- to Neoarchean: Geochemical Study Results

NASA Astrophysics Data System (ADS)

Chekulaev, V. P.; Arestova, N. A.; Egorova, Yu. S.; Kucherovskii, G. A.

2018-05-01

The compositions of the tonalite-trondhjemite-granodiorite (TTG) assemblage and volcanic rocks of the Archaean greenstone belts from different domains of the Karelian province of the Baltic Shield are compared. Neoarchean medium felsic volcanic rocks and TTG of the Central Karelian domain drastically differ from analogous Mesoarchean rocks of the neighboring Vodlozero and West Karelian domains in higher Rb, Sr, P, La, and Ce contents and, correspondingly, values of Sr/Y, La/Yb, and La/Sm, and also in a different REE content distribution owing to different rock sources of these domains. This fact is confirmed by differences in the composition and the nature of the REE distribution in the basic and ultrabasic volcanic rocks making up the greenstone belts of these domains. It is established that the average compositions of Mesoarchean TTG rocks and volcanic rocks of the Karelian province differ markedly from those of plagiogranitoids and volcanic rocks of the recent geotectonic environments in high Mg (mg#) and Sr contents. Neoarchean volcanic rocks of Karelia differ from recent island-arc volcanic rocks, but are similar in composition to recent volcanic rocks of the continental arcs. On the basis of the cumulative evidence, the Karelian province of the Baltic Shield was subject to dramatic changes in the crust formation conditions at the beginning of the Neoarchean at the turn of about 2.75-2.78 Ga. These changes led to formation of volcano-sedimentary and plutonic rock complexes, different in composition from Mesoarchean rocks, and specific complexes of intrusive sanukitoids and granites. Changes and variations in the rock composition were related to the mixing of plume sources with continental crust and/or lithospheric mantle material, likely as a result of the combined effect of plumes and plate tectonics. This process resulted in formation of a younger large fragment of the Archean crust such as the Central Karelian domain which factually connected more ancient fragments of the crust and likely contributed to development of the Neoarchean Kenorland Supercontinent.

Stratigraphy, geochemistry and tectonic significance of the Oligocene magmatic rocks of western Oaxaca, southern Mexico

USGS Publications Warehouse

Martiny, B.; Martinez-Serrano, R. G.; Moran-Zenteno, D. J.; MacIas-Romo, C.; Ayuso, R.A.

2000-01-01

In Western Oaxaca, Tertiary magmatic activity is represented by extensive plutons along the continental margin and volcanic sequences in the inland region. K-Ar age determinations reported previously and in the present work indicate that these rocks correspond to a relatively broad arc in this region that was active mainly during the Oligocene (~ 35 to ~ 25 Ma). In the northern sector of western Oaxaca (Huajuapan-Monte Verde-Yanhuitlan), the volcanic suite comprises principally basaltic andesite to andesitic lavas, overlying minor silicic to intermediate volcaniclastic rocks (epiclastic deposits, ash fall tuffs, ignimbrites) that were deposited in the lacustrine-fluvial environment. The southern sector of the volcanic zone includes the Tlaxiaco-Laguna de Guadalupe region and consists of intermediate to silicic pyroclastic and epiclastic deposits, with silicic ash fall tuffs and ignimbrites. In both sectors, numerous andesitic to dacitic hypabyssal intrusions (stocks and dikes) were emplaced at different levels of the sequence. The granitoids of the coastal plutonic belt are generally more differentiated than the volcanic rocks that predominate in the northern sector and vary in composition from granite to granodiorite. The studied rocks show large-ion lithophile element (LILE) enrichment (K, Rb, Ba, Th) relative to high-field-strength (HFS) elements (Nb, Ti, Zr) that is characteristic of subduction-related magmatic rocks. On chondrite-normalized rare earth element diagrams, these samples display light rare earth element enrichment (LREE) and a flat pattern for the heavy rare earth elements (HREE). In spite of the contrasting degree of differentiation between the coastal plutons and inland volcanic rocks, there is a relatively small variation in the isotopic composition of these two suites. Initial 87Sr/86Sr ratios obtained and reported previously for Tertiary plutonic rocks of western Oaxaca range from 0.7042 to 0.7054 and ??Nd values, from -3.0 to +2.4, and for the volcanic rocks, from 0.7042 to 0.7046 and 0 +2.6. The range of these isotope ratios and those reported for the basement rocks in this region suggest a relatively low degree of old crustal involvement for most of the studied rocks. The Pb isotopic compositions of the Tertiary magmatic rocks also show a narrow range [(206Pb/204Pb) = 18.67-18.75; (207Pb/204Pb) = 15.59-15.62; (208Pb/204Pb) = 38.44-38.59], suggesting a similar source region for the volcanic and plutonic rocks. Trace elements and isotopic compositions suggest a mantle source in the subcontinental lithosphere that has been enriched by a subduction component. General tectonic features in this region indicate a more active rate of transtensional deformation for the inland volcanic region than along the coastal margin during the main events of Oligocene magmatism. The lower degree of differentiation of the inland volcanic sequences, particularly the upper unit of the northern sector, compared to the plutons of the coastal margin, suggests that the differentiation of the Tertiary magmas in southern Mexico was controlled to a great extent by the characteristics of the different strain domains. (C) 2000 Elsevier Science B.V. All rights reserved.

Comparison of ground-based measurements of natural radiation to airborne radiation survey data on transects from coastal California to the Colorado Plateau

NASA Astrophysics Data System (ADS)

Stoffer, P. W.; Hernández, L.; Messina, P.; Dearaujo, J.; Li, A.; Hicks, A.; White, L.

2008-12-01

Natural gamma radiation measurements were collected with a hand-held Geiger counter at nearly 400 locations on two general transects across the southwestern United States. The data are used to provide ground-truth comparison to published airborne radiation surveys of the region. The first transect was collected by high school students in the SF-ROCKS program at San Francisco State University in the summer of 2008 starting in San Francisco. Data were collected across the Sierra Nevada Range on I-80, and across Highway 50 in Nevada, and I-70 in Utah. Data were collected in and around Great Basin, Arches, Capitol Reef, Bryce, and Zion National Parks, and Grand Staircase-Escalante National Monument. A second transect extends from San José, California to Flagstaff, Arizona and includes the Mojave National Reserve, Death Valley region, and locations throughout the Navajo Reservation region in northern Arizona and western New Mexico. Radiation data (with GPS reference) were collected from all the major sedimentary rock formations and igneous rocks of the Colorado Plateau and from many igneous and metamorphic rocks throughout the Great Basin and southern California deserts. Anomalously high localized levels were noted in selected sedimentary units associated with uranium exploration targets in the Colorado Plateau region, and in caverns and rock fissures where radon gas (and accumulation of derivative fission products) are the inferred sources.

Evaluation of lunar rocks and soils for resource utilization: Detailed image analysis of raw materials and beneficiated products

NASA Technical Reports Server (NTRS)

Taylor, Lawrence A.; Chambers, John G.; Patchen, Allan; Jerde, Eric A.; Mckay, David S.; Graf, John; Oder, Robin R.

1993-01-01

The rocks and soils of the Moon will be the raw materials for fuels and construction needs at a lunar base. This includes sources of materials for the generation of hydrogen, oxygen, metals, and other potential construction materials. For most of the bulk material needs, the regolith, and its less than 1 cm fraction, the soil, will suffice. But for specific mineral resources, it may be necessary to concentrate minerals from rocks or soils, and it is not always obvious which is the more appropriate feedstock. Besides an appreciation of site geology, the mineralogy and petrography of local rocks and soils is important for consideration of the resources which can provide feedstocks of ilmenite, glass, agglutinates, anorthite, etc. In such studies, it is very time-consuming and practically impossible to correlate particle counts (the traditional method of characterizing lunar soil petrography) with accurate modal analyses and with mineral associations in multi-mineralic grains. But x ray digital imaging, using x rays characteristic of each element, makes all this possible and much more (e.g., size and shape analysis). An application of beneficiation image analysis, in use in our lab (Oxford Instr. EDS and Cameca SX-50 EMP), was demonstrated to study mineral liberation from lunar rocks and soils. Results of x ray image analysis are presented.

Hydrocarbon potential of the Early Oligocene Menilite shales in the Eastern Outer Carpathians (Tarcău and Vrancea Nappes, Romania)

NASA Astrophysics Data System (ADS)

Wendorff, Małgorzata; Rospondek, Mariusz; Kluska, Bartosz; Marynowski, Leszek

2017-04-01

During Oligocene to early Miocene time an extensive accumulation of organic-rich sedimentary rocks occurred in entire Paratethyan Basin, including its central part, i.e. the Carpathian Foredeep basin. Rocks of so-called Menilite facies formed there, burying significant amounts of organic matter (OM). These Menilite shales are now widely considered as a source of hydrocarbons throughout the Carpathian region. For the purpose of presented study, rock samples of the Menilite facies (mainly of the Lower Menilite and Bituminous Marl Members) were collected from two sections located in the different tectonic units (the Tarcău and Vrancea Nappes, Romania) of the Outer Carpathians. The main goal of the study was to assess and compare their hydrocarbon potential by examination of bulk geochemistry (total organic carbon content, pyrolysis Rock-Eval), vitrinite reflectance (Ro) and application of lipid biomarker parameters. The data show high variability in OM quantity and quality. Total organic carbon (TOC) content reaches peak values in the siliceous facies of the Lower Menilite Member (up to 8.6 wt% TOC), which contains type II kerogen represented by mainly marine OM type. Such results are confirmed by the presence of short-chain n-alkanes and hopanes. Mixed type II/III kerogen gains importance together with increasing contribution of turbiditic sedimentation. Terrigenous input is marked by occurrence of conifer aromatic biomarkers (such as simonellite, retene and 1,2,3,4-tetrahydroretene) and odd over even long chain n-alkanes predominance, characteristic for epicuticular leaf waxes. The analysed source rocks can be classified as oil-prone and subordinately mixed oil/gas-prone. OM in the inner tectonic unit (Tarcău Nappe; Tmax 430° C, Ro 0.5%) reaches onset of hydrocarbon generation, while in the outer unit (Vrancea Nappe) OM is immature (Tmax 425° C, Ro 0.4%). This maturity trend may be an effect of different burial histories of these units, as well as variation in subsequent erosion and exhumation levels resulting from the more inner position of the Tarcău Nappe within the orogen relative to the Vrancea Nappe (Wendorff et al., 2017). Based on the TOC content, S1 and S2 peak values the investigated rocks from the Vrancea Nappe reveal good to even excellent petroleum potential (especially for the siliceous facies of the Lower Menilite Mb.), although they did not attain the oil-window stage. The Tarcău Nappe source rocks have fair to good hydrocarbon potential. Hydrocarbons have been locally generated due to sufficient maturity, as also confirmed by high extractable bitumen yields and field observation of solid bitumen veins. However, hydrocarbon potential has not been exhausted as revealed by still high hydrocarbon index values. In the studied area the rocks of the Menilite facies have been suggested as a source for small gas/oil deposits, i.e. the Cuejdiu and Moineşti/Comăneşti field. References Wendorff, M., Rospondek, M., Kluska, B., Marynowski, L., 2017. Organic matter maturity and hydrocarbon potential of the Lower Oligocene Menilite facies in the Eastern Flysch Carpathians (Tarcău and Vrancea Nappes), Romania. Applied Geochemistry (in press).

Petrogenesis of postcollisional magmatism at Scheelite Dome, Yukon, Canada: Evidence for a lithospheric mantle source for magmas associated with intrusion-related gold systems

USGS Publications Warehouse

Mair, John L.; Farmer, G. Lang; Groves, David I.; Hart, Craig J.R.; Goldfarb, Richard J.

2011-01-01

The type examples for the class of deposits termed intrusion-related gold systems occur in the Tombstone-Tungsten belt of Alaska and Yukon, on the eastern side of the Tintina gold province. In this part of the northern Cordillera, extensive mid-Cretaceous postcollisional plutonism took place following the accretion of exotic terranes to the continental margin. The most cratonward of the resulting plutonic belts comprises small isolated intrusive centers, with compositionally diverse, dominantly potassic rocks, as exemplified at Scheelite Dome, located in central Yukon. Similar to other spatially and temporally related intrusive centers, the Scheelite Dome intrusions are genetically associated with intrusion-related gold deposits. Intrusions have exceptional variability, ranging from volumetrically dominant clinopyroxene-bearing monzogranites, to calc-alkaline minettes and spessartites, with an intervening range of intermediate to felsic stocks and dikes, including leucominettes, quartz monzonites, quartz monzodiorites, and granodiorites. All rock types are potassic, are strongly enriched in LILEs and LREEs, and feature high LILE/HFSE ratios. Clinopyroxene is common to all rock types and ranges from salite in felsic rocks to high Mg augite and Cr-rich diopside in lamprophyres. Less common, calcic amphibole ranges from actinolitic hornblende to pargasite. The rocks have strongly radiogenic Sr (initial 87Sr/86Sr from 0.711-0.714) and Pb isotope ratios (206Pb/204Pb from 19.2-19.7), and negative initial εNd values (-8.06 to -11.26). Whole-rock major and trace element, radiogenic isotope, and mineralogical data suggest that the felsic to intermediate rocks were derived from mafic potassic magmas sourced from the lithospheric mantle via fractional crystallization and minor assimilation of metasedimentary crust. Mainly unmodified minettes and spessartites represent the most primitive and final phases emplaced. Metasomatic enrichments in the underlying lithospheric mantle are attributes of the ancient North American cratonic margin that appear to be essential prerequisites to this style of postcollisional magmatism and associated gold-rich fluid exsolution. This type of magmatic hydrothermal activity occurs in a very specific tectonic setting that typically sets intrusion-related gold deposits apart from orogenic gold deposits, which are synorogenic in timing and have no consistent direct relationship to such diverse and contemporaneous lithospheric mantle-derived magmas, although they too are commonly sited adjacent to lithospheric boundaries.

An integrated management tool for rockfall evaluation along transportation corridors: the ParaChute research project

NASA Astrophysics Data System (ADS)

Cloutier, Catherine; Locat, Jacques; Mayers, Mélanie; Noël, François; Turmel, Dominique; Jacob, Chantal; Dorval, Pierre; Bossé, François; Gionet, Pierre; Jaboyedoff, Michel

2016-04-01

Rockfall is a significant hazard along linear infrastructures due to the presence of natural and man-made rock slopes. Knowing where the problematic rockfalls source areas are is of primary importance to properly manage and mitigate the risk associated to rockfall along linear infrastructures. The aim of the ParaChute research project is to integrate various technologies into a workflow for rockfall characterization for such infrastructures, using a 220 km-long railroad as the study site which is located on Québec's North Shore, Canada. The objectives of this 3-year project which started in 2014 are: (1) to optimize the use of terrestrial, mobile and airborne laser scanners data into terrain analysis, structural geology analysis and rockfall susceptibility rating, (2) to further develop the use of unmanned aerial vehicles (UAV) for photogrammetry applied to rock cliff characterization, and (3) to integrate rockfall simulation studies into a rock slope classification system similar to the Rockfall Hazard Rating System. Firstly, based on laser scanner data and aerial photographs, the morpho-structural features of the terrain (genetic material, landform, drainage, etc.) are mapped. The result can be used to assess all types of mass movements. Secondly, to guide field work and decrease uncertainty of various parameters, systematic rockfall simulations and a first structural analysis are made from point clouds acquired by mobile and airborne laser scanner. The simulation results are used to recognize the rock slopes that have potentially problematic rockfall paths, meaning they could reach the linear infrastructure. Other rock slopes are not included in the inventory. Field work is carried out to validate and complete the rock slopes characterization previously made from remote sensing technique. Because some or parts of cliffs are not visible or accessible from the railroad, we are currently developing the use of photogrammetry by UAV in order to complete the characterization of these rock slopes. At a cliff scale, joint sets orientation and spacing were quantified to identify failure mechanisms and evaluate the most active rockfall areas in order to define susceptibility criteria at that scale. Finally, using all these information, a system will be developed offering, in graphical form, a way to systematically assess rockfall sources and support the development of a dynamic mitigation strategy.

Multiple stable isotope fronts during non-isothermal fluid flow

NASA Astrophysics Data System (ADS)

Fekete, Szandra; Weis, Philipp; Scott, Samuel; Driesner, Thomas

2018-02-01

Stable isotope signatures of oxygen, hydrogen and other elements in minerals from hydrothermal veins and metasomatized host rocks are widely used to investigate fluid sources and paths. Previous theoretical studies mostly focused on analyzing stable isotope fronts developing during single-phase, isothermal fluid flow. In this study, numerical simulations were performed to assess how temperature changes, transport phenomena, kinetic vs. equilibrium isotope exchange, and isotopic source signals determine mineral oxygen isotopic compositions during fluid-rock interaction. The simulations focus on one-dimensional scenarios, with non-isothermal single- and two-phase fluid flow, and include the effects of quartz precipitation and dissolution. If isotope exchange between fluid and mineral is fast, a previously unrecognized, significant enrichment in heavy oxygen isotopes of fluids and minerals occurs at the thermal front. The maximum enrichment depends on the initial isotopic composition of fluid and mineral, the fluid-rock ratio and the maximum change in temperature, but is independent of the isotopic composition of the incoming fluid. This thermally induced isotope front propagates faster than the signal related to the initial isotopic composition of the incoming fluid, which forms a trailing front behind the zone of transient heavy oxygen isotope enrichment. Temperature-dependent kinetic rates of isotope exchange between fluid and rock strongly influence the degree of enrichment at the thermal front. In systems where initial isotope values of fluids and rocks are far from equilibrium and isotope fractionation is controlled by kinetics, the temperature increase accelerates the approach of the fluid to equilibrium conditions with the host rock. Consequently, the increase at the thermal front can be less dominant and can even generate fluid values below the initial isotopic composition of the input fluid. As kinetics limit the degree of isotope exchange, a third front may develop in kinetically limited systems, which propagates with the advection speed of the incoming fluid and is, therefore, traveling fastest. The results show that oxygen isotope signatures at thermal fronts recorded in rocks and veins that experienced isotope exchange with fluids can easily be misinterpreted, namely if bulk analytical techniques are applied. However, stable isotope microanalysis on precipitated minerals may - if later isotope exchange is kinetically limited - provide a valuable archive of the transient thermal and hydrological evolution of a system.

Analysis and occurrence of C sub 26 -steranes in petroleum and source rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moldowan, J.M.; Lee, C.Y.; Gallegos, E.J.

1991-04-01

The C{sub 26}-steranes previously reported in oils and source rocks have been identified as 21-, 24-, and 27-norcholestanes (1A, 1B, and 1C). Various 24-norcholesterols or stanols, possible prescursors for the 24-norcholestanes, occur widely at low levels in marine invertebrates and some algae, and 24-norcholestanes occur in marine petroleums of Tertiary through Paleozoic age. There are reports of 27-norcholesterols and stanols in recent sediments, but the precursor organisms have not been identified. The natural occurrence of the 21-norcholestane structure is unprecedented. Unlike 24- and 27-norcholestane, 21-norcholestane is in low concentration or absent in immature rocks and increases substantially relative to themore » other C{sub 26}-steranes in thermally mature rocks, oils, and condensates. This suggests an origin involving thermal degradation of a higher molecuar weight steroid. The ratio of 21-norcholestane to the total C{sub 26}-steranes is shown to be an effective maturity parameter in a series of Wyoming (Phosphoria source) and California (Monterey source) oils. Molecular mechanics MM2 steric energy calculations indicate a relative stability order of 21 {much gt} 27 > 24-norcholestane for the major stereoisomers. Authentic 21-, 24-, and 27-nor-5{alpha}-cholestanes and 24- and 27-nor-5{beta}-cholestanes were synthesized and subjected to catalytic isomerization over Pd/C to yield the full suite of stereoisomers for each.« less

Mantle contribution and tectonic transition in the Aqishan-Yamansu Belt, Eastern Tianshan, NW China: Insights from geochronology and geochemistry of Early Carboniferous to Early Permian felsic intrusions

NASA Astrophysics Data System (ADS)

Du, Long; Long, Xiaoping; Yuan, Chao; Zhang, Yunying; Huang, Zongying; Wang, Xinyu; Yang, Yueheng

2018-04-01

Late Paleozoic is a key period for the accretion and collision of the southern Central Asian Orogenic Belt (CAOB). Here, we present new zircon U-Pb ages, whole-rock geochemistry and Sr-Nd isotopic compositions for four Late Paleozoic felsic plutons in Eastern Tianshan (or Tienshan in some literatures) in order to constrain the tectonic evolution of the southern CAOB. The granodioritic pluton and its dioritic enclaves were synchronously formed in the Early Carboniferous (336 ± 3 Ma and 335 ± 2 Ma, respectively). These rocks are depleted in Nb, Ta and Ti, and enriched in Rb, Ba, Th and U related to the primitive mantle, which show typical features of arc rocks. They both have similar Sr-Nd isotopic ratios to those granitic rocks from the eastern Central Tianshan Block and have the latest Mesoproterozoic two stage Nd model ages (TDM2) (1111-1195 Ma for the granodioritic pluton and 1104-1108 Ma for the enclaves, respectively), indicating that their source magmas may have been derived from the Mesoproterozoic crust. The albitophyric pluton was also emplaced in the Early Carboniferous (333 ± 3 Ma). Rocks of this pluton have similar εNd(t) values (-0.69 to -0.37) and TDM2 ages (1135-1161 Ma) to those of the granodioritic rocks, suggest similar crustal source for both types of rocks. In contrast, the K-feldspar granitic and monzonitic plutons were emplaced in the Early Permian (292 ± 3 Ma and 281 ± 2 Ma, respectively). Samples of the K-feldspar granitic pluton have high K2O + Na2O, FeO/MgO, Ga/Al, HFSE (e.g., Zr and Hf) and low CaO, Sr and Ba, exhibiting characteristics of A2-type granites, which probably emplaced in a post-collisional extension environment. They have higher εNd(t) values (+2.77 to +3.27) and more juvenile TDM2 ages (799-841 Ma) than the Early Carboniferous plutons, suggesting that they were derived from relatively younger crustal sources. The monzonitic granites are metaluminous to weakly peraluminous with A/CNK ranging from 0.93 to 1.05, and have very low P2O5, indicating characteristics of I-type granites. They also have positive εNd(t) values (+2.22 to +2.34) and juvenile TDM2 ages (868-878 Ma), suggesting this pluton was also produced by partial melting of relatively young crustal source. Based on an isotopic mixing simulation, significant mantle contributions were added to the magma source of both the Early Carboniferous and the Early Permian felsic rocks. The mantle contribution changes from 60% in the Early Carboniferous to 75% in the Early Permian. The remarkably increasing of mantle materials in the magma source of the felsic rocks in the Aqishan-Yamansu belt was most likely induced by the tectonic transition from an Early Carboniferous continental arc to an Early Permian post-collisional extension environment.

Chlorine-36 tracing of salinity sources in the dry valleys of Victoria land, Antarctica

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carlson, C.A.; Phillips, F.M.; Elmore, D.

1990-02-01

Chlorine-36 was used to trace the origins of salts in six saline lakes in the Dry Valleys of Southern Victoria Land, Antarctica. Characteristic {sup 36}Cl signatures were estimated for the various potential chloride sources, which include atmospheric deposition, rock weathering, seawater, and deep ground water. {sup 36}Cl/Cl ratios were measured in natural waters and salts from the Dry Valleys. Dilute lake waters (Cl{sup {minus}} < 100 mg/l) were found to have {sup 36}Cl/Cl ratios in the range 100 {times} 10{sup {minus}15} to 1,700 {times} 10{sup {minus}15}, whereas saline waters (Cl{sup {minus}} > 1000 mg/l) had ratios in the range 9more » {times} 10{sup {minus}15} to 40 {times} 10{sup {minus}15}. Simple mixing models were employed to quantify the relative contributions of the various chloride sources to Lake Vanda and Don Juan Pond. These results show that Lake Vanda has received its chloride from both deep ground water and the Onyx River. Don Juan Pond has received nearly all its chloride from deep ground water, probably ultimately from rock-water interaction. Deep ground water is the principal sources of chloride to the lakes of Wright Valley. However, preliminary data suggest that marine-derived salts or relict sea water may be a significant sources of chloride to the lakes of Taylor Valley, implying a possible recent marine invasion that did not affect Wright Valley.« less

Karst mapping in the United States: Past, present and future

USGS Publications Warehouse

Weary, David J.; Doctor, Daniel H.

2015-01-01

The earliest known comprehensive karst map of the entire USA was published by Stringfield and LeGrand (1969), based on compilations of William E. Davies of the U.S. Geological Survey (USGS). Various versions of essentially the same map have been published since. The USGS recently published new digital maps and databases depicting the extent of known karst, potential karst, and pseudokarst areas of the United States of America including Puerto Rico and the U.S. Virgin Islands (Weary and Doctor, 2014). These maps are based primarily on the extent of potentially karstic soluble rock types, and rocks with physical properties conducive to the formation of pseudokarst features. These data were compiled and refined from multiple sources at various spatial resolutions, mostly as digital data supplied by state geological surveys. The database includes polygons delineating areas with potential for karst and that are tagged with attributes intended to facilitate classification of karst regions. Approximately 18% of the surface of the fifty United States is underlain by significantly soluble bedrock. In the eastern United States the extent of outcrop of soluble rocks provides a good first-approximation of the distribution of karst and potential karst areas. In the arid western states, the extent of soluble rock outcrop tends to overestimate the extent of regions that might be considered as karst under current climatic conditions, but the new dataset encompasses those regions nonetheless. This database will be revised as needed, and the present map will be updated as new information is incorporated.

A novel molecular index for secondary oil migration distance

PubMed Central

Zhang, Liuping; Li, Maowen; Wang, Yang; Yin, Qing-Zhu; Zhang, Wenzheng

2013-01-01

Determining oil migration distances from source rocks to reservoirs can greatly help in the search for new petroleum accumulations. Concentrations and ratios of polar organic compounds are known to change due to preferential sorption of these compounds in migrating oils onto immobile mineral surfaces. However, these compounds cannot be directly used as proxies for oil migration distances because of the influence of source variability. Here we show that for each source facies, the ratio of the concentration of a select polar organic compound to its initial concentration at a reference point is independent of source variability and correlates solely with migration distance from source rock to reservoir. Case studies serve to demonstrate that this new index provides a valid solution for determining source-reservoir distance and could lead to many applications in fundamental and applied petroleum geoscience studies. PMID:23965930

Petrogenesis of basaltic volcanic rocks from the Pribilof Islands, Alaska, by melting of metasomatically enriched depleted lithosphere, crystallization differentiation, and magma mixing

USGS Publications Warehouse

Chang, J.M.; Feeley, T.C.; Deraps, M.R.

2009-01-01

The Pribilof Islands, Alaska, are located in the Bering Sea in a continental intraplate setting. In this study we examine the petrology and geochemistry of volcanic rocks from St. Paul (0??54-0??003 Ma) and St. George (2??8-1??4 Ma) Islands, the two largest Pribilof Islands. Rocks from St. George can be divided into three groups: group 1 is a high-MgO, low-SiO. 2 suite composed primarily of basanites; group 2 is a high-MgO, high-SiO 2 suite consisting predominantly of alkali basalts; group 3 is an intermediate- to low-MgO suite that includes plagioclase-phyric subalkali basalts and hawaiites. Major and trace element geochemistry suggests that groups 1 and 2 formed by small-degree partial melting of amphibole-bearing to amphibole-free garnet peridotite. Group 1 rocks were the earliest melts produced from the most hydrous parts of the mantle, as they show the strongest geochemical signature of amphibole in their source. The suite of rocks from St. Paul ranges from 14??4 to 4??2 wt % MgO at relatively constant SiO 2 contents (43??1-47??3 wt %). The most primitive St. Paul rocks are modeled as mixtures between magmas with compositions similar to groups 1 and 2 from St. George Island, which subsequently fractionated olivine, clinopyroxene, and spinel to form more evolved rocks. Plagioclase-phyric group 3 rocks from St. George are modeled as mixtures between an evolved melt similar to the evolved magmas on St. Paul and a fractionated group 2 end-member from St. George. Mantle potential temperatures estimated for primitive basanites and alkali basalts are ???1400??C and are similar to those of mid-ocean ridge basalts (MORB). Similarly, 87Sr/. 86Sr and 143Nd/. 144Nd values for all rocks are MORB-like, in the range of 0??702704-0??703035 and 0??513026-0??513109, respectively. 208Pb/. 204Pb vs 206Pb/. 204Pb values lie near the MORB end-member but show a linear trend towards HIMU (high time-integrated 238U/. 204Pb). Despite isotopic similarities to MORB, many of the major and trace element characteristics are similar to those of ocean island basalts (OIB), including enrichment in alkalis and incompatible trace elements. These characteristics are interpreted to indicate that their mantle source experienced an ancient melt-removal event that is reflected in depleted radiogenic isotopic compositions and was then re-enriched by metasomatism that elevated incompatible trace element contents, but was too young to produce a time-integrated change in radiogenic isotopic ratios. Evidence suggests that the Pribilof Island basalts did not form in either a plume or a back-arc basin tectonic setting. Rather, they were produced by melting of metasomatically hydrated upper mantle peridotite at relatively low temperatures and were able to erupt at the surface through extensional or transtensional faults that served as conduits for the magmas. ?? The Author 2009. Published by Oxford University Press.

Ferromanganese crusts and nodules, rocks that grow

USGS Publications Warehouse

Mizell, Kira; Hein, James

2016-01-01

Ferromanganese (Fe-Mn) crusts and nodules are marine sed- imentary mineral deposits, composed mostly of iron and manganese oxides. They precipitate very slowly from seawa- ter, or for nodules also from deep-sea sediment pore waters, recording the chemical signature of these source waters as they grow. Additional elements incorporate via sorption pro- cesses onto the Fe-Mn oxides, including rare and valuable metals that can reach concentrations that are economically valuable.

Neodymium isotopic study of rare earth element sources and mobility in hydrothermal Fe-oxide (Fe-P-REE) systems

NASA Astrophysics Data System (ADS)

Gleason, James D.; Marikos, Mark A.; Barton, Mark D.; Johnson, David A.

2000-03-01

Rare earth element (REE)-enriched, igneous-related hydrothermal Fe-oxide hosted (Fe-P-REE) systems from four areas in North America have been analyzed for their neodymium isotopic composition to constrain REE sources and mobility in these systems. The Nd isotopic results evidence a common pattern of REE concentration from igneous sources despite large differences in age (Proterozoic to Tertiary), tectonic setting (subduction vs. intraplate), and magmatic style (mafic vs. felsic). In the Middle Proterozoic St. Francois Mountains terrane of southeastern Missouri, ɛ Nd for Fe-P-REE (apatite, monazite, xenotime) deposits ranges from +3.5 to +5.1, similar to associated felsic to intermediate igneous rocks of the same age (ɛ Nd = +2.6 to +6.2). At the mid-Jurassic Humboldt mafic complex in western Nevada, ɛ Nd for Fe-P-REE (apatite) mineralization varies between +1.1 and +2.4, similar to associated mafic igneous rocks (-1.0 to +3.5). In the nearby Cortez Mountains in central Nevada, mid-Jurassic felsic volcanic and plutonic rocks (ɛ Nd = -2.0 to -4.4) are associated with Fe-P-REE (apatite-monazite) mineralization having similar ɛ Nd (-1.7 to -2.4). At Cerro de Mercado, Durango, Mexico, all assemblages analyzed in this Tertiary rhyolite-hosted Fe oxide deposit have identical isotopic compositions with ɛ Nd = -2.5. These data are consistent with coeval igneous host rocks being the primary source of REE in all four regions, and are inconsistent with a significant contribution of REE from other sources. Interpretations of the origin of these hydrothermal systems and their concomitant REE mobility must account for nonspecialized igneous sources and varied tectonic settings.

Neodymium isotopic study of rare earth element sources and mobility in hydrothermal Fe oxide (Fe-P-REE) systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gleason, J.D.; Marikos, M.A.; Barton, M.D.

2000-03-01

Rare earth element (REE)-enriched, igneous-related hydrothermal Fe-oxide hosted (Fe-P-REE) systems from four areas in North America have been analyzed for their neodymium iosotopic composition to constrain REE sources and mobility in these systems. The Nd isotopic results evidence a common pattern of REE concentration from igneous sources despite large differences in age (Proterozoic to Tertiary), tectonic setting (subduction vs. intraplate), and magmatic style (mafic vs. felsic). In the Middle Proterozoic St. Francois Mountains terrane of southeastern Missouri, {epsilon}{sub Nd} for Fe-P-REE (apatite, monazite, xenotime) deposits ranges from +3.5 to +5.1, similar to associated felsic to intermediate igneous rocks of themore » same age ({epsilon}{sub Nd} = +2.6 to +6.2). At the mid-Jurassic Humboldt mafic complex in western Nevada, {epsilon}{sub Nd} for Fe-P-REE (apatite) mineralization varies between +1.1 and +2.4, similar to associated mafic igneous rocks ({minus}1.0 to +3.5). In the nearby Cortez Mountains in central Nevada, mid-Jurassic felsic volcanic and plutonic rocks ({epsilon}{sub Nd} = {minus}2.0 to {minus}4.4) are associated with Fe-P-REE (apatite-monazite) mineralization having similar {epsilon}{sub Nd}({minus}1.7 to {minus}2.4). At Cerro de Mercado, Durango, Mexico, all assemblages analyzed in this Tertiary rhyolite-hosted Fe oxide deposit have identical isotopic compositions with {epsilon}{sub Nd} = {minus}2.5. These data are consistent with coeval igneous host rocks being the primary source of REE in all four regions, and are inconsistent with a significant contribution of REE from other sources. Interpretations of the origin of these hydrothermal systems and their concomitant REE mobility must account for nonspecialized igneous sources and varied tectonic settings.« less

Biofiltration of methane using hybrid mixtures of biochar, lava rock and compost.

PubMed

La, Helen; Hettiaratchi, J Patrick A; Achari, Gopal; Verbeke, Tobin J; Dunfield, Peter F

2018-05-21

Using hybrid packing materials in biofiltration systems takes advantage of both the inorganic and organic properties offered by the medium including structural stability and a source of available nutrients, respectively. In this study, hybrid mixtures of compost with either lava rock or biochar in four different mixture ratios were compared against 100% compost in a methane biofilter with active aeration at two ports along the height of the biofilter. Biochar outperformed lava rock as a packing material by providing the added benefit of participating in sorption reactions with CH 4 . This study provides evidence that a 7:1 volumetric mixture of biochar and compost can successfully remove up to 877 g CH 4 /m 3 ·d with empty-bed residence times of 82.8 min. Low-affinity methanotrophs were responsible for the CH 4 removal in these systems (K M(app) ranging from 5.7 to 42.7 µM CH 4 ). Sequencing of 16S rRNA gene amplicons indicated that Gammaproteobacteria methanotrophs, especially members of the genus Methylobacter, were responsible for most of the CH 4 removal. However, as the compost medium was replaced with more inert medium, there was a decline in CH 4 removal efficiency coinciding with an increased dominance of Alphaproteobacteria methanotrophs like Methylocystis and Methylocella. As a biologically-active material, compost served as the sole source of nutrients and inoculum for the biofilters which greatly simplified the operation of the system. Higher elimination capacities may be possible with higher compost content such as a 1:1 ratio of either biochar or lava rock, while maintaining the empty-bed residence time at 82.8 min. Copyright © 2018 Elsevier Ltd. All rights reserved.

The ammonium content in the Malayer igneous and metamorphic rocks (Sanandaj-Sirjan Zone, Western Iran)

NASA Astrophysics Data System (ADS)

Ahadnejad, Vahid; Hirt, Ann Marie; Valizadeh, Mohammad-Vali; Bokani, Saeed Jabbari

2011-04-01

The ammonium (NH4+) contents of the Malayer area (Western Iran) have been determined by using the colorimetric method on 26 samples from igneous and metamorphic rocks. This is the first analysis of the ammonium contents of Iranian metamorphic and igneous rocks. The average ammonium content of metamorphic rocks decreases from low-grade to high-grade metamorphic rocks (in ppm): slate 580, phyllite 515, andalusite schist 242. In the case of igneous rocks, it decreases from felsic to mafic igneous types (in ppm): granites 39, monzonite 20, diorite 17, gabbro 10. Altered granitic rocks show enrichment in NH4+ (mean 61 ppm). The high concentration of ammonium in Malayer granites may indicate metasedimentary rocks as protoliths rather than meta-igneous rocks. These granitic rocks (S-types) have high K-bearing rock-forming minerals such as biotite, muscovite and K-feldspar which their potassium could substitute with ammonium. In addition, the high ammonium content of metasediments is probably due to inheritance of nitrogen from organic matter in the original sediments. The hydrothermally altered samples of granitic rocks show highly enrichment of ammonium suggesting external sources which intruded additional content by either interaction with metasedimentary country rocks or meteoritic solutions.

Estimating carbon and nitrogen pools in a forest soil: Influence of soil bulk density methods and rock content

Treesearch

Martin F. Jurgensen; Deborah S. Page-Dumroese; Robert E. Brown; Joanne M. Tirocke; Chris A. Miller; James B. Pickens; Min Wang

2017-01-01

Soils with high rock content are common in many US forests, and contain large amounts of stored C. Accurate measurements of soil bulk density and rock content are critical for calculating and assessing changes in both C and nutrient pool size, but bulk density sampling methods have limitations and sources of variability. Therefore, we evaluated the use of small-...

Total petroleum systems and geologic assessment of undiscovered oil and gas resources in the San Juan Basin Province, exclusive of Paleozoic rocks, New Mexico and Colorado

USGS Publications Warehouse

,

2013-01-01

In 2002, the U.S. Geological Survey (USGS) estimated undiscovered oil and gas resources that have the potential for additions to reserves in the San Juan Basin Province, New Mexico and Colorado. Paleozoic rocks were not appraised. The last oil and gas assessment for the province was in 1995. There are several important differences between the 1995 and 2002 assessments. The area assessed is smaller than that in the 1995 assessment. This assessment of undiscovered hydrocarbon resources in the San Juan Basin Province also used a slightly different approach in the assessment, and hence a number of the plays defined in the 1995 assessment are addressed differently in this report. After 1995, the USGS has applied a total petroleum system (TPS) concept to oil and gas basin assessments. The TPS approach incorporates knowledge of the source rocks, reservoir rocks, migration pathways, and time of generation and expulsion of hydrocarbons; thus the assessments are geologically based. Each TPS is subdivided into one or more assessment units, usually defined by a unique set of reservoir rocks, but which have in common the same source rock. Four TPSs and 14 assessment units were geologically evaluated, and for 13 units, the undiscovered oil and gas resources were quantitatively assessed.

Characterization of phosphorus leaching from phosphate waste rock in the Xiangxi River watershed, Three Gorges Reservoir, China.

PubMed

Jiang, Li-Guo; Liang, Bing; Xue, Qiang; Yin, Cheng-Wei

2016-05-01

Phosphate mining waste rocks dumped in the Xiangxi River (XXR) bay, which is the largest backwater zone of the Three Gorges Reservoir (TGR), are treated as Type I industry solid wastes by the Chinese government. To evaluate the potential pollution risk of phosphorus leaching from phosphate waste rocks, the phosphorus leaching behaviors of six phosphate waste rock samples with different weathering degrees under both neutral and acidic conditions were investigated using a series of column leaching experiments, following the Method 1314 standard of the US EPA. The results indicate that the phosphorus release mechanism is solubility-controlled. Phosphorus release from waste rocks increases as pH decreases. The phosphorus leaching concentration and cumulative phosphorus released in acidic leaching conditions were found to be one order of magnitude greater than that in neutral leaching conditions. In addition, the phosphorus was released faster during the period when environmental pH turned from weak alkalinity to slight acidity, with this accelerated release period appearing when L/S was in the range of 0.5-2.0 mL/g. In both neutral and acidic conditions, the average values of Total Phosphorus (TP), including orthophosphates, polyphosphates and organic phosphate, leaching concentration exceed the availability by regulatory (0.5 mg/L) in the whole L/S range, suggesting that the phosphate waste rocks stacked within the XXR watershed should be considered as Type II industry solid wastes. Therefore, the phosphate waste rocks deposited within the study area should be considered as phosphorus point pollution sources, which could threaten the adjacent surface-water environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

Geochemical Aspects of Formation of Large Oil Deposits in the Volga-Ural Sedimentary Basin

NASA Astrophysics Data System (ADS)

Plotnikova, I.; Nosova, F.; Pronin, N.; Nosova, J.; Budkevich, T.

2012-04-01

The study of the rocks domanikoid type in the territory of the Ural-Volga region has an almost century-long history, beginning with the first studies of A.D. Archangelsky in the late 20's of last century. But nevertheless the question of the source of oil that formed the industrial deposits of Volga-Ural oil and gas province (OGP), where Romashkinskoye oil field occupies a special place, remains unresolved and topical. According to the sedimentary-migration theory of origin of oil and gas, it is supposed that the primary source of hydrocarbons in this area are the deposits of domanikoid type that contain a large ammount of sapropel organic matter (OM). Semiluki (domanik) horizon of srednefranski substage of the Upper Devonian is considered to be a typical domanikoid stratum. Investigation of the OM of the rocks and oils of the sedimentary cover on the basis of chromato-mass spectrometry method allows us to study the correlations between rock and oil and to assess the location (or absence) of the sources of hydrocarbons in the Paleozoic sedimentary cover. The results of geochemical study of dispersed organic matter (DOM) of rocks from Semiluksky horizon of the Upper Devonian and of the oil from Pashiysky horizon of the Middle Devonian form the basis of this paper. The objectives of this study were the following: to determine the original organic matter of the rocks, which would indicate the conditions of sedimentation of the supposed rock-oil sources; the study of chemofossils (biomarkers) in oil from Pashiyskiy horizon; and the identification of genetic association of DOM rocks from Semiluksky horizon with this oil on the basis of the oil-DOM correlation. The study of biomarkers was carried out with the help of chromato-mass spectrometry in the Laboratory of Geochemistry of Fossil Fuels (Kazan Federal University). In this study we used several informative parameters characterizing the depositional environment, the type of source OM and its maturity: STER / PENT, hC35/hC34, GAM / HOP, S27/S28/S29 (steranes), DIA / REG, Ts / Tm, MOR / HOP, NOR / HOP, TET / TRI, C29SSR, C29BBAA, C31HSR, S30STER, TRI / PENT, TRI / HOP. Comparison in the rock-oil system was performed primarily according to the parameters indicating the depositional environment of the source rock that contains syngenetic DOM - according to the coefficients that determine lithological conditions for the formation of the supposed oil-source bed strata (DIA / REG, Ts / Tm, NOR / HOP, TRI / HOP and STER / PENT). Biomarker ratios indicate a different type of sedimentation basins. Sediments, which accumulated DOM from Semilukskiy horizon, can be characterized by low clay content, or its absence, that is consistent with the carbonate type of cut of the horizon. The bacterial material that was accumulated under reducing conditions of sedimentation appeared to be the source of syngenetic OM. Chemofossils found in oils from Pashiyskiy horizon are typical of sedimentary strata that contain clay - for clastic rocks, which in the study area are mainly represented by deposits and Eyfel Givetian layers of the Middle Devonian and lowfransk substage of the Upper Devonian. The study of correlations obtained for the different coefficients of OM and oils showed that only the relationships between Ts/Tm and DIA/REG and between NOR/HOP and TRI/HOP are characteristic of close, almost similar values of correlation both for the dispersed organic matter and for oil. In all other cases, the character of the correlation of OM is significantly different from that of oil. The differences in values and ranges of biomarker ratios as well as the character of their correlation indicates the absence of genetic connection between the oil from Pashiyskiy horizon for the dispersed organic matter from Semilukskiy horizon. This conclusion is based on the study of five biomarker parameters (DIA/REG, Ts/Tm, NOR/HOP, TRI/HOP and STER/PENT). The research results described in the article clearly indicate the need for further studies of geochemical features of the organic matter of the Paleozoic mantle rocks and the underlying sedimentary and crystalline complexes of Precambrian.

Geochemical constraints on the spatial distribution of recycled oceanic crust in the mantle source of late Cenozoic basalts, Vietnam

NASA Astrophysics Data System (ADS)

Hoang, Thi Hong Anh; Choi, Sung Hi; Yu, Yongjae; Pham, Trung Hieu; Nguyen, Kim Hoang; Ryu, Jong-Sik

2018-01-01

This study presents a comprehensive analysis of the major and trace element, mineral, and Sr, Nd, Pb and Mg isotopic compositions of late Cenozoic intraplate basaltic rocks from central and southern Vietnam. The Sr, Nd, and Pb isotopic compositions of these basalts define a tight linear array between Indian mid-ocean-ridge basalt (MORB)-like mantle and enriched mantle type 2 (EM2) components. These basaltic rocks contain low concentrations of CaO (6.4-9.7 wt%) and have high Fe/Mn ratios (> 60) and FeO/CaO-3MgO/SiO2 values (> 0.54), similar to partial melts derived from pyroxenite/eclogite sources. This similarity is also supported by the composition of olivine within these samples, which contains low concentration of Ca and high concentrations of Ni, and shows high Fe/Mn ratios. The basaltic rocks have elevated Dy/Yb ratios that fall within the range of melts derived from garnet lherzolite material, although their Yb contents are much higher than those of modeled melts derived from only garnet lherzolite material and instead plot near the modeled composition of eclogite-derived melts. The Vietnamese basaltic rocks have lighter δ26Mg values (- 0.38 ± 0.06‰) than is expected for the normal mantle (- 0.25 ± 0.07‰), and these values decrease with decreasing Hf/Hf* and Ti/Ti* ratios, indicating that these basalts were derived from a source containing carbonate material. On primitive mantle-normalized multi-element variation diagrams, the central Vietnamese basalts are characterized by positive Sr, Eu, and Ba anomalies. These basalts also plot within the pelagic sediment field in Pbsbnd Pb isotopic space. This suggests that the mantle source of the basalts contained both garnet peridotite and recycled oceanic crust. A systematic analysis of variations in geochemical composition in basalts from southern to central Vietnam indicates that the recycled oceanic crust (possibly the paleo-Pacific slab) source material contains varying proportions of gabbro, basalt, and sediment. The basalts from south-central Vietnam (12°N-14°N) may be dominated by the lowest portion of the residual slab that contains rutile-bearing plagioclase-rich gabbroic eclogite, whereas the uppermost portion of the recycled slab, including sediment and basaltic material with small amounts of gabbro, may be a major constituent of the source for the basalts within the central region of Vietnam (14°N-16°N). Finally, the southern region (10°N-12°N) contains basalts sourced mainly from recycled upper oceanic crust that is basalt-rich and contains little or no sediment.

Hydrocarbon generation and expulsion in shale Vs. carbonate source rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leythaeuser, D.; Krooss, B.; Hillebrand, T.

1993-09-01

For a number of commercially important source rocks of shale and of carbonate lithologies, which were studied by geochemical, microscopical, and petrophysical techniques, a systematic comparison was made of the processes on how hydrocarbon generation and migration proceed with maturity progress. In this way, several fundamental differences between both types of source rocks were recognized, which are related to differences of sedimentary facies and, more importantly, of diagenetic processes responsible for lithification. Whereas siliciclastic sediments lithify mainly by mechanical compaction, carbonate muds get converted into lithified rocks predominantly by chemical diagenesis. With respect to their role as hydrocarbon source rocks,more » pressure solution processes appear to be key elements. During modest burial stages and prior to the onset of hydrocarbon generation reactions by thermal decomposition of kerogen, pressure solution seams and stylolites. These offer favorable conditions for hydrocarbon generation and expulsion-a three-dimensional kerogen network and high organic-matter concentrations that lead to effective saturation of the internal pore fluid system once hydrocarbon generation has started. As a consequence, within such zones pore fluids get overpressured, leading ultimately to fracturing. Petroleum expulsion can then occur at high efficiencies and in an explosive fashion, whereby clay minerals and residual kerogen particles are squeezed in a toothpaste-like fashion into newly created fractures. In order to elucidate several of the above outlined steps of hydrocarbon generation and migration processes, open-system hydrous pyrolysis experiments were performed. This approach permits one to monitor changes in yield and composition of hydrocarbon products generated and expelled at 10[degrees]C temperature increments over temperature range, which mimics in the laboratory the conditions prevailing in nature over the entire liquid window interval.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiefelbein, C.; Ho, T.

Changes in the physical properties (measured in terms of vitrinite reflectance, elemental analysis, and C-13 nuclear magnetic resonance) of an immature coal (0.46% R{sub o}) from Craig County, Colorado, that was thermally altered using hydrous pyrolysis were used to establish a correspondence between hydrous pyrolysis time/temperature reaction conditions and relative maturity (expressed in terms of vitrinite reflectance). This correspondence was used to determine the oil generation maturity limits for an immature hydrogen-rich (Type I fluorescing amorphous oil-prone kerogen) source rock from an offshore Congo well that was thermally altered using the same reaction conditions as applied to the immature coal.more » The resulting changes in the physical properties of the altered source rock, measured in terms of decreasing reactive carbon content (from Rock-Eval pyrolysis), were used to construct a hydrocarbon yield curve from which the relative maturity associated with the onset, main phase, and peak of oil generation was determined. Results, substantiated by anhydrous pyrolysis techniques, indicate that the source rock from Congo has a late onset of appreciable ({gt}10% transformation) oil generation (0.9% R{sub o} {plus minus} 0.1%), generates maximum quantities of oil from about 1.1 to 1.3% R{sub o}, and reaches the end (or peak) of the primary oil generating window at approximately 1.4% R{sub o} ({plus minus}0.1%) when secondary cracking reactions become important. However, the bottom of the oil window can be extended to about 1.6% R{sub o} because the heavy molecular weight degradation by-products (asphaltenes) that are not efficiently expelled from source rocks continue to degrade into progressively lower molecular weight hydrocarbons.« less

Landslides and rock fall processes in the proglacial area of the Gepatsch glacier, Tyrol, Austria - Quantitative assessment of controlling factors and process rates

NASA Astrophysics Data System (ADS)

Vehling, Lucas; Rohn, Joachim; Moser, Michael

2013-04-01

Due to the rapid deglaciation since 1850, lithological structures and topoclimatic factors, mass movements like rock fall, landslides and complex processes are important contributing factors to sediment transport and modification of the earth's surface in the steep, high mountain catchment of the Gepatsch reservoir. Contemporary geotechnical processes, mass movement deposits, their source areas, and controlling factors like material properties and relief parameters are mapped in the field, on Orthofotos and on digital elevation models. The results are presented in an Arc-Gis based geotechnical map. All mapped mass movements are stored in an Arc-Gis geodatabase and can be queried regarding properties, volume and controlling factors, so that statistical analyses can be conducted. The assessment of rock wall retreat rates is carried out by three different methods in multiple locations, which differ in altitude, exposition, lithology and deglaciation time: Firstly, rock fall processes and rates are investigated in detail on five rock fall collector nets with an overall size of 750 m2. Rock fall particles are gathered, weighed and grain size distribution is detected by sieving and measuring the diameter of the particles to distinct between rock fall processes and magnitudes. Rock wall erosion processes like joint formation and expansions are measured with high temporal resolution by electrical crack meters, together with rock- and air temperature. Secondly, in cooperation with the other working groups in the PROSA project, rock fall volumes are determined with multitemporal terrestrial laserscanning from several locations. Lately, already triggered rock falls are accounted by mapping the volume of the deposit and calculating of the bedrock source area. The deposition time span is fixed by consideration of the late Holocene lateral moraines and analysing historical aerial photographs, so that longer term rock wall retreat rates can be calculated. In order to limit homogenous bedrock sections for calculating specific rock wall retreat rates and to extrapolate the local determinated rock wall retreat rates to larger scale, bedrock areas will be divided into units of similar morphodynamic intensities which will be therefore classified by a rock mass strength (RMS) system. The RMS-System contains lithological and topoclimatic factors but also takes the measured rock wall retreat rates into account.

Geologic assessment of undiscovered hydrocarbon resources of the Western Oregon and Washington Province

USGS Publications Warehouse

,; Brownfield, Michael E.; Charpentier, Ronald R.; Cook, Troy A.; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.; Le, P.A.; ,

2011-01-01

The purpose of the U.S. Geological Survey (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered, technically recoverable oil and gas resources in western Oregon and Washington (USGS Western Oregon and Washington Province 5004). The province includes all of Oregon and Washington north of the Klamath Mountains and west of the crest of the Cascade Range, and extends offshore to the 3-mi limit of State waters on the west and to the International Boundary in the Straits of Juan de Fuca and Canada on the north. It measures about 450 mi north-south and 50 to 160 mi east-west, encompassing more than 51,000 mi2. The assessment of the Western Oregon and Washington Province is geology based and used the total petroleum system (TPS) concept. The geologic elements of a TPS include hydrocarbon source rocks (source rock maturation and hydrocarbon generation and migration), reservoir rocks (quality and distribution), and traps for hydrocarbon accumulation. Using these geologic criteria, two conventional and one unconventional (continuous) total petroleum systems were defined, with one assessment unit (AU) in each TPS: (1) the Cretaceous-Tertiary Composite TPS and the Western Oregon and Washington Conventional Gas AU, (2) the Tertiary Marine TPS and the Tertiary-Marine Gas AU, and (3) the Tertiary Coalbed Gas TPS and the Eocene Coalbed Gas AU, in which a cell-based methodology was used to estimate coalbed-gas resources.

Biostratigraphic correlation chart of some Upper Cretaceous rocks from the Lost Soldier area, Wyoming to west of Craig, Colorado

USGS Publications Warehouse

Bader, J.W.; Gill, J.R.; Cobban, W.A.; Law, B.E.

1983-01-01

This chart depicts the time-stratigraphic relations of some Upper Cretaceous rocks along the eastern and southeastern margins of the Greater Green River Basin, south-central Wyoming and northwestern Colorado. The purpose of this report is to release a preferred set of correlations based upon marine mollusk biostratigraphy. The senior author, with the help of B. E. Law, has acquired, synthesized, compiled, and interpreted data from various sources. These include selected published documents (see "References Cited") and unpublished reports of fossil identifications by W. A. Cobban who examined collections made by the late J. R. Gill. Numerous measured sections of Gill's were also utilized. It must be emphasized that all interpretations on this chart are based on information obtained from these sources and the senior author has yet to substantiate these correlations in the field. Not all data from the area of this study is included herein because it is either repetitive in nature or its reliability is uncertain. This uncertainty is due to the ambiguity inherent in both fossil identification and stratigraphic interpretation. Questionable unpublished material has been omitted while published data which is inconsistent with the senior author's correlations may be found in the footnotes portion of this report. The rock units are assigned to a range of ammonites that have been related to an absolute time scale. The ammonite zonation and age boundaries are adapted from Obradovich and Cobban (1975). "D" numbers are provided for each geographic locality where fossils were collected and described by personnel of the U.S. Geological Survey. These fossils may be accessed at the offices of the Survey in Lakewood, Colorado.

[Noise-induced hearing loss in children and youth: causes and prevention].

PubMed

Sułkowski, Wiesław J

2009-01-01

The populations at risk of adverse effects of noise include, in addition to adults, also children and juveniles, the two groups considered to be particularly vulnerable to noise-induced hearing loss and numerous other adverse systemic effects of exposure to noise. Major sources of noise exposure in children's and youth's environments include incubators at neonate intensive care wards, toys (such as e.g. rattles, squeeze toys, percussion cap toys, pistols), fireworks, pop and rock music concerts, aerobic courses and personal portable music players. This paper reports dB-A noise levels associated with those noise sources, and also combined dB-A levels of noise from external and internal sources prevailing at schools. The suggested preventive steps specified in the CE-HAPE (Children's Environment and Health Action Plan for Europe) and PINCHE (Policy Interpretation Network on Children's Health and Environment) include legislative measures to limit the intensity and time of exposure to noise and classes/education actions for youths and parents.

Elemental composition of the Martian crust.

PubMed

McSween, Harry Y; Taylor, G Jeffrey; Wyatt, Michael B

2009-05-08

The composition of Mars' crust records the planet's integrated geologic history and provides clues to its differentiation. Spacecraft and meteorite data now provide a global view of the chemistry of the igneous crust that can be used to assess this history. Surface rocks on Mars are dominantly tholeiitic basalts formed by extensive partial melting and are not highly weathered. Siliceous or calc-alkaline rocks produced by melting and/or fractional crystallization of hydrated, recycled mantle sources, and silica-poor rocks produced by limited melting of alkali-rich mantle sources, are uncommon or absent. Spacecraft data suggest that martian meteorites are not representative of older, more voluminous crust and prompt questions about their use in defining diagnostic geochemical characteristics and in constraining mantle compositional models for Mars.

Thermal maturity of type II kerogen from the New Albany Shale assessed by13C CP/MAS NMR

USGS Publications Warehouse

Werner-Zwanziger, U.; Lis, G.; Mastalerz, Maria; Schimmelmann, A.

2005-01-01

Thermal maturity of oil and gas source rocks is typically quantified in terms of vitrinite reflectance, which is based on optical properties of terrestrial woody remains. This study evaluates 13C CP/MAS NMR parameters in kerogen (i.e., the insoluble fraction of organic matter in sediments and sedimentary rocks) as proxies for thermal maturity in marine-derived source rocks where terrestrially derived vitrinite is often absent or sparse. In a suite of samples from the New Albany Shale (Middle Devonian to the Early Mississippian, Illinois Basin) the abundance of aromatic carbon in kerogen determined by 13C CP/MAS NMR correlates linearly well with vitrinite reflectance. ?? 2004 Elsevier Inc. All rights reserved.

Automatic Rock Detection and Mapping from HiRISE Imagery

NASA Technical Reports Server (NTRS)

Huertas, Andres; Adams, Douglas S.; Cheng, Yang

2008-01-01

This system includes a C-code software program and a set of MATLAB software tools for statistical analysis and rock distribution mapping. The major functions include rock detection and rock detection validation. The rock detection code has been evolved into a production tool that can be used by engineers and geologists with minor training.

Strontium and neodymium isotope systematics of target rocks and impactites from the El'gygytgyn impact structure: Linking impactites and target rocks

NASA Astrophysics Data System (ADS)

Wegner, Wencke; Koeberl, Christian

2016-12-01

The 3.6 Ma El'gygytgyn structure, located in northeastern Russia on the Chukotka Peninsula, is an 18 km diameter complex impact structure. The bedrock is formed by mostly high-silica volcanic rocks of the 87 Ma old Okhotsk-Chukotka Volcanic Belt (OCVB). Volcanic target rocks and impact glasses collected on the surface, as well as drill core samples of bedrock and impact breccias have been investigated by thermal ionization mass spectrometry (TIMS) to obtain new insights into the relationships between these lithologies in terms of Nd and Sr isotope systematics. Major and trace element data for impact glasses are added to compare with the composition of target rocks and drill core samples. Sr isotope data are useful tracers of alteration processes and Nd isotopes reveal characteristics of the magmatic sources of the target rocks, impact breccias, and impact glasses. There are three types of target rocks mapped on the surface: mafic volcanics, dacitic tuff and lava of the Koekvun' Formation, and dacitic to rhyolitic ignimbrite of the Pykarvaam Formation. The latter represents the main contributor to the impact rocks. The drill core is divided into a suevite and a bedrock section by the Sr isotope data, for which different postimpact alteration regimes have been detected. Impact glasses from the present-day surface did not suffer postimpact hydrothermal alteration and their data indicate a coherent alteration trend in terms of Sr isotopes with the target rocks from the surface. Surprisingly, the target rocks do not show isotopic coherence with the Central Chukotka segment of the OCVB or with the Berlozhya magmatic assemblage (BMA), a late Jurassic felsic volcanic suite that crops out in the eastern part of the central Chukotka segment of the OCVB. However, concordance for these rocks exists with the Okhotsk segment of the OCVB. This finding argues for variable source magmas having contributed to the build-up of the OCVB.