Calculation extinction cross sections and molar attenuation coefficient of small gold nanoparticles and experimental observation of their UV-vis spectral properties.

PubMed

Tang, Junqi; Gao, Kunpeng; Ou, Quanhong; Fu, Xuewen; Man, Shi-Qing; Guo, Jie; Liu, Yingkai

2018-02-15

Gold nanoparticles (AuNPs) have been researched extensively, such as applied in various biosensors, biomedical imaging and diagnosis, catalysis and physico-chemical analysis. These applications usually required to know the nanoparticle size or concentration. Researchers have been studying a simply and quick way to estimate the concentration or size of nanoparticles from their optical spectra and SPR feature for several years. The extinction cross-sections and the molar attenuation coefficient were one of the key parameters. In this study, we calculated the extinction cross-sections and molar attenuation coefficient (decadic molar extinction coefficient) of small gold nanoparticles by dipole approximation method and modified Beer-Lambert law. The theoretical result showed that the surface plasmon resonance peak of small gold nanoparticles was blueshift with an increase size. Moreover, small AuNPs (sub-10nm) were prepared by using of dextran or trisodium citrate as reducing agent and capping agent. The experimental synthesized AuNPs was also shows a blueshift as increasing particle size in a certain range. And the concentration of AuNPs was calculated based on the obtained molar attenuation coefficient. For small nanoparticles, the size of nanoparticles and surface plasmon resonance property was not showed a positive correlation compared to larger nanoparticles. These results suggested that SPR peak depended not only on the nanoparticle size and shape but also on the nanoparticles environment. Copyright © 2017 Elsevier B.V. All rights reserved.

The spectral irradiance of the moon

USGS Publications Warehouse

Kieffer, H.H.; Stone, T.C.

2005-01-01

Images of the Moon at 32 wavelengths from 350 to 2450 nm have been obtained from a dedicated observatory during the bright half of each month over a period of several years. The ultimate goal is to develop a spectral radiance model of the Moon with an angular resolution and radiometric accuracy appropriate for calibration of Earth-orbiting spacecraft. An empirical model of irradiance has been developed that treats phase and libration explicitly, with absolute scale founded on the spectra of the star Vega and returned Apollo samples. A selected set of 190 standard stars are observed regularly to provide nightly extinction correction and long-term calibration of the observations. The extinction model is wavelength-coupled and based on the absorption coefficients of a number of gases and aerosols. The empirical irradiance model has the same form at each wavelength, with 18 coefficients, eight of which are constant across wavelength, for a total of 328 coefficients. Over 1000 lunar observations are fitted at each wavelength; the average residual is less than 1%. The irradiance model is actively being used in lunar calibration of several spacecraft instruments and can track sensor response changes at the 0.1% level. ?? 2005. The American Astronomical Society. All rights reserved.

High Spectral Resolution Lidar and MPLNET Micro Pulse Lidar Aerosol Optical Property Retrieval Intercomparison During the 2012 7-SEAS Field Campaign at Singapore

NASA Technical Reports Server (NTRS)

Lolli, Simone; Welton, Ellsworth J.; Campbell, James R.; Eloranta, Edwin; Holben, Brent N.; Chew, Boon Ning; Salinas, Santo V.

2014-01-01

From August 2012 to February 2013 a High Resolution Spectral Lidar (HSRL; 532 nm) was deployed at that National University of Singapore near a NASA Micro Pulse Lidar NETwork (MPLNET; 527 nm) site. A primary objective of the MPLNET lidar project is the production and dissemination of reliable Level 1 measurements and Level 2 retrieval products. This paper characterizes and quantifies error in Level 2 aerosol optical property retrievals conducted through inversion techniques that derive backscattering and extinction coefficients from MPLNET elastic single-wavelength datasets. MPLNET Level 2 retrievals for aerosol optical depth and extinction/backscatter coefficient profiles are compared with corresponding HSRL datasets, for which the instrument collects direct measurements of each using a unique optical configuration that segregates aerosol and cloud backscattered signal from molecular signal. The intercomparison is performed, and error matrices reported, for lower (0-5km) and the upper (>5km) troposphere, respectively, to distinguish uncertainties observed within and above the MPLNET instrument optical overlap regime.

Optical and structural properties of amorphous Se x Te100- x aligned nanorods

NASA Astrophysics Data System (ADS)

Al-Agel, Faisal A.

2013-12-01

In the present work, we report studies on optical and structural phenomenon in as-deposited thin films composed of aligned nanorods of amorphous Se x Te100- x ( x = 3, 6, 9, and 12). In structural studies, field emission scanning electron microscopic (FESEM) images suggest that these thin films contain high yield of aligned nanorods. These nanorods show a completely amorphous nature, which is verified by X-ray diffraction patterns of these thin films. Optical studies include the measurement of spectral dependence of absorption, reflection, and transmission of these thin films, respectively. On the basis of optical absorption data, a direct optical band gap is observed. This observation of a direct optical band gap in these nanorods is interesting as chalcogenides normally show an indirect band gap, and due to this reason, these materials could not become very popular for semiconducting devices. Therefore, this is an important report and will open up new directions for the application of these materials in semiconducting devices. The value of this optical band gap is found to decrease with the increase in selenium (Se) concentration. The reflection and absorption data are employed to estimate the values of optical constants (extinction coefficient ( k) and refractive index ( n)). From the spectral dependence of these optical constants, it is found that the values of refractive index ( n) increase, whereas the values of extinction coefficient ( k) decrease with the increase in photon energy. The real and imaginary parts of dielectric constants calculated with the values of extinction coefficient ( k) and refractive index ( n), are found to vary with photon energy and dopant concentration.

Dynamic Optical Grating Device and Associated Method for Modulating Light

NASA Technical Reports Server (NTRS)

Park, Yeonjoon (Inventor); Choi, Sang H. (Inventor); King, Glen C. (Inventor); Chu, Sang-Hyon (Inventor)

2012-01-01

A dynamic optical grating device and associated method for modulating light is provided that is capable of controlling the spectral properties and propagation of light without moving mechanical components by the use of a dynamic electric and/or magnetic field. By changing the electric field and/or magnetic field, the index of refraction, the extinction coefficient, the transmittivity, and the reflectivity fo the optical grating device may be controlled in order to control the spectral properties of the light reflected or transmitted by the device.

A new interpretation of Serkowski's polarization law

NASA Astrophysics Data System (ADS)

Papoular, R.

2018-06-01

The basic tenets of the alternative interpretation to be presented here are that the spectral profiles of the star light polarization peaks observed in the visible and near IR are a result of the optical properties of silicate grains in the same spectral range, not of the grain size, provided it remains within the range of Rayleigh's approximation. The silicate properties are those obtained experimentally by Scott and Duley (1996) for the non-iron bearing amorphous forsterite and enstatite. The whole range of observed Serkowski polarization profiles can be simulated with mixtures made of forsterite plus an increasing fraction (0 to 0.5) of enstatite as the spectral peak shifts from 0.8 to 0.3 μm. Fits to individual observed polarization spectra are also demonstrated. The optical extinction of silicates in the vis/IR (the "transparency range") can be understood by analogy with the thoroughly studied amorphous hydrogenated carbons and amorphous silica. It is due to structural disorder (dangling bonds and coordination defects) and impurities, which give rise to electronic states in the forbidden gap of semi-conductors. Because they are partially localized, their extinction power is dramatically reduced and has been ignored or simply described by a low, flat plateau. As their number density depends on the environment, one expects variations in the ratio of optical extinction coefficients in the visible and mid-IR. It is also argued that the measured steep rise of extinction beyond 3 μm-1 into the UV is due to atomic transitions, and so cannot give rise to coherent molecular polarization, but only localized extinction.

An Accuracy Assessment of the CALIOP/CALIPSO Version 2/Version 3 Daytime Aerosol Extinction Product Based on a Detailed Multi-Sensor, Multi-Platform Case Study

NASA Technical Reports Server (NTRS)

Kacenelenbogen, M.; Vaughan, M. A.; Redemann, J.; Hoff, R. M.; Rogers, R. R.; Ferrare, R. A.; Russell, P. B.; Hostetler, C. A.; Hair, J. W.; Holben, B. N.

2011-01-01

The Cloud Aerosol LIdar with Orthogonal Polarization (CALIOP), on board the CALIPSO platform, has measured profiles of total attenuated backscatter coefficient (level 1 products) since June 2006. CALIOP s level 2 products, such as the aerosol backscatter and extinction coefficient profiles, are retrieved using a complex succession of automated algorithms. The goal of this study is to help identify potential shortcomings in the CALIOP version 2 level 2 aerosol extinction product and to illustrate some of the motivation for the changes that have been introduced in the next version of CALIOP data (version 3, released in June 2010). To help illustrate the potential factors contributing to the uncertainty of the CALIOP aerosol extinction retrieval, we focus on a one-day, multi-instrument, multiplatform comparison study during the CALIPSO and Twilight Zone (CATZ) validation campaign on 4 August 2007. On that day, we observe a consistency in the Aerosol Optical Depth (AOD) values recorded by four different instruments (i.e. spaceborne MODerate Imaging Spectroradiometer, MODIS: 0.67 and POLarization and Directionality of Earth s Reflectances, POLDER: 0.58, airborne High Spectral Resolution Lidar, HSRL: 0.52 and ground-based AErosol RObotic NETwork, AERONET: 0.48 to 0.73) while CALIOP AOD is a factor of two lower (0.32 at 532 nm). This case study illustrates the following potential sources of uncertainty in the CALIOP AOD: (i) CALIOP s low signal-to-noise ratio (SNR) leading to the misclassification and/or lack of aerosol layer identification, especially close to the Earth s surface; (ii) the cloud contamination of CALIOP version 2 aerosol backscatter and extinction profiles; (iii) potentially erroneous assumptions of the aerosol extinction-to-backscatter ratio (Sa) used in CALIOP s extinction retrievals; and (iv) calibration coefficient biases in the CALIOP daytime attenuated backscatter coefficient profiles. The use of version 3 CALIOP extinction retrieval for our case study seems to partially fix factor (i) although the aerosol retrieved by CALIOP is still somewhat lower than the profile measured by HSRL; the cloud contamination (ii) appears to be corrected; no particular change is apparent in the observation-based CALIOP Sa value (iii). Our case study also showed very little difference in version 2 and version 3 CALIOP attenuated backscatter coefficient profiles, illustrating a minor change in the calibration scheme (iv).

Longwave radiative effects of Saharan dust during the ICE-D campaign

NASA Astrophysics Data System (ADS)

Brooke, Jennifer; Havemann, Stephan; Ryder, Claire; O'Sullivan, Debbie

2017-04-01

The Havemann-Taylor Fast Radiative Transfer Code (HT-FRTC) is a fast radiative transfer model based on Principal Components. Scattering has been incorporated into HT-FRTC which allows simulations of aerosol as well as clear-sky atmospheres. This work evaluates the scattering scheme in HT-FRTC and investigates dust-affected brightness temperatures using in-situ observations from Ice in Clouds Experiment - Dust (ICE-D) campaign. The ICE-D campaign occurred during August 2015 and was based from Cape Verde. The ICE-D campaign is a multidisciplinary project which achieved measurements of in-situ mineral dust properties of the dust advected from the Sahara, and on the aerosol-cloud interactions using the FAAM BAe-146 research aircraft. ICE-D encountered a range of low (0.3), intermediate (0.8) and high (1.3) aerosol optical depths, AODs, and therefore provides a range of atmospheric dust loadings in the assessment of dust scattering in HT-FRTC. Spectral radiances in the thermal infrared window region (800 - 1200 cm-1) are sensitive to the presence of mineral dust; mineral dust acts to reduce the upwelling infrared radiation caused by the absorption and re-emission of radiation by the dust layer. ARIES (Airborne Research Interferometer Evaluation System) is a nadir-facing interferometer, measuring infrared radiances between 550 and 3000 cm-1. The ARIES spectral radiances are converted to brightness temperatures by inversion of the Planck function. The mineral dust size distribution is important for radiative transfer applications as it provides a measure of aerosol scattering. The longwave spectral mineral dust optical properties including the mass extinction coefficients, single scattering albedos and the asymmetry parameter have been derived from the mean ICE-D size distribution. HT-FRTC scattering simulations are initialised with vertical mass fractions which can be derived from extinction profiles from the lidar along with the specific extinction coefficient, kext (m2/g) at 355 nm. In general the comparison between the lidar retrieval of aerosol extinction coefficients and in-situ measurements show a good agreement. The root mean square of the brightness temperature residuals in the window region for observations (ARIES) minus model simulations for i) clear-sky, ii) HT-FRTC 'line-by-line' scattering and, iii) HT-FRTC fast scattering are calculated. For the ICE-D case studies mineral dust impacts on the brightness temperature of the background on the order of 1 - 1.5 K.

Retrieval of spheroid particle size distribution from spectral extinction data in the independent mode using PCA approach

NASA Astrophysics Data System (ADS)

Tang, Hong; Lin, Jian-Zhong

2013-01-01

An improved anomalous diffraction approximation (ADA) method is presented for calculating the extinction efficiency of spheroids firstly. In this approach, the extinction efficiency of spheroid particles can be calculated with good accuracy and high efficiency in a wider size range by combining the Latimer method and the ADA theory, and this method can present a more general expression for calculating the extinction efficiency of spheroid particles with various complex refractive indices and aspect ratios. Meanwhile, the visible spectral extinction with varied spheroid particle size distributions and complex refractive indices is surveyed. Furthermore, a selection principle about the spectral extinction data is developed based on PCA (principle component analysis) of first derivative spectral extinction. By calculating the contribution rate of first derivative spectral extinction, the spectral extinction with more significant features can be selected as the input data, and those with less features is removed from the inversion data. In addition, we propose an improved Tikhonov iteration method to retrieve the spheroid particle size distributions in the independent mode. Simulation experiments indicate that the spheroid particle size distributions obtained with the proposed method coincide fairly well with the given distributions, and this inversion method provides a simple, reliable and efficient method to retrieve the spheroid particle size distributions from the spectral extinction data.

The Complex Refractive Index of Volcanic Ash Aerosol Retrieved From Spectral Mass Extinction

NASA Astrophysics Data System (ADS)

Reed, Benjamin E.; Peters, Daniel M.; McPheat, Robert; Grainger, R. G.

2018-01-01

The complex refractive indices of eight volcanic ash samples, chosen to have a representative range of SiO2 contents, were retrieved from simultaneous measurements of their spectral mass extinction coefficient and size distribution. The mass extinction coefficients, at 0.33-19 μm, were measured using two optical systems: a Fourier transform spectrometer in the infrared and two diffraction grating spectrometers covering visible and ultraviolet wavelengths. The particle size distribution was measured using a scanning mobility particle sizer and an optical particle counter; values for the effective radius of ash particles measured in this study varied from 0.574 to 1.16 μm. Verification retrievals on high-purity silica aerosol demonstrated that the Rayleigh continuous distribution of ellipsoids (CDEs) scattering model significantly outperformed Mie theory in retrieving the complex refractive index, when compared to literature values. Assuming the silica particles provided a good analogue of volcanic ash, the CDE scattering model was applied to retrieve the complex refractive index of the eight ash samples. The Lorentz formulation of the complex refractive index was used within the retrievals as a convenient way to ensure consistency with the Kramers-Kronig relation. The short-wavelength limit of the electric susceptibility was constrained by using independently measured reference values of the complex refractive index of the ash samples at a visible wavelength. The retrieved values of the complex refractive indices of the ash samples showed considerable variation, highlighting the importance of using accurate refractive index data in ash cloud radiative transfer models.

[Research on the measurement range of particle size with total light scattering method in vis-IR region].

PubMed

Sun, Xiao-gang; Tang, Hong; Dai, Jing-min

2008-12-01

The problem of determining the particle size range in the visible-infrared region was studied using the independent model algorithm in the total scattering technique. By the analysis and comparison of the accuracy of the inversion results for different R-R distributions, the measurement range of particle size was determined. Meanwhile, the corrected extinction coefficient was used instead of the original extinction coefficient, which could determine the measurement range of particle size with higher accuracy. Simulation experiments illustrate that the particle size distribution can be retrieved very well in the range from 0. 05 to 18 microm at relative refractive index m=1.235 in the visible-infrared spectral region, and the measurement range of particle size will vary with the varied wavelength range and relative refractive index. It is feasible to use the constrained least squares inversion method in the independent model to overcome the influence of the measurement error, and the inverse results are all still satisfactory when 1% stochastic noise is added to the value of the light extinction.

Spectral dependence of backscattering coefficient of mixed phase clouds over West Africa measured with two-wavelength Raman polarization lidar: Features attributed to ice-crystals corner reflection

NASA Astrophysics Data System (ADS)

Veselovskii, I.; Goloub, P.; Podvin, T.; Tanre, D.; Ansmann, A.; Korenskiy, M.; Borovoi, A.; Hu, Q.; Whiteman, D. N.

2017-11-01

The existing models predict that corner reflection (CR) of laser radiation by simple ice crystals of perfect shape, such as hexagonal columns or plates, can provide a significant contribution to the ice cloud backscattering. However in real clouds the CR effect may be suppressed due to crystal deformation and surface roughness. In contrast to the extinction coefficient, which is spectrally independent, consideration of diffraction associated with CR results in a spectral dependence of the backscattering coefficient. Thus measuring the spectral dependence of the cloud backscattering coefficient, the contribution of CR can be identified. The paper presents the results of profiling of backscattering coefficient (β) and particle depolarization ratio (δ) of ice and mixed-phase clouds over West Africa by means of a two-wavelength polarization Mie-Raman lidar operated at 355 nm and 532 nm during the SHADOW field campaign. The lidar observations were performed at a slant angle of 43 degree off zenith, thus CR from both randomly oriented crystals and oriented plates could be analyzed. For the most of the observations the cloud backscatter color ratio β355/β532 was close to 1.0, and no spectral features that might indicate the presence of CR of randomly oriented crystals were revealed. Still, in two measurement sessions we observed an increase of backscatter color ratio to a value of nearly 1.3 simultaneously with a decrease of the spectral depolarization ratio δ355/δ532 ratio from 1.0 to 0.8 inside the layers containing precipitating ice crystals. We attribute these changes in optical properties to corner reflections by horizontally oriented ice plates.

Improved identification of the solution space of aerosol microphysical properties derived from the inversion of profiles of lidar optical data, part 1: theory.

PubMed

Kolgotin, Alexei; Müller, Detlef; Chemyakin, Eduard; Romanov, Anton

2016-12-01

Multiwavelength Raman/high spectral resolution lidars that measure backscatter coefficients at 355, 532, and 1064 nm and extinction coefficients at 355 and 532 nm can be used for the retrieval of particle microphysical parameters, such as effective and mean radius, number, surface-area and volume concentrations, and complex refractive index, from inversion algorithms. In this study, we carry out a correlation analysis in order to investigate the degree of dependence that may exist between the optical data taken with lidar and the underlying microphysical parameters. We also investigate if the correlation properties identified in our study can be used as a priori or a posteriori constraints for our inversion scheme so that the inversion results can be improved. We made the simplifying assumption of error-free optical data in order to find out what correlations exist in the best case situation. Clearly, for practical applications, erroneous data need to be considered too. On the basis of simulations with synthetic optical data, we find the following results, which hold true for arbitrary particle size distributions, i.e., regardless of the modality or the shape of the size distribution function: surface-area concentrations and extinction coefficients are linearly correlated with a correlation coefficient above 0.99. We also find a correlation coefficient above 0.99 for the extinction coefficient versus (1) the ratio of the volume concentration to effective radius and (2) the product of the number concentration times the sum of the squares of the mean radius and standard deviation of the investigated particle size distributions. Besides that, we find that for particles of any mode fraction of the particle size distribution, the complex refractive index is uniquely defined by extinction- and backscatter-related Ångström exponents, lidar ratios at two wavelengths, and an effective radius.

Microscale determination of the spectral characteristics and carbon-isotopic compositions of porphyrins

NASA Technical Reports Server (NTRS)

Popp, B. N.; Hayes, J. M.; Boreham, C. J.

1993-01-01

Molar extinction coefficients for band III of Ni porphyrins are calculated from results of spectrophotometric and manometric analyses of individual etioporphyrins, DPEP, cyclic, and diDPEP porphyrins known to initially be pure from mass spectrometry, 1H NMR, and analytical HPLC studies. A method for determining carbon-isotopic compositions and purity of micromolar quantities of individual porphyrins using combined spectrophotometric and manometric techniques is presented.

Lidar inelastic multiple-scattering parameters of cirrus particle ensembles determined with geometrical-optics crystal phase functions.

PubMed

Reichardt, J; Hess, M; Macke, A

2000-04-20

Multiple-scattering correction factors for cirrus particle extinction coefficients measured with Raman and high spectral resolution lidars are calculated with a radiative-transfer model. Cirrus particle-ensemble phase functions are computed from single-crystal phase functions derived in a geometrical-optics approximation. Seven crystal types are considered. In cirrus clouds with height-independent particle extinction coefficients the general pattern of the multiple-scattering parameters has a steep onset at cloud base with values of 0.5-0.7 followed by a gradual and monotonic decrease to 0.1-0.2 at cloud top. The larger the scattering particles are, the more gradual is the rate of decrease. Multiple-scattering parameters of complex crystals and of imperfect hexagonal columns and plates can be well approximated by those of projected-area equivalent ice spheres, whereas perfect hexagonal crystals show values as much as 70% higher than those of spheres. The dependencies of the multiple-scattering parameters on cirrus particle spectrum, base height, and geometric depth and on the lidar parameters laser wavelength and receiver field of view, are discussed, and a set of multiple-scattering parameter profiles for the correction of extinction measurements in homogeneous cirrus is provided.

Spectral structure of laser light scattering revisited: bandwidths of nonresonant scattering lidars.

PubMed

She, C Y

2001-09-20

It is well known that scattering lidars, i.e., Mie, aerosol-wind, Rayleigh, high-spectral-resolution, molecular-wind, rotational Raman, and vibrational Raman lidars, are workhorses for probing atmospheric properties, including the backscatter ratio, aerosol extinction coefficient, temperature, pressure, density, and winds. The spectral structure of molecular scattering (strength and bandwidth) and its constituent spectra associated with Rayleigh and vibrational Raman scattering are reviewed. Revisiting the correct name by distinguishing Cabannes scattering from Rayleigh scattering, and sharpening the definition of each scattering component in the Rayleigh scattering spectrum, the review allows a systematic, logical, and useful comparison in strength and bandwidth between each scattering component and in receiver bandwidths (for both nighttime and daytime operation) between the various scattering lidars for atmospheric sensing.

Spectroscopic ellipsometry study of Cu2ZnSnS4 bulk poly-crystals

NASA Astrophysics Data System (ADS)

Levcenko, S.; Hajdeu-Chicarosh, E.; Garcia-Llamas, E.; Caballero, R.; Serna, R.; Bodnar, I. V.; Victorov, I. A.; Guc, M.; Merino, J. M.; Pérez-Rodriguez, A.; Arushanov, E.; León, M.

2018-04-01

The linear optical properties of Cu2ZnSnS4 bulk poly-crystals have been investigated using spectroscopic ellipsometry in the range of 1.2-4.6 eV at room temperature. The characteristic features identified in the optical spectra are explained by using the Adachi analytical model for the interband transitions at the corresponding critical points in the Brillouin zone. The experimental data have been modeled over the entire spectral range taking into account the lowest E0 transition near the fundamental absorption edge and E1A and E1B higher energy interband transitions. In addition, the spectral dependences of the refractive index, extinction coefficient, absorption coefficient, and normal-incidence reflectivity values have been accurately determined and are provided since they are essential data for the design of Cu2ZnSnS4 based optoelectronic devices.

The determination of extinction coefficient of CuInS2, and ZnCuInS3 multinary nanocrystals.

PubMed

Qin, Lei; Li, Dongze; Zhang, Zhuolei; Wang, Kefei; Ding, Hong; Xie, Renguo; Yang, Wensheng

2012-10-21

A pioneering work for determining the extinction coefficient of colloidal semiconductor nanocrystals (NCs) has been cited over 1500 times (W. Yu, W. Guo, X. G. Peng, Chem. Mater., 2003, 15, 2854-2860), indicating the importance of calculating NC concentration for further research and applications. In this study, the size-dependent nature of the molar extinction coefficient of "greener" CuInS(2) and ZnCuInS(3) NCs with emission covering the whole visible to near infrared (NIR) is presented. With the increase of NC size, the resulting quantitative values of the extinction coefficients of ternary CuInS(2) and quaternary ZnCuInS(3) NCs are found to follow a power function with exponents of 2.1 and 2.5, respectively. Obviously, a larger value of extinction coefficient is observed in quaternary NCs for the same size of particles. The difference of the extinction coefficient from both samples is clearly demonstrated due to incorporating ZnS with a much larger extinction coefficient into CuInS(2) NCs.

Atmospheric aerosols: Their Optical Properties and Effects (supplement)

NASA Technical Reports Server (NTRS)

1976-01-01

A digest of technical papers is presented. Topics include aerosol size distribution from spectral attenuation with scattering measurements; comparison of extinction and backscattering coefficients for measured and analytic stratospheric aerosol size distributions; using hybrid methods to solve problems in radiative transfer and in multiple scattering; blue moon phenomena; absorption refractive index of aerosols in the Denver pollution cloud; a two dimensional stratospheric model of the dispersion of aerosols from the Fuego volcanic eruption; the variation of the aerosol volume to light scattering coefficient; spectrophone in situ measurements of the absorption of visible light by aerosols; a reassessment of the Krakatoa volcanic turbidity, and multiple scattering in the sky radiance.

An Improved Method of Predicting Extinction Coefficients for the Determination of Protein Concentration.

PubMed

Hilario, Eric C; Stern, Alan; Wang, Charlie H; Vargas, Yenny W; Morgan, Charles J; Swartz, Trevor E; Patapoff, Thomas W

2017-01-01

Concentration determination is an important method of protein characterization required in the development of protein therapeutics. There are many known methods for determining the concentration of a protein solution, but the easiest to implement in a manufacturing setting is absorption spectroscopy in the ultraviolet region. For typical proteins composed of the standard amino acids, absorption at wavelengths near 280 nm is due to the three amino acid chromophores tryptophan, tyrosine, and phenylalanine in addition to a contribution from disulfide bonds. According to the Beer-Lambert law, absorbance is proportional to concentration and path length, with the proportionality constant being the extinction coefficient. Typically the extinction coefficient of proteins is experimentally determined by measuring a solution absorbance then experimentally determining the concentration, a measurement with some inherent variability depending on the method used. In this study, extinction coefficients were calculated based on the measured absorbance of model compounds of the four amino acid chromophores. These calculated values for an unfolded protein were then compared with an experimental concentration determination based on enzymatic digestion of proteins. The experimentally determined extinction coefficient for the native proteins was consistently found to be 1.05 times the calculated value for the unfolded proteins for a wide range of proteins with good accuracy and precision under well-controlled experimental conditions. The value of 1.05 times the calculated value was termed the predicted extinction coefficient. Statistical analysis shows that the differences between predicted and experimentally determined coefficients are scattered randomly, indicating no systematic bias between the values among the proteins measured. The predicted extinction coefficient was found to be accurate and not subject to the inherent variability of experimental methods. We propose the use of a predicted extinction coefficient for determining the protein concentration of therapeutic proteins starting from early development through the lifecycle of the product. LAY ABSTRACT: Knowing the concentration of a protein in a pharmaceutical solution is important to the drug's development and posology. There are many ways to determine the concentration, but the easiest one to use in a testing lab employs absorption spectroscopy. Absorbance of ultraviolet light by a protein solution is proportional to its concentration and path length; the proportionality constant is the extinction coefficient. The extinction coefficient of a protein therapeutic is usually determined experimentally during early product development and has some inherent method variability. In this study, extinction coefficients of several proteins were calculated based on the measured absorbance of model compounds. These calculated values for an unfolded protein were then compared with experimental concentration determinations based on enzymatic digestion of the proteins. The experimentally determined extinction coefficient for the native protein was 1.05 times the calculated value for the unfolded protein with good accuracy and precision under controlled experimental conditions, so the value of 1.05 times the calculated coefficient was called the predicted extinction coefficient. Comparison of predicted and measured extinction coefficients indicated that the predicted value was very close to the experimentally determined values for the proteins. The predicted extinction coefficient was accurate and removed the variability inherent in experimental methods. © PDA, Inc. 2017.

Parameterization of the Extinction Coefficient in Ice and Mixed-Phase Arctic Clouds during the ISDAC Field Campaign

DOE Office of Scientific and Technical Information (OSTI.GOV)

Korolev, A; Shashkov, A; Barker, H

This report documents the history of attempts to directly measure cloud extinction, the current measurement device known as the Cloud Extinction Probe (CEP), specific problems with direct measurement of extinction coefficient, and the attempts made here to address these problems. Extinction coefficient is one of the fundamental microphysical parameters characterizing bulk properties of clouds. Knowledge of extinction coefficient is of crucial importance for radiative transfer calculations in weather prediction and climate models given that Earth's radiation budget (ERB) is modulated much by clouds. In order for a large-scale model to properly account for ERB and perturbations to it, it mustmore » ultimately be able to simulate cloud extinction coefficient well. In turn this requires adequate and simultaneous simulation of profiles of cloud water content and particle habit and size. Similarly, remote inference of cloud properties requires assumptions to be made about cloud phase and associated single-scattering properties, of which extinction coefficient is crucial. Hence, extinction coefficient plays an important role in both application and validation of methods for remote inference of cloud properties from data obtained from both satellite and surface sensors (e.g., Barker et al. 2008). While estimation of extinction coefficient within large-scale models is relatively straightforward for pure water droplets, thanks to Mie theory, mixed-phase and ice clouds still present problems. This is because of the myriad forms and sizes that crystals can achieve, each having their own unique extinction properties. For the foreseeable future, large-scale models will have to be content with diagnostic parametrization of crystal size and type. However, before they are able to provide satisfactory values needed for calculation of radiative transfer, they require the intermediate step of assigning single-scattering properties to particles. The most basic of these is extinction coefficient, yet it is rarely measured directly, and therefore verification of parametrizations is difficult. The obvious solution is to be able to measure microphysical properties and extinction at the same time and for the same volume. This is best done by in situ sampling by instruments mounted on either balloon or aircraft. The latter is the usual route and the one employed here. Yet the problem of actually measuring extinction coefficient directly for arbitrarily complicated particles still remains unsolved.« less

Altitude Differentiated Aerosol Extinction Over Tenerife (North Atlantic Coast) During ACE-2 by Means of Ground and Airborne Photometry and Lidar Measurements

NASA Technical Reports Server (NTRS)

Formenti, P.; Elias, T.; Welton, J.; Diaz, J. P.; Exposito, F.; Schmid, B.; Powell, D.; Holben, B. N.; Smirnov, A.; Andreae, M. O.;

Controlling of the optical properties of the solutions of the PTCDI-C8 organic semiconductor

NASA Astrophysics Data System (ADS)

Erdoğan, Erman; Gündüz, Bayram

2016-09-01

N,N'-Dioctyl-3,4,9,10 perylenedicarboximide (PTCDI-C8) organic semiconductor have vast applications in solar cells, thermoelectric generators, thin film photovoltaics and many other optoelectronic devices. These applications of the materials are based on their spectral and optical properties. The solutions of the PTCDI-C8 for different molarities were prepared and the spectral and optical mesaurements were analyzed. Effects of the molarities on optical properties were investigated. Vibronic structure has been observed based on the absorption bands of PTCDI-C8 semiconductor with seven peaks at 2.292, 2.451, 2.616, 3.212, 3.851, 4.477 and 4.733 eV. The important spectral parameteres such as molar/mass extinction coefficients, absorption coefficient of the PTCDI-C8 molecule were calculated. Optical properties such as angle of incidence/refraction, optical band gap, real and imaginary parts of dielectric constant, loss factor and electrical susceptibility of the the PTCDI-C8 were obtained. Finally, we discussed these parameters for optoelectronic applications and compared with related parameters in literature.

MAX-DOAS retrieval of aerosol extinction properties in Madrid, Spain

NASA Astrophysics Data System (ADS)

Wang, Shanshan; Cuevas, Carlos A.; Frieß, Udo; Saiz-Lopez, Alfonso

2017-04-01

We present Multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements performed in the urban environment of Madrid, Spain, from March to September 2015. The O4 absorption in the ultraviolet (UV) spectral region was used to retrieve the aerosol extinction profile using an inversion algorithm. The results show a good agreement between the hourly retrieved aerosol optical depth (AOD) and the correlative Aerosol Robotic Network (AERONET) product. Higher AODs are found in the summer season due to the more frequent occurrence of Saharan dust intrusions. The surface aerosol extinction coefficient as retrieved by the MAX-DOAS measurements was also compared to in situ PM2:5 concentrations. The level of agreement between both measurements indicates that the MAX-DOAS retrieval has the ability to characterize the extinction of aerosol particles near the surface. The retrieval algorithm was also used to study a case of severe dust intrusion on 12 May 2015. The capability of the MAX-DOAS retrieval to recognize the dust event including an elevated particle layer is investigated along with air mass back-trajectory analysis.

Emittance Theory for Cylindrical Fiber Selective Emitter

NASA Technical Reports Server (NTRS)

Chubb, Donald L.

1998-01-01

A fibrous rare earth selective emitter is approximated as an infinitely long cylinder. The spectral emittance, epsilon(lambda), is obtained by solving the radiative transfer equations with appropriate boundary conditions and uniform temperature. For optical depths, Kappa(R) = alpha(lambda)R, where alpha(lambda) is the extinction coefficient and R is the cylinder radius, greater than 1 the spectral emittance is nearly at its maximum value. There is an optimum cylinder radius, R(opt), for maximum emitter efficiency, eta(E). Values for R(opt) are strongly dependent on the number of emission bands of the material. The optimum radius decreases slowly with increasing emitter temperature, while the maximum efficiency and useful radiated power increase rapidly with increasing temperature.

Joint Aerospace Weapon System Support, Sensors And Simulation Symposium (5th Annual). Held In San Diego, California on 13-18 June 1999

DTIC Science & Technology

1999-06-18

and 1.54 microns and to compute the spectral extinction coefficient. 3. Near IR (1.54 um) Laser rangefinders measure the time-of-flight of a short...quantitative understanding n n Research ( long term) n Encourage research in adaptive systems : evolutionary programming, genetic algorithms, neural nets... measures , such as false alarm rate , are not measurable in field applications. Other measures such as Incremental Fault Resolution, Operational Isolation

Light extinction method for diagnostics of particles sizes formed in magnetic field

NASA Astrophysics Data System (ADS)

Myshkin, Vyacheslav; Izhoykin, Dmitry; Grigoriev, Alexander; Gamov, Denis; Leonteva, Daria

2018-03-01

The results of laser diagnostics of dispersed particles formed upon cooling of Zn vapor are presented. The radiation attenuation in the wavelength range 420-630 nm with a step of 0.3 nm was registered. The attenuation coefficients spectral dependence was processed using known algorithms for integral equation solving. The 10 groups of 8 attenuation coefficients were formed. Each group was processed taking with considering of previous decisions. After processing of the 10th group of data, calculations were repeated from the first one. Data of the particles sizes formed in a magnetic field of 0, 44 and 76 mT are given. A model of physical processes in a magnetic field is discussed.

Relationship of extinction coefficient, air pollution, and meteorological parameters in an urban area during 2007 to 2009.

PubMed

Sabetghadam, Samaneh; Ahmadi-Givi, Farhang

2014-01-01

Light extinction, which is the extent of attenuation of light signal for every distance traveled by light in the absence of special weather conditions (e.g., fog and rain), can be expressed as the sum of scattering and absorption effects of aerosols. In this paper, diurnal and seasonal variations of the extinction coefficient are investigated for the urban areas of Tehran from 2007 to 2009. Cases of visibility impairment that were concurrent with reports of fog, mist, precipitation, or relative humidity above 90% are filtered. The mean value and standard deviation of daily extinction are 0.49 and 0.39 km(-1), respectively. The average is much higher than that in many other large cities in the world, indicating the rather poor air quality over Tehran. The extinction coefficient shows obvious diurnal variations in each season, with a peak in the morning that is more pronounced in the wintertime. Also, there is a very slight increasing trend in the annual variations of atmospheric extinction coefficient, which suggests that air quality has regressed since 2007. The horizontal extinction coefficient decreased from January to July in each year and then increased between July and December, with the maximum value in the winter. Diurnal variation of extinction is often associated with small values for low relative humidity (RH), but increases significantly at higher RH. Annual correlation analysis shows that there is a positive correlation between the extinction coefficient and RH, CO, PM10, SO2, and NO2 concentration, while negative correlation exists between the extinction and T, WS, and O3, implying their unfavorable impact on extinction variation. The extinction budget was derived from multiple regression equations using the regression coefficients. On average, 44% of the extinction is from suspended particles, 3% is from air molecules, about 5% is from NO2 absorption, 0.35% is from RH, and approximately 48% is unaccounted for, which may represent errors in the data as well as contribution of other atmospheric constituents omitted from the analysis. Stronger regression equation is achieved in the summer, meaning that the extinction is more predictable in this season using pollutant concentrations.

Radiative Properties of Cirrus Clouds in the Infrared (8-13 microns) Spectral Region

NASA Technical Reports Server (NTRS)

Yang, Ping; Gao, Bo-Cai; Baum, Bryan A.; Hu, Yong X.; Wiscombe, Warren J.; Tsay, Si-Chee; Winker, Dave M.; Einaudi, Franco (Technical Monitor)

2000-01-01

Atmospheric radiation in the infrared (IR) 8-13 microns spectral region contains a wealth of information that is very useful for the retrieval of ice cloud properties from aircraft or space-borne measurements. To provide the scattering and absorption properties of nonspherical ice crystals that are fundamental to the IR retrieval implementation, we use the finite-difference time domain (FDTD) method to solve for the extinction efficiency, single-scattering albedo, and the asymmetry parameter of the phase function for ice crystals smaller than 40 microns. For particles larger than this size, the improved geometric optics method (IGOM) can be employed to calculate the asymmetry parameter with an acceptable accuracy, provided that we properly account for the inhomogeneity of the refracted wave due to strong absorption inside the ice particle. A combination of the results computed from the two methods provides the asymmetry parameter for the entire practical range of particle sizes between 1 micron and 10000 microns over wavelengths ranging from 8 microns to 13 microns. For the extinction and absorption efficiency calculations, several methods including the IGOM, Mie solution for equivalent spheres (MSFES), and the anomalous diffraction theory (ADT) can lead to a substantial discontinuity in comparison with the FDTD solutions for particle sizes on the order of 40 microns. To overcome this difficulty, we have developed a novel approach called the stretched scattering potential method (SSPM). For the IR 8-13 microns spectral region, we show that SSPM is a more accurate approximation than ADT, MSFES, and IGOM. The SSPM solution can be further refined numerically. Through a combination of the FDTD and SSPM, we have computed the extinction and absorption efficiency for hexagonal ice crystals with sizes ranging from 1 to 10000 microns at 12 wavelengths between 8 and 13 microns Calculations of the cirrus bulk scattering and absorption properties are performed for 30 size distributions obtained from various field campaigns for midlatitude and tropical cirrus cloud systems. Parameterization of these bulk scattering properties is carried out by using second-order polynomial functions for the extinction efficiency and the single-scattering albedo and the power law expression for the asymmetry parameter. We note that the volume-normalized extinction coefficient can be separated into two parts: one is inversely proportional to effective size and is independent of wavelength, and the other is the wavelength-dependent effective extinction efficiency. Unlike conventional parameterization efforts, the present parameterization scheme is more accurate because only the latter part of the volume-normalized extinction coefficient is approximated in terms of an analytical expression. After averaging over size distribution, the single-scattering albedo is shown to decrease with an increase in effective size for wavelengths shorter than 10.0 microns whereas the opposite behavior is observed for longer wavelengths. The variation of the asymmetry parameter as a function of effective size is substantial when the effective size is smaller than 50 microns. For effective sizes larger than 100 microns, the asymmetry parameter approaches its asymptotic value. The results derived in this study can be useful to remote sensing applications involving IR window bands under cirrus cloud conditions.

Simultaneous aerosol/ocean products retrieved during the 2014 SABOR campaign using the NASA Research Scanning Polarimeter (RSP)

NASA Astrophysics Data System (ADS)

Stamnes, S.; Hostetler, C. A.; Ferrare, R. A.; Hair, J. W.; Burton, S. P.; Liu, X.; Hu, Y.; Stamnes, K. H.; Chowdhary, J.; Brian, C.

2017-12-01

The SABOR (Ship-Aircraft Bio-Optical Research) campaign was conducted during the summer of 2014, in the Atlantic Ocean, over the Chesapeake Bay and the eastern coastal region of the United States. The NASA GISS Research Scanning Polarimeter, a multi-angle, multi-spectral polarimeter measured the upwelling polarized radiances from a B200 aircraft. We present results from the new "MAPP" algorithm for RSP that is based on optimal estimation and that can retrieve simultaneous aerosol microphysical properties (including effective radius, single-scattering albedo, and real refractive index) and ocean color products using accurate radiative transfer and Mie calculations. The algorithm was applied to data collected during SABOR to retrieve aerosol microphysics and ocean products for all Aerosols-Above-Ocean (AAO) scenes. The RSP MAPP products are compared against collocated aerosol extinction and backscatter profiles collected by the NASA LaRC airborne High Spectral Resolution Lidar (HSRL-1), including lidar depth profiles of the ocean diffuse attenuation coefficient and the hemispherical backscatter coefficient.

[Reconstructed ambient light extinction coefficient and its contribution factors in Beijing in January, 2010].

PubMed

Zhu, Li-Hua; Tao, Jun; Chen, Zhong-Ming; Zhao, Yue; Zhang, Ren-Jian; Cao, Jun-Ji

2012-01-01

Aerosol samples for PM2.5 were collected from 1st January to 31st January 2010, in Beijing. The concentrations of organic carbon, elemental carbon, water-solubile ions and soil elements of all particle samples were determined by thermal/optical carbon analyzer, ion chromatography and X-ray fluorescence spectrometer, respectively. The scattering coefficients (b(sp)), absorbing coefficients (b(ap)) and meteorological parameters for this period were also measured. Ambient light extinction coefficients were reconstructed by IMPROVE formula and were compared with measured light extinction coefficients. The results showed that the average mass concentration of PM2.5 was (144.3 +/- 89.1) microg x m(-3) during campaigning period. The average values of measured b(ap), b(sp) and extinction coefficient (b(ext)) were (67.4 +/- 54.3), (328.5 +/- 353.8) and (395.9 +/- 405.2) Mm(-1), respectively. IMPROVE formula is suitable for source apportionment of light extinction coefficient in campaign period. The average value of calculated b'(ext) was (611 +/- 503) Mm(-1) in January, 2010. The major contributors to ambient light extinction coefficients included (NH4) 2SO4 (24.6%), NH4NO3 (11.6%), OM (45.5%), EC (11.9%) and FS (6.4%), respectively.

Inter-Comparison of ILAS-II Version 1.4 Aerosol Extinction Coefficient at 780 nm with SAGE II, SAGE III, and POAM III Aerosol Data

NASA Technical Reports Server (NTRS)

Saitoh, Naoko; Hayashida, S.; Sugita, T.; Nakajima, H.; Yokota, T.; Hayashi, M.; Shiraishi, K.; Kanzawa, H.; Ejiri, M. K.; Irie, H.;

[Modeling and Simulation of Spectral Polarimetric BRDF].

PubMed

Ling, Jin-jiang; Li, Gang; Zhang, Ren-bin; Tang, Qian; Ye, Qiu

2016-01-01

Under the conditions of the polarized light, The reflective surface of the object is affected by many factors, refractive index, surface roughness, and so the angle of incidence. For the rough surface in the different wavelengths of light exhibit different reflection characteristics of polarization, a spectral polarimetric BRDF based on Kirchhof theory is proposee. The spectral model of complex refraction index is combined with refraction index and extinction coefficient spectral model which were got by using the known complex refraction index at different value. Then get the spectral model of surface roughness derived from the classical surface roughness measuring method combined with the Fresnel reflection function. Take the spectral model of refraction index and roughness into the BRDF model, then the spectral polarimetirc BRDF model is proposed. Compare the simulation results of the refractive index varies with wavelength, roughness is constant, the refraction index and roughness both vary with wavelength and origin model with other papers, it shows that, the spectral polarimetric BRDF model can show the polarization characteristics of the surface accurately, and can provide a reliable basis for the application of polarization remote sensing, and other aspects of the classification of substances.

40 CFR 796.1050 - Absorption in aqueous solution: Ultraviolet/visible spectra.

Code of Federal Regulations, 2013 CFR

2013-07-01

... by both molar absorption coefficient (molar extinction coefficient) and band width. However, the..., expressed in cm; and the molar absorption (extinction) coefficient,εi, of each species. The absorbance...

40 CFR 796.1050 - Absorption in aqueous solution: Ultraviolet/visible spectra.

Code of Federal Regulations, 2012 CFR

2012-07-01

... by both molar absorption coefficient (molar extinction coefficient) and band width. However, the..., expressed in cm; and the molar absorption (extinction) coefficient,εi, of each species. The absorbance...

40 CFR 796.1050 - Absorption in aqueous solution: Ultraviolet/visible spectra.

Code of Federal Regulations, 2014 CFR

2014-07-01

... by both molar absorption coefficient (molar extinction coefficient) and band width. However, the..., expressed in cm; and the molar absorption (extinction) coefficient,εi, of each species. The absorbance...

Generalized Radiative Transfer as an Efficient Computational Tool for Spatial and/or Spectral Integration over Unresolved Variability in Multi-Angle Observations

NASA Astrophysics Data System (ADS)

Davis, A. B.; Xu, F.; Diner, D. J.

2017-12-01

Two perennial problems in applied theoretical and computational radiative transfer (RT) are: (1) the impact of unresolved spatial variability on large-scale fluxes (in climate models) or radiances (in remote sensing); and (2) efficient-yet-accurate estimation of broadband spectral integrals in radiant energy budget estimation as well as in remote sensing, in particular, of trace gases.Generalized RT (GRT) is a modification of classic RT in an optical medium with uniform extinction where Beer's exponential law for direct transmission is replaced by a monotonically decreasing function with a slower power-law decay. In a convenient parameterized version of GRT, mean extinction replaces the uniform value and just one new property is introduced. As a non-dimensional metric for the unresolved variability, we use the square of the mean extinction coefficient divided by its variance. This parameter is also the exponent of the power-law tail of the modified transmission law.This specific form of sub-exponential transmission has explored for almost two decades in application to spatial variability in the presence of long-range correlations, much like in turbulent media such as clouds, with a focus on multiple scattering. It has also been proposed by Conley and Collins (JQSRT, 112, 1525-, 2011) to improve on the standard (weak-line) implementation of the correlated-k technique for efficient spectral integration.We have merged these two applications within a rigorous formulation of the combined problem, and solve the new integral RT equations in the single-scattering limit. The result is illustrated by addressing practical problems in multi-angle remote sensing of aerosols using the O2 A-band, an emerging methodology for passive profiling of coarse aerosols and clouds.

Optical characterization of Mg-doped ZnO thin films deposited by RF magnetron sputtering technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Satyendra Kumar; Tripathi, Shweta; Hazra, Purnima

2016-05-06

This paper reports the in-depth analysis on optical characteristics of magnesium (Mg) doped zinc oxide (ZnO) thin films grown on p-silicon (Si) substrates by RF magnetron sputtering technique. The variable angle ellipsometer is used for the optical characterization of as-deposited thin films. The optical reflectance, transmission spectra and thickness of as-deposited thin films are measured in the spectral range of 300-800 nm with the help of the spectroscopic ellipsometer. The effect of Mg-doping on optical parameters such as optical bandgap, absorption coefficient, absorbance, extinction coefficient, refractive Index and dielectric constant for as-deposited thin films are extracted to show its application inmore » optoelectronic and photonic devices.« less

Information Retrieval from SAGE II and MFRSR Multi-Spectral Extinction Measurements

NASA Technical Reports Server (NTRS)

Lacis, Andrew A.; Hansen, James E. (Technical Monitor)

2001-01-01

Direct beam spectral extinction measurements of solar radiation contain important information on atmospheric composition in a form that is essentially free from multiple scattering contributions that otherwise tend to complicate the data analysis and information retrieval. Such direct beam extinction measurements are available from the solar occultation satellite-based measurements made by the Stratospheric and Aerosol Gas Experiment (SAGE II) instrument and by ground-based Multi-Filter Shadowband Radiometers (MFRSRs). The SAGE II data provide cross-sectional slices of the atmosphere twice per orbit at seven wavelengths between 385 and 1020 nm with approximately 1 km vertical resolution, while the MFRSR data provide atmospheric column measurements at six wavelengths between 415 and 940 nm but at one minute time intervals. We apply the same retrieval technique of simultaneous least-squares fit to the observed spectral extinctions to retrieve aerosol optical depth, effective radius and variance, and ozone, nitrogen dioxide, and water vapor amounts from the SAGE II and MFRSR measurements. The retrieval technique utilizes a physical model approach based on laboratory measurements of ozone and nitrogen dioxide extinction, line-by-line and numerical k-distribution calculations for water vapor absorption, and Mie scattering constraints on aerosol spectral extinction properties. The SAGE II measurements have the advantage of being self-calibrating in that deep space provides an effective zero point for the relative spectral extinctions. The MFRSR measurements require periodic clear-day Langley regression calibration events to maintain accurate knowledge of instrument calibration.

40 CFR 51.301 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... impairment. A deciview is a haze index derived from calculated light extinction, such that uniform changes in... (for the purposes of calculating deciview, the atmospheric light extinction coefficient must be... light extinction coefficient, expressed in inverse megameters (Mm−1). Existing stationary facility means...

40 CFR 51.301 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... impairment. A deciview is a haze index derived from calculated light extinction, such that uniform changes in... (for the purposes of calculating deciview, the atmospheric light extinction coefficient must be... light extinction coefficient, expressed in inverse megameters (Mm−1). Existing stationary facility means...

40 CFR 51.301 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... impairment. A deciview is a haze index derived from calculated light extinction, such that uniform changes in... (for the purposes of calculating deciview, the atmospheric light extinction coefficient must be... light extinction coefficient, expressed in inverse megameters (Mm−1). Existing stationary facility means...

40 CFR 51.301 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... impairment. A deciview is a haze index derived from calculated light extinction, such that uniform changes in... (for the purposes of calculating deciview, the atmospheric light extinction coefficient must be... light extinction coefficient, expressed in inverse megameters (Mm−1). Existing stationary facility means...

40 CFR 51.301 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... impairment. A deciview is a haze index derived from calculated light extinction, such that uniform changes in... (for the purposes of calculating deciview, the atmospheric light extinction coefficient must be... extinction coefficient, expressed in inverse megameters (Mm−1). Existing stationary facility means any of the...

Rare earth garnet selective emitter

NASA Technical Reports Server (NTRS)

Lowe, Roland A.; Chubb, Donald L.; Farmer, Serene C.; Good, Brian S.

1994-01-01

Thin film Ho-YAG and Er-YAG emitters with a platinum substrate exhibit high spectral emittance in the emission band (epsilon(sub lambda) approximately equal to 0.74, ((4)l(sub 15/2)) - ( (4)l(sub13/2)), for Er-YAG and epsilon(sub lambda) approximately equal to 0.65, ((5)l(sub 7))-((5)l(sub 8)) for Ho-YAG) at excellent candidates for high efficiency selective emitters in the thermophotovoltaics (TPV) systems operating at moderate temperatures (1200-1500K). Spectral emittance measurements of the thin films were made (1.2 less than lambda less than 3.0 microns) and compared to the theoretical emittances calculated using measured values of the spectral extinction coefficient. In this paper we present the results for a new class of rare earth ion selective emitters. These emitters are thin sections (less than 1 mm) of yttrium aluminum garnet (YAG) single crystal with a rare earth substitutional impurity. This paper presents normal spectral emittance, epsilon(sub lambda), measurements of holmium (Ho), and erbium (Er) doped YAG thin film selective emitters at 1500 K, and compares those results with the theoretical spectral emittance.

Using Airborne High Spectral Resolution Lidar Data to Evaluate Combined Active Plus Passive Retrievals of Aerosol Extinction Profiles

NASA Technical Reports Server (NTRS)

Burton, S. P.; Ferrare, R. A.; Kittaka, C.; Hostetler, C. A.; Hair, J. W.; Obland, M. D.; Rogers, R. R.; Cook, A. L.; Haper, D. B.

2008-01-01

Aerosol extinction profiles are derived from backscatter data by constraining the retrieval with column aerosol optical thickness (AOT), for example from coincident MODIS observations and without reliance on a priori assumptions about aerosol type or optical properties. The backscatter data were acquired with the NASA Langley High Spectral Resolution Lidar (HSRL). The HSRL also simultaneously measures extinction independently, thereby providing an ideal data set for evaluating the constrained retrieval of extinction from backscatter. We will show constrained extinction retrievals using various sources of column AOT, and examine comparisons with the HSRL extinction measurements and with a similar retrieval using data from the CALIOP lidar on the CALIPSO satellite.

Measurements of Soot Mass Absorption Coefficients from 300 to 660 nm

NASA Astrophysics Data System (ADS)

Renbaum-Wolff, Lindsay; Fisher, Al; Helgestad, Taylor; Lambe, Andrew; Sedlacek, Arthur; Smith, Geoffrey; Cappa, Christopher; Davidovits, Paul; Onasch, Timothy; Freedman, Andrew

2016-04-01

Soot, a product of incomplete combustion, plays an important role in the earth's climate system through the absorption and scattering of solar radiation. In particular, the assumed mass absorption coefficient (MAC) of soot and its variation with wavelength presents a significant uncertainty in the calculation of radiative forcing in global climate change models. As part of the fourth Boston College/Aerodyne soot properties measurement campaign, we have measured the mass absorption coefficient of soot produced by an inverted methane diffusion flame over a spectral range of 300-660 nm using a variety of optical absorption techniques. Extinction and absorption were measured using a dual cavity ringdown photoacoustic spectrometer (CRD-PAS, UC Davis) at 405 nm and 532 nm. Scattering and extinction were measured using a CAPS PMssa single scattering albedo monitor (Aerodyne) at 630 nm; the absorption coefficient was determined by subtraction. In addition, the absorption coefficients in 8 wavelength bands from 300 to 660 nm were measured using a new broadband photoacoustic absorption monitor (UGA). Soot particle mass was quantified using a centrifugal particle mass analyzer (CPMA, Cambustion), mobility size with a scanning mobility particle sizer (SMPS, TSI) and soot concentration with a CPC (Brechtel). The contribution of doubly charged particles to the sample mass was determined using a Single Particle Soot Photometer (DMT). Over a mass range of 1-8 fg, corresponding to differential mobility diameters of ~150 nm to 550 nm, the value of the soot MAC proved to be independent of mass for all wavelengths. The wavelength dependence of the MAC was best fit to a power law with an Absorption Ångstrom Coefficient slightly greater than 1.

[Determination of the error of aerosol extinction coefficient measured by DOAS].

PubMed

Si, Fu-qi; Liu, Jian-guo; Xie, Pin-hua; Zhang, Yu-jun; Wang, Mian; Liu, Wen-qing; Hiroaki, Kuze; Liu, Cheng; Nobuo, Takeuchi

2006-10-01

The method of defining the error of aerosol extinction coefficient measured by differential optical absorption spectroscopy (DOAS) is described. Some factors which could bring errors to result, such as variation of source, integral time, atmospheric turbulence, calibration of system parameter, displacement of system, and back scattering of particles, are analyzed. The error of aerosol extinction coefficient, 0.03 km(-1), is determined by theoretical analysis and practical measurement.

Noninvasive spectral imaging of skin chromophores based on multiple regression analysis aided by Monte Carlo simulation

NASA Astrophysics Data System (ADS)

Nishidate, Izumi; Wiswadarma, Aditya; Hase, Yota; Tanaka, Noriyuki; Maeda, Takaaki; Niizeki, Kyuichi; Aizu, Yoshihisa

2011-08-01

In order to visualize melanin and blood concentrations and oxygen saturation in human skin tissue, a simple imaging technique based on multispectral diffuse reflectance images acquired at six wavelengths (500, 520, 540, 560, 580 and 600nm) was developed. The technique utilizes multiple regression analysis aided by Monte Carlo simulation for diffuse reflectance spectra. Using the absorbance spectrum as a response variable and the extinction coefficients of melanin, oxygenated hemoglobin, and deoxygenated hemoglobin as predictor variables, multiple regression analysis provides regression coefficients. Concentrations of melanin and total blood are then determined from the regression coefficients using conversion vectors that are deduced numerically in advance, while oxygen saturation is obtained directly from the regression coefficients. Experiments with a tissue-like agar gel phantom validated the method. In vivo experiments with human skin of the human hand during upper limb occlusion and of the inner forearm exposed to UV irradiation demonstrated the ability of the method to evaluate physiological reactions of human skin tissue.

SOI ring resonators with controllable MMI coupler sections

NASA Astrophysics Data System (ADS)

Hu, Youfang; Gardes, Frédéric Y.; Mashanovich, Goran Z.; Reed, Graham T.

2011-01-01

A ring resonator using a single 2×2 MMI as the coupler section has the distinct advantages of low sensitivity to fabrication error, temperature, wavelength and polarisation. However, the coupling coefficient of the 2×2 MMI coupler is fixed; hence, the performance of this type of device is limited, e.g. transmission spectrum with high extinction ratio is difficult to achieve. We have designed and simulated ring resonators with coupler sections consisting of two 2×2 MMIs and phase shifters, so that the coupling efficiency can be varied from 0% to 100% with relative ease. For a single ring resonator, the transmission spectrum can be controlled to achieve an extinction ratio of >20dB and a spectral bandwidth of <1nm. For a multiple ring filter, the transmission spectrum can be controlled to achieve an extinction ratio of >30dB and a bandwidth of <1nm in addition, a flat-top transmission spectrum is also achievable. The whole device has a footprint of approximately 200μm by 100μm.

Transversely coupled Fabry-Perot resonators with Bragg grating reflectors.

PubMed

Saber, Md Ghulam; Wang, Yun; El-Fiky, Eslam; Patel, David; Shahriar, Kh Arif; Alam, Md Samiul; Jacques, Maxime; Xing, Zhenping; Xu, Luhua; Abadía, Nicolás; Plant, David V

2018-01-01

We design and demonstrate Fabry-Perot resonators with transverse coupling using Bragg gratings as reflectors on the silicon-on-insulator (SOI) platform. The effects of tailoring the cavity length and the coupling coefficient of the directional coupler on the spectral characteristics of the device are studied. The fabricated resonators achieved an extinction ratio (ER) of 37.28 dB and a Q-factor of 3356 with an effective cavity length of 110 μm, and an ER of 8.69 dB and a Q-factor of 23642 with a 943 μm effective cavity length. The resonator structure presented here has the highest reported ER on SOI and provides additional degrees of freedom compared to an all-pass ring resonator to tune the spectral characteristics.

Emittance Theory for Cylindrical Fiber Selective Emitter

NASA Technical Reports Server (NTRS)

Chubb, Donald L.

1998-01-01

A fibrous rare earth selective emitter is approximated as an infinitely long, cylinder. The spectral emittance, e(sub x), is obtained L- by solving the radiative transfer equations with appropriate boundary conditions and uniform temperature. For optical depth, K(sub R), where alpha(sub lambda), is the extinction coefficient and R is the cylinder radius, greater than 1 the spectral emittance depths, K(sub R) alpha(sub lambda)R, is nearly at its maximum value. There is an optimum cylinder radius, R(sub opt) for maximum emitter efficiency, n(sub E). Values for R(sub opt) are strongly dependent on the number of emission bands of the material. The optimum radius decreases slowly with increasing emitter temperature, while the maximum efficiency and useful radiated power increase rapidly with increasing, temperature.

Determination of a refractive index and an extinction coefficient of standard production of CVD-graphene.

PubMed

Ochoa-Martínez, Efraín; Gabás, Mercedes; Barrutia, Laura; Pesquera, Amaia; Centeno, Alba; Palanco, Santiago; Zurutuza, Amaia; Algora, Carlos

2015-01-28

The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical properties of the stacked structure is noticeable both in the visible and the ultraviolet spectral regions, thus masking the graphene optical response. Finally, the use of heat treatment under a nitrogen atmosphere of the graphene-based stacked structures, as a method to reduce the water content of the sample, and its effect on the optical response of both graphene and the residual debris layer are presented. The Lorentz-Drude model proposed for the optical response of graphene fits fairly well the experimental ellipsometric data for all the analysed graphene-based stacked structures.

The New Horizons Ultraviolet Solar Occultation by Pluto's Atmosphere

NASA Astrophysics Data System (ADS)

Young, L. A.; Kammer, J.; Steffl, A.; Gladstone, R.; Summers, M. E.; Strobel, D. F.; Hinson, D. P.; Stern, A.; Weaver, H. A., Jr.; Olkin, C.; Ennico Smith, K.; McComas, D. J.

2017-12-01

The Alice instrument on NASA's New Horizons spacecraft observed an ultraviolet solar occultation by Pluto's atmosphere on 2015 July 14, as the spacecraft flew nearly diametrically though the solar shadow. The resulting dataset was a time-series of spectra from 52 to 187 nm with a spectral resolution of 0.3 nm. From these, we derived line-of-sight abundances and local number densities for the major species (N2 and CH4) and minor hydrocarbons (C2H2, C2H4, C2H6), and line-of-sight optical depth and extinction coefficients for the haze. Analysis of these data imply that (1) temperatures in Pluto's upper atmosphere were colder than expected before the New Horizons flyby, with upper atmospheric temperatures near 65-68 K, and subsequently lower escape rates, dominated by CH4 escape over N2; (2) the lower atmosphere was very stable, placing the homopause within 12 km of the surface, (3) the abundance profiles of the "C2Hx hydrocarbons" had non-exponential density profiles that compared favorably with models for hydrocarbon production near 300-400 km and haze condensation near 200 km, and (4) haze had an extinction coefficient approximately proportional to N2 density.

Nanoparticle Distributions in Cancer and other Cells from Light Transmission Spectroscopy

NASA Astrophysics Data System (ADS)

Deatsch, Alison; Sun, Nan; Johnson, Jeffery; Stack, Sharon; Tanner, Carol; Ruggiero, Steven

We have measured the optical properties of whole cells and lysates using light transmission spectroscopy (LTS). LTS provides both the optical extinction coefficient in the wavelength range from 220 to 1100 nm and (by spectral inversion using a Mie model) the particle distribution density in the size range from 1 to 3000 nm. Our current work involves whole cells and lysates of cultured human oral cells and other plant and animal cells. We have found systematic differences in the optical extinction between cancer and normal whole cells and lysates, which translate to different particle size distributions (PSDs) for these materials. We have also found specific power-law dependences of particle density with particle diameter for cell lysates. This suggests a universality of the packing distribution in cells that can be compared to ideal Apollonian packing, with the cell modeled as a fractal body comprised of spheres on all size scales.

MULTIPLY: Development of a European HSRL Airborne Facility

NASA Astrophysics Data System (ADS)

Binietoglou, Ioannis; Serikov, Ilya; Nicolae, Doina; Amiridis, Vassillis; Belegante, Livio; Boscornea, Andrea; Brugmann, Bjorn; Costa Suros, Montserrat; Hellmann, David; Kokkalis, Panagiotis; Linne, Holger; Stachlewska, Iwona; Vajaiac, Sorin-Nicolae

2016-08-01

MULTIPLY is a novel airborne high spectral resolution lidar (HSRL) currently under development by a consortium of European institutions from Romania, Germany, Greece, and Poland. Its aim is to contribute to calibration and validations activities of the upcoming ESA aerosol sensing missions like ADM-Aeolus, EarthCARE and the Sentinel-3/-4/-5/-5p which include products related to atmospheric aerosols. The effectiveness of these missions depends on independent airborne measurements to develop and test the retrieval methods, and validate mission products following launch. The aim of ESA's MULTIPLY project is to design, develop, and test a multi-wavelength depolarization HSRL for airborne applications. The MULTIPLY lidar will deliver the aerosol extinction and backscatter coefficient profiles at three wavelengths (355nm, 532nm, 1064nm), as well as profiles of aerosol intensive parameters (Ångström exponents, extinction- to-backscatter ratios, and linear particle depolarization ratios).

The Measurement of Aerosol Optical Properties using Continuous Wave Cavity Ring-Down Techniques

NASA Technical Reports Server (NTRS)

Strawa, Anthony W.; Castaneda, Rene; Owano, Thomas; Baer, Douglas S.; Paldus, Barbara A.; Gore, Warren J. (Technical Monitor)

2002-01-01

Large uncertainties in the effects that aerosols have on climate require improved in situ measurements of extinction coefficient and single-scattering albedo. This paper describes the use of continuous wave cavity ring-down (CW-CRD) technology to address this problem. The innovations in this instrument are the use of CW-CRD to measure aerosol extinction coefficient, the simultaneous measurement of scattering coefficient, and small size suitable for a wide range of aircraft applications. Our prototype instrument measures extinction and scattering coefficient at 690 nm and extinction coefficient at 1550 nm. The instrument itself is small (60 x 48 x 15 cm) and relatively insensitive to vibrations. The prototype instrument has been tested in our lab and used in the field. While improvements in performance are needed, the prototype has been shown to make accurate and sensitive measurements of extinction and scattering coefficients. Combining these two parameters, one can obtain the single-scattering albedo and absorption coefficient, both important aerosol properties. The use of two wavelengths also allows us to obtain a quantitative idea of the size of the aerosol through the Angstrom exponent. Minimum sensitivity of the prototype instrument is 1.5 x 10(exp -6)/m (1.5 M/m). Validation of the measurement of extinction coefficient has been accomplished by comparing the measurement of calibration spheres with Mie calculations. This instrument and its successors have potential to help reduce uncertainty currently associated with aerosol optical properties and their spatial and temporal variation. Possible applications include studies of visibility, climate forcing by aerosol, and the validation of aerosol retrieval schemes from satellite data.

The Measurement of Aerosol Optical Properties Using Continuous Wave Cavity Ring-Down Techniques

NASA Technical Reports Server (NTRS)

Strawa, A. W.; Owano, T.; Castaneda, R.; Baer, D. S.; Paldus, B. A.; Gore, Warren J. (Technical Monitor)

2002-01-01

Large uncertainties in the effects that aerosols have on climate require improved in-situ measurements of extinction coefficient and single-scattering albedo. This abstract describes the use of continuous wave cavity ring-down (CW-CRD) technology to address this problem. The innovations in this instrument are the use of CW-CRD to measure aerosol extinction coefficient, the simultaneous measurement of scattering coefficient, and small size suitable for a wide range of aircraft applications. Our prototype instrument measures extinction and scattering coefficient at 690 nm and extinction coefficient at 1550 nm. The instrument itself is small (60 x 48 x 15 cm) and relatively insensitive to vibrations. The prototype instrument has been tested in our lab and used in the field. While improvements in performance are needed, the prototype has been shown to make accurate and sensitive measurements of extinction and scattering coefficients. Combining these two parameters, one can obtain the single-scattering albedo and absorption coefficient, both important aerosol properties. The use of two wavelengths also allows us to obtain a quantitative idea of the size of the aerosol through the Angstrom exponent. Minimum sensitivity of the prototype instrument is 1.5 x 10(exp -6)/m (1.5/Mm). Validation of the measurement of extinction coefficient has been accomplished by comparing the measurement of calibration spheres with Mie calculations. This instrument and its successors have potential to help reduce uncertainty currently associated with aerosol optical properties and their spatial and temporal variation. Possible applications include studies of visibility, climate forcing by aerosol, and the validation of aerosol retrieval schemes from satellite data.

Small-scale Scheimpflug lidar for aerosol extinction coefficient and vertical atmospheric transmittance detection.

PubMed

Sun, Guodong; Qin, Laian; Hou, Zaihong; Jing, Xu; He, Feng; Tan, Fengfu; Zhang, Silong

2018-03-19

In this paper, a new prototypical Scheimpflug lidar capable of detecting the aerosol extinction coefficient and vertical atmospheric transmittance at 1 km above the ground is described. The lidar system operates at 532 nm and can be used to detect aerosol extinction coefficients throughout an entire day. Then, the vertical atmospheric transmittance can be determined from the extinction coefficients with the equation of numerical integration in this area. CCD flat fielding of the image data is used to mitigate the effects of pixel sensitivity variation. An efficient method of two-dimensional wavelet transform according to a local threshold value has been proposed to reduce the Gaussian white noise in the lidar signal. Furthermore, a new iteration method of backscattering ratio based on genetic algorithm is presented to calculate the aerosol extinction coefficient and vertical atmospheric transmittance. Some simulations are performed to reduce the different levels of noise in the simulated signal in order to test the precision of the de-noising method and inversion algorithm. The simulation result shows that the root-mean-square errors of extinction coefficients are all less than 0.02 km -1 , and that the relative errors of the atmospheric transmittance between the model and inversion data are below 0.56% for all cases. The feasibility of the instrument and the inversion algorithm have also been verified by an optical experiment. The average relative errors of aerosol extinction coefficients between the Scheimpflug lidar and the conventional backscattering elastic lidar are 3.54% and 2.79% in the full overlap heights of two time points, respectively. This work opens up new possibilities of using a small-scale Scheimpflug lidar system for the remote sensing of atmospheric aerosols.

Variation of haemoglobin extinction coefficients can cause errors in the determination of haemoglobin concentration measured by near-infrared spectroscopy

NASA Astrophysics Data System (ADS)

Kim, J. G.; Liu, H.

2007-10-01

Near-infrared spectroscopy or imaging has been extensively applied to various biomedical applications since it can detect the concentrations of oxyhaemoglobin (HbO2), deoxyhaemoglobin (Hb) and total haemoglobin (Hbtotal) from deep tissues. To quantify concentrations of these haemoglobin derivatives, the extinction coefficient values of HbO2 and Hb have to be employed. However, it was not well recognized among researchers that small differences in extinction coefficients could cause significant errors in quantifying the concentrations of haemoglobin derivatives. In this study, we derived equations to estimate errors of haemoglobin derivatives caused by the variation of haemoglobin extinction coefficients. To prove our error analysis, we performed experiments using liquid-tissue phantoms containing 1% Intralipid in a phosphate-buffered saline solution. The gas intervention of pure oxygen was given in the solution to examine the oxygenation changes in the phantom, and 3 mL of human blood was added twice to show the changes in [Hbtotal]. The error calculation has shown that even a small variation (0.01 cm-1 mM-1) in extinction coefficients can produce appreciable relative errors in quantification of Δ[HbO2], Δ[Hb] and Δ[Hbtotal]. We have also observed that the error of Δ[Hbtotal] is not always larger than those of Δ[HbO2] and Δ[Hb]. This study concludes that we need to be aware of any variation in haemoglobin extinction coefficients, which could result from changes in temperature, and to utilize corresponding animal's haemoglobin extinction coefficients for the animal experiments, in order to obtain more accurate values of Δ[HbO2], Δ[Hb] and Δ[Hbtotal] from in vivo tissue measurements.

Extinction spectra of suspensions of microspheres: determination of the spectral refractive index and particle size distribution with nanometer accuracy.

PubMed

Gienger, Jonas; Bär, Markus; Neukammer, Jörg

2018-01-10

A method is presented to infer simultaneously the wavelength-dependent real refractive index (RI) of the material of microspheres and their size distribution from extinction measurements of particle suspensions. To derive the averaged spectral optical extinction cross section of the microspheres from such ensemble measurements, we determined the particle concentration by flow cytometry to an accuracy of typically 2% and adjusted the particle concentration to ensure that perturbations due to multiple scattering are negligible. For analysis of the extinction spectra, we employ Mie theory, a series-expansion representation of the refractive index and nonlinear numerical optimization. In contrast to other approaches, our method offers the advantage to simultaneously determine size, size distribution, and spectral refractive index of ensembles of microparticles including uncertainty estimation.

Grey Milky Way extinction from SDSS stellar photometry

NASA Astrophysics Data System (ADS)

Gorbikov, Evgeny; Brosch, Noah

2010-01-01

We report results concerning the distribution and properties of galactic extinction at high galactic latitudes derived from stellar statistics using the Sloan Digital Sky Survey (SDSS). We use the classical Wolf diagram method to identify regions with extinction, and derive the extinction and the extinction law of the dust using all five SDSS spectral bands. We estimate the distance to the extinguishing medium using simple assumptions about the stellar populations in the line of sight. We report the identification of three extinguishing clouds, each a few tens of pc wide, producing 0.2-0.4 mag of g'-band extinction, located 1-2 kpc away or 0.5-1 kpc above the Galactic plane. All clouds exhibit grey extinction, i.e. almost wavelength independent in the limited spectral range of the SDSS. We discuss the implication of this finding on general astrophysical questions.

Extinction coefficients of CC and CC bands in ethyne and ethene molecules interacting with Cu+ and Ag+ in zeolites--IR studies and quantumchemical DFT calculations.

PubMed

Kozyra, Paweł; Góra-Marek, Kinga; Datka, Jerzy

2015-02-05

The values of extinction coefficients of CC and CC IR bands of ethyne and ethene interacting with Cu+ and Ag+ in zeolites were determined in quantitative IR experiments and also by quantumchemical DFT calculations with QM/MM method. Both experimental and calculated values were in very good agreement validating the reliability of calculations. The values of extinction coefficients of ethyne and ethene interacting with bare cations and cations embedded in zeolite-like clusters were calculated. The interaction of organic molecules with Cu+ and Ag+ in zeolites ZSM-5 and especially charge transfers between molecule, cation and zeolite framework was also discussed in relation to the values of extinction coefficients. Copyright © 2014 Elsevier B.V. All rights reserved.

Aerosol properties from spectral extinction and backscatter estimated by an inverse Monte Carlo method.

PubMed

Ligon, D A; Gillespie, J B; Pellegrino, P

2000-08-20

The feasibility of using a generalized stochastic inversion methodology to estimate aerosol size distributions accurately by use of spectral extinction, backscatter data, or both is examined. The stochastic method used, inverse Monte Carlo (IMC), is verified with both simulated and experimental data from aerosols composed of spherical dielectrics with a known refractive index. Various levels of noise are superimposed on the data such that the effect of noise on the stability and results of inversion can be determined. Computational results show that the application of the IMC technique to inversion of spectral extinction or backscatter data or both can produce good estimates of aerosol size distributions. Specifically, for inversions for which both spectral extinction and backscatter data are used, the IMC technique was extremely accurate in determining particle size distributions well outside the wavelength range. Also, the IMC inversion results proved to be stable and accurate even when the data had significant noise, with a signal-to-noise ratio of 3.

Retrieval method of aerosol extinction coefficient profile by an integral lidar system and case study

NASA Astrophysics Data System (ADS)

Shan, Huihui; Zhang, Hui; Liu, Junjian; Wang, Shenhao; Ma, Xiaomin; Zhang, Lianqing; Liu, Dong; Xie, Chenbo; Tao, Zongming

2018-02-01

Aerosol extinction coefficient profile is an essential parameter for atmospheric radiation model. But it is difficult to get the full aerosol extinction profile from the ground to the tropopause especially in near ground precisely using backscattering lidar. A combined measurement of side-scattering, backscattering and Raman-scattering lidar is proposed to retrieve the aerosol extinction coefficient profile from the surface to the tropopause which covered a dynamic range of 5 orders. The side-scattering technique solves the dead zone and the overlap problem caused by the traditional lidar in the near range. Using the Raman-scattering the aerosol lidar ratio (extinction to backscatter ratio) can be obtained. The cases studies in this paper show the proposed method is reasonable and feasible.

Aerosol and Cloud Interaction Observed From High Spectral Resolution Lidar Data

NASA Technical Reports Server (NTRS)

Su, Wenying; Schuster, Gregory L.; Loeb, Norman G.; Rogers, Raymond R.; Ferrare, Richard A.; Hostetler, Chris A.; Hair, Johnathan W.; Obland, Michael D.

2008-01-01

Recent studies utilizing satellite retrievals have shown a strong correlation between aerosol optical depth (AOD) and cloud cover. However, these retrievals from passive sensors are subject to many limitations, including cloud adjacency (or 3D) effects, possible cloud contamination, uncertainty in the AOD retrieval. Some of these limitations do not exist in High Spectral Resolution Lidar (HSRL) observations; for instance, HSRL observations are not a ected by cloud adjacency effects, are less prone to cloud contamination, and offer accurate aerosol property measurements (backscatter coefficient, extinction coefficient, lidar ratio, backscatter Angstrom exponent,and aerosol optical depth) at a neospatial resolution (less than 100 m) in the vicinity of clouds. Hence, the HSRL provides an important dataset for studying aerosol and cloud interaction. In this study, we statistically analyze aircraft-based HSRL profiles according to their distance from the nearest cloud, assuring that all profile comparisons are subject to the same large-scale meteorological conditions. Our results indicate that AODs from HSRL are about 17% higher in the proximity of clouds (approximately 100 m) than far away from clouds (4.5 km), which is much smaller than the reported cloud 3D effect on AOD retrievals. The backscatter and extinction coefficients also systematically increase in the vicinity of clouds, which can be explained by aerosol swelling in the high relative humidity (RH) environment and/or aerosol growth through in cloud processing (albeit not conclusively). On the other hand, we do not observe a systematic trend in lidar ratio; we hypothesize that this is caused by the opposite effects of aerosol swelling and aerosol in-cloud processing on the lidar ratio. Finally, the observed backscatter Angstrom exponent (BAE) does not show a consistent trend because of the complicated relationship between BAE and RH. We demonstrate that BAE should not be used as a surrogate for Angstrom exponent, especially at high RH.

Dynamic Determination of Some Optical and Electrical Properties of Galena Natural Mineral: Potassium Ethyl Xanthate Solution Interface

NASA Astrophysics Data System (ADS)

Todoran, D.; Todoran, R.; Anitas, E. M.; Szakacs, Zs.

2017-12-01

This paper presents results concerning optical and electrical properties of galena natural mineral and of the interface layer formed between it and the potassium ethyl xanthate solution. The applied experimental method was differential optical reflectance spectroscopy over the UV-Vis/NIR spectral domain. Computations were made using the Kramers-Kronig formalism. Spectral dependencies of the electron loss functions, determined from the reflectance data obtained from the polished mineral surface, display van Hove singularities, leading to the determination of its valence band gap and electron plasma energy. Time dependent measurement of the spectral dispersion of the relative reflectance of the film formed at the interface, using the same computational formalism, leads to the dynamical determination of the spectral variation of its optical and electrical properties. We computed behaviors of the dielectric constant (dielectric permittivity), the dielectric loss function, refractive index and extinction coefficient, effective valence number and of the electron loss functions. The measurements tend to stabilize when the dynamic adsorption-desorption equilibrium is reached at the interface level.

Scattering characteristics of relativistically moving concentrically layered spheres

NASA Astrophysics Data System (ADS)

Garner, Timothy J.; Lakhtakia, Akhlesh; Breakall, James K.; Bohren, Craig F.

2018-02-01

The energy extinction cross section of a concentrically layered sphere varies with velocity as the Doppler shift moves the spectral content of the incident signal in the sphere's co-moving inertial reference frame toward or away from resonances of the sphere. Computations for hollow gold nanospheres show that the energy extinction cross section is high when the Doppler shift moves the incident signal's spectral content in the co-moving frame near the wavelength of the sphere's localized surface plasmon resonance. The energy extinction cross section of a three-layer sphere consisting of an olivine-silicate core surrounded by a porous and a magnetite layer, which is used to explain extinction caused by interstellar dust, also depends strongly on velocity. For this sphere, computations show that the energy extinction cross section is high when the Doppler shift moves the spectral content of the incident signal near either of olivine-silicate's two localized surface phonon resonances at 9.7 μm and 18 μm.

Measurement of aerosol optical properties by cw cavity enhanced spectroscopy

NASA Astrophysics Data System (ADS)

Jie, Guo; Ye, Shan-Shan; Yang, Xiao; Han, Ye-Xing; Tang, Huai-Wu; Yu, Zhi-Wei

2016-10-01

The CAPS (Cavity Attenuated Phase shift Spectroscopy) system, which detects the extinction coefficients within a 10 nm bandpass centered at 532 nm, comprises a green LED with center wavelength in 532nm, a resonant optical cavity (36 cm length), a Photo Multiplier Tube detector, and a lock in amplifier. The square wave modulated light from the LED passes through the optical cavity and is detected as a distorted waveform which is characterized by a phase shift with respect to the initial modulation. Extinction coefficients are determined from changes in the phase shift of the distorted waveform of the square wave modulated LED light that is transmitted through the optical cavity. The performance of the CAPS system was evaluated by using measurements of the stability and response of the system. The minima ( 0.1 Mm-1) in the Allan plots show the optimum average time ( 100s) for optimum detection performance of the CAPS system. In the paper, it illustrates that extinction coefficient was correlated with PM2.5 mass (0.91). These figures indicate that this method has the potential to become one of the most sensitive on-line analytical techniques for extinction coefficient detection. This work aims to provide an initial validation of the CAPS extinction monitor in laboratory and field environments. Our initial results presented in this paper show that the CAPS extinction monitor is capable of providing state-of-the-art performance while dramatically reducing the complexity of optical instrumentation for directly measuring the extinction coefficients.

Optical properties of non-spherical desert dust particles in the terrestrial infrared - An asymptotic approximation approach

NASA Astrophysics Data System (ADS)

Klüser, Lars; Di Biagio, Claudia; Kleiber, Paul D.; Formenti, Paola; Grassian, Vicki H.

2016-07-01

Optical properties (extinction efficiency, single scattering albedo, asymmetry parameter and scattering phase function) of five different desert dust minerals have been calculated with an asymptotic approximation approach (AAA) for non-spherical particles. The AAA method combines Rayleigh-limit approximations with an asymptotic geometric optics solution in a simple and straightforward formulation. The simulated extinction spectra have been compared with classical Lorenz-Mie calculations as well as with laboratory measurements of dust extinction. This comparison has been done for single minerals and with bulk dust samples collected from desert environments. It is shown that the non-spherical asymptotic approximation improves the spectral extinction pattern, including position of the extinction peaks, compared to the Lorenz-Mie calculations for spherical particles. Squared correlation coefficients from the asymptotic approach range from 0.84 to 0.96 for the mineral components whereas the corresponding numbers for Lorenz-Mie simulations range from 0.54 to 0.85. Moreover the blue shift typically found in Lorenz-Mie results is not present in the AAA simulations. The comparison of spectra simulated with the AAA for different shape assumptions suggests that the differences mainly stem from the assumption of the particle shape and not from the formulation of the method itself. It has been shown that the choice of particle shape strongly impacts the quality of the simulations. Additionally, the comparison of simulated extinction spectra with bulk dust measurements indicates that within airborne dust the composition may be inhomogeneous over the range of dust particle sizes, making the calculation of reliable radiative properties of desert dust even more complex.

Near-IR extinction and backscatter coefficient measurements in low- and mid-altitude clouds

NASA Technical Reports Server (NTRS)

Sztankay, Z. G.

1986-01-01

Knowledge of the attenuation and backscattering properties of clouds is required to high resolution for several types of optical sensing systems. Such data was obtained in about 15 hours of flights through clouds in the vicinity of Washington, D.C. The flights were mainly through stratocumulus, altocumulus, stratus, and stratus fractus clouds and covered an altitude and temperature range of 300 to 3200 m and -13 to 17 C. Two instruments were flown, each of which measured the backscatter from close range in two range bins to independently determine both the extinction and backscatter coefficients. The extinction and backscatter coefficients can be obtained from the signals in the two channels of each instrument, provided that the aerosol is uniform over the measurement region. When this assumptions holds, the extinction coefficient is derived basically from the ratio of the signal in the two channels; the backscatter coefficient can then be obtained from the signal in either channel.

Ultrafast studies of excess electrons in liquid acetonitrile: revisiting the solvated electron/solvent dimer anion equilibrium.

PubMed

Doan, Stephanie C; Schwartz, Benjamin J

2013-04-25

We examine the ultrafast relaxation dynamics of excess electrons injected into liquid acetonitrile using air- and water-free techniques and compare our results to previous work on this system [Xia, C. et al. J. Chem. Phys. 2002, 117, 8855]. Excess electrons in liquid acetonitrile take on two forms: a "traditional" solvated electron that absorbs in the near-IR, and a solvated molecular dimer anion that absorbs weakly in the visible. We find that excess electrons initially produced via charge-transfer-to-solvent excitation of iodide prefer to localize as solvated electrons, but that there is a subsequent equilibration to form the dimer anion on an ~80 ps time scale. The spectral signature of this interconversion between the two forms of the excess electron is a clear isosbestic point. The presence of the isosbestic point makes it possible to fully deconvolute the spectra of the two species. We find that solvated molecular anion absorbs quite weakly, with a maximum extinction coefficient of ~2000 M(-1)cm(-1). With the extinction coefficient of the dimer anion in hand, we are also able to determine the equilibrium constant for the two forms of excess electron, and find that the molecular anion is favored by a factor of ~4. We also find that relatively little geminate recombination takes place, and that the geminate recombination that does take place is essentially complete within the first 20 ps. Finally, we show that the presence of small amounts of water in the acetonitrile can have a fairly large effect on the observed spectral dynamics, explaining the differences between our results and those in previously published work.

THE IMPACT OF ACCURATE EXTINCTION MEASUREMENTS FOR X-RAY SPECTRAL MODELS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Randall K.; Valencic, Lynne A.; Corrales, Lia, E-mail: lynne.a.valencic@nasa.gov

Interstellar extinction includes both absorption and scattering of photons from interstellar gas and dust grains, and it has the effect of altering a source's spectrum and its total observed intensity. However, while multiple absorption models exist, there are no useful scattering models in standard X-ray spectrum fitting tools, such as XSPEC. Nonetheless, X-ray halos, created by scattering from dust grains, are detected around even moderately absorbed sources, and the impact on an observed source spectrum can be significant, if modest, compared to direct absorption. By convolving the scattering cross section with dust models, we have created a spectral model asmore » a function of energy, type of dust, and extraction region that can be used with models of direct absorption. This will ensure that the extinction model is consistent and enable direct connections to be made between a source's X-ray spectral fits and its UV/optical extinction.« less

Effectively Improving Extinction Coefficient of Benzodithiophene and Benzodithiophenedione-based Photovoltaic Polymer by Grafting Alkylthio Functional Groups.

PubMed

Wang, Qi; Zhang, Shaoqing; Xu, Bowei; Ye, Long; Yao, Huifeng; Cui, Yong; Zhang, Hao; Yuan, Wenxia; Hou, Jianhui

2016-10-06

Alkylthio groups have received much attention in the polymer community for their molecular design applications in polymer solar cells. In this work, alkylthio substitution on the conjugated thiophene side chains in benzodithiophene (BDT) and benzodithiophenedione (BDD)-based photovoltaic polymer was used to improve the extinction coefficient. The introduction of alkylthio groups into the polymer increased its extinction coefficient while the HOMO levels, bandgaps, and absorption bands remained the same. Thus, the short circuit current density (J sc ) and the efficiency of the device were much better than those of the control device. Thus, introducing the alkylthio functional group in polymer is an effective method to tune the extinction coefficient of photovoltaic polymer. This provides a new path to improve photovoltaic performance without increasing active layer thickness, which will be very helpful to design advanced photovoltaic materials for high photovoltaic performance. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Simultaneous all-optical determination of molecular concentration and extinction coefficient.

PubMed

Cho, Byungmoon; Tiwari, Vivek; Jonas, David M

2013-06-04

Absolute molecular number concentration and extinction coefficient are simultaneously determined from linear and nonlinear spectroscopic measurements. This method is based on measurements of absolute femtosecond pump-probe signals. Accounting for pulse propagation, we present a closed form expression for molecular number concentration in terms of absorbance, fluorescence, absolute pump-probe signal, and laser pulse parameters (pulse energy, spectrum, and spatial intensity profile); all quantities are measured optically. As in gravimetric and coulometric determinations of concentration, no standard samples are needed for calibration. The extinction coefficient can then be determined from the absorbance spectrum and the concentration. For fluorescein in basic methanol, the optically determined molar concentrations and extinction coefficients match gravimetric determinations to within 10% for concentrations from 0.032 to 0.540 mM, corresponding to absorbance from 0.06 to 1. In principle, this photonumeric method is extensible to transient chemical species for which other methods are not available.

Spectrally-resolved measurements of aerosol extinction at ultraviolet and visible wavelengths

NASA Astrophysics Data System (ADS)

Flores, M.; Washenfelder, R. A.; Brock, C. A.; Brown, S. S.; Rudich, Y.

2012-12-01

Aerosols play an important role in the Earth's radiative budget. Aerosol extinction includes both the scattering and absorption of light, and these vary with wavelength, aerosol diameter, and aerosol composition. Historically, aerosol absorption has been measured using filter-based or extraction methods that are prone to artifacts. There have been few investigations of ambient aerosol optical properties at the blue end of the visible spectrum and into the ultraviolet. Brown carbon is particularly important in this spectral region, because it both absorbs and scatters light, and encompasses a large and variable group of organic compounds from biomass burning and secondary organic aerosol. We have developed a laboratory instrument that combines new, high-power LED light sources with high-finesse optical cavities to achieve sensitive measurements of aerosol optical extinction. This instrument contains two broadband channels, with spectral coverage from 360 - 390 nm and 385 - 420 nm. Using this instrument, we report aerosol extinction in the ultraviolet and near-visible spectral region as a function of chemical composition and structure. We have measured the extinction cross-sections between 360 - 420 nm with 0.5 nm resolution using different sizes and concentrations of polystyrene latex spheres, ammonium sulfate, and Suwannee River fulvic acid. Fitting the real and imaginary part of the refractive index allows the absorption and scattering to be determined.

On Spectral Invariance of Single Scattering Albedo for Water Droplets and Ice Crystals at Weakly Absorbing Wavelengths

NASA Technical Reports Server (NTRS)

Marshak, Alexander; Knyazikhin, Yuri; Chiu, J. Christine; Wiscombe, Warren J.

2012-01-01

The single scattering albedo omega(sub O lambda) in atmospheric radiative transfer is the ratio of the scattering coefficient to the extinction coefficient. For cloud water droplets both the scattering and absorption coefficients, thus the single scattering albedo, are functions of wavelength lambda and droplet size r. This note shows that for water droplets at weakly absorbing wavelengths, the ratio omega(sub O lambda)(r)/omega(sub O lambda)(r (sub O)) of two single scattering albedo spectra is a linear function of omega(sub O lambda)(r). The slope and intercept of the linear function are wavelength independent and sum to unity. This relationship allows for a representation of any single scattering albedo spectrum omega(sub O lambda)(r) via one known spectrum omega(sub O lambda)(r (sub O)). We provide a simple physical explanation of the discovered relationship. Similar linear relationships were found for the single scattering albedo spectra of non-spherical ice crystals.

Electromagnetic wave extinction within a forested canopy

NASA Technical Reports Server (NTRS)

Karam, M. A.; Fung, A. K.

1989-01-01

A forested canopy is modeled by a collection of randomly oriented finite-length cylinders shaded by randomly oriented and distributed disk- or needle-shaped leaves. For a plane wave exciting the forested canopy, the extinction coefficient is formulated in terms of the extinction cross sections (ECSs) in the local frame of each forest component and the Eulerian angles of orientation (used to describe the orientation of each component). The ECSs in the local frame for the finite-length cylinders used to model the branches are obtained by using the forward-scattering theorem. ECSs in the local frame for the disk- and needle-shaped leaves are obtained by the summation of the absorption and scattering cross-sections. The behavior of the extinction coefficients with the incidence angle is investigated numerically for both deciduous and coniferous forest. The dependencies of the extinction coefficients on the orientation of the leaves are illustrated numerically.

The wavelength dependent model of extinction in fog and haze for free space optical communication.

PubMed

Grabner, Martin; Kvicera, Vaclav

2011-02-14

The wavelength dependence of the extinction coefficient in fog and haze is investigated using Mie single scattering theory. It is shown that the effective radius of drop size distribution determines the slope of the log-log dependence of the extinction on wavelengths in the interval between 0.2 and 2 microns. The relation between the atmospheric visibility and the effective radius is derived from the empirical relationship of liquid water content and extinction. Based on these results, the model of the relationship between visibility and the extinction coefficient with different effective radii for fog and for haze conditions is proposed.

Determination of nocturnal aerosol properties from a combination of lunar photometer and lidar observations

NASA Astrophysics Data System (ADS)

Li, Donghui; Li, Zhengqiang; Lv, Yang; Zhang, Ying; Li, Kaitao; Xu, Hua

2015-10-01

Aerosol plays a key role in the assessment of global climate change and environmental health, while observation is one of important way to deepen the understanding of aerosol properties. In this study, the newly instrument - lunar photometer is used to measure moonlight and nocturnal column aerosol optical depth (AOD, τ) is retrieved. The AOD algorithm is test and verified with sun photometer both in high and low aerosol loading. Ångström exponent (α) and fine/coarse mode AOD (τf, τc) 1 is derived from spectral AOD. The column aerosol properties (τ, α, τf, τc) inferred from the lunar photometer is analyzed based on two month measurement in Beijing. Micro-pulse lidar has advantages in retrieval of aerosol vertical distribution, especially in night. However, the typical solution of lidar equation needs lidar ratio(ratio of aerosol backscatter and extinction coefficient) assumed in advance(Fernald method), or constrained by AOD2. Yet lidar ratio is varied with aerosol type and not easy to fixed, and AOD is used of daylight measurement, which is not authentic when aerosol loading is different from day and night. In this paper, the nocturnal AOD measurement from lunar photometer combined with mie scattering lidar observations to inverse aerosol extinction coefficient(σ) profile in Beijing is discussed.

Probing the 9.7 μm Interstellar Silicate Extinction Profile through the Spitzer/IRS Spectroscopy of OB Stars

NASA Astrophysics Data System (ADS)

Shao, Zhenzhen; Jiang, B. W.; Li, Aigen; Gao, Jian; Lv, Zhangpan; Yao, Jiawen

2018-05-01

The 9.7 μm interstellar spectral feature, arising from the Si-O stretch of amorphous silicate dust, is the strongest extinction feature in the infrared (IR). In principle, the spectral profile of this feature could allow one to diagnose the mineralogical composition of interstellar silicate material. However, observationally, the 9.7 μm interstellar silicate extinction profile is not well determined. Here we utilize the Spitzer/IRS spectra of five early-type (one O- and four B-type) stars and compare them with that of unreddened stars of the same spectral type to probe the interstellar extinction of silicate dust around 9.7 μm. We find that, while the silicate extinction profiles all peak at ˜ 9.7 μm, two stars exhibit a narrow feature of FWHM ˜ 2.0 μm and three stars display a broad feature of FWHM ˜ 3.0 μm. We also find that the width of the 9.7 μm extinction feature does not show any environmental dependence. With a FWHM of ˜ 2.2 μm, the mean 9.7 μm extinction profile, obtained by averaging over our five stars, closely resembles that of the prototypical diffuse interstellar medium along the lines of sight toward Cyg OB2 No. 12 and WR 98a. Finally, an analytical formula is presented to parameterize the interstellar extinction in the IR at 0.9 μm ≲ λ ≲ 15 μm.

A subtle calculation method for nanoparticle’s molar extinction coefficient: The gift from discrete protein-nanoparticle system on agarose gel electrophoresis

NASA Astrophysics Data System (ADS)

Zhong, Ruibo; Yuan, Ming; Gao, Haiyang; Bai, Zhijun; Guo, Jun; Zhao, Xinmin; Zhang, Feng

2016-03-01

Discrete biomolecule-nanoparticle (NP) conjugates play paramount roles in nanofabrication, in which the key is to get the precise molar extinction coefficient of NPs. By making best use of the gift from a specific separation phenomenon of agarose gel electrophoresis (GE), amphiphilic polymer coated NP with exact number of bovine serum albumin (BSA) proteins can be extracted and further experimentally employed to precisely calculate the molar extinction coefficient of the NPs. This method could further benefit the evaluation and extraction of any other dual-component NP-containing bio-conjugates.

Theoretical simulation of solar spectra in the middle ultraviolet and visible for atmospheric trace constituent measurements

NASA Technical Reports Server (NTRS)

Goldman, A.

1978-01-01

Two balloon flights reaching float altitudes of approximately 30 and 40 km respectively, were used to obtain scans of the ultraviolet and visible solar spectra. Both flights covered the UV (2800-3500A) at approximately 0.3A resolution and the visible at approximately 0.6A. Numerous scans were obtained during ascent and from float for both flights. All spectral scans obtained at float, from high sun to low sun, were calibrated in wavelength by using several standard solar spectra for line position references. Comparisons of low sun scans and high sun scans show significant atmospheric continuum extinction and have the potential of being used to identify atmospheric lines superimposed on the attenuated solar spectrum. The resolution was mathematically degraded to approximately 5A to better see the broad band atmospheric extinction. This low resolution is also appropriate for the available low resolution absorption coefficients of NO2 and O3, allowing the identification of NO2 and O3 features on the sunset spectra.

Estimation of black carbon content for biomass burning aerosols from multi-channel Raman lidar data

NASA Astrophysics Data System (ADS)

Talianu, Camelia; Marmureanu, Luminita; Nicolae, Doina

2015-04-01

Biomass burning due to natural processes (forest fires) or anthropical activities (agriculture, thermal power stations, domestic heating) is an important source of aerosols with a high content of carbon components (black carbon and organic carbon). Multi-channel Raman lidars provide information on the spectral dependence of the backscatter and extinction coefficients, embedding information on the black carbon content. Aerosols with a high content of black carbon have large extinction coefficients and small backscatter coefficients (strong absorption), while aerosols with high content of organic carbon have large backscatter coefficients (weak absorption). This paper presents a method based on radiative calculations to estimate the black carbon content of biomass burning aerosols from 3b+2a+1d lidar signals. Data is collected at Magurele, Romania, at the cross-road of air masses coming from Ukraine, Russia and Greece, where burning events are frequent during both cold and hot seasons. Aerosols are transported in the free troposphere, generally in the 2-4 km altitude range, and reaches the lidar location after 2-3 days. Optical data are collected between 2011-2012 by a multi-channel Raman lidar and follows the quality assurance program of EARLINET. Radiative calculations are made with libRadTran, an open source radiative model developed by ESA. Validation of the retrievals is made by comparison to a co-located C-ToF Aerosol Mass Spectrometer. Keywords: Lidar, aerosols, biomass burning, radiative model, black carbon Acknowledgment: This work has been supported by grants of the Romanian National Authority for Scientific Research, Programme for Research- Space Technology and Advanced Research - STAR, project no. 39/2012 - SIAFIM, and by Romanian Partnerships in priority areas PNII implemented with MEN-UEFISCDI support, project no. 309/2014 - MOBBE

Dispersion and thermal properties of lithium aluminum silicate glasses doped with Cr3+ ions

NASA Astrophysics Data System (ADS)

El-Diasty, Fouad; Abdel-Baki, Manal; Abdel Wahab, Fathy A.; Darwish, Hussein

2006-10-01

A series of new lithium aluminum silicate (LAS) glass systems doped with chromium ion is prepared. The reflectance and transmittance of the glass slabs are recorded. By means of an iteration procedure, the glass refractive index n and the extinction coefficient k and their dispersions are obtained. Across a wide spectral range of 0.2-1.6 μm, the dispersion curves are used to determine the atomic and quantum constants of the prepared glasses. These findings provide the average oscillator wavelength, the average oscillator strength, oscillator energy, dispersion energy, lattice energy, and material dispersion of the glass materials to be calculated. For optical waveguide applications, the wavelength for zero material dispersion is obtained. Dilatometric measurements are performed and the thermal expansion coefficient is calculated to throw some light on the thermo-optical properties of the present glasses correlating them with their structure and the presence of nonbridging oxygen ions.

Arrange and average algorithm for the retrieval of aerosol parameters from multiwavelength high-spectral-resolution lidar/Raman lidar data.

PubMed

Chemyakin, Eduard; Müller, Detlef; Burton, Sharon; Kolgotin, Alexei; Hostetler, Chris; Ferrare, Richard

2014-11-01

We present the results of a feasibility study in which a simple, automated, and unsupervised algorithm, which we call the arrange and average algorithm, is used to infer microphysical parameters (complex refractive index, effective radius, total number, surface area, and volume concentrations) of atmospheric aerosol particles. The algorithm uses backscatter coefficients at 355, 532, and 1064 nm and extinction coefficients at 355 and 532 nm as input information. Testing of the algorithm is based on synthetic optical data that are computed from prescribed monomodal particle size distributions and complex refractive indices that describe spherical, primarily fine mode pollution particles. We tested the performance of the algorithm for the "3 backscatter (β)+2 extinction (α)" configuration of a multiwavelength aerosol high-spectral-resolution lidar (HSRL) or Raman lidar. We investigated the degree to which the microphysical results retrieved by this algorithm depends on the number of input backscatter and extinction coefficients. For example, we tested "3β+1α," "2β+1α," and "3β" lidar configurations. This arrange and average algorithm can be used in two ways. First, it can be applied for quick data processing of experimental data acquired with lidar. Fast automated retrievals of microphysical particle properties are needed in view of the enormous amount of data that can be acquired by the NASA Langley Research Center's airborne "3β+2α" High-Spectral-Resolution Lidar (HSRL-2). It would prove useful for the growing number of ground-based multiwavelength lidar networks, and it would provide an option for analyzing the vast amount of optical data acquired with a future spaceborne multiwavelength lidar. The second potential application is to improve the microphysical particle characterization with our existing inversion algorithm that uses Tikhonov's inversion with regularization. This advanced algorithm has recently undergone development to allow automated and unsupervised processing; the arrange and average algorithm can be used as a preclassifier to further improve its speed and precision. First tests of the performance of arrange and average algorithm are encouraging. We used a set of 48 different monomodal particle size distributions, 4 real parts and 15 imaginary parts of the complex refractive index. All in all we tested 2880 different optical data sets for 0%, 10%, and 20% Gaussian measurement noise (one-standard deviation). In the case of the "3β+2α" configuration with 10% measurement noise, we retrieve the particle effective radius to within 27% for 1964 (68.2%) of the test optical data sets. The number concentration is obtained to 76%, the surface area concentration to 16%, and the volume concentration to 30% precision. The "3β" configuration performs significantly poorer. The performance of the "3β+1α" and "2β+1α" configurations is intermediate between the "3β+2α" and the "3β."

Mass extinction efficiency and extinction hygroscopicity of ambient PM2.5 in urban China.

PubMed

Cheng, Zhen; Ma, Xin; He, Yujie; Jiang, Jingkun; Wang, Xiaoliang; Wang, Yungang; Sheng, Li; Hu, Jiangkai; Yan, Naiqiang

2017-07-01

The ambient PM 2.5 pollution problem in China has drawn substantial international attentions. The mass extinction efficiency (MEE) and hygroscopicity factor (f(RH)) of PM 2.5 can be readily applied to study the impacts on atmospheric visibility and climate. The few previous investigations in China only reported results from pilot studies and are lack of spatial representativeness. In this study, hourly average ambient PM 2.5 mass concentration, relative humidity, and atmospheric visibility data from China national air quality and meteorological monitoring networks were retrieved and analyzed. It includes 24 major Chinese cities from nine city-clusters with the period of October 2013 to September 2014. Annual average extinction coefficient in urban China was 759.3±258.3Mm -1 , mainly caused by dry PM 2.5 (305.8.2±131.0Mm -1 ) and its hygroscopicity (414.6±188.1Mm -1 ). High extinction coefficient values were resulted from both high ambient PM 2.5 concentration (68.5±21.7µg/m 3 ) and high relative humidity (69.7±8.6%). The PM 2.5 mass extinction efficiency varied from 2.87 to 6.64m 2 /g with an average of 4.40±0.84m 2 /g. The average extinction hygroscopic factor f(RH=80%) was 2.63±0.45. The levels of PM 2.5 mass extinction efficiency and hygroscopic factor in China were in comparable range with those found in developed countries in spite of the significant diversities among all 24 cities. Our findings help to establish quantitative relationship between ambient extinction coefficient (visual range) and PM 2.5 & relative humidity. It will reduce the uncertainty of extinction coefficient estimation of ambient PM 2.5 in urban China which is essential for the research of haze pollution and climate radiative forcing. Copyright © 2017 Elsevier Inc. All rights reserved.

A Compact Airborne High Spectral Resolution Lidar for Observations of Aerosol and Cloud Optical Properties

NASA Technical Reports Server (NTRS)

Hostetler, Chris A.; Hair, John W.; Cook, Anthony L.

2002-01-01

We are in the process of developing a nadir-viewing, aircraft-based high spectral resolution lidar (HSRL) at NASA Langley Research Center. The system is designed to measure backscatter and extinction of aerosols and tenuous clouds. The primary uses of the instrument will be to validate spaceborne aerosol and cloud observations, carry out regional process studies, and assess the predictions of chemical transport models. In this paper, we provide an overview of the instrument design and present the results of simulations showing the instrument's capability to accurately measure extinction and extinction-to-backscatter ratio.

An Algorithm for the Vertical Structure of Aerosol Extinction in the Lowest Kilometer of the Atmosphere: Rev. 1

DTIC Science & Technology

2017-11-01

inversion layer, or the well-mixed boundary layer. In such cases a low cloud ceiling is not present. In all instances the atmospheric extinction profiles...height, radiation fog depth, or the inversion layer height. The visibility regions and several representative vertical profiles of extinction are...the coefficient B can be found by B = ln(D/A) . (2) The coefficient B is sometimes a function of the cloud ceiling height, the inversion layer height

Applications of broadband cavity enhanced spectroscopy for measurements of trace gases and aerosols

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Attwood, A. R.; Brock, C. A.; Brown, S. S.; Dube, W. P.; Flores, J. M.; Langford, A. O.; Min, K. E.; Rudich, Y.; Stutz, J.; Wagner, N.; Young, C.; Zarzana, K. J.

2015-12-01

Broadband cavity enhanced spectroscopy (BBCES) uses a broadband light source, optical cavity, and multichannel detector to measure light extinction with high sensitivity. This method differs from cavity ringdown spectroscopy, because it uses an inexpensive, incoherent light source and allows optical extinction to be determined simultaneously across a broad wavelength region.Spectral fitting methods can be used to retrieve multiple absorbers across the observed wavelength region. We have successfully used this method to measure glyoxal (CHOCHO), nitrous acid (HONO), and nitrogen dioxide (NO2) from ground-based and aircraft-based sampling platforms. The detection limit (2-sigma) in 5 s for retrievals of CHOCHO, HONO and NO2 is 32, 250 and 80 parts per trillion (pptv).Alternatively, gas-phase absorbers can be chemically removed to allow the accurate determination of aerosol extinction. In the laboratory, we have used the aerosol extinction measurements to determine scattering and absorption as a function of wavelength. We have deployed a ground-based field instrument to measure aerosol extinction, with a detection limit of approximately 0.2 Mm-1 in 1 min.BBCES methods are most widely used in the near-ultraviolet and visible spectral region. Recently, we have demonstrated measurements at 315-350 nm for formaldehyde (CH2O) and NO2. Extending the technique further into the ultraviolet spectral region will allow important additional measurements of trace gas species and aerosol extinction.

Markov chain formalism for generalized radiative transfer in a plane-parallel medium, accounting for polarization

NASA Astrophysics Data System (ADS)

Xu, Feng; Davis, Anthony B.; Diner, David J.

2016-11-01

A Markov chain formalism is developed for computing the transport of polarized radiation according to Generalized Radiative Transfer (GRT) theory, which was developed recently to account for unresolved random fluctuations of scattering particle density and can also be applied to unresolved spectral variability of gaseous absorption as an improvement over the standard correlated-k method. Using Gamma distribution to describe the probability density function of the extinction or absorption coefficient, a shape parameter a that quantifies the variability is introduced, defined as the mean extinction or absorption coefficient squared divided by its variance. It controls the decay rate of a power-law transmission that replaces the usual exponential Beer-Lambert-Bouguer law. Exponential transmission, hence classic RT, is recovered when a→∞. The new approach is verified to high accuracy against numerical benchmark results obtained with a custom Monte Carlo method. For a<∞, angular reciprocity is violated to a degree that increases with the spatial variability, as observed for finite portions of real-world cloudy scenes. While the degree of linear polarization in liquid water cloudbows, supernumerary bows, and glories is affected by spatial heterogeneity, the positions in scattering angle of these features are relatively unchanged. As a result, a single-scattering model based on the assumption of subpixel homogeneity can still be used to derive droplet size distributions from polarimetric measurements of extended stratocumulus clouds.

Lidars for smoke and dust cloud diagnostics

NASA Astrophysics Data System (ADS)

Fujimura, S. F.; Warren, R. E.; Lutomirski, R. F.

1980-11-01

An algorithm that integrates a time-resolved lidar signature for use in estimating transmittance, extinction coefficient, mass concentration, and CL values generated under battlefield conditions is applied to lidar signatures measured during the DIRT-I tests. Estimates are given for the dependence of the inferred transmittance and extinction coefficient on uncertainties in parameters such as the obscurant backscatter-to-extinction ratio. The enhanced reliability in estimating transmittance through use of a target behind the obscurant cloud is discussed. It is found that the inversion algorithm can produce reliable estimates of smoke or dust transmittance and extinction from all points within the cloud for which a resolvable signal can be detected, and that a single point calibration measurement can convert the extinction values to mass concentration for each resolvable signal point.

Polarization extinction ratio of the polarization crosstalk caused by point pressure force in the polarization-maintaining fiber

NASA Astrophysics Data System (ADS)

Mukhtubayev, Azamat B.; Aksarin, Stanislav M.; Strigalev, Vladimir E.

2017-11-01

A study of the orthogonal polarization modes crosstalk changes in the point of different mechanical actions (pressure force) in the polarization-maintaining fiber with straining elliptical cladding is presented. It was found that by increasing of the pressure force the polarization extinction ratio increases nonlinearly. Also revealed the dependence of the extinction coefficient and the angle between vector of the mechanical action and polarization axes of the test fiber, which leads to change the extinction coefficient variable from -57 dB to -25 dB under the pressure force of 0.7 N. Also it was found that the cross angle of the fiber axes doesn't influence on the extinction ratio value of the mechanical induced polarization crosstalk.

Laser measurement of extinction coefficients of highly absorbing liquids. [airborne oil spill monitoring application

NASA Technical Reports Server (NTRS)

Hoge, F. E.; Kincaid, J. S.

1980-01-01

A coaxial dual-channel laser system has been developed for the measurement of extinction coefficients of highly absorbing liquids. An empty wedge-shaped sample cell is first translated laterally through a He-Ne laser beam to measure the differential thickness using interference fringes in reflection. The wedge cell is carefully filled with the oil sample and translated through the coaxially positioned dye laser beam for the differential attenuation or extinction measurement. Optional use of the instrumentation as a single-channel extinction measurement system and also as a refractometer is detailed. The system and calibration techniques were applied to the measurement of two crude oils whose extinction values were required to complete the analysis of airborne laser data gathered over four controlled spills.

Does spatial arrangement of 3D plants affect light transmission and extinction coefficient within maize crops?

USDA-ARS?s Scientific Manuscript database

Row spacing effects on light interception and extinction coefficient have been inconsistent for maize (Zea mays L.) when calculated with field measurements. To avoid inconsistencies due to variable light conditions and variable leaf canopies, we used a model to describe three-dimensional (3D) shoot ...

FDTD analysis of the light extraction efficiency of OLEDs with a random scattering layer.

PubMed

Kim, Jun-Whee; Jang, Ji-Hyang; Oh, Min-Cheol; Shin, Jin-Wook; Cho, Doo-Hee; Moon, Jae-Hyun; Lee, Jeong-Ik

2014-01-13

The light extraction efficiency of OLEDs with a nano-sized random scattering layer (RSL-OLEDs) was analyzed using the Finite Difference Time Domain (FDTD) method. In contrast to periodic diffraction patterns, the presence of an RSL suppresses the spectral shift with respect to the viewing angle. For FDTD simulation of RSL-OLEDs, a planar light source with a certain spatial and temporal coherence was incorporated, and the light extraction efficiency with respect to the fill factor of the RSL and the absorption coefficient of the material was investigated. The design results were compared to the experimental results of the RSL-OLEDs in order to confirm the usefulness of FDTD in predicting experimental results. According to our FDTD simulations, the light confined within the ITO-organic waveguide was quickly absorbed, and the absorption coefficients of ITO and RSL materials should be reduced in order to obtain significant improvement in the external quantum efficiency (EQE). When the extinction coefficient of ITO was 0.01, the EQE in the RSL-OLED was simulated to be enhanced by a factor of 1.8.

Extinction coefficients from lidar observations in ice clouds compared to in-situ measurements from the Cloud Integrating Nephelometer during CRYSTAL-FACE

NASA Technical Reports Server (NTRS)

Noel, Vincent; Winker, D. M.; Garrett, T. J.; McGill, M.

2005-01-01

This paper presents a comparison of volume extinction coefficients in tropical ice clouds retrieved from two instruments : the 532-nm Cloud Physics Lidar (CPL), and the in-situ probe Cloud Integrating Nephelometer (CIN). Both instruments were mounted on airborne platforms during the CRYSTAL-FACE campaign and took measurements in ice clouds up to 17km. Coincident observations from three cloud cases are compared : one synoptically-generated cirrus cloud of low optical depth, and two ice clouds located on top of convective systems. Emphasis is put on the vertical variability of the extinction coefficient. Results show small differences on small spatial scales (approx. 100m) in retrievals from both instruments. Lidar retrievals also show higher extinction coefficients in the synoptic cirrus case, while the opposite tendency is observed in convective cloud systems. These differences are generally variations around the average profile given by the CPL though, and general trends on larger spatial scales are usually well reproduced. A good agreement exists between the two instruments, with an average difference of less than 16% on optical depth retrievals.

Toward a Combined SAGE II-HALOE Aerosol Climatology: An Evaluation of HALOE Version 19 Stratospheric Aerosol Extinction Coefficient Observations

NASA Technical Reports Server (NTRS)

Thomason, L. W.

2012-01-01

Herein, the Halogen Occultation Experiment (HALOE) aerosol extinction coefficient data is evaluated in the low aerosol loading period after 1996 as the first necessary step in a process that will eventually allow the production of a combined HALOE/SAGE II (Stratospheric Aerosol and Gas Experiment) aerosol climatology of derived aerosol products including surface area density. Based on these analyses, it is demonstrated that HALOE's 3.46 microns is of good quality above 19 km and suitable for scientific applications above that altitude. However, it is increasingly suspect at lower altitudes and should not be used below 17 km under any circumstances after 1996. The 3.40 microns is biased by about 10% throughout the lower stratosphere due to the failure to clear NO2 but otherwise appears to be a high quality product down to 15 km. The 2.45 and 5.26 micron aerosol extinction coefficient measurements are clearly biased and should not be used for scientific applications after the most intense parts of the Pinatubo period. Many of the issues in the aerosol data appear to be related to either the failure to clear some interfering gas species or doing so poorly. For instance, it is clear that the 3.40micronaerosol extinction coefficient measurements can be improved through the inclusion of an NO2 correction and could, in fact, end up as the highest quality overall HALOE aerosol extinction coefficient measurement. It also appears that the 2.45 and 5.26 micron channels may be improved by updating the Upper Atmosphere Pilot Database which is used as a resource for the removal of gas species otherwise not available from direct HALOE measurements. Finally, a simple model to demonstrate the promise of mixed visible/infrared aerosol extinction coefficient ensembles for the retrieval of bulk aerosol properties demonstrates that a combined HALOE/SAGE II aerosol climatology is feasible and may represent a substantial improvement over independently derived data sets.

Direct comparison of extinction coefficients derived from Mie-scattering lidar and number concentrations of particles, subjective weather report in Japan

NASA Astrophysics Data System (ADS)

Shimizu, Atsushi; Sugimoto, Nobuo; Matsui, Ichiro; Nishizawa, Tomoaki

2015-03-01

Two components of the lidar extinction coefficient, the dust extinction and the spherical particles extinction, were obtained from observations made by the National Institute for Environmental Studies lidar network in Japan. These two extinctions were compared with the number concentration of particles measured by an optical particle counter, and with subjective weather reports recorded at the nearest meteorological observatories. The dust extinction corresponded well with the number concentration of large particles with diameters as great as 5 μm and during dry conditions with the number concentration of particles larger than 2 μm. The relationship between the spherical particle extinction and the number of small particles was nearly constant under all conditions. Asian dust was sometimes reported by meteorological observatories in the period of lower dust extinction. This indicates contradicting relationship between human-eye based reports and optical characteristics observed by lidars in some cases. The most consistent results between lidar observation and meteorological reports were obtained in dry mist conditions, in which lidars exhibited higher spherical extinction as expected by the definition of the atmospheric phenomenon of dry mist or haze.

Characteristic of Nano-Cu Film Prepared by Energy Filtrating Magnetron Sputtering Technique and Its Optical Property

NASA Astrophysics Data System (ADS)

Wang, Zhaoyong; Hu, Xing; Yao, Ning

2015-03-01

At the optimized deposition parameters, Cu film was deposited by the direct current magnetron sputtering (DMS) technique and the energy filtrating magnetron sputtering (EFMS) technique. The nano-structure was charactered by x-ray diffraction. The surface morphology of the film was observed by atomic force microscopy. The optical properties of the film were measured by spectroscopic ellipsometry. The refractive index, extinction coefficient and the thickness of the film were obtained by the fitted spectroscopic ellipsometry data using the Drude-Lorentz oscillator optical model. Results suggested that a Cu film with different properties was fabricated by the EFMS technique. The film containing smaller particles is denser and the surface is smoother. The average transmission coefficient, the refractive index and the extinction coefficients are higher than those of the Cu film deposited by the DMS technique. The average transmission coefficient (400-800 nm) is more than three times higher. The refractive index and extinction coefficient (at 550 nm) are more than 36% and 14% higher, respectively.

Albedo and flux extinction coefficient of impure snow for diffuse shortwave radiation

NASA Technical Reports Server (NTRS)

Choudhury, B. J.; Mo, T.; Wang, J. R.; Chang, A. T. C.

1981-01-01

Impurities enter a snowpack as a result of fallout of scavenging by falling snow crystals. Albedo and flux extinction coefficient of soot contaminated snowcovers were studied using a two stream approximation of the radiative transfer equation. The effect of soot was calculated by two methods: independent scattering by ice grains and impurities and average refractive index for ice grains. Both methods predict a qualitatively similar effect of soot; the albedo is decreased and the extinction coefficient is increased compared to that for pure snow in the visible region; the infrared properties are largely unaffected. Quantitatively, however, the effect of soot is more pronounced in the average refractive index method. Soot contamination provides a qualitative explanation for several snow observations.

Fabry-Perot resonators with transverse coupling on SOI using loop mirrors

NASA Astrophysics Data System (ADS)

Saber, Md Ghulam; Abadía, Nicolás; Wang, Yun; Plant, David V.

2018-05-01

A novel integrated transversely coupled Fabry-Perot resonator using loop mirrors as the end reflectors are demonstrated via simulations and experiments on the silicon-on-insulator (SOI) platform. The resonator is formed by connecting two loop mirrors to the two output ports of a directional coupler to form the resonant cavity and utilizing the other two ports as the input and the output. Depending on which two ports of the directional coupler are mirrored, two configurations of the resonator can be achieved. The impacts of varying the cavity length and the coupling coefficient of the directional coupler on the output characteristics of the resonators are analyzed. A Q-factor of 28086 and an extinction ratio of 10.04 dB with an insertion loss of 1.9 dB is achieved experimentally for a 1038 μm cavity length and an extinction ratio of 18.14 dB and a Q-factor of 5120 with an insertion loss of 2.12 dB is obtained for a cavity length of 376 μm. The reported resonator offers additional freedom to tune the spectral characteristics.

MRS proof-of-concept on atmospheric corrections. Atmospheric corrections using an orbital pointable imaging system

NASA Technical Reports Server (NTRS)

Slater, P. N. (Principal Investigator)

1980-01-01

The feasibility of using a pointable imager to determine atmospheric parameters was studied. In particular the determination of the atmospheric extinction coefficient and the path radiance, the two quantities that have to be known in order to correct spectral signatures for atmospheric effects, was simulated. The study included the consideration of the geometry of ground irradiance and observation conditions for a pointable imager in a LANDSAT orbit as a function of time of year. A simulation study was conducted on the sensitivity of scene classification accuracy to changes in atmospheric condition. A two wavelength and a nonlinear regression method for determining the required atmospheric parameters were investigated. The results indicate the feasibility of using a pointable imaging system (1) for the determination of the atmospheric parameters required to improve classification accuracies in urban-rural transition zones and to apply in studies of bi-directional reflectance distribution function data and polarization effects; and (2) for the determination of the spectral reflectances of ground features.

Growth, spectral, linear and nonlinear optical characteristics of an efficient semiorganic acentric crystal: L-valinium L-valine chloride

NASA Astrophysics Data System (ADS)

Nageshwari, M.; Jayaprakash, P.; Kumari, C. Rathika Thaya; Vinitha, G.; Caroline, M. Lydia

2017-04-01

An efficient nonlinear optical semiorganic material L-valinium L-valine chloride (LVVCl) was synthesized and grown-up by means of slow evaporation process. Single crystal XRD evince that LVVCl corresponds to monoclinic system having acentric space group P21. The diverse functional groups existing in LVVCl were discovered with FTIR spectral investigation. The UV-Visible and photoluminescence spectrum discloses the optical and electronic properties respectively for the grown crystal. Several optical properties specifically extinction coefficient, reflectance, linear refractive index, electrical and optical conductivity were also determined. The SEM analysis was also carried out and it portrayed the surface morphology of LVVCl. The calculated value of laser damage threshold was 2.59 GW/cm2. The mechanical and dielectric property of LVVCl was investigated employing microhardness and dielectric studies. The second and third order nonlinear optical characteristics of LVVCl was characterized utilizing Kurtz Perry and Z scan technique respectively clearly suggest its suitability in the domain of optics and photonics.

Variation in crown light utilization characteristics among tropical canopy trees.

PubMed

Kitajima, Kaoru; Mulkey, Stephen S; Wright, S Joseph

2005-02-01

Light extinction through crowns of canopy trees determines light availability at lower levels within forests. The goal of this paper is the exploration of foliage distribution and light extinction in crowns of five canopy tree species in relation to their shoot architecture, leaf traits (mean leaf angle, life span, photosynthetic characteristics) and successional status (from pioneers to persistent). Light extinction was examined at three hierarchical levels of foliage organization, the whole crown, the outermost canopy and the individual shoots, in a tropical moist forest with direct canopy access with a tower crane. Photon flux density and cumulative leaf area index (LAI) were measured at intervals of 0.25-1 m along multiple vertical transects through three to five mature tree crowns of each species to estimate light extinction coefficients (K). Cecropia longipes, a pioneer species with the shortest leaf life span, had crown LAI <0.5. Among the remaining four species, crown LAI ranged from 2 to 8, and species with orthotropic terminal shoots exhibited lower light extinction coefficients (0.35) than those with plagiotropic shoots (0.53-0.80). Within each type, later successional species exhibited greater maximum LAI and total light extinction. A dense layer of leaves at the outermost crown of a late successional species resulted in an average light extinction of 61% within 0.5 m from the surface. In late successional species, leaf position within individual shoots does not predict the light availability at the individual leaf surface, which may explain their slow decline of photosynthetic capacity with leaf age and weak differentiation of sun and shade leaves. Later-successional tree crowns, especially those with orthotropic branches, exhibit lower light extinction coefficients, but greater total LAI and total light extinction, which contribute to their efficient use of light and competitive dominance.

Spectral signatures of polar stratospheric clouds and sulfate aerosol

NASA Technical Reports Server (NTRS)

Massie, S. T.; Bailey, P. L.; Gille, J. C.; Lee, E. C.; Mergenthaler, J. L.; Roche, A. E.; Kumer, J. B.; Fishbein, E. F.; Waters, J. W.; Lahoz, W. A.

1994-01-01

Multiwavelength observations of Antarctic and midlatitude aerosol by the Cryogenic Limb Array Etalon Spectrometer (CLAES) experiment on the Upper Atmosphere Research Satellite (UARS) are used to demonstrate a technique that identifies the location of polar stratospheric clouds. The technique discussed uses the normalized area of the triangle formed by the aerosol extinctions at 925, 1257, and 1605/cm (10.8, 8.0, and 6.2 micrometers) to derive a spectral aerosol measure M of the aerosol spectrum. Mie calculations for spherical particles and T-matrix calculations for spheriodal particles are used to generate theoretical spectral extinction curves for sulfate and polar stratospheric cloud particles. The values of the spectral aerosol measure M for the sulfate and polar stratospheric cloud particles are shown to be different. Aerosol extinction data, corresponding to temperatures between 180 and 220 K at a pressure of 46 hPa (near 21-km altitude) for 18 August 1992, are used to demonstrate the technique. Thermodynamic calculations, based upon frost-point calculations and laboratory phase-equilibrium studies of nitric acid trihydrate, are used to predict the location of nitric acid trihydrate cloud particles.

Broadband measurements of aerosol extinction in the ultraviolet spectral region

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Flores, J. M.; Brock, C. A.; Brown, S. S.; Rudich, Y.

2013-04-01

Aerosols influence the Earth's radiative budget by scattering and absorbing incoming solar radiation. The optical properties of aerosols vary as a function of wavelength, but few measurements have reported the wavelength dependence of aerosol extinction cross sections and complex refractive indices. We describe a new laboratory instrument to measure aerosol optical extinction as a function of wavelength, using cavity enhanced spectroscopy with a broadband light source. The instrument consists of two broadband channels which span the 360-390 and 385-420 nm spectral regions using two light emitting diodes (LED) and a grating spectrometer with charge-coupled device (CCD) detector. We determined aerosol extinction cross sections and directly observed Mie scattering resonances for aerosols that are purely scattering (polystyrene latex spheres and ammonium sulfate), slightly absorbing (Suwannee River fulvic acid), and strongly absorbing (nigrosin dye). We describe an approach for retrieving refractive indices as a function of wavelength from the measured extinction cross sections over the 360-420 nm wavelength region. The retrieved refractive indices for PSL and ammonium sulfate agree within uncertainty with the literature values for this spectral region. The refractive index determined for nigrosin is 1.78 (± 0.03) + 0.19 (± 0.08)i at 360 nm and 1.63 (± 0.03) + 0.21 (± 0.05)i at 420 nm. The refractive index determined for Suwannee River fulvic acid is 1.71 (± 0.02) + 0.07 (± 0.06)i at 360 nm and 1.66 (± 0.02) + 0.06 (± 0.04)i at 420 nm. These laboratory results support the potential for a field instrument capable of determining ambient aerosol optical extinction, average aerosol extinction cross section, and complex refractive index as a function of wavelength.

Broadband measurements of aerosol extinction in the ultraviolet spectral region

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Flores, J. M.; Brock, C. A.; Brown, S. S.; Rudich, Y.

2013-01-01

Aerosols influence the Earth's radiative budget by scattering and absorbing incoming solar radiation. The optical properties of aerosols vary as a function of wavelength, but few measurements have reported the wavelength dependence of aerosol extinction cross-sections and complex refractive indices. We describe a new laboratory instrument to measure aerosol optical extinction as a function of wavelength, using cavity enhanced spectroscopy with a broadband light source. The instrument consists of two broadband channels which span the 360-390 and 385-420 nm spectral regions using two light emitting diodes (LED) and a grating spectrometer with charge-coupled device (CCD) detector. We determined aerosol extinction cross-sections and directly observed Mie scattering resonances for aerosols that are purely scattering (polystyrene latex spheres and ammonium sulfate), slightly absorbing (Suwannee River fulvic acid), and strongly absorbing (nigrosin dye). We describe an approach for retrieving refractive indices as a function of wavelength from the measured extinction cross-sections over the 360-420 nm wavelength region. The retrieved refractive indices for PSL and ammonium sulfate agree within uncertainty with literature values for this spectral region. The refractive index determined for nigrosin is 1.78 (±0.03) + 0.19 (±0.08) i at 360 nm and 1.53 (±0.03) + 0.21 (±0.05) i at 420 nm. The refractive index determined for Suwannee River fulvic acid is 1.71 (±0.02) + 0.07 (±0.06) i at 360 nm and 1.66 (±0.02) + 0.06 (±0.04) i at 420 nm. These laboratory results support the potential for a field instrument capable of determining ambient aerosol optical extinction, average aerosol extinction cross-section, and complex refractive index as a function of wavelength.

Determination of extinction coefficients of human hemoglobin in various redox states

PubMed Central

Meng, Fantao; Alayash, Abdu I.

2017-01-01

The role of hemoglobin (Hb) redox forms in tissue and organ toxicities remain ambiguous despite the well-documented contribution of Hb redox reactivity to cellular and subcellular oxidative changes. Moreover, several recent studies, in which Hb toxicity were investigated, have shown conflicting outcomes. Uncertainties over the potential role of these species may in part be due to the protein preparation method of choice, the use of published extinction coefficients and the lack of suitable controls for Hb oxidation and heme loss. Highly purified and well characterized redox forms of human Hb were used in this study and the extinction coefficients of each Hb species (ferrous/oxy, ferric/met and ferryl) were determined. A new set of equations were established to improve accuracy in determining the transient ferryl Hb species. Additionally, heme concentrations in solutions and in human plasma were determined using a novel reversed phase HPLC method in conjugation with our photometric measurements. The use of more accurate redox-specific extinction coefficients and method calculations will be an invaluable tool for both in vitro and in vivo experiments aimed at determining the role of Hb-mediated vascular pathology in hemolytic anemias and when Hb is used as oxygen therapeutics. PMID:28069451

Sensitivity of high-spectral resolution and broadband thermal infrared nadir instruments to the chemical and microphysical properties of secondary sulfate aerosols in the upper-troposphere/lower-stratosphere

NASA Astrophysics Data System (ADS)

Sellitto, Pasquale; Legras, Bernard

2016-04-01

The observation of upper-tropospheric/lower-stratospheric (UTLS) secondary sulfate aerosols (SSA) and their chemical and microphysical properties from satellite nadir observations (with better spatial resolution than limb observations) is a fundamental tool to better understand their formation and evolution processes and then to estimate their impact on UTLS chemistry, and on regional and global radiative balance. Thermal infrared (TIR) observations are sensitive to the chemical composition of the aerosols due to the strong spectral variations of the imaginary part of the refractive index in this band and, correspondingly, of the absorption, as a function of the composition Then, these observations are, in principle, well adapted to detect and characterize UTLS SSA. Unfortunately, the exploitation of nadir TIR observations for sulfate aerosol layer monitoring is today very limited. Here we present a study aimed at the evaluation of the sensitivity of TIR satellite nadir observations to the chemical composition and the size distribution of idealised UTLS SSA layers. The sulfate aerosol particles are assumed as binary systems of sulfuric acid/water solution droplets, with varying sulphuric acid mixing ratios. The extinction properties of the SSA, for different sulfuric acid mixing ratios and temperatures, are systematically analysed. The extinction coefficients are derived by means of a Mie code, using refractive indices taken from the GEISA (Gestion et Étude des Informations Spectroscopiques Atmosphériques: Management and Study of Spectroscopic Information) spectroscopic database and log-normal size distributions with different effective radii and number concentrations. High-spectral resolution pseudo-observations are generated using forward radiative transfer calculations performed with the 4A (Automatized Atmospheric Absorption Atlas) radiative transfer model, to estimate the impact of the extinction of idealised aerosol layers, at typical UTLS conditions, on the brightness temperature (BT) spectra observed by satellite instruments. We isolated a marked and typical spectral signature of these aerosol layers between 700 and 1200 cm-1, due to the absorption bands of the sulfate and bisulfate ions and the undissociated sulfuric acid, with the main absorption peaks at 1170 and 905 cm-1 (sulfuric acid vibrational bands). The dependence of the residual aerosol spectral BT signature to the sulfuric acid mixing ratio, and effective number concentration and radius, as well as the role of interfering parameters like the ozone, sulfur dioxide, carbon dioxide and ash absorption, and temperature and water vapour profile uncertainties, are analysed and critically discussed. The information content (degrees of freedom and retrieval uncertainties) of synthetic satellite observations is estimated for different instrumental configurations. High spectral resolution (Infrared Atmospheric Sounding Interferometer (IASI)-like pseudo-observations) and broadband spectral features (Moderate Resolution Imaging Spectroradiometer (MODIS) and Spinning Enhanced Visible and InfraRed Imager (SEVIRI)-like pseudo-observations) approaches are proposed and discussed.

Chemical compositions and reconstructed light extinction coefficients of particulate matter in a mega-city in the western Yangtze River Delta, China

NASA Astrophysics Data System (ADS)

Shen, Guofeng; Xue, Miao; Yuan, Siyu; Zhang, Jie; Zhao, Qiuyue; Li, Bing; Wu, Haisuo; Ding, Aijun

2014-02-01

Ambient particulate matter was collected in a megacity, Nanjing in western YRD during the spring and summer periods. Chemical compositions of fine PM including organic carbon, elemental carbon, elements and water soluble ions were analyzed. The light extinction coefficients were reconstructed following the IMPROVE formula. Organic matter was the most abundant composition in PM2.5 (20-25% of total mass), followed by the inorganic ions. During the spring time, geological materials contributed 25% of the total PM2.5. Estimated light extinction coefficient ranged from 133 to 560 Mm-1 with the deciview haze index value of 26-40 dv, indicating strong light extinction by PM and subsequently low visibility in the city. Reconstructed ammonium sulfate, ammonium nitrate, organic matter and light absorption carbon in fine PM contributed significantly (37 ± 10, 16 ± 6, 15 ± 4 and 10 ± 3%, respectively) to the total light extinction of PM, while soil (5-7%) and sea salt fractions (2-4%) in fine PM and coarse PM (6-11%) had relatively minor influences. The results of backward air trajectory showed that the site was strongly influenced by the air from the eastern (39%) and southeastern (29%) areas during the sampling period. Air plumes from the Southeastern had both high PM mass pollution and large light extinction, while the air mass originating from the Northwestern resulted in high PM mass loading but relatively lower light extinction.

Performance of ultracompact copper-capped silicon hybrid plasmonic waveguide-ring resonators at telecom wavelengths.

PubMed

Zhu, Shiyang; Lo, G Q; Kwong, D L

2012-07-02

Ultracompact Cu-capped Si hybrid plasmonic waveguide-ring resonators (WRRs) with ring radii of 1.09-2.59 μm are fabricated on silicon on insulator substrates using standard complementary metal-oxide-semiconductor technology and characterized over the telecom wavelength range of 1.52-1.62 μm. The dependence of the spectral characteristics on the key structural parameters such as the Si core width, the ring radius, the separation gap between the ring and bus waveguides, and the ring configuration is systematically studied. A WRR with 2.59-μm radius and 0.250-μm nominal gap exhibits good performances such as normalized insertion loss of ~0.1 dB, extinction ratio of ~12.8 dB, free spectral range of ~47 nm, and quality factor of ~275. The resonance wavelength is redshifted by ~4.6 nm and an extinction ratio of ~7.5 dB is achieved with temperature increasing from 27 to 82°C. The corresponding effective thermo-optical coefficient (dn(g)/dT) is estimated to be ~1.6 × 10(-4) K(-1), which is contributed by the thermo-optical effect of both the Si core and the Cu cap, as revealed by numerical simulations. Combined with the compact size and the high thermal conductivity of Cu, various effective thermo-optical devices based on these Cu-capped plasmonic WRRs could be realized for seamless integration in existing Si electronic-photonic integrated circuits.

Field Studies of Broadband Aerosol Optical Extinction in the Ultraviolet Spectral Region

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Attwood, A.; Brock, C. A.; Brown, S. S.

2013-12-01

Aerosols influence the Earth's radiative budget by scattering and absorbing incoming solar radiation. The optical properties of aerosols vary as a function of wavelength, but few measurements have reported the wavelength dependence of aerosol extinction cross sections and complex refractive indices. In the case of brown carbon, its wavelength-dependent absorption in the ultraviolet spectral region has been suggested as an important component of aerosol radiative forcing. We describe a new field instrument to measure aerosol optical extinction as a function of wavelength, using cavity enhanced spectroscopy with a broadband light source. The instrument consists of two broadband channels which span the 360-390 and 385-420 nm spectral regions using two light emitting diodes (LED) and a grating spectrometer with charge-coupled device (CCD) detector. We deployed this instrument during the Fire Lab at Missoula Experiment during Fall 2012 to measure biomass burning aerosol, and again during the Southern Oxidant and Aerosol Study in summer 2013 to measure organic aerosol in the Southeastern U.S. In both field experiments, we determined aerosol optical extinction as a function of wavelength and can interpret this together with size distribution and composition measurements to characterize the aerosol optical properties and radiative forcing.

Analysis of structural and optical properties of annealed fullerene thin films

NASA Astrophysics Data System (ADS)

El-Nahass, M. M.; Ali, H. A. M.; Gadallah, A.-S.; Atta Khedr, M.; Afify, H. A.

2015-08-01

Fullerene thin films were thermally deposited onto different substrates. The films annealed at 523 K for 10 h. X-ray diffraction technique was used to examine the structure of the films. The morphology of films was examined by field emission scanning electron microscopy. Fourier transform infrared spectra were recorded in wavenumber range 400-2000 cm-1. The optical characteristics were analyzed using UV- Vis-NIR spectrophotometric measurements in the spectral range 200-2500 nm. The refractive index and extinction coefficient were determined. Some dispersion parameters were calculated such as single oscillator energy, dispersion energy, dielectric constant at high frequency and lattice dielectric constant. As well as, the nonlinear optical susceptibility χ(3) and nonlinear refractive index n2 were determined.

Metal/dielectric/metal sandwich film for broadband reflection reduction

PubMed Central

Jen, Yi-Jun; Lakhtakia, Akhlesh; Lin, Meng-Jie; Wang, Wei-Hao; Wu, Huang-Ming; Liao, Hung-Sheng

2013-01-01

A film comprising randomly distributed metal/dielectric/metal sandwich nanopillars with a distribution of cross-sectional diameters, displayed extremely low reflectance over the blue-to-red regime, when coated on glass and illuminated normally. When it is illuminated by normally incident light, this sandwich film (SWF) has a low extinction coefficient, its phase thickness is close to a negative wavelength in the blue-to-red spectral regime, and it provides weakly dispersive forward and backward impedances, so that reflected waves from the two faces of the SWF interfere destructively. Broadband reflection-reduction, over a wide range of incidence angles and regardless of the polarization state of the incident light, was observed when the SWF was deposited on polished silicon. PMID:23591704

Investigation of optical properties of ternary Zn-Ti-O thin films prepared by magnetron reactive co-sputtering

NASA Astrophysics Data System (ADS)

Netrvalová, Marie; Novák, Petr; Šutta, Pavol; Medlín, Rostislav

2017-11-01

Zn-Ti-O thin films with different concentrations of titanium were deposited by reactive magnetron co-sputtering in a reactive Ar/O2 atmosphere from zinc and titanium targets. It was found that with increasing Ti content the structure of the films gradually changes from a fully crystalline pure ZnO wurtzite structure with a strongly preferred columnar orientation to an amorphous Zn-Ti-O material with 12.5 at.% Ti. The optical parameters (spectral refractive index and extinction coefficient, optical band gap) and thickness of the films were analysed by the combined evaluation of ellipsometric measurements and measurements of transmittance on a UV-vis spectrophotometer. For evaluation of optical parameters was used Cody-Lorentz dispersion model.

Synthesis, spectral and thermal studies of the newly hydrogen bonded charge transfer complex of o-phenylenediamine with π acceptor picric acid

NASA Astrophysics Data System (ADS)

Khan, Ishaat M.; Ahmad, Afaq

2010-10-01

Newly proton or charge transfer complex [(OPDH) +(PA) -] was synthesized by the reaction of the donor, o-phenylenediamine (OPD) with acceptor, 2,4,6-trinitrophenol (PAH). The chemical reaction has occurred via strong hydrogen bonding followed by migration of proton from acceptor to donor. UV-vis, 1H NMR and FTIR spectra, in addition to the thermal and elemental analysis were used to confirm the proposed occurrence of the chemical reaction and to investigate the newly synthesized solid CT complex. The stoichiometry of the CT complex was found to be 1:1. The formation constant and molar extinction coefficient of the CT complex were evaluated by the Benesi-Hildebrand equation.

Lidar extinction measurement in the mid infrared

NASA Astrophysics Data System (ADS)

Mitev, Valentin; Babichenko, S.; Borelli, R.; Fiorani, L.; Grigorov, I.; Nuvoli, M.; Palucci, A.; Pistilli, M.; Puiu, Ad.; Rebane, Ott; Santoro, S.

2014-11-01

We present a lidar measurement of atmospheric extinction coefficient. The measurement is performed by inversion of the backscatter lidar signal at wavelengths 3'000nm and 3'500nm. The inversion of the backscatter lidar signal was performed with constant extinction-to-backscatter ration values of 104 and exponential factor 0.1.

Interstitial diffuse radiance spectroscopy of gold nanocages and nanorods in bulk muscle tissues

PubMed Central

Grabtchak, Serge; Montgomery, Logan G; Pang, Bo; Wang, Yi; Zhang, Chao; Li, Zhiyuan; Xia, Younan; Whelan, William M

2015-01-01

Radiance spectroscopy was applied to the interstitial detection of localized inclusions containing Au nanocages or nanorods with various concentrations embedded in porcine muscle phantoms. The radiance was quantified using a perturbation approach, which enabled the separation of contributions from the porcine phantom and the localized inclusion, with the inclusion serving as a perturbation probe of photon distributions in the turbid medium. Positioning the inclusion at various places in the phantom allowed for tracking of photons that originated from a light source, passed through the inclusion’s location, and reached a detector. The inclusions with high extinction coefficients were able to absorb nearly all photons in the range of 650–900 nm, leading to a spectrally flat radiance signal. This signal could be converted to the relative density of photons incident on the inclusion. Finally, the experimentally measured quantities were expressed via the relative perturbation and arranged into the classical Beer–Lambert law that allowed one to extract the extinction coefficients of various types of Au nanoparticles in both the transmission and back reflection geometries. It was shown that the spatial variation of perturbation could be described as 1/r dependence, where r is the distance between the inclusion and the detector. Due to a larger absorption cross section, Au nanocages produced greater perturbations than Au nanorods of equal particle concentration, indicating a better suitability of Au nanocages as contrast agents for optical measurements in turbid media. Individual measurements from different inclusions were combined into detectability maps. PMID:25709450

Interstitial diffuse radiance spectroscopy of gold nanocages and nanorods in bulk muscle tissues.

PubMed

Grabtchak, Serge; Montgomery, Logan G; Pang, Bo; Wang, Yi; Zhang, Chao; Li, Zhiyuan; Xia, Younan; Whelan, William M

2015-01-01

Radiance spectroscopy was applied to the interstitial detection of localized inclusions containing Au nanocages or nanorods with various concentrations embedded in porcine muscle phantoms. The radiance was quantified using a perturbation approach, which enabled the separation of contributions from the porcine phantom and the localized inclusion, with the inclusion serving as a perturbation probe of photon distributions in the turbid medium. Positioning the inclusion at various places in the phantom allowed for tracking of photons that originated from a light source, passed through the inclusion's location, and reached a detector. The inclusions with high extinction coefficients were able to absorb nearly all photons in the range of 650-900 nm, leading to a spectrally flat radiance signal. This signal could be converted to the relative density of photons incident on the inclusion. Finally, the experimentally measured quantities were expressed via the relative perturbation and arranged into the classical Beer-Lambert law that allowed one to extract the extinction coefficients of various types of Au nanoparticles in both the transmission and back reflection geometries. It was shown that the spatial variation of perturbation could be described as 1/r dependence, where r is the distance between the inclusion and the detector. Due to a larger absorption cross section, Au nanocages produced greater perturbations than Au nanorods of equal particle concentration, indicating a better suitability of Au nanocages as contrast agents for optical measurements in turbid media. Individual measurements from different inclusions were combined into detectability maps.

VizieR Online Data Catalog: Coefficients for passband extinctions (Sale+, 2015)

NASA Astrophysics Data System (ADS)

Sale, S. E.; Magorrian, J.

2017-11-01

We have considered how one should measure the distance and extinction to individual stars for use in constructing extinction maps of the whole Galaxy. We advocate the use of monochromatic extinctions, since, unlike bandpass measures such as AV and E(B-V), monochromatic extinctions are linear functions of the dust column density and are independent of the source SED. In particular we suggest the use of A4000, the monochromatic extinction at 4000Å because of its insensitivity to the dust grain size distribution. Files for converting from A_4000 to passband extinctions at 35 RV extinction law value and for 11 photometric systems. (2 data files).

High-extinction virtually imaged phased array-based Brillouin spectroscopy of turbid biological media

NASA Astrophysics Data System (ADS)

Fiore, Antonio; Zhang, Jitao; Shao, Peng; Yun, Seok Hyun; Scarcelli, Giuliano

2016-05-01

Brillouin microscopy has recently emerged as a powerful technique to characterize the mechanical properties of biological tissue, cell, and biomaterials. However, the potential of Brillouin microscopy is currently limited to transparent samples, because Brillouin spectrometers do not have sufficient spectral extinction to reject the predominant non-Brillouin scattered light of turbid media. To overcome this issue, we combined a multi-pass Fabry-Perot interferometer with a two-stage virtually imaged phased array spectrometer. The Fabry-Perot etalon acts as an ultra-narrow band-pass filter for Brillouin light with high spectral extinction and low loss. We report background-free Brillouin spectra from Intralipid solutions and up to 100 μm deep within chicken muscle tissue.

Spectral interferometric microscopy reveals absorption by individual optical nanoantennas from extinction phase

PubMed Central

Gennaro, Sylvain D.; Sonnefraud, Yannick; Verellen, Niels; Van Dorpe, Pol; Moshchalkov, Victor V.; Maier, Stefan A.; Oulton, Rupert F.

2014-01-01

Optical antennas transform light from freely propagating waves into highly localized excitations that interact strongly with matter. Unlike their radio frequency counterparts, optical antennas are nanoscopic and high frequency, making amplitude and phase measurements challenging and leaving some information hidden. Here we report a novel spectral interferometric microscopy technique to expose the amplitude and phase response of individual optical antennas across an octave of the visible to near-infrared spectrum. Although it is a far-field technique, we show that knowledge of the extinction phase allows quantitative estimation of nanoantenna absorption, which is a near-field quantity. To verify our method we characterize gold ring-disk dimers exhibiting Fano interference. Our results reveal that Fano interference only cancels a bright mode’s scattering, leaving residual extinction dominated by absorption. Spectral interference microscopy has the potential for real-time and single-shot phase and amplitude investigations of isolated quantum and classical antennas with applications across the physical and life sciences. PMID:24781663

Thin cirrus clouds - Seasonal distribution over oceans deduced from Nimbus-4 IRIS

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Fraser, R. S.; Dalu, G.; Wu, Man-Li C.; Curran, R. J.

1988-01-01

Spectral differences in the extinction of the 10.8- and 12.6-micron bands of the IR window region, due to optically thin clouds, were found in the measurements made by both an airborne broadband IR radiometer and the IR interferometer spectrometer (IRIS) aboard the Nimbus-4 satellite; the extinction at 12.6 microns was significantly larger than that at 10.8 microns; both water and ice particles in the clouds can account for such spectral difference in extinction. Multiple scattering radiative transfer calculations of IRIS data revealed this spectral feature about 100 to 20 km away from the high-altitude cold clouds; it is assumed that this feature is related to the spreading of cirrus clouds. Based on this assumption, mean seasonal maps of the distribution of thin cirrus clouds over the oceans were deduced from the IRIS data. The maps show that such clouds are often present over the convectively active areas, such as ITCZ, SPCZ, and the Bay of Bengal during the summer monsoon.

Atmospheric Extinction Coefficients in the Ic Band for Several Major International Observatories: Results from the BiSON Telescopes, 1984-2016

NASA Astrophysics Data System (ADS)

Hale, S. J.; Chaplin, W. J.; Davies, G. R.; Elsworth, Y. P.; Howe, R.; Lund, M. N.; Moxon, E. Z.; Thomas, A.; Pallé, P. L.; Rhodes, E. J., Jr.

2017-09-01

Over 30 years of solar data have been acquired by the Birmingham Solar Oscillations Network (BiSON), an international network of telescopes used to study oscillations of the Sun. Five of the six BiSON telescopes are located at major observatories. The observational sites are, in order of increasing longitude: Mount Wilson (Hale) Observatory (MWO), California, USA; Las Campanas Observatory, Chile; Observatorio del Teide, Izaña, Tenerife, Canary Islands; the South African Astronomical Observatory, Sutherland, South Africa; Carnarvon, Western Australia; and the Paul Wild Observatory, Narrabri, New South Wales, Australia. The BiSON data may be used to measure atmospheric extinction coefficients in the {{{I}}}{{c}} band (approximately 700-900 nm), and presented here are the derived atmospheric extinction coefficients from each site over the years 1984-2016.

In vivo Photoacoustic Imaging of Prostate Cancer Using Targeted Contrast Agent

DTIC Science & Technology

2016-11-01

has over 15 years of experience investigating signaling in the prostate, and is well versed in both cell culture and animal models for prostate cancer...as Hb generate relatively weak photoacoustic signals (due to a small absorptivity factor or extinction coefficient) and lack cancer specificity...oxyhemoglobin (dHb) and oxyhemoglobin (HbO2) have two limitations: i) their small absorptivity factor ( extinction coefficient) leads to weak PA signals

Use of a Spreadsheet to Help Students Understand the Origin of the Empirical Equation that Allows Estimation of the Extinction Coefficients of Proteins

ERIC Educational Resources Information Center

Sims, Paul A.

2012-01-01

A brief history of the development of the empirical equation that is used by prominent, Internet-based programs to estimate (or calculate) the extinction coefficients of proteins is presented. In addition, an overview of a series of related assignments designed to help students understand the origin of the empirical equation is provided. The…

Ultrafast laser processing of copper: A comparative study of experimental and simulated transient optical properties

NASA Astrophysics Data System (ADS)

Winter, Jan; Rapp, Stephan; Schmidt, Michael; Huber, Heinz P.

2017-09-01

In this paper, we present ultrafast measurements of the complex refractive index for copper up to a time delay of 20 ps with an accuracy <1% at laser fluences in the vicinity of the ablation threshold. The measured refractive index n and extinction coefficient k are supported by a simulation including the two-temperature model with an accurate description of thermal and optical properties and a thermomechanical model. Comparison of the measured time resolved optical properties with results of the simulation reveals underlying physical mechanisms in three distinct time delay regimes. It is found that in the early stage (-5 ps to 0 ps) the thermally excited d-band electrons make a major contribution to the laser pulse absorption and create a steep increase in transient optical properties n and k. In the second time regime (0-10 ps) the material expansion influences the plasma frequency, which is also reflected in the transient extinction coefficient. In contrast, the refractive index n follows the total collision frequency. Additionally, the electron-ion thermalization time can be attributed to a minimum of the extinction coefficient at ∼10 ps. In the third time regime (10-20 ps) the transient extinction coefficient k indicates the surface cooling-down process.

Determination of the molar extinction coefficient for the ferric reducing/antioxidant power assay.

PubMed

Hayes, William A; Mills, Daniel S; Neville, Rachel F; Kiddie, Jenna; Collins, Lisa M

2011-09-15

The FRAP reagent contains 2,4,6-tris(2-pyridyl)-s-triazine, which forms a blue-violet complex ion in the presence of ferrous ions. Although the FRAP (ferric reducing/antioxidant power) assay is popular and has been in use for many years, the correct molar extinction coefficient of this complex ion under FRAP assay conditions has never been published, casting doubt on the validity of previous calibrations. A previously reported value of 19,800 is an underestimate. We determined that the molar extinction coefficient was 21,140. The value of the molar extinction coefficient was also shown to depend on the type of assay and was found to be 22,230 under iron assay conditions, in good agreement with published data. Redox titration indicated that the ferrous sulfate heptahydrate calibrator recommended by Benzie and Strain, the FRAP assay inventors, is prone to efflorescence and, therefore, is unreliable. Ferrous ammonium sulfate hexahydrate in dilute sulfuric acid was a more stable alternative. Few authors publish their calibration data, and this makes comparative analyses impossible. A critical examination of the limited number of examples of calibration data in the published literature reveals only that Benzie and Strain obtained a satisfactory calibration using their method. Copyright © 2011 Elsevier Inc. All rights reserved.

Nanofluid optical property characterization: towards efficient direct absorption solar collectors.

PubMed

Taylor, Robert A; Phelan, Patrick E; Otanicar, Todd P; Adrian, Ronald; Prasher, Ravi

2011-03-15

Suspensions of nanoparticles (i.e., particles with diameters < 100 nm) in liquids, termed nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm). A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm) with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power) increase.

Nanofluid optical property characterization: towards efficient direct absorption solar collectors

PubMed Central

2011-01-01

Suspensions of nanoparticles (i.e., particles with diameters < 100 nm) in liquids, termed nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm). A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm) with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power) increase. PMID:21711750

Dust models compatible with Planck intensity and polarization data in translucent lines of sight

NASA Astrophysics Data System (ADS)

Guillet, V.; Fanciullo, L.; Verstraete, L.; Boulanger, F.; Jones, A. P.; Miville-Deschênes, M.-A.; Ysard, N.; Levrier, F.; Alves, M.

2018-02-01

Context. Current dust models are challenged by the dust properties inferred from the analysis of Planck observations in total and polarized emission. Aims: We propose new dust models compatible with polarized and unpolarized data in extinction and emission for translucent lines of sight (0.5 < AV < 2.5). Methods: We amended the DustEM tool to model polarized extinction and emission. We fit the spectral dependence of the mean extinction, polarized extinction, total and polarized spectral energy distributions (SEDs) with polycyclic aromatic hydrocarbons, astrosilicate and amorphous carbon (a-C) grains. The astrosilicate population is aligned along the magnetic field lines, while the a-C population may be aligned or not. Results: With their current optical properties, oblate astrosilicate grains are not emissive enough to reproduce the emission to extinction polarization ratio P353/pV derived with Planck data. Successful models are those using prolate astrosilicate grains with an elongation a/b = 3 and an inclusion of 20% porosity. The spectral dependence of the polarized SED is steeper in our models than in the data. Models perform slightly better when a-C grains are aligned. A small (6%) volume inclusion of a-C in the astrosilicate matrix removes the need for porosity and perfect grain alignment, and improves the fit to the polarized SED. Conclusions: Dust models based on astrosilicates can be reconciled with data by adapting the shape of grains and adding inclusions of porosity or a-C in the astrosilicate matrix.

Studies of absorption coefficient cum electro-optic performance of polymer dispersed liquid crystal doped with CNT and dichroic dye

NASA Astrophysics Data System (ADS)

Sharma, Vandna; Kumar, Pankaj

2017-11-01

Absorption coefficient of doped polymer dispersed liquid crystals (PDLCs) is a critical factor for their device performance and depends on dopants parameters like solubility, order parameter and extinction coefficients, in addition to configuration and orientation of the droplets. In this study, a fixed amount (0.125% wt/wt) of multiwall carbon nanotubes (CNTs) and orange azo dichroic dye was doped in PDLC and measured the OFF state absorption coefficient. Considering the theory based on Beer's law and followed by extinction coefficients of CNT and dye, the OFF state transmission for dye doped PDLC was found lower compared to CNT doped PDLC. As a result, absorption coefficient for dye doped PDLC was higher and resulted in the superior contrast ratio. The experimental results were found be consistent with the theoretical results.

Star clusters: age, metallicity and extinction from integrated spectra

NASA Astrophysics Data System (ADS)

González Delgado, Rosa M.; Cid Fernandes, Roberto

2010-01-01

Integrated optical spectra of star clusters in the Magellanic Clouds and a few Galactic globular clusters are fitted using high-resolution spectral models for single stellar populations. The goal is to estimate the age, metallicity and extinction of the clusters, and evaluate the degeneracies among these parameters. Several sets of evolutionary models that were computed with recent high-spectral-resolution stellar libraries (MILES, GRANADA, STELIB), are used as inputs to the starlight code to perform the fits. The comparison of the results derived from this method and previous estimates available in the literature allow us to evaluate the pros and cons of each set of models to determine star cluster properties. In addition, we quantify the uncertainties associated with the age, metallicity and extinction determinations resulting from variance in the ingredients for the analysis.

FIBER OPTICS: Polarization phase nonreciprocity in all-fiber ring interferometers

NASA Astrophysics Data System (ADS)

Andreev, A. Ts; Vasilev, V. D.; Kozlov, V. A.; Kuznetsov, A. V.; Senatorov, A. A.; Shubochkin, R. L.

1993-08-01

The polarization phase nonreciprocity in all-fiber ring interferometers based on single-mode optical fibers was studied experimentally. The results confirm existing theoretical models. Experimentally, it was possible to use fiber ring interferometers to measure the extinction coefficients of optical fiber polarizers. The largest extinction coefficients found for optical-fiber polarizers were 84 dB (for the wavelength 0.82 μm) and 86 dB (1.3 μm).

Respirable particulate monitoring with remote sensors. (Public health ecology: Air pollution)

NASA Technical Reports Server (NTRS)

Severs, R. K.

1974-01-01

The feasibility of monitoring atmospheric aerosols in the respirable range from air or space platforms was studied. Secondary reflectance targets were located in the industrial area and near Galveston Bay. Multichannel remote sensor data were utilized to calculate the aerosol extinction coefficient and thus determine the aerosol size distribution. Houston Texas air sampling network high volume data were utilized to generate computer isopleth maps of suspended particulates and to establish the mass loading of the atmosphere. In addition, a five channel nephelometer and a multistage particulate air sampler were used to collect data. The extinction coefficient determined from remote sensor data proved more representative of wide areal phenomena than that calculated from on site measurements. It was also demonstrated that a significant reduction in the standard deviation of the extinction coefficient could be achieved by reducing the bandwidths used in remote sensor.

Shipboard Visibility Measurement System Definition Study.

DTIC Science & Technology

1982-01-01

Aerosol Extinction (AAE) Coef- ficients Derived from NRL Long - Path Transmission Measurements at CCAFS...determined. Occasionally long - path extinction measurements for many laser lines were collected (as many as 80 CO2 laser lines on some days and repeated...EXPERIMENT DAY FIGURE 22. PLOT OF APPARENT AEROSOL EXTINCTION (AAE) COEFFICIENTS DERIVED FROM NRL LONG - PATH TRANSMISSION MEASUREMENTS AT CCAFS MINUS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shcheglova, L S; Maryakhina, V S; Abramova, L L

The differences in optical and biophysical properties between the cells of mammary gland tumour extracted from tumours of different diameter are described. It is shown that the spectral and spectrokinetic properties of fluorescent probes in the cells extracted from the tumours 1 – 3 cm in diameter are essentially different. Thus, the extinction coefficient of rhodamine 6G gradually increases with the pathology development. At the same time the rate of interaction of the triplet states of molecular probes with the oxygen, diluted in the tumour cells cytoplasm, decreases with the growth of the tumour capsule diameter. The observed regularities canmore » be due to the changes in the cell structure, biochemical and biophysical properties. The reported data may be useful for developing optical methods of diagnostics of biotissue pathological conditions. (optical methods in biology and medicine)« less

Synthesis, spectral and thermal studies of the newly hydrogen bonded charge transfer complex of o-phenylenediamine with pi acceptor picric acid.

PubMed

Khan, Ishaat M; Ahmad, Afaq

2010-10-01

Newly proton or charge transfer complex [(OPDH)(+)(PA)(-)] was synthesized by the reaction of the donor, o-phenylenediamine (OPD) with acceptor, 2,4,6-trinitrophenol (PAH). The chemical reaction has occurred via strong hydrogen bonding followed by migration of proton from acceptor to donor. UV-vis, (1)H NMR and FTIR spectra, in addition to the thermal and elemental analysis were used to confirm the proposed occurrence of the chemical reaction and to investigate the newly synthesized solid CT complex. The stoichiometry of the CT complex was found to be 1:1. The formation constant and molar extinction coefficient of the CT complex were evaluated by the Benesi-Hildebrand equation. Copyright 2010 Elsevier B.V. All rights reserved.

Current Research in Lidar Technology Used for the Remote Sensing of Atmospheric Aerosols

PubMed Central

Comerón, Adolfo; Muñoz-Porcar, Constantino; Rocadenbosch, Francesc; Rodríguez-Gómez, Alejandro; Sicard, Michaël

2017-01-01

Lidars are active optical remote sensing instruments with unique capabilities for atmospheric sounding. A manifold of atmospheric variables can be profiled using different types of lidar: concentration of species, wind speed, temperature, etc. Among them, measurement of the properties of aerosol particles, whose influence in many atmospheric processes is important but is still poorly stated, stands as one of the main fields of application of current lidar systems. This paper presents a review on fundamentals, technology, methodologies and state-of-the art of the lidar systems used to obtain aerosol information. Retrieval of structural (aerosol layers profiling), optical (backscatter and extinction coefficients) and microphysical (size, shape and type) properties requires however different levels of instrumental complexity; this general outlook is structured following a classification that attends these criteria. Thus, elastic systems (detection only of emitted frequencies), Raman systems (detection also of Raman frequency-shifted spectral lines), high spectral resolution lidars, systems with depolarization measurement capabilities and multi-wavelength instruments are described, and the fundamentals in which the retrieval of aerosol parameters is based is in each case detailed. PMID:28632170

Intergalactic Extinction of High Energy Gamma-Rays

NASA Technical Reports Server (NTRS)

Stecker, F. W.

1998-01-01

We discuss the determination of the intergalactic pair-production absorption coefficient as derived by Stecker and De Jager by making use of a new empirically based calculation of the spectral energy distribution of the intergalactic infrared radiation field as given by Malkan and Stecker. We show that the results of the Malkan and Stecker calculation agree well with recent data on the infrared background. We then show that Whipple observations of the flaring gamma-ray spectrum of Mrk 421 hint at extragalactic absorption and that the HEGRA observations of the flaring spectrum of Mrk 501 appear to strongly indicate extragalactic absorption. We also discuss the determination of the y-ray opacity at higher redshifts, following the treatment of Salamon and Stecker. We give a predicted spectrum, with absorption included for PKS 2155-304. This XBL lies at a redshift of 0.12, the highest redshift source yet observed at an energy above 0.3 TeV. This source should have its spectrum steepened by approx. 1 in its spectral index between approx. 0.3 and approx. 3 TeV and should show an absorption cutoff above approx. 6 TeV.

A New Analysis of the Spectra Obtained by the Venera Missions in the Venusian Atmosphere. I. The Analysis of the Data Received from the Venera-11 Probe at Altitudes Below 37 km in the 0.44 0.66 µm Wavelength Range

NASA Astrophysics Data System (ADS)

Maiorov, B. S.; Ignat'ev, N. I.; Moroz, V. I.; Zasova, L. V.; Moshkin, B. E.; Khatuntsev, I. V.; Ekonomov, A. P.

2005-07-01

The processes of the solar radiation extinction in deep layers of the Venus atmosphere in a wavelength range from 0.44 to 0.66 µm have been considered. The spectra of the solar radiation scattered in the atmosphere of Venus at various altitudes above the planetary surface measured by the Venera-11 entry probe in December 1978 are used as observational data. The problem of the data analysis is solved by selecting an atmospheric model; the discrete-ordinate method is applied in calculations. For the altitude interval from 2 10 km to 36 km, the altitude and spectral dependencies of the volume coefficient of true absorption have been obtained. At altitudes of 3 19 km, the spectral dependence is close to the wavelength dependence of the absorption cross section of S3 molecules, whence it follows that the mixing ratio of this sulfur allotrope increases with altitude from 0.03 to 0.1 ppbv.

[Research on the measurement of flue-dust concentration in Vis, IR spectral region].

PubMed

Sun, Xiao-gang; Tang, Hong; Yuan, Gui-bin

2008-10-01

In the measurement of flue-dust concentration based on the transmission method, the dependent model algorithm was used to invert the flue-dust concentration in the visible, infrared and visible-infrared spectral regions respectively. By the analysis and comparison of the accuracy, linearity and sensitivity of the inversion flue-dust concentration, the optimal spectral region was determined. Meanwhile, the influence of the water droplet with different size distribution and volume concentration was simulated, and a method was proposed which has advantages of simplicity, rapidity, and suitability for on line measurement. Simulation experiments illustrate that the flue-dust concentration can be inverted very well in the visible-infrared spectral region, and it is feasible to use the ratio of the constrained light extinction method to overcome the influence of water droplet. The inverse results all remain satisfactory when 2% stochastic noise is added to the value of the light extinction.

Precise determination of protein extinction coefficients under native and denaturing conditions using SV-AUC.

PubMed

Hoffmann, Andreas; Grassl, Kerstin; Gommert, Janine; Schlesak, Christian; Bepperling, Alexander

2018-04-17

The accurate determination of protein concentration is an important though non-trivial task during the development of a biopharmaceutical. The fundamental prerequisite for this is the availability of an accurate extinction coefficient. Common approaches for the determination of an extinction coefficient for a given protein are either based on the theoretical prediction utilizing the amino acid sequence or the photometric determination combined with a measurement of absolute protein concentration. Here, we report on an improved SV-AUC based method utilizing an analytical ultracentrifuge equipped with absorbance and Rayleigh interference optics. Global fitting of datasets helped to overcome some of the obstacles encountered with the traditional method employing synthetic boundary cells. Careful calculation of dn/dc values taking glycosylation and solvent composition into account allowed the determination of the extinction coefficients of monoclonal antibodies and an Fc-fusion protein under native as well as under denaturing conditions. An intra-assay precision of 0.9% and an accuracy of 1.8% compared to the theoretical value was achieved for monoclonal antibodies. Due to the large number of data points of a single dataset, no meaningful difference between the ProteomeLab XL-I and the new Optima AUC platform could be observed. Thus, the AUC-based approach offers a precise, convenient and versatile alternative to conventional methods like total amino acid analysis (AAA).

Interstellar extinction in the ultraviolet

NASA Technical Reports Server (NTRS)

Bless, R. C.; Savage, B. D.

1972-01-01

Interstellar extinction curves over the region 3600-1100 A for 17 stars are presented. The observations were made by the two Wisconsin spectrometers onboard the OAO-2 with spectral resolutions of 10 A and 20 A. The extinction curves generally show a pronounced maximum at 2175 plus or minus 25 A, a broad minimum in the region 1800-1350 A, and finally a rapid rise to the far ultraviolet. Large extinction variations from star to star are found, especially in the far ultraviolet; however, with only two possible exceptions in this sample, the wavelength at the maximum of the extinction bump is essentially constant. These data are combined with visual and infrared observations to display the extinction behavior over a range in wavelength of about a factor of 20.

Measurement of fog and haze extinction characteristics and availability evaluation of free space optical link under the sea surface environment.

PubMed

Wu, Xiaojun; Wang, Hongxing; Song, Bo

2015-02-10

Fog and haze can lead to changes in extinction characteristics. Therefore, the performance of the free space optical link is highly influenced by severe weather conditions. Considering the influential behavior of weather conditions, a state-of-the-art solution for the observation of fog and haze over the sea surface is presented in this paper. A Mie scattering laser radar, with a wavelength of 532 nm, is used to observe the weather conditions of the sea surface environment. The horizontal extinction coefficients and visibilities are obtained from the observation data, and the results are presented in the paper. The changes in the characteristics of extinction coefficients and visibilities are analyzed based on both the short-term (6 days) severe weather data and long-term (6 months) data. Finally, the availability performance of the free space optical communication link is evaluated under the sea surface environment.

Optical constants of SrF 2 thin films in the 25-780-eV spectral range

DOE PAGES

Rodriguez-de Marcos, Luis; Larraguert, Juan I.; Aznarez, Jose A.; ...

2013-04-08

The transmittance and the optical constants of SrF 2 thin films, a candidate material for multilayer coatings operating in the extreme ultraviolet and soft x-rays, have been determined in the spectral range of 25–780 eV, in most of which no experimental data were previously available. SrF 2 films of various thicknesses were deposited by evaporation onto room-temperature, thin Al support films, and their transmittance was measured with synchrotron radiation. The transmittance as a function of film thickness was used to calculate the extinction coefficient k at each photon energy. A decrease in density with increasing SrF 2 film thickness wasmore » observed. In the calculation of k, this effect was circumvented by fitting the transmittance versus the product of thickness and density. The real part of the refractive index of SrF 2 films was calculated from k with Kramers-Krönig analysis, for which the measured spectral range was extended both to lower and to higher photon energies with data in the literature combined with interpolations and extrapolations. In conclusion, with the application of f- and inertial sum rules, the consistency of the compiled data was found to be excellent.« less

Fugitive Dust Emission Factors for Puff and Mobile Military Sources Measured by Micro-pulse Lidar - A Summary of Results

NASA Astrophysics Data System (ADS)

Yuen, W.; Du, K.; Rood, M. J.; Kemme, M. R.; Kim, B.; Hashmonay, R. A.

2010-12-01

A summary of the development of a novel optical remote sensing (ORS) method that determined fugitive dust emission factors for unique military activities is described for puff and mobile sources. Four field campaigns characterized artillery back blasts as puff sources (M549A1 and M107), and movement of military vehicles (M1A1, M113, Bradley Fighting Vehicle (BFV), M88, M270, M577, and HEMTT) and an airborne helicopter (Bell 210) as mobile sources. The ORS method includes a Micro-Pulse Lidar (MPL) and a reflective target that determines one-dimensional (1-D) light extinction coefficient profiles. The MPL was mounted on a positioner that allows the MPL to automatically scan vertically, which allowed 1-D extinction coefficient profiles to be measured at select angles from horizontal. Two-dimensional (2-D) light extinction coefficient profiles were then determined by interpolating the 1-D extinction profiles measured at select angles. Dust property, in the form of the mass extinction efficiency (MEE), was measured using Open Path- Fourier Transform Infrared Spectrometry (OP-FTIR) and Open Path- Laser Transmissometry (OP-LT) in the first three field campaigns and an OP-LT and DustTrak™ in the fourth field campaign. MEE was used to convert the 2-D light extinction coefficient profiles to 2-D dust mass concentration profiles. Emission factors were determined by integrating the 2-D mass concentration profiles with measured wind vectors. Results from these field campaigns show that: 1) artillery with stronger recoiling forces generates more fugitive dust; 2) the dust emission factors for tracked vehicles are correlated with vehicle momentum; 3) emission factor decreases with increasing speed for airborne helicopters; and 4) wheeled vehicles (HEMTT) generate more fugitive dust than tracked vehicles (M88, M270, M577).

A Comparison of Aerosol Optical Property Measurements Made During the DOE Aerosol Intensive Operating Period and Their Effects on Regional Climate

NASA Technical Reports Server (NTRS)

Strawa, Anthony W.; Hallar, A. G.; Arnott, W. P.; Covert, D.; Elleman, R.; Ogren, J.; Schmid, B.; Luu, A.

2004-01-01

The amount of radiant energy an aerosol absorbs has profound effects on climate and air quality. It is ironic that aerosol absorption coefficient is one of the most difficult to measure aerosol properties. One of the main purposes of the DOE Aerosol Intensive Operating Period (IOP) flown in May, 2003 was to assess our ability to measure absorption coefficient in situ. This paper compares measurements of aerosol optical properties made during the IOP. Measurements of aerosol absorption coefficient were made by Particle Soot Absorption Photometer (PSAP) aboard the CIRPAS Twin-Otter (U. Washington) and on the DOE Cessna 172 (NOAA-C,MDL). Aerosol absorption coefficient was also measured by a photoacoustic instrument (DRI) that was operated on an aircraft for the first time during the IOP. A new cavity ring-down (CRD) instrument, called Cadenza (NASA-AkC), measures the aerosol extinction coefficient for 675 nm and 1550 nm light, and simultaneously measures the scattering coefficient at 675 nm. Absorption coefficient is obtained from the difference of measured extinction and scattering within the instrument. Measurements of absorption coefficient from all of these instruments during appropriate periods are compared. During the IOP, several significant aerosol layers were sampled aloft. These layers are identified in the remote (AATS-14) as well as in situ measurements. Extinction profiles measured by Cadenza are compared to those derived from the Ames Airborne Tracking Sunphotometer (AATS-14, NASA-ARC). The regional radiative impact of these layers is assessed by using the measured aerosol optical properties in a radiative transfer model.

Effective resolution concepts for lidar observations

NASA Astrophysics Data System (ADS)

Iarlori, M.; Madonna, F.; Rizi, V.; Trickl, T.; Amodeo, A.

2015-12-01

Since its establishment in 2000, EARLINET (European Aerosol Research Lidar NETwork) has provided, through its database, quantitative aerosol properties, such as aerosol backscatter and aerosol extinction coefficients, the latter only for stations able to retrieve it independently (from Raman or high-spectral-resolution lidars). These coefficients are stored in terms of vertical profiles, and the EARLINET database also includes the details of the range resolution of the vertical profiles. In fact, the algorithms used in the lidar data analysis often alter the spectral content of the data, mainly acting as low-pass filters to reduce the high-frequency noise. Data filtering is described by the digital signal processing (DSP) theory as a convolution sum: each filtered signal output at a given range is the result of a linear combination of several signal input data samples (relative to different ranges from the lidar receiver), and this could be seen as a loss of range resolution of the output signal. Low-pass filtering always introduces distortions in the lidar profile shape. Thus, both the removal of high frequency, i.e., the removal of details up to a certain spatial extension, and the spatial distortion produce a reduction of the range resolution. This paper discusses the determination of the effective resolution (ERes) of the vertical profiles of aerosol properties retrieved from lidar data. Large attention has been dedicated to providing an assessment of the impact of low-pass filtering on the effective range resolution in the retrieval procedure.

Optical band gap studies on lithium aluminum silicate glasses doped with Cr3+ ions

NASA Astrophysics Data System (ADS)

El-Diasty, Fouad; Abdel Wahab, Fathy A.; Abdel-Baki, Manal

2006-11-01

Lithium aluminum silicate glass system (LAS) implanted with chromium ions is prepared. The reflectance and transmittance measurements are used to determine the dispersion of absorption coefficient. The optical data are explained in terms of the different oxidation states adopted by the chromium ions into the glass network. It is found that the oxidation state of the chromium depends on its concentration. Across a wide spectral range, 0.2-1.6μm, analysis of the fundamental absorption edge provides values for the average energy band gaps for allowed direct and indirect transitions. The optical absorption coefficient just below the absorption edge varies exponentially with photon energy indicating the presence of Urbach's tail. Such tail is decreased with the increase of the chromium dopant. From the analysis of the optical absorption data, the absorption peak at ground state exciton energy, the absorption at band gap, and the free exciton binding energy are determined. The extinction coefficient data are used to determine the Fermi energy level of the studied glasses. The metallization criterion is obtained and discussed exploring the nature of the glasses. The measured IR spectra of the different glasses are used to throw some light on the optical properties of the present glasses correlating them with their structure and composition.

Aerosol profiling with lidar in the Amazon Basin during the wet and dry season

NASA Astrophysics Data System (ADS)

Baars, H.; Ansmann, A.; Althausen, D.; Engelmann, R.; Heese, B.; Müller, D.; Artaxo, P.; Paixao, M.; Pauliquevis, T.; Souza, R.

2012-11-01

For the first time, multiwavelength polarization Raman lidar observations of optical and microphysical particle properties over the Amazon Basin are presented. The fully automated advanced Raman lidar was deployed 60 km north of Manaus, Brazil (2.5°S, 60°W) in the Amazon rain forest from January to November 2008. The measurements thus cover both the wet season (Dec-June) and the dry or burning season (July-Nov). Two cases studies of young and aged smoke plumes are discussed in terms of spectrally resolved optical properties (355, 532, and 1064 nm) and further lidar products such as particle effective radius and single-scattering albedo. These measurement examples confirm that biomass burning aerosols show a broad spectrum of optical, microphysical, and chemical properties. The statistical analysis of the entire measurement period revealed strong differences between the pristine wet and the polluted dry season. African smoke and dust advection frequently interrupt the pristine phases during the wet season. Compared to pristine wet season conditions, the particle scattering coefficients in the lowermost 2 km of the atmosphere were found to be enhanced, on average, by a factor of 4 during periods of African aerosol intrusion and by a factor of 6 during the dry (burning) season. Under pristine conditions, the particle extinction coefficients and optical depth for 532 nm wavelength were frequently as low as 10-30 Mm-1 and <0.05, respectively. During the dry season, biomass burning smoke plumes reached to 3-5 km height and caused a mean optical depth at 532 nm of 0.26. On average during that season, particle extinction coefficients (532 nm) were of the order of 100 Mm-1 in the main pollution layer (up to 2 km height). Ångström exponents were mainly between 1.0 and 1.5, and the majority of the observed lidar ratios were between 50-80 sr.

Periodic Impact Cratering and Extinction Events Over the Last 260 Million Years

NASA Technical Reports Server (NTRS)

Rampino, Michael R.; Caldeira, Ken

2015-01-01

The claims of periodicity in impact cratering and biological extinction events are controversial. Anewly revised record of dated impact craters has been analyzed for periodicity, and compared with the record of extinctions over the past 260 Myr. A digital circular spectral analysis of 37 crater ages (ranging in age from 15 to 254 Myr ago) yielded evidence for a significant 25.8 +/- 0.6 Myr cycle. Using the same method, we found a significant 27.0 +/- 0.7 Myr cycle in the dates of the eight recognized marine extinction events over the same period. The cycles detected in impacts and extinctions have a similar phase. The impact crater dataset shows 11 apparent peaks in the last 260 Myr, at least 5 of which correlate closely with significant extinction peaks. These results suggest that the hypothesis of periodic impacts and extinction events is still viable.

Optimization and photomodification of extremely broadband optical response of plasmonic core-shell obscurants.

PubMed

de Silva, Vashista C; Nyga, Piotr; Drachev, Vladimir P

2016-12-15

Plasmonic resonances of the metallic shells depend on their nanostructure and geometry of the core, which can be optimized for the broadband extinction normalized by mass. The fractal nanostructures can provide a broadband extinction. It allows as well for a laser photoburning of holes in the extinction spectra and consequently windows of transparency in a controlled manner. The studied core-shell microparticles synthesized using colloidal chemistry consist of gold fractal nanostructures grown on precipitated calcium carbonate (PCC) microparticles or silica (SiO 2 ) microspheres. The optimization includes different core sizes and shapes, and shell nanostructures. It shows that the rich surface of the PCC flakes is the best core for the fractal shells providing the highest mass normalized extinction over the extremely broad spectral range. The mass normalized extinction cross section up to 3m 2 /g has been demonstrated in the broad spectral range from the visible to mid-infrared. Essentially, the broadband response is a characteristic feature of each core-shell microparticle in contrast to a combination of several structures resonant at different wavelengths, for example nanorods with different aspect ratios. The photomodification at an IR wavelength makes the window of transparency at the longer wavelength side. Copyright © 2016 Elsevier Inc. All rights reserved.

Spectral Aerosol Extinction (SpEx): A New Instrument for In situ Ambient Aerosol Extinction Measurements Across the UV/Visible Wavelength Range

NASA Technical Reports Server (NTRS)

Jordan, C. E.; Anderson, B. E.; Beyersdorf, A. J.; Corr, C. A.; Dibb, J. E.; Greenslade, M. E.; Martin, R. F.; Moore, R. H.; Scheuer, E.; Shook, M. A.;

Optical properties of size-resolved particles at a Hong Kong urban site during winter

NASA Astrophysics Data System (ADS)

Gao, Yuan; Lai, Senchao; Lee, Shun-Cheng; Yau, Pui Shan; Huang, Yu; Cheng, Yan; Wang, Tao; Xu, Zheng; Yuan, Chao; Zhang, Yingyi

2015-03-01

Visibility degradation in Hong Kong is related to the city's serious air pollution problems. To investigate the aerosols' optical properties and their relationship with the chemical composition and size distribution of the particles, a monitoring campaign was conducted at an urban site in the early winter period (from October to December, 2010). The particle light scattering coefficient (Bsp) and absorption coefficient (Bap) were measured. Two collocated Micro-Orifice Uniform Deposit Impactor samplers (MOUDI110, MSP, USA) with nominal 50% cut-off aerodynamic diameters of 18, 10, 5.6, 3.2, 1.8, 1, 0.56, 0.32, 0.18, 0.1, and 0.056 μm were used to collect size-resolved particle samples. The average Bsp and Bap were 201.96 ± 105.82 Mm- 1 and 39.91 ± 19.16 Mm- 1, with an average single scattering albedo (ωo) of 0.82 ± 0.07. The theoretical method of light extinction calculation was used to determine the extinction of the size-resolved particulate matters (PM). The reconstructed light scattering coefficient correlated well with the measured scattering value in the Hong Kong urban area. Droplet mode (0.56-1.8 μm) particles contributed most to the particle light extinction (~ 69%). Organic matter, ammonium sulphate and elemental carbon were the key components causing visibility degradation in the droplet (0.56-1.8 μm) and condensation (0.1-0.56 μm) size ranges. Five sources contributing to particle light extinction have been identified using positive matrix factorisation (PMF). Traffic/engine exhausts and secondary aerosols accounted for ~ 36% and ~ 32% of particle light extinction, respectively, followed by sea salt (15%). The remaining sources, soil/fugitive dust and tire dust, contributed by ~ 10% and 7%, respectively, to particle light extinction.

High-latitude dust clouds LDN 183 and LDN 169: distances and extinctions

NASA Astrophysics Data System (ADS)

Straižys, V.; Boyle, R. P.; Zdanavičius, J.; Janusz, R.; Corbally, C. J.; Munari, U.; Andersson, B.-G.; Zdanavičius, K.; Kazlauskas, A.; Maskoliūnas, M.; Černis, K.; Macijauskas, M.

2018-03-01

Interstellar extinction is investigated in a 2°× 2° area containing the dust and molecular clouds LDN 183 (MBM 37) and LDN 169, which are located at RA = 15h 54m, Dec = - 3°. The study is based on a photometric classification in spectral and luminosity classes of 782 stars selected from the catalogs of 1299 stars down to V = 20 mag observed in the Vilnius seven-color system. For control, the MK types for the 18 brightest stars with V between 8.5 and 12.8 mag were determined spectroscopically. For 14 stars, located closer than 200 pc, distances were calculated from trigonometric parallaxes taken from the Gaia Data Release 1. For about 70% of the observed stars, two-dimensional spectral types, interstellar extinctions AV, and distances were determined. Using 57 stars closer than 200 pc, we estimate that the front edge of the clouds begins at 105 ± 8 pc. The extinction layer in the vicinities of the clouds can be about 20 pc thick. In the outer parts of the clouds and between the clouds, the extinction is 0.5-2.0 mag. Behind the Serpens/Libra clouds, the extinction range does not increase; this means that the dust layer at 105 pc is a single extinction source. Full Tables 1 and 2 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/611/A9

Imaging of Biological Cells Using Luminescent Silver Nanoparticles

NASA Astrophysics Data System (ADS)

Kravets, Vira; Almemar, Zamavang; Jiang, Ke; Culhane, Kyle; Machado, Rosa; Hagen, Guy; Kotko, Andriy; Dmytruk, Igor; Spendier, Kathrin; Pinchuk, Anatoliy

2016-01-01

The application of luminescent silver nanoparticles as imaging agents for neural stem and rat basophilic leukemia cells was demonstrated. The experimental size dependence of the extinction and emission spectra for silver nanoparticles were also studied. The nanoparticles were functionalized with fluorescent glycine dimers. Spectral position of the resonance extinction and photoluminescence emission for particles with average diameters ranging from 9 to 32 nm were examined. As the particle size increased, the spectral peaks for both extinction and the intrinsic emission of silver nanoparticles shifted to the red end of the spectrum. The intrinsic photoluminescence of the particles was orders of magnitude weaker and was spectrally separated from the photoluminescence of the glycine dimer ligands. The spectral position of the ligand emission was independent of the particle size; however, the quantum yield of the nanoparticle-ligand system was size-dependent. This was attributed to the enhancement of the ligand's emission caused by the local electric field strength's dependence on the particle size. The maximum quantum yield determined for the nanoparticle-ligand complex was (5.2 ± 0.1) %. The nanoparticles were able to penetrate cell membranes of rat basophilic leukemia and neural stem cells fixed with paraformaldehyde. Additionally, toxicity studies were performed. It was found that towards rat basophilic leukemia cells, luminescent silver nanoparticles had a toxic effect in the silver atom concentration range of 10-100 μM.

Airborne Cavity Ring-Down Measurement of Aerosol Extinction and Scattering During the Aerosol IOP

NASA Technical Reports Server (NTRS)

Strawa, A. W.; Ricci, K.; Provencal, R.; Schmid, B.; Covert, D.; Elleman, R.; Arnott, P.

2003-01-01

Large uncertainties in the effects of aerosols on climate require improved in-situ measurements of extinction coefficient and single-scattering albedo. This paper describes preliminary results from Cadenza, a new continuous wave cavity ring-down (CW-CRD) instrument designed to address these uncertainties. Cadenza measures the aerosol extinction coefficient for 675 nm and 1550 nm light, and simultaneously measures the scattering coefficient at 675 nm. In the past year Cadenza was deployed in the Asian Dust Above Monterey (ADAM) and DOE Aerosol Intensive Operating Period (IOP) field projects. During these flights Cadenza produced measurements of aerosol extinction in the range from 0.2 to 300 Mm-1 with an estimated precision of 0.1 Min-1 for 1550 nm light and 0.2 Mm-1 for 675 nm light. Cadenza data from the ADAM and Aerosol IOP missions compared favorably with data from the other instruments aboard the CIRPAS Twin Otter aircraft and participating in those projects.= We present comparisons between the Cadenza measurements and those friom a TSI nephelometer, Particle Soot Absorption Photometer (PSAP), and the AATS 14 sun-photometer. Measurements of the optical properties of smoke and dust plumes sampled during these campaigns are presented and estimates of heating rates due to these plumes are made.

In Situ Measurement of Aerosol Extinction

NASA Technical Reports Server (NTRS)

Strawa, Anthony W.; Castaneda, R.; Owano, T. G.; Bear, D.; Gore, Warren J. (Technical Monitor)

2001-01-01

Aerosols are important contributors to the radiative forcing in the atmosphere. Much of the uncertainty in our knowledge of climate forcing is due to uncertainties in the radiative forcing due to aerosols as illustrated in the IPCC reports of the last ten years. Improved measurement of aerosol optical properties, therefore, is critical to an improved understanding of atmospheric radiative forcing. Additionally, attempts to reconcile in situ and remote measurements of aerosol radiative properties have generally not been successful. This is due in part to the fact that it has been impossible to measure aerosol extinction in situ in the past. In this presentation we introduce a new instrument that employs the techniques used in cavity ringdown spectroscopy to measure the aerosol extinction and scattering coefficients in situ. A prototype instrument has been designed and tested in the lab and the field. It is capable of measuring aerosol extinction coefficient to 2x10(exp -6) per meter. This prototype instrument is described and results are presented.

DO PERIODICITIES IN EXTINCTION-WITH POSSIBLE ASTRONOMICAL CONNECTIONS-SURVIVE A REVISION OF THE GEOLOGICAL TIMESCALE?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Melott, Adrian L.; Bambach, Richard K.

A major revision of the geological timescale was published in 2012. We re-examine our past finding of a 27 Myr periodicity in marine extinction rates by re-assigning dates to the extinction data used previously. We find that the spectral power in this period is somewhat increased, and persists at a narrow bandwidth, which supports our previous contention that the Nemesis hypothesis is untenable as an explanation for the periodicity that was first noted by Raup and Sepkoski in the 1980s. We enumerate a number of problems in a recent study comparing extinction rates with time series models.

Assessing the measurement of aerosol single scattering albedo by Cavity Attenuated Phase-Shift Single Scattering Monitor (CAPS PMssa)

NASA Astrophysics Data System (ADS)

Perim de Faria, Julia; Bundke, Ulrich; Onasch, Timothy B.; Freedman, Andrew; Petzold, Andreas

2016-04-01

The necessity to quantify the direct impact of aerosol particles on climate forcing is already well known; assessing this impact requires continuous and systematic measurements of the aerosol optical properties. Two of the main parameters that need to be accurately measured are the aerosol optical depth and single scattering albedo (SSA, defined as the ratio of particulate scattering to extinction). The measurement of single scattering albedo commonly involves the measurement of two optical parameters, the scattering and the absorption coefficients. Although there are well established technologies to measure both of these parameters, the use of two separate instruments with different principles and uncertainties represents potential sources of significant errors and biases. Based on the recently developed cavity attenuated phase shift particle extinction monitor (CAPS PM_{ex) instrument, the CAPS PM_{ssa instrument combines the CAPS technology to measure particle extinction with an integrating sphere capable of simultaneously measuring the scattering coefficient of the same sample. The scattering channel is calibrated to the extinction channel, such that the accuracy of the single scattering albedo measurement is only a function of the accuracy of the extinction measurement and the nephelometer truncation losses. This gives the instrument an accurate and direct measurement of the single scattering albedo. In this study, we assess the measurements of both the extinction and scattering channels of the CAPS PM_{ssa through intercomparisons with Mie theory, as a fundamental comparison, and with proven technologies, such as integrating nephelometers and filter-based absorption monitors. For comparison, we use two nephelometers, a TSI 3563 and an Aurora 4000, and two measurements of the absorption coefficient, using a Particulate Soot Absorption Photometer (PSAP) and a Multi Angle Absorption Photometer (MAAP). We also assess the indirect absorption coefficient measurement from the CAPS PM_{ssa (calculated as the difference from the measured extinction and scattering). The study was carried out in the laboratory with controlled particle generation systems. We used both light absorbing aerosols (Regal 400R pigment black from Cabot Corp. and colloidal graphite - Aquadag - from Agar Scientific) and purely scattering aerosols (ammonium sulphate and polystyrene latex spheres), covering single scattering albedo values from approximately 0.4 to 1.0. A new truncation angle correction for the CAPS PM_{ssa integrated sphere is proposed.

Series cell light extinction monitor

DOEpatents

Novick, Vincent J.

1990-01-01

A method and apparatus for using the light extinction measurements from two or more light cells positioned along a gasflow chamber in which the gas volumetric rate is known to determine particle number concentration and mass concentration of an aerosol independent of extinction coefficient and to determine estimates for particle size and mass concentrations. The invention is independent of particle size. This invention has application to measurements made during a severe nuclear reactor fuel damage test.

Results of Laser-Calibrated High-Resolution Transmission Measurements and Comparisons with Broadband Transmissometer Data: San Nicolas Island, California, May 1979.

DTIC Science & Technology

1982-09-30

system . Atmospheric aerosol extinction coefficients at DF laser wavelengths obtained from the long - path transmission data show a wide range of variation...described in this report, it is recommended that addi- tional long - path field measurements of laser extinction and high-resolution transmission spectra be...independent long path laser extinction measurement . Column 7 of Table 3 lists the lime of the laser

Multispectral Light Curves of Vesta

NASA Astrophysics Data System (ADS)

Jaumann, R.; Nathues, A.; Mottola, S.; Hoffmann, H.

1996-01-01

In order to characterize its compositional heterogeneity we have carried out time-resolved CCD spectrophotometry of 4 Vesta during its last apparition in 1996. The observations have been performed from the European Southern Observatory (La Silla, Chile), with the DLR CCD camera attached at the Bochum 24" telescope using a set of five interference filters covering the spectral range 0.45-0.95 pm. In order to obtain the high photometric accuracy necessary to reveal subtle color variations, we have performed on-chip differential photometry against a field star, which allows effective correction for short-term atmospheric extinction fluctuations. The observations were therefore carefully planned and scheduled for one night when 4 Vesta was passing close to a bright star (SAO 140637). Measurements in each filter were automatically cycled over about 5 hr, in order to fully cover an asteroid's rotational period. Only the small portion of the CCD actually containing 4 Vesta and the comparison star was read out, which allowed us to have a very fast duty cycle of about 90 s. A GO-type star (BS 5779) located less than 2 degrees from the Vesta field was acquired during its passage at meridian, in order to provide reflectance calibration. The resulting dataset of approximately 1000 frames was preprocessed using bias frames and twilight sky flat fields, while photometry was computed by using ASTPHOT, a synthetic aperture program developed at DLR. Extinction correction was derived directly by dividing the flux of the asteroid by the on-field comparison star, while higher-order, differential extinction coefficients were neglected due to the comparatively narrow bandwidth of the filters used.

Testing spectral models for stellar populations with star clusters - II. Results

NASA Astrophysics Data System (ADS)

González Delgado, Rosa M.; Cid Fernandes, Roberto

2010-04-01

High spectral resolution evolutionary synthesis models have become a routinely used ingredient in extragalactic work, and as such deserve thorough testing. Star clusters are ideal laboratories for such tests. This paper applies the spectral fitting methodology outlined in Paper I to a sample of clusters, mainly from the Magellanic Clouds and spanning a wide range in age and metallicity, fitting their integrated light spectra with a suite of modern evolutionary synthesis models for single stellar populations. The combinations of model plus spectral library employed in this investigation are Galaxev/STELIB, Vazdekis/MILES, SED@/GRANADA and Galaxev/MILES+GRANADA, which provide a representative sample of models currently available for spectral fitting work. A series of empirical tests are performed with these models, comparing the quality of the spectral fits and the values of age, metallicity and extinction obtained with each of them. A comparison is also made between the properties derived from these spectral fits and literature data on these nearby, well studied clusters. These comparisons are done with the general goal of providing useful feedback for model makers, as well as guidance to the users of such models. We find the following. (i) All models are able to derive ages that are in good agreement both with each other and with literature data, although ages derived from spectral fits are on average slightly older than those based on the S-colour-magnitude diagram (S-CMD) method as calibrated by Girardi et al. (ii) There is less agreement between the models for the metallicity and extinction. In particular, Galaxev/STELIB models underestimate the metallicity by ~0.6 dex, and the extinction is overestimated by 0.1 mag. (iii) New generations of models using the GRANADA and MILES libraries are superior to STELIB-based models both in terms of spectral fit quality and regarding the accuracy with which age and metallicity are retrieved. Accuracies of about 0.1 dex in age and 0.3 dex in metallicity can be achieved as long as the models are not extrapolated beyond their expected range of validity.

Global direct radiative forcing by process-parameterized aerosol optical properties

NASA Astrophysics Data System (ADS)

KirkevâG, Alf; Iversen, Trond

2002-10-01

A parameterization of aerosol optical parameters is developed and implemented in an extended version of the community climate model version 3.2 (CCM3) of the U.S. National Center for Atmospheric Research. Direct radiative forcing (DRF) by monthly averaged calculated concentrations of non-sea-salt sulfate and black carbon (BC) is estimated. Inputs are production-specific BC and sulfate from [2002] and background aerosol size distribution and composition. The scheme interpolates between tabulated values to obtain the aerosol single scattering albedo, asymmetry factor, extinction coefficient, and specific extinction coefficient. The tables are constructed by full calculations of optical properties for an array of aerosol input values, for which size-distributed aerosol properties are estimated from theory for condensation and Brownian coagulation, assumed distribution of cloud-droplet residuals from aqueous phase oxidation, and prescribed properties of the background aerosols. Humidity swelling is estimated from the Köhler equation, and Mie calculations finally yield spectrally resolved aerosol optical parameters for 13 solar bands. The scheme is shown to give excellent agreement with nonparameterized DRF calculations for a wide range of situations. Using IPCC emission scenarios for the years 2000 and 2100, calculations with an atmospheric global cliamte model (AFCM) yield a global net anthropogenic DRF of -0.11 and 0.11 W m-2, respectively, when 90% of BC from biomass burning is assumed anthropogenic. In the 2000 scenario, the individual DRF due to sulfate and BC has separately been estimated to -0.29 and 0.19 W m-2, respectively. Our estimates of DRF by BC per BC mass burden are lower than earlier published estimates. Some sensitivity tests are included to investigate to what extent uncertain assumptions may influence these results.

Photometry of occultation candidate stars. I - Uranus 1985 and Saturn 1985-1991

NASA Technical Reports Server (NTRS)

French, L. M.; Morales, G.; Dalton, A. S.; Klavetter, J. J.; Conner, S. R.

1985-01-01

Photometric observations of five stars to be occulted by the rings around Uranus are presented. The four stars to be occulted by Saturn or its rings during the period 1985-1991 were also observed. The observations were carried out with a CCD detector attached to the Kitt Peak McGraw-Hill 1.30-m telescope. Landolt standards of widely ranging V-I color indices were used to determine the extinction coefficients, transformation coefficients, and zero points of the stars. Mean extinction coefficients are given for each night of observation. K magnitudes for each star were estimated on the basis of the results of Johnson (1967). The complete photometric data set is given in a series of tables.

Interaction between photons and leaf canopies

NASA Technical Reports Server (NTRS)

Knyazikhin, Yuri V.; Marshak, Alexander L.; Myneni, Ranga B.

1991-01-01

The physics of neutral particle interaction for photons traveling in media consisting of finite-dimensional scattering centers that cross-shade mutually is investigated. A leaf canopy is a typical example of such media. The leaf canopy is idealized as a binary medium consisting of randomly distributed gaps (voids) and regions with phytoelements (turbid phytomedium). In this approach, the leaf canopy is represented by a combination of all possible open oriented spheres. The mathematical approach for characterizing the structure of the host medium is considered. The extinction coefficient at any phase-space location in a leaf canopy is the product of the extinction coefficient in the turbid phytomedium and the probability of absence gaps at that location. Using a similar approach, an expression for the differential scattering coefficient is derived.

Gold and CuS as multifunctional theranostics platform for imaging and therapy (Conference Presentation)

NASA Astrophysics Data System (ADS)

Zhu, Junjie

2017-02-01

Localized surface plasmon resonances arising from the free carriers in copper-deficient copper chalcogenides nanocrystals (Cu2-xE, E=S,Se) enables them with high extinction coefficient in the near-infrared range, which was superior for photothermal related purpose. Although Cu2-xE nanocrystals with different compositions (0< x≪1) all possess NIR absorption, their extinction coefficients were significantly different due to their distinct valence band free carrier concentration. Herein, by optimizing the synthetic conditions, we were able to obtain pure covellite phase CuS nanoparticles with maximized free carrier concentration (x=1), which provides extremely high mass extinction coefficient (up to 60 Lg-1cm-1 at 980 nm and 32.4 Lg-1cm-1 at 800 nm). To the best of our knowledge, these values was maximal among all inorganic nanomaterials. High quality Cu2-xSe can also be obtained with a similar approach. In order to introduce CuS nanocrystals for biomedical applications, we further transferred these nanocrystals into aqueous solution with an amphiphilic polymer and colvalently linked with beta-cyclodextrin. Using host-guest interaction, adamantine-modified RGD peptide can be further anchored on the nanoparticles for the recognition of integrin-positive cancer cells. Together with the high extinction coefficient and outstand photothermal conversion efficiency (determined to be higher than 40%), these CuS nanocrystals were applied for photothermal therapy of cancer cells and photoacoustic imaging. In addition, anticancer drug doxorubicin can also be loading onto the nanoparticles through either hydrophobic or electrostatic interaction for chemotherapy.

Ultraviolet photometry from the Orbiting Astronomical Observatory. II Interstellar extinction.

NASA Technical Reports Server (NTRS)

Bless, R. C.; Savage, B. D.

1972-01-01

Evaluation of interstellar extinction curves over the region from 3600 to 1100 A for 17 stars. The observations were made by the two Wisconsin spectrometers on board the Orbiting Astronomical Observatory 2, with spectral resolutions of 10 and 20 A. The extinction curves generally show a pronounced maximum at 2175 plus or minus 25 A, a broad minimum in the region from 1800 to 1350 A, and finally a rapid rise to the far-ultraviolet. Large extinction variations from star to star are found, especially in the far-ultraviolet; however, with only two possible exceptions in this sample, the wavelength at the maximum of the extinction bump is essentially constant. These data are combined with visual and infrared observations to display the extinction behavior over a range in wavelength of about a factor of 20. The observations appear to require a multicomponent model of the interstellar dust.

Prediction of apparent extinction for optical transmission through rain

NASA Astrophysics Data System (ADS)

Vasseur, H.; Gibbins, C. J.

1996-12-01

At optical wavelengths, geometrical optics holds that the extinction efficiency of raindrops is equal to two. This approximation yields a wavelength-independent extinction coefficient that, however, can hardly be used to predict accurately rain extinction measured in optical transmissions. Actually, in addition to the extinct direct incoming light, a significant part of the power scattered by the rain particles reaches the receiver. This leads to a reduced apparent extinction that depends on both rain characteristics and link parameters. A simple method is proposed to evaluate this apparent extinction. It accounts for the additional scattered power that enters the receiver when one considers the forward-scattering pattern of the raindrops as well as the multiple-scattering effects using, respectively, the Fraunhofer diffraction and Twersky theory. It results in a direct analytical formula that enables a quick and accurate estimation of the rain apparent extinction and highlights the influence of the link parameters. Predictions of apparent extinction through rain are found in excellent agreement with measurements in the visible and IR regions.

Aerosol Optical Properties at the Ground Sites during the 2010 CARES Field Campaign

NASA Astrophysics Data System (ADS)

Atkinson, D. B.; Radney, J. G.; Harworth, J. W.

2010-12-01

Preliminary results from the ground sites at the 2010 CARES field campaign (T0 near Sacramento, CA and T1 near Cool, CA) will be presented. A number of aerosol optical properties were measured at high time resolution for the four week study period using custom instruments. The aerosol extinction coefficient was measured at T0 using a cavity ring-down transmissometer (CRDT) at two wavelengths (532 and 1064 nm) and the aerosol scattering coefficient was measured at 532 nm using a Radiance Research M903 nephelometer. At T1, a new CRDT instrument was deployed that measured the extinction coefficient at three wavelengths (355, 532, and 1064 nm) for sub-10 μm (nominal) and sub-2.5 μm aerosols at ambient, elevated, and reduced relative humidity. A new type of custom nephelometer that measures the aerosol scattering coefficient at 532 nm using an array detector was also deployed at T1.

Bacterial Luciferase: Determination of the Structure by X-Ray Diffraction

DTIC Science & Technology

1994-05-20

absorbance at 280 nm, using an extinction coefficient mation of the active enzyme should show a concentration- of 0.94 (mg/ml-s *cm-’ (Gunsalus- Miguel et a...absorbance at 280 rm, using an extinction coefficient into the presumed assembly-incompetent form (Ziegler et aL, of 0.94 (mg/ml)- 1.cm-’ (Gunualus- Miguel et...Gunsalus- Miguel et aL (1972): E for a - 1.23 (mg/ml)-’.cm-’ and for 0 = 0.72 (mg/ml)’. cm . Refoldi’i of Luciferase and of Individual Subunits from 5 M

The functional correlation between rainfall rate and extinction coefficient for frequencies from 3 to 10 GHz

NASA Technical Reports Server (NTRS)

Jameson, A. R.

1990-01-01

The relationship between the rainfall rate (R) obtained from radiometric brightness temperatures and the extinction coefficient (k sub e) is investigated by computing the values of k sub e over a wide range of rainfall rates, for frequencies from 3 to 25 GHz. The results show that the strength of the relation between the R and the k sub e values exhibits considerable variation for frequencies at this range. Practical suggestions are made concerning the selection of particular frequencies for rain measurements to minimize the error in R determinations.

Design and fabrication of far ultraviolet filters based on π-multilayer technology in high-k materials

PubMed Central

Wang, Xiao-Dong; Chen, Bo; Wang, Hai-Feng; He, Fei; Zheng, Xin; He, Ling-Ping; Chen, Bin; Liu, Shi-Jie; Cui, Zhong-Xu; Yang, Xiao-Hu; Li, Yun-Peng

2015-01-01

Application of π-multilayer technology is extended to high extinction coefficient materials, which is introduced into metal-dielectric filter design. Metal materials often have high extinction coefficients in far ultraviolet (FUV) region, so optical thickness of metal materials should be smaller than that of the dielectric material. A broadband FUV filter of 9-layer non-periodic Al/MgF2 multilayer was successfully designed and fabricated and it shows high reflectance in 140–180 nm, suppressed reflectance in 120–137 nm and 181–220 nm. PMID:25687255

Optical characteristics of composites obtained by ion implantation of silver ions in polyethylene terephthalate

NASA Astrophysics Data System (ADS)

Bumai, Yu. A.; Volobuev, V. S.; Valeev, V. F.; Dolgikh, N. I.; Lukashevich, M. G.; Khaibullin, R. I.; Nuzhdin, V. I.; Odzhaev, V. B.

2012-11-01

Metal-polymer composites are obtained by implantation of 30 keV silver ions at doses D = 1•1016-1.5•1017 cm-2 and ion current densities j = 4.0 μA/cm2 in films of polyethylene terephthalate. The spectral dependences of the reflection, transmission, and extinction coefficients for wavelengths of 190-1100 nm are studied. The reflection bands at λ1 = 205 nm and λ2 = 260 nm are found to be enhanced for light incident on the unimplanted side. Surface plasmon resonances on the silver nanoparticles are investigated. The refractive index of the modified layer is calculated and the sizes of the silver nanoparticles are estimated using a two-layer model of this structure together with the optical measurements. Depending on the implantation dose, these are found to vary over 1.3-2.8 and 5-20 nm, respectively.

Selective enhancement of carbohydrate ion abundances by diamond nanoparticles for mass spectrometric analysis.

PubMed

Wu, Chieh-Lin; Wang, Chia-Chen; Lai, Yin-Hung; Lee, Hsun; Lin, Jia-Der; Lee, Yuan Tseh; Wang, Yi-Sheng

2013-04-16

Diamond nanoparticles (DNPs) were incorporated into matrix-assisted laser desorption/ionization (MALDI) samples to enhance the sensitivity of the mass spectrometer to carbohydrates. The DNPs optimize the MALDI sample morphology and thermalize the samples for thermally labile compounds because they have a high thermal conductivity, a low extinction coefficient in UV-vis spectral range, and stable chemical properties. The best enhancement effect was achieved when matrix, DNP, and carbohydrate solutions were deposited and vacuum-dried consecutively to form a trilayer sample morphology. It allows the direct identification of underivatized carbohydrates mixed with equal amount of proteins because no increase in the ion abundance of proteins was achieved. For dextran with an average molecular weight of 1500, the trilayer method typically improves the sensitivity by 79- and 7-fold in comparison to the conventional dried-droplet and thin-layer methods, respectively.

Vacuum ultraviolet thin films. I - Optical constants of BaF2, CaF2, LaF3, MgF2, Al2O3, HfO2, and SiO2 thin films. II - Vacuum ultraviolet all-dielectric narrowband filters

NASA Technical Reports Server (NTRS)

Zukic, Muamer; Torr, Douglas G.; Spann, James F.; Torr, Marsha R.

1990-01-01

An iteration process matching calculated and measured reflectance and transmittance values in the 120-230 nm VUV region is presently used to ascertain the optical constants of bulk MgF2, as well as films of BaF2, CaF2, LaF3, MgF2, Al2O3, HfO2, and SiO2 deposited on MgF2 substrates. In the second part of this work, a design concept is demonstrated for two filters, employing rapidly changing extinction coefficients, centered at 135 nm for BaF2 and 141 nm for SiO2. These filters are shown to yield excellent narrowband spectral performance in combination with narrowband reflection filters.

Optical, morphological and structural characterization of Langmuir-Schaefer films of a functionalized copper phthalocyanine.

PubMed

Giancane, Gabriele; Filippo, Emanuela; Manno, Daniela; Serra, Antonio; Valli, Ludovico

2011-11-01

Langmuir-Schaefer (LS) films of copper(II) tetrakis-(isoprpoxy-carbonyl)-phthalocyanine (TiPCuPc) have been deposited onto various solid supports. Its floating film have been characterized at the air-water interface by means of Brewster Angle Microscopy and Langmuir curves. Vibrational modes of multilayer transferred LS film have been studied by Raman spectroscopy and the optical parameters (refractive index n and extinction coefficient k) have been determined in the visible range of the electromagnetic spectrum. Linearly polarized light absorbance measurements have been performed at room temperature in the 400-800 nm spectral range and the average orientation of the phthalocyanine rings have been estimated. Transmission electron microscopy has been also used to characterize the morphological properties of the LS film and a close packed arrangement of the deposited molecules has been observed. Copyright © 2011 Elsevier Inc. All rights reserved.

Spectroscopic and structural characterization of the charge-transfer interaction of N,N'-bis-alkyl derivatives of 1,4,6,8-naphthalenediimide with chloranilic and picric acids.

PubMed

Refat, Moamen S; Ahmed, Hamdy A; Grabchev, Ivo; El-Zayat, Lamia A

2008-09-01

Charge-transfer (CT) complexes formed from the reactions of two N,N'-bis-alkyl derivatives of 1,4,6,8-naphthalenediimide such as N,N'-bis[2-hydroxyethyl)]-1,4,6,8-naphthalenediimide (BHENDI) and N,N'-bis-[2-N,N-dimethylaminoethyl)]-1,4,6,8-naphthalenediimide (BDMAENDI) with chloranilic acid (CLA) and piciric acid (PA) as pi-acceptors, have been studied spectrophotometrically in methanol and chloroform, respectively at 25 degrees C. The photometric titration curves for the reactions indicated that the data obtained refer to 1:1 charge-transfer complexes of [(BHENDI)(CLA)], [(BDMAENDI)(CLA)], [(BHENDI)(PA)] and [(BDMAENDI)(PA)] were formed. Benesi-Hildebrand and its modification methods were applied to the determination of association constant (K), molar extinction coefficient (epsilon). The solid CT complexes have been synthesized and characterization by different spectral methods.

Spectroscopic and structural characterization of the charge-transfer interaction of N,N'-bis-alkyl derivatives of 1,4,6,8-naphthalenediimide with chloranilic and picric acids

NASA Astrophysics Data System (ADS)

Refat, Moamen S.; Ahmed, Hamdy A.; Grabchev, Ivo; El-Zayat, Lamia A.

2008-09-01

Charge-transfer (CT) complexes formed from the reactions of two N,N'-bis-alkyl derivatives of 1,4,6,8-naphthalenediimide such as N, N'-bis[2-hydroxyethyl)]-1,4,6,8-naphthalenediimide (BHENDI) and N, N'-bis-[2- N, N-dimethylaminoethyl)]-1,4,6,8-naphthalenediimide (BDMAENDI) with chloranilic acid (CLA) and piciric acid (PA) as π-acceptors, have been studied spectrophotometrically in methanol and chloroform, respectively at 25 °C. The photometric titration curves for the reactions indicated that the data obtained refer to 1:1 charge-transfer complexes of [(BHENDI)(CLA)], [(BDMAENDI)(CLA)], [(BHENDI)(PA)] and [(BDMAENDI)(PA)] were formed. Benesi-Hildebrand and its modification methods were applied to the determination of association constant ( K), molar extinction coefficient ( ɛ). The solid CT complexes have been synthesized and characterization by different spectral methods.

A model predicting the evolution of ice particle size spectra and radiative properties of cirrus clouds. Part 2: Dependence of absorption and extinction on ice crystal morphology

NASA Technical Reports Server (NTRS)

Mitchell, David L.; Arnott, W. Patrick

1994-01-01

This study builds upon the microphysical modeling described in Part 1 by deriving formulations for the extinction and absorption coefficients in terms of the size distribution parameters predicted from the micro-physical model. The optical depth and single scatter albedo of a cirrus cloud can then be determined, which, along with the asymmetry parameter, are the input parameters needed by cloud radiation models. Through the use of anomalous diffraction theory, analytical expressions were developed describing the absorption and extinction coefficients and the single scatter albedo as functions of size distribution parameters, ice crystal shapes (or habits), wavelength, and refractive index. The extinction coefficient was formulated in terms of the projected area of the size distribution, while the absorption coefficient was formulated in terms of both the projected area and mass of the size distribution. These properties were formulated as explicit functions of ice crystal geometry and were not based on an 'effective radius.' Based on simulations of the second cirrus case study described in Part 1, absorption coefficients predicted in the near infrared for hexagonal columns and rosettes were up to 47% and 71% lower, respectively, than absorption coefficients predicted by using equivalent area spheres. This resulted in single scatter albedos in the near-infrared that were considerably greater than those predicted by the equivalent area sphere method. Reflectances in this region should therefore be underestimated using the equivalent area sphere approach. Cloud optical depth was found to depend on ice crystal habit. When the simulated cirrus cloud contained only bullet rosettes, the optical depth was 142% greater than when the cloud contained only hexagonal columns. This increase produced a doubling in cloud albedo. In the near-infrared (IR), the single scatter albedo also exhibited a significant dependence on ice crystal habit. More research is needed on the geometrical properties of ice crystals before the influence of ice crystal shape on cirrus radiative properties can be adequately understood. This study provides a way of coupling the radiative properties of absorption, extinction, and single scatter albedo to the microphysical properties of cirrus clouds. The dependence of extinction and absorption on ice crystal shape was not just due to geometrical differences between crystal types, but was also due to the effect these differences had on the evolution of ice particle size spectra. The ice particle growth model in Part 1 and the radiative properties treated here are based on analytical formulations, and thus represent a computationally efficient means of modeling the microphysical and radiative properties of cirrus clouds.

Spectral analysis of extinguished sunlight

NASA Astrophysics Data System (ADS)

Zagury, Frédéric; Goutail, Florence

2003-08-01

SAOZ (Système d'Analyse par Observation Zénitale) is a balloon-borne experiment which determines the column density of several molecular species from the visible spectrum of sunlight. We will use sequence of spectra collected during a sunset to discuss atmospheric extinction, and the nature of the radiation field in the atmosphere. The radiation field in the atmosphere is, from daylight to sunset, and with a clear sky, dominated by light coming from the direction of the sun. This light is composed of direct sunlight (extinguished by the gas), and of sunlight forward-scattered by aerosols. As the sun sets, aerosol scattering is first perceived towards the UV. It progressively replaces direct sunlight over all of the spectrum. Our analysis permits fixing the main parameters of each component of the radiation field at any time. The fits we find for the extinction of sunlight in the atmosphere must also apply to starlight. Thus, the present work can be used in astronomy to correct ground-based spectral observations for extinction in the atmosphere.

Broadband Measurement of Aerosol Extinction in the Visible Range

NASA Astrophysics Data System (ADS)

He, Quanfu; Bluvshtein, Nir; Segev, Lior; Flores, Michel; Rudich, Yinon; Washenfelder, Rebecca; Brown, Steven

2017-04-01

Atmospheric aerosols influence the Earth's radiative budget directly by scattering and absorbing incoming solar radiation. Aerosol direct forcing remains one of the largest uncertainties in quantifying the role that aerosols play in the Earth's radiative budget. The optical properties of aerosols vary as a function of wavelength, but few measurements reported the wavelength dependence of aerosol extinction cross section and complex refractive indices, particularly in the blue and visible spectral range. There is also currently a large gap in our knowledge of how the optical properties evolve as a function of atmospheric aging in the visible spectrum. In this study, we constructed a new and novel laboratory instrument to measure aerosol extinction as a function of wavelength, using cavity enhanced spectroscopy with a white light source. This broadband cavity enhanced spectroscopy (BBCES) covers the 395-700 nm spectral region using a broadband light source and a grating spectrometer with charge-coupled device detector (CCD). We evaluated this BBCES by measuring extinction cross section for aerosols that are pure scattering, slightly absorbing and strongly absorbing atomized from standard materials. We also retrieved the refractive indices from the measured extinction cross sections. Secondary organic aerosols from biogenic and anthropogenic precursors were "aged" to differential time scales (1 to 10 days) in an Oxidation Flow Reactor (OFR) under the combined influence of OH, O3 and UV light. The new BBCES was used to online measure the extinction cross sections of the SOA. This talk will provide a comprehensive understanding of aerosol optical properties alerting during aging process in the 395 - 700 nm spectrum.

Effective resolution concepts for lidar observations

NASA Astrophysics Data System (ADS)

Iarlori, M.; Madonna, F.; Rizi, V.; Trickl, T.; Amodeo, A.

2015-05-01

Since its first establishment in 2000, EARLINET (European Aerosol Research Lidar NETwork) has been devoted to providing, through its database, exclusively quantitative aerosol properties, such as aerosol backscatter and aerosol extinction coefficients, the latter only for stations able to retrieve it independently (from Raman or High Spectral Resolution Lidars). As these coefficients are provided in terms of vertical profiles, EARLINET database must also include the details on the range resolution of the submitted data. In fact, the algorithms used in the lidar data analysis often alter the spectral content of the data, mainly working as low pass filters with the purpose of noise damping. Low pass filters are mathematically described by the Digital Signal Processing (DSP) theory as a convolution sum. As a consequence, this implies that each filter's output, at a given range (or time) in our case, will be the result of a linear combination of several lidar input data relative to different ranges (times) before and after the given range (time): a first hint of loss of resolution of the output signal. The application of filtering processes will also always distort the underlying true profile whose relevant features, like aerosol layers, will then be affected both in magnitude and in spatial extension. Thus, both the removal of noise and the spatial distortion of the true profile produce a reduction of the range resolution. This paper provides the determination of the effective resolution (ERes) of the vertical profiles of aerosol properties retrieved starting from lidar data. Large attention has been addressed to provide an assessment of the impact of low-pass filtering on the effective range resolution in the retrieval procedure.

Galvanic Synthesis of Hollow Gold Nanoshells

DTIC Science & Technology

2015-02-01

HAuNS of select diameter and shell thickness were synthesized and tunability of the extinction coefficient was demonstrated through control of the... extinction peak HAuNS ......................................................................................................... 4 Fig. 2 Histogram of...was supported in part by an appointment to the Research Participation Program at the US Army Research Laboratory (ARL) administered by the Oak Ridge

Titan's Aerosol and Stratospheric Ice Opacities Between 18 and 500 Micrometers: Vertical and Spectral Characteristics from Cassini CIRS

NASA Technical Reports Server (NTRS)

Anderson, Carrie M.; Samuelson, Robert E.

2011-01-01

Vertical distributions and spectral characteristics of Titan's photochemical aerosol and stratospheric ices are determined between 20 and 560 per centimeter (500-18 micrometers) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15 N, 15 S, and 58 S, where accurate temperature profiles can be independently determined. In addition, estimates of aerosol and ice abundances at 62 N relative to those at 15 S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are approximately 3 times more abundant at 62 N than at 15 S. Generally, nitrile ice clouds (probably HCN and HC3N), as inferred from a composite emission feature at approximately 160 per centimeter, appear to be located over a narrow altitude range in the stratosphere centered at approximately 90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58 S. There is some evidence of a second ice cloud layer at approximately 60 km altitude at 58 S associated with an emission feature at approximately 80 per centimeter. We speculate that the identify of this cloud may be due to C2H6 ice, which in the vapor phase is the most abundant hydrocarbon (next to CH4) in the stratosphere of Titan. Unlike the highly restricted range of altitudes (50-100 km) associated with organic condensate clouds, Titan's photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15 N and 58 S latitude. The ratio of aerosol-to-gas scale heights range from 1.3-2.4 at about 160 km to 1.1-1.4 at 300 km, although there is considerable variability with latitude, The aerosol exhibits a very broad emission feature peaking at approximately 140 per centimeter. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics. Finally, volume extinction coefficients N chi EPSILON derived from 15 S CIRS data at a wavelength of lambda = 62.5 micrometers are compared with those derived from the 10 S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 micrometers. This comparison yields volume extinction coefficient ratios N chi EPSILON (1.583 micrometers)/N chi EPSILON (62.5 micrometers) of roughly 70 and 20, respectively, for Titan's aerosol and stratospheric ices, The inferred particle cross-section ratios chi EPSILON(1.583 micrometers)/chi EPSILON (62.5 micrometers) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles.

Microwave vector radiative transfer equation of a sea foam layer by the second-order Rayleigh approximation

NASA Astrophysics Data System (ADS)

Wei, En-Bo

2011-10-01

The microwave vector radiative transfer (VRT) equation of a coated spherical bubble layer is derived by means of the second-order Rayleigh approximation field when the microwave wavelength is larger than the coated spherical particle diameter. Meanwhile, the perturbation method is developed to solve the second-order Rayleigh VRT equation for the small ratio of the volume scattering coefficient to the extinction coefficient. As an example, the emissive properties of a sea surface foam layer, which consists of seawater coated bubbles, are investigated. The extinction, absorption, and scattering coefficients of sea foam are obtained by the second-order Rayleigh approximation fields and discussed for the different microwave frequencies and the ratio of inner radius to outer radius of a coated bubble. Our results show that in the dilute limit, the volume scattering coefficient decreases with increasing the ratio of inner radius to outer radius and decreasing the frequencies. It is also found that the microwave emissivity and the extinction coefficient have a peak at very thin seawater coating and its peak value decreases with frequency decrease. Furthermore, with the VRT equation and effective medium approximation of densely coated bubbles, the mechanism of sea foam enhancing the emissivity of a sea surface is disclosed. In addition, excellent agreement is obtained by comparing our VRT results with the experimental data of microwave emissivities of sea surface covered by a sea foam layer at L-band (1.4 GHz) and the Camps' model.

Spectral peculiarities of electromagnetic wave scattering by Veselago's cylinders

NASA Astrophysics Data System (ADS)

Sukhov, S. V.; Shevyakhov, N. S.

2006-03-01

The results are presented of spectral calculations of extinction cross-section for scattering of E- and H-polarized electromagnetic waves by cylinders made of Veselago material. The insolvency of previously developed models of scattering is demonstrated. It is shown that correct description of scattering requires separate consideration of both electric and magnetic subsystems.

Spectral peculiarities of electromagnetic wave scattered by Veselago's cylinders

NASA Astrophysics Data System (ADS)

Sukhov, S. V.; Shevyakhov, N. S.

2005-09-01

The results are presented of spectral calculations of extinction cross-section for scattering of E- and H-polarized electromagnetic waves by cylinders made of Veselago material. The insolvency of previously developed models of scattering is demonstrated. It is shown that correct description of scattering requires separate consideration of both electric and magnetic subsystems.

Airborne Aerosol Closure Studies During PRIDE

NASA Technical Reports Server (NTRS)

Redemann, Jens; Livingston, John M.; Russell, Philip B.; Schmid, Beat; Reid, Jeff

2000-01-01

The Puerto Rico Dust Experiment (PRIDE) was conducted during June/July of 2000 to study the properties of Saharan dust aerosols transported across the Atlantic Ocean to the Caribbean Islands. During PRIDE, the NASA Ames Research Center six-channel (380 - 1020 nm) airborne autotracking sunphotometer (AATS-6) was operated aboard a Piper Navajo airplane alongside a suite of in situ aerosol instruments. The in situ aerosol instrumentation relevant to this paper included a Forward Scattering Spectrometer Probe (FSSP-100) and a Passive Cavity Aerosol Spectrometer Probe (PCASP), covering the radius range of approx. 0.05 to 10 microns. The simultaneous and collocated measurement of multi-spectral aerosol optical depth and in situ particle size distribution data permits a variety of closure studies. For example, vertical profiles of aerosol optical depth obtained during local aircraft ascents and descents can be differentiated with respect to altitude and compared to extinction profiles calculated using the in situ particle size distribution data (and reasonable estimates of the aerosol index of refraction). Additionally, aerosol extinction (optical depth) spectra can be inverted to retrieve estimates of the particle size distributions, which can be compared directly to the in situ size distributions. In this paper we will report on such closure studies using data from a select number of vertical profiles at Cabras Island, Puerto Rico, including measurements in distinct Saharan Dust Layers. Preliminary results show good agreement to within 30% between mid-visible aerosol extinction derived from the AATS-6 optical depth profiles and extinction profiles forward calculated using 60s-average in situ particle size distributions and standard Saharan dust aerosol refractive indices published in the literature. In agreement with tendencies observed in previous studies, our initial results show an underestimate of aerosol extinction calculated based on the in situ size distributions relative to the extinction obtained from the sunphotometer measurements. However, a more extensive analysis of all available AATS-6 and in situ size distribution data is necessary to ascertain whether the preliminary results regarding the degree of extinction closure is representative of the entire range of dust conditions encountered in PRIDE. Finally, we will compare the spectral extinction measurements obtained in PRIDE to similar data obtained in Saharan dust layers encountered above the Canary Islands during ACE-2 (Aerosol Characterization Experiment) in July 1997. Thus, the evolution of Saharan dust spectral properties during its transport across the Atlantic can be investigated, provided the dust origin and microphysical properties are found to be comparable.

Cavity Attenuated Phase Shift (CAPS) Method for Airborne Aerosol Light Extinction Measurement: Instrument Validation and First Results from Field Deployment

NASA Astrophysics Data System (ADS)

Petzold, A.; Perim de Faria, J.; Berg, M.; Bundke, U.; Freedman, A.

2015-12-01

Monitoring the direct impact of aerosol particles on climate requires the continuous measurement of aerosol optical parameters like the aerosol extinction coefficient on a regular basis. Remote sensing and ground-based networks are well in place (e.g., AERONET, ACTRIS), whereas the regular in situ measurement of vertical profiles of atmospheric aerosol optical properties remains still an important challenge in quantifying climate change. The European Research Infrastructure IAGOS (In-service Aircraft for a Global Observing System; www.iagos.org) responds to the increasing requests for long-term, routine in situ observational data by using commercial passenger aircraft as measurement platform. However, scientific instrumentation for the measurement of atmospheric constituents requires major modifications before being deployable aboard in-service passenger aircraft. Recently, a compact and robust family of optical instruments based on the cavity attenuated phase shift (CAPS) technique has become available for measuring aerosol light extinction. While this technique was successfully deployed for ground-based atmospheric measurements under various conditions, its suitability for operation aboard aircraft in the free and upper free troposphere still has to be demonstrated. In this work, the modifications of a CAPS PMex instrument for measuring aerosol light extinction on aircraft, the results from subsequent laboratory tests for evaluating the modified instrument prototype, and first results from a field deployment aboard a research aircraft will be covered. In laboratory studies, the instrument showed excellent agreement (deviation < 5%) with theoretical values calculated from Rayleigh scattering cross-sections, when operated on pressurized air and CO2 at ambient and low pressure (~200 hPa). For monodisperse and polydisperse aerosols, reference aerosol extinction coefficients were calculated from measured size distributions and agreed with the CAPS PMex instrument response within 10% deviation. During the field deployment, aerosol extinction coefficients and associated aerosol size distributions have been measured and will be presented as comparison studies between measured and calculated data.

On-site ocean horizontal aerosol extinction coefficient inversion under different weather conditions on the Bo-hai and Huang-hai Seas

NASA Astrophysics Data System (ADS)

Zeng, Xianjiang; Xia, Min; Ge, Yinghui; Guo, Wenping; Yang, Kecheng

2018-03-01

In this paper, we explore the horizontal extinction characteristics under different weather conditions on the ocean surface with on-site experiments on the Bo-hai and Huang-hai Seas in the summer of 2016. An experimental lidar system is designed to collect the on-site experimental data. By aiming at the inhomogeneity and uncertainty of the horizontal aerosol in practice, a joint retrieval method is proposed to retrieve the aerosol extinction coefficients (AEC) from the raw data along the optical path. The retrieval results of both the simulated and the real signals demonstrate that the joint retrieval method is practical. Finally, the sequence observation results of the on-site experiments under different weather conditions are reported and analyzed. These results can provide the attenuation information to analyze the atmospheric aerosol characteristics on the ocean surface.

Seismotectonic, structural, volcanologic, and geomorphic study of New Zealand; indigenous forest assessment in New Zealand; mapping, land use, and environmental studies in New Zealand, volume 1

NASA Technical Reports Server (NTRS)

Probine, M. C.; Suggate, R. P.; Mcgreevy, M. G.; Stirling, I. F. (Principal Investigator)

1977-01-01

The author has identified the following significant results. Results of the atmospheric extinction measurements show clearly the greater opacity of the atmosphere in MSS band 4 which is due to Rayleigh scattering. Atmospheric water vapor absorbs strongly in a wide region between 900 nm and 1000 nm, and this results in a consistently higher extinction coefficient than would otherwise be expected in MSS band 7. The short term fluctuations tend to be greater in band 7 than in the other bands, and this effect is probably due to variations of water vapor concentration in the instrument line of sight. These high extinction coefficients and short term fluctuations in band 7 were observed at Menindee which is in a semi-desert region in western New South Wales.

The Extinction Toward the Galactic Bulge from RR Lyrae Stars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kunder, A; Popowski, P; Cook, K

2007-11-07

The authors present mean reddenings toward 3525 RR0 Lyrae stars from the Galactic bulge fields of the MACHO Survey. These reddenings are determined using the color at minimum V-band light of the RR0 Lyrae stars themselves and are found to be in general agreement with extinction estimates at the same location obtained from other methods. Using 3256 stars located in the Galactic Bulge, they derive the selective extinction coefficient R{sub V,VR} = A{sub V}/E(V-R) = 4.2 {+-} 0.2. this value is what is expected for a standard extinction law with R{sub V,BV} = 3.1 {+-} 0.3

Source apportionment of PM2.5 light extinction in an urban atmosphere in China.

PubMed

Lan, Zijuan; Zhang, Bin; Huang, Xiaofeng; Zhu, Qiao; Yuan, Jinfeng; Zeng, Liwu; Hu, Min; He, Lingyan

2018-01-01

Haze in China is primarily caused by high pollution of atmospheric fine particulates (PM 2.5 ). However, the detailed source structures of PM 2.5 light extinction have not been well established, especially for the roles of various organic aerosols, which makes haze management lack specified targets. This study obtained the mass concentrations of the chemical compositions and the light extinction coefficients of fine particles in the winter in Dongguan, Guangdong Province, using high time resolution aerosol observation instruments. We combined the positive matrix factor (PMF) analysis model of organic aerosols and the multiple linear regression method to establish a quantitative relationship model between the main chemical components, in particular the different sources of organic aerosols and the extinction coefficients of fine particles with a high goodness of fit (R 2 =0.953). The results show that the contribution rates of ammonium sulphate, ammonium nitrate, biomass burning organic aerosol (BBOA), secondary organic aerosol (SOA) and black carbon (BC) were 48.1%, 20.7%, 15.0%, 10.6%, and 5.6%, respectively. It can be seen that the contribution of the secondary aerosols is much higher than that of the primary aerosols (79.4% versus 20.6%) and are a major factor in the visibility decline. BBOA is found to have a high visibility destroying potential, with a high mass extinction coefficient, and was the largest contributor during some high pollution periods. A more detailed analysis indicates that the contribution of the enhanced absorption caused by BC mixing state was approximately 37.7% of the total particle absorption and should not be neglected. Copyright © 2017. Published by Elsevier B.V.

Time Resolved X-Ray Spectral Analysis of Class II YSOs in NGC 2264 During Optical Dips and Bursts

NASA Astrophysics Data System (ADS)

Guarcello, Mario Giuseppe; Flaccomio, Ettore; Micela, Giuseppina; Argiroffi, Costanza; Venuti, Laura

2016-07-01

Pre-Main Sequence stars are variable sources. The main mechanisms responsible for their variability are variable extinction, unsteady accretion, and rotational modulation of both hot and dark photospheric spots and X-ray active regions. In stars with disks this variability is thus related to the morphology of the inner circumstellar region (<0.1 AU) and that of photosphere and corona, all impossible to be spatially resolved with present day techniques. This has been the main motivations of the Coordinated Synoptic Investigation of NGC2264, a set of simultaneous observations of NGC2264 with 15 different telescopes.We analyze the X-ray spectral properties of stars with disks extracted during optical bursts and dips in order to unveil the nature of these phenomena. Stars are analyzed in two different samples. In stars with variable extinction a simultaneous increase of optical extinction and X-ray absorption is searched during the optical dips; in stars with accretion bursts we search for soft X-ray emission and increasing X-ray absorption during the bursts. In 9/33 stars with variable extinction we observe simultaneous increase of X-ray absorption and optical extinction. In seven dips it is possible to calculate the NH/AV ratio in order to infer the composition of the obscuring material. In 5/27 stars with optical accretion bursts, we observe soft X-ray emission during the bursts that we associate to the emission of accreting gas. It is not surprising that these properties are not observed in all the stars with dips and bursts since favorable geometric configurations are required. The observed variable absorption during the dips is mainly due to dust-free material in accretion streams. In stars with accretion bursts we observe in average a larger soft X-ray spectral component not observed in non accreting stars. This indicates that this soft X-ray emission arises from the accretion shocks.

High Spectral Resolution Lidar: System Calibration

NASA Astrophysics Data System (ADS)

Vivek Vivekanandan, J.; Morley, Bruce; Spuler, Scott; Eloranta, Edwin

2015-04-01

One of the unique features of the high spectral resolution lidar (HSRL) is simultaneous measurements of backscatter and extinction of atmosphere. It separates molecular scattering from aerosol and cloud particle backscatter based on their Doppler spectrum width. Scattering from aerosol and cloud particle are referred as Mie scattering. Molecular or Rayleigh scattering is used as a reference for estimating aerosol extinction and backscatter cross-section. Absolute accuracy of the backscattered signals and their separation into Rayleigh and Mie scattering depends on spectral purity of the transmitted signals, accurate measurement of transmit power, and precise performance of filters. Internal calibration is used to characterize optical subsystems Descriptions of high spectral resolution lidar system and its measurement technique can be found in Eloronta (2005) and Hair et al.(2001). Four photon counting detectors are used to measure the backscatter from the combined Rayleigh and molecular scattering (high and low gain), molecular scattering and cross-polarized signal. All of the detectors are sensitive to crosstalk or leakage through the optical filters used to separate the received signals and special data files are used to remove these effects as much as possible. Received signals are normalized with respect to the combined channel response to Mie and Rayleigh scattering. The laser transmit frequency is continually monitored and tuned to the 1109 Iodine absorption line. Aerosol backscatter cross-section is measured by referencing the aerosol return signal to the molecular return signal. Extinction measurements are calculated based on the differences between the expected (theoretical) and actual change in the molecular return. In this paper an overview of calibration of the HSRL is presented. References: Eloranta, E. W., High Spectral Resolution Lidar in Lidar: Range-Resolved Optical Remote Sensing of the Atmosphere, Klaus Weitkamp editor, Springer Series in Optical Sciences, Springer-Verlag, New York, 2005. Hair, JW; Caldwell, LM; Krueger, D. A.Krueger, and C.Y. She 2001: High-spectral-resolution lidar with iodine-vapor filters: measurement of atmospheric-state and aerosol profiles. Appl. Optics, 40, 5280-5294.

In-Situ Measurements of Aerosol Optical Properties using New Cavity Ring-Down and Photoacoustics Instruments and Comparison with more Traditional Techniques

NASA Technical Reports Server (NTRS)

Strawa, A. W.; Arnott, P.; Covert, D.; Elleman, R.; Ferrare, R.; Hallar, A. G.; Jonsson, H.; Kirchstetter, T. W.; Luu, A. P.; Ogren, J.

2004-01-01

Carbonaceous species (BC and OC) are responsible for most of the absorption associated with aerosol particles. The amount of radiant energy an aerosol absorbs has profound effects on climate and air quality. It is ironic that aerosol absorption coefficient is one of the most difficult aerosol properties to measure. A new cavity ring-down (CRD) instrument, called Cadenza (NASA-ARC), measures the aerosol extinction coefficient for 675 nm and 1550 nm light, and simultaneously measures the scattering coefficient at 675 nm. Absorption coefficient is obtained from the difference of measured extinction and scattering within the instrument. Aerosol absorption coefficient is also measured by a photoacoustic (PA) instrument (DRI) that was operated on an aircraft for the first time during the DOE Aerosol Intensive Operating Period (IOP). This paper will report on measurements made with this new instrument and other in-situ instruments during two field recent field studies. The first field study was an airborne cam;oaign, the DOE Aerosol Intensive Operating Period flown in May, 2003 over northern Oklahoma. One of the main purposes of the IOP was to assess our ability to measure extinction and absorption coefficient in situ. This paper compares measurements of these aerosol optical properties made by the CRD, PA, nephelometer, and Particle Soot Absorption Photometer (PSAP) aboard the CIRPAS Twin-Otter. During the IOP, several significant aerosol layers were sampled aloft. These layers are identified in the remote (AATS-14) as well as in situ measurements. Extinction profiles measured by Cadenza are compared to those derived from the Ames Airborne Tracking Sunphotometer (AATS-14, NASA-ARC). The regional radiative impact of these layers is assessed by using the measured aerosol optical properties in a radiative transfer model. The second study was conducted in the Caldecott Tunnel, a heavily-used tunnel located north of San Francisco, Ca. The aerosol sampled in this study was characterized by fresh automobile and diesel exhaust. Measurements from Cadenza and from an aethalometer are presented. The aethalometer is a filter-based photometer and the infrared channel is calibrated to produce a measure of BC mass loading.

Temperature and pressure dependence of dichloro-difluoromethane (CF2C12) absorption coefficients for CO2 waveguide laser radiation

NASA Technical Reports Server (NTRS)

Harward, C. N.

1977-01-01

Measurements were performed to determine the pressure and temperature dependence of CFM-12 absorption coefficients for CO2 waveguide laser radiation. The absorption coefficients of CFM-12 for CO2 waveguide laser radiation were found to have no spectral structure within small spectral bandwidths around the CO2 waveguide laser lines in the CO2 spectral band for pressures above 20 torr. All of the absorption coefficients for the CO2 laser lines studied are independent of pressure above 100 torr, except for the P(36) laser CO2 spectral band. The absorption coefficients associated with the P(42) line in the same band showed the greatest change with temperature, and it also has the largest value of all the lines studied.

The CO2 absorption continuum by high pressure CRDS in the 1.74 μm window

NASA Astrophysics Data System (ADS)

Mondelain, D.; Campargue, A.; Čermák, P.; Gamache, R. R.; Kassi, S.; Tashkun, S. A.; Tran, H.

2017-12-01

The very weak absorption continuum of CO2 is studied by Cavity Ring Down Spectroscopy in three 20 cm-1 wide spectral intervals near the centre of the 1.74 μm window (5693-5795 cm-1). For each spectral interval, a set of room temperature spectra is recorded at pressures between 0 and 10 bar thanks to a high pressure CRDS spectrometer. The absorption continuum is retrieved after subtraction of the contributions due to Rayleigh scattering and to local lines of CO2 and water (present as an impurity in the sample) from the measured extinction. Due to some deficiencies of the CO2 HITRAN2012 line list, a composite line list had to be built on the basis of the Ames calculated line list with line positions adjusted according to the Carbon Dioxide Spectroscopic Databank and self-broadening and pressure shift coefficients calculated with the Complex Robert Bonamy method. The local line contribution of the CO2 monomer is calculated using this list and a Voigt profile truncated at ±25 cm-1 from the line centre. Line mixing effects were taken into account through the use of the impact and Energy Corrected Sudden approximations. The density dependence of the retrieved continuum absorption was found to be purely quadratic in the low frequency interval below 5710 cm-1 but a small significant linear contribution was required to reproduce the observations above this value. This linear increase is tentatively attributed to the foreign-continuum of water vapor present in CO2 sample with a relative concentration of some tens ppm. The retrieved binary coefficient is observed to vary smoothly with the wavenumber with a minimum value of 6×10-10 cm-1 amagat-2. By gathering the present data with the results reported in Kassi et al. J Quant Spectrosc Radiat Transf 2015;167:97, a recommended set of binary coefficients is provided for the 5700-5950 cm-1 region.

The efficiency of photodissociation for molecules in interstellar ices

NASA Astrophysics Data System (ADS)

Kalvāns, J.

2018-05-01

Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average, general ratio between photodissociation coefficients for molecules in ice and gas. A 1D astrochemical model was utilized to simulate the chemical composition for a line of sight through a collapsing interstellar cloud core, whose interstellar extinction changes with time. At different extinctions, the calculated column densities of icy carbon oxides and ammonia (relative to water ice) were compared to observations. The latter were taken from literature data of background stars sampling ices in molecular clouds. The best-fit value for the solid/gas photodissociation coefficient ratio was found to be ≈0.3. In other words, gas-phase photodissociation rate coefficients have to be reduced by a factor of 0.3 before applying them to icy species. A crucial part of the model is a proper inclusion of cosmic-ray induced desorption. Observations sampling gas with total extinctions in excess of ≈22 mag were found to be uncorrelated to modelling results, possibly because of grains being covered with non-polar molecules.

Investigation of shortcomings in simulated aerosol vertical profiles

NASA Astrophysics Data System (ADS)

Park, S.; Allen, R.

2017-12-01

The vertical distribution of aerosols is one important factor for aerosol radiative forcing. Previous studies show that climate models poorly reproduce the aerosol vertical profile, with too much aerosol aloft in the upper troposphere. This bias may be related to several factors, including excessive convective mass flux and wet removal. In this study, we evaluate the aerosol vertical profile from several Coupled Model Intercomparison Project 5 (CMIP5) models, as well as the Community Atmosphere Model 5 (CAM5), relative to the Cloud-Aerosol Lidar Infrared Pathfinder Satellite Observation (CALIPSO). The results show that all models significantly underestimate extinction coefficient in the lower troposphere, while overestimating extinction coefficient in the upper troposphere. In addition, the majority of models indicate a land-ocean dependence in the relationship between aerosol extinction coefficient in the upper troposphere and convective mass flux. Over the continents, more convective mass flux is related to more aerosol aloft; over the ocean, more convective mass flux is associated with less aerosol in upper troposphere. Sensitivity experiments are conducted to investigate the role that convection and wet deposition have in contributing to the deficient simulation of the vertical aerosol profile, including the land-ocean dependence.

Mutation load and the extinction of large populations

NASA Astrophysics Data System (ADS)

Bernardes, A. T.

1996-02-01

In the time evolution of finite populations, the accumulation of harmful mutations in further generations might lead to a temporal decay in the mean fitness of the whole population that, after sufficient time, would reduce population size and so lead to extinction. This joint action of mutation load and population reduction is called Mutational Meltdown and is usually considered only to occur in small asexual or very small sexual populations. However, the problem of extinction cannot be discussed in a proper way if one previously assumes the existence of an equilibrium state, as initially discussed in this paper. By performing simulations in a genetically inspired model for time-changing populations, we show that mutational meltdown also occurs in large asexual populations and that the mean time to extinction is a nonmonotonic function of the selection coefficient. The stochasticity of the extinction process is also discussed. The extinction of small sexual N ∼ 700 populations is shown and our results confirm the assumption that the existence of recombination might be a powerful mechanism to avoid extinction.

Backscatter and extinction measurements in cloud and drizzle at CO2 laser wavelengths

NASA Technical Reports Server (NTRS)

Jennings, S. G.

1986-01-01

The backscatter and extinction of laboratory generated cloud and drizzle sized water drops were measured at carbon dioxide laser wavelengths (predominately at lambda = 10.591 micrometers). Two distinctly different drop size regimes were studied: one which covers the range normally encompassed by natural cloud droplets and the other representative of mist or drizzle sized drops. The derivation and verification of the relation between extinction and backscatter at carbon dioxide laser wavelengths should allow the determination of large cloud drop and drizzle extinction coefficient solely from a lidar return signal without requiring knowledge of the drop size distribution. This result will also apply to precipitation sized drops so long as they are spherical.

Report on Research

DTIC Science & Technology

1989-06-01

Force systems require a resolved information on the optical thorough understanding of the propaga- extinction coefficient. Measurements of tion path , the...Depolarization as Function of Snow Density. Measurement System ). (It correlated well with the ( Multi -scatter scale length information is usable to extinction ...data on the effect of optically thin cirrus clouds on long - path infrared transmit- tance. Future system designers will have access to this new

Development of seismic fragility curves for low-rise masonry infilled reinforced concrete buildings by a coefficient-based method

NASA Astrophysics Data System (ADS)

Su, Ray Kai Leung; Lee, Chien-Liang

2013-06-01

This study presents a seismic fragility analysis and ultimate spectral displacement assessment of regular low-rise masonry infilled (MI) reinforced concrete (RC) buildings using a coefficient-based method. The coefficient-based method does not require a complicated finite element analysis; instead, it is a simplified procedure for assessing the spectral acceleration and displacement of buildings subjected to earthquakes. A regression analysis was first performed to obtain the best-fitting equations for the inter-story drift ratio (IDR) and period shift factor of low-rise MI RC buildings in response to the peak ground acceleration of earthquakes using published results obtained from shaking table tests. Both spectral acceleration- and spectral displacement-based fragility curves under various damage states (in terms of IDR) were then constructed using the coefficient-based method. Finally, the spectral displacements of low-rise MI RC buildings at the ultimate (or nearcollapse) state obtained from this paper and the literature were compared. The simulation results indicate that the fragility curves obtained from this study and other previous work correspond well. Furthermore, most of the spectral displacements of low-rise MI RC buildings at the ultimate state from the literature fall within the bounded spectral displacements predicted by the coefficient-based method.

Four-wavelength lidar evaluation of particle characteristics and aerosol densities

NASA Astrophysics Data System (ADS)

Uthe, E. E.; Livingston, J. M.; Delateur, S. A.; Nielsen, N. B.

1985-06-01

The SRI International four-wavelength (0.53, 1.06, 3.8, 10.6 micron) lidar systems was used during the SNOW-ONE-B and Smoke Week XI/SNOW-TWO field experiments to validate its capabilities in assessing obscurant optical and physical properties. The lidar viewed along a horizontal path terminated by a passive reflector. Data examples were analyzed in terms of time-dependent transmission, wavelength dependence of optical depth, and range-resolved extinction coefficients. Three methods were used to derive extinction data from the lidar signatures. These were target method, Klett method and experimental data method. The results of the field and analysis programs are reported in the journal and conference papers that are appended to this report, and include: comparison study of lidar extinction methods, submitted to applied optics, error analysis of lidar solution techniques for range-resolved extinction coefficients based on observational data, smoke/obscurants symposium 9, Four--Wavelength Lidar Measurements from smoke week 6/SNOW-TWO, smoke/obscurants symposium 8, SNOW-ONE-B multiple-wavelength lidar measurements. Snow symposium 3, and lidar applications for obscurant evaluations, smoke/obscurants Symposium 7. The report also provides a summary of background work leading to this project, and of project results.

Electromagnetic Attenuation Characteristics of Microbial Materials in the Infrared Band.

PubMed

Wang, Peng; Liu, Hongxia; Zhao, Yizheng; Gu, Youlin; Chen, Wei; Wang, Li; Li, Le; Zhao, Xinying; Lei, Wuhu; Hu, Yihua; Zheng, Zhiming

2016-09-01

In this study, seven microbial materials (entomogenous fungi Bb3088 mycelia, entomogenous fungi Bb3088 spores, entomogenous fungi Ma2677 mycelia, entomogenous fungi Ma2677 spores, Bacillus subtilis 8204, Staphylococcus aureus 6725, and Saccharomyces cerevisiae 1025) were used to measure electromagnetic (EM) signal extinction. They were subjected to light absorption and reflection measurements in the range of 4000-400 cm(-1) (2.5-25 µm) using Fourier transform infrared spectroscopy. The specular reflection spectrum method was used to calculate the real (n) and imaginary (k) parts of the complex refractive index. The complex refractive index with real part n and imaginary part k in the infrared band satisfies the following conditions n ≥ 1 and k ≥ 0. The mass extinction coefficient was calculated based on Mie theory. Entomogenous fungi Ma2677 spores and entomogenous fungi Bb3088 spores were selected as EM signal extinction materials in the smoke box test. The transmittances of entomogenous fungi Bb3088 spores and entomogenous fungi Ma2677 spores were 11.63% and 5.42%, and the mass extinction coefficients were 1.8337 m(2)/g and 1.227 m(2)/g. These results showed that entomogenous fungi Bb3088 spores and entomogenous fungi Ma2677 spores have higher extinction characteristics than other microbial materials. © The Author(s) 2016.

DustEM: Dust extinction and emission modelling

NASA Astrophysics Data System (ADS)

Compiègne, M.; Verstraete, L.; Jones, A.; Bernard, J.-P.; Boulanger, F.; Flagey, N.; Le Bourlot, J.; Paradis, D.; Ysard, N.

2013-07-01

DustEM computes the extinction and the emission of interstellar dust grains heated by photons. It is written in Fortran 95 and is jointly developed by IAS and CESR. The dust emission is calculated in the optically thin limit (no radiative transfer) and the default spectral range is 40 to 108 nm. The code is designed so dust properties can easily be changed and mixed and to allow for the inclusion of new grain physics.

The spectral energy distribution of Zeta Puppis and HD 50896

NASA Technical Reports Server (NTRS)

Holm, A. V.; Cassinelli, J. P.

1977-01-01

The ultraviolet spectral energy distribution of the O5f star Zeta Pup and the WN5 star HD 50896 are derived from OAO-2 observations with the calibration of Bless, Code, and Fairchild (1976). An estimate of the interstellar reddening (0.12 magnitude) of the Wolf-Rayet star is determined from the size of the characteristic interstellar extinction bump at 4.6 inverse microns. After correction for extinction, both stars show a flat energy distribution in the ultraviolet. The distribution of HD 50896 from 1100 A to 2 microns is in good agreement with results of extended model atmospheres, but some uncertainty remains because of the interstellar-extinction correction. The absolute energy distribution of Zeta Pup is fitted by a 42,000-K plane-parallel model if the model's flux is adjusted for the effects of electron scattering in the stellar wind and for UV line blanketing that was determined empirically from high-resolution Copernicus satellite observations. To achieve this fit, it is necessary to push both the spectroscopically determined temperature and the ultraviolet calibration to the limits of their probable errors.

Comparison of Aerosol Classification From Airborne High Spectral Resolution Lidar and the CALIPSO Vertical Feature Mask

NASA Technical Reports Server (NTRS)

Burton, Sharon P.; Ferrare, Rich A.; Omar, Ali H.; Vaughan, Mark A.; Rogers, Raymond R.; Hostetler, Chris a.; Hair, Johnathan W.; Obland, Michael D.; Butler, Carolyn F.; Cook, Anthony L.;

Do Periodicities in Extinction—with Possible Astronomical Connections—Survive a Revision of the Geological Timescale?

NASA Astrophysics Data System (ADS)

Melott, Adrian L.; Bambach, Richard K.

2013-08-01

A major revision of the geological timescale was published in 2012. We re-examine our past finding of a 27 Myr periodicity in marine extinction rates by re-assigning dates to the extinction data used previously. We find that the spectral power in this period is somewhat increased, and persists at a narrow bandwidth, which supports our previous contention that the Nemesis hypothesis is untenable as an explanation for the periodicity that was first noted by Raup & Sepkoski in the 1980s. We enumerate a number of problems in a recent study comparing extinction rates with time series models.

Retrieval of the aerosol size distribution in the complex anomalous diffraction approximation

NASA Astrophysics Data System (ADS)

Franssens, Ghislain R.

This contribution reports some recently achieved results in aerosol size distribution retrieval in the complex anomalous diffraction approximation (ADA) to MIE scattering theory. This approximation is valid for spherical particles that are large compared to the wavelength and have a refractive index close to 1. The ADA kernel is compared with the exact MIE kernel. Despite being a simple approximation, the ADA seems to have some practical value for the retrieval of the larger modes of tropospheric and lower stratospheric aerosols. The ADA has the advantage over MIE theory that an analytic inversion of the associated Fredholm integral equation becomes possible. In addition, spectral inversion in the ADA can be formulated as a well-posed problem. In this way, a new inverse formula was obtained, which allows the direct computation of the size distribution as an integral over the spectral extinction function. This formula is valid for particles that both scatter and absorb light and it also takes the spectral dispersion of the refractive index into account. Some details of the numerical implementation of the inverse formula are illustrated using a modified gamma test distribution. Special attention is given to the integration of spectrally truncated discrete extinction data with errors.

Quantitative impact of small angle forward scatter on whole blood oximetry using a Beer-Lambert absorbance model.

PubMed

LeBlanc, Serge Emile; Atanya, Monica; Burns, Kevin; Munger, Rejean

2011-04-21

It is well known that red blood cell scattering has an impact on whole blood oximetry as well as in vivo retinal oxygen saturation measurements. The goal of this study was to quantify the impact of small angle forward scatter on whole blood oximetry for scattering angles found in retinal oximetry light paths. Transmittance spectra of whole blood were measured in two different experimental setups: one that included small angle scatter in the transmitted signal and one that measured the transmitted signal only, at absorbance path lengths of 25, 50, 100, 250 and 500 µm. Oxygen saturation was determined by multiple linear regression in the 520-600 nm wavelength range and compared between path lengths and experimental setups. Mean calculated oxygen saturation differences between setups were greater than 10% at every absorbance path length. The deviations to the Beer-Lambert absorbance model had different spectral dependences between experimental setups, with the highest deviations found in the 520-540 nm range when scatter was added to the transmitted signal. These results are consistent with other models of forward scatter that predict different spectral dependences of the red blood cell scattering cross-section and haemoglobin extinction coefficients in this wavelength range.

Photodynamic therapy of solid tumors

NASA Astrophysics Data System (ADS)

Jori, Giulio

Some porphyrin compounds, which are characterized by a relatively large degree of hydrophobicity (n-octanol/water partition coefficient above 8), are accumulated in greater amounts and retained for longer periods of time by neoplastic as compared with normal tissues. The affinity of these dyes for tumors is partially a consequence of their in vivo transport by low-density lipoproteins, which are preferentially endocytosized by hyperproliferating tissues in a receptor-mediated process. In general, at 24-48 h after the systematic administration of porphyrin doses in the range of 2.5 mg/kg body weight, the ratio of drug concentration between the neoplastic and the surrounding tissues is sufficiently large to guarantee a selective photoexcitation of the porphyrin. Toward this aim, the porphyrin-containing tumor tissues are irradiated with light wavelengths longer than 600 nm, since the transmittance of biological tissues is maximal in this spectral region. The electronically excited porphyrin transfers its excitation energy to oxygen, thus generating activated oxygen species (mainly, singlet oxygen): as a consequence, the photooxidative modification of subcellular targets (e.g. the plasma membrane and mitochondria) is readily obtained leading to an irreversible necrosis of the cell. With the most frequently used porphyrins for clinical phototherapy (including hematoporphyrin and its derivatives HpD and Photofrin II), one observes the preferential photosensitized destruction of endothelial cells, hence the vascular damage is a major process involved in the necrosis of tumors. The optimization of the phototherapy of tumors is presently pursued by the definition of clinical protocols tailored to the optical properties of specific neoplastic tissues as well as by the use of porphyrin analogs, such as chlorins and phthalocyanines, having an extinction coefficient in the red spectral region larger than that typical of hematoporphyrin and HpD.

Investigation on the growth, spectral, lifetime, mechanical analysis and third-order nonlinear optical studies of L-methionine admixtured D-mandelic acid single crystal: A promising material for nonlinear optical applications

NASA Astrophysics Data System (ADS)

Jayaprakash, P.; Sangeetha, P.; Kumari, C. Rathika Thaya; Caroline, M. Lydia

2017-08-01

A nonlinear optical bulk single crystal of L-methionine admixtured D-mandelic acid (LMDMA) has been grown by slow solvent evaporation technique using water as solvent at ambient temperature. The crystallized LMDMA single crystal subjected to single crystal X-ray diffraction study confirmed monoclinic system with the acentric space group P21. The FTIR analysis gives information about the modes of vibration in the various functional groups present in LMDMA. The UV-visible spectral analysis assessed the optical quality and linear optical properties such as extinction coefficient, reflectance, refractive index and from which optical conductivity and electric susceptibility were also evaluated. The frequency doubling efficiency was observed using Kurtz Perry powder technique. A multiple shot laser was utilized to evaluate the laser damage threshold energy of the crystal. Discrete thermodynamic properties were carried out by TG-DTA studies. The hardness, Meyer's index, yield strength, elastic stiffness constant, Knoop hardness, fracture toughness and brittleness index were analyzed using Vickers microhardness tester. Layer growth pattern and the surface defect were examined by chemical etching studies using optical microscope. Fluorescence emission spectrum was recorded and lifetime was also studied. The electric field response of crystal was investigated from the dielectric studies at various temperatures at different frequencies. The third-order nonlinear optical response in LMDMA has been investigated using Z-scan technique with He-Ne laser at 632.8 nm and nonlinear parameters such as refractive index (n2), absorption coefficient (β) and susceptibility (χ3) investigated extensively for they are in optical phase conjucation, high-speed optical switches and optical dielectric devices.

A simple method of measuring the effective SRS coefficient in single-mode optical fibres and the range of its applicability

NASA Astrophysics Data System (ADS)

Shikhaliev, I. I.; Gainov, V. V.; Dorozhkin, A. N.; Nanii, O. E.; Konyshev, V. A.; Treshchikov, V. N.

2017-11-01

This paper describes techniques for measuring the SRS coefficient in a wide spectral range, including the region of small Stokes shifts. A simple, approximate method is proposed for evaluating the SRS coefficient near a gain peak. Spectral dependences of the SRS coefficient are presented for various telecom fibres.

Influence of particle aspect ratio on the midinfrared extinction spectra of wavelength-sized ice crystals.

PubMed

Wagner, Robert; Benz, Stefan; Möhler, Ottmar; Saathoff, Harald; Schnaiter, Martin; Leisner, Thomas

2007-12-20

We have used the T-matrix method and the discrete dipole approximation to compute the midinfrared extinction cross-sections (4500-800 cm(-1)) of randomly oriented circular ice cylinders for aspect ratios extending up to 10 for oblate and down to 1/6 for prolate particle shapes. Equal-volume sphere diameters ranged from 0.1 to 10 microm for both particle classes. A high degree of particle asphericity provokes a strong distortion of the spectral habitus compared to the extinction spectrum of compactly shaped ice crystals with an aspect ratio around 1. The magnitude and the sign (increase or diminution) of the shape-related changes in both the absorption and the scattering cross-sections crucially depend on the particle size and the values for the real and imaginary part of the complex refractive index. When increasing the particle asphericity for a given equal-volume sphere diameter, the values for the overall extinction cross-sections may change in opposite directions for different parts of the spectrum. We have applied our calculations to the analysis of recent expansion cooling experiments on the formation of cirrus clouds, performed in the large coolable aerosol and cloud chamber AIDA of Forschungszentrum Karlsruhe at a temperature of 210 K. Depending on the nature of the seed particles and the temperature and relative humidity characteristics during the expansion, ice crystals of various shapes and aspect ratios could be produced. For a particular expansion experiment, using Illite mineral dust particles coated with a layer of secondary organic matter as seed aerosol, we have clearly detected the spectral signatures characteristic of strongly aspherical ice crystal habits in the recorded infrared extinction spectra. We demonstrate that the number size distributions and total number concentrations of the ice particles that were generated in this expansion run can only be accurately derived from the recorded infrared spectra when employing aspect ratios as high as 10 in the retrieval approach. Remarkably, the measured spectra could also be accurately fitted when employing an aspect ratio of 1 in the retrieval. The so-deduced ice particle number concentrations, however, exceeded the true values, determined with an optical particle counter, by more than 1 order of magnitude. Thus, the shape-induced spectral changes between the extinction spectra of platelike ice crystals of aspect ratio 10 and compactly shaped particles of aspect ratio 1 can be efficiently balanced by deforming the true number size distribution of the ice cloud. As a result of this severe size/shape ambiguity in the spectral analysis, we consider it indispensable to cross-check the infrared retrieval results of wavelength-sized ice particles with independent reference measurements of either the number size distribution or the particle morphology.

Diffuse interstellar clouds as a chemical laboratory - The chemistry of diatomic carbon species

NASA Technical Reports Server (NTRS)

Federman, S. R.; Huntress, W. T., Jr.

1989-01-01

The chemistry of C2, CH, and CO in diffuse interstellar clouds is analyzed and compared to absorption line measurements toward background stars. Analytical expressions in terms of column densities are derived for the rate equations. The results indicate that in clouds with 4 mag of visual extinction, the abundance of C+ has to decrease by a factor of about 15 from the value traditionally used for clouds with 1 mag of extinction. The rate coefficients for the reactions C+ + CH - C2+ + H and C+ + H2 - CH2+ + h-nu need to be reduced from previous estimates. Chemical arguments are presented for the revised rate coefficients.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Jay; Harris, Tequila

A novel bidirectional thickness profilometer based on transmission densitometry was designed to measure the localized thickness of semitransparent films on a dynamic manufacturing line. The densitometer model shows that, for materials with extinction coefficients between 0.3 and 2.9 D/mm, 100-500 {mu}m measurements can be recorded with less than {+-}5% error at more than 10,000 locations in real time. As a demonstration application, the thickness profiles of 75 mmx100 mm regions of polymer electrolyte membrane (PEM) were determined by converting the optical density of the sample to thickness with the Beer-Lambert law. The PEM extinction coefficient was determined to be 1.4more » D/mm, with an average thickness error of 4.7%.« less

Measurement and analysis on optical characteristics of Aspergillus oryzae spores in infrared band

NASA Astrophysics Data System (ADS)

Li, Le; Hu, Yihua; Gu, Youlin; Chen, Wei; Xu, Shilong; Zhao, Xinying

2015-10-01

Spore is an important part of bioaerosols. The optical characteristics of spore is a crucial parameter for study on bioaerosols. The reflection within the waveband of 2.5 to15μm were measured by squash method. Based on the measured data, Complex refractive index of Aspergillus oryzae spores within the waveband of 3 to 5μm and 8 to 14 μm were calculated by using Krames-Kronig (K-K) relationship. Then,the mass extinction coefficient of Aspergillus oryzae spores within the waveband of 3 to 5μm and 8 to 14μm were obtained by utilizing Mie scattering theory, and the results were analyzed and discussed. The average mass extinction coefficient of Aspergillus oryzae spores is 0.51 m2/g in the range of 3 to 5μm and 0.48m2/g in the range of 8 to 14μm. Compared with common inorganic compounds, Aspergillus oryzae spores possesses a good extinction performance in infrared band.

Aerosol optical properties measurements by a CAPS single scattering albedo monitor: Comparisons between summer and winter in Beijing, China

NASA Astrophysics Data System (ADS)

Han, Tingting; Xu, Weiqi; Li, Jie; Freedman, Andrew; Zhao, Jian; Wang, Qingqing; Chen, Chen; Zhang, Yingjie; Wang, Zifa; Fu, Pingqing; Liu, Xingang; Sun, Yele

2017-02-01

Aerosol optical properties were measured in Beijing in summer and winter using a state-of-the-art cavity attenuated phase shift single scattering albedo monitor (CAPS PMssa) along with aerosol composition measurements by aerosol mass spectrometers and aethalometers. The SSA directly measured by the CAPS PMssa showed overall agreements with those derived from colocated measurements. However, substantial differences were observed during periods with low SSA values in both summer and winter, suggesting that interpretation of low SSA values needs to be cautious. The average (±σ) extinction coefficient (bext) and absorption coefficient (bap) were 336 (±343) Mm-1 and 44 (±41) Mm-1, respectively, during wintertime, which were approximately twice those observed in summer, while the average SSA was relatively similar, 0.86 (±0.06) and 0.85 (±0.04) in summer and winter, respectively. Further analysis showed that the variations in SSA can be approximately parameterized as a function of mass fraction of secondary particulate matter (fSPM), which is SSA = 0.74 + 0.19 × fSPM (fSPM > 0.3, r2 = 0.85). The contributions of aerosol species to extinction coefficients during the two seasons were also estimated. Our results showed that the light extinction was dominantly contributed by ammonium sulfate (30%) and secondary organic aerosol (22%) in summer, while organic aerosol was the largest contributor (51%) in winter. Consistently, SPM played the major role in visibility degradation in both seasons by contributing 70% of the total extinction.

Determination of the wavelength dependence of the differential pathlength factor from near-infrared pulse signals

NASA Astrophysics Data System (ADS)

Kohl, Matthias; Nolte, Christian; Heekeren, Hauke R.; Horst, Susanne; Scholz, Udo; Obrig, Hellmuth; Villringer, Arno

1998-06-01

For the calculation of changes in oxyhaemoglobin, deoxyhaemoglobin and the redox state of cytochrome-c-oxidase from attenuation data via a modified Beer-Lambert equation the wavelength dependence of the differential pathlength factor (DPF) has to be taken into account. The DPF, i.e. the ratio of the mean optical pathlength and the physical light source-detector separation at each wavelength, determines the crosstalk between the different concentrations and is therefore essential for a sensitive detection of chromophore changes. Here a simple method is suggested to estimate the wavelength dependence of the DPF from pulse-induced attenuation changes measured on the head of adult humans. The essence is that the DPF is the ratio of the attenuation changes over absorption coefficient changes, and that the spectral form of the pulse correlated absorption coefficient change can be assumed to be proportional to the extinction coefficient of blood. Indicators for the validity of the DPF derived for wavelengths between 700 and 970 nm are the stability of the calculated haemoglobin and cytochrome signals with variations of the wavelength range included for their calculation and its overall agreement with the data available from the literature.

The enigma of the open cluster M29 (NGC 6913) solved

DOE Office of Scientific and Technical Information (OSTI.GOV)

Straižys, V.; Milašius, K.; Černis, K.

2014-11-01

Determining the distance to the open cluster M29 (NGC 6913) has proven difficult, with distances determined by various authors differing by a factor of two or more. To solve this problem, we have initiated a new photometric investigation of the cluster in the Vilnius seven-color photometric system, supplementing it with available data in the BV and JHK {sub s} photometric systems and spectra of the nine brightest stars of spectral classes O and B. Photometric spectral classes and luminosities of 260 stars in a 15' × 15' area down to V = 19 mag are used to investigate the interstellarmore » extinction run with distance and to estimate the distance of the Great Cygnus Rift, ∼ 800 pc. The interstellar reddening law in the optical and near-infrared regions is found to be close to normal, with the ratio of extinction to color excess R{sub BV} = 2.87. The extinction A{sub V} of cluster members is between 2.5 and 3.8 mag, with a mean value of 2.97 mag, or E {sub B–V} = 1.03. The average distance of eight stars of spectral types O9-B2 is 1.54 ± 0.15 kpc. Two stars from the seven brightest stars are field stars: HDE 229238 is a background B0.5 supergiant and HD 194378 is a foreground F star. In the intrinsic color-magnitude diagram, seven fainter stars of spectral classes B3-B8 are identified as possible members of the cluster. The 15 selected members of the cluster of spectral classes O9-B8 plotted on the log L/L {sub ☉} versus log T {sub eff} diagram, together with the isochrones from the Padova database, give the age of the cluster as 5 ± 1 Myr.« less

A New GaAs Laser Radar for Atmospheric Measurements

NASA Technical Reports Server (NTRS)

Brown, R. T.; Stoliar, A. P.

1973-01-01

A special GaAs lidar using fiber coupled diode lasers was constructed for the purpose of measuring the extinction coefficient distribution within a large atmospheric volume at a rate compatible with atmospheric kinematics. The technique is based on taking backscatter signature ratios over spatial increments after the returns are normalized by pulse integration. Essential aspects of the lidar design are beam pulse power, repetition rate, detection system dynamic range and decay linearity. It was necessary to preclude the possibility of eye hazard under any operating conditions, including directly viewing the emitting aperture at close distance with a night-adapted eye. The electronic signal processing and control circuits were built to allow versatile operations. Extinction coefficient measurements were made in fog and clouds using a low-power laboratory version of the lidar, demonstrating feasibility. Data are presented showing range squared corrected backscatter profiles converted to extinction coefficient profiles, temporal signal fluctuations, and solar induced background noise. These results aided in the design of the lidar which is described. Functional tests of this lidar and the implications relevant to the design of a prototype model are discussed. This work was jointly sponsored by Sperry Rand Corporation under its Independent Research and Development program; the Air Force Avionics Laboratory, Wright Field, Dayton, Ohio; and the Naval Ammunition Depot, Crane, Indiana.

Cavity Ring-Down Measurement of Aerosol Optical Properties During the Asian Dust Above Monterey Experiment and DOE Aerosol Intensive Operating Period

NASA Technical Reports Server (NTRS)

Ricci, K.; Strawa, A. W.; Provencal, R.; Castaneda, R.; Bucholtz, A.; Schmid, B.

2004-01-01

Large uncertainties in the effects of aerosols on climate require improved in-situ measurements of extinction coefficient and single-scattering albedo. This paper describes preliminary results from Cadenza, a new continuous wave cavity ring-down (CW-CRD) instrument designed to address these uncertainties. Cadenza measures the aerosol extinction coefficient for 675 nm and 1550 nm light, and simultaneously measures the scattering coefficient at 675 nm. In the past year Cadenza was deployed in the Asian Dust Above Monterey (ADAM) and DOE Aerosol Intensive Operating Period (IOP) field projects. During these flights Cadenza produced measurements of aerosol extinction in the range from 0.2 to 300/Mm with an estimated precision of 0.1/Mm for 1550 nm light and 0.2/Mm for 675 nm light. Cadenza data from the ADAM and Aerosol IOP missions compared favorably with data from the other instruments aboard the CIRPAS Twin Otter aircraft and participating in those projects. We present comparisons between the Cadenza measurements and those from a TSI nephelometer, Particle Soot Absorption Photometer (PSAP), and the AATS 14 sun-photometer. Measurements of the optical properties of smoke and dust plumes sampled during these campaigns are presented and estimates of heating rates due to these plumes are made.

Cavity Ring-Down Measurement of Aerosol Optical Properties During the Asian Dust Above Monterey Experiment and DOE Aerosol Intensive Operating Period

NASA Astrophysics Data System (ADS)

Ricci, K.; Strawa, A. W.; Provencal, R.; Castaneda, R.; Bucholtz, A.; Schmid, B.

2003-12-01

Large uncertainties in the effects of aerosols on climate require improved in-situ measurements of extinction coefficient and single-scattering albedo. This paper describes preliminary results from Cadenza, a new continuous wave cavity ring-down (CW-CRD) instrument designed to address these uncertainties. Cadenza measures the aerosol extinction coefficient for 675 nm and 1550 nm light, and simultaneously measures the scattering coefficient at 675 nm. In the past year Cadenza was deployed in the Asian Dust Above Monterey (ADAM) and DOE Aerosol Intensive Operating Period (IOP) field projects. During these flights Cadenza produced measurements of aerosol extinction in the range from 0.2 to 300 Mm-1 with an estimated precision of 0.1 Mm-1 for 1550 nm light and 0.2 Mm-1 for 675 nm light. Cadenza data from the ADAM and Aerosol IOP missions compared favorably with data from the other instruments aboard the CIRPAS Twin Otter aircraft and participating in those projects. We present comparisons between the Cadenza measurements and those from a TSI nephelometer, Particle Soot Absorption Photometer (PSAP), and the AATS14 sun-photometer. Measurements of the optical properties of smoke and dust plumes sampled during these campaigns are presented and estimates of heating rates due to these plumes are made.

An analytical prediction of the oscillation and extinction thresholds of a clarinet

NASA Astrophysics Data System (ADS)

Dalmont, Jean-Pierre; Gilbert, Joël; Kergomard, Jean; Ollivier, Sébastien

2005-11-01

This paper investigates the dynamic range of the clarinet from the oscillation threshold to the extinction at high pressure level. The use of an elementary model for the reed-mouthpiece valve effect combined with a simplified model of the pipe assuming frequency independent losses (Raman's model) allows an analytical calculation of the oscillations and their stability analysis. The different thresholds are shown to depend on parameters related to embouchure parameters and to the absorption coefficient in the pipe. Their values determine the dynamic range of the fundamental oscillations and the bifurcation scheme at the extinction.

Properties of Ferrite Garnet (Bi, Lu, Y)3(Fe, Ga)5O12 Thin Film Materials Prepared by RF Magnetron Sputtering

PubMed Central

Nur-E-Alam, Mohammad; Belotelov, Vladimir; Alameh, Kamal

2018-01-01

This work is devoted to physical vapor deposition synthesis, and characterisation of bismuth and lutetium-substituted ferrite-garnet thin-film materials for magneto-optic (MO) applications. The properties of garnet thin films sputtered using a target of nominal composition type Bi0.9Lu1.85Y0.25Fe4.0Ga1O12 are studied. By measuring the optical transmission spectra at room temperature, the optical constants and the accurate film thicknesses can be evaluated using Swanepoel’s envelope method. The refractive index data are found to be matching very closely to these derived from Cauchy’s dispersion formula for the entire spectral range between 300 and 2500 nm. The optical absorption coefficient and the extinction coefficient data are studied for both the as-deposited and annealed garnet thin-film samples. A new approach is applied to accurately derive the optical constants data simultaneously with the physical layer thickness, using a combination approach employing custom-built spectrum-fitting software in conjunction with Swanepoel’s envelope method. MO properties, such as specific Faraday rotation, MO figure of merit and MO swing factor are also investigated for several annealed garnet-phase films. PMID:29789463

Optical and dielectric studies of KH2PO4 crystal influenced by organic ligand of citric acid and L-valine: A single crystal growth and comparative study

NASA Astrophysics Data System (ADS)

Anis, Mohd; Hakeem, D. A.; Muley, G. G.

In the present study pure, citric acid (CA) and L-valine (LV) doped potassium dihydrogen phosphate (KDP) crystals have been grown with the aim to investigate the nonlinear optical applications facilitated by UV-visible, third order nonlinear optical (TONLO) and dielectric properties. The structural parameters of grown crystals have been confirmed by single crystal X-ray diffraction analysis. The enhancement in optical transparency of KDP crystal due to addition of CA and LV has been examined within 200-900 nm by means of UV-visible spectral analysis. In addition, the transmittance data have been used to evaluate the effect of dopants on reflectance, refractive index and extinction coefficient of grown crystals in the visible region. The Z-scan analysis has been performed at 632.8 nm to identify the nature of photoinduced nonlinear refraction and nonlinear absorption in doped KDP crystals. The influence of π-bonded ligand of dopant CA and LV on TONLO susceptibility (χ3), refractive index (n2) and absorption coefficient (β) of KDP crystals has been evaluated to discuss laser assisted device applications. The decrease in dielectric constant and dielectric loss of KDP crystal due to addition of CA and LV has been explored using the temperature dependent dielectric studies.

Effect of 60Co γ-irradiation on structural and optical properties of thin films of Ga10Se80Hg10

NASA Astrophysics Data System (ADS)

Ahmad, Shabir; Asokan, K.; Shahid Khan, Mohd.; Zulfequar, M.

2015-08-01

Thin films of Ga10Se80Hg10 have been deposited onto a chemically cleaned Al2O3 substrates by thermal evaporation technique under vacuum. The investigated thin films are irradiated by 60Co γ-rays in the dose range of 50-150 kGy. X-ray diffraction patterns of the investigated thin films confirm the preferred crystallite growth occurs in the tetragonal phase structure. It also shows, the average crystallite size increases after γ-exposure, which indicates the crystallinity of the material increases after γ-irradiation. These results were further supported by surface morphological analysis carried out by scanning electron microscope and atomic force microscope which also shows the crystallinity of the material increases with increasing the γ-irradiation dose. The optical transmission spectra of the thin films at normal incidence were investigated in the spectral range from 190 to 1100 nm. Using the transmission spectra, the optical constants like refractive index (n) and extinction coefficient (k) were calculated based on Swanepoel's method. The optical band gap (Eg) was also estimated using Tauc's extrapolation procedure. The optical analysis shows: the value of optical band gap of investigated thin films decreases and the corresponding absorption coefficient increases continuously with increasing dose of γ-irradiation.

Optical-NIR dust extinction towards Galactic O stars

NASA Astrophysics Data System (ADS)

Maíz Apellániz, J.; Barbá, R. H.

2018-05-01

Context. O stars are excellent tracers of the intervening ISM because of their high luminosity, blue intrinsic SED, and relatively featureless spectra. We are currently conducting the Galactic O-Star Spectroscopic Survey (GOSSS), which is generating a large sample of O stars with accurate spectral types within several kpc of the Sun. Aims: We aim to obtain a global picture of the properties of dust extinction in the solar neighborhood based on optical-NIR photometry of O stars with accurate spectral types. Methods: We have processed a carefully selected photometric set with the CHORIZOS code to measure the amount [E(4405 - 5495)] and type [R5495] of extinction towards 562 O-type stellar systems. We have tested three different families of extinction laws and analyzed our results with the help of additional archival data. Results: The Maíz Apellániz et al. (2014, A&A, 564, A63) family of extinction laws provides a better description of Galactic dust that either the Cardelli et al. (1989, ApJ, 345, 245) or Fitzpatrick (1999, PASP, 111, 63) families, so it should be preferentially used when analysing samples similar to the one in this paper. In many cases O stars and late-type stars experience similar amounts of extinction at similar distances but some O stars are located close to the molecular clouds left over from their births and have larger extinctions than the average for nearby late-type populations. In qualitative terms, O stars experience a more diverse extinction than late-type stars, as some are affected by the small-grain-size, low-R5495 effect of molecular clouds and others by the large-grain-size, high-R5495 effect of H II regions. Late-type stars experience a narrower range of grain sizes or R5495, as their extinction is predominantly caused by the average, diffuse ISM. We propose that the reason for the existence of large-grain-size, high-R5495 regions in the ISM in the form of H II regions and hot-gas bubbles is the selective destruction of small dust grains by EUV photons and possibly by thermal sputtering by atoms or ions. Table 1 is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/613/A9

Helicopter-borne observations of the continental background aerosol in combination with remote sensing and ground-based measurements

NASA Astrophysics Data System (ADS)

Düsing, Sebastian; Wehner, Birgit; Seifert, Patric; Ansmann, Albert; Baars, Holger; Ditas, Florian; Henning, Silvia; Ma, Nan; Poulain, Laurent; Siebert, Holger; Wiedensohler, Alfred; Macke, Andreas

2018-01-01

This paper examines the representativeness of ground-based in situ measurements for the planetary boundary layer (PBL) and conducts a closure study between airborne in situ and ground-based lidar measurements up to an altitude of 2300 m. The related measurements were carried out in a field campaign within the framework of the High-Definition Clouds and Precipitation for Advancing Climate Prediction (HD(CP)2) Observational Prototype Experiment (HOPE) in September 2013 in a rural background area of central Europe.The helicopter-borne probe ACTOS (Airborne Cloud and Turbulence Observation System) provided measurements of the aerosol particle number size distribution (PNSD), the aerosol particle number concentration (PNC), the number concentration of cloud condensation nuclei (CCN-NC), and meteorological atmospheric parameters (e.g., temperature and relative humidity). These measurements were supported by the ground-based 3+2 wavelength polarization lidar system PollyXT, which provided profiles of the particle backscatter coefficient (σbsc) for three wavelengths (355, 532, and 1064 nm). Particle extinction coefficient (σext) profiles were obtained by using a fixed backscatter-to-extinction ratio (also lidar ratio, LR). A new approach was used to determine profiles of CCN-NC for continental aerosol. The results of this new approach were consistent with the airborne in situ measurements within the uncertainties.In terms of representativeness, the PNSD measurements on the ground showed a good agreement with the measurements provided with ACTOS for lower altitudes. The ground-based measurements of PNC and CCN-NC are representative of the PBL when the PBL is well mixed. Locally isolated new particle formation events on the ground or at the top of the PBL led to vertical variability in the cases presented here and ground-based measurements are not entirely representative of the PBL. Based on Mie theory (Mie, 1908), optical aerosol properties under ambient conditions for different altitudes were determined using the airborne in situ measurements and were compared with the lidar measurements. The investigation of the optical properties shows that on average the airborne-based particle light backscatter coefficient is 50.1 % smaller for 1064 nm, 27.4 % smaller for 532 nm, and 29.5 % smaller for 355 nm than the measurements of the lidar system. These results are quite promising, since in situ measurement-based Mie calculations of the particle light backscattering are scarce and the modeling is quite challenging. In contrast, for the particle light extinction coefficient we found a good agreement. The airborne-based particle light extinction coefficient was just 8.2 % larger for 532 nm and 3 % smaller for 355 nm, for an assumed LR of 55 sr. The particle light extinction coefficient for 1064 nm was derived with a LR of 30 sr. For this wavelength, the airborne-based particle light extinction coefficient is 5.2 % smaller than the lidar measurements. For the first time, the lidar ratio of 30 sr for 1064 nm was determined on the basis of in situ measurements and the LR of 55 sr for 355 and 532 nm wavelength was reproduced for European continental aerosol on the basis of this comparison. Lidar observations and the in situ based aerosol optical properties agree within the uncertainties. However, our observations indicate that a determination of the PNSD for a large size range is important for a reliable modeling of aerosol particle backscattering.

Observations of particle extinction, PM2.5 mass concentration profile and flux in north China based on mobile lidar technique

NASA Astrophysics Data System (ADS)

Lv, Lihui; Liu, Wenqing; Zhang, Tianshu; Chen, Zhenyi; Dong, Yunsheng; Fan, Guangqiang; Xiang, Yan; Yao, Yawei; Yang, Nan; Chu, Baolin; Teng, Man; Shu, Xiaowen

2017-09-01

Fine particle with diameter <2.5 μm (PM2.5) have important direct and indirect effects on human life and activities. However, the studies of fine particle were limited by the lack of monitoring data obtained with multiple fixed site sampling strategies. Mobile monitoring has provided a means for broad measurement of fine particles. In this research, the potential use of mobile lidar to map the distribution and transport of fine particles was discussed. The spatial and temporal distributions of particle extinction, PM2.5 mass concentration and regional transport flux of fine particle in the planetary boundary layer were investigated with the use of vehicle-based mobile lidar and wind field data from north China. Case studies under different pollution levels in Beijing were presented to evaluate the contribution of regional transport. A vehicle-based mobile lidar system was used to obtain the spatial and temporal distributions of particle extinction in the measurement route. Fixed point lidar and a particulate matter sampler were operated next to each other at the University of Chinese Academy of Science (UCAS) in Beijing to determine the relationship between the particle extinction coefficient and PM2.5 mass concentration. The correlation coefficient (R2) between the particle extinction coefficient and PM2.5 mass concentration was found to be over 0.8 when relative humidity (RH) was less than 90%. A mesoscale meteorological model, the Weather Research and Forecasting (WRF) model, was used to obtain profiles of the horizontal wind speed, wind direction and relative humidity. A vehicle-based mobile lidar technique was applied to estimate transport flux based on the PM2.5 profile and vertical profile of wind data. This method was applicable when hygroscopic growth can be neglected (relatively humidity<90%). Southwest was found to be the main pathway of Beijing during the experiments.

Observations of Sk-69 deg 203 and the interstellar extinction towards SN 1987A

NASA Technical Reports Server (NTRS)

Fitzpatrick, Edward L.; Walborn, Nolan R.

1990-01-01

Optical and UV spectroscopic observations of the Large Magellanic Cloud (LMC) star Sk-69 deg 203 are discussed. The optical data reveal Sk-69 deg 203 to be a BO.7 Ia supergiant with a moderate nitrogen enhancement, and its UV spectrum is consistent with this classification. UV interstellar extinction curves were constructed for the star using, as flux standards, two lightly reddened LMS supergiants, which bracket Sk-69 deg 203's spectral type. The resultant extinction curves are consistent with the extinction law derived previously for the 30 Doradus region, and the results for Sk-69 deg 203 suggest that the general 30 Doradus extinction law is appropriate for dereddening the observed fluxes of SN 1987A. Published H I 21 observations place SN 1987A in a region with a strong E-W gradient in the total hydrogen content. Comparison with the H I column density implied by the reddening indicates that the supernova is imbedded approximately in the middle of the main H I complex.

30 Doradus - Ultraviolet and optical stellar photometry

NASA Technical Reports Server (NTRS)

Hill, Jesse K.; Bohlin, Ralph C.; Cheng, Kwang-Ping; Fanelli, Michael N.; Hintzen, Paul; O'Connell, Robert W.; Roberts, Morton S.; Smith, Andrew M.; Smith, Eric P.; Stecher, Theodore P.

1993-01-01

Ultraviolet Imaging Telescope (UIT) UV magnitudes in four bands, together with optical B magnitudes, are presented for up to 314 early-type stars located in a 9.7 x 9.7 arcmin field centered on R136. The magnitudes have an rms uncertainty estimated at 0.10 mag from a comparison between the UIT magnitudes and the IUE spectra. Spectral types and E(B-V) color excesses are estimated. The mean color excesses following the two extinction curves agree well with the predictions of the two-component extinction model of Fitzpatrick and Savage (1984). However, the degree of nebular extinction is found to vary systematically by large amounts over the 30 Dor field. The minimum of nebular extinction in the central parts of the nebula suggests that dust has been expelled from this region by stellar winds. It is suggested that the form of the UV extinction curve can be understood as a consequence of the evolutionary state of the stellar population responsible for making the dust grains.

TM-pass polarizer based on multilayer graphene polymer waveguide

NASA Astrophysics Data System (ADS)

Cai, Ke-su; Li, Yue-e.; Wei, Wen-jing; Mu, Xi-jiao; Ma, A.-ning; Wang, Zhong; Song, Dan-ming

2018-05-01

A TM-pass polarizer based on multilayer graphene polymer waveguide is proposed and theoretically analyzed. The mode properties, the extinction ratio, the insertion loss and the bandwidth are also discussed. The results show that a TM-pass polarizer, which only guides the TM mode, can be achieved by multilayer graphene polymer waveguide. With length of 150 μm, the proposed polarizer can achieve extinction ratio of 33 dB and insertion loss of 0.5 dB at optical wavelength of 1.55 μm. This device has an excellent performance, including large extinction ratio and low insertion loss within the spectral range from 1.45 μm to 1.6 μm.

Spectral theory of extreme statistics in birth-death systems

NASA Astrophysics Data System (ADS)

Meerson, Baruch

2008-03-01

Statistics of rare events, or large deviations, in chemical reactions and systems of birth-death type have attracted a great deal of interest in many areas of science including cell biochemistry, astrochemistry, epidemiology, population biology, etc. Large deviations become of vital importance when discrete (non-continuum) nature of a population of ``particles'' (molecules, bacteria, cells, animals or even humans) and stochastic character of interactions can drive the population to extinction. I will briefly review the novel spectral method [1-3] for calculating the extreme statistics of a broad class of birth-death processes and reactions involving a single species. The spectral method combines the probability generating function formalism with the Sturm-Liouville theory of linear differential operators. It involves a controlled perturbative treatment based on a natural large parameter of the problem: the average number of particles/individuals in a stationary or metastable state. For extinction (the first passage) problems the method yields accurate results for the extinction statistics and for the quasi-stationary probability distribution, including the tails, of metastable states. I will demonstrate the power of the method on the example of a branching and annihilation reaction, A ->-2.8mm2mm2A,,A ->-2.8mm2mm , representative of a rather general class of processes. *M. Assaf and B. Meerson, Phys. Rev. Lett. 97, 200602 (2006). *M. Assaf and B. Meerson, Phys. Rev. E 74, 041115 (2006). *M. Assaf and B. Meerson, Phys. Rev. E 75, 031122 (2007).

Growth and characterization of barium complex of 1,3,5-triazinane-2,4,6-trione in gel: a corrosion inhibiting material

NASA Astrophysics Data System (ADS)

Divya, R.; Nair, Lekshmi P.; Bijini, B. R.; Nair, C. M. K.; Babu, K. Rajendra

2018-05-01

Good quality prismatic crystals of industrially applicable corrosion inhibiting barium complex of 1,3,5-triazinane-2,4,6-trione have been grown by conventional gel method. The crystal structure, packing, and nature of bonds are revealed in the single crystal X-ray diffraction analysis. The crystal has a three-dimensional polymeric structure having a triclinic crystal system with the space group P-1. The powder X-ray diffraction analysis confirms its crystalline nature. The functional groups present in the crystal are identified by Fourier transform infrared spectroscopy. Elemental analysis confirms the stoichiometry of the elements present in the complex. Thermogravimetric analysis and differential thermal analysis reveal its good thermal stability. The optical properties like band gap, refractive index and extinction coefficient are evaluated from the UV-visible spectral analysis. The singular property of the material, corrosion inhibition efficiency achieved by the adsorption of the sample molecules is determined by the weight loss method.

Photophysical properties of fluorescently-labeled peptoids.

PubMed

Rudat, Birgit; Birtalan, Esther; Vollrath, Sidonie B L; Fritz, Daniel; Kölmel, Dominik K; Nieger, Martin; Schepers, Ute; Müllen, Klaus; Eisler, Hans-Jürgen; Lemmer, Uli; Bräse, Stefan

2011-09-01

Fluorescently-labeled biomolecules are often utilized in biochemical or cellular experiments without further detailed spectroscopical characterization. This report is intended to narrow this gap and therefore presents the photophysical investigation of a library of 17 fluorescently-labeled molecules, namely peptoid transporters. First, one peptoid structure is labeled with seven different fluorophores and the spectroscopical properties are examined. Absorption and fluorescence maxima are almost identical for free dyes and conjugated dyes, suggesting free choice of a spectrally suitable fluorophore for different applications. Otherwise, extinction coefficients and quantum yields, and therefore the brightness of all seven dyes are strongly influenced. For the fluorophores, e.g. rhodamine B, the extent of this influence depends on the peptoid itself. This is shown by comparing different structures in the second part of this report. Especially the side chain functionalities influence the brightness. And finally, peptoids having two identical fluorescent labels are presented, which show decreased quantum yields. Possible reasons for the observed photophysical properties are discussed. Copyright © 2011 Elsevier Masson SAS. All rights reserved.

Spectroscopic and spectrofluorimetric studies on the interaction of albendazole and trimethoprim with iodine

NASA Astrophysics Data System (ADS)

Ganesh, K.; Elango, K. P.

Raman, UV-vis, FT-IR, and fluorescence spectral techniques were employed to investigate the mechanism of interaction of albendazole (ALB) and trimethoprim (TMP) drugs with iodine. Interactions of ALB and TMP with iodine yields triiodide ion and its formation was confirmed by electronic and Raman spectra. The peaks appeared in Raman spectra of the isolated products are at around 145, 113 and 82 cm-1 are assigned to νas(I-I), νs(I-I) and δ(I3-) respectively, confirmed the presence of I3- ion. Formation constant (K), molar extinction coefficient (ɛ) and thermodynamic properties ΔH#, ΔS# and ΔG# were determined and discussed. Fluorescence quenching studies indicated that the interaction between the ALB, TMP with iodine are spontaneous and the TMP-iodine interaction is found to be stronger than that the other system. Solvent variation studies indicated that the binding constant increased with an increase in polarity of the medium.

Synthesis and spectral characterization of environmentally responsive fluorescent deoxycytidine analogs

PubMed Central

Elmehriki, Adam AH; Suchý, Mojmír; Chicas, Kirby J; Wojciechowski, Filip; Hudson, Robert HE

2014-01-01

Herein, we describe the synthesis and spectroscopic properties of five novel pyrrolodeoxycytidine analogs, and the related 5-(1-pyrenylethynyl)-2’-deoxycytidine analog; as well as fluorescence characterization of 5-(p-methoxyphenylethynyl)-2’-deoxyuridine. Within this series of compounds, rigidification of the structure from 6-phenylpyrrolodeoxycytidine to 5,6-benzopyrroldeoxycytidine made remarkable improvement of the fluorescence quantum yield (Φ ~1, EtOH) and substantially increased the Stokes shift. Exchange of the phenyl group of 6-phenylpyrrolodeoxycytidine for other heterocycles (benzofuryl or indolyl) produced an increase in the extinction coefficient at the excitation wavelength while preserving high quantum yields. The steady-state fluorescence response to the environment was determined by sensitivity of Stokes shift to solvent polarity. The effect of solvent polarity on fluorescence emission intensity was concurrently examined and showed that 5,6-benzopyrrolodeoxycytidine is highly sensitive to the presence of water. On the other hand, the previously synthesized 5-(p-methoxyphenylethynyl)-2’-deoxyuridine was found to be sensitive to solvent viscosity indicating molecular rotor behavior. PMID:25483932

Efficient and robust method for simultaneous reconstruction of the temperature distribution and radiative properties in absorbing, emitting, and scattering media

NASA Astrophysics Data System (ADS)

Niu, Chun-Yang; Qi, Hong; Huang, Xing; Ruan, Li-Ming; Tan, He-Ping

2016-11-01

A rapid computational method called generalized sourced multi-flux method (GSMFM) was developed to simulate outgoing radiative intensities in arbitrary directions at the boundary surfaces of absorbing, emitting, and scattering media which were served as input for the inverse analysis. A hybrid least-square QR decomposition-stochastic particle swarm optimization (LSQR-SPSO) algorithm based on the forward GSMFM solution was developed to simultaneously reconstruct multi-dimensional temperature distribution and absorption and scattering coefficients of the cylindrical participating media. The retrieval results for axisymmetric temperature distribution and non-axisymmetric temperature distribution indicated that the temperature distribution and scattering and absorption coefficients could be retrieved accurately using the LSQR-SPSO algorithm even with noisy data. Moreover, the influences of extinction coefficient and scattering albedo on the accuracy of the estimation were investigated, and the results suggested that the reconstruction accuracy decreased with the increase of extinction coefficient and the scattering albedo. Finally, a non-contact measurement platform of flame temperature field based on the light field imaging was set up to validate the reconstruction model experimentally.

A New Reddening Law for M4

NASA Astrophysics Data System (ADS)

Hendricks, Benjamin; Stetson, Peter B.; VandenBerg, Don A.; Dall'Ora, Massimo

2012-07-01

We have used a combination of broadband near-infrared and optical Johnson-Cousins photometry to study the dust properties in the line of sight to the Galactic globular cluster M4. We have investigated the reddening effects in terms of absolute strength and variation across the cluster field, as well as the shape of the reddening law defined by the type of dust. All three aspects had been poorly defined for this system and, consequently, there has been controversy about the absolute distance to this globular cluster, which is closest to the Sun. Here, we determine the ratio of absolute to selective extinction (RV ) in the line of sight toward M4, which is known to be a useful indicator for the type of dust and therefore characterizes the applicable reddening law. Our method is independent of age assumptions and appears to be significantly more precise and accurate than previous approaches. We obtain AV /E(B - V) = 3.76 ± 0.07 (random error) for the dust in the line of sight to M4 for our set of filters. That corresponds to a dust-type parameter RV = 3.62 ± 0.07 in the Cardelli et al. reddening law. With this value, the distance to M4 is found to be 1.80 ± 0.05 kpc, corresponding to a true distance modulus of (m - M)0 = 11.28 ± 0.06 (random error). A reddening map for M4 has been created, which reveals a spatial differential reddening of δE(B - V) >= 0.2 mag across the field within 10' around the cluster center; this is about 50% of the total mean reddening, which we have determined to be E(B - V) = 0.37 ± 0.01. In order to provide accurate zero points for the extinction coefficients of our photometric filters, we investigated the impact of stellar parameters such as temperature, surface gravity, and metallicity on the extinction properties and the necessary corrections in different bandpasses. Using both synthetic ATLAS9 spectra and observed spectral energy distributions, we found similarly sized effects for the range of temperature and surface gravity typical of globular cluster stars: each causes a change of about 3% in the necessary correction factor for each filter combination. Interestingly, variations in the metallicity cause effects of the same order when the assumed value is changed from the solar metallicity ([Fe/H] = 0.0) to [Fe/H] = -2.5. The systematic differences between the reddening corrections for a typical main-sequence turnoff star in a metal poor globular cluster and a Vega-like star are even stronger (~5%). We compared the results from synthetic spectra to those obtained with observed spectral energy distributions and found significant differences for temperatures lower than ~5000 K. We have attributed these discrepancies to the inadequate treatment of some molecular bands in the B filter within the ATLAS9 models. Fortunately, these differences do not affect the principal astrophysical conclusions in this study, which are based on stars hotter than 5000 K. From our calculations, we provide extinction zero points for Johnson-Cousins and Two Micron All Sky Survey filters, spanning a wide range of stellar parameters and dust types. These extinction tables are suited for accurate, object-specific extinction corrections.

Planck 2013 results. IX. HFI spectral response

NASA Astrophysics Data System (ADS)

Planck Collaboration; Ade, P. A. R.; Aghanim, N.; Armitage-Caplan, C.; Arnaud, M.; Ashdown, M.; Atrio-Barandela, F.; Aumont, J.; Baccigalupi, C.; Banday, A. J.; Barreiro, R. B.; Battaner, E.; Benabed, K.; Benoît, A.; Benoit-Lévy, A.; Bernard, J.-P.; Bersanelli, M.; Bielewicz, P.; Bobin, J.; Bock, J. J.; Bond, J. R.; Borrill, J.; Bouchet, F. R.; Boulanger, F.; Bridges, M.; Bucher, M.; Burigana, C.; Cardoso, J.-F.; Catalano, A.; Challinor, A.; Chamballu, A.; Chary, R.-R.; Chen, X.; Chiang, H. C.; Chiang, L.-Y.; Christensen, P. R.; Church, S.; Clements, D. L.; Colombi, S.; Colombo, L. P. L.; Combet, C.; Comis, B.; Couchot, F.; Coulais, A.; Crill, B. P.; Curto, A.; Cuttaia, F.; Danese, L.; Davies, R. D.; de Bernardis, P.; de Rosa, A.; de Zotti, G.; Delabrouille, J.; Delouis, J.-M.; Désert, F.-X.; Dickinson, C.; Diego, J. M.; Dole, H.; Donzelli, S.; Doré, O.; Douspis, M.; Dupac, X.; Efstathiou, G.; Enßlin, T. A.; Eriksen, H. K.; Falgarone, E.; Finelli, F.; Forni, O.; Frailis, M.; Franceschi, E.; Galeotta, S.; Ganga, K.; Giard, M.; Giraud-Héraud, Y.; González-Nuevo, J.; Górski, K. M.; Gratton, S.; Gregorio, A.; Gruppuso, A.; Hansen, F. K.; Hanson, D.; Harrison, D.; Henrot-Versillé, S.; Hernández-Monteagudo, C.; Herranz, D.; Hildebrandt, S. R.; Hivon, E.; Hobson, M.; Holmes, W. A.; Hornstrup, A.; Hovest, W.; Huffenberger, K. M.; Hurier, G.; Jaffe, A. H.; Jaffe, T. R.; Jones, W. C.; Juvela, M.; Keihänen, E.; Keskitalo, R.; Kisner, T. S.; Kneissl, R.; Knoche, J.; Knox, L.; Kunz, M.; Kurki-Suonio, H.; Lagache, G.; Lamarre, J.-M.; Lasenby, A.; Laureijs, R. J.; Lawrence, C. R.; Leahy, J. P.; Leonardi, R.; Leroy, C.; Lesgourgues, J.; Liguori, M.; Lilje, P. B.; Linden-Vørnle, M.; López-Caniego, M.; Lubin, P. M.; Macías-Pérez, J. F.; Maffei, B.; Mandolesi, N.; Maris, M.; Marshall, D. J.; Martin, P. G.; Martínez-González, E.; Masi, S.; Massardi, M.; Matarrese, S.; Matthai, F.; Mazzotta, P.; McGehee, P.; Melchiorri, A.; Mendes, L.; Mennella, A.; Migliaccio, M.; Mitra, S.; Miville-Deschênes, M.-A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Munshi, D.; Murphy, J. A.; Naselsky, P.; Nati, F.; Natoli, P.; Netterfield, C. B.; Nørgaard-Nielsen, H. U.; North, C.; Noviello, F.; Novikov, D.; Novikov, I.; Osborne, S.; Oxborrow, C. A.; Paci, F.; Pagano, L.; Pajot, F.; Paoletti, D.; Pasian, F.; Patanchon, G.; Perdereau, O.; Perotto, L.; Perrotta, F.; Piacentini, F.; Piat, M.; Pierpaoli, E.; Pietrobon, D.; Plaszczynski, S.; Pointecouteau, E.; Polenta, G.; Ponthieu, N.; Popa, L.; Poutanen, T.; Pratt, G. W.; Prézeau, G.; Prunet, S.; Puget, J.-L.; Rachen, J. P.; Reinecke, M.; Remazeilles, M.; Renault, C.; Ricciardi, S.; Riller, T.; Ristorcelli, I.; Rocha, G.; Rosset, C.; Roudier, G.; Rusholme, B.; Santos, D.; Savini, G.; Scott, D.; Shellard, E. P. S.; Spencer, L. D.; Starck, J.-L.; Stolyarov, V.; Stompor, R.; Sudiwala, R.; Sureau, F.; Sutton, D.; Suur-Uski, A.-S.; Sygnet, J.-F.; Tauber, J. A.; Tavagnacco, D.; Terenzi, L.; Tomasi, M.; Tristram, M.; Tucci, M.; Umana, G.; Valenziano, L.; Valiviita, J.; Van Tent, B.; Vielva, P.; Villa, F.; Vittorio, N.; Wade, L. A.; Wandelt, B. D.; Yvon, D.; Zacchei, A.; Zonca, A.

2014-11-01

The Planck High Frequency Instrument (HFI) spectral response was determined through a series of ground based tests conducted with the HFI focal plane in a cryogenic environment prior to launch. The main goal of the spectral transmission tests was to measure the relative spectral response (includingthe level of out-of-band signal rejection) of all HFI detectors to a known source of electromagnetic radiation individually. This was determined by measuring the interferometric output of a continuously scanned Fourier transform spectrometer with all HFI detectors. As there is no on-board spectrometer within HFI, the ground-based spectral response experiments provide the definitive data set for the relative spectral calibration of the HFI. Knowledge of the relative variations in the spectral response between HFI detectors allows for a more thorough analysis of the HFI data. The spectral response of the HFI is used in Planck data analysis and component separation, this includes extraction of CO emission observed within Planck bands, dust emission, Sunyaev-Zeldovich sources, and intensity to polarization leakage. The HFI spectral response data have also been used to provide unit conversion and colour correction analysis tools. While previous papers describe the pre-flight experiments conducted on the Planck HFI, this paper focusses on the analysis of the pre-flight spectral response measurements and the derivation of data products, e.g. band-average spectra, unit conversion coefficients, and colour correction coefficients, all with related uncertainties. Verifications of the HFI spectral response data are provided through comparisons with photometric HFI flight data. This validation includes use of HFI zodiacal emission observations to demonstrate out-of-band spectral signal rejection better than 108. The accuracy of the HFI relative spectral response data is verified through comparison with complementary flight-data based unit conversion coefficients and colour correction coefficients. These coefficients include those based upon HFI observations of CO, dust, and Sunyaev-Zeldovich emission. General agreement is observed between the ground-based spectral characterization of HFI and corresponding in-flight observations, within the quoted uncertainty of each; explanations are provided for any discrepancies.

Designs and Materials for Better Coronagraph Occulting Masks

NASA Technical Reports Server (NTRS)

Balasubramanian, Kunjithapatham

2010-01-01

New designs, and materials appropriate for such designs, are under investigation in an effort to develop coronagraph occulting masks having broad-band spectral characteristics superior to those currently employed. These designs and materials are applicable to all coronagraphs, both ground-based and spaceborne. This effort also offers potential benefits for the development of other optical masks and filters that are required (1) for precisely tailored spatial transmission profiles, (2) to be characterized by optical-density neutrality and phase neutrality (that is, to be characterized by constant optical density and constant phase over broad wavelength ranges), and/or (3) not to exhibit optical- density-dependent phase shifts. The need for this effort arises for the following reasons: Coronagraph occulting masks are required to impose, on beams of light transmitted through them, extremely precise control of amplitude and phase according to carefully designed transmission profiles. In the original application that gave rise to this effort, the concern has been to develop broad-band occulting masks for NASA s Terrestrial Planet Finder coronagraph. Until now, experimental samples of these masks have been made from high-energy-beam-sensitive (HEBS) glass, which becomes locally dark where irradiated with a high-energy electron beam, the amount of darkening depending on the electron-beam energy and dose. Precise mask profiles have been written on HEBS glass blanks by use of electron beams, and the masks have performed satisfactorily in monochromatic light. However, the optical-density and phase profiles of the HEBS masks vary significantly with wavelength; consequently, the HEBS masks perform unsatisfactorily in broad-band light. The key properties of materials to be used in coronagraph occulting masks are their extinction coefficients, their indices of refraction, and the variations of these parameters with wavelength. The effort thus far has included theoretical predictions of performances of masks that would be made from alternative materials chosen because the wavelength dependences of their extinction coefficients and their indices of refraction are such that that the optical-density and phase profiles of masks made from these materials can be expected to vary much less with wavelength than do those of masks made from HEBS glass. The alternative materials considered thus far include some elemental metals such as Pt and Ni, metal alloys such as Inconel, metal nitrides such as TiN, and dielectrics such as SiO2. A mask as now envisioned would include thin metal and dielectric films having stepped or smoothly varying thicknesses (see figure). The thicknesses would be chosen, taking account of the indices of refraction and extinction coefficients, to obtain an acceptably close approximation of the desired spatial transmittance profile with a flat phase profile

Physical and Optical Properties of Falling Snow

DTIC Science & Technology

1989-07-01

ments with those measured with a transmissometer .................................. 19 24. HSS forward-scatter meter used for measuring extinction in...snowfall conditions, the different ge- ometries of the transmission systems and discrep- | 2• a 2 n(a) da ancies in the snow precipitation rate measure ...J0 ments. Bet = Ms. (27) Table 3. Relationships between measured fn(a) mn(a) da extinction coefficient and snow precipita- ion rate . 091 This

VLT/X-shooter GRBs: Individual extinction curves of star-forming regions★

NASA Astrophysics Data System (ADS)

Zafar, T.; Watson, D.; Møller, P.; Selsing, J.; Fynbo, J. PU; Schady, P.; Wiersema, K.; Levan, A. J.; Heintz, K. E.; Postigo, A. de Ugarte; D'Elia, V.; Jakobsson, P.; Bolmer, J.; Japelj, J.; Covino, S.; Gomboc, A.; Cano, Z.

2018-05-01

The extinction profiles in Gamma-Ray Burst (GRB) afterglow spectral energy distributions (SEDs) are usually described by the Small Magellanic Cloud (SMC)-type extinction curve. In different empirical extinction laws, the total-to-selective extinction, RV, is an important quantity because of its relation to dust grain sizes and compositions. We here analyse a sample of 17 GRBs (0.34

Optimal estimation retrieval of aerosol microphysical properties from SAGE~II satellite observations in the volcanically unperturbed lower stratosphere

NASA Astrophysics Data System (ADS)

Wurl, D.; Grainger, R. G.; McDonald, A. J.; Deshler, T.

2010-05-01

Stratospheric aerosol particles under non-volcanic conditions are typically smaller than 0.1 μm. Due to fundamental limitations of the scattering theory in the Rayleigh limit, these tiny particles are hard to measure by satellite instruments. As a consequence, current estimates of global aerosol properties retrieved from spectral aerosol extinction measurements tend to be strongly biased. Aerosol surface area densities, for instance, are observed to be about 40% smaller than those derived from correlative in situ measurements (Deshler et al., 2003). An accurate knowledge of the global distribution of aerosol properties is, however, essential to better understand and quantify the role they play in atmospheric chemistry, dynamics, radiation and climate. To address this need a new retrieval algorithm was developed, which employs a nonlinear Optimal Estimation (OE) method to iteratively solve for the monomodal size distribution parameters which are statistically most consistent with both the satellite-measured multi-wavelength aerosol extinction data and a priori information. By thus combining spectral extinction measurements (at visible to near infrared wavelengths) with prior knowledge of aerosol properties at background level, even the smallest particles are taken into account which are practically invisible to optical remote sensing instruments. The performance of the OE retrieval algorithm was assessed based on synthetic spectral extinction data generated from both monomodal and small-mode-dominant bimodal sulphuric acid aerosol size distributions. For monomodal background aerosol, the new algorithm was shown to fairly accurately retrieve the particle sizes and associated integrated properties (surface area and volume densities), even in the presence of large extinction uncertainty. The associated retrieved uncertainties are a good estimate of the true errors. In the case of bimodal background aerosol, where the retrieved (monomodal) size distributions naturally differ from the correct bimodal values, the associated surface area (A) and volume densities (V) are, nevertheless, fairly accurately retrieved, except at values larger than 1.0 μm2 cm-3 (A) and 0.05 μm3 cm-3 (V), where they tend to underestimate the true bimodal values. Due to the limited information content in the SAGE II spectral extinction measurements this kind of forward model error cannot be avoided here. Nevertheless, the retrieved uncertainties are a good estimate of the true errors in the retrieved integrated properties, except where the surface area density exceeds the 1.0 μm2 cm-3 threshold. When applied to near-global SAGE II satellite extinction measured in 1999 the retrieved OE surface area and volume densities are observed to be larger by, respectively, 20-50% and 10-40% compared to those estimates obtained by the SAGE~II operational retrieval algorithm. An examination of the OE algorithm biases with in situ data indicates that the new OE aerosol property estimates tend to be more realistic than previous estimates obtained from remotely sensed data through other retrieval techniques. Based on the results of this study we therefore suggest that the new Optimal Estimation retrieval algorithm is able to contribute to an advancement in aerosol research by considerably improving current estimates of aerosol properties in the lower stratosphere under low aerosol loading conditions.

A closer look at the physical and optical properties of gold nanostars: an experimental and computational study

DOE PAGES

Tsoulos, T. V.; Han, L.; Weir, J.; ...

2017-02-22

A combined experimental and computational study was carried out to design a semi-empirical method to determine the volume, surface area, and extinction coefficients of gold nanostars. The values obtained were confirmed by reconstructing the nanostar 3D topography through high-tilt TEM tomography and introducing the finite elements in COMSOL Multiphysics through which we have also calculated the morphology-dependent extinction coefficient. We have, for the first time, modeled the heat losses of a real, experimentally synthesized nanostar, and found the plasmon resonances to be in excellent agreement with those obtained experimentally. Furthermore, we believe that our approach could substantially improve the applicabilitymore » of this remarkable nanomaterial.« less

A closer look at the physical and optical properties of gold nanostars: an experimental and computational study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsoulos, T. V.; Han, L.; Weir, J.

A combined experimental and computational study was carried out to design a semi-empirical method to determine the volume, surface area, and extinction coefficients of gold nanostars. The values obtained were confirmed by reconstructing the nanostar 3D topography through high-tilt TEM tomography and introducing the finite elements in COMSOL Multiphysics through which we have also calculated the morphology-dependent extinction coefficient. We have, for the first time, modeled the heat losses of a real, experimentally synthesized nanostar, and found the plasmon resonances to be in excellent agreement with those obtained experimentally. Furthermore, we believe that our approach could substantially improve the applicabilitymore » of this remarkable nanomaterial.« less

Research on the peculiarity of optical parameters of atmospheric aerosol in Guangzhou coastal areas

NASA Astrophysics Data System (ADS)

Li, Shasha; Li, Xuebin; Zhang, Wenzhong; Bai, Shiwei; Liu, Qing; Zhu, Wenyue; Weng, Ningquan

2018-02-01

The long-term measurement of atmospheric aerosol is constructed via such equipment as visibility meter, optical particle counter, solar radiometer, automatic weather station, aerosol laser radar and aerosol scattering absorption coefficient measurer and so on during the year of 2010 and 2017 in the coastal areas of Guangzhou, China to study the optical parameter characteristics of atmospheric aerosol and establish the aerosol optical parameter mode in such areas. The effects of temperature and humidity on aerosol concentration, extinction and absorption coefficient are analyzed and the statistical characteristics of atmospheric temperature and humidity, visibility, extinction profiles and other parameters in different months are tallied, preliminarily establishing the atmospheric aerosol optical parameter pattern in Guangzhou coastal areas.

A Chronology of Annual-Mean Effective Radii of Stratospheric Aerosols from Volcanic Eruptions During the Twentieth Century as Derived From Ground-based Spectral Extinction Measurements

NASA Technical Reports Server (NTRS)

Strothers, Richard B.; Hansen, James E. (Technical Monitor)

2001-01-01

Stratospheric extinction can be derived from ground-based spectral photometric observations of the Sun and other stars (as well as from satellite and aircraft measurements, available since 1979), and is found to increase after large volcanic eruptions. This increased extinction shows a characteristic wavelength dependence that gives information about the chemical composition and the effective (or area weighted mean) radius of the particles responsible for it. Known to be tiny aerosols constituted of sulfuric acid in a water solution, the stratospheric particles at midlatitudes exhibit a remarkable uniformity of their column-averaged effective radii r(sub eff) in the first few months after the eruption. Considering the seven largest eruptions of the twentieth century, r(sub eff) at this phase of peak aerosol abundance is approx. 0.3 micrometers in all cases. A year later, r(sub eff) either has remained about the same size (almost certainly in the case of the Katmai eruption of 1912) or has increased to approx. 0.5 micrometers (definitely so for the Pinatubo eruption of 1991). The reasons for this divergence in aerosol growth are unknown.

A TALE OF TWO MYSTERIES IN INTERSTELLAR ASTROPHYSICS: THE 2175 A EXTINCTION BUMP AND DIFFUSE INTERSTELLAR BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiang, F. Y.; Zhong, J. X.; Li Aigen, E-mail: jxzhong@xtu.edu.cn, E-mail: lia@missouri.edu

2011-06-01

The diffuse interstellar bands (DIBs) are ubiquitous absorption spectral features arising from the tenuous material in the space between stars-the interstellar medium (ISM). Since their first detection nearly nine decades ago, over 400 DIBs have been observed in the visible and near-infrared wavelength range in both the Milky Way and external galaxies, both nearby and distant. However, the identity of the species responsible for these bands remains as one of the most enigmatic mysteries in astrophysics. An equally mysterious interstellar spectral signature is the 2175 A extinction bump, the strongest absorption feature observed in the ISM. Its carrier also remainsmore » unclear since its first detection 46 years ago. Polycyclic aromatic hydrocarbon (PAH) molecules have long been proposed as a candidate for DIBs as their electronic transitions occur in the wavelength range where DIBs are often found. In recent years, the 2175 A extinction bump is also often attributed to the {pi}-{pi}* transition in PAHs. If PAHs are indeed responsible for both the 2175 A extinction feature and DIBs, their strengths may correlate. We perform an extensive literature search for lines of sight for which both the 2175 A extinction feature and DIBs have been measured. Unfortunately, we found no correlation between the strength of the 2175 A feature and the equivalent widths of the strongest DIBs. A possible explanation might be that DIBs are produced by small free gas-phase PAH molecules and ions, while the 2175 A bump is mainly from large PAHs or PAH clusters in condensed phase so that there is no tight correlation between DIBs and the 2175 A bump.« less

Vertical Profiles of Aerosol Volume from High Spectral Resolution Infrared Transmission Measurements: Results

NASA Technical Reports Server (NTRS)

Eldering, Annmarie; Kahn, Brian H.; Mills, Franklin P.; Irion, Fredrick W.; Steele, Helen M.; Gunson, Michael R.

2004-01-01

The high-resolution infrared absorption spectra of the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment are utilized to derive vertical profiles of sulfate aerosol volume density and extinction coefficient. Following the eruption of Mt. Pinatubo in June 1991, the ATMOS spectra obtained on three Space Shuttle missions (1992, 1993, and 1994) provide a unique opportunity to study the global stratospheric sulfate aerosol layer shortly after a major volcanic eruption and periodically during the decay phase. Synthetic sulfate aerosol spectra are fit to the observed spectra, and a global fitting inversion routine is used to derive vertical profiles of sulfate aerosol volume density. Vertical profiles of sulfate aerosol volume density for the three missions over portions of the globe are presented, with the peak in aerosol volume density occurring from as low as 10 km (polar latitudes) to as high as 20 km (subtropical latitudes). Derived aerosol volume density is as high as 2-3.5 (mu)m(exp 3) per cubic centimeter +/-10% in 1992, decreasing to 0.2-0.5 (mu)m(exp 3) per cubic centimeter +/-20% in 1994, in agreement with other experiments. Vertical extinction profiles derived from ATMOS are compared with profiles from Improved Stratospheric And Mesospheric Sounder (ISAMS) and Cryogenic Limb Array Etalon Spectrometer (CLAES) that coincide in space and time and show good general agreement. The uncertainty of the ATMOS vertical profiles is similar to CLAES and consistently smaller than ISAMS at similar altitudes.

Spectral singularities of complex scattering potentials and infinite reflection and transmission coefficients at real energies.

PubMed

Mostafazadeh, Ali

2009-06-05

Spectral singularities are spectral points that spoil the completeness of the eigenfunctions of certain non-Hermitian Hamiltonian operators. We identify spectral singularities of complex scattering potentials with the real energies at which the reflection and transmission coefficients tend to infinity, i.e., they correspond to resonances having a zero width. We show that a waveguide modeled using such a potential operates like a resonator at the frequencies of spectral singularities. As a concrete example, we explore the spectral singularities of an imaginary PT-symmetric barrier potential and demonstrate the above resonance phenomenon for a certain electromagnetic waveguide.

Spectral Singularities of Complex Scattering Potentials and Infinite Reflection and Transmission Coefficients at Real Energies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mostafazadeh, Ali

2009-06-05

Spectral singularities are spectral points that spoil the completeness of the eigenfunctions of certain non-Hermitian Hamiltonian operators. We identify spectral singularities of complex scattering potentials with the real energies at which the reflection and transmission coefficients tend to infinity, i.e., they correspond to resonances having a zero width. We show that a waveguide modeled using such a potential operates like a resonator at the frequencies of spectral singularities. As a concrete example, we explore the spectral singularities of an imaginary PT-symmetric barrier potential and demonstrate the above resonance phenomenon for a certain electromagnetic waveguide.

Retrieval of atmospheric backscatter and extinction profiles with the aladin airborne demonstrator (A2D)

NASA Astrophysics Data System (ADS)

Geiss, Alexander; Marksteiner, Uwe; Lux, Oliver; Lemmerz, Christian; Reitebuch, Oliver; Kanitz, Thomas; Straume-Lindner, Anne Grete

2018-04-01

By the end of 2017, the European Space Agency (ESA) will launch the Atmospheric laser Doppler instrument (ALADIN), a direct detection Doppler wind lidar operating at 355 nm. An important tool for the validation and optimization of ALADIN's hardware and data processors for wind retrievals with real atmospheric signals is the ALADIN airborne demonstrator A2D. In order to be able to validate and test aerosol retrieval algorithms from ALADIN, an algorithm for the retrieval of atmospheric backscatter and extinction profiles from A2D is necessary. The A2D is utilizing a direct detection scheme by using a dual Fabry-Pérot interferometer to measure molecular Rayleigh signals and a Fizeau interferometer to measure aerosol Mie returns. Signals are captured by accumulation charge coupled devices (ACCD). These specifications make different steps in the signal preprocessing necessary. In this paper, the required steps to retrieve aerosol optical products, i. e. particle backscatter coefficient βp, particle extinction coefficient αp and lidar ratio Sp from A2D raw signals are described.

[1]Benzothieno[3,2-b]benzothiophene-Based Organic Dyes for Dye-Sensitized Solar Cells.

PubMed

Capodilupo, Agostina L; Fabiano, Eduardo; De Marco, Luisa; Ciccarella, Giuseppe; Gigli, Giuseppe; Martinelli, Carmela; Cardone, Antonio

2016-04-15

Three new metal-free organic dyes with the [1]benzothieno[3,2-b]benzothiophene (BTBT) π-bridge, having the structure donor-π-acceptor (D-π-A) and labeled as 19, 20 and 21, have been designed and synthesized for application in dye-sensitized solar cells (DSSC). Once the design of the π-acceptor block was fixed, containing the BTBT as the π-bridge and the cyanoacrylic group as the electron acceptor and anchoring unit, we selected three donor units with different electron-donor capacity, in order to assemble new chromophores with high molar extinction coefficients (ε), whose absorption features well reflect the good performance of the final DSSC devices. Starting with the 19 dye, which shows a molar extinction coefficient ε of over 14,000 M(-1) cm(-1) and takes into account the absorption maximun at the longer wavelength, the substitution of the BFT donor unit with the BFA yields a great enhancement of absorptivity (molar extinction coefficient ε > 42,000 M(-1) cm(-1)), until reaching the higher value (ε > 69,000 M(-1) cm(-1)) with the BFPhz donor unit. The good general photovoltaic performances obtained with the three dyes highlight the suitable properties of electron-transport of the BTBT as the π-bridge in organic chromophore for DSSC, making this very cheap and easy to synthesize molecule particularly attractive for efficient and low-cost photovoltaic devices.

Extrinsic extinction cross-section in the multiple acoustic scattering by fluid particles

NASA Astrophysics Data System (ADS)

Mitri, F. G.

2017-04-01

Cross-sections (and their related energy efficiency factors) are physical parameters used in the quantitative analysis of different phenomena arising from the interaction of waves with a particle (or multiple particles). Earlier works with the acoustic scattering theory considered such quadratic (i.e., nonlinear) quantities for a single scatterer, although a few extended the formalism for a pair of scatterers but were limited to the scattering cross-section only. Therefore, the standard formalism applied to viscous particles is not suitable for the complete description of the cross-sections and energy balance of the multiple-particle system because both absorption and extinction phenomena arise during the multiple scattering process. Based upon the law of the conservation of energy, this work provides a complete comprehensive analysis for the extrinsic scattering, absorption, and extinction cross-sections (i.e., in the far-field) of a pair of viscous scatterers of arbitrary shape, immersed in a nonviscous isotropic fluid. A law of acoustic extinction taking into consideration interparticle effects in wave propagation is established, which constitutes a generalized form of the optical theorem in multiple scattering. Analytical expressions for the scattering, absorption, and extinction cross-sections are derived for plane progressive waves with arbitrary incidence. The mathematical expressions are formulated in partial-wave series expansions in cylindrical coordinates involving the angle of incidence, the addition theorem for the cylindrical wave functions, and the expansion coefficients of the scatterers. The analysis shows that the multiple scattering cross-section depends upon the expansion coefficients of both scatterers in addition to an interference factor that depends on the interparticle distance. However, the extinction cross-section depends on the expansion coefficients of the scatterer located in a particular system of coordinates, in addition to the interference term. Numerical examples illustrate the analysis for two viscous fluid circular cylindrical cross-sections immersed in a non-viscous fluid. Computations for the (non-dimensional) scattering, absorption, and extinction cross-section factors are performed with particular emphasis on varying the angle of incidence, the interparticle distance, and the sizes, and the physical properties of the particles. A symmetric behavior is observed for the dimensionless multiple scattering cross-section, while asymmetries arise for both the dimensionless absorption and extinction cross-sections with respect to the angle of incidence. The present analysis provides a complete analytical and computational method for the prediction of cross-section and energy efficiency factors in multiple acoustic scattering of plane waves of arbitrary incidence by a pair of scatterers. The results can be used as a priori information in the direct or inverse characterization of multiple scattering systems such as acoustically engineered fluid metamaterials with reconfigurable periodicities, cloaking devices, liquid crystals, and other applications.

Applications of Sunphotometry to Aerosol Extinction and Surface Anisotropy

NASA Technical Reports Server (NTRS)

Tsay, S. C.; Holben, B. N.; Privette, J. L.

2005-01-01

Support cost-sharing of a newly developed sunphotometer in field deployment for aerosol studies. This is a cost-sharing research to deploy a newly developed sun-sky-surface photometer for studying aerosol extinction and surface anisotropy at the ARM SGP, TWP, and NSA-AAO CART sites and in many field campaigns. Atmospheric aerosols affect the radiative energy balance of the Earth, both directly by perturbing the incoming/outgoing radiation fields and indirectly by influencing the properties/processes of clouds and reactive greenhouse gases. The surface bidirectional reflectance distribution function (BRDF) also plays a crucial role in the radiative energy balance, since the BRDF is required to determine (1) the spectral and spectrally-averaged surface albedo, and (2) the top-of-the-atmosphere (TOA) angular distribution of radiance field. Therefore, the CART sites provide an excellent, albeit unique, opportunity to collect long-term climatic data in characterizing aerosol properties and various types of surface anisotropy.

A method for testing the spectraltransmittance of infrared smoke interference

NASA Astrophysics Data System (ADS)

Lei, Hao; Zhang, Yazhou; Wang, Guangping; Wu, Jingli

2018-02-01

Infrared smoke is mainly used for shielding, blind, deception and recognition on the battlefield. The traditional shelter smoke is mainly placed in the friendly positions or positions between the friendly positions and enemy positions, to reduce the enemy observation post investigative capacity. The passive interference capability of the smoke depends on the infrared extinction ability of the smoke. The infrared transmittance test is an objective and accurate representation of the extinction ability of the smoke. In this paper, a method for testing the spectral transmittance of infrared smoke interference is introduced. The uncertainty of the measurement results is analyzed. The results show that this method can effectively obtain the spectral transmittance of the infrared smoke and uncertainty of the measurement is 7.16%, which can be effective for the smoke detection, smoke composition analysis, screening effect evaluation to provide test parameters support.

Study of MPLNET-Derived Aerosol Climatology over Kanpur, India, and Validation of CALIPSO Level 2 Version 3 Backscatter and Extinction Products

NASA Technical Reports Server (NTRS)

Misra, Amit; Tripathi, S. N.; Kaul, D. S.; Welton, Ellsworth J.

2012-01-01

The level 2 aerosol backscatter and extinction profiles from the NASA Micropulse Lidar Network (MPLNET) at Kanpur, India, have been studied from May 2009 to September 2010. Monthly averaged extinction profiles from MPLNET shows high extinction values near the surface during October March. Higher extinction values at altitudes of 24 km are observed from April to June, a period marked by frequent dust episodes. Version 3 level 2 Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) aerosol profile products have been compared with corresponding data from MPLNET over Kanpur for the above-mentioned period. Out of the available backscatter profiles, the16 profiles used in this study have time differences less than 3 h and distances less than 130 km. Among these profiles, four cases show good comparison above 400 m with R2 greater than 0.7. Comparison with AERONET data shows that the aerosol type is properly identified by the CALIOP algorithm. Cloud contamination is a possible source of error in the remaining cases of poor comparison. Another source of error is the improper backscatter-to-extinction ratio, which further affects the accuracy of extinction coefficient retrieval.

Goodness of fit of probability distributions for sightings as species approach extinction.

PubMed

Vogel, Richard M; Hosking, Jonathan R M; Elphick, Chris S; Roberts, David L; Reed, J Michael

2009-04-01

Estimating the probability that a species is extinct and the timing of extinctions is useful in biological fields ranging from paleoecology to conservation biology. Various statistical methods have been introduced to infer the time of extinction and extinction probability from a series of individual sightings. There is little evidence, however, as to which of these models provide adequate fit to actual sighting records. We use L-moment diagrams and probability plot correlation coefficient (PPCC) hypothesis tests to evaluate the goodness of fit of various probabilistic models to sighting data collected for a set of North American and Hawaiian bird populations that have either gone extinct, or are suspected of having gone extinct, during the past 150 years. For our data, the uniform, truncated exponential, and generalized Pareto models performed moderately well, but the Weibull model performed poorly. Of the acceptable models, the uniform distribution performed best based on PPCC goodness of fit comparisons and sequential Bonferroni-type tests. Further analyses using field significance tests suggest that although the uniform distribution is the best of those considered, additional work remains to evaluate the truncated exponential model more fully. The methods we present here provide a framework for evaluating subsequent models.

Fractional-order Fourier analysis for ultrashort pulse characterization.

PubMed

Brunel, Marc; Coetmellec, Sébastien; Lelek, Mickael; Louradour, Frédéric

2007-06-01

We report what we believe to be the first experimental demonstration of ultrashort pulse characterization using fractional-order Fourier analysis. The analysis is applied to the interpretation of spectral interferometry resolved in time (SPIRIT) traces [which are spectral phase interferometry for direct electric field reconstruction (SPIDER)-like interferograms]. First, the fractional-order Fourier transformation is shown to naturally allow the determination of the cubic spectral phase coefficient of pulses to be analyzed. A simultaneous determination of both cubic and quadratic spectral phase coefficients of the pulses using the fractional-order Fourier series expansion is further demonstrated. This latter technique consists of localizing relative maxima in a 2D cartography representing decomposition coefficients. It is further used to reconstruct or filter SPIRIT traces.

[Light scattering extinction properties of atmospheric particle and pollution characteristics in hazy weather in Hangzhou].

PubMed

Xu, Chang; Ye, Hui; Shen, Jian-Dong; Sun, Hong-Liang; Hong, Sheng-Mao; Jiao, Li; Huang, Kan

2014-12-01

In order to evaluate the influence of particle scattering on visibility, light scattering coefficient, particle concentrations and meteorological factor were simultaneously monitored from July 2011 to June 2012 in Hangzhou. Daily scattering coefficients ranged from 108.4 to 1 098.1 Mm(-1), with an annual average concentration of 428.6 Mm(-1) ± 200.2 Mm(-1). Seasonal variation of scattering coefficients was significant, with the highest concentrations observed in autumn and winter and the lowest in summer. It was found there were two peaks for the average diurnal variations of the scattering coefficient, which could be observed at 08:00 and 21:00. The scattering efficiencies of PM2.5 and PM10 were 7.6 m2 x g(-1) and 4.4 m2 x g(-1), respectively. The particle scattering was about 90.2 percent of the total light extinction. The scattering coefficients were 684.4 Mm(-1) ± 218.1 Mm(-1) and 1 095.4 Mm(-1) ± 397.7 Mm(-1) in hazy and heavy hazy days, respectively, which were 2.6 and 4.2 times as high as in non-hazy weather, indicating that particle scattering is the main factor for visibility degradation and the occurrence of hazy weather in Hangzhou.

UV and fluorescence spectral changes induced by neodymium binding of N,N'-ethylenebis[2-(o-hydroxyphenolic)glycine] and N,N'-di(2-hydroxybenzyl)ethylenediamine-N,N' diacetic acid.

PubMed

Wang, Zhijun; Yang, Binsheng

2006-11-01

In 0.01 M 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid (Hepes), pH 7.4 and room temperature, the binding of neodymium to N,N'-ethylenebis[2-(o-hydroxyphenolic)glycine] (EHPG), or N,N'-di(2-hydroxybenzyl)ethylenediamine-N,N' diacetic acid (HBED) had been studied from 210 to 330 nm by means of difference UV spectra. Two peaks at 240 and 292 nm appear in difference UV spectra after neodymium binding to EHPG or HBED. The 1:1 stable complex can be confirmed from spectral titration curves. The molar extinction coefficient of Nd-EHPG and Nd-HBED complexes are Deltaepsilon(Nd-EHPG)=(12.93+/-0.21) x 10(3)cm(-1)M(-1), Deltaepsilon(Nd-HBED)=(14.45+/-0.51) x 10(5)cm(-1)M(-1) at 240 nm, respectively. Using EDTA as a competitor, the conditional equilibrium constants of the complexes are logK(Nd-EHPG)=11.89+/-0.09 and logK(Nd-HBED)=12.19+/-0.15, respectively. At the same conditions, fluorescence measurements show that neodymium binding to EHPG leads to a quenching of the fluorescence of EHPG at near 310 nm. However, there is no obvious fluorescence change of HBED at 318 nm with the binding of neodymium to HBED.

An interdisciplinary study of the estaurine and coastal oceanography of Block Island Sound and adjacent New York coastal waters

NASA Technical Reports Server (NTRS)

Yost, E.; Hollman, R.; Alexander, J.; Nuzzi, R.

1974-01-01

ERTS-1 photographic data products have been analyzed using additive color viewing and electronic image analysis techniques. Satellite data were compared to water sample data collected simultaneously with the data of ERTS-1 coverage in New York Bight. Prediction of the absolute value of total suspended particles can be made using composites of positives of MSS bands 5 and 6 which have been precisely made using the step wedge supplied on the imagery. Predictions of the relative value of the extinction coefficient can be made using bands 4 and 5. Thematic charts of total suspended particles (particles per litre) and extinction coefficient provide scientists conducting state and federal water sampling programs in New York Bight with data which improves the performance of these programs.

Theory of invasion extinction dynamics in minimal food webs

NASA Astrophysics Data System (ADS)

Haerter, Jan O.; Mitarai, Namiko; Sneppen, Kim

2018-02-01

When food webs are exposed to species invasion, secondary extinction cascades may be set off. Although much work has gone into characterizing the structure of food webs, systematic predictions on their evolutionary dynamics are still scarce. Here we present a theoretical framework that predicts extinctions in terms of an alternating sequence of two basic processes: resource depletion by or competitive exclusion between consumers. We first propose a conceptual invasion extinction model (IEM) involving random fitness coefficients. We bolster this IEM by an analytical, recursive procedure for calculating idealized extinction cascades after any species addition and simulate the long-time evolution. Our procedure describes minimal food webs where each species interacts with only a single resource through the generalized Lotka-Volterra equations. For such food webs ex- tinction cascades are determined uniquely and the system always relaxes to a stable steady state. The dynamics and scale invariant species life time resemble the behavior of the IEM, and correctly predict an upper limit for trophic levels as observed in the field.

Theory of invasion extinction dynamics in minimal food webs.

PubMed

Haerter, Jan O; Mitarai, Namiko; Sneppen, Kim

2018-02-01

When food webs are exposed to species invasion, secondary extinction cascades may be set off. Although much work has gone into characterizing the structure of food webs, systematic predictions on their evolutionary dynamics are still scarce. Here we present a theoretical framework that predicts extinctions in terms of an alternating sequence of two basic processes: resource depletion by or competitive exclusion between consumers. We first propose a conceptual invasion extinction model (IEM) involving random fitness coefficients. We bolster this IEM by an analytical, recursive procedure for calculating idealized extinction cascades after any species addition and simulate the long-time evolution. Our procedure describes minimal food webs where each species interacts with only a single resource through the generalized Lotka-Volterra equations. For such food webs ex- tinction cascades are determined uniquely and the system always relaxes to a stable steady state. The dynamics and scale invariant species life time resemble the behavior of the IEM, and correctly predict an upper limit for trophic levels as observed in the field.

Improved evaluation of optical depth components from Langley plot data

NASA Technical Reports Server (NTRS)

Biggar, S. F.; Gellman, D. I.; Slater, P. N.

1990-01-01

A simple, iterative procedure to determine the optical depth components of the extinction optical depth measured by a solar radiometer is presented. Simulated data show that the iterative procedure improves the determination of the exponent of a Junge law particle size distribution. The determination of the optical depth due to aerosol scattering is improved as compared to a method which uses only two points from the extinction data. The iterative method was used to determine spectral optical depth components for June 11-13, 1988 during the MAC III experiment.

Seasonal variability of dust in the eastern Mediterranean (Athens, Greece), through lidar measurements in the frame of EARLINET (2002-2012)

NASA Astrophysics Data System (ADS)

Kokkalis, Panos; Papayannis, Alex; Tsaknakis, George; Mamouri, RodElise; Argyrouli, Athina

2013-04-01

Aerosols play an important role in earth's atmospheric radiation balance, which is enhanced in areas where dust is mostly present (e.g. the Mediterranean region), as in the case of the city of Athens. The focus of this paper is to provide a comprehensive analysis of the seasonal variability of optical and geometrical properties, as well as the mass concentration of Saharan dust over the city of Athens, Greece, for a 10-years time period: 2002-2012 based on the laser remote sensing (lidar) technique. More specifically, the aerosol optical properties concern the extinction and the backscatter coefficient, as well as the lidar ratio, while the geometrical properties concern the dust layer thickness and center of mass. The calculations of the aerosol extinction coefficient and of the so-called lidar ratio (defined as the ratio of the aerosol extinction coefficient over the aerosol backscatter coefficient) are made by using the Raman lidar technique, only under cloud-free conditions. The calculation of the dust mass concentration was retrieved by a applying a conversion factor (the so-called dust extinction cross section; mean value of the order of 0.64 m2g-1) and by combining sun photometric measurements and modeled dust loading values. Our data analysis was based on monthly-mean values, and only in time periods under cloud-free conditions and for lidar signals with signal to noise ratios (SNR) greater than 1.5 under dusty conditions. The mean value of the lidar ratio at 355 nm was found to be 62±20sr, while the mean dust mass concentration was of the order of 240 μgm-3. The data analyzed were obtained by systematic aerosol lidar measurements performed by the EOLE Raman lidar system of the National Technical University of Athens (NTUA), in the frame of the European Aerosol Research Lidar network (EARLINET). EOLE is able to provide the vertical profiles of the aerosol backscatter (at 355, 532, 1064 nm) and extinction coefficients (at 355 and 532 nm), as well as the water vapor mixing ratio, from about 700 m up to 10000 m, with high temporal (< 5 min.) and spatial (7.5 m) resolution. Acknowledgements: This research has been co-financed by the European Union (European Social Fund - ESF) and Greek national funds through the Operational Program "Education and Lifelong Learning" of the National Strategic Reference Framework (NSRF) - Research Funding Program: Heracleitus II - Investing in knowledge society through the European Social Fund. This research was also financially supported by ITARS (www.itars.net), European Union Seventh Framework Programme (FP7/2007-2013): People, ITN Marie Curie Actions Programme (2012-2016) under grant agreement no 289923.

Evaluating Satellite Retrievals of Smoke Aerosol above Clouds using Airborne High Spectral Resolution Lidar Measurements during ORACLES

NASA Astrophysics Data System (ADS)

Ferrare, R. A.; Burton, S. P.; Cook, A. L.; Harper, D. B.; Hostetler, C. A.; Hair, J. W.; Vaughan, M.; Hu, Y.; Fenn, M. A.; Clayton, M.; Scarino, A. J.; Jethva, H. T.; Sayer, A. M.; Meyer, K.; Torres, O.; Josset, D. B.; Redemann, J.

2017-12-01

The NASA Langley Research Center airborne High Spectral Resolution Lidar (HSRL-2) provided extensive measurements of smoke above shallow marine clouds while deployed from the NASA ER-2 aircraft during the NASA EV-S Observations of Aerosols above Clouds and their Interactions (ORACLES) mission. During the first ORACLES field campaign in September 2016, the ER-2 was deployed from Walvis Bay, Namibia and conducted flights over the southeastern Atlantic Ocean. HSRL-2 measured profiles of aerosol backscattering, extinction and aerosol optical depth (AOD) at 355 and 532 nm and aerosol backscattering and depolarization at 1064 nm and so provided an excellent characterization of the widespread smoke layers above shallow marine clouds. OMI, MODIS, and CALIOP satellite retrievals of above cloud AOD (ACAOD) are compared to the HSRL-2 measurements. The OMI above-cloud aerosols data product (OMACA) ACAOD product relies on the spectral contrast produced by aerosol absorption in two near-UV measurements (354 and 388 nm) to derive ACAOD. Two MODIS ACAOD products are examined; the first ("multichannel') relies on the spectral contrast in aerosol absorption derived from reflectance measurements at six MODIS channels from the visible to the shortwave infrared (swIR). The second method is an extension of the "Deep Blue" method and differs from the multichannel method in that it does not use swIR channels. The CALIOP V4 operational and "depolarization ratio (DR)" methods of retrieving ACAOD are also examined. The MODIS and OMI ACAOD values were well correlated (r2>0.6) with the HSRL-2 ACAOD values; bias differences were generally less than about 0.1 at 532 nm (10-30%). The CALIOP operational retrievals missed a significant amount of aerosol and so were biased low by 50-75% compared to HSRL-2. In contrast, the CALIOP DR method produced ACAOD values in excellent agreement (bias differences less than 0.03 (5%)) with HSRL-2. Aerosol extinction profiles computed for the smoke layer using the CALIOP attenuated backscatter profiles and constrained by the CALIOP DR ACAOD retrievals are also found to agree well on average with coincident HSRL-2 extinction profiles. These constrained CALIOP extinction profiles are used to characterize the smoke distribution over this region.

In vivo imaging of scattering and absorption properties of exposed brain using a digital red-green-blue camera

NASA Astrophysics Data System (ADS)

Nishidate, Izumi; Yoshida, Keiichiro; Kawauchi, Satoko; Sato, Shunichi; Sato, Manabu

2014-03-01

We investigate a method to estimate the spectral images of reduced scattering coefficients and the absorption coefficients of in vivo exposed brain tissues in the range from visible to near-infrared wavelength (500-760 nm) based on diffuse reflectance spectroscopy using a digital RGB camera. In the proposed method, the multi-spectral reflectance images of in vivo exposed brain are reconstructed from the digital red, green blue images using the Wiener estimation algorithm. The Monte Carlo simulation-based multiple regression analysis for the absorbance spectra is then used to specify the absorption and scattering parameters of brain tissue. In this analysis, the concentration of oxygenated hemoglobin and that of deoxygenated hemoglobin are estimated as the absorption parameters whereas the scattering amplitude a and the scattering power b in the expression of μs'=aλ-b as the scattering parameters, respectively. The spectra of absorption and reduced scattering coefficients are reconstructed from the absorption and scattering parameters, and finally, the spectral images of absorption and reduced scattering coefficients are estimated. The estimated images of absorption coefficients were dominated by the spectral characteristics of hemoglobin. The estimated spectral images of reduced scattering coefficients showed a broad scattering spectrum, exhibiting larger magnitude at shorter wavelengths, corresponding to the typical spectrum of brain tissue published in the literature. In vivo experiments with exposed brain of rats during CSD confirmed the possibility of the method to evaluate both hemodynamics and changes in tissue morphology due to electrical depolarization.

CSI 2264: Simultaneous optical and X-ray variability in pre-main sequence stars. I. Time resolved X-ray spectral analysis during optical dips and accretion bursts in stars with disks

NASA Astrophysics Data System (ADS)

Guarcello, M. G.; Flaccomio, E.; Micela, G.; Argiroffi, C.; Sciortino, S.; Venuti, L.; Stauffer, J.; Rebull, L.; Cody, A. M.

2017-06-01

Context. Pre-main sequence stars are variable sources. The main mechanisms responsible for their variability are variable extinction, unsteady accretion, and rotational modulation of both hot and dark photospheric spots and X-ray-active regions. In stars with disks, this variability is related to the morphology of the inner circumstellar region (≤0.1 AU) and that of the photosphere and corona, all impossible to be spatially resolved with present-day techniques. This has been the main motivation for the Coordinated Synoptic Investigation of NGC 2264, a set of simultaneous observations of NGC 2264 with 15 different telescopes. Aims: In this paper, we focus on the stars with disks. We analyze the X-ray spectral properties extracted during optical bursts and dips in order to unveil the nature of these phenomena. Stars without disks are studied in a companion paper. Methods: We analyze simultaneous CoRoT and Chandra/ACIS-I observations to search for coherent optical and X-ray flux variability in stars with disks. Then, stars are analyzed in two different samples. In stars with variable extinction, we look for a simultaneous increase of optical extinction and X-ray absorption during the optical dips; in stars with accretion bursts, we search for soft X-ray emission and increasing X-ray absorption during the bursts. Results: We find evidence for coherent optical and X-ray flux variability among the stars with variable extinction. In 9 of the 24 stars with optical dips, we observe a simultaneous increase of X-ray absorption and optical extinction. In seven dips, it is possible to calculate the NH/AV ratio in order to infer the composition of the obscuring material. In 5 of the 20 stars with optical accretion bursts, we observe increasing soft X-ray emission during the bursts that we associate to the emission of accreting gas. It is not surprising that these properties are not observed in all the stars with dips and bursts, since favorable geometric configurations are required. Conclusions: The observed variable absorption during the dips is mainly due to dust-free material in accretion streams. In stars with accretion bursts, we observe, on average, a larger soft X-ray spectral component not observed in non-accreting stars.

Phase function, backscatter, extinction, and absorption for standard radiation atmosphere and El Chichon aerosol models at visible and near-infrared wavelengths

NASA Technical Reports Server (NTRS)

Whitlock, C. H.; Suttles, J. T.; Lecroy, S. R.

1985-01-01

Tabular values of phase function, Legendre polynominal coefficients, 180 deg backscatter, and extinction cross section are given for eight wavelengths in the atmospheric windows between 0.4 and 2.2 microns. Also included are single scattering albedo, asymmetry factor, and refractive indices. These values are based on Mie theory calculations for the standard rediation atmospheres (continental, maritime, urban, unperturbed stratospheric, volcanic, upper atmospheric, soot, oceanic, dust, and water-soluble) assest measured volcanic aerosols at several time intervals following the El Chichon eruption. Comparisons of extinction to 180 deg backscatter for different aerosol models are presented and related to lidar data.

International Laser Radar Conference (16th) held at the Massachusetts Institute of Technology, Cambridge, Massachusetts on 20-24 July 1992. Part 1

DTIC Science & Technology

1993-07-24

orders smaller than the Rayleigh cross section. We estimated the extinction coefficients of the Pinatubo volcanic aerosol in the stratosphere using a Raman...to a common aerosol parameter (e.g., backscatter coefficients at selected CO2 wavelengths), have all led to similar estimated values of that...increase only as -r 2 . During this phase, therefore, the backscatter coefficient of a coagulating aerosol population decreases as -r- The maximum

Measurement of tropospheric aerosol in São Paulo area using a new upgraded Raman LIDAR system

NASA Astrophysics Data System (ADS)

Landulfo, Eduardo; Rodrigues, Patrícia F.; da Silva Lopes, Fábio Juliano; Bourayou, Riad

2012-11-01

Elastic backscatter LIDAR systems have been used to determine aerosol profile concentration in several areas such as weather, pollution and air quality monitoring. In order to determine the aerosol extinction and backscattering profiles, the Klett inversion method is largely used, but this method suffers from lack of information since there are two unknown variables to be determined using only one measured LIDAR signal, and assumption of the LIDAR ratio (the relation between the extinction and backscattering coefficients) is needed. When a Raman LIDAR system is used, the inelastic backscattering signal is affected by aerosol extinction but not by aerosol backscatter, which allows this LIDAR to uniquely determine extinction and backscattering coefficients without any assumptions or any collocated instruments. The MSP-LIDAR system, set-up in a highly dense suburban area in the city of São Paulo, has been upgraded to a Raman LIDAR, and in its actual 6-channel configuration allows it to monitor elastic backscatter at 355 and 532 nm together with nitrogen and water vapor Raman backscatters at 387nm and 608 nm and 408nm and 660 nm, respectively. Thus, the measurements of aerosol backscattering, extinction coefficients and water vapor mixing ratio in the Planetary Boundary Layer (PBL) are becoming available. The system will provide the important meteorological parameters such as Aerosol Optical Depth (AOD) and will be used for the study of aerosol variations in lower troposphere over the city of São Paulo, air quality monitoring and for estimation of humidity impact on the aerosol optical properties, without any a priori assumption. This study will present the first results obtained with this upgraded LIDAR system, demonstrating the high quality of obtained aerosol and water vapor data. For that purpose, we compared the data obtained with the new MSP-Raman LIDAR with a mobile Raman LIDAR collocated at the Center for Lasers and Applications, Nuclear and Energy Research Institute in São Paulo and radiosonde data from Campo de Marte Airport, in São Paulo.

A spatially resolved radio spectral index study of the dwarf irregular galaxy NGC 1569

NASA Astrophysics Data System (ADS)

Westcott, Jonathan; Brinks, Elias; Hindson, Luke; Beswick, Robert; Heesen, Volker

2018-04-01

We study the resolved radio continuum spectral energy distribution of the dwarf irregular galaxy, NGC 1569, on a beam-by-beam basis to isolate and study its spatially resolved radio emission characteristics. Utilizing high-quality NRAO Karl G. Jansky Very Large Array observations that densely sample the 1-34 GHz frequency range, we adopt a Bayesian fitting procedure, where we use H α emission that has not been corrected for extinction as a prior, to produce maps of how the separated thermal emission, non-thermal emission, and non-thermal spectral index vary across NGC 1569's main disc. We find a higher thermal fraction at 1 GHz than is found in spiral galaxies (26^{+2}_{-3} {per cent}) and find an average non-thermal spectral index α = -0.53 ± 0.02, suggesting that a young population of cosmic ray electrons is responsible for the observed non-thermal emission. By comparing our recovered map of the thermal radio emission with literature H α maps, we estimate the total reddening along the line of sight to NGC 1569 to be E(B - V) = 0.49 ± 0.05, which is in good agreement with other literature measurements. Spatial variations in the reddening indicate that a significant portion of the total reddening is due to internal extinction within NGC 1569.

a Brief Climatology of Cirrus LIDAR Ratios Measured by High Spectral Resolution LIDAR

NASA Astrophysics Data System (ADS)

Kuehn, R.; Holz, R.; Hair, J. W.; Vaughan, M. A.; Eloranta, E. W.

2015-12-01

Our ability to detect and probe the vertical extent of cirrus was hugely improved with the launch of the NASA-CNES CALIPSO mission in April 2006. However, our skill at retrieving the optical properties of the cirrus detected by the CALIPSO lidar is not yet commensurate with our detection abilities. As with any new observing system, CALIPSO faces challenges and uncertainties in the retrieval of the geophysical parameters from its fundamental measurements. Specifically, extinction and optical depth retrievals for elastic backscatter lidars like CALIPSO typically rely on a priori assumptions about layer-mean extinction-to-backscatter ratios (AKA lidar ratios), which can vary regionally and for which uncertainties are high. To improve CALIPSO optical properties retrievals, we show High Spectral Resolution Lidar (HSRL) measurements acquired with systems from the University of Wisconsin and NASA Langley. HSRLs can directly determine ice cloud extinction and lidar ratio by separately measuring the molecular and particulate components of the total backscattered signal, thus largely eliminating many of the uncertainties inherent in elastic backscatter retrievals. These measurements were acquired during the SEAC4RS (Huntsville, AL, USA and Singapore), and FRAPPE/DISCOVER-AQ 2014 (BAO tower near Boulder, CO, USA) field campaigns, and an intensive operations period in Hampton, VA, USA.

A hybrid artificial bee colony algorithm and pattern search method for inversion of particle size distribution from spectral extinction data

NASA Astrophysics Data System (ADS)

Wang, Li; Li, Feng; Xing, Jian

2017-10-01

In this paper, a hybrid artificial bee colony (ABC) algorithm and pattern search (PS) method is proposed and applied for recovery of particle size distribution (PSD) from spectral extinction data. To be more useful and practical, size distribution function is modelled as the general Johnson's ? function that can overcome the difficulty of not knowing the exact type beforehand encountered in many real circumstances. The proposed hybrid algorithm is evaluated through simulated examples involving unimodal, bimodal and trimodal PSDs with different widths and mean particle diameters. For comparison, all examples are additionally validated by the single ABC algorithm. In addition, the performance of the proposed algorithm is further tested by actual extinction measurements with real standard polystyrene samples immersed in water. Simulation and experimental results illustrate that the hybrid algorithm can be used as an effective technique to retrieve the PSDs with high reliability and accuracy. Compared with the single ABC algorithm, our proposed algorithm can produce more accurate and robust inversion results while taking almost comparative CPU time over ABC algorithm alone. The superiority of ABC and PS hybridization strategy in terms of reaching a better balance of estimation accuracy and computation effort increases its potentials as an excellent inversion technique for reliable and efficient actual measurement of PSD.

The Development of a Tactical Dual-Wavelength Nephelometer.

DTIC Science & Technology

1982-11-24

Instrument Layout 50 4.5 Optical Systems 53 4.6 Electronic Systems 56 4.6.1 Transmitter System 56 4.6.2 Receiver Systems 58 5. R&D TEST AND ACCEPTANCE PLAN 61... PLAN , 136 HSS-B-086, 10 DEC1981. APPENDIX B ARVIN CALSPAN DOCUMENTATION OF 155 EXTINCTION AND PARTICLE SIZE MEASUREMENTS FOR CHAMBER TESTS OF MAY 1982. 6...121 FP’enn Aerosol Models. 8.9 Aerosol Extinction Coefficients at Two Wavelenghts 129 and their Ratio for Four Deirmendjian Aerosol Models. 10

A rapid approach for measuring silver nanoparticle concentration and dissolution in seawater by UV-Vis.

PubMed

Sikder, Mithun; Lead, Jamie R; Chandler, G Thomas; Baalousha, Mohammed

2018-03-15

Detection and quantification of engineered nanoparticles (NPs) in environmental systems is challenging and requires sophisticated analytical equipment. Furthermore, dissolution is an important environmental transformation process for silver nanoparticles (AgNPs) which affects the size, speciation and concentration of AgNPs in natural water systems. Herein, we present a simple approach for the detection, quantification and measurement of dissolution of PVP-coated AgNPs (PVP-AgNPs) based on monitoring their optical properties (extinction spectra) using UV-vis spectroscopy. The dependence of PVP-AgNPs extinction coefficient (ɛ) and maximum absorbance wavelength (λ max ) on NP size was experimentally determined. The concentration, size, and extinction spectra of PVP-AgNPs were characterized during dissolution in 30ppt synthetic seawater. AgNPs concentration was determined as the difference between the total and dissolved Ag concentrations measured by inductively coupled plasma-mass spectroscopy (ICP-MS); extinction spectra of PVP-AgNPs were monitored by UV-vis; and size evolution was monitored by atomic force microscopy (AFM) over a period of 96h. Empirical equations for the dependence of maximum absorbance wavelength (λ max ) and extinction coefficient (ɛ) on NP size were derived. These empirical formulas were then used to calculate the size and concentration of PVP-AgNPs, and dissolved Ag concentration released from PVP-AgNPs in synthetic seawater at variable particle concentrations (i.e. 25-1500μgL -1 ) and in natural seawater at particle concentration of 100μgL -1 . These results suggest that UV-vis can be used as an easy and quick approach for detection and quantification (size and concentration) of sterically stabilized PVP-AgNPs from their extinction spectra. This approach can also be used to monitor the release of Ag from PVP-AgNPs and the concurrent NP size change. Finally, in seawater, AgNPs dissolve faster and to a higher extent with the decrease in NP concentration toward environmentally relevant concentrations. Copyright © 2017 Elsevier B.V. All rights reserved.

Estimation of desert-dust-related ice nuclei profiles from polarization lidar

NASA Astrophysics Data System (ADS)

Mamouri, Rodanthi-Elisavet; Nisantzi, Argyro; Hadjimitsis, Diofantos; Ansmann, Albert

2015-04-01

This paper presents a methodology based on the use of active remote sensing techniques for the estimation of ice nuclei concentrations (INC) for desert dust plumes. Although this method can be applied to other aerosol components, in this study we focus on desert dust. The method makes use of the polarization lidar technique for the separation of dust and non-dust contributions to the particle backscatter and extinction coefficients. The profile of the dust extinction coefficient is converted to APC280 (dust particles with radius larger than 280 nm) and, in a second step, APC280 is converted to INC by means of an APC-INC relationship from the literature. The observed close relationship between dust extinction at 500 nm and APC280 is the key to a successful INC retrieval. The correlation between dust extinction coefficient and APC280 is studied by means of AERONET sun/sky photometer at Morocco, Cape Verde, Barbados, and Cyprus, during situations dominated by desert dust outbreaks. In the present study, polarization lidar observations of the EARLINET (European Aerosol Research Lidar Network) lidar at the Cyprus University of Technology (CUT), Limassol (34.7o N, 33o E), Cyprus were used together with spaceborne lidar observations during CALIPSO satellite overpasses to demonstrate the potential of the new INC retrieval method. A good agreement between the CALIOP (Cloud Aerosol Lidar with Orthogonal Polarization) and our CUT lidar observations regarding the retrieval of dust extinction coefficient, APC280, and INC profiles were found and corroborate the potential of CALIOP to provide 3-D global desert-dust-related INC data sets. In the next step, efforts should be undertaken towards the establishment of a global, height-resolved INC climatology for desert dust plumes. Realistic global INC distributions are required for an improved estimation of aerosol effects on cloud formation and the better quantification of the indirect aerosol effect on climate. Acknowledgements. The authors thank the CUT Remote Sensing Laboratory for their support. The research leading to these results has also received scientific support from the European Union Seventh Framework Programme (FP7/2011-2015) under grant agreement no. 262254 (ACTRIS project). We acknowledge funding from the EU FP7-ENV-2013 programme "impact of Biogenic vs. Anthropogenic emissions on Clouds and Climate: towards a Holistic UnderStanding" (BACCHUS), project no. 603445. We are grateful to AERONET for high-quality sun/sky photometer measurements in Cyprus, Morocco, Cape Verde, and Barbados. We thank the NASA Langley Research Center and the CALIPSO science team for the constant effort and improvement of then CALIPSO data.

Study of the amplified spontaneous emission spectral width and gain coefficient for a KrF laser in unsaturated and saturated conditions

NASA Astrophysics Data System (ADS)

Hariri, A.; Sarikhani, S.

2014-01-01

On the basis of a model of a geometrically dependent gain coefficient, the amplified spontaneous emission (ASE) spectral width was calculated analytically for the nearly resonant transition of ν ˜ ν0, and also numerically for a wide range of transition frequencies. For this purpose, the intensity rate equation was used under unsaturated and saturated conditions. For verifying the proposed model, reported measurements of the ASE energy versus the excitation length for a KrF laser were used. For the excitation length of l = 84 cm corresponding to single-path propagation, the ASE spectral width for the homogeneously broadened transition was calculated to be 6.28 Å, to be compared with the measured 4.1 Å spectral width reported for a KrF oscillator utilizing a two-mirror resonator. With the gain parameters obtained from the ASE energy measurements, the unsaturated and saturated gain coefficients for l = 84 cm were calculated to be 0.042 cm-1 and 0.014 cm-1, respectively. These values of the gain coefficient are comparable to but slightly lower than the measured gain coefficient for laser systems of 80-100 cm excitation lengths reported from different laboratories.

Effects of annealing on the optical, structural, and chemical properties of TiO2 and MgF2 thin films prepared by plasma ion-assisted deposition.

PubMed

Woo, Seouk-Hoon; Hwangbo, Chang Kwon

2006-03-01

Effects of thermal annealing at 400 degrees C on the optical, structural, and chemical properties of TiO2 single-layer, MgF2 single-layer, and TiO2/MgF2 narrow-bandpass filters deposited by conventional electron-beam evaporation (CE) and plasma ion-assisted deposition (PIAD) were investigated. In the case of TiO2 films, the results show that the annealing of both CE and PIAD TiO2 films increases the refractive index slightly and the extinction coefficient and surface roughness greatly. Annealing decreases the thickness of CE TiO2 films drastically, whereas it does not vary that of PIAD TiO2 films. For PIAD MgF2 films, annealing increases the refractive index and decreases the extinction coefficient drastically. An x-ray photoelectron spectroscopy analysis suggests that an increase in the refractive index and a decrease in the extinction coefficient for PIAD MgF2 films after annealing may be related to the enhanced concentration of MgO in the annealed PIAD MgF2 films and the changes in the chemical bonding states of Mg 2p, F 1s, and O is. It is found that (TiO2/MgF2) multilayer filters, consisting of PIAD TiO2 and CE MgF2 films, are as deposited without microcracks and are also thermally stable after annealing.

Polarization lidar for atmospheric monitoring

NASA Astrophysics Data System (ADS)

Liu, Qiaojun; Wu, Chengxuan; Yuk Sun Cheng, Andrew; Wang, Zhangjun; Meng, Xiangqian; Chen, Chao; Li, Xianxin; Liu, Xingtao; Zhang, Hao; Zong, Fangyi

2018-04-01

Aerosol plays an important role in global climate and weather changes. Polarization lidar captures parallel and perpendicular signals from atmosphere to research aerosols. The lidar system we used has three emission wavelengths and could obtain the atmospheric aerosol extinction coefficient, backscattering coefficient and depolarization ratio. In this paper, the design of the lidar is described. The methods of data acquisition and inversion are given. Some recent results are presented.

Evidence and mapping of extinction debts for global forest-dwelling reptiles, amphibians and mammals

NASA Astrophysics Data System (ADS)

Chen, Youhua; Peng, Shushi

2017-03-01

Evidence of extinction debts for the global distributions of forest-dwelling reptiles, mammals and amphibians was tested and the debt magnitude was estimated and mapped. By using different correlation tests and variable importance analysis, the results showed that spatial richness patterns for the three forest-dwelling terrestrial vertebrate groups had significant and stronger correlations with past forest cover area and other variables in the 1500 s, implying the evidence for extinction debts. Moreover, it was likely that the extinction debts have been partially paid, given that their global richness patterns were also significantly correlated with contemporary forest variables in the 2000 s (but the absolute magnitudes of the correlation coefficients were usually smaller than those calculated for historical forest variables). By utilizing species-area relationships, spatial extinction-debt magnitudes for the three vertebrate groups at the global scale were estimated and the hotspots of extinction debts were identified. These high-debt hotspots were generally situated in areas that did not spatially overlap with hotspots of species richness or high extinction-risk areas based on IUCN threatened status to a large extent. This spatial mismatch pattern suggested that necessary conservation efforts should be directed toward high-debt areas that are still overlooked.

Evidence and mapping of extinction debts for global forest-dwelling reptiles, amphibians and mammals.

PubMed

Chen, Youhua; Peng, Shushi

2017-03-16

Evidence of extinction debts for the global distributions of forest-dwelling reptiles, mammals and amphibians was tested and the debt magnitude was estimated and mapped. By using different correlation tests and variable importance analysis, the results showed that spatial richness patterns for the three forest-dwelling terrestrial vertebrate groups had significant and stronger correlations with past forest cover area and other variables in the 1500 s, implying the evidence for extinction debts. Moreover, it was likely that the extinction debts have been partially paid, given that their global richness patterns were also significantly correlated with contemporary forest variables in the 2000 s (but the absolute magnitudes of the correlation coefficients were usually smaller than those calculated for historical forest variables). By utilizing species-area relationships, spatial extinction-debt magnitudes for the three vertebrate groups at the global scale were estimated and the hotspots of extinction debts were identified. These high-debt hotspots were generally situated in areas that did not spatially overlap with hotspots of species richness or high extinction-risk areas based on IUCN threatened status to a large extent. This spatial mismatch pattern suggested that necessary conservation efforts should be directed toward high-debt areas that are still overlooked.

Growth, spectral and optical characterization of a novel nonlinear optical organic material: D-Alanine DL-Mandelic acid single crystal

NASA Astrophysics Data System (ADS)

Jayaprakash, P.; Mohamed, M. Peer; Caroline, M. Lydia

2017-04-01

An organic nonlinear optical single crystal, D-alanine DL-mandelic acid was synthesized and successfully grown by slow evaporation solution growth technique at ambient temperature using solvent of aqueous solution. The unit cell parameters were assessed from single crystal X-ray diffraction analysis. The presence of diverse functional groups and vibrational modes were identified using Fourier Transform Infra Red and Fourier Transform Raman spectral analyses. The chemical structure of grown crystal has been identified by Nuclear Magnetic Resonance spectroscopic study. Ultraviolet-visible spectral analysis reveal that the crystal has lower cut-off wavelength down to 259 nm, is a key factor to exhibit second harmonic generation signal. The electronic optical band gap and Urbach energy is calculated as 5.31 eV and 0.2425 eV respectively from the UV absorption profile. The diverse optical properties such as, extinction coefficient, reflectance, linear refractive index, optical conductivity was calculated using UV-visible data. The relative second harmonic efficiency of the compound is found to be 0.81 times greater than that of KH2PO4 (KDP). The thermal stability of the grown crystal was studied by thermogravimetric analysis and differential thermal analysis techniques. The luminescence spectrum exhibited two peaks (520 nm, 564 nm) due to the donation of protons from carboxylic acid to amino group. The Vickers microhardness test was carried out employing one of the as-grown hard crystal and there by hardness number (Hv), Meyer's index (n), yield strength (σy), elastic stiffness constant (C11) and Knoop hardness number (HK) were assessed. The dielectric behaviour of the as-grown crystal was analyzed for different temperatures (313 K, 333 K, 353 K, and 373 K) at different frequencies.

Multispectral imaging of absorption and scattering properties of in vivo exposed rat brain using a digital red-green-blue camera.

PubMed

Yoshida, Keiichiro; Nishidate, Izumi; Ishizuka, Tomohiro; Kawauchi, Satoko; Sato, Shunichi; Sato, Manabu

2015-05-01

In order to estimate multispectral images of the absorption and scattering properties in the cerebral cortex of in vivo rat brain, we investigated spectral reflectance images estimated by the Wiener estimation method using a digital RGB camera. A Monte Carlo simulation-based multiple regression analysis for the corresponding spectral absorbance images at nine wavelengths (500, 520, 540, 560, 570, 580, 600, 730, and 760 nm) was then used to specify the absorption and scattering parameters of brain tissue. In this analysis, the concentrations of oxygenated hemoglobin and that of deoxygenated hemoglobin were estimated as the absorption parameters, whereas the coefficient a and the exponent b of the reduced scattering coefficient spectrum approximated by a power law function were estimated as the scattering parameters. The spectra of absorption and reduced scattering coefficients were reconstructed from the absorption and scattering parameters, and the spectral images of absorption and reduced scattering coefficients were then estimated. In order to confirm the feasibility of this method, we performed in vivo experiments on exposed rat brain. The estimated images of the absorption coefficients were dominated by the spectral characteristics of hemoglobin. The estimated spectral images of the reduced scattering coefficients had a broad scattering spectrum, exhibiting a larger magnitude at shorter wavelengths, corresponding to the typical spectrum of brain tissue published in the literature. The changes in the estimated absorption and scattering parameters during normoxia, hyperoxia, and anoxia indicate the potential applicability of the method by which to evaluate the pathophysiological conditions of in vivo brain due to the loss of tissue viability.

Quantitative determination of band distortions in diamond attenuated total reflectance infrared spectra.

PubMed

Boulet-Audet, Maxime; Buffeteau, Thierry; Boudreault, Simon; Daugey, Nicolas; Pézolet, Michel

2010-06-24

Due to its unmatched hardness and chemical inertia, diamond offers many advantages over other materials for extreme conditions and routine analysis by attenuated total reflection (ATR) infrared spectroscopy. Its low refractive index can offer up to a 6-fold absorbance increase compared to germanium. Unfortunately, it also results for strong bands in spectral distortions compared to transmission experiments. The aim of this paper is to present a methodological approach to determine quantitatively the degree of the spectral distortions in ATR spectra. This approach requires the determination of the optical constants (refractive index and extinction coefficient) of the investigated sample. As a typical example, the optical constants of the fibroin protein of the silk worm Bombyx mori have been determined from the polarized ATR spectra obtained using both diamond and germanium internal reflection elements. The positions found for the amide I band by germanium and diamond ATR are respectively 6 and 17 cm(-1) lower than the true value dtermined from the k(nu) spectrum, which is calculated to be 1659 cm(-1). To determine quantitatively the effect of relevant parameters such as the film thickness and the protein concentration, various spectral simulations have also been performed. The use of a thinner film probed by light polarized in the plane of incidence and diluting the protein sample can help in obtaining ATR spectra that are closer to their transmittance counterparts. To extend this study to any system, the ATR distortion amplitude has been evaluated using spectral simulations performed for bands of various intensities and widths. From these simulations, a simple empirical relationship has been found to estimate the band shift from the experimental band height and width that could be of practical use for ATR users. This paper shows that the determination of optical constants provides an efficient way to recover the true spectrum shape and band frequencies of distorted ATR spectra.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barbosa, C. L.; Blum, R. D.; Damineli, A.

In this paper we present the results of a mid-infrared study of G49.5-0.4, or W51A, part of the massive starbirth complex W51. Combining public data from the Spitzer IRAC camera, and Gemini mid-infrared camera T-ReCS at 7.73, 9.69, 12.33, and 24.56 μ m, with a spatial resolution of ∼0.″5, we have identified the mid-infrared counterparts of eight ultracompact H ii regions, showing that two radio sources are deeply embedded in molecular clouds and another is a cloud of ionized gas. From the T-ReCS data we have unveiled the central core of the W51 region, revealing massive young stellar candidates. Wemore » modeled the spectral energy distribution of the detected sources. The results suggest that the embedded objects are sources with spectral types ranging from B3 to O5, but the majority of the fits indicate stellar objects with B1 spectral types. We also present an extinction map of IRS 2, showing that a region with lower extinction corresponds to the region where a proposed jet of gas has impacted the foreground cloud. From this map, we also derived the total extinction toward the enigmatic source IRS 2E, which amounts to ∼60 mag in the V band. We calculated the color temperature due to thermal emission of the circumstellar dust of the detected sources; the temperatures are in the interval of ∼100–150 K, which corresponds to the emission of dust located at 0.1 pc from the central source. Finally, we show a possible mid-infrared counterpart of a detected source at millimeter wavelengths that was found by Zapata et al. to be a massive young stellar object undergoing a high accretion rate.« less

The Pan-STARRS1 Proper-motion Survey for Young Brown Dwarfs in Nearby Star-forming Regions. I. Taurus Discoveries and a Reddening-free Classification Method for Ultracool Dwarfs

NASA Astrophysics Data System (ADS)

Zhang, Zhoujian; Liu, Michael C.; Best, William M. J.; Magnier, Eugene A.; Aller, Kimberly M.; Chambers, K. C.; Draper, P. W.; Flewelling, H.; Hodapp, K. W.; Kaiser, N.; Kudritzki, R.-P.; Metcalfe, N.; Wainscoat, R. J.; Waters, C.

2018-05-01

We are conducting a proper-motion survey for young brown dwarfs in the Taurus-Auriga molecular cloud based on the Pan-STARRS1 3π Survey. Our search uses multi-band photometry and astrometry to select candidates, and is wider (370 deg2) and deeper (down to ≈3 M Jup) than previous searches. We present here our search methods and spectroscopic follow-up of our high-priority candidates. Since extinction complicates spectral classification, we have developed a new approach using low-resolution (R ≈ 100) near-infrared spectra to quantify reddening-free spectral types, extinctions, and gravity classifications for mid-M to late-L ultracool dwarfs (≲100–3 M Jup in Taurus). We have discovered 25 low-gravity (VL-G) and the first 11 intermediate-gravity (INT-G) substellar (M6–L1) members of Taurus, constituting the largest single increase of Taurus brown dwarfs to date. We have also discovered 1 new Pleiades member and 13 new members of the Perseus OB2 association, including a candidate very wide separation (58 kau) binary. We homogeneously reclassify the spectral types and extinctions of all previously known Taurus brown dwarfs. Altogether our discoveries have thus far increased the substellar census in Taurus by ≈40% and added three more L-type members (≲5–10 M Jup). Most notably, our discoveries reveal an older (>10 Myr) low-mass population in Taurus, in accord with recent studies of the higher-mass stellar members. The mass function appears to differ between the younger and older Taurus populations, possibly due to incompleteness of the older stellar members or different star formation processes.

Anomalous optical scattering from intersecting fine particles

NASA Astrophysics Data System (ADS)

Paley, Alina V.; Radchik, Alex V.; Smith, Geoffrey B.

1995-09-01

There are many areas of science and technology where the scattering of electromagnetic waves by clusters or merging particles are of interest. The merging particles under study might be inclusions in high-density composites, liquid drops, biological cells, macroscopic ceramic particles, etc. As intersecting particles are bounded by a complex physical surface, the problem of scattering from these particles valid for any degree of merging, including touching, and for arbitrary materials of the constituents, has received limited attention. Here we present solutions which are valid and exact in the long wavelength limit compared with the size of intersecting spherical particles and cardioidal particles of similar dimensions. Both shapes are almost coincident everywhere except in the region of intersection. We treat the case when the waves are polarized along the common axis (longitudinal field). The solutions of Laplace's equation are integrals (spheres) or sums (cardioids) over continuous or discrete eigenvalue spectra respectively. The spectral dependencies of the resulting extinction coefficients and the scattering for the spherical and cardioidal particles are quite distinct. There is an enormous difference in the magnitude of absorption responses. Overall the cardioidal particle behaves as if it is almost invisible in terms of effects on the external field for a very broad band of optical frequencies. THe latter result was checked for a number of dielectric permittivities and seems to be universal. It scatters far more weakly than the isolated sphere. In constrast the intersecting sphere has an extinction band which is broad and is much enhanced at longer wavelegnths relative to the simple sphere. This result has significant implications for the design of surfaces with minimum scattering.

High spectral resolution lidar at the university of wisconsin-madison

NASA Astrophysics Data System (ADS)

Razenkov, Ilya I.; Eloranta, Edwin W.

2018-04-01

This paper describes the modifications done on the University of Wisconsin-Madison High Spectral Resolution Lidar (HSRL) that improved the instrument's performance. The University of Wisconsin HSRL lidars designed by our group at the Space Science and Engineering Center were deployed in numerous field campaigns in various locations around the world. Over the years the instruments have undergone multiple modifications that improved the performance and added new measurement capabilities such as atmospheric temperature profile and extinction cross-section measurements.

Polarizing beam splitter based on the anisotropic spectral reflectivity characteristic of form-birefringent multilayer gratings.

PubMed

Tyan, R C; Sun, P C; Scherer, A; Fainman, Y

1996-05-15

We introduce a novel polarizing beam splitter that uses the anisotropic spectral reflectivity (ASR) characteristic of a high-spatial-frequency multilayer binary grating. Such ASR effects allow us to design an optical element that is transparent for TM polarization and reflective for TE polarization. For normally incident light our element acts as a polarization-selective mirror. The properties of this polarizing beam splitter are investigated with rigorous coupled-wave analysis. The design results show that an ASR polarizing beam splitter can provide a high polarization extinction ratio for optical waves from a wide range of incident angles and a broad optical spectral bandwidth.

Visible/Infrared Optical Depths of Cirrus as Seen by Satellite and Scanning Lidar

NASA Technical Reports Server (NTRS)

Wylie, Donald; Wolf, Walt; Piironen, Paivi; Eloranta, Edwin

1996-01-01

The High Spectral Resolution Lidar (HSRL) and the Volume Imaging Lidar (VIL) were combined to produce a quantitative image of the visible optical depth of cirrus clouds. The HSRL was used to calibrate the VIL signal into backscatter cross sections of particulates. The backscatter cross sections were related to extinction by a constant backscatter phase function determined from the HSRL data. This produced a three dimensional image of visual extinction in the cirrus clouds over a one hour period. Two lidar images were constructed from one hour VIL cross section records.

Measurements of the vertical profile of water vapor abundance in the Martian atmosphere from Mars Observer

NASA Technical Reports Server (NTRS)

Schofield, J. T.; Mccleese, Daniel J.

1988-01-01

An analysis is presented of the Pressure Modulator Infrared Radiometer (PMIRR) capabilities along with how the vertical profiles of water vapor will be obtained. The PMIRR will employ filter and pressure modulation radiometry using nine spectral channels, in both limb scanning and nadir sounding modes, to obtain daily, global maps of temperature, dust extinction, condensate extinction, and water vapor mixing ratio profiles as a function of pressure to half scale height or 5 km vertical resolution. Surface thermal properties will also be mapped, and the polar radiactive balance will be monitored.

Data bank of optical properties of biological tissue and blood in the visible and near infrared spectral region

NASA Astrophysics Data System (ADS)

Khairullina, Alphiya Y.; Bui, Lilia; Oleinik, Tatiana V.; Artishevsky, Nelli; Prigoun, Natalia; Sevkovsky, Jakov; Mokhort, Tatiana

1996-12-01

The data bank contains optical, ordinary biochemical and biophysical information on 120 venous blood samples of donors, healthy persons, patients with high pathology, 60 tissue samples. The optical parameters include diffuse reflection R((lambda) ) and transmission T((lambda) ) coefficients for optically thick layers, the absorption K((lambda) ) and extinction (epsilon) ((lambda) ) spectra, oxygenation degree CO2, parameter p determined by sizes and shapes of cells and their aggregates, refractive index of a disperse phase relative to surrounding media, and cooperative effects at high relative concentration. The peculiarities in absorption K((lambda) spectra are connected with different pathologies. It is shown from K((lambda) ) that the grade of pathology connected with the concentration of hemoglobin and mithohondrion together with oxygenation degree of blood and tissues, with the pathological hemoglobin's forms and its decomposition products of different levels. Parameter p is an important diagnostic parameter. We consider that it is necessary to include the oxygenation degree and erythrocyte's aggregation parameter to extend the range of common diagnostic parameters of blood by the first rota.

Optical and Photophysical Investigation of (2E)-1-(2,5-Dimethylfuran-3-Yl)-3-(9-Ethyl-9H-Carbazol-3-Yl)Prop-2-en-1-One (DEPO) by Spectrofluorometer in Organized Medium.

PubMed

Asiri, Abdullah M; Al-Dies, Al-Anood M; Khan, Salman A

2017-07-01

(2E)-1-(2,5-dimethylfuran-3-yl)-3-(9-ethyl-9H-carbazol-3-yl)prop-2-en-1-one (DEPO) was prepared by the reaction of 9-ethyl-9H-carbazole-3-carbaldehyde with 1-(2,5-dimethylfuran-3-yl)ethanone under microwave irradiation. The structure of DEPO was established experimentally by EI-MS, FT-IR, 1 H and 13 C NMR spectral studies. Electronic absorption and emission spectra of DEPO were studied in different solvents on the basis of polarities, and the obtain data were used to determine the solvatochromic properties such as extinction coefficient, oscillator strength, transition dipole moment, stokes shift, fluorescence quantum yield and photochemical quantum yield. Photochemical quantum yield (Φ c ) of DEPO dye was determined in different solvent. The dye comparatively photostable in DMSO but undergoes photodecomposition in chloro methane solvents. The DEPO dye may be use as probe or quencher to determine critical micelle concentration (CMC) of cetyltri methyl ammonium bromide (CTAB) and sodium dodecyl sulfate (SDS).

A novel structure of gel grown strontium cyanurate crystal and its structural, optical, electrical characterization

NASA Astrophysics Data System (ADS)

Divya, R.; Nair, Lekshmi P.; Bijini, B. R.; Nair, C. M. K.; Gopakumar, N.; Babu, K. Rajendra

2017-12-01

Strontium cyanurate crystals with novel structure and unique optical property like mechanoluminescence have been grown by conventional gel method. Transparent crystals were obtained. The single crystal X-ray diffraction analysis reveals the exquisite structure of the grown crystal. The crystal is centrosymmetric and has a three dimensional polymeric structure. The powder X ray diffraction analysis confirms its crystalline nature. The functional groups present in the crystal were identified by Fourier transform infrared spectroscopy. Elemental analysis confirmed the composition of the complex. A study of thermal properties was done by thermo gravimetric analysis and differential thermal analysis. The optical properties like band gap, refractive index and extinction coefficient were evaluated from the UV visible spectral analysis. The etching study was done to reveal the dislocations in the crystal which in turn explains mechanoluminescence emission. The mechanoluminescence property exhibited by the crystal makes it suitable for stress sensing applications. Besides being a centrosymmetric crystal, it also exhibits NLO behavior. Dielectric properties were studied and theoretical calculations of Fermi energy, valence electron plasma energy, penn gap and polarisability have been done.

Gas-assisted electron-beam-induced nanopatterning of high-quality titanium oxide.

PubMed

Riazanova, A V; Costanzi, B N; Aristov, A I; Rikers, Y G M; Mulders, J J L; Kabashin, A V; Dahlberg, E Dan; Belova, L M

2016-03-18

Electron-beam-induced deposition of titanium oxide nanopatterns is described. The precursor is titanium tetra-isopropoxide, delivered to the deposition point through a needle and mixed with oxygen at the same point via a flow through a separate needle. The depositions are free of residual carbon and have an EDX determined stoichiometry of TiO2.2. High resolution transmission electron microscopy and Raman spectroscopy studies reveal an amorphous structure of the fabricated titanium oxide. Ellipsometric characterization of the deposited material reveals a refractive index of 2.2-2.4 RIU in the spectral range of 500-1700 nm and a very low extinction coefficient (lower than 10(-6) in the range of 400-1700 nm), which is consistent with high quality titanium oxide. The electrical resistivity of the titanium oxide patterned with this new process is in the range of 10-40 GΩ cm and the measured breakdown field is in the range of 10-70 V μm(-1). The fabricated nanopatterns are important for a variety of applications, including field-effect transistors, memory devices, MEMS, waveguide structures, bio- and chemical sensors.

Gas-assisted electron-beam-induced nanopatterning of high-quality titanium oxide

NASA Astrophysics Data System (ADS)

Riazanova, A. V.; Costanzi, B. N.; Aristov, A. I.; Rikers, Y. G. M.; Mulders, J. J. L.; Kabashin, A. V.; Dahlberg, E. Dan; Belova, L. M.

2016-03-01

Electron-beam-induced deposition of titanium oxide nanopatterns is described. The precursor is titanium tetra-isopropoxide, delivered to the deposition point through a needle and mixed with oxygen at the same point via a flow through a separate needle. The depositions are free of residual carbon and have an EDX determined stoichiometry of TiO2.2. High resolution transmission electron microscopy and Raman spectroscopy studies reveal an amorphous structure of the fabricated titanium oxide. Ellipsometric characterization of the deposited material reveals a refractive index of 2.2-2.4 RIU in the spectral range of 500-1700 nm and a very low extinction coefficient (lower than 10-6 in the range of 400-1700 nm), which is consistent with high quality titanium oxide. The electrical resistivity of the titanium oxide patterned with this new process is in the range of 10-40 GΩ cm and the measured breakdown field is in the range of 10-70 V μm-1. The fabricated nanopatterns are important for a variety of applications, including field-effect transistors, memory devices, MEMS, waveguide structures, bio- and chemical sensors.

Correlation of Spectral and Electrochemical Properties of a Series of Ferrocene Derivatives

NASA Technical Reports Server (NTRS)

Hepp, Aloysius F.; Wrighton, Mark S.

2016-01-01

Charge-transfer-to-solvent (CTTS) bands are observed in the UV/VIS spectra of a series of ferrocene derivatives (ferrocene; 1,1'-dimethyl; 1,2,3,4,5-pentamethyl; 1,2,3,4,l',2',3',4'-octamethyl; and decamethyl) by the addition of increasing amounts of CCl4 to ethanol solutions. A linear correlation (slope = 8540 cm-1/V) was found between the redox potential and the energy of the CTTS band, consistent with electrochemical and photochemical oxidation by removal of an electron from the same molecular orbital. Inclusion of literature data for ruthenocene and [(?5-C5H5)Fe(CO)]4 results in a line with a slope of 8140 cm-1/V, within 1 percent of the wavenumber to electron volt conversion factor. Calculation of association constants (K) shows a slight decrease (1.2 to 0.7 mole fraction-1) as the bulkiness of the cyclopentadienyl ring increases, consistent with either a steric or a repulsive electronic effect. The extinction coefficient of the CTTS absorption was constant at approximately 1700/M/cm.

Photothermal therapy of Lewis lung carcinoma in mice using gold nanoshells on carboxylated polystyrene spheres

NASA Astrophysics Data System (ADS)

Liu, Huiyu; Chen, Dong; Tang, Fangqiong; Du, Gangjun; Li, Linlin; Meng, Xianwei; Liang, Wei; Zhang, Yangde; Teng, Xu; Li, Yi

2008-11-01

A new approach towards the design of gold nanoshells on carboxylated polystyrene spheres (GNCPSs) is reported here. Gold nanoshells were self-assembled on the surface of carboxylated polystyrene spheres by a seed growth method. Chitosan (CHI) was used as a functional agent of carboxylated polystyrene spheres for attaching gold seeds. The surface plasmon resonance (SPR) peak of GNCPSs can be tuned, greatly redshifted, over a broad spectral range including the near-infrared (NIR) wavelength region, which provides maximal penetration of light through tissue. Irradiation of GNCPSs at their peak extinction coefficient results in the conversion of light to heat energy that produces a local rise in temperature. Our study revealed that the Lewis lung carcinoma (LLC) in mice treated with GNCPSs exposed to a low dose of NIR light (808 nm, 4 W cm-2) induced irreversible tissue damage. The tumor volumes of the treatment group by GNCPSs were significantly lower than those of control groups, with an average inhibition rate over 55% (P<0.005). This study proves that GNCPSs are promising in plasmonic photothermal tumor therapy.

Crystallographic effects during radiative melting of semitransparent materials

NASA Astrophysics Data System (ADS)

Webb, B. W.; Viskanta, R.

1987-10-01

Experiments have been performed to illustrate crystallogrpahic effects during radiative melting of unconfined vertical layers of semitransparent material. Radiative melting of a polycrystalline paraffin was performed and the instantaneous layer weight and transmittance were measured using a cantilever beam technique and thermopile radiation detector, respectively. The effects of radiative flux, initial solid subcooling, spectral distribution of the irradiation, and crystal structure of the solid as determined qualitatively by the sample solidification rate were studied. Experimental results show conclusively the dominant influence of cystallographic effects in the form of multiple internal scattering of radiation during the melting process. A theoretical model is formulated to predict the melting rate of the material. Radiation transfer is treated by solving the one-dimensional radiative transfer equation for an absorbing-scattering medium using the discrete ordinates method. Melting rate and global layer reflectance as predicted by the model agree well with experimental data. Parametric studies conducted with the model illustrate the sensitivity of the melting behavior to such variables as incident radiative flux, initial layer opacity (material extinction coefficient), and scattering asymmetry factor.

Optical investigation of vacuum evaporated Se80-xTe20Sbx (x = 0, 6, 12) amorphous thin films

NASA Astrophysics Data System (ADS)

Deepika; Singh, Hukum

2017-09-01

Amorphous thin films of Se80-xTe20Sbx (x = 0, 6, 12) chalcogenide glasses has been deposited onto pre-cleaned glass substrate using thermal evaporation technique under a vacuum of 10-5 Torr. The absorption and transmission spectra of these thin films have been recorded using UV spectrophotometer in the spectral range 400-2500 nm at room temperature. Swanepoel envelope method has been employed to obtain film thickness and optical constants such as refractive index, extinction coefficient and dielectric constant. The optical band gap of the samples has been calculated using Tauc relation. The study reveals that optical band gap decreases on increase in Sb content. This is due to decrease in average single bond energy calculated using chemical bond approach. The values of urbach energy has also been computed to support the above observation. Variation of refractive index has also been studies in terms of wavelength and energy using WDD model and values of single oscillator energy and dispersion energy has been obtained.

Spectral characterization of a newly synthesized fluorescent semicarbazone derivative and its usage as a selective fiber optic sensor for copper(II).

PubMed

Oter, Ozlem; Ertekin, Kadriye; Kirilmis, Cumhur; Koca, Murat

2007-02-19

In this work photoluminescent properties of highly Cu(2+) selective organic fluoroionophore, semicarbazone derivative; bis(naphtho[2,1-b]furan-2-yl)methanone semicarbazone (BNF) was investigated in different solvents (dichloromethane, tetrahydrofuran, toluene and ethanol) and in polymer matrices of polyvinylchloride (PVC) and ethyl cellulose (EC) by absorption and emission spectrometry. The BNF derivative displayed enhanced fluorescence emission quantum yield, Q(f)=6.1 x 10(-2) and molar extinction coefficient, epsilon=29,000+/-65 cm(-1)M(-1) in immobilized PVC matrix, compared to 2.6 x 10(-3) and 24,573+/-115 in ethanol solution. The offered sensor exhibited remarkable fluorescence intensity quenching upon exposure to Cu(2+) ions at pH 4.0 in the concentration range of 1.0 x 10(-9) to 3.0 x 10(-4)M [Cu(2+)] while the effects of the responding ions (Ca(2+), Hg(+), Pb(2+), Al(3+), Cr(3+), Mn(2+), Mg(2+), Sn(2+), Cd(2+), Co(2+) and Ni(2+)) were less pronounced.

Theoretical and experimental emittance measurements for a thin liquid sheet flow

NASA Technical Reports Server (NTRS)

Englehart, Amy N.; Mcconley, Marc W.; Chubb, Donald L.

1995-01-01

Surface tension forces at the edges of a thin liquid (approximately 200 microns) sheet flow result in a triangularly shaped sheet. Such a geometry is ideal for an external flow radiator. Since the fluid must have very low vapor pressure, Dow Corning 705 silicone oil was used and the emittance of a flowing sheet of oil was determined by two methods. The emittance was derived as a function of the temperature drop between the top of the sheet and the coalescence point of the sheet, the sink temperature, the volumetric flow and the length of the sheet. the emittance for the oil was also calculated using an extinction coefficient determined from spectral transmittance data of the oil. The oil's emittance ranges from .67 to .87 depending on the sheet thickness and sheet temperature. The emittance derived from the temperature drop was slightly less than the emittance calculated from transmittance data. An investigation of temperature fluctuation upstream of the slit plate was also done. The fluctuations were determined to be negligible, not affecting the temperature drop which was due to radiation.

Theoretical Study of near Neutrality. II. Effect of Subdivided Population Structure with Local Extinction and Recolonization

PubMed Central

Ohta, T.

1992-01-01

There are several unsolved problems concerning the model of nearly neutral mutations. One is the interaction of subdivided population structure and weak selection that spatially fluctuates. The model of nearly neutral mutations whose selection coefficient spatially fluctuates has been studied by adopting the island model with periodic extinction-recolonization. Both the number of colonies and the migration rate play significant roles in determining mutants' behavior, and selection is ineffective when the extinction-recolonization is frequent with low migration rate. In summary, the number of mutant substitutions decreases and the polymorphism increases by increasing the total population size, and/or decreasing the extinction-recolonization rate. However, by increasing the total size of the population, the mutant substitution rate does not become as low when compared with that in panmictic populations, because of the extinction-recolonization, especially when the migration rate is limited. It is also found that the model satisfactorily explains the contrasting patterns of molecular polymorphisms observed in sibling species of Drosophila, including heterozygosity, proportion of polymorphism and fixation index. PMID:1582566

Spectral multigrid methods for the solution of homogeneous turbulence problems

NASA Technical Reports Server (NTRS)

Erlebacher, G.; Zang, T. A.; Hussaini, M. Y.

1987-01-01

New three-dimensional spectral multigrid algorithms are analyzed and implemented to solve the variable coefficient Helmholtz equation. Periodicity is assumed in all three directions which leads to a Fourier collocation representation. Convergence rates are theoretically predicted and confirmed through numerical tests. Residual averaging results in a spectral radius of 0.2 for the variable coefficient Poisson equation. In general, non-stationary Richardson must be used for the Helmholtz equation. The algorithms developed are applied to the large-eddy simulation of incompressible isotropic turbulence.

Spectra of Particulate Backscattering in Natural Waters

NASA Technical Reports Server (NTRS)

Gordon, Howard, R.; Lewis, Marlon R.; McLean, Scott D.; Twardowski, Michael S.; Freeman, Scott A.; Voss, Kenneth J.; Boynton, Chris G.

2009-01-01

Hyperspectral profiles of downwelling irradiance and upwelling radiance in natural waters (oligotrophic and mesotrophic) are combined with inverse radiative transfer to obtain high resolution spectra of the absorption coefficient (a) and the backscattering coefficient (bb) of the water and its constituents. The absorption coefficient at the mesotrophic station clearly shows spectral absorption features attributable to several phytoplankton pigments (Chlorophyll a, b, c, and Carotenoids). The backscattering shows only weak spectral features and can be well represented by a power-law variation with wavelength (lambda): b(sub b) approx. Lambda(sup -n), where n is a constant between 0.4 and 1.0. However, the weak spectral features in b(sub b), suggest that it is depressed in spectral regions of strong particle absorption. The applicability of the present inverse radiative transfer algorithm, which omits the influence of Raman scattering, is limited to lambda < 490 nm in oligotrophic waters and lambda < 575 nm in mesotrophic waters.

PARAMETER MONITORING FOR REAL-TIME ELECTROSTATIC PRECIPITATOR TROUBLESHOOTING

EPA Science Inventory

The paper discusses detailed numerical calculations of particle charge and extinction coefficient performed using current models. The results suggest that information about rapping reentrainment, back corona, and, possibly, sulfuric acid condensation can be gained from simultaneo...

What are the associated parameters and temporal coverage?

Atmospheric Science Data Center

2014-12-08

... Extinction Coefficient, Cloud Vertical Profile, Radar-only Liquid Water Content, Radar-only Liquid Ice Content, Vertical Flux Profile, ... ISCCP-D2like Cloud fraction, Effective Pressure, Temperature, optical depth, IWP/LWP, particle size, IR Emissivity in ...

Statistical Analysis of Spectral Properties and Prosodic Parameters of Emotional Speech

NASA Astrophysics Data System (ADS)

Přibil, J.; Přibilová, A.

2009-01-01

The paper addresses reflection of microintonation and spectral properties in male and female acted emotional speech. Microintonation component of speech melody is analyzed regarding its spectral and statistical parameters. According to psychological research of emotional speech, different emotions are accompanied by different spectral noise. We control its amount by spectral flatness according to which the high frequency noise is mixed in voiced frames during cepstral speech synthesis. Our experiments are aimed at statistical analysis of cepstral coefficient values and ranges of spectral flatness in three emotions (joy, sadness, anger), and a neutral state for comparison. Calculated histograms of spectral flatness distribution are visually compared and modelled by Gamma probability distribution. Histograms of cepstral coefficient distribution are evaluated and compared using skewness and kurtosis. Achieved statistical results show good correlation comparing male and female voices for all emotional states portrayed by several Czech and Slovak professional actors.

Laser Transmission Measurements of Soot Extinction Coefficients in the Exhaust Plume of the X-34 60K-lb Thrust Fastrac Rocket Engine

NASA Technical Reports Server (NTRS)

Dobson, C. C.; Eskridge, R. H.; Lee, M. H.

2000-01-01

A four-channel laser transmissometer has been used to probe the soot content of the exhaust plume of the X-34 60k-lb thrust Fastrac rocket engine at NASA's Marshall Space Flight Center. The transmission measurements were made at an axial location approximately equal 1.65 nozzle diameters from the exit plane and are interpreted in terms of homogeneous radial zones to yield extinction coefficients from 0.5-8.4 per meter. The corresponding soot mass density, spatially averaged over the plume cross section, is, for Rayleigh particles, approximately equal 0.7 microgram/cc, and alternative particle distributions are briefly considered. Absolute plume radiance at the laser wavelength (515 nm) is estimated from the data at approximately equal 2,200 K equivalent blackbody temperature, and temporal correlations in emission from several spatial locations are noted.

Laser Transmission Measurements of Soot Extinction Coefficients in the Exhaust Plume of the X-34 60k-lb Thrust Fastrac Rocket Engine

NASA Technical Reports Server (NTRS)

Dobson, C. C.; Eskridge, R. H.; Lee, M. H.

2000-01-01

A four-channel laser transmissometer has been used to probe the soot content of the exhaust plume of the X-34 60k-lb thrust Fastrac rocket engine at NASA's Marshall Space Flight Center. The transmission measurements were made at an axial location about equal 1.65 nozzle diameters from the exit plane and are interpreted in terms of homogeneous radial zones to yield extinction coefficients from 0.5-8.4 per meter. The corresponding soot mass density, spatially averaged over the plume cross section, is, for Rayleigh particles, approximately equal to 0.7 micrograms/cubic cm and alternative particle distributions are briefly considered. Absolute plume radiance at the laser wavelength (515 nm) is estimated from the data at approximately equal to 2.200 K equivalent blackbody temperature, and temporal correlations in emission from several spatial locations are noted.

Measurement of phase function of aerosol at different altitudes by CCD Lidar

NASA Astrophysics Data System (ADS)

Sun, Peiyu; Yuan, Ke'e.; Yang, Jie; Hu, Shunxing

2018-02-01

The aerosols near the ground are closely related to human health and climate change, the study on which has important significance. As we all know, the aerosol is inhomogeneous at different altitudes, of which the phase function is also different. In order to simplify the retrieval algorithm, it is usually assumed that the aerosol is uniform at different altitudes, which will bring measurement error. In this work, an experimental approach is demonstrated to measure the scattering phase function of atmospheric aerosol particles at different heights by CCD lidar system, which could solve the problem of the traditional CCD lidar system in assumption of phase function. The phase functions obtained by the new experimental approach are used to retrieve the aerosol extinction coefficient profiles. By comparison of the aerosol extinction coefficient retrieved by Mie-scattering aerosol lidar and CCD lidar at night, the reliability of new experimental approach is verified.

New Examination of the Traditional Raman Lidar Technique II: Evaluating the Ratios for Water Vapor and Aerosols

NASA Technical Reports Server (NTRS)

Whiteman, David N.

2003-01-01

In a companion paper, the temperature dependence of Raman scattering and its influence on the Raman and Rayleigh-Mie lidar equations was examined. New forms of the lidar equation were developed to account for this temperature sensitivity. Here those results are used to derive the temperature dependent forms of the equations for the water vapor mixing ratio, aerosol scattering ratio, aerosol backscatter coefficient, and extinction to backscatter ratio (Sa). The error equations are developed, the influence of differential transmission is studied and different laser sources are considered in the analysis. The results indicate that the temperature functions become significant when using narrowband detection. Errors of 5% and more can be introduced in the water vapor mixing ratio calculation at high altitudes and errors larger than 10% are possible for calculations of aerosol scattering ratio and thus aerosol backscatter coefficient and extinction to backscatter ratio.

Changes in cytochrome-oxidase oxidation in the occipital cortex during visual simulation: improvement in sensitivity by the determination of the wavelength dependence of the differential pathlength

NASA Astrophysics Data System (ADS)

Kohl-Bareis, Matthias; Nolte, Christian; Heekeren, Hauke R.; Horst, Susanne; Scholz, J.; Obrig, Hellmuth; Villringer, Arno

1998-01-01

In this study we assess changes in the hemoglobin oxygenation (oxy-Hb, deoxy-Hb) and the Cytochrome-C-Oxidase redox state (Cyt-ox) in the occipital cortex during visual stimulation by near infrared spectroscopy. For the calculation of changes in oxy-Hb, deoxy-Hb and Cyt-ox from attenuation data via a modified Beer-Lambert equation, the wavelength dependence of the differential pathlength factor (DPF), i.e. the ratio of the mean optical pathlength and the physical light-source-detector separation, has to be taken into account. The wavelength dependence of the DPF determines the crosstalk between the different concentrations and is therefore essential for a high sensitivity. Here a simple method is suggested to estimate the wavelength dependence of the DPF((lambda) ) from pulse induced attenuation changes measured on the head of adult humans. The essence is that the DPF is the ratio of the attenuation changes over absorption coefficient changes and the spectral form of the pulse correlated absorption coefficient change is proportional to the extinction coefficient of blood. Indicators for the validity of the DPF((lambda) ) derived for wavelengths between 700 and 970 nm are the stability of the calculated oxy-Hb, deoxy-Hb and Cyt-ox signals with variations of the wavelength range included for their calculation and its overall agreement with the data available from the literature. The DPF derived from pulse measurements was used for the analysis of attenuation data from cortical stimulations. We show that Cyt-ox in the occipital cortex of human subjects is transiently oxidized during visual stimulation.

Changes in cytochrome-oxidase oxidation in the occipital cortex during visual simulation: improvement in sensitivity by the determination of the wavelength dependence of the differential pathlength

NASA Astrophysics Data System (ADS)

Kohl, Matthias; Nolte, Christian; Heekeren, Hauke R.; Horst, Susanne; Scholz, Udo; Obrig, Hellmuth; Villringer, Arno

1997-12-01

In this study we assess changes in the hemoglobin oxygenation (oxy-Hb, deoxy-Hb) and the Cytochrome-C-Oxidase redox state (Cyt-ox) in the occipital cortex during visual stimulation by near infrared spectroscopy. For the calculation of changes in oxy-Hb, deoxy-Hb and Cyt-ox from attenuation data via a modified Beer-Lambert equation, the wavelength dependence of the differential pathlength factor (DPF), i.e. the ratio of the mean optical pathlength and the physical light-source-detector separation, has to be taken into account. The wavelength dependence of the DPF determines the crosstalk between the different concentrations and is therefore essential for a high sensitivity. Here a simple method is suggested to estimate the wavelength dependence of the DPF((lambda) ) from pulse induced attenuation changes measured on the head of adult humans. The essence is that the DPF is the ratio of the attenuation changes over absorption coefficient changes and the spectral form of the pulse correlated absorption coefficient change is proportional to the extinction coefficient of blood. Indicators for the validity of the DPF((lambda) ) derived for wavelengths between 700 and 970 nm are the stability of the calculated oxy-Hb, deoxy-Hb and Cyt-ox signals with variations of the wavelength range included for their calculation and its overall agreement with the data available from the literature. The DPF derived from pulse measurements was used for the analysis of attenuation data from cortical stimulations. We show that Cyt-ox in the occipital cortex of human subjects is transiently oxidized during visual stimulation.

Evaluating the potential for near-shore bathymetry on the Majuro Atoll, Republic of the Marshall Islands, using Landsat 8 and WorldView-3 imagery

USGS Publications Warehouse

Poppenga, Sandra K.; Palaseanu-Lovejoy, Monica; Gesch, Dean B.; Danielson, Jeffrey J.; Tyler, Dean J.

2018-04-16

Satellite-derived near-shore bathymetry (SDB) is becoming an increasingly important method for assessing vulnerability to climate change and natural hazards in low-lying atolls of the northern tropical Pacific Ocean. Satellite imagery has become a cost-effective means for mapping near-shore bathymetry because ships cannot collect soundings safely while operating close to the shore. Also, green laser light detection and ranging (lidar) acquisitions are expensive in remote locations. Previous research has demonstrated that spectral band ratio-based techniques, commonly called the natural logarithm approach, may lead to more precise measurements and modeling of bathymetry because of the phenomenon that different substrates at the same depth have approximately equal ratio values. The goal of this research was to apply the band ratio technique to Landsat 8 at-sensor radiance imagery and WorldView-3 atmospherically corrected imagery in the coastal waters surrounding the Majuro Atoll, Republic of the Marshall Islands, to derive near-shore bathymetry that could be incorporated into a seamless topobathymetric digital elevation model of Majuro. Attenuation of light within the water column was characterized by measuring at-sensor radiance and reflectance at different depths and calculating an attenuation coefficient. Bathymetric lidar data, collected by the U.S. Naval Oceanographic Office in 2006, were used to calibrate the SDB results. The bathymetric lidar yielded a strong linear relation with water depths. The Landsat 8-derived SDB estimates derived from the blue/green band ratio exhibited a water attenuation extinction depth of 6 meters with a coefficient of determination R2=0.9324. Estimates derived from the coastal/red band ratio had an R2=0.9597. At the same extinction depth, SDB estimates derived from WorldView-3 imagery exhibited an R2=0.9574. Because highly dynamic coastal shorelines can be affected by erosion, wetland loss, hurricanes, sea-level rise, urban development, and population growth, consistent bathymetric data are needed to better understand sensitive coastal land/water interfaces in areas subject to coastal disasters.

Using spectral methods to obtain particle size information from optical data: applications to measurements from CARES 2010

NASA Astrophysics Data System (ADS)

Atkinson, Dean B.; Pekour, Mikhail; Chand, Duli; Radney, James G.; Kolesar, Katheryn R.; Zhang, Qi; Setyan, Ari; O'Neill, Norman T.; Cappa, Christopher D.

2018-04-01

Multi-wavelength in situ aerosol extinction, absorption and scattering measurements made at two ground sites during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) are analyzed using a spectral deconvolution method that allows extraction of particle-size-related information, including the fraction of extinction produced by the fine-mode particles and the effective radius of the fine mode. The spectral deconvolution method is typically applied to analysis of remote sensing measurements. Here, its application to in situ measurements allows for comparison with more direct measurement methods and validation of the retrieval approach. Overall, the retrieved fine-mode fraction and effective radius compare well with other in situ measurements, including size distribution measurements and scattering and absorption measurements made separately for PM1 and PM10, although there were some periods during which the different methods yielded different results. One key contributor to differences between the results obtained is the alternative, spectrally based definitions of fine and coarse modes from the optical methods, relative to instruments that use a physically defined cut point. These results indicate that for campaigns where size, composition and multi-wavelength optical property measurements are made, comparison of the results can result in closure or can identify unusual circumstances. The comparison here also demonstrates that in situ multi-wavelength optical property measurements can be used to determine information about particle size distributions in situations where direct size distribution measurements are not available.

Using spectral methods to obtain particle size information from optical data: applications to measurements from CARES 2010

DOE PAGES

Atkinson, Dean B.; Pekour, Mikhail; Chand, Duli; ...

2018-04-23

Here, multi-wavelength in situ aerosol extinction, absorption and scattering measurements made at two ground sites during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) are analyzed using a spectral deconvolution method that allows extraction of particle-size-related information, including the fraction of extinction produced by the fine-mode particles and the effective radius of the fine mode. The spectral deconvolution method is typically applied to analysis of remote sensing measurements. Here, its application to in situ measurements allows for comparison with more direct measurement methods and validation of the retrieval approach. Overall, the retrieved fine-mode fraction and effective radius compare wellmore » with other in situ measurements, including size distribution measurements and scattering and absorption measurements made separately for PM 1 and PM 10, although there were some periods during which the different methods yielded different results. One key contributor to differences between the results obtained is the alternative, spectrally based definitions of fine and coarse modes from the optical methods, relative to instruments that use a physically defined cut point. These results indicate that for campaigns where size, composition and multi-wavelength optical property measurements are made, comparison of the results can result in closure or can identify unusual circumstances. The comparison here also demonstrates that in situ multi-wavelength optical property measurements can be used to determine information about particle size distributions in situations where direct size distribution measurements are not available.« less

Using spectral methods to obtain particle size information from optical data: applications to measurements from CARES 2010

DOE Office of Scientific and Technical Information (OSTI.GOV)

Atkinson, Dean B.; Pekour, Mikhail; Chand, Duli

Here, multi-wavelength in situ aerosol extinction, absorption and scattering measurements made at two ground sites during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) are analyzed using a spectral deconvolution method that allows extraction of particle-size-related information, including the fraction of extinction produced by the fine-mode particles and the effective radius of the fine mode. The spectral deconvolution method is typically applied to analysis of remote sensing measurements. Here, its application to in situ measurements allows for comparison with more direct measurement methods and validation of the retrieval approach. Overall, the retrieved fine-mode fraction and effective radius compare wellmore » with other in situ measurements, including size distribution measurements and scattering and absorption measurements made separately for PM 1 and PM 10, although there were some periods during which the different methods yielded different results. One key contributor to differences between the results obtained is the alternative, spectrally based definitions of fine and coarse modes from the optical methods, relative to instruments that use a physically defined cut point. These results indicate that for campaigns where size, composition and multi-wavelength optical property measurements are made, comparison of the results can result in closure or can identify unusual circumstances. The comparison here also demonstrates that in situ multi-wavelength optical property measurements can be used to determine information about particle size distributions in situations where direct size distribution measurements are not available.« less

Using spectral methods to obtain particle size information from optical data: applications to measurements from CARES 2010

DOE Office of Scientific and Technical Information (OSTI.GOV)

Atkinson, Dean B.; Pekour, Mikhail; Chand, Duli

Multi-wavelength in situ aerosol extinction, absorption and scattering measurements made at two ground sites during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) are analyzed using a spectral deconvolution method that allows extraction of particle-size-related information, including the fraction of extinction produced by the fine-mode particles and the effective radius of the fine mode. The spectral deconvolution method is typically applied to analysis of remote sensing measurements. Here, its application to in situ measurements allows for comparison with more direct measurement methods and validation of the retrieval approach. Overall, the retrieved fine-mode fraction and effective radius compare well withmore » other in situ measurements, including size distribution measurements and scattering and absorption measurements made separately for PM 1 and PM 10, although there were some periods during which the different methods yielded different results. One key contributor to differences between the results obtained is the alternative, spectrally based definitions of fine and coarse modes from the optical methods, relative to instruments that use a physically defined cut point. These results indicate that for campaigns where size, composition and multi-wavelength optical property measurements are made, comparison of the results can result in closure or can identify unusual circumstances. The comparison here also demonstrates that in situ multi-wavelength optical property measurements can be used to determine information about particle size distributions in situations where direct size distribution measurements are not available.« less

Quenching or Bursting: Star Formation Acceleration—A New Methodology for Tracing Galaxy Evolution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, D. Christopher; Darvish, Behnam; Seibert, Mark

We introduce a new methodology for the direct extraction of galaxy physical parameters from multiwavelength photometry and spectroscopy. We use semianalytic models that describe galaxy evolution in the context of large-scale cosmological simulation to provide a catalog of galaxies, star formation histories, and physical parameters. We then apply models of stellar population synthesis and a simple extinction model to calculate the observable broadband fluxes and spectral indices for these galaxies. We use a linear regression analysis to relate physical parameters to observed colors and spectral indices. The result is a set of coefficients that can be used to translate observedmore » colors and indices into stellar mass, star formation rate, and many other parameters, including the instantaneous time derivative of the star formation rate, which we denote the Star Formation Acceleration (SFA), We apply the method to a test sample of galaxies with GALEX photometry and SDSS spectroscopy, deriving relationships between stellar mass, specific star formation rate, and SFA. We find evidence for a mass-dependent SFA in the green valley, with low-mass galaxies showing greater quenching and higher-mass galaxies greater bursting. We also find evidence for an increase in average quenching in galaxies hosting an active galactic nucleus. A simple scenario in which lower-mass galaxies accrete and become satellite galaxies, having their star-forming gas tidally and/or ram-pressure stripped, while higher-mass galaxies receive this gas and react with new star formation, can qualitatively explain our results.« less

Particle size distribution of the stratospheric aerosol from SCIAMACHY limb measurements

NASA Astrophysics Data System (ADS)

Rozanov, Alexei; Malinina, Elizaveta; Bovensmann, Heinrich; Burrows, John

2017-04-01

A crucial role of the stratospheric aerosols for the radiative budget of the Earth's atmosphere and the consequences for the climate change are widely recognized. A reliable knowledge on physical and optical properties of the stratospheric aerosols as well as on their vertical and spatial distributing is a key issue to assure a proper initialization and running conditions for climate models. On a global scale this information can only be gained from space borne measurements. While a series of past, present and future instruments provide extensive date sets of such aerosol characteristics as extinction coefficient or backscattering ratio, information on a size distribution of the stratospheric aerosols is sparse. One of the important sources on vertically and spatially resolved information on the particle size distribution of stratospheric aerosols is provided by space borne measurements of the scattered solar light in limb viewing geometry performed in visible, near-infrared and short-wave infrared spectral ranges. SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) instrument operated on the European satellite Envisat from 2002 to 2102 was capable of providing spectral information needed to retrieve parameters of aerosol particle size distributions. In this presentation we discuss the retrieval method, present first validation results with SAGE II data and analyze first data sets of stratospheric aerosol particle size distribution parameters obtained from SCIAMACHY limb measurements. The research work was performed in the framework of ROMIC (Role of the middle atmosphere in climate) project.

Crystal growth, structural, spectral, thermal, dielectric, linear and nonlinear optical characteristics of a new organic acentric material: L-Methionine-Succinic acid (2/1)

NASA Astrophysics Data System (ADS)

Nageshwari, M.; Kumari, C. Rathika Thaya; Vinitha, G.; Mohamed, M. Peer; Sudha, S.; Caroline, M. Lydia

2018-03-01

L-Methionine-Succinic acid (2/1) (LMSA), 2C5H11NO2S·C4H6O4, a novel nonlinear optical material which belongs to the class of organic category was grown-up for the first time by the technique of slow evaporation. Purity of LMSA was improved using repetitive recrystallization. LMSA was analyzed by single crystal and powder X-ray diffraction investigation to affirm the crystal structure and crystalline character. The single crystal XRD revealed that LMSA corresponds to the crystal system of triclinic with P1 as space group showing the asymmetric unit consists of a neutral succinic acid molecule and two methionine residues which are crystallographically independent existing in zwitterionic form. The functional groups existing in LMSA was accomplished using Fourier transform infrared spectroscopy. The optical transparency and the band gap energy were identified utilizing UV-Visible spectrum. The optical constants specifically reflectance and extinction coefficient clearly indicate the elevated transparency of LMSA. The thermal analyses affirmed its thermal stability. The luminescence behavior of LMSA has been analyzed by Photoluminescence (PL) spectral study. The mechanical, laser damage threshold and dielectric investigation of LMSA was done to suggest the material for practical applications. The second and third harmonic generation efficacy was confirmed by means of Kurtz-Perry and Z-scan procedure which attest its potentiality in the domain of nonlinear optics.

Quantitative photoacoustic assessment of red blood cell aggregation under pulsatile blood flow: experimental and theoretical approaches

NASA Astrophysics Data System (ADS)

Bok, Tae-Hoon; Hysi, Eno; Kolios, Michael C.

2017-03-01

In the present paper, the optical wavelength dependence on the photoacoustic (PA) assessment of the pulsatile blood flow was investigated by means of the experimental and theoretical approaches analyzing PA radiofrequency spectral parameters such as the spectral slope (SS) and mid-band fit (MBF). For the experimental approach, the pulsatile flow of human whole blood at 60 bpm was imaged using the VevoLAZR system (40-MHz-linear-array probe, 700-900 nm illuminations). For the theoretical approach, a Monte Carlo simulation for the light transmit into a layered tissue phantom and a Green's function based method for the PA wave generation was implemented for illumination wavelengths of 700, 750, 800, 850 and 900 nm. The SS and MBF for the experimental results were compared to theoretical ones as a function of the illumination wavelength. The MBF increased with the optical wavelength in both theory and experiments. This was expected because the MBF is representative of the PA magnitude, and the PA signal from red blood cell (RBC) is dependent on the molar extinction coefficient of oxyhemoglobin. On the other hand, the SS decreased with the wavelength, even though the RBC size (absorber size which is related to the SS) cannot depend on the illumination wavelength. This conflicting result can be interpreted by means of the changes of the fluence pattern for different illumination wavelengths. The SS decrease with the increasing illumination wavelength should be further investigated.

Quenching or Bursting: Star Formation Acceleration—A New Methodology for Tracing Galaxy Evolution

NASA Astrophysics Data System (ADS)

Martin, D. Christopher; Gonçalves, Thiago S.; Darvish, Behnam; Seibert, Mark; Schiminovich, David

2017-06-01

We introduce a new methodology for the direct extraction of galaxy physical parameters from multiwavelength photometry and spectroscopy. We use semianalytic models that describe galaxy evolution in the context of large-scale cosmological simulation to provide a catalog of galaxies, star formation histories, and physical parameters. We then apply models of stellar population synthesis and a simple extinction model to calculate the observable broadband fluxes and spectral indices for these galaxies. We use a linear regression analysis to relate physical parameters to observed colors and spectral indices. The result is a set of coefficients that can be used to translate observed colors and indices into stellar mass, star formation rate, and many other parameters, including the instantaneous time derivative of the star formation rate, which we denote the Star Formation Acceleration (SFA), We apply the method to a test sample of galaxies with GALEX photometry and SDSS spectroscopy, deriving relationships between stellar mass, specific star formation rate, and SFA. We find evidence for a mass-dependent SFA in the green valley, with low-mass galaxies showing greater quenching and higher-mass galaxies greater bursting. We also find evidence for an increase in average quenching in galaxies hosting an active galactic nucleus. A simple scenario in which lower-mass galaxies accrete and become satellite galaxies, having their star-forming gas tidally and/or ram-pressure stripped, while higher-mass galaxies receive this gas and react with new star formation, can qualitatively explain our results.

Optical properties and emissivities of liquid metals and alloys

NASA Technical Reports Server (NTRS)

Krishnan, Shankar; Nordine, Paul C.

1993-01-01

This paper presents the results from our on-going program to investigate the optical properties of liquid metals and alloys at elevated temperatures. Ellipsometric and polarimetric techniques have been used to investigate the optical properties of materials in the 1000 - 3000 K temperature range and in the 0.3 - 0.1 mu m wavelength range. The ellipsometric and polarimetric techniques are described and the characteristics of the instruments are presented. The measurements are conducted by reflecting a polarized laser beam from an electromagnetically levitated liquid metal or alloy specimen. A Rotating Analyzer Ellipsometer (RAE) or a four-detector Division-of-Amplitude Photopolarimeter (DOAP) is used to determine the polarimetric properties of the light reflected at an angle of incidence of approximately 68 deg. Optical properties of the specimen which are calculated from these measurements include the index of refraction, extinction coefficient, normal spectral emissivity, and spectral hemispherical emissivity. These properties have been determined at various wavelengths and temperatures for liquid Ag, Al, Au, Cu, Nb, Ni, Pd, Pt, Si, Ti, Ti-Al alloys, U, and Zr. We also describe new experiments using pulsed-dye laser spectroscopic ellipsometry for studies of the wavelength dependence of the emissivities and optical properties of materials at high temperature. Preliminary results are given for liquid Al. The application of four-detector polarimetry for rapid determination of surface emissivity and true temperature is also described. Characteristics of these devices are presented. An example of the accuracy of this instrument in measurements of the melting point of zirconium is illustrated.

[Estimation of organic matter content of north fluvo-aquic soil based on the coupling model of wavelet transform and partial least squares].

PubMed

Wang, Yan-Cang; Yang, Gui-Jun; Zhu, Jin-Shan; Gu, Xiao-He; Xu, Peng; Liao, Qin-Hong

2014-07-01

For improving the estimation accuracy of soil organic matter content of the north fluvo-aquic soil, wavelet transform technology is introduced. The soil samples were collected from Tongzhou district and Shunyi district in Beijing city. And the data source is from soil hyperspectral data obtained under laboratory condition. First, discrete wavelet transform efficiently decomposes hyperspectral into approximate coefficients and detail coefficients. Then, the correlation between approximate coefficients, detail coefficients and organic matter content was analyzed, and the sensitive bands of the organic matter were screened. Finally, models were established to estimate the soil organic content by using the partial least squares regression (PLSR). Results show that the NIR bands made more contributions than the visible band in estimating organic matter content models; the ability of approximate coefficients to estimate organic matter content is better than that of detail coefficients; The estimation precision of the detail coefficients fir soil organic matter content decreases with the spectral resolution being lower; Compared with the commonly used three types of soil spectral reflectance transforms, the wavelet transform can improve the estimation ability of soil spectral fir organic content; The accuracy of the best model established by the approximate coefficients or detail coefficients is higher, and the coefficient of determination (R2) and the root mean square error (RMSE) of the best model for approximate coefficients are 0.722 and 0.221, respectively. The R2 and RMSE of the best model for detail coefficients are 0.670 and 0.255, respectively.

Optical properties of sea ice doped with black carbon - an experimental and radiative-transfer modelling comparison

NASA Astrophysics Data System (ADS)

Marks, Amelia A.; Lamare, Maxim L.; King, Martin D.

2017-12-01

Radiative-transfer calculations of the light reflectivity and extinction coefficient in laboratory-generated sea ice doped with and without black carbon demonstrate that the radiative-transfer model TUV-snow can be used to predict the light reflectance and extinction coefficient as a function of wavelength. The sea ice is representative of first-year sea ice containing typical amounts of black carbon and other light-absorbing impurities. The experiments give confidence in the application of the model to predict albedo of other sea ice fabrics. Sea ices, ˜ 30 cm thick, were generated in the Royal Holloway Sea Ice Simulator ( ˜ 2000 L tanks) with scattering cross sections measured between 0.012 and 0.032 m2 kg-1 for four ices. Sea ices were generated with and without ˜ 5 cm upper layers containing particulate black carbon. Nadir reflectances between 0.60 and 0.78 were measured along with extinction coefficients of 0.1 to 0.03 cm-1 (e-folding depths of 10-30 cm) at a wavelength of 500 nm. Values were measured between light wavelengths of 350 and 650 nm. The sea ices generated in the Royal Holloway Sea Ice Simulator were found to be representative of natural sea ices. Particulate black carbon at mass ratios of ˜ 75, ˜ 150 and ˜ 300 ng g-1 in a 5 cm ice layer lowers the albedo to 97, 90 and 79 % of the reflectivity of an undoped clean sea ice (at a wavelength of 500 nm).

Extinction coefficients and purity of single-walled carbon nanotubes.

PubMed

Zhao, B; Itkis, M E; Niyogi, S; Hu, H; Perea, D E; Haddon, R C

2004-11-01

Single-walled carbon nanotubes (SWNTs) hold great promise for advanced applications in aerospace, electronics and medicine, yet these industries require materials with rigorous quality control. There are currently no accepted standards for quality assurance or quality control among the commercial suppliers of SWNTs. We briefly discuss the applicability of various techniques to measure SWNT purity and review, in detail, the advantages of near infrared (NIR) spectroscopy for the quantitative assessment of the bulk carbonaceous purity of SWNTs. We review the use of solution phase NIR spectroscopy for the analysis and characterization of a variety of carbon materials, emphasizing SWNTs produced by the electric arc (EA), laser oven (LO) and HiPco (HC) methods. We consider the applicability of Beer's law to carbon materials dispersed in dimethylformamide (DMF) and the effective extinction coefficients that are obtained from such dispersions. Analysis of the areal absorptivities of the second interband transition of semiconducting EA-produced SWNTs for a number of samples of differing purities has lead to an absolute molar extinction coefficient for the carbonaceous impurities in EA-produced SWNT samples. We conclude that NIR spectroscopy is the clear method of choice for the assessment of the bulk carbonaceous purity of EA-produced SWNTs, and we suggest that an absolute determination of the purity of SWNTs is within reach. Continued work in this area is expected to lead to a universal method for the assessment of the absolute bulk purity of SWNTs from all sources--such a development will be of great importance for nanotube science and for future customers for this product.

Open-path, closed-path and reconstructed aerosol extinction at a rural site.

PubMed

Gordon, Timothy D; Prenni, Anthony J; Renfro, James R; McClure, Ethan; Hicks, Bill; Onasch, Timothy B; Freedman, Andrew; McMeeking, Gavin R; Chen, Ping

2018-04-09

The Handix Scientific Open-Path Cavity Ringdown Spectrometer (OPCRDS) was deployed during summer 2016 in Great Smoky Mountains National Park (GRSM). Extinction coefficients from the relatively new OPCRDS and from a more well-established extinction instrument agreed to within 7%. Aerosol hygroscopic growth (f(RH)) was calculated from the ratio of ambient extinction measured by the OPCRDS to dry extinction measured by a closed-path extinction monitor (Aerodyne's Cavity Attenuated Phase Shift Particulate Matter Extinction Monitor, CAPS PMex). Derived hygroscopicity (RH < 95%) from this campaign agreed with data from 1995 at the same site and time of year, which is noteworthy given the decreasing trend for organics and sulfate in the eastern U.S. However, maximum f(RH) values in 1995 were less than half as large as those recorded in 2016-possibly due to nephelometer truncation losses in 1995. Two hygroscopicity parameterizations were investigated using high time resolution OPCRDS+CAPS PMex data, and the K ext model was more accurate than the γ model. Data from the two ambient optical instruments, the OPCRDS and the open-path nephelometer, generally agreed; however, significant discrepancies between ambient scattering and extinction were observed, apparently driven by a combination of hygroscopic growth effects, which tend to increase nephelometer truncation losses and decrease sensitivity to the wavelength difference between the two instruments as a function of particle size. There was not a statistically significant difference in the mean reconstructed extinction values obtained from the original and the revised IMPROVE (Interagency Monitoring of Protected Visual Environments) equations. On average IMPROVE reconstructed extinction was ~25% lower than extinction measured by the OPCRDS, which suggests that the IMPROVE equations and 24-hr aerosol data are moderately successful in estimating current haze levels at GRSM. However, this conclusion is limited by the coarse temporal resolution and the low dynamic range of the IMPROVE reconstructed extinction.

Characterizing the Vertical Profile of Aerosol Particle Extinction and Linear Depolarization over Southeast Asia and the Maritime Continent: The 2007-2009 View from CALIOP

NASA Technical Reports Server (NTRS)

Campbell, James R.; Reid, Jeffrey S.; Westphal, Douglas L.; Zhang, Jianglong; Tackett, Jason L.; Chew, Boon Ning; Welton, Ellsworth J.; Shimizu, Atsushi; Sugimoto, Nobuo; Aoki, Kazuma;

Distortion of Magnetic Fields in a Starless Core. III. Polarization–Extinction Relationship in FeSt 1-457

NASA Astrophysics Data System (ADS)

Kandori, Ryo; Tamura, Motohide; Nagata, Tetsuya; Tomisaka, Kohji; Kusakabe, Nobuhiko; Nakajima, Yasushi; Kwon, Jungmi; Nagayama, Takahiro; Tatematsu, Ken’ichi

2018-04-01

The relationship between dust polarization and extinction was determined for the cold dense starless molecular cloud core FeSt 1-457 based on the background star polarimetry of dichroic extinction at near-infrared wavelengths. Owing to the known (three-dimensional) magnetic field structure, the observed polarizations from the core were corrected by considering (a) the subtraction of the ambient polarization component, (b) the depolarization effect of inclined distorted magnetic fields, and (c) the magnetic inclination angle of the core. After these corrections, a linear relationship between polarization and extinction was obtained for the core in the range up to A V ≈ 20 mag. The initial polarization versus extinction diagram changed dramatically after the corrections of (a) to (c), with the correlation coefficient being refined from 0.71 to 0.79. These corrections should affect the theoretical interpretation of the observational data. The slope of the finally obtained polarization–extinction relationship is {P}H/{E}H-{Ks}=11.00+/- 0.72 % {mag}}-1, which is close to the statistically estimated upper limit of the interstellar polarization efficiency. This consistency suggests that the upper limit of interstellar polarization efficiency might be determined by the observational viewing angle toward polarized astronomical objects.

Risk of population extinction from fixation of deleterious and reverse mutations.

PubMed

Lande, R

1998-01-01

A model is developed for alternate fixations of mildly deleterious and wild-type alleles arising by forward and reverse mutation in a finite population. For almost all parameter values, this gives an equilibrium load that agrees closely with the general expression derived from diffusion theory. Nearly neutral mutations with selection coefficient a few times larger than 1/(2N(e)) do the most damage by increasing the equilibrium load. The model of alternate fixations facilitates dynamical analysis of the expected load and the mean time to extinction in a population that has been suddenly reduced from a very large size to a small size. Reverse mutation can substantially improve population viability, increasing the mean time to extinction by an order of magnitude or more, but because many mutations are irreversible the effects may not be large. Populations with initially high mean fitness and small effective size, N(e) below a few hundred individuals, may be at serious risk of extinction from fixation of deleterious mutations within 10(3) to 10(4) generations.

Selection in a subdivided population with local extinction and recolonization.

PubMed Central

Cherry, Joshua L

2003-01-01

In a subdivided population, local extinction and subsequent recolonization affect the fate of alleles. Of particular interest is the interaction of this force with natural selection. The effect of selection can be weakened by this additional source of stochastic change in allele frequency. The behavior of a selected allele in such a population is shown to be equivalent to that of an allele with a different selection coefficient in an unstructured population with a different size. This equivalence allows use of established results for panmictic populations to predict such quantities as fixation probabilities and mean times to fixation. The magnitude of the quantity N(e)s(e), which determines fixation probability, is decreased by extinction and recolonization. Thus deleterious alleles are more likely to fix, and advantageous alleles less likely to do so, in the presence of extinction and recolonization. Computer simulations confirm that the theoretical predictions of both fixation probabilities and mean times to fixation are good approximations. PMID:12807797

Determination of the single scattering albedo and direct radiative forcing of biomass burning aerosol with data from the MODIS (Moderate Resolution Imaging Spectroradiometer) satellite instrument

NASA Astrophysics Data System (ADS)

Zhu, Li

Biomass burning aerosols absorb and scatter solar radiation and therefore affect the energy balance of the Earth-atmosphere system. The single scattering albedo (SSA), the ratio of the scattering coefficient to the extinction coefficient, is an important parameter to describe the optical properties of aerosols and to determine the effect of aerosols on the energy balance of the planet and climate. Aerosol effects on radiation also depend strongly on surface albedo. Large uncertainties remain in current estimates of radiative impacts of biomass burning aerosols, due largely to the lack of reliable measurements of aerosol and surface properties. In this work we investigate how satellite measurements can be used to estimate the direct radiative forcing of biomass burning aerosols. We developed a method using the critical reflectance technique to retrieve SSA from the Moderate Resolution Imaging Spectroradiometer (MODIS) observed reflectance at the top of the atmosphere (TOA). We evaluated MODIS retrieved SSAs with AErosol RObotic NETwork (AERONET) retrievals and found good agreements within the published uncertainty of the AERONET retrievals. We then developed an algorithm, the MODIS Enhanced Vegetation Albedo (MEVA), to improve the representations of spectral variations of vegetation surface albedo based on MODIS observations at the discrete 0.67, 0.86, 0.47, 0.55, 1.24, 1.64, and 2.12 mu-m channels. This algorithm is validated using laboratory measurements of the different vegetation types from the Amazon region, data from the Johns Hopkins University (JHU) spectral library, and data from the U.S. Geological Survey (USGS) digital spectral library. We show that the MEVA method can improve the accuracy of flux and aerosol forcing calculations at the TOA compared to more traditional interpolated approaches. Lastly, we combine the MODIS retrieved biomass burning aerosol SSA and the surface albedo spectrum determined from the MEVA technique to calculate TOA flux and aerosol direct radiative forcing over the Amazon region and compare it with Clouds and the Earth's Radiant Energy System (CERES) satellite results. The results show that MODIS based forcing calculations present similar averaged results compared to CERES, but MODIS shows greater spatial variation of aerosol forcing than CERES. Possible reasons for these differences are explored and discussed in this work. Potential future research based on these results is discussed as well.

Measurement of solar extinction in tower plants with digital cameras

NASA Astrophysics Data System (ADS)

Ballestrín, J.; Monterreal, R.; Carra, M. E.; Fernandez-Reche, J.; Barbero, J.; Marzo, A.

2016-05-01

Atmospheric extinction of solar radiation between the heliostat field and the receiver is accepted as a non-negligible source of energy loss in the increasingly large central receiver plants. However, the reality is that there is currently no reliable measurement method for this quantity and at present these plants are designed, built and operated without knowing this local parameter. Nowadays digital cameras are used in many scientific applications for their ability to convert available light into digital images. Its broad spectral range, high resolution and high signal to noise ratio, make them an interesting device in solar technology. In this work a method for atmospheric extinction measurement based on digital images is presented. The possibility of defining a measurement setup in circumstances similar to those of a tower plant increases the credibility of the method. This procedure is currently being implemented at Plataforma Solar de Almería.

Temperature-dependent spectral mismatch corrections

DOE PAGES

Osterwald, Carl R.; Campanelli, Mark; Moriarty, Tom; ...

2015-11-01

This study develops the mathematical foundation for a translation of solar cell short-circuit current from one thermal and spectral irradiance operating condition to another without the use of ill-defined and error-prone temperature coefficients typically employed in solar cell metrology. Using the partial derivative of quantum efficiency with respect to temperature, the conventional isothermal expression for spectral mismatch corrections is modified to account for changes of current due to temperature; this modification completely eliminates the need for short-circuit-current temperature coefficients. An example calculation is provided to demonstrate use of the new translation.

Stellar ultraviolet colors and interstellar extinction

NASA Technical Reports Server (NTRS)

Peytremann, E.; Davis, R. J.

1972-01-01

A sample of celescope results is studied. Most of the sample stars belong to the Orion and Vela regions. Stars with visual excess E(B-V) less than 0.05 are selected in order to derive relationships of intrinsic color index versus spectral type. The resulting intrinsic color-color relations are compared with existing blanketed and unblanketed model calculations. Finally, the preceding intrinsic relations are utilized to derive some results on interstellar extinction. Owing to the rather large scatter in the celescope data, the Vela stars give the more significant results because their visible excess E(B-V) is, in general, larger than that for the Orion stars.

Fröhlich resonance in carbon nanospiroids and the 2175 Å interstellar absorption feature

NASA Astrophysics Data System (ADS)

Yastrebov, Sergey; Chekulaev, Maxim; Siklitskaya, Alexandra; Majewski, Jacek A.; Smith, Roger

2017-02-01

This paper demonstrates that a free electron gas model accurately simulates the spectral dependence of optical extinction spectra for carbon spiroids under the assumption that free electrons are confined in an homogeneous spherical particle owing to the delocalisation of π electrons that occurs in the actual spectral range. This effect can occur in the spiroid, rather than a spheroid (onion) due to the variable radii of the spiral turns as a function of distance from the centre, which are smaller than typical values for the spheroid.

Scanner observations of cool stars from 3400 to 11,000 A.

NASA Technical Reports Server (NTRS)

Fay, T.; Honeycutt, R. K.

1972-01-01

Evaluation of photoelectric scans of the M supergiant alpha Ori and the carbon stars 19 Psc, W Ori, and DS Peg made at 20-A resolution from 3400 to 6000 A and at 40-A resolution from 6000 to 11,000 A. The data are corrected for atmospheric extinction and for the instrumental response to obtain plots of log flux per unit frequency interval versus wavelength. The dominant spectral features are due to C2, CN, and TiO; the variation of these features with spectral class is pointed out.

Nonlinear Spectral Singularity and Laser Output Intensity for the TE and TM Modes

NASA Astrophysics Data System (ADS)

Ghaemidizicheh, Hamed; Mostafazadeh, Ali

The nonlinear spectral singularity arising from a Kerr nonlinearity is explored in. This reference studies the effect of nonlinearity in Lasing condition and shows that Kerr nonlinearity with spectral singularity for a normally incident wave provides an explanation of lasing at gain coefficient g. Lasing occurs when it exceeds threshold gain g0. For oblique waves, Ref. looks at the behavior of threshold gain coefficient g0 which is given by the condition that there is a linear spectral singularity. We investigated imposing the condition of the existence of nonlinear spectral singularity in the TE / TM modes of a mirrorless slab of gain materials and studied the θ-dependence of intensity. Supported by TUBITAK Project No: 114F357 and by the Turkish Academy of Science (TUBA).

Wavelength selection for portable noninvasive blood component measurement system based on spectral difference coefficient and dynamic spectrum

NASA Astrophysics Data System (ADS)

Feng, Ximeng; Li, Gang; Yu, Haixia; Wang, Shaohui; Yi, Xiaoqing; Lin, Ling

2018-03-01

Noninvasive blood component analysis by spectroscopy has been a hotspot in biomedical engineering in recent years. Dynamic spectrum provides an excellent idea for noninvasive blood component measurement, but studies have been limited to the application of broadband light sources and high-resolution spectroscopy instruments. In order to remove redundant information, a more effective wavelength selection method has been presented in this paper. In contrast to many common wavelength selection methods, this method is based on sensing mechanism which has a clear mechanism and can effectively avoid the noise from acquisition system. The spectral difference coefficient was theoretically proved to have a guiding significance for wavelength selection. After theoretical analysis, the multi-band spectral difference coefficient-wavelength selection method combining with the dynamic spectrum was proposed. An experimental analysis based on clinical trial data from 200 volunteers has been conducted to illustrate the effectiveness of this method. The extreme learning machine was used to develop the calibration models between the dynamic spectrum data and hemoglobin concentration. The experiment result shows that the prediction precision of hemoglobin concentration using multi-band spectral difference coefficient-wavelength selection method is higher compared with other methods.

[Near ultraviolet absorption spectral properties of chromophoric dissolved organic matter in the north area of Yellow Sea].

PubMed

Wang, Lin; Zhao, Dong-Zhi; Yang, Jian-Hong; Chen, Yan-Long

2010-12-01

Chromophoric dissolved organic matter (CDOM) near ultraviolet absorption spectra contains CDOM molecular structure, composition and other important physical and chemical information. Based on the measured data of CDOM absorption coefficient in March 2009 in the north area of Yellow Sea, the present paper analyzed near ultraviolet absorption spectral properties of CDOM. The results showed that due to the impact of near-shore terrigenous input, the composition of CDOM is quite different in the north area of Yellow Sea, and this area is a typical case II water; fitted slope with specific range of spectral band and absorption coefficient at specific band can indicate the relative size of CDOM molecular weight, correlation between spectral slope of the Sg,275-300), Sg,300-350, Sg,350-400 and Sg,250-275 and the relative size of CDOM molecular weight indicative parameter M increases in turn and the highest is up to 0.95. Correlation between a(g)(lambda) and M value increases gradually with the increase in wavelength, and the highest is up to 0.92 at 400 nm; being correlated or not between spectral slope and absorption coefficient is decided by the fitting-band wavelength range for the spectra slope and the wavelength for absorption coefficient. Correlation between Sg,275-300 and a(g)(400) is the largest, up to 0.87.

A TV-constrained decomposition method for spectral CT

NASA Astrophysics Data System (ADS)

Guo, Xiaoyue; Zhang, Li; Xing, Yuxiang

2017-03-01

Spectral CT is attracting more and more attention in medicine, industrial nondestructive testing and security inspection field. Material decomposition is an important issue to a spectral CT to discriminate materials. Because of the spectrum overlap of energy channels, as well as the correlation of basis functions, it is well acknowledged that decomposition step in spectral CT imaging causes noise amplification and artifacts in component coefficient images. In this work, we propose materials decomposition via an optimization method to improve the quality of decomposed coefficient images. On the basis of general optimization problem, total variance minimization is constrained on coefficient images in our overall objective function with adjustable weights. We solve this constrained optimization problem under the framework of ADMM. Validation on both a numerical dental phantom in simulation and a real phantom of pig leg on a practical CT system using dual-energy imaging is executed. Both numerical and physical experiments give visually obvious better reconstructions than a general direct inverse method. SNR and SSIM are adopted to quantitatively evaluate the image quality of decomposed component coefficients. All results demonstrate that the TV-constrained decomposition method performs well in reducing noise without losing spatial resolution so that improving the image quality. The method can be easily incorporated into different types of spectral imaging modalities, as well as for cases with energy channels more than two.

Sensitivity of the Lidar ratio to changes in size distribution and index of refraction

NASA Technical Reports Server (NTRS)

Evans, B. T. N.

1986-01-01

In order to invert lidar signals to obtain reliable extinction coefficients, sigma, a relationship between sigma and the backscatter coefficient, beta, must be given. These two coefficients are linearly related if the complex index of refraction, m, particle shape size distribution, N, does not change along the path illuminated by the laser beam. This, however, is generally not the case. An extensive Mie computation of the lidar ratio R = beta/sigma and the sensitivity of R to the changes in a parametric space defined by N and m were examined.

Chemical apportionment of aerosol optical properties during the Asia-Pacific Economic Cooperation summit in Beijing, China

NASA Astrophysics Data System (ADS)

Han, Tingting; Xu, Weiqi; Chen, Chen; Liu, Xingang; Wang, Qingqing; Li, Jie; Zhao, Xiujuan; Du, Wei; Wang, Zifa; Sun, Yele

2015-12-01

We have investigated the chemical and optical properties of aerosol particles during the 2014 Asia-Pacific Economic Cooperation (APEC) summit in Beijing, China, using the highly time-resolved measurements by a high-resolution aerosol mass spectrometer and a cavity attenuated phase shift extinction monitor. The average (±σ) extinction coefficient (bext) and absorption coefficient (bap) were 186.5 (±184.5) M m-1 and 23.3 (±21.9) M m-1 during APEC, which were decreased by 63% and 56%, respectively, compared to those before APEC primarily due to strict emission controls. The aerosol composition and size distributions showed substantial changes during APEC; as a response, the mass scattering efficiency (MSE) of PM1 was decreased from 4.7 m2 g-1 to 3.5 m2 g-1. Comparatively, the average single-scattering albedo (SSA) remained relatively unchanged, illustrating the synchronous reductions of bext and bap during APEC. MSE and SSA were found to increase as function of the oxidation degree of organic aerosol (OA), indicating a change of aerosol optical properties during the aging processes. The empirical relationships between chemical composition and particle extinction were established using a multiple linear regression model. Our results showed the largest contribution of ammonium nitrate to particle extinction, accounting for 35.1% and 29.3% before and during APEC, respectively. This result highlights the important role of ammonium nitrate in the formation of severe haze pollution during this study period. We also observed very different optical properties of primary and secondary aerosol. Owing to emission controls in Beijing and surrounding regions and also partly the influences of meteorological changes, the average bext of secondary aerosol during APEC was decreased by 71% from 372.3 M m-1 to 108.5 M m-1, whereas that of primary aerosol mainly from cooking, traffic, and biomass burning emissions showed a smaller reduction from 136.7 M m-1 to 71.3 M m-1. As a result, the contribution of primary aerosol to particle extinction increased from 26.8% to 39.6%, elucidating an enhanced role of local primary sources in visibility deterioration during APEC. Further analysis of chemically resolved particle extinction showed that the extinction contributions of aerosol species varied greatly between different air masses but generally with ammonium nitrate, ammonium sulfate, and secondary OA being the three major contributors.

Impact of organic coating on growth of ammonium sulfate particles: light extinction measurements relevant for the direct effect

NASA Astrophysics Data System (ADS)

Robinson, C. B.; Zarzana, K. J.; Hasenkopf, C. A.; Tolbert, M. A.

2012-12-01

Light extinction by particles is strongly dependent on chemical composition, particle size, and water uptake. Relative humidity affects extinction by causing changes in refractive index and particle size due to hygroscopic growth. The ability of particles to take up water depends on their composition and structure. In both laboratory and field studies, inorganic salts completely covered by an organic coating have been observed. The impact of this coating on water uptake is uncertain, and a systematic study that examines water uptake as a function of relative humidity is highly desirable. These data are critical to evaluate the aerosol direct effect on climate, which is one of the most uncertain aspects of future climate change. In this study, we probe the connection between aerosol composition, size and light extinction directly by measuring fRHext, the ratio of the extinction coefficient for humidified particles to the extinction coefficient for dry particles. Particles were composed of 1,2,6-hexanetriol and ammonium sulfate, a system that forms organic coatings around the inorganic core. A cavity ring-down aerosol extinction spectrometer at 532 nm is used to measure the optical growth factor as a function of relative humidity. The fRHext values for a range of %RH for pure ammonium sulfate, pure 1,2,6-hexanetriol, and ammonium sulfate particles with 1,2,6-hexanetriol coatings were measured. The coated particles are created using a method of liquid-liquid separation, where the particles are exposed to water vapor creating a RH% above their deliquescence RH%. The particles are then dried with a Nafion dryer to a RH% that is below the point where liquid-liquid phase separation is observed, but above the efflorescence RH%. Pure 1,2,6-hexanetriol takes up little water over the observed RH range of 45-65%, and therefore fRHext ~ 1. With pure ammonium sulfate for the same RH% range, the fRHext varied from 1.5 - 2, depending on the RH% and the particle size. For the coated particles, at each RH%, the fRHext values fall between those for pure ammonium sulfate and pure 1,2,6-hexanetriol values. This suggests that the organic coating does not prevent water uptake by the ammonium sulfate cores.

Tunable diode laser measurements of HO2NO2 absorption coefficients near 12.5 microns

NASA Technical Reports Server (NTRS)

May, R. D.; Molina, L. T.; Webster, C. R.

1988-01-01

A tunable diode laser spectrometer has been used to measure absorption coefficients of peroxynitric acid (HO2NO2) near the 803/cm Q branch. HO2NO2 concentrations in a low-pressure flowing gas mixture were determined from chemical titration procedures and UV absorption spectroscopy. The diode laser measured absorption coefficients, at a spectral resolution of better than 0.001/cm, are about 10 percent larger than previous Fourier transform infrared measurements made at a spectral resolution of 0.06/cm.

Bayesian assessment of uncertainty in aerosol size distributions and index of refraction retrieved from multiwavelength lidar measurements.

PubMed

Herman, Benjamin R; Gross, Barry; Moshary, Fred; Ahmed, Samir

2008-04-01

We investigate the assessment of uncertainty in the inference of aerosol size distributions from backscatter and extinction measurements that can be obtained from a modern elastic/Raman lidar system with a Nd:YAG laser transmitter. To calculate the uncertainty, an analytic formula for the correlated probability density function (PDF) describing the error for an optical coefficient ratio is derived based on a normally distributed fractional error in the optical coefficients. Assuming a monomodal lognormal particle size distribution of spherical, homogeneous particles with a known index of refraction, we compare the assessment of uncertainty using a more conventional forward Monte Carlo method with that obtained from a Bayesian posterior PDF assuming a uniform prior PDF and show that substantial differences between the two methods exist. In addition, we use the posterior PDF formalism, which was extended to include an unknown refractive index, to find credible sets for a variety of optical measurement scenarios. We find the uncertainty is greatly reduced with the addition of suitable extinction measurements in contrast to the inclusion of extra backscatter coefficients, which we show to have a minimal effect and strengthens similar observations based on numerical regularization methods.

Improving optical properties of silicon nitride films to be applied in the middle infrared optics by a combined high-power impulse/unbalanced magnetron sputtering deposition technique.

PubMed

Liao, Bo-Huei; Hsiao, Chien-Nan

2014-02-01

Silicon nitride films are prepared by a combined high-power impulse/unbalanced magnetron sputtering (HIPIMS/UBMS) deposition technique. Different unbalance coefficients and pulse on/off ratios are applied to improve the optical properties of the silicon nitride films. The refractive indices of the Si3N4 films vary from 2.17 to 2.02 in the wavelength ranges of 400-700 nm, and all the extinction coefficients are smaller than 1×10(-4). The Fourier transform infrared spectroscopy and x-ray diffractometry measurements reveal the amorphous structure of the Si3N4 films with extremely low hydrogen content and very low absorption between the near IR and middle IR ranges. Compared to other deposition techniques, Si3N4 films deposited by the combined HIPIMS/UBMS deposition technique possess the highest refractive index, the lowest extinction coefficient, and excellent structural properties. Finally a four-layer coating is deposited on both sides of a silicon substrate. The average transmittance from 3200 to 4800 nm is 99.0%, and the highest transmittance is 99.97% around 4200 nm.

Extinction Maps and Dust-to-gas Ratios in Nearby Galaxies with LEGUS

NASA Astrophysics Data System (ADS)

Kahre, L.; Walterbos, R. A.; Kim, H.; Thilker, D.; Calzetti, D.; Lee, J. C.; Sabbi, E.; Ubeda, L.; Aloisi, A.; Cignoni, M.; Cook, D. O.; Dale, D. A.; Elmegreen, B. G.; Elmegreen, D. M.; Fumagalli, M.; Gallagher, J. S., III; Gouliermis, D. A.; Grasha, K.; Grebel, E. K.; Hunter, D. A.; Sacchi, E.; Smith, L. J.; Tosi, M.; Adamo, A.; Andrews, J. E.; Ashworth, G.; Bright, S. N.; Brown, T. M.; Chandar, R.; Christian, C.; de Mink, S. E.; Dobbs, C.; Evans, A. S.; Herrero, A.; Johnson, K. E.; Kennicutt, R. C.; Krumholz, M. R.; Messa, M.; Nair, P.; Nota, A.; Pellerin, A.; Ryon, J. E.; Schaerer, D.; Shabani, F.; Van Dyk, S. D.; Whitmore, B. C.; Wofford, A.

2018-03-01

We present a study of the dust-to-gas ratios in five nearby galaxies: NGC 628 (M74), NGC 6503, NGC 7793, UGC 5139 (Holmberg I), and UGC 4305 (Holmberg II). Using Hubble Space Telescope broadband WFC3/UVIS UV and optical images from the Treasury program Legacy ExtraGalactic UV Survey (LEGUS) combined with archival HST/Advanced Camera for Surveys data, we correct thousands of individual stars for extinction across these five galaxies using an isochrone-matching (reddening-free Q) method. We generate extinction maps for each galaxy from the individual stellar extinctions using both adaptive and fixed resolution techniques and correlate these maps with neutral H I and CO gas maps from the literature, including the H I Nearby Galaxy Survey and the HERA CO-Line Extragalactic Survey. We calculate dust-to-gas ratios and investigate variations in the dust-to-gas ratio with galaxy metallicity. We find a power-law relationship between dust-to-gas ratio and metallicity, consistent with other studies of dust-to-gas ratio compared to metallicity. We find a change in the relation when H2 is not included. This implies that underestimation of {N}{{{H}}2} in low-metallicity dwarfs from a too-low CO-to-H2 conversion factor X CO could have produced too low a slope in the derived relationship between dust-to-gas ratio and metallicity. We also compare our extinctions to those derived from fitting the spectral energy distribution (SED) using the Bayesian Extinction and Stellar Tool for NGC 7793 and find systematically lower extinctions from SED fitting as compared to isochrone matching.

The open cluster IC 1805 and its vicinity: investigation of stars in the Vilnius, IPHAS, 2MASS, and WISE systems

NASA Astrophysics Data System (ADS)

Straižys, V.; Boyle, R. P.; Janusz, R.; Laugalys, V.; Kazlauskas, A.

2013-06-01

The results of CCD photometry in the Vilnius seven-color system down to V = 18 mag are presented for 242 stars in the direction of the young open cluster IC 1805 that is located in the active star-forming region W4 in the Cas OB6 association. Photometric data were used to classify stars into spectral and luminosity classes, and to determine their interstellar reddenings, extinctions and distances. We confirm the CH3OH and H2O maser VLBA parallax results that the cluster is located close to the front side of the Perseus arm, at a distance about 2.0 kpc. In the color-magnitude diagram, zero-age main sequence (ZAMS) stars of the cluster extend to spectral class A0. The extinction values for the majority of the cluster stars are between 2.2 and 2.7 mag, with a mean value of 2.46 mag. This extinction originates mainly between the Sun and the outer edge of the Local arm, in accordance with the distribution of CO clouds. In the Perseus arm and beyond, the extinction was investigated using the classification and reddening determination for A0-F0 stars measured in the r, i, Hα system of the IPHAS survey to r = 19 mag. The extinction AV within the Perseus arm ranges from 2.5-4.5 mag at the front edge to 3.0-5.0 mag at the far edge. Possibly, we have found about 20 early A-type stars located in the Outer arm. The 2MASS JHKs photometry for red giants gives much higher extinction values (up to about 6 mag), which would correspond to the stars located behind dense clouds of both arms. In the area, using the WISE, 2MASS, and IPHAS photometry data, 18 possible young stellar objects (YSOs) of low masses are identified. Six high-mass YSOs (five Ae/Be stars and a F6e star) are known from previous investigations. Full Table 1 is only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/554/A3

Switchgrass leaf area index and light extinction coefficients

USDA-ARS?s Scientific Manuscript database

Biomass production simulation modeling for plant species is often dependent upon accurate simulation or measurement of canopy light interception and radiation use efficiency. With the recent interest in converting large tracts of land to biofuel species cropping, modeling vegetative yield with grea...

DEVELOPMENT AND APPLICAIONS OF A STANDARD VISUAL INDEX

EPA Science Inventory

A standard visual index appropriate for characterizing visibility through uniform hazes, is defined in terms of either of the traditional metrics: visual range or extinction coefficient. This index was designed to be linear with respect to perceived visual changes over its entire...

CALIPSO V1.00 L3 IceCloud Formal Release Announcement

Atmospheric Science Data Center

2018-06-13

... The Atmospheric Science Data Center (ASDC) at NASA Langley Research Center in collaboration with the CALIPSO mission team announces the ... distributions of ice cloud extinction coefficients and ice water content histograms on a uniform spatial grid.  All parameters are ...

Optical modulation in silicon waveguides via charge state control of deep levels.

PubMed

Logan, D F; Jessop, P E; Knights, A P; Wojcik, G; Goebel, A

2009-10-12

The control of defect mediated optical absorption at a wavelength of 1550 nm via charge state manipulation is demonstrated using optical absorption measurements of indium doped Silicon-On-Insulator (SOI) rib waveguides. These measurements introduce the potential for modulation of waveguide transmission by using the local depletion and injection of free-carriers to change deep-level occupancy. The extinction ratio and modulating speed are simulated for a proposed device structure. A 'normally-off' depletion modulator is described with an extinction coefficient limited to 5 dB/cm and switching speeds in excess of 1 GHz. For a carrier injection modulator a fourfold enhancement in extinction ratio is provided relative to free carrier absorption alone. This significant improvement in performance is achieved with negligible increase in driving power but slightly degraded switching speed.

Conjugation of antibodies to gold nanorods through Fc portion: synthesis and molecular specific imaging

PubMed Central

Joshi, Pratixa P.; Yoon, Soon Joon; Hardin, William G.; Emelianov, Stanislav; Sokolov, Konstantin V.

2013-01-01

Anisotropic gold nanorods provide a convenient combination of properties, such as tunability of plasmon resonances and strong extinction cross-sections in the near-infrared to red spectral region. These properties have created significant interest in the development of antibody conjugation methods for synthesis of targeted nanorods for a number of biomedical applications, including molecular specific imaging and therapy. Previously published conjugation approaches have achieved molecular specificity. However, the current conjugation methods have several downsides including low stability and potential cytotoxicity of bioconjugates that are produced by electrostatic interactions as well as lack of control over antibody orientation during covalent conjugation. Here we addressed these shortcomings by introducing directional antibody conjugation to the gold nanorod surface. The directional conjugation is achieved through the carbohydrate moiety, which is located on one of the heavy chains of the Fc portion of most antibodies. The carbohydrate is oxidized under mild conditions to a hydrazide reactive aldehyde group. Then, a heterofunctional linker with hydrazide and dithiol groups is used to attach antibodies to gold nanorods. The directional conjugation approach was characterized using electron microscopy, zeta potential and extinction spectra. We also determined spectral changes associated with nanorod aggregation; these spectral changes can be used as a convenient quality control of nanorod bioconjugates. Molecular specificity of the synthesized antibody targeted nanorods was demonstrated using hyperspectral optical and photoacoustic imaging of cancer cell culture models. Additionally, we observed characteristic changes in optical spectra of molecular specific nanorods after their interactions with cancer cells; the observed spectral signatures can be explored for sensitive cancer detection. PMID:23631707

Vertically-resolved profiles of mass concentrations and particle backscatter coefficients of Asian dust plumes derived from lidar observations of silicon dioxide.

PubMed

Noh, Youngmin; Müller, Detlef; Shin, Sung-Kyun; Shin, Dongho; Kim, Young J

2016-01-01

This study presents a method to retrieve vertically-resolved profiles of dust mass concentrations by analyzing Raman lidar signals of silicon dioxide (quartz) at 546nm. The observed particle plumes consisted of mixtures of East Asian dust with anthropogenic pollution. Our method for the first time allows for extracting the contribution of the aerosol component "pure dust" contained in the aerosol type "polluted dust". We also propose a method that uses OPAC (Optical Properties of Aerosols and Clouds) and the mass concentrations profiles of dust in order to derive profiles of backscatter coefficients of pure dust in mixed dust/pollution plumes. The mass concentration of silicon dioxide (quartz) in the atmosphere can be estimated from the backscatter coefficient of quartz. The mass concentration of dust is estimated by the weight percentage (38-77%) of mineral quartz in Asian dust. The retrieved dust mass concentrations are classified into water soluble, nucleation, accumulation, mineral-transported and coarse mode according to OPAC. The mass mixing ratio of 0.018, 0.033, 0.747, 0.130 and 0.072, respectively, is used. Dust extinction coefficients at 550nm were calculated by using OPAC and prescribed number concentrations for each of the 5 components. Dust backscatter coefficients were calculated from the dust extinction coefficients on the basis of a lidar ratio of 45±3sr at 532nm. We present results of quartz-Raman measurements carried out on the campus of the Gwangju Institute of Science and Technology (35.10°N, 126.53°E) on 15, 16, and 21 March 2010. Copyright © 2015 Elsevier Ltd. All rights reserved.

Design of SOI wavelength filter based on multiple MMIs structures

NASA Astrophysics Data System (ADS)

Hu, Youfang; Gardes, Frédéric Y.; Jenkins, Richard M.; Finlayson, Ewan D.; Mashanovich, Goran Z.; Reed, Graham T.

2011-01-01

SOI based MMIs prove to be versatile photonic structures for optical power splitting/combining, directional coupling, wavelength multiplexing/demultiplexing, etc. Such a structure benefits from relative ease of fabrication, low sensitivity to fabrication error and low temperature dependence. Whilst the majority of previous designs and optimizations investigated single MMIs, there is significant potential to combine MMIs within a single device for the realization of improved device performance. We have designed and simulated a wavelength filter device consisting of a series of MMIs with different lengths. The bandwidth, free spectral range, and extinction ratio can be controlled by changing the MMI's width and length. We have optimized our design to achieve a -3dB bandwidth of 5nm, a free spectral range of 60nm, an extinction ratio of >30dB, and a side peak suppression ratio of >22dB. Such a device can be used for high performance coarse wavelength filtering. The whole structure can fit into a 70μm×300μm area. Temperature sensitivity of the designed structures was also investigated.

TEMPLATES: Targeting Extremely Magnified Panchromatic Lensed Arcs and Their Extended Star Formation

NASA Astrophysics Data System (ADS)

Rigby, Jane; Vieira, Joaquin; Bayliss, M.; Fischer, T.; Florian, M.; Gladders, M.; Gonzalez, A.; Law, D.; Marrone, D.; Phadke, K.; Sharon, K.; Spilker, J.

2017-11-01

We propose high signal-to-noise NIRSpec and MIRI IFU spectroscopy, with accompanying imaging, for 4 gravitationally lensed galaxies at 1

Snow stratigraphic heterogeneity within ground-based passive microwave radiometer footprints: Implications for emission modeling

NASA Astrophysics Data System (ADS)

Rutter, Nick; Sandells, Mel; Derksen, Chris; Toose, Peter; Royer, Alain; Montpetit, Benoit; Langlois, Alex; Lemmetyinen, Juha; Pulliainen, Jouni

2014-03-01

Two-dimensional measurements of snowpack properties (stratigraphic layering, density, grain size, and temperature) were used as inputs to the multilayer Helsinki University of Technology (HUT) microwave emission model at a centimeter-scale horizontal resolution, across a 4.5 m transect of ground-based passive microwave radiometer footprints near Churchill, Manitoba, Canada. Snowpack stratigraphy was complex (between six and eight layers) with only three layers extending continuously throughout the length of the transect. Distributions of one-dimensional simulations, accurately representing complex stratigraphic layering, were evaluated using measured brightness temperatures. Large biases (36 to 68 K) between simulated and measured brightness temperatures were minimized (-0.5 to 0.6 K), within measurement accuracy, through application of grain scaling factors (2.6 to 5.3) at different combinations of frequencies, polarizations, and model extinction coefficients. Grain scaling factors compensated for uncertainty relating optical specific surface area to HUT effective grain size inputs and quantified relative differences in scattering and absorption properties of various extinction coefficients. The HUT model required accurate representation of ice lenses, particularly at horizontal polarization, and large grain scaling factors highlighted the need to consider microstructure beyond the size of individual grains. As variability of extinction coefficients was strongly influenced by the proportion of large (hoar) grains in a vertical profile, it is important to consider simulations from distributions of one-dimensional profiles rather than single profiles, especially in sub-Arctic snowpacks where stratigraphic variability can be high. Model sensitivity experiments suggested that the level of error in field measurements and the new methodological framework used to apply them in a snow emission model were satisfactory. Layer amalgamation showed that a three-layer representation of snowpack stratigraphy reduced the bias of a one-layer representation by about 50%.

Characterization of smoke and dust episode over West Africa: comparison of MERRA-2 modeling with multiwavelength Mie-Raman lidar observations

NASA Astrophysics Data System (ADS)

Veselovskii, Igor; Goloub, Philippe; Podvin, Thierry; Tanre, Didier; da Silva, Arlindo; Colarco, Peter; Castellanos, Patricia; Korenskiy, Mikhail; Hu, Qiaoyun; Whiteman, David N.; Pérez-Ramírez, Daniel; Augustin, Patrick; Fourmentin, Marc; Kolgotin, Alexei

2018-02-01

Observations of multiwavelength Mie-Raman lidar taken during the SHADOW field campaign are used to analyze a smoke-dust episode over West Africa on 24-27 December 2015. For the case considered, the dust layer extended from the ground up to approximately 2000 m while the elevated smoke layer occurred in the 2500-4000 m range. The profiles of lidar measured backscattering, extinction coefficients, and depolarization ratios are compared with the vertical distribution of aerosol parameters provided by the Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2). The MERRA-2 model simulated the correct location of the near-surface dust and elevated smoke layers. The values of modeled and observed aerosol extinction coefficients at both 355 and 532 nm are also rather close. In particular, for the episode reported, the mean value of difference between the measured and modeled extinction coefficients at 355 nm is 0.01 km-1 with SD of 0.042 km-1. The model predicts significant concentration of dust particles inside the elevated smoke layer, which is supported by an increased depolarization ratio of 15 % observed in the center of this layer. The modeled at 355 nm the lidar ratio of 65 sr in the near-surface dust layer is close to the observed value (70 ± 10) sr. At 532 nm, however, the simulated lidar ratio (about 40 sr) is lower than measurements (55 ± 8 sr). The results presented demonstrate that the lidar and model data are complimentary and the synergy of observations and models is a key to improve the aerosols characterization.

Characterization of soot properties in two-meter JP-8 pool fires.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suo-Anttila, Jill Marie; Jensen, Kirk A.; Blevins, Linda Gail

2005-02-01

The thermal hazard posed by large hydrocarbon fires is dominated by the radiative emission from high temperature soot. Since the optical properties of soot, especially in the infrared region of the electromagnetic spectrum, as well as its morphological properties, are not well known, efforts are underway to characterize these properties. Measurements of these soot properties in large fires are important for heat transfer calculations, for interpretation of laser-based diagnostics, and for developing soot property models for fire field models. This research uses extractive measurement diagnostics to characterize soot optical properties, morphology, and composition in 2 m pool fires. For measurementmore » of the extinction coefficient, soot extracted from the flame zone is transported to a transmission cell where measurements are made using both visible and infrared lasers. Soot morphological properties are obtained by analysis via transmission electron microscopy of soot samples obtained thermophoretically within the flame zone, in the overfire region, and in the transmission cell. Soot composition, including carbon-to-hydrogen ratio and polycyclic aromatic hydrocarbon concentration, is obtained by analysis of soot collected on filters. Average dimensionless extinction coefficients of 8.4 {+-} 1.2 at 635 nm and 8.7 {+-} 1.1 at 1310 nm agree well with recent measurements in the overfire region of JP-8 and other fuels in lab-scale burners and fires. Average soot primary particle diameters, radius of gyration, and fractal dimensions agree with these recent studies. Rayleigh-Debye-Gans theory of scattering applied to the measured fractal parameters shows qualitative agreement with the trends in measured dimensionless extinction coefficients. Results of the density and chemistry are detailed in the report.« less

Irrigation management with remote sensing. [Navajo Indian Irrigation Project

NASA Technical Reports Server (NTRS)

Harlan, C.; Heilman, J. L.; Moore, D.; Myers, V. (Principal Investigator)

1982-01-01

Two visible/near IR hand held radiometers and a hand held thermoradiometer were used along with soil moisture and lysimetric measurements in a study of soil moisture distribution in afalfa fields on the Navajo Indian Irrigation Project near farmington, New Mexico. Radiances from irrigated plots were measured and converted to reflectances. Surface soil water contents (o cm to 4 cm) were determined gravimetrically on samples collected at the same time as the spectral measurements. The relationship between the spectral measurements and the crop coefficient were evaluated to demonstrate potential for using spectral measurement to estimate crop coefficient.

Deriving Cloud Droplet Number Concentration from Combined Airborne Lidar and Polarimeter Measurements from the NAAMES Mission

NASA Astrophysics Data System (ADS)

Hair, J. W.; Hostetler, C. A.; Brian, C.; Ziemba, L. D.; Alexandrov, M. D.; Hu, Y.; Crosbie, E.; Scarino, A. J.; Butler, C. F.; Moore, R.; Berkoff, T.; Harper, D. B.; Cook, A. L.; Hare, R. J.; Lee, J.; Anderson, B. E.

2017-12-01

The NASA Langley High Spectral Resolution lidar (HSRL) and the NASA GISS Research Scanning Polarimeter (RSP) were deployed onboard the NASA C-130 during two field campaigns as part of the NASA's Earth Venture-Suborbital (EVS) North Atlantic Aerosol and Marine Ecosystems Study (NAAMES) during November 2015 and May 2016. The main objectives of NAAMES are to study the phases of the North Atlantic annual plankton cycle and to investigate remote marine aerosols and their impact on boundary layer clouds. Lidar retrievals of the cloud-top extinction and lidar ratio (extinction/backscatter ratio) of boundary layer clouds are presented. These retrievals are unique and are enabled by two characteristics of the lidar: employment of the high-spectral-resolution lidar technique and the high-vertical-resolution (1.25 m) the Langley HSRL instrument. The HSRL lidar ratio retrievals are compared to estimates derived from Research Scanning Polarimeter data to assess consistency between the two remote sensors. The measurements of effective size and variance from RSP are combined with the HSRL cloud top extinction to retrieve the cloud droplet number concentrations (CDNC). The lidar+polarimeter CDNC estimates are compared to those from the Cloud Droplet Probe (CDP) that is part of the NASA Langley Aerosol Research Group Experiment (LARGE) instrument suite. Histograms of the CNDC measurements from remote sensors are shown to highlight the observed differences in CDNC between the November and May deployments.

Retrieving the complex refractive index of atmospheric aerosols from ratios of solar spectral extinction measurements

NASA Technical Reports Server (NTRS)

Fymat, A. L.; Mease, K. D.

1978-01-01

The technique proposed by Fymat (1976) for retrieving the complex refractive index of atmospheric aerosols using narrowband spectral transmission ratios, taken within an overall narrow spectral interval, is investigated in the case of modelled polydispersions of rural, maritime-continental, maritime-sea spray and meteoric dust aerosols. It is confirmed that for not too broad size distributions most of the information comes from a narrow size range of 'active' aerosols so that, under these circumstances, the refractive index components can indeed be retrieved essentially independently of the size distribution. For 0.1% accurate data in three colors, the technique can provide the real and imaginary components of the index respectively within 0.07% and 0.3% accuracy.

Near-Infrared Spectroscopic Study of Supernova Ejecta and Supernova Dust in Cassiopeia A

NASA Astrophysics Data System (ADS)

Lee, Yong-Hyun; Koo, Bon-Chul; Moon, Dae-Sik; Lee, Jae-Joon; Burton, Michael G.

2016-06-01

We have carried out near-infrared (NIR) spectroscopic observations of the Cassiopeia A supernova (SN) remnant. We obtained medium-resolution, JHK (0.95 - 2.46 µm) spectra around the main ejecta shell. Using a clump-finding algorithm, we identified 63 'knots' in the two-dimensional dispersed images, and derived their spectroscopic properties. We first present the result of spectral classification of the knots using Principal Component (PC) Analysis. We found that the NIR spectral characteristics of the knots can be mostly (85%) represented by three PCs composed of different sets of emission lines: (1) recombination lines of H and He together with [N I] lines, (2) forbidden lines of Si, P, and S lines, and (3) forbidden Fe lines. The distribution of the knots in the PC planes matches well with the above spectral groups, and we classified the knots into the three corresponding groups, i.e., He-rich, S-rich, and Fe-rich knots. The kinematic and chemical properties of the former two groups match well with those of Quasi-Stationary Flocculi and Fast-Moving Knots known from optical studies. The Fe-rich knots show intermediate characteristics between the former two groups, and we suggest that they are the SN ejecta material from the innermost layer of the progenitor. We also present the results of extinction measurements using the flux ratios between the two NIR [Fe II] lines at 1.257 and 1.644 µm. We have found a clear correlation between the NIR extinction and the radial velocity of ejecta knots, indicating the presence of a large amount of SN dust inside and around the main ejecta shell. In a southern part of the ejecta shell, by analyzing the NIR extinction together with far-infrared thermal dust emission, we show that there are warm (˜100 K) and cool (˜40 K) SN dust components and that the former needs to be silicate grains while the latter, which is responsible for the observed NIR extinction, could be either small (.0.01 µm) Fe or large (&0.1 µm) Si grains. We suggest that the warm and cool dust components represent grain species produced in diffuse SN ejecta and in dense ejecta clumps, respectively

Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime

NASA Astrophysics Data System (ADS)

Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V.

2012-06-01

Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of <3%. We also quantified the total hemoglobin concentration and hemoglobin oxygen saturation in a live mouse. Compared with the conventional amplitude method, the acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime

PubMed Central

Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro

2012-01-01

Abstract. Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of <3%. We also quantified the total hemoglobin concentration and hemoglobin oxygen saturation in a live mouse. Compared with the conventional amplitude method, the acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed. PMID:22734767

Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime.

PubMed

Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V

2012-06-01

Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of <3%. We also quantified the total hemoglobin concentration and hemoglobin oxygen saturation in a live mouse. Compared with the conventional amplitude method, the acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

The measurement of atmospheric visibility with Lidar: TSC field test results

DOT National Transportation Integrated Search

1974-03-01

The report represents a technical feasibility study of the use of lidar for determining the atmospheric extinction coefficient in low visibility. Measurements were made with three laser sources: a Q-switched ruby laser, a GaAlAs diode laser array, an...

An improved cyan fluorescent protein variant useful for FRET.

PubMed

Rizzo, Mark A; Springer, Gerald H; Granada, Butch; Piston, David W

2004-04-01

Many genetically encoded biosensors use Förster resonance energy transfer (FRET) between fluorescent proteins to report biochemical phenomena in living cells. Most commonly, the enhanced cyan fluorescent protein (ECFP) is used as the donor fluorophore, coupled with one of several yellow fluorescent protein (YFP) variants as the acceptor. ECFP is used despite several spectroscopic disadvantages, namely a low quantum yield, a low extinction coefficient and a fluorescence lifetime that is best fit by a double exponential. To improve the characteristics of ECFP for FRET measurements, we used a site-directed mutagenesis approach to overcome these disadvantages. The resulting variant, which we named Cerulean (ECFP/S72A/Y145A/H148D), has a greatly improved quantum yield, a higher extinction coefficient and a fluorescence lifetime that is best fit by a single exponential. Cerulean is 2.5-fold brighter than ECFP and replacement of ECFP with Cerulean substantially improves the signal-to-noise ratio of a FRET-based sensor for glucokinase activation.

Through-transmission laser welding of glass fibre composite: Experimental light scattering identification

NASA Astrophysics Data System (ADS)

Cosson, Benoit; Asséko, André Chateau Akué; Dauphin, Myriam

2018-05-01

The purpose of this paper is to develop a cost-effective, efficient and quick to implement experimental optical method in order to predict the optical properties (extinction coefficient) of semi-transparent polymer composites. The extinction coefficient takes into account the effects due to the absorption and the scattering phenomena in a semi-transparent component during the laser processes, i.e. TTLW (through-transmission laser welding). The present method used a laser as light source and a reflex camera equipped with a macro lens as a measurement device and is based on the light transmission measurement through different thickness samples. The interaction between the incident laser beam and the semi-transparent composite is exanimated. The results are presented for the case of a semi-transparent composite reinforced with the unidirectional glass fiber (UD). A numerical method, ray tracing, is used to validate the experimental results. The ray tracing method is appropriate to characterize the light-scattering phenomenon in semi-transparent materials.

Experimental Determination of Infrared Extinction Coefficients of Interplanetary Dust Particles

NASA Technical Reports Server (NTRS)

Spann, J. F., Jr.; Abbas, M. M.

1998-01-01

This technique is based on irradiating a single isolated charged dust particle suspended in balance by an electric field, and measuring the scattered radiation as a function of angle. The observed scattered intensity profile at a specific wavelength obtained for a dust particle of known composition is compared with Mie theory calculations, and the variable parameters relating to the particle size and complex refractive index are adjusted for a best fit between the two profiles. This leads to a simultaneous determination of the particle radius, the complex refractive index, and the scattering and extinction coefficients. The results of these experiments can be utilized to examine the IRAS and DIRBE (Diffuse Infrared Background Experiment) infrared data sets in order to determine the dust particle physical characteristics and distributions by using infrared models and inversion techniques. This technique may also be employed for investigation of the rotational bursting phenomena whereby large size cosmic and interplanetary particles are believed to fragment into smaller dust particles.

Pluto's Solar Occultation from New Horizons

NASA Astrophysics Data System (ADS)

Young, Leslie; Kammer, Joshua; Steffl, Andrew J.; Gladstone, Randy; Summers, Michael; Strobel, Darrell F.; Hinson, David P.; Stern, S. Alan; Weaver, Harold A.; Olkin, Catherine; Ennico, Kimberly; McComas, Dave; New Horizons Atmospheres Science Theme Team

2017-10-01

The Alice instrument on NASA’s New Horizons spacecraft observed an ultraviolet solar occultation by Pluto's atmosphere on 2015 July 14. We derived line-of-sight abundances and local number densities for the major species (N2 and CH4) and minor hydrocarbons (C2H2, C2H4, C2H6), and line-of-sight optical depth and extinction coefficients for the haze. Our major conclusions are that (1) we confirmed temperatures in Pluto’s upper atmosphere that were colder than expected before the New Horizons flyby, with upper atmospheric temperatures near 65-68 K, and subsequently lower escape rates, (2) the lower atmosphere was very stable, placing the homopause within 12 km of the surface, (3) the abundance profiles of the “C2Hx hydrocarbons” had non-exponential density profiles that compare favorably with models for hydrocarbon production near 300-400 km and haze condensation near 200 km, and (4) haze had an extinction coefficient approximately proportional to N2 density.This work was supported by NASA’s New Horizons project.

Effect of heat treatment on properties of HfO2 film deposited by ion-beam sputtering

NASA Astrophysics Data System (ADS)

Liu, Huasong; Jiang, Yugang; Wang, Lishuan; Li, Shida; Yang, Xiao; Jiang, Chenghui; Liu, Dandan; Ji, Yiqin; Zhang, Feng; Chen, Deying

2017-11-01

The effects of atmosphere heat treatment on optical, stress, and microstructure properties of an HfO2 film deposited by ion-beam sputtering were systematically researched. The relationships among annealing temperature and refractive index, extinction coefficient, physical thickness, forbidden-band width, tape trailer width, Urbach energy, crystal phase structure, and stress were assessed. The results showed that 400 °C is the transformation point, and the microstructure of the HfO2 film changed from an amorphous into mixed-phase structure. Multistage phonons appeared on the HfO2 film, and the trends of the refractive index, extinction coefficient, forbidden-band width change, and Urbach energy shifted from decrease to increase. With the elevation of the annealing temperature, the film thickness increased monotonously, the compressive stress gradually turned to tensile stress, and the transformation temperature point for the stress was between 200 °C and 300 °C. Therefore, the change in the stress is the primary cause for the shifts in thin-film thickness.

Theory of scattering of electromagnetic waves of the microwave range in a turbid medium

NASA Astrophysics Data System (ADS)

Konstantinov, O. V.; Matveentsev, A. V.

2013-02-01

The coefficient of extinction of electromagnetic waves of the microwave range due to their scattering from clusters suspended in an amorphous medium and responsible for turbidity is calculated. Turbidity resembles the case when butter clusters transform water into milk. In the case under investigation, the clusters are conductors (metallic or semiconducting). The extinction coefficient is connected in a familiar way with the cross section of light scattering from an individual cluster. A new formula is derived for the light scattering cross section in the case when damping of oscillations of an electron is due only to spontaneous emission of light quanta. In this case, the resonant scattering cross section for light can be very large. It is shown that this can be observed only in a whisker nanocluster. In addition, the phonon energy on a whisker segment must be higher than the photon energy, which is close to the spacing between the electron energy levels in the cluster.

Aerosol optical properties retrieved from the future space lidar mission ADM-aeolus

NASA Astrophysics Data System (ADS)

Martinet, Pauline; Flament, Thomas; Dabas, Alain

2018-04-01

The ADM-Aeolus mission, to be launched by end of 2017, will enable the retrieval of aerosol optical properties (extinction and backscatter coefficients essentially) for different atmospheric conditions. A newly developed feature finder (FF) algorithm enabling the detection of aerosol and cloud targets in the atmospheric scene has been implemented. Retrievals of aerosol properties at a better horizontal resolution based on the feature finder groups have shown an improvement mainly on the backscatter coefficient compared to the common 90 km product.

VizieR Online Data Catalog: The ESO DIBs Large Exploration Survey (Cox+, 2017)

NASA Astrophysics Data System (ADS)

Cox, N. L. J.; Cami, J.; Farhang, A.; Smoker, J.; Monreal-Ibero, A.; Lallement, R.; Sarre, P. J.; Marshall, C. C. M.; Smith, K. T.; Evans, C. J.; Royer, P.; Linnartz, H.; Cordiner, M. A.; Joblin, C.; van Loon, J. T.; Foing, B. H.; Bhatt, N. H.; Bron, E.; Elyajouri, M.; de Koter, A.; Ehrenfreund, P.; Javadi, A.; Kaper, L.; Khosroshadi, H. G.; Laverick, M.; Le Petit, F.; Mulas, G.; Roueff, E.; Salama, F.; Spaans, M.

2018-01-01

We constructed a statistically representative survey sample that probes a wide range of interstellar environment parameters including reddening E(B-V), visual extinction AV, total-to-selective extinction ratio RV, and molecular hydrogen fraction fH2. EDIBLES provides the community with optical (~305-1042nm) spectra at high spectral resolution (R~70000 in the blue arm and 100000 in the red arm) and high signal-to-noise (S/N; median value ~500-1000), for a statistically significant sample of interstellar sightlines. Many of the >100 sightlines included in the survey already have auxiliary available ultraviolet, infrared and/or polarisation data on the dust and gas components. (2 data files).

THE MID-INFRARED EXTINCTION LAW IN THE LARGE MAGELLANIC CLOUD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, Jian; Jiang, B. W.; Xue, M. Y.

Based on photometric data from the Spitzer/SAGE survey, using red giants as extinction tracers, the mid-infrared (MIR) extinction laws in the Large Magellanic Cloud (LMC) are derived for the first time in the form of A{sub λ}/A{sub K{sub S}}. This quantity refers to the extinction in the four Infrared Array Camera (IRAC) bands (i.e., [3.6], [4.5], [5.8], and [8.0] μm) relative to the Two Micron All Sky Survey K{sub S} band at 2.16 μm. We obtain the near-infrared extinction coefficient to be E(J – H)/E(H – K{sub S} ) ≈ 1.29 ± 0.04 and E(J – K{sub S} )/E(H –more » K{sub S} ) ≈ 1.94 ± 0.04. The wavelength dependence of the MIR extinction A{sub λ}/A{sub K{sub S}} in the LMC varies from one sightline to another. The overall mean MIR extinction is A{sub [3.6]}/A{sub K{sub S}}∼0.72±0.03, A{sub [4.5]}/A{sub K{sub S}}∼0.94±0.03, A{sub [5.8]}/A{sub K{sub S}}∼0.58±0.04, and A{sub [8.0]}/A{sub K{sub S}}∼0.62±0.05. Except for the extinction in the IRAC [4.5] μm band, which may be contaminated by the 4.6 μm CO gas absorption of red giants used to trace LMC extinction, the extinction in the other three IRAC bands show a flat curve, close to the Milky Way R{sub V} = 5.5 model extinction curve, where R{sub V} is the optical total-to-selective extinction ratio. The possible systematic bias caused by the correlated uncertainties of K{sub S} – λ and J – K{sub S} is explored in terms of Monte Carlo simulations. We find that this bias could lead to an overestimation of A{sub λ}/A{sub K{sub S}} in the MIR.« less

Evaluation of Uncertainties in Measuring Particulate Matter Emission Factors from Atmospheric Fugitive Sources Using Optical Remote Sensing

NASA Astrophysics Data System (ADS)

Yuen, W.; Ma, Q.; Du, K.; Koloutsou-Vakakis, S.; Rood, M. J.

2015-12-01

Measurements of particulate matter (PM) emissions generated from fugitive sources are of interest in air pollution studies, since such emissions vary widely both spatially and temporally. This research focuses on determining the uncertainties in quantifying fugitive PM emission factors (EFs) generated from mobile vehicles using a vertical scanning micro-pulse lidar (MPL). The goal of this research is to identify the greatest sources of uncertainty of the applied lidar technique in determining fugitive PM EFs, and to recommend methods to reduce the uncertainties in this measurement. The MPL detects the PM plume generated by mobile fugitive sources that are carried downwind to the MPL's vertical scanning plane. Range-resolved MPL signals are measured, corrected, and converted to light extinction coefficients, through inversion of the lidar equation and calculation of the lidar ratio. In this research, both the near-end and far-end lidar equation inversion methods are considered. Range-resolved PM mass concentrations are then determined from the extinction coefficient measurements using the measured mass extinction efficiency (MEE) value, which is an intensive PM property. MEE is determined by collocated PM mass concentration and light extinction measurements, provided respectively by a DustTrak and an open-path laser transmissometer. These PM mass concentrations are then integrated with wind information, duration of plume event, and vehicle distance travelled to obtain fugitive PM EFs. To obtain the uncertainty of PM EFs, uncertainties in MPL signals, lidar ratio, MEE, and wind variation are considered. Error propagation method is applied to each of the above intermediate steps to aggregate uncertainty sources. Results include determination of uncertainties in each intermediate step, and comparison of uncertainties between the use of near-end and far-end lidar equation inversion methods.

[Pollution Characteristics and Light Extinction Effects of Water-soluble Ions in PM2.5 During Winter Hazy Days at North Suburban Nanjing].

PubMed

Zhou, Yao-yao; Ma, Yan; Zheng, Jun; Cui, Fen-ping; Wang, Li

2015-06-01

To investigate the characteristics of water-soluble ions in PM2.5 and their contribution to light extinction in haze days, on-line monitoring of PM2.5. was conducted at North Suburban Nanjing from 25 January through 3 February, 2013. Water-soluble components were collected with a particle-into-liquid sampler (PILS), and analyzed by ion chromatography (IC) for the contents of SO4(2-), NO3-, NH4+, Cl-, Na+, K+, Mg2+ and Ca2+ Simultaneously particle size distributions were measured using scanning mobility particle sizer (SMPS) and Aerodynamic Particle Sizer (APS). The absorption and scattering coefficients were measured by three-wavelength photoacoustic soot spectrometer (PASS-3). Trace gases (SO2, NO2 etc.) were also monitored. The results showed that the average concentrations of total water-soluble ions were 70.3 and 22.9 microg x m(-3) in haze and normal days, respectively. Secondary hygroscopic components including SO4(2-), NO3- and NH4+ were the major ionic pollutants. Hazy days favored the conversion of SO2 and NOx, to SO4(2-) and NO3-, respectively, and in particular the oxidation of NOx. Using multiple linear regression statistical method, the empirical relationship between the dry aerosol extinction coefficient and the chemical composition was established. NH4NO3 was found to be the largest contributor to aerosol extinction in winter in Nanjing, followed by (NH4)2SO4, OC and EC. In two heavy pollution events, the increase of ion concentrations was influenced by the increase of primary emissions and secondary transformation.

Effect of structural transformation of C+-ion implanted PMMA into quasi-continuous carbonaceous layer on its optical and electrical properties

NASA Astrophysics Data System (ADS)

Arif, Shafaq; Rafique, M. Shahid; Saleemi, Farhat; Sagheer, Riffat

2018-02-01

The samples of Polymethylmethacrylate (PMMA) have been implanted with 500 keV C+-ions at different ion fluences ranging from 9.3 × 1013 to 8.4 × 1014 ions/cm2. The structural modifications are examined by Fourier Transform Infrared and Raman spectral studies. For the investigation of optical, electrical and surface morphological properties of implanted samples UV-Visible spectrometer, four probe apparatus and optical microscope have been employed. The FTIR spectra confirmed the cleavage of chemicals bonds as a consequence of polymer chain scission, whereas, Raman studies revealed the transformation of PMMA structure into quasi-continuous amorphous carbon with increasing ion fluences. A continuous reduction has been observed in the optical band gap of PMMA from 3.16 to 1.42 eV. Moreover, the refractive index, extinction coefficient and electrical conductivity of implanted PMMA are found to be an increasing function of the ion fluence. The micrographic images revealed the signatures of ion-induced defects like cracking, dehydrogenation, stress and swelling on the surface of PMMA. These implanted samples have a potential to be used in the field of optical communications and thin plastic flexible electronics.

Lateral scattered light used to study laser light propagation in turbid media phantoms

NASA Astrophysics Data System (ADS)

Valdes, Claudia; Solarte, Efrain

2010-02-01

Laser light propagation in soft tissues is important because of the growing biomedical applications of lasers and the need to optically characterize the biological media. Following previous developments of the group, we have developed low cost models, Phantoms, of soft tissue. The process was developed in a clean room to avoid the medium contamination. Each model was characterized by measuring the refractive index, and spectral reflectance and transmittance. To study the laser light propagation, each model was illuminated with a clean beam of laser light, using sources such as He-Ne (632nm) and DPSSL (473 nm). Laterally scattered light was imaged and these images were digitally processed. We analyzed the intensity distribution of the scattered radiation in order to obtain details of the beam evolution in the medium. Line profiles taken from the intensity distribution surface allow measuring the beam spread, and to find expressions for the longitudinal (along the beam incident direction) and transversal (across the beam incident direction) intensities distributions. From these behaviors, the radiation penetration depth and the total coefficient of extinction have been determined. The multiple scattering effects were remarkable, especially for the low wavelength laser beam.

Tailoring density and optical and thermal behavior of gold surfaces and nanoparticles exploiting aromatic dithiols.

PubMed

Bruno, Giovanni; Babudri, Francesco; Operamolla, Alessandra; Bianco, Giuseppe V; Losurdo, Maria; Giangregorio, Maria M; Hassan Omar, Omar; Mavelli, Fabio; Farinola, Gianluca M; Capezzuto, Pio; Naso, Francesco

2010-06-01

Self-assembled monolayers (SAMs) derived of 4-methoxy-terphenyl-3'',5''-dimethanethiol (TPDMT) and 4-methoxyterphenyl-4''-methanethiol (TPMT) have been prepared by chemisorption from solution onto gold thin films and nanoparticles. The SAMs have been characterized by spectroscopic ellipsometry, Raman spectroscopy and atomic force microscopy to determine their optical properties, namely the refractive index and extinction coefficient, in an extended spectral range of 0.75-6.5 eV. From the analysis of the optical data, information on SAMs structural organization has been inferred. Comparison of SAMs generated from the above aromatic thiols to well-known SAMs generated from the alkanethiol dodecanethiol revealed that the former aromatic SAMs are densely packed and highly vertically oriented, with a slightly higher packing density and a absence of molecular inclination in TPMT/Au. The thermal behavior of SAMs has also been monitored using ellipsometry in the temperature range 25-500 degrees C. Gold nanoparticles functionalized by the same aromatic thiols have also been discussed for surface enhanced Raman spectroscopy applications. This study represents a step forward tailoring the optical and thermal behavior of surfaces as well as nanoparticles.

Synthesis, spectroscopic characterization and structural studies of a new proton transfer (H-bonded) complex of o-phenylenediamine with L-tartaric acid

NASA Astrophysics Data System (ADS)

Khan, Ishaat M.; Ahmad, Afaq

2013-10-01

A proton transfer or H-bonded (CT) complex of o-phenylenediamine (OPD) as donor with L-tartaric acid (TART) as acceptor was synthesized and characterized by spectral techniques such as FTIR, 1H NMR, elemental analysis, TGA-TDA, X-ray crystallography and spectrophotometric studies. The structural investigations exhibit that the cation [OPD+] and anion [TART-] are linked together through strong N+-H⋯O- type hydrogen bonds due to transfer of proton from acceptor to donor. Formed H-bonded complex exhibits well resolved proton transfer bands in the regions where neither donor nor acceptor has any absorption. The stoichiometry of the H-bonded complex (HBC) was found to be 1:1, determined by straight line methods. Spectrophotometric studies have been performed at room temperature and Benesi-Hildebrand equation was used to determine formation constant (KCT), molar extinction coefficient (ɛCT) and also transition energy (ECT) of the H-bonded complex. Spectrophotomeric and crystallographic studies have ascertained the formation of 1:1 H-bonded complex. Thermal analysis (TGA-DTA) was also used to confirm the thermal fragmentation and the stability of the synthesized H-bonded complex.

Improving reflectance reconstruction from tristimulus values by adaptively combining colorimetric and reflectance similarities

NASA Astrophysics Data System (ADS)

Cao, Bin; Liao, Ningfang; Li, Yasheng; Cheng, Haobo

2017-05-01

The use of spectral reflectance as fundamental color information finds application in diverse fields related to imaging. Many approaches use training sets to train the algorithm used for color classification. In this context, we note that the modification of training sets obviously impacts the accuracy of reflectance reconstruction based on classical reflectance reconstruction methods. Different modifying criteria are not always consistent with each other, since they have different emphases; spectral reflectance similarity focuses on the deviation of reconstructed reflectance, whereas colorimetric similarity emphasizes human perception. We present a method to improve the accuracy of the reconstructed spectral reflectance by adaptively combining colorimetric and spectral reflectance similarities. The different exponential factors of the weighting coefficients were investigated. The spectral reflectance reconstructed by the proposed method exhibits considerable improvements in terms of the root-mean-square error and goodness-of-fit coefficient of the spectral reflectance errors as well as color differences under different illuminants. Our method is applicable to diverse areas such as textiles, printing, art, and other industries.

Variable extinction in HD 45677 and the evolution of dust grains in pre-main-sequence disks

NASA Technical Reports Server (NTRS)

Sitko, Michael L.; Halbedel, Elaine M.; Lawrence, Geoffrey F.; Smith, J. Allyn; Yanow, Ken

1994-01-01

Changes in the UV extinction and IR emission were sought in the Herbig Ae/Be star candidate HD 45677 (= FS CMa) by comparing UV, optical, and IR observations made approximately 10 yr apart. HD 45677 varied significantly, becoming more than 50% brighter in the UV and optical than it was a decade ago. A comparison of the observations between epochs indicates that if the variations are due to changes in dust obscuration, the dust acts as a gray absorber into the near-IR and must be depleted in grains smaller than 1 micron. This is similar to the results obtained on the circumstellar disks of stars like Vega and Beta Pic, and suggests that radiation pressure may be responsible for the small-grain depletion. In addition, the total IR flux seems to have declined, indicating a decrease in the total mass of the dust envelope that contributes to the IR emission in this part of the spectrum. Due to the anomalous nature of the extinction, the use of normal extinction curves to deredden the spectral energy distributions of stars with circumstellar dust may lead to significant errors and should be used with great caution.

Mapping Surface Water DOC in the Northern Gulf of Mexico Using CDOM Absorption Coefficients and Remote Sensing Imagery

NASA Astrophysics Data System (ADS)

Kelly, B.; Chelsky, A.; Bulygina, E.; Roberts, B. J.

2017-12-01

Remote sensing techniques have become valuable tools to researchers, providing the capability to measure and visualize important parameters without the need for time or resource intensive sampling trips. Relationships between dissolved organic carbon (DOC), colored dissolved organic matter (CDOM) and spectral data have been used to remotely sense DOC concentrations in riverine systems, however, this approach has not been applied to the northern Gulf of Mexico (GoM) and needs to be tested to determine how accurate these relationships are in riverine-dominated shelf systems. In April, July, and October 2017 we sampled surface water from 80+ sites over an area of 100,000 km2 along the Louisiana-Texas shelf in the northern GoM. DOC concentrations were measured on filtered water samples using a Shimadzu TOC-VCSH analyzer using standard techniques. Additionally, DOC concentrations were estimated from CDOM absorption coefficients of filtered water samples on a UV-Vis spectrophotometer using a modification of the methods of Fichot and Benner (2011). These values were regressed against Landsat visible band spectral data for those same locations to establish a relationship between the spectral data, CDOM absorption coefficients. This allowed us to spatially map CDOM absorption coefficients in the Gulf of Mexico using the Landsat spectral data in GIS. We then used a multiple linear regressions model to derive DOC concentrations from the CDOM absorption coefficients and applied those to our map. This study provides an evaluation of the viability of scaling up CDOM absorption coefficient and remote-sensing derived estimates of DOC concentrations to the scale of the LA-TX shelf ecosystem.

Study on laser and infrared attenuation performance of carbon nanotubes

NASA Astrophysics Data System (ADS)

Liu, Xiang-cui; Liu, Qing-hai; Dai, Meng-yan; Cheng, Xiang; Fang, Guo-feng; Zhang, Tong; Liu, Haifeng

2014-11-01

In recent years, the weapon systems of laser and infrared (IR) imaging guidance have been widely used in modern warfare because of their high precision and strong anti-interference. However, military smoke, a rapid and effective passive jamming method, can effectively counteract the attack of precision-guided weapons by their scattering and absorbing effects. The traditional smoke has good visible light (0.4-0.76μm) obscurant performance, but hardly any effects to other electromagnetic wave bands while the weapon systems of laser and IR imaging guidance usually work in broad band, including the near-infrared (1-3μm), middle-infrared (3-5μm), far-infrared (8-14μm), and so on. Accordingly, exploiting new effective obscurant materials has attracted tremendous interest worldwide nowadays. As is known, the nano-structured materials have lots of unique properties comparing with the traditional materials suggesting that they might be the perfect alternatives to solve the problems above. Carbon nanotubes (CNTs) are well-ordered, all-carbon hollow graphitic nano-structured materials with a high aspect ratio, lengths from several hundred nanometers to several millimeters. CNTs possess many unique intrinsic physical-chemical properties and are investigated in many areas reported by the previous studies. However, no application research about CNTs in smoke technology field is reported yet. In this paper, the attenuation performances of CNTs smoke to laser and IR were assessed in 20m3 smoke chamber. The testing wavebands employed in experiments are 1.06μm and 10.6μm laser, 3-5μm and 8-14μm IR radiation. The main parameters were obtained included the attenuation rate, transmission rate, mass extinction coefficient, etc. The experimental results suggest that CNTs smoke exhibits excellent attenuation ability to the broadband IR radiation. Their mass extinction coefficients are all above 1m2·g-1. Nevertheless, the mass extinction coefficients vary with the sampling time and smoke particles concentrations, even in the same testing waveband. With the time going the mass extinction coefficients will increase gradually. Based on the above results, theoretical calculations are also carried out for further exploitations. In general, CNTs smoke behaves excellent attenuation ability toward laser and IR under the experimental conditions. Therefore, they have great potentials to develop new smoke obscurant materials which could effectively interfere with broadband IR radiation including 1.06μm, 10.6μm, 3-5μm and 8-12μm IR waveband.

Improved spectral absorption coefficient grouping strategy of wide band k-distribution model used for calculation of infrared remote sensing signal of hot exhaust systems

NASA Astrophysics Data System (ADS)

Hu, Haiyang; Wang, Qiang

2018-07-01

A new strategy for grouping spectral absorption coefficients, considering the influences of both temperature and species mole ratio inhomogeneities on correlated-k characteristics of the spectra of gas mixtures, has been deduced to match the calculation method of spectral overlap parameter used in multiscale multigroup wide band k-distribution model. By comparison with current spectral absorption coefficient grouping strategies, for which only the influence of temperature inhomogeneity on the correlated-k characteristics of spectra of single species was considered, the improvements in calculation accuracies resulting from the new grouping strategy were evaluated using a series of 0D cases in which radiance under 3-5-μm wave band emitted by hot combustion gas of hydrocarbon fuel was attenuated by atmosphere with quite different temperature and mole ratios of water vapor and carbon monoxide to carbon dioxide. Finally, evaluations are presented on the calculation of remote sensing thermal images of transonic hot jet exhausted from a chevron ejecting nozzle with solid wall cooling system.

Derivation of atmospheric extinction profiles and wind speed over the ocean from a satellite-borne lidar.

PubMed

Weinman, J A

1988-10-01

A simulated analysis is presented that shows that returns from a single-frequency space-borne lidar can be combined with data from conventional visible satellite imagery to yield profiles of aerosol extinction coefficients and the wind speed at the ocean surface. The optical thickness of the aerosols in the atmosphere can be derived from visible imagery. That measurement of the total optical thickness can constrain the solution to the lidar equation to yield a robust estimate of the extinction profile. The specular reflection of the lidar beam from the ocean can be used to determine the wind speed at the sea surface once the transmission of the atmosphere is known. The impact on the retrieved aerosol profiles and surface wind speed produced by errors in the input parameters and noise in the lidar measurements is also considered.

Interstellar Extinction in the Vicinity of the Galactic Center

NASA Technical Reports Server (NTRS)

Cotera, Angela S.; Simpson, Janet P.; Erickson, Edwin F.; Colgan, Sean W. J.; Burton, Michael G.; Allen, David A.

2000-01-01

We present J (1.2 microns), H (1-6 microns), K' (2.11 microns) and Br(gamma) (2.166 microns) images from four large regions within the central 40 pc of the Galaxy. Localized variations in the extinction, as determined by observations of the stellar population, are examined using the median H-K' color as a function of position within each region. As the value of the derived extinction from the stars is dependent upon the intrinsic magnitude of the assumed stellar type, the J-H vs. H-K' diagrams are first used to investigate the distribution of stellar types in the four regions. We find that there is a distinct OB population, contrary to earlier assumptions, with the ratio of K and M giants and supergiants to OB stars approximately twice that of the solar neighborhood. Although the on the scale of approx. l' fluctuations in the extinction are on the order of A(sub V) approx. 2, throughout the entire region the extinction varies from A(sub V) approx. greater than 25 to A(sub V) approx. less than 40. We also examine whether there is any variation in the extinction and stellar number density relative to the usual radio features in these regions and do not find a significant correlation. Spectral imaging in Br(gamma) 2.166 microns emission shows a strong morphological correspondence between the 6 cm radio images and the diffuse Br(gamma) emission. By comparing the theoretical Br(gamma) flux derived from the radio flux using recombination theory, with our measured Br(gamma) flux, we obtain a second, independent, estimate of the extinction. We compare the two data sets and find that the extinction as derived from the stars is consistently greater, sometimes by a factor of two, than the value of the extinction derived from the Br(gamma) images. The derived extinction in various regions, however, is insufficient for any of these regions-to be located behind the molecular clouds as previously observed in the Galactic Center, consistent with the theory that the observed radio emission is produced on the foreground surface of these clouds.

Interstellar Extinction in the Vicinity of the Galactic Center

NASA Technical Reports Server (NTRS)

Cotera, Angela S.; Simpson, Janet P.; Erickson, Edwin F.; Colgan, Sean W. J.

1998-01-01

We present J (1.2 microns) H (1-6 microns) K' (2.11 microns) and Br(gamma) (2.166 microns) images from four large regions within the central 40 pc of the Galaxy. Localized variations in the extinction, as determined by observations of the stellar population, are examined using the median H-K' color as a function of position within each region. As the value of the derived extinction from the stars is dependent upon the intrinsic magnitude of the assumed stellar type, the J-H vs. H-K' diagrams are first used to investigate the distribution of stellar types in the four regions. We find that there is a distinct OB population, contrary to earlier assumptions, with the ratio of K and M giants and supergiants to OB stars approximately twice that of the solar neighborhood. Although the on the scale of approx. 1 min. fluctuations in the extinction are on the order of A(sub V) approx. greater than 2, throughout the entire region the extinction varies from A(sub V) approx. greater than 25 to A(sub V) approx. less than 40. We also examine whether there is any variation in the extinction and stellar number density relative to the unusual radio features in these regions and do not find a significant correlation. Spectral imaging in Br(gamma) 2.166 microns emission shows a strong morphological correspondence between the 6 cm radio images and the diffuse Br(gamma) emission. By comparing the theoretical Br(gamma) flux derived from the radio flux using recombination theory, with our measured Br(gamma) flux, we obtain a second, independent, estimate of the extinction. We compare the two data sets and find that the extinction as derived from the stars is consistently greater, sometimes by a factor of two, than the value of the extinction derived from the Br(gamma) images. The derived extinction in various regions, however, is insufficient for any of these regions to be located behind the molecular clouds as previously observed in the Galactic Center, consistent with the theory that the observed radio emission is produced on the foreground surface of these clouds.

In Situ Measurement of the Infrared Spectral Extinction for Various Chemical, Biological, and Background Aerosols

DTIC Science & Technology

2003-09-01

silicon dioxide that is composed of fine sub- micron SiO2 particles. Used commercially as a thickening agent for food and cosmetics, this silica ... aerogel ” is extremely amorphous (94% of its volume is air) and is sometimes used as a fluidizer to improve aerosol dissemination efficiencies. As a

Infrared extinction and microwave absorption properties of hybrid Fe3O4@SiO2@Ag nanospheres synthesized via a facile seed-mediated growth route.

PubMed

Chen, Yongpeng; Li, Shichuan; Wei, Xuebin; Tang, Runze; Zhou, Zunning

2018-06-21

Fe3O4@SiO2@Ag ternary hybrid nanoparticles were synthesized via a facile seed-mediated growth route. X-ray diffraction (XRD), transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM) measurements were used to characterize the as-prepared product. The results indicated that the nanoparticles exhibited excellent magnetic properties and an extremely dense structure with Ag layer thicknesses of 30 nm, 40 nm, and 50 nm. Furthermore, the microwave shielding effectiveness exceeded 20 dB over almost the entire frequency range (2-18 GHz), and the effectiveness obviously improved as the thickness of the Ag layer increased. In addition, the IR extinction coefficient of the nanoparticles was calculated by a finite-difference time-domain (FDTD) method, which showed that the nanoparticles can inherit the extinction performance of pure silver when the Ag shell thickness was 30 nm. Specifically, after assembling into chains, the peak position of the IR extinction curves displayed a significant redshift and an intensity increase as the number of nanoparticles increased in the chain, which dramatically promoted the IR extinction capability. As a result, the Fe3O4@SiO2@Ag nanoparticles are expected to be used as a new multispectral interference material. © 2018 IOP Publishing Ltd.

Fast monitoring of dissolved organic and suspended matter using data of beam attenuation coefficient in Black Sea

NASA Astrophysics Data System (ADS)

Mankovskaya, E. V.; Korchemkina, E. N.; Latushkin, A. A.

2017-11-01

A method allowing to obtain estimates of dissolved organic and suspended matter content in Black Sea waters using beam attenuation coefficient (BAC) measurements in two spectral channels is proposed. It makes possible to assess the composition, bio-productivity and ecological state of waters in real time, and to validate the data of satellite scanners. The method is based on retrieval the spectral distribution of BAC by orthogonal functions. Full spectral distribution in range 416 - 677 nm allows to select spectral sites with a dominant contribution of certain substance in BAC and to obtain the content of yellow substance and suspended matter using specially designed optimization technique. Calculated values are in good agreement with the satellite data obtained from MODIS scanner.

Determination of particles concentration in Black Sea waters from spectral beam attenuation coefficient

NASA Astrophysics Data System (ADS)

Korchemkina, E. N.; Latushkin, A. A.; Lee, M. E.

2017-11-01

The methods of determination of concentration and scattering by suspended particles in seawater are compared. The methods considered include gravimetric measurements of the mass concentration of suspended matter, empirical and analytical calculations based on measurements of the light beam attenuation coefficient (BAC) in 4 spectral bands, calculation of backscattering by particles using satellite measurements in the visible spectral range. The data were obtained in two cruises of the R/V "Professor Vodyanitsky" in the deep-water part of the Black Sea in July and October 2016., Spatial distribution of scattering by marine particles according to satellite data is in good agreement with the contact measurements.

Evaluation of spatial, radiometric and spectral Thematic Mapper performance for coastal studies

NASA Technical Reports Server (NTRS)

Klemas, V. (Principal Investigator)

1984-01-01

The effect different wetland plant canopies have upon observed reflectance in Thematic Mapper bands is examined. The three major vegetation canopy types (broadleaf, gramineous and leafless) produce unique spectral responses for a similar quantity of live biomass. Biomass estimates computed from spectral data were most similar to biomass estimates determined from harvest data when models developed for a specific canopy were used. Precise determination of regression coefficients for each canopy type and modeling changes in the coefficients with various combinations of canopy types are being tested. The multispectral band scanner vegetation index estimates are very similar to the vegetation index estimates.

Generation of vector dissipative and conventional solitons in large normal dispersion regime.

PubMed

Yun, Ling

2017-08-07

We report the generation of both polarization-locked vector dissipative soliton and group velocity-locked vector conventional soliton in a nanotube-mode-locked fiber ring laser with large normal dispersion, for the first time to our best knowledge. Depending on the polarization-depended extinction ratio of the fiber-based Lyot filter, the two types of vector solitons can be switched by simply tuning the polarization controller. In the case of low filter extinction ratio, the output vector dissipative soliton exhibits steep spectral edges and strong frequency chirp, which presents a typical pulse duration of ~23.4 ps, and can be further compressed to ~0.9 ps. In the contrastive case of high filter extinction ratio, the vector conventional soliton has clear Kelly sidebands with transform-limited pulse duration of ~1.8 ps. Our study provides a new and simple method to achieve two different vector soliton sources, which is attractive for potential applications requiring different pulse profiles.

The Sun-Earth connect 3: lessons from the periodicities of deep time influencing sea-level change and marine extinctions in the geological record.

PubMed

Baker, Robert Gv; Flood, Peter G

2015-01-01

A number of papers since Rampino and Stothers published in Science 1984 have reported common periodicities in a wide range of climate, geomagnetic, tectonic and biological proxies, including marine extinctions. Single taper and multitaper spectral analysis of marine fluctuations between the Late Cretaceous and the Miocene replicates a number of the published harmonics. Whereas these common periodicities have been argued to have a galactic origin, this paper presents an alternative fractal model based on large scale fluctuations of the magnetic field of the Sun. The fluctuations follow a self-similar matrix of periodicities and the solutions of the differential equation allow for models to be constructed predicting extreme events for solar emissions. A comparison to major Phanerozoic extinction, climate and geomagnetic events, captured in the geological record, show a striking loop symmetry summarised in major 66 Ma irradiance and electromagnetic pulses from the Sun.

On the Time Variation of Dust Extinction and Gas Absorption for Type Ia Supernovae Observed through a Nonuniform Interstellar Medium

NASA Astrophysics Data System (ADS)

Huang, X.; Aldering, G.; Biederman, M.; Herger, B.

2017-11-01

For Type Ia supernovae (SNe Ia) observed through a nonuniform interstellar medium (ISM) in its host galaxy, we investigate whether the nonuniformity can cause observable time variations in dust extinction and in gas absorption due to the expansion of the SN photosphere with time. We show that, owing to the steep spectral index of the ISM density power spectrum, sizable density fluctuation amplitudes at the length scale of typical ISM structures (≳ 10 {pc}) will translate to much smaller fluctuations on the scales of an SN photosphere. Therefore, the typical amplitude of time variation due to a nonuniform ISM, of absorption equivalent widths, and of extinction, would be small. As a result, we conclude that nonuniform ISM density should not impact cosmology measurements based on SNe Ia. We apply our predictions based on the ISM density power-law power spectrum to the observations of two highly reddened SNe Ia, SN 2012cu and SN 2014J.

On the Time Variation of Dust Extinction and Gas Absorption for Type Ia Supernovae Observed Through Non-uniform Interstellar Medium

NASA Astrophysics Data System (ADS)

Huang, Xiaosheng; Aldering, Gregory; Biederman, Moriah; Herger, Brendan

2018-01-01

For Type Ia supernovae (SNe Ia) observed through a non-uniform interstellar medium (ISM) in its host galaxy, we investigate whether the non-uniformity can cause observable time variations in dust extinction and in gas absorption due to the expansion of the SN photosphere with time. We show that, owing to the steep spectral index of the ISM density power spectrum, sizable density fluctuation amplitudes at the length scale of typical ISM structures (>~ 10 pc) will translate to much smaller fluctuations on the scales of a SN photosphere. Therefore the typical amplitude of time variation due to non-uniform ISM, of absorption equivalent widths and of extinction, would be small. As a result, we conclude that non-uniform ISM density should not impact cosmology measurements based on SNe Ia. We apply our predictions based on the ISM density power law power spectrum to the observations of two highly reddened SNe Ia, SN 2012cu and SN 2014J.

Correction method for influence of tissue scattering for sidestream dark-field oximetry using multicolor LEDs

NASA Astrophysics Data System (ADS)

Kurata, Tomohiro; Oda, Shigeto; Kawahira, Hiroshi; Haneishi, Hideaki

2016-12-01

We have previously proposed an estimation method of intravascular oxygen saturation (SO_2) from the images obtained by sidestream dark-field (SDF) imaging (we call it SDF oximetry) and we investigated its fundamental characteristics by Monte Carlo simulation. In this paper, we propose a correction method for scattering by the tissue and performed experiments with turbid phantoms as well as Monte Carlo simulation experiments to investigate the influence of the tissue scattering in the SDF imaging. In the estimation method, we used modified extinction coefficients of hemoglobin called average extinction coefficients (AECs) to correct the influence from the bandwidth of the illumination sources, the imaging camera characteristics, and the tissue scattering. We estimate the scattering coefficient of the tissue from the maximum slope of pixel value profile along a line perpendicular to the blood vessel running direction in an SDF image and correct AECs using the scattering coefficient. To evaluate the proposed method, we developed a trial SDF probe to obtain three-band images by switching multicolor light-emitting diodes and obtained the image of turbid phantoms comprised of agar powder, fat emulsion, and bovine blood-filled glass tubes. As a result, we found that the increase of scattering by the phantom body brought about the decrease of the AECs. The experimental results showed that the use of suitable values for AECs led to more accurate SO_2 estimation. We also confirmed the validity of the proposed correction method to improve the accuracy of the SO_2 estimation.

Oxazine dye-conjugated dna oligonucleotides: Förster resonance energy transfer in view of molecular dye-DNA interactions.

PubMed

Kupstat, Annette; Ritschel, Thomas; Kumke, Michael U

2011-12-21

In this work, the photophysical properties of two oxazine dyes (ATTO 610 and ATTO 680) covalently attached via a C6-amino linker to the 5'-end of short single-stranded as well as double-stranded DNA (ssDNA and dsDNA, respectively) of different lengths were investigated. The two oxazine dyes were chosen because of the excellent spectral overlap, the high extinction coefficients, and the high fluorescence quantum yield of ATTO 610, making them an attractive Förster resonance energy transfer (FRET) pair for bioanalytical applications in the far-red spectral range. To identify possible molecular dye-DNA interactions that cause photophysical alterations, we performed a detailed spectroscopic study, including time-resolved fluorescence anisotropy and fluorescence correlation spectroscopy measurements. As an effect of the DNA conjugation, the absorption and fluorescence maxima of both dyes were bathochromically shifted and the fluorescence decay times were increased. Moreover, the absorption of conjugated ATTO 610 was spectrally broadened, and a dual fluorescence emission was observed. Steric interactions with ssDNA as well as dsDNA were found for both dyes. The dye-DNA interactions were strengthened from ssDNA to dsDNA conjugates, pointing toward interactions with specific dsDNA domains (such as the top of the double helix). Although these interactions partially blocked the dye-linker rotation, a free (unhindered) rotational mobility of at least one dye facilitated the appropriate alignment of the transition dipole moments in doubly labeled ATTO 610/ATTO 680-dsDNA conjugates for the performance of successful FRET. Considering the high linker flexibility for the determination of the donor-acceptor distances, good accordance between theoretical and experimental FRET parameters was obtained. The considerably large Förster distance of ~7 nm recommends the application of this FRET pair not only for the detection of binding reactions between nucleic acids in living cells but also for monitoring interactions of larger biomolecules such as proteins.

Inversion of solar extinction data from the Apollo-Soyuz Test Project Stratospheric Aerosol Measurement (ASTP/SAM) experiment

NASA Technical Reports Server (NTRS)

Pepin, T. J.

1977-01-01

The inversion methods are reported that have been used to determine the vertical profile of the extinction coefficient due to the stratospheric aerosols from data measured during the ASTP/SAM solar occultation experiment. Inversion methods include the onion skin peel technique and methods of solving the Fredholm equation for the problem subject to smoothing constraints. The latter of these approaches involves a double inversion scheme. Comparisons are made between the inverted results from the SAM experiment and near simultaneous measurements made by lidar and balloon born dustsonde. The results are used to demonstrate the assumptions required to perform the inversions for aerosols.

Population dynamical behavior of Lotka-Volterra system under regime switching

NASA Astrophysics Data System (ADS)

Li, Xiaoyue; Jiang, Daqing; Mao, Xuerong

2009-10-01

In this paper, we investigate a Lotka-Volterra system under regime switching where B(t) is a standard Brownian motion. The aim here is to find out what happens under regime switching. We first obtain the sufficient conditions for the existence of global positive solutions, stochastic permanence and extinction. We find out that both stochastic permanence and extinction have close relationships with the stationary probability distribution of the Markov chain. The limit of the average in time of the sample path of the solution is then estimated by two constants related to the stationary distribution and the coefficients. Finally, the main results are illustrated by several examples.

Spectral Classification of Heavily Reddened Stars by CO Absorption Strength

NASA Astrophysics Data System (ADS)

Garling, Christopher; Bary, Jeffrey S.; Huard, Tracy L.

2017-01-01

The nature of dust grains in dense molecular clouds can be explored by obtaining spectra of giant stars located behind the clouds and examining the wavelength-dependent attentuation of their light. This approach requires the intrinsic spectra of the background stars to be known, which can be achieved by determining their spectral types. In the K-band spectra of cool giant stars, several temperature-sensitive CO absorption bands serve as good spectral type indicators. Taking advantage of the SpeX Infrared Telescope Facility Spectral Library, near-infrared spectra collected with TripleSpec and the 3.5-meter ARC Telescope at Apache Point Observatory, and a previously constructed CO spectral index, we make precise spectral determinations of 20 giant stars located behind two dense cloud cores: CB188 and L429C. With spectral types in hand, we then utilize Markov Chain Monte Carlo techniques to constrain extinctions along these lines of sight. The spectral typing method will be described and assessed as well as its success at finding a couple of incorrectly spectral typed stars in the SpeX Library. Funding for this program was provided by a NSF REU grant to the Keck Northeast Astronomy Consortium and a grant from the NASA Astrophysics Data Analysis Program.

Effect of conditioned stimulus exposure during slow wave sleep on fear memory extinction in humans.

PubMed

He, Jia; Sun, Hong-Qiang; Li, Su-Xia; Zhang, Wei-Hua; Shi, Jie; Ai, Si-Zhi; Li, Yun; Li, Xiao-Jun; Tang, Xiang-Dong; Lu, Lin

2015-03-01

Repeated exposure to a neutral conditioned stimulus (CS) in the absence of a noxious unconditioned stimulus (US) elicits fear memory extinction. The aim of the current study was to investigate the effects of mild tone exposure (CS) during slow wave sleep (SWS) on fear memory extinction in humans. The healthy volunteers underwent an auditory fear conditioning paradigm on the experimental night, during which tones served as the CS, and a mild shock served as the US. They were then randomly assigned to four groups. Three groups were exposed to the CS for 3 or 10 min or an irrelevant tone (control stimulus, CtrS) for 10 min during SWS. The fourth group served as controls and was not subjected to any interventions. All of the subjects completed a memory test 4 h after SWS-rich stage to evaluate the effect on fear extinction. Moreover, we conducted similar experiments using an independent group of subjects during the daytime to test whether the memory extinction effect was specific to the sleep condition. Ninety-six healthy volunteers (44 males) aged 18-28 y. Participants exhibited undisturbed sleep during 2 consecutive nights, as assessed by sleep variables (all P > 0.05) from polysomnographic recordings and power spectral analysis. Participants who were re-exposed to the 10 min CS either during SWS and wakefulness exhibited attenuated fear responses (wake-10 min CS, P < 0.05; SWS-10 min CS, P < 0.01). Conditioned stimulus re-exposure during SWS promoted fear memory extinction without altering sleep profiles. © 2015 Associated Professional Sleep Societies, LLC.

Nonautonomous solitons for an extended forced Korteweg-de Vries equation with variable coefficients in the fluid or plasma

NASA Astrophysics Data System (ADS)

Wang, Yong-Yan; Su, Chuan-Qi; Liu, Xue-Qing; Li, Jian-Guang

2018-07-01

Under investigation in this paper is an extended forced Korteweg-de Vries equation with variable coefficients in the fluid or plasma. Lax pair, bilinear forms, and bilinear Bäcklund transformations are derived. Based on the bilinear forms, the first-, second-, and third-order nonautonomous soliton solutions are derived. Propagation and interaction of the nonautonomous solitons are investigated and influence of the variable coefficients is also discussed: Amplitude of the first-order nonautonomous soliton is determined by the spectral parameter and perturbed factor; there exist two kinds of the solitons, namely the elevation and depression solitons, depending on the sign of the spectral parameter; the background where the nonautonomous soliton exists is influenced by the perturbed factor and external force coefficient; breather solutions can be constructed under the conjugate condition, and period of the breather is related to the dispersive and nonuniform coefficients.

Influence of water vapour and permanent gases on the atmospheric optical depths and transmittance

NASA Astrophysics Data System (ADS)

Badescu, V.

1991-05-01

The influence of the atmospheric state on the extinction of direct solar radiation has been studied by using a four layer atmospheric model. Simple analytical formulae are established for the spectral optical depths of permanent gases and water vapour. These formulae use the ground level values of air pressure, temperature and relative huniidity. An additional parameter, related to the vertical distribution of the hunmidity content, is used for a better estimation of the water vapour optical depth. Good agreement between theory and measurements is found. The paper shows the dependence of the atmospheric spectral transmittance on the above mentioned parameters. L'influence de l'état atmosphérique sur l'extinction de la radiation solaire directe a été étudiée à l'aide d'un modèle atmosphérique développé antérieurement par l'auteur. Des formules simples ont été établies pour l'épaisseur optique spectrale des gaz et de la vapeur d'eau. Ces formules utilisent les valeurs de la pression atmosphérique, de la température et de l'humidité relative, mesurées au niveau du sol. Un paramètre supplémentaire, lié à la distribution verticale du contenu d'humidité, est utilisé pour calculer l'épaisseur optique due à la vapeur d'eau. La théorie est en bon accord avec les résultats des mesures. Le travail montre la dépendance de la transmittance atmosphérique spectrale en fonction des paramètres spécifiés ci-dessus.

Crop parameters for modeling sugarcane under rainfed conditions in Mexico

USDA-ARS?s Scientific Manuscript database

Crop models with well-tested parameters can improve sugarcane productivity for food and biofuel generation. This study aimed to (i) calibrate the light extinction coefficient (k) and other crop parameters for the sugarcane cultivar CP 72-2086, an early-maturing cultivar grown in Mexico and many oth...

Efficient iodine-free dye-sensitized solar cells employing truxene-based organic dyes.

PubMed

Zong, Xueping; Liang, Mao; Chen, Tao; Jia, Jiangnan; Wang, Lina; Sun, Zhe; Xue, Song

2012-07-07

Two new truxene-based organic sensitizers (M15 and M16) featuring high extinction coefficients were synthesized for dye-sensitized solar cells employing cobalt electrolyte. The M16-sensitized device displays a 7.6% efficiency at an irradiation of AM1.5 full sunlight.

Radical Recombination Kinetics: An Experiment in Physical Organic Chemistry.

ERIC Educational Resources Information Center

Pickering, Miles

1980-01-01

Describes a student kinetic experiment involving second order kinetics as well as displaying photochromism using a wide variety of techniques from both physical and organic chemistry. Describes measurement of (1) the rate of the recombination reaction; (2) the extinction coefficient; and (3) the ESR spectrometer signal. (Author/JN)

Quantitative retrieval of aerosol optical properties by means of ceilometers

NASA Astrophysics Data System (ADS)

Wiegner, Matthias; Gasteiger, Josef; Geiß, Alexander

2016-04-01

In the last few years extended networks of ceilometers have been established by several national weather services. Based on improvements of the hardware performance of these single-wavelength backscatter lidars and their 24/7 availability they are increasingly used to monitor mixing layer heights and to derive profiles of the particle backscatter profile. As a consequence they are used for a wide range of applications including the dispersion of volcanic ash plumes, validation of chemistry transport models and air quality studies. In this context the development of automated schemes to detect aerosol layers and to identify the mixing layer are essential, in particular as the latter is often used as a proxy for air quality. Of equal importance is the calibration of ceilometer signals as a pre-requisite to derive quantitative optical properties. Recently, it has been emphasized that the majority of ceilometers are influenced by water vapor absorption as they operate in the spectral range of 905 - 910 nm. If this effect is ignored, errors of the aerosol backscatter coefficient can be as large as 50%, depending on the atmospheric water vapor content and the emitted wavelength spectrum. As a consequence, any other derived quantity, e.g. the extinction coefficient or mass concentration, would suffer from a significant uncertainty in addition to the inherent errors of the inversion of the lidar equation itself. This can be crucial when ceilometer derived profiles shall be used to validate transport models. In this presentation, the methodology proposed by Wiegner and Gasteiger (2015) to correct for water vapor absorption is introduced and discussed.

Cap integration in spectral gravity forward modelling: near- and far-zone gravity effects via Molodensky's truncation coefficients

NASA Astrophysics Data System (ADS)

Bucha, Blažej; Hirt, Christian; Kuhn, Michael

2018-04-01

Spectral gravity forward modelling is a technique that converts a band-limited topography into its implied gravitational field. This conversion implicitly relies on global integration of topographic masses. In this paper, a modification of the spectral technique is presented that provides gravity effects induced only by the masses located inside or outside a spherical cap centred at the evaluation point. This is achieved by altitude-dependent Molodensky's truncation coefficients, for which we provide infinite series expansions and recurrence relations with a fixed number of terms. Both representations are generalized for an arbitrary integer power of the topography and arbitrary radial derivative. Because of the altitude-dependency of the truncation coefficients, a straightforward synthesis of the near- and far-zone gravity effects at dense grids on irregular surfaces (e.g. the Earth's topography) is computationally extremely demanding. However, we show that this task can be efficiently performed using an analytical continuation based on the gradient approach, provided that formulae for radial derivatives of the truncation coefficients are available. To demonstrate the new cap-modified spectral technique, we forward model the Earth's degree-360 topography, obtaining near- and far-zone effects on gravity disturbances expanded up to degree 3600. The computation is carried out on the Earth's surface and the results are validated against an independent spatial-domain Newtonian integration (1 μGal RMS agreement). The new technique is expected to assist in mitigating the spectral filter problem of residual terrain modelling and in the efficient construction of full-scale global gravity maps of highest spatial resolution.

Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feng, Y.; Kotamarthi, V. R.; Coulter, R.

Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profilesmore » averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48% more heating in the atmosphere and 21% more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7K day −1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II, underlining the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. Additionally, the model results suggest that both the direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feng, Y.; Kotamarthi, V. R.; Coulter, R.

Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore » and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day −1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II underlying the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

DOE PAGES

Feng, Y.; Kotamarthi, V. R.; Coulter, R.; ...

2016-01-18

Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profilesmore » averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48% more heating in the atmosphere and 21% more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7K day −1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II, underlining the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. Additionally, the model results suggest that both the direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feng, Y.; Kotamarthi, V. R.; Coulter, R.

Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profilesmore » averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day −1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II, underlining the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both the direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

DOE PAGES

Feng, Y.; Kotamarthi, V. R.; Coulter, R.; ...

2015-06-19

Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore » and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day −1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II underlying the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

Development and Validation of a New Fallout Transport Method Using Variable Spectral Winds

NASA Astrophysics Data System (ADS)

Hopkins, Arthur Thomas

A new method has been developed to incorporate variable winds into fallout transport calculations. The method uses spectral coefficients derived by the National Meteorological Center. Wind vector components are computed with the coefficients along the trajectories of falling particles. Spectral winds are used in the two-step method to compute dose rate on the ground, downwind of a nuclear cloud. First, the hotline is located by computing trajectories of particles from an initial, stabilized cloud, through spectral winds, to the ground. The connection of particle landing points is the hotline. Second, dose rate on and around the hotline is computed by analytically smearing the falling cloud's activity along the ground. The feasibility of using specgtral winds for fallout particle transport was validated by computing Mount St. Helens ashfall locations and comparing calculations to fallout data. In addition, an ashfall equation was derived for computing volcanic ash mass/area on the ground. Ashfall data and the ashfall equation were used to back-calculate an aggregated particle size distribution for the Mount St. Helens eruption cloud. Further validation was performed by comparing computed and actual trajectories of a high explosive dust cloud (DIRECT COURSE). Using an error propagation formula, it was determined that uncertainties in spectral wind components produce less than four percent of the total dose rate variance. In summary, this research demonstrated the feasibility of using spectral coefficients for fallout transport calculations, developed a two-step smearing model to treat variable winds, and showed that uncertainties in spectral winds do not contribute significantly to the error in computed dose rate.

Visualization of hemodynamics and light scattering in exposed brain of rat using multispectral image reconstruction based on Wiener estimation method

NASA Astrophysics Data System (ADS)

Nishidate, Izumi; Ishizuka, Tomohiro; Yoshida, Keiichiro; Kawauchi, Satoko; Sato, Shunichi; Sato, Manabu

2015-07-01

We investigate a method to estimate the spectral images of reduced scattering coefficients and the absorption coefficients of in vivo exposed brain tissues in the range from visible to near-infrared wavelength (500-760 nm) based on diffuse reflectance spectroscopy using a digital RGB camera. In the proposed method, the multi-spectral reflectance images of in vivo exposed brain are reconstructed from the digital red, green, blue images using the Wiener estimation algorithm. The Monte Carlo simulation-based multiple regression analysis for the absorbance spectra is then used to specify the absorption and scattering parameters of brain tissue. In this analysis, the concentration of oxygenated hemoglobin and that of deoxygenated hemoglobin are estimated as the absorption parameters whereas the scattering amplitude a and the scattering power b in the expression of μs'=aλ-b as the scattering parameters, respectively. The spectra of absorption and reduced scattering coefficients are reconstructed from the absorption and scattering parameters, and finally, the spectral images of absorption and reduced scattering coefficients are estimated. We performed simultaneous recordings of spectral diffuse reflectance images and of the electrophysiological signals for in vivo exposed rat brain during the cortical spreading depression evoked by the topical application of KCl. Changes in the total hemoglobin concentration and the tissue oxygen saturation imply the temporary change in cerebral blood flow during CSD. Change in the reduced scattering coefficient was observed before the profound increase in the total hemoglobin concentration, and its occurrence was synchronized with the negative dc shift of the local field potential.

Infrared absorption-coefficient data on SF6 applicable to atmospheric remote sensing

NASA Technical Reports Server (NTRS)

Varanasi, P.; Gopalan, A.; Brannon, J. F., Jr.

1992-01-01

Spectral absorption coefficients, k(nu)/cm per atm, of SF6 have been measured in the central Q-branches of the nu(3)-fundamental at 947/cm at various temperature-pressure combinations representing tangent heights in solar-occultation experiments or layers in the atmosphere. The data obtained with the Doppler-limited spectral resolution (about 0.0001/cm) of a tunable-diode laser spectrometer are useful in the atmospheric remote sensing of this trace gas.

Determining Mass-Loss Rates of Evolved Stars in the Galactic Bulge from Infrared Surveys

NASA Astrophysics Data System (ADS)

Riley, Allyssa; Sargent, Benjamin A.; Srinivasan, Sundar; Meixner, Margaret; Kastner, Joel H.

2018-06-01

To investigate the relationship between mass loss from evolved stars and host galaxy metallicity, we are computing the dust mass loss budget due to red supergiant (RSG) and asymptotic giant branch (AGB) stars in the Galactic Bulge and comparing this result to that previously obtained for the Magellanic Clouds. We construct spectral energy distributions (SEDs) for our candidate RSG and AGB stars using observations from various infrared surveys, including the Galactic Legacy Infrared Mid-Plane Survey Extraordinaire (GLIMPSE). Because Robitaille et al (2008, AJ, 136, 2413) have already identified Intrinsically Red Objects from the GLIMPSE I and II surveys, we use their method as a starting point and expand the study by using the GLIMPSE 3D survey. Because AGB stars can be variable, we also match the GLIMPSE I, II, and 3D sources to other surveys, such as DEEP GLIMPSE, WISE, VVV, and DENIS, in order to characterize the variability across the spectral energy distribution (SED) of each source. This allows us to determine the source’s average SED over multiple epochs. We use extinction curves derived from Spitzer studies of extinction in the Galaxy to determine the extinction corrections for our sample. To establish mass-loss rates of evolved stars in the Bulge, we use the Grid of Red supergiant and Asymptotic giant branch ModelS (GRAMS) of dust-enshrouded evolved stars (2011, A&A, 532, A54; 2011, ApJ, 728, 93). This allows us to determine the total mass return to the Bulge from these stars. This work has been supported by NASA ADAP grant 80NSSC17K0057.

Development of a rapid, simple assay of plasma total carotenoids

PubMed Central

2012-01-01

Background Plasma total carotenoids can be used as an indicator of risk of chronic disease. Laboratory analysis of individual carotenoids by high performance liquid chromatography (HPLC) is time consuming, expensive, and not amenable to use beyond a research laboratory. The aim of this research is to establish a rapid, simple, and inexpensive spectrophotometric assay of plasma total carotenoids that has a very strong correlation with HPLC carotenoid profile analysis. Results Plasma total carotenoids from 29 volunteers ranged in concentration from 1.2 to 7.4 μM, as analyzed by HPLC. A linear correlation was found between the absorbance at 448 nm of an alcohol / heptane extract of the plasma and plasma total carotenoids analyzed by HPLC, with a Pearson correlation coefficient of 0.989. The average coefficient of variation for the spectrophotometric assay was 6.5% for the plasma samples. The limit of detection was about 0.3 μM and was linear up to about 34 μM without dilution. Correlations between the integrals of the absorption spectra in the range of carotenoid absorption and total plasma carotenoid concentration gave similar results to the absorbance correlation. Spectrophotometric assay results also agreed with the calculated expected absorbance based on published extinction coefficients for the individual carotenoids, with a Pearson correlation coefficient of 0.988. Conclusion The spectrophotometric assay of total carotenoids strongly correlated with HPLC analysis of carotenoids of the same plasma samples and expected absorbance values based on extinction coefficients. This rapid, simple, inexpensive assay, when coupled with the carotenoid health index, may be useful for nutrition intervention studies, population cohort studies, and public health interventions. PMID:23006902

A 3-D mid-infrared view of the central parsec

NASA Astrophysics Data System (ADS)

Moultaka, J.; Eckart, A.; Mužić, K.; Sabha, N.

2014-05-01

We present a mid-infrared 3D view of the central parsec using ISAAC spectrograph (ESO/VLT) with its spectroscopic mode. We mapped the central parsec in L- and M-bands by using 27 and 21 slit positions, respectively, that allowed us to build two data cubes of the region in these spectral domains. We also use an original method to distinguish the contribution of the foreground extinction to the absorbed spectra from that of the local extinction in both wavelength ranges. We find that there are residual water and CO ices in the central parsec as well as hydrocarbons and gaseous CO implying very low temperatures of the order of tens of Kelvin in the local environment of Sgr A*.

A new method to determine the interstellar reddening towards WN stars

NASA Technical Reports Server (NTRS)

Conti, Peter S.; Morris, Patrick W.

1990-01-01

An empirical approach to determine the redding in WN stars is presented, in which the measured strengths of the emission lines of He II at 1640 and 4686 A are used to estimate the extinction. The He II emission lines at these wavelengths are compared for a number of WN stars in the Galaxy and the LMC. It is shown that the equivalent width ratios are single valued and are independent of the spectral subtypes. The reddening for stars in the Galaxy is derived using a Galactic extinction law and observed line flux ratios, showing good agreement with previous determinations of reddening. The possible application of the method to study the absorption properties of the interstellar medium in more distant galaxies is discussed.

Using aligned poly(3-hexylthiophene)/poly(methyl methacrylate) blend fibers to detect volatile organic compounds

NASA Astrophysics Data System (ADS)

Chan, Shun-Hsiang; Lin, Tz-Feng; Wu, Ming-Chung; Chen, Shih-Hsuan; Su, Wei-Fang; Lai, Chao-Sung

2018-04-01

In this study, we developed a novel sensing material fabricated using a poly(3-hexylthiophene) (P3HT)/poly(methyl methacrylate) (PMMA) blend fiber on a glass substrate. The sensing materials can easily be used for sensing toluene vapor detected from extinction spectral changes. The extinction spectra variation is noted from the absorption of volatile organic compounds in a highly specific surface area of fibrous coating. An electrospinning technique is applied to generate a nonwoven structure and uniaxial orientation by fibrous coating. The response of the uniaxially orientated fibrous film is even improved at several toluene vapor concentrations. The best detection limit of this well-aligned fibrous film is up to 200 ppm for toluene vapor.

Effects of FeCl3 additives on optical parameters of PVA

NASA Astrophysics Data System (ADS)

Latif, Duha M. A.; Chiad, Sami S.; Erhayief, Muhssen S.; Abass, Khalid H.; Habubi, Nadir F.; Hussin, Hadi A.

2018-05-01

PVA doped FeCl3 have been deposited utilizing casting technique. Absorption spectrum was registered in the wavelengths (300-900 nm) utilizing UV-Visible spectrophotometer. Optical constants behavior such as, absorbance, absorption coefficient, and skin depth were studied. It was found these parameters were increased as Fe content increase. While the extinction coefficient and optical conductivity was decreased. The energy gap of PVA-Fe films were decreased from 4 eV for the PVA film to 3.5 eV for the PVA: 4 % Fe film.

Airborne High Spectral Resolution Lidar Aerosol Measurements during MILAGRO and TEXAQS/GOMACCS

NASA Technical Reports Server (NTRS)

Ferrare, Richard; Hostetler, Chris; Hair, John; Cook Anthony; Harper, David; Burton, Sharon; Clayton, Marian; Clarke, Antony; Russell, Phil; Redemann, Jens

2007-01-01

Two1 field experiments conducted during 2006 provided opportunities to investigate the variability of aerosol properties near cities and the impacts of these aerosols on air quality and radiative transfer. The Megacity Initiative: Local and Global Research Observations (MILAGRO) /Megacity Aerosol Experiment in Mexico City (MAX-MEX)/Intercontinental Chemical Transport Experiment-B (INTEX-B) joint experiment conducted during March 2006 investigated the evolution and transport of pollution from Mexico City. The Texas Air Quality Study (TEXAQS)/Gulf of Mexico Atmospheric Composition and Climate Study (GoMACCS) (http://www.al.noaa.gov/2006/) conducted during August and September 2006 investigated climate and air quality in the Houston/Gulf of Mexico region. During both missions, the new NASA Langley airborne High Spectral Resolution Lidar (HSRL) was deployed on the NASA Langley B200 King Air aircraft and measured profiles of aerosol extinction, backscattering, and depolarization to: 1) characterize the spatial and vertical distributions of aerosols, 2) quantify aerosol extinction and optical thickness contributed by various aerosol types, 3) investigate aerosol variability near clouds, 4) evaluate model simulations of aerosol transport, and 5) assess aerosol optical properties derived from a combination of surface, airborne, and satellite measurements.

Quantum gravity boundary terms from the spectral action of noncommutative space.

PubMed

Chamseddine, Ali H; Connes, Alain

2007-08-17

We study the boundary terms of the spectral action of the noncommutative space, defined by the spectral triple dictated by the physical spectrum of the standard model, unifying gravity with all other fundamental interactions. We prove that the spectral action predicts uniquely the gravitational boundary term required for consistency of quantum gravity with the correct sign and coefficient. This is a remarkable result given the lack of freedom in the spectral action to tune this term.

Measurements of Nascent Soot Using a Cavity Attenauted Phase Shift (CAPS)-based Single Scattering Albedo Monitor

NASA Astrophysics Data System (ADS)

Freedman, A.; Onasch, T. B.; Renbaum-Wollf, L.; Lambe, A. T.; Davidovits, P.; Kebabian, P. L.

2015-12-01

Accurate, as compared to precise, measurement of aerosol absorption has always posed a significant problem for the particle radiative properties community. Filter-based instruments do not actually measure absorption but rather light transmission through the filter; absorption must be derived from this data using multiple corrections. The potential for matrix-induced effects is also great for organic-laden aerosols. The introduction of true in situ measurement instruments using photoacoustic or photothermal interferometric techniques represents a significant advance in the state-of-the-art. However, measurement artifacts caused by changes in humidity still represent a significant hurdle as does the lack of a good calibration standard at most measurement wavelengths. And, in the absence of any particle-based absorption standard, there is no way to demonstrate any real level of accuracy. We, along with others, have proposed that under the circumstance of low single scattering albedo (SSA), absorption is best determined by difference using measurement of total extinction and scattering. We discuss a robust, compact, field deployable instrument (the CAPS PMssa) that simultaneously measures airborne particle light extinction and scattering coefficients and thus the single scattering albedo (SSA) on the same sample volume. The extinction measurement is based on cavity attenuated phase shift (CAPS) techniques as employed in the CAPS PMex particle extinction monitor; scattering is measured using integrating nephelometry by incorporating a Lambertian integrating sphere within the sample cell. The scattering measurement is calibrated using the extinction measurement of non-absorbing particles. For small particles and low SSA, absorption can be measured with an accuracy of 6-8% at absorption levels as low as a few Mm-1. We present new results of the measurement of the mass absorption coefficient (MAC) of soot generated by an inverted methane diffusion flame at 630 nm. A value of 6.60 ±0.2 m2 g-1 was determined where the uncertainty refers to the precision of the measurement. The overall accuracy of the measurement, traceable to the properties of polystyrene latex particles, is estimated to be better than ±10%.

Preliminary results on interstellar reddening as deduced from filter photometry

NASA Technical Reports Server (NTRS)

Laget, M.

1972-01-01

Filter photometry has been used to derive the interstellar reddening law from stars through the study of a single spectral type, B0. The deficiency in the far ultraviolet flux of a supergiant relative to a main sequence star is compared with the difference in the flux distribution due to a change of one spectral class. Individual interstellar reddening curves show the general feature reported by Stecher (1969) and by Bless and Savage (1970). There is a large amount of scatter in the far ultraviolet which may be partially due to a real difference in interstellar extinction and partially due to observational inaccuracy.

Determination of the spectral behaviour of atmospheric soot using different particle models

NASA Astrophysics Data System (ADS)

Skorupski, Krzysztof

2017-08-01

In the atmosphere, black carbon aggregates interact with both organic and inorganic matter. In many studies they are modeled using different, less complex, geometries. However, some common simplification might lead to many inaccuracies in the following light scattering simulations. The goal of this study was to compare the spectral behavior of different, commonly used soot particle models. For light scattering simulations, in the visible spectrum, the ADDA algorithm was used. The results prove that the relative extinction error δCext, in some cases, can be unexpectedly large. Therefore, before starting excessive simulations, it is important to know what error might occur.

A Moderate Resolution NIR Spectral Library of Weak-Lined T Tauri Stars

NASA Astrophysics Data System (ADS)

Cooper, Rachel; Covey, K. R.

2013-01-01

We present a spectral library of high-quality moderate resolution (R ~ 3500) NIR spectra for 44 weak-lined T Tauri Stars (WTTS) in the Taurus-Auriga Molecular Cloud. These spectra, obtained with the TripleSpec spectrograph on the Astrophysical Research Consortium (ARC) 3.5 meter telescope, provide full coverage of the J, H, and K near-infrared bands in a single epoch. Analyzing these spectra, along with those of dwarf and giant spectral type standards from the SpeX Spectral Library, we have identified several elemental and molecular absorption lines that vary in strength with respect to each star's spectral type and luminosity class. Calibrating each of these features as a spectral type indicator, we provide a detailed characterization for each of the WTTSs in our sample, identifying each star's NIR spectral type and line-of-sight extinction, estimated both from the shape of the overall continuum and from the fluxes of the Paschen beta and Brackett gamma emission lines. In addition to improving our understanding of the properties of these WTTSs, this well characterized spectral library will be a valuable resource for analyses of the NIR continuum veiling and line emission present in the spectra of accreting classical T Tauri stars. This research was made possible by NSF Grant AST-1004107.

Infrared spectra and physochemical properties of oils

NASA Astrophysics Data System (ADS)

Strelets, L. A.; Svarovskaya, L. I.; Manakov, A. Yu.

2017-12-01

The paper reports on a multiparametric study of West Siberian crude oils using Fourier transform infrared (FTIR) spectroscopy to establish a relationship between the physicochemical properties of the oils, their spectral coefficients, and biodegradation levels. It is found that the test oils are slightly biodegraded, feature a roughly linear dependence between the freezing temperature and the content of resin and asphaltene, and display a relation of their emulsifying ability and spectral coefficient C2, being the ratio of alkanes and substituted alkylbenzene compounds.

On the possibility of spectroscopic cancer diagnostics

NASA Astrophysics Data System (ADS)

Khairullina, Alphiya Y.; Oleinik, Tatiana V.; Korolevich, Alexander N.; Sevkovsky, Yacob I.

1993-07-01

The diffuse reflection and transmission coefficients, other optical parameters of normal and cancer tissues have been investigated in visible and infrared spectra. The optimal spectral range for distinguishing the cancer is found. The spectral absorption coefficients and size of cells parameter determined using our approach are analyzed to be different for normal and pathological tissues. The method is proposed for calculating the diffuse reflectance and transmittance of multiple tissue layers. The investigations have shown that cancer may be distinguished under the layers of skin and normal tissue.

Laboratory investigation of the contribution of complex aromatic/aliphatic polycyclic hybrid molecular structures to interstellar ultraviolet extinction and infrared emission

NASA Technical Reports Server (NTRS)

Arnoult, K. M.; Wdowiak, T. J.; Beegle, L. W.

2000-01-01

We have demonstrated by experiment that, in an energetic environment, a simple polycyclic aromatic hydrocarbon (PAH) such as naphthalene will undergo chemical reactions that produce a wide array of more complex species (an aggregate). For a stellar wind of a highly evolved star (post-asymptotic giant branch [post-AGB]), this process would be in addition to what is expected from reactions occurring under thermodynamic equilibrium. A surprising result of that work was that produced in substantial abundance are hydrogenated forms that are hybrids of polycyclic aromatic and polycyclic alkanes. Infrared spectroscopy described here reveals a spectral character for these materials that has much in common with that observed for the constituents of circumstellar clouds of post-AGB stars. It can be demonstrated that a methylene (-CH2-) substructure, as in cycloalkanes, is the likely carrier of the 6.9 microns band emission of dust that has recently been formed around IRAS 22272+5433, NGC 7027, and CPD -56 8032. Ultraviolet spectroscopy previously done with a lower limit of 190 nm had revealed that this molecular aggregate can contribute to the interstellar extinction feature at 2175 angstroms. We have now extended our UV spectroscopy of these materials to 110 nm by a vacuum ultraviolet technique. That work, described here, reveals new spectral characteristics and describes how material newly formed during the late stages of stellar evolution could have produced an extinction feature claimed to exist at 1700 angstroms in the spectrum of HD 145502 and also how the newly formed hydrocarbon material would be transformed/aged in the general interstellar environment. The contribution of this molecular aggregate to the rise in interstellar extinction at wavelengths below 1500 angstroms is also examined. The panspectral measurements of the materials produced in the laboratory, using plasmas of H, He, N, and O to convert the simple PAH naphthalene to an aggregate of complex species, provide insight into possible molecular structure details of newly formed hydrocarbon-rich interstellar dust and its transformation into aged material that becomes resident in the interstellar medium. Specifically the presence of naphthalene-like and butadiene-like conjugated structures as chromophores for the 2175 angstroms ultraviolet extinction feature is indicated.

Infrared Extinction Coefficients of Aerosolized Conductive Flake Powders and Flake Suspensions having a Zero-Truncated Poisson Size Distribution

DTIC Science & Technology

2012-11-01

report may not be cited for purposes of advertisement . This report has been approved for public release. Acknowledgments The authors would...visible wavelengths, the eye perceives an image as a result of color contrasts that consist of differences in luminance and chromaticity (hue and

A Comparison of the AFGL Flash, Draper Dart and AWS Haze Models with the Rand Wetta Model for Calculating Atmospheric Contrast Reduction.

DTIC Science & Technology

1982-03-01

52 ILLUSTRATIONS Figure I Horizontal Visibility Profiles for Stair-Step and Exponential Extinction Coefficient...background reflectances. These values were then numerically intergrated (via a combination of Simpson’s and Newton’s 3/8th rules) and compared with the

Optical Constants of Minerals and Other Materials from the Millimeter to the Ultraviolet

DTIC Science & Technology

1987-11-01

refractive index N, and extinction coefficient K for pottasium choie................................................ 31Schloride... pottasium chloride. 31 POTASSIUM CHLORIDE S6C _ _ u5 ’U .. 4 31 0 1000 2000 WAVELENGTH (NM) 1.80 1.70 -- _ N 1.60 1.50 - -"- 1.40- 0 1000 2000 WAVELENGTH

Impacts of PM concentrations on visibility impairment

NASA Astrophysics Data System (ADS)

Jie, Guo; Wang, Mei-mei; Han, Ye-Xing; Yu, Zhi-Wei; Tang, Huai-Wu

2016-11-01

In the paper, an accurate and sensitive cavity attenuated phase shift spectroscopy (CAPS) sensor was used to monitor the atmospheric visibility. The CAPS system mainly includes a LED light source, a band-pass filter, an optical resonant cavity (composed of two high mirror, reflectivity is greater than 99.99%), a photoelectric detector and a lock-in amplifier. The 2L/min flow rate, the optical sensor rise and fall response time is about 15 s, so as to realize the fast measurement of visibility. An Allan variance analysis was carried out evaluating the optical system stability (and hence the maximum averaging time for the minimum detection limit) of the CAPS system. The minima ( 0.1 Mm-1) in the Allan plots show the optimum average time ( 100s) for optimum detection performance of the CAPS system. During this period, the extinction coefficient was correlated with PM2.5 mass (0.88), the extinction coefficient was correlated with PM10 mass (0.85). The atmospheric visibility was correlated with PM2.5 mass (0.74). The atmospheric visibility was correlated with PM10 mass (0.66).

The Experimental Cloud Lidar Pilot Study (ECLIPS) for cloud-radiation research

NASA Technical Reports Server (NTRS)

Platt, C. M.; Young, S. A.; Carswell, A. I.; Pal, S. R.; Mccormick, M. P.; Winker, D. M.; Delguasta, M.; Stefanutti, L.; Eberhard, W. L.; Hardesty, M.

1994-01-01

The Experimental Cloud Lidar Pilot Study (ECLIPS) was initiated to obtain statistics on cloud-base height, extinction, optical depth, cloud brokenness, and surface fluxes. Two observational phases have taken place, in October-December 1989 and April-July 1991, with intensive 30-day periods being selected within the two time intervals. Data are being archived at NASA Langley Research Center and, once there, are readily available to the international scientific community. This article describes the scale of the study in terms of its international involvement and in the range of data being recorded. Lidar observations of cloud height and backscatter coefficient have been taken from a number of ground-based stations spread around the globe. Solar shortwave and infrared longwave fluxes and infrared beam radiance have been measured at the surface wherever possible. The observations have been tailored to occur around the overpass times of the NOAA weather satellites. This article describes in some detail the various retrieval methods used to obtain results on cloud-base height, extinction coefficient, and infrared emittance, paying particular attention to the uncertainties involved.

[The evoked activity of the lateral hypothalamus during extinction and differential inhibition].

PubMed

Vanetsian, G L

1995-01-01

Character of interaction between symmetric points of the cat's auditory cortex (A1) and the lateral hypothalamus (HL) was determined by calculating Spearman correlation coefficients between averaged summed sound-evoked activity (AEP) of the structures before, during elaboration, extinction and restoration, as well as differentiation of food-procuring conditioned reflex and in the eating full. Close mutual co-tuning between the cortex and hypothalamus characteristic for stable conditioned reflex was found to disrupted during its extinction, elaboration of differentiation and fullness eat inhibition due to entire reduction of hypothalamic AEP and disappearance of correlated with negativity of HL AEP "doubling" of the first positive wave of A1 AEP. Hyperactivity stage, expressed at the beginning of extinction and at the end of differentiation, preceded inactivation of hypothalamic afferents during elaboration of conditioned inhibition. The stage of hyperactivity, initiated by the elevated emotional state of the animal, testifies to an important role of emotional brain structures in the process of internal inhibition. The stage of HL and A1 hyperactivity initiated by emotional stress of the animal and following HL inactivation during inhibition of the conditioned response point to an important role of emotional subcortical brain structures in the mechanisms of inhibitory conditioning.

Validation of Earth atmosphere models using solar EUV observations from the CORONAS and PROBA2 satellites in occultation mode

NASA Astrophysics Data System (ADS)

Slemzin, Vladimir; Ulyanov, Artyom; Gaikovich, Konstantin; Kuzin, Sergey; Pertsov, Andrey; Berghmans, David; Dominique, Marie

2016-02-01

Aims: Knowledge of properties of the Earth's upper atmosphere is important for predicting the lifetime of low-orbit spacecraft as well as for planning operation of space instruments whose data may be distorted by atmospheric effects. The accuracy of the models commonly used for simulating the structure of the atmosphere is limited by the scarcity of the observations they are based on, so improvement of these models requires validation under different atmospheric conditions. Measurements of the absorption of the solar extreme ultraviolet (EUV) radiation in the upper atmosphere below 500 km by instruments operating on low-Earth orbits (LEO) satellites provide efficient means for such validation as well as for continuous monitoring of the upper atmosphere and for studying its response to the solar and geomagnetic activity. Method: This paper presents results of measurements of the solar EUV radiation in the 17 nm wavelength band made with the SPIRIT and TESIS telescopes on board the CORONAS satellites and the SWAP telescope on board the PROBA2 satellite in the occulted parts of the satellite orbits. The transmittance profiles of the atmosphere at altitudes between 150 and 500 km were derived from different phases of solar activity during solar cycles 23 and 24 in the quiet state of the magnetosphere and during the development of a geomagnetic storm. We developed a mathematical procedure based on the Tikhonov regularization method for solution of ill-posed problems in order to retrieve extinction coefficients from the transmittance profiles. The transmittance profiles derived from the data and the retrieved extinction coefficients are compared with simulations carried out with the NRLMSISE-00 atmosphere model maintained by Naval Research Laboratory (USA) and the DTM-2013 model developed at CNES in the framework of the FP7 project ATMOP. Results: Under quiet and slightly disturbed magnetospheric conditions during high and low solar activity the extinction coefficients calculated by both models agreed with the measurements within the data errors. The NRLMSISE-00 model was not able to predict the enhancement of extinction above 300 km observed after 14 h from the beginning of a geomagnetic storm whereas the DTM-2013 model described this variation with good accuracy.

Extreme dust storm over the eastern Mediterranean in September 2015: satellite, lidar, and surface observations in the Cyprus region

NASA Astrophysics Data System (ADS)

Mamouri, Rodanthi-Elisavet; Ansmann, Albert; Nisantzi, Argyro; Solomos, Stavros; Kallos, George; Hadjimitsis, Diofantos G.

2016-11-01

A record-breaking dust storm originating from desert regions in northern Syria and Iraq occurred over the eastern Mediterranean in September 2015. In this contribution of a series of two articles (part 1, observations; part 2, atmospheric modeling), we provide a comprehensive overview of the aerosol conditions during this extreme dust outbreak in the Cyprus region. These observations are based on satellite observations (MODIS, moderate resolution imaging spectroradiometer) of aerosol optical thickness (AOT) and Ångström exponent, surface particle mass (PM10) concentrations measured at four sites in Cyprus, visibility observations at three airports in southern Cyprus and corresponding conversion products (particle extinction coefficient, dust mass concentrations), EARLINET (European Aerosol Research Lidar Network) lidar observations of dust vertical layering over Limassol, particle optical properties (backscatter, extinction, lidar ratio, linear depolarization ratio), and derived profiles of dust mass concentrations. Maximum 550 nm AOT exceeded values of 5.0, according to MODIS, and the mass loads were correspondingly > 10 g m-2 over Larnaca and Limassol during the passage of an extremely dense dust front on 8 September 2015. Hourly mean PM10 values were close to 8000 µg m-3 and the observed meteorological optical range (visibility) was reduced to 300-750 m at Larnaca and Limassol. The visibility observations suggest peak values of the near-surface total suspended particle (TSP) extinction coefficients of 6000 Mm-1 and thus TSP mass concentrations of 10 000 µg m-3. The Raman polarization lidar observations mainly indicated a double layer structure of the dust plumes (reaching to about 4 km height), pointing to at least two different dust source regions. Dust particle extinction coefficients (532 nm) already exceeded 1000 Mm-1 and the mass concentrations reached 2000 µg m-3 in the elevated dust layers on 7 September, more than 12 h before the peak dust front on 8 September reached the Limassol lidar station around local noon. Typical Middle Eastern dust lidar ratios around 40 sr were observed in the dense dust plumes. The particle depolarization ratio decreased from around 0.3 in the lofted dense dust layers to 0.2 at the end of the dust period (11 September), indicating an increasing impact of anthropogenic haze.

On a generalized Ablowitz-Kaup-Newell-Segur hierarchy in inhomogeneities of media: soliton solutions and wave propagation influenced from coefficient functions and scattering data

NASA Astrophysics Data System (ADS)

Zhang, Sheng; Hong, Siyu

2018-07-01

In this paper, a generalized Ablowitz-Kaup-Newell-Segur (AKNS) hierarchy in inhomogeneities of media described by variable coefficients is investigated, which includes some important nonlinear evolution equations as special cases, for example, the celebrated Korteweg-de Vries equation modeling waves on shallow water surfaces. To be specific, the known AKNS spectral problem and its time evolution equation are first generalized by embedding a finite number of differentiable and time-dependent functions. Starting from the generalized AKNS spectral problem and its generalized time evolution equation, a generalized AKNS hierarchy with variable coefficients is then derived. Furthermore, based on a systematic analysis on the time dependence of related scattering data of the generalized AKNS spectral problem, exact solutions of the generalized AKNS hierarchy are formulated through the inverse scattering transform method. In the case of reflectionless potentials, the obtained exact solutions are reduced to n-soliton solutions. It is graphically shown that the dynamical evolutions of such soliton solutions are influenced by not only the time-dependent coefficients but also the related scattering data in the process of propagations.

Voigt equivalent widths and spectral-bin single-line transmittances: Exact expansions and the MODTRAN®5 implementation

NASA Astrophysics Data System (ADS)

Berk, Alexander

2013-03-01

Exact expansions for Voigt line-shape total, line-tail and spectral bin equivalent widths and for Voigt finite spectral bin single-line transmittances have been derived in terms of optical depth dependent exponentially-scaled modified Bessel functions of integer order and optical depth independent Fourier integral coefficients. The series are convergent for the full range of Voigt line-shapes, from pure Doppler to pure Lorentzian. In the Lorentz limit, the expansion reduces to the Ladenburg and Reiche function for the total equivalent width. Analytic expressions are derived for the first 8 Fourier coefficients for pure Lorentzian lines, for pure Doppler lines and for Voigt lines with at most moderate Doppler dependence. A strong-line limit sum rule on the Fourier coefficients is enforced to define an additional Fourier coefficient and to optimize convergence of the truncated expansion. The moderate Doppler dependence scenario is applicable to and has been implemented in the MODTRAN5 atmospheric band model radiative transfer software. Finite-bin transmittances computed with the truncated expansions reduce transmittance residuals compared to the former Rodgers-Williams equivalent width based approach by ∼2 orders of magnitude.

Design of a terahertz photonic crystal transmission filter containing ferroelectric material.

PubMed

King, Tzu-Chyang; Chen, Jian-Jie; Chang, Kai-Chun; Wu, Chien-Jang

2016-10-10

The ferroelectric material KTaO₃ (KTO) has a very high refractive index, which is advantageous to the photonic crystal (PC) design. KTO polycrystalline crystal has a high extinction coefficient. In this work, we perform a theoretical study of the transmission properties of a PC bandpass filter made of polycrystalline KTO at terahertz (THz) frequencies. Our results show that the defect modes of usual PC narrowband filters no longer exist because of the existence of the high loss. We provide a new PC structure for the high-extinction materials and show that it has defect modes in its transmittance spectra, providing a possible bandpass filter design in the THz region.

MONSTER IN THE DARK: THE ULTRALUMINOUS GRB 080607 AND ITS DUSTY ENVIRONMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Perley, D. A.; Morgan, A. N.; Miller, A. A.

2011-02-15

We present early-time optical through infrared photometry of the bright Swift gamma-ray burst (GRB) 080607, starting only 6 s following the initial trigger in the rest frame. Complemented by our previously published spectroscopy, this high-quality photometric data set allows us to solve for the extinction properties of the redshift 3.036 sightline, giving perhaps the most detailed information to date on the ultraviolet continuum absorption properties of any sightline outside our Local Group. The extinction properties are not adequately modeled by any ordinary extinction template (including the average Milky Way, Large Magellanic Cloud, and Small Magellanic Cloud curves), partially because themore » 2175 A feature (while present) is weaker by about a factor of two than when seen under similar circumstances locally. However, the spectral energy distribution is exquisitely fitted by the more general Fitzpatrick and Massa parameterization of Local-Group extinction, putting it in the same family as some peculiar Milky Way extinction curves. After correcting for this (considerable, A{sub V} = 3.3 {+-} 0.4 mag) extinction, GRB 080607 is revealed to have been among the most optically luminous events ever observed, comparable to the naked-eye burst GRB 080319B. Its early peak time (t{sub rest} < 6 s) indicates a high initial Lorentz factor ({Gamma}>600), while the extreme luminosity may be explained in part by a large circumburst density. Only because of its early high luminosity could the afterglow of GRB 080607 be studied in such detail in spite of the large attenuation and great distance, making this burst an excellent prototype for the understanding of other highly obscured extragalactic objects, and of the class of 'dark' GRBs in particular.« less

Graph characterization via Ihara coefficients.

PubMed

Ren, Peng; Wilson, Richard C; Hancock, Edwin R

2011-02-01

The novel contributions of this paper are twofold. First, we demonstrate how to characterize unweighted graphs in a permutation-invariant manner using the polynomial coefficients from the Ihara zeta function, i.e., the Ihara coefficients. Second, we generalize the definition of the Ihara coefficients to edge-weighted graphs. For an unweighted graph, the Ihara zeta function is the reciprocal of a quasi characteristic polynomial of the adjacency matrix of the associated oriented line graph. Since the Ihara zeta function has poles that give rise to infinities, the most convenient numerically stable representation is to work with the coefficients of the quasi characteristic polynomial. Moreover, the polynomial coefficients are invariant to vertex order permutations and also convey information concerning the cycle structure of the graph. To generalize the representation to edge-weighted graphs, we make use of the reduced Bartholdi zeta function. We prove that the computation of the Ihara coefficients for unweighted graphs is a special case of our proposed method for unit edge weights. We also present a spectral analysis of the Ihara coefficients and indicate their advantages over other graph spectral methods. We apply the proposed graph characterization method to capturing graph-class structure and clustering graphs. Experimental results reveal that the Ihara coefficients are more effective than methods based on Laplacian spectra.

Evaluation of spatial, radiometric and spectral thematic mapper performance for coastal studies

NASA Technical Reports Server (NTRS)

Klemas, V.

1985-01-01

The main emphasis of the research was to determine what effect different wetland plant canopies would have upon observed reflectance in Thematic Mapper bands. The three major vegetation canopy types (broadleaf, gramineous and leafless) produce unique spectral responses for a similar quantity of live biomass. Biomass estimates computed from spectral data were most similar to biomass estimates determined from harvest data when models developed for a specific canopy were used. In other words, the spectral biomass estimate of a broadleaf canopy was most similar to the harvest biomass estimate when a broadleaf canopy radiance model was used. Work is continuing to more precisely determine regression coefficients for each canopy type and to model the change in the coefficients with various combinations of canopy types. Researchers suspect that textural and spatial considerations can be used to identify canopy types and improve biomass estimates from Thematic Mapper data.

Surface Measurements of Solar Spectral Radiative Flux in the Cloud-Free Atmosphere

NASA Technical Reports Server (NTRS)

Pilewskie, Peter; Goetz, A. F. H.; Bergstrom, R.; Beal, D.; Gore, Warren J. Y. (Technical Monitor)

1997-01-01

Recent studies (Charlock, et al.; Kato, et. al) have indicated a potential discrepancy between measured solar irradiance in the cloud-free atmosphere and model derived downwelling solar irradiance. These conclusions were based primarily on broadband integrated solar flux. Extinction (both absorption and scattering) phenomena, however, typically have spectral characteristics that would be present in moderate resolution (e.g., 10 nm) spectra, indicating the need for such measurements to thoroughly investigate the cause of any discrepancies. The 1996 Department of Energy Atmospheric Radiation Measurement Program (ARM) Intensive Observation Period (IOP), held simultaneously with the NASA Subsonic Aircraft: Contrail and Cloud Effects Special Study (SUCCESS) Program, provided an opportunity for two simultaneous but independent measurements of moderate resolution solar spectral downwelling irradiance at the surface. The instruments were the NASA Ames Solar Spectral Flux Radiometer and the Analytical Spectral Devices, Inc., FieldSpecT-FR. Spectral and band integrated quantities from both sets of measurements will be presented, along with estimates of the downwelling solar irradiance from band model and line by line calculations, in an effort to determine the compatibility between measured and calculated solar irradiance in the cloud-free atmosphere.

Spectroscopic parallaxes of MAP region stars from UBVRI, DDO, and uvbyH-beta photometry. [Multichannel Astrometric Photometer for astronomical observation

NASA Technical Reports Server (NTRS)

Persinger, Tim; Castelaz, Michael W.

1990-01-01

This paper presents the results of spectral type and luminosity classification of reference stars in the Allegheny Observatory MAP parallax program, using broadband and intermediate-band photometry. In addition to the use of UBVRI and DDO photometric systems, the uvbyH-beta photometric system was included for classification of blue (B - V less than 0.6) reference stars. The stellar classifications made from the photometry are used to determine spectroscopic parallaxes. The spectroscopic parallaxes are used in turn to adjust the relative parallaxes measured with the MAP to absolute parallaxes. A new method for dereddening stars using more than one photometric system is presented. In the process of dereddening, visual extinctions, spectral types, and luminosity classes are determined, as well as a measure of the goodness of fit. The measure of goodness of fit quantifies confidence in the stellar classifications. It is found that the spectral types are reliable to within 2.5 spectral subclasses.

Retrieval of Aerosol Parameters from Continuous H24 Lidar-Ceilometer Measurements

NASA Astrophysics Data System (ADS)

Dionisi, D.; Barnaba, F.; Costabile, F.; Di Liberto, L.; Gobbi, G. P.; Wille, H.

2016-06-01

Ceilometer technology is increasingly applied to the monitoring and the characterization of tropospheric aerosols. In this work, a method to estimate some key aerosol parameters (extinction coefficient, surface area concentration and volume concentration) from ceilometer measurements is presented. A numerical model has been set up to derive a mean functional relationships between backscatter and the above mentioned parameters based on a large set of simulated aerosol optical properties. A good agreement was found between the modeled backscatter and extinction coefficients and the ones measured by the EARLINET Raman lidars. The developed methodology has then been applied to the measurements acquired by a prototype Polarization Lidar-Ceilometer (PLC). This PLC instrument was developed within the EC- LIFE+ project "DIAPASON" as an upgrade of the commercial, single-channel Jenoptik CHM15k system. The PLC run continuously (h24) close to Rome (Italy) for a whole year (2013-2014). Retrievals of the aerosol backscatter coefficient at 1064 nm and of the relevant aerosol properties were performed using the proposed methodology. This information, coupled to some key aerosol type identification made possible by the depolarization channel, allowed a year-round characterization of the aerosol field at this site. Examples are given to show how this technology coupled to appropriate data inversion methods is potentially useful in the operational monitoring of parameters of air quality and meteorological interest.

The relationship between species detection probability and local extinction probability

USGS Publications Warehouse

Alpizar-Jara, R.; Nichols, J.D.; Hines, J.E.; Sauer, J.R.; Pollock, K.H.; Rosenberry, C.S.

2004-01-01

In community-level ecological studies, generally not all species present in sampled areas are detected. Many authors have proposed the use of estimation methods that allow detection probabilities that are < 1 and that are heterogeneous among species. These methods can also be used to estimate community-dynamic parameters such as species local extinction probability and turnover rates (Nichols et al. Ecol Appl 8:1213-1225; Conserv Biol 12:1390-1398). Here, we present an ad hoc approach to estimating community-level vital rates in the presence of joint heterogeneity of detection probabilities and vital rates. The method consists of partitioning the number of species into two groups using the detection frequencies and then estimating vital rates (e.g., local extinction probabilities) for each group. Estimators from each group are combined in a weighted estimator of vital rates that accounts for the effect of heterogeneity. Using data from the North American Breeding Bird Survey, we computed such estimates and tested the hypothesis that detection probabilities and local extinction probabilities were negatively related. Our analyses support the hypothesis that species detection probability covaries negatively with local probability of extinction and turnover rates. A simulation study was conducted to assess the performance of vital parameter estimators as well as other estimators relevant to questions about heterogeneity, such as coefficient of variation of detection probabilities and proportion of species in each group. Both the weighted estimator suggested in this paper and the original unweighted estimator for local extinction probability performed fairly well and provided no basis for preferring one to the other.

Temperature and salinity correction coefficients for light absorption by water in the visible to infrared spectral region.

PubMed

Röttgers, Rüdiger; McKee, David; Utschig, Christian

2014-10-20

The light absorption coefficient of water is dependent on temperature and concentration of ions, i.e. the salinity in seawater. Accurate knowledge of the water absorption coefficient, a, and/or its temperature and salinity correction coefficients, Ψ(T) and Ψ(S), respectively, is essential for a wide range of optical applications. Values are available from published data only at specific narrow wavelength ranges or at single wavelengths in the visible and infrared regions. Ψ(T) and Ψ(S) were therefore spectrophotometrically measured throughout the visible, near, and short wavelength infrared spectral region (400 to ~2700 nm). Additionally, they were derived from more precise measurements with a point-source integrating-cavity absorption meter (PSICAM) for 400 to 700 nm. When combined with earlier measurements from the literature in the range of 2600 - 14000 nm (wavenumber: 3800 - 700 cm(-1)), the coefficients are provided for 400 to 14000 nm (wavenumber: 25000 to 700 cm(-1)).

Spectroscopic and thermal investigations on the charge transfer interaction between risperidone as a schizophrenia drug with some traditional π-acceptors: Part 2

NASA Astrophysics Data System (ADS)

El-Habeeb, Abeer A.; Al-Saif, Foziah A.; Refat, Moamen S.

2013-03-01

The focus of present investigation was to assess the utility of non-expensive techniques in the evaluation of risperidone (Ris) in solid and solution states with different traditional π-acceptors and subsequent incorporation of the analytical determination into pharmaceutical formulation for a faster release of risperidone. Charge-transfer complexes (CTC) of risperidone with picric acid (PA), 2,3-dichloro-5,6-dicyano-p-benzoquinon (DDQ), tetracyanoquinodimethane (TCNQ), tetracyano ethylene (TCNE), tetrabromo-p-quinon (BL) and tetrachloro-p-quinon (CL) have been studied spectrophotometrically in absolute methanol at room temperature. The stoichiometries of the complexes were found to be 1:1 ratio by the photometric molar ratio between risperidone and the π-acceptors. The equilibrium constants, molar extinction coefficient (ɛCT) and spectroscopic-physical parameters (standard free energy (ΔGo), oscillator strength (f), transition dipole moment (μ), resonance energy (RN) and ionization potential (ID)) of the complexes were determined upon the modified Benesi-Hildebrand equation. Risperidone in pure form was applied in this study. The results indicate that the formation constants for the complexes depend on the nature of electron acceptors and donor, and also the spectral studies of the complexes were determined by (infrared, Raman, and 1H NMR) spectra and X-ray powder diffraction (XRD). The most stable mono-protonated form of Ris is characterized by the formation of +Nsbnd H (pyrimidine ring) intramolecular hydrogen bonded. In the high-wavenumber spectral region ˜3400 cm-1, the bands of the +Nsbnd H stretching vibrations and of the pyrimidine nitrogen atom could be potentially useful to discriminate the investigated forms of Ris. The infrared spectra of both Ris complexes are confirming the participation of +Nsbnd H pyrimidine ring in the donor-acceptor interaction.

Interconversion of Anthozoa GFP-like fluorescent and non-fluorescent proteins by mutagenesis

PubMed Central

Bulina, Maria E; Chudakov, Dmitry M; Mudrik, Nikolay N; Lukyanov, Konstantin A

2002-01-01

Background Within the family of green fluorescent protein (GFP) homologs, one can mark two main groups, specifically, fluorescent proteins (FPs) and non-fluorescent or chromoproteins (CPs). Structural background of differences between FPs and CPs are poorly understood to date. Results Here, we applied site-directed and random mutagenesis in order to to transform CP into FP and vice versa. A purple chromoprotein asCP (asFP595) from Anemonia sulcata and a red fluorescent protein DsRed from Discosoma sp. were selected as representatives of CPs and FPs, respectively. For asCP, some substitutions at positions 148 and 165 (numbering in accordance to GFP) were found to dramatically increase quantum yield of red fluorescence. For DsRed, substitutions at positions 148, 165, 167, and 203 significantly decreased fluorescence intensity, so that the spectral characteristics of these mutants became more close to those of CPs. Finally, a practically non-fluorescent mutant DsRed-NF was generated. This mutant carried four amino acid substitutions, specifically, S148C, I165N, K167M, and S203A. DsRed-NF possessed a high extinction coefficient and an extremely low quantum yield (< 0.001). These spectral characteristics allow one to regard DsRed-NF as a true chromoprotein. Conclusions We located a novel point in asCP sequence (position 165) mutations at which can result in red fluorescence appearance. Probably, this finding could be applied onto other CPs to generate red and far-red fluorescent mutants. A possibility to transform an FP into CP was demonstrated. Key role of residues adjacent to chromophore's phenolic ring in fluorescent/non-fluorescent states determination was revealed. PMID:11972899

Orbit-dependent spectral trends for the near-Earth asteroid population

NASA Astrophysics Data System (ADS)

Fevig, Ronald Adrey

Results of visible to near-infrared spectrophotometric observations of 55 near- Earth asteroids (NEAs) are reported. The observing techniques, instrumentation, and method of data analysis are described. A new asteroid classification method that directly compares these NEA spectra with spectral features of meteorites is presented. Two major siliceous groups (having discernible "1-mm" absorptions) result from this method, OC-likes which match the spectra of ordinary chondrites and S-types. The dataset shows a preponderance of spectra consistent with ordinary chondrites (23 NEAs), as well as S-types (19), 2 with spectra consistent with black ordinary chondrites, 2 R-types, and 9 that show no 1-mm absorption. The spectral characteristics of the siliceous S-type and OC-like asteroids blend together, providing evidence that S-type asteroids are simply ordinary chondrites whose surface has been modified by weathering. This helps resolve the long standing question of the lack of main belt asteroids having spectra matching ordinary chondrite meteorites. Main belt asteroids have on average much older surfaces while NEAs that exhibit OC-like spectra have younger surfaces. It was found that fresh objects having spectra consistent with ordinary chondrites (1) occupy mostly highly eccentric Apollo orbits which encounter a strong collisional environment in the asteroid main-belt, (2) may have been recently injected into high eccentricity orbits, or (3) have suffered tidal disruption. S-type NEAs reside primarily in orbits that do not cross the asteroid main-belt. This orbit dependent trend is verified by using the larger NEA dataset of Binzel et al. (2004a). Nine NEAs from this survey exhibiting no 1-mm absorption can be associated with extinct comets, iron meteorites or enstatite meteorites. It is shown that most of these NEAs must be extinct comets, implying a considerably larger fraction of comets among the NEA population than previously thought. A correlation of these objects with low inclination orbits is found. This study finds that the NEA population is divided roughly as follows: ~40 % fresh ordinary chondrites, ~35% S-types, ~20% extinct comet candidates, and ~5% in minor classes. This work may guide NEA mitigation planning should such an emergency arise.

Time domain simulation of the response of geometrically nonlinear panels subjected to random loading

NASA Technical Reports Server (NTRS)

Moyer, E. Thomas, Jr.

1988-01-01

The response of composite panels subjected to random pressure loads large enough to cause geometrically nonlinear responses is studied. A time domain simulation is employed to solve the equations of motion. An adaptive time stepping algorithm is employed to minimize intermittent transients. A modified algorithm for the prediction of response spectral density is presented which predicts smooth spectral peaks for discrete time histories. Results are presented for a number of input pressure levels and damping coefficients. Response distributions are calculated and compared with the analytical solution of the Fokker-Planck equations. RMS response is reported as a function of input pressure level and damping coefficient. Spectral densities are calculated for a number of examples.

Effect of Conditioned Stimulus Exposure during Slow Wave Sleep on Fear Memory Extinction in Humans

PubMed Central

He, Jia; Sun, Hong-Qiang; Li, Su-Xia; Zhang, Wei-Hua; Shi, Jie; Ai, Si-Zhi; Li, Yun; Li, Xiao-Jun; Tang, Xiang-Dong; Lu, Lin

2015-01-01

Study Objectives: Repeated exposure to a neutral conditioned stimulus (CS) in the absence of a noxious unconditioned stimulus (US) elicits fear memory extinction. The aim of the current study was to investigate the effects of mild tone exposure (CS) during slow wave sleep (SWS) on fear memory extinction in humans. Design: The healthy volunteers underwent an auditory fear conditioning paradigm on the experimental night, during which tones served as the CS, and a mild shock served as the US. They were then randomly assigned to four groups. Three groups were exposed to the CS for 3 or 10 min or an irrelevant tone (control stimulus, CtrS) for 10 min during SWS. The fourth group served as controls and was not subjected to any interventions. All of the subjects completed a memory test 4 h after SWS-rich stage to evaluate the effect on fear extinction. Moreover, we conducted similar experiments using an independent group of subjects during the daytime to test whether the memory extinction effect was specific to the sleep condition. Participants: Ninety-six healthy volunteers (44 males) aged 18–28 y. Measurements and Results: Participants exhibited undisturbed sleep during 2 consecutive nights, as assessed by sleep variables (all P > 0.05) from polysomnographic recordings and power spectral analysis. Participants who were re-exposed to the 10 min CS either during SWS and wakefulness exhibited attenuated fear responses (wake-10 min CS, P < 0.05; SWS-10 min CS, P < 0.01). Conclusions: Conditioned stimulus re-exposure during slow wave sleep promoted fear memory extinction without altering sleep profiles. Citation: He J, Sun HQ, Li SX, Zhang WH, Shi J, Ai SZ, Li Y, Li XJ, Tang XD, Lu L. Effect of conditioned stimulus exposure during slow wave sleep on fear memory extinction in humans. SLEEP 2015;38(3):423–431. PMID:25348121

Dust models post-Planck: constraining the far-infrared opacity of dust in the diffuse interstellar medium

NASA Astrophysics Data System (ADS)

Fanciullo, L.; Guillet, V.; Aniano, G.; Jones, A. P.; Ysard, N.; Miville-Deschênes, M.-A.; Boulanger, F.; Köhler, M.

2015-08-01

Aims: We compare the performance of several dust models in reproducing the dust spectral energy distribution (SED) per unit extinction in the diffuse interstellar medium (ISM). We use our results to constrain the variability of the optical properties of big grains in the diffuse ISM, as published by the Planck collaboration. Methods: We use two different techniques to compare the predictions of dust models to data from the Planck HFI, IRAS, and SDSS surveys. First, we fit the far-infrared emission spectrum to recover the dust extinction and the intensity of the interstellar radiation field (ISRF). Second, we infer the ISRF intensity from the total power emitted by dust per unit extinction, and then predict the emission spectrum. In both cases, we test the ability of the models to reproduce dust emission and extinction at the same time. Results: We identify two issues. Not all models can reproduce the average dust emission per unit extinction: there are differences of up to a factor ~2 between models, and the best accord between model and observation is obtained with the more emissive grains derived from recent laboratory data on silicates and amorphous carbons. All models fail to reproduce the variations in the emission per unit extinction if the only variable parameter is the ISRF intensity: this confirms that the optical properties of dust are indeed variable in the diffuse ISM. Conclusions: Diffuse ISM observations are consistent with a scenario where both ISRF intensity and dust optical properties vary. The ratio of the far-infrared opacity to the V band extinction cross-section presents variations of the order of ~20% (40-50% in extreme cases), while ISRF intensity varies by ~30% (~60% in extreme cases). This must be accounted for in future modelling. Appendices are available in electronic form at http://www.aanda.org

Dependence of the absorption and optical surface plasmon scattering of MoS₂ nanoparticles on aspect ratio, size, and media.

PubMed

Yadgarov, Lena; Choi, Charina L; Sedova, Anastasiya; Cohen, Ayala; Rosentsveig, Rita; Bar-Elli, Omri; Oron, Dan; Dai, Hongjie; Tenne, Reshef

2014-04-22

The optical and electronic properties of suspensions of inorganic fullerene-like nanoparticles of MoS2 are studied through light absorption and zeta-potential measurements and compared to those of the corresponding microscopic platelets. The total extinction measurements show that, in addition to excitonic peaks and the indirect band gap transition, a new peak is observed at 700-800 nm. This spectral peak has not been reported previously for MoS2. Comparison of the total extinction and decoupled absorption spectrum indicates that this peak largely originates from scattering. Furthermore, the dependence of this peak on nanoparticle size, shape, and surface charge, as well as solvent refractive index, suggests that this transition arises from a plasmon resonance.

Effective Heat and Mass Transport Properties of Anisotropic Porous Ceria for Solar Thermochemical Fuel Generation

PubMed Central

Haussener, Sophia; Steinfeld, Aldo

2012-01-01

High-resolution X-ray computed tomography is employed to obtain the exact 3D geometrical configuration of porous anisotropic ceria applied in solar-driven thermochemical cycles for splitting H2O and CO2. The tomography data are, in turn, used in direct pore-level numerical simulations for determining the morphological and effective heat/mass transport properties of porous ceria, namely: porosity, specific surface area, pore size distribution, extinction coefficient, thermal conductivity, convective heat transfer coefficient, permeability, Dupuit-Forchheimer coefficient, and tortuosity and residence time distributions. Tailored foam designs for enhanced transport properties are examined by means of adjusting morphologies of artificial ceria samples composed of bimodal distributed overlapping transparent spheres in an opaque medium. PMID:28817039

Combined High Spectral Resolution Lidar and Millimeter Wavelength Radar Measurement of Ice Crystal Precipitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eloranta, Edwin

The goal of this research has been to improve measurements of snowfall using a combination of millimeter-wavelength radar and High Spectral Resolution Lidar (HSRL) Observations. Snowflakes are large compared to the 532nm HSRL wavelength and small compared to the 3.2 and 8.6 mm wavelength radars used in this study. This places the particles in the optical scattering regime of the HSRL, where extinction cross-section is proportional to the projected area of the particles, and in the Rayleigh regime for the radar, where the backscatter cross-section is proportional to the mass-squared of the particles. Forming a ratio of the radar measuredmore » cross-section to the HSRL measured cross section eliminates any dependence on the number of scattering particles, yielding a quantity proportional to the average mass-squared of the snowflakes over the average area of the flakes. Using simultaneous radar measurements of particle fall velocities, which are dependent particle mass and cross-sectional area it is possible to derive the average mass of the snow flakes, and with the radar measured fall velocities compute the snowfall rate. Since this retrieval requires the optical extinction cross-section we began by considering errors this quantity. The HSRL is particularly good at measuring the backscatter cross-section. In previous studies of snowfall in the high Arctic were able to estimate the extinction cross-section directly as a fixed ratio to the backscatter cross-section. Measurements acquired in the STORMVEX experiment in Colorado showed that this approach was not valid in mid-latitude snowfalls and that direct measurement of the extinction cross-section is required. Attempts to measure the extinction directly uncovered shortcomings in thermal regulation and mechanical stability of the newly deployed DOE HSRL systems. These problems were largely mitigated by modifications installed in both of the DOE systems. We also investigated other sources of error in the HSRL direct measurement of extinction (see appendix II of this report). We also developed improved algorithms to extract extinction from the HSRL data. These have been installed in the standard HSRL data processing software and are now available to all users of HSRL data. Validation of snowfall measurements has proven difficult due to the unreliability of conventional snowfall measurements coupled with the complexity of considering the vast variety of snowflake geometries. It was difficult to tell how well the algorithm’s approach to accommodating differences in snowflakes was working without good measurements for comparison. As a result, we decided to apply this approach to the somewhat simpler, but scientifically important, problem of drizzle measurement. Here the particle shape is known and the conventional measurement are more reliable. These algorithms where successfully applied to drizzle data acquired during the ARM MAGIC study of marine stratus clouds between California and Hawaii (see Appendix I). This technique is likely to become a powerful tool for studying lifetime of the climatically important marine stratus clouds.« less

Mapping luminous blue compact galaxies with VIRUS-P. Morphology, line ratios, and kinematics

NASA Astrophysics Data System (ADS)

Cairós, L. M.; Caon, N.; García Lorenzo, B.; Kelz, A.; Roth, M.; Papaderos, P.; Streicher, O.

2012-11-01

Context. Blue compact galaxies (BCG) are narrow emission-line systems that undergo a violent burst of star formation. They are compact, low-luminosity galaxies, with blue colors and low chemical abundances, which offer us a unique opportunity to investigate collective star formation and its effects on galaxy evolution in a relatively simple, dynamically unperturbed environment. Spatially resolved spectrophotometric studies of BCGs are essential for a better understanding of the role of starburst-driven feedback processes on the kinematical and chemical evolution of low-mass galaxies near and far. Aims: We carry out an integral field spectroscopy (IFS) study of a sample of luminous BCGs, with the aim to probe the morphology, kinematics, dust extinction, and excitation mechanisms of their warm interstellar medium (ISM). Methods: We obtained IFS data for five luminous BCGs with VIRUS-P, the prototype instrument for the Visible Integral Field Replicable Unit Spectrograph, attached to the 2.7 m Harlan J. Smith Telescope at the McDonald Observatory. VIRUS-P consists of a square array of 247 optical fibers, which covers a 109″ × 109″ field of view, with a spatial sampling of 4farcs2 and a 0.3 filling factor. We observed in the 3550-5850 Å spectral range, with a resolution of 5 Å FWHM. From these data we built two-dimensional maps of the continuum and the most prominent emission-lines ([O ii] λ3727, Hγ, Hβ and [O iii] λ5007), and investigated the morphology of diagnostic emission-line ratios and the extinction patterns in the ISM as well as stellar and gas kinematics. Additionally, from integrated spectra we inferred total line fluxes and luminosity-weighted extinction coefficients and gas-phase metallicities. Results: All galaxies exhibit an overall regular morphology in the stellar continuum, while their warm ISM morphology is more complex: in II Zw 33 and Mrk 314, the star-forming regions are aligned along a chain-structure; Haro 1, NGC 4670 and III Zw 102 display several salient features, such as extended gaseous filaments and bubbles. A significant intrinsic absorption by dust is present in all galaxies, the most extreme case being III Zw 102. Our data reveal a plethora of kinematical patterns, from overall regular gas and stellar rotation to complex velocity fields produced by structurally and kinematically distinct components.

The extinction law in the open cluster NGC 457 and the intrinsic energy distribution of Phi Cassiopeiae (F0 Ia)

NASA Technical Reports Server (NTRS)

Rosenzweig, P.; Morrison, N. D.

1986-01-01

Five early B-type stars near the main-sequence turnoff in NGC 457 have been observed at low dispersion with the short-wavelength prime and the long-wavelength redundant cameras of the IUE satellite. The equivalent widths of spectral features that are particularly strong and sensitive to temperature and luminosity were computed in the cluster stars and in 20 lightly reddened stars of types O9-B3 and luminosity classes III-V. The comparison of the equivalent widths provides a reliable method for finding matching pairs. Having identified the best comparison star for each program star, binned fluxes were used to determine the mean extinction curve. In order to cover the visible region, monochromatic fluxes of Phi Cas were derived from observations with the intensified Reticon scanner mounted on the No. 2 0.9 m telescope of KPNO, and they were dereddened with the mean extinction curve of Savage and Mathis. Thus, the intrinsic energy distribution of Phi Cas were determined from 1500 to 5800 A for use in a detailed model-atmosphere analysis.

Surface plasmon resonance in electrodynamically coupled Au NPs monolayer/dielectric spacer/Al film nanostructure: tuning by variation of spacer thickness

NASA Astrophysics Data System (ADS)

Yeshchenko, Oleg A.; Kozachenko, Viktor V.; Liakhov, Yuriy F.; Tomchuk, Anastasiya V.; Haftel, Michael; Pinchuk, Anatoliy O.

2017-10-01

Effects of plasmonic coupling between metal nanoparticles and thin metal films separated by thin dielectric film-spacers have been studied by means of light extinction in three-layer planar Au NPs monolayer/dielectric (shellac) film/Al film nanostructure. The influence of coupling on the spectral characteristics of the Au NPs SPR extinction peak has been analyzed with spacer thickness, varied from 3 to 200 nm. The main observed features are a strong red shift (160 nm), and non-monotonical behavior of the magnitude and width of Au NPs SPR, as the spacer thickness decreased. The appearance of an intensive gap mode peak was observed at a spacer thickness smaller than approximately 30 nm, caused by the hybridization of the Au NPs SPR mode and gap mode in the presence of the Al film. Additionally, the appreciable enhancement (5.6 times) of light extinction by the Au NPs monolayer in the presence of Al film has been observed. A certain value of dielectric spacer thickness (70 nm) exists at which such enhancement is maximal.

High speed ultra-broadband amplitude modulators with ultrahigh extinction >65 dB.

PubMed

Liu, S; Cai, H; DeRose, C T; Davids, P; Pomerene, A; Starbuck, A L; Trotter, D C; Camacho, R; Urayama, J; Lentine, A

2017-05-15

We experimentally demonstrate ultrahigh extinction ratio (>65 dB) amplitude modulators (AMs) that can be electrically tuned to operate across a broad spectral range of 160 nm from 1480 - 1640 nm and 95 nm from 1280 - 1375 nm. Our on-chip AMs employ one extra coupler compared with conventional Mach-Zehnder interferometers (MZI), thus form a cascaded MZI (CMZI) structure. Either directional or adiabatic couplers are used to compose the CMZI AMs and experimental comparisons are made between these two different structures. We investigate the performance of CMZI AMs under extreme conditions such as using 95:5 split ratio couplers and unbalanced waveguide losses. Electro-optic phase shifters are also integrated in the CMZI AMs for high-speed operation. Finally, we investigate the output optical phase when the amplitude is modulated, which provides us valuable information when both amplitude and phase are to be controlled. Our demonstration not only paves the road to applications such as quantum information processing that requires high extinction ratio AMs but also significantly alleviates the tight fabrication tolerance needed for large-scale integrated photonics.