Preliminary estimates of residence times and apparent ages of ground water in the Chesapeake Bay watershed, and water-quality data from a survey of springs

USGS Publications Warehouse

Focazio, Michael J.; Plummer, Niel; Bohlke, John K.; Busenberg, Eurybiades; Bachman, L. Joseph; Powars, David S.

1998-01-01

Knowledge of the residence times of the ground-water systems in Chesapeake Bay watershed helps resource managers anticipate potential delays between implementation of land-management practices and any improve-ments in river and estuary water quality. This report presents preliminary estimates of ground-water residence times and apparent ages of water in the shallow aquifers of the Chesapeake Bay watershed. A simple reservoir model, published data, and analyses of spring water were used to estimate residence times and apparent ages of ground-water discharge. Ranges of aquifer hydraulic characteristics throughout the Bay watershed were derived from published literature and were used to estimate ground-water residence times on the basis of a simple reservoir model. Simple combinations of rock type and physiographic province were used to delineate hydrogeomorphic regions (HGMR?s) for the study area. The HGMR?s are used to facilitate organization and display of the data and analyses. Illustrations depicting the relation of aquifer characteristics and associated residence times as a continuum for each HGMR were developed. In this way, the natural variation of aquifer characteristics can be seen graphically by use of data from selected representative studies. Water samples collected in September and November 1996, from 46 springs throughout the watershed were analyzed for chlorofluorocarbons (CFC?s) to estimate the apparent age of ground water. For comparison purposes, apparent ages of water from springs were calculated assuming piston flow. Additi-onal data are given to estimate apparent ages assuming an exponential distribution of ages in spring discharge. Additionally, results from previous studies of CFC-dating of ground water from other springs and wells in the watershed were compiled. The CFC data, and the data on major ions, nutrients, and nitrogen isotopes in the water collected from the 46 springs are included in this report. The apparent ages of water discharging from 30 of the 46 springs sampled were less than 20 years, including 5 that were 'modern' (0-4 years). Four samples had apparent ages of 22 to 34 years, and two others from thermal springs were 40 years or greater. The remaining ten samples were contaminated with local sources of CFC and could not be dated. Nitrate concentrations and nitrate delta 15 nitrogen (15N) values in water from many springs are similar to those in shallow ground water beneath fertilized fields, and some values are high enough to indicate a probable source from animal-waste components. The nitrogen data reported here highlight the significance of the springs sampled during this study as pathways for nutrient transport in the Chesapeake Bay watershed. Ground-water samples were collected from springs during an unusually high flow period and thus may not be representative of low base-flow conditions. Residence times estimated from plausible ranges of aquifer properties and results of previous age-dating analyses generally corroborate the apparent-age analysis made in the current study and suggests that some residence times could be much longer. The shortest residence times tend to be in the Blue Ridge and northern carbonate areas; however, the data are preliminary and not appropriate for statistical tests of significance or variance. Because the age distributions in the aquifer discharging to the springs are not known, and because the apparent ages of water from the springs are based on various com-binations of CFC criteria, the apparent ages and calculated residence times are compared for illustrative purposes but are considered preliminary until further work is accomplished.

Chemistry of spring and well waters on Kilauea Volcano, Hawaii, and vicinity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Janik, C.J.; Nathenson, M.; Scholl, M.A.

1994-12-31

Published and new data for chemical and isotopic samples from wells and springs on Kilauea Volcano and vicinity are presented. These data are used to understand processes that determine the chemistry of dilute meteoric water, mixtures with sea water, and thermal water. Data for well and spring samples of non-thermal water indicate that mixing with sea water and dissolution of rock from weathering are the major processes that determine the composition of dissolved constituents in water. Data from coastal springs demonstrate that there is a large thermal system south of the lower east rift of Kilauea. Samples of thermal watermore » from shallow wells in the lower east rift and vicinity have rather variable chemistry indicating that a number of processes operate in the near surface. Water sampled from the available deep wells is different in composition from the shallow thermal water, indicating that generally there is not a significant component of deep water in the shallow wells. Data for samples from available deep wells show significant gradients in chemistry and steam content of the reservoir fluid. These gradients are interpreted to indicate that the reservoir tapped by the existing wells is an evolving vapor-dominated system.« less

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

USGS Publications Warehouse

Hoos, Anne B.

1990-01-01

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee?s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable

Occurrence of anthropogenic organic compounds in ground water and finished water of community water systems in Eagle and Spanish Springs Valleys, Nevada, 2002-2004

USGS Publications Warehouse

Rosen, Michael R.; Shaefer, Donald H.; Toccalino, Patricia A.; Delzer, Gregory C.

2006-01-01

As a part of the U.S. Geological Survey's National Water-Quality Assessment Program, an effort to characterize the quality of major rivers and aquifers used as a source of supply to some of the largest community water systems (CWSs) in the United States has been initiated. These studies, termed Source Water-Quality Assessments (SWQAs), consist of two sampling phases. Phase 1 was designed to determine the frequency of detection and concentrations of about 260 volatile organic compounds (VOCs), pesticides and pesticide degradates, and other anthropogenic organic compounds in source water of 15 CWS wells in each study. Phase 2 monitors concentrations in the source water and also the associated finished water of CWSs for compounds most frequently detected during phase 1. One SWQA was completed in the Nevada Basin and Range area in Nevada. Ten CWS wells in Eagle Valley and five CWS wells in Spanish Springs Valley were sampled. For phase 2, two wells were resampled in Eagle Valley. Samples were collected during 2002-2004 for both phases. Water use in Eagle Valley is primarily for domestic purposes and is supplied through CWSs. Ground-water sources provide about 55 percent of the public-water supply, and surface-water sources supply about 45 percent. Lesser amounts of water are provided by domestic wells. Very little water is used for agriculture or manufacturing. Spanish Springs Valley has water-use characteristics similar to those in Eagle Valley, although there is more agricultural water use in Spanish Springs Valley than in Eagle Valley. Maximum contaminant concentrations were compared to two human-health benchmarks, if available, to describe the water-quality data in a human-health context for these findings. Measured concentrations of regulated contaminants were compared to U.S. Environmental Protection Agency and Nevada Maximum Contaminant Level (MCL) values. Measured concentrations of unregulated contaminants were compared to Health-Based Screening Levels, which are not regulatory standards and are not legally enforceable values. All of the contaminants detected in this study were found at concentrations less than available human-health benchmarks. In the source waters sampled in phase 1, 10 contaminants of the approximately 260 measured were detected in samples collected from Eagle Valley, and 4 contaminants were detected in samples from Spanish Springs Valley. The most frequently detected compounds in the Eagle Valley source water were chloroform (a disinfection by-product), which was detected in samples from four wells, and deethylatrazine (a degradation product of the herbicide atrazine), which was detected in samples from three wells. Each of the four contaminants detected in the Spanish Springs Valley source waters was detected in samples from one well. The detection frequencies of VOCs and pesticides in samples from the SWQA wells were similar to those in samples from both shallow and deep monitoring wells in Carson City, Reno, and Spanish Springs. This indicates that the SWQA sampling is representative of the organic chemical compounds likely to be detected in the aquifers sampled. However, more organic compounds were detected at low frequencies and concentrations in samples from the monitoring wells than in samples from SWQA wells. Three contaminants were detected in one finished-water sample collected from Eagle Valley. Comparison of SWQA results in the Nevada Basin and Range Study Unit to results of an SWQA in the larger urban area of Salt Lake City showed that fewer anthropogenic compounds were detected in Eagle and Spanish Springs Valleys and generally at lower concentrations than in the Salt Lake City study.

1988 Hanford riverbank springs characterization report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dirkes, R.L.

1990-12-01

This reports presents the results of a special study undertaken to characterize the riverbank springs (i.e., ground-water seepage) entering the Columbia River along the Hanford Site. Radiological and nonradiological analyses were performed. River water samples were also analyzed from upstream and downstream of the Site as well as from the immediate vicinity of the springs. In addition, irrigation return water and spring water entering the river along the shoreline opposite Hanford were analyzed. Hanford-origin contaminants were detected in spring water entering the Columbia River along the Hanford Site. The type and concentrations of contaminants in the spring water were similarmore » to those known to exist in the ground water near the river. The location and extent of the contaminated discharges compared favorably with recent ground-water reports and predictions. Spring discharge volumes remain very small relative to the flow of the Columbia. Downstream river sampling demonstrates the impact of ground-water discharges to be minimal, and negligible in most cases. Radionuclide concentrations were below US Department of Energy Derived Concentration Guides (DCGs) with the exception {sup 90}Sr near the 100-N Area. Tritium, while below the DCG, was detected at concentrations above the US Environmental Protection Agency drinking water standards in several springs. All other radionuclide concentrations were below drinking water standards. Nonradiological contaminants were generally undetectable in the spring water. River water contaminant concentrations, outside of the immediate discharge zones, were below drinking water standards in all cases. 19 refs., 5 figs., 12 tabs.« less

Effects of septic-tank effluent on ground-water quality in northern Williamson County and southern Davidson County, Tennessee

USGS Publications Warehouse

Hanchar, D.W.

1991-01-01

An investigation of the potential contamination of ground water from septic tank systems blasted in bedrock in Williamson and Davidson Counties, Tennessee, was conducted during 1988-89. Water samples were collected from domestic and observation wells, springs, and surface-water sites in a residential subdivision in the northern part of Williamson County near Nashville. The subdivision has a high density of septic-tank field lines installed into blasted bedrock Water samples also were collected from a well located in an area of Davidson County where field lines were installed in 5 feet of soil. Samples were analyzed for major inorganic constituents, nutrients, total organic carbon, optical brighteners, and bacteria. Although results of analyses of water samples from wells indicate no effect of septic-tank effluent on ground-water quality at these sites, water from two springs located downgradient from the subdivision had slightly larger concentrations of nitrite plus nitrate (2.2 and 2.7 milligrams per liter N), and much larger concentrations of fecal coliform and fecal streptococci bacteria (2,000 to 3,200 and 700 to 900 colonies per 100 milliliters of sample, respectively), than other wells and springs sampled during 1988. Water from one of these springs contained optical brighteners, which indicates that septic-tank effluent is affecting ground-water quality.

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

USGS Publications Warehouse

Beisner, Kimberly R.; Paretti, Nicholas; Tillman, Fred; Naftz, David L.; Bills, Donald; Walton-Day, Katie; Gallegos, Tanya J.

2017-01-01

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234U/238U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.

Effect of water stage and tree stand composition on spatiotemporal differentiation of spring water chemistry draining Carpathian flysch slopes (Gorce Mts).

PubMed

Jasik, Michał; Małek, Stanisław; Żelazny, Mirosław

2017-12-01

The purpose of this study was to identify the factors affecting spring water chemistry in different tree stands and to measure the influence of water stage on the physicochemical parameters of spring waters in a small Carpathian catchment. Water samples were collected three times per year at various stages of the water: after the spring thaw, after a period of heavy rain and after a dry period in 2011 and 2012. Water samples were left in the laboratory to reach room temperature (19-20°C) and analyzed for EC (reference T=25°C) and pH. After filtration through 0.45μm PTFE syringe filters, the water samples were analyzed by means of ion chromatography using a DIONEX ICS 5000 unit. The following ions were analyzed: Ca 2+ , Mg 2+ , Na + , K + , HCO 3 - , SO 4 2- , Cl - , and NO 3 - . Multivariate analysis (PCA) allowed the identification of two factors of spring water chemistry: factor 1, water stage and factor 2 tree stand composition. Seasonal variation of spring water chemistry showed that, higher pH values and mineralization as well as higher concentrations of Ca 2+ and Mg 2+ were measured during low water stage periods while lower EC and pH values were noted after spring snowmelt and rainfall, when higher concentrations of NO 3 - and SO 4 2- were also found. Higher concentrations of Ca 2+ and Mg 2+ and higher pH of spring waters located in beech-fir stands and in those mixed with a large proportion of beech as well as a lower concentration of Ca 2+ , Mg 2+ and HCO 3 - , pH, conductivity and mineralization of these spring waters, in which the alimentation areas were covered by upper subalpine spruce stands were noted. Copyright © 2017 Elsevier B.V. All rights reserved.

The comparison of heavy metals (Pb and Cd) in the water and sediment during spring and neap tide tidal periods in Popoh Bay, Indonesia

NASA Astrophysics Data System (ADS)

Yona, D.; Febriana, R.; Handayani, M.

2018-04-01

This study attempted to investigate different concentration of lead (Pb) dan cadmium (Cd) in the water and sediment during spring and neap tidal periods in the Popoh Bay, Indonesia. Water and sediment samples were taken during spring and neap tides from eight sampling stations in the study area. The result shows higher concentration of Pb than the concentration of Cd in both spring and neap tides due to higher input of Pb from the oil pollution by boat and fisheries activities. Pb concentrations were doubled during neap tide in both water and sediments with the value of 0.51 and 0.28 ml/L in the water during neap and spring tide, respectively; and 0.27 ppm and 0.16 mg/kg in the sediment during neap and spring tide, respectively. On the other hand, Cd concentrations in the water were found in almost similar values between spring and neap tide (0.159 and 0.165 ml/L in spring tide and neap tide, respectively), but in the sediment, the concentration was a little higher during spring tide (0.09 and 0.05 mg/kg during spring and neap tide, respectively). This study shows that water movement during spring and neap tides has significant effect on the distribution of heavy metals.

Neutral degradates of chloroacetamide herbicides: occurrence in drinking water and removal during conventional water treatment.

PubMed

Hladik, Michelle L; Bouwer, Edward J; Roberts, A Lynn

2008-12-01

Treated drinking water samples from 12 water utilities in the Midwestern United States were collected during Fall 2003 and Spring 2004 and were analyzed for selected neutral degradates of chloroacetamide herbicides, along with related compounds. Target analytes included 20 neutral chloroacetamide degradates, six ionic chloroacetamide degradates, four parent chloroacetamide herbicides, three triazine herbicides, and two neutral triazine degradates. In the fall samples, 17 of 20 neutral chloroacetamide degradates were detected in the finished drinking water, while 19 of 20 neutral chloroacetamide degradates were detected in the spring. Median concentrations for the neutral chloroacetamide degradates were approximately 2-60ng/L during both sampling periods. Concentrations measured in the fall samples of treated water were nearly the same as those measured in source waters, despite the variety of treatment trains employed. Significant removals (average of 40% for all compounds) were only found in the spring samples at those utilities that employed activated carbon.

Fluoride content and distribution pattern in groundwater of eastern Yunnan and western Guizhou, China.

PubMed

Luo, Kunli; Liu, Yonglin; Li, Huijie

2012-02-01

For study, the fluoride (F) content and distribution pattern in groundwater of eastern Yunnan and western Guizhou fluorosis area in southwestern China, the F content of 93 water samples [groundwater (fissure water, cool spring, and hot springs), rivers water] and 60 rock samples were measured. The result shows the F content of the fissure water and cold spring water is 0.027-0.47 mg/L, and river water is 0.048-0.224 mg/L. The F content of hot spring water is 1.02-6.907 mg/L. The drinking water supplied for local resident is mainly from fissure water, cool spring, and river water. And the F content in all of them is much lower than the Chinese National Standard (1.0 mg/L), which is the safe intake of F in drinking water. The infected people in eastern Yunnan and western Guizhou fluorosis area have very little F intake from the drinking water. The hot spring water in fluorosis area of eastern Yunnan and western Guizhou, southwest China has high F content, which is not suitable for drinking. © Springer Science+Business Media B.V. 2011

Prevalence and Genetic Diversity of Enterococcus faecalis Isolates from Mineral Water and Spring Water in China.

PubMed

Wei, Lei; Wu, Qingping; Zhang, Jumei; Guo, Weipeng; Chen, Moutong; Xue, Liang; Wang, Juan; Ma, Lianying

2017-01-01

Enterococcus faecalis is an important opportunistic pathogen which is frequently detected in mineral water and spring water for human consumption and causes human urinary tract infections, endocarditis and neonatal sepsis. The aim of this study was to determine the prevalence, virulence genes, antimicrobial resistance and genetic diversity of E. faecalis from mineral water and spring water in China. Of 314 water samples collected from January 2013 to January 2014, 48 samples (15.3%) were contaminated E. faecalis . The highest contamination rate occurred in activated carbon filtered water of spring water (34.5%), followed by source water of spring water (32.3%) and source water of mineral water (6.4%). The virulence gene test of 58 E. faecalis isolates showed that the detection rates of asa1 , ace , cylA , gelE and hyl were 79.3, 39.7, 0, 100, 0%, respectively. All 58 E. faecalis isolates were not resistant to 12 kinds of antibiotics (penicillin, ampicillin, linezolid, quinupristin/dalfopristin, vancomycin, gentamicin, streptomycin, ciprofloxacin, levofloxacin, norfloxacin, nitrofurantoin, and tetracycline). Enterobacterial repetitive intergenic consensus-PCR classified 58 isolates and three reference strains into nine clusters with a similarity of 75%. This study is the first to investigate the prevalence of E. faecalis in mineral water and spring water in China. The results of this study suggested that spring water could be potential vehicles for transmission of E. faecalis .

Hydrology, Water Quality, and Aquatic Communities of Selected Springs in the St. Johns River Water Management District, Florida

USGS Publications Warehouse

Walsh, Stephen J.; Knowles, Leel; Katz, Brian G.; Strom, Douglas G.

2009-01-01

Hydrologic, physicochemical, and aquatic community data were collected and compiled by the U.S. Geological Survey for selected springs within the St. Johns River Water Management District from January 2004 to October 2007. Nine springs were included in this study: Alexander, Apopka, Bugg, De Leon, Gemini, Green, Rock, Silver Glen, and Wekiwa. Urban lands increased in Alexander, Apopka, De Leon, Gemini, Green, and Wekiwa springsheds between 1973 and 2004, accompanied by a loss of forested and/or agricultural lands in most springsheds. Forested cover increased and open surface waters and wetlands decreased in the Bugg and Rock springsheds. Although rainfall did not change significantly over time in each springshed, spring discharge decreased significantly in De Leon, Fern Hammock, Rock, Silver, and Wekiwa Springs. Nitrate concentrations increased significantly with time in Apopka, Fern Hammock, Gemini Springs run, and Juniper Springs, and decreased significantly in Alexander Spring, Bugg Spring run, Rock Springs, and Wekiwa Springs. Phosphorus increased significantly with time in Juniper Springs and decreased significantly in Apopka, De Leon, Rock, Silver Glen, and Wekiwa Springs. Benthic macroinvertebrate communities ranged from relatively low diversity assemblages (Green Spring) to assemblages with high taxonomic richness, diversity, and dominance (Rock and De Leon Springs). Shannon-Wiener diversity index averages among samples pooled by spring were lowest for Apopka Spring and greatest for Rock, Bugg, and Silver Glen Springs. Mean Stream Condition Index for pooled samples per spring was lowest for De Leon and Gemini Springs and highest for Rock and Wekiwa Springs. Mean percentages of very tolerant taxa were lowest for Alexander Spring and highest for Bugg and Green Springs. Fish community richness was lowest for Green Spring, and greatest for Alexander Spring run and Silver Glen Springs. Forty five fish species representing 35 genera and 23 families were collected or observed from all springs in this study. Samples were dominated by centrarchids, cyprinids, fundulids, atherinopsids, and poeciliids.

Contamination investigation in a karst region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bentowski, J.E.

1993-03-01

A series of springs in the karst region of north central Kentucky appeared to have been contaminated. These springs are within 1/2 mile of two sinkholes which were filled-in as permitted landfills for inert waste and then developed into an industrial park. A pre-remedial site inspection was performed under the authority of the Superfund laws in late 1989. A preliminary site visit included site reconnaissance and geologic field work to locate the springs. A review of historical serial photos aided in the planning the investigation program consisting of magnetic and soil gas surveys and the taking environmental soil and watermore » samples. The soil gas survey indicated potential soil sampling locations. Seventeen surface and subsurface soil samples were taken. Eleven water samples were taken from various springs, rivers and the local public water supply. The analytical results from soil samples taken over the largest sinkhole matched nine inorganic and eleven volatile organic compounds also found in the spring water and sediment samples. The springs are roughly on strike with major fracture systems reported in the literature. The success of this investigation emphasizes the importance of proper geologic consideration for contaminant monitoring in karst regions.« less

Construction, lithologic, and water-level data for wells near the Dickson County landfill, Dickson County, Tennessee, 1995

USGS Publications Warehouse

Ladd, D.E.

1996-01-01

Organic compounds were detected in water samples collected from Sullivan Spring during several sampling events in 1994. Prior to this, the spring was the drinking-water source for two families in the Dickson, Tennessee area. An investigation was conducted by the U.S. Geological Survey, in cooperation with Dickson County Solid Waste Management, to determine if Sullivan Spring is hydraulically downgradient from the Dickson County landfill. This report describes the data collected during the investigation. Five monitoring wells were installed near the northwestern corner of the landfill at points between the landfill and Sullivan Spring. Water-level measurements were made on June 1 and 2, 1995, at these wells and 13 other wells near the landfill to determine ground- water altitudes in the area. Water-level altitudes in the five new monitoring wells and three other landfill-monitoring wells were higher (750.04 to 800.17 feet) than the altitude of Sullivan Spring (approximately 725 feet). In general, wells in topographically high areas had higher water-level altitudes than Sullivan Spring and wells near streams in lowland areas.

Water resources of Hot Springs County, Wyoming

USGS Publications Warehouse

Plafcan, Maria; Ogle, Kathy Muller

1994-01-01

The wells and springs inventoried in Hot Springs County most commonly had been completed in or issued from the Quaternary alluvium, Quaternary terrace deposits, Fort Union and Mesaverde Formations, Cody Shale, and the Frontier and Chugwater Formations. The largest discharges measured were from the Quaternary terrace deposits (400 gallons per minute) and the Phosphoria Formation (1,000 gallons per minute). Discharges from all other geologic units varied, but most wells and springs yielded 50 gallons per minute or less.Water-quality samples collected from springs that issued from the Absaroka Volcanic Supergroup, the Bighorn Dolomite, and the Flathead Sandstone had the lowest dissolved-solids concentrations, which ranged from 58 to 265 milligrams per liter, and the least variable water types. Water from the volcanic rocks was a sodium bicarbonate type; whereas, water from the Flathead Sandstone was a calcium bicarbonate type. Water types for all the other aquifers varied from sampling site to sampling site; however, water samples from the Fort Union Formation and the Cody Shale were consistently of the sodium sulfate type. The effect of oil- and gas-development at Hamilton Dome on thermal spring discharges at Hot Springs State Park near Thermopolis was studied. The estimated drawdown from 1918, when the Hamilton Dome oil field was discovered, to 1988 was made using drill-stem data from previous studies. Drawdown at Big Spring in the Park was estimated to be less than 3 feet on the basis of recent oil- and water-production data, previous modeling studies, and the estimated water-level drawdown of 330 feet in wells at the Hamilton Dome oil field.Streams originating in the Plains region of the county, such as Middle Fork Owl Creek, are ephemeral or intermittent; whereas, streams originating in the mountains, such as Gooseberry Creek, are perennial. Average annual runoff across the county ranges from 0.26 inches at a representative streamflow-gaging station near Worland in the plains region to 5.4 inches in the Owl Creek Mountains and southeastern Absaroka Range.

Compilation of hydrologic data for White Sands pupfish habitat and nonhabitat areas, northern Tularosa Basin, White Sands Missile Range and Holloman Air Force Base, New Mexico, 1911-2008

USGS Publications Warehouse

Naus, C.A.; Myers, R.G.; Saleh, D.K.; Myers, N.C.

2014-01-01

The White Sands pupfish (Cyprinodon tularosa), listed as threatened by the State of New Mexico and as a Federal species of concern, is endemic to the Tularosa Basin, New Mexico. Because water quality can affect pupfish and the environmental conditions of their habitat, a comprehensive compilation of hydrologic data for pupfish habitat and nonhabitat areas in the northern Tularosa Basin was undertaken by the U.S. Geological Survey in cooperation with White Sands Missile Range. The four locations within the Tularosa Basin that are known pupfish habitat areas are the Salt Creek, Malpais Spring and Malpais Salt Marsh, Main Mound Spring, and Lost River habitat areas. Streamflow data from the Salt Creek near Tularosa streamflow-gaging station indicated that the average annual mean streamflow and average annual total streamflow for water years 1995–2008 were 1.35 cubic feet per second (ft3/s) and 983 acre-feet, respectively. Periods of no flow were observed in water years 2002 through 2006. Dissolved-solids concentrations in Salt Creek samples collected from 1911 through 2007 ranged from 2,290 to 66,700 milligrams per liter (mg/L). The average annual mean streamflow and average annual total streamflow at the Malpais Spring near Oscura streamflow-gaging station for water years 2003–8 were 6.81 ft3/s and 584 acre-feet, respectively. Dissolved-solids concentrations for 16 Malpais Spring samples ranged from 3,882 to 5,500 mg/L. Isotopic data for a Malpais Spring near Oscura water sample collected in 1982 indicated that the water was more than 27,900 years old. Streamflow from Main Mound Spring was estimated at 0.007 ft3/s in 1955 and 1957 and ranged from 0.02 to 0.07 ft3/s from 1996 to 2001. Dissolved-solids concentrations in samples collected between 1955 and 2007 ranged from an estimated 3,760 to 4,240 mg/L in the upper pond and 4,840 to 5,120 mg/L in the lower pond. Isotopic data for a Main Mound Spring water sample collected in 1982 indicated that the water was about 19,600 years old. Dissolved-solids concentrations of Lost River samples collected from 1984 to 1999 ranged from 8,930 to 118,000 (estimated) mg/L. Dissolved-solids concentrations in samples from nonhabitat area sites ranged from 1,740 to 54,200 (estimated) mg/L. In general, water collected from pupfish nonhabitat area sites tends to have larger proportions of calcium, magnesium, and sulfate than water from pupfish habitat area sites. Water from springs associated with mounds in pupfish nonhabitat areas was of a similar type (calcium-sulfate) to water associated with mounds in pupfish habitat areas. Alkali Spring had a sodium-chloride water type, but the proportions of sodium-chloride and magnesium-sulfate are unique as compared to samples from other sites.

Goodenough Spring, Texas, USA: Discharge and water chemistry of a large spring deeply submerged under the binational Amistad Reservoir

NASA Astrophysics Data System (ADS)

Kamps, Ray H.; Tatum, Gregg S.; Gault, Mike; Groeger, Alan W.

2009-06-01

Goodenough Spring (Texas, USA) is a large spring near the border of the American state of Texas and the Mexican state of Coahuila, discharging into the international Amistad Reservoir on the river Rio Grande (Rio Bravo). Discharge was routinely measured from 1928 until 1968 to partition the flow of the river between the two countries in accordance with water-use treaties. Samples were analyzed for water-quality parameters in 1967-1968 prior to inundation under 45 m of Amistad Reservoir in 1968. Subsequently, discharge has been estimated indirectly by the International Boundary and Water Commission (IBWC). For the first direct measurements of the spring in 37 years, velocity and cross-sectional measurements were made and water samples collected in the summer of 2005 using advanced self-contained underwater breathing apparatus (SCUBA) techniques. Spring discharge was calculated at 2.03 m3 s-1, approximately one-half of the historical mean of 3.94 m3 s-1. In situ and laboratory analyses of samples for temperature, pH, dissolved oxygen, specific conductance, alkalinity, nitrate-nitrogen, dissolved solids, chloride, sulfate, fluoride, phosphorus, calcium, sodium, potassium, magnesium, and iron showed the water quality to be very good for human consumption and crop irrigation. Measurement values are relatively unchanged from those reported 37 years prior.

Assessment of physico-chemical quality of borehole and spring water sources supplied to Robe Town, Oromia region, Ethiopia

NASA Astrophysics Data System (ADS)

Shigut, Dagim Abera; Liknew, Geremew; Irge, Dejene Disasa; Ahmad, Tanweer

2017-03-01

The study was carried out to find the physico-chemical water quality of borehole and spring water supplied to Robe Town. For this study, a total of six water samples were collected from three borehole and three spring water sources. The analyses for 14 physico-chemical parameters, pH, turbidity, electrical conductivity, total dissolved solids, total suspended solids total hardness cations (Ca2+, Mg2+), anions (NO2 -, NO3 -, SO4 2- and PO4 3-) and heavy metals (Fe and Mn), were done in the laboratory by adopting standard procedures suggested by the American Public Health Association (APHA). Descriptive statistics were used to describe data, while Pearson correlation was used to determine the influences of the physico-chemical variables. The single factor analysis of variance ( t test) was used to determine possible differences between the borehole and spring water, while means plots were used for further structure detection. From the total samples analyzed, most of the samples comply with the water quality guidelines of Ethiopian limit, WHO and U.SEPA. The pH of the water samples from borehole groundwater source was found to be slightly acidic and bove the maximum permissible limit (MPL). High concentration of Fe and Mn that exceeds the MPL set by WHO was found in the three boreholes. The spring water sources were found to be better for drinking than borehole water sources.

Chemistry of ground water in the Silver Springs basin, Florida, with an emphasis on nitrate

USGS Publications Warehouse

Phelps, G.G.

2004-01-01

The Silver Springs group, in central Marion County, Florida, has a combined average discharge rate of 796 cubic feet per second and forms the headwaters of the Silver River. The springs support a diverse ecosystem and are an important cultural and economic resource. Concentrations of nitrite-plus-nitrate (nitrate-N) in water from the Main Spring increased from less than 0.5 milligrams per liter (mg/L) in the 1960s to about 1.0 mg/L in 2003. The Upper Floridan aquifer supplies the ground water to support spring discharge. This aquifer is at or near land surface in much of the ground-water basin; nutrients leached at land surface can easily percolate downward into the aquifer. Sources of nitrogen in ground water in the Silver Springs basin include atmospheric deposition, fertilizers used by agricultural and urban activities, and human and animal wastes. During 2000-2001, 56 wells in the area contributing recharge to Silver Springs were sampled for major ions, nutrients, and some trace constituents. Selected wells also were sampled for a suite of organic constituents commonly found in domestic and industrial wastewater and for the ratio of nitrogen isotopes (15N/14N) to better understand the sources of nitrate. Wells were selected to be representative of both confined and unconfined conditions of the Upper Floridan aquifer, as well as a variety of land-use types. Data from this study were compared to data collected from 25 wells in 1989-90. Concentrations of nitrate-N in ground water during this study ranged from less than the detection limit of 0.02 to 12 mg/L, with a median of 1.2 mg/L. For data from 1989-90, the range was from less than 0.02 to 3.6 mg/L, with a median of 1.04 mg/L. Water from wells in agricultural land-use areas had the highest median nitrate-N concentration (1.7 mg/L), although it is uncertain if the 12 mg/L maximum concentration was influenced by land-use activities or proximity to a septic tank. The median value for all urban land-use areas was 1.15 mg/L. Because fewer wells were in rangeland or forested areas, those categories were grouped together. The median concentration for that group was 0.09 mg/L. The ratio of 15N/14N in ground-water samples ranged from -0.5 to 11.5 per mil. The median value for ground-water samples from 35 wells, 4.9 per mil, is near the top of the range that indicates inorganic nitrogen sources. In agricultural areas, the median 15N/14N was 4.8 per mil, indicating mostly inorganic (fertilizer) sources. In urban areas, the median 15N/14N was 5.4 per mil, indicating more influence of organic nitrogen (N) sources. Thus, in both agricultural and urban areas, fertilizer is an important inorganic source of N in ground water (and, therefore, in spring water as well). The influence of organic N is more apparent in urban areas than in agricultural areas. Two distinct 15N/14N values were observed in water from the Main Spring, one indicating an inorganic nitrogen source and the other indicating a mixture of sources with a strong influence of organic nitrogen. Thirty-five wells and three springs of the Silver Springs group (the Main Spring, the Abyss, and the Blue Grotto) were sampled for a suite of 63 compounds common in wastewater. A total of 38 compounds was detected, nearly all in very low concentrations. The most frequently detected compound was the insecticide N,N-diethyl-meta-toluamide (DEET), which was detected in water from 27 wells and all three springs. The presence or absence of DEET in ground-water samples did not seem to be related to land use; however, hydrogeologic conditions at the well sites (confined or unconfined) generally did affect the presence or absence of DEET in the ground water. DEET also appears to be a useful tracer for the presence of reused water. Water samples were collected from the Main Spring and two other springs of the Silver Springs group and analyzed for concentrations of dissolved gasses and for chlorofluorocarbons (CFCs), sulfur hexaflu

Cooperative geochemical investigation of geothermal resources in the Imperial Valley and Yuma areas. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coplen, T.B.

1973-10-01

Preliminary studies indicate that the Imperial Valley has a large geothermal potential. In order to delineate additional geothermal systems a chemical and isotopic investigation of samples from water wells, springs, and geothermal wells in the Imperial Valley and Yuma areas was conducted. Na, K, and Ca concentrations of nearly 200 well water, spring water, hot spring, and geothermal fluid samples from the Imperial Valley area were measured by atomic absorption spectrophotometry. Fournier and Truesdell's function was determined for each water sample. Suspected geothermal areas are identified. Hydrogen and oxygen isotope abundances were determined in order to determine and to identifymore » the source of the water in the Mesa geothermal system. (JGB)« less

An examination of short-term variations in water quality at a karst spring in Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryan, M.; Meiman, J.

1996-01-01

Water quality at many karst springs undergoes very high amplitude but relatively brief degradation following influxes of runoff. Accurately recording transient variations requires more rigorous sampling strategies than traditional methods. A pilot study to determine the usefulness of high-frequency, flow-dependent sampling strategies, combined with coincidental quantitative dye tracer tests, was implemented in the Big Spring Ground-Water Basin in Mammoth Cave National Park, Kentucky. Data recorded following two separate runoff events showed that the concentrations of two nonpoint source pollutants, fecal coliform bacteria and suspended sediment, greatly exceeded prerunoff event values for very short periods of time. A phreatic conduit segment,more » calculated at 17 million liters in volume, instantaneously propagated head changes, caused by direct runoff entering the aquifer, from the ground-water inputs to Big Spring. A significant delay between the initial increases in discharge and the arrival of direct runoff, as indicated by a steady decrease in specific conductance, represented the time required to displace this volume of phreatic water. The delay showed that sampling a karst spring only during peak discharge would be an unreliable sampling method. Runoff from two different subcatchments was tagged with tracer dye and the timing of the passage of the resultant dye clouds through Big Spring were compared to water quality variations. Distinct lag times between the arrival of direct runoff at Big Spring and the bacteria and suspended sediment waveforms were shown through the concurrent quantitative tracer tests to be related to the areal distribution of land-cover type within the basin.« less

Water-quality data collected to determine the presence, source, and concentration of lead in the drinking water supply at Pipe Spring National Monument, northern Arizona

USGS Publications Warehouse

Macy, Jamie P.; Sharrow, David; Unema, Joel

2013-01-01

Pipe Spring National Monument in northern Arizona contains historically significant springs. The groundwater source of these springs is the same aquifer that presently is an important source of drinking water for the Pipe Spring National Monument facilities, the Kaibab Paiute Tribe, and the community of Moccasin. The Kaibab Paiute Tribe monitored lead concentrations from 2004 to 2009; some of the analytical results exceeded the U.S. Environmental Protection Agency action level for treatment technique for lead of 15 parts per billion. The National Park Service and the Kaibab Paiute Tribe were concerned that the local groundwater system that provides the domestic water supply might be contaminated with lead. Lead concentrations in water samples collected by the U.S. Geological Survey from three springs, five wells, two water storage tanks, and one faucet were less than the U.S. Environmental Protection Agency action level for treatment technique. Lead concentrations of rock samples representative of the rock units in which the local groundwater resides were less than 22 parts per million.

Water quality and aquatic toxicity data of 2002 spring thaw conditions in the upper Animas River watershed, Silverton, Colorado

USGS Publications Warehouse

Fey, D.L.; Wirt, L.; Besser, J.M.; Wright, W.G.

2002-01-01

This report presents hydrologic, water-quality, and biologic toxicity data collected during the annual spring thaw of 2002 in the upper Animas River watershed near Silverton, Colorado. The spring-thaw runoff is a concern because elevated concentrations of iron oxyhydroxides can contain sorbed trace metals that are potentially toxic to aquatic life. Water chemistry of streams draining the San Juan Mountains is affected by natural acid drainage and weathering of hydrothermal altered volcanic rocks and by more than a century of mining activities. The timing of the spring-thaw sampling effort was determined by reviewing historical climate and stream-flow hydrographs and current weather conditions. Twenty-one water-quality samples were collected between 11:00 AM March 27, 2002 and 6:00 PM March 30, 2002 to characterize water chemistry at the A-72 gage on the upper Animas River below Silverton. Analyses of unfiltered water at the A-72 gage showed a relation between turbidity and total-recoverable iron concentrations, and showed diurnal patterns. Copper and lead concentrations were related to iron concentrations, indicating that these elements are probably sorbed to colloidal iron material. Calcium, strontium, and sulfate concentrations showed overall decreasing trends due to dilution, but the loads of those constituents increased over the sampling period. Nine water-quality samples were collected near the confluence of Mineral Creek with the Animas River, the confluence of Cement Creek with the Animas River, and on the upper Animas River above the confluence with Cement Creek (three samples at each site). A total of six bulk water-toxicity samples were collected before, during, and after the spring thaw from the Animas River at the A-72 gage site. Toxicity tests conducted with the bulk water samples on amphipods did not show strong differences in toxicity among the three sampling periods; however, toxicity of river water to fathead minnows showed a decreasing trend during the course of the study.

Groundwater quality at Alabama Plating and Vincent Spring, Vincent, Alabama, 2007–2008

USGS Publications Warehouse

Bradley, Michael W.; Gill, Amy C.

2014-01-01

The former Alabama Plating site in Vincent, Alabama, includes the location where the Alabama Plating Company operated an electroplating facility from 1956 until 1986. The operation of the facility generated waste containing cyanide, arsenic, cadmium, chromium, copper, lead, zinc, and other heavy metals. Contamination resulting from the site operations was identified in groundwater, soil, and sediment. Vincent Spring, used as a public water supply by the city of Vincent, Alabama, is located about ½ mile southwest of the site. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, conducted an investigation at Vincent Spring and the Alabama Plating site, Vincent, Alabama, during 2007–2008 to evaluate the groundwater quality and evaluate the potential effect of contaminated groundwater on the water quality of Vincent Spring. The results of the investigation will provide scientific data and information on the occurrence, fate, and transport of contaminants in the water resources of the area and aid in the evaluation of the vulnerability of the public water supply to contamination. Samples were analyzed to evaluate the water quality at the former plating site, investigate the presence of possible contaminant indicators at Vincent Spring, and determine the usefulness of stable isotopes and geochemical properties in understanding groundwater flow and contaminant transport in the area. Samples collected from 16 monitor wells near the plating site and Vincent Spring were analyzed for major constituents, trace metals, nutrients, and the stable isotopes for hydrogen (2H/H) and oxygen (18O/16O). Groundwater collected from Vincent Spring was characterized as a calcium-magnesium-bicarbonate water type with total dissolved solids concentrations ranging from 110 to 120 milligrams per liter and pH ranging from about 7.5 to 7.9 units. Groundwater chemistry at the monitor wells at the Alabama Plating site was highly variable by location and depth. Dissolved solids concentrations ranged from 28 to 2,880 milligrams per liter, and the water types varied from calcium-magnesium-bicarbonate-chloride, to calcium-sulfate or calcium-magnesium-sulfate, to sodium-chloride water types. The stable isotope ratios for hydrogen (2H/H) and oxygen (18O/16O) for water from the monitor wells and from Vincent Spring, based on a single sampling event, can be separated into three groups: (1) Vincent Spring, (2) monitor wells MW03 and MW28, and (3) the remaining Alabama Plating monitor wells. The geochemical and stable isotope analyses indicate that water from Vincent Spring is distinct from water from the Alabama Plating monitor wells; however, this evaluation is based on a single sampling event. Although the water from Vincent Spring, for this sampling event, is different and does not seem to be affected by contaminated groundwater from the Alabama Plating site, additional hydrologic and water-quality data are needed to fully identify flow paths, the potential for contaminant transport, and water-quality changes through time.

Uranium hydrogeochemical and stream sediment reconnaissance of the Albuquerque NTMS Quadrangle, New Mexico, including concentrations of forty-three additional elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maassen, L.W.; Bolivar, S.L.

1979-06-01

The Los Alamos Scientific Laboratory conducted a hydrogeochemical and stream sediment reconnaissance for uranium. Totals of 408 water and 1538 sediment samples were collected from 1802 locations over a 20 100-km/sup 2/ area at an average density of one location per 11 km/sup 2/. Water samples were collected from springs, wells, and streams; sediments samples were collected predominantly from streams, but also from springs. All water samples were analyzed for uranium and 12 other elements. Sediment samples were analyzed for uranium and 42 additional elements. The uranium concentrations in water samples range from below the detection limit of 0.02 ppBmore » to 194.06 ppB. The mean uranium concentration for all water types containing < 40 ppB uranium is 1.98 ppB. Six samples contained uranium concentrations > 40.00 ppB. Well waters have the highest mean uranium concentration; spring waters have the lowest. Clusters of water samples that contain anomalous uranium concentrations are delineated in nine areas. Sediments collected from the quadrangle have uranium concentrations that range between 0.63 ppM and 28.52 ppM, with a mean for all sediments of 3.53 ppM. Eight areas containing clusters of sediments with anomalous uranium concentrations are delineated. One cluster contains sample locations within the Ambrosia Lake uranium district. Five clusters of sediment samples with anomalous uranium concentrations were collected from streams that drain the Jemez volcanic field. Another cluster defines an area just northeast of Albuquerque where streams drain Precambrian rocks, predominantly granites, of the Sandia Mountains. The last cluster, consisting of spring sediments from Mesa Portales, was collected near the contact of the Tertiary Ojo Alamo sandstone with underlying Cretaceous sediments. Sediments from these springs exhibit some of the highest uranium values reported and are associated with high uranium/thorium ratios.« less

Field observations and management strategy for hot spring wastewater in Wulai area, Taiwan.

PubMed

Lin, J Y; Chen, C F; Lei, F R; Hsieh, C D

2010-01-01

Hot springs are important centers for recreation and tourism. However, the pollution that may potentially be caused by hot spring wastewater has rarely been discussed. More than half of Taiwan's hot springs are located in areas where the water quality of water bodies is to be protected, and untreated wastewater could pollute the receiving water bodies. In this study, we investigate hot spring wastewater in the Wulai area, one of Taiwan's famous hot spring resorts. Used water from five hot spring hotels was sampled and ten sampling events were carried out to evaluate the changes in the quality of used water in different seasons, at different periods of the week, and from different types of hotels. The concentrations of different pollutants in hot spring wastewater were found to exhibit wide variations, as follows: COD, 10-250 mg/L; SS, N.D.-93 mg/L; NH(3)-N, 0.01-1.93 mg/L; TP, 0.01-0.45 mg/L; and E. coli, 10-27,500 CFU/100 mL. The quality of hot spring wastewater depends on the operation of public pools, because this affects the frequency of supplementary fresh water and the outflow volume. Two management strategies, namely, onsite treatment systems and individually packaged treatment equipment, are considered, and a multi-objective optimization model is used to determine the optimal strategy.

Physicochemical and microbial assessment of spring water quality for drinking supply in Piedmont of Béni-Mellal Atlas (Morocco)

NASA Astrophysics Data System (ADS)

Barakat, Ahmed; Meddah, Redouane; Afdali, Mustapha; Touhami, Fatima

2018-04-01

The present study was conducted to examine the water quality of karst springs located along the Piedmont of Béni-Mellal Atlas (Morocco) for drinking purposes. Twenty-five water samples were collected from seven springs in June, July, August and September 2013, and May 2016 have been analyzed for their physicochemical and microbial characteristics. The analytical data of temperature, pH, DO, TAC, TH, oxidizability and NH4+ showed that all sampled springs are suitable as drinking water according to Moroccan and the World Health Organization (WHO) standards. Nevertheless, EC, turbidity, and NO3- were sometimes noted higher than the allowable limits, what would be ascribed to erosion and leaching of soil and karstic rocks. The microbial analysis revealed the presence of fecal contamination (total coliforms, E. coli, and intestinal enterococci) in all springs at various times. The water quality index (WQI) calculated based on physicochemical and microbial data reveled that water quality categorization for all sampling springs was found to be 'medium' to 'good' for drinking uses in the National Sanitation Foundation WQI (NSF-WQI), and ''necessary treatment becoming more extensive'' to ''purification not necessary'' in the Dinius' Second Index (D-WQI). The Aine Asserdoune and Foum el Anceur springs showed the good quality of drinking water. According to Moroccan standards for water used for drinking purposes, the waters belong to category A1 that requires becoming drinkable a simple physical treatment and disinfection. From the type of parameters present in quantities exceeding drinking water limits, it is very obvious that these water resources are under the influence of anthropogenic activities such as sewage, waste disposal, deforestation and agricultural activities, caused land degradation and nonpoint pollution sources. Environmental attention, such as systematic quality control and adequate treatment before being used for drinking use and access to sewage sanitation, are required to guarantee sufficient protection of the studied springs.

Environmental Survey of Drinking Water Sources in Kampala, Uganda, during a Typhoid Fever Outbreak

PubMed Central

Kahler, A. M.; Nansubuga, I.; Nanyunja, E. M.; Kaplan, B.; Jothikumar, N.; Routh, J.; Gómez, G. A.; Mintz, E. D.; Hill, V. R.

2017-01-01

ABSTRACT In 2015, a typhoid fever outbreak began in downtown Kampala, Uganda, and spread into adjacent districts. In response, an environmental survey of drinking water source types was conducted in areas of the city with high case numbers. A total of 122 samples was collected from 12 source types and tested for Escherichia coli, free chlorine, and conductivity. An additional 37 grab samples from seven source types and 16 paired large volume (20 liter) samples from wells and springs were also collected and tested for the presence of Salmonella enterica serovar Typhi. Escherichia coli was detected in 60% of kaveras (drinking water sold in plastic bags) and 80% of refilled water bottles; free chlorine was not detected in either source type. Most jerry cans (68%) contained E. coli and had free chlorine residuals below the WHO-recommended level of 0.5 mg/liter during outbreaks. Elevated conductivity readings for kaveras, refilled water bottles, and jerry cans (compared to treated surface water supplied by the water utility) suggested that they likely contained untreated groundwater. All unprotected springs and wells and more than 60% of protected springs contained E. coli. Water samples collected from the water utility were found to have acceptable free chlorine levels and no detectable E. coli. While S. Typhi was not detected in water samples, Salmonella spp. were detected in samples from two unprotected springs, one protected spring, and one refilled water bottle. These data provided clear evidence that unregulated vended water and groundwater represented a risk for typhoid transmission. IMPORTANCE Despite the high incidence of typhoid fever globally, relatively few outbreak investigations incorporate drinking water testing. During waterborne disease outbreaks, measurement of physical-chemical parameters, such as free chlorine residual and electrical conductivity, and of microbiological parameters, such as the presence of E. coli or the implicated etiologic agent, in drinking water samples can identify contaminated sources. This investigation indicated that unregulated vended water and groundwater sources were contaminated and were therefore a risk to consumers during the 2015 typhoid fever outbreak in Kampala. Identification of contaminated drinking water sources and sources that do not contain adequate disinfectant levels can lead to rapid targeted interventions. PMID:28970225

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas, Kansas, Missouri and Oklahoma, USA

USGS Publications Warehouse

Adamski, J.C.

2000-01-01

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate-rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field-measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water-rock interactions. Water from wells flow through small fractures, which restrict flow and increase water-rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright (C) 2000 John Wiley and Sons, Ltd.Geochemical data indicate that the Springfield Plateau carbonate aquifer has two distinct hydrochemical zones. With each hydrochemical zone, water from springs is geochemically and isotopically different from the water from wells. Spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Factors affecting the differences in the geochemical composition of groundwater between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zones.

Time-series variations in CFC and 3H/3He ages in springs discharging from an eogenetic karst aquifer (Invited)

NASA Astrophysics Data System (ADS)

Martin, J. B.; Kurz, M. J.; Khadka, M. B.; Cohen, M. J.

2013-12-01

One of the hallmarks of karst aquifers is rapid mixing between surface water and groundwater, which results in changes in flow and water chemistry at springs. Aquifers with little matrix porosity (telogenetic karst) tend to respond to storm events within days to weeks (e.g., are flashy) while aquifers characterized by elevated matrix porosity (eogenetic karst) may take months or years to respond. This response time is an important control on remediation of storm-derived contaminants as well as the magnitude of water-rock reactions that may result from mixing of surface water and groundwater with different compositions. Responses of flashy springs may be observed through time-series measurements of various solute compositions of the discharge, but response at springs discharging from eogenetic aquifers are difficult to observe because the chemical composition of the recharged storm water may be altered during its residence in the subsurface. For these aquifers, conservative tracers such as chlorofluorocarbon and 3H/3He ratios may provide useful information on the mixing, residence time, and variation in the average age of discharged water. We are testing this hypothesis at six springs discharging from the Floridan Aquifer to the Ichetucknee River in north Florida. Samples were first collected September 3, 2009 during record low flow when the river was discharging 7.2 m3/sec and subsequently after about 400 mm of rain fell over the springshed from June 23 to 26, 2012 during Tropical Storm Debby. Following the storm, samples were collected July 27, 2012 (all six springs) when flow had increased to 10.5 m3/sec. Three of the six springs were sampled during the recession on October 25, 2012 (Q = 10.3 m3/sec), February 14, 2013 (Q = 8.7 m3/sec), and May 16, 2013 (Q = 8.6 m3/sec). CFC dates are available now for all sampling times but 3H/3He dates are only available through October 25, 2012. The two different tracers yield conflicting results with CFC ages generally increasing from the low flow to flood samples while 3H/3He ages decrease in five of the six springs with increasing discharge. The age of the water would be expected to decrease following the storm, suggesting that the CFC data may be contaminated. Assuming the drought discharge is solely groundwater and the measured reduction in the 3H/3He ages originates from mixing old groundwater with zero-aged water from the storm, the fraction of discharging storm water ranged from 4 to 25% of the total discharge. This variation in the fraction of the storm-derived water corresponds to estimated depths of flow paths to the springs based on dissolved oxygen and temperature data. Springs originating from deep flow paths have smaller fractions of storm water. Time-series measurements of ages of water discharging from springs appear to be a useful technique for estimating fractions of storm derived water and possibly flow paths in springs discharging from eogenetic karst aquifers.

Trace metal contamination of mineral spring water in an historical mining area in regional Victoria, Australia

NASA Astrophysics Data System (ADS)

Martin, Rachael; Dowling, Kim

2013-11-01

Significant global consumption of spring and mineral water is fuelled by perceived therapeutic and medicinal qualities, cultural habits and taste. The Central Victorian Mineral Springs Region, Australia comprises approximately 100 naturally effervescent, cold, high CO2 content springs with distinctive tastes linked to a specific spring or pump. The area has a rich settlement history. It was first settled by miners in the 1840s closely followed by the first commercial operations of a health resort 1895. The landscape is clearly affected by gold mining with geographically proximal mine waste, mullock heaps or tailings. Repeated mineral springs sampling since 1985 has revealed elevated arsenic concentrations. In 1985 an arsenic concentration five times the current Australian Drinking Water Guideline was recorded at a popular tourist spring site. Recent sampling and analyses have confirmed elevated levels of heavy metals/metalloids, with higher concentrations occurring during periods of low rainfall. Despite the elevated levels, mineral water source points remain accessible to the public with some springs actively promoting the therapeutic benefits of the waters. In light of our analysis, the risk to consumers (some of whom are likely to be negatively health-affected or health-compromised) needs to be considered with a view to appropriate and verified analyses made available to the public.

Sources and chronology of nitrate contamination in spring waters, Suwannee River basin, Florida

USGS Publications Warehouse

Katz, Brian G.; Hornsby, H.D.; Bohlke, J.K.; Mokray, M.F.

1999-01-01

A multi-tracer approach, which consisted of analyzing water samples for n aturally occurring chemical and isotopic indicators, was used to better understand sources and chronology of nitrate contamination in spring wate rs discharging to the Suwannee and Santa Fe Rivers in northern Florida. Dur ing 1997 and 1998, as part of a cooperative study between the Suwannee River Water Management District and the U.S. Geological Survey, water samples were collected and analyzed from 24 springs and two wells for major ions, nutrients, dissolved organic carbon, and selected environmental isotopes [18O/16O, D/H, 13C/12C, 15N/14N]. To better understand when nitrate entered the ground-water system, water samples were analyzed for chlorofluorocarbons (CFCs; CCl3F, CCl2F2, and C2Cl3F3) and tritium (3H); in this way, the apparent ages and residence times of spring waters and water from shallow zones in the Upper Floridan aquifer were determined. In addition to information obtained from the use of isotopic and other chemical tracers, information on changes in land-use activities in the basin during 1954-97 were used to estimate nitrogen inputs from nonpoint sources for five counties in the basin. Changes in nitrate concentrations in spring waters with time were compared with estimated nitrogen inputs for Lafayette and Suwannee Counties. Agricultural activities [cropland farming, animal farming operations (beef and dairy cows, poultry, and swine)] along with atmospheric deposition have contributed large quantities of nitrogen to ground water in the Suwannee River Basin in northern Florida. Changes in agricultural land use during the past 40 years in Alachua, Columbia, Gilchrist, Lafayette, and Suwannee Counties have contributed variable amounts of nitrogen to the ground-water system. During 1955-97, total estimated nitrogen from all nonpoint sources (fertilizers, animal wastes, atmospheric deposition, and septic tanks) increased continuously in Gilchrist and Lafayette Counties. In Suwannee, Alachua, and Columbia Counties, estimated nitrogen inputs from all nonpoint sources peaked in the late 1970's corresponding to the peak use in fertilizer during this time. Fertilizer use in Columbia, Gilchrist, Lafayette, and Suwannee Counties increased substantially during 1993-97. The heavy use of fertilizers in the basin is corroborated by nitrogen isotope data. Values of d15N of nitrate (d15N-NO3) in spring waters range from 2.7 per mil (SUW718971) to 10.6 per mil (Poe Spring) with a median of 5.4 per mil. The range of values indicates that nitrate in the sampled spring waters most likely originates from a mixture of inorganic (fertilizers) and organic (animal wastes) sources; however, higher d15N values for Poe and Lafayette Blue Springs indicate that an organic source of nitrogen probably is contributing nitrate to these spring waters. Water samples from two wells sampled in Lafayette County have high d15N-NO3 values of 11.0 and 12.1 per mil, indicating the predominance of an organic source of nitrate. These two wells are located near dairy and poultry farms, where leachate from animal wastes may contribute nitrate to ground water. Dissolved-gas data (nitrogen, argon, and oxygen) indicate that denitrification has not removed large amounts of nitrate from the ground-water system. Thus, variations in d15N-NO3 values of spring waters can be attributed to variations in d15N-NO3 values of ground-water recharge, and can be used to obtain information about source(s) of nitrate. Extending the use of age-dating techniques (CFCs and 3H) to spring waters in complex karst systems required the use of several different approaches for estimating age and residence time of ground water discharging to springs. These approaches included the use of a simple reservoir model, a piston-flow model, an exponential model, and a binary-mixing model. When age data (CFC-11, CFC-113, and 3H) are combined for all springs, models that incorporate exponential mixtures seem to provide re

Ex vivo regenerative effects of a spring water.

PubMed

Nicoletti, Giovanni; Saler, Marco; Pellegatta, Tommaso; Tresoldi, Marco Mario; Bonfanti, Viola; Malovini, Alberto; Faga, Angela; Riva, Federica

2017-12-01

Previous experiments by our group have indicated the regenerative effects of a spring water (Comano), which was possibly associated with the native non-pathogenic bacterial flora. The present study aimed to confirm these regenerative properties in a human ex vivo experimental model in the context of physiological wound healing. Human 6-mm punch skin biopsies harvested during plastic surgery sessions were injured in their central portion to induce skin loss and were cultured in either conventional medium (controls) or medium powder reconstituted with filtered Comano spring water (treated samples). At 24, 48 and 72 h the specimens were observed following staining with hematoxylin and eosin, Picrosirius Red, orcein and anti-proliferating cell nuclear antigen. Compared with the controls, the treated samples exhibited reduced overall cell infiltration, evidence of fibroblasts, stimulation of cell proliferation and collagen and elastic fiber regeneration. In the spring water, in addition to 12 resident non-pathogenic bacterial strains exhibiting favorable metabolic activities, more unknown non-pathogenic species are being identified by genomic analysis. In the present study, the efficacy of this 'germ-free', filtered spring water in wound regeneration was indicated. Thus, the Comano spring water microbiota should be acknowledged for its regenerative properties.

Chemical characteristics of the major thermal springs of Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mariner, R.H.; Presser, T.S.; Evans, W.C.

1976-07-01

Twenty-one thermal springs in western Montana were sampled for chemical, isotope, and gas compositions. Most of the springs issue dilute to slightly saline sodium-bicarbonate waters of neutral to slightly alkaline pH. A few of the springs issue sodium-mixed anion waters of near neutral pH. Fluoride concentrations are high in most of the thermal waters, up to 18 miligrams per litre, while F/Cl ratios range from 3/1 in the dilute waters to 1/10 in the slightly saline waters. Most of the springs are theoretically in thermodynamic equilibrium with respect to calcite and fluorite. Nitrogen is the major gas escaping from mostmore » of the hot springs; however, Hunters Hot Springs issue principally methane. The deuterium content of the hot spring waters is typical of meteoric water in western Montana. Geothermal calculations based on silica concentrations and Na-K-Ca ratios indicate that most of the springs are associated with low temperature aquifers (less than 100/sup 0/C). Chalcedony may be controlling the silica concentrations in these low temperature aquifers even in ''granitic'' terranes.« less

Seasonal distribution and prevalence of diarrheagenic Escherichia coli in different aquatic environments in Taiwan.

PubMed

Huang, Wen-Chien; Hsu, Bing-Mu; Kao, Po-Min; Tao, Chi-Wei; Ho, Ying-Ning; Kuo, Chun-Wei; Huang, Yu-Li

2016-02-01

Diarrheagenic Escherichia coli (DEC) are the most common agents of diarrhea. Waterborne DEC could pose a potential health risk to human through agricultural, household, recreational, and industrial use. There are few published reports on the detection of DEC and its seasonal distribution in aquatic environments. The presence of DEC in different types of aquatic environments was investigated in this study. Water samples were collected from major rivers, water reservoirs, and recreational hot springs throughout Taiwan. Moreover, an intensive water sampling plan was carried out along Puzih River. The detection of DEC target genes was used to determine the presence of enterotoxigenic E. coli (ETEC), enteropathogenic E. coli (EPEC), and Shiga toxin-producing E. coli (STEC). Among the 383 water samples analyzed, DEC was found in 122 (31.8%) samples. The detection rate varied by genotype, raging from 3.6% for STEC to 17.2% for EPEC. The DEC detection rate was higher from river waters than reservoirs and hot springs. In addition, DEC was detected at a higher rate in spring and summer. The presence of EPEC was significantly associated with total coliform levels among hot spring samples. Moreover, the presence of ETEC in river water samples was associated with heterotrophic plate counts. Water with EPEC differed significantly in pH from Puzih River samples. These results suggest that seasonal characteristics may affect the presence of DEC in different aquatic environments, and water quality indicators may be indicative of the presence of DEC. Copyright © 2015 Elsevier Inc. All rights reserved.

Dissolved gas concentrations of the geothermal fluids in Taiwan

NASA Astrophysics Data System (ADS)

Chen, Ai-Ti; Yang, Tsanyao Frank

2010-05-01

Taiwan, a geologically active island, is located on the boundary of the Philippine Sea Plate and the Eurasian Plate. High heat flow and geothermal gradient generated by the complex collision and orogeny, warm up the meteoric water and/or the ground water. The heated water becomes geothermal fluids. In previous studies, researchers tried to categorize hot springs based on the appearance, chemical compositions and lithological areas. Because of the chemical inertness, the concentrations and isotopic composition of dissolved noble gases are good indicators of the mantle degassing, geothermal conditions, and so on. In this study, 55 hot springs were collected from different tectonic units. It is the first time to systematically study the hot springs in Taiwan in terms of dissolved gases. Hot spring water is sampled and stored in pre-evacuated glass bottles for analyzing gas compositions. The abundances of noble gases were determined by a quadrupole mass spectrometer based on the isotope dilution technique. Samples with glass vials are introduced to RAD 7 and GC for dissolved Rn and major dissolved gases analyses. Furthermore, helium isotopic ratios and helium-neon ratios are measured on a conventional noble gas mass spectrometer. For hydrochemistry analysis, water samples are analyzed by IC, ICP-MS and titration. We can classify the hot springs samples into three major groups from main anion concentration data; and then, subdivide them into nine minor groups by cation concentration data. Moreover, according to major dissolved gases compositions, three major gas components: CH4, N2 and CO2, are identified. Dissolved noble gases provided more detailed clues about hot springs sources in Taiwan, such as the degree of mixing between meteoric water and deep-source water, which will be further discussed in this study.

Spring response to precipitation events using δ(18)O and δ(2)H in the Tanour catchment, NW Jordan.

PubMed

Hamdan, Ibraheem; Wiegand, Bettina; Toll, Mathias; Sauter, Martin

2016-12-01

The Tanour spring is one of the several karst springs located in the northern part of Jordan. Water samples from the Tanour spring and precipitation were collected in the area of Ajloun in NW Jordan for the analysis of stable oxygen and hydrogen isotopes to evaluate the spring response to precipitation events. Rainwater and snow samples were collected from different elevations during winters of 2013-2014 and 2014-2015. In addition, spring samples were collected between December 2014 and March 2015. δ(18)O values in rainwater vary from -3.26 to -17.34 ‰ (average: -7.84 ± 3.23 ‰), while δ(2)H values range between -4.4 and -110.4 ‰ (average: -35.7 ± 25.0 ‰). Deuterium excess ranges from 17.8 to 34.1 ‰ (average: 27.1 ± 4.0 ‰). The Local Meteoric Water Line for the study area was calculated to be δ(2)H = 7.66*δ(18)O + 24.43 (R(2) = 0.98). Pre-event spring discharge showed variation in δ(18)O (range -6.29 to -7.17 ‰; average -6.58 ± 0.19 ‰) and δ(2)H values (range -28.8 to -32.7 ‰; average: -30.5 ± 1.0 ‰). In contrast, δ(18)O and δ(2)H rapidly changed to more negative values during rainfall and snowmelt events and persisted for several days before returning to background values. Spring water temperature, spring discharge, and turbidity followed the trend in isotopic composition during and after the precipitation events. The rapid change in the isotopic composition, spring discharge, water temperature, and turbidity in response to recharge events is related to fast water travel times and low storage capacity in the conduit system of the karst aquifer. Based on the changes in the isotopic composition of spring water after the precipitation events, the water travel time in the aquifer is in the order of 5-11 days.

Seasonal radon measurements in Darbandikhan Lake water resources at Kurdistan region-northeastern of Iraq

NASA Astrophysics Data System (ADS)

Jafir, Adeeb Omer; Ahmad, Ali Hassan; Saridan, Wan Muhamad

2016-03-01

A total of 164 water samples were collected from Darbandikhan Lake with their different resources (spring, stream, and lake) during the four seasons, and the measurements were carried out using the electronic RAD 7 detector. For spring water the average radon concentration for spring, summer, autumn and summer were found to be 8.21 Bq/1, 8.94 Bq/1, 7.422 Bq/1, and 8.06 Bq/1, respectively, while for lake and streams the average values were found to be 0.43 Bq/1, 0.877 Bq/1, 0.727 Bq/1, 0.575 Bq/1 respectively. The radon concentration level was higher in summer and lower in spring, and only two samples from spring water have radon concentrations more than 11.1 Bq/1 recommended by the EPA. Total annual effective dose due to ingestion and inhalation has been estimated, the mean annual effective dose during the whole year for spring water was 0.022 mSv/y while for lake with streams was 0.00157 mSv/y. The determined mean annual effective dose in water was lower than the 0.1 mSv/y recommended by WHO. Some physicochemical parameters were measured and no correlation was found between them and radon concentration except for the conductivity of the spring drinking water which reveals a strong correlation for the four seasons.

Quantitative analysis of ions in spring water in three different areas of Hyogo Prefecture in Japan by far ultraviolet spectroscopy.

PubMed

Mitsuoka, Motoki; Shinzawa, Hideyuki; Morisawa, Yusuke; Kariyama, Naomi; Higashi, Noboru; Tsuboi, Motohiro; Ozaki, Yukihiro

2011-01-01

Far-ultraviolet (FUV) spectra in the 190-300 nm region were measured for spring water in Awaji-Akashi area, Tamba area and Rokko-Arima area in Hyogo Prefecture, Japan, these areas have quite different geology features. The spectra of the spring water in the Awaji-Akashi area can be divided into two groups: the spring water samples containing large amounts of NO(3)(-) and/or Cl(-), and those containing only small amounts of NO(3)(-) and Cl(-). The former shows a saturated band below 190 nm due to NO(3)(-) and/or Cl(-). These two types of spectra correspond to different lithological areas: sedimentary lithology near the sea shore containing many ions in the seawater and gravitic lithology far from the sea side, in the Awaji-Akashi area. The spring water from the Tamba area, which is far from the sea, contains relatively small amounts of NO(3)(-) and Cl(-); it does not yield a strong band in the region observed. The FUV spectra of three of four kinds of spring water samples in the Arima Hotspring show characteristic spectral patterns. They are quite different from the spectra of the spring water samples of the Rokko area. Calibration models were developed for NO(3)(-), Cl(-), SO(4)(2-), Na(+), and Mg(2+) in the nine kinds of spring water collected in the Awaji-Akashi area, Tamba, and Rokko-Arima area by using univariate analysis of the first derivative spectra and the actual values obtained by ion chromatography. NO(3)(-) yields the best results: correlation coefficient of 0.999 and standard deviation of 0.09 ppm with the wavelength of 212 nm. Cl(-) also gives good results: correlation coefficient of 0.993 and standard deviation of 0.5 ppm with the wavelength of 192 nm.

Measurements of natural radioactivity concentration in drinking water samples of Shiraz city and springs of the Fars province, Iran, and dose estimation.

PubMed

Mehdizadeh, Simin; Faghihi, Reza; Sina, Sedigheh; Derakhshan, Shahrzad

2013-11-01

The Fars province is located in the south-west region of Iran where different nuclear sites has been established, such as Bushehr Nuclear Power Plant. In this research, 92 water samples from the water supplies of Shiraz city and springs of the Fars province were investigated with regard to the concentrations of natural radioactive elements, total uranium, (226)Ra, gross alpha and gross beta. (226)Ra concentration was determined by the (222)Rn emanation method. To measure the total uranium concentration, a laser fluorimetry analyzer (UA-3) was used. The mean concentration of (226)Ra in Shiraz's water resources was 23.9 mBq l(-1), while 93 % of spring waters have a concentration <2 mBq l(-1). The results of uranium concentration measurements show the mean concentrations of 7.6 and 6 μg l(-1) in the water of Shiraz and springs of Fars, respectively. The gross alpha and beta concentrations measured by the evaporation method were lower than the limit of detection of the measuring instruments used in this survey. The mean annual effective doses of infants, children and adults from (238)U and (226)Ra content of Shiraz's water and spring waters were estimated. According to the results of this study, the activity concentration in water samples were below the maximum permissible concentrations determined by the World Health Organization and the US Environmental Protection Agency. Finally, the correlation between (226)Ra and total U activity concentrations and geochemical properties of water samples, i.e. pH, total dissolve solids and SO4(-2), were estimated.

Mercury Release from the Rathburn Mine, Petray Mine, and Bear Valley Saline Springs, Colusa County, California 2004-2006

USGS Publications Warehouse

Slowey, Aaron J.; Rytuba, James J.

2008-01-01

This report summarizes data obtained from field sampling of mine tailings and waste rock at the Rathburn and Petray Mines that was initiated in July 17, 2001 and water and sediment in regional springs and tributaries that drain from the mine area into Bear Creek on December 14, 2004 and February 16 and May 27, 2005. Although it was initially assumed that the mines were the cause of elevated levels of monomethyl Hg measured by the Central Regional Water Quality Control Board in tributaries near their confluence with Bear Creek (Foe and others, unpublished results), it became apparent during this study that ground water springs were also potential sources of Hg. In addition to sampling of springs in May 2005, saline ground water seepage along an unnamed fault on the west side of Bear Valley was sampled on December 13-14, 2006. We did not sample water or sediment in Bear Creek itself during this study. Our results permit a preliminary assessment of mining and natural sources of Hg and associated chemical constituents that could elevate levels of monomethyl Hg in Bear Creek.

Water-quality characteristics and contaminants in the rural karst-dominated Spring Mill Lake watershed, southern Indiana

USGS Publications Warehouse

Hasenmueller, N.R.; Buehler, M.A.; Krothe, N.C.; Comer, J.B.; Branam, T.D.; Ennis, M.V.; Smith, R.T.; Zamani, D.D.; Hahn, L.; Rybarczyk, J.P.

2006-01-01

The Spring Mill Lake watershed is located in the Mitchell Plateau, a karst area that developed on Mississippian carbonates in southern Indiana. Spring Mill Lake is a reservoir built in the late 1930s and is located in Spring Mill State Park. Within the park, groundwater from subsurface conduits issues as natural springs and then flows in surface streams to the lake. From 1998 to 2002, surface and subsurface hydrology and water quality were investigated to determine the types and sources of potential contaminants entering the lake. Water samples collected during base flow and a February 2000 storm event were analyzed for selected cations, anions, trace elements, selected U.S. Environmental Protection Agency (EPA) primary and secondary drinkingwater contaminants, nitrogen isotopes, suspended solids, Escherichia coli, and pesticides. All of the water samples met the EPA drinking-water standards for inorganic constituents, except those collected at five sites in August 1999 during a drought. Nitrate nitrogen (NO3-N) concentrations were highest during base-flow conditions and displayed a dilutional trend during peak-flow periods. The NO3-N concentrations in water samples collected during the 2001 spring fertilizer applications tended to increase from early to late spring. All of the ??15N values were low, which is indicative of either an inorganic source or soil organic matter. Storm discharge contained increased concentrations of total suspended solids; thus, storms are responsible for most of the sediment accumulation in the lake. E. coli levels in 24% of the samples analyzed contained a most probable number (MPN) greater than 235/100 mL, which is the maximum acceptable level set for recreational waters in Indiana. E. coli does appear to be a potential health risk, particularly at Rubble spring. The sources of E. coli found at this spring may include barnyard runoff from a horse barn or wastes from a wastewater treatment facility. The pesticides atrazine, metolachlor, acetochlor, and simazine were detected during the spring of 2001. Atrazine, metolachlor, acetochlor, and simazine are used to suppress weeds during corn and soybean production. Additional sources of atrazine and simazine may result from application to right-of-ways, orchards, and managed forest areas. ?? 2006 Geological Society of America.

Environmental Survey of Drinking Water Sources in Kampala, Uganda, during a Typhoid Fever Outbreak.

PubMed

Murphy, J L; Kahler, A M; Nansubuga, I; Nanyunja, E M; Kaplan, B; Jothikumar, N; Routh, J; Gómez, G A; Mintz, E D; Hill, V R

2017-12-01

In 2015, a typhoid fever outbreak began in downtown Kampala, Uganda, and spread into adjacent districts. In response, an environmental survey of drinking water source types was conducted in areas of the city with high case numbers. A total of 122 samples was collected from 12 source types and tested for Escherichia coli , free chlorine, and conductivity. An additional 37 grab samples from seven source types and 16 paired large volume (20 liter) samples from wells and springs were also collected and tested for the presence of Salmonella enterica serovar Typhi. Escherichia coli was detected in 60% of kaveras (drinking water sold in plastic bags) and 80% of refilled water bottles; free chlorine was not detected in either source type. Most jerry cans (68%) contained E. coli and had free chlorine residuals below the WHO-recommended level of 0.5 mg/liter during outbreaks. Elevated conductivity readings for kaveras, refilled water bottles, and jerry cans (compared to treated surface water supplied by the water utility) suggested that they likely contained untreated groundwater. All unprotected springs and wells and more than 60% of protected springs contained E. coli Water samples collected from the water utility were found to have acceptable free chlorine levels and no detectable E. coli While S Typhi was not detected in water samples, Salmonella spp. were detected in samples from two unprotected springs, one protected spring, and one refilled water bottle. These data provided clear evidence that unregulated vended water and groundwater represented a risk for typhoid transmission. IMPORTANCE Despite the high incidence of typhoid fever globally, relatively few outbreak investigations incorporate drinking water testing. During waterborne disease outbreaks, measurement of physical-chemical parameters, such as free chlorine residual and electrical conductivity, and of microbiological parameters, such as the presence of E. coli or the implicated etiologic agent, in drinking water samples can identify contaminated sources. This investigation indicated that unregulated vended water and groundwater sources were contaminated and were therefore a risk to consumers during the 2015 typhoid fever outbreak in Kampala. Identification of contaminated drinking water sources and sources that do not contain adequate disinfectant levels can lead to rapid targeted interventions. Copyright © 2017 American Society for Microbiology.

Water quality of potential reference lakes in the Arkansas Valley and Ouachita Mountain ecoregions, Arkansas

USGS Publications Warehouse

Justus, B.G.; Meredith, Bradley J.

2014-01-01

This report describes a study to identify reference lakes in two lake classifications common to parts of two level III ecoregions in western Arkansas—the Arkansas Valley and Ouachita Mountains. Fifty-two lakes were considered. A screening process that relied on land-use data was followed by reconnaissance water-quality sampling, and two lakes from each ecoregion were selected for intensive water-quality sampling. Our data suggest that Spring Lake is a suitable reference lake for the Arkansas Valley and that Hot Springs Lake is a suitable reference lake for the Ouachita Mountains. Concentrations for five nutrient constituents—orthophosphorus, total phosphorus, total kjeldahl nitrogen, total nitrogen, and total organic carbon—were lower at Spring Lake on all nine sampling occasions and transparency measurements at Spring Lake were significantly deeper than measurements at Cove Lake. For the Ouachita Mountains ecoregion, water quality at Hot Springs Lake slightly exceeded that of Lake Winona. The most apparent water-quality differences for the two lakes were related to transparency and total organic carbon concentrations, which were deeper and lower at Hot Springs Lake, respectively. Our results indicate that when nutrient concentrations are low, transparency may be more valuable for differentiating between lake water quality than chemical constituents that have been useful for distinguishing between water-quality conditions in mesotrophic and eutrophic settings. For example, in this oligotrophic setting, concentrations for chlorophyll a can be less than 5 μg/L and diurnal variability that is typically associated with dissolved oxygen in more productive settings was not evident.

Hydrologic data and description of a hydrologic monitoring plan for the Borax Lake area, Oregon

USGS Publications Warehouse

Schneider, Tiffany Rae; McFarland, William D.

1995-01-01

Information from field visits was used to develop a monitoring plan. The plan would include monitoring Borax Lake by measuring discharge, stage, evaporation, temperature, and specific conductance; water-quality sampling and analysis; and monitoring shallow ground-water levels near Borax Lake using shallow piezometers. Minimally, one hot spring in North Borax Lake Spring Group 1 would be monitored for temperature and specific conductance and sampled for water-quality analysis. In addition, two flowing wells would be monitored for water levels, temperature, specific conductance, and discharge and sampled for water-quality analysis. The construction characteristics of these wells must be verified before long-term data collection begins. In the future, it may be helpful to monitor shallow and (or) deep observation wells drilled into the thermal aquifer to understand the possible effects of geothermal development on Borax Lake and nearby springs.

Selected ground-water-quality data in Pennsylvania - 1979-2006

USGS Publications Warehouse

Low, Dennis J.; Chichester, Douglas C.; Zarr, Linda F.

2009-01-01

This study, by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP), provides a compilation of ground-water-quality data for a 28-year period (January 1, 1979, through December 31, 2006) based on water samples from wells and springs. The data are from 14 source agencies or programs—Borough of Carroll Valley, Chester County Health Department, Montgomery County Health Department, Pennsylvania Department of Agriculture, Pennsylvania Department of Environmental Protection 2002 Pennsylvania Water-Quality Assessment, Pennsylvania Department of Environmental Protection Agency Act 537 Sewage Facilities Program, Pennsylvania Department of Environmental Protection-Ambient and Fixed Station Network, Pennsylvania Department of Environmental Protection–North-Central Region, Pennsylvania Department of Environmental Protection–South-Central Region, Pennsylvania Drinking Water Information System, Pennsylvania Topographic and Geologic Survey, Susquehanna River Basin Commission, U.S. Environmental Protection Agency, and the U.S. Geological Survey. The ground-water-quality data from the different source agencies or programs varied in type and number of analyses; however, the analyses are represented by 11 major analyte groups: antibiotics, major ions, microorganisms (bacteria, viruses, and other microorganisms), minor ions (including trace elements), nutrients (predominantly nitrate and nitrite as nitrogen), pesticides, pharmaceuticals, radiochemicals (predominantly radon or radium), volatiles (volatile organic compounds), wastewater compounds, and water characteristics (field measurements, predominantly field pH, field specific conductance, and hardness). For the USGS and the PADEP–North-Central Region, the pesticide analyte group was broken down into fungicides, herbicides, and insecticides. Summary maps show the areal distribution of wells and springs with ground-water-quality data statewide by source agency or program. Summary data tables by source agency or program provide information on the number of wells and springs and samples collected for each of the 35 watersheds and analyte groups.The number of wells and springs sampled for ground-water-quality data varies considerably across Pennsylvania. Of the 24,772 wells and springs sampled, the greatest concentration of wells and springs is in the southeast (Berks, Bucks, Chester, Delaware, Lancaster, Montgomery, and Philadelphia Counties) and in the northwest (Erie County). The number of wells and springs sampled is relatively sparse in north-central (Cameron, Elk, Forest, McKean, Potter, and Warren Counties) Pennsylvania. Little to no data are available for approximately one-fourth of the state. Nutrients and water characteristics were the most frequently sampled major analyte groups—43,025 and 30,583 samples, respectively. Minor ions and major ions were the next most frequently sampled major analyte groups–26,972 and 13,115 samples, respectively. For the remaining 10 major analyte groups, the number of samples collected ranged from a low of 24 samples (antibiotic compounds) to a high of approximately 4,674 samples (microorganisms).The number of samples that exceeded a maximum contaminant level (MCL) or secondary maximum contaminant level (SMCL) by major analyte group also varied. Of the 4,674 samples in the microorganism analyte group, 50.2 percent had water that exceeded an MCL. Of the 4,528 samples collected and analyzed for volatile organic compounds, 23.5 percent exceeded an MCL. Other major analyte groups that frequently exceeded MCLs or SMCLs included major ions (18,343 samples and a 27.7 percent exceedence), minor ions (26,972 samples, 44.7 percent exceedence), pesticides (4,868 samples, 0.7 percent exceedence), water characteristics (30,583 samples, 19.3 percent exceedence), and radiochemicals (1,866 samples, 9.6 percent exceedence). Samples collected and analyzed for antibiotics (24 samples), fungicides (1,273 samples), herbicides (1,470 samples), insecticides (1,424 samples), nutrients (43,025 samples), pharmaceuticals (28 samples), and wastewater compounds (328 samples) had the lowest exceedences of 0.0, 2.4, 1.2, <1.0, 8.3, 0.0, and <1.0 percent, respectively.

Origin and characteristics of discharge at San Marcos Springs based on hydrologic and geochemical data (2008-10), Bexar, Comal, and Hays Counties, Texas

USGS Publications Warehouse

Musgrove, MaryLynn; Crow, Cassi L.

2012-01-01

The Edwards aquifer in south-central Texas is a productive and important water resource. Several large springs issuing from the aquifer are major discharge points, popular locations for recreational activities, and habitat for threatened and endangered species. Discharges from Comal and San Marcos Springs, the first and second largest spring complexes in Texas, are used as thresholds in groundwater management strategies for the Edwards aquifer. Comal Springs is generally understood to be supplied by predominantly regional groundwater flow paths; the hydrologic connection of San Marcos Springs with the regional flow system, however, is less understood. During November 2008–December 2010, a hydrologic and geochemical investigation of San Marcos Springs was conducted by the U.S. Geological Survey (USGS) in cooperation with the San Antonio Water System. The primary objective of this study was to define and characterize sources of discharge from San Marcos Springs. During this study, hydrologic conditions transitioned from exceptional drought (the dry period, November 1, 2008 to September 8, 2009) to wetter than normal (the wet period, September 9, 2009 to December 31, 2010), which provided the opportunity to investigate the hydrogeology of San Marcos Springs under a wide range of hydrologic conditions. Water samples were collected from streams, groundwater wells, and springs at and in the vicinity of San Marcos Springs, including periodic (routine) sampling (every 3–7 weeks) and sampling in response to storms. Samples were analyzed for major ions, trace elements, nutrients, and selected stable and radiogenic isotopes (deuterium, oxygen, carbon, strontium). Additionally, selected physicochemical properties were measured continuously at several sites, and hydrologic data were compiled from other USGS efforts (stream and spring discharge). Potential aquifer recharge was evaluated from local streams, and daily recharge or gain/loss estimates were computed for several local streams. Local rainfall and recharge events were compared with physicochemical properties and geochemical variability at San Marcos Springs, with little evidence for dilution by local recharge.

Residence times and age distributions of spring waters at the Semmering catchment area, Eastern Austria, as inferred from tritium, CFCs and stable isotopes.

PubMed

Han, Liangfeng; Hacker, Peter; Gröning, Manfred

2007-03-01

The groundwater system in the mountainous area of Semmering, Austria, was studied by environmental tracers in several karst springs. The tracers used included stable isotopes ((18)O, (2)H), tritium ((3)H) and chlorofluorocarbons (CFCs). The tracers provided valuable information in regard to (1) the mean altitude of the spring catchment areas; (2) the residence time and age distribution of the spring waters; and (3) the interconnection of the springs to a sinkhole. The combination of the stable isotopic data and the topography/geology provided the estimates of the mean altitudes of the catchment areas. Based on the stable isotopic data the recharge temperature of the spring waters was estimated. The smoothing of precipitation's isotopic signal in spring discharge provided information on the minimum transit time of the spring waters. Due to short observation time, (3)H data alone cannot be used for describing the mean residence time of the karst waters. CFCs, though useful in recognizing the co-existence of young (post-1993) water with old (CFC-free) water, could not be used to resolve age distribution models. It is shown in this article, however, that the combined use of tritium and CFCs can provide a better assessment of models to account for different groundwater age distributions. In Appendix A, a simplified method for collecting groundwater samples for the analysis of CFCs is described. The method provides a real facilitation for fieldwork. Test data are given for this sampling method in regard to potential contamination by atmospheric CFCs.

Estimating background and threshold nitrate concentrations using probability graphs

USGS Publications Warehouse

Panno, S.V.; Kelly, W.R.; Martinsek, A.T.; Hackley, Keith C.

2006-01-01

Because of the ubiquitous nature of anthropogenic nitrate (NO 3-) in many parts of the world, determining background concentrations of NO3- in shallow ground water from natural sources is probably impossible in most environments. Present-day background must now include diffuse sources of NO3- such as disruption of soils and oxidation of organic matter, and atmospheric inputs from products of combustion and evaporation of ammonia from fertilizer and livestock waste. Anomalies can be defined as NO3- derived from nitrogen (N) inputs to the environment from anthropogenic activities, including synthetic fertilizers, livestock waste, and septic effluent. Cumulative probability graphs were used to identify threshold concentrations separating background and anomalous NO3-N concentrations and to assist in the determination of sources of N contamination for 232 spring water samples and 200 well water samples from karst aquifers. Thresholds were 0.4, 2.5, and 6.7 mg/L for spring water samples, and 0.1, 2.1, and 17 mg/L for well water samples. The 0.4 and 0.1 mg/L values are assumed to represent thresholds for present-day precipitation. Thresholds at 2.5 and 2.1 mg/L are interpreted to represent present-day background concentrations of NO3-N. The population of spring water samples with concentrations between 2.5 and 6.7 mg/L represents an amalgam of all sources of NO3- in the ground water basins that feed each spring; concentrations >6.7 mg/L were typically samples collected soon after springtime application of synthetic fertilizer. The 17 mg/L threshold (adjusted to 15 mg/L) for well water samples is interpreted as the level above which livestock wastes dominate the N sources. Copyright ?? 2006 The Author(s).

Stable Water Isotope Climate Archives in Springs from the Olympic Mountains, Washington

EPA Science Inventory

The ¹⁸O and ²H (HDO) compositions are summarized for sampled springs (n = 81) within the Elwha watershed (≈ 692 km²) on the northern Olympic Peninsula. Samples, collected during 2001–2009, of springs (n = 158), precipitation (n = 520), streams (n...

Age and source of water in springs associated with the Jacksonville Thrust Fault Complex, Calhoun County, Alabama

USGS Publications Warehouse

Robinson, James L.

2004-01-01

Water from wells and springs accounts for more than 90 percent of the public water supply in Calhoun County, Alabama. Springs associated with the Jacksonville Thrust Fault Complex are used for public water supply for the cities of Anniston and Jacksonville. The largest ground-water supply is Coldwater Spring, the primary source of water for Anniston, Alabama. The average discharge of Coldwater Spring is about 32 million gallons per day, and the variability of discharge is about 75 percent. Water-quality samples were collected from 6 springs and 15 wells in Calhoun County from November 2001 to January 2003. The pH of the ground water typically was greater than 6.0, and specific conductance was less than 300 microsiemens per centimeter. The water chemistry was dominated by calcium, carbonate, and bicarbonate ions. The hydrogen and oxygen isotopic composition of the water samples indicates the occurrence of a low-temperature, water-rock weathering reaction known as silicate hydrolysis. The residence time of the ground water, or ground-water age, was estimated by using analysis of chlorofluorocarbon, sulfur hexafluoride, and regression modeling. Estimated ground-water ages ranged from less than 10 to approximately 40 years, with a median age of about 18 years. The Spearman rho test was used to identify statistically significant covariance among selected physical properties and constituents in the ground water. The alkalinity, specific conductance, and dissolved solids increased as age increased; these correlations reflect common changes in ground-water quality that occur with increasing residence time and support the accuracy of the age estimates. The concentration of sodium and chloride increased as age increased; the correlation of these constituents is interpreted to indicate natural sources for chloride and sodium. The concentration of silica increased as the concentration of potassium increased; this correlation, in addition to the isotopic data, is evidence that silicate hydrolysis of clay minerals occurred. The geochemical modeling program NETPATH was used to investigate possible mixing scenarios that could yield the chemical composition of water collected from springs associated with the Jacksonville Thrust Fault Complex. The results of NETPATH modeling suggest that the primary source of water in Coldwater Spring is a deep aquifer, and only small amounts of rainwater from nearby sources are discharged from the spring. Starting with Piedmont Sports Spring and moving southwest along a conceptual ground-water flow path that parallels the Jacksonville Thrust Fault Complex, NETPATH simulated the observed water quality of each spring, in succession, by mixing rainwater and water from the spring just to the northeast of the spring being modeled. The percentage of rainwater and ground water needed to simulate the quality of water flowing from the springs ranged from 1 to 25 percent rainwater and 75 to 99 percent ground water.

Potential for travertine formation: Fossil Creek, Arizona

Treesearch

John Malusa; Steven T. Overby; Roderic A. Parnell

2003-01-01

Chemical analyses of water emanating from Fossil Springs in Central Arizona were conducted to predict changes in travertine deposition related to changes in stream discharge caused by diversion for hydroelectric power generation. During spring of 1996, water was sampled at 15 locations during normal seepage flow in a 6.7 km reach below Fossil Springs and at full...

Hydrologic data for the Big Spring basin, Clayton County, Iowa, water year 1991

USGS Publications Warehouse

Kalkhoff, S.J.; Kuzniar, R.L.

1994-01-01

Stream discharge, specific conductance, pH, and water temperature were monitored continuously, and monthly water-quality samples were collected at a site on Roberts Creek and at Big Spring. Nitrite plus nitrate as nitrogen concentrations in 27 samples from Roberts Creek at the point where it leaves the study area ranged from 1.8 to 22 mg/L. Herbicide concentrations in 26 samples from the Roberts Creek site ranged from less than 0.10 μg/L (micrograms per liter) to 43 μg/L. Alachlor was detected in 42 percent of the samples; atrazine in 92 percent; and cyanazine and metolachlor in 35 percent of the samples. The total suspended-sediment load discharged in Roberts Creek was about 160,000 tons. At Big Spring, the ground-water discharge point, the daily mean specific conductance ranged from 414 to 788 microsiemens per centimeter at 25 degrees Celsius, the daily median pH ranged from 6.7 to 7.1, and the daily mean water temperature ranged from 8.5 to 13.0 degrees Celsius. Concentrations of nitrite plus nitrate as nitrogen in 23 samples ranged from 4.2 to 17 mg/L. The total measured suspended-sediment discharged from Big Spring was about 17,000 tons. Alachlor was detected in 26 percent; atrazine in 100 percent; cyanazine in 26 percent, and metolachlor in 9 percent of the samples. The maximum atrazine concentration was 16 μg/L.

Water-quality data for Navajo National Monument, northeastern Arizona--2001-02

USGS Publications Warehouse

Thomas, Blakemore E.

2003-01-01

Water-quality data are provided for six sites in Navajo National Monument in northeastern Arizona. These data describe the current water quality and provide baseline water-quality information for monitoring future trends. Water samples were collected from six sites near three ancient Indian ruins during September 2001 to August 2002. Two springs and one well near Betatakin Ruin, one spring is near Keet Seel Ruin, and one spring and one stream are near Inspection House Ruin. Water from all the sites is from the N aquifer, a regional sandstone aquifer that is the source of drinking water for most members of the Navajo Nation and Hopi Tribe in northeastern Arizona. Concentrations of dissolved solids, major ions, trace elements, and uranium were low at the six sites. Dissolved-solids concentration ranged from 94 to 221 milligrams per liter. Concentrations of dissolved nitrate (as nitrogen) were generally low (less than 0.05 to 0.92 milligrams per liter) and were within the range of concentrations at other N-aquifer sites within 20 miles of the study area. Water samples from Inscription House Spring, Navajo Creek Tributary (near Inscription House Ruin), and Keet Seel Ruin Spring contained indicators of human or animal wastes--fecal coliform and Escherichia coli bacteria.

Radioactivity and geochemistry of selected mineral-spring waters in the Western United States; basic data and multivariate statistical analysis

USGS Publications Warehouse

Felmlee, J.K.; Cadigan, R.A.

1982-01-01

Multivariate statistical analyses were performed on data from 156 mineral-spring sites in nine Western States to analyze relationships among the various parameters measured in the spring waters. Correlation analysis and R-mode factor analysis indicate that three major factors affect water composition in the spring systems studied: (1) duration of water circulation, (2) depth of water circulation, and (3) partial pressure of carbon dioxide. An examination of factor scores indicates that several types of hydrogeologic systems were sampled. Most of the samples are (1) older water from deeper circulating systems having relatively high salinity, high temperature, and low Eh or (2) younger water from shallower circulating systems having relatively low salinity, low temperature, and high Eh. The rest of the samples are from more complex systems. Any of the systems can have a relatively high or low content of dissolved carbonate species, resulting in a low or high pH, respectively. Uranium concentrations are commonly higher in waters of relatively low temperature and high Eh, and radium concentrations are commonly higher in waters having a relatively high carbonate content (low pH) and, secondarily, relatively high salinity. Water samples were collected and (or) measurements were taken at 156 of the 171 mineral-spring sites visited. Various samples were analyzed for radium, uranium, radon, helium, and radium-228 as well as major ions and numerous trace elements. On-site measurements for physical properties including temperature, specific conductance, pH, Eh, and dissolved oxygen were made. All constituents and properties show a wide range of values. Radium concentrations range from less than 0.01 to 300 picocuries per liter; they average 1.48 picocuries per liter and have an anomaly threshold value of 171 picocuries per liter for the samples studied. Uranium concentrations range from less than 0.01 to 120 micrograms per liter and average 0.26 micrograms per liter; they have an anomaly threshold value of 48.1 micrograms per liter. Radon content ranges from less than 10 to 110,000 picocuries per liter, averages 549 picocuries per liter and has an anomaly threshold of 20,400 picocuries per liter. Helium content ranges from -1,300 to +13,000 parts per billion relative to atmospheric helium; it averages +725 parts per billion and has an anomaly threshold of 10,000 parts per billion. Radium-228 concentrations range from less than 2.0 to 33 picocuries per liter; no anomaly threshold was determined owing to the small number of samples. All of the anomaly thresholds may be somewhat high because the sampling was biased toward springs likely to be radioactive. The statistical variance in radium and uranium concentrations unaccounted for by the identified factors testifies to the complexity of some hydrogeologic systems. Unidentified factors related to geologic setting and the presence of uranium-rich rocks in the systems also affect the observed concentrations of the radioactive elements in the water. The association of anomalous radioactivity in several springs with nearby known uranium occurrences indicates that other springs having anomalous radioactivity may also be associated with uranium occurrences as yet undiscovered.

Physical characteristics and chemical quality of selected springs in parts of Juab, Millard, Tooele, and Utah counties, Utah

USGS Publications Warehouse

Wilberg, D.E.; Stolp, B.J.

1985-01-01

Hydrologic, geologic, and partial water quality data were collected at 90 selected springs in west-central Utah, and chemical analyses performed on water samples from 62 of the springs. Descriptions of the physiographic and geologic conditions, climate, and vegetation patterns for the study area are included. Allowable limits of certain chemical constituents in water for human and livestock consumption are included with the water quality data. Three classifications of springs were established based on physical characteristics of the springs, and chemical composition of the springflow: (1) mountain springs; (2) non-thermal valley springs, and (3) thermal valley springs. Mountain springs are in and near recharge areas, have seasonal variations of discharge and temperature, typically discharge from extrusive and metamorphic geohydrologic units, and generally discharge freshwater. Non-thermal valley springs are peripheral to recharge areas, have seasonal variations of discharge and temperature, typically discharge from a variety of geohydrologic units, and have variable water composition. Thermal valley springs are near topographic low areas of valleys , and have little seasonal variation of discharge or temperature. They typically discharge from unconsolidated deposits (but the discharge probably has flowed through buried carbonate geohydrologic units). They also have a considerable range of water composition that reflects the relative complexity of the groundwater system. (Author 's abstract)

Multi-tracer approach (18O, 3H/3He, CFC, SF6, 35S) to find the best emergency drinking water supply, Vorarlberg, Austria

NASA Astrophysics Data System (ADS)

Kralik, Martin; Vergnaud, Virginie; Uriostegui, Stephanie; Esser, Bradley

2016-04-01

To provide an emergency drinking water supply in case of catastrophic events (regional chemical accidents, floods, earth quakes etc.), wells and springs should be known which are fed by a large reservoir. Such reservoirs provide a good filtering capacity and long Mean Residence Times (MRTs) of the raw water. Their existence allows to use these resources for longer periods excluding the danger of contamination. This provides the water authorities the necessary time to set measures to protect the general water supply. After preselection of 16 wells and springs all over the territory of the province of Vorarlberg at the western end of Austria by the local water authority, these wells and springs were measured (water temperature, electric conductivity, pH and dissolved oxygen content) and sampled monthly for δ 18O/2H measurements over the winter half-year 2013/14. At the same time the tritium concentrations of the October and March samples were measured as well. Based on the variation of the monthly on-site measurements and the δ 18O/2H results 12 wells and springs were selected for further investigations. On these sites samples for 3H/3He, CFC-11/12/113, SF6 and sulphur-35 measurements were collected in August 2014. As expected from a humid alpine area, non of the selected springs or wells showed really long MRTs. Five out of 16 investigated sites are regarded as well suited to be used as emergency water source with a range of MRTs of 9 - 30 years. Five springs and wells are regarded of limited suitability due to the shorter MRTs of 5 - 9 years. In two springs the 3H/3He method could not be applied due to He-degassing in a karst-system and during sampling. CFC and SF6 excess at some sites with anthropogenic and geogenic sources hampered the utilisation of these gases as dating tool, but they were useful as source tracers. Sulphur-35 was detected in two wells only, indicating contribution of very young water (< 1 year). In both cases MRTs of 13 - 17 years, calculated from the other applied tracers, otherwise would have supported the suitability of these wells as emergency drinking water supply. In general, the combination of tracers measured here over the period of one year are well suited to select and confirm springs or wells to be used as emergency drinking water supply, even situated in areas with fast groundwater cycles.

Survey of bottled drinking water sold in Canada. Part 2. Selected volatile organic compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Page, B.D.; Conacher, H.B.S.; Salminen, J.

Selected volatile organic compound (VOC) contaminants were determined in 182 samples of retail bottled waters purchased in Canada. Samples included spring water (86) packaged in containers of polyethylene or in smaller containers of transparent plastic or glass, mineral water (61) packaged only in transparent plastic or glass, and miscellaneous bottled waters (35). Analyses were performed by 3 laboratories, each using headspace sampling and capillary gas chromatography with either mass spectrometric (1 laboratory) or flame ionization detection with mass spectrometric confirmation, if required (2 laboratories). Benzene, the contaminant of primary interest, was detected in only 1 of the 182 samples atmore » 2 {mu}g/kg. Other VOC contaminants detected (number of positive samples, average, and range of positives in {mu}g/kg) included toluene (20, 6.92, 0.5-63), cyclohexane (23, 39.2, 3-108), chloroform (12, 25.8, 3.7-70), and dichloromethane (4, 59, 22-97). Cyclohexane was found in the plastic and as a migrant from the plastic in 20 samples of spring water, but it was found in only 1 of 61 mineral water samples analyzed at only 3 {mu}g/kg/. Chloroform was found almost exclusively in samples that could have been obtained from public water supplies. It was not found in mineral water samples, but it was found in 1 spring water sample at 3.7 {mu}g/kg. The source of the toluene contamination was not known. Other VOCs detected include ethanol and limonene, associated with added flavoring; pentane, as a migrant from a foamed polystyrene cap liner; and 1,1,2,2-tetra-chloroethylene in a sample of demineralized water. 10 refs., 6 tabs.« less

Hydrologic assessment of the Upper Dorr Run Watershed, Hocking County, Ohio, 1998

USGS Publications Warehouse

Haefner, R.J.

1999-01-01

The Upper Dorr Run Watershed in Hocking County, Ohio, has been mined several times for coal and clay since 1913 and is a significant source of acid mine drainage to the Hocking River. To assess the surface-water hydrology of the site, a topographic map showing the location of springs and other hydrologic features of interest was prepared using aerial photography and field surveying and mapping techniques. Discharge and water-quality measurements at six springs and one stream site were made during field investigations in June 1998. Discharge and water quality observed at a downstream weir on Upper Dorr Run represents the combined discharge from springs plus ground-water inflow. Discharges from springs to surface water were generally small (less than 0.3 cubic foot per second), but one spring constituted 56 percent of the total discharge measured at the downstream weir. The total flow at an intermediate measurement site was less than the combined discharge of the upgradient springs because of evaporation, transpiration, and ground-water flow beneath the stream channel. The total flow at the weir was greater than the combined discharge of all springs, primarily because two potential sources of water were not included in field measurements. The water quality in Upper Dorr Run is strongly affected by acid mine drainage as indicated by pH less than 4, elevated acidity, and elevated concentrations of dissolved sulfate and dissolved iron. Concentrations of chemical constituents in the water were lower at the downstream weir than at the source springs because of residence times in ponds and chemical interactions between the water and the atmosphere. Acidity loads during the sampling period were significantly higher from the Lower Kittanning (No. 5) coal (272 kilograms per day) than from the Upper Kittanning (No. 6) coal (17.7 kilograms per day). Comparison of data obtained in 1998 to data obtained in 1982 showed that quality of water of selected sampling sites had not changed appreciably in 16 years.

Identification and significance of Naegleria fowleri isolated from the hot spring which related to the first primary amebic meningoencephalitis (PAM) patient in Taiwan.

PubMed

Tung, Min-Che; Hsu, Bing-Mu; Tao, Chi-Wei; Lin, Wei-Chen; Tsai, Hsiu-Feng; Ji, Dar-Der; Shen, Shu-Min; Chen, Jung-Sheng; Shih, Feng-Cheng; Huang, Yu-Li

2013-08-01

Naegleria fowleri can cause primary amoebic meningoencephalitis, a rapidly developing and highly lethal infectious disease. The first confirmed case of primary amoebic meningoencephalitis in Taiwan was reported in November 2011, in which the patient visited a thermal spring recreational area 1 week prior to hospitalisation. Water sampling was performed to verify the presence of Naegleria at the facility. According to our results, 32% and 20% of recreational water samples were contaminated with Naegleria spp. and Acanthamoeba spp., respectively. The genotypes of Naegleria identified at the hot spring included N. fowleri, Naegleria australiensis and Naegleria lovaniensis. Using PCR, it was determined that the strain of N. fowleri in one sample possessed the same genotype 2 as the clinical isolate. Thus, the thermal spring was suggested to be the likely source of infection. This is the first known instance of simultaneously isolating N. fowleri from both a patient as well as from a hot spring in Taiwan. Following this initial study, the pools at the thermal spring recreational area were drained, scrubbed and disinfected, and a follow-up study was performed 1 month later. Naegleria fowleri was not detected in follow-up testing; however, other Naegleria spp. were identified. We postulate that the biofilm in the waterlines may have provided a reservoir for free-living amoebae. The presence/absence of Acanthamoeba and Naegleria spp. did not differ significantly with any measured parameters related to water quality; however, a high percentage of the thermal water pool samples were contaminated with Naegleria or Acanthamoeba. Thus, amoebic contamination may present a serious threat to the health of humans who engage in leisure activities at thermal springs. Copyright © 2013 Australian Society for Parasitology Inc. Published by Elsevier Ltd. All rights reserved.

Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma

USGS Publications Warehouse

Adamski, James C.

1997-01-01

A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.

Chemical, isotopic, and gas compositions of selected thermal springs in Arizona, New Mexico, and Utah

USGS Publications Warehouse

Mariner, R.H.; Presser, T.S.; Evans, William C.

1977-01-01

Twenty-seven thermal springs in Arizona, New Mexico, and Utah were sampled for detailed chemical and isotopic analysis. The springs issue sodium chloride, sodium bicarbonate, or sodium mixed-anion waters of near neutral (6.2) to alkaline (9.2) pH. High concentrations of fluoride, more than 8 milligrams per liter, occur in Arizona in waters from Gillard Hot Springs, Castle Hot Springs, and the unnamed spring of Eagle Creek, and in New Mexico from springs along the Gila River. Deuterium compositions of the thermal waters cover the same range as those expected for meteoric waters in the respective areas. The chemical compositions of the thermal waters indicate that Thermo Hot Springs in Utah and Gillard Hot Springs in Arizona represent hydrothermal systems which are at temperatures higher than 125 deg C. Estimates of subsurface temperature based on the quartz and Na-K-Ca geothermometer differ by up to 60 deg C for Monroe, Joseph, Red Hill, and Crater hot springs in Utah. Similar conflicting estimates of aquifer temperature occur for Verde Hot Springs, the springs near Clifton and Coolidge Dam, in Arizona; and the warm springs near San Ysidro, Radium Hot Springs, and San Francisco Hot Springs, in New Mexico. Such disparities could result from mixing, precipitation of calcium carbonate, or perhaps appreciable concentrations of magnesium. (Woodard-USGS)

Spatiotemporal patterns of stable isotopes and hydrochemistry in springs and river flow of the upper Karkheh River Basin, Iran.

PubMed

Osati, Khaled; Koeniger, Paul; Salajegheh, Ali; Mahdavi, Mohammad; Chapi, Kamran; Malekian, Arash

2014-06-01

Karst springs of the Zagros Mountains contribute a significant amount to agricultural and human water demands of western and south-western Iran. For an adequate management of available water resources in semi-arid and arid regions, sufficient hydrological monitoring is needed, and hydro-chemical and isotope hydrological data provide important additional information. About 350 water samples were collected from precipitation, river water, and karst springs of the upper part of the Karkheh River Basin (20,895 km(2)) located between 33°35(') and 34°55(') North and 46°22(') and 49°10(') East with elevations ranging from 928 to 3563 m above sea level. Sampling was conducted in monthly time resolution from August 2011 to July 2012. All samples were analysed for hydro-chemical parameters (pH, electrical conductivity, and major ions) and stable isotopes (deuterium, oxygen-18). Isotope values of precipitation indicate a local meteoric water line (Zagros MWL δ(2)H=6.8 δ(18)O+10.1; R(2)=0.99) situated between the Mediterranean MWL and Global MWL. Spring and river water isotope values vary between-7.1 and-4.1 ‰, and-38 and-25 ‰ for δ(18)O and δ(2)H, respectively, responding to winter snowmelt and evaporation. This work implements stable isotopes and hydro-chemical information of springs and river water to understand hydrological and hydro-geological interrelations in karstic semi-arid areas and helps to improve the current water resources management practices of western Iran.

Modeling anthropogenic boron in groundwater flow and discharge at Volusia Blue Spring (Florida, USA)

NASA Astrophysics Data System (ADS)

Reed, Erin M.; Wang, Dingbao; Duranceau, Steven J.

2017-01-01

Volusia Blue Spring (VBS) is the largest spring along the St. Johns River in Florida (USA) and the spring pool is refuge for hundreds of manatees during winter months. However, the water quality of the spring flow has been degraded due to urbanization in the past few decades. A three-dimensional contaminant fate and transport model, utilizing MODFLOW-2000 and MT3DMS, was developed to simulate boron transport in the Upper Florida Aquifer, which sustains the VBS spring discharge. The VBS model relied on information and data related to natural water features, rainfall, land use, water use, treated wastewater discharge, septic tank effluent flows, and fertilizers as inputs to simulate boron transport. The model was calibrated against field-observed water levels, spring discharge, and analysis of boron in water samples. The calibrated VBS model yielded a root-mean-square-error value of 1.8 m for the head and 17.7 μg/L for boron concentrations within the springshed. Model results show that anthropogenic boron from surrounding urbanized areas contributes to the boron found at Volusia Blue Spring.

Using multiple geochemical tracers to characterize the hydrogeology of the submarine spring off Crescent Beach, Florida

USGS Publications Warehouse

Swarzenski, P.W.; Reich, C.D.; Spechler, R.M.; Kindinger, J.L.; Moore, W.S.

2001-01-01

A spectacular submarine spring is located about 4 km east of Crescent Beach, FL, in the Atlantic Ocean. The single vent feature of Crescent Beach Spring provides a unique opportunity to examine onshore-offshore hydrogeologic processes, as well as point source submarine ground water discharge. The Floridan aquifer system in northeastern Florida consists of Tertiary interspersed limestone and dolomite strata. Impermeable beds confine the water-bearing zones under artesian pressure. Miocene and younger confining strata have been eroded away at the vent feature, enabling direct hydrologic communication of Eocene ground water with coastal bottom waters. The spring water had a salinity of 6.02, which was immediately diluted by ambient seawater during advection/mixing. The concentration of major solutes in spring water and onshore well waters confirm a generalized easterly flow direction of artesian ground water. Nutrient concentrations were generally low in the reducing vent samples, and the majority of the total nitrogen species existed as NH3. The submarine ground water tracers, Rn-222 (1174 dpm I-1, dpm), methane (232 nM) and barium (294.5 nM) were all highly enriched in the spring water relative to ambient seawater. The concentrations of the reverse redox elements U, V and Mo were expectedly low in the submarine waters. The strontium isotope ratio of the vent water (87Sr/86Sr = 0.70798) suggests that the spring water contain an integrated signature indicative of Floridan aquifer system ground water. Additional Sr isotopic ratios from a series of surficial and Lower Floridan well samples suggest dynamic ground water mixing, and do not provide clear evidence for a single hydrogeologic water source at the spring vent. In this karst-dominated aquifer, such energetic mixing at the vent feature is expected, and would be facilitated by conduit and fractured flow. Radium isotope activities were utilized to estimate flow-path trajectories and to provide information on potential travel times between an onshore well and the spring. Using either 223Ra and 224Ra or 228Ra, and qualifying this approach with several key assumptions, estimates of water mass travel times from an upper Floridan well in Crescent Beach to the submarine vent feature (distance =4050 m) are in the order of ??? 0.01-0.1 m min-1. ?? 2001 Elsevier Science B.V. All rights reserved.

[Impacts of dominated landscape types on hydrogen and oxygen isotope effects of spring water in the Hani Rice Terraces].

PubMed

Jiao, Yuan Mei; Liu, Cheng Jing; Liu, Xin; Liu, Zhi Lin; Ding, Yin Ping

2017-07-18

Analysis of hydrogen and oxygen stable isotopes is an effective method to track the water cycle in watershed. Impact of landscape pattern on the isotope effects of spring water is a new interdisciplinary topic between landscape ecology and isotope hydrology. Taking the Quanfuzhuang River basin located in the core area of UNESCO World Cultural Heritage of Honghe Hani Rice Terrace as the object, collecting the monthly samples of 78 points of spring water and 39 precipitation at altitude of 1500 m (terraces), 1700 m (terraces) and 1900 m (forest) from March 2015 to March 2016, we analyzed the hydrogen and oxygen stable isotopes of water samples under the different landscape types. The results indicated that the dominated landscape types were forests and rice terraces, being 66.6% and 22.1% of the whole landscape area respectively, and they had a spatial vertical pattern of forest located at the mountain top and rice terraces at the down-slope. The correlation analysis showed that the spring water not only came from the precipitation, but also from other water sources which had a more positive δ 18 O and δD values, the spring water in up-slope forests mainly came from precipitation, while that in down-slope rice terraces came from precipitation, ri-ver water, rice terrace water and under ground water. Therefore, the mixing effects of spring water δ 18 O and δD were more significant in rice terraces. The overall altitude effect of the hydrogen and oxygen stable isotopes in spring water was obvious. The linear decreasing rates of δ 18 O and δD values were -0.125‰·(100 m) -1 and -0.688‰·(100 m) -1 , respectively. The deuterium surplus value increased with the altitude because of the impacts of landscape pattern and the local cycle of water isotopes. In summary, the dominant landscape types had a significant impact on the hydrogen and oxygen isotopes of spring water, which could be used as response indicator to reveal the impacts of landscape pattern on hydrological process.

Spatial distribution of residence time, microbe and storage volume of groundwater in headwater catchments

NASA Astrophysics Data System (ADS)

Tsujimura, Maki; Ogawa, Mahiro; Yamamoto, Chisato; Sakakibara, Koichi; Sugiyama, Ayumi; Kato, Kenji; Nagaosa, Kazuyo; Yano, Shinjiro

2017-04-01

Headwater catchments in mountainous region are the most important recharge area for surface and subsurface waters, and time and stock information of the water is principal to understand hydrological processes in the catchments. Also, a variety of microbes are included in the groundwater and spring water, and those varies in time and space, suggesting that information of microbe could be used as tracer for groundwater flow system. However, there have been few researches to evaluate the relationship among the residence time, microbe and storage volume of the groundwater in headwater catchments. We performed an investigation on age dating using SF6 and CFCs, microbe counting in the spring water, and evaluation of groundwater storage volume based on water budget analysis in 8 regions underlain by different lithology, those are granite, dacite, sedimentary rocks, serpentinite, basalt and volcanic lava all over Japan. We conducted hydrometric measurements and sampling of spring water in base flow conditions during the rainless periods 2015 and 2016 in those regions, and SF6, CFCs, stable isotopic ratios of oxygen-18 and deuterium, inorganic solute concentrations and total number of prokaryotes were determined on all water samples. Residence time of spring water ranged from 0 to 16 years in all regions, and storage volume of the groundwater within topographical watershed was estimated to be 0.1 m to 222 m in water height. The spring with the longer residence time tends to have larger storage volume in the watershed, and the spring underlain by dacite tends to have larger storage volume as compared with that underlain by sand stone and chert. Also, total number of prokaryotes in the spring water ranged from 103 to 105 cells/mL, and the spring tends to show clear increasing of total number of prokaryotes with decreasing of residence time. Thus, we observed a certain relationship among residence time, storage volume and total number of prokaryotes in the spring water, and these parameters are effective to evaluate hydrological characteristics in the headwaters, and the microbe information could be an excellent tracer for groundwater flow research.

Seasonal variation of residence time in spring and groundwater evaluated by CFCs and numerical simulation in mountainous headwater catchment

NASA Astrophysics Data System (ADS)

Tsujimura, Maki; Watanabe, Yasuto; Ikeda, Koichi; Yano, Shinjiro; Abe, Yutaka

2016-04-01

Headwater catchments in mountainous region are the most important recharge area for surface and subsurface waters, additionally time information of the water is principal to understand hydrological processes in the catchments. However, there have been few researches to evaluate variation of residence time of subsurface water in time and space at the mountainous headwaters especially with steep slope. We investigated the temporal variation of the residence time of the spring and groundwater with tracing of hydrological flow processes in mountainous catchments underlain by granite, Yamanashi Prefecture, central Japan. We conducted intensive hydrological monitoring and water sampling of spring, stream and ground waters in high-flow and low-flow seasons from 2008 through 2013 in River Jingu Watershed underlain by granite, with an area of approximately 15 km2 and elevation ranging from 950 m to 2000 m. The CFCs, stable isotopic ratios of oxygen-18 and deuterium, inorganic solute constituent concentrations were determined on all water samples. Also, a numerical simulation was conducted to reproduce of the average residence times of the spring and groundwater. The residence time of the spring water estimated by the CFCs concentration ranged from 10 years to 60 years in space within the watershed, and it was higher (older) during the low flow season and lower (younger) during the high flow season. We tried to reproduce the seasonal change of the residence time in the spring water by numerical simulation, and the calculated residence time of the spring water and discharge of the stream agreed well with the observed values. The groundwater level was higher during the high flow season and the groundwater dominantly flowed through the weathered granite with higher permeability, whereas that was lower during the low flow season and that flowed dominantly through the fresh granite with lower permeability. This caused the seasonal variation of the residence time of the spring water, older in low flow season and younger in the high flow season in the watershed. As a result, the numerical model simulated successfully the dynamics of the groundwater flow and residence time in the spring water.

Simulation of the recharge area for Frederick Springs, Dane County, Wisconsin

USGS Publications Warehouse

Hunt, R.J.; Steuer, J.J.

2000-01-01

Analysis of samples from the springs and a nearby municipal well identified large contrasts in chemistry, even for springs within 50 feet of one another. The differences were stable over time, were present in both ion and isotope analyses, and showed a distinct gradation from high nitrate, high calcium, Ordovician-carbonate dominated water in western spring vents to low nitrate, lower calcium, Cambrian-sandstone influenced water in eastern spring vents. The difference in chemistry was attributed to distinctive bedrock geology as demonstrated by overlaying the 50 percent probability capture zone over a bedrock geology map for the area. This finding gives additional confidence to the capture zone calculated by the ground-water flow model.

Relation between flow and temporal variations of nitrate and pesticides in two karst springs in northern Alabama

USGS Publications Warehouse

Kingsbury, J.A.

2008-01-01

Two karst springs in the Mississippian Carbonate Aquifer of northern Alabama were sampled between March 1999 and March 2001 to characterize the variability in concentration of nitrate, pesticides, selected pesticide degradates, water temperature, and inorganic constituents. Water temperature and inorganic ion data for McGeehee Spring indicate that this spring represents a shallow flow system with a relatively short average ground-water residence time. Water issuing from the larger of the two springs, Meridianville Spring, maintained a constant temperature, and inorganic ion data indicate that this water represents a deeper flow system having a longer average ground-water residence time than McGeehee Spring. Although water-quality data indicate differing short-term responses to rainfall at the two springs, the seasonal variation of nitrate and pesticide concentrations generally is similar for the two springs. With the exception of pesticides detected at low concentrations, the coefficient of variation for most constituent concentrations was less than that of flow at both springs, with greater variability in concentration at McGeehee Spring. Degradates of the herbicides atrazine and fluometuron were detected at concentrations comparable to or greater than the parent pesticides. Decreases in concentration of the principal degradate of fluometuron from about July to November indicate that the degradation rate may decrease as fluometuron (demethylfluometuron) moves deeper into the soil after application. Data collected during the study show that from about November to March when recharge rates increase, nitrate and residual pesticides in the soil, unsaturated zone, and storage within the aquifer are transported to the spring discharges. Because of the increase in recharge, fluometuron loads discharged from the springs during the winter were comparable to loads discharged at the springs during the growing season. ?? 2008 American Water Resources Association.

Identification and quantitative detection of Legionella spp. in various aquatic environments by real-time PCR assay.

PubMed

Kao, Po-Min; Tung, Min-Che; Hsu, Bing-Mu; Chiu, Yi-Chou; She, Cheng-Yu; Shen, Shu-Min; Huang, Yu-Li; Huang, Wen-Chien

2013-09-01

In this study, a SYBR green quantitative real-time PCR was developed to quantify and detect the Legionella spp. in various environmental water samples. The water samples were taken from watershed, water treatment plant, and thermal spring area in Taiwan. Legionella was detected in 13.6 % (24/176), and the detection rate for river water, raw drinking water, and thermal spring water was 10, 21.4, and 16.6 %, respectively. Using real-time PCR, concentration of Legionella spp. in detected samples ranged between 9.75 × 10(4) and 3.47 × 10(5) cells/L in river water, 6.92 × 10(4) and 4.29 × 10(5) cells/L in raw drinking water, and 5.71 × 10(4) and 2.12 × 10(6) cells/L for thermal spring water samples. The identified species included Legionella pneumophila (20.8 %), Legionella jordanis (4.2 %), Legionella nautarum (4.2 %), Legionella sp. (4.2 %), and uncultured Legionella sp. (66.6 %). The presence of L. pneumophila in aquatic environments suggested a potential public health threat that must be further examined.

Evaluating Monitoring Strategies to Detect Precipitation-Induced Microbial Contamination Events in Karstic Springs Used for Drinking Water

PubMed Central

Besmer, Michael D.; Hammes, Frederik; Sigrist, Jürg A.; Ort, Christoph

2017-01-01

Monitoring of microbial drinking water quality is a key component for ensuring safety and understanding risk, but conventional monitoring strategies are typically based on low sampling frequencies (e.g., quarterly or monthly). This is of concern because many drinking water sources, such as karstic springs are often subject to changes in bacterial concentrations on much shorter time scales (e.g., hours to days), for example after precipitation events. Microbial contamination events are crucial from a risk assessment perspective and should therefore be targeted by monitoring strategies to establish both the frequency of their occurrence and the magnitude of bacterial peak concentrations. In this study we used monitoring data from two specific karstic springs. We assessed the performance of conventional monitoring based on historical records and tested a number of alternative strategies based on a high-resolution data set of bacterial concentrations in spring water collected with online flow cytometry (FCM). We quantified the effect of increasing sampling frequency and found that for the specific case studied, at least bi-weekly sampling would be needed to detect precipitation events with a probability of >90%. We then proposed an optimized monitoring strategy with three targeted samples per event, triggered by precipitation measurements. This approach is more effective and efficient than simply increasing overall sampling frequency. It would enable the water utility to (1) analyze any relevant event and (2) limit median underestimation of peak concentrations to approximately 10%. We conclude with a generalized perspective on sampling optimization and argue that the assessment of short-term dynamics causing microbial peak loads initially requires increased sampling/analysis efforts, but can be optimized subsequently to account for limited resources. This offers water utilities and public health authorities systematic ways to evaluate and optimize their current monitoring strategies. PMID:29213255

Evaluating Monitoring Strategies to Detect Precipitation-Induced Microbial Contamination Events in Karstic Springs Used for Drinking Water.

PubMed

Besmer, Michael D; Hammes, Frederik; Sigrist, Jürg A; Ort, Christoph

2017-01-01

Monitoring of microbial drinking water quality is a key component for ensuring safety and understanding risk, but conventional monitoring strategies are typically based on low sampling frequencies (e.g., quarterly or monthly). This is of concern because many drinking water sources, such as karstic springs are often subject to changes in bacterial concentrations on much shorter time scales (e.g., hours to days), for example after precipitation events. Microbial contamination events are crucial from a risk assessment perspective and should therefore be targeted by monitoring strategies to establish both the frequency of their occurrence and the magnitude of bacterial peak concentrations. In this study we used monitoring data from two specific karstic springs. We assessed the performance of conventional monitoring based on historical records and tested a number of alternative strategies based on a high-resolution data set of bacterial concentrations in spring water collected with online flow cytometry (FCM). We quantified the effect of increasing sampling frequency and found that for the specific case studied, at least bi-weekly sampling would be needed to detect precipitation events with a probability of >90%. We then proposed an optimized monitoring strategy with three targeted samples per event, triggered by precipitation measurements. This approach is more effective and efficient than simply increasing overall sampling frequency. It would enable the water utility to (1) analyze any relevant event and (2) limit median underestimation of peak concentrations to approximately 10%. We conclude with a generalized perspective on sampling optimization and argue that the assessment of short-term dynamics causing microbial peak loads initially requires increased sampling/analysis efforts, but can be optimized subsequently to account for limited resources. This offers water utilities and public health authorities systematic ways to evaluate and optimize their current monitoring strategies.

Relation of specific conductance in ground water to intersection of flow paths by wells, and associated major ion and nitrate geochemistry, Barton Springs Segment of the Edwards Aquifer, Austin, Texas, 1978-2003

USGS Publications Warehouse

Garner, Bradley D.; Mahler, Barbara J.

2007-01-01

Understanding of karst flow systems can be complicated by the presence of solution-enlarged conduits, which can transmit large volumes of water through the aquifer rapidly. If the geochemistry at a well can be related to streamflow or spring discharge (springflow), or both, the relations can indicate the presence of recent recharge in water at the well, which in turn might indicate that the well intersects a conduit (and thus a major flow path). Increasing knowledge of the occurrence and distribution of conduits in the aquifer can contribute to better understanding of aquifer framework and function. To that end, 26 wells in the Barton Springs segment of the Edwards aquifer, Austin, Texas, were investigated for potential intersection with conduits; 26 years of arbitrarily timed specific conductance measurements in the wells were compared to streamflow in five creeks that provide recharge to the aquifer and were compared to aquifer flow conditions as indicated by Barton Springs discharge. A nonparametric statistical test (Spearman's rho) was used to divide the 26 wells into four groups on the basis of correlation of specific conductance of well water to streamflow or spring discharge, or both. Potential relations between conduit intersection by wells and ground-water geochemistry were investigated through analysis of historical major ion and nitrate geochemistry for wells in each of the four groups. Specific conductance at nine wells was negatively correlated with both streamflow and spring discharge, or streamflow only. These correlations were interpreted as evidence of an influx of surface-water recharge during periods of high streamflow and the influence at the wells of water from a large, upgradient part of the aquifer; and further interpreted as indicating that four wells intersect major aquifer flow paths and five wells intersect minor aquifer flow paths (short, tributary conduits). Specific conductance at six wells was positively correlated with spring discharge, which was interpreted as not intersecting a flow path (conduit). Of the 11 wells for which specific conductance did not correlate with either streamflow or spring discharge, no interpretations regarding flow-path intersection by wells were made. In some cases, specific conductance data might not have indicated intersection with a flow path because of small sample sets. Water in the Barton Springs segment generally is a calcium-magnesium-bicarbonate type, although some water compositions deviate from this. Multiple geochemical processes were identified that might affect geochemistry at the wells, but in general the geochemical composition of ground water, except for dilution by surface-water recharge, was not related to intersection of a well with a flow path. Some samples from wells indicate inflow of water from the saline zone to the east; this inflow is associated with low streamflow and spring discharge. Other samples indicate that the aquifer at some wells might be receiving water that has been in contact with rocks of the Trinity aquifer; this mixing is most evident when spring discharge is high. Occurrence of nitrate in ground water was unrelated to intersection of flow paths by wells and appeared to be the result of localized contamination. However, most of the wells with one or more samples contaminated by nitrate are in the more densely populated parts of the study area.

Investigation of Carbon, Nutrients, and Groundwater Inputs in Coastal Florida Using Colored Dissolved Organic Matter

NASA Astrophysics Data System (ADS)

Arellano, A. R.; Coble, P. G.; Conmy, R. N.; Marine Spectrochemistry Group

2010-12-01

Very few studies of the exchange of water between aquifers and the ocean have been conducted along the Florida coast. Progression of residential and agricultural development in coastal areas is leading to increased nutrients from fertilizers and wastewaters to groundwater. A portion of these nutrients ultimately is released to coastal surface waters. Groundwater mining has increased salt water intrusions in coastal aquifers which may further enhance nutrient fluxes to coastal surface waters. Nutrient concentration in coastal groundwater is sometimes higher than those in river water, counterbalancing for the lower mass flux of groundwater relative to surface waters. Nutrient and carbon inputs through groundwater in certain areas may play an important role in cycling and primary productivity in the coastal ocean. King’s Bay is a spring-fed watershed and manatee sanctuary located on the West Florida Shelf. Over the past 25 years, springs supplying groundwater to King’s Bay have shown a three-fold increase in nitrate concentration and increased invasion of nuisance algae. It has been challenging to track sources of both nutrients and other water quality parameters because there are multiple water supplies to King’s Bay. The goal of this project is to improve the estimate of water, nutrients, and carbon from groundwater discharge into the coastal zone. This paper will present preliminary results of high resolution fluorescence spectroscopy analyses of the various source water types in the King's Bay watershed, including deep and shallow aquifers, wells, springs, and surface water sources. Samples were obtained from various sites--5 springs, 27 wells, 12 surface, and 9 lakes and rivers-- within the King’s Bay area during one dry season. Lakes and rivers had the highest fluorescence intensities and showed similar composition, with the most red-shifted emission maxima. Second highest concentration was seen in some of the wells which had wide range in both composition and intensities. King’s Bay surface sites appear to be a mixture of surface water and spring water based on both composition and concentration. Springs samples were all similar in composition, with concentrations in middle range found in well samples. These results will be discussed in reference to determination of source of water, carbon, and nutrients to the springs.

Effect of alteration zones on water quality: a case study from Biga Peninsula, Turkey.

PubMed

Baba, Alper; Gunduz, Orhan

2010-04-01

Widespread and intense zones of silicified, propylitic, and argillic alteration can be found in the Can volcanics of Biga Peninsula, northwest Turkey. Most of the springs in the study area surface out from the boundary between fractured aquifer (silicified zone) and impervious boundary (argillic zone). This study focuses on two such springs in Kirazli area (Kirazli and Balaban springs) with a distinct quality pattern. Accordingly, field parameters (temperature, pH, and electrical conductivity), major anion and cation (sodium, potassium, calcium, magnesium, chloride, bicarbonate, and sulfate), heavy metals (aluminum, arsenic, barium, chromium, cobalt, cupper, iron, lithium, manganese, nickel, lead, and zinc), and isotopes (oxygen-18, deuterium, and tritium) were determined in water samples taken from these springs during 2005 through 2007. The chemical analyses showed that aluminum concentrations were found to be two orders of magnitude greater in Kirazli waters (mean value 13813.25 microg/L). The levels of this element exceeded the maximum allowable limits given in national and international standards for drinking-water quality. In addition, Balaban and Kirazli springs are >55 years old according to their tritium levels; Kirazli spring is older than Balaban spring. Kirazli spring is also more enriched than Balaban spring based in oxygen-18 and deuterium values. Furthermore, Kirazli spring water has been in contact with altered rocks longer than Balaban spring water, according to its relatively high chloride and electrical conductivity values.

Sources and Residence Times of Groundwater in Shasta County, CA Determined by Isotopic Tracers

NASA Astrophysics Data System (ADS)

Peters, E.; Moran, J. E.; Deinhart, A.; Roberts, S. K.; Esser, B.; Visser, A.

2015-12-01

Large-volume springs are a significant source of water to communities in Shasta County. Aquifers in this region are developed in young volcanic formations and the age and flow of groundwater is not well characterized, making predicting the impact of drought and climate change on spring flow difficult. To better understand the water resources and the hydrogeology of the region and to better constrain the age of water produced by springs, we have sampled water from wells, springs, and streams for a suite of geochemical and isotopic tracers. We are using isotopic tracers because of the limited number of sampling points over a large area, leaving traditional hydrogeologic methods such as water levels and pump tests inadequate for a regional study. We analyzed samples for sulfur-35 (87.4 day half-life) and found detections in two springs, confirming the presence of a fraction of recently (1-2 years) recharged groundwater. Tritium (12.3 year half-life) activities show that some wells produce water recharged more than 5 decades ago, but most produce more recently recharged water. We will also report results for sodium-22 (2.6 year half-life), krypton-85 (10.8 year half-life), carbon-14 (5,730 year half-life), dissolved noble gases, stable isotopes of water, and helium isotopic composition. These isotopes are applied to determine the age (residence time) of groundwater over a broad age distribution, from less than one year to tens of thousands of years. These tracers should also provide information on aquifer volumes, help delineate groundwater flow, and help to identify recharge areas. A collection of groundwater ages from springs at high elevations to wells in the upper Sacramento Valley will help delineate groundwater flowpaths. Finally, groundwater residence times will help determine groundwater volume and recharge rates, and resolve questions related to drought vulnerability and effective adjustments in water resource management.

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona--2003-04

USGS Publications Warehouse

Truini, Margot; Macy, Jamie P.; Porter, Thomas J.

2005-01-01

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2003, total ground-water withdrawals were 7,240 acre-feet, industrial withdrawals were 4,450 acre-feet, and municipal withdrawals were 2,790 acre-feet. From 2002 to 2003, total withdrawals decreased by 10 percent, industrial withdrawals decreased by 4 percent, and municipal withdrawals decreased by 20 percent. Flowmeter testing was completed for 24 municipal wells in 2004. The median difference between pumping rates for the permanent meter and a test meter for all the sites tested was -2.9 percent. Values ranged from -10.9 percent at Forest Lake NTUA 1 to +7.8 percent at Rough Rock NTUA 2. From 2003 to 2004, water levels declined in 6 of 12 wells in the unconfined part of the aquifer, and the median change was -0.1 foot. Water levels declined in 7 of 11 wells in the confined part of the aquifer, and the median change was -2.7 feet. From the prestress period (prior to 1965) to 2003, the median water-level change for 26 wells was -23.2 feet. Median water-level change were -6.1 feet for 14 wells in the unconfined parts of the aquifer and and -72.1 feet for 12 wells in the confined part. Discharges were measured once in 2003 and once in 2004 at four springs. Discharge stayed the same at Pasture Canyon Spring, increased 9 percent at Moenkopi Spring, decreased 26 percent at an unnamed spring near Dennehotso, and decreased 50 percent at Burro Spring. For the past 12 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2003 at Moenkopi Wash, 1996 to 2003 at Laguna Creek, 1993 to 2003 at Dinnebito Wash, and 1994 to 2003 at Polacca Wash. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since the first continuous record of surface-water discharge in 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2004, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 100 to 649 milligrams per liter. Water samples from 11 of the wells and from all the springs had less than 500 milligrams per liter of dissolved solids. There are no appreciable time trends in the chemistry of water samples from 7 wells and 2 springs; increasing trends in dissolved-solids and chloride concentrations were evident from the more than 10 years of data for 2 springs.

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona, 2002-03

USGS Publications Warehouse

Truini, Margot; Thomas, Blakemore E.

2004-01-01

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2002, total ground-water withdrawals were 8,000 acre-feet, industrial use was 4,640 acre-feet, and municipal use was 3,360 acre-feet. From 2001 to 2002, total withdrawals increased by 4 percent, industrial use increased by 2 percent, and municipal use increased by 7 percent. Flowmeter testing was completed for 32 municipal wells in 2003. The median difference between pumping rates for the permanent meter and a test meter for all the sites tested was -2.0 percent. Values ranged from -13.7 percent at Hopi High School no. 2 to +12.9 percent at Shonto PM3. From 2002 to 2003, water levels declined in 5 of 13 wells in the unconfined part of the aquifer, and the median change was 0.0 foot. Water levels declined in 8 of 13 wells in the confined part of the aquifer, and the median change was -1.1 feet. From the prestress period (prior to 1965) to 2003, the median water-level change for 26 wells was -8.3 feet. Median water-level changes were -0.4 foot for 13 wells in the unconfirned part of the aquifer and -60.3 feet for 13 wells in the confined part. Discharges were measured once in 2002 and once in 2003 at four springs. Discharge decreased by 16 percent at Pasture Canyon Spring, increased 10 percent at Moenkopi Spring and 90 percent at an unnamed spring near Dennehotso, and did not change at Burro Spring. For the past 11 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2002 at Moenkopi Wash, 1996 to 2002 at Laguna Creek, 1993 to 2002 at Dinnebito Wash, and 1994 to 2002 at Polacca Wash. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since the first continuous record of surface-water discharge in 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2003, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 118 to 642 milligrams per liter. Water samples from 10 of the wells and from all of the springs had less than 500 milligrams per liter of dissolved solids. There are no appreciable time trends in the chemistry of water samples from 7 wells and 4 springs; 7 wells had more than 8 years of data, and the 4 springs had more than 10 years of data.

Water-Chemistry Data for Selected Springs, Geysers, and Streams in Yellowstone National Park, Wyoming, 2003-2005

USGS Publications Warehouse

Ball, James W.; McCleskey, R. Blaine; Nordstrom, D. Kirk; Holloway, JoAnn M.

2008-01-01

Water analyses are reported for 157 samples collected from numerous hot springs, their overflow drainages, and Lemonade Creek in Yellowstone National Park (YNP) during 2003-2005. Water samples were collected and analyzed for major and trace constituents from ten areas of YNP including Terrace and Beryl Springs in the Gibbon Canyon area, Norris Geyser Basin, the West Nymph Creek thermal area, the area near Nymph Lake, Hazle Lake, and Frying Pan Spring, Lower Geyser Basin, Washburn Hot Springs, Mammoth Hot Springs, Potts Hot Spring Basin, the Sulphur Caldron area, and Lemonade Creek near the Solfatara Trail. These water samples were collected and analyzed as part of research investigations in YNP on arsenic, antimony, and sulfur redox distribution in hot springs and overflow drainages, and the occurrence and distribution of dissolved mercury. Most samples were analyzed for major cations and anions, trace metals, redox species of antimony, arsenic, iron, nitrogen, and sulfur, and isotopes of hydrogen and oxygen. Analyses were performed at the sampling site, in an on-site mobile laboratory vehicle, or later in a U.S. Geological Survey laboratory, depending on stability of the constituent and whether it could be preserved effectively. Water samples were filtered and preserved onsite. Water temperature, specific conductance, pH, Eh (redox potential relative to the Standard Hydrogen Electrode), and dissolved hydrogen sulfide were measured onsite at the time of sampling. Acidity was determined by titration, usually within a few days of sample collection. Alkalinity was determined by titration within 1 to 2 weeks of sample collection. Concentrations of thiosulfate and polythionate were determined as soon as possible (generally minutes to hours after sample collection) by ion chromatography in an on-site mobile laboratory vehicle. Total dissolved-iron and ferrous-iron concentrations often were measured onsite in the mobile laboratory vehicle. Concentrations of dissolved aluminum, arsenic, boron, barium, beryllium, calcium, cadmium, cobalt, chromium, copper, iron, potassium, lithium, magnesium, manganese, molybdenum, sodium, nickel, lead, selenium, silica, strontium, vanadium, and zinc were determined by inductively-coupled plasma-optical emission spectrometry. Trace concentrations of dissolved antimony, cadmium, cobalt, chromium, copper, lead, and selenium were determined by Zeeman-corrected graphite-furnace atomic-absorption spectrometry. Dissolved concentrations of total arsenic, arsenite, total antimony, and antimonite were determined by hydride-generation atomic-absorption spectrometry using a flow-injection analysis system. Dissolved concentrations of total mercury and methyl mercury were determined by cold-vapor atomic-fluorescence spectrometry. Concentrations of dissolved chloride, fluoride, nitrate, bromide, and sulfate were determined by ion chromatography. Concentrations of dissolved ferrous and total iron were determined by the FerroZine colorimetric method. Concentrations of dissolved nitrite were determined by colorimetry or chemiluminescence. Concentrations of dissolved ammonium were determined by ion chromatography, with reanalysis by colorimetry when separation of sodium and ammonia peaks was poor. Dissolved organic carbon concentrations were determined by the wet persulfate oxidation method. Hydrogen and oxygen isotope ratios were determined using the hydrogen and CO2 equilibration techniques, respectively.

A waterborne outbreak of hepatitis A in Meade County, Kentucky.

PubMed Central

Bergeisen, G H; Hinds, M W; Skaggs, J W

1985-01-01

In November 1982, Meade County, Kentucky health officials noted a sudden increase in the incidence of hepatitis A. Using a standardized interview of 73 cases (68 serologically confirmed), and 85 controls (all negative for antibody to hepatitis A virus), the most important risk factor identified was household use of untreated water from a single spring. A dose-response relationship was found for consumption of unboiled spring water. Water samples taken from the spring during the outbreak were contaminated with fecal coliforms. PMID:3966622

Hydrology and water quality of the Edwards Aquifer associated with Barton Springs in the Austin area, Texas

USGS Publications Warehouse

Slade, Raymond M.; Dorsey, Michael E.; Stewart, Sheree L.

1986-01-01

Water-quality data for 1979-83 are available for each creek that recharges the aquifer, from Barton Springs, and for 38 wells. Water quality from Barton Springs and the wells is better than the creeks providing surface recharge, which have fecal-bacteria values as high as 100,000 colonies per 100 milliliters. Significant densities of fecal bacteria have been found in water from Barton Springs. Significant concentrations of nitrate nitrogen, fecal-group bacteria, and fluoride have been identified in samples from wells. Fluoride originates in the aquifers that underlie the Edwards aquifer. Nitrate nitrogen and fecal-group bacteria originate in residential developments and cattle ranches located in the area.

Relative abundance and distribution of fishes and crayfish at Ash Meadows National Wildlife Refuge, Nye County, Nevada, 2007-08

USGS Publications Warehouse

Scoppettone, G. Gary; Rissler, Peter; Johnson, Danielle; Hereford, Mark

2011-01-01

This study provides baseline data of native and non-native fish populations in Ash Meadows National Wildlife Refuge (NWR), Nye County, Nevada, that can serve as a gauge in native fish enhancement efforts. In support of Carson Slough restoration, comprehensive surveys of Ash Meadows NWR fishes were conducted seasonally from fall 2007 through summer 2008. A total of 853 sampling stations were created using Geographic Information Systems and National Agricultural Imagery Program. In four seasons of sampling, Amargosa pupfish (genus Cyprinodon) was captured at 388 of 659 stations. The number of captured Amargosa pupfish ranged from 5,815 (winter 2008) to 8,346 (summer 2008). The greatest success in capturing Amargosa pupfish was in warm water spring-pools with temperature greater than 25 degrees C, headwaters of warm water spring systems, and shallow (depths less than 10 centimeters) grassy marshes. In four seasons of sampling, Ash Meadows speckled dace (Rhinichthys osculus nevadesis) was captured at 96 of 659 stations. The number of captured Ash Meadows speckled dace ranged from 1,009 (summer 2008) to 1,552 (winter 2008). The greatest success in capturing Ash Meadows speckled dace was in cool water spring-pools with temperature less than 20 degrees C and in the high flowing water outflows. Among 659 sampling stations within the range of Amargosa pupfish, red swamp crayfish (Procambarus clarkii) was collected at 458 stations, western mosquitofish (Gambusia affinis) at 374 stations, and sailfin molly (Poecilia latipinna) at 128 stations. School Springs was restored during the course of this study. Prior to restoration of School Springs, maximum Warm Springs Amargosa pupfish (Cyprinodon nevadensis pectoralis) captured from the six springs of the Warm Springs Complex was 765 (fall 2007). In four seasons of sampling, Warm Springs Amargosa pupfish were captured at 85 of 177 stations. The greatest success in capturing Warm Springs Amargosa pupfish when co-occurring with red swamp crayfish and western mosquitofish was in water with temperature greater than 26 degrees C near the springhead, and in shallow (depths less than 10 centimeters) grassy marshes. Among 177 sampling stations within the range of Warm Springs Amargosa pupfish, red swamp crayfish were collected at 96 stations and western mosquitofish were collected at 49 stations. Removal of convict cichlid (Amatitlania nigrofasciata) from Fairbanks Spring was followed by a substantial increase in Ash Meadows Amargosa pupfish (Cyprinodon nevadensis mionectes) captures from 910 pre-removal to 3,056 post-removal. Red swamp crayfish was continually removed from Bradford 1 Spring, which seemed to cause an increase in the speckled dace population. Restoration of Kings Pool and Jackrabbit Springs promoted the success of native fishes with the greatest densities in restored reaches. Ongoing restoration of Carson Slough and its tributaries, as well as control and elimination of invasive species, is expected to increase abundance and distribution of Ash Meadows' native fish populations. Further analysis of data from this study will help determine the habitat characteristic(s) that promote native species and curtail non-native species.

Fate and transport of petroleum hydrocarbons in soil and ground water at Big South Fork National River and Recreation Area, Tennessee and Kentucky, 2002-2003

USGS Publications Warehouse

Williams, Shannon D.; Ladd, David E.; Farmer, James

2006-01-01

In 2002 and 2003, the U.S. Geological Survey (USGS), by agreement with the National Park Service (NPS), investigated the effects of oil and gas production operations on ground-water quality at Big South Fork National River and Recreation Area (BISO) with particular emphasis on the fate and transport of petroleum hydrocarbons in soils and ground water. During a reconnaissance of ground-water-quality conditions, samples were collected from 24 different locations (17 springs, 5 water-supply wells, 1 small stream, and 1 spring-fed pond) in and near BISO. Benzene, toluene, ethylbenzene, and xylene (BTEX) compounds were not detected in any of the water samples, indicating that no widespread contamination of ground-water resources by dissolved petroleum hydrocarbons probably exists at BISO. Additional water-quality samples were collected from three springs and two wells for more detailed analyses to obtain additional information on ambient water-quality conditions at BISO. Soil gas, soil, water, and crude oil samples were collected at three study sites in or near BISO where crude oil had been spilled or released (before 1993). Diesel range organics (DRO) were detected in soil samples from all three of the sites at concentrations greater than 2,000 milligrams per kilogram. Low concentrations (less than 10 micrograms per kilogram) of BTEX compounds were detected in lab-analyzed soil samples from two of the sites. Hydrocarbon-degrading bacteria counts in soil samples from the most contaminated areas of the sites were not greater than counts for soil samples from uncontaminated (background) sites. The elevated DRO concentrations, the presence of BTEX compounds, and the low number of -hydrocarbon-degrading bacteria in contaminated soils indicate that biodegradation of petroleum hydrocarbons in soils at these sites is incomplete. Water samples collected from the three study sites were analyzed for BTEX and DRO. Ground-water samples were collected from three small springs at the two sites located on ridge tops. BTEX and DRO were not detected in any of the water samples, and petroleum hydrocarbons do not appear to have leached into ground water at these sites. Ground-water samples were collected from a small spring and from three auger holes at the third site, which is located in a stream valley. BTEX and DRO were not detected in these ground-water samples, and currently, petroleum hydrocarbons do not appear to be leaching into ground water at this site. Weathered crude oil, however, was detected at the water surface in one of the auger holes, indicating that soluble petroleum hydrocarbons may have leached into the ground water and may have migrated downgradient from the site in the past. The concentration of soluble petroleum hydrocarbons present in the ground water would depend on the concentration of the hydrocarbons in the crude oil at the site. A laboratory study was conducted to examine the dissolution of petroleum hydrocarbons from a fresh crude oil sample collected from one of the study sites. The effective solubility of benzene, toluene, ethylbenzene, and total xylenes for the crude oil sample was determined to be 1,900, 1,800, 220, and 580 micrograms per liter (?g/L), respectively. These results indicate that benzene and toluene could be present at concentrations greater than maximum contaminant levels (5 ?g/L for benzene and 1,000 ?g/L for toluene for drinking water) in ground water that comes into contact with fresh crude oil from the study area.

Ground-water, surface-water, and water-chemistry data, Black Mesa area, Northeastern Arizona: 1999

USGS Publications Warehouse

Thomas, Blakemore E.; Truini, Margot

2000-01-01

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and a precipitation of only about 6 to 12 inches per year. The monitoring program in Black Mesa has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, and (5) ground-water chemistry. In 1999, total ground-water withdrawals were 7,110 acre-feet, industrial use was 4,210 acre-feet, and municipal use was 2,900 acre-feet. From 1998 to 1999, total withdrawals increased by 0.7 percent, industrial use increased by 4 percent, and municipal use decreased by 4 percent. From 1998 to 1999, water levels declined in 11 of 15 wells in the unconfined part of the aquifer, and the median decline was 0.7 foot. Water levels declined in 14 of 16 wells in the confined part of the aquifer, and the median decline was 1.2 feet. From the prestress period (prior to 1965) to 1999, the median water-level decline in 31 wells was 10.6 feet. Median water-level changes were 0.0 foot for 15 wells in the unconfined part of the aquifer and a decline of 45.5 feet in 16 wells in the confined part. From 1998 to 1999, discharges were measured annually at four springs. Discharges declined 30 percent and 3 percent at 2 springs, did not change at 1 spring, and increased by 11 percent at 1 spring. For the past 10 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend was not observed. Continuous records of surface-water discharge have been collected from July 1976 to 1999 at Moenkopi Wash, July 1996 to 1999 at Laguna Creek, June 1993 to 1999 at Dinnebito Wash, and April 1994 to 1999 at Polacca Wash. Median flows for November, December, January, and February of each water year are used as an index of ground-water discharge to those streams. Increasing or decreasing trends are not apparent in these median winter flows for the periods of record. In 1999, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 91 to 630 milligrams per liter. Water samples from 10 of the wells and the 4 springs had less than 350 milligrams per liter of dissolved solids. Water-chemistry data are available for nine wells and four springs from about the mid-1980s. For that time period, the data from those sites have remained fairly stable. From 1987 to 1999, concentrations of dissolved solids, chloride, and sulfate may have increased slightly in samples from Moenkopi School Spring.

Ground-water, surface-water and water-chemistry data, Black Mesa area, northeastern Arizona: 2001-02

USGS Publications Warehouse

Thomas, Blakemore E.

2002-01-01

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, and (5) ground-water chemistry. In 2001, total ground-water withdrawals were 7,680 acre-feet, industrial use was 4,530 acre-feet, and municipal use was 3,150 acre-feet. From 2000 to 2001, total withdrawals decreased by 1 percent, industrial use increased by 1 percent, and municipal use decreased by 3 percent. From 2001 to 2002, water levels declined in 5 of 14 wells in the unconfined part of the aquifer, and the median change was +0.2 foot. Water levels declined in 12 of 17 wells in the confined part of the aquifer, and the median change was -1.4 feet. From the prestress period (prior to 1965) to 2002, the median water-level change for 32 wells was -15.8 feet. Median water-level changes were -1.3 feet for 15 wells in the unconfined part of the aquifer and -31.7 feet for 17 wells in the confined part. Discharges were measured once in 2001 and once in 2002 at four springs. Discharges decreased by 26 percent and 66 percent at two springs, increased by 100 percent at one spring, and did not change at one spring. For the past 10 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2001 at Moenkopi Wash, 1996 to 2001 at Laguna Creek, 1993 to 2001 at Dinnebito Wash, and 1994 to 2001 at Polacca Wash. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2002, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 96 to 636 milligrams per liter. Water samples from 8 of the wells and from 3 of the springs had less than 300 milligrams per liter of dissolved solids. There are no appreciable time trends in the chemistry of water samples from 9 wells and 4 springs; the 9 wells had more than 7 years of data, and the 4 springs had more than 9 years of data.

Potential impacts to perennial springs from tar sand mining, processing, and disposal on the Tavaputs Plateau, Utah, USA.

PubMed

Johnson, William P; Frederick, Logan E; Millington, Mallory R; Vala, David; Reese, Barbara K; Freedman, Dina R; Stenten, Christina J; Trauscht, Jacob S; Tingey, Christopher E; Kip Solomon, D; Fernandez, Diego P; Bowen, Gabriel J

2015-11-01

Similar to fracking, the development of tar sand mining in the U.S. has moved faster than understanding of potential water quality impacts. Potential water quality impacts of tar sand mining, processing, and disposal to springs in canyons incised approximately 200 m into the Tavaputs Plateau, at the Uinta Basin southern rim, Utah, USA, were evaluated by hydrogeochemical sampling to determine potential sources of recharge, and chemical thermodynamic estimations to determine potential changes in transfer of bitumen compounds to water. Because the ridgetops in an area of the Tavaputs Plateau named PR Spring are starting to be developed for their tar sand resource, there is concern for potential hydrologic connection between these ridgetops and perennial springs in adjacent canyons on which depend ranching families, livestock, wildlife and recreationalists. Samples were collected from perennial springs to examine possible progression with elevation of parameters such as temperature, specific conductance, pH, dissolved oxygen, isotopic tracers of phase change, water-rock interaction, and age since recharge. The groundwater age dates indicate that the springs are recharged locally. The progression of hydrogeochemical parameters with elevation, in combination with the relatively short groundwater residence times, indicate that the recharge zone for these springs includes the surrounding ridges, and thereby suggests a hydrologic connection between the mining, processing, disposal area and the springs. Estimations based on chemical thermodynamic approaches indicate that bitumen compounds will have greatly enhanced solubility in water that comes into contact with the residual bitumen-solvent mixture in disposed tailings relative to water that currently comes into contact with natural tar. Copyright © 2015 Elsevier B.V. All rights reserved.

Radioactive mineral springs in Delta County, Colorado

USGS Publications Warehouse

Cadigan, Robert A.; Rosholt, John N.; Felmlee, J. Karen

1976-01-01

The system of springs in Delta County, Colo., contains geochemical clues to the nature and location of buried uranium-mineralized rock. The springs, which occur along the Gunnison River and a principal tributary between Delta and Paonia, are regarded as evidence of a still-functioning hydrothermal system. Associated with the springs are hydrogen sulfide and sulfur dioxide gas seeps, carbon dioxide gas-powered geysers, thick travertine deposits including radioactive travertine, and a flowing warm-water (41?C) radioactive well. Geochemical study of the springs is based on surface observations, on-site water-property measurements, and sampling of water, travertine, soft precipitates, and mud. The spring deposits are mostly carbonates, sulfates, sulfides, and chlorides that locally contain notable amounts of some elements, such as arsenic, barium, lithium, and radium. Samples from five localities have somewhat different trace element assemblages even though they are related to the same hydrothermal system. All the spring waters but one are dominated by sodium chloride or sodium bicarbonate. The exception is an acid sulfate water with a pH of 2.9, which contains high concentrations of aluminum and iron. Most of the detectable radioactivity is due to the presence of radium-226, a uranium daughter product, but at least one spring precipitate contains abundant radium-228, a thorium daughter product. The 5:1 ratio of radium-228 to radium-226 suggests the proximity of a vein-type deposit as a source for the radium. The proposed locus of a thorium-uranium mineral deposit is believed to lie in the vicinity of Paonia, Colo. Exact direction and depth are not determinable from data now available.

Water quality parameters associated with prevalence of Legionella in hot spring facility water bodies.

PubMed

Huang, Shih-Wei; Hsu, Bing-Mu; Wu, Shu-Fen; Fan, Cheng-Wei; Shih, Feng-Cheng; Lin, Yung-Chang; Ji, Dar-Der

2010-09-01

Some species of Legionella are recognized as opportunistic potential human pathogens, such as Legionella pneumophila, which causes legionnaires disease. Indeed, outbreaks of legionellosis are frequently reported in areas in which the organism has been spread via aerosols from contaminated institutional water systems. Contamination in hot tubs, spas and public baths are also possible. As a result, in this study, we investigated the distribution of Legionella at six hot spring recreation areas throughout Taiwan. Legionella were detected in all six hot spring recreation areas, as well as in 20 of the 72 samples that were collected (27.8%). Seven species of Legionella identified from samples by the direct DNA extraction method were unidentified Legionella spp., Legionella anisa, L. pneumophila, Legionella erythra, Legionella lytica, Legionella gresilensis and Legionella rubrilucen. Three species of Legionella identified in the samples using the culture method were L. pneumophila, unidentified Legionella spp. and L. erythra. Legionella species were found in water with temperatures ranging from 22.7 °C to 48.6 °C. The optimal pH appeared to range from 5.0 to 8.0. Taken together, the results of this survey confirmed the ubiquity of Legionella in Taiwan spring recreational areas. Therefore, a long-term investigation of the health of workers at hot spring recreational areas and the occurrence of Legionella in hot spring recreational areas throughout Taiwan are needed. Copyright © 2010 Elsevier Ltd. All rights reserved.

The impact of river water intrusion on trace metal cycling in karst aquifers: an example from the Floridan aquifer system at Madison Blue Spring, Florida

NASA Astrophysics Data System (ADS)

Brown, A. L.; Martin, J. B.; Screaton, E.; Spellman, P.; Gulley, J.

2011-12-01

Springs located adjacent to rivers can serve as recharge points for aquifers when allogenic runoff increases river stage above the hydraulic head of the spring, forcing river water into the spring vent. Depending on relative compositions of the recharged water and groundwater, the recharged river water could be a source of dissolved trace metals to the aquifer, could mobilize solid phases such as metal oxide coatings, or both. Whether metals are mobilized or precipitated should depend on changes in redox and pH conditions as dissolved oxygen and organic carbon react following intrusion of the river water. To assess how river intrusion events affect metal cycling in springs, we monitored a small recharge event in April 2011 into Madison Blue Spring, which discharges to the Withlacoochee River in north-central Florida. Madison Blue Spring is the entrance to a phreatic cave system that includes over 7.8 km of surveyed conduits. During the event, river stage increased over base flow conditions for approximately 25 days by a maximum of 8%. Intrusion of the river water was monitored with conductivity, temperature and depth sensors that were installed within the cave system and adjacent wells. Decreased specific conductivity within the cave system occurred for approximately 20 days, reflecting the length of time that river water was present in the cave system. During this time, grab samples were collected seven times over a period of 34 days for measurements of major ion and trace metal concentrations at the spring vent and at Martz sink, a karst window connected to the conduit system approximately 150 meters from the spring vent. Relative fractions of surface water and groundwater were estimated based on Cl concentrations of the samples, assuming conservative two end-member mixing during the event. This mixing model indicates that maximum river water contribution to the groundwater system was approximately 20%. River water had concentrations of iron, manganese, and other trace metals that were elevated by several orders of magnitude above the concentrations of groundwater at base flow. Maximum iron concentrations in the grab samples coincide with the peak of river water inflow into the cave system, but preliminary results suggest the maximum concentration is about 13% lower than expected based on mixing alone. This depletion below expected concentrations indicates that some of the iron intruded with the river water has been removed, presumably through precipitation of Fe-oxides. In contrast, peak manganese concentrations in the aquifer occur 14 days after the peak of the reversal when the spring is again discharging, suggesting that manganese within the cave system was mobilized. These data suggest that dissolution and precipitation reactions of Fe and Mn are decoupled in the system. This decoupling could result from changing redox conditions as river water intrudes the caves, driving oxidation of dissolved organic matter introduced with the river water.

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona--2004-05

USGS Publications Warehouse

Truini, Margot; Macy, J.P.

2006-01-01

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2004, total ground-water withdrawals were 7,210 acre-feet, industrial withdrawals were 4,370 acre-feet, and municipal withdrawals were 2,840 acre-feet. From 2003 to 2004, total withdrawals decreased by less than 1 percent, industrial withdrawals decreased by 2 percent, and municipal withdrawals increased by 2 percent. From 2004 to 2005, annually measured water levels declined in 6 of 13 wells in the unconfined areas of the aquifer, and the median change was -0.1 foot. Water levels declined in 8 of 12 wells in the confined area of the aquifer, and the median change was -1.2 feet. From the prestress period (prior to 1965) to 2005, the median water-level change for 33 wells was -9.0 feet. Median water-level changes were -0.6 foot for 16 wells in the unconfined areas and -32.0 feet for 17 wells in the confined area. Discharges were measured once in 2004 and once in 2005 at four springs. Discharge increased by 8 percent at Pasture Canyon Spring, decreased by 5 percent at Moenkopi School Spring, increased by 71 percent at an unnamed spring near Dennehotso, and stayed the same at Burro Spring. For the period of record at each spring, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2004 at Moenkopi Wash, 1996 to 2004 at Laguna Creek, 1993 to 2004 at Dinnebito Wash, 1994 to 2004 at Polacca Wash, and August 2004 to December 2004 at Pasture Canyon Spring. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since the first continuous record of surface-water discharge in 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2005, water samples were collected from 11 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 122 to 639 milligrams per liter. Water samples from 9 of the wells and from all the springs had less than 500 milligrams per liter of dissolved solids. There are some long-term trends in the chemistry of water samples from 7 wells having more than 10 years of data and from 2 springs. Rough Rock PM5, Keams Canyon PM2, Second Mesa PM2, and Kayenta PM2 show an increasing trend in dissolved solids; Forest Lake NTUA1 and PWCC 2 show a decreasing trend in dissolved solids; and Kykostmovi PM2 shows a steady trend. Increasing trends in dissolved-solids and chloride concentrations were evident from the more than 11 years of data for 2 springs.

Hydrologic Contributions of Springs to the Logan River, Utah

NASA Astrophysics Data System (ADS)

Gooseff, M. N.; Evans, J.; Kolesar, P.; Lachmar, T.; Payn, R.

2005-05-01

The Logan River flows through a fractured karst watershed of the Bear River mountain range in northern Utah, and provides significant water supply to the city of Logan, Utah. Springs flowing into the Logan River are important sources of water after annual snowmelt has been exhausted. In this work, we present results from a year of monitoring water chemistry and stable isotopes (D, 18O, and 13C) in two major springs and in the Logan River upstream and downstream of the combined spring inputs. The two springs, DeWitt and Spring Hollow, flow into the river within 1.5 km of each other. Annual patterns of Si and Mg suggest a flushing pattern, with reduced concentrations during snowmelt, and increasing concentrations throughout baseflow recession, at all for sampling locations. Cl concentrations are likewise greatly depressed after the snowmelt pulse but afterward remain consistently low at all four sites. Stable isotope data show that spring water is generally more enriched in D and 18O than river water, with an enriching pattern throughout annual stream flow recession.

Assessment of ground water quality for drinking purpose, District Nainital, Uttarakhand, India.

PubMed

Jain, C K; Bandyopadhyay, A; Bhadra, A

2010-07-01

The ground water quality of District Nainital (Uttarakhand, India) has been assessed to see the suitability of ground water for drinking and irrigation applications. This is a two-part series paper and this paper examines the suitability of ground water including spring water for drinking purposes. Forty ground water samples (including 28 spring samples) were collected during pre- and post-monsoon seasons and analyzed for various water quality constituents. The hydrochemical and bacteriological data was analyzed with reference to BIS and WHO standards and their hydrochemical facies were determined. The concentration of total dissolved solids exceeds the desirable limit of 500 mg/L in about 10% of the samples, alkalinity values exceed the desirable limit of 200 mg/L in about 30% of the samples, and total hardness values exceed the desirable limit of 300 mg/L in 15% of the samples. However, no sample crosses the maximum permissible limit for TDS, alkalinity, hardness, calcium, magnesium, chloride, sulfate, nitrate, and fluoride. The concentration of chloride, sulfate, nitrate, and fluoride are well within the desirable limit at all the locations. The bacteriological analysis of the samples does not show any sign of bacterial contamination in hand pump and tube-well water samples. However, in the case of spring water samples, six samples exceed the permissible limit of ten coliforms per 100 ml of sample. It is recommended that water drawn from such sources should be properly disinfected before being used for drinking and other domestic applications. Among the metal ions, the concentration of iron and lead exceeds the permissible limit at one location whereas the concentration of nickel exceeds the permissible limit in 60 and 32.5% of the samples during pre- and post-monsoon seasons, respectively. The grouping of samples according to their hydrochemical facies indicates that majority of the samples fall in Ca-Mg-HCO(3) hydrochemical facies.

Seismo-volcanic monitoring at Furnas Volcano (Azores): radon (222Rn) concentration in groundwater

NASA Astrophysics Data System (ADS)

Silva, Catarina; Virgílio Cruz, José; Ferreira, Teresa; Viveiros, Fátima; Freire, Pedro; Allard, Patrick

2017-04-01

The Azores archipelago, located in the middle of the North Atlantic Ocean, is composed of nine volcanic islands that formed at the triple junction of the North American, Eurasian and African (Nubian) tectonic plates. These volcanic islands were the sites of several eruptions and destructive earthquakes since human settlement in the 15th century. S. Miguel Island, the largest and most densely populated island of the Azores, hosts three active strato-volcanoes with calderas. Furnas Volcano is one of these. Its eruptive activity has been essentially explosive, involving magmas with trachytic (s.l.) composition. In the last 5000 years at least 10 explosive eruptions occurred inside the caldera of Furnas. The last one occurred in 1630 and was subplinian in character. Since then an intense hydrothermal activity has persisted, involving four main fumarolic fields, thermal springs, CO2-rich springs, several soil diffuse degassing areas (CO2 and 222Rn), as well as occasional hydrothermal explosions. In the past decade we have developed a radon survey of Furnas hydrothermal manifestations. Here we report on the radon survey of twelve water springs, located inside the caldera, and representative of the different water types encountered at the volcano (orthothermal, thermal and CO2-rich springs). Bimonthly sampling and determination of radon activity and water temperature was performed in the selected springs between years 2007 and 2011. At each sampling point two water samples were collected for radon dosing in laboratory with the RAD7 equipment. A decay correction was applied to each sample. The average radon activities were found to vary between 1.15 Bq/L and 29.77 Bq/L, while water temperatures ranged between 16.5 °C and 76.2 °C. As a whole radon activities inversely correlate with water temperature, with orthothermal springs showing higher radon activity than thermal springs. Temporal variations in both parameters appear to be mainly determined by seasonal variations of environmental conditions as soil temperature, rainfall and soil water content, rather than by volcanic activity, with the exception of one spring where radon activity seems to change more closely relate to the seismic activity of Furnas Volcano. Because some of the surveyed waters are often drunk by the local population and tourists, our results are also useful in a public health perspective. We conclude that the measured radon activities do not pose any health problem, as they remain under the safety threshold (100 Bq/L) defined by the World Health Organization. The research performed allowed to define the radon background for each one of the groundwater discharges sampled and to identify the environmental parameters that can influence the radon concentration in the groundwater of Furnas Volcano, allowing more easily to identify a future reactivation of this volcanic system.

Surveillance of Vittaforma corneae in hot springs by a small-volume procedure.

PubMed

Chen, Jung-Sheng; Hsu, Tsui-Kang; Hsu, Bing-Mu; Huang, Tung-Yi; Huang, Yu-Li; Shaio, Men-Fang; Ji, Dar-Der

2017-07-01

Vittaforma corneae is an obligate intracellular fungus and can cause human ocular microsporidiosis. Although accumulating reports of V. corneae causing keratoconjunctivitis in both healthy and immunocompromised persons have been published, little is known about the organism's occurrence in aquatic environments. Limitations in detection sensitivity have meant a large sampling volume is required to detect the pathogen up to now, which is problematic. A recent study in Taiwan has shown that some individuals suffering from microsporidial keratitis (MK) were infected after exposure to the pathogen at a hot spring. As a consequence of this, a survey and analysis of environmental V. corneae present in hot springs became an urgent need. In this study, sixty water samples from six hot spring recreation areas around Taiwan were analyzed. One liter of water from each sample site was filtered to harvest the fungi. The positive samples were detected using a modified nested PCR approach followed by sequencing using specific SSU rRNA gene primer pairs for V. corneae. In total fifteen V. corneae-like isolates were identified (25.0% of sites). Among them, six isolates, which were collected from recreational areas B, C and D, were highly similar to known V. corneae keratitis strains from Taiwan and other countries. Furthermore, five isolates, which were collected from recreation areas A, C, E and F, were very similar to Vittaforma-like diarrhea strains isolated in Portugal. Cold spring water tubs and public foot bath pools had the highest detection rate (50%), suggesting that hot springs might be contaminated via untreated water sources. Comparing the detection rate across different regions of Taiwan, Taitung, which is in the east of the island, gave the highest positive rate (37.5%). Statistical analysis showed that outdoor/soil exposure and a high heterotrophic plate count (HPC) were risk factors for the occurrence of V. corneae. Our findings provide empirical evidence supporting the need for proper control and regulations at hot spring recreational waters in order to avoid health risks from this pathogen. Finally, we have developed a small volume procedure for detecting V. corneae in water samples and this has proved to be very useful. Copyright © 2017 Elsevier Ltd. All rights reserved.

Ground-water data in the Baker County-northern Malheur County area, Oregon

USGS Publications Warehouse

Collins, C.A.

1979-01-01

Ground-water data for the Baker County-northern Malheur area, Oregon, are tabulated for the Bureau of Land Management. The data include well and spring records, a well-location map, drillers ' logs of wells, observation-well hydrographs, and chemical analyses of ground-water samples. The reported yields of wells and springs in the area ranged from less than 1 to 2 ,500 gallons per minute. Dissolved solids in ground-water samples ranged from 50 to 1,587 milligrams per liter, and arsenic ranged from 0.001 to 0.317 milligrams per liter. (Woodard-USGS)

Reconnaissance of surface-water and ground-water quality at the Lincoln Boyhood National Memorial near Lincoln City, Indiana, 2001-02

USGS Publications Warehouse

Buszka, Paul M.; Fowler, Kathleen K.

2005-01-01

In cooperation with the National Park Service, the U.S. Geological Survey investigated water quality of key water bodies at the Lincoln Boyhood National Memorial near Lincoln City in southwestern Indiana. The key water bodies were a stock pond, representing possible nonpoint agricultural effects on water quality; an ephemeral stream, representing the water quality of drainage from forested areas of the park; parking-lot runoff, representing water quality related to roads and parking lots; an unnamed ditch below the parking lot, representing the water quality of drainage from the parking lot and from an adjacent railroad track; and Lincoln Spring, a historical ground-water source representing ground-water conditions near a former diesel-fuel-spill site along a rail line. Water samples were analyzed for pH, temperature, specific conductance, and dissolved oxygen and for concentrations of selected major ions and trace metals, nutrients, organic constituents, and Escherichia coli bacteria. Surface-water-quality data of water samples from the park represent baseline conditions for the area in relation to the data available from previous studies of area streams. Specific-conductance values and concentrations of most major ions and various nutrients in surface-water samples from the park were smaller than those reported for samples collected in other USGS studies in areas adjacent to the park. Water-quality-management issues identified by this investigation include potentially impaired water quality from parking-lot runoff, unknown effects on surface-water quality from adjacent railroads, and the potential impairment of water quality in Lincoln Spring from human influences. Parking-lot runoff is a source of calcium, alkalinity, iron, lead, and organic carbon in the water samples from the unnamed ditch. Detection of small concentrations of petroleum hydrocarbons in water from Lincoln Spring could indicate residual contamination from a 1995 diesel-fuel spill and cleanup. The concentration of nitrite plus nitrate in water from Lincoln Spring was 16.5 milligrams per liter as nitrogen, greater than the State of Indiana standard for nitrate in drinking water (10 milligrams per liter as nitrogen). Lead concentrations in samples from the stock pond, parking-lot runoff, and the unnamed ditch exceeded the Indiana chronic aquatic criteria.

Noble gas isotopes in mineral springs and wells within the Cascadia forearc, Washington, Oregon, and California

USGS Publications Warehouse

McCrory, Patricia A.; Constantz, James E.; Hunt, Andrew G.

2017-01-31

IntroductionThis U.S. Geological Survey report presents laboratory analyses along with field notes for an exploratory study to document the relative abundance of noble gases in mineral springs and water wells within the Cascadia forearc of Washington, Oregon, and California (fig. 1). This report describes 14 samples collected in 2014 and 2015 and complements a previous report that describes 9 samples collected in 2012 and 2013 (McCrory and others, 2014b). Estimates of the depth to the underlying Juan de Fuca oceanic plate beneath sample sites are derived from the McCrory and others (2012) slab model. Some of the springs have been previously sampled for chemical analyses (Mariner and others, 2006), but none of the springs or wells currently has publicly available noble gas data. The helium and neon isotope values and ratios presented below are used to determine the sources and mixing history of these mineral and well waters (for example, McCrory and others, 2016).

Physical and hydrochemical evidence of lake leakage near Jim Woodruff lock and dam and ground-water inflow to Lake Seminole, and an assessment of karst features in and near the lake, southwestern Georgia and northwestern Florida

USGS Publications Warehouse

Torak, Lynn J.; Crilley, Dianna M.; Painter, Jaime A.

2006-01-01

Hydrogeologic data and water-chemistry analyses indicate that Lake Seminole leaks into the Upper Floridan aquifer near Jim Woodruff Lock and Dam, southwestern Georgia and northwestern Florida, and that ground water enters Lake Seminole along upstream reaches of the lake's four impoundment arms (Chattahoochee and Flint Rivers, Spring Creek, and Fishpond Drain). Written accounts by U.S. Army Corps of Engineers geologists during dam construction in the late 1940s and early 1950s, and construction-era photographs, document karst-solution features in the limestone that comprise the lake bottom and foundation rock to the dam, and confirm the hydraulic connection of the lake and aquifer. More than 250 karst features having the potential to connect the lake and aquifer were identified from preimpoundment aerial photographs taken during construction. An interactive map containing a photomosaic of 53 photographic negatives was orthorectfied to digital images of 1:24,000-scale topographic maps to aid in identifying karst features that function or have the potential to function as locations of water exchange between Lake Seminole and the Upper Floridan aquifer. Some identified karst features coincide with locations of mapped springs, spring runs, and depressions that are consistent with sinkholes and sinkhole ponds. Hydrographic surveys using a multibeam echosounder (sonar) with sidescan sonar identified sinkholes in the lake bottom along the western lakeshore and in front of the dam. Dye-tracing experiments indicate that lake water enters these sinkholes and is transported through the Upper Floridan aquifer around the west side of the dam at velocities of about 500 feet per hour to locations where water 'boils up' on land (at Polk Lake Spring) and in the channel bottom of the Apalachicola River (at the 'River Boil'). Water discharging from Polk Lake Spring joins flow from a spring-fed ground-water discharge zone located downstream of the dam; the combined flow disappears into a sinkhole located on the western floodplain of the river and is transmitted through the Upper Floridan aquifer, eventually discharging to the Apalachicola River at the River Boil. Acoustic Doppler current profiling yielded flow estimates from the River Boil in the range from about 140 to 220 cubic feet per second, which represents from about 1 to 3 percent of the average daily flow in the river. Binary mixing-model analysis using naturally occurring isotopes of oxygen and hydrogen (oxygen-18 and deuterium) indicates that discharge from the River Boil consists of a 13-to-1 ratio of lake water to ground water and that other sources of lake leakage and discharge to the boil probably exist. Analyses of major ions, nutrients, radon-222, and stable isotopes of hydrogen and oxygen contained in water samples collected from 29 wells, 7 lake locations, and 5 springs in the Lake Seminole area during 2000 indicate distinct chemical signatures for ground water and surface water. Ground-water samples contained higher concentrations of calcium and magnesium, and higher alkalinity and specific conductance than surface-water samples, which contained relatively high concentrations of total organic carbon and sulfate. Solute and isotopic tracers indicate that, from May to October 2000, springflow exhibited more ground-water qualities (high specific conductance, low dissolved oxygen, and low temperature) than surface water; however, the ratio of ground water to surface water of the springs was difficult to quantify from November to April because of reduced springflow and rapid mixing of springflow and lake water during sampling. The saturation index of calcite in surface-water samples indicates that while surface water is predominately undersaturated with regard to calcite year-round, a higher potential for dissolution of the limestone matrix exists from late fall through early spring than during summer. The relatively short residence time (5-7 hours) and rapid flow velocity

Concentrations of nutrients, pesticides, and suspended sediment in the karst terrane of the Sinking Creek basin, Kentucky, 2004

USGS Publications Warehouse

Crain, Angela S.

2006-01-01

Water samples were collected in streams and springs in the karst terrane of the Sinking Creek Basin in 2004 as part of study in cooperation with the Kentucky Department of Agriculture. A total of 48 water samples were collected at 7 sites (4 springs, 2 streams, and 1 karst window) from April through November 2004. The karst terrane of the Sinking Creek Basin (also known as Boiling Spring Basin) encompasses about 125 square miles in Breckinridge County and portions of Meade and Hardin Counties in Kentucky. Fourteen pesticides were detected of the 52 pesticides analyzed in the stream and spring samples. Of the 14 detected pesticides, 12 were herbicides and 2 were insecticides. The most commonly detected pesticides?atrazine, simazine, metolachlor, and acetochlor?were those most heavily used on crops during the study. Atrazine was detected in 100 percent of all samples; simazine, metolachlor, and acetochlor were detected in more than 35 percent of all samples. The pesticide-transformation compound, deethylatrazine, was detected in 98 percent of the samples. Only one nonagricultural herbicide, prometon, was detected in more than 30 percent of the samples. Malathion, the most commonly detected insecticide, was found in 4 percent of the samples, which was followed by carbofuran (2 percent). Most of the pesticides were present in low concentrations; however, atrazine was found in springs exceeding the U.S. Environmental Protection Agency?s (USEPA) standards for drinking water. Atrazine exceeded the USEPA?s maximum contaminant level 2 times in 48 detections. Concentrations of nitrate greater than 10 milligrams per liter (mg/L) were not found in water samples from any of the sites. Concentrations of nitrite plus nitrate ranged from 0.21 to 3.9 mg/L at the seven sites. The median concentration of nitrite plus nitrate for all sites sampled was 1.5 mg/L. Concentrations of nitrite plus nitrate generally were higher in the springs than in the main stem of Sinking Creek. Forty-two percent of the concentrations of total phosphorus at all seven sites exceeded the USEPA?s recommended maximum concentration of 0.1 mg/L. The median concentration of total phosphorus for all sites sampled was 0.09 mg/L. The highest median concentrations of total phosphorus were found in the springs. Median concentrations of orthophosphate followed the same pattern as concentrations of total phosphorus in the springs. Concentrations of orthophosphate ranged from <0.006 to 0.192 mg/L. Concentrations of suspended sediment generally were low throughout the basin; the median concentration of suspended sediment for all sites sampled was 23 mg/L. The highest concentration of suspended sediment (1,486 mg/L) was measured following a storm event at Sinking Creek near Lodiburg, Ky.

Water-quality data for Walnut Canyon and Wupatki National Monuments, Arizona, 2001-02

USGS Publications Warehouse

Thomas, Blakemore E.

2003-01-01

Water-quality data are provided for four sites in Walnut Canyon and Wupatki National Monuments in north-central Arizona. These data describe the current water quality and provide baseline water-quality information for monitoring future trends. Water samples were collected from a ground-water seep and well in Walnut Canyon and from a spring and a river in Wupatki during September 2001 to September 2002. Water from the four sites is from four different sources. In Walnut Canyon, Cherry Canyon seep is in a shallow local aquifer, and the Little Colorado River contains ground-water discharge from several aquifers and runoff from a 22,000 square-mile drainage area. Concentrations of dissolved solids were similar within the two monuments; the range for water samples from Walnut Canyon was 203 to 248 milligrams per liter, and the range for water samples from Wupatki was 503 to 614 milligrams per liter. Concentrations of trace elements were generally low in water samples from the three ground-water sites--Cherry Canyon seep, Walnut Canyon headquarters well, and Heiser Spring. The water sample collected from the Little Colorado River, however, had high concentrations of aluminum (4,020 micrograms per liter), antimony (54 micrograms per liter), arsenic (14.3 micrograms per liter), and iron (749 micrograms per liter) relative to U.S. Environmental Protection Agency Primary and Secondary Maximum Contaminant Levels. Concentrations of nitrate (as nitrogen) in water samples from the four sites were generally low (0.11 to 1.8 milligrams per liter) and are within the upper 25 percent of nitrate concentrations measured in the regional aquifer near Flagstaff in 1996 and 1997. Water samples from Cherry Canyon seep, Heiser Spring, and the Little Colorado River contained total coliform bacteria. Fecal coliform and Escherichia coli bacteria were found in water samples from Cherry Canyon seep and the Little Colorado River.

Hydrologic data for the Weldon Spring radioactive waste-disposal sites, St. Charles County, Missouri; 1984-1986

USGS Publications Warehouse

Kleeschulte, M.J.; Emmett, L.F.; Barks, J.H.

1986-01-01

Hydrologic and water quality data were collected during an investigation of the Weldon Spring radioactive waste disposal sites and surroundings area in St. Charles County, Missouri, from 1984 to 1986. The data consists of water quality analyses of samples collected from 45 groundwater and 27 surface water sites. This includes analyses of water from four raffinate pits and from the Weldon Spring quarry. Also included in the report are the results of a seepage run on north flowing tributaries to Dardenne Creek from Kraut Run to Crooked Creek. Mean daily discharge from April 1985 to April 1986 is given for two springs located about 1.5 mi north of the chemical plant. (USGS)

Determination of groundwater travel time in a karst aquifer by stable water isotopes, Tanour and Rasoun spring (Jordan)

NASA Astrophysics Data System (ADS)

Hamdan, Ibraheem; Wiegand, Bettina; Sauter, Martin; Ptak, Thomas

2016-04-01

Key words: karst aquifers, stable isotopes, water travel time, Jordan. Tanour and Rasoun karst springs are located about 75 kilometers northwest of the city of Amman in Jordan. The aquifer is composed of Upper Cretaceous limestone that exhibits a moderate to high degree of karstification. The two springs represent the main drinking water resources for the surrounding villages. The yearly water production is about 1,135,000 m3/yr for Tanour spring and 125,350 m3/yr for Rasoun spring (MWI 2015). Due to contamination from microbiological pollution (leakage of wastewater from septic tanks) or infiltration of wastewater from local olive presses, drinking water supply from the two springs is frequently interrupted. From November 2014 through March 2015, spring water samples were collected from Tanour and Rasoun spring for the analysis of stable hydrogen and oxygen isotopes to investigate spring response to precipitation and snowmelt events. Both Tanour and Rasoun spring show a fast response to precipitation and snowmelt events, implying short water travel times. Based on the variation of δ 18O and δ 2H in spring discharge, the average maximum water travel time is in the order of 8 days for Tanour spring and 6 days for Rasoun spring. Due to fast water travel times, Tanour and Rasoun spring can be considered as highly vulnerable to pollutants. δ 18O and δ 2H values of Tanour and Rasoun springs parallel other monitored parameter like water temperature, turbidity, electrical conductivity and spring discharge. In addition, a high turbidity peak was monitored in Tanour spring during a pollution event from olive mills wastewater (Hamdan et al., 2016; Hamdan, in prep.). The fast response in both Tanour and Rasoun springs to precipitation events requires monitoring potential sources of pollution within the catchment area. References: MWI (Ministry of Water and Irrigation) (2015) Monthly Production values for Tanour and Rasoun Springs for the time period between 1996 and 2014. Water Information System, National Master Plan Directorate. Jordan. Hamdan I., Wiegand B., Toll M., Sauter M. (2016) Spring response to precipitation events using δ 18O and δ 2H in the Tanour catchment, NW-Jordan. Isotopes in Environmental and Health Studies journal. Accepted GIEH-2015-0139. Hamdan, I.~in preparation.~Characterization of groundwater flow and vulnerability assessment of karstic aquifer - A case study from Tanour and Rasoun spring catchment (Ajloun, NW-Jordan).~Ph.D. Thesis, University of Göttingen, Germany.

Using chemical and microbiological indicators to track the impacts from the land application of treated municipal wastewater and other sources on groundwater quality in a karstic springs basin

NASA Astrophysics Data System (ADS)

Katz, Brian G.; Griffin, Dale W.

2008-08-01

Multiple chemical constituents (nutrients; N, O, H, C stable isotopes; 64 organic wastewater compounds, 16 pharmaceutical compounds) and microbiological indicators were used to assess the impact on groundwater quality from the land application of approximately 9.5 million liters per day of treated municipal sewage effluent to a sprayfield in the 960-km2 Ichetucknee Springs basin, northern Florida. Enriched stable isotope signatures (δ18O and δ2H) were found in water from the effluent reservoir and a sprayfield monitoring well (MW-7) due to evaporation; however, groundwater samples downgradient from the sprayfield have δ18O and δ2H concentrations that represented recharge of meteoric water. Boron and chloride concentrations also were elevated in water from the sprayfield effluent reservoir and MW-7, but concentrations in groundwater decreased substantially with distance downgradient to background levels in the springs (about 12 km) and indicated at least a tenfold dilution factor. Nitrate-nitrogen isotope (δ15N NO3) values above 10 ‰ in most water samples were indicative of organic nitrogen sources except Blue Hole Spring (δ15N NO3 = 4.6 4.9 ‰), which indicated an inorganic source of nitrogen (fertilizers). The detection of low concentrations the insect repellent N, N-diethyl-metatoluamide (DEET), and other organic compounds associated with domestic wastewater in Devil’s Eye Spring indicated that leakage from a nearby septic tank drainfield likely has occurred. Elevated levels of fecal coliforms and enterococci were found in Blue Hole Spring during higher flow conditions, which likely resulted from hydraulic connections to upgradient sinkholes and are consistent with previoius dye-trace studies. Enteroviruses were not detected in the sprayfield effluent reservoir, but were found in low concentrations in water samples from a downgradient well and Blue Hole Spring during high-flow conditions indicating a human wastewater source. The Upper Floridan aquifer in the Ichetucknee Springs basin is highly vulnerable to contamination from multiple anthropogenic sources throughout the springs basin.

Using chemical and microbiological indicators to track the impacts from the land application of treated municipal wastewater and other sources on groundwater quality in a karstic springs basin

USGS Publications Warehouse

Katz, B.G.; Griffin, Dale W.

2008-01-01

Multiple chemical constituents (nutrients; N, O, H, C stable isotopes; 64 organic wastewater compounds, 16 pharmaceutical compounds) and microbiological indicators were used to assess the impact on groundwater quality from the land application of approximately 9.5 million liters per day of treated municipal sewage effluent to a sprayfield in the 960-km2 Ichetucknee Springs basin, northern Florida. Enriched stable isotope signatures (?? 18O and ??2H) were found in water from the effluent reservoir and a sprayfield monitoring well (MW-7) due to evaporation; however, groundwater samples downgradient from the sprayfield have ??18O and ??2H concentrations that represented recharge of meteoric water. Boron and chloride concentrations also were elevated in water from the sprayfield effluent reservoir and MW-7, but concentrations in groundwater decreased substantially with distance downgradient to background levels in the springs (about 12 km) and indicated at least a tenfold dilution factor. Nitrate-nitrogen isotope (??15N-NO3) values above 10 ??? in most water samples were indicative of organic nitrogen sources except Blue Hole Spring (??15N-NO3 = 4.6-4.9 ???), which indicated an inorganic source of nitrogen (fertilizers). The detection of low concentrations the insect repellent N,N-diethyl-metatoluamide (DEET), and other organic compounds associated with domestic wastewater in Devil's Eye Spring indicated that leakage from a nearby septic tank drainfield likely has occurred. Elevated levels of fecal coliforms and enterococci were found in Blue Hole Spring during higher flow conditions, which likely resulted from hydraulic connections to upgradient sinkholes and are consistent with previoius dye-trace studies. Enteroviruses were not detected in the sprayfield effluent reservoir, but were found in low concentrations in water samples from a downgradient well and Blue Hole Spring during high-flow conditions indicating a human wastewater source. The Upper Floridan aquifer in the Ichetucknee Springs basin is highly vulnerable to contamination from multiple anthropogenic sources throughout the springs basin. ?? 2007 Springer-Verlag.

Water-chemistry and on-site sulfur-speciation data for selected springs in Yellowstone National Park, Wyoming, 1994-1995

USGS Publications Warehouse

Ball, James W.; Nordstrom, D. Kirk; Cunningham, Kirk M.; Schoonen, Martin A.; Xu, Yong; DeMonge, Jennifer M.

1998-01-01

Forty-two water analyses are reported for samples collected at 8 hot springs and their overflow drainages, two geysers, and two ambient-temperature acid streams in Yellowstone National Park during 1994-95. These water samples were collected and analyzed as part of the initial research investigations on sulfur redox speciation in the hot springs of Yellowstone and to document chemical changes in overflows that affect major ions, redox species, and trace elements. The sulfur redox speciation research is a collaboration between the State University of New York (SUNY) at Stony Brook and the U.S. Geological Survey (USGS). Four hot springs, Ojo Caliente, Azure, Frying Pan, and Angel Terrace, were studied in detail. Analyses were performed adjacent to the sampling site or in an on-site mobile lab truck constructed by the USGS, or later in a USGS laboratory. Water temperature, specific conductance, pH, Eh, D.O., and dissolved H2S were determined adjacent to the sample source at the time of sampling. Alkalinity and F- were determined on-site on the day of sample collection. Thiosulfate and polythionates were determined as soon as possible (minutes to hours later) by ion chromatography (IC). Other major anions (Cl-, SO4 2-, Br-) also were determined on-site by IC within two days of sample collection. Ammonium, Fe(II), and Fe(total) were determined on-site by ultraviolet/visible spectrophotometry within two days of sample collection. Later in the USGS laboratory, densities were determined. Concentrations of Ca, Mg, Li, Na, and K were determined by flame atomic absorption and emission (Na, K) spectrometry. Concentrations of Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe(total), K, Mg, Mn, Na, Ni, Pb, Si, Sr, V, and Zn were determined by inductively-coupled plasma optical emission spectrometry. Trace concentrations of Al and Mg were determined by Zeeman-corrected graphite furnace atomic absorption spectrometry. Three important conclusions from the sampling and analyses are: (1) variability in H2S concentrations can be caused as much by sampling and preservation artifacts as by actual variations in water composition over time, (2) historical determinations of S2O3 2- were subject to overestimation, most likely because of inadequate preservation leading to H2S oxidation, and (3) S2O3 2- is a common constituent of hot spring waters.

Geochemical Investigation of the Arbuckle-Simpson Aquifer, South-Central Oklahoma, 2004-06

USGS Publications Warehouse

Christenson, Scott; Hunt, Andrew G.; Parkhurst, David L.

2009-01-01

A geochemical reconnaissance investigation of the Arbuckle-Simpson aquifer in south-central Oklahoma was initiated in 2004 to characterize the ground-water quality at an aquifer scale, to describe the chemical evolution of ground water as it flows from recharge areas to discharge in wells and springs, and to determine the residence time of ground water in the aquifer. Thirty-six water samples were collected from 32 wells and springs distributed across the aquifer for chemical analysis of major ions, trace elements, isotopes of oxygen and hydrogen, dissolved gases, and age-dating tracers. In general, the waters from wells and springs in the Arbuckle-Simpson aquifer are chemically suitable for all regulated uses, such as public supplies. Dissolved solids concentrations are low, with a median of 347 milligrams per liter (mg/L). Two domestic wells produced water with nitrate concentrations that exceeded the U.S. Environmental Protection Agency's nitrate maximum contaminant level (MCL) of 10 mg/L. Samples from two wells in the confined part of the aquifer exceeded the secondary maximum contaminant level (SMCL) for chloride of 250 mg/L and the SMCL of 500 mg/L for dissolved solids. Water samples from these two wells are not representative of water samples from the other wells and springs completed in the unconfined part of the aquifer. No other water samples from the Arbuckle-Simpson geochemical reconnaissance exceeded MCLs or SMCLs, although not every chemical constituent for which the U.S. Environmental Protection Agency has established a MCL or SMCL was analyzed as part of the Arbuckle-Simpson geochemical investigation. The major ion chemistry of 34 of the 36 samples indicates the water is a calcium bicarbonate or calcium magnesium bicarbonate water type. Calcium bicarbonate water type is found in the western part of the aquifer, which is predominantly limestone. Calcium magnesium bicarbonate water is found in the eastern part of the aquifer, which is predominantly a dolomite. The major ion chemistry for these 34 samples is consistent with a set of water-rock interactions. Rainfall infiltrates the soil zone, where the host rock, limestone or dolomite, dissolves as a result of uptake of carbon dioxide gas. Some continued dissolution of dolomite and precipitation of calcite occur as the water flows through the saturated zone. The major ion chemistry of the two samples from wells completed in the confined part of the aquifer indicates the water is a sodium chloride type. Geochemical inverse modeling determined that mixing of calcite-saturated recharge water with brine and dissolving calcite, dolomite, and gypsum accounts for the water composition of these two samples. One of the two samples, collected at Vendome Well in Chickasaw National Recreation Area, had a mixing fraction of brine of about 1 percent. The brine component of the sample at Vendome Well is likely to account for the relatively large concentrations of many of the trace elements (potassium, fluoride, bromide, iodide, ammonia, arsenic, boron, lithium, selenium, and strontium) measured in the water sample. Carbon-14, helium-3/tritium, and chlorofluorocarbons were used to calculate ground-water ages, recharge temperatures, and mixtures of ground water in the Arbuckle-Simpson aquifer. Thirty four of 36 water samples recharged the aquifer after 1950, indicating that water is moving quickly from recharge areas to discharge at streams and springs. Two exceptions to this classification were noted in samples 6 and 15 (Vendome Well). Ground-water ages determined for these two samples by using carbon-14 are 34,000 years (site 6) and 10,500 years (site 15). Concentrations of dissolved argon, neon, and xenon in water samples were used to determine the temperature of the water when it recharged the aquifer. The mean annual air temperature at Ada, Oklahoma, is 16 degrees Celsius (C) and the median temperature of the 30 reconnaissance water samples was 18.1 C. The av

Surveillance and evaluation of the infection risk of free-living amoebae and Legionella in different aquatic environments.

PubMed

Ji, Wen-Tsai; Hsu, Bing-Mu; Chang, Tien-Yu; Hsu, Tsui-Kang; Kao, Po-Min; Huang, Kuan-Hao; Tsai, Shiou-Feng; Huang, Yu-Li; Fan, Cheng-Wei

2014-11-15

Free-living amoebae (FLA) are ubiquitous in various aquatic environments. Several amoebae species are pathogenic and host other pathogens such as Legionella, but the presence of FLA and its parasites as well as the related infection risk are not well known. In this study, the presence of pathogenic FLA and Legionella in various water bodies was investigated. Water samples were collected from a river, intake areas of drinking water treatment plants, and recreational hot spring complexes in central and southern Taiwan. A total of 140 water samples were tested for the presence of Acanthamoeba spp., Naegleria spp., Vermamoeba vermiformis, and Legionella. In addition, phylogenetic characteristics and water quality parameters were also assessed. The pathogenic genotypes of FLA included Acanthamoeba T4 and Naegleria australiensis, and both were abundant in the hot spring water. In contrast, Legionella pneumophila was detected in different aquatic environments. Among the FLA assessed, V. vermiformis was most likely to coexist with Legionella spp. The total bacteria level was associated with the presence of FLA and Legionella especially in hot spring water. Taken together, FLA contamination in recreational hot springs and drinking water source warrants more attention on potential legionellosis and amoebae infections. Copyright © 2014. Published by Elsevier B.V.

Application of EMA-qPCR as a complementary tool for the detection and monitoring of Legionella in different water systems.

PubMed

Qin, Tian; Tian, Zhengan; Ren, Hongyu; Hu, Guangchun; Zhou, Haijian; Lu, Jinxing; Luo, Chengwang; Liu, Zunyu; Shao, Zhujun

2012-05-01

Legionella are prevalent in human-made water systems and cause legionellosis in humans. Conventional culturing and polymerase chain reaction (PCR) techniques are not sufficiently accurate for the quantitative analysis of live Legionella bacteria in water samples because of the presence of viable but nonculturable cells and dead cells. Here, we report a rapid detection method for viable Legionella that combines ethidium monoazide (EMA) with quantitative real-time PCR (qPCR) and apply this method to detect Legionella in a large number of water samples from different sources. Results yielded that samples treated with 5 μg/ml EMA for 10 min and subsequently exposed to light irradiation for 5 min were optimal for detecting Legionella. EMA treatment before qPCR could block the signal from approximately 4 log(10) of dead cells. When investigating environmental water samples, the percent-positive rate obtained by EMA-qPCR was significantly higher than conventional PCR and culture methods, and slightly lower than qPCR. The bacterial count of Legionella determined by EMA-qPCR were mostly greater than those determined by culture assays and lower than those determined by qPCR. Acceptable correlations were found between the EMA-qPCR and qPCR results for cooling towers, piped water and hot spring water samples (r = 0.849, P < 0.001) and also found between the EMA-qPCR and culture results for hot spring water samples (r = 0.698, P < 0.001). The results indicate that EMA-qPCR could be used as a complementary tool for the detection and monitoring of Legionella in water systems, especially in hot spring water samples.

Estimating the input of wastewater-born micropollutants in a rural karst catchment (Gallusquelle, Germany)

NASA Astrophysics Data System (ADS)

Zirlewagen, Johannes; Hillebrand, Olav; Nödler, Karsten; Schiperski, Ferry; Scheytt, Traugott; Licha, Tobias

2013-04-01

The main focus of the AGRO research project is on the use of various micropollutants as indicators (e.g. for wastewater) in the catchment of the karst spring Gallusquelle, Swabian Alb. For modeling the micropollutants' fate in the subsurface and their occurrence in spring water, reliable estimates of the spatio-temporal input, i.e. input functions, are crucial. Therefore potential sources for wastewater-born substances are identified. These are the combined sewer system with a stormwater retention basin (untreated wastewater) and the river Fehla (treated wastewater). The micropollutants' concentrations and loads in the potentially infiltrating waters are estimated on the one hand by local water and substance consumption data and on the other hand by water sample analysis and stream gauging. The spring's discharge varies from 0.2-2.0 m³/s with an average of 0.5 m³/s. Treated spring water serves as drinking water for 45 000 people. The catchment area measures 45 km² and is rural in character with 55% forest, 27% grassland, 15% agriculture and 3% residential/industrial. Industrial activity is restricted to a few minor textile and metal works. There are around 4 000 inhabitants and except for a few farms, all households are connected to the public sewer system. The only surface water within the catchment is the stream Fehla, which forms a part of the catchment boundary. It was formerly identified as a sinking stream with an ephemeral part in the lower course. Connections to the Gallusquelle spring were proven by several tracer tests conducted in the 1960's, when the river started to become perennial over the whole course due to heavy colmatation. During a one week campaign, samples of wastewater and river water were taken three times per day. Additionally, hourly samples were taken during a 24 h period. Water samples were analysed for major ions and 58 micropollutants, including pharmaceuticals, stimulants (as caffeine), the artificial sweeteners acesulfame and cyclamate, contrast media, corrosion inhibitors, pesticides and metabolites of several substances. For analysis of micropollutants, water samples were spiked with internal standards before solid-phase-extraction (SPE) and the analysis was conducted by high-performance liquid chromatographic separation with tandem mass spectrometric detection (HPLC/MS-MS). Quantification limits were in the range of 1-28 ng/l for river water and 200-650 ng/l for untreated wastewater. Once the concentrations and loads of micropollutants in the infiltrating waters are known and compared to those in the spring water, one might distinguish and quantify the portions of water infiltrating from the different sources in the catchment area.

Discharge, water temperature, and water quality of Warm Mineral Springs, Sarasota County, Florida: A retrospective analysis

USGS Publications Warehouse

Metz, Patricia A.

2016-09-27

Warm Mineral Springs, located in southern Sarasota County, Florida, is a warm, highly mineralized, inland spring. Since 1946, a bathing spa has been in operation at the spring, attracting vacationers and health enthusiasts. During the winter months, the warm water attracts manatees to the adjoining spring run and provides vital habitat for these mammals. Well-preserved late Pleistocene to early Holocene-age human and animal bones, artifacts, and plant remains have been found in and around the spring, and indicate the surrounding sinkhole formed more than 12,000 years ago. The spring is a multiuse resource of hydrologic importance, ecological and archeological significance, and economic value to the community.The pool of Warm Mineral Springs has a circular shape that reflects its origin as a sinkhole. The pool measures about 240 feet in diameter at the surface and has a maximum depth of about 205 feet. The sinkhole developed in the sand, clay, and dolostone of the Arcadia Formation of the Miocene-age to Oligocene-age Hawthorn Group. Underlying the Hawthorn Group are Oligocene-age to Eocene-age limestones and dolostones, including the Suwannee Limestone, Ocala Limestone, and Avon Park Formation. Mineralized groundwater, under artesian pressure in the underlying aquifers, fills the remnant sink, and the overflow discharges into Warm Mineral Springs Creek, to Salt Creek, and subsequently into the Myakka River. Aquifers described in the vicinity of Warm Mineral Springs include the surficial aquifer system, the intermediate aquifer system within the Hawthorn Group, and the Upper Floridan aquifer in the Suwannee Limestone, Ocala Limestone, and Avon Park Formation. The Hawthorn Group acts as an upper confining unit of the Upper Floridan aquifer.Groundwater flow paths are inferred from the configuration of the potentiometric surface of the Upper Floridan aquifer for September 2010. Groundwater flow models indicate the downward flow of water into the Upper Floridan aquifer in inland areas, and upward flow toward the surface in coastal areas, such as at Warm Mineral Springs. Warm Mineral Springs is located in a discharge area. Changes in water use in the region have affected the potentiometric surface of the Upper Floridan aquifer. Historical increase in groundwater withdrawals resulted in a 10- to 20-foot regional decline in the potentiometric surface of the Upper Floridan aquifer by May 1975 relative to predevelopment levels and remained at approximately that level in May 2007 in the area of Warm Mineral Springs. Discharge measurements at Warm Mineral Springs (1942–2014) decreased from about 11–12 cubic feet per second in the 1940s to about 6–9 cubic feet per second in the 1970s and remained at about that level for the remainder of the period of record. Similarity of changes in regional water use and discharge at Warm Mineral Springs indicates that basin-scale changes to the groundwater system have affected discharge at Warm Mineral Springs. Water temperature had no significant trend in temperature over the period of record, 1943–2015, and outliers were identified in the data that might indicate inconsistencies in measurement methods or locations.Within the regional groundwater basin, Warm Mineral Springs is influenced by deep Upper Floridan aquifer flow paths that discharge toward the coast. Associated with these flow paths, the groundwater temperatures increase with depth and toward the coast. Multiple lines of evidence indicate that a source of warm groundwater to Warm Mineral Springs is likely the permeable zone of the Avon Park Formation within the Upper Floridan aquifer at a depth of about 1,400 to 1,600 feet, or deeper sources. The permeable zone contains saline groundwater with water temperatures of at least 95 degrees Fahrenheit.The water quality of Warm Mineral Springs, when compared with other springs in Florida had the highest temperature and the greatest mineralized content. Warm Mineral Springs water is characterized by a slight-green color, with varying water clarity, low dissolved oxygen (indicative of deep groundwater), and a hydrogen sulfide odor. Water-quality samples detected ammonium-nitrogen and nitrates, but at low concentrations. The drinking water standard for nitrate adopted by the U.S. Environmental Protection Agency is 10 milligrams per liter, measured as nitrogen. Water samples collected at spring vents by divers on April 29, 2015, had concentrations of 0.9 milligram per liter nitrate-nitrogen at vent A and 0.04–0.05 milligram per liter at vents B, C, and D. Typically, the water clarity is highest in the morning (about 30 feet Secchi depth) and often decreases throughout the day.Analysis of existing data provided some insight into the hydrologic processes affecting Warm Mineral Springs; however, data have been sparsely and discontinuously collected since the 1940s. Continuous monitoring of hydrologic characteristics such as discharge, water temperature, specific conductance, and water-quality indicators, such as nitrate and turbidity (water clarity), would be valuable for monitoring and development of models of spring discharge and water quality. In addition, water samples could be analyzed for isotopic tracers, such as strontium, and the results used to identify and quantify the sources of groundwater that discharge at Warm Mineral Springs. Groundwater flow/transport models could be used to evaluate the sensitivity of the quality and quantity of water flowing from Warm Mineral Springs to changes in climate, aquifer levels, and water use.

Bacterial Activity and Geochemical Reactions in Submerged Cave Development -- Impact on Karst Aquifers in Florida

NASA Astrophysics Data System (ADS)

Herman, J. S.; Franklin, R. B.; Mills, A. L.; Giannotti, A. L.; Tysall, T. N.

2008-05-01

Elucidation of coupled mechanisms of sulfide oxidation and biomass generation supports an improved understanding the driving forces behind acid production, calcite dissolution, cave development, and karst aquifers characterization. Wekiwa Springs Cave and DeLeon Springs Cave, located in central Florida, both contain prolific bacterial mats from which sulfur-oxidizing bacteria have been identified. Wekiwa Springs Cave, a submerged cave developed in the Hawthorne Formation and located near Orlando, Florida, has groundwater discharge from the Floridian aquifer system, with some contribution from surficial and intermediate aquifers. The spring is the headwater of the Wekiwa River and releases a total of 170,000 m3 of water per day. The ceiling and walls are heavily covered (10 cm thick) with three morphologically distinct types of microbial mats largely comprising sulfur-oxidizing bacteria. Analysis of nearby groundwater collected from wells confirms sulfide concentrations in the regional groundwater of ~ 1.5 mg/L, though sulfide concentrations for water collected in the cave are below detection. Dissolved oxygen concentration in the water is low (<0.5 mg/L). DeLeon Springs Cave, a submerged cave located in Volusia County, Florida, is a single conduit with an average discharge of ~ 70,000 m3 of water per day, and water chemistry data suggest the presence of a saline seep in the system. Dense microbial mats cover the rock surfaces of the cave; the mats are highly filamentous, with long white streamers that often extend 1-2 feet from the cave wall. Microscopic analysis has confirmed the presence of sulfur granules within these bacterial cells, similar to those observed in the Wekiwa cave organisms. The water chemistry in DeLeon Springs Cave, however, is distinct from that of Wekiwa Springs Cave. Though DO, Fetotal, and HS- values are similar for the two sites, the concentration of ions such as Cl-, Na+, and SO42- are considerably higher at DeLeon. A similar contrast exists for the other major cations (Ca2+, Mg2+, K+), although the difference is less pronounced. An important difference between the two cave systems is the considerable spatial variability associated with water chemistry along the flowpath in the DeLeon system, whereas water chemistry is fairly constant at all locations sampled in Wekiwa Springs Cave. Microbial communities were characterized based on the on overall genetic similarity between whole-community DNA samples as compared using T-RFLP analysis of 16S rRNA genes. The microbial communities found at each sampling station in the Wekiwa Springs Cave are relatively similar to one another, while the communities found at the different sampling stations in the DeLeon Springs Cave are distinct from one another and from the Wekiwa community. This examination of submerged caves with respect to the specific speleogenic mechanisms and the importance of biological processes in their generation informs our understanding of caves and karst environments.

Prevalence and characterization of extended-spectrum beta-lactamase-producing Enterobacteriaceae in spring waters.

PubMed

Li, S; Zhu, Z C; Wang, L; Zhou, Y F; Tang, Y J; Miao, Z M

2015-12-01

The purpose of this study was to investigate the prevalence and characterization of extended-spectrum beta-lactamases (ESBL)-producing Enterobacteriaceae from spring waters in Mountain Tai of China. ESBL-producing Enterobacteriaceae were found in four out of 50 sampled spring waters (4/50, 8·0%) and a total of 16 non-duplicate ESBL-producing Enterobacteriaceae were obtained, including 13 Escherichia coli (E. coli) and three Klebsiella pneumoniae (Kl. pneumoniae). All 16 nonduplicate ESBL-producing Enterobacteriaceae isolates harboured genes encoding CTX-M ESBLs, among which six expressed CTX-M-15, five produced CTX-M-14, three produced CTX-M-55 and two expressed CTX-M-27. Four multilocus sequence types (ST) were found and ST131 was the dominant type (8/16, 50·0%). Taken together, the contamination of ESBL-producing Enterobacteriaceae were present in spring waters of Mountain Tai. The results indicated that spring waters could become a reservoir of antibiotic resistant bacteria and contribute to the spread of antimicrobial-resistant bacteria via drinking water or food chain. In addition, wastewater discharge of restaurants or hotels may be an important contribution source of antibiotic resistant bacteria in spring waters. © 2015 The Society for Applied Microbiology.

Ikaite precipitation by mixing of shoreline springs and lake water, Mono Lake, California, USA

NASA Astrophysics Data System (ADS)

Bischoff, James L.; Stine, Scott; Rosenbauer, Robert J.; Fitzpatrick, John A.; Stafford, Thomas W., Jr.

1993-08-01

Metastable ikaite (CaCO 3·6H 2O) forms abundantly during winter months along the south shoreline of Mono Lake where shoreline springs mix with lake water. Ikaite precipitates because of its decreased solubility at low temperature and because of orthophosphate-ion inhibition of calcite and aragonite. During the spring some of the ikaite is transformed to anhydrous CaCO 3 and is incorporated into tufa, but most is dispersed by wave action into the lake where it reacts to form gaylussite (Na 2Ca(CO 3) 2· 5H 2O). Spring waters have low pH values, are dominantly Ca-Na-HCO 3, have low radiocarbon activities, and are mixtures of deep-seated geothermal and cold groundwaters. Chemical modeling reveals that precipitation of CaCO 3 can occur over a broad range of mixtures of spring and lake water with a maximum production occurring at 96% spring water and 4% lake water. Under these conditions all the Ca and a significant fraction of the CO 3 of the precipitate is spring supplied. A radiocarbon age of 19,580 years obtained on a natural ikaite sample supports this conclusion. With the springs supplying a large and probably variable portion of the carbonate, and with apparent 14C age of the carbonate varying from spring to spring, tufa of similar actual antiquity may yield significantly different 14C dates, making tufa at this location unsuitable for absolute age dating by the radiocarbon method.

Ikaite precipitation by mixing of shoreline springs and lake water, Mono Lake, California, USA

USGS Publications Warehouse

Bischoff, J.L.; Stine, S.; Rosenbauer, R.J.; Fitzpatrick, J.A.; Stafford, Thomas W.

1993-01-01

Metastable ikaite (CaCO3??6H2O) forms abundantly during winter months along the south shoreline of Mono Lake where shoreline springs mix with lake water. Ikaite precipitates because of its decreased solubility at low temperature and because of orthophosphate-ion inhibition of calcite and aragonite. During the spring some of the ikaite is transformed to anhydrous CaCO3 and is incorporated into tufa, but most is dispersed by wave action into the lake where it reacts to form gaylussite (Na2Ca(CO3)2?? 5H2O). Spring waters have low pH values, are dominantly Ca-Na-HCO3, have low radiocarbon activities, and are mixtures of deep-seated geothermal and cold groundwaters. Chemical modeling reveals that precipitation of CaCO3 can occur over a broad range of mixtures of spring and lake water with a maximum production occurring at 96% spring water and 4% lake water. Under these conditions all the Ca and a significant fraction of the CO3 of the precipitate is spring supplied. A radiocarbon age of 19,580 years obtained on a natural ikaite sample supports this conclusion. With the springs supplying a large and probably variable portion of the carbonate, and with apparent 14C age of the carbonate varying from spring to spring, tufa of similar actual antiquity may yield significantly different 14C dates, making tufa at this location unsuitable for absolute age dating by the radiocarbon method. ?? 1993.

Bath water contamination with Legionella and nontuberculous mycobacteria in 24-hour home baths, hot springs, and public bathhouses of Nagano Prefecture, Japan.

PubMed

Kobayashi, Michiko; Oana, Kozue; Kawakami, Yoshiyuki

2014-01-01

Bath water samples were collected from 116 hot springs, 197 public bathhouses, and 38 24-hour home baths in Nagano Prefecture, Japan, during the period of April 2009 to November 2011, for determining the presence and extent of contamination with Legionella and nontuberculous mycobacteria. Cultures positive for Legionella were observed in 123 of the 3,314 bath water samples examined. The distribution and abundance of Legionella and/or combined contamination with Legionella and nontuberculous mycobacteria were investigated to clarify the contamination levels. The abundance of Legionella was demonstrated to correlate considerably with the levels of combined contamination with Legionella and nontuberculous mycobacteria. Legionella spp. were obtained from 61% of the water samples from 24-hour home baths, but only from 3% of the samples from public bathhouses and hot springs. This is despite the fact that a few outbreaks of Legionnaires' disease in Nagano Prefecture as well as other regions of Japan have been traced to bath water contamination. The comparatively higher rate of contamination of the 24-hour home baths is a matter of concern. It is therefore advisable to routinely implement good maintenance of the water basins, particularly of the 24-hour home baths.

Study on the TOC concentration in raw water and HAAs in Tehran's water treatment plant outlet.

PubMed

Ghoochani, Mahboobeh; Rastkari, Noushin; Nabizadeh Nodehi, Ramin; Mahvi, Amir Hossein; Nasseri, Simin; Nazmara, Shahrokh

2013-11-12

A sampling has been undertaken to investigate the variation of haloacetic acids formation and nature organic matter through 81 samples were collected from three water treatment plant and three major rivers of Tehran Iran. Changes in the total organic matter (TOC), ultraviolet absorbance (UV254), specific ultraviolet absorbance (SUVA) were measured in raw water samples. Haloacetic acids concentrations were monitored using a new static headspace GC-ECD method without a manual pre-concentration in three water treatment plants. The average concentration of TOC and HAAs in three rivers and three water treatment plants in spring, summer and fall, were 4, 2.41 and 4.03 mg/L and 48.75, 43.79 and 51.07 μg/L respectively. Seasonal variation indicated that HAAs levels were much higher in spring and fall.

Thermal Springs and the Search for Past Life on Mars

NASA Technical Reports Server (NTRS)

DesMarais, D. J.; Farmer, J. D.; Walter, M. R.

1995-01-01

Ancient thermal spring sites have several features which make them significant targets in a search for past life. Chemical (including redox) reactions in hydrothermal systems possibly played a role in the origin of life on Earth and elsewhere. Spring waters frequently contain reduced species (sulfur compounds, Fe(sup +2), etc.) which can provide chemical energy for organic synthesis. Relatively cool hydrothermal systems can sustain abundant microbial life (on Earth, at temperatures greater than 110 C). A spring site on Mars perhaps might even have maintained liquid water for periods sufficiently long to sustain surface-dwelling biota had they existed. On Earth, a variety of microbial mat communities can be sampled along the wide range of temperatures surrounding the spring, thus offering an opportunity to sample a broad biological diversity. Thermal spring waters frequently deposit minerals (carbonates, silica, etc.) which can entomb and preserve both fluid inclusions and microbial communities. These deposits can be highly fossiliferous and preserve biological inclusions for geologically long periods of time. Such deposits can cover several square km on Earth, and their distinctive mineralogy (e.g., silica- and/or carbonate-rich) can contrast sharply with that of the surrounding region. As with Martian volcanoes, Martian thermal spring complexes and their deposits might typically be much larger than their counterparts on Earth. Thus Martian spring deposits are perhaps readily detectable and even accessible. Elysium Planitia is an example of a promising region where hydrothermal activity very likely remobilized ground ice and sustained springs.

Sources and Chronology of Nitrate Contamination of Spring Waters: Integrating Science and Policy Decisions

NASA Astrophysics Data System (ADS)

Katz, B. G.; Stevenson, J. A.

2002-12-01

Human health and ecological concerns have arisen regarding spring waters in Florida as a steady increase in nitrate concentrations has been observed during the past 30 years. The extensive aesthetic, cultural, and recreational value of these springs, which also supply water for human consumption and support critical ecological habitats, could be threatened by the presence of nitrate. As part of the response to these concerns by the State of Florida, several research studies have used various chemical and isotopic tracers to determine sources of nitrate contamination and age of ground water discharging from springs. Since 1997, 60 water samples have been collected from 44 springs and analyzed for isotopic (15N, 3H/3He, 18O, 2H, 13C) and other chemical tracers (CFCs, major ions, dissolved gases, SF6). Delta 15N values of nitrate ranged from 2.6 to 12.9 per mil (median = 5.8 per mil) and indicated that nitrate in most spring waters originated from synthetic fertilizers. CFCs, 3H/3He, and SF6, used to estimate the residence time of ground water discharging from springs, indicated that spring-water ages ranged from 5 to 39 years. Concentrations of these multiple transient tracers are consistent with a two-component hydrologic model with mixtures of varying proportions of young water (less than 8 years) from the shallow part of the aquifer system and older water (20-50 years) from the deeper part of the flow system. Given residence times of 20-40 years for ground water discharging from most springs, it could take decades for nitrate concentrations to decrease to near background levels, even with immediate reductions in nitrogen inputs to the land surface. These research results are being used by the State of Florida to inform elected officials, water-resource mangers, and planners that decisions about land use today will affect the quality of ground water in springs for decades.

Phosphorus and nitrogen concentrations and loads at Illinois River south of Siloam Springs, Arkansas, 1997-1999

USGS Publications Warehouse

Green, W. Reed; Haggard, Brian E.

2001-01-01

Water-quality sampling consisting of every other month (bimonthly) routine sampling and storm event sampling (six storms annually) is used to estimate annual phosphorus and nitrogen loads at Illinois River south of Siloam Springs, Arkansas. Hydrograph separation allowed assessment of base-flow and surfacerunoff nutrient relations and yield. Discharge and nutrient relations indicate that water quality at Illinois River south of Siloam Springs, Arkansas, is affected by both point and nonpoint sources of contamination. Base-flow phosphorus concentrations decreased with increasing base-flow discharge indicating the dilution of phosphorus in water from point sources. Nitrogen concentrations increased with increasing base-flow discharge, indicating a predominant ground-water source. Nitrogen concentrations at higher base-flow discharges often were greater than median concentrations reported for ground water (from wells and springs) in the Springfield Plateau aquifer. Total estimated phosphorus and nitrogen annual loads for calendar year 1997-1999 using the regression techniques presented in this paper (35 samples) were similar to estimated loads derived from integration techniques (1,033 samples). Flow-weighted nutrient concentrations and nutrient yields at the Illinois River site were about 10 to 100 times greater than national averages for undeveloped basins and at North Sylamore Creek and Cossatot River (considered to be undeveloped basins in Arkansas). Total phosphorus and soluble reactive phosphorus were greater than 10 times and total nitrogen and dissolved nitrite plus nitrate were greater than 10 to 100 times the national and regional averages for undeveloped basins. These results demonstrate the utility of a strategy whereby samples are collected every other month and during selected storm events annually, with use of regression models to estimate nutrient loads. Annual loads of phosphorus and nitrogen estimated using regression techniques could provide similar results to estimates using integration techniques, with much less investment.

Nitrate in ground water and spring water near four dairy farms in North Florida, 1990-93

USGS Publications Warehouse

Andrews, W.J.

1994-01-01

Concentrations of nitrate and other selected water- quality characteristics were analyzed periodically for two years in water from 51 monitoring wells installed at four farms and in water discharging from three nearby springs along the Suwannee River in Lafayette and Suwannee Counties to examine the quality of ground water at these farms and the transport of nutrients in ground water to the nearby spring-fed Suwannee River: Ground water from shallow wells, which were completed in the top ten feet of the saturated zone in a surficial sandy aquifer and in the karstic Upper Floridan aquifer generally had the highest concentrations of nitrate, ranging from <.02 to 130 mg/L as nitrogen. Nitrate concentrations commonly exceeded the primary drinking water standard of 10 mg/L for nitrate as nitrogen in water from shallow wells, which tapped the top ten feet of the uppermost aquifers near waste-disposal areas such as wastewater lagoons and defoliated, intensive-use areas near milking barns. Upgradient from waste-disposal areas, concentrations of nitrate in ground water were commonly less than 1 mg/L as nitrogen. Water samples from deep wells (screened 20 feet deeper than shallow wells in these aquifers) generally had lower concentrations of nitrate (ranging from <0.02 to 84 mg/L) than water from shallow wells. Water samples from the three monitored springs (Blue, Telford, and Convict Springs) had nitrate concentrations ranging from 1.5 to 6.5 mg/L as nitrogen, which were higher than those typically occurring in water from upgradient wells at the monitored dairy farms or from back- ground wells sampled in the region. Analyses of nitrogen isotope ratios in nitrate indicated that leachate from animal wastes was the principal source of nitrate in ground water adjacent to waste-disposal areas at the monitored and unmonitored dairy farms. Leachate from a combi- nation of fertilizers, soils, and animal wastes appeared to be the source of nitrate in ground- water downgradient from pastures and wastewater spray fields at dairy farms and in water discharging from three nearby springs. Although denitrifying bacteria were present in counts sometimes exceeding 240,000 colonies/100mL in water from dairy-farm monitoring wells, ground water in the uppermost aquifers in Lafayette and Suwannee Counties generally contained too much oxygen for denitrification to remove nitrate from shallow ground water. Denitrification was more likely to occur in deeper ground water, which typically has lower dissolved oxygen concentrations.

Ground-Water, Surface-Water, and Water-Chemistry Data, Black Mesa Area, Northeastern Arizona-2005-06

USGS Publications Warehouse

Truini, Margot; Macy, J.P.

2007-01-01

The N aquifer is the major source of water in the 5,400 square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use and the needs of a growing population. Precipitation in the Black Mesa area averages about 6 to 14 inches per year. The water monitoring program in the Black Mesa area began in 1971 and is designed to provide information about the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected for the monitoring program in the Black Mesa area from January 2005 to September 2006. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2005, ground-water withdrawals in the Black Mesa area totaled 7,330 acre-feet, including ground-water withdrawals for industrial (4,480 acre-feet) and municipal (2,850 acre-feet) uses. From 2004 to 2005, total withdrawals increased by less than 2 percent, industrial withdrawals increased by approximately 3 percent, and total municipal withdrawals increased by 0.35 percent. From 2005 to 2006, annually measured water levels in the Black Mesa area declined in 10 of 13 wells in the unconfined areas of the N aquifer, and the median change was -0.5 foot. Measurements indicated that water levels declined in 12 of 15 wells in the confined area of the aquifer, and the median change was -1.4 feet. From the prestress period (prior to 1965) to 2006, the median water-level change for 29 wells was -8.5 feet. Median water-level changes were -0.2 foot for 13 wells in the unconfined areas and -46.6 feet for 16 wells in the confined area. Ground-water discharges were measured once in 2005 and once in 2006 at Moenkopi School Spring and Burro Spring. Discharge decreased by 3.5 percent at Moenkopi School Spring and by 15 percent at Burro Spring. During the period of record at each spring, discharges fluctuated; a decreasing trend was apparent. Continuous records of surface-water discharge in the Black Mesa area have been collected from streamflow gages at the following sites: Moenkopi Wash (1976 to 2005), Dinnebito Wash (1993 to 2005), Polacca Wash (1994 to 2005), Pasture Canyon Spring (August 2004 to December 2005), and Laguna Creek (1996 to 2005). Median flows during November, December, January, and February of each water year were used as an index of the amount of ground-water discharge to the above named sites. For the period of record at each streamflow-gaging station, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. There is not a long enough period of record for Pasture Canyon Spring and Laguna Creek was discontinued at the end of December 2005. In 2006, water samples were collected from 6 wells and 2 springs in the Black Mesa area and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 111 to 588 milligrams per liter. Water samples from 5 of the wells and both of the springs had less than 500 milligrams per liter of dissolved solids. Trends in the chemistry of water samples from the 6 wells show the Pi?on NTUA 1 and Peabody 9 wells increasing in dissolved solids, Forest Lake NTUA 1 and Peabody 2 wells decreasing in dissolved solids, and Kykotsmovi PM2 and Keams Canyon PM2 wells show a steady trend. Increasing trends in dissolved-solids, chloride, and sulfate concentrations were evident from the more than 11 years of data for the 2 springs.

Using Hydrogen Isotopes to Distinguish Allochthony and Autochthony in Hot Springs Ecosystems

NASA Astrophysics Data System (ADS)

Hungate, J.; DeSousa, T. M.; Ong, J. C.; Caron, M. M.; Brown, J. R.; Patel, N.; Dijkstra, P.; Hedlund, B. P.; Hungate, B. A.

2013-12-01

Hot springs are hosts to abundant and diverse microbial communities. Above the temperature threshold for photosynthesis (~73 degrees C), a variety of chemosynthetic organisms support autochthonous primary production in hot springs ecosystems. These organisms are thought to drive the carbon and energy budgets of these ecosystems, but the importance of energy inputs from the surrounding terrestrial environments - allochthonous inputs - is not well known. Here, we tested the efficacy of stable isotopes of hydrogen in distinguishing autochthonous from allochthonous sources of organic matter in hot springs ecosystems. Under laboratory conditions and in pure culture, we grew autotrophic, mixotrophic, and heterotrophic organisms from the Great Boiling Springs in northern Nevada as well as organisms typical of other hot springs environments. We measured the δ2H composition of biomass, water and organic matter sources used by the organisms to produce that biomass. We also surveyed organic matter in and around hot springs in Nevada and in the Tengchong geothermal region in China, sampling terrestrial plants at the hot springs margin, microorganisms (either scraped from surfaces or in the water column), and organic matter in the sediment accruing in the spring itself as an integrative measure of the relative importance of organic matter sources to the spring ecosystem. We found that autotrophic production in culture results in strongly depleted δ2H signatures, presumably because of fractionation against 2H-H2O during chemosynthesis. The observed difference between microbial biomass and water was larger than that typically found for terrestrial plants during photosynthesis, setting the stage for using δ2H to distinguish allochthonous from autochthonous sources of productivity in hot springs. In surveys of natural hot springs, microbial biomass sampled from the water column or from surfaces was often strongly depleted in δ2H, consistent with in situ chemosynthesis. Organic matter in sediments in the springs, however, was substantially higher in δ2H, consistent with a terrestrial origin. These results indicate that hot springs ecosystems are not biogeochemical islands, but rather receive substantial inputs of organic matter and energy produced on land. These external energy sources should be considered in a full understanding of hot springs biology and biogeochemistry.

Radionuclides, inorganic constituents, organic compounds, and bacteria in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area, Idaho, 1992

USGS Publications Warehouse

Bartholomay, R.C.; Edwards, D.D.; Campbell, L.J.

1994-01-01

Dissolved concentrations of radon-222, a naturally occurring radioactive gas, are found in water in Idaho. The U.S. Geological Survey collected water samples for radon-222 analyses from 339 Idaho wells and springs during 1989-91. These water samples were collected as part of ongoing monitoring programs with the Idaho Department of Water Resources and the U.S. Department of Energy. Concentrations of dissolved radon-222 ranged from -58+30 to 5,715+66 picocuries per liter; the mean and median concentrations were 446+35 and 242+25 picocuries per liter, respectively.

Shallow ground-water quality in selected agricultural areas of south-central Georgia, 1994

USGS Publications Warehouse

Crandall, C.A.

1996-01-01

The Georgia-Florida Coastal Plain National Water-Quality Assessment Program began an agricultural land-use study in March 1994. The study area is located in the upper Suwannee River basin in Tift, Turner, Worth, Irwin, Wilcox, and Crisp Counties, Ga. Twenty-three shallow monitoring wells were installed in a 1,335-square- mile area characterized by intensive row-crop agriculture (peanuts, corn, cotton, and soybeans). The study focused on recently recharged shallow ground water in surficial aquifers to assess the relation between land-use activities and ground- water quality. All wells were sampled in March and April (spring) 1994, and 14 of these wells were resampled in August (summer) 1994. Shallow ground water in the study area is characterized by oxic and acidic conditions, low bicarbonate, and low dissolved-solids concentrations. The median pH of shallow ground water was 4.7 and the median bicarbonate concentration was 1.7 mg/L (milligrams per liter). Dissolved oxygen concentrations ranged from 3.0 to 8.0 mg/L. The median dissolved-solids concentration in samples collected in the spring was 86 mg/L. Major inorganic ion composition was generally mixed with no dominant cation; nitrate was the dominant anion (greater than 60 percent of the anion composition) in 14 of 23 samples. Only concentrations of bicarbonate, dissolved organic carbon, and nitrate had significant differences in concentrations between samples collected in the spring and the background samples. However, median concentrations of some of the major ingredients in fertilizer (including magnesium, chloride, nitrate, iron, and manganese) were higher in water samples from agricultural wells than in background samples. The median concentration of dissolved solids in ground-water samples collected in the spring (86 mg/L) was more than double the median concentration (41 mg/L) of the background samples. The median nitrate as nitrogen concentration of 6.7 mg/L in the spring samples reflects the effects of agricultural activities on ground-water quality. Samples from 30 percent of the wells exceeded the maximum contaminant level (MCL) for nitrate in drinking water (10 mg/L as N). Nitrogen isotope ratios ranged from 2.4 to 9.0 parts per thousand and indicate that most nitrogen in shallow ground water is probably from inorganic fertilizer. In addition, nitrate concentrations were positively correlated (p-values all less than 0.01) with concentrations of some of the major ingredients in fertilizer, such as potassium, calcium, magnesium, manganese, and chloride, and with values of specific conductance. Concentrations of pesticides and volatile organic compounds, detected in samples from 11 wells, were all below the MCLs. Of these constituents, only alachlor, metolachlor, metribuzin, toluene, benzene, and methyl chloride were detected in ground water at concentrations that ranged from 0.01 to 1.0 mg/L (micrograms per liter). Maximum concentrations of 1.0 mg/L of metolachlor and toluene were detected in two wells. Radon concentrations ranged from 530 to 1,400 pCi/L (picocuries per liter), exceeding the proposed MCL of 300 pCi/L in all samples; the median concentration was 1,000 pCi/L.

Escherichia coli Concentrations in Recreational Streams and Backcountry Drinking-Water Supplies in Shenandoah National Park, Virginia, 2005-2006

USGS Publications Warehouse

Hyer, Kenneth

2007-01-01

Although fecal contamination of streams is a problem of national scope, few investigations have been directed at relatively pristine streams in forested basins in national parks. With approximately 1.8 million visitors annually, Shenandoah National Park in Virginia is subject to extensive recreational use. The effects of these visitors and their recreational activities on fecal indicator bacteria levels in the streams are poorly understood and of concern for Shenandoah National Park managers. During 2005 and 2006, streams and springs in Shenandoah National Park were sampled for Escherichia coli (E. coli) concentrations. The first study objective was to evaluate the effects of recreational activities on E. coli concentrations in selected streams. Of the 20 streams that were selected, 14 were in basins with extensive recreational activity, and 6 were in control basins where minimal recreational activities occurred. Water-quality sampling was conducted during low-flow conditions during the relatively warm months, as this is when outdoor recreation and bacterial survivorship are greatest. Although most sampling was conducted during low-flow conditions, approximately three stormflow samples were collected from each stream. The second study objective was to evaluate E. coli levels in backcountry drinking-water supplies throughout Shenandoah National Park. Nineteen drinking-water supplies (springs and streams) were sampled two to six times each by Shenandoah National Park staff and analyzed by the U.S. Geological Survey for this purpose. The water-quality sampling results indicated relatively low E. coli concentrations during low-flow conditions, and no statistically significant increase in E. coli concentrations was observed in the recreational streams relative to the control streams. These results indicate that during low-flow conditions, recreational activities had no significant effect on E. coli concentrations. During stormflow conditions, E. coli concentrations increased by nearly a factor of 10 in both basin types, and the Virginia instantaneous water-quality standard for E. coli (235 colonies per 100 milliliters) frequently was exceeded. The sampling results from drinking-water supplies throughout Shenandoah National Park indicated relatively low E. coli concentrations in all springs that were sampled. Several of the streams that were sampled had slightly higher E. coli concentrations relative to the springs, but no E. coli concentrations exceeded the instantaneous water-quality standard. Although E. coli concentrations in all the drinking-water supplies were relatively low, Shenandoah National Park management continues to stress that all hikers must treat drinking water from all streams and springs prior to consumption. After determining that recreational activities in Shenandoah National Park did not have a statistically significant effect on low-flow E. coli concentrations, an additional concern was addressed regarding the quality of the water releases from the wastewater-treatment plants in the park. Sampling of three wastewater-treatment plant outfalls was conducted in 2006 to evaluate their effects on water quality. Samples were analyzed for E. coli and a collection of wastewater organic compounds that may be endocrine disruptors. Relatively elevated E. coli concentrations were observed in 2 of the 3 samples, and between 9 and 13 wastewater organic compounds were detected in the samples, including 3 known and 5 suspected endocrine-disrupting compounds.

Giardia spp. and Cryptosporidium spp. In the Ivaí Indigenous Land, Brazil.

PubMed

Nishi, Letícia; Bergamasco, Rosângela; Toledo, Max Jean de Ornelas; Falavigna, Dina Lúcia Morais; Gomes, Mônica Lúcia; Mota, Lúcio Tadeu; Falavigna-Guilherme, Ana Lúcia

2009-10-01

The objective of this study was to investigate the occurrence of cysts of Giardia spp. and oocysts of Cryptosporidium spp. in waters of the Ivaí Indigenous Land, Brazil. Samples of river and spring water and of treated water were filtered and analyzed by direct immunofluorescence (Merifluor kit, Meridian Bioscience, Cincinnati, Ohio). Of 21 samples, 7 from each locality, 3 (3/7, 42.8%) from a river were positive for Giardia (mean concentration 2.57 cysts/L), and 1 (1/7, 14.3%) was positive for Cryptosporidium (6 oocysts/L). From springs, 1 sample (1/7, 14.3%) was positive for Cryptosporidium (6 oocysts/L). One sample (1/7, 14.3%) from treated water was positive for both, with 4 oocysts/L and 2 cysts/L. Giardia was the more frequent protozoan present.

Pumping tests of well Campbell et al. No. 2, Gila Hot Springs, Grant County, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwab, G.E.; Summers, W.K.; Colpitts, R.M. Jr.

1982-03-01

Well Campbell et al. No. 2 near Gila Hot Springs in southwestern New Mexico (Section 5, Township 13 South, Range 13 West) was pumped for a five-step test and a 48-hour constant-rate test during October 1981. Measurements included depth to water in the pumping well and two observation wells, and discharge rates at the pumping well and two springs. The water level in the pumping well responded during both tests. However, water-level changes in the observation wells were too small for analytical use and discharge rates from the springs showed no change. Chemical analyses of water samples collected from twomore » springs and the pumping well show very similar water chemistries. Estimates of hydraulic properties show transmissivity from 12,000 to 14,000 gpd/ft and a storativity of 0.05. Combining these parameters with well data gives the first-year optimum discharge rate as 50 gpm with 20 feet of drawdown. Pumping this well at 50 gpm for forty years should produce only small water-level changes in wells a few hundred feet away. It would diminish the flow of the springs, and for planning purposes the combined discharge of the springs and well should be considered constant.« less

Groundwater quality impacts from the land application of treated municipal wastewater in a large karstic spring basin: Chemical and microbiological indicators

USGS Publications Warehouse

Katz, B.G.; Griffin, Dale W.; Davis, J.H.

2009-01-01

Geochemical and microbiological techniques were used to assess water-quality impacts from the land application of treated municipal wastewater in the karstic Wakulla Springs basin in northern Florida. Nitrate-N concentrations have increased from about 0.2 to as high as 1.1??mg/L (milligrams per liter) during the past 30??years in Wakulla Springs, a regional discharge point for groundwater (mean flow about 11.3??m3/s) from the Upper Floridan aquifer (UFA). A major source of nitrate to the UFA is the approximately 64??million L/d (liters per day) of treated municipal wastewater applied at a 774??ha (hectare) sprayfield farming operation. About 260 chemical and microbiological indicators were analyzed in water samples from the sprayfield effluent reservoir, wells upgradient from the sprayfield, and from 21 downgradient wells and springs to assess the movement of contaminants into the UFA. Concentrations of nitrate-N, boron, chloride, were elevated in water samples from the sprayfield effluent reservoir and in monitoring wells at the sprayfield boundary. Mixing of sprayfield effluent water was indicated by a systematic decrease in concentrations of these constituents with distance downgradient from the sprayfield, with about a 10-fold dilution at Wakulla Springs, about 15??km (kilometers) downgradient from the sprayfield. Groundwater with elevated chloride and boron concentrations in wells downgradient from the sprayfield and in Wakulla Springs had similar nitrate isotopic signatures, whereas the nitrate isotopic composition of water from other sites was consistent with inorganic fertilizers or denitrification. The sprayfield operation was highly effective in removing most studied organic wastewater and pharmaceutical compounds and microbial indicators. Carbamazepine (an anti-convulsant drug) was the only pharmaceutical compound detected in groundwater from two sprayfield monitoring wells (1-2??ppt). One other detection of carbamazepine was found in a distant well water sample where enteroviruses also were detected, indicating a likely influence from a nearby septic tank.

Groundwater quality impacts from the land application of treated municipal wastewater in a large karstic spring basin: chemical and microbiological indicators.

PubMed

Katz, Brian G; Griffin, Dale W; Davis, J Hal

2009-04-01

Geochemical and microbiological techniques were used to assess water-quality impacts from the land application of treated municipal wastewater in the karstic Wakulla Springs basin in northern Florida. Nitrate-N concentrations have increased from about 0.2 to as high as 1.1 mg/L (milligrams per liter) during the past 30 years in Wakulla Springs, a regional discharge point for groundwater (mean flow about 11.3 m(3)/s) from the Upper Floridan aquifer (UFA). A major source of nitrate to the UFA is the approximately 64 million L/d (liters per day) of treated municipal wastewater applied at a 774 ha (hectare) sprayfield farming operation. About 260 chemical and microbiological indicators were analyzed in water samples from the sprayfield effluent reservoir, wells upgradient from the sprayfield, and from 21 downgradient wells and springs to assess the movement of contaminants into the UFA. Concentrations of nitrate-N, boron, chloride, were elevated in water samples from the sprayfield effluent reservoir and in monitoring wells at the sprayfield boundary. Mixing of sprayfield effluent water was indicated by a systematic decrease in concentrations of these constituents with distance downgradient from the sprayfield, with about a 10-fold dilution at Wakulla Springs, about 15 km (kilometers) downgradient from the sprayfield. Groundwater with elevated chloride and boron concentrations in wells downgradient from the sprayfield and in Wakulla Springs had similar nitrate isotopic signatures, whereas the nitrate isotopic composition of water from other sites was consistent with inorganic fertilizers or denitrification. The sprayfield operation was highly effective in removing most studied organic wastewater and pharmaceutical compounds and microbial indicators. Carbamazepine (an anti-convulsant drug) was the only pharmaceutical compound detected in groundwater from two sprayfield monitoring wells (1-2 ppt). One other detection of carbamazepine was found in a distant well water sample where enteroviruses also were detected, indicating a likely influence from a nearby septic tank.

Bacteriological quality of drinking water from dispensers (coolers) and possible control measures.

PubMed

Baumgartner, Andreas; Grand, Marius

2006-12-01

Three water dispensers (coolers) were bacteriologically monitored over a period of 3 months to evaluate their hygienic status. For this purpose, 174 samples of chilled and unchilled water were analyzed for levels of mesophilic aerobic bacteria and the presence of Escherichia coli and enterococci in 100-ml samples, and the presence of Pseudomonas aeruginosa in 10- and 100-ml samples. Additionally, 12 samples from 20-liter plastic bottles of spring water used to supply the coolers and 36 samples of 12 different brands of noncarbonated bottled mineral water were similarly analyzed. Water from the coolers yielded aerobic plate counts of 3 to 5 log CFU/ml with a geometric mean of 3.86 log CFU/ml, whereas water from the 20-liter bottles had a mean aerobic plate count of 3.3 log CFU/ml. Aerobic plate counts for noncarbonated mineral waters were generally lower (13 samples, < 10 CFU/ml; 6 samples, 10 to 10(2) CFU/ml; 13 samples, 10(2) to 10(3) CFU/ml; 3 samples, 10(3) to 10(4) CFU/ ml; 1 sample, 2 x 10(4) CFU/ml). Although occasional professional cleaning of the coolers did not affect the aerobic plate count, P. aeruginosa was successfully eliminated 2 weeks after cleaning, with only one cooler becoming recolonized. Neither E. coli nor enterococci was found in any of the water samples tested. However, P. aeruginosa was identified in three (25%) of twelve 100-ml samples from 20-liter bottles of spring water; a similar frequency of 24.1% was seen for water samples from coolers. Overall, 35 (21.6%) of 162 water samples (10 ml) from coolers also yielded P. aeruginosa, suggesting potential growth of P. aeruginosa in the dispensers. Pulsed-field gel electrophoresis typing and antibiotic susceptibility testing found 19 P. aeruginosa isolates from the coolers and bottles to be identical, indicating that a single strain originated from the bottled water rather than the surroundings of the coolers. Because P. aeruginosa can cause serious nosocomial infections, its spread should be strictly controlled in institutions caring for vulnerable people such as hospitals and nursing homes. Consequently, in keeping with legal requirement for bottled spring and mineral water in Switzerland, it is also advisable that P. aeruginosa be absent in 100-ml samples of cooler water.

Sources of nitrate contamination and age of water in large karstic springs of Florida

USGS Publications Warehouse

Katz, B.G.

2004-01-01

In response to concerns about the steady increase in nitrate concentrations over the past several decades in many of Florida's first magnitude spring waters (discharge ???2.8 m3/s), multiple isotopic and other chemical tracers were analyzed in water samples from 12 large springs to assess sources and timescales of nitrate contamination. Nitrate-N concentrations in spring waters ranged from 0.50 to 4.2 mg/L, and ??15N values of nitrate in spring waters ranged from 2.6 to 7.9 per mil. Most ??15N values were below 6 per mil indicating that inorganic fertilizers were the dominant source of nitrogen in these waters. Apparent ages of groundwater discharging from springs ranged from 5 to about 35 years, based on multi-tracer analyses (CFC-12, CFC-113, SF6, 3H/3He) and a piston flow assumption; however, apparent tracer ages generally were not concordant. The most reliable spring-water ages appear to be based on tritium and 3He data, because concentrations of CFCs and SF6 in several spring waters were much higher than would be expected from equilibration with modern atmospheric concentrations. Data for all tracers were most consistent with output curves for exponential and binary mixing models that represent mixtures of water in the Upper Floridan aquifer recharged since the early 1960s. Given that groundwater transit times are on the order of decades and are related to the prolonged input of nitrogen from multiple sources to the aquifer, nitrate could persist in groundwater that flows toward springs for several decades due to slow transport of solutes through the aquifer matrix.

Prevalence, characteristics and correlates of enteric pathogenic protozoa in drinking water sources in Molyko and Bomaka, Cameroon: a cross-sectional study.

PubMed

Nsoh, Fuh Anold; Wung, Buh Amos; Atashili, Julius; Benjamin, Pokam Thumamo; Marvlyn, Eba; Ivo, Keumami Katte; Nguedia, Assob Jules Clément

2016-11-08

Access to potable water remains a major challenge particularly in resource-limited settings. Although the potential contaminants of water are varied, enteric pathogenic protozoa are known to cause waterborne diseases greatly. This study aimed at investigating the prevalence, characteristics and correlates of enteric pathogenic protozoa in drinking water sources in Buea, Cameroon. A cross-sectional study was conducted using 155 water samples collected from various drinking sources (boreholes, springs, taps and wells). Each sample was subjected to physicochemical examinations (pH, turbidity, odour and sliminess) and parasitological analysis (wet mount, modified Ziehl-Neelsen stain) to determine the presence of enteric pathogenic protozoa. A data collection tool was used to note characteristics of collected samples and the data was analysed using EPI-INFO Version 3.5.3. The overall prevalence of enteric pathogenic protozoa in water sources was 62.6 %. Eight species of enteric protozoa were observed with Cryptosporidium parvum being the most predominant (45.8 %). Spring water was the most contaminated source with enteric protozoa (85.7 %) while pipe borne water had all eight species of protozoa identified. A pH of 6 was the only significant factor associated with the prevalence of these pathogens in water sources. The prevalence of enteric protozoa in water sources in Molyko and Bomaka is high, spring water is the most contaminated water source and Cryptosporidium parvum is the most common protozoa contaminating water. A water pH of 6 is associated to the prevalence of protozoa. Community members need to be educated to treat water before drinking to avoid infection by enteric protozoa in water and further studies with larger samples of water need to be conducted to find other correlates of the presence of protozoa in water.

Arsenic-related water quality with depth and water quality of well-head samples from production wells, Oklahoma, 2008

USGS Publications Warehouse

Becker, Carol J.; Smith, S. Jerrod; Greer, James R.; Smith, Kevin A.

2010-01-01

The U.S. Geological Survey well profiler was used to describe arsenic-related water quality with well depth and identify zones yielding water with high arsenic concentrations in two production wells in central and western Oklahoma that yield water from the Permian-aged Garber-Wellington and Rush Springs aquifers, respectively. In addition, well-head samples were collected from 12 production wells yielding water with historically large concentrations of arsenic (greater than 10 micrograms per liter) from the Garber-Wellington aquifer, Rush Springs aquifer, and two minor aquifers: the Arbuckle-Timbered Hills aquifer in southern Oklahoma and a Permian-aged undefined aquifer in north-central Oklahoma. Three depth-dependent samples from a production well in the Rush Springs aquifer had similar water-quality characteristics to the well-head sample and did not show any substantial changes with depth. However, slightly larger arsenic concentrations in the two deepest depth-dependent samples indicate the zones yielding noncompliant arsenic concentrations are below the shallowest sampled depth. Five depth-dependent samples from a production well in the Garber-Wellington aquifer showed increases in arsenic concentrations with depth. Well-bore travel-time information and water-quality data from depth-dependent and well-head samples showed that most arsenic contaminated water (about 63 percent) was entering the borehole from perforations adjacent to or below the shroud that overlaid the pump. Arsenic concentrations ranged from 10.4 to 124 micrograms per liter in 11 of the 12 production wells sampled at the well head, exceeding the maximum contaminant level of 10 micrograms per liter for drinking water. pH values of the 12 well-head samples ranged from 6.9 to 9. Seven production wells in the Garber-Wellington aquifer had the largest arsenic concentrations ranging from 18.5 to 124 micrograms per liter. Large arsenic concentrations (10.4-18.5) and near neutral to slightly alkaline pH values (6.9-7.4) were detected in samples from one well in the Garber-Wellington aquifer, three production wells in the Rush Springs aquifer, and one well in an undefined Permian-aged aquifer. All well-head samples were oxic and arsenate was the only species of arsenic in water from 10 of the 12 production wells sampled. Arsenite was measured above the laboratory reporting level in water from a production well in the Garber-Wellington aquifer and was the only arsenic species measured in water from the Arbuckle-Timbered Hills aquifer. Fluoride and uranium were the only trace elements, other than arsenic, that exceeded the maximum contaminant level for drinking water in well-head samples collected for the study. Uranium concentrations in four production wells in the Garber-Wellington aquifer ranged from 30.2 to 99 micrograms per liter exceeding the maximum contaminant level of 30 micrograms per liter for drinking water. Water from these four wells also had the largest arsenic concentrations measured in the study ranging from 30 to 124 micrograms

Radionuclides, stable isotopes, inorganic constituents, and organic compounds in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area, Idaho, 1993

USGS Publications Warehouse

Bartholomay, Roy C.; Edwards, Daniel D.; Campbell, Linford J.

1994-01-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in response to a request from the U.S. Department of Energy, sampled 19 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radionuclides, stable isotopes, inorganic constituents, and organic compounds. The samples were collected from seven irrigation wells, four domestic wells, two springs, one stock well, three dairy wells, one observation well, and one commercial well. Two quality assurance samples also were collected and analyzed. None of the radionuclides, inorganic constituents, or organic compounds exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concen- trations exceeded their respective laboratory reporting levels. All samples analyzed for surfactants and dissolved organic carbon had concentrations that exceeded their reporting level. Ethylbenzene concentrations exceeded the reporting level in one water sample.

Isotopes and Sustainability of the Shallow Groundwater System in Spring and Snake Valleys, Eastern White Pine County, Nevada

NASA Astrophysics Data System (ADS)

Acheampong, S. Y.

2007-12-01

A critical component to managing water resources is understanding the source of ground water that is extracted from a well. Detail information on the source of recharge and the age of groundwater is thus vital for the proper assessment, development, management, and monitoring of the groundwater resources in an area. Great differences in the isotopic composition of groundwater in a basin and the basin precipitation imply that the groundwater in the basin originates from a source outside the basin or is recharged under different climatic conditions. The stable isotopes of oxygen and hydrogen in precipitation were compared with the isotopic composition of water from wells, springs, and creeks to evaluate the source of the shallow groundwater recharge in Spring and Snake Valleys, Nevada, as part of an evaluation of the water resources in the area. Delta deuterium and delta oxygen-18 composition of springs, wells, creeks, and precipitation in Spring and Snake Valleys show that groundwater recharge occurs primarily from winter precipitation in the surrounding mountains. The carbon-14 content of the groundwater ranged from 30 to 95 percent modern carbon (pmc). Twenty two of the thirty samples had carbon-14 values of greater than 50 pmc. The relatively high carbon-14 values suggest that groundwater in the area is recharged by modern precipitation and the waters have rapid travel times. Total dissolved solids content of the samples outside the playa areas are generally low, and suggests that the water has a relatively short travel time between the recharge areas and sample sites. The presence of tritium in some of the springs and wells also indicate that groundwater mixes with post 1952 precipitation. Hydrogen bomb tests which began in 1952 in the northern hemisphere added large amounts of tritium to the atmosphere and reached a peak in 1963. The stable isotopic composition, the high carbon-14 activities, and the presence of tritium, show that the shallow groundwater in Snake and Spring Valleys originates as modern recharge. The shallow groundwater in these valleys is thus a renewable resource and can be developed in a sustainable manner using the appropriate planning and management tools.

Intensive exploitation of a karst aquifer leads to Cryptosporidium water supply contamination.

PubMed

Khaldi, S; Ratajczak, M; Gargala, G; Fournier, M; Berthe, T; Favennec, L; Dupont, J P

2011-04-01

Groundwater from karst aquifers is an important source of drinking water worldwide. Outbreaks of cryptosporidiosis linked to surface water and treated public water are regularly reported. Cryptosporidium oocysts are resistant to conventional drinking water disinfectants and are a major concern for the water industry. Here, we examined conditions associated with oocyst transport along a karstic hydrosystem, and the impact of intensive exploitation on Cryptosporidium oocyst contamination of the water supply. We studied a well-characterized karstic hydrosystem composed of a sinkhole, a spring and a wellbore. Thirty-six surface water and groundwater samples were analyzed for suspended particulate matter, turbidity, electrical conductivity, and Cryptosporidium and Giardia (oo)cyst concentrations. (Oo)cysts were identified and counted by means of solid-phase cytometry (ChemScan RDI(®)), a highly sensitive method. Cryptosporidium oocysts were detected in 78% of both surface water and groundwater samples, while Giardia cysts were found in respectively 22% and 8% of surface water and groundwater samples. Mean Cryptosporidium oocyst concentrations were 29, 13 and 4/100 L at the sinkhole, spring and wellbore, respectively. Cryptosporidium oocysts were transported from the sinkhole to the spring and the wellbore, with respective release rates of 45% and 14%, suggesting that oocysts are subject to storage and remobilization in karst conduits. Principal components analysis showed that Cryptosporidium oocyst concentrations depended on variations in hydrological forcing factors. All water samples collected during intensive exploitation contained oocysts. Control of Cryptosporidium oocyst contamination during intensive exploitation is therefore necessary to ensure drinking water quality. Copyright © 2011. Published by Elsevier Ltd.

Characterization and treatment of water used for human consumption from six sources located in the Cameron/Tuba City abandoned uranium mining area.

PubMed

Orescanin, Visnja; Kollar, Robert; Nad, Karlo; Mikelic, Ivanka Lovrencic; Kollar, Iris

2011-01-01

The purpose of this research was the characterization and improvement of the quality of water used for human consumption of unregulated/regulated water sources located in the Cameron/Tuba City abandoned uranium mining area (NE Arizona, western edge of the Navajo Nation). Samples were collected at six water sources which included regulated sources: Wind Mill (Tank 3T-538), Badger Springs and Paddock Well as well as unregulated sources: Willy Spring, Water Wall and Water Hole. Samples taken from Wind Mill, Water Wall and Water Hole were characterized with high turbidity and color as well as high level of manganese, iron and nickel and elevated value of molybdenum. High level of iron was also found in Badger Spring, Willy Spring, and Paddock Well. These three water sources were also characterized with elevated values of fluoride and vanadium. Significant amounts of zinc were found in Water Wall and Water Hole samples. Water Wall sample was also characterized with high level of Cr(VI). Compared to primary or secondary Navajo Nation Environmental Protection Agency (NNEPA) water quality standard the highest enrichment was found for turbidity (50.000 times), color (up to 1.796 times) and manganese (71 times), Cr(VI) (17.5 times), iron (7.4 times) and arsenic (5.2 times). Activities of (226)Ra and (238)U in water samples were still in agreement with the maximum contaminant levels. In order to comply with NNEPA water quality standard water samples were subjected to electrochemical treatment. This method was selected due to its high removal efficiency for heavy metals and uranium, lower settlement time, production of smaller volume of waste mud and higher stability of waste mud compared to physico-chemical treatment. Following the treatment, concentrations of heavy metals and activities of radionuclides in all samples were significantly lower compared to NNEPA or WHO regulated values. The maximum removal efficiencies for color, turbidity, arsenic, manganese, molybdenum and nickel were 100.0%. Maximum removal percentage of Cu, F(-), V, Zn, (137)Cs, (226)Ra, (232)Th, (238)U were as follows: 98.0%; 82.7%; 99.9%; 95.6%; 75.0%; 76.9%; 80.0% and 99.2%. From the results presented it could be concluded that electrochemical treatment is a suitable approach for the purification of drinking water with complex mixture of contaminants, especially those with high turbidity and color.

Geochemical analysis of atlantic rim water, carbon county, wyoming: New applications for characterizing coalbed natural gas reservoirs

USGS Publications Warehouse

McLaughlin, J.F.; Frost, C.D.; Sharma, Shruti

2011-01-01

Coalbed natural gas (CBNG) production typically requires the extraction of large volumes of water from target formations, thereby influencing any associated reservoir systems. We describe isotopic tracers that provide immediate data on the presence or absence of biogenic natural gas and the identify methane-containing reservoirs are hydrologically confined. Isotopes of dissolved inorganic carbon and strontium, along with water quality data, were used to characterize the CBNG reservoirs and hydrogeologic systems of Wyoming's Atlantic Rim. Water was analyzed from a stream, springs, and CBNG wells. Strontium isotopic composition and major ion geochemistry identify two groups of surface water samples. Muddy Creek and Mesaverde Group spring samples are Ca-Mg-S04-type water with higher 87Sr/86Sr, reflecting relatively young groundwater recharged from precipitation in the Sierra Madre. Groundwaters emitted from the Lewis Shale springs are Na-HCO3-type waters with lower 87Sr/86Sr, reflecting sulfate reduction and more extensive water-rock interaction. To distinguish coalbed waters, methanogenically enriched ??13CDIC wasused from other natural waters. Enriched ??13CDIC, between -3.6 and +13.3???, identified spring water that likely originates from Mesaverde coalbed reservoirs. Strongly positive ??13CDIC, between +12.6 and +22.8???, identified those coalbed reservoirs that are confined, whereas lower ??13CDIC, between +0.0 and +9.9???, identified wells within unconfined reservoir systems. Copyright ?? 2011. The American Association of Petroleum Geologists. All rights reserved.

Geologic, hydrologic, and geochemical identification of flow paths in the Edwards Aquifer, northeastern Bexar and southern Comal Counties, Texas

USGS Publications Warehouse

Otero, Cassi L.

2007-01-01

The U.S. Geological Survey, in cooperation with the San Antonio Water System, conducted a 4-year study during 2002?06 to identify major flow paths in the Edwards aquifer in northeastern Bexar and southern Comal Counties (study area). In the study area, faulting directs ground water into three hypothesized flow paths that move water, generally, from the southwest to the northeast. These flow paths are identified as the southern Comal flow path, the central Comal flow path, and the northern Comal flow path. Statistical correlations between water levels for six observation wells and between the water levels and discharges from Comal Springs and Hueco Springs yielded evidence for the hypothesized flow paths. Strong linear correlations were evident between the datasets from wells and springs within the same flow path and the datasets from wells in areas where flow between flow paths was suspected. Geochemical data (major ions, stable isotopes, sulfur hexafluoride, and tritium and helium) were used in graphical analyses to obtain evidence of the flow path from which wells or springs derive water. Major-ion geochemistry in samples from selected wells and springs showed relatively little variation. Samples from the southern Comal flow path were characterized by relatively high sulfate and chloride concentrations, possibly indicating that the water in the flow path was mixing with small amounts of saline water from the freshwater/saline-water transition zone. Samples from the central Comal flow path yielded the most varied major-ion geochemistry of the three hypothesized flow paths. Central Comal flow path samples were characterized, in general, by high calcium concentrations and low magnesium concentrations. Samples from the northern Comal flow path were characterized by relatively low sulfate and chloride concentrations and high magnesium concentrations. The high magnesium concentrations characteristic of northern Comal flow path samples from the recharge zone in Comal County might indicate that water from the Trinity aquifer is entering the Edwards aquifer in the subsurface. A graph of the relation between the stable isotopes deuterium and delta-18 oxygen showed that, except for samples collected following an unusually intense rain storm, there was not much variation in stable isotope values among the flow paths. In the study area deuterium ranged from -36.00 to -20.89 per mil and delta-18 oxygen ranged from -6.03 to -3.70 per mil. Excluding samples collected following the intense rain storm, the deuterium range in the study area was -33.00 to -20.89 per mil and the delta-18 oxygen range was -4.60 to -3.70 per mil. Two ground-water age-dating techniques, sulfur hexafluoride concentrations and tritium/helium-3 isotope ratios, were used to compute apparent ages (time since recharge occurred) of water samples collected in the study area. In general, the apparent ages computed by the two methods do not seem to indicate direction of flow. Apparent ages computed for water samples in northeastern Bexar and southern Comal Counties do not vary greatly except for some very young water in the recharge zone in central Comal County.

Geologic and tributary influences on the chemistry of a headwater stream

Treesearch

Alexander C. Wooten; James Preer; Pamela J. Edwards

1999-01-01

Water samples were collected weekly from June 12 to August 14, 1995, from Big Spring Run (BSR) in West Virginia. BSR originates in Big Spring Cave, where three stream samples were collected. In addition, 18 BSR sites were sampled downstream from the cave, three from its tributaries, and one above and below the stream?s confluence with Elklick Run. Along its length (653...

Overview of water resources in and near Wichita and Affiliated Tribes treaty lands in western Oklahoma

USGS Publications Warehouse

Abbott, Marvin M.; Tortorelli, R.L.; Becker, M.F.; Trombley, T.J.

2003-01-01

This report is an overview of water resources in and near the Wichita and Affiliated Tribes treaty lands in western Oklahoma. The tribal treaty lands are about 1,140 square miles and are bordered by the Canadian River on the north, the Washita River on the south, 98? west longitude on the east, and 98? 40' west longitude on the west. Seventy percent of the study area lies within the Washita River drainage basin and 30 percent of the area lies within the Canadian River drainage basin. March through June are months of greatest average streamflow, with 49 to 57 percent of the annual streamflow occurring in these four months. November through February, July, and August have the least average streamflow with only 26 to 36 percent of the annual streamflow occurring in these six months. Two streamflow-gaging stations, Canadian River at Bridgeport and Cobb Creek near Fort Cobb, indicated peak streamflows generally decrease with regulation. Two other streamflow-gaging stations, Washita River at Carnegie and Washita River at Anadarko, indicated a decrease in peak streamflows after regulation at less than the 100-year recurrence and an increase in peak streamflows greater than the 100-year recurrence. Canadian River at Bridgeport and Washita River at Carnegie had estimated annual low flows that generally increased with regulation. Cobb Creek near Fort Cobb had a decrease of estimated annual low flows after regulation. There are greater than 900 ground-water wells in the tribal treaty lands. Eighty percent of the wells are in Caddo County.The major aquifers in the study area are the Rush Springs Aquifer and portions of the Canadian River and Washita River valley alluvial aquifers. The Rush Springs Aquifer is used extensively for irrigation as well as industrial and municipal purposes, especially near population centers.The Canadian River and Washita River valley alluvial aquifers are not used extensively in the study area. Well yields from the Rush Springs Aquifer ranged from 11 to greater than 850 gallons per minute. The Rush Springs Aquifer is recharged by the infiltration of precipitation. The estimated recharge is about 1.80 inches per year evenly distributed over the outcrop of the aquifer in the study area. Principal factors affecting the water quality in the study area include geology, agricultural practices,and oil and gas production. Calcium, magnesium, sulfate, and bicarbonate are the dominant dissolved constituents in water in the study area. Interquartile dissolved-solids concentrations in surface-water samples in the study area generally were greater than interquartile concentrations in ground-water samples. Median dissolved-solids concentrations for ground-water samples from Canadian River, Ionine Creek, Spring Creek,and Washita River Basins, which ranged from 535 to 1,195 milligrams per liter,exceeded the U.S. Environmental Protection Agency Secondary Drinking Water Standard of 500 milligrams per liter. Interquartile sulfate concentrations in surface-water samples in the study area generally were greater than interquartile concentrations in ground-water samples. Median sulfate concentrations from ground-water samples in the Canadian River, IonineCreek,and Spring Creek Basins, which ranged from 385 to 570 milligrams per liter, exceeded the U.S. Environmental Protection Agency Secondary Drinking Water Standard of 250 milligrams per liter. Nitrite plus nitrate as nitrogen concentrations in surface-water samples in the study area generally were less than concentrations in ground-water samples. The median nitrite plus nitrate as nitrogen concentration in ground water was 9.8 milligrams per liter, suggesting almost one-half the ground-water samples exceeded the U.S. Environmental Protection Agency Primary Drinking Water Standard (10 milligrams per liter). An estimated 100 million gallons of water per day were withdrawn from surface and ground water for all uses in

Springtime phytoplankton dynamics in Arctic Krossfjorden and Kongsfjorden (Spitsbergen) as a function of glacier proximity

NASA Astrophysics Data System (ADS)

Piquet, A. M.-T.; van de Poll, W. H.; Visser, R. J. W.; Wiencke, C.; Bolhuis, H.; Buma, A. G. J.

2014-04-01

The hydrographic properties of the Kongsfjorden-Krossfjorden system (79° N, Spitsbergen) are affected by Atlantic water incursions as well as glacier meltwater runoff. This results in strong physical gradients (temperature, salinity and irradiance) within the fjords. Here, we tested the hypothesis that glaciers affect phytoplankton dynamics as early as the productive spring bloom period. During two campaigns in 2007 (late spring) and 2008 (early spring) we studied hydrographic characteristics and phytoplankton variability along two transects in both fjords, using high-performance liquid chromatography (HPLC)-CHEMTAX pigment fingerprinting, molecular fingerprinting (denaturing gradient gel electrophoresis, or DGGE) and sequencing of 18S rRNA genes. The sheltered inner fjord locations remained colder during spring as opposed to the outer locations. Vertical light attenuation coefficients increased from early spring onwards, at all locations, but in particular at the inner locations. In late spring meltwater input caused stratification of surface waters in both fjords. The inner fjord locations were characterized by overall lower phytoplankton biomass. Furthermore HPLC-CHEMTAX data revealed that diatoms and Phaeocystis sp. were replaced by small nano- and picophytoplankton during late spring, coinciding with low nutrient availability. The innermost stations showed higher relative abundances of nano- and picophytoplankton throughout, notably of cyanophytes and cryptophytes. Molecular fingerprinting revealed a high similarity between inner fjord samples from early spring and late spring samples from all locations, while outer samples from early spring clustered separately. We conclude that glacier influence, mediated by early meltwater input, modifies phytoplankton biomass and composition already during the spring bloom period, in favor of low biomass and small cell size communities. This may affect higher trophic levels especially when regional warming further increases the period and volume of meltwater.

Springtime phytoplankton dynamics in the Arctic Krossfjorden and Kongsfjorden (Spitsbergen) as a function of glacier proximity

NASA Astrophysics Data System (ADS)

Piquet, A. M.-T.; van de Poll, W. H.; Visser, R. J. W.; Wiencke, C.; Bolhuis, H.; Buma, A. G. J.

2013-10-01

The hydrographic properties of the Kongsfjorden - Krossfjorden system (79° N, Spitsbergen) are affected by Atlantic water incursions as well as glacier meltwater runoff. This results in strong physical gradients (temperature, salinity and irradiance) within the fjords. Here, we tested the hypothesis that glaciers affect phytoplankton dynamics as early as the productive spring bloom period. During two campaigns in 2007 (late spring) and 2008 (early spring) we studied hydrographic characteristics and phytoplankton variability along 2 transects in both fjords, using HPLC-CHEMTAX pigment fingerprinting, molecular fingerprinting (DGGE) and sequencing of 18S rRNA genes. The sheltered inner fjord locations remained colder during spring as opposed to the outer locations. Vertical light attenuation coefficients increased from early spring onwards, at all locations, but in particular at the inner locations. During the end of spring, meltwater input had stratified surface waters throughout the fjords. The inner fjord locations were characterized by overall lower phytoplankton biomass. Furthermore HPLC-CHEMTAX data revealed that diatoms and Phaeocystis sp. were replaced by small nano- and picophytoplankton during late spring, coinciding with low nutrient availability. The innermost stations showed higher relative abundances of nano- and picophytoplankton throughout, notably of cyanophytes and cryptophytes. Molecular fingerprinting revealed a high similarity between inner fjord samples from early spring and late spring samples from all locations, while outer samples from early spring clustered separately. We conclude that glacier influence, mediated by early meltwater input, modifies phytoplankton biomass and composition already during the spring bloom period, in favor of low biomass and small cell size communities. This may affect higher trophic levels especially when regional warming further increases the period and volume of meltwater.

Household safe water management in Kisii County, Kenya.

PubMed

Misati, A G

2016-11-01

Contaminated drinking water can lead to the risk of intestinal and other infectious diseases that lead to high morbidity. Therefore, determining household safe water management practices will benefit billions of people by ensuring there is no recontamination. A cross-sectional study design was used and a sample of 346 households was selected through systematic random sampling. A questionnaire was then used which was based on the core questions on drinking water and sanitation for household surveys and descriptive analyses were performed for the collected data using SPSS. Springs were predominantly used as the main source of water (97 %). Approximately, over half (58 %) of the sampled households never treated their drinking water to ensure that it was safe for drinking. Mostly (56 %), the households used jerricans for the storage of water with a majority of the households (95 %) covering their containers which were elevated from the reach of children in 52 % of the households. The risks included lack of water treatment, not covering the water container, risk of permitting dipping for those containers, lacking narrow neck and the risk of container being accessible to children. Basic treatment of the water at the household level by use of chemicals, filtration and boiling may have a great impact on the drinking water quality and health of the inhabitants of Kisii County. Also, creation of awareness on the possibilities of spring water being contaminated should be carried because of the assumption that spring water is safe and does not need to be treated.

Radionuclides, inorganic constituents, organic compounds, and bacteria in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1990

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartholomay, R.C.; Edwards, D.D.; Campbell, L.J.

1992-03-01

The US Geological Survey and the Idaho Department of Water Resources, in response to a request from the US Department of Energy, sampled 19 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for manmade pollutants and naturally occurring constituents. The samples were collected from seven irrigation wells, five domestic wells, two springs, one stock well, two dairy wells, one observation well, and one commercial well. Two quality assurance samples also weremore » collected and analyzed. The water samples were analyzed for selected radionuclides, inorganic constituents, organic compounds, and bacteria. None of the radionuclides, inorganic constituents, or organic compounds exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. All samples analyzed for surfactants and dissolved organic carbon had concentrations that exceeded their reporting level. Toluene concentrations exceeded the reporting level in one water sample. Two samples contained fecal coliform bacteria counts that exceeded established maximum contaminant levels for drinking water.« less

Ground-water flow and water quality in the Upper Floridan aquifer, southwestern Albany area, Georgia, 1998-2001

USGS Publications Warehouse

Warner, Debbie; Lawrence, Stephen J.

2005-01-01

During 1997, the Dougherty County Health Department sampled more than 700 wells completed in the Upper Floridan aquifer in Dougherty County, Georgia, and determined that nitrate as nitrogen (hereinafter called nitrate) concentrations were above 10 milligrams per liter (mg/L) in 12 percent of the wells. Ten mg/L is the Georgia primary drinking-water standard. The ground-water flow system is complex and poorly understood in this predominantly agricultural area. Therefore, the U.S. Geological Survey (USGS) - in cooperation with Albany Water, Gas and Light Commission - conducted a study to better define ground-water flow and water quality in the Upper Florida aquifer in the southwestern Albany area, Georgia. Ground-water levels were measured in the southwestern Albany area, Georgia, during May 1998 and March 1999 (spring), and October 1998 and September 1999 (fall). Groundwater levels measured in 75 wells open only to the Upper Floridan aquifer were used to construct potentiometric-surface maps for those four time periods. These maps show that ground water generally flows from northwest to southeast at gradients ranging from about 2 to greater than 10 feet per mile. During spring and fall 1998, ground-water levels were high and mounding of the potentiometric surface occurred in the central part of the study area, indicating a local recharge area. Water levels declined from December through February, and by March 1999 the mound in the potentiometric surface had dissipated. Of the 75 wells in the potentiometric network, 24 were selected for a water-quality network. These 24 wells and 1 spring were sampled during fall 1998 and spring 1999. Samples were analyzed for major chemical constituents, selected minor constituents, selected nutrients, and chlorofluorocarbons (CFC). Water-quality field measurements - such as water temperature, pH, specific conductance (SC), and dissolved oxygen (DO) - were taken at each well. During August 2000, a ground-water sample was collected and analyzed for selected sewage tracers. During March 2001, water samples from selected wells were analyzed for nitrogen and oxygen isotopes. Age-dating analysis using CFCs yield apparent groundwater ages that range from modern to greater than 50 years. The chemistry of ground water in the Upper Floridan aquifer varies widely throughout the southwestern Albany area, Georgia, and in general represents the chemistry commonly found in recharge areas. From fall 1998 through spring 1999, median values of pH, SC, and DO concentration were 7.6 standard units, 266 microsiemens per centimeter at 25 degrees Celsius (uS/cm), and 5.6 mg/L, respectively. The SC is highest (350 - 400 uS/cm) where mounding of the potentiometric surface exists. Specific DO concentrations indicate an area of anoxic ground water in the north-central part of the study area. Water samples indicate that ground water in the study area is dominated by calcium and bicarbonate ions, which is consistent with the limestone lithology of the aquifer. About 25 percent of the samples contained sodium and chloride at ratios similar to those in rainfall, indicating a close proximity to recharge areas. The remaining water samples, however, had sodiumchloride ratios less than 0.90, the ratio in Tift County, Georgia, rainfall samples. These low sodium-chloride ratios are consistent with chloride enrichment. Minor constituent and nutrient concentrations typically are below laboratory reporting limits; however, the maximum nitrate concentration measured during the study period was 12.2 mg/L, and the median concentration for the study period was 3.0 mg/L. Samples collected during 1999 had a higher median nitrate concentration than the 1998 samples. Regression analysis indicated that nitrate concentrations are related exponentially to chloride concentrations. Four distinct groups of ground-water-quality samples, plus four unique samples, were identified using cluster analysis. Water-quality groups I and

Tularaemia outbreaks in Sakarya, Turkey: case-control and environmental studies.

PubMed

Meric, M; Sayan, M; Dundar, D; Willke, A

2010-08-01

Tularaemia is an important zoonotic disease that leads to outbreaks. This study aimed to compare the epidemiological characteristics of two tularaemia outbreaks that occurred in the Sakarya region of Turkey, analyse the risk factors for the development of outbreaks and identify Francisella (F.) tularensis in the water samples. Two tularaemia outbreaks occurred in the Kocadongel village in 2005 and 2006. A field investigation and a case-control study with 47 cases and 47 healthy households were performed during the second outbreak. Clinical samples from the patients and filtrated water samples were analysed for F. tularensis via real-time polymerase chain reaction. From the two outbreaks, a total of 58 patients were diagnosed with oropharyngeal tularaemia based on their clinical and serological results. Both outbreaks occurred between the months of January and April, and the number of patients peaked in February. Logistic regression analysis revealed that the consumption of natural spring water was the only significant risk factor for tularaemia infection (odds ratio 3.5, confidence interval 1.23-10.07). F. tularensis was detected in eight clinical samples and in the filtrated natural spring water. This study is the first report of tularaemia from this region. The results show that both tularaemia outbreaks were related to the consumption of untreated natural spring water. To prevent waterborne tularaemia, community water supplies should be treated and checked periodically.

Evolution of concentration-discharge relations revealed by high frequency diurnal sampling of stream water during spring snowmelt

NASA Astrophysics Data System (ADS)

Olshansky, Y.; White, A. M.; Thompson, M.; Moravec, B. G.; McIntosh, J. C.; Chorover, J.

2017-12-01

Concentration discharge (C-Q) relations contain potentially important information on critical zone (CZ) processes including: weathering reactions, water flow paths and nutrient export. To examine the C-Q relations in a small (3.3 km2) headwater catchment - La Jara Creek located in the Jemez River Basin Critical Zone Observatory, daily, diurnal stream water samples were collected during spring snow melt 2017, from two flumes located in outlets of the La Jara Creek and a high elevation zero order basin within this catchment. Previous studies from this site (McIntosh et al., 2017) suggested that high frequency sampling was needed to improve our interpretation of C-Q relations. The dense sampling covered two ascending and two descending limbs of the snowmelt hydrograph, from March 1 to May 15, 2017. While Na showed inverse correlation (dilution) with discharge, most other solutes (K, Mg, Fe, Al, dissolved organic carbon) exhibited positive (concentration) or chemostatic trends (Ca, Mn, Si, dissolved inorganic carbon and dissolved nitrogen). Hysteresis in the C-Q relation was most pronounced for bio-cycled cations (K, Mg) and for Fe, which exhibited concentration during the first ascending limb followed by a chemostatic trend. A pulsed increase in Si concentration immediately after the first ascending limb in both flumes suggests mixing of deep groundwater with surface water. A continual increase in Ge/Si concentrations followed by a rapid decrease after the second rising limb may suggest a fast transition between soil water to ground water dominating the stream flow. Fourier transform infrared spectroscopy of selected samples across the hydrograph demonstrated pronounced changes in dissolved organic matter molecular composition with the advancement of the spring snow melt. X-ray micro-spectroscopy of colloidal material isolated from the collected water samples indicated a significant role for organic matter in the transport of inorganic colloids. Analyses of high frequency diurnal sampling greatly improve our ability to probe rapid CZ changes occurring during spring snowmelt, and provide useful information for evaluation and modeling of CZ processes in other snow melt dominated regions.

Radioactive springs geochemical data related to uranium exploration

USGS Publications Warehouse

Cadigan, R.A.; Felmlee, J.K.

1977-01-01

Radioactive mineral springs and wells at 33 localities in the States of Colorado, Utah, Arizona and New Mexico in the United States were sampled and studied to obtain geochemical data which might be used for U exploration. The major source of radioactivity at mineral spring sites is 226Ra. Minor amounts of 228Ra, 238U and 232Th are also present. Ra is presumed to have been selectively removed from possibly quite deep uranium-mineralized rock by hydrothermal solutions and is either precipitated at the surface or added to fresh surface water. In this way, the source rocks influence the geochemistry of the spring waters and precipitates. Characteristics of the spring waters at or near the surface are also affected by variations in total dissolved solids, alkalinity, temperature and co-precipitation. Spring precipitates, both hard and soft, consist of four major types: (1) calcite travertine; (2) iron- and arsenic-rich precipitates; (3) manganese- and barium-rich precipitates; and (4) barite, in some instances accompanied by S, Ra and U, if present in the spring water, are co-precipitated with the barite, Mn-Ba and Fe-As precipitates. Using parameters based on U and Ra concentrations in waters and precipitates springsite areas are tentatively rated for favourability as potential uraniferous areas. ?? 1977.

Ground-water quality and effects of poultry confined animal feeding operations on shallow ground water, upper Shoal Creek basin, Southwest Missouri, 2000

USGS Publications Warehouse

Mugel, Douglas N.

2002-01-01

Forty-seven wells and 8 springs were sampled in May, October, and November 2000 in the upper Shoal Creek Basin, southwest Missouri, to determine if nutrient concentrations and fecal bacteria densities are increasing in the shallow aquifer as a result of poultry confined animal feeding operations (CAFOs). Most of the land use in the basin is agricultural, with cattle and hay production dominating; the number of poultry CAFOs has increased in recent years. Poultry waste (litter) is used as a source of nutrients on pasture land as much as several miles away from poultry barns.Most wells in the sample network were classified as ?P? wells, which were open only or mostly to the Springfield Plateau aquifer and where poultry litter was applied to a substantial acreage within 0.5 mile of the well both in spring 2000 and in several previous years; and ?Ag? wells, which were open only or mostly to the Springfield Plateau aquifer and which had limited or no association with poultry CAFOs. Water-quality data from wells and springs were grouped for statistical purposes as P1, Ag1, and Sp1 (May 2000 samples) and P2, Ag2, and Sp2 (October or November 2000 samples). The results of this study do not indicate that poultry CAFOs are affecting the shallow ground water in the upper Shoal Creek Basin with respect to nutrient concentrations and fecal bacteria densities. Statistical tests do not indicate that P wells sampled in spring 2000 have statistically larger concentrations of nitrite plus nitrate or fecal indicator bacteria densities than Ag wells sampled during the same time, at a 95-percent confidence level. Instead, the Ag wells had statistically larger concentrations of nitrite plus nitrate and fecal coliform bacteria densities than the P wells.The results of this study do not indicate seasonal variations from spring 2000 to fall 2000 in the concentrations of nutrients or fecal indicator bacteria densities from well samples. Statistical tests do not indicate statistically significant differences at a 95-percent confidence level for nitrite plus nitrate concentrations or fecal indicator bacteria densities between either P wells sampled in spring and fall 2000, or Ag wells sampled in spring and fall 2000. However, analysis of samples from springs shows that fecal streptococcus bacteria densities were statistically smaller in fall 2000 than in spring 2000 at a 95-percent confidence level.Nitrite plus nitrate concentrations in spring 2000 samples ranged from less than the detection level [0.02 mg/L (milligram per liter) as nitrogen] to 18 mg/L as nitrogen. Seven samples from three wells had nitrite plus nitrate concentrations at or larger than the maximum contaminant level (MCL) of 10 mg/L as nitrogen. The median nitrite plus nitrate concentrations were 0.28 mg/L as nitrogen for P1 samples, 4.6 mg/L as nitrogen for Ag1 samples, and 3.9 mg/L as nitrogen for Sp1 samples.Fecal coliform bacteria were detected in 1 of 25 P1 samples and 5 of 15 Ag1 samples. Escherichia coli (E. coli) bacteria were detected in 3 of 24 P1 samples and 1 of 13 Ag1 samples. Fecal streptococcus bacteria were detected in 8 of 25 P1 samples and 6 of 15 Ag1 samples. Bacteria densities in samples from wells ranged from less than 1 to 81 col/100 mL (colonies per 100 milliliters) of fecal coliform, less than 1 to 140 col/100 mL of E. coli, and less than 1 to 130 col/100 mL of fecal streptococcus. Fecal indicator bacteria densities in samples from springs were substantially larger than in samples from wells. In Sp1 samples, bacteria densities ranged from 12 to 3,300 col/100 mL of fecal coliform, 40 to 2,700 col/100 mL of E. coli, and 42 to 3,100 col/100 mL of fecal streptococcus.

Estimation of deepwater temperature and hydrogeochemistry of springs in the Takab geothermal field, West Azerbaijan, Iran.

PubMed

Sharifi, Reza; Moore, Farid; Mohammadi, Zargham; Keshavarzi, Behnam

2016-01-01

Chemical analyses of water samples from 19 hot and cold springs are used to characterize Takab geothermal field, west of Iran. The springs are divided into two main groups based on temperature, host rock, total dissolved solids (TDS), and major and minor elements. TDS, electrical conductivity (EC), Cl(-), and SO4 (2-) concentrations of hot springs are all higher than in cold springs. Higher TDS in hot springs probably reflect longer circulation and residence time. The high Si, B, and Sr contents in thermal waters are probably the result of extended water-rock interaction and reflect flow paths and residence time. Binary, ternary, and Giggenbach diagrams were used to understand the deeper mixing conditions and locations of springs in the model system. It is believed that the springs are heated either by mixing of deep geothermal fluid with cold groundwater or low conductive heat flow. Mixing ratios are evaluated using Cl, Na, and B concentrations and a mass balance approach. Calculated quartz and chalcedony geothermometer give lower reservoir temperatures than cation geothermometers. The silica-enthalpy mixing model predicts a subsurface reservoir temperature between 62 and 90 °C. The δ(18)O and δD (δ(2)H) are used to trace and determine the origin and movement of water. Both hot and cold waters plot close to the local meteoric line, indicating local meteoric origin.

Noble Gas Signatures in Groundwater and Rainwater on the Island of Maui, Hawaii - Developing a New Noble Gas Application in Fractured, Volcanic Systems

NASA Astrophysics Data System (ADS)

Castro, M. C.; Niu, Y.; Warrier, R. B.; Hall, C. M.; Gingerich, S. B.; Scholl, M. A.; Bouvier, L.

2014-12-01

Recent work in the Galapagos Islands suggests that noble gas temperatures (NGTs) in fractured groundwater systems reflect the temperature of the ground surface at the time of infiltration rather than the mean annual air temperature (MAAT) value as commonly assumed in sedimentary systems where NGTs are typically used as indicators of past climate. This suggests that noble gases in fractured areas may record seasonality, and thus, provide information about timing of recharge in addition to location. Calculation of NGTs assumes that rain-derived recharge at the water table is in equilibrium with ground air. Lack of noble gas equilibration with respect to surface conditions, however, was observed in high-altitude springs in the Galapagos Islands and in a rainwater pilot study in Michigan, supporting the NGT seasonality hypothesis. Developing this new NGT application will lead to a better understanding of fractured groundwater flow systems and will contribute to improved water resource management plans. This study, carried out on Maui, Hawaii, is meant to test these hypotheses while improving knowledge of this island's groundwater flow system where limited hydrologic data are available. Here, we present the first results of noble gas analyses from samples collected in springs, groundwater wells and rainwater on northeast Maui. Results show that like most Michigan rainwater samples, rainwater from Maui is in disequilibrium with surface conditions and follows a mass-dependent pattern. Spring samples follow a similar pattern to that of rainwater and suggest that spring water originates directly from rainfall. These findings further support the hypothesis of NGT seasonality. However, while the atmospheric composition of noble gases points to direct supply from rainfall to spring aquifer systems, a direct connection between spring water and deeper aquifer levels or the mantle is apparent from He isotopic ratios which display an almost pure He mantle component in some springs.

Geochemical and isotopic characteristics of spring and groundwater in the State of São Paulo, Brazil

NASA Astrophysics Data System (ADS)

Szikszay, M.; Teissedre, J.-M.; Barner, U.; Matsui, E.

1981-12-01

A study of spring water shows that a correlation exists between the physical and chemical characteristics of the water and the lithology from where it issues. Water from crystalline rock can be classified as Ca/1bMg-bicarbonate, with low conductivity and temperature; water from sediments and/or weathered crystalline rock as Ca/1bMg-chloride—sulfate; and from volcanic rock, diabase and basalt as Na-bicarbonate water. Monthly samples of eight springs and of rain water in the region of Águas da Prata were analyzed for the deuterium and 18O isotopic contents expressed as δD and δ18O in order to determine the origin of these waters. The coincidence of the isotopic values of spring water with the regional meteoric line indicates a local source of recharge. Chemical anomalies of groundwater in the shallow Bauru and Basalto aquifers in the Paraná Basin are probably caused by ascending water from the confined deep Botucatu—Piramboia aquifer through fracture and fault zones.

Environmental isotope investigation for the identification of source of springs observed in the hillock on the left flank of Gollaleru Earthen Dam, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Noble, J.; Arzoo Ansari, MD

2017-07-01

A hydrometric, hydrochemical and environmental isotopic study was conducted to identify the source and origin of observed springs on the foot of the hillock abutting the left flank of the Gollaleru earthen dam, Nandyal, Andhra Pradesh, India. Water samples (springs, reservoir water and groundwater) in and around the dam area were collected and analyzed for environmental isotopes (δ^{18}!O, δ2H and 3H) and hydrochemistry. Reservoir level, spring discharges and physico-chemical parameters (temperature, electrical conductivity, pH, etc.) were monitored in-situ. Isotopic results indicated that the source of springs is from the Owk reservoir and groundwater contribution to the springs is insignificant. Based on hydrometric observations, it is inferred that the springs might be originated from the reservoir level of 209 m amsl. It is found that the lower spring discharges were derived from diffuse sources (seepage) which could be a mixture of reservoir water and the groundwater, while the relatively higher spring discharges were resulted from concentrated sources (leakage) from the reservoir. Thus, the study portraits the usefulness of isotope techniques in understanding the dam seepage/leakage related problems.

Subaqueous hot springs in Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay (SW Turkey): Locations, chemistry and origins

NASA Astrophysics Data System (ADS)

Avşar, Özgür; Avşar, Ulaş; Arslan, Şebnem; Kurtuluş, Bedri; Niedermann, Samuel; Güleç, Nilgün

2017-10-01

In this study, horizontal temperature measurements along organized grids have been used to detect subaqueous hot springs. The study area, located in the southwest of Turkey and comprised of Köyceğiz Lake, Dalyan Channel and Fethiye-Göcek Bay, was scanned by measuring temperatures horizontally, 2-3 m above the bottom of the lake or sea. After analyzing the temperature data along the grids, the locations with anomalous temperature values were detected, and divers headed here for further verification. Accordingly, among these anomalies, the divers confirmed seven of them as subaqueous hot springs. Three of these hot springs are located in the Köyceğiz Lake, three of them are located in the Dalyan Channel and one hot spring is located in the Fethiye-Göcek Bay. At the locations where temperature anomalies were detected, the divers collected samples directly from the subaqueous hot spring using a syringe-type sampler. We evaluated these water samples together with samples collected from hot and cold springs on land and from local rivers, lakes and the sea, with an aim to generate a conceptual hydrogeochemical model of the geothermal system in the study area. This model predicts that rainwater precipitating in the highlands percolates through fractures and faults into the deeper parts of the Earth's crust, here it is heated and ascends through the sea bottom via buried faults. Pervious carbonate nappes that are underlain and overlain by impervious rocks create a confined aquifer. The southern boundary of the Carbonate-Marmaris nappes is buried under alluvium and/or sea/lake water bodies and this phenomenon determines whether hot springs occur on land or subaqueous. The chemical and isotopic properties of the hot springs point to seawater mixing at deep levels. Thus, the mixing most probably occurs while the water is ascending through the faults and fractures. The gas geochemistry results reveal that the lowest mantle He contributions occur in the samples from Köycegiz Lake, whereas the highest ones are found in samples from the Dalaman plain. For the first time, we made use of the micro-XRF sediment core scanning (ITRAX Scanner) for exploring the relation between subaqueous geothermal occurrence and chemical properties of the surrounding sediments. The spatial elemental distribution of sea/lake bottom sediments suggests that depending on the surrounding rock units and the temperature of the hot spring, the sediments around the spring can be enriched with certain elements.

Quality of water resources in Kullu Valley in Himachal Himalayas, India: perspective and prognosis

NASA Astrophysics Data System (ADS)

Thakur, Nandini; Rishi, Madhuri; Sharma, Diana A.; Keesari, Tirumalesh

2018-03-01

The water quality in mountain regions of Himalaya is considered to be good and quantity adequate. However, recent reports suggest that urbanisation and population growth have been tremendous, which are impacting the land use/cover changes and also endangering the water resources both in quality and quantity. This paper elaborates the systematic investigation carried out on different attributes impacting the drinking water resources in Kullu valley. Two approaches were employed in this study: (1) ex-ante approach involving field survey and secondary data analysis from ancillary sources and (2) hydrochemical approach for the measurement of water quality parameters from springs. Results from ex-ante approach infer rise in population of about 15% during 2001-2011, which led to a significant change in land use pattern, microclimate and also increased water demand. Hydrochemistry of the water samples in the study area has indicated that the current status of spring waters is satisfactory for drinking purposes with a few incidences of high NO3 - which is mostly attributed to contamination from sewage, while F-, Cl- and TDS contamination is mainly confined to hot springs. From both ex-ante approach and primary hydrochemical data it can be inferred that springs need to be restored in terms of both quantity and quality. Hydrochemical interpretation suggests two main groups of samples: (1) low TDS and Ca-Mg-Cl-HCO3 type, which are mainly recharging waters with very less interaction with the aquifer material and (ii) moderate TDS and Mg-Ca-Cl, Ca-Na-HCO3, Na-Ca-Cl-SO4 and Ca-Mg-HCO3 and have undergone water-rock interaction. Based on the inferences obtained from the Piper's, Chadha's and Durov's classification no evidence of hot springs contaminating or contributing to other cold springs and shallow groundwater (hand pump) is found. The study concludes that the water resources are vulnerable to anthropogenic interventions and needs treatment prior to drinking. Periodic monitoring of water quality and adopting proper treatment procedures are essential for supplying safe and sustainable water to the community in the Kullu valley, Himachal Pradesh.

Contrasting occurrence of Chromobacterium violaceum in tropical drinking water springs of Uganda.

PubMed

Byamukama, Denis; Farnleitner, Andreas H; Kansiime, Frank; Manafi, Mohamad; Burtscher, Martina; Mach, Robert L

2005-09-01

Occurrence of Chromobacterium violaceum in six protected drinking water springs in Uganda was investigated. C. violaceum showed a contrasting occurrence, which was independent of human impact as assessed by faecal pollution indicators. It was isolated from two springs (S1 and S2) that were located close to each other (3 km) but not in the rest. In S1 C. violaceum was continuously detected, in concentrations ranging from 6 to 270 cfu 100 ml(-1), while in S2 it was detected on only one sampling occasion. C. violaceum was never detected in the investigated upper soil layers (down to 15 cm) in the immediate surroundings (50 m radius) of the springs, despite continued isolation of faecal indicators. The results of the study indicate that C. violaceum may not be ubiquitous in spring water, but could occur in significant numbers in particular potable groundwaters as an autochthonous member.

Radionuclides, inorganic constituents, organic compounds, and bacteria in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartholomay, R.C.; Edwards, D.D.; Campbell, L.J.

1993-11-01

The US Geological Survey and the Idaho Department of Water Resources, in response to a request from the US Department of Energy, sampled 18 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for manmade pollutants and naturally occurring constituents. The samples were collected from six irrigation wells, seven domestic wells, two springs, one stock well, one dairy well, and one observation well. Quality assurance samples also were collected and analyzed. Themore » water samples were analyzed for selected radionuclides, inorganic constituents, organic compounds, and bacteria. None of the samples analyzed for radionuclides, inorganic constituents, or organic compounds exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. All the samples analyzed for dissolved organic carbon had concentrations that exceeded their reporting level. Concentrations of 1,1,1 -trichloroethane exceeded the reporting level in two water samples. Two samples and a quality assurance replicate contained reportable concentrations of 2, 4-D. One sample contained fecal coliform bacteria counts that exceeded established maximum contaminant levels for drinking water.« less

Sediment microbial communities in Great Boiling Spring are controlled by temperature and distinct from water communities

PubMed Central

Cole, Jessica K; Peacock, Joseph P; Dodsworth, Jeremy A; Williams, Amanda J; Thompson, Daniel B; Dong, Hailiang; Wu, Geng; Hedlund, Brian P

2013-01-01

Great Boiling Spring is a large, circumneutral, geothermal spring in the US Great Basin. Twelve samples were collected from water and four different sediment sites on four different dates. Microbial community composition and diversity were assessed by PCR amplification of a portion of the small subunit rRNA gene using a universal primer set followed by pyrosequencing of the V8 region. Analysis of 164 178 quality-filtered pyrotags clearly distinguished sediment and water microbial communities. Water communities were extremely uneven and dominated by the bacterium Thermocrinis. Sediment microbial communities grouped according to temperature and sampling location, with a strong, negative, linear relationship between temperature and richness at all taxonomic levels. Two sediment locations, Site A (87–80 °C) and Site B (79 °C), were predominantly composed of single phylotypes of the bacterial lineage GAL35 (p̂=36.1%), Aeropyrum (p̂=16.6%), the archaeal lineage pSL4 (p̂=15.9%), the archaeal lineage NAG1 (p̂=10.6%) and Thermocrinis (p̂=7.6%). The ammonia-oxidizing archaeon ‘Candidatus Nitrosocaldus' was relatively abundant in all sediment samples <82 °C (p̂=9.51%), delineating the upper temperature limit for chemolithotrophic ammonia oxidation in this spring. This study underscores the distinctness of water and sediment communities in GBS and the importance of temperature in driving microbial diversity, composition and, ultimately, the functioning of biogeochemical cycles. PMID:23235293

Recent (2008-10) water quality in the Barton Springs segment of the Edwards aquifer and its contributing zone, central Texas, with emphasis on factors affecting nutrients and bacteria

USGS Publications Warehouse

Mahler, Barbara J.; Musgrove, MaryLynn; Sample, Thomas L.; Wong, Corinne I.

2011-01-01

The Barton Springs zone, which comprises the Barton Springs segment of the Edwards aquifer and the watersheds to the west that contribute to its recharge, is in south-central Texas, an area with rapid growth in population and increasing amounts of land area affected by development. During November 2008-March 2010, an investigation of factors affecting the fate and transport of nutrients and bacteria in the Barton Springs zone was conducted by the U.S. Geological Survey (USGS), in cooperation with the Texas Commission on Environmental Quality. The primary objectives of the study were to characterize occurrence of nutrients and bacteria in the Barton Springs zone under a range of flow conditions; to improve understanding of the interaction between surface-water quality and groundwater quality; and to evaluate how factors such as streamflow variability and dilution affect the fate and transport of nutrients and bacteria in the Barton Springs zone. The USGS collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge and Buda), and the main orifice of Barton Springs in Austin, Texas. During the period of the study, during which the hydrologic conditions transitioned from exceptional drought to wetter than normal, water samples were collected routinely (every 3 to 4 weeks) from the streams, wells, and spring and, in response to storms, from the streams and spring. All samples were analyzed for major ions, nutrients, the bacterium Escherichia coli, and suspended sediment. During the dry period, the geochemistry of groundwater at the two wells and at Barton Springs was dominated by flow from the aquifer matrix and was relatively similar and unchanging at the three sites. At the onset of the wet period, when the streams began to flow, the geochemistry of groundwater samples from the Marbridge well and Barton Springs changed rapidly, and concentrations of most major ions and nutrients and densities of Escherichia coli became more similar to those of samples from the streams relative to concentrations and densities during the dry period. Geochemical modeling indicated that the proportion of Barton Springs discharge composed of stream recharge increased from about 0-8 percent during the dry period to about 80 percent during the wet period. The transition from exceptional drought to wetter-than-normal conditions resulted in a number of marked changes that highlight factors affecting the fate and transport of nutrients and bacteria and the strong influence of stream recharge on water quality in the Barton Springs segment of the Edwards aquifer and had a pronounced effect on the fate of nitrogen species. Organic nitrogen loaded to and stored in soils during the dry period was nitrified to nitrate when the soils were rewetted, resulting in elevated concentrations of nitrate plus nitrite in streams as these constituents were progressively leached during continued wet weather. Estimated mean monthly loads of organic nitrogen and nitrate plus nitrite in stream recharge and Barton Springs discharge, which were relatively low and constant during the dry period, increased during the wet period. Loads of organic nitrogen, on average, were about six times greater in stream recharge than in Barton Springs discharge, indicating that organic nitrogen likely was being converted to nitrate within the aquifer. Loads of total nitrogen (organic nitrogen plus ammonia and nitrate plus nitrite) in stream recharge (162 kilograms per day) and in Barton Springs discharge (157 kilograms per day) for the period of the investigation were not significantly different. Dilution was not an important factor affecting concentrations of nitrate plus nitrite in the streams or in Barton Springs during the period of this investigation: Concentrations of nitrate plus nitrite did not decrease in streams with increasing stream discharge, and nitrate plus nitrite concentrations measured at Barton

Arsenic-contaminated cold-spring water in mountainous areas of Hui County, Northwest China: a new source of arsenic exposure.

PubMed

Zhang, Qiang; Zheng, Quanmei; Sun, Guifan

2011-11-15

Although pump-well is the primary drinking water source in rural areas of China, there are still 8.4% of villages reliant on cold-spring. In this study, a survey of arsenic concentration in cold-springs and pump-wells was carried out in Hui County, Northwest China. A total of 352 drinking water samples, including 177 cold-springs and 175 pump-wells, were collected. The maximum arsenic concentrations in cold-springs and pump-wells were 0.482 mg/L and 0.067 mg/L, respectively. We found that 15.8% (28) of total cold-springs and 1.1% (2) of total pump-wells had arsenic concentrations exceeding the maximum allowable concentration of arsenic in drinking water of rural China (0.05 mg/L). Our findings show that 5 cold spring-contaminated villages are located in the mountainous areas of Hui County and 2224 inhabitants may be at risk of high arsenic exposure. This paper indicates that arsenic contamination of cold-springs may be more serious than expected in mountainous areas of Northwest China and extensive surveys and epidemiological studies should be carried out to investigate the potential contaminated areas and affected population. Copyright © 2011 Elsevier B.V. All rights reserved.

Integrated Field Analyses of Thermal Springs

NASA Astrophysics Data System (ADS)

Shervais, K.; Young, B.; Ponce-Zepeda, M. M.; Rosove, S.

2011-12-01

A group of undergraduate researchers through the SURE internship offered by the Southern California Earthquake Center (SCEC) have examined thermal springs in southern Idaho, northern Utah as well as mud volcanoes in the Salton Sea, California. We used an integrated approach to estimate the setting and maximum temperature, including water chemistry, Ipad-based image and data-base management, microbiology, and gas analyses with a modified Giggenbach sampler.All springs were characterized using GISRoam (tmCogent3D). We are performing geothermometry calculations as well as comparisons with temperature gradient data on the results while also analyzing biological samples. Analyses include water temperature, pH, electrical conductivity, and TDS measured in the field. Each sample is sealed and chilled and delivered to a water lab within 12 hours.Temperatures are continuously monitored with the use of Solinst Levelogger Juniors. Through partnership with a local community college geology club, we receive results on a monthly basis and are able to process initial data earlier in order to evaluate data over a longer time span. The springs and mudpots contained microbial organisms which were analyzed using methods of single colony isolation, polymerase chain reaction, and DNA sequencing showing the impact of the organisms on the springs or vice versa. Soon we we will collect gas samples at sites that show signs of gas. This will be taken using a hybrid of the Giggenbach method and our own methods. Drawing gas samples has proven a challenge, however we devised a method to draw out gas samples utilizing the Giggenbach flask, transferring samples to glass blood sample tubes, replacing NaOH in the Giggenbach flask, and evacuating it in the field for multiple samples using a vacuum pump. We also use a floating platform devised to carry and lower a levelogger, to using an in-line fuel filter from a tractor in order to keep mud from contaminating the equipment.The use of raster imagery on the iPad2 has drastically changed how we plan and conduct our sampling trips. Orthoimagery onto the iPad2 is viewed with GISRoam and we use that imagery to help guide us toward points that we wish to visit. GISRoam was used to plot spatially correlated data points while in the field, estimate latitude and longitude, and record aforementioned data. A key factor to our success is up to the minute collaboration between all participants. Google's suite of services provides phone number for landowners, web site hosting, and the most crucial implementation for sharing data in real time has been the beta google Fusion Table. This spreadsheet allows for the incorporation of images, sample data and GPS location to be displayed as a kml file to be viewed in Google maps. This ability to modify and recognize data points in real time has made us more effective in the field, and in documenting progress in the lab. This workflow has enabled us to sample over 30 springs in 2 months, find 10 new springs, and estimate Tmax for 14 sites.By the end of 3 months we anticipate having water chemistry, isotope samples, gas samples, and Tmax determinations for 30 springs in the two study areas.

Origin of radon concentration of Csalóka Spring in the Sopron Mountains (West Hungary).

PubMed

Freiler, Ágnes; Horváth, Ákos; Török, Kálmán; Földes, Tamás

2016-01-01

We examined the Csalóka Spring, which has the highest radon concentration in the Sopron Mountains (West Hungary) (, yearly average of 227 ± 10 Bq L(-1)). The main rock types here are gneiss and micaschist, formed from metamorphism of former granitic and clastic sedimentary rocks respectively. The aim of the study was to find a likely source of the high radon concentration in water. During two periods (2007-2008 and 2012-2013) water samples were taken from the Csalóka Spring to measure its radon concentration (from 153 ± 9 Bq L(-1) to 291 ± 15 Bq L(-1)). Soil and rock samples were taken within a 10-m radius of the spring from debrish and from a deformed gneiss outcrop 500 m away from the spring. The radium activity concentration of the samples (between 24.3 ± 2.9 Bq kg(-1) and 145 ± 6.0 Bq kg(-1)) was measured by gamma-spectroscopy, and the specific radon exhalation was determined using radon-chamber measurements (between 1.32 ± 0.5 Bq kg(-1) and 37.1 ± 2.2 Bq kg(-1)). Based on these results a model calculation was used to determine the maximum potential radon concentration, which the soil or the rock may provide into the water. We showed that the maximum potential radon concentration of these mylonitic gneissic rocks (cpot = 2020 Bq L(-1)) is about eight times higher than the measured radon concentration in the water. However the maximum potential radon concentration for soils are significantly lower (41.3 Bq L(-1)) Based on measurements of radon exhalation and porosity of rock and soil samples we concluded that the source material can be the gneiss rock around the spring rather than the soil there. We determined the average radon concentration and the time dependence of the radon concentration over these years in the spring water. We obtained a strong negative correlation (-0.94 in period of 2007-2008 and -0.91 in 2012-2013) between precipitation and radon concentration. Copyright © 2015 Elsevier Ltd. All rights reserved.

Questa baseline and pre-mining ground-water quality investigation. 2. Low-flow (2001) and snowmelt (2002) synoptic/tracer water chemistry for the Red River, New Mexico

USGS Publications Warehouse

McCleskey, R. Blaine; Nordstrom, D. Kirk; Steiger, Judy I.; Kimball, Briant A.; Verplanck, Philip L.

2003-01-01

Water analyses are reported for 259 samples collected from the Red River, New Mexico, and its tributaries during low-flow(2001) and spring snowmelt (2002) tracer studies. Water samples were collected along a 20-kilometer reach of the Red River beginning just east of the town of Red River and ending at the U.S. Geological Survey streamflow-gaging station located east of Questa, New Mexico. The study area was divided into three sections where separate injections and synoptic sampling events were performed during the low-flow tracer study. During the spring snowmelt tracer study, three tracer injections and synoptic sampling events were performed bracketing the areas with the greatest metal loading into the Red River as determined from the low-flow tracer study. The lowflow tracer synoptic sampling events were August 17, 20, and 24, 2001. The synoptic sampling events for the spring snowmelt tracer were March 30, 31, and April 1, 2002. Stream and large inflow water samples were sampled using equal-width and depth-integrated sampling methods and composited into half-gallon bottles. Grab water samples were collected from smaller inflows. Stream temperatures were measured at the time of sample collection. Samples were transported to a nearby central processing location where pH and specific conductance were measured and the samples processed for chemical analyses. Cations, trace metals, iron redox species, and fluoride were analyzed at the U.S. Geological Survey laboratory in Boulder, Colorado. Cations and trace metal concentrations were determined using inductively coupled plasma-optical emission spectrometry and graphite furnace atomic absorption spectrometry. Arsenic concentrations were determined using hydride generation atomic absorption spectrometry, iron redox species were measured using ultraviolet-visible spectrometry, and fluoride concentrations were determined using an ion-selective electrode. Alkalinity was measured by automated titration, and sulfate, chloride, and bromide were analyzed by ion chromatography at the U.S. Geological Survey laboratory in Salt Lake City, Utah.

Sustainable Management of Springs and Associated Wetlands in Aridland Regions: A Water Quality Perspective for Cibola National Forest, NM

NASA Astrophysics Data System (ADS)

Paffett, K.; Crossey, L. J.; Crowley, L.; Karlstrom, K. E.

2010-12-01

In the arid southwestern U.S., springs and their associated wetlands provide an opportunity for diverse ecosystems to flourish. With increasing encroachment, multiple-use requirements and increasing groundwater depletion, a better understanding of how the springs function is needed in order to properly manage the springs as a resource. Critical data on spring status (discharge patterns across seasons and water quality) are lacking for most springs. New strategies and environmental sensors can be employed to provide baseline information, as well as continuous data. We report here on systematic evaluation of a suite of springs of the Cibola National Forest in central New Mexico, including characteristics of discharge and water quality. The work is prompted by concerns on preservation of vital habitat for the Zuni Bluehead Sucker in portions of the Cibola National Forest. Spring occurrence includes a range of elevation (2000-2500m), vegetation type (arid grasslands to alpine wilderness), impact (livestock use, increased groundwater withdrawal, species of concern, and increased recreational use), and water quality (potable to saline). Many of the springs occur along fault structures, and are fed by groundwater from confined aquifer systems. Two levels of protocols are described: Level One for developing a baseline survey for water quality in managed lands (geospatial data, geologic map, systematic photography, discharge estimate and field-determined water quality parameters); and Level Two Impact Evaluation Monitoring (includes high-resolution geologic mapping, major ion chemistry, multiple sampling dates, and real-time autonomous logging of several parameters including temperature, pH, conductance and dissolved oxygen). Data collected from the surveys are stored in a geospatial repository to serve as background for future monitoring of the water resources in the area.

Organic acids in cloud water and rainwater at a mountain site in acid rain areas of South China.

PubMed

Sun, Xiao; Wang, Yan; Li, Haiyan; Yang, Xueqiao; Sun, Lei; Wang, Xinfeng; Wang, Tao; Wang, Wenxing

2016-05-01

To investigate the chemical characteristics of organic acids and to identify their source, cloud water and rainwater samples were collected at Mount Lu, a mountain site located in the acid rain-affected area of south China, from August to September of 2011 and March to May of 2012. The volume-weighted mean (VWM) concentration of organic acids in cloud water was 38.42 μeq/L, ranging from 7.45 to 111.46 μeq/L, contributing to 2.50 % of acidity. In rainwater samples, organic acid concentrations varied from 12.39 to 68.97 μeq/L (VWM of 33.39 μeq/L). Organic acids contributed significant acidity to rainwater, with a value of 17.66 %. Formic acid, acetic acid, and oxalic acid were the most common organic acids in both cloud water and rainwater. Organic acids had an obviously higher concentration in summer than in spring in cloud water, whereas there was much less discrimination in rainwater between the two seasons. The contribution of organic acids to acidity was lower during summer than during spring in both cloud water (2.20 % in summer vs 2.83 % in spring) and rainwater (12.24 % in summer vs 19.89 % in spring). The formic-to-acetic acid ratio (F/A) showed that organic acids were dominated by primary emissions in 71.31 % of the cloud water samples and whole rainwater samples. Positive matrix factorization (PMF) analysis determined four factors as the sources of organic acids in cloud water, including biogenic emissions (61.8 %), anthropogenic emissions (15.28 %), marine emissions (15.07 %) and soil emissions (7.85 %). The findings from this study imply an indispensable role of organic acids in wet deposition, but organic acids may have a limited capacity to increase ecological risks in local environments.

Chemical characteristics, including stable-isotope ratios, of surface water and ground water from selected sources in and near East Fork Armells Creek basin, southeastern Montana, 1985

USGS Publications Warehouse

Ferreira, R.F.; Lambing, J.H.; Davis, R.E.

1989-01-01

Water samples were collected from 29 sites to provide synoptic chemical data, including stable-isotope ratios, for an area of active surface coal mining and to explore the effectiveness of using the data to chemically distinguish water from different aquifers. Surface-water samples were collected from one spring, four sites on East Armells Creek, one site on Stocker Creek, and two fly-ash ponds. Streamflows in East Fork Armells Creek ranged from no flow in several upstream reaches to 2.11 cu ft/sec downstream from Colstrip, Montana. Only one tributary, Stocker Creek, was observed to contribute surface flow in the study area. Groundwater samples were collected from wells completed in Quaternary alluvium or mine spoils, Rosebud overburden, Rosebud coal bed, McKay coal bed, and sub-McKay deposits of the Tongue River Member, Paleocene Fort Union Formation. Dissolved-solids concentrations, in mg/L, were 840 at the spring, 3,100 to 5,000 in the streams, 13,000 to 22,000 in the ash ponds, and 690 to 4 ,100 in the aquifers. With few exceptions, water from the sampled spring, streams, and wells had similar concentrations of major constituents and trace elements and similar stable-isotope ratios. Water from the fly-ash ponds had larger concentrations of dissolved solids, boron, and manganese and were isotopically more enriched in deuterium and oxygen-18 than water from other sources. Water from individual aquifers could not be distinguished by either ion-composition diagrams or statistical cluster analyses. (USGS)

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman Area, Idaho, 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

R. C. Bartholomay; L. M. Williams; L. J. Campbell

1998-12-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in cooperation with the U.S. Department of Energy, sampled 18 sites as part of the fourth round of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radiochemical and chemical constituents. The samples were collected from seven domestic wells, six irrigation wells, two springs, one dairy well, one observation well, and one stock well. Two quality-assurance samples also were collected andmore » analyzed. None of the radiochemical or chemical constituents exceeded the established maximum contaminant levels for drinking water. Many of the radionuclide- and inorganic-constituent concentrations were greater than their respective reporting levels.« less

A multi-disciplinary investigation of Irish warm springs and their potential for geothermal energy provision.

NASA Astrophysics Data System (ADS)

Blake, Sarah; Jones, Alan G.; Henry, Tiernan

2015-04-01

Irish warm springs are one of a set of several target types that are being evaluated for their geothermal energy potential during the course of the island-wide assessment of the geothermal energy potential of Ireland under the IRETHERM project (www.iretherm.ie). Forty-two warm springs and warm shallow groundwater occurrences have been recorded in Ireland; water temperatures in the springs (approx. 12-25 °C) are elevated with respect to average Irish groundwater temperatures (10-11 °C). This study focuses on warm springs in east-central Ireland found in the Carboniferous limestone of the Dublin Basin. A combination of geophysical methods (controlled source electromagnetics (CSEM) and audio-magnetotellurics (AMT)) and hydrochemical analyses (including time-lapse temperature and electrical conductivity measurements) have been utilised at several of the springs to determine the source of the heated waters at depth and the nature of the geological structures that deliver the warm waters to the surface. Using the example of St. Gorman's Well, Co. Meath, we show how the combination of these different methods of investigation and the interpretation of these various data sets enables us to better understand the physical and chemical variability of the spring through time. This will provide the basis for an assessment of the source of these thermal waters as a potential geothermal energy reservoir and will allow for more precise characterisation of the groundwater resource. We present subsurface models derived from new geophysical data collected at St. Gorman's Well in 2013. This high-resolution AMT survey consisted of a grid of 40 soundings recorded at approximately 200 m intervals centred on the spring. The aim of the survey was to image directly any (electrically conductive) fluid conduit systems that may be associated with the springs and to provide an understanding of the observed association of the Irish warm springs with major structural lineaments, such as the NE-SW Caledonian structural trend which dominates Irish geology. Seasonal hydrochemical sampling of six warm spring locations commenced in July 2013. Data loggers installed at each location measured temperature and electrical conductivity (15-minute sampling intervals) throughout the sampling period (July 2013 - early 2015). The hydrochemical results and the data from the logger at St. Gorman's Well are examined here in conjunction with regional rainfall and available hydrogeological information in order to establish the nature of the relationship between the hydrological cycle and fluctuations in the hydrochemistry of the spring.

Radionuclides, inorganic constitutents, organic compounds, and bacteria in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartholomay, R.C.; Edwards, D.D.; Campbell, L.J.

1994-11-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in response to a request from the U.S. Department of Energy, sampled 18 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radionuclides, inorganic constituents, organic compounds, and bacteria. The samples were collected from 13 irrigation wells, 1 domestic well, 1 spring, 2 stock wells, and 1 public supply well. Quality assurance samples also were collected and analyzed. Nonemore » of the samples analyzed for radionuclides, inorganic constituents, or organic compounds exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. Most of the samples analyzed for surfactants and dissolved organic carbon had concentrations that exceeded their reporting levels. None of the samples contained reportable concentrations of purgeable organic compounds or pesticides. Total coliform bacteria was present in nine samples.« less

Pioneering Techniques to Determine Wastewater and Urban Runoff Loads in Karst Spring Systems

NASA Astrophysics Data System (ADS)

Hasenmueller, E. A.; Criss, R. E.

2010-12-01

Comparison of urban and rural springs quantifies the magnitude and sources of water quality degradation in east-central Missouri. Urban springs consistently display a suite of impairment characteristics including increases in: (1) specific conductance; (2) coliform bacteria; (3) total suspended solids (TSS); (4) nutrient concentrations including N, P, and S species; (5) B concentration; (6) heavy metal concentrations such as Cd, Cr, and Pb; and (7) temperature variability. Several dozen springs, representing a range in magnitude and recharge area land use, were sampled in and around St. Louis, MO. In addition, effluent from the Duckett Creek Treatment Plant was sampled to ascertain the chemistry of municipal waste waters in the area. Sodium perborate is a primary ingredient in bleaching agents for detergents, and therefore B is found in very high concentrations in waste waters (> 240 ppb) compared to background levels (< 20 ppb) in carbonate-hosted springs. Consequently, B provides an excellent, conservative tracer of sewage contributions to groundwater systems, and this study has shown that several urban springs comprise > 25% waste water. High B concentrations correlate well with increased nutrient contents and high E. coli and total coliform levels, which also suggest large sewage contributions to the shallow groundwater. Elevated specific conductance in these springs is primarily due to road salt contamination of these Ca-Mg-bicarbonate waters. In marked contrast to natural springs, Na and Cl can even be the dominant ions in urban springs, so they are useful indicators of urban runoff. High concentrations of Na and Cl ions persist well into late summer, confirming stable isotope models for the ~ 1 year residence time of these shallow groundwaters. Further, specific conductance, temperature, and TSS are highly variable in urban springs because of amplified throughput of storm water runoff; in fact, many detention basins directly feed into cave systems. Dissolved oxygen (DO) and pH are useful indicators of the nature of subsurface groundwater environments. In particular, springs with no known cave passage typically have low DO and pH (< 60% saturation and < 7.7, respectively), as is common in goundwaters that do not communicate with the atmosphere. However, springs draining open cave systems have higher DO and pH (60 - 90% saturation and > 7.7, respectively) due to the equilibration of DO with the overlying cave atmosphere and the degassing of carbon dioxide. This pair of parameters might provide a novel means to detect undiscovered caves.

Water-chemistry data for selected springs, geysers, and streams in Yellowstone National Park, Wyoming, 2006-2008

USGS Publications Warehouse

Ball, James W.; McMleskey, R. Blaine; Nordstrom, D. Kirk

2010-01-01

Water analyses are reported for 104 samples collected from numerous thermal and non-thermal features in Yellowstone National Park (YNP) during 2006-2008. Water samples were collected and analyzed for major and trace constituents from 10 areas of YNP including Apollinaris Spring and Nymphy Creek along the Norris-Mammoth corridor, Beryl Spring in Gibbon Canyon, Norris Geyser Basin, Lower Geyser Basin, Crater Hills, the Geyser Springs Group, Nez Perce Creek, Rabbit Creek, the Mud Volcano area, and Washburn Hot Springs. These water samples were collected and analyzed as part of research investigations in YNP on arsenic, antimony, iron, nitrogen, and sulfur redox species in hot springs and overflow drainages, and the occurrence and distribution of dissolved mercury. Most samples were analyzed for major cations and anions, trace metals, redox species of antimony, arsenic, iron, nitrogen, and sulfur, and isotopes of hydrogen and oxygen. Analyses were performed at the sampling site, in an on-site mobile laboratory vehicle, or later in a U.S. Geological Survey laboratory, depending on stability of the constituent and whether it could be preserved effectively. Water samples were filtered and preserved on-site. Water temperature, specific conductance, pH, emf (electromotive force or electrical potential), and dissolved hydrogen sulfide were measured on-site at the time of sampling. Dissolved hydrogen sulfide was measured a few to several hours after sample collection by ion-specific electrode on samples preserved on-site. Acidity was determined by titration, usually within a few days of sample collection. Alkalinity was determined by titration within 1 to 2 weeks of sample collection. Concentrations of thiosulfate and polythionate were determined as soon as possible (generally a few to several hours after sample collection) by ion chromatography in an on-site mobile laboratory vehicle. Total dissolved iron and ferrous iron concentrations often were measured on-site in the mobile laboratory vehicle. Concentrations of dissolved aluminum, arsenic, boron, barium, beryllium, calcium, cadmium, cobalt, chromium, copper, iron, potassium, lithium, magnesium, manganese, molybdenum, sodium, nickel, lead, selenium, silica, strontium, vanadium, and zinc were determined by inductively coupled plasma-optical emission spectrometry. Trace concentrations of dissolved antimony, cadmium, cobalt, chromium, copper, lead, and selenium were determined by Zeeman-corrected graphite-furnace atomic-absorption spectrometry. Dissolved concentrations of total arsenic, arsenite, total antimony, and antimonite were determined by hydride generation atomic-absorption spectrometry using a flow-injection analysis system. Dissolved concentrations of total mercury and methylmercury were determined by cold-vapor atomic fluorescence spectrometry. Concentrations of dissolved chloride, fluoride, nitrate, bromide, and sulfate were determined by ion chromatography. For many samples, concentrations of dissolved fluoride also were determined by ion-specific electrode. Concentrations of dissolved ferrous and total iron were determined by the FerroZine colorimetric method. Concentrations of dissolved ammonium were determined by ion chromatography, with reanalysis by colorimetry when separation of sodium and ammonia peaks was poor. Dissolved organic carbon concentrations were determined by the wet persulfate oxidation method. Hydrogen and oxygen isotope ratios were determined using the hydrogen and CO2 equilibration techniques, respectively.

[Space-time water monitoring system at the Iriklinsk hydroelectric power station].

PubMed

Deriabin, D G; Poliakov, E G; Priakhina, A A; Karimov, I F

2002-01-01

The Microbiosensor B 17677 F test system was applied to make a space-time monitoring of the biotoxicity of water used for production and everyday purposes at the Iriklinsk hydroelectric power station (IHEPS) and to identify the leading causes determining the biotoxicity of tested samples. There were seasonal variations in the biotoxicity with the maximum in spring and with minimum in winter and spring and a relationship of the spring rise in the biotoxicity to water pH changes. There was also an association of the certain values of the biotoxicity of industrial water with the concentration of petroleum products that are major pollutants at the IHEPS. The datum points that characterize the maximum level of technogenic exposure were identified.

Concentration of organic contaminants in fish and their biological effects in a wastewater-dominated urban stream

USGS Publications Warehouse

Lozano, Nuria; Rice, Clifford P.; Pagano, James; Zintek, Larry; Barber, Larry B.; Murphy, Elizabeth W.; Nettesheim, Todd G.; Minarik, Thomas A.; Schoenfuss, Heiko L.

2012-01-01

Data are presented on the concentrations of alkylphenol and alkylphenol ethoxylates (APEs) and persistent organic compounds in largemouth bass collected from a waste-water dominated stream in downtown Chicago. The fish residue concentrations of APEs are compared to concentrations of the APEs in the water that were collected at weekly intervals over two months bracketing the fall (2006) and a spring (2007) fish collection. The concentrations of APEs were significantly higher in the spring-collected fish (5.42 μg/g) versus the fall (0.99 μg/g) tand these differences were shared by differences in the water concentrations (spring — 11.47 versus fall — 3.44 μg/L). The differences in water concentration were negatively correlated with water temperatures observed over the two sampling times. Fish residue concentrations of persistent organic compounds (PCBs, PBDEs, toxaphene, and many legacy pesticides including the DDT family) did not vary from fall to spring. Some of these residue concentrations were comparable to the highest NPE (nonylphenol ethoxylate) homologue concentrations, e.g. NP1EO was 3.5 μg/g in the bass for the spring, the PBDE-congener 47 and p,p′-DDE averaged 1.0 μg/g and 0.5 μg/g, respectively, over both seasons. All the other persistent single-analyte concentrations were lower. Biological endpoints for endocrine effects measured in the same fish showed that there was an apparent positive correlation for physiological effects based on increased vitellogenin levels in males versus concentration of NPEs; however there were no observable histological differences in fall versus spring fish samples.

Hydrology and Water Quality of the Grand Portage Reservation, Northeastern Minnesota, 1991-2000

USGS Publications Warehouse

Winterstein, Thomas A.

2002-01-01

Measured tritium and sulfur hexafluoride (SF6) concentrations in water samples from springs and wells were used to determine the recharge age of the sampled water. The recharge ages of two of the wells sampled for tritium are before 1953. The recharge ages of the remaining 10 samples for tritium are probably after 1970. The recharge ages of seven SF6 samples were between 1973 and 1998.

Rotenone persistence in freshwater ponds: Effects of temperature and sediment adsorption

USGS Publications Warehouse

Dawson, V.K.; Gingerich, W.H.; Davis, R.A.; Gilderhus, P.A.

1991-01-01

The persistence of rotenone was compared between a cement-lined pond (0.04 hectare) and an earthen-bottom pond (0.02 hectare) treated with 5 I?L Noxfish/L (250 I?g rotenone/L) during spring, summer, and fall. Water temperatures on the days of treatment in each season were 8, 22, and 15A?C, respectively. Both ponds were filled with pond water from a common source 1 week before each of the three treatments. Water samples (filtered and unfiltered) and sediment samples were analyzed by high-performance liquid chromatography to monitor the decrease of rotenone until residues were at or below the detection limit (<2.0 I?g/L for water and < 25 ng/g for sediments). The loss of rotenone from water generally followed a first-order rate ofdecay. Rotenone disappeared two to three times faster in the earthen pond than in the concrete pond. The rotenone half-life times in the spring, summer, and fall treatments were 3.7, 1.3, and 5.2 d, respectively, in the concrete pond, and 1.8, 0.7, and 1.8 d in the earthen pond. Rates of decay in both ponds were directly correlated with water temperature. Filtered water samples from both ponds contained less rotenone than unfiltered water, indicating that some rotenone was bound to suspended material. The highest concentration of rotenone in sediment samples was 102 ng/g; residues decreased to below the detection limit within 14 d in the spring treatment and within 3 d in the summer and fall treatments.

Radon Levels Measured at a Touristic Thermal Spa Resort in Montagu (South Africa) and Associated Effective Doses.

PubMed

Botha, R; Newman, R T; Maleka, P P

2016-09-01

Radon activity concentrations (in water and in air) were measured at 13 selected locations at the Avalon Springs thermal spa resort in Montagu (Western Cape, South Africa) to estimate the associated effective dose received by employees and visitors. A RAD-7 detector (DURRIDGE), based on alpha spectrometry, and electret detectors (E-PERM®Radelec) were used for these radon measurements. The primary source of radon was natural thermal waters from the hot spring, which were pumped to various locations on the resort, and consequently a range of radon in-water analyses were performed. Radon in-water activity concentration as a function of time (short term and long term measurements) and spatial distributions (different bathing pools, etc.) were studied. The mean radon in-water activity concentrations were found to be 205 ± 6 Bq L (source), 112 ± 5 Bq L (outdoor pool) and 79 ± 4 Bq L (indoor pool). Radon in-air activity concentrations were found to range between 33 ± 4 Bq m (at the outside bar) to 523 ± 26 Bq m (building enclosing the hot spring's source). The most significant potential radiation exposure identified is that due to inhalation of air rich in radon and its progeny by the resort employees. The annual occupational effective dose due to the inhalation of radon progeny ranges from 0.16 ± 0.01 mSv to 0.40 ± 0.02 mSv. For the water samples collected, the Ra in-water activity concentrations from samples collected were below the lower detection limit (~0.7 Bq L) of the γ-ray detector system used. No significant radiological health risk can be associated with radon and progeny from the hot spring at the Avalon Springs resort.

Radionuclides, stable isotopes, inorganic constituents, and organic compounds in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartholomay, R.C.; Williams, L.M.; Campbell, L.J.

1995-10-01

The US Geological Survey and the Idaho Department of Water Resources, in response to a request from the US Department of Energy, samples 18 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radionuclides, stable isotopes, inorganic constituents, and organic compounds. The samples were collected from seven irrigation wells, seven domestic wells, two springs, one stock well, and one observation well. Two quality assurance samples also were collected and analyzed.more » None of the radionuclide, inorganic constituent, or organic compound concentrations exceeded the established maximum contaminant levels for drinking water. Many of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. All samples analyzed for dissolved organic carbon had concentrations that exceeded their minimum reporting levels.« less

Radionuclides, stable isotopes, inorganic constituents, and organic compounds in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartholomay, R.C.; Williams, L.M.; Campbell, L.J.

1996-09-01

The US Geological Survey and the Idaho Department of Water Resources, in cooperation with the US Department of Energy, sampled 17 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radionuclides, stable isotopes, inorganic constituents, and organic compounds. The samples were collected from 11 irrigation wells, 2 domestic wells, 2 stock wells, 1 spring, and 1 public-supply well. Two quality assurance samples also were collected and analyzed. None of themore » radionuclide, inorganic constituents, or organic compound concentrations exceeded the established maximum contaminant levels for drinking water. Many of the radionuclide and inorganic constituent concentrations were greater than their respective reporting levels. All samples analyzed for dissolved organic carbon had concentrations that were greater than the minimum reporting level.« less

Geochemical characterization of groundwater discharging from springs north of the Grand Canyon, Arizona, 2009–2016

USGS Publications Warehouse

Beisner, Kimberly R.; Tillman, Fred D.; Anderson, Jessica R.; Antweiler, Ronald C.; Bills, Donald J.

2017-08-01

A geochemical study was conducted on 37 springs discharging from the Toroweap Formation, Coconino Sandstone, Hermit Formation, Supai Group, and Redwall Limestone north of the Grand Canyon near areas of breccia-pipe uranium mining. Baseline concentrations were established for the elements As, B, Li, Se, SiO2, Sr, Tl, U, and V. Three springs exceeded U.S. Environmental Protection Agency drinking water standards: Fence Spring for arsenic, Pigeon Spring for selenium and uranium, and Willow (Hack) Spring for selenium. The majority of the spring sites had uranium values of less than 10 micrograms per liter (μg/L), but six springs discharging from all of the geologic units studied that are located stratigraphically above the Redwall Limestone had uranium values greater than 10 μg/L (Cottonwood [Tuckup], Grama, Pigeon, Rock, and Willow [Hack and Snake Gulch] Springs). The geochemical characteristics of these six springs with elevated uranium include Ca-Mg-SO4 water type, circumneutral pH, high specific conductance, correlation and multivariate associations between U, Mo, Sr, Se, Li, and Zn, low 87Sr/86Sr, low 234U/238U activity ratios (1.34–2.31), detectable tritium, and carbon isotopic interpretation indicating they may be a mixture of modern and pre-modern waters. Similar geochemical compositions of spring waters having elevated uranium concentrations are observed at sites located both near and away from sites of uranium-mining activities in the present study. Therefore, mining does not appear to explain the presence of elevated uranium concentrations in groundwater at the six springs noted above. The elevated uranium at the six previously mentioned springs may be influenced by iron mineralization associated with mineralized breccia pipe deposits. Six springs discharging from the Coconino Sandstone (Upper Jumpup, Little, Horse, and Slide Springs) and Redwall Limestone (Kanab and Side Canyon Springs) contained water with corrected radiocarbon ages as much as 9,300 years old. Of the springs discharging water with radiocarbon age, Kanab and Side Canyon Springs contain tritium of more than 1.3 picocuries per liter (pCi/L), indicating they may contain a component of modern water recharged after 1952. Springs containing high values of tritium (greater than 5.1 pCi/L), which may suggest a significant component of modern water, include Willow (Hack), Saddle Horse, Cottonwood (Tuckup), Hotel, Bitter, Unknown, Hole in the Wall, and Hanging Springs. Fence and Rider Springs, located on the eastern end of the study area near the Colorado River, have distinctly different geochemical compositions compared to the other springs of the study. Additionally, water from Fence Spring has the highest 87Sr/86Sr for samples analyzed from this study with a value greater than those known in sedimentary rocks from the region. Strontium isotope data likely indicate that water discharging at Fence Spring has interacted with Precambrian basement rocks. Rider Spring had the most depleted values of stable O and H isotopes indicating that recharge, if recent, occurred at higher elevations or was recharged during earlier, cooler-climate conditions.

Water-quality and ground-water-level trends, 1990-99, and data collected from 1995 through 1999, East Mountain area, Bernalillo County, central New Mexico

USGS Publications Warehouse

Rankin, D.R.

2000-01-01

Bernalillo County officials recognize the importance of monitoring water quality and ground-water levels in rapidly developing areas. For this reason, water-quality and ground-water- level data were collected from 87 wells, 3 springs, and the Ojo Grande Acequia in the east mountain area of Bernalillo County between January 1990 and June 1999. The water samples were analyzed for selected nutrient species; total organic carbon; major dissolved constituents; methylene blue active substances; and dissolved arsenic. Analytical results were used to compute hardness, sodium adsorption ratio, and dissolved solids. Specific conductance, pH, air and water temperature, alkalinity, and dissolved oxygen were measured in the field at the time of sample collection. Ground-water levels were measured at the time of sample collection. From January 1990 through June 1993, water-quality and ground- water-level data were collected monthly from an initial set of 20 wells; these data were published in a 1995 report. During 1995, water samples and ground-water-level data were collected and analyzed from the initial set of 20 wells and from an additional 31 wells, 2 springs, and the Ojo Grande Acequia; these data were published in a 1996 report. Additional water-quality and ground-water-level data have been collected from sites in the east mountain area: 34 wells and the acequia during 1997, 14 wells and 1 spring during 1998, and 6 wells during 1999. Water-quality and ground- water-level data collected in the east mountain area during 1995 through 1999 are presented in tables. In addition, temporal trends for ground-water levels, concentrations of total and dissolved nitrite plus nitrate, concentrations of dissolved chloride, and specific conductance are presented for 20 selected wells in water-quality and water- level hydrographs.

Microbial source tracking in highly vulnerable karst drinking water resources.

PubMed

Diston, D; Robbi, R; Baumgartner, A; Felleisen, R

2018-02-01

Water resources situated in areas with underlying karst geology are particularly vulnerable to fecal pollution. In such vulnerable systems, microbial source tracking (MST) methods are useful tools to elucidate the pathways of both animal and human fecal pollution, leading to more accurate water use risk assessments. Here, we describe the application of a MST toolbox using both culture-dependent bacteriophage and molecular-dependent 16S rRNA assays at spring and well sites in the karstic St Imier Valley, Switzerland. Culture-dependent and molecular-dependent marker performance varied significantly, with the 16S rRNA assays displaying greater sensitivity than their phage counterpart; HF183 was the best performing human wastewater-associated marker while Rum2Bac was the best performing ruminant marker. Differences were observed in pollution regimes between the well and spring sampling sites, with the spring water being more degraded than the well site. Our results inform the choice of marker selection for MST studies and highlight differences in microbial water quality between well and spring karst sites.

Occurrence of multi-antibiotic resistant Pseudomonas spp. in drinking water produced from karstic hydrosystems.

PubMed

Flores Ribeiro, Angela; Bodilis, Josselin; Alonso, Lise; Buquet, Sylvaine; Feuilloley, Marc; Dupont, Jean-Paul; Pawlak, Barbara

2014-08-15

Aquatic environments could play a role in the spread of antibiotic resistance genes by enabling antibiotic-resistant bacteria transferred through wastewater inputs to connect with autochthonous bacteria. Consequently, drinking water could be a potential pathway to humans and animals for antibiotic resistance genes. The aim of this study was to investigate occurrences of Escherichia coli and Pseudomonas spp. in drinking water produced from a karst, a vulnerable aquifer with frequent increases in water turbidity after rainfall events and run-offs. Water samples were collected throughout the system from the karstic springs to the drinking water tap during three non-turbid periods and two turbid events. E. coli densities in the springs were 10- to 1000-fold higher during the turbid events than during the non-turbid periods, indicating that, with increased turbidity, surface water had entered the karstic system and contaminated the spring water. However, no E. coli were isolated in the drinking water. In contrast, Pseudomonas spp. were isolated from the drinking water only during turbid events, while the densities in the springs were from 10- to 100-fold higher than in the non-turbid periods. All the 580 Pseudomonas spp. isolates obtained from the sampling periods were resistant (to between 1 and 10 antibiotics), with similar resistance patterns. Among all the Pseudomonas isolated throughout the drinking water production system, between 32% and 86% carried the major resistance pattern: ticarcillin, ticarcillin-clavulanic acid, cefsulodin, and/or aztreonam, and/or sulfamethoxazol-trimethoprim, and/or fosfomycin. Finally, 8 Pseudomonas spp. isolates, related to the Pseudomonas putida and Pseudomonas fluorescens species, were isolated from the drinking water. Thus, Pseudomonas could be involved in the dissemination of antibiotic resistance via drinking water during critical periods. Copyright © 2014 Elsevier B.V. All rights reserved.

Occurrence of Naegleria species in therapeutic geothermal water sources, Northern Iran.

PubMed

Latifi, Ali Reza; Niyyati, Maryam; Lorenzo-Morales, Jacob; Haghighi, Ali; Tabaei, Seyyed Javad Seyyed; Lasjerdi, Zohreh; Azargashb, Eznolah

2017-03-01

Potentially pathogenic Free-Living Amoebae include members belonging to Naegleria genus. The species N. fowleri is known worldwide as the causative agent of the lethal Primary Amoebic Meningoencephalitis (PAM). Only one clinical case of N. fowleri has been reported in Iran. Several species of Naegleria have been reported to be natural carriers of other potentially pathogenic microbial agents. The thermotolerance properties of this genus facilitates their presence in geothermal water sources including hot springs and spas. In the current study water samples were collected from 22 therapeutic hot springs, Northern Iran and investigated for the presence of Naegleria spp. using morphological keys and PCR/DNA sequencing based methods. Incubation of collected samples were done at both 30°C and 45°C in order to detect Naegleria spp. and N. fowleri, respectively. Thermotolerance assay and flagellation tests were also performed. The obtained results revealed that 54% of the investigated water samples were positive for Naegleria spp. including N. australiensis, N. americana, N. dobsoni, N. pagei, N. polaris and N. fultoni. The pathogenic N. fowleri was not detected. The most detected Naegleria was belonged to N. australiensis. This is the first report on the Naegleria spp. occurrence in hot springs in Northern Iran showing that most of the surveyed hot spring sources were contaminated with non-pathogenic Naegleria spp. However, due to the recent report of PAM in the country, further studies to investigate the presence of pathogenic N. fowleri in the environment and clinical samples is needed in the region and worldwide.

Microbial communities and arsenic biogeochemistry at the outflow of an alkaline sulfide-rich hot spring.

PubMed

Jiang, Zhou; Li, Ping; Van Nostrand, Joy D; Zhang, Ping; Zhou, Jizhong; Wang, Yanhong; Dai, Xinyue; Zhang, Rui; Jiang, Dawei; Wang, Yanxin

2016-04-29

Alkaline sulfide-rich hot springs provide a unique environment for microbial community and arsenic (As) biogeochemistry. In this study, a representative alkaline sulfide-rich hot spring, Zimeiquan in the Tengchong geothermal area, was chosen to study arsenic geochemistry and microbial community using Illumina MiSeq sequencing. Over 0.26 million 16S rRNA sequence reads were obtained from 5-paired parallel water and sediment samples along the hot spring's outflow channel. High ratios of As(V)/AsSum (total combined arsenate and arsenite concentrations) (0.59-0.78), coupled with high sulfide (up to 5.87 mg/L), were present in the hot spring's pools, which suggested As(III) oxidation occurred. Along the outflow channel, AsSum increased from 5.45 to 13.86 μmol/L, and the combined sulfide and sulfate concentrations increased from 292.02 to 364.28 μmol/L. These increases were primarily attributed to thioarsenic transformation. Temperature, sulfide, As and dissolved oxygen significantly shaped the microbial communities between not only the pools and downstream samples, but also water and sediment samples. Results implied that the upstream Thermocrinis was responsible for the transformation of thioarsenic to As(III) and the downstream Thermus contributed to derived As(III) oxidation. This study improves our understanding of microbially-mediated As transformation in alkaline sulfide-rich hot springs.

Microbial community composition and endolith colonization at an Arctic thermal spring are driven by calcite precipitation

USGS Publications Warehouse

Starke, Verena; Kirshtein, Julie; Fogel, Marilyn L.; Steele, Andrew

2013-01-01

Environmental conditions shape community composition. Arctic thermal springs provide an opportunity to study how environmental gradients can impose strong selective pressures on microbial communities and provide a continuum of niche opportunities. We use microscopic and molecular methods to conduct a survey of microbial community composition at Troll Springs on Svalbard, Norway, in the high Arctic. Microorganisms there exist under a wide range of environmental conditions: in warm water as periphyton, in moist granular materials, and in cold, dry rock as endoliths. Troll Springs has two distinct ecosystems, aquatic and terrestrial, together in close proximity, with different underlying environmental factors shaping each microbial community. Periphyton are entrapped during precipitation of calcium carbonate from the spring's waters, providing microbial populations that serve as precursors for the development of endolithic communities. This process differs from most endolith colonization, in which the rock predates the communities that colonize it. Community composition is modulated as environmental conditions change within the springs. At Troll, the aquatic environments show a small number of dominant operational taxonomic units (OTUs) that are specific to each sample. The terrestrial environments show a more even distribution of OTUs common to multiple samples.

Uranium hydrogeochemical and stream sediment reconnaissance of the Newcastle NTMS quadrangle, Wyoming, including concentrations of forty-two additional elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goff, S.J.; Sandoval, W.F.; Gallimore, D.L.

1980-06-01

During the summer and fall of 1977, 533 water and 1226 sediment samples were collected from 1740 locations within the 18,000 km/sup 2/ area of the Newcastle quadrangle, Wyoming. Water samples were collected from wells and springs; sediment samples were collected from stream channels and from springs. Each water sample was analyzed for uranium, and each sediment sample was analyzed for 43 elements, including uranium and thorium. Uranium concentrations in water samples range from below the detection limit of 0.02 ppB to 702.26 ppB and have a median of 1.73 ppB and a mean of 11.76 ppB. Water samples containingmore » high uranium concentrations (>20 ppB) generally are associated with known uranium mining activity or units known to be uranium bearing. About one-third of the water samples containing high uranium concentrations were collected from locations within the Pumpkin Buttes and Turnercrest-Ross Districts. Nearly half of the water samples containing high uranium concentrations were collected from locations just west of the Monument Hill and Highland Flats-Box Creek Districts. Similar anomalous uranium concentrations in this region have been reported updip from Exxon's Highland uranium deposits. High uranium concentrations were also found associated with the Lance Creek-Old Woman Anticline District.« less

Mercury in water and biomass of microbial communities in hot springs of Yellowstone National Park, USA

USGS Publications Warehouse

King, S.A.; Behnke, S.; Slack, K.; Krabbenhoft, D.P.; Nordstrom, D. Kirk; Burr, M.D.; Striegl, Robert G.

2006-01-01

Ultra-clean sampling methods and approaches typically used in pristine environments were applied to quantify concentrations of Hg species in water and microbial biomass from hot springs of Yellowstone National Park, features that are geologically enriched with Hg. Microbial populations of chemically-diverse hot springs were also characterized using modern methods in molecular biology as the initial step toward ongoing work linking Hg speciation with microbial processes. Molecular methods (amplification of environmental DNA using 16S rDNA primers, cloning, denatured gradient gel electrophoresis (DGGE) screening of clone libraries, and sequencing of representative clones) were used to examine the dominant members of microbial communities in hot springs. Total Hg (THg), monomethylated Hg (MeHg), pH, temperature, and other parameters influential to Hg speciation and microbial ecology are reported for hot springs water and associated microbial mats. Several hot springs indicate the presence of MeHg in microbial mats with concentrations ranging from 1 to 10 ng g-1 (dry weight). Concentrations of THg in mats ranged from 4.9 to 120,000 ng g-1 (dry weight). Combined data from surveys of geothermal water, lakes, and streams show that aqueous THg concentrations range from l to 600 ng L-1. Species and concentrations of THg in mats and water vary significantly between hot springs, as do the microorganisms found at each site. ?? 2006.

Factors affecting temporal and spatial variations of Arsenic (III) and (V) in the geothermally impacted Jemez river, NM.

NASA Astrophysics Data System (ADS)

Hansson, L.

2015-12-01

Arsenic (As) in surface waters and groundwater is of global concern due to its potential negative impact on human health and eco systems. Due to the high leaching capacity of hot waters, geothermal waters in areas with As-rich bedrock, often contain high concentrations of As. This water can reach the surface through fractures and cracks that manifest through diffuse seeps and hot springs. The Soda Dam area in the Jemez Mountains of northwestern NM, with frequent hot springs and seeps, has long been of interest due to the hot spring's high discharge (1500L/s) of geothermal waters into the Jemez River. Although the species of As highly controls its mobility and toxicity, previous studies have focused exclusively on the total amounts of As in the waters, while little is known about the species occurring along the river. We collected water and "sediment" from 14 sites along the Jemez river to study factors governing spatial and temporal variations of As in hot springs and river water; the interrelationship between As(III) and As(V) and to calculate mass flows during the summer monsoon months of 2015. We found that As(V) is the dominant species along the river stretch of interest except for in the hot springs. As(III) occurs at all sites, and the fraction of total As(III) varies both on a spatial and temporal scale, ranging between 1-7 % upstream of Soda Dam, and 12 - 21 % below it. We also found that hot spring water in the beginning of the southwest monsoon season only contains As(III), but further into the season explicitly As(V), possibly due to a heavy rainfall occurring two days before sampling. The fraction of As(III) correlates well with alkalinity (R2 =0.98-0.59) and temperature (R2 = 0.86-0.46) although differently at different sampling occasions. Since As(III) is generally more toxic and mobile in water than As(V), our results emphasizes that risks associated with As may change over the season due to season-related changes in As speciation.

Annual summary of ground-water conditions in Arizona, spring 1982 to spring 1983

USGS Publications Warehouse

,

1984-01-01

The withdrawal of ground water was slightly less than 4.2 million acre-feet in Arizona in 1982, which is about 1.2 million acre-feet less than the amount withdrawn in 1981. Most of the decrease in 1982 was in the amount of ground water used for irrigation in the Basin and Range lowlands province. Through 1982, slightly more than 193 million acre-feet of ground water had been withdrawn from the ground-water reservoirs in Arizona. The report contains three small-scale maps that show ground-water pumpage by areas, the status of the ground-water inventory and observation-well program, and the ground-water quality sampling program. The main map, which is at a scale of 1:500,000, shows potential well production, depth to water in selected wells in spring 1983, and change in water level in selected wells from 1978 to 1983. A brief text summarizes the current ground-water conditions in the State. (USGS)

Hydrologic and geochemical monitoring in Long Valley Caldera, Mono County, California, 1985

USGS Publications Warehouse

Farrar, C.D.; Sorey, M.L.; Rojstaczer, S.A.; Janik, C.J.; Winnett, T.L.; Clark, M.D.

1987-01-01

Hydrologic and geochemical monitoring, to detect changes caused by magmatic and tectonic processes in the Long Valley caldera has continued through 1985. The monitoring included the collection of the following types of data: chemical and isotopic composition of water and gases from springs, wells, and steam vents; temperatures in wells, springs, and steam vents; flow rates of springs and streams; water levels in wells; and barometric pressure and precipitation at several sites. In addition, reservoir temperatures for the geothermal system were estimated from computations based on chemical geothermometers applied to fluid samples from wells and springs. Estimates of thermal water discharged from springs were made on the basis of boron and chloride fluxes in surface waters for selected sites in the Casa Diablo area and along the Mammoth-Hot Creek drainage. These data are presented in tables and graphs. The Long Valley area was relatively quiescent throughout 1985 in terms of geodetic changes and seismic activity. As a consequence , the hydrologic system varied mainly in response to seasonal influences of temperature, atmospheric pressure, and precipitation. However, spring flows near Casa Diablo were influenced by pumping at the geothermal production well field nearby. (Author 's abstract)

Greater temporal changes of sediment microbial community than its waterborne counterpart in Tengchong hot springs, Yunnan Province, China

PubMed Central

Wang, Shang; Dong, Hailiang; Hou, Weiguo; Jiang, Hongchen; Huang, Qiuyuan; Briggs, Brandon R.; Huang, Liuqin

2014-01-01

Temporal variation in geochemistry can cause changes in microbial community structure and diversity. Here we studied temporal changes of microbial communities in Tengchong hot springs of Yunnan Province, China in response to geochemical variations by using microbial and geochemical data collected in January, June and August of 2011. Greater temporal variations were observed in individual taxa than at the whole community structure level. Water and sediment communities exhibited different temporal variation patterns. Water communities were largely stable across three sampling times and dominated by similar microbial lineages: Hydrogenobaculum in moderate-temperature acidic springs, Sulfolobus in high-temperature acidic springs, and Hydrogenobacter in high-temperature circumneutral to alkaline springs. Sediment communities were more diverse and responsive to changing physicochemical conditions. Most of the sediment communities in January and June were similar to those in waters. However, the August sediment community was more diverse and contained more anaerobic heterotrophs than the January and June: Desulfurella and Acidicaldus in moderate-temperature acidic springs, Ignisphaera and Desulfurococcus in high-temperature acidic springs, the candidate division OP1 and Fervidobacterium in alkaline springs, and Thermus and GAL35 in neutral springs. Temporal variations in physicochemical parameters including temperature, pH, and dissolved organic carbon may have triggered the observed microbial community shifts. PMID:25524763

Ground-water levels and water-quality data for wells in the Spring Creek area near Arnold Air Force Base, Tennessee, April and May 2000

USGS Publications Warehouse

Williams, Shannon D.; Aycock, Robert A.

2001-01-01

Arnold Air Force Base (AAFB) occupies about 40,000 acres in Coffee and Franklin Counties, Tennessee. Numerous site-specific ground-water contamination investigations have been conducted at designated solid waste management units (SWMU?s) at AAFB. Several synthetic volatile organic compounds (VOC?s), primarily chlorinated solvents, have been identified in groundwater samples collected from monitoring wells near SWMU 8 in the Spring Creek area. During April and May 2000, a study of the groundwater resources in the Spring Creek area was conducted to determine if VOC?s from AAFB have affected local private water supplies and to advance understanding of the ground-water-flow system in this area. The study focused on sampling private wells located within the Spring Creek area that are used as a source of drinking water. Ground-water-flow directions were determined by measuring water levels in wells and constructing a potentiometric-surface map of the Manchester aquifer in the study area. Data were collected from a total of 35 private wells and 22 monitoring wells during the period of study. Depths to ground water were determined for 22 of the private wells and all 22 of the monitoring wells. The wells ranged in depth from 21 to 105 feet. Water-level altitudes ranged from 930 to 1,062 feet above sea level. Depths to water ranged from 8 to 83 feet below land surface. Water-quality samples were collected from 29 private wells which draw water from either gravel zones in the upper part of the Manchester aquifer, fractured bedrock in the lower part of the Manchester aquifer, or a combination of these two zones. Concentrations of 50 of the 55 VOC?s analyzed for were less than method detection limits. Chloroform, acetone, chloromethane, 2-butanone, and tetrachloroethylene were detected in concentrations exceeding the method detection limits. Only chloroform and acetone were detected in concentrations equal to or exceeding reporting limits. Chloroform was detected in a sample from one well at a concentration of 1.2 micrograms per liter (?g/L). Acetone was detected in a sample from another well at a concentration of 10 ?g/L. Acetone also was detected in a duplicate sample from the same well at an estimated concentration of 7.2 ?g/L, which is less than the reporting limit for acetone. The only contaminant of concern detected was tetrachloroethylene. Tetrachloroethylene was detected in only one sample, and this detection was at an estimated concentration below the reporting limit. None of the VOC concentrations exceeded drinking water maximum contaminant levels for public water systems.

Hydro-chemical detection of permafrost degradation in the Eastern European Alps - Implications for geomorphological process studies and natural hazard assessment

NASA Astrophysics Data System (ADS)

Kraushaar, Sabine; Kamleitner, Sarah; Czarnowsky, Verena; Blöthe, Jan; Morche, David; Knöller, Kay; Lachner, Johannes

2017-04-01

The Gepatschferner glacier in the Upper Kaunertal valley is one of the fastest melting glaciers in the Eastern European Alps. With a retreat rate of around 110 m a-1 since the hydrological year 2012/ 2013, unconsolidated sediments of steep lateral moraines have been exposed to erosion, from which nowadays episodic and perennial springs well. We hypothesize that the springs indicate the melt out of dead ice lenses in areas below 2500 m, causing a potential significant morphological change in the moraines and a decrease of slope stability in the proglacial long after glacier retreat. However, permafrost degradation has not been considered so far in contemporary erosion measurements. The present study aims to identify the spring water's origin and displays first attempts of quantifying thermal erosion, which describes the matrix volume loss due to melting and drainage of ice water. Samples were routinely analyzed for temperature, electrical conductivity, δ2H, and δ18O. Results support the hypothesis that certain springs derive from melting ice of similar isotopic signature as the glacier. In a second step, chosen samples were examined for the long-lived anthropogenic nuclide 129I. Since the 1950s the atmospheric abundance of 129I has significantly increased. Its occurrence in the water samples hints a surface contact of the waters in the last 65 years. Springs of ice origin show little 129I content and are believed to derive from dead ice by the glacier. First electric resistivity measurements support the hydro-chemical results and suggest the existence of ice lenses in the subsurface. Ice ablation and discharge measurements allowed first estimates of the thermal erosion volume caused by the melt out and drainage of ice lenses.

Dissolved pesticides in the Alamo River and the Salton Sea, California, 1996-97

USGS Publications Warehouse

Crepeau, Kathryn L.; Kuivila, Kathryn; Bergamaschi, Brian A.

2002-01-01

Water samples were collected from the Alamo River and the Salton Sea, California, in autumn 1996 and late winter/early spring 1997 and analyzed for dissolved pesticides. The two seasons chosen for sampling were during pesticide application periods in the Imperial Valley. Pesticide concentrations were measured in filtered water samples using solid-phase extraction and analyzed by gas chromatography/mass spectrometry. Generally, the highest concentrations were measured in the Alamo River. The concentrations of carbaryl, chlorpyrifos, cycloate, dacthal, diazinon, and eptam were highest in samples collected in autumn 1996. In contrast, the concentrations of atrazine, carbofuran, and malathion were highest in samples collected in late winter/early spring 1997. The highest concentrations measured of atrazine, carbofuran, dacthal, eptam, and malathion all exceeded 1,000 nanograms per liter.

Chemistry of Hot Spring Pool Waters in Calamba and Los Banos and Potential Effect on the Water Quality of Laguna De Bay

NASA Astrophysics Data System (ADS)

Balangue, M. I. R. D.; Pena, M. A. Z.; Siringan, F. P.; Jago-on, K. A. B.; Lloren, R. B.; Taniguchi, M.

2014-12-01

Since the Spanish Period (1600s), natural hot spring waters have been harnessed for balneological purposes in the municipalities of Calamba and Los Banos, Laguna, south of Metro Manila. There are at more than a hundred hot spring resorts in Brgy. Pansol, Calamba and Tadlac, Los Banos. These two areas are found at the northern flanks of Mt. Makiling facing Laguna de Bay. This study aims to provide some insights on the physical and chemical characteristics of hot spring resorts and the possible impact on the lake water quality resulting from the disposal of used water. Initial ocular survey of the resorts showed that temperature of the pool water ranges from ambient (>300C) to as high as 500C with an average pool size of 80m3. Water samples were collected from a natural hot spring and pumped well in Los Banos and another pumped well in Pansol to determine the chemistry. The field pH ranges from 6.65 to 6.87 (Pansol springs). Cation analysis revealed that the thermal waters belonged to the Na-K-Cl-HCO3 type with some trace amount of heavy metals. Methods for waste water disposal are either by direct discharge down the drain of the pool or by discharge in the public road canal. Both methods will dump the waste water directly into Laguna de Bay. Taking in consideration the large volume of waste water used especially during the peak season, the effect on the lake water quality would be significant. It is therefore imperative for the environmental authorities in Laguna to regulate and monitor the chemistry of discharges from the pool to protect both the lake water as well as groundwater quality.

Geochemistry, Comparative Analysis, and Physical and Chemical Characteristics of the Thermal Waters East of Hot Springs National Park, Arkansas, 2006-09

USGS Publications Warehouse

Kresse, Timothy M.; Hays, Phillip D.

2009-01-01

A study was conducted by the U.S Geological Survey in cooperation with the Arkansas State Highway and Transportation Department to characterize the source and hydrogeologic conditions responsible for thermal water in a domestic well 5.5 miles east of Hot Springs National Park, Hot Springs, Arkansas, and to determine the degree of hydraulic connectivity between the thermal water in the well and the hot springs in Hot Springs National Park. The water temperature in the well, which was completed in the Stanley Shale, measured 33.9 degrees Celsius, March 1, 2006, and dropped to 21.7 degrees Celsius after 2 hours of pumping - still more than 4 degrees above typical local groundwater temperature. A second domestic well located 3 miles from the hot springs in Hot Springs National Park was discovered to have a thermal water component during a reconnaissance of the area. This second well was completed in the Bigfork Chert and field measurement of well water revealed a maximum temperature of 26.6 degrees Celsius. Mean temperature for shallow groundwater in the area is approximately 17 degrees Celsius. The occurrence of thermal water in these wells raised questions and concerns with regard to the timing for the appearance of the thermal water, which appeared to coincide with construction (including blasting activities) of the Highway 270 bypass-Highway 70 interchange. These concerns were heightened by the planned extension of the Highway 270 bypass to the north - a corridor that takes the highway across a section of the eroded anticlinal complex responsible for recharge to the hot springs of Hot Springs National Park. Concerns regarding the possible effects of blasting associated with highway construction near the first thermal well necessitated a technical review on the effects of blasting on shallow groundwater systems. Results from available studies suggested that propagation of new fractures near blasting sites is of limited extent. Vibrations from blasting can result in rock collapse for uncased wells completed in highly fractured rock. However, the propagation of newly formed large fractures that potentially could damage well structures or result in pirating of water from production wells appears to be of limited possibility based on review of relevant studies. Characteristics of hydraulic conductivity, storage, and fracture porosity were interpreted from flow rates observed in individual wells completed in the Bigfork Chert and Stanley Shale; from hydrographs produced from continuous measurements of water levels in wells completed in the Arkansas Novaculite, the Bigfork Chert, and Stanley Shale; and from a potentiometric-surface map constructed using water levels in wells throughout the study area. Data gathered from these three separate exercises showed that fracture porosity is much greater in the Bigfork Chert relative to that in the Stanley Shale, shallow groundwater flows from elevated recharge areas with exposures of Bigfork Chert along and into streams within the valleys formed on exposures of the Stanley Shale, and there was no evidence of interbasin transfer of groundwater within the shallow flow system. Fifteen shallow wells and two cold-water springs were sampled from the various exposed formations in the study area to characterize the water quality and geochemistry for the shallow groundwater system and for comparison to the geochemistry of the hot springs in Hot Springs National Park. For the quartz formations (novaculite, chert, and sandstone formations), total dissolved solids concentrations were very low with a median concentration of 23 milligrams per liter, whereas the median concentration for groundwater from the shale formations was 184 milligrams per liter. Ten hot springs in Hot Springs National Park were sampled for the study. Several chemical constituents for the hot springs, including pH, total dissolved solids, major cations and anions, and trace metals, show similarity with the shale formations

Hydrochemical Characteristics and Formation of the Saline or Salty Springs in Eastern Sichuan Basin of China

NASA Astrophysics Data System (ADS)

Zhou, X.

2017-12-01

Saline or salty springs provide important information on the hydrogeochemical processes and hydrology within subsurface aquifers. More than 20 saline and salty springs occur in the core of anticlines in the eastern Sichuan Basin in southwestern China where the Lower and Middle Triassic carbonates outcrop. Water samples of 8 saline and salty springs (including one saline hot spring) were collected for analyses of the major and minor constituents, trace elements and stable oxygen and hydrogen isotopes. The TDS of the springs range from 4 to 83 g/L, and they are mainly of Cl-Na type. Sr, Ba and Li are the predominant trace elements. The δ2H and δ18O of the water samples indicate that they are of meteoric origin. The source of salinity of the springs originates from dissolution of minerals in the carbonates, including halite, gypsum, calcite and dolomite. The formation mechanism of the springs is that groundwater receives recharge from infiltration of precipitation, undergoes shallow or deep circulation in the core of the anticline and incongruent dissolution of the salt-bearing carbonates occurs, and emerges in the river valley in the form of springs with relatively high TDS. The 8 springs can be classified into 4 springs of shallow groundwater circulation and 4 springs of deep groundwater circulation according to the depth of groundwater circulation, 7 springs of normal temperature and 1 hot spring according to temperature. There are also 2 up-flow springs: the carbonate aquifers are overlain by relatively impervious sandstone and shale, groundwater may flows up to the ground surface through the local portion of the overlying aquiclude where fractures were relatively well developed, and emerges as an up-flow spring. Knowledge of the hydrochemical characteristics and the geneses of the saline and salty springs are of important significance for the utilization and preservation of the springs.

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman Area, Idaho, 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

R. C. Bartholomay; B. V. Twining; L. J. Campbell

1999-06-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in cooperation with the U.S. Department of Energy, sampled 18 sites as part of the fourth round of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman area. The samples were analyzed for selected radiochemical and chemical constituents. The samples were collected from 2 domestic wells, 12 irrigation wells, 2 stock wells, 1 spring, and 1 public supply well. Two quality-assurance samples also were collected and analyzed. None of themore » reported radiochemical or chemical constituent concentrations exceeded the established maximum contaminant levels for drinking water. Many of the radionuclide- and inorganic-constituent concentrations were greater than the respective reporting levels. Most of the organic-constituent concentrations were less than the reporting levels.« less

Physical, chemical, and isotopic data for samples from the Anderson Springs area, Lake County, California, 1998-1999

USGS Publications Warehouse

Janik, C.J.; Goff, F.; Sorey, M.L.; Rytuba, J.J.; Counce, D.; Colvard, E.M.; Huebner, M.; White, L.D.; Foster, A.

1999-01-01

Anderson Springs is located about 90 miles (145 kilometers) north of San Francisco, California, in the southwestern part of Lake County. The area was first developed in the late 1800s as a health resort, which was active until the 1930s. In the rugged hills to the south of the resort were four small mercury mines of the eastern Mayacmas quicksilver district. About 1,260 flasks of mercury were produced from these mines between 1909 and 1943. In the 1970s, the high-elevation areas surrounding Anderson Springs became part of The Geysers geothermal field. Today, several electric powerplants are located on the ridges above Anderson Springs, utilizing steam produced from a 240°C vapor-dominated reservoir. The primary purpose of this report is to provide physical, chemical, and isotopic data on samples collected in the Anderson Springs area during 1998 and 1999, in response to a Freedom of Information Act request. In July 1998, drainage from the Schwartz adit of the abandoned Anderson mercury mine increased substantially over a 2-day period, transporting a slurry of water and precipitates down a tributary and into Anderson Creek. In August 1998, J.J. Rytuba and coworkers sampled the Schwartz adit drainage and water from the Anderson Springs Hot Spring for base metal and methylmercury analysis. They measured a maximum temperature (Tm) of 85°C in the Hot Spring. Published records show that the temperature of the Anderson Springs Hot Spring (main spring) was 63°C in 1889, 42–52°C from 1974 through 1991, and 77°C in March 1995. To investigate possible changes in thermal spring activity and to collect additional samples for geochemical analysis, C.J. Janik and coworkers returned to the area in September and December 1998. They determined that a cluster of springs adjacent to the main spring had Tm=98°C, and they observed that a new area of boiling vents and small fumaroles (Tm=99.3°C) had formed in an adjacent gully about 20 meters to the north of the main spring. During August–October 1999, several field trips were conducted in the vicinity of Anderson Springs to continue monitoring and sampling the thermal manifestations. The new fumarolic area had increased in temperature and in discharge intensity since 1998, and a zone of dead trees had developed on the steep bank directly west of the fumaroles. Ground temperatures and diffuse flow of CO2 flow through soils were measured in the area surrounding the main spring and new fumaroles and in the zone of tree-kill.

Temporal and Spatial Diversity of Bacterial Communities in Coastal Waters of the South China Sea

PubMed Central

Du, Jikun; Xiao, Kai; Li, Li; Ding, Xian; Liu, Helu; Lu, Yongjun; Zhou, Shining

2013-01-01

Bacteria are recognized as important drivers of biogeochemical processes in all aquatic ecosystems. Temporal and geographical patterns in ocean bacterial communities have been observed in many studies, but the temporal and spatial patterns in the bacterial communities from the South China Sea remained unexplored. To determine the spatiotemporal patterns, we generated 16S rRNA datasets for 15 samples collected from the five regularly distributed sites of the South China Sea in three seasons (spring, summer, winter). A total of 491 representative sequences were analyzed by MOTHUR, yielding 282 operational taxonomic units (OTUs) grouped at 97% stringency. Significant temporal variations of bacterial diversity were observed. Richness and diversity indices indicated that summer samples were the most diverse. The main bacterial group in spring and summer samples was Alphaproteobacteria, followed by Cyanobacteria and Gammaproteobacteria, whereas Cyanobacteria dominated the winter samples. Spatial patterns in the samples were observed that samples collected from the coastal (D151, D221) waters and offshore (D157, D1512, D224) waters clustered separately, the coastal samples harbored more diverse bacterial communities. However, the temporal pattern of the coastal site D151 was contrary to that of the coastal site D221. The LIBSHUFF statistics revealed noticeable differences among the spring, summer and winter libraries collected at five sites. The UPGMA tree showed there were temporal and spatial heterogeneity of bacterial community composition in coastal waters of the South China Sea. The water salinity (P=0.001) contributed significantly to the bacteria-environment relationship. Our results revealed that bacterial community structures were influenced by environmental factors and community-level changes in 16S-based diversity were better explained by spatial patterns than by temporal patterns. PMID:23785512

Hydrogeology and quality of ground water in the Boone Formation and Cotter Dolomite in karst terrain of northwestern Boone County, Arkansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leidy, V.A.; Morris, E.E.

1991-01-01

Shallow groundwater flow systems in karst terrain of northwestern Boone County, Arkansas, are particularly susceptible to contamination. The potential for groundwater contamination probably is greater in the northern one-half of the study area where there are more photolineaments and presumably subsurface fractures. Groundwater samples from 17 springs discharging from the Boone Formation and 17 wells completed in the Cotter Dolomite were analyzed to determine ambient groundwater quality and to document water quality variations. The chemical constituents in groundwater generally did not exceed US Environmental Protection Agency primary or secondary maximum contaminant levels. However, fecal coliform and fecal streptococcus bacteria weremore » detected in most springs and in three wells. One spring, located near an abandoned wood-treatment plant (a designated Superfund site), had maximum iron, manganese, lead, and pentachlorophenol concentration that exceeded US Environmental Protection Agency's primary or secondary maximum contamination levels for drinking water. Water samples collected from selected springs emerging from the Boone Formation exhibited an overall decrease in specific conductance and total alkalinity, calcium, magnesium, sodium, and chloride concentrations and an overall increase in nitrate, fecal coliform, and fecal streptococcus bacteria concentrations 3 to 8 hours after a rainstorm.« less

Effects of wildfire on source-water quality and aquatic ecosystems, Colorado Front Range

USGS Publications Warehouse

Writer, Jeffrey H.; McCleskey, R. Blaine; Murphy, Sheila F.; Stone, Mike; Collins, Adrian; Thoms, Martin C.

2012-01-01

Watershed erosion can dramatically increase after wildfire, but limited research has evaluated the corresponding influence on source-water quality. This study evaluated the effects of the Fourmile Canyon wildfire (Colorado Front Range, USA) on source-water quality and aquatic ecosystems using high- frequency sampling. Dissolved organic carbon (DOC) and nutrient loads in stream water were evaluated for a one-year period during different types of runoff events, including spring snowmelt, and both frontal and summer convective storms. DOC export from the burned watershed did not increase relative to the unburned watershed during spring snowmelt, but substantial increases in DOC export were observed during summer convective storms. Elevated nutrient export from the burned watershed was observed during spring snowmelt and summer convective storms, which increased the primary productivity of stream biofilms. Wildfire effects on source-water quality were shown to be substantial following high-intensity storms, with the potential to affect drinking-water treatment processes.

Enzyme activity screening of thermophilic bacteria isolated from Dusun Tua Hot Spring, Malaysia

NASA Astrophysics Data System (ADS)

Msarah, Marwan; Ibrahim, Izyanti; Aqma, Wan Syaidatul

2018-04-01

Thermophilic bacteria have biotechnological importance due to the availability of unique enzymes which are stable in extreme circumstances. The aim of this study includes to isolate thermophilic bacteria from hot spring and screen for important enzyme activities. Water samples from the Dusun Tua Hot Spring were collected and the physiochemical characterisation of water was measured. Eight thermophilic bacteria were isolated and determined to have at least three strong enzyme activity including protease, lipase, amylase, cellulase, pectinase and xylanase. The results showed that HuluC2 displayed all the enzyme activities and can be further studied.

Occurrence of foodborne bacteria in Alberta feedlots.

PubMed

Van Donkersgoed, Joyce; Bohaychuk, Valerie; Besser, Thomas; Song, Xin-Ming; Wagner, Bruce; Hancock, Dale; Renter, David; Dargatz, David

2009-02-01

The occurrence of generic Escherichia coli, E. coli O157, Salmonella, and Campylobacter in cattle manure, beef carcasses, catch basin water, and soils receiving manure application was determined in 21 Alberta feedlots. In cattle manure, generic E. coli (98%, 2069/2100) and Campylobacter (76%, 1590/2100) were frequently detected; E. coli O157 (7%, 143/2100) and Salmonella (1%, 20/2100) were less frequently detected. Samples from beef carcasses in the cooler following Hazard Analysis Critical Control Point interventions yielded only 1 isolate each of generic E. coli and Campylobacter (1/1653) and no Salmonella (0/1653). Catch basin water specimens were positive for generic E. coli in both the spring (62%, 13/21) and the fall (52%, 11/21). Other bacteria were detected only in the spring water specimens, including E. coli O157 (29%, 6/21), Salmonella (5%, 1/21), and Campylobacter (52%, 11/21). Generic E. coli was frequently isolated from soil specimens (30%, 27/88), but E. coli O157 was not found in soil samples obtained in the spring and was only occasionally detected in the fall samples (9%, 3/32). Salmonella were occasionally found in the soil specimens collected in the spring (3%, 2/56), but not in the fall season (0/32). Campylobacter jejuni was frequent in cattle manure (66%, 1070/1623), but rare in carcass and environmental samples. E. coli O157 and Salmonella were rarely detected in cattle or the environment. Generic E. coli and Salmonella were rarely detected on carcasses.

[Water quality evaluation in rural areas of Lavras, Minas Gerais, Brazil, 1999-2000].

PubMed

Rocha, Christiane Maria Barcellos Magalhães da; Rodrigues, Luciano Dos Santos; Costa, Claudionor C; de Oliveira, Paulo Roberto; da Silva, Israel José; de Jesus, Eder Ferreira Moraes; Rolim, Renata G

2006-09-01

In addition to personal interviews, laboratory analyses were performed using 80 water samples from 45 rural areas that are crossed by the Agua Limpa and Santa Cruz streams close to the city of Lavras, southern Minas Gerais State. The results allowed comparing the quality of water used for agriculture and the identification of determinant factors. The Agua Limpa stream mostly crosses an area used primarily for housing and characterized by low schooling. Many houses are supplied by shallow water wells and have ordinary cesspits for human waste disposal. All springs are polluted. The Santa Cruz stream displays a different scenario. The land is used mostly for agricultural purposes. Most owners live in town, with widely varied levels of school, from none to university. The houses are supplied by surface water. Most of the springs are polluted. The perception by both home and land owners concerning quality of the drinking water is determined solely by the water's physical and organoleptic characteristics. Sanitary parameters are not taken into account. Moreover, there is no relationship between fecal contamination and the type of spring. Land use and anthropic activity are far more important than the type of spring for water quality.

Spring contributions to water quality and nitrate loads in the Suwannee River during base flow in July 1995

USGS Publications Warehouse

Pittman, J.R.; Hatzell, H.H.; Oaksford, E.T.

1997-01-01

The Suwannee River flows through an area of north-central Florida where ground water has elevated nitrate concentrations. A study was conducted to determine how springs and other ground-water inflow affect the quantity and quality of water in the Suwannee River. The study was done on a 33-mile (mi) reach of the lower Suwannee River from just downstream of Dowling Park, Fla., to Branford, Fla. Water samples for nitrate concentrations (dissolved nitrite plus nitrate as nitrogen) and discharge data were collected at 11 springs and 3 river sites during the 3-day period in July 1995 during base flow in the river. In the study reach, all inflow to the river is derived from ground water. Measured springs and other ground-water inflow, such as unmeasured springs and upward diffuse leakage through the riverbed, increased the river discharge 47 percent over the 33-mi reach. The 11 measured springs contributed 41 percent of the increased discharge and other ground-water inflow contributed the remaining 59 percent. River nitrate loads increased downstream from 2,300 to 6,000 kilograms per day (kg/d), an increase of 160 percent in the 33-mi study reach. Measured springs contributed 46 percent of this increase and other ground-water inflow contributed the remaining 54 percent. The study reach was divided at Luraville, Fla., into an 11-mi upper segment and a 22-mi lower segment to determine whether the ground-water inflows and nitrate concentrations were uniform throughout the entire study reach (fig. 1). The two segments were dissimilar. The amount of water added to the river by measured springs more than tripled from the upper to the lower segment. Even though the median nitrate concentration for the three springs in the upper segment (1.7 milligrams per liter (mg/L)) was similar to the median for the eight springs in the lower segment (1.8 mg/L), nitrate concentrations in the river almost doubled from 0.46 to 0.83 mg/L in the lower segment. Only 11 percent of the increase in nitrate load for the study reach occurred in the upper segment; the remaining 89 percent occurred in the lower segment. Measured springs were the major source of nitrate load in the upper reach and other ground-water inflow was the major source in the lower segment. Differences in nitrate loads between the upper and lower river segments are probably controlled by such factors as differences in the magnitude of the spring discharges, the size and location of spring basins, and the hydrologic characteristics of ground water in the study area.

Evaluation of potential human health risk and investigation of drinking water quality in Isparta city center (Turkey).

PubMed

Varol, Simge; Davraz, Aysen

2016-06-01

Isparta city center is selected as a work area in this study because the public believes that the tap water is dirty and harmful. In this study, the city's drinking water in the distribution system and other spring waters which are used as drinking water in this region were investigated from the point of water quality and health risk assessment. Water samples were collected from major drinking water springs, tap waters, treatment plants and dam pond in the Isparta province center. Ca-Mg-HCO3, Mg-Ca-HCO3, Ca-Na-HCO3, Ca-HCO3, Ca-HCO3-SO4 and Ca-Mg-HCO3-SO4 are dominant water types. When compared to drinking water guidelines established by World Health Organization and Turkey, much greater attention should be paid to As, Br, Fe, F, NH4, PO4 through varied chemicals above the critical values. The increases of As, Fe, F, NH4 and PO4 are related to water-rock interaction. In tap waters, the increases of As and Fe are due to corrosion of pipes in drinking water distribution systems. The major toxic and carcinogenic chemicals within drinking water are As and Br for both tap water and spring water. Also, F is the non-carcinogenic chemical for only spring waters in the study area.

Can Sanitary Surveys Replace Water Quality Testing? Evidence from Kisii, Kenya.

PubMed

Misati, Aaron Gichaba; Ogendi, George; Peletz, Rachel; Khush, Ranjiv; Kumpel, Emily

2017-02-07

Information about the quality of rural drinking water sources can be used to manage their safety and mitigate risks to health. Sanitary surveys, which are observational checklists to assess hazards present at water sources, are simpler to conduct than microbial tests. We assessed whether sanitary survey results were associated with measured indicator bacteria levels in rural drinking water sources in Kisii Central, Kenya. Overall, thermotolerant coliform (TTC) levels were high: all of the samples from the 20 tested dug wells, almost all (95%) of the samples from the 25 tested springs, and 61% of the samples from the 16 tested rainwater harvesting systems were contaminated with TTC. There were no significant associations between TTC levels and overall sanitary survey scores or their individual components. Contamination by TTC was associated with source type (dug wells and springs were more contaminated than rainwater systems). While sanitary surveys cannot be substituted for microbial water quality results in this context, they could be used to identify potential hazards and contribute to a comprehensive risk management approach.

Natural radioactivity in geothermal waters, Alhambra Hot Springs and nearby areas, Jefferson County, Montana

USGS Publications Warehouse

Leonard, Robert B.; Janzer, Victor J.

1978-01-01

Radioactive hot springs issue from a fault zone in crystalline rock of the Boulder batholith at Alhambra, Jefferson County, in southwestern Montana. The discharge contains high concentrations of radon, and the gross alpha activity and the concentration of adium-226 exceed maximum levels recommended by the Environmental Protection Agency for drinking water. Part of the discharge is diverted for space heating, bathing, and domestic use. The radioactive thermal waters at measured temperatures of about 60°C are of the sodium bicarbonate type and saturated with respect to calcium carbonate. Radium-226 in the rock and on fractured surfaces or coprecipitated with calcium carbonate probably is the principal source of radon that is dissolved in the thermal water and discharged with other gases from some wells and springs. Local surface water and shallow ground water are of the calcium bicarbonate type and exhibit low background activity. The temperature, percent sodium, and radioactivity of mixed waters adjacent to the fault zone increase with depth. Samples from most of the major hot springs in southwestern Montana have been analyzed for gross alpha and beta activity. The high level of radioactivity at Alhambra appears to be related to leaching of radioactive material from siliceous veins by ascending thermal waters and is not a normal characteristic of hot springs issuing from fractured crystalline rock in Montana.

[Pollution characteristics and sources of polycyclic aromatic hydrocarbons in urban rivers of Wenzhou city].

PubMed

Zhou, Jie-Cheng; Chen, Zhen-Lou; Bi, Chun-Juan; Lü, Jin-Gang; Xu, Shi-Yuan; Pan, Qi

2012-12-01

Concentrations of 18 polycyclic aromatic hydrocarbons (PAHs) in water and surface sediments collected from the urban rivers of Wenzhou city in spring and summer were measured by GC-MS. The results showed that the total PAHs concentrations in water and sediments of the studied rivers varied in ranges of 146.74-3 047.89 ng x L(-1) and 21.01-11 990.48 ng x g(-1), respectively. Higher concentrations occurred in spring. The low and middle rings of 2-4-ring were dominant in both water and sediments, but the concentrations of 5-ring and 6-ring PAHs in sediments were relatively higher than those in water. The EBaP values of PAHs in water of the studied rivers in spring and summer were 1.69-51.95 ng x L(-1) and 0-3.03 ng x L(-1), respectively. Eighty percent of water samples in spring surpassed the limits of BaP in surface water of China. The concentrations of sigma PAHs in the sediments both in spring and summer were lower than the ERM value, but part of the components of PAHs had values higher than the ERM, suggesting possible toxic effect on living organisms. Based on the PAHs molecule ratios and principal component analysis, a mixed PAHs source of petroleum and combustion in water and sediments was diagnosed, while sediments showed a greater proportion of combustion sources.

Occurrence of Pesticides in Ground Water of Wyoming, 1995-2006

USGS Publications Warehouse

Bartos, Timothy T.; Eddy-Miller, Cheryl A.; Hallberg, Laura L.

2009-01-01

Little existing information was available describing pesticide occurrence in ground water of Wyoming, so the U.S. Geological Survey, in cooperation with the Wyoming Department of Agriculture and the Wyoming Department of Environmental Quality on behalf of the Wyoming Ground-water and Pesticides Strategy Committee, collected ground-water samples twice (during late summer/early fall and spring) from 296 wells during 1995-2006 to characterize pesticide occurrence. Sampling focused on the State's ground water that was mapped as the most vulnerable to pesticide contamination because of either inherent hydrogeologic sensitivity (for example, shallow water table or highly permeable aquifer materials) or a combination of sensitivity and associated land use. Because of variations in reporting limits among different compounds and for the same compound during this study, pesticide detections were recensored to two different assessment levels to facilitate qualitative and quantitative examination of pesticide detection frequencies - a common assessment level (CAL) of 0.07 microgram per liter and an assessment level that differed by compound, referred to herein as a compound-specific assessment level (CSAL). Because of severe data censoring (fewer than 50 percent of the data are greater than laboratory reporting limits), categorical statistical methods were used exclusively for quantitative comparisons of pesticide detection frequencies between seasons and among various natural and anthropogenic (human-related) characteristics. One or more pesticides were detected at concentrations greater than the CAL in water from about 23 percent of wells sampled in the fall and from about 22 percent of wells sampled in the spring. Mixtures of two or more pesticides occurred at concentrations greater than the CAL in about 9 percent of wells sampled in the fall and in about 10 percent of wells sampled in the spring. At least 74 percent of pesticides detected were classified as herbicides. Considering only detections using the CAL, triazine pesticides were detected much more frequently than all other pesticide classes, and the number of different pesticides classified as triazines was the largest of all classes. More pesticides were detected at concentrations greater than the CSALs in water from wells sampled in the fall (28 different pesticides) than in the spring (21 different pesticides). Many pesticides were detected infrequently as nearly one-half of pesticides detected in the fall and spring at concentrations greater than the CSALs were detected only in one well. Using the CSALs for pesticides analyzed for in 11 or more wells, only five pesticides (atrazine, prometon, tebuthiuron, picloram, and 3,4-dichloroaniline, listed in order of decreasing detection frequency) were each detected in water from more than 5 percent of sampled wells. Atrazine was the pesticide detected most frequently at concentrations greater than the CSAL. Concentrations of detected pesticides generally were small (less than 1 microgram per liter), although many infrequent detections at larger concentrations were noted. All detected pesticide concentrations were smaller than U.S. Environmental Protection Agency (USEPA) drinking-water standards or applicable health advisories. Most concentrations were at least an order of magnitude smaller; however, many pesticides did not have standards or advisories. The largest percentage of pesticide detections and the largest number of different pesticides detected were in samples from wells located in the Bighorn Basin and High Plains/ Casper Arch geographic areas of north-central and southeastern Wyoming. Prometon was the only pesticide detected in all eight geographic areas of the State. Pesticides were detected much more frequently in samples from wells located in predominantly urban areas than in samples from wells located in predominantly agricultural or mixed areas. Pesticides were detected distinctly less often in sa

Karst hydrogeology and hydrochemistry of the Cave Springs basin near Chattanooga, Tennessee

USGS Publications Warehouse

Pavlicek, D.J.

1996-01-01

The Cave Springs ground-water basin, located near Chattanooga, Tennessee, was chosen as one of the Valley and Ridge physiographic province type area studies for the Appalachian Valley-Piedmont Regional Aquifer-System Analysis study in 1990. Karstic Paleozoic carbonate rocks, residual clay-rich regolith, and coarse alluvium form the aquifer framework. Recharge from rainfall dispersed over the basin enters the karst aquifer through the thick regolith. The area supplying recharge to the Cave Springs Basin is approximately 7 square miles. Recharge from North Chickamauga Creek may contribute recharge to the Cave Springs Basin along losing reaches. The flow medium consists of mixed dolomite and limestone with cavernous and fracture porosity. Flow type as determined by the coefficient of variation of long-term continuous specific conductance (18 and 15 percent) from two wells completed in cavernous intervals about 150 feet northeast of Cave Springs, indicates an aquifer with conduit flow. Flow type, based on the ratio (6:1) of spring flood-flow discharge to spring base-flow discharge, indicates an aquifer with diffuse flow. Conduit flow probably dominates the aquifer system west of Cave Springs Ridge from the highly transmissive, unconfined, alluvium capped aquifer and along losing reaches of North Chickamauga Creek. Diffuse flow probably predominates in the areas along and east of Cave Springs Ridge covered with the thick, clay-rich regolith that forms a leaky confining layer. Based on average annual long-term precipitation and runoff records, the amount of water available for recharge to Cave Springs is 11.8 cubic feet per second. The mean annual long-term discharge of Cave Springs is 16.4 cubic feet per second which leaves 4.6 cubic feet per second of recharge unaccounted for. As determined by low-flow stream discharge measurements, recharge along losing reaches of North Chickamauga Creek may be an important source of unaccounted-for-recharge to the Cave Springs Basin. Selected ground-water samples in the study area are characterized by calcium bicarbonate type water and calcium magnesium bicarbonate type water. Calcium bicarbonate type water characterizes Lick Branch and Poe Branch. North Chickamauga Creek water is calcium magnesium sulfate type water and reflects interaction with the pyrite-containing siliciclastic rocks of the Cumberland Plateau or acid mine drainage. Seasonal high spring discharge is associated with lower specific conductance and lower temperatures, which lag in response to increasing spring discharge by approximately 2 months. Seasonal decrease in spring discharge is accompanied by an incident increase in specific conductance and temperature increase, which leads by about 4 months.

Nitrate Contamination in the groundwater of the Lake Acıgöl Basin, SW Turkey

NASA Astrophysics Data System (ADS)

Karaman, Muhittin; Budakoǧlu, Murat; Taşdelen, Suat

2017-04-01

The lacustrine Acıgöl basin, formed as an extensional half-graben, hosts various bodies of water, such as cold-hot springs, lakes, streams, and wells. The hydrologically closed basin contains a hypersaline lake (Lake Acıgöl) located in the southern part of the basin. The brackish springs and deep waters discharged along the Acıgöl fault zone in the southern part of the basin feed the hypersaline lake. Groundwater is used as drinking, irrigation, and domestic water in the closed Acıgöl Basin. Groundwater flows into the hypersaline lake from the highland. The Acıgöl basin hosts large plains (Hambat, Başmakçı, and Evciler). Waters in agricultural areas contain high amounts of nitrate; groundwater samples in agricultural areas contain nitrate levels higher than 10 mg/L. Nitrate concentrations in the groundwater samples varied from 0 to 487 mg/L (n=165); 25.4 % of the groundwater samples from the basin had nitrate concentrations above 10 mg/L (the WHO drinking guideline) and 52.2% of the groundwater samples from the basin had nitrate concentrations above 3.0 mg/L, and these high values were regarded as the result of human activity. The highest nitrate values were measured in the Hambat plain (480 and 100 mg/L) and Yirce Pinari spring (447 mg/L), which discharges along the Acıgöl fault zone in the southern part of the basin. The average multi-temporal nitrate concentration of the Yirce Pınarı spring was 3.3 mg/L. Extreme nitrate values were measured in the Yirce Pınarı spring during periods when sheep wool was washed (human activity). The lowest nitrate concentrations were observed in some springs that discharged along the Acıgöl fault zone in the southern part of the basin. Nitrate was not detected in deep groundwater discharged along the Acıgöl fault zone. Nitrate concentrations in deep groundwater and some springs discharged along the Acıgöl fault zone and those feeding the hypersaline lake were significantly affected by redox conditions. Nitrate in these reducing waters was transformed into ammonium. Nitrate concentrations in the Acıgöl Basin were enriched in groundwater beneath agricultural areas and this affected redox conditions. The main source of nitrate contamination was agricultural fertilizers. Elevated nitrate concentrations in groundwater, especially in agricultural areas of the Acigol Basin, can cause public health problems and environmental pollution.

Water-Quality Data for Selected National Park Units within the Southern Colorado Plateau Network, Arizona, Utah, Colorado, and New Mexico, Water Years 2005 and 2006

USGS Publications Warehouse

Macy, Jamie P.; Monroe, Stephen A.

2006-01-01

The National Park Service initiated a Level 1 Water-Quality Inventory program to provide water-quality data to park managers so informed natural resource management decisions could be made. Level 1 water-quality data were collected by the U.S. Geological Survey Arizona Water Science Center at 57 sites in 13 National Park units located in the Southern Colorado Plateau Inventory and Monitoring network in water years 2005 and 2006. These data describe the current water-quality at selected sites within the park units and provide information for monitoring future trends. Water samples were collected three times at each type of site including wells, springs, seeps, tinajas, rivers, a lake, and an irrigation ditch. Field measurements were taken at each site and they included pH, specific conductance, temperature, barometric pressure, dissolved oxygen, alkalinity, turbidity, and discharge rates where applicable. Water samples collected were sent to the U.S. Geological Survey National Water Quality Laboratory and analyzed for major ions, trace elements, and nutrients. The National Water Quality Laboratory also analyzed selected samples for mercury and petroleum hydrocarbons. Additional samples at selected sites were collected and analyzed for cyanide, radiochemistry, and suspended sediment by U.S. Geological Survey contract labs. Fecal-indicator bacteria (Escherichia coli) were sampled for at selected sites as another indicator of water quality. Quality control for this study was achieved through proper training of field personnel, use of standard U.S. Geological Survey field and laboratory protocols, collection of sample blanks and replicates, and a thorough review of the water-quality analyses. Measured field pH ranged from 6.0 to 8.8, within normal range for springs and rivers, at most sites. Concentrations of dissolved solids ranged from 48 to 8,680 mg/L and the majority of samples had concentrations of dissolved solids below 900 mg/L. Trace-element concentrations at most sites were at or near the laboratory reporting levels. The highest overall trace-element concentrations were found at U.S. Highway 160 Spring near Park Entrance to Mesa Verde National Park. Concentrations of uranium in samples at all sites ranged from below the detection limit to 55.7 ?g/L. Water samples from selected sites were analyzed for total petroleum hydrocarbons and concentrations of total petroleum hydrocarbons were at or above the laboratory detection limit in samples at six National Park units. Ten sites were sampled for Escherichia coli and positive counts were found at 9 out of the ten sites, the highest colony counts were found at Chinle Creek at Chinle, AZ in Canyon de Chelly National Monument. Measured concentrations of dissolved ammonia, nitrite, and nitrate were at or near laboratory reporting levels at most sites; nitrate concentrations ranged from below the reporting limit (0.047 mg/L) to 9.77 mg/L. Samples that were analyzed for mercury had concentrations below or at the laboratory reporting level. Concentrations of cyanide were less than the laboratory reporting level for all samples except two, Spruce Tree House Spring in Mesa Verde National Park and Pine Tree Canyon Tinaja in Canyon de Chelly National Monument, which had average concentrations of .042 and .011 ?g/L respectively. Gross alpha/beta radioactivity counts were below the U.S. Environmental Protection Agency maximum contaminant level except for samples from Casa Chiquita Well Middle at Chaco Culture National Historical Park which averaged 35 pCi/L. Suspended-sediment concentrations were variable and ranged from 10 to 150,000 mg/L.

The thermal regime and species composition of fish and invertebrates in Kelly Warm Spring, Grand Teton National Park, Wyoming

USGS Publications Warehouse

Harper, David; Farag, Aida

2017-01-01

We evaluated the thermal regime and relative abundance of native and nonnative fish and invertebrates within Kelly Warm Spring and Savage Ditch, Grand Teton National Park, Wyoming. Water temperatures within the system remained relatively warm year-round with mean temperatures >20 °C near the spring source and >5 °C approximately 2 km downstream of the source. A total of 7 nonnative species were collected: Convict/Zebra Cichlid (Cichlasoma nigrofasciatum), Green Swordtail (Xiphophorus hellerii), Tadpole Madtom (Noturus gyrinus), Guppy (Poecilia reticulata), Goldfish (Carassius auratus), red-rimmed melania snail (Melanoides tuberculata), and American bullfrog tadpoles (Lithobates catesbeianus). Nonnative fish (Zebra Cichlids and Green Swordtails), red-rimmed melania snails, and bullfrog tadpoles dominated the upper 2 km of the system. Abundance estimates of the Zebra Cichlid exceeded 12,000 fish/km immediately downstream of the spring source. Relative abundance of native species increased movingdownstream as water temperatures attenuated with distance from the thermally warmed spring source; however, nonnative species were captured 4 km downstream from the spring. Fish diseases were prevalent in both native and nonnative fish from the Kelly Warm Spring pond. Clinostomum marginatum, a trematode parasite, was found in native species samples, and the tapeworm Diphyllobothrium dendriticum was present in samples from nonnative species. Diphyllobothrium dendriticum is rare in Wyoming. Salmonella spp. were also found in some samples of nonnative species. These bacteria are associated with aquarium fish and aquaculture and are generally not found in the wild.

Assessment of sulfurous springs in the west of Iraq for balneotherapy, drinking, irrigation and aquaculture purposes.

PubMed

Awadh, Salih Muhammad; Al-Ghani, Sura Abdul

2014-06-01

This research deals with the sulfurous spring waters flow along the course of the Euphrates River in western Iraq in the area extended between Haqlaniya and Hit within the Al-Anbar governorate. Eleven springs (3 in Haqlanya, 4 in Kubaysa and 4 in Hit) have been addressed for the purpose of water evaluation for balneology, drinking, irrigation and aquaculture (fish farming). In order to meet the objectives of this research, all springs were sampled and analyzed for the total dissolved solid, electrical conductivity, pH, temperature, major cations (Ca(2+), Mg(2+), Na(+) and K(+)), major anions (SO(4)(2-), Cl(-), HCO(3)(-) and CO(3)(2-)), minor anions (PO(4)(3-)and NO(3)(-)) as well as the trace elements that included Pb, Zn, Cd, Ni, Fe, Mn, Cu, Br, F, Ba, B, Sr, Al, As, Cr, Hg and Se. The International Standards of World Health Organization are used for assessing the water quality. The results revealed that the springs belong to the tepid springs of 27-30 °C and classified as hypothermal to the thermal springs. Lithochemistry and geochemical processes clearly affected the water chemistry. The hydrogeochemical processes are responsible for the element enrichment in water by the chemical dissolution of carbonate and gypsum and evaporation as well. The results of the study indicate the possibility of using spring water for therapeutic purposes, but not allowed for drinking and aquaculture (fish farming), except those free of H(2)S gas. On the other hand, it can be used for irrigation with risk. However, soil type as well as proper selection of plants should be taken into consideration.

Streamflow and Water-Quality Characteristics for Wind Cave National Park, South Dakota, 2002-03

USGS Publications Warehouse

Heakin, Allen J.

2004-01-01

A 2-year study of streamflow and water-quality characteristics in Wind Cave National Park was performed by the U.S. Geological Survey in cooperation with the National Park Service. During this study, streamflow and water-quality data were collected for three of the park's perennial streams (Cold Spring, Beaver, and Highland Creeks) from January 2002 through November 2003. The potential influence of parking lot runoff on cave drip within Wind Cave also was investigated by collecting and analyzing several time-dependent samples from a drainage culvert downstream from the parking lot and from Upper Minnehaha Falls inside the cave following a series of simulated runoff events. The primary focus of the report is on data collected during the 2-year study from January 2002 to November 2003; however, data collected previously also are summarized. Losing reaches occur on both Beaver and Highland Creeks as these streams flow across outcrops of bedrock aquifers within the park. No streamflow losses occur along Cold Spring Creek because its confluence with Beaver Creek is located upstream from the outcrop of the Madison aquifer, where most streamflow losses occur. Physical properties, major ions, trace elements, nutrients, bacteria, benthic macroinvertebrates, organic (wastewater) compounds, bottom sediment, and suspended sediment are summarized for samples collected from 2 sites on Cold Spring Creek, 2 sites on Beaver Creek, and 1 site on Highland Creek. None of the constituent concentrations for any of the samples collected during 2002-03 exceeded any of the U.S. Environmental Protection Agency drinking-water standards, with the exception of the Secondary Maximum Contaminant Level for pH, which was exceeded in numerous samples from Beaver Creek and Highland Creek. Additionally, the pH values in several of these same samples also exceeded beneficial-use criteria for coldwater permanent fisheries and coldwater marginal fisheries. Water temperature exceeded the coldwater permanent fisheries criterion in numerous samples from all three streams. Two samples from Highland Creek also exceeded the coldwater marginal fisheries criterion for water temperature. Mean concentrations of ammonia, orthophosphate, and phosphorous were higher for the upstream site on Beaver Creek than for other water-quality sampling sites. Concentrations of E. coli, fecal coliform, and total coliform bacteria also were higher at the upstream site on Beaver Creek than for any other site. Samples for the analysis of benthic macroinvertebrates were collected from one site on each of the three streams during July 2002 and May 2003. The benthic macroinvertebrate data showed that Beaver Creek had lower species diversity and a higher percentage of tolerant species than the other two streams during 2002, but just the opposite was found during 2003. However, examination of the complete data set indicates that the quality of water at the upstream site was generally poorer than the quality of water at the downstream site. Furthermore, the quality of water at the upstream site on Beaver Creek is somewhat degraded when compared to the quality of water from Highland and Cold Spring Creeks, indicating that anthropogenic activities outside the park probably are affecting the quality of water in Beaver Creek. Samples for the analysis of wastewater compounds were collected at least twice from four of the five water-quality sampling sites. Bromoform, phenol, caffeine, and cholesterol were detected in samples from Cold Spring Creek, but only phenol was detected at concentrations greater than the minimum reporting level. Concentrations of several wastewater compounds were estimated in samples collected from sites on Beaver Creek, including phenol, para-cresol, and para-nonylphenol-total. Phenol was detected at both sites on Beaver Creek at concentrations greater than the minimum reporting level. Bromoform; para-cresol; ethanol,2-butoxy-phosphate; and cholesterol were detected

The impact of post-exercise hydration with deep-ocean mineral water on rehydration and exercise performance.

PubMed

Keen, Douglas A; Constantopoulos, Eleni; Konhilas, John P

2016-01-01

Dehydration caused by prolonged exercise impairs thermoregulation, endurance and exercise performance. Evidence from animal and human studies validates the potential of desalinated deep-ocean mineral water to positively impact physiological and pathophysiological conditions. Here, we hypothesize that deep-ocean mineral water drawn from a depth of 915 m off the Kona, HI coast enhances recovery of hydration and exercise performance following a dehydrating exercise protocol compared to mountain spring water and a carbohydrate-based sports drink. Subjects (n = 8) were exposed to an exercise-dehydration protocol (stationary biking) under warm conditions (30 °C) to achieve a body mass loss of 3 % (93.4 ± 21.7 total exercise time). During the post-exercise recovery period, subjects received deep-ocean mineral water (Kona), mountain spring water (Spring) or a carbohydrate-based sports drink (Sports) at a volume (in L) equivalent to body mass loss (in Kg). Salivary samples were collected at regular intervals during exercise and post-exercise rehydration. Additionally, each participant performed peak torque knee extension as a measure of lower body muscle performance. Subjects who received Kona during the rehydrating period showed a significantly more rapid return to pre-exercise (baseline) hydration state, measured as the rate of decline in peak to baseline salivary osmolality, compared to Sports and Spring groups. In addition, subjects demonstrated significantly improved recovery of lower body muscle performance following rehydration with Kona versus Sports or Spring groups. Deep-ocean mineral water shows promise as an optimal rehydrating source over spring water and/or sports drink.

Hydrologic reconnaissance of western Arctic Alaska, 1976 and 1977

USGS Publications Warehouse

Childers, Joseph M.; Kernodle, Donald R.; Loeffler, Robert M.

1979-01-01

Reconnaissance water-resource investigations were conducted on the western Alaskan Arctic Slope during April 1976 and August 1977; these months are times of winter and summer low flow. The information gathered is important for coordinated development in the area. Such development has been spurred by oil and gas discoveries on the North Slope, most notably at Prudhoe Bay. Little water resources information is currently available. The study area extended from the Colville River to the vicinity of Kotzebue. It included the western Arctic Slope and the western foothills of the Brooks Range. Nine springs, nine lakes and eleven rivers were sampled during the April 1976 reconnaissance trip. Its purpose was to locate winter flow and describe its quantity and quality. Field water-quality measurements made at these sites were: ice thickness, water depth, discharge (spring and streams), specific conductance, water temperature, dissolved oxygen, alkalinity (bicarbonate, HOC3), and pH. A followup summer trip was made in August 1977 to determine flood characteristics of twenty selected streams. Bankfull and maximum evident flood-peak discharges were determined by measuring channel geometry and estimating channel roughness. Aquatic invertebrate samples were collected at springs and flood survey sites visited during both reconnaissance trips. (Woodard-USGS)

Water quality deterioration at a karst spring (Gallusquelle, Germany) due to combined sewer overflow: evidence of bacterial and micro-pollutant contamination

NASA Astrophysics Data System (ADS)

Heinz, B.; Birk, S.; Liedl, R.; Geyer, T.; Straub, K. L.; Andresen, J.; Bester, K.; Kappler, A.

2009-04-01

The concurrent use of karst aquifers as drinking water resources and receptors of combined sewer overflow lacking appropriate pre-treatment may cause conflicts between drinking water supply and storm water management. A storm water tank (SWT) for combined wastewater is identified as the source of sporadic contamination of a karst spring (Gallusquelle, “Schwäbische Alb”, SW Germany) used for public water supply. Spring water quality was examined by routine and event sampling and by evaluating physicochemical and microbiological parameters. The total number of microbial colonies growing at 20°C and the number of Escherichia coli colonies rose to values up to four orders of magnitude higher than background, 2-5 days after overflow of the SWT. High concentrations of chloride, sodium, and total organic carbon (TOC) and high values of turbidity coincide with this increase. However, high bacterial contamination is also observed while turbidity and TOC are low. Several wastewater-related organic micro-pollutants such as chlorinated and non-chlorinated organophosphates were detected in the SWT and, depending on their K ow values and their biodegradability, in lower concentrations at the spring.

Lagrangian sampling of wastewater treatment plant effluent in Boulder Creek, Colorado, and Fourmile Creek, Iowa, during the summer of 2003 and spring of 2005--Hydrological and chemical data

USGS Publications Warehouse

Barber, Larry B.; Keefe, Steffanie H.; Kolpin, Dana W.; Schnoebelen, Douglas J.; Flynn, Jennifer L.; Brown, Gregory K.; Furlong, Edward T.; Glassmeyer, Susan T.; Gray, James L.; Meyer, Michael T.; Sandstrom, Mark W.; Taylor, Howard E.; Zaugg, Steven D.

2011-01-01

This report presents methods and data for a Lagrangian sampling investigation into chemical loading and in-stream attenuation of inorganic and organic contaminants in two wastewater treatment-plant effluent-dominated streams: Boulder Creek, Colorado, and Fourmile Creek, Iowa. Water-quality sampling was timed to coincide with low-flow conditions when dilution of the wastewater treatment-plant effluent by stream water was at a minimum. Sample-collection times corresponded to estimated travel times (based on tracer tests) to allow the same "parcel" of water to reach downstream sampling locations. The water-quality data are linked directly to stream discharge using flow- and depth-integrated composite sampling protocols. A range of chemical analyses was made for nutrients, carbon, major elements, trace elements, biological components, acidic and neutral organic wastewater compounds, antibiotic compounds, pharmaceutical compounds, steroid and steroidal-hormone compounds, and pesticide compounds. Physical measurements were made for field conditions, stream discharge, and time-of-travel studies. Two Lagrangian water samplings were conducted in each stream, one in the summer of 2003 and the other in the spring of 2005. Water samples were collected from five sites in Boulder Creek: upstream from the wastewater treatment plant, the treatment-plant effluent, and three downstream sites. Fourmile Creek had seven sampling sites: upstream from the wastewater treatment plant, the treatment-plant effluent, four downstream sites, and a tributary. At each site, stream discharge was measured, and equal width-integrated composite water samples were collected and split for subsequent chemical, physical, and biological analyses. During the summer of 2003 sampling, Boulder Creek downstream from the wastewater treatment plant consisted of 36 percent effluent, and Fourmile Creek downstream from the respective wastewater treatment plant was 81 percent effluent. During the spring of 2005 samplings, Boulder Creek downstream from the wastewater treatment plant was 40 percent effluent, and Fourmile Creek downstream from that wastewater treatment plant was 28 percent effluent. At each site, 300 individual constituents were determined to characterize the water. Most of the inorganic constituents were detected in all of the stream and treatment-plant effluent samples, whereas detection of synthetic organic compounds was more limited and contaminants typically occurred only in wastewater treatment-plant effluents and at downstream sites. Concentrations ranged from nanograms per liter to milligrams per liter.

Hydrogeology, water quality, and ecology of Anderton Branch near the Quail Hollow Landfill, Bedford County, Tennessee, 1995-99

USGS Publications Warehouse

Farmer, James

2004-01-01

The Quail Hollow Landfill, located in southeastern Bedford County on the Highland Rim overlooking the Central Basin karst region of Tennessee, is constructed on the gravelly, clay-rich residuum of the Fort Payne Formation of Mississippian age. A conceptual hydrologic model of the landfill indicated that Anderton Branch was at risk of being affected by the landfill. Ground water flowing beneath the landfill mixes with percolating rainwater that has passed through the landfill and discharges to the surface from numerous weeps, seeps, and springs present in the area. Anderton Branch, adjacent to the landfill site on the north and east, receives most of the discharge from these weeps, seeps, and springs. Anderton Branch also receives water from the Powell Branch drainage basin to the west and south because of diverted flow of ground water through Harrison Spring Cave. The U.S. Geological Survey, in cooperation with the Bedford County Solid Waste Authority, conducted a study to evaluate the effect of the Quail Hollow Landfill on ground- and surface-water quality. During storm runoff, specific conductance was elevated, and cadmium, iron, manganese, lead, and nickel concentrations in Anderton Branch frequently exceeded maximum contaminant levels for drinking water for the State of Tennessee. High chloride inputs to Anderton Branch were detected at two locations?a barnyard straddling the stream and a tributary draining a pond that receives water directly from the landfill. The chloride inputs probably contribute to chloride load levels that are three times higher for Anderton Branch than for the control stream Anthony Branch. Although toxic volatile organic compounds were detected in water from monitoring wells at the landfill, no organic contaminants were detected in domestic water wells adjacent to the landfill or in Anderton Branch. Sons Spring, a karst spring near the landfill, has been affected by the landfill as indicated by an increase in chloride concentrations from 4 milligrams per liter in 1974 to 59 milligrams per liter in 1996. Analysis of water samples from Sons Spring detected concentrations of nickel that exceeded primary drinking-water standards and Tennessee Department of Environment and Conservation fish and aquatic life chronic standards. Trichloroethene, 1,1-dichloroethene, and 1,1-dichloroethane also were detected at Sons Spring. The presence of these chlorinated solvents imply the landfill origin of the contaminants in Sons Spring. Continuous monitoring at Sons Spring indicated a pattern of decreased specific conductance and lower contaminant concentrations after a storm. Contaminant concentrations increased with specific conductance to pre-storm levels after several days. The benthic macroinvertebrate community in Anderton Branch adjacent to the landfill was not different from the communities at control sites upstream and in Anthony Branch. Sons Spring, however, has low abundance and numbers of benthic macroinvertebrate taxa. Toxicity studies using Ceriodaphnia dubia indicated no toxicity in the base flow or storm water in Anderton Branch or in a tributary draining a pond that receives water from the landfill and Sons Spring; however, water collected from Sons Spring resulted in 100 percent mortality to all organisms within 48 hours. High concentrations of nickel were detected in crayfish tissue from control sites and Anderton Branch. Analysis of sediment samples also indicates nickel concentrations are high at control sites upstream of the landfill. Increased levels of the biomarker metallothionein detected in crayfish from Anderton Branch likely are not caused by nickel or cadmium because the levels present in the tissue are not correlated with metallothionein levels. Despite the high levels of certain metals in Anderton Branch during storm flow, the lack of toxicity and the health of the benthic community imply no detectable negative effect from the landfill to the stream. Sons Spring, howe

Geochemistry of the Arbuckle-Simpson Aquifer

USGS Publications Warehouse

Christenson, Scott; Hunt, Andrew G.; Parkhurst, David L.; Osborn, Noel I.

2009-01-01

The Arbuckle-Simpson aquifer in south-central Oklahoma provides water for public supply, farms, mining, wildlife conservation, recreation, and the scenic beauty of springs, streams, and waterfalls. A new understanding of the aquifer flow system was developed as part of the Arbuckle-Simpson Hydrology Study, done in 2003 through 2008 as a collaborative research project between the State of Oklahoma and the Federal government. The U.S. Geological Survey collected 36 water samples from 32 wells and springs in the Arbuckle-Simpson aquifer in 2004 through 2006 for geochemical analyses of major ions, trace elements, isotopes of oxygen and hydrogen, dissolved gases, and dating tracers. The geochemical analyses were used to characterize the water quality in the aquifer, to describe the origin and movement of ground water from recharge areas to discharge at wells and springs, and to determine the age of water in the aquifer.

Rare earth elements geochemistry in springs from Taftan geothermal area SE Iran

NASA Astrophysics Data System (ADS)

Shakeri, Ata; Ghoreyshinia, Sayedkazem; Mehrabi, Behzad; Delavari, Morteza

2015-10-01

Concentrations of rare earth elements (REEs) were determined in springs and andesitic-dacitic rocks of Taftan geothermal field. Hydrochemical results of major ions indicate that thermal springs are Na-SO4-Cl and Ca-SO4-Cl types. Concentrations of REEs are in ranges of 10- 4 to 1.2 and 49 to 62 times of chondrite for springwater and rock samples, respectively. The thermal (STS and TTS) and the cold (APS) springs with low pH values exhibit a very high REE contents (0.64 to 3.15 mg/l). Saturation index indicates that Fe and Al phases can control dissolved REE concentration in FTS and PF cold springs. The speciation of REE complexes indicates dominant presence of LnSO4+ and free ion in the Taftan thermal springs. In APS cold spring with pH 4, fluoride complexes are dominate over the free ion and sulfate species, while in PF and FTS cold springs with pH 6.4 and 7, respectively, carbonate complexes (LnCO3+) are predominant species. Chondrite-normalized pattern for the low-pH waters show very distinctive gull-wing patterns, characteristic feature of acid-sulfate geothermal systems, and are similar to those of the host rocks. Chemical characteristics of rare earth elements in spring and volcanic rock samples indicate that REEs are originated from the andesitic-dacitic host rocks. Whole-rock-normalized REE patterns and petrographic evidences show that rare earth elements leached mainly from marginal alteration of minerals and matrix decomposition in volcanic rocks. In chondrite-normalized REE patterns, significant negative Eu anomaly in the cold springs compare to the thermal and acidic springs indicates that alteration of plagioclase is more intense in the later, corresponding to increasing in temperature and acidic state of reactant water.

Sample Return from Ancient Hydrothermal Springs

NASA Technical Reports Server (NTRS)

Allen, Carlton C.; Oehler, Dorothy Z.

2008-01-01

Hydrothermal spring deposits on Mars would make excellent candidates for sample return. Molecular phylogeny suggests that that life on Earth may have arisen in hydrothermal settings [1-3], and on Mars, such settings not only would have supplied energy-rich waters in which martian life may have evolved [4-7] but also would have provided warm, liquid water to martian life forms as the climate became colder and drier [8]. Since silica, sulfates, and clays associated with hydrothermal settings are known to preserve geochemical and morphological remains of ancient terrestrial life [9-11], such settings on Mars might similarly preserve evidence of martian life. Finally, because formation of hydrothermal springs includes surface and subsurface processes, martian spring deposits would offer the potential to assess astrobiological potential and hydrological history in a variety of settings, including surface mineralized terraces, associated stream deposits, and subsurface environments where organic remains may have been well protected from oxidation. Previous attempts to identify martian spring deposits from orbit have been general or limited by resolution of available data [12-14]. However, new satellite imagery from HiRISE has a resolution of 28 cm/pixel, and based on these new data, we have interpreted several features in Vernal Crater, Arabia Terra as ancient hydrothermal springs [15, 16].

Natural radioactivity in various water samples and radiation dose estimations in Bolu province, Turkey.

PubMed

Gorur, F Korkmaz; Camgoz, H

2014-10-01

The level of natural radioactivity for Bolu province of north-western Turkey was assessed in this study. There is no information about radioactivity measurement reported in water samples in the Bolu province so far. For this reason, gross α and β activities of 55 different water samples collected from tap, spring, mineral, river and lake waters in Bolu were determined. The mean activity concentrations were 68.11 mBq L(-1), 169.44 mBq L(-1) for gross α and β in tap water. For all samples the gross β activity is always higher than the gross α activity. All value of the gross α were lower than the limit value of 500 mBq L(-1) while two spring and one mineral water samples were found to have gross β activity concentrations of greater than 1000 mBq L(-1). The associated age-dependent dose from all water ingestion in Bolu was estimated. The total dose for adults had an average value exceeds the WHO recommended limit value. The risk levels from the direct ingestion of the natural radionuclides in tap and mineral water in Bolu were determinated. The mean (210)Po and (228)Ra risk the value of tap and mineral waters slightly exceeds what some consider on acceptable risk of 10(-4) or less. Copyright © 2014 Elsevier Ltd. All rights reserved.

[Occurrence and morphology of some predatory fungi, amoebicidal, rotifericidal and nematodicidal, in the surface waters of Białystok region].

PubMed

Kiziewicz, Bozena; Czeczuga, Bazyli

2003-01-01

Studies concerned the occurrence of some predatory fungi in the surface waters: springs, rivers, lakes and ponds of Białystok region, collected in years 1999-2002. The following species of predatory fungi, amoebicidal, rotifericidal and nematodicidal were found: Arthrobotrys oligospora Fresenius, Zoophagus insidians Somlnestorff, Somnuerstorffia spinosa Arnaudov, Dactylaria brochopaga Drechsler, Euryancale sacciospora Dreschler and Zoopage phanera Drechsler. Physico-chemical parameters of waters in basins and water-courses did not prove important effect on existence of fungi. A little more species of predatory fungi were recorded in samples of water in early spring and late autumn.

Tracer-based identification of rock glacier thawing in a glacierized Alpine catchment

NASA Astrophysics Data System (ADS)

Engel, Michael; Penna, Daniele; Tirler, Werner; Comiti, Francesco

2017-04-01

Current warming in high mountains leads to increased melting of snow, glacier ice and permafrost. In particular rock glaciers, as a creeping form of mountain permafrost, may release contaminants such as heavy metals into the stream during intense melting periods in summer. This may have strong impacts on both water quantity and quality of fresh water resources but might also harm the aquatic fauna in mountain regions. In this context, the present study used stable isotopes of water and electrical conductivity (EC) combined with trace, major and minor elements to identify the influence of permafrost thawing on the water quality in the glacierized Solda catchment (130 km2) in South Tyrol (Italy). We carried out a monthly sampling of two springs fed by an active rock glacier at about 2600 m a.s.l. from July to October 2015. Furthermore, we took monthly water samples from different stream sections of the Solda River (1110 to m a.s.l.) from March to November 2015. Meteorological data were measured by an Automatic Weather Station at 2825 m a.s.l. of the Hydrographic Office (Autonomous Province of Bozen-Bolzano). First results show that water from the rock glacier springs and stream water fell along the global meteoric water line. Spring water was slightly more variable in isotopic ratio (δ2H: -91 to - 105 ) and less variable in dissolved solutes (EC: 380 to 611 μS/cm) than stream water (δ2H: -96 to - 107 ‰ and EC: 212 to 927 μS/cm). Both spring water and stream water showed a pronounced drop in EC during July and August, very likely induced by increased melt water dilution. In both water types, element concentrations of Ca and Mg were highest (up to 160 and 20 mg/l, respectively). In September, spring water showed higher concentrations in Cu, As, and Pb than stream water, indicating that these elements partly exceeded the concentration limit for drinking water. These observations highlight the important control, which rock glacier thawing may have on water quality of alpine streams and they underline the need for water quality monitoring at high elevations. Keywords: stable isotopes of water; heavy metals, permafrost thawing; alpine rivers; glacierized catchment

Aquifer susceptibility in Virginia, 1998-2000

USGS Publications Warehouse

Nelms, David L.; Harlow, George E.; Plummer, Niel; Busenberg, Eurybiades

2003-01-01

The U.S. Geological Survey (USGS), in cooperation with the Virginia Department of Health, sampled water from 171 wells and springs across the Commonwealth of Virginia between 1998 and 2000 as part of the Virginia Aquifer Susceptibility study. Most of the sites sampled are public water supplies that are part of the comprehensive Source Water Assessment Program for the Commonwealth. The fundamental premise of the study was that the identification of young waters (less than 50 years) by multiple environmental tracers could be used as a guide for classifying aquifers in terms of susceptibility to contamination from near-surface sources. Environmental tracers, including chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), tritium (3H), and tritium/helium-3 (3H/3He), and carbon isotopes (14C and d13C) were used to determine the age of water discharging from wells and springs. Concentrations of CFCs greater than 5 picograms per kilogram and 3H concentrations greater than 0.6 tritium unit were used as thresholds to indicate that parts of the aquifer sampled have a component of young water and are, therefore, susceptible to near-surface contamination. Concentrations of CFCs exceeded the susceptibility threshold in 22 percent of the wells and in one spring sampled in the Coastal Plain regional aquifer systems. About 74 percent of the samples from wells with the top of the first water zone less than 100 feet below land surface exceeded the threshold values, and water supplies developed in the upper 100 feet of the Coastal Plain are considered to be susceptible to contamination from near-surface sources. The maximum depth to the top of the screened interval for wells that contained CFCs was less than 150 feet. Wells completed in the deep confined aquifers in the Coastal Plain generally contain water older than 1,000 years, as indicated by carbon-14 dating, and are not considered to be susceptible to contamination under natural conditions. All of the water samples from wells and springs in the fractured-rock terrains (the Appalachian Plateaus, Valley and Ridge, Blue Ridge, and Piedmont regional aquifer systems) contained concentrations of CFCs and 3H greater than one or both of the thresholds. Because all of the water samples exceeded at least one of the threshold values, young water is present throughout most of these regional aquifer systems; therefore, water supplies developed in these systems are susceptible to contamination from near-surface sources. No relation between well depth and presence of CFCs is evident from samples in the fractured-rock terrains. More than 95 percent of the samples for which the dating methods were applicable contained waters with apparent ages less than 35 years. About 5 percent of these samples, most of which were from the Blue Ridge and Piedmont regional aquifer systems, contained young waters with apparent ages of less than 5 years. Most of the samples from the Valley and Ridge Carbonate, Blue Ridge, and Piedmont regional aquifer systems had young water fractions of more than 50 percent, whereas samples from the Coastal Plain Shallow and Appalachian Plateaus regional aquifer systems contained less than 40 percent young waters. Concentrations of CFCs in excess of air-water equilibrium, which can indicate that nonatmospheric sources (such as sewage effluent) have introduced CFCs into the ground-water system, were measured in 6 and 48 percent of the water samples from the Coastal Plain and fractured-rock regional aquifer systems, respectively. The nitrate (NO3) concentrations greater than the USGS detection level of 0.05 milligrams per liter generally increase as the apparent age of the young water fraction decreases, with the highest NO3 concentrations for samples in which one or more of the CFCs are above modern atmospheric mixing ratios (commonly referred to as 'contaminated' for ground-water dating purposes). Most of the samples in which NO3 was detected w

Changes in sources and storage in a karst aquifer during a transition from drought to wet conditions

USGS Publications Warehouse

Wong, C.I.; Mahler, B.J.; Musgrove, M.; Banner, J.L.

2012-01-01

Understanding the sources and processes that control groundwater compositions and the timing and magnitude of groundwater vulnerability to potential surface-water contamination under varying meteorologic conditions is critical to informing groundwater protection policies and practices. This is especially true in karst terrains, where infiltrating surface water can rapidly affect groundwater quality. We analyzed the evolution of groundwater compositions (major ions and Sr isotopes) during the transition from extreme drought to wetconditions, and used inverse geochemical modeling (PHREEQC) to constrain controls on groundwater compositions during this evolution. Spring water and groundwater from two wells dominantly receiving diffuse and conduit flow (termed diffuse site and conduit site, respectively) in the Barton Springs segment of the Edwards aquifer (central Texas, USA) and surface water from losing streams that recharge the aquifer were sampled every 3–4 weeks during November 2008–March 2010. During this period, water compositions at the spring and conduit sites changed rapidly but there was no change at the diffuse site, illustrating the dual nature (i.e., diffuse vs. conduit) of flow in this karst system. Geochemical modeling demonstrated that, within a month of the onset of wetconditions, the majority of spring water and groundwater at the conduit site was composed of surface water, providing quantitative information on the timing and magnitude of the vulnerability of groundwater to potential surface-water contamination. The temporal pattern of increasing spring discharge and changing pattern of covariation between spring discharge and surface-water (steam) recharge indicates that that there were two modes of aquifer response—one with a small amount of storage and a second that accommodates more storage.

Water Source Pollution and Disease Diagnosis in a Nigerian Rural Community.

ERIC Educational Resources Information Center

Sangodoyin, A. Y.

1991-01-01

Samples from five water sources (spring, borehole, pond, stream, and well) in rural Nigerian communities were tested. Results include source reliabilities in terms of water quality and quantity, pollution effects upon water quality, epidemiological effects related to water quantity and waste disposal, and impact of water quality improvement upon…

Total Mercury and Methylmercury in Indiana Streams, August 2004-September 2006

USGS Publications Warehouse

Ulberg, Amanda L.; Risch, Martin R.

2008-01-01

Total mercury and methylmercury were determined by use of low (subnanogram per liter) level analytical methods in 225 representative water samples collected following ultraclean protocols at 25 Indiana monitoring stations in a statewide network, on a seasonal schedule, August 2004-September 2006. The highest unfiltered total mercury concentrations were at six monitoring stations - five that are downstream from urban and industrial wastewater discharges and that have upstream drainage areas more than 1,960 square miles and one that is downstream from active and abandoned mine lands and that has an upstream drainage area of 602 square miles. Total mercury concentrations in unfiltered samples ranged from 0.24 to 26.9 nanograms per liter (ng/L), with a median of 2.35 ng/L. The highest concentrations of total mercury, those in the 90th percentile and above, were more than 9.05 ng/L, and most were in samples collected during winter and spring 2006 during changing streamflow hydrograph conditions. Seasonal medians for unfiltered total mercury were highest during winter and spring. Instantaneous streamflow and turbidity at the time of sample collection also were highest in winter and spring and potentially indicate conditions for the most particulate mercury transport. Samples with the highest total mercury concentrations were from water that had the highest turbidity at the time of sample collection. Unfiltered total mercury concentrations were significantly lower in samples collected at five stations downstream from dams. Values for particulate total mercury and streamflow also were significantly lower at these five stations. Total mercury concentrations equaled or exceeded the 2007 Indiana chronic aquatic criterion of 12 ng/L in 5.8 percent of samples and at 10 monitoring stations. Most of the total mercury in these 13 samples was estimated to be particulate. Most of the samples with mercury concentrations that equaled or exceeded the 12 ng/L criterion were collected during winter and spring 2006 during changing streamflow hydrograph conditions and in streamflow that was high for 2004-2006. Methylmercury was detected in 83 percent of unfiltered samples; reported concentrations ranged from 0.04 to 0.57 ng/L, with a median of 0.09 ng/L. The highest concentrations of methylmercury, those in the 90th percentile and above, were more than 0.25 ng/L, and most were in samples collected during spring and summer. Methylation efficiency in most samples was less than 5.8 percent, but was as much as 24.6 percent. Seasonal medians for methylmercury were highest during spring and summer. Seasonal medians for water temperatures at the time of sample collection were highest during these seasons and potentially indicate conditions for the most formation of methylmercury. The low streamflow statistical category had the significantly highest methylation efficiency.

Groundwater flow cycling between a submarine spring and an inland fresh water spring

USGS Publications Warehouse

Davis, J. Hal; Verdi, Richard

2014-01-01

Spring Creek Springs and Wakulla Springs are large first magnitude springs that derive water from the Upper Floridan Aquifer. The submarine Spring Creek Springs are located in a marine estuary and Wakulla Springs are located 18 km inland. Wakulla Springs has had a consistent increase in flow from the 1930s to the present. This increase is probably due to the rising sea level, which puts additional pressure head on the submarine Spring Creek Springs, reducing its fresh water flow and increasing flows in Wakulla Springs. To improve understanding of the complex relations between these springs, flow and salinity data were collected from June 25, 2007 to June 30, 2010. The flow in Spring Creek Springs was most sensitive to rainfall and salt water intrusion, and the flow in Wakulla Springs was most sensitive to rainfall and the flow in Spring Creek Springs. Flows from the springs were found to be connected, and composed of three repeating phases in a karst spring flow cycle: Phase 1 occurred during low rainfall periods and was characterized by salt water backflow into the Spring Creek Springs caves. The higher density salt water blocked fresh water flow and resulted in a higher equivalent fresh water head in Spring Creek Springs than in Wakulla Springs. The blocked fresh water was diverted to Wakulla Springs, approximately doubling its flow. Phase 2 occurred when heavy rainfall resulted in temporarily high creek flows to nearby sinkholes that purged the salt water from the Spring Creek Springs caves. Phase 3 occurred after streams returned to base flow. The Spring Creek Springs caves retained a lower equivalent fresh water head than Wakulla Springs, causing them to flow large amounts of fresh water while Wakulla Springs flow was reduced by about half.

Assessment of drinking water quality using indicator bacteria and bacteriophages.

PubMed

Méndez, Javier; Audicana, Ana; Cancer, Mercedes; Isern, Anna; Llaneza, Julian; Moreno, Belén; Navarro, Mercedes; Tarancón, M Lluisa; Valero, Fernando; Ribas, Ferran; Jofre, Juan; Lucena, Francisco

2004-09-01

Bacterial indicators and bacteriophages suggested as potential indicators of water quality were determined by public laboratories in water from springs, household water wells, and rural and metropolitan water supplies in north-eastern Spain. Indicator bacteria were detected more frequently than bacteriophages in springs, household water wells and rural water supplies. In contrast, positive bacteriophage detections were more numerous than those of bacteria in metropolitan water supplies. Most of the metropolitan water supply samples containing indicators had concentrations of chlorine below 0.1 mg l(-1), their indicator loads resembling more closely those of rural water supplies than any other samples taken from metropolitan water supplies. The number of samples from metropolitan water supplies containing more than 0.1 mg l(-1) of chlorine that contained phages clearly outnumbered those containing indicator bacteria. Some association was observed between rainfall and the presence of indicators. Sediments from service reservoirs and water from dead ends in the distribution network of one of the metropolitan water supplies were also tested. Bacterial indicators and phages were detected in a higher percentage than in samples of tap water from the same network. Additionally, indicator bacteria were detected more frequently than bacteriophages in sediments of service reservoirs and water from dead end samples. We conclude that naturally occurring indicator bacteria and bacteriophages respond differently to chlorination and behave differently in drinking water distribution networks. Moreover, this study has shown that testing for the three groups of phages in routine laboratories is easy to implement and feasible without the requirement for additional material resources for the laboratories.

Quality of water types in Ukraine evaluated by WaterTox bioassays.

PubMed

Arkhipchuk, V V; Malinovskaya, M V

2002-01-01

The quality of river, ground-, and tap water was analyzed using the basic set of WaterTox bioassays [Daphnia (Daphnia magna), Hydra (Hydra attenuata), and lettuce (Lactuca sativa)] as well as two additional bioassays, onion (Allium cepa) and microalga (Selenastrum gracile). Samples of these waters were also concentrated fivefold using a solid-phase procedure. The results of the Daphnia and Hydra bioassays showed that the winter and spring concentrated and nonconcentrated samples from the Dnieper and Desna rivers, the main water supply sources for Kiev, were nontoxic. In spring, after concentration, the two river samples brought about the same relative decrease in the lettuce root length (by 35%, p < 0.001), where the Desna River sample considerably reduced (by 79.1%, p < 0.001) the number of microalga cells. Samples of groundwater from countryside wells studied in autumn in several villages of the Kiev region were toxic mainly to Hydra (sublethal effects were found in 11%-78%) and lettuce (the root length decreased 15%-56%). Studies of tap water samples from two of the largest cities of Ukraine, Kiev and Kharkiv, were found to be nontoxic to both plants, lettuce and onion, but showed increased sublethal and lethal effects on both animals, Daphnia and Hydra, as well as a reduced number of microalgae. Different bioassays were sensitive to varying degrees to different water types. This reinforces the necessity of using sets of bioassays in toxicity evaluation. In general, all the tested water samples demonstrated some toxicity. These data suggest that drinking water quality in Ukraine needs improvement. Copyright 2002 Wiley Periodicals, Inc.

Exposure assessment of radon in the drinking water supplies: a descriptive study in Palestine

PubMed Central

2012-01-01

Background Radon gas is considered as a main risk factor for lung cancer and found naturally in rock, soil, and water. The objective of this study was to determine the radon level in the drinking water sources in Nablus city in order to set up a sound policy on water management in Palestine. Methods This was a descriptive study carried out in two phases with a random sampling technique in the second phase. Primarily, samples were taken from 4 wells and 5 springs that supplied Nablus city residents. For each source, 3 samples were taken and each was analyzed in 4 cycles by RAD 7 device manufactured by Durridge Company. Secondly, from the seven regions of the Nablus city, three samples were taken from the residential tap water of each region. Regarding the old city, ten samples were taken. Finally, the mean radon concentration value for each source was calculated. Results The mean (range) concentration of radon in the main sources were 6.9 (1.5-23.4) Becquerel/liter (Bq/L). Separately, springs and wells' means were 4.6 Bq/L and 9.5 Bq/L; respectively. For the residential tap water in the 7 regions, the results of the mean (range) concentration values were found to be 1.0 (0.9-1.3) Bq/L. For the old city, the mean (range) concentration values were 2.3 (0.9-3.9) Bq/L. Conclusions Except for Al-Badan well, radon concentrations in the wells and springs were below the United State Environmental Protection Agency maximum contaminated level (U.S EPA MCL). The level was much lower for tap water. Although the concentration of radon in the tap water of old city were below the MCL, it was higher than other regions in the city. Preventive measures and population awareness on radon's exposure are recommended. PMID:22243625

Exposure assessment of radon in the drinking water supplies: a descriptive study in Palestine.

PubMed

Al Zabadi, Hamzeh; Musmar, Samar; Issa, Shaza; Dwaikat, Nidal; Saffarini, Ghassan

2012-01-13

Radon gas is considered as a main risk factor for lung cancer and found naturally in rock, soil, and water. The objective of this study was to determine the radon level in the drinking water sources in Nablus city in order to set up a sound policy on water management in Palestine. This was a descriptive study carried out in two phases with a random sampling technique in the second phase. Primarily, samples were taken from 4 wells and 5 springs that supplied Nablus city residents. For each source, 3 samples were taken and each was analyzed in 4 cycles by RAD 7 device manufactured by Durridge Company. Secondly, from the seven regions of the Nablus city, three samples were taken from the residential tap water of each region. Regarding the old city, ten samples were taken. Finally, the mean radon concentration value for each source was calculated. The mean (range) concentration of radon in the main sources were 6.9 (1.5-23.4) Becquerel/liter (Bq/L). Separately, springs and wells' means were 4.6 Bq/L and 9.5 Bq/L; respectively. For the residential tap water in the 7 regions, the results of the mean (range) concentration values were found to be 1.0 (0.9-1.3) Bq/L. For the old city, the mean (range) concentration values were 2.3 (0.9-3.9) Bq/L. Except for Al-Badan well, radon concentrations in the wells and springs were below the United State Environmental Protection Agency maximum contaminated level (U.S EPA MCL). The level was much lower for tap water. Although the concentration of radon in the tap water of old city were below the MCL, it was higher than other regions in the city. Preventive measures and population awareness on radon's exposure are recommended.

Hydrogeochemical response of groundwater springs during central Italy earthquakes (24 August 2016 and 26-30 October 2016)

NASA Astrophysics Data System (ADS)

Archer, Claire; Binda, Gilberto; Terrana, Silvia; Gambillara, Roberto; Michetti, Alessandro; Noble, Paula; Petitta, Marco; Rosen, Michael; Pozzi, Andrea; Bellezza, Paolo; Brunamonte, Fabio

2017-04-01

Co-seismic hydrological and chemical response at groundwater springs following strong earthquakes is a significant concern in the Apennines, a region in central Italy characterized by regional karstic groundwater systems interacting with active normal faults capable of producing Mw 6.5 to 7.0 seismic events. These aquifers also provide water supply to major metropolitan areas in the region. On August 24, 2016, a Mw 6.0 earthquake hit Central Italy in the area where Latium joins Umbria, Marche and Abruzzi; this was immediately followed one hour later by a Mw 5.4 shock. The epicenter of the event was located at the segment boundary between the Mt. Vettore and Mt. Laga faults. On October 26, 2016 and on October 30, 2016, three other big shocks (Mw 5.5, Mw 6.0 and Mw 6.5) ruptured again the Vettore Fault and its NW extension. Immediately after Aug. 24, we sampled springs discharging different aquifers in the Rieti area, including the Peschiera spring, which feeds the aqueduct of Rome. Thermal springs connected with deep groundwater flowpaths were also sampled. These springs, sampled previously in 2014 and 2015, provide some pre-earthquake data. Moreover, we sampled 4 springs along the Mt. Vettore fault system: 3 small springs at Forca di Presta, close to the trace of the earthquake surface ruptures, and two in Castel Sant'Angelo sul Nera. The latter are feeding the Nera aqueduct and the Nerea S.p.A. mineral water plant, which also kindly allowed us to collect bottled water samples from the pre-seismic period. The aim of this study is to evaluate the strong earthquake sequence effects on the hydrochemistry and flow paths of groundwater from different aquifer settings based on analysis before and after seismic events. The comparison between the responses of springs ca. 40 km from the epicenter (Rieti basin) and the springs located near the epicenter (Castelsantangelo sul Nera and Forca di Presta) is especially significant for understanding the resilience of groundwater systems in an active tectonic zone because these springs are located near parallel active fault segments within the same extensional regime. The epicentral springs are subject to the direct effects of the shaking and coseismic fault displacement; the more distal ones to the tectonic displacement of large hydrogeologic structures, which affect the chemical composition and flow path even with late responses, lasting for weeks and months after the mainshocks. Temporal trend analysis, based on pre-earthquake and post-earthquake chemical-physical data, point out alteration of different parameters. For example, the lowering of different trace metals in all areas after the first earthquake. These changes could be due to fluctuations in redox equilibria related to degassing and/or interactions with deeper fluid flow. In the Rieti springs, the EC, alkalinity, and trace metals show small transient responses within 1-3 days following the main shocks, however δ2H vs. δ18O remain stable and plot with previous data, indicating no major change in recharge source. Analysis is ongoing and preliminary results will be presented here.

Quantitative Determination of Spring Water Quality Parameters via Electronic Tongue.

PubMed

Carbó, Noèlia; López Carrero, Javier; Garcia-Castillo, F Javier; Tormos, Isabel; Olivas, Estela; Folch, Elisa; Alcañiz Fillol, Miguel; Soto, Juan; Martínez-Máñez, Ramón; Martínez-Bisbal, M Carmen

2017-12-25

The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These noble metals have a high durability and are not demanding for maintenance, features required for the development of future automated equipment. A pulse voltammetry study was conducted in 83 spring water samples to determine concentrations of nitrate (range: 6.9-115 mg/L), sulfate (32-472 mg/L), fluoride (0.08-0.26 mg/L), chloride (17-190 mg/L), and sodium (11-94 mg/L) as well as pH (7.3-7.8). These parameters were also determined by routine analytical methods in spring water samples. A partial least squares (PLS) analysis was run to obtain a model to predict these parameter. Orthogonal signal correction (OSC) was applied in the preprocessing step. Calibration (67%) and validation (33%) sets were selected randomly. The electronic tongue showed good predictive power to determine the concentrations of nitrate, sulfate, chloride, and sodium as well as pH and displayed a lower R² and slope in the validation set for fluoride. Nitrate and fluoride concentrations were estimated with errors lower than 15%, whereas chloride, sulfate, and sodium concentrations as well as pH were estimated with errors below 10%.

Some investigations of the deposition of travertine from Hot Springs-I. The isotopic chemistry of a travertine-depositing spring

USGS Publications Warehouse

Friedman, I.

1970-01-01

The isotopic compositions of the travertine and of the hot spring solutions were studied at Main Springs and New Highland Terrace in the Mammoth Hot Springs area of Yellowstone Park. The springs issue at 74??C and a pH of 6.65 and the carbon isotopic composition of the travertine depositing at the orifice is +2%.??C13 (PDB). As the water travels out from the orifice, it cools and loses CO2. The travertine depositing at lower temperature is enriched in C13, reaching values of +4.8%. and the solution has a pH of 8.2 at 27??C. The ??C13 of the carbon species in solution is about -2.3%. at 74?? and about +4.3 at 27??C. Therefore, the difference in ??C13 between the solid and solution is approximately 4%. at 74?? and decreases to zero at about 20??C. These differences are shown to be due to kinetic (non-equilibrium) factors. The ??O18 contents of the travertine and water show that in most samples the carbonate oxygen is in equilibrium with the water O18 at the temperatures of deposition. This is especially true for travertine depositing slowly and at temperatures above about 50??C. Calculations based on pH and alkalinity titrations of the hot spring waters in situ show that at the spring orifice the water is very high in free CO2, which is quickly lost in transit. The springs are supersaturated with respect to both aragonite and calcite during most of their travel in the open air. The carbon isotopic composition of the travertine is similar to that in the marine carbonates that are adjacent to the springs and that are the probable source of the calcium carbonate. The travertine from inactive prehistoric springs near Mammoth has similar ??C13 and O18 to that from the active springs. Soda Butte, an inactive center 25 miles east of Mammoth, contains heavier carbon and oxygen than the springs near Mammoth. ?? 1970.

River-spring connectivity and hydrogeochemical interactions in a shallow fractured rock formation. The case study of Fuensanta river valley (Southern Spain)

NASA Astrophysics Data System (ADS)

Barberá, J. A.; Andreo, B.

2017-04-01

In upland catchments, the hydrology and hydrochemistry of streams are largely influenced by groundwater inflows, at both regional and local scale. However, reverse conditions (groundwater dynamics conditioned by surface water interferences), although less described, may also occur. In this research, the local river-spring connectivity and induced hydrogeochemical interactions in intensely folded, fractured and layered Cretaceous marls and marly-limestones (Fuensanta river valley, S Spain) are discussed based on field observations, tracer tests and hydrodynamic and hydrochemical data. The differential flow measurements and tracing experiments performed in the Fuensanta river permitted us to quantify the surface water losses and to verify its direct hydraulic connection with the Fuensanta spring. The numerical simulations of tracer breakthrough curves suggest the existence of a groundwater flow system through well-connected master and tributary fractures, with fast and multi-source flow components. Furthermore, the multivariate statistical analysis conducted using chemical data from the sampled waters, the geochemical study of water-rock interactions and the proposed water mixing approach allowed the spatial characterization of the chemistry of the springs and river/stream waters draining low permeable Cretaceous formations. Results corroborated that the mixing of surface waters, as well as calcite dissolution and CO2 dissolution/exsolution, are the main geochemical processes constraining Fuensanta spring hydrochemistry. The estimated contribution of the tributary surface waters to the spring flow during the research period was approximately 26-53% (Fuensanta river) and 47-74% (Convento stream), being predominant the first component during high flow and the second one during the dry season. The identification of secondary geochemical processes (dolomite and gypsum dissolution and dedolomitization) in Fuensanta spring waters evidences the induced hydrogeochemical changes resulting from the allogenic recharge. This research highlights the usefulness of an integrated approach based on river and spring flow examination, dye tracing interpretation and regression and multivariate statistical analysis using hydrochemical data for surface water-groundwater interaction assessment in fractured complex environments worldwide, whose implementation becomes critical for an appropriate groundwater policy.

Arsenic and antimony in geothermal waters of Yellowstone National Park, Wyoming, USA

USGS Publications Warehouse

Stauffer, R.E.; Thompson, J.M.

1984-01-01

A total of 268 thermal spring samples were analyzed for total soluble As using reduced molybdenum-blue; 27 of these samples were also analyzed for total Sb using flame atomic absorption spectrometry. At Yellowstone the Cl As atomic ratio is nearly constant among neutral-alkaline springs with Cl > 100 mg L-1, and within restricted geographic areas, indicating no differential effects of adiabatic vs. conductive cooling on arsenic. The Cl As ratio increases with silica and decreases with decreasing Cl ??CO3; the latter relationship is best exemplified for springs along the extensively sampled SE-NW trend within the Lone Star-Upper-Midway Basin region. The relationship between Cl As and Cl ??CO3 at Yellowstone suggests a possible rock leaching rather than magmatic origin for much of the Park's total As flux. Condensed vapor springs are low in both As and Cl. Very high Cl As ratios ( > 1000) are associated exclusively with highly diluted (Cl < 100 mg L-1) mixed springs in the Norris and Shoshone Basins and in the Upper White Creek and Firehole Lake areas of Lower Basin. The high ratios are associated with acidity and/or oxygen and iron; they indicate precipitation of As following massive dilution of the Asbearing high-Cl parent water. Yellowstone Sb ranged from 0.009 at Mammoth to 0.166 mg L-1 at Joseph's Coat Spring. Within basins, the Cl Sb ratio increases as the Cl ??CO3 ratio decreases, in marked contrast to As. Mixed springs also have elevated Cl Sb ratios. White (1967) and Weissberg (1969) previously reported stibnite (Sb2S3), but not orpiment (As2S3), precipitating in the near surface zone of alkaline geothermal systems. ?? 1984.

Groundwater, springs, and stream flow generation in an alpine meadow of a tropical glacierized catchment

NASA Astrophysics Data System (ADS)

Gordon, R.; Lautz, L. K.; McKenzie, J. M.; Mark, B. G.; Chavez, D.

2013-12-01

Melting tropical glaciers supply approximately half of dry season stream discharge in glacierized valleys of the Cordillera Blanca, Peru. The remainder of streamflow originates as groundwater stored in alpine meadows, moraines and talus slopes. A better understanding of the dynamics of alpine groundwater, including sources and contributions to streamflow, is important for making accurate estimates of glacial inputs to the hydrologic budget, and for our ability to make predictions about future water resources as glaciers retreat. Our field study, conducted during the dry season in the Llanganuco valley, focused on a 0.5-km2 alpine meadow complex at 4400 m elevation, which includes talus slopes, terminal moraines, and a debris fan. Two glacial lakes and springs throughout the complex feed a network of stream channels that flow across the meadow (~2 km total length). We combined tracer measurements of stream and spring discharge and groundwater-surface water exchange with synoptic sampling of water isotopic and geochemical composition, in order to characterize and quantify contributions to streamflow from different geomorphic features. Surface water inputs to the stream channels totaled 58 l/s, while the stream gained an additional 57 l/s from groundwater inputs. Water chemistry is primarily controlled by flowpath type (surface/subsurface) and length, as well as bedrock lithology, while stable water isotopic composition appears to be controlled by water source (glacial lake, meadow or deep groundwater). Stream water chemistry is most similar to meadow groundwater springs, but isotopic composition suggests that the majority of stream water, which issues from springs at the meadow/fan interface, is from the same glacial source as the up-gradient lake. Groundwater sampled from piezometers in confined meadow aquifers is unique in both chemistry and isotopic composition, but does not contribute a large percentage of stream water exiting this small meadow, as quantified by discharge measurements and isotopic mixing. However, we expect that as streams flow down through extensive meadows and wetlands in many Cordillera Blanca valleys, meadow groundwater is a more significant contributor to streamflow. Results from this small, high meadow in Llanganuco will be compared to a larger and lower-elevation meadow system in the Quilcayhuanca valley.

Water quality of Rob Roy Reservoir and Lake Owen, Albany County, and Granite Springs and Crystal Lake Reservoirs, Laramie County, Wyoming, 1997-98

USGS Publications Warehouse

Ogle, Kathy Muller; Peterson, D.A.; Spillman, Bud; Padilla, Rosie

1999-01-01

The water quality of four reservoirs was assessed during 1997 and 1998 as a cooperative project between the Cheyenne Board of Public Utilities and the U. S. Geological Survey. The four reservoirs, Rob Roy, Lake Owen, Granite Springs, and Crystal Lake, provide approximately 75 percent of the public water supply for Cheyenne, Wyoming. Samples of water and bottom sediment were collected and analyzed for selected physical, chemical, and biological characteristics to provide data about the reservoirs. Water flows between the reservoirs through a series of pipelines and stream channels. The reservoirs differ in physical characteristics such as elevation, volume, and depth.Profiles of temperature, dissolved oxygen, specific conductance, and pH were examined. Three of the four reservoirs exhibited stratification during the summer. The profiles indicate that stratification develops in all reservoirs except Lake Owen. Stratification developed in Rob Roy, Granite Springs, and Crystal Lake Reservoirs by mid-July in 1998 and continued until September, with the thickness of the epilimnion increasing during that time. Secchi disk readings indicated Rob Roy Reservoir had the clearest water of the four reservoirs studied.The composition of the phytoplankton community was different in the upper two reservoirs from that in the lower two reservoirs. Many of the species found in Rob Roy Reservoir and Lake Owen are associated with oligotrophic, nutrient-poor conditions. In contrast, many of the species found in Granite Springs and Crystal Lake Reservoirs are associated with mesotrophic or eutrophic conditions. The total number of taxa identified also increased downstream.The chemical water type in the reservoirs was similar, but dissolved-solids concentrations were greater in the downstream reservoirs. Water in all four reservoirs was a calcium-bicarbonate type. In the fall of 1997, Rob Roy Reservoir had the lowest dissolved-solids concentration (19 milligrams per liter), whereas Crystal Lake Reservoir had the highest concentration (63 milligrams per liter). Relatively little differences in the concentrations of major-ion species were noted between samples collected near the surface and near the bottom of the same reservoir. In contrast, iron and manganese concentrations generally were higher in samples collected near the bottom of a reservoir than in near-surface samples collected from the same reservoir.Composite bottom-sediment samples from all four reservoirs contained similar concentrations of bulk constituents such as aluminum, iron, phosphorus and titanium, but varied in concentrations of trace elements. Trace-element concentrations in Rob Roy Reservoir and Lake Owen were similar to the crustal average, whereas in Granite Springs and Crystal Lake Reservoirs the concentrations were similar to granitic rocks.

Recent (2008-10) concentrations and isotopic compositions of nitrate and concentrations of wastewater compounds in the Barton Springs zone, south-central Texas, and their potential relation to urban development in the contributing zone

USGS Publications Warehouse

Mahler, Barbara J.; Musgrove, MaryLynn; Herrington, Chris; Sample, Thomas L.

2011-01-01

During 2008–10, the U.S. Geological Survey, in cooperation with the City of Austin, the City of Dripping Springs, the Barton Springs/Edwards Aquifer Conservation District, the Lower Colorado River Authority, Hays County, and Travis County, collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge well [YD–58–50–704] and Buda well [LR–58–58–403]), and the main orifice of Barton Springs in Austin, Texas, with the objective of characterizing concentrations and isotopic compositions of nitrate and concentrations of wastewater compounds in the Barton Springs zone. The Barton Springs zone is in south-central Texas, an area undergoing rapid growth in population and in land area affected by development, with associated increases in wastewater generation. Over a period of 17 months, during which the hydrologic conditions transitioned from dry to wet, samples were collected routinely from the streams, wells, and spring and, in response to storms, from the streams and spring; some or all samples were analyzed for nitrate, nitrogen and oxygen isotopes of nitrate, and waste­water compounds. The median nitrate concentrations in routine samples from all sites were higher in samples collected during the wet period than in samples collected during the dry period, with the greatest difference for stream samples (0.05 milligram per liter during the dry period to 0.96 milligram per liter for the wet period). Nitrate concentrations in recent (2008–10) samples were elevated relative to concentrations in historical (1990–2008) samples from streams and from Barton Springs under medium- and high-flow conditions. Recent nitrate concentrations were higher than historical concentrations at the Marbridge well but the reverse was true at the Buda well. The elevated concentrations likely are related to the cessation of dry conditions coupled with increased nitrogen loading in the contributing watersheds. An isotopic composition of nitrate (delta nitrogen–15) greater than 8 per mil in many of the samples indicated there was a contribution of nitrate with a biogenic (human and or animal waste, or both) origin. Wastewater compounds measured in routine samples were detected infrequently (3 percent of cases), and concentrations were very low (less than the method reporting level in most cases). There was no correlation between nitrate concentrations and the frequency of detection of wastewater compounds, indicating that wastewater compounds might be undergoing removal during such processes as infiltration through soil. Three potential sources of biogenic nitrate to the contributing zone were considered: septic systems, land application of treated wastewater, and domesticated dogs and cats. During 2001–10, the estimated densities of septic systems and domesticated dogs and cats (number per acre) increased in the watersheds of all five creeks, and the rate of land application of treated wastewater (gallons per day per acre) increased in the watersheds of Barton, Bear, and Onion Creeks. Considering the timing and location of the increases in the three sources, septic systems were considered a likely source of increased nitrate to Bear Creek; land application of treated wastewater a likely source to Barton, Bear, and Onion Creeks; and domestic dogs and cats a potential source principally to Williamson Creek. The results of this investigation indicate that baseline water quality, in terms of nitrate, has shifted upward between 2001 and 2010, even without any direct discharges of treated wastewater to the creeks.

Applying spatial analysis techniques to assess the suitability of multipurpose uses of spring water in the Jiaosi Hot Spring Region, Taiwan

NASA Astrophysics Data System (ADS)

Jang, Cheng-Shin

2016-04-01

The Jiaosi Hot Spring Region is located in northeastern Taiwan and is rich in geothermal springs. The geothermal development of the Jiaosi Hot Spring Region dates back to the 18th century and currently, the spring water is processed for various uses, including irrigation, aquaculture, swimming, bathing, foot spas, and recreational tourism. Because of the proximity of the Jiaosi Hot Spring Region to the metropolitan area of Taipei City, the hot spring resources in this region attract millions of tourists annually. Recently, the Taiwan government is paying more attention to surveying the spring water temperatures in the Jiaosi Hot Spring Region because of the severe spring water overexploitation, causing a significant decline in spring water temperatures. Furthermore, the temperature of spring water is a reliable indicator for exploring the occurrence and evolution of springs and strongly affects hydrochemical reactions, components, and magnitudes. The multipurpose uses of spring water can be dictated by the temperature of the water. Therefore, accurately estimating the temperature distribution of the spring water is critical in the Jiaosi Hot Spring Region to facilitate the sustainable development and management of the multipurpose uses of the hot spring resources. To evaluate the suitability of spring water for these various uses, this study spatially characterized the spring water temperatures of the Jiaosi Hot Spring Region by using ordinary kriging (OK), sequential Gaussian simulation (SGS), and geographical information system (GIS). First, variogram analyses were used to determine the spatial variability of spring water temperatures. Next, OK and SGS were adopted to model the spatial distributions and uncertainty of the spring water temperatures. Finally, the land use (i.e., agriculture, dwelling, public land, and recreation) was determined and combined with the estimated distributions of the spring water temperatures using GIS. A suitable development strategy for the multipurpose uses of spring water is proposed according to the integration of the land use and spring water temperatures. The study results indicate that OK, SGS, and GIS are capable of characterizing spring water temperatures and the suitability of multipurpose uses of spring water. SGS realizations are more robust than OK estimates for characterizing spring water temperatures. Furthermore, current land use is almost ideal in the Jiaosi Hot Spring Region according to the estimated spatial pattern of spring water temperatures. Keywords: Hot spring; Temperature; Land use; Ordinary kriging; Sequential Gaussian simulation; Geographical information system

Water-resources investigations in Dinosaur National Monument, Utah-Colorado, fiscal year 1970

USGS Publications Warehouse

Sumsion, C.T.

1971-01-01

Water-resources data were acquired during fiscal year 1970 by the U.S. Geological Survey at Dinosaur National Monument, Utah-Colorado, for the U.S. National Park Service as part of a continuing project. The data provide a basis for planning the development, management, and use of the available water resources to provide adequate water supplies. Thirty-one springs, 19 in relatively inaccessible areas, were evaluated as sources of water supplies. Seven potential well sites were evaluated for drilling depths in specific aquifers. A well drilled in Echo Park near the confluence of the Green and Yampa Rivers was tested. The pumping test showed the well to yield 130 gallons per minute with a drawdown of 1.96 feet; specific capacity of the well at 130 gallons per minute is 66 gallons per minute per foot. Water samples for chemical analysis were - collected from nine springs and one well; all except that from Disappointment Spring, were of good chemical quality.

Hydrogeology of the Mammoth Spring groundwater basin and vicinity, Markagunt Plateau, Garfield, Iron, and Kane Counties, Utah

USGS Publications Warehouse

Spangler, Lawrence E.

2012-01-01

The Markagunt Plateau, in southwestern Utah, lies at an altitude of about 9,500 feet, largely within Dixie National Forest. The plateau is capped primarily by Tertiary- and Quaternary-age volcanic rocks that overlie Paleocene- to Eocene-age limestone of the Claron Formation, which forms escarpments on the west and south sides of the plateau. In the southwestern part of the plateau, an extensive area of sinkholes has formed that resulted primarily from dissolution of the underlying limestone and subsequent subsidence and (or) collapse of the basalt, producing sinkholes as large as 1,000 feet across and 100 feet deep. Karst development in the Claron Formation likely has been enhanced by high infiltration rates through the basalt. Numerous large springs discharge from the volcanic rocks and underlying limestone on the Markagunt Plateau, including Mammoth Spring, one of the largest in Utah, with discharge that ranges from less than 5 to more than 300 cubic feet per second (ft3/s). In 2007, daily mean peak discharge of Mammoth Spring was bimodal, reaching 54 and 56 ft3/s, while daily mean peak discharge of the spring in 2008 and in 2009 was 199 ft3/s and 224 ft3/s, respectively. In both years, the rise from baseflow, about 6 ft3/s, to peak flow occurred over a 4- to 5-week period. Discharge from Mammoth Spring accounted for about 54 percent of the total peak streamflow in Mammoth Creek in 2007 and 2008, and about 46 percent in 2009, and accounted for most of the total streamflow during the remainder of the year. Results of major-ion analyses for water samples collected from Mammoth and other springs on the plateau during 2006 to 2009 indicated calcium-bicarbonate type water, which contained dissolved-solids concentrations that ranged from 91 to 229 milligrams per liter. Concentrations of major ions, trace elements, and nutrients did not exceed primary or secondary drinking-water standards; however, total and fecal coliform bacteria were present in water from Mammoth and other springs. Temperature and specific conductance of water from Mammoth and other springs showed substantial variance and generally were inversely related to changes in discharge during snowmelt runoff and rainfall events. Over the 3-year study period, daily mean temperature and specific conductance of water from Mammoth Spring ranged from 3.4 degrees Celsius (°C) and 112 microsiemens per centimeter (μS/cm) during peak flow from snowmelt runoff to 5.3°C and 203 μS/cm during baseflow conditions. Increases in specific conductance of the spring water prior to an increase in discharge in 2008–09 were likely the result of drainage of increasingly older water from storage. Variations in these parameters in water from two rise pools upstream from Mammoth Spring were the largest observed in relation to discharge and indicate a likely hydraulic connection to Mammoth Creek. Variations in water quality, discharge, and turbidity indicate a high potential for transport of contaminants from surface sources to Mammoth and other large springs in a matter of days. Results of dye-tracer tests indicated that recharge to Mammoth Spring largely originates from southwest of the spring and outside of the watershed for Mammoth Creek, particularly along the drainages of Midway and Long Valley Creeks, and in the Red Desert, Horse Pasture, and Hancock Peak areas, where karst development is greatest. A significant component of recharge to the spring takes place by both focused and diffuse infiltration through the basalt and into the underlying Claron limestone. Losing reaches along Mammoth Creek are also a source of rapid recharge to the spring. Maximum groundwater travel time to the spring during the snowmelt runoff period was about 7 days from sinking streams as far as 9 miles away and 1,900 feet higher, indicating a velocity of more than a mile per day. Response of the spring to rainfall events in the recharge area, however, indicated potential lag times of only about 1 to 2 days. Samples collected from Mammoth Spring during baseflow conditions and analyzed for tritium and sulfur-35 showed that groundwater in storage is relatively young, with apparent ages ranging from less than 1 year to possibly a few tens of years. Ratios of oxygen-18 and deuterium also showed that water from the spring represents a mixture of waters from different sources and altitudes. On the basis of evaluating results of dye-tracer tests and relations to adjacent basins, the recharge area for Mammoth Spring probably includes about 40 square miles within the Mammoth Creek watershed as well as at least 25 square miles outside and to the south of the watershed. Additional dye-tracer tests are needed to better define boundaries between the groundwater basins for Mammoth Spring and Duck Creek, Cascade, and Asay Springs.

Groundwater flow cycling between a submarine spring and an inland fresh water spring.

PubMed

Davis, J Hal; Verdi, Richard

2014-01-01

Spring Creek Springs and Wakulla Springs are large first magnitude springs that derive water from the Upper Floridan Aquifer. The submarine Spring Creek Springs are located in a marine estuary and Wakulla Springs are located 18 km inland. Wakulla Springs has had a consistent increase in flow from the 1930s to the present. This increase is probably due to the rising sea level, which puts additional pressure head on the submarine Spring Creek Springs, reducing its fresh water flow and increasing flows in Wakulla Springs. To improve understanding of the complex relations between these springs, flow and salinity data were collected from June 25, 2007 to June 30, 2010. The flow in Spring Creek Springs was most sensitive to rainfall and salt water intrusion, and the flow in Wakulla Springs was most sensitive to rainfall and the flow in Spring Creek Springs. Flows from the springs were found to be connected, and composed of three repeating phases in a karst spring flow cycle: Phase 1 occurred during low rainfall periods and was characterized by salt water backflow into the Spring Creek Springs caves. The higher density salt water blocked fresh water flow and resulted in a higher equivalent fresh water head in Spring Creek Springs than in Wakulla Springs. The blocked fresh water was diverted to Wakulla Springs, approximately doubling its flow. Phase 2 occurred when heavy rainfall resulted in temporarily high creek flows to nearby sinkholes that purged the salt water from the Spring Creek Springs caves. Phase 3 occurred after streams returned to base flow. The Spring Creek Springs caves retained a lower equivalent fresh water head than Wakulla Springs, causing them to flow large amounts of fresh water while Wakulla Springs flow was reduced by about half. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.

Modeling of dough mixing profile under thermal and non thermal constraint for evalution of breadmaking quality of Hard Spring Wheat flour

USDA-ARS?s Scientific Manuscript database

This research was initiated to investigate the association between flour breadmaking traits and mixing characteristics and empirical dough rheological property under thermal stress. Flour samples from 30 hard spring wheat were analyzed by a mixolab standard procedure at optimum water absorptions. Mi...

Results of weekly chemical and isotopic monitoring of selected springs in Norris Geyser Basin, Yellowstone National Park during June-September, 1995

USGS Publications Warehouse

Fournier, R.O.; Weltman, U.; Counce, D.; White, L.D.; Janik, C.J.

2002-01-01

Each year at Norris Geyser Basin, generally in August or September, a widespread hydrothermal 'disturbance' occurs that is characterized by simultaneous changes in the discharge characteristics of many springs, particularly in the Back Basin. During the summer season of 1995, water samples from eight widely distributed hot springs and geysers at Norris were collected each week and analyzed to determine whether chemical and isotopic changes also occurred in the thermal waters at the time of the disturbance. In addition, Beryl Spring in Gibbon Canyon, 5.8 km southwest of Norris Geyser Basin, was included in the monitoring program. Waters discharged by four of the monitored hot springs and geysers appear to issue from relatively deep reservoirs where temperatures are at least 270 C and possibly higher than 300 C. At the time of, and for several days after, the onset of the 1995 disturbance, the normally neutral-chloride waters discharged by these four features all picked up an acid-sulfate component and became isotopically heavier. The acid-sulfate component appears to be similar in composition to some waters discharged in 100 Spring Plain that issue from subsurface regions where temperatures are in the range 170-210 C. However, the two monitored springs that discharge acid-chloride-sulfate waters in the 100 Spring Plain region did not show any significant chemical or isotopic response to the annual disturbance. Beryl Spring, and two neutral-chloride hot springs at Norris that appear to draw their water from reservoirs where temperatures are 250 C or less, also did not show any significant chemical or isotopic response to the annual disturbance. After the start of the annual disturbance, chloride concentrations in water sampled from Double Bulger Geyser in the Back Basin increased from about 800 ppm to about 1500 ppm, nearly twice as high as any previously reported chloride concentration in a thermal water at Yellowstone. The isotopic composition of that water precludes an origin of the high chloride by evaporation at atmospheric pressure. One way to account for the unique chemical and isotopic composition of this highly concentrated wateris by recirculation of water that had gone through one cycle of adiabatic cooling during upflow (decompressional boiling) back down into the hydrothermal system, where it is reheated to greater than 220 C. This previously boiled water then undergoes additional cycles of decompressional boiling during subsequent upflow. Another way the unique chemical and isotopic composition of Double Bulger water might evolve is by excess boiling in the formation that results from a decrease in fluid pressure within the channels of upflow. The annual disturbance at Norris Geyser Basin generally appears to be triggered by a cyclic up and down movement of the boilingpoint curve within the hydrothermal system in response to changes in the potentiometric surface of the cold water that is adjacent to, and interconnected with, that hydrothermal system. Annual disturbance phenomena that are easily recognized at Norris Geyser Basin may not be easily recognized elsewhere in Yellowstone National Park because (1) the neutral-chloride waters at Norris ascend directly from higher-temperature and higherpressure reservoirs (270 to >300 C at Norris compared to 180-215C at Upper and Lower Geyser Basins) that are capable of producing massive amounts of high-pressure steam, and (2) the clay that makes hot spring and geyser waters become turbid at Norris, heralding the start of the disturbance, comes from acid altered rocks that are widely distributed at intermediate depths at Norris, and that are rare in other geyser basins.

Identification of 18S ribosomal DNA genotype of Acanthamoeba from hot spring recreation areas in the central range, Taiwan

NASA Astrophysics Data System (ADS)

Hsu, Bing-Mu; Ma, Po-Hua; Liou, Tai-Sheng; Chen, Jung-Sheng; Shih, Feng-Cheng

2009-04-01

SummaryAcanthamoeba is a free-living amoebae ubiquitous to aquatic environments. Within the genus a few species are recognized as opportunistic potential human pathogens, which cause granulomatous amoebic encephalitis (GAE) and keratitis. Infections of keratitis are frequently reported through wearing lens while swimming in the non-disinfected aquatic environment. Contaminations in hot tubs, spas and public baths are also possible. As a result, in this study, we identified Acanthamoeba based on the PCR amplification with a genus-specific primer pair and investigated the distribution of Acanthamoeba at five hot spring recreation areas in central range, Taiwan. We gathered data on factors potentially associated with the pathogen's distribution, including various sampling sites, aquatic environment, physical and microbiological water quality parameters. Spring water was collected from 55 sites and Acanthamoeba was detected in 9 (16.4%). The most frequently detected was Acanthamoeba griffini, followed by Acanthamoeba jacobsi. Legionella were detected in 18 (32.7%) of the sites sampled in this study. The species of Legionella identified included Legionella pneumophila serotype 6, serotype 1, and Legionella erythra. Overall, 9.1% of the samples contained both Acanthamoeba and Legionella. The prevalence of Acanthamoeba was contrary to the levels of microbiological indicators recommended by Taiwan CDC, and no significant differences (Mann-Whitney U test, P < 0.05) were observed between the presence/absence of Acanthamoeba and water quality parameters. Results of this survey confirm the existence of Acanthamoeba in Taiwan spring recreation areas. Acanthamoeba, the organism responsible for the majority of Acanthamoeba keratitis and can serve as vehicles for facultative pathogens, should be considered a potential threat for health associated with human activities in spring recreation areas of Taiwan.

Exploring the potential of DOC fluorescence as proxy for groundwater contamination by pesticides

NASA Astrophysics Data System (ADS)

Farlin, Julien; Gallé, Tom; Bayerle, Michael; Pittois, Denis; Huck, viola

2017-04-01

Of the different water quality surrogates the fluorescence of dissolved organic content (FDOC) appears particularly promising due to its sensitivity and specificity. A complete spectrum of FDOC can be obtained using bench top instruments scanning a spectral space going from short wavelength UV to visible blue, yielding a so-called an excitation-emission matrix (EEM). The raw EEM can be either used directly for correlation analysis with the variable of interest, or first decomposed into underlying elements corresponding to different groups of organic compounds displaying similar properties using multiway techniques such as Parallel factor analysis (PARAFAC). Fluorescence spectroscopy has up to now only rarely been applied specifically to groundwater environments. The objective of the project was to explore systematically the possibilities offered by FDOC and PARAFAC for the assessment of groundwater contamination by pesticides, taking into account the transit time from the pesticide source to the groundwater outlet. Three sites corresponding to different transit times were sampled: -one spring regularly contaminated by surface water from a nearby stream (sub-daily to daily response to fast-flow generating storm events) -one spring displaying a weekly to monthly response to interflow -sampling along a flowline consisting of a series of springs and an observation well situated upgradient with mean transit times difference of several years Preliminary results show that a three component PARAFAC model is sufficient to decompose the raw EEMs, which is less than the seven or eight component models often encountered in surface water studies. For the first site, one component in the protein-like region 275(excitation)/310 (emission) nm measured in the stream samples was filtrered completely by the aquifer and did not appear in the spring samples. The other two components followed roughly the trend of the DOC and pesticide breakthrough. For the second site, soil sampling of the agricultural plots and DOC extraction also allowed to characterise the spectral signature of the pollution source. A humic-like component (250/450 nm) was correlated with the breakthrough of recent soil water and pesticide concentration. Lastly, the fluorescence intensity of the different components for the third sampling site showed a decrease proportional to the decrease in DOC concentration between the observation well and the springs caused either by dilution, degradation or both. This lack of change in the spectral pattern along a flow line seems to indicate that labile soil DOC fractions have already been degraded by the time water reaches the observation well.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Broxton, D.E.

A total of 338 water and 1877 sediment samples were collected over a 20,700-km/sup 2/ area from 2125 locations at a nominal density of one sample per 10 km/sup 2/. Water samples were collected from wells, streams, springs, and artificial ponds. Sediment samples were collected from streams, springs, natural ponds, and artificial ponds. Arbitrary anomaly thresholds of two standard deviations above the mean were chosen for both water and sediment sample populations. The U concentrations in waters collected in the Tularosa quadrangle range from below the detection limit of 0.2 parts per billion (ppB) to 57.8 ppB. Most clusters ofmore » water samples containing anomalously high uranium concentrations were collected from locations in uplifts underlain either by volcanic rocks of the mid-Tertiary Datil group or by sedimentary rocks of late Paleozoic and Mesozoic age. Other groups of anomalous waters are from wells that tap Cenozoic aquifers in the intermontane basins. In those areas where the water-sample location coverage is adequate, the known U occurrences are generally associated with high or anomalous U concentrations in water samples. With the exception of one sample with a U concentration of 67.7 ppM, sediments collected in this study have U concentrations that range between 0.2 and 15.2 ppM. Most sediments with U concentrations above the arbitrary anomaly threshold value are from locations which occur in or parallel outcrops of Precambrian crystalline rock exposed in the San Andres and Oscura Mountains. Other anomalous sediments occur as more discreet groups in areas underlain by mid-Tertiary volcanic rocks of the Datil group. Several anomalous samples from the Mogollon-Datil volcanic field were collected along ring fracture systems that surround large volcanic cauldrons.« less

Can Sanitary Surveys Replace Water Quality Testing? Evidence from Kisii, Kenya

PubMed Central

Misati, Aaron Gichaba; Ogendi, George; Peletz, Rachel; Khush, Ranjiv; Kumpel, Emily

2017-01-01

Information about the quality of rural drinking water sources can be used to manage their safety and mitigate risks to health. Sanitary surveys, which are observational checklists to assess hazards present at water sources, are simpler to conduct than microbial tests. We assessed whether sanitary survey results were associated with measured indicator bacteria levels in rural drinking water sources in Kisii Central, Kenya. Overall, thermotolerant coliform (TTC) levels were high: all of the samples from the 20 tested dug wells, almost all (95%) of the samples from the 25 tested springs, and 61% of the samples from the 16 tested rainwater harvesting systems were contaminated with TTC. There were no significant associations between TTC levels and overall sanitary survey scores or their individual components. Contamination by TTC was associated with source type (dug wells and springs were more contaminated than rainwater systems). While sanitary surveys cannot be substituted for microbial water quality results in this context, they could be used to identify potential hazards and contribute to a comprehensive risk management approach. PMID:28178226

Recharge area of the Umbulan spring on the basis of the geology, hydrochemistry and isotopic approach, a high discharge spring of the Bromo-Tengger volcano, East Java

NASA Astrophysics Data System (ADS)

Jourde, H.; Toulier, A.; Baud, B.; De Montety, V.; Leonardi, V.; Pistre, S.; Hendrayana, H.

2017-12-01

Hydrogeochemical analysis and geological mapping, together with water Isotopes analysis, were performed to identify the recharge area of Umbulan spring, a high discharge spring located in the Bromo-Tengger volcano. The volcanic edifice, situated in a tropical climatic context, is the origin of exceptionally high discharge springs in such a volcanic context. This is the case of Umbulan spring whose discharge is about 3500 l/s that supply drinking water to the city of Surabaya, the second biggest city of Indonesia. Groundwater flows through fractured/weathered andesitic lava flow and pyroclastic deposits. The main groundwater outlet corresponds to gravity springs on the flanks of the volcano and to artesian springs in the plain. To improve the hydrogeological knowledge of the study area, the geological mapping of the North volcano flank has been performed to identify the aquiferous formations and refine the geological limits defined in the literature. Based on this geological survey, a new geological map was proposed. Water samples of gravity springs, artesian springs and deep wells were collected with elevations ranging from 40 to 2700 m above sea level, for water major ions elements and stable isotope (δ18O, δD). The meteoric local gradient of δ18O is assessed from the water isotope contents of springs, which are considered as "local pluviometer" representative of the precipitation isotope content at a given elevation corresponding to the mean elevation of their recharge catchment. Based on the analysis of the meteoric local gradient of δ18O, the mean elevation of Umbulan spring recharge catchment ranges between 700 to 1300 m a.s.l, which in agreement with geological observations. Many interrogations subsist but these first hydrogeological data collected in the field allowed to propose a first conceptual model of the Bromo-Tengger volcano, which will help improving the hydrogeological knowledge of the study area and thus preserve and manage the groundwater resource of Bromo-Tengger volcano.

Water-quality, discharge, and biologic data for streams and springs in the Highland Rim Escarpment of southeastern Bedford County, Tennessee

USGS Publications Warehouse

Hollyday, E.F.; Byl, T.D.

1995-01-01

From November 1994 through April 1995, streams and springs in 9 drainage basins were observed and sampled at 176 sites to obtain information on environmental quality near the Quail Hollow landfill, Bedford County, Tennessee. Reconnaissance data were collected to establish a regional pattern. Water samples from 26 seepage sites were analyzed to determine water-quality conditions. During the reconnaissance, conductivity ranged regionally from 17 to 617 microsiemens per centimeter. The greatest biologic diversity was in Bennett Branch, followed by Daniel Hollow, Prince, Powell and Renegar, County Line, and Anthony Branches, Hurricane Creek, and Anderton Branch, respectively. In general, conductivity was less than 50 microsiemens per centimeter at and upstream of the Chattanooga Shale but increased downstream to between 200 and 300 microsiemens per centimeter. Of the constituents and properties analyzed, only pH and four metals at six sites had values that were not within the limits set by the State of Tennessee for drinking water. Chloride and dissolved manganese concentrations were highest for a spring and a seep adjacent to the landfill. Scans indicated the presence of about 37 unidentified organic compounds at these same two sites.

Applying spatial analysis techniques to assess the suitability of multipurpose uses of spring water in the Jiaosi Hot Spring Region, Taiwan.

PubMed

Jang, Cheng-Shin; Huang, Han-Chen

2017-07-01

The Jiaosi Hot Spring Region is one of the most famous tourism destinations in Taiwan. The spring water is processed for various uses, including irrigation, aquaculture, swimming, bathing, foot spas, and recreational tourism. Moreover, the multipurpose uses of spring water can be dictated by the temperature of the water. To evaluate the suitability of spring water for these various uses, this study spatially characterized the spring water temperatures of the Jiaosi Hot Spring Region by integrating ordinary kriging (OK), sequential Gaussian simulation (SGS), and Geographic information system (GIS). First, variogram analyses were used to determine the spatial variability of spring water temperatures. Next, OK and SGS were adopted to model the spatial uncertainty and distributions of the spring water temperatures. Finally, the land use (i.e., agriculture, dwelling, public land, and recreation) was determined using GIS and combined with the estimated distributions of the spring water temperatures. A suitable development strategy for the multipurpose uses of spring water is proposed according to the integration of the land use and spring water temperatures. The study results indicate that the integration of OK, SGS, and GIS is capable of characterizing spring water temperatures and the suitability of multipurpose uses of spring water. SGS realizations are more robust than OK estimates for characterizing spring water temperatures compared to observed data. Furthermore, current land use is almost ideal in the Jiaosi Hot Spring Region according to the estimated spatial pattern of spring water temperatures.

Causes of toxicity to Hyalella azteca in a stormwater management facility receiving highway runoff and snowmelt. Part II: salts, nutrients, and water quality.

PubMed

Bartlett, A J; Rochfort, Q; Brown, L R; Marsalek, J

2012-01-01

The Terraview-Willowfield Stormwater Management Facility (TWSMF) features a tandem of stormwater management ponds, which receive inputs of multiple contaminants from highway and residential runoff. Previous research determined that benthic communities in the ponds were impacted by poor habitat quality, due to elevated sediment concentrations of metals and polycyclic aromatic hydrocarbons (PAHS), and salinity in the overlying water, but did not address seasonal changes, including those caused by the influx of contaminants with the snowmelt. In order to address this issue, water and sediment samples were collected from the TWSMF during the fall and spring, and four-week sediment toxicity tests were conducted with Hyalella azteca. The effects of metals and PAHs are discussed in a companion paper; the effects of road salt, nutrients, and water quality are discussed here. After exposure to fall samples, survival of Hyalella was reduced (64-74% of controls) at three out of four sites, but growth was not negatively affected. After exposure to spring samples, survival was 0-75% of controls at the two sites furthest downstream, and growth was significantly lower in four out of five sites when comparing Hyalella exposed to site water overlying site sediment versus control water overlying site sediment. Toxicity appeared to be related to chloride concentrations: little or no toxicity occurred in fall samples (200 mg Cl(-)/L), and significant effects on survival and growth occurred in spring samples above 1550 mg Cl(-)/L and 380 mg Cl(-)/L, respectively. Sodium chloride toxicity tests showed similar results: four-week LC50s and EC25s (growth) were 1200 and 420 mg Cl(-)/L, respectively. Although water quality and nutrients were associated with effects observed in the TWSMF, chloride from road salt was the primary cause of toxicity in this study. Chloride persists during much of the year at concentrations representing a significant threat to benthic communities in the TWSMF. Copyright © 2011. Published by Elsevier B.V.

Hydrologic connections and dynamics of water movement in the classical Karst (Kras) Aquifer: evidence from frequent chemical and stable isotope sampling

USGS Publications Warehouse

Doctor, Daniel H.

2008-01-01

A review of past research on the hydrogeology of the Classical Karst (Kras) region and new information obtained from a two- year study using environmental tracers are presented in this paper. The main problems addressed are 1) the sources of water to the Kras aquifer resurgence zone-including the famous Timavo springs-under changing flow regimes; 2) a quantification of the storage volumes of the karst massif corresponding to flow regimes defined by hydrograph recessions of the Timavo springs; and 3) changing dynamics between deep phreatic conduit flow and shallow phreatic and epiphreatic storage within the aquifer resurgence zone as determined through changes in chemical and isotopic composition at springs and wells. Particular focus was placed on addressing the long-standing question of the influence of the Soca River on the ground waters of the aquifer resurgence zone. The results indicate that the alluvial aquifer supplied by the sinking of the Soca River on the northwestern edge of the massif contributes approximately 75% of the mean annual outflow to the smaller springs of the aquifer resurgence zone, and as much as 53% to the mean annual outflow of the Timavo springs. As a whole, the Soca River is estimated to contribute 56% of the average outflow of the Kras aquifer resurgence. The proportions of Soca River water increase under drier conditions, and decrease under wetter conditions. Time series analysis of oxygen stable isotope records indicate that the transit time of Soca River water to the Timavo springs, Sardos spring, and well B-4 is on the order of 1-2 months, depending on hydrological conditions. The total baseflow storage of the Timavo springs is estimated to be 518 million m3, and represents 88.5% of the storage capacity estimated for all flow regimes of the springs. The ratio of baseflow storage volume to the average annual volume discharged at the Timavo springs is 0.54. The Reka River sinking in Slovenia supplies substantial allogenic recharge to the aquifer; however, its influence on the northwest resurgence zone is limited to the Timavo springs, and is only a significant component of the spring discharge under flood conditions for relatively brief periods (several days to weeks). Sustainability of the trans-boundary aquifer of the Kras will benefit from maintaining high water quality in the Soca River, as well as focused water tracing experiments within the epiphreatic zone of the aquifer to better delineate the recharge zone and to identify sources of potential contamination to the Brestovica water supply well.

Historical patterns of acidification and increasing CO2 flux associated with Florida springs

USGS Publications Warehouse

Barrera, Kira E.; Robbins, Lisa L.

2017-01-01

Florida has one of the highest concentrations of springs in the world, with many discharging into rivers and predominantly into eastern Gulf of Mexico coast, and they likely influence the hydrochemistry of these adjacent waters; however, temporal and spatial trends have not been well studied. We present over 20 yr of hydrochemical, seasonally sampled data to identify temporal and spatial trends of pH, alkalinity, partial pressure of carbon dioxide (pCO2), and CO2flux from five first-order-magnitude (springs that discharge greater than 2.83 m3 s−1) coastal spring groups fed by the Floridan Aquifer System that ultimately discharge into the Gulf of Mexico. All spring groups had pCO2 levels (averages 3174.3–6773.2 μatm) that were much higher than atmospheric levels of CO2 and demonstrated statistically significant temporal decreases in pH and increases in CO2 flux, pCO2, and alkalinity. Total carbon flux emissions increased from each of the spring groups by between 3.48 × 107 and 2.856 × 108 kg C yr−1 over the time period. By 2013 the Springs Groups in total emitted more than 1.1739 × 109 kg C yr−1. Increases in alkalinity and pCO2 varied from 90.9 to 347.6 μmol kg−1 and 1262.3 to 2666.7 μatm, respectively. Coastal data show higher CO2 evasion than the open Gulf of Mexico, which suggests spring water influences nearshore waters. The results of this study have important implications for spring water quality, dissolution of the Florida carbonate platform, and identification of the effect and partitioning of carbon fluxes to and within coastal and marine ecosystems.

Field application of passive SBSE for the monitoring of pesticides in surface waters.

PubMed

Assoumani, A; Coquery, M; Liger, L; Mazzella, N; Margoum, C

2015-03-01

Spot sampling lacks representativeness for monitoring organic contaminants in most surface waters. Passive sampling has emerged as a cost-effective complementary sampling technique. We recently developed passive stir bar sorptive extraction (passive SBSE), with Twister from Gerstel, for monitoring moderately hydrophilic to hydrophobic pesticides (2.18 < log K ow < 5.11) in surface water. The aims of the present study were to assess this new passive sampler for the determination of representative average concentrations and to evaluate the contamination levels of two French rivers. Passive SBSE was evaluated for the monitoring of 16 pesticides in two rivers located in a small vineyard watershed during two 1-month field campaigns in spring 2010 and spring 2011. Passive SBSE was applied for periods of 1 or 2 weeks during the field campaigns and compared with spot sampling and weekly average automated sampling. The results showed that passive SBSE could achieve better time-representativeness than spot sampling and lower limits of quantification than automated sampling coupled with analytical SBSE for the pesticides studied. Finally, passive SBSE proved useful for revealing spatial and temporal variations in pesticide contamination of both rivers and the impact of rainfall and runoff on the river water quality.

Volcanic Gases and Hot Spring Water to Evaluate the Volcanic Activity of the Mt. Baekdusan

NASA Astrophysics Data System (ADS)

Yun, S. H.; Lee, S.; Chang, C.

2017-12-01

This study performed the analysis on the volcanic gases and hot spring waters from the Julong hot spring at Mt. Baekdu, also known as Changbaishan on the North Korea(DPRK)-China border, during the period from July 2015 to August 2016. Also, we confirmed the errors that HCO3- concentrations of hot spring waters in the previous study (Lee et al. 2014) and tried to improve the problem. Dissolved CO2 in hot spring waters was analyzed using gas chromatograph in Lee et al.(2014). Improving this, from 2015, we used TOC-IC to analysis dissolved CO2. Also, we analyzed the Na2CO3 standard solutions of different concentrations using GC, and confirmed the correlation between the analytical concentrations and the real concentrations. However, because the analytical results of the Julong hot spring water were in discord with the estimated values based on this correlation, we can't estimate the HCO3-concentrations of 2014 samples. During the period of study, CO2/CH4 ratios in volcanic gases are gradually decreased, and this can be interpreted in two different ways. The first interpretation is that the conditions inside the volcanic edifice are changing into more reduction condition, and carbon in volcanic gases become more favorable to distribute into CH4 or CO than CO2. The second interpretation is that the interaction between volcanic gases and water becomes greater than past, and the concentrations of CO2which have much higher solubility in water decreased, relatively. In general, the effect of scrubbing of volcanic gas is strengthened during the quiet periods of volcanic activity rather than active periods. Meanwhile, the analysis of hot spring waters was done on the anion of acidic gases species, the major cations, and some trace elements (As, Cd, Re).This work was funded by the Korea Meteorological Administration Research and Development Program under Grant KMIPA 2015-3060.

Intrusion Pattern of the Offshore Kuroshio Branch Current and Its Effects on Nutrient Contributions in the East China Sea

NASA Astrophysics Data System (ADS)

Wang, Wentao; Yu, Zhiming; Song, Xiuxian; Yuan, Yongquan; Wu, Zaixing; Zhou, Peng; Cao, Xihua

2018-03-01

During the autumn season of 2014 (October-November), nutrient samples and nitrogen and oxygen isotope samples from the East China Sea (ECS) were collected and analyzed, and auxiliary physical parameters were determined. Distinctive high-salinity water column conditions with significant haloclines and pycnoclines similar to those observed during the spring were detected at the bottom of the ECS during the autumn. These water column conditions were attributed to the intrusion of the Kuroshio Subsurface Water (KSSW), which then separated into two currents, including the Offshore Kuroshio Branch Current (OKBC). Compared with spring, this intrusion transported higher phosphorus (P) concentrations onto the ECS continental shelf in autumn. However, according to multiple analyses, biogeochemical nitrogen processes are unable to explain the variations in the P concentrations (increase) while assuming that each distinctive water column is consistent. Identifying the water columns by their salinities and P concentrations revealed that the northern ECS water column was similar to the deep KSSW while the southern ECS water column was similar to the shallow KSSW. Therefore, we speculate that the distinctions among the seasonal variations of P-enriched water masses were attributable to the different intrusion positions of the Kuroshio. The shift of the KSSW intrusion location moved toward the northeast during the autumn relative to the spring. This shift, which was proved by the oceanic vortex data, caused the deeper KSSW water upwelled to the ECS and formed the OKBC, thereby supplying additional P during the autumn.

Radon constrains the transit time of springs water at the border between tabular Middle Atlas and the Sais Basin (Morocco)

NASA Astrophysics Data System (ADS)

Mayer, Adriano; Rouai, Mohammed; Saracco, Ginette; Dekayir, Abdelilak; Miche, Héléne

2010-05-01

The tabular Middle Atlas (TMA) is an important fractured karstic reservoir in northern Morocco constituted by Liassic limestones and dolomites with a nearly sub-horizontal attitude, overlying basalts, shales and evaporates of Triassic age, as well as Paleozoic anchi-metamorphic schists. The zone is characterised by relative abundant rainfall (700 mm/y) and the absence of a surface watershed, which lead to an important groundwater reservoir hosted in the karstic (k-) aquifer. TMA is bordered to the North by extensive graben-like, normal, northward, fault-systems, which burden the Karstic formations under Plio-quaternary sediments at the Sais Basin border. At this limit, several important springs of high water-quality occur at the northernmost outcropping Lias limestone, which is overlaid in some areas by quaternary travertines. Two of these springs in particular, Bittit and Ribaa springs, provide almost drinking water for the town of Meknes (0.7 Million inhabitants), for local population and agriculture. These springs experienced a significant drop in water flow-rate in the last decades. Although the main origin of this water is certainly the k-aquifer, the drop in water-table raises several questions regarding the modality of water transport (influence of fractured and karstic systems in particular) and the possible participations of other groundwater reservoirs, which may deteriorate the high water-quality. A recent study has been carried out to shed some light on these questions, by using geochemical methods (K, Mg, Na, Ca, Fe, Mn, Ba, Sr, As, Sb, Hg, HCO3, SO4, NO3, Cl, Br, delta18-O, deltaD, Rn, EC, O2, pH, Eh, Temp). Constraints on the groundwater flow-path have been obtained by using a radon- hydrochemical- isotopic characterisation of spring waters. Here we report the results of the first geochemical sample collection (November 09). Several springs in the TMA yield Mg-Ca HCO3 rich water equilibrated with limestone and dolomite, having a very similar Rn activity of 3000 Bq/m3, unrelated to spring altitude. Similar radon activity is also found in a deep well in the Lias-confined aquifer of the Sais Basin and is hence considered to be the steady state activity in k-aquifer. Other springs situated at lower altitude yield more mineralised water (EC = 1200 uS/cm), richer in Na, K, Cl and Rn (15000 Bq/m3). These waters partially interacted with a non-karstic aquifer, most probably the deeper underlying Paleozoic schists (p-aquifer), as suggested by hydro chemical similarity with a water sample collected from a well in these shists. Since such water springs-out of Liassic carbonates, the measured Rn activity probably differs from the equilibrium activity achieved in the underlying p-aquifer, depending on the transit time from p-aquifer and the radon half-life (3.8 days). Furthermore, three other springs have hydrochemical characteristics intermediate between p- and k-aquifers, suggesting that a binary mixing of these waters occurred, either in the k- or in the p- aquifer. In principle, if the groundwater mixing occurred in k-aquifer, unsupported Rn activity would be lower than the activity expected from the binary mixing because of the time elapsed since the mixing occurred. The data show on the contrary that the mixed water has Rn activity higher than the expected activity calculated from the mixing. This suggests that groundwater mixing occurred in the p-aquifer. The excess of radon relatively to the expected activity calculated after the mixing, is interpreted to result from Rn radioactive ingrowth during the residence time in the p-aquifer, followed by radon decay occurred during uplift from p-aquifer to the spring in the Liassic carbonates. With this simple model, the measured Rn excess constraints the total time elapsed since the beginning of interaction with the p-aquifer on a time scale of 2 weeks. Remote sensed imaging of the area evidences that these "mixed" springs lies on important tectonic alignments, which suggest that fractures system could play a role in the fast upwelling of groundwater.

Potential hydrothermal resource temperatures in the Eastern Snake River Plain, Idaho

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghanashayam Neupane; Earl D. Mattson; Cody J. Cannon

The Eastern Snake River Plain (ESRP) in southern Idaho is a region of high heat flow. Sustained volcanic activities in the wake of the passage of the Yellowstone Hotspot have turned this region into an area with great potential for geothermal resources as evidenced by numerous hot springs scattered along the margins of the plain and several hot-water producing wells and hot springs within the plain. Despite these thermal expressions, it is hypothesized that the pervasive presence of an overlying groundwater aquifer in the region effectively masks thermal signatures of deep-seated geothermal resources. The dilution of deeper thermal water andmore » re-equilibration at lower temperature are significant challenges for the evaluation of potential resource areas in the ESRP. Over the past several years, we collected approximately 100 water samples from springs/wells for chemical analysis as well as assembled existing water chemistry data from literature. We applied several geothermometric and geochemical modeling tools to these chemical compositions of ESRP water samples. Geothermometric calculations based on principles of multicomponent equilibrium geothermometry with inverse geochemical modeling capability (e.g., Reservoir Temperature Estimator, RTEst) have been useful for the evaluation of reservoir temperatures. RTEst geothermometric calculations of ESRP thermal water samples indicated numerous potential geothermal areas with elevated reservoir temperatures. Specifically, areas around southern/southwestern side of the Bennett Hills and within the Camas Prairies in the western-northwestern regions of the ESRP and its margins suggest temperatures in the range of 140-200°C. In the northeastern portions of the ESRP, Lidy Hot Springs, Ashton, Newdale, and areas east of Idaho Falls have expected reservoir temperature =140 °C. In the southern ERSP, areas near Buhl and Twin Falls are found to have elevated temperatures as high as 160 °C. These areas are likely to host potentially economic geothermal resources; however, further detailed study is warranted to each site to evaluate hydrothermal suitability for economic use.« less

Variation in glyphosate and AMPA concentrations of surface water and groundwater

NASA Astrophysics Data System (ADS)

Caprile, Ana Clara; Aparicio, Virginia; Sasal, Carolina; Andriulo, Enrique

2017-04-01

The presence of pesticides in various environmental matrices indicate that the soil's ability to function as a bio-physical-chemical reactor is declining. As it operates as an interface between air and water, it causes a negative impact on these two vital resources. Currently, the pampa agriculture is simplified with a marked tendency towards spring-summer crops, where the main crops are RR soybean and corn. Herbicides are neither retained nor degraded in the soil, which results in polluted groundwater and surface waters. The objectives of this study were: a) to verify the presence of glyphosate and aminomethylphosphonic acid (AMPA) in Pergamino stream (a typical representative of the most productive agricultural region of Argentina) under different land use and to detect if in the detections there was a space-time pattern, and b) to verify the detection of these molecules in groundwater of the upper same basin under exclusively rural land use. Surface stream was sampling in six sites (five under rural land use and one under urban-industrial land use) at a rate of one sample by spring, summer and winter seasons (2010-2013, 54 total samples). Groundwater glyphosate and AMPA concentrations were determined in 24 piezometers constructed at two positions of the landscape, across the groundwater flow direction, sampled at two sampling dates (2010 and 2012, 45 total samples). In surface water, glyphosate and AMPA were detected in 54 and 69% of the samples analyzed, respectively. The median concentrations were 0.9 and 0.8 µg L-1 for glyphosate and AMPA and maximal concentrations 258 and 5865 µg L-1, respectively. The sampling site under urban-industrial land use had abnormally high concentrations of glyphosate in the spring (attributed to point pollution), a fact that not allowed to see differences in the remaining sampling times under different land uses. AMPA concentrations under urban-industrial land use were high and higher than rural land use in 3 studied seasons. Under rural land use, AMPA differences between seasons were found, being the highest concentration in spring (1.9 µg L-1). In groundwater glyphosate and AMPA concentrations were detected in 32 and 36% of the analyzed samples respectively. Medium and maximum glyphosate and AMPA concentrations were 0.7 and 1.0 µg L-1, and 2.3 and 6.0 µg L-1, respectively. In the first sampling date, glyphosate and AMPA were not detected probably associated with a dilution during a period of high groundwater recharge. On the contrary, in the second date the two molecules were detected in coincidence with a previous period with lowering water table accompanied by the first recharges. The temporal dynamics showed that herbicides are found in higher concentrations in surface water during the spring, and this is possibly associated with overlapping applications with rains that produce runoff. In groundwater, detections were associated with periods where the first small recharges are produced, which are concentrated in solutes. Loss of the environmental services retention and degradation of glyphosate of the agricultural soils was confirmed

Geochemical investigation of the hydrothermal system on Akutan Island, Alaska, July 2012

USGS Publications Warehouse

Bergfeld, D.; Lewicki, Jennifer L.; Evans, William C.; Hunt, Andrew G.; Revesz, Kinga; Huebner, Mark

2014-01-01

We have studied the geochemistry of the hot springs on Akutan Island in detail for the first time since the early 1980s. Springs in four discrete groups (A-D) along Hot Springs Creek showed generally higher temperatures and substantially higher Na, Ca, and Cl concentrations than previously reported, and total hot-spring discharge has also increased markedly. The springs now account for a heat output of ~29 MW, about an order of magnitude more than in 1981. Gas samples from the hot springs and from a fumarolic area on the flank of Akutan Volcano show high 3He/4He ratios (>6.4 RA) after correction for air contamination and reveal a common magmatic heat source. Hot-spring gases are unusually rich in N2, Ar, and CH4, suggesting that the water has boiled and lost CO2 during upflow beneath the flank fumarole field. Gas geothermometry calculations applied to the flank fumarole field implies temperatures of 200–240 °C for the reservoir, and Na-K-Ca geothermometry implies temperatures near 180 °C for the outflow waters that feed the hot springs. The results of our study confirm the existence of a substantial geothermal resource on the island.

Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators

USGS Publications Warehouse

Panno, S.V.; Hackley, Keith C.; Hwang, H.-H.; Kelly, W.R.

2001-01-01

The sources of nitrate (NO-3) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO-3 concentrations in excess of the USEPA's drinking water standard of 10 mg N/1. Relative to background levels, the NO-3 concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter have contributed additional NO-3 to groundwater in the shallow karst aquifer. This information, and the dominance of agriculture in the study area, suggest that agrichemical contributions may be significant. To test this hypothesis, water samples from 10 relatively large karst springs were collected during four different seasons and analyzed for inorganic constituents, dissolved organic carbon, atrazine, and ??15N and ??18O of the NO-3 ions. The isotopic data were most definitive and suggested that the sources of NO-3 in spring water are dominated by N-fertilizer with some possible influence of atmospheric NO-3 and, to a much lesser extent, human and/or animal waste. Differences in the isotopic composition of NO-3 and some of the chemical characteristics were observed during the four consecutive seasons in which spring water samples were collected. Isotopic values for ??15N and ??18O of the NO-3 ranged from 3.2??? to 19.1??? and from 7.2??? to 18.7???, respectively. The trend of ??15N and ??18O data for NO-3 also indicated that a significant degree of denitrification is occurring in the shallow karst hydrologic system (within the soil zone, the epikarst and the shallow karst aquifer) prior to discharging to springs. ?? 2001 Elsevier Science B.V. All rights reserved.

Water-Chemistry and On-Site Sulfur-Speciation Data for Selected Springs in Yellowstone National Park, Wyoming, 1996-1998

USGS Publications Warehouse

Ball, James W.; Nordstrom, D. Kirk; McCleskey, R. Blaine; Schoonen, Martin A.A.; Xu, Yong

2001-01-01

Fifty-eight water analyses are reported for samples collected from 19 hot springs and their overflow drainages and one ambient-temperature acid stream in Yellowstone National Park (YNP) during 1996-98. These water samples were collected and analyzed as part of research investigations on microbially mediated sulfur oxidation in stream waters and sulfur redox speciation in hot springs in YNP and chemical changes in overflow drainages that affect major ions, redox species, and trace elements. The research on sulfur redox speciation in hot springs is a collaboration with the State University of New York at Stony Brook, Northern Arizona University, and the U.S. Geological Survey (USGS). One ambient-temperature acidic stream system, Alluvium Creek and its tributaries in Brimstone Basin, was studied in detail. Analyses were performed adjacent to the sampling site, in an on-site mobile laboratory truck, or later in a USGS laboratory, depending on stability and preservability of the constituent. Water temperature, specific conductance, pH, Eh, dissolved oxygen (D.O.), and dissolved H2S were determined on-site at the time of sampling. Alkalinity and F were determined within a few days of sample collection by titration and by ion-selective electrode, respectively. Concentrations of S2O3 and SxO6 were determined as soon as possible (minutes to hours later) by ion chromatography (IC). Concentrations of Cl, SO4, and Br were determined by IC within a few days of sample collection. Concentrations of Fe(II) and Fe(total) were determined by ultraviolet/visible spectrophotometry within a few days of sample collection. Densities were determined later in the USGS laboratory. Concentrations of Li, Na, and K were determined by flame atomic absorption (Li) and emission (Na, K) spectrometry. Concentrations of Al, As(total), B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe(total), Mg, Mn, Ni, Pb, Si, Sr, V, and Zn were determined by inductively-coupled plasma optical emission spectrometry. Trace concentrations of Cd, Se, As(total), Ni, and Pb were determined by Zeeman-corrected graphite-furnace atomic-absorption spectrometry. Trace concentrations of As(total) and As(III) were determined by hydride generation using a flow-injection analysis system.

Characterization of ground-water flow and water quality for the Madison and Minnelusa aquifers in northern Lawrence County, South Dakota

USGS Publications Warehouse

Putnam, Larry D.; Long, Andrew J.

2007-01-01

The Madison and Minnelusa aquifers are used extensively for water supplies for the city of Spearfish and other users in northern Lawrence County, South Dakota. Ground water in the Madison and Minnelusa aquifers in the study area generally flows north from outcrop areas where recharge from sinking streams and infiltration of precipitation occurs. Ground water that moves northward and eastward around the Black Hills enters the study area from the west and results in hydraulic heads that are several hundred feet higher on the western side of the study area than on the eastern side. The estimated average recharge rate of 38 cubic feet per second (ft3/s) on outcrops of the Madison Limestone and Minnelusa Formation is less than the total estimated average spring discharge rate of 51 ft3/s in the northwestern part of the study area. Sixteen pounds of fluorescein dye were injected into Spearfish Creek on March 25, 2003, when streamflow was 6.6 ft3/s. The dye was detected in water samples from four wells completed in the Madison aquifer ranging from 2.6 to 4.5 miles north of the injection site. First arrival times ranged from 5 to 169 days, and ground-water velocities ranged from about 0.1 to 0.5 mile per day. Sixty-four pounds of Rhodamine WT was injected into Spearfish Creek at the same location on May 9, 2003, when streamflow was 5.6 ft3/s. Rhodamine WT dye concentrations measured in samples from the same four wells were about an order of magnitude less than measured fluorescein concentrations. Oxygen- and deuterium-isotope values for samples from Cox Lake and McNenny Pond springs indicated a probable component of spring discharge that originates from outcrops of the Madison Limestone and Minnelusa Formation on the Limestone Plateau south of the study area. Oxygen- and deuterium-isotope values for samples from Mirror Lake spring indicated possible contributions from overlying aquifers and local recharge. Oxygen- and deuterium-isotope values for the combined springflow contributing to Crow Creek in the northwestern part of the study area indicated that the primary source of water is the Madison and Minnelusa aquifers. Oxygen- and deuterium-isotope values for Old Hatchery and Higgins Gulch springs, located north of Spearfish, indicated a source water originating from the outcrops of the Madison Limestone and Minnelusa Formation within the study area. Concentrations of three chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) were used to characterize ground-water residence times in the study area. For the four wells where dye was detected, CFC-11 apparent ages ranged from 12 to 26 years, indicating that the wells contained months-old water mixed with years- to decades-old water. Logarithmic regression analysis of the CFC-11 apparent ages for water from 10 wells and distance to a possible conduit trending north through the area where dye was detected, yielded an r2 value of 0.71. Straight-line regression analysis of the CFC-11 apparent ages for the six wells closest to the possible conduit had an r2 value of 0.96. Two wells located relatively close to the outcrop areas had no or very low tritium values indicating relatively long residence times and diffuse ground-water flow. The tritium value of 7.2 TU in water from well COL where dye was detected, indicated that the water probably is a bimodal mixture, with a substantial portion that is older than 50 years. Water from well ELL, where dye was detected, had a tritium value of 19.7 TU and a CFC apparent age of 15 years, indicating that the sample from this well probably is a unimodal mixture with very little water older than 50 years. Comparison of the CFC apparent age for three spring sites (Cox Lake, 26 years; McNenny Pond, 26 years; Mirror Lake, 13 years) also indicated that Mirror Lake spring probably has a component of local recharge from formations that overlie the Minnelusa Formation. In the Madison aquifer, specific conductance ranges from 18 to 945 microsiemens per cen

Hydrologic data for Block Island, Rhode Island

USGS Publications Warehouse

Burns, Emily

1993-01-01

This report was compiled as part of a study to assess the hydrogeology and the quality and quantity of fresh ground water on Block Island, Rhode Island. Hydrologic data were collected on Block Island during 1988-91. The data are pre- sented in illustrations and tables. Data collec- ted include precipitation, surfae-water, ground- water, lithologic, and well-construction and dis- charge information. Precipitation data include total monthly precipitation values from 11 rain gages and water-quality analyses of 14 precipi- tation samples from one station. Surface-water data include water-level measurements at 12 ponds, water-quality data for five ponds, and field specific-conductance measurements at 56 surface- water sites (streams, ponds, and springs). Ground- water data include water-level measurements at 159 wells, water-quality data at 150 wells, and field specific-conductance data at 52 wells. Lithologic logs for 375 wells and test borings, and construc- tion and location data for 570 wells, springs, and test borings are included. In addition, the data set contains data on water quality of water samples, collected by the Rhode Island Department of Health during 1976-91, from Fresh and Sands Ponds and from wells at the Block Island Water Company well field north of Sands Pond.

Using multiple chemical indicators to assess sources of nitrate and age of groundwater in a karstic spring basin

USGS Publications Warehouse

Katz, B.; Copeland, R.; Greenhalgh, T.; Ceryak, R.; Zwanka, W.

2005-01-01

Human health and ecological concerns have arisen due to a steady increase in nitrate-N concentrations during the past 40 years in Fannin Springs (0.3-4.7 mg/L), a regional discharge point with an average flow of >2.8 m3/second (>100 ft3/second) for water from the karstic Upper Floridan aquifer (UFA). Multiple chemical indicators (major dissolved species, 15N and 18O of nitrate, dissolved gases, 78 pesticides and degradates, and 67 organic compounds typically found in domestic and industrial wastewater) and transient tracers (3H/3He, chlorofluorocarbons [CFCs], sulfur hexafluoride [SF6]) were analyzed in water samples from nine wells along three transects and in spring water to assess groundwater age and potential contaminant sources. Land use is predominantly agricultural (52 percent) and forest (31 percent) in the 320 km2 (124 mi2) spring basin, which was delineated from a potentiometric-surface map of the UFA using high-resolution water-level data. Nitrate-N concentrations were highly variable in the oxic UFA and ranged from <0.02 to 4.7 mg/L. ?? 15N-NO3 values (3.4-9.9 per mil) indicated that nitrate contamination originated from inorganic sources (synthetic fertilizer) and organic sources (manure spreading or waste disposal). Higher nitrate concentrations and the younger age of spring water relative to water from upgradient wells indicate better communication with N sources at the surface. Apparent ages of groundwater correlated positively with well depth (P < 0.05) and were younger in water from wells nearer to the spring (<8 years) compared with other wells (10-50 years). Most transient tracer concentrations were consistent with binary mixing curves representing mixtures of water recharged during the past 10 years and older water (recharged before 1940). Young water mixing fractions ranged from 0.07 to 0.90. Trace levels of herbicides found in groundwater and spring water were indicative of applications for vegetative control in agricultural and other land-use types.

A Comprehensive Census of Microbial Diversity in Hot Springs of Tengchong, Yunnan Province China Using 16S rRNA Gene Pyrosequencing

PubMed Central

Dong, Hailiang; Jiang, Hongchen; Briggs, Brandon R.; Peacock, Joseph P.; Huang, Qiuyuan; Huang, Liuqin; Wu, Geng; Zhi, Xiaoyang; Li, Wenjun; Dodsworth, Jeremy A.; Hedlund, Brian P.; Zhang, Chuanlun; Hartnett, Hilairy E.; Dijkstra, Paul; Hungate, Bruce A.

2013-01-01

The Rehai and Ruidian geothermal fields, located in Tengchong County, Yunnan Province, China, host a variety of geochemically distinct hot springs. In this study, we report a comprehensive, cultivation-independent census of microbial communities in 37 samples collected from these geothermal fields, encompassing sites ranging in temperature from 55.1 to 93.6°C, in pH from 2.5 to 9.4, and in mineralogy from silicates in Rehai to carbonates in Ruidian. Richness was low in all samples, with 21–123 species-level OTUs detected. The bacterial phylum Aquificae or archaeal phylum Crenarchaeota were dominant in Rehai samples, yet the dominant taxa within those phyla depended on temperature, pH, and geochemistry. Rehai springs with low pH (2.5–2.6), high temperature (85.1–89.1°C), and high sulfur contents favored the crenarchaeal order Sulfolobales, whereas those with low pH (2.6–4.8) and cooler temperature (55.1–64.5°C) favored the Aquificae genus Hydrogenobaculum. Rehai springs with neutral-alkaline pH (7.2–9.4) and high temperature (>80°C) with high concentrations of silica and salt ions (Na, K, and Cl) favored the Aquificae genus Hydrogenobacter and crenarchaeal orders Desulfurococcales and Thermoproteales. Desulfurococcales and Thermoproteales became predominant in springs with pH much higher than the optimum and even the maximum pH known for these orders. Ruidian water samples harbored a single Aquificae genus Hydrogenobacter, whereas microbial communities in Ruidian sediment samples were more diverse at the phylum level and distinctly different from those in Rehai and Ruidian water samples, with a higher abundance of uncultivated lineages, close relatives of the ammonia-oxidizing archaeon “Candidatus Nitrosocaldus yellowstonii”, and candidate division O1aA90 and OP1. These differences between Ruidian sediments and Rehai samples were likely caused by temperature, pH, and sediment mineralogy. The results of this study significantly expand the current understanding of the microbiology in Tengchong hot springs and provide a basis for comparison with other geothermal systems around the world. PMID:23326417

A comprehensive census of microbial diversity in hot springs of Tengchong, Yunnan Province China using 16S rRNA gene pyrosequencing.

PubMed

Hou, Weiguo; Wang, Shang; Dong, Hailiang; Jiang, Hongchen; Briggs, Brandon R; Peacock, Joseph P; Huang, Qiuyuan; Huang, Liuqin; Wu, Geng; Zhi, Xiaoyang; Li, Wenjun; Dodsworth, Jeremy A; Hedlund, Brian P; Zhang, Chuanlun; Hartnett, Hilairy E; Dijkstra, Paul; Hungate, Bruce A

2013-01-01

The Rehai and Ruidian geothermal fields, located in Tengchong County, Yunnan Province, China, host a variety of geochemically distinct hot springs. In this study, we report a comprehensive, cultivation-independent census of microbial communities in 37 samples collected from these geothermal fields, encompassing sites ranging in temperature from 55.1 to 93.6°C, in pH from 2.5 to 9.4, and in mineralogy from silicates in Rehai to carbonates in Ruidian. Richness was low in all samples, with 21-123 species-level OTUs detected. The bacterial phylum Aquificae or archaeal phylum Crenarchaeota were dominant in Rehai samples, yet the dominant taxa within those phyla depended on temperature, pH, and geochemistry. Rehai springs with low pH (2.5-2.6), high temperature (85.1-89.1°C), and high sulfur contents favored the crenarchaeal order Sulfolobales, whereas those with low pH (2.6-4.8) and cooler temperature (55.1-64.5°C) favored the Aquificae genus Hydrogenobaculum. Rehai springs with neutral-alkaline pH (7.2-9.4) and high temperature (>80°C) with high concentrations of silica and salt ions (Na, K, and Cl) favored the Aquificae genus Hydrogenobacter and crenarchaeal orders Desulfurococcales and Thermoproteales. Desulfurococcales and Thermoproteales became predominant in springs with pH much higher than the optimum and even the maximum pH known for these orders. Ruidian water samples harbored a single Aquificae genus Hydrogenobacter, whereas microbial communities in Ruidian sediment samples were more diverse at the phylum level and distinctly different from those in Rehai and Ruidian water samples, with a higher abundance of uncultivated lineages, close relatives of the ammonia-oxidizing archaeon "Candidatus Nitrosocaldus yellowstonii", and candidate division O1aA90 and OP1. These differences between Ruidian sediments and Rehai samples were likely caused by temperature, pH, and sediment mineralogy. The results of this study significantly expand the current understanding of the microbiology in Tengchong hot springs and provide a basis for comparison with other geothermal systems around the world.

Water quality of the Lexington Reservoir, Santa Clara County, California, 1978-80

USGS Publications Warehouse

Iwatsubo, R.T.; Sylvester, M.A.; Gloege, I.S.

1988-01-01

Analysis of water samples from Lexington Reservoir and Los Gatos Creek upstream from the reservoir from June 1978 through September 1980 showed that water generally met water-quality objectives identified by California Regional Water Quality Control Board, San Francisco Bay Region. Water-temperature profiles show that Lexington Reservoir is a warm monomictic lake. During summer, dissolved-oxygen concentrations generally were not reduced below 5.0 mg/L in the hyplimnion; only once during the study did bottom waters become anoxic. Water transparency decreased with depth. The euphotic zone ranged from 1.0 to 5.4 m, depending on suspended solids and algae, and was greater in summer than in spring. Calcium and bicarbonate were dominant ions at all stations except during spring, following the rainy season, when waters were a mixed cation bicarbonate type. Nitrogen concentrations were greater in samples from reservoir stations than in those from Los Gatos Creek, with most of the nitrogen in ammonia and organic forms. The amount of dissolved nitrate appeared to be related to phytoplankton abundance. Phosphorus and trace-element concentrations were low at all stations. Estimates of net primary productivity and Carlson 's trophic-state index, based on chlorophyll-a concentrations, indicated that reservoir classification ranges from oligotrophic to mesotrophic. Blue-green algae generally were predominant in reservoir samples. (USGS)

Perchlorate as a Ground-Water Tracer Along the Lower Colorado River

NASA Astrophysics Data System (ADS)

Justet, L.; Lico, M. S.

2008-12-01

Anthropogenic perchlorate was first observed in the lower Colorado River (NV and AZ) in 1997. The perchlorate source was traced upstream from Hoover Dam and Lake Mead to Las Vegas Wash. Perchlorate migrated through the local surface- and ground-water systems to the Wash from nearby manufacturing facilities in Henderson, NV, which had been operating since the 1940s. The Nevada Division of Environmental Protection (NDEP) began monitoring perchlorate in the lower Colorado River at Willow Beach, located about 18 km south of the Dam, in 1997. A 3 μg/L reduction was observed at Willow Beach in 2003-2004, coincident with remediation at the Henderson site in 1999-2004. This observed decrease indicates that the effects of remediation rapidly propagated through the surface-water system below the Dam. In July 2008 water samples were collected and analyzed for perchlorate from eight springs along the lower Colorado River below Hoover Dam, from a discharge tunnel in the country rock at Hoover Dam, and from Lake Mead (above and below the thermocline). Lake Mead water collected above the thermocline east of Sentinel Island contained 3.9 μg/L perchlorate, while water below the thermocline contained 1.8 μg/L. Perchlorate concentrations were lower than the 2 to 4 μg/L quantitation limit for the six springs located more than 2 km south of the Dam. Samples from Pupfish Springs, about 0.9 km south of the Dam, contained 6.4-6.8 μg/L perchlorate. Water collected from the discharge tunnel in the Dam contained 8.2 μg/L perchlorate. Perchlorate concentrations observed at Pupfish Springs and the discharge tunnel in the Dam in 2008 are similar to those reported downstream at Willow Beach prior to 2003-2004 by NDEP indicating that the ground water travel time from the Dam to Pupfish Springs is between 4 and 70 years and the maximum flow velocities are between about 13-200 m/y. These rapid velocity estimates suggest that faults and fractures in the area are an important control on discharge points in the vicinity of the Dam. The presence of perchlorate at two sites and absence or background concentrations at the other sites indicates the presence of multiple flow paths between the perchlorate source and the springs near the Dam or that the flow paths are more complex than previously thought.

Unusual cohabitation and competition between Planktothrix rubescens and Microcystis sp. (cyanobacteria) in a subtropical reservoir (Hammam Debagh) located in Algeria

PubMed Central

Guellati, Fatma Zohra; Touati, Hassen; Tambosco, Kevin; Quiblier, Catherine; Bensouilah, Mourad

2017-01-01

Succession in bloom-forming cyanobacteria belonging to distant functional groups in freshwater ecosystems is currently an undescribed phenomenon. However in the Hammam Debagh reservoir (Algeria), P. rubescens and Microcystis sp. co-occur and sometimes proliferate. With the aim of identifying the main factors and processes involved in this unusual cohabitation, water samples were collected monthly from February 2013 to June 2015 at the subsurface at four sampling stations and along the entire water column at one sampling station. In addition, the composition of the cyanobacterial communities was estimated by Illumina sequencing of a 16S rRNA gene fragment from samples collected over one year (October 2013-November 2014). This molecular approach showed that the Hammam Debagh reservoir displays high species richness (89 species) but very low diversity due to the high dominance of Microcystis in this community. Furthermore, it appears that Planktothrix rubescens and Microcystis sp. coexisted (from September to January) but proliferated alternately (Spring 2015 for P. rubescens and Spring 2014 and Autumn 2014/2015 for Microcystis). The main factors and processes explaining these changes in bloom-forming species seem to be related to the variation in the depth of the lake during the mixing period and to the water temperatures during the winter prior to the bloom season in spring. PMID:28859113

Aquifer Susceptibility in Virginia: Data on Chemical and Isotopic Composition, Recharge Temperature, and Apparent Age of Water from Wells and Springs, 1998-2000

USGS Publications Warehouse

Nelms, David L.; Harlow, George E.

2003-01-01

The determination of aquifer susceptibility to contamination from near-surface sources by the use of ground-water dating techniques is a critical part of Virginia's Source Water Assessment Program. As part of the Virginia Aquifer Susceptibility study, water samples were collected between 1998 and 2000 from 145 wells and 6 springs in various hydrogeologic settings across the Commonwealth. Samples were analyzed to determine water chemistry?including nitrate (NO3), dissolved organic carbon (DOC), and radon-222 (222Rn), major dissolved and noble gases?nitrogen (N2), argon (Ar), oxygen (O2), carbon dioxide (CO2), methane (CH4), helium (He), and neon (Ne), environmental tracers?chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), tritium (3H), and tritium/helium-3 (3H/3He), carbon isotopes?carbon-14 (14C) and carbon-13 (d13C), and stable isotopes of oxygen (d18O) and hydrogen (d2H). The chemical and isotopic composition, recharge temperatures, and apparent ages of these water samples are presented in this report. Data collected between 1999 and 2000 from 18 wells in Virginia as part of two other studies by the U.S. Geological Survey also are presented. Most of the sites sampled serve as public water supplies and are included in the comprehensive Source Water Assessment Program for the Commonwealth.

Geochemistry and migration of contaminants at the Weldon Spring chemical plant site, St. Charles County, Missouri, 1989-91

USGS Publications Warehouse

Schumacher, John G.

1993-01-01

The geochemistry of the shallow aquifer and geochemical controls on the migration of uranium and other constituents from raffinate pits were determined at the Weldon Spring chemical plant site. Surface-water samples from the raffinate pits con- tained large concentrations of calcium, magnesium, sodium, potassium, sulfate, nitrite, lithium, moly- bdenum, strontium, vanadium, and uranium. Analyses of interstitial-water samples from raffinate pit 3 indicated that concentrations of most constituents increased with increasing depth below the water- sediment interface. Nitrate and uranium were not chemically reduced and attenuated within the raffinate pits and can be expected to migrate into the overburden. Laboratory sorption experiments were performed to evaluate the effect of pH value on the sorption of several raffinate constituents by the overburden. No sorption of calcium, sodium, sulfate, nitrate, or lithium was observed. Sorption of molybdenum was dependent on solution pH and sorption of uranium was dependent on solution pH and carbonate concentration. The sorption of uranium and molybdenum was consistent with sorption controlled by oxyhydroxides. The quality of water collected in overburden lysimeters near raffinate pit 4 can be modeled as a mixture of water from raffinate pits 3 and 4, and an uncontaminated com- ponent in a system at equilibrium with ferrihydrite and calcite. Increased constituent concentrations in a perennial spring north of the site were the result of a subsurface connection between the spring and several losing stream segments receiving runoff from the site, in addition to seepage from the raffinate pits.

Hydrologic and environmental controls on uranium-series and strontium isotope ratios in a natural weathering environment

NASA Astrophysics Data System (ADS)

White, A. M.; Ma, L.; Moravec, B. G.; McIntosh, J. C.; Chorover, J.

2017-12-01

In a remote, volcanic headwater catchment of the Jemez River Basin Critical Zone Observatory (JRB-CZO) in NM, stable water isotopes and solute chemistry have shown that snowmelt infiltrates and is stored before later discharging into springs and streams via subsurface flowpaths that vary seasonally. Therefore, water-rock reactions are also expected to change with season as hydrologic flowpaths transport water, gases and solutes through different biogeochemical conditions, rock types and fracture networks. Uranium-series isotopes have been shown to be a novel tracer of water-rock reactions and source water contributions while strontium isotopes are frequently used as indicators of chemical weathering and bedrock geology. This study combines both isotopes to understand how U and Sr isotope signatures evolve through the Critical Zone (CZ). More specifically, this work examines the relationship between seasonality, water transit time (WTT), and U-series and Sr isotopes in stream and spring waters from three catchments within the JRB-CZO, as well as lithology, rock type and CZ structure in solid phase cores. Samples from ten springs with known WTTs were analyzed for U and Sr isotopes to determine the effect of WTT on the isotopic composition of natural waters. Results suggest that WTT alone cannot explain the variability of U and Sr isotopes in JRB-CZO springs. Stream samples were also collected across two water years to establish how seasonality controls surface water isotopic composition. U and Sr isotope values vary with season, consistent with a previous study from the La Jara catchment; however, this study revealed that these changes do not show a systematic pattern among the three catchments suggesting that differences in the mineralogy and structure of the deep CZ in individual catchments, and partitioning of water along deep vs surficial and fracture vs matrix flow paths, likely also control isotopic variability. The distribution of U-series and Sr isotopes in core samples with depth shows distinct weathering profiles with variable 234U/238U activity and Sr isotope ratios. Comparison of the isotopic composition of cores and groundwaters from similar depths, as well as surface waters in the JRB-CZO will be vital for the characterization of hydrogeologic controls on isotopic composition in this complex terrain.

Geochemical Investigation of Source Water to Cave Springs, Great Basin National Park, White Pine County, Nevada

USGS Publications Warehouse

Prudic, David E.; Glancy, Patrick A.

2009-01-01

Cave Springs supply the water for the Lehman Caves Visitor Center at Great Basin National Park, which is about 60 miles east of Ely, Nevada, in White Pine County. The source of water to the springs was investigated to evaluate the potential depletion caused by ground-water pumping in areas east of the park and to consider means to protect the supply from contamination. Cave Springs are a collection of several small springs that discharge from alluvial and glacial deposits near the contact between quartzite and granite. Four of the largest springs are diverted into a water-collection system for the park. Water from Cave Springs had more dissolved strontium, calcium, and bicarbonate, and a heavier value of carbon-13 than water from Marmot Spring at the contact between quartzite and granite near Baker Creek campground indicating that limestone had dissolved into water at Cave Springs prior to discharging. The source of the limestone at Cave Springs was determined to be rounded gravels from a pit near Baker, Nevada, which was placed around the springs during the reconstruction of the water-collection system in 1996. Isotopic compositions of water at Cave Springs and Marmot Spring indicate that the source of water to these springs primarily is from winter precipitation. Mixing of water at Cave Springs between alluvial and glacial deposits along Lehman Creek and water from quartzite is unlikely because deuterium and oxygen-18 values from a spring discharging from the alluvial and glacial deposits near upper Lehman Creek campground were heavier than the deuterium and oxygen-18 values from Cave Springs. Additionally, the estimated mean age of water determined from chlorofluorocarbon concentrations indicates water discharging from the spring near upper Lehman Creek campground is younger than that discharging from either Cave Springs or Marmot Spring. The source of water at Cave Springs is from quartzite and water discharges from the springs on the upstream side of the contact between quartzite and granite where the alluvial and glacial deposits are thin. Consequently, the potential for depletion of discharge at Cave Springs from ground-water pumping in Snake Valley east of the park is less than if the source of water was from alluvial and glacial deposits or carbonate rocks, which would be more directly connected to downstream pumping sites in Snake Valley.

Uranium hydrogeochemical and stream sediment reconnaissance of the Arminto NTMS quadrangle, Wyoming, including concentrations of forty-three additional elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morgan, T.L.

1979-11-01

During the summers of 1976 and 1977, 570 water and 1249 sediment samples were collected from 1517 locations within the 18,000-km/sup 2/ area of the Arminto NTMS quadrangle of central Wyoming. Water samples were collected from wells, springs, streams, and artifical ponds; sediment samples were collected from wet and dry streams, springs, and wet and dry ponds. All water samples were analyzed for 13 elements, including uranium, and each sediment sample was analyzed for 43 elements, including uranium and thorium. Uranium concentrations in water samples range from below the detection limit to 84.60 parts per billion (ppb) with a meanmore » of 4.32 ppb. All water sample types except pond water samples were considered as a single population in interpreting the data. Pond water samples were excluded due to possible concentration of uranium by evaporation. Most of the water samples containing greater than 20 ppb uranium grouped into six clusters that indicate possible areas of interest for further investigation. One cluster is associated with the Pumpkin Buttes District, and two others are near the Kaycee and Mayoworth areas of uranium mineralization. The largest cluster is located on the west side of the Powder River Basin. One cluster is located in the central Big Horn Basin and another is in the Wind River Basin; both are in areas underlain by favorable host units. Uranium concentrations in sediment samples range from 0.08 parts per million (ppm) to 115.50 ppm with a mean of 3.50 ppm. Two clusters of sediment samples over 7 ppm were delineated. The first, containing the two highest-concentration samples, corresponds with the Copper Mountain District. Many of the high uranium concentrations in samples in this cluster may be due to contamination from mining or prospecting activity upstream from the sample sites. The second cluster encompasses a wide area in the Wind River Basin along the southern boundary of the quadrangle.« less

Quantitative Determination of Spring Water Quality Parameters via Electronic Tongue

PubMed Central

Carbó, Noèlia; López Carrero, Javier; Garcia-Castillo, F. Javier; Olivas, Estela; Folch, Elisa; Alcañiz Fillol, Miguel; Soto, Juan

2017-01-01

The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These noble metals have a high durability and are not demanding for maintenance, features required for the development of future automated equipment. A pulse voltammetry study was conducted in 83 spring water samples to determine concentrations of nitrate (range: 6.9–115 mg/L), sulfate (32–472 mg/L), fluoride (0.08–0.26 mg/L), chloride (17–190 mg/L), and sodium (11–94 mg/L) as well as pH (7.3–7.8). These parameters were also determined by routine analytical methods in spring water samples. A partial least squares (PLS) analysis was run to obtain a model to predict these parameter. Orthogonal signal correction (OSC) was applied in the preprocessing step. Calibration (67%) and validation (33%) sets were selected randomly. The electronic tongue showed good predictive power to determine the concentrations of nitrate, sulfate, chloride, and sodium as well as pH and displayed a lower R2 and slope in the validation set for fluoride. Nitrate and fluoride concentrations were estimated with errors lower than 15%, whereas chloride, sulfate, and sodium concentrations as well as pH were estimated with errors below 10%. PMID:29295592

Online analysis: Deeper insights into water quality dynamics in spring water.

PubMed

Page, Rebecca M; Besmer, Michael D; Epting, Jannis; Sigrist, Jürg A; Hammes, Frederik; Huggenberger, Peter

2017-12-01

We have studied the dynamics of water quality in three karst springs taking advantage of new technological developments that enable high-resolution measurements of bacterial load (total cell concentration: TCC) as well as online measurements of abiotic parameters. We developed a novel data analysis approach, using self-organizing maps and non-linear projection methods, to approximate the TCC dynamics using the multivariate data sets of abiotic parameter time-series, thus providing a method that could be implemented in an online water quality management system for water suppliers. The (TCC) data, obtained over several months, provided a good basis to study the microbiological dynamics in detail. Alongside the TCC measurements, online abiotic parameter time-series, including spring discharge, turbidity, spectral absorption coefficient at 254nm (SAC254) and electrical conductivity, were obtained. High-density sampling over an extended period of time, i.e. every 45min for 3months, allowed a detailed analysis of the dynamics in karst spring water quality. Substantial increases in both the TCC and the abiotic parameters followed precipitation events in the catchment area. Differences between the parameter fluctuations were only apparent when analyzed at a high temporal scale. Spring discharge was always the first to react to precipitation events in the catchment area. Lag times between the onset of precipitation and a change in discharge varied between 0.2 and 6.7h, depending on the spring and event. TCC mostly reacted second or approximately concurrent with turbidity and SAC254, whereby the fastest observed reaction in the TCC time series occurred after 2.3h. The methodological approach described here enables a better understanding of bacterial dynamics in karst springs, which can be used to estimate risks and management options to avoid contamination of the drinking water. Copyright © 2017 Elsevier B.V. All rights reserved.

Quantitative analysis of microbial contamination in private drinking water supply systems.

PubMed

Allevi, Richard P; Krometis, Leigh-Anne H; Hagedorn, Charles; Benham, Brian; Lawrence, Annie H; Ling, Erin J; Ziegler, Peter E

2013-06-01

Over one million households rely on private water supplies (e.g. well, spring, cistern) in the Commonwealth of Virginia, USA. The present study tested 538 private wells and springs in 20 Virginia counties for total coliforms (TCs) and Escherichia coli along with a suite of chemical contaminants. A logistic regression analysis was used to investigate potential correlations between TC contamination and chemical parameters (e.g. NO3(-), turbidity), as well as homeowner-provided survey data describing system characteristics and perceived water quality. Of the 538 samples collected, 41% (n = 221) were positive for TCs and 10% (n = 53) for E. coli. Chemical parameters were not statistically predictive of microbial contamination. Well depth, water treatment, and farm location proximate to the water supply were factors in a regression model that predicted presence/absence of TCs with 74% accuracy. Microbial and chemical source tracking techniques (Bacteroides gene Bac32F and HF183 detection via polymerase chain reaction and optical brightener detection via fluorometry) identified four samples as likely contaminated with human wastewater.

Using multiple chemical indicators to characterize and determine the age of groundwater from selected vents of the silver springs group, Central Florida, USA

USGS Publications Warehouse

Knowles, L.; Katz, B.G.; Toth, D.J.

2010-01-01

The Silver Springs Group, Florida (USA), forms the headwaters of the Silver River and supports a diverse ecosystem. The 30 headwater springs divide into five subgroups based on chemistry. Five selected spring vents were sampled in 2007 to better understand the contaminant sources and groundwater flow system. Elevated nitrate-N concentrations (>0.8mg/L) in the five spring vents likely originate from inorganic (fertilizers) and organic sources, based on nitrogen and oxygen isotope ratios of nitrate. Evidence for denitrification in the Lost River Boil spring includes enriched ??15N and ??18O, excess N2 gas, and low dissolved O2 concentrations (<0.5mg/L). Multiple age-tracer data (SF6, 3H, tritiogenic 3He) for the two uppermost springs (Mammoth East and Mammoth West) indicate a binary mixture dominated by recent recharge water (mean age 6-7 years, and 87-97% young water). Tracer data for the three downstream spring vents (Lost River Boil, Catfish Hotel-1, and Catfish Conventional Hall-1) indicate exponential mixtures with mean ages of 26-35 years. Contamination from non-atmospheric sources of CFCs and SF5CF3 precluded their use as age tracers here. Variations in chemistry were consistent with mean groundwater age, as nitrate-N and dissolved O2 concentrations were higher in younger waters, and the Ca/Mg ratio decreased with increasing mean age. ?? 2010 Springer-Verlag (outside the USA).

Using multiple chemical indicators to characterize and determine the age of groundwater from selected vents of the Silver Springs Group, central Florida, USA

NASA Astrophysics Data System (ADS)

Knowles, Leel; Katz, Brian G.; Toth, David J.

2010-12-01

The Silver Springs Group, Florida (USA), forms the headwaters of the Silver River and supports a diverse ecosystem. The 30 headwater springs divide into five subgroups based on chemistry. Five selected spring vents were sampled in 2007 to better understand the contaminant sources and groundwater flow system. Elevated nitrate-N concentrations (>0.8 mg/L) in the five spring vents likely originate from inorganic (fertilizers) and organic sources, based on nitrogen and oxygen isotope ratios of nitrate. Evidence for denitrification in the Lost River Boil spring includes enriched δ15N and δ18O, excess N2 gas, and low dissolved O2 concentrations (<0.5 mg/L). Multiple age-tracer data (SF6, 3H, tritiogenic 3He) for the two uppermost springs (Mammoth East and Mammoth West) indicate a binary mixture dominated by recent recharge water (mean age 6-7 years, and 87-97% young water). Tracer data for the three downstream spring vents (Lost River Boil, Catfish Hotel-1, and Catfish Conventional Hall-1) indicate exponential mixtures with mean ages of 26-35 years. Contamination from non-atmospheric sources of CFCs and SF5CF3 precluded their use as age tracers here. Variations in chemistry were consistent with mean groundwater age, as nitrate-N and dissolved O2 concentrations were higher in younger waters, and the Ca/Mg ratio decreased with increasing mean age.

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2013–2015

USGS Publications Warehouse

Macy, Jamie P.; Mason, Jon P.

2017-12-07

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area. Precipitation in the area typically is between 6 and 16 inches per year.The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2013 to December 2015. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry.In 2013, total groundwater withdrawals were 3,980 acre-feet (ft), in 2014 total withdrawals were 4,170 acre-ft, and in 2015 total withdrawals were 3,970 acre-ft. From 2013 to 2015 total withdrawals varied by less than 5 percent.From 2014 to 2015, annually measured water levels in the Black Mesa area declined in 9 of 15 wells that were available for comparison in the unconfined areas of the N aquifer, and the median change was -0.1 feet. Water levels declined in 3 of 16 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was 0.6 feet. From the prestress period (prior to 1965) to 2015, the median water-level change for 34 wells in both the confined and unconfined areas was -13.2 feet; the median water-level changes were -1.7 feet for 16 wells measured in the unconfined areas and -42.3 feet for 18 wells measured in the confined area.Spring flow was measured at four springs in 2014. Flow fluctuated during the period of record for Burro Spring and Unnamed Spring near Dennehotso, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Pasture Canyon Spring. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s and discharge at Unnamed Spring near Dennehotso has fluctuated for the period of record. Trend analysis for discharge at Moenkopi and Pasture Canyon Springs yielded a slope significantly different (p<0.05) from zero.Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2015), Dinnebito Wash near Sand Springs 09401110 (1993 to 2015), Polacca Wash near Second Mesa 09400568 (1994 to 2015), and Pasture Canyon Springs 09401265 (2004 to 2015). Median winter flows (November through February) of each water year were used as an index of the amount of groundwater discharge at the above-named sites. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, which suggests no change in groundwater discharge.In 2014, water samples collected from four springs in the Black Mesa area were analyzed for selected chemical constituents, and the results were compared with previous analyses. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 25 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Burro Spring and Unnamed Spring near Dennehotso have varied for the period of record, but there is no increasing or decreasing statistical trend in the data.

Evaluation of baseline ground-water conditions in the Mosteiros, Ribeira Paul, and Ribeira Fajã Basins, Republic of Cape Verde, West Africa, 2005-06

USGS Publications Warehouse

Heilweil, Victor M.; Earle, John D.; Cederberg, Jay R.; Messer, Mickey M.; Jorgensen, Brent E.; Verstraeten, Ingrid M.; Moura, Miguel A.; Querido, Arrigo; Spencer,; Osorio, Tatiana

2006-01-01

This report documents current (2005-06) baseline ground-water conditions in three basins within the West African Republic of Cape Verde (Mosteiros on Fogo, Ribeira Paul on Santo Antão, and Ribeira Fajã on São Nicolau) based on existing data and additional data collected during this study. Ground-water conditions (indicators) include ground-water levels, ground-water recharge altitude, ground-water discharge amounts, ground-water age (residence time), and ground-water quality. These indicators are needed to evaluate (1) long-term changes in ground-water resources or water quality caused by planned ground-water development associated with agricultural projects in these basins, and (2) the feasibility of artificial recharge as a mitigation strategy to offset the potentially declining water levels associated with increased ground-water development.Ground-water levels in all three basins vary from less than a few meters to more than 170 meters below land surface. Continuous recorder and electric tape measurements at three monitoring wells (one per basin) showed variations between August 2005 and June 2006 of as much as 1.8 meters. Few historical water-level data were available for the Mosteiros or Ribeira Paul Basins. Historical records from Ribeira Fajã indicate very large ground-water declines during the 1980s and early 1990s, associated with dewatering of the Galleria Fajã tunnel. More-recent data indicate that ground-water levels in Ribeira Fajã have reached a new equilibrium, remaining fairly constant since the late 1990s.Because of the scarcity of observation wells within each basin, water-level data were combined with other techniques to evaluate ground-water conditions. These techniques include the quantification of ground-water discharge (well withdrawals, spring discharge, seepage to springs, and gallery drainage), field water-quality measurements, and the use of environmental tracers to evaluate sources of aquifer recharge, flow paths, and ground-water residence times.In the Mosteiros Basin, measured well and spring discharge is about 220,000 cubic meters per year. For the Ribeira Paul Basin, measured well discharge, spring discharge, and ground-water seepage to springs is about 1,600,000 cubic meters per year. Ribeira Fajã Basin is the driest of the three basins with a precipitation rate of about half that of the other two basins. The only measurable ground-water discharge from this basin is from Galleria Fajã, estimated to be about 150,000 cubic meters per year. Measured discharge for all three basins does not include submarine outflow or agricultural/phreatophyte consumptive use (Paul Basin, only) and is assumed to be less than total ground-water discharge.Ground-water ages indicate that recharge to wells and springs occurred from more than 50 years ago at some locations to within the past decade at other sites. Ground water in Paul is younger than that in the other two basins, indicating that recharge generally occurred within the past 50 years. Ground water at all the dateable sites using tritium/helium in both the Mosteiros and Ribeira Fajã Basins show that recharge occurred more than 50 years before the sampling dates. Ground-water tritium/helium age dating was not possible at some sites in Mosteiros and Ribeira Fajã Basins because of the presence of helium in the aquifer derived from the mantle or aquifer matrix. However, this helium was useful for accurate age dating of the unaffected ground-water sites.Dissolved gases indicate that most ground-water recharge occurs at mid and high altitudes within all three basins; calculated recharge altitudes ranged from 700 to more than 2,000 meters. In the Mosteiros and Ribeira Fajã Basins, recharge altitudes are much higher than the wells and springs. This suggests that it may take many years for artificial recharge to result in a beneficial impact on the aquifer in areas where the agricultural projects are implemented. Recharge altitudes in Paul Basin also were generally higher than their respective ground-water discharge sampling sites except for one spring, Seladinha. This spring, in combination with generally younger ground-water ages in Paul, indicates the existence of some short flow paths where artificial recharge may possibly enhance available water resources within a few years.The salinity of wells and springs is generally low in the Ribeira Paul and Ribeira Fajã Basins, but somewhat higher in Mosteiros Basin. Specific-conductance measurements of wells and springs in Ribeira Paul and Ribeira Fajã ranged from about 200 to 700 microsiemens per centimeter at 25 degrees Celsius. Although the Monte Vermelho spring in Mosteiros Basin also has very low salinity (200 microsiemens per centimeter at 25 degrees Celsius), water from the wells along the coastal plain has specific-conductance measurements of as much as 16,000 microsiemens per centimeter at 25 degrees Celsius. These higher values indicate some brackish water intrusion. Additional ground-water development of the Mosteiros coastal plain may exacerbate this situation.

Baseline well inventory and groundwater-quality data from a potential shale gas resource area in parts of Lee and Chatham Counties, North Carolina, October 2011-August 2012

USGS Publications Warehouse

Chapman, Melinda J.; Gurley, Laura N.; Fitzgerald, Sharon A.

2014-01-01

Records were obtained for 305 wells and 1 spring in northwestern Lee and southeastern Chatham counties, North Carolina. Well depths ranged from 26 to 720 feet and yields ranged from 0.25 to 100 gallons per minute. A subset of 56 wells and 1 spring were sampled for baseline groundwaterquality constituents including the following: major ions; dissolved metals; nutrients; dissolved gases (including methane); volatile and semivolatile organic compounds; glycols; isotopes of strontium, radium, methane (if sufficient concentration), and water; and dissolved organic and inorganic carbon. Dissolved methane gas concentrations were low, ranging from less than 0.00007 (lowest reporting level) to 0.48 milligrams per liter. Concentrations of nitrate, boron, iron, manganese, sulfate, chloride, total dissolved solids, and measurements of pH exceeded federal and state drinking water standards in a few samples. Iron and manganese concentrations exceeded the secondary (aesthetic) drinking water standard in approximately 35 to 37 percent of the samples.

Fluid-inclusion evidence for previous higher temperatures in the SUNEDCO 58-28 drill hole near Breitenbush hot springs, Oregon

USGS Publications Warehouse

Bargar, Keith E.; ,

1993-01-01

The SUNEDCO 58-28 geothermal exploration drill hole was completed in 1981 to a depth of 2, 457 m near Breitenbush Hot Springs in the Western Cascade Mountains of northern Oregon. One hundred thirteen liquid-rich fluid inclusions (mostly secondary) were analyzed from drill cuttings samples of hydrothermal quartz, calcite, and anhydrite, as well as primary quartz phenocrysts. Except for one hydrothermal quartz specimen, minimum homogenization temperature (Th) measurements of fluid inclusions plot very close to the present measured temperatures for the drill hole. Fluid-inclusion data from near the bottom of the drill hole suggest that these rocks were altered by water of significantly greater salinity than Breitenbush Hot Springs water.

Statistical analysis of arsenic contamination in drinking water in a city of Iran and its modeling using GIS.

PubMed

Sadeghi, Fatemeh; Nasseri, Simin; Mosaferi, Mohammad; Nabizadeh, Ramin; Yunesian, Masud; Mesdaghinia, Alireza

2017-05-01

In this research, probable arsenic contamination in drinking water in the city of Ardabil was studied in 163 samples during four seasons. In each season, sampling was carried out randomly in the study area. Results were analyzed statistically applying SPSS 19 software, and the data was also modeled by Arc GIS 10.1 software. The maximum permissible arsenic concentration in drinking water defined by the World Health Organization and Iranian national standard is 10 μg/L. Statistical analysis showed 75, 88, 47, and 69% of samples in autumn, winter, spring, and summer, respectively, had concentrations higher than the national standard. The mean concentrations of arsenic in autumn, winter, spring, and summer were 19.89, 15.9, 10.87, and 14.6 μg/L, respectively, and the overall average in all samples through the year was 15.32 μg/L. Although GIS outputs indicated that the concentration distribution profiles changed in four consecutive seasons, variance analysis of the results showed that statistically there is no significant difference in arsenic levels in four seasons.

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman Area, Idaho, 2002

USGS Publications Warehouse

Rattray, Gordon W.; Campbell, Linford J.

2004-01-01

The U.S. Geological Survey, Idaho Department of Water Resources, and the State of Idaho INEEL Oversight Program, in cooperation with the U.S. Department of Energy, sampled water from 17 sites as part of the sixth round of a long-term project to monitor water quality of the eastern Snake River Plain aquifer from the southern boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman area. The samples were collected from eight irrigation wells, three domestic wells, one stock well, one dairy well, one commercial well, one observation well, and two springs and analyzed for selected radiochemical and chemical constituents. One quality-assurance sample, a sequential replicate, also was collected and analyzed. Many of the radionuclide and inorganic-constituent concentrations were greater than the reporting levels and most of the organic-constituent concentrations were less than the reporting levels. However, none of the reported radiochemical- or chemical-constituent concentrations exceeded the maximum contaminant levels for drinking water established by the U.S. Environmental Protection Agency. Statistical evaluation of the replicate sample pair indicated that, with 95 percent confidence, 132 of the 135 constituent concentrations of the replicate pair were equivalent.

Influence of volcanic history on groundwater patterns on the west slope of the Oregon High Cascades.

Treesearch

A. Jefferson; G. Grant; T. Rose

2006-01-01

Spring systems on the west slope of the Oregon High Cascades exhibit complex relationships among modern topography, lava flow geometries, and groundwater flow patterns. Seven cold springs were continuously monitored for discharge and temperature in the 2004 water year, and they were periodically sampled for ?18O, ?D, tritium, and dissolved noble gases. Anomalously high...

Results of investigation at the Miravalles geothermal field, Costa Rica. Resultados de las investigaciones en el campo geotermico de Miravalles, Costa Rica; Parte 2, Muestreo de fluidos pozo abajo

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grigsby, C.O.; Goff, F.; Trujillo, P.E. Jr.

Samples of the geothermal fluids in the Miravalles, Costa Rica, geothermal system were collected from production wellbores using downhole fluid samplers, from flowing wellheads using miniseparators, and from hot springs that discharge in the area. The reservoir fluid at Miravalles is a neutral-chloride-type water, but fumaroles and acid-sulfate springs are present within the main thermal area, and there are bicarbonate-rich hot springs that are clearly related to the neutral-chloride reservoir fluids. Dissolved gases are primarily a mixture of CO{sub 2} with air, but samples collected in the fumarolic areas also contain H{sub 2}S. Water-stable isotope analyses suggest local meteoric recharge,more » and the reservoir fluid shows oxygen isotopic shifts of about 2.5% due to high-temperature oxygen exchange between water and rock. Chemical geothermometer temperatures are consistent with the measured downhole temperature of 220{degrees} to 255{degrees}C. This pattern of neutral-chloride reservoir fluids with acid-sulfate springs near the source region and bicarbonate-rich chloride hot springs at the periphery of the system suggests a lateral outflow type of hydrothermal system. In addition to the geochemical evidence, temperature profiles from several of the wells show temperature reversals that are characteristic of lateral outflow plumes. We find no evidence for the underlying, higher temperature (300{degrees}C) system, which has been suggested by other investigators. 24 refs., 14 figs., 6 tabs.« less

Microbial and Metabolic Diversity of the Alkaline Hot Springs of Paoha Island: A Late Archean and Proterozoic Ocean Analogue Environment.

NASA Astrophysics Data System (ADS)

Foster, I. S.; Demirel, C.; Hyde, A.; Motamedi, S.; Frantz, C. M.; Stamps, B. W.; Nunn, H. S.; Oremland, R. S.; Rosen, M.; Miller, L. G.; Corsetti, F. A.; Spear, J. R.

2016-12-01

Paoha Island formed 450 years ago within Mono Lake, California, as a result of magmatic activity in the underlying Long Valley Caldera. Previous studies of Paoha Island hot springs focused on the presence of novel organisms adapted to high levels of arsenic (114-138 µM). However, the microbial community structure, relationship with Mono Lake, and preservation potential of these communities remains largely unexplored. Here, we present water chemistry, 16S and 18S rRNA gene sequences, and metagenomic data for spring water and biofilms sampled on a recently exposed mudflat along the shoreline of Paoha Island. Spring waters were hypoxic, alkaline, and saline, had variable temperature (39-70 °C near spring sources) and high concentrations of arsenic, sulfide and reduced organic compounds. Thermodynamic modeling based on spring water chemistry indicated that sulfide and methane oxidation were the most energetically favorable respiratory metabolisms. 16S rRNA gene sequencing revealed distinct communities in different biofilms: red biofilms were dominated by arsenite-oxidizing phototrophs within the Ectothiorhodospiraceae, while OTUs most closely related to the cyanobacterial genus Arthrospira were present in green biofilms, as well as a large proportion of sequences assigned to sulfur-oxidizing bacteria. Metagenomic analysis identified genes related to arsenic resistance, arsenic oxidation/reduction, sulfur oxidation and photosynthesis. Eukaryotic rRNA gene sequencing analyses revealed few detectable taxa in spring biofilms and waters compared to Mono Lake; springs receiving splash from the lake were dominated by the alga Picocystis. The co-occurrence of hypoxia, high pH, and close proximity of anoxygenic and oxygenic phototrophic mats makes this site a potential Archean/Proterozoic analogue environment, but suggests that similar environments if preserved in the rock record, may not preserve evidence for community dynamics or the existence of photosynthetic metabolisms.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rose, T

I'm writing at the request of the Pit River Tribe to offer my professional opinion as a geochemist regarding the origin of groundwater discharge at the Fall River Springs, Shasta Co., California. In 1997, I conducted a study of the large volume cold springs associated with the Cascade Volcanoes in northern California, in collaboration with one of my colleagues. This work was published as a Lawrence Livermore National Laboratory report (Davisson and Rose, 1997). The Fall River Springs emerge from the distal end of the Giant Crater Lava Field, a laterally extensive basalt flow that stretches from the southern flankmore » of Medicine Lake Volcano southward for a distance of 40 km. Both Medicine Lake Volcano and the Giant Crater Lava Field have virtually no surface water drainages. Precipitation that falls in these areas is inferred to seep into fractures in the rock, where it is carried down gradient under the force of gravity. Mean annual precipitation rates on Medicine Lake Volcano and the Giant Crater Lava field are adequate to account for the {approx}1200 ft{sup 3}/sec discharge of the Fall River Springs. To evaluate the origin of the springs using geochemical methods, water samples were collected from the Fall River Springs and the Medicine Lake highlands and analyzed for oxygen and hydrogen isotope ratios. The isotope ratios measured for a groundwater sample are diagnostic of the average composition of the precipitation from which the water was derived. The isotope ratios of rain and snow also vary systematically with elevation, such that groundwater derived from recharge at higher elevations can be distinguished from that which originated at lower elevations. The stable isotope data for the Fall River Springs are consistent with groundwater recharge on the Medicine Lake Volcano and adjacent lava field. Mass balance calculations suggest that approximately half of the Fall River Springs flow is derived from the volcanic edifice. Rose and Davisson (1996) showed that the large volume cold springs associated with the Cascade Volcanoes commonly contain dissolved CO{sub 2} that originated from the volcanoes. This volcanic CO{sub 2} component is readily identified from carbon-14 measurements of the water. Carbon-14 analyses of the Fall River samples indicate that at least 27% of the dissolved inorganic carbon in the springs was derived from a volcanic CO{sub 2} source. Such a large volcanic CO{sub 2} flux requires that the groundwater supplying flow to the Fall River Springs must originate from a volcano where magma degassing is actively occurring. Given the hydrogeologic configuration of the Fall River aquifer system, it appears that the Medicine Lake Volcano is the only likely source of the volcanic CO{sub 2}. These data independently confirm the Medicine Lake highlands as a significant recharge source for the Fall River Springs. Moreover, these data indicate that groundwater recharge occurring on Medicine Lake Volcano must interact with a CO{sub 2} volatile phase derived from the geothermal system beneath the volcano. The lack of hot springs on Medicine Lake Volcano suggests that the geothermal system underlying the volcano is relatively tightly sealed. Nevertheless, it is probable that the geothermal fluid originates from precipitation falling on the volcanic edifice. This is the same water that supplies an important fraction of the Fall River Spring discharge. The source of the geothermal fluid can be evaluated using stable isotopes. The oxygen isotope signature of the geothermal fluid may have been modified by high temperature oxygen isotope exchange with the surrounding rock, but the hydrogen isotope signature should still be diagnostic of the origin of the fluid. Although the geothermal system appears to be largely decoupled from the shallow groundwater system that supplies the Fall River Springs, it is uncertain what impact the development of the geothermal system as an energy resource would have on groundwater circulation patterns on the volcano. Given the importance of the Fall River Springs as a water resource for the State of California, it would be prudent to carefully evaluate this question before proceeding with geothermal energy development on Medicine Lake Volcano.« less

Artificial sweeteners: Sucralose and Acesulfame-K; emerging pollutants indicators of specific transport in karst systems: Application to semi-arid regions.

NASA Astrophysics Data System (ADS)

Doummar, J.; Aoun, M. E.

2016-12-01

The assessment of vulnerability in karst system is highly challenging as it highly depends on the identification of diffuse and concentrated infiltration from surface karst features, the latter varying with time. This work shows that the artificial sweeteners Sucralose (SUC) and Acesulfame-K (ACE-K) can be used as transport indicators for persistent waste water effluent in karst systems. In the framework of a PEER NSF/USAID funded project, a karst spring (Qachqouch; yearly discharge of circa 50 Mm3) in Mount Lebanon was monitored following a multi-precipitation event. Acesulfame-K (ACE-K) and Sucralose (SUC), indicative of domestic waste water, Chloride and Calcium ions, Electrical conductivity (EC), and turbidity along with discharge were collected at the spring for nine days after the rain events at time intervals varying between 30 min and 4 hours. The samples were analyzed for ACE-K and SUC at Eaton Eurofins in California. A first sampling campaign was undertaken to assess the base flow concentrations in wells, waste water, and the main losing river on the catchment area along with Spring Qachqouch. It revealed that ACE-K and SUC are found in the spring at base flow concentrations of 170 ng/l, and 120 ng/l respectively. A two-end mixing model based on Chloride and Calcium allowed the quantification of newly recharged water (11% of total flow) reaching the springs at specific monitoring intervals through fast flow pathways. The results revealed that the artificial sweeteners are persistent in the system outside rain events. They are mostly transported to the springs through fast pathways from flushed wastewater; their breakthrough curves coincide with the arrival of new waters (from the sinking stream or sinkholes). About 120 grams of SUC and 160 grams of ACE-K reached the springs during peak response in three consecutive events. Based on the quantities, and given that both acesulfame and SUC are excreted mostly unchanged in wastewater, estimates of consumption of SUC and ACE-K on the catchment area can be determined accordingly . Moreover, the comparison of breakthrough curves of both artificial sweeteners shows that ACE-K displays a higher variance (translated by a higher longitudinal dispersivity) with respect to SUC.

Seasonal changes in Sphagnum peatland testate amoeba communities along a hydrological gradient.

PubMed

Marcisz, Katarzyna; Lamentowicz, Lukasz; Słowińska, Sandra; Słowiński, Michał; Muszak, Witold; Lamentowicz, Mariusz

2014-10-01

Testate amoebae are an abundant and functionally important group of protists in peatlands, but little is known about the seasonal patterns of their communities. We investigated the relationships between testate amoeba diversity and community structure and water table depth and light conditions (shading vs. insolation) in a Sphagnum peatland in Northern Poland (Linje mire) in spring and summer 2010. We monitored the water table at five sites across the peatland and collected Sphagnum samples in lawn and hummock micro-sites around each piezometer, in spring (3 May) and mid-summer (6 August) 2010. Water table differed significantly between micro-sites and seasons (Kruskal-Wallis test, p=0.001). The community structure of testate amoebae differed significantly between spring and summer in both hummock and lawn micro-sites. We recorded a small, but significant drop in Shannon diversity, between spring and summer (1.76 vs. 1.72). Strongest correlations were found between testate amoeba communities and water table lowering and light conditions. The relative abundance of mixotrophic species Hyalosphenia papilio, Archerella flavum and of Euglypha ciliata was higher in the summer. Copyright © 2014 Elsevier GmbH. All rights reserved.

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2012–2013

USGS Publications Warehouse

Macy, Jamie P.; Truini, Margot

2016-03-02

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area. Precipitation in the area typically is between 6 and 14 inches per year.The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2012 to September 2013. The monitoring program includes measurements of (1) groundwater withdrawals, (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry.In calendar year 2012, total groundwater withdrawals were 4,010 acre-ft, industrial withdrawals were 1,370 acre-ft, and municipal withdrawals were 2,640 acre-ft. Total withdrawals during 2012 were about 45 percent less than total withdrawals in 2005 because of Peabody Western Coal Company’s discontinued use of water to transport coal in a coal slurry pipeline. From 2011 to 2012 total withdrawals decreased by 10 percent; industrial withdrawals decreased by approximately 1 percent, and total municipal withdrawals decreased by 15 percent.From 2012 to 2013, annually measured water levels in the Black Mesa area declined in 6 of 16 wells that were available for comparison in the unconfined areas of the N aquifer, and the median change was 0.8 feet. Water levels declined in 5 of 16 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was 0.3 feet. From the prestress period (prior to 1965) to 2013, the median water-level change for 34 wells in both the confined and unconfined areas was -13.5 feet; the median water-level changes were -0.8 feet for 16 wells measured in the unconfined areas and -51.0 feet for 16 wells measured in the confined area.Spring flow was measured at four springs in 2013; Burro, Unnamed Spring near Dennehotso, Moenkopi School, and Pasture Canyon Springs. Flow fluctuated during the period of record for Burro and Unnamed Springs near Dennehotso, but a decreasing trend was apparent at Moenkopi School Spring and Pasture Canyon Spring. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s and discharge at Unnamed Spring near Dennehotso has fluctuated for the period of record at each spring. Trend analysis for discharge at Moenkopi School and Pasture Canyon Springs showed a decreasing trend.Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2013), Dinnebito Wash near Sand Springs 09401110 (1993 to 2013), Polacca Wash near Second Mesa 09400568 (1994 to 2013), and Pasture Canyon Springs 09401265 (2004 to 2013). Median winter flows (November through February) from these sites for each water year were used as an index of the amount of groundwater discharge. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, which suggests no change in groundwater discharge.In 2013, water samples collected from 12 wells and 4 springs in the Black Mesa area were analyzed for selected chemical constituents, and the results were compared with previous analyses. Concentrations of dissolved solids, chloride, and sulfate have varied at all 12 wells for the period of record, but neither increasing nor decreasing trends over time were found. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 13 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied significantly since the early 1980s. Concentrations of dissolved solids, chloride, and sulfate at Burro Spring and Unnamed Spring near Dennehotso have varied for the period of record with no increasing or decreasing trend in the data.

Southwest Alaska Regional Geothermal Energy Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holdmann, Gwen

2015-04-30

The village of Elim, Alaska is 96 miles west of Nome, on the Seward Peninsula. The Darby Mountains north of the village are rich with hydrothermal systems associated with the Darby granitic pluton(s). In addition to the hot springs that have been recorded and studied over the last 100 years, additional hot springs exist. They are known through a rich oral history of the region, though they are not labeled on geothermal maps. This research primarily focused on Kwiniuk Hot Springs, Clear Creek Hot Springs and Molly’s Hot Springs. The highest recorded surface temperatures of these resources exist at Clearmore » Creek Hot Springs (67°C). Repeated water sampling of the resources shows that maximum temperatures at all of the systems are below boiling.« less

Microbial communities and arsenic biogeochemistry at the outflow of an alkaline sulfide-rich hot spring

PubMed Central

Jiang, Zhou; Li, Ping; Van Nostrand, Joy D.; Zhang, Ping; Zhou, Jizhong; Wang, Yanhong; Dai, Xinyue; Zhang, Rui; Jiang, Dawei; Wang, Yanxin

2016-01-01

Alkaline sulfide-rich hot springs provide a unique environment for microbial community and arsenic (As) biogeochemistry. In this study, a representative alkaline sulfide-rich hot spring, Zimeiquan in the Tengchong geothermal area, was chosen to study arsenic geochemistry and microbial community using Illumina MiSeq sequencing. Over 0.26 million 16S rRNA sequence reads were obtained from 5-paired parallel water and sediment samples along the hot spring’s outflow channel. High ratios of As(V)/AsSum (total combined arsenate and arsenite concentrations) (0.59–0.78), coupled with high sulfide (up to 5.87 mg/L), were present in the hot spring’s pools, which suggested As(III) oxidation occurred. Along the outflow channel, AsSum increased from 5.45 to 13.86 μmol/L, and the combined sulfide and sulfate concentrations increased from 292.02 to 364.28 μmol/L. These increases were primarily attributed to thioarsenic transformation. Temperature, sulfide, As and dissolved oxygen significantly shaped the microbial communities between not only the pools and downstream samples, but also water and sediment samples. Results implied that the upstream Thermocrinis was responsible for the transformation of thioarsenic to As(III) and the downstream Thermus contributed to derived As(III) oxidation. This study improves our understanding of microbially-mediated As transformation in alkaline sulfide-rich hot springs. PMID:27126380

Geohydrology and ground-water quality at selected sites in Meade County, Kentucky, 1987-88

USGS Publications Warehouse

Mull, D.S.; Alexander, A.G.; Schultz, P.E.

1989-01-01

Meade County in north-central Kentucky is about 305 sq mi in size, and is underlain by thick beds of limestone and dolomite which are the principal sources of drinking water for about 8 ,500 residents. About half the area contains mature, karst terrain with abundant sinkholes, springs, and caves. Because of this karst terrain, groundwater is susceptible to rapid changes in water quality and contamination from human sources. Thirty-seven wells and 12 springs were selected as sampling points to characterize groundwater quality in the area. Water was analyzed for major anions and cations, nitrates, trace elements, and organic compounds. Water from selected sites was also analyzed for fecal species of coliform streptococci bacteria and total coliform content. Except for fluoride and lead, the water quality was within the range expected for carbonate aquifers.The fluoride content was significantly higher in water from wells than in water from springs. Concentrations of detectable lead ranged from 10 to 50 micrograms/L and had a median value of 7.5 microg/L. Dissolved solids ranged from 100 to 2,200 mg/L and the median value was 512 mg/L. Hardness ranged from 20 to 1,100 mg/L and the median value was 290 mg/L. Organic compounds detected by the gas chromatographic/flame ionization detection scans, did not indicate evidence of concentrations in excess of the current Federal drinking water standards. Analysis for specific organic compounds indicated that the presence of these compounds was associated with agricultural chemicals, usually pesticides. Total coliform content exceeded drinking water standards in water from all 12 springs and in 18 wells. Statistical analysis of the groundwater quality data indicates that the variance of the concentrations of fluoride and chloride may be attributed to the site type. There was strong correlation between hardness and dissolved solids, hardness and sulfate, and sulfate and dissolved solids. No apparent relations were detected between water quality and the geographic location of sampling sites. However, seasonal variations were detected in the concentrations of dissolved solids, hardness, and iron. (Lantz-PTT)

Effects of urbanization on groundwater evolution in an urbanizing watershed

NASA Astrophysics Data System (ADS)

Reyes, D.; Banner, J. L.; Bendik, N.

2011-12-01

The Jollyville Plateau Salamander (Eurycea tonkawae), a candidate species for listing under the Endangered Species Act, is endemic to springs and caves within the Bull Creek Watershed of Austin, Texas. Rapid urbanization endangers known populations of this salamander. Conservation strategies lack information on the extent of groundwater contamination from anthropogenic sources in this karst watershed. Spring water was analyzed for strontium (Sr) isotopes and major ions from sites classified as "urban" or "rural" based on impervious cover estimates. Previous studies have shown that the 87Sr/86Sr value of municipal water is significantly higher than values for natural streamwater, which are similar to those for the Cretaceous limestone bedrock of the region's watersheds. We investigate the application of this relationship to understanding the effects of urbanization on groundwater quality. The use of Sr isotopes as hydrochemical tracers is complemented by major ion concentrations, specifically the dominant ions in natural groundwater (Ca and HCO3) and the ions associated with the addition of wastewater (Na and Cl). To identify high priority salamander-inhabited springs for water quality remediation, we explore the processes controlling the chemical evolution of groundwater such as municipal water inputs, groundwater-soil interactions, and solution/dissolution reactions. 87Sr/86Sr values for water samples from within the watershed range from 0.70760 to 0.70875, the highest values corresponding to sites located in the urbanized areas of the watershed. Analyses of the covariation of Sr isotopes with major ion concentrations help elucidate controls on spring water evolution. Springs located in rural portions of the watershed have low 87Sr/86Sr, high concentrations of Ca and HCO3, and low concentrations of Na and Cl. This is consistent with small inputs of municipal water. Three springs located in urban portions of the watershed have high 87Sr/86Sr, low Ca and HCO3, and high Na and Cl. This is consistent with large inputs of municipal water. The other five springs located in urban portions have low 87Sr/86Sr, low concentrations of Ca and HCO3, and high concentrations of Na and Cl. This is reflects a process other than an input of municipal water. Groundwater interaction with soils generally results in higher Na concentrations relative to Ca. 87Sr/86Sr values in this scenario may increase or decrease, depending on the Sr isotope variability of the local soils. Alternatively, precipitation of calcite from groundwater would decrease the concentration of Ca without necessarily decreasing 87Sr/86Sr values. The results suggest more anthropogenic water in urban springs than rural springs. These data serve to identify sources of spring recharge, including better constraints on the location(s) of urban leakage.

Assessing the Variability of Heavy Metal Concentrations in Liquid-Solid Two-Phase and Related Environmental Risks in the Weihe River of Shaanxi Province, China

PubMed Central

Song, Jinxi; Yang, Xiaogang; Zhang, Junlong; Long, Yongqing; Zhang, Yan; Zhang, Taifan

2015-01-01

Accurate estimation of the variability of heavy metals in river water and the hyporheic zone is crucial for pollution control and environmental management. The biotoxicities and potential ecological risks of heavy metals (Cu, Zn, Pb, Cd) in a solid-liquid two-phase system were estimated using the Geo-accumulation Index, Potential Ecological Risk Assessment and Quality Standard Index methods in the Weihe River of Shaanxi Province, China. Water and sediment samples were collected from five study sites during spring, summer and winter, 2013. The dominant species in the streambed sediments were chironomids and flutter earthworm, whose bioturbation mainly ranged from 0 to 20 cm. The concentrations of heavy metals in surface water and pore water varied obviously in spring and summer. The degrees of concentration of Cu and Cd in spring and summer were higher than the U.S. water quality Criteria Maximum Concentrations. Furthermore, the biotoxicities of Pb and Zn demonstrated season-spatial variations. The concentrations of Cu, Zn, Pb and Cd in spring and winter were significantly higher than those in summer, and the pollution levels also varied obviously in different layers of the sediments. Moreover, the pollution level of Cd was the most serious, as estimated by all three assessment methods. PMID:26193293

Water-quality, well-construction, and ground-water level data for an investigation of radionuclides in ground water, Hickman and Maury counties, Tennessee

USGS Publications Warehouse

Hileman, G.E.

1990-01-01

Water quality, well construction, and groundwater level data were collected for an investigation of radionuclides in groundwater in Maury and Hickman Counties, Tennessee. Seventeen wells and 3 springs were sampled in Hickman County, and 20 wells were sampled in Maury County. Samples from each site were analyzed for radionuclides, common and trace inorganic ions, indicators of redox conditions, selected nutrients, total organic carbon, and selected physical characteristics. Well-construction data were obtained to help determine the source of the water. Where possible, groundwater level measurements were made for each well sampled. Samples were collected from May 1989 through mid-August 1989. Data are presented in tables. Maps of each county show the location of the sites sampled. (USGS)

Stable isotope and noble gas constraints on the source and residence time of spring water from the Table Mountain Group Aquifer, Paarl, South Africa and implications for large scale abstraction

NASA Astrophysics Data System (ADS)

Miller, J. A.; Dunford, A. J.; Swana, K. A.; Palcsu, L.; Butler, M.; Clarke, C. E.

2017-08-01

Large scale groundwater abstraction is increasingly being used to support large urban centres especially in areas of low rainfall but presents particular challenges in the management and sustainability of the groundwater system. The Table Mountain Group (TMG) Aquifer is one of the largest and most important aquifer systems in South Africa and is currently being considered as an alternative source of potable water for the City of Cape Town, a metropolis of over four million people. The TMG aquifer is a fractured rock aquifer hosted primarily in super mature sandstones, quartzites and quartz arenites. The groundwater naturally emanates from numerous springs throughout the cape region. One set of springs were examined to assess the source and residence time of the spring water. Oxygen and hydrogen isotopes indicate that the spring water has not been subject to evaporation and in combination with Na/Cl ratios implies that recharge to the spring systems is via coastal precipitation. Although rainfall in the Cape is usually modelled on orographic rainfall, δ18O and δ2H values of some rainfall samples are strongly positive indicating a stratiform component as well. Comparing the spring water δ18O and δ2H values with that of local rainfall, indicates that the springs are likely derived from continuous bulk recharge over the immediate hinterland to the springs and not through large and/or heavy downpours. Noble gas concentrations, combined with tritium and radiocarbon activities indicate that the residence time of the TMG groundwater in this area is decadal in age with a probable maximum upper limit of ∼40 years. This residence time is probably a reflection of the slow flow rate through the fractured rock aquifer and hence indicates that the interconnectedness of the fractures is the most important factor controlling groundwater flow. The short residence time of the groundwater suggest that recharge to the springs and the Table Mountain Group Aquifer as a whole is vulnerable to climate change and reductions in regional precipitation. Any plans for large scale abstraction to supplement the City of Cape Town water supply would need to factor this into models of maximum sustainable yield.

Preliminary assessment of water chemistry related to groundwater flooding in Wawarsing, New York, 2009-11

USGS Publications Warehouse

Brown, Craig J.; Eckhardt, David A.; Stumm, Frederick; Chu, Anthony

2012-01-01

Water-quality samples collected in an area prone to groundwater flooding in Wawarsing, New York, were analyzed and assessed to better understand the hydrologic system and to aid in the assessment of contributing water sources. Above average rainfall over the past decade, and the presence of a pressurized water tunnel that passes about 700 feet beneath Wawarsing, could both contribute to groundwater flooding. Water samples were collected from surface-water bodies, springs, and wells and analyzed for major and trace inorganic constituents, dissolved gases, age tracers, and stable isotopes. Distinct differences in chemistry exist between tunnel water and groundwater in unconsolidated deposits and in bedrock, and among groundwater samples collected from some bedrock wells during high head pressure and low head pressure of the Rondout-West Branch Tunnel. Samples from bedrock wells generally had relatively higher concentrations of sulfate (SO42-), strontium (Sr), barium (Ba), and lower concentrations of calcium (Ca) and bicarbonate (HCO3-), as compared to unconsolidated wells. Differences in stable-isotope ratios among oxygen-18 to oxygen-16 (δ18O), hydrogen-2 to hydrogen-1 (δ2H), sulfur-34 to sulfur-32(δ34S) of SO42-, Sr-87 to Sr-86 (87Sr/86Sr), and C-13 to C-12 (δ13C) of dissolved inorganic carbon (DIC) indicate a potential for distinguishing water in the Delaware-West Branch Tunnel from native groundwater. For example, 87Sr/86Sr ratios were more depleted in groundwater samples from most bedrock wells, as compared to samples from surface-water sources, springs, and wells screened in unconsolidated deposits in the study area. Age-tracer data provided useful information on pathways of the groundwater-flow system, but were limited by inherent problems with dissolved gases in bedrock wells. The sulfur hexafluoride (SF6) and (or) chlorofluorocarbons (CFCs) apparent recharge years of most water samples from wells screened in unconsolidated deposits and springs ranged from 2003 to 2010 (current) and indicate short flow paths from the point of groundwater recharge. All but three of the samples from bedrock wells had interference problems with dissolved gases, mainly caused by excess air from degassing of hydrogen sulfide and methane. The SF6 and (or) CFC apparent recharge years of samples from three of the bedrock wells ranged from the 1940s to the early 2000s; the sample with the early 2000s recharge year was from a flowing artesian well that was chemically similar to water samples collected at the influent to the tunnel at Rondout Reservoir and the most hydraulically responsive to water tunnel pressure compared to other bedrock wells. Data described in this report can be used, together with hydrogeologic data, to improve the understanding of source waters and groundwater-flow patterns and pathways, and to help assess the mixing of different source waters in water samples. Differences in stable isotope ratios, major and trace constituent concentrations, saturation indexes, tritium concentrations, and apparent groundwater ages will be used to estimate the proportion of water that originates from Rondout-West Branch Tunnel leakage.

Chemical Source Tracking of Bacterial Contamination Using Micropollutants - A Karst Aquifer Case Study

NASA Astrophysics Data System (ADS)

Zirlewagen, Johannes; Hillebrand, Olav; Nödler, Karsten; Licha, Tobias; Schiperski, Ferry; Stange, Claudia; Tiehm, Andreas; Scheytt, Traugott

2015-04-01

Karst aquifers are important drinking water resources in many parts of the world, though they are well known for their high vulnerability to contamination. Rainfall and snowmelt often trigger temporary contamination of karst water resources. Free-range animal breeding and application of manure on the one hand and sewage leakage or spillage on the other hand are usually regarded as main sources for fecal contamination. But distinction of their respective contributions is difficult. This study investigates the feasibility to track the origin of fecal contamination from the occurrences of indicator bacteria and chemical source indicators in karst spring water. The study site is the 45 km² rural catchment of the perennial karst spring Gallusquelle in SW-Germany (mean discharge: 0.5 m³/s). Overflow events of a stormwater detention basin (combined sewer system) are known to impact water quality at the spring. There is no free-range animal breeding in the catchment but intense application of manure. Following two heavy rainfall events with overflow of the stormwater detention basin, spring water was sampled over several days. Samples were analysed for indicator bacteria (total Coliform, E. coli, Enterococci) and 57 micropollutants, among them cyclamate and metazachlor. For the Gallusquelle catchment the artificial sweetener cyclamate and the herbicide metazachlor have been established as source specific indicators, the former for the sewer system and the latter for cropland. Though recharge in the Gallusquelle catchment is predominantly diffuse, there is a significant portion of direct recharge reflected by distinct breakthrough curves for cyclamate and metazachlor. The breakthrough of indicator bacteria coincides very well with the occurrence of both, cyclamate and metazachlor. However, indicator bacteria cannot be unambiguously tracked back to a specific source.

The source, discharge, and chemical characteristics of water from Agua Caliente Spring, Palm Springs, California

USGS Publications Warehouse

Brandt, Justin; Catchings, Rufus D.; Christensen, Allen H.; Flint, Alan L.; Gandhok, Gini; Goldman, Mark R.; Halford, Keith J.; Langenheim, V.E.; Martin, Peter; Rymer, Michael J.; Schroeder, Roy A.; Smith, Gregory A.; Sneed, Michelle; Martin, Peter

2011-01-01

Agua Caliente Spring, in downtown Palm Springs, California, has been used for recreation and medicinal therapy for hundreds of years and currently (2008) is the source of hot water for the Spa Resort owned by the Agua Caliente Band of the Cahuilla Indians. The Agua Caliente Spring is located about 1,500 feet east of the eastern front of the San Jacinto Mountains on the southeast-sloping alluvial plain of the Coachella Valley. The objectives of this study were to (1) define the geologic structure associated with the Agua Caliente Spring; (2) define the source(s), and possibly the age(s), of water discharged by the spring; (3) ascertain the seasonal and longer-term variability of the natural discharge, water temperature, and chemical characteristics of the spring water; (4) evaluate whether water-level declines in the regional aquifer will influence the temperature of the spring discharge; and, (5) estimate the quantity of spring water that leaks out of the water-collector tank at the spring orifice.

Hydrological and geochemical processes constraining groundwater salinity in wetland areas related to evaporitic (karst) systems. A case study from Southern Spain

NASA Astrophysics Data System (ADS)

Gil-Márquez, J. M.; Barberá, J. A.; Andreo, B.; Mudarra, M.

2017-01-01

Chemical and isotopic evolution of groundwater in an evaporite karst plateau (including wetland areas and saline to hyper-saline springs) located at S Spain was studied. Physicochemical parameters, major ions and stable isotopes were analyzed in rain, brine spring, wetland and leakage water samples, from which the most common mineral saturation indexes were computed and geochemical and isotopic modelling were performed. Results show an apparent relationship between the elevation of brine springs and their water mineralization, indicating that drainage at higher altitude may be associated to gravity-driven flows, since brackish groundwater is isotopically fractionated due to evaporation. On the other hand, the lower altitude springs could drain deeper flows with longer residence time, resulting in highly mineralized and warmer (briny) groundwater. The dissolution of halite and gypsum has proved to be the main geochemical processes, which are favored by the great ionic strength of groundwater. Calcite precipitation occurs in brackish waters draining wetlands, being boosted by common ion effect (when CaSO4 waters are present) and solute concentration caused by evaporation. Modelling results strongly support the hypothesis that most of the selected springs geochemically evolve in a common (S-N) flowpath. The methods used in this research contribute to a better understanding of the hydrogeological processes occurring in the studied evaporitic system, but also in equivalent hydrological environments worldwide.

Meiofaunal Richness in Highly Acidic Hot Springs in Unzen-Amakusa National Park, Japan, Including the First Rediscovery Attempt for Mesotardigrada.

PubMed

Suzuki, Atsushi C; Kagoshima, Hiroshi; Chilton, Glen; Grothman, Gary T; Johansson, Carl; Tsujimoto, Megumu

2017-02-01

Extreme environments sometimes support surprisingly high meiofaunal diversity. We sampled runoff from the acidic hot springs of Unzen, Japan. This is the type locality of Thermozodium esakii Rahm, 1937, the only tardigrade in the class Mesotardigrada, which remains contentious in the absence of corroboration or supporting specimens. Our sampling revealed at least three species of arthropods, four rotifers, and five nematodes living in the hot (ca. 40°C) and acidic (ca. pH 2.5) water, but no tardigrades.

Late quaternary history and uranium isotopic compositions of ground water discharge deposits, Crater Flat, Nevada

USGS Publications Warehouse

Paces, James B.; Taylor, Emily M.; Bush, Charles

1993-01-01

Three carbonate-rich spring deposits are present near the southern end of Crater Flat, NV, approximately 18 km southwest of the potential high-level waste repository at Yucca Mountain. We have analyzed five samples of carbonate-rich material from two of the deposits for U and Th isotopic compositions. Resulting U-series disequilibrium ages indicate that springs were active at 18 ?? 1, 30 ?? 3, 45 ?? 4 and >70 ka. These ages are consistent with a crude internal stratigraphy at one site. Identical ages for two samples at two separate sites suggest that springs were contemporaneous, at least in part, and were most likely part of the same hydrodynamic system. In addition, initial U isotopic compositions range from 2.8 to 3.8 and strongly suggest that ground water from the regional Tertiary-volcanic aquifer provided the source for these hydrogenic deposits. This interpretation, along with water level data from near-by wells suggest that the water table rose approximately 80 to 115 m above present levels during the late Quaternary and may have fluctuated repeatedly. Current data are insufficient to allow reconstruction of a detailed depositional history, however geochronological data are in good agreement with other paleoclimatic proxy records preserved throughout the region. Since these deposits are down gradient from the potential repository site, the possibility of higher ground water levels in the future dramatically shortens both vertical and lateral ground water pathways and reduces travel times of transported radionuclides to potential discharge sites.

Bioaccumulation of selenium by the Bryophyte Hygrohypnum ochraceum in the Fountain Creek Watershed, Colorado.

PubMed

Herrmann, S J; Turner, J A; Carsella, J S; Lehmpuhl, D W; Nimmo, D R

2012-12-01

Aquatic bryophytes, Hygrohypnum ochraceum, were deployed "in situ" at 14 sites in the Fountain Creek Watershed, spring and fall, 2007 to study selenium (Se) accumulation. Dissolved, total, and pore (sediment derived) water samples were collected and water quality parameters determined while plants were exposed to the water for 10 days. There was a trend showing plant tissue-Se uptake with distance downstream and we found a strong correlation between Se in the water with total hardness in both seasons. There was a modest association between Se-uptake in plants with hardness in the spring of 2007 but not the fall. Plants bioconcentrated Se from the water by a factor of 5.8 × 10(3) at Green Mountain Falls and 1.5 × 10(4) at Manitou Springs in the fall of 2007. Both are examples of the bioconcentration abilities of the plants, primarily in the upper reaches of the watershed where bioconcentration factors were highest. However, the mean minima and maxima of Se in the plants in each of the three watershed segments appeared similar during both seasons. We found direct relationships between the pore and dissolved Se in water in the spring (R (2) = 0.84) and fall (R (2) = 0.95) and dissolved Se and total hardness in the spring and fall (R (2) = 0.92). The data indicate that H. ochraceum was a suitable indicator of Se bioavailability and Se uptake in other trophic levels in the Fountain Creek Watershed based on a subsequent study of Se accumulation in fish tissues at all 14 sites.

Associations among pathogenic bacteria, parasites, and environmental and land use factors in multiple mixed-use watersheds.

PubMed

Wilkes, G; Edge, T A; Gannon, V P J; Jokinen, C; Lyautey, E; Neumann, N F; Ruecker, N; Scott, A; Sunohara, M; Topp, E; Lapen, D R

2011-11-15

Over a five year period (2004-08), 1171 surface water samples were collected from up to 24 sampling locations representing a wide range of stream orders, in a river basin in eastern Ontario, Canada. Water was analyzed for Cryptosporidium oocysts and Giardia cyst densities, the presence of Salmonella enterica subspecies enterica, Campylobacter spp., Listeria monocytogenes, and Escherichia coli O157:H7. The study objective was to explore associations among pathogen densities/occurrence and objectively defined land use, weather, hydrologic, and water quality variables using CART (Classification and Regression Tree) and binary logistical regression techniques. E. coli O157:H7 detections were infrequent, but detections were related to upstream livestock pasture density; 20% of the detections were located where cattle have access to the watercourses. The ratio of detections:non-detections for Campylobacter spp. was relatively higher (>1) when mean air temperatures were 6% below mean study period temperature values (relatively cooler periods). Cooler water temperatures, which can promote bacteria survival and represent times when land applications of manure typically occur (spring and fall), may have promoted increased frequency of Campylobacter spp. Fifty-nine percent of all Salmonella spp. detections occurred when river discharge on a branch of the river system of Shreve stream order = 9550 was >83 percentile. Hydrological events that promote off farm/off field/in stream transport must manifest themselves in order for detection of Salmonella spp. to occur in surface water in this region. Fifty seven percent of L. monocytogenes detections occurred in spring, relative to other seasons. It was speculated that a combination of winter livestock housing, silage feeding during winter, and spring application of manure that accrued during winter, contributed to elevated occurrences of this pathogen in spring. Cryptosporidium and Giardia oocyst and cyst densities were, overall, positively associated with surface water discharge, and negatively associated with air/water temperature during spring-summer-fall. Yet, some of the highest Cryptosporidium oocyst densities were associated with low discharge conditions on smaller order streams, suggesting wildlife as a contributing fecal source. Fifty six percent of all detections of ≥ 2 bacteria pathogens (including Campylobacter spp., Salmonella spp., and E. coli O157:H7) in water was associated with lower water temperatures (<∼ 14 °C; primarily spring and fall) and when total rainfall the week prior to sampling was >∼ 27 mm (62 percentile). During higher water temperatures (>∼ 14 °C), a higher amount of weekly rainfall was necessary to promote detection of ≥ 2 pathogens (primarily summer; weekly rainfall ∼>42 mm (>77 percentile); 15% of all ≥ 2 detections). Less rainfall may have been necessary to mobilize pathogens from adjacent land, and/or in stream sediments, during cooler water conditions; as these are times when manures are applied to fields in the area, and soil water contents and water table depths are relatively higher. Season, stream order, turbidity, mean daily temperature, surface water discharge, cropland coverage, and nearest upstream distance to a barn and pasture were variables that were relatively strong and recurrent with regard to discriminating pathogen presence and absence, and parasite densities in surface water in the region. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved.

Noble gas isotopes in mineral springs within the Cascadia Forearc, Wasihington and Oregon

USGS Publications Warehouse

McCrory, Patricia A.; Constantz, James E.; Hunt, Andrew G.

2014-01-01

This U.S. Geological Survey report presents laboratory analyses along with field notes for a pilot study to document the relative abundance of noble gases in mineral springs within the Cascadia forearc of Washington and Oregon. Estimates of the depth to the underlying Juan de Fuca oceanic plate beneath the sample sites are derived from the McCrory and others (2012) slab model. Some of these springs have been previously sampled for chemical analyses (Mariner and others, 2006), but none currently have publicly available noble gas data. Helium isotope values as well as the noble gas values and ratios presented below will be used to determine the sources and mixing history of these mineral waters.

Data on ground-water quality in the Carson River basin, western Nevada and eastern California, 1987-90

USGS Publications Warehouse

Whitney, Rita

1994-01-01

The U.S. Geological Survey collected and analyzed water samples from June 1987 through February 1990 as part of a study of the ground-water quality in the Carson River Basin. The Carson River Basin is one of seven national pilot projects conducted by the Geological Survey as part of a National Water-Quality Assessment Program. The data from the sampling program include analyses of 110 different constituents and properties of ground water in 400 separate samplings of 230 domestic, public-supply, irrigation, and shallow monitoring wells and one spring. The water-quality data include: field measurements, major constituents, nutrients, minor constituents, radionuclides, stable isotopes, and synthetic organic compounds.

GREENROOF RUNOFF WATER QUALITY

EPA Science Inventory

Runoff samples were collected from 5 experimental green roof test plots on small buildings at the Center for Green Roof Research at Rock Springs, PA during the period from January 2005 through May 2006. Samples were either analyzed in-house for pH, Electrical Conductivity (EC), T...

Groundwater flow and potential effects on evaporite dissolution in the Paradox Basin, SE Utah

NASA Astrophysics Data System (ADS)

Reitman, N.; Ge, S.; Mueller, K. J.

2012-12-01

A hydrogeologic study was conducted in the portion of the Paradox Basin south of the Needles District of Canyonlands National Park, Utah. Geology of the study area comprises fractured and faulted Paleozoic sandstone, limestone, and shale, which are underlain by evaporite cycles of the Paradox Formation. The evaporite deposits deform and dissolve when they come in contact with groundwater, generating land subsidence, saline groundwater, and salt input to the Colorado River. Active faults in the region slip at a rate of approximately 2 mm/year, likely due to evaporite dissolution. The objective of this study is to better understand groundwater flow and solute transport dynamics and to help determine the rate and timing of subsurface salt dissolution, which is an important control on the salt tectonics in the region. Study methods include hydrologic fieldwork, laboratory tests, and numerical modeling. No groundwater wells exist in the study area. Water samples from springs and seeps were collected throughout the study area. Analysis of total dissolved solids (TDS), stable oxygen (δ18O) and deuterium (δD) isotopes, spring and seep locations, and prior data are used to gain a preliminary understanding of the shallow groundwater flow in the region. Stable isotope ratios of oxygen (18O/16O) and deuterium (D/H) are used to constrain the source of spring water. Measured δ values are compared to predicted δ values for precipitation from WaterIsotopes.org for each sample site. Measured isotopic values range from -14.9 ‰ to -10.7 ‰ for δ18O and -108 ‰ to -78 ‰ for δD. The majority of samples from above 2000 m match predicted isotopic values for precipitation. Most samples taken below 2000 m are lighter than predicted isotopic values for precipitation. The TDS of spring samples measured in the lab show they range from 184 mg/L to 1552 mg/L with the majority of samples between 220 - 430 mg/L. TDS shows a weak correlation (R2 = 0.54) with altitude, where lower TDS is measured in higher altitude samples. These measurements are consistent with high altitude samples representing precipitation and low altitude samples representing shallow groundwater. Location and altitude of springs sampled in this study, as well as those recorded by earlier studies, were used to create a potentiometric surface map in GIS. From the map, water flow direction is inferred to flow mostly from the Abajo Mountains in the southeast towards the Colorado River in the northwest. A transient groundwater flow and solute transport model is developed for a 2-D cross section from the Abajo Mountains in the SE to the Colorado River in the NW. Recharge is applied in the southeast, driving water flow towards the northwest. Most discharge flows into the Colorado River, primarily via seepage through cliff faces. Surface discharge occurs in topographic lows. The flow and solute concentration patterns from the model are generally consistent with field data. Evaporite dissolution varies laterally depending on groundwater flow pattern. Deep groundwater flow patterns and pore pressure data from the model will contribute to an understanding of subsurface salt dissolution and active salt tectonics in the study region. Additionally, the results of this study will help land and water managers protect scarce freshwater resources in this arid desert region.

The origin of groundwater in Zhangye Basin, northwestern China, using isotopic signature

NASA Astrophysics Data System (ADS)

Chen, Jiansheng; Liu, Xiaoyan; Sun, Xiaoxu; Su, Zhiguo; Yong, Bin

2014-03-01

Zhangye Basin, in arid northwestern China, has recently been repeatedly flooded by rising groundwater. Isotope signatures of sampled waters gained insight into the recharge source of the groundwater. The summer Heihe River water and most of the spring water in Zhangye and Yongchang basins plotted above the global meteoric water line (GMWL) on the δ18O-δD plot. The spring water had R/Ra ratio >1, low TDS and high tritium, which indicates origin from Qilian Mountain glacier meltwater. The groundwater of Qilian Mountains was transported to the Hexi Corridor (in which Zhangye Basin is located) through underground fault zones. Additionally, some of the groundwater in the alluvial plain, and all spring water surrounding Zhangye Basin, plotted below the GMWL on the δ18O-δD plot along an evaporation line, and had R/Ra ratio < 1 and high TDS. It is proposed that the Tibetan rivers or lakes source the Hexi Corridor groundwater through either the NE-trending or NW-trending buried fault zones. The isotopic signatures presented as part of this study rule out the conventional viewpoint that groundwater of the Zhangye Basin was recharged by local precipitation and infiltration of Heihe River water on the alluvial plain.

Geohydrology, geochemistry, geothermal potency of Rianiate Toba Lake North Sumatera

NASA Astrophysics Data System (ADS)

Nainggolan, Juliper; Sitepu, Cristin; Pardede, Sanggam; Diantoro, Markus

2017-09-01

This research was performed to determine the potency of Rianiate’s geothermal an alternative of energy source and determine the types of geothermal that was begun with the position’s measurement by using GPS (Global Position System), and then the direct observation of chemical and physical properties such as pH, surface’s temperature, color etc. The following steps were taking sample in four different springs indicated by spring 1, spring 2, spring 3, and spring 4. The chemical nature was measured by titrimetry method by using AAS, XRD, and gas Chromathology. The calculating of temperature of subsurface has done by using geothermometer and sequentially followed by geothermal potency’s calculation. The position of four springs are located about N: 02° 31,852’ and E: 098° 44. 021’ where were average height from sea’s level is 958 m. The highest surface’s temperature is 80 °C and the temperature under soil is about 130.5 °C described the average of geothermal. The calculation of content of chloride, sulfate, bicarbonations revealed that the water can be categorized as chloride type. The trilateral diagram Na/1000 - K/100 - √Mg of hot water is in the regime of immature water. From the calculation of Indonesia’s Standardized Geotherm, it was obtained that the estimated reservoir potency of Rianiate geotherm is 2,68 MWe.

Water-quality reconnaissance and streamflow gain and loss of Yocum Creek basin, Carroll County, Arkansas

USGS Publications Warehouse

Joseph, Robert L.; Green, W. Reed

1994-01-01

A study of the Yocum Creek Basin conducted between July 27 and August 3, 1993, described the surface- and ground-water quality of the basin and the streamflow gain and loss. Water samples were collected from 12 sites on the main stem of Yocum Creek and 2 tributaries during periods of low to moderate streamflow (less than 40 cubic feet per second). Water samples were collected from 5 wells and 12 springs located in the basin. In 14 surface- water samples, nitrite plus nitrate concentrations ranged from 1.3 to 3.8 milligrams per liter as nitrogen. Orthophosphorus concentrations ranged from 0.01 to 0.06 milligrams per liter as phosphorous. Fecal coliform bacteria counts ranged from 9 to 220 colonies per 100 milliliters, with a median of 49 colonies per 100 milliliters. Fecal streptococci bacteria counts ranged from 37 to 1,500 colonies per 100 milliliters with a median of 420 colonies per 100 milliliters. Analyses for selected metals collected near the mouth of Yocum Creek indicate that metals are not present in significant concen- trations in surface-water samples. Diel dissolved oxygen concentrations and temperatures were measured at two sites on the mainstem of the stream. At the upstream site, dissolved oxygen concentrations ranged from 6.2 to 9.9 milligrams per liter and temperatures ranged from 18.5 to 23.0 degrees Celsius. Dissolved oxygen concentrations were higher and tempentture values were lower at the upstream site than those at the downstream site. Five wells were sampled in the basin and dissolved ammonia was present in concentrations ranging from 0.01 to 0.07 milligrams per liter as nitrogen. Dissolved nitrite plus nitrate was present in wells, with concen- trations ranging from less than 0.02 to 6.0 milligrams per liter as nitrogen. Volatile organic compound samples were collected at two wells and two springs. Chloroform was the only volatile organic compound found to be above the detection limit. Analysis indicated that 0.2 micrograms per liter of chloroform was present in one spring-water sample. In springs sampled, nitrite plus nitrate concen- trations ranged from 1.4 to 7.0 milligrams per llter as nitrogen. Dissolved ammonia plus organic nitrogen concentrations ranged from less than 0.2 to 0.49 milligrams per liter as nitrogen. Orthophosphorus concentrations ranged from 0.01 to 0.07 milligrams per liter as phosphorus. Fecal colfform bacteria counts ranged from 3 to 200 colonies per 100 milliliters, with a median of 18 colonies per 100 milliliters. Fecal streptococci bacteria counts ranged from 110 to more than 2,000 colonies per 100 milliliters with a median of 350 colonies per 100 milliliters. Large producing springs 1ocated in the mid to upper reaches of the basin contribute most of the flow to Yocum Creek. Streamflow increased an average of 29 percent on the mainstem of the stream. One losing reach was discovered on the mainstem of the stream and two losing reaches on tributaries to the mainstem. Surface flow steadily decreased along these reaches to the point where surface flow was not present, and the streambed became dry. These observations suggest that significant interaction exists between the underlying Springfield aquifer and surface flow in the Yocum Creek Basin.

The Growing Season, but Not the Farming System, Is a Food Safety Risk Determinant for Leafy Greens in the Mid-Atlantic Region of the United States

PubMed Central

Marine, Sasha C.; Pagadala, Sivaranjani; Wang, Fei; Pahl, Donna M.; Melendez, Meredith V.; Kline, Wesley L.; Oni, Ruth A.; Walsh, Christopher S.; Everts, Kathryne L.; Buchanan, Robert L.

2015-01-01

Small- and medium-size farms in the mid-Atlantic region of the United States use varied agricultural practices to produce leafy greens during spring and fall, but the impact of preharvest practices on food safety risk remains unclear. To assess farm-level risk factors, bacterial indicators, Salmonella enterica, and Shiga toxin-producing Escherichia coli (STEC) from 32 organic and conventional farms were analyzed. A total of 577 leafy greens, irrigation water, compost, field soil, and pond sediment samples were collected. Salmonella was recovered from 2.2% of leafy greens (n = 369) and 7.7% of sediment (n = 13) samples. There was an association between Salmonella recovery and growing season (fall versus spring) (P = 0.006) but not farming system (organic or conventional) (P = 0.920) or region (P = 0.991). No STEC was isolated. In all, 10% of samples were positive for E. coli: 6% of leafy greens, 18% of irrigation water, 10% of soil, 38% of sediment, and 27% of compost samples. Farming system was not a significant factor for levels of E. coli or aerobic mesophiles on leafy greens but was a significant factor for total coliforms (TC) (P < 0.001), with higher counts from organic farm samples. Growing season was a factor for aerobic mesophiles on leafy greens (P = 0.004), with higher levels in fall than in spring. Water source was a factor for all indicator bacteria (P < 0.001), and end-of-line groundwater had marginally higher TC counts than source samples (P = 0.059). Overall, the data suggest that seasonal events, weather conditions, and proximity of compost piles might be important factors contributing to microbial contamination on farms growing leafy greens. PMID:25616798

A preliminary assessment of the occurrence and possible sources of MTBE in ground water of the United States, 1993-94

USGS Publications Warehouse

Squillace, P.J.

1995-01-01

The 1990 Clean Air Act Amendments require fuel oxygenates to be added to gasoline used in some metropolitan areas to reduce atmospheric concen- trations of carbon monoxide or ozone. Methyl tert-butyl ether (MTBE), is the most commonly used fuel oxygenate and is a relatively new gasoline additive. Nevertheless, out of 60 volatile organic chemicals analyzed, MTBE was the second most frequently detected chemical in samples of shallow ambient ground water from urban areas that were collected during 1993-94 as part of the U.S. Geological Survey's National Water-Quality Assessment program. Samples were collected from 5 drinking-water wells, 12 springs, and 193 monitoring wells in urban areas. No MTBE was detected in drinking-water wells. At a reporting level of 0.2 ug/L (micrograms per liter), MTBE was detected most frequently in shallow ground water from urban areas (27 percent of 210 wells and springs sampled in 8 areas) as compared to shallow ground water from agricultural areas (1.3 percent of 549 wells sampled in 21 areas) or deeper ground water from major aquifers (1 percent of 412 wells sampled in 9 areas). Only 3 percent of the shallow wells sampled in urban areas had concentrations of MTBE that exceed 20 ug/L, which is the estimated lower limit of the U.S. Environmental Protection Agency draft drinking-water health advisory. Because MTBE is persistent and mobile in ground water, it can move from shallow to deeper aquifers with time. In shallow urban ground water, MTBE generally was not found with benzene, toluene, ethylbenzene, or xylenes (BTEX) compounds which commonly are associated with gasoline spills. This disassociation causes uncertainty as to the source of MTBE. Possible sources of MTBE in ground water include point sources, such as leaking storage tanks, and nonpoint sources, such as recharge of precipitation and storm-water runoff.

Estimating nitrate concentrations in groundwater at selected wells and springs in the surficial aquifer system and Upper Floridan aquifer, Dougherty Plain and Marianna Lowlands, Georgia, Florida, and Alabama, 2002-50

USGS Publications Warehouse

Crandall, Christy A.; Katz, Brian G.; Berndt, Marian P.

2013-01-01

Groundwater from the surficial aquifer system and Upper Floridan aquifer in the Dougherty Plain and Marianna Lowlands in southwestern Georgia, northwestern Florida, and southeastern Alabama is affected by elevated nitrate concentrations as a result of the vulnerability of the aquifer, irrigation water-supply development, and intensive agricultural land use. The region relies primarily on groundwater from the Upper Floridan aquifer for drinking-water and irrigation supply. Elevated nitrate concentrations in drinking water are a concern because infants under 6 months of age who drink water containing nitrate concentrations above the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter as nitrogen can become seriously ill with blue baby syndrome. In response to concerns about water quality in domestic wells and in springs in the lower Apalachicola–Chattahoochee–Flint River Basin, the Florida Department of Environmental Protection funded a study in cooperation with the U.S. Geological Survey to examine water quality in groundwater and springs that provide base flow to the Chipola River. A three-dimensional, steady-state, regional-scale groundwater-flow model and two local-scale models were used in conjunction with particle tracking to identify travel times and areas contributing recharge to six groundwater sites—three long-term monitor wells (CP-18A, CP-21A, and RF-41) and three springs (Jackson Blue Spring, Baltzell Springs Group, and Sandbag Spring) in the lower Apalachicola–Chattahoochee–Flint River Basin. Estimated nitrate input to groundwater at land surface, based on previous studies of nitrogen fertilizer sales and atmospheric nitrate deposition data, were used in the advective transport models for the period 2002 to 2050. Nitrate concentrations in groundwater samples collected from the six sites during 1993 to 2007 and groundwater age tracer data were used to calibrate the transport aspect of the simulations. Measured nitrate concentrations (as nitrogen) in wells and springs sampled during the study ranged from 0.37 to 12.73 milligrams per liter. Average apparent ages of groundwater calculated from measurements of chlorofluorocarbon, sulfur hexafluoride, and tritium from wells CP-18A, CP-21A,and RF-41 were about 23, 29, and 32 years, respectively. Average apparent ages of groundwater from Baltzell Springs Group, Sandbag Spring, and Jackson Blue Spring were about 16, 18, and 19 years, respectively. Simulated travel times of particles from the six selected sites ranged from less than 1 day to 511 years; both the minimum and maximum particle travel times were estimated for water from Jackson Blue Spring. Median simulated travel times of particles were about 30, 38, and 62 years for Jackson Blue Spring, Sandbag Spring, and Baltzell Springs Group, respectively. Study results indicated that travel times for approximately 50 percent of the particles from all spring sites were less than 50 years. The median simulated travel times of particles arriving at receptor wells CP-18A, CP-21A, and RF-41 were about 50, 35, and 36 years, respectively. All particle travel times were within the same order of magnitude as the tracer-derived average apparent ages for water, although slightly older than the measured ages. Travel time estimates were substantially greater than the measured age for groundwater reaching well CP-18A, as confirmed by the average apparent age of water determined from tracers. Local-scale particle-tracking models were used to predict nitrate concentrations in the three monitor wells and three springs from 2002 to 2050 for three nitrogen management scenarios: (1) fixed input of nitrate at the 2001 level, (2) reduction of nitrate inputs of 4 percent per year (from the previous year) from 2002 to 2050, and (3) elimination of nitrate input after 2001. Simulated nitrate concentrations in well CP-21A peaked at 7.82 milligrams per liter in 2030, and concentrations in background well RF-41 peaked at 1.10 milligrams per liter in 2020. The simulated particle travel times were longer than indicated by age dating analysis for groundwater in well CP-18A; to account for the poor calibration fit at this well, nitrate concentrations were shifted 21 years. With the shift, simulated nitrate concentrations in groundwater at CP-18A peaked at 13.76 milligrams per liter in 2026. For groundwater in Baltzell Springs Group, Jackson Blue Spring, and Sandbag Spring, simulated nitrate concentrations peaked at 3.77 milligrams per liter in 2006, 3.51 milligrams per liter in 2011, and 0.81 milligram per liter in 2018, respectively, under the three management scenarios. In management scenario 3 (elimination of nitrate input after 2001), simulated nitrate concentrations in Baltzell Springs Group decreased to less than background concentrations (0.10 milligram per liter) by 2033, and in Sandbag Spring concentrations decreased to less than background by 2041. Simulations using nitrate management scenarios 1 (fixed input of nitrate at 2001 levels) and 2 (reduction of 4.0 percent per year) indicate that nitrate concentrations in groundwater may remain above background concentrations through 2050 at all sites.

Seasonal and longitudinal distributions of atmospheric water-soluble dicarboxylic acids, oxocarboxylic acids, and α-dicarbonyls over the North Pacific

NASA Astrophysics Data System (ADS)

Bikkina, Srinivas; Kawamura, Kimitaka; Imanishi, Katsuya; Boreddy, S. K. R.; Nojiri, Yukihiro

2015-05-01

In order to assess the seasonal variability of atmospheric abundances of dicarboxylic acids, oxocarboxylic acids, and α-dicarbonyls over the North Pacific and Sea of Japan, aerosol samples were collected along the longitudinal transacts during six cruises between Canada and Japan. The back trajectory analyses indicate that aerosol samples collected in winter and spring are influenced by the East Asian outflow, whereas summer and fall samples are associated with the pristine maritime air masses. Molecular distributions of water-soluble organics in winter and spring samples show the predominance of oxalic acid (C2) followed by succinic (C4) and malonic acids (C3). In contrast, summer and fall marine aerosols are characterized by the predominance of C3 over C4. Concentrations of dicarboxylic acids were higher over the Sea of Japan than the North Pacific. With a lack of continental outflow, higher concentrations during early summer are ascribed to atmospheric oxidation of organic precursors associated with high biological activity in the North Pacific. This interpretation is further supported by the high abundances of azelaic acid, which is a photochemical oxidation product of biogenic unsaturated fatty acids, over the Bering Sea in early summer when surface waters are characterized by high biological productivity. We found higher ratios of oxalic acid to pyruvic and glyoxylic acids (C2/Pyr and C2/ωC2) and glyoxal and methylglyoxal (C2/Gly and C2/MeGly) in summer and fall than in winter and spring, suggesting a production of C2 from the aqueous-phase oxidation of oceanic isoprene. In this study, dicarboxylic acids account for 0.7-38% of water-soluble organic carbon.

Estimates of groundwater recharge rates and sources in the East Mountain area, Eastern Bernalillo County, New Mexico, 2005-12

USGS Publications Warehouse

Rice, Steven E.; Crilley, Dianna M.

2014-01-01

Stable isotope data from springs and snowpacks sampled in the East Mountain area were compared with local, regional, and global meteoric water lines and were analyzed along with values representing the stable isotope composition of winter precipitation and summer monsoonal rains. Results of the stable isotope analysis from springs in this study suggested that winter precipitation is the primary source of groundwater recharge to the aquifers supplying the springs, but there is a component of more isotopically enriched precipitation being recharged as well, likely from summer monsoonal rains. Specific conductance, groundwater-level hydrographs, snowpack chemistry, and snow-water equivalent data were used to inform the analyses and corroborate the findings of the CMB and stable isotope results.

Radiochemical and chemical constituents in water from selected wells and springs from the southern boundary of the Idaho National Laboratory to the Hagerman Area, Idaho, 2003

USGS Publications Warehouse

Rattray, Gordon W.; Wehnke, Amy J.; Hall, L. Flint; Campbell, Linford J.

2005-01-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in cooperation with the U.S. Department of Energy, sampled water from 14 sites as part of an ongoing study to monitor the water quality of the eastern Snake River Plain aquifer between the southern boundary of the Idaho National Laboratory (INL) and the Burley-Twin Falls-Hagerman area. The State of Idaho, Department of Environmental Quality, Division of INL Oversight and Radiation Control cosampled with the U.S. Geological Survey and the Idaho Department of Water Resources and their analytical results are included in this report. The samples were collected from four domestic wells, two dairy wells, two springs, four irrigation wells, one observation well, and one stock well and analyzed for selected radiochemical and chemical constituents. Two quality-assurance samples, sequential replicates, also were collected and analyzed. None of the concentrations of radiochemical or organic-chemical constituents exceeded the maximum contaminant levels for drinking water established by the U.S. Environmental Protection Agency. However, the concentration of one inorganic-chemical constituent, nitrate (as nitrogen), in water from site MV-43 was 20 milligrams per liter which exceeded the maximum contaminant level for that constituent. Of the radiochemical and chemical concentrations analyzed for in the replicate-sample pairs, 267 of the 270 pairs (with 95 percent confidence) were statistically equivalent.

The geochemical characteristics of soil water and epikarst springs and their response to vegetation-soil degradation in a karst area

NASA Astrophysics Data System (ADS)

Xiao, D. A.; Xu, H.

2012-04-01

Samples of soil waters and epi-karst springs in four vegetation types were collected at Maolan nature reserve in Libo county, which including protogenetic arbors, secondary arbor-shrub, shrubs and shrub-grass, to analyze their hydro-geochemical properties and the variations of nutrient elements, and further to illustrate the intrinsic correlations of vegetation, soil, environment changes and their geochemical information. The conclusions have been concluded as follows: (1) The pH of soil waters in the study area varies between 5.32 and 7.93, with a mean value of 6.78, and the conductivity changes between 31.82 and 353.65 μS/cm, with a mean value of 126.19 μS/cm. Both descend as the vegetation degrades. The hydro-chemistry of soil waters are Ca- HCO3-, and their ions mainly consist of Ca2+, Mg2+, HCO3-, SO42-. Ca2+, Mg2+, HCO3-are very sensitive to vegetations degradation. Ion contents are high in rain seasons and low in dry ones. (2) The pH of surface karst springs in the study area vary between 6.7 and 8.42, with a mean value of 7.65, and the conductivity between 125.6 and 452 μS/cm, with a mean value of 288.09 μS/cm. The hydro-chemistry of surface karst springs are Ca- HCO3-. HCO3-and SO42-are the main anions while Ca2+and Mg2+as main cations. The chemical properties and geochemical process of surface springs are mainly controlled by the solubility equilibrium of carbonate rocks, thus not sensitive to vegetation degradations. (3) All the calcite saturation indices of soil waters in four vegetation types are below 0, while most indices of surface karst springs are above 0, demonstrating greater denudation of soil waters than surface karst springs. As soil waters flow to surface springs, the partial pressure of CO2decreases, the denudation of water lessens, and saturation index, Ca2+, HCO3-, consequently, pH and conductivity increase. (4) Inorganic nitrogen in soil waters exist mainly as N-NO3- and N-NH4+, accounting ~ 95% of the 3 Ns. As vegetation degrades, nitrate nitrogen, organic nitrogen and total nitrogen change in follow way, protogenetic arbors > secondary arbor-shrub, shrubs > shrub-grass, but the differences among all vegetation types are not prominent. Ammonia nitrogen, however, changes otherwise as follows: shrubs, shrub-grass > protogenetic arbors, secondary arbor-shrub. In surface springs, few inorganic nitrogen exists as NO2--N ( 2 μg/L on average ), and most exists as NO3-N ( 215 μg/L on average ), and NH4+-N is 185μg/L on average. In general, NH4+-N, NO3--N and TN formations in the four vegetation types are: protogenetic arbors > secondary arbor-shrub > shrubs > shrub-grass. (5) DOC content in soil waters vary between 1.88 and 10.37 mg/L, with an average 4.8 mg/L. DOC content in surface karst springs changes between 0.39 and 9.98 mg/L, with an average 2.25 mg/L. DOCs in soil waters are greater than those in surface karst springs in all four vegetation types, and have sharp differences ( P≤0.01 ). DOCs in soil waters and surface karst springs share a great relationship and a similar change tendency, which well illustrates a main source of surface springs from soil waters. In both of them, DOCs are larger in original vegetations than in degraded vegetations. This is because the soil-vegetation system is stable in an original ecology environment which free from outside disturbs. By contrast, a degraded system is unstable, weak at beating disturbs, and conserves less but loses more. Key words: soil waters, epi-karst springs, hydro-geochemical, vegetation, karst area, Maolan in Guizhou

Transport of suspended solids from a karstic to an alluvial aquifer: The role of the karst/alluvium interface

USGS Publications Warehouse

Massei, N.; Lacroix, M.; Wang, H.Q.; Mahler, B.J.; Dupont, J.P.

2002-01-01

This study focuses on the coupled transport of dissolved constituents and particulates, from their infiltration on a karst plateau to their discharge from a karst spring and their arrival at a well in an alluvial plain. Particulate markers were identified and the transport of solids was characterised in situ in porous and karstic media, based on particle size analyses, SEM, and traces. Transport from the sinkhole to the spring appeared to be dominated by flow through karst: particulate transport was apparently conservative between the two sites, and there was little difference in the overall character of the particle size distribution of the particulates infiltrating the sinkhole and of those discharging from the spring. Qualitatively, the mineralogy of the infiltrating and discharging material was similar, although at the spring an autochthonous contribution from the aquifer was noted (chalk particles eroded from the parent rock by weathering). In contrast, transport between the spring and the well appears to be affected by the overlying alluvium: particles in the water from the well, showed evidence of considerable size-sorting. Additionally, SEM images of the well samples showed the presence of particles originating from the overlying alluvial system; these particles were not found in samples from the sinkhole or the spring. The differences between the particulates discharging from the spring and the well indicate that the water pumped from the alluvial plain is coming from the karst aquifer via the very transmissive, complex geologic interface between the underlying chalk formation and the gravel at the base of the overlying alluvial system. ?? 2002 Elsevier Science B.V. All rights reserved.

Alkylphenols and alkylphenol ethoxylates, PBDEs, PCBs and chlorinated pesticides in largemouth bass from North Shore Channel of the Chicago River, Illinois

USDA-ARS?s Scientific Manuscript database

Fall 2006 and Spring 2007 samples of fish, water and effluent (Chicago Northside Water Reclamation Plant) were collected and analyzed for several persistent and semi-persistent chemicals that are believed to be significantly loading into the North Branch of the Chicago River from the Northside Water...

Fluoride content in drinking water supply in São Miguel volcanic island (Azores, Portugal).

PubMed

Cordeiro, S; Coutinho, R; Cruz, J V

2012-08-15

High fluoride contents in the water supply of the city of Ponta Delgada, located in the volcanic island of São Miguel (Azores, Portugal) have been reported. Dental fluorosis in São Miguel has been identified and described in several medical surveys. The water supply in Ponta Delgada consists entirely of groundwater. A study was carried out in order to characterize the natural F-pollution of a group of springs (30) and wells (3), that are associated to active central volcanoes of a trachytic nature. Two springs known for their high content in fluoride were sampled, both located in the central volcano of Furnas. The sampled waters are cold, ranging from slightly acidic to slightly alkaline (pH range 6.53-7.60), exhibiting a low electrical conductivity (springs range 87-502 μS/cm; wells range 237-1761 μS/cm), and are mainly from the Na-HCO(3), Na-HCO(3)-Cl and Na-Cl-HCO(3) water types. Results suggest two main trends of geochemical evolution: silicate weathering, enhanced by CO(2) dilution, and seawater spraying. Fluoride contents range between 0.17 mg/L and 2 mg/L, and no seasonal variations were detected. Results in the sources of the water supply system are lower than those of the Furnas volcano, which reach 5.09 mgF/L, demonstrating the effect of F-rich gaseous emanations in this area. Instead, the higher fluoride contents in the water supply are mainly due to silicate weathering in aquifers made of more evolved volcanic rocks. Copyright © 2012 Elsevier B.V. All rights reserved.

Mutagenicity and genotoxicity of drinking water in Guelma region, Algeria.

PubMed

Abda, Ahlem; Benouareth, Djamel E; Tabet, Mouna; Liman, Recep; Konuk, Muhsin; Khallef, Messaouda; Taher, Ali

2015-02-01

In this study, a battery of genotoxicity assays for monitoring drinking water was performed to assess the quality of the water resulting from the treatment plants. Five different types of samples were collected: raw water (P1), treated after pre-chlorination (P2), treated after decantation (P3), treated post-chlorination (P4), and consumers' taps (P5-P12). This study aims to evaluate the formation/occurrence of mutagenic and/or genotoxic compounds in surface drinking waters treated with chlorine disinfectant, during four seasonal experiments: summer, autumn, winter, and spring between 2012 and 2013 by bacterial reverse mutation assay in both Salmonella typhimurium TA98 and TA100 strains with or without metabolic activation system (S9 mix) and Allium cepa root meristematic cells, respectively. All of water samples, except at P1, P2, and P5 in summer; P1 in autumn; and P1 and P3-P12 in spring without S9 mix, and at P1 and P2 in summer and P6 and P8-P12 in spring with S9 mix, were found to be mutagenic in S. typhimurium TA98. However, only P11 and P12 in winter were found to be mutagenic for TA100 without S9 mix. The tested preparations in Allium anaphase-telophase test revealed a significant decrease in mitotic index (MI) and a simultaneous increase in chromosome aberrations (CAs) compared to the control. The bridge, stickiness, vagrant chromosomes, and disturbed chromosome aberrations were observed in anaphase-telophase cells. Physicochemical analysis, trihalomethanes (THMs), romoform (CHBr3), chloroform (CHCl3), bromodichloromethane (CHBrCl2), and dibromochloromethane (CHBr2Cl) levels in water samples were also determined. The results show also that this short-term battery tests are applicable in the routine monitoring of drinking water quality before and after distribution.

Stable water isotope patterns in a climate change hotspot: the isotope hydrology framework of Corsica (western Mediterranean).

PubMed

van Geldern, Robert; Kuhlemann, Joachim; Schiebel, Ralf; Taubald, Heinrich; Barth, Johannes A C

2014-06-01

The Mediterranean is regarded as a region of intense climate change. To better understand future climate change, this area has been the target of several palaeoclimate studies which also studied stable isotope proxies that are directly linked to the stable isotope composition of water, such as tree rings, tooth enamel or speleothems. For such work, it is also essential to establish an isotope hydrology framework of the region of interest. Surface waters from streams and lakes as well as groundwater from springs on the island of Corsica were sampled between 2003 and 2009 for their oxygen and hydrogen isotope compositions. Isotope values from lake waters were enriched in heavier isotopes and define a local evaporation line (LEL). On the other hand, stream and spring waters reflect the isotope composition of local precipitation in the catchment. The intersection of the LEL and the linear fit of the spring and stream waters reflect the mean isotope composition of the annual precipitation (δP) with values of-8.6(± 0.2) ‰ for δ(18)O and-58(± 2) ‰ for δ(2)H. This value is also a good indicator of the average isotope composition of the local groundwater in the island. Surface water samples reflect the altitude isotope effect with a value of-0.17(± 0.02) ‰ per 100 m elevation for oxygen isotopes. At Vizzavona Pass in central Corsica, water samples from two catchments within a lateral distance of only a few hundred metres showed unexpected but systematic differences in their stable isotope composition. At this specific location, the direction of exposure seems to be an important factor. The differences were likely caused by isotopic enrichment during recharge in warm weather conditions in south-exposed valley flanks compared to the opposite, north-exposed valley flanks.

Cloud deposition of PAHs at Mount Lushan in southern China.

PubMed

Wang, Ruixia; Wang, Yan; Li, Hongli; Yang, Minmin; Sun, Lei; Wang, Tao; Wang, Wenxing

2015-09-01

Cloud water samples were collected from Mount Lushan, a high alpine area of southern China, and analyzed using GC-MS to investigate the concentration levels, seasonal variations, particle-dissolved phase partitioning, ecological risk of PAHs and its relationship to the atmosphere and rainwater. The average concentration of total (dissolved+particle) PAHs in cloud water was 819.90 ng/L, which ranged from 2.30 ng/L for DbA to 295.38 ng/L for PhA. PhA (33.11%) contributed the most individual PAHs, followed by Flu (28.24%). Distinct seasonal variations in the total PAHs measured in this research had a higher concentration during the spring and a lower concentration during the summer. When cloud events occurred, the concentration of the atmospheric PAHs of the two phases decreased. The contribution from the gaseous phase of total PAHs in the air to the dissolved phase in cloud water was up to 60.43%, but the particulate phase in the air only contributed 39.57% to the total scavenging. The contribution of total PAHs from the atmosphere to clouds is higher in the gaseous phase than in the particulate phase. A comparative study of the concentrations of cloud water and the closest rain water revealed that the PAH concentration in rainwater was 1.80 times less than that of cloud water and that the dominant individual compounds in cloud water and rainwater were PhA and Flu. A total of 81.27% of the PAHs in cloud samples and 72.21% of the PAHs in rain samples remained in the dissolved phase. Ecological risk assessment indicated that PAHs in cloud water in spring and summer caused a certain degree of ecosystem risk and the mean ecosystem risk in spring was higher than that in summer. Copyright © 2015 Elsevier B.V. All rights reserved.

Effect of on-site wastewater disposal on quality of ground water and base flow: A pilot study in Chester County, Southeastern Pennsylvania, 2005

USGS Publications Warehouse

Senior, Lisa A.; Cinotto, Peter J.

2007-01-01

On-site wastewater disposal has the potential to introduce contaminants into ground water and subsequently, by ground-water discharge, to streams. A pilot study was conducted during 2005 by the U.S. Geological Survey in cooperation with the Chester County Health Department and the Chester County Water Resources Authority to determine if wastewater components, including inorganic constituents and selected organic wastewater compounds, such as detergents, considered to be emerging contaminants, were present in ground water and stream base flow in areas with on-site wastewater disposal. The study area was a small watershed (about 7.1 square miles) of mixed land use drained by Broad Run in central Chester County, Pa. The area is underlain by fractured metamorphic rocks that form aquifers recharged by precipitation. Surface- and ground-water sampling was done in areas with and without on-site wastewater disposal for comparison, including a relatively densely populated village with cesspools and septic systems, a residential area with septic systems, a residential area served by sewers, and agricultural land. Samples were collected in May-June and September 2005 from eight headwater stream sites under base-flow conditions and in June 2005 from eight wells and two springs. Samples were analyzed for major ions, nutrients, boron, bacteria, and a suite of organic wastewater compounds. Several emerging contaminant wastewater compounds, including detergent components, insect repellents, and flame retardants, were detected in base-flow and ground-water samples. Stream base-flow samples generally contained more compounds and higher concentrations of those compounds than did ground-water samples, and of the ground-water samples, samples from springs contained more compounds and higher concentrations than samples from wells. Concentrations of nitrate, chloride, and boron (inorganic constituents associated with wastewater) generally were all elevated in base-flow and ground-water samples in areas with relatively high densities of on-site wastewater disposal (septic systems or cesspools) compared to other areas sampled. Results of this pilot study should be considered preliminary because of limited data.

Morphological and phylogenetic diversity of thermophilic cyanobacteria in Algerian hot springs.

PubMed

Amarouche-Yala, Samia; Benouadah, Ali; El Ouahab Bentabet, Abd; López-García, Purificación

2014-11-01

Geothermal springs in Algeria have been known since the Roman Empire. They mainly locate in Eastern Algeria and are inhabited by thermophilic organisms, which include cyanobacteria forming mats and concretions. In this work, we have investigated the cyanobacterial diversity of these springs. Cyanobacteria were collected from water, concretions and mats in nine hot springs with water temperatures ranging from 39 to 93 °C. Samples were collected for isolation in culture, microscopic morphological examination, and molecular diversity analysis based on 16S rRNA gene sequences. Nineteen different cyanobacterial morphotypes were identified, the most abundant of which were three species of Leptolyngbya, accompanied by members of the genera Gloeocapsa, Gloeocapsopsis, Stigonema, Fischerella, Synechocystis, Microcoleus, Cyanobacterium, Chroococcus and Geitlerinema. Molecular diversity analyses were in good general agreement with classical identification and allowed the detection of additional species in three springs with temperatures higher than 50 °C. They corresponded to a Synechococcus clade and to relatives of the intracellularly calcifying Candidatus Gloeomargarita lithophora. The hottest springs were dominated by members of Leptolyngbya, Synechococcus-like cyanobacteria and Gloeomargarita, whereas Oscillatoriales other than Leptolyngbya, Chroococcales and Stigonematales dominated lower temperature springs. The isolation of some of these strains sets the ground for future studies on the biology of thermophilic cyanobacteria.

Geochemical Indicators of Urban Development in Tributaries and Springs along the Bull Creek Watershed, Austin, TX

NASA Astrophysics Data System (ADS)

Senison, J. J.; Banner, J. L.; Reyes, D.; Sharp, J. M.

2012-12-01

Urbanization can cause significant changes to both flow and water quality in streams and tributaries. In the Austin, Texas, area, previous studies have demonstrated that streamwater strontium isotope compositions (87Sr/86Sr) correlate with measures of urbanization when comparing non-urbanized streams to their urban counterparts. The inclusion of municipal water into natural surface water is inferred from the mean 87Sr/86Sr value found in urbanized streams, which falls between the high value in treated municipal water and the lower values found in local surface streams sourcing from non-urbanized catchments. Fluoride is added to municipal tap water in the treatment process, and a correlation between 87Sr/86Sr and fluoride is observed in streamwater sampled from the watersheds around Austin. These relationships represent some of the principal findings reported in Christian et al. (2011). Current research is testing the hypothesis that municipal water influx in urban areas is a primary modifier of stream- and spring-water chemistry in a single watershed that contains a strong gradient in land use. We compare 87Sr/86Sr and other chemical constituents with potential contributing endmembers, such as municipal tap water and wastewater, local soil and rock leachates, and land use within the Bull Creek watershed. As a consequence of the history of land development, some Bull Creek tributaries are sourced and flow almost entirely in fully-developed areas, whereas others are located in protected natural areas. Thirteen tributaries were monitored and classified as either urbanized or non-urbanized based upon land use within the tributary catchment. Springs in the Bull Creek watershed were also sampled and are similarly classified. The Bull Creek watershed is composed of Lower Cretaceous limestone with significantly lower 87Sr/86Sr than that of municipal water taken from the Lower Colorado River, which is underlain in part by Precambrian rocks upstream of Austin. There are notable differences in urbanized vs. non-urbanized watersheds in mean concentrations of fluoride (urbanized: 0.27 ± 0.08 vs. non-urbanized: 0.19 ± 0.01 ppm), sodium (34.7 ± 17.3 vs. 8.4 ± 1.0 ppm), and potassium (2.9 ± 0.8 vs. 1.2 ± 0.2 ppm), consistent with higher concentrations in municipal water contributing to the urbanized tributaries. Springwater demonstrates similar divergences for these ions. 87Sr/86Sr for the springs falls within a narrow range for non-urbanized springs (0.7079-0.7081), similar to Cretaceous limestone values, whereas urbanized springs contain a larger range (0.7077-0.7087). These results are consistent with urbanization effects in the Bull Creek watershed.

Estimation of transit times in a Karst Aquifer system using environmental tracers: Application on the Jeita Aquifer system-Lebanon.

NASA Astrophysics Data System (ADS)

Doummar, Joanna; Hamdan, Ahmad

2016-04-01

Estimating transit times is essential for the assessment of aquifer vulnerability to contaminants. Groundwater in karst aquifer is assumed to be relatively young due to fast preferential pathways; slow flow components are present in water stored in the fissured matrix. Furthermore, transit times are site specific as they depend on recharge rates, temperatures, elevation, and flow media; saturated and unsaturated zones. These differences create significant variation in the groundwater age in karst systems as the water sampled will be a mix of different water that has been transported through different flow pathways (fissured matrix and conduits). Several methods can be applied to estimate water transit time of an aquifer such as artificial tracers, which provide an estimate for fast flow velocities. In this study, groundwater residence times in the Jeita spring aquifer (Lebanon) were estimated using several environmental tracers such as Chlorofluorocarbons (CFCs), Sulfur Hexafluoride (SF6), Helium-Tritium (3H, 3H- 3He). Additional stable isotope and major ion analysis was performed to characterize water types. Groundwater samples were collected from six different wells in the Jeita catchment area (Jurassic Kesrouane aquifer) as well as from the spring and cave itself. The results are reproducible for the Tritium-Helium method, unlike for the CFC/SF6 methods that yielded poor results due to sampling problems. Tritium concentrations in all groundwater samples show nearly the same concentration (~2.73 TU) except for one sample with relatively lower tritium concentration (~2.26 TU). Ages ranging from 0.07 ± 0.07 years to 23.59 ± 0.00 years were obtained. The youngest age is attributed to the spring/ cave while the oldest ages were obtained in wells tapping the fissured matrix. Neon in these samples showed considerable variations and high delta Ne in some samples indicating high excess air. Four (4) samples showed extreme excess air (Delta-Ne is greater than 70 %) and the remaining 3 samples have Delta-Ne in the expected range between (10-35%). Moreover Tritium-Helium analysis has showed some radiogenic Helium (4He) in one sample along with lower tritium concentrations signifying a mixture of new groundwater with old groundwater (older than 50 yrs). Furthermore, this study is complemented with published analysis of a series of 26 artificial tracer experiments performed in the Jeita karst system (Doummar, 2012). Transit times calculated from tracer experiments ranged between 3 and 300 hours (12 days). The shortest ones were recorded in the Jeita subsurface conduit. While injections in sinkholes yielded moderate transit times, fissured matrix and unsaturated zone resulted in relatively long ones. In Lebanon this type of spatial groundwater age dating using environmental tracers was not applied to date, to the exception of grab sample analysis. A second round of sampling for Tritium-Helium, CFCs and SF6 analysis will be undertaken under different flow periods in February 2016 to validate the obtained results. References Geyer, T. 2008: Process-based characterization of flow and transport in karst aquifers at catchment scale. Dissertation, Georg-August-Universität Göttingen, 103 S. Geyer, T., and Doummar, J. 2013. Protection of the Jeita Spring: Bestimmung der mittleren Verweilzeit des Grundwassers im Einzugsgebiet der Jeita Quelle-Libanon. Special report. Protection of the Jeita Spring. Applied Geosciences. Georg August University, Göttingen.

Age dating and flow path evaluation of groundwater by SF6 and microbe in the foot of Mt. Fuji, central Japan

NASA Astrophysics Data System (ADS)

Yamamoto, Chisato; Tsujimura, Maki; Kato, Kenji; Nagaosa, Kazuyo; Sakakibara, Koichi; Umei, Yohei; Ohara, Kazuma

2016-04-01

A variety of industries are developed at the foot of volcanic mountains in Japan and the groundwater is major source for industrial activity in those regions. The age of groundwater has been estimated to be from 10 to 30 years in Mt. Fuji regions by using 36Cl and 3H. However, the age has not been evaluated using SF6 with higher time resolution in these regions. Also, the total number of prokaryotes shows a specific value in each spring water, suggesting different path and age of the groundwater. Therefore, we aim to estimate residence time and the groundwater flow in three dimensions using the multi-tracers approach; CFCs, SF6, the total number of prokaryotes, the stable isotopes of oxygen-18, deuterium. We collected totally 25 spring water samples in Mt. Fuji and analyzed concentration of inorganic ions, the stable isotopes of oxygen-18, deuterium, CFCs, SF6. The apparent age of the spring water was estimated to be ranging from 4 to 19 years at the foot of Mt. Fuji. These results are reasonable as considering the existed age data by36Cl (Tosaki, 2008) in this region. The spring water with younger age tends to show higher total number of prokaryotes, suggesting that the groundwater flows dominantly through the shallow and young lava with the higher total number of prokaryotes, leads to younger age. Focusing on a specific spring water, the seasonal change of SF6 and total number of prokaryotes were monitored. The spring water showed a younger age and higher total number of prokaryotes during the high water flow season, whereas it showed an older age and lower total number of prokaryotes. Therefore, the total number of prokaryotes shows a good negative correlation with the residence time of the spring/ groundwater in space and time. This shows a possibility that the total number of prokaryotes could be a useful tracer of groundwater for time and space in the three dimensions information.

Geochemical and isotopic characterization of groundwater origins in a Mediterranean karst system (southern France)

NASA Astrophysics Data System (ADS)

Seidel, J. L.; Ladouche, B.; Batiot-Guilhe, C.

2013-12-01

Geochemical and isotopic ratio (11B/10B and 87Sr/86Sr) results are reported for better determining the groundwater origins in the Lez Karst system (southern France). The Lez spring is the main perennial outlet of the system and supplies with drinking water the metropolitan area of Montpellier. According to the hydrodynamic conditions, five water-types discharge at the Lez spring with important mineralization fluctuations (Caetano Bicalho et al., 2012). This geochemical response suggests that hydrodynamics targets groundwater circulation, resulting from different water end-member solicitation and mixing. Previous studies using conventional natural tracers do not succeed to identify all the water compartments supporting the flow during the hydrologic cycle (Marjolet & Salado, 1977; Joseph et al., 1988) and to explain the mineralization variation of the Lez spring. The present study combines a basic geochemical survey data with boron and strontium isotope ratio data for a better characterization of the Lez spring geochemical functioning. Groundwater samples were collected at the Lez spring and surrounding springs and wells under different hydrologic conditions from 2009 to 2011. Major, trace and rare earth elements were determined at AETE analytical platform (OREME, Univ. Montpellier 2) by ionic chromatography and Q-ICP-MS respectively. d11B and 87Sr/86Sr were determined at BRGM/MMA Orleans by TIMS. The geochemical survey has been extended at a larger scale by sampling the main geochemical end- members already identified to replace the Lez spring waters in the regional geochemical context. From this geochemical study, valuable informations have been provided on the reservoir types and water origins flowing in high and low stage periods. For the highly mineralized waters occurring in the fall first rainy events or severe low stages, a deep contribution is highlighted but B and Sr isotopic data do not ascertain the two Triassic end-members (halite or gypsum) as possible sources of the mineralization increase. However, the Lez spring REE profiles, despite a close Cretaceous end-member signature, exhibit an evolution between the Bajocian and the highly depleted Triassic signature. A better characterization of the regional deep basement end-member and a multi-isotopic approach (d7Li, d11B, d18O, D and 87Sr/86Sr) have been undertaken for a conclusive identification of the Lez spring water type. This study could be generalized to the coastal karstic systems of the Mediterranean region. Caetano Bicalho C., Batiot-Guilhe C., Seidel J. L., Van Exter S. and Jourde H. (2012). Geochemical evidence of water source characterization and hydrodynamic responses in a karst aquifer. J. Hydrol., 450-451, 206-218. Joseph, C., Rodier, C., Soulte, M., Sinegre, F., Baylet, R., Deltour, P., 1988. Approche des transferts de pollution bactérienne dans une crue karstique par l'étude des paramètres physico-chimiques. Rev. Sci. l'eau 1-2, 73-106. Marjolet, G., Salado, J., 1976. Contribution à l'étude de l'aquifère karstique de la source du Lez (Hérault). Etude du chimisme des eaux de la source du Lez et de son bassin Tome IX - FASC II., Université des Sciences et Techniques du Languedoc (Montpellier 2), Montpellier 101 pp.

Temporal and spatial variations in kinetics of alkaline phosphatase in sediments of a shallow Chinese eutrophic lake (Lake Donghu).

PubMed

Yiyong, Zhou; Jianqiu, Li; Min, Zhang

2002-04-01

Monthly sediment and interstitial water samples were collected in a shallow Chinese freshwater lake (Lake Donghu) from three areas to determine if alkaline phosphatase activity (APA) plays an important role, in phosphorus cycling in sediment. The seasonal variability in the kinetics of APA and other relevant parameters were investigated from 1995-1996. The phosphatase hydrolyzable phosphorus (PHP) fluctuated seasonally in interstitial water, peaking in the spring. A synchronous pattern was observed in chlorophyll a contents in surface water in general. The orthophosphate (o-P) concentrations in the interstitial water increased during the spring. An expected negative relationship between PHP and Vmax of APA is not evident in interstitial water. The most striking feature of the two variables is their co-occurring, which can be explained in terms of an induction mechanism. It is argued that phosphatase activity mainly contributes to the driving force of o-P regeneration from PHP in interstitial water, supporting the development of phytoplankton biomass in spring. The Vmax values in sediment increased during the summer, in conjunction with lower Km values in interstitial water that suggest a higher affinity for the substrate. The accumulation of organic matter in the sediment could be traced back to the breakdown of the algal spring bloom, which may stimulate APA with higher kinetic efficiency, by a combination of the higher Vmax in sediments plus lower Km values in interstitial water, in summer. In summary, a focus on phosphatase and its substrate in annual scale may provide a useful framework for the development of novel P cycling, possible explanations for the absence of a clear relationship between PHP and APA were PHP released from the sediment which induced APA, and the presence of kinetically higher APA both in sediment and interstitial water which permitted summer mineralization of organic matter derived from the spring bloom to occur. The study highlighted the need for distinguishing functionally distinct extracellular enzymes between the sediment and interstitial water of lakes.

Brassica cover crops for nitrogen retention in the Mid-Atlantic coastal plain.

PubMed

Dean, Jill E; Weil, Ray R

2009-01-01

Brassica cover crops are new to the mid-Atlantic region, and limited information is available on their N uptake capabilities for effective N conservation. Forage radish (Raphanus sativus L. cv. Daikon), oilseed radish (Raphanus sativus L. cv. Adagio), and rape (Brassica napus L. cv. Dwarf Essex) were compared with rye (Secale cereale L. cv. Wheeler), a popular cover crop in the region, with regard to N uptake ability and potential to decrease N leaching at two sites in Maryland. Plants were harvested in fall and spring for dry matter and N analysis. Soil samples from 0 cm to 105 to 180 cm depth were obtained in fall and spring for NH(4)-N and NO(3)-N analyses. Ceramic cup tension lysimeters were installed at depths of 75 to 120 cm to monitor NO(3)-N in soil pore water. Averaged across 3 site-years, forage radish and rape shoots had greater dry matter production and captured more N in fall than rye shoots. Compared with a weedy fallow control, rape and rye caused similar decreases in soil NO(3)-N in fall and spring throughout the sampled profile. Cover crops had no effect on soil NH(4)-N. During the spring on coarse textured soil, pore water NO(3)-N concentrations in freeze-killed Brassica (radish) plots were greater than in control and overwintering Brassica (rape) and rye plots. On fine textured soil, all cover crops provided a similar decrease in pore water NO(3)-N concentration compared with control. On coarse textured soils, freeze-killed Brassica cover crops should be followed by an early-planted spring main crop.

Using Spring Water Nitrate to Monitor Spatiotemporal Trends in Nitrogen Deposition for the Santa Clara Valley Habitat Plan

NASA Astrophysics Data System (ADS)

Weiss, S. B.; Hastings, M. G.

2016-12-01

Atmospheric nitrogen deposition is a major acute threat to biodiversity, but has rarely been addressed in regulatory conservation plans. The Santa Clara Valley Habitat Plan is a Habitat Conservation Plan/Natural Communities Conservation Plan (HCP/NCCP) that addresses development impacts on 19 covered species, most of which inhabit nutrient-poor serpentine grasslands that are highly sensitive to N-deposition with a critical load of 6 kg-N ha-1 year-1. Increased N-deposition from highway improvements and development was a major regulatory nexus, and a novel nitrogen fee based on car trips generated is one of the funding mechanisms, driving a need for cost-effective and robust monitoring of N-deposition trends over the 50-year plan and beyond. In the high deposition zone (10-20 kg-N ha-1 year-1), spring water nitrate levels up to 25 ppm (as NO3-) were measured in baseflow, levels higher than any reported for non-agricultural sites in California. Nitrate measurements follow measured and modeled deposition gradients, and are affected by catchment soils, geomorphology, and vegetation. Existing knowledge of local nitrogen deposition using passive samplers, CMAQ models, N-cycling measurements, and emissions inventories/projections are used to generate hypotheses that can be tested with a combination of spring water nitrate sampled through the year and across deposition gradients, N and O isotopic analysis including 17O to trace atmospheric nitrate, modeled recharge rates, and groundwater dating. A set of sentinel springs for long-term monitoring will be identified and sampled on an interval commensurate with shallow groundwater residence times. The unique characteristics of serpentine grasslands (low productivity, shallow soils, highly fractured bedrock, and numerous springs) provide a model system for tracing N-deposition and its effects on protected species.

Hydrology of coal-resource areas in the southern Wasatch Plateau, central Utah

USGS Publications Warehouse

Danielson, T.W.; Sylla, D.A.

1982-01-01

The study defines the surface and groundwater hydrology of coal-resources areas in the Southern Wasatch Plateau in Central Utah and, where possible, predicts the hydrologic impacts of underground mining. Discharge data at four streamflow gaging stations indicated that from 5 to 29% of the average annual precipitation on a drainage runs off streams, mainly during the snowmelt period (spring and summer). Most of the base flow of streams originates as spring discharge in the higher altitudes of drainages. Peak flows, average 7-day flood flows, and flood depths were related to basin characteristics in order to develop flood equations for ungaged sites. Chemical quality of surface water was suitable for most uses. Dissolved-solids concentrations ranged from 97 to 835 milligrams per liter in 61 samples collected throughout the area. Data from wells and coal-test holes, and a comprehensive spring inventory indicate that groundwater occurs in all geologic units exposed in the study area. The coal-bearing Blackhawk Formation and underlying Star Point Sandstone are saturated in most areas. Some future mining operations would require dewatering of the Star Point-Blackhawk aquifer. Most of the springs issue from the Flagstaff Limestone and North Horn Formation above the Star Point-Blackhawk aquifer. It is not known whether water in the Flagstaff and North Horn is perched. Dissolved-solids concentrations in groundwater ranged from 105 to 1,080 milligrams per liter in 87 analyzed samples. Water levels in wells, the discharge of springs, benthic invertebrates in streams, and quantity and quality of mine effluents all need to be monitored in order to detect changes in the hydrologic system caused by coal mining. (USGS)

Hydrological and Geochemical Influences on the Dissolved Silica Concentrations in Natural Water in a Steep Headwater Catchment

NASA Astrophysics Data System (ADS)

Asano, Y.; Uchida, T.; Ohte, N.

2002-12-01

Dissolved silica has been used as a useful indicator of a chemical weathering in many geochemical studies in natural environment. Previous hydrological studies indicated that various hydrological processes affect the dissolution and precipitation of silica in hillslope and transport of this silica to stream; however, information is still limited to link this knowledge to understand geochemical processes. The observations of dissolved silica concentration in groundwater, spring and stream water was conducted at the unchannelled hillslope in the Tanakami Mountains of central Japan; (1) to clarify the effects of preferential flowpaths including lateral and vertical flow in soil layer and flow through bedrock fracture in the variation of dissolved silica concentration in runoff and groundwater, and (2) to isolate the effects of mixing of water from geochemically diverse water sources on the dissolved silica concentration. The mean dissolved silica concentrations in soil water at 40 cm depth and transient groundwater formed in upslope area were relatively constant independent of the variation in the new water ratio. The mean dissolved silica concentrations were similar regardless of the sampling depth in soil although the mean residence times of water increase with depth. These results indicated that dissolved silica concentrations in soil water and transient groundwater were defined almost independent of contact time of water with minerals. While the mean dissolved silica concentration in perennial groundwater, which was recharged by infiltrating water through soil and water emerging from bedrock in a area near to spring, was more than twice that of transient groundwater and the variation was relatively large. The mean dissolved silica concentration increased significantly at downslope from perennial groundwater, spring to the stream and the spring and stream concentrations also showed large variation. The dissolved silica concentrations of those perennial groundwater, the spring and the stream was controlled by the mixing of water from soil and bedrock. Our results demonstrated that in most areas of this headwater catchment, the preferential flowpaths give only small effect on dissolved silica concentrations. While in a small area (less than 10% of the longitudinal axis of the hollow near the spring), the dissolved silica concentration were controlled by the mixing of water from geochemically diverse water sources.

Hydrogeochemical survey of groundwater for selected areas in the Arabian Shield and in cover rocks, Kingdom of Saudi Arabia

USGS Publications Warehouse

McHugh, John B.; Miller, W. Roger

1989-01-01

In the spring of 1984, a hydrogeochemical survey was conducted in the Kingdom of Saudi Arabia to test ground water as a sampling medium in exploration for mineral deposits. Eighty-one water samples (mostly from wells) were collected. The samples were analysed for the presence and concentration of major cations and anions, as well as a suite of trace elements. Most of the water samples contained high concentrations of dissolved salts. The majority of the samples showed no significant amounts of the trace elements. A few well-water samples contained moderately anomalous concentrations of zinc, molybdenum, and uranium. These anomalies could be due to salinity effects, contamination, or the proximity of mineral sources. This survey has established some baseline water-chemistry data, especially for the trace metals, which to date have not been reported in ground water in the Kingdom of Saudi Arabia.

CO2 outgassing in a combined fracture and conduit karst aquifer near lititz spring, Pennsylvania

USGS Publications Warehouse

Toran, L.; Roman, E.

2006-01-01

Lititz Spring in southeastern Pennsylvania and a nearby domestic well were sampled for 9 months. Although both locations are connected to conduits (as evidenced by a tracer test), most of the year they were saturated with respect to calcite, which is more typical of matrix flow. Geochemical modeling (PHREEQC) was used to explain this apparent paradox and to infer changes in matrix and conduit contribution to flow. The saturation index varied from 0.5 to 0 most of the year, with a few samples in springtime dropping below saturation. The log PCO2 value varied from -2.5 to -1.7. Lower log PCO2 values (closer to the atmospheric value of -3.5) were observed when the solutions were at or above saturation with respect to calcite. In contrast, samples collected in the springtime had high PCO2, low saturation indices, and high water levels. Geochemical modeling showed that when outgassing occurs from a water with initially high PCO2, the saturation index of calcite increases. In the Lititz Spring area, the recharge water travels through the soil zone, where it picks up CO2 from soil gas, and excess CO 2 subsequently is outgassed when this recharge water reaches the conduit. At times of high water level (pipe full), recharge with excess CO 2 enters the system but the outgassing does not occur. Instead the recharge causes dilution, reducing the calcite saturation index. Understanding the temporal and spatial variation in matrix and conduit flow in karst aquifers benefited here by geochemical modeling and calculation of PCO2 values. ?? 2006 Geological Society of America.

Using isotopes of dissolved inorganic carbon species and water to separate sources of recharge in a cave spring, northwestern Arkansas, USA Blowing Spring Cave

USGS Publications Warehouse

Knierim, Katherine J.; Pollock, Erik; Hays, Phillip D.

2013-01-01

Blowing Spring Cave in northwestern Arkansas is representative of cave systems in the karst of the Ozark Plateaus, and stable isotopes of water (δ18O and δ2H) and inorganic carbon (δ13C) were used to quantify soil-water, bedrock-matrix water, and precipitation contributions to cave-spring flow during storm events to understand controls on cave water quality. Water samples from recharge-zone soils and the cave were collected from March to May 2012 to implement a multicomponent hydrograph separation approach using δ18O and δ2H of water and dissolved inorganic carbon (δ13C–DIC). During baseflow, median δ2H and δ18O compositions were –41.6‰ and –6.2‰ for soil water and were –37.2‰ and –5.9‰ for cave water, respectively. Median DIC concentrations for soil and cave waters were 1.8 mg/L and 25.0 mg/L, respectively, and median δ13C–DIC compositions were –19.9‰ and –14.3‰, respectively. During a March storm event, 12.2 cm of precipitation fell over 82 h and discharge increased from 0.01 to 0.59 m3/s. The isotopic composition of precipitation varied throughout the storm event because of rainout, a change of 50‰ and 10‰ for δ2H and δ18O was observed, respectively. Although, at the spring, δ2H and δ18O only changed by approximately 3‰ and 1‰, respectively. The isotopic compositions of precipitation and pre-event (i.e., soil and bedrock matrix) water were isotopically similar and the two-component hydrograph separation was inaccurate, either overestimating (>100%) or underestimating (<0%) the precipitation contribution to the spring. During the storm event, spring DIC and δ13C–DIC decreased to a minimum of 8.6 mg/L and –16.2‰, respectively. If the contribution from precipitation was assumed to be zero, soil water was found to contribute between 23 to 72% of the total volume of discharge. Although the assumption of negligible contributions from precipitation is unrealistic, especially in karst systems where rapid flow through conduits occurs, the hydrograph separation using inorganic carbon highlights the importance of considering vadose-zone soil water when analyzing storm chemohydrographs.

Evaluation of water quality in surface water and shallow groundwater: a case study of a rare earth mining area in southern Jiangxi Province, China.

PubMed

Hao, Xiuzhen; Wang, Dengjun; Wang, Peiran; Wang, Yuxia; Zhou, Dongmei

2016-01-01

This study was conducted to evaluate the quality of surface water and shallow groundwater near a rare earth mining area in southern Jiangxi Province, China. Water samples from paddy fields, ponds, streams, wells, and springs were collected and analyzed. The results showed that water bodies were characterized by low pH and high concentrations of total nitrogen (total N), ammonium nitrogen (NH4 (+)-N), manganese (Mn), and rare earth elements (REEs), which was likely due to residual chemicals in the soil after mining activity. A comparison with the surface water standard (State Environmental Protection Administration & General Administration of Quality Supervision, Inspection and Quarantine of China GB3838, 2002) and drinking water sanitary standard (Ministry of Health & National Standardization Management Committee of China GB5749, 2006) of China revealed that 88 % of pond and stream water samples investigated were unsuitable for agricultural use and aquaculture water supply, and 50 % of well and spring water samples were unsuitable for drinking water. Moreover, significant cerium (Ce) negative and heavy REEs enrichment was observed after the data were normalized to the Post-Archean Australian Shales (PAAS). Principal component analysis indicated that the mining activity had a more significant impact on local water quality than terrace field farming and poultry breeding activities. Moreover, greater risk of water pollution and adverse effects on local residents' health was observed with closer proximity to mining sites. Overall, these findings indicate that effective measures to prevent contamination of surrounding water bodies from the effects of mining activity are needed.

Database of historically documented springs and spring flow measurements in Texas

USGS Publications Warehouse

Heitmuller, Franklin T.; Reece, Brian D.

2003-01-01

Springs are naturally occurring features that convey excess ground water to the land surface; they represent a transition from ground water to surface water. Water issues through one opening, multiple openings, or numerous seeps in the rock or soil. The database of this report provides information about springs and spring flow in Texas including spring names, identification numbers, location, and, if available, water source and use. This database does not include every spring in Texas, but is limited to an aggregation of selected digital and hard-copy data of the U.S. Geological Survey (USGS), the Texas Water Development Board (TWDB), and Capitol Environmental Services.

Do natural spring waters in Australia and New Zealand affect health? A systematic review.

PubMed

Stanhope, Jessica; Weinstein, Philip; Cook, Angus

2018-02-01

Therapeutic use of spring waters has a recorded history dating back to at least 1550 BC and includes both bathing in and drinking such waters for their healing properties. In Australia and New Zealand the use of therapeutic spring waters is a much more recent phenomenon, becoming a source of health tourism from the late 1800s. We conducted a systematic review aimed at determining the potential health outcomes relating to exposure to Australian or New Zealand natural spring water. We found only low-level evidence of adverse health outcomes relating to this spring water exposure, including fatalities from hydrogen sulphide poisoning, drowning and primary amoebic meningoencephalitis. We found no studies that investigated the therapeutic use of these waters, compared with similar treatment with other types of water. From the broader literature, recommendations have been made, including fencing potentially harmful spring water, and having signage and media messages to highlight the potential harms from spring water exposure and how to mitigate the risks (e.g. not putting your head under water from geothermal springs). Sound research into the potential health benefits of Australian and New Zealand spring waters could provide an evidence base for the growing wellness tourism industry.

Analytical data from phases I and II of the Willamette River basin water quality study, Oregon

USGS Publications Warehouse

Harrison, Howard E.; Anderson, Chauncey W.; Rinella, Frank A.; Gasser, Timothy M.; Pogue, Ted R.

1995-01-01

The data were collected at 50 sites, representing runoff from agricultural, forested, and urbanized subbasins. In Phase I, water samples were collected during high and low flows in 1992 and 1993 to represent a wide range of hydrologic conditions. Bed-sediment samples were collected during low flows in 1993. In Phase II, water samples were collected in the spring of 1994 after the first high-flow event following the application of agricultural fertilizers and pesticides and in the fall during the first high-flow events following the conclusion of the agricultural season.

Groundwater residence times in Shenandoah National Park, Blue Ridge Mountains, Virginia, USA: A multi-tracer approach

USGS Publications Warehouse

Plummer, Niel; Busenberg, E.; Böhlke, J.K.; Nelms, D.L.; Michel, R.L.; Schlosser, P.

2001-01-01

Chemical and isotopic properties of water discharging from springs and wells in Shenandoah National Park (SNP), near the crest of the Blue Ridge Mountains, VA, USA were monitored to obtain information on groundwater residence times. Investigated time scales included seasonal (wet season, April, 1996; dry season, August–September, 1997), monthly (March through September, 1999) and hourly (30-min interval recording of specific conductance and temperature, March, 1999 through February, 2000). Multiple environmental tracers, including tritium/helium-3 (3H/3He), chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), sulfur-35 (35S), and stable isotopes (δ18O and δ2H) of water, were used to estimate the residence times of shallow groundwater discharging from 34 springs and 15 wells. The most reliable ages of water from springs appear to be based on SF6 and 3H/3He, with most ages in the range of 0–3 years. This range is consistent with apparent ages estimated from concentrations of CFCs; however, CFC-based ages have large uncertainties owing to the post-1995 leveling-off of the CFC atmospheric growth curves. Somewhat higher apparent ages are indicated by 35S (>1.5 years) and seasonal variation of δ18O (mean residence time of 5 years) for spring discharge. The higher ages indicated by the 35S and δ18O data reflect travel times through the unsaturated zone and, in the case of 35S, possible sorption and exchange of S with soils or biomass. In springs sampled in April, 1996, apparent ages derived from the 3H/3He data (median age of 0.2 years) are lower than those obtained from SF6 (median age of 4.3 years), and in contrast to median ages from 3H/3He (0.3 years) and SF6 (0.7 years) obtained during the late summer dry season of 1997. Monthly samples from 1999 at four springs in SNP had SF6apparent ages of only 1.2 to 2.5±0.8 years, and were consistent with the 1997 SF6 data. Water from springs has low excess air (0–1 cm3 kg−1) and N2–Ar temperatures that vary seasonally. Concentrations of He and Ne in excess of solubility equilibrium indicate that the dissolved gases are not fractionated. The seasonal variations in N2–Ar temperatures suggest shallow, seasonal recharge, and the excess He and Ne data suggest waters mostly confined to gas exchange in the shallow, mountain-slope, water-table spring systems. Water from wells in the fractured rock contains up to 8 cm3 kg−1 of excess air with ages in the range of 0–25 years. Transient responses in specific conductance and temperature were observed in spring discharge within several hours of large precipitation events in September, 1999; both parameters increased initially, then decreased to values below pre-storm base-flow values. The groundwater residence times indicate that flushing rates of mobile atmospheric constituents through groundwater to streams draining the higher elevations in SNP average less than 3 years in base-flow conditions.

Abrupt physical and chemical changes during 1992-1999, Anderson Springs, SE Geyser Geothermal Field, California

USGS Publications Warehouse

Janik, Cathy J.; Goff, Fraser; Walter, Stephen R.; Sorey, Michael L.; Counce, Dale; Colvard, Elizabeth M.

2000-01-01

The Anderson Springs area is located about 90 miles (145 kilometers) north of San Francisco, California, in the southwestern part of Lake County. The area was first developed in the late 1800s as a health resort, which was active until the 1930s. Patrons drank a variety of cool to hot mineral waters from improved springs, swam in various baths and pools, and hiked in the rugged hills flanking Anderson Creek and its tributaries. In the bluffs to the south of the resort were four small mercury mines of the eastern Mayacmas quicksilver district. About 1,260 flasks of mercury were produced from these mines between 1909 and 1943. By the early 1970s, the higher ridges south and west of Anderson Springs became part of the southeast sector of the greater Geysers geothermal field. Today, several electric power plants are built on these ridges, producing energy from a vapor-dominated 240 °C reservoir. Only the main hot spring at Anderson Springs has maintained a recognizable identity since the 1930s. The hot spring is actually a cluster of seeps and springs that issue from a small fault in a ravine southwest of Anderson Creek. Published and unpublished records show that the maximum temperature (Tm) of this cluster fell gradually from 63°C in 1889 to 48°C in 1992. However, Tm of the cluster climbed to 77°C in 1995 and neared boiling (98°C) in 1998. A new cluster of boiling vents and small fumaroles (Tm = 99.3°C) formed in 1998 about 30 m north of the old spring cluster. Several evergreen trees on steep slopes immediately above these vents apparently were killed by the new activity. Thermal waters at Anderson Hot Springs are mostly composed of near-surface ground waters with some added gases and condensed steam from The Geysers geothermal system. Compared to gas samples from Southeast Geysers wells, the hot spring gases are higher in CO2 and lower in H2S and NH3. As the springs increased in temperature, however, the gas composition became more like the mean composition of steam discharges from the Southeast Geysers. The hot spring waters are low in ions of Cl, B, and Li, but relatively high in HCO3, SO4 and NH4. The stable-isotope compositions (deuterium and oxygen-18) of these waters plot near the global meteoric water line. Geochemical data through time reveal apparent maxima in the concentrations of SO4, Fe, and Mn in 1991 to 1992, before the cluster became hotter. The black-to-gray deposits from the new spring cluster are rich in pyrite and contain anomalous metals. About one-half mile to the east of the hot springs, mineralized water discharges intermittently from an old adit of the Schwartz (Anderson) mine, and enters a tributary of Anderson Creek. This drainage increased substantially in July 1998, and a slurry of mine water and precipitates were transported down the tributary and into Anderson Creek. In December 1998, the adit water was 22°C, and had a chemical composition that was similar to spring waters that once discharged in the ravines surrounding the old Anderson Springs resort. The cause for the abrupt changes that have occurred in thermal features at Anderson Springs is still not resolved. One possibility is that these changes are a response to withdrawal of steam from The Geysers geothermal field over more than 20 years of production. Pressure declines in the geothermal reservoir may have caused a "drying out" of the overlying condensation zone. Induced boiling in this zone and upflow of deep steam to shallower depths would cause heating and vaporization of shallow ground waters. In addition, earthquakes occurring in the vicinity of Anderson Springs have increased significantly after nearby geothermal power plants began operation. These earthquakes may have enhanced surface discharge of thermal fluids along fractures and faults.

[Isolation of Legionella species from hot springs used for foot-soaking].

PubMed

Furuhata, Katsunori; Edagawa, Akiko; Fukuyama, Masafumi

2012-05-01

We aimed to investigate the presence of Legionella species in hot-spring baths for feet, which have been rapidly increasing in number in Japan in recent years. The investigations were conducted between March 2009 and November 2011, and hot springs throughout the country were sampled. Legionella isolates were confirmed on the basis of the method described in the "Manual for the countermeasure to legionellosis, 3rd Edition." In this method, the samples were concentrated and smeared on GVPCalpha agar medium after acid treatment and cultured for 7 days at 36 degrees C. Gram-negative rods that required L-cysteine were determined to be Legionella species. After the first identification using Duopath Legionella (Merck Ltd. Japan), isolates were identified on the basis of agglutination reaction of an immune serum or genetic examination. Legionella was isolated from 56 of the 196 samples (28.6%) and was confirmed to widely inhabit hot-spring baths from Hokkaido to Kyushu. The isolation rates were the highest (40.9%) in facilities installed around railway stations, including those on platforms. The average microbial density of Legionella species per 100 ml of hot spring water was 1.0 x 10(1) CFU, with a maximum value of 1.0 x 10(4) CFU, although the microbial density in most of the samples (34 samples; 60.7%) was less than 10(2) CFU. Legionella pneumophila was the dominant strain, and 16 strains (23.9%) of serogroup 1 were isolated. In addition, 7 strains (10.4%) of Legionella londiniensis and 4 strains (6.0%) of Legionella rubrilucens were isolated. Legionella species inhabit approximately 30% of all hot springs for foot-soaking in the country. Although the number of viable organisms is small, the dominant presence of Legionella pneumophila, a major pathogen responsible for legionnaire's disease, raises the possibility of legionnaire's disease in users of these hot springs. Therefore, each institute should understand the present distribution of Legionella species in these hot springs and undertake appropriate sanitary measures.

Hydrogeology of the Coconino Plateau and adjacent areas, Coconino and Yavapai Counties, Arizona

USGS Publications Warehouse

Bills, Donald J.; Flynn, Marilyn E.; Monroe, Stephen A.

2007-01-01

Two large, regional ground-water flow systems occur in the Coconino Plateau and adjacent areas: the C aquifer and the Redwall-Muav aquifer. The C aquifer occurs mainly in the eastern and southern parts of the 10,300-square-mile Coconino Plateau study area, and the Redwall-Muav aquifer underlies the entire study area. The C aquifer is a water-table aquifer for most of its occurrence with depths to water that range from a few hundred feet to more than 1,500 feet. In the western part of the Coconino Plateau study area, the C aquifer is dry except for small localized perched water-bearing zones decoupled from the C aquifer to the east. The Redwall-Muav aquifer underlies the C aquifer and ranges from at least 3,000 feet below land surface in the western part of the Coconino Plateau study area to more than 3,200 feet below land surface in the eastern part of the study area. The Redwall-Muav aquifer is a confined aquifer for most of its occurrence with hydraulic heads of several hundred to more than 500 feet above the top of the aquifer in the western part of the study area and more than 2,000 feet above the top of the aquifer in the eastern part of the study area near Flagstaff. In the eastern and northeast parts of the area, the C aquifer and the Redwall-Muav aquifer are in partial hydraulic connection through faults and other fractures. The water discharging from the two aquifers on the Coconino Plateau study area is generally of good quality for most intended uses. Water from sites in the lower Little Colorado River Canyon had high concentrations of most trace elements relative to other springs, rivers, and streams in the study area. Concentrations of barium, arsenic, uranium, and lead, and gross alpha radioactivity were greater than U.S. Environmental Protection Agency Maximum Contaminant Levels for drinking water at some sites. Ground water discharging to most springs, streams, and wells on the Coconino Plateau and in adjacent areas is a calcium magnesium bicarbonate type and has low concentrations of the major dissolved constituents. Ground water discharging from the Redwall-Muav aquifer to springs in the lower Little Colorado River Canyon is a mixture of water from the C aquifer and the Redwall-Muav aquifer and is a sodium chloride type with high concentrations of most major dissolved constituents. Concentrations of sulfate and chloride in ground water discharging from the Redwall-Muav aquifer at springs near the south rim of Grand Canyon increase toward the west. Water samples from the Verde River above Mormon Pocket had higher concentrations of most dissolved constituents than samples from springs that discharge from the Redwall-Muav aquifer at Mormon Pocket and in Sycamore Canyon. Water-chemistry data from C aquifer wells and springs in the Flagstaff area indicate that ground-water ages in the aquifer range from 7,000 years to modern and that samples were a mix of younger and older waters. Ground-water ages for the Redwall-Muav aquifer are estimated to range from 22,600 to 7,500 years, and low tritium values indicate that this water is older than water discharging from the C aquifer. Tritium and carbon-14 results indicate that ground water discharging at most springs and streams is a mixture of young and old ground waters, likely resulting from multiple flow paths and multiple recharge areas. Ground-water withdrawals in the study area increased from about 4,000 acre-feet per year prior to 1975, to about 20,000 acre-feet per year in 2003. About two-thirds of the water withdrawn is from the C aquifer and about one-third is from the Redwall-Muav aquifer. In the study area, most development of the C aquifer has occurred near Flagstaff. Development of the Redwall-Muav aquifer is more extensive in Verde Valley where water-bearing zones of the aquifer are closer to land surface. In recent years, however, development of the Redwall-Muav aquifer in the study area has increased in response to population growth and the atten

Hydrogeology of the Markagunt Plateau, Southwestern Utah

USGS Publications Warehouse

Spangler, Lawrence E.

2010-01-01

The Markagunt Plateau, in southwestern Utah, lies at an altitude of about 9,500 feet and is capped primarily by Quaternary-age basalt that overlies Eocene-age freshwater limestone of the Claron Formation. Over large parts of the Markagunt Plateau, dissolution of the Claron limestone and subsequent collapse of the overlying basalt have produced a terrain characterized by sinkholes as much as 1,000 feet across and 100 feet deep. Numerous large springs discharge from the basalt and underlying limestone on the plateau, including Mammoth Spring, one of the largest springs in Utah, with a discharge that can exceed 300 cubic feet per second. Discharge from Mammoth Spring is from the Claron Formation; however, recharge to the spring largely takes place by both focused and diffuse infiltration through the basalt that caps the limestone. Results of dye tracing to Mammoth Spring indicate that recharge originates largely southwest of the spring outside of the Mammoth Creek watershed, as well as from losing reaches along Mammoth Creek. Maximum groundwater travel time to the spring from dye-tracer tests during the snowmelt runoff period was about 1 week. Specific conductance and water temperature data from the spring show an inverse relation to discharge during snowmelt runoff and rainfall events, also indicating short groundwater residence times. Results of major-ion analyses for samples collected from Mammoth and other springs on the plateau indicate calcium-bicarbonate type water containing low (less than 200 mg/L) dissolved-solids concentrations. Investigations in the Navajo Lake area along the southern margin of the plateau have shown that water losing to sinkholes bifurcates and discharges to both Cascade and Duck Creek Springs, which subsequently flow into the Virgin and Sevier River basins, respectively. Groundwater travel times to these springs, on the basis of dye tracing, were about 8.5 and 53 hours, respectively. Similarly, groundwater travel time from Duck Creek Sinks to Lower Asay Spring was about 68 hours. Dye-tracer studies conducted at the Mammoth Creek fish hatchery along the eastern margin of the Markagunt Plateau indicate that water losing through the channel of Mammoth Creek 3,000 feet upstream of the hatchery discharges from the hatchery springs in about 7.5 hours. Results of studies using soil bacteria and club moss spores as surrogate particle tracers for the whirling disease parasite also indicate that the potential exists for transport of the parasite to the springs from Mammoth Creek.

Investigation of iodine concentration in salt, water and soil along the coast of Zhejiang, China*

PubMed Central

Lu, Ying-li; Wang, Ning-jian; Zhu, Lan; Wang, Guo-xing; Wu, Hui; Kuang, Lin; Zhu, Wen-ming

2005-01-01

Objective: We aim to describe the environment iodine concentration in salt, water and soil along Zhejiang Province coast in the China foreland. It will be helpful for us to judge whether this area is insufficient in iodine and universal iodized salt is necessary or not. Methods: We collected iodized salt samples, drinking water samples (tap water in the towns, and well water or spring water in the villages), water samples from different sources (ditches, lakes, rivers) and soil samples through random sampling in June, 2005. Salt, water and soil iodine was detected by arsenic-cerium redox method. Statistical analysis was expressed as mean±SEM by Windows SPSS 13.0. Results: (1) The iodine concentration in salt was 27.9±4.33 mg/kg (n=108). (2) Seventy-five water samples were collected. The water iodine value was 0.6~84.8 μg/L (mean of 11.66 μg/L). The watershed along the Qiantang River has significantly higher iodine content than the water in Lin’an in mountain area (P<0.01). The iodine content and mean iodine content of tap water, well or spring water and natural water sources were 4.30±2.43 μg/L (n=34), 23.59±27.74 μg/L (n=19) and 12.72±10.72 μg/L (n=22) respectively. This indicated that among environmental water sources, the ditch iodine content was the highest with river water iodine being the lowest (P<0.01). (3) Soil iodine value was 0.11~2.93 mg/kg (mean of 1.32 mg/kg). Though there was no statistical difference of soil iodine in different districts (P=0.131), soil iodine content correlated positively with water iodine content. Conclusion: Iodine concentration in salt accords with national policy of adding iodine in salt. Foreland has more iodine in water than mountain area. The data reflected that water and soil iodine in foreland area was not high, which suggests universal iodized salt should be necessary. Environment iodine has relatively close association with pollution. PMID:16358379

Source Of Hydrogen Sulfide To Sulfidic Spring And Watershed Ecosystems In Northern Sierra De Chiapas, Mexico Based On Sulfur And Carbon Isotopes

NASA Astrophysics Data System (ADS)

Rosales Lagarde, L.; Boston, P. J.; Campbell, A.

2013-12-01

At least four watersheds in northern Sierra de Chiapas, Mexico are fed by conspicuous karst sulfide-rich springs. The toxic hydrogen sulfide (H2S) in these springs nurtures rich ecosystems including especially adapted microorganisms, invertebrates and fish. Sulfur and carbon isotopic analysis of various chemical species in the spring water are integrated within their hydrogeologic context to evaluate the hydrogen sulfide source. Constraining the H2S origin can also increase the understanding of this compound effect in the quality of the nearby hydrocarbon reservoirs, and the extent to which its oxidation to sulfuric acid increases carbonate dissolution and steel corrosion in surface structures. The SO42-/H2S ratio in the spring water varies from 70,000 to 2 meq/L thus sulfate is the dominant species in the groundwater system. This sulfate is mainly produced from anhydrite dissolution based on its isotopic signature. The Δ SO42--H2S range of 16 spring water samples (30-50 ‰) is similar to the values determined by Goldhaber & Kaplan (1975) and Canfield (2001) for low rates of bacterial sulfate reduction suggesting that this is the most important mechanism producing H2S. Although the carbon isotopes do not constrain the nature of the organic matter participating in this reaction, this material likely comes from depth, perhaps as hydrocarbons, due to the apparent stability of the system. The organic matter availability and reactivity probably control the progress of sulfate reduction. The subsurface environments identified in the area also have different sulfur isotopic values. The heavier residual sulfate isotopic value in the Northern brackish springs (δ34S SO42- ≥ 18 ‰) compared to the Southern springs (δ34S SO42- ~18 ‰) suggests sulfate reduction is particularly enhanced in the former, probably by contribution of organic matter associated with oil produced water. In comparison, the composition of the Southern aquifer is mainly influenced by halite dissolution. Fresh water from the Local environment percolates into the Northern and the Southern environments. Mixing between these three aquifers may enhance bacterial sulfate reduction, thus increasing the H2S concentration in the sulfidic springs. The integration of the geochemical attributes and the aquatic communities at each watershed will produce a more comprehensive view of these spring ecosystems and their temporal and spatial evolution.

Spatial distribution of bisphenol S in surface water and human serum from Yangtze River watershed, China: Implications for exposure through drinking water.

PubMed

Wan, Yanjian; Xia, Wei; Yang, Shunyi; Pan, Xinyun; He, Zhenyu; Kannan, Kurunthachalam

2018-05-01

Bisphenol S (BPS) is an emerging environmental contaminant. The occurrence of this compound in humans and the environment is not well described. In this study, 120 surface water samples and 240 human serum samples were collected along the Yangtze River in 2015 for the determination of the occurrence of BPS. Surface water and human serum samples were extracted by solid phase extraction and liquid-liquid extraction, respectively, and analyzed by ultra-high performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). BPS was detected in all river water samples at concentrations that ranged from 0.18 to 14.9 ng/L (median: 0.98 ng/L), with higher concentrations in spring than summer. The median estimated daily intake (EDI) of BPS through water ingestion by infants in spring and summer was 0.12 and 0.06 ng/kg body weight (bw)/day, respectively. BPS was detected in human serum with the highest concentrations in samples from Nanjing (median: 0.65 ng/mL, maximum: 169 ng/mL) among the four cities studied. No significant gender related difference in BPS concentrations was observed in human sera, while higher concentrations were found in younger individuals than elderly. The EDI of BPS calculated based on serum concentrations of adults in Nanjing was 22.8 ng/kg bw/day. Ingestion of water accounted for <1% of the total BPS intake by the Chinese population. This is the first report of the occurrence of BPS in water from the Yangtze River and human serum from several cities located along this river in China. Copyright © 2018 Elsevier Ltd. All rights reserved.

Ground-Water, Surface-Water, and Water-Chemistry Data, Black Mesa Area, Northeastern Arizona - 2006-07

USGS Publications Warehouse

Truini, Margot; Macy, J.P.

2008-01-01

The N aquifer is the major source of water in the 5,400 square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use and the needs of a growing population. Precipitation in the Black Mesa area is typically about 6 to 14 inches per year. The water-monitoring program in the Black Mesa area began in 1971 and is designed to provide information about the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected for the monitoring program in the Black Mesa area from January 2006 to September 2007. The monitoring program includes measurements of (1) ground-water withdrawals, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, and (5) ground-water chemistry. Periodic testing of ground-water withdrawal meters is completed every 4 to 5 years. The Navajo Tribal Utility Authority (NTUA) yearly totals for the ground-water metered withdrawal data were unavailable in 2006 due to an up-grade within the NTUA computer network. Because NTUA data is often combined with Bureau of Indian Affairs data for the total withdrawals in a well system, withdrawals will not be published in this year's annual report. From 2006 to 2007, annually measured water levels in the Black Mesa area declined in 3 of 11 wells measured in the unconfined areas of the N aquifer, and the median change was 0.0 feet. Measurements indicated that water levels declined in 8 of 17 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was 0.2 feet. From the prestress period (prior to 1965) to 2007, the median water-level change for 30 wells was -11.1 feet. Median water-level changes were 2.9 feet for 11 wells measured in the unconfined areas and -40.2 feet for 19 wells measured in the confined area. Spring flow was measured once in 2006 and once in 2007 at Moenkopi School Spring. Flow decreased by 18.9 percent at Moenkopi School Spring. During the period of record, flow fluctuated, and a decreasing trend was apparent. Continuous records of surface-water discharge in the Black Mesa area have been collected from streamflow gages at the following sites: Moenkopi Wash at Moenkopi (1976 to 2006), Dinnebito Wash near Sand Springs (1993 to 2006), Polacca Wash near Second Mesa (1994 to 2006), and Pasture Canyon Springs (August 2004 to December 2006). Median flows during November, December, January, and February of each water year were used as an index of the amount of ground-water discharge to the above named sites. For the period of record at each streamflow-gaging station, the median winter flows have generally remained even, showing neither a significant increase nor decrease in flows. There is not a long enough period of record for Pasture Canyon Spring for a trend to be apparent. In 2007, water samples were collected from 1 well and 1 spring in the Black Mesa area and were analyzed for selected chemical constituents. Concentrations of dissolved solids, chloride, and sulfate have varied at Peabody well 5 for the period of record, and there is an apparent increasing trend. Dissolved-solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 12 years of record.

Modern pollen distribution in the northeastern Indian Ocean and its significance.

PubMed

Luo, Chuanxiu; Jiang, Weiming; Chen, Chixin; Peng, Huanhuan; Xiang, Rong; Liu, Jianguo; Lu, Jun; Su, Xiang; Zhang, Qiang; Yang, Mingxi

2018-06-26

In order to provide a reference for reconstructing the paleoclimate of the northeastern Indian Ocean, 36 airborne pollen samples were analyzed using methods for airborne pollen, and 26 surface water samples were analyzed using a lab method for surface water. We found that little pollen is airborne over the Indian Ocean in spring, but airborne pollen types and concentrations can help to deduce paleomonsoon strength and direction. The conclusions included the following: (1) Pollen in the sediment was transported mainly via ocean currents instead of the early summer or spring wind. (2) Airborne pollen types and concentrations are proportional to the wind speed and inversely proportional to the pollen distance transported and depend on whether the wind is from the land or from the sea. If the wind is from the land, the pollen concentration is proportional to the angle between the wind direction and the coastline. (3) The pollen concentration in the sample collected from a water depth of 30-45 m is higher than in the samples collected from a depth of 5 m. The pollen concentration and salinity are higher in the equatorial area than in the Northern Hemisphere.

Foraging habitat for shorebirds in southeastern Missouri and its predicted future availability

USGS Publications Warehouse

Twedt, Daniel J.

2013-01-01

Water management to protect agriculture in alluvial floodplains often conflicts with wildlife use of seasonal floodwater. Such is the case along the Mississippi River in southeastern Missouri where migrating shorebirds forage in shallow-flooded fields. I estimated the current availability of habitat for foraging shorebirds within the New Madrid and St. Johns Basins based on daily river elevations (1943–2009), under assumptions that shorebirds forage in open habitat with water depth <15 cm and use mudflats for 3 days after exposure. The area of shorebird foraging habitat, based on replicated 50-year random samples, averaged 975 ha per day during spring and 33 ha per day during fall. Adjustments to account for habitat quality associated with different water depths, duration of mudflat exposure, intra-seasonal availability, and state of agricultural crops, indicated the equivalent of 494 ha daily of optimal habitat during spring and 11 ha during fall. Proposed levees and pumps to protect cropland would reduce shorebird foraging habitat by 80 %: to 211 ha (108 optimal ha) per day during spring and 9 ha (<3 optimal ha) per day during fall. Alternative water management that allows natural flooding below a prescribed elevation would retain nearly all existing shorebird foraging habitat during fall and about 60 % of extant habitat during spring.

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona: 2011-2012

USGS Publications Warehouse

Macy, Jamie P.; Unema, Joel A.

2014-01-01

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area. Precipitation in the area typically is between 6 and 14 inches per year. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2011 to September 2012. The monitoring program includes measurements of (1) groundwater withdrawals, (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In 2011, total groundwater withdrawals were 4,480 acre-ft, industrial withdrawals were 1,390 acre-ft, and municipal withdrawals were 3,090 acre-ft. Total withdrawals during 2011 were about 39 percent less than total withdrawals in 2005 because of Peabody Western Coal Company’s discontinued use of water to transport coal in a slurry. From 2010 to 2011 total withdrawals increased by 11 percent; industrial withdrawals increased by approximately 19 percent, and total municipal withdrawals increased by 8 percent. From 2011 to 2012, annually measured water levels in the Black Mesa area declined in 8 of 15 wells that were available for comparison in the unconfined areas of the N aquifer, and the median change was -0.1 feet. Water levels declined in 9 of 18 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was 0.0 feet. From the prestress period (prior to 1965) to 2012, the median water-level change for 34 wells in both the confined and unconfined areas was -13.4 feet; the median water-level changes were -2.1 feet for 16 wells measured in the unconfined areas and -39.1 feet for 18 wells measured in the confined area. Spring flow was measured at four springs in 2012. Flow fluctuated during the period of record for Burro and Unnamed Spring near Dennehotso, but a decreasing trend was apparent at Moenkopi School Spring and Pasture Canyon Spring. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s and discharge at Unnamed Spring near Dennehotso has fluctuated for the period of record. Trend analysis for discharge at Moenkopi and Pasture Canyon Springs yielded a slope significantly different from zero. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2010), Dinnebito Wash near Sand Springs 09401110 (1993 to 2010), Polacca Wash near Second Mesa 09400568 (1994 to 2010), and Pasture Canyon Springs 09401265 (2004 to 2010). Median winter flows (November through February) of each water year were used as an index of the amount of groundwater discharge at the above-named sites. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, and there are no significant statistical trends in groundwater discharge. In 2012, water samples collected from 10 wells and 4 springs in the Black Mesa area were analyzed for selected chemical constituents, and the results were compared with previous analyses. Concentrations of dissolved solids, chloride, and sulfate have varied at all 10 wells for the period of record, but neither increasing nor decreasing trends over time were found. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 12 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied significantly since the early 1980s, and there is no increasing or decreasing trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Burro Spring and Unnamed Spring near Dennehotso have varied for the period of record, but there is no increasing or decreasing trend in the data.

Drinking water quality in the Ethiopian section of the East African Rift Valley I--data and health aspects.

PubMed

Reimann, Clemens; Bjorvatn, Kjell; Frengstad, Bjørn; Melaku, Zenebe; Tekle-Haimanot, Redda; Siewers, Ulrich

2003-07-20

Drinking water samples were collected throughout the Ethiopian part of the Rift Valley, separated into water drawn from deep wells (deeper than 60 m), shallow wells (<60 m deep), hot springs (T>36 degrees C), springs (T<32 degrees C) and rivers. A total of 138 samples were analysed for 70 parameters (Ag, Al, As, B, Ba, Be, Bi, Br, Ca, Cd, Ce, Cl, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, In, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, NO(2), NO(3), Pb, Pr, Rb, Sb, Se, Si, Sm, Sn, SO(4), Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, temperature, pH, conductivity and alkalinity) with ion chromatography (anions), spectrometry (ICP-OES and ICP-MS, cations) and parameter-specific (e.g. titration) techniques. In terms of European water directives and WHO guidelines, 86% of all wells yield water that fails to pass the quality standards set for drinking water. The most problematic element is fluoride (F), for which 33% of all samples returned values above 1.5 mg/l and up to 11.6 mg/l. The incidence of dental and skeletal fluorosis is well documented in the Rift Valley. Another problematic element may be uranium (U)-47% of all wells yield water with concentrations above the newly suggested WHO maximum acceptable concentration (MAC) of 2 microg/l. Fortunately, only 7% of the collected samples are above the 10 microg/l EU-MAC for As in drinking water.

Analysis of interrelation between water quality and hydrologic conditions on a small karst catchment area of sinking watercourse Trbuhovica

NASA Astrophysics Data System (ADS)

Hinić, V.; Rubinić, J.; Vučković, I.; Ružić, I.; Gržetić, A.; Volf, G.; Ljubotina, M.; Kvas, N.

2008-11-01

Sinking watercourse Trbuhovica is located at the topping karst of Gorski Kotar in Croatia, near the Slovenian border. About 900 inhabitants live in Trbuhovica catchment area. Sewage system had not been built. The project KEEP WATERS CLEAN (INTERREG III A project) was approved by EU commission and has a purpose of investigating water resources of that area, their appropriate protection and improving management of those resources. This paper presents project's 1st phase investigation results: hydrologic conditions and water quality at several locations on stream and at the springs of Trbuhovica, Mlake and Obrh. Climatologic (precipitation, air temperature and snow cover), basic hydrologic characteristics (flow and water temperature), water quality parameters (pH, electric conductivity, alkalinity, oxygen regime, nutrients and mineral oils) and microbiology indicators have been monitored. Samples of micro invertebrates and samples of periphyton have been collected in the field. Biological results have been elaborated via Saprobial Index according to Pantle-Buck. Analyses results showed a strong connection between hydrologic condition and selected water quality parameters. The groundwater quality changes are very quick. Maximum pollutions occur during the period of intensive rain. Water at the spring of Mlaka is very clean and is classified in the first to second water category, while Trbuhovica shows higher organic pollution.

Data compilation and assessment for water resources in Pennsylvania state forest and park lands

USGS Publications Warehouse

Galeone, Daniel G.

2011-01-01

As a result of a cooperative study between the U.S. Geological Survey and the Pennsylvania Department of Conservation and Natural Resources (PaDCNR), available electronic data were compiled for Pennsylvania state lands (state forests and parks) to allow PaDCNR to initially determine if data exist to make an objective evaluation of water resources for specific basins. The data compiled included water-quantity and water-quality data and sample locations for benthic macroinvertebrates within state-owned lands (including a 100-meter buffer around each land parcel) in Pennsylvania. In addition, internet links or contacts for geographic information system coverages pertinent to water-resources studies also were compiled. Water-quantity and water-quality data primarily available through January 2007 were compiled and summarized for site types that included streams, lakes, ground-water wells, springs, and precipitation. Data were categorized relative to 35 watershed boundaries defined by the Pennsylvania Department of Environmental Protection for resource-management purposes. The primary sources of continuous water-quantity data for Pennsylvania state lands were the U.S. Geological Survey (USGS) and the National Weather Service (NWS). The USGS has streamflow data for 93 surface-water sites located in state lands; 38 of these sites have continuous-recording data available. As of January 2007, 22 of these 38 streamflow-gaging stations were active; the majority of active gaging stations have over 40 years of continuous record. The USGS database also contains continuous ground-water elevation data for 32 wells in Pennsylvania state lands, 18 of which were active as of January 2007. Sixty-eight active precipitation stations (primarily from the NWS network) are located in state lands. The four sources of available water-quality data for Pennsylvania state lands were the USGS, U.S. Environmental Protection Agency, Pennsylvania Department of Environmental Protection (PaDEP), and the Susquehanna River Basin Commission. The water-quality data, which were primarily collected after 1970, were summarized by categorizing the analytical data for each site into major groups (for example, trace metals, pesticides, major ions, etc.) for each type (streams, lakes, ground-water wells, and springs) of data compiled. The number of samples and number of detections for each analyte within each group also were summarized. A total of 410 stream sites and 205 ground-water wells in state lands had water-quality data from the available data sets, and these sites were well-distributed across the state. A total of 107 lakes and 47 springs in state lands had water-quality data from the available data sets, but these data types were not well-distributed across the state; the majority of water-quality data for lakes was in the western or eastern sections of the state and water-quality data for springs was primarily located in the central part of the Lower Susquehanna River Valley. The most common types of water-quality data collected were major ions, trace elements, and nutrients. Physical parameters, such as water temperature, stream discharge, or water level, typically were collected for most water-quality samples. Given the large database available from PaDEP for benthic macroinvertebrates, along with some data from other agencies, there is very good distribution of benthic-macroinvertebrate data for state lands. Benthic macroinvertebrate samples were collected at 1,077 locations in state lands from 1973 to 2006. Most (980 samples) of the benthic-macroinvertebrate samples were collected by PaDEP as part of the state assessment of stream conditions required by the Clean Water Act. Data compiled in this report can be used for various water-resource issues, such as basin-wide water-budget analysis, studies of ecological or instream flow, or water-quality assessments. The determination of an annual water budget in selected basins is best supported by the availab

Hydrogeologic characteristics of four public drinking-water supply springs in northern Arkansas

USGS Publications Warehouse

Galloway, Joel M.

2004-01-01

In October 2000, a study was undertaken by the U.S. Geological Survey (USGS) in cooperation with the Arkansas Department of Health to determine the hydrogeologic characteristics, including the extent of the recharge areas, for Hughes Spring, Stark Spring, Evening Shade Spring, and Roaring Spring, which are used for public-water supply in northern Arkansas. Information pertaining to each spring can be used to enable development of effective management plans to protect these water resources and public health. An integrated approach to determine the ground-water characteristics and the extent of the local recharge areas of the four springs incorporated tools and methods of hydrology, structural geology, geomorphology, geophysics, and geochemistry. Analyses of discharge, temperature, and water quality were completed to describe ground-water flow characteristics, source-water characteristics, and connectivity of the ground-water system with surface runoff. Water-level contour maps were constructed to determine ground-water flow directions and ground-water tracer tests were conducted to determine the extent of the recharge areas and ground-water flow velocities. Hughes Spring supplies water for the city of Marshall, Arkansas, and the surrounding area. The mean annual discharge for Hughes Spring was 2.9 and 5.2 cubic feet per second for water years 2001 and 2002, respectively. Recharge to the spring occurs mainly from the Boone Formation (Springfield Plateau aquifer). Ground-water tracer tests indicate the recharge area for Hughes Spring generally coincides with the surface drainage area (15.8 square miles) and that Hughes Spring is connected directly to the surface flow in Brush Creek. The geochemistry of Hughes Spring demonstrated variations with flow conditions and the influence of surface-runoff in the recharge area. Calcite saturation indices, total dissolved solids concentrations, and hardness demonstrate noticeable differences with flow conditions reflecting the reduced residence time and interaction of water with the source rock within the ground-water system at higher discharges for Hughes Spring. Concentrations of fecal indicator bacteria also demonstrated a substantial increase during high-flow conditions, suggesting that a non-point source of bacteria possibly from livestock may enter the system. Conversely, nutrient concentrations did not vary with flow and were similar to concentrations reported for undeveloped sites in the Springfield Plateau and Ozark aquifers in northern Arkansas and southern Missouri. Deuterium and oxygen-18 data show that the Hughes Spring discharge is representative of direct precipitation and not influenced by water enriched in oxygen-18 through evaporation. Discharge data show that Hughes Spring is dominated by conduit type ground-water flow, but a considerable component of diffuse flow also exists in the ground-water system. Carbon-13 data indicate a substantial component of the recharge water interacts with the surface material (soil and regolith) in the recharge area before entering the ground-water system for Hughes Spring. Tritium data for Hughes Spring indicate that the discharge water is a mixture of recent recharge and sub-modern water (recharged prior to 1952). Stark Spring supplies water for the city of Cushman, Arkansas, and the surrounding area. 2 Hydrogeologic Characteristics of Four Public Drinking-Water Supply Springs in Northern Arkansas The mean annual discharge for Stark Spring was 0.5 and 1.5 cubic feet per second for water years 2001 and 2002, respectively. The discharge and water-quality data show the ground-water system for Stark Spring is dominated by rapid recharge from surface runoff and mainly consists of a conduit- type flow system with little diffuse-type flow. Analyses of discharge data show that the estimated recharge area (0.79 square mile) is larger than the surface drainage area (0.34 square mile). Ground-water tracer tests and the outcrop of the

Occurrence and risk assessment of antibiotics in surface water and groundwater from different depths of aquifers: A case study at Jianghan Plain, central China.

PubMed

Yao, Linlin; Wang, Yanxin; Tong, Lei; Deng, Yamin; Li, Yonggang; Gan, Yiqun; Guo, Wei; Dong, Chuangju; Duan, Yanhua; Zhao, Ke

2017-01-01

The occurrence of 14 antibiotics (fluoroquinolones, tetracyclines, macrolides and sulfonamides) in groundwater and surface water at Jianghan Plain was investigated during three seasons. The total concentrations of target compounds in the water samples were higher in spring than those in summer and winter. Erythromycin was the predominant antibiotic in surface water samples with an average value of 1.60μg/L, 0.772μg/L and 0.546μg/L respectively in spring, summer and winter. In groundwater samples, fluoroquinolones and tetracyclines accounted for the dominant proportion of total antibiotic residues. The vertical distributions of total antibiotics in groundwater samples from three different depths boreholes (10m, 25m, and 50m) exhibited irregular fluctuations. Consistently decreasing of antibiotic residues with increasing of depth was observed in four (G01, G02, G03 and G05) groundwater sampling sites over three seasons. However, at the sampling sites G07 and G08, the pronounced high concentrations of total antibiotic residues were detected in water samples from 50m deep boreholes instead of those at upper aquifer in winter sampling campaign, with the total concentrations of 0.201μg/L and 0.100μg/L respectively. The environmental risks posed by the 14 antibiotics were assessed by using the methods of risk quotient and mixture risk quotient for algae, daphnids and fish in surface water and groundwater. The results suggested that algae might be the aquatic organism most sensitive to the antibiotics, with the highest risk levels posed by erythromycin in surface water and by ciprofloxacin in groundwater among the 14 antibiotics. In addition, the comparison between detected antibiotics in groundwater samples and the reported effective concentrations of antibiotics on denitrification by denitrifying bacteria, indicating this biogeochemical process driven by microorganisms won't be inhibitory influenced by the antibiotic residues in groundwater. Copyright © 2016. Published by Elsevier Inc.

Selective Phylogenetic Analysis Targeted at 16S rRNA Genes of Thermophiles and Hyperthermophiles in Deep-Subsurface Geothermal Environments

PubMed Central

Kimura, Hiroyuki; Sugihara, Maki; Kato, Kenji; Hanada, Satoshi

2006-01-01

Deep-subsurface samples obtained by deep drilling are likely to be contaminated with mesophilic microorganisms in the drilling fluid, and this could affect determination of the community structure of the geothermal microflora using 16S rRNA gene clone library analysis. To eliminate possible contamination by PCR-amplified 16S rRNA genes from mesophiles, a combined thermal denaturation and enzyme digestion method, based on a strong correlation between the G+C content of the 16S rRNA gene and the optimum growth temperatures of most known prokaryotic cultures, was used prior to clone library construction. To validate this technique, hot spring fluid (76°C) and river water (14°C) were used to mimic a deep-subsurface sample contaminated with drilling fluid. After DNA extraction and PCR amplification of the 16S rRNA genes from individual samples separately, the amplified products from river water were observed to be denatured at 82°C and completely digested by exonuclease I (Exo I), while the amplified products from hot spring fluid remained intact after denaturation at 84°C and enzyme digestion with Exo I. DNAs extracted from the two samples were mixed and used as a template for amplification of the 16S rRNA genes. The amplified rRNA genes were denatured at 84°C and digested with Exo I before clone library construction. The results indicated that the 16S rRNA gene sequences from the river water were almost completely eliminated, whereas those from the hot spring fluid remained. PMID:16391020

Climatic Events and Historical Disturbances Control Acute and Chronic Water-Quality Impairment After Wildfire

NASA Astrophysics Data System (ADS)

Murphy, S. F.; Martin, D. A.; McCleskey, R. B.; Writer, J. H.

2016-12-01

Many studies have shown that surface water quality can be impaired after wildfire. The majority of these studies are typically conducted for short periods (1-2 years), and until recently, usually employed routine (fixed-interval) sampling. We monitored stream water quality for five years after a wildfire in the Colorado Front Range using a combination of routine sampling, storm sampling, and continuous sensors. This five-year study facilitated the measurement of post-wildfire water-quality response to a number of climatic events, including low- to moderate-intensity rain storms, drought, extreme rainfall (based on amount of rain that fell in a 7-day period), and the highest spring runoff recorded from the watershed during 23 years of record. Post-wildfire water quality was controlled by the hydrologic response to these climatic events, and by a legacy of historical disturbance from mining and related activities. Increased surface runoff during rain storms led to mobilization of sediment from hillslopes to stream channels. The sediment remained in stream channels during a drought that led to reduced (25% of mean) spring runoff, but this sediment, and associated constituents such as dissolved organic carbon and manganese, were remobilized into the water column and transported downstream during sustained high-flow spring runoff in the third year. We infer that the relative proportions of surface and subsurface runoff were altered by the wildfire and during the extreme rainfall, possibly leading to greater flow through abandoned mine adits and tunnels, and thus causing increased instream metal concentrations (such as arsenic and manganese). Post-wildfire water-quality issues were both acute, with significant water-quality impairment during storm events, and chronic, with elevated concentrations of sediment, nitrate, dissolved organic carbon, manganese, and arsenic for months to years after the wildfire. Such variable source water quality, in both contaminant type and concentration, presents a substantial challenge to water-treatment facilities. Climate change is projected to increase wildfire risk and possibly storm frequency and intensity, and thus the risk of wildfire impacts on water supplies is likely to worsen in the future.

Spring runoff water-chemistry data from the Standard Mine and Elk Creek, Gunnison County, Colorado, 2010

USGS Publications Warehouse

Manning, Andrew H.; Verplanck, Philip L.; Mast, M. Alisa; Marsik, Joseph; McCleskey, R. Blaine

2011-01-01

Water samples were collected approximately every two weeks during the spring of 2010 from the Level 1 portal of the Standard Mine and from two locations on Elk Creek. The objective of the sampling was to: (1) better define the expected range and timing of variations in pH and metal concentrations in Level 1 discharge and Elk Creek during spring runoff; and (2) further evaluate possible mechanisms controlling water quality during spring runoff. Samples were analyzed for major ions, selected trace elements, and stable isotopes of oxygen and hydrogen (oxygen-18 and deuterium). The Level 1 portal sample and one of the Elk Creek samples (EC-CELK1) were collected from the same locations as samples taken in the spring of 2007, allowing comparison between the two different years. Available meteorological and hydrologic data suggest that 2010 was an average water year and 2007 was below average. Field pH and dissolved metal concentrations in Level 1 discharge had the following ranges: pH, 2.90 to 6.23; zinc, 11.2 to 26.5 mg/L; cadmium, 0.084 to 0.158 mg/L; manganese, 3.23 to 10.2 mg/L; lead, 0.0794 to 1.71 mg/L; and copper, 0.0674 to 1.14 mg/L. These ranges were generally similar to those observed in 2007. Metal concentrations near the mouth of Elk Creek (EC-CELK1) were substantially lower than in 2007. Possible explanations include remedial efforts at the Standard Mine site implemented after 2007 and greater dilution due to higher Elk Creek flows in 2010. Temporal patterns in pH and metal concentrations in Level 1 discharge were similar to those observed in 2007, with pH, zinc, cadmium, and manganese concentrations generally decreasing, and lead and copper generally increasing during the snowmelt runoff period. Zinc and cadmium concentrations were inversely correlated with flow and thus apparently dilution-controlled. Lead and copper concentrations were inversely correlated with pH and thus apparently pH-controlled. Zinc, cadmium, and manganese concentrations near the mouth of Elk Creek did not display the pronounced increase observed during high flow in 2007, again perhaps due to remedial activities at the mine site or greater dilution in 2010. Zinc and cadmium loads near the mouth of Elk Creek were generally greater than those at the Level 1 portal for the six sample days in 2010. Whereas metal loads in September 2007 suggested that Level 1 portal discharge was the primary source of metals to the creek, metal loads computed for this study suggest that this may not have been the case in the spring of 2010. d18O values are well correlated with flow, becoming lighter (more negative) during snowmelt in both Level 1 discharge and Elk Creek. Seasonal variations in the chemistry of Level 1 discharge, along with portal flow tracking very closely with creek flow, are consistent with geochemical and environmental tracer data from 2007 that indicate short residence times (<1 year) for groundwater discharging from the Standard Mine.

Determination of acidic pharmaceuticals and potential endocrine disrupting compounds in wastewaters and spring waters by selective elution and analysis by gas chromatography-mass spectrometry.

PubMed

Gibson, Richard; Becerril-Bravo, Elías; Silva-Castro, Vanessa; Jiménez, Blanca

2007-10-26

Although the trend in development of analytical methods for emerging contaminants is towards reduced sample preparation and increased detector selectivity, there are still benefits from removal of matrix material during sample preparation. This paper describes a simple method for acidic pharmaceuticals and a range of potential endocrine disrupting compounds in untreated wastewaters and spring waters. It is based on separation of the two classes during elution from the extraction cartridge with final analysis by gas chromatography-mass spectrometry. 3,4-D was used as the recovery standard for the acids while 4-n-nonylphenol and [2H4]estrone were used for the endocrine disrupters; mean recoveries varied between 89% and 111%. The method was also extensively validated by fortification with the target compounds. Recoveries of acids were from 68% to 97% with relative standard deviations generally less than 10% and recoveries of endocrine disrupters were 68-109% with relative standard deviations less than 20%. Detection limits varied from 0.005 to 1 ng/L in spring water, and from 0.5 to 100 ng/L in untreated wastewater. Concentrations of the analytes in the wastewater ranged from 0.018 to 22.4 microg/L. Values were comparable to reported data, although concentrations were generally relatively high, probably because of a lack of treatment. Triclosan, phthalates, estrone, 17beta-estradiol, ibuprofen, and naproxen were present in the spring water from aquifers recharged indirectly with this wastewater after its use for irrigation; concentrations ranged from 0.01 to 25.0 ng/L. The much lower concentrations compared to wastewater indicate effective removal processes on passage through the soil and subsoil.

The spectral absorption coefficient at 254 nm as a real-time early warning proxy for detecting faecal pollution events at alpine karst water resources.

PubMed

Stadler, H; Klock, E; Skritek, P; Mach, R L; Zerobin, W; Farnleitner, A H

2010-01-01

Because spring water quality from alpine karst aquifers can change very rapidly during event situations, water abstraction management has to be performed in near real-time. Four summer events (2005-2008) at alpine karst springs were investigated in detail in order to evaluate the spectral absorption coefficient at 254 nm (SAC254) as a real-time early warning proxy for faecal pollution. For the investigation Low-Earth-Orbit (LEO) Satellite-based data communication between portable hydrometeorological measuring stations and an automated microbiological sampling device was used. The method for event triggered microbial sampling and analyzing was already established and described in a previous paper. Data analysis including on-line event characterisation (i.e. precipitation, discharge, turbidity, SAC254) and comprehensive E. coli determination (n>800) indicated that SAC254 is a useful early warning proxy. Irrespective of the studied event situations SAC254 always increased 3 to 6 hours earlier than the onset of faecal pollution, featuring different correlation phases. Furthermore, it seems also possible to use SAC254 as a real-time proxy parameter for estimating the extent of faecal pollution after establishing specific spring and event-type calibrations that take into consideration the variability of the occurrence and the transferability of faecal material It should be highlighted that diffuse faecal pollution from wildlife and live stock sources was responsible for spring water contamination at the investigated catchments. In this respect, the SAC254 can also provide useful information to support microbial source tracking efforts where different situations of infiltration have to be investigated.

Probability-based classifications for spatially characterizing the water temperatures and discharge rates of hot springs in the Tatun Volcanic Region, Taiwan.

PubMed

Jang, Cheng-Shin

2015-05-01

Accurately classifying the spatial features of the water temperatures and discharge rates of hot springs is crucial for environmental resources use and management. This study spatially characterized classifications of the water temperatures and discharge rates of hot springs in the Tatun Volcanic Region of Northern Taiwan by using indicator kriging (IK). The water temperatures and discharge rates of the springs were first assigned to high, moderate, and low categories according to the two thresholds of the proposed spring classification criteria. IK was then used to model the occurrence probabilities of the water temperatures and discharge rates of the springs and probabilistically determine their categories. Finally, nine combinations were acquired from the probability-based classifications for the spatial features of the water temperatures and discharge rates of the springs. Moreover, various combinations of spring water features were examined according to seven subzones of spring use in the study region. The research results reveal that probability-based classifications using IK provide practicable insights related to propagating the uncertainty of classifications according to the spatial features of the water temperatures and discharge rates of the springs. The springs in the Beitou (BT), Xingyi Road (XYR), Zhongshanlou (ZSL), and Lengshuikeng (LSK) subzones are suitable for supplying tourism hotels with a sufficient quantity of spring water because they have high or moderate discharge rates. Furthermore, natural hot springs in riverbeds and valleys should be developed in the Dingbeitou (DBT), ZSL, Xiayoukeng (XYK), and Macao (MC) subzones because of low discharge rates and low or moderate water temperatures.

The question of recharge to the deep thermal reservoir underlying the geysers and hot springs of Yellowstone National Park: Chapter H in Integrated geoscience studies in Integrated geoscience studies in the Greater Yellowstone Area—Volcanic, tectonic, and hydrothermal processes in the Yellowstone geoecosystem

USGS Publications Warehouse

Rye, Robert O.; Truesdell, Alfred Hemingway; Morgan, Lisa A.

2007-01-01

The extraordinary number, size, and unspoiled beauty of the geysers and hot springs of Yellowstone National Park (the Park) make them a national treasure. The hydrology of these special features and their relation to cold waters of the Yellowstone area are poorly known. In the absence of deep drill holes, such information is available only indirectly from isotope studies. The δD-δ18O values of precipitation and cold surface-water and ground-water samples are close to the global meteoric water line (Craig, 1961). δD values of monthly samples of rain and snow collected from 1978 to 1981 at two stations in the Park show strong seasonal variations, with average values for winter months close to those for cold waters near the collection sites. δD values of more than 300 samples from cold springs, cold streams, and rivers collected during the fall from 1967 to 1992 show consistent north-south and east-west patterns throughout and outside of the Park, although values at a given site vary by as much as 8 ‰ from year to year. These data, along with hot-spring data (Truesdell and others, 1977; Pearson and Truesdell, 1978), show that ascending Yellowstone thermal waters are modified isotopically and chemically by a variety of boiling and mixing processes in shallow reservoirs. Near geyser basins, shallow recharge waters from nearby rhyolite plateaus dilute the ascending deep thermal waters, particularly at basin margins, and mix and boil in reservoirs that commonly are interconnected. Deep recharge appears to derive from a major deep thermal-reservoir fluid that supplies steam and hot water to all geyser basins on the west side of the Park and perhaps in the entire Yellowstone caldera. This water (T ≥350°C; δD = –149±1 ‰) is isotopically lighter than all but the farthest north, highest altitude cold springs and streams and a sinter-producing warm spring (δD = –153 ‰) north of the Park. Derivation of this deep fluid solely from present-day recharge is problematical. The designation of source areas depends on assumptions about the age of the deep water, which in turn depend on assumptions about the nature of the deep thermal system. Modeling, based on published chloride-flux studies of thermal waters, suggests that for a 0.5- to 4-km-deep reservoir the residence time of most of the thermal water could be less than 1,900 years, for a piston-flow model, to more than 10,000 years, for a well-mixed model. For the piston-flow model, the deep system quickly reaches the isotopic composition of the recharge in response to climate change. For this model, stable-isotope data and geologic considerations suggest that the most likely area of recharge for the deep thermal water is in the northwestern part of the Park, in the Gallatin Range, where major north-south faults connect with the caldera. This possible recharge area for the deep thermal water is at least 20 km, and possibly as much as 70 km, from outflow in the thermal areas, indicating the presence of a hydrothermal system as large as those postulated to have operated around large, ancient igneous intrusions. For this model, the volume of isotopically light water infiltrating in the Gallatin Range during our sampling period is too small to balance the present outflow of deep water. This shortfall suggests that some recharge possibly occurred during a cooler time characterized by greater winter precipitation, such as during the Little Ice Age in the 15th century. However, this scenario requires exceptionally fast flow rates of recharge into the deep system. For the well-mixed model, the composition of the deep reservoir changes slowly in response to climate change, and a significant component of the deep thermal water could have recharged during Pleistocene glaciation. The latter interpretation is consistent with the recent discovery of warm waters in wells and springs in southern Idaho that have δD values 10–20 ‰ lower than the winter snow for their present-day high-level recharge. These waters have been interpreted to be Pleistocene in age (Smith and others, 2002). The well-mixed model permits a significant component of recharge water for the deep system to have δD values less negative than –150 ‰ and consequently for the deep system recharge to be closer to the caldera at a number of possible localities in the Park.

Effects of groundwater withdrawals from the Hurricane Fault zone on discharge of saline water from Pah Tempe Springs, Washington County, Utah

USGS Publications Warehouse

Gardner, Philip M.

2018-04-10

Pah Tempe Springs, located in Washington County, Utah, contribute about 95,000 tons of dissolved solids annually along a 1,500-foot gaining reach of the Virgin River. The river gains more than 10 cubic feet per second along the reach as thermal, saline springwater discharges from dozens of orifices located along the riverbed and above the river on both banks. The spring complex discharges from fractured Permian Toroweap Limestone where the river crosses the north-south trending Hurricane Fault. The Bureau of Reclamation Colorado River Basin Salinity Control Program is evaluating the feasibility of capturing and desalinizing the discharge of Pah Tempe Springs to improve downstream water quality in the Virgin River. The most viable plan, identified by the Bureau of Reclamation in early studies, is to capture spring discharge by pumping thermal groundwater from within the Hurricane Fault footwall damage zone and to treat this water prior to returning it to the river.Three multiple-day interference tests were conducted between November 2013 and November 2014, wherein thermal groundwater was pumped from fractured carbonate rock in the fault damage zone at rates of up to 7 cubic feet per second. Pumping periods for these tests lasted approximately 66, 74, and 67 hours, respectively, and the tests occurred with controlled streamflows of approximately 2.0, 3.5, and 24.5 cubic feet per second, respectively, in the Virgin River upstream from the springs reach. Specific conductance, water temperature, and discharge were monitored continuously in the river (upstream and downstream of the springs reach) at selected individual springs, and in the pumping discharge during each of the tests. Water levels were monitored in three observation wells screened in the thermal system. Periodic stream and groundwater samples were analyzed for dissolved-solids concentration and the stable isotopes of oxygen and hydrogen. Additional discrete measurements of field parameters (specific conductance, water temperature, pH, and discharge) were made at up to 26 sites along the springs reach. These data demonstrate the interaction between the saline, thermal groundwater system and the Virgin River, and provide estimates of reductions in dissolved-solids loads to the river.The interference tests show that pumping thermal groundwater from the shallow carbonate aquifer adjacent to the springs is effective at capturing high dissolved-solids loads discharging from Pah Tempe Springs before they enter the Virgin River. Discharge measurements made in the Virgin River downstream of the springs reach show that streamflow is reduced by approximately the amount pumped, indicating that complete capture of thermal discharge is possible. During the February 2014 test, the dissolved-solids load removed by pumping (190 tons per day) was approximately equal to the dissolved-solids load reduction observed in the river below the springs reach, indicating near 100-percent efficient capture of spring-sourced dissolved solids. However, an observed decrease in temperature and specific conductance of the pumping discharge during the high-flow test in November 2014 showed that capture of the cool, fresh river water can occur and is more likely at a higher stage in the Virgin River.

Water quality and quantity of selected springs and seeps along the Colorado River corridor, Utah and Arizona: Arches National Park, Canyonlands National Park, Glen Canyon National Recreation Area, and Grand Canyon National Park, 1997-98

USGS Publications Warehouse

Taylor, Howard E.; Spence, John R.; Antweiler, Ronald C.; Berghoff, Kevin; Plowman, Terry I.; Peart, Dale B.; Roth, David A.

2004-01-01

The U.S. Geological Survey, in cooperation with the National Park Service conducted an intensive assessment of selected springs along the Colorado River Corridor in Arches National Park, Canyonlands National Park, Glen Canyon National Recreation Area, and Grand Canyon National Park in 1997 and 1998, for the purpose of measuring and evaluating the water quality and quantity of the resource. This study was conducted to establish baseline data for the future evaluation of possible effects from recreational use and climate change. Selected springs and seeps were visited over a study period from 1997 to 1998, during which, discharge and on-site chemical measurements were made at selected springs and seeps, and samples were collected for subsequent chemical laboratory analysis. This interdisciplinary study also includes simultaneous studies of flora and fauna, measured and sampled coincidently at the same sites. Samples collected during this study were transported to U.S. Geological Survey laboratories in Boulder, Colorado, where analyses were performed using state-of-the-art laboratory technology. The location of the selected springs and seeps, elevation, geology, aspect, and onsite measurements including temperature, discharge, dissolved oxygen, pH, and specific conductance, were recorded. Laboratory analyses include determinations for alkalinity, aluminum, ammonium (nitrogen), antimony, arsenic, barium, beryllium, bismuth, boron, bromide, cadmium, calcium, cerium, cesium, chloride, chromium, cobalt, copper, dissolved inorganic carbon, dissolved organic carbon, dysprosium, erbium, europium, fluoride, gadolinium, holmium, iodine, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, nitrate (nitrogen), nitrite (nitrogen), phosphate, phosphorus, potassium, praseodymium, rhenium, rubidium, samarium, selenium, silica, silver, sodium, strontium, sulfate, tellurium, terbium, thallium, thorium, thulium, tin, titanium, tungsten, uranium, vanadium, yttrium, ytterbium, zinc, and zirconium in these springs and seeps. Biological observations include physical setting, vegetation, invertebrate habitats, and invertebrate microhabitats.

Water-quality and ground-water-level data, Bernalillo County, central New Mexico, 1995

USGS Publications Warehouse

Rankin, D.R.

1996-01-01

Water-quality and ground-water-level data were collected in two areas of eastern Bernalillo County in central New Mexico between March and July of 1995. Fifty-one wells, two springs, and the Ojo Grande Acequia in the east mountain area of Bernalillo County and nine wells in the northeast area of the city of Albuquerque were sampled. The water samples were analyzed for selected nutrient species; total organic carbon; major dissolved constituents; dissolved arsenic, boron, iron, and manganese; and methylene blue active substances. Analytical results were used to compute hardness, sodium adsorption ratio, and dissolved solids. Specific conductance, pH, temperature, and alkalinity were measured in the field at the time of sample collection. Ground- water-level and well-depth measurements were made at the time of sample collection when possible. Water-quality data, ground- water-level data, and well-depth data are presented in tabular form.

Hydrology of the coastal springs ground-water basin and adjacent parts of Pasco, Hernando, and Citrus Counties, Florida

USGS Publications Warehouse

Knochenmus, Lari A.; Yobbi, Dann K.

2001-01-01

The coastal springs in Pasco, Hernando, and Citrus Counties, Florida consist of three first-order magnitude springs and numerous smaller springs, which are points of substantial ground-water discharge from the Upper Floridan aquifer. Spring flow is proportional to the water-level altitude in the aquifer and is affected primarily by the magnitude and timing of rainfall. Ground-water levels in 206 Upper Floridan aquifer wells, and surface-water stage, flow, and specific conductance of water from springs at 10 gaging stations were measured to define the hydrologic variability (temporally and spatially) in the Coastal Springs Ground-Water Basin and adjacent parts of Pasco, Hernando, and Citrus Counties. Rainfall at 46 stations and ground-water withdrawals for three counties, were used to calculate water budgets, to evaluate long-term changes in hydrologic conditions, and to evaluate relations among the hydrologic components. Predictive equations to estimate daily spring flow were developed for eight gaging stations using regression techniques. Regression techniques included ordinary least squares and multiple linear regression techniques. The predictive equations indicate that ground-water levels in the Upper Floridan aquifer are directly related to spring flow. At tidally affected gaging stations, spring flow is inversely related to spring-pool altitude. The springs have similar seasonal flow patterns throughout the area. Water-budget analysis provided insight into the relative importance of the hydrologic components expected to influence spring flow. Four water budgets were constructed for small ground-water basins that form the Coastal Springs Ground-Water Basin. Rainfall averaged 55 inches per year and was the only source of inflow to the Basin. The pathways for outflow were evapotranspiration (34 inches per year), runoff by spring flow (8 inches per year), ground-water outflow from upward leakage (11 inches per year), and ground-water withdrawal (2 inches per year). Recharge (rainfall minus evapotranspiration) to the Upper Floridan aquifer consists of vertical leakage through the surficial deposits. Discharge is primarily through springs and diffuse upward leakage that maintains the extensive swamps along the Gulf of Mexico. The ground-water basins had slightly different partitioning of hydrologic components, reflecting variation among the regions. Trends in hydrologic data were identified using nonparametric statistical techniques to infer long-term changes in hydrologic conditions, and yielded mixed results. No trend in rainfall was detected during the past century. No trend in spring flow was detected in 1931-98. Although monotonic trends were not detected, rainfall patterns are naturally variable from month to month and year to year; this variability is reflected in ground-water levels and spring flows. A decreasing trend in ground-water levels was detected in the Weeki Wachee well (1966-98), but the trend was statistically weak. At current ground-water withdrawal rates, there is no discernible affect on ground-water levels and spring flows. Sporadic data records, lack of continuous data, and inconsistent periods of record among the hydrologic components impeded analysis of long-term changes to the hydrologic system and interrelations among components. The ongoing collection of hydrologic data from index sites could provide much needed information to assess the hydrologic factors affecting the quantity and quality of spring flow in the Coastal Springs Ground-Water Basin.

Comparison of Estimated Areas Contributing Recharge to Selected Springs in North-Central Florida by Using Multiple Ground-Water Flow Models

USGS Publications Warehouse

Shoemaker, W. Barclay; O'Reilly, Andrew M.; Sepúlveda, Nicasio; Williams, Stanley A.; Motz, Louis H.; Sun, Qing

2004-01-01

Areas contributing recharge to springs are defined in this report as the land-surface area wherein water entering the ground-water system at the water table eventually discharges to a spring. These areas were delineated for Blue Spring, Silver Springs, Alexander Springs, and Silver Glen Springs in north-central Florida using four regional ground-water flow models and particle tracking. As expected, different models predicted different areas contributing recharge. In general, the differences were due to different hydrologic stresses, subsurface permeability properties, and boundary conditions that were used to calibrate each model, all of which are considered to be equally feasible because each model matched its respective calibration data reasonably well. To evaluate the agreement of the models and to summarize results, areas contributing recharge to springs from each model were combined into composite areas. During 1993-98, the composite areas contributing recharge to Blue Spring, Silver Springs, Alexander Springs, and Silver Glen Springs were about 130, 730, 110, and 120 square miles, respectively. The composite areas for all springs remained about the same when using projected 2020 ground-water withdrawals.

Chemical changes in spring waters at Tacaná volcano, Chiapas, Mexico: A possible precursor of the May 1986 seismic crisis and phreatic explosion

NASA Astrophysics Data System (ADS)

de la Cruz-Reyna, S.; Armienta, M. A.; Zamora, V.; Juárez, F.

1989-09-01

Local seismic activity consisting of sharp earthquakes accompanied by thunderous noise was reported starting in late December 1985 around Tacaná volcano (15.13°N, 92.10°W). Portable seismic stations were established in the area by late January 1986 and sampling of the only known thermal spring on the volcano flanks started at the same time. A marked increase in SO 42- concentration in the spring water preceded by two months the occurrence of a seismic swarm crisis and a small phreatic explosion. A model involving a crystalline basement fractured by tectonic stresses is proposed to explain the chemical and seismic anomalies, and the consequences on risk of volcanic activity are briefly discussed in terms of the observed behaviour.

Temporal analyses of Salmonellae in a headwater spring ecosystem reveals the effects of precipitation and runoff events.

PubMed

Gaertner, James P; Garres, Tiffany; Becker, Jesse C; Jimenez, Maria L; Forstner, Michael R J; Hahn, Dittmar

2009-03-01

Sediments and water from the spring and slough arm of Spring Lake, the pristine headwaters of the San Marcos River, Texas, were analyzed for Salmonellae by culture and molecular techniques before and after three major precipitation events, each with intermediate dry periods. Polymerase chain reaction (PCR)-assisted analyses of enrichment cultures detected Salmonellae in samples after all three precipitation events, but failed to detect them immediately prior to the rainfall events. Detection among individual locations differed with respect to the precipitation event analyzed, and strains isolated were highly variable with respect to serovars. These results demonstrate that rainwater associated effects, most likely surface runoff, provide an avenue for short-term pollution of aquatic systems with Salmonellae that do not, however, appear to establish for the long-term in water nor sediments.

Hydrochemical determination of source water contributions to Lake Lungo and Lake Ripasottile (central Italy)

USGS Publications Warehouse

Archer, Claire; Noble, Paula; Kreamer, David; Piscopo, Vincenzo; Petitta, Marco; Rosen, Michael R.; Poulson, Simon R.; Piovesan, Gianluca; Mensing, Scott

2017-01-01

Lake Lungo and Lake Ripasottile are two shallow (4-5 m) lakes located in the Rieti Basin, central Italy, that have been described previously as surface outcroppings of the groundwater table. In this work, the two lakes as well as springs and rivers that represent their potential source waters are characterized physio-chemically and isotopically, using a combination of environmental tracers. Temperature and pH were measured and water samples were analyzed for alkalinity, major ion concentration, and stable isotope (δ2H, δ18O, δ13C of dissolved inorganic carbon, and δ34S and δ18O of sulfate) composition. Chemical data were also investigated in terms of local meteorological data (air temperature, precipitation) to determine the sensitivity of lake parameters to changes in the surrounding environment. Groundwater represented by samples taken from Santa Susanna Spring was shown to be distinct with SO42- and Mg2+ content of 270 and 29 mg/L, respectively, and heavy sulfate isotopic composition(δ34S=15.2 ‰ and δ18O=10‰). Outflow from the Santa Susanna Spring enters Lake Ripasottile via a canal and both spring and lake water exhibits the same chemical distinctions and comparatively low seasonal variability. Major ion concentrations in Lake Lungo are similar to the Vicenna Riara Spring and are interpreted to represent the groundwater locally recharged within the plain. The δ13CDIC exhibit the same groupings as the other chemical parameters, providing supporting evidence of the source relationships. Lake Lungo exhibited exceptional ranges of δ13CDIC (±5 ‰) and δ2H, δ18O (±5 ‰ and ±7 ‰, respectively), attributed to sensitivity to seasonal changes. The hydrochemistry results, particularly major ion data, highlight how the two lakes, though geographically and morphologically similar, represent distinct hydrochemical facies. These data also show a different response in each lake to temperature and precipitation patterns in the basin that may be attributed to lake water retention time. The sensitivity of each lake to meteorological patterns can be used to understand the potential effects from long-term climate variability.

Major element concentrations in six Alaskan arctic rivers from melt to freeze-up

NASA Astrophysics Data System (ADS)

Douglas, T. A.; Barker, A.; Jacobson, A. D.; McClelland, J. W.; Khosh, M. S.; Lehn, G. O.

2010-12-01

It is increasingly evident that permafrost in the Arctic is responding to climate warming. An expected response to this warming is permafrost degradation and the downward migration of the seasonally thawed (active) layer into previously frozen material. This could allow weathering of previously frozen soils and influence surface water biogeochemistry in Arctic rivers. The weathering signal would most likely be evident in surface waters during summer and early fall base flow when the active layer is at its deepest extent. Studies collecting water samples from spring through late fall could capture these flows. Fieldwork in remote regions often requires long storage times for samples prior to analysis. One aspect of our study was to investigate whether waters collected for major element analyses should be preserved by acidification. We collected up to 60 surface water samples from each of six rivers between April and October, 2009. Two rivers were underlain by organic rich permafrost, two of the rivers drained mountainous bedrock, and two rivers were underlain by a combination of both bedrock and organic rich permafrost. We collected duplicate samples from each river. Samples were filtered in the field to less than 0.45 microns and collected into high density polyethylene bottles. Waters were stored for six months prior to analysis. One set of samples was analyzed without acidification while the second set was acidified with nitric acid to a pH of 2 after 6 months of storage. Concentrations of sodium, potassium, magnesium, calcium, ammonium, fluoride, chloride, nitrate, sulfate and phosphate were measured from all samples by ion chromatography. Sulfate, calcium, magnesium, sodium and potassium concentrations increase steadily through the summer from the end of spring melt into early fall. In all six rivers the potassium concentrations are unaffected by acidification. In the two streams underlain by organic rich permafrost and in one of the bedrock streams the calcium, magnesium, and sodium values are similar for both the acidified and unacidified samples. In the other rivers, however, the calcium, magnesium and sodium concentrations yield complex behavior. From spring melt into early summer the cation values are identical in the acidified and unacidified samples. However, in late summer and early fall calcium, magnesium, and sodium concentrations are roughly ten percent higher in the acidified samples than in the unacidified ones. Our results suggest an enhanced mineral weathering signal in the watersheds in the late summer which is evidenced by steadily increasing sulfate and cation concentrations throughout the summer. Potassium does not appear to be affected by acidification. Some cation species respond to acidification, especially in waters representing baseflow. However, the cause(s) for the higher values in some acidified samples is unknown.

Lentic small water bodies: Variability of pesticide transport and transformation patterns.

PubMed

Ulrich, Uta; Hörmann, Georg; Unger, Malte; Pfannerstill, Matthias; Steinmann, Frank; Fohrer, Nicola

2018-03-15

Lentic small water bodies have a high ecological potential as they fulfill several ecosystem services such as the retention of water and pollutants. They serve as a hot spot of biodiversity. Due to their location in or adjacent to agricultural fields, they can be influenced by inputs of pesticides and their transformation products. Since small water bodies have rarely been part of monitorings/campaigns up to now, their current exposure and processes guiding the pesticide input are not understood, yet. This study presents results of a sampling campaign of 10 lentic small water bodies from 2015 to 2016. They were sampled once after the spring application for a pesticide target screening, before autumn application and three times after rainfall events following the application. The autumn sampling focused on the herbicides metazachlor, flufenacet and their transformation products - oxalic acid and - sulfonic acid as representatives for common pesticides in the study region. The concentrations were associated with rainfall before and after application, characteristics of the site and the water bodies, physicochemical parameters and the applied amount of pesticides. The key results of the pesticide screening in spring indicate positive detections of pesticides which have not been applied for years to the single fields. The autumn sampling showed frequent occurrences of the transformation products, which are formed in soil, from 39% to 94% of all samples (n=71). Discharge patterns were observed for metazachlor with highest concentrations in the first sample after application and then decreasing, but not for flufenacet. The concentrations of the transformation products increased over time and revealed highest values mainly in the last sample. Besides rainfall patterns right after application, the spatial and temporal dissemination of the pesticides to the water bodies seems to play a major role to understand the exposure of lentic small water bodies. Copyright © 2017 Elsevier B.V. All rights reserved.

Dissolved nitrogen seasonal dynamics in Alaskan Arctic streams & rivers

NASA Astrophysics Data System (ADS)

Khosh, M. S.; McClelland, J. W.; Douglas, T. A.; Jacobson, A. D.; Barker, A. J.; Lehn, G. O.

2011-12-01

Over the coming century, continued warming in the Arctic is expected to bring about many changes to the region including altered precipitation regimes, earlier snowmelt, and degradation of permafrost. These alterations are likely to modify the hydrology within the region, including changes in the quantity, seasonality, and flow paths of water; all of which may impact biogeochemical processes within Arctic catchments. The anticipated responses to warming in the Arctic are likely to become most apparent during the spring snowmelt period, and in the late summer to early fall when the seasonally-thawed active layer reaches its maximum depth. While our knowledge of the seasonal dynamics of water-borne constituents in Arctic rivers is improving, the spring snowmelt and the late summer/early fall are times of the year that Arctic rivers have historically been under sampled. An improved understanding of the mechanisms that control the seasonal variability of water chemistry may help us to better understand how these systems will respond to further warming. Between May and October of 2009 and 2010 we collected surface water samples from six different rivers/streams in the Alaskan Arctic, with particular emphasis placed on sampling during the spring snowmelt and during the late summer until fall freeze-up. These rivers were selected because they represent end-member physical characteristics ranging from high gradient rivers draining predominantly bedrock to low gradient rivers draining predominantly tundra. The catchments of all six rivers are underlain by continuous permafrost and range in size from 1.6 km2 to 610 km2. Samples were analyzed for total dissolved nitrogen (TDN), nitrate (NO3-), and ammonium (NH4+). Dissolved organic nitrogen (DON) was calculated as [TDN] - [NO3-] - [NH4+]. TDN concentrations exhibited maxima in the spring and fall, but the prevailing forms of nitrogen differed markedly between the early and late periods. There were also marked differences between the tundra and bedrock dominated streams. The DON fraction comprised the majority of TDN (>90%) in all of the rivers during the spring, but the tundra-dominated sites had higher DON concentrations. Additionally, DON concentrations in the bedrock-dominated streams declined more sharply after the spring freshet than DON concentrations in the tundra-dominated streams. Beginning in mid-late July and extending through freeze-up in the fall, DIN concentrations (predominantly nitrate) increased dramatically in the bedrock-dominated streams. Indeed, by late summer and early fall DIN made up the majority of TDN (often >90%) observed at the bedrock-dominated sites. A similar trend of increasing DIN was also seen at the tundra-dominated sites, but the increase occurred later in the year (mid to late September) and the magnitude of change was smaller than that observed in the bedrock-dominated sites. Observed increases in DIN starting in mid to late summer may suggest a decrease in nitrogen assimilation rates as vegetation senesces and/or water flow paths move through deeper mineral soils.

Bio-optical properties of coastal waters in the Eastern English Channel

NASA Astrophysics Data System (ADS)

Vantrepotte, Vincent; Brunet, Christophe; Mériaux, Xavier; Lécuyer, Eric; Vellucci, Vincenzo; Santer, Richard

2007-03-01

Strong tidal currents, shallow water and numerous freshwater inputs characterize the coastal waters of the eastern English Channel. These case 2 waters were investigated through an intensive sampling effort in 2000 aiming to study the distribution and variability of the Chromophoric Dissolved Organic Matter (CDOM), Non-Algal Particles (NAP) and phytoplankton absorption at the mesoscale. Four cruises were carried out in February, March, May and July and more than 80 stations each cruise were sampled for hydrographical, chemical and bio-optical analyses. Results showed two distinct situations, the winter period characterized by the strong dominance of CDOM absorption over the particulate matter, and the spring-summer period when phytoplankton and CDOM represented the same contribution. Meteorology was the main factor driving the bio-optical properties of the water column in winter whereas in spring-summer the biological activity seemed to be the more active driving force. The algal community composition in term of dominant cell size and, therefore pigment packaging, is the main factor driving the phytoplankton specific absorption in the water column. Photoprotective pigments did not significantly influence algal absorption, due to turbid and highly mixed water masses. This feature also explained the bio-optical homogeneity found along the water column. On the mesoscale, distinct bio-optical provinces were defined in relation with the observed bio-hydrographical variability.

Differential endozoochory of aquatic invertebrates by two duck species in shallow lakes

NASA Astrophysics Data System (ADS)

Valls, Luis; Castillo-Escrivà, Andreu; Barrera, Luis; Gómez, Eulalia; Gil-Delgado, José Antonio; Mesquita-Joanes, Francesc; Armengol, Xavier

2017-04-01

Animal vectors are essential for the movement of invertebrate resting eggs between water bodies. However, differences in habitat preferences and feeding behaviour between bird species may result in variations in the dispersal of invertebrates via these birds, even if the different bird species live in the same lake. To test such effects, faecal samples from Anas platyrhynchos (collected in autumn and spring) and Tadorna tadorna (collected in spring) were cultured in water at 20° C and 12 L: 12 D conditions in order to quantify the resting eggs which could be internally transported by these birds. One half of each faecal sample was initially cultured at a conductivity of 0.6 mS cm-1 and the other half at 6 mS cm-1. 1054 invertebrates hatched from a total of 60 faecal samples, including cladocerans, copepods, ostracods, rotifers and ciliates, with a wide variability among faeces. Autumn yielded a low proportion of samples with hatchlings (12.5%) compared to spring (90%). Significant differences were observed between birds, but not between conductivity treatments. Thus, our results imply different hatching dynamics affected by disperser and season, but most species transported as resting eggs by birds seem to have a wide tolerance to hatch under variable salinity conditions. These differences may largery influence the metacommunity dynamics of lake networks, and could be a key factor to consider in wetland conservation planning.

Favorable Geochemistry from Springs and Wells in Colorado

DOE Data Explorer

Richard E. Zehner

2012-02-01

This layer contains favorable geochemistry for high-temperature geothermal systems, as interpreted by Richard "Rick" Zehner. The data is compiled from the data obtained from the USGS. The original data set combines 15,622 samples collected in the State of Colorado from several sources including 1) the original Geotherm geochemical database, 2) USGS NWIS (National Water Information System), 3) Colorado Geological Survey geothermal sample data, and 4) original samples collected by R. Zehner at various sites during the 2011 field season. These samples are also available in a separate shapefile FlintWaterSamples.shp. Data from all samples were reportedly collected using standard water sampling protocols (filtering through 0.45 micron filter, etc.) Sample information was standardized to ppm (micrograms/liter) in spreadsheet columns. Commonly-used cation and silica geothermometer temperature estimates are included.

Trace-metal concentrations, waters from selected sky lakes, streams and springs, northern Shawangunk Mountains, New York: geologic and ecologic implications

USGS Publications Warehouse

Friedman, J.D.; Huth, P.C.; Smiley, D.

1990-01-01

Reconnaissance sampling and chemical analysis of water from selected lakes, streams and springs of the northern Shawangunk Mountains in 1987 to 1988 to determine the influence of lithology on trace-metal concentrations in surface water, and to establish a base level of concentration of 27 selected metals by ICP-AES and Hg by cold-vapor AAS methods, for geochemical exploration, ecologic, acid-rain, and climatic-change studies, have yielded trace-metal concentrations greater than detection limits for 10 metallic elements. Eighteen additional metallic elements were also present in trace quantities below the quantitative detection limit. Two distinct geochemical populations are related to source lithology and pH. -from Authors

Hot springs of the central Sierra Nevada, California

USGS Publications Warehouse

Mariner, R.H.; Presser, T.S.; Evans, William C.

1977-01-01

Thermal springs of the central Sierra Nevada issue dilute to slightly saline sodium chloride, sodium bicarbonate, or sodium mixed-anion waters ranging in pH from 6.4 to 9.3. The solubility of chalcedony appears to control the silica concentration in most of the spring waters. Fales Hot Springs may be associated with a higher temperature aquifer, 150 degrees Celsius or more, in which quartz is controlling the silica concentration. Carbon dioxide is the predominant gas escaping from Fales Hot Springs, the unnamed hot spring on the south side of Mono Lake, and the two thermal springs near Bridgeport. Most of the other thermal springs issue small amounts of gas consisting principally of nitrogen. Methane is the major component of the gas escaping from the unnamed spring on Paoha Island in Mono Lake. The deuterium and oxygen isotopic composition of most of the thermal waters are those expected for local meteoric water which has undergone minor water-rock reaction. The only exceptions are the hot spring on Paoha Island in Mono Lake and perhaps the unnamed warm spring (south side of Mono Lake) which issues mixtures of thermal water and saline lake water. (Woodard-USGS)

Spring water quality and usability in the Mount Cameroon area revealed by hydrogeochemistry.

PubMed

Ako, Andrew Ako; Shimada, Jun; Hosono, Takahiro; Kagabu, Makoto; Ayuk, Akoachere Richard; Nkeng, George Elambo; Eyong, Gloria Eneke Takem; Fouepe Takounjou, Alain L

2012-10-01

Groundwater is the only reliable water resource for drinking, domestic, and agricultural purposes for the people living in the Mount Cameroon area. Hydrogeochemical and R-mode factor analysis were used to identify hydrogeochemical processes controlling spring water quality and assess its usability for the above uses. Main water types in the study area are Ca-Mg-HCO(3) and Na-HCO(3). This study reveals that three processes are controlling the spring water quality. CO(2)-driven silicate weathering and reverse cation exchange are the most important processes affecting the hydrochemistry of the spring waters. While tropical oceanic monsoon chloride-rich/sulfate-rich rainwater seems to affect spring water chemistry at low-altitude areas, strong correlations exist between major ions, dissolved silica and the altitude of springs. In general, the spring waters are suitable for drinking and domestic uses. Total hardness (TH) values indicate a general softness of the waters, which is linked to the development of cardiovascular diseases. Based on Na %, residual sodium carbonate, sodium adsorption ratio, and the USSL classification, the spring waters are considered suitable for irrigation. Though there is wide spread use of chemical fertilizers and intense urban settlements at the lower flanks of the volcano, anthropogenic activities for now seem to have little impact on the spring water quality.

Hydrogeochemical and stream sediment special reconnaissance report for the Deep Creek Mountains, Nevada and Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qualheim, B.

1979-04-01

This report represents the results of the reconnaissance sampling of the Deep Creek Mountains of western Utah. The Deep Creek range is located in the northwest corner of the Delta NTMS 1:250,000 and the southwestern corner of the Tooele NTMS 1:250,000 sheets and covers an area of 1750 km/sup 2/. Samples collected in this study include dry and wet stream sediments and water from available streams, wells, and springs. The samples were analyzed for uranium, as well as 15 to 20 trace elements, using neutron activation techniques. In addition, field and laboratory measurements were made on the water samples. Analyticalmore » data and field measurements are presented in tabular hard copy and fiche format. Water-sample site locations, water-sample uranium concentrations, sediment-sample site locations, and sediment-sample uranium concentrations are shown on separate overlays.« less

Identification of subsurface microorganisms at Yucca Mountain. Quarterly report, July 1, 1995--September 30, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stetzenbach, L.D.

1995-12-01

More than 1100 bacterial isolates were obtained over a two year period from 31 springs in a region along the southern boarder of California and Nevada. Water samples were collected from 17 springs in Ash Meadows National Wildlife Refuge and 14 springs in Death Valley National Park. Bacteria isolated from these samples were subjected to extraction and gas chromatography to determine the cellular fatty acid profile of each isolate. Fatty acid methyl esters (FAME) extracted from cell membranes were separated and classified using the Hewlett Packard by gas chromatography. The FAME profiles of each isolate were then subjected to clustermore » analysis by the unweighted pair-group method using arithmetic averages. During this quarter the relatedness of FAME patterns of bacterial isolates were examined at the genus level by counting the number of clusters produced in a MIDI dendrogram at a Euclidian distance of 25. This information was then used to determine microbiological relationships among springs.« less

Hydrosalinity studies of the Virgin River, Dixie Hot Springs, and Littlefield Springs, Utah, Arizona, and Nevada

USGS Publications Warehouse

Gerner, Steven J.; Thiros, Susan A.; Gerner, Steven J.; Thiros, Susan A.

2014-01-01

The Virgin River contributes a substantial amount of dissolved solids (salt) to the Colorado River at Lake Mead in the lower Colorado River Basin. Degradation of Colorado River water by the addition of dissolved solids from the Virgin River affects the suitability of the water for municipal, industrial, and agricultural use within the basin. Dixie Hot Springs in Utah are a major localized source of dissolved solids discharging to the Virgin River. The average measured discharge from Dixie Hot Springs during 2009–10 was 11.0 cubic feet per second (ft3/s), and the average dissolved-solids concentration was 9,220 milligrams per liter (mg/L). The average dissolved-solids load—a measurement that describes the mass of salt that is transported per unit of time—from Dixie Hot Springs during this period was 96,200 tons per year (ton/yr). Annual dissolved-solids loads were estimated at 13 monitoring sites in the Virgin River Basin from streamflow data and discrete measurements of dissolved-solids concentrations and (or) specific conductance. Eight of the sites had the data needed to estimate annual dissolved-solids loads for water years (WYs) 1999 through 2010. During 1999–2010, the smallest dissolved-solids loads in the Virgin River were upstream of Dixie Hot Springs (59,900 ton/yr, on average) and the largest loads were downstream of Littlefield Springs (298,200 ton/yr, on average). Annual dissolved-solids loads were smallest during 2002–03, which was a period of below normal precipitation. Annual dissolved-solids loads were largest during 2005—a year that included a winter rain storm that resulted in flooding throughout much of the Virgin River Basin. An average seepage loss of 26.7 ft3/s was calculated from analysis of monthly average streamflow from July 1998 to September 2010 in the Virgin River for the reach that extends from just upstream of the Utah/Arizona State line to just above the Virgin River Gorge Narrows. Seepage losses from three river reaches in the Virgin River Gorge containing known fault zones accounted for about 48 percent of this total seepage loss. An additional seepage loss of 6.7 ft3/s was calculated for the reach of the Virgin River between Bloomington, Utah, and the Utah/Arizona State line. This loss in flow is small compared to total flow in the river and is comparable to the rated error in streamflow measurements in this reach; consequently, it should be used with caution. Littlefield Springs were studied to determine the fraction of its discharge that originates as upstream seepage from the Virgin River and residence time of this water in the subsurface. Geochemical and environmental tracer data from groundwater and surface-water sites in the Virgin River Gorge area suggest that discharge from Littlefield Springs is a mixture of modern (post-1950s) seepage from the Virgin River upstream of the springs and older groundwater from a regional carbonate aquifer. Concentrations of the chlorofluorocarbons (CFCs) CFC-12 and CFC-113, chloride/fluoride and chloride/bromide ratios, and the stable isotope deuterium indicate that water discharging from Littlefield Springs is about 60 percent seepage from the Virgin River and about 40 percent discharge from the regional carbonate aquifer. The river seepage component was determined to have an average subsurface traveltime of about 26 ±1.6 years before discharging at Littlefield Springs. Radiocarbon data for Littlefield Springs suggest groundwater ages from 1,000 to 9,000 years. Because these are mixed waters, the component of discharge from the carbonate aquifer is likely much older than the groundwater ages suggested by the Littlefield Springs samples. If the dissolved-solids load from Dixie Hot Springs to the Virgin River were reduced, the irrigation water subsequently applied to agricultural fields in the St. George and Washington areas, which originates as water from the Virgin River downstream of Dixie Hot Springs, would have a lower dissolved-solids concentration. Dissolved-solids concentrations in excess irrigation water draining from the agricultural fields are about 1,700 mg/L higher than the concentrations in the Virgin River water that is currently (2014) used for irrigation that contains inflow from Dixie Hot Springs; this increase results from evaporative concentration and dissolution of mineral salts in the irrigated agricultural fields. The water samples collected from drains downgradient from the irrigated areas are assumed to include the dissolution of all available minerals precipitated in the soil during the previous irrigation season. Based on this assumption, a change to more dilute irrigation water will not dissolve additional minerals and increase the dissolved-solids load in the drain discharge. Following the hypothetical reduction of salts from Dixie Hot Springs, which would result in more dilute Virgin River irrigation water than is currently used, the dissolution of minerals left in the soil from the previous irrigation season would result in a net increase in dissolved-solids concentrations in the drain discharge, but this increase should only last one irrigation season. After one (or several) seasons of irrigating with more dilute irrigation water, mineral precipitation and subsequent re-dissolution beneath the agricultural fields should be greatly reduced, leading to a reduction in dissolved-solids load to the Virgin River below the agricultural drains. A mass-balance model was used to predict changes in the dissolved-solids load in the Virgin River if the salt discharging from Dixie Hot Springs were reduced or removed. Assuming that 33.4 or 26.7 ft3/s of water seeps from the Virgin River to the groundwater system upstream of the Virgin River Gorge Narrows, the immediate hypothetical reduction in dissolved-solids load in the Virgin River at Littlefield, Arizona is estimated to be 67,700 or 71,500 ton/yr, respectively. The decrease in dissolved-solids load in seepage from the Virgin River to the groundwater system is expected to reduce the load discharging from Littlefield Springs in approximately 26 years, the estimated time lag between seepage from the river and discharge of the seepage water, after subsurface transport, from Littlefield Springs. At that time, the entire reduction in dissolved solids seeping from the Virgin River is expected to be realized as a reduction in dissolved solids discharging from Littlefield Springs, resulting in an additional reduction of 24,700 ton/yr (based on 33.4 ft3/s of seepage loss) or 21,000 ton/yr (based on 26.7 ft3/s of seepage loss) in the river’s dissolved-solids load at Littlefield.

Reconnaissance of land-use sources of pesticides in drinking water, McKenzie River, Oregon

USGS Publications Warehouse

Kelly, Valerie J.; Anderson, Chauncey W.; Morgenstern, Karl

2012-01-01

The Eugene Water and Electric Board (EWEB) provides water and electricity to the City of Eugene, Oregon, from the McKenzie River. In the spring of 2002, EWEB initiated a pesticide monitoring program in cooperation with the U.S. Geological Survey as part of their Drinking Water Source Protection Plan. Approximately twice yearly pesticide samples were collected from 2002 to 2010 at a suite of sampling sites representing varying land uses in the lower McKenzie River basin. A total of 117 ambient samples were collected from 28 tributary and mainstem sites, including those dominated by forestry, urban, and agricultural activities, as well as the mouths of major tributaries characterized by a mixture of upstream land use. Constituents tested included 175 compounds in filtered water (72 herbicides, 43 insecticides, 10 fungicides, and 36 of their degradation products, as well as 14 pharmaceutical compounds). No attempt was made to sample different site types equivalently; sampling was instead designed primarily to characterize representative storm events during spring and fall runoff conditions in order to assess or confirm the perceived importance of the different site types as sources for pesticides. Sampling was especially limited for agricultural sites, which were only sampled during two spring storm surveys. A total of 43 compounds were detected at least once, with many of these detected only at low concentrations (<0.1 micrograms per liter). Nine compounds were detected at the drinking- water intake, and most of these were reported as estimates less than the laboratory reporting level. Human-health benchmark concentrations were consistently several orders of magnitude higher than detected concentrations at the intake, indicating that pesticide concentrations present a negligible threat to human health. The largest number of pesticide detections occurred during spring storm surveys and primarily were associated with urban stormwater drains. Urban sites also were associated with the highest concentrations, occasionally exceeding 1 microgram per liter. Many of the compounds detected at urban sites were relatively hydrophobic (do not mix easily with water), persistent, and suspected of endocrine disruption. In contrast, forestry compounds were rarely detectable in the McKenzie River, even though forest land predominates in the basin and forestry pesticide use was detected in small tributaries draining forested lands following application. Agricultural pesticide runoff was not well characterized by the limited data available, although a large number of compounds was estimated to be used in the basin and concentrations were moderately high in the few samples collected from small tributaries draining agricultural lands. Results from this analysis indicate that urban pesticide use is potentially an important source for pesticides of concern for drinking water, not limited exclusively to storm conditions. Forestry pesticide use is not considered a likely threat to drinking water quality at the present time (2012). A more complete understanding of agricultural chemicals in runoff in the McKenzie River basin requires further investigation. In addition to evaluating the data collected in this study, a conceptual model describing pesticide contamination in the McKenzie River basin is provided, based on current scientific understanding that is consistent with the data analysis presented in this report. This model is intended to provide a foundation for future monitoring in the basin.

Detection and quality of previously undetermined Floridan aquifer system discharge to the St. Johns River, Jacksonville, to Green Cove Springs, northeastern Florida

USGS Publications Warehouse

Spechler, R.M.

1996-01-01

Potentiometric surface maps of the Upper Floridan aquifer show two depressions around the St. Johns River frm the city of Jacksonville south toward Green Cove Springs. These depressions, depending on their locations, are the result of withdrawals from agricultural, industrial, domestic and public-supply wells, diffuse upward leakage, and discharge from springs. Submerged springs that discharge into the St. Johns River between Jacksonville and Green Cove Springs have been thought to exist, but locating and evaluating these springs had not been attempted before this investigation. Thermal infrared imagery, seismic reflection, and numerous interviews with local residents were used to locate springs. An airborne thermal infrared survey was conducted along a section of the St. Johns River in northeastern Florida during February 1992 to detect possible sources of ground-water discharge to the river. An infrared image displayed one thermal anomaly in the St. Johns River which is associated with a previously unknown spring discharge from the Floridan aquifer system. Thermal anomalies also were observed at six locations where municipal facilities discharge treated wastewater to the river. Results of seismic reflection surveys indicate the presence of collapse and other karst features underlying the St. Johns River. These features indicate that the surficial deposits and the Hawthorn Formation that underlie the river probably do not consist of continuous beds. The collapse or deformation of the Hawthorn Formation or the presence of permeable sediment of localized extent could create zones of relatively high vertical leakance. This could provide a more direct hydraulic connection between the Upper Floridan aquifer and the river. Water samples collected from the only submerged spring in the St. Johns River within the Jacksonville-Green Cove Springs reach indicate that the source of the water is the Floridan aquifer system. Chloride and sulfate concentrations were 12 and 340 milligrams per liter, respectively. Specific conductance was 826 microsiemens per centimeter and the temperature of the water discharging from the spring was 25.1 degrees Celsius. The ratio of 87 Strontium/86 Strontium also indicates that the springwater has been in contact with rock materials of Eocene age, providing additional evidence that the springwater is derived from the Floridan aquifer system.

It's not just how high; it's how clean: Sampling the spring 2001 flood in the Upper Mississippi River Basin

USGS Publications Warehouse

Patterson, Glenn; Kolpin, Dana W.; Kalkhoff, Stephen J.; Lee, Kathy E.; Schnoebelen, Douglas J.; Barnes, Kimberlee K.; Coupe, Richard H.

2001-01-01

Floods can cause water-quality problems because of the large amounts of contaminants (sediment, nutrients, pesticides, and bacteria) that can be transported by floodwaters. during the flood on the Upper Mississippi River in 2001, water-quality and water-quality data were collected during near-record streamflow. This is the first time that samples for determining organic wastewater contaminants (pharmaceuticals, hormones, and industrial/household use compounds) and pesticide degradates have been collected during a flood of this magnitude.

Water Quality and Geochemical Modeling of Water at an Abandoned Coal Mine Reclaimed With Coal Combustion By-Products

USGS Publications Warehouse

Haefner, Ralph J.

2002-01-01

An abandoned coal mine in eastern Ohio was reclaimed with 125 tons per acre of pressurized fluidized bed combustion (PFBC) by-product. Water quality at the site (known as the Fleming site) was monitored for 7 years after reclamation; samples included water from soil-suction lysimeters (interstitial water), wells, and spring sites established downgradient of the application area. This report presents a summary of data collected at the Fleming site during the period September 1994 through June 2001. Additionally, results of geochemical modeling are included in this report to evaluate the potential fate of elements derived from the PFBC by-product. Chemical analyses of samples of interstitial waters within the PFBC by-product application area indicated elevated levels of pH and specific conductance and elevated concentrations of boron, calcium, chloride, fluoride, magnesium, potassium, strontium, and sulfate compared to water samples collected in a control area where traditional reclamation methods were used. Magnesium-to-calcium (Mg:Ca) mole ratios and sulfur-isotope ratios were used to trace the PFBC by-product leachate and showed that little, if any, leachate reached ground water. Concentrations of most constituents in interstitial waters in the application-area decreased during the seven sampling rounds and approached background concentrations observed in the control area; however, median pH in the application area remained above 6, indicating that some acid-neutralizing capacity was still present. Although notable changes in water quality were observed in interstitial waters during the study period, quality of ground water and spring water remained poor. Water from the Fleming site was not potable, given exceedances of primary and secondary Maximum Contaminant Levels (MCLs) for inorganic constituents in drinking water set by the U.S. Environmental Protection Agency. Only fluoride and sulfate, which were found in higher concentrations in application-area interstitial waters than in control-area interstitial waters, could be related to the PFBC by-product. Concentrations of arsenic, lead, and selenium typically were at or below the detection limits (generally 1 or 2 micrograms per liter). Elements detected at elevated concentrations in PFBC by-product application-area interstitial waters were not evident in downgradient ground water or spring water. Dilution of leachate by ground water was confirmed with a mixing model generated by the computer code NETPATH. Additionally, thermodynamic modeling of the chemical composition of water samples by use of the computer code PHREEQC indicated favorable conditions for precipitation of secondary minerals in the unsaturated zone and in aquifer materials. Because of low application rates of PFBC by-product and precipitation and sorption of elements in the unsaturated zone, it is improbable that concentrations of any toxic elements of concern (arsenic, lead, or selenium) will exceed drinking-water standards at this site or other sites where similar volumes of PFBC by-products are used.

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

USGS Publications Warehouse

Hayes, Timothy Scott

1999-01-01

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage

Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs

NASA Astrophysics Data System (ADS)

Toth, David J.; Katz, Brian G.

2006-06-01

Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca-HCO3 (six), Na-Cl (four), and mixed (one). The evolution of water chemistry for Ca-HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na-Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4-53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca-HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na-Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.

Timescales for nitrate contamination of spring waters, northern Florida, USA

USGS Publications Warehouse

Katz, B.G.; Böhlke, J.K.; Hornsby, H.D.

2001-01-01

Residence times of groundwater, discharging from springs in the middle Suwannee River Basin, were estimated using chlorofluorocarbons (CFCs), tritium (3H), and tritium/helium-3 (3H/3He) age-dating methods to assess the chronology of nitrate contamination of spring waters in northern Florida. During base-flow conditions for the Suwannee River in 1997–1999, 17 water samples were collected from 12 first, second, and third magnitude springs discharging groundwater from the Upper Floridan aquifer. Extending age-dating techniques, using transient tracers to spring waters in complex karst systems, required an assessment of several models [piston-flow (PFM), exponential mixing (EMM), and binary-mixing (BMM)] to account for different distributions of groundwater age. Multi-tracer analyses of four springs yielded generally concordant PFM ages of around 20±2 years from CFC-12, CFC-113, 3H, and 3He, with evidence of partial CFC-11 degradation. The EMM gave a reasonable fit to CFC-113, CFC-12, and 3H data, but did not reproduce the observed 3He concentrations or 3H/3He ratios, nor did a combination PFM–EMM. The BMM could reproduce most of the multi-tracer data set only if both endmembers had 3H concentrations not much different from modern values. CFC analyses of 14 additional springs yielded apparent PFM ages from about 10 to 20 years from CFC-113, with evidence of partial CFC-11 degradation and variable CFC-12 contamination. While it is not conclusive, with respect to the age distribution within each spring, the data indicate that the average residence times were in the order of 10–20 years and were roughly proportional to spring magnitude. Applying similar models to recharge and discharge of nitrate based on historical nitrogen loading data yielded contrasting trends for Suwanee County and Lafayette County. In Suwanee County, spring nitrate trends and nitrogen isotope data were consistent with a peak in fertilizer input in the 1970s and a relatively high overall ratio of artificial fertilizer/manure; whereas in Lafayette County, spring nitrate trends and nitrogen isotope data were consistent with a more monotonic increase in fertilizer input and relatively low overall ratio of artificial fertilizer/manure. The combined results of this study indicate that the nitrate concentrations of springs in the Suwannee River basin have responded to increased nitrogen loads from various sources in the watersheds over the last few decades; however, the responses have been subdued and delayed because the average residence time of groundwater discharging from springs are in the order of decades.

Nitrogen, phosphorus, organic carbon, and biochemical oxygen demand : in Florida surface waters, 1972

USGS Publications Warehouse

Kaufman, Matthew I.; Dysart, J.E.

1978-01-01

Water samples were collected during spring and autumn 1972 from about 100 surface-water sites in Florida. The samples were analyzed for the plant nutrients, nitrogen and phosphorus. In most waters, nitrogen concentrations are less than 2.0 milligrams per liter as nitrogen, and organic nitrogen is dominant. Median total nitrogen concentration for Florida surface waters is between 1.2 and 2.0 milligrams per liter as nitrogen. In samples from 85 percent of the sites, total nitrogen exceeded 0.6 milligrams per liter. Median total phosphorus concentration as phosphorus for Florida surface waters is between 0.05 and 0.1 milligrams per liter. The information will form a base useful to agencies concerned with setting concentration limits for nitrogen and phosphorus in industrial and sewage plant outfalls. (Woodard-USGS)

Causes of toxicity to Hyalella azteca in a stormwater management facility receiving highway runoff and snowmelt. Part I: polycyclic aromatic hydrocarbons and metals.

PubMed

Bartlett, A J; Rochfort, Q; Brown, L R; Marsalek, J

2012-01-01

The Terraview-Willowfield Stormwater Management Facility (TWSMF) receives inputs of multiple contaminants, including metals, polycyclic aromatic hydrocarbons (PAHs), road salt, and nutrients, via highway and residential runoff. Contaminant concentrations in runoff are seasonally dependent, and are typically high in early spring, coinciding with the snowmelt. In order to investigate the seasonal fluctuations of contaminant loading and related changes in toxicity to benthic invertebrates, overlying water and sediment samples were collected in the fall and spring, reflecting low and high contaminant loading, respectively, and four-week sediment toxicity tests were conducted with Hyalella azteca. The effects of metals and PAHs are discussed here; the effects of salts, nutrients, and water quality are discussed in a companion paper. Survival and growth of Hyalella after exposure to fall samples were variable: survival was significantly reduced (64-74% of controls) at three out of four sites, but there were no significant growth effects. More dramatic effects were observed after Hyalella were exposed to spring samples: survival was significantly reduced at the two sites furthest downstream (0-75% of controls), and growth was significantly lower in four out of five sites when comparing Hyalella exposed to site sediment with overlying site water versus site sediment with overlying control water. These seasonal changes in toxicity were not related to metals or PAHs: 1. levels of bioavailable metals were below those expected to cause toxicity, and 2. levels of PAHs in sediment were lowest at sites with the greatest toxicity and highest in water and sediment at sites with no toxicity. Although not associated with toxicity, some metals and PAHs exceeded probable and severe effect levels, and could be a cause for concern if contaminant bioavailability changes. Toxicity in the TWSMF appeared to be primarily associated with water-borne contaminants. The cause(s) of these effects are discussed in our companion manuscript. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

Organochlorine compounds in ice melt water from Italian Alpine rivers.

PubMed

Villa, Sara; Negrelli, Christian; Finizio, Antonio; Flora, Onelio; Vighi, Marco

2006-01-01

Organochlorine chemicals (OCs) (dichlorodiphenyltrichloroethanes, hexachlorocyclohexanes, and hexachlorobenzene) were measured in ice melt water from five glaciers in the Italian Alps. Even though the data collected may not be sufficient for a precise description of persistent organic pollutant release patterns from glacier melting, they have, however, highlighted the potential for surface water contamination. Concentrations were of the same order of magnitude in all glacial streams, indicating comparable contamination levels in different glaciers of the alpine region. OC levels in nonglacial springs sampled in the same areas are usually lower. Even if differences during the melting season (from spring to autumn) have been identified, a regular seasonal pattern in OC concentrations was not observed. Risk for the aquatic environment is excluded through direct water exposure, but it is likely to occur through biomagnification and secondary poisoning exposure.

Appraisal of water in bedrock aquifers, northern Cascade County, Montana

USGS Publications Warehouse

Wilke, K.R.

1982-01-01

Suburban residential expansion of the city of Great Falls has resulted in an increased demand on water supplies from bedrock aquifers in northern Cascade County. The unconsolidated deposits aquifer of Quaternary age, including alluvium and glacial lake deposits, also is an important source of water in the area. Water levels in the Madison-Swift aquifer and all overlying aquifers, including the Quaternary deposits aquifer, reflect unconfined (water-table) conditions in the Great Falls vicinity. This interconnected hydrologic system is the result of breaching of the major anticlinal structure, by ancestral and present day erosion of drainage channels by the Missouri River and its tributaries. Significant vertical inter-aquifer mixing of water, as well as surface water/groundwater interchange, probably occurs in the central part of the study area. Characterization of the chemical composition of water in individual aquifers based on samples from wells in this area probably is unreliable because of this mixing. Quality of water from two wells in the Madison-Swift aquifer near Giant Springs is similar to water from the springs. Water from these three samples is less mineralized than most groundwater in the study area; dissolved solids concentrations for the three samples range from 516 to 550 mg/L. The quality of water varies among aquifers and throughout the study area. The ranges of dissolved solids concentrations determined by chemical analysis are Madison-Swift aquifer, about 520 to 1,570 mg/L; Morrison Formation, 908 to 1 ,480 mg/L; Kootenai Formation, 558 to 1,550 mg/L; Colorado Group , 2,690 and 2,740 mg/L (two samples); and unconsolidated Quaternary deposits, 383 to 2,060 mg/L. The chemical quality of water from the Colorado Group in the western one-third of the area generally is more mineralized than water from aquifers in the rest of the area. Specific conductance of water from eight wells completed in the Colorado Group averages 4,440 micromhos at 25 C. (Author 's abstract)

Map showing springs in the Salina quadrangle, Utah

USGS Publications Warehouse

Covington, Harry R.

1972-01-01

A spring is “a place where, without the agency of man, water flows from a rock or soil upon the land or into a body of surface water” (Meinzer, 1923, p. 48).About 450 springs are located on this map. Locations and names are from the U.S. Forest Service maps (1963, 1964) and from topographic maps of the U.S. Geological Survey, both published and in preparation. There is considerable variation in geological occurrence of the springs and in quantity and chemical quality of the water that issues from them. Springs in the Salina quadrangle are more abundant where annual precipitation is 16 inches or more, although there are many springs in arid parts of the quadrangle as well.In the Salina quadrangle, springs are used most commonly for watering livestock. They are used also for irrigation and for domestic and municipal water supply. Several communities in Rabbit Valley, Grass Valley, and Sevier Valley depend on springs for all or part of their water supply.Quantity and quality of water are shown for those few springs for which data are available (Mundorff, 1971). Caution must be used in drinking from springs, especially in arid areas; the water commonly tastes bad and may cause illness.

Selected hydrologic data for the central Virgin River basin area, Washington and Iron counties, Utah, 1915-97

USGS Publications Warehouse

Wilkowske, Christopher D.; Heilweil, Victor M.; Wilberg, Dale E.

1998-01-01

Hydrologic data were collected in Washington and Iron Counties, Utah, from 1995 to 1997 to better understand the hydrologic system. Data from earlier years also are presented. Data collected from wells include well-completion data, water-level measurements, and physical properties of the water. Data collected from springs and surface-water sites include discharge and physical properties of the water. Selected water samples collected from ground- and surface-water sites were analyzed for isotopes, chlorofluorocarbons, and dissolved gases.

Diversity and Distribution of Thermophilic Bacteria in Hot Springs of Pakistan.

PubMed

Amin, Arshia; Ahmed, Iftikhar; Salam, Nimaichand; Kim, Byung-Yong; Singh, Dharmesh; Zhi, Xiao-Yang; Xiao, Min; Li, Wen-Jun

2017-07-01

Chilas and Hunza areas, located in the Main Mantle Thrust and Main Karakoram Thrust of the Himalayas, host a range of geochemically diverse hot springs. This Himalayan geothermal region encompassed hot springs ranging in temperature from 60 to 95 °C, in pH from 6.2 to 9.4, and in mineralogy from bicarbonates (Tato Field), sulfates (Tatta Pani) to mixed type (Murtazaabad). Microbial community structures in these geothermal springs remained largely unexplored to date. In this study, we report a comprehensive, culture-independent survey of microbial communities in nine samples from these geothermal fields by employing a bar-coded pyrosequencing technique. The bacterial phyla Proteobacteria and Chloroflexi were dominant in all samples from Tato Field, Tatta Pani, and Murtazaabad. The community structures however depended on temperature, pH, and physicochemical parameters of the geothermal sites. The Murtazaabad hot springs with relatively higher temperature (90-95 °C) favored the growth of phylum Thermotogae, whereas the Tatta Pani thermal spring site TP-H3-b (60 °C) favored the phylum Proteobacteria. At sites with low silica and high temperature, OTUs belonging to phylum Chloroflexi were dominant. Deep water areas of the Murtazaabad hot springs favored the sulfur-reducing bacteria. About 40% of the total OTUs obtained from these samples were unclassified or uncharacterized, suggesting the presence of many undiscovered and unexplored microbiota. This study has provided novel insights into the nature of ecological interactions among important taxa in these communities, which in turn will help in determining future study courses in these sites.

Near-road sampling of PM2. 5, BC, and fine-particle chemical components in Kathmandu Valley, Nepal

NASA Astrophysics Data System (ADS)

Shakya, Kabindra M.; Rupakheti, Maheswar; Shahi, Anima; Maskey, Rejina; Pradhan, Bidya; Panday, Arnico; Puppala, Siva P.; Lawrence, Mark; Peltier, Richard E.

2017-06-01

Semicontinuous PM2. 5 and black carbon (BC) concentrations, and 24 h integrated PM2. 5 filter samples were collected near roadways in the Kathmandu Valley, Nepal. Instruments were carried by a group of volunteer traffic police officers in the vicinity of six major roadway intersections in the Kathmandu Valley across two sampling periods in 2014. Daily PM2. 5 filter samples were analyzed for water-soluble inorganic ions, elemental carbon (EC) and organic carbon (OC), and 24 elements. Mean PM2. 5 and BC concentrations were 124.76 µg m-3 and 16.74 µgC m-3 during the drier spring sampling period, and 45.92 µg m-3 and 13.46 µgC m-3 during monsoonal sampling. Despite the lower monsoonal PM2. 5 concentrations, BC and several elements were not significantly lower during the monsoon, which indicates an important contribution of vehicle-related emissions throughout both seasons in this region. During the monsoon, there was an enhanced contribution of chemical species (elements and water-soluble inorganic ions), except secondary inorganic ions, and BC to PM2. 5 (crustal elements: 19 %; heavy metals: 5 %; and BC: 39 %) compared to those in spring (crustal elements: 9 %; heavy metals: 1 %; and BC: 18 %). Silica, calcium, aluminum, and iron were the most abundant elements during both spring and the monsoon, with total concentrations of 12.13 and 8.85 µg m-3, respectively. PM2. 5 and BC showed less spatial variation compared to that for individual chemical species.

Hydrochemical Signatures of Glacier Melt and Groundwater Storage on Volcán Chimborazo, Ecuador

NASA Astrophysics Data System (ADS)

McLaughlin, R.; Ng, G. H. C.; La Frenierre, J.; Wickert, A. D.; Baraer, M.

2016-12-01

With ever-growing water demands for hydroelectricity, agriculture, and domestic use, the accelerated retreat of tropical glaciers is raising concerns about future water supply sustainability. In the tropical Andes, where precipitation is seasonal and spatially heterogeneous, glaciers are particularly important as their storage and slow release of water helps to modulate stream discharge on daily to yearly time scales. Predicting the effect their shrinkage will have on water resources is not straightforward as little is known about the connections in these glaciated volcanic catchments between meltwater, groundwater, precipitation and surficial discharge. Here, stable isotope and major ion analyses inform a hydrochemical mixing model in order to identify water sources and their relative contributions to stream and spring discharge on Volcán Chimborazo, a stratovolcano located in the Ecuadorian Andes. Moisture in this region generally arrives from the Amazon basin to the east, resulting in a steep northeast-southwest precipitation gradient that produces wet and dry sides of the mountain. Dry season water samples were collected on both sides from major streams and springs at varying elevations and distances from the glacier tongues, along with samples of precipitation (when possible) and glacier ice. Data on specific conductivity, pH, and temperature were collected in situ for each sample. The paired catchment study allows us to isolate a primarily glacial melt signature on the dry side and compare it to data on the wet side, where glacial melt and precipitation both contribute to groundwater and surface-water discharge.

Principal locations of major-ion, trace-element, nitrate, and Escherichia coli loading to Emigration Creek, Salt Lake County, Utah, October 2005

USGS Publications Warehouse

Kimball, Briant A.; Runkel, Robert L.; Walton-Day, Katherine

2008-01-01

Housing development and recreational activity in Emigration Canyon have increased substantially since 1980, perhaps causing an observed decrease in water quality of this northern Utah stream located near Salt Lake City. To identify reaches of the stream that contribute to water-quality degradation, a tracer-injection and synoptic-sampling study was done to quantify mass loading of major ions, trace elements, nitrate, and Escherichia coli (E. coli) to the stream. The resulting mass-loading profiles for major ions and trace elements indicate both geologic and anthropogenic inputs to the stream, principally from tributary and spring inflows to the stream at Brigham Fork, Burr Fork, Wagner Spring, Emigration Tunnel Spring, Blacksmith Hollow, and Killyon Canyon. The pattern of nitrate loading does not correspond to the major-ion and trace-element loading patterns. Nitrate levels in the stream did not exceed water-quality standards at the time of synoptic sampling. The majority of nitrate mass loading can be considered related to anthropogenic input, based on the field settings and trends in stable isotope ratios of nitrogen. The pattern of E. coli loading does not correspond to the major-ion, trace-element, or nitrate loading patterns. The majority of E. coli loading was related to anthropogenic sources based on field setting, but a considerable part of the loading also comes from possible animal sources in Killyon Canyon, in Perkins Flat, and in Rotary Park. In this late summer sampling, E. coli concentrations only exceeded water-quality standards in limited sections of the study reach. The mass-loading approach used in this study provides a means to design future studies and to evaluate the loading on a catchment scale.

Occurrence of antibiotic compounds in source water and finished drinking water from the upper Scioto River Basin, Ohio, 2005-6

USGS Publications Warehouse

Finnegan, Dennis P.; Simonson, Laura A.; Meyer, Michael T.

2010-01-01

The occurrence of antibiotics in surface water and groundwater in urban basins has become a topic of increasing interest in recent years. Little is known about the occurrence, fate, or transport of these compounds and the possible health effects in humans and aquatic life. The U.S. Geological Survey, in cooperation with the City of Columbus, Division of Power and Water, did a study to provide a synoptic view of the occurrence of antibiotics in source and finished waters in the upper Scioto River Basin. Water samples were collected seasonally-winter (December 2005), spring (May 2006), summer (August 2006) and fall (October 2006)-at five surface-water sites, one groundwater site, and three water-treatment plants (WTPs). Within the upper Scioto River Basin, sampling at each WTP involved two sampling sites: a source-water intake site and a finished-water site. One or more antibiotics were detected at 11 of the 12 sampling sites. Of the 49 targeted antibiotic compounds, 12 (24 percent) were detected at least one time for a total of 61 detections overall. These compounds were azithromycin, tylosin, erythromycin-H2O, erythromycin, roxithromycin, ciprofloxacin, ofloxacin, sulfamethazine, sulfamethoxazole, iso-chlorotetracycline, lincomycin, and trimethoprim. Detection results were at low levels, with an overall median of 0.014 (u or mu)g/L. Hap Cremean WTP had the fewest detections, with two source-water detections of sulfamethoxazole and azithromycin and no detections in the finished water. Of the total of 61 detections, 31 were in the winter sample run. Sulfamethoxazale and azithromycin detections represent 41 percent of all antibiotic detections. Azithromycin was detected only in the winter sample. Some antibiotics, such as those in the quinoline and tetracycline families, dissipate more quickly in warm water, which may explain why they were detected in the cool months (winter, spring, and fall) and not in the summer. Antibiotic data collected during this study were compared to antibiotic data collected in previous national, regional, and local studies. Many of the same antibiotic compounds detected in the upper Scioto River Basin also were detected in those investigations.

Executive summary: Weldon Spring Site Environmental Report for calendar year 1992. Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-06-01

This report has been prepared to provide information about the public safety and environmental protection programs conducted by the Weldon Spring Site Remedial Action Project. The Weldon Spring site is located in southern St. Charles County, Missouri, approximately 48 km (30 mi) west of St. Louis. The site consists of two main areas, the Weldon Spring Chemical Plant and raffinate pits and the Weldon Spring Quarry. The objectives of the Site Environmental Report are to present a summary of data from the environmental monitoring program, to characterize trends and environmental conditions at the site, and to confirm compliance with environmentalmore » and health protection standards and requirements. The report also presents the status of remedial activities and the results of monitoring these activities to assess their impacts on the public and environment. The scope of the environmental monitoring program at the Weldon Spring site has changed since it was initiated. Previously, the program focused on investigations of the extent and level of contaminants in the groundwater, surface waters, buildings, and air at the site. In 1992, the level of remedial activities required monitoring for potential impacts of those activities, particularly on surface water runoff and airborne effluents. This report includes monitoring data from routine radiological and nonradiological sampling activities. These data include estimates of dose to the public from the Weldon Spring site; estimates of effluent releases; and trends in groundwater contaminant levels. Also, applicable compliance requirements, quality assurance programs, and special studies conducted in 1992 to support environmental protection programs are reviewed.« less

Hydrology and geochemistry of carbonate springs in Mantua Valley, northern Utah

USGS Publications Warehouse

Rice, Karen C.; Spangler, Lawrence E.; Spangler, Lawrence E.; Allen, Constance J.

1999-01-01

Water chemistry, tritium data, precipitation-discharge relations, geology, topography, and dye tracing were used to determine recharge areas, ground-water residence times, factors influencing ground-water flow, and aquifer characteristic for five springs that discharge from Paleozoic limestones and dolostones along the margin of Manuta Valley, northern Utah.Temperature of Mantua Valley spring water ranged between 6.0 and 15.0 degrees Celsius. Spring-water temperature indicates that depth of circulation of ground water could be as shallow as 80 feet (25 meters) to as much as 1,150 feet (350 meters). Dissolved-solids concentration in the water from springs ranged from 176 to 268 milligrams per liter. Average total hardness of spring water ranged from 157 to 211 milligrams per liter. Water from all of the springs is a calcium-magnesium-bicarbonate type that generally is undersaturated with respect to calcite and dolomite. The molar calcium/magnesium ratio in spring water ranged from 1.21 to 1.88, and indicates that ground water flows through impure dolostone or a mixed limestone and dolostone terrace.Discharge from carbonate springs in Mantua Valley ranges from about to 10 to 4,300 gallons per minute (0.6 to 271 liters per second). Seasonal variations in chemical parameters and discharge indicate that the aquifers supplying water to most of these springs are predominantly diffuse-flow systems that have been locally enhanced by bedrock dissolution. Estimated recharge area for th springs ranges from 2.7 to 7 square miles (7 to 18 square kilometers).On the basis of tritium age dating, the mean residence time of ground water discharges from Olsens-West Hallins and Maple Springs was determined to be from 3 to 9, and from 4 to 15 years, respectively. Dye tracing from point sources 2.65 miles (4.26 kilometers) southeast of Maple Spring, however, indicates a substantially faster component of flow during snowmelt runoff, with a travel time of about 5 days, or an average ground-water velocity of about 2,700 feet per day (823 meters per day).

Isotope and chemical compositions of meteoric and thermal waters and snow from the greater Yellowstone National Park region

USGS Publications Warehouse

Kharaka, Yousif K.; Thordsen, James J.; White, Lloyd D.

2002-01-01

An intensive hydrogeologic investigation, mandated by U.S. Congress and centered on the Norris-Mammoth corridor was conducted by USGS and other scientists during 1988-90 to determine the effects of using thermal water from a private well located in the Corwin Springs Known Geothermal Resources Area, Montana, on the thermal springs of Yellowstone National Park (YNP), especially Mammoth Hot Springs. As part of this investigation, we carried out a detailed study of the isotopic and chemical compositions of meteoric water from cold springs and wells, of thermal water, especially from the Norris-Mammoth corridor and of snow. Additional sampling of meteoric and thermal waters from YNP and surrounding region in northwest Wyoming, southwest Montana and southeast Idaho was carried out in 1991-92 to characterize the distribution of water isotopes in this mountainous region and to determine the origin and possible recharge locations of thermal waters in and adjacent to the Park. The D and 18O values for 40 snow samples range from ?88 to ?178? and ?12.5 to ?23.9?, respectively, and define a well constrained line given by D = 8.2 18O + 14.7 (r2 = 0.99) that is nearly identical to the Global Meteoric Water Line. The D and 18O values of 173 cold water samples range from ?115 to ?153? and ?15.2 to ?20.2?, respectively, and exhibit a similar relationship although with more scatter and with some shift to heavier isotopes, most likely due to evaporation effects. The spatial distribution of cold-water isotopes shows a roughly circular pattern with isotopically lightest waters centered on the mountains and high plateau in the northwest corner of Yellowstone National Park and becoming heavier in all directions. The temperature effect due to altitude is the dominant control on stable water isotopes throughout the region; however, this effect is obscured in narrow 'canyons' and areas of high topographic relief. The effects due to distance (i.e. 'continental') and latitude on water isotopes probably are relatively minor and difficult to resolve from the major controls. The data indicate that the groundwater are derived predominantly from cold, isotopically light winter precipitation, and that the isotope values of groundwater from elevations above about 2.5-3.0 km in the Gallatin and northern Absaroka Ranges are light enough (The D ?149?) to be the presumed recharge water for the hydrothermal system in the Park. However, estimation of the present-day volume of this recharged, isotopically light water indicates that it is not adequate to supply the high (3-4 m3/s) thermal water discharges from YNP, and cooler temperatures at the time of recharge would be required. The volume of meteoric water with D values lighter than ?145? may be adequate for recharging the hydrothermal system, and this may be a more plausible value than the ?149? originally calculated from data that are subject to moderate uncertainties.

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2009–10

USGS Publications Warehouse

Macy, Jamie P.; Brown, Christopher R.

2011-01-01

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area. Precipitation in the area is typically between 6 and 14 inches per year. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2009 to September 2010. The monitoring program includes measurements of (1) groundwater withdrawals, (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In 2009, total groundwater withdrawals were 4,230 acre-ft, industrial withdrawals were 1,390 acre-ft, and municipal withdrawals were 2,840 acre-ft. Total withdrawals during 2009 were about 42 percent less than total withdrawals in 2005 because of Peabody Western Coal Company's discontinued use of water in a coal slurry used for transporting coal. From 2008 to 2009 total withdrawals increased by 3 percent and industrial withdrawals increased by approximately 15 percent, but total municipal withdrawals decreased by 2 percent. From 2009 to 2010, annually measured water levels in the Black Mesa area declined in 7 of 16 wells that were available for comparison in the unconfined areas of the N aquifer, and the median change was 0.1 foot. Water levels declined in 12 of 18 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was -0.3 foot. From the prestress period (prior to 1965) to 2010, the median water-level change for 34 wells in both the confined and unconfined area was -13.9 feet. Also, from the prestress period to 2009, the median water-level changes were -0.8 foot for 16 wells measured in the unconfined areas and -38.7 feet for 18 wells measured in the confined area. Spring flow was measured at four springs in 2010. Flow fluctuated during the period of record, but a decreasing trend was apparent at Moenkopi School Spring and Pasture Canyon Spring. Discharge at Burro Spring and Unnamed Spring near Dennehotso has remained relatively constant since they were first measured in the 1980s. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2009), Dinnebito Wash near Sand Springs 09401110 (1993 to 2009), Polacca Wash near Second Mesa 09400568 (1994 to 2009), and Pasture Canyon Springs 09401265 (2004 to 2009). Median winter flows (November through February) of each water year were used as an index of the amount of groundwater discharge at the above-named sites. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, which suggests no change in groundwater discharge. In 2010, water samples collected from 11 wells and 4 springs in the Black Mesa area were analyzed for selected chemical constituents, and the results were compared with previous analyses. Concentrations of dissolved solids, chloride, and sulfate have varied at all 11 wells for the period of record, but neither increasing nor decreasing trends over time were found. Dissolved-solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 12 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied much since the early 1980s, and there is no increasing or decreasing trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Burro Spring and Unnamed Spring near Dennehotso have varied for the period of record, but there is no increasing or decreasing trend in the data.

A rapid leaf-disc sampler for psychrometric water potential measurements.

PubMed

Wullschleger, S D; Oosterhuis, D M

1986-06-01

An instrument was designed which facilitates faster and more accurate sampling of leaf discs for psychrometric water potential measurements. The instrument consists of an aluminum housing, a spring-loaded plunger, and a modified brass-plated cork borer. The leaf-disc sampler was compared with the conventional method of sampling discs for measurement of leaf water potential with thermocouple psychrometers on a range of plant material including Gossypium hirsutum L., Zea mays L., and Begonia rex-cultorum L. The new sampler permitted a leaf disc to be excised and inserted into the psychrometer sample chamber in less than 7 seconds, which was more than twice as fast as the conventional method. This resulted in more accurate determinations of leaf water potential due to reduced evaporative water losses. The leaf-disc sampler also significantly reduced sample variability between individual measurements. This instrument can be used for many other laboratory and field measurements that necessitate leaf disc sampling.

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin; data on agricultural organic compounds, nutrients, and sediment in water, 1988-90

USGS Publications Warehouse

Sullivan, D.J.; Terrio, P.J.

1994-01-01

This report describes the sampling design and methods and presents data collected to determine the distribution of agricultural organic compounds, nutrients, and sediment in selected areas of the upper Illinois River Basin as part of the National Water-Quality Assessment program. Four stations in small watersheds (two urban, two agricultural) were sampled in 1988 and 1989. Seventeen stations in an agricultural subbasin were sampled in 1990. Samples were collected before, during, and after runoff events from late spring to midsummer to determine concentrations of agricultural organic compounds in surface waters resulting from storm runoff, as well as background concentrations. Over 200 water samples were analyzed for agricultural organic compound, nutrient, and suspended-sediment concentrations. The agricultural organic compounds included triazine and chlorophenoxy-acid herbicides, and organo-phosphorus insecticides.

Groundwater, Surface-Water, and Water-Chemistry Data, Black Mesa Area, Northeastern Arizona-2008-2009

USGS Publications Warehouse

Macy, Jamie P.

2010-01-01

The N aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area, which is typically about 6 to 14 inches per year. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2008 to September 2009. The monitoring program includes measurements of (1) groundwater withdrawals, (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In 2008, total groundwater withdrawals were 4,110 acre-feet, industrial withdrawals were 1,210 acre-ft, and municipal withdrawals were 2,900 acre-ft. Total withdrawals during 2008 were about 44 percent less than total withdrawals in 2005. From 2007 to 2008 total withdrawals decreased by 4 percent, industrial withdrawals increased by approximately 3 percent, but total municipal withdrawals decreased by 6 percent. From 2008 to 2009, annually measured water levels in the Black Mesa area declined in 8 of 15 wells that were available for comparison in the unconfined areas of the N aquifer, and the median change was -0.1 feet. Water levels declined in 11 of 18 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was -0.2 feet. From the prestress period (prior to 1965) to 2009, the median water-level change for 34 wells in both the confined and unconfined area was -11.8 feet. Also, from the prestress period to 2009, the median water-level changes were -1.6 feet for 16 wells measured in the unconfined areas and -36.7 feet for 18 wells measured in the confined area. Spring flow was measured at three springs in 2009. Flow fluctuated during the period of record, but a decreasing trend was apparent at Moenkopi School Spring and Pasture Canyon Spring. Discharge at Burro spring has remained constant since it was first measured in 1998. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2008), Dinnebito Wash near Sand Springs 09401110 (1993 to 2008), Polacca Wash near Second Mesa 09400568 (1994 to 2008), and Pasture Canyon Springs 09401265 (August 2004 to 2008). Median winter flows (November through February) of each water year were used as an index of the amount of groundwater discharge at the above-named sites. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, which suggests no change in groundwater discharge. In 2009, water samples collected from 6 wells and 3 springs in the Black Mesa area were analyzed for selected chemical constituents, and the results were compared with previous analyses. Concentrations of dissolved solids, chloride, and sulfate have varied at all 6 wells for the period of record, but neither increasing nor decreasing trends over time were found. Dissolved-solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 12 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied much since the early 1980s, and there is no trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Burro Spring have varied for the period of record, but there is no trend in the data.

Chemical and isotopic characteristics of geothermal fluids from Sulphur Springs, Saint Lucia

NASA Astrophysics Data System (ADS)

Joseph, Erouscilla P.; Fournier, Nicolas; Lindsay, Jan M.; Robertson, Richard; Beckles, Denise M.

2013-03-01

Sulphur Springs is a vigorous, geothermal field associated with the active Soufrière Volcanic Centre in southern Saint Lucia, Lesser Antilles island arc. The 'Sulphur Springs Park' is an important tourist attraction (touted as the 'world's only drive-through volcano') with some of the hot pools being developed into recreational pools. Some 200,000 people visit the park each year. Since 2001, the hydrothermal fluids of Sulphur Springs have been sampled as part of an integrated volcanic monitoring programme for the island. Gas and water samples were analysed to characterise the geochemistry of the hydrothermal system, and to assess the equilibrium state and subsurface temperatures of the reservoir. This has also enabled us, for the first time, to establish baseline data for future geochemical monitoring. The gases are of typical arc-type composition, with N2 excess and low He and Ar content. The dry gas composition is dominated by CO2 (ranging from 601-993 mmol/mol), with deeper magmatic sourced H2S-rich vapour undergoing boiling and redox changes in the geothermal reservoir to emerge with a hydrothermal signature in the fumarolic gases. Fluid contributions from magmatic degassing are also evident, mainly from the moderate to high contents of HCl and deeply-sourced H2S gas, respectively. Sulphur Springs hydrothermal waters have acid-sulphate type compositions (SO4 = 78-4008 mg/L; pH = 3-7), and are of primarily meteoric origin which have been affected by evaporation processes based on the enrichment in both δ18O and δD (δ18O = - 1 to 15‰ and δD = - 9 to 14‰ respectively) in relation to the global meteoric water line (GMWL). These waters are steam-heated water typically formed by absorption of H2S-rich gases in the near surface oxygenated groundwaters. Reservoir temperatures calculated from the evaluation of gas equilibria in the CO2-CH4-H2 system reveal higher temperatures (190 to 300 °C) than those derived from quartz geothermometry (95 to 169 °C), which appeared to be affected by dilution with meteoric waters. Generally, no significant variations in fluid geochemistry of the hydrothermal system were observed between 2001 and 2006, and we propose that there were no changes in the state of volcanic activity during this period.

Resistivity structure and geochemistry of the Jigokudani Valley hydrothermal system, Mt. Tateyama, Japan

NASA Astrophysics Data System (ADS)

Seki, Kaori; Kanda, Wataru; Tanbo, Toshiya; Ohba, Takeshi; Ogawa, Yasuo; Takakura, Shinichi; Nogami, Kenji; Ushioda, Masashi; Suzuki, Atsushi; Saito, Zenshiro; Matsunaga, Yasuo

2016-10-01

This study clarifies the hydrothermal system of Jigokudani Valley near Mt. Tateyama volcano in Japan by using a combination of audio-frequency magnetotelluric (AMT) survey and hot-spring water analysis in order to assess the potential of future phreatic eruptions in the area. Repeated phreatic eruptions in the area about 40,000 years ago produced the current valley morphology, which is now an active solfatara field dotted with hot springs and fumaroles indicative of a well-developed hydrothermal system. The three-dimensional (3D) resistivity structure of the hydrothermal system was modeled by using the results of an AMT survey conducted at 25 locations across the valley in 2013-2014. The model suggests the presence of a near-surface highly conductive layer of < 50 m in thickness across the entire valley, which is interpreted as a cap rock layer. Immediately below the cap rock is a relatively resistive body interpreted as a gas reservoir. Field measurements of temperature, pH, and electrical conductivity (EC) were taken at various hot springs across the valley, and 12 samples of hot-spring waters were analyzed for major ion chemistry and H2O isotopic ratios. All hot-spring waters had low pH and could be categorized into three types on the basis of the Cl-/SO 42 - concentration ratio, with all falling largely on a mixing line between magmatic fluids and local meteoric water (LMW). The geochemical analysis suggests that the hydrothermal system includes a two-phase zone of vapor-liquid. A comparison of the resistivity structure and the geochemically inferred structure suggests that a hydrothermal reservoir is present at a depth of approximately 500 m, from which hot-spring water differentiates into the three observed types. The two-phase zone appears to be located immediately beneath the cap rock structure. These findings suggest that the hydrothermal system of Jigokudani Valley exhibits a number of factors that could trigger a future phreatic eruption.

Uranium hydrogeochemical and stream sediment reconnaissance of the Cortez NTMS Quadrangle, Colorado/Utah, including concentrations of forty-three additional elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warren, R.G.

1979-05-01

During the summers of 1976, 1977, and 1978, 598 water and 1657 sediment samples were collected from 1775 locations within the 19,600-km/sup 2/ area of the Cortez Quadrangle, Colorado and Utah. Water samples were collected from streams, springs, and wells; sediment samples were collected from stream channels (wet and dry) and from springs. Each water sample was analyzed for 13 elements, and each sediment sample was analyzed for 43 elements. Uranium concentrations in water samples range from below the detection limit of 0.02 to 241.47 ppB and have a median of 0.87 ppB and a mean of 3.80 ppB. Backgroundmore » uranium concentrations are 2 to 5 ppB in several nonmountainous regions but are much lower in mountainous areas, particularly in the northeastern portion of the quadrangle. Water samples containing high uranium concentrations (>20 ppB) generally are associated with high conductivities, high concentrations of other metallic elements, and geologic units, such as the Mancos shale, that are unfavorable for uranium mineralization. However, four ground-water samples exhibit high uranium concentrations without concomitant high conductivities or high concentrations of other metallic elements. Two of these samples were collected from sites in the Slick Rock U--V district, and two were collected in the Morrison formation in the southern portion of the quadrangle where large uranium deposits are not known. Water samples collected from the northwestern corner of the quadrangle uniformly exhibit background uranium values but generally contain high nickel concentrations. In this area, U--Cu (White Canyon-type) deposits are hosted primarily by the Shinarump member of the Chinle formation. Uranium concentrations in sediment samples range from 0.51 to 76.41 ppM and have a median of 2.76 ppM and a mean of 3.08 ppM. Background uranium and metallic element concentrations decrease to the southwest from the highest values in the northeastern portion of the quadrangle.« less

Duck Valley Habitat Enhancement and Protection, 2000 Annual Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dodson, Guy; Pero, Vincent

The Duck Valley Indian Reservations' Habitat Enhancement project is an ongoing project designed to enhance and protect the critical riparian areas, natural springs, and native fish spawning areas on the Reservation. The project was begun in 1997 with the hiring of a fisheries biologist and the creation of a new department for the Tribes. The project's goals are to protect and enhance the springs, Owyhee River, its tributaries, and to develop a database that can be used by other fisheries professionals which includes information on water quality and fish composition, health, abundance, and genetic makeup. One habitat portion of themore » project is a focus on protection the numerous springs that provide clean, cool water to the Owyhee River. This will be accomplished through enclosure fences of the spring heads and water troughs to provide clean cool drinking water for wildlife and livestock. Another habitat portion of the project involves protecting headwater areas of streams with native fish populations. This is accomplished through enclosure fencing and riparian plantings on any eroded or degraded banks in the enclosure area. Finally, we monitor and evaluate the areas protected and enhanced. This is accomplished through biological sampling for temperature, Oxygen, sedimentation, and measurements of water depth, bank height and undercut, and width of stream. With the habitat and biological indices we will be able to evaluate how well protective measures are doing, and where to focus future efforts.« less

Residence times and nitrate transport in ground water discharging to streams in the Chesapeake Bay Watershed

USGS Publications Warehouse

Lindsey, Bruce D.; Phillips, Scott; Donnelly, Colleen A.; Speiran, Gary K.; Plummer, Niel; Bohlke, John Karl; Focazio, Michael J.; Burton, William C.; Busenberg, Eurybiades

2003-01-01

One of the major water-quality problems in the Chesapeake Bay is an overabundance of nutrients from the streams and rivers that discharge to the Bay. Some of these nutrients are from nonpoint sources such as atmospheric deposition, agricultural manure and fertilizer, and septic systems. The effects of efforts to control nonpoint sources, however, can be difficult to quantify because of the lag time between changes at the land surface and the response in the base-flow (ground water) component of streams. To help resource managers understand the lag time between implementation of management practices and subsequent response in the nutrient concentrations in the base-flow component of streamflow, a study of ground-water discharge, residence time, and nitrate transport in springs throughout the Chesapeake Bay Watershed and in four smaller watersheds in selected hydrogeomorphic regions (HGMRs) was conducted. The four watersheds were in the Coastal Plain Uplands, Piedmont crystalline, Valley and Ridge carbonate, and Valley and Ridge siliciclastic HGMRs.A study of springs to estimate an apparent age of the ground water was based on analyses for concentrations of chlorofluorocarbons in water samples collected from 48 springs in the Chesapeake Bay Watershed. Results of the analysis indicate that median age for all the samples was 10 years, with the 25th percentile having an age of 7 years and the 75th percentile having an age of 13 years. Although the number of samples collected in each HGMR was limited, there did not appear to be distinct differences in the ages between the HGMRs. The ranges were similar between the major HGMRs above the Fall Line (modern to about 50 years), with only two HGMRs of small geographic extent (Piedmont carbonate and Mesozoic Lowland) having ranges of modern to about 10 years. The median values of all the HGMRs ranged from 7 to 11 years. Not enough samples were collected in the Coastal Plain for comparison. Spring samples showed slightly younger water under wet conditions than under dry conditions. The apparent age of water from wells, springs, and other ground-water discharge points in the four targeted watersheds was modern to 60 years, which was similar to the apparent ages from the spring study. In the Pocomoke River Watershed in the Coastal Plain Uplands HGMR, the apparent age of ground-water samples ranged from 0 to 60 years; the ages in the vicinity of the streams ranged from 0 to 23 years.The apparent ages of ground water in the Polecat Creek Watershed in the Piedmont crystalline HGMR ranged from 2 to 30 years. The apparent ages of water from wells in the Muddy Creek Watershed in the Valley and Ridge carbonate HGMR ranged from 10 to 20 years (except for a single sample that was 45 years). The ages in the East Mahantango Creek Watershed in the Valley and Ridge siliciclastic HGMR ranged from 0 to 50 years. The distribution in apparent age of water from wells in the targeted watersheds, however, generally is older than that for water from the springs. The median age of water from wells in the Muddy Creek Watershed, for example, was 15 years, compared to 11 years for the water from the springs in that watershed, and less than 10 years for water from all springs in the spring study. The similarity in the ranges in apparent age of water from the wells and from the springs shows that the samples from the targeted watersheds and springs have bracketed the range of apparent ages that would be expected in the shallow ground-water-flow systems throughout the Chesapeake Bay Watershed.The apparent age of water from individual wells does not necessarily represent the entire distribution of ages of the discharging ground water, and it is this distribution of ages that affects the response of nutrient concentrations in stream base flow. Nutrient-reduction scenarios were modeled for two watersheds for which the distribution of apparent ground-water ages was available, the East Mahantango Creek Watershed in the Valley and Ridge siliciclastic HGMR and the Locust Grove Watershed in the Coastal Plain Uplands HGMR. A nutrient-reduction scenario was created for East Mahantango Creek, where the average residence time was determined to be approximately 10 years on the basis of the output of particle tracking from a ground-water-flow model. This scenario showed decreases of nearly 50 percent in base-flow concentrations of nitrate in streams within the first year after the reduction in nitrogen input; smaller reductions in nitrate concentration occurred in each subsequent year. A second scenario for that same watershed, in which the same 10-year average residence time was assumed and an exponential model was used for analysis, showed that a 50-percent reduction in base-flow concentrations of nitrate could take up to 5 years. For the Locust Grove Watershed, in which an average residence time of 32 years was assumed, simulation with the exponential model showed that it may take more than 20 years to achieve a 50-percent reduction in base-flow concentra-tions of nitrate. Although it was not possible to construct such scenarios for all watersheds, these examples show the range of possible responses to changes in nutrient inputs in two very different types of watersheds.Findings from this study include information on factors that affect ground-water age, spatial distribution of ages, and nitrogen transport. In the East Mahantango Creek Watershed and the Polecat Creek Watershed, the residence time varied spatially depending on the position of the flow path, and temporally depending on the recharge conditions. Generally, ground water in areas near the stream had short residence times and the water in upland areas had longer residence times. Water traveling through deep layers had longer residence times than water traveling through shallow layers, and residence times were faster under high recharge conditions than low recharge conditions. Ground water in the Pocomoke Watershed exhibits a similar pattern: younger water discharges to small order streams in headwater basins and older water discharges to larger streams near the basin outlet.Factors affecting nitrogen transport in ground water include spatial and temporal variation in input sources, ground-water age, and aquifer processes that lead to denitrification. Spatial and temporal variations in nitrogen sources affect all the watersheds. Tributaries with higher inputs of nitrogen have higher concentrations in stream base flow. Areas where nitrogen application rates have increased over time show an age-nitrate relation in ground-water samples. The age-nitrate relation can be affected by denitrification, which occurs in Pocomoke and East Mahantango Creeks but is not evident in Polecat and Muddy Creeks. In East Mahantango Creek, the level of denitrification is significant in water with residence times greater than 20 years, but because this is a small component of overall ground-water discharge to a stream, it may not remove a significant quantity of nitrogen from the system. Denitrification in Pocomoke Creek is significant and appears to affect mostly older water discharging to streams. Therefore, if most of the nitrogen entering these two streams is associated with the discharge of younger ground water, denitrification may not greatly affect the overall nitrogen delivery to these streams.Other findings of this study show that nitrate in ground water discharging along preferential flow paths may not be affected by natural processes, such as denitrification or uptake by riparian vegetation. Seeps to swales and ditches beneath the north uplands at Polecat Creek indicate a shallow water table and discharge of young ground water whereas the absence of such seeps on the south side indicates a deep water table and a lack of young ground water. Similarly, discharge at the base of the slope and to the valley wetland south of the creek but not north of the creek indicates a different role for the riparian forest on the two sides of the creek. In many of the systems where water discharges at the base of slopes to wetlands, ditches have been dug to drain the valley. Such drainage circumvents possible removal of nitrate by riparian vegetation.Because ground-water residence times do not appear directly related to the HGMRs, the targeting of management practices will achieve the most rapid response in water quality if directed at 1) watersheds with large agricultural sources of nitrate, 2) areas with the shortest ground-water-flow paths and 3) areas not affected by significant denitrification. The fastest response in stream base-flow concentrations of nitrogen to implementation of management practices would be to implement practices in those areas with the highest loads rather than attempt to target practices on the basis of HGMR stratification. Overall findings of the study indicate that 1) ground-water contributions to nitrogen in streamflow are significant, 2) some response to management practices should be evident in base-flow concentrations of nitrogen and loads within 1 to 5 years in watersheds with the shortest average residence times, but response time may be closer to 20 years in watersheds with longer average ground-water residence times, 3) the majority of the response in ground-water discharge to any changes in management practices will be distributed over a 10-year time period even in the watersheds with the fastest response times, and 4) given that half the streamflow is from ground-water discharge and the other half is runoff or soil water, about 90 percent of total water being discharged to a stream will be less than about a decade old; therefore, full implementation of nutrient reductions may result in improved streamwater quality in about a decade. In the more-likely scenario of gradual source reduction, the reduction in concentrations of nitrate in streams and aquifers would take longer than the examples shown here.

Uranium transport in the Walker River Basin, California and Nevada

USGS Publications Warehouse

Benson, L.V.; Leach, D.L.

1979-01-01

During the summer of 1976 waters from tributaries, rivers, springs and wells were sampled in the Walker River Basin. Snow and sediments from selected sites were also sampled. All samples were analyzed for uranium and other elements. The resulting data provide an understanding of the transport of uranium within a closed hydrologic basin as well as providing a basis for the design of geochemical reconnaissance studies for the Basin and Range Province of the Western United States. Spring and tributary data are useful in locating areas containing anomalous concentrations of uranium. However, agricultural practices obscure the presence of known uranium deposits and render impossible the detection of other known deposits. Uranium is extremely mobile in stream waters and does not appear to sorb or precipitate. Uranium has a long residence time (2500 years) in the open waters of Walker Lake; however, once it crosses the sediment-water interface, it is reduced to the U(IV) state and is lost from solution. Over the past two million years the amount of uranium transported to the terminal point of the Walker River system may have been on the order of 4 ?? 108 kg. This suggests that closed basin termini are sites for significant uranium accumulations and are, therefore, potential sites of uranium ore deposits. ?? 1979.

Changes in DOM Character and Composition during Spring Snow Melt in the Jemez River Basin Critical Zone Observatory.

NASA Astrophysics Data System (ADS)

Thompson, M.; Olshansky, Y.; Chorover, J.

2017-12-01

Dynamics of dissolved organic matter (DOM) in stream waters are important indicators of internal processes in the critical zone, such as decomposition and mobilization of soil organic matter, hydrologic flow paths, potential for metal mobilization and nutrient redistribution. Previous studies indicate that DOM concentration was highest during peak snow melt in the La Jara catchment located in the Jemez River Basin Critical Zone Observatory (Perdrial et al., 2014). We postulate that the molecular composition and character of DOM changes with the advance of spring snow melt. Water samples were collected from two flumes located at the outlets of the La Jara Creek and from a zero order basin within this catchment through the spring snowmelt from March 1 to May 15 2017. DOM concentration increased with stream discharge. Quantification of molecular changes was conducted using Fourier transform infrared spectroscopy (FTIR), which showed the variation in carboxyl abundance (wavenumbers 1680, 1600 and 1410 cm-1) correlated with dissolved organic carbon concentration, indicating that this component is relatively a constant fraction of the organic carbon exported through the stream during spring snowmelt. In contrast, amide vibrations (3550, 1640 and 670 cm-1) were shown to decrease with the advance of spring snowmelt. This trend further corresponded to a decrease in the ratio of carboxylic acid (above) to aromatic (1622, 1490, 955 cm-1) moieties, suggesting either a flush of compounds accumulated prior to spring snow melt, or increased decomposition of plant derived material in the soil that was then transported to the stream. Aliphatic components (2965, 2925 and 2865 cm-1) decreased from the beginning to the middle of sampling period, then showed an increase toward the end of snowmelt. O-Alkyl peak (1150 and 1073 cm-1) varied without a clear trend during the spring snowmelt. These changes in O-Alkyl and aliphatic compounds may be related to microbial derived compounds and indicate changes in microbial activity during the spring snowmelt. These results will be combined with concentration discharge analysis and data from fluorescence and UV-vis spectroscopy for evaluation and modeling of CZ processes dominated by spring snowmelt.

Recharge Area, Base-Flow and Quick-Flow Discharge Rates and Ages, and General Water Quality of Big Spring in Carter County, Missouri, 2000-04

USGS Publications Warehouse

Imes, Jeffrey L.; Plummer, Niel; Kleeschulte, Michael J.; Schumacher, John G.

2007-01-01

Exploration for lead deposits has occurred in a mature karst area of southeast Missouri that is highly valued for its scenic beauty and recreational opportunities. The area contains the two largest springs in Missouri (Big Spring and Greer Spring), both of which flow into federally designated scenic rivers. Concerns about potential mining effects on the area ground water and aquatic biota prompted an investigation of Big Spring. Water-level measurements made during 2000 helped define the recharge area of Big Spring, Greer Spring, Mammoth Spring, and Boze Mill Spring. The data infer two distinct potentiometric surfaces. The shallow potentiometric surface, where the depth-to-water is less than about 250 feet, tends to mimic topographic features and is strongly controlled by streams. The deep potentiometric surface, where the depth-to-water is greater than about 250 feet represents ground-water hydraulic heads within the more mature karst areas. A highly permeable zone extends about 20 mile west of Big Spring toward the upper Hurricane Creek Basin. Deeper flowing water in the Big Spring recharge area is directed toward this permeable zone. The estimated sizes of the spring recharge areas are 426 square miles for Big Spring, 352 square miles for Greer Spring, 290 square miles for Mammoth Spring, and 54 square miles for Boze Mill Spring. A discharge accumulation curve using Big Spring daily mean discharge data shows no substantial change in the discharge pattern of Big Spring during the period of record (water years 1922 through 2004). The extended periods when the spring flow deviated from the trend line can be attributed to prolonged departures from normal precipitation. The maximum possible instantaneous flow from Big Spring has not been adequately defined because of backwater effects from the Current River during high-flow conditions. Physical constraints within the spring conduit system may restrict its maximum flow. The largest discharge measured at Big Spring during the period of record (water years 1922 through 2004) was 1,170 cubic feet per second on December 7, 1982. The daily mean water temperature of Big Spring was monitored during water years 2001 through 2004 and showed little variability, ranging from 13 to 15? C (degree Celsius). Water temperatures generally vary less than 1? C throughout the year. The warmest temperatures occur during October and November and decrease until April, indicating Big Spring water temperature does show a slight seasonal variation. The use of the traditional hydrograph separation program HYSEP to determine the base flow and quick flow or runoff components at Big Spring failed to yield base-flow and quick-flow discharge curves that matched observations of spring characteristics. Big Spring discharge data were used in combination with specific conductance data to develop an improved hydrograph separation method for the spring. The estimated annual mean quick flow ranged from 15 to 48 cubic feet per second for the HYSEP analysis and ranged from 26 to 154 cubic feet per second for the discharge and specific conductance method for water years 2001 to 2004. Using the discharge and specific conductance method, the estimated base-flow component rises abruptly as the spring hydrograph rises, attains a peak value on the same day as the discharge peak, and then declines abruptly from its peak value. Several days later, base flow begins to increase again at an approximately linear trend, coinciding with the time at which the percentage of quick flow has reached a maximum after each recharge-induced discharge peak. The interval between the discharge peak and the peak in percentage quick flow ranges from 8 to 11 days for seven hydrograph peaks, consistent with quick-flow traveltime estimates by dye-trace tests from the mature karst Hurricane Creek Basin in the central part of the recharge area. Concentrations of environmental tracers chlorofluorocarbons (CFCs: CFC-11, CFC-12, CFC-113)

Determination of Organic and Inorganic Percentages and Mass of Suspended Material at Four Sites in the Illinois River in Northwestern Arkansas and Northeastern Oklahoma, 2005-07

USGS Publications Warehouse

Galloway, Joel M.

2008-01-01

The Illinois River located in northwestern Arkansas and northeastern Oklahoma is influenced by point and nonpoint sources of nutrient enrichment. This has led to increased algal growth within the stream, reducing water clarity. Also, sediment runoff from fields, pastures, construction sites, and other disturbed areas, in addition to frequent streambank failure, has increased sedimentation within the stream and decreased water clarity. A study was conducted by the U.S. Geological Survey in cooperation with the Arkansas Department of Environmental Quality and the U.S. Environmental Protection Agency to characterize the increased turbidity by determining the organic and inorganic composition and mass of suspended material in the Illinois River from August 2005 through July 2007. Water-quality samples were collected at four sites on the Illinois River (listed in downstream order): near Viney Grove, Arkansas; at Savoy, Arkansas; south of Siloam Springs, Arkansas; and near Tahlequah, Oklahoma. In general, turbidity, total suspended solids, suspended-sediment concentration, organic material concentration (measured as volatile suspended solids and ash-free dry mass), and chlorophyll a concentration were the greatest in samples collected from the Illinois River at Savoy and the least in samples from the most upstream Illinois River site (near Viney Grove) and the most downstream site (near Tahlequah) from August 2005 through July 2007. For example, the suspended-sediment concentration at the Illinois River at Savoy had a median of 15 milligrams per liter, and the total suspended solids had a median of 12 milligrams per liter. The Illinois River near Tahlequah had the least suspended-sediment concentration with a median of 10 milligrams per liter and the least total suspended solids with a median of 6 milligrams per liter. The turbidity, total suspended solids, suspended-sediment concentration, organic material concentration, and chlorophyll a concentration in samples collected during high-flow events were greater than in samples collected during base-flow conditions at the Illinois River at Savoy, south of Siloam Springs, and near Tahlequah. For example, the median turbidity for the Illinois River at Savoy was 3 nephelometric turbidity ratio units during base-flow conditions and 52 nephelometric turbidity ratio units during high-flow conditions. Organic material in the Illinois River generally composed between 13 and 47 percent of the total suspended material in samples collected from August 2005 through July 2007. Therefore, most of the suspended material in samples collected from the sites was inorganic material. Overall, the highest percentage of organic material was found at the Illinois River near Viney Grove and at the Illinois River near Tahlequah. The Illinois River south of Siloam Springs had the lowest percentage of organic material among the four sites. In general, the percentage of organic material was greater in samples collected during base-flow conditions compared to samples collected during high-flow conditions. The mean seasonal concentrations and percentages of organic material were the least in the fall (September through November) in samples collected from August 2005 to July 2007 from the four Illinois River sites, while the greatest concentrations and percentages of organic material occurred at various times of the year depending on the site. The greatest concentrations of organic material occurred in the summer (June through August) in samples from sites on the Illinois River near Viney Grove, at Savoy and south of Siloam Springs, but in the spring (March through May) in samples from the Illinois River near Tahlequah. The greatest percentages of organic material (least percentages of inorganic material) occurred in the summer in samples from the site near Viney Grove, the winter and summer at the site at Savoy, in the spring, fall, and winter (December through February) at the site south of Siloam Springs, an

Season matters when sampling streams for swine CAFO waste pollution impacts.

PubMed

Mallin, Michael A; McIver, Matthew R

2018-02-01

Concentrated (or confined) animal feed operations (CAFOs) are the principal means of livestock production in the United States, and such facilities pollute nearby waterways because of their waste management practices; CAFO waste is pumped from the confinement structure into a cesspit and sprayed on a field. Stocking Head Creek is located in eastern North Carolina, a state with >9,000,000 head of swine confined in CAFOs. This watershed contains 40 swine CAFOs; stream water quality was investigated at seven sites during 2016, with five sampling dates in early spring and five in summer. Geometric mean fecal coliform counts were in the thousands/100 mL at five sites in spring and all seven sites in summer. Excessive nitrate pollution was widespread with concentrations up to >11.0 mg N/L. Seasonality played an important role in pollutant concentrations. In North Carolina, spraying animal waste on adjoining fields is permissible from March 1 through September 30. Seasonal data showed significantly higher (p < 0.01) concentrations of conductivity, nitrate, total nitrogen, total organic carbon, and fecal bacteria in summer as opposed to early spring. Thus, sampling performed only in winter-early spring would significantly underestimate impacts from swine CAFO spray fields on nearby waterways.

Anthropogenic pressure in a Portuguese river: Endocrine-disrupting compounds, trace elements and nutrients.

PubMed

Ribeiro, Cláudia M R; Maia, Alexandra S; Ribeiro, Ana R; Couto, Cristina; Almeida, Agostinho A; Santos, Mariana; Tiritan, Maria E

2016-10-14

Natural organic compounds such as phytoestrogens and phytosterols found in various plants, as well as mycotoxins produced by fungi, can be found in aquatic environments. The aim of this study was to investigate the occurrence of three different classes of natural estrogenic compounds, i.e., phytoestrogens, phytosterols and mycotoxins, in estuarine water samples from the Ave River estuary. For that, water samples were collected at five sampling points distributed along the estuary at low tide, during 1 year, processed by solid-phase extraction (SPE) and analyzed by gas chromatography coupled to mass spectrometry (GC-MS). To correlate the presence of phytoestrogens and phytosterols in the estuarine water, local flora was collected on riverside. Trace elements content and physicochemical parameters such as nutrients and dissolved oxygen were also determined seasonally at each sampling point, to give insights for the evaluation of water quality and anthropogenic pressure. Both phytoestrogens and phytosterols showed a seasonal variation, with the highest values observed in spring and summer and the lowest in winter. Daidzein (DAID) was found up to 404.0 ng L(-1) in spring and coumestrol (COUM) was found up to 165.0 ng L(-1) in summer. The mycotoxin deoxynivalenol (DON) was ubiquitously determined with values ranging from 59.5 to 642.4 ng L(-1). Nutrients and metals distribution and concentration varied among sampling stations and seasons. This study revealed for the first time the presence of mycotoxins, various classes of phytoestrogens and stigmasterol (STG) in estuarine water from the Ave River (Portugal), and the evaluation of the water quality confirmed that this estuary is still highly impacted by anthropogenic activities.

Arsenic Speciation of Waters from the Aegean Region, Turkey by Hydride Generation: Atomic Absorption Spectrometry.

PubMed

Çiftçi, Tülin Deniz; Henden, Emur

2016-08-01

Arsenic in drinking water is a serious problem for human health. Since the toxicity of arsenic species As(III) and As(V) is different, it is important to determine the concentrations separately. Therefore, it is necessary to develop an accurate and sensitive method for the speciation of arsenic. It was intended with this work to determine the concentrations of arsenic species in water samples collected from Izmir, Manisa and nearby areas. A batch type hydride generation atomic absorption spectrometer was used. As(V) gave no signal under the optimal measurement conditions of As(III). A certified reference drinking water was analyzed by the method and the results showed excellent agreement with the reported values. The procedure was applied to 34 water samples. Eleven tap water, two spring water, 19 artesian well water and two thermal water samples were analyzed under the optimal conditions.

Detection of Cryptosporidium sp. Oocyst and Giardia sp. cyst in faucet water samples from cattle and goat farms in Taiwan.

PubMed

Watanabe, Yuko; Kimura, Kenji; Yang, Cheng-Hsiung; Ooi, Hong-Kean

2005-12-01

A survey on the presence of Cryptosporidium oocyst and Giardia cyst in livestock drinking water as well as the urban tap water throughout Taiwan was carried out. Water examination for the presence of the protozoa was conducted by filtering through a PTFE membrane followed by immunomagnetic separation (IMS) and immunostaining the sediment with commercially available monoclonal antibody against Cryptosporidium and Giardia. Of the 55 different water samples from various sources examined, 2 were found to contain both of Cryptosporidium oocyst and Giardia cyst, 1 was found to contain Cryptosporidium oocyst only. These protozoa-positive water samples, originating from underground well and from the mountain spring, were also used as drinking water for livestock. However, no Cryptosporidium oocyst was found in the city tap water. This is the first report of Cryptosporidium oocyst and Giardia cyst being found in the drinking water for livestock.

New geothermal database for Utah

USGS Publications Warehouse

Blackett, Robert E.; ,

1993-01-01

The Utah Geological Survey complied a preliminary database consisting of over 800 records on thermal wells and springs in Utah with temperatures of 20??C or greater. Each record consists of 35 fields, including location of the well or spring, temperature, depth, flow-rate, and chemical analyses of water samples. Developed for applications on personal computers, the database will be useful for geochemical, statistical, and other geothermal related studies. A preliminary map of thermal wells and springs in Utah, which accompanies the database, could eventually incorporate heat-flow information, bottom-hole temperatures from oil and gas wells, traces of Quaternary faults, and locations of young volcanic centers.

Biogeochemical characteristics of Kuan-Tzu-Ling, Chung-Lun and Bao-Lai hot springs in southern Taiwan.

PubMed

Maity, Jyoti Prakash; Liu, Chia-Chuan; Nath, Bibhash; Bundschuh, Jochen; Kar, Sandeep; Jean, Jiin-Shuh; Bhattacharya, Prosun; Liu, Jiann-Hong; Atla, Shashi B; Chen, Chien-Yen

2011-01-01

Hot springs are the important natural sources of geothermally heated groundwater from the Earth's crust. Kuan-Tzu-Ling (KTL), Chung-Lun (CL) and Bao-Lai (BL) are well-known hot springs in southern Taiwan. Fluid and mud (sediments) samples were collected from the eruption points of three hot springs for detailed biogeochemical characterization. The fluid sample displays relatively high concentrations of Na(+) and Cl(-) compared with K(+), Mg(2+), Ca(2+), NO(2) (-), and SO(4) (2-), suggesting a possible marine origin. The concentrations of Fe, Cr, Mn, Ni, V and Zn were significantly higher in the mud sediments compared with fluids, whereas high concentrations of As, Ba, Cu, Se, Sr and Rb were observed in the fluids. This suggests that electronegative elements were released during sediment-water interactions. High As concentration in the fluids was observed to be associated with low redox (Eh) conditions. The FTIR spectra of the humic acid fractions of the sediments showed the presence of possible functional groups of secondary amines, ureas, urethanesm (amide), and silicon. The sulfate-reducing deltaproteobacterium 99% similar to Desulfovibrio psychrotolerans (GU329907) were rich in the CL hot spring while mesophilic, proteolytic, thiosulfate- and sulfur-reducing bacterium that 99% similar to Clostridium sulfidigenes (GU329908) were rich in the BL hot spring.

Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs

USGS Publications Warehouse

Toth, D.J.; Katz, B.G.

2006-01-01

Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca-HCO3 (six), Na-Cl (four), and mixed (one). The evolution of water chemistry for Ca-HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na-Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4-53% of the total spring discharge. Multiple-tracer data-chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6) - for four Ca-HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na-Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge. ?? Springer-Verlag 2006.

Erratum: Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs

NASA Astrophysics Data System (ADS)

Toth, David J.; Katz, Brian G.

2006-09-01

Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca-HCO3 (six), Na-Cl (four), and mixed (one). The evolution of water chemistry for Ca-HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na-Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4-53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca-HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na-Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.

Statistical analyses of the background distribution of groundwater solutes, Los Alamos National Laboratory, New Mexico.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Longmire, Patrick A.; Goff, Fraser; Counce, D. A.

2004-01-01

Background or baseline water chemistry data and information are required to distingu ish between contaminated and non-contaminated waters for environmental investigations conducted at Los Alamos National Laboratory (referred to as the Laboratory). The term 'background' refers to natural waters discharged by springs or penetrated by wells that have not been contaminated by LANL or other municipal or industrial activities, and that are representative of groundwater discharging from their respective aquifer material. These investigations are conducted as part of the Environmental Restoration (ER) Project, Groundwater Protection Program (GWPP), Laboratory Surveillance Program, the Hydrogeologic Workplan, and the Site-Wide Environmental Impact Statement (SWEIS).more » This poster provides a comprehensive, validated database of inorganic, organic, stable isotope, and radionuclide analyses of up to 136 groundwater samples collected from 15 baseline springs and wells located in and around Los Alamos National Laboratory, New Mexico. The region considered in this investigation extends from the western edge of the Jemez Mountains eastward to the Rio Grande and from Frijoles Canyon northward to Garcia Canyon. Figure 1 shows the fifteen stations sampled for this investigation. The sampling stations and associated aquifer types are summarized in Table 1.« less

Influence of rock composition on the geochemistry of stream and spring waters from mountainous watersheds in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado

USGS Publications Warehouse

Miller, William Roger

2002-01-01

The ranges of geochemical baselines for stream and spring waters were determined and maps were constructed showing acid-neutralizing capacity and potential release of total dissolved solids for streams and spring waters for watersheds underlain by each of ten different rock composition types in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado (GMUG). Water samples were collected in mountainous headwater watersheds that have comparatively high precipitation and low evapotranspiration rates and that generally lack extensive ground-water reservoirs. Mountainous headwaters react quickly to changes in input of water from rain and melting snow and they are vulnerable to anthropogenic impact. Processes responsible for the control and mobility of elements in the watersheds were investigated. The geochemistry of water from the sampled watersheds in the GMUG, which are underlain by rocks that are relatively unmineralized, is compared to the geochemistry of water from the mineralized Redcloud Peak area. The water with the highest potential for release of total dissolved solids is from watersheds that are underlain by Paleozoic sedimentary rocks; that high potential is caused primarily by gypsum in those rocks. Water that has the highest acid-neutralizing capacity is from watersheds that are underlain by Paleozoic sedimentary rocks. The water from watersheds underlain by the Mancos Shale has the next highest acid-neutralizing capacity. Water that has the lowest acid-neutralizing capacity is from watersheds that are underlain by Tertiary ash-flow tuff. Tertiary sedimentary rocks containing oil shale, the Mesavede Formation containing coal, and the Mancos Shale all contain pyrite with elevated metal contents. In these mountainous head-water areas, water from watersheds underlain by these rock types is only slightly impacted by oxidation of pyrite, and over-all it is of good chemical quality. These geochemical baselines demonstrate the importance of rock composition in determining the types of waters that are in the headwater areas. The comparison of these geochemical baselines to later geochemical base-lines will allow recognition of any significant changes in water quality that may occur in the future.

Climate-induced warming imposes a threat to north European spring ecosystems.

PubMed

Jyväsjärvi, Jussi; Marttila, Hannu; Rossi, Pekka M; Ala-Aho, Pertti; Olofsson, Bo; Nisell, Jakob; Backman, Birgitta; Ilmonen, Jari; Virtanen, Risto; Paasivirta, Lauri; Britschgi, Ritva; Kløve, Bjørn; Muotka, Timo

2015-12-01

Interest in climate change effects on groundwater has increased dramatically during the last decade. The mechanisms of climate-related groundwater depletion have been thoroughly reviewed, but the influence of global warming on groundwater-dependent ecosystems (GDEs) remains poorly known. Here we report long-term water temperature trends in 66 northern European cold-water springs. A vast majority of the springs (82%) exhibited a significant increase in water temperature during 1968-2012. Mean spring water temperatures were closely related to regional air temperature and global radiative forcing of the corresponding year. Based on three alternative climate scenarios representing low (RCP2.6), intermediate (RCP6) and high-emission scenarios (RCP8.5), we estimate that increase in mean spring water temperature in the region is likely to range from 0.67 °C (RCP2.6) to 5.94 °C (RCP8.5) by 2086. According to the worst-case scenario, water temperature of these originally cold-water ecosystems (regional mean in the late 1970s: 4.7 °C) may exceed 12 °C by the end of this century. We used bryophyte and macroinvertebrate species data from Finnish springs and spring-fed streams to assess ecological impacts of the predicted warming. An increase in spring water temperature by several degrees will likely have substantial biodiversity impacts, causing regional extinction of native, cold-stenothermal spring specialists, whereas species diversity of headwater generalists is likely to increase. Even a slight (by 1 °C) increase in water temperature may eliminate endemic spring species, thus altering bryophyte and macroinvertebrate assemblages of spring-fed streams. Climate change-induced warming of northern regions may thus alter species composition of the spring biota and cause regional homogenization of biodiversity in headwater ecosystems. © 2015 John Wiley & Sons Ltd.

Evaluation of nutrient quality-assurance data for Alexanders and Mount Rock Spring basins, Cumberland County, Pennsylvania

USGS Publications Warehouse

Witt, E. C.; Hippe, D.J.; Giovannitti, R.M.

1992-01-01

A total of 304 nutrient samples were collected from May 1990 through September 1991 to determine concentrations and loads of nutrients in water discharged from two spring basins in Cumberland County, Pa. Fifty-four percent of these nutrient samples were for the evaluation of (1) laboratory consistency, (2) container and preservative cleanliness, (3) maintenance of analyte representativeness as affected by three different preservation methods, and (4) comparison of analyte results with the "Most Probable Value" for Standard Reference Water Samples. Results of 37 duplicate analyses indicate that the Pennsylvania Department of Environmental Resources, Bureau of Laboratories (principal laboratory) remained within its ±10 percent goal for all but one analyte. Results of the blank analysis show that the sampling containers did not compromise the water quality. However, mercuric-chloride-preservation blanks apparently contained measurable ammonium in four of five samples and ammonium plus organic nitrogen in two of five samples. Interlaboratory results indicate substantial differences in the determination of nitrate and ammonium plus organic nitrogen between the principal laboratory and the U.S. Geological Survey National Water-Quality Laboratory. In comparison with the U.S. Environmental Protection Agency Quality-Control Samples, the principal laboratory was sufficiently accurate in its determination of nutrient anafytes. Analysis of replicate samples indicated that sulfuric-acid preservative best maintained the representativeness of the anafytes nitrate and ammonium plus organic nitrogen, whereas, mercuric chloride best maintained the representativeness of orthophosphate. Comparison of nutrient analyte determinations with the Most Probable Value for each preservation method shows that two of five analytes with no chemical preservative compare well, three of five with mercuric-chloride preservative compare well, and three of five with sulfuricacid preservative compare well.

Pesticides in the surface waters of Lake Vistonis Basin, Greece: Occurrence and environmental risk assessment.

PubMed

Papadakis, Emmanouil-Nikolaos; Tsaboula, Aggeliki; Kotopoulou, Athina; Kintzikoglou, Katerina; Vryzas, Zisis; Papadopoulou-Mourkidou, Euphemia

2015-12-01

A study was undertaken for the evaluation of the pesticide pollution caused by the agricultural activities in the basin of Lake Vistonis, Greece during the years 2010-2012. Water samples were collected from Lake Vistonis, four major rivers and various small streams and agriculture drainage canals. The concentration of 302 compounds was determined after solid-phase extraction of the water samples and subsequent LC-MS/MS and GC-MS/MS analysis of the extracts. Overall, herbicides were the most frequently detected pesticides (57%), followed by insecticides (28%) and fungicides (14%). In Lake Vistonis 11 pesticides were detected. Specifically, fluometuron was detected in the 75% of the samples (maximum concentration 0.088 μg/L) whereas lambda-cyhalothrin was detected in all the samples of spring 2011 and alphamethrin in all the samples of spring 2012 (maximum concentration 0.041 and 0.168 μg/L, respectively). In the rivers and drainage canals 68 pesticides were detected. Specifically, fluometuron was detected in the 53% of the samples (maximum concentration 317.6 μg/L) followed by chlorpyrifos and prometryn (16 and 13% of the samples respectively). An environmental risk assessment was performed by employing the Risk Quotient (RQ) method. The risk assessment revealed that at least one pesticide concentration led to a RQ>1 in 20% of the samples. In Lake Vistonis, alphamethrin and lambda-cyhalothrin concentrations resulted in RQ>1, whereas in the other water bodies this was mainly the result of chlorpyrifos-methyl and alphamethrin exposure. In contrast, herbicide and fungicide concentrations contributed substantially less to environmental risks. Copyright © 2015 Elsevier B.V. All rights reserved.

The Biogeography of Endorheic Soda Lakes in the Western United States

NASA Astrophysics Data System (ADS)

Stamps, B. W.; Petryshyn, V.; Johnson, H.; Berelson, W.; Nunn, H. S.; Stevenson, B. S.; Loyd, S. J.; Oremland, R. S.; Miller, L. G.; Rosen, M. R.; Corsetti, F. A.; Spear, J. R.

2016-12-01

Closed-basin (endorheic) soda lakes are of economic, social, and ecological importance. Shifts in global climate, which in turn affects local climate, significantly impact the distribution and diversity of microbial communities and lake ecologies. In California, the Mono Lake Basin (MLB) is especially fragile, as it has undergone a significant decline in lake level beginning in the early twentieth century due to both climatic effects and water diversion. The result is a lake with elevated salinity (60-90 g/L) and pH (9.8). The diversion of MLB water has created a unique lake environment dominated by a single macroeukaryote (Artemia monica) in which primary production is controlled at all depths by the microalgae Picocystis sp. In order to better understand the microbial diversity and functional potential of Mono Lake during an on-going drought and climatic upheaval, a combined geochemical, metagenomic, and metatranscriptomic study was undertaken. Members of The International GeoBiology course sampled the water column at multiple depths in the summer of 2016, during a large bloom of Picocystis. A mud spring from a volcanic island (Paoha) near the center of the lake was also sampled. The spring was recently submerged and interacts intermittently with Mono Lake, which may allow for mixing of microbial communities as lake levels fluctuate. Surface sediment samples were also taken from 7 m water depth. Finally, via SSU rRNA gene sequence analyses, the microbial communities of nearby soda lakes were compared in an attempt to place the Mono Lake community in the context of the overall regional biodiversity of endorheic soda lakes. Overall the microbial communities at Mono Lake were distinct both in the bacterial community composition and the abundance of Picocystis from those found at other sampled soda lakes or the surrounding rivers and springs. Our results reveal diverse microbial ecosystems at multiple lakes potentially at risk to continued climate change.

Carbonate ion-enriched hot spring water promotes skin wound healing in nude rats.

PubMed

Liang, Jingyan; Kang, Dedong; Wang, Yingge; Yu, Ying; Fan, Jianglin; Takashi, En

2015-01-01

Hot spring or hot spa bathing (Onsen) is a traditional therapy for the treatment of certain ailments. There is a common belief that hot spring bathing has therapeutic effects for wound healing, yet the underlying molecular mechanisms remain unclear. To examine this hypothesis, we investigated the effects of Nagano hot spring water (rich in carbonate ion, 42°C) on the healing process of the skin using a nude rat skin wound model. We found that hot spring bathing led to an enhanced healing speed compared to both the unbathed and hot-water (42°C) control groups. Histologically, the hot spring water group showed increased vessel density and reduced inflammatory cells in the granulation tissue of the wound area. Real-time RT-PCR analysis along with zymography revealed that the wound area of the hot spring water group exhibited a higher expression of matrix metalloproteinases-2 and -9 compared to the two other control groups. Furthermore, we found that the enhanced wound healing process induced by the carbonate ion-enriched hot spring water was mediated by thermal insulation and moisture maintenance. Our results provide the evidence that carbonate ion-enriched hot spring water is beneficial for the treatment of skin wounds.

Vertical variation in the amplitude of the seasonal isotopic content of rainfall as a tool to jointly estimate the groundwater recharge zone and transit times in the Ordesa and Monte Perdido National Park aquifer system, north-eastern Spain.

PubMed

Jódar, Jorge; Custodio, Emilio; Lambán, Luis Javier; Martos-Rosillo, Sergio; Herrera-Lameli, Christian; Sapriza-Azuri, Gonzalo

2016-12-15

The time series of stable water isotope composition relative to meteorological stations and springs located in the high mountainous zone of the Ordesa and Monte Perdido National Park are analyzed in order to study how the seasonal isotopic content of precipitation propagates through the hydrogeological system in terms of the aquifer recharge zone elevation and transit time. The amplitude of the seasonal isotopic composition of precipitation and the mean isotopic content in rainfall vary along a vertical transect, with altitudinal slopes for δ 18 O of 0.9‰/km for seasonal amplitude and -2.2‰/km for isotopic content. The main recharge zone elevation for the sampled springs is between 1950 and 2600m·a.s.l. The water transit time for the sampled springs ranges from 1.1 to 4.5yr, with an average value of 1.85yr and a standard deviation of 0.8yr. The hydrological system tends to behave as a mixing reservoir. Copyright © 2016 Elsevier B.V. All rights reserved.

Water Treatment Technology - Springs.

ERIC Educational Resources Information Center

Ross-Harrington, Melinda; Kincaid, G. David

One of twelve water treatment technology units, this student manual on springs provides instructional materials for two competencies. (The twelve units are designed for a continuing education training course for public water supply operators.) The competencies focus on spring basin construction and spring protection. For each competency, student…

Determination of heavy metal levels in water, sediment and tissues of tench (Tinca tinca L., 1758) from Beyşehir Lake (Turkey).

PubMed

Tekin-Ozan, Selda

2008-10-01

In the present study, some heavy metals (Cu, Fe, Zn and Mn) were seasonally determined in water, sediment and some tissues of fish Tinca tinca from Beyşehir Lake, which is an important bird nesting and visiting area, a water source for irrigation and drinking. In the water, Fe has the highest concentrations among the studied metals. Generally, the metal concentrations increased in the hottest period decreased in warm seasons. Results for levels in water were compared with national and international water quality guidelines, as well as literature data reported for the lakes. Fe was the highest in sediment samples, also Cu and Zn were the highest in spring, while Fe and Mn were in autumn. Among the heavy metals studied, Cu and Mn were below the detection limits in some tissues. Generally, higher concentrations of the tested metals were found in the summer and winter, compared with those during the autumn and spring seasons. High levels of heavy metals were found in liver of T. tinca, while low levels in muscle samples. Metal concentrations in the muscle of examined fish were within the safety permissible levels for human consumption. The present study shows that precautions need to be taken in order to prevent further heavy metal pollution.

Biodiversity of thermophilic prokaryotes with hydrolytic activities in hot springs of Uzon Caldera, Kamchatka (Russia).

PubMed

Kublanov, Ilya V; Perevalova, Anna A; Slobodkina, Galina B; Lebedinsky, Aleksander V; Bidzhieva, Salima K; Kolganova, Tatyana V; Kaliberda, Elena N; Rumsh, Lev D; Haertlé, Thomas; Bonch-Osmolovskaya, Elizaveta A

2009-01-01

Samples of water from the hot springs of Uzon Caldera with temperatures from 68 to 87 degrees C and pHs of 4.1 to 7.0, supplemented with proteinaceous (albumin, casein, or alpha- or beta-keratin) or carbohydrate (cellulose, carboxymethyl cellulose, chitin, or agarose) biological polymers, were filled with thermal water and incubated at the same sites, with the contents of the tubes freely accessible to the hydrothermal fluid. As a result, several enrichment cultures growing in situ on different polymeric substrates were obtained. Denaturing gradient gel electrophoresis (DGGE) analysis of 16S rRNA gene fragments obtained after PCR with Bacteria-specific primers showed that the bacterial communities developing on carbohydrates included the genera Caldicellulosiruptor and Dictyoglomus and that those developing on proteins contained members of the Thermotogales order. DGGE analysis performed after PCR with Archaea- and Crenarchaeota-specific primers showed that archaea related to uncultured environmental clones, particularly those of the Crenarchaeota phylum, were present in both carbohydrate- and protein-degrading communities. Five isolates obtained from in situ enrichments or corresponding natural samples of water and sediments represented the bacterial genera Dictyoglomus and Caldanaerobacter as well as new archaea of the Crenarchaeota phylum. Thus, in situ enrichment and consequent isolation showed the diversity of thermophilic prokaryotes competing for biopolymers in microbial communities of terrestrial hot springs.

Geochemistry of Standard Mine Waters, Gunnison County, Colorado, July 2009

USGS Publications Warehouse

Verplanck, Philip L.; Manning, Andrew H.; Graves, Jeffrey T.; McCleskey, R. Blaine; Todorov, Todor I.; Lamothe, Paul J.

2009-01-01

In many hard-rock-mining districts water flowing from abandoned mine adits is a primary source of metals to receiving streams. Understanding the generation of adit discharge is an important step in developing remediation plans. In 2006, the U.S. Environmental Protection Agency listed the Standard Mine in the Elk Creek drainage basin near Crested Butte, Colorado as a superfund site because drainage from the Standard Mine enters Elk Creek, contributing dissolved and suspended loads of zinc, cadmium, copper, and other metals to the stream. Elk Creek flows into Coal Creek, which is a source of drinking water for the town of Crested Butte. In 2006 and 2007, the U.S. Geological Survey undertook a hydrogeologic investigation of the Standard Mine and vicinity and identified areas of the underground workings for additional work. Mine drainage, underground-water samples, and selected spring water samples were collected in July 2009 for analysis of inorganic solutes as part of a follow-up study. Water analyses are reported for mine-effluent samples from Levels 1 and 5 of the Standard Mine, underground samples from Levels 2 and 3 of the Standard Mine, two spring samples, and an Elk Creek sample. Reported analyses include field measurements (pH, specific conductance, water temperature, dissolved oxygen, and redox potential), major constituents and trace elements, and oxygen and hydrogen isotopic determinations. Overall, water samples collected in 2009 at the same sites as were collected in 2006 have similar chemical compositions. Similar to 2006, water in Level 3 did not flow out the portal but was observed to flow into open workings to lower parts of the mine. Many dissolved constituent concentrations, including calcium, magnesium, sulfate, manganese, zinc, and cadmium, in Level 3 waters substantially are lower than in Level 1 effluent. Concentrations of these dissolved constituents in water samples collected from Level 2 approach or exceed concentrations of Level 1 effluent suggesting that water-rock interaction between Levels 3 and 1 can account for the elevated concentration of metals and other constituents in Level 1 portal effluent. Ore minerals (sphalerite, argentiferous galena, and chalcopyrite) are the likely sources of zinc, cadmium, lead, and copper and are present within the mine in unmined portions of the vein system, within plugged ore chutes, and in muck piles.

Geochemical evolution processes and water-quality observations based on results of the National Water-Quality Assessment Program in the San Antonio segment of the Edwards aquifer, 1996-2006

USGS Publications Warehouse

Musgrove, MaryLynn; Fahlquist, Lynne; Houston, Natalie A.; Lindgren, Richard J.; Ging, Patricia B.

2010-01-01

As part of the National Water-Quality Assessment Program, the U.S. Geological Survey collected and analyzed groundwater samples during 1996-2006 from the San Antonio segment of the Edwards aquifer of central Texas, a productive karst aquifer developed in Cretaceous-age carbonate rocks. These National Water-Quality Assessment Program studies provide an extensive dataset of groundwater geochemistry and water quality, consisting of 249 groundwater samples collected from 136 sites (wells and springs), including (1) wells completed in the shallow, unconfined, and urbanized part of the aquifer in the vicinity of San Antonio (shallow/urban unconfined category), (2) wells completed in the unconfined (outcrop area) part of the regional aquifer (unconfined category), and (3) wells completed in and springs discharging from the confined part of the regional aquifer (confined category). This report evaluates these data to assess geochemical evolution processes, including local- and regional-scale processes controlling groundwater geochemistry, and to make water-quality observations pertaining to sources and distribution of natural constituents and anthropogenic contaminants, the relation between geochemistry and hydrologic conditions, and groundwater age tracers and travel time. Implications for monitoring water-quality trends in karst are also discussed. Geochemical and isotopic data are useful tracers of recharge, groundwater flow, fluid mixing, and water-rock interaction processes that affect water quality. Sources of dissolved constituents to Edwards aquifer groundwater include dissolution of and geochemical interaction with overlying soils and calcite and dolomite minerals that compose the aquifer. Geochemical tracers such as magnesium to calcium and strontium to calcium ratios and strontium isotope compositions are used to evaluate and constrain progressive fluid-evolution processes. Molar ratios of magnesium to calcium and strontium to calcium in groundwater typically increase along flow paths; results for samples of Edwards aquifer groundwater show an increase from shallow/urban unconfined, to unconfined, to confined groundwater categories. These differences are consistent with longer residence times and greater extents of water-rock interaction controlling fluid compositions as groundwater evolves from shallow unconfined groundwater to deeper confined groundwater. Results for stable isotopes of hydrogen and oxygen indicate specific geochemical processes affect some groundwater samples, including mixing with downdip saline water, mixing with recent recharge associated with tropical cyclonic storms, or mixing with recharge water than has undergone evaporation. The composition of surface water recharging the aquifer, as well as mixing with downdip water from the Trinity aquifer or the saline zone, also might affect water quality. A time-series record (1938-2006) of discharge at Comal Springs, one of the major aquifer discharge points, indicates an upward trend for nitrate and chloride concentrations, which likely reflects anthropogenic activities. A small number of organic contaminants were routinely or frequently detected in Edwards aquifer groundwater samples. These were the pesticides atrazine, its degradate deethylatrazine, and simazine; the drinking-water disinfection byproduct chloroform; and the solvent tetrachloroethene. Detection of these contaminants was most frequent in samples of the shallow/urban unconfined groundwater category and least frequent in samples of the unconfined groundwater category. Results indicate that the shallow/urban unconfined part of the aquifer is most affected by anthropogenic contaminants and the unconfined part of the aquifer is the least affected. The high frequency of detection for these anthropogenic contaminants aquifer-wide and in samples of deep, confined groundwater indicates that the entire aquifer is susceptible to water-quality changes as a result of anthropogenic activities. L

Late Spring Nitrate Distributions Beneath the Ice-Covered Northeastern Chukchi Shelf

NASA Astrophysics Data System (ADS)

Arrigo, Kevin R.; Mills, Matthew M.; van Dijken, Gert L.; Lowry, Kate E.; Pickart, Robert S.; Schlitzer, Reiner

2017-09-01

Measurements of late springtime nutrient concentrations in Arctic waters are relatively rare due to the extensive sea ice cover that makes sampling difficult. During the SUBICE (Study of Under-ice Blooms In the Chukchi Ecosystem) cruise in May-June 2014, an extensive survey of hydrography and prebloom concentrations of inorganic macronutrients, oxygen, particulate organic carbon and nitrogen, and chlorophyll a was conducted in the northeastern Chukchi Sea. Cold (<-1.5°C) winter water was prevalent throughout the study area, and the water column was weakly stratified. Nitrate (NO3-) concentration averaged 12.6 ± 1.92 μM in surface waters and 14.0 ± 1.91 μM near the bottom and was significantly correlated with salinity. The highest NO3- concentrations were associated with winter water within the Central Channel flow path. NO3- concentrations were much reduced near the northern shelf break within the upper halocline waters of the Canada Basin and along the eastern side of the shelf near the Alaskan coast. Net community production (NCP), estimated as the difference in depth-integrated NO3- content between spring (this study) and summer (historical), varied from 28 to 38 g C m-2 a-1. This is much lower than previous NCP estimates that used NO3- concentrations from the southeastern Bering Sea as a baseline. These results demonstrate the importance of using profiles of NO3- measured as close to the beginning of the spring bloom as possible when estimating local NCP. They also show that once the snow melts in spring, increased light transmission through the sea ice to the waters below the ice could fuel large phytoplankton blooms over a much wider area than previously known.

Hydrogeochemical, Stable Isotopes and Hydrology of Fogo Volcano Perched Aquifers: São Miguel Island, Azores (Portugal)

NASA Astrophysics Data System (ADS)

Antunes, P. C.; Boutt, D. F.; Martini, A. M.; Ferstad, J.; Rodrigues, F. C.

2012-12-01

Fogo Volcano is located at central part of São Miguel Island and corresponds to a polygenetic volcano with a caldera made by an intercalated accumulation of volcaniclastic deposits and lava flows. São Miguel Island is one of the nine volcanic islands that form the Azores Archipelago. The volcano is 950 meters high, with a caldera diameter of 3.2 Km, which holds a lake inside. The last eruption occurred in 1563-1564, as one of a group of seven traquitic eruptions occurring within the last 5000 years. The volcanic activity is related to hydrothermal activity in a geothermal field located in the volcanoes North flank. The hydrology of Fogo Volcano is characterized by a series of perched-water bodies drained by a large number of springs grouped at different altitudes on the volcano flanks. It is possible to identify three types of water (1) Fresh water, cold temperature (12 - 17 C) with low dissolved solids contents (average conductivity of 179 μS/cm), pH range between 6.60 and 7.82, dominated by the major ions Na, K, HCO3, and Cl, and correspond mainly to sodium bicarbonate type water. (2) Mineral water, cold temperature (12.5 - 19.4 C) with low dissolved solids contents (average conductivity of 261 μS/cm), acid pH range between 4.62 and 6.79, and correspond mainly to sodium bicarbonate type water. (3) Thermal water, with temperature of 32 C, high dissolved solids content (4.62 mS/cm), with a pH around 4.50 and belongs to sodium sulfate type water. South Fogo volcano have only fresh water springs and at high elevation, springs drained from pumice fall deposits near 700 m of altitude. Water dissolved solids contents increased slightly with springs at lower altitude due to water-rock interaction. Springs sampled around 700 m high have a conductivity average of 85 μS/cm, at 520 m an average of 129 μS/cm, at 430 m an average of 182 μS/cm, at 200 m an average of 192 μS/cm and at 12 m high sea level and average of 472 μS/cm. This trend is observed at North Fogo volcano flank for fresh water springs. Mineral and thermal waters show an influence of magmatic input, a natural water pollution source in areas with volcanic activity. Rainwater isotopic composition showed elevation effect variation with lighter δ18O and δD values and recharge appear to be at highest altitudes with influence of sea salt from atmospheric contamination. Evaporation is clearly associated with mineral and thermal waters. Hydrogeochemistry differentiates the low altitude springs at South volcano flank where they are separated by ultramafic intrusions supporting the existence of dike impounded aquifers as Peterson (1972) proposed with the Hawaiian conceptual model for volcanic islands.

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona - 2010-2011

USGS Publications Warehouse

Macy, Jamie P.; Brown, Christopher R.; Anderson, Jessica R.

2012-01-01

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area. Precipitation in the area is typically between 6 to 14 inches per year. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2010 to September 2011. The monitoring program includes measurements of (1) groundwater withdrawals, (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In 2010, total groundwater withdrawals were 4,040 acre-ft, industrial withdrawals were 1,170 acre-ft, and municipal withdrawals were 2,870 acre-ft. Total withdrawals during 2010 were about 42 percent less than total withdrawals in 2005 because of Peabody Western Coal Company's discontinued use of water to transport coal in a slurry. From 2009 to 2010 total withdrawals decreased by 5 percent; industrial withdrawals decreased by approximately 16 percent, and total municipal withdrawals increased by 1 percent. From 2010 to 2011, annually measured water levels in the Black Mesa area declined in 7 of 15 wells that were available for comparison in the unconfined areas of the N aquifer, and the median change was 0.0 foot. Water levels declined in 11 of 18 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was -0.7 foot. From the prestress period (prior to 1965) to 2011, the median water-level change for 33 wells in both the confined and unconfined areas was -15.0 feet. Also, from the prestress period to 2011, the median water-level changes were -1.2 foot for 15 wells measured in the unconfined areas and -41.2 feet for 18 wells measured in the confined area. Spring flow was measured at three springs in 2011. Flow fluctuated during the period of record, but a decreasing trend was apparent at Moenkopi School Spring and Pasture Canyon Spring. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2010), Dinnebito Wash near Sand Springs 09401110 (1993 to 2010), Polacca Wash near Second Mesa 09400568 (1994 to 2010), and Pasture Canyon Springs 09401265 (2004 to 2010). Median winter flows (November through February) of each water year were used as an index of the amount of groundwater discharge at the above-named sites. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, which suggests no change in groundwater discharge. In 2011, water samples collected from 11 wells and 4 springs in the Black Mesa area were analyzed for selected chemical constituents, and the results were compared with previous analyses. Concentrations of dissolved solids, chloride, and sulfate have varied at all 11 wells for the period of record, but neither increasing nor decreasing trends over time were found. Dissolved-solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 12 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied much since the early 1980s, and there is no increasing or decreasing trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Burro Spring and Unnamed Spring near Dennehotso have varied for the period of record, but there is no increasing or decreasing trend in the data.

Implications of ground water chemistry and flow patterns for earthquake studies

USGS Publications Warehouse

Guangcai, W.; Zuochen, Z.; Min, W.; Cravotta, C.A.; Chenglong, L.

2005-01-01

Ground water can facilitate earthquake development and respond physically and chemically to tectonism. Thus, an understanding of ground water circulation in seismically active regions is important for earthquake prediction. To investigate the roles of ground water in the development and prediction of earthquakes, geological and hydrogeological monitoring was conducted in a seismogenic area in the Yanhuai Basin, China. This study used isotopic and hydrogeochemical methods to characterize ground water samples from six hot springs and two cold springs. The hydrochemical data and associated geological and geophysical data were used to identify possible relations between ground water circulation and seismically active structural features. The data for ??18O, ??D, tritium, and 14C indicate ground water from hot springs is of meteoric origin with subsurface residence times of 50 to 30,320 years. The reservoir temperature and circulation depths of the hot ground water are 57??C to 160??C and 1600 to 5000 m, respectively, as estimated by quartz and chalcedony geothermometers and the geothermal gradient. Various possible origins of noble gases dissolved in the ground water also were evaluated, indicating mantle and deep crust sources consistent with tectonically active segments. A hard intercalated stratum, where small to moderate earthquakes frequently originate, is present between a deep (10 to 20 km), high-electrical conductivity layer and the zone of active ground water circulation. The ground water anomalies are closely related to the structural peculiarity of each monitoring point. These results could have implications for ground water and seismic studies in other seismogenic areas. Copyright ?? 2005 National Ground Water Association.

Groundwater resources monitoring and population displacement in northern Uganda

NASA Astrophysics Data System (ADS)

Chalikakis, K.; Hammache, Y.; Nawa, A.; Slinski, K.; Petropoulos, G.; Muteesasira, A.

2009-04-01

Northern Uganda has been devastated by more than 20 years of open conflict by the LRA (Lord's Resistance Army) and the Government of Uganda. This war has been marked by extreme violence against civilians, who had been gathered in protected IDP (Internally Displaced Persons) camps. At the height of the displacement in 2007, the UN office for coordination of humanitarian affairs, estimated that nearly 2.5 million people were interned into approximately 220 camps throughout Northern Uganda. With the improved security since mid-2006, the people displaced by the conflict in Northern Uganda started to move out of the overcrowded camps and return either to their villages/parishes of origin or to resettlement/transit sites. However, basic water, sanitation and hygiene infrastructure in the return areas or any new settlements sites are minimal. People returning to their villages of origin encounter a situation where in many cases there is no access to safe water. Since 1998 ACF (Action Against Hunger, part of the Action Contre la Faim International Network) activities have been concentrated in the Acholi and Lango regions of Northern Uganda. ACF's WASH (Water, sanitation and hygiene) department interventions concern sanitation infrastructure, hygiene education and promotion as well as water points implementation. To ensure safe water access, actions are focused in borehole construction and traditional spring rehabilitation, also called "protected" springs. These activities follow the guidelines as set forth by the international WASH cluster, led by UNICEF. A three year project (2008-2010) is being implemented by ACF, to monitor the available groundwater resources in Northern Uganda. The main objectives are: 1. to monitor the groundwater quality from existing water points during different hydrological seasons, 2. to identify, if any, potential risks of contamination from population concentrations and displacement, lack of basic infrastructure and land use, and finally 3. to provide a guideline for a sustainable exploration of groundwater resources within the investigated regions, relating to population movements and potential of aquifers. To achieve these objectives a) groundwater samples are collected and analyzed (microbiologically, chemically and physically) from all types of water points, boreholes and "protected" springs, during rainy, dry and intermediate seasons, b) a network of piezometers is being installed for monitoring groundwater level, and comparison with available rainfall data will define groundwater balance. During these steps results are compared with the population's displacement and density in order to quantify the consequences towards the groundwater resources. Preliminary results after microbiological analysis show the inadequacy of traditional "protected" springs in providing safe water. Feacal pollution is observed in "protected" springs even though it was not being observed before and during rehabilitation. It is mainly due to recent population concentration around the available water resources and the lack of comprehensive hydrogeological study of the functioning of the near surface aquifers. Accordingly all operations concerning spring rehabilitation are on hold. No evidence regarding microbiological contamination was found from borehole water samples. However, high concentration in ferrous iron and total iron was found in several boreholes. Concentrations in the water of weathered bedrock are expected and specific treatment is necessary.

Biological Characterization of Microenvironments in a Hypersaline Cold Spring Mars Analog

PubMed Central

Sapers, Haley M.; Ronholm, Jennifer; Raymond-Bouchard, Isabelle; Comrey, Raven; Osinski, Gordon R.; Whyte, Lyle G.

2017-01-01

While many habitable niches on Earth are characterized by permanently cold conditions, little is known about the spatial structure of seasonal communities and the importance of substrate-cell associations in terrestrial cyroenvironments. Here we use the 16S rRNA gene as a marker for genetic diversity to compare two visually distinct but spatially integrated surface microbial mats on Axel Heiberg Island, Canadian high arctic, proximal to a perennial saline spring. This is the first study to describe the bacterial diversity in microbial mats on Axel Heiberg Island. The hypersaline springs on Axel Heiberg represent a unique analog to putative subsurface aquifers on Mars. The Martian subsurface represents the longest-lived potentially habitable environment on Mars and a better understanding of the microbial communities on Earth that thrive in analog conditions will help direct future life detection missions. The microbial mats sampled on Axel Heiberg are only visible during the summer months in seasonal flood plains formed by melt water and run-off from the proximal spring. Targeted-amplicon sequencing revealed that not only does the bacterial composition of the two mat communities differ substantially from the sediment community of the proximal cold spring, but that the mat communities are distinct from any other microbial community in proximity to the Arctic springs studied to date. All samples are dominated by Gammaproteobacteria: Thiotichales is dominant within the spring samples while Alteromonadales comprises a significant component of the mat communities. The two mat samples differ in their Thiotichales:Alteromonadales ratio and contribution of Bacteroidetes to overall diversity. The red mats have a greater proportion of Alteromonadales and Bacteroidetes reads. The distinct bacterial composition of the mat bacterial communities suggests that the spring communities are not sourced from the surface, and that seasonal melt events create ephemerally habitable niches with distinct microbial communities in the Canadian high arctic. The finding that these surficial complex microbial communities exist in close proximity to perennial springs demonstrates the existence of a transiently habitable niche in an important Mars analog site. PMID:29312221

Biological Characterization of Microenvironments in a Hypersaline Cold Spring Mars Analog.

PubMed

Sapers, Haley M; Ronholm, Jennifer; Raymond-Bouchard, Isabelle; Comrey, Raven; Osinski, Gordon R; Whyte, Lyle G

2017-01-01

While many habitable niches on Earth are characterized by permanently cold conditions, little is known about the spatial structure of seasonal communities and the importance of substrate-cell associations in terrestrial cyroenvironments. Here we use the 16S rRNA gene as a marker for genetic diversity to compare two visually distinct but spatially integrated surface microbial mats on Axel Heiberg Island, Canadian high arctic, proximal to a perennial saline spring. This is the first study to describe the bacterial diversity in microbial mats on Axel Heiberg Island. The hypersaline springs on Axel Heiberg represent a unique analog to putative subsurface aquifers on Mars. The Martian subsurface represents the longest-lived potentially habitable environment on Mars and a better understanding of the microbial communities on Earth that thrive in analog conditions will help direct future life detection missions. The microbial mats sampled on Axel Heiberg are only visible during the summer months in seasonal flood plains formed by melt water and run-off from the proximal spring. Targeted-amplicon sequencing revealed that not only does the bacterial composition of the two mat communities differ substantially from the sediment community of the proximal cold spring, but that the mat communities are distinct from any other microbial community in proximity to the Arctic springs studied to date. All samples are dominated by Gammaproteobacteria: Thiotichales is dominant within the spring samples while Alteromonadales comprises a significant component of the mat communities. The two mat samples differ in their Thiotichales:Alteromonadales ratio and contribution of Bacteroidetes to overall diversity. The red mats have a greater proportion of Alteromonadales and Bacteroidetes reads. The distinct bacterial composition of the mat bacterial communities suggests that the spring communities are not sourced from the surface, and that seasonal melt events create ephemerally habitable niches with distinct microbial communities in the Canadian high arctic. The finding that these surficial complex microbial communities exist in close proximity to perennial springs demonstrates the existence of a transiently habitable niche in an important Mars analog site.

Rare earth element content of cryptocrystalline magnesites of Konya, Turkey

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zedef, Veysel, E-mail: vzedef@selcuk.edu.tr; Russell, Michael

We examined the rare earth element content of several cryptocrystalline magnesites as well as hydromagnesite, host rock serpentinites, lake water and hot spring water from Turkey. Southwestern Turkey hosts cryptocrystalline magnesites, sedimentary magnesites with presently forming, biologically mediated hydromagnesites and travertines. Our results show the REE content of the minerals, rocks and waters are well below detection limits. One hydromagnesite sample from Lake Salda has slightly high La (2.38ppb), Ce (3.91 ppb) and Nd (1.68 ppb) when compared to other samples, but these are also still below detection limits of the method we followed.

Stream water quality in the context of payments for environmental services in Southeastern Brazil

NASA Astrophysics Data System (ADS)

Piccolo, M. C.; Reis, L. D. C.; Figueiredo, R. D. O.; Camargo, P. B. D.; Costa, C. F. G. D.; Zuccari, M. L.; Green, T. R.

2015-12-01

Public policy of payment for environmental services (PES) was established in 2007 to face the challenge of recuperatingwater resources at one of the headwater areas of the Jaguari River Basin, which supplies an important reservoir for the metropolitan region of São Paulo, Brazil. Such effort consists of reforestation of riparian zones and spring lands at the hills of selected catchments, including the Ribeirão das Posses (RP) catchment. Since 2012 the University of São Paulo has developed research at RP to monitor the benefits of these practices on stream water quality, and identified a few parameters as good indicators to follow up the results of this PES program. The present study has the objective to show results of the monthly monitoring in2015,including 13 sampling stations at RP catchment distributed as follows: one in a spring forested area, three in spring areas of different ages of reforestation (3, 5 and 8 years), and nine at reaches of RP streamlocated in a way to contemplate the effects of the first order streams that comes from the studied spring areas entering RP. We established two additional stations at the Jaguari River, upstream and downstream of RP outlet. In situ measurements include temperature, pH, electric conductivity (EC) and dissolved oxygen (DO), and collect water samples to bring to the laboratory for analyses of dissolved organic and inorganic carbon (DOC and DIC), total nitrogen (TN) and alkalinity. Also, sediments (fine fraction: >0.45 μm; and coarse fraction: >63 μm) are collected for isotopic carbon analyses. Preliminary results show pH values ranging from 5.5 to 7.8, while DO ranges from 5.8 to 8.9 mg L-1. As for EC, the mean at the spring forested station was 34.6 μS cm-1, while at spring areas of 3, 6 and 8 years of reforestation they were 53.3, 73.8 and 34.8 μS cm-1, respectively. We expected that by the end of this annual monitoring the benefits of reforestation will be affirmed.

Annual ground-water discharge by evapotranspiration from areas of spring-fed riparian vegetation along the eastern margin of Death Valley, 2000-02

USGS Publications Warehouse

Laczniak, Randell J.; Smith, J. LaRue; DeMeo, Guy A.

2006-01-01

Flow from major springs and seeps along the eastern margin of Death Valley serves as the primary local water supply and sustains much of the unique habitat in Death Valley National Park. Together, these major spring complexes constitute the terminus of the Death Valley Regional Ground-Water Flow System--one of the larger flow systems in the Southwestern United States. The Grapevine Springs complex is the least exploited for water supply and consequently contains the largest area of undisturbed riparian habitat in the park. Because few estimates exist that quantify ground-water discharge from these spring complexes, a study was initiated to better estimate the amount of ground water being discharged annually from these sensitive, spring-fed riparian areas. Results of this study can be used to establish a basis for estimating water rights and as a baseline from which to assess any future changes in ground-water discharge in the park. Evapotranspiration (ET) is estimated volumetrically as the product of ET-unit (general vegetation type) acreage and a representative ET rate. ET-unit acreage is determined from high-resolution multi-spectral imagery; and a representative ET rate is computed from data collected in the Grapevine Springs area using the Bowen-ratio solution to the energy budget, or from rates given in other ET studies in the Death Valley area. The ground-water component of ET is computed by removing the local precipitation component from the ET rate. Two different procedures, a modified soil-adjusted vegetation index using the percent reflectance of the red and near-infrared wavelengths and land-cover classification using multi-spectral imagery were used to delineate the ET units within each major spring-discharge area. On the basis of the more accurate procedure that uses the vegetation index, ET-unit acreage for the Grapevine Springs discharge area totaled about 192 acres--of which 80 acres were moderate-density vegetation and 112 acres were high-density vegetation. ET-unit acreage for two other discharge areas delineated in the Grapevine Springs area (Surprise Springs and Staininger Spring) totaled about 6 and 43 acres, respectively; and for the discharge areas delineated in the Furnace Creek area (Nevares Springs, Cow Creek-Salt Springs, Texas Spring, and Travertine Springs) totaled about 29, 13, 11, and 21 acres, respectively. In discharge areas other than Grapevine Springs, watering and spring diversions have altered the natural distribution of the vegetation. More...

Microbes Characteristics in Groundwater Flow System in Mountainous Area

NASA Astrophysics Data System (ADS)

Yamamoto, Chisato; Tsujimura, Maki; Kato, Kenji; Sakakibara, Koichi; Ogawa, Mahiro; Sugiyama, Ayumi; Nagaosa, Kazuyo

2017-04-01

We focus on a possibility of microbes as a tracer for groundwater flow investigation. Some previous papers showed that the total number of prokaryotes in groundwater has correlation with depth and geology (Parkes et al., 1994; Griebler et al., 2009; Kato et al., 2012). However, there are few studies investigating both microbe characteristics and groundwater flow system. Therefore, we investigated a relationship between the total number of prokaryotes and age of spring water and groundwater. Intensive field survey was conducted at four mountainous areas, namely Mt. Fuji (volcano), a headwater at Mt. Setohachi, a headwater at River Oi and a headwater at River Nagano underlain by volcanic lava at Mt. Fuji, granite at Mt. Setohachi and sedimentary rock at River Oi and River Nagano. We collected totally 40 spring water/ groundwater samples in these mountainous areas in October 2015, August, October and November 2016 and analyzed concentration of inorganic ions, the stable isotopes of oxygen - 18, deuterium, CFCs and SF6. Also, we counted prokaryotic cells under the epifluorescence microscopy after fixation and filteration. The total number of prokaryotes in the spring water/ groundwater ranged from 1.0×102 to 7.0×103cells mL-1 at the Mt. Fuji, 1.3×104 to 2.7×105cells mL-1 at Mt. Setohachi, 3.1×104cells mL-1 at River Oi and 1.8×105 to 3.2×106cells mL-1 at River Nagano. The SF6 age of the spring water/ groundwater ranged from 8 to 64 years at Mt. Fuji, 2 to 32.5 years at Mt. Setohachi, 2.5 years at River Oi and 15 to 16 years at River Nagano. The total number of prokaryotes showed a clear negative correlation with residence time of spring water/ groundwater in all regions. Especially the prokaryotes number increased in the order of 102 cells mL-1 with decreasing of residence time in approximately 10 years in the groundwater and spring water with the age less than 15 years.

Methods to estimate annual mean spring discharge to the Snake River between Milner Dam and King Hill, Idaho

USGS Publications Warehouse

Kjelstrom, L.C.

1995-01-01

Many individual springs and groups of springs discharge water from volcanic rocks that form the north canyon wall of the Snake River between Milner Dam and King Hill. Previous estimates of annual mean discharge from these springs have been used to understand the hydrology of the eastern part of the Snake River Plain. Four methods that were used in previous studies or developed to estimate annual mean discharge since 1902 were (1) water-budget analysis of the Snake River; (2) correlation of water-budget estimates with discharge from 10 index springs; (3) determination of the combined discharge from individual springs or groups of springs by using annual discharge measurements of 8 springs, gaging-station records of 4 springs and 3 sites on the Malad River, and regression equations developed from 5 of the measured springs; and (4) a single regression equation that correlates gaging-station records of 2 springs with historical water-budget estimates. Comparisons made among the four methods of estimating annual mean spring discharges from 1951 to 1959 and 1963 to 1980 indicated that differences were about equivalent to a measurement error of 2 to 3 percent. The method that best demonstrates the response of annual mean spring discharge to changes in ground-water recharge and discharge is method 3, which combines the measurements and regression estimates of discharge from individual springs.

Physical characteristics and quality of water from selected springs and wells in the Lincoln Point-Bird Island area, Utah Lake, Utah

USGS Publications Warehouse

Baskin, R.L.; Spangler, L.E.; Holmes, W.F.

1994-01-01

From February 1991 to October 1992, the U.S. Geological Survey, in cooperation with the Central Utah Water Conservancy District, investigated the hydrology of the Lincoln Point - Bird Island area in the southeast part of Utah Lake, Utah. The investigation included measurements of the discharge of selected springs and measurements of the physical and chemical characteristics of water from selected springs and wells in the LincolnPoint - Bird Island area. This report contains data for twenty-one distinct springs in the study area including two springs beneath the surface of Utah Lake at Bird Island. Data from this study, combined with data from previous studies, indicate that the location of springs in the Lincoln Point - Bird Island area probably is controlled by fractures that are the result of faulting. Measured discharge of springs in the Lincoln Point - Bird Island area ranged from less than 0.01 cubic foot per second to 0.84 cubic foot per second. Total discharge in the study area, including known unmeasured springs and seeps, is estimated to be about 5 cubic feet per second. Reported and measured temperatures of water from springs and wells in the Lincoln Point - Bird Island area ranged from 16.0 degrees Celsius to 36.5 degrees Celsius. Dissolved-solids con-centrations ranged from 444 milligrams per liter to 7,932 milligrams per liter, and pH ranged from 6.3 to 8.1. Physical and chemical characteristics of spring and well water from the west side of Lincoln Point were virtually identical to the physical and chemical characteristics of water from the submerged Bird Island springs, indicating a similar source for the water. Water chemistry, isotope analyses, and geothermometer calculations indicate deep circulation of water discharging from the springs and indicate that the source of recharge for the springs at Lincoln Point and Bird Island does not appear to be localized in the LincolnPoint - Bird Island area.

PCBs in Rain Water, Streams and a Reservoir in a Small Catchment of NW Spain

NASA Astrophysics Data System (ADS)

Delgado-Martín, Jordi; Cereijo-Arango, José Luis; García-Morrondo, David; Juncosa-Rivera, Ricardo; Cillero-Castro, Carmen; Muñoz-Ibáñez, Andrea

2016-04-01

Polychlorinated biphenyls (PCBs) constitute a significant environmental concern due to its persistence, tendency to bio-accumulate, acknowledged toxicity and ubiquity. In the present study, a small water catchment (~100 km2) inclusive of a two-tailed water supply reservoir (Abegondo-Cecebre) has been monitored between 2009 and 2014. Sampling stations include: a) one precipitation gauge used to collect monthly-integrated bulk precipitation (25 samples); b) seven streams (95 samples); c) five surface and one bottom points within the reservoir (104 samples); d) five points for sediment sampling in two surveys (spring and summer; 10 samples). All the water samples as well as the leachates of sediment washing have been analyzed for their concentration in 6 marker PCB (congeners 28, 52, 101, 138, 153 and 180) and 12 dioxin-like PCB (congeners 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169 and 189) compounds. The average concentration of PCBtot in the bulk precipitation during the sampling period is ~406 pg/L although a very significant decrease has occurred since the end of 2011 (~800 pg/L) to the end of 2014 (~60 pg/L). Likewise, the mean concentration of PCBtot in the stream water samples is 174 pg/L and a similar reduction in the concentration of PCBtot is also acknowledged for the same period of time (~250 pg/L before the end of 2011 and ~30 pg/L after then). Reservoir surface water has a PCBtot concentration of ~234 pg/L which, according to its sampling time (2010-2011) is consistent with the measured stream waters. However, deep reservoir water reveals an average concentration which is higher than the corresponding top water (~330 pg/L) but significantly smaller than the water-leached sediments (~860 pg/L). The available data suggest that up to a 30% of PCBs associated with precipitation becomes sequestered by the soil/sediment system while no significant change takes place during the transfer of water from the stream to the reservoir system, at least in surface. However, deep reservoir water is enriched in PCBs what is likely due to exchange reactions with the already enriched reservoir sediments. Significant differences are also observed between the PCBtot concentrations of the sediment samples taken in spring (lower) and summer (higher) as well as in connection with the different organic carbon and metal content present in the two tails of the reservoir.

Groundwater, Surface-Water, and Water-Chemistry Data, Black Mesa Area, Northeastern Arizona - 2007-2008

USGS Publications Warehouse

Macy, Jamie P.

2009-01-01

The N aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use by a growing population and because of low precipitation in the arid climate of the Black Mesa area, which is typically about 6 to 14 inches per year. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from January 2007 to September 2008. The monitoring program includes measurements of (1) groundwater withdrawals, (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In 2007, total groundwater withdrawals were 4,270 acre-feet, industrial withdrawals were 1,170 acre-ft, and municipal withdrawals were 3,100 acre-ft. Total withdrawals during 2007 were about 41 percent less than total withdrawals in 2005. From 2006 to 2007, however, total withdrawals increased by 4 percent, industrial withdrawals decreased by approximately 2 percent, and total municipal withdrawals increased by 7 percent. From 2007 to 2008, annually measured water levels in the Black Mesa area declined in 6 of 11 wells measured in the unconfined areas of the N aquifer, and the median change was -0.2 feet. Water levels declined in 9 of 18 wells measured in the confined area of the aquifer. The median change for the confined area of the aquifer was -0.2 feet. From the prestress period (prior to 1965) to 2008, the median water-level change for 33 wells in both the confined and unconfined area was -12.9 feet. Median water-level changes were -1.0 feet for 15 wells measured in the unconfined areas and -33.2 feet for 18 wells measured in the confined area. Spring flow was measured at two springs in 2008. Flow decreased at both Moenkopi School Spring and Pasture Canyon Spring from previous years. Flow fluctuated during the period of record, but a decreasing trend was apparent. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2007), Dinnebito Wash near Sand Springs 09401110 (1993 to 2007), Polacca Wash near Second Mesa 09400568 (1994 to 2007), and Pasture Canyon Springs 09401265 (August 2004 to 2007). Median winter flows (November through February) of each water year were used as an index of the amount of groundwater discharge at the above-named sites. For the period of record of each streamflow-gaging station, the median winter flows have generally remained constant, which suggests no change in groundwater. The period of record is too short to determine if there is a trend at Pasture Canyon Spring. In 2008, water samples collected from 6 wells and 2 springs in the Black Mesa area were analyzed for selected chemical constituents and the results compared with previous analyses. Concentrations of dissolved solids, chloride, and sulfate have varied at all 6 wells for the period of record, but neither increasing nor decreasing trends over time were found. Dissolved-solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 12 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied much since the early 1980s, and there is no trend in those data.

Water clarity in the Florida Keys, USA, as observed from space (1984-2002)

NASA Astrophysics Data System (ADS)

Palandro, D. A.; Hu, C.; Andrefouet, S.; Muller-Karger, F. E.; Hallock, P.

2007-12-01

Landsat TM and ETM+ satellite data were used to derive the diffuse attenuation coefficient (Kd, m-1), a measure of water clarity, for 29 sites throughout the Florida Keys Reef Tract. A total of 28 individual Landsat images between 1984 and 2002 were used, with imagery gathered every two years for spring seasons and every six years for fall seasons. Useful information was obtained by Landsat bands 1 (blue) and 2 (green), except when sites were covered by clouds or showed turbid water. Landsat band 3 (red) provided no consistent data due to the high absorption of red light by water. Because image sampling represented only one or two samples per year on specific days, and because water turbidity may change over short time scales, it was not possible to assess temporal trends at the sites with the Landsat data. Kd values in band 1 were higher in the spring (mean spring = 0.034 m-1, mean fall = 0.031 m-1) and band 2 were higher in the fall (mean spring = 0.056 m-1, mean fall = 0.058 m-1), but the differences were not statistically significant. Spatial variability was high between sites and between regions (Upper, Middle and Lower Keys), with band 1 ranges of 0.019 m-1 - 0.060 m-1 and band 2 ranges of 0.036 m-1 - 0.076 m-1. The highest Kd values were found in the Upper Keys, followed by the Middle Keys and Lower Keys, respectively. This result must be taken in context however, two Middle Keys sites were found to be inconsistent due to high turbidity, obscuring the benthos and altering our assumption of a visible seafloor, which the algorithm is dependent upon. If all Middle Keys data were valid it is likely that this region would have the highest Kd values for both bands. The Landsat-derived Kd values, and inherent variability, may be influenced by the dominant water mass associated with each Florida Keys region, as well as localized oceanic variables. The methodology used here may be applied to other reef areas and used with satellites that offer higher temporal resolution to assess temporal change and variability.

Patterns in larval fish assemblages under the influence of the Brazil current

NASA Astrophysics Data System (ADS)

Katsuragawa, M.; Dias, J. F.; Harari, J.; Namiki, C.; Zani-Teixeira, M. L.

2014-10-01

The present work investigates the composition of larval fish assemblages in the area under the influence of the Brazil Current (BC) off the Southeastern Brazilian Bight. Ichthyoplankton was sampled during two oceanographic cruises (November-December/1997 - spring; May/2001 - autumn) with bongo nets oblique tows. Seasonal variation and a coastal-ocean pattern in the distribution of larval fish was observed and was influenced by the dynamics of the water masses, Coastal Water (CW), Tropical Water (TW) and South Atlantic Central Water (SACW), the last two of which were transported by the BC. During spring, the shelf assemblage was dominated by larvae of small pelagic fishes, such as Sardinella brasiliensis, Engraulis anchoita and Trachurus lathami, and was associated with the enrichment of shallow water by the SACW upwelling. In autumn, the abundance of coastal species larvae was reduced, and the shelf assemblage was dominated by Bregmaceros cantori. A transitional assemblage occurred during the spring, and comprised mesopelagic and coastal species. In both seasons, the oceanic assemblage was dominated by the mesopelagic families, Myctophidae, Sternopthychidae and Phosichthyidae. The oceanographic conditions also demonstrated clear differences between the northern and southern subareas, particularly in the shelf zone. This was especially the case during autumn when a latitudinal gradient in larval fish assemblages became more pronounced.

Geochemical and radionuclide profile of Tuzla geothermal field, Turkey.

PubMed

Baba, Alper; Deniz, Ozan; Ozcan, Hasan; Erees, Serap F; Cetiner, S Ziya

2008-10-01

Tuzla geothermal basin is situated in north-western Turkey on the Biga Peninsula, which is located at the west end of the Northern Anatolian Fault system. Soil and water samples were collected between August 2003 and June 2004 to initiate development of a geochemical profile of surface and subsurface waters in the geothermal basin and radionuclide concentrations in soils. All water samples were found to fall within Turkish Water Quality Class 4, meaning they were remarkably contaminated for any water consumption sector (industrial, human use or agricultural) based on sodium and chloride ions. Such waters could be used only after appropriate water treatment. The water samples are of the chloride type in terms of geochemical evaluation. Preliminary geochemical evidence shows that the N-S flowing part of the Tuzla River acts as a natural barrier within the basin. Heavy metal concentrations in the soil samples show slight elevations, especially those obtained from the east part of the basin where thermal springs are dominant. Geochemical calculations were carried out with PHREEQC software to determine equilibrium concentration of chemical species and saturation indices, by which it is suggested that chloride is the most important ligand to mobilize the heavy metals in the studied system. In addition, the activity concentration and gamma-absorbed dose rates of the terrestrial naturally occurring radionuclides were determined in the soil using gamma-ray spectrometry. The soil activity ranged from 42.77 to 988.66 Bq kg(-1) (averaging 138 Bq kg(-1)) for ( 238 )U, 13.27 to 106.31 Bq kg(-1) (averaging 32.42 Bq kg(-1)) for ( 232 )Th, and 99.28 to 935.36 Bq kg(-1) (averaging 515.44 Bq kg(-1)) for ( 40 )K. The highest value of ( 238 )U was found in the soil samples obtained from an area close to the hot spring.

Implications of ground water chemistry and flow patterns for earthquake studies.

PubMed

Guangcai, Wang; Zuochen, Zhang; Min, Wang; Cravotta, Charles A; Chenglong, Liu

2005-01-01

Ground water can facilitate earthquake development and respond physically and chemically to tectonism. Thus, an understanding of ground water circulation in seismically active regions is important for earthquake prediction. To investigate the roles of ground water in the development and prediction of earthquakes, geological and hydrogeological monitoring was conducted in a seismogenic area in the Yanhuai Basin, China. This study used isotopic and hydrogeochemical methods to characterize ground water samples from six hot springs and two cold springs. The hydrochemical data and associated geological and geophysical data were used to identify possible relations between ground water circulation and seismically active structural features. The data for delta18O, deltaD, tritium, and 14C indicate ground water from hot springs is of meteoric origin with subsurface residence times of 50 to 30,320 years. The reservoir temperature and circulation depths of the hot ground water are 57 degrees C to 160 degrees C and 1600 to 5000 m, respectively, as estimated by quartz and chalcedony geothermometers and the geothermal gradient. Various possible origins of noble gases dissolved in the ground water also were evaluated, indicating mantle and deep crust sources consistent with tectonically active segments. A hard intercalated stratum, where small to moderate earthquakes frequently originate, is present between a deep (10 to 20 km), high-electrical conductivity layer and the zone of active ground water circulation. The ground water anomalies are closely related to the structural peculiarity of each monitoring point. These results could have implications for ground water and seismic studies in other seismogenic areas.

Spatial distributions of floating seaweeds in the East China Sea from late winter to early spring.

PubMed

Mizuno, S; Ajisaka, T; Lahbib, S; Kokubu, Y; Alabsi, M N; Komatsu, T

2014-01-01

Floating seaweeds play an important role as a habitat for many animals accompanying or attaching to them in offshore waters. It was in 2000 that the first report described abundant distributions of floating seaweeds in offshore waters in the East China Sea in spring. Young individuals of the yellowtail Seriola quinqueradiata are captured for aquaculture purposes from floating seaweeds in the East China Sea. Therefore, a sound understanding of the distributions of floating seaweeds in the East China Sea is needed. Detailed information is especially important during the late winter to early spring, which corresponds to the juvenile period of the yellowtail. Thus, field surveys using R/V Tansei-Maru were conducted in the Japanese Exclusive Economic Zone in the East China Sea from late winter to early spring in 2010 and 2011. We obtained positions of the vessel by GPS and transversal distances from the vessel to a raft by visual observation. Distance sampling method (Thomas et al. 2010) was applied to estimation of floating seaweed densities (rafts km -2 ). Seaweed rafts were also randomly sampled using nets during the research cruises. In the East China Sea, seaweed rafts were distributed mainly on the continental shelf west of the Kuroshio, especially in waters between 26° N and 30° N. Collected rafts consisted of only one species, Sargassum horneri (Turner) C. Agardh. Taking into account surface currents and geographical distribution of S . horneri , it is estimated that these floating seaweeds originated from natural beds along the coast between mid and south China. Considering the approximate travel times, it is suggested that floating patches are colonized by yellowtails early on during their trips, i.e., close to the Chinese coast.

Indoor radon levels in selected hot spring hotels in Guangdong, China.

PubMed

Song, Gang; Zhang, Boyou; Wang, Xinming; Gong, Jingping; Chan, Daniel; Bernett, John; Lee, S C

2005-03-01

Guangdong is one of the provinces that have most hot springs in China, and many hotels have been set up near hot springs, with spring water introduced into the bath inside each hotel room for hot spring bathing to attract tourists. In the present study, we measured radon in indoor and outdoor air, as well as in hot spring waters, in four hot spring hotels in Guangdong by using NR-667A (III) continuous radon detector. Radon concentrations ranged 53.4-292.5 Bq L(-1) in the hot spring water and 17.2-190.9 Bq m(-3) in outdoor air. Soil gas intrusion, indoor hot spring water use and inefficient ventilation all contributed to the elevated indoor radon levels in the hotel rooms. From the variation of radon levels in closed unoccupied hotel rooms, soil gas intrusion was found to be a very important source of indoor radon in hotel rooms with floors in contact with soils. When there was spring water bathing in the bathes, average radon levels were 10.9-813% higher in the hotel rooms and 13.8-489% higher in bathes compared to their corresponding average levels when there was no spring water use. Spring water use in the hotel rooms had radon transfer coefficients from 1.6x10(-4) to 5.0x10(-3). Radon in some hotel rooms maintained in concentrations much higher than guideline levels might thus have potential health risks to the hotel workers, and technical and management measures should be taken to lower their exposure of radon through inhalation.

Geology, Streamflow, and Water Chemistry of the Talufofo Stream Basin, Saipan, Northern Mariana Islands

USGS Publications Warehouse

Izuka, Scot K.; Ewart, Charles J.

1995-01-01

A study of the geology, streamflow, and water chemistry of Talufofo Stream Basin, Saipan, Commonwealth of the Northern Mariana Islands, was undertaken to determine the flow characteristics of Talufofo Stream and the relation to the geology of the drainage basin. The Commonwealth government is exploring the feasibility of using water from Talufofo Stream to supplement Saipan's stressed municipal water supply. Streamflow records from gaging stations on the principal forks of Talufofo Stream indicate that peak streamflows and long-term average flow are higher at the South Fork gaging station than at the Middle Fork gaging station because the drainage area of the South Fork gaging station is larger, but persistent base flow from ground-water discharge during dry weather is greater in the Middle Fork gaging station. The sum of the average flows at the Middle Fork and South Fork gaging stations, plus an estimate of the average flow at a point in the lower reaches of the North Fork, is about 2.96 cubic feet per second or 1.91 million gallons per day. Although this average represents the theoretical maximum long-term draft rate possible from the Talufofo Stream Basin if an adequate reservoir can be built, the actual amount of surface water available will be less because of evaporation, leaks, induced infiltration, and reservoir-design constraints. Base-flow characteristics, such as stream seepage and spring discharge, are related to geology of the basin. Base flow in the Talufofo Stream Basin originates as discharge from springs near the base of limestones located in the headwaters of Talufofo Stream, flows over low-permeability volcanic rocks in the middle reaches, and seeps back into the high-permeability limestones in the lower reaches. Water sampled from Talufofo Stream during base flow had high dissolved-calcium concentrations (between 35 and 98 milligrams per liter), characteristic of water from a limestone aquifer. Concentrations of potassium, sodium, and chloride ions in water samples from Talufofo Stream are characteristic of water draining a heavily vegetated basin near the ocean. The streamflow and water-chemistry data indicate that discharge from springs is in hydraulic connection with the limestone aquifer near the headwaters of the basin. The base flow therefore is subject to stresses placed on the nearby limestone ground-water system. Pumping from wells in the limestones at the headwaters of Talufofo Stream Basin may decrease spring flow in Talufofo Stream.

Quality of surface water in the Suwannee River Basin, Florida, August 1968 through December 1977

USGS Publications Warehouse

Hull, Robert W.; Dysart, Joel E.; Mann, William B.

1981-01-01

In the 9,950-square mile area of the Suwannee River basin in Florida and Georgia, 17 surface-water stations on 9 streams and several springs were sampled for selected water-quality properties and constituents from August 1968 through December 1977. Analyses from these samples indicate that: (1) the water quality of tributary wetlands controls the water quality of the upper Suwannee River headwaters; (2) groundwater substantially affects the water quality of the Suwannee River basin streams below these headquarters; (3) the water quality of the Suwannee River, and many of its tributaries, is determined by several factors and is not simply related to discharge; and (4) development in the Suwannee River basin has had observable effects on the quality of surface waters. 

Are wetlands the reservoir for avian cholera?

USGS Publications Warehouse

Samuel, M.D.; Shadduck, D.J.; Goldberg, Diana R.

2004-01-01

Wetlands have long been suspected to be an important reservoir for Pasteurella multocida and therefore the likely source of avian cholera outbreaks. During the fall of 1995a??98 we collected sediment and water samples from 44 wetlands where avian cholera epizootics occurred the previous winter or spring. We attempted to isolate P. multocida in sediment and surface water samples from 10 locations distributed throughout each wetland. We were not able to isolate P. multocida from any of the 440 water and 440 sediment samples collected from these wetlands. In contrast, during other investigations of avian cholera we isolated P. multocida from 20 of 44 wetlands, including 7% of the water and 4.5% of the sediment samples collected during or shortly following epizootic events. Our results indicate that wetlands are an unlikely reservoir for the bacteria that causes avian cholera.