6. DETAIL OF UNITEDTOD TWINTANDEM STEAM ENGINE, SHOWING CRANK END ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. DETAIL OF UNITED-TOD TWIN-TANDEM STEAM ENGINE, SHOWING CRANK END OF LOW PRESSURE SIDE OF ENGINE. - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

33. Photocopy of photograph. STEEL PLANT, 1800HORSEPOWER CORLISS STEAM ENGINE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

33. Photocopy of photograph. STEEL PLANT, 1800-HORSEPOWER CORLISS STEAM ENGINE AND FLYWEEL FOR 22-INCH MILL, 1910. (From the Bethlehem Steel Corporation collection, Seattle, WA) - Irondale Iron & Steel Plant, Port Townsend, Jefferson County, WA

Pressurized chemical-looping combustion of coal with an iron ore-based oxygen carrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, Rui; Song, Min; Zhang, Shuai

2010-06-15

Chemical-looping combustion (CLC) is a new combustion technology with inherent separation of CO{sub 2}. Most of the previous investigations on CLC of solid fuels were conducted under atmospheric pressure. A pressurized CLC combined cycle (PCLC-CC) system is proposed as a promising coal combustion technology with potential higher system efficiency, higher fuel conversion, and lower cost for CO{sub 2} sequestration. In this study pressurized CLC of coal with Companhia Valedo Rio Doce (CVRD) iron ore was investigated in a laboratory fixed bed reactor. CVRD iron ore particles were exposed alternately to reduction by 0.4 g of Chinese Xuzhou bituminous coal gasifiedmore » with 87.2% steam/N{sub 2} mixture and oxidation with 5% O{sub 2} in N{sub 2} at 970 C. The operating pressure was varied between 0.1 MPa and 0.6 MPa. First, control experiments of steam coal gasification over quartz sand were performed. H{sub 2} and CO{sub 2} are the major components of the gasification products, and the operating pressure influences the gas composition. Higher concentrations of CO{sub 2} and lower fractions of CO, CH{sub 4}, and H{sub 2} during the reduction process with CVRD iron ore was achieved under higher pressures. The effects of pressure on the coal gasification rate in the presence of the oxygen carrier were different for pyrolysis and char gasification. The pressurized condition suppresses the initial coal pyrolysis process while it also enhances coal char gasification and reduction with iron ore in steam, and thus improves the overall reaction rate of CLC. The oxidation rates and variation of oxygen carrier conversion are higher at elevated pressures reflecting higher reduction level in the previous reduction period. Scanning electron microscope and energy-dispersive X-ray spectroscopy (SEM-EDX) analyses show that particles become porous after experiments but maintain structure and size after several cycles. Agglomeration was not observed in this study. An EDX analysis demonstrates that there is very little coal ash deposited on the oxygen carrier particles but no appreciable crystalline phases change as verified by X-ray diffraction (XRD) analysis. Overall, the limited pressurized CLC experiments carried out in the present work suggest that PCLC of coal is promising and further investigations are necessary. (author)« less

11. DETAIL OF UNITEDTOD TWINTANDEM STEAM ENGINE, SHOWING HIGHPRESSURE CYLINDER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. DETAIL OF UNITED-TOD TWIN-TANDEM STEAM ENGINE, SHOWING HIGH-PRESSURE CYLINDER AND VALVE, AND LUBRICATING EQUIPMENT FOR ENGINE. - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

17. Woodworking Mill (basement): view looking north showing Ames Iron ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

17. Woodworking Mill (basement): view looking north showing Ames Iron Works steam boiler; note turbine control handle in middle right of photo - Ben Thresher's Mill, State Aid No. 1, Barnet, Caledonia County, VT

10. DETAIL OF UNITEDTOD TWINTANDEM STEAM ENGINE, AS SEEN FROM ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. DETAIL OF UNITED-TOD TWIN-TANDEM STEAM ENGINE, AS SEEN FROM HIGH-PRESSURE SIDE OF ENGINE (SPARE CRANK WAS KEPT AT THIS END) - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

7. DETAIL OF UNITEDTOD TWINTANDEM STEAM ENGINE, SHOWING CYLINDER AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. DETAIL OF UNITED-TOD TWIN-TANDEM STEAM ENGINE, SHOWING CYLINDER AND CROSS HEAD OF PISTON AT THE LOW PRESSURE SIDE OF ENGINE. - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

8. DETAIL OF UNITEDTOD TWINTANDEM STEAM ENGINE, SHOWING CYLINDER AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. DETAIL OF UNITED-TOD TWIN-TANDEM STEAM ENGINE, SHOWING CYLINDER AND CROSS HEAD OF PISTON AT THE HIGH-PRESSURE SIDE OF ENGINE. - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

12. GENERAL VIEW OF UNITEDTOD TWINTANDEM STEAM ENGINE, AS SEEN ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. GENERAL VIEW OF UNITED-TOD TWIN-TANDEM STEAM ENGINE, AS SEEN FROM WALKWAY ALONG WALL, ON THE OTHER SIDE OF WHICH STOOD THE 40" BLOOMING MILL - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

74. View of small steam tank used in 'blowing down' ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

74. View of small steam tank used in 'blowing down' or cleaning boilers; in background can be seen the bottom of cylindrical water tank located in setback at southeast corner of blowing engine house. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

Non-Heme Iron Absorption and Utilization from Typical Whole Chinese Diets in Young Chinese Urban Men Measured by a Double-Labeled Stable Isotope Technique

PubMed Central

Yang, Lichen; Zhang, Yuhui; Wang, Jun; Huang, Zhengwu; Gou, Lingyan; Wang, Zhilin; Ren, Tongxiang; Piao, Jianhua; Yang, Xiaoguang

2016-01-01

Background This study was to observe the non-heme iron absorption and biological utilization from typical whole Chinese diets in young Chinese healthy urban men, and to observe if the iron absorption and utilization could be affected by the staple food patterns of Southern and Northern China. Materials and Methods Twenty-two young urban men aged 18–24 years were recruited and randomly assigned to two groups in which the staple food was rice and steamed buns, respectively. Each subject received 3 meals containing approximately 3.25 mg stable 57FeSO4 (the ratio of 57Fe content in breakfast, lunch and dinner was 1:2:2) daily for 2 consecutive days. In addition, approximately 2.4 mg 58FeSO4 was administered intravenously to each subject at 30–60 min after dinner each day. Blood samples were collected from each subject to measure the enrichment of the 57Fe and 58Fe. Fourteen days after the experimental diet, non-heme iron absorption was assessed by measuring 57Fe incorporation into red blood cells, and absorbed iron utilization was determined according to the red blood cell incorporation of intravenously infused 58Fe SO4. Results Non-heme iron intake values overall, and in the rice and steamed buns groups were 12.8 ±2.1, 11.3±1.3 and 14.3±1.5 mg, respectively; the mean 57Fe absorption rates were 11±7%, 13±7%, and 8±4%, respectively; and the mean infused 58Fe utilization rates were 85±8%, 84±6%, and 85±10%, respectively. There was no significantly difference in the iron intakes, and 57Fe absorption and infused 58Fe utilization rates between rice and steamed buns groups (all P>0.05). Conclusion We present the non-heme iron absorption and utilization rates from typical whole Chinese diets among young Chinese healthy urban men, which was not affected by the representative staple food patterns of Southern and Northern China. This study will provide a basis for the setting of Chinese iron DRIs. PMID:27099954

Effect of steam during Fischer–Tropsch Synthesis using biomass-derived syngas

Treesearch

Zi Wang; Khiet Mai; Nitin Kumar; Thomas Elder; Leslie H. Groom; James J. Spivey

2017-01-01

Fischer–Tropsch synthesis (FTS) with biomass- derived syngas was performed using both iron-based 100Fe/6Cu/4K/25Al catalyst and ruthenium-based 5 % Ru/SiO2 catalyst. During FTS, different concentrations of steam were co-fed with the biomass-derived syngas to promote the water gas shift reaction and increase the H2/ CO ratio...

9. RW Meyer Sugar Mill: 18761889. Locomotivetype, firetube, portable boiler, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. RW Meyer Sugar Mill: 1876-1889. Locomotive-type, fire-tube, portable boiler, No. 1 model. Manufactured by Ames Iron Works, Oswego, New York, 1879. 120 lbs/sq. inch working pressure, 66 sq. ft. heating surface in tubes. View: from side. The boiler provided steam for steam engine which in turn powered the mill's centrifugals. The section on the left side included the firebox with its surrounding water-legs. The fluted chimney-type structure is the steam port, safety valve, and whistle. Column projecting from side was part of steam pressure and water gauge. Pipe running above boiler carried steam to the engine. Pipe running below boiler provided the boiler feed-water. Cylindrical section included 22 fire-tube surrounded by water. The far right ... - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

Water chemistry of the secondary circuit at a nuclear power station with a VVER power reactor

NASA Astrophysics Data System (ADS)

Tyapkov, V. F.; Erpyleva, S. F.

2017-05-01

Results of implementation of the secondary circuit organic amine water chemistry at Russian nuclear power plant (NPP) with VVER-1000 reactors are presented. The requirements for improving the reliability, safety, and efficiency of NPPs and for prolonging the service life of main equipment items necessitate the implementation of new technologies, such as new water chemistries. Data are analyzed on the chemical control of power unit coolant for quality after the changeover to operation with the feed of higher amines, such as morpholine and ethanolamine. Power units having equipment containing copper alloy components were converted from the all-volatile water chemistry to the ethanolamine or morpholine water chemistry with no increase in pH of the steam generator feedwater. This enables the iron content in the steam generator feedwater to be decreased from 6-12 to 2.0-2.5 μg/dm3. It is demonstrated that pH of high-temperature water is among the basic factors controlling erosion and corrosion wear of the piping and the ingress of corrosion products into NPP steam generators. For NPP power units having equipment whose construction material does not include copper alloys, the water chemistries with elevated pH of the secondary coolant are adopted. Stable dosing of correction chemicals at these power units maintains pH25 of 9.5 to 9.7 in the steam generator feedwater with a maximum iron content of 2 μg/dm3 in the steam generator feedwater.

Continuous Steelmaking Directly from Ore

NASA Astrophysics Data System (ADS)

Warner, Noel A.

2014-12-01

In-line continuous processing of high-grade hematite ore (crushed ore or fines) with a pure hydrogen reductant is assessed. An appraisal is made of the rate controlling mechanisms involved in the reduction of a pure layer of molten wustite being transported by floating on a molten carrier iron carbon-free medium at temperatures just in excess of the iron melting point. Published research clearly indicates that under these conditions the kinetics are principally controlled by molecular gaseous diffusion. Thus, the rate is essentially not influenced by total gas pressure above 1 atmosphere. Accordingly, on safety grounds it is recommended that high pressure should not be used for hydrogen steelmaking in the future, but the operation should be conducted close to atmospheric pressure with low pressure steam encapsulation of the plant items involved. Using hydrogen as the reductant means that sub-surface nucleation of CO bubbles cannot disrupt continuous processing. The operation is then no different to processing a normal liquid phase. The off-gases from the reduction zone of a melt circulation loop are super-clean and only contaminated with iron vapor. Accordingly, the best available technology becomes available for energy conservation without risk of non-fusible solids deposition. The net result is that the energy requirements are expected to be superior to other potential processes.

Carbon capture by sorption-enhanced water-gas shift reaction process using hydrotalcite-based material

DOE Office of Scientific and Technical Information (OSTI.GOV)

van Selow, E.R.; Cobden, P.D.; Verbraeken, P.A.

2009-05-15

A novel route for precombustion decarbonization is the sorption-enhanced water-gas shift (SEWGS) process. In this process carbon dioxide is removed from a synthesis gas at elevated temperature by adsorption. Simultaneously, carbon monoxide is converted to carbon dioxide by the water-gas shift reaction. The periodic adsorption and desorption of carbon dioxide is induced by a pressure swing cycle, and the cyclic capacity can be amplified by purging with steam. From previous studies is it known that for SEWGS applications, hydrotalcite-based materials are particularly attractive as sorbent, and commercial high-temperature shift catalysts can be used for the conversion of carbon monoxide. Tabletsmore » of a potassium promoted hydrotalcite-based material are characterized in both breakthrough and cyclic experiments in a 2 m tall fixed-bed reactor. When exposed to a mixture of carbon dioxide, steam, and nitrogen at 400{sup o}C, the material shows a breakthrough capacity of 1.4 mmol/g. In subsequent experiments the material was mixed with tablets of promoted iron-chromium shift catalyst and exposed to a mixture of carbon dioxide, carbon monoxide, steam, hydrogen, and nitrogen. It is demonstrated that carbon monoxide conversion can be enhanced to 100% in the presence of a carbon dioxide sorbent. At breakthrough, carbon monoxide and carbon dioxide simultaneously appear at the end of the bed. During more than 300 cycles of adsorption/reaction and desorption, the capture rate, and carbon monoxide conversion are confirmed to be stable. Two different cycle types are investigated: one cycle with a CO{sub 2} rinse step and one cycle with a steam rinse step. The performance of both SEWGS cycles are discussed.« less

Performance of iron-chromium-aluminum alloy surface coatings on Zircaloy 2 under high-temperature steam and normal BWR operating conditions

NASA Astrophysics Data System (ADS)

Zhong, Weicheng; Mouche, Peter A.; Han, Xiaochun; Heuser, Brent J.; Mandapaka, Kiran K.; Was, Gary S.

2016-03-01

Iron-chromium-aluminum (FeCrAl) coatings deposited on Zircaloy 2 (Zy2) and yttria-stabilized zirconia (YSZ) by magnetron sputtering have been tested with respect to oxidation weight gain in high-temperature steam. In addition, autoclave testing of FeCrAl-coated Zy2 coupons under pressure-temperature-dissolved oxygen coolant conditions representative of a boiling water reactor (BWR) environment has been performed. Four different FeCrAl compositions have been tested in 700 °C steam; compositions that promote alumina formation inhibited oxidation of the underlying Zy2. Parabolic growth kinetics of alumina on FeCrAl-coated Zy2 is quantified via elemental depth profiling. Autoclave testing under normal BWR operating conditions (288 °C, 9.5 MPa with normal water chemistry) up to 20 days demonstrates observable weight gain over uncoated Zy2 simultaneously exposed to the same environment. However, no FeCrAl film degradation was observed. The 900 °C eutectic in binary Fe-Zr is addressed with the FeCrAl-YSZ system.

Constraints on silicates formation in the Si-Al-Fe system: Application to hard deposits in steam generators of PWR nuclear reactors

NASA Astrophysics Data System (ADS)

Berger, Gilles; Million-Picallion, Lisa; Lefevre, Grégory; Delaunay, Sophie

2015-04-01

Introduction: The hydrothermal crystallization of silicates phases in the Si-Al-Fe system may lead to industrial constraints that can be encountered in the nuclear industry in at least two contexts: the geological repository for nuclear wastes and the formation of hard sludges in the steam generator of the PWR nuclear plants. In the first situation, the chemical reactions between the Fe-canister and the surrounding clays have been extensively studied in laboratory [1-7] and pilot experiments [8]. These studies demonstrated that the high reactivity of metallic iron leads to the formation of Fe-silicates, berthierine like, in a wide range of temperature. By contrast, the formation of deposits in the steam generators of PWR plants, called hard sludges, is a newer and less studied issue which can affect the reactor performance. Experiments: We present here a preliminary set of experiments reproducing the formation of hard sludges under conditions representative of the steam generator of PWR power plant: 275°C, diluted solutions maintained at low potential by hydrazine addition and at alkaline pH by low concentrations of amines and ammoniac. Magnetite, a corrosion by-product of the secondary circuit, is the source of iron while aqueous Si and Al, the major impurities in this system, are supplied either as trace elements in the circulating solution or by addition of amorphous silica and alumina when considering confined zones. The fluid chemistry is monitored by sampling aliquots of the solution. Eh and pH are continuously measured by hydrothermal Cormet© electrodes implanted in a titanium hydrothermal reactor. The transformation, or not, of the solid fraction was examined post-mortem. These experiments evidenced the role of Al colloids as precursor of cements composed of kaolinite and boehmite, and the passivation of amorphous silica (becoming unreactive) likely by sorption of aqueous iron. But no Fe-bearing was formed by contrast to many published studies on the Fe-clay interactions in the nuclear waste storage, and by contrast with basic thermodynamic predictions. Conclusion: The Fe-clays and steam generators contexts imply relatively close aqueous environments: hydrothermal, reduced, diluted, neutral to slightly alkaline. The main difference is the status of iron: ferric/ferrous (magnetite) in the steam generators, metallic in the Fe-clay experiments. The concentration of aqueous iron when supplied by magnetite is low and does not allow its incorporation in secondary phases. By contrast, aqueous ferrous iron released by the corrosion of steel is not limited by the source, rather by the sink, and produces Fe-rich silicates. This example illustrates the discrepancy between complex mineral reactions and oversimplified predictions when sorption/passivation and nucleation/growth constraints are ignored. Reference: [1] Lanson et al. (2012) Amer. Min. 97, 864-871. [2] Lantenois et al. (2005) Clays & Clay Min. 53, 597-612. [3] Mosser-Ruck et al. (2010) Clays & Clay Min. 58, 280-291. [4] Perronnet et al. (2008) App. Clay Sci. 38, 187-202. [5] Osacky et al. (2010) App. Clay Sci. 50, 237-244. [6] Guillaume et al. (2003) Clay Min. 38, 281-302. [7] Rivard et al. (2013) Amer. Mineral. 98, 163-180. [8] Svensson and Hansen (2013) Clays & Clay Min. 61, 566-579.

21. RW Meyer Sugar Mill: 18761889. Simple, singlecylinder, horizontal, reciprocating ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

21. RW Meyer Sugar Mill: 1876-1889. Simple, single-cylinder, horizontal, reciprocating steam engine, model no. 1, 5' x 10', 6 hp, 175 rpm. Manufactured by Ames Iron Works, Oswego, New York, 1879. View: Steam engine powered the mill's centrifugals. Steam-feed pipe at top left of engine. Steam exhaust pipe leaves base of engine on right end and projects upwards. The boiler feed and supply pipe running water through the engine's pre-heat system are seen running to the lower left end of the engine. Pulley in the foreground was not used. The centrifugals were powered by a belt running from the flywheel in the background. Ball-type governor and pulley are on left end of the engine. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

Preliminary Screening - Technical and Economic Assessment of Synthesis Gas to Fuels and Chemicals With Emphasis on the Potential for Biomass-Derived Syngas

DTIC Science & Technology

2003-12-01

hydrogen from syngas produced from steam methane reforming was commercialized. Haber and Bosch discovered the synthesis of ammonia from H2 and N2 in...reforming, in the catalytic process developed in the early 1900s by Fritz Haber and Carl Bosch using a promoted iron catalyst discovered by Alwin Mittasch...Derived Syngas December 2003 • NREL/TP-510-34929 P.L. Spath and D.C. Dayton National Renewable Energy Laboratory 1617 Cole Boulevard

8. RW Meyer Sugar Mill: 18761889. Simple, singlecylinder, horizontal, reciprocating ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. RW Meyer Sugar Mill: 1876-1889. Simple, single-cylinder, horizontal, reciprocating steam engine, model No. 1, 5' x 10', 6 hp, 175 rpm. Manufactured by Ames Iron Works, Oswego, New York, 1879. View: Steam engine powered the mill's centrifugals. It received steam from the locomotive type, fire-tube portable boiler in the background. The engine's water pump which pumped water from the feed-water clarifying cistern, in between the boiler and engine, through a pre-heat system and on to the boiler, is seen in front of the fluted cylinder. The fly-ball governor, missing its balls, the steam port, and manual throttle valve are above and behind the cylinder. The flywheel, drive shaft, and pulley are on the left side of the engine bed. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

Economical and Energy Efficiency of Iron and Steel Industry Reindustrialisation in Russia Based on Implementation of Breakthrough Energy-Saving Technologies

NASA Astrophysics Data System (ADS)

Shevelev, L. N.

2017-12-01

Estimates were given of economical and energy efficiency of breakthrough energy-saving technologies, which increase competitive advantages and provide energy efficiency of production while reducing negative impact on the environment through reduction of emissions of harmful substances and greenhouse gases in the atmosphere. Among these technologies, preference is given to the following: pulverized coal fuel, blast-furnace gas recycling, gasification of non-coking coal in bubble-type gas-generators, iron-ore concentrate briquetting with steam coal with further use of ore-coal briquettes in electric furnace steel making. Implementation of these technologies at iron and steel works will significantly reduce the energy intensity of production through reduction of expensive coking coal consumption by means of their substitution by less expensive non-coking (steam) coal, and natural gas substitution by own secondary energy resource, which is the reducing gas. As the result, plants will get an opportunity to become self-sufficient in energy-resources and free themselves entirely from expensive purchased energy resources (natural gas, electric power, and partially coking coals), and cross over to low-carbon development.

Estimation and Optimization of the Parameters Preserving the Lustre of the Fabrics

NASA Astrophysics Data System (ADS)

Prodanova, Krasimira

2009-11-01

The paper discusses the optimization of the continuance of the Damp-Heating Process of a steaming iron press machine, and the preserving of the lustre of the fabrics. In order to be obtained high qualitative damp-heating processing, it is necessary to monitor parameters such as temperature, damp, and pressure during the process. The purpose of the present paper is a mathematical model to be constructed that adequately describes the technological process using multivariate data analysis. It was established that the full factorial design of type 23 is not adequate. The research has proceeded with central rotatable design of experiment. The obtained model adequately describes the technological process of damp-heating treatment in the defined factor space. The present investigation is helpful to the technological improvement and modernization in sewing companies.

10. RW Meyer Sugar Mill: 18761889. Simple, singlecylinder, horizontal, reciprocating ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. RW Meyer Sugar Mill: 1876-1889. Simple, single-cylinder, horizontal, reciprocating steam engine, model No. 1, 5' x 10', 6 hp, 175 rpm. Manufactured by Ames Iron Works, Oswego, New York, 1879. View: Steam engine powered the mill's centrifugals. To the left of the horizontal (fluted) cylinder is the water pump which moved the boiler feed water through the engine's pre-heat system (the exhaust steam heated the boiler feedwater before it was pumped on to the boiler). The steam-feed port, manual throttle valve, and fly-ball governor and pulley and to the right of the cylinder. The drive shaft with flywheel to the left and pulley to the right are seen behind the piston rod, cross-head, wrist pen, connecting rod and the slide valve and eccentric. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

7. RW Meyer Sugar Mill: 18761889. Engine and boiler house; ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. RW Meyer Sugar Mill: 1876-1889. Engine and boiler house; ca. 1881. Simple, single-cylinder, horizontal, reciprocating steam engine, model No. 1, 5' x 10', 6 hp, 175 rpm. Manufactured by Ames Iron Works, Oswego, New York, 1879. View: Historical view, 1934, from T. T. Waterman collection, Hawaiian Sugar Planters' Association. View shows interior of engine and boiler house intact. The steam-feed pipe is still attached to throttle valve, not the case in 1978 view. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

Hydrolysis of ferric chloride in solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lussiez, G.; Beckstead, L.

1996-11-01

The Detox{trademark} process uses concentrated ferric chloride and small amounts of catalysts to oxidize organic compounds. It is under consideration for oxidizing transuranic organic wastes. Although the solution is reused extensively, at some point it will reach the acceptable limit of radioactivity or maximum solubility of the radioisotopes. This solution could be cemented, but the volume would be increased substantially because of the poor compatibility of chlorides and cement. A process has been developed that recovers the chloride ions as HCl and either minimizes the volume of radioactive waste or permits recycling of the radioactive chlorides. The process involves amore » two-step hydrolysis at atmospheric pressure, or preferably under a slight vacuum, and relatively low temperature, about 200{degrees}C. During the first step of the process, hydrolysis occurs according to the reaction below: FeCl{sub 3 liquid} + H{sub 2}O {r_arrow} FeOCl{sub solid} + 2 HCl{sub gas} During the second step, the hot, solid, iron oxychloride is sprayed with water or placed in contact with steam, and hydrolysis proceeds to the iron oxide according to the following reaction: 2 FeOCl{sub solid} + H{sub 2}O {r_arrow} Fe{sub 2}O{sub 3 solid} + 2 HCl{sub gas}. The iron oxide, which contains radioisotopes, can then be disposed of by cementation or encapsulation. Alternately, these chlorides can be washed off of the solids and can then either be recycled or disposed of in some other way.« less

Recent Developments in Superheated Steam Processing of Foods-A Review.

PubMed

Alfy, Anto; Kiran, B V; Jeevitha, G C; Hebbar, H Umesh

2016-10-02

Although the use of superheated steam has been known for quite a long time, only in the recent past has it emerged as a viable technology for food processing. Superheated steam, having higher enthalpy, can quickly transfer heat to the material being processed, resulting in its rapid heating. The major advantages of using superheated steam for food processing are better product quality (color, shrinkage, and rehydration characteristics), reduced oxidation losses, and higher energy efficiency. This review provides a comprehensive overview of recent studies on the application of superheated steam for food-processing operations such as drying, decontamination and microbial load reduction, parboiling, and enzyme inactivation. The review encompasses aspects such as the effect of superheated steam processing on product quality, mathematical models reported for superheated steam drying, and the future scope of application in food processing. Recent studies on process improvisation, wherein superheated steam is used at low pressure, in fluidized bed mode, sequential processing with hot air/infrared, and in combination with micro droplets of water have also been discussed.

40 CFR 408.270 - Applicability; description of the steamed and canned oyster processing subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... steamed and canned oyster processing subcategory. 408.270 Section 408.270 Protection of Environment... PROCESSING POINT SOURCE CATEGORY Steamed and Canned Oyster Processing Subcategory § 408.270 Applicability; description of the steamed and canned oyster processing subcategory. The provisions of this subpart are...

Evaluation of on-line chelant addition to PWR steam generators. Steam generator cleaning project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tvedt, T.J.; Wallace, S.L.; Griffin, F. Jr.

1983-09-01

The investigation of chelating agents for continuous water treatment of secondary loops of PWR steam generators were conducted in two general areas: the study of the chemistry of chelating agents and the study of materials compatability with chelating agents. The thermostability of both EDTA and HEDTA metal chelates in All Volatile Treatment (AVT) water chemistry were shown to be greater than or equal to the thermostability of EDTA metal chelates in phosphate-sulfite water chemistry. HEDTA metal chelates were shown to have a much greater stability than EDTA metal chelates. Using samples taken from the EDTA metal chelate thermostability study andmore » from the Commonwealth Research Corporation (CRC) model steam generators (MSG), EDTA decomposition products were determined. Active metal surfaces were shown to become passivated when exposed to EDTA and HEDTA concentrations as high as 0.1% w/w in AVT. Trace amounts of iron in the water were found to increase the rate of passivation. Material balance and visual inspection data from CRC model steam generators showed that metal was transported through and cleaned from the MSG's. The Inconel 600 tubes of the salt water fouled model steam generators experienced pitting corrosion. Results of this study demonstrates the feasibility of EDTA as an on-line water treatment additive to maintain nuclear steam generators in a clean condition.« less

Determining the effect of different cooking methods on the nutritional composition of salmon (Salmo salar) and chilean jack mackerel (Trachurus murphyi) fillets.

PubMed

Bastías, José M; Balladares, Pamela; Acuña, Sergio; Quevedo, Roberto; Muñoz, Ociel

2017-01-01

The effect of four cooking methods was evaluated for proximate composition, fatty acid, calcium, iron, and zinc content in salmon and Chilean jack mackerel. The moisture content of steamed salmon decreased (64.94%) compared to the control (68.05%); a significant decrease was observed in Chilean jack mackerel in all the treatments when compared to the control (75.37%). Protein content in both salmon and Chilean jack mackerel significantly increased under the different treatments while the most significant decrease in lipids was found in oven cooking and canning for salmon and microwaving for Chilean jack mackerel. Ash concentration in both salmon and Chilean jack mackerel did not reveal any significant differences. Iron and calcium content only had significant changes in steaming while zinc did not undergo any significant changes in the different treatments. Finally, no drastic changes were observed in the fatty acid profile in both salmon and Chilean jack mackerel.

Determining the effect of different cooking methods on the nutritional composition of salmon (Salmo salar) and chilean jack mackerel (Trachurus murphyi) fillets

PubMed Central

Balladares, Pamela; Acuña, Sergio; Quevedo, Roberto; Muñoz, Ociel

2017-01-01

The effect of four cooking methods was evaluated for proximate composition, fatty acid, calcium, iron, and zinc content in salmon and Chilean jack mackerel. The moisture content of steamed salmon decreased (64.94%) compared to the control (68.05%); a significant decrease was observed in Chilean jack mackerel in all the treatments when compared to the control (75.37%). Protein content in both salmon and Chilean jack mackerel significantly increased under the different treatments while the most significant decrease in lipids was found in oven cooking and canning for salmon and microwaving for Chilean jack mackerel. Ash concentration in both salmon and Chilean jack mackerel did not reveal any significant differences. Iron and calcium content only had significant changes in steaming while zinc did not undergo any significant changes in the different treatments. Finally, no drastic changes were observed in the fatty acid profile in both salmon and Chilean jack mackerel. PMID:28686742

Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siriwardane, Ranjani; Benincosa, William; Riley, Jarrett

This paper presents data on conversion of two different coals with a chemical looping oxygen carrier, CuO-Fe 2O 3-alumina, and over a range of conditions including steam and various levels of reduction of the oxygen carrier. Reactions of coal/steam/CuO-Fe 2O 3-alumina oxygen carrier and coal/steam/partially reduced CuO-Fe 2O 3-alumina oxygen carrier were investigated with Wyodak coal and Illinois #6 coal in a fluidized bed reactor. Temperature programmed reaction studies indicated that the oxygen carrier enhanced the steam gasification/combustion rates of both coals. Rates of gasification/combustion were higher with Wyodak coal (sub bituminous) than that with Illinois #6 coal (bituminous). Inmore » addition to the increase in reaction rates, the total moles of carbon that were gasified and combusted from coal/steam increased in the presence of the oxygen carrier. The reduced oxygen carrier promoted the water-gas shift reaction when reacted with synthesis gas in the presence of steam, but the reverse water gas shift reaction was observed when steam was not present. The partially reduced oxygen carrier enhanced the production of H 2 from coal/steam, which was different from the observations with un-reduced oxygen carrier. Water splitting reaction to produce H 2 was also observed with the reduced oxygen carrier. CuO-Fe 2O 3-alumina reacted with coal during the temperature ramp to 850 °C even in the absence of steam due to the chemical-looping oxygen uncoupling (CLOU) reaction. Here, the fourier transform infra-red (FTIR) analysis indicated the presence of volatile aromatics during the temperature ramp and these may have also contributed to the reactions with the oxygen carrier in the absence of steam. Increasing steam concentration had a negative effect on the CLOU reaction.« less

Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier

DOE PAGES

Siriwardane, Ranjani; Benincosa, William; Riley, Jarrett; ...

2016-10-06

This paper presents data on conversion of two different coals with a chemical looping oxygen carrier, CuO-Fe 2O 3-alumina, and over a range of conditions including steam and various levels of reduction of the oxygen carrier. Reactions of coal/steam/CuO-Fe 2O 3-alumina oxygen carrier and coal/steam/partially reduced CuO-Fe 2O 3-alumina oxygen carrier were investigated with Wyodak coal and Illinois #6 coal in a fluidized bed reactor. Temperature programmed reaction studies indicated that the oxygen carrier enhanced the steam gasification/combustion rates of both coals. Rates of gasification/combustion were higher with Wyodak coal (sub bituminous) than that with Illinois #6 coal (bituminous). Inmore » addition to the increase in reaction rates, the total moles of carbon that were gasified and combusted from coal/steam increased in the presence of the oxygen carrier. The reduced oxygen carrier promoted the water-gas shift reaction when reacted with synthesis gas in the presence of steam, but the reverse water gas shift reaction was observed when steam was not present. The partially reduced oxygen carrier enhanced the production of H 2 from coal/steam, which was different from the observations with un-reduced oxygen carrier. Water splitting reaction to produce H 2 was also observed with the reduced oxygen carrier. CuO-Fe 2O 3-alumina reacted with coal during the temperature ramp to 850 °C even in the absence of steam due to the chemical-looping oxygen uncoupling (CLOU) reaction. Here, the fourier transform infra-red (FTIR) analysis indicated the presence of volatile aromatics during the temperature ramp and these may have also contributed to the reactions with the oxygen carrier in the absence of steam. Increasing steam concentration had a negative effect on the CLOU reaction.« less

11. RW Meyer Sugar Mill: 18761889. Locomotive=type, firetube, portable boiler, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. RW Meyer Sugar Mill: 1876-1889. Locomotive=type, fire-tube, portable boiler, model No. 1, Manufactured by Ames Iron Works, Oswego, New York, 1879. 120 lbs./sq. in. working pressure, 66 sq. ft. heating surface in tubes. View: the boiler provided steam for steam engine which in turn powered the centrifugals. View shows front fire box, end of boiler. Below fire-box,used for removing ashes, is a door. Circular openings at the rear of the fire-box are where fire-tubes connected with furnace. Column to right of fire-box carried pressure and water level gauges. Fluted chimney-type structure is steam-port, safety valve, and whistle. Weights originally sat on the arm extending from the top of the port and controlled the boiler pressure. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

Regenerability of hydrotalcite-derived nickel-iron alloy nanoparticles for syngas production from biomass tar.

PubMed

Li, Dalin; Koike, Mitsuru; Wang, Lei; Nakagawa, Yoshinao; Xu, Ya; Tomishige, Keiichi

2014-02-01

Nickel-iron/magnesium/aluminum bimetallic catalysts were prepared by the calcination and reduction of nickel-magnesium-iron-aluminum hydrotalcite-like compounds. Characterization suggests that, at iron/nickel≤0.5, both nickel and iron species are homogeneously distributed in the hydrotalcite precursor and incorporated into the Mg(Ni, Fe, Al)O periclase after calcination, giving rise to uniform nickel-iron alloy nanoparticles after reduction. Ni-Fe/Mg/Al (Fe/Ni=0.25) exhibits the best catalytic performance for the steam reforming of tar derived from the pyrolysis of biomass. It is suggested that the uniform nickel-iron alloy nanoparticles and the synergy between nickel and iron are responsible for the high catalytic performance. Moreover, the Ni-Fe/Mg/Al catalyst exhibits much better regenerability toward oxidation-reduction treatment for the removal of deposited coke than that of conventional Ni-Fe/α-Al2 O3 . This property can be attributed to the better regeneration of Ni-Fe alloy nanoparticles through the formation and reduction of Mg(Ni, Fe, Al)O. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Types and analysis of defects in welding junctions of the header to steam generator shells on power-generating units with VVER-1000

NASA Astrophysics Data System (ADS)

Ozhigov, L. S.; Voevodin, V. N.; Mitrofanov, A. S.; Vasilenko, R. L.

2016-10-01

Investigation objects were metal templates, which were cut during the repair of welding junction no. 111 (header to the steam generator shell) on a power-generating unit with VVER-1000 of the South-Ukraine NPP, and substances of mud depositions collected from walls of this junction. Investigations were carried out using metallography, optical microscopy, and scanning electron microscopy with energy dispersion microanalysis by an MMO-1600-AT metallurgical microscope and a JEOL JSM-7001F scanning electron microscope with the Shottky cathode. As a result of investigations in corrosion pits and mud depositions in the area of welding junction no. 111, iron and copper-enriched particles were revealed. It is shown that, when contacting with the steel header surface, these particles can form microgalvanic cells causing reactions of iron dissolution and the pit corrosion of metal. Nearby corrosion pits in metal are microcracks, which can be effect of the stress state of metal under corrosion pits along with revealed effects of twinning. The hypothesis is expressed that pitting corrosion of metal occurred during the first operation period of the power-generating unit in the ammonia water chemistry conditions (WCC). The formation of corrosion pits and nucleating cracks from them was stopped with the further operation under morpholine WCC. The absence of macrocracks in metal of templates verifies that, during operation, welding junction no. 111 operated under load conditions not exceeding the permissible ones by design requirements. The durability of the welding junction of the header to the steam generator shell significantly depends on the technological schedule of chemical cleaning and steam generator shut-down cooling.

54. View from southeast of KinneyOsborne slag granulator at right ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

54. View from southeast of Kinney-Osborne slag granulator at right and stack at left that vented steam generated when water was sprayed on hot slag to solidify and fracture it. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

4. INTERIOR OF ENGINE ROOM, CONTAINING UNITEDTOD TWINTANDEM ENGINE, FOR ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. INTERIOR OF ENGINE ROOM, CONTAINING UNITED-TOD TWIN-TANDEM ENGINE, FOR 40" BLOOMING MILL; AS SEEN FROM THE UPPER LEVEL BRIDGE CRANE, THIS ENGINE WAS THE DIRECT DRIVE TO THE 40" BLOOMING MILL LOCATED IN THE ADJACENT ROOM TO THE LEFT. THE UNITED-TOD ENGINE, A TWIN TANDEM COMPOUND STEAM ENGINE, WAS RATED AT 20,000 MP. IN 1946 NEW HIGH PRESSURE CYLINDERS WERE INSTALLED AND THE ENGINE RAN ON 200 PSI STEAM, WITH A 44"X76"X60" STROKE, TO A BUILT-UP COUNTER-BALANCED CENTER CRANK. - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

6. EXTERIOR VIEW OF HILLMAN FAN HOUSE LOOKING WEST The ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. EXTERIOR VIEW OF HILLMAN FAN HOUSE LOOKING WEST The engine house is on the right. The end of the 1883 Pittston Steam Engine cylinder head and steam chest is visible in the doorway. Although its stairs are missing, the iron framing of a porch stands in front of what was a doorway. The entrance door to the north airlock is visible inside the enlarged window. The end view of the upshaft chimney shows the brick ribbing for support, the brick corbelling, and concrete capstones. - Dorrance Colliery Fan Complex, South side of Susquehanna River at Route 115 & Riechard Street, Wilkes-Barre, Luzerne County, PA

[Effects of steaming and baking on content of alkaloids in Aconite Lateralis Radix (Fuzi)].

PubMed

Yang, Chang-lin; Huang, Zhi-fang; Zhang, Yi-han; Liu, Yu-hong; Liu, Yun-huan; Chen, Yan; Yi, Jin-hai

2014-12-01

To study the effect of steaming and baking process on contents of alkaloids in Aconite Lateralis Radix (Fuzi), 13 alkaloids were analyzed by UPLC-MS/MS equipped with ESI ion source in MRM mode. In steaming process, the contents of diester-diterpenoid alkaloids decreased rapidly, the contents of monoester-diterpenoid alkaloids firstly increased, reached the peak at 40 min, and then deceased gradually. The contents of aconine alkaloids (mesaconine, aconine and hypaconine) increased all the time during processing, while the contents of fuziline, songorine, karacoline, salsolionl were stable or slightly decreased. In baking process, dynamic variations of alkaloids were different from that in the steaming process. Diester-diterpenoid alkaloids were degraded slightly slower than in steaming process. Monoester-diterpenoid alkaloids, aconine alkaloids and the total alkaloids had been destroyed at different degrees, their contents were significantly lower than the ones in steaming Fuzi at the same processing time. This experiment revealed the dynamic variations of alkaloids in the course of steaming and baking. Two processing methods which can both effectively remove the toxic ingredients and retain the active ingredients are simple and controllable, and are valuable for popularization and application.

Effect of flow velocity on the process of air-steam condensation in a vertical tube condenser

NASA Astrophysics Data System (ADS)

Havlík, Jan; Dlouhý, Tomáš

2018-06-01

This article describes the influence of flow velocity on the condensation process in a vertical tube. For the case of condensation in a vertical tube condenser, both the pure steam condensation process and the air-steam mixture condensation process were theoretically and experimentally analyzed. The influence of steam flow velocity on the value of the heat transfer coefficient during the condensation process was evaluated. For the condensation of pure steam, the influence of flow velocity on the value of the heat transfer coefficient begins to be seen at higher speeds, conversely, this effect is negligible at low values of steam velocity. On the other hand, for the air-steam mixture condensation, the influence of flow velocity must always be taken into account. The flow velocity affects the water vapor diffusion process through non-condensing air. The presence of air significantly reduces the value of the heat transfer coefficient. This drop in the heat transfer coefficient is significant at low velocities; on the contrary, the decrease is relatively small at high values of the velocity.

Breckinridge Project, initial effort

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1982-01-01

The project cogeneration plant supplies electric power, process steam and treated boiler feedwater for use by the project plants. The plant consists of multiple turbine generators and steam generators connected to a common main steam header. The major plant systems which are required to produce steam, electrical power and treated feedwater are discussed individually. The systems are: steam, steam generator, steam generator fuel, condensate and feedwater deaeration, condensate and blowdown collection, cooling water, boiler feedwater treatment, coal handling, ash handling (fly ash and bottom ash), electrical, and control system. The plant description is based on the Phase Zero design basismore » established for Plant 31 in July of 1980 and the steam/condensate balance as presented on Drawing 31-E-B-1. Updating of steam requirements as more refined process information becomes available has generated some changes in the steam balance. Boiler operation with these updated requirements is reflected on Drawing 31-D-B-1A. The major impact of updating has been that less 600 psig steam generated within the process units requires more extraction steam from the turbine generators to close the 600 psig steam balance. Since the 900 psig steam generation from the boilers was fixed at 1,200,000 lb/hr, the additional extraction steam required to close the 600 psig steam balance decreased the quantity of electrical power available from the turbine generators. In the next phase of engineering work, the production of 600 psig steam will be augmented by increasing convection bank steam generation in the Plant 3 fired heaters by 140,000 to 150,000 lb/hr. This modification will allow full rated power generation from the turbine generators.« less

Evaluation Of In Situ Steam-Injection Processes For Reduction Of Petroleum Compounds Within An Abandoned Canal

EPA Science Inventory

A conceptual approach of a novel application of in-situ thermal processes that would either use a steam injection process or a steam/surfactant injection process was considered to remediate petroleum contaminated sediment residing in an abandoned canal. Laboratory tests were c...

60. View from stock bin trestle looking northeast at Babcock ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

60. View from stock bin trestle looking northeast at Babcock & Wilcox type boilers (manufactured by Casey-Hedges Co., Chattanooga, TN) where washed furnace gas is burned with natural gas and coal to generate heat for steam. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

Steam distillation extraction of ginger essential oil: Study of the effect of steam flow rate and time process

NASA Astrophysics Data System (ADS)

Fitriady, Muhammad Arifuddin; Sulaswatty, Anny; Agustian, Egi; Salahuddin, Aditama, Deska Prayoga Fauzi

2017-01-01

In Indonesia ginger was usually used as a seasoning for dishes, an ingredient for beverage and a source of herbal medicines. Beside raw usage, ginger can be processed to obtain the essential oil which has many advantages such as proven to be an active antimicrobial and having an antioxidant ability. There are a lot of methods to extract essential oil from ginger, one of which is steam distillation. The aim of the current study was to investigate the effect of variation of time process and steam flow rate in the yield on ginger essential oil steam distillation extraction process. It was found that the best operation condition was 0.35 ml/s as the steam flow rate which yields 2.43% oil. The optimum time process was predicted at 7.5 hours. The composition of the oil was varied depend on the flow rate and every flow rate has its own major component contained in the oil. Curcumene composition in the oil was increased as increased steam flow rate applied, but the composition of camphene was decreased along with the increasing steam flow rate.

Review of surface steam sterilization for validation purposes.

PubMed

van Doornmalen, Joost; Kopinga, Klaas

2008-03-01

Sterilization is an essential step in the process of producing sterile medical devices. To guarantee sterility, the process of sterilization must be validated. Because there is no direct way to measure sterility, the techniques applied to validate the sterilization process are based on statistical principles. Steam sterilization is the most frequently applied sterilization method worldwide and can be validated either by indicators (chemical or biological) or physical measurements. The steam sterilization conditions are described in the literature. Starting from these conditions, criteria for the validation of steam sterilization are derived and can be described in terms of physical parameters. Physical validation of steam sterilization appears to be an adequate and efficient validation method that could be considered as an alternative for indicator validation. Moreover, physical validation can be used for effective troubleshooting in steam sterilizing processes.

In situ analysis of chemical components induced by steaming between fresh ginseng, steamed ginseng, and red ginseng.

PubMed

In, Gyo; Ahn, Nam-Geun; Bae, Bong-Seok; Lee, Myoung-Woo; Park, Hee-Won; Jang, Kyoung Hwa; Cho, Byung-Goo; Han, Chang Kyun; Park, Chae Kyu; Kwak, Yi-Seong

2017-07-01

The chemical constituents of Panax ginseng are changed by processing methods such as steaming or sun drying. In the present study, the chemical change of Panax ginseng induced by steaming was monitored in situ . Samples were separated from the same ginseng root by incision during the steaming process, for in situ monitoring. Sampling was sequentially performed in three stages; FG (fresh ginseng) → SG (steamed ginseng) → RG (red ginseng) and 60 samples were prepared and freeze dried. The samples were then analyzed to determine 43 constituents among three stages of P. ginseng . The results showed that six malonyl-ginsenoside (Rg1, Rb1, Rb3, Rc, Rd, Rb2) and 15 amino acids were decreased in concentration during the steaming process. In contrast, ginsenoside-Rh1, 20( S )-Rg2, 20( S, R )-Rg3 and Maillard reaction product such as AF (arginine-fructose), AFG (arginine-fructose-glucose), and maltol were newly generated or their concentrations were increased. This study elucidates the dynamic changes in the chemical components of P. ginseng when the steaming process was induced. These results are thought to be helpful for quality control and standardization of herbal drugs using P. ginseng and they also provide a scientific basis for pharmacological research of processed ginseng (Red ginseng).

Effect of soaking, boiling, and steaming on total phenolic contentand antioxidant activities of cool season food legumes.

PubMed

Xu, Baojun; Chang, Sam K C

2008-09-01

The effects of soaking, boiling and steaming processes on the total phenolic components and antioxidant activity in commonly consumed cool season food legumes (CSFL's), including green pea, yellow pea, chickpea and lentil were investigated. As compared to original unprocessed legumes, all processing steps caused significant (p<0.05) decreases in total phenolic content (TPC), DPPH free radical scavenging activity (DPPH) in all tested CSFL's. All soaking and atmospheric boiling treatments caused significant (p<0.05) decreases in oxygen radical absorbing capacity (ORAC). However, pressure boiling and pressure steaming caused significant (p<0.05) increases in ORAC values. Steaming treatments resulted in a greater retention of TPC, DPPH, and ORAC values in all tested CSFL's as compared to boiling treatments. To obtain cooked legumes with similar palatability and firmness, pressure boiling shortened processing time as compared to atmospheric boiling, resulted in insignificant differences in TPC, DPPH for green and yellow pea. However, TPC and DPPH in cooked lentils differed significantly between atmospheric and pressure boiling. As compared to atmospheric processes, pressure processes significantly increased ORAC values in both boiled and steamed CSFL's. Greater TPC, DPPH and ORAC values were detected in boiling water than that in soaking and steaming water. Boiling also caused more solid loss than steaming. Steam processing exhibited several advantages in retaining the integrity of the legume appearance and texture of the cooked product, shortening process time, and greater retention of antioxidant components and activities. Copyright © 2008 Elsevier Ltd. All rights reserved.

Effect of carbide precipitation on the corrosion behavior of Inconel alloy 690

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sarver, J.M.; Crum, J.R.; Mankins, W.L.

1987-01-01

Intergranular carbide precipitation reactions have been shown to affect the stress corrosion cracking (SCC) resistance of nickel-chromium-iron alloys in environments relative to nuclear steam generators. Carbon solubility curves, time-temperature-sensitization plots and other carbide precipitation data are presented for alloy 690 as an aid in developing heat treatments for improved SCC resistance.

21. INTERIOR VIEW, UNDER THE MAIN FLOOR SHOWING THE LINESHAFT ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

21. INTERIOR VIEW, UNDER THE MAIN FLOOR SHOWING THE LINESHAFT SYSTEM ONCE POWERED BY A STEAM ENGINE AND LATER BY TWO LARGE ELECTRICAL MILL MOTORS (NOTICE LARGE GEAR IN FOREGROUND) THAT OPERATED EACH NAIL MACHINE; PRESENTLY THE NAIL MACHINES ARE DRIVEN BY INDIVIDUAL ELECTRICAL MOTORS - LaBelle Iron Works, Thirtieth & Wood Streets, Wheeling, Ohio County, WV

Distillate fuel-oil processing for phosphoric acid fuel cell power plants

NASA Astrophysics Data System (ADS)

1980-02-01

Efforts to develop distillate oil steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high temperature steam reforming; autothermal reforming; autothermal gasification; and ultra desulfurization followed by steam reforming. Sulfur in the feed is a problem in the process development.

Development and property evaluation of nuclear grade wrought FeCrAl fuel cladding for light water reactors

DOE PAGES

Yamamoto, Yukinori; Pint, Bruce A.; Terrani, Kurt A.; ...

2015-10-19

Development of nuclear grade, iron-based wrought FeCrAl alloys has been initiated for light water reactor (LWR) fuel cladding to serve as a substitute for zirconium-based alloys with enhanced accident tolerance. Ferritic alloys with sufficient chromium and aluminum additions can exhibit significantly improved oxidation kinetics in high-temperature steam environments when compared to zirconium-based alloys. In the first phase, a set of model FeCrAl alloys containing 10–20Cr, 3–5Al, and 0–0.12Y in weight percent, were prepared by conventional arc-melting and hot-working processes to explore the effect of composition on the properties of FeCrAlY alloys. It was found that the tensile properties were insensitivemore » to the alloy compositions studied; however, the steam oxidation resistance strongly depended on both the chromium and the aluminum contents. The second phase development focused on strengthening Fe-13Cr-5Al with minor alloying additions of molybdenum, niobium, and silicon. Combined with an optimized thermo-mechanical treatment, a thermally stable microstructure was produced with improved tensile properties at temperatures up to 741°C.« less

75 FR 68294 - Revisions to the California State Implementation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-05

... matter emissions from boilers, steam generators and process heaters greater than 5.0 MMbtu/hour. We are... Advance Emission 10/16/08 03/17/09 Reduction Options for Boilers, Steam Generators and Process Heaters..., steam generators and process heaters with a total rated heat input greater than 5 MMBtu/ hour. EPA's...

Experiences with industrial solar process steam generation in Jordan

NASA Astrophysics Data System (ADS)

Krüger, Dirk; Berger, Michael; Mokhtar, Marwan; Willwerth, Lisa; Zahler, Christian; Al-Najami, Mahmoud; Hennecke, Klaus

2017-06-01

At the Jordanian pharmaceuticals manufacturing company RAM Pharma a solar process heat supply has been constructed by Industrial Solar GmbH in March 2015 and operated since then (Figure 1). The collector field consists of 394 m² of linear Fresnel collectors supplying saturated steam to the steam network at RAM Pharma at about 6 bar gauge. In the frame of the SolSteam project funded by the German Federal Ministry for Economic Affairs and Energy (BMWi) the installation has been modified introducing an alternative way to separate water and steam by a cyclone. This paper describes the results of experiments with the cyclone and compares the operation with a steam drum. The steam production of the solar plant as well as the fuel demand of the steam boiler are continuously monitored and results are presented in this paper.

Invited review: summary of steam-flaking corn or sorghum grain for lactating dairy cows.

PubMed

Theurer, C B; Huber, J T; Delgado-Elorduy, A; Wanderley, R

1999-09-01

Nineteen lactation trials (43 grain processing comparisons) are summarized, in addition to digestibility and postabsorptive metabolism studies. The net energy for lactation (NEL) of steam-flaked corn or sorghum grain is about 20% greater than the NEL for dry-rolled corn or sorghum. Based on lactational performance, steam-flaked sorghum grain is of equal value to steam-flaked corn, and steam-flaked corn is superior to steam-rolled corn. Steam-flaking of corn or sorghum compared to steam-rolling of corn or dry-rolling of corn or sorghum consistently improves milk production and milk protein yield. This result is because of a much greater proportion of dietary starch fermented in the rumen, enhanced digestibility of the smaller fraction of dietary starch reaching the small intestine, and increased total starch digestion. Steam-flaking increases cycling of urea to the gut, microbial protein flow to the small intestine, and estimated mammary uptake of amino acids. Steam-rolling compared to dry-rolling of barley or wheat did not alter total starch digestibilities in two trials, one with each grain source. Lactation studies with these processing comparisons have not been reported. Most cited studies have been with total mixed rations (TMR) and alfalfa hay as the principal forage. Additional studies are needed with lactating cows fed steam-flaked corn or sorghum in TMR containing alfalfa or corn silage. Optimal flake density of steam-processed corn or sorghum grain appears to be about 360 g/L (approximately 28 lb/bu).

Production of synthetic fuels using syngas from a steam hydrogasification and reforming process

NASA Astrophysics Data System (ADS)

Raju, Arun Satheesh Kumar

This thesis is aimed at the research, optimization and development of a thermo-chemical process aimed at the production of synthesis gas (mixture of H2 and CO) with a flexible H2 to CO ratio using coupled steam hydrogasification and steam reforming processes. The steam hydrogasification step generates a product gas containing significant amounts of methane by gasifying a carbonaceous feed material with steam and internally generated H2. This product gas is converted to synthesis gas with an excess H2 to CO using the steam reformer. Research involving experimental and simulation work has been conducted on steam hydrogasification, steam reforming and the Fischer-Tropsch reaction. The Aspen Plus simulation tool has been used to develop a process model that can perform heat and mass balance calculations of the whole process using built-in reactor modules and an empirical FT model available in the literature. This model has been used to estimate optimum feed ratios and process conditions for specific feedstocks and products. Steam hydrogasification of coal and wood mixtures of varying coal to wood ratios has been performed in a stirred batch reactor. The carbon conversion of the feedstocks to gaseous products is around 60% at 700°C and 80% at 800°C. The coal to wood ratio of the feedstock does not exert a significant influence on the carbon conversion. The rates of formation of CO, CO 2 and CH4 during gasification have been calculated based on the experimental results using a simple kinetic model. Experimental research on steam reforming has been performed. It has been shown that temperature and the feed CO2/CH4 ratio play a dominant role in determining the product gas H2/CO ratio. Reforming of typical steam hydrogasification product-gas stream has been investigated over a commercial steam reforming catalyst. The results demonstrate that the combined use of steam hydrogasification process with a reformer can generate a synthesis gas with a predetermined H2/CO ratio from carbonaceous feedstocks. Experimental work on the Fischer-Tropsch synthesis has also been performed. A life cycle analysis has been performed with the objective of comparing the life cycle energy consumption and emissions of synthetic diesel fuel produced through the CE-CERT process with other fuel/vehicle combinations. The experimental and simulation results presented here demonstrate that the CE-CERT process is versatile and can potentially handle a number of different feedstocks. CE-CERT process appears to be suitable for commercialization in very large scales with a coal feedstock and also in a distributed network of smaller scale reactors utilizing localized renewable feedstocks.

One-Step Coal Liquefaction

NASA Technical Reports Server (NTRS)

Qader, S. A.

1984-01-01

Steam injection improves yield and quality of product. Single step process for liquefying coal increases liquid yield and reduces hydrogen consumption. Principal difference between this and earlier processes includes injection of steam into reactor. Steam lowers viscosity of liquid product, so further upgrading unnecessary.

Advanced Steels for Accident Tolerant Fuel Cladding in Current Light Water Reactors

NASA Astrophysics Data System (ADS)

Rebak, Raul B.

After the March 2011 Fukushima events, the U.S. Congress directed the Department of Energy (DOE) to focus efforts on the development of fuel cladding materials with enhanced accident tolerance. In comparison with the stand-ard UO2-Zirconium based system, the new fuels need to tolerate loss of active cooling in the core for a considerably longer time period while maintaining or improving the fuel performance during normal operation conditions. Advanced steels such as iron-chromium-aluminum (FeCrAl) alloys are being investigated for degradation behavior both under normal operation conditions in high temperature water (e.g. 288°C) and under accident conditions for reaction with steam up to 1400°C. Commercial and experimental alloys were tested for several periods of time in 100% superheated steam from 800°C to 1475°C. Results show that FeCrAl alloys significantly outperform the resistance in steam of the current zirconium alloys.

Investigation of on-line chelant addition to PWR steam generators. Annual report, 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tvedt, T.J.; Wallace, S.L.; Griffin, F. Jr.

1982-11-01

The thermostability of both ethylenediaminetetraacetic acid (EDTA) and hydroxyethylethylenediamininetriacetic acid (HEDTA) metal chelates in all volatile treatment water chemistry (AVT) was shown to be greater than or equal to thermostability of EDTA metal chelates in phosphate-sulfite water chemistry. HEDTA metal chelates were shown to have a much greater stability than EDTA metal chelates. Using samples taken from the EDTA metal chelate thermostability studies and samples from Commonwealth Research Corporation (CRC) model steam generators (MSG), EDTA decomposition products were determined. Active metal surfaces were shown to become passivated when exposed to EDTA and HEDTA concentrations as high as 0.1% w/w inmore » AVT. Trace amounts of iron in the water were found to increase the rate of passivation. Material balance and visual inspection data from CRC model steam generators showed that metal is being transported through and cleaning from the MSG's. EDTA metal chelates were removed from chelate solutions by passing the solutions over strong anion exchange resins.« less

A Novel Method for Preparing Auxetic Foam from Closed-cell Polymer Foam Based on Steam Penetration and Condensation (SPC) Process.

PubMed

Fan, Donglei; Li, Minggang; Qiu, Jian; Xing, Haiping; Jiang, Zhiwei; Tang, Tao

2018-05-31

Auxetic materials are a class of materials possessing negative Poisson's ratio. Here we establish a novel method for preparing auxetic foam from closed-cell polymer foam based on steam penetration and condensation (SPC) process. Using polyethylene (PE) closed-cell foam as an example, the resultant foams treated by SPC process present negative Poisson's ratio during stretching and compression testing. The effect of steam-treated temperature and time on the conversion efficiency of negative Poisson's ratio foam is investigated, and the mechanism of SPC method for forming re-entrant structure is discussed. The results indicate that the presence of enough steam within the cells is a critical factor for the negative Poisson's ratio conversion in the SPC process. The pressure difference caused by steam condensation is the driving force for the conversion from conventional closed-cell foam to the negative Poisson's ratio foam. Furthermore, the applicability of SPC process for fabricating auxetic foam is studied by replacing PE foam by polyvinyl chloride (PVC) foam with closed-cell structure or replacing water steam by ethanol steam. The results verify the universality of SPC process for fabricating auxetic foams from conventional foams with closed-cell structure. In addition, we explored potential application of the obtained auxetic foams by SPC process in the fabrication of shape memory polymer materials.

Actual operation and regulatory activities on steam generator replacement in Japan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saeki, Hitoshi

1997-02-01

This paper summarizes the operating reactors in Japan, and the status of the steam generators in these plants. It reviews plans for replacement of existing steam generators, and then goes into more detail on the planning and regulatory steps which must be addressed in the process of accomplishing this maintenance. The paper also reviews the typical steps involved in the process of removal and replacement of steam generators.

3. GENERAL VIEW OF REMAINS OF 40" BLOOMING MILL; THE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. GENERAL VIEW OF REMAINS OF 40" BLOOMING MILL; THE ENGINE ROOM CONTAINING THE MESTA-CORLISS STEAM ENGINE, IS LOCATED AT THE FAR END OF THE MILL AS SEEN TO THE FAR RIGHT (THE BUILDING WITH THE SHED ROOF). - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

Chemical changes associated with lotus and water lily natto production

NASA Astrophysics Data System (ADS)

Lestari, S. D.; Fatimah, N.; Nopianti, R.

2017-04-01

Natto is a traditional Japanese food made by fermenting whole soybean seeds with pure culture of Bacillus subtilis subsp. natto. The purpose of this study was to investigate the suitability of lotus (Nelumbo nucifera) and water lily (Nymphaea stellata) seeds as the raw materials for natto production. Chemical (proximate, amino acids and minerals) changes were observed on raw, steamed and fermented seeds. Proximate compositions of all samples were calculated in both wet basis and dry basis. In wet basis calculation, steaming and fermentation tended to lower the carbohydrates, ashes, fats and protein content which were attributed to the increase of moisture. The total amino acid, iron and magnesium contents of raw lotus seeds were 24.29%, 5.08 mg 100g-1 and 174.23 mg 100g-1 dry matter, respectively. After a 24h-fermentation at 40°C, the total amino acids decreased while iron and magnesium contents increased significantly reaching, in respective order, 9.9 mg 100g-1 and 411.36 mg 100g-1 dry matter. Changes in chemical composition after fermentation were more pronounced in lotus seeds than water lily seeds indicating that their nutrient composition were more suitable to support Bacillus subtilis growth.

Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seaman, John

2013-01-14

The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittal’s Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel;more » however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.« less

Hydrogen production from steam reforming of ethylene glycol over iron loaded on MgO

NASA Astrophysics Data System (ADS)

Chen, Mingqiang; Wang, Yishuang; Liang, Tian; Yang, Jie; Yang, Zhonglian

2017-01-01

In this study, a series of Fe-based catalysts loaded on MgO were prepared by a precipitation technique. And they were tested in hydrogen production from steam reforming of ethylene glycol (SRE), which was a representative model compound of fast bio-oil. The catalysts were characterized by XRD, SEM and H2-TPR analysis. The results showed that the crystalline phases of catalysts contained Fe2O3 (Hematite), Fe3O4 (Magnetite), Fe2MgO4 (iron magnesium oxide) and MgO, and morphology of MgO was changed from the rugby-ball like particles to spherical particles with the addition of Fe. In addition, the catalytic test results indicated that the 18%Fe/MgO catalyst exhibited the highest ethylene glycol conversion (˜99.8%) and H2 molar percent (˜77%) during at the following conditions: H2O/C molar ratio is 5˜7, the feeding rate is 14 mL/h and the reaction temperature at 600˜650°C. Furthermore, the 18%Fe/MgO catalyst can keep outstanding stability during SRE for 12 h.

High-temperature oxidation of advanced FeCrNi alloy in steam environments

NASA Astrophysics Data System (ADS)

Elbakhshwan, Mohamed S.; Gill, Simerjeet K.; Rumaiz, Abdul K.; Bai, Jianming; Ghose, Sanjit; Rebak, Raul B.; Ecker, Lynne E.

2017-12-01

Alloys of iron-chromium-nickel are being explored as alternative cladding materials to improve safety margins under severe accident conditions. Our research focuses on non-destructively investigating the oxidation behavior of the FeCrNi alloy "Alloy 33" using synchrotron-based methods. The evolution and structure of oxide layer formed in steam environments were characterized using X-ray diffraction, hard X-ray photoelectron spectroscopy, X-ray fluorescence methods and scanning electron microscopy. Our results demonstrate that a compact and continuous oxide scale was formed consisting of two layers, chromium oxide and spinel phase (FeCr2O4) oxides, wherein the concentration of the FeCr2O4 phase decreased from the surface to the bulk-oxide interface.

Liquid-metal magnetohydrodynamic system evaluation. [coal-fired designs

NASA Technical Reports Server (NTRS)

Holman, R. R.; Lippert, T. E.

1976-01-01

The present study emphasizes a direct coal-fired design using a bubbly two-component flow of sodium and argon in the MHD generator and a Rankine steam-bottoming plant. Two basic cycles were studied, corresponding to argon temperatures of 922 and 1089 K at the duct inlet. The MHD duct system consisted of multiple ducts arranged in clusters and separated by iron magnet pole pieces. The ducts, each with an output of about 100 MW, were parallel to the flow, but were connected in series electrically to provide a higher MHD voltage. With channel efficiencies of 80%, a pump efficiency of 90%, and a 45% efficient steam-bottoming plant, the overall efficiency of the 1089 K liquid-metal MHD power plant was 43%.

Application of Fourier transform near-infrared spectroscopy to optimization of green tea steaming process conditions.

PubMed

Ono, Daiki; Bamba, Takeshi; Oku, Yuichi; Yonetani, Tsutomu; Fukusaki, Eiichiro

2011-09-01

In this study, we constructed prediction models by metabolic fingerprinting of fresh green tea leaves using Fourier transform near-infrared (FT-NIR) spectroscopy and partial least squares (PLS) regression analysis to objectively optimize of the steaming process conditions in green tea manufacture. The steaming process is the most important step for manufacturing high quality green tea products. However, the parameter setting of the steamer is currently determined subjectively by the manufacturer. Therefore, a simple and robust system that can be used to objectively set the steaming process parameters is necessary. We focused on FT-NIR spectroscopy because of its simple operation, quick measurement, and low running costs. After removal of noise in the spectral data by principal component analysis (PCA), PLS regression analysis was performed using spectral information as independent variables, and the steaming parameters set by experienced manufacturers as dependent variables. The prediction models were successfully constructed with satisfactory accuracy. Moreover, the results of the demonstrated experiment suggested that the green tea steaming process parameters could be predicted on a larger manufacturing scale. This technique will contribute to improvement of the quality and productivity of green tea because it can objectively optimize the complicated green tea steaming process and will be suitable for practical use in green tea manufacture. Copyright © 2011 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

40 CFR 429.80 - Applicability; description of the wood preserving-steam subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 31 2013-07-01 2013-07-01 false Applicability; description of the wood... Wood Preserving Steam Subcategory § 429.80 Applicability; description of the wood preserving—steam... process wastewater pollutants into publicly owned treatment works from wood preserving processes that use...

40 CFR 429.80 - Applicability; description of the wood preserving-steam subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 30 2014-07-01 2014-07-01 false Applicability; description of the wood... Wood Preserving Steam Subcategory § 429.80 Applicability; description of the wood preserving—steam... process wastewater pollutants into publicly owned treatment works from wood preserving processes that use...

40 CFR 429.80 - Applicability; description of the wood preserving-steam subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 31 2012-07-01 2012-07-01 false Applicability; description of the wood... Wood Preserving Steam Subcategory § 429.80 Applicability; description of the wood preserving—steam... process wastewater pollutants into publicly owned treatment works from wood preserving processes that use...

Pretreatment effects on orange processing waste for making ethanol by simultaneous saccharification and fermentation

USDA-ARS?s Scientific Manuscript database

Pretreatment of orange processing waste (CPW) by steam explosion under various conditions (pretreatment time, pH and temperatures) was investigated. Pretreatments longer than 4 min with steam purging resulted in CPW containing less than 0.1% limonene, an inhibitor for fermentation. Steam pretreatmen...

Process for purifying geothermal steam

DOEpatents

Li, Charles T.

1980-01-01

Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

Process for purifying geothermal steam

DOEpatents

Li, C.T.

Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

DEMONSTRATION BULLETIN STEAM ENHANCED REMEDIATION STEAM TECH ENVIRONMENTAL SERVICES, INC.

EPA Science Inventory

Steam Enhanced Remediation is a process in which steam is injected into the subsurface to recover volatile and semivolatile organic contaminants. It has been applied successfully to recover contaminants from soil and aquifers and at a fractured granite site. This SITE demonstra...

Integrated gasifier combined cycle polygeneration system to produce liquid hydrogen

NASA Technical Reports Server (NTRS)

Burns, R. K.; Staiger, P. J.; Donovan, R. M.

1982-01-01

An integrated gasifier combined cycle (IGCC) system which simultaneously produces electricity, process steam, and liquid hydrogen was evaluated and compared to IGCC systems which cogenerate electricity and process steam. A number of IGCC plants, all employing a 15 MWe has turbine and producing from 0 to 20 tons per day of liquid hydrogen and from 0 to 20 MWt of process steam were considered. The annual revenue required to own and operate such plants was estimated to be significantly lower than the potential market value of the products. The results indicate a significant potential economic benefit to configuring IGCC systems to produce a clean fuel in addition to electricity and process steam in relatively small industrial applications.

Novel integrated mechanical biological chemical treatment (MBCT) systems for the production of levulinic acid from fraction of municipal solid waste: A comprehensive techno-economic analysis.

PubMed

Sadhukhan, Jhuma; Ng, Kok Siew; Martinez-Hernandez, Elias

2016-09-01

This paper, for the first time, reports integrated conceptual MBCT/biorefinery systems for unlocking the value of organics in municipal solid waste (MSW) through the production of levulinic acid (LA by 5wt%) that increases the economic margin by 110-150%. After mechanical separation recovering recyclables, metals (iron, aluminium, copper) and refuse derived fuel (RDF), lignocelluloses from remaining MSW are extracted by supercritical-water for chemical valorisation, comprising hydrolysis in 2wt% dilute H2SO4 catalyst producing LA, furfural, formic acid (FA), via C5/C6 sugar extraction, in plug flow (210-230°C, 25bar, 12s) and continuous stirred tank (195-215°C, 14bar, 20min) reactors; char separation and LA extraction/purification by methyl isobutyl ketone solvent; acid/solvent and by-product recovery. The by-product and pulping effluents are anaerobically digested into biogas and fertiliser. Produced biogas (6.4MWh/t), RDF (5.4MWh/t), char (4.5MWh/t) are combusted, heat recovered into steam generation in boiler (efficiency: 80%); on-site heat/steam demand is met; balance of steam is expanded into electricity in steam turbines (efficiency: 35%). Copyright © 2016 Elsevier Ltd. All rights reserved.

DETERMINATION OF MAXIMUM PERMISSIBLE LEAKAGE FROM THE HRT PROCESS STEAM SYSTEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gift, E.H.

1959-01-30

Calculations were made to determine the radiation hazard to HRT personnel as a result of leakage to the atmosphere from the process steam system in the event of a heat exchanger tube rupture. These calculations show that with the present four-minute delay before dumping approximately 1020 lb of fuel solution may be transferred to the steam system. The radiation hazard from fission products in the atomosphere will be negligble if the steam killer blower is operating. If this blower is not operatin. a natural convection loop will be set up in the steam killer which will have a condensing capacitymore » of 4 lb/min of steam at atmospheric pressure. In this latter case. the inhalation hazard will be negligible when the leak rate through the steam stop valves is less than 4lb/ min. (auth)« less

Reforming of natural gas—hydrogen generation for small scale stationary fuel cell systems

NASA Astrophysics Data System (ADS)

Heinzel, A.; Vogel, B.; Hübner, P.

The reforming of natural gas to produce hydrogen for fuel cells is described, including the basic concepts (steam reforming or autothermal reforming) and the mechanisms of the chemical reactions. Experimental work has been done with a compact steam reformer, and a prototype of an experimental reactor for autothermal reforming was tested, both containing a Pt-catalyst on metallic substrate. Experimental results on the steam reforming system and a comparison of the steam reforming process with the autothermal process are given.

Solar process steam for a pharmaceutical company in Jordan

NASA Astrophysics Data System (ADS)

Berger, M.; Mokhtar, M.; Zahler, C.; Al-Najami, M. M. R.; Krüger, D.; Hennecke, K.

2016-05-01

This paper presents details of the recent installation of a linear Fresnel collector to provide saturated steam for process heat usage through Direct Steam Generation (DSG) for industrial use in the Jordanian pharmaceuticals manufacturing company RAM Pharma, where first solar steam has been provided in March 2015. This commercial DSG project also represents the first solar DSG plant in MENA. During sunshine, the system achieves a solar fraction of 100 %, and the conventional steam boiler is not needed. In the evening the fossil fired backup takes over automatically and replaces the solar collector in operation. Operational experience, details of the control strategy, and measurement data are presented in the paper.

Transformation of deoxynivalenol and its acetylated derivatives in Chinese steamed bread making, as affected by pH, yeast, and steaming time.

PubMed

Wu, Li; Wang, Bujun

2016-07-01

We hereby report the transformation of deoxynivalenol (DON) and its acetylated derivatives (3-ADON and 15-ADON) by spiking targeted mycotoxins to Fusarium mycotoxin-free flour in the process of making Chinese steamed bread (CSB). The impacts of pH, yeast level, and steaming time on the transformation of 3-ADON to DON were investigated. DON, 3-ADON, and 15-ADON were analyzed by UPLC-MS/MS. Spiked DON was stable throughout the CSB making process. Spiked 3-ADON and 15-ADON were partially deacetylated and transformed to DON during kneading (54.1-60.0% and 59.3-77.5%, respectively), fermentation (64.0-76.9% and 78.2-91.6%, respectively), and steaming (47.2-52.7% and 52.4-61.9%, respectively). The ADONs level increased after steaming compared with their level in the previous step. The pH level and steaming duration significantly (P<0.05) affected the conversion of 3-ADON during the CSB making process. Briefly, alkaline conditions and short steaming times favored the deacetylation of 3-ADON. The level of yeast did not remarkably (P<0.05) alter the transformation between ADONs and DON. Copyright © 2016 Elsevier Ltd. All rights reserved.

High-temperature oxidation of advanced FeCrNi alloy in steam environments

DOE PAGES

Elbakhshwan, Mohamed S.; Gill, Simerjeet K.; Rumaiz, Abdul K.; ...

2017-07-04

Alloys of iron-chromium-nickel are being explored as alternative cladding materials to improve safety margins under severe accident conditions. Here, our research focuses on non-destructively investigating the oxidation behavior of the FeCrNi alloy “Alloy 33” using synchrotron-based methods. The evolution and structure of oxide layer formed in steam environments were characterized using X-ray diffraction, hard X-ray photoelectron spectroscopy, X-ray fluorescence methods and scanning electron microscopy. In conclusion, our results demonstrate that a compact and continuous oxide scale was formed consisting of two layers, chromium oxide and spinel phase (FeCr 2O 4) oxides, wherein the concentration of the FeCr 2O 4 phasemore » decreased from the surface to the bulk-oxide interface.« less

Modeling of corrosion product migration in the secondary circuit of nuclear power plants with WWER-1200

NASA Astrophysics Data System (ADS)

Kritskii, V. G.; Berezina, I. G.; Gavrilov, A. V.; Motkova, E. A.; Zelenina, E. V.; Prokhorov, N. A.; Gorbatenko, S. P.; Tsitser, A. A.

2016-04-01

Models of corrosion and mass transfer of corrosion products in the pipes of the condensate-feeding and steam paths of the secondary circuit of NPPs with WWER-1200 are presented. The mass transfer and distribution of corrosion products over the currents of the working medium of the secondary circuit were calculated using the physicochemical model of mass transfer of corrosion products in which the secondary circuit is regarded as a cyclic system consisting of a number of interrelated elements. The circuit was divided into calculated regions in which the change in the parameters (flow rate, temperature, and pressure) was traced and the rates of corrosion and corrosion products entrainment, high-temperature pH, and iron concentration were calculated. The models were verified according to the results of chemical analyses at Kalinin NPP and iron corrosion product concentrations in the feed water at different NPPs depending on pH at 25°C (pH25) for service times τ ≥ 5000 h. The calculated pH values at a coolant temperature t (pH t ) in the secondary circuit of NPPs with WWER-1200 were presented. The calculation of the distribution of pH t and ethanolamine and ammonia concentrations over the condensate feed (CFC) and steam circuits is given. The models are designed for developing the calculation codes. The project solutions of ATOMPROEKT satisfy the safety and reliability requirements for power plants with WWER-1200. The calculated corrosion and corrosion product mass transfer parameters showed that the model allows the designer to choose between the increase of the correcting reagent concentration, the use of steel with higher chromium contents, and intermittent washing of the steam generator from sediments as the best solution for definite regions of the circuit.

In-Space Propulsion, Logistics Reduction, and Evaluation of Steam Reformer Kinetics: Problems and Prospects

NASA Technical Reports Server (NTRS)

Jaworske, D. A.; Palaszewski, B. A.; Kulis, M. J.; Gokoglu, S. A.

2015-01-01

Human space missions generate waste materials. A 70-kg crewmember creates a waste stream of 1 kg per day, and a four-person crew on a deep space habitat for a 400+ day mission would create over 1600 kg of waste. Converted into methane, the carbon could be used as a fuel for propulsion or power. The NASA Advanced Exploration Systems (AES) Logistics Reduction and Repurposing (LRR) project is investing in space resource utilization with an emphasis on repurposing logistics materials for useful purposes and has selected steam reforming among many different competitive processes as the preferred method for repurposing organic waste into methane. Already demonstrated at the relevant processing rate of 5.4 kg of waste per day, high temperature oxygenated steam consumes waste and produces carbon dioxide, carbon monoxide, and hydrogen which can then be converted into methane catalytically. However, the steam reforming process has not been studied in microgravity. Data are critically needed to understand the mechanisms that allow use of steam reforming in a reduced gravity environment. This paper reviews the relevant literature, identifies gravity-dependent mechanisms within the steam gasification process, and describes an innovative experiment to acquire the crucial kinetic information in a small-scale reactor specifically designed to operate within the requirements of a reduced gravity aircraft flight. The experiment will determine if the steam reformer process is mass-transport limited, and if so, what level of forced convection will be needed to obtain performance comparable to that in 1-g.

Disinfection of Cystoscopes by Subatmospheric Steam and Steam and Formaldehyde at 80°C

PubMed Central

Alder, V. G.; Gingell, J. C.; Mitchell, J. P.

1971-01-01

A new method of disinfection adapted for endoscopic instruments uses low temperature steam at 80°C or steam and formaldehyde at 80°C. The process has considerable advantages over existing methods and more closely approaches the ideal requirements. ImagesFIG. 3FIG. 4FIG. 5 PMID:5569551

Net energy ratio for the production of steam pretreated biomass-based pellets

DOE PAGES

Shahrukh, Hassan; Oyedun, Adetoyese Olajire; Kumar, Amit; ...

2015-06-21

In this study, a process model was developed to determine the net energy ratio (NER) for both regular and steam-pretreated pellet production from ligno-cellulosic biomass. NER is a ratio of the net energy output to the total net energy input from non-renewable energy source into the system. Scenarios were developed to measure the effect of temperature and level of steam pretreatment on the NER of both production processes. The NER for the base case at 6 kg h –1 is 1.29 and 5.0 for steam-pretreated and regular pellet production respectively. However, at the large scale NER would improve. The majormore » factor for NER is energy for steam and drying unit. The sensitivity analysis for the model shows that the optimum temperature for steam pretreatment is 200 °C with 50% pretreatment (Steam pretreating 50% feed stock, while the rest is undergoing regular pelletization). Uncertainty result for steam pretreated and regular pellet is 1.35 ± 0.09 and 4.52 ± 0.34 respectively.« less

Performance and economic assessments of a solid oxide fuel cell system with a two-step ethanol-steam-reforming process using CaO sorbent

NASA Astrophysics Data System (ADS)

Tippawan, Phanicha; Arpornwichanop, Amornchai

2016-02-01

The hydrogen production process is known to be important to a fuel cell system. In this study, a carbon-free hydrogen production process is proposed by using a two-step ethanol-steam-reforming procedure, which consists of ethanol dehydrogenation and steam reforming, as a fuel processor in the solid oxide fuel cell (SOFC) system. An addition of CaO in the reformer for CO2 capture is also considered to enhance the hydrogen production. The performance of the SOFC system is analyzed under thermally self-sufficient conditions in terms of the technical and economic aspects. The simulation results show that the two-step reforming process can be run in the operating window without carbon formation. The addition of CaO in the steam reformer, which runs at a steam-to-ethanol ratio of 5, temperature of 900 K and atmospheric pressure, minimizes the presence of CO2; 93% CO2 is removed from the steam-reforming environment. This factor causes an increase in the SOFC power density of 6.62%. Although the economic analysis shows that the proposed fuel processor provides a higher capital cost, it offers a reducing active area of the SOFC stack and the most favorable process economics in term of net cost saving.

Heat penetration attributes of milkfish (Chanos chanos) thermal processed in flexible pouches: a comparative study between steam application and water immersion.

PubMed

Adepoju, Mary A; Omitoyin, Bamidele O; Mohan, Chitradurga O; Zynudheen, Aliyam A

2017-05-01

The difference in the heating penetration characteristics of product processed in retort by steam-air application and water immersion was studied. Fresh milkfish ( Chanos chanos ) packed in dry pack and in oil medium, both in flexible pouches, was thermal processed to minimum F 0 value of 7.77 at 121.1°C. Heat penetration values were recorded for each minute of processing with the aid Ellab (TM 9608, Denmark) temperature recorder. Retort come up time to achieve 121.1°C was observed to be less in steam-air which invariably led to a lower Ball's process time (B) and the total process time (T) observed in steam-air as compared to water immersion. Obtained data were plotted on a semi-logarithmic paper with temperature deficit on x -axis against time on the y -axis.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shahrukh, Hassan; Oyedun, Adetoyese Olajire; Kumar, Amit

In this study, a process model was developed to determine the net energy ratio (NER) for both regular and steam-pretreated pellet production from ligno-cellulosic biomass. NER is a ratio of the net energy output to the total net energy input from non-renewable energy source into the system. Scenarios were developed to measure the effect of temperature and level of steam pretreatment on the NER of both production processes. The NER for the base case at 6 kg h –1 is 1.29 and 5.0 for steam-pretreated and regular pellet production respectively. However, at the large scale NER would improve. The majormore » factor for NER is energy for steam and drying unit. The sensitivity analysis for the model shows that the optimum temperature for steam pretreatment is 200 °C with 50% pretreatment (Steam pretreating 50% feed stock, while the rest is undergoing regular pelletization). Uncertainty result for steam pretreated and regular pellet is 1.35 ± 0.09 and 4.52 ± 0.34 respectively.« less

Alteration processes in volcanic soils and identification of exobiologically important weathering products on Mars using remote sensing.

PubMed

Bishop, J L; Froschl, H; Mancinelli, R L

1998-12-25

Determining the mineralogy of the Martian surface material provides information about the past and present environments on Mars which are an integral aspect of whether or not Mars was suitable for the origin of life. Mineral identification on Mars will most likely be achieved through visible-infrared remote sensing in combination with other analyses on landed missions. Therefore, understanding the visible and infrared spectral properties of terrestrial samples formed via processes similar to those thought to have occurred on Mars is essential to this effort and will facilitate site selection for future exobiology missions to Mars. Visible to infrared reflectance spectra are presented here for the fine-grained fractions of altered tephra/lava from the Haleakala summit basin on Maui, the Tarawera volcanic complex on the northern island of New Zealand, and the Greek Santorini island group. These samples exhibit a range of chemical and mineralogical compositions, where the primary minerals typically include plagioclase, pyroxene, hematite, and magnetite. The kind and abundance of weathering products varied substantially for these three sites due, in part, to the climate and weathering environment. The moist environments at Santorini and Tarawera are more consistent with postulated past environments on Mars, while the dry climate at the top of Haleakala is more consistent with the current Martian environment. Weathering of these tephra is evaluated by assessing changes in the leachable and immobile elements, and through detection of phyllosilicates and iron oxide/oxyhydroxide minerals. Identifying regions on Mars where phyllosilicates and many kinds of iron oxides/oxyhydroxides are present would imply the presence of water during alteration of the surface material. Tephra samples altered in the vicinity of cinder cones and steam vents contain higher abundances of phyllosilicates, iron oxides, and sulfates and may be interesting sites for exobiology.

Changes in Levels of Phenylethanoid Glycosides, Antioxidant Activity, and Other Quality Traits in Cistanche deserticola Slices by Steam Processing.

PubMed

Peng, Fang; Chen, Jun; Wang, Xia; Xu, Changqing; Liu, Tongning; Xu, Rong

2016-07-01

We investigated the effect of steaming time on Cistanche deserticola Y. C. MA slices by analyzing levels of bioactive compounds, antioxidant activity, and weight loss compared with fresh, directly oven-dried, and blanched samples. Fresh samples had extremely low levels of phenylethanoid glycosides and antioxidant activity. Lower levels of weight loss and higher amounts of soluble sugars, polysaccharides, and dilute ethanol-soluble extracts were found when the slices were steamed rather than blanched. Slices steamed for 5 and 7 min contained significantly (p<0.05) higher amounts of acteoside, isoacteoside, and 2'-acetylacteoside than directly oven-dried samples. However, soluble sugars and dilute ethanol-soluble extracts decreased gradually throughout the steaming process. The concentration of polysaccharides fluctuated during the steaming process. The steaming time had a consistent effect on antioxidant properties evaluated by oxygen radical absorbance capacity (ORAC), 2,2-diphenyl-1-picrylhydrazyl free radical scavenging activity (DPPH) and ferric reducing antioxidant property (FRAP), showing a significant increase and reaching 108.62, 23.08, and 11.68 micromoles Trolox per mass of fresh slice (μmol TE/g FW), respectively. The present results suggest that fresh-cut C. deserticola can be subjected to approximately 5-7 min of steaming to improve phenylethanoid glycoside levels and antioxidant activity, while still preserving the amounts of soluble sugars, polysaccharides, and dilute ethanol-soluble extracts. These results would help to improve the production process for fresh-cut Chinese medicines, and increase the understanding of their associated health benefits.

STEAM Enacted: A Case Study of a Middle School Teacher Implementing STEAM Instructional Practices

ERIC Educational Resources Information Center

Herro, Danielle; Quigley, Cassie

2016-01-01

This paper examines the implementation practices of a 6th grade middle school teacher enacting STEAM (science, technology, engineering, art and math) teaching in his classroom after participating in a 45-hour STEAM professional development. Case study is used to detail the process, successes, and challenges. Project-based learning, technology…

Thermodynamic equilibrium calculations of dimethyl ether steam reforming and dimethyl ether hydrolysis

NASA Astrophysics Data System (ADS)

Semelsberger, Troy A.; Borup, Rodney L.

The production of a hydrogen-rich fuel-cell feed by dimethyl ether (DME) steam reforming was investigated using calculations of thermodynamic equilibrium as a function of steam-to-carbon ratio (0.00-4.00), temperature (100-600 °C), pressure (1-5 atm), and product species. Species considered were acetone, acetylene, carbon dioxide, carbon monoxide, dimethyl ether, ethane, ethanol, ethylene, formaldehyde, formic acid, hydrogen, isopropanol, methane, methanol, methyl-ethyl ether, n-propanol and water. Thermodynamic equilibrium calculations of DME steam reforming indicate complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide at temperatures greater than 200 °C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure ( P = 1 atm). Increasing the operating pressure shifts the equilibrium toward the reactants; increasing the pressure from 1 to 5 atm decreases the conversion of dimethyl ether from 99.5 to 76.2%. The trend of thermodynamically stable products in decreasing mole fraction is methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol-formaldehyde, formic acid, and acetylene were not observed. Based on the equilibrium calculations, the optimal processing conditions for dimethyl ether steam reforming occur at a steam-to-carbon ratio of 1.50, a pressure of 1 atm, and a temperature of 200 °C. These thermodynamic equilibrium calculations show dimethyl ether processed with steam will produce hydrogen-rich fuel-cell feeds—with hydrogen concentrations exceeding 70%. The conversion of dimethyl ether via hydrolysis (considering methanol as the only product) is limited by thermodynamic equilibrium. Equilibrium conversion increases with temperature and steam-to-carbon ratio. A maximum dimethyl ether conversion of 62% is achieved at a steam-to-carbon ratio of 5.00 and a processing temperature of 600 °C.

Downhole steam generator using low-pressure fuel and air supply

DOEpatents

Fox, R.L.

1981-01-07

For tertiary oil recovery, an apparatus for downhole steam generation is designed in which water is not injected directly onto the flame in the combustor, the combustion process is isolated from the reservoir pressure, the fuel and oxidant are supplied to the combustor at relatively low pressures, and the hot exhaust gases is prevented from entering the earth formation but is used to preheat the fuel and oxidant and water. The combustion process is isolated from the steam generation process. (DLC)

Dual Rate Adaptive Control for an Industrial Heat Supply Process Using Signal Compensation Approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chai, Tianyou; Jia, Yao; Wang, Hong

The industrial heat supply process (HSP) is a highly nonlinear cascaded process which uses a steam valve opening as its control input, the steam flow-rate as its inner loop output and the supply water temperature as its outer loop output. The relationship between the heat exchange rate and the model parameters, such as steam density, entropy, and fouling correction factor and heat exchange efficiency are unknown and nonlinear. Moreover, these model parameters vary in line with steam pressure, ambient temperature and the residuals caused by the quality variations of the circulation water. When the steam pressure and the ambient temperaturemore » are of high values and are subjected to frequent external random disturbances, the supply water temperature and the steam flow-rate would interact with each other and fluctuate a lot. This is also true when the process exhibits unknown characteristic variations of the process dynamics caused by the unexpected changes of the heat exchange residuals. As a result, it is difficult to control the supply water temperature and the rates of changes of steam flow-rate well inside their targeted ranges. In this paper, a novel compensation signal based dual rate adaptive controller is developed by representing the unknown variations of dynamics as unmodeled dynamics. In the proposed controller design, such a compensation signal is constructed and added onto the control signal obtained from the linear deterministic model based feedback control design. Such a compensation signal aims at eliminating the unmodeled dynamics and the rate of changes of the currently sample unmodeled dynamics. A successful industrial application is carried out, where it has been shown that both the supply water temperature and the rate of the changes of the steam flow-rate can be controlled well inside their targeted ranges when the process is subjected to unknown variations of its dynamics.« less

Investigation of Redox Metal Oxides for Carbonaceous Fuel Conversion and CO2 Capture

NASA Astrophysics Data System (ADS)

Galinsky, Nathan Lee

The chemical looping combustion (CLC) process uses metal oxides, also referred to as oxygen carriers, in a redox scheme for conversion of carbonaceous fuels into a concentrated stream of CO2 and steam while also producing heat and electricity. The unique redox scheme of CLC allows CO2 capture with minimal energy penalty. The CLC process performance greatly depends on the oxygen carrier that is chosen. To date, more than 1000 oxygen carriers have been developed for chemical-looping processes using metal oxides containing first-row transition metals. Oxygen carriers are typically mixed with an inert ceramic support to improve their overall mechanical stability and recyclability. This study focuses on design of (i) iron oxide oxygen carriers for conversion of gaseous carbonaceous fuels and (ii) development of perovskite CaMnO 3-d with improved stability and redox properties for conversion of solid fuels. Iron oxide is cheap and environmentally benign. However, it suffers from low activity with carbonaceous fuels due partially to the low ionic conductivity of iron oxides. In order to address the low activity of iron-oxide-based oxygen carriers, support addition has been shown to lower the energy barrier of oxygen anion transport within the oxygen carrier. This work adds a mixed-ionic-and-electronic-conductor (MIEC) support to iron oxide to help facilitate O2- transport inside the lattice of iron oxide. The MIEC-supported iron oxide is compared to commonly used supports including TiO2 and Al2O 3 and the pure ionic conductor support yttria-stabilized zirconia (YSZ) for conversion of different carbonaceous fuels and hydrogen. Results show that the MIEC-supported iron oxide exhibits up to 70 times higher activity than non-MIEC-supported iron oxides for methane conversion. The MIEC supported iron oxide also shows good recyclability with only minor agglomeration and carbon formation observed. The effect of support-iron oxide synergies is further investigated to understand other physical and chemical properties that lead to highly active and recyclable oxygen carriers. Perovskite and fluorite-structured MIEC supports are tested for conversion of methane. The perovskite supported iron oxides exhibit higher activity and stability resulting from the high mixed conductivity of the support. Fluorite-structured CeO2 oxygen carriers deactivated by 75% after 10 redox cycles. This deactivation was attributed to agglomeration of iron oxide. The agglomeration was determined to occur due to Fe x+ transport during the oxidation step leading to high content of Fe on the surface of the oxygen carrier. Besides the MIEC supports, inert MgAl2O4 supported iron oxide is observed to activate in methane. The activation is attributed to carbon formation causing physical degradation of the oxygen carrier and leading to higher surface area and porosity. To achieve high activity with solid fuels, chemical looping with oxygen uncoupling (CLOU) is commonly used. This process uses oxygen carriers with high PO2 that allows the oxygen carrier to release a portion of their lattice oxygen as gaseous oxygen. In turn, the gaseous oxygen can react with solid fuel particles at a higher rate than the lattice oxygen. CaMnO 3 perovskite oxygen carriers offer high potential for CLOU. However, pure CaMnO3 suffers from long-term recyclability and sulfur poisoning. Addition of A-site (Ba and Sr) and B-site (Fe, Ni, Co, Al, and V) dopants are used to improve the performance of the base CaMnO3 oxygen carrier. Sr (A-site) and Fe (B-site) exhibit high compatibility with the base perovskite structure. Both dopants observe oxygen uncoupling properties up to 200°C below that of pure CaMnO3. Additionally, the doped structures also exhibit higher stability at high temperatures (>1000°C) and during redox cycles. The doped oxygen carriers also demonstrate significantly improved activity for coal char conversion.

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST

DOE Office of Scientific and Technical Information (OSTI.GOV)

BANNING DL

2010-08-03

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required.more » The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.« less

Study on loading coefficient in steam explosion process of corn stalk.

PubMed

Sui, Wenjie; Chen, Hongzhang

2015-03-01

The object of this work was to evaluate the effect of loading coefficient on steam explosion process and efficacy of corn stalk. Loading coefficient's relation with loading pattern and material property was first revealed, then its effect on transfer process and pretreatment efficacy of steam explosion was assessed by established models and enzymatic hydrolysis tests, respectively, in order to propose its optimization strategy for improving the process economy. Results showed that loading coefficient was mainly determined by loading pattern, moisture content and chip size. Both compact loading pattern and low moisture content improved the energy efficiency of steam explosion pretreatment and overall sugar yield of pretreated materials, indicating that they are desirable to improve the process economy. Pretreatment of small chip size showed opposite effects in pretreatment energy efficiency and enzymatic hydrolysis performance, thus its optimization should be balanced in investigated aspects according to further techno-economical evaluation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Pretreatment efficiency and structural characterization of rice straw by an integrated process of dilute-acid and steam explosion for bioethanol production.

PubMed

Chen, Wen-Hua; Pen, Ben-Li; Yu, Ching-Tsung; Hwang, Wen-Song

2011-02-01

The combined pretreatment of rice straw using dilute-acid and steam explosion followed by enzymatic hydrolysis was investigated and compared with acid-catalyzed steam explosion pretreatment. In addition to measuring the chemical composition, including glucan, xylan and lignin content, changes in rice straw features after pretreatment were investigated in terms of the straw's physical properties. These properties included crystallinity, surface area, mean particle size and scanning electron microscopy imagery. The effect of acid concentration on the acid-catalyzed steam explosion was studied in a range between 1% and 15% acid at 180°C for 2 min. We also investigated the influence of the residence time of the steam explosion in the combined pretreatment and the optimum conditions for the dilute-acid hydrolysis step in order to develop an integrated process for the dilute-acid and steam explosion. The optimum operational conditions for the first dilute-acid hydrolysis step were determined to be 165°C for 2 min with 2% H(2)SO(4) and for the second steam explosion step was to be carried out at 180°C for 20 min; this gave the most favorable combination in terms of an integrated process. We found that rice straw pretreated by the dilute-acid/steam explosions had a higher xylose yield, a lower level of inhibitor in the hydrolysate and a greater degree of enzymatic hydrolysis; this resulted in a 1.5-fold increase in the overall sugar yield when compared to the acid-catalyzed steam explosion. Copyright © 2010 Elsevier Ltd. All rights reserved.

Utilisation of energy from digester gas and sludge incineration at Hamburg's Köhlbrandhöft WWTP.

PubMed

Thierbach, R D; Hanssen, H

2002-01-01

At Hamburg's Köhlbrandhöft WWTP the demand for external energy supply is minimised by state of the art sludge treatment. The sludge is subjected to thickening, anaerobic digestion, dewatering, drying and incineration. The digester gas is used in a combined gas and steam turbine process. The sludge incineration also produces steam, which is also used in the steam turbine that follows the gas turbine. The turbines produce electricity, partially expanded steam is used for the sludge drying process. Heat from the condensation of vapours from sludge drying is used to heat the anaerobic digesters. The overall process requires no external heat or fuel and produces 60% of the WWTP's electricity demand.

Engineering and economic analysis for the utilization of geothermal fluids in a cane sugar processing plant. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Humme, J.T.; Tanaka, M.T.; Yokota, M.H.

1979-07-01

The purpose of this study was to determine the feasibility of geothermal resource utilization at the Puna Sugar Company cane sugar processing plant, located in Keaau, Hawaii. A proposed well site area was selected based on data from surface exploratory surveys. The liquid dominated well flow enters a binary thermal arrangement, which results in an acceptable quality steam for process use. Hydrogen sulfide in the well gases is incinerated, leaving sulfur dioxide in the waste gases. The sulfur dioxide in turn is recovered and used in the cane juice processing at the sugar factory. The clean geothermal steam from themore » binary system can be used directly for process requirements. It replaces steam generated by the firing of the waste fibrous product from cane sugar processing. The waste product, called bagasse, has a number of alternative uses, but an evaluation clearly indicated it should continue to be employed for steam generation. This steam, no longer required for process demands, can be directed to increased electric power generation. Revenues gained by the sale of this power to the utility, in addition to other savings developed through the utilization of geothermal energy, can offset the costs associated with hydrothermal utilization.« less

Identification of abiotic and biotic reductive dechlorination in a chlorinated ethene plume after thermal source remediation by means of isotopic and molecular biology tools

NASA Astrophysics Data System (ADS)

Badin, Alice; Broholm, Mette M.; Jacobsen, Carsten S.; Palau, Jordi; Dennis, Philip; Hunkeler, Daniel

2016-09-01

Thermal tetrachloroethene (PCE) remediation by steam injection in a sandy aquifer led to the release of dissolved organic carbon (DOC) from aquifer sediments resulting in more reduced redox conditions, accelerated PCE biodegradation, and changes in microbial populations. These changes were documented by comparing data collected prior to the remediation event and eight years later. Based on the premise that dual C-Cl isotope slopes reflect ongoing degradation pathways, the slopes associated with PCE and TCE suggest the predominance of biotic reductive dechlorination near the source area. PCE was the predominant chlorinated ethene near the source area prior to thermal treatment. After thermal treatment, cDCE became predominant. The biotic contribution to these changes was supported by the presence of Dehalococcoides sp. DNA (Dhc) and Dhc targeted rRNA close to the source area. In contrast, dual C-Cl isotope analysis together with the almost absent VC 13C depletion in comparison to cDCE 13C depletion suggested that cDCE was subject to abiotic degradation due to the presence of pyrite, possible surface-bound iron (II) or reduced iron sulphides in the downgradient part of the plume. This interpretation is supported by the relative lack of Dhc in the downgradient part of the plume. The results of this study show that thermal remediation can enhance the biodegradation of chlorinated ethenes, and that this effect can be traced to the mobilisation of DOC due to steam injection. This, in turn, results in more reduced redox conditions which favor active reductive dechlorination and/or may lead to a series of redox reactions which may consecutively trigger biotically induced abiotic degradation. Finally, this study illustrates the valuable complementary application of compound-specific isotopic analysis combined with molecular biology tools to evaluate which biogeochemical processes are taking place in an aquifer contaminated with chlorinated ethenes.

Steam drum design for direct steam generation

NASA Astrophysics Data System (ADS)

Willwerth, Lisa; Müller, Svenja; Krüger, Joachim; Succo, Manuel; Feldhoff, Jan Fabian; Tiedemann, Jörg; Pandian, Yuvaraj; Krüger, Dirk; Hennecke, Klaus

2017-06-01

For the direct steam generation in solar fields, the recirculation concept has been demonstrated in several installations. Water masses in the solar field vary during transient phases, such as passing clouds. The volume of the steam drum can serve as a buffer during such transients by taking in excess water and providing water storage. The saturated steam mass flow to the superheating section or the consumer can be maintained almost constant during short transients; therefore the steam drum plays a key role for constant steam supply. Its buffer effect depends on the right sizing of the steam drum for the prevailing situations. Due to missing experiences, steam drums have been sized under conservative assumptions and are thereby usually oversized. With this paper, experiences on the steam drum of the 5 MWel TSE1 power plant are discussed for optimized future plant design. The results are also of relevance for process heat installations, in which saturated steam is produced by the solar field.

Trace metals related to historical iron smelting at Hopewell Furnace National Historic Site, Berks and Chester Counties, Pennsylvania

USGS Publications Warehouse

Sloto, Ronald A.

2011-01-01

Iron ore containing elevated concentrations of trace metals was smelted at Hopewell Furnace during its 113 years of operation (1771-1883). The ore used at Hopewell Furnace was obtained from iron mines within 5 miles of the furnace. The iron-ore deposits were formed about 200 million years ago and contain abundant magnetite, the primary iron mineral, and accessory minerals enriched in arsenic, cobalt, copper, lead, and other metals. Hopewell Furnace, built by Mark Bird during 1770-71, was one of the last of the charcoal-burning, cold-blast iron furnaces operated in Pennsylvania. The most productive years for Hopewell Furnace were from 1830 to 1837. Castings were the most profitable product, especially the popular Hopewell Stove. More than 80,000 stoves were cast at Hopewell, which produced as many as 23 types and sizes of cooking and heating stoves. Beginning in the 1840s, the iron industry shifted to large-scale, steam-driven coke and anthracite furnaces. Independent rural enterprises like Hopewell could no longer compete when the iron and steel industries consolidated in urban manufacturing centers. The furnace ceased operation in 1883 (Kurjack, 1954). The U.S. Geological Survey (USGS), in cooperation with the National Park Service, completed a study at Hopewell Furnace National Historic Site (NHS) in Berks and Chester Counties, Pennsylvania, to determine the fate of toxic trace metals, such as arsenic, cobalt, and lead, released into the environment during historical iron-smelting operations. The results of the study, conducted during 2008-10, are presented in this fact sheet.

Syngas production by high temperature steam/CO2 coelectrolysis using solid oxide electrolysis cells.

PubMed

Chen, Xinbing; Guan, Chengzhi; Xiao, Guoping; Du, Xianlong; Wang, Jian-Qiang

2015-01-01

High temperature (HT) steam/CO2 coelectrolysis with solid oxide electrolysis cells (SOECs) using the electricity and heat generated from clean energies is an important alternative for syngas production without fossil fuel consumption and greenhouse gas emissions. Herein, reaction characteristics and the outlet syngas composition of HT steam/CO2 coelectrolysis under different operating conditions, including distinct inlet gas compositions and electrolysis current densities, are systematically studied at 800 °C using commercially available SOECs. The HT coelectrolysis process, which has comparable performance to HT steam electrolysis, is more active than the HT CO2 electrolysis process, indicating the important contribution of the reverse water-gas shift reaction in the formation of CO. The outlet syngas composition from HT steam/CO2 coelectrolysis is very sensitive to the operating conditions, indicating the feasibility of controlling the syngas composition by varying these conditions. Maximum steam and CO2 utilizations of 77% and 76% are achieved at 1.0 A cm(-2) with an inlet gas composition of 20% H2/40% steam/40% CO2.

A Model for Generation of Martian Surface Dust, Soil and Rock Coatings: Physical vs. Chemical Interactions, and Palagonitic Plus Hydrothermal Alteration

NASA Technical Reports Server (NTRS)

Bishop, J. L.; Murchie, S.; Pieters, C.; Zent, A.

1999-01-01

This model is one of many possible scenarios to explain the generation of the current surface material on Mars using chemical, magnetic and spectroscopic data from Mars and geologic analogs from terrestrial sites. One basic premise is that there are physical and chemical interactions of the atmospheric dust particles and that these two processes create distinctly different results. Physical processes distribute dust particles on rocks, forming physical rock coatings, and on the surface between rocks forming soil units; these are reversible processes. Chemical reactions of the dust/soil particles create alteration rinds on rock surfaces or duricrust surface units, both of which are relatively permanent materials. According to this model the mineral components of the dust/soil particles are derived from a combination of "typical" palagonitic weathering of volcanic ash and hydrothermally altered components, primarily from steam vents or fumeroles. Both of these altered materials are composed of tiny particles, about 1 micron or smaller, that are aggregates of silicates and iron oxide/oxyhydroxide/sulfate phases. Additional information is contained in the original extended abstract.

Equations for calculating the properties of dissociated steam

NASA Astrophysics Data System (ADS)

Aminov, R. Z.; Gudym, A. A.

2017-08-01

The equations of state for dissociated steam have been developed in the temperature and pressure ranges of 1250-2300 K and 0.01-10.00 MPa for calculating thermodynamic processes in thermal power units operating on high-temperature steam. These equations are based on the property tables for dissociated steam derived at a reference temperature of 0 K. It is assumed that the initial substance is steam, the dissociation of which—in accordance with the most likely chemical reactions—results in formation of molecules of hydrogen, oxygen, steam, hydroxyl, and atoms of oxygen and hydrogen. Differential thermodynamic correlations, considering a change in the chemical potential and the composition of the mixture, during the steam dissociation are used. A reference temperature of 0.01°C used in the calculation of parameters of nondissociated steam has been adopted to predict processes in thermal power units without matching the reference temperatures and to account for transformation of dissociated steam into its usual form for which there is the international system of equations with the water triple point of 0.01°C taken as the reference. In the investigated region, the deviation of dissociated steam properties from those of nondissociated steam, which increases with decreasing the pressure or increasing the temperature, was determined. For a pressure of 0.02 MPa and a temperature of 2200 K, these deviations are 512 kJ/kg for the enthalpy, 0.2574 kJ/(kg K) for the entropy, and 3.431 kJ/(kg K) for the heat capacity at constant pressure. The maximum deviation of the dissociated steam properties calculated by the developed equations from the handbook values that these equations are based on does not exceed 0.03-0.05%.

Dynamic underground stripping: steam and electric heating for in situ decontamination of soils and groundwater

DOEpatents

Daily, W.D.; Ramirez, A.L.; Newmark, R.L.; Udell, K.; Buetnner, H.M.; Aines, R.D.

1995-09-12

A dynamic underground stripping process removes localized underground volatile organic compounds from heterogeneous soils and rock in a relatively short time. This method uses steam injection and electrical resistance heating to heat the contaminated underground area to increase the vapor pressure of the contaminants, thus speeding the process of contaminant removal and making the removal more complete. The injected steam passes through the more permeable sediments, distilling the organic contaminants, which are pumped to the surface. Large electrical currents are also applied to the contaminated area, which heat the impermeable subsurface layers that the steam has not penetrated. The condensed and vaporized contaminants are withdrawn by liquid pumping and vacuum extraction. The steam injection and electrical heating steps are repeated as necessary. Geophysical imaging methods can be used to map the boundary between the hot, dry, contamination-free underground zone and the cool, damp surrounding areas to help monitor the dynamic stripping process. 4 figs.

Dynamic underground stripping: steam and electric heating for in situ decontamination of soils and groundwater

DOEpatents

Daily, William D.; Ramirez, Abelardo L.; Newmark, Robin L.; Udell, Kent; Buetnner, Harley M.; Aines, Roger D.

1995-01-01

A dynamic underground stripping process removes localized underground volatile organic compounds from heterogeneous soils and rock in a relatively short time. This method uses steam injection and electrical resistance heating to heat the contaminated underground area to increase the vapor pressure of the contaminants, thus speeding the process of contaminant removal and making the removal more complete. The injected steam passes through the more permeable sediments, distilling the organic contaminants, which are pumped to the surface. Large electrical currents are also applied to the contaminated area, which heat the impermeable subsurface layers that the steam has not penetrated. The condensed and vaporized contaminants are withdrawn by liquid pumping and vacuum extraction. The steam injection and electrical heating steps are repeated as necessary. Geophysical imaging methods can be used to map the boundary between the hot, dry, contamination-free underground zone and the cool, damp surrounding areas to help monitor the dynamic stripping process.

Evaluation of control over the microbiological contamination of carcasses in a lamb carcass dressing process operated with or without pasteurizing treatment.

PubMed

Milios, K; Mataragas, M; Pantouvakis, A; Drosinos, E H; Zoiopoulos, P E

2011-03-30

The aim of this study was to quantify the hygienic status of a lamb slaughterhouse by means of multivariate statistical analysis, to demonstrate how the microbiological data could be exploited to improve the lamb slaughter process by constructing control charts and to evaluate the potential effect of an intervention step such as steam application on the microbiological quality of lamb carcasses. Results showed that pelt removal and evisceration were hygienically uncontrolled. TVC and Enterobacteriaceae progressively increased from the stage 'after pelt removal of hind and forelegs/before final pulling' to the stage 'after evisceration/before pluck removal' thus indicating possible deposition of microorganisms during these operations. It seems that the processing stages of freshly produced carcasses were better distinguished by Enterobacteriaceae, with evisceration contributing mostly to the final Enterobacteriaceae counts. Application of steam during the lamb slaughter process reduced microbial counts without adverse effects on the organoleptic characteristics of the carcasses. Moreover, the construction of control charts showed that decontamination with steam contributed to the maintenance of an in control process compared to that before the application of steam, suggesting the potential use of steam as an intervention step during the lamb slaughter process. Copyright © 2011 Elsevier B.V. All rights reserved.

Steam thermolysis of tire shreds: modernization in afterburning of accompanying gas with waste steam

NASA Astrophysics Data System (ADS)

Kalitko, V. A.

2010-03-01

On the basis of experience in the commercial operation of tire-shred steam thermolysis in EnresTec Inc. (Taiwan) producing high-grade commercial carbon, liquid pyrolysis fuel, and accompanying fuel gas by this method, we have proposed a number of engineering solutions and calculated-analytical substantiations for modernization and intensification of the process by afterburning the accompanying gas with waste steam condensable in the scrubber of water gas cleaning of afterburning products. The condensate is completely freed of the organic pyrolysis impurities and the necessity of separating it from the liquid fuel, as is the case with the active process, is excluded.

Developing an energy efficient steam reforming process to produce hydrogen from sulfur-containing fuels

NASA Astrophysics Data System (ADS)

Simson, Amanda

Hydrogen powered fuel cells have the potential to produce electricity with higher efficiency and lower emissions than conventional combustion technology. In order to realize the benefits of a hydrogen fuel cell an efficient method to produce hydrogen is needed. Currently, over 90% of hydrogen is produced from the steam reforming of natural gas. However, for many applications including fuel cell vehicles, the use of a liquid fuel rather than natural gas is desirable. This work investigates the feasibility of producing hydrogen efficiently by steam reforming E85 (85% ethanol/15% gasoline), a commercially available sulfur-containing transportation fuel. A Rh-Pt/SiO2-ZrO2 catalyst has demonstrated good activity for the E85 steam reforming reaction. An industrial steam reforming process is often run less efficiently, with more water and at higher temperatures, in order to prevent catalyst deactivation. Therefore, it is desirable to develop a process that can operate without catalyst deactivation at more energy efficient conditions. In this study, the steam reforming of a sulfur-containing fuel (E85) was studied at near stoichiometric steam/carbon ratios and at 650C, conditions at which catalyst deactivation is normally measured. At these conditions the catalyst was found to be stable steam reforming a sulfur-free E85. However, the addition of low concentrations of sulfur significantly deactivated the catalyst. The presence of sulfur in the fuel caused catalyst deactivation by promoting ethylene which generates surface carbon species (coke) that mask catalytic sites. The amount of coke increased during time on stream and became increasingly graphitic. However, the deactivation due to both sulfur adsorption and coke formation was reversible with air treatment at 650°C. However, regenerations were found to reduce the catalyst life. Air regenerations produce exotherms on the catalyst surface that cause structural changes to the catalyst. During regenerations the accessibility of the precious metal particles is reduced which causes the catalyst to deactivate more rapidly during subsequent steam reforming cycles. Changes to the carrier morphology also occur at these conditions. Regenerating the catalyst before significant deactivation is measured can improve the stability of the catalyst. Thus a process with preemptive controlled air regenerations is proposed in order to run a steam reforming process with sulfur containing fuels.

METHANE STEAM REACTION OVER NICKEL CATALYSTS IN THE HYNOL PROCESS

EPA Science Inventory

The report discusses the reaction of methane-steam over nickel catalysts in the Hynol process, a process that uses biomass and natural gas as feedstocks to maximize methanol yields and minimize greenhouse gas emissions. EPA's APPCD has established a laboratory in which to conduct...

Production of hydrogen from biomass by catalytic steam reforming of fast pyrolysis oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Czernik, S.; Wang, D.; Chornet, E.

1998-08-01

Hydrogen is the prototype of the environmentally cleanest fuel of interest for power generation using fuel cells and for transportation. The thermochemical conversion of biomass to hydrogen can be carried out through two distinct strategies: (a) gasification followed by water-gas shift conversion, and (b) catalytic steam reforming of specific fractions derived from fast pyrolysis and aqueous/steam processes of biomass. This paper presents the latter route that begins with fast pyrolysis of biomass to produce bio-oil. This oil (as a whole or its selected fractions) can be converted to hydrogen via catalytic steam reforming followed by a water-gas shift conversion step.more » Such a process has been demonstrated at the bench scale using model compounds, poplar oil aqueous fraction, and the whole pyrolysis oil with commercial Ni-based steam reforming catalysts. Hydrogen yields as high as 85% have been obtained. Catalyst initial activity can be recovered through regeneration cycles by steam or CO{sub 2} gasification of carbonaceous deposits.« less

Experimental research of heterogeneous nuclei in superheated steam

NASA Astrophysics Data System (ADS)

Bartoš, Ondřej; Kolovratník, Michal; Šmíd, Bohuslav; Hrubý, Jan

2016-03-01

A mobile steam expansion chamber has been developed to investigate experimentally homogeneous and heterogeneous nucleation processes in steam, both in the laboratory and at power plants using the steam withdrawn from the steam turbine. The purpose of the device is to provide new insight into the physics of nonequilibrium wet steam formation, which is one of the factors limiting the efficiency and reliability of steam turbines. The expanded steam or a mixture of steam with a non-condensable gas rapidly expands in the expansion chamber. Due to adiabatic cooling, the temperature drops below the dew point of the steam at a given pressure. When reaching a sufficiently high supersaturation, droplets are nucleated. By tuning the supersaturation in the so-called nucleation pulse, particles of various size ranges can be activated. This fact is used in the present study to measure the aerosol particles present in the air. Homogeneous nucleation was negligible in this case. The experiment demonstrates the functionality of the device, data acquisition system and data evaluation methods.

Steam trap monitor

DOEpatents

Ryan, M.J.

1987-05-04

A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

Detailed partial load investigation of a thermal energy storage concept for solar thermal power plants with direct steam generation

NASA Astrophysics Data System (ADS)

Seitz, M.; Hübner, S.; Johnson, M.

2016-05-01

Direct steam generation enables the implementation of a higher steam temperature for parabolic trough concentrated solar power plants. This leads to much better cycle efficiencies and lower electricity generating costs. For a flexible and more economic operation of such a power plant, it is necessary to develop thermal energy storage systems for the extension of the production time of the power plant. In the case of steam as the heat transfer fluid, it is important to use a storage material that uses latent heat for the storage process. This leads to a minimum of exergy losses during the storage process. In the case of a concentrating solar power plant, superheated steam is needed during the discharging process. This steam cannot be superheated by the latent heat storage system. Therefore, a sensible molten salt storage system is used for this task. In contrast to the state-of-the-art thermal energy storages within the concentrating solar power area of application, a storage system for a direct steam generation plant consists of a latent and a sensible storage part. Thus far, no partial load behaviors of sensible and latent heat storage systems have been analyzed in detail. In this work, an optimized fin structure was developed in order to minimize the costs of the latent heat storage. A complete system simulation of the power plant process, including the solar field, power block and sensible and latent heat energy storage calculates the interaction between the solar field, the power block and the thermal energy storage system.

Investigations of structural transformation within metal (austenite chromium-manganese steel) at the external surface of steam superheating tubes

NASA Astrophysics Data System (ADS)

Bogachev, V. A.; Pshechenkova, T. P.; Shumovskaya, M. A.

2016-04-01

The elemental composition of an altered layer at the external surface of a steam superheating tube of grade DI59 steel is investigated after long-term operation. It is shown that the layer is located between a scale and a matrix and depleted by silicon, manganese, copper, and chromium with the maximum oxidizer affinity, enriched by iron and nickel to 90%, and mainly composed of the α-Fe phase (ferrite) with the ferromagnetic properties. The layer formed as a result of selective oxidation and diffusion from the matrix into the metal scale with the less standard free energy of the formation of sulfides and oxides. A magnetic ferrite meter is used in the experimental investigation of the layer evolution by testing grade DI59 steel for heat resistance in air environment at temperatures of 585, 650, and 700°C for 15 × 103 h; creep at a temperature of 750°C and a stress of 60 MPa; and long-term strength at temperatures of 700 and 750°C and stresses of from 30 to 80 MPa. Specimens for tests are made of tubes under as-received conditions. The relationship between the ferrite phase content in the surface metal layer and the temperature and time of test is determined. The dependence is developed to evaluate the equivalent temperature for operation of the external surface of steam superheating tubes using data of magnetic ferritometry. It is shown that operation temperatures that are determined by the ferrite phase content and the σ phase concentration in the metal structure of steam superheating tubes with the significant operating time are close. It is proposed to use magnetic ferritometry for revelation of thermal nonuniformity and worst tubes of steam superheaters of HPP boilers.

Desulfurizing Coal With an Alkali Treatment

NASA Technical Reports Server (NTRS)

Ravindram, M.; Kalvinskas, J. J.

1987-01-01

Experimental coal-desulfurization process uses alkalies and steam in fluidized-bed reactor. With highly volatile, high-sulfur bituminous coal, process removed 98 percent of pyritic sulfur and 47 percent of organic sulfur. Used in coal liquefaction and in production of clean solid fuels and synthetic liquid fuels. Nitrogen or steam flows through bed of coal in reactor. Alkalies react with sulfur, removing it from coal. Nitrogen flow fluidizes bed while heating or cooling; steam is fluidizing medium during reaction.

Can bread processing conditions alter glycaemic response?

PubMed

Lau, Evelyn; Soong, Yean Yean; Zhou, Weibiao; Henry, Jeyakumar

2015-04-15

Bread is a staple food that is traditionally made from wheat flour. This study aimed to compare the starch digestibility of western baked bread and oriental steamed bread. Four types of bread were prepared: western baked bread (WBB) and oriental steamed bread (OSB), modified baked bread (MBB) made with the OSB recipe and WBB processing, and modified steamed bread (MSB) made with the WBB recipe and OSB processing. MBB showed the highest starch digestibility in vitro, followed by WBB, OSB and MSB. A similar trend was observed for glycaemic response in vivo. MBB, WBB, OSB and MSB had a glycaemic index of 75±4, 71±5, 68±5 and 65±4, respectively. Processing differences had a more pronounced effect on starch digestibility in bread, and steamed bread was healthier in terms of glycaemic response. The manipulation of processing conditions could be an innovative route to alter the glycaemic response of carbohydrate-rich foods. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effects of acid impregnated steam explosion process on xylose recovery and enzymatic conversion of cellulose in corncob.

PubMed

Fan, Xiaoguang; Cheng, Gang; Zhang, Hongjia; Li, Menghua; Wang, Shizeng; Yuan, Qipeng

2014-12-19

Corncob residue is a cellulose-rich byproduct obtained from industrial xylose production via dilute acid hydrolysis processes. Enzymatic hydrolysis of cellulose in acid hydrolysis residue of corncob (AHRC) is often less efficient without further pretreatment. In this work, the process characteristics of acid impregnated steam explosion were studied in conjunction with a dilute acid process, and their effects on physiochemical changes and enzymatic saccharification of corncob residue were compared. With the acid impregnated steam explosion process, both higher xylose recovery and higher cellulose conversion were obtained. The maximum conversion of cellulose in acid impregnated steam explosion residue of corncob (ASERC) reached 85.3%, which was 1.6 times higher than that of AHRC. Biomass compositional analysis showed similar cellulose and lignin content in ASERC and AHRC. XRD analysis demonstrated comparable crystallinity of ASERC and AHRC. The improved enzymatic hydrolysis efficiency was attributed to higher porosity in ASERC, measured by mercury porosimetry. Copyright © 2014 Elsevier Ltd. All rights reserved.

Potential applications for amylose inclusion complexes produced by steam jet cooking

USDA-ARS?s Scientific Manuscript database

Steam jet cooking is a commercially scalable method of thermomechanically processing starch for many applications. Previous studies at NCAUR have revealed the specific effects of heat and shear on various starch types cooked under different steam flow, pressure, and slurry flow conditions. Starch-...

40 CFR 429.80 - Applicability; description of the wood preserving-steam subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Applicability; description of the wood... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS TIMBER PRODUCTS PROCESSING POINT SOURCE CATEGORY Wood Preserving Steam Subcategory § 429.80 Applicability; description of the wood preserving—steam subcategory...

40 CFR 429.80 - Applicability; description of the wood preserving-steam subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Applicability; description of the wood... (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS TIMBER PRODUCTS PROCESSING POINT SOURCE CATEGORY Wood Preserving Steam Subcategory § 429.80 Applicability; description of the wood preserving—steam subcategory...

Developing a Conceptual Model of STEAM Teaching Practices

ERIC Educational Resources Information Center

Quigley, Cassie F.; Herro, Dani; Jamil, Faiza M.

2017-01-01

STEAM, where the "A" represents arts and humanities, is considered a transdisciplinary learning process that has the potential to increase diverse participation in science, technology, engineering, and math (STEM) fields. However, a well-defined conceptual model that clearly articulates essential components of the STEAM approach is…

Investigating steam penetration using thermometric methods in dental handpieces with narrow internal lumens during sterilizing processes with non-vacuum or vacuum processes.

PubMed

Winter, S; Smith, A; Lappin, D; McDonagh, G; Kirk, B

2017-12-01

Dental handpieces are required to be sterilized between patient use. Vacuum steam sterilization processes with fractionated pre/post-vacuum phases or unique cycles for specified medical devices are required for hollow instruments with internal lumens to assure successful air removal. Entrapped air will compromise achievement of required sterilization conditions. Many countries and professional organizations still advocate non-vacuum sterilization processes for these devices. To investigate non-vacuum downward/gravity displacement, type-N steam sterilization of dental handpieces, using thermometric methods to measure time to achieve sterilization temperature at different handpiece locations. Measurements at different positions within air turbines were undertaken with thermocouples and data loggers. Two examples of widely used UK benchtop steam sterilizers were tested: a non-vacuum benchtop sterilizer (Little Sister 3; Eschmann, Lancing, UK) and a vacuum benchtop sterilizer (Lisa; W&H, Bürmoos, Austria). Each sterilizer cycle was completed with three handpieces and each cycle in triplicate. A total of 140 measurements inside dental handpiece lumens were recorded. The non-vacuum process failed (time range: 0-150 s) to reliably achieve sterilization temperatures within the time limit specified by the international standard (15 s equilibration time). The measurement point at the base of the handpiece failed in all test runs (N = 9) to meet the standard. No failures were detected with the vacuum steam sterilization type B process with fractionated pre-vacuum and post-vacuum phases. Non-vacuum downward/gravity displacement, type-N steam sterilization processes are unreliable in achieving sterilization conditions inside dental handpieces, and the base of the handpiece is the site most likely to fail. Copyright © 2017 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

The Nation Builders: A Sesquicentennial History of the Corps of Topographical Engineers, 1838 - 1863

DTIC Science & Technology

1988-06-01

Archimedes ................. 40 John McClellan’s Plan for Cribwork ............ 42 Buffalo Harbor ....................... 43 James D. Graham...Graham’s 1854 report. The screw - pile lighthouse is an example of early iron truss technology. It was devel- oped in England and imported by the Army...While on the West Coast, he invented a fog signal based on a locomotive steam whistle. Air forced through a pipe by the rush of seawater made the

The hydrogen sulfide emissions abatement program at the Geysers Geothermal Power Plant

NASA Technical Reports Server (NTRS)

Allen, G. W.; Mccluer, H. K.

1974-01-01

The scope of the hydrogen sulfide (H2S) abatement program at The Geysers Geothermal Power Plant and the measures currently under way to reduce these emissions are discussed. The Geysers steam averages 223 ppm H2S by weight and after passing through the turbines leaves the plant both through the gas ejector system and by air-stripping in the cooling towers. The sulfide dissolved in the cooling water is controlled by the use of an oxidation catalyst such as an iron salt. The H2S in the low Btu ejector off gases may be burned to sulfur dioxide and scrubbed directly into the circulating water and reinjected into the steam field with the excess condensate. Details are included concerning the disposal of the impure sulfur, design requirements for retrofitting existing plants and modified plant operating procedures. Discussion of future research aimed at improving the H2S abatement system is also included.

Thermodynamic analyses of a biomass-coal co-gasification power generation system.

PubMed

Yan, Linbo; Yue, Guangxi; He, Boshu

2016-04-01

A novel chemical looping power generation system is presented based on the biomass-coal co-gasification with steam. The effects of different key operation parameters including biomass mass fraction (Rb), steam to carbon mole ratio (Rsc), gasification temperature (Tg) and iron to fuel mole ratio (Rif) on the system performances like energy efficiency (ηe), total energy efficiency (ηte), exergy efficiency (ηex), total exergy efficiency (ηtex) and carbon capture rate (ηcc) are analyzed. A benchmark condition is set, under which ηte, ηtex and ηcc are found to be 39.9%, 37.6% and 96.0%, respectively. Furthermore, detailed energy Sankey diagram and exergy Grassmann diagram are drawn for the entire system operating under the benchmark condition. The energy and exergy efficiencies of the units composing the system are also predicted. Copyright © 2016 Elsevier Ltd. All rights reserved.

The effects of steam injection in a sandstone reservoir (Etchegoin Formation), Buena Vista field, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant, C.W.; Reed, A.A.

1991-03-01

At Buena Vista field, California, 120 ft of post-steamflood core, spanning the middle Pliocene Wilhelm Member of the Etchegoin Formation, was taken to assess the influence of stratigraphy on light-oil steamflood (LOSF) processes and to determine what steam-rock reactions occurred and how these affected reservoir properties. High-quality steam (600F (300C)) had been injected ({approximately}1,700 psi) into mixed tidal flat and estuarine facies in an injector well located 55 ft from the cored well. Over a period of 20 months, steam rapidly channeled through a thin ({approximately}7 ft), relatively permeable (1-1,000 md), flaser-bedded sandstone unit. Conductive heating above this permeable unitmore » produced, in the vicinity of the cored well, a 35-ft steam-swept zone (oil saturation = 0), overlain by a 29-ft steam-affected zone in which oil saturation had been reduced to 13%, far below the presteam saturation of 30%. Steam-induced alteration ('artificial diagenesis') of the clay-rich reservoir rock was recognized using SEM, petrography, and X-ray diffraction. Salient dissolution effects were the complete to partial removal of siliceous microfossils, Fe-dolomite, volcanic rock fragments, and labile heavy minerals. The artificial diagenetic effects are first encountered in the basal 6 ft of the 29-ft steam-affected zone. Based on the distribution of the authigenic phases, the authors conclude that the reactions took place, or were at least initiated, in the steam condensate bank ahead of the advancing steam front. Although these changes presumably reduced permeability, the steamflood process was effective in reducing oil saturation to zero in the steam-contacted portion of the reservoir.« less

The use of advanced steam reforming technology for hydrogen production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abbishaw, J.B.; Cromarty, B.J.

1996-12-01

The demand for supplementary hydrogen production in refineries is growing significantly world-wide as environmental legislation concerning cleaner gasoline and diesel fuels is introduced. The main manufacturing method is by steam reforming. The process has been developed both to reduce the capital cost and increase efficiency, reliability and ease of operation. ICI Katalco`s Leading Concept Hydrogen or LCH process continues this process of improvement by replacing the conventional fired steam reformer with a type of heat exchange reformer known as the Gas Heated Reformer or GHR. The GHR was first used in the Leading Concept Ammonia process, LCA at ICI`s manufacturingmore » site at Severnside, England and commissioned in 1988 and later in the Leading Concept Methanol (LCM) process for methanol at Melbourne, Australia and commissioned in 1994. The development of the LCH process follows on from both LCA and LCM processes. This paper describes the development and use of the GHR in steam reforming, and shows how the GHR can be used in LCH. A comparison between the LCH process and a conventional hydrogen plant is given, showing the benefits of the LCH process in certain circumstances.« less

26. Photocopy of diagram (from Bernhardt Skrotzki's Electric GenerationSteam Stations, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

26. Photocopy of diagram (from Bernhardt Skrotzki's Electric Generation--Steam Stations, New York, New York, 1956, figure I-1) THE GENERAL WAY IN WHICH ELECTRICITY IS CREATED THROUGH THE STEAM GENERATION PROCESS - Portland General Electric Company, Station "L", 1841 Southeast Water Street, Portland, Multnomah County, OR

Steaming Clean

ERIC Educational Resources Information Center

Hoverson, Rick

2006-01-01

Schools can provide a cleaner, more healthful school environment by simply combining heat and water. Steam vapor systems use only tap water with no chemicals added. Low-pressure (12 psi to 65 psi) steam vapor sanitizes and deodorizes. This process can then be used safely in many situations, but is especially suited for restrooms and food-service…

PHYSICAL AND OPTICAL PROPERTIES OF STEAM-EXPLODED LASER-PRINTED PAPER

EPA Science Inventory

Laser-printed paper was pulped by the steam-explosion process. A full-factorial experimental design was applied to determine the effects of key operating variables on the properties of steam-exploded pulp. The variables were addition level for pulping chemicals (NaOH and/or Na2SO...

75 FR 45080 - Revisions to the California State Implementation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-02

... revisions concern oxides of nitrogen (NO X ) emissions from boilers, steam generators and process heaters... 1--Submitted Rule Local agency Rule No. Rule title Adopted Submitted SJVUAPCD 4308 Boilers, Steam... regulations that control NO X emissions. Rule 4308 limits NO X and CO emissions from boilers, steam generators...

Investigation of Stainless Steel Corrosion in Ultrahigh-Purity Water and Steam Systems by Surface Analytical Techniques

NASA Astrophysics Data System (ADS)

Dong, Xia; Iacocca, Ronald G.; Bustard, Bethany L.; Kemp, Craig A. J.

2010-02-01

Stainless steel pipes with different degrees of rouging and a Teflon®-coated rupture disc with severe corrosion were thoroughly investigated by combining multiple surface analytical techniques. The surface roughness and iron oxide layer thickness increase with increasing rouge severity, and the chromium oxide layer coexists with the iron oxide layer in samples with various degrees of rouging. Unlike the rouging observed for stainless steel pipes, the fast degradation of the rupture disc was caused by a crevice corrosion environment created by perforations in the protective Teflon coating. This failure analysis clearly shows the highly corrosive nature of ultrapure water used in the manufacture of pharmaceutical products, and demonstrates some of the unexpected corrosion mechanisms that can be encountered in these environments.

Applications of thermal energy storage to process heat storage and recovery in the paper and pulp industry

NASA Technical Reports Server (NTRS)

Carr, J. H.; Hurley, P. J.; Martin, P. J.

1978-01-01

Applications of Thermal Energy Storage (TES) in a paper and pulp mill power house were studied as one approach to the transfer of steam production from fossil fuel boilers to waste fuel of (hog fuel) boilers. Data from specific mills were analyzed, and various TES concepts evaluated for application in the process steam supply system. Constant pressure and variable pressure steam accumulators were found to be the most attractive storage concepts for this application.

Method for increasing steam decomposition in a coal gasification process

DOEpatents

Wilson, Marvin W.

1988-01-01

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Method to prevent/mitigate steam explosions in casting pits

DOEpatents

Taleyarkhan, Rusi P.

1996-01-01

Steam explosions can be prevented or mitigated during a metal casting process by the placement of a perforated flooring system in the casting pit. An upward flow of compressed gas through this perforated flooring system is introduced during the casting process to produce a buffer layer between any spilled molten metal and the cooling water in the reservoir. This buffer layer provides a hydrodynamic layer which acts to prevent or mitigate steam explosions resulting from hot, molten metal being spilled into or onto the cooling water.

Method for increasing steam decomposition in a coal gasification process

DOEpatents

Wilson, M.W.

1987-03-23

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Chemical and Physical Interactions of Martian Surface Material

NASA Astrophysics Data System (ADS)

Bishop, J. L.

1999-09-01

A model of alteration and maturation of the Martian surface material is described involving both chemical and physical interactions. Physical processes involve distribution and mixing of the fine-grained soil particles across the surface and into the atmosphere. Chemical processes include reaction of sulfate, salt and oxidizing components of the soil particles; these agents in the soils deposited on rocks will chew through the rock minerals forming coatings and will bind surface soils together to form duricrust deposits. Formation of crystalline iron oxide/oxyhydroxide minerals through hydrothermal processes and of poorly crystalline and amorphous phases through palagonitic processes both contribute to formation of the soil particles. Chemical and physical alteration of these soil minerals and phases contribute to producing the chemical, magnetic and spectroscopic character of the Martian soil as observed by Mars Pathfinder and Mars Global Surveyor. Minerals such as maghemite/magnetite and jarosite/alunite have been observed in terrestrial volcanic soils near steam vents and may be important components of the Martian surface material. The spectroscopic properties of several terrestrial volcanic soils containing these minerals have been analyzed and evaluated in terms of the spectroscopic character of the surface material on Mars.

Alkali-enhanced steam foam oil recovery process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lau, H.C.

1986-09-02

This patent describes a process in which steam and steam-foaming surfactant are injected into a subterranean reservoir for displacing a relatively acidic oil toward a production location. An improvement is described which consisits of: injecting into the reservoir, at least as soon as at least some portion of the steam is injected, (a) a kind and amount of water soluble, alkaline material effective for ion-exchanging multivalent ions from the reservoir rocks and precipitating compounds containing those ions and for causing the aqueous liquid phase of the injected fluid to form soaps of substantially all of the petroleum acids in themore » reservoir oil, and (b) at least one surfactant arranged for foaming the steam and providing a preformed cosurfactant material capable of increasing the salinity requirement of an aqueous surfactant system in which soaps derived from the reservoir oil comprise a primary surfactant.« less

Gasification of carbonaceous solids

DOEpatents

Coates, Ralph L.

1976-10-26

A process and apparatus for converting coal and other carbonaceous solids to an intermediate heating value fuel gas or to a synthesis gas. A stream of entrained pulverized coal is fed into the combustion stage of a three-stage gasifier along with a mixture of oxygen and steam at selected pressure and temperature. The products of the combustion stage pass into the second or quench stage where they are partially cooled and further reacted with water and/or steam. Ash is solidified into small particles and the formation of soot is suppressed by water/steam injections in the quench stage. The design of the quench stage prevents slag from solidifying on the walls. The products from the quench stage pass directly into a heat recovery stage where the products pass through the tube, or tubes, of a single-pass, shell and tube heat exchanger and steam is generated on the shell side and utilized for steam feed requirements of the process.

Graphical Procedure for Comparing Thermal Death of Bacillus stearothermophilus Spores in Saturated and Superheated Steam

PubMed Central

Shull, James J.; Ernst, Robert R.

1962-01-01

The thermal death curve of dried spores of Bacillus stearothermophilus in saturated steam was characterized by three phases: (i) a sharp initial rise in viable count; (ii) a low rate of death which gradually increased; and (iii) logarithmic death at maximal rate. The first phase was a reflection of inadequate heat activation of the spore population. The second and third phases represented the characteristic thermal death curve of the spores in saturated steam. A jacketed steam sterilizer, equipped with a system for initial evacuation of the chamber, was examined for superheat during normal operation. Measurements of spore inactivation and temperature revealed superheat in surface layers of fabrics being processed in steam at 121 C. The high temperature of the fabric surfaces was attributed to absorption of excess heat energy from superheated steam. The superheated steam was produced at the beginning of the normal sterilizing cycle by transfer of heat from the steam-heated jacket to saturated steam entering the vessel. PMID:13988774

Steam generation by combustion of processed waste fats

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pudel, F.; Lengenfeld, P.

1993-12-31

The use of specially processed waste fats as a fuel oil substitute offers, at attractive costs, an environmentally friendly alternative to conventional disposal like refuse incineration or deposition. For that purpose the processed fat is mixed with EL fuel oil and burned in a standard steam generation plant equipped with special accessories. The measured emission values of the combustion processes are very low.

Trona-enhanced steam foam oil recovery process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lau, H.C.

1988-03-01

In a process in which steam and steam-foaming surfactant are injected into a subterranean reservoir for displacing a relatively acidic oil toward a production location, which process includes injecting into the reservoir, at least as soon as at least some portion of the steam is injected, (a) a kind and amount of water soluble, alkaline material effective for ion-exchanging multivalent ions from the reservoir rocks and precipitating compounds containing those ions and for causing the aqueous liquid phase of the injected fluid to form soaps of substantially all of the petroleum acids in the reservoir oil, and (b) at leastmore » one surfactant arranged for foaming the steam and providing a preformed cosurfactant material capable of increasing the salinity requirement of an aqueous surfactant system in which soaps derived from the reservoir oil comprise a primary surfactant, an improvement is described comprising: using as the water soluble alkaline material, a material consisting essentially of a substantially equal molar mixture of alkali metal carbonates and bicarbonates which is, or is substantially equivalent to, trona.« less

Thermal analysis of heat and power plant with high temperature reactor and intermediate steam cycle

NASA Astrophysics Data System (ADS)

Fic, Adam; Składzień, Jan; Gabriel, Michał

2015-03-01

Thermal analysis of a heat and power plant with a high temperature gas cooled nuclear reactor is presented. The main aim of the considered system is to supply a technological process with the heat at suitably high temperature level. The considered unit is also used to produce electricity. The high temperature helium cooled nuclear reactor is the primary heat source in the system, which consists of: the reactor cooling cycle, the steam cycle and the gas heat pump cycle. Helium used as a carrier in the first cycle (classic Brayton cycle), which includes the reactor, delivers heat in a steam generator to produce superheated steam with required parameters of the intermediate cycle. The intermediate cycle is provided to transport energy from the reactor installation to the process installation requiring a high temperature heat. The distance between reactor and the process installation is assumed short and negligable, or alternatively equal to 1 km in the analysis. The system is also equipped with a high temperature argon heat pump to obtain the temperature level of a heat carrier required by a high temperature process. Thus, the steam of the intermediate cycle supplies a lower heat exchanger of the heat pump, a process heat exchanger at the medium temperature level and a classical steam turbine system (Rankine cycle). The main purpose of the research was to evaluate the effectiveness of the system considered and to assess whether such a three cycle cogeneration system is reasonable. Multivariant calculations have been carried out employing the developed mathematical model. The results have been presented in a form of the energy efficiency and exergy efficiency of the system as a function of the temperature drop in the high temperature process heat exchanger and the reactor pressure.

UV-Vis as quantification tool for solubilized lignin following a single-shot steam process.

PubMed

Lee, Roland A; Bédard, Charles; Berberi, Véronique; Beauchet, Romain; Lavoie, Jean-Michel

2013-09-01

In this short communication, UV/Vis was used as an analytical tool for the quantification of lignin concentrations in aqueous mediums. A significant correlation was determined between absorbance and concentration of lignin in solution. For this study, lignin was produced from different types of biomasses (willow, aspen, softwood, canary grass and hemp) using steam processes. Quantification was performed at 212, 225, 237, 270, 280 and 287 nm. UV-Vis quantification of lignin was found suitable for different types of biomass making this a timesaving analytical system that could lead to uses as Process Analytical Tool (PAT) in biorefineries utilizing steam processes or comparable approaches. Copyright © 2013 Elsevier Ltd. All rights reserved.

Thermodynamic equilibrium calculations of hydrogen production from the combined processes of dimethyl ether steam reforming and partial oxidation

NASA Astrophysics Data System (ADS)

Semelsberger, Troy A.; Borup, Rodney L.

Thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the combined processes of dimethyl ether (DME) partial oxidation and steam reforming were investigated as a function of oxygen-to-carbon ratio (0.00-2.80), steam-to-carbon ratio (0.00-4.00), temperature (100 °C-600 °C), pressure (1-5 atm) and product species. Thermodynamically, dimethyl ether processed with air and steam generates hydrogen-rich fuel-cell feeds; however, the hydrogen concentration is less than that for pure DME steam reforming. Results of the thermodynamic processing of dimethyl ether indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 °C, oxygen-to-carbon ratios greater than 0.00 and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure has negligible effects on the hydrogen content. Thermodynamically, dimethyl ether can produce concentrations of hydrogen and carbon monoxide of 52% and 2.2%, respectively, at a temperature of 300 °C, and oxygen-to-carbon ratio of 0.40, a pressure of 1 atm and a steam-to-carbon ratio of 1.50. The order of thermodynamically stable products (excluding H 2, CO, CO 2, DME, NH 3 and H 2O) in decreasing mole fraction is methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol and methyl-ethyl ether; trace amounts of formaldehyde, formic acid and methanol are observed. Ammonia and hydrogen cyanide are also thermodynamically favored products. Ammonia is favored at low temperatures in the range of oxygen-to-carbon ratios of 0.40-2.50 regardless of the steam-to-carbon ratio employed. The maximum ammonia content (i.e., 40%) occurs at an oxygen-to-carbon ratio of 0.40, a steam-to-carbon ratio of 1.00 and a temperature of 100 °C. Hydrogen cyanide is favored at high temperatures and low oxygen-to-carbon ratios with a maximum of 3.18% occurring at an oxygen-to-carbon ratio of 0.40 and a steam-to-carbon ratio of 0.00 in the temperature range of 400 °C-500 °C. Increasing the system pressure shifts the equilibrium toward ammonia and hydrogen cyanide.

IN SITU STEAM ENHANCED RECOVERY PROCESS - HUGHES ENVIRONMENTAL SYSTEMS, INC. - INNOVATIVE TECHNOLOGY EVALUATION REPORT

EPA Science Inventory

This Innovative Technology Evaluation report summarizes the findings of an evaluation of the in situ Steam Enhanced Recovery Process (SERP) operated by Hughes Environmental Systems, Inc. at the Rainbow Disposal facility in Huntington Beach, California. he technology demonstration...

DEMONSTRATION BULLETIN: IN SITU STEAM ENHANCED RECOVERY PROCESS - HUGHES ENVIRONMENTAL SYSTEMS, INC.

EPA Science Inventory

The Steam Enhanced Recovery Process (SERP) is designed to remove volatile compounds such as halogenated solvents and petroleum hydrocarbons, and semi-volatile compounds from contaminated soils in situ. The vapor pressures of most contaminants will increase by the addition of ste...

14. INTERIOR OF ENGINE ROOM, CONTAINING MESTACORLISS CROSSCOMPOUND ENGINE, FOR ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

14. INTERIOR OF ENGINE ROOM, CONTAINING MESTA-CORLISS CROSS-COMPOUND ENGINE, FOR 40" BLOOMING MILL. THIS VIEW HIGHLIGHTS THE CRANK AND 24' DIAMETER FLYWHEEL. THE ENGINE IS A 7,940 HP MESTA-CORLISS CROSS-COMPOUND STEAM ENGINE ITS BORE AND STROKE ARE 32"X84"X60". NOTE FLY BALL GOVERNOR ON ENGINE. MILL DRIVE SHAFT ATTACHED TO PULLEY ON LOCATED ON CRANK. - Republic Iron & Steel Company, Youngstown Works, Blooming Mill & Blooming Mill Engines, North of Poland Avenue, Youngstown, Mahoning County, OH

Microbial safety and overall quality of cantaloupe fresh-cut pieces prepared from whole fruit after wet steam treatment

USDA-ARS?s Scientific Manuscript database

Fresh-cut cantaloupes have been associated with outbreaks of Salmonellosis. Minimally processed fresh-cut fruits have a limited shelf life because of deterioration caused by spoilage microflora and physiological processes. The objectives of this study were to use a wet steam process to 1) reduce ind...

The effect of saturated steam vapor temperature on heat consumption in the process of color modification of acacia wood

NASA Astrophysics Data System (ADS)

Dzurenda, Ladislav

2017-09-01

This paper presents the heat consumption on the process of colour modification of acacia timber with measures 30 x 55 x 500 mm in pressure autoclaves AZ 240 using saturated water steam with temperatures from t = 110 to 140 °C following the regimes of colour homogenisation of I., II. and III. degree. The dependance of the heat consumption normative QTFS on the temparature of saturated water steam in the process of colour homogenisation of acacia timber following these regimes describes the equation: QTFS = 1.1122.t -13.903 kWh.m-3.

Preparation and evaluation of GAC-based iron-containing adsorbents for arsenic removal.

PubMed

Gu, Zhimang; Fang, Jun; Deng, Baolin

2005-05-15

Granular activated carbon-based, iron-containing adsorbents (As-GAC) were developed for effective removal of arsenic from drinking water. Granular activated carbon (GAC) was used primarily as a supporting medium for ferric iron that was impregnated by ferrous chloride (FeCl2) treatment, followed by chemical oxidation. Sodium hypochlorite (NaClO) was the most effective oxidant, and carbons produced from steam activation of lignite were most suitable for iron impregnation and arsenic removal. Two As-GAC materials prepared by FeCl2 treatment (0.025 -0.40 M) of Dacro 20 x 50 and Dacro 20 x 40LI resulted in a maximum impregnated iron of 7.89% for Dacro 20 x 50 and 7.65% for Dacro 20 x 40Ll. Nitrogen adsorption-desorption analyses showed the BET specific surface area, total pore volume, porosity, and average mesoporous diameter all decreased with iron impregnation, indicating that some micropores were blocked. SEM studies with associated EDS indicated that the distribution of iron in the adsorbents was mainly on the edge of As-GAC in the low iron content (approximately 1% Fe) sample but extended to the center at the higher iron content (approximately 6% Fe). When the iron content was > approximately 7%, an iron ring formed at the edge of the GAC particles. No difference in X-ray diffraction patterns was observed between untreated GAC and the one with 4.12% iron, suggesting that the impregnated iron was predominantly in amorphous form. As-GAC could remove arsenic most efficiently when the iron content was approximately 6%; further increases of iron decreased arsenic adsorption. The removal of arsenate occurred in a wide range of pH as examined from 4.4 to 11, but efficiency was decreased when pH was higher than 9.0. The presence of phosphate and silicate could significantly decrease arsenate removal at pH > 8.5, while the effects of sulfate, chloride, and fluoride were minimal. Column studies showed that both As(V) and As(III) could be removed to below 10 microg/L within 6000 empty bed volume when the groundwater containing approximately 50 microg/L of arsenic was treated.

40 CFR 63.441 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... flash steam from the digester or live steam. Closed-vent system means a system that is not open to the... this subpart, including emissions from individual process vents, stacks, open pieces of process... stock chests, and their associated vacuum pumps, filtrate tanks, foam breakers or tanks, and any other...

40 CFR 63.441 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... flash steam from the digester or live steam. Closed-vent system means a system that is not open to the... this subpart, including emissions from individual process vents, stacks, open pieces of process... stock chests, and their associated vacuum pumps, filtrate tanks, foam breakers or tanks, and any other...

40 CFR 63.441 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... flash steam from the digester or live steam. Closed-vent system means a system that is not open to the... this subpart, including emissions from individual process vents, stacks, open pieces of process... stock chests, and their associated vacuum pumps, filtrate tanks, foam breakers or tanks, and any other...

Off-design analysis of a gas turbine powerplant augmented by steam injection using various fuels

NASA Technical Reports Server (NTRS)

Stochl, R. J.

1980-01-01

Results are compared using coal derived low and intermediate heating valve fuel gases and a conventional distillate. The results indicate that steam injection provides substantial increases in both power and efficiency within the available compressor surge margin. The results also indicate that these performance gains are relatively insensitive as to the type of fuel. Also, in a cogeneration application, steam injection could provide some degree of flexibility by varying the split between power and process steam.

Steam Methane Reformation Testing for Air-Independent Solid Oxide Fuel Cell Systems

NASA Technical Reports Server (NTRS)

Mwara, Kamwana N.

2015-01-01

Recently, NASA has been looking into utilizing landers that can be propelled by LOX-CH (sub 4), to be used for long duration missions. Using landers that utilize such propellants, also provides the opportunity to use solid oxide fuel cells as a power option, especially since they are able to process methane into a reactant through fuel reformation. One type of reformation, called steam methane reformation, is a process to reform methane into a hydrogen-rich product by reacting methane and steam (fuel cell exhaust) over a catalyst. A steam methane reformation system could potentially use the fuel cell's own exhaust to create a reactant stream that is hydrogen-rich, and requires less internal reforming of the incoming methane. Also, steam reformation may hold some advantages over other types of reforming, such as partial oxidation (PROX) reformation. Steam reformation does not require oxygen, while up to 25 percent can be lost in PROX reformation due to unusable CO (sub 2) reformation. NASA's Johnson Space Center has conducted various phases of steam methane reformation testing, as a viable solution for in-space reformation. This has included using two different types of catalysts, developing a custom reformer, and optimizing the test system to find the optimal performance parameters and operating conditions.

Heat exchanger for fuel cell power plant reformer

DOEpatents

Misage, Robert; Scheffler, Glenn W.; Setzer, Herbert J.; Margiott, Paul R.; Parenti, Jr., Edmund K.

1988-01-01

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Effect of the presence of oil on foam performance; A field simulation study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Law, D.H.S.; Yang, Z.M.; Stone, T.W.

1992-05-01

This paper describes a field-scale sensitivity study of the effect of the presence of oil on foam performance in a steam-foam-drive process. The 2D field-scale simulation was based on a field pilot in the Karamay formation in Zin-Jiang, China. Numerical results showed that the detrimental effect of oil on the foam performance in field operations is significant. The success of a steam-foam process depended mainly on the ability of the foam to divert steam from the depleted zone.

Method to prevent/mitigate steam explosions in casting pits

DOEpatents

Taleyarkhan, R.P.

1996-12-24

Steam explosions can be prevented or mitigated during a metal casting process by the placement of a perforated flooring system in the casting pit. An upward flow of compressed gas through this perforated flooring system is introduced during the casting process to produce a buffer layer between any spilled molten metal and the cooling water in the reservoir. This buffer layer provides a hydrodynamic layer which acts to prevent or mitigate steam explosions resulting from hot, molten metal being spilled into or onto the cooling water. 3 figs.

The Development and Application of a STEAM Program Based on Traditional Korean Culture

ERIC Educational Resources Information Center

Kim, Hyoungbum; Chae, Dong-Hyun

2016-01-01

The purpose of this research was to develop a STEAM program in the context of teaching and learning a traditional Korean instrument and implement it in a high school class to determine the program's effectiveness. The STEAM program was developed through a continuous consultation process between a development team and external experts, including an…

Effects of press sizes on internal steam pressure during particleboard hot-pressing process

Treesearch

Zhiyong Cai; Michael Birkeland; James M. Wescott; Jane O' Dell; Jerrold E. Winandy

2009-01-01

Internal steam pressure produced during the hot-pressing cycle in particleboard production is critical to the newly developed bond strength that will determine the overall performance of particleboard. The difference between the accumulation of internal steam pressure for small panels made in the laboratory and that of large commercial-sized panels makes it difficult...

Steam trap monitor

DOEpatents

Ryan, Michael J.

1988-01-01

A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

Cyclic steaming in heavy oil diatomite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, M.; Beatty, F.D.

1995-12-31

Chevron currently uses cyclic steaming as a recovery method to produce economically its heavy oil diatomite resource in the Cymric field, San Joaquin Valley, California. A highly instrumented, cyclically steaming well from this field was simulated in this study to delineate important production mechanisms, to optimize operations, and to improve reservoir management. The model was constrained, as much as possible, by the available measured data. Results show that fluid flow from the well to the reservoir is primarily through the hydraulic fracture induced by the injected steam. Parameters with unique importance to modeling cyclic steaming in diatomites are: (1) inducedmore » fracture dimension (length and height), (2) matrix permeability, (3) oil/water capillary pressure, (4) grid size perpendicular to fracture face, and (5) producing bottomhole pressures. Additionally, parameters important for conventional steam injection processes, such as relative permeabilities and injected steam volume, quality, and rate, are important for diatomites also. Oil production rates and steam/oil ratios calculated by this model compare reasonably with field data.« less

Downhole measurements and fluid chemistry of a castle rock steam well, the Geysers, Lake County, California

USGS Publications Warehouse

Truesdell, A.H.; Nathenson, M.; Frye, G.A.

1981-01-01

Wellbore and reservoir processes in a steam well in the Castle Rock field of The Geysers have been studied by means of down-hole pressure and temperature measurements and analyses of ejected water and steam produced under bleed and full flow. Down-hole measurements show that below a vapor zone there is liquid water in the well in pressure equilibrium with reservoir steam at a depth of 2290 m. The progressive decreases, from 1973 to 1977, of pressure and temperature in the vapor zone indicate that wellbore heat loss is high enough to condense a large fraction of the steam inflow. The chemical composition of water ejected from the well is consistent with an origin from wellbore condensation of steam. Calculations using the differences in gas and isotopic compositions between bleed and full-flow steam show that about half of the full-flow steam originated as liquid water in the reservoir and that about 30% of the steam entering the well under bleed was condensed in the wellbore and drained downward. Heat loss calculations are also consistent with this amount of condensation. ?? 1981.

Evaluation of rock/fracture interactions during steam injection through vertical hydrofractures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovscek, A.R.; Johnston, R.M.; Patzek, T.W.

1995-12-31

This paper illustrates the design and results of Shell`s Phase 2 steam drive pilot in the South Belridge Diatomite, Kern County, California. Steam drive on 5/8 acre spacing appears to be an economically viable alternative to waterflooding in the Diatomite; hence, it is being explored as a secondary recovery process. The purpose of the Phase 2 pilot was to demonstrate that steam could be injected across the full Diatomite interval and to quantify reservoir heating and volumetric sweep by steam. In this pilot, two separate, noncommunicating hydrofractures that span the entire Diatomite column (1,110--1,910 ft) are used for injection. Tomore » interpret quantitatively steam drive results the authors propose a computationally simple, high resolution model that captures formation heating due to both steam/hot condensate convection and heat conduction, evolution of formation permeability, and changes in the size and shape of the injection hydrofractures. From this model they obtain formation pressure, temperature, the cumulative steam injection, the dynamics of hydrofractures while they undergo steam injection, and, thus, a history match for the pilot.« less

Effects of gamma-sterilization on the physico-chemical properties of natural sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bank, Tracy L.; Kukkadapu, Ravi K.; Madden, Andrew S.

2008-06-30

A series of experiments were completed to determine the effects of soil sterilization on various soil chemical properties including U(VI) sorption, soil pH, natural organic matter (NOM), cation exchange capacity (CEC), and iron oxidation state. Soils under investigation were a saprolitic sequence of interbedded weathered shale and limestone collected from the Oak Ridge Reservation (ORR). Sediments were sterilized by either steam sterilization at 121oC or by γ-irradiation using a cobalt-60 source. Subsamples of sediments were pretreated with dithionate-citrate-bicarbonate (DCB) and/or H2O2 to remove reducible Fe(III) oxides and NOM. Results from aerobic U(VI) sorption experiments indicated that γ-sterilized sediments sorbed moremore » U(VI) compared to non-sterile sediments. Results from sorption experiments completed using DCB and H2O2-treated samples indicated that the iron oxide and NOM fractions of the sediment accounted for the majority of U(VI) sorption and that γ-irradiation of these phases resulted in increased sorption of U(VI). Mössbauer spectra of γ-sterilized sedimentsdisplayed a decrease in the amount of ferric iron associated with goethite and a small increase in the amount of reduced iron in silicate minerals compared to spectra from non-sterile samples. Our results suggest that sterilization by γ-irradiation induced iron reduction that may have increased sorption of U(VI) on these sediments.« less

A fast response miniature probe for wet steam flow field measurements

NASA Astrophysics Data System (ADS)

Bosdas, Ilias; Mansour, Michel; Kalfas, Anestis I.; Abhari, Reza S.

2016-12-01

Modern steam turbines require operational flexibility due to renewable energies’ increasing share of the electrical grid. Additionally, the continuous increase in energy demand necessitates efficient design of the steam turbines as well as power output augmentation. The long turbine rotor blades at the machines’ last stages are prone to mechanical vibrations and as a consequence time-resolved experimental data under wet steam conditions are essential for the development of large-scale low-pressure steam turbines. This paper presents a novel fast response miniature heated probe for unsteady wet steam flow field measurements. The probe has a tip diameter of 2.5 mm, and a miniature heater cartridge ensures uncontaminated pressure taps from condensed water. The probe is capable of providing the unsteady flow angles, total and static pressure as well as the flow Mach number. The operating principle and calibration procedure are described in the current work and a detailed uncertainty analysis demonstrates the capability of the new probe to perform accurate flow field measurements under wet steam conditions. In order to exclude any data possibly corrupted by droplets’ impact or evaporation from the heating process, a filtering algorithm was developed and implemented in the post-processing phase of the measured data. In the last part of this paper the probe is used in an experimental steam turbine test facility and measurements are conducted at the inlet and exit of the last stage with an average wetness mass fraction of 8.0%.

Conceptual design assessment for the co-firing of bio-refinery supplied lignin project. Quarterly report, July 1--September 30, 2000

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berglund, T.; Ranney, J.T.; Babb, C.L.

2000-10-01

The initial design criteria of the MSW to ethanol facility have been completed along with preliminary site identification and layouts for the processing facility. These items are the first step in evaluating the feasibility of this co-located facility. Pilot facility design and modification are underway for the production and dewatering of the lignin fuel. Major process equipment identification has been completed and several key unit operations will be accomplished on rental equipment. Equipment not available for rental or at TVA has been ordered and facility modification and shakedown will begin in October. The study of the interface and resulting impactsmore » on the TVA Colbert facility are underway. The TVA Colbert fossil plant is fully capable of providing a reliable steam supply for the proposed Masada waste processing facility. The preferred supply location in the Colbert steam cycle has been identified as have possible steam pipeline routes to the Colbert boundary. Additional analysis is underway to fully predict the impact of the steam supply on Colbert plant performance and to select a final steam pipeline route.« less

Effects of water states on steam explosion of lignocellulosic biomass.

PubMed

Sui, Wenjie; Chen, Hongzhang

2016-01-01

The work aimed to identify the complexity and roles of water states in steam explosion process of corn stalk to enhance the treatment efficiency. Results showed that two main water states with different mobility existed in corn stalk and influenced steam explosion treatment. By correlating dynamic water states data to feedstock mechanical properties and treatment process characteristics, the bound water being the excellent plasticizer that reduced the mechanical strength of fibers by over 30%, was conducive to treatment; while, the free water presenting buffering effects in treatment by hindering heat transfer which was reflected by the increase of temperature rising time by 1.29 folds and steam consumption by 2.18 folds, was not conducive. The distinguished point of these two waters was fiber saturated point. By considering treatment efficacy and energy consumption, the significance of fiber saturated point was highlighted as the optimal water states for steam explosion of corn stalk. Copyright © 2015 Elsevier Ltd. All rights reserved.

Estimation of water level and steam temperature using ensemble Kalman filter square root (EnKF-SR)

NASA Astrophysics Data System (ADS)

Herlambang, T.; Mufarrikoh, Z.; Karya, D. F.; Rahmalia, D.

2018-04-01

The equipment unit which has the most vital role in the steam-powered electric power plant is boiler. Steam drum boiler is a tank functioning to separate fluida into has phase and liquid phase. The existence in boiler system has a vital role. The controlled variables in the steam drum boiler are water level and the steam temperature. If the water level is higher than the determined level, then the gas phase resulted will contain steam endangering the following process and making the resulted steam going to turbine get less, and the by causing damages to pipes in the boiler. On the contrary, if less than the height of determined water level, the resulted height will result in dry steam likely to endanger steam drum. Thus an error was observed between the determined. This paper studied the implementation of the Ensemble Kalman Filter Square Root (EnKF-SR) method in nonlinear model of the steam drum boiler equation. The computation to estimate the height of water level and the temperature of steam was by simulation using Matlab software. Thus an error was observed between the determined water level and the steam temperature, and that of estimated water level and steam temperature. The result of simulation by Ensemble Kalman Filter Square Root (EnKF-SR) on the nonlinear model of steam drum boiler showed that the error was less than 2%. The implementation of EnKF-SR on the steam drum boiler r model comprises of three simulations, each of which generates 200, 300 and 400 ensembles. The best simulation exhibited the error between the real condition and the estimated result, by generating 400 ensemble. The simulation in water level in order of 0.00002145 m, whereas in the steam temperature was some 0.00002121 kelvin.

The Isolation of Nanofibre Cellulose from Oil Palm Empty Fruit Bunch Via Steam Explosion and Hydrolysis with HCl 10%

NASA Astrophysics Data System (ADS)

Gea, S.; Zulfahmi, Z.; Yunus, D.; Andriayani, A.; Hutapea, Y. A.

2018-03-01

Cellulose nanofibrils were obtained from oil palm empty fruit bunch using steam explosion and hydrolized with 10% solution of HCl. Steam explosion coupled with acid hydrolysis pretreatment on the oil palm empty fruit bunch was very effective in the depolymerization and defibrillation process of the fibre to produce fibers in nanodimension. Structural analysis of steam exploded fibers was determined by Fourier Transform Infrared (FT-IR) spectroscopy. Thermal stability of cellulose measured using image analysis software image J. Characterization of the fibers by TEM and SEM displayed that fiber diameter decreases with mechanical-chemical treatment and final nanofibril size was 20-30 nm. FT-IR and TGA data confirmed the removal of hemicellulose and lignin during the chemical treatment process.

A computational approach to real-time image processing for serial time-encoded amplified microscopy

NASA Astrophysics Data System (ADS)

Oikawa, Minoru; Hiyama, Daisuke; Hirayama, Ryuji; Hasegawa, Satoki; Endo, Yutaka; Sugie, Takahisa; Tsumura, Norimichi; Kuroshima, Mai; Maki, Masanori; Okada, Genki; Lei, Cheng; Ozeki, Yasuyuki; Goda, Keisuke; Shimobaba, Tomoyoshi

2016-03-01

High-speed imaging is an indispensable technique, particularly for identifying or analyzing fast-moving objects. The serial time-encoded amplified microscopy (STEAM) technique was proposed to enable us to capture images with a frame rate 1,000 times faster than using conventional methods such as CCD (charge-coupled device) cameras. The application of this high-speed STEAM imaging technique to a real-time system, such as flow cytometry for a cell-sorting system, requires successively processing a large number of captured images with high throughput in real time. We are now developing a high-speed flow cytometer system including a STEAM camera. In this paper, we describe our approach to processing these large amounts of image data in real time. We use an analog-to-digital converter that has up to 7.0G samples/s and 8-bit resolution for capturing the output voltage signal that involves grayscale images from the STEAM camera. Therefore the direct data output from the STEAM camera generates 7.0G byte/s continuously. We provided a field-programmable gate array (FPGA) device as a digital signal pre-processor for image reconstruction and finding objects in a microfluidic channel with high data rates in real time. We also utilized graphics processing unit (GPU) devices for accelerating the calculation speed of identification of the reconstructed images. We built our prototype system, which including a STEAM camera, a FPGA device and a GPU device, and evaluated its performance in real-time identification of small particles (beads), as virtual biological cells, owing through a microfluidic channel.

[Steam cautery of the cornea in microbial keratitis].

PubMed

Maier, P; Birnbaum, F; Reinhard, T

2008-01-01

In some cases topical antimicrobial treatment of microbial keratitis or corneal ulcers remains unsuccessful, with increasing infiltration of the corneal stroma. In this situation the steam cautery procedure developed by Karl Wessely in 1911 can lead to rapid healing of the inflammatory process, avoiding further corneal surgery. In this article we describe the steam cautery technique and discuss its indications for microbial keratitis.

A Fresnel collector process heat experiment at Capitol Concrete Products

NASA Technical Reports Server (NTRS)

Hauger, J. S.

1981-01-01

An experiment is planned, conducted and evaluated to determine the feasibility of using a Power Kinetics' Fresnel concentrator to provide process heat in an industrial environment. The plant provides process steam at 50 to 60 psig to two autoclaves for curing masonry blocks. When steam is not required, the plant preheats hot water for later use. A second system is installed at the Jet Propulsion Laboratory parabolic dish test site for hardware validation and experiment control. Experiment design allows for the extrapolation of results to varying demands for steam and hot water, and includes a consideration of some socio-technical factors such as the impact on production scheduling of diurnal variations in energy availability.

[Steam and air co-injection in removing TCE in 2D-sand box].

PubMed

Wang, Ning; Peng, Sheng; Chen, Jia-Jun

2014-07-01

Steam and air co-injection is a newly developed and promising soil remediation technique for non-aqueous phase liquids (NAPLs) in vadose zone. In this study, in order to investigate the mechanism of the remediation process, trichloroethylene (TCE) removal using steam and air co-injection was carried out in a 2-dimensional sandbox with different layered sand structures. The results showed that co-injection perfectly improved the "tailing" effect compared to soil vapor extraction (SVE), and the remediation process of steam and air co-injection could be divided into SVE stage, steam strengthening stage and heat penetration stage. Removal ratio of the experiment with scattered contaminant area was higher and removal speed was faster. The removal ratios from the two experiments were 93.5% and 88.2%, and the removal periods were 83.9 min and 90.6 min, respectively. Steam strengthened the heat penetration stage. The temperature transition region was wider in the scattered NAPLs distribution experiment, which reduced the accumulation of TCE. Slight downward movement of TCE was observed in the experiment with TCE initially distributed in a fine sand zone. And such downward movement of TCE reduced the TCE removal ratio.

Quality comparison of continuous steam sterilization segmented-flow aseptic processing versus conventional canning of whole and sliced mushrooms.

PubMed

Anderson, N M; Walker, P N

2011-08-01

This study was carried out to investigate segmented-flow aseptic processing of particle foods. A pilot-scale continuous steam sterilization unit capable of producing shelf stable aseptically processed whole and sliced mushrooms was developed. The system utilized pressurized steam as the heating medium to achieve high temperature-short time processing conditions with high and uniform heat transfer that will enable static temperature penetration studies for process development. Segmented-flow technology produced a narrower residence time distribution than pipe-flow aseptic processing; thus, whole and sliced mushrooms were processed only as long as needed to achieve the target F₀  = 7.0 min and were not overcooked. Continuous steam sterilization segmented-flow aseptic processing produced shelf stable aseptically processed mushrooms of superior quality to conventionally canned mushrooms. When compared to conventionally canned mushrooms, aseptically processed yield (weight basis) increased 6.1% (SD = 2.9%) and 6.6% (SD = 2.2%), whiteness (L) improved 3.1% (SD = 1.9%) and 4.7% (SD = 0.7%), color difference (ΔE) improved 6.0% (SD = 1.3%) and 8.5% (SD = 1.5%), and texture improved 3.9% (SD = 1.7%) and 4.6% (SD = 4.2%), for whole and sliced mushrooms, respectively. Segmented-flow aseptic processing eliminated a separate blanching step, eliminated the unnecessary packaging of water and promoted the use of bag-in-box and other versatile aseptic packaging methods. Segmented-flow aseptic processing is capable of producing shelf stable aseptically processed particle foods of superior quality to a conventionally canned product. This unique continuous steam sterilization process eliminates the need for a separate blanching step, reduces or eliminates the need for a liquid carrier, and promotes the use of bag-in-box and other versatile aseptic packaging methods. © 2011 Institute of Food Technologists®

40 CFR Table 1 to Subpart Ddddd of... - Emission Limits for New or Reconstructed Boilers and Process Heaters

Code of Federal Regulations, 2013 CFR

2013-07-01

.... HCl 2.2E-02 lb per MMBtu of heat input 2.5E-02 lb per MMBtu of steam output or 0.28 lb per MWh For... basis corrected to 3 percent oxygen, 30-day rolling average) 1.2E-01 lb per MMBtu of steam output or 1.5... per MMBtu of steam output or 4.2E-01 lb per MWh; or (2.7E-05 lb per MMBtu of steam output or 3.7E-04...

40 CFR 61.305 - Reporting and recordkeeping.

Code of Federal Regulations, 2012 CFR

2012-07-01

... unit or process heater with a design heat input capacity of 44 MW (150 × 106 BTU/hr) or greater is used... or other flare design (i.e., steam-assisted, air-assisted or nonassisted), all visible emission... temperature of the steam generating unit or process heater with a design heat input capacity of less than 44...

40 CFR 61.305 - Reporting and recordkeeping.

Code of Federal Regulations, 2014 CFR

2014-07-01

... unit or process heater with a design heat input capacity of 44 MW (150 × 106 BTU/hr) or greater is used... or other flare design (i.e., steam-assisted, air-assisted or nonassisted), all visible emission... temperature of the steam generating unit or process heater with a design heat input capacity of less than 44...

40 CFR 61.305 - Reporting and recordkeeping.

Code of Federal Regulations, 2010 CFR

2010-07-01

... unit or process heater with a design heat input capacity of 44 MW (150 × 106 BTU/hr) or greater is used... or other flare design (i.e., steam-assisted, air-assisted or nonassisted), all visible emission... temperature of the steam generating unit or process heater with a design heat input capacity of less than 44...

40 CFR 61.305 - Reporting and recordkeeping.

Code of Federal Regulations, 2013 CFR

2013-07-01

... unit or process heater with a design heat input capacity of 44 MW (150 × 106 BTU/hr) or greater is used... or other flare design (i.e., steam-assisted, air-assisted or nonassisted), all visible emission... temperature of the steam generating unit or process heater with a design heat input capacity of less than 44...

40 CFR 61.305 - Reporting and recordkeeping.

Code of Federal Regulations, 2011 CFR

2011-07-01

... unit or process heater with a design heat input capacity of 44 MW (150 × 106 BTU/hr) or greater is used... or other flare design (i.e., steam-assisted, air-assisted or nonassisted), all visible emission... temperature of the steam generating unit or process heater with a design heat input capacity of less than 44...

Microbial safety and overall quality of cantaloupe fresh-cut pieces prepared from whole cantaloupe after wet steam treatment

USDA-ARS?s Scientific Manuscript database

Fresh-cut cantaloupes have been associated with outbreaks of Salmonelosis disease and the minimally processed fresh-cut fruits have a limited shelf life because of deterioration caused by spoilage microflora and physiological processes. In this study, we evaluated the effect of minimal wet steam t...

Progress in ethanol production from corn kernel by applying cooking pre-treatment.

PubMed

Voca, Neven; Varga, Boris; Kricka, Tajana; Curic, Duska; Jurisic, Vanja; Matin, Ana

2009-05-01

In order to improve technological properties of corn kernel for ethanol production, samples were treated with a hydrothermal pre-treatment of cooking (steaming), prior to drying. Two types of cooking process parameters were applied; steam pressure of 0.5 bars during a 10 min period, and steam pressure of 1.5 bars during a 30 min period. Afterwards, samples were dried at four different temperatures, 70, 90, 110 and 130 degrees C. Control sample was also submitted to the aforementioned drying parameters. Since the results showed that starch utilization, due to the gelatinization process, was considerably higher in the samples pre-treated before the ethanol production process, it was found that the cooking treatment had a positive effect on ethanol yield from corn kernel. Therefore, the highest ethanol yield was found in the corn kernel samples cooked for 30 min at steam pressure 1.5 bars and dried at 130 degrees C. Due to the similarity of processes used for starch fermentation, introduction of cooking pre-treatment will not significantly increase the overall ethanol production costs, whereas it will result in significantly higher ethanol yield.

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR BENCH-SCALE REFORMER TREATABILITY STUDIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

BANNING DL

2011-02-11

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Bench-Scale Reforming testing. The type, quantity, and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluidized bed steam reformer. A determination of the adequacy of the fluidized bed steam reformer process to treat Hanford tank waste is required.more » The initial step in determining the adequacy of the fluidized bed steam reformer process is to select archived waste samples from the 222-S Laboratory that will be used in a bench scale tests. Analyses of the selected samples will be required to confirm the samples meet the shipping requirements and for comparison to the bench scale reformer (BSR) test sample selection requirements.« less

Effect of Steam Deactivation Severity of ZSM-5 Additives on LPG Olefins Production in the FCC Process.

PubMed

Gusev, Andrey A; Psarras, Antonios C; Triantafyllidis, Konstantinos S; Lappas, Angelos A; Diddams, Paul A

2017-10-21

ZSM-5-containing catalytic additives are widely used in oil refineries to boost light olefin production and improve gasoline octanes in the Fluid Catalytic Cracking (FCC) process. Under the hydrothermal conditions present in the FCC regenerator (typically >700 °C and >8% steam), FCC catalysts and additives are subject to deactivation. Zeolites (e.g., Rare Earth USY in the base catalyst and ZSM-5 in Olefins boosting additives) are prone to dealumination and partial structural collapse, thereby losing activity, micropore surface area, and undergoing changes in selectivity. Fresh catalyst and additives are added at appropriate respective levels to the FCC unit on a daily basis to maintain overall targeted steady-state (equilibrated) activity and selectivity. To mimic this process under accelerated laboratory conditions, a commercial P/ZSM-5 additive was hydrothermally equilibrated via a steaming process at two temperatures: 788 °C and 815 °C to simulate moderate and more severe equilibration industrial conditions, respectively. n -Dodecane was used as probe molecule and feed for micro-activity cracking testing at 560 °C to determine the activity and product selectivity of fresh and equilibrated P-doped ZSM-5 additives. The fresh/calcined P/ZSM-5 additive was very active in C 12 cracking while steaming limited its activity, i.e., at catalyst-to-feed (C/F) ratio of 1, about 70% and 30% conversion was obtained with the fresh and steamed additives, respectively. A greater activity drop was observed upon increasing the hydrothermal deactivation severity due to gradual decrease of total acidity and microporosity of the additives. However, this change in severity did not result in any selectivity changes for the LPG (liquefied petroleum gas) olefins as the nature (Brønsted-to-Lewis ratio) of the acid/active sites was not significantly altered upon steaming. Steam deactivation of ZSM-5 had also no significant effect on aromatics formation which was enhanced at higher conversion levels. Coke remained low with both fresh and steam-deactivated P/ZSM-5 additives.

A novel cleaning process for industrial production of xylose in pilot scale from corncob by using screw-steam-explosive extruder.

PubMed

Zhang, Hong-Jia; Fan, Xiao-Guang; Qiu, Xue-Liang; Zhang, Qiu-Xiang; Wang, Wen-Ya; Li, Shuang-Xi; Deng, Li-Hong; Koffas, Mattheos A G; Wei, Dong-Sheng; Yuan, Qi-Peng

2014-12-01

Steam explosion is the most promising technology to replace conventional acid hydrolysis of lignocellulose for biomass pretreatment. In this paper, a new screw-steam-explosive extruder was designed and explored for xylose production and lignocellulose biorefinery at the pilot scale. We investigated the effect of different chemicals on xylose yield in the screw-steam-explosive extrusion process, and the xylose production process was optimized as followings: After pre-impregnation with sulfuric acid at 80 °C for 3 h, corncob was treated at 1.55 MPa with 9 mg sulfuric acid/g dry corncob (DC) for 5.5 min, followed by countercurrent extraction (3 recycles), decoloration (activated carbon dosage 0.07 g/g sugar, 75 °C for 40 min), and ion exchange (2 batches). Using this process, 3.575 kg of crystal xylose was produced from 22 kg corncob, almost 90 % of hemicellulose was released as monomeric sugar, and only a small amount of by-products was released (formic acid, acetic acid, fural, 5-hydroxymethylfurfural, and phenolic compounds were 0.17, 1.14, 0.53, 0.19, and 1.75 g/100 g DC, respectively). All results indicated that the screw-steam-explosive extrusion provides a more effective way to convert hemicellulose into xylose and could be an alternative method to traditional sulfuric acid hydrolysis process for lignocellulose biorefinery.

Pilot-scale steam aging of steel slags.

PubMed

Kumar, Praveen; Satish Kumar, D; Marutiram, K; Prasad, Smr

2017-06-01

Solid waste management has gained importance in the steel industry in view of rising environmental concerns and scarcity of raw materials. In spite of significant developments in reducing waste generation and development of recycling technologies, steel slag is still a concern for the industry as most of it is dumped. Steel slag is similar to stone aggregates in strength, but its volumetric instability in contact with water hinders its application as aggregates in construction. A part of steel slag is normally exposed to rain and sun for natural aging and stabilization for months before use. The natural aging process is slow and time-consuming, and thus restricts its usage. The steelmaking slag can be put to effective use as coarse aggregates if quickly aged and stabilized by pre-reacting the free expansive phases. In the present work, a new process has been developed to accelerate the steel slag aging process using steam in a 30 T pilot scale facility. The setup has controlled steam injection, distribution, and process control system for steam, temperature, flow, and pressure. Steam percolates through the minute pores in the slag lumps and hydrates the expansive free lime and MgO phases, making it stable. The aged slag expansion properties were tested using an in-house developed expansion testing apparatus. The process is capable of reducing the expansion of steel slag from 3.5% to <1.5% (standard requirement) in 7 days. The aged steel slag is currently being used in roads at JSW Steel, Vijayanagar Works.

Voluntary GHG reduction of industrial sectors in Taiwan.

PubMed

Chen, Liang-Tung; Hu, Allen H

2012-08-01

The present paper describes the voluntary greenhouse gas (GHG) reduction agreements of six different industrial sectors in Taiwan, as well as the fluorinated gases (F-gas) reduction agreement of the semiconductor and Liquid Crystal Display (LCD) industries. The operating mechanisms, GHG reduction methods, capital investment, and investment effectiveness are also discussed. A total of 182 plants participated in the voluntary energy saving and GHG reduction in six industrial sectors (iron and steel, petrochemical, cement, paper, synthetic fiber, and textile printing and dyeing), with 5.35 Mt reduction from 2004 to 2008, or 33% higher than the target goal (4.02 Mt). The reduction accounts for 1.6% annual emission or 7.8% during the 5-yr span. The petrochemical industry accounts for 49% of the reduction, followed by the cement sector (21%) and the iron and steel industry (13%). The total investment amounted to approximately USD 716 million, in which, the majority of the investment went to the modification of the manufacturing process (89%). The benefit was valued at around USD 472 million with an average payback period of 1.5 yr. Moreover, related energy saving was achieved through different approaches, e.g., via electricity (iron and steel), steam and oil consumption (petrochemical) and coal usage (cement). The cost for unit CO(2) reduction varies per industry, with the steel and iron industrial sector having the highest cost (USD 346 t(-1) CO(2)) compared with the average cost of the six industrial sectors (USD 134 t(-1) CO(2)). For the semiconductor and Thin-Film Transistor LCD industries, F-gas emissions were reduced from approximately 4.1 to about 1.7 Mt CO(2)-eq, and from 2.2 to about 1.1 Mt CO(2)-eq, respectively. Incentive mechanisms for participation in GHG reduction are also further discussed. Copyright © 2012 Elsevier Ltd. All rights reserved.

Case study on the orientation of phaco hand pieces during steam sterilization processes.

PubMed

van Doornmalen Gomez Hoyos, J P C M; van Wezel, R A C; van Doornmalen, H W J M

2015-05-01

Steam sterilization is an essential part of infection prevention. The literature shows that sterilization of medical instruments containing channels is not trivial. Phaco hand pieces have a simple configuration: a device contains a channel with a constant radius. No literature was found indicating whether the sterilization conditions on the inner surface of a phaco hand piece are influenced by the orientation of the hand piece. To determine whether the orientation of a phaco hand piece influences the results of a sterilization process of this device. A qualitative case study, including experiments, is performed with a protocolled combination of steam sterilizer, process, phaco hand piece, orientation of the phaco hand piece, and wrapping. In this specific case, the orientation of the hand piece influenced the result of the steam sterilization process; in vertically (upright) oriented phaco hand pieces with free water drainage, sterilization conditions are reproducibly established. In the same process, in horizontally oriented or vertically oriented hand pieces without free drainage, these conditions are not established in a reproducible way. In the investigated combination of sterilizer, process, load, loading pattern and wrapping, phaco hand pieces have to be oriented vertically (upright) with free water drainage to obtain steam sterilization conditions on the inner surface. It is likely that instruments with comparable configuration and dimensions will yield comparable results. It is therefore recommended that this issue is considered during the development of medical instruments and during performance qualifications of such instruments. Copyright © 2015 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lower, Mark D; Christopher, Timothy W; Oland, C Barry

The Facilities and Operations (F&O) Directorate is sponsoring a continuous process improvement (CPI) program. Its purpose is to stimulate, promote, and sustain a culture of improvement throughout all levels of the organization. The CPI program ensures that a scientific and repeatable process exists for improving the delivery of F&O products and services in support of Oak Ridge National Laboratory (ORNL) Management Systems. Strategic objectives of the CPI program include achieving excellence in laboratory operations in the areas of safety, health, and the environment. Identifying and promoting opportunities for achieving the following critical outcomes are important business goals of the CPImore » program: improved safety performance; process focused on consumer needs; modern and secure campus; flexibility to respond to changing laboratory needs; bench strength for the future; and elimination of legacy issues. The Steam Pressure-Reducing Station (SPRS) Safety and Energy Efficiency Improvement Project, which is under the CPI program, focuses on maintaining and upgrading SPRSs that are part of the ORNL steam distribution network. This steam pipe network transports steam produced at the ORNL steam plant to many buildings in the main campus site. The SPRS Safety and Energy Efficiency Improvement Project promotes excellence in laboratory operations by (1) improving personnel safety, (2) decreasing fuel consumption through improved steam system energy efficiency, and (3) achieving compliance with applicable worker health and safety requirements. The SPRS Safety and Energy Efficiency Improvement Project being performed by F&O is helping ORNL improve both energy efficiency and worker safety by modifying, maintaining, and repairing SPRSs. Since work began in 2006, numerous energy-wasting steam leaks have been eliminated, heat losses from uninsulated steam pipe surfaces have been reduced, and deficient pressure retaining components have been replaced. These improvements helped ORNL reduce its overall utility costs by decreasing the amount of fuel used to generate steam. Reduced fuel consumption also decreased air emissions. These improvements also helped lower the risk of burn injuries to workers and helped prevent shrapnel injuries resulting from missiles produced by pressurized component failures. In most cases, the economic benefit and cost effectiveness of the SPRS Safety and Energy Efficiency Improvement Project is reflected in payback periods of 1 year or less.« less

Downhole steam generator using low pressure fuel and air supply

DOEpatents

Fox, Ronald L.

1983-01-01

An apparatus for generation of steam in a borehole for penetration into an earth formation wherein a spiral, tubular heat exchanger is used in the combustion chamber to isolate the combustion process from the water being superheated for conversion into steam. The isolation allows combustion of a relatively low pressure oxidant and fuel mixture for generating high enthalpy steam. The fuel is preheated by feedback of combustion gases from the top of the combustion chamber through a fuel preheater chamber. The hot exhaust gases of combustion at the bottom of the combustion chamber, after flowing over the heat exchanger enter an exhaust passage and pipe. The exhaust pipe is mounted inside the water supply line heating the water flowing into the heat exchanger. After being superheated in the heat exchanger, the water is ejected through an expansion nozzle and converts into steam prior to penetration into the earth formation. Pressure responsive doors are provided at a steam outlet downstream of the nozzle and close when the steam pressure is lost due to flameout.

Processing Maple Syrup with a Vapor Compression Distiller: An Economic Analysis

Treesearch

Lawrence D. Garrett

1977-01-01

A test of vapor compression distillers for processing maple syrup revealed that: (1) vapor compression equipment tested evaporated 1 pound of water with .047 pounds of steam equivalent (electrical energy); open-pan evaporators of similar capacity required 1.5 pounds of steam equivalent (oil energy) to produce 1 pound of water; (2) vapor compression evaporation produced...

Extraction and recovery of pectic fragments from citrus processing waste for co-production with ethanol

USDA-ARS?s Scientific Manuscript database

Steam treatment of citrus processing waste (CPW) at 160°C followed by a rapid decompression (steam explosion) at either pH 2.8 or 4.5 provides an efficient and rapid fragmentation of protopectin in CPW and renders a large fraction of fragmented pectins, arabinans, galactans and arabinogalactans solu...

A novel nano-Ni/SiO2 catalyst for hydrogen production from steam reforming of ethanol.

PubMed

Wu, Chunfei; Williams, Paul T

2010-08-01

Catalytic steam reforming of ethanol has been regarded as a promising way to produce hydrogen. However, catalytic deactivation is a key problem in the process. In this paper, a novel nano-Ni/SiO2 catalyst was prepared by a simple sol-gel method and compared to catalysts prepared by an impregnation method in relation to the steam reforming ethanol process. Good Ni dispersion and high BET surface areas (>700 m2 g(-1)) were obtained for sol-gel catalysts, whereas only 1 m2 g(-1) surface area was obtained for the Ni/SiO2 impregnation catalyst. The results of catalytic steam reforming of ethanol showed that about twice of the hydrogen production was produced with the Ni/SiO2 catalyst prepared by sol-gel (around 0.2 g h(-1)) compared with that prepared by impregnation (around 0.1 g h(-1)). The analysis of the used catalysts showed that 10Ni/SiO2-B and 20Ni/SiO2-B presented the highest stability, while other catalysts were fragmented into small pieces after the reforming process, especially the catalysts prepared by impregnation. A novel catalyst has been produced that has been shown to be effective in the production of hydrogen from the steam reforming of ethanol.

Coproduction of volatiles and metals from extraterrestrial materials

NASA Technical Reports Server (NTRS)

Lewis, John S.

1991-01-01

Two main efforts in support of the general goals of SERC/culpr are presented. Investigations of processes for the coproduction of metals from extra-terrestrial materials in conjunction with plausible schemes for oxygen extraction continue. The principal emphasis was on the extraction and purification of iron from the ilmenite reduction process for oxygen, from the cathode metal deposits made in the magma electrolysis process for oxygen, and from native ferrous metal alloys on the moon and asteroids. All work on the separation and purification of ferrous metals was focussed upon the gaseous carbonyl process, a scheme that involves only temperatures attainable by passive thermal control. The exploration of a variety of schemes was initiated, involving the use of several different propulsion options and both propulsive and aerobraking capture at earth, for return of extraterrestrial resources to earth orbits. In addition, the search for new opportunities in space resource utilization continues. Examples include the continuation of work underway on: (1) the feasibility of locating solar power satellites in highly eccentric earth orbit; (2) the energetics of extracting the potential clean fusion fuel He-3 from the atmosphere for return to earth; and (3) the utility of a nuclear steam rocket (using non-terrestrial water as the working fluid) for transportation in the inner solar system.

Catalyst and process development for the H/sub 2/ preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1978-December 31, 1978

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yarrington, R M; Feins, I R; Hwang, H S

1979-01-01

The work done under this contract in the last quarter of 1978 was concerned with Phase I, which involved preliminary catalyst and process evaluation. The processes under study are hydrogen assisted steam reforming (HASR), catalytic partial oxidation (CPO), and autothermal steam reforming (ATR). Existing Engelhard test units were modified to carry out preliminary runs using the first two processes. Technical analysis to support work in this area consisted of heat and material balances constrained by equilibrium considerations. In a third task, the steam reforming of methanol to produce hydrogen was studied over two commercial low-temperature shift catalysts. Aging runs indicatedmore » good initial performance on both catalysts, but methanol conversion started to decline after a few hundred hours on stream.« less

Spiral inlets for steam turbines

NASA Astrophysics Data System (ADS)

Škach, Radek; Uher, Jan

2017-09-01

This paper deals with the design process of special nozzle blades for spiral inlets. Spiral inlets are used for the first stages of high pressure and intermediate pressure steam turbines with both reaction and impulse blades when throttling or sliding pressure control is applied. They improve the steam flow uniformity from the inlet pipe and thus decrease the aerodynamic losses. The proposed evaluation of the inlet angle is based on the free vortex law.

Imitative modeling automatic system Control of steam pressure in the main steam collector with the influence on the main Servomotor steam turbine

NASA Astrophysics Data System (ADS)

Andriushin, A. V.; Zverkov, V. P.; Kuzishchin, V. F.; Ryzhkov, O. S.; Sabanin, V. R.

2017-11-01

The research and setting results of steam pressure in the main steam collector “Do itself” automatic control system (ACS) with high-speed feedback on steam pressure in the turbine regulating stage are presented. The ACS setup is performed on the simulation model of the controlled object developed for this purpose with load-dependent static and dynamic characteristics and a non-linear control algorithm with pulse control of the turbine main servomotor. A method for tuning nonlinear ACS with a numerical algorithm for multiparametric optimization and a procedure for separate dynamic adjustment of control devices in a two-loop ACS are proposed and implemented. It is shown that the nonlinear ACS adjusted with the proposed method with the regulators constant parameters ensures reliable and high-quality operation without the occurrence of oscillations in the transient processes the operating range of the turbine loads.

Hockey-stick steam generator for LMFBR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hallinan, G.J.; Svedlund, P.E.

1981-01-01

This paper presents the criteria and evaluation leading to the selection of the Hockey Stick Steam Generator Concept and subsequent development of that concept for LMFBR application. The selection process and development of the Modular Steam Generator (MSG) is discussed, including the extensive test programs that culminated in the manufacture and test of a 35 MW(t) Steam Generator. The design of the CRBRP Steam Generator is described, emphasizing the current status and a review of the critical structural areas. CRBRP steam generator development tests are evaluated, with a discussion of test objectives and rating of the usefulness of test resultsmore » to the CRBRP prototype design. Manufacturing experience and status of the CRBRP prototype and plant units is covered. The scaleup of the Hockey Stick concept to large commercial plant application is presented, with an evaluation of scaleup limitations, transient effects, and system design implications.« less

Chemicals and ruminant feed from lignocelluloses by the steaming-extraction process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puls, J.; Ayla, C.; Dietrichs, H.H.

1983-01-01

Steaming is applicable to lignocelluloses with lower lignin content such as hardwoods and most agricultural residues. The cellulose of steamed fiber materials becomes accessible for enzymatic degradation in spite of the presence of lignin. The hemicelluloses become water soluble. The lignin can be extracted with alkaline or organic solvents. Without further treatment, the steamed material can be used as highly digestible ruminant feed. Steam treatment, however, is most effective after separation of the hemicelluloses. Depending on the starting material, 10-25% hemicelluloses with xylose contents up to 80% can be recovered by aqueous extraction of the fiber material. The xylans andmore » xylan fragments can be used as substrates for chemical, biochemical, or microbial processes. The residual fiber material consists only of cellulose and lignin in highly accessible form for rumen bacteria and fungal cellulases. They are digested by ruminants up to 70-80% and degraded by cellulases without further treatment to 50-60%. In a second extraction step, the lignin can be removed from the fiber material. After controlled steaming at 190/sup 0/C with an optimum yield of hemicellulose, two-thirds of the original lignin present in the starting material can be extracted with dilute alkali. A relatively mild steaming with additional alkaline extraction of lignin is recommended when total utilization of the components including the hemicelluloses is desired. The extracted lignin can be used as a chemical feedstock. 16 references, 6 figures, 3 tables.« less

Multifactorial modelling of high-temperature treatment of timber in the saturated water steam medium

NASA Astrophysics Data System (ADS)

Prosvirnikov, D. B.; Safin, R. G.; Ziatdinova, D. F.; Timerbaev, N. F.; Lashkov, V. A.

2016-04-01

The paper analyses experimental data obtained in studies of high-temperature treatment of softwood and hardwood in an environment of saturated water steam. Data were processed in the Curve Expert software for the purpose of statistical modelling of processes and phenomena occurring during this process. The multifactorial modelling resulted in the empirical dependences, allowing determining the main parameters of this type of hydrothermal treatment with high accuracy.

Failure of non-vacuum steam sterilization processes for dental handpieces.

PubMed

Winter, S; Smith, A; Lappin, D; McDonagh, G; Kirk, B

2017-12-01

Dental handpieces are used in critical and semi-critical operative interventions. Although some dental professional bodies recommend that dental handpieces are sterilized between patient use there is a lack of clarity and understanding of the effectiveness of different steam sterilization processes. The internal mechanisms of dental handpieces contain narrow lumens (0.8-2.3 mm) which can impede the removal of air and ingress of saturated steam required to achieve sterilization conditions. To identify the extent of sterilization failure in dental handpieces using a non-vacuum process. In-vitro and in-vivo investigations were conducted on widely used UK bench-top steam sterilizers and three different types of dental handpieces. The sterilization process was monitored inside the lumens of dental handpieces using thermometric (TM; dataloggers), chemical indicator (CI), and biological indicator (BI) methods. All three methods of assessing achievement of sterility within dental handpieces that had been exposed to non-vacuum sterilization conditions demonstrated a significant number of failures [CI: 8/3024 (fails/no. of tests); BI: 15/3024; TM: 56/56] compared to vacuum sterilization conditions (CI: 2/1944; BI: 0/1944; TM: 0/36). The dental handpiece most likely to fail sterilization in the non-vacuum process was the surgical handpiece. Non-vacuum sterilizers located in general dental practice had a higher rate of sterilization failure (CI: 25/1620; BI: 32/1620; TM: 56/56) with no failures in vacuum process. Non-vacuum downward/gravity displacement, type N steam sterilizers are an unreliable method for sterilization of dental handpieces in general dental practice. The handpiece most likely to fail sterilization is the type most frequently used for surgical interventions. Copyright © 2017 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

Industry starts to tap the sun's energy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-01-15

The dedication in 1978 of the Riegel Textile Corp's solar-collecting field in La France, South Carolina, marked the first solar process hot water application within the textile industry. Results from this DOE-funded project could provide a breakthrough in the application of solar energy to industrial process hot water, which accounts for about 4% of the nation's energy needs. A General Electric Co. industrial solar process-hot-water system is used to heat water to 190 F in an open fabric-dyeing vat designed to provide from 50 to 70% of the process heat required for a single-dye unit. The largest, citrus-juice processing plantmore » in the world at Bradenton, Florida, is being equipped wth a General Electric solar system that will supply high temperature steam (350 F, 134 psig) to one of the plant's pasteurizers during weekdays. On weekends, the solar unit will supply a major part of the steam used by two of the plant's four glycol-refrigerant dryers. A solar total energy system that will be used to provide electricity, steam, heat, and hot water for a knitware plant in Shenandoah, Georgia, is described. The project, managed by Sandia Laboratory, will utilize two axis parabolic dish solar collectors, which will produce steam at temperatures in the range of 750 F. The system is being designed to provide 60% of the annual energy requirements of the knitware facility. It will provide 35% of the electricity, 60% of the process steam, 98% of the domestic water and space heating needs, and 85% of the air conditioning requirements of the 42,000 sq ft factory being built for the West Germany-based Wilhelm Bleyle Co. (MCW)« less

Steam reforming of commercial ultra-low sulphur diesel

NASA Astrophysics Data System (ADS)

Boon, Jurriaan; van Dijk, Eric; de Munck, Sander; van den Brink, Ruud

Two main routes for small-scale diesel steam reforming exist: low-temperature pre-reforming followed by well-established methane steam reforming on the one hand and direct steam reforming on the other hand. Tests with commercial catalysts and commercially obtained diesel fuels are presented for both processes. The fuels contained up to 6.5 ppmw sulphur and up to 4.5 vol.% of biomass-derived fatty acid methyl ester (FAME). Pre-reforming sulphur-free diesel at around 475 °C has been tested with a commercial nickel catalyst for 118 h without observing catalyst deactivation, at steam-to-carbon ratios as low as 2.6. Direct steam reforming at temperatures up to 800 °C has been tested with a commercial precious metal catalyst for a total of 1190 h with two catalyst batches at steam-to-carbon ratios as low as 2.5. Deactivation was neither observed with lower steam-to-carbon ratios nor for increasing sulphur concentration. The importance of good fuel evaporation and mixing for correct testing of catalysts is illustrated. Diesel containing biodiesel components resulted in poor spray quality, hence poor mixing and evaporation upstream, eventually causing decreasing catalyst performance. The feasibility of direct high temperature steam reforming of commercial low-sulphur diesel has been demonstrated.

Postfact phenomena of the wet-steam flow electrization in turbines

NASA Astrophysics Data System (ADS)

Tarelin, A. A.

2017-11-01

Physical processes occurring in a turbine with natural electrization of a humidity-steam flow and their effect on efficiency and reliability of the turbine operation has been considered. Causes of the electrical potential occurrence on a rotor shaft are analyzed. The wet steam's electrization exposure on the electrical potential that is one of the major factors of bearings' electroerosion has been demonstrated on the full-scale installation. Hydrogen formation in wheelspace of the turbine as a result of electrochemical processes and electric field exposure of the space charge has been considered. Hydrogen concentration dependence on a volume charge density in the steam flow has been determined. It is stated that the processes occurring behind the final stage of wet-steam turbines are similar to the ones in elaerosol ectrostatic generators. It has been demonstrated that this phenomenon causes the flow's temporal inhibition and starts pulsations. These factors' impact on power loss of the turbine has been evaluated and recommendations for their elimination have been offered. It has been determined that motions of charged drops can cause self-maintained discharges inside of the flow and between the flow and grounded surfaces that are accompanied by electromagnetic radiation of the wide spectrum. The integrated studies have shown that physical phenomena occurring due to natural electrization negatively affect efficiency and reliability of the turbine operation. Practical recommendations allowing one to minimize the negative effects of the flow natural electrization process have been offered.

Students' construction of a simple steam distillation apparatus and development of creative thinking skills: A project-based learning

NASA Astrophysics Data System (ADS)

Diawati, Chansyanah; Liliasari, Setiabudi, Agus; Buchari

2017-05-01

This project-based learning combined the chemistry of separation process using steam distillation with engineering design process in an undergraduate chemistry course. Students built upon their knowledge of phase changes, immiscible mixture, and the relationship between vapor pressure and boiling point to complete a project of modifications steam distillation apparatus. The research method is a qualitative case study, which aims to describe how (1) the creative thinking skills of students emerged during six weeks of theproject, (2) students built steam distillation apparatus characteristics as the project product and (3) students response to the project-based learning model. The results showed that the students had successfully constructed a steam distillation apparatus using plastic kettle as steam generator and distillation flask. A Plastic tubewas used to drain water vapor from steam generator to distillation flask and to drain steam containing essential oil to the condenser. A biscuit tin filled with ice was used as a condenser. The time required until resulting distillate was fifteen minutes. The production of essential was conductive qualitatively by a very strong smell typical of essential oil and two phases of distillate. Throughout the project, students formulated the relevant and varied problem, formulated the goals, proposed the ideas of the apparatus and materials, draw apparatus design, constructed apparatus, tested apparatus, evaluated, and reported the project. Student response was generally positive. They were pleased, interested, more understanding the concepts and work apparatus principles, also implemented new ideas. These results indicate that project-based learning can develop students' creative thinking skills. Based on these results, it is necessary to conduct research and implemented project-based learning to other concepts.

Alteration of biomacromolecule in corn by steam flaking in relation to biodegradation kinetics in ruminant, revealed with vibrational molecular spectroscopy

NASA Astrophysics Data System (ADS)

Xu, Ningning; Liu, Jianxin; Yu, Peiqiang

2018-02-01

Large scale of steam flaked corn has been used in dairy ration to maintain high milk production level. This study aimed to determine effects of steam flaking on processing-induced intrinsic molecular structure changes that were associated with rumen degradation kinetics and nutrients supply. The advanced vibrational molecular spectroscopy was applied to reveal the processing-induced intrinsic structure changes on a molecular basis. The rumen degradation kinetics and nutrient supply were determined using in situ approach in ruminant livestock system. Raw corn grain (RC) and steam flaked corn grain (SFC) were obtained from two different processing plants. The results showed that (1) Compared to RC, SFC had greater truly digestible non-fiber carbohydrate [tdNFC: 86.8 versus 78.0% dry matter (DM)], but lower truly digestible crude protein [tdCP: 7.7 versus 9.0% DM]. (2) The steam flaking increased (P < 0.01) rumen degradable DM (RDDM) and starch (RDSt), but decreased (P < 0.01) rumen degradable protein (RDP). (3) Molecular absorbance intensities of most carbohydrate biopolymers were greater in SFC (P < 0.01), but protein amides associated molecular spectral intensities were lower (P < 0.01) in SFC. (4). The molecular structure and nutrient interactive study showed that carbohydrate spectral intensities were positively (P < 0.10) associated with RDDM and RDSt and protein amide spectral intensities were positively (P < 0.10) associated with RDP. This results indicated that the steam flaking induced molecular structure changes had an interactive relationship with rumen degradation kinetics.

Immediate use steam sterilization: moving beyond current policy.

PubMed

Seavey, Rose

2013-05-01

Immediate-use steam sterilization (IUSS) is steam sterilization intended for immediate use. IUSS may cause an increased risk of infection to patients because of stress and time constraints placed on staff. When IUSS is used, it is vital to properly carry out the complete multistep process according to the manufacturer's written validated instructions for use. Copyright © 2013 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Mosby, Inc. All rights reserved.

The Effects of Alarm Display, Processing, and Availability on Crew Performance

DTIC Science & Technology

2000-11-01

snow Instrumentation line leakage Small LOCA Steam generator tube rupture Small feedwater leakage inside containment Cycling of main steam...implemented. • Due to primary pressure controller failure, pressure heater banks cycle between on and off. 8.00 CF1 CF2 CF3 CF4 CF5...temperatures after the high-pressure pre- heaters flows into the steam generators number of active emergency feedwater pumps openings of the condensate

$gamma$-RAY PROCESSING OF RICE. (IV.) STUDIES ON THE AVAILABILITY OF $gamma$-IRRADIATED RICE FOR KOJI

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishimura, A.; Takaoka, K.

The availability of rice, gamma -irradiated up to 4.6 x 10/sup 4/ and 3.5 x 10/sup 5/r for koji was studied. The enzyme activities of koji of the steamed samples were stronger than the unirradiated rice in amylase and protease. The sensory test on the once-steamed irradiated rice was almost the same as the twice-steamed unirradiated rice. (OID)

Development and demonstration of techniques for reducing occupational radiation doses during refueling outages. Task 1. Steam generator channel head decontamination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abrams, W.T.; Cope, A.W.; Orsulak, R.M.

The overall objective of Task 1 was to demonstrate an effective method for removing tenacious corrosion products in a pressurized water reactor steam generator and thus significantly reduce radiation exposure during subsequent maintenance activities. Various decontamination methods were evaluated and a multistep, low concentration chemical process originated by Kraftwerk Union A.G. (KWU) of the Federal Republic of Germany was selected. The process was further developed and tested by C-E and KWU in West Germany and at C-E's facilities in Windsor, Connecticut. C-E designed, fabricated and tested a portable system to apply the process at Millstone Point II. The decontamination ofmore » the primary channel heads of the two Millstone steam generators was performed by C-E and NUSCO during the 1983 refueling shutdown of Millstone Point II plant. Results of the decontamination were very satisfactory. NUSCO determined that a net savings of 3660 man-rem of personnel exposure was realized during the decontamination demonstration and the subsequent maintenance work on the steam generators.« less

Comparative techno-economic analysis of steam explosion, dilute sulfuric acid, ammonia fiber explosion and biological pretreatments of corn stover.

PubMed

Baral, Nawa Raj; Shah, Ajay

2017-05-01

Pretreatment is required to destroy recalcitrant structure of lignocelluloses and then transform into fermentable sugars. This study assessed techno-economics of steam explosion, dilute sulfuric acid, ammonia fiber explosion and biological pretreatments, and identified bottlenecks and operational targets for process improvement. Techno-economic models of these pretreatment processes for a cellulosic biorefinery of 113.5 million liters butanol per year excluding fermentation and wastewater treatment sections were developed using a modelling software-SuperPro Designer. Experimental data of the selected pretreatment processes based on corn stover were gathered from recent publications, and used for this analysis. Estimated sugar production costs ($/kg) via steam explosion, dilute sulfuric acid, ammonia fiber explosion and biological methods were 0.43, 0.42, 0.65 and 1.41, respectively. The results suggest steam explosion and sulfuric acid pretreatment methods might be good alternatives at present state of technology and other pretreatment methods require research and development efforts to be competitive with these pretreatment methods. Copyright © 2017 Elsevier Ltd. All rights reserved.

Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant L. Hawkes; Michael G. McKellar

2009-11-01

A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the powermore » cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.« less

Impact of pretreatment and downstream processing technologies on economics and energy in cellulosic ethanol production.

PubMed

Kumar, Deepak; Murthy, Ganti S

2011-09-05

While advantages of biofuel have been widely reported, studies also highlight the challenges in large scale production of biofuel. Cost of ethanol and process energy use in cellulosic ethanol plants are dependent on technologies used for conversion of feedstock. Process modeling can aid in identifying techno-economic bottlenecks in a production process. A comprehensive techno-economic analysis was performed for conversion of cellulosic feedstock to ethanol using some of the common pretreatment technologies: dilute acid, dilute alkali, hot water and steam explosion. Detailed process models incorporating feedstock handling, pretreatment, simultaneous saccharification and co-fermentation, ethanol recovery and downstream processing were developed using SuperPro Designer. Tall Fescue (Festuca arundinacea Schreb) was used as a model feedstock. Projected ethanol yields were 252.62, 255.80, 255.27 and 230.23 L/dry metric ton biomass for conversion process using dilute acid, dilute alkali, hot water and steam explosion pretreatment technologies respectively. Price of feedstock and cellulose enzymes were assumed as $50/metric ton and 0.517/kg broth (10% protein in broth, 600 FPU/g protein) respectively. Capital cost of ethanol plants processing 250,000 metric tons of feedstock/year was $1.92, $1.73, $1.72 and $1.70/L ethanol for process using dilute acid, dilute alkali, hot water and steam explosion pretreatment respectively. Ethanol production cost of $0.83, $0.88, $0.81 and $0.85/L ethanol was estimated for production process using dilute acid, dilute alkali, hot water and steam explosion pretreatment respectively. Water use in the production process using dilute acid, dilute alkali, hot water and steam explosion pretreatment was estimated 5.96, 6.07, 5.84 and 4.36 kg/L ethanol respectively. Ethanol price and energy use were highly dependent on process conditions used in the ethanol production plant. Potential for significant ethanol cost reductions exist in increasing pentose fermentation efficiency and reducing biomass and enzyme costs. The results demonstrated the importance of addressing the tradeoffs in capital costs, pretreatment and downstream processing technologies.

Impact of pretreatment and downstream processing technologies on economics and energy in cellulosic ethanol production

PubMed Central

2011-01-01

Background While advantages of biofuel have been widely reported, studies also highlight the challenges in large scale production of biofuel. Cost of ethanol and process energy use in cellulosic ethanol plants are dependent on technologies used for conversion of feedstock. Process modeling can aid in identifying techno-economic bottlenecks in a production process. A comprehensive techno-economic analysis was performed for conversion of cellulosic feedstock to ethanol using some of the common pretreatment technologies: dilute acid, dilute alkali, hot water and steam explosion. Detailed process models incorporating feedstock handling, pretreatment, simultaneous saccharification and co-fermentation, ethanol recovery and downstream processing were developed using SuperPro Designer. Tall Fescue (Festuca arundinacea Schreb) was used as a model feedstock. Results Projected ethanol yields were 252.62, 255.80, 255.27 and 230.23 L/dry metric ton biomass for conversion process using dilute acid, dilute alkali, hot water and steam explosion pretreatment technologies respectively. Price of feedstock and cellulose enzymes were assumed as $50/metric ton and 0.517/kg broth (10% protein in broth, 600 FPU/g protein) respectively. Capital cost of ethanol plants processing 250,000 metric tons of feedstock/year was $1.92, $1.73, $1.72 and $1.70/L ethanol for process using dilute acid, dilute alkali, hot water and steam explosion pretreatment respectively. Ethanol production cost of $0.83, $0.88, $0.81 and $0.85/L ethanol was estimated for production process using dilute acid, dilute alkali, hot water and steam explosion pretreatment respectively. Water use in the production process using dilute acid, dilute alkali, hot water and steam explosion pretreatment was estimated 5.96, 6.07, 5.84 and 4.36 kg/L ethanol respectively. Conclusions Ethanol price and energy use were highly dependent on process conditions used in the ethanol production plant. Potential for significant ethanol cost reductions exist in increasing pentose fermentation efficiency and reducing biomass and enzyme costs. The results demonstrated the importance of addressing the tradeoffs in capital costs, pretreatment and downstream processing technologies. PMID:21892958

Industrial steam systems and the energy-water nexus.

PubMed

Walker, Michael E; Lv, Zhen; Masanet, Eric

2013-11-19

This paper presents estimates for water consumption and steam generation within U.S. manufacturing industries. These estimates were developed through the integration of detailed, industry-level fuel use and operation data with an engineering-based steam system model. The results indicate that industrial steam systems consume approximately 3780 TBTU/yr (3.98 × 10(9) GJ/yr) to generate an estimated 2.9 trillion lb/yr (1.3 trillion kg/yr) of steam. Since a good portion of this steam is injected directly into plant processes, vented, leaked, or removed via blowdown, roughly 354 MGD of freshwater must be introduced to these systems as makeup. This freshwater consumption rate is approximately 11% of that for the entire U.S. manufacturing sector, or the total residential consumption rate of Los Angeles, the second largest city in the U.S. The majority of this consumption (>94%) can be attributed to the food, paper, petroleum refining, and chemicals industries. The results of the analyses presented herein provide previously unavailable detail on water consumption in U.S. industrial steam systems and highlight opportunities for combined energy and water savings.

Method and apparatus for destroying organic contaminants in aqueous liquids

DOEpatents

Donaldson, T.L.; Wilson, J.H.

1993-09-21

A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

Method and apparatus for destroying organic contaminants in aqueous liquids

DOEpatents

Donaldson, Terrence L.; Wilson, James H.

1993-01-01

A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing.

Solar production of intermediate temperature process heat. Phase I design. Final report. [For sugarcane processing plant in Hawaii

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1980-08-01

This report is the final effort in the Phase I design of a solar industrial process heat system for the Hilo Coast Processing Company (HCPC) in Pepeekeo, Hawaii. The facility is used to wash, grind and extract sugar from the locally grown sugarcane and it operates 24 hours a day, 305 days per year. The major steam requirements in the industrial process are for the prime movers (mill turbines) in the milling process and heat for evaporating water from the extracted juices. Bagasse (the fibrous residue of milled sugarcane) supplied 84% of the fuel requirement for steam generation in 1979,more » while 65,000 barrels of No. 6 industrial fuel oil made up the remaining 16%. These fuels are burned in the power plant complex which produces 825/sup 0/F, 1,250 psi superheated steam to power a turbogenerator set which, in addition to serving the factory, generates from 7 to 16 megawatts of electricity that is exported to the local utility company. Extracted steam from the turbo-generator set supplies the plant's process steam needs. The system consists of 42,420 ft./sup 2/ of parabolic trough, single axis tracking, concentrating solar collectors. The collectors will be oriented in a North-South configuration and will track East-West. A heat transfer fluid (Gulf Synfluid 4cs) will be circulated in a closed loop fashion through the solar collectors and a series of heat exchangers. The inlet and outlet fluid temperatures for the collectors are 370/sup 0/F and 450/sup 0/F respectively. It is estimated that the net useable energy delivered to the industrial process will be 7.2 x 10/sup 9/ Btu's per year. With an HCPC boiler efficiency of 78% and 6.2 x 10/sup 6/ Btu's per barrel of oil, the solar energy system will displace 1489 barrels of oil per year. (WHK)« less

Innovative Method for Separating Phosphorus and Iron from High-Phosphorus Oolitic Hematite by Iron Nugget Process

NASA Astrophysics Data System (ADS)

Han, Hongliang; Duan, Dongping; Wang, Xing; Chen, Siming

2014-10-01

This study puts forward a new method to separate phosphorus and iron from high-phosphorus oolitic hematite through iron nuggets process. Firstly, the physical, chemical, and microscopic characteristics of high-phosphorus oolitic hematite are investigated. Then, the reaction mechanisms of high-phosphorus hematite together with feasibility to separating phosphorus and iron by iron nugget process are discussed. Meanwhile, the experiments of high-phosphorus hematite used in rotary hearth furnace iron nugget processes are studied as well. The results indicate that the iron nugget process is a feasible and efficient method for iron and phosphorus separation of high-phosphorus oolitic hematite. The phosphorus content in iron nuggets is relatively low. Through the optimization of process parameters, the lowest of phosphorus in iron nuggets is 0.22 pct, the dephosphorization rate is above 86 pct, and the recovery of Fe is above 85 pct by the iron nugget process. This study aims to provide a theoretical and technical basis for economical and rational use of high-phosphorus oolitic hematite.

A review of water recovery by vapour permeation through membranes.

PubMed

Bolto, Brian; Hoang, Manh; Xie, Zongli

2012-02-01

In vapour permeation the feed is a vapour, not a liquid as in pervaporation. The process employs a polymeric membrane as a semi-permeable barrier between the feed side under high pressure and the permeate side under low pressure. Separation is achieved by the different degrees to which components are dissolved in and diffuse through the membrane, the system working according to a solution-diffusion mechanism. The materials used in the membrane depend upon the types of compounds being separated, so water transport is favoured by hydrophilic material, whether organic or inorganic. The process is used for the dehydration of natural gas and various organic solvents, notably alcohol as biofuel, as well as the removal of water from air and its recovery from waste steam. Waste steam can be found in almost every plant/factory where steam is used. It is frequently contaminated and cannot be reused. Discharging the spent steam to the atmosphere is a serious energy loss and environmental issue. Recycling the steam can significantly improve the overall energy efficiency of an industry, which is responsible for massive CO(2) emissions. Steam separation at high fluxes and temperatures has been accomplished with a composite poly(vinyl alcohol) membrane containing silica nanoparticles, and also, less efficiently, with an inorganic zeolite membrane. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved.

Steam--water mixing and system hydrodynamics program. Task 4. Quarterly progress report, October 1, 1977--December 31, 1977. [PWR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carbiener, W.A.; Cudnik, R.A.; Dykhuizen, R.C.

Experimental studies were conducted in a /sup 2///sub 15/-scale model of a four-loop pressurized water reactor at pressures to 75 psia to extend the understanding of steam-water interaction phenomena and processes associated with a loss-of-coolant accident. Plenum filling studies were conducted with hydraulic communication between the cold leg and core steam supplies and hot walls, with both fixed and ramped steam flows. Comparisons of correlational fits have been made for penetration data obtained with hydraulic communication, fixed cold leg steam, and no cold leg steam. Statistical tests applied to these correlational fits have indicated that the hydraulic communication and fixedmore » cold leg steam data can be considered to be a common data set. Comparing either of these data sets to the no cold leg steam data using the statistical test indicated that it was unlikely that these sets could be considered to be a common data set. The introduction of cold leg steam results in a slight decrease in penetration relative to that obtained without cold leg steam at the same value of subcooling of water entering the downcomer. A dimensionless parameter which is a weighted mean of a modified Froude number and the Weber number has been proposed as a scaling parameter for penetration data. This parameter contains an additional degree of freedom which allows data from different scales to collapse more closely to a single curve than current scaling parameters permit.« less

Heterogeneous Catalysts for VOC Oxidation from Red Mud and Bagasse Ash Carbon

NASA Astrophysics Data System (ADS)

Pande, Gaurav

A range of VOC oxidation catalysts have been prepared in this study from agricultural and industrial waste as the starting point. The aim is to prepare catalysts with non-noble metal oxides as the active catalytic component (iron in red mud). The same active component was also supported on activated carbon obtained from unburned carbon in bagasse ash. Red mud which is an aluminum industry waste and rich in different phases of iron as oxide and hydroxide is used as the source for the catalytically active species. It is our aim to enhance the catalytic performance of red mud which though high in iron concentration has a low surface area and may not have the properties of an ideal catalyst by itself. In one of the attempts to enhance the catalytic performance, we have tried to leach red mud for which we have explored a range of leaching acids for effecting the leaching most efficiently and then precipitated the iron from the leachate as its hydroxide by precipitating with alkali solution followed by drying and calcination to give high surface area metal oxide material. Extensive surface characterization and VOC oxidation catalytic testing were performed for these solids. In a step to further enhance the catalytic activity towards oxidation, copper was introduced by taking another industrial waste from the copper tubing industry viz. the pickling acid. Copper has a more favourable redox potential making it catalytically more effective than iron. To make the mixed metal oxide, red mud leachate was mixed with the pickling acid in a pre-decided ratio before precipitating with alkali solution followed by drying and calcination as was done with the red mud leachate. The results from these experiments are encouraging. The temperature programmed reduction (TPR) of the solids show that the precipitate of red mud leachates show hydrogen uptake peak at a lower temperature than for just the calcined red mud. This could be due to the greatly enhanced surface area of the prepared solids. The highest surface area of 311 m2/g was for the sample prepared from oxalic acid and l-ascorbic acid as the leaching acid; as received red mud has a surface area of 11.5 m2/g. This sample showed better catalytic performance than the ones made from hydrochloric acid as the leaching acid in spite of a similar increase in surface area. High temperature XRD shows the reason for this difference in catalytic properties could be due to both the solids reducing in a different way to give different phases though they are both derived from red mud as the starting material. Also, the sample prepared with oxalic acid leachate had higher surface iron concentration. For the best catalyst (oxalic acid derived) the light off temperature is about 300 °C for toluene oxidation. For solids prepared from red mud leachate for iron source and pickling acid for copper source, it was seen that the TPR gave hydrogen absorption at temperatures even lower than that for red mud leachate precipitates. In another set of experiments, iron oxide impregnated on activated carbon supports were prepared. Activated carbon is known for its adsorption properties which could give a better access of the impregnated metal oxide catalyst to perform the catalytic oxidation on the adsorbed substrate. Unburned carbon in bagasse ash which is a sugar industry agricultural waste was used to get the activated carbon. This material was separated from the ash and further modified to enhance the activity and increase the porosity. To this effect steam activation was performed. To impart thermal stability for oxidation reaction, the carbon was impregnated by phosphoric acid at activated at high temperatures in inert atmosphere. These carbons were thermally stable due to the surface C--O--P groups. Toluene adsorption studies were also performed for both the steam activated as well as phosphoric acid activated carbon and it was found that the steam activated carbons with less surface oxygen had reasonable adsorption attributes. For iron impregnation onto the prepared bagasse ash carbons, two different methods of impregnation viz. incipient wetness method as well as impregnation by precipitation of the red mud leachate by adding alkali to a slurry of carbon and leachate (Pratt method) was used. It was found that impregnation by precipitation led to better butanol oxidation performing catalyst than the one prepared by impregnating by incipient wetness method. The best performing catalyst amongst the iron impregnated on carbon types was found to give 100% butanol conversion at 200 °C. It was also observed that red mud leachate precipitated catalyst performed well for toluene oxidation and not for butanol oxidation while carbon supported iron oxide catalysts worked better for butanol oxidation than for toluene oxidation.

Bioactive compounds and antioxidant activity of fresh and processed white cauliflower.

PubMed

Ahmed, Fouad A; Ali, Rehab F M

2013-01-01

Brassica species are very rich in health-promoting phytochemicals, including phenolic compounds, vitamin C, and minerals. The objective of this study was to investigate the effect of different blanching (i.e., water and steam) and cooking (i.e., water boiling, steam boiling, microwaving, and stir-frying) methods on the nutrient components, phytochemical contents (i.e., polyphenols, carotenoids, flavonoid, and ascorbic acid), antioxidant activity measured by DPPH assay, and phenolic profiles of white cauliflower. Results showed that water boiling and water blanching processes had a great effect on the nutrient components and caused significant losses of dry matter, protein, and mineral and phytochemical contents. However, steam treatments (blanching and cooking), stir-frying, and microwaving presented the lowest reductions. Methanolic extract of fresh cauliflower had significantly the highest antioxidant activity (68.91%) followed by the extracts of steam-blanched, steam-boiled, stir-fried, and microwaved cauliflower 61.83%, 59.15%, 58.93%, and 58.24%, respectively. HPLC analysis revealed that the predominant phenolics of raw cauliflower were protocatechuic acid (192.45), quercetin (202.4), pyrogallol (18.9), vanillic acid (11.90), coumaric acid (6.94), and kaempferol (25.91) mg/100 g DW, respectively.

Bioactive Compounds and Antioxidant Activity of Fresh and Processed White Cauliflower

PubMed Central

Ahmed, Fouad A.; Ali, Rehab F. M.

2013-01-01

Brassica species are very rich in health-promoting phytochemicals, including phenolic compounds, vitamin C, and minerals. The objective of this study was to investigate the effect of different blanching (i.e., water and steam) and cooking (i.e., water boiling, steam boiling, microwaving, and stir-frying) methods on the nutrient components, phytochemical contents (i.e., polyphenols, carotenoids, flavonoid, and ascorbic acid), antioxidant activity measured by DPPH assay, and phenolic profiles of white cauliflower. Results showed that water boiling and water blanching processes had a great effect on the nutrient components and caused significant losses of dry matter, protein, and mineral and phytochemical contents. However, steam treatments (blanching and cooking), stir-frying, and microwaving presented the lowest reductions. Methanolic extract of fresh cauliflower had significantly the highest antioxidant activity (68.91%) followed by the extracts of steam-blanched, steam-boiled, stir-fried, and microwaved cauliflower 61.83%, 59.15%, 58.93%, and 58.24%, respectively. HPLC analysis revealed that the predominant phenolics of raw cauliflower were protocatechuic acid (192.45), quercetin (202.4), pyrogallol (18.9), vanillic acid (11.90), coumaric acid (6.94), and kaempferol (25.91) mg/100 g DW, respectively. PMID:24171164

Modeling of steam distillation mechanism during steam injection process using artificial intelligence.

PubMed

Daryasafar, Amin; Ahadi, Arash; Kharrat, Riyaz

2014-01-01

Steam distillation as one of the important mechanisms has a great role in oil recovery in thermal methods and so it is important to simulate this process experimentally and theoretically. In this work, the simulation of steam distillation is performed on sixteen sets of crude oil data found in the literature. Artificial intelligence (AI) tools such as artificial neural network (ANN) and also adaptive neurofuzzy interference system (ANFIS) are used in this study as effective methods to simulate the distillate recoveries of these sets of data. Thirteen sets of data were used to train the models and three sets were used to test the models. The developed models are highly compatible with respect to input oil properties and can predict the distillate yield with minimum entry. For showing the performance of the proposed models, simulation of steam distillation is also done using modified Peng-Robinson equation of state. Comparison between the calculated distillates by ANFIS and neural network models and also equation of state-based method indicates that the errors of the ANFIS model for training data and test data sets are lower than those of other methods.

Reason behind wet pack after steam sterilization and its consequences: An overview from Central Sterile Supply Department of a cancer center in eastern India.

PubMed

Basu, Debabrata

Wet pack after steam sterilization process that means there are surely obtain millions of microorganisms that can breed and multiply rapidly and objects are unsterile and can never be used for further procedure. There are many reasons behind the wet pack occurrences after autoclaving like poor quality of wrapping materials, faulty valves of rigid container, faulty loading and packaging technique, poor steam quality, sterilizer malfunction and may be design related problems in CSSD sterile storage area. Cause of wet pack after steam sterilization processes may occur severe problems because of wasted time and effort, increased work load, increased cost, potentially contaminated instruments, infection risk to the patient, poor patient outcomes and delayed or cancellation of procedures. But such wet pack scenario can be avoided by various methods by using good steam (water) quality, performing periodic maintenance of the Autoclaves, avoidance of sterilizer overloading, allowing adequate post sterilization time to cool down the materials to room temperature, using good quality wrapping materials, properly maintain temperature and humidity of sterile storage area etc. Copyright © 2016 King Saud Bin Abdulaziz University for Health Sciences. Published by Elsevier Ltd. All rights reserved.

Modeling of Steam Distillation Mechanism during Steam Injection Process Using Artificial Intelligence

PubMed Central

Ahadi, Arash; Kharrat, Riyaz

2014-01-01

Steam distillation as one of the important mechanisms has a great role in oil recovery in thermal methods and so it is important to simulate this process experimentally and theoretically. In this work, the simulation of steam distillation is performed on sixteen sets of crude oil data found in the literature. Artificial intelligence (AI) tools such as artificial neural network (ANN) and also adaptive neurofuzzy interference system (ANFIS) are used in this study as effective methods to simulate the distillate recoveries of these sets of data. Thirteen sets of data were used to train the models and three sets were used to test the models. The developed models are highly compatible with respect to input oil properties and can predict the distillate yield with minimum entry. For showing the performance of the proposed models, simulation of steam distillation is also done using modified Peng-Robinson equation of state. Comparison between the calculated distillates by ANFIS and neural network models and also equation of state-based method indicates that the errors of the ANFIS model for training data and test data sets are lower than those of other methods. PMID:24883365

Steam generators secondary side chemical cleaning at Point Lepreau using the Siemens high temperature process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Verma, K.; MacNeil, C.; Odar, S.

1997-02-01

This paper describes the chemical cleaning of the four steam generators at the Point Lepreau facility, which was accomplished as a part of a normal service outage. The steam generators had been in service for twelve years. Sludge samples showed the main elements were Fe, P and Na, with minor amounts of Ca, Mg, Mn, Cr, Zn, Cl, Cu, Ni, Ti, Si, and Pb, 90% in the form of Magnetite, substantial phosphate, and trace amounts of silicates. The steam generators were experiencing partial blockage of broached holes in the TSPs, and corrosion on tube ODs in the form of pittingmore » and wastage. In addition heat transfer was clearly deteriorating. More than 1000 kg of magnetite and 124 kg of salts were removed from the four steam generators.« less

Incineration and pyrolysis vs. steam gasification of electronic waste.

PubMed

Gurgul, Agnieszka; Szczepaniak, Włodzimierz; Zabłocka-Malicka, Monika

2018-05-15

Constructional complexity of items and their integration are the most distinctive features of electronic wastes. These wastes consist of mineral and polymeric materials and have high content of valuable metals that could be recovered. Elimination of polymeric components (especially epoxy resins) while leaving non-volatile mineral and metallic phases is the purpose of thermal treatment of electronic wastes. In the case of gasification, gaseous product of the process may be, after cleaning, used for energy recovery or chemical synthesis. If not melted, metals from solid products of thermal treatment of electronic waste could be recovered by hydrometallurgical processing. Three basic, high temperature ways of electronic waste processing, i.e. smelting/incineration, pyrolysis and steam gasification were shortly discussed in the paper, giving a special attention to gasification under steam, illustrated by laboratory experiments. Copyright © 2017 Elsevier B.V. All rights reserved.

Statistical validation and an empirical model of hydrogen production enhancement found by utilizing passive flow disturbance in the steam-reformation process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erickson, Paul A.; Liao, Chang-hsien

2007-11-15

A passive flow disturbance has been proven to enhance the conversion of fuel in a methanol-steam reformer. This study presents a statistical validation of the experiment based on a standard 2{sup k} factorial experiment design and the resulting empirical model of the enhanced hydrogen producing process. A factorial experiment design was used to statistically analyze the effects and interactions of various input factors in the experiment. Three input factors, including the number of flow disturbers, catalyst size, and reactant flow rate were investigated for their effects on the fuel conversion in the steam-reformation process. Based on the experimental results, anmore » empirical model was developed and further evaluated with an uncertainty analysis and interior point data. (author)« less

Alternative method for steam generation for thermal oxidation of silicon

NASA Astrophysics Data System (ADS)

Spiegelman, Jeffrey J.

2010-02-01

Thermal oxidation of silicon is an important process step in MEMS device fabrication. Thicker oxide layers are often used as structural components and can take days or weeks to grow, causing high gas costs, maintenance issues, and a process bottleneck. Pyrolytic steam, which is generated from hydrogen and oxygen combustion, was the default process, but has serious drawbacks: cost, safety, particles, permitting, reduced growth rate, rapid hydrogen consumption, component breakdown and limited steam flow rates. Results from data collected over a 24 month period by a MEMS manufacturer supports replacement of pyrolytic torches with RASIRC Steamer technology to reduce process cycle time and enable expansion previously limited by local hydrogen permitting. Data was gathered to determine whether Steamers can meet or exceed pyrolytic torch performance. The RASIRC Steamer uses de-ionized water as its steam source, eliminating dependence on hydrogen and oxygen. A non-porous hydrophilic membrane selectively allows water vapor to pass. All other molecules are greatly restricted, so contaminants in water such as dissolved gases, ions, total organic compounds (TOC), particles, and metals can be removed in the steam phase. The MEMS manufacturer improved growth rate by 7% over the growth range from 1μm to 3.5μm. Over a four month period, wafer uniformity, refractive index, wafer stress, and etch rate were tracked with no significant difference found. The elimination of hydrogen generated a four-month return on investment (ROI). Mean time between failure (MTBF) was increased from 3 weeks to 32 weeks based on three Steamers operating over eight months.

Retrofitting Cogeneration Power Stations under Conditions of Reduction or Abandonment of Steam Delivery for Process Needs

NASA Astrophysics Data System (ADS)

Dubrovskii, V. G.; Zubov, A. P.; Koshelev, S. A.

2018-06-01

Presently, when the structure of energy consumption by industrial enterprises is being changed, many type PT turbine units operate with limitations imposed on their operating conditions, while type R backpressure turbines are often shut down for a long time or even removed from operation. Thus, the problem of using steam previously intended for process needs combined with the loading of the main equipment and additional generation of power and heat becomes urgent for many power stations. Three main ways for solving this problem are examined in this paper. Potential alternatives for retrofitting of cogeneration power stations (TETS) with types PT and R turbines are discussed. Each alternative solves a specific problem brought about by the actual operating conditions of a turbine at a specific TETs. The results of retrofitting of PT-80-130 turbines with an increase in the throughput capacity of the intermediate pressure cylinder (IPC) and R-50-130 turbines with installation of an additional low-pressure cylinder (LPC) are presented. The experience in operation of the retrofitted R-50-130 turbine with an unconventional arrangement where an additional LPC is installed upstream the high-pressure cylinder (HPC) rather than between the generator and HPC is also described. The experience in the upgrading of TETs with installation of bottom steam turbines driven by steam from a process steam extraction that is not demanded for is presented. Depending on the conditions at a specific TETs, a bottom steam turbine can be installed on a new foundation or in the compartment of a dismounted turbine with the use of serviceable auxiliary and heat-exchange equipment.

Effect of processing techniques on color and active components amount of sweet potato (Ipomoea Batatas l) flakes

NASA Astrophysics Data System (ADS)

Rahmawati, Y.; Mahmudatussa'adah, A.; Yogha, S.

2016-04-01

Sweet potato processing is limited, such as flour, snacks, cystic, or chips. Flakes as pre-cooked meals are made through the stages of making pasta and drying. The purpose of this study was to optimize the production of sweet potato flakes at the stage of making pasta and drying. Making the pasta is done through techniques steamed or baked. Pasta drying using tools a drum dryer or cabinet dryer. As an indicator of optimization is the total of monomeric anthocyanins, β-carotene and color the resulting flakes. The results showed that the amount of anthocyanin monomeric flakes by using steam, and drum dryer (3.83 ± 0.03 mg CYE/g db), flakes by the technique of steam, and cabinet dryer (3.03 ± 0.02 mg CYE/g db), flakes with techniques bake, drum dryer (2.49 ± 0.05 CYE mg/g db), flakes with bake technique, cabinet dryer (1.98 ± 0.03 mg CYE/g db). The Color of purple sweet potato flakes produced through steamed techniques bright purple, while the color purple sweet potato flakes produced through techniques roast give a brownish purple color. The amount of β-carotene yellow flakes sweet potato with stages of cooking steamed, drum dryer (152±0.5 mg/Kg db), grilled drum dryer (136±0.4 mg/Kg db), flakes of yellow sweet potato with stages of roasted and cabinet dryer (140±0.8 mg/Kg db), and grilled stage with cabinet dryer (122±0.3 mg/Kg db). In conclusion sweet potato flakes production techniques through the stages of steam process, and used drum dryers have a number of anthocyanins or β-carotene bigger and brighter colors than the baked flakes techniques and used cabinet dryer.

Ceramic oxygen transport membrane array reactor and reforming method

DOEpatents

Kelly, Sean M.; Christie, Gervase Maxwell; Robinson, Charles; Wilson, Jamie R; Gonzalez, Javier E.; Doraswami, Uttam R.

2017-10-03

The invention relates to a commercially viable modular ceramic oxygen transport membrane system for utilizing heat generated in reactively-driven oxygen transport membrane tubes to generate steam, heat process fluid and/or provide energy to carry out endothermic chemical reactions. The system provides for improved thermal coupling of oxygen transport membrane tubes to steam generation tubes or process heater tubes or reactor tubes for efficient and effective radiant heat transfer.

Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper

DOE Office of Scientific and Technical Information (OSTI.GOV)

A.M. Gandrik

2012-04-01

This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

Application of CaO-Based Bed Material for Dual Fluidized Bed Steam Biomass Gasification

NASA Astrophysics Data System (ADS)

Koppatz, S.; Pfeifer, C.; Kreuzeder, A.; Soukup, G.; Hofbauer, H.

Gasification of biomass is a suitable option for decentralized energy supply based on renewable sources in the range of up to 50 MW fuel input. The paper presents the dual fluidized bed (DFB) steam gasification process, which is applied to generate high quality and nitrogen-free product gas. Essential part of the DFB process is the bed material used in the fluidized reactors, which has significant impact on the product gas quality. By the use of catalytically active bed materials the performance of the overall process is increased, since the bed material favors reactions of the steam gasification. In particular, tar reforming reactions are favored. Within the paper, the pilot plant based on the DFB process with 100kW fuel input at Vienna University of Technology, Austria is presented. Actual investigations with focus on CaO-based bed materials (limestone) as well as with natural olivine as bed material were carried out at the pilot plant. The application of CaO-based bed material shows mainly decreased tar content in the product gas in contrast to experiments with olivine as bed material. The paper presents the results of steam gasification experiments with limestone and olivine, whereby the product gas composition as well as the tar content and the tar composition are outlined.

Optical wet steam monitor

DOEpatents

Maxey, L.C.; Simpson, M.L.

1995-01-17

A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

New features and applications of PRESTO, a computer code for the performance of regenerative, superheated steam turbine cycles

NASA Technical Reports Server (NTRS)

Choo, Y. K.; Staiger, P. J.

1982-01-01

The code was designed to analyze performance at valves-wide-open design flow. The code can model conventional steam cycles as well as cycles that include such special features as process steam extraction and induction and feedwater heating by external heat sources. Convenience features and extensions to the special features were incorporated into the PRESTO code. The features are described, and detailed examples illustrating the use of both the original and the special features are given.

Optical wet steam monitor

DOEpatents

Maxey, Lonnie C.; Simpson, Marc L.

1995-01-01

A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

Steam Hydrocarbon Cracking and Reforming

ERIC Educational Resources Information Center

Golombok, Michael

2004-01-01

The interactive methods of steam hydrocarbon reforming and cracking of the oil and chemical industries are scrutinized, with special focus on their resemblance and variations. The two methods are illustrations of equilibrium-controlled and kinetically-controlled processes, the analysis of which involves theories, which overlap and balance each…

LABORATORY MICROCOSM EXPERIMENTS OF OXIDATION PROCESSES AFTER STEAM INJECTION

EPA Science Inventory

Aggressive thermal methods such as steam injection or resistive heating are known to be effective for the recovery of many types of volatile and semivolatile compounds. It has been suggested that oxidation or other chemical reactions that occur at remediation temperatures can ai...

Double-wall tubing for oil recovery

NASA Technical Reports Server (NTRS)

Back, L. H.; Carroll, W. F.; Jaffee, L. D.; Stimpson, L. D.

1980-01-01

Insulated double-wall tubing designed for steam injection oil recovery makes process more economical and allows deeper extension of wells. Higher quality wet steam is delivered through tubing to oil deposits with significant reductions in heat loss to surrounding rock allowing greater exploitation of previously unworkable reservoirs.

Contents Changes of Triterpenic Acids, Nucleosides, Nucleobases, and Saccharides in Jujube (Ziziphus jujuba) Fruit During the Drying and Steaming Process.

PubMed

Guo, Sheng; Duan, Jin-Ao; Zhang, Ying; Qian, Dawei; Tang, Yuping; Zhu, Zhenhua; Wang, Hanqing

2015-12-12

Chinese jujube (Ziziphus jujuba), a medicinal and edible plant, is widely consumed in Asian countries owing to the remarkable health activities of its fruits. To facilitate selection of the suitable processing method for jujube fruits, in this study their contents of triterpenic acids, nucleosides, nucleobases and saccharides after drying and steaming treatment were determined using ultra-high performance liquid chromatography and high performance liquid chromatography coupled with evaporative light scattering detector methods. The results showed that except for sucrose, the content levels of most analytes were increasing in the jujube fruits during drying treatment at 45 °C. The levels of cyclic nucleotides such as adenosine 3',5'-cyclic monophosphate and guanosine 3',5'-cyclic monophosphate, were significantly decreased after the fruits were steamed. Therefore, owing to the bioactivities of these components for human health, the dried fruits would be the better choice as medicinal material or functional food, and dried jujube fruit should not be further steamed.

Coupling of a 2.5 kW steam reformer with a 1 kW el PEM fuel cell

NASA Astrophysics Data System (ADS)

Mathiak, J.; Heinzel, A.; Roes, J.; Kalk, Th.; Kraus, H.; Brandt, H.

The University of Duisburg-Essen has developed a compact multi-fuel steam reformer suitable for natural gas, propane and butane. This steam reformer was combined with a polymer electrolyte membrane fuel cell (PEM FC) and a system test of the process chain was performed. The fuel processor comprises a prereformer step, a primary reformer, water gas shift reactors, a steam generator, internal heat exchangers in order to achieve an optimised heat integration and an external burner for heat supply as well as a preferential oxidation step (PROX) as CO purification. The fuel processor is designed to deliver a thermal hydrogen power output from 500 W to 2.5 kW. The PEM fuel cell stack provides about 1 kW electrical power. In the following paper experimental results of measurements of the single components PEM fuel cell and fuel processor as well as results of the coupling of both to form a process chain are presented.

A comparison of essential oils obtained from lavandin via different extraction processes: Ultrasound, microwave, turbohydrodistillation, steam and hydrodistillation.

PubMed

Périno-Issartier, Sandrine; Ginies, Christian; Cravotto, Giancarlo; Chemat, Farid

2013-08-30

A total of eight extraction techniques ranging from conventional methods (hydrodistillation (HD), steam distillation (SD), turbohydrodistillation (THD)), through innovative techniques (ultrasound assisted extraction (US-SD) and finishing with microwave assisted extraction techniques such as In situ microwave-generated hydrodistillation (ISMH), microwave steam distillation (MSD), microwave hydrodiffusion and gravity (MHG), and microwave steam diffusion (MSDf)) were used to extract essential oil from lavandin flowers and their results were compared. Extraction time, yield, essential oil composition and sensorial analysis were considered as the principal terms of comparison. The essential oils extracted using the more innovative processes were quantitatively (yield) and qualitatively (aromatic profile) similar to those obtained from the conventional techniques. The method which gave the best results was the microwave hydrodiffusion and gravity (MHG) method which gave reduced extraction time (30min against 220min for SD) and gave no differences in essential oil yield and sensorial perception. Copyright © 2013 Elsevier B.V. All rights reserved.

Steam versus hot-water scalding in reducing bacterial loads on the skin of commercially processed poultry.

PubMed

Patrick, T E; Goodwin, T L; Collins, J A; Wyche, R C; Love, B E

1972-04-01

A comparison of two types of scalders was conducted to determine their effectiveness in reducing bacterial contamination of poultry carcasses. A conventional hot-water scalder and a prototype model of a steam scalder were tested under commercial conditions. Total plate counts from steam-scalded birds were significantly lower than the counts of water-scalded birds immediately after scalding and again after picking. No differences in the two methods could be found after chilling. Coliform counts from steam-scalded birds were significantly lower than the counts from water-scalded birds immediately after scalding. No significant differences in coliform counts were detected when the two scald methods were compared after defeathering and chilling.

Features of steam turbine cooling by the example of an SKR-100 turbine for supercritical steam parameters

NASA Astrophysics Data System (ADS)

Arkadyev, B. A.

2015-10-01

Basic principles of cooling of high-temperature steam turbines and constructive solutions used for development of the world's first cooled steam turbine SKR-100 (R-100-300) are described. Principal differences between the thermodynamic properties of cooling medium in the steam and gas turbines and the preference of making flow passes of cooled cylinders of steam turbines as reactive are shown. Some of its operation results and their conclusions are given. This turbine with a power of 100 MW, initial steam parameters approximately 30 MPa and 650°C, and back pressure 3 MPa was made by a Kharkov turbine plant in 1961 and ran successfully at a Kashira GRES (state district power plant) up to 1979, when it was taken out of use in a still fully operating condition. For comparison, some data on construction features and operation results of the super-high pressure cylinder of steam turbines of American Philo 6 (made by General Electric Co.) and Eddystone 1 (made by Westinghouse Co.) power generating units, which are close to the SKR-100 turbine by design initial steam parameters and the implementation time, are given. The high operational reliability and effectiveness of the cooling system that was used in the super-high pressure cylinder of the SKR-100 turbine of the power-generating unit, which were demonstrated in operation, confirms rightfulness and expediency of principles and constructive solutions laid at its development. As process steam temperatures are increased, the realization of the proposed approach to cooling of multistage turbines makes it possible to limit for large turbine parts the application of new, more expensive high-temperature materials, which are required for making steam boilers, and, in some cases, to do completely away with their utilization.

Food-cooking processes modulate allergenic properties of hen's egg white proteins.

PubMed

Liu, Xiaoyu; Feng, Bai-Sui; Kong, Xiaoli; Xu, Hong; Li, Xiumin; Yang, Ping-Chang; Liu, Zhigang

2013-01-01

Reducing the allergenicity of food allergens can suppress the clinical symptoms of food allergy. The objective of the present study was to investigate the effects of processing on the allergenic properties of hen's egg white proteins. Eggs were processed by traditional Chinese cooking, including steaming, water boiling, frying, spicing and tea boiling. The contents of processed egg protein were assessed by sodium dodecyl sulfate polyacrylamide gel electrophoresis; the allergenicity was evaluated by Western blotting, enzyme-linked immunosorbent assay and enzyme allergosorbent test inhibition. Circular dichroism spectrum analysis of four major egg allergens from various egg products was performed as well. A mouse model of food allergy was developed to test the allergenicity of processed egg protein in vivo. Protein degradation was significant following tea boiling and spiced-tea boiling. The total allergenic potential of water-boiled egg and fried egg was relatively higher than that of steamed egg, spiced egg and tea-boiled egg. Challenge with proteins from raw egg, water-boiled egg and fried egg induced skewed T-helper 2 pattern responses (Th2 responses) in the intestine of mice sensitized to egg proteins; however, when the mice sensitized to egg proteins were challenged with proteins from steamed egg, spiced egg and tea-boiled egg, respectively, only weak Th2 responses were induced in their intestine. Processing by steaming, spicing, or tea boiling can weaken the allergenicity of egg proteins. Copyright © 2012 S. Karger AG, Basel.

Comparative net energy ratio analysis of pellet produced from steam pretreated biomass from agricultural residues and energy crops

DOE PAGES

Shahrukh, Hassan; Oyedun, Adetoyese Olajire; Kumar, Amit; ...

2016-04-05

Here, a process model was developed to determine the net energy ratio (NER) for production of pellets from steam pretreated agricultural residue (AR) and energy crop (i.e. switchgrass in this case). The NER is a ratio of the net energy output to the total net energy input from non-renewable energy sources into a system. Scenarios were developed to measure the effects of temperature and level of steam pretreatment on the NER of steam pretreated AR- and switch grass-based pellets. The NER for the base case at 6 kg h -1 is 1.76 and 1.37 for steam-pretreated AR- and switchgrass-based pellets,more » respectively. The reason behind the difference is that more energy is required to dry switchgrass pellets than AR pellets. The sensitivity analysis for the model shows that the optimum temperature for steam pretreatment is 160 C with 50% pretreatment (half the feedstock is pretreated, while the rest is undergoes regular pelletization). The uncertainty results for NER for steam pretreated AR and switch grass pellets are 1.62 ± 0.10 and 1.42 ± 0.11, respectively.« less

A New Microstructure Device for Efficient Evaporation of Liquids

NASA Astrophysics Data System (ADS)

Brandner, Juergen J.; Maikowske, Stefan; Vittoriosi, Alice

Evaporation of liquids is of major interest for many topics in process engineering. One of these is chemical process engineering, where evaporation of liquids and generation of superheated steam is mandatory for numerous processes. Generally, this is performed by use of classical pool boiling and evaporation process equipment. Another possibility is creating mixtures of gases and liquids, combined with a heating of this haze. Both methods provide relatively limited performance. Due to the advantages of microstructure devices especially in chemical process engineering [1] the interest in microstructure evaporators and steam generators have been increased through the last decade. In this publication several microstructure devices used for evaporation and generation of steam as well as superheating will be described. Here, normally electrically powered devices containing micro channels as well as non-channel microstructures are used due to better controllability of the temperature level. Micro channel heat exchangers have been designed, manufactured and tested at the Institute for Micro Process Engineering of the Karlsruhe Institute of Technology for more than 15 years. Starting with the famous Karlsruhe Cube, a cross-flow micro channel heat exchanger of various dimensions, not only conventional heat transfer between liquids or gases have been theoretically and experimentally examined but also phase transition from liquids to gases (evaporation) and condensation of liquids. However, the results obtained with sealed microstructure devices have often been unsatisfying. Thus, to learn more onto the evaporation process itself, an electrically powered device for optical inspection of the microstructures and the processes inside has been designed and manufactured [2]. This was further optimized and improved for better controllability and reliable experiments [3]. Exchangeable metallic micro channel array foils as well as an optical inspection of the evaporation process by high-speed videography have been integrated into the experimental setup. Fundamental research onto the influences of the geometry and dimensions of the integrated micro channels, the inlet flow distribution system geometry as well as the surface quality and surface coatings of the micro channels have been performed. While evaporation of liquids in crossflow and counterflow or co-current flow micro channel devices is possible, it is, in many cases, not possible to obtain superheated steam due to certain boundary conditions [4]. In most cases, the residence time is not sufficiently long, or the evaporation process itself cannot be stabilized and controlled precisely enough. Thus, a new design was proposed to obtain complete evaporation and steam superheating. This microstructure evaporator consists of a concentric arrangement of semi-circular walls or semi-elliptic walls providing at least two nozzles to release the generated steam. The complete arrangement forms a row of circular blanks. An example of such geometry is shown in Figure 7. A maximum power density of 1400 kW·m-2 has been transferred using similar systems, while liquid could be completely evaporated and the generated steam superheated. This is, compared to liquid heat exchanges, a small value, but it has to be taken in account that the specific heat capacity of vapour is considerably smaller than that of liquids. It could also be shown that the arrangement in circular blanks with semi-elliptic side walls acts as a kind of micro mixer for the remaining liquid and generated steam and, therefore, enhances the evaporation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kohnert, Aaron A.; Dasgupta, Dwaipayan; Wirth, Brian

In order to improve the accident tolerance of light water reactor (LWR) fuel, alternative cladding materials have been proposed to replace zirconium (Zr)-based alloys. Of these materials, there is a particular focus on iron-chromium-aluminum (FeCrAl) alloys due to much slower oxidation kinetics in high-temperature steam than Zr-alloys. This should decrease the energy release due to oxidation and allow the cladding to remain integral longer in the presence of high temperature steam, making accident mitigation more likely. As a continuation of the development for these alloys, the material response must be demonstrated to provide suitable radiation stability, in order to ensuremore » that there will not be significant dimensional changes (e.g., swelling), as well as quantifying the radiation hardening and radiation creep behavior. In this report, we describe the use of cluster dynamics modeling to evaluate the defect physics and damage accumulation behavior of FeCrAl alloys subjected to neutron irradiation, with a particular focus on irradiation-induced swelling and defect fluxes to dislocations that are required to model irradiation creep behavior.« less

Application and optimisation of air-steam cooking on selected vegetables: impact on physical and antioxidant properties.

PubMed

Paciulli, Maria; Dall'Asta, Chiara; Rinaldi, Massimiliano; Pellegrini, Nicoletta; Pugliese, Alessandro; Chiavaro, Emma

2018-04-01

Several studies investigated the impact of different cooking techniques on the quality of vegetables. However, the use of the combined air-steam cooking is still scarcely debated, despite the advantages informally referred by professional catering workers. In this study, its optimisation was studied on Brussels sprouts and pumpkin cubes to obtain the best physical (texture, colour) and antioxidant (FRAP, total phenols) response, in comparison to a conventional steaming treatment. Increasing the strength of the air-steam treatment, Brussels sprouts resulted to be softer, less green (higher a* value), richer in phenols and exhibited lower FRAP values than the steamed ones. The air-steamed pumpkin cubes exhibited an equivalent softening degree to that of steamed ones and, under the strongest cooking conditions, a higher antioxidant quality and a yellow darkening (lower b* value). Varying the cooking time and/or temperature, a linear change of force/compression hardness and a* (negative a*: greenness) for Brussels sprouts, b* (yellowness) and total phenol content for pumpkin cubes was observed. A predictive model for these variables was obtained by response surface methodology. The best process conditions to achieve the optimal desirability were also identified. The application of air-steam cooking under suitable time/temperature conditions could be proposed as an alternative method to a traditional steam cooking on Brussels sprouts and pumpkin cubes, being able to preserve or improve their quality. The best air-steam cooking conditions were 25 min at 90 °C for Brussels sprouts and 10 min at 110 °C for pumpkin. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon

DOEpatents

Sircar, Shivaji; Hufton, Jeffrey Raymond; Nataraj, Shankar

2000-01-01

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Bo; Lu, Hongyou; Price, Lynn K.

In the U.S., energy consumption by steam and process heat combined accounts for over 50% of the total energy use from industrial systems (see Figure 1). The use of boilers, process heaters, and furnaces for generating steam and heat in industrial facilities, commercial settings, and institutions consumes significant amounts of energy and is one of major sources of hazardous air pollutants, which contribute significantly to local pollution and global climate change. To address the energy and environmental challenges caused by boiler systems in the U.S., the country has taken a series of actions to reduce emissions from industrial, commercial andmore » institutional boilers, improve the efficiency of steam systems, replace coal with cleaner energy resources, and promote the wider use of combined heat and power (CHP).« less

Processing urinary endoscopes in a low-temperature steam and formaldehyde autoclave.

PubMed Central

Gibson, G L

1977-01-01

Methods of disinfection and sterilisation of urinary endoscopes are considered. A small mobile low-temperature steam and formaldehyde autoclave (Miniclave 80) is evaluated and shown to be satisfactory for this purpose as judged by a variety of relevant microbiological test pieces. Images PMID:557503

EVALUATION OF STATIONARY SOURCE PARTICULATE MEASUREMENT METHODS. VOLUME II. OIL-FIRED STEAM GENERATORS

EPA Science Inventory

An experimental study was conducted to determine the reliability of the Method 5 procedure for providing particulate emission data from an oil-fired steam generator. The study was concerned with determining whether any 'false' particulate resulted from the collection process of f...

SITE TECHNOLOGY CAPSULE: IN SITU STEAM ENHANCED RECOVERY PROCESS

EPA Science Inventory

The SERP technology is designed to treat soils contaminated with VOCs and SVOCs in situ. Steam injection and vacuum extraction are used to remove the organic compounds from the soil and concentrate them for disposal or recycling. A full-scale demonstration of SERP was conducted a...

Cogeneration systems and processes for treating hydrocarbon containing formations

DOEpatents

Vinegar, Harold J [Bellaire, TX; Fowler, Thomas David [Houston, TX; Karanikas, John Michael [Houston, TX

2009-12-29

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Phenols recovery after steam explosion of Olive Mill Solid Waste and its influence on a subsequent biomethanization process.

PubMed

Serrano, Antonio; Fermoso, Fernando G; Alonso-Fariñas, Bernabé; Rodríguez-Gutierrez, Guillermo; Fernandez-Bolaños, Juan; Borja, Rafael

2017-11-01

A promising source of high added value compounds is the Olive Mill Solid Waste (OMSW). The aim of this research was to evaluate the viability of a biorefinery approach to valorize OMSW through the combination of steam explosion, phenols extraction, and anaerobic digestion. Steam explosion treatment increased the total phenol content in the steam exploited OMSW, which was twice than that the total phenol content in raw OMSW, although some undesirable compounds were also formed. Phenol extraction allowed the recovery of 2098mg hydroxytyrosol per kg of OMSW. Anaerobic digestion allowed the partial stabilization of the different substrates, although it was not improved by the steam explosion treatment. The economic suitability of the proposed biorefinery approach is favorable up to a phenol extract price 90.7% lower than the referenced actual price of 520€/kg. Copyright © 2017 Elsevier Ltd. All rights reserved.

Practical achievements on biomass steam gasification in a rotary tubular coiled-downdraft reactor.

PubMed

Andrew, Renny; Gokak, D T; Sharma, Pankaj; Gupta, Shalini

2016-12-01

Today, the impending stringent environmental norms and concerns about the depletion of fossil fuel reserves have added impetus on development of cutting edge technologies for production of alternative fuels from renewable sources, like biomass. The concept of biomass pyro-gasification offers a platform for production of (a) hydrogen, (b) hydrocarbons and (c) value added chemicals, etc. In this context, there exists potential for hydrogen production from biomass by superheated steam gasification. Apart from H 2 , gaseous products of biomass steam gasification contain CO, CH 4 and other hydrocarbons that can be converted to hydrogen through cracking, steam reforming and water gas shift reactions. In the present work, the characteristics of biomass steam gasification in an indigenously designed rotary tubular coiled-downdraft reactor for high value gaseous fuel production from rice husk was studied through a series of experiments. The robust reactor system enhances biomass conversion to gaseous products by improved mass and heat transfer within the system induced by a coiled flow pattern with increased heat transfer area. Also, the system has improved upon the reliability of operation and offered greater continuity of the process and easier control in comparison with a conventional process by making use of an innovative gas cooler assembly and efficient venturi-mixing system for biomass and steam. Subsequently, the effects of reactor temperature, steam-to-biomass ratio and residence time on overall product gas yield and hydrogen yield were investigated. From the experimental results, it can be deduced that an optimum reactor temperature of 750 °C, steam-to-biomass ratio of 2.0 and a residence time of 3.0 min contributed highest gas yield (1.252 Nm 3  kg -1 moisture-free biomass). Based on the obtained experimental results, a projected potential hydrogen yield of 8.6 wt% of the moisture-free biomass could be achieved, and is also practical for production of pure hydrogen. © The Author(s) 2016.

Evidence of technetium and iodine release from a sodalite-bearing ceramic waste form

DOE PAGES

Neeway, James J.; Qafoku, Nikolla P.; Williams, Benjamin D.; ...

2015-12-31

We proposed sodalites as a possible host of certain radioactive species, specifically 99Tc and 129I, which may be encapsulated into the cage structure of the mineral. To demonstrate the ability of this framework silicate mineral to encapsulate and immobilize 99Tc and 129I, single-pass flow-through (SPFT) tests were conducted on a sodalite-bearing multi-phase ceramic waste form produced through a steam reforming process. We produced two samples made using a steam reformer samples using nonradioactive I and Re (as a surrogate for Tc), while a third sample was produced using actual radioactive tank waste containing Tc and added Re. One of themore » non-radioactive samples was produced with an engineering-scale steam reformer while the other non-radioactive sample and the radioactive sample were produced using a bench-scale steam reformer. For all three steam reformer products, the similar steady-state dilute-solution release rates for Re, I, and Tc at pH (25 C) 9 and 40 C were measured. However, it was found that the Re, I, and Tc releases were equal or up to 4.5x higher compared to the release rates of the network-forming elements, Na, Al, and Si. Moreover, the similar releases of Re and Tc in the SPFT test, and the similar time-dependent shapes of the release curves for samples containing I, suggest that Re, Tc, and I partition to the sodalite minerals during the steam reforming process.« less

Energy alternative for industry: the high-temperature gas-cooled reactor steamer

DOE Office of Scientific and Technical Information (OSTI.GOV)

McMain, A.T. Jr.; Blok, F.J.

1978-04-01

Large industrial complexes are faced with new requirements that will lead to a transition from such fluid fuels as natural gas and oil to such solid fuels as coal and uranium for supply of industrial energy. Power plants using these latter fuels will be of moderate size (800 to 1200 MW(thermal)) and will generally have the capability of co-generating electric power and process steam. A study has been made regarding use of the 840-MW(thermal) Fort St. Vrain high-temperature gas-cooled reactor (HTGR) design for industrial applications. The initial conceptual design (referred to as the HTGR Steamer) is substantially simplified relative tomore » Fort St. Vrain in that outlet helium and steam temperatures are lower and the reheat section is deleted from the steam generators. The Steamer has four independent steam generating loops producing a total of 277 kg/s (2.2 x 10/sup 6/ lb/h) of prime steam at 4.5 MPa/672 K (650 psia/750/sup 0/F). The unit co-generates 46 MW(electric) and provides process steam at 8.31 MPa/762 K(1200 psia/912/sup 0/F). The basic configuration and much of the equipment are retained from the Fort St. Vrain design. The system has inherent safety features important for industrial applications. These and other features indicate that the HTGR Steamer is an industrial energy option deserving additional evaluation. Subsequent work will focus on parallel design optimization and application studies.« less

Microbial safety and overall quality of cantaloupe fresh-cut pieces prepared from whole fruit after wet steam treatment.

PubMed

Ukuku, Dike O; Geveke, David J; Chau, Lee; Niemira, Brendan A

2016-08-16

Fresh-cut cantaloupes have been associated with outbreaks of Salmonellosis. Minimally processed fresh-cut fruits have a limited shelf life because of deterioration caused by spoilage microflora and physiological processes. The objectives of this study were to use a wet steam process to 1) reduce indigenous spoilage microflora and inoculated populations of Salmonella, Escherichia coli O157:H7 and Listeria monocytogenes on the surface of cantaloupes, and 2) reduce the populations counts in cantaloupe fresh-cut pieces after rind removal and cutting. The average inocula of Salmonella, E. coli O157:H7 and Listeria monocytogenes was 10(7)CFU/ml and the populations recovered on the cantaloupe rind surfaces after inoculation averaged 4.5, 4.8 and 4.1logCFU/cm(2), respectively. Whole cantaloupes were treated with a wet steam processing unit for 180s, and the treated melons were stored at 5°C for 29days. Bacterial populations in fresh-cut pieces prepared from treated and control samples stored at 5 and 10°C for up to 12days were determined and changes in color (CIE L*, a*, and b*) due to treatments were measured during storage. Presence and growth of aerobic mesophilic bacteria and Salmonella, E. coli O157:H7 and L. monocytogenes were determined in fresh-cut cantaloupe samples. There were no visual signs of physical damage on all treated cantaloupe surfaces immediately after treatments and during storage. All fresh-cut pieces from treated cantaloupes rind surfaces were negative for bacterial pathogens even after an enrichment process. Steam treatment significantly (p<0.05) changed the color of the fresh-cut pieces. Minimal wet steam treatment of cantaloupes rind surfaces designated for fresh-cut preparation will enhance the microbial safety of fresh-cut pieces, by reducing total bacterial populations. This process holds the potential to significantly reduce the incidence of foodborne illness associated with fresh-cut fruits. Published by Elsevier B.V.

Effects of combined traditional processing methods on the nutritional quality of beans.

PubMed

Nakitto, Aisha M; Muyonga, John H; Nakimbugwe, Dorothy

2015-05-01

Consumption of dry beans is limited by long cooking times thus high fuel requirement. The bioavailability of nutrients in beans is also limited due to presence of antinutrients such as phytates and tannins. Little research has been done on combined processing methods for production of nutritious fast cooking bean flour and the effect of combined treatments on nutritional quality of beans has not previously determined. The aim of this study was to reduce cooking time and enhance the nutritional value of dry beans. Specifically to: develop protocols for production of fast cooking bean flours and assess the effect of processing on the nutritional characteristics of the flours. Dry beans (K131 variety) were soaked for 12 h; sprouted for 48 h; dehulled and steamed for 25 and 15 min for whole and dehulled beans respectively or roasted at 170°C for 45 and 15 min for whole and dehulled beans respectively. Dehulling eliminated phytates and tannins and increased protein digestibility. In vitro protein digestibility and mineral (iron and zinc) extractability were negatively correlated with tannin and phytate content. Total available carbohydrates were highest in moist heat-treated bean flours. Overall, combined processing of beans improved the nutritional quality of dry beans and the resulting precooked flours need less cooking time compared to whole dry beans.

Effects of combined traditional processing methods on the nutritional quality of beans

PubMed Central

Nakitto, Aisha M; Muyonga, John H; Nakimbugwe, Dorothy

2015-01-01

Consumption of dry beans is limited by long cooking times thus high fuel requirement. The bioavailability of nutrients in beans is also limited due to presence of antinutrients such as phytates and tannins. Little research has been done on combined processing methods for production of nutritious fast cooking bean flour and the effect of combined treatments on nutritional quality of beans has not previously determined. The aim of this study was to reduce cooking time and enhance the nutritional value of dry beans. Specifically to: develop protocols for production of fast cooking bean flours and assess the effect of processing on the nutritional characteristics of the flours. Dry beans (K131 variety) were soaked for 12 h; sprouted for 48 h; dehulled and steamed for 25 and 15 min for whole and dehulled beans respectively or roasted at 170°C for 45 and 15 min for whole and dehulled beans respectively. Dehulling eliminated phytates and tannins and increased protein digestibility. In vitro protein digestibility and mineral (iron and zinc) extractability were negatively correlated with tannin and phytate content. Total available carbohydrates were highest in moist heat-treated bean flours. Overall, combined processing of beans improved the nutritional quality of dry beans and the resulting precooked flours need less cooking time compared to whole dry beans. PMID:25987998

Effects of Steaming Time and Frequency for Manufactured Red Liriope platyphylla on the Insulin Secretion Ability and Insulin Receptor Signaling Pathway.

PubMed

Choi, Sun Il; Lee, Hye Ryun; Goo, Jun Seo; Kim, Ji Eun; Nam, So Hee; Hwang, In Sik; Lee, Young Ju; Prak, So Hae; Lee, Hee Seob; Lee, Jong Sup; Jang, In Surk; Son, Hong Ju; Hwang, Dae Youn

2011-06-01

In oriental medicine, Liriope platyphylla (LP) has long been regarded as a curative herb useful for the treatment of diabetes, asthma, and neurodegenerative disorders. The principal objective of this study was to assess the effects of steaming time and frequency for manufactured Red LP (RLP) on insulin secretion ability and insulin receptor signaling pathway. To achieve our goal, several types of LPs manufactured under different conditions were applied to INS cells and streptozotocin (STZ)-induced diabetic ICR mice, after which alterations in insulin concentrations were detected in the culture supernatants and sera. The optimal concentration for the investigation of insulin secretion ability was found to be 50 ug/mL of LP. At this concentration, maximum insulin secretion was observed in the INS cells treated with LP extract steamed for 3 h (3-SLP) with two repeated steps (3 h steaming and 24 h air-dried) carried out 9 times (9-SALP); no significant changes in viability were detected in any of the treated cells. Additionally, the expression and phosphorylation levels of most components in the insulin receptor signaling pathway were increased significantly in the majority of cells treated with steaming-processed LP as compared to the cells treated with LP prepared without steaming. With regard to glucose transporter (GLUT) expression, alterations of steaming time induced similar responses on the expression levels of GLUT-2 and GLUT-3. However, differences in steaming frequency were also shown to induce dose-dependent responses in the expression level of GLUT-2 only; no significant differences in GLUT-3 expression were detected under these conditions. Furthermore, these responses observed in vitro were similarly detected in STZ-induced diabetic mice. 24-SLP and 9-SALP treatment applied for 14 days induced the down-regulation of glucose concentration and upregulation of insulin concentration. Therefore, these results indicated that the steaming processed LP may contribute to the relief of diabetes symptoms and should be regarded as an excellent candidate for a diabetes treatment.

Effects of Steaming Time and Frequency for Manufactured Red Liriope platyphylla on the Insulin Secretion Ability and Insulin Receptor Signaling Pathway

PubMed Central

Choi, Sun Il; Lee, Hye Ryun; Goo, Jun Seo; Kim, Ji Eun; Nam, So Hee; Hwang, In Sik; Lee, Young Ju; Prak, So Hae; Lee, Hee Seob; Lee, Jong Sup; Jang, In Surk; Son, Hong Ju

2011-01-01

In oriental medicine, Liriope platyphylla (LP) has long been regarded as a curative herb useful for the treatment of diabetes, asthma, and neurodegenerative disorders. The principal objective of this study was to assess the effects of steaming time and frequency for manufactured Red LP (RLP) on insulin secretion ability and insulin receptor signaling pathway. To achieve our goal, several types of LPs manufactured under different conditions were applied to INS cells and streptozotocin (STZ)-induced diabetic ICR mice, after which alterations in insulin concentrations were detected in the culture supernatants and sera. The optimal concentration for the investigation of insulin secretion ability was found to be 50 ug/mL of LP. At this concentration, maximum insulin secretion was observed in the INS cells treated with LP extract steamed for 3 h (3-SLP) with two repeated steps (3 h steaming and 24 h air-dried) carried out 9 times (9-SALP); no significant changes in viability were detected in any of the treated cells. Additionally, the expression and phosphorylation levels of most components in the insulin receptor signaling pathway were increased significantly in the majority of cells treated with steaming-processed LP as compared to the cells treated with LP prepared without steaming. With regard to glucose transporter (GLUT) expression, alterations of steaming time induced similar responses on the expression levels of GLUT-2 and GLUT-3. However, differences in steaming frequency were also shown to induce dose-dependent responses in the expression level of GLUT-2 only; no significant differences in GLUT-3 expression were detected under these conditions. Furthermore, these responses observed in vitro were similarly detected in STZ-induced diabetic mice. 24-SLP and 9-SALP treatment applied for 14 days induced the down-regulation of glucose concentration and upregulation of insulin concentration. Therefore, these results indicated that the steaming processed LP may contribute to the relief of diabetes symptoms and should be regarded as an excellent candidate for a diabetes treatment. PMID:21826171

Influence of processing on the allergenic properties of pistachio nut assessed in vitro.

PubMed

Noorbakhsh, Reihaneh; Mortazavi, Seyed Ali; Sankian, Mojtaba; Shahidi, Fakhri; Maleki, Soheila J; Nasiraii, Leila Roozbeh; Falak, Reza; Sima, Hamid Reza; Varasteh, AbdolReza

2010-09-22

Pistachio (Pistacia vera) is a tree nut that has been reported to cause IgE-mediated allergic reactions. This study was undertaken to investigate the distinctions between different cultivars of pistachio nut and the influence of different processing on the IgE-binding capacity of whole pistachio protein extracts. The influence of different processes on allergenicity was investigated using competitive inhibition ELISA and Western blotting assays. The Western blotting results of extracts from pistachio cultivars showed no marked difference among them. The IgE-binding capacity was significantly lower for the protein extract prepared from steam-roasted than from raw and dry-roasted pistachio nuts. The results of sensory evaluation analysis and hedonic rating proved no significant differences in color, taste, flavor, and overall quality of raw, roasted, and steam-roasted pistachio nut treatments. The most significant finding of the present study was the successful reduction of IgE-binding by pistachio extracts using steam-roast processing without any significant changes in sensory quality of product.

Nanoparticulate-catalyzed oxygen transfer processes

DOEpatents

Hunt, Andrew T [Atlanta, GA; Breitkopf, Richard C [Dunwoody, GA

2009-12-01

Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

Conceptual Design of Low-Temperature Hydrogen Production and High-Efficiency Nuclear Reactor Technology

NASA Astrophysics Data System (ADS)

Fukushima, Kimichika; Ogawa, Takashi

Hydrogen, a potential alternative energy source, is produced commercially by methane (or LPG) steam reforming, a process that requires high temperatures, which are produced by burning fossil fuels. However, as this process generates large amounts of CO2, replacement of the combustion heat source with a nuclear heat source for 773-1173K processes has been proposed in order to eliminate these CO2 emissions. In this paper, a novel method of nuclear hydrogen production by reforming dimethyl ether (DME) with steam at about 573K is proposed. From a thermodynamic equilibrium analysis of DME steam reforming, the authors identified conditions that provide high hydrogen production fraction at low pressure and temperatures of about 523-573K. By setting this low-temperature hydrogen production process upstream from a turbine and nuclear reactor at about 573K, the total energy utilization efficiency according to equilibrium mass and heat balance analysis is about 50%, and it is 75%for a fast breeder reactor (FBR), where turbine is upstream of the reformer.

Steam atmosphere dryer project: System development and field test. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-02-01

The objective of this project was to develop and demonstrate the use of a superheated steam atmosphere dryer as a highly improved alternative to conventional hot air-drying systems, the present industrial standard method for drying various wet feedstocks. The development program plan consisted of three major activities. The first was engineering analysis and testing of a small-scale laboratory superheated steam dryer. This dryer provided the basic engineering heat transfer data necessary to design a large-scale system. The second major activity consisted of the design, fabrication, and laboratory checkout testing of the field-site prototype superheated steam dryer system. The third majormore » activity consisted of the installation and testing of the complete 250-lb/hr evaporation rate dryer and a 30-kW cogeneration system in conjunction with an anaerobic digester facility at the Village of Bergen, NY. Feedstock for the digester facility at the Village of Bergen, NY. Feedstock for the digester was waste residue from a nearby commercial food processing plant. The superheated steam dryer system was placed into operation in August 1996 and operated successfully through March 1997. During this period, the dryer processed all the material from the digester to a powdered consistency usable as a high-nitrogen-based fertilizer.« less

Effects of gamma and electron beam irradiation on the microbial quality of steamed tofu rolls

NASA Astrophysics Data System (ADS)

Jia, Qian; Gao, Meixu; Li, Shurong; Wang, Zhidong

2013-01-01

The effectiveness of two kinds of radiation processing, gamma and electron beam (ebeam) irradiation, for the inactivation of Staphylococcus aureus, Salmonella enteritidis and Listeria innocua which were inoculated in pre-sterilised steamed tofu rolls was studied. The corresponding effects of both irradiation types on total bacterial counts (TBCs) in commercial steamed tofu rolls available in the market were also examined. The microbiological results demonstrated that gamma irradiation yielded D10 values of 0.20, 0.24 and 0.22 kGy for S. aureus, S. enteritidis and L. innocua, respectively. The respective D10 values for ebeam irradiation were 0.31, 0.35 and 0.27 kGy. Gamma and ebeam irradiation yielded D10 values of 0.48 and 0.43 kGy for total bacterial counts in commercial steamed tofu rolls, respectively. The results suggest that ebeam irradiation has similar effect on decreasing TBCs in steamed tofu rolls, and gamma irradiation is slightly more effective than ebeam irradiation in reducing the populations of pathogenic bacteria. The observed differences in D10-values between them might be due to the significant differences in dose rate applied, and radiation processing of soybean products to improve their microbial quality could be available for other sources of protein.

Central waste processing system

NASA Technical Reports Server (NTRS)

Kester, F. L.

1973-01-01

A new concept for processing spacecraft type wastes has been evaluated. The feasibility of reacting various waste materials with steam at temperatures of 538 - 760 C in both a continuous and batch reactor with residence times from 3 to 60 seconds has been established. Essentially complete gasification is achieved. Product gases are primarily hydrogen, carbon dioxide, methane, and carbon monoxide. Water soluble synthetic wastes are readily processed in a continuous tubular reactor at concentrations up to 20 weight percent. The batch reactor is able to process wet and dry wastes at steam to waste weight ratios from 2 to 20. Feces, urine, and synthetic wastes have been successfully processed in the batch reactor.

Process for making unsaturated hydrocarbons using microchannel process technology

DOEpatents

Tonkovich, Anna Lee [Dublin, OH; Yuschak, Thomas [Lewis Center, OH; LaPlante, Timothy J [Columbus, OH; Rankin, Scott [Columbus, OH; Perry, Steven T [Galloway, OH; Fitzgerald, Sean Patrick [Columbus, OH; Simmons, Wayne W [Dublin, OH; Mazanec, Terry Daymo, Eric

2011-04-12

The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

Intraconversion of Polar Ginsenosides, Their Transformation into Less-Polar Ginsenosides, and Ginsenoside Acetylation in Ginseng Flowers upon Baking and Steaming.

PubMed

Li, Xiang; Yao, Fan; Fan, Hang; Li, Ke; Sun, Liwei; Liu, Yujun

2018-03-26

Heating is a traditional method used in ginseng root processing, however, there aren't reports on differences resulting from baking and steaming. Moreover, ginseng flowers, with 5.06 times more total saponins than ginseng root, are not fully taken advantage of for their ginsenosides. Transformation mechanisms of ginsenosides in ginseng flowers upon baking and steaming were thus explored. HPLC using authentic standards of 20 ginsenosides and UPLC-QTOF-MS/MS were used to quantify and identify ginsenosides, respectively, in ginseng flowers baked or steamed at different temperatures and durations. Results show that baking and steaming caused a 3.2-fold increase in ginsenoside species existed in unheated ginseng flowers (20/64 ginsenosides) and transformation of a certain amount of polar ginsenosides into numerous less polar ginsenosides. Among the 20 ginsenosides with standards, polar ginsenosides were abundant in ginseng flowers baked or steamed at lower temperatures, whereas less polar ginsenosides occurred and were enriched at higher temperatures. Furthermore, the two types of heating treatments could generate mostly similar ginsenosides, but steaming was much efficient than baking in transforming polar- into less polar ginsenosides, with steaming at 120 °C being comparably equivalent to baking at 150 °C. Moreover, both the two heating methods triggered ginsenoside acetylation and thus caused formation of 16 acetylginsenosides. Finally, a new transformation mechanism concerning acetyl-ginsenosides formation was proposed.

Macroporous Double-Network Hydrogel for High-Efficiency Solar Steam Generation Under 1 sun Illumination.

PubMed

Yin, Xiangyu; Zhang, Yue; Guo, Qiuquan; Cai, Xiaobing; Xiao, Junfeng; Ding, Zhifeng; Yang, Jun

2018-04-04

Solar steam generation is one of the most promising solar-energy-harvesting technologies to address the issue of water shortage. Despite intensive efforts to develop high-efficiency solar steam generation devices, challenges remain in terms of the relatively low solar thermal efficiency, complicated fabrications, high cost, and difficulty in scaling up. Herein, a double-network hydrogel with a porous structure (p-PEGDA-PANi) is demonstrated for the first time as a flexible, recyclable, and efficient photothermal platform for low-cost and scalable solar steam generation. As a novel photothermal platform, the p-PEGDA-PANi involves all necessary properties of efficient broadband solar absorption, exceptional hydrophilicity, low heat conductivity, and porous structure for high-efficiency solar steam generation. As a result, the hydrogel-based solar steam generator exhibits a maximum solar thermal efficiency of 91.5% with an evaporation rate of 1.40 kg m -2 h -1 under 1 sun illumination, which is comparable to state-of-the-art solar steam generation devices. Furthermore, the good durability and environmental stability of the p-PEGDA-PANi hydrogel enables a convenient recycling and reusing process toward real-life applications. The present research not only provides a novel photothermal platform for solar energy harvest but also opens a new avenue for the application of the hydrogel materials in solar steam generation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shahrukh, Hassan; Oyedun, Adetoyese Olajire; Kumar, Amit

Here, a process model was developed to determine the net energy ratio (NER) for production of pellets from steam pretreated agricultural residue (AR) and energy crop (i.e. switchgrass in this case). The NER is a ratio of the net energy output to the total net energy input from non-renewable energy sources into a system. Scenarios were developed to measure the effects of temperature and level of steam pretreatment on the NER of steam pretreated AR- and switch grass-based pellets. The NER for the base case at 6 kg h -1 is 1.76 and 1.37 for steam-pretreated AR- and switchgrass-based pellets,more » respectively. The reason behind the difference is that more energy is required to dry switchgrass pellets than AR pellets. The sensitivity analysis for the model shows that the optimum temperature for steam pretreatment is 160 C with 50% pretreatment (half the feedstock is pretreated, while the rest is undergoes regular pelletization). The uncertainty results for NER for steam pretreated AR and switch grass pellets are 1.62 ± 0.10 and 1.42 ± 0.11, respectively.« less

System and method for coproduction of activated carbon and steam/electricity

DOEpatents

Srinivasachar, Srivats [Sturbridge, MA; Benson, Steven [Grand Forks, ND; Crocker, Charlene [Newfolden, MN; Mackenzie, Jill [Carmel, IN

2011-07-19

A system and method for producing activated carbon comprising carbonizing a solid carbonaceous material in a carbonization zone of an activated carbon production apparatus (ACPA) to yield a carbonized product and carbonization product gases, the carbonization zone comprising carbonaceous material inlet, char outlet and carbonization gas outlet; activating the carbonized product via activation with steam in an activation zone of the ACPA to yield activated carbon and activation product gases, the activation zone comprising activated carbon outlet, activation gas outlet, and activation steam inlet; and utilizing process gas comprising at least a portion of the carbonization product gases or a combustion product thereof; at least a portion of the activation product gases or a combustion product thereof; or a combination thereof in a solid fuel boiler system that burns a solid fuel boiler feed with air to produce boiler-produced steam and flue gas, the boiler upstream of an air heater within a steam/electricity generation plant, said boiler comprising a combustion zone, a boiler-produced steam outlet and at least one flue gas outlet.

J-Band Infrared Spectroscopy of a Sample of Brown Dwarfs Using NIRSPEC on Keck II.

PubMed

McLean; Wilcox; Becklin; Figer; Gilbert; Graham; Larkin; Levenson; Teplitz; Kirkpatrick

2000-04-10

Near-infrared spectroscopic observations of a sample of very cool, low-mass objects are presented with higher spectral resolution than in any previous studies. Six of the objects are L dwarfs, ranging in spectral class from L2 to L8/9, and the seventh is a methane or T dwarf. These new observations were obtained during commissioning of the near-infrared spectrometer (NIRSPEC), the first high-resolution near-infrared cryogenic spectrograph for the Keck II 10 m telescope on Mauna Kea, Hawaii. Spectra with a resolving power of R approximately 2500 from 1.135 to 1.360 µm (approximately J band) are presented for each source. At this resolution, a rich spectral structure is revealed, much of which is due to blending of unresolved molecular transitions. Strong lines due to neutral potassium (K i) and bands due to iron hydride (FeH) and steam (H2O) change significantly throughout the L sequence. Iron hydride disappears between L5 and L8, the steam bands deepen, and the K i lines gradually become weaker but wider because of pressure broadening. An unidentified feature occurs at 1.22 µm that has a temperature dependence like FeH but has no counterpart in the available FeH opacity data. Because these objects are 3-6 mag brighter in the near-infrared compared with the I band, spectral classification is efficient. One of the objects studied (2MASSW J1523+3014) is the coolest L dwarf discovered so far by the 2 Micron All-Sky Survey (2MASS), but its spectrum is still significantly different from the methane-dominated objects such as Gl 229B or SDSS 1624+0029.

Steam Versus Hot-Water Scalding in Reducing Bacterial Loads on the Skin of Commercially Processed Poultry

PubMed Central

Patrick, Thomas E.; Goodwin, T. L.; Collins, J. A.; Wyche, R. C.; Love, B. E.

1972-01-01

A comparison of two types of scalders was conducted to determine their effectiveness in reducing bacterial contamination of poultry carcasses. A conventional hot-water scalder and a prototype model of a steam scalder were tested under commercial conditions. Total plate counts from steam-scalded birds were significantly lower than the counts of water-scalded birds immediately after scalding and again after picking. No differences in the two methods could be found after chilling. Coliform counts from steam-scalded birds were significantly lower than the counts from water-scalded birds immediately after scalding. No significant differences in coliform counts were detected when the two scald methods were compared after defeathering and chilling. PMID:4553146

Doctor William Gunn (1804-1890): From the South Pacific Islands to Chatham Royal Dockyard.

PubMed

Biddle, Richard

2016-11-24

Doctor William Gunn had a long and varied career in the Royal Navy. After spending time on anti-slavery patrols along the west coast of Africa, he was posted to the south Pacific. At Pitcairn Island, he treated the inhabitants during an influenza epidemic, proving himself to be a determined and dedicated practitioner. Subsequently, he was appointed head of the medical department at Chatham Royal Dockyard (1859-1865), an appointment that coincided with the final stages of the Royal Navy's transition from sail and wood to steam and iron. The impact of these changes on the health of dockworkers was quickly felt at Chatham, and Gunn found himself in charge during the building of the first iron warship in a royal dockyard. His story thus offers a window through which to observe a practitioner confronting the health issues and medical uncertainties thrown up by technological change in the Victorian era. © The Author(s) 2016.

Characterisation and Processing of Some Iron Ores of India

NASA Astrophysics Data System (ADS)

Krishna, S. J. G.; Patil, M. R.; Rudrappa, C.; Kumar, S. P.; Ravi, B. P.

2013-10-01

Lack of process characterization data of the ores based on the granulometry, texture, mineralogy, physical, chemical, properties, merits and limitations of process, market and local conditions may mislead the mineral processing entrepreneur. The proper implementation of process characterization and geotechnical map data will result in optimized sustainable utilization of resource by processing. A few case studies of process characterization of some Indian iron ores are dealt with. The tentative ascending order of process refractoriness of iron ores is massive hematite/magnetite < marine black iron oxide sands < laminated soft friable siliceous ore fines < massive banded magnetite quartzite < laminated soft friable clayey aluminous ore fines < massive banded hematite quartzite/jasper < massive clayey hydrated iron oxide ore < manganese bearing iron ores massive < Ti-V bearing magnetite magmatic ore < ferruginous cherty quartzite. Based on diagnostic process characterization, the ores have been classified and generic process have been adopted for some Indian iron ores.

An analytical model of SAGD process considering the effect of threshold pressure gradient

NASA Astrophysics Data System (ADS)

Morozov, P.; Abdullin, A.; Khairullin, M.

2018-05-01

An analytical model is proposed for the development of super-viscous oil deposits by the method of steam-assisted gravity drainage, taking into account the nonlinear filtration law with the limiting gradient. The influence of non-Newtonian properties of oil on the productivity of a horizontal well and the cumulative steam-oil ratio are studied. Verification of the proposed model based on the results of physical modeling of the SAGD process was carried out.

Energy recovery from solid waste. [production engineering model

NASA Technical Reports Server (NTRS)

Dalton, C.; Huang, C. J.

1974-01-01

A recent group study on the problem of solid waste disposal provided a decision making model for a community to use in determining the future for its solid waste. The model is a combination of the following factors: technology, legal, social, political, economic and environmental. An assessment of local or community needs determines what form of energy recovery is desirable. A market for low pressure steam or hot water would direct a community to recover energy from solid waste by incineration to generate steam. A fuel gas could be produced by a process known as pyrolysis if there is a local market for a low heating value gaseous fuel. Solid waste can also be used directly as a fuel supplemental to coal in a steam generator. An evaluation of these various processes is made.

A review of test results on parabolic dish solar thermal power modules with dish-mounted Rankine engines and for production of process steam

NASA Technical Reports Server (NTRS)

Jaffe, Leonard D.

1988-01-01

This paper presents results of development testing of various solar thermal parabolic dish modules and assemblies. Most of the tests were at modules and assemblies that used a dish-mounted, organic Rankine cycle turbine for production of electric power. Some tests were also run on equipment for production of process steam or for production of electricity using dish-mounted reciprocating steam engines. These tests indicate that early modules achieve efficiencies of about 18 percent in converting sunlight to electricity (excluding the inverter but including parasitics). A number of malfunctions occurred. The performance measurements, as well as the malfunctions and other operating experience, provided information that should be of value in developing systems with improved performance and reduced maintenance.

Recovery comparisons--hot nitrogen Vs steam regeneration of toxic dichloromethane from activated carbon beds in oil sands process.

PubMed

Ramalingam, Shivaji G; Pré, Pascaline; Giraudet, Sylvain; Le Coq, Laurence; Le Cloirec, Pierre; Baudouin, Olivier; Déchelotte, Stéphane

2012-02-29

The regeneration experiments of dichloromethane from activated carbon bed had been carried out by both hot nitrogen and steam to evaluate the regeneration performance and the operating cost of the regeneration step. Factorial Experimental Design (FED) tool had been implemented to optimize the temperature of nitrogen and the superficial velocity of the nitrogen to achieve maximum regeneration at an optimized operating cost. All the experimental results of adsorption step, hot nitrogen and steam regeneration step had been validated by the simulation model PROSIM. The average error percentage between the simulation and experiment based on the mass of adsorption of dichloromethane was 2.6%. The average error percentages between the simulations and experiments based on the mass of dichloromethane regenerated by nitrogen regeneration and steam regeneration were 3 and 12%, respectively. From the experiments, it had been shown that both the hot nitrogen and steam regeneration had regenerated 84% of dichloromethane. But the choice of hot nitrogen or steam regeneration depends on the regeneration time, operating costs, and purity of dichloromethane regenerated. A thorough investigation had been made about the advantages and limitations of both the hot nitrogen and steam regeneration of dichloromethane. Copyright © 2011 Elsevier B.V. All rights reserved.

FY95 limited energy study for the area `a` package boiler. Holston Army Ammunition Plant, Kingsport, Tennessee. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-11-03

Holston Army Ammunition Plant (HSAAP) in Holston, Tennessee, manufactures explosives from raw materials. The facility comprises two separate areas designated Area `A11 and Area 11B`. Each area is served by a steam plant which produces steam for production processes, equipment operation, space heating, domestic water heating, steam tracing, and product storage heating requirements. The purpose of this study is to identify and evaluate the technical and economic feasibility of alternative methods of meeting the steam requirements of the Area 11A11 industrial complex. The following items were specifically requested to be evaluated. Evaluate the use of two new gas-fired packaged boilersmore » sized to meet the requirements of the industrial complex. The new boilers would be installed adjacent to the existing steam plant and would utilize the existing smokestacks and steam distribution system. Evaluate using the existing steam distribution system rather than locating multiple boilers at various sites. Existing steam driven chillers will be replaced with electric driven equipment. Evaluate this impact on the steam system requirements. Field survey and test two existing gas-fired packaged boilers located at the Volunteer Army Ammunition Plant in Chattanooga, Tennessee. The two boilers were last used about 1980 and are presently laid away. The boilers are approximately the same capacity and operating characteristics as the ones at HSAAP. Relocation of the existing boilers and ancillary equipment (feedwater pumps, generators, fans, etc.) would be required as well as repairs or modifications necessary to meet current operating conditions and standards.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leskovar, Matjaz; Koncar, Bostjan

An ex-vessel steam explosion may occur when during a severe reactor accident the reactor vessel fails and the molten core pours into the water in the reactor cavity. A steam explosion is a fuel coolant interaction process where the heat transfer from the melt to water is so intense and rapid that the timescale for heat transfer is shorter than the timescale for pressure relief. This can lead to the formation of shock waves and production of missiles at later times, during the expansion of the highly pressurized water vapor, that may endanger surrounding structures. In contrast to specialized steammore » explosion CFD codes, where the steam explosion is modeled on micro-scale using fundamental averaged multiphase flow conservation equations, in the presented approach the steam explosion is modeled in a simplified manner as an expanding high-pressure pre-mixture of dispersed molten fuel, liquid water and vapor. Applying the developed steam explosion model, a comprehensive analysis of the ex-vessel steam explosion in a typical PWR reactor cavity was done using the CFD code CFX-10. At four selected locations, which are of importance for the assessment of the vulnerability of cavity structures, the pressure histories were recorded and the corresponding pressure impulses calculated. The pressure impulses determine the destructive potential of the steam explosion and represent the input for the structural mechanical analysis of the cavity structures. The simulation results show that the pressure impulses depend mainly on the steam explosion energy conversion ratio, whereas the influence of the pre-mixture vapor volume fraction, which is a parameter in our model and determines the maximum steam explosion pressure, is not significant. (authors)« less

9 CFR 381.202 - Poultry products offered for entry; reporting of findings to customs; handling of articles...

Code of Federal Regulations, 2012 CFR

2012-01-01

... supervisor shall determine whether the inspector's decision was correct. Review of such appeal determination... the official establishments.) (1) Steam treatment (which shall be accomplished by processing the condemned product in a pressure tank under at least 40 pounds of steam pressure) or thorough cooking in a...

9 CFR 381.202 - Poultry products offered for entry; reporting of findings to customs; handling of articles...

Code of Federal Regulations, 2014 CFR

2014-01-01

... supervisor shall determine whether the inspector's decision was correct. Review of such appeal determination... the official establishments.) (1) Steam treatment (which shall be accomplished by processing the condemned product in a pressure tank under at least 40 pounds of steam pressure) or thorough cooking in a...

9 CFR 381.202 - Poultry products offered for entry; reporting of findings to customs; handling of articles...

Code of Federal Regulations, 2013 CFR

2013-01-01

... supervisor shall determine whether the inspector's decision was correct. Review of such appeal determination... the official establishments.) (1) Steam treatment (which shall be accomplished by processing the condemned product in a pressure tank under at least 40 pounds of steam pressure) or thorough cooking in a...

9 CFR 381.202 - Poultry products offered for entry; reporting of findings to customs; handling of articles...

Code of Federal Regulations, 2011 CFR

2011-01-01

... supervisor shall determine whether the inspector's decision was correct. Review of such appeal determination... the official establishments.) (1) Steam treatment (which shall be accomplished by processing the condemned product in a pressure tank under at least 40 pounds of steam pressure) or thorough cooking in a...

40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

Code of Federal Regulations, 2013 CFR

2013-07-01

...) temperature Continuous records as specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle...

40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

Code of Federal Regulations, 2014 CFR

2014-07-01

...) temperature Continuous records as specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle...

Effects of steam distillation on extraction, composition, and functional properties of coriander (Coriandrum sativum L.) proteins

USDA-ARS?s Scientific Manuscript database

Coriander (Coriandrum sativum L.) is a summer annual plant commonly used as fresh green herb, spice, or for its essential oil. A newly-developed process combined steam distillation and mechanical pressing to recover the essential oil and edible oil, respectively, from dehulled coriander seeds. The c...

Design and Selection of Soy Breads Used for Evaluating Isoflavone Bioavailability in Clinical Trials

PubMed Central

Ahn-Jarvis, Jennifer H.; Riedl, Kenneth M.; Schwartz, Steven J.; Vodovotz, Yael

2013-01-01

To modulate isoflavone aglycone composition within a soy functional food, soy ingredients were processed and evaluated in a soy bread system intended for clinical trials. A soy flour/soy milk mixture (SM) was boiled, fermented, steamed, or roasted prior to dough preparation. The isoflavone compositions of five processed SM and their corresponding breads combined with and without β-glucosidase-rich almonds were examined using HPLC. Isoflavone malonyl-glucosides (>80%) were converted into acetyl and simple glucoside forms (substrates more favorable for β-glucosidase) in steamed and roasted SM. Their corresponding breads had isoflavones predominately as aglycones (∼75%) with soy–almond bread with steamed SM being more consumer acceptable than roasted. Isoflavone composition in soy bread was stable during frozen storage and toasting. A suitable glycoside-rich soy bread (31.6 ± 2.1 mg aglycone equiv/slice) using unprocessed SM and an aglycone-rich soy–almond bread (31.1 ± 1.9 mg aglycone equiv/slice) using steamed SM were developed to evaluate fundamental questions of isoflavone bioavailability in clinical trials. PMID:23451757

Steam-soak performance in south Oman

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rice, S.A.

1991-11-01

With about 2 {times} 10{sup 9} stock-tank m{sup 3} (12.6 {times} 10{sup 9} STB) of medium/heavy oil originally in place (OOIP) in south Oman, considerable scope exists for increasing oil recovery by thermal methods. The viability of thermal recovery in south Oman was tested with a steamflood pilot in the Al Khlata sands of the Marmul field and a 2-year steam-soak project to test the applicability of steam soak in five south Oman oil fields producing heavy oil. This paper describes the performance of the latter project. The wells selected for the test program included a wide range of southmore » Oman reservoir and oil characteristics i.e., the main reservoir drive mechanisms of depletion, solution-gas, and edge- and bottomwater drive, the reservoir sandbody types, and oil viscosities from 80 to 4000 mPa {center dot} s (80 to 4,000 cp). Steam-soak operations were successful, and oil production accelerated significantly, with an average stimulate production rate twice that before stimulation. Acceleration was less marked in wells where reservoir energy is limited or where the primary (cold) water cut is more than 30%. At primary (cold) water cuts {gt}50%, no increase in oil production rate was observed. The process was simulated numerically for several wells, with the results in close agreement with performance. Improved understanding of the process resulting from the simulation allowed the most important factors influencing performance to be identified and aided process optimization in the field test. Two small-scale steam-soak projects currently are being assessed for implementatioimplementation in the early 1990's.« less

Cogeneration Technology Alternatives Study (CTAS). Volume 1: Summary report

NASA Technical Reports Server (NTRS)

Gerlaugh, H. E.; Hall, E. W.; Brown, D. H.; Priestley, R. R.; Knightly, W. F.

1980-01-01

Large savings can be made in industry by cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed-cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum-based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules for determining performance and cost in individual plants and on a national level. It was found that: (1) atmospheric and pressurized fluidized bed steam turbine systems were the most attractive of the direct coal-fired systems; and (2) open-cycle gas turbines with heat recovery steam generators and combined-cycles with NO(x) emission reduction and moderately increased firing temperatures were the most attractive of the coal-derived liquid-fired systems.

A separate phase drag model and a surrogate approximation for simulation of the steam assisted gravity drainage (SAGD) process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Padrino-Inciarte, Juan Carlos; Ma, Xia; VanderHeyden, W. Brian

General ensemble phase averaged equations for multiphase flows have been specialized for the simulation of the steam assisted gravity drainage (SAGD) process. In the average momentum equation, fluid-solid and fluid-fluid viscous interactions are represented by separate force terms. This equation has a form similar to that of Darcy’s law for multiphase flow but augmented by the fluid-fluid viscous forces. Models for these fluid-fluid interactions are suggested and implemented into the numerical code CartaBlanca. Numerical results indicate that the model captures the main features of the multiphase flow in the SAGD process, but the detailed features, such as plumes are missed.more » We find that viscous coupling among the fluid phases is important. Advection time scales for the different fluids differ by several orders of magnitude because of vast viscosity differences. Numerically resolving all of these time scales is time consuming. To address this problem, we introduce a steam surrogate approximation to increase the steam advection time scale, while keeping the mass and energy fluxes well approximated. This approximation leads to about a 40-fold speed-up in execution speed of the numerical calculations at the cost of a few percent error in the relevant quantities.« less

Modeling of the steam hydrolysis in a two-step process for hydrogen production by solar concentrated energy

NASA Astrophysics Data System (ADS)

Valle-Hernández, Julio; Romero-Paredes, Hernando; Pacheco-Reyes, Alejandro

2017-06-01

In this paper the simulation of the steam hydrolysis for hydrogen production through the decomposition of cerium oxide is presented. The thermochemical cycle for hydrogen production consists of the endothermic reduction of CeO2 to lower-valence cerium oxide, at high temperature, where concentrated solar energy is used as a source of heat; and of the subsequent steam hydrolysis of the resulting cerium oxide to produce hydrogen. The modeling of endothermic reduction step was presented at the Solar Paces 2015. This work shows the modeling of the exothermic step; the hydrolysis of the cerium oxide (III) to form H2 and the corresponding initial cerium oxide made at lower temperature inside the solar reactor. For this model, three sections of the pipe where the reaction occurs were considered; the steam water inlet, the porous medium and the hydrogen outlet produced. The mathematical model describes the fluid mechanics; mass and energy transfer occurring therein inside the tungsten pipe. Thermochemical process model was simulated in CFD. The results show a temperature distribution in the solar reaction pipe and allow obtaining the fluid dynamics and the heat transfer within the pipe. This work is part of the project "Solar Fuels and Industrial Processes" from the Mexican Center for Innovation in Solar Energy (CEMIE-Sol).

A separate phase drag model and a surrogate approximation for simulation of the steam assisted gravity drainage (SAGD) process

DOE PAGES

Padrino-Inciarte, Juan Carlos; Ma, Xia; VanderHeyden, W. Brian; ...

2016-01-01

General ensemble phase averaged equations for multiphase flows have been specialized for the simulation of the steam assisted gravity drainage (SAGD) process. In the average momentum equation, fluid-solid and fluid-fluid viscous interactions are represented by separate force terms. This equation has a form similar to that of Darcy’s law for multiphase flow but augmented by the fluid-fluid viscous forces. Models for these fluid-fluid interactions are suggested and implemented into the numerical code CartaBlanca. Numerical results indicate that the model captures the main features of the multiphase flow in the SAGD process, but the detailed features, such as plumes are missed.more » We find that viscous coupling among the fluid phases is important. Advection time scales for the different fluids differ by several orders of magnitude because of vast viscosity differences. Numerically resolving all of these time scales is time consuming. To address this problem, we introduce a steam surrogate approximation to increase the steam advection time scale, while keeping the mass and energy fluxes well approximated. This approximation leads to about a 40-fold speed-up in execution speed of the numerical calculations at the cost of a few percent error in the relevant quantities.« less

Structural features and antioxidant activities of lignins from steam-exploded bamboo (Phyllostachys pubescens).

PubMed

Sun, Shao-Ni; Cao, Xue-Fei; Xu, Feng; Sun, Run-Cang; Jones, Gwynn Lloyd

2014-06-25

An environmentally friendly steam explosion process of bamboo, followed by alkali and alkaline ethanol delignification, was developed to fractionate lignins. Results showed that after steam explosion the lignins isolated showed relatively low carbohydrate contents (0.55-1.76%) and molecular weights (780-1050 g/mol). For each steam-exploded sample, alkali-extracted lignins presented higher phenolic OH values (1.41-1.82 mmol/g), p-coumaric acid to ferulic acid ratios (pCA/FA ratios 4.5-14.1), and syringyl to guaiacyl ratios (S/G ratios 5.0-8.5) than those from alkaline ethanol-extracted lignins (phenolic OH 0.85-1.35 mmol/g, pCA/FA ratios 1.6-5.2, and S/G ratios 3.5-4.8). The lignins obtained consisted mainly of β-O-4' linkages combined with small amounts of β-β', β-5', and α-O-4/β-O-4 linkages. Antioxidant activities of the lignins obtained were tested by the 2,2-diphenyl-1-picrylhydrazyl, 2,2'-azobis(3-ethylbenzothiazoline-6-sulfonic acid), and ferric reducing activity power methods. It was found that alkali-extracted lignins obtained during the initial extraction process had higher antioxidant activities than alkaline ethanol-extracted lignins obtained during the second extraction process.

Processing real-world waste plastics by pyrolysis-reforming for hydrogen and high-value carbon nanotubes.

PubMed

Wu, Chunfei; Nahil, Mohamad A; Miskolczi, Norbert; Huang, Jun; Williams, Paul T

2014-01-01

Producing both hydrogen and high-value carbon nanotubes (CNTs) derived from waste plastics is reported here using a pyrolysis-reforming technology comprising a two-stage reaction system, in the presence of steam and a Ni-Mn-Al catalyst. The waste plastics consisted of plastics from a motor oil container (MOC), commercial waste high density polyethylene (HDPE) and regranulated HDPE waste containing polyvinyl chloride (PVC). The results show that hydrogen can be produced from the pyrolysis-reforming process, but also carbon nanotubes are formed on the catalyst. However, the content of 0.3 wt.% polyvinyl chloride in the waste HDPE (HDPE/PVC) has been shown to poison the catalyst and significantly reduce the quantity and purity of CNTs. The presence of sulfur has shown less influence on the production of CNTs in terms of quantity and CNT morphologies. Around 94.4 mmol H2 g(-1) plastic was obtained for the pyrolysis-reforming of HDPE waste in the presence of the Ni-Mn-Al catalyst and steam at a reforming temperature of 800 °C. The addition of steam in the process results in an increase of hydrogen production and reduction of carbon yield; in addition, the defects of CNTs, for example, edge dislocations were found to be increased with the introduction of steam (from Raman analysis).

Simulation of heat and mass transfer processes in the experimental section of the air-condensing unit of Scientific Production Company "Turbocon"

NASA Astrophysics Data System (ADS)

Artemov, V. I.; Minko, K. B.; Yan'kov, G. G.; Kiryukhin, A. V.

2016-05-01

A mathematical model was developed to be used for numerical analysis of heat and mass transfer processes in the experimental section of the air condenser (ESAC) created in the Scientific Production Company (SPC) "Turbocon" and mounted on the territory of the All-Russia Thermal Engineering Institute. The simulations were performed using the author's CFD code ANES. The verification of the models was carried out involving the experimental data obtained in the tests of ESAC. The operational capability of the proposed models to calculate the processes in steam-air mixture and cooling air and algorithms to take into account the maldistribution in the various rows of tube bundle was shown. Data on the influence of temperature and flow rate of the cooling air on the pressure in the upper header of ESAC, effective heat transfer coefficient, steam flow distribution by tube rows, and the dimensions of the ineffectively operating zones of tube bundle for two schemes of steam-air mixture flow (one-pass and two-pass ones) were presented. It was shown that the pressure behind the turbine (in the upper header) increases significantly at increase of the steam flow rate and reduction of the flow rate of cooling air and its temperature rise, and the maximum value of heat transfer coefficient is fully determined by the flow rate of cooling air. Furthermore, the steam flow rate corresponding to the maximum value of heat transfer coefficient substantially depends on the ambient temperature. The analysis of the effectiveness of the considered schemes of internal coolant flow was carried out, which showed that the two-pass scheme is more effective because it provides lower pressure in the upper header, despite the fact that its hydraulic resistance at fixed flow rate of steam-air mixture is considerably higher than at using the one-pass schema. This result is a consequence of the fact that, in the two-pass scheme, the condensation process involves the larger internal surface of tubes, results in lower values of Δ t (the temperature difference between internal and external coolant) for a given heat load.

Ultra-trace level analysis of morpholine, cyclohexylamine, and diethylaminoethanol in steam condensate by gas chromatography with multi-mode inlet, and flame ionization detection.

PubMed

Luong, J; Shellie, R A; Cortes, H; Gras, R; Hayward, T

2012-03-16

Steam condensate water treatment is a vital and integral part of the overall cooling water treatment process. Steam condensate often contains varying levels of carbon dioxide and oxygen which acts as an oxidizer. Carbon dioxide forms corrosive carbonic acid when dissolved in condensed steam. To neutralize the harmful effect of the carbonic acid, volatile amine compounds such as morpholine, cyclohexylamine, and diethylaminoethanol are often employed as part of a strategy to control corrosion in the water treatment process. Due to the high stability of these compounds in a water matrix, the indirect addition of such chemicals into the process via steam condensate often results in their presence throughout the process and even into the final product. It is therefore important to understand the impact of these chemicals and their fate within a chemical plant. The ability to analyze such compounds by gas chromatography has historically been difficult due to the lack of chromatographic system inertness at the trace level concentrations especially in an aqueous matrix. Here a highly sensitive, practical, and reliable gas chromatographic approach is described for the determination of morpholine, cyclohexylamine, and diethylaminoethanol in steam condensate at the part-per-billion (ppb) levels. The approach does not require any sample enrichment or derivatization. The technique employs a multi-mode inlet operating in pulsed splitless mode with programmed inlet temperature for sample introduction, an inert base-deactivated capillary column for solute separation and flame ionization detection. Chromatographic performance was further enhanced by the incorporation of 2-propanol as a co-solvent. Detection limits for morpholine, cyclohexylamine, diethylaminoethanol were established to be 100 ppb (v/v), with relative standard deviations (RSD) of less than 6% at the 95% confidence level (n=20) and a percent recovery of 96% or higher for the solutes of interest over a range of 0.1-100 ppm (v/v). A complete analysis can be conducted in less than 10 min. Copyright © 2012 Elsevier B.V. All rights reserved.

Experimental and numerical investigation of the Fast-SAGD process

NASA Astrophysics Data System (ADS)

Shin, Hyundon

The SAGD process has been tested in the field, and is now in a commercial stage in Western Canadian oil sands areas. The Fast-SAGD method can partly solve the drilling difficulty and reduce costs in a SAGD operation requiring paired parallel wells one above the other. This method also enhances the thermal efficiency in the reservoir. In this research, the reservoir parameters and operating conditions for the SAGD and Fast-SAGD processes are investigated by numerical simulation in the three Alberta oil sands areas. Scaled physical model experiments, which are operated by an automated process control system, are conducted under high temperature and high pressure conditions. The results of the study indicate that the shallow Athabasca-type reservoir, which is thick with high permeability (high kxh), is a good candidate for SAGD application, whereas Cold Lake- and Peace River-type reservoirs, which are thin with low permeability, are not as good candidates for conventional SAGD implementation. The simulation results indicate improved energy efficiency and productivity in most cases for the Fast-SAGD process; in those cases, the project economics were enhanced compared to the SAGD process. Both Cold Lake- and Peace River-type reservoirs are good candidates for a Fast-SAGD application rather than a conventional SAGD application. This new process demonstrates improved efficiency and lower costs for extracting heavy oil from these important reservoirs. A new economic indicator, called simple thermal efficiency parameter (STEP), was developed and validated to evaluate the performance of a SAGD project. STEP is based on cumulative steam-oil ratio (CSOR), calendar day oil rate (CDOR) and recovery factor (RF) for the time prior to the steam-oil ratio (SOR) attaining 4. STEP can be used as a financial metric quantitatively as well as qualitatively for this type of thermal project. An automated process control system was set-up and validated, and has the capability of controlling and handling steam injection processes like the steam-assisted gravity drainage process. The results of these preliminary experiments showed the overall cumulative oil production to be larger in the Fast-SAGD case, but end-point CSOR to be lower in the SAGD case. History matching results indicated that the steam quality was as low as 0.3 in the SAGD experiments, and even lower in the Fast-SAGD experiments after starting the CSS.

Waste heat utilization in industrial processes

NASA Technical Reports Server (NTRS)

Weichsel, M.; Heitmann, W.

1978-01-01

A survey is given of new developments in heat exchangers and heat pumps. With respect to practical applications, internal criteria for plant operation are discussed. Possibilities of government support are pointed out. Waste heat steam generators and waste heat aggregates for hot water generation or in some cases for steam superheating are used. The possibilities of utilization can be classified according to the economic improvements and according to their process applications, for example, gascooling. Examples are presented for a large variety of applications.

Interpretation of steam drive pilots in the Belridge Diatomite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnston, R.M.; Shahin, G.T.

1995-12-31

The South Belridge Diatomite Field contains more than 2.5 billion barrels of oil-in-place. Current primary and waterflood development are estimated to recover only a small fraction of this oil. Despite its low permeability, the diatomite may be a good candidate for the steam drive process, due to its thick oil column (1,000 ft), high porosity (50% to 65%), and high oil saturation (up to 70%). With these attributes, thermal expansion and decreased viscosity of reservoir fluids accelerate oil production, without significant heat loss to cap and base rock. Steam drive pilot operations have been conducted at South Belridge since 1986.more » This paper discusses the pilot projects and the 15-acre steam drive full-scale project currently being installed.« less

An afterburner-powered methane/steam reformer for a solid oxide fuel cells application

NASA Astrophysics Data System (ADS)

Mozdzierz, Marcin; Chalusiak, Maciej; Kimijima, Shinji; Szmyd, Janusz S.; Brus, Grzegorz

2018-04-01

Solid oxide fuel cell (SOFC) systems can be fueled by natural gas when the reforming reaction is conducted in a stack. Due to its maturity and safety, indirect internal reforming is usually used. A strong endothermic methane/steam reforming process needs a large amount of heat, and it is convenient to provide thermal energy by burning the remainders of fuel from a cell. In this work, the mathematical model of afterburner-powered methane/steam reformer is proposed. To analyze the effect of a fuel composition on SOFC performance, the zero-dimensional model of a fuel cell connected with a reformer is formulated. It is shown that the highest efficiency of a solid oxide fuel cell is achieved when the steam-to-methane ratio at the reforming reactor inlet is high.

Inhibition of DNA polymerase λ and associated inflammatory activities of extracts from steamed germinated soybeans.

PubMed

Mizushina, Yoshiyuki; Kuriyama, Isoko; Yoshida, Hiromi

2014-04-01

During the screening of selective DNA polymerase (pol) inhibitors from more than 50 plant food materials, we found that the extract from steamed germinated soybeans (Glycine max L.) inhibited human pol λ activity. Among the three processed soybean samples tested (boiled soybeans, steamed soybeans, and steamed germinated soybeans), both the hot water extract and organic solvent extract from the steamed germinated soybeans had the strongest pol λ inhibition. We previously isolated two glucosyl compounds, a cerebroside (glucosyl ceramide, AS-1-4, compound ) and a steroidal glycoside (eleutheroside A, compound ), from dried soybean, and these compounds were prevalent in the extracts of the steamed germinated soybeans as pol inhibitors. The hot water and organic solvent extracts of the steamed germinated soybeans and compounds and selectively inhibited the activity of eukaryotic pol λ in vitro but did not influence the activities of other eukaryotic pols, including those from the A-family (pol γ), B-family (pols α, δ, and ε), and Y-family (pols η, ι, and κ), and also showed no effect on the activity of pol β, which is of the same family (X) as pol λ. The tendency for in vitro pol λ inhibition by these extracts and compounds showed a positive correlation with the in vivo suppression of TPA (12-O-tetradecanoylphorbol-13-acetate)-induced inflammation in mouse ear. These results suggest that steamed germinated soybeans, especially the glucosyl compound components, may be useful for their anti-inflammatory properties.

Mechanism of influence water vapor on combustion characteristics of propane-air mixture

NASA Astrophysics Data System (ADS)

Larionov, V. M.; Mitrofanov, G. A.; Sachovskii, A. V.; Kozar, N. K.

2016-01-01

The article discusses the results of an experimental study of the effect of water vapor at the flame temperature. Propane-butane mixture with air is burning on a modified Bunsen burner. Steam temperature was varied from 180 to 260 degrees. Combustion parameters changed by steam temperature and its proportion in the mixture with the fuel. The fuel-air mixture is burned in the excess air ratio of 0.1. It has been established that the injection of steam changes the characteristics of combustion fuel-air mixture and increase the combustion temperature. The concentration of CO in the combustion products is substantially reduced. Raising the temperature in the combustion zone is associated with increased enthalpy of the fuel by the added steam enthalpy. Reducing the concentration of CO is caused by decrease in the average temperature in the combustion zone by applying steam. Concentration of active hydrogen radicals and oxygen increases in the combustion zone. That has a positive effect on the process of combustion.

Process for gasifying carbonaceous material from a recycled condensate slurry

DOEpatents

Forney, Albert J.; Haynes, William P.

1981-01-01

Coal or other carbonaceous material is gasified by reaction with steam and oxygen in a manner to minimize the problems of effluent water stream disposal. The condensate water from the product gas is recycled to slurry the coal feed and the amount of additional water or steam added for cooling or heating is minimized and preferably kept to a level of about that required to react with the carbonaceous material in the gasification reaction. The gasification is performed in a pressurized fluidized bed with the coal fed in a water slurry and preheated or vaporized by indirect heat exchange contact with product gas and recycled steam. The carbonaceous material is conveyed in a gas-solid mixture from bottom to top of the pressurized fluidized bed gasifier with the solids removed from the product gas and recycled steam in a supported moving bed filter of the resulting carbonaceous char. Steam is condensed from the product gas and the condensate recycled to form a slurry with the feed coal carbonaceous particles.

22. National Geographic Paper in the making. In this large ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. National Geographic Paper in the making. In this large room, some two hundred feet long, the liquid pulp shown in the previous picture is converted into uncoated paper. At the end of each machine is a tank of the pulp. A film of this pulp flows out upon an endless belt of fine-meshed wire, which is shaken vigorously. The water drops through the wire and gradually the residue solidifies. By the time the endless belt reaches the returning point, this residue is solid enough to hold its form as paper. It is then caught up between two rolls, which squeeze out the remaining water. Thence it passes around a series of iron drums filled with live steam; these dry it. After that is passes between big calender rolls and emerges in the foreground as machine-finish paper, ready for the coating or glazing process. These machines give one an idea of the huge proportions of a modern paper plant. (p.237.) - Champion-International Paper Company, West bank of Spicket River at Canal Street, Lawrence, Essex County, MA

Effect of Sodium Bisulfite Injection on the Microbial Community Composition in a Brackish-Water-Transporting Pipeline▿†

PubMed Central

Park, Hyung Soo; Chatterjee, Indranil; Dong, Xiaoli; Wang, Sheng-Hung; Sensen, Christoph W.; Caffrey, Sean M.; Jack, Thomas R.; Boivin, Joe; Voordouw, Gerrit

2011-01-01

Pipelines transporting brackish subsurface water, used in the production of bitumen by steam-assisted gravity drainage, are subject to frequent corrosion failures despite the addition of the oxygen scavenger sodium bisulfite (SBS). Pyrosequencing of 16S rRNA genes was used to determine the microbial community composition for planktonic samples of transported water and for sessile samples of pipe-associated solids (PAS) scraped from pipeline cutouts representing corrosion failures. These were obtained from upstream (PAS-616P) and downstream (PAS-821TP and PAS-821LP, collected under rapid-flow and stagnant conditions, respectively) of the SBS injection point. Most transported water samples had a large fraction (1.8% to 97% of pyrosequencing reads) of Pseudomonas not found in sessile pipe samples. The sessile population of PAS-616P had methanogens (Methanobacteriaceae) as the main (56%) community component, whereas Deltaproteobacteria of the genera Desulfomicrobium and Desulfocapsa were not detected. In contrast, PAS-821TP and PAS-821LP had lower fractions (41% and 0.6%) of Methanobacteriaceae archaea but increased fractions of sulfate-reducing Desulfomicrobium (18% and 48%) and of bisulfite-disproportionating Desulfocapsa (35% and 22%) bacteria. Hence, SBS injection strongly changed the sessile microbial community populations. X-ray diffraction analysis of pipeline scale indicated that iron carbonate was present both upstream and downstream, whereas iron sulfide and sulfur were found only downstream of the SBS injection point, suggesting a contribution of the bisulfite-disproportionating and sulfate-reducing bacteria in the scale to iron corrosion. Incubation of iron coupons with pipeline waters indicated iron corrosion coupled to the formation of methane. Hence, both methanogenic and sulfidogenic microbial communities contributed to corrosion of pipelines transporting these brackish waters. PMID:21856836

Enhancing the ecological and operational characteristics of water treatment units at TPPs based on baromembrane technologies

NASA Astrophysics Data System (ADS)

Chichirova, N. D.; Chichirov, A. A.; Filimonova, A. A.; Saitov, S. R.

2017-12-01

The innovative baromembrane technologies for water demineralization were introduced at Russian TPPs more than 25 years ago. While being used in the power engineering industry of Russia, these technologies demonstrated certain advantages over the traditional ion-exchange and thermal technologies of makeup water treatment for steam boilers. Water treatment units based on the baromembrane technology are compact, easy to operate, and highly automated. The experience gained from the use of these units shows that their reliability depends directly on preliminary water treatment. The popular water pretreatment technology with coagulation by aluminum oxychloride proved to be inefficient during the seasonal changes of source water quality that occurs at some stations. The use of aluminum coagulant at pH 8 and higher does not ensure the stable and qualitative pretreatment regime: soluble aluminum forms slip on membranes of the ultrafiltration unit, thereby causing pollution and intoxication as well as leading to structural damages or worsening of mechanical properties of the membranes. The problem of increased pH and seasonal changes of the source water quality can be solved by substitution of the traditional coagulant into a new one. To find the most successful coagulant for water pretreatment, experiments have been performed on both qualitative and quantitative analysis of the content of natural organic matters in the Volga water and their structure. We have developed a software program and measured the concentrations of soluble aluminum and iron salts at different pH values of the source water. The analysis of the obtained results has indicated that iron sulfate at pH 6.0-10.2, in contrast to aluminum oxychloride, is not characterized by increased solubility. Thus, the basic process diagrams of water pretreatment based on baromembrane technologies with pretreatment through coagulation by iron salts and wastewater amount reducing from 60-40 to 5-2% have been introduced for thermal power stations.

The influence of surface-active agents in gas mixture on the intensity of jet condensation

NASA Astrophysics Data System (ADS)

Yezhov, YV; Okhotin, VS

2017-11-01

The report presents: the methodology of calculation of contact condensation of steam from the steam-gas mixture into the stream of water, taking into account: the mass flow of steam through the boundary phase, particularly the change in turbulent transport properties near the interface and their connection to the interface perturbations due to the surface tension of the mixture; the method of calculation of the surface tension at the interface water - a mixture of fluorocarbon vapor and water, based on the previously established analytical methods we calculate the surface tension for simple one - component liquid-vapor systems. The obtained analytical relation to calculate the surface tension of the mixture is a function of temperature and volume concentration of the fluorocarbon gas in the mixture and is true for all sizes of gas molecules. On the newly created experimental stand is made verification of experimental studies to determine the surface tension of pure substances: water, steam, C3F8 pair C3F8, produced the first experimental data on surface tension at the water - a mixture of water vapor and fluorocarbon C3F8. The obtained experimental data allow us to refine the values of the two constants used in the calculated model of the surface tension of the mixture. Experimental study of jet condensation was carried out with the flow in the zone of condensation of different gases. The condensation process was monitored by measurement of consumption of water flowing from the nozzle, and the formed condensate. When submitting C3F8, there was a noticeable, intensification condensation process compared with the condensation of pure water vapor. The calculation results are in satisfactory agreement with the experimental data on surface tension of the mixture and steam condensation from steam-gas mixture. Analysis of calculation results shows that the presence of surfactants in the condensation zone affects the partial vapor pressure on the interfacial surface, and the thermal conductivity of the liquid jet. The first circumstance leads to deterioration of the condensation process, the second to the intensification of this process. There is obviously an optimum value of concentration of the additive surfactants to the vapour when the condensation process is maximum. According to the developed design methodology contact condensation can evaluate these optimum conditions, their practical effect in the field study.

Experimental constraints on phreatic eruption processes at Whakaari (White Island volcano)

NASA Astrophysics Data System (ADS)

Mayer, Klaus; Scheu, Bettina; Gilg, H. Albert; Heap, Michael J.; Kennedy, Ben M.; Lavallée, Yan; Letham-Brake, Mark; Dingwell, Donald B.

2015-09-01

Vigorous hydrothermal activity interspersed by sequences of phreatic and phreatomagmatic eruptions occur at Whakaari (White Island volcano), New Zealand. Here, we investigate the influence of sample type (hydrothermally altered cemented ash tuffs and unconsolidated ash/lapilli) and fragmentation mechanism (steam flashing versus gas expansion) on fragmentation and ejection velocities as well as on particle-size and shape. Our rapid decompression experiments show that fragmentation and ejection speeds of two ash tuffs, cemented by alunite and amorphous opal, increase with increasing porosity and that both are significantly enhanced in the presence of steam flashing. Ejection speeds of unconsolidated samples are higher than ejection speeds of cemented tuffs, as less energy is consumed by fragmentation. Fragmentation dominated by steam flashing results in increased fragmentation energy and a higher proportion of fine particles. Particle shape analyses before and after fragmentation reveal that both steam flashing and pure gas expansion produce platy or bladed particles from fracturing parallel to the decompression front. Neither fragmentation mechanisms nor sample type show a significant influence on the shape. Our results emphasize that, under identical pressure and temperature conditions, eruptions accompanied by the process of liquid water flashing to steam are significantly more violent than those driven simply by gas expansion. Therefore, phase changes during decompression and cementation are both important considerations for hazard assessment and modeling of eruptions in hydrothermally active environments.

Ventilatory responses of normal subjects to flax dust inhalation: the protective effect of autoclaving the flax.

PubMed Central

Jamison, J P; Langlands, J H; Bodel, C C

1985-01-01

A homogeneous batch of dew retted hackled flax was divided into two portions. One was untreated and the other was steamed for 45 minutes at 125 degrees C in three pressure/vacuum cycles in an autoclave. Dust was collected when the two flaxes were separately processed by industrial doubler and stapler machines. From untreated flax 7.2 g of dust was collected per kilogram of flax after two processing operations. From the steamed flax 4.4 g of flax was obtained per kilogram after four operations. A method was devised to disperse the dust in a room to produce dust levels similar to those encountered in a dusty mill (4.5-5.7 mg/m3). Twelve normal volunteers from the managerial staff of the linen industry of Northern Ireland inhaled the dust over six hour periods. With the untreated flax decreases were obtained in mean forced expiratory measurements of 7.6% in FEV1 and 4.5% in FVC (p less than 0.01). A double blind crossover comparison of similar levels of untreated and steamed flax dusts showed 30% less impairment of the forced expirations with steamed than with untreated flax (p less than 0.05). If these responses reflect the long term airway effects of flax dust then the steaming of flax may help in reducing byssinosis. Images PMID:3970886

Ventilatory responses of normal subjects to flax dust inhalation: the protective effect of autoclaving the flax.

PubMed

Jamison, J P; Langlands, J H; Bodel, C C

1985-03-01

A homogeneous batch of dew retted hackled flax was divided into two portions. One was untreated and the other was steamed for 45 minutes at 125 degrees C in three pressure/vacuum cycles in an autoclave. Dust was collected when the two flaxes were separately processed by industrial doubler and stapler machines. From untreated flax 7.2 g of dust was collected per kilogram of flax after two processing operations. From the steamed flax 4.4 g of flax was obtained per kilogram after four operations. A method was devised to disperse the dust in a room to produce dust levels similar to those encountered in a dusty mill (4.5-5.7 mg/m3). Twelve normal volunteers from the managerial staff of the linen industry of Northern Ireland inhaled the dust over six hour periods. With the untreated flax decreases were obtained in mean forced expiratory measurements of 7.6% in FEV1 and 4.5% in FVC (p less than 0.01). A double blind crossover comparison of similar levels of untreated and steamed flax dusts showed 30% less impairment of the forced expirations with steamed than with untreated flax (p less than 0.05). If these responses reflect the long term airway effects of flax dust then the steaming of flax may help in reducing byssinosis.

Steam explosion and its combinatorial pretreatment refining technology of plant biomass to bio-based products.

PubMed

Chen, Hong-Zhang; Liu, Zhi-Hua

2015-06-01

Pretreatment is a key unit operation affecting the refinery efficiency of plant biomass. However, the poor efficiency of pretreatment and the lack of basic theory are the main challenges to the industrial implementation of the plant biomass refinery. The purpose of this work is to review steam explosion and its combinatorial pretreatment as a means of overcoming the intrinsic characteristics of plant biomass, including recalcitrance, heterogeneity, multi-composition, and diversity. The main advantages of the selective use of steam explosion and other combinatorial pretreatments across the diversity of raw materials are introduced. Combinatorial pretreatment integrated with other unit operations is proposed as a means to exploit the high-efficiency production of bio-based products from plant biomass. Finally, several pilot- and demonstration-scale operations of the plant biomass refinery are described. Based on the principle of selective function and structure fractionation, and multi-level and directional composition conversion, an integrated process with the combinatorial pretreatments of steam explosion and other pretreatments as the core should be feasible and conform to the plant biomass refinery concept. Combinatorial pretreatments of steam explosion and other pretreatments should be further exploited based on the type and intrinsic characteristics of the plant biomass used, the bio-based products to be made, and the complementarity of the processes. Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Accumulation of Contaminants in the Distribution System.

EPA Science Inventory

Removal of arsenic from water using iron-related processes including coagulation with iron salts, iron removal with oxidation/filtration, and specific iron resins is established. These processes are effective because iron solids including minerals and chemical floc have strong ad...

Hydrogen rich gas generator

NASA Technical Reports Server (NTRS)

Houseman, J.; Rupe, J. H.; Kushida, R. O. (Inventor)

1976-01-01

A process and apparatus is described for producing a hydrogen rich gas by injecting air and hydrocarbon fuel at one end of a cylindrically shaped chamber to form a mixture and igniting the mixture to provide hot combustion gases by partial oxidation of the hydrocarbon fuel. The combustion gases move away from the ignition region to another region where water is injected to be turned into steam by the hot combustion gases. The steam which is formed mixes with the hot gases to yield a uniform hot gas whereby a steam reforming reaction with the hydrocarbon fuel takes place to produce a hydrogen rich gas.

Disinfection of woollen blankets in steam at subatmospheric pressure

PubMed Central

Alder, V. G.; Gillespie, W. A.

1961-01-01

Blankets may be disinfected in steam at subatmospheric pressures by temperatures below boiling point inside a suitably adapted autoclave chamber. The chamber and its contents are thoroughly evacuated of air so as to allow rapid heat penetration, and steam is admitted to a pressure of 10 in. Hg below atmospheric pressure, which corresponds to a temperature of 89°C. Woollen blankets treated 50 times by this process were undamaged. Vegetative organisms were destroyed but not spores. The method is suitable for large-scale disinfection of blankets and for disinfecting various other articles which would be damaged at higher temperatures. PMID:13860203

Sourcing of Steam and Electricity for Carbon Capture Retrofits.

PubMed

Supekar, Sarang D; Skerlos, Steven J

2017-11-07

This paper compares different steam and electricity sources for carbon capture and sequestration (CCS) retrofits of pulverized coal (PC) and natural gas combined cycle (NGCC) power plants. Analytical expressions for the thermal efficiency of these power plants are derived under 16 different CCS retrofit scenarios for the purpose of illustrating their environmental and economic characteristics. The scenarios emerge from combinations of steam and electricity sources, fuel used in each source, steam generation equipment and process details, and the extent of CO 2 capture. Comparing these scenarios reveals distinct trade-offs between thermal efficiency, net power output, levelized cost, profit, and net CO 2 reduction. Despite causing the highest loss in useful power output, bleeding steam and extracting electric power from the main power plant to meet the CCS plant's electricity and steam demand maximizes plant efficiency and profit while minimizing emissions and levelized cost when wholesale electricity prices are below 4.5 and 5.2 US¢/kWh for PC-CCS and NGCC-CCS plants, respectively. At prices higher than these higher profits for operating CCS retrofits can be obtained by meeting 100% of the CCS plant's electric power demand using an auxiliary natural gas turbine-based combined heat and power plant.

Lignin Sulfonation and SO2 Addition Enhance the Hydrolyzability of Deacetylated and Then Steam-Pretreated Poplar with Reduced Inhibitor Formation.

PubMed

Tang, Yong; Dou, Xiaoli; Hu, Jinguang; Jiang, Jianxin; Saddler, Jack N

2018-01-01

The merit of deacetylation of corn stover prior to pretreatment is decreasing the formation of inhibitors and improving enzyme hydrolysis, proved in dilute acid pretreatment. However, few studies are done on how deacetylation would affect bioconversion process containing steam explosion. In this study, the effect of deacetylation on steam explosion was conducted using poplar as substrate. About 57 to 90% of acetyl group in poplar, depending on alkaline types and concentration, was removed by dilute alkaline deacetylation in 6 h. Deacetylation eliminated over 85% of inhibitor formation during downstream steam explosion. However, deacetylation prior to steam explosion decreased the dissolution of hemicellulose, thus reducing the cellulose accessibility of pretreated poplar, finally resulting in 5-20% decrease in glucose yield and 20-35% decrease in xylose yield. The addition of 5% SO 2 during steam explosion significantly improved the hydrolysis of deacetylated and pretreated poplar without significantly increasing the concentration of inhibitors. Incorporating 45 mmol/kg sulfoacid group in lignin fraction of deacetylated and then pretreated poplar dramatically improved the xylose yield to about 100% and increased the glucose yield by 30%.

Method and apparatus for removing coarse unentrained char particles from the second stage of a two-stage coal gasifier

DOEpatents

Donath, Ernest E.

1976-01-01

A method and apparatus for removing oversized, unentrained char particles from a two-stage coal gasification process so as to prevent clogging or plugging of the communicating passage between the two gasification stages. In the first stage of the process, recycled process char passes upwardly while reacting with steam and oxygen to yield a first stage synthesis gas containing hydrogen and oxides of carbon. In the second stage, the synthesis gas passes upwardly with coal and steam which react to yield partially gasified char entrained in a second stage product gas containing methane, hydrogen, and oxides of carbon. Agglomerated char particles, which result from caking coal particles in the second stage and are too heavy to be entrained in the second stage product gas, are removed through an outlet in the bottom of the second stage, the particles being separated from smaller char particles by a counter-current of steam injected into the outlet.

Integral process assessment of sugarcane agricultural crop residues conversion to ethanol.

PubMed

Manfredi, Adriana Paola; Ballesteros, Ignacio; Sáez, Felicia; Perotti, Nora Inés; Martínez, María Alejandra; Negro, María José

2018-07-01

This work focuses a whole process assessment on post-harvesting sugarcane residues for 2G ethanol production by different saccharification-fermentation conditions at high solids loading, performed after steam explosion, alkaline and acidic pretreatments. Carbohydrate recoveries and enzymatic digestibility results showed that alkali and steam explosion pretreatments were effective for the biomass assayed. Due to a significant improvement (60%) of the glucose released by combining hemicellulases and cellulases only after the NaOH pretreatment, the most favorable process settled comprised an alkali-based pretreatment followed by a pre-saccharification and simultaneous saccharification and fermentation (PSSF). The produced ethanol reached 4.8% (w/w) as a result of an 80% conversion of the glucose from the pretreated biomass. Finally, an ethanol concentration of 3.2% (w/w) was obtained by means of a steam explosion followed by PSSF, representing a suitable start point to further develop a low environmental impact alternative for ethanol production. Copyright © 2018 Elsevier Ltd. All rights reserved.

Environmental friendly method for the extraction of coir fibre and isolation of nanofibre.

PubMed

Abraham, Eldho; Deepa, B; Pothen, L A; Cintil, J; Thomas, S; John, M J; Anandjiwala, R; Narine, S S

2013-02-15

The objective of this work was to develop an environmental friendly method for the effective utilization of coir fibre by adopting steam pre-treatment. The retting of the coconut bunch makes strong environmental problems which can be avoided by this method. Chemical characterization of the fibre during each processing stages confirmed the increase of cellulose content from raw (40%) to final steam treated fibres (93%). Morphological and dynamic light scattering analyses of the fibres at different processing stages revealed that the isolation of cellulose nano fibres occur in the final step of the process as an aqueous suspension. FT-IR and XRD analysis demonstrated that the treatments lead to the gradual removal of lignin and hemicelluloses from the fibres. The existence of strong lignin-cellulose complex in the raw coir fibre is proved by its enhanced thermal stability. Steam explosion has been proved to be a green method to expand the application areas of coir fibre. Copyright © 2012 Elsevier Ltd. All rights reserved.

Comparison of the efficiency of bacterial and fungal laccases in delignification and detoxification of steam-pretreated lignocellulosic biomass for bioethanol production.

PubMed

De La Torre, María; Martín-Sampedro, Raquel; Fillat, Úrsula; Eugenio, María E; Blánquez, Alba; Hernández, Manuel; Arias, María E; Ibarra, David

2017-11-01

This study evaluates the potential of a bacterial laccase from Streptomyces ipomoeae (SilA) for delignification and detoxification of steam-exploded wheat straw, in comparison with a commercial fungal laccase from Trametes villosa. When alkali extraction followed by SilA laccase treatment was applied to the water insoluble solids fraction, a slight reduction in lignin content was detected, and after a saccharification step, an increase in both glucose and xylose production (16 and 6%, respectively) was observed. These effects were not produced with T. villosa laccase. Concerning to the fermentation process, the treatment of the steam-exploded whole slurry with both laccases produced a decrease in the phenol content by up to 35 and 71% with bacterial and fungal laccases, respectively. The phenols reduction resulted in an improved performance of Saccharomyces cerevisiae during a simultaneous saccharification and fermentation (SSF) process, improving ethanol production rate. This enhancement was more marked with a presaccharification step prior to the SSF process.

40 CFR 63.7500 - What emission limitations, work practice standards, and operating limits must I meet?

Code of Federal Regulations, 2014 CFR

2014-07-01

... pounds per million Btu of steam output, in Tables 1 or 2 to this subpart are an alternative applicable only to boilers and process heaters that generate steam. The output-based emission limits, in units of..., monitoring results, review of operation and maintenance procedures, review of operation and maintenance...

21 CFR 129.80 - Processes and controls.

Code of Federal Regulations, 2013 CFR

2013-04-01

..., including those performed by chemical means or by any other means such as circulation of live steam or hot... intensities shall be considered a minimum: (1) Steam in enclosed system: At least 170 °F for at least 15... be available for official review at reasonable times. [42 FR 14355, Mar. 15, 1977, as amended at 44...

40 CFR 63.7500 - What emission limitations, work practice standards, and operating limits must I meet?

Code of Federal Regulations, 2013 CFR

2013-07-01

... pounds per million Btu of steam output, in Tables 1 or 2 to this subpart are an alternative applicable only to boilers and process heaters that generate steam. The output-based emission limits, in units of..., monitoring results, review of operation and maintenance procedures, review of operation and maintenance...

21 CFR 129.80 - Processes and controls.

Code of Federal Regulations, 2014 CFR

2014-04-01

..., including those performed by chemical means or by any other means such as circulation of live steam or hot... intensities shall be considered a minimum: (1) Steam in enclosed system: At least 170 °F for at least 15... be available for official review at reasonable times. [42 FR 14355, Mar. 15, 1977, as amended at 44...

21 CFR 129.80 - Processes and controls.

Code of Federal Regulations, 2012 CFR

2012-04-01

..., including those performed by chemical means or by any other means such as circulation of live steam or hot... intensities shall be considered a minimum: (1) Steam in enclosed system: At least 170 °F for at least 15... be available for official review at reasonable times. [42 FR 14355, Mar. 15, 1977, as amended at 44...

40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

Code of Federal Regulations, 2012 CFR

2012-07-01

... specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. Temperature of the carbon bed...

40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

Code of Federal Regulations, 2010 CFR

2010-07-01

... specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. Temperature of the carbon bed...

40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

Code of Federal Regulations, 2011 CFR

2011-07-01

... specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. Temperature of the carbon bed...

Effects of steam distillation and screw-pressing on extraction, composition and functional properties of protein in dehulled coriander (Coriandrum sativum L.)

USDA-ARS?s Scientific Manuscript database

Coriander (Coriandrum sativum L.) is a summer annual plant commonly used as fresh green herb, spice, or for its essential oil. An integrated process combined steam distillation, dehulling, and screw pressing to recover the essential oil and edible oil from coriander fruit. The current work determine...

Effect of ferrous sulfate fortification in germinated brown rice on seed iron concentration and bioavailability.

PubMed

Wei, Yanyan; Shohag, M J I; Ying, Feng; Yang, Xiaoe; Wu, Chunyong; Wang, Yuyan

2013-06-01

The present study evaluated the effectiveness of germination and iron fortification on iron concentration and bioavailability of brown rice. Iron fortification during germination process with 0.05-2 g/L ferrous sulfate increased the iron concentration in germinated brown rice from 1.1 to 15.6 times than those in raw brown rice. Based on the recommended dietary allowance of iron, maximum germination rate and γ-aminobutyric acid, we recommend the brown rice fortified with 0.25 g/L FeSO(4) as a suitable fortification level to use in germination process. Iron fortification during the germination process has a positive effect on iron concentration and bioavailability. A significant difference was observed among the cultivars in respect to the capacity for iron accumulation and bioavailability. Germination alone could improve in vitro iron solubility, but had no effect on iron bioavailability in Caco-2 cell, the additional fortification process should be combined to get high amount of bioavailable iron from the brown rice. Copyright © 2012 Elsevier Ltd. All rights reserved.

Study of Catalyst Variation Effect in Glycerol Conversion Process to Hydrogen Gas by Steam Reforming

NASA Astrophysics Data System (ADS)

Widayat; Hartono, R.; Elizabeth, E.; Annisa, A. N.

2018-04-01

Along with the economic development, needs of energy being increase too. Hydrogen as alternative energy has many usages. Besides that, hydrogen is one source of energy that is a clean fuel, but process production of hydrogen from natural gas as a raw material has been used for a long time. Therefore, there is need new invention to produce hydrogen from the others raw material. Glycerol, a byproduct of biodiesel production, is a compound which can be used as a raw material for hydrogen production. By using glycerol as a raw material of hydrogen production, we can get added value of glycerol as well as an energy source solution. The process production of hydrogen by steam reforming is a thermochemical process with efficiency 70%. This process needs contribution of catalyst to improve its efficiency and selectivity of the process. In this study will be examined the effect variation of catalyst for glycerol conversion process to hydrogen by steam reforming. The method for catalyst preparation was variation of catalyst impregnation composition, catalyst calcined with difference concentration of hydrochloric acid and calcined with difference hydrochloric acid ratio. After that, all of catalyst which have been prepared, used for steam reforming process for hydrogen production from glycerol as a raw material. From the study, the highest yield of hydrogen gas showed in the process production by natural zeolite catalyst with 1:15 Hydrochloric acid ratio was 42.28%. Hydrogen yield for 2M calcined natural zeolite catalyst was 38.37%, for ZSM-5 catalyst was 15.83%, for 0.5M calcined natural zeolite was 13.09% and for ultrasonic natural zeolite was 11.43%. The lowest yield of hydrogen gas showed in catalyst 2Zn/ZSM-5 with 11.22%. This result showed that hydrogen yield product was affected by catalyst variation because of the catalyst has difference characteristic and difference catalytic activity after the catalyst preparation process.

Steam jet mill-a prospective solution to industrial exhaust steam and solid waste.

PubMed

Zhang, Mingxing; Chen, Haiyan

2018-04-20

Bulk industrial solid wastes occupy a lot of our resources and release large amounts of toxic and hazardous substances to the surrounding environment, demanding innovative strategies for grinding, classification, collection, and recycling for economically ultrafine powder. A new technology for grinding, classification, collection, and recycling solid waste is proposed, using the superheated steam produced from the industrial exhaust steam to disperse, grind, classify, and collect the industrial solid waste. A large-scale steam jet mill was designed to operate at an inlet steam temperature 230-300 °C and an inlet pressure of 0.2-0.6 MPa. A kind of industrial solid waste fluidized-bed combustion ashes was used to grinding tests at different steam temperatures and inlet pressures. The total process for grinding, classification, and collection is drying. Two kinds of particle sizes are obtained. One particle size is d 50  = 4.785 μm, and another particle size is d 50  = 8.999 μm. For particle size d 50  = 8.999 μm, the inlet temperature is 296 °C and an inlet pressure is 0.54 MPa for the grinding chamber. The steam flow is 21.7 t/h. The yield of superfine powder is 73 t/h. The power consumption is 3.76 kW h/t. The obtained superfine powder meets the national standard S95 slag. On the basis of these results, a reproducible and sustainable industrial ecological protocol using steam produced by industrial exhaust heat coupled to solid waste recycling is proposed, providing an efficient, large-scale, low-cost, promising, and green method for both solid waste recovery and industrial exhaust heat reutilization.

Mixed ionic and electronic conducting membranes for hydrogen generation and separation

NASA Astrophysics Data System (ADS)

Cui, Hengdong

Dense mixed ionic and electronic conducting (MIEC) membranes are receiving increasing attention due to their potential for application as gas separation membranes to separate oxygen from air. The objective of this work is to study a novel, chemically-assisted separation process that utilizes oxygen-ion and electron-conducting MIECs for generating and separating hydrogen from steam. This research aims at exploring new routes and materials for high-purity hydrogen production for use in fuel cells and hydrogen-based internal combustion (IC) engines. In this approach, hydrocarbon fuel such as methane is fed to one side of the membrane, while steam is fed to the other side. The MIEC membrane separation process involves steam dissociation and oxidation of the fuel. The oxygen ions formed as a result of steam dissociation are transported across the membrane in a coupled transport process with electrons being transported in the opposite direction. Upon reaching the fuel side of the membrane, the oxygen ions oxidize the hydrocarbon. This process results in hydrogen production on the steam side of the membrane. The oxygen partial pressure gradient across the membrane is the driving force for this process. In this work, a novel, dual-phase composite MIEC membrane system comprising of rare-earth doped ceria with high oxygen ion conductivity and donor-doped strontium titanate with high electronic conductivity were investigated. The chemical diffusion coefficient and surface exchange coefficient have been measured using the electrical conductivity relaxation (ECR) technique. These two parameters control the rate of oxygen permeation across the membrane. The permeation data have been fit with a kinetic model that incorporates oxygen surface exchange on two sides of the membrane and bulk transport of oxygen through the membrane. This material has higher bulk diffusion coefficient and surface exchange reaction rate compared to other known MIEC conductors under the process conditions of interest. Over 10 mumol·cm-2·s-1 (micromoles per square cm per second) of area specific hydrogen flux has been achieved employing a membrane of this material with thickness of 0.2 mm. This flux is several orders of magnitude higher than the hydrogen generation rates reported using other MIEC materials under similar operating conditions.

Derate Mitigation Options for Pulverized Coal Power Plant Carbon Capture Retrofits

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoffmann, Jeffrey W.; Hackett, Gregory A.; Lewis, Eric G.

Carbon capture and storage (CCS) technologies available in the near-term for pulverized coal-fueled power plants (i.e., post combustion solvent technologies) require substantial capital investment and result in marked decrease in electricity available for sale to the grid. The impact to overall plant economics can be mitigated for new plant designs (where the entire plant can be optimized around the CCS system). However, existing coal-fueled power plants were designed without the knowledge or intent to retrofit a CCS process, and it is simply not possible to re-engineer an existing plant in a manner that it could achieve the same performance asmore » if it was originally designed and optimized for CCS technology. Pairing an auxiliary steam supply to the capture system is a technically feasible option to mitigate the derate resulting from diverting steam away from an existing steam turbine and continuing to run that turbine at steam flow rates and properties outside of the original design specifications. The results of this analysis strongly support the merits of meeting the steam and power requirements for a retrofitted post-combustion solvent based carbon dioxide (CO2) capture system with an auxiliary combined heat and power (CHP) plant rather than robbing the base plant (i.e., diverting steam from the existing steam cycle and electricity from sale to the grid).« less

Effect of sanitizer combined with steam heating on the inactivation of foodborne pathogens in a biofilm on stainless steel.

PubMed

Ban, Ga-Hee; Kang, Dong-Hyun

2016-05-01

The combined effect of chemical sanitizers including sodium hypochlorite, hydrogen peroxide, iodophor, and benzalkonium chloride with steam heating on the inactivation of biofilms formed by Escherichia coli O157:H7, Salmonella Typhimurium, and Listeria monocytogenes on stainless steel was investigated. Six day old biofilms, comprised of a mixture of three strains each of three foodborne pathogens, were produced on stainless steel coupons at 25 °C and treated with each sanitizer alone (for 5, 15, and 30 s), steam alone (for 5, 10, and 20 s), and the combination. There was a synergistic effect of sanitizer and steam on the viability of biofilm cells of the three pathogens as evidenced by plating counts and imaging. The combination treatment achieved an additional 0.01 to 2.78 log reduction compared to the sum of each individual treatment. The most effective combination for reducing levels of biofilm cells was the combination of steam and iodophor; steam for 20 s and merely 20 ppm iodophor for 30 s reduced cell numbers to below the detection limit (<1.48 log CFU/coupon). These results suggest that the combination treatment of sanitizer with steam can be applied to control foodborne pathogens biofilm cells in food processing facilities as a potential intervention. Copyright © 2015 Elsevier Ltd. All rights reserved.

Upstream H/sub 2/S removal from geothermal steam. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-11-01

The purpose of this project was to evaluate a new heat exchanger process as a method for removing hydrogen sulfide (H/sub 2/S) gas from geothermal steam upstream of a power plant turbine. The process utilizes a heat exchanger to condense geothermal steam so that noncondensable gases (including H/sub 2/S) can be removed in the form of a concentrated vent stream. Ultimate disposal of the removed H/sub 2/S gas may then be accomplished by use of other processes such as the commercially available Stretford process. The clean condensate is reevaporated on the other side of the heat exchanger using the heatmore » removed from the condensing geothermal steam. The necessary heat transfer is induced by maintaining a slight pressure difference, and consequently a slight temperature difference, between the two sides of the heat exchanger. Evaluation of this condensing and reboiling process was performed primarily through the testing of a small-scale 14 m/sup 2/ (150 ft/sup 2/) vertical tube evaporator heat exchanger at The Geysers Power Plant in northern California. The field test results demonstrated H/sub 2/S removal rates consistently better than 90 percent, with an average removal rate of 94 percent. In addition, the removal rate for all noncondensable gases is about 98 percent. Heat transfer rates were high enough to indicate acceptable economics for application of the process on a commercial scale. The report also includes an evaluation of the cost and performance of various configurations of the system, and presents design and cost estimates for a 2.5 MWe and a 55 MWe unit.« less

Study on steam pressure characteristics in various types of nozzles

NASA Astrophysics Data System (ADS)

Firman; Anshar, Muhammad

2018-03-01

Steam Jet Refrigeration (SJR) is one of the most widely applied technologies in the industry. The SJR system was utilizes residual steam from the steam generator and then flowed through the nozzle to a tank that was containing liquid. The nozzle converts the pressure energy into kinetic energy. Thus, it can evaporate the liquid briefly and release it to the condenser. The chilled water, was produced from the condenser, can be used to cool the product through a heat transfer process. This research aims to study the characteristics of vapor pressure in different types of nozzles using a simulation. The Simulation was performed using ANSYS FLUENT software for nozzle types such as convergent, convrgent-parallel, and convergent-divergent. The results of this study was presented the visualization of pressure in nozzles and was been validated with experiment data.

Steam jet ejectors for the process industries. [Glossary included

DOE Office of Scientific and Technical Information (OSTI.GOV)

Power, R.B.

1994-01-01

Steam jet ejectors were for many years the workhorse of the chemical process industries for producing vacuum. With increasing emphasis on stricter pollution control, their use was curtailed. There are still many applications, however, such as those with large capacity requirements, where ejectors are the only equipment that can produce sufficient vacuum. Chapter 1 is a short overview on how to use the text. Chapter 2 discusses what an ejector is and how it works. How ejector stages work is reviewed in Chapter 3. Engineering calculations for ejector stages is thoroughly discussed in Chapter 4. In Chapter 5, contact andmore » surface condensers are reviewed, and calculation procedures are presented. The various types of pressure control are discussed in Chapter 6. Chapter 7 is an excellent review of installation of ejector vacuum systems. The final chapter of Part 2 (Chapters 3--8) thoroughly covers all aspects of operation, testing, troubleshooting and maintenance. Part 3, consisting of two chapters, is devoted to specifying and purchasing steam jet ejectors. Part 4 on other ejector applications and upgrading ejector usage also consists of two chapters. Chapter 11 reviews steam-jet refrigeration, steam-jet and gas-jet compressors, liquid jet eductors, desuperheaters, special design situations, and designing one's own systems. Upgrading of existing ejector procedures and hardware is reviewed in Chapter 12. The 12 appendixes cover: physical properties of common fluids; handy vacuum engineering data and rules of thumb; SI unit conversions; sizing air and steam metering orifices for testing; drill sizes; ejector operating costs and design optimization; forms for ejector calculations, tests, and inspections; instructions for preparing ejector specifications; test kit contents list; ejector manufacturers and suppliers of referenced hardware and information; and failure modes and symptoms.« less

Endotoxin inactivation via steam-heat treatment in dilute simethicone emulsions used in biopharmaceutical processes.

PubMed

Britt, Keith A; Galvin, Jeffrey; Gammell, Patrick; Nti-Gyabaah, Joseph; Boras, George; Kolwyck, David; Ramirez, José G; Presente, Esther; Naugle, Gregory

2014-01-01

Simethicone emulsion is used to regulate foaming in cell culture operations in biopharmaceutical processes. It is also a potential source of endotoxin contamination. The inactivation of endotoxins in dilute simethicone emulsions was assessed as a function of time at different steam temperatures using a Limulus amebocyte lysate kinetic chromogenic technique. Endotoxin inactivation from steam-heat treatment was fit to a four-parameter double exponential decay model, which indicated that endotoxin inactivation was biphasic, consisting of fast and slow regimes. In the fast regime, temperature-related effects were dominant. Transitioning into the slow regime, the observed temperature dependence diminished, and concentration-related effects became increasingly significant. The change in the Gibbs free energy moving through the transition state indicated that a large energy barrier must be overcome for endotoxin inactivation to occur. The corresponding Arrhenius pre-exponential factor was >10(12) s(-1) suggesting that endotoxins in aqueous solution exist as aggregates. The disorder associated with the endotoxin inactivation reaction pathway was assessed via the change in entropy moving through the transition state. This quantity was positive indicating that endotoxin inactivation may result from hydrolysis of individual endotoxin molecules, which perturbs the conformation of endotoxin aggregates, thereby modulating the biological activity observed. Steam-heat treatment decreased endotoxin levels by 1-2 logarithm (log) reduction (LRV), which may be practically relevant depending on incoming raw material endotoxin levels. Antifoam efficiency and cell culture performance were negligibly impacted following steam-heat treatment. The results from this study show that steam-heat treatment is a viable endotoxin control strategy that can be implemented to support large-scale biopharmaceutical manufacturing. © 2014 American Institute of Chemical Engineers.

Phase separation of metal-added corium and its effect on a steam explosion

NASA Astrophysics Data System (ADS)

Min, B. T.; Kim, J. H.; Hong, S. W.; Hong, S. H.; Park, I. K.; Song, J. H.; Kim, H. D.

2008-07-01

To simulate a relocation of molten core material and its interaction phenomenon with water during a severe accident in a nuclear reactor, a typical corium of UO 2/ZrO 2/Zr/Stainless steel mixed at a 62 wt%, 15 wt%, 12 wt% and 11 wt%, respectively, was melted and then cooled down to become a solidified ingot. It was shown that the molten corium was separated into two layers, of which the upper layer was oxide mixtures and the lower layer was metal alloys. The upper layer was UO 2 and ZrO 2 and the lower layer mostly consisted of metal mixtures such as uranium, zirconium and stainless steel. Iron content varied with the positions and about a half of it existed as an alloy such as Fe 2U. Uranium metal was produced by reduction of UO 2 by zirconium metal. The average densities of the upper oxide layer and the lower metal layer were 8.802 and 9.411 g/cm 3, respectively. In another test, metal-added molten corium was poured into water and it showed that a steam explosion could occur by applying an external trigger.

High temperature oxidation behavior of austenitic stainless steel AISI 304 in steam of nanofluids contain nanoparticle ZrO2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prajitno, Djoko Hadi, E-mail: djokohp@batan.go.id; Syarif, Dani Gustaman, E-mail: djokohp@batan.go.id

2014-03-24

The objective of this study is to evaluate high temperature oxidation behavior of austenitic stainless steel SS 304 in steam of nanofluids contain nanoparticle ZrO{sub 2}. The oxidation was performed at high temperatures ranging from 600 to 800°C. The oxidation time was 60 minutes. After oxidation the surface of the samples was analyzed by different methods including, optical microscope, scanning electron microscope (SEM) and X-ray diffraction (XRD). X-ray diffraction examination show that the oxide scale formed during oxidation of stainless steel AISI 304 alloys is dominated by iron oxide, Fe{sub 2}O{sub 3}. Minor element such as Cr{sub 2}O{sub 3} ismore » also appeared in the diffraction pattern. Characterization by optical microscope showed that cross section microstructure of stainless steel changed after oxidized with the oxide scale on the surface stainless steels. SEM and x-ray diffraction examination show that the oxide of ZrO{sub 2} appeared on the surface of stainless steel. Kinetic rate of oxidation of austenite stainless steel AISI 304 showed that increasing oxidation temperature and time will increase oxidation rate.« less

Iron in non-hydroxyl radical mediated photochemical processes for dye degradation: Catalyst or inhibitor?

PubMed

Wu, Bingdang; Zhang, Shujuan; Li, Xuchun; Liu, Xitong; Pan, Bingcai

2015-07-01

The acetylacetone (AA) mediated photochemical process has been proven as an efficient approach for decoloration. For azo dyes, the UV/AA process was several to more than ten times more efficient than the UV/H2O2 process. Iron is one of the most common elements on the earth. It is well known that iron can improve the UV/H2O2 process through thermal Fenton and photo-Fenton reactions. What will be the role of iron in the UV/AA process? Could iron-AA complexes act as photocatalysts in environmental remediation? To answer these questions, the photo-degradation of an azo dye, Acid Orange 7 (AO7), was conducted under the variant combinations of AA with iron species in both ionic (Fe2+, Fe3+) and complex (Fe(AA)3) forms. The pseudo-first-order decoloration rate constants of AO7 in these photochemical processes followed such an order: UV/Fe(II)/AA

Characterization of gas chemistry and noble-gas isotope ratios of inclusion fluids in magmatic-hydrothermal and magmatic-steam alunite

USGS Publications Warehouse

Landis, G.P.; Rye, R.O.

2005-01-01

Chemical and isotope data were obtained for the active gas and noble gas of inclusion fluids in coarse-grained samples of magmatic-hydrothermal and magmatic-steam alunite from well-studied deposits (Marysvale, Utah; Tambo, Chile; Tapajo??s, Brazil; Cactus, California; Pierina, Peru), most of which are discussed in this Volume. Primary fluid inclusions in the alunite typically are less than 0.2 ??m but range up to several micrometers. Analyses of the active-gas composition of these alunite-hosted inclusion fluids released in vacuo by both crushing and heating indicate consistent differences in the compositions of magmatic-hydrothermal and magmatic-steam fluids. The compositions of fluids released by crushing were influenced by contributions from significant populations of secondary inclusions that trapped largely postdepositional hydrothermal fluids. Thermally released fluids gave the best representation of the fluids that formed primary alunite. The data are consistent with current models for the evolution of magmatic-hydrothermal and magmatic-steam fluids. Magmatic-steam fluids are vapor-dominant, average about 49 mol% H2O, and contain N2, H2, CH4, CO, Ar, He, HF, and HCl, with SO2 the dominant sulfur gas (average SO2/ H2S=202). In contrast, magmatic-hydrothermal fluids are liquid-dominant, average about 88 mol% H2O, and N2, H2, CO2, and HF, with H2S about as abundant as SO2 (average SO2/H2 S=0.7). The low SO2/H2S and N2/Ar ratios, and the near-absence of He in magmatic-hydrothermal fluids, are consistent with their derivation from degassed condensed magmatic fluids whose evolution from reduced-to-oxidized aqueous sulfur species was governed first by rock and then by fluid buffers. The high SO2/H2S and N2/Ar with significant concentrations of He in magmatic-steam fluids are consistent with derivation directly from a magma. None of the data supports the entrainment of atmospheric gases or mixing of air-saturated gases in meteoric water in either magmatic-hydrothermal or magmatic-steam fluids. Thus, the oxidation of SO2 to aqueous sulfate in the magmatic-steam fluids did not result from mixing with atmospheric oxygen. Both of the fluid types are characterized by high H2 contents that range from 0.2 mol% to the extraordinarily large amounts (66 mol%) observed in some magmatic-steam fluids. Modeling of gas speciation using SOLVGAS requires most of the gas species to have been in disequilibrium at the time of their trapping in the fluid inclusions. The origin of such extreme H2 concentrations, although problematic, is thought to be largely related to accumulation of H2 from the reaction of water with ferrous iron during the rise of magma and probably even after exsolution of fluid from a magma. The large contents of reduced gases in the inclusion fluids are far in excess of those observed in volcanic emanations, and are thought to reflect the close "sampling position" of the host alunite relative to the location of the magma. Isotope ratios of He and Ne indicate largely crustal sources for these gases in the alunite parental fluids derived from Tertiary magmas, but a greater mantle component for the gases in alunite parental fluids derived from Proterozoic magmas.

Recovery of copper from PVC multiwire cable waste by steam gasification.

PubMed

Zabłocka-Malicka, Monika; Rutkowski, Piotr; Szczepaniak, Włodzimierz

2015-12-01

Screened multiwire, PVC insulated tinned copper cable was gasified with steam at high temperature (HTSG) under atmospheric pressure for recovery of cooper. Gases from the process were additionally equilibrated at 850°C on the bed of calcined clay granules and more than 98% of C+H content in the cable was transformed to non-condensing species. Granules prepared from local clay were generally resistant for chlorination, there was also almost no deposition of metals, Cu and Sn, on the catalytic bed. It was found that 28% of chlorine reacted to form CaCl2, 71% was retained in aqueous condensate and only 0.6% was absorbed in alkaline scrubber. More than 99% of calcium existed in the process solid residue as a mixture of calcium chloride and calcium oxide/hydroxide. PVC and other hydrocarbon constituents were completely removed from the cable sample. Copper was preserved in original form and volatilization of copper species appeared insignificant. Tin was alloying with copper and its volatilization was less than 1%. Fractionation and speciation of metals, chlorine and calcium were discussed on the basis of equilibrium model calculated with HSC Chemistry software. High temperature steam gasification prevents direct use of the air and steam/water is in the process simultaneously gaseous carrier and reagent, which may be recycled together with hydrocarbon condensates. Copyright © 2015 Elsevier Ltd. All rights reserved.

Physical characteristics of sinking and floating extruded and expansion-steam pelleted feeds and their effects on water quality and growth of rainbow trout in a commercial setting

USDA-ARS?s Scientific Manuscript database

To determine the effects of feed pellet processing (extrusion and expansion-steam pelleting) and on feed physico-chemical characteristics, fecal stability, water quality, and growth performance in rainbow trout, three types of trout feed pellets (compressed sinking, extruded sinking, and extruded fl...

Modification of whole flours of navy bean, pinto bean, black bean and chickpea by steam jet cooking and drum drying

USDA-ARS?s Scientific Manuscript database

Whole bean flours of navy bean, pinto bean, black bean and chickpea were processed by excess steam jet cooking, drum drying, and milling to a state resembling the raw flours. Analysis of the structure and size of the particles, color, solubility and pasting characteristics, dietary fiber, and protei...

Steam pretreatment of Saccharum officinarum L. bagasse by adding of impregnating agents for advanced bioethanol production.

PubMed

Verardi, A; Blasi, A; De Bari, I; Calabrò, V

2016-12-01

The main byproduct of the sugarcane industry, Saccharum officinarum L. bagasse (sugarcane bagasse, SCB), is widely used as lignocellulose biomass for bio-ethanol (EtOH) production. In this research study, SCB was pretreated by steam explosion (SE) method using two different impregnating agents: sulfur dioxide (SD) and hydrogen peroxide (HP). As matter of fact, the use of impregnating agents improves the performance of SE method, increasing the concentrations of fermentable sugars after enzymatic saccharification, and decreasing the inhibitor compounds produced during the steam pretreatment step. The aim of this study was to investigate and compare the use of the two impregnating agents in various SE-conditions in order to optimize pretreatment parameters. For every pretreatment condition, it has been evaluated: concentration of fermentable sugars, glucose and xylose yields, and the effects of the inhibitor compounds on enzymatic hydrolysis step. The obtained results allow to improve the efficiency of the whole process of bio-EtOH synthesis enhancing the amount of fermentable sugars produced and the eco-sustainability of the whole process. Indeed, the optimization of steam pretreatment leads to a reduction of energy requirements and to a lower environmental impact. Copyright © 2015 Elsevier Inc. All rights reserved.

Chemical recovery process using break up steam control to prevent smelt explosions

DOEpatents

Kohl, Arthur L.; Stewart, Albert E.

1988-08-02

An improvement in a chemical recovery process in which a hot liquid smelt is introduced into a dissolving tank containing a pool of green liquor. The improvement comprises preventing smelt explosions in the dissolving tank by maintaining a first selected superatmospheric pressure in the tank during normal operation of the furnace; sensing the pressure in the tank; and further impinging a high velocity stream of steam upon the stream of smelt whenever the pressure in the tank decreases below a second selected superatmospheric pressure which is lower than said first pressure.

Assessment of iron bioavailability from different bread making processes using an in vitro intestinal cell model.

PubMed

Rodriguez-Ramiro, I; Brearley, C A; Bruggraber, S F A; Perfecto, A; Shewry, P; Fairweather-Tait, S

2017-08-01

Myo-inositol hexakisphosphate (IP6), is the main iron chelator in cereals and bread. The aim of this study was to investigate the effect of three commercial baking processes (sourdough, conventional yeast and Chorleywood Bread Making Process (CBP)) on the IP6 content of wholemeal bread, its impact on iron uptake in Caco-2 cells and the predicted bioavailability of iron from these breads with added iron, simulating a mixed-meal. The sourdough process fully degraded IP6 whilst the CBP and conventional processes reduced it by 75% compared with wholemeal flour. The iron released in solution after a simulated digestion was 8-fold higher in sourdough bread than with others but no difference in cellular iron uptake was observed. Additionally, when iron was added to the different breads digestions only sourdough bread elicited a significant ferritin response in Caco-2 cells (4.8-fold compared to the other breads) suggesting that sourdough bread could contribute towards improved iron nutrition. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

Application of a single-fluid model for the steam condensing flow prediction

NASA Astrophysics Data System (ADS)

Smołka, K.; Dykas, S.; Majkut, M.; Strozik, M.

2016-10-01

One of the results of many years of research conducted in the Institute of Power Engineering and Turbomachinery of the Silesian University of Technology are computational algorithms for modelling steam flows with a non-equilibrium condensation process. In parallel with theoretical and numerical research, works were also started on experimental testing of the steam condensing flow. This paper presents a comparison of calculations of a flow field modelled by means of a single-fluid model using both an in-house CFD code and the commercial Ansys CFX v16.2 software package. The calculation results are compared to inhouse experimental testing.

Coincident steam generator tube rupture and stuck-open safety relief valve carryover tests: MB-2 steam generator transient response test program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garbett, K; Mendler, O J; Gardner, G C

In PWR steam generator tube rupture (SGTR) faults, a direct pathway for the release of radioactive fission products can exist if there is a coincident stuck-open safety relief valve (SORV) or if the safety relief valve is cycled. In addition to the release of fission products from the bulk steam generator water by moisture carryover, there exists the possibility that some primary coolant may be released without having first mixed with the bulk water - a process called primary coolant bypassing. The MB-2 Phase II test program was designed specifically to identify the processes for droplet carryover during SGTR faultsmore » and to provide data of sufficient accuracy for use in developing physical models and computer codes to describe activity release. The test program consisted of sixteen separate tests designed to cover a range of steady-state and transient fault conditions. These included a full SGTR/SORV transient simulation, two SGTR overfill tests, ten steady-state SGTR tests at water levels ranging from very low levels in the bundle up to those when the dryer was flooded, and three moisture carryover tests without SGTR. In these tests the influence of break location and the effect of bypassing the dryer were also studied. In a final test the behavior with respect to aerosol particles in a dry steam generator, appropriate to a severe accident fault, was investigated.« less

Optimization of High Temperature and Pressurized Steam Modified Wood Fibers for High-Density Polyethylene Matrix Composites Using the Orthogonal Design Method.

PubMed

Gao, Xun; Li, Qingde; Cheng, Wanli; Han, Guangping; Xuan, Lihui

2016-10-18

The orthogonal design method was used to determine the optimum conditions for modifying poplar fibers through a high temperature and pressurized steam treatment for the subsequent preparation of wood fiber/high-density polyethylene (HDPE) composites. The extreme difference, variance, and significance analyses were performed to reveal the effect of the modification parameters on the mechanical properties of the prepared composites, and they yielded consistent results. The main findings indicated that the modification temperature most strongly affected the mechanical properties of the prepared composites, followed by the steam pressure. A temperature of 170 °C, a steam pressure of 0.8 MPa, and a processing time of 20 min were determined as the optimum parameters for fiber modification. Compared to the composites prepared from untreated fibers, the tensile, flexural, and impact strength of the composites prepared from modified fibers increased by 20.17%, 18.5%, and 19.3%, respectively. The effect on the properties of the composites was also investigated by scanning electron microscopy and dynamic mechanical analysis. When the temperature, steam pressure, and processing time reached the highest values, the composites exhibited the best mechanical properties, which were also well in agreement with the results of the extreme difference, variance, and significance analyses. Moreover, the crystallinity and thermal stability of the fibers and the storage modulus of the prepared composites improved; however, the hollocellulose content and the pH of the wood fibers decreased.

Study on characteristics of single cavitation bubble considering condensation and evaporation of kerosene steam under ultrasonic vibration honing.

PubMed

Ye, Linzheng; Zhu, Xijing; Wang, Lujie; Guo, Ce

2018-01-01

Ultrasonic vibration honing technology is an effective means for materials difficult to machine, where cavitation occurs in grinding fluid under the action of ultrasound. To investigate the changes of single cavitation bubble characteristics in the grinding area and how honing parameters influence bubble characteristics, a dynamic model of single cavitation bubble in the ultrasonic vibration honing grinding area was established. The model was based on the bubble dynamics and considered the condensation and evaporation of kerosene steam and honing processing environment. The change rules of bubble radius, temperature, pressure and number of kerosene steam molecules inside the bubble were numerically simulated in the process of bubble moving. The results show that the condensation and evaporation of kerosene steam can help to explain the changes of temperature and pressure inside the bubble. Compared with ultrasonic vibration, the amplitude of bubble radius is greatly suppressed in the ultrasonic honing environment. However, the rate of movement of the bubble is faster. Meanwhile, the minimum values of pressure and temperature are larger, and the number of kerosene steam molecules is less. By studying the effect of honing factors on the movement of the cavitation bubble, it is found that honing pressure has a greater influence on bubble evolution characteristics, while rotation speed of honing head has a minor effect and the reciprocating speed of honing head has little impacts. Copyright © 2017 Elsevier B.V. All rights reserved.

Optimization of High Temperature and Pressurized Steam Modified Wood Fibers for High-Density Polyethylene Matrix Composites Using the Orthogonal Design Method

PubMed Central

Gao, Xun; Li, Qingde; Cheng, Wanli; Han, Guangping; Xuan, Lihui

2016-01-01

The orthogonal design method was used to determine the optimum conditions for modifying poplar fibers through a high temperature and pressurized steam treatment for the subsequent preparation of wood fiber/high-density polyethylene (HDPE) composites. The extreme difference, variance, and significance analyses were performed to reveal the effect of the modification parameters on the mechanical properties of the prepared composites, and they yielded consistent results. The main findings indicated that the modification temperature most strongly affected the mechanical properties of the prepared composites, followed by the steam pressure. A temperature of 170 °C, a steam pressure of 0.8 MPa, and a processing time of 20 min were determined as the optimum parameters for fiber modification. Compared to the composites prepared from untreated fibers, the tensile, flexural, and impact strength of the composites prepared from modified fibers increased by 20.17%, 18.5%, and 19.3%, respectively. The effect on the properties of the composites was also investigated by scanning electron microscopy and dynamic mechanical analysis. When the temperature, steam pressure, and processing time reached the highest values, the composites exhibited the best mechanical properties, which were also well in agreement with the results of the extreme difference, variance, and significance analyses. Moreover, the crystallinity and thermal stability of the fibers and the storage modulus of the prepared composites improved; however, the hollocellulose content and the pH of the wood fibers decreased. PMID:28773963

System Modeling for Ammonia Synthesis Energy Recovery System

NASA Astrophysics Data System (ADS)

Bran Anleu, Gabriela; Kavehpour, Pirouz; Lavine, Adrienne; Ammonia thermochemical Energy Storage Team

2015-11-01

An ammonia thermochemical energy storage system is an alternative solution to the state-of-the-art molten salt TES system for concentrating solar power. Some of the advantages of this emerging technology include its high energy density, no heat losses during the storage duration, and the possibility of long storage periods. Solar energy powers an endothermic reaction to disassociate ammonia into hydrogen and nitrogen, which can be stored for future use. The reverse reaction is carried out in the energy recovery process; a hydrogen-nitrogen mixture flowing through a catalyst bed undergoes the exothermic ammonia synthesis reaction. The goal is to use the ammonia synthesis reaction to heat supercritical steam to temperatures on the order of 650°C as required for a supercritical steam Rankine cycle. The steam will flow through channels in a combined reactor-heat exchanger. A numerical model has been developed to determine the optimal design to heat supercritical steam while maintaining a stable exothermic reaction. The model consists of a transient one dimensional concentric tube counter-flow reactor-heat exchanger. The numerical model determines the inlet mixture conditions needed to achieve various steam outlet conditions.

Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant Hawkes; James O'Brien; Michael McKellar

2012-06-01

Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oilmore » and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier.« less

On high suppression of NO x and CO emissions in gas-turbine plants with combined gas-and-steam cycles

NASA Astrophysics Data System (ADS)

Ivanov, A. A.; Ermakov, A. N.; Shlyakhov, R. A.

2010-12-01

In this work are given results of analyzing processes of production of nitrogen oxides (NO x ) and afterburning of CO when firing natural gas at combined-cycle gas-turbine plants. It is shown that for suppressing emissions of the said microcomponents it is necessary to lower temperature in hot local zones of the flame in which NOx is formed, and, in so doing, to avoid chilling of cold flame zones that prevents afterburning of CO. The required lowering of the combustion temperature can be provided by combustion of mixtures of methane with steam, with high mixing uniformity that ensures the same and optimum fraction of the steam "ballast" in each microvolume of the flame. In addition to chilling, the steam ballast makes it possible to maintain a fairly high concentration of hydroxil radicals in the flame zone as well, and this provides high burning out of fuel and reduction in carbon monoxide emissions (active steam ballast). Due to this fact the fraction of steam when firing its mixtures with methane in a gas-turbine plant can be increased up to the weight ratio 4: 1. In this case, the concentrations of NO x and CO in emissions can be reduced to ultra-low values (less than 3 ppm).

Validation of a program for supercritical power plant calculations

NASA Astrophysics Data System (ADS)

Kotowicz, Janusz; Łukowicz, Henryk; Bartela, Łukasz; Michalski, Sebastian

2011-12-01

This article describes the validation of a supercritical steam cycle. The cycle model was created with the commercial program GateCycle and validated using in-house code of the Institute of Power Engineering and Turbomachinery. The Institute's in-house code has been used extensively for industrial power plants calculations with good results. In the first step of the validation process, assumptions were made about the live steam temperature and pressure, net power, characteristic quantities for high- and low-pressure regenerative heat exchangers and pressure losses in heat exchangers. These assumptions were then used to develop a steam cycle model in Gate-Cycle and a model based on the code developed in-house at the Institute of Power Engineering and Turbomachinery. Properties, such as thermodynamic parameters at characteristic points of the steam cycle, net power values and efficiencies, heat provided to the steam cycle and heat taken from the steam cycle, were compared. The last step of the analysis was calculation of relative errors of compared values. The method used for relative error calculations is presented in the paper. The assigned relative errors are very slight, generally not exceeding 0.1%. Based on our analysis, it can be concluded that using the GateCycle software for calculations of supercritical power plants is possible.

Comparison of steam sterilization conditions efficiency in the treatment of Infectious Health Care Waste.

PubMed

Maamari, Olivia; Mouaffak, Lara; Kamel, Ramza; Brandam, Cedric; Lteif, Roger; Salameh, Dominique

2016-03-01

Many studies show that the treatment of Infectious Health Care Waste (IHCW) in steam sterilization devices at usual operating standards does not allow for proper treatment of Infectious Health Care Waste (IHCW). Including a grinding component before sterilization allows better waste sterilization, but any hard metal object in the waste can damage the shredder. The first objective of the study is to verify that efficient IHCW treatment can occur at standard operating parameters defined by the contact time-temperature couple in steam treatment systems without a pre-mixing/fragmenting or pre-shredding step. The second objective is to establish scientifically whether the standard operation conditions for a steam treatment system including a step of pre-mixing/fragmenting were sufficient to destroy the bacterial spores in IHCW known to be the most difficult to treat. Results show that for efficient sterilization of dialysis cartridges in a pilot 60L steam treatment system, the process would require more than 20 min at 144°C without a pre-mixing/fragmenting step. In a 720L steam treatment system including pre-mixing/fragmenting paddles, only 10 min at 144°C are required to sterilize IHCW proved to be sterilization challenges such as dialysis cartridges and diapers in normal conditions of rolling. Copyright © 2016 Elsevier Ltd. All rights reserved.

Changes in iron, zinc and chelating agents during traditional African processing of maize: Effect of iron contamination on bioaccessibility.

PubMed

Greffeuille, Valérie; Polycarpe Kayodé, A P; Icard-Vernière, Christèle; Gnimadi, Muriel; Rochette, Isabelle; Mouquet-Rivier, Claire

2011-06-15

The effect of the different unit operations of processing traditionally used to produce four maize foods commonly consumed in Africa on the nutritional composition of the products was investigated, using Benin as a study context. The impact of the processes on lipid, fibre, phytate, iron and zinc contents varied with the process. The lowest IP6/Fe and IP6/Zn molar ratios, the indices used to assess Fe and Zn bioavailability were obtained in mawè, a fermented dough. Analysis of maize products highlighted a significant increase in iron content after milling, as a result of contamination by the equipment used. Evaluation of iron bioaccessibility by in vitro enzymatic digestion followed by dialysis revealed that the iron contamination, followed by lactic acid fermentation, led to a considerable increase in bioaccessible iron content. Extrinsic iron supplied to food products by the milling equipment could play a role in iron intake in developing countries. Copyright © 2010 Elsevier Ltd. All rights reserved.

An experimental study on providing a scientific evidence for seven-time alcohol-steaming of Rhei Rhizoma when clinically used.

PubMed

Sim, Yeomoon; Oh, Hyein; Oh, Dal-Seok; Kim, Namkwon; Gu, Pil Sung; Choi, Jin Gyu; Kim, Hyo Geun; Kang, Tong Ho; Oh, Myung Sook

2015-10-27

Rhei Rhizoma (RR) has been widely used as laxative and processed to alter its therapeutic actions or reduce its side effects. In this study, we evaluated experimentally the clinical application guideline that RR should be alcohol-steamed seven times before being used in elderly patients, as described in Dongeuibogam, the most famous book on Korean traditional medicine. Unprocessed RR (RR-U) was soaked in rice wine, steamed and then fully dried (RR-P1). The process was repeated four (RR-P4) or seven times (RR-P7). Reversed-phase high-performance liquid chromatography was used to determine the RR-U, RR-P1, RR-P4 and RR-P7 (RRs) constituents. To evaluate the effect of RRs on liver toxicity, human hepatoma cells (HepG2) were treated with RRs at 100 μg/mL for 4 h and then cell viabilities were measured using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide method. To confirm the effects in vivo, 5-week-old male Sprague-Dawley rats were treated with RRs at 3 g/kg/day for 21 days. Body weight and serum biochemical parameters were measured and liver histology was assessed. The levels of sennosides decreased in processed RRs in an iteration-dependent manner, while the emodin level was unaffected. In HepG2 cells, cell viability was reduced with RR-U, while the toxicity decreased according to the number of processing cycles. The changes in body weight, relative liver weight and liver enzymes of RR-U-treated rats were reduced in processed RRs-treated rats. Histopathological analysis indicated swelling and cholestasis improved following seven times alcohol-steaming cycles. These results provide experimental evidence that RR-P7 almost completely reduces RR hepatotoxicity.

J-resistance curves for Inconel 690 and Incoloy 800 nuclear steam generators tubes at room temperature and at 300 °C

NASA Astrophysics Data System (ADS)

Bergant, Marcos A.; Yawny, Alejandro A.; Perez Ipiña, Juan E.

2017-04-01

The structural integrity of steam generator tubes is a relevant issue concerning nuclear plant safety. In the present work, J-resistance curves of Inconel 690 and Incoloy 800 nuclear steam generator tubes with circumferential and longitudinal through wall cracks were obtained at room temperature and 300 °C using recently developed non-standard specimens' geometries. It was found that Incoloy 800 tubes exhibited higher J-resistance curves than Inconel 690 for both crack orientations. For both materials, circumferential cracks resulted into higher fracture resistance than longitudinal cracks, indicating a certain degree of texture anisotropy introduced by the tube fabrication process. From a practical point of view, temperature effects have found to be negligible in all cases. The results obtained in the present work provide a general framework for further application to structural integrity assessments of cracked tubes in a variety of nuclear steam generator designs.

Hydrothermal pretreatment of wood by mild steam explosion and hot water extraction.

PubMed

Wojtasz-Mucha, Joanna; Hasani, Merima; Theliander, Hans

2017-10-01

The aim of this work was to compare the two most common hydrothermal pre-treatments for wood - mild steam explosion and hot water extraction - both with the prospect of enabling extraction of hemicelluloses and facilitating further processing. Although both involve autohydrolysis of the lignocellulosic tissue, they are performed under different conditions: the most prominent difference is the rapid, disintegrating, discharge employed in the steam explosion opening up the structure. In this comparative study, the emphasis was placed on local composition of the pre-treated wood chips (of industrially relevant size). The results show that short hot water extraction treatments lead to significant variations in the local composition within the wood chips, while steam explosion accomplishes a comparably more even removal of hemicelluloses due to the advective mass transport during the explosion step. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effects of raw material extrusion and steam conditioning on feed pellet quality and nutrient digestibility of growing meat rabbits.

PubMed

Liao, Kuoyao; Cai, Jingyi; Shi, Zhujun; Tian, Gang; Yan, Dong; Chen, Delin

2017-06-01

This study was conducted to investigate the effects of raw material extrusion and steam conditioning on feed pellet quality and nutrient digestibility of growing meat rabbits, in order to determine appropriate rabbit feed processing methods and processing parameters. In Exp. 1, an orthogonal design was adopted. Barrel temperature, material moisture content and feed rate were selected as test factors, and acid detergent fiber (ADF) content was selected as an evaluation index to research the optimum extrusion parameters. In Exp. 2, a two-factor design was adopted. Four kinds of rabbit feeds were processed and raw material extrusion adopted optimum extrusion parameters of Exp. 1. A total of 40 healthy and 42-day-old rabbits with similar weight were used in a randomized design, which consisted of 4 groups and 10 replicates in each group (1 rabbits in each replicate). The adaptation period lasted for 7 d, and the digestion trial lasted for 4 d. The results showed as follows: 1) ADF was significantly affected by barrel temperature ( P  < 0.05); the optimum extrusion parameters were barrel temperature 125 °C, moisture content 16% and feed rate 9 Hz. 2) Raw material extrusion and steam conditioning both significantly decreased powder percentage, pulverization ratio and protein solubility ( P  < 0.05), significantly improved hardness and starch gelatinization degree of rabbit feed ( P  < 0.05). They both had significant interaction effects on the processing quality of rabbit feed ( P  < 0.05). 3) Extrusion significantly improved the apparent digestibility of dry matter and total energy ( P  < 0.05). Extrusion and steam conditioning both significantly improved the apparent digestibility of crude fiber (CF), ADF and NDF ( P  < 0.05), but they had no interaction effects on the apparent digestibility of rabbit feed. Thus, using extrusion and steam conditioning technology at the same time in the weaning rabbits feed processing can improve the pellet quality and nutrient apparent digestibility of rabbit feed.

40 CFR 455.21 - Specialized definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... pollution control blowdown, steam jet blowdown, vacuum pump water, pump seal water, safety equipment.../process laboratory quality control wastewater. Notwithstanding any other regulation, process wastewater...

40 CFR 455.21 - Specialized definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... pollution control blowdown, steam jet blowdown, vacuum pump water, pump seal water, safety equipment.../process laboratory quality control wastewater. Notwithstanding any other regulation, process wastewater...

40 CFR 455.21 - Specialized definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... pollution control blowdown, steam jet blowdown, vacuum pump water, pump seal water, safety equipment.../process laboratory quality control wastewater. Notwithstanding any other regulation, process wastewater...

DOE Office of Scientific and Technical Information (OSTI.GOV)

S.K. Kawatra; B. Anamerie; T.C. Eisele

The pig iron nugget process was developed as an alternative to the traditional blast furnace process by Kobe Steel. The process aimed to produce pig iron nuggets, which have similar chemical and physical properties to blast furnace pig iron, in a single step. The pig iron nugget process utilizes coal instead of coke and self reducing and fluxing dried green balls instead of pellets and sinters. In this process the environmental emissions caused by coke and sinter production, and energy lost between pellet induration (heat hardening) and transportation to the blast furnace can be eliminated. The objectives of this researchmore » were to (1) produce pig iron nuggets in the laboratory, (2) characterize the pig iron nugget produced and compare them with blast furnace pig iron, (3) investigate the furnace temperature and residence time effects on the pig iron nugget production, and (4) optimize the operational furnace temperatures and residence times. The experiments involved heat treatment of self reducing and fluxing dried green balls at various furnace temperatures and residence times. Three chemically and physically different products were produced after the compete reduction of iron oxides to iron depending on the operational furnace temperatures and/or residence times. These products were direct reduced iron (DRI), transition direct reduced iron (TDRI), and pig iron nuggets. The increase in the carbon content of the system as a function of furnace temperature and/or residence time dictated the formation of these products. The direct reduced iron, transition direct reduced iron, and pig iron nuggets produced were analyzed for their chemical composition, degree of metallization, apparent density, microstructure and microhardness. In addition, the change in the carbon content of the system with the changing furnace temperature and/or residence time was detected by optical microscopy and Microhardness measurements. The sufficient carbon dissolution required for the production of pig iron nuggets was determined. It was determined that pig iron nuggets produced had a high apparent density (6.7-7.2 gr/cm3), highly metallized, slag free structure, high iron content (95-97%), high microhardness values (> 325 HVN) and microstructure similar to white cast iron. These properties made them a competitive alternative to blast furnace pig iron.« less

Chemical, mineral composition, and sensory acceptability of cocoyam-based recipes enriched with cowpea flour.

PubMed

Olayiwola, Ibiyemi; Folaranmi, Funmi; Adebowale, Abdul-Rasaq A; Oluseye, Onabanjo; Ajoke, Sanni; Wasiu, Afolabi

2013-05-01

The study was conducted to improve cocoyam-based recipes (steamed cocoyam paste [ ebiripo ], ikokore, and fried cocoyam balls [ ojojo ]) using different blends of cocoyam and cowpea flours (100:0, 80:20, 70:30, 60:40, and 50:50). The proximate composition, mineral composition, and sensory qualities of the recipes were determined using standard analytical procedures. The recipes had significantly ( P  <   0.05) higher contents of protein, fat, crude fiber, iron, zinc, sodium, and phosphorus compared with the control recipe (100% cocoyam flour). The protein content was highest in all recipes containing 50:50 cocoyam: cowpea flour (10.79%, 10.56%, 10.36% for ojojo, ikokore, and ebiripo , respectively). However, ikokore had higher iron (2.5 mg), phosphorus (92.5 mg), and zinc (1.92 mg) contents than ebiripo and ojojo . While the 80:20 recipe for ebiripo had significantly ( P  <   0.05) higher flavor and overall acceptability scores compared with other recipes. In conclusion, enrichment of cocoyam-based recipes with cowpea flour improved the proximate composition, mineral composition, and sensory acceptability of the foods.

Processing of Advanced Cast Alloys for A-USC Steam Turbine Applications

NASA Astrophysics Data System (ADS)

Jablonski, Paul D.; Hawk, Jeffery A.; Cowen, Christopher J.; Maziasz, Philip J.

2012-02-01

The high-temperature components within conventional supercritical coal-fired power plants are manufactured from ferritic/martensitic steels. To reduce greenhouse-gas emissions, the efficiency of pulverized coal steam power plants must be increased to as high a temperature and pressure as feasible. The proposed steam temperature in the DOE/NETL Advanced Ultra Supercritical power plant is high enough (760°C) that ferritic/martensitic steels will not work for the majority of high-temperature components in the turbine or for pipes and tubes in the boiler due to temperature limitations of this class of materials. Thus, Ni-based superalloys are being considered for many of these components. Off-the-shelf forged nickel alloys have shown good promise at these temperatures, but further improvements can be made through experimentation within the nominal chemistry range as well as through thermomechanical processing and subsequent heat treatment. However, cast nickel-based superalloys, which possess high strength, creep resistance, and weldability, are typically not available, particularly those with good ductility and toughness that are weldable in thick sections. To address those issues related to thick casting for turbine casings, for example, cast analogs of selected wrought nickel-based superalloys such as alloy 263, Haynes 282, and Nimonic 105 have been produced. Alloy design criteria, melt processing experiences, and heat treatment are discussed with respect to the as-processed and heat-treated microstructures and selected mechanical properties. The discussion concludes with the prospects for full-scale development of a thick section casting for a steam turbine valve chest or rotor casing.

The alkaline solution to the emergence of life: energy, entropy and early evolution.

PubMed

Russell, Michael J

2007-01-01

The Earth agglomerates and heats. Convection cells within the planetary interior expedite the cooling process. Volcanoes evolve steam, carbon dioxide, sulfur dioxide and pyrophosphate. An acidulous Hadean ocean condenses from the carbon dioxide atmosphere. Dusts and stratospheric sulfurous smogs absorb a proportion of the Sun's rays. The cooled ocean leaks into the stressed crust and also convects. High temperature acid springs, coupled to magmatic plumes and spreading centers, emit iron, manganese, zinc, cobalt and nickel ions to the ocean. Away from the spreading centers cooler alkaline spring waters emanate from the ocean floor. These bear hydrogen, formate, ammonia, hydrosulfide and minor methane thiol. The thermal potential begins to be dissipated but the chemical potential is dammed. The exhaling alkaline solutions are frustrated in their further attempt to mix thoroughly with their oceanic source by the spontaneous precipitation of biomorphic barriers of colloidal iron compounds and other minerals. It is here we surmise that organic molecules are synthesized, filtered, concentrated and adsorbed, while acetate and methane--separate products of the precursor to the reductive acetyl-coenzyme-A pathway-are exhaled as waste. Reactions in mineral compartments produce acetate, amino acids, and the components of nucleosides. Short peptides, condensed from the simple amino acids, sequester 'ready-made' iron sulfide clusters to form protoferredoxins, and also bind phosphates. Nucleotides are assembled from amino acids, simple phosphates carbon dioxide and ribose phosphate upon nanocrystalline mineral surfaces. The side chains of particular amino acids register to fitting nucleotide triplet clefts. Keyed in, the amino acids are polymerized, through acid-base catalysis, to alpha chains. Peptides, the tenuous outer-most filaments of the nanocrysts, continually peel away from bound RNA. The polymers are concentrated at cooler regions of the mineral compartments through thermophoresis. RNA is reproduced through a convective polymerase chain reaction operating between 40 and 100 degrees C. The coded peptides produce true ferredoxins, the ubiquitous proteins with the longest evolutionary pedigree. They take over the role of catalyst and electron transfer agent from the iron sulfides. Other iron-nickel sulfide clusters, sequestered now by cysteine residues as CO-dehydrogenase and acetyl-coenzyme-A synthase, promote further chemosynthesis and support the hatchery--the electrochemical reactor--from which they sprang. Reactions and interactions fall into step as further pathways are negotiated. This hydrothermal circuitry offers a continuous supply of material and chemical energy, as well as electricity and proticity at a potential appropriate for the onset of life in the dark, a rapidly emerging kinetic structure born to persist, evolve and generate entropy while the sun shines.

Pyrite in contact with supercritical water: the desolation of steam.

PubMed

Stirling, András; Rozgonyi, Tamás; Krack, Matthias; Bernasconi, Marco

2015-07-14

The supercritical water-pyrite interface has been studied by ab initio molecular dynamics simulation. Extreme conditions are relevant in the iron-sulfur world (ISW) theory where prebiotic chemical reactions are postulated to occur at the mineral-water interface. We have investigated the properties of this interface under such conditions. We have come to the conclusion that hot-pressurized water on pyrite leads to an interface where a dry pyrite surface is in contact with the nearby SC water without significant chemical interactions. This picture is markedly different from that under ambient conditions where the surface is fully covered with adsorbed water molecules which is of relevance for the surface reactions of the ISW hypothesis.

Isolation and structural characterization of sugarcane bagasse lignin after dilute phosphoric acid plus steam explosion pretreatment and its effect on cellulose hydrolysis

Treesearch

Jijiao Zeng; Zhaohui Tong; Letian Wang; J.Y. Zhu; Lonnie Ingram

2014-01-01

The structure of lignin after dilute phosphoric acid plus steam explosion pretreatment process of sugarcane bagasse in a pilot scale and the effect of the lignin extracted by ethanol on subsequent cellulose hydrolysis were investigated. The lignin structural changes caused by pretreatment were identified using advanced nondestructive techniques such as gel permeation...

Radiation from Large Gas Volumes and Heat Exchange in Steam Boiler Furnaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makarov, A. N., E-mail: tgtu-kafedra-ese@mail.ru

2015-09-15

Radiation from large cylindrical gas volumes is studied as a means of simulating the flare in steam boiler furnaces. Calculations of heat exchange in a furnace by the zonal method and by simulation of the flare with cylindrical gas volumes are described. The latter method is more accurate and yields more reliable information on heat transfer processes taking place in furnaces.

40 CFR Table 7 to Subpart Jjj of... - Group 1 Batch Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping, and...

Code of Federal Regulations, 2012 CFR

2012-07-01

... collected—PR. d,e Carbon Adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle.2. Record and report the total...

40 CFR Table 6 to Subpart U of... - Group 1 Batch Front-End Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping...

Code of Federal Regulations, 2012 CFR

2012-07-01

... collected—PR. d,e Carbon adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record of total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. 2. Record and report the total...

40 CFR Table 6 to Subpart U of... - Group 1 Batch Front-End Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping...

Code of Federal Regulations, 2011 CFR

2011-07-01

... collected—PR. d,e Carbon adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record of total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. 2. Record and report the total...

40 CFR Table 7 to Subpart Jjj of... - Group 1 Batch Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping, and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... collected—PR. d,e Carbon Adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle.2. Record and report the total...

40 CFR Table 6 to Subpart U of... - Group 1 Batch Front-End Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping...

Code of Federal Regulations, 2013 CFR

2013-07-01

... collected—PR. d,e Carbon adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record of total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. 2. Record and report the total...

40 CFR Table 6 to Subpart U of... - Group 1 Batch Front-End Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping...

Code of Federal Regulations, 2010 CFR

2010-07-01

... collected—PR. d,e Carbon adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record of total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. 2. Record and report the total...

40 CFR Table 7 to Subpart Jjj of... - Group 1 Batch Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping, and...

Code of Federal Regulations, 2013 CFR

2013-07-01

... collected—PR. d,e Carbon Adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle.2. Record and report the total...

40 CFR Table 7 to Subpart Jjj of... - Group 1 Batch Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... collected—PR. d,e Carbon Adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle.2. Record and report the total...

40 CFR Table 6 to Subpart U of... - Group 1 Batch Front-End Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping...

Code of Federal Regulations, 2014 CFR

2014-07-01

... collected—PR. d e Carbon adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record of total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. 2. Record and report the total...

40 CFR Table 7 to Subpart Jjj of... - Group 1 Batch Process Vents and Aggregate Batch Vent Streams-Monitoring, Recordkeeping, and...

Code of Federal Regulations, 2014 CFR

2014-07-01

... collected—PR. d e Carbon Adsorber f a. Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and 1. Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle.2. Record and report the total...

High temperature electrolysis for syngas production

DOEpatents

Stoots, Carl M [Idaho Falls, ID; O'Brien, James E [Idaho Falls, ID; Herring, James Stephen [Idaho Falls, ID; Lessing, Paul A [Idaho Falls, ID; Hawkes, Grant L [Sugar City, ID; Hartvigsen, Joseph J [Kaysville, UT

2011-05-31

Syngas components hydrogen and carbon monoxide may be formed by the decomposition of carbon dioxide and water or steam by a solid-oxide electrolysis cell to form carbon monoxide and hydrogen, a portion of which may be reacted with carbon dioxide to form carbon monoxide. One or more of the components for the process, such as steam, energy, or electricity, may be provided using a nuclear power source.

Hydropyrolysis process

DOEpatents

Ullman, Alan Z.; Silverman, Jacob; Friedman, Joseph

1986-01-01

An improved process for producing a methane-enriched gas wherein a hydrogen-deficient carbonaceous material is treated with a hydrogen-containing pyrolysis gas at an elevated temperature and pressure to produce a product gas mixture including methane, carbon monoxide and hydrogen. The improvement comprises passing the product gas mixture sequentially through a water-gas shift reaction zone and a gas separation zone to provide separate gas streams of methane and of a recycle gas comprising hydrogen, carbon monoxide and methane for recycle to the process. A controlled amount of steam also is provided which when combined with the recycle gas provides a pyrolysis gas for treatment of additional hydrogen-deficient carbonaceous material. The amount of steam used and the conditions within the water-gas shift reaction zone and gas separation zone are controlled to obtain a steady-state composition of pyrolysis gas which will comprise hydrogen as the principal constituent and a minor amount of carbon monoxide, steam and methane so that no external source of hydrogen is needed to supply the hydrogen requirements of the process. In accordance with a particularly preferred embodiment, conditions are controlled such that there also is produced a significant quantity of benzene as a valuable coproduct.

Thermodynamic analyses of hydrogen production from sub-quality natural gas. Part II: Steam reforming and autothermal steam reforming

NASA Astrophysics Data System (ADS)

Huang, Cunping; T-Raissi, Ali

Part I of this paper analyzed sub-quality natural gas (SQNG) pyrolysis and autothermal pyrolysis. Production of hydrogen via direct thermolysis of SQNGs produces only 2 mol of hydrogen and 1 mol of carbon per mole of methane (CH 4). Steam reforming of SQNG (SRSQNG) could become a more effective approach because the processes produce two more moles of hydrogen via water splitting. A Gibbs reactor unit operation in the AspenPlus™ chemical process simulator was employed to accomplish equilibrium calculations for the SQNG + H 2O and SQNG + H 2O + O 2 systems. The results indicate that water and oxygen inlet flow rates do not significantly affect the decomposition of hydrogen sulfide (H 2S) at temperatures lower than 1000 °C. The major co-product of the processes is carbonyl sulfide (COS) while sulfur dimer (S 2) and carbon disulfide (CS 2) are minor by-products within this temperature range. At higher temperatures (>1300 °C), CS 2 and S 2 become major co-products. No sulfur dioxide (SO 2) or sulfur trioxide (SO 3) is formed during either SRSQNG or autothermal SRSQNG processes, indicating that no environmentally harmful acidic gases are generated.

Mathematical modeling of the dynamic storage of iron in ferritin

PubMed Central

2010-01-01

Background Iron is essential for the maintenance of basic cellular processes. In the regulation of its cellular levels, ferritin acts as the main intracellular iron storage protein. In this work we present a mathematical model for the dynamics of iron storage in ferritin during the process of intestinal iron absorption. A set of differential equations were established considering kinetic expressions for the main reactions and mass balances for ferritin, iron and a discrete population of ferritin species defined by their respective iron content. Results Simulation results showing the evolution of ferritin iron content following a pulse of iron were compared with experimental data for ferritin iron distribution obtained with purified ferritin incubated in vitro with different iron levels. Distinctive features observed experimentally were successfully captured by the model, namely the distribution pattern of iron into ferritin protein nanocages with different iron content and the role of ferritin as a controller of the cytosolic labile iron pool (cLIP). Ferritin stabilizes the cLIP for a wide range of total intracellular iron concentrations, but the model predicts an exponential increment of the cLIP at an iron content > 2,500 Fe/ferritin protein cage, when the storage capacity of ferritin is exceeded. Conclusions The results presented support the role of ferritin as an iron buffer in a cellular system. Moreover, the model predicts desirable characteristics for a buffer protein such as effective removal of excess iron, which keeps intracellular cLIP levels approximately constant even when large perturbations are introduced, and a freely available source of iron under iron starvation. In addition, the simulated dynamics of the iron removal process are extremely fast, with ferritin acting as a first defense against dangerous iron fluctuations and providing the time required by the cell to activate slower transcriptional regulation mechanisms and adapt to iron stress conditions. In summary, the model captures the complexity of the iron-ferritin equilibrium, and can be used for further theoretical exploration of the role of ferritin in the regulation of intracellular labile iron levels and, in particular, as a relevant regulator of transepithelial iron transport during the process of intestinal iron absorption. PMID:21047430

Mathematical modeling of the dynamic storage of iron in ferritin.

PubMed

Salgado, J Cristian; Olivera-Nappa, Alvaro; Gerdtzen, Ziomara P; Tapia, Victoria; Theil, Elizabeth C; Conca, Carlos; Nuñez, Marco T

2010-11-03

Iron is essential for the maintenance of basic cellular processes. In the regulation of its cellular levels, ferritin acts as the main intracellular iron storage protein. In this work we present a mathematical model for the dynamics of iron storage in ferritin during the process of intestinal iron absorption. A set of differential equations were established considering kinetic expressions for the main reactions and mass balances for ferritin, iron and a discrete population of ferritin species defined by their respective iron content. Simulation results showing the evolution of ferritin iron content following a pulse of iron were compared with experimental data for ferritin iron distribution obtained with purified ferritin incubated in vitro with different iron levels. Distinctive features observed experimentally were successfully captured by the model, namely the distribution pattern of iron into ferritin protein nanocages with different iron content and the role of ferritin as a controller of the cytosolic labile iron pool (cLIP). Ferritin stabilizes the cLIP for a wide range of total intracellular iron concentrations, but the model predicts an exponential increment of the cLIP at an iron content > 2,500 Fe/ferritin protein cage, when the storage capacity of ferritin is exceeded. The results presented support the role of ferritin as an iron buffer in a cellular system. Moreover, the model predicts desirable characteristics for a buffer protein such as effective removal of excess iron, which keeps intracellular cLIP levels approximately constant even when large perturbations are introduced, and a freely available source of iron under iron starvation. In addition, the simulated dynamics of the iron removal process are extremely fast, with ferritin acting as a first defense against dangerous iron fluctuations and providing the time required by the cell to activate slower transcriptional regulation mechanisms and adapt to iron stress conditions. In summary, the model captures the complexity of the iron-ferritin equilibrium, and can be used for further theoretical exploration of the role of ferritin in the regulation of intracellular labile iron levels and, in particular, as a relevant regulator of transepithelial iron transport during the process of intestinal iron absorption.

Combined steam-ultrasound treatment of 2 seconds achieves significant high aerobic count and Enterobacteriaceae reduction on naturally contaminated food boxes, crates, conveyor belts, and meat knives.

PubMed

Musavian, Hanieh S; Butt, Tariq M; Larsen, Annette Baltzer; Krebs, Niels

2015-02-01

Food contact surfaces require rigorous sanitation procedures for decontamination, although these methods very often fail to efficiently clean and disinfect surfaces that are visibly contaminated with food residues and possible biofilms. In this study, the results of a short treatment (1 to 2 s) of combined steam (95°C) and ultrasound (SonoSteam) of industrial fish and meat transportation boxes and live-chicken transportation crates naturally contaminated with food and fecal residues were investigated. Aerobic counts of 5.0 to 6.0 log CFU/24 cm(2) and an Enterobacteriaceae spp. level of 2.0 CFU/24 cm(2) were found on the surfaces prior to the treatment. After 1 s of treatment, the aerobic counts were significantly (P < 0.0001) reduced, and within 2 s, reductions below the detection limit (<10 CFU) were reached. Enterobacteriaceae spp. were reduced to a level below the detection limit with only 1 s of treatment. Two seconds of steam-ultrasound treatment was also applied on two different types of plastic modular conveyor belts with hinge pins and one type of flat flexible rubber belt, all visibly contaminated with food residues. The aerobic counts of 3.0 to 5.0 CFU/50 cm(2) were significantly (P < 0.05) reduced, while Enterobacteriaceae spp. were reduced to a level below the detection limit. Industrial meat knives were contaminated with aerobic counts of 6.0 log CFU/5 cm(2) on the handle and 5.2 log CFU/14 cm(2) on the steel. The level of Enterobacteriaceae spp. contamination was approximately 2.5 log CFU on the handle and steel. Two seconds of steam-ultrasound treatment reduced the aerobic counts and Enterobacteriaceae spp. to levels below the detection limit on both handle and steel. This study shows that the steam-ultrasound treatment may be an effective replacement for disinfection processes and that it can be used for continuous disinfection at fast process lines. However, the treatment may not be able to replace efficient cleaning processes used to remove high loads of debris.

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101/102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

DOE Office of Scientific and Technical Information (OSTI.GOV)

DUNCAN JB; HUBER HJ

2011-06-08

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannahmore » River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'« less

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

DOE Office of Scientific and Technical Information (OSTI.GOV)

DUNCAN JB; HUBER HJ

2011-04-21

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannahmore » River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.« less

Process for the synthesis of iron powder

DOEpatents

Not Available

1982-03-06

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Process for the synthesis of iron powder

DOEpatents

Welbon, William W.

1983-01-01

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Materials processing threshold report: 2. Use of low gravity for cast iron process development

NASA Technical Reports Server (NTRS)

Frankhouser, W. L.

1980-01-01

Potential applications of a low gravity environment of interest to the commercial producers of cast iron were assessed to determine whether low gravity conditions offer potential opportunities to producers for improving cast iron properties and expanding the use of cast irons. The assessment is limited to the gray and nodular types of iron, however, the findings are applicable to all cast irons. The potential advantages accrued through low gravity experiments with cast irons are described.

In situ steam enhanced recovery process, Hughes Environmental Systems, Inc. innovative technology evaluation report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cook, K.

1995-01-01

This Innovative Technology Evaluation report summarizes the findings of an evaluation of the in situ Steam Enhanced Recovery Process (SERP) operated by Hughes Environmental Systems, Inc. at the Rainbow Disposal facility in Huntington Beach, California. The technology demonstration was conducted concurrent with a full-scale remedial action using the technology on an underground diesel leak. From this demonstration, it was concluded that the SERP process did not achieve the remedial goals desired at this site and there were significant operational problems. It is believed that these operational problems can be solved and substantially better performance can be attained. The cost ofmore » treatment was quite low, as expected with an in-situ process.« less

Development of the CCP-200 mathematical model for Syzran CHPP using the Thermolib software package

NASA Astrophysics Data System (ADS)

Usov, S. V.; Kudinov, A. A.

2016-04-01

Simplified cycle diagram of the CCP-200 power generating unit of Syzran CHPP containing two gas turbines PG6111FA with generators, two steam recovery boilers KUP-110/15-8.0/0.7-540/200, and one steam turbine Siemens SST-600 (one-cylinder with two variable heat extraction units of 60/75 MW in heatextraction and condensing modes, accordingly) with S-GEN5-100 generators was presented. Results of experimental guarantee tests of the CCP-200 steam-gas unit are given. Brief description of the Thermolib application for the MatLab Simulink software package is given. Basic equations used in Thermolib for modeling thermo-technical processes are given. Mathematical models of gas-turbine plant, heat-recovery steam generator, steam turbine and integrated plant for power generating unit CCP-200 of Syzran CHPP were developed with the help of MatLab Simulink and Thermolib. The simulation technique at different ambient temperature values was used in order to get characteristics of the developed mathematical model. Graphic comparison of some characteristics of the CCP-200 simulation model (gas temperature behind gas turbine, gas turbine and combined cycle plant capacity, high and low pressure steam consumption and feed water consumption for high and low pressure economizers) with actual characteristics of the steam-gas unit received at experimental (field) guarantee tests at different ambient temperature are shown. It is shown that the chosen degrees of complexity, characteristics of the CCP-200 simulation model, developed by Thermolib, adequately correspond to the actual characteristics of the steam-gas unit received at experimental (field) guarantee tests; this allows considering the developed mathematical model as adequate and acceptable it for further work.

Atmospheric Processing and Iron Mobilization of Ilmenite: Iron-Containing Ternary Oxide in Mineral Dust Aerosol.

PubMed

Hettiarachchi, Eshani; Hurab, Omar; Rubasinghege, Gayan

2018-02-08

Over the last several decades, iron has been identified as a limiting nutrient in about half of the world's oceans. Its most significant source is identified as deposited iron-containing mineral dust that has been processed during atmospheric transportation. The current work focuses on chemical and photochemical processing of iron-containing mineral dust particles in the presence of nitric acid, and an organic pollutant dimethyl sulfide under atmospherically relevant conditions. More importantly, ilmenite (FeTiO 3 ) is evaluated as a proxy for the iron-containing mineral dust. The presence of titanium in its lattice structure provides higher complexity to mimic mineral dust, yet it is simple enough to study reaction pathways and mechanisms. Here, spectroscopic methods are combined with dissolution measurements to investigate atmospheric processing of iron in mineral dust, with specific focus on particle mineralogy, particle size, and their environmental conditions (i.e., pH and solar flux). Our results indicate that the presence of titanium elemental composition enhances iron dissolution from mineral dust, at least by 2-fold comparison with its nontitanium-containing counterparts. The extent of iron dissolution and speciation is further influenced by the above factors. Thus, our work highlights these important, yet unconsidered, factors in the atmospheric processing of iron-containing mineral dust aerosol.

Modulating conversion of isoflavone glycosides to aglycones using crude beta-glycosidase extracts from almonds and processed soy.

PubMed

Ahn-Jarvis, J H; Teegarden, M D; Schwartz, S J; Lee, K; Vodovotz, Y

2017-12-15

Food processing alters the physicochemical state of soy which can enhance chemical and enzymatic conversion of isoflavones to their aglycone forms. This study investigated the role of β-glycosidase from processed soy-ingredient mixture (SIM) or almonds, and examined the impact of isoflavone composition in mediating conversion to aglycones. β-Glycosidase activity was quantified using p-nitrophenol-β-d-glucopyranoside and SIM isoflavone extracts. Almond β-glycosidase activity was significantly (p<0.001) reduced after roasting (99% reduction) or steaming (97% reduction) compared to raw almonds. SIM β-glycosidase activity, however, increased, with steaming by 66% (p<0.001) and with roasting by 52% (p=0.022), compared to raw SIM. After incubation with β-glycosidase, percentage of aglycone (total aglycone/total isoflavones) in SIM isoflavone extracts increased significantly in raw (35%), fermented (48%), roasted (88%) and steamed (91%) SIM, compared to their initial (∼5%) compositions. Manipulation of β-glycosidase activity and isoflavone composition can be used to modulate aglycone content in soy food products. Copyright © 2017 Elsevier Ltd. All rights reserved.

Xylose production from corn stover biomass by steam explosion combined with enzymatic digestibility.

PubMed

Liu, Zhi-Hua; Chen, Hong-Zhang

2015-10-01

A novel conversion process using steam explosion combined with enzymatic digestibility was exploited to increase sugar yield. Results showed that glucan and xylan recovery decreased with the increase of holding temperature and residence time in SE, respectively, while glucan and xylan conversion exhibited an opposite trend. The optimal conditions of steam explosion were 160 °C and 48 min, under which glucan and xylan recovery was 93.4% and 71.6%, respectively. Glucan and xylan conversion at 18% solid loading by periodic peristalsis increased by 3.4-5.8% and 4.5-6.2%, respectively, compared with that by water baths shaker. In the whole process, glucose, xylose and total sugar yield reached to 77.3%, 62.8% and 72.3%, respectively. The yield of hydroxymethyl furfural, furfural and lignin-derived products was 6.3 × 10(-2), 7.5 × 10(-2) and less than 3.7 × 10(-2) g/100 g feedstock, respectively. This novel conversion process increased sugar recovery, reduced degradation products formation, improved digestibility efficiency, and hence increased sugar yield. Copyright © 2015 Elsevier Ltd. All rights reserved.

Rapid Generation of Superheated Steam Using a Water-containing Porous Material

NASA Astrophysics Data System (ADS)

Mori, Shoji; Okuyama, Kunito

Heat treatment by superheated steam has been utilized in several industrial fields including sterilization, desiccation, and cooking. In particular, cooking by superheated steam is receiving increased attention because it has advantages of reducing the salt and fat contents in foods as well as suppressing the oxidation of vitamin C and fat. In this application, quick startup and cut-off responses are required. Most electrically energized steam generators require a relatively long time to generate superheated steam due to the large heat capacities of the water in container and of the heater. Zhao and Liao (2002) introduced a novel process for rapid vaporization of subcooled liquid, in which a low-thermal-conductivity porous wick containing water is heated by a downward-facing grooved heating block in contact with the upper surface of the wick structure. They showed that saturated steam is generated within approximately 30 seconds from room-temperature water at a heat flux 41.2 kW⁄m2. In order to quickly generate superheated steam of approximately 300°C, which is required for cooking, the heat capacity of the heater should be as small as possible and the imposed heat flux should be so high enough that the porous wick is able to dry out in the vicinity of the contact with the heater and that the resulting heater temperature becomes much higher than the saturation temperature. The present paper proposes a simple structured generator to quickly produce superheated steam. Only a fine wire heater is contacted spirally on the inside wall in a hollow porous material. The start-up, cut-off responses and the rate of energy conversion for input power are investigated experimentally. Superheated steam of 300°C is produced in approximately 19 seconds from room-temperature water for an input power of 300 W. The maximum rate of energy conversion in the steady state is approximately 0.9.

The effects of oat β-glucan incorporation on the quality, structure, consumer acceptance and glycaemic response of steamed bread.

PubMed

Wang, Lei; Ye, Fayin; Feng, Liyuan; Wei, Fubin; Zhao, Guohua

2017-12-01

The objective of this study was to evaluate the effects of the incorporation of oat β-glucan (OβG) on the sensory and nutritional quality of steamed bread. Wheat flour was substituted with OβG at levels varying from 0 g/100 g to 5 g/100 g. The results showed that the products containing 1 g/100 g and 3 g/100 g OβG produced a comparable overall consumer acceptance while a significantly lower score was given to the product with 5 g/100 g. Nutritionally, the presence of OβG impeded in vitro starch hydrolysis by amylolytic enzymes. More importantly, the addition of OβG up to 5 g/100 g did bring about a lower in vitro predicted glycaemic index to steamed bread, but it generated insignificant effects on the in vivo glycaemic response. The current work first demonstrated the feasibility of fabricating OβG-enriched steamed bread and its nutritional superiority compared to the corresponding normal product. Modern methods of food elaboration and processing frequently reduce the content of dietary fiber (DF). Despite the well-known health benefits of DF consumption, average intake levels still fall far below recommended ones. Oat β-glucan (OβG) is a kind of indigestible polysaccharide with diverse bioactivity. This article evaluated the effects of OβG incorporation on quality, structure, consumer acceptance, and glycaemic response of steamed bread. The addition of less than 3 g/100 g of OβG had negligible effects on the consumer acceptance of steamed bread. The enrichment at 5 g/100 g indeed deteriorated the consumer acceptance. Moreover, OβG highly lowered the glycaemic response of steamed bread. The current work first demonstrated the feasibility of fabricating OβG-enriched steamed bread and its nutritional superiority compared to the corresponding normal product. OβG enriched steamed bread may offer an alternative to improve DF intake of residents. © 2017 Wiley Periodicals, Inc.

Advanced steam power plant concepts with optimized life-cycle costs: A new approach for maximum customer benefit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seiter, C.

1998-07-01

The use of coal power generation applications is currently enjoying a renaissance. New highly efficient and cost-effective plant concepts together with environmental protection technologies are the main factors in this development. In addition, coal is available on the world market at attractive prices and in many places it is more readily available than gas. At the economical leading edge, standard power plant concepts have been developed to meet the requirements of emerging power markets. These concepts incorporate the high technological state-of-the-art and are designed to achieve lowest life-cycle costs. Low capital cost, fuel costs and operating costs in combination withmore » shortest lead times are the main assets that make these plants attractive especially for IPPs and Developers. Other aspects of these comprehensive concepts include turnkey construction and the willingness to participate in BOO/BOT projects. One of the various examples of such a concept, the 2 x 610-MW Paiton Private Power Project Phase II in Indonesia, is described in this paper. At the technological leading edge, Siemens has always made a major contribution and was pacemaker for new developments in steam power plant technology. Modern coal-fired steam power plants use computer-optimized process and plant design as well as advanced materials, and achieve efficiencies exceeding 45%. One excellent example of this high technology is the world's largest lignite-fired steam power plant Schwarze Pumpe in Germany, which is equipped with two 800 MW Siemens steam turbine generators with supercritical steam parameters. The world's largest 50-Hz single-shaft turbine generator with supercritical steam parameters rated at 1025 MW for the Niederaussem lignite-fired steam power plant in Germany is a further example of the sophisticated Siemens steam turbine technology and sets a new benchmark in this field.« less

Process for the synthesis of iron powder

DOEpatents

Welbon, W.W.

1983-11-08

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder. 2 figs.

Kinetics of Fe Release from Organic Ligand Complexes: Implications for Fe Isotopes?

NASA Astrophysics Data System (ADS)

Nuester, J.; Liermann, L. J.; Brantley, S. L.

2006-12-01

Although iron is the fourth most abundant element in the earth's surface, its bioavailability is limited by its natural tendency to form insoluble iron (oxyhydr)oxides in terrestrial and marine environments. Paradoxically, iron is an essential nutrient for virtually all living cells, so in order to survive, organisms must develop mechanisms to solubilize iron. To acquire iron, organisms synthesize and release iron-specific chelators called siderophores. These siderophores facilitate the transformation of insoluble crystal-bound iron to organically ligand-bound dissolved iron. The reverse process whereby ferric iron is released from siderophores resulting in the precipitation of iron (oxyhydr)oxides or complexation by other iron chelators is an important but not well studied process in the B-horizon of soils. Fe mobility is documented in soils where Fe is often extracted at the top and precipitated at depth. Both the concentration and isotopic signature of Fe varies with depth due to dissolution, precipitation, sorption, and biological processes. Our study is focused on measurement of isotopic fractionation during this reverse process. In a first approach to understand iron liberation form organic ligands, we mimic this process using a reductive mechanism. We use acetohydroxamic acid (aha), EDTA and desferrioxamine B (DFMB) as test ligands to investigate iron release by sodium ascorbate at varying pH. Our first kinetic measurements showed significant differences in iron release depending on pH and stability of the iron complex. Within one hour all iron is released from aha with a small pH effect in the pH range between 4 and 6. In contrast, the pH has a major influence on the iron release from EDTA and DFMB. Depending on pH, total iron is released from EDTA within 24 hours, while only an incomplete iron release from DFMB could be observed within two weeks. These strong kinetic differences in iron release as a consequence of iron reduction are expected to result in significant iron isotope effects, and we are testing for these effects. For example, we expect to see enrichment of light isotopes in the early released fractions as iron is reduced (like effects observed by Wiederhold et al. (2006) for ligand-controlled and reductive dissolution of goethite). Such kinetic isotope effects should be particularly strong for iron release from siderophores with high Fe affinities like DFMB (log ß_(Fe(III)) = 30.60). We are also investigating other mechanisms to liberate iron from organic ligands including a pathway with extracellular iron reductases.

Radial Microchannel Reactor (RMR) used in Steam Reforming CH4

DTIC Science & Technology

2013-05-13

process on land and at sea will reduce CO2 emission and enable cost reductions in the generation of energy in many small market economies. Peter R...size of GTL process on land and at sea will reduce CO2 emission and enable cost reductions in the generation of energy in many small market ...distribution of a 3.3:1 steam-methane mixture at 750 °C and 11 bar is: H2 45.8%, H2O 36.99%, CO 6.365%, CO2 6.681% and CH4 4.14% Barring any coking , this

An alternative process to treat boiler feed water for reuse.

PubMed

Guirgis, Adel; Ghosh, Jyoti P; Achari, Gopal; Langford, Cooper H; Banerjee, Daliya

2012-09-01

A bench-scale process to treat boiler feed water for reuse in steam generation was developed. Industrial water samples from a steam-assisted gravity drainage plant in northern Alberta, Canada, were obtained and samples characterized. The technology, which consists of coagulation-settling to remove oil/grease and particulates followed by an advanced oxidative treatment, led to clean water samples with negligible organic carbon. Coagulation followed by settling removed most particulates and some insoluble organics. The advanced oxidative treatment removed any remaining color in the samples, decreased the organic content to near-zero, and provided water ready for reuse.

Compact solar autoclave based on steam generation using broadband light-harvesting nanoparticles.

PubMed

Neumann, Oara; Feronti, Curtis; Neumann, Albert D; Dong, Anjie; Schell, Kevin; Lu, Benjamin; Kim, Eric; Quinn, Mary; Thompson, Shea; Grady, Nathaniel; Nordlander, Peter; Oden, Maria; Halas, Naomi J

2013-07-16

The lack of readily available sterilization processes for medicine and dentistry practices in the developing world is a major risk factor for the propagation of disease. Modern medical facilities in the developed world often use autoclave systems to sterilize medical instruments and equipment and process waste that could contain harmful contagions. Here, we show the use of broadband light-absorbing nanoparticles as solar photothermal heaters, which generate high-temperature steam for a standalone, efficient solar autoclave useful for sanitation of instruments or materials in resource-limited, remote locations. Sterilization was verified using a standard Geobacillus stearothermophilus-based biological indicator.

[Sterilization effect analysis of B-class pulsation table top vacuum sterilizer to dental handpieces].

PubMed

Zeng, Shu-Rong; Jiang, Bo; Xiao, Xiao-Rong

2007-06-01

Discuss sterilization effect of B-class pulsation table top vacuum pressure steam sterilizer for dental handpiece. Analysis selection of sterilizer for dental handpiece and sterilization management processes and sterilization effect monitoring, evaluation of monitoring result and effective sterilization method. The B-class pulsation table top vacuum pressure steam sterilizer to dental handpiece in West China Stomatological Hospital of Sichuan University met the requirement of the chemical and biological monitoring. Its efficiency of sterilization was 100%. The results of aerobic culture, anaerobic culture, B-type hepatitis mark monitoring to sterilized dental handpiece were negative. It is effective method for dental handpiece sterilization to use B-class pulsation table top vacuum pressure steam sterilizer.

Profit from a Problem

NASA Technical Reports Server (NTRS)

1981-01-01

The Refuse-fired Steam Generating Facility was jointly sponsored by Hampton, NASA Langley and Langley Air Force Base. The facility disposes of all solid waste from the NASA Center, the Air Force Base, the Army's Fort Monroe and other federal installations in the area, and accommodates about 70 percent of Hampton's municipal waste. Incinerated refuse is reduced to a readily-disposable ash whose volume is one-seventh that of the solid waste brought to the plant. The energy produced in the burning process is converted to steam for use in research and administrative facilities at Langley Research Center. Plant is expected to produce some 300 million pounds of steam annually, about 85 percent of Langley Research Center's needs.

Simulation and analysis of main steam control system based on heat transfer calculation

NASA Astrophysics Data System (ADS)

Huang, Zhenqun; Li, Ruyan; Feng, Zhongbao; Wang, Songhan; Li, Wenbo; Cheng, Jiwei; Jin, Yingai

2018-05-01

In this paper, after thermal power plant 300MW boiler was studied, mat lab was used to write calculation program about heat transfer process between the main steam and boiler flue gas and amount of water was calculated to ensure the main steam temperature keeping in target temperature. Then heat transfer calculation program was introduced into Simulink simulation platform based on control system multiple models switching and heat transfer calculation. The results show that multiple models switching control system based on heat transfer calculation not only overcome the large inertia of main stream temperature, a large hysteresis characteristic of main stream temperature, but also adapted to the boiler load changing.

The Outer Space as an Educational Motivation

NASA Astrophysics Data System (ADS)

Pérez-Pérez, Melquíades; Hernández-López, Montserrat

2017-06-01

STEAM is an educational approach to learning that uses Science, Technology, Engineering, the Arts and Mathematics as access points for guiding student inquiry, dialogue, and critical thinking. The end results are students who take thoughtful risks, engage in experiential learning, persist in problem-solving, embrace collaboration, and work through the creative process. The Outer Space is a window to the past and the future of our travel around the history of the Universe and can be used as a educational tool in primary and secondary education. This paper talks about the integration of the resources of European Space Agency, Space Awareness, Nuclio, Scientix and Schoolnet as motivation to integrate STEAM methodology in secondary education. Keywords: STEAM, outer space, motivation, methodology

Synergistic effect of steam and lactic acid against Escherichia coli O157:H7, Salmonella Typhimurium, and Listeria monocytogenes biofilms on polyvinyl chloride and stainless steel.

PubMed

Ban, Ga-Hee; Park, Sang-Hyun; Kim, Sang-Oh; Ryu, Sangryeol; Kang, Dong-Hyun

2012-07-02

This study was designed to investigate the individual and combined effects of steam and lactic acid (LA) on the inactivation of biofilms formed by Escherichia coli O157:H7, Salmonella Typhimurium, and Listeria monocytogenes on polyvinyl chloride (PVC) and stainless steel. Six day old biofilms were developed on PVC and stainless steel coupons by using a mixture of three strains each of three foodborne pathogens at 25°C. After biofilm development, PVC and stainless steel coupons were treated with LA alone (immersed in 0.5% or 2% for 5s, 15s, and 30s), steam alone (on both sides for 5, 10, and 20s), and the combination of steam and LA. The numbers of biofilm cells of the three foodborne pathogens were significantly (p<0.05) reduced as the amount of LA and duration of steam exposure increased. There was a synergistic effect of steam and LA on the viability of biofilm cells of the three pathogens. For all biofilm cells of the three foodborne pathogens, reduction levels of individual treatments ranged from 0.11 to 2.12 log CFU/coupon. The combination treatment of steam and LA achieved an additional 0.2 to 2.11 log reduction compared to the sum of individual treatments. After a combined treatment of immersion in 2% LA for 15s or 30s followed by exposure to steam for 20s, biofilm cells of the three pathogens were reduced to below the detection limit (1.48 log). From the results of this study, bacterial populations of biofilms on PVC coupons did not receive the same thermal effect as on stainless steel coupons. Effectiveness of steam and LA may be attributed to the difference between Gram-negative and Gram-positive characteristics of the bacteria studied. The results of this study suggest that the combination of steam and LA has potential as a biofilm control intervention for food processing facilities. Copyright © 2012 Elsevier B.V. All rights reserved.

Gasification system

DOEpatents

Haldipur, Gaurang B.; Anderson, Richard G.; Cherish, Peter

1985-01-01

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Gasification system

DOEpatents

Haldipur, Gaurang B.; Anderson, Richard G.; Cherish, Peter

1983-01-01

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Steam injection pressing : large panel fabrication with southern hardwoods

Treesearch

Robert L. Geimer; Eddie W. Price

1986-01-01

Large 4 by 8 ft (1.22 by 2.44 m) panels were made using a steam injection method of pressing. Homogenously constructed flakeboards were fabricated from southern red oak, sweet gum, and a mixture of the two species using both isocyanate and phenolic resins. Isocyanate was especially suited to the process and 1-1/2 in. (38 mm) thick panels were pressed in less than 150...

Influence of reactivation on the electrochemical performances of activated carbon based on coconut shell.

PubMed

Geng, Xin; Li, Lixiang; Zhang, Meiling; An, Baigang; Zhu, Xiaoming

2013-12-01

Coconut shell-based activated carbon (AC) were prepared by CO2 activation, and then the ACs with higher mesopore ratio were obtained by steam activation and by impregnating iron catalyst followed by steam activation, respectively. The AC with the highest mesopore ratio (AChmr) shows superior capacitive behavior, power output and high-frequency performance in supercapacitors. The results should attribute to the connection of its wide micropores and mesopores larger than 3 nm, which is more favorable for fast ionic transportation. The pore size distribution exhibits that the mesopore ratios of the ACs are significantly increased by reactivation of steam or catalyst up to 75% and 78%, respectively. As evidenced by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic measurements, the AChmr shows superior capacitive behaviors, conductivity and performance of electrolytic ionic transportation. The response current densities are evidently enhanced through the cyclic voltammery test at 50 mV/sec scan rate. The electrochemical impedance spectroscopy demonstrates that the conductivity and ion transport performance of the ACs are improved. The specific capacitances of the ACs were increased from 140 to 240 F/g at 500 mA/g current density. The AChmr can provide much higher power density while still maintaining good energy density, and demonstrate excellent high-frequency performances. The pore structure and conductivity of the AChmr also improve the cycleability and self-discharge of supercapacitors. Such AChmr exhibits a great potential in supercapacitors, particularly for applications where high power output and good high-frequency capacitive performances are required. Copyright © 2013 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Utilization of acetone-butanol-ethanol-water mixture obtained from biomass fermentation as renewable feedstock for hydrogen production via steam reforming: Thermodynamic and energy analyses.

PubMed

Kumar, Brajesh; Kumar, Shashi; Sinha, Shishir; Kumar, Surendra

2018-08-01

A thermodynamic equilibrium analysis on steam reforming process to utilize acetone-butanol-ethanol-water mixture obtained from biomass fermentation as biorenewable fuel has been performed to produce clean energy carrier H 2 via non-stoichiometric approach namely Gibbs free energy minimization method. The effect of process variables such as temperature (573-1473 K), pressure (1-10 atm), and steam/fuel molar feed ratio (F ABE  = 5.5-12) have been investigated on equilibrium compositions of products, H 2 , CO, CO 2 , CH 4 and solid carbon. The best suitable conditions for maximization of desired product H 2 , suppression of CH 4 , and inhibition of solid carbon are 973 K, 1 atm, steam/fuel molar feed ratio = 12. Under these conditions, the maximum molar production of hydrogen is 8.35 with negligible formation of carbon and methane. Furthermore, the energy requirement per mol of H 2 (48.96 kJ), thermal efficiency (69.13%), exergy efficiency (55.09%), exergy destruction (85.36 kJ/mol), and generated entropy (0.29 kJ/mol.K) have been achieved at same operating conditions. Copyright © 2018 Elsevier Ltd. All rights reserved.

A numerical analysis of heat and mass transfer during the steam reforming process of ethane

NASA Astrophysics Data System (ADS)

Tomiczek, Marcin; Kaczmarczyk, Robert; Mozdzierz, Marcin; Brus, Grzegorz

2017-11-01

This paper presents a numerical analysis of heat and mass transfer during the steam reforming of ethane. From a chemical point of view, the reforming process of heavy hydrocarbons, such as ethane, is complex. One of the main issue is a set of undesired chemical reactions that causes the deposition of solid carbon and consequently blocks the catalytic property of a reactor. In the literature a carbon deposition regime is selected by thermodynamical analysis to design safe operation conditions. In the case of Computational Fluid Dynamic (CFD, hereafter) models each control volume should be investigated to determinate if carbon deposition is thermodynamically favourable. In this paper the authors combine equilibrium and kinetics analysis to simulate the steam reforming of methane-ethane rich fuel. The results of the computations were juxtaposed with experimental data for methane steam reforming, and good agreement was found. An analysis based on the kinetics of reactions was conducted to predict the influence of temperature drop and non-equilibrium composition on solid carbon deposition. It was found that strong non-uniform temperature distribution in the reactor causes conditions favourable for carbon deposition at the inlet of the reformer. It was shown that equilibrium calculations, often used in the literature, are insufficient.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mann, M.K.

Technoeconomic analyses have been conducted on two processes to produce hydrogen from biomass: indirectly-heated gasification of biomass followed by steam reforming of the syngas, and biomass pyrolysis followed by steam reforming of the pyrolysis oil. The analysis of the gasification-based process was highly detailed, including a process flowsheet, material and energy balances calculated with a process simulation program, equipment cost estimation, and the determination of the necessary selling price of hydrogen. The pyrolysis-based process analysis was of a less detailed nature, as all necessary experimental data have not been obtained; this analysis is a follow-up to the preliminary economic analysismore » presented at the 1994 Hydrogen Program Review. A coproduct option in which pyrolysis oil is used to produce hydrogen and a commercial adhesive was also studied for economic viability. Based on feedstock availability estimates, three plant sizes were studied: 907 T/day, 272 T/day, and 27 T/day. The necessary selling price of hydrogen produced by steam reforming syngas from the Battelle Columbus Laboratories indirectly heated biomass gasifier falls within current market values for the large and medium size plants within a wide range of feedstock costs. Results show that the small scale plant does not produce hydrogen at economically competitive prices, indicating that if gasification is used as the upstream process to produce hydrogen, local refueling stations similar to current gasoline stations, would probably not be feasible.« less

Characterization and taste-masking evaluation of acetaminophen granules: comparison between different preparation methods in a high-shear mixer.

PubMed

Albertini, Beatrice; Cavallari, Cristina; Passerini, Nadia; Voinovich, Dario; González-Rodríguez, Marisa L; Magarotto, Lorenzo; Rodriguez, Lorenzo

2004-02-01

The aim of this study was to prepare and to investigate acetaminophen taste-masked granules obtained in a high-shear mixer using three different wet granulation methods (method A: water granulation, method B: granulation with a polyvinylpyrrolidone (PVP) binding solution and method C: steam granulation). The studied formulation was: acetaminophen 15%, alpha-lactose monohydrate 30%, cornstarch 45%, polyvinylpyrrolidone K30 5% and orange flavour 5% (w/w). In vitro dissolution studies, performed at pH 6.8, showed that steam granules enabled the lower dissolution rate in comparison to the water and binding solution granules; these results were then confirmed by their lower surface reactivity (D(R)) during the dissolution process. Moreover, the results of the gustatory sensation test performed by six volunteers confirmed the taste-masking effects of the granules, especially steam granules (P<0.001). Morphological, fractal and porosity analysis were then performed to explain the dissolution profiles and the results of the gustatory sensation test. Scanning electron microscopy (SEM) analysis revealed the smoother and the more regular surface of steam granules with respect to the samples obtained using methods A and B; these results were also confirmed by their lower fractal dimension (D(s)) and porosity values. Finally, differential scanning calorimetry (DSC) results showed a shift of the melting point of the drug, which was due to the simple mixing of the components and not to the granulation processes. In conclusion, the steam granulation technique resulted a suitable method to comply the purpose of this work, without modifying the availability of the drug.

Influence of atmospheric processes on the solubility and composition of iron in Saharan dust

DOE PAGES

Longo, Amelia F.; Feng, Yan; Lai, Barry; ...

2016-06-10

Aerosol iron was examined in Saharan dust plumes using a combination of iron near-edge X-ray absorption spectroscopy and wet-chemical techniques. Aerosol samples were collected at three sites located in the Mediterranean, the Atlantic, and Bermuda to characterize iron at different atmospheric transport lengths and time scales. Iron(III) oxides were a component of aerosols at all sampling sites and dominated the aerosol iron in Mediterranean samples. In Atlantic samples, iron(II and III) sulfate, iron(III) phosphate, and iron(II) silicates were also contributors to aerosol composition. With increased atmospheric transport time, iron(II) sulfates are found to become more abundant, aerosol iron oxidation statemore » became more reduced, and aerosol acidity increased. As a result, atmospheric processing including acidic reactions and photoreduction likely influence the form of iron minerals and oxidation state in Saharan dust aerosols and contribute to increases in aerosol-iron solubility.« less

Influence of Atmospheric Processes on the Solubility and Composition of Iron in Saharan Dust.

PubMed

Longo, Amelia F; Feng, Yan; Lai, Barry; Landing, William M; Shelley, Rachel U; Nenes, Athanasios; Mihalopoulos, Nikolaos; Violaki, Kalliopi; Ingall, Ellery D

2016-07-05

Aerosol iron was examined in Saharan dust plumes using a combination of iron near-edge X-ray absorption spectroscopy and wet-chemical techniques. Aerosol samples were collected at three sites located in the Mediterranean, the Atlantic, and Bermuda to characterize iron at different atmospheric transport lengths and time scales. Iron(III) oxides were a component of aerosols at all sampling sites and dominated the aerosol iron in Mediterranean samples. In Atlantic samples, iron(II and III) sulfate, iron(III) phosphate, and iron(II) silicates were also contributors to aerosol composition. With increased atmospheric transport time, iron(II) sulfates are found to become more abundant, aerosol iron oxidation state became more reduced, and aerosol acidity increased. Atmospheric processing including acidic reactions and photoreduction likely influence the form of iron minerals and oxidation state in Saharan dust aerosols and contribute to increases in aerosol-iron solubility.

The Iron Metallome in Eukaryotic Organisms

PubMed Central

Dlouhy, Adrienne C.; Outten, Caryn E.

2013-01-01

This chapter is focused on the iron metallome in eukaryotes at the cellular and subcellular level, including properties, utilization in metalloproteins, trafficking, storage, and regulation of these processes. Studies in the model eukaryote Saccharomyces cerevisiae and mammalian cells will be highlighted. The discussion of iron properties will center on the speciation and localization of intracellular iron as well as the cellular and molecular mechanisms for coping with both low iron bioavailability and iron toxicity. The section on iron metalloproteins will emphasize heme, iron-sulfur cluster, and non-heme iron centers, particularly their cellular roles and mechanisms of assembly. The section on iron uptake, trafficking, and storage will compare methods used by yeast and mammalian cells to import iron, how this iron is brought into various organelles, and types of iron storage proteins. Regulation of these processes will be compared between yeast and mammalian cells at the transcriptional, post-transcriptional, and post-translational levels. PMID:23595675

Metal regeneration of iron chelates in nitric oxide scrubbing

DOEpatents

Chang, Shih-Ger; Littlejohn, David; Shi, Yao

1997-08-19

The present invention relates to a process of using metal particles to reduce NO to NH.sub.3. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20.degree. and 90.degree. C. to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution.

Metal regeneration of iron chelates in nitric oxide scrubbing

DOEpatents

Chang, S.G.; Littlejohn, D.; Shi, Y.

1997-08-19

The present invention relates to a process of using metal particles to reduce NO to NH{sub 3}. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: (a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20 and 90 C to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution. 34 figs.

Nonuniformity of Temperatures in Microwave Steam Heating of Lobster Tail.

PubMed

Fleischman, Gregory J

2016-11-01

The biennial Conference for Food Protection provides a formal process for all interested parties to influence food safety guidance. At a recent conference, an issue was raised culminating in a formal request to the U.S. Food and Drug Administration to change its Food Code recommendation for safe cooking of seafood using microwave energy when steaming was also employed. The request was to treat microwave steam cooked seafood as a conventionally cooked raw animal product rather than a microwave cooked product, for which the safe cooking recommendation is more extensive owing to the complex temperature distributions in microwave heating. The request was motivated by a literature study that revealed a more uniform temperature distribution in microwave steam cooked whole lobster. In that study, single-point temperatures were recorded in various sections of the whole lobster, but only one temperature was recorded in the tail, although the large size of the tail could translate to multiple hot and cold points. The present study was conducted to examine lobster tail specifically, measuring temperatures at multiple points during microwave steam cooking. Large temperature differences, greater than 60°C at times, were found throughout the heating period. To compensate for such differences, the Food Code recommends a more extensive level of cooking when microwave energy, rather than conventional heat sources, is used. Therefore, a change in the Food Code regarding microwave steam heating cannot be recommended.

International water and steam quality standards on thermal power plants at all-volatile treatment

NASA Astrophysics Data System (ADS)

Petrova, T. I.; Orlov, K. A.; Dooley, R. B.

2016-12-01

One of the methods for the improvement of reliability and efficiency of the equipment at heat power plants is the decrease in the rate of corrosion of structural materials and sedimentation in water/steam circuit. These processes can be reduced to minimum by using the water with low impurity content and coolant treatment. For many years, water and steam quality standards were developed in various countries (United States, Germany, Japan, etc.) for specific types of equipment. The International Association for the Properties of Water and Steam (IAPWS), which brings together specialists from 21 countries, developed the water and steam quality standards for various types of power equipment based on theoretical studies and long-term operating experience of power equipment. Recently, various water-chemistry conditions are applied on heatpower equipment including conventional boilers and HRSGs with combined cycle power plants (Combined Cycle Power Plants (CCPP)). In paper, the maintenance conditions of water chemistry with ammonia or volatile amine dosing are described: reducing AVT(R), oxidizing AVT(O), and oxygen OT. Each of them is provided by the water and steam quality standards and recommendations are given on their maintenance under various operation conditions. It is noted that the quality control of heat carrier must be carried out with a particular care on the HPPs with combined cycle gas turbine units, where frequent starts and halts are performed.

Anatomical and physical changes in leaves during the production of tamales.

PubMed

Angeles, Guillermo; Lascurain, Maite; Davalos-Sotelo, Raymundo; Zarate-Morales, Reyna Paula; Ortega-Escalona, Fernando

2013-08-01

Tamale preparation has a long tradition in Mexico. To understand which material properties have been considered important for this purpose throughout the years, a study was conducted of the anatomical, chemical, and mechanical properties of the leaves of four plant species used in tamale preparation in Veracruz, Mexico: Calathea misantlensis, Canna indica, Musa paradisiaca, and Oreopanax capitatus. Four cooking treatments were considered: fresh (F), roasted (soasado, R), steamed (S), and roasted plus steamed (R/S). Chemical, anatomical, and mechanical analyses were conducted before and after each treatment. Leaf samples were tested for tensile strength at both parallel and perpendicular orientation relative to the fibers. Musa paradisiaca had the highest proportion of cellulose, while the remaining species shared similar lower proportions. Leaves were stronger and stiffer in the longitudinal direction of the fibers. Musa paradisiaca leaves had higher values of mechanical strength than the other species. The cooking process that most affected the mechanical properties was steaming. The chemical constituents of the leaves are closely correlated with their physical properties. The treatment that caused the greatest decrease in leaf physical integrity was steaming, while the combination of roasting and steaming showed similar results to those of steaming alone. No evident anatomical changes are produced by any of the treatments. This is one of the few studies comparing physical, chemical, and anatomical characteristics of leaves used for human consumption, before and after cooking.

An easy “SteamDrop” method for high quality plant chromosome preparation

PubMed Central

2014-01-01

Background The chromosome preparation is a crucial step for obtaining satisfactory results in molecular cytogenetic researches. The preparation of plant chromosomes for molecular cytogenetic purposes remains a challenge for some species. In contrast to human chromosome preparation, the processes occurring during plant chromosome preparation and causing chromosome spreading are still poorly understood. Results We studied the dynamics of plant chromosome spreading after dropping cell suspension on slides. We showed that steam stimulates cytoplasm hydrolysis and rapid chromosome spreading and that chromosomes stretch during this chromosome spreading. Based on these observations, we developed a novel method, named “SteamDrop”, for the preparation of well-spread mitotic and pachytene chromosomes and successfully used it for 28 plant species with large and small chromosomes. We applied cell suspensions in ethanol instead of the commonly used ethanol/acetic acid fixative. Mitotic and meiotic chromosomes prepared via “SteamDrop” were used in fluorescent in situ hybridization (FISH) experiments with repetitive and unique DNA probes. Long storage of cell suspensions in ethanol did not impair the quality of chromosome preparations. Conclusion The SteamDrop procedure provides a robust and routine method for high quality plant chromosome preparations. The method can be applied for metaphase as well as pachytene chromosome preparation in wide range of species. The chromosomes prepared by SteamDrop are well suitable for repetitive and unique DNA visualization. PMID:24602284

Assessment and control design for steam vent noise in an oil refinery.

PubMed

Monazzam, Mohammad Reza; Golmohammadi, Rostam; Nourollahi, Maryam; Momen Bellah Fard, Samaneh

2011-06-13

Noise is one of the most important harmful agents in work environment. Noise pollution in oil refinery industries is related to workers' health. This study aimed to determine the overall noise pollution of an oil refinery operation and its frequency analysis to determine the control plan for a vent noise in these industries. This experimental study performed in control unit of Tehran Oil Refinery in 2008. To determine the noise distributions, environmental noise measurements were carried out by lattice method according to basic information and technical process. The sound pressure level and frequency distribution was measured for each study sources subject separately was performed individually. According to the vent's specification, the measured steam noise characteristics reviewed and compared to the theoretical results of steam noise estimation. Eventually, a double expansion muffler was designed. Data analysis and graphical design were carried out using Excel software. The results of environmental noise measurements indicated that the level of sound pressure was above the national permitted level (85 dB (A)). The Mean level of sound pressure of the studied steam jet was 90.3 dB (L). The results of noise frequency analysis for the steam vents showed that the dominant frequency was 4000 Hz. To obtain 17 dB noise reductions, a double chamber aluminum muffler with 500 mm length and 200 mm diameter consisting pipe drilled was designed. The characteristics of steam vent noise were separated from other sources, a double expansion muffler was designed using a new method based on the level of steam noise, and principle sound frequency, a double expansion muffler was designed.

Potential ability of zeolite to generate high-temperature vapor using waste heat

NASA Astrophysics Data System (ADS)

Fukai, Jun; Wijayanta, Agung Tri

2018-02-01

In various material product industries, a large amount of high temperature steam as heat sources are produced from fossil fuel, then thermal energy retained by condensed water at lower than 100°C are wasted. Thermal energies retained by exhaust gases at lower than 200°C are also wasted. Effective utilization of waste heat is believed to be one of important issues to solve global problems of energy and environment. Zeolite/water adsorption systems are introduced to recover such low-temperature waste heats in this study. Firstly, an adsorption steam recovery system was developed to generate high temperature steam from unused hot waste heat. The system used a new principle that adsorption heat of zeolite/water contact was efficiently extracted. A bench-scaled system was constructed, demonstrating contentious generation of saturated steam nearly 150°C from hot water at 80°C. Energy conservation is expected by returning the generated steam to steam lines in the product processes. Secondly, it was demonstrated that superheated steam/vapor at higher than 200°C could be generated from those at nearly 120°C using a laboratory-scaled setup. The maximum temperature and the time variation of output temperature were successfully estimated using macroscopic heat balances. Lastly, the maximum temperatures were estimated whose saturate air at the relative humidity 20-80% were heated by the present system. Theoretically, air at higher than 200°C was generated from saturate air at higher than 70°C. Consequently, zeolite/water adsorption systems have potential ability to regenerate thermal energy of waste water and exhaust gases.

Influence of steam explosion pretreatment on the anaerobic digestion of vinegar residue.

PubMed

Feng, Jiayu; Zhang, Jiyu; Zhang, Jiafu; He, Yanfeng; Zhang, Ruihong; Liu, Guangqing; Chen, Chang

2016-07-01

Vinegar residue is the by-product in the vinegar production process. The large amount of vinegar residue has caused a serious environmental problem owing to its acidity and corrosiveness. Anaerobic digestion is an effective way to convert agricultural waste into bioenergy, and a previous study showed that vinegar residue could be treated by anaerobic digestion but still had room to improve digestion efficiency. In this study, steam explosion at pressure of 0.8, 1.2, and 1.5 MPa and residence time of 5, 10, 15, and 20 min were used to pretreat vinegar residue to improve methane production, respectively. Scanning electron microscopy and X-ray diffraction analyses were applied to validate structural changes of vinegar residue after steam explosion. Results showed that steam explosion pretreatment could destroy the structure of lignocellulose by removing the hemicellulose and lignin, and improve the methane yield effectively. Steam explosion-treated vinegar residue at 0.8 MPa for 5 min produced the highest methane yield of 153.58 mL gVS (-1), which was 27.65% (significant, α < 0.05) more than untreated vinegar residue (120.31 mL gVS (-1)). The analyses of pH, total ammonia-nitrogen, total alkalinity, and volatile fatty acids showed that steam explosion did not influence the stability of anaerobic digestion. This study suggested that steam explosion pretreatment on vinegar residue might be a promising approach and it is worth further study to improve the efficiency of vinegar residue waste utilisation. © The Author(s) 2016.

Investigation of optical and hydrodynamic processes initiated in biological tissues and liquids under the action of high-power pulses of 1.54 μm laser radiation

NASA Astrophysics Data System (ADS)

Belikov, Andrey V.; Fomicheva, Yana Yu.; Gagarskiy, Sergey V.; Sergeev, Andrey N.; Smirnov, Sergey N.; Zagorulko, Alexey M.

2018-04-01

The results of strobe-photographic study of steam-gas cavities formation in a bulk of saline as a result of high-power Yb,Er:Glass laser pulses impact are presented. The data on dynamics of laser pulse transmission through the laserproduced steam-gas cavity for different values of the distance h between the fiber end and the cuvette bottom (quartz plate) are presented. It was observed that the steam-gas cavity might be used for effective non-contact delivery of laser radiation to the submerged target: transmission value at maximum steam-gas cavity size reached 0.87 for h = 0.5 mm. The influence of steam-gas cavities parameters on ablation efficiency of eye lens destruction in vitro is also discussed. The ablation of cataract eye lens in liquid environment is more effective than in air. The efficiency of eye lens ablation decreases with the increase of h . The maximal values of ablation efficiency (2.14·10-3 mm3/pulse) were obtained in the case of underwater ablation at h = 0 mm.

Antioxidant changes during domestic food processing of the white shaft and green leaves of leek (Allium ampeloprasum var. porrum).

PubMed

Bernaert, Nathalie; De Loose, Marc; Van Bockstaele, Erik; Van Droogenbroeck, Bart

2014-04-01

Evaluating the effect of domestic cooking on the health benefits of vegetables has great practical importance. However, only a limited number of reports provide information on the effect of these treatments on the antioxidant capacity, polyphenol and S-alk(en)yl-L-cysteine sulfoxide (ACSO, e.g. isoalliin and methiin) content of the white shaft and green leaves of leek (Allium ampeloprasum var. porrum). In the present study, the antioxidant capacity of leek was highly influenced by cooking (blanching, boiling and steaming). Boiling had a negative effect on total phenolic content in the white shaft and green leaves. An obvious increase could be observed in the antioxidant capacity of the steamed green leaves, while steaming did not influence the polyphenolic content. Remarkably, blanching resulted in a slight increase in the ACSO content. Subjecting leek samples to a longer thermal treatment appeared to have a negative influence on the ACSO content in leek. Steaming was also responsible for a decrease in ACSOs. Methiin was less susceptible to heat treatment than isoalliin. In general, steaming appeared to be responsible for better retention of the bioactive compounds present in leek compared with boiling. © 2013 Society of Chemical Industry.

Oxygen transport membrane reactor based method and system for generating electric power

DOEpatents

Kelly, Sean M.; Chakravarti, Shrikar; Li, Juan

2017-02-07

A carbon capture enabled system and method for generating electric power and/or fuel from methane containing sources using oxygen transport membranes by first converting the methane containing feed gas into a high pressure synthesis gas. Then, in one configuration the synthesis gas is combusted in oxy-combustion mode in oxygen transport membranes based boiler reactor operating at a pressure at least twice that of ambient pressure and the heat generated heats steam in thermally coupled steam generation tubes within the boiler reactor; the steam is expanded in steam turbine to generate power; and the carbon dioxide rich effluent leaving the boiler reactor is processed to isolate carbon. In another configuration the synthesis gas is further treated in a gas conditioning system configured for carbon capture in a pre-combustion mode using water gas shift reactors and acid gas removal units to produce hydrogen or hydrogen-rich fuel gas that fuels an integrated gas turbine and steam turbine system to generate power. The disclosed method and system can also be adapted to integrate with coal gasification systems to produce power from both coal and methane containing sources with greater than 90% carbon isolation.

Improvement of Steam Turbine Operational Performance and Reliability with using Modern Information Technologies

NASA Astrophysics Data System (ADS)

Brezgin, V. I.; Brodov, Yu M.; Kultishev, A. Yu

2017-11-01

The report presents improvement methods review in the fields of the steam turbine units design and operation based on modern information technologies application. In accordance with the life cycle methodology support, a conceptual model of the information support system during life cycle main stages (LC) of steam turbine unit is suggested. A classifying system, which ensures the creation of sustainable information links between the engineer team (manufacture’s plant) and customer organizations (power plants), is proposed. Within report, the principle of parameterization expansion beyond the geometric constructions at the design and improvement process of steam turbine unit equipment is proposed, studied and justified. The report presents the steam turbine unit equipment design methodology based on the brand new oil-cooler design system that have been developed and implemented by authors. This design system combines the construction subsystem, which is characterized by extensive usage of family tables and templates, and computation subsystem, which includes a methodology for the thermal-hydraulic zone-by-zone oil coolers design calculations. The report presents data about the developed software for operational monitoring, assessment of equipment parameters features as well as its implementation on five power plants.

LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS

DOE Office of Scientific and Technical Information (OSTI.GOV)

G. L. Hawkes; J. E. O'Brien; M. G. McKellar

2011-11-01

Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expandsmore » the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.« less

[Cost management: the implementation of the activity-based costing method in sterile processing department].

PubMed

Jericó, Marli de Carvalho; Castilho, Valéria

2010-09-01

This exploratory case study was performed aiming at implementing the Activity-based Costing (ABC) method in a sterile processing department (SPD) of a major teaching hospital. Data collection was performed throughout 2006. Documentary research techniques and non participant closed observation were used. The ABC implementation allowed for learning the activity-based costing of both the chemical and physical disinfection cycle/load: (dollar 9.95) and (dollar 12.63), respectively; as well as the cost for sterilization by steam under pressure (autoclave) (dollar 31.37) and low temperature steam and gaseous formaldehyde sterilization (LTSF) (dollar 255.28). The information provided by the ABC method has optimized the overall understanding of the cost driver process and provided the foundation for assessing performance and improvement in the SPD processes.

Alcoa Pressure Calcination Process for Alumina

NASA Astrophysics Data System (ADS)

Sucech, S. W.; Misra, C.

A new alumina calcination process developed at Alcoa Laboratories is described. Alumina is calcined in two stages. In the first stage, alumina hydrate is heated indirectly to 500°C in a decomposer vessel. Released water is recovered as process steam at 110 psig pressure. Partial transformation of gibbsite to boehmite occurs under hydrothermal conditions of the decomposer. The product from the decomposer containing about 5% LOI is then calcined by direct heating to 850°C to obtain smelting grade alumina. The final product is highly attrition resistant, has a surface area of 50-80 m2/g and a LOI of less than 1%. Accounting for the recovered steam, the effective fuel consumption for the new calcination process is only 1.6 GJ/t A12O3.

Acidic processing of mineral dust iron by anthropogenic compounds over the north Pacific Ocean

NASA Astrophysics Data System (ADS)

Solmon, F.; Chuang, P. Y.; Meskhidze, N.; Chen, Y.

2009-01-01

Atmospheric processing of mineral aerosol by anthropogenic pollutants may be an important process by which insoluble iron can be transformed into soluble forms and become available to oceanic biota. Observations of the soluble iron fraction in atmospheric aerosol exhibit large variability, which is poorly represented in models. In this study, we implemented a dust iron dissolution scheme in a global chemistry transport model (GEOS-Chem). The model is applied over the North Pacific Ocean during April 2001, a period when concentrations of dust and pollution within the east Asia outflow were high. Simulated fields of many key chemical constituents compare reasonably well with available observations, although some discrepancies are identified and discussed. In our simulations, the production of soluble iron varies temporally and regionally depending on pollution-to-dust ratio, primarily due to strong buffering by calcite. Overall, we show that the chemical processing mechanism produces significant amounts of dissolved iron reaching and being deposited in remote regions of the Pacific basin, with some seasonal variability. Simulated enhancements in particulate soluble iron fraction range from 0.5% to 6%, which is consistent with the observations. According to our simulations, ˜30% to 70% of particulate soluble iron over the North Pacific Ocean basin can be attributed to atmospheric processing. On the basis of April 2001 monthly simulations, sensitivity tests suggest that doubling SO2 emissions can induce a significant increase (13% on average, up to 40% during specific events) in dissolved iron production and deposition to the remote Pacific. We roughly estimate that half of the primary productivity induced by iron deposition in a north Pacific high-nutrient low-chlorophyll region is due to soluble iron derived from anthropogenic chemical processing of Asian aerosol.

Techno-economical study of biogas production improved by steam explosion pretreatment.

PubMed

Shafiei, Marzieh; Kabir, Maryam M; Zilouei, Hamid; Sárvári Horváth, Ilona; Karimi, Keikhosro

2013-11-01

Economic feasibility of steam explosion pretreatment for improvement of biogas production from wheat straw and paper tube residuals was investigated. The process was simulated by Aspen plus ®, and the economical feasibility of five different plant capacities was studied by Aspen Process Economic Analyzer. Total project investment of a plant using paper tube residuals or wheat straw was 63.9 or 61.8 million Euros, respectively. The manufacturing cost of raw biogas for these two feedstocks was calculated to 0.36 or 0.48 €/m(3) of methane, respectively. Applying steam explosion pretreatment resulted in 13% higher total capital investment while significantly improved the economy of the biogas plant and decreased the manufacturing cost of methane by 36%. The sensitivity analysis showed that 5% improvement in the methane yield and 20% decrease in the raw material price resulted in 5.5% and 8% decrease in the manufacturing cost of methane, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

Relationship between microstructure and mechanical properties of Alloy 690 tubes for steam generators

NASA Astrophysics Data System (ADS)

Diano, P.; Muggeo, A.; Van Duysen, J. C.; Guttmann, M.

1989-12-01

Alloy 690 is used to replace Alloy 600 for the fabrication of tubes for steam generators of french pressurized water nuclear reactors. In order to reduce the dispersion in tensile properties observed for the first Alloy 690 industrial tubes, and which had already been noticed for Alloy 600, a joint research programme has been carried out by Electricité de France (Département Etude des Matériaux) and Valinox Montbard. The dispersion in the tensile properties of the first industrial Alloy 690 tubes for PWR steam generators arises from two main factors: - a grain size dispersion which is in particular controlled by the carbon content and by the final heat treatment, - differences in the degree of strain hardening induced by the straightening process with rollers. An improvement of the fabrication processes which have an influence on these two factors has allowed to reduce considerably the dispersion of the tensile properties of the more recent series of tubes.

Pilot-scale study on the acid-catalyzed steam explosion of rice straw using a continuous pretreatment system.

PubMed

Chen, Wen-Hua; Tsai, Chia-Chin; Lin, Chih-Feng; Tsai, Pei-Yuan; Hwang, Wen-Song

2013-01-01

A continuous acid-catalyzed steam explosion pretreatment process and system to produce cellulosic ethanol was developed at the pilot-scale. The effects of the following parameters on the pretreatment efficiency of rice straw feedstocks were investigated: the acid concentration, the reaction temperature, the residence time, the feedstock size, the explosion pressure and the screw speed. The optimal presteaming horizontal reactor conditions for the pretreatment process are as follows: 1.7 rpm and 100-110 °C with an acid concentration of 1.3% (w/w). An acid-catalyzed steam explosion is then performed in the vertical reactor at 185 °C for 2 min. Approximately 73% of the total saccharification yield was obtained after the rice straw was pretreated under optimal conditions and subsequent enzymatic hydrolysis at a combined severity factor of 0.4-0.7. Moreover, good long-term stability and durability of the pretreatment system under continuous operation was observed. Copyright © 2012 Elsevier Ltd. All rights reserved.

Pulsed laser ablation of IC packages for device failure analyses

NASA Astrophysics Data System (ADS)

Hong, Ming Hui; Mai, ZhiHong; Chen, G. X.; Thiam, Thomas; Song, Wen D.; Lu, Yongfeng; Soh, Chye E.; Chong, Tow Chong

2002-06-01

Pulsed laser ablation of mold compounds for IC packaging in air and with steam assistance is investigated. It is applied to decap IC packages and expose computer CPU dies for the device failure analyses. Compared with chemical decapping, the laser ablation has advantages of being fast speed, non- contact and dry processing. Laser ablation with the steam assistance results in higher ablation rate and wider ablated crater with much smoother surface morphology. It implies that the steam assisted laser ablation can achieve a faster and better quality laser processing. Audible acoustic wave and plasma optical signal diagnostics are also carried out to have a better understanding of the mechanisms behind. Light wavelength and laser fluence applied in the decapping are two important parameters. The 532 nm Nd:YAG laser decapping at a low laser fluence can achieve a large decapping area with a fine ablation profile. IC packages decapped by the laser ablation show good quality for the device failure analyses.

Enzymatic saccharification and bioethanol production from Cynara cardunculus pretreated by steam explosion.

PubMed

Fernandes, Maria C; Ferro, Miguel D; Paulino, Ana F C; Mendes, Joana A S; Gravitis, Janis; Evtuguin, Dmitry V; Xavier, Ana M R B

2015-06-01

The correct choice of the specific lignocellulosic biomass pretreatment allows obtaining high biomass conversions for biorefinery implementations and cellulosic bioethanol production from renewable resources. Cynara cardunculus (cardoon) pretreated by steam explosion (SE) was involved in second-generation bioethanol production using separate hydrolysis and fermentation (SHF) or simultaneous saccharification and fermentation (SSF) processes. Steam explosion pretreatment led to partial solubilisation of hemicelluloses and increased the accessibility of residual polysaccharides towards enzymatic hydrolysis revealing 64% of sugars yield against 11% from untreated plant material. Alkaline extraction after SE pretreatment of cardoon (CSEOH) promoted partial removal of degraded lignin, tannins, extractives and hemicelluloses thus allowing to double glucose concentration upon saccharification step. Bioethanol fermentation in SSF mode was faster than SHF process providing the best results: ethanol concentration 18.7 g L(-1), fermentation efficiency of 66.6% and a yield of 26.6g ethanol/100 g CSEOH or 10.1 g ethanol/100 g untreated cardoon. Copyright © 2015 Elsevier Ltd. All rights reserved.

Impact of thermal processing on sulforaphane yield from broccoli ( Brassica oleracea L. ssp. italica).

PubMed

Wang, Grace C; Farnham, Mark; Jeffery, Elizabeth H

2012-07-11

In broccoli, sulforaphane forms when the glucosinolate glucoraphanin is hydrolyzed by the endogenous plant thiohydrolase myrosinase. A myrosinase cofactor directs hydrolysis away from the formation of bioactive sulforaphane and toward an inactive product, sulforaphane nitrile. The cofactor is more heat sensitive than myrosinase, presenting an opportunity to preferentially direct hydrolysis toward sulforaphane formation through regulation of thermal processing. Four broccoli cultivars were microwave heated, boiled, or steamed for various lengths of time. Production of nitrile during hydrolysis of unheated broccoli varied among cultivars from 91 to 52% of hydrolysis products (Pinnacle > Marathon > Patriot > Brigadier). Boiling and microwave heating caused an initial loss of nitrile, with a concomitant increase in sulforaphane, followed by loss of sulforaphane, all within 1 min. In contrast, steaming enhanced sulforaphane yield between 1.0 and 3.0 min in all but Brigadier. These data are proof of concept that steaming for 1.0-3.0 min provides less nitrile and more sulforaphane yield from a broccoli meal.

Post-treatment mechanical refining as a method to improve overall sugar recovery of steam pretreated hybrid poplar.

PubMed

Dou, Chang; Ewanick, Shannon; Bura, Renata; Gustafson, Rick

2016-05-01

This study investigates the effect of mechanical refining to improve the sugar yield from biomass processed under a wide range of steam pretreatment conditions. Hybrid poplar chips were steam pretreated using six different conditions with or without SO2. The resulting water insoluble fractions were subjected to mechanical refining. After refining, poplar pretreated at 205°C for 10min without SO2 obtained a 32% improvement in enzymatic hydrolysis and achieved similar overall monomeric sugar recovery (539kg/tonne) to samples pretreated with SO2. Refining did not improve hydrolyzability of samples pretreated at more severe conditions, nor did it improve the overall sugar recovery. By maximizing overall sugar recovery, refining could partially decouple the pretreatment from other unit operations, and enable the use of low temperature, non-sulfur pretreatment conditions. The study demonstrates the possibility of using post-treatment refining to accommodate potential pretreatment process upsets without sacrificing sugar yields. Copyright © 2016 Elsevier Ltd. All rights reserved.

Sorption enhanced reaction process (SERP) for the production of hydrogen

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hufton, J.; Mayorga, S.; Gaffney, T.

1998-08-01

The novel Sorption Enhanced Reaction Process has the potential to decrease the cost of hydrogen production by steam methane reforming. Current effort for development of this technology has focused on adsorbent development, experimental process concept testing, and process development and design. A preferred CO{sub 2} adsorbent, K{sub 2}CO{sub 3} promoted hydrotalcite, satisfies all of the performance targets and it has been scaled up for process testing. A separate class of adsorbents has been identified which could potentially improve the performance of the H{sub 2}-SER process. Although this material exhibits improved CO{sub 2} adsorption capacity compared to the HTC adsorbent, itsmore » hydrothermal stability must be improved. Single-step process experiments (not cyclic) indicate that the H{sub 2}-SER reactor performance during the reaction step improves with decreasing pressure and increasing temperature and steam to methane ratio in the feed. Methane conversion in the H{sub 2}-SER reactor is higher than for a conventional catalyst-only reactor operated at similar temperature and pressure. The reactor effluent gas consists of 90+% H{sub 2}, balance CH{sub 4}, with only trace levels (< 50 ppm) of carbon oxides. A best-case process design (2.5 MMSCFD of 99.9+% H{sub 2}) based on the HTC adsorbent properties and a revised SER process cycle has been generated. Economic analysis of this design indicates the process has the potential to reduce the H{sub 2} product cost by 25--31% compared to conventional steam methane reforming.« less

Applications of thermal energy storage to process heat and waste heat recovery in the iron and steel industry

NASA Technical Reports Server (NTRS)

Katter, L. B.; Peterson, D. J.

1978-01-01

The system identified operates from the primary arc furnace evacuation system as a heat source. Energy from the fume stream is stored as sensible energy in a solid medium (packed bed). A steam-driven turbine is arranged to generate power for peak shaving. A parametric design approach is presented since the overall system design, at optimum payback is strongly dependent upon the nature of the electric pricing structure. The scope of the project was limited to consideration of available technology so that industry-wide application could be achieved by 1985. A search of the literature, coupled with interviews with representatives of major steel producers, served as the means whereby the techniques and technologies indicated for the specific site are extrapolated to the industry as a whole and to the 1985 time frame. The conclusion of the study is that by 1985, a national yearly savings of 1.9 million barrels of oil could be realized through recovery of waste heat from primary arc furnace fume gases on an industry-wide basis. Economic studies indicate that the proposed system has a plant payback time of approximately 5 years.

Use of grape stalk, a waste of the viticulture industry, to obtain activated carbon.

PubMed

Deiana, A C; Sardella, M F; Silva, H; Amaya, A; Tancredi, N

2009-12-15

Grape stalk is an organic waste produced in great amounts in the industrialization processes of grape. This work presents the results of studies carried out to use this waste as raw material to prepare activated carbon through the physical and chemical route. The physicochemical characterization of this material suggests the presence of unusually high levels of ashes. Metal content was determined and high levels of potassium, sodium, iron, calcium and magnesium in carbonized and raw grape stalk were exhibited. This characteristic made difficult physical activation at high temperatures. A leaching step was included before the activation with steam, and adsorbents with surface areas between 700 and 900 m(2)/g were obtained. Physical activation was also performed at lower temperatures using carbonized grape stalk without leaching, leading to the development of some grade of porosity, with an area of 412 m(2)/g. These results would indicate the catalytic effect of the minerals present in this raw material. Chemical activation using phosphoric acid as activating agent seemed to be a very efficient method as final products with BET areas between 1000 and 1500 m(2)/g were obtained.

Hydrogen production from coal using a nuclear heat source

NASA Technical Reports Server (NTRS)

Quade, R. N.

1976-01-01

A strong candidate for hydrogen production in the intermediate time frame of 1985 to 1995 is a coal-based process using a high-temperature gas-cooled reactor (HTGR) as a heat source. Expected process efficiencies in the range of 60 to 70% are considerably higher than all other hydrogen production processes except steam reforming of a natural gas. The process involves the preparation of a coal liquid, hydrogasification of that liquid, and steam reforming of the resulting gaseous or light liquid product. A study showing process efficiency and cost of hydrogen vs nuclear reactor core outlet temperature has been completed, and shows diminishing returns at process temperatures above about 1500 F. A possible scenario combining the relatively abundant and low-cost Western coal deposits with the Gulf Coast hydrogen users is presented which provides high-energy density transportation utilizing coal liquids and uranium.

Testing theories of irony processing using eye-tracking and ERPs.

PubMed

Filik, Ruth; Leuthold, Hartmut; Wallington, Katie; Page, Jemma

2014-05-01

Not much is known about how people comprehend ironic utterances, and to date, most studies have simply compared processing of ironic versus non-ironic statements. A key aspect of the graded salience hypothesis, distinguishing it from other accounts (such as the standard pragmatic view and direct access view), is that it predicts differences between processing of familiar and unfamiliar ironies. Specifically, if an ironic utterance is familiar, then the ironic interpretation should be available without the need for extra inferential processes, whereas for unfamiliar ironies, the literal interpretation would be computed first, and a mismatch with context would lead to a re-interpretation of the statement as being ironic. We recorded participants' eye movements while they were reading (Experiment 1), and electrical brain activity while they were listening to (Experiment 2), familiar and unfamiliar ironies compared to non-ironic controls. Results show disruption to eye movements and an N400-like effect for unfamiliar ironies only, supporting the predictions of the graded salience hypothesis. In addition, in Experiment 2, a late positivity was found for both familiar and unfamiliar ironic materials, compared to non-ironic controls. We interpret this positivity as reflecting ongoing conflict between the literal and ironic interpretations of the utterance. PsycINFO Database Record (c) 2014 APA, all rights reserved.

Apparatus and methods for supplying auxiliary steam in a combined cycle system

DOEpatents

Gorman, William G.; Carberg, William George; Jones, Charles Michael

2002-01-01

To provide auxiliary steam, a low pressure valve is opened in a combined cycle system to divert low pressure steam from the heat recovery steam generator to a header for supplying steam to a second combined cycle's steam turbine seals, sparging devices and cooling steam for the steam turbine if the steam turbine and gas turbine lie on a common shaft with the generator. Cooling steam is supplied the gas turbine in the combined cycle system from the high pressure steam turbine. Spent gas turbine cooling steam may augment the low pressure steam supplied to the header by opening a high pressure valve whereby high and low pressure steam flows are combined. An attemperator is used to reduce the temperature of the combined steam in response to auxiliary steam flows above a predetermined flow and a steam header temperature above a predetermined temperature. The auxiliary steam may be used to start additional combined cycle units or to provide a host unit with steam turbine cooling and sealing steam during full-speed no-load operation after a load rejection.

The influence of manufacturing processes on the microstructure, grain boundary characteristics and SCC behavior of Alloy 690 steam generator tubing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sarver, J.M.; Doherty, P.E.; Doyle, D.M.

1995-12-31

Thermally treated Alloy 690 is the tubing material of choice for replacement steam generators in the United States. Throughout the world, it is manufactured using different melting and thermomechanical processing methods. The influence of different processing steps on the intergranular stress corrosion cracking (IGSCC) behavior of Alloy 690 has not been thoroughly evaluated. Evaluations were performed on Alloy 690 steam generator tubing produced using several different melting practices and thermomechanical processing procedures. The evaluations included extensive microstructural examinations as well as constant extension rate (CERT) tests. The CERT test results indicated that the thermally treated Alloy 690 tubing which wasmore » subjected to higher annealing temperatures displayed the highest degree of resistance to stress corrosion cracking (SCC). Examination of the microstructures indicated that the microstructural changes which are produced by increased annealing temperatures are subtle. In an attempt to further elucidate and quantify the effect of manufacturing processes on corrosion behavior, grain boundary character distribution (GBCD) measurements were performed on the same materials which were CERT tested. Analysis of GBCDs of the samples used in this study indicate that Alloy 690 exhibits a significantly larger fraction of special boundaries as compared to Alloy 600 and Alloy 800, regardless of the processing history of the tubing. Preliminary results indicate that a correlation may exist between processing method, GBCD`s and degree of IGSCC exhibited by the thermally treated samples examined in this study.« less

Hydrogen rich gas generator

NASA Technical Reports Server (NTRS)

Houseman, J. (Inventor)

1976-01-01

A process and apparatus is described for producing a hydrogen rich gas by introducing a liquid hydrocarbon fuel in the form of a spray into a partial oxidation region and mixing with a mixture of steam and air that is preheated by indirect heat exchange with the formed hydrogen rich gas, igniting the hydrocarbon fuel spray mixed with the preheated mixture of steam and air within the partial oxidation region to form a hydrogen rich gas.

Method for producing ethanol and co-products from cellulosic biomass

DOEpatents

Nguyen, Quang A

2013-10-01

The present invention generally relates to processes for production of ethanol from cellulosic biomass. The present invention also relates to production of various co-products of preparation of ethanol from cellulosic biomass. The present invention further relates to improvements in one or more aspects of preparation of ethanol from cellulosic biomass including, for example, improved methods for cleaning biomass feedstocks, improved acid impregnation, and improved steam treatment, or "steam explosion."

Process And Apparatus To Accomplish Autothermal Or Steam Reforming Via A Reciprocating Compression Device

DOEpatents

Lyons, K. David; James, Robert; Berry, David A.; Gardner, Todd

2004-09-21

The invention provides a method and apparatus for producing a synthesis gas from a variety of hydrocarbons. The apparatus (device) consists of a semi-batch, non-constant volume reactor to generate a synthesis gas. While the apparatus feeds mixtures of air, steam, and hydrocarbons into a cylinder where work is performed on the fluid by a piston to adiabatically raise its temperature without heat transfer from an external source.

Changes provoked by boiling, steaming and sous-vide cooking in the lipid and volatile profile of European sea bass.

PubMed

Nieva-Echevarría, Bárbara; Manzanos, María J; Goicoechea, Encarnación; Guillén, María D

2017-09-01

This study aims to shed light on the changes provoked by boiling, steaming and sous-vide cooking on the lipids and volatile profile of farmed and wild European sea bass meat. None of the cooking techniques provoked changes due to hydrolytic or oxidation processes detectable by 1 H NMR on sea bass lipids. The lipid profile of main and minor lipidic components was maintained after cooking. However, study by SPME-GC/MS evidenced that steaming and sous-vide cooking modified the volatile profile of sea bass meat, especially in farmed specimens. The compounds generated came from the occurrence, to a very small extent, of lipid and protein degradation. By contrast, boiling scarcely modified the initial characteristics of raw sea bass. Thus, from a sensory point of view and considering the odour-active compounds generated, steaming and sous-vide cooking provoked more noticeable changes than boiling, especially in farmed sea bass meat. Copyright © 2017. Published by Elsevier Ltd.

The Influence of Fabrication Process on the Initial Stages of Steam Oxidation Performed on Haynes® 282® Alloy at 760 °C

NASA Astrophysics Data System (ADS)

Dudziak, T.; Boron, L.; Homa, M.; Nowak, R.; Horton, N.; Sheppard, R.; Purgert, R. M.; Siewiorek, A.; Sobczak, N.; Sobczak, J. J.

2017-01-01

This work presents results observed after the first 5 h of oxidation of Haynes® 282® alloy. The steam oxidation tests have been carried out in pure water at 760 °C for 1, 2 and 5 h, respectively, using an accurate thermogravimetric balance technique. The alloy used for comparison in this work was fabricated using three different methods. The initial steam oxidation performance of the commercially wrought alloy Haynes® 282® was compared with a fabricated cast alloy and a HIP/PM alloy. The results show that in terms of corrosion resistance, fabrication techniques appear to have little impact on steam oxidation performance and behavior. The exposed Ni-based alloys all developed the oxide scales consisting mainly of Cr2O3 phase mixed with some TiO2, while internal Al and Ti precipitations along the grain boundaries were observed both in Haynes® 282® wrought and HIP/PM alloy.

Functionality of ovalbumin during Chinese steamed bread-making processing.

PubMed

Sang, Shangyuan; Zhang, Huang; Xu, Lei; Chen, Yisheng; Xu, Xueming; Jin, Zhengyu; Yang, Na; Wu, Fengfeng; Li, Dandan

2018-07-01

Hen egg is commonly used in some cereal-based food, including cakes and bread. Ovalbumin, one of the major components of egg white protein, can affect the performance of the food product. The interaction between ovalbumin and gluten protein and its effect on property of dough and quality of Chinese steamed bread was investigated in this study. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) patterns indicated that ovalbumin was surprisingly not incorporated in glutenins by covalent bond, whereas size-exclusion high-performance liquid chromatography showed that glutenin macropolymer content in glutenins increased slightly. Furthermore, dynamic rheology experiments indicated ovalbumin led to a decrease inG' andG″ of dough. Based on molecular dynamic simulation and SDS-PAGE results, it was inferred that ovalbumin was not hydrolyzed by endopeptidases during dough fermentation and crosslinked to gluten proteins during steaming. Finally, ovalbumin improved maximum dough height (Hm) during dough development and specific volume of Chinese steamed bread. Copyright © 2018 Elsevier Ltd. All rights reserved.

Current techniques in acid-chloride corrosion control and monitoring at The Geysers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hirtz, Paul; Buck, Cliff; Kunzman, Russell

1991-01-01

Acid chloride corrosion of geothermal well casings, production piping and power plant equipment has resulted in costly corrosion damage, frequent curtailments of power plants and the permanent shut-in of wells in certain areas of The Geysers. Techniques have been developed to mitigate these corrosion problems, allowing continued production of steam from high chloride wells with minimal impact on production and power generation facilities.The optimization of water and caustic steam scrubbing, steam/liquid separation and process fluid chemistry has led to effective and reliable corrosion mitigation systems currently in routine use at The Geysers. When properly operated, these systems can yield steammore » purities equal to or greater than those encountered in areas of The Geysers where chloride corrosion is not a problem. Developments in corrosion monitoring techniques, steam sampling and analytical methodologies for trace impurities, and computer modeling of the fluid chemistry has been instrumental in the success of this technology.« less

Ammonia synthesis. Ammonia synthesis by N₂ and steam electrolysis in molten hydroxide suspensions of nanoscale Fe₂O₃.

PubMed

Licht, Stuart; Cui, Baochen; Wang, Baohui; Li, Fang-Fang; Lau, Jason; Liu, Shuzhi

2014-08-08

The Haber-Bosch process to produce ammonia for fertilizer currently relies on carbon-intensive steam reforming of methane as a hydrogen source. We present an electrochemical pathway in which ammonia is produced by electrolysis of air and steam in a molten hydroxide suspension of nano-Fe2O3. At 200°C in an electrolyte with a molar ratio of 0.5 NaOH/0.5 KOH, ammonia is produced at 1.2 volts (V) under 2 milliamperes per centimeter squared (mA cm(-2)) of applied current at coulombic efficiency of 35% (35% of the applied current results in the six-electron conversion of N2 and water to ammonia, and excess H2 is cogenerated with the ammonia). At 250°C and 25 bar of steam pressure, the electrolysis voltage necessary for 2 mA cm(-2) current density decreased to 1.0 V. Copyright © 2014, American Association for the Advancement of Science.

Formation of inclusion complexes between high amylose starch and octadecyl ferulate via steam jet cooking.

PubMed

Kenar, James A; Compton, David L; Little, Jeanette A; Peterson, Steve C

2016-04-20

Amylose-ligand inclusion complexes represent an interesting approach to deliver bioactive molecules. However, ferulic acid has been shown not to form single helical inclusion complexes with amylose from high amylose maize starch. To overcome this problem a lipophilic ferulic acid ester, octadecyl ferulate, was prepared and complexed with amylose via excess steam jet cooking. Jet-cooking octadecyl ferulate and high amylose starch gave an amylose-octadecyl ferulate inclusion complex in 51.0% isolated yield. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) confirmed that a 61 V-type inclusion complex was formed. Amylose and extraction assays showed the complex to be enriched in amylose (91.9±4.3%) and contain 70.6±5.6mgg(-1) octadecyl ferulate, although, minor hydrolysis (∼4%) of the octadecyl ferulate was observed under the excess steam jet-cooking conditions utilized. This study demonstrates that steam jet cooking is a rapid and scalable process in which to prepare amylose-octadecyl ferulate inclusion complexes. Published by Elsevier Ltd.

High temperature oxidation in boiler environment of chromized steel

NASA Astrophysics Data System (ADS)

Alia, F. F.; Kurniawan, T.; Asmara, Y. P.; Ani, M. H. B.; Nandiyanto, A. B. D.

2017-10-01

The demand for increasing efficiency has led to the development and construction of higher operating temperature power plant. This condition may lead to more severe thickness losses in boiler tubes due to excessive corrosion process. Hence, the research to improve the corrosion resistance of the current operated material is needed so that it can be applied for higher temperature application. In this research, the effect of chromizing process on the oxidation behaviour of T91 steel was investigated under steam condition. In order to deposit chromium, mixture of chromium (Cr) powder as master alloy, halide salt (NH4Cl) powder as activator and alumina (Al2O3) powder as inert filler were inserted into alumina retort together with the steel sample and heated inside furnace at 1050°C for ten hours under argon gas environment. Furthermore, for the oxidation process, steels were exposed at 700°C at different oxidation time (6h-24h) under steam condition. From FESEM/EDX analysis, it was found that oxidation rate of pack cemented steel was lower than the un-packed steel. These results show that Cr from chromizing process was able to become reservoir for the formation of Cr2O3 in high temperature steam oxidation, and its existence can be used for a longer oxidation time.