Large-Scale Total Water Storage and Water Flux Changes over the Arid and Semiarid Parts of the Middle East from GRACE and Reanalysis Products

NASA Astrophysics Data System (ADS)

Forootan, E.; Safari, A.; Mostafaie, A.; Schumacher, M.; Delavar, M.; Awange, J. L.

2017-05-01

Previous studies indicate that water storage over a large part of the Middle East has been decreased over the last decade. Variability in the total (hydrological) water flux (TWF, i.e., precipitation minus evapotranspiration minus runoff) and water storage changes of the Tigris-Euphrates river basin and Iran's six major basins (Khazar, Persian, Urmia, Markazi, Hamun, and Sarakhs) over 2003-2013 is assessed in this study. Our investigation is performed based on the TWF that are estimated as temporal derivatives of terrestrial water storage (TWS) changes from the Gravity Recovery and Climate Experiment (GRACE) products and those from the reanalysis products of ERA-Interim and MERRA-Land. An inversion approach is applied to consistently estimate the spatio-temporal changes of soil moisture and groundwater storage compartments of the seven basins during the study period from GRACE TWS, altimetry, and land surface model products. The influence of TWF trends on separated water storage compartments is then explored. Our results, estimated as basin averages, indicate negative trends in the maximums of TWF peaks that reach up to -5.2 and -2.6 (mm/month/year) over 2003-2013, respectively, for the Urmia and Tigris-Euphrates basins, which are most likely due to the reported meteorological drought. Maximum amplitudes of the soil moisture compartment exhibit negative trends of -11.1, -6.6, -6.1, -4.8, -4.7, -3.8, and -1.2 (mm/year) for Urmia, Tigris-Euphrates, Khazar, Persian, Markazi, Sarakhs, and Hamun basins, respectively. Strong groundwater storage decrease is found, respectively, within the Khazar -8.6 (mm/year) and Sarakhs -7.0 (mm/year) basins. The magnitude of water storage decline in the Urmia and Tigris-Euphrates basins is found to be bigger than the decrease in the monthly accumulated TWF indicating a contribution of human water use, as well as surface and groundwater flow to the storage decline over the study area.

PLOT PLAN OF FUEL STORAGE BUILDING (CPP603) SHOWING STORAGE BASINS ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

PLOT PLAN OF FUEL STORAGE BUILDING (CPP-603) SHOWING STORAGE BASINS AND PROPOSED LOCATION OF FUEL ELEMENT CUTTING FACILITY. INL DRAWING NUMBER 200-0603-00-706-051287. ALTERNATE ID NUMBER CPP-C-1287. - Idaho National Engineering Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex, Scoville, Butte County, ID

46 CFR 45.111 - Strength of bulkheads at ends of superstructures.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 2 2011-10-01 2011-10-01 false Strength of bulkheads at ends of superstructures. 45.111... LOAD LINES Conditions of Assignment § 45.111 Strength of bulkheads at ends of superstructures. Bulkheads at ends of enclosed superstructures must have sufficient strength to withstand impact of boarding...

46 CFR 45.111 - Strength of bulkheads at ends of superstructures.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Strength of bulkheads at ends of superstructures. 45.111... LOAD LINES Conditions of Assignment § 45.111 Strength of bulkheads at ends of superstructures. Bulkheads at ends of enclosed superstructures must have sufficient strength to withstand impact of boarding...

Voids and superstructures: correlations and induced large-scale velocity flows

NASA Astrophysics Data System (ADS)

Lares, Marcelo; Luparello, Heliana E.; Maldonado, Victoria; Ruiz, Andrés N.; Paz, Dante J.; Ceccarelli, Laura; Garcia Lambas, Diego

2017-09-01

The expanding complex pattern of filaments, walls and voids build the evolving cosmic web with material flowing from underdense on to high density regions. Here, we explore the dynamical behaviour of voids and galaxies in void shells relative to neighbouring overdense superstructures, using the Millenium simulation and the main galaxy catalogue in Sloan Digital Sky Survey data. We define a correlation measure to estimate the tendency of voids to be located at a given distance from a superstructure. We find voids-in-clouds (S-types) preferentially located closer to superstructures than voids-in-voids (R-types) although we obtain that voids within ˜40 h-1 Mpc of superstructures are infalling in a similar fashion independently of void type. Galaxies residing in void shells show infall towards the closest superstructure, along with the void global motion, with a differential velocity component depending on their relative position in the shell with respect to the direction to the superstructure. This effect is produced by void expansion and therefore is stronger for R-types. We also find that galaxies in void shells facing the superstructure flow towards the overdensities faster than galaxies elsewhere at the same relative distance to the superstructure. The results obtained for the simulation are also reproduced for the Sky Survey Data Release data with a linearized velocity field implementation.

The MIL-88A-Derived Fe3O4-Carbon Hierarchical Nanocomposites for Electrochemical Sensing

PubMed Central

Wang, Li; Zhang, Yayun; Li, Xia; Xie, Yingzhen; He, Juan; Yu, Jie; Song, Yonghai

2015-01-01

Metal or metal oxides/carbon nanocomposites with hierarchical superstructures have become one of the most promising functional materials in sensor, catalysis, energy conversion, etc. In this work, novel hierarchical Fe3O4/carbon superstructures have been fabricated based on metal-organic frameworks (MOFs)-derived method. Three kinds of Fe-MOFs (MIL-88A) with different morphologies were prepared beforehand as templates, and then pyrolyzed to fabricate the corresponding novel hierarchical Fe3O4/carbon superstructures. The systematic studies on the thermal decomposition process of the three kinds of MIL-88A and the effect of template morphology on the products were carried out in detail. Scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy and thermal analysis were employed to investigate the hierarchical Fe3O4/carbon superstructures. Based on these resulted hierarchical Fe3O4/carbon superstructures, a novel and sensitive nonenzymatic N-acetyl cysteine sensor was developed. The porous and hierarchical superstructures and large surface area of the as-formed Fe3O4/carbon superstructures eventually contributed to the good electrocatalytic activity of the prepared sensor towards the oxidation of N-acetyl cysteine. The proposed preparation method of the hierarchical Fe3O4/carbon superstructures is simple, efficient, cheap and easy to mass production. It might open up a new way for hierarchical superstructures preparation. PMID:26387535

Water storage capacity of natural wetland depressions in the Devils Lake basin of North Dakota

USGS Publications Warehouse

Ludden, A.P.; Frink, D.L.; Johnson, D.H.

1983-01-01

Photogrammetric mapping techniques were used to derive the water storage capacities of natural wetland depressions other than lakes in the Devils Lake Basin of North Dakota. Results from sample quarter-section areas were expanded to the entire basin. Depressions in the Devils Lake Basin have a maximum storage capacity of nearly 811,000 cubic dekameters (657,000 acre-feet). The depressions store about 72 percent of the total runoff volume from a 2-year-frequency runoff and about 41 percent of the total runoff volume from a 100-year-frequency runoff.

Geohydrology of Storage Unit III and a combined flow model of the Santa Barbara and foothill ground-water basins, Santa Barbara County, California

USGS Publications Warehouse

Freckleton, John R.; Martin, Peter; Nishikawa, Tracy

1998-01-01

The city of Santa Barbara pumps most of its ground water from the Santa Barbara and Foothill ground-water basins. The Santa Barbara basin is subdivided into two storage units: Storage Unit I and Storage Unit III. The Foothill basin and Storage Unit I of the Santa Barbara basin have been studied extensively and ground-water flow models have been developed for them. In this report, the geohydrology of the Santa Barbara ground- water basin is described with a special emphasis on Storage Unit III in the southwestern part of the basin. The purposes of this study were to summarize and evaluate the geohydrology of Storage Unit III and to develop an areawide model of the Santa Barbara and Foothill basins that includes the previously unmodeled Storage Unit III. Storage Unit III is in the southwestern part of the city of Santa Barbara. It is approximately 3.5 miles long and varies in width from about 2,000 feet in the southeast to 4,000 feet in the north-west. Storage Unit III is composed of the Santa Barbara Formation and overlying alluvium. The Santa Barbara Formation (the principal aquifer) consists of Pleistocene and Pliocene(?) unconsolidated marine sand, silt, and clay, and it has a maximum saturated thickness of about 160 feet. The alluvium that overlies the Santa Barbara Formation has a maximum saturated thickness of about 140 feet. The storage unit is bounded areally by faults and low-permeability deposits and is underlain by rocks of Tertiary age. The main sources of recharge to Storage Unit III are seepage from Arroyo Burro and infiltration of precipitation. Most of the recharge occurs in the northwest part of the storage unit, and ground water flows toward the southeast along the unit's long axis. Lesser amounts of recharge may occur as subsurface flow from the Hope Ranch subbasin and as upwelling from the underlying Tertiary rocks. Discharge from Storage Unit III occurs as pumpage, flow to underground drains, underflow through alluvium in the vicinity of Arroyo Burro across the Lavigia Fault, evapotranspiration, and underflow to the Pacific Ocean. The faults that bound Storage Unit III generally are considered to be effective barriers to the flow of ground water. Interbasin ground-water flow occurs where deposits of younger alluvium along stream channels cross faults. Ground-water quality in Storage Unit III deposits varies with location and depth. Upward leakage of poor-quality water from the underlying Tertiary rocks occurs in the storage unit, and such leakage can be influenced by poor well construction or by heavy localized pumping. The highest dissolved-solids concentration (4,710 milligrams per liter) in ground water resulting from this upward leakage is found in the coastal part of the storage unit. The ground-water system was modeled as two horizontal layers. In the Foothill basin and Storage Unit I the layers are separated by a confining bed. The upper layer represents the upper producing zone and the shallow zone near the coast. The lower layer represents the lower producing zone. In general, the faults in the study area were assumed to be no-flow boundaries, except for the offshore fault that forms the southeast boundary; the southeast boundary was simulated as a general-head boundary. The Storage Unit III model was combined with the preexisting Storage Unit I and Foothill basin models, using horizontal flow barriers, to form an areawide model. The areawide model was calibrated by simulating steady-state predevelopment conditions and transient conditions for 1978-92. The nonpumping steady- state simulation was used to verify that the calibrated model yielded physically reasonable results for predevelopment conditions. The calibrated areawide model calculates water levels in Storage Unit III that are within 10 feet of measured water levels at all sites of comparison. In addition, the model adequately simulates water levels in the Storage Unit I and Foothill basin areas. A total of 33,430 acre-feet of water was pum

Geologic framework for the national assessment of carbon dioxide storage resources: Arkoma Basin, Kansas Basins, and Midcontinent Rift Basin study areas: Chapter F in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Buursink, Marc L.; Craddock, William H.; Blondes, Madalyn S.; Freeman, Phillip A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.

2013-01-01

2007 Energy Independence and Security Act (Public Law 110–140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO2). The methodology used by the USGS for the national CO2 assessment follows that of previous USGS work. This methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of three storage assessment units (SAUs) in Upper Cambrian to Mississippian sedimentary rocks within the Arkoma Basin study area, and two SAUs in Upper Cambrian to Mississippian sedimentary rocks within the Kansas Basins study area. The Arkoma Basin and Kansas Basins are adjacent with very similar geologic units; although the Kansas Basins area is larger, the Arkoma Basin is more structurally complex. The report focuses on the characteristics, specified in the methodology, that influence the potential CO2 storage resource in the SAUs. Specific descriptions of the SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are usually provided to illustrate geologic factors critical to the assessment. Although assessment results are not contained in this report, the geologic information herein was employed, as specified in the USGS methodology, to calculate a probabilistic distribution of potential storage resources in each SAU. The Midcontinent Rift Basin study area was not assessed, because no suitable storage formations meeting our size, depth, reservoir quality, and regional seal guidelines were found. Figures in this report show study area boundaries along with the SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one-square mile and are derived from interpretations of incompletely attributed well data and from a digital compilation that is known not to include all drilling. The USGS does not expect to know the location of all wells and cannot guarantee the amount of drilling through specific formations in any given cell shown on the cell maps.

Superstructures with diverse morphologies and highly ordered fullerene C60 arrays from 1 : 1 and 2 : 1 adamantane-C60 hybrid molecules.

PubMed

Zhou, Shengju; Wang, Lin; Chen, Mengjun; Liu, Baoyong; Sun, Xiaofeng; Cai, Meirong; Li, Hongguang

2017-11-02

Superstructures from fullerene C 60 -containing compounds, especially those tethered to rigid functional groups with defined shapes, remain largely unexplored. Being the smallest diamondoid, adamantane (Ad) can be viewed as a promising building block for the construction of well-defined superstructures. Here, we report the syntheses of 1 : 1 (4a) and 2 : 1 (4b) Ad-C 60 hybrid molecules, which were then used to construct superstructures in binary solvent mixtures via a modified liquid/liquid interfacial precipitation (LLIP) method using CHCl 3 as a good solvent. Typically in the combination of DMSO/CHCl 3 with a final concentration (c f ) of 1.0 mmol L -1 , 4a successively forms spheres, plates, nanoflowers and plicated particles with increasing content of DMSO while 4b forms cuboid blocks and microparticles with hierarchically organized surfaces. Changing from DMSO to other poor solvents including acetone, MeOH and EtOAc leads to variations of the morphology of the superstructures for both 4a and 4b. At the nanometer length scale, 4a and 4b adopt different organizations within the superstructures. While 4a tends to self-organize into lamellae with highly ordered C 60 layers, the hexagonal phase is dominant in the superstructures formed by 4b. Wettability tests indicate that films formed by the superstructures of 4a and 4b show anti-wetting properties. Besides the solvent effect, the morphology of the superstructures can be also tuned by concentration. For example, when c f is lowered to 0.5 mmol L -1 , a new form of superstructure, i.e., fibers, was detected for 4a. Our results also indicate that besides the solvent-induced aggregate transition, gravity-induced sedimentation and subsequent structure ripening can have a significant influence on the final morphology of the superstructures and the aggregate transition pathways.

Studying Basin Water Balance Variations at Inter- and Intra-annual Time Scales Based On the Budyko Hypothesis and GRACE Gravimetry Satellite Observations

NASA Astrophysics Data System (ADS)

Shen, H.

2017-12-01

Increasing intensity in global warming and anthropogenic activities has triggered significant changes over regional climates and landscapes, which, in turn, drive the basin water cycle and hydrological balance into a complex and unstable state. Budyko hypothesis is a powerful tool to characterize basin water balance and hydrological variations at long-term average scale. However, due to the absence of basin water storage change, applications of Budyko theory to the inter-annual and intra-annual time scales has been prohibited. The launch of GRACE gavimetry satellites provides a great opportunity to quantify terrestrial water storage change, which can be further introduced into the Budyko hypothesis to reveal the inter- and intra-annual response of basin water components under impacts of climate variability and/or human activities. This research targeted Hai River Basin (in China) and Murray-Darling Basin (in Australia), which have been identified with a continuous groundwater depletion trend as well as impacts by extreme climates in the past decade. This can help us to explore how annual or seasonal precipitation were redistributed to evapotranspiration and runoff via changing basin water storage. Moreover, the impacts of vegetation on annual basin water balance will be re-examined. Our results are expected to provide deep insights about the water cycle and hydrological behaviors for the targeted basins, as well as a proof for a consideration of basin water storage change into the Budyko model at inter- or intra-annual time steps.

Geologic framework for the national assessment of carbon dioxide storage resources: Permian and Palo Duro Basins and Bend Arch-Fort Worth Basin: Chapter K in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Merrill, Matthew D.; Slucher, Ernie R.; Roberts-Ashby, Tina L.; Warwick, Peter D.; Blondes, Madalyn S.; Freeman, P.A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2015-01-01

The U.S. Geological Survey has completed an assessment of the potential geologic carbon dioxide storage resource in the onshore areas of the United States. To provide geological context and input data sources for the resources numbers, framework documents are being prepared for all areas that were investigated as part of the national assessment. This report is the geologic framework document for the Permian and Palo Duro Basins, the combined Bend arch-Fort Worth Basin area, and subbasins therein of Texas, New Mexico, and Oklahoma. In addition to a summarization of the geology and petroleum resources of studied basins, the individual storage assessment units (SAUs) within the basins are described and explanations for their selection are presented. Though appendixes in the national assessment publications include the input values used to calculate the available storage resource, this framework document provides only the context and source of inputs selected by the assessment geologists. Spatial files of boundaries for the SAUs herein, as well as maps of the density of known well bores that penetrate the SAU seal, are available for download with the release of this report.

Ship Superstructure Icing: Crystalline And Physical Properties

DOT National Transportation Integrated Search

2000-08-01

Ice grows on ship superstructure components as a result of precipitation of saline spray from the ocean surface in winter seas. A potentially serious problem, superstructure icing reduces ship sea-keeping ability and hinders deck operations. In Febru...

Summary of Carbon Storage Incentives and Potential Legislation: East Sub-Basin Project Task 3.1 Business and Financial Case Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trabucchi, Chiara

The CarbonSAFE Illinois – East Sub-Basin project is conducting a pre-feasibility assessment for commercial-scale CO2 geological storage complexes. The project aims to identify sites capable of storing more than 50 million tons of industrially-sourced CO2. To support the business development assessment of the economic viability of potential sites in the East Sub-Basin and explore conditions under which a carbon capture and storage (CCS) project therein might be revenue positive, this document provides a summary of carbon storage incentives and legislation of potential relevance to the project.

Daily GRACE storage anomaly data for characterization of dynamic storage-discharge relationships of natural drainage basins

NASA Astrophysics Data System (ADS)

Sharma, D.; Patnaik, S.; Reager, J. T., II; Biswal, B.

2017-12-01

Despite the fact that streamflow occurs mainly due to depletion of storage, our knowledge on how a drainage basin stores and releases water is very limited because of measurement limitations. As a result storage has largely remained an elusive entity in hydrological analysis and modelling. A window of opportunity, however, is given to us by GRACE satellite mission that provides storage anomaly (TWSA) data for the entire globe. Many studies have used TWSA data for storage-discharge analysis, uncovering a range of potential applications of TWSA data. Here we argue that the capability of GRACE satellite mission has not been fully explored as most of the studies in the past have performed storage-discharge analysis using monthly TWSA data for large river basins. With such coarse data we are quite unlikely to fully understand variation of storage and discharge in space and time. In this study, we therefore use daily TWSA data for several mid-sized catchments and perform storage-discharge analysis. Daily storage-discharge relationship is highly dynamic, which generates large amount of scatter in storage-discharge plots. Yet a careful analysis of those scatter plots reveals interesting information on storage-discharge relationships of basins, particularly by looking at the relationships during individual recession events. It is observed that storage-discharge relationship is exponential in nature, contrary to the general assumption that the relationship is linear. We find that there is a strong relationship between power-law recession coefficient and initial storage (TWSA at the beginning of recession event). Furthermore, appreciable relationships are observed between recession coefficient and past TWSA values implying that storage takes time to deplete completely. Overall, insights drawn from this study expands our knowledge on how discharge is dynamically linked to storage.

Geologic framework for the national assessment of carbon dioxide storage resources─South Florida Basin: Chapter L in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Roberts-Ashby, Tina L.; Brennan, Sean T.; Merrill, Matthew D.; Blondes, Madalyn S.; Freeman, P.A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2015-08-26

This report presents five storage assessment units (SAUs) that have been identified as potentially suitable for geologic carbon dioxide sequestration within a 35,075-square-mile area that includes the entire onshore and State-water portions of the South Florida Basin. Platform-wide, thick successions of laterally extensive carbonates and evaporites deposited in highly cyclic depositional environments in the South Florida Basin provide several massive, porous carbonate reservoirs that are separated by evaporite seals. For each storage assessment unit identified within the basin, the areal distribution of the reservoir-seal couplet identified as suitable for geologic Carbon dioxide sequestration is presented, along with a description of the geologic characteristics that influence the potential carbon dioxide storage volume and reservoir performance. On a case-by-case basis, strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are also discussed. Geologic information presented in this report has been employed to calculate potential storage capacities for carbon dioxide sequestration in the storage assessment units assessed herein, although complete assessment results are not contained in this report.

Standard plans for timber bridge superstructures

Treesearch

James P. Wacker; Matthew S. Smith

2001-01-01

These standardized bridge plans are for superstructures consisting of treated timber. Seven superstructure types are includes: five longitudinal and two transverse deck systems. Both HS520 and HS25 loadings are included, along with L/360 and L/500 deflection criteria.

Integral ceramic superstructure evaluation using time domain optical coherence tomography

NASA Astrophysics Data System (ADS)

Sinescu, Cosmin; Bradu, Adrian; Topala, Florin I.; Negrutiu, Meda Lavinia; Duma, Virgil-Florin; Podoleanu, Adrian G.

2014-02-01

Optical Coherence Tomography (OCT) is a non-invasive low coherence interferometry technique that includes several technologies (and the corresponding devices and components), such as illumination and detection, interferometry, scanning, adaptive optics, microscopy and endoscopy. From its large area of applications, we consider in this paper a critical aspect in dentistry - to be investigated with a Time Domain (TD) OCT system. The clinical situation of an edentulous mandible is considered; it can be solved by inserting 2 to 6 implants. On these implants a mesostructure will be manufactured and on it a superstructure is needed. This superstructure can be integral ceramic; in this case materials defects could be trapped inside the ceramic layers and those defects could lead to fractures of the entire superstructure. In this paper we demonstrate that a TD-OCT imaging system has the potential to properly evaluate the presence of the defects inside the ceramic layers and those defects can be fixed before inserting the prosthesis inside the oral cavity. Three integral ceramic superstructures were developed by using a CAD/CAM technology. After the milling, the ceramic layers were applied on the core. All the three samples were evaluated by a TD-OCT system working at 1300 nm. For two of the superstructures evaluated, no defects were found in the most stressed areas. The third superstructure presented four ceramic defects in the mentioned areas. Because of those defects the superstructure may fracture. The integral ceramic prosthesis was send back to the dental laboratory to fix the problems related to the material defects found. Thus, TD-OCT proved to be a valuable method for diagnosing the ceramic defects inside the integral ceramic superstructures in order to prevent fractures at this level.

Joint Simultaneous Reconstruction of Regularized Building Superstructures from Low-Density LIDAR Data Using Icp

NASA Astrophysics Data System (ADS)

Wichmann, Andreas; Kada, Martin

2016-06-01

There are many applications for 3D city models, e.g., in visualizations, analysis, and simulations; each one requiring a certain level of detail to be effective. The overall trend goes towards including various kinds of anthropogenic and natural objects therein with ever increasing geometric and semantic details. A few years back, the featured 3D building models had only coarse roof geometry. But nowadays, they are expected to include detailed roof superstructures like dormers and chimneys. Several methods have been proposed for the automatic reconstruction of 3D building models from airborne based point clouds. However, they are usually unable to reliably recognize and reconstruct small roof superstructures as these objects are often represented by only few point measurements, especially in low-density point clouds. In this paper, we propose a recognition and reconstruction approach that overcomes this problem by identifying and simultaneously reconstructing regularized superstructures of similar shape. For this purpose, candidate areas for superstructures are detected by taking into account virtual sub-surface points that are assumed to lie on the main roof faces below the measured points. The areas with similar superstructures are detected, extracted, grouped together, and registered to one another with the Iterative Closest Point (ICP) algorithm. As an outcome, the joint point density of each detected group is increased, which helps to recognize the shape of the superstructure more reliably and in more detail. Finally, all instances of each group of superstructures are modeled at once and transformed back to their original position. Because superstructures are reconstructed in groups, symmetries, alignments, and regularities can be enforced in a straight-forward way. The validity of the approach is presented on a number of example buildings from the Vaihingen test data set.

Dry Storage of Research Reactor Spent Nuclear Fuel - 13321

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adams, T.M.; Dunsmuir, M.D.; Leduc, D.R.

2013-07-01

Spent fuel from domestic and foreign research reactors is received and stored at the Savannah River Site's L Area Material Storage (L Basin) Facility. This DOE-owned fuel consists primarily of highly enriched uranium in metal, oxide or silicide form with aluminum cladding. Upon receipt, the fuel is unloaded and transferred to basin storage awaiting final disposition. Disposition alternatives include processing via the site's H Canyon facility for uranium recovery, or packaging and shipment of the spent fuel to a waste repository. A program has been developed to provide a phased approach for dry storage of the L Basin fuel. Themore » initial phase of the dry storage program will demonstrate loading, drying, and storage of fuel in twelve instrumented canisters to assess fuel performance. After closure, the loaded canisters are transferred to pad-mounted concrete overpacks, similar to those used for dry storage of commercial fuel. Unlike commercial spent fuel, however, the DOE fuel has high enrichment, very low to high burnup, and low decay heat. The aluminum cladding presents unique challenges due to the presence of an oxide layer that forms on the cladding surface, and corrosion degradation resulting from prolonged wet storage. The removal of free and bound water is essential to the prevention of fuel corrosion and radiolytic generation of hydrogen. The demonstration will validate models predicting pressure, temperature, gas generation, and corrosion performance, provide an engineering scale demonstration of fuel handling, drying, leak testing, and canister backfill operations, and establish 'road-ready' storage of fuel that is suitable for offsite repository shipment or retrievable for onsite processing. Implementation of the Phase I demonstration can be completed within three years. Phases II and III, leading to the de-inventory of L Basin, would require an additional 750 canisters and 6-12 years to complete. Transfer of the fuel from basin storage to dry storage requires integration with current facility operations, and selection of equipment that will allow safe operation within the constraints of existing facility conditions. Examples of such constraints that are evaluated and addressed by the dry storage program include limited basin depth, varying fuel lengths up to 4 m, (13 ft), fissile loading limits, canister closure design, post-load drying and closure of the canisters, instrument selection and installation, and movement of the canisters to storage casks. The initial pilot phase restricts the fuels to shorter length fuels that can be loaded to the canister directly underwater; subsequent phases will require use of a shielded transfer system. Removal of the canister from the basin, followed by drying, inerting, closure of the canister, and transfer of the canister to the storage cask are completed with remotely operated equipment and appropriate shielding to reduce personnel radiation exposure. (authors)« less

11. BUOY DECK, NEAR PILOT HOUSE SUPERSTRUCTURE, LOOKING TOWARDS HATCH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. BUOY DECK, NEAR PILOT HOUSE SUPERSTRUCTURE, LOOKING TOWARDS HATCH DOOR INTO WINCH ROOM IN THE SUPERSTRUCTURE (LABELED AT PASSAGE & HYDRAULIC MACHINERY ON PLAN). - U.S. Coast Guard Cutter WHITE HEATH, USGS Integrated Support Command Boston, 427 Commercial Street, Boston, Suffolk County, MA

Control superstructure of rigid polyelectrolytes in oppositely charged hydrogels via programmed internal stress

NASA Astrophysics Data System (ADS)

Takahashi, Riku; Wu, Zi Liang; Arifuzzaman, Md; Nonoyama, Takayuki; Nakajima, Tasuku; Kurokawa, Takayuki; Gong, Jian Ping

2014-08-01

Biomacromolecules usually form complex superstructures in natural biotissues, such as different alignments of collagen fibres in articular cartilages, for multifunctionalities. Inspired by nature, there are efforts towards developing multiscale ordered structures in hydrogels (recognized as one of the best candidates of soft biotissues). However, creating complex superstructures in gels are hardly realized because of the absence of effective approaches to control the localized molecular orientation. Here we introduce a method to create various superstructures of rigid polyanions in polycationic hydrogels. The control of localized orientation of rigid molecules, which are sensitive to the internal stress field of the gel, is achieved by tuning the swelling mismatch between masked and unmasked regions of the photolithographic patterned gel. Furthermore, we develop a double network structure to toughen the hydrogels with programmed superstructures, which deform reversibly under large strain. This work presents a promising pathway to develop superstructures in hydrogels and should shed light on designing biomimetic materials with intricate molecular alignments.

Terrestrial Water Mass Load Changes from Gravity Recovery and Climate Experiment (GRACE)

NASA Technical Reports Server (NTRS)

Seo, K.-W.; Wilson, C. R.; Famiglietti, J. S.; Chen, J. L.; Rodell M.

2006-01-01

Recent studies show that data from the Gravity Recovery and Climate Experiment (GRACE) is promising for basin- to global-scale water cycle research. This study provides varied assessments of errors associated with GRACE water storage estimates. Thirteen monthly GRACE gravity solutions from August 2002 to December 2004 are examined, along with synthesized GRACE gravity fields for the same period that incorporate simulated errors. The synthetic GRACE fields are calculated using numerical climate models and GRACE internal error estimates. We consider the influence of measurement noise, spatial leakage error, and atmospheric and ocean dealiasing (AOD) model error as the major contributors to the error budget. Leakage error arises from the limited range of GRACE spherical harmonics not corrupted by noise. AOD model error is due to imperfect correction for atmosphere and ocean mass redistribution applied during GRACE processing. Four methods of forming water storage estimates from GRACE spherical harmonics (four different basin filters) are applied to both GRACE and synthetic data. Two basin filters use Gaussian smoothing, and the other two are dynamic basin filters which use knowledge of geographical locations where water storage variations are expected. Global maps of measurement noise, leakage error, and AOD model errors are estimated for each basin filter. Dynamic basin filters yield the smallest errors and highest signal-to-noise ratio. Within 12 selected basins, GRACE and synthetic data show similar amplitudes of water storage change. Using 53 river basins, covering most of Earth's land surface excluding Antarctica and Greenland, we document how error changes with basin size, latitude, and shape. Leakage error is most affected by basin size and latitude, and AOD model error is most dependent on basin latitude.

46 CFR 108.133 - Hull superstructure, structural bulkheads, decks, and deckhouses.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Hull superstructure, structural bulkheads, decks, and deckhouses. 108.133 Section 108.133 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A... Protection § 108.133 Hull superstructure, structural bulkheads, decks, and deckhouses. Each hull...

77 FR 16172 - Application for Foreign Rebuilding Determination

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-20

... determinations and directs when vessels with coastwise trade endorsements whose hulls or superstructure are.... This company noted that the existing discretionary rebuild test of 7.5 to 10 percent of hull or... components of the hull or superstructure of a vessel. However, ``hull'' and ``superstructure'' remain defined...

46 CFR 108.133 - Hull superstructure, structural bulkheads, decks, and deckhouses.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 4 2014-10-01 2014-10-01 false Hull superstructure, structural bulkheads, decks, and deckhouses. 108.133 Section 108.133 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A... Protection § 108.133 Hull superstructure, structural bulkheads, decks, and deckhouses. Each hull...

46 CFR 108.133 - Hull superstructure, structural bulkheads, decks, and deckhouses.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 4 2012-10-01 2012-10-01 false Hull superstructure, structural bulkheads, decks, and deckhouses. 108.133 Section 108.133 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A... Protection § 108.133 Hull superstructure, structural bulkheads, decks, and deckhouses. Each hull...

46 CFR 45.109 - Strength of superstructures and deckhouses.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Strength of superstructures and deckhouses. 45.109... LOAD LINES Conditions of Assignment § 45.109 Strength of superstructures and deckhouses. Each... approved assigning authority with regard to general strength and weathertightness. The Commandant may use...

46 CFR 45.109 - Strength of superstructures and deckhouses.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 2 2011-10-01 2011-10-01 false Strength of superstructures and deckhouses. 45.109... LOAD LINES Conditions of Assignment § 45.109 Strength of superstructures and deckhouses. Each... approved assigning authority with regard to general strength and weathertightness. The Commandant may use...

Basin-Scale Hydrologic Impacts of CO2 Storage: Regulatory and Capacity Implications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Birkholzer, J.T.; Zhou, Q.

Industrial-scale injection of CO{sub 2} into saline sedimentary basins will cause large-scale fluid pressurization and migration of native brines, which may affect valuable groundwater resources overlying the deep sequestration reservoirs. In this paper, we discuss how such basin-scale hydrologic impacts can (1) affect regulation of CO{sub 2} storage projects and (2) may reduce current storage capacity estimates. Our assessment arises from a hypothetical future carbon sequestration scenario in the Illinois Basin, which involves twenty individual CO{sub 2} storage projects in a core injection area suitable for long-term storage. Each project is assumed to inject five million tonnes of CO{sub 2}more » per year for 50 years. A regional-scale three-dimensional simulation model was developed for the Illinois Basin that captures both the local-scale CO{sub 2}-brine flow processes and the large-scale groundwater flow patterns in response to CO{sub 2} storage. The far-field pressure buildup predicted for this selected sequestration scenario suggests that (1) the area that needs to be characterized in a permitting process may comprise a very large region within the basin if reservoir pressurization is considered, and (2) permits cannot be granted on a single-site basis alone because the near- and far-field hydrologic response may be affected by interference between individual sites. Our results also support recent studies in that environmental concerns related to near-field and far-field pressure buildup may be a limiting factor on CO{sub 2} storage capacity. In other words, estimates of storage capacity, if solely based on the effective pore volume available for safe trapping of CO{sub 2}, may have to be revised based on assessments of pressure perturbations and their potential impact on caprock integrity and groundwater resources, respectively. We finally discuss some of the challenges in making reliable predictions of large-scale hydrologic impacts related to CO{sub 2} sequestration projects.« less

Hydrogeologic framework and estimates of groundwater storage for the Hualapai Valley, Detrital Valley, and Sacramento Valley basins, Mohave County, Arizona

USGS Publications Warehouse

Truini, Margot; Beard, L. Sue; Kennedy, Jeffrey; Anning, Dave W.

2013-01-01

We have investigated the hydrogeology of the Hualapai Valley, Detrital Valley, and Sacramento Valley basins of Mohave County in northwestern Arizona to develop a better understanding of groundwater storage within the basin fill aquifers. In our investigation we used geologic maps, well-log data, and geophysical surveys to delineate the sedimentary textures and lithology of the basin fill. We used gravity data to construct a basin geometry model that defines smaller subbasins within the larger basins, and airborne transient-electromagnetic modeled results along with well-log lithology data to infer the subsurface distribution of basin fill within the subbasins. Hydrogeologic units (HGUs) are delineated within the subbasins on the basis of the inferred lithology of saturated basin fill. We used the extent and size of HGUs to estimate groundwater storage to depths of 400 meters (m) below land surface (bls). The basin geometry model for the Hualapai Valley basin consists of three subbasins: the Kingman, Hualapai, and southern Gregg subbasins. In the Kingman subbasin, which is estimated to be 1,200 m deep, saturated basin fill consists of a mixture of fine- to coarse-grained sedimentary deposits. The Hualapai subbasin, which is the largest of the subbasins, contains a thick halite body from about 400 m to about 4,300 m bls. Saturated basin fill overlying the salt body consists predominately of fine-grained older playa deposits. In the southern Gregg subbasin, which is estimated to be 1,400 m deep, saturated basin fill is interpreted to consist primarily of fine- to coarse-grained sedimentary deposits. Groundwater storage to 400 m bls in the Hualapai Valley basin is estimated to be 14.1 cubic kilometers (km3). The basin geometry model for the Detrital Valley basin consists of three subbasins: northern Detrital, central Detrital, and southern Detrital subbasins. The northern and central Detrital subbasins are characterized by a predominance of playa evaporite and fine-grained clastic deposits; evaporite deposits in the northern Detrital subbasin include halite. The northern Detrital subbasin is estimated to be 600 m deep and the middle Detrital subbasin is estimated to be 700 m deep. The southern Detrital subbasin, which is estimated to be 1,500 m deep, is characterized by a mixture of fine- to coarse-grained basin fill deposits. Groundwater storage to 400 m bls in the Detrital Valley basin is estimated to be 9.8 km3. The basin geometry model for the Sacramento Valley basin consists of three subbasins: the Chloride, Golden Valley, and Dutch Flat subbasins. The Chloride subbasin, which is estimated to be 900 m deep, is characterized by fine- to coarse-grained basin fill deposits. In the Golden Valley subbasin, which is elongated north-south, and is estimated to be 1,300 m deep, basin fill includes fine-grained sedimentary deposits overlain by coarse-grained sedimentary deposits in much of the subbasin. The Dutch Flat subbasin is estimated to be 2,600 m deep, and well-log lithologic data suggest that the basin fill consists of interlayers of gravel, sand, and clay. Groundwater storage to 400 m bls in the Sacramento Valley basin is estimated to be 35.1 km3.

Hydrologic implications of GRACE satellite data in the Colorado River Basin

USGS Publications Warehouse

Scanlon, Bridget R.; Zhang, Zizhan; Reedy, Robert C.; Pool, Donald R.; Save, Himanshu; Long, Di; Chen, Jianli; Wolock, David M.; Conway, Brian D.; Winester, Daniel

2015-01-01

Use of GRACE (Gravity Recovery and Climate Experiment) satellites for assessing global water resources is rapidly expanding. Here we advance application of GRACE satellites by reconstructing long-term total water storage (TWS) changes from ground-based monitoring and modeling data. We applied the approach to the Colorado River Basin which has experienced multiyear intense droughts at decadal intervals. Estimated TWS declined by 94 km3 during 1986–1990 and by 102 km3 during 1998–2004, similar to the TWS depletion recorded by GRACE (47 km3) during 2010–2013. Our analysis indicates that TWS depletion is dominated by reductions in surface reservoir and soil moisture storage in the upper Colorado basin with additional reductions in groundwater storage in the lower basin. Groundwater storage changes are controlled mostly by natural responses to wet and dry cycles and irrigation pumping outside of Colorado River delivery zones based on ground-based water level and gravity data. Water storage changes are controlled primarily by variable water inputs in response to wet and dry cycles rather than increasing water use. Surface reservoir storage buffers supply variability with current reservoir storage representing ∼2.5 years of available water use. This study can be used as a template showing how to extend short-term GRACE TWS records and using all available data on storage components of TWS to interpret GRACE data, especially within the context of droughts.

Water resources in basin-fill deposits in the Tularosa Basin, New Mexico

USGS Publications Warehouse

Orr, B.R.; Myers, R.G.

1986-01-01

The Tularosa Basin, a faulted intermontane depression in south-central New Mexico, contains a thick sequence of alluvial and lacustrine deposits of Tertiary and Quaternary age. Most of these sediments are saturated with very saline water. Freshwater supplies (dissolved solids concentration < 1000 mg/L) principally are found in alluvial fans located around the basin margin. On the eastern side of the Tularosa Basin, fresh groundwater supplies are limited to alluvial fan deposits from Grapevine Canyon to about 3 mi south of Alamogordo. Data from surface geophysical surveys indicate that about 1.4 to 2.1 million acre-ft of freshwater may be in storage in this area, not all of which is recoverable. An additional 3.6 to 5.4 million acre-ft of slightly saline water (dissolved solids concentration 1000 to 3000 mg/L) may be in storage in the same area, again not all of which is recoverable. On the western side of the Tularosa Basin, alluvial fans in the vicinity of Rhodes Canyon may contain freshwater. Geophysical data indicate the freshwater zone may be as thick as 1500 ft in places; however, the limited number of wells in this area precludes a precise definition of the volume of freshwater in storage. To the south, freshwater is present in alluvial fans associated with the Ash Canyon drainage system. Geophysical data indicate that perhaps as much as 450,000 acre-ft of freshwater, not all recoverable, may be in storage in this area. Fan deposits between Ash Canyon and Rhodes canyon may contain additional freshwater supplies. Possibly 10.7 million acre-ft of freshwater, not all of which is recoverable, may be in storage on the western side of the Tularosa Basin. Possibly 180 million acre-ft of brine (concentrations of dissolved solids exceeding 35,000 mg/L), not all of which is recoverable, may be in storage in the Tularosa Basin. Information is sparse concerning the capability of saline aquifers in the Tularosa Basin to store and transmit fluid. (Author 's abstract)

40 CFR 745.228 - Accreditation of training programs: public and commercial buildings, bridges and superstructures...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Accreditation of training programs: public and commercial buildings, bridges and superstructures. [Reserved] 745.228 Section 745.228... Accreditation of training programs: public and commercial buildings, bridges and superstructures. [Reserved] ...

46 CFR 67.177 - Application for foreign rebuilding determination.

Code of Federal Regulations, 2012 CFR

2012-10-01

... rebuilt when work performed on its hull or superstructure constitutes a quantum of work determined, to the... be considered rebuilt when work performed on its hull or superstructure constitutes a quantum of work... superstructure constitutes a quantum of work determined, to the maximum extent practicable, to be comparable to 7...

46 CFR 67.177 - Application for foreign rebuilding determination.

Code of Federal Regulations, 2011 CFR

2011-10-01

... rebuilt when work performed on its hull or superstructure constitutes a quantum of work determined, to the... be considered rebuilt when work performed on its hull or superstructure constitutes a quantum of work... superstructure constitutes a quantum of work determined, to the maximum extent practicable, to be comparable to 7...

46 CFR 67.177 - Application for foreign rebuilding determination.

Code of Federal Regulations, 2014 CFR

2014-10-01

... rebuilt when work performed on its hull or superstructure constitutes a quantum of work determined, to the... be considered rebuilt when work performed on its hull or superstructure constitutes a quantum of work... superstructure constitutes a quantum of work determined, to the maximum extent practicable, to be comparable to 7...

46 CFR 67.177 - Application for foreign rebuilding determination.

Code of Federal Regulations, 2013 CFR

2013-10-01

... rebuilt when work performed on its hull or superstructure constitutes a quantum of work determined, to the... be considered rebuilt when work performed on its hull or superstructure constitutes a quantum of work... superstructure constitutes a quantum of work determined, to the maximum extent practicable, to be comparable to 7...

46 CFR 45.58 - Correction: Short superstructure.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 2 2013-10-01 2013-10-01 false Correction: Short superstructure. 45.58 Section 45.58 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) LOAD LINES GREAT LAKES LOAD LINES Freeboards § 45.58 Correction: Short superstructure. The minimum freeboard in summer for a type B vessel that...

46 CFR 45.58 - Correction: Short superstructure.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 2 2014-10-01 2014-10-01 false Correction: Short superstructure. 45.58 Section 45.58 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) LOAD LINES GREAT LAKES LOAD LINES Freeboards § 45.58 Correction: Short superstructure. The minimum freeboard in summer for a type B vessel that...

46 CFR 67.177 - Application for foreign rebuilding determination.

Code of Federal Regulations, 2010 CFR

2010-10-01

... rebuilt when work performed on its hull or superstructure constitutes a quantum of work determined, to the... be considered rebuilt when work performed on its hull or superstructure constitutes a quantum of work... superstructure constitutes a quantum of work determined, to the maximum extent practicable, to be comparable to 7...

40 CFR 745.228 - Accreditation of training programs: public and commercial buildings, bridges and superstructures...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Accreditation of training programs: public and commercial buildings, bridges and superstructures. [Reserved] 745.228 Section 745.228... Accreditation of training programs: public and commercial buildings, bridges and superstructures. [Reserved] ...

Potential for using the Upper Coachella Valley ground-water basin, California, for storage of artificially recharged water

USGS Publications Warehouse

Mallory, Michael J.; Swain, Lindsay A.; Tyley, Stephen J.

1980-01-01

This report presents a preliminary evaluation of the geohydrologic factors affecting storage of water by artificial recharge in the upper Coachella Valley, Calif. The ground-water basin of the upper Coachella Valley seems to be geologically suitable for large-scale artificial recharge. A minimum of 900 ,000 acre-feet of water could probably be stored in the basin without raising basinwide water levels above those that existed in 1945. Preliminary tests indicate that a long-term artificial recharge rate of 5 feet per day may be feasible for spreading grounds in the basin if such factors as sediment and bacterial clogging can be controlled. The California Department of Water Resources, through the Future Water Supply Program, is investigating the use of ground-water basins for storage of State Water Project water in order to help meet maximum annual entitlements to water project contractors. (USGS)

Land Water Storage within the Congo Basin Inferred from GRACE Satellite Gravity Data

NASA Technical Reports Server (NTRS)

Crowley, John W.; Mitrovica, Jerry X.; Bailey, Richard C.; Tamisiea, Mark E.; Davis, James L.

2006-01-01

GRACE satellite gravity data is used to estimate terrestrial (surface plus ground) water storage within the Congo Basin in Africa for the period of April, 2002 - May, 2006. These estimates exhibit significant seasonal (30 +/- 6 mm of equivalent water thickness) and long-term trends, the latter yielding a total loss of approximately 280 km(exp 3) of water over the 50-month span of data. We also combine GRACE and precipitation data set (CMAP, TRMM) to explore the relative contributions of the source term to the seasonal hydrological balance within the Congo Basin. We find that the seasonal water storage tends to saturate for anomalies greater than 30-44 mm of equivalent water thickness. Furthermore, precipitation contributed roughly three times the peak water storage after anomalously rainy seasons, in early 2003 and 2005, implying an approximately 60-70% loss from runoff and evapotranspiration. Finally, a comparison of residual land water storage (monthly estimates minus best-fitting trends) in the Congo and Amazon Basins shows an anticorrelation, in agreement with the 'see-saw' variability inferred by others from runoff data.

11. BUOY DECK, NEAR PILOT HOUSE SUPERSTRUCTURE, LOOKING TOWARDS HATCH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. BUOY DECK, NEAR PILOT HOUSE SUPERSTRUCTURE, LOOKING TOWARDS HATCH DOOR INTO WINCH ROOM IN THE SUPERSTRUCTURE (LABELED AS FASSAGE & HYDRAULIC MACHINERY ON PLAN), SHOWING UNDERSIDE OF GEARED WHEEL OF BOOM. - U.S. Coast Guard Cutter WHITE LUPINE, U.S. Coast Guard Station Rockland, east end of Tillson Avenue, Rockland, Knox County, ME

DEMONSTRATION OF LONG-TERM STORAGE CAPABILITY FOR SPENT NUCLEAR FUEL IN L BASIN

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sindelar, R.; Deible, R.

2011-04-27

The U.S. Department of Energy decisions for the ultimate disposition of its inventory of used nuclear fuel presently in, and to be received and stored in, the L Basin at the Savannah River Site, and schedule for project execution have not been established. A logical decision timeframe for the DOE is following the review of the overall options for fuel management and disposition by the Blue Ribbon Commission on America's Nuclear Future (BRC). The focus of the BRC review is commercial fuel; however, the BRC has included the DOE fuel inventory in their review. Even though the final report bymore » the BRC to the U.S. Department of Energy is expected in January 2012, no timetable has been established for decisions by the U.S. Department of Energy on alternatives selection. Furthermore, with the imminent lay-up and potential closure of H-canyon, no ready path for fuel disposition would be available, and new technologies and/or facilities would need to be established. The fuel inventory in wet storage in the 3.375 million gallon L Basin is primarily aluminum-clad, aluminum-based fuel of the Materials Test Reactor equivalent design. An inventory of non-aluminum-clad fuel of various designs is also stored in L Basin. Safe storage of fuel in wet storage mandates several high-level 'safety functions' that would be provided by the Structures, Systems, and Components (SSCs) of the storage system. A large inventory of aluminum-clad, aluminum-based spent nuclear fuel, and other nonaluminum fuel owned by the U.S. Department of Energy is in wet storage in L Basin at the Savannah River Site. An evaluation of the present condition of the fuel, and the Structures, Systems, or Components (SSCs) necessary for its wet storage, and the present programs and storage practices for fuel management have been performed. Activities necessary to validate the technical bases for, and verify the condition of the fuel and the SSCs under long-term wet storage have also been identified. The overall conclusion is that the fuel can be stored in L Basin, meeting general safety functions for fuel storage, for an additional 50 years and possibly beyond contingent upon continuation of existing fuel management activities and several augmented program activities. It is concluded that the technical bases and well-founded technologies have been established to store spent nuclear fuel in the L Basin. Methodologies to evaluate the fuel condition and characteristics, and systems to prepare fuel, isolate damaged fuel, and maintain water quality storage conditions have been established. Basin structural analyses have been performed against present NPH criteria. The aluminum fuel storage experience to date, supported by the understanding of the effects of environmental variables on materials performance, demonstrates that storage systems that minimize degradation and provide full retrievability of the fuel up to and greater than 50 additional years will require maintaining the present management programs, and with the recommended augmented/additional activities in this report.« less

VIEW OF TRANSFER BASIN CORRIDOR OF FUEL STORAGE BUILDING (CPP603). ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW OF TRANSFER BASIN CORRIDOR OF FUEL STORAGE BUILDING (CPP-603). PHOTO TAKEN LOOKING NORTH. INL PHOTO NUMBER HD-54-17-2. Mike Crane, Photographer, 8/2005 - Idaho National Engineering Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex, Scoville, Butte County, ID

Hydrologic implications of GRACE satellite data in the Colorado River Basin

NASA Astrophysics Data System (ADS)

Scanlon, Bridget R.; Zhang, Zizhan; Reedy, Robert C.; Pool, Donald R.; Save, Himanshu; Long, Di; Chen, Jianli; Wolock, David M.; Conway, Brian D.; Winester, Daniel

2015-12-01

Use of GRACE (Gravity Recovery and Climate Experiment) satellites for assessing global water resources is rapidly expanding. Here we advance application of GRACE satellites by reconstructing long-term total water storage (TWS) changes from ground-based monitoring and modeling data. We applied the approach to the Colorado River Basin which has experienced multiyear intense droughts at decadal intervals. Estimated TWS declined by 94 km3 during 1986-1990 and by 102 km3 during 1998-2004, similar to the TWS depletion recorded by GRACE (47 km3) during 2010-2013. Our analysis indicates that TWS depletion is dominated by reductions in surface reservoir and soil moisture storage in the upper Colorado basin with additional reductions in groundwater storage in the lower basin. Groundwater storage changes are controlled mostly by natural responses to wet and dry cycles and irrigation pumping outside of Colorado River delivery zones based on ground-based water level and gravity data. Water storage changes are controlled primarily by variable water inputs in response to wet and dry cycles rather than increasing water use. Surface reservoir storage buffers supply variability with current reservoir storage representing ˜2.5 years of available water use. This study can be used as a template showing how to extend short-term GRACE TWS records and using all available data on storage components of TWS to interpret GRACE data, especially within the context of droughts. This article was corrected on 12 JAN 2016. See the end of the full text for details.

Amplicon Sequencing Reveals Microbiological Signatures in Spent Nuclear Fuel Storage Basins

DOE PAGES

Bagwell, Christopher E.; Noble, Peter A.; Milliken, Charles E.; ...

2018-03-09

Water quality is an important determinant for the structural integrity of alloy cladded fuels and assemblies during long-term wet storage. Detailed characterization of a water filled storage basin for spent nuclear reactor fuel was performed following the formation and proliferation of an amorphous white flocculent. White precipitant was sampled throughout the storage basin for chemical and spectroscopic characterization, and environmental DNA was extracted for 454 pyrosequencing of bacterial 16S rRNA gene diversity. Accordingly, spectroscopic analyses indicated the precipitant to be primarily amorphous to crystalline aluminum (oxy) hydroxides with minor associated elemental components including Fe, Si, Ti, and U. High levelsmore » of organic carbon were co-localized with the precipitant relative to bulk dissolved organic concentrations. Bacterial densities were highly variable between sampling locations and with depth within the water filled storage basin; cell numbers ranged from 4 × 10 3to 4 × 104 cells/mL. Bacterial diversity that was physically associated with the aluminum (oxy) hydroxide complexes exceeded an estimated 4,000 OTUs/amplicon library (3% cutoff) and the majority of sequences were aligned to the families Burkholderiaceae (23%), Nitrospiraceae (23%), Hyphomicrobiaceae (17%), and Comamonadaceae (6%). We surmise that episodic changes in the physical and chemical properties of the basin contribute to the polymerization of aluminum (oxy) hydroxides, which in turn can chemisorb nutrients, carbon ligands and bacterial cells from the surrounding bulk aqueous phase. As such, these precipitants should establish favorable microhabitats for bacterial colonization and growth. Comparative analyses of 16S rRNA gene amplicon libraries across a selection of natural and engineered aquatic ecosystems were performed and microbial community and taxonomic signatures unique to the spent nuclear fuel (SNF) storage basin environment were revealed. These insights could spur the development of tractable bio-indicators that are specific of and diagnostic for water quality at discrete locations and finer scales of resolution, marking an important contribution for improved water quality and management of SNF storage facilities.« less

Amplicon Sequencing Reveals Microbiological Signatures in Spent Nuclear Fuel Storage Basins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bagwell, Christopher E.; Noble, Peter A.; Milliken, Charles E.

Water quality is an important determinant for the structural integrity of alloy cladded fuels and assemblies during long-term wet storage. Detailed characterization of a water filled storage basin for spent nuclear reactor fuel was performed following the formation and proliferation of an amorphous white flocculent. White precipitant was sampled throughout the storage basin for chemical and spectroscopic characterization, and environmental DNA was extracted for 454 pyrosequencing of bacterial 16S rRNA gene diversity. Accordingly, spectroscopic analyses indicated the precipitant to be primarily amorphous to crystalline aluminum (oxy) hydroxides with minor associated elemental components including Fe, Si, Ti, and U. High levelsmore » of organic carbon were co-localized with the precipitant relative to bulk dissolved organic concentrations. Bacterial densities were highly variable between sampling locations and with depth within the water filled storage basin; cell numbers ranged from 4 × 10 3to 4 × 104 cells/mL. Bacterial diversity that was physically associated with the aluminum (oxy) hydroxide complexes exceeded an estimated 4,000 OTUs/amplicon library (3% cutoff) and the majority of sequences were aligned to the families Burkholderiaceae (23%), Nitrospiraceae (23%), Hyphomicrobiaceae (17%), and Comamonadaceae (6%). We surmise that episodic changes in the physical and chemical properties of the basin contribute to the polymerization of aluminum (oxy) hydroxides, which in turn can chemisorb nutrients, carbon ligands and bacterial cells from the surrounding bulk aqueous phase. As such, these precipitants should establish favorable microhabitats for bacterial colonization and growth. Comparative analyses of 16S rRNA gene amplicon libraries across a selection of natural and engineered aquatic ecosystems were performed and microbial community and taxonomic signatures unique to the spent nuclear fuel (SNF) storage basin environment were revealed. These insights could spur the development of tractable bio-indicators that are specific of and diagnostic for water quality at discrete locations and finer scales of resolution, marking an important contribution for improved water quality and management of SNF storage facilities.« less

Amplicon Sequencing Reveals Microbiological Signatures in Spent Nuclear Fuel Storage Basins.

PubMed

Bagwell, Christopher E; Noble, Peter A; Milliken, Charles E; Li, Dien; Kaplan, Daniel I

2018-01-01

Water quality is an important determinant for the structural integrity of alloy cladded fuels and assemblies during long-term wet storage. Detailed characterization of a water filled storage basin for spent nuclear reactor fuel was performed following the formation and proliferation of an amorphous white flocculent. White precipitant was sampled throughout the storage basin for chemical and spectroscopic characterization, and environmental DNA was extracted for 454 pyrosequencing of bacterial 16S rRNA gene diversity. Accordingly, spectroscopic analyses indicated the precipitant to be primarily amorphous to crystalline aluminum (oxy) hydroxides with minor associated elemental components including Fe, Si, Ti, and U. High levels of organic carbon were co-localized with the precipitant relative to bulk dissolved organic concentrations. Bacterial densities were highly variable between sampling locations and with depth within the water filled storage basin; cell numbers ranged from 4 × 10 3 to 4 × 10 4 cells/mL. Bacterial diversity that was physically associated with the aluminum (oxy) hydroxide complexes exceeded an estimated 4,000 OTUs/amplicon library (3% cutoff) and the majority of sequences were aligned to the families Burkholderiaceae (23%), Nitrospiraceae (23%), Hyphomicrobiaceae (17%), and Comamonadaceae (6%). We surmise that episodic changes in the physical and chemical properties of the basin contribute to the polymerization of aluminum (oxy) hydroxides, which in turn can chemisorb nutrients, carbon ligands and bacterial cells from the surrounding bulk aqueous phase. As such, these precipitants should establish favorable microhabitats for bacterial colonization and growth. Comparative analyses of 16S rRNA gene amplicon libraries across a selection of natural and engineered aquatic ecosystems were performed and microbial community and taxonomic signatures unique to the spent nuclear fuel (SNF) storage basin environment were revealed. These insights could spur the development of tractable bio-indicators that are specific of and diagnostic for water quality at discrete locations and finer scales of resolution, marking an important contribution for improved water quality and management of SNF storage facilities.

Amplicon Sequencing Reveals Microbiological Signatures in Spent Nuclear Fuel Storage Basins

PubMed Central

Bagwell, Christopher E.; Noble, Peter A.; Milliken, Charles E.; Li, Dien; Kaplan, Daniel I.

2018-01-01

Water quality is an important determinant for the structural integrity of alloy cladded fuels and assemblies during long-term wet storage. Detailed characterization of a water filled storage basin for spent nuclear reactor fuel was performed following the formation and proliferation of an amorphous white flocculent. White precipitant was sampled throughout the storage basin for chemical and spectroscopic characterization, and environmental DNA was extracted for 454 pyrosequencing of bacterial 16S rRNA gene diversity. Accordingly, spectroscopic analyses indicated the precipitant to be primarily amorphous to crystalline aluminum (oxy) hydroxides with minor associated elemental components including Fe, Si, Ti, and U. High levels of organic carbon were co-localized with the precipitant relative to bulk dissolved organic concentrations. Bacterial densities were highly variable between sampling locations and with depth within the water filled storage basin; cell numbers ranged from 4 × 103to 4 × 104 cells/mL. Bacterial diversity that was physically associated with the aluminum (oxy) hydroxide complexes exceeded an estimated 4,000 OTUs/amplicon library (3% cutoff) and the majority of sequences were aligned to the families Burkholderiaceae (23%), Nitrospiraceae (23%), Hyphomicrobiaceae (17%), and Comamonadaceae (6%). We surmise that episodic changes in the physical and chemical properties of the basin contribute to the polymerization of aluminum (oxy) hydroxides, which in turn can chemisorb nutrients, carbon ligands and bacterial cells from the surrounding bulk aqueous phase. As such, these precipitants should establish favorable microhabitats for bacterial colonization and growth. Comparative analyses of 16S rRNA gene amplicon libraries across a selection of natural and engineered aquatic ecosystems were performed and microbial community and taxonomic signatures unique to the spent nuclear fuel (SNF) storage basin environment were revealed. These insights could spur the development of tractable bio-indicators that are specific of and diagnostic for water quality at discrete locations and finer scales of resolution, marking an important contribution for improved water quality and management of SNF storage facilities. PMID:29593667

Recrystallization-induced self-assembly for the growth of Cu₂O superstructures.

PubMed

Shang, Yang; Shao, Yi-Ming; Zhang, Dong-Feng; Guo, Lin

2014-10-20

The assembly of inorganic nanoparticles (NPs) into 3D superstructures with defined morphologies is of particular interest. A novel strategy that is based on recrystallization-induced self-assembly (RISA) for the construction of 3D Cu2O superstructures and employs Cu2O mesoporous spheres with diameters of approximately 300 nm as the building blocks has now been developed. Balancing the hydrolysis and recrystallization rates of the CuCl precursors through precisely adjusting the experimental parameters was key to success. Furthermore, the geometry of the superstructures can be tuned to obtain either cubes or tetrahedra and was shown to be dependent on the growth behavior of bulk CuCl. The overall strategy extends the applicability of recrystallization-based processes for the guided construction of assemblies and offers unique insights for assembling larger particles into complicated 3D superstructures. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Potential evaluation of CO2 storage and enhanced oil recovery of tight oil reservoir in the Ordos Basin, China.

PubMed

Tian, Xiaofeng; Cheng, Linsong; Cao, Renyi; Zhang, Miaoyi; Guo, Qiang; Wang, Yimin; Zhang, Jian; Cui, Yu

2015-07-01

Carbon -di-oxide (CO2) is regarded as the most important greenhouse gas to accelerate climate change and ocean acidification. The Chinese government is seeking methods to reduce anthropogenic CO2 gas emission. CO2 capture and geological storage is one of the main methods. In addition, injecting CO2 is also an effective method to replenish formation energy in developing tight oil reservoirs. However, exiting methods to estimate CO2 storage capacity are all based on the material balance theory. This was absolutely correct for normal reservoirs. However, as natural fractures widely exist in tight oil reservoirs and majority of them are vertical ones, tight oil reservoirs are not close. Therefore, material balance theory is not adaptive. In the present study, a new method to calculate CO2 storage capacity is presented. The CO2 effective storage capacity, in this new method, consisted of free CO2, CO2 dissolved in oil and CO2 dissolved in water. Case studies of tight oil reservoir from Ordos Basin was conducted and it was found that due to far lower viscosity of CO2 and larger solubility in oil, CO2 could flow in tight oil reservoirs more easily. As a result, injecting CO2 in tight oil reservoirs could obviously enhance sweep efficiency by 24.5% and oil recovery efficiency by 7.5%. CO2 effective storage capacity of Chang 7 tight oil reservoir in Longdong area was 1.88 x 10(7) t. The Chang 7 tight oil reservoir in Ordos Basin was estimated to be 6.38 x 10(11) t. As tight oil reservoirs were widely distributed in Songliao Basin, Sichuan Basin and so on, geological storage capacity of CO2 in China is potential.

GRACE Hydrological estimates for small basins: Evaluating processing approaches on the High Plains Aquifer, USA

NASA Astrophysics Data System (ADS)

Longuevergne, Laurent; Scanlon, Bridget R.; Wilson, Clark R.

2010-11-01

The Gravity Recovery and Climate Experiment (GRACE) satellites provide observations of water storage variation at regional scales. However, when focusing on a region of interest, limited spatial resolution and noise contamination can cause estimation bias and spatial leakage, problems that are exacerbated as the region of interest approaches the GRACE resolution limit of a few hundred km. Reliable estimates of water storage variations in small basins require compromises between competing needs for noise suppression and spatial resolution. The objective of this study was to quantitatively investigate processing methods and their impacts on bias, leakage, GRACE noise reduction, and estimated total error, allowing solution of the trade-offs. Among the methods tested is a recently developed concentration algorithm called spatiospectral localization, which optimizes the basin shape description, taking into account limited spatial resolution. This method is particularly suited to retrieval of basin-scale water storage variations and is effective for small basins. To increase confidence in derived methods, water storage variations were calculated for both CSR (Center for Space Research) and GRGS (Groupe de Recherche de Géodésie Spatiale) GRACE products, which employ different processing strategies. The processing techniques were tested on the intensively monitored High Plains Aquifer (450,000 km2 area), where application of the appropriate optimal processing method allowed retrieval of water storage variations over a portion of the aquifer as small as ˜200,000 km2.

Water Demand Management Strategies and Challenges in the Upper Colorado River Basin

NASA Astrophysics Data System (ADS)

Kuhn, R. E.

2016-12-01

Under the 1922 Colorado River Compact, the Upper Basin (Colorado, New Mexico, Utah, and Wyoming) has flow obligations at Lee Ferry to downstream states and Mexico. The Colorado River Storage Project Act (CRSPA) of 1956 led to the construction of four large storage reservoirs. These provide river regulation to allow the Upper Basin to meet its obligations. Lake Powell, the largest and most important, and Lake Mead are now operated in a coordinated manner under the 2007 Interim Guidelines. Studies show that at current demand levels and if the hydrologic conditions the Basin has experienced since the mid-1980s continue or get drier, reservoir operations, alone, may not provide the necessary water to meet the Upper Basin's obligations. Therefore, the Upper Basin states are now studying demand management strategies that will reduce consumptive uses when total system reservoir storage reaches critically low levels. Demand management has its own economic, political and technical challenges and limitations and will provide new opportunities for applied research. This presentation will discuss some of those strategies, their challenges, and the kinds of information that research could provide to inform demand management.

Shallow aquifer storage and recovery (SASR): Initial findings from the Willamette Basin, Oregon

NASA Astrophysics Data System (ADS)

Neumann, P.; Haggerty, R.

2012-12-01

A novel mode of shallow aquifer management could increase the volumetric potential and distribution of groundwater storage. We refer to this mode as shallow aquifer storage and recovery (SASR) and gauge its potential as a freshwater storage tool. By this mode, water is stored in hydraulically connected aquifers with minimal impact to surface water resources. Basin-scale numerical modeling provides a linkage between storage efficiency and hydrogeological parameters, which in turn guides rulemaking for how and where water can be stored. Increased understanding of regional groundwater-surface water interactions is vital to effective SASR implementation. In this study we (1) use a calibrated model of the central Willamette Basin (CWB), Oregon to quantify SASR storage efficiency at 30 locations; (2) estimate SASR volumetric storage potential throughout the CWB based on these results and pertinent hydrogeological parameters; and (3) introduce a methodology for management of SASR by such parameters. Of 3 shallow, sedimentary aquifers in the CWB, we find the moderately conductive, semi-confined, middle sedimentary unit (MSU) to be most efficient for SASR. We estimate that users overlying 80% of the area in this aquifer could store injected water with greater than 80% efficiency, and find efficiencies of up to 95%. As a function of local production well yields, we estimate a maximum annual volumetric storage potential of 30 million m3 using SASR in the MSU. This volume constitutes roughly 9% of the current estimated summer pumpage in the Willamette basin at large. The dimensionless quantity lag #—calculated using modeled specific capacity, distance to nearest in-layer stream boundary, and injection duration—exhibits relatively high correlation to SASR storage efficiency at potential locations in the CWB. This correlation suggests that basic field measurements could guide SASR as an efficient shallow aquifer storage tool.

Modified Streamflows 1990 Level of Irrigation : Missouri, Colorado, Peace and Slave River Basin, 1928-1989.

DOE Office of Scientific and Technical Information (OSTI.GOV)

A.G. Crook Company; United States. Bonneville Power Administration

1993-07-01

This report presents data for monthly mean streamflows adjusted for storage change, evaporation, and irrigation, for the years 1928-1990, for the Colorado River Basin, the Missouri River Basin, the Peace River Basin, and the Slave River Basin.

Analysis of Ignition Testing on K-West Basin Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. Abrefah; F.H. Huang; W.M. Gerry

Approximately 2100 metric tons of spent nuclear fuel (SNF) discharged from the N-Reactor have been stored underwater at the K-Basins in the 100 Area of the Hanford Site. The spent fuel has been stored in the K-East Basin since 1975 and in the K-West Basin since 1981. Some of the SNF elements in these basins have corroded because of various breaches in the Zircaloy cladding that occurred during fuel discharge operations and/or subsequent handling and storage in the basins. Consequently, radioactive material in the fuel has been released into the basin water, and water has leaked from the K-East Basinmore » into the soil below. To protect the Columbia River, which is only 380 m from the basins, the SNF is scheduled to be removed and transported for interim dry storage in the 200 East Area, in the central portion of the Site. However, before being shipped, the corroded fuel elements will be loaded into Multi-Canister OverPacks and conditioned. The conditioning process will be selected based on the Integrated Process Strategy (IPS) (WHC 1995), which was prepared on the basis of the dry storage concept developed by the Independent Technical Assessment (ITA) team (ITA 1994).« less

Comparison of Decadal Water Storage Trends from Global Hydrological Models and GRACE Satellite Data

NASA Astrophysics Data System (ADS)

Scanlon, B. R.; Zhang, Z. Z.; Save, H.; Sun, A. Y.; Mueller Schmied, H.; Van Beek, L. P.; Wiese, D. N.; Wada, Y.; Long, D.; Reedy, R. C.; Doll, P. M.; Longuevergne, L.

2017-12-01

Global hydrology is increasingly being evaluated using models; however, the reliability of these global models is not well known. In this study we compared decadal trends (2002-2014) in land water storage from 7 global models (WGHM, PCR-GLOBWB, and GLDAS: NOAH, MOSAIC, VIC, CLM, and CLSM) to storage trends from new GRACE satellite mascon solutions (CSR-M and JPL-M). The analysis was conducted over 186 river basins, representing about 60% of the global land area. Modeled total water storage trends agree with those from GRACE-derived trends that are within ±0.5 km3/yr but greatly underestimate large declining and rising trends outside this range. Large declining trends are found mostly in intensively irrigated basins and in some basins in northern latitudes. Rising trends are found in basins with little or no irrigation and are generally related to increasing trends in precipitation. The largest decline is found in the Ganges (-12 km3/yr) and the largest rise in the Amazon (43 km3/yr). Differences between models and GRACE are greatest in large basins (>0.5x106 km2) mostly in humid regions. There is very little agreement in storage trends between models and GRACE and among the models with values of r2 mostly <0.1. Various factors can contribute to discrepancies in water storage trends between models and GRACE, including uncertainties in precipitation, model calibration, storage capacity, and water use in models and uncertainties in GRACE data related to processing, glacier leakage, and glacial isostatic adjustment. The GRACE data indicate that land has a large capacity to store water over decadal timescales that is underrepresented by the models. The storage capacity in the modeled soil and groundwater compartments may be insufficient to accommodate the range in water storage variations shown by GRACE data. The inability of the models to capture the large storage trends indicates that model projections of climate and human-induced changes in water storage may be mostly underestimated. Future GRACE and model studies should try to reduce the various sources of uncertainty in water storage trends and should consider expanding the modeled storage capacity of the soil profiles and their interaction with groundwater.

Single crystalline silicene consist of various superstructures using a flexible ultrathin Ag(111) template on Si(111)

NASA Astrophysics Data System (ADS)

Hsu, Hung-Chang; Lu, Yi-Hung; Su, Tai-Lung; Lin, Wen-Chin; Fu, Tsu-Yi

2018-07-01

Using scanning tunneling microscopy, we studied the formation of silicene on an ultrathin Ag(111) film with a thickness of 6–12 monolayers, which was prepared on a Si(111) substrate. A low-energy electron diffraction pattern with an oval spot indicated that the ultrathin Ag(111) film is more disordered than the single-crystal Ag(111). After Si epitaxy growth, we still measured the classical 4 × 4, √13 × √13, and 2√3 × 2√3 silicene superstructures, which are the same as the silicene superstructure on single-crystal Ag(111). Growing silicene on a single-crystal Ag(111) bulk usually results in the formation of a defect boundary due to the inconsistent orientation of various superstructures. By comparing the angles and boundary conditions between various silicene superstructures on the ultrathin film and single-crystal Ag(111), we discovered that a consistent orientation of various superstructures without obvious boundary defects formed on the ultrathin Ag(111) film. The results indicated single crystalline silicene formation, which was attributed to the domain rotation and lateral shift of the disordered ultrathin Ag(111) film.

Superstructures at Te/Au(111) interface evolving upon increasing Te coverage

NASA Astrophysics Data System (ADS)

Guan, Jiaqi; Huang, Xiaochun; Xu, Xiaofeng; Zhang, Shuyuan; Jia, Xun; Zhu, Xuetao; Wang, Weihua; Guo, Jiandong

2018-03-01

By in-situ low temperature scanning tunneling microscopy, we systematically investigated the superstructure evolution at Te/Au(111) interface upon increasing Te coverage. Te atoms form one-dimensional √{ 3} R30∘ chains at ∼0.10 monolayer (ML) coverage. Two two-dimensional chiral superstructures, (√{ 111} ×√{ 111}) R 4 .7∘ and (3√{ 21} × 3√{ 21}) R 10 .9∘ , are selectively formed with the Te coverage below and above 1/3 ML, respectively. The two chiral superstructures can be converted to each other reversibly by adding Te atoms or moderately annealing. A honeycomb-like superstructure, decorated with adatoms that are distributed in quasi-one-dimensional chains, is observed by further increasing the Te coverage to 4/9 ML. At the Te/Au(111) interface, an interfacial state at -0.65 eV to -0.55 eV below the Fermi level is also resolved by scanning tunneling spectroscopy. The formation of these Te-induced high-order superstructures is accompanied by relaxation of gold atoms in the surface layer, indicating a strong Te-Au interaction. Our work demonstrates a reliable method to fabricate Te nanostructures on noble metals in a controlled way.

Multi-scale analysis of the fluxes between terrestrial water storage, groundwater, and stream discharge in the Columbia River Basin

EPA Science Inventory

The temporal relationships between the measurements of terrestrial water storage (TWS), groundwater, and stream discharge were analyzed at three different scales in the Columbia River Basin (CRB) for water years 2004 - 2012. Our nested watershed approach examined the Snake River ...

RECONNAISSANCE ASSESSMENT OF CO2 SEQUESTRATION POTENTIAL IN THE TRIASSIC AGE RIFT BASIN TREND OF SOUTH CAROLINA, GEORGIA, AND NORTHERN FLORIDA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blount, G.; Millings, M.

2011-08-01

A reconnaissance assessment of the carbon dioxide (CO{sub 2}) sequestration potential within the Triassic age rift trend sediments of South Carolina, Georgia and the northern Florida Rift trend was performed for the Office of Fossil Energy, National Energy Technology Laboratory (NETL). This rift trend also extends into eastern Alabama, and has been termed the South Georgia Rift by previous authors, but is termed the South Carolina, Georgia, northern Florida, and eastern Alabama Rift (SGFAR) trend in this report to better describe the extent of the trend. The objectives of the study were to: (1) integrate all pertinent geologic information (literaturemore » reviews, drilling logs, seismic data, etc.) to create an understanding of the structural aspects of the basin trend (basin trend location and configuration, and the thickness of the sedimentary rock fill), (2) estimate the rough CO{sub 2} storage capacity (using conservative inputs), and (3) assess the general viability of the basins as sites of large-scale CO{sub 2} sequestration (determine if additional studies are appropriate). The CO{sub 2} estimates for the trend include South Carolina, Georgia, and northern Florida only. The study determined that the basins within the SGFAR trend have sufficient sedimentary fill to have a large potential storage capacity for CO{sub 2}. The deeper basins appear to have sedimentary fill of over 15,000 feet. Much of this fill is likely to be alluvial and fluvial sedimentary rock with higher porosity and permeability. This report estimates an order of magnitude potential capacity of approximately 137 billion metric tons for supercritical CO{sub 2}. The pore space within the basins represent hundreds of years of potential storage for supercritical CO{sub 2} and CO{sub 2} stored in aqueous form. There are many sources of CO{sub 2} within the region that could use the trend for geologic storage. Thirty one coal fired power plants are located within 100 miles of the deepest portions of these basins. There are also several cement and ammonia plants near the basins. Sixteen coal fired power plants are present on or adjacent to the basins which could support a low pipeline transportation cost. The current geological information is not sufficient to quantify specific storage reservoirs, seals, or traps. There is insufficient hydrogeologic information to quantify the saline nature of the water present within all of the basins. Water data in the Dunbarton Basin of the Savannah River Site indicates dissolved solids concentrations of greater than 10,000 parts per million (not potential drinking water). Additional reservoir characterization is needed to take advantage of the SGFAR trend for anthropogenic CO{sub 2} storage. The authors of this report believe it would be appropriate to study the reservoir potential in the deeper basins that are in close proximity to the current larger coal fired power plants (Albany-Arabi, Camilla-Ocilla, Alamo-Ehrhardt, and Jedburg basin).« less

Exploring storage and runoff generation processes for urban flooding through a physically based watershed model

NASA Astrophysics Data System (ADS)

Smith, B. K.; Smith, J. A.; Baeck, M. L.; Miller, A. J.

2015-03-01

A physically based model of the 14 km2 Dead Run watershed in Baltimore County, MD was created to test the impacts of detention basin storage and soil storage on the hydrologic response of a small urban watershed during flood events. The Dead Run model was created using the Gridded Surface Subsurface Hydrologic Analysis (GSSHA) algorithms and validated using U.S. Geological Survey stream gaging observations for the Dead Run watershed and 5 subbasins over the largest 21 warm season flood events during 2008-2012. Removal of the model detention basins resulted in a median peak discharge increase of 11% and a detention efficiency of 0.5, which was defined as the percent decrease in peak discharge divided by percent detention controlled area. Detention efficiencies generally decreased with increasing basin size. We tested the efficiency of detention basin networks by focusing on the "drainage network order," akin to the stream order but including storm drains, streams, and culverts. The detention efficiency increased dramatically between first-order detention and second-order detention but was similar for second and third-order detention scenarios. Removal of the soil compacted layer, a common feature in urban soils, resulted in a 7% decrease in flood peak discharges. This decrease was statistically similar to the flood peak decrease caused by existing detention. Current soil storage within the Dead Run watershed decreased flood peak discharges by a median of 60%. Numerical experiment results suggested that detention basin storage and increased soil storage have the potential to substantially decrease flood peak discharges.

Investigation on the effectiveness of pretreatment in stormwater management technologies.

PubMed

Maniquiz-Redillas, Marla C; Geronimo, Franz Kevin F; Kim, Lee-Hyung

2014-09-01

The effectiveness of presettling basins as component of stormwater best management practice (BMP) technologies was investigated. Storm event monitoring and sediment collection were conducted from May 2009 to November 2012 on the presettling basins of the three BMP technologies designed to capture and treat stormwater runoff from highly impervious roads and parking lots. Data on captured runoff and sediment, total suspended solids (TSS) loadings, rainfall and runoff rate, sediment accumulation rate, as well as particle distribution and pollutant concentrations of sediment were gathered and analyzed along with the physical design characteristics of the presettling basins such as surface area and storage volume. Regression models were generated to determine significant relationships between design parameters. Results revealed that the storage volume ratio (ratio of storage volume of presettling basin to BMP) was an important parameter in designing the presettling basin of the BMP. For practicality, optimizing the design of the presettling basin means that the storage volume ratio should be determined based on the desired captured amount of runoff and sediment from runoff to limit the frequency of maintenance caused by the accumulation of sediment. It was recommended that pretreatment of runoff should be employed when the site in which the BMP is to be sited has high TSS loading and runoff rate, and is subjected to high intensity rainfall. Copyright © 2014. Published by Elsevier B.V.

Transient storage assessments of dye-tracer injections in rivers of the Willamette Basin, Oregon

USGS Publications Warehouse

Laenen, A.; Bencala, K.E.

2001-01-01

Rhodamine WT dye-tracer injections in rivers of the Willamette Basin yield concentration-time curves with characteristically long recession times suggestive of active transient storage processes. The scale of drainage areas contributing to the stream reaches studied in the Willamette Basin ranges from 10 to 12,000 km2. A transient storage assessment of the tracer studies has been completed using the U.S. Geological Survey's One-dimensional Transport with Inflow and Storage (OTIS) model, which incorporates storage exchange and decay functions along with the traditional dispersion and advection transport equation. The analysis estimates solute transport of the dye. It identifies first-order decay coefficients to be on the order of 10-5/sec for the nonconservative Rhodamine WT. On an individual subreach basis, the first-order decay is slower (typically by an order of magnitude) than the transient storage process, indicating that nonconservative tracers may be used to evaluate transient storage in rivers. In the transient storage analysis, a dimensionless parameter (As/A) expresses the spatial extent of storage zone area relative to stream cross section. In certain reaches of Willamette Basin pool-and-riffle, gravel-bed rivers, this parameter was as large as 0.5. A measure of the storage exchange flux was calculated for each stream subreach in the simulation analysis. This storage exchange is shown subjectively to be higher at higher stream discharges. Hyporheic linkage between streams and subsurface flows is the probable physical mechanism contributing to a significant part of this inferred active transient storage. Hyporheic linkages are further suggested by detailed measurements of river discharge with an Acoustic Doppler Current Profiler system delineating zones in two large rivers where water alternately enters and leaves the surface channels through graveland-cobble riverbeds. Measurements show patterns of hyporheic exchange that are highly variable in time and space.

Future snow? A spatial-probabilistic assessment of the extraordinarily low snowpacks of 2014 and 2015 in the Oregon Cascades

NASA Astrophysics Data System (ADS)

Sproles, Eric A.; Roth, Travis R.; Nolin, Anne W.

2017-02-01

In the Pacific Northwest, USA, the extraordinarily low snowpacks of winters 2013-2014 and 2014-2015 stressed regional water resources and the social-environmental system. We introduce two new approaches to better understand how seasonal snow water storage during these two winters would compare to snow water storage under warmer climate conditions. The first approach calculates a spatial-probabilistic metric representing the likelihood that the snow water storage of 2013-2014 and 2014-2015 would occur under +2 °C perturbed climate conditions. We computed snow water storage (basin-wide and across elevations) and the ratio of snow water equivalent to cumulative precipitation (across elevations) for the McKenzie River basin (3041 km2), a major tributary to the Willamette River in Oregon, USA. We applied these computations to calculate the occurrence probability for similarly low snow water storage under climate warming. Results suggest that, relative to +2 °C conditions, basin-wide snow water storage during winter 2013-2014 would be above average, while that of winter 2014-2015 would be far below average. Snow water storage on 1 April corresponds to a 42 % (2013-2014) and 92 % (2014-2015) probability of being met or exceeded in any given year. The second approach introduces the concept of snow analogs to improve the anticipatory capacity of climate change impacts on snow-derived water resources. The use of a spatial-probabilistic approach and snow analogs provide new methods of assessing basin-wide snow water storage in a non-stationary climate and are readily applicable in other snow-dominated watersheds.

Cleanup Verification Package for the 118-H-6:2, 105-H Reactor Ancillary Support Areas, Below-Grade Structures, and Underlying Soils; the 118-H-6:3, 105-H Reactor Fuel Storage Basin and Underlying Soils; The 118-H-6:3 Fuel Storage Basin Deep Zone Side Slope Soils; the 100-H-9, 100-H-10, and 100-H-13 French Drains; the 100-H-11 and 100-H-12 Expansion Box French Drains; and the 100-H-14 and 100-H-31 Surface Contamination Zones

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel

2006-06-29

This cleanup verification package documents completion of removal actions for the 105-H Reactor Ancillary Support Areas, Below-Grade Structures, and Underlying Soils (subsite 118-H-6:2); 105-H Reactor Fuel Storage Basin and Underlying Soils (118-H-6:3); and Fuel Storage Basin Deep Zone Side Slope Soils. This CVP also documents remedial actions for the following seven additional waste sties: French Drain C (100-H-9), French Drain D (100-H-10), Expansion Box French Drain E (100-H-11), Expansion Box French Drain F (100-H-12), French Drain G (100-H-13), Surface Contamination Zone H (100-H-14), and the Polychlorinated Biphenyl Surface Contamination Zone (100-H-31).

Long-term trend analysis of reservoir water quality and quantity at the landscape scale in two major river basins of Texas, USA.

USGS Publications Warehouse

Patino, Reynaldo; Asquith, William H.; VanLandeghem, Matthew M.; Dawson, D.

2016-01-01

Trends in water quality and quantity were assessed for 11 major reservoirs of the Brazos and Colorado river basins in the southern Great Plains (maximum period of record, 1965–2010). Water quality, major contributing-stream inflow, storage, local precipitation, and basin-wide total water withdrawals were analyzed. Inflow and storage decreased and total phosphorus increased in most reservoirs. The overall, warmest-, or coldest-monthly temperatures increased in 7 reservoirs, decreased in 1 reservoir, and did not significantly change in 3 reservoirs. The most common monotonic trend in salinity-related variables (specific conductance, chloride, sulfate) was one of no change, and when significant change occurred, it was inconsistent among reservoirs. No significant change was detected in monthly sums of local precipitation. Annual water withdrawals increased in both basins, but the increase was significant (P < 0.05) only in the Colorado River and marginally significant (P < 0.1) in the Brazos River. Salinity-related variables dominated spatial variability in water quality data due to the presence of high- and low-salinity reservoirs in both basins. These observations present a landscape in the Brazos and Colorado river basins where, in the last ∼40 years, reservoir inflow and storage generally decreased, eutrophication generally increased, and water temperature generally increased in at least 1 of 3 temperature indicators evaluated. Because local precipitation remained generally stable, observed reductions in reservoir inflow and storage during the study period may be attributable to other proximate factors, including increased water withdrawals (at least in the Colorado River basin) or decreased runoff from contributing watersheds.

Will building new reservoirs always help increase the water supply reliability? - insight from a modeling-based global study

NASA Astrophysics Data System (ADS)

Zhuang, Y.; Tian, F.; Yigzaw, W.; Hejazi, M. I.; Li, H. Y.; Turner, S. W. D.; Vernon, C. R.

2017-12-01

More and more reservoirs are being build or planned in order to help meet the increasing water demand all over the world. However, is building new reservoirs always helpful to water supply? To address this question, the river routing module of Global Change Assessment Model (GCAM) has been extended with a simple yet physical-based reservoir scheme accounting for irrigation, flood control and hydropower operations at each individual reservoir. The new GCAM river routing model has been applied over the global domain with the runoff inputs from the Variable Infiltration Capacity Model. The simulated streamflow is validated at 150 global river basins where the observed streamflow data are available. The model performance has been significantly improved at 77 basins and worsened at 35 basins. To facilitate the analysis of additional reservoir storage impacts at the basin level, a lumped version of GCAM reservoir model has been developed, representing a single lumped reservoir at each river basin which has the regulation capacity of all reservoir combined. A Sequent Peak Analysis is used to estimate how much additional reservoir storage is required to satisfy the current water demand. For basins with water deficit, the water supply reliability can be improved with additional storage. However, there is a threshold storage value at each basin beyond which the reliability stops increasing, suggesting that building new reservoirs will not help better relieve the water stress. Findings in the research can be helpful to the future planning and management of new reservoirs.

Demonstration of a conceptual model for using LiDAR to improve the estimation of floodwater mitigation potential of Prairie Pothole Region wetlands

USGS Publications Warehouse

Huang, S.; Young, Caitlin; Feng, M.; Heidemann, Hans Karl; Cushing, Matthew; Mushet, D.M.; Liu, S.

2011-01-01

Recent flood events in the Prairie Pothole Region of North America have stimulated interest in modeling water storage capacities of wetlands and their surrounding catchments to facilitate flood mitigation efforts. Accurate estimates of basin storage capacities have been hampered by a lack of high-resolution elevation data. In this paper, we developed a 0.5 m bare-earth model from Light Detection And Ranging (LiDAR) data and, in combination with National Wetlands Inventory data, delineated wetland catchments and their spilling points within a 196 km2 study area. We then calculated the maximum water storage capacity of individual basins and modeled the connectivity among these basins. When compared to field survey results, catchment and spilling point delineations from the LiDAR bare-earth model captured subtle landscape features very well. Of the 11 modeled spilling points, 10 matched field survey spilling points. The comparison between observed and modeled maximum water storage had an R2 of 0.87 with mean absolute error of 5564 m3. Since maximum water storage capacity of basins does not translate into floodwater regulation capability, we further developed a Basin Floodwater Regulation Index. Based upon this index, the absolute and relative water that could be held by wetlands over a landscape could be modeled. This conceptual model of floodwater downstream contribution was demonstrated with water level data from 17 May 2008.

Study on superstructure in ion co-doped BiFeO3 by using transmission electron microscopy

NASA Astrophysics Data System (ADS)

Pu, Shi-Zhou; Guo, Chao; Li, Mei-Ya; Chen, Zhen-Lian; Zou, Hua-Min

2015-04-01

La3+ and V5+ co-doped BiFeO3 ceramics are synthesized by rapid liquid sintering technique. The modulated structure in Bi0.85La0.15Fe0.97V0.03O3 is investigated by using transmission electron microscopy (TEM). Two kinds of superstructures are observed in the samples. One is the component modulated superstructure and twin-domain, which is generated by La3+ ordered substitution for Bi3+ and frequently appears. The chemical composition of the superstructure is explored by x-ray energy dispersive spectroscopy (EDS). The model of the ordered structure is proposed. Simulation based on the model is conducted. The second is the fluorite-type δ-Bi2O3 related superstructure. The relation between the ferroelectric property and the microstructure of the sample is also discussed. Project supported by the National Natural Science Foundation of China (Grant Nos. 51372174, 11074193, and 51132001) and the Fundamental Research Funds for the Central Universities.

Reversible near-infrared light directed reflection in a self-organized helical superstructure loaded with upconversion nanoparticles.

PubMed

Wang, Ling; Dong, Hao; Li, Yannian; Xue, Chenming; Sun, Ling-Dong; Yan, Chun-Hua; Li, Quan

2014-03-26

Adding external, dynamic control to self-organized superstructures with desired functionalities is an important leap necessary in leveraging the fascinating molecular systems for applications. Here, the new light-driven chiral molecular switch and upconversion nanoparticles, doped in a liquid crystal media, were able to self-organize into an optically tunable helical superstructure. The resulting nanoparticle impregnated helical superstructure was found to exhibit unprecedented reversible near-infrared (NIR) light-guided tunable behavior only by modulating the excitation power density of a continuous-wave NIR laser (980 nm). Upon irradiation by the NIR laser at the high power density, the reflection wavelength of the photonic superstructure red-shifted, whereas its reverse process occurred upon irradiation by the same laser but with the lower power density. Furthermore, reversible dynamic NIR-light-driven red, green, and blue reflections in a single thin film, achieved only by varying the power density of the NIR light, were for the first time demonstrated.

The Collyhurst Sandstone as a secondary storage unit for CCS in the East Irish Sea Basin (UK)

NASA Astrophysics Data System (ADS)

Gamboa, D.; Williams, J. D. O.; Kirk, K.; Gent, C. M. A.; Bentham, M.; Schofield, D. I.

2016-12-01

Carbon Capture and Storage (CCS) is key technology for low-carbon energy and industry. The UK hosts a large CO2 storage potential offshore with an estimated capacity of 78 Gt. The East Irish Sea Basin (EISB) is the key area for CCS in the western UK, with a CO2 storage potential of 1.7 Gt in hydrocarbon fields and in saline aquifers within the Triassic Sherwood Sandstone Formation. However, this theoretical storage capacity does not consider the secondary storage potential in the lower Permian Collyhurst Sandstone Formation. 3D seismic data were used to characterise the Collyhurst Sandstone Formation in the EISB. On the southern basin domain, numerous fault-bound blocks limit the lateral continuity of the sandstone strata, while on the northern domain the sandstones are intersected by less faults. The caprock for the Collyhurst sandstones is variable. The Manchester Marls predominate in the south, transitioning to the St. Bees evaporites towards the north. The evaporites in the EISB cause overburden faults to terminate or detach along Upper Permian strata, limiting the deformation of the underlying reservoir units. Five main storage closures have been identified in the Permian strata. In the southern and central area these are predominantly fault bounded, occurring at depths over 1000m. Despite the higher Collyhurst sandstone thickness in the southern IESB, the dolomitic nature of the caprock constitutes a storage risk in this area. Closures in the northern area are deeper (around 2000-2500m) and wider, reaching areas of 34Km2, and are overlain by evaporitic caprocks. The larger Collyhurst closures to the north underlie large Triassic fields with high storage potential. The spatial overlap favours storage plans including secondary storage units in the EISB. The results of this work also expand the understanding of prospective areas for CO2 sequestration in the East Irish Sea Basin in locations where the primary Sherwood Sandstone Formation is either too shallow, discontinuous or eroded.

Global Assessment of Exploitable Surface Reservoir Storage under Climate Change

NASA Astrophysics Data System (ADS)

Liu, L.; Parkinson, S.; Gidden, M.; Byers, E.; Satoh, Y.; Riahi, K.

2016-12-01

Surface water reservoirs provide us with reliable water supply systems, hydropower generation, flood control, and recreation services. Reliable reservoirs can be robust measures for water security and can help smooth out challenging seasonal variability of river flows. Yet, reservoirs also cause flow fragmentation in rivers and can lead to flooding of upstream areas, thereby displacing existing land-uses and ecosystems. The anticipated population growth, land use and climate change in many regions globally suggest a critical need to assess the potential for appropriate reservoir capacity that can balance rising demands with long-term water security. In this research, we assessed exploitable reservoir potential under climate change and human development constraints by deriving storage-yield relationships for 235 river basins globally. The storage-yield relationships map the amount of storage capacity required to meet a given water demand based on a 30-year inflow sequence. Runoff data is simulated with an ensemble of Global Hydrological Models (GHMs) for each of five bias-corrected general circulation models (GCMs) under four climate change pathways. These data are used to define future 30-year inflows in each river basin for time period between 2010 and 2080. The calculated capacity is then combined with geographical information of environmental and human development exclusion zones to further limit the storage capacity expansion potential in each basin. We investigated the reliability of reservoir potentials across different climate change scenarios and Shared Socioeconomic Pathways (SSPs) to identify river basins where reservoir expansion will be particularly challenging. Preliminary results suggest large disparities in reservoir potential across basins: some basins have already approached exploitable reserves, while some others display abundant potential. Exclusions zones pose significant impact on the amount of actual exploitable storage and firm yields worldwide: 30% of reservoir potential would be unavailable because of land occupation by environmental and human development. Results from this study will help decision makers to understand the reliability of infrastructure systems particularly sensitive to future water availability.

Ground-Water Storage Change and Land Subsidence in Tucson Basin and Avra Valley, Southeastern Arizona, 1998-2002

USGS Publications Warehouse

Pool, Donald R.; Anderson, Mark T.

2008-01-01

Gravity and land subsidence were measured annually at wells and benchmarks within two networks in Tucson Basin and Avra Valley from 1998 to 2002. Both networks are within the Tucson Active Management Area. Annual estimates of ground-water storage change, ground-water budgets, and land subsidence were made based on the data. Additionally, estimates of specific yield were made at wells within the monitored region. Increases in gravity and water-level rises followed above-average natural recharge during winter 1998 in Tucson Basin. Overall declining gravity and water-level trends from 1999 to 2002 in Tucson Basin reflected general declining ground-water storage conditions and redistribution of the recent recharge throughout a larger region of the aquifer. The volume of stored ground-water in the monitored portion of Tucson Basin increased 200,000 acre-feet from December 1997 to February 1999; however, thereafter an imbalance in ground-water pumpage in excess of recharge led to a net storage loss for the monitoring period by February 2002. Ground-water storage in Avra Valley increased 70,000 acre-feet during the monitoring period, largely as a result of artificial and incidental recharge in the monitored region. The water-budget for the combined monitored regions of Tucson Basin and Avra Valley was dominated by about 460,000 acre-feet of recharge during 1998 followed by an average-annual recharge rate of about 80,000 acre-feet per year from 1999 to 2002. Above-average recharge during winter 1998, followed by average-annual deficit conditions, resulted in an overall balanced water budget for the monitored period. Monitored variations in storage compared well with simulated average-annual conditions, except for above-average recharge from 1998 to 1999. The difference in observed and simulated conditions indicate that ground-water flow models can be improved by including climate-related variations in recharge rates rather than invariable rates of average-annual recharge. Observed land-subsidence during the monitoring period was less than 1 inch except in the central part of Tucson Basin where land subsidence was about 2-3 inches. Correlations of gravity-based storage and water-level change at 37 wells were variable and illustrate the complex nature of the aquifer system. Storage and water-level variations were insufficient to estimate specific yield at many wells. Correlations at several wells were poor, inverse, or resulted in unreasonably large values of specific yield. Causes of anomalously correlated gravity and water levels include significant storage change in thick unsaturated zones, especially near major ephemeral channels, and multiple aquifers that are poorly connected hydraulically. Good correlation of storage and water-level change at 10 wells that were not near major streams where significant changes in unsaturated zone storage occur resulted in an average specific-yield value of 0.27.

Gas nanobubbles and aqueous nanostructures: the crucial role of dynamization.

PubMed

Demangeat, Jean-Louis

2015-04-01

Nanobubbles (NBs) have been a subject of intensive research over the past decade. Their peculiar characteristics, including extremely low buoyancy, longevity, enhanced solubility of oxygen in water, zeta potentials and burst during collapse, have led to many applications in the industrial, biological and medical fields. NBs may form spontaneously from dissolved gas but the process is greatly enhanced by gas supersaturation and mechanical actions such as dynamization. Therefore, the formation of NBs during the preparation of homeopathic dilutions under atmospheric pressure cannot be ignored. I suggested in 2009 the involvement of NBs in nanometric superstructures revealed in high dilutions using NMR relaxation. These superstructures seemed to increase in size with dilution, well into the ultramolecular range (>12c). I report here new experiments that confirm the involvement of NBs and prove the crucial role of dynamization to create superstructures specific to the solute. A second dynamization was shown to enhance or regenerate these superstructures. I postulate that superstructures result from a nucleation process of NBs around the solute, with shells of highly organized water (with ions and silicates if any) which protect the solute against out-diffusion and behave as nucleation centres for further dilution steps. The sampling tip may play an active role by catching the superstructures and thus carry the encaged solute across the dilution range, possibly up to the ultramolecular range. The superstructures were not observed at low dilution, probably because of a destructuring of the solvent by the solute and/or of an inadequate gas/solute ratio. Copyright © 2015 The Faculty of Homeopathy. Published by Elsevier Ltd. All rights reserved.

Studies on growth mechanism and physical properties of hydrothermally synthesized CdS with novel hierarchical superstructures and their photocatalytic activity

NASA Astrophysics Data System (ADS)

Jamble, Shweta N.; Ghoderao, Karuna P.; Kale, Rohidas B.

2018-03-01

A simple, facile and organic-free hydrothermal method was utilized to synthesize cadmium sulfide (CdS) superstructures. The cadmium chloride and thiourea used as a Cd2+ and S2- ion sources for the growth of CdS superstructures. The reaction was carried out at different time and temperatures. The X-ray diffraction studies confirmed that the obtained products were highly crystalline with hexagonal phase. Scanning and transmission electron microscopy images reveal a monodisperse dendrite-like CdS superstructure. It consisted of a central long trunk with secondary branches, lying parallel to each other and making a certain angle with the central trunk, and small ternary branches grew out of the secondary branches. The selected area electron diffraction altogether with high-resolution electron microscopy patterns depicted that the leaves of dendrite were single crystalline in nature and preferentially grown along (111) direction. The UV-vis absorbance and photoluminescence study illustrated that the hierarchically grown CdS superstructures revealed the good quality of optical properties. A probable growth mechanism for the formation of CdS dendritic superstructures was also discussed and demonstrated by experimental results. The photocatalytic activity of CdS superstructures was studied with the photodegradation of methylene blue (MB) in an aqueous solution, under the visible light irradiation. The results showed that the degradation ratio of MB could reach 94.93% in 220 min. Based on the results, the possible mechanism of the photocatalytic reaction of MB with CdS dendrites is useful for visible light photocatalytic applications.

Morphology and Structural Properties of Novel Short Linear Glucan/Protein Hybrid Nanoparticles and Their Influence on the Rheological Properties of Starch Gel.

PubMed

Li, Xiaojing; Ji, Na; Li, Man; Zhang, Shuangling; Xiong, Liu; Sun, Qingjie

2017-09-13

Starch nanoparticles were potential texture modifiers. However, they have strong tendency to aggregate and poor water dispersibility, which limited their application. The interaction between glucan (prepared from starch by enzymatic modification) and protein could significantly improve the dispersity of starch nanoparticles and, thus, enhance the rheological properties of food gels. In this work, glucan/protein hybrid nanoparticles were successfully developed for the first time using short linear glucan (SLG) and edible proteins [soy protein isolate (SPI), rice protein (RP), and whey protein isolate (WPI)]. The results showed that the SLG/SPI hybrid nanoparticles exhibited hollow structures, of which the smallest size was approximately 10-20 nm when the SLG/SPI ratio was 10:5. In contrast, SLG/RP nanoparticles displayed flower-like superstructures, and SLG/WPI nanoparticles presented stacked lamellar nanostructures with a width of 5-10 nm and a length of 50-70 nm. In comparison to bare SLG nanoparticles, SLG/SPI and SLG/WPI hybrid nanoparticles had higher melting temperatures. The addition of all nanoparticles greatly increased the storage modulus of corn starch gels and decreased loss tangent values. Importantly, the G' value of starch gels increased by 567% with the addition of flower-like SLG/RP superstructures.

Geologic framework for the national assessment of carbon dioxide storage resources: Alaska North Slope and Kandik Basin, Alaska: Chapter I in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Craddock, William H.; Buursink, Marc L.; Covault, Jacob A.; Brennan, Sean T.; Doolan, Colin A.; Drake II, Ronald M.; Merrill, Matthew D.; Roberts-Ashby, Tina L.; Slucher, Ernie R.; Warwick, Peter D.; Blondes, Madalyn S.; Freeman, P.A.; Cahan, Steven N.; DeVera, Christina A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2014-01-01

For each SAU in both of the basins, we discuss the areal distribution of suitable CO2 sequestration reservoir rock. We also characterize the overlying sealing unit and describe the geologic characteristics that influence the potential CO2 storage volume and reservoir performance. These characteristics include reservoir depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this report, the geologic information included herein was employed to calculate the potential storage volume in the various SAUs. Lastly, in this report, we present the rationale for not conducting assessment work in fifteen sedimentary basins distributed across the Alaskan interior and within Alaskan State waters.

A technique for estimating time of concentration and storage coefficient values for Illinois streams

USGS Publications Warehouse

Graf, Julia B.; Garklavs, George; Oberg, Kevin A.

1982-01-01

Values of the unit hydrograph parameters time of concentration (TC) and storage coefficient (R) can be estimated for streams in Illinois by a two-step technique developed from data for 98 gaged basins in the State. The sum of TC and R is related to stream length (L) and main channel slope (S) by the relation (TC + R)e = 35.2L0.39S-0.78. The variable R/(TC + R) is not significantly correlated with drainage area, slope, or length, but does exhibit a regional trend. Regional values of R/(TC + R) are used with the computed values of (TC + R)e to solve for estimated values of time of concentration (TCe) and storage coefficient (Re). The use of the variable R/(TC + R) is thought to account for variations in unit hydrograph parameters caused by physiographic variables such as basin topography, flood-plain development, and basin storage characteristics. (USGS)

K Basins sludge removal temporary sludge storage tank system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mclean, M.A.

1997-06-12

Shipment of sludge from the K Basins to a disposal site is now targeted for August 2000. The current path forward for sludge disposal is shipment to Tank AW-105 in the Tank Waste Remediation System (TWRS). Significant issues of the feasibility of this path exist primarily due to criticality concerns and the presence of polychlorinated biphenyls (PCBS) in the sludge at levels that trigger regulation under the Toxic Substance Control Act. Introduction of PCBs into the TWRS processes could potentially involve significant design and operational impacts to both the Spent Nuclear Fuel and TWRS projects if technical and regulatory issuesmore » related to PCB treatment cannot be satisfactorily resolved. Concerns of meeting the TWRS acceptance criteria have evolved such that new storage tanks for the K Basins sludge may be the best option for storage prior to vitrification of the sludge. A reconunendation for the final disposition of the sludge is scheduled for June 30, 1997. To support this decision process, this project was developed. This project provides a preconceptual design package including preconceptual designs and cost estimates for the temporary sludge storage tanks. Development of cost estimates for the design and construction of sludge storage systems is required to help evaluate a recommendation for the final disposition of the K Basin sludge.« less

Geologic framework for the national assessment of carbon dioxide storage resources—Southern Rocky Mountain Basins: Chapter M in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Merrill, Matthew D.; Drake, Ronald M.; Buursink, Marc L.; Craddock, William H.; East, Joseph A.; Slucher, Ernie R.; Warwick, Peter D.; Brennan, Sean T.; Blondes, Madalyn S.; Freeman, Philip A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2016-06-02

The U.S. Geological Survey has completed an assessment of the potential geologic carbon dioxide storage resources in the onshore areas of the United States. To provide geological context and input data sources for the resources numbers, framework documents are being prepared for all areas that were investigated as part of the national assessment. This report, chapter M, is the geologic framework document for the Uinta and Piceance, San Juan, Paradox, Raton, Eastern Great, and Black Mesa Basins, and subbasins therein of Arizona, Colorado, Idaho, Nevada, New Mexico, and Utah. In addition to a summary of the geology and petroleum resources of studied basins, the individual storage assessment units (SAUs) within the basins are described and explanations for their selection are presented. Although appendixes in the national assessment publications include the input values used to calculate the available storage resource, this framework document provides only the context and source of the input values selected by the assessment geologists. Spatial-data files of the boundaries for the SAUs, and the well-penetration density of known well bores that penetrate the SAU seal, are available for download with the release of this report.

Hanford Spent Nuclear Fuel Project recommended path forward

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fulton, J.C.

The Spent Nuclear Fuel Project (the Project), in conjunction with the U.S. Department of Energy-commissioned Independent Technical Assessment (ITA) team, has developed engineered alternatives for expedited removal of spent nuclear fuel, including sludge, from the K Basins at Hanford. These alternatives, along with a foreign processing alternative offered by British Nuclear Fuels Limited (BNFL), were extensively reviewed and evaluated. Based on these evaluations, a Westinghouse Hanford Company (WHC) Recommended Path Forward for K Basins spent nuclear fuel has been developed and is presented in Volume I of this document. The recommendation constitutes an aggressive series of projects to construct andmore » operate systems and facilities to safely retrieve, package, transport, process, and store K Basins fuel and sludge. The overall processing and storage scheme is based on the ITA team`s proposed passivation and vault storage process. A dual purpose staging and vault storage facility provides an innovative feature which allows accelerated removal of fuel and sludge from the basins and minimizes programmatic risks beyond any of the originally proposed alternatives. The projects fit within a regulatory and National Environmental Policy Act (NEPA) overlay which mandates a two-phased approach to construction and operation of the needed facilities. The two-phase strategy packages and moves K Basins fuel and sludge to a newly constructed Staging and Storage Facility by the year 2000 where it is staged for processing. When an adjoining facility is constructed, the fuel is cycled through a stabilization process and returned to the Staging and Storage Facility for dry interim (40-year) storage. The estimated total expenditure for this Recommended Path Forward, including necessary new construction, operations, and deactivation of Project facilities through 2012, is approximately $1,150 million (unescalated).« less

76 FR 5586 - Williston Basin Interstate Pipeline Company; Notice of Request Under Blanket Authorization

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-01

... Commission's Regulations under the Natural Gas Act (NGA) as amended, for the construction and operation of... Baker Storage Reservoir. Williston Basin also adds two natural gas-fueled units, rated at 2,370 hp each... Storage Reservoir by 35,000 Mcf/day and provide 7,000 Mcf/day of incremental transportation transfer...

Characterizing the Sensitivity of Groundwater Storage to Climate variation in the Indus Basin

NASA Astrophysics Data System (ADS)

Huang, L.; Sabo, J. L.

2017-12-01

Indus Basin represents an extensive groundwater aquifer facing the challenge of effective management of limited water resources. Groundwater storage is one of the most important variables of water balance, yet its sensitivity to climate change has rarely been explored. To better estimate present and future groundwater storage and its sensitivity to climate change in the Indus Basin, we analyzed groundwater recharge/discharge and their historical evolution in this basin. Several methods are applied to specify the aquifer system including: water level change and storativity estimates, gravity estimates (GRACE), flow model (MODFLOW), water budget analysis and extrapolation. In addition, all of the socioeconomic and engineering aspects are represented in the hydrological system through the change of temporal and spatial distributions of recharge and discharge (e.g., land use, crop structure, water allocation, etc.). Our results demonstrate that the direct impacts of climate change will result in unevenly distributed but increasing groundwater storage in the short term through groundwater recharge. In contrast, long term groundwater storage will decrease as a result of combined indirect and direct impacts of climate change (e.g. recharge/discharge and human activities). The sensitivity of groundwater storage to climate variation is characterized by topography, aquifer specifics and land use. Furthermore, by comparing possible outcomes of different human interventions scenarios, our study reveals human activities play an important role in affecting the sensitivity of groundwater storage to climate variation. Over all, this study presents the feasibility and value of using integrated hydrological methods to support sustainable water resource management under climate change.

Necessary storage as a signature of discharge variability: towards global maps

NASA Astrophysics Data System (ADS)

Takeuchi, Kuniyoshi; Masood, Muhammad

2017-09-01

This paper proposes the use of necessary storage to smooth out discharge variability to meet a discharge target as a signature of discharge variability in time. Such a signature has a distinct advantage over other statistical indicators such as standard deviation (SD) or coefficient of variation (CV) as it expresses hydrological variability in human terms, which directly indicates the difficulty and ease of managing discharge variation for water resource management. The signature is presented in the form of geographical distribution, in terms of both necessary storage (km3) and normalized necessary storage (months), and is related to the basin characteristics of hydrological heterogeneity. The signature is analyzed in different basins considering the Hurst equation of range as a reference. The slope of such a relation and the scatter of departures from the average relation are analyzed in terms of their relationship with basin characteristics. As a method of calculating necessary storage, the flood duration curve (FDC) and drought duration curve (DDC) methods are employed in view of their relative advantage over other methods to repeat the analysis over many grid points. The Ganges-Brahmaputra-Meghna (GBM) basin is selected as the case study and the BTOPMC hydrological model with Water and Global Change (WATCH) Forcing Data (WFD) is used for estimating FDC and DDC. It is concluded that the necessary storage serves as a useful signature of discharge variability, and its analysis could be extended to the entire globe and in this way seek new insights into hydrological variability in the storage domain at a larger range of scales.

Recent changes in terrestrial water storage in the Upper Nile Basin: an evaluation of commonly used gridded GRACE products

NASA Astrophysics Data System (ADS)

Shamsudduha, Mohammad; Taylor, Richard G.; Jones, Darren; Longuevergne, Laurent; Owor, Michael; Tindimugaya, Callist

2017-09-01

GRACE (Gravity Recovery and Climate Experiment) satellite data monitor large-scale changes in total terrestrial water storage (ΔTWS), providing an invaluable tool where in situ observations are limited. Substantial uncertainty remains, however, in the amplitude of GRACE gravity signals and the disaggregation of TWS into individual terrestrial water stores (e.g. groundwater storage). Here, we test the phase and amplitude of three GRACE ΔTWS signals from five commonly used gridded products (i.e. NASA's GRCTellus: CSR, JPL, GFZ; JPL-Mascons; GRGS GRACE) using in situ data and modelled soil moisture from the Global Land Data Assimilation System (GLDAS) in two sub-basins (LVB: Lake Victoria Basin; LKB: Lake Kyoga Basin) of the Upper Nile Basin. The analysis extends from January 2003 to December 2012, but focuses on a large and accurately observed reduction in ΔTWS of 83 km3 from 2003 to 2006 in the Lake Victoria Basin. We reveal substantial variability in current GRACE products to quantify the reduction of ΔTWS in Lake Victoria that ranges from 80 km3 (JPL-Mascons) to 69 and 31 km3 for GRGS and GRCTellus respectively. Representation of the phase in TWS in the Upper Nile Basin by GRACE products varies but is generally robust with GRGS, JPL-Mascons, and GRCTellus (ensemble mean of CSR, JPL, and GFZ time-series data), explaining 90, 84, and 75 % of the variance respectively in "in situ" or "bottom-up" ΔTWS in the LVB. Resolution of changes in groundwater storage (ΔGWS) from GRACE ΔTWS is greatly constrained by both uncertainty in changes in soil-moisture storage (ΔSMS) modelled by GLDAS LSMs (CLM, NOAH, VIC) and the low annual amplitudes in ΔGWS (e.g. 1.8-4.9 cm) observed in deeply weathered crystalline rocks underlying the Upper Nile Basin. Our study highlights the substantial uncertainty in the amplitude of ΔTWS that can result from different data-processing strategies in commonly used, gridded GRACE products; this uncertainty is disregarded in analyses of ΔTWS and individual stores applying a single GRACE product.

Estimation of Groundwater Storage Change via GRACE over a Small Watershed - A Case Study over Konya Closed Basin

NASA Astrophysics Data System (ADS)

Karasu, İ. G.; Yilmaz, K. K.; Yilmaz, M. T.

2017-12-01

Estimation of the groundwater storage change and its interannual variability is critical over Konya Closed Basin which has excessive agricultural production. The annual total precipitation falling over the region is not sufficient to compensate the agricultural irrigation needs of the region. This leds many to use groundwater as the primary water resource, which resulted in significant drop in the groundwater levels. Accordingly, monitoring of the groundwater change is critical for sustainable water resources management. Gravity Recovery and Climate Experiment (GRACE) observations and Global Land Data Assimilation System (GLDAS) have been succesfully used over many locations to monitor the change in the groundwater storages. In this study, GRACE-derived terrestrial water storage estimates and GLDAS model soil moisture, canopy water, snow water equivalent and surface runoff simulations are used to retrieve the change in the groundwater storage over Konya Closed Basin streching over 50,000 km2 area. Initial comparisons show the declining trend in GRACE and GLDAS combined groundwater storage change estimates between 2002 and 2016 are consistent with the actual groundwater level change observed at ground stations. Even though many studies recommend GRACE observations to be used over regions larger than 100,000 km2 - 200,000 km2 area, results show GRACE remote sensing and GLDAS modeled groundwater change information are skillful to monitor the large mass changes occured as a result of the excessive groundwater exploitation over Konya Closed Basin with 50,000 km2 area.

Isometric Scaling in Developing Long Bones Is Achieved by an Optimal Epiphyseal Growth Balance

PubMed Central

Stern, Tomer; Aviram, Rona; Rot, Chagai; Galili, Tal; Sharir, Amnon; Kalish Achrai, Noga; Keller, Yosi; Shahar, Ron; Zelzer, Elazar

2015-01-01

One of the major challenges that developing organs face is scaling, that is, the adjustment of physical proportions during the massive increase in size. Although organ scaling is fundamental for development and function, little is known about the mechanisms that regulate it. Bone superstructures are projections that typically serve for tendon and ligament insertion or articulation and, therefore, their position along the bone is crucial for musculoskeletal functionality. As bones are rigid structures that elongate only from their ends, it is unclear how superstructure positions are regulated during growth to end up in the right locations. Here, we document the process of longitudinal scaling in developing mouse long bones and uncover the mechanism that regulates it. To that end, we performed a computational analysis of hundreds of three-dimensional micro-CT images, using a newly developed method for recovering the morphogenetic sequence of developing bones. Strikingly, analysis revealed that the relative position of all superstructures along the bone is highly preserved during more than a 5-fold increase in length, indicating isometric scaling. It has been suggested that during development, bone superstructures are continuously reconstructed and relocated along the shaft, a process known as drift. Surprisingly, our results showed that most superstructures did not drift at all. Instead, we identified a novel mechanism for bone scaling, whereby each bone exhibits a specific and unique balance between proximal and distal growth rates, which accurately maintains the relative position of its superstructures. Moreover, we show mathematically that this mechanism minimizes the cumulative drift of all superstructures, thereby optimizing the scaling process. Our study reveals a general mechanism for the scaling of developing bones. More broadly, these findings suggest an evolutionary mechanism that facilitates variability in bone morphology by controlling the activity of individual epiphyseal plates. PMID:26241802

Deriving Scaling Factors Using a Global Hydrological Model to Restore GRACE Total Water Storage Changes for China's Yangtze River Basin

NASA Technical Reports Server (NTRS)

Long, Di; Yang, Yuting; Yoshihide, Wada; Hong, Yang; Liang, Wei; Chen, Yaning; Yong, Bin; Hou, Aizhong; Wei, Jiangfeng; Chen, Lu

2015-01-01

This study used a global hydrological model (GHM), PCR-GLOBWB, which simulates surface water storage changes, natural and human induced groundwater storage changes, and the interactions between surface water and subsurface water, to generate scaling factors by mimicking low-pass filtering of GRACE signals. Signal losses in GRACE data were subsequently restored by the scaling factors from PCR-GLOBWB. Results indicate greater spatial heterogeneity in scaling factor from PCR-GLOBWB and CLM4.0 than that from GLDAS-1 Noah due to comprehensive simulation of surface and subsurface water storage changes for PCR-GLOBWB and CLM4.0. Filtered GRACE total water storage (TWS) changes applied with PCR-GLOBWB scaling factors show closer agreement with water budget estimates of TWS changes than those with scaling factors from other land surface models (LSMs) in China's Yangtze River basin. Results of this study develop a further understanding of the behavior of scaling factors from different LSMs or GHMs over hydrologically complex basins, and could be valuable in providing more accurate TWS changes for hydrological applications (e.g., monitoring drought and groundwater storage depletion) over regions where human-induced interactions between surface water and subsurface water are intensive.

Quantifying Changes in Accessible Water in the Colorado River Basin

NASA Astrophysics Data System (ADS)

Castle, S.; Thomas, B.; Reager, J. T.; Swenson, S. C.; Famiglietti, J. S.

2013-12-01

The Colorado River Basin (CRB) in the western United States is heavily managed yet remains one of the most over-allocated rivers in the world providing water across seven US states and Mexico. Future water management strategies in the CRB have employed land surface models to forecast discharges; such approaches have focused on discharge estimates to meet allocation requirements yet ignore groundwater abstractions to meet water demands. In this analysis, we illustrate the impact of changes in accessible water, which we define as the conjunctive use of both surface water reservoir storage and groundwater storage, using remote sensing observations to explore sustainable water management strategies in the CRB. We employ high resolution Landsat Thematic Mapper satellite data to detect changes in reservoir storage in the two largest reservoirs within the CRB, Lakes Mead and Powell, and the Gravity Recovery and Climate Experiment (GRACE) terrestrial water storage anomalies to isolate changes in basin-wide groundwater storage in the Upper and Lower CRB from October 2003 to December 2012. Our approach quantifies reservoir and groundwater storage within the CRB using remote sensing to provide new information to water managers to sustainably and conjunctively manage accessible water.

11. The work area of a typical fuel storage and ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. The work area of a typical fuel storage and transfer basin. The wooden floor was built over the 20-foot deep water-filled basin. Buckets filled with irradiated fuel of dummy slugs in the floor and were hung on trolleys attached to the monorail tracks suspended from the ceiling. 85-H807 - B Reactor, Richland, Benton County, WA

Enhanced thermophysical properties via PAO superstructure

NASA Astrophysics Data System (ADS)

Pournorouz, Zahra; Mostafavi, Amirhossein; Pinto, Aditya; Bokka, Apparao; Jeon, Junha; Shin, Donghyun

2017-01-01

For the last few years, molten salt nanomaterials have attracted many scientists for their enhanced specific heat by doping a minute concentration of nanoparticles (up to 1% by weight). Likewise, enhancing the specific heat of liquid media is important in many aspects of engineering such as engine oil, coolant, and lubricant. However, such enhancement in specific heat was only observed for molten salts, yet other engineering fluids such as water, ethylene glycol, and oil have shown a decrease of specific heat with doped nanoparticles. Recent studies have shown that the observed specific heat enhancement resulted from unique nanostructures that were formed by molten salt molecules when interacting with nanoparticles. Thus, such enhancement in specific heat is only possible for molten salts because other fluids may not naturally form such nanostructures. In this study, we hypothesized such nanostructures can be mimicked through in situ formation of fabricated nano-additives, which are putative nanoparticles coated with useful organic materials (e.g., polar-group-ended organic molecules) leading to superstructures, and thus can be directly used for other engineering fluids. We first applied this approach to polyalphaolefin (PAO). A differential scanning calorimeter (DSC), a rheometer, and a customized setup were employed to characterize the heat capacity, viscosity, and thermal conductivity of PAO and PAO with fabricated nano-additives. Results showed 44.5% enhanced heat capacity and 19.8 and 22.98% enhancement for thermal conductivity and viscosity, respectively, by an addition of only 2% of fabricated nanostructures in comparison with pure PAO. Moreover, a partial melting of the polar-group-ended organic molecules was observed in the first thermal cycle and the peak disappeared in the following cycles. This indicates that the in situ formation of fabricated nano-additives spontaneously occurs in the thermal cycle to form nanostructures. Figure of merit analyses have been performed for the PAO superstructure to evaluate its performance for heat storage and transfer media.

Enhanced thermophysical properties via PAO superstructure.

PubMed

Pournorouz, Zahra; Mostafavi, Amirhossein; Pinto, Aditya; Bokka, Apparao; Jeon, Junha; Shin, Donghyun

2017-12-01

For the last few years, molten salt nanomaterials have attracted many scientists for their enhanced specific heat by doping a minute concentration of nanoparticles (up to 1% by weight). Likewise, enhancing the specific heat of liquid media is important in many aspects of engineering such as engine oil, coolant, and lubricant. However, such enhancement in specific heat was only observed for molten salts, yet other engineering fluids such as water, ethylene glycol, and oil have shown a decrease of specific heat with doped nanoparticles. Recent studies have shown that the observed specific heat enhancement resulted from unique nanostructures that were formed by molten salt molecules when interacting with nanoparticles. Thus, such enhancement in specific heat is only possible for molten salts because other fluids may not naturally form such nanostructures. In this study, we hypothesized such nanostructures can be mimicked through in situ formation of fabricated nano-additives, which are putative nanoparticles coated with useful organic materials (e.g., polar-group-ended organic molecules) leading to superstructures, and thus can be directly used for other engineering fluids. We first applied this approach to polyalphaolefin (PAO). A differential scanning calorimeter (DSC), a rheometer, and a customized setup were employed to characterize the heat capacity, viscosity, and thermal conductivity of PAO and PAO with fabricated nano-additives. Results showed 44.5% enhanced heat capacity and 19.8 and 22.98% enhancement for thermal conductivity and viscosity, respectively, by an addition of only 2% of fabricated nanostructures in comparison with pure PAO. Moreover, a partial melting of the polar-group-ended organic molecules was observed in the first thermal cycle and the peak disappeared in the following cycles. This indicates that the in situ formation of fabricated nano-additives spontaneously occurs in the thermal cycle to form nanostructures. Figure of merit analyses have been performed for the PAO superstructure to evaluate its performance for heat storage and transfer media.

Assimilation of Terrestrial Water Storage from GRACE in a Snow-Dominated Basin

NASA Technical Reports Server (NTRS)

Forman, Barton A.; Reichle, R. H.; Rodell, M.

2011-01-01

Terrestrial water storage (TWS) information derived from Gravity Recovery and Climate Experiment (GRACE) measurements is assimilated into a land surface model over the Mackenzie River basin located in northwest Canada. Assimilation is conducted using an ensemble Kalman smoother (EnKS). Model estimates with and without assimilation are compared against independent observational data sets of snow water equivalent (SWE) and runoff. For SWE, modest improvements in mean difference (MD) and root mean squared difference (RMSD) are achieved as a result of the assimilation. No significant differences in temporal correlations of SWE resulted. Runoff statistics of MD remain relatively unchanged while RMSD statistics, in general, are improved in most of the sub-basins. Temporal correlations are degraded within the most upstream sub-basin, but are, in general, improved at the downstream locations, which are more representative of an integrated basin response. GRACE assimilation using an EnKS offers improvements in hydrologic state/flux estimation, though comparisons with observed runoff would be enhanced by the use of river routing and lake storage routines within the prognostic land surface model. Further, GRACE hydrology products would benefit from the inclusion of better constrained models of post-glacial rebound, which significantly affects GRACE estimates of interannual hydrologic variability in the Mackenzie River basin.

Glacier mass budget measurements by hydrologic means

USGS Publications Warehouse

Tangborn, Wendell V.

1966-01-01

Ice storage changes for the South Cascade Glacier drainage basin were determined for the 1957–1964 period using basin runoff and precipitation measurements. Measurements indicate that evaporation and condensation are negligible compared with the large runoff and precipitation values. Runoff, measured by a stream discharge station, averaged 4.04 m/yr; precipitation, determined by snow accumulation measurements at a central point on the glacier and by storage gages, averaged 3.82 m/yr, resulting in a basin net loss of about 0.22 m/yr. During the same period, South Cascade Glacier net budgets were determined by ablation stakes, snow density-depth profiles, and maps. The average glacier net budget for the period was −0.61sol;yr of water. This amount is equivalent to −0.26 m of water when averaged over the drainage basin (43% glacier-covered), which is in fair agreement with the net storage change measured by hydrologic methods. Agreement between the two methods for individual years is slightly less perfect.

Geologic framework for the national assessment of carbon dioxide storage resources: Williston Basin, Central Montana Basins, and Montana Thrust Belt study areas: Chapter J in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Buursink, Marc L.; Merrill, Matthew D.; Craddock, William H.; Roberts-Ashby, Tina L.; Brennan, Sean T.; Blondes, Madalyn S.; Freeman, P.A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2014-01-01

Figures in this report show the study area boundaries along with the SAU extent and cell maps of well penetrations through sealing units into the top of the storage formations. The USGS does not necessarily know the location of all wells and cannot guarantee the full extent of drilling through specific formations in any given cell shown on the cell maps.

Impact of surface water withdrawals on water storage variations under a changing climate

NASA Astrophysics Data System (ADS)

Ashraf, B.; AghaKouchak, A.; Mousavi Baygi, M.; Alizadeh, A.; Moftakhari, H.; Miao, C.; Arab, D. R.; Anjileli, H.

2016-12-01

Quantitative evaluation of water storage variations in large river basins is an important element of water management, especially in a climate change. In addition, human water use has developed into another strong driver of water storage changes especially in densely populated semiarid and arid areas. In this study, we estimate the normalized human outflow of the thirty main basins in Iran during the past three decades. Then, we investigate the individual and combined effects of climate variability and human water withdrawals on surface water storage in the 21st century in four major basins (Urmia, Karkheh, Karun and Jarrahi) located in semi-arid areas of Iran. These basins are selected because they experienced medium to high human-induced water demand in last decades. We use bias-corrected historical simulations and future projections from 26 General Circulation Models (GCMs) and three climate change scenarios RCP2.6, RCP4.5, RCP8.5). The results show that humans have strongly impacted the water balances of most basins in Iran, dominating potential climate change impacts in the historical period. In fact, the main reason for water scarcity in these regions appears to be due to the increased anthropogenic water demand resulting from substantial socio-economic growth in the past three decades. Furthermore, by the end of the 21st century, the compounding effects of increased irrigation water demand and precipitation variability may lead to severe local water scarcity in these basins. Our study highlights the need to improve our understanding of the hydrologic responses to anthropogenic perturbations, and local water resource management decisions.

Mythical systems: mathematic and logical theory

NASA Astrophysics Data System (ADS)

Nescolarde-Selva, J.; Usó-Doménech, J. L.; Lloret-Climent, M.

2015-01-01

The process of elaboration of the symbolic universe leads to exciting insights regarding the search for human emotional security. The symbols end up as explanatory axes of universal reality and on them are constructed myths that form a superstructure for belief systems. Human society is a multi-level system with a material structure (society), an ideological superstructure (belief systems, values, etc.) and a super superstructure with two parts: mythical (origin and justification) and utopic (final goal). All mythical belief systems have a numinous-religious nature.

22. Top 30/5. Plan of superstructure elevations. Wyoming Valley ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. Top 30/5. Plan of superstructure elevations. - Wyoming Valley Flood Control System, Woodward Pumping Station, East of Toby Creek crossing by Erie-Lackawanna Railroad, Edwardsville, Luzerne County, PA

23. Top 30/6. Plan of superstructure sections. Wyoming Valley ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

23. Top 30/6. Plan of superstructure sections. - Wyoming Valley Flood Control System, Woodward Pumping Station, East of Toby Creek crossing by Erie-Lackawanna Railroad, Edwardsville, Luzerne County, PA

24. Top 30/7. Plan of superstructure details. Wyoming Valley ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

24. Top 30/7. Plan of superstructure details. - Wyoming Valley Flood Control System, Woodward Pumping Station, East of Toby Creek crossing by Erie-Lackawanna Railroad, Edwardsville, Luzerne County, PA

High resolution modeling of reservoir storage and extent dynamics at the continental scale

NASA Astrophysics Data System (ADS)

Shin, S.; Pokhrel, Y. N.

2017-12-01

Over the past decade, significant progress has been made in developing reservoir schemes in large scale hydrological models to better simulate hydrological fluxes and storages in highly managed river basins. These schemes have been successfully used to study the impact of reservoir operation on global river basins. However, improvements in the existing schemes are needed for hydrological fluxes and storages, especially at the spatial resolution to be used in hyper-resolution hydrological modeling. In this study, we developed a reservoir routing scheme with explicit representation of reservoir storage and extent at the grid scale of 5km or less. Instead of setting reservoir area to a fixed value or diagnosing it using the area-storage equation, which is a commonly used approach in the existing reservoir schemes, we explicitly simulate the inundated storage and area for all grid cells that are within the reservoir extent. This approach enables a better simulation of river-floodplain-reservoir storage by considering both the natural flood and man-made reservoir storage. Results of the seasonal dynamics of reservoir storage, river discharge at the downstream of dams, and the reservoir inundation extent are evaluated with various datasets from ground-observations and satellite measurements. The new model captures the dynamics of these variables with a good accuracy for most of the large reservoirs in the western United States. It is expected that the incorporation of the newly developed reservoir scheme in large-scale land surface models (LSMs) will lead to improved simulation of river flow and terrestrial water storage in highly managed river basins.

Out-of-plane (SH) soil-structure interaction: a shear wall with rigid and flexible ring foundation

NASA Astrophysics Data System (ADS)

Le, Thang; Lee, Vincent W.; Luo, Hao

2016-02-01

Soil-structure interaction (SSI) of a building and shear wall above a foundation in an elastic half-space has long been an important research subject for earthquake engineers and strong-motion seismologists. Numerous papers have been published since the early 1970s; however, very few of these papers have analytic closed-form solutions available. The soil-structure interaction problem is one of the most classic problems connecting the two disciplines of earthquake engineering and civil engineering. The interaction effect represents the mechanism of energy transfer and dissipation among the elements of the dynamic system, namely the soil subgrade, foundation, and superstructure. This interaction effect is important across many structure, foundation, and subgrade types but is most pronounced when a rigid superstructure is founded on a relatively soft lower foundation and subgrade. This effect may only be ignored when the subgrade is much harder than a flexible superstructure: for instance a flexible moment frame superstructure founded on a thin compacted soil layer on top of very stiff bedrock below. This paper will study the interaction effect of the subgrade and the superstructure. The analytical solution of the interaction of a shear wall, flexible-rigid foundation, and an elastic half-space is derived for incident SH waves with various angles of incidence. It found that the flexible ring (soft layer) cannot be used as an isolation mechanism to decouple a superstructure from its substructure resting on a shaking half-space.

STP K Basin Sludge Sample Archive at the Pacific Northwest National Laboratory FY2014

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fiskum, Sandra K.; Smoot, Margaret R.; Schmidt, Andrew J.

2014-06-01

The Pacific Northwest National Laboratory (PNNL) currently houses 88 samples (~10.5 kg) of K Basin sludge (81 wet and seven dry samples) on behalf of the Sludge Treatment Project (STP), which is managed for the U.S. Department of Energy (DOE) by the CH2M Hill Plateau Remediation Company (CHPRC). Selected samples are intended to serve, in part, as sentinels to enhance understanding of sludge properties after long-term storage, and thus enhance understanding of sludge behavior following transfer to sludge transfer and storage containers (STSCs) and storage at the Hanford 200 Area central plateau. In addition, remaining samples serve in contingency formore » future testing requirements. At PNNL, the samples are tracked and maintained under a prescriptive and disciplined monthly sample-monitoring program implemented by PNNL staff. This report updates the status of the K Basin archive sludge sample inventory to April 2014. The previous inventory status report, PNNL 22245 (Fiskum et al. 2013, limited distribution report), was issued in February of 2013. This update incorporates changes in the inventory related to repackaging of 17 samples under test instructions 52578 TI052, K Basin Sludge Sample Repackaging for Continued Long Term Storage, and 52578 TI053, K Basin Sludge Sample Repackaging Post-2014 Shear Strength Measurements. Note that shear strength measurement results acquired in 2014 are provided separately. Specifically, this report provides the following: • a description of the K Basin sludge sample archive program and the sample inventory • a summary and images of the samples that were repackaged in April 2014 • up-to-date images and plots of the settled density and water loss from all applicable samples in the inventory • updated sample pedigree charts, which provide a roadmap of the genesis and processing history of each sample in the inventory • occurrence and deficiency reports associated with sample storage and repackaging« less

US Water Law Impacts on Hydrology: A retrospective, paired watershed approach

NASA Astrophysics Data System (ADS)

Glosser, D. B.; Bain, D. J.

2011-12-01

Understanding the couplings between hydrology and human activity is increasingly important as population and economic growth elevate stress on water systems. Since human activity is mediated by the law, we use water rights law as a starting point to understand human activity. In the United States, water rights are delegated at the state level. In Riparian (Eastern) states, water rights are tied to land ownership. Storage of water beyond a right holder's share is generally illegal, and water rights cannot be lost through non-use. However, in P.A. (Western) states, storage of water is required in order to gain a water use right. The first party to appropriate the water is given rights senior to later appropriators, and these rights can be transferred and sold at will. Continual use of a P.A. right is required in order to maintain a right, therefore lower water yields from P.A. governed basins is the expected result. However, these differences remain unquantified. The P.A./Riparian divide runs north-south through the center of the contiguous United States. We take advantage of this geographic divide in water law, and use a paired basin approach to compare historic water dynamics in basins along opposite sides of the divide. By choosing basin pair members in close proximity, we minimize geologic and climatic differences within each pair. Data including USGS discharge records; National Climate Data Center weather records; the National Land Cover Dataset, the National Inventory of Dams, and well data from state agencies, are used to characterize basin hydrology. Preliminary results confirm P.A. water yields are lower than Riparian yields (P.A. yields are between 58% and 80% of Riparian yields). Further, Runoff:rainfall ratios are lower in the P.A. basins (P.A. ratios are between 54% and 85% of Riparian ratios). While well data are not consistent among states, and seemingly sensitive to local registration requirements, in a P.A. basin where such data are available, a substantial and rapid increase in permitted withdrawals does not seemingly affect discharge records when compared to earlier periods and to the other basin pair. In contrast, differences in dam occurrence are unambiguous. P.A. dam storage can exceed Riparian storage by as much as 48 millimeters. The large differential in dam storage may also lower discharge variability. In basin pairs with substantial storage differential; the average annual coefficient of variation is half of that in the Riparian member. Water law can cause consistent and likely predictable effects on water dynamics. Quantitative comparison of water law implications to hydrology is a critical step in informing US water policy.

Base of fresh ground water, northern Louisiana Salt-Dome Basin and vicinity, northern Louisiana and southern Arkansas

USGS Publications Warehouse

Ryals, G.N.

1980-01-01

The National Waste Terminal Storage Program is an effort by the U.S. Department of Energy to locate and develop sites for disposal or storage of commercially produced radioactive wastes. As part of this program, salt domes in the northern Louisiana salt-dome basin are being studied to determine their suitability as repositories. Part of the U.S. Geological Survey 's participation in the program has been to describe the regional geohydrology of the northern Louisiana salt-dome basin. A map based on a compilation of published data and the interpretation of electrical logs shows the altitude of the base of freshwater in aquifers in the northern Louisiana salt-dome basin. (USGS)

Amplicon Sequencing Reveals Microbiological Signatures in Spent Nuclear Fuel Storage Basins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bagwell, Christopher E.; Noble, Peter A.; Milliken, Charles E.

Water quality is an important determinant for the structural integrity of alloy cladded fuels and assemblies during long-term wet storage. Detailed characterization of a water filled storage basin for spent nuclear reactor fuel was performed following the formation and proliferation of an amorphous white flocculent. White precipitant was sampled throughout the storage basin for chemical and spectroscopic characterization, and eDNA was extracted for pyrosequencing of bacterial rRNA gene diversity. Accordingly, spectroscopic analyses indicated the precipitant to be primarily amorphous to crystalline aluminum (oxy) hydroxides with minor associated elemental components including Fe, Si, Ti, and U. High levels of dissolved carbonmore » were co-localized with the precipitant relative to bulk water. Bacterial densities were highly variable between sampling locations and with depth; cell numbers (log scale) ranged from 5.6 to 4.89 cells / mL. Bacterial diversity that was physically associated with the aluminum (oxy) hydroxide complexes exceeded an estimated 4,000 OTUs / amplicon library (3% cutoff) and the greatest percent majority of sequences were aligned to the families Burkholderiales (23%), Nitrospiraceae (23%), Hyphomicrobiaceae (17%), and Comamonadaceae (6%). We surmise that episodic changes in the physical and chemical properties of the basin contribute to the polymerization of aluminum (oxy) hydroxides, which in turn can chemisorb nutrients, carbon ligands and bacterial cells from the surrounding bulk aqueous phase. As such, these precipitants should establish favorable microhabitats for bacterial colonization and growth. Comparative analyses of 16S rRNA gene amplicon libraries across diverse environmental landscapes were performed and microbiological signatures unique to the spent nuclear fuel storage basin environment were revealed. These insights could spur the development of tractable bioindicators that are specific of and diagnostic for water quality at discrete locations and finer scales of resolution, marking an important contribution for improved water quality and management of spent nuclear fuel storage facilities.« less

Interplay between intercalated oxygen superstructures and monolayer h -BN on Cu(100)

DOE PAGES

Ma, Chuanxu; Park, Jewook; Liu, Lei; ...

2016-08-18

The confinement effect of intercalated atoms in van der Waals heterostructures can lead to interesting interactions between the confined atoms or molecules and the overlaying two-dimensional (2D) materials. In this paper, we report the formation of ordered Cu(100) p(2×2) oxygen superstructures by oxygen intercalation under the monolayer hexagonal boron nitride (h-BN) on Cu after annealing. By using scanning tunneling microscopy and x-ray photoelectron spectroscopy, we identify the superstructure and reveal its roles in passivating the exposed Cu surfaces, decoupling h-BN and Cu, and disintegrating h-BN monolayers. The oxygen superstructure appears as a 2D pattern on the exposed Cu surface ormore » quasi-1D stripes of paired oxygen intercalated in the interface of h-BN and Cu predominantly oriented along the moiré modulations. The oxygen superstructure is shown to etch the overlaying h-BN monolayer in a thermal annealing process. After extended annealing, the h-BN monolayer disintegrates into nanoislands with zigzag edges. Finally, we discuss the implications of these findings on the stability and oxidation resistance of h-BN and relate them to challenges in process integration and 2D heterostructures.« less

A superstructure-based electrochemical assay for signal-amplified detection of DNA methyltransferase activity.

PubMed

Zhang, Hui; Yang, Yin; Dong, Huilei; Cai, Chenxin

2016-12-15

DNA methyltransferase (MTase) activity is highly correlated with the occurrence and development of cancer. This work reports a superstructure-based electrochemical assay for signal-amplified detection of DNA MTase activity using M.SssI as an example. First, low-density coverage of DNA duplexes on the surface of the gold electrode was achieved by immobilized mercaptohexanol, followed by immobilization of DNA duplexes. The duplex can be cleaved by BstUI endonuclease in the absence of DNA superstructures. However, the cleavage is blocked after the DNA is methylated by M.SssI. The DNA superstructures are formed with the addition of helper DNA. By using an electroactive complex, RuHex, which can bind to DNA double strands, the activity of M.SssI can be quantitatively detected by differential pulse voltammetry. Due to the high site-specific cleavage by BstUI and signal amplification by the DNA superstructure, the biosensor can achieve ultrasensitive detection of DNA MTase activity down to 0.025U/mL. The method can be used for evaluation and screening of the inhibitors of MTase, and thus has potential in the discovery of methylation-related anticancer drugs. Copyright © 2016 Elsevier B.V. All rights reserved.

5. EAST SIDE, TEST STAND AND ITS SUPERSTRUCTURE. Edwards ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. EAST SIDE, TEST STAND AND ITS SUPERSTRUCTURE. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

8. SOUTH REAR, SUPERSTRUCTURE. Looking north from deck. Edwards ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. SOUTH REAR, SUPERSTRUCTURE. Looking north from deck. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

Estimate of ground water in storage in the Great Lakes basin, United States, 2006

USGS Publications Warehouse

Coon, William F.; Sheets, Rodney A.

2006-01-01

Hydrogeologic data from Regional Aquifer System Analyses (RASA) studies by the U.S. Geological Survey in the Great Lakes Basin, United States, during 1978-95, were compiled and used to estimate the total volume of water that is stored in the many aquifers of the basin. These studies focused on six regional aquifer systems: the Cambrian-Ordovician aquifer system in Wisconsin, Illinois, and Indiana; the Silurian- Devonian aquifers in Wisconsin, Michigan, Illinois, Indiana, and Ohio; the surficial aquifer system (aquifers of alluvial and glacial origin) found throughout the Great Lakes Basin; and the Pennsylvanian sandstone and carbonate-rock aquifers and the Mississippian sandstone aquifer in Michigan. Except for the surficial aquifers, all of these aquifer systems are capable of yielding substantial quantities of water and are not small aquifers with only local importance. Individual surficial aquifers, although small in comparison to the bedrock aquifers, collectively represent large potential sources of ground water and therefore have been treated as a regional system. Summation of ground-water volumes in the many regional aquifers of the basin indicates that about 1,340 cubic miles of water is in storage; of this, about 984 cubic miles is considered freshwater (that is, water with dissolved-solids concentration less than 1,000 mg/L). These volumes should not be interpreted as available in their entirety to meet water-supply needs; complete dewatering of any aquifer is environmentally undesirable. The amount of water that is considered available on the basis of water quality and environmental, economic, and legal constraints has not been determined. The effect of heavy pumping in the Chicago, Ill., and Milwaukee, Wis., areas, which has caused the regional ground-water divide in the Cambrian-Ordovician aquifer system to shift westward, has been included in the above estimates. This shift in the ground-water divide has increased the amount of water in storage in the deep-bedrock aquifers of the Great Lakes Basin by about 36 cubic miles; however, this water is removed by wells and, after use, is mostly discharged to the Mississippi River Basin rather than to the Great Lakes Basin. The corresponding decrease in ground-water storage that has resulted from lowering of the potentiometric surface due to this heavy pumping (0.059 cubic miles) is negligible compared to the total estimated storage.

LGSOWG CCT format CCB document: The standard CCT family of tape formats

NASA Technical Reports Server (NTRS)

1979-01-01

The tape format standardization approach recommended by the committee on CCT standardization is described and defined. All rules and conventions required to employ the superstructure approach to the CCT family of tape formats are presented for users of remote sensing data and producer of user tapes and the superstructure records are specified. The standard for future tape format design is presented as a guide to designing data records of a particular tape format. An example is provided showing how to incorporate the superstructure into an already established tape format.

Superstructure for high current applications in superconducting linear accelerators

DOEpatents

Sekutowicz, Jacek [Elbchaussee, DE; Kneisel, Peter [Williamsburg, VA

2008-03-18

A superstructure for accelerating charged particles at relativistic speeds. The superstructure consists of two weakly coupled multi-cell subunits equipped with HOM couplers. A beam pipe connects the subunits and an HOM damper is included at the entrance and the exit of each of the subunits. A coupling device feeds rf power into the subunits. The subunits are constructed of niobium and maintained at cryogenic temperatures. The length of the beam pipe between the subunits is selected to provide synchronism between particles and rf fields in both subunits.

Magneto-electronic coupling in modulated defect-structures of natural Fe{sub 1−x}S

DOE Office of Scientific and Technical Information (OSTI.GOV)

Charilaou, M., E-mail: charilaou@mat.ethz.ch; Löffler, J. F.; Kind, J.

2015-08-28

We provide compelling experimental evidence that the low-temperature transition in natural non-stoichiometric Fe{sub 7}S{sub 8}, a major magnetic remanence carrier in the Earth's crust and in extraterrestrial materials, is a phenomenon caused by magnetic coupling between epitaxially intergrown superstructures. The two superstructures differ in their defect distribution, and consequently in their magnetic anisotropy. At T < 30 K, the magnetic moments of the superstructures become strongly coupled, resulting in a 12-fold anisotropy symmetry, which is reflected in the anisotropic magneto-resistance.

Substantial inorganic carbon sink in closed drainage basins globally

NASA Astrophysics Data System (ADS)

Li, Yu; Zhang, Chengqi; Wang, Naiang; Han, Qin; Zhang, Xinzhong; Liu, Yuan; Xu, Lingmei; Ye, Wangting

2017-07-01

Arid and semi-arid ecosystems are increasingly recognized as important carbon storage sites. In these regions, extensive sequestration of dissolved inorganic carbon can occur in the terminal lakes of endorheic basins--basins that do not drain to external bodies of water. However, the global magnitude of this dissolved inorganic carbon sink is uncertain. Here we present isotopic, radiocarbon, and chemical analyses of groundwater, river water, and sediments from the terminal region of the endorheic Shiyang River drainage basin, in arid northwest China. We estimate that 0.13 Pg of dissolved inorganic carbon was stored in the basin during the mid-Holocene. Pollen-based reconstructions of basin-scale productivity suggest that the mid-Holocene dissolved inorganic carbon sink was two orders of magnitude smaller than terrestrial productivity in the basin. We use estimates of dissolved inorganic carbon storage based on sedimentary data from 11 terminal lakes of endorheic basins around the world as the basis for a global extrapolation of the sequestration of dissolved organic carbon in endorheic basins. We estimate that 0.152 Pg of dissolved inorganic carbon is buried per year today, compared to about 0.211 Pg C yr-1 during the mid-Holocene. We conclude that endorheic basins represent an important carbon sink on the global scale, with a magnitude similar to deep ocean carbon burial.

Feasibility Study For Use Of Commercial Cask Vendor Dry Transfer Systems To Unload Used Fuel Assemblies In L-Area

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krementz, Dan; Rose, David; Dunsmuir, Mike

2014-02-06

The purpose of this study is to determine whether a commercial dry transfer system (DTS) could be used for loading or unloading used nuclear fuel (UNF) in L-Basin and to determine if a DTS pool adapter could be made for L-Basin Transfer Pit #2 that could accommodate a variety of DTS casks and fuel baskets or canisters up to 24” diameter.[1, 2] This study outlines the technical feasibility of accommodating different vendor dry transfer systems in the L-Basin Transfer Bay with a general work scope. It identifies equipment needing development, facility modifications, and describes the needed analyses and calculations. Aftermore » reviewing the L-Basin Transfer Bay area layout and information on the only DTS system currently in use for the Nuclear Assurance Corporation Legal Weight Truck cask (NAC LWT), the authors conclude that use of a dry transfer cask is feasible. AREVA was contacted and acknowledged that they currently do not have a design for a dry transfer cask for their new Transnuclear Long Cask (TN-LC) cask. Nonetheless, this study accounted for a potential future DTS from AREVA to handle fuel baskets up to 18” in diameter. Due to the layout of the Transfer Bay, it was determined that a DTS cask pool adapter designed specifically for spanning Pit #2 and placed just north of the 70 Ton Cask lid lifting superstructure would be needed. The proposed pool adapter could be used to transition a fuel basket up to 24” in diameter and ~11 feet long from a dry transfer cask to the basin. The 18” and 24” applications of the pool adapter are pending vendor development of dry transfer casks that accommodate these diameters. Once a fuel basket has been lowered into Pit #2 through a pool adapter, a basket cart could be used to move the basket out from under the pool adapter for access by the 5 Ton Crane. The cost to install a dry transfer cask handling system in L-Area capable of handling multiple vendor provided transport and dry transfer casks and baskets with different diameters and lengths would likely be on the same order of magnitude as the Basin Modifications project. The cost of a DTS capability is affected by the number of design variations of different vendor transport and dry transfer casks to be considered for design input. Some costs would be incurred for each vendor DTS to be handled. For example, separate analyses would be needed for each dry transfer cask type such as criticality, shielding, dropping a dry transfer cask and basket, handling and auxiliary equipment, procedures, operator training, readiness assessments, and operational readiness reviews. A DTS handling capability in L-Area could serve as a backup to the Shielded Transfer System (STS) for unloading long casks and could support potential future missions such as the Idaho National Laboratory (INL) Exchange or transferring UNF from wet to dry storage.« less

Offshore platform structure intended to be installed in arctic waters, subjected to drifting icebergs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kure, G.; Jenssen, D.N.; Naesje, K.

1984-09-11

An offshore platform structure, particularly intended to be installed in waters where drifting iceberg frequently appear, the platform structure being intended to be founded in a sea bed and comprises a substructure, a superstructure rigidly affixed to the substructure and extending vertically up above the sea level supporting a deck superstructure at its upper end. The horizontal cross-sectional area of the substructure is substantially greater than tath of the superstructure. The substructure rigidly supports a fender structure, the fender structure comprising an outer peripherally arranged wall and an inner cylindrical wall the inner and outer wall being rigidly interconnected bymore » means of a plurality of vertical and/or horizontal partition walls, dividing the fender structure into a plurality of cells or compartlents. The fender structure is arranged in spaced relation with respect to the superstructure.« less

Turbulent Superstructures in Rayleigh-Bénard convection at different Prandtl number

NASA Astrophysics Data System (ADS)

Schumacher, Jörg; Pandey, Ambrish; Ender, Martin; Westermann, Rüdiger; Scheel, Janet D.

2017-11-01

Large-scale patterns of the temperature and velocity field in horizontally extended cells can be considered as turbulent superstructures in Rayleigh-Bénard convection (RBC). These structures are obtained once the turbulent fluctuations are removed by a finite-time average. Their existence has been reported for example in Bailon-Cuba et al.. This large-scale order obeys a strong similarity with the well-studied patterns from the weakly nonlinear regime at lower Rayleigh number in RBC. In the present work we analyze the superstructures of RBC at different Prandtl number for Prandtl values between Pr = 0.005 for liquid sodium and 7 for water. The characteristic evolution time scales, the typical spatial extension of the rolls and the properties of the defects of the resulting superstructure patterns are analyzed. Data are obtained from well-resolved spectral element direct numerical simulations. The work is supported by the Priority Programme SPP 1881 of the Deutsche Forschungsgemeinschaft.

SLUDGE TREATMENT PROJECT PHASE 1 SLUDGE STORAGE OPTIONS ASSESSMENT OF T PLANT VERSUS ALTERNATE STORAGE FACILITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

RUTHERFORD WW; GEUTHER WJ; STRANKMAN MR

2009-04-29

The CH2M HILL Plateau Remediation Company (CHPRC) has recommended to the U.S. Department of Energy (DOE) a two phase approach for removal and storage (Phase 1) and treatment and packaging for offsite shipment (Phase 2) of the sludge currently stored within the 105-K West Basin. This two phased strategy enables early removal of sludge from the 105-K West Basin by 2015, allowing remediation of historical unplanned releases of waste and closure of the 100-K Area. In Phase 1, the sludge currently stored in the Engineered Containers and Settler Tanks within the 105-K West Basin will be transferred into sludge transportmore » and storage containers (STSCs). The STSCs will be transported to an interim storage facility. In Phase 2, sludge will be processed (treated) to meet shipping and disposal requirements and the sludge will be packaged for final disposal at a geologic repository. The purpose of this study is to evaluate two alternatives for interim Phase 1 storage of K Basin sludge. The cost, schedule, and risks for sludge storage at a newly-constructed Alternate Storage Facility (ASF) are compared to those at T Plant, which has been used previously for sludge storage. Based on the results of the assessment, T Plant is recommended for Phase 1 interim storage of sludge. Key elements that support this recommendation are the following: (1) T Plant has a proven process for storing sludge; (2) T Plant storage can be implemented at a lower incremental cost than the ASF; and (3) T Plant storage has a more favorable schedule profile, which provides more float, than the ASF. Underpinning the recommendation of T Plant for sludge storage is the assumption that T Plant has a durable, extended mission independent of the K Basin sludge interim storage mission. If this assumption cannot be validated and the operating costs of T Plant are borne by the Sludge Treatment Project, the conclusions and recommendations of this study would change. The following decision-making strategy, which is dependent on the confidence that DOE has in the long term mission for T Plant, is proposed: (1) If the confidence level in a durable, extended T Plant mission independent of sludge storage is high, then the Sludge Treatment Project (STP) would continue to implement the path forward previously described in the Alternatives Report (HNF-39744). Risks to the sludge project can be minimized through the establishment of an Interface Control Document (ICD) defining agreed upon responsibilities for both the STP and T Plant Operations regarding the transfer and storage of sludge and ensuring that the T Plant upgrade and operational schedule is well integrated with the sludge storage activities. (2) If the confidence level in a durable, extended T Plant mission independent of sludge storage is uncertain, then the ASF conceptual design should be pursued on a parallel path with preparation of T Plant for sludge storage until those uncertainties are resolved. (3) Finally, if the confidence level in a durable, extended T Plant mission independent of sludge storage is low, then the ASF design should be selected to provide independence from the T Plant mission risk.« less

Estimating probabilities of reservoir storage for the upper Delaware River basin

USGS Publications Warehouse

Hirsch, Robert M.

1981-01-01

A technique for estimating conditional probabilities of reservoir system storage is described and applied to the upper Delaware River Basin. The results indicate that there is a 73 percent probability that the three major New York City reservoirs (Pepacton, Cannonsville, and Neversink) would be full by June 1, 1981, and only a 9 percent probability that storage would return to the ' drought warning ' sector of the operations curve sometime in the next year. In contrast, if restrictions are lifted and there is an immediate return to normal operating policies, the probability of the reservoir system being full by June 1 is 37 percent and the probability that storage would return to the ' drought warning ' sector in the next year is 30 percent. (USGS)

Cosmogenic nuclide budgeting of floodplain sediment transfer

NASA Astrophysics Data System (ADS)

Wittmann, H.; von Blanckenburg, F.

2009-08-01

Cosmogenic nuclides produced in quartz may either decay or accumulate while sediment is moved through a river basin. A change in nuclide concentration resulting from storage in a floodplain is potentially important in large drainage basins in which sediment is prone to repeated burial and remobilization as a river migrates through its floodplain. We have modeled depth- and time-dependent cosmogenic nuclide concentration changes for 10Be, 26Al, and 14C during sediment storage and mixing in various active floodplain settings ranging from confined, shallow rivers with small floodplains to foreland-basin scale floodplains traversed by deep rivers. Floodplain storage time, estimated from channel migration rates, ranges from 0.4 kyr for the Beni River basin (Bolivia) to 7 kyr for the Amazon River basin, while floodplain storage depth, estimated from channel depth, ranges from 1 to 25 m. For all modeled active floodplain settings, the long-lived nuclides 10Be and 26Al show neither significant increase in nuclide concentration from irradiation nor decrease from decay. We predict a hypothetical response time after which changes in 10Be or 26Al concentrations become analytically resolvable. This interval ranges from 0.07 to 2 Myr and exceeds in all cases the typical residence time of sediment in a floodplain. Due to the much shorter half life of 14C, nuclide concentrations modeled for the in situ-produced variety of this nuclide are, however, sensitive to floodplain storage on residence times of < 20 kyr. The cosmogenic nuclide composition of old deposits in currently inactive floodplains that have been isolated for periods of millions of years from the river that once deposited them is predicted to either increase or decrease in 10Be and 26Al concentration, depending on the depositional depth. These conditions can be evaluated using the 26Al/ 10Be ratio that readily discloses the depth and duration of storage. We illustrate these models with examples from the Amazon basin. As predicted, modern bedload collected from an Amazon tributary, the Bolivian Beni River, shows no systematic change in nuclide concentration as sediment is moved through 500 km of floodplain by river meandering. In contrast, in the central Amazon floodplain currently untouched by the modern river system, low 26Al/ 10Be ratios account for minimum burial depths of 5 to 10 m for a duration of > 5 Myr. The important result of this analysis is that in all likely cases of active floodplains, cosmogenic 10Be and 26Al concentrations remain virtually unchanged over the interval sediment usually spends in the basin. Thus, spatially-averaged denudation rates of the sediment-producing area can be inferred throughout the entire basin, provided that nuclide production rates are scaled for the altitudes of the sediment-producing area only, because floodplain storage does not modify nuclide concentrations introduced from the sediment source area.

Construction of prestressed concrete single-tee bridge superstructures.

DOT National Transportation Integrated Search

1977-01-01

This report discusses in detail the construction of the first five precast, prestressed concrete, single-tee beam bridge superstructures to be let to contract in Virginia. The data suggest that this single-tee beam enables efficient construction of t...

Large-scale laboratory observations of wave forces on a highway bridge superstructure.

DOT National Transportation Integrated Search

2011-10-01

The experimental setup and data are presented for a laboratory experiment conducted to examine realistic wave forcing on a highway bridge : superstructure. The experiments measure wave conditions along with the resulting forces, pressures, and struct...

Geomorphological Controls on Fluvial Organic Carbon Storage in Wood and Soil in the Olympic, Cascade, and Rocky Mountains

NASA Astrophysics Data System (ADS)

Scott, D.; Wohl, E.

2017-12-01

The terrestrial organic carbon (OC) pool plays a major role in impacting global climate through the storage and potential release of carbon. In particular, areas of high net primary productivity, such as mountainous regions, and high spatial complexity, such as mountain river floodplains, show potential to act as both strong OC reservoirs and potential OC emitters in a changing climate. We focus on mountain rivers as potential hot swaths of OC storage and, accordingly, as places where land management to retain OC on the landscape may be especially impactful. Mountain river OC storage magnitude and age is a function of the soil and geomorphologic conditions at a reach scale, which are in turn determined by broader characteristics, such as climate, ecology, and tectonics. We present field data on OC storage in soil and wood from three mountain ranges across the western U.S.: the Wind River Range in Wyoming and the Olympic and Central Cascade Ranges in Washington. While the Big Sandy River basin in the Wind River Range exhibits relatively low relief, a semi-arid climate, and a fire-mediated disturbance regime, the Middle Fork Snoqualmie basin in the Cascades and the Sitkum and South Fork Calawah basins in the Olympics exhibit high relief and a humid climate. In contrast to the Olympics, the study basin in the Cascades exhibits strong longitudinal disconnectivity in the form of glaciogenic lakes, whereas the study basins in the Olympics lack large depositional zones that can store sediment for long periods of time. With our expansive dataset of OC storage magnitude and age in downed wood and soil from these three disparate regions, covering a wide range of tectonic, geomorphic, climatic, and ecologic variability, we are able to evaluate both the magnitude and age of the mountain river carbon pool as well as the factors that control that magnitude and age. We present a statistical model that illuminates the dominant controls on the magnitude and age of OC storage in mountain rivers. Using this, we broadly examine mountain river carbon storage dynamics with the goal of allowing land managers to prioritize and focus management efforts to retain OC on the landscape.

Aggregation of carbon dioxide sequestration storage assessment units

USGS Publications Warehouse

Blondes, Madalyn S.; Schuenemeyer, John H.; Olea, Ricardo A.; Drew, Lawrence J.

2013-01-01

The U.S. Geological Survey is currently conducting a national assessment of carbon dioxide (CO2) storage resources, mandated by the Energy Independence and Security Act of 2007. Pre-emission capture and storage of CO2 in subsurface saline formations is one potential method to reduce greenhouse gas emissions and the negative impact of global climate change. Like many large-scale resource assessments, the area under investigation is split into smaller, more manageable storage assessment units (SAUs), which must be aggregated with correctly propagated uncertainty to the basin, regional, and national scales. The aggregation methodology requires two types of data: marginal probability distributions of storage resource for each SAU, and a correlation matrix obtained by expert elicitation describing interdependencies between pairs of SAUs. Dependencies arise because geologic analogs, assessment methods, and assessors often overlap. The correlation matrix is used to induce rank correlation, using a Cholesky decomposition, among the empirical marginal distributions representing individually assessed SAUs. This manuscript presents a probabilistic aggregation method tailored to the correlations and dependencies inherent to a CO2 storage assessment. Aggregation results must be presented at the basin, regional, and national scales. A single stage approach, in which one large correlation matrix is defined and subsets are used for different scales, is compared to a multiple stage approach, in which new correlation matrices are created to aggregate intermediate results. Although the single-stage approach requires determination of significantly more correlation coefficients, it captures geologic dependencies among similar units in different basins and it is less sensitive to fluctuations in low correlation coefficients than the multiple stage approach. Thus, subsets of one single-stage correlation matrix are used to aggregate to basin, regional, and national scales.

SLUDGE TREATMENT PROJECT COST COMPARISON BETWEEN HYDRAULIC LOADING AND SMALL CANISTER LOADING CONCEPTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

GEUTHER J; CONRAD EA; RHOADARMER D

2009-08-24

The Sludge Treatment Project (STP) is considering two different concepts for the retrieval, loading, transport and interim storage of the K Basin sludge. The two design concepts under consideration are: (1) Hydraulic Loading Concept - In the hydraulic loading concept, the sludge is retrieved from the Engineered Containers directly into the Sludge Transport and Storage Container (STSC) while located in the STS cask in the modified KW Basin Annex. The sludge is loaded via a series of transfer, settle, decant, and filtration return steps until the STSC sludge transportation limits are met. The STSC is then transported to T Plantmore » and placed in storage arrays in the T Plant canyon cells for interim storage. (2) Small Canister Concept - In the small canister concept, the sludge is transferred from the Engineered Containers (ECs) into a settling vessel. After settling and decanting, the sludge is loaded underwater into small canisters. The small canisters are then transferred to the existing Fuel Transport System (FTS) where they are loaded underwater into the FTS Shielded Transfer Cask (STC). The STC is raised from the basin and placed into the Cask Transfer Overpack (CTO), loaded onto the trailer in the KW Basin Annex for transport to T Plant. At T Plant, the CTO is removed from the transport trailer and placed on the canyon deck. The CTO and STC are opened and the small canisters are removed using the canyon crane and placed into an STSC. The STSC is closed, and placed in storage arrays in the T Plant canyon cells for interim storage. The purpose of the cost estimate is to provide a comparison of the two concepts described.« less

Climatic and biotic controls on annual carbon storage in Amazonian ecosystems

USGS Publications Warehouse

Tian, H.; Melillo, J.M.; Kicklighter, D.W.; McGuire, A.D.; Helfrich, J.; Moore, B.; Vorosmarty, C.J.

2000-01-01

1 The role of undisturbed tropical land ecosystems in the global carbon budget is not well understood. It has been suggested that inter-annual climate variability can affect the capacity of these ecosystems to store carbon in the short term. In this paper, we use a transient version of the Terrestrial Ecosystem Model (TEM) to estimate annual carbon storage in undisturbed Amazonian ecosystems during the period 1980-94, and to understand the underlying causes of the year-to-year variations in net carbon storage for this region. 2 We estimate that the total carbon storage in the undisturbed ecosystems of the Amazon Basin in 1980 was 127.6 Pg C, with about 94.3 Pg C in vegetation and 33.3 Pg C in the reactive pool of soil organic carbon. About 83% of the total carbon storage occurred in tropical evergreen forests. Based on our model's results, we estimate that, over the past 15 years, the total carbon storage has increased by 3.1 Pg C (+ 2%), with a 1.9-Pg C (+2%) increase in vegetation carbon and a 1.2-Pg C (+4%) increase in reactive soil organic carbon. The modelled results indicate that the largest relative changes in net carbon storage have occurred in tropical deciduous forests, but that the largest absolute changes in net carbon storage have occurred in the moist and wet forests of the Basin. 3 Our results show that the strength of interannual variations in net carbon storage of undisturbed ecosystems in the Amazon Basin varies from a carbon source of 0.2 Pg C/year to a carbon sink of 0.7 Pg C/year. Precipitation, especially the amount received during the drier months, appears to be a major controller of annual net carbon storage in the Amazon Basin. Our analysis indicates further that changes in precipitation combine with changes in temperature to affect net carbon storage through influencing soil moisture and nutrient availability. 4 On average, our results suggest that the undisturbed Amazonian ecosystems accumulated 0.2 Pg C/year as a result of climate variability and increasing atmospheric CO2 over the study period. This amount is large enough to have compensated for most of the carbon losses associated with tropical deforestation in the Amazon during the same period. 5 Comparisons with empirical data indicate that climate variability and CO2 fertilization explain most of the variation in net carbon storage for the undisturbed ecosystems. Our analyses suggest that assessment of the regional carbon budget in the tropics should be made over at least one cycle of El Nino-Southern Oscillation because of inter-annual climate variability. Our analyses also suggest that proper scaling of the site-specific and sub-annual measurements of carbon fluxes to produce Basin-wide flux estimates must take into account seasonal and spatial variations in net carbon storage.

Reservoir-development impacts on surface-water quantity and quality in the Yampa River basin, Colorado and Wyoming

USGS Publications Warehouse

Adams, D. Briane; Bauer, Daniel P.; Dale, Robert H.; Steele, Timothy Doak

1983-01-01

Development of coal resources and associated economy is accelerating in the Yampa River basin in northwestern Colorado and south-central Wyoming. Increased use of the water resources of the area will have a direct impact on their quantity and quality. As part of 18 surface-water projects, 35 reservoirs have been proposed with a combined total storage of 2.18 million acre-feet, 41% greater than the mean annual outflow from the basin. Three computer models were used to demonstrate methods of evaluating future impacts of reservoir development in the Yampa River basin. Four different reservoir configurations were used to simulate the effects of different degrees of proposed reservoir development. A multireservoir-flow model included both within-basin and transmountain diversions. Simulations indicated that in many cases diversion amounts would not be available for either type of diversion. A corresponding frequency analysis of reservoir storage levels indicated that most reservoirs would be operating with small percentages of total capacities and generally with less than 20% of conservation-pool volumes. Simulations using a dissolved-solids model indicated that extensive reservoir development could increase average annual concentrations at most locations. Simulations using a single-reservoir model indicated no significant occurrence of water-temperature stratification in most reservoirs due to limited reservoir storage. (USGS)

High-Elevation Evapotranspiration Estimates During Drought: Using Streamflow and NASA Airborne Snow Observatory SWE Observations to Close the Upper Tuolumne River Basin Water Balance

NASA Astrophysics Data System (ADS)

Henn, Brian; Painter, Thomas H.; Bormann, Kat J.; McGurk, Bruce; Flint, Alan L.; Flint, Lorraine E.; White, Vince; Lundquist, Jessica D.

2018-02-01

Hydrologic variables such as evapotranspiration (ET) and soil water storage are difficult to observe across spatial scales in complex terrain. Streamflow and lidar-derived snow observations provide information about distributed hydrologic processes such as snowmelt, infiltration, and storage. We use a distributed streamflow data set across eight basins in the upper Tuolumne River region of Yosemite National Park in the Sierra Nevada mountain range, and the NASA Airborne Snow Observatory (ASO) lidar-derived snow data set over 3 years (2013-2015) during a prolonged drought in California, to estimate basin-scale water balance components. We compare snowmelt and cumulative precipitation over periods from the ASO flight to the end of the water year against cumulative streamflow observations. The basin water balance residual term (snow melt plus precipitation minus streamflow) is calculated for each basin and year. Using soil moisture observations and hydrologic model simulations, we show that the residual term represents short-term changes in basin water storage over the snowmelt season, but that over the period from peak snow water equivalent (SWE) to the end of summer, it represents cumulative basin-mean ET. Warm-season ET estimated from this approach is 168 (85-252 at 95% confidence), 162 (0-326) and 191 (48-334) mm averaged across the basins in 2013, 2014, and 2015, respectively. These values are lower than previous full-year and point ET estimates in the Sierra Nevada, potentially reflecting reduced ET during drought, the effects of spatial variability, and the part-year time period. Using streamflow and ASO snow observations, we quantify spatially-distributed hydrologic processes otherwise difficult to observe.

An industrialized construction approach to concrete superstructures for bridges.

DOT National Transportation Integrated Search

1974-01-01

The objective of this study was to develop drawings for a specific site or sites that incorporated the best concepts of industrialized bridge superstructure construction, that is, great emphasis was placed upon the use of modular design and assembly ...

Exploratory study of partial isolation of highway bridges.

DOT National Transportation Integrated Search

2011-01-01

A special class of seismically isolated bridges shares a common feature in that both ends of the superstructure are restrained and isolators over the columns of bridge uncouple the superstructure from the ground motions. They are defined as partial i...

Hierarchically Superstructured Prussian Blue Analogues: Spontaneous Assembly Synthesis and Applications as Pseudocapacitive Materials

DOE PAGES

Yue, Yanfeng; Zhang, Zhiyong; Binder, Andrew J.; ...

2014-11-10

Hierarchically superstructured Prussian blue analogues (hexa- conventional hybrid graphene/MnO 2 nanostructured textiles. cyanoferrate, M = Ni II, Co II and Cu II) are synthesized through Because sodium or potassium ions are involved in energy stor- a spontaneous assembly technique. In sharp contrast to mac- age processes, more environmentally neutral electrolytes can roporous-only Prussian blue analogues, the hierarchically su- be utilized, making the superstructured porous Prussian blue perstructured porous Prussian blue materials are demonstrated analogues a great contender for applications as high-per- to possess a high capacitance, which is similar to those of the formance pseudocapacitors.

Surface Superstructure of Carbon Nanotubes on Highly Oriented Pyrolytic Graphite Annealed at Elevated Temperatures

NASA Astrophysics Data System (ADS)

An, Bai; Fukuyama, Seiji; Yokogawa, Kiyoshi; Yoshimura, Masamichi

1998-06-01

Carbon nanotubes deposited on highly oriented pyrolytic graphite (HOPG) are annealed in ultra high vacuum. The effect of annealing temperature on the surface morphology of the carbon nanotubes on HOPG is examined by scanning tunneling microscopy. The ring-like surface superstructure of (\\sqrt {3}× \\sqrt {3})R30° of graphite is found on the carbon nanotubes annealed above 1593 K. The tips of the carbon nanotubes are destroyed and the stacking misarrangement between the upper and the lower walls of the tube join with HOPG resulting in the superstructure.

77 FR 37036 - Williston Basin Interstate Pipeline Company; Notice of Request Under Blanket Authorization

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-20

... operation of natural gas facilities in Sheridan County and Campbell County, Wyoming and modification of underground storage facilities at its Baker Storage Reservoir in Fallon County, Montana. The details of... firm storage deliverability from its Baker Storage Reservoir that it will use to make up for declining...

Economic performance of water storage capacity expansion for food security

NASA Astrophysics Data System (ADS)

Gohar, Abdelaziz A.; Ward, Frank A.; Amer, Saud A.

2013-03-01

SummaryContinued climate variability, population growth, and rising food prices present ongoing challenges for achieving food and water security in poor countries that lack adequate water infrastructure. Undeveloped storage infrastructure presents a special challenge in northern Afghanistan, where food security is undermined by highly variable water supplies, inefficient water allocation rules, and a damaged irrigation system due three decades of war and conflict. Little peer-reviewed research to date has analyzed the economic benefits of water storage capacity expansions as a mechanism to sustain food security over long periods of variable climate and growing food demands needed to feed growing populations. This paper develops and applies an integrated water resources management framework that analyzes impacts of storage capacity expansions for sustaining farm income and food security in the face of highly fluctuating water supplies. Findings illustrate that in Afghanistan's Balkh Basin, total farm income and food security from crop irrigation increase, but at a declining rate as water storage capacity increases from zero to an amount equal to six times the basin's long term water supply. Total farm income increases by 21%, 41%, and 42% for small, medium, and large reservoir capacity, respectively, compared to the existing irrigation system unassisted by reservoir storage capacity. Results provide a framework to target water infrastructure investments that improve food security for river basins in the world's dry regions with low existing storage capacity that face ongoing climate variability and increased demands for food security for growing populations.

Surface Freshwater Storage and Variability in the Amazon Basin from Multi-Satellite Observations, 1993-2007

NASA Technical Reports Server (NTRS)

Papa, Fabrice; Frappart, Frederic; Guntner, Andreas; Prigent, Catherine; Aires, Filipe; Getirana, Augusto; Maurer, Raffael

2013-01-01

The amount of water stored and moving through the surface water bodies of large river basins (river, floodplains, wetlands) plays a major role in the global water and biochemical cycles and is a critical parameter for water resources management. However, the spatio-temporal variations of these freshwater reservoirs are still widely unknown at the global scale. Here, we propose a hypsographic curve approach to estimate surface freshwater storage variations over the Amazon basin combining surface water extent from a multi-satellite-technique with topographic data from the Global Digital Elevation Model (GDEM) from Advance Spaceborne Thermal Emission and Reflection Radiometer (ASTER). Monthly surface water storage variations for 1993-2007 are presented, showing a strong seasonal and interannual variability, and are evaluated against in situ river discharge and precipitation. The basin-scale mean annual amplitude of approx. 1200 cu km is in the range of previous estimates and contributes to about half of the Gravity Recovery And Climate Experiment (GRACE) total water storage variations. For the first time, we map the surface water volume anomaly during the extreme droughts of 1997 (October-November) and 2005 (September-October) and found that during these dry events the water stored in the river and flood-plains of the Amazon basin was, respectively, approx. 230 (approx. 40%) and 210 (approx. 50%) cu km below the 1993-2007 average. This new 15year data set of surface water volume represents an unprecedented source of information for future hydrological or climate modeling of the Amazon. It is also a first step toward the development of such database at the global scale.

Recharge rates and aquifer hydraulic characteristics for selected drainage basins in middle and east Tennessee

USGS Publications Warehouse

Hoos, A.B.

1990-01-01

Quantitative information concerning aquifer hydrologic and hydraulic characteristics is needed to manage the development of ground-water resources. These characteristics are poorly defined for the bedrock aquifers in Middle and East Tennessee where demand for water is increasing. This report presents estimates of recharge rate, storage coefficient, diffusivity, and transmissivity for representative drainage basins in Middle and East Tennessee, as determined from analyses of stream-aquifer interactions. The drainage basins have been grouped according to the underlying major aquifer, then statistical descriptions applied to each group, in order to define area1 distribution of these characteristics. Aquifer recharge rates are estimated for representative low, average, and high flow years for 63 drainage basins using hydrograph analysis techniques. Net annual recharge during average flow years for all basins ranges from 4.1 to 16.8 in/yr (inches per year), with a mean value of 7.3 in. In general, recharge rates are highest for basins underlain by the Blue Ridge aquifer (mean value11.7 in/yr) and lowest for basins underlain by the Central Basin aquifer (mean value 5.6 in/yr). Mean recharge values for the Cumberland Plateau, Highland Rim, and Valley and Ridge aquifers are 6.5, 7.4, and 6.6 in/yr, respectively. Gravity drainage characterizes ground-water flow in most surficial bedrock aquifer in Tennessee. Accordingly, a gravity yield analysis, which compares concurrent water-level and streamflow hydrographs, was used to estimate aquifer storage coefficient for nine study basins. The basin estimates range from 0.002 to 0.140; however, most estimates are within a narrow range of values, from 0.01 to 0.025. Accordingly, storage coefficient is estimated to be 0.01 for all aquifers in Middle and East Tennessee, with the exception of the aquifer in the inner part of the Central Basin, for which storage coefficient is estimated to be 0.002. Estimates of aquifer hydraulic diffusivity are derived from estimates of the streamflow recession index and drainage density for 75 drainage basins; values range from 3,300 to 130,000 ft^2/d (feet squared per day). Basin-specific and site-specific estimates of transmissivity are computed from estimates of hydraulic diffusivity and specific-capacity test data, respectively. Basin-specific, or areal, estimates of transmissivity range from 22 to 1,300 ft^2/d, with a mean of 240 ft^2/d In general, areal transmissivity is highest for basins underlain by the Cumberland Plateau aquifer (mean value 480 ft^2/d) and lowest for basins underlain by the Central Basin aquifer (mean value 79 ft^2/d). Mean transmissivity values for the Highland Rim, Valley and Ridge, and Blue Ridge aquifer are 320,140, and 120 ft^2/d respectively. Site-specific estimates of transmissivity, computed from specific-capacity data from 118 test wells in Middle and East Tennessee range from 2 to 93,000 ft^2/d with a mean of 2,600 ft^2/d Mean transmissivity values for the Cumberland Plateau, Highland Rim, Central Basin, Valley and Ridge, and Blue Ridge aquifers are 2,800,1,200, 7,800, 390, and 65Oft Id, respectively.

Geologic framework for the national assessment of carbon dioxide storage resources: Powder River Basin, Wyoming, Montana, South Dakota, and Nebraska: Chapter B in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Craddock, William H.; Drake II, Ronald M.; Mars, John L.; Merrill, Matthew D.; Warwick, Peter D.; Blondes, Madalyn S.; Gosai, Mayur A.; Freeman, P.A.; Cahan, Steven A.; DeVera, Christina A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2012-01-01

This report presents ten storage assessment units (SAUs) within the Powder River Basin of Wyoming, Montana, South Dakota, and Nebraska. The Powder River Basin contains a thick succession of sedimentary rocks that accumulated steadily throughout much of the Phanerozoic, and at least three stratigraphic packages contain strata that are suitable for CO2 storage. Pennsylvanian through Triassic siliciclastic strata contain two potential storage units: the Pennsylvanian and Permian Tensleep Sandstone and Minnelusa Formation, and the Triassic Crow Mountain Sandstone. Jurassic siliciclastic strata contain one potential storage unit: the lower part of the Sundance Formation. Cretaceous siliciclastic strata contain seven potential storage units: (1) the Fall River and Lakota Formations, (2) the Muddy Sandstone, (3) the Frontier Sandstone and Turner Sandy Member of the Carlile Shale, (4) the Sussex and Shannon Sandstone Members of Cody Shale, and (5) the Parkman, (6) Teapot, and (7) Teckla Sandstone Members of the Mesaverde Formation. For each SAU, we discuss the areal distribution of suitable CO2 reservoir rock. We also characterize the overlying sealing unit and describe the geologic characteristics that influence the potential CO2 storage volume and reservoir performance. These characteristics include reservoir depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this report, the geologic information included herein will be employed to calculate the potential storage space in the various SAUs.

Hybrid FRP-concrete bridge deck system final report I : development and system performance validation.

DOT National Transportation Integrated Search

2009-10-01

In this study, the concept of the hybrid FRP-concrete structural systems was applied to both bridge : superstructure and deck systems. Results from the both experimental and computational analysis for : both the hybrid bridge superstructure and deck ...

18. CROWS NEST ATOP SUPERSTRUCTURE. Looking up from northeast corner ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

18. CROWS NEST ATOP SUPERSTRUCTURE. Looking up from northeast corner of run line deck. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

19. TRAVELING CRANE ATOP SUPERSTRUCTURE, FROM RUN LINE DECK. Looking ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

19. TRAVELING CRANE ATOP SUPERSTRUCTURE, FROM RUN LINE DECK. Looking up to north northeast. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

32. Another type of upper superstructure assembly found on the ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

32. Another type of upper superstructure assembly found on the 1st and 4th spans. View is of north side of 4th span. - Cleves Bridge, Spanning Great Miami River on U.S. Highway 50, Cleves, Hamilton County, OH

Unknown Aspects of Self-Assembly of PbS Microscale Superstructures

PubMed Central

Querejeta-Fernández, Ana; Hernández-Garrido, Juan C.; Yang, Hengxi; Zhou, Yunlong; Varela, Aurea; Parras, Marina; Calvino-Gámez, José J.; González-Calbet, Jose M.; Green, Peter F.; Kotov, Nicholas A.

2012-01-01

A lot of interesting and sophisticated examples of nanoparticle (NP) self-assembly (SA) are known. From both fundamental and technological standpoints this field requires advancements in three principle directions: a) understanding the mechanism and driving forces of three-dimensional (3D) SA with both nano- and micro-levels of organization; b) understanding of disassembly/deconstruction processes; and c) finding synthetic methods of assembly into continuous superstructures without insulating barriers. From this perspective, we investigated the formation of well-known star-like PbS superstructures and found a number of previously unknown or overlooked aspects that can advance the knowledge of NP self-assembly in these three directions. The primary one is that the formation of large seemingly monocrystalline PbS superstructures with multiple levels of octahedral symmetry can be explained only by SA of small octahedral NPs. We found five distinct periods in the formation PbS hyperbranched stars: 1) nucleation of early PbS NPs with an average diameter of 31 nm; 2) assembly into 100–500 nm octahedral mesocrystals; 3) assembly into 1000–2500 nm hyperbranched stars; 4) assembly and ionic recrystallization into six-arm rods accompanied by disappearance of fine nanoscale structure; 5) deconstruction into rods and cubooctahedral NPs. The switches in assembly patterns between the periods occur due to variable dominance of pattern–determining forces that include vander Waals and electrostatic (charge-charge, dipole-dipole, and polarization) interactions. The superstructure deconstruction is triggered by chemical changes in the deep eutectic solvent (DES) used as the media. PbS superstructures can be excellent models for fundamental studies of nanoscale organization and SA manufacturing of (opto)electronics and energy harvesting devices which require organization of PbS components at multiple scales. PMID:22515512

Unknown aspects of self-assembly of PbS microscale superstructures.

PubMed

Querejeta-Fernández, Ana; Hernández-Garrido, Juan C; Yang, Hengxi; Zhou, Yunlong; Varela, Aurea; Parras, Marina; Calvino-Gámez, José J; González-Calbet, Jose M; Green, Peter F; Kotov, Nicholas A

2012-05-22

A lot of interesting and sophisticated examples of nanoparticle (NP) self-assembly (SA) are known. From both fundamental and technological standpoints, this field requires advancements in three principle directions: (a) understanding the mechanism and driving forces of three-dimensional (3D) SA with both nano- and microlevels of organization; (b) understanding disassembly/deconstruction processes; and (c) finding synthetic methods of assembly into continuous superstructures without insulating barriers. From this perspective, we investigated the formation of well-known star-like PbS superstructures and found a number of previously unknown or overlooked aspects that can advance the knowledge of NP self-assembly in these three directions. The primary one is that the formation of large seemingly monocrystalline PbS superstructures with multiple levels of octahedral symmetry can be explained only by SA of small octahedral NPs. We found five distinct periods in the formation PbS hyperbranched stars: (1) nucleation of early PbS NPs with an average diameter of 31 nm; (2) assembly into 100-500 nm octahedral mesocrystals; (3) assembly into 1000-2500 nm hyperbranched stars; (4) assembly and ionic recrystallization into six-arm rods accompanied by disappearance of fine nanoscale structure; (5) deconstruction into rods and cuboctahedral NPs. The switches in assembly patterns between the periods occur due to variable dominance of pattern-determining forces that include van der Waals and electrostatic (charge-charge, dipole-dipole, and polarization) interactions. The superstructure deconstruction is triggered by chemical changes in the deep eutectic solvent (DES) used as the media. PbS superstructures can be excellent models for fundamental studies of nanoscale organization and SA manufacturing of (opto)electronics and energy-harvesting devices which require organization of PbS components at multiple scales.

Impact of abutment rotation and angulation on marginal fit: theoretical considerations.

PubMed

Semper, Wiebke; Kraft, Silvan; Mehrhof, Jurgen; Nelson, Katja

2010-01-01

Rotational freedom of various implant positional index designs has been previously calculated. To investigate its clinical relevance, a three-dimensional simulation was performed to demonstrate the influence of rotational displacements of the abutment on the marginal fit of prosthetic superstructures. Idealized abutments with different angulations (0, 5, 10, 15, and 20 degrees) were virtually constructed (SolidWorks Office Premium 2007). Then, rotational displacement was simulated with various degrees of rotational freedom (0.7, 0.95, 1.5, 1.65, and 1.85 degrees). The resulting horizontal displacement of the abutment from the original position was quantified in microns, followed by a simulated pressure-less positioning of superstructures with defined internal gaps (5 µm, 60 µm, and 100 µm). The resulting marginal gap between the abutment and the superstructure was measured vertically with the SolidWorks measurement tool. Rotation resulted in a displacement of the abutment of up to 157 µm at maximum rotation and angulation. Interference of a superstructure with a defined internal gap of 5 µm placed on the abutment resulted in marginal gaps up to 2.33 mm at maximum rotation and angulation; with a 60-µm internal gap, the marginal gaps reached a maximum of 802 µm. Simulation using a superstructure with an internal gap of 100 µm revealed a marginal gap of 162 µm at abutment angulation of 20 degrees and rotation of 1.85 degrees. The marginal gaps increased with the degree of abutment angulation and the extent of rotational freedom. Rotational displacement of the abutment influenced prosthesis misfit. The marginal gaps between the abutment and the superstructure increased with the rotational freedom of the index and the angulation of the abutment.

Construction of sediment budgets for drainage basins

Treesearch

William E. Dietrich; Thomas Dunne; Neil F. Humphrey; Leslie M. Reid

1982-01-01

Abstract - A sediment budget for a drainage basin is a quantitative statement of the rates of production, transport, and discharge of detritus. To construct a sediment budget for a drainage basin, one must integrate the temporal and spatial variations of transport and storage processes. This requires: recognition and quantification of transport processes, recognition...

Ground Water Recharge Estimation Using Water Table Fluctuation Method And By GIS Applications

NASA Astrophysics Data System (ADS)

Vajja, V.; Bekkam, V.; Nune, R.; M. v. S, R.

2007-05-01

Quite often it has become a debating point that how much recharge is occurring to the groundwater table through rainfall on one hand and through recharge structures such as percolation ponds and checkdams on the other. In the present investigations Musi basin of Andhra Pradesh, India is selected for study during the period 2005-06. Pre-monsoon and Post-monsoon groundwater levels are collected through out the Musi basin at 89 locations covering an area11, 291.69 km2. Geology of the study area and rainfall data during the study period has been collected. The contour maps of rainfall and the change in groundwater level between Pre-monsoon and Post- monsoon have been prepared. First the change in groundwater storage is estimated for each successive strips of areas enclosed between two contours of groundwater level fluctuations. In this calculation Specific yield (Sy) values are adopted based on the local Geology. Areas between the contours are estimated through Arc GIS software package. All such storages are added to compute the total storage for the entire basin. In order to find out the percent of rainfall converted into groundwater storage as well as to find out the ground water recharge due to storageponds, a contour map of rainfall for the study area is prepared and areas between successive contours have been calculated. Based on the Geology map, Infiltration values are adopted for each successive strip of the contour area. Then the amount of water infiltrated into the ground is calculated by adjusting the infiltration values for each strip, so that the total infiltrated water for the entire basin is matched with change in Ground water storage, which is 1314.37 MCM for the upper Musi basin while it is 2827.29 MCM for entire Musi basin. With this procedure on an average 29.68 and 30.66 percent of Rainfall is converted into Groundwater recharge for Upper Musi and for entire Musi basin respectively. In the total recharge, the contribution of rainfall directly to Groundwater recharge is 8.53 and 8.81 percent and the remaining 21.15 and 21.85 percent is due to groundwater recharge from water conservation structures such as check dams, contour bunds, tanks, etc. for Upper Musi and for entire Musi basin respectively. The difference is attributable to the canal recharge in the case of Lower Musi. Therefore the Upper Musi values may be taken as a percent of Rainfall that is converted into Groundwater recharge.

40 CFR 745.230 - Work practice standards for conducting lead-based paint activities: public and commercial...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Work practice standards for conducting lead-based paint activities: public and commercial buildings, bridges and superstructures. [Reserved... and commercial buildings, bridges and superstructures. [Reserved] ...

9. WEST SIDE, TEST STAND AND SUPERSTRUCTURE. TEST STAND 1B ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. WEST SIDE, TEST STAND AND SUPERSTRUCTURE. TEST STAND 1-B IN DISTANCE. Looking east. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

40 CFR 745.230 - Work practice standards for conducting lead-based paint activities: public and commercial...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Work practice standards for conducting lead-based paint activities: public and commercial buildings, bridges and superstructures. [Reserved... and commercial buildings, bridges and superstructures. [Reserved] ...

Assembly of Nanorods into Designer Superstructures: The Role of Templating, Capillary Forces, Adhesion, and Polymer Hydration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ciszek, Jacob W.; Huang, Ling; Tsonchev, Stefan

The assembly mechanism by which hundreds of thousands of two-segment gold-polypyrrole nanorods are assembled into kinetically controlled shape-directed superstructures is examined to predict the range of nanoparticle sizes and materials that can be utilized in their formation. Four processes are responsible for assembly: templating, capillary force assembly, adhesion, and polymer hydration. It is shown that templating, where rods are prepositioned for assembly, is scale invariant and that the energy-minimized state after this step is highly disordered. In addition, we predict that superstructures can be made independently from patterns of rods separated by a distance as small as six times themore » inter-rod spacing. Both modeling and experiment show that adhesion and polymer dehydration, which induces curvature in the superstructures, are applicable to other materials. However, the high surface energy and low elastic modulus of polypyrrole are advantageous toward generating three-dimensional structures, inducing curvature at gold/polypyrrole length ratios as large as 7:1.« less

The adsorption and dissociation of oxygen on Ag (111) supported χ3 borophene

NASA Astrophysics Data System (ADS)

Luo, W. W.; Liu, G.; Wang, X.; Lei, X. L.; Ouyang, C. Y.; Liu, S. Q.

2018-05-01

The superstructure of χ3 borophene on Ag (111) has recently been synthesized in experiment. In this work, we investigate its structural, electronic properties and the oxidation mechanism through first-principles calculations. We find the superstructure of χ3 borophene on Ag (111) maintain the planar characteristics, like its free-standing form, owing to the weakly interaction between adsorbate and substrate. Moreover, oxygen molecule can be spontaneously adsorbed on its superstructure in a manner of chemical adsorption. Importantly, the energy barrier of ∼0.35 eV for oxygen dissociation indicates its relative stability in ambient conditions compared with the active silicene. Furthermore, the mobility of O2-dissociation-induced O atom is poor at room temperature, implying the difficult migration of O atom on borophene surface. On the other hand, due to the strong Bsbnd O bonding, desorption of O2-dissociation-induced O atoms on superstructure of χ3 borophene becomes impossible, ultimately leading to form the boron oxides.

Laser ablation synthesis of Si-overdoped Ni1- x O with rocksalt-type derived superstructures and tailored optical properties

NASA Astrophysics Data System (ADS)

Chang, Yu-Ling; Lin, Shih-Siang; Zheng, Yuyuan; Shen, Pouyan; Chen, Shuei-Yuan

2017-04-01

Si-overdoped Ni1- x O nanocondensates/particulates with novel superstructures were fabricated by pulsed laser ablation (PLA) of Ni in tetraethyl orthosilicate and characterized using electron microscopy and optical spectroscopy. The Si-overdoped and C-H-mediated Ni1- x O turned out to have two kinds of rocksalt-type derived superstructures, i.e., (1) 2 × 2 × 2 type of high-pressure stabilized Ni2SiO4 spinel which occurred as platy domains in the particles with {135} facets and (2) 3 × 3 × 3 type intimately mixed with 1D 6 × (100) throughout the particles with {100}, {110}, and {111} facets. Such shaped and superstructured particles, more or less encapsulated with graphitic carbon and siliceous amorphous phase, showed phase and dopant-tailored optical properties, in particular violet and green photoluminescence and UV-visible absorbance for potential engineering applications and shed light on their occurrence in natural dynamic settings.

Automatic recognition of ship types from infrared images using superstructure moment invariants

NASA Astrophysics Data System (ADS)

Li, Heng; Wang, Xinyu

2007-11-01

Automatic object recognition is an active area of interest for military and commercial applications. In this paper, a system addressing autonomous recognition of ship types in infrared images is proposed. Firstly, an approach of segmentation based on detection of salient features of the target with subsequent shadow removing is proposed, as is the base of the subsequent object recognition. Considering the differences between the shapes of various ships mainly lie in their superstructures, we then use superstructure moment functions invariant to translation, rotation and scale differences in input patterns and develop a robust algorithm of obtaining ship superstructure. Subsequently a back-propagation neural network is used as a classifier in the recognition stage and projection images of simulated three-dimensional ship models are used as the training sets. Our recognition model was implemented and experimentally validated using both simulated three-dimensional ship model images and real images derived from video of an AN/AAS-44V Forward Looking Infrared(FLIR) sensor.

3D superstructures with an orthorhombic lattice assembled by colloidal PbS quantum dots.

PubMed

Ushakova, Elena V; Cherevkov, Sergei A; Litvin, Aleksandr P; Parfenov, Peter S; Kasatkin, Igor A; Fedorov, Anatoly V; Gun'ko, Yurii K; Baranov, Alexander V

2018-05-03

We report a new type of metamaterial comprising a highly ordered 3D network of 3-7 nm lead sulfide quantum dots self-assembled in an organic matrix formed by amphiphilic ligands (oleic acid molecules). The obtained 3D superstructures possess an orthorhombic lattice with the distance between the nanocrystals as large as 10-40 nm. Analysis of self-assembly and destruction of the superstructures in time performed by a SAXS technique shows that their morphology depends on the quantity of amphiphilic ligands and width of the quantum dot size and its distribution. Formation of the superstructures is discussed in terms of a model describing the lyotropic crystal formation by micelles from three-phase mixtures. The results show that the organic molecules possessing surfactant properties and capable of forming micelles with nanoparticles as a micelle core can be utilized as building blocks for the creation of novel metamaterials based on a highly ordered 3D network of semiconductors, metals or magnetic nanoparticles.

Spatiotemporal Assessment of Groundwater Resources in the South Platte Basin, Colorado

NASA Astrophysics Data System (ADS)

Ruybal, C. J.; McCray, J. E.; Hogue, T. S.

2015-12-01

The South Platte Basin is one of the most economically diverse and fastest growing basins in Colorado. Strong competition for water resources in an over-appropriated system brings challenges to meeting future water demands. Balancing the conjunctive use of surface water and groundwater from the South Platte alluvial aquifer and the Denver Basin aquifer system is critical for meeting future demands. Over the past decade, energy development in the basin has added to the competition for water resources, highlighting the need to advance our understanding of the availability and sustainability of groundwater resources. Current work includes evaluating groundwater storage changes and recharge regimes throughout the South Platte Basin under competing uses, e.g. agriculture, oil and gas, urban, recreational, and environmental. The Gravity Recovery and Climate Experiment satellites in conjunction with existing groundwater data is used to evaluate spatiotemporal variability in groundwater storage and identify areas of high water stress. Spatiotemporal data will also be utilized to develop a high resolution groundwater model of the region. Results will ultimately help stakeholders in the South Platte Basin better understand groundwater resource challenges and contribute to Colorado's strategic future water planning.

Hierarchical super-structure identified by polarized light microscopy, electron microscopy and nanoindentation: Implications for the limits of biological control over the growth mode of abalone sea shells

PubMed Central

2012-01-01

Background Mollusc shells are commonly investigated using high-resolution imaging techniques based on cryo-fixation. Less detailed information is available regarding the light-optical properties. Sea shells of Haliotis pulcherina were embedded for polishing in defined orientations in order to investigate the interface between prismatic calcite and nacreous aragonite by standard materialographic methods. A polished thin section of the interface was prepared with a defined thickness of 60 μm for quantitative birefringence analysis using polarized light and LC-PolScope microscopy. Scanning electron microscopy images were obtained for comparison. In order to study structural-mechanical relationships, nanoindentation experiments were performed. Results Incident light microscopy revealed a super-structure in semi-transparent regions of the polished cross-section under a defined angle. This super-structure is not visible in transmitted birefringence analysis due to the blurred polarization of small nacre platelets and numerous organic interfaces. The relative orientation and homogeneity of calcite prisms was directly identified, some of them with their optical axes exactly normal to the imaging plane. Co-oriented "prism colonies" were identified by polarized light analyses. The nacreous super-structure was also visualized by secondary electron imaging under defined angles. The domains of the super-structure were interpreted to consist of crystallographically aligned platelet stacks. Nanoindentation experiments showed that mechanical properties changed with the same periodicity as the domain size. Conclusions In this study, we have demonstrated that insights into the growth mechanisms of nacre can be obtained by conventional light-optical methods. For example, we observed super-structures formed by co-oriented nacre platelets as previously identified using X-ray Photo-electron Emission Microscopy (X-PEEM) [Gilbert et al., Journal of the American Chemical Society 2008, 130:17519–17527]. Polarized optical microscopy revealed unprecedented super-structures in the calcitic shell part. This bears, in principle, the potential for in vivo studies, which might be useful for investigating the growth modes of nacre and other shell types. PMID:22967319

The effect of different screw-tightening techniques on the stress generated on an internal-connection implant superstructure.

PubMed

Choi, Jung-Han; Lim, Young-Jun; Kim, Chang-Whe; Kim, Myung-Joo

2009-01-01

This study evaluated the effect of different screw-tightening sequences, forces, and methods on the stresses generated on a well-fitting internal-connection implant (Astra Tech) superstructure. A metal framework directly connected to four parallel implants was fabricated on a fully edentulous mandibular resin model. Six stone casts with four implant replicas were made from a pickup impression of the superstructure to represent a "well-fitting" situation. Stresses generated by four screw-tightening sequences (1-2-3-4, 4-3-2-1, 2-4-3-1, and 2-3-1-4), two forces (10 and 20 Ncm), and two methods (one-step and two-step) were evaluated. In the two-step method, screws were tightened to the initial torque (10 Ncm) in a predetermined screw-tightening sequence and then to the final torque (20 Ncm) in the same sequence. Stresses were recorded twice by three strain gauges attached to the framework (superior face midway between abutments). Deformation data were analyzed using multiple analysis of variance at a .05 level of statistical significance. In all stone casts, stresses were produced by the superstructure connection, regardless of screw-tightening sequence, force, and method. No statistically significant differences for superstructure preload stresses were found based on screw-tightening sequences (-180.0 to -181.6 microm/m) or forces (-163.4 and -169.2 microm/m) (P > .05). However, different screw-tightening methods induced different stresses on the superstructure. The two-step screw-tightening method (-180.1 microm/m) produced significantly higher stress than the one-step method (-169.2 microm/m) (P = .0457). Within the limitations of this in vitro study, screw-tightening sequence and force were not critical factors in the stress generated on a well-fitting internal-connection implant superstructure. The stress caused by the two-step method was greater than that produced using the one-step method. Further studies are needed to evaluate the effect of screw-tightening techniques on preload stress in various different clinical situations.

Sediment fluxes from California Coastal Rivers: the influences of climate, geology, and topography

USGS Publications Warehouse

Andrews, E.D.; Antweiler, Ronald C.

2012-01-01

The influences of geologic and climatic factors on erosion and sedimentation processes in rivers draining the western flank of the California Coast Range are assessed. Annual suspended, bedload, and total sediment fluxes were determined for 16 river basins that have hydrologic records covering all or most of the period from 1950 to 2006 and have been relatively unaffected by flow storage, regulation, and depletion, which alter the downstream movement of water and sediment. The occurrence of relatively large annual sediment fluxes are strongly influenced by the El Nino–Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). The frequency of relatively large annual sediment fluxes decreases from north to south during La Nina phases and increases from north to south during El Nino phases. The influence of ENSO is modulated over a period of decades by the PDO, such that relatively large annual sediment fluxes are more frequent during a La Nina phase in conjunction with a cool PDO and during an El Nino phase in conjunction with a warm PDO. Values of mean annual sediment flux, , were regressed against basin and climatic characteristics. Basin area, bedrock erodibility, basin relief, and precipitation explain 87% of the variation in from the 16 river basins. Bedrock erodibility is the most significant characteristic influencing . Basin relief is a superior predictor of compared with basin slope. is nearly proportional to basin area and increases with increasing precipitation. For a given percentage change, basin relief has a 2.3-fold greater effect on than a similar change in precipitation. The estimated natural from all California coastal rivers for the period 1950–2006 would have been approximately 85 million tons without flow storage, regulation, and depletion; the actual has been approximately 50 million tons, because of the effects of flow storage, regulation, and depletion.

The effect of sulfated polysaccharides on the crystallization of calcite superstructures

NASA Astrophysics Data System (ADS)

Fried, Ruth; Mastai, Yitzhak

2012-01-01

Calcite with unique morphology and uniform size has been successfully synthesized in the presence of classes of polysaccharides based on carrageenans. In the crystallization of calcite, the choice of different carrageenans, (iota, lambda and kappa), as additives concedes systematic study of the influence of different chemical structures and particularly molecular charge on the formation of CaCO 3 crystals. The uniform calcite superstructures are formed by assemblies and aggregation of calcite crystals. The mechanism for the formation of calcite superstructures was studied by a variety of techniques, SEM, TEM, XRD, time-resolved conductivity and light scattering measurements, focusing on the early stages of crystals' nucleation and aggregation.

Structure Analyses of Highly Symmetric Superstructures Formed by Rodlike Mesogen

NASA Astrophysics Data System (ADS)

Saito, Kazuya; Kutsumizu, Shoichi

Process of structure determination of liquid-crystalline superstructures formed in a mesogenic series, bis(n-alkoxybenzoyl)hydrazine[BABH(n) ; n, the number of carbon atoms in the alkoxy group], is described. The chain-length (n) dependence of relative diffraction intensities from the Ia3d phase resolves the phase problem, leading to the structural description that the molecular centers are on the rods forming two interpenetrating jungle gyms. Theoretical consideration on the stability of superstructures and systematic MEM analysis reveal the coexistence of two aggregation modes (rods forming an extending jungle gym and closed sheets forming spherical shells) for the Im3m phase.

CO2 Adsorption in Low-Rank Coals: Progress Toward Assessing the National Capacity to Store CO2 in the Subsurface

NASA Astrophysics Data System (ADS)

Stanton, R. W.; Burruss, R. C.; Flores, R. M.; Warwick, P. D.

2001-05-01

Subsurface environments for geologic storage of CO2 from combustion of fossil fuel include saline formations, depleted oil and gas reservoirs, and unmineable coalbeds. Of these environments, storage in petroleum reservoirs and coal beds offers a potential economic benefit of enhanced recovery of energy resources. Meaningful assessment of the volume and geographic distribution of storage sites requires quantitative estimates of geologic factors that control storage capacity. The factors that control the storage capacity of unmineable coalbeds are poorly understood. In preparation for a USGS assessment of CO2 storage capacity we have begun new measurements of CO2 and CH4 adsorption isotherms of low-rank coal samples from 4 basins. Initial results for 13 samples of low-rank coal beds from the Powder River Basin (9 subbituminous coals), Greater Green River Basin (1 subbituminous coal), Williston Basin (2 lignites) and the Gulf Coast (1 lignite) indicate that their adsorption capacity is up to 10 times higher than it is for CH4. These values contrast with published measurements of the CO2 adsorption capacity of bituminous coals from the Fruitland Formation, San Juan basin, and Gates Formation, British Columbia, that indicate about twice as much carbon dioxide as methane can be adsorbed on coals. Because CH4 adsorption isotherms are commonly measured on coals, CO2 adsorption capacity can be estimated if thecorrect relationship between the gases is known. However, use a factor to predict CO2 adsorption that is twice that of CH4 adsorption, which is common in the published literature, grossly underestimates the storage capacity of widely distributed, thick low-rank coal beds. Complete petrographic and chemical characterization of these low-rank coal samples is in progress. Significant variations in adsorption measurements among samples are depicted depending on the reporting basis used. Properties were measured on an "as received" (moist) basis but can be converted to a dry basis, ash-free basis (moist), or dry ash-free basis to emphasize the property having the greatest effect on the adsorption isotherm. Initial results show that moisture content has a strong effect on CO2 adsorption. Our current sample base covers a limited range of coal rank and composition. Full characterization of the storage capacity of coalbeds in the US will require additional samples that cover a broader range of coal compositions, ranks, and depositional environments. Even at this preliminary stage, we can use results from the recent USGS assessment of the Powder River Basin (Wyoming and Montana) to examine the impact of these new measurements on estimates of storage capacity. At depths greater than 500 feet, the Wyodak-Anderson coal zone contains 360 billion metric tons of coal. Using the new measurements of CO2 storage capacity, this coal zone could, theoretically, sequester about 290 trillion cubic feet (TCF) of CO2. This estimate contrasts sharply with an estimated capacity of 70 TCF based on the published values for bituminous coals.

National assessment of geologic carbon dioxide storage resources: summary

USGS Publications Warehouse

,

2013-01-01

The U.S. Geological Survey (USGS) recently completed an evaluation of the technically accessible storage resource (TASR) for carbon dioxide (CO2) for 36 sedimentary basins in the onshore areas and State waters of the United States. The TASR is an estimate of the geologic storage resource that may be available for CO2 injection and storage and is based on current geologic and hydrologic knowledge of the subsurface and current engineering practices. By using a geology-based probabilistic assessment methodology, the USGS assessment team members obtained a mean estimate of approximately 3,000 metric gigatons (Gt) of subsurface CO2 storage capacity that is technically accessible below onshore areas and State waters; this amount is more than 500 times the 2011 annual U.S. energy-related CO2 emissions of 5.5 Gt (U.S. Energy Information Administration, 2012, http://www.eia.gov/environment/emissions/carbon/). In 2007, the Energy Independence and Security Act (Public Law 110–140) directed the U.S. Geological Survey to conduct a national assessment of geologic storage resources for CO2 in consultation with the U.S. Environmental Protection Agency, the U.S. Department of Energy, and State geological surveys. The USGS developed a methodology to estimate storage resource potential in geologic formations in the United States (Burruss and others, 2009, USGS Open-File Report (OFR) 2009–1035; Brennan and others, 2010, USGS OFR 2010–1127; Blondes, Brennan, and others, 2013, USGS OFR 2013–1055). In 2012, the USGS completed the assessment, and the results are summarized in this Fact Sheet and are provided in more detail in companion reports (U.S. Geological Survey Geologic Carbon Dioxide Storage Resources Assessment Team, 2013a,b; see related reports at right). The goal of this project was to conduct an initial assessment of storage capacity on a regional basis, and results are not intended for use in the evaluation of specific sites for potential CO2 storage. The national assessment was a geology-based examination of all sedimentary basins in the onshore and State waters area of the United States that contain storage assessment units (SAUs) that could be defined according to geologic and hydrologic characteristics. Although geologic storage of CO2 may be possible in some areas not assessed by the USGS, the SAUs identified in this assessment represent those areas within sedimentary basins that met the assessment criteria. A geologic description of each SAU was prepared; descriptions for SAUs in several basins are in Warwick and Corum (2012, USGS OFR 2012–1024).

2. NORTH FRONT, FROM SUPERSTRUCTURE TO FLAME DEFLECTOR. Looking south ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. NORTH FRONT, FROM SUPERSTRUCTURE TO FLAME DEFLECTOR. Looking south southwest from Observation Post No. 1 (Building 8767). - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

Multi Canister Overpack (MCO) Topical Report [SEC 1 THRU 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

LORENZ, B.D.

In February 1995, the US Department of Energy (DOE) approved the Spent Nuclear Fuel (SNF) Project's ''Path Forward'' recommendation for resolution of the safety and environmental concerns associated with the deteriorating SNF stored in the Hanford Site's K Basins (Hansen 1995). The recommendation included an aggressive series of projects to design, construct, and operate systems and facilitates to permit the safe retrieval, packaging, transport, conditions, and interim storage of the K Basins' SNF. The facilities are the Cold VAcuum Drying Facility (CVDF) in the 100 K Area of the Hanford Site and the Canister Storage building (CSB) in the 200more » East Area. The K Basins' SNF is to be cleaned, repackaged in multi-canister overpacks (MCOs), removed from the K Basins, and transported to the CVDF for initial drying. The MCOs would then be moved to the CSB and weld sealed (Loscoe 1996) for interim storage (about 40 years). One of the major tasks associated with the initial Path Forward activities is the development and maintenance of the safety documentation. In addition to meeting the construction needs for new structures, the safety documentation for each must be generated.« less

Dynamic Nanoparticles Assemblies

PubMed Central

WANG, LIBING; XU, LIGUANG; KUANG, HUA; XU, CHUANLAI; KOTOV, NICHOLAS A.

2012-01-01

CONSPECTUS Importance Although nanoparticle (NP) assemblies are at the beginning of their development, their unique geometrical shapes and media-responsive optical, electronic and magnetic properties have attracted significant interest. Nanoscale assembly bridges multiple sizes of materials: individual nanoparticles, discrete molecule-like or virus-like nanoscale agglomerates, microscale devices, and macroscale materials. The capacity to self-assemble can greatly facilitate the integration of nanotechnology with other technologies and, in particular, with microscale fabrication. In this Account, we describe developments in the emerging field of dynamic NP assemblies, which are spontaneously formed superstructures containing more than two inorganic nanoscale particles that display ability to change their geometrical, physical, chemical, and other attributes. In many ways, dynamic assemblies can represent a bottleneck in the ‘bottom-up’ fabrication of NP-based devices because they can produce a much greater variety of assemblies, but they also provide a convenient tool for variation of geometries and dimensions of nanoparticle assemblies. Classification Superstructures of NPs (and those held together by similar intrinsic forces) are classified into two groups: Class 1 where media and external fields can alter shape, conformation, and order of stable superstructures with a nearly constant number same. The future development of successful dynamic assemblies requires understanding the equilibrium in dynamic NP systems. The dynamic nature of Class 1 assemblies is associated with the equilibrium between different conformations of a superstructure and is comparable to the isomerization in classical chemistry. Class 2 assemblies involve the formation and/or breakage of linkages between the NPs, which is analogous to the classical chemical equilibrium for the formation of a molecule from atoms. Finer classification of NP assemblies in accord with established conventions in the field may include different size dimensionalities: discrete assemblies (artificial molecules), one-dimensional (spaced chains) and two-dimensional (sheets) and three-dimensional (superlattices, twisted structures) assemblies. Notably, these dimensional attributes must be regarded as primarily topological in nature because all of these superstructures can acquire complex three-dimensional shapes. Preparation We discuss three primary strategies used to prepare NP superstructures: (1) anisotropy-based assemblies utilizing either intrinsic force field anisotropy around NPs or external anisotropy associated with templates and/or applied fields; (2) assembly methods utilizing uniform NPs with isotropic interactions; and (3) methods based on mutual recognition of biomolecules, such as DNA and antigen-antibody interactions. Applications We consider optical, electronic, and magnetic properties of dynamic superstructures, focusing primarily on multiparticle effects in NP superstructures as represented by surface plasmon resonance, NP-NP charge transport, and multibody magnetization. Unique properties of NP superstructures are being applied to biosensing, drug delivery, and nanoelectronics. For both Class 1 and Class 2 dynamic assemblies, biosensing is the most dominant and well-developed area of dynamic nanostructures being successfully transitioned into practice. We can foresee the rapid development of dynamic NP assemblies toward applications in harvesting of dissipated energy, photonics, and electronics. The final part of the review is devoted to the fundamental questions facing dynamic assemblies of NPs in the future. PMID:22449243

Evolvement rules of basin flood risk under low-carbon mode. Part I: response of soil organic carbon to land use change and its influence on land use planning in the Haihe basin.

PubMed

Li, Fawen; Wang, Liping; Zhao, Yong

2017-08-01

Soil organic carbon (SOC) plays an important role in the global carbon cycle. The aim of this study was to evaluate the response of SOC to land use change and its influence on land use planning in the Haihe basin, and provide planning land use pattern for basin flood risk assessment. Firstly, the areas of different land use types in 1980, 2008, and the planning year (2020) were counted by area statistics function of ArcGIS. Then, the transfer matrixes of land use were produced by spatial overlay analysis function. Lastly, based on the land use maps, soil type map and soil profile database, SOC storage of different land use types in three different periods were calculated. The results showed the patterns of land use have changed a lot from 1980 to 2008, among the 19,835 km 2 of grassland was transformed into forestland, which was the largest conversion landscape. And land use conversion brought the SOC storage changes. Total carbon source was 88.83 Tg, and total carbon sink was 85.49 Tg. So, the Haihe basin presented as a carbon source from 1980 to 2008. From 2008 to 2020, the changes of forestland and grassland are the biggest in Haihe basin, which cause the SOC pool change from a carbon source to a carbon sink. SOC storage will increase from 2420.5 Tg in 2008 to 2495.5 Tg in 2020. The changing trend is conducive to reducing atmospheric concentrations. Therefore, land use planning in Haihe basin is reasonable and can provide the underlying surface condition for flood risk assessment.

Water Chemistry Control System for Recovery of Damaged and Degraded Spent Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sindelar, R.; Fisher, D.; Thomas, J.

2011-02-18

The International Atomic Energy Agency (IAEA) and the government of Serbia have led the project cosponsored by the U.S, Russia, European Commission, and others to repackage and repatriate approximately 8000 spent fuel elements from the RA reactor fuel storage basins at the VIN?A Institute of Nuclear Sciences to Russia for reprocessing. The repackaging and transportation activities were implemented by a Russian consortium which includes the Sosny Company, Tekhsnabeksport (TENEX) and Mayak Production Association. High activity of the water of the fuel storage basin posed serious risk and challenges to the fuel removal from storage containers and repackaging for transportation. Themore » risk centered on personnel exposure, even above the basin water, due to the high water activity levels caused by Cs-137 leached from fuel elements with failed cladding. A team of engineers from the U.S. DOE-NNSA's Global Threat Reduction Initiative, the Vinca Institute, and the IAEA performed the design, development, and deployment of a compact underwater water chemistry control system (WCCS) to remove the Cs-137 from the basin water and enable personnel safety above the basin water for repackaging operations. Key elements of the WCCS system included filters, multiple columns containing an inorganic sorbent, submersible pumps and flow meters. All system components were designed to be remotely serviceable and replaceable. The system was assembled and successfully deployed at the Vinca basin to support the fuel removal and repackaging activities. Following the successful operations, the Cs-137 is now safely contained and consolidated on the zeolite sorbent used in the columns of the WCCS, and the fuel has been removed from the basins. This paper reviews the functional requirements, design, and deployment of the WCCS.« less

Global models underestimate large decadal declining and rising water storage trends relative to GRACE satellite data

PubMed Central

Scanlon, Bridget R.; Zhang, Zizhan; Save, Himanshu; Sun, Alexander Y.; van Beek, Ludovicus P. H.; Wiese, David N.; Reedy, Robert C.; Longuevergne, Laurent; Döll, Petra; Bierkens, Marc F. P.

2018-01-01

Assessing reliability of global models is critical because of increasing reliance on these models to address past and projected future climate and human stresses on global water resources. Here, we evaluate model reliability based on a comprehensive comparison of decadal trends (2002–2014) in land water storage from seven global models (WGHM, PCR-GLOBWB, GLDAS NOAH, MOSAIC, VIC, CLM, and CLSM) to trends from three Gravity Recovery and Climate Experiment (GRACE) satellite solutions in 186 river basins (∼60% of global land area). Medians of modeled basin water storage trends greatly underestimate GRACE-derived large decreasing (≤−0.5 km3/y) and increasing (≥0.5 km3/y) trends. Decreasing trends from GRACE are mostly related to human use (irrigation) and climate variations, whereas increasing trends reflect climate variations. For example, in the Amazon, GRACE estimates a large increasing trend of ∼43 km3/y, whereas most models estimate decreasing trends (−71 to 11 km3/y). Land water storage trends, summed over all basins, are positive for GRACE (∼71–82 km3/y) but negative for models (−450 to −12 km3/y), contributing opposing trends to global mean sea level change. Impacts of climate forcing on decadal land water storage trends exceed those of modeled human intervention by about a factor of 2. The model-GRACE comparison highlights potential areas of future model development, particularly simulated water storage. The inability of models to capture large decadal water storage trends based on GRACE indicates that model projections of climate and human-induced water storage changes may be underestimated. PMID:29358394

Global models underestimate large decadal declining and rising water storage trends relative to GRACE satellite data.

PubMed

Scanlon, Bridget R; Zhang, Zizhan; Save, Himanshu; Sun, Alexander Y; Müller Schmied, Hannes; van Beek, Ludovicus P H; Wiese, David N; Wada, Yoshihide; Long, Di; Reedy, Robert C; Longuevergne, Laurent; Döll, Petra; Bierkens, Marc F P

2018-02-06

Assessing reliability of global models is critical because of increasing reliance on these models to address past and projected future climate and human stresses on global water resources. Here, we evaluate model reliability based on a comprehensive comparison of decadal trends (2002-2014) in land water storage from seven global models (WGHM, PCR-GLOBWB, GLDAS NOAH, MOSAIC, VIC, CLM, and CLSM) to trends from three Gravity Recovery and Climate Experiment (GRACE) satellite solutions in 186 river basins (∼60% of global land area). Medians of modeled basin water storage trends greatly underestimate GRACE-derived large decreasing (≤-0.5 km 3 /y) and increasing (≥0.5 km 3 /y) trends. Decreasing trends from GRACE are mostly related to human use (irrigation) and climate variations, whereas increasing trends reflect climate variations. For example, in the Amazon, GRACE estimates a large increasing trend of ∼43 km 3 /y, whereas most models estimate decreasing trends (-71 to 11 km 3 /y). Land water storage trends, summed over all basins, are positive for GRACE (∼71-82 km 3 /y) but negative for models (-450 to -12 km 3 /y), contributing opposing trends to global mean sea level change. Impacts of climate forcing on decadal land water storage trends exceed those of modeled human intervention by about a factor of 2. The model-GRACE comparison highlights potential areas of future model development, particularly simulated water storage. The inability of models to capture large decadal water storage trends based on GRACE indicates that model projections of climate and human-induced water storage changes may be underestimated. Copyright © 2018 the Author(s). Published by PNAS.

40 CFR 745.229 - Certification of individuals and firms engaged in lead-based paint activities: public and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Certification of individuals and firms engaged in lead-based paint activities: public and commercial buildings, bridges and superstructures... paint activities: public and commercial buildings, bridges and superstructures. [Reserved] ...

3. DETAIL OF NORTH FRONT AND WEST SIDE, WITH SUPERSTRUCTURE, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. DETAIL OF NORTH FRONT AND WEST SIDE, WITH SUPERSTRUCTURE, FROM NEAR OBSERVATION POST NO. 3. Looking south southeast from below. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

15. SUPERSTRUCTURE PLANS, ELEVATION AND DETAILS, SHEET 4 OF 117, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. SUPERSTRUCTURE PLANS, ELEVATION AND DETAILS, SHEET 4 OF 117, 1920. - Sacramento River Water Treatment Plant Intake Pier & Access Bridge, Spanning Sacramento River approximately 175 feet west of eastern levee on river; roughly .5 mile downstream from confluence of Sacramento & American Rivers, Sacramento, Sacramento County, CA

Evaluation of effects of super-heavy loading on the US 41 bridge over the White River : appendices.

DOT National Transportation Integrated Search

2011-01-01

Built in 1958, the US-41 White River Bridge is a two-girder, riveted steel structure located in Hazelton, IN. The bridge is comprised of two, sixteen span superstructures sharing a common substructure. Each superstructure also contains four pin and h...

Evaluation of effects of super-heavy loading on the US 41 bridge over the White River.

DOT National Transportation Integrated Search

2011-01-01

Built in 1958, the US-41 White River Bridge is a two-girder, riveted steel structure located in Hazelton, IN. The bridge is comprised of two, sixteen span : superstructures sharing a common substructure. Each superstructure also contains four pin and...

Looking northeast from Test Stand 'A' superstructure towards Test Stand ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Looking northeast from Test Stand 'A' superstructure towards Test Stand 'D' tower (4223/E-24, left background), Test Stand 'C' tower (4217/E-18, center), and Test Stand 'B' (4215/E-16, right foreground). - Jet Propulsion Laboratory Edwards Facility, Edwards Air Force Base, Boron, Kern County, CA

Evaluation of the performance of a press-lam timber bridge : interim report no. 1, bridge installation and load test.

DOT National Transportation Integrated Search

1977-01-01

The report describes the installation and load test of the world's first press-lam timber bridge superstructure. A five-man crew replaced the substandard steel stringer-timber deck superstructure on Rte. 610 over Little Stoney Creek in Shenandoah Cou...

Globalisation in Africa: Reflecting on Peter Jarvis's Superstructure and Substructure Model

ERIC Educational Resources Information Center

Preece, Julia

2017-01-01

This paper reflects on Peter Jarvis' book "Globalisation, lifelong learning and the learning society," volume 2--in which he describes human learning within a global context and factors contributing to globalisation. He describes the relationship of power between countries manifested as the superstructure and sub structure. The paper…

Optically Reconfigurable Chiral Microspheres of Self-Organized Helical Superstructures with Handedness Inversion.

PubMed

Wang, Ling; Chen, Dong; Gutierrez-Cuevas, Karla G; Bisoyi, Hari Krishna; Fan, Jing; Zola, Rafael S; Li, Guoqiang; Urbas, Augustine M; Bunning, Timothy J; Weitz, David A; Li, Quan

2017-01-01

Optically reconfigurable monodisperse chiral microspheres of self-organized helical superstructures with dynamic chirality were fabricated via a capillary-based microfluidic technique. Light-driven handedness-invertible transformations between different configurations of microspheres were vividly observed and optically tunable RGB photonic cross-communications among the microspheres were demonstrated.

Marxian Approaches to Education.

ERIC Educational Resources Information Center

Carnoy, Martin

Traditional Marxist approaches to the state relegate superstructural institutions like the school to a minor role in the process of social change. More recent theories like those of Gramsci, Althusser, and Poulantzas raise the state and the class struggle in the state apparatuses to a much more prominent position: superstructure, including the…

Evaluation of effects of super-heavy loading on the US 41 bridge over the White River : technical summary.

DOT National Transportation Integrated Search

2011-01-01

Built in 1958, the US-41 White River Bridge is a two-girder, riveted steel structure located near Hazelton, IN. The bridge is comprised of two, sixteen span superstructures sharing a common substructure. Each superstructure also contains four pin and...

40 CFR 745.229 - Certification of individuals and firms engaged in lead-based paint activities: public and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Certification of individuals and firms engaged in lead-based paint activities: public and commercial buildings, bridges and superstructures... paint activities: public and commercial buildings, bridges and superstructures. [Reserved] ...

12. A CLOSE UP VIEW OF THE IRON SUPERSTRUCTURE OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. A CLOSE UP VIEW OF THE IRON SUPERSTRUCTURE OF THIS CAMELBACK TRUSS BRIDGE. THIS PHOTO SHOWS A DETAIL OF THE LATTICE WORK, AND AN INTERESTING CURVED BRACE MEMBER. - Freedom Bridge, Spanning West Fork of White River at County Road 590 South, Freedom, Owen County, IN

Geomechanical Framework for Secure CO 2 Storage in Fractured Reservoirs and Caprocks for Sedimentary Basins in theMidwest United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sminchak, Joel

This report presents final technical results for the project Geomechanical Framework for Secure CO 2 Storage in Fractured Reservoirs and Caprocks for Sedimentary Basins in the Midwest United States (DE-FE0023330). The project was a three-year effort consisting of seven technical tasks focused on defining geomechanical factors for CO 2 storage applications in deep saline rock formations in Ohio and the Midwest United States, because geomechancial issues have been identified as a significant risk factor for large-scale CO 2 storage applications. A basin-scale stress-strain analysis was completed to describe the geomechanical setting for rock formations of Ordovician-Cambrian age in Ohio andmore » adjacent areas of the Midwest United States in relation to geologic CO 2 storage applications. The tectonic setting, stress orientation-magnitude, and geomechanical and petrophysical parameters for CO 2 storage zones and caprocks in the region were cataloged. Ten geophysical image logs were analyzed for natural fractures, borehole breakouts, and drilling-induced fractures. The logs indicated mostly less than 10 fractures per 100 vertical feet in the borehole, with mostly N65E principal stress orientation through the section. Geophysical image logs and other logs were obtained for three wells located near the sites where specific models were developed for geomechanical simulations: Arches site in Boone County, Kentucky; Northern Appalachian Basin site in Chautauqua County, New York; and E-Central Appalachian Basin site in Tuscarawas County, Ohio. For these three wells, 9,700 feet of image logs were processed and interpreted to provide a systematic review of the distribution within each well of natural fractures, wellbore breakouts, faults, and drilling induced fractures. There were many borehole breakouts and drilling-induced tensile fractures but few natural fractures. Concentrated fractures were present at the Rome-basal sandstone and basal sandstone-Precambrian contacts at the Arches and East-Central Appalachian Basin sites. Geophysical logs were utilized to develop local-scale geologic models by determining geomechanical and petrophysical parameters within the geologic formations. These data were ported to coupled fluid-flow and reservoir geomechanics multi-phase CO 2 injection simulations. The models were developed to emphasize the geomechanical layers within the CO 2 storage zones and caprocks. A series of simulations were completed for each site to evaluate whether commercial-scale CO 2 could be safely injected into each site, given site-specific geologic and geomechanical controls. This involved analyzing the simulation results for the integrity of the caprock, intermediate, and reservoir zones, as well quantifying the areal uplift at the surface. Simulation results were also examined to ensure that the stress-stress perturbations were isolated within the subsurface, and that there was only limited upward migration of the CO 2. Simulations showed capacity to inject more than 10 million metric tons of CO 2 in a single well at the Arches and East Central Appalachian Basin sites without excessive geomechanical risks. Low-permeability rock layers at the Northern Appalachian Basin study area well resulted in very low CO 2 injection capacity. Fracture models developed for the sites suggests that the sites have sparse fracture network in the deeper Cambrian rocks. However, there were indicators in image logs of a moderate fracture matrix in the Rose Run Sandstone at the Northern Appalachian Basin site. Dual permeability fracture matrix simulations suggest the much higher injection rates may be feasible in the fractured interval. Guidance was developed for geomechanical site characterization in the areas of geophysical logging, rock core testing, well testing, and site monitoring. The guidance demonstrates that there is a suitable array of options for addressing geomechanical issues at CO 2 storage sites. Finally, a review of Marcellus and Utica-Point Pleasant shale gas wells and CO 2 storage intervals indicates that these items are vertically separated, except for the Oriskany sandstone and Marcellus wells in southwest Pennsylvania and northern West Virginia. Together, project results present a more realistic portrayal of geomechanical risk factors related to CO 2 storage for existing and future coal-fired power plants in Ohio.« less

A Comparison of Groundwater Storage Using GRACE Data, Groundwater Levels, and a Hydrological Model in Californias Central Valley

NASA Technical Reports Server (NTRS)

Kuss, Amber; Brandt, William; Randall, Joshua; Floyd, Bridget; Bourai, Abdelwahab; Newcomer, Michelle; Skiles, Joseph; Schmidt, Cindy

2011-01-01

The Gravity Recovery and Climate Experiment (GRACE) measures changes in total water storage (TWS) remotely, and may provide additional insight to the use of well-based data in California's agriculturally productive Central Valley region. Under current California law, well owners are not required to report groundwater extraction rates, making estimation of total groundwater extraction difficult. As a result, other groundwater change detection techniques may prove useful. From October 2002 to September 2009, GRACE was used to map changes in TWS for the three hydrological regions (the Sacramento River Basin, the San Joaquin River Basin, and the Tulare Lake Basin) encompassing the Central Valley aquifer. Net groundwater storage changes were calculated from the changes in TWS for each of the three hydrological regions and by incorporating estimates for additional components of the hydrological budget including precipitation, evapotranspiration, soil moisture, snow pack, and surface water storage. The calculated changes in groundwater storage were then compared to simulated values from the California Department of Water Resource's Central Valley Groundwater- Surface Water Simulation Model (C2VSIM) and their Water Data Library (WDL) Geographic Information System (GIS) change in storage tool. The results from the three methods were compared. Downscaling GRACE data into the 21 smaller Central Valley sub-regions included in C2VSIM was also evaluated. This work has the potential to improve California's groundwater resource management and use of existing hydrological models for the Central Valley.

Geologic Storage at the Basin Scale: Region-Based Basin Modeling, Powder River Basin (PRB), NE Wyoming and SE Montana

NASA Astrophysics Data System (ADS)

Melick, J. J.; Gardner, M. H.

2008-12-01

Carbon capture and storage from the over 2000 power plants is estimated at 3-5 GT/yr, which requires large- scale geologic storage of greenhouse gasses in sedimentary basins. Unfortunately, determination of basin scale storage capacity is currently based on oversimplified geologic models that are difficult to validate. Simplification involves reducing the number of geologic parameters incorporated into the model, modeling with large grid cells, and treatment of subsurface reservoirs as homogeneous media. The latter problem reflects the focus of current models on fluid and/or fluid-rock interactions rather than fluid movement and migration pathways. For example, homogeneous models over emphasize fluid behavior, like the buoyancy of super-critical CO2, and hence overestimate leakage rates. Fluid mixing and fluid-rock interactions cannot be assessed with models that only investigate these reactions at a human time scale. Preliminary and conservative estimates of the total pore volume for the PRB suggest 200 GT of supercritical CO2 can be stored in this typical onshore sedimentary basin. The connected pore volume (CPV) however is not included in this estimate. Geological characterization of the CPV relates subsurface storage units to the most prolific reservoir classes (RCs). The CPV, number of well penetrations, supercritical storage area, and potential leakage pathways characterize each RC. Within each RC, a hierarchy of stratigraphic cycles is populated with stationary sedimentation regions that control rock property distributions by correlating environment of deposition (EOD) to CPV. The degree to which CPV varies between RCs depends on the geology and attendant heterogeneity retained in the fluid flow model. Region-based modeling of the PRB incorporates 28000 wells correlated across a 70,000 Km2 area, 2 km thick on average. Within this basin, five of the most productive RCs were identified from production history and placed in a fourfold stratigraphic framework (second- through fourth-order cycles). Within the small- scale 4th-order sequences (30-150-m thick, 16 total), sedimentation regions, each corresponding to an EOD, are defined by thickness, lithology and core-calibrated well-log patterns. This talk illustrates the workflow by focusing on one of the 16 layers in the basin-scale model. Isopach maps from this sample layer conform to depositional patterns confirmed through definition of five core-calibrated, well-log defined sedimentation regions. Lithology distributions also conform to thickness trends in nearshore deltas, but not in offshore regions, where sand-rich and sheet-like, but thin-bedded sandstones are flanked by mud-rich intervals of equivalent thickness. These maps represent sedimentation patterns confined by basal erosional sequence boundary and basin-wide bentonite, yet containing up to seven high-frequency sequence boundaries. To illustrate over simplification problems in this same layer, a 14000 km2 sample area is 600 km3 and using standard averaging methods, which are considered to be geologic in origin, the CPV is 16 km3. However, averaging increases connectivity with high CPV more uniformly distributed; significantly, the key mud belt region separating nearshore from offshore sandstones is not represented. Region-based modeling of this layer yields 13 km3 (110 Bbl). Furthermore, significant vertical leakage may exist from the 20000 well penetrations and faults and fractures along the western basin margin. This example illustrates the importance of accurately characterizing heterogeneity and distributing CPV using sedimentation regions.

Groundwater and surface-water interaction and potential for underground water storage in the Buena Vista-Salida Basin, Chaffee County, Colorado, 2011

USGS Publications Warehouse

Watts, Kenneth R.; Ivahnenko, Tamara I.; Stogner, Sr., Robert W.; Bruce, James F.

2014-01-01

By 2030, the population of the Arkansas Headwaters Region, which includes all of Chaffee and Lake Counties and parts of Custer, Fremont, and Park Counties, Colorado, is forecast to increase about 73 percent. As the region’s population increases, it is anticipated that groundwater will be used to meet much of the increased demand. In September 2009, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District and with support from the Colorado Water Conservation Board; Chaffee, Custer, and Fremont Counties; Buena Vista, Cañon City, Poncha Springs, and Salida; and Round Mountain Water and Sanitation District, began a 3-year study of groundwater and surface-water conditions in the Buena Vista-Salida Basin. This report presents results from the study of the Buena Vista-Salida Basin including synoptic gain-loss measurements and water budgets of Cottonwood, Chalk, and Browns Creeks, changes in groundwater storage, estimates of specific yield, transmissivity and hydraulic conductivity from aquifer tests and slug tests, an evaluation of areas with potential for underground water storage, and estimates of stream-accretion response-time factors for hypothetical recharge and selected streams in the basin. The four synoptic measurements of flow of Cottonwood, Chalk, and Browns Creeks, suggest quantifiable groundwater gains and losses in selected segments in all three perennial streams. The synoptic measurements of flow of Cottonwood and Browns Creeks suggest a seasonal variability, where positive later-irrigation season values in these creeks suggest groundwater discharge, possibly as infiltrated irrigation water. The overall sum of gains and losses on Chalk Creek does not indicate a seasonal variability but indicates a gaining stream in April and August/September. Gains and losses in the measured upper segments of Chalk Creek likely are affected by the Chalk Cliffs Rearing Unit (fish hatchery). Monthly water budgets were estimated for selected segments of five perennial streams (Cottonwood, North Cottonwood, Chalk, and Browns Creeks, and South Arkansas River) in the Buena Vista-Salida Basin for calendar year 2011. Differences between reported diversions and estimated crop irrigation requirements were used to estimate groundwater recharge in the areas irrigated by water supplied from the diversions. The amount of groundwater recharge in all the basins varied monthly; however, the greatest amount of recharge was during June and July for Cottonwood, North Cottonwood, and Chalk Creeks and South Arkansas River. The greatest amount of recharge in 2011 in Browns Creek occurred in July and August. The large seasonal fluctuations of groundwater near irrigated areas in the Buena Vista-Salida Basin indicate that the increased groundwater storage resulting from infiltration of surface-water diversions has dissipated by the following spring. Areas within the Buena Vista-Salida Basin with the potential for underground storage were identified using geographic information system data, including topographic, geologic, and hydrologic data, excluding the mountainous areas that border the Buena Vista-Salida Basin and igneous and metamorphic rock outcrop areas. The areas that met the selection criteria for underground water storage are located on terrace deposits near the Arkansas River and adjacent to its major tributaries. The selected areas also contain much of the irrigated land within the basin; consequently, irrigation ditches and canals could provide a means of conveying water to potential recharge sites.

Global analysis of approaches for deriving total water storage changes from GRACE satellites and implications for groundwater storage change estimation

NASA Astrophysics Data System (ADS)

Long, D.; Scanlon, B. R.; Longuevergne, L.; Chen, X.

2015-12-01

Increasing interest in use of GRACE satellites and a variety of new products to monitor changes in total water storage (TWS) underscores the need to assess the reliability of output from different products. The objective of this study was to assess skills and uncertainties of different approaches for processing GRACE data to restore signal losses caused by spatial filtering based on analysis of 1°×1° grid scale data and basin scale data in 60 river basins globally. Results indicate that scaling factors from six land surface models (LSMs), including four models from GLDAS-1 (Noah 2.7, Mosaic, VIC, and CLM 2.0), CLM 4.0, and WGHM, are similar over most humid, sub-humid, and high-latitude regions but can differ by up to 100% over arid and semi-arid basins and areas with intensive irrigation. Large differences in TWS anomalies from three processing approaches (scaling factor, additive, and multiplicative corrections) were found in arid and semi-arid regions, areas with intensive irrigation, and relatively small basins (e.g., ≤ 200,000 km2). Furthermore, TWS anomaly products from gridded data with CLM4.0 scaling factors and the additive correction approach more closely agree with WGHM output than the multiplicative correction approach. Estimation of groundwater storage changes using GRACE satellites requires caution in selecting an appropriate approach for restoring TWS changes. A priori ground-based data used in forward modeling can provide a powerful tool for explaining the distribution of signal gains or losses caused by low-pass filtering in specific regions of interest and should be very useful for more reliable estimation of groundwater storage changes using GRACE satellites.

Constructing molecular structures on periodic superstructure of graphene/Ru(0001)

PubMed Central

Li, Geng; Huang, Li; Xu, Wenyan; Que, Yande; Zhang, Yi; Lu, Jianchen; Du, Shixuan; Liu, Yunqi; Gao, Hong-Jun

2014-01-01

We review the way to fabricate large-scale, high-quality and single crystalline graphene epitaxially grown on Ru(0001) substrate. A moiré pattern of the graphene/Ru(0001) is formed due to the lattice mismatch between graphene and Ru(0001). This superstructure gives rise to surface charge redistribution and could behave as an ordered quantum dot array, which results in a perfect template to guide the assembly of organic molecular structures. Molecules, for example iron phthalocyanine and C60, on this template show how the molecule–substrate interaction makes different superstructures. These results show the possibility of constructing ordered molecular structures on graphene/Ru(0001), which is helpful for practical applications in the future. PMID:24615151

Measuring Water Storage in the Amazon

NASA Image and Video Library

2010-07-07

This image is from data taken by NASA Gravity Recovery and Climate Experiment showing the Amazon basin in South America. The amount of water stored in the Amazon basin varies from month to month. Animations are available at the Photojournal.

76 FR 48855 - Questar Pipeline Company; Notice of Request Under Blanket Authorization

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-09

... gas to be stored at its Clay Basin storage reservoir and increase the maximum certificated shut-in pressure of Clay Basin located in Daggett County, Utah. The request was made pursuant to the blanket...

Understanding Subsurface Flow Mechanisms by Studying Recession Flow Curves

NASA Astrophysics Data System (ADS)

patnaik, S.; Biswal, B.; D, N.

2013-12-01

The recession flows offer valuable information on the subsurface systems of the drainage which cannot be observed due to technological limitations. Many analytical frameworks have been proposed in the past to analyze recession flow curves assess. Among them the most widely used one is Brutsaert-Neiber method of expressing negative time derivative of Q (discharge at the basin outlet at time t), -dQ/dt, as a function of Q itself, which eliminates the need of finding a reference time. Typically, basins across geographical regions display a power law relationship of the type: -dQ/dt = kQ^α. For a particular basin, the exponent α remains fairly constant recession events while the coefficient k varies greatly from one recession event to another, indicating the dynamic nature -dQ/dt-Q relationship. Recent observations show that subsurface storage in a basin mainly controls the dynamic parameter k. As subsurface water takes long time to fully drain, k of a recession event can also be influenced by the storage that occurred during the past rainfall events. We indirectly analyze the effect of past storage on recession flow by considering past streamflow as a proxy of past storage. A stronger relationship implies that the basin is able to store water for longer duration, and vice versa. In this study, we used streamflow data from 388 USGS basins that are relatively unaffected by human activities to find out the factors that affect the relationship between the power law correlation (R^2_PN) between past discharge and k, where the subscript N is the number of days of past streamflow observations considered for the recession event. For most of the basins R^2_PN decreases with N. We then selected 18 physical and climatological parameters for each study basin and investigated how they influence the value of R^2_PN for each N. We followed multiple linear regression method and found that R^2_PN is strongly influenced by the selected parameters (R^2 = 0.58) for N =30 days. We also employed principal component analysis to identify influence of individual parameters on R^2_PN. Our findings strongly indicate the possibility of understanding subsurface flow mechanism by merely analyzing recession flow curves.

Monitoring groundwater storage changes in the highly dynamic Bengal Basin: validation of GRACE measurements

NASA Astrophysics Data System (ADS)

Shamsudduha, M.; Taylor, R. G.; Longuevergne, L.

2011-12-01

Monitoring of spatio-temporal changes in terrestrial water storage (ΔTWS) provides valuable information regarding the basin-scale dynamics of hydrological systems. Recent satellite measurements of the ΔTWS under the Gravity Recovery and Climate Experiment (GRACE) enable the derivation of groundwater storage changes (ΔGWS) where in situ data are limited. In the well monitored and highly-dynamic Bengal Basin of Bangladesh, we test the ability of GRACE measurements to trace the seasonality and trend in groundwater storage associated with intensive groundwater abstraction for dry-season irrigation and wet-season (monsoonal) recharge. Two different GRACE products (CSR and GRGS) and data processing methods (gridded and spherical harmonics) are also compared. Results show that GRACE derived estimates of recent (2003 to 2007) ΔGWS correlate well (r=0.77 to 0.93, p-value <0.0001) with borehole-derived estimates from a network of 236 monitoring stations in Bangladesh. The highest correlation (r=0.93, p-value <0.0001) and lowest root mean square error (<4 cm) are realized using a spherical harmonic product of CSR for these estimates. ΔGWS accounts for 44% of the total variation in ΔTWS in the Bengal Basin. Changes in surface water storage (ΔSWS) estimated from a network of 298 river gauging stations and soil moisture storage (ΔSMS) derived from Land Surface Models explain 22% and 33% of ΔTWS respectively. Groundwater depletion estimated from borehole hydrographs (-0.52±0.30 km3/yr) is within the range of satellite-derived estimates (-0.44 to -2.04 km3/yr) that result from uncertainty associated with ΔSMS (CLM, NOAH, VIC) and GRACE data processing techniques. Recent (2003 to 2007) estimates of groundwater depletion are substantially greater than the long-term (1985 to 2007) mean (-0.21±0.03 km3/yr) and are explained primarily by substantial increases in groundwater abstraction for the dry-season irrigation and drinking water supplies over the last two decades.

Geologic framework for the national assessment of carbon dioxide storage resources: Columbia Basin of Oregon, Washington, and Idaho, and the Western Oregon-Washington basins: Chapter D in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Covault, Jacob A.; Blondes, Madalyn S.; Cahan, Steven M.; DeVera, Christina A.; Freeman, P.A.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2013-01-01

The 2007 Energy Independence and Security Act (Public Law 110–140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO2). The methodology used by the USGS for the national CO2 assessment follows that of previous USGS work. The methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of three storage assessment units (SAUs) in Eocene and Oligocene sedimentary rocks within the Columbia, Puget, Willapa, Astoria, Nehalem, and Willamette Basins of Oregon, Washington, and Idaho, and focuses on the characteristics, specified in the methodology, that influence the potential CO2 storage resource in those SAUs. Specific descriptions of the SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are provided to illustrate geologic factors critical to the assessment. The designated sealing unit in the Columbia Basin is tentatively chosen to be the ubiquitous and thick Miocene Columbia River Basalt Group. As a result of uncertainties regarding the seal integrity of the Columbia River Basalt Group, the SAUs were not quantitatively assessed. Figures in this report show SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one square mile and are derived from interpretations of incompletely attributed well data, a digital compilation that is known not to include all drilling. The USGS does not expect to know the location of all wells and cannot guarantee the amount of drilling through specific formations in any given cell shown on the cell maps.

Sensitive analysis of low-flow parameters using the hourly hydrological model for two mountainous basins in Japan

NASA Astrophysics Data System (ADS)

Fujimura, Kazumasa; Iseri, Yoshihiko; Kanae, Shinjiro; Murakami, Masahiro

2014-05-01

Accurate estimation of low flow can contribute to better water resources management and also lead to more reliable evaluation of climate change impacts on water resources. In the early study, the nonlinearity of low flow related to the storage in the basin was suggested by Horton (1937) as the exponential function of Q=KSN, where Q is the discharge, S is the storage, K is a constant and N is the exponent value. In the recent study by Ding (2011) showed the general storage-discharge equation of Q = KNSN. Since the constant K is defined as the fractional recession constant and symbolized as Au by Ando et al. (1983), in this study, we rewrite this equation as Qg=AuNSgN, where Qg is the groundwater runoff and Sg is the groundwater storage. Although this equation was applied to a short-term runoff event of less than 14 hours using the unit hydrograph method by Ding, it was not yet applied for a long-term runoff event including low flow more than 10 years. This study performed a sensitive analysis of two parameters of the constant Au and exponent value N by using the hourly hydrological model for two mountainous basins in Japan. The hourly hydrological model used in this study was presented by Fujimura et al. (2012), which comprise the Diskin-Nazimov infiltration model, groundwater recharge and groundwater runoff calculations, and a direct runoff component. The study basins are the Sameura Dam basin (SAME basin) (472 km2) located in the western Japan which has variability of rainfall, and the Shirakawa Dam basin (SIRA basin) (205km2) located in a region of heavy snowfall in the eastern Japan, that are different conditions of climate and geology. The period of available hourly data for the SAME basin is 20 years from 1 January 1991 to 31 December 2010, and for the SIRA basin is 10 years from 1 October 2003 to 30 September 2013. In the sensitive analysis, we prepared 19900 sets of the two parameters of Au and N, the Au value ranges from 0.0001 to 0.0100 in steps of 0.0001 and the N value ranges from 1.0 to 100.0 in steps of 0.5. The analysis was evaluated by the Average of Daily runoff Relative Error (ADRE). The results showed that the minimum value of the ADRE is 32.199% using N=100.0 and Au=0.0003 for the SAME basin, and is 38.058% using N=0.0003 and Au=70.0 for the SIRA basin. Log-log plot for optimal sets of Au and N suggested accurate simulation of low flow can be achieved when relation of Au and N are in exponential form. The equations are Au=1/{26.91N1.041} and Au=1/{34.55N1.060} for each basin, which have similar gradients, but have different intercept on the log-log graph. From this study, it is found that the optimal sets of Au and N, which obtained lower relative error in the hydrological analysis, are formulated using the exponent equation. Acknowledgements This work was supported by the Research Program on Climate Change Adaption (the RECCA Project) of the Ministry of Education, Culture, Sports, Science and Technology. References Ding, J. Y. (2011) A measure of watershed nonlinearity: interpreting a variable instantaneous unit hydrograph model on two vastly different sized watersheds. Hydrol. Earth Syst. Sci., 15, 405-423. Fujimura, K., Shiraha, K., Kanae, S. & Murakami, M. (2012) Development of the hourly hydrological model for mountainous basins using the storage function method and the Diskin-Nazimov infiltration model. In: Models - Repositories of Knowledge, IAHS Publ. 355, 338-344. Horton, R. E. (1936) Natural stream channel-storage. Trans. Am. Geophys. Union, 17, 406-415. Ando, Y., Musiake, K. & Takahasi, Y. (1983) Modelling of hydrologic processes in a small natural hillslope basin, based on the synthesis of partial hydrological relationships. Journal of Hydrology, 64, 311-337.

Bridging the gap between small and large scale sediment budgets? - A scaling challenge in the Upper Rhone Basin, Switzerland

NASA Astrophysics Data System (ADS)

Schoch, Anna; Blöthe, Jan; Hoffmann, Thomas; Schrott, Lothar

2016-04-01

A large number of sediment budgets have been compiled on different temporal and spatial scales in alpine regions. Detailed sediment budgets based on the quantification of a number of sediment storages (e.g. talus cones, moraine deposits) exist only for a few small scale drainage basins (up to 10² km²). In contrast, large scale sediment budgets (> 10³ km²) consider only long term sediment sinks such as valley fills and lakes. Until now, these studies often neglect small scale sediment storages in the headwaters. However, the significance of these sediment storages have been reported. A quantitative verification whether headwaters function as sediment source regions is lacking. Despite substantial transport energy in mountain environments due to steep gradients and high relief, sediment flux in large river systems is frequently disconnected from alpine headwaters. This leads to significant storage of coarse-grained sediment along the flow path from rockwall source regions to large sedimentary sinks in major alpine valleys. To improve the knowledge on sediment budgets in large scale alpine catchments and to bridge the gap between small and large scale sediment budgets, we apply a multi-method approach comprising investigations on different spatial scales in the Upper Rhone Basin (URB). The URB is the largest inneralpine basin in the European Alps with a size of > 5400 km². It is a closed system with Lake Geneva acting as an ultimate sediment sink for suspended and clastic sediment. We examine the spatial pattern and volumes of sediment storages as well as the morphometry on the local and catchment-wide scale. We mapped sediment storages and bedrock in five sub-regions of the study area (Goms, Lötschen valley, Val d'Illiez, Vallée de la Liène, Turtmann valley) in the field and from high-resolution remote sensing imagery to investigate the spatial distribution of different sediment storage types (e.g. talus deposits, debris flow cones, alluvial fans). These sub-regions cover all three litho-tectonic units of the URB (Helvetic nappes, Penninic nappes, External massifs) and different catchment sizes to capture the inherent variability. Different parameters characterizing topography, surface characteristics, and vegetation cover are analyzed for each storage type. The data is then used in geostatistical models (PCA, stepwise logistic regression) to predict the spatial distribution of sediment storage for the whole URB. We further conduct morphometric analyses of the URB to gain information on the varying degree of glacial imprint and postglacial landscape evolution and their control on the spatial distribution of sediment storage in a large scale drainage basin. Geophysical methods (ground penetrating radar and electrical resistivity tomography) are applied on different sediment storage types on the local scale to estimate mean thicknesses. Additional data from published studies are used to complement our dataset. We integrate the local data in the statistical model on the spatial distribution of sediment storages for the whole URB. Hence, we can extrapolate the stored sediment volumes to the regional scale in order to bridge the gap between small and large scale studies.

Designing timber highway bridge superstructures using AASHTO?LRFD specifications

Treesearch

James P. Wacker; James S. Groenier

2007-01-01

The allowable-stress design methodology that has been used for decades to design timber bridge superstructures is being replaced in the near future. Beginning in October 2007, bridge designers will be required by the Federal Highway Administration (FHWA) to utilize the Load and Resistance Factor Design (LRFD) design specifications published by the American Association...

46 CFR 42.15-15 - Positions of hatchways, doorways and ventilators.

Code of Federal Regulations, 2010 CFR

2010-10-01

... exposed superstructure decks situated forward of a point located a quarter of the vessel's length from the forward perpendicular. (2) Position 2: Upon exposed superstructure decks situated abaft a quarter of the vessel's length from the forward perpendicular. [CGFR 68-60, 33 FR 10060, July 12, 1968, as amended by...

46 CFR 42.15-15 - Positions of hatchways, doorways and ventilators.

Code of Federal Regulations, 2011 CFR

2011-10-01

... exposed superstructure decks situated forward of a point located a quarter of the vessel's length from the forward perpendicular. (2) Position 2: Upon exposed superstructure decks situated abaft a quarter of the vessel's length from the forward perpendicular. [CGFR 68-60, 33 FR 10060, July 12, 1968, as amended by...

Incommensurate structure of a lillianite-type samarium chromium sulfide Sm{sub 2/3}Cr{sub 2}S{sub 4}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lafond, A.; Cario, L.; Meerschaut, A.

1996-12-01

The structure of Sm{sub 2/3}Cr{sub 2}S{sub 4} has been solved from single-crystal X-ray diffraction data. This compound presents a 3 X a superstructure along a and an incommensurate superstructure along b close to 3 x b. The basic structure is described in the space group Pmnb with a = 3.5030(3) {Angstrom}, b = 10.9199(8) {Angstrom}, c = 12.7987(8) {Angstrom}, Z = 4, R = 0.046 for 916 observed reflections. The modulated structure refinement, taking into account the two superstructures, was carried out in a (3 + 2)D superspace group and leads to R = 0.063 for 1706 reflections. This structuremore » consists of staggered double columns of [CrS{sub 6}] octahedra connected by samarium atoms in a trigonal prismatic bicapped environment. This structure is reminiscent of that found in the lillianite mineral family. The statistical occupancy of samarium atoms (1/3), in agreement with the charge equilibrium (Sm{sup 3+}, Cr{sup 3+}, S{sup 2-}), is related to the superstructure.« less

Geologic framework for the national assessment of carbon dioxide storage resources: Denver Basin, Colorado, Wyoming, and Nebraska: Chapter G in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Drake II, Ronald M.; Brennan, Sean T.; Covault, Jacob A.; Blondes, Madalyn S.; Freeman, P.A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.

2014-01-01

This is a report about the geologic characteristics of five storage assessment units (SAUs) within the Denver Basin of Colorado, Wyoming, and Nebraska. These SAUs are Cretaceous in age and include (1) the Plainview and Lytle Formations, (2) the Muddy Sandstone, (3) the Greenhorn Limestone, (4) the Niobrara Formation and Codell Sandstone, and (5) the Terry and Hygiene Sandstone Members. The described characteristics, as specified in the methodology, affect the potential carbon dioxide storage resource in the SAUs. The specific geologic and petrophysical properties of interest include depth to the top of the storage formation, average thickness, net-porous thickness, porosity, permeability, groundwater quality, and the area of structural reservoir traps. Descriptions of the SAU boundaries and the overlying sealing units are also included. Assessment results are not contained in this report; however, the geologic information included here will be used to calculate a statistical Monte Carlo-based distribution of potential storage volume in the SAUs.

Implications of GRACE Satellite Gravity Measurements for Diverse Hydrological Applications

NASA Astrophysics Data System (ADS)

Yirdaw-Zeleke, Sitotaw

Soil moisture plays a major role in the hydrologic water balance and is the basis for most hydrological models. It influences the partitioning of energy and moisture inputs at the land surface. Because of its importance, it has been used as a key variable for many hydrological studies such as flood forecasting, drought studies and the determination of groundwater recharge. Therefore, spatially distributed soil moisture with reasonable temporal resolution is considered a valuable source of information for hydrological model parameterization and validation. Unfortunately, soil moisture is difficult to measure and remains essentially unmeasured over spatial and temporal scales needed for a number of hydrological model applications. In 2002, the Gravity Recovery And Climate Experiment (GRACE) satellite platform was launched to measure, among other things, the gravitational field of the earth. Over its life span, these orbiting satellites have produced time series of mass changes of the earth-atmosphere system. The subsequent outcome of this, after integration over a number of years, is a time series of highly refined images of the earth's mass distribution. In addition to quantifying the static distribution of mass, the month-to-month variation in the earth's gravitational field are indicative of the integrated value of the subsurface total water storage for specific catchments. Utilization of these natural changes in the earth's gravitational field entails the transformation of the derived GRACE geopotential spherical harmonic coefficients into spatially varying time series estimates of total water storage. These remotely sensed basin total water storage estimates can be routinely validated against independent estimates of total water storage from an atmospheric-based water balance approach or from well calibrated macroscale hydrologic models. The hydrological relevance and implications of remotely estimated GRACE total water storage over poorly gauged, wetland-dominated watershed as well as over a deltaic region underlain by a thick sand aquifer in Western Canada are the focus of this thesis. The domain of the first case study was the Mackenzie River Basin wherein the GRACE total water storage estimates were successfully inter-compared and validated with the atmospheric based water balance. These were then used to assess the WAT-CLASS hydrological model estimates of total water storage. The outcome of this inter-comparison revealed the potential application of the GRACE-based approach for the closure of the hydrological water balance of the Mackenzie River Basin as well as a dependable source of data for the calibration of traditional hydrological models. The Mackenzie River Basin result led to a second case study where the GRACE-based total water storage was validated using storage estimated from the atmospheric-based water balance P--E computations in conjunction with the measured streamflow records for the Saskatchewan River Basin at its Grand Rapids outlet in Manitoba. The fallout from this comparison was then applied to the characterization of the Prairie-wide 2002/2003 drought enabling the development of a new drought index now known as the Total Storage Deficit Index (TSDI). This study demonstrated the potential application of the GRACE-based technique as a tool for drought characterization in the Canadian Prairies. Finally, the hydroinformatic approach based on the artificial neural network (ANN) enabled the downscaling of the groundwater component from the total water storage estimate from the remote sensing satellite, GRACE. This was subsequently explored as an alternate source of calibration and validation for a hydrological modeling application over the Assiniboine Delta Aquifer in Manitoba. Interestingly, a high correlation exists between the simulated groundwater storage from the coupled hydrological model, CLM-PF and the downscaled groundwater time series storage from the remote sensing satellite GRACE over this 4,000 km2 deltaic basin in Canada.

Impact of extreme precipitation events in the Miño-Sil river basin

NASA Astrophysics Data System (ADS)

Fernández-González, Manuel; Añel, Juan Antonio; de la Torre, Laura

2015-04-01

We herein research the impact of extreme rainfall events in the Miño-Sil basin, a heavily dammed basin located in the northwestern Iberian Peninsula. Extreme rainfall events are very important in this basin because with 106 dams it is the most dammed in Spain. These dams are almost exclusively used for hydropower generation, the installed generating capacity reaches more than 2700 MW and represents almost 9% of the total installed electrical generation capacity of the Iberian Peninsula, therefore with a potential impact on the energy market. We research the extreme events of rainfall an their return periods trying to reproduce the past extreme events of rainfall and their time periods to prove the proper functioning of the adapted model, so we can forecast future extreme events of rainfall in the basin. This research tries to optimize the storage of dams and adapt the management to problems as climate change. The results obtained are very relevant for hydroelectric generation because the operation of hydropower system depends primarily on the availability of storaged water.

Increased Water Storage in the Qaidam Basin, the North Tibet Plateau from GRACE Gravity Data

PubMed Central

Jiao, Jiu Jimmy; Zhang, Xiaotao; Liu, Yi; Kuang, Xingxing

2015-01-01

Groundwater plays a key role in maintaining the ecology and environment in the hyperarid Qaidam Basin (QB). Indirect evidence and data from sparse observation wells suggest that groundwater in the QB is increasing but there has been no regional assessment of the groundwater conditions in the entire basin because of its remoteness and the severity of the arid environment. Here we report changes in the spatial and temporal distribution of terrestrial water storage (TWS) in the northern Tibetan Plateau (NTP) using Gravity Recovery and Climate Experiment (GRACE) data. Our study confirms long-term (2003–2012) TWS increases in the NTP. Between 2003 and 2012 the TWS increased by 88.4 and 20.6 km3 in the NTP and the QB, respectively, which is 225% and 52% of the capacity of the Three Gorges Reservoir, respectively. Soil and water changes from the Global Land Data Assimilation System (GLDAS) were also used to identify groundwater storage in the TWS and to demonstrate a long-term increase in groundwater storage in the QB. We demonstrate that increases in groundwater, not lake water, are dominant in the QB, as observed by groundwater levels. Our study suggests that the TWS increase was likely caused by a regional increase in precipitation and a decrease in evaporation. Degradation of the permafrost increases the thickness of the active layers providing increased storage for infiltrated precipitation and snow and ice melt water, which may also contribute to the increased TWS. The huge increase of water storage in the NTP will have profound effects, not only on local ecology and environment, but also on global water storage and sea level changes. PMID:26506230

Increased Water Storage in the Qaidam Basin, the North Tibet Plateau from GRACE Gravity Data.

PubMed

Jiao, Jiu Jimmy; Zhang, Xiaotao; Liu, Yi; Kuang, Xingxing

2015-01-01

Groundwater plays a key role in maintaining the ecology and environment in the hyperarid Qaidam Basin (QB). Indirect evidence and data from sparse observation wells suggest that groundwater in the QB is increasing but there has been no regional assessment of the groundwater conditions in the entire basin because of its remoteness and the severity of the arid environment. Here we report changes in the spatial and temporal distribution of terrestrial water storage (TWS) in the northern Tibetan Plateau (NTP) using Gravity Recovery and Climate Experiment (GRACE) data. Our study confirms long-term (2003-2012) TWS increases in the NTP. Between 2003 and 2012 the TWS increased by 88.4 and 20.6 km3 in the NTP and the QB, respectively, which is 225% and 52% of the capacity of the Three Gorges Reservoir, respectively. Soil and water changes from the Global Land Data Assimilation System (GLDAS) were also used to identify groundwater storage in the TWS and to demonstrate a long-term increase in groundwater storage in the QB. We demonstrate that increases in groundwater, not lake water, are dominant in the QB, as observed by groundwater levels. Our study suggests that the TWS increase was likely caused by a regional increase in precipitation and a decrease in evaporation. Degradation of the permafrost increases the thickness of the active layers providing increased storage for infiltrated precipitation and snow and ice melt water, which may also contribute to the increased TWS. The huge increase of water storage in the NTP will have profound effects, not only on local ecology and environment, but also on global water storage and sea level changes.

Hydrogeologic framework and preliminary simulation of ground-water flow in the Mimbres Basin, southwestern New Mexico

USGS Publications Warehouse

Hanson, R.T.; McLean, J.S.; Miller, Ryan S.

1994-01-01

The bolson-fill aquifer, the major water-yielding unit in the Mimbres Basin, southwestern New Mexico, ranges in thickness from 0 to about 3,700 feet. Recharge to the bolson-fill aquifer occurs by infiltration of ephemeral streams that cross the basin margin, infiltration from precipitation and streamflow, ground-water underflow from adjacent basins, and infiltration of springflow from adjacent bedrock units within the basin. Ground water generally flows southward from the northern highland areas of the basin. Ground-water discharge consists of pumpage from wells, transpiration by plants, outflow to playas and springs in the Los Muertos Basin in Mexico, discharge to the Mimbres River, and ground-water flow to the Mesilla Basin near Mason Draw. Before 1910, ground-water recharge and discharge were approximately equal; by 1975, however, about 75 percent of the 146,000 acre-feet withdrawn annually was ground water, most of it from aquifer storage. The transmissivity of the bolson-fill aquifer determined from aquifer tests and specific-capacity data ranges from 10 to 50,000 feet squared per day. Hydraulic conductivity, calculated from saturated thickness and transmissivity, ranges from 0.03 to 800 feet per day, with median values of about 18 feet per day in the Deming area and 6 feet per day elsewhere. Reported storage-coefficient values representing confined parts of the aquifer range from 0.00036 to 0.0036, and those representing unconfined parts of the aquifer range from 0.02 to 0.24. Water quality in the north and central parts of the Mimbres Basin is suitable for most uses. Due to its large salinity and alkalinity, some of the ground water in the south and southeastern areas of the bolson-fill aquifer may not be suitable for irrigation or domestic use. A preliminary two-dimensional digital model was constructed to evaluate ground-water flow in the bolson-fill aquifer. The model was divided into zones of uniform hydraulic conductivity corresponding to the major structural elements of the basin. For simulation purposes, hydraulic conductivity in the central part of the basin ranged from 2.2 to 4.4 feet per day, whereas locally along the edges of the aquifer less certain values ranged from 0.003 to 62 feet per day Analysis of the results of this predevelopment model indicated that use of the mountain-front recharge method overestimates total recharge and that evapotranspiration is substantial. The simulated total inflow was about 55 percent of that estimated in a water budget for the Mimbres Basin.Ground-water development between 1930 and 1985 was simulated using storage-coefficient values of 0.01 and 0.02 for the Gila Conglomerate, 0.04 to 0.17 for bolson-fill deposits, and 0.001 for bolson fill capped with lacustrine clay. The simulated transient water budget indicated that most of the water pumped by 1985 came from storage, and lesser but substantial amounts came from reductions in evapotranspiration.

A point-infiltration model for estimating runoff from rainfall on small basins in semiarid areas of Wyoming

USGS Publications Warehouse

Rankl, James G.

1990-01-01

A physically based point-infiltration model was developed for computing infiltration of rainfall into soils and the resulting runoff from small basins in Wyoming. The user describes a 'design storm' in terms of average rainfall intensity and storm duration. Information required to compute runoff for the design storm by using the model include (1) soil type and description, and (2) two infiltration parameters and a surface-retention storage parameter. Parameter values are tabulated in the report. Rainfall and runoff data for three ephemeral-stream basins that contain only one type of soil were used to develop the model. Two assumptions were necessary: antecedent soil moisture is some long-term average, and storm rainfall is uniform in both time and space. The infiltration and surface-retention storage parameters were determined for the soil of each basin. Observed rainstorm and runoff data were used to develop a separation curve, or incipient-runoff curve, which distinguishes between runoff and nonrunoff rainfall data. The position of this curve defines the infiltration and surface-retention storage parameters. A procedure for applying the model to basins that contain more than one type of soil was developed using data from 7 of the 10 study basins. For these multiple-soil basins, the incipient-runoff curve defines the infiltration and retention-storage parameters for the soil having the highest runoff potential. Parameters were defined by ranking the soils according to their relative permeabilities and optimizing the position of the incipient-runoff curve by using measured runoff as a control for the fit. Analyses of runoff from multiple-soil basins indicate that the effective contributing area of runoff is less than the drainage area of the basin. In this study, the effective drainage area ranged from 41.6 to 71.1 percent of the total drainage area. Information on effective drainage area is useful in evaluating drainage area as an independent variable in statistical analyses of hydrologic data, such as annual peak frequency distributions and sediment yield.A comparison was made of the sum of the simulated runoff and the sum of the measured runoff for all available records of runoff-producing storms in the 10 study basins. The sums of the simulated runoff ranged from 12.0 percent less than to 23.4 percent more than the sums of the measured runoff. A measure of the standard error of estimate was computed for each data set. These values ranged from 20 to 70 percent of the mean value of the measured runoff. Rainfall-simulator infiltrometer tests were made in two small basins. The amount of water uptake measured by the test in Dugout Creek tributary basin averaged about three times greater than the amount of water uptake computed from rainfall and runoff data. Therefore, infiltrometer data were not used to determine infiltration rates for this study.

A study of the Flint River, Michigan, as it relates to low-flow augmentation

USGS Publications Warehouse

Hulbert, Gordon C.

1972-01-01

One of the uses of the Flint River is dilution of waste-water. Population and industrial growth in the Flint area hah placed new demands on the stream and emphasized the need for an analysis of the surface water resources of the basin. This report describes selected streamflow characteristics of the Flint River and its tributaries, and presents draft-storage relations for the river basin. Flow characteristics for 17 sites show that the 7-day 2-year low flow ranges from 0 to 0.17 cfs (cubic feet per second) per square mile. Draft-storage relations for the basin show that existing storage, if fully utilized, could, on an average, provide a minimum discharge at Montrose of 160 cfs in 19 out of 20 years. The discharge, in conjunction with water diverted from Lake Huron to the Flint River through the Detroit and Flint water systems (about 60 cfs in 1971), indicates that low flows would seldom be less than about 200 cfs at Montrose. Diversions from the basin for irrigation may reduce low flows by about 12 cfs. Ground-water sources offer small potential for development of large supplies of water for streamflow augmentation, although wells in the glacial deposits may provide a supplemental source of water at some locations.

Sediment storage quantification and postglacial evolution of an inner-alpine sedimentary basin (Gradenmoos, Schober Mountains, Austria)

NASA Astrophysics Data System (ADS)

Götz, J.; Buckel, J.; Otto, J. C.; Schrott, L.

2012-04-01

Knickpoints in longitudinal valley profiles of alpine headwater catchments can be frequently assigned to the lithological and tectonical setting, to damming effects through large (rockfall) deposits, or to the impact of Pleistocene glaciations causing overdeepened basins. As a consequence various sedimentary sinks developed, which frequently interrupt sediment flux in alpine drainage basins. Today these locations may represent landscape archives documenting a sedimentary history of great value for the understanding of alpine landscape evolution. The glacially overdeepened Gradenmoos basin at 1920 m a.s.l. (an alpine lake mire with adjacent floodplain deposits and surrounding slope storage landforms; approx. 4.1 km2) is the most pronounced sink in the studied Gradenbach catchment (32.5 km2). The basin is completely filled up with sediments delivered by mainly fluvial processes, debris flows, and rock falls, it is assumed to be deglaciated since Egesen times and it is expected to archive a continuous stratigraphy of postglacial sedimentation. As the analysis of denudation-accumulation-systems is generally based on back-calculation of stored sediment volumes to a specific sediment delivering area, most reliable results will be consequently obtained (1) if sediment output of the system can be neglected for the investigated period of time, (2) if - due to spatial scale - sediment storage can be assessed quantitatively with a high level of accuracy, and (3) if the sediment contributing area can be clearly delimited. All three aspects are considered to be fulfilled to a high degree within the Gradenmoos basin. Sediment storage is quantified using geophysical methods, core drillings and GIS modelling whereas postglacial reconstruction is based on radiocarbon dating and palynological analyses. Subject to variable subsurface conditions, different geophysical methods were applied to detect bedrock depth. Electrical resistivity surveying (2D/3D) was used most extensively as it delivered detailed and realistic subsurface models with low residual errors in the fine grained and water saturated central and distal part of the basin. With a lower data density, ground penetrating radar and refraction seismic supplied bedrock depths underneath adjacent debris and talus slope deposits. Additionally extracted sediment cores (up to 22 m depth) yielded a detailed stratigraphic record of the basin comprising a basal till layer underneath lake sediments (sandy-silty, partly varved), a sandy matrix with several oxidised layers in the upper sections, and layers of peat towards the surface. As bedrock was reached several times, core drilling further enabled to calibrate resistivity models. On the base of geophysical derived bedrock points, the shape of the assumed bedrock basin was modelled using a thin-plate-spline interpolation. Sediment volumes were calculated by subtracting the bedrock model from a surface DEM derived from terrestrial laser scanning. Since sediment delivering areas can be clearly assigned to single storage landform volumes, denudation rates could be calculated in detail and related to sedimentation rates obtained by radiocarbon dating results. An integrated analysis of surface, subsurface and temporal information finally yielded a model of postglacial basin evolution which will be discussed in a paraglacial context. This presentation is supported by the EUROCORES programme TOPO-EUROPE of the European Science Foundation.

46 CFR 174.080 - Flooding on self-elevating and surface type units.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 7 2014-10-01 2014-10-01 false Flooding on self-elevating and surface type units. 174... Drilling Units § 174.080 Flooding on self-elevating and surface type units. (a) On a surface type unit or... superstructure deck where superstructures are fitted must be assumed to be subject to simultaneous flooding. (b...

46 CFR 174.080 - Flooding on self-elevating and surface type units.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 7 2011-10-01 2011-10-01 false Flooding on self-elevating and surface type units. 174... Drilling Units § 174.080 Flooding on self-elevating and surface type units. (a) On a surface type unit or... superstructure deck where superstructures are fitted must be assumed to be subject to simultaneous flooding. (b...

46 CFR 174.080 - Flooding on self-elevating and surface type units.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 7 2012-10-01 2012-10-01 false Flooding on self-elevating and surface type units. 174... Drilling Units § 174.080 Flooding on self-elevating and surface type units. (a) On a surface type unit or... superstructure deck where superstructures are fitted must be assumed to be subject to simultaneous flooding. (b...

A Critical Reassessment of Marxian Base-Superstructure Explanations of the Role of Education in Social Change.

ERIC Educational Resources Information Center

Chun, Kyung-Kap

1986-01-01

Examines how four major versions of neo-Marxism (i.e., Hegelian, Phenomenological, Structuralist Marxism, and the Frankfurt School) attempt to overcome the base-superstructure thesis of the political economists of education. Considers the implicit social ontological and epistemological assumptions and the related theory of education of each.…

11. VIEW SHOWING THE SUPERSTRUCTURE OF THE SHED ROOF (REMOVED ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. VIEW SHOWING THE SUPERSTRUCTURE OF THE SHED ROOF (REMOVED AUTUMN OF 1996) PROTECTING THE PRESENT INTAKE GATES- AND RAKE-LIFTING MECHANISMS AND THE TRASH RACKS (LOWER FOREGROUND), LOOKING NORTH. - Washington Water Power Company Post Falls Power Plant, Middle Channel Powerhouse & Dam, West of intersection of Spokane & Fourth Streets, Post Falls, Kootenai County, ID

A Field Assessment of Timber Highway Bridge Durability in the United States

Treesearch

J.P. Wacker; B.K. Brashaw; F. Jalinoos

2015-01-01

This paper summarizes a cooperative project to assess the current condition and life expectancy of 132 timber highway bridge superstructures at locations throughout the United States. Several superstructure types were included in this comprehensive effort, of which two-thirds were sawn timber stringer systems. In-depth inspections were conducted by the project team...

Creosote retention levels of timber highway bridge superstructures in Michigan’s Lower Peninsula.

Treesearch

James P. Wacker; Douglas M. Crawford; Merv O. Eriksson

2003-01-01

Environmental concerns about preservative bleeding (or migrating) from timber bridges have increased in recent years. This preliminary study examined the creosote retention levels at six timber highway bridges in Michigan's lower peninsula during the summer of 2000. Several test core samples were removed from the bridge superstructures (four bleeders and two...

Two modes of longe-range orientation of DNA bases realized upon compaction.

PubMed Central

Yevdokimov YuM; Salyanov, V I; Berg, H

1981-01-01

Formation of compact particles from linear DNA-anthracycline complexes is accompanied by appearance of intense bands in the CD spectra in the region of absorption of DNA bases (UV-region) and in the region of absorption of anthracycline chromophores (visible region). The intense (positive or negative) bands in the region of anthracycline absorption demonstrate an ordered helical location of anthracycline molecules on the DNA template. This fact, in its turn, is related to formation of the DNA superstructure in PEG-containing water-salt solutions with a long-range orientation of nitrogen bases. Possible types of DNA superstructures and the relation between the local- and the long-range order of bases in the DNA superstructure are discussed. PMID:6938929

U.S. Geological Survey Geologic Carbon Sequestration Assessment

NASA Astrophysics Data System (ADS)

Warwick, P. D.; Blondes, M. S.; Brennan, S.; Corum, M.; Merrill, M. D.

2012-12-01

The Energy Independence and Security Act of 2007 authorized the U.S. Geological Survey (USGS) to conduct a national assessment of potential geological storage resources for carbon dioxide (CO2) in consultation with the U.S. Department of Energy (DOE), the U.S. Environmental Protection Agency (EPA) and State geological surveys. To conduct the assessment, the USGS developed a probability-based assessment methodology that was extensively reviewed by experts from industry, government and university organizations (Brennan et al., 2010, http://pubs.usgs.gov/of/2010/1127). The methodology is intended to be used at regional to sub-basinal scales and it identifies storage assessment units (SAUs) that are based on two depth categories below the surface (1) 3,000 to 13,000 ft (914 to 3,962 m), and (2) 13,000 ft (3,962 m) and greater. In the first category, the 3,000 ft (914 m) minimum depth of the storage reservoir ensures that CO2 is in a supercritical state to minimize the storage volume. The depth of 13,000 ft (3,962 m) represents maximum depths that are accessible with average injection pressures. The second category represents areas where a reservoir formation has potential storage at depths below 13,000 ft (3,962 m), although they are not accessible with average injection pressures; these are assessed as a separate SAU. SAUs are restricted to formation intervals that contain saline waters (total dissolved solids greater than 10,000 parts per million) to prevent contamination of protected ground water. Carbon dioxide sequestration capacity is estimated for buoyant and residual storage traps within the basins. For buoyant traps, CO2 is held in place in porous formations by top and lateral seals. For residual traps, CO2 is contained in porous formations as individual droplets held within pores by capillary forces. Preliminary geologic models have been developed to estimate CO2 storage capacity in approximately 40 major sedimentary basins within the United States. More than 200 SAUs have been identified within these basins. The results of the assessment are estimates of the technically accessible storage resources based on present-day geological and engineering technology related to CO2 injection into geologic formations; therefore the assessment is not of total in-place resources. Summary geologic descriptions of the evaluated basins and SAUs will be prepared, along with the national assessment results. During the coming year, these results will be released as USGS publications available from http://energy.usgs.gov. In support of these assessment activities, CO2 sequestration related research science is being conducted by members of the project. Results of our research will contribute to current and future CO2 storage assessments conducted by the USGS and other organizations. Research topics include: (a) geochemistry of CO2 interactions with subsurface environments; (b) subsurface petrophysical rock properties in relation to CO2 injection; (c) enhanced oil recovery and the potential for CO2 storage; (d) storage of CO2 in unconventional reservoirs (coal, shale, and basalt); (e) statistical aggregation of assessment results; and (f) potential risks of induced seismicity.

Carbon storage and late Holocene chronostratigraphy of a Mississippi River deltaic marsh, St. Bernard Parish, Louisiana

USGS Publications Warehouse

Markewich, H. W.

1998-01-01

Today, the causes, results, and time scale(s) of climate change, past and potential, are the focus of much research, news coverage, and pundit speculation. Many of the US government scientific agencies have some funds earmarked for research into past and (or) future climate change (National Science and Technology Council, 1997). The Mississippi Basin Carbon Project (MBCP) is part of the U.S. Geological Survey (USGS) effort in global change research . The project is motivated by the need to increase our understanding of the role of terrestrial carbon in the global carbon cycle, particularly in the temperate latitudes of North America. The global land area between 30 O and 60 O N is thought to be a large sink for atmospheric CO2 (IPCC, 1996). The identity of this sink is unknown, but is in part the soil and sediment that makes up the upper several meters of the Earth's surface. The MBCP focuses on the Mississippi River basin, the third largest river system in the world (fig. 1), that drains an area of 3.3 x 10 6 km 2 (1.27 x 10 6 mi 2 ). The Mississippi River basin includes more than 40 percent of the land surface, and is the home of more than one-third of the population, of the conterminous United States. Because climate, vegetation, and land use vary greatly within the Mississippi River basin, the primary terrestrial sinks for carbon need to be identified and quantified for representative parts of the basin. The primary goal of the MBCP is to quantify the interactive effects of land-use, erosion, sedimentation, and soil development on carbon storage and nutrient cycles within the Mississippi River basin. The project includes spatial analysis of a wide variety of geographic data, estimation of whole-basin and sub-basin carbon and sediment budgets, development and implementation of terrestrial carbon-cycle models, and site-specific field studies of relevant processes. Areas can be studied and compared, and estimates can be made for whole-basin carbon storage and flux.

Modeling the water budget of the Upper Blue Nile basin using the JGrass-NewAge model system and satellite data

NASA Astrophysics Data System (ADS)

Abera, Wuletawu; Formetta, Giuseppe; Brocca, Luca; Rigon, Riccardo

2017-06-01

The Upper Blue Nile basin is one of the most data-scarce regions in developing countries, and hence the hydrological information required for informed decision making in water resource management is limited. The hydrological complexity of the basin, tied with the lack of hydrometeorological data, means that most hydrological studies in the region are either restricted to small subbasins where there are relatively better hydrometeorological data available, or on the whole-basin scale but at very coarse timescales and spatial resolutions. In this study we develop a methodology that can improve the state of the art by using available, but sparse, hydrometeorological data and satellite products to obtain the estimates of all the components of the hydrological cycle (precipitation, evapotranspiration, discharge, and storage). To obtain the water-budget closure, we use the JGrass-NewAge system and various remote sensing products. The satellite product SM2R-CCI is used for obtaining the rainfall inputs, SAF EUMETSAT for cloud cover fraction for proper net radiation estimation, GLEAM for comparison with NewAge-estimated evapotranspiration, and GRACE gravimetry data for comparison of the total water storage amounts available in the whole basin. Results are obtained at daily time steps for the period 1994-2009 (16 years), and they can be used as a reference for any water resource development activities in the region. The overall water-budget analysis shows that precipitation of the basin is 1360 ± 230 mm per year. Evapotranspiration accounts for 56 % of the annual water budget, runoff is 33 %, storage varies from -10 to +17 % of the water budget.

Modeling basin- and plume-scale processes of CO2 storage for full-scale deployment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Q.; Birkholzer, J.T.; Mehnert, E.

Integrated modeling of basin- and plume-scale processes induced by full-scale deployment of CO{sub 2} storage was applied to the Mt. Simon Aquifer in the Illinois Basin. A three-dimensional mesh was generated with local refinement around 20 injection sites, with approximately 30 km spacing. A total annual injection rate of 100 Mt CO{sub 2} over 50 years was used. The CO{sub 2}-brine flow at the plume scale and the single-phase flow at the basin scale were simulated. Simulation results show the overall shape of a CO{sub 2} plume consisting of a typical gravity-override subplume in the bottom injection zone of highmore » injectivity and a pyramid-shaped subplume in the overlying multilayered Mt. Simon, indicating the important role of a secondary seal with relatively low-permeability and high-entry capillary pressure. The secondary-seal effect is manifested by retarded upward CO{sub 2} migration as a result of multiple secondary seals, coupled with lateral preferential CO{sub 2} viscous fingering through high-permeability layers. The plume width varies from 9.0 to 13.5 km at 200 years, indicating the slow CO{sub 2} migration and no plume interference between storage sites. On the basin scale, pressure perturbations propagate quickly away from injection centers, interfere after less than 1 year, and eventually reach basin margins. The simulated pressure buildup of 35 bar in the injection area is not expected to affect caprock geomechanical integrity. Moderate pressure buildup is observed in Mt. Simon in northern Illinois. However, its impact on groundwater resources is less than the hydraulic drawdown induced by long-term extensive pumping from overlying freshwater aquifers.« less

Human amplified changes in precipitation-runoff patterns in large river basins of the Midwestern United States

NASA Astrophysics Data System (ADS)

Kelly, Sara A.; Takbiri, Zeinab; Belmont, Patrick; Foufoula-Georgiou, Efi

2017-10-01

Complete transformations of land cover from prairie, wetlands, and hardwood forests to row crop agriculture and urban centers are thought to have caused profound changes in hydrology in the Upper Midwestern US since the 1800s. In this study, we investigate four large (23 000-69 000 km2) Midwest river basins that span climate and land use gradients to understand how climate and agricultural drainage have influenced basin hydrology over the last 79 years. We use daily, monthly, and annual flow metrics to document streamflow changes and discuss those changes in the context of precipitation and land use changes. Since 1935, flow, precipitation, artificial drainage extent, and corn and soybean acreage have increased across the region. In extensively drained basins, we observe 2 to 4 fold increases in low flows and 1.5 to 3 fold increases in high and extreme flows. Using a water budget, we determined that the storage term has decreased in intensively drained and cultivated basins by 30-200 % since 1975, but increased by roughly 30 % in the less agricultural basin. Storage has generally decreased during spring and summer months and increased during fall and winter months in all watersheds. Thus, the loss of storage and enhanced hydrologic connectivity and efficiency imparted by artificial agricultural drainage appear to have amplified the streamflow response to precipitation increases in the Midwest. Future increases in precipitation are likely to further intensify drainage practices and increase streamflows. Increased streamflow has implications for flood risk, channel adjustment, and sediment and nutrient transport and presents unique challenges for agriculture and water resource management in the Midwest. Better documentation of existing and future drain tile and ditch installation is needed to further understand the role of climate versus drainage across multiple spatial and temporal scales.

INTERIOR VIEW OF FUEL STORAGE BUILDING (CPP603) LOOKING SOUTHWEST SHOWING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR VIEW OF FUEL STORAGE BUILDING (CPP-603) LOOKING SOUTHWEST SHOWING STORAGE BASIN IN FOREGROUND, TRANSFER CRANE AND UNLOADER TO LEFT OF NORTH SIDE OF HOT CELL. INL PHOTO NUMBER NRTS-58-157. J. Anderson, Photographer, 1/15/1958 - Idaho National Engineering Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex, Scoville, Butte County, ID

Using the nonlinear aquifer storage-discharge relationship to simulate the base flow of glacier- and snowmelt-dominated basins in northwest China

NASA Astrophysics Data System (ADS)

Gan, R.; Luo, Y.

2013-09-01

Base flow is an important component in hydrological modeling. This process is usually modeled by using the linear aquifer storage-discharge relation approach, although the outflow from groundwater aquifers is nonlinear. To identify the accuracy of base flow estimates in rivers dominated by snowmelt and/or glacier melt in arid and cold northwestern China, a nonlinear storage-discharge relationship for use in SWAT (Soil Water Assessment Tool) modeling was developed and applied to the Manas River basin in the Tian Shan Mountains. Linear reservoir models and a digital filter program were used for comparisons. Meanwhile, numerical analysis of recession curves from 78 river gauge stations revealed variation in the parameters of the nonlinear relationship. It was found that the nonlinear reservoir model can improve the streamflow simulation, especially for low-flow period. The higher Nash-Sutcliffe efficiency, logarithmic efficiency, and volumetric efficiency, and lower percent bias were obtained when compared to the one-linear reservoir approach. The parameter b of the aquifer storage-discharge function varied mostly between 0.0 and 0.1, which is much smaller than the suggested value of 0.5. The coefficient a of the function is related to catchment properties, primarily the basin and glacier areas.

Study on glacier changes from multi-source remote sensing data in the mountainous areas of the upper reaches of Shule River Basin

NASA Astrophysics Data System (ADS)

Zhang, S.; Li, H.

2017-12-01

The changes of glacier area, ice surface elevation and ice storage in the upper reaches of the Shule River Basin were investigated by the Landsat TM series SRTM and stereo image pairs of Third Resources Satellite (ZY-3)from 2000 to 2015. There are 510 glaciers with areas large than 0.01 km2 in 2015, and the glacier area is 435 km2 in the upper reach of Shule River basin. 96 glaciers were disappeared from 2000 to 2015, and the total glacier area decreased by 57.6±2.68km2 (11.7 %). After correcting the elevation difference between ZY-3 DEM and SRTM and aspect, we found that the average ice surface elevation of glaciers reduced by 2.58±0.6m from 2000 to 2015 , with average reduction 0.172 ±0.04m a-1, and the ice storage reduced by 1.277±0.311km3. Elevation variation of ice surface in different sub-regions reflects the complexity of glacier change. The ice storage change calculated from the sum of single glacier area-volume relationship is glacier 1.46 times higher than that estimated from ice surface elevation change, indicating that the global ice storage change estimated from glacier area-volume change probably overestimated. The shrinkage of glacier increased glacier runoff, and led the significant increase of river runoff. The accuracy of projecting the potential glacier change, glacier runoff and river runoff is the key issues of delicacy water resource management in Shule River Basin.

Estimating continental water storage variations in Central Asia area using GRACE data

NASA Astrophysics Data System (ADS)

Dapeng, Mu; Zhongchang, Sun; Jinyun, Guo

2014-03-01

The goal of GRACE satellite is to determine time-variations of the Earth's gravity, and particularly the effects of fluid mass redistributions at the surface of the Earth. This paper uses GRACE Level-2 RL05 data provided by CSR to estimate water storage variations of four river basins in Asia area for the period from 2003 to 2011. We apply a two-step filtering method to reduce the errors in GRACE data, which combines Gaussian averaging function and empirical de-correlation method. We use GLDAS hydrology to validate the result from GRACE. Special averaging approach is preformed to reduce the errors in GLDAS. The results of former three basins from GRACE are consistent with GLDAS hydrology model. In the Tarim River basin, there is more discrepancy between GRACE and GLDAS. Precipitation data from weather station proves that the results of GRACE are more plausible. We use spectral analysis to obtain the main periods of GRACE and GLDAS time series and then use least squares adjustment to determine the amplitude and phase. The results show that water storage in Central Asia is decreasing.

Monitoring groundwater variation by satellite and implications for in-situ gravity measurements.

PubMed

Fukuda, Yoichi; Yamamoto, Keiko; Hasegawa, Takashi; Nakaegawa, Toshiyuki; Nishijima, Jun; Taniguchi, Makoto

2009-04-15

In order to establish a new technique for monitoring groundwater variations in urban areas, the applicability of precise in-situ gravity measurements and extremely high precision satellite gravity data via GRACE (Gravity Recovery and Climate Experiment) was tested. Using the GRACE data, regional scale water mass variations in four major river basins of the Indochina Peninsula were estimated. The estimated variations were compared with Soil-Vegetation-Atmosphere Transfer Scheme (SVATS) models with a river flow model of 1) globally uniform river velocity, 2) river velocity tuned by each river basin, 3) globally uniform river velocity considering groundwater storage, and 4) river velocity tuned by each river basin considering groundwater storage. Model 3) attained the best fit to the GRACE data, and the model 4) yielded almost the same values. This implies that the groundwater plays an important role in estimating the variation of total terrestrial storage. It also indicates that tuning river velocity, which is based on the in-situ measurements, needs further investigations in combination with the GRACE data. The relationships among GRACE data, SVATS models, and in-situ measurements were also discussed briefly.

Mapping of reciprocal space of La{sub 0.30}CoO{sub 2} in 3D: Analysis of superstructure diffractions and intergrowths with Co{sub 3}O{sub 4}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brázda, Petr, E-mail: brazda@fzu.cz; Palatinus, Lukáš; Klementová, Mariana

2015-07-15

We have used electron diffraction tomography and powder X-ray diffraction to elucidate the structural properties of layered cobaltate γ-La{sub 0.30}CoO{sub 2}. The structure consists of hexagonal sheets of edge-sharing CoO{sub 6} octahedra interleaved by lanthanum monolayers. The La{sup 3+} cations occupy only one third of available P2 sites, forming a 2-dimensional a√3×a√3 superstructure in a–b plane. The results show that there exists no order in the mutual relative shift between the neighbouring La interlayers within the a–b plane. This is manifested in the observed monotonous decrease of the diffracted intensity of the superstructure diffractions along c{sup ⁎} in both X-raymore » and electron diffraction data. The observed lack of stacking order differentiates the La{sub x}CoO{sub 2} from its Ca and Sr analogues where at least a partial stacking order of the cationic interlayers is manifested in experimental data published in literature. - Highlights: • We use electron diffraction tomography for reciprocal space mapping of La{sub 0.30}CoO{sub 2}. • We observed a complete disorder of the stacking of Lanthanum interlayers. • Co{sub 3}O{sub 4} intergrown with La{sub 0.30}CoO{sub 2} crystals brings about fake superstructure diffractions. • Twinning of Co{sub 3}O{sub 4} enhances the problem of fake superstructure diffractions.« less

Impact of temperature on nitrification in biological activated carbon (BAC) filters used for drinking water treatment.

PubMed

Andersson, A; Laurent, P; Kihn, A; Prévost, M; Servais, P

2001-08-01

The impact of temperature on nitrification in biological granular activated carbon (GAC) filters was evaluated in order to improve the understanding of the nitrification process in drinking water treatment. The study was conducted in a northern climate where very cold water temperatures (below 2 degrees C) prevail for extended periods and rapid shifts of temperature are frequent in the spring and fall. Ammonia removals were monitored and the fixed nitrifying biomass was measured using a method of potential nitrifying activity. The impact of temperature was evaluated on two different filter media: an opened superstructure wood-based activated carbon and a closed superstructure activated carbon-based on bituminous coal. The study was conducted at two levels: pilot scale (first-stage filters) and full-scale (second-stage filters) and the results indicate a strong temperature impact on nitrification activity. Ammonia removal capacities ranged from 40 to 90% in pilot filters, at temperatures above 10 degrees C, while more than 90% ammonia was removed in the full-scale filters for the same temperature range. At moderate temperatures (4-10 degrees C), the first stage pilot filters removed 10-40% of incoming ammonia for both media (opened and closed superstructure). In the full-scale filters, a difference between the two media in nitrification performances was observed at moderate temperatures: the ammonia removal rate in the opened superstructure support (more than 90%) was higher than in the closed superstructure support (45%). At low temperatures (below 4 degrees C) both media performed poorly. Ammonia removal capacities were below 30% in both pilot- and full-scale filters.

Seismic soil structure interaction analysis for asymmetrical buildings supported on piled raft for the 2015 Nepal earthquake

NASA Astrophysics Data System (ADS)

Badry, Pallavi; Satyam, Neelima

2017-01-01

Seismic damage surveys and analyses conducted on modes of failure of structures during past earthquakes observed that the asymmetrical buildings show the most vulnerable effect throughout the course of failures (Wegner et al., 2009). Thus, all asymmetrical buildings significantly fails during the shaking events and it is really needed to focus on the accurate analysis of the building, including all possible accuracy in the analysis. Apart from superstructure geometry, the soil behavior during earthquake shaking plays a pivotal role in the building collapse (Chopra, 2012). Fixed base analysis where the soil is considered to be infinitely rigid cannot simulate the actual scenario of wave propagation during earthquakes and wave transfer mechanism in the superstructure (Wolf, 1985). This can be well explained in the soil structure interaction analysis, where the ground movement and structural movement can be considered with the equal rigor. In the present study the object oriented program has been developed in C++ to model the SSI system using the finite element methodology. In this attempt the seismic soil structure interaction analysis has been carried out for T, L and C types piled raft supported buildings in the recent 25th April 2015 Nepal earthquake (M = 7.8). The soil properties have been considered with the appropriate soil data from the Katmandu valley region. The effect of asymmetry of the building on the responses of the superstructure is compared with the author's research work. It has been studied/observed that the shape or geometry of the superstructure governs the response of the superstructure subjected to the same earthquake load.

46 CFR 45.127 - Position of structures, openings, and fittings.

Code of Federal Regulations, 2010 CFR

2010-10-01

... quarter deck; (2) A superstructure deck or a trunk deck and forward of a point 1/4 L from the forward... deck aft of a point 1/4 L abaft the forward perpendicular; or (2) On a superstructure and trunk combination, that is H s or more n height, aft or a point 1/4 L abaft the forward perpendicular. ...

46 CFR 45.127 - Position of structures, openings, and fittings.

Code of Federal Regulations, 2011 CFR

2011-10-01

... quarter deck; (2) A superstructure deck or a trunk deck and forward of a point 1/4 L from the forward... deck aft of a point 1/4 L abaft the forward perpendicular; or (2) On a superstructure and trunk combination, that is H s or more n height, aft or a point 1/4 L abaft the forward perpendicular. ...

Novel symmetrical coralloid Cu 3D superstructures: Solid-state synthesis from a Cu-carboxylate MOF and their in-situ thermal conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Lingyun, E-mail: lychen@cqu.edu.c; Shen Yongming; Bai Junfeng, E-mail: bjunfeng@nju.edu.c

2009-08-15

We describe here a one-step solid-state process for the synthesis of metal three-dimensional (3D) superstructures from a metal-organic framework (MOF). Novel symmetrical coralloid Cu 3D superstructures with surface interspersed with clusters of Cu nanoparticles were successfully synthesized by thermolysis of the [Cu{sub 3}(btc){sub 2}] (btc=benzene-1,3,5-tricarboxylato) MOF in a one-end closed horizontal tube furnace (OCTF). The obtained products were characterized by TGA, FT-IR, XRD, EDX, SEM, TEM, HRTEM and SAED. Different reaction conditions were discussed. Furthermore, the synthesized Cu samples were converted into CuO microstructures by in-situ calcination in the air. In addition, the possible formation mechanism was also proposed. Thismore » method is a simple and facile route, which builds a direct linkage between metal-carboxylate MOF crystals and metal nano- or microstructures and also opens a new application field of MOFs. - Graphical abstract: Novel symmetrical coralloid Cu 3D superstructures were synthesized by thermolysis of the [Cu{sub 3}(btc){sub 2}] (btc=benzene-1,3,5-tricarboxylato) MOF microcrystals in a one-end closed horizontal tube furnace (OCTF).« less

Basin-wide water accounting using remote sensing data: the case of transboundary Indus Basin

NASA Astrophysics Data System (ADS)

Karimi, P.; Bastiaanssen, W. G. M.; Molden, D.; Cheema, M. J. M.

2012-11-01

The paper describes the application of a new Water Accounting Plus (WA+) framework to produce spatial information on water flows, sinks, uses, storages and assets, in the Indus Basin, South Asia. It demonstrates how satellite-derived estimates of land use, land cover, rainfall, evaporation (E), transpiration (T), interception (I) and biomass production can be used in the context of WA+. The results for one selected year showed that total annual water depletion in the basin (502 km3) plus outflows (21 km3) exceeded total precipitation (482 km3). The deficit in supply was augmented through abstractions beyond actual capacity, mainly from groundwater storage (30 km3). The "landscape ET" (depletion directly from rainfall) was 344 km3 (69% of total consumption). "Blue water" depletion ("utilized flow") was 158 km3 (31%). Agriculture was the biggest water consumer and accounted for 59% of the total depletion (297 km3), of which 85% (254 km3) was through irrigated agriculture and the remaining 15% (44 km3) through rainfed systems. While the estimated basin irrigation efficiency was 0.84, due to excessive evaporative losses in agricultural areas, half of all water consumption in the basin was non-beneficial. Average rainfed crop yields were 0.9 t ha-1 and 7.8 t ha-1 for two irrigated crop growing seasons combined. Water productivity was low due to a lack of proper agronomical practices and poor farm water management. The paper concludes that the opportunity for a food-secured and sustainable future for the Indus Basin lies in focusing on reducing soil evaporation. Results of future scenario analyses suggest that by implementing techniques to convert soil evaporation to crop transpiration will not only increase production but can also result in significant water savings that would ease the pressure on the fast declining storage.

The Amazon Basin in transition

Treesearch

Eric A. Davidson; Alessandro C. de Araujo; Paulo Artaxo; Jennifer K. Balch; I. Foster Brown; Mercedes M.C. Bustamente; Michael T. Coe; Ruth S. DeFriess; Michael Keller; Marcos Longo; J. William Munger; Wilfrid Schroeder; Britaldo Soares-Filho; Carlos M. Souza, Jr.; Steven C. Wofsy

2012-01-01

Agricultural expansion and climate variability have become important agents of disturbance in the Amazon basin. Recent studies have demonstrated considerable resilience of Amazonian forests to moderate annual drought, but they also show that interactions between deforestation, fire and drought potentially lead to losses of carbon storage and changes in regional...

Estimation of small reservoir storage capacities in the São Francisco, Limpopo, Bandama and Volta river basins using remotely sensed surface areas

NASA Astrophysics Data System (ADS)

Rodrigues, Lineu; Senzanje, Aidan; Cecchi, Philippe; Liebe, Jens

2010-05-01

People living in areas with highly variable rainfall, experience droughts and floods and often have insecure livelihoods. Small multi-purpose reservoirs (SR) are a widely used form of infrastructures to provide people in such areas with water during the dry season, e.g. in the basins of São Francisco, Brazil, Limpopo, Zimbabwe, Bandama, Ivory Coast and Volta, Ghana. In these areas, the available natural flow in the streams is sometimes less than the flow required for water supply or irrigation, however water can be stored in times of surplus, for example, from a wet season to a dry season. Efficient water management and sound reservoir planning are hindered by the lack of information about the functioning of these reservoirs. Reservoirs in these regions were constructed in a series of projects funded by different agencies, at different times, with little or no coordination among the implementing partners. Poor record keeping and the lack of appropriate institutional support result in deficiencies of information on the capacity, operation, and maintenance of these structures. Estimating the storage capacity of dams is essential to the responsible management of water diversion. Most of SR in these basins have never been evaluated, possibly because the tools currently used for such measurement are labor-intensive, costly and time-consuming. The objective of this research was to develop methodology to estimate small reservoir capacities as a function of their remotely sensed surface areas in the São Francisco, Limpopo, Bandama and Volta basins, as a way to contribute to improve the water resource management in those catchments. Remote sensing was used to identify, localize and characterize small reservoirs. The surface area of each was calculated from satellite images. A sub-set of reservoirs was selected. For each reservoir in the sub-set, the surface area was estimated from field surveys, and storage capacity was estimated using information on reservoir surface area, depth and shape. Depth was measured using a stadia rod or a manual echosounder. For reservoirs in the sub-set, estimated surface area was used as an input into the triangulated irregular network model. With the surface area and depth, measured volume was calculated. Comparisons were made between estimates of surface area from field surveys and estimates of surface area from remote sensing. A linear regression analysis was carried out to establish the relationship between surface area and storage capacities. Within geomorphologically homogenous regions, one may expect a good correlation between the surface area, which may be determined through satellite observations, and the stored volume. Such a relation depends on the general shape of the slopes (convex, through straight, to concave). The power relationships between remotely sensed surface areas (m^2) and storage capacities of reservoirs (m^3) obtained were - Limpopo basin (Lower Mzingwane sub-catchment): Volume = 0.023083 x Area^1.3272 (R2 = 95%); Bandama basin (North of the basin in Ivory Coast): Volume = 0.00405 x Area^1.4953 (R2 = 88.9%); Volta basin (Upper East region of the Volta Basin in Ghana): Volume = 0.00857 × Area^1.43 (R2 = 97.5%); São Francisco basin (Preto river sub-catchment): Volume = 0.2643 x Area^1.1632 (R2 = 92.1%). Remote sensing was found to be a suitable means to detect small reservoirs and accurately measure their surface areas. The general relationship between measured reservoir volumes and their remotely sensed surface areas showed good accuracy for all four basins. Combining such relationships with periodical satellite-based reservoir area measurements may allow hydrologists and planners to have clear picture of water resource system in the Basins, especially in ungauged sub-basins.

Watershed nitrogen and phosphorus balance: The upper Potomac River basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jaworski, N.A.; Groffman, P.M.; Keller, A.A.

1992-01-01

Nitrogen and phosphorus mass balances were estimated for the portion of the Potomac River basin watershed located above Washington, D.C. The total nitrogen (N) balance included seven input source terms, six sinks, and one 'change-in-storage' term, but was simplified to five input terms and three output terms. The phosphorus (P) baance had four input and three output terms. The estimated balances are based on watershed data from seven information sources. Major sources of nitrogen are animal waste and atmospheric deposition. The major sources of phosphorus are animal waste and fertilizer. The major sink for nitrogen is combined denitrification, volatilization, andmore » change-in-storage. The major sink for phosphorus is change-in-storage. River exports of N and P were 17% and 8%, respectively, of the total N and P inputs. Over 60% of the N and P were volatilized or stored. The major input and output terms on the budget are estimated from direct measurements, but the change-in-storage term is calculated by difference. The factors regulating retention and storage processes are discussed and research needs are identified.« less

The Effect of modeled recharge distribution on simulated groundwater availability and capture

USGS Publications Warehouse

Tillman, Fred D.; Pool, Donald R.; Leake, Stanley A.

2015-01-01

Simulating groundwater flow in basin-fill aquifers of the semiarid southwestern United States commonly requires decisions about how to distribute aquifer recharge. Precipitation can recharge basin-fill aquifers by direct infiltration and transport through faults and fractures in the high-elevation areas, by flowing overland through high-elevation areas to infiltrate at basin-fill margins along mountain fronts, by flowing overland to infiltrate along ephemeral channels that often traverse basins in the area, or by some combination of these processes. The importance of accurately simulating recharge distributions is a current topic of discussion among hydrologists and water managers in the region, but no comparative study has been performed to analyze the effects of different recharge distributions on groundwater simulations. This study investigates the importance of the distribution of aquifer recharge in simulating regional groundwater flow in basin-fill aquifers by calibrating a groundwater-flow model to four different recharge distributions, all with the same total amount of recharge. Similarities are seen in results from steady-state models for optimized hydraulic conductivity values, fit of simulated to observed hydraulic heads, and composite scaled sensitivities of conductivity parameter zones. Transient simulations with hypothetical storage properties and pumping rates produce similar capture rates and storage change results, but differences are noted in the rate of drawdown at some well locations owing to the differences in optimized hydraulic conductivity. Depending on whether the purpose of the groundwater model is to simulate changes in groundwater levels or changes in storage and capture, the distribution of aquifer recharge may or may not be of primary importance.

Analyses of infrequent (quasi-decadal) large groundwater recharge events in the northern Great Basin: Their importance for groundwater availability, use, and management

USGS Publications Warehouse

Masbruch, Melissa D.; Rumsey, Christine; Gangopadhyay, Subhrendu; Susong, David D.; Pruitt, Tom

2016-01-01

There has been a considerable amount of research linking climatic variability to hydrologic responses in the western United States. Although much effort has been spent to assess and predict changes in surface water resources, little has been done to understand how climatic events and changes affect groundwater resources. This study focuses on characterizing and quantifying the effects of large, multiyear, quasi-decadal groundwater recharge events in the northern Utah portion of the Great Basin for the period 1960–2013. Annual groundwater level data were analyzed with climatic data to characterize climatic conditions and frequency of these large recharge events. Using observed water-level changes and multivariate analysis, five large groundwater recharge events were identified with a frequency of about 11–13 years. These events were generally characterized as having above-average annual precipitation and snow water equivalent and below-average seasonal temperatures, especially during the spring (April through June). Existing groundwater flow models for several basins within the study area were used to quantify changes in groundwater storage from these events. Simulated groundwater storage increases per basin from a single recharge event ranged from about 115 to 205 Mm3. Extrapolating these amounts over the entire northern Great Basin indicates that a single large quasi-decadal recharge event could result in billions of cubic meters of groundwater storage. Understanding the role of these large quasi-decadal recharge events in replenishing aquifers and sustaining water supplies is crucial for long-term groundwater management.

Scale Issues in Modeling the Water Resources Sector in National Economic Models: A Case study of China

NASA Astrophysics Data System (ADS)

Strzepek, K. M.; Kirshen, P.; Yohe, G.

2001-05-01

The fundamental theme of this research was to investigate tradeoffs in model resolution for modeling water resources in the context of national economic development and capital investment decisions.. Based on a case study of China, the research team has developed water resource models at relatively fine scales, then investigated how they can be aggregated to regional or national scales and for use in national level planning decisions or global scale integrated assessment models of food and/or environmental change issues. The team has developed regional water supply and water demand functions.. Simplifying and aggregating the supply and demand functions will allow reduced form functions of the water sector for inclusion in large scale national economic models. Water Supply Cost functions were developed looking at both surface and groundwater supplies. Surface Water: Long time series of flows at the mouths of the 36 major river sub-basins in China are used in conjunction with different basin reservoir storage quantities to obtain storage-yield curves. These are then combined with reservoir and transmission cost data to obtain yield-cost or surface water demand curves. The methodology to obtain the long time series of flows for each basin is to fit a simple abcd water balance model to each basin. The costs of reservoir storage have been estimated by using a methodology developed in the USA that relates marginal storage costs to existing storage, slope and geological conditions. USA costs functions have then been adjusted to Chinese costs. The costs of some actual dams in China were used to "ground-truth" the methodology. Groundwater: The purpose of the groundwater work is to estimate the recharge in each basin, and the depths and quality of water of aquifers. A byproduct of the application of the abcd water balance model is the recharge. Depths and quality of aquifers are being taken from many separate reports on groundwater in different parts of China; we have been unable to find any global or regional datasets of groundwater.. Combining Surface and Groundwater Supply Functions Water Demand Curves. Water Use data is reported on political regions. Water Supply is reported and modeled on river basin regions. It is necessary to allocate water demands to river basins. To accomplish this China's 9 major river basins were divided into 36 hydroeconomic regions. The counties were then allocated to one of the 36-hydroeconomic zones. The county-level water use data was aggregated to 5 major water use sectors: 1)industry; 2)urban municipal and vegetable gardens: 3) major irrigation; 4) Energy and 5)Other agriculture (forestry, pasture; fishery). Sectoral Demand functions that include price and income elasticity were developed for the 5 sectors for each of the 9 major river basin. The supply and demand curves were aggregated at a variety of geographical scales as well as levels of economic sectoral aggregation. Implications for investment and sustainable development policies were examined for the various aggregation using partial and general equilibrium modeling of the Chinese economy. These results and policy implications for China as well as insights and recommendation for other developing countries will be presented.

Rising Water Storage in the Niger River basin: Clues and Cause

NASA Astrophysics Data System (ADS)

Werth, S.

2016-12-01

Heavily populated west African regions along the Niger River are affected by climate and land cover changes, altering the distribution of water resources. To maintain a reliable water supply in the region, water management authorities require knowledge of hydrological changes at various spatial and temporal scales. Local and regional studies reported rising water tables over the last decades as a consequence of complex responses on land use change in the Sahel zone. The spatial extend of this responses is not well understood, as of yet. Thus, this study provides an in-depth investigation of long-term changes in the water storages of Niger River basin and its sub-regions by analyzing more than a decade of satellite based gravity data from the Gravity Recovery And Climate Change (GRACE) satellites. Soil moisture data from four global hydrological models serve to separate freshwater resources (WR) from GRACE-based terrestrial water storage variations. Surface water variations from a global water storage model and trends from altimetry data were applied to separate the groundwater component from WR trends. Errors of all datasets are taken into account. Trends in WR are positive, except for the tropical Upper Niger with negative trends. For the Niger basin, a rise in GW stocks was detected. On the subbasin scale, GW changes are positive for the Sahelian Middle Niger and the Benue. The findings confirm previous observations of water tables in the Sahel and tropical zones, indicating that reported effects of land use change are relevant on large, i.e. basin and subbasin, scales. Our results have implications for Niger water management strategies. While areas with rising water storage are stocking a comfortable backup to mitigate possible future droughts and to deliver water to remote areas with no access to rivers or reservoirs. Increasing groundwater recharges may be accompanied by a reduction in water quality. This study helps to inform authority's decision to address risks for affected communities.

Hydrogeologic framework and characterization of the Truxton Aquifer on the Hualapai Reservation, Mohave County, Arizona

USGS Publications Warehouse

Bills, Donald J.; Macy, Jamie P.

2016-12-30

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, developed this study to determine an estimate of groundwater in storage in the Truxton aquifer on the Hualapai Reservation in northwestern Arizona. For this study, the Truxton aquifer is defined as the unconfined, saturated groundwater in the unconsolidated to semiconsolidated older and younger basin-fill deposits of the Truxton basin overlying bedrock. The physical characteristics of the Truxton aquifer have not been well characterized in the past. In particular, the depth to impermeable granite bedrock and thickness of the basin are known in only a few locations where water wells have penetrated into the granite. Increasing water demands on the Truxton aquifer by both tribal and nontribal water users have led to concern about the long-term sustainability of this water resource. The Hualapai Tribe currently projects an increase of their water needs from about 300 acre-feet (acre-ft) per year to about 780 acre-ft per year by 2050 to support the community of Peach Springs, Arizona, and the southern part of the reservation. This study aimed to quantitatively develop better knowledge of aquifer characteristics, including aquifer storage and capacity, using (1) surface resistivity data collected along transects and (2) analysis of existing geologic, borehole, precipitation, water use, and water-level data.The surface resistivity surveys indicated that the depth to granite along the survey lines varied from less than 100 feet (ft) to more than 1,300 ft below land surface on the Hualapai Reservation. The top of the granite bedrock is consistent with the erosional character of the Truxton basin and exhibits deep paleochannels filled with basin-fill deposits consistent with the results of surface resistivity surveys and borehole logs from wells. The estimated average saturated thickness of the Truxton aquifer on the Hualapai Reservation is about 330 ft (with an estimated range of 260 to 390 ft), based on both resistivity results and the depth to water in wells. The saturated thickness might be greater in parts of the Truxton aquifer where paleochannels are incised into the granite underlying the basin-fill sediments. The estimated groundwater storage of the Truxton aquifer on the Hualapai Reservation ranges from 420,000 to 940,000 acre-ft and does not include groundwater storage in the aquifer outside the Hualapai Reservation boundary. In addition, the calculation of total storage in the Truxton aquifer does not determine nor indicate the availability and sustainability of that groundwater as a long-term resource. These results compared well with studies done on alluvial-basin aquifers in areas adjacent to this study. The part of the Truxton aquifer on the Hualapai Reservation represents about 20 percent of the entire aquifer.

Monitoring groundwater storage changes in the highly seasonal humid tropics: Validation of GRACE measurements in the Bengal Basin

NASA Astrophysics Data System (ADS)

Shamsudduha, M.; Taylor, R. G.; Longuevergne, L.

2012-02-01

Satellite monitoring of changes in terrestrial water storage provides invaluable information regarding the basin-scale dynamics of hydrological systems where ground-based records are limited. In the Bengal Basin of Bangladesh, we test the ability of satellite measurements under the Gravity Recovery and Climate Experiment (GRACE) to trace both the seasonality and trend in groundwater storage associated with intensive groundwater abstraction for dry-season irrigation and wet-season (monsoonal) recharge. We show that GRACE (CSR, GRGS) datasets of recent (2003 to 2007) groundwater storage changes (ΔGWS) correlate well (r = 0.77 to 0.93, p value < 0.0001) with in situ borehole records from a network of 236 monitoring stations and account for 44% of the total variation in terrestrial water storage (ΔTWS); highest correlation (r = 0.93, p value < 0.0001) and lowest root-mean-square error (<4 cm) are realized using a spherical harmonic product of CSR. Changes in surface water storage estimated from a network of 298 river gauging stations and soil-moisture derived from Land Surface Models explain 22% and 33% of ΔTWS, respectively. Groundwater depletion estimated from borehole hydrographs (-0.52 ± 0.30 km3 yr-1) is within the range of satellite-derived estimates (-0.44 to -2.04 km3 yr-1) that result from uncertainty associated with the simulation of soil moisture (CLM, NOAH, VIC) and GRACE signal-processing techniques. Recent (2003 to 2007) estimates of groundwater depletion are substantially greater than long-term (1985 to 2007) mean (-0.21 ± 0.03 km3 yr-1) and are explained primarily by substantial increases in groundwater abstraction for the dry-season irrigation and public water supplies over the last two decades.

Patterns of Woody Growth for Brazilian Savanna (Cerrado) Trees in the Cuiaba Basin and Pantanal of Mato Grosso, Brazil

NASA Astrophysics Data System (ADS)

Zappia, A. J.; Vourlitis, G. L.; Pinto-Jr, O. B.

2015-12-01

The Brazilian savanna, locally known as cerrado, is a major ecosystem that covers a vast majority of central Brazil. Little is known about how woody growth within the cerrado is affected by soil properties such as texture and/or nutrient availability. Thus, in this study we assessed the relationship between woody growth and soil properties in the Cuiaba Basin and Pantanal of Mato Grosso, Brazil. We sampled 4-5 vegetation stands in each site that varied in hydrology, soil type, and vegetation composition and structure, and measured diameter at breast height, wood density, and soil nutrient concentration and physical properties every 5-10 m along a 100 m long transect. We hypothesized that as tree diameter at breast height increases, annual tree growth rate will decrease and that woody carbon (C) storage will increase as a function of soil nutrient availability. Our preliminary data support our hypotheses. Tree growth rates declined with tree size in both the Cuiaba Basin and the Pantanal. Rates of woody C storage, both on a per tree basis (kgC tree-1 year-1) and on a per unit ground area basis (kgC m-2 year-1) were significantly positively correlated with soil extractable phosphorus (P), calcium (Ca), and clay content, while only woody C storage on a per tree basis was positively correlated with potassium (K), magnesium (Mg), and cation exchange capacity (CEC). These data suggest that rates of woody C storage in cerrado are nutrient limited, while correspondence between C storage and soil physical properties could indicate both nutrient and water limitations to C storage.

Quantifying water storage anomaly in the 2009/10 drought across North China

NASA Astrophysics Data System (ADS)

Zhu, B.; Xie, X.; Zhang, K.

2017-12-01

Global climate change is expected to have widespread impacts on the terrestrial hydrological cycle, leading to a variety of extreme disasters such as flood and drought. Drought occurs frequently in North China and it ranks the most damaging disaster in this region due to its large-scale impact on hydrology and ecosystem. Quantifying water deficit in drought is beneficial for water management including water transfer from other basins (e.g., the South-to-North Water Diversion (SNWD) project). During 2009/2010, a mega drought swept across the North China, causing a serious water deficit in industry and agriculture as well as restrictions on vegetation growth. However, little is known about the regime of water deficit during this drought at regional scale. In this study, we attempt to detect the water storage changes in response to the 2009/10 drought event. Satellite remote-sensing data from the Gravity Recovery and Climate Experiment (GRACE) were used and validated with ground measurements and land surface modeling data. As comparing with different land surface modeling data sets, the results indicate that GRACE can successfully capture the temporal variation of total water storage. The total water storage shows decline trend, and it reaches the low point during the 2009/10 drought with water storage deficit up to 25 km3 ( 22 mm). The groundwater storage shows similar pattern with the trend of -4.68 mm/yr estimated by GRACE data, while the Hai River (HR) basin has a larger trend of -14.8 mm/yr and a less trend of -1.29 mm/yr over the Liao River (LR) basin. Therefore this drought event has led to damaging hydrological effects in North China. To ease this situation, water management practice, such as the SNWD project, should make relevant response to this level of drought.

Remotely Sensed Based Lake/Reservoir Routing in Congo River Basin

NASA Astrophysics Data System (ADS)

Raoufi, R.; Beighley, E.; Lee, H.

2017-12-01

Lake and reservoir dynamics can influence local to regional water cycles but are often not well represented in hydrologic models. One challenge that limits their inclusion in models is the need for detailed storage-discharge behavior that can be further complicated in reservoirs where specific operation rules are employed. Here, the Hillslope River Routing (HRR) model is combined with a remotely sensed based Reservoir Routing (RR) method and applied to the Congo River Basin. Given that topographic data are often continuous over the entire terrestrial surface (i.e., does not differentiate between land and open water), the HRR-RR model integrates topographic derived river networks and catchment boundaries (e.g., HydroSHEDs) with water boundary extents (e.g., Global Lakes and Wetlands Database) to develop the computational framework. The catchments bordering lakes and reservoirs are partitioned into water and land portions, where representative flowpath characteristics are determined and vertical water balance and lateral routings is performed separately on each partition based on applicable process models (e.g., open water evaporation vs. evapotranspiration). To enable reservoir routing, remotely sensed water surface elevations and extents are combined to determine the storage change time series. Based on the available time series, representative storage change patterns are determined. Lake/reservoir routing is performed by combining inflows from the HRR-RR model and the representative storage change patterns to determine outflows. In this study, a suite of storage change patterns derived from remotely sensed measurements are determined representative patterns for wet, dry and average conditions. The HRR-RR model dynamically selects and uses the optimal storage change pattern for the routing process based on these hydrologic conditions. The HRR-RR model results are presented to highlight the importance of lake attenuation/routing in the Congo Basin.

Summertime Minimum Streamflow Elasticity to Antecendent Winter Precipitation, Peak Snow Water Equivalent and Summertime Evaporative Demand in the Western US Maritime Mountains

NASA Astrophysics Data System (ADS)

Schaperow, J.; Cooper, M. G.; Cooley, S. W.; Alam, S.; Smith, L. C.; Lettenmaier, D. P.

2017-12-01

As climate regimes shift, streamflows and our ability to predict them will change, as well. Elasticity of summer minimum streamflow is estimated for 138 unimpaired headwater river basins across the maritime western US mountains to better understand how climatologic variables and geologic characteristics interact to determine the response of summer low flows to winter precipitation (PPT), spring snow water equivalent (SWE), and summertime potential evapotranspiration (PET). Elasticities are calculated using log log linear regression, and linear reservoir storage coefficients are used to represent basin geology. Storage coefficients are estimated using baseflow recession analysis. On average, SWE, PET, and PPT explain about 1/3 of the summertime low flow variance. Snow-dominated basins with long timescales of baseflow recession are least sensitive to changes in SWE, PPT, and PET, while rainfall-dominated, faster draining basins are most sensitive. There are also implications for the predictability of summer low flows. The R2 between streamflow and SWE drops from 0.62 to 0.47 from snow-dominated to rain-dominated basins, while there is no corresponding increase in R2 between streamflow and PPT.

Groundwater model of the Blue River basin, Nebraska-Twenty years later

USGS Publications Warehouse

Alley, W.M.; Emery, P.A.

1986-01-01

Groundwater flow models have become almost a routine tool of the practicing hydrologist. Yet, surprisingly little attention has been given to true verification analysis of studies using these models. This paper examines predictions for 1982 of water-level declines and streamflow depletions that were made in 1965 using an electric analog groundwater model of the Blue River basin in southeastern Nebraska. Analysis of the model's predictions suggests that the analog model used too low an estimate of net groundwater withdrawals, yet overestimated water-level declines. The model predicted that almost all of the net groundwater pumpage would come from storage in the Pleistocene aquifer within the Blue River basin. It appears likely that the model underestimated the contributions of other sources of water to the pumpage, and that the aquifer storage coefficients used in the model were too low. There is some evidence that groundwater pumpage has had a greater than predicted effect on streamflow. Considerable uncertainty about the basic conceptualization of the hydrology of the Blue River basin greatly limits the reliability of groundwater models developed for the basin. The paper concludes with general perspectives on groundwater modeling gained from this post-audit analysis. ?? 1986.

Relevance of hydro-climatic change projection and monitoring for assessment of water cycle changes in the Arctic.

PubMed

Bring, Arvid; Destouni, Georgia

2011-06-01

Rapid changes to the Arctic hydrological cycle challenge both our process understanding and our ability to find appropriate adaptation strategies. We have investigated the relevance and accuracy development of climate change projections for assessment of water cycle changes in major Arctic drainage basins. Results show relatively good agreement of climate model projections with observed temperature changes, but high model inaccuracy relative to available observation data for precipitation changes. Direct observations further show systematically larger (smaller) runoff than precipitation increases (decreases). This result is partly attributable to uncertainties and systematic bias in precipitation observations, but still indicates that some of the observed increase in Arctic river runoff is due to water storage changes, for example melting permafrost and/or groundwater storage changes, within the drainage basins. Such causes of runoff change affect sea level, in addition to ocean salinity, and inland water resources, ecosystems, and infrastructure. Process-based hydrological modeling and observations, which can resolve changes in evapotranspiration, and groundwater and permafrost storage at and below river basin scales, are needed in order to accurately interpret and translate climate-driven precipitation changes to changes in freshwater cycling and runoff. In contrast to this need, our results show that the density of Arctic runoff monitoring has become increasingly biased and less relevant by decreasing most and being lowest in river basins with the largest expected climatic changes.

Source, habitat and nutrient enrichment effects on decomposition of detritus in Lower Mississippi River Basin bayous

USDA-ARS?s Scientific Manuscript database

Potential differences in storage and processing of detritus in agricultural landscapes may alter freshwater ecosystem function. We compared decomposition rates of maize (Zea mays) and willow oak (Quercus phellos) from three bayous located within the Lower Mississippi River Basin of NW Mississippi, ...

EAST/WEST TRUCK BAY AREA OF TRANSFER BASIN CORRIDOR OF FUEL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

EAST/WEST TRUCK BAY AREA OF TRANSFER BASIN CORRIDOR OF FUEL STORAGE BUILDING (CPP-603). PHOTO TAKEN LOOKING NORTHWEST. INL PHOTO NUMBER HD-54-19-1. Mike Crane, Photographer, 8/2005 - Idaho National Engineering Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex, Scoville, Butte County, ID

Competences of Dominican College Students in the Comprehension of Superstructure and Macrostructure of Expositive Texts

ERIC Educational Resources Information Center

Tavarez, Pedro J.; Gomez, Jorge; Mercedes, Arismendy

2016-01-01

The objective of this research is to determine the competences of students of Basic Spanish Language II (Let. 012) in the comprehension of the superstructure and macrostructure of expository texts, in two college Campuses; the UASD San Francisco de Macorís Campus, and the UASD Bonao Campus for the semester 2015-2. The theory is based on the…

Impact of Water Withdrawals from Groundwater and Surface Water on Continental Water Storage Variations

NASA Technical Reports Server (NTRS)

Doell, Petra; Hoffmann-Dobrev, Heike; Portmann, Felix T.; Siebert, Stefan; Eicker, Annette; Rodell, Matthew; Strassberg, Gil

2011-01-01

Humans have strongly impacted the global water cycle, not only water flows but also water storage. We have performed a first global-scale analysis of the impact of water withdrawals on water storage variations, using the global water resources and use model WaterGAP. This required estimation of fractions of total water withdrawals from groundwater, considering five water use sectors. According to our assessment, the source of 35% of the water withdrawn worldwide (4300 cubic km/yr during 1998-2002) is groundwater. Groundwater contributes 42%, 36% and 27% of water used for irrigation, households and manufacturing, respectively, while we assume that only surface water is used for livestock and for cooling of thermal power plants. Consumptive water use was 1400 cubic km/yr during 1998-2002. It is the sum of the net abstraction of 250 cubic km/yr of groundwater (taking into account evapotranspiration and return flows of withdrawn surface water and groundwater) and the net abstraction of 1150 km3/yr of surface water. Computed net abstractions indicate, for the first time at the global scale, where and when human water withdrawals decrease or increase groundwater or surface water storage. In regions with extensive surface water irrigation, such as Southern China, net abstractions from groundwater are negative, i.e. groundwater is recharged by irrigation. The opposite is true for areas dominated by groundwater irrigation, such as in the High Plains aquifer of the central USA, where net abstraction of surface water is negative because return flow of withdrawn groundwater recharges the surface water compartments. In intensively irrigated areas, the amplitude of seasonal total water storage variations is generally increased due to human water use; however, in some areas, it is decreased. For the High Plains aquifer and the whole Mississippi basin, modeled groundwater and total water storage variations were compared with estimates of groundwater storage variations based on groundwater table observations, and with estimates of total water storage variations from the GRACE satellites mission. Due to the difficulty in estimating area-averaged seasonal groundwater storage variations from point observations of groundwater levels, it is uncertain whether WaterGAP underestimates actual variations or not. We conclude that WaterGAP possibly overestimates water withdrawals in the High Plains aquifer where impact of human water use on water storage is readily discernible based on WaterGAP calculations and groundwater observations. No final conclusion can be drawn regarding the possibility of monitoring water withdrawals in the High Plains aquifer using GRACE. For the less intensively irrigated Mississippi basin, observed and modeled seasonal groundwater storage reveals a discernible impact of water withdrawals in the basin, but this is not the case for total water storage such that water withdrawals at the scale of the whole Mississippi basin cannot be monitored by GRACE.

Controlling superstructural ordering in the clathrate-I Ba 8 M 16 P 30 (M = Cu, Zn) through the formation of metal–metal bonds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dolyniuk, J.; Whitfield, P. S.; Lee, K.

2017-01-01

Order–disorder–order phase transitions in the clathrate-I Ba8Cu16P30 were induced and controlled by aliovalent substitutions of Zn into the framework. Unaltered Ba8Cu16P30 crystallizes in an ordered orthorhombic (Pbcn) clathrate-I superstructure that maintains complete segregation of metal and phosphorus atoms over 23 different crystallographic positions in the clathrate framework. The driving force for the formation of this Pbcn superstructure is the avoidance of Cu–Cu bonds. This superstructure is preserved upon aliovalent substitution of Zn for Cu in Ba8Cu16-xZnxP30 with 0 < x < 1.6 (10% Zn/Mtotal), but vanishes at greater substitution concentrations. Higher Zn concentrations (up to 35% Zn/Mtotal) resulted in themore » additional substitution of Zn for P in Ba8M16+yP30-y (M = Cu, Zn) with 0 ≤ y ≤ 1. This causes the formation of Cu–Zn bonds in the framework, leading to a collapse of the orthorhombic superstructure into the more common cubic subcell of clathrate-I (Pm[3 with combining macron]n). In the resulting cubic phases, each clathrate framework position is jointly occupied by three different elements: Cu, Zn, and P. Detailed structural characterization of the Ba–Cu–Zn–P clathrates-I via single crystal X-ray diffraction, joint synchrotron X-ray and neutron powder diffractions, pair distribution function analysis, electron diffraction and high-resolution electron microscopy, along with elemental analysis, indicates that local ordering is present in the cubic clathrate framework, suggesting the evolution of Cu–Zn bonds. For the compounds with the highest Zn content, a disorder–order transformation is detected due to the formation of another superstructure with trigonal symmetry and Cu–Zn bonds in the clathrate-I framework. It is shown that small changes in the composition, synthesis, and crystal structure have significant impacts on the structural and transport properties of Zn-substituted Ba8Cu16P30.« less

COMBINED SEWER OVERFLOW - BALANCING FLOW FOR CSO ABATEMENT

EPA Science Inventory

Instead of using conventional storage units, e.g., reinforced concrete tanks and lined earthen basins, which are relatively expensive and require a lot of urban land area, the in-receiving water flow balance method (FBM) facilities use the receiving water body itself for storage ...

Improved Regional Water Management Utilizing Climate Forecasts: An Inter-basin Transfer Model with a Risk Management Framework

NASA Astrophysics Data System (ADS)

Li, W.; Arumugam, S.; Ranjithan, R. S.; Brill, E. D., Jr.

2014-12-01

Regional water supply systems undergo surplus and deficit conditions due to differences in inflow characteristics as well as due to their seasonal demand patterns. This study presents a framework for regional water management by proposing an Inter-Basin Transfer (IBT) model that uses climate-information-based inflow forecast for minimizing the deviations from the end- of-season target storage across the participating reservoirs. Using the ensemble streamflow forecast, the IBT water allocation model was applied for two reservoir systems in the North Carolina Triangle area. Results show that inter-basin transfers initiated by the ensemble streamflow forecast could potentially improve the overall water supply reliability as the demand continues to grow in the Triangle Area. To further understand the utility of climate forecasts in facilitating IBT under different spatial correlation structures between inflows and between the initial storages of the two systems, a synthetic experiment was designed to evaluate the framework under inflow forecast having different skills. Findings from the synthetic study can be summarized as follows: (a) Inflow forecasts combined with the proposed IBT optimization model provide improved allocation in comparison to the allocations obtained under the no- transfer scenario as well as under transfers obtained with climatology; (b) Spatial correlations between inflows and between initial storages among participating reservoirs could also influence the potential benefits that could be achieved through IBT; (c) IBT is particularly beneficial for systems that experience low correlations between inflows or between initial storages or on both attributes of the regional water supply system. Thus, if both infrastructure and permitting structures exist for promoting inter-basin transfers, season-ahead inflow forecasts could provide added benefits in forecasting surplus/deficit conditions among the participating reservoirs in the regional water supply system.

Geophysical Tools for an Improved Hydrogeologic Conceptual Model of the Big Chino Sub-basin, Central Arizona

NASA Astrophysics Data System (ADS)

Macy, J. P.; Kennedy, J.

2017-12-01

Water users and managers who rely on the Verde River system and its aquifers for water supplies have an intrinsic interest in developing the best possible tools for assessing the effects of groundwater withdrawals. Past, present, and future groundwater withdrawals from the Big Chino sub-basin will affect groundwater levels in the Big Chino area and groundwater discharge at the headwaters of the Verde River, specifically at the Upper Verde Springs, which is believed to be a major discharge zone of groundwater from the sub-basin. The amount and timing of reduced discharge as base flow is a function of connections between hydrogeologic (aquifer) units, aquifer storage properties and transmissivity, and proximity of withdrawal locations to discharge areas. To better define the aquifer units and aquifer storage properties, the United States Geological Survey, Cities of Prescott and Prescott Valley, and Salt River Project have initiated an ongoing geophysical study using controlled-source audio-frequency magnetotellurics (CSAMT) and repeat microgravity methods. CSAMT, a high-energy electromagnetic method sensitive to lithologic variations between rock and sediment types, is useful for defining aquifers at depths of up to 600 meters. Visual display of CSAMT profiles using Google Earth is useful for understanding and visualizing the relation between geophysics and Big Chino Sub-basin hydrogeology. Initial results from repeat microgravity surveys, which measure changes in subsurface mass (and therefore aquifer storage) over time, reveal spatial variation in the relation between aquifer storage changes and groundwater level changes. This variation reflects different confining conditions and multiple aquifer systems in different parts of the aquifer. Information about confining conditions and multiple aquifers could improve numerical groundwater models and predictions of future groundwater-level and base-flow depletion.

Comparison of evaporation at two central Florida lakes, April 2005–November 2007

USGS Publications Warehouse

Swancar, Amy

2015-09-25

Both lakes are seepage lakes (no surface-water inflow or outflows) that are dependent on groundwater inflow from their basins to offset an atmospheric deficit, because long-term rainfall in this area is less than evaporation. The Lake Starr basin, where sandy, well-drained ridges surround the lake, has a greater capacity to store infiltrating rain than the Lake Calm basin, which is flat and has poorly drained soils. The storage capacities of the basins affect groundwater exchange with the lakes. Rainfall and net groundwater exchange, which is related to basin characteristics, varied more between these two lakes than did evaporation during this study.

Meta-Generalis: A Novel Method for Structuring Information from Radiology Reports

PubMed Central

Barbosa, Flavio; Traina, Agma Jucci

2016-01-01

Summary Background A structured report for imaging exams aims at increasing the precision in information retrieval and communication between physicians. However, it is more concise than free text and may limit specialists’ descriptions of important findings not covered by pre-defined structures. A computational ontological structure derived from free texts designed by specialists may be a solution for this problem. Therefore, the goal of our study was to develop a methodology for structuring information in radiology reports covering specifications required for the Brazilian Portuguese language, including the terminology to be used. Methods We gathered 1,701 radiological reports of magnetic resonance imaging (MRI) studies of the lumbosacral spine from three different institutions. Techniques of text mining and ontological conceptualization of lexical units extracted were used to structure information. Ten radiologists, specialists in lumbosacral MRI, evaluated the textual superstructure and terminology extracted using an electronic questionnaire. Results The established methodology consists of six steps: 1) collection of radiology reports of a specific MRI examination; 2) textual decomposition; 3) normalization of lexical units; 4) identification of textual superstructures; 5) conceptualization of candidate-terms; and 6) evaluation of superstructures and extracted terminology by experts using an electronic questionnaire. Three different textual superstructures were identified, with terminological variations in the names of their textual categories. The number of candidate-terms conceptualized was 4,183, yielding 727 concepts. There were a total of 13,963 relationships between candidate-terms and concepts and 789 relationships among concepts. Conclusions The proposed methodology allowed structuring information in a more intuitive and practical way. Indications of three textual superstructures, extraction of lexicon units and the normalization and ontologically conceptualization were achieved while maintaining references to their respective categories and free text radiology reports. PMID:27580980

Meta-generalis: A novel method for structuring information from radiology reports.

PubMed

Barbosa, Flavio; Traina, Agma Jucci; Muglia, Valdair Francisco

2016-08-24

A structured report for imaging exams aims at increasing the precision in information retrieval and communication between physicians. However, it is more concise than free text and may limit specialists' descriptions of important findings not covered by pre-defined structures. A computational ontological structure derived from free texts designed by specialists may be a solution for this problem. Therefore, the goal of our study was to develop a methodology for structuring information in radiology reports covering specifications required for the Brazilian Portuguese language, including the terminology to be used. We gathered 1,701 radiological reports of magnetic resonance imaging (MRI) studies of the lumbosacral spine from three different institutions. Techniques of text mining and ontological conceptualization of lexical units extracted were used to structure information. Ten radiologists, specialists in lumbosacral MRI, evaluated the textual superstructure and terminology extracted using an electronic questionnaire. The established methodology consists of six steps: 1) collection of radiology reports of a specific MRI examination; 2) textual decomposition; 3) normalization of lexical units; 4) identification of textual superstructures; 5) conceptualization of candidate-terms; and 6) evaluation of superstructures and extracted terminology by experts using an electronic questionnaire. Three different textual superstructures were identified, with terminological variations in the names of their textual categories. The number of candidate-terms conceptualized was 4,183, yielding 727 concepts. There were a total of 13,963 relationships between candidate-terms and concepts and 789 relationships among concepts. The proposed methodology allowed structuring information in a more intuitive and practical way. Indications of three textual superstructures, extraction of lexicon units and the normalization and ontologically conceptualization were achieved while maintaining references to their respective categories and free text radiology reports.

Effects of groundwater levels and headwater wetlands on streamflow in the Charlie Creek basin, Peace River watershed, west-central Florida

USGS Publications Warehouse

Lee, T.M.; Sacks, L.A.; Hughes, J.D.

2010-01-01

The Charlie Creek basin was studied from April 2004 to December 2005 to better understand how groundwater levels in the underlying aquifers and storage and overflow of water from headwater wetlands preserve the streamflows exiting this least-developed tributary basin of the Peace River watershed. The hydrogeologic framework, physical characteristics, and streamflow were described and quantified for five subbasins of the 330-square mile Charlie Creek basin, allowing the contribution of its headwaters area and tributary subbasins to be separately quantified. A MIKE SHE model simulation of the integrated surface-water and groundwater flow processes in the basin was used to simulate daily streamflow observed over 21 months in 2004 and 2005 at five streamflow stations, and to quantify the monthly and annual water budgets for the five subbasins including the changing amount of water stored in wetlands. Groundwater heads were mapped in Zone 2 of the intermediate aquifer system and in the Upper Floridan aquifer, and were used to interpret the location of artesian head conditions in the Charlie Creek basin and its relation to streamflow. Artesian conditions in the intermediate aquifer system induce upward groundwater flow into the surficial aquifer and help sustain base flow which supplies about two-thirds of the streamflow from the Charlie Creek basin. Seepage measurements confirmed seepage inflow to Charlie Creek during the study period. The upper half of the basin, comprised largely of the Upper Charlie Creek subbasin, has lower runoff potential than the lower basin, more storage of runoff in wetlands, and periodically generates no streamflow. Artesian head conditions in the intermediate aquifer system were widespread in the upper half of the Charlie Creek basin, preventing downward leakage from expansive areas of wetlands and enabling them to act as headwaters to Charlie Creek once their storage requirements were met. Currently, the dynamic balance between wetland storage, rainfall-runoff processes, and groundwater-level differences in the upper basin allow it to generate approximately half of the streamflow from the Charlie Creek basin. Therefore, future development in the upper basin that would alter the hydraulic connectivity of wetlands during high flow conditions or expand recharging groundwater conditions could substantially affect streamflow in Charlie Creek. LIDAR (Light detection and ranging) based topographic maps and integrated modeling results were used to quantify the water stored in wetlands and other topographic depressions, and to describe the network of shallow stream channels connecting wetlands to Charlie Creek and its tributaries over distances of several thousand feet. Peak flows at all but one streamflow station were underpredicted in MIKE SHE simulations, possibly because the hydraulics of surface channels connecting wetlands to stream channels were not explicitly simulated in the model. Explicitly simulating the smaller channels connecting wetlands and stream channels should improve the ability of future watershed models to simulate peak flows in streams with headwater wetlands. The runoff potential was greater in the lower half of the Charlie Creek basin than in the upper half, and the streambed of Charlie Creek had greater potential to both directly gain streamflow from groundwater and lose streamflow to groundwater. Charlie Creek is more incised into the surficial aquifer in the lower basin than in the upper basin, and the streambed intersects the top of the intermediate aquifer system at two known locations. Groundwater levels in the intermediate aquifer system varied widely in the lower half of the basin from artesian conditions inducing upward flow toward the surficial aquifer and streams, to recharging conditions allowing downward flow and stream leakage. Recharge areas were greatest in May 2004 when rainfall was at a seasonal low and irrigation pumping was at a seasonal high. Recharge conditions

A Feasibility Study of Geologic Water Storage in Arid Regions

NASA Astrophysics Data System (ADS)

Fairley, J. P.; Preuit, T.

2001-05-01

An important control on the carrying capacity of arid and semi-arid regions is the ability to develop and maintain a reliable water supply for domestic and agricultural use. In the semi-arid highlands of southern Peru, the pre-Columbian Incas developed a technique of collecting and storing basin yields by controlling the discharge boundary of an existing aquifer. This water resource management strategy has been dubbed "Geologic Water Storage" (Fairley, in review). Yield from at least one such system near Cuzco, Peru, has provided a reliable source of irrigation water for rural farmers to the present day. The geologic water storage systems of southern Peru suggested the possibility of developing a similar system to water stock in rural Idaho. Annual precipitation in Idaho is about one-third that of southern Peru, and obtaining an adequate stock water supply is often problematic. The application of a simple lumped capacitance model to a selected basin in central Idaho showed that it may be physically and economically feasible to modify the basin characteristics to prolong water availability at the site. A more detailed study of this problem, that includes field characterization of the site, is necessary to substantiate the model results. If further studies and field trials confirm the viability of geologic water storage, this approach may find applications in many rural and developing areas, both nationally and internationally.

Analysis of sludge from Hanford K East Basin canisters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makenas, B.J.; Welsh, T.L.; Baker, R.B.

1997-09-12

Sludge samples from the canisters in the Hanford K East Basin fuel storage pool have been retrieved and analyzed. Both chemical and physical properties have been determined. The results are to be used to determine the disposition of the bulk of the sludge and to assess the impact of residual sludge on dry storage of the associated intact metallic uranium fuel elements. This report is a summary and review of the data provided by various laboratories. Although raw chemistry data were originally reported on various bases (compositions for as-settled, centrifuged, or dry sludge) this report places all of the datamore » on a common comparable basis. Data were evaluated for internal consistency and consistency with respect to the governing sample analysis plan. Conclusions applicable to sludge disposition and spent fuel storage are drawn where possible.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tao, J.; Sun, K.; Yin, W. -G.

The ground-state electronic order in doped manganites is frequently associated with a lattice modulation, contributing to their many interesting properties. However, measuring the thermal evolution of the lattice superstructure with reciprocal-space probes alone can lead to ambiguous results with competing interpretations. Here, we provide direct observations of the evolution of the superstructure in La 1/3Ca 2/3MnO 3 in real space, as well as reciprocal space, using transmission electron microscopic (TEM) techniques. We show that the transitions are the consequence of a proliferation of dislocations plus electronic phase separation. The resulting states are well described by the symmetries associated with electronic-liquid-crystalmore » (ELC) phases. Furthermore, our results resolve the long-standing controversy over the origin of the incommensurate superstructure and suggest a new structural model that is consistent with recent theoretical calculations.« less

Evolution of Moiré Profiles from van der Waals Superstructures of Boron Nitride Nanosheets

PubMed Central

Liao, Yunlong; Cao, Wei; Connell, John W.; Chen, Zhongfang; Lin, Yi

2016-01-01

Two-dimensional (2D) van der Waals (vdW) superstructures, or vdW solids, are formed by the precise restacking of 2D nanosheet lattices, which can lead to unique physical and electronic properties that are not available in the parent nanosheets. Moiré patterns formed by the crystalline mismatch between adjacent nanosheets are the most direct features for vdW superstructures under microscopic imaging. In this article, transmission electron microscopy (TEM) observation of hexagonal Moiré patterns with unusually large micrometer-sized lateral areas (up to ~1 μm2) and periodicities (up to ~50 nm) from restacking of liquid exfoliated hexagonal boron nitride nanosheets (BNNSs) is reported. This observation was attributed to the long range crystallinity and the contaminant-free surfaces of these chemically inert nanosheets. Parallel-line-like Moiré fringes with similarly large periodicities were also observed. The simulations and experiments unambiguously revealed that the hexagonal patterns and the parallel fringes originated from the same rotationally mismatched vdW stacking of BNNSs and can be inter-converted by simply tilting the TEM specimen following designated directions. This finding may pave the way for further structural decoding of other 2D vdW superstructure systems with more complex Moiré images. PMID:27188697

The emergence of superstructural order in insulin amyloid fibrils upon multiple rounds of self-seeding

NASA Astrophysics Data System (ADS)

Surmacz-Chwedoruk, Weronika; Babenko, Viktoria; Dec, Robert; Szymczak, Piotr; Dzwolak, Wojciech

2016-08-01

Typically, elongation of an amyloid fibril entails passing conformational details of the mother seed to daughter generations of fibrils with high fidelity. There are, however, several factors that can potentially prevent such transgenerational structural imprinting from perpetuating, for example heterogeneity of mother seeds or so-called conformational switching. Here, we examine phenotypic persistence of bovine insulin amyloid ([BI]) upon multiple rounds of self-seeding under quiescent conditions. According to infrared spectroscopy, with the following passages of homologous seeding, daughter fibrils gradually depart from the mother seed’s spectral characteristics. We note that this transgenerational structural drift in [BI] amyloid leads toward fibrils with infrared, chiroptical, and morphological traits similar to those of the superstructural variant of fibrils which normally forms upon strong agitation of insulin solutions. However, in contrast to agitation-induced insulin amyloid, the superstructural assemblies of daughter fibrils isolated through self-seeding are sonication-resistant. Our results suggest that formation of single amyloid fibrils is not a dead-end of the amyloidogenic self-assembly. Instead, the process appears to continue toward the self-assembly of higher-order structures although on longer time-scales. From this perspective, the fast agitation-induced aggregation of insulin appears to be a shortcut to amyloid superstructures whose formation under quiescent conditions is slow.

Electron microscope studies of nano-domain structures in Ru-based magneto-superconductors: RuSr(2)Gd(1.5)Ce(0.5)Cu(2)O(10-delta) (Ru-1222) and RuSr(2)GdCu(2)O(8) (Ru-1212).

PubMed

Yokosawa, Tadahiro; Awana, V P S Veer Pal Singh; Kimoto, Koji; Takayama-Muromachi, Eiji; Karppinen, Maarit; Yamauchi, Hisao; Matsui, Yoshio

2004-01-01

Microstructures of the RuSr(2)Gd(1.5)Ce(0.5)Cu(2)O(10-delta) (Ru-1222) and RuSr(2)GdCu(2)O(8) (Ru-1212) magneto-superconductors have been investigated by using selected-area electron diffraction, convergent-beam electron diffraction, dark-field electron microscopy and high-resolution electron microscopy at room temperature. Both Ru-1212 and Ru-1222 consist of nm-size domains stacked along the [Formula: see text] direction, where the domains are formed by two types of superstructures due to ordering of rotated RuO(6) octahedra about the c-axis. In Ru-1212, both primitive-and body-centered tetragonal superstructures (the possible space groups: P4/mbm and I4/mcm) are derived to form the corresponding nm-domains. It is of great interest that Ru-1212 consists of domains of two crystallographically different superstructures, while the similar domains observed in Ru-1222 have crystallographically identical superstructure with an orthorhombic symmetry (possible space group: Aeam), related by 90 degrees rotation around the c-axis (Yokosawa et al., 2003, submitted for publication).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Long; Department of Chemistry, Huangshan University, Huangshan 245041; Post-Doctoral Scientific Research Workstation, HuangShan NOVEL Co. Ltd, Huangshan 245061

In this paper, biomimetic synthesis of aragonite superstructures using a low molecular weight organic-hexamethylenetetramine (HMT) as an additive in the presence of CO{sub 2} supplied by an ammonium carbonate ((NH{sub 4}){sub 2}CO{sub 3}) diffusion method at room temperature was studied. The products were characterized by scanning or transmission electron microscopy, Fourier transform infrared (FT-IR) spectroscopy, X-ray powder diffractometry, and selected area electron diffraction. The results showed the aragonite superstructures especially dumbbell-flower-like ones were obtained. The formation process of calcium carbonate (CaCO{sub 3}) in HMT aqueous solution was investigated, suggesting that the products transformed from calcite to vaterite primarily, and thenmore » changed into a mixture of aragonite and calcite with an increase of reaction time. The formation mechanism of CaCO{sub 3} in HMT solution was also discussed, revealing that aragonite might be controlled by HMT molecules and NH{sub 4}{sup +} ions together. - Graphical abstract: The well-defined aragonite hierarchical superstructures are formed using hexamethylenetetramine in aqueous solution. Highlights: > Aragonite superstructures are formed with hexamethylenetetramine at about 25 deg. C. > Dumbbell-flower-like aragonite produces when hexamethylenetetramine/Ca{sup 2+}=10:1. > CaCO{sub 3} formation in hexamethylenetetramine solution violates the Ostwald ripening. > Hexamethylenetetramine and NH{sub 4}{sup +} might control the growth of aragonite together.« less

Mach Number effects on turbulent superstructures in wall bounded flows

NASA Astrophysics Data System (ADS)

Kaehler, Christian J.; Bross, Matthew; Scharnowski, Sven

2017-11-01

Planer and three-dimensional flow field measurements along a flat plat boundary layer in the Trisonic Wind Tunnel Munich (TWM) are examined with the aim to characterize the scaling, spatial organization, and topology of large scale turbulent superstructures in compressible flow. This facility is ideal for this investigation as the ratio of boundary layer thickness to test section spanwise extent ratio is around 1/25, ensuring minimal sidewall and corner effects on turbulent structures in the center of the test section. A major difficulty in the experimental investigation of large scale features is the mutual size of the superstructures which can extend over many boundary layer thicknesses. Using multiple PIV systems, it was possible to capture the full spatial extent of large-scale structures over a range of Mach numbers from Ma = 0.3 - 3. To calculate the average large-scale structure length and spacing, the acquired vector fields were analyzed by statistical multi-point methods that show large scale structures with a correlation length of around 10 boundary layer thicknesses over the range of Mach numbers investigated. Furthermore, the average spacing between high and low momentum structures is on the order of a boundary layer thicknesses. This work is supported by the Priority Programme SPP 1881 Turbulent Superstructures of the Deutsche Forschungsgemeinschaft.

Flood characteristics of urban watersheds in the United States

USGS Publications Warehouse

Sauer, Vernon B.; Thomas, W.O.; Stricker, V.A.; Wilson, K.V.

1983-01-01

A nationwide study of flood magnitude and frequency in urban areas was made for the purpose of reviewing available literature, compiling an urban flood data base, and developing methods of estimating urban floodflow characteristics in ungaged areas. The literature review contains synopses of 128 recent publications related to urban floodflow. A data base of 269 gaged basins in 56 cities and 31 States, including Hawaii, contains a wide variety of topographic and climatic characteristics, land-use variables, indices of urbanization, and flood-frequency estimates. Three sets of regression equations were developed to estimate flood discharges for ungaged sites for recurrence intervals of 2, 5, 10, 25, 50, 100, and 500 years. Two sets of regression equations are based on seven independent parameters and the third is based on three independent parameters. The only difference in the two sets of seven-parameter equations is the use of basin lag time in one and lake and reservoir storage in the other. Of primary importance in these equations is an independent estimate of the equivalent rural discharge for the ungaged basin. The equations adjust the equivalent rural discharge to an urban condition. The primary adjustment factor, or index of urbanization, is the basin development factor, a measure of the extent of development of the drainage system in the basin. This measure includes evaluations of storm drains (sewers), channel improvements, and curb-and-gutter streets. The basin development factor is statistically very significant and offers a simple and effective way of accounting for drainage development and runoff response in urban areas. Percentage of impervious area is also included in the seven-parameter equations as an additional measure of urbanization and apparently accounts for increased runoff volumes. This factor is not highly significant for large floods, which supports the generally held concept that imperviousness is not a dominant factor when soils become more saturated during large storms. Other parameters in the seven-parameter equations include drainage area size, channel slope, rainfall intensity, lake and reservoir storage, and basin lag time. These factors are all statistically significant and provide logical indices of basin conditions. The three-parameter equations include only the three most significant parameters: rural discharge, basin-development factor, and drainage area size. All three sets of regression equations provide unbiased estimates of urban flood frequency. The seven-parameter regression equations without basin lag time have average standard errors of regression varying from ? 37 percent for the 5-year flood to ? 44 percent for the 100-year flood and ? 49 percent for the 500-year flood. The other two sets of regression equations have similar accuracy. Several tests for bias, sensitivity, and hydrologic consistency are included which support the conclusion that the equations are useful throughout the United States. All estimating equations were developed from data collected on drainage basins where temporary in-channel storage, due to highway embankments, was not significant. Consequently, estimates made with these equations do not account for the reducing effect of this temporary detention storage.

Assessing Reservoir Depositional Environments to Develop and Quantify Improvements in CO 2 Storage Efficiency. A Reservoir Simulation Approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Okwen, Roland; Frailey, Scott; Leetaru, Hannes

2014-09-30

The storage potential and fluid movement within formations are dependent on the unique hydraulic characteristics of their respective depositional environments. Storage efficiency (E) quantifies the potential for storage in a geologic depositional environment and is used to assess basinal or regional CO 2 storage resources. Current estimates of storage resources are calculated using common E ranges by lithology and not by depositional environment. The objectives of this project are to quantify E ranges and identify E enhancement strategies for different depositional environments via reservoir simulation studies. The depositional environments considered include deltaic, shelf clastic, shelf carbonate, fluvial deltaic, strandplain, reef,more » fluvial and alluvial, and turbidite. Strategies considered for enhancing E include CO 2 injection via vertical, horizontal, and deviated wells, selective completions, water production, and multi-well injection. Conceptual geologic and geocellular models of the depositional environments were developed based on data from Illinois Basin oil fields and gas storage sites. The geologic and geocellular models were generalized for use in other US sedimentary basins. An important aspect of this work is the development of conceptual geologic and geocellular models that reflect the uniqueness of each depositional environment. Different injection well completions methods were simulated to investigate methods of enhancing E in the presence of geologic heterogeneity specific to a depositional environment. Modeling scenarios included horizontal wells (length, orientation, and inclination), selective and dynamic completions, water production, and multiwell injection. A Geologic Storage Efficiency Calculator (GSECalc) was developed to calculate E from reservoir simulation output. Estimated E values were normalized to diminish their dependency on fluid relative permeability. Classifying depositional environments according to normalized baseline E ranges ranks fluvial deltaic and turbidite highest and shelf carbonate lowest. The estimated average normalized baseline E of turbidite, and shelf carbonate depositional environments are 42.5% and 13.1%, with corresponding standard deviations of 11.3%, and 3.10%, respectively. Simulations of different plume management techniques suggest that the horizontal well, multi-well injection with brine production from blanket vertical producers are the most efficient E enhancement strategies in seven of eight depositional environments; for the fluvial deltaic depositional environment, vertical well with blanket completions is the most efficient. This study estimates normalized baseline E ranges for eight depositional environments, which can be used to assess the CO 2 storage resource of candidate formations. This study also improves the general understanding of depositional environment’s influence on E. The lessons learned and results obtained from this study can be extrapolated to formations in other US basins with formations of similar depositional environments, which should be used to further refine regional and national storage resource estimates in future editions of the Carbon Utilization and Storage Atlas of the United States. Further study could consider the economic feasibility of the E enhancement strategies identified here.« less

Evaluation of Cask Drop Criticality Issues at K Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

GOLDMANN, L.H.

An analysis of ability of Multi-canister Overpack (MCO) to withstand drops at K Basin without exceeding the criticality design requirements. Report concludes the MCO will function acceptably. The spent fuel currently residing in the 105 KE and 105 KW storage basins will be placed in fuel storage baskets which will be loaded into the MCO cask assembly. During the basket loading operations the MCO cask assembly will be positioned near the bottom of the south load out pit (SLOP). The loaded MCO cask will be lifted from the SLOP transferred to the transport trailer and delivered to the Cold Vacuummore » Drying Facility (CVDF). In the wet condition there is a potential for criticality problems if significant changes in the designed fuel configurations occur. The purpose of this report is to address structural issues associated with criticality design features for MCO cask drop accidents in the 105 KE and 105 KW facilities.« less

Beyond annual streamflow reconstructions for the Upper Colorado River Basin: a paleo-water-balance approach

USGS Publications Warehouse

Gangopadhyay, Subhrendu; McCabe, Gregory J.; Woodhouse, Connie A.

2015-01-01

In this paper, we present a methodology to use annual tree-ring chronologies and a monthly water balance model to generate annual reconstructions of water balance variables (e.g., potential evapotrans- piration (PET), actual evapotranspiration (AET), snow water equivalent (SWE), soil moisture storage (SMS), and runoff (R)). The method involves resampling monthly temperature and precipitation from the instrumental record directed by variability indicated by the paleoclimate record. The generated time series of monthly temperature and precipitation are subsequently used as inputs to a monthly water balance model. The methodology is applied to the Upper Colorado River Basin, and results indicate that the methodology reliably simulates water-year runoff, maximum snow water equivalent, and seasonal soil moisture storage for the instrumental period. As a final application, the methodology is used to produce time series of PET, AET, SWE, SMS, and R for the 1404–1905 period for the Upper Colorado River Basin.

76 FR 30320 - Public Scoping Meeting and Preparation of Environmental Impact Statement for Luce Bayou...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-25

... involvement associated with the proposed action is the discharge or dredged or fill material into waters of... affect navigable waters. Federal authorizations for the proposed project would constitute a ``major... sedimentation settling basin. c. An approximate 20-acre sedimentation settling and storage basin. d. An...

Simulation of rainfall-runoff response in mined and unmined watersheds in coal areas of West Virginia

USGS Publications Warehouse

Puente, Celso; Atkins, John T.

1989-01-01

Meteorologic and hydrologic data from five small watersheds in the coal areas of West Virginia were used to calibrate and test the U.S. Geological Survey Precipitation-Runoff Modeling System for simulating streamflow under various climatic and land-use conditions. Three of the basins--Horsecamp Run, Gilmer Run, and Collison Creek--are primarily forested and relatively undisturbed. The remaining basins--Drawdy Creek and Brier Creek-are extensively mined, both surface and underground above stream drainage level. Low-flow measurements at numerous synoptic sites in the mined basins indicate that coal mining has substantially altered the hydrologic system of each basin. The effects of mining on streamflow that were identified are (1) reduced base flow in stream segments underlain by underground mines, (2) increased base flow in streams that are downdip and stratigraphically below the elevation of the mined coal beds, and (3) interbasin transfer of ground water through underground mines. These changes probably reflect increased permeability of surface rocks caused by subsidence fractures associated with collapsed underground mines in the basin. Such fractures would increase downward percolation of precipitation, surface and subsurface flow, and ground-water flow to deeper rocks or to underground mine workings. Model simulations of the water budgets for the unmined basins during the 1972-73 water years indicate that total annual runoff averaged 60 percent of average annual precipitation; annual evapotranspiration losses averaged 40 percent of average annual precipitation. Of the total annual runoff, approximately 91 percent was surface and subsurface runoff and 9 percent was groundwater discharge. Changes in storage in the soil zone and in the subsurface and ground-water reservoirs in the basins were negligible. In contrast, water-budget simulations for the mined basins indicate significant differences in annual recharge and in total annual runoff. Model simulations of the water budget for Drawdy Creek basin indicate that total annual runoff during 1972-73 averaged only 43 percent of average annual precipitation--the lowest of all study basins; annual evapotranspiration losses averaged 49 percent, and interbasin transfer of ground-water losses averaged about 8 percent. Of the total annual runoff, approximately 74 percent was surface and subsurface flow and 26 percent was ground-water discharge. The low total annual runoff at Drawdy Creek probably reflects increased recharge of precipitation and surface and subsurface flow losses to ground water. Most of the increase in ground-water storage is, in turn, lost to a ground-water sink--namely, interbasin transfer of ground water by gravity drainage and (or) mine pumpage from underground mines that extend to adjacent basins. Hypothetical mining situations were posed for model analysis to determine the effects of increased mining on streamflow in the mined basins. Results of model simulations indicate that streamflow characteristics, the water budget, and the seasonal distribution of streamflow would be significantly modified in response to an increase in mining in the basins. Simulations indicate that (1) total annual runoff in the basins would decrease because of increased surface- and subsurface-flow losses and increased recharge of precipitation to ground water (these losses would tend to reduce medium to high flows mainly during winter and spring when losses would be greatest), (2) extreme high flows in response to intense rainstorms would be negligibly affected, regardless of the magnitude of mining in the basins, (3) ground-water discharge also would decrease during winter and spring, but the amount and duration of low flows during summer and fall would substantially increase in response to increased ground-water storage in rocks and in underground mines, and (4) the increase in ground-water storage in the basins would be depleted, mostly by increased losses to a grou

The Contribution of Reservoirs to Global Land Surface Water Storage Variations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Tian; Nijssen, Bart; Gao, Huilin

Man-made reservoirs play a key role in the terrestrial water system. They alter water fluxes at the land surface and impact surface water storage through water management regulations for diverse purposes such as irrigation, municipal water supply, hydropower generation, and flood control. Although most developed countries have established sophisticated observing systems for many variables in the land surface water cycle, long-term and consistent records of reservoir storage are much more limited and not always shared. Furthermore, most land surface hydrological models do not represent the effects of water management activities. Here, the contribution of reservoirs to seasonal water storage variationsmore » is investigated using a large-scale water management model to simulate the effects of reservoir management at basin and continental scales. The model was run from 1948 to 2010 at a spatial resolution of 0.258 latitude–longitude. A total of 166 of the largest reservoirs in the world with a total capacity of about 3900 km3 (nearly 60%of the globally integrated reservoir capacity) were simulated. The global reservoir storage time series reflects the massive expansion of global reservoir capacity; over 30 000 reservoirs have been constructed during the past half century, with a mean absolute interannual storage variation of 89 km3. The results indicate that the average reservoir-induced seasonal storage variation is nearly 700 km3 or about 10%of the global reservoir storage. For some river basins, such as the Yellow River, seasonal reservoir storage variations can be as large as 72%of combined snow water equivalent and soil moisture storage.« less

Convection Cells in the Atmospheric Boundary Layer

NASA Astrophysics Data System (ADS)

Fodor, Katherine; Mellado, Juan-Pedro

2017-04-01

In dry, shear-free convective boundary layers (CBLs), the turbulent flow of air is known to organise itself on large scales into coherent, cellular patterns, or superstructures, consisting of fast, narrow updraughts and slow, wide downdraughts which together form circulations. Superstructures act as transport mechanisms from the surface to the top of the boundary layer and vice-versa, as opposed to small-scale turbulence, which only modifies conditions locally. This suggests that a thorough investigation into superstructure properties may help us better understand transport across the atmospheric boundary layer as a whole. Whilst their existence has been noted, detailed studies into superstructures in the CBL have been scarce. By applying methods which are known to successfully isolate similar large-scale patterns in turbulent Rayleigh-Bénard convection, we can assess the efficacy of those detection techniques in the CBL. In addition, through non-dimensional analysis, we can systematically compare superstructures in various convective regimes. We use direct numerical simulation of four different cases for intercomparison: Rayleigh-Bénard convection (steady), Rayleigh-Bénard convection with an adiabatic top lid (quasi-steady), a stably-stratified CBL (quasi-steady) and a neutrally-stratified CBL (unsteady). The first two are non-penetrative and the latter two penetrative. We find that although superstructures clearly emerge from the time-mean flow in the non-penetrative cases, they become obscured by temporal averaging in the CBL. This is because a rigid lid acts to direct the flow into counter-rotating circulation cells whose axis of rotation remains stationary, whereas a boundary layer that grows in time and is able to entrain fluid from above causes the circulations to not only grow in vertical extent, but also to move horizontally and merge with neighbouring circulations. Spatial filtering is a useful comparative technique as it can be performed on boundary layers of the same depth, defined from the surface to the height at which the turbulent kinetic energy (TKE) is zero (in non-penetrative cases) or less than 10% of its maximum value (in penetrative cases). We find that with increasing filter width, the contribution of the filtered flow to the total TKE in the middle of the boundary layer decreases much more rapidly in the penetrative cases than in the non-penetrative cases. In particular, around 20-25% of the TKE at this height comes from small-scale turbulence with a length scale less than or equal to 15% of the boundary layer depth in the CBL, whereas in Rayleigh-Bénard convection, it is just 6-7%. This is consistent with visualisations, which show that entrainment creates additional small-scale mixing within the large-scale circulations in the CBL. Without entrainment, large-scale organisation predominates. Neither spatial nor temporal filtering are as successful at extracting superstructures in the penetrative cases as in the non-penetrative cases. Hence, these techniques depend not on the steadiness of the system, but rather on the presence of entrainment. We therefore intend to try other detection techniques, such as proper orthogonal decomposition, in order to make a rigorous assessment of which is most effective for isolating superstructures in all four cases.

Effects of including surface depressions in the application of the Precipitation-Runoff Modeling System in the Upper Flint River Basin, Georgia

USGS Publications Warehouse

Viger, Roland J.; Hay, Lauren E.; Jones, John W.; Buell, Gary R.

2010-01-01

This report documents an extension of the Precipitation Runoff Modeling System that accounts for the effect of a large number of water-holding depressions in the land surface on the hydrologic response of a basin. Several techniques for developing the inputs needed by this extension also are presented. These techniques include the delineation of the surface depressions, the generation of volume estimates for the surface depressions, and the derivation of model parameters required to describe these surface depressions. This extension is valuable for applications in basins where surface depressions are too small or numerous to conveniently model as discrete spatial units, but where the aggregated storage capacity of these units is large enough to have a substantial effect on streamflow. In addition, this report documents several new model concepts that were evaluated in conjunction with the depression storage functionality, including: ?hydrologically effective? imperviousness, rates of hydraulic conductivity, and daily streamflow routing. All of these techniques are demonstrated as part of an application in the Upper Flint River Basin, Georgia. Simulated solar radiation, potential evapotranspiration, and water balances match observations well, with small errors for the first two simulated data in June and August because of differences in temperatures from the calibration and evaluation periods for those months. Daily runoff simulations show increasing accuracy with streamflow and a good fit overall. Including surface depression storage in the model has the effect of decreasing daily streamflow for all but the lowest flow values. The report discusses the choices and resultant effects involved in delineating and parameterizing these features. The remaining enhancements to the model and its application provide a more realistic description of basin geography and hydrology that serve to constrain the calibration process to more physically realistic parameter values.

The effect of modeled recharge distribution on simulated groundwater availability and capture.

PubMed

Tillman, F D; Pool, D R; Leake, S A

2015-01-01

Simulating groundwater flow in basin-fill aquifers of the semiarid southwestern United States commonly requires decisions about how to distribute aquifer recharge. Precipitation can recharge basin-fill aquifers by direct infiltration and transport through faults and fractures in the high-elevation areas, by flowing overland through high-elevation areas to infiltrate at basin-fill margins along mountain fronts, by flowing overland to infiltrate along ephemeral channels that often traverse basins in the area, or by some combination of these processes. The importance of accurately simulating recharge distributions is a current topic of discussion among hydrologists and water managers in the region, but no comparative study has been performed to analyze the effects of different recharge distributions on groundwater simulations. This study investigates the importance of the distribution of aquifer recharge in simulating regional groundwater flow in basin-fill aquifers by calibrating a groundwater-flow model to four different recharge distributions, all with the same total amount of recharge. Similarities are seen in results from steady-state models for optimized hydraulic conductivity values, fit of simulated to observed hydraulic heads, and composite scaled sensitivities of conductivity parameter zones. Transient simulations with hypothetical storage properties and pumping rates produce similar capture rates and storage change results, but differences are noted in the rate of drawdown at some well locations owing to the differences in optimized hydraulic conductivity. Depending on whether the purpose of the groundwater model is to simulate changes in groundwater levels or changes in storage and capture, the distribution of aquifer recharge may or may not be of primary importance. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.

Regional assessment of aquifers for thermal energy storage. Volume 1: Regions 1 through 6

NASA Astrophysics Data System (ADS)

1981-06-01

The geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the western mountains, alluvial basins, Columbia LAVA plateau, Colorado plateau, high plains, and glaciated central region are discussed.

Physical and economic potential of geological CO2 storage in saline aquifers.

PubMed

Eccles, Jordan K; Pratson, Lincoln; Newell, Richard G; Jackson, Robert B

2009-03-15

Carbon sequestration in sandstone saline reservoirs holds great potential for mitigating climate change, but its storage potential and cost per ton of avoided CO2 emissions are uncertain. We develop a general model to determine the maximum theoretical constraints on both storage potential and injection rate and use it to characterize the economic viability of geosequestration in sandstone saline aquifers. When applied to a representative set of aquifer characteristics, the model yields results that compare favorably with pilot projects currently underway. Over a range of reservoir properties, maximum effective storage peaks at an optimal depth of 1600 m, at which point 0.18-0.31 metric tons can be stored per cubic meter of bulk volume of reservoir. Maximum modeled injection rates predict minima for storage costs in a typical basin in the range of $2-7/ ton CO2 (2005 U.S.$) depending on depth and basin characteristics in our base-case scenario. Because the properties of natural reservoirs in the United States vary substantially, storage costs could in some cases be lower or higher by orders of magnitude. We conclude that available geosequestration capacity exhibits a wide range of technological and economic attractiveness. Like traditional projects in the extractive industries, geosequestration capacity should be exploited starting with the low-cost storage options first then moving gradually up the supply curve.

The role of storage capacity in coping with intra-annual runoff variability on a global scale

NASA Astrophysics Data System (ADS)

Gaupp, Franziska; Hall, Jim; Dadson, Simon

2015-04-01

Intra-annual variability poses a risk to water security in many basins as runoff is unevenly distributed over the year. Areas such as Northern Africa, Australia and the South-Western USA are characterized by a high coefficient of variability of monthly runoff. Analyzing the global risk of water scarcity, this study examines 680 basin-country units (BCUs) (403 river basins divided by country borders). By calculating the water balance for each BCU, the interplay of runoff on the one hand and domestic, industrial and environmental water needs on the other hand is shown. In contrast to other studies on average water scarcity, this work focuses on variability of water supply as metrics based on annual average water availability and demand can underestimate the risk of scarcity. The model is based on the assumption that each country-basin with sub-basins and tributaries can be treated as one single reservoir with storage capacity aggregated over that BCU. It includes surface runoff and the possibility to withdraw groundwater as water supply. The storage capacity of each BCU represents the ability to transfer water from wet months to dry months in order to buffer and cope with intra-annual water supply variability and to meet total water demand. Average monthly surface runoff per country-basin for the period 1979 to 2012 is derived from outcomes of the hydrological model Mac-PDM. Mac-PDM is forced with monthly ERAI-Interim reanalysis climate data on a one degree resolution. Groundwater withdrawal capacity, total water demand and storage capacity are taken from the IMPACT model provided by the International Food Research Institute (IFPRI). Storage refers to any kind of surface reservoir whose water can be managed and used for human activities in the industrial, domestic and agricultural sectors. Groundwater withdrawal capacity refers to the technological capacity to pump water rather than the amount of groundwater available. Total water demand includes consumptive water use from the industrial, domestic and agricultural sectors and varies between months. Due to a lack of data, the 2010 figures for groundwater withdrawal capacity are assumed to be equally distributed over 12 months without accounting for possible variation within a year. For runoff and water demand, monthly data are used. Our study shows that storage capacity helps to cope with intra-annual water variability and thereby decreases the risk of water scarcity. Several cases emerge where water security is critically dependent on transboundary flows such as the Nile in Egypt or the Aral Drainage in Uzbekistan. Furthermore, we calculate environmental flow requirements using the Variable Monthly Flow (VMF) method and analyse the effects of abstraction and dam construction on environmental flows. For each BCU, we examine whether environmental water requirements can be met with given human abstractions. Additionally, water scarcity is examined for the case when water is reserved for the environment and cannot be abstracted for human purposes.

The origin of the superstructure in Bi2Sr2CaCu2O(8+delta) as revealed by scanning tunneling microscopy

NASA Astrophysics Data System (ADS)

Kirk, M. D.; Nogami, J.; Baski, A. A.; Mitzi, D. B.; Kapitulnik, A.

1988-12-01

Real-space images with atomic resolution of the BiO plane of Bi2Sr2CaCu2O(8+delta) were obtained with a scanning tunneling microscope. Single-crystal samples were cleaved and imaged under ultrahigh vacuum conditions at room temperature. The images clearly show the one-dimensional incommensurate superstructure along the b-axis that is common to this phase. High-resolution images show the position of the Bi atoms, revelaing the structural nature of the superlattice. A missing row of Bi atoms occurs either every nine or ten atomic sites in both 110-line directions, accounting for the measured incommensurate periodicity of the superstructure. A model is proposed that includes missing rows of atoms, as well as displacements of the atomic positions along both the a- and c-axis directions.

The Origin of the Superstructure in Bi2Sr2CaCu2O8+dgr as Revealed by Scanning Tunneling Microscopy.

PubMed

Kirk, M D; Nogami, J; Baski, A A; Mitzi, D B; Kapitulnik, A; Geballe, T H; Quate, C F

1988-12-23

Real-space images with atomic resolution of the BiO plane of Bi(2)Sr(2)CaCu(2)O(8+delta) were obtained with a scanning tunneling microscope. Single-crystal samples were cleaved and imaged under ultrahigh vacuum conditions at room temperature. The images clearly show the one-dimensional incommensurate superstructure along the b-axis that is common to this phase. High-resolution images show the position of the Bi atoms, revealing the structural nature of the superlattice. A missing row of Bi atoms occurs either every nine or ten atomic sites in both (110) directions, accounting for the measured incommensurate periodicity of the superstructure. A model is proposed that includes missing rows of atoms, as well as displacements of the atomic positions along both the a- and c-axis directions.

Long-range two-dimensional superstructure in the superconducting electron-doped cuprate Pr 0.88 LaCe 0.12 CuO 4

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campbell, B. J.; Rosenkranz, S.; Kang, H. J.

2015-07-01

Utilizing single-crystal synchrotron x-ray scattering, we observe distorted CuO 2 planes in the electron- doped superconductor Pr 1-xLaCe xCuO 4+δ , x =0.12. Resolution-limited rods of scattering are indicative of a long-range two-dimensional 2√2 × 2√2 superstructure in the a-b plane, adhering to planar space-group symmetry p4gm, which is subject to stacking disorder perpendicular to the planes. This superstructure is present only in annealed, superconducting samples, but not in the as-grown, nonsuperconducting samples. These long-range distortions of the CuO 2 planes, which are generally considered to be detrimental to superconductivity, have avoided detection to date due to the challenges ofmore » observing and interpreting subtle diffuse-scattering features.« less

Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La 1/3Ca 2/3MnO 3

DOE PAGES

Tao, J.; Sun, K.; Yin, W. -G.; ...

2016-11-22

The ground-state electronic order in doped manganites is frequently associated with a lattice modulation, contributing to their many interesting properties. However, measuring the thermal evolution of the lattice superstructure with reciprocal-space probes alone can lead to ambiguous results with competing interpretations. Here, we provide direct observations of the evolution of the superstructure in La 1/3Ca 2/3MnO 3 in real space, as well as reciprocal space, using transmission electron microscopic (TEM) techniques. We show that the transitions are the consequence of a proliferation of dislocations plus electronic phase separation. The resulting states are well described by the symmetries associated with electronic-liquid-crystalmore » (ELC) phases. Furthermore, our results resolve the long-standing controversy over the origin of the incommensurate superstructure and suggest a new structural model that is consistent with recent theoretical calculations.« less

Solar Synthesis of PbS-SnS2 Superstructure Nanoparticles.

PubMed

Brontvein, Olga; Albu-Yaron, Ana; Levy, Moshe; Feuerman, Daniel; Popovitz-Biro, Ronit; Tenne, Reshef; Enyashin, Andrey; Gordon, Jeffrey M

2015-08-25

We report the synthesis and supporting density-functional-theory computations for a closed-cage, misfit layered-compound superstructure from PbS-SnS2, generated by highly concentrated sunlight from a precursor mixture of Pb, SnS2, and graphite. The unique reactor conditions created in our solar furnace are found to be particularly conducive to the formation of these nanomaterials. Detailed structural and chemical characterization revealed a spontaneous inside-out formation mechanism, with a broad range of nonhollow fullerene-like structures starting at a diameter of ∼20 nm and a wall thickness of ∼5 layers. The computations also reveal a counterintuitive charge transfer pathway from the SnS2 layers to the PbS layers, which indicates that, in contrast to binary-layered compounds where it is principally van der Waals forces that hold the layers together, polar forces appear to be as important in stabilizing superstructures of misfit layered compounds.

Calibration parameters used to simulate streamflow from application of the Hydrologic Simulation Program-FORTRAN Model (HSPF) to mountainous basins containing coal mines in West Virginia

USGS Publications Warehouse

Atkins, John T.; Wiley, Jeffrey B.; Paybins, Katherine S.

2005-01-01

This report presents the Hydrologic Simulation Program-FORTRAN Model (HSPF) parameters for eight basins in the coal-mining region of West Virginia. The magnitude and characteristics of model parameters from this study will assist users of HSPF in simulating streamflow at other basins in the coal-mining region of West Virginia. The parameter for nominal capacity of the upper-zone storage, UZSN, increased from south to north. The increase in UZSN with the increase in basin latitude could be due to decreasing slopes, decreasing rockiness of the soils, and increasing soil depths from south to north. A special action was given to the parameter for fraction of ground-water inflow that flows to inactive ground water, DEEPFR. The basis for this special action was related to the seasonal movement of the water table and transpiration from trees. The models were most sensitive to DEEPFR and the parameter for interception storage capacity, CEPSC. The models were also fairly sensitive to the parameter for an index representing the infiltration capacity of the soil, INFILT; the parameter for indicating the behavior of the ground-water recession flow, KVARY; the parameter for the basic ground-water recession rate, AGWRC; the parameter for nominal capacity of the upper zone storage, UZSN; the parameter for the interflow inflow, INTFW; the parameter for the interflow recession constant, IRC; and the parameter for lower zone evapotranspiration, LZETP.

Analysis for Eccentric Multi Canister Overpack (MCO) Drops at the Canister Storage Building (CSB) (CSB-S-0073)

DOE Office of Scientific and Technical Information (OSTI.GOV)

HOLLENBECK, R.G.

The Spent Nuclear Fuel (SNF) Canister Storage Building (CSB) is the interim storage facility for the K-Basin SNF at the US. Department of Energy (DOE) Hanford Site. The SNF is packaged in multi-canister overpacks (MCOs). The MCOs are placed inside transport casks, then delivered to the service station inside the CSB. At the service station, the MCO handling machine (MHM) moves the MCO from the cask to a storage tube or one of two sample/weld stations. There are 220 standard storage tubes and six overpack storage tubes in a below grade reinforced concrete vault. Each storage tube can hold twomore » MCOs.« less

Use of a stochastic approach for description of water balance and runoff production dynamics

NASA Astrophysics Data System (ADS)

Gioia, A.; Manfreda, S.; Iacobellis, V.; Fiorentino, M.

2009-04-01

The present study exploits an analytical model (Manfreda, NHESS [2008]) for the description of the probability density function of soil water balance and runoff generation over a set of river basins belonging to Southern Italy. The model is based on a stochastic differential equation where the rainfall forcing is interpreted as an additive noise in the soil water balance; the watershed heterogeneity is described exploiting the conceptual lumped watershed Xinanjiang model (widely used in China) that uses a parabolic curve for the distribution of the soil water storage capacity (Zhao et al. [1980]). The model, characterized by parameters that depend on soil, vegetation and basin morphology, allowed to derive the probability density function of the relative saturation and the surface runoff of a basin accounting for the spatial heterogeneity in soil water storage. Its application on some river basins belonging to regions of Southern Italy, gives interesting insights for the investigation of the role played by the dynamical interaction between climate, soil, and vegetation in soil moisture and runoff production dynamics. Manfreda, S., Runoff Generation Dynamics within a Humid River Basin, Natural Hazard and Earth System Sciences, 8, 1349-1357, 2008. Zhao, R. -J., Zhang, Y. L., and Fang, L. R.: The Xinanjiang model, Hydrological Forecasting Proceedings Oxford Symposium, IAHS Pub. 129, 351-356, 1980.

Basin Scale Estimates of Evapotranspiration Using GRACE and other Observations

NASA Technical Reports Server (NTRS)

Rodell, M.; Famiglietti, J. S.; Chen, J.; Seneviratne, S. I.; Viterbo, P.; Holl, S.; Wilson, C. R.

2004-01-01

Evapotranspiration is integral to studies of the Earth system, yet it is difficult to measure on regional scales. One estimation technique is a terrestrial water budget, i.e., total precipitation minus the sum of evapotranspiration and net runoff equals the change in water storage. Gravity Recovery and Climate Experiment (GRACE) satellite gravity observations are now enabling closure of this equation by providing the terrestrial water storage change. Equations are presented here for estimating evapotranspiration using observation based information, taking into account the unique nature of GRACE observations. GRACE water storage changes are first substantiated by comparing with results from a land surface model and a combined atmospheric-terrestrial water budget approach. Evapotranspiration is then estimated for 14 time periods over the Mississippi River basin and compared with output from three modeling systems. The GRACE estimates generally lay in the middle of the models and may provide skill in evaluating modeled evapotranspiration.

Large-scale runoff generation - parsimonious parameterisation using high-resolution topography

NASA Astrophysics Data System (ADS)

Gong, L.; Halldin, S.; Xu, C.-Y.

2011-08-01

World water resources have primarily been analysed by global-scale hydrological models in the last decades. Runoff generation in many of these models are based on process formulations developed at catchments scales. The division between slow runoff (baseflow) and fast runoff is primarily governed by slope and spatial distribution of effective water storage capacity, both acting at very small scales. Many hydrological models, e.g. VIC, account for the spatial storage variability in terms of statistical distributions; such models are generally proven to perform well. The statistical approaches, however, use the same runoff-generation parameters everywhere in a basin. The TOPMODEL concept, on the other hand, links the effective maximum storage capacity with real-world topography. Recent availability of global high-quality, high-resolution topographic data makes TOPMODEL attractive as a basis for a physically-based runoff-generation algorithm at large scales, even if its assumptions are not valid in flat terrain or for deep groundwater systems. We present a new runoff-generation algorithm for large-scale hydrology based on TOPMODEL concepts intended to overcome these problems. The TRG (topography-derived runoff generation) algorithm relaxes the TOPMODEL equilibrium assumption so baseflow generation is not tied to topography. TRG only uses the topographic index to distribute average storage to each topographic index class. The maximum storage capacity is proportional to the range of topographic index and is scaled by one parameter. The distribution of storage capacity within large-scale grid cells is obtained numerically through topographic analysis. The new topography-derived distribution function is then inserted into a runoff-generation framework similar VIC's. Different basin parts are parameterised by different storage capacities, and different shapes of the storage-distribution curves depend on their topographic characteristics. The TRG algorithm is driven by the HydroSHEDS dataset with a resolution of 3" (around 90 m at the equator). The TRG algorithm was validated against the VIC algorithm in a common model framework in 3 river basins in different climates. The TRG algorithm performed equally well or marginally better than the VIC algorithm with one less parameter to be calibrated. The TRG algorithm also lacked equifinality problems and offered a realistic spatial pattern for runoff generation and evaporation.

Large-scale runoff generation - parsimonious parameterisation using high-resolution topography

NASA Astrophysics Data System (ADS)

Gong, L.; Halldin, S.; Xu, C.-Y.

2010-09-01

World water resources have primarily been analysed by global-scale hydrological models in the last decades. Runoff generation in many of these models are based on process formulations developed at catchments scales. The division between slow runoff (baseflow) and fast runoff is primarily governed by slope and spatial distribution of effective water storage capacity, both acting a very small scales. Many hydrological models, e.g. VIC, account for the spatial storage variability in terms of statistical distributions; such models are generally proven to perform well. The statistical approaches, however, use the same runoff-generation parameters everywhere in a basin. The TOPMODEL concept, on the other hand, links the effective maximum storage capacity with real-world topography. Recent availability of global high-quality, high-resolution topographic data makes TOPMODEL attractive as a basis for a physically-based runoff-generation algorithm at large scales, even if its assumptions are not valid in flat terrain or for deep groundwater systems. We present a new runoff-generation algorithm for large-scale hydrology based on TOPMODEL concepts intended to overcome these problems. The TRG (topography-derived runoff generation) algorithm relaxes the TOPMODEL equilibrium assumption so baseflow generation is not tied to topography. TGR only uses the topographic index to distribute average storage to each topographic index class. The maximum storage capacity is proportional to the range of topographic index and is scaled by one parameter. The distribution of storage capacity within large-scale grid cells is obtained numerically through topographic analysis. The new topography-derived distribution function is then inserted into a runoff-generation framework similar VIC's. Different basin parts are parameterised by different storage capacities, and different shapes of the storage-distribution curves depend on their topographic characteristics. The TRG algorithm is driven by the HydroSHEDS dataset with a resolution of 3'' (around 90 m at the equator). The TRG algorithm was validated against the VIC algorithm in a common model framework in 3 river basins in different climates. The TRG algorithm performed equally well or marginally better than the VIC algorithm with one less parameter to be calibrated. The TRG algorithm also lacked equifinality problems and offered a realistic spatial pattern for runoff generation and evaporation.

Reviving the Ganges Water Machine: potential

NASA Astrophysics Data System (ADS)

Amarasinghe, Upali Ananda; Muthuwatta, Lal; Surinaidu, Lagudu; Anand, Sumit; Jain, Sharad Kumar

2016-03-01

The Ganges River basin faces severe water challenges related to a mismatch between supply and demand. Although the basin has abundant surface water and groundwater resources, the seasonal monsoon causes a mismatch between supply and demand as well as flooding. Water availability and flood potential is high during the 3-4 months (June-September) of the monsoon season. Yet, the highest demands occur during the 8-9 months (October-May) of the non-monsoon period. Addressing this mismatch, which is likely to increase with increasing demand, requires substantial additional storage for both flood reduction and improvements in water supply. Due to hydrogeological, environmental, and social constraints, expansion of surface storage in the Ganges River basin is problematic. A range of interventions that focus more on the use of subsurface storage (SSS), and on the acceleration of surface-subsurface water exchange, has long been known as the Ganges Water Machine (GWM). The approach of the GWM for providing such SSS is through additional pumping and depleting of the groundwater resources prior to the onset of the monsoon season and recharging the SSS through monsoon surface runoff. An important condition for creating such SSS is the degree of unmet water demand. The paper shows that the potential unmet water demand ranging from 59 to 124 Bm3 year-1 exists under two different irrigation water use scenarios: (i) to increase irrigation in the Rabi (November-March) and hot weather (April-May) seasons in India, and the Aman (July-November) and Boro (December-May) seasons in Bangladesh, to the entire irrigable area, and (ii) to provide irrigation to Rabi and the hot weather season in India and the Aman and Boro seasons in Bangladesh to the entire cropped area. However, the potential for realizing the unmet irrigation demand is high only in 7 sub-basins in the northern and eastern parts, is moderate to low in 11 sub-basins in the middle, and has little or no potential in 4 sub-basins in the western part of the Ganges basin. Overall, a revived GWM plan has the potential to meet 45-84 Bm3year-1 of unmet water demand.

Drought propagation in the Paraná Basin, Brazil: from rainfall deficits to impacts on reservoir storage

NASA Astrophysics Data System (ADS)

Melo, D. D.; Wendland, E.

2017-12-01

The sensibility and resilience of hydrologic systems to climate changes are crucial for estimating potential impacts of droughts, responsible for major economic and human losses globally. Understanding how droughts propagate is a key element to develop a predictive understanding for future management and mitigation strategies. In this context, this study investigated the drought propagation in the Paraná Basin (PB), Southeast Brazil, a major hydroelectricity producing region with 32 % (60 million people) of the country's population. Reservoir storage (RESS), river discharge (Q) and rainfall (P) data were used to assess the linkages between meteorological and hydrological droughts, characterized by the Standard Precipitation Index (SPI) and Streamflow Drought Index (SDI), respectively. The data are from 37 sub-basins within the PB, consisting of contributing areas of 37 reservoirs (250 km3 of stored water) within the PB for the period between 1995 and 2015. The response time (RT) of the hydrologic system to droughts, given as the time lag between P, Q and RESS, was quantified using a non-parametric statistical method that combines cumulative sums and Bootstrap resampling technique. Based on our results, the RTs of the hydrologic system of the PB varies from 0 to 6 months, depending on a number of aspects: lithology, topography, dam operation, etc. Linkages between SPI and SDI indicated that the anthropogenic control (dam operation) plays an important role in buffering drought impacts to downstream sub-basins: SDI decreased from upstream to downstream despite similar SPI values over the whole area. Comparisons between sub-basins, with variable drainage sizes (5,000 - 50,000 km2), confirmed the benefice of upstream reservoirs in reducing hydrological droughts. For example, the RT for a 4,800 km2 basin was 6 months between P and Q and 9 months between Q and RESS, under anthropogenic control. Conversely, the RT to precipitation for a reservoir subjected to natural controls only (no major human influence on storage and routing) was less than 1 month for both Q and RESS. This study underscores the importance of the reservoirs in the Paraná basin in reducing drought impacts on water supply and energy generation.

Hydrologic reconnaissance of the Wah Wah Valley drainage basin, Millard and Beaver Counties, Utah

USGS Publications Warehouse

Stephens, Jerry C.

1974-01-01

The Wah Wah Valley drainage basin is an area of about 600 square miles (1,550 km2) in Millard and Beaver Counties in southwestern Utah. Surface-water supplies of the area are negligible--total runoff averages about 7,800 acre-feet (9.62 hm3) annually, all streams are ephemeral or intermittent, and surface storage is negligible. Evaporation and transpiration within the basin consume more than 97 percent of total annual precipitation. There is no surface outflow.

Commitment to Excellence: A History of the Sacramento District U.S. Army Corps of Engineers 1929-1973

DTIC Science & Technology

1976-01-01

consist of Daguerre Point Dam, which forms a storage basin for debris, and some fifteen miles of training walls de- signed to keep the river within...obtaining up to the date of passage of this act owners of property anywhere in the basin were at liberty to reclaim practically as they pleased, with...Yolo Basin some 21 miles of the east levee had been constructed, and another twenty miles had been planned and approved. When completed, about forty

Water in urban planning, Salt Creek Basin, Illinois water management as related to alternative land-use practices

USGS Publications Warehouse

Spieker, Andrew Maute

1970-01-01

Water management can be an integral part of urban comprehensive planning in a large metropolitan area. Water both imposes constraints on land use and offers opportunities for coordinated land and water management. Salt Creek basin in Cook and Du Page Counties of the Chicago metropolitan area is typical of rapidly developing suburban areas and has been selected to illustrate some of these constraints and opportunities and to suggest the effects of alternative solutions. The present study concentrates on the related problems of ground-water recharge, water quality, management of flood plains, and flood-control measures. Salt Creek basin has a drainage area of 150 square miles. It is in flat to. gently rolling terrain, underlain by glacial drift as much as 200 feet thick which covers a dolomite aquifer. In 1964, the population of the basin was about 400,000, and 40 percent of the land was in urban development. The population is expected to number 550,000 to 650,000 by 1990, and most of the land will be taken by urban development. Salt Creek is a sluggish stream, typical of small drainage channels in the headwaters area of northeastern Illinois. Low flows of 15 to 25 cubic feet per second in the lower part of the basin consist largely of sewage effluent. Nearly all the public water supplies in the basin depend on ground water. Of the total pumpage of 27.5 million gallons per day, 17.5 million gallons per day is pumped from the deep (Cambrian-Ordovician) aquifers and 10 million gallons per day is pumped from the shallow (Silurian dolomite and glacial drift) aquifers. The potential yield of the shallow aquifers, particularly glacial drift in the northern part of the basin, far exceeds present use. The largest concentration of pumpage from the shallow ,aquifers is in the Hinsdale-La Grange area. Salt Creek serves as an important source of recharge to these supplies, particularly just east of Hinsdale. The entire reach of Salt Creek south and east of Elmhurst can be regarded as an area of potential recharge to the shallow aquifers. Preservation of the effectiveness of these potential recharge areas should be considered in land-use planning. Salt Creek is polluted in times of both low and high flow. Most communities in the basin in Du Page County discharge their treated sewage into the creek, whereas those in Cook County transfer their sewage to plants of the Metropolitan Sanitary District outside the basin. During periods of high runoff, combined storm runoff and overflow from sanitary sewers enter the creek. Such polluted water detracts from the stream's esthetic and recreational potential and poses a threat to ground-water supplies owing to induced recharge of polluted water to shallow aquifers. Alternative approaches .to the pollution problem include improvement of the degree of sewage treatment, detention and treatment of storm runoff, dilution of sewage through flow augmentation, or transfer of sewage from the basin to a central treatment plant. To result in an enhanced environment, the streambed would have to be cleansed of accumulated sludge deposits. The overbank flooding in Salt Creek basin every 2 to 3 years presents problems because of encroachments and developments on the flood plains. Flood plains in an urban area can be managed by identifying them, by recognizing that either their natural storage capacity or equivalent artificial capacity is needed to accommodate floods, and by planning land use accordingly. Examples of effective floodplain management include (1) preservation of greenbelts or regional parks along stream courses, (2) use of flood plains for recreation, parking lots. or other low-intensity uses, (3) use of flood-proofed commercial buildings, and (4) provision for compensatory storage to replace natural storage capacity. Results of poor flood-plain management include uncontrolled residential development and encroachment by fill into natural storage areas where no compensatory storage has been

Small angle neutron and X-ray studies of carbon structures with metal atoms

NASA Astrophysics Data System (ADS)

Lebedev, V. T.; Szhogina, A. A.; Bairamukov, V. Yu

2017-05-01

Encapsulation of metal atoms inside carbon single-wall cages or within multi-layer cells has been realized using molecular precursors and high temperature processes transforming them into desirable structures. Endohedral fullerenols Fe@C60(OH)X with 3d-metal (iron) have been studied by SANS in aqueous solutions where they form stable globular clusters with radii R C ∼ 10-12 nm and aggregation numbers N C ∼ 104. This self-assembly is a crucial feature of paramagnetic fullerenols as perspective contrast agents for Magneto-Resonance Imaging in medicine. Cellular carbon-metal structures have been created by the pyrolysis of diphthalocyanines of lanthanides and actinides. It was established that these ultra porous matrices consist of globular cells of molecular precursor size (∼ 1 nm) which are aggregated into superstructures. This provides retain of metal atoms inside matrices which may serve for safety storage of spent fuel of nuclear power plants.

15. The 183Filter Plant with settling basins in January 1945. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. The 183-Filter Plant with settling basins in January 1945. The 182-B Reservoir and Pump House is on the left in the background, and the coal storage pond for the 184-B Power House is in the upper right. View is to the northwest. P-8012 - B Reactor, Richland, Benton County, WA

GRACE Detected Rise of Groundwater in the Sahelian Niger River Basin

NASA Astrophysics Data System (ADS)

Werth, S.; White, D.; Bliss, D. W.

2017-12-01

West African regions along the Niger River experience climate and land cover changes that affect hydrological processes and therewith the distribution of fresh water resources (WR). This study provides an investigation of long-term changes in terrestrial water storages (TWS) of the Niger River basin and its subregions by analyzing a decade of satellite gravity data from the Gravity Recovery and Climate Experiment (GRACE) mission. The location of large trends in TWS maps of differently processed GRACE solutions points to rising groundwater stocks. Soil moisture data from a global land surface model allow separating the effect of significantly increasing amount of WR from that of TWS variations. Surface water variations from a global water storage model validated with observations from altimetry data were applied to estimate the groundwater component in WR. For the whole Niger, a rise in groundwater stocks is estimated to be 93 ± 61 km3 between January 2003 and December 2013. A careful analysis of uncertainties in all data sets supports the significance of the groundwater rise. Our results confirm previous observations of rising water tables, indicating that effects of land cover changes on groundwater storage are relevant on basin scales. Areas with rising water storage are stocking a comfortable backup to mitigate possible future droughts and to deliver water to remote areas. This has implications for Niger water management strategies. Increasing groundwater recharges may be accompanied by reduction in water quality. This study helps to inform authority's decision to mitigate its negative impacts on local communities.

Satellite Observations of Drought and Falling Water Storage in the Colorado River Basin and Lake Mead

NASA Astrophysics Data System (ADS)

Castle, S.; Famiglietti, J. S.; Reager, J. T.; Thomas, B.

2012-12-01

Over the past decade the Western US has experienced extreme drought conditions, which have affected both agricultural and urban areas. An example of water infrastructure being impacted by these droughts is Lake Mead, the largest reservoir in the United States at its full capacity that provides water and energy for several states in the Western US. Once Lake Mead falls below the critical elevation of 1050 feet above sea level, the Hoover Dam, the structure that created Lake Mead by damming flow within the Colorado River, will stop producing energy for Las Vegas. The Gravity Recovery and Climate Experiment (GRACE) satellites, launched in 2002, have proven successful for monitoring changes in water storage over large areas, and give hydrologists a first-ever picture of how total water storage is changing spatially and temporally within large regions. Given the importance of the Colorado River to meet water demands to several neighboring regions, including Southern California, it is vital to understand how water is transported and managed throughout the basin. In this research, we use hydrologic remote sensing to characterize the human and natural water balance of the Colorado River basin and Lake Mead. The research will include quantifying the amount of Colorado River water delivered to Southern California, coupling the GRACE Total Water Storage signal of the Upper and Lower Colorado River with Landsat-TM satellite imagery and areal extent of Lake Mead water storage, and combining these data together to determine the current status of water availability in the Western US. We consider water management and policy changes necessary for sustainable water practices including human water use, hydropower, and ecosystem services in arid regions throughout the Western US.

Decision Support System for Aquifer Recharge (AR) and Aquifer Storage and Recovery (ASR) Planning, Design, and Evaluation - Principles and Technical Basis

EPA Science Inventory

Aquifer recharge (AR) is a technical method being utilized to enhance groundwater resources through man-made replenishment means, such as infiltration basins and injections wells. Aquifer storage and recovery (ASR) furthers the AR techniques by withdrawal of stored groundwater at...

Brine Flow Up a Borehole Caused by Pressure Perturbation From CO2 Storage: Static and Dynamic Evaluations

EPA Science Inventory

Industrial-scale storage of CO2 in saline sedimentary basins will cause zones of elevated pressure, larger than the CO2 plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards al...

Rotational superstructure in van der Waals heterostructure of self-assembled C 60 monolayer on the WSe 2 surface

DOE PAGES

Santos, Elton J. G.; Scullion, Declan; Chu, Ximo S.; ...

2017-08-23

Hybrid van der Waals (vdW) heterostructures composed of two-dimensional (2D) layered materials and self-assembled organic molecules are promising systems for electronic and optoelectronic applications with enhanced properties and performance. Control of molecular assembly is therefore paramount to fundamentally understand the nucleation, ordering, alignment, and electronic interaction of organic molecules with 2D materials. Here, we report the formation and detailed study of highly ordered, crystalline monolayers of C 60 molecules self-assembled on the surface of WSe 2 in well-ordered arrays with large grain sizes (~5 μm). Using high-resolution scanning tunneling microscopy (STM), we observe a periodic 2 × 2 superstructure inmore » the C 60 monolayer and identify four distinct molecular appearances. Using vdW-corrected ab initio density functional theory (DFT) simulations, we determine that the interplay between vdW and Coulomb interactions as well as adsorbate–adsorbate and adsorbate–substrate interactions results in specific rotational arrangements of the molecules forming the superstructure. The orbital ordering through the relative positions of bonds in adjacent molecules creates a charge redistribution that links the molecule units in a long-range network. Furthermore, this rotational superstructure extends throughout the self-assembled monolayer and opens a pathway towards engineering aligned hybrid organic/inorganic vdW heterostructures with 2D layered materials in a precise and controlled way.« less

Rotational superstructure in van der Waals heterostructure of self-assembled C 60 monolayer on the WSe 2 surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Santos, Elton J. G.; Scullion, Declan; Chu, Ximo S.

Hybrid van der Waals (vdW) heterostructures composed of two-dimensional (2D) layered materials and self-assembled organic molecules are promising systems for electronic and optoelectronic applications with enhanced properties and performance. Control of molecular assembly is therefore paramount to fundamentally understand the nucleation, ordering, alignment, and electronic interaction of organic molecules with 2D materials. Here, we report the formation and detailed study of highly ordered, crystalline monolayers of C 60 molecules self-assembled on the surface of WSe 2 in well-ordered arrays with large grain sizes (~5 μm). Using high-resolution scanning tunneling microscopy (STM), we observe a periodic 2 × 2 superstructure inmore » the C 60 monolayer and identify four distinct molecular appearances. Using vdW-corrected ab initio density functional theory (DFT) simulations, we determine that the interplay between vdW and Coulomb interactions as well as adsorbate–adsorbate and adsorbate–substrate interactions results in specific rotational arrangements of the molecules forming the superstructure. The orbital ordering through the relative positions of bonds in adjacent molecules creates a charge redistribution that links the molecule units in a long-range network. Furthermore, this rotational superstructure extends throughout the self-assembled monolayer and opens a pathway towards engineering aligned hybrid organic/inorganic vdW heterostructures with 2D layered materials in a precise and controlled way.« less

Hydrology of the North Cascades region, Washington: 2. A proposed hydrometeorological streamflow prediction method

USGS Publications Warehouse

Tangborn, Wendell V.; Rasmussen, Lowell A.

1976-01-01

On the basis of a linear relationship between winter (October-April) precipitation and annual runoff from a drainage basin (Rasmussen and Tangborn, 1976) a physically reasonable model for predicting summer (May-September) streamflow from drainages in the North Cascades region was developed. This hydrometeorological prediction method relates streamflow for a season beginning on the day of prediction to the storage (including snow, ice, soil moisture, and groundwater) on that day. The spring storage is inferred from an input-output relationship based on the principle of conservation of mass: spring storage equals winter precipitation on the basin less winter runoff from the basin and less winter evapotranspiration, which is presumed to be small. The method of prediction is based on data only from the years previous to the one for which the prediction is made, and the system is revised each year as data for the previous year become available. To improve the basin storage estimate made in late winter or early spring, a short-season runoff prediction is made. The errors resulting from this short-term prediction are used to revise the storage estimate and improve the later prediction. This considerably improves the accuracy of the later prediction, especially for periods early in the summer runoff season. The optimum length for the test period appears to be generally less than a month for east side basins and between 1 and 2 months for those on the west side of the Cascade Range. The time distribution of the total summer runoff can be predicted when this test season is used so that on May 1 monthly streamflow for the May-September season can be predicted. It was found that summer precipitation and the time of minimum storage are two error sources that were amenable to analysis. For streamflow predictions in seasons beginning in early spring the deviation of the subsequent summer precipitation from a long-period average will contribute up to 53% of the prediction error. This contribution decreases to nearly zero during the summer and then rises slightly for late summer predictions. The reason for the smaller than expected effect of summer precipitation is thought to be due to the compensating effect of increased evaporative losses and increased infiltration when precipitation is greater than normal during the summer months. The error caused by the beginning winter month (assumed to be October in this study) not coinciding with the time of minimum storage was examined; it appears that October may be the best average beginning winter month for most drainages but that a more detailed study is needed. The optimum beginning of the winter season appears to vary from August to October when individual years are examined. These results demonstrate that standard precipitation and runoff measurements in the North Cascades region are adequate for constructing a predictive hydrologic model. This model can be used to make streamflow predictions that compare favorably with current multiple regression methods based on mountain snow surveys. This method has the added advantages of predicting the space and time distributions of storage and summer runoff.

From Drought to Recovery: a GRACE-Based Assessment of Groundwater Storage Variations in California

NASA Astrophysics Data System (ADS)

McEvoy, A.; Famiglietti, J. S.; Liu, P. W.; Reager, J. T., II

2017-12-01

The 2011-2015 drought in California was the most severe on record and significantly depleted state water reserves. However, after the consecutive wet winters of 2015-16 and 2016-17, water storage in reservoirs, soil, snowpack, and aquifers began recovering and the state government lifted the drought emergency for all California counties except four. But is the drought really "over"? Quantifiable metrics of groundwater storage are necessary to provide such evidence, yet in situ measurements are sparse at best. Here we holistically test whether California state water resources have fully recovered in the Sacramento, San Joaquin, and Tulare Lake basins of California, using remote sensing satellite observations, in situ measurements, and numerical models. Specifically, we partition water storage into four components of the terrestrial water cycle: soil moisture, snow water equivalent, surface water, and groundwater. We derive soil moisture and snow water equivalent from the North American Land Data Assimilation System (NLDAS) and we use the California Data Exchange Center (CDEC) network to measure in situ reservoir storage. To estimate changes in groundwater storage, we subtract these three components from the total water storage derived from the Gravity Recovery and Climate Experiment (GRACE) satellite. Preliminary results show that the groundwater storage plummeted to a record low during the 2011-2015 drought. The results also show a rapid recovery in total water storage from 2015-2017. Moreover, we find that groundwater accounts for, on average, 60% of the total water storage variations in the study basins. Our results hold social significance when placed in the context of arid California: Did the groundwater recover? Is this the largest recovery that California can expect? Finally, our results have implications for the utility of remote sensing to inform water resource management decisions.

The Coal-Seq III Consortium. Advancing the Science of CO 2 Sequestration in Coal Seam and Gas Shale Reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koperna, George

The Coal-Seq consortium is a government-industry collaborative that was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO2 sequestration in deep, unmineable coal seams. The consortium’s objective aimed to advancing industry’s understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. Research from this collaborative effort was utilized to produce modules to enhance reservoir simulation and modeling capabilities to assess the technical and economic potential for CO2 storage and enhanced coalbed methane recovery in coal basins. Coal-Seq Phase 3more » expands upon the learnings garnered from Phase 1 & 2, which has led to further investigation into refined model development related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins the extension of the work to gas shale reservoirs, and continued global technology exchange. The first research objective assesses changes in coal and shale properties with exposure to CO2 under field replicated conditions. Results indicate that no significant weakening occurs when coal and shale were exposed to CO2, therefore, there was no need to account for mechanical weakening of coal due to the injection of CO2 for modeling. The second major research objective evaluates cleat, Cp, and matrix, Cm, swelling/shrinkage compressibility under field replicated conditions. The experimental studies found that both Cp and Cm vary due to changes in reservoir pressure during injection and depletion under field replicated conditions. Using laboratory data from this study, a compressibility model was developed to predict the pore-volume compressibility, Cp, and the matrix compressibility, Cm, of coal and shale, which was applied to modeling software to enhance model robustness. Research was also conducted to improve algorithms and generalized adsorption models to facilitate realistic simulation of CO2 sequestration in coal seams and shale gas reservoirs. The interaction among water and the adsorbed gases, carbon dioxide (CO2), methane (CH4), and nitrogen (N2) in coalbeds is examined using experimental in situ laboratory techniques to comprehensively model CBM production and CO2 sequestration in coals. An equation of state (EOS) module was developed which is capable of predicting the density of pure components and mixtures involving the wet CBM gases CH4, CO2, and N2 at typical reservoir condition, and is used to inform CO2 injection models. The final research objective examined the effects adsorbed CO2 has on coal strength and permeability. This research studied the weakening or failure of coal by the adsorption of CO2 from empirically derived gas production data to develop models for advanced modeling of permeability changes during CO2 sequestration. The results of this research effort have been used to construct a new and improved model for assessing changes in permeability of coal reservoirs due CO2 injection. The modules developed from these studies and knowledge learned are applied to field validation and basin assessment studies. These data were used to assess the flow and storage of CO2 in a shale reservoir, test newly developed code against large-scale projects, and conduct a basin-oriented review of coal storage potential in the San Juan Basin. The storage potential and flow of CO2 was modeled for shale sequestration of a proprietary Marcellus Shale horizontal gas production well using COMET3 simulation software. Simulation results from five model runs indicate that stored CO2 quantities are linked to the duration of primary production preceding injection. Matrix CO2 saturation is observed to increase in each shale zone after injection with an increase in primary production, and the size of the CO2 plume is also observed to increase in size the longer initial production is sustained. The simulation modules developed around the Coal-Seq experimental work are also incorporated into a pre-existing large-scale numerical simulation model of the Pump Canyon CO2-ECBM pilot in the San Juan Basin. The new model was applied to re-history match the data set to explore the improvements made in permeability prediction against previously published data sets and to validate this module. The assessment of the new data, however, indicates that the impact of the variable Cp is negligible on the overall behavior of the coal for CO2 storage purposes. Applying these new modules, the San Juan Basin and the Marcellus Shale are assessed for their technical ECBM/AGR and CO2 storage potential and the economic potential of these operations. The San Juan Basin was divided into 4 unique geographic zones based on production history, and the Marcellus was divided into nine. Each was assessed based upon each zone’s properties, and simulations were run to assess the potential of full Basin development. Models of a fully developed San Juan Basin suggest the potential for up to 104 Tcf of CO2 storage, and 12.3 Tcf of methane recovery. The Marcellus models suggest 1,248 Tcf of CO2 storage and 924 Tcf of AGR. The economics are deemed favorable where credits cover the cost of CO2 in the San Juan Basin, and in many cases in the Marcellus, but to maximize storage potential, credits need to extend to pay the operator to store CO2.« less

Numerical Simulation of Ground-Water Flow and Assessment of the Effects of Artificial Recharge in the Rialto-Colton Basin, San Bernardino County, California

USGS Publications Warehouse

Woolfenden, Linda R.; Koczot, Kathryn M.

2001-01-01

The Rialto?Colton Basin, in western San Bernardino County, California, was chosen for storage of imported water because of the good quality of native ground water, the known storage capacity for additional ground-water storage in the basin, and the availability of imported water. To supplement native ground-water resources and offset overdraft conditions in the basin during dry periods, artificial-recharge operations during wet periods in the Rialto?Colton Basin were begun in 1982 to store surplus imported water. Local water purveyors recognized that determining the movement and ultimate disposition of the artificially recharged imported water would require a better understanding of the ground-water flow system. In this study, a finite-difference model was used to simulate ground-water flow in the Rialto?Colton Basin to gain a better understanding of the ground-water flow system and to evaluate the hydraulic effects of artificial recharge of imported water. The ground-water basin was simulated as four horizontal layers representing the river- channel deposits and the upper, middle, and lower water-bearing units. Several flow barriers bordering and internal to the Rialto?Colton Basin influence the direction of ground-water flow. Ground water may flow relatively unrestricted in the shallow parts of the flow system; however, the faults generally become more restrictive at depth. A particle-tracking model was used to simulate advective transport of imported water within the ground-water flow system and to evaluate three artificial-recharge alternatives. The ground-water flow model was calibrated to transient conditions for 1945?96. Initial conditions for the transient-state simulation were established by using 1945 recharge and discharge rates, and assuming no change in storage in the basin. Average hydrologic conditions for 1945?96 were used for the predictive simulations (1997?2027). Ground-water-level measurements made during 1945 were used for comparison with the initial-conditions simulation to determine if there was a reasonable match, and thus reasonable starting heads, for the transient simulation. The comparison between simulated head and measured water levels indicates that, overall, the simulated heads match measured water levels well; the goodness-of-fit value is 0.99. The largest differences between simulated head and measured water level occurred between Barrier H and the Rialto?Colton Fault. Simulated heads near the Santa Ana River and Warm Creek, and simulated heads northwest of Barrier J, generally are within 30 feet of measured water levels and five are within 20 feet. Model-simulated heads were compared with measured long-term changes in hydrographs of composite water levels in selected wells, and with measured short-term changes in hydrographs of water levels in multiple-depth observation wells installed for this project. Simulated hydraulic heads generally matched measured water levels in wells northwest of Barrier J (in the northwestern part of the basin) and in the central part of the basin during 1945?96. In addition, the model adequately simulated water levels in the southeastern part of the basin near the Santa Ana River and Warm Creek and east of an unnamed fault that subparallels the San Jacinto Fault. Simulated heads and measured water levels in the central part of the basin generally are within 10 feet until about 1982?85 when differences become greater. In the northwestern part of the basin southeast of Barrier J, simulated heads were as much as 50 feet higher than measured water levels during 1945?82 but matched measured water levels well after 1982. In the compartment between Barrier H and the Rialto?Colton Fault, simulated heads match well during 1945?82 but are comparatively low during 1982?96. Near the Santa Ana River and Warm Creek, simulated heads generally rose above measured water levels except during 1965?72 when simulated heads compared well with measured water levels. Average

The size distribution of organic carbon in headwater streams in the Amazon basin.

PubMed

de Paula, Joana D'Arc; Luizão, Flávio Jesus; Piedade, Maria Teresa Fernandez

2016-06-01

Despite the strong representativeness of streams in the Amazon basin, their role in the accumulation of coarse particulate organic carbon (CPOC), fine particulate organic carbon (FPOC), and dissolved organic carbon (DOC) in transport, an important energy source in these environments, is poorly known. It is known that the arboreal vegetation in the Amazon basin is influenced by soil fertility and rainfall gradients, but would these gradients promote local differences in organic matter in headwater streams? To answer this question, 14 low-order streams were selected within these gradients along the Amazon basin, with extensions that varied between 4 and 8 km. The efficiency of the transformation of particulate into dissolved carbon fractions was assessed for each stream. The mean monthly benthic organic matter storage ranged between 1.58 and 9.40 t ha(-1) month(-1). In all locations, CPOC was the most abundant fraction in biomass, followed by FPOC and DOC. Rainfall and soil fertility influenced the distribution of the C fraction (p = 0.01), showing differentiated particulate organic carbon (POC) storage and DOC transportation along the basin. Furthermore, the results revealed that carbon quantification at the basin level could be underestimated, ultimately influencing the global carbon calculations for the region. This is especially due to the fact that the majority of studies consider only fine particulate organic matter and dissolved organic matter, which represent less than 50 % of the stored and transported carbon in streambeds.

The effect of different screw-tightening techniques on the strain generated on an internal-connection implant superstructure. Part 2: Models created with a splinted impression technique.

PubMed

Choi, Jung-Han

2011-01-01

This study aimed to evaluate the effect of different screw-tightening sequences, torques, and methods on the strains generated on an internal-connection implant (Astra Tech) superstructure with good fit. An edentulous mandibular master model and a metal framework directly connected to four parallel implants with a passive fit to each other were fabricated. Six stone casts were made from a dental stone master model by a splinted impression technique to represent a well-fitting situation with the metal framework. Strains generated by four screw-tightening sequences (1-2-3-4, 4-3-2-1, 2-4-3-1, and 2-3-1-4), two torques (10 and 20 Ncm), and two methods (one-step and two-step) were evaluated. In the two-step method, screws were tightened to the initial torque (10 Ncm) in a predetermined screw-tightening sequence and then to the final torque (20 Ncm) in the same sequence. Strains were recorded twice by three strain gauges attached to the framework (superior face midway between abutments). Deformation data were analyzed using multiple analysis of variance at a .05 level of statistical significance. In all stone casts, strains were produced by connection of the superstructure, regardless of screw-tightening sequence, torque, and method. No statistically significant differences in superstructure strains were found based on screw-tightening sequences (range, -409.8 to -413.8 μm/m), torques (-409.7 and -399.1 μm/m), or methods (-399.1 and -410.3 μm/m). Within the limitations of this in vitro study, screw-tightening sequence, torque, and method were not critical factors for the strain generated on a well-fitting internal-connection implant superstructure by the splinted impression technique. Further studies are needed to evaluate the effect of screw-tightening techniques on the preload stress in various different clinical situations.

Description of water-systems operations in the Arkansas River basin, Colorado

USGS Publications Warehouse

Abbott, P.O.

1985-01-01

To facilitate a current project modeling the hydrology of the Arkansas River basin in Colorado, a description of the regulation of water in the basin is necessary. The geographic and climatic setting of the Arkansas River basin that necessitates the use, reuse, importation, and storage of water are discussed. The history of water-resource development in the basin, leading to the present complex of water systems, also is discussed. Municipal, irrigation, industrial, and multipurpose water systems are described. System descriptions are illustrated with schematic line drawings, and supplemented with physical data tables for the lakes, tunnels, conduits, and canals in the various systems. Copies of criteria under which certain of the water systems operate, are included. (USGS)

Mathematical programming (MP) model to determine optimal transportation infrastructure for geologic CO2 storage in the Illinois basin

NASA Astrophysics Data System (ADS)

Rehmer, Donald E.

Analysis of results from a mathematical programming model were examined to 1) determine the least cost options for infrastructure development of geologic storage of CO2 in the Illinois Basin, and 2) perform an analysis of a number of CO2 emission tax and oil price scenarios in order to implement development of the least-cost pipeline networks for distribution of CO2. The model, using mixed integer programming, tested the hypothesis of whether viable EOR sequestration sites can serve as nodal points or hubs to expand the CO2 delivery infrastructure to more distal locations from the emissions sources. This is in contrast to previous model results based on a point-to- point model having direct pipeline segments from each CO2 capture site to each storage sink. There is literature on the spoke and hub problem that relates to airline scheduling as well as maritime shipping. A large-scale ship assignment problem that utilized integer linear programming was run on Excel Solver and described by Mourao et al., (2001). Other literature indicates that aircraft assignment in spoke and hub routes can also be achieved using integer linear programming (Daskin and Panayotopoulos, 1989; Hane et al., 1995). The distribution concept is basically the reverse of the "tree and branch" type (Rothfarb et al., 1970) gathering systems for oil and natural gas that industry has been developing for decades. Model results indicate that the inclusion of hubs as variables in the model yields lower transportation costs for geologic carbon dioxide storage over previous models of point-to-point infrastructure geometries. Tabular results and GIS maps of the selected scenarios illustrate that EOR sites can serve as nodal points or hubs for distribution of CO2 to distal oil field locations as well as deeper saline reservoirs. Revenue amounts and capture percentages both show an improvement over solutions when the hubs are not allowed to come into the solution. Other results indicate that geologic storage of CO2 into saline aquifers does not come into solutions selected by the model until the CO 2 emissions tax approaches 50/tonne. CO2 capture and storage begins to occur when the oil price is above 24.42 a barrel based on the constraints of the model. The annual storage capacity of the basin is nearly maximized when the net price of oil is as low as 40 per barrel and the CO2 emission tax is 60/tonne. The results from every subsequent scenario that was examined by this study demonstrate that EOR utilizing anthropogenically captured CO2 will earn net revenue, and thus represents an economically viable option for CO2 storage in the Illinois Basin.

Testing conceptual and physically based soil hydrology schemes against observations for the Amazon Basin

NASA Astrophysics Data System (ADS)

Guimberteau, M.; Ducharne, A.; Ciais, P.; Boisier, J. P.; Peng, S.; De Weirdt, M.; Verbeeck, H.

2014-06-01

This study analyzes the performance of the two soil hydrology schemes of the land surface model ORCHIDEE in estimating Amazonian hydrology and phenology for five major sub-basins (Xingu, Tapajós, Madeira, Solimões and Negro), during the 29-year period 1980-2008. A simple 2-layer scheme with a bucket topped by an evaporative layer is compared to an 11-layer diffusion scheme. The soil schemes are coupled with a river routing module and a process model of plant physiology, phenology and carbon dynamics. The simulated water budget and vegetation functioning components are compared with several data sets at sub-basin scale. The use of the 11-layer soil diffusion scheme does not significantly change the Amazonian water budget simulation when compared to the 2-layer soil scheme (+3.1 and -3.0% in evapotranspiration and river discharge, respectively). However, the higher water-holding capacity of the soil and the physically based representation of runoff and drainage in the 11-layer soil diffusion scheme result in more dynamic soil water storage variation and improved simulation of the total terrestrial water storage when compared to GRACE satellite estimates. The greater soil water storage within the 11-layer scheme also results in increased dry-season evapotranspiration (+0.5 mm d-1, +17%) and improves river discharge simulation in the southeastern sub-basins such as the Xingu. Evapotranspiration over this sub-basin is sustained during the whole dry season with the 11-layer soil diffusion scheme, whereas the 2-layer scheme limits it after only 2 dry months. Lower plant drought stress simulated by the 11-layer soil diffusion scheme leads to better simulation of the seasonal cycle of photosynthesis (GPP) when compared to a GPP data-driven model based on eddy covariance and satellite greenness measurements. A dry-season length between 4 and 7 months over the entire Amazon Basin is found to be critical in distinguishing differences in hydrological feedbacks between the soil and the vegetation cover simulated by the two soil schemes. On average, the multilayer soil diffusion scheme provides little improvement in simulated hydrology over the wet tropical Amazonian sub-basins, but a more significant improvement is found over the drier sub-basins. The use of a multilayer soil diffusion scheme might become critical for assessments of future hydrological changes, especially in southern regions of the Amazon Basin where longer dry seasons and more severe droughts are expected in the next century.

Assimilation of GRACE Terrestrial Water Storage Data into a Land Surface Model

NASA Technical Reports Server (NTRS)

Reichle, Rolf H.; Zaitchik, Benjamin F.; Rodell, Matt

2008-01-01

The NASA Gravity Recovery and Climate Experiment (GRACE) system of satellites provides observations of large-scale, monthly terrestrial water storage (TWS) changes. In. this presentation we describe a land data assimilation system that ingests GRACE observations and show that the assimilation improves estimates of water storage and fluxes, as evaluated against independent measurements. The ensemble-based land data assimilation system uses a Kalman smoother approach along with the NASA Catchment Land Surface Model (CLSM). We assimilated GRACE-derived TWS anomalies for each of the four major sub-basins of the Mississippi into the Catchment Land Surface Model (CLSM). Compared with the open-loop (no assimilation) CLSM simulation, assimilation estimates of groundwater variability exhibited enhanced skill with respect to measured groundwater. Assimilation also significantly increased the correlation between simulated TWS and gauged river flow for all four sub-basins and for the Mississippi River basin itself. In addition, model performance was evaluated for watersheds smaller than the scale of GRACE observations, in the majority of cases, GRACE assimilation led to increased correlation between TWS estimates and gauged river flow, indicating that data assimilation has considerable potential to downscale GRACE data for hydrological applications. We will also describe how the output from the GRACE land data assimilation system is now being prepared for use in the North American Drought Monitor.

Annual Variations in Water Storage and Precipitation in the Amazon Basin: Bounding Sink Terms in the Terrestrial Hydrological Balance using GRACE Satellite Gravity Data

NASA Technical Reports Server (NTRS)

Crowley, John W.; Mitrovica, Jerry X.; Bailey, Richard C.; Tamisiea, Mark E.; Davis, James L.

2007-01-01

We combine satellite gravity data from the Gravity Recovery and Climate Experiment (GRACE) and precipitation measurements from the National Oceanic and Atmospheric Administration (NOAA) Climate Prediction Center's (CPC) Merged Analysis of Precipitation (CMAP) and the Tropical Rainfall Measuring Mission (TRMM), over the period from mid-2002 to mid-2006, to investigate the relative importance of sink (runoff and evaporation) and source (precipitation) terms in the hydrological balance of the Amazon Basin. When linear and quadratic terms are removed, the time series of land water storage variations estimated from GRACE exhibits a dominant annual signal of 250 mm peak-to-peak, which is equivalent to a water volume change of approximately 1800 cubic kilometers. A comparison of this trend with accumulated (i.e., integrated) precipitation shows excellent agreement and no evidence of basin saturation. The agreement indicates that the net runoff and evaporation contributes significantly less than precipitation to the annual hydrological mass balance. Indeed, raw residuals between the detrended water storage and precipitation anomalies range from plus or minus 40 mm. This range is consistent with streamflow measurements from the region, although the latter are characterized by a stronger annual signal than ow residuals, suggesting that runoff and evaporation may act to partially cancel each other.

A method for examining the geospatial distribution of CO2 storage resources applied to the Pre-Punta Gorda Composite and Dollar Bay reservoirs of the South Florida Basin, U.S.A

USGS Publications Warehouse

Roberts-Ashby, Tina; Brandon N. Ashby,

2016-01-01

This paper demonstrates geospatial modification of the USGS methodology for assessing geologic CO2 storage resources, and was applied to the Pre-Punta Gorda Composite and Dollar Bay reservoirs of the South Florida Basin. The study provides detailed evaluation of porous intervals within these reservoirs and utilizes GIS to evaluate the potential spatial distribution of reservoir parameters and volume of CO2 that can be stored. This study also shows that incorporating spatial variation of parameters using detailed and robust datasets may improve estimates of storage resources when compared to applying uniform values across the study area derived from small datasets, like many assessment methodologies. Geospatially derived estimates of storage resources presented here (Pre-Punta Gorda Composite = 105,570 MtCO2; Dollar Bay = 24,760 MtCO2) were greater than previous assessments, which was largely attributed to the fact that detailed evaluation of these reservoirs resulted in higher estimates of porosity and net-porous thickness, and areas of high porosity and thick net-porous intervals were incorporated into the model, likely increasing the calculated volume of storage space available for CO2 sequestration. The geospatial method for evaluating CO2 storage resources also provides the ability to identify areas that potentially contain higher volumes of storage resources, as well as areas that might be less favorable.

Workshop on sediment budgets and routing in forested drainage basins: proceedings.

Treesearch

Frederick J. Swanson; Richard J. Janda; Thomas Dunne; Douglas N. Swanston

1982-01-01

Sediment budgets quantify the transport and storage of soil and sediment in drainage basins or smaller landscape units. Studies of sediment routing deal with the overall movement of soil and sediment through a series of landscape units. The 14 papers and 5 summaries from discussion groups in this volume report results of sediment budget and routing studies conducted...

Optimization of wetland restoration siting and zoning in flood retention areas of river basins in China: A case study in Mengwa, Huaihe River Basin

NASA Astrophysics Data System (ADS)

Zhang, Xiaolei; Song, Yuqin

2014-11-01

Wetland restoration in floodplains is an ecological solution that can address basin-wide flooding issues and minimize flooding and damages to riverine and downstream areas. High population densities, large economic outputs, and heavy reliance on water resources make flood retention and management pressing issues in China. To balance flood control and sustainable development economically, socially, and politically, flood retention areas have been established to increase watershed flood storage capacities and enhance the public welfare for the populace living in the areas. However, conflicts between flood storage functions and human habitation appear irreconcilable. We developed a site-specific methodology for identifying potential sites and functional zones for wetland restoration in a flood retention area in middle and eastern China, optimizing the spatial distribution and functional zones to maximize flood control and human and regional development. This methodology was applied to Mengwa, one of 21 flood retention areas in China's Huaihe River Basin, using nine scenarios that reflected different flood, climatic, and hydraulic conditions. The results demonstrated improved flood retention and ecological functions, as well as increased economic benefits.

Characterization of the Triassic Newark Basin of New York and New Jersey for geologic storage of carbon dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Collins, Daniel J.

The Newark Basin is a Triassic-aged rift basin underlying densely populated, industrialized sections of New York, New Jersey and Pennsylvania. The Basin is an elongate half-graben encompassing an area of more than 7,510 square-kilometers (2,900 square-miles), and could represent a key storage component for commercial scale management of carbon dioxide emissions via geologic sequestration. The project team first acquired published reports, surface and subsurface maps, and seismic data, which formed the basis for a three-dimensional model framework for the northern end of the Basin incorporating stratigraphic, hydrologic, and water quality data. Field investigations included drilling, coring, and logging of two stratigraphic test borings in Clarkstown, NY (Exit 14 Tandem Lot Well No. 1), drilled to a depth of 2,099 meters (6,885 feet); and Palisades, NY (Lamont-Doherty Earth Observatory Test Well No. 4) drilled to a depth of 549 meters (1,802 feet). Two two-dimensional seismic reflection data lines arrayed perpendicularly were acquired by Schlumberger/WesternGeco to help characterize the structure and stratigraphy and as part of pre-drilling field screening activities for the deep stratigraphic borehole. A total of 47 meters (155 feet) of continuous whole core was recovered from the Tandem Lot boring from depths of 1,393 meters (4,570 feet) to 1,486 meters (4,877 feet). Twenty-five horizontal rotary cores were collected in mudstones and sandstones in the surface casing hole and fifty-two cores were taken in various lithologies in the deep borehole. Rotary core plugs were analyzed by Weatherford Laboratories for routine and advanced testing. Rotary core plug trim end thin sections were evaluated by the New York State Museum for mineralogical analysis and porosity estimation. Using core samples, Lawrence Berkley National Laboratory designed and completed laboratory experiments and numerical modeling analyses to characterize the dissolution and reaction of carbon dioxide with formation brine and minerals, and resulting effects on injection rate, pressure, effective storage volume, and carbon dioxide migration within a prospective sandstone reservoir.more » $$Three potential porous and permeable sandstone units were identified in the Passaic Formation at the New York State Thruway Exit 14 location. Potential Flow Unit 1, at a depth of 643 meters (2,110 feet) to 751 meters (2,465 feet); Potential Flow Unit 2 at a depth of 853 meters (2,798 feet) to 1,000 meters (3,280 feet); and Potential Flow Unit 3, at a depth of 1,114 meters (3,655 feet) to 1,294 meters (4,250 feet). Reactive transport simulations of interactions between carbon dioxide, brine and formation minerals were carried out to evaluate changes in formation water chemistry, mineral precipitation and dissolution reactions, and any potential resulting effects on formation permeability. The experimental and modeling analyses suggest that mineral precipitation and dissolution reactions (within the target formation) are not expected to lead to significant changes to the underground hydrologic system over time frames (~30 years) typically relevant for carbon dioxide injection operations. Key findings of this basin characterization study include an estimate of carbon dioxide storage capacity in the Newark Basin. Assuming an average porosity of twelve percent and an aquifer volume of 6.1E+12 meters3, calculated ranges of likely storage capacity range from 1.9 – 20.2 gigatonnes under high temperature (low carbon dioxide density) conditions; and 2.9 – 30.2 gigatonnes under low temperature (low carbon dioxide density) conditions. Intra-basin faulting, geometry of the Palisades Sill, and the presence of altered meta-sediments above and below the Sill, increase potential compartmentalization within the basin. A structural/stratigraphic trap type may occur where porous/permeable sediments are cross-cut by the Palisades Sill. Potential injection intervals are present within the Stockton Formation of the Newark Basin. Additional porous/permeable intervals may be present within sandstones of the Passaic Formation, increasing projected storage capacity. Deeper wedges of strata are likely present in the deeper portions of the basin in southern New York and into northern New Jersey. Abundant mudstones are present in the Passaic, Lockatong, and Stockton Formations. These intervals have the requisite petrophysical properties to form effective primary and secondary containment intervals to industrial-scale sequestration of carbon dioxide in the Newark Basin. Hydro-thermally altered meta-sediments in the region immediately surrounding the top and base of the Palisades Sill is devoid of porosity/permeability and forms an additional effective lateral/vertical sealing cap rock.« less

7. VIEW NORTHWEST OF 'ISLAND' (TOWER OR SUPERSTRUCTURE) ON THE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. VIEW NORTHWEST OF 'ISLAND' (TOWER OR SUPERSTRUCTURE) ON THE DECK OF THE AIRCRAFT CARRIER JOHN F. KENNEDY. WHEN THE PHOTOGRAPH WAS TAKEN IN SEPTEMBER 1994, THE KENNEDY WAS IN DRY-DOCK FOR REFURBISHMENT UNDER THE 'SERVICE LIFE EXTENSION PROGRAM (SLEP). THE 'ISLAND' HOUSES THE SHIP'S BRIDGE AND A CONTROL CENTER FOR AIRCRAFT OPERATIONS. EXTENSIVE SCAFFOLDING WAS REQUIRED TO ALLOW FULL ACCESS TO THE PAINTERS AND TECHNICIANS WORKING HERE. - Naval Base Philadelphia-Philadelphia Naval Shipyard, Dry Dock No. 5, League Island, Philadelphia, Philadelphia County, PA

Finite Element and Analytical Analysis of Cracks in Thick Stiffened Plates Repaired with a Single Sided Composite Patch

DTIC Science & Technology

2014-06-01

DC,Tech. Rep. CG-D-05–00, 2000. [16] S. Kou, Welding Metallurgy , 2nd edition, Hoboken: Wiley Interscience, 2003. [17] C. Poe, “Stress intensity...continuous aluminum superstructure welded to the deck. The shape of the superstructure created numerous stress concentration areas. Of the greatest concern...study as it will help provide a conservative estimate. In marine applications almost all stiffening members are attached by welding . Unlike a

Measurements of aquifer-storage change and specific yield using gravity surveys

USGS Publications Warehouse

Pool, D.R.; Eychaner, J.H.

1995-01-01

Pinal Creek is an intermittent stream that drains a 200-square-mile alluvial basin in central Arizona. Large changes in water levels and aquifer storage occur in an alluvial aquifer near the stream in response to periodic recharge and ground-water withdrawals. Outflow components of the ground-water budget and hydraulic properties of the alluvium are well-defined by field measurements; however, data are insufficient to adequately describe recharge, aquifer-storage change, and specific-yield values. An investigation was begun to assess the utility of temporal-gravity surveys to directly measure aquifer-storage change and estimate values of specific yield.The temporal-gravity surveys measured changes in the differences in gravity between two reference stations on bedrock and six stations at wells; changes are caused by variations in aquifer storage. Specific yield was estimated by dividing storage change by water-level change. Four surveys were done between February 21, 1991, and March 31, 1993. Gravity increased as much as 158 microGal ± 1 to 6 microGal, and water levels rose as much as 58 feet. Average specific yield at wells ranged from 0.16 to 0.21, and variations in specific yield with depth correlate with lithologic variations. Results indicate that temporal-gravity surveys can be used to estimate aquifer-storage change and specific yield of water-table aquifers where significant variations in water levels occur. Direct measurement of aquifer-storage change can eliminate a major unknown from the ground-water budget of arid basins and improve residual estimates of recharge.

How are the wetlands over tropical basins impacted by the extreme hydrological events?

NASA Astrophysics Data System (ADS)

Al-Bitar, A.; Parrens, M.; Frappart, F.; Papa, F.; Kerr, Y. H.; Cretaux, J. F.; Wigneron, J. P.

2016-12-01

Wetlands play a crucial role in tropical basins and still many questions remain unanswered on how extreme events (like El-Nino) impacts them. Answering these questions is challenging as monitoring of inland water surfaces via remote sensing over tropical areas is a difficult task because of impact of vegetation and cloud cover. Several microwave based products have been elaborated to monitor these surfaces (Papa et al. 2010). In this study we combine the use of L-band microwave brightness temperatures and altimetric data from SARAL/ALTIKA to derive water storage maps at relatively high (7days) temporal frequency. The area of interest concerns the Amazon, Congo and GBH basins A first order radiative model is used to derive surface water over land from the brightness temperature measured by ESA SMOS mission at coarse resolution (25 km x 25 km) and 7-days frequency. An initial investigation of the use of the SMAP mission for the same purpose will be also presented. The product is compared to the static land cover map such as ESA CCI and the International Geosphere-Biosphere Program (IGBP) and also dynamic maps from SWAPS. It is then combined to the altimetric data to derive water storage maps. The water surfaces and water storage products are then compared to precipitation data from GPM TRMM datasets, ground water storage change from GRACE and river discharge data from field data. The amplitudes and time shifts of the signals is compared based on the sub-basin definition from Hydroshed database. The dataset is then divided into years of strong and weak El-Nino signal and the anomaly is between the two dataset is compared. The results show a strong influence of EL-Nino on the time shift of the different components showing that the hydrological regime of wetlands is highly impacted by these extreme events. This can have dramatic impacts on the ecosystem as the wetlands are vulnerable with a high biodiversity.

Comparing Budget-based and Tracer-based Residence Times in Butte Basin, California

NASA Astrophysics Data System (ADS)

Moran, J. E.; Visser, A.; Esser, B.; Buck, C.

2017-12-01

The California Sustainable Groundwater Management Act of 2014 (SGMA) calls for basin-scale Groundwater Sustainability Plans (GSPs) that include a water budget covering a 50 year planning horizon. A nine layer, Integrated Water Flow Model (IWFM) developed for Butte Basin, California, allows examination of water budgets within 36 sub-regions having varying land and water use, to inform SGMA efforts. Detailed land use, soil type, groundwater pumping, and surface water delivery data were applied in the finite element IWFM calibration. In a sustainable system, the volume of storage does not change over a defined time period, and the residence time can be calculated from the water storage volume divided by the flux (recharge or discharge rate). Groundwater ages based on environmental tracer data reflect the mean residence time of groundwater, or its inverse, the turnover rate. Comparisons between budget-based residence times determined from storage and flux, and residence times determined from isotopic tracers of groundwater age, can provide insight into data quality, model reliability, and system sustainability. Budget-based groundwater residence times were calculated from IWFM model output by assuming constant storage and dividing by either averaged annual net recharge or discharge. Calculated residence times range between approximately 100 and 1000 years, with shorter times in subregions where pumping dominates discharge. Independently, 174 wells within the model boundaries were analyzed for tritium-helium groundwater age as part of the California Groundwater Ambient Monitoring and Assessment program. Age distributions from isotopic tracers were compared to model-derived groundwater residence times from groundwater budgets within the subregions of Butte Basin. Mean, apparent, tracer-based residence times are mostly between 20 and 40 years, but 25% of the long-screened wells that were sampled do not have detectable tritium, indicating residence times of more than about 60 years and broad age distributions. A key factor in making meaningful comparisons is to examine budget-based and tracer-based results over transmissive vertical sections, where pumping increases turnover time.

Evaluating the efficacy of distributed detention structures to reduce downstream flooding under variable rainfall, antecedent soil, and structural storage conditions

NASA Astrophysics Data System (ADS)

Thomas, Nicholas W.; Arenas Amado, Antonio; Schilling, Keith E.; Weber, Larry J.

2016-10-01

This research systematically analyzed the influence of antecedent soil wetness, rainfall depth, and the subsequent impact on peak flows in a 45 km2 watershed. Peak flows increased with increasing antecedent wetness and rainfall depth, with the highest peak flows occurring under intense precipitation on wet soils. Flood mitigation structures were included and investigated under full and empty initial storage conditions. Peak flows were reduced at the outlet of the watershed by 3-17%. The highest peak flow reductions occurred in scenarios with dry soil, empty project storage, and low rainfall depths. These analyses showed that with increased rainfall depth, antecedent moisture conditions became increasingly less impactful. Scaling invariance of peak discharges were shown to hold true within this basin and were fit through ordinary least squares regression for each design scenario. Scale-invariance relationships were extrapolated beyond the outlet of the analyzed basin to the point of intersection of with and without structure scenarios. In each scenario extrapolated peak discharge benefits depreciated at a drainage area of approximately 100 km2. The associated drainage area translated to roughly 2 km downstream of the Beaver Creek watershed outlet. This work provides an example of internal watershed benefits of structural flood mitigation efforts, and the impact the may exert outside of the basin. Additionally, the influence of 1.8 million in flood reduction tools was not sufficient to routinely address downstream flood concerns, shedding light on the additional investment required to alter peak flows in large basins.

75 FR 44982 - Arkansas Valley Conduit (AVC) and Long-Term Excess Capacity Master Contract, Fryingpan-Arkansas...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-30

... Reservoir due to AVC and Excess Capacity Master Contract operations and potential contributions to flooding... Southeastern for storage of non-Fry-Ark Project water in Pueblo Reservoir, a feature of the Fry-Ark Project... storage in Pueblo Reservoir for entities within its boundaries in the Upper Arkansas basin, Lower Arkansas...

Simulation of streamflow temperatures in the Yakima River basin, Washington, April-October 1981

USGS Publications Warehouse

Vaccaro, J.J.

1986-01-01

The effects of storage, diversion, return flow, and meteorological variables on water temperature in the Yakima River, in Washington State, were simulated, and the changes in water temperature that could be expected under four alternative-management scenarios were examined for improvement in anadromous fish environment. A streamflow routing model and Lagrangian streamflow temperature model were used to simulate water discharge and temperature in the river. The estimated model errors were 12% for daily discharge and 1.7 C for daily temperature. Sensitivity analysis of the simulation of water temperatures showed that the effect of reservoir outflow temperatures diminishes in a downstream direction. A 4 C increase in outflow temperatures results in a 1.0 C increase in mean irrigation season water temperature at Umtanum in the upper Yakima River basin, but only a 0.01C increase at Prosser in the lower basin. The influence of air temperature on water temperature increases in a downstream direction and is the dominant influence in the lower basin. A 4 C increase in air temperature over the entire basin resulted in a 2.34 C increase in river temperatures at Prosser in the lower basin and 1.46 C at Umtanum in the upper basin. Changes in wind speed and model wind-function parameters had little effect on the model predicted water temperature. Of four alternative management scenarios suggested by the U.S. Bureau of Indian Affairs and the Yakima Indian Nation, the 1981 reservoir releases maintained without diversions or return flow in the river basin produced water temperatures nearest those considered as preferable for salmon and steelhead trout habitat. The alternative management scenario for no reservoir storage and no diversions or return flows in the river basin (estimate of natural conditions) produced conditions that were the least like those considered as preferable for salmon and steelhead trout habitat. (Author 's abstract)

Evaluating the hydrological consistency of evaporation products using satellite-based gravity and rainfall data

NASA Astrophysics Data System (ADS)

López, Oliver; Houborg, Rasmus; McCabe, Matthew Francis

2017-01-01

Advances in space-based observations have provided the capacity to develop regional- to global-scale estimates of evaporation, offering insights into this key component of the hydrological cycle. However, the evaluation of large-scale evaporation retrievals is not a straightforward task. While a number of studies have intercompared a range of these evaporation products by examining the variance amongst them, or by comparison of pixel-scale retrievals against ground-based observations, there is a need to explore more appropriate techniques to comprehensively evaluate remote-sensing-based estimates. One possible approach is to establish the level of product agreement between related hydrological components: for instance, how well do evaporation patterns and response match with precipitation or water storage changes? To assess the suitability of this consistency-based approach for evaluating evaporation products, we focused our investigation on four globally distributed basins in arid and semi-arid environments, comprising the Colorado River basin, Niger River basin, Aral Sea basin, and Lake Eyre basin. In an effort to assess retrieval quality, three satellite-based global evaporation products based on different methodologies and input data, including CSIRO-PML, the MODIS Global Evapotranspiration product (MOD16), and Global Land Evaporation: the Amsterdam Methodology (GLEAM), were evaluated against rainfall data from the Global Precipitation Climatology Project (GPCP) along with Gravity Recovery and Climate Experiment (GRACE) water storage anomalies. To ensure a fair comparison, we evaluated consistency using a degree correlation approach after transforming both evaporation and precipitation data into spherical harmonics. Overall we found no persistent hydrological consistency in these dryland environments. Indeed, the degree correlation showed oscillating values between periods of low and high water storage changes, with a phase difference of about 2-3 months. Interestingly, after imposing a simple lag in GRACE data to account for delayed surface runoff or baseflow components, an improved match in terms of degree correlation was observed in the Niger River basin. Significant improvements to the degree correlations (from ˜ 0 to about 0.6) were also found in the Colorado River basin for both the CSIRO-PML and GLEAM products, while MOD16 showed only half of that improvement. In other basins, the variability in the temporal pattern of degree correlations remained considerable and hindered any clear differentiation between the evaporation products. Even so, it was found that a constant lag of 2 months provided a better fit compared to other alternatives, including a zero lag. From a product assessment perspective, no significant or persistent advantage could be discerned across any of the three evaporation products in terms of a sustained hydrological consistency with precipitation and water storage anomaly data. As a result, our analysis has implications in terms of the confidence that can be placed in independent retrievals of the hydrological cycle, raises questions on inter-product quality, and highlights the need for additional techniques to evaluate large-scale products.

Macroscale water fluxes 3. Effects of land processes on variability of monthly river discharge

USGS Publications Warehouse

Milly, P.C.D.; Wetherald, R.T.

2002-01-01

A salient characteristic of river discharge is its temporal variability. The time series of flow at a point on a river can be viewed as the superposition of a smooth seasonal cycle and an irregular, random variation. Viewing the random component in the spectral domain facilitates both its characterization and an interpretation of its major physical controls from a global perspective. The power spectral density functions of monthly flow anomalies of many large rivers worldwide are typified by a "red noise" process: the density is higher at low frequencies (e.g., <1 y-1) than at high frequencies, indicating disproportionate (relative to uncorrelated "white noise") contribution of low frequencies to variability of monthly flow. For many high-latitude and arid-region rivers, however, the power is relatively evenly distributed across the frequency spectrum. The power spectrum of monthly flow can be interpreted as the product of the power spectrum of monthly basin total precipitation (which is typically white or slightly red) and several filters that have physical significance. The filters are associated with (1) the conversion of total precipitation (sum of rainfall and snowfall) to effective rainfall (liquid flux to the ground surface from above), (2) the conversion of effective rainfall to soil water excess (runoff), and (3) the conversion of soil water excess to river discharge. Inferences about the roles of each filter can be made through an analysis of observations, complemented by information from a global model of the ocean-atmosphere-land system. The first filter causes a snowmelt-related amplification of high-frequency variability in those basins that receive substantial snowfall. The second filter causes a relatively constant reduction in variability across all frequencies and can be predicted well by means of a semiempirical water balance relation. The third filter, associated with groundwater and surface water storage in the river basin, causes a strong reduction in high-frequency variability of many basins. The strength of this reduction can be quantified by an average residence time of water in storage, which is typically on the order of 20-50 days. The residence time is demonstrably influenced by freezing conditions in the basin, fractional cover of the basin by lakes, and runoff ratio (ratio of mean runoff to mean precipitation). Large lake areas enhance storage and can greatly increase total residence times (100 to several hundred days). Freezing conditions appear to cause bypassing of subsurface storage, thus reducing residence times (0-30 days). Small runoff ratios tend to be associated with arid regions, where the water table is deep, and consequently, most of the runoff is produced by processes that bypass the saturated zone, leading to relatively small residence times for such basins (0-40 days).

Turbulent thermal superstructures in Rayleigh-Bénard convection

NASA Astrophysics Data System (ADS)

Stevens, Richard J. A. M.; Blass, Alexander; Zhu, Xiaojue; Verzicco, Roberto; Lohse, Detlef

2018-04-01

We report the observation of superstructures, i.e., very large-scale and long living coherent structures in highly turbulent Rayleigh-Bénard convection up to Rayleigh Ra=109 . We perform direct numerical simulations in horizontally periodic domains with aspect ratios up to Γ =128 . In the considered Ra number regime the thermal superstructures have a horizontal extend of six to seven times the height of the domain and their size is independent of Ra. Many laboratory experiments and numerical simulations have focused on small aspect ratio cells in order to achieve the highest possible Ra. However, here we show that for very high Ra integral quantities such as the Nusselt number and volume averaged Reynolds number only converge to the large aspect ratio limit around Γ ≈4 , while horizontally averaged statistics such as standard deviation and kurtosis converge around Γ ≈8 , the integral scale converges around Γ ≈32 , and the peak position of the temperature variance and turbulent kinetic energy spectra only converge around Γ ≈64 .

Dynamic cholesteric liquid crystal superstructures photoaligned by one-step polarization holography

NASA Astrophysics Data System (ADS)

Li, Sen-Sen; Shen, Yuan; Chang, Zhen-Ni; Li, Wen-Song; Xu, Yan-Chao; Fan, Xing-Yu; Chen, Lu-Jian

2017-12-01

A convenient approach to modulate the fingerprint textures of methyl red (MR) doped cholesteric liquid crystals by asymmetric photoalignment in the green-light waveband is presented, resulting in the generation of voltage-controllable helical superstructures. The interaction between the MR molecules and the incident light polarization determines the initial twisted planar geometry, providing a multivariant control over the stripe directions of fingerprint textures by applying a proper electric field. The key factors for precise manipulation of fingerprint stripes in a predictable and rewritable manner are analyzed theoretically and investigated experimentally, which involves the alignment asymmetry, the ratio of cell gap to natural pitch length, and the chirality of chiral dopant. Dynamic periodic fingerprint textures in shapes of dashed curve and dashed line are further demonstrated by utilizing a facile one-step polarization holography process using two beams with orthogonal circular and orthogonal linear polarizations, respectively. It is believed that the practical approach described in this study would enrich the research contents of self-assembled hierarchical superstructures using soft liquid crystal building blocks.

Photochemically and Thermally Driven Full-Color Reflection in a Self-Organized Helical Superstructure Enabled by a Halogen-Bonded Chiral Molecular Switch.

PubMed

Wang, Hao; Bisoyi, Hari Krishna; Wang, Ling; Urbas, Augustine M; Bunning, Timothy J; Li, Quan

2018-02-05

Supramolecular approaches toward the fabrication of functional materials and systems have been an enabling endeavor. Recently, halogen bonding has been harnessed as a promising supramolecular tool. Herein we report the synthesis and characterization of a novel halogen-bonded light-driven axially chiral molecular switch. The photoactive halogen-bonded chiral switch is able to induce a self-organized, tunable helical superstructure, that is, cholesteric liquid crystal (CLC), when doped into an achiral liquid crystal (LC) host. The halogen-bonded switch as a chiral dopant has a high helical twisting power (HTP) and shows a large change of its HTP upon photoisomerization. This light-driven dynamic modulation enables reversible selective reflection color tuning across the entire visible spectrum. The chiral switch also displays a temperature-dependent HTP change that enables thermally driven red, green, and blue (RGB) reflection colors in the self-organized helical superstructure. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Novel symmetrical coralloid Cu 3D superstructures: Solid-state synthesis from a Cu-carboxylate MOF and their in-situ thermal conversion

NASA Astrophysics Data System (ADS)

Chen, Lingyun; Shen, Yongming; Bai, Junfeng; Wang, Chunzhao

2009-08-01

We describe here a one-step solid-state process for the synthesis of metal three-dimensional (3D) superstructures from a metal-organic framework (MOF). Novel symmetrical coralloid Cu 3D superstructures with surface interspersed with clusters of Cu nanoparticles were successfully synthesized by thermolysis of the [Cu 3( btc) 2] ( btc=benzene-1,3,5-tricarboxylato) MOF in a one-end closed horizontal tube furnace (OCTF). The obtained products were characterized by TGA, FT-IR, XRD, EDX, SEM, TEM, HRTEM and SAED. Different reaction conditions were discussed. Furthermore, the synthesized Cu samples were converted into CuO microstructures by in-situ calcination in the air. In addition, the possible formation mechanism was also proposed. This method is a simple and facile route, which builds a direct linkage between metal-carboxylate MOF crystals and metal nano- or microstructures and also opens a new application field of MOFs.

An assessment of flood mitigation measures - "room for the river

NASA Astrophysics Data System (ADS)

Komma, J.; Blöschl, G.; Habereder, C.

2009-04-01

In this paper we analyse the relative effect of different flood mitigation measures for the example of the Kamp catchment in Austria. The main idea is to decrease flood peaks through (a) retaining water in the landscape and (b) providing additional inundation areas along the main stream (room for the river). To increase the retention of excess rainfall in the landscape we introduced two different measures. One measure is the increase of water storage capacity in the study catchment through the change of land use from agriculture to forest. The second measure is the installation of many small sized retention basins without an outlet (micro ponds). The micro ponds are situated at the hill slopes to intercept surface runoff. In case of the room for the river scenario the additional retention volume is gained due to the installation of retention basins along the Kamp river and its tributary Zwettl. Three flood retention basins with culverts at each river are envisaged. The geometry of the bottom outlets is defined for design discharges in a way to gain the greatest flood peak reduction for large flood events (above a 100 yr flood). The study catchment at the Kamp river with a size of 622 km² is located in north-eastern Austria. For the simulation of the different scenarios (retaining water in the landscape) a well calibrated continuous hydrologic model is available. The hydrological model consists of a spatially distributed soil moisture accounting scheme and a flood routing component. To analyse the effect of the room for the river scenario with retention basins along the river reaches a linked 1D/2D hydrodynamic model (TUFLOW) is used. In the river channels a one dimensional simulation is carried out. The flow conditions in the flood plains are represented by two dimensional model elements. The model domain incorporates 18 km of the Kamp and 12 km of the Zwettl river valley. For the assessment of the land use change scenario the hydrologic model parameters for wooded areas are transferred to areas that are currently not forested. Through higher storage capacities in the wooded areas the scenario of afforestation helps to reduce flood peaks. The micro ponds are represented in the hydrological model by a bucket storage component. It is filled by a fraction of the simulated direct runoff and drains into the groundwater with a constant percolation rate. For the scenarios of flood mitigation with retention basins along the river reaches three locations at the Kamp and three locations at the Zwettl river have been chosen for hypothetical retention basins or polders with bottom outlets. The main difference between the "room for the river" method and the "retaining water in the landscape" methods is the magnitude of the flood event for which the retention is maximised. For the case of retaining water in the landscape (either by land use change or microponds) the storage capacity obtained by these measures is filled at the beginning of the event. For small event magnitudes, the flood peak reduction is hence maximised. In the Kamp catchment, significant reductions in the flood peaks can be obtained when retention basins along the main stream are constructed and the flood plains are inundated. The main advantage of the room for the river methodology is that the polders/retention basins can be designed in a way that there is no retention for small flood discharges which leaves the full storage capacity for larger floods at the time of peak. In contrast, for the retaining water in the landscape measures, the storage is exhausted at an early stage of medium and large events, resulting in very small flood peak reductions.

Reservoir Performance Under Future Climate For Basins With Different Hydrologic Sensitivities

NASA Astrophysics Data System (ADS)

Mateus, M. C.; Tullos, D. D.

2013-12-01

In addition to long-standing uncertainties related to variable inflows and market price of power, reservoir operators face a number of new uncertainties related to hydrologic nonstationarity, changing environmental regulations, and rapidly growing water and energy demands. This study investigates the impact, sensitivity, and uncertainty of changing hydrology on hydrosystem performance across different hydrogeologic settings. We evaluate the performance of reservoirs in the Santiam River basin, including a case study in the North Santiam Basin, with high permeability and extensive groundwater storage, and the South Santiam Basin, with low permeability, little groundwater storage and rapid runoff response. The modeling objective is to address the following study questions: (1) for the two hydrologic regimes, how does the flood management, water supply, and environmental performance of current reservoir operations change under future 2.5, 50 and 97.5 percentile streamflow projections; and (2) how much change in inflow is required to initiate a failure to meet downstream minimum or maximum flows in the future. We couple global climate model results with a rainfall-runoff model and a formal Bayesian uncertainty analysis to simulate future inflow hydrographs as inputs to a reservoir operations model. To evaluate reservoir performance under a changing climate, we calculate reservoir refill reliability, changes in flood frequency, and reservoir time and volumetric reliability of meeting minimum spring and summer flow target. Reservoir performance under future hydrology appears to vary with hydrogeology. We find higher sensitivity to floods for the North Santiam Basin and higher sensitivity to minimum flow targets for the South Santiam Basin. Higher uncertainty is related with basins with a more complex hydrologeology. Results from model simulations contribute to understanding of the reliability and vulnerability of reservoirs to a changing climate.

Characterization of basin concrete in support of structural integrity demonstration for extended storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duncan, A.

Concrete core samples from C basin were characterized through material testing and analysis to verify the design inputs for structural analysis of the L Basin and to evaluate the type and extent of changes in the material condition of the concrete under extended service for fuel storage. To avoid the impact on operations, core samples were not collected from L area, but rather, several concrete core samples were taken from the C Basin prior to its closure. C basin was selected due to its similar environmental exposure and service history compared to L Basin. The microstructure and chemical composition ofmore » the concrete exposed to the water was profiled from the water surface into the wall to evaluate the impact and extent of exposure. No significant leaching of concrete components was observed. Ingress of carbonation or deleterious species was determined to be insignificant. No evidence of alkali-silica reactions (ASR) was observed. Ettringite was observed to form throughout the structure (in air voids or pores); however, the sulfur content was measured to be consistent with the initial concrete that was used to construct the facility. Similar ettringite trends were observed in the interior segments of the core samples. The compressive strength of the concrete at the mid-wall of the basin was measured, and similar microstructural analysis was conducted on these materials post compression testing. The microstructure was determined to be similar to near-surface segments of the core samples. The average strength was 4148 psi, which is well-above the design strength of 2500 psi. The analyses showed that phase alterations and minor cracking in a microstructure did not affect the design specification for the concrete.« less

Integrated groundwater resource management in Indus Basin using satellite gravimetry and physical modeling tools.

PubMed

Iqbal, Naveed; Hossain, Faisal; Lee, Hyongki; Akhter, Gulraiz

2017-03-01

Reliable and frequent information on groundwater behavior and dynamics is very important for effective groundwater resource management at appropriate spatial scales. This information is rarely available in developing countries and thus poses a challenge for groundwater managers. The in situ data and groundwater modeling tools are limited in their ability to cover large domains. Remote sensing technology can now be used to continuously collect information on hydrological cycle in a cost-effective way. This study evaluates the effectiveness of a remote sensing integrated physical modeling approach for groundwater management in Indus Basin. The Gravity Recovery and Climate Experiment Satellite (GRACE)-based gravity anomalies from 2003 to 2010 were processed to generate monthly groundwater storage changes using the Variable Infiltration Capacity (VIC) hydrologic model. The groundwater storage is the key parameter of interest for groundwater resource management. The spatial and temporal patterns in groundwater storage (GWS) are useful for devising the appropriate groundwater management strategies. GRACE-estimated GWS information with large-scale coverage is valuable for basin-scale monitoring and decision making. This frequently available information is found useful for the identification of groundwater recharge areas, groundwater storage depletion, and pinpointing of the areas where groundwater sustainability is at risk. The GWS anomalies were found to favorably agree with groundwater model simulations from Visual MODFLOW and in situ data. Mostly, a moderate to severe GWS depletion is observed causing a vulnerable situation to the sustainability of this groundwater resource. For the sustainable groundwater management, the region needs to implement groundwater policies and adopt water conservation techniques.

Hydrometeorological model for streamflow prediction

USGS Publications Warehouse

Tangborn, Wendell V.

1979-01-01

The hydrometeorological model described in this manual was developed to predict seasonal streamflow from water in storage in a basin using streamflow and precipitation data. The model, as described, applies specifically to the Skokomish, Nisqually, and Cowlitz Rivers, in Washington State, and more generally to streams in other regions that derive seasonal runoff from melting snow. Thus the techniques demonstrated for these three drainage basins can be used as a guide for applying this method to other streams. Input to the computer program consists of daily averages of gaged runoff of these streams, and daily values of precipitation collected at Longmire, Kid Valley, and Cushman Dam. Predictions are based on estimates of the absolute storage of water, predominately as snow: storage is approximately equal to basin precipitation less observed runoff. A pre-forecast test season is used to revise the storage estimate and improve the prediction accuracy. To obtain maximum prediction accuracy for operational applications with this model , a systematic evaluation of several hydrologic and meteorologic variables is first necessary. Six input options to the computer program that control prediction accuracy are developed and demonstrated. Predictions of streamflow can be made at any time and for any length of season, although accuracy is usually poor for early-season predictions (before December 1) or for short seasons (less than 15 days). The coefficient of prediction (CP), the chief measure of accuracy used in this manual, approaches zero during the late autumn and early winter seasons and reaches a maximum of about 0.85 during the spring snowmelt season. (Kosco-USGS)

Superstructure-based Design and Optimization of Batch Biodiesel Production Using Heterogeneous Catalysts

NASA Astrophysics Data System (ADS)

Nuh, M. Z.; Nasir, N. F.

2017-08-01

Biodiesel as a fuel comprised of mono alkyl esters of long chain fatty acids derived from renewable lipid feedstock, such as vegetable oil and animal fat. Biodiesel production is complex process which need systematic design and optimization. However, no case study using the process system engineering (PSE) elements which are superstructure optimization of batch process, it involves complex problems and uses mixed-integer nonlinear programming (MINLP). The PSE offers a solution to complex engineering system by enabling the use of viable tools and techniques to better manage and comprehend the complexity of the system. This study is aimed to apply the PSE tools for the simulation of biodiesel process and optimization and to develop mathematical models for component of the plant for case A, B, C by using published kinetic data. Secondly, to determine economic analysis for biodiesel production, focusing on heterogeneous catalyst. Finally, the objective of this study is to develop the superstructure for biodiesel production by using heterogeneous catalyst. The mathematical models are developed by the superstructure and solving the resulting mixed integer non-linear model and estimation economic analysis by using MATLAB software. The results of the optimization process with the objective function of minimizing the annual production cost by batch process from case C is 23.2587 million USD. Overall, the implementation a study of process system engineering (PSE) has optimized the process of modelling, design and cost estimation. By optimizing the process, it results in solving the complex production and processing of biodiesel by batch.

Nonstoichiometric control of tunnel-filling order, thermal expansion, and dielectric relaxation in tetragonal tungsten Bronzes Ba0.5-xTaO3-x.

PubMed

Pan, Fengjuan; Li, Xiaohui; Lu, Fengqi; Wang, Xiaoming; Cao, Jiang; Kuang, Xiaojun; Véron, Emmanuel; Porcher, Florence; Suchomel, Matthew R; Wang, Jing; Allix, Mathieu

2015-09-21

Ordering of interpolated Ba(2+) chains and alternate Ta-O rows (TaO)(3+) in the pentagonal tunnels of tetragonal tungsten bronzes (TTB) is controlled by the nonstoichiometry in the highly nonstoichiometric Ba0.5-xTaO3-x system. In Ba0.22TaO2.72, the filling of Ba(2+) and (TaO)(3+) groups is partially ordered along the ab-plane of the simple TTB structure, resulting in a √2-type TTB superstructure (Pbmm), while in Ba0.175TaO2.675, the pentagonal tunnel filling is completely ordered along the b-axis of the simple TTB structure, leading to a triple TTB superstructure (P21212). Both superstructures show completely empty square tunnels favoring Ba(2+) conduction and feature unusual accommodation of Ta(5+) cations in the small triangular tunnels. In contrast with stoichiometric Ba6GaTa9O30, which shows linear thermal expansion of the cell parameters and monotonic decrease of permittivity with temperature within 100-800 K, these TTB superstructures and slightly nonstoichiometric simple TTB Ba0.4TaO2.9 display abnormally broad and frequency-dependent extrinsic dielectric relaxations in 10(3)-10(5) Hz above room temperature, a linear deviation of the c-axis thermal expansion around 600 K, and high dielectric permittivity ∼60-95 at 1 MHz at room temperature.

Regional modelling of groundwater flow and salt and environmental tracer transport in deep aquifers in the Paris Basin

NASA Astrophysics Data System (ADS)

Wei, Huai Fu; Ledoux, Emmanuel; De Marsily, Ghislain

1990-12-01

A hydrodynamic model which takes into account the aquitard storage effect was developed for the deep multilayered system including the Dogger aquifer and its surroundings in the Paris Basin. It provides a good explanation for a series of observations in the Dogger concerning, for instance, the hydraulic head, the salinity and the transmissivity. The calibration of the model also makes it possible to estimate some unmeasured parameters such as the aquifer and aquitard storage coefficients. Finally, the results of simulations of the transport of 4He and 14C strengthen the representativeness of the model. The Darcy average horizontal velocity in the Dogger, obtained with the model, is of the order of 0.33m year -1.

Informing a hydrological model of the Ogooué with multi-mission remote sensing data

NASA Astrophysics Data System (ADS)

Kittel, Cecile M. M.; Nielsen, Karina; Tøttrup, Christian; Bauer-Gottwein, Peter

2018-02-01

Remote sensing provides a unique opportunity to inform and constrain a hydrological model and to increase its value as a decision-support tool. In this study, we applied a multi-mission approach to force, calibrate and validate a hydrological model of the ungauged Ogooué river basin in Africa with publicly available and free remote sensing observations. We used a rainfall-runoff model based on the Budyko framework coupled with a Muskingum routing approach. We parametrized the model using the Shuttle Radar Topography Mission digital elevation model (SRTM DEM) and forced it using precipitation from two satellite-based rainfall estimates, FEWS-RFE (Famine Early Warning System rainfall estimate) and the Tropical Rainfall Measuring Mission (TRMM) 3B42 v.7, and temperature from ECMWF ERA-Interim. We combined three different datasets to calibrate the model using an aggregated objective function with contributions from (1) historical in situ discharge observations from the period 1953-1984 at six locations in the basin, (2) radar altimetry measurements of river stages by Envisat and Jason-2 at 12 locations in the basin and (3) GRACE (Gravity Recovery and Climate Experiment) total water storage change (TWSC). Additionally, we extracted CryoSat-2 observations throughout the basin using a Sentinel-1 SAR (synthetic aperture radar) imagery water mask and used the observations for validation of the model. The use of new satellite missions, including Sentinel-1 and CryoSat-2, increased the spatial characterization of river stage. Throughout the basin, we achieved good agreement between observed and simulated discharge and the river stage, with an RMSD between simulated and observed water amplitudes at virtual stations of 0.74 m for the TRMM-forced model and 0.87 m for the FEWS-RFE-forced model. The hydrological model also captures overall total water storage change patterns, although the amplitude of storage change is generally underestimated. By combining hydrological modeling with multi-mission remote sensing from 10 different satellite missions, we obtain new information on an otherwise unstudied basin. The proposed model is the best current baseline characterization of hydrological conditions in the Ogooué in light of the available observations.

Quantifying the potential for reservoirs to secure future surface water yields in the world’s largest river basins

NASA Astrophysics Data System (ADS)

Liu, Lu; Parkinson, Simon; Gidden, Matthew; Byers, Edward; Satoh, Yusuke; Riahi, Keywan; Forman, Barton

2018-04-01

Surface water reservoirs provide us with reliable water supply, hydropower generation, flood control and recreation services. Yet reservoirs also cause flow fragmentation in rivers and lead to flooding of upstream areas, thereby displacing existing land-use activities and ecosystems. Anticipated population growth and development coupled with climate change in many regions of the globe suggests a critical need to assess the potential for future reservoir capacity to help balance rising water demands with long-term water availability. Here, we assess the potential of large-scale reservoirs to provide reliable surface water yields while also considering environmental flows within 235 of the world’s largest river basins. Maps of existing cropland and habitat conservation zones are integrated with spatially-explicit population and urbanization projections from the Shared Socioeconomic Pathways to identify regions unsuitable for increasing water supply by exploiting new reservoir storage. Results show that even when maximizing the global reservoir storage to its potential limit (∼4.3–4.8 times the current capacity), firm yields would only increase by about 50% over current levels. However, there exist large disparities across different basins. The majority of river basins in North America are found to gain relatively little firm yield by increasing storage capacity, whereas basins in Southeast Asia display greater potential for expansion as well as proportional gains in firm yield under multiple uncertainties. Parts of Europe, the United States and South America show relatively low reliability of maintaining current firm yields under future climate change, whereas most of Asia and higher latitude regions display comparatively high reliability. Findings from this study highlight the importance of incorporating different factors, including human development, land-use activities, and climate change, over a time span of multiple decades and across a range of different scenarios when quantifying available surface water yields and the potential for reservoir expansion.

Strength Measurements of Archive K Basin Sludge Using a Soil Penetrometer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delegard, Calvin H.; Schmidt, Andrew J.; Chenault, Jeffrey W.

2011-12-06

Spent fuel radioactive sludge present in the K East and K West spent nuclear fuel storage basins now resides in the KW Basin in six large underwater engineered containers. The sludge will be dispositioned in two phases under the Sludge Treatment Project: (1) hydraulic retrieval into sludge transport and storage containers (STSCs) and transport to interim storage in Central Plateau and (2) retrieval from the STSCs, treatment, and packaging for shipment to the Waste Isolation Pilot Plant. In the years the STSCs are stored, sludge strength is expected to increase through chemical reaction, intergrowth of sludge crystals, and compaction andmore » dewatering by settling. Increased sludge strength can impact the type and operation of the retrieval equipment needed prior to final sludge treatment and packaging. It is important to determine whether water jetting, planned for sludge retrieval from STSCs, will be effective. Shear strength is a property known to correlate with the effectiveness of water jetting. Accordingly, the unconfined compressive strengths (UCS) of archive K Basin sludge samples and sludge blends were measured using a pocket penetrometer modified for hot cell use. Based on known correlations, UCS values can be converted to shear strengths. Twenty-six sludge samples, stored in hot cells for a number of years since last being disturbed, were identified as potential candidates for UCS measurement and valid UCS measurements were made for twelve, each of which was found as moist or water-immersed solids at least 1/2-inch deep. Ten of the twelve samples were relatively weak, having consistencies described as 'very soft' to 'soft'. Two of the twelve samples, KE Pit and KC-4 P250, were strong with 'very stiff' and 'stiff' consistencies described, respectively, as 'can be indented by a thumb nail' or 'can be indented by thumb'. Both of these sludge samples are composites collected from KE Basin floor and Weasel Pit locations. Despite both strong sludges having relatively high iron concentrations, attribution of their high strengths to this factor could not be made with confidence as other measured sludge samples, also from the KE Basin floor and of high iron concentration, were relatively weak. The observed UCS and shear strengths for the two strong sludges were greater than observed in any prior testing of K Basin sludge except for sludge processed at 185 C under hydrothermal conditions.« less

Assessing the influence of climate change and inter-basin water diversion on Haihe River basin, eastern China: a coupled model approach

NASA Astrophysics Data System (ADS)

Xia, Jun; Wang, Qiang; Zhang, Xiang; Wang, Rui; She, Dunxian

2018-04-01

The modeling of changes in surface water and groundwater in the areas of inter-basin water diversion projects is quite difficult because surface water and groundwater models are run separately most of the time and the lack of sufficient data limits the application of complex surface-water/groundwater coupling models based on physical laws, especially for developing countries. In this study, a distributed surface-water and groundwater coupling model, named the distributed time variant gain model-groundwater model (DTVGM-GWM), was used to assess the influence of climate change and inter-basin water diversion on a watershed hydrological cycle. The DTVGM-GWM model can reflect the interaction processes of surface water and groundwater at basin scale. The model was applied to the Haihe River Basin (HRB) in eastern China. The possible influences of climate change and the South-to-North Water Diversion Project (SNWDP) on surface water and groundwater in the HRB were analyzed under various scenarios. The results showed that the newly constructed model DTVGM-GWM can reasonably simulate the surface and river runoff, and describe the spatiotemporal distribution characteristics of groundwater level, groundwater storage and phreatic recharge. The prediction results under different scenarios showed a decline in annual groundwater exploitation and also runoff in the HRB, while an increase of groundwater storage and groundwater level after the SNWDP's operation. Additionally, as the project also addresses future scenarios, a slight increase is predicted in the actual evapotranspiration, soil water content and phreatic recharge. This study provides valuable insights for developing sustainable groundwater management options for the HRB.

Hydrogeologic framework and selected components of the groundwater budget for the upper Umatilla River Basin, Oregon

USGS Publications Warehouse

Herrera, Nora B.; Ely, Kate; Mehta, Smita; Stonewall, Adam J.; Risley, John C.; Hinkle, Stephen R.; Conlon, Terrence D.

2017-05-31

Executive SummaryThis report presents a summary of the hydrogeology of the upper Umatilla River Basin, Oregon, based on characterization of the hydrogeologic framework, horizontal and vertical directions of groundwater flow, trends in groundwater levels, and components of the groundwater budget. The conceptual model of the groundwater flow system integrates available data and information on the groundwater resources of the upper Umatilla River Basin and provides insights regarding key hydrologic processes, such as the interaction between the groundwater and surface water systems and the hydrologic budget.The conceptual groundwater model developed for the study area divides the groundwater flow system into five hydrogeologic units: a sedimentary unit, three Columbia River basalt units, and a basement rock unit. The sedimentary unit, which is not widely used as a source of groundwater in the upper basin, is present primarily in the lowlands and consists of conglomerate, loess, silt and sand deposits, and recent alluvium. The Columbia River Basalt Group is a series of Miocene flood basalts that are present throughout the study area. The basalt is uplifted in the southeastern half of the study area, and either underlies the sedimentary unit, or is exposed at the surface. The interflow zones of the flood basalts are the primary aquifers in the study area. Beneath the flood basalts are basement rocks composed of Paleogene to Pre-Tertiary sedimentary, volcanic, igneous, and metamorphic rocks that are not used as a source of groundwater in the upper Umatilla River Basin.The major components of the groundwater budget in the upper Umatilla River Basin are (1) groundwater recharge, (2) groundwater discharge to surface water and wells, (3) subsurface flow into and out of the basin, and (4) changes in groundwater storage.Recharge from precipitation occurs primarily in the upland areas of the Blue Mountains. Mean annual recharge from infiltration of precipitation for the upper Umatilla River Basin during 1951–2010 is about 9.6 inches per year (in/yr). Annual recharge from precipitation for water year 2010 ranged from 3 in. in the lowland area to about 30 in. in the Blue Mountains. Using Kahle and others (2011) data and methods from the Columbia Plateau regional model, average annual recharge from irrigation is estimated to be about 2.2 in/yr for the 13 square miles of irrigated land in the upper Umatilla River Basin.Groundwater discharges to streams throughout the year and is a large component of annual streamflow in the upper Umatilla River Basin. Upward vertical hydraulic gradients near the Umatilla River indicate the potential for groundwater discharge. Groundwater discharge to the Umatilla River generally occurs in the upper part of the basin, upstream from the main stem.Groundwater development in the upper Umatilla River Basin began sometime after 1950 (Davies-Smith and others, 1988; Gonthier and Bolke, 1991). By water year 2010, groundwater use in the upper Umatilla River Basin was approximately 11,214 acre-feet (acre-ft). Total groundwater withdrawals for the study area were estimated at 7,575 acre-ft for irrigation, 3,173 acre-ft for municipal use, and 466 acre-ft for domestic use.Total groundwater flow into or from the study area depends locally on geology and hydraulic head distribution. Estimates of subsurface flow were calculated using the U.S. Geological Survey Columbia Plateau regional groundwater flow model. Net flux values range from 25,000 to 27,700 acre-ft per year and indicate that groundwater is moving out of the upper Umatilla River Basin into the lower Umatilla River Basin.Water level changes depend on storage changes within an aquifer, and storage changes depend on the storage properties of the aquifer, as well as recharge to or discharge from the aquifer. Groundwater level data in the upper Umatilla River Basin are mostly available from wells in Columbia River basalt units, which indicate areas of long-term water level declines in the Grande Ronde basalt unit near Pendleton and Athena, Oregon. Groundwater levels in the Wanapum basalt unit do not show long-term declines in the upper Umatilla River Basin. Because of pumping, some areas in the upper Umatilla River Basin have shown a decrease, or reversal, in the upward vertical head gradient.Key data needs are improvement of the spatial and temporal distribution of water-level data collection and continued monitoring of streamflow gaging sites. Additionally, refinement of recharge estimates would enhance understanding of the processes that provide the groundwater resources in the upper Umatilla River Basin.

Site Characterization for CO 2 Storage from Coal-fired Power Facilities in the Black Warrior Basin of Alabama

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clark, Peter E.; Pashin, Jack; Carlson, Eric

2013-11-29

Coal-fired power plants produce large quantities of carbon dioxide. In order to mitigate the greenhouse gas emissions from these power plants, it is necessary to separate and store the carbon dioxide. Saline formations provide a potential sink for carbon dioxide and delineating the capacity of the various known saline formations is a key part of building a storage inventory. As part of this effort, a project was undertaken to access the storage capacity of saline reservoirs in the Black Warrior Basin of Alabama. This basin has been a productive oil and gas reservoir that is well characterized to the westmore » of the two major coal-fired power plants that are north of Birmingham. The saline zones were thought to extend as far east as the Sequatchie Anticline which is just east of the power plants. There is no oil or gas production in the area surrounding the power plants so little is known about the formations in that area. A geologic characterization well was drilled on the Gorgas Power Plant site, which is the farthest west of two power plants in the area. The well was planned to be drilled to approximately 8,000 feet, but drilling was halted at approximately 5,000 feet when a prolific freshwater zone was penetrated. During drilling, a complete set of cores through all of the potential injection zones and the seals above these zones were acquired. A complete set of openhole logs were run along with a vertical seismic profile (VSP). Before drilling started two approximately perpendicular seismic lines were run and later correlated with the VSP. While the zones that were expected were found at approximately the predicted depths, the zones that are typically saline through the reservoir were found to be saturated with a light crude oil. Unfortunately, both the porosity and permeability of these zones were small enough that no meaningful hydrocarbon production would be expected even with carbon dioxide flooding. While this part of the basin was found to be unsuitable for carbon dioxide injection, there is still a large storage capacity in the basin to the west of the power plants. It will, however, require pipeline construction to transport the carbon dioxide to the injection sites.« less

Observation of polar order and thermochromic behaviour in a chiral bent-core system exhibiting exotic mesophases due to superstructural frustration.

PubMed

Punjani, Vidhika; Mohiuddin, Golam; Kaur, Supreet; Khan, Raj Kumar; Ghosh, Sharmistha; Pal, Santanu Kumar

2018-04-03

A new approach accompanied by superstructural frustration is reported. By attaching a cholesterol moiety directly to the central bent-core system it displayed exotic BPIII, BPII/I, Ncyb*, TGBA, SmAPA, SmA and SmX phases as shown by X-ray scattering results. While higher homologues of the series exhibited spontaneous formation of polar order (Ps ∼ 61 nC cm-2) upon applied voltage, the lower homologues showed thermochromic behaviour which can also be trapped via temperature quenching.

Experimental investigation of colorless ONU employing superstructured fiber Bragg gratings in WDM/OCDMA-PON

NASA Astrophysics Data System (ADS)

Wang, Dawei; Cheng, Liang; Chen, Biao

2009-11-01

Colorless optical network unit (ONU) is a very important concept for the wavelength division multiplexing (WDM) based passive optical networks (PON). We present a novel scheme to construct non-wavelength-selective ONUs in WDM/OCDMA-PON by making use of the broad spectrum band of superstructure fiber Bragg gratings (SSFBGs). The experiment results reveal that the spectrum-sliced encoded signals from different wavelength channels can be successfully decoded with the same SSFBGs, and thus the proposed colorless ONU scheme is proved to be feasible.

Reviving the "Ganges Water Machine": where and how much?

NASA Astrophysics Data System (ADS)

Muthuwatta, Lal; Amarasinghe, Upali A.; Sood, Aditya; Surinaidu, Lagudu

2017-05-01

Runoff generated in the monsoon months in the upstream parts of the Ganges River basin (GRB) contributes substantially to downstream floods, while water shortages in the dry months affect agricultural production in the basin. This paper examines the potential for subsurface storage (SSS) in the Ganges basin to mitigate floods in the downstream areas and increase the availability of water during drier months. The Soil and Water Assessment Tool (SWAT) is used to estimate sub-basin water availability. The water availability estimated is then compared with the sub-basin-wise unmet water demand for agriculture. Hydrological analysis reveals that some of the unmet water demand in the sub-basin can be met provided it is possible to capture the runoff in sub-surface storage during the monsoon season (June to September). Some of the groundwater recharge is returned to the stream as baseflow and has the potential to increase dry season river flows. To examine the impacts of groundwater recharge on flood inundation and flows in the dry season (October to May), two groundwater recharge scenarios are tested in the Ramganga sub-basin. Increasing groundwater recharge by 35 and 65 % of the current level would increase the baseflow during the dry season by 1.46 billion m3 (34.5 % of the baseline) and 3.01 billion m3 (71.3 % of the baseline), respectively. Analysis of pumping scenarios indicates that 80 000 to 112 000 ha of additional wheat area can be irrigated in the Ramganga sub-basin by additional SSS without reducing the current baseflow volumes. Augmenting SSS reduces the peak flow and flood inundated areas in Ramganga (by up to 13.0 % for the 65 % scenario compared to the baseline), indicating the effectiveness of SSS in reducing areas inundated under floods in the sub-basin. However, this may not be sufficient to effectively control the flood in the downstream areas of the GRB, such as in the state of Bihar (prone to floods), which receives a total flow of 277 billion m3 from upstream sub-basins.

Monitoring small reservoirs' storage with satellite remote sensing in inaccessible areas

NASA Astrophysics Data System (ADS)

Avisse, Nicolas; Tilmant, Amaury; François Müller, Marc; Zhang, Hua

2017-12-01

In river basins with water storage facilities, the availability of regularly updated information on reservoir level and capacity is of paramount importance for the effective management of those systems. However, for the vast majority of reservoirs around the world, storage levels are either not measured or not readily available due to financial, political, or legal considerations. This paper proposes a novel approach using Landsat imagery and digital elevation models (DEMs) to retrieve information on storage variations in any inaccessible region. Unlike existing approaches, the method does not require any in situ measurement and is appropriate for monitoring small, and often undocumented, irrigation reservoirs. It consists of three recovery steps: (i) a 2-D dynamic classification of Landsat spectral band information to quantify the surface area of water, (ii) a statistical correction of DEM data to characterize the topography of each reservoir, and (iii) a 3-D reconstruction algorithm to correct for clouds and Landsat 7 Scan Line Corrector failure. The method is applied to quantify reservoir storage in the Yarmouk basin in southern Syria, where ground monitoring is impeded by the ongoing civil war. It is validated against available in situ measurements in neighbouring Jordanian reservoirs. Coefficients of determination range from 0.69 to 0.84, and the normalized root-mean-square error from 10 to 16 % for storage estimations on six Jordanian reservoirs with maximal water surface areas ranging from 0.59 to 3.79 km2.

Understanding the hydrologic sources and sinks in the Nile Basin using multisource climate and remote sensing data sets

USGS Publications Warehouse

Senay, Gabriel; Velpuri, Naga Manohar; Bohms, Stefanie; Demissie, Yonas; Gebremichael, Mekonnen

2014-01-01

In this study, we integrated satellite-drived precipitation and modeled evapotranspiration data (2000–2012) to describe spatial variability of hydrologic sources and sinks in the Nile Basin. Over 2000–2012 period, 4 out of 11 countries (Ethiopia, Tanzania, Kenya, and Uganda) in the Nile Basin showed a positive water balance while three downstream countries (South Sudan, Sudan, and Egypt) showed a negative balance. Gravity Recovery and Climate Experiment (GRACE) mass deviation in storage data analysis showed that at annual timescales, the Nile Basin storage change is substantial while over longer time periods, it is minimal (<1% of basin precipitation). We also used long-term gridded runoff and river discharge data (1869–1984) to understand the discrepancy in the observed and expected flow along the Nile River. The top three countries that contribute most to the flow are Ethiopia, Tanzania, and Kenya. The study revealed that ∼85% of the runoff generated in the equatorial region is lost in an interstation basin that includes the Sudd wetlands in South Sudan; this proportion is higher than the literature reported loss of 50% at the Sudd wetlands alone. The loss in runoff and flow volume at different sections of the river tend to be more than what can be explained by evaporation losses, suggesting a potential recharge to deeper aquifers that are not connected to the Nile channel systems. On the other hand, we also found that the expected average annual Nile flow at Aswan is greater (97 km3) than the reported amount (84 km3). Due to the large variations of the reported Nile flow at different locations and time periods, the study results indicate the need for increased hydrometeorological instrumentation of the basin. The study also helped improve our understanding of the spatial dynamics of water sources and sinks in the Nile Basin and identified emerging hydrologic questions that require further attention.

Comprehensive Characterization of Droughts to Assess the Effectiveness of a Basin-Wide Integrated Water Management in the Yakima River Basin

NASA Astrophysics Data System (ADS)

Demissie, Y.; Mortuza, M. R.; Li, H. Y.

2017-12-01

Better characterization and understanding of droughts and their potential links to climate and hydrologic factors are essential for water resources planning and management in drought-sensitive but agriculturally productive regions like the Yakima River Basin (YKB) in Washington State. The basin is semi-arid and heavily relies on a fully appropriated irrigation water for fruit and crop productions that worth more than 3 billion annually. The basin experienced three major droughts since 2000 with estimated 670 million losses in farm revenue. In response to these and expected worsening drought conditions in the future, there is an ongoing multi-agency effort to adopt a basin-wide integrated water management to ensure water security during severe droughts. In this study, the effectiveness of the proposed water management plan to reduce the frequency and severity of droughts was assessed using a new drought index developed based on the seasonal variations of precipitation, temperature, snow accumulation, streamflow, and reservoir storages. In order to uncover the underlying causes of the various types of droughts observed during the 1961-2016, explanatory data analysis using deep learning was conducted for the local climate and hydrologic data including total water supply available, as well as global climatic phenomenon (El Niño/Southern Oscillation, Pacific Decadal Oscillation and North Atlantic Oscillation). The preliminary results showed that besides shortage in annual precipitation, various combinations of climate and hydrologic factors are responsible for the different drought conditions in the basin. Particularly, the winter snowpack, which provides about 2/3 of the surface water in the basin along with the carryover storage from the reservoirs play an important role during both single- and multiple-year drought events. Besides providing the much-needed insights about characteristics of droughts and their contributing factors, the outcome of the study is expected to have a direct contribution to the ongoing discussion of the effectiveness of the water management plan in the YRB.

Understanding the hydrologic sources and sinks in the Nile Basin using multisource climate and remote sensing data sets

NASA Astrophysics Data System (ADS)

Senay, Gabriel B.; Velpuri, Naga Manohar; Bohms, Stefanie; Demissie, Yonas; Gebremichael, Mekonnen

2014-11-01

In this study, we integrated satellite-drived precipitation and modeled evapotranspiration data (2000-2012) to describe spatial variability of hydrologic sources and sinks in the Nile Basin. Over 2000-2012 period, 4 out of 11 countries (Ethiopia, Tanzania, Kenya, and Uganda) in the Nile Basin showed a positive water balance while three downstream countries (South Sudan, Sudan, and Egypt) showed a negative balance. Gravity Recovery and Climate Experiment (GRACE) mass deviation in storage data analysis showed that at annual timescales, the Nile Basin storage change is substantial while over longer time periods, it is minimal (<1% of basin precipitation). We also used long-term gridded runoff and river discharge data (1869-1984) to understand the discrepancy in the observed and expected flow along the Nile River. The top three countries that contribute most to the flow are Ethiopia, Tanzania, and Kenya. The study revealed that ˜85% of the runoff generated in the equatorial region is lost in an interstation basin that includes the Sudd wetlands in South Sudan; this proportion is higher than the literature reported loss of 50% at the Sudd wetlands alone. The loss in runoff and flow volume at different sections of the river tend to be more than what can be explained by evaporation losses, suggesting a potential recharge to deeper aquifers that are not connected to the Nile channel systems. On the other hand, we also found that the expected average annual Nile flow at Aswan is greater (97 km3) than the reported amount (84 km3). Due to the large variations of the reported Nile flow at different locations and time periods, the study results indicate the need for increased hydrometeorological instrumentation of the basin. The study also helped improve our understanding of the spatial dynamics of water sources and sinks in the Nile Basin and identified emerging hydrologic questions that require further attention.

Applications of the SWOT Mission to Reservoirs in the Mekong River Basin

NASA Astrophysics Data System (ADS)

Bonnema, M.; Hossain, F.

2017-12-01

The forthcoming Surface Water and Ocean Topography (SWOT) mission has the potential to significantly improve our ability to observe artificial reservoirs globally from a remote sensing perspective. By providing simultaneous estimates of reservoir water surface extent and elevation with near global coverage, reservoir storage changes can be estimated. Knowing how reservoir storage changes over time is critical for understanding reservoir impacts on river systems. In data limited regions, remote sensing is often the only viable method of retrieving such information about reservoir operations. When SWOT launches in 2021, it will join an array of satellite sensors with long histories of reservoir observation and monitoring capabilities. There are many potential synergies in the complimentary use of future SWOT observations with observations from current satellite sensors. The work presented here explores the potential benefits of utilizing SWOT observations over 20 reservoirs in the Mekong River Basin. The SWOT hydrologic simulator, developed by NASA Jet Propulsion Laboratory, is used to generate realistic SWOT observations, which are then inserted into a previously established remote sensing modeling framework of the 20 Mekong Basin reservoirs. This framework currently combines data from Landsat missions, Jason radar altimeters, and the Shuttle Radar and Topography Mission (SRTM), to provide monthly estimates of reservoir storage change. The incorporation of SWOT derived reservoir surface area and elevation into the model is explored in an effort to improve both accuracy and temporal resolution of observed reservoir operations.

On the treatment of evapotranspiration, soil moisture accounting, and aquifer recharge in monthly water balance models

USGS Publications Warehouse

Alley, William M.

1984-01-01

Several two- to six-parameter regional water balance models are examined by using 50-year records of monthly streamflow at 10 sites in New Jersey. These models include variants of the Thornthwaite-Mather model, the Palmer model, and the more recent Thomas abcd model. Prediction errors are relatively similar among the models. However, simulated values of state variables such as soil moisture storage differ substantially among the models, and fitted parameter values for different models sometimes indicated an entirely different type of basin response to precipitation. Some problems in parameter identification are noted, including difficulties in identifying an appropriate time lag factor for the Thornthwaite-Mather-type model for basins with little groundwater storage, very high correlations between upper and lower storages in the Palmer-type model, and large sensitivity of parameter a of the abcd model to bias in estimates of precipitation and potential evapotranspiration. Modifications to the threshold concept of the Thornthwaite-Mather model were statistically valid for the six stations in northern New Jersey. The abcd model resulted in a simulated seasonal cycle of groundwater levels similar to fluctuations observed in nearby wells but with greater persistence. These results suggest that extreme caution should be used in attaching physical significance to model parameters and in using the state variables of the models in indices of drought and basin productivity.

National Assessment of Geologic Carbon Dioxide Storage Resources -- Trends and Interpretations

NASA Astrophysics Data System (ADS)

Buursink, M. L.; Blondes, M. S.; Brennan, S.; Drake, R., II; Merrill, M. D.; Roberts-Ashby, T. L.; Slucher, E. R.; Warwick, P.

2013-12-01

In 2012, the U.S. Geological Survey (USGS) completed an assessment of the technically accessible storage resource (TASR) for carbon dioxide (CO2) in geologic formations underlying the onshore and State waters area of the United States. The formations assessed are at least 3,000 feet (914 meters) below the ground surface. The TASR is an estimate of the CO2 storage resource that may be available for CO2 injection and storage that is based on present-day geologic and hydrologic knowledge of the subsurface and current engineering practices. Individual storage assessment units (SAUs) for 36 basins or study areas were defined on the basis of geologic and hydrologic characteristics outlined in the USGS assessment methodology. The mean national TASR is approximately 3,000 metric gigatons. To augment the release of the assessment, this study reviews input estimates and output results as a part of the resource calculation. Included in this study are a collection of both cross-plots and maps to demonstrate our trends and interpretations. Alongside the assessment, the input estimates were examined for consistency between SAUs and cross-plotted to verify expected trends, such as decreasing storage formation porosity with increasing SAU depth, for instance, and to show a positive correlation between storage formation porosity and permeability estimates. Following the assessment, the output results were examined for correlation with selected input estimates. For example, there exists a positive correlation between CO2 density and the TASR, and between storage formation porosity and the TASR, as expected. These correlations, in part, serve to verify our estimates for the geologic variables. The USGS assessment concluded that the Coastal Plains Region of the eastern and southeastern United States contains the largest storage resource. Within the Coastal Plains Region, the storage resources from the U.S. Gulf Coast study area represent 59 percent of the national CO2 storage capacity. As part of this follow up study, additional maps were generated to show the geographic distribution of the input estimates and the output results across the U.S. For example, the distribution of the SAUs with fresh, saline or mixed formation water quality is shown. Also mapped is the variation in CO2 density as related to basin location and to related properties such as subsurface temperature and pressure. Furthermore, variation in the estimated SAU depth and resulting TASR are shown across the assessment study areas, and these depend on the geologic basin size and filling history. Ultimately, multiple map displays are possible with the complete data set of input estimates and range of reported results. The findings from this study show the effectiveness of the USGS methodology and the robustness of the assessment.

Estimating terrestrial water storage changes in the Tarim River Basin using GRACE data

NASA Astrophysics Data System (ADS)

Zhao, Kefei; Li, Xia

2017-12-01

Terrestrial water storage (TWS) plays a fundamental role in the arid Tarim River Basin, which is mainly fed by glacier and snow melt water. However, the significant scarcity of ground-based observations, especially in the high-altitude mountain areas, limits our understanding of TWS changes in this region. In this study, TWS variations in the Tarim River Basin were estimated using monthly GRACE Level 2 Release 5 (RL05) products from 2002 to August 2015. The GRACE results were validated against outputs of Global Land Data Assimilation System (GLDAS) including spatial and temporal correlation analysis. The correlation between the regional TWS time-series of GRACE and GLDAS is 0.7777. It was found that GRACE TWS shows a slightly decreasing trend of -1.4069 ± 0.5060 mm yr-1 in the entire Tarim River Basin during the study period and a significant spatial difference over the study area. An apparent decreasing trend in Tien Shan and the Taklamakan Desert, and a significant increasing trend in the Kunlun Mountains and eastern Pamirs Plateau were also detected. Moreover, seasonal analysis of regional TWS time-series, precipitation and the 0 °C isotherm height in summer showed that detrended TWS variations were consistent with precipitation while long-term trends of TWS were contrary to that of the 0 °C isotherm height in summer. It implied that the interannual TWS variations were dominated by precipitation and the long-term trend of TWS changes was affected by changes of the 0 °C isotherm height in summer. This information could enrich our knowledge about water storage changes, including glacier mass balance and groundwater, and its response to climate change in this vast but sparse in-situ measurements area.

Submittal for 2003 Project of the Year K Basins Fuel Transfer System Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

GERBER, M.S.

2003-01-29

Fluor Hanford, Inc. is pleased to submit the K Basins Fuel Transfer System (FTS) for consideration by the Project Management Institute as Project of the Year for 2003. The FTS involved installing a unique, unproven system in an inhospitable and deteriorating radiological and hazardous environment, under very stringent requirements and within an extremely condensed schedule, just 19 months, from authorization to full operations. The FTS, therefore, is an excellent example of effective project management, and the dynamic involvement of an integrated team representing a broad spectrum of personnel, disciplines, and services. The FTS is an integral and critical part ofmore » a larger project at Hanford -the Spent Nuclear Fuel Project (SNF). The mission of the SNF Project is to relocate used, or spent, nuclear fuel to safe interim storage, permanently dispose of radioactive debris in the K-Basins, and deactivate all related facilities and prepare them for demolition. Today, the FTS is being used to remove highly radioactive nuclear fuel from an aging, and potentially unstable storage in underground pools of water--the K-Basins--and safely transport it to a processing area to be cleaned, dried and sent to safe storage. The role the FTS plays in successfully completing the mission of the SNF Project is concrete evidence of the intrinsic value of project management and a testimonial to the innovation, ingenuity, and teamwork of many--from workers to management and subcontractors, and regulators to stakeholders. It's a true success story and one that will have a happy ending, safely eliminating the risk of potentially contaminating one of Washington state's most valuable natural resources, the Columbia River. This nomination is dedicated to that Project Team.« less

Framework for the assessment of interaction between CO2 geological storage and other sedimentary basin resources.

PubMed

Michael, K; Whittaker, S; Varma, S; Bekele, E; Langhi, L; Hodgkinson, J; Harris, B

2016-02-01

Sedimentary basins around the world considered suitable for carbon storage usually contain other natural resources such as petroleum, coal, geothermal energy and groundwater. Storing carbon dioxide in geological formations in the basins adds to the competition for access to the subsurface and the use of pore space where other resource-based industries also operate. Managing potential impacts that industrial-scale injection of carbon dioxide may have on other resource development must be focused to prevent potential conflicts and enhance synergies where possible. Such a sustainable coexistence of various resource developments can be accomplished by implementing a Framework for Basin Resource Management strategy (FBRM). The FBRM strategy utilizes the concept of an Area of Review (AOR) for guiding development and regulation of CO2 geological storage projects and for assessing their potential impact on other resources. The AOR is determined by the expected physical distribution of the CO2 plume in the subsurface and the modelled extent of reservoir pressure increase resulting from the injection of the CO2. This information is used to define the region to be characterised and monitored for a CO2 injection project. The geological characterisation and risk- and performance-based monitoring will be most comprehensive within the region of the reservoir containing the carbon dioxide plume and should consider geological features and wells continuously above the plume through to its surface projection; this region defines where increases in reservoir pressure will be greatest and where potential for unplanned migration of carbon dioxide is highest. Beyond the expanse of the carbon dioxide plume, geological characterisation and monitoring should focus only on identified features that could be a potential migration conduit for either formation water or carbon dioxide.

Estimating aquifer properties using time-lapse, high precision gravity surveys and groundwater modeling

NASA Astrophysics Data System (ADS)

Keating, E.; Cogbill, A. H.; Ferguson, J. F.

2003-12-01

In the past, gravity methods have had limited application for monitoring aquifers, primarily due to the poor drift characteristics of relative gravimeters, which made long-term gravity studies of aquifers prohibitively expensive. Recent developments in portable, very accurate, absolute gravity instruments having essentially zero long-term drift have reawakened interest in using gravity methods for hydrologic monitoring. Such instruments have accuracies of 7 microGals or better and can acquire measurements at the rate of better than one station per hour. Theoretically, temporal changes in gravity can be used to infer storage characteristics and fluxes into and out of the aquifer. The sensitivity of the method to scaling effects, temporal lags between recharge/discharge and changes in storage, and to uncertainties in aquifer structure are poorly understood. In preparation for interpreting a basin-scale, time-lapse gravity data set, we have established a network of gravity stations within the Espanola Basin in northern New Mexico, a semi-arid region which is experiencing rapid population growth and groundwater resource use. We are using an existing basin-scale groundwater flow model to predict changes in mass, given our current level of understanding of inflows, outflows, and aquifer properties. Preliminary model results will be used to examine scaling issues related to the spatial density of the gravity station network and depths to the regional water table. By modeling the gravitational response to water movement in the aquifer, we study the sensitivity of gravity measurements to aquifer storage properties, given other known uncertainties in basin-scale fluxes. Results will be used to evaluate the adequacy of the existing network and to modify its design, if necessary.

Sediment Management at the Watershed Level

DTIC Science & Technology

2012-08-01

al. 2005). Trimble examined ten river basins (1,000 to 7,500 mi2 ) and found that the sediment yield averaged about six percent. He attributed the...importance of storage and remobilization in controlling sediment yield from the 139 mi2 Coon Creek watershed in Wisconsin. Trimble prepared sediment...Federal government in 1984, DHP activities targeted sixteen watersheds comprising 2,625 mi2 within the Yazoo River Basin in the Lower Mississippi

Evolving Groundwater Rights and Management in Metropolitan Los Angeles: Implications for Water Supply and Stormwater

NASA Astrophysics Data System (ADS)

Porse, E.; Pincetl, S.; Glickfeld, M.

2015-12-01

Groundwater supports many aspects of human life. In cities, groundwater can provide a cost-effective source of water for drinking and industrial uses, while groundwater basins provide storage. The role of groundwater in a city's water supply tends to change over time. In the Los Angeles metropolitan area, groundwater is critical. Over decades, users in the region's many basins allocated annual pumping rights to groundwater among users through adjudications. These rights were determined through collective processes over decades, which contributed to the complex array of public and private organizations involved in water management. The rights also continue to evolve. We analyzed changes in the distribution of groundwater rights over time for adjudicated basins in Southern Los Angeles County. Results indicate that groundwater rights are increasingly: 1) controlled or regulated by public institutions and municipalities, and 2) consolidated among larger users. Yet, both the percentage of total supplies provided by groundwater, as well as the distribution of groundwater rights, varies widely among cities and communities throughout Los Angeles. As metropolitan Los Angeles faces reduced water imports and emphasizes local water reliance, access to pumping rights and storage capacity in groundwater basins will become even more vital. We discuss implications of our results for future urban water management.

Preliminary Modelling of the Effect of Impurity in CO2 Streams on the Storage Capacity and the Plume Migration in Pohang Basin, Korea

NASA Astrophysics Data System (ADS)

Park, Yongchan; Choi, Byoungyoung; Shinn, Youngjae

2015-04-01

Captured CO2 streams contain various levels of impurities which vary depending on the combustion technology and CO2 sources such as a power plant and iron and steel production processes. Common impurities or contaminants are non-condensable gases like nitrogen, oxygen and hydrogen, and are also air pollutants like sulphur and nitrogen oxides. Specifically for geological storage, the non-condensable gases in CO2 streams are not favourable because they can decrease density of the injected CO2 stream and can affect buoyancy of the plume. However, separation of these impurities to obtain the CO2 purity higher than 99% would greatly increase the cost of capture. In 2010, the Korean Government announced a national framework to develop CCS, with the aim of developing two large scale integrated CCS projects by 2020. In order to achieve this goal, a small scale injection project into Pohang basin near shoreline has begun which is seeking the connection with a capture project, especially at a steel company. Any onshore sites that are suitable for the geological storage are not identified by this time so we turned to the shallow offshore Pohang basin where is close to a large-scale CO2 source. Currently, detailed site surveys are being undertaken and the collected data were used to establish a geological model of the basin. In this study, we performed preliminary modelling study on the effect of impurities on the geological storage using the geological model. Using a potential compositions of impurities in CO2 streams from the steel company, we firstly calculated density and viscosity of CO2 streams as a function of various pressure and temperature conditions with CMG-WINPROP and then investigated the effect of the non-condensable gases on storage capacity, injectivity and plume migrations with CMG-GEM. Further simulations to evaluate the areal and vertical sweep efficiencies by impurities were perform in a 2D vertical cross section as well as in a 3D simulation grid. Also, pressure increases caused by the impurities and the partitioning between CO2 and other non-condensable gases were explored. In addition, the possibility of using these contaminants as a tracer were examined.

Groundwater-flow budget for the lower Apalachicola-Chattahoochee-Flint River Basin in southwestern Georgia and parts of Florida and Alabama, 2008–12

USGS Publications Warehouse

Jones, L. Elliott; Painter, Jaime A.; LaFontaine, Jacob H.; Sepúlveda, Nicasio; Sifuentes, Dorothy F.

2017-12-29

As part of the National Water Census program in the Apalachicola-Chattahoochee-Flint (ACF) River Basin, the U.S. Geological Survey evaluated the groundwater budget of the lower ACF, with particular emphasis on recharge, characterizing the spatial and temporal relation between surface water and groundwater, and groundwater pumping. To evaluate the hydrologic budget of the lower ACF River Basin, a groundwater-flow model, constructed using MODFLOW-2005, was developed for the Upper Floridan aquifer and overlying semiconfining unit for 2008–12. Model input included temporally and spatially variable specified recharge, estimated using a Precipitation-Runoff Modeling System (PRMS) model for the ACF River Basin, and pumping, partly estimated on the basis of measured agricultural pumping rates in Georgia. The model was calibrated to measured groundwater levels and base flows, which were estimated using hydrograph separation.The simulated groundwater-flow budget resulted in a small net cumulative loss of groundwater in storage during the study period. The model simulated a net loss in groundwater storage for all the subbasins as conditions became substantially drier from the beginning to the end of the study period. The model is limited by its conceptualization, the data used to represent and calibrate the model, and the mathematical representation of the system; therefore, any interpretations should be considered in light of these limitations. In spite of these limitations, the model provides insight regarding water availability in the lower ACF River Basin.

Observation of Vacancies, Faults, and Superstructures in Ln5Mo2O12 (Ln = La, Y, and Lu) Compounds with Direct Mo-Mo Bonding.

PubMed

Colabello, Diane M; Sobalvarro, Elizabeth M; Sheckelton, John P; Neuefeind, Joerg C; McQueen, Tyrel M; Khalifah, Peter G

2017-11-06

Among oxide compounds with direct metal-metal bonding, the Y 5 Mo 2 O 12 (A 5 B 2 O 12 ) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2 O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal-metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal-metal bonding have integer oxidation states resulting from the lifting of orbital degeneracy typically induced by the metal-metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5 Mo 2 O 12 (Ln = La-Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2 O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1-2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5 Mo 2 O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. This represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.

Observation of Vacancies, Faults, and Superstructures in Ln 5Mo 2O 12 (Ln = La, Y, and Lu) Compounds with Direct Mo–Mo Bonding

DOE PAGES

Colabello, Diane M.; Sobalvarro, Elizabeth M.; Sheckelton, John P.; ...

2017-10-26

Among oxide compounds with direct metal–metal bonding, the Y 5Mo 2O 12 (A 5B 2O 12) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal–metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal–metal bonding have integer oxidation states resulting from the lifting of orbital degeneracymore » typically induced by the metal–metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5Mo 2O 12 (Ln = La–Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown in this paper that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1–2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5Mo 2O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. Finally, this represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.« less

Observation of Vacancies, Faults, and Superstructures in Ln 5Mo 2O 12 (Ln = La, Y, and Lu) Compounds with Direct Mo–Mo Bonding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Colabello, Diane M.; Sobalvarro, Elizabeth M.; Sheckelton, John P.

Among oxide compounds with direct metal–metal bonding, the Y 5Mo 2O 12 (A 5B 2O 12) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal–metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal–metal bonding have integer oxidation states resulting from the lifting of orbital degeneracymore » typically induced by the metal–metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5Mo 2O 12 (Ln = La–Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown in this paper that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1–2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5Mo 2O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. Finally, this represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.« less

Comparison and Assessment of Three Advanced Land Surface Models in Simulating Terrestrial Water Storage Components over the United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xia, Youlong; Mocko, David; Huang, Maoyi

2017-03-01

In preparation for next generation North American Land Data Assimilation System (NLDAS), 3 three advanced land surface models (CLM4.0, Noah-MP, and CLSM-F2.5) were run from 1979 4 to 2014 within the NLDAS-based framework. Monthly total water storage anomaly (TWSA) and 5 its individual water storage components were evaluated against satellite-based and in situ 6 observations, and reference reanalysis products at basin-wide and statewide scales. In general, all 7 three models are able to reasonably capture the monthly and interannual variability and 8 magnitudes for TWSA. However, contributions of the anomalies of individual water 9 components to TWSA are very dependentmore » on the model and basin. A major contributor to the 10 TWSA is the anomaly of total column soil moisture content (SMCA) for CLM4.0 and Noah-MP 11 or groundwater storage anomaly (GWSA) for CLSM-F2.5 although other components such as 12 the anomaly of snow water equivalent (SWEA) also play some role. For each individual water 13 storage component, the models are able to capture broad features such as monthly and 14 interannual variability. However, there are large inter-model differences and quantitative 15 uncertainties in this study. Therefore, it should be thought of as a preliminary synthesis and 16 analysis.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Yi, E-mail: zhouyihn@163.com; Huang, Yan; Li, Dang

Graphical abstract: SEM images of the samples synthesized at different hydrothermal temperatures for 8 h: (a) 75; (b) 100; (c) 120; and (d) 140°C, followed by calcination at 450 °C for 2 h. Highlights: ► Effects of calcination temperature on the phase transformation were studied. ► Effects of hydrothermal temperature and time on the morphology growth were studied. ► A two-stage reaction mechanism for the formation was presented. ► The photocatalytic activity was evaluated under sunlight irradiation. ► Effects of calcination temperature on the photocatalytic activity were studied. - Abstract: Novel three-dimensional sea-urchin-like hierarchical TiO{sub 2} superstructures were synthesized onmore » a Ti plate in a mixture of H{sub 2}O{sub 2} and NaOH aqueous solution by a facile one-pot hydrothermal method at a low temperature, followed by protonation and calcination. The results of series of electron microscopy characterizations suggested that the hierarchical TiO{sub 2} superstructures consisted of numerous one-dimensional nanostructures. The microspheres were approximately 2–4 μm in diameter, and the one-dimensional TiO{sub 2} nanostructures were up to 600–700 nm long. A two-stage reaction mechanism, i.e., initial growth and then assembly, was proposed for the formation of these architectures. The three-dimensional sea-urchin-like hierarchical TiO{sub 2} microstructures showed excellent photocatalytic activity for the degradation of Rhodamine B aqueous solution under sunlight irradiation, which was attributed to the special three-dimensional hierarchical superstructure, and increased number of surface active sites. This novel superstructure has promising use in practical aqueous purification.« less

Biomechanical factors associated with mandibular cantilevers: analysis with three-dimensional finite element models.

PubMed

Gonda, Tomoya; Yasuda, Daiisa; Ikebe, Kazunori; Maeda, Yoshinobu

2014-01-01

Although the risks of using a cantilever to treat missing teeth have been described, the mechanisms remain unclear. This study aimed to reveal these mechanisms from a biomechanical perspective. The effects of various implant sites, number of implants, and superstructural connections on stress distribution in the marginal bone were analyzed with three-dimensional finite element models based on mandibular computed tomography data. Forces from the masseter, temporalis, and internal pterygoid were applied as vectors. Two three-dimensional finite element models were created with the edentulous mandible showing severe and relatively modest residual ridge resorption. Cantilevers of the premolar and molar were simulated in the superstructures in the models. The following conditions were also included as factors in the models to investigate changes: poor bone quality, shortened dental arch, posterior occlusion, lateral occlusion, double force of the masseter, and short implant. Multiple linear regression analysis with a forced-entry method was performed with stress values as the objective variable and the factors as the explanatory variable. When bone mass was high, stress around the implant caused by differences in implantation sites was reduced. When bone mass was low, the presence of a cantilever was a possible risk factor. The stress around the implant increased significantly if bone quality was poor or if increased force (eg, bruxism) was applied. The addition of a cantilever to the superstructure increased stress around implants. When large muscle forces were applied to a superstructure with cantilevers or if bone quality was poor, stress around the implants increased.

Seismic response evaluation of base-isolated reinforced concrete buildings under bidirectional excitation

NASA Astrophysics Data System (ADS)

Bhagat, Satish; Wijeyewickrema, Anil C.

2017-04-01

This paper reports on an investigation of the seismic response of base-isolated reinforced concrete buildings, which considers various isolation system parameters under bidirectional near-fault and far-fault motions. Three-dimensional models of 4-, 8-, and 12-story base-isolated buildings with nonlinear effects in the isolation system and the superstructure are investigated, and nonlinear response history analysis is carried out. The bounding values of isolation system properties that incorporate the aging effect of isolators are also taken into account, as is the current state of practice in the design and analysis of base-isolated buildings. The response indicators of the buildings are studied for near-fault and far-fault motions weight-scaled to represent the design earthquake (DE) level and the risk-targeted maximum considered earthquake (MCER) level. Results of the nonlinear response history analyses indicate no structural damage under DE-level motions for near-fault and far-fault motions and for MCER-level far-fault motions, whereas minor structural damage is observed under MCER-level near-fault motions. Results of the base-isolated buildings are compared with their fixed-base counterparts. Significant reduction of the superstructure response of the 12-story base-isolated building compared to the fixed-base condition indicates that base isolation can be effectively used in taller buildings to enhance performance. Additionally, the applicability of a rigid superstructure to predict the isolator displacement demand is also investigated. It is found that the isolator displacements can be estimated accurately using a rigid body model for the superstructure for the buildings considered.

Imprint of DES superstructures on the cosmic microwave background

DOE PAGES

Kovács, A.; Sánchez, C.; García-Bellido, J.; ...

2016-11-17

Here, small temperature anisotropies in the Cosmic Microwave Background can be sourced by density perturbations via the late-time integrated Sachs-Wolfe effect. Large voids and superclusters are excellent environments to make a localized measurement of this tiny imprint. In some cases excess signals have been reported. We probed these claims with an independent data set, using the first year data of the Dark Energy Survey in a different footprint, and using a different super-structure finding strategy. We identified 52 large voids and 102 superclusters at redshiftsmore » $0.2 < z < 0.65$. We used the Jubilee simulation to a priori evaluate the optimal ISW measurement configuration for our compensated top-hat filtering technique, and then performed a stacking measurement of the CMB temperature field based on the DES data. For optimal configurations, we detected a cumulative cold imprint of voids with $$\\Delta T_{f} \\approx -5.0\\pm3.7~\\mu K$$ and a hot imprint of superclusters $$\\Delta T_{f} \\approx 5.1\\pm3.2~\\mu K$$ ; this is $$\\sim1.2\\sigma$$ higher than the expected $$|\\Delta T_{f}| \\approx 0.6~\\mu K$$ imprint of such super-structures in $$\\Lambda$$CDM. If we instead use an a posteriori selected filter size ($$R/R_{v}=0.6$$), we can find a temperature decrement as large as $$\\Delta T_{f} \\approx -9.8\\pm4.7~\\mu K$$ for voids, which is $$\\sim2\\sigma$$ above $$\\Lambda$$CDM expectations and is comparable to previous measurements made using SDSS super-structure data.« less

Imprint of DES superstructures on the cosmic microwave background

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovács, A.; Sánchez, C.; García-Bellido, J.

Here, small temperature anisotropies in the Cosmic Microwave Background can be sourced by density perturbations via the late-time integrated Sachs-Wolfe effect. Large voids and superclusters are excellent environments to make a localized measurement of this tiny imprint. In some cases excess signals have been reported. We probed these claims with an independent data set, using the first year data of the Dark Energy Survey in a different footprint, and using a different super-structure finding strategy. We identified 52 large voids and 102 superclusters at redshiftsmore » $0.2 < z < 0.65$. We used the Jubilee simulation to a priori evaluate the optimal ISW measurement configuration for our compensated top-hat filtering technique, and then performed a stacking measurement of the CMB temperature field based on the DES data. For optimal configurations, we detected a cumulative cold imprint of voids with $$\\Delta T_{f} \\approx -5.0\\pm3.7~\\mu K$$ and a hot imprint of superclusters $$\\Delta T_{f} \\approx 5.1\\pm3.2~\\mu K$$ ; this is $$\\sim1.2\\sigma$$ higher than the expected $$|\\Delta T_{f}| \\approx 0.6~\\mu K$$ imprint of such super-structures in $$\\Lambda$$CDM. If we instead use an a posteriori selected filter size ($$R/R_{v}=0.6$$), we can find a temperature decrement as large as $$\\Delta T_{f} \\approx -9.8\\pm4.7~\\mu K$$ for voids, which is $$\\sim2\\sigma$$ above $$\\Lambda$$CDM expectations and is comparable to previous measurements made using SDSS super-structure data.« less

Glacistore: Understanding Late Cenozoic Glaciation and Basin Processes for the Development of Secure Large Scale Offshore CO2 Storage (North Sea).

NASA Astrophysics Data System (ADS)

Stewart, H. A.; Barrio, M.; Akhurst, M.; Aagaard, P.; Alcalde, J.; Bauer, A.; Bradwell, T.; Cavanagh, A.; Faleide, J. I.; Furre, A. K.; Haszeldine, S.; Hjelstuen, B. O.; Holloway, S.; Johansen, H.; Johnson, G.; Kuerschner, W.; Mondol, N. H.; Querendez, E.; Ringrose, P. S.; Sejrup, H. P.; Stewart, M.; Stoddart, D.; Wilkinson, M.; Zalmstra, H.

2014-12-01

The sedimentary strata of the North Sea Basin (NSB) record the glacial and interglacial history of environmental change in the Northern Hemisphere, and are a proposed location for the engineered storage of carbon dioxide (CO2) captured from power plant and industrial sources to reduce greenhouse gas emissions. These aspects interact in the geomechanical and fluid flow domain, as ice sheet dynamics change the properties of potential seal and reservoir rocks that are the prospective geological storage strata for much of Europe's captured CO2. The intensification of the global glacial-interglacial cycle at the onset of the Pleistocene (2.5-2.7 Ma) was a critical tipping-point in Earth's recent climate history. The increased severity of glaciations at the Plio-Pleistocene boundary triggered the first development of large-scale continental ice sheets in the Northern Hemisphere. The central part of the NSB preserves a unique history of the depositional record spanning at least the last 3 Ma, which also forms the overburden and seal to the underlying CO2 reservoirs. There is good evidence that these ice sheets created strong feedback loops that subsequently affected the evolution of the Quaternary climate system through complex ocean-atmosphere-cryosphere linkages. Understanding NSB dynamics, including the role of fluids in controlling compaction, cementation, and diagenetic processes in shale-dominated basins, is essential for CO2 storage site characterisation to increase understanding and confidence in secure storage. An increased understanding of the overlying sequence will inform quantitative predictions of the performance of prospective CO2 storage sites in glaciated areas in Europe and worldwide; to include improved resolution of glacial cycles (depositional and chronological framework), characterise pore fluids, flow properties of glacial landforms within the sequence (e.g. tunnel valleys) and the geomechanical effects (quantify compaction, rock stiffness, strength and stress profiles) of advancing and retreating ice on the underlying strata to verify and constrain models of glaciation. This presentation describes current work and introduces a proposal submitted to the Integrated Ocean Discovery Program (852-Pre) by the authors.

Water resources of the Raft River basin, Idaho-Utah

USGS Publications Warehouse

Nace, Raymond L.; ,

1961-01-01

Much arable land in the Raft River basin of Idaho lacks water for irrigation, and the potentially irrigable acreage far exceeds the amount that could be irrigated with the estimated total supply of water. Therefore, the amount of uncommitted water that could be intercepted and used within the basin is the limiting factor in further development of its native water supply. Water for additional irrigation might be obtained by constructing surface-storage works, by pumping ground water, or by importing surface water. Additional groundwater development is feasible. As an aid to orderly development and use of the water supplies, the report summarizes available geologic and hydrologic data and, by analysis and interpretation, derives an estimate of the recoverable water yield of the basin.

Effect of enhanced manganese oxidation in the hyporheic zone on basin-scale geochemical mass balance

USGS Publications Warehouse

Harvey, Judson W.; Fuller, Christopher C.

1998-01-01

We determined the role of the hyporheic zone (the subsurface zone where stream water and shallow groundwater mix) in enhancing microbially mediated oxidation of dissolved manganese (to form manganese precipitates) in a drainage basin contaminated by copper mining. The fate of manganese is of overall importance to water quality in Pinal Creek Basin, Arizona, because manganese reactions affect the transport of trace metals. The basin-scale role of the hyporheic zone is difficult to quantify because stream-tracer studies do not always reliably characterize the cumulative effects of the hyporheic zone. This study determined cumulative effects of hyporheic reactions in Pinal Creek basin by characterizing manganese uptake at several spatial scales (stream-reach scale, hyporheic-flow-path scale, and sediment-grain scale). At the stream-reach scale a one-dimensional stream-transport model (including storage zones to represent hyporheic flow paths) was used to determine a reach-averaged time constant for manganese uptake in hyporheic zones, 1/λs, of 1.3 hours, which was somewhat faster but still similar to manganese uptake time constants that were measured directly in centimeter-scale hyporheic flow paths (1/λh= 2.6 hours), and in laboratory batch experiments using streambed sediment (1/λ = 2.7 hours). The modeled depths of subsurface storage zones (ds = 4–17 cm) and modeled residence times of water in storage zones (ts = 3–12 min) were both consistent with direct measurements in hyporheic flow paths (dh = 0–15 cm, th = 1–25 min). There was also good agreement between reach-scale modeling and direct measurements of the percentage removal of dissolved manganese in hyporheic flow paths (fs = 8.9%, andfh = 9.3%rpar;. Manganese uptake experiments in the laboratory using sediment from Pinal Creek demonstrated (through comparison of poisoned and unpoisoned treatments) that the manganese removal process was enhanced by microbially mediated oxidation. The cumulative effect of hyporheic exchange in Pinal Creek basin was to remove approximately 20% of the dissolved manganese flowing out of the drainage basin. Our results illustrate that the cumulative significance of reactive uptake in the hyporheic zone depends on the balance between chemical reaction rates, hyporheic porewater residence time, and turnover of streamflow through hyporheic flow paths. The similarity between the hyporheic reaction timescale (1/λs ≈ 1.3 hours), and the hyporheic porewater residence timescale (ts ≈ 8 min) ensured that there was adequate time for the reaction to progress. Furthermore, it was the similarity between the turnover length for stream water flow through hyporheic flow paths (Ls = stream velocity/storage-zone exchange coefficient ≈ 1.3 km) and the length of Pinal Creek (L ≈ 7 km), which ensured that all stream water passed through hyporheic flow paths several times. As a means to generalize our findings to other sites where similar types of hydrologic and chemical information are available, we suggest a cumulative significance index for hyporheic reactions, Rs = λstsL/Ls (dimensionless); higher values indicate a greater potential for hyporheic reactions to influence geochemical mass balance. Our experience in Pinal Creek basin suggests that values of Rs > 0.2 characterize systems where hyporheic reactions are likely to influence geochemical mass balance at the drainage-basin scale.

Investigation of aquifer-system compaction in the Hueco basin, El Paso, Texas, USA

USGS Publications Warehouse

Heywood, Charles

1995-01-01

The Pleistocene geologic history of the Rio Grande valley in the Hueco basin included a cycle of sediment erosion and re-aggradation, resulting in unconformable stratification of sediment of contrasting compressibility and stress history. Since the 1950s large groundwater withdrawals have resulted in significant water-level declines and associated land subsidence. Knowledge of the magnitude and variation of specific storage is needed for developing predictive models of subsidence and groundwater flow simulations. Analyses of piezometric and extensometric data in the form of stress-strain diagrams from a 16 month period yield in situ measurements of aquifer-system compressibility across two discrete aquifer intervals. The linear elastic behaviour of the deeper interval indicates over-consolidation of basin deposits, probably resulting from deeper burial depth before the middle Pleistocene. By contrast, the shallow aquifer system displays an inelastic component, suggesting pre-consolidation stress not significantly greater than current effective stress levels for a sequence of late Pleistocene clay. Harmonic analyses of the piezometric response to earth tides in two water-level piezometers provide an independent estimate of specific storage of aquifer sands.

Collapse Mechanism Analysis in the Design of Superstructure Vehicle

NASA Astrophysics Data System (ADS)

Mohd Nor, M. K.

2016-11-01

The EU directive 2001/85/EC is an official European text which describes the specifications for “single deck class II and III vehicles” required to be approved by the regulation UN/ECE no.66 (R66). To prevent the catastrophic consequences by occupant during an accident, the Malaysian government has reinforced the same regulation upon superstructure construction. This paper discusses collapse mechanism analysis of a superstructure vehicle using a Crash D nonlinear analysis computer program based on this regulation. The analysis starts by hand calculation to define the required energy absorption by the chosen structure. Simple calculations were then performed to define the weakest collapse mechanism after undesirable collapse modes are eliminated. There are few factors highlighted in this work to pass the regulation. Using the selected cross section, Crash D simulation showed a good result. Generally, the deformation is linearly correlates to the energy absorption for the structure with low stiffness. Failure of critical members such as vertical lower side wall must be avoided to sustain safety of the passenger compartment and prevent from severe and fatal injuries to the trapped occupant.

Nonlinear analysis of collapse mechanism in superstructure vehicle

NASA Astrophysics Data System (ADS)

Nor, M. K. Mohd; Ho, C. S.; Ma'at, N.

2017-04-01

The EU directive 2001/85/EC is an official European text which describes the specifications for "single deck class II and III vehicles" required to be approved by the regulation UN/ECE no.66 (R66). To prevent the catastrophic consequences by occupant during an accident, the Malaysian government has reinforced the same regulation upon superstructure construction. This paper discusses collapse mechanism analysis of a superstructure vehicle using a Crash D nonlinear analysis computer program based on this regulation. The analysis starts by hand calculation to define the required energy absorption by the chosen structure. Simple calculations were then performed to define the weakest collapse mechanism after undesirable collapse modes are eliminated. There are few factors highlighted in this work to pass the regulation. Using the selected cross section, Crash D simulation showed a good result. Generally, the deformation is linearly correlates to the energy absorption for the structure with low stiffness. Failure of critical members such as vertical lower side wall must be avoided to sustain safety of the passenger compartment and prevent from severe and fatal injuries to the trapped occupant.

The influence of tightening sequence and method on screw preload in implant superstructures.

PubMed

Al-Sahan, Maha M; Al Maflehi, Nassr S; Akeel, Riyadh F

2014-01-01

This study evaluated the effect of six screw-tightening sequences and two tightening methods on the screw preload in implant-supported superstructures. The preload was measured using strain gauges following the screw tightening of a metal framework connected to four implants. The experiment included six sequences ([1] 1-2-3-4, [2] 4-2-3-1, [3] 4-3-1-2, [4] 1-4-2-3, [5] 2-3-4-1, and [6] 3-2-4-1), two methods (onestep, three-step), and five replications. Significant differences were found between tightening sequences and methods. In the three-step method, a higher total preload was found in sequences 2 (312 ± 85 N), 3 (246 ± 54 N), and 4 (310 ± 96 N). In the one-step method, a higher total preload was found in sequences 1 (286 ± 94 N), 5 (764 ± 142 N), and 6 (350 ± 69 N). It is concluded that the highest total screw preload was achieved when anterior implants of the superstructure were first tightened in one step, followed by posterior implants.

Bipartite electronic superstructures in the vortex core of Bi2Sr2CaCu2O8+δ

PubMed Central

Machida, T.; Kohsaka, Y.; Matsuoka, K.; Iwaya, K.; Hanaguri, T.; Tamegai, T.

2016-01-01

The central issue in the physics of cuprate superconductivity is the mutual relationship among superconductivity, pseudogap and broken-spatial-symmetry states. A magnetic field B suppresses superconductivity, providing an opportunity to investigate the competition among these states. Although various B-induced electronic superstructures have been reported, their energy, spatial and momentum-space structures are unclear. Here, we show using spectroscopic-imaging scanning tunnelling microscopy on Bi2Sr2CaCu2O8+δ that there are two distinct B-induced electronic superstructures, both being localized in the vortex core but appearing at different energies. In the low-energy range where the nodal Bogoliubov quasiparticles are well-defined, we observe the so-called vortex checkerboard that we identify as the B-enhanced quasiparticle interference pattern. By contrast, in the high-energy region where the pseudogap develops, the broken-spatial-symmetry patterns that pre-exist at B=0 T is locally enhanced in the vortex core. This evidences the competition between superconductivity and the broken-spatial-symmetry state that is associated with the pseudogap. PMID:27230420

Drying results of K-Basin fuel element 1990 (Run 1)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marschman, S.C.; Abrefah, J.; Klinger, G.S.

1998-06-01

The water-filled K-Basins in the Hanford 100-Area have been used to store N-Reactor spent nuclear fuel (SNF) since the 1970s. Because some leaks in the basins have been detected and some of the fuel is breached due to handling damage and corrosion, efforts are underway to remove the fuel elements from wet storage. An Integrated Process Strategy (IPS) has been developed to package, dry, transport, and store these metallic uranium fuels in an interim storage facility on the Hanford Site (WHC 1995). Information required to support the development of the drying processes, and the required safety analyses, is being obtainedmore » from characterization tests conducted on fuel elements removed from the K-Basins. A series of whole element drying tests (reported in separate documents, see Section 8.0) have been conducted by Pacific Northwest National Laboratory (PNNL) on several intact and damaged fuel elements recovered from both the K-East and K-West Basins. This report documents the results of the first of those tests (Run 1), which was conducted on an N-Reactor inner fuel element (1990) that had been stored underwater in the K-West Basin (see Section 2.0). This fuel element was subjected to a combination of low- and high-temperature vacuum drying treatments that were intended to mimic, wherever possible, the fuel treatment strategies of the IPS. The testing was conducted in the Whole Element Furnace Testing System, described in Section 3.0, located in the Postirradiation Testing Laboratory (PTL, 327 Building). The test conditions and methodology are given in Section 4.0, and the experimental results provided in Section 5.0. These results are further discussed in Section 6.0.« less

Mechanical Stability of Fractured Rift Basin Mudstones: from lab to basin scale

NASA Astrophysics Data System (ADS)

Zakharova, N. V.; Goldberg, D.; Collins, D.; Swager, L.; Payne, W. G.

2016-12-01

Understanding petrophysical and mechanical properties of caprock mudstones is essential for ensuring good containment and mechanical formation stability at potential CO2 storage sites. Natural heterogeneity and presence of fractures, however, create challenges for accurate prediction of mudstone behavior under injection conditions and at reservoir scale. In this study, we present a multi-scale geomechanical analysis for Mesozoic mudstones from the Newark Rift basin, integrating petropyshical core and borehole data, in situ stress measurements, and caprock stability modeling. The project funded by the U.S. Department of Energy's National Energy Technology Laboratory (NETL) focuses on the Newark basin as a representative locality for a series of the Mesozoic rift basins in eastern North America considered as potential CO2 storage sites. An extensive core characterization program, which included laboratory CT scans, XRD, SEM, MICP, porosity, permeability, acoustic velocity measurements, and geomechanical testing under a range of confining pressures, revealed large variability and heterogeneity in both petrophysical and mechanical properties. Estimates of unconfined compressive strength for these predominantly lacustrine mudstones range from 5,000 to 50,000 psi, with only a weak correlation to clay content. Thinly bedded intervals exhibit up to 30% strength anisotropy. Mineralized fractures, abundant in most formations, are characterized by compressive strength as low as 10% of matrix strength. Upscaling these observations from core to reservoir scale is challenging. No simple one-to-one correlation between mechanical and petrophyscial properties exists, and therefore, we develop multivariate empirical relationships among these properties. A large suite of geophysical logs, including new measurements of the in situ stress field, is used to extrapolate these relationships to a basin-scale geomechanical model and predict mudstone behavior under injection conditions.

New insights into hydrologic sources and sinks in the Nile Basin: A multi-source satellite data analysis

NASA Astrophysics Data System (ADS)

Senay, G. B.; Velpuri, N. M.; Bohms, S.; Demissie, Y.; Gebremichael, M.

2014-12-01

The Nile River is the longest in the world with a length of 6,800 km. However, the contrast between the length of the river or the size of the basin and the comparatively small volume of basin runoff generated is a unique feature of the Nile Basin. Due to non-availability of in-situ hydrologic data, we do not clearly understand the spatial distribution of hydrologic sources and sinks and how much they control input-output dynamics? In this study, we integrated satellite-derived precipitation, and modeled evapotranspiration data (2000-2012) to describe spatial variability of hydrologic sources and sinks in the Nile Basin. We also used long-term gridded runoff and river discharge data (1869-1984) to understand the discrepancy in the observed and expected flow along the Nile River. Results indicate that over 2000-2012 period, 4 out of 11 countries (Ethiopia, Tanzania, Kenya, and Uganda) in the Nile basin showed a positive water balance while three downstream countries (South Sudan, Sudan, and Egypt) showed a negative balance. The top three countries that contribute most to the flow are Ethiopia, Tanzania and Kenya. The study revealed that ~85% of the runoff generated in the Equatorial region is lost in an inter-station basin that includes the Sudd wetlands in South Sudan; this proportion is higher than the reported loss of 50% at the Sudd wetlands alone. The loss in runoff and flow volume at different sections of the river tend to be more than what can be explained by evaporation losses, suggesting a potential recharge to deeper aquifers that are not connected to the Nile channel systems. On the other hand, we also found that the expected average annual Nile flow at Aswan is larger (97 km3) than the reported amount (84 km3). Gravity Recovery and Climate Experiment (GRACE) mass deviation in storage data analysis showed that at annual time-scales, the Nile Basin shows storage change is substantial while over longer-time periods, it is minimal (<1% of basin precipitation). Due to the large variations of the reported Nile flow at different locations and time periods, the study recommends increased hydro-meteorological instrumentation of the basin. This study improves our understanding of the spatial dynamics of water sources and sinks in the Nile basin and identified emerging hydrologic questions that require further attention.

Demolition of Munitions Storage Area Facilities. Right Size Project 10-0192C

DTIC Science & Technology

2011-07-01

area of the Proposed Action. 3.4.2 Affected Environment Fairchild AFB is situated within the channeled scablands of the Columbia River Basin which...grebe, great blue heron, turkey vulture, Caspian tern , black tern , and osprey. The white-tailed jackrabbit, a state candidate species, is known to...Geography The MSA is located in the Upper Columbia River Basin Basalt Geomorphic Province and lies within the Latah Creek watershed. The landtype is

Diffusion mechanism in the sodium-ion battery material sodium cobaltate.

PubMed

Willis, T J; Porter, D G; Voneshen, D J; Uthayakumar, S; Demmel, F; Gutmann, M J; Roger, M; Refson, K; Goff, J P

2018-02-16

High performance batteries based on the movement of Li ions in Li x CoO 2 have made possible a revolution in mobile electronic technology, from laptops to mobile phones. However, the scarcity of Li and the demand for energy storage for renewables has led to intense interest in Na-ion batteries, including structurally-related Na x CoO 2 . Here we have determined the diffusion mechanism for Na 0.8 CoO 2 using diffuse x-ray scattering, quasi-elastic neutron scattering and ab-initio molecular dynamics simulations, and we find that the sodium ordering provides diffusion pathways and governs the diffusion rate. Above T ~ 290 K the so-called partially disordered stripe superstructure provides channels for quasi-1D diffusion, and melting of the sodium ordering leads to 2D superionic diffusion above T ~ 370 K. We obtain quantitative agreement between our microscopic study of the hopping mechanism and bulk self-diffusion measurements. Our approach can be applied widely to other Na- or Li-ion battery materials.

Intermixing behaviors of PCBM with CuPc on Au(1 1 1) surface

NASA Astrophysics Data System (ADS)

Masui, Akane; Sakaue, Hiroyuki; Takahagi, Takayuki; Suzuki, Hitoshi

2016-09-01

The behavior of phenyl-C61-butyric acid methyl ester (PCBM) and copper-phthalocyanine (CuPc) on a Au(1 1 1) surface was investigated using scanning tunneling microscopy (STM). When CuPc was deposited in addition to PCBM it entered and disturbed the regularly spaced double row superstructure of the PCBM molecules. PCBM intermixed with CuPc to form a new square shaped superstructure that consisted of six to eight PCBM molecules with a CuPc molecule in its center. The intermixing of these materials that was observed indicated that they possessed an attractive interaction.

First-principles study of giant thermoelectric power in incommensurate TlInSe2

NASA Astrophysics Data System (ADS)

Ishikawa, M.; Nakayama, T.; Wakita, K.; Shim, Y. G.; Mamedov, N.

2018-04-01

Ternary thallium compound TlInSe2 exhibits a giant Seebeck effect below around 410 K, where Tl atoms form one dimensional incommensurate (IC) arrays. To clarify the origin of large thermoelectric power in the IC phase, the electronic properties of Tl-atom super-structured TlInSe2 were studied using the first-principles calculations. It was shown that the super-structures induce strong binding states between Se-p orbitals in the nearest neighboring layers and produce large density of states near lower conduction bands, which might be one of the origins to produce large thermoelectric power.

Superstructures and Electronic Properties of Manganese-Phthalocyanine Molecules on Au(110) from Submonolayer Coverage to Ultrathin Molecular Films.

PubMed

Topyła, M; Néel, N; Kröger, J

2016-07-12

The adsorption of manganese-phthalocyanine molecules on Au(110) was investigated using a low-temperature scanning tunneling microscope. A rich variety of commensurate superstructures was observed upon increasing the molecule coverage from submonolayers to ultrathin films. All structures were associated with reconstructions of the Au(110) substrate. Molecules adsorbed in the second molecular layer exhibited negative differential conductance occurring symmetrically around zero bias voltage. A double-barrier tunneling model rationalized this observation in terms of a peaked molecular resonance at the Fermi energy together with a voltage drop across the molecular film.

Geologic framework for the national assessment of carbon dioxide storage resources: Hanna, Laramie, and Shirley Basins, Wyoming: Chapter C in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Merrill, Matthew D.; Covault, Jacob A.; Craddock, William H.; Slucher, Ernie R.; Warwick, Peter D.; Blondes, Madalyn S.; Gosai, Mayur A.; Freeman, P.A.; Cahan, Steven M.; Lohr, Celeste D.; Warwick, Peter D.; Corum, Margo D.

2012-01-01

The 2007 Energy Independence and Security Act (Public Law 110-140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO2). The methodology used for the national CO2 assessment is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of twelve storage assessment units (SAUs) in six separate packages of sedimentary rock within the Hanna, Laramie, and Shirley Basins of Wyoming. It focuses on the particular characteristics, specified in the methodology, that influence the potential CO2 storage resource in those SAUs. Specific descriptions of SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU, such as depth to top, gross thickness, net porous thickness, porosity, permeability, groundwater quality, and structural reservoir traps are provided to illustrate geologic factors critical to the assessment. Although assessment results are not contained in this report, the geologic information included herein will be employed, as specified in the methodology, to calculate a statistical Monte Carlo-based distribution of potential storage space in the various SAUs. Figures in this report show SAU boundaries and cell maps of well penetrations through the sealing unit into the top of the storage formation. Cell maps show the number of penetrating wells within one square mile and are derived from interpretations of incompletely attributed well data in a digital compilation that is known not to include all drilling. The USGS does not expect to know the location of all wells and cannot guarantee the amount of drilling through specific formations in any given cell shown on cell maps.

Credit PSR. This photograph displays the south and east facades ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Credit PSR. This photograph displays the south and east facades of the storage facility as seen when looking to the west northwest (288°). The concrete pit in the foreground is a catch basin designed to hold run-off from spilled oxidizers or clean-up operations, thus preventing them from contaminating the soil - Jet Propulsion Laboratory Edwards Facility, Solid Oxidizer Storage, Edwards Air Force Base, Boron, Kern County, CA

CO 2 Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frailey, Scott M.; Krapac, Ivan G.; Damico, James R.

2012-03-30

The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO 2) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO 2 storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO 2 flooding.

Sedimentation Survey of Lago Toa Vaca, Puerto Rico, June-July 2002

USGS Publications Warehouse

Soler-López, Luis R.

2004-01-01

The Lago Toa Vaca dam is located in the municipality of Villalba in southern Puerto Rico, and is owned and operated by the Puerto Rico Aqueduct and Sewer Authority. Construction was completed in 1972 as the first phase of a multi-purpose project that contemplated four possible diversions from other basins to mitigate the rapid storage capacity loss of Lago Guayabal, located immediately downstream of the Toa Vaca dam. The latter phases of the intra-basin diversions were cancelled, and currently, the reservoir receives runoff from only 56.8 square kilometers of its drainage area. Lago Toa Vaca reservoir when constructed was to be used for irrigation of croplands in the southern coastal plain. The reservoir had an original storage capacity of 68.94 million cubic meters. Sedimentation has reduced the storage capacity by only 7 percent between 1972 and 2002 to 64.08 million cubic meters. This represents a long-term sedimentation rate of about 162,000 cubic meters per year. Based on the 2002 sedimentation survey, Lago Toa Vaca has a sediment trapping efficiency of about 98 percent and a drainage area-normalized sedimentation rate of about 3,086 cubic meters per square kilometer per year between 1972 and 2002. At the current long-term sedimentation rate the reservoir would lose its storage capacity by the year 2400.

Confined aquifer head measurements and storage properties in the San Luis Valley, Colorado, from spaceborne InSAR observations

NASA Astrophysics Data System (ADS)

Chen, Jingyi; Knight, Rosemary; Zebker, Howard A.; Schreüder, Willem A.

2016-05-01

Interferometric Synthetic Aperture Radar (InSAR), a remote sensing technique for measuring centimeter-level surface deformation, is used to estimate hydraulic head in the confined aquifer of the San Luis Valley (SLV), Colorado. Reconstructing head measurements from InSAR in agricultural regions can be difficult, as InSAR phase data are often decorrelated due to vegetation growth. Analysis of 17 L-band ALOS PALSAR scenes, acquired between January 2007 and March 2011, demonstrates that comprehensive InSAR deformation measurements can be recovered over the vegetated groundwater basin with an improved processing strategy. Local skeletal storage coefficients and time delays between the head change and deformation are estimated through a joint InSAR-well data analysis. InSAR subsidence estimates are transformed to head changes with finer temporal and spatial resolution than is possible using existing well records alone. Both InSAR and well data suggest that little long-term water-storage loss occurred in the SLV over the study period and that inelastic compaction was negligible. The seasonal head variations derived from InSAR are consistent with the existing well data at most locations where confined aquifer pumping activity dominates. Our results demonstrate the advantages of InSAR measurements for basin-wide characterization of aquifer storage properties and groundwater levels over agricultural regions.

Assimilation of GRACE Terrestrial Water Storage Observations into a Land Surface Model for the Assessment of Regional Flood Potential

NASA Technical Reports Server (NTRS)

Reager, John T.; Thomas, Alys C.; Sproles, Eric A.; Rodell, Matthew; Beaudoing, Hiroko K.; Li, Bailing; Famiglietti, James S.

2015-01-01

We evaluate performance of the Catchment Land Surface Model (CLSM) under flood conditions after the assimilation of observations of the terrestrial water storage anomaly (TWSA) from NASA's Gravity Recovery and Climate Experiment (GRACE). Assimilation offers three key benefits for the viability of GRACE observations to operational applications: (1) near-real time analysis; (2) a downscaling of GRACE's coarse spatial resolution; and (3) state disaggregation of the vertically-integrated TWSA. We select the 2011 flood event in the Missouri river basin as a case study, and find that assimilation generally made the model wetter in the months preceding flood. We compare model outputs with observations from 14 USGS groundwater wells to assess improvements after assimilation. Finally, we examine disaggregated water storage information to improve the mechanistic understanding of event generation. Validation establishes that assimilation improved the model skill substantially, increasing regional groundwater anomaly correlation from 0.58 to 0.86. For the 2011 flood event in the Missouri river basin, results show that groundwater and snow water equivalent were contributors to pre-event flood potential, providing spatially-distributed early warning information.

Geologic framework for the national assessment of carbon dioxide storage resources: Bighorn Basin, Wyoming and Montana: Chapter A in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Covault, Jacob A.; Buursink, Mark L.; Craddock, William H.; Merrill, Matthew D.; Blondes, Madalyn S.; Gosai, Mayur A.; Freeman, P.A.; Warwick, Peter D.; Corum, Margo D.

2012-01-01

This report identifies and contains geologic descriptions of twelve storage assessment units (SAUs) in six separate packages of sedimentary rocks within the Bighorn Basin of Wyoming and Montana and focuses on the particular characteristics, specified in the methodology, that influence the potential CO2 storage resource in those SAUs. Specific descriptions of the SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU such as depth to top, gross thickness, net porous thickness, porosity, permeability, groundwater quality, and structural reservoir traps are provided to illustrate geologic factors critical to the assessment. Although assessment results are not contained in this report, the geologic information included here will be employed, as specified in the methodology of earlier work, to calculate a statistical Monte Carlo-based distribution of potential storage space in the various SAUs. Figures in this report show SAU boundaries and cell maps of well penetrations through the sealing unit into the top of the storage formation. Wells sharing the same well borehole are treated as a single penetration. Cell maps show the number of penetrating wells within one square mile and are derived from interpretations of incompletely attributed well data, a digital compilation that is known not to include all drilling. The USGS does not expect to know the location of all wells and cannot guarantee the amount of drilling through specific formations in any given cell shown on cell maps.

Eco-hydrological Responses to Soil and Water Conservation in the Jinghe River Basin

NASA Astrophysics Data System (ADS)

Peng, H.; Jia, Y.; Qiu, Y.

2011-12-01

The Jinghe River Basin is one of the most serious soil erosion areas in the Loess Plateau. Many measures of soil and water conservation were applied in the basin. Terrestrial ecosystem model BIOME-BGC and distributed hydrological model WEP-L were used to build eco-hydrological model and verified by field observation and literature values. The model was applied in the Jinghe River Basin to analyze eco-hydrological responses under the scenarios of vegetation type change due to soil and water conservation polices. Four scenarios were set under the measures of conversion of cropland to forest, forestation on bare land, forestation on slope wasteland and planting grass on bare land. Analysis results show that the soil and water conservation has significant effects on runoff and the carbon cycle in the Jinghe River Basin: the average annual runoff would decrease and the average annual NPP and carbon storage would increase. Key words: soil and water conservation; conversion of cropland to forest; eco-hydrology response; the Jinghe River Basin

The visual and radiological inspection of a pipeline using a teleoperated pipe crawler

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fogle, R.F.; Kuelske, K.; Kellner, R.A.

1996-07-01

In the 1950s the Savannah River Site built an open, unlined retention basin for temporary storage of potentially radionuclide-contaminated cooling water form a chemical separations process and storm water drainage from a nearby waste management facility which stored large quantities of nuclear fission by-products in carbon steel tanks. An underground process pipeline lead to the basin. Once the closure of the basin in 1972, further assessment has been required. A visual and radiological inspection of the pipeline was necessary to aid in the decision about further remediation. This article describes the inspection using a teleoperated pipe crawler. 5 figs.

Individual and cumulative effects of agriculture, forestry and metal mining activities on the metal and phosphorus content of fluvial fine-grained sediment; Quesnel River Basin, British Columbia, Canada.

PubMed

Smith, Tyler B; Owens, Philip N

2014-10-15

The impact of agriculture, forestry and metal mining on the quality of fine-grained sediment (<63 μm) was investigated in the Quesnel River Basin (QRB) (~11,500 km(2)) in British Columbia, Canada. Samples of fine-grained sediment were collected monthly during the snow-free season in 2008 using time-integrated samplers at replicate sites representative of agriculture, forestry and mining activities in the basin (i.e. "impacted" sites). Samples were also collected from replicate reference sites and also from the main stem of the Quesnel River at the downstream confluence with the Fraser River. Generally, metal(loid) and phosphorus (P) concentrations for "impacted" sites were greater than for reference sites. Furthermore, concentrations of copper (forestry and mining sites), manganese (agriculture and forestry sites) and selenium (agriculture, forestry and mining sites) exceeded upper sediment quality guideline (SQG) thresholds. These results suggest that agriculture, forestry and metal mining activities are having an influence on the concentrations of sediment-associated metal(loid)s and P in the Quesnel basin. Metal(loid) and P concentrations of sediment collected from the downstream site were not significantly greater than values for the reference sites, and were typically lower than the values for the impacted sites. This suggests that the cumulative effects of agriculture, forestry and mining activities in the QRB are presently not having a measureable effect at the river basin-scale. The lack of a cumulative effect at the basin-scale is thought to reflect: (i) the relatively recent occurrence of land use disturbances in this basin; (ii) the dominance of sediment contributions from natural forest and agriculture; and (iii) the potential for storage of contaminants on floodplains and other storage elements between the locations of disturbance activities and the downstream sampling site, which may be attenuating the disturbance signal. Copyright © 2014 Elsevier B.V. All rights reserved.

Hydrogeology, water resources, and water budget of the upper Rio Hondo Basin, Lincoln County, New Mexico, 2010

USGS Publications Warehouse

Darr, Michael J.; McCoy, Kurt J.; Rattray, Gordon W.; Durall, Roger A.

2014-01-01

The upper Rio Hondo Basin occupies a drainage area of 585 square miles in south-central New Mexico and comprises three general hydrogeologic terranes: the higher elevation “Mountain Block,” the “Central Basin” piedmont area, and the lower elevation “Hondo Slope.” As many as 12 hydrostratigraphic units serve as aquifers locally and form a continuous aquifer on the regional scale. Streams and aquifers in the basin are closely interconnected, with numerous gaining and losing stream reaches across the study area. In general, the aquifers are characterized by low storage capacity and respond to short-term and long-term variations in recharge with marked water-level fluctuations on short (days to months) and long (decadal) time scales. Droughts and local groundwater withdrawals have caused marked water-table declines in some areas, whereas periodically heavy monsoons and snowmelt events have rapidly recharged aquifers in some areas. A regional-scale conceptual water budget was developed for the study area in order to gain a basic understanding of the magnitude of the various components of input, output, and change in storage. The primary input is watershed yield from the Mountain Block terrane, supplying about 38,200 to 42,300 acre-feet per year (acre-ft/yr) to the basin, as estimated by comparing the residual of precipitation and evapotranspiration with local streamgage data. Streamflow from the basin averaged about 21,200 acre-ft/yr, and groundwater output left the basin at an estimated 2,300 to 5,700 acre-ft/yr. The other major output (about 13,500 acre-ft/yr) was by public water supply, private water supply, livestock, commercial and industrial uses, and the Bonito Pipeline. The residual in the water budget, the difference between the totals of the input and output terms or the potential change in storage, ranged from -2,200 acre-ft/yr to +5,300 acre-ft/yr. There is a high degree of variability in precipitation and consequently in the water supply; small variations in annual precipitation can result in major changes in overall watershed yield. Changing water-use patterns, concentrated areas of groundwater withdrawal, and variations in precipitation have created localized areas where water-table declines and diminished surface flow are of concern.

Vegetation function and non-uniqueness of the hydrological response

NASA Astrophysics Data System (ADS)

Ivanov, V. Y.; Fatichi, S.; Kampf, S. K.; Caporali, E.

2012-04-01

Through local moisture uptake vegetation exerts seasonal and longer-term impacts on the watershed hydrological response. However, the role of vegetation may go beyond the conventionally implied and well-understood "sink" function in the basin soil moisture storage equation. We argue that vegetation function imposes a "homogenizing" effect on pre-event soil moisture spatial storage, decreasing the likelihood that a rainfall event will result in a topographically-driven redistribution of soil water and the consequent formation of variable source areas. In combination with vegetation temporal dynamics, this may lead to the non-uniqueness of the hydrological response with respect to the mean basin wetness. This study designs a set of relevant numerical experiments carried out with two physically-based models; one of the models, HYDRUS, resolves variably saturated subsurface flow using a fully three-dimensional formulation, while the other model, tRIBS+VEGGIE, uses a one-dimensional formulation applied in a quasi-three-dimensional framework in combination with the model of vegetation dynamics. We demonstrate that (1) vegetation function modifies spatial heterogeneity in moisture spatial storage by imposing different degrees of subsurface flow connectivity; explore mechanistically (2) how and why a basin with the same mean soil moisture can have distinctly different spatial soil moisture distributions; and demonstrate (2) how these distinct moisture distributions result in a hysteretic runoff response to precipitation. Furthermore, the study argues that near-surface soil moisture is an insufficient indicator of the initial moisture state of a catchment with the implication of its limited effect on hydrological predictability.

Water resources management in the Ganges Basin: a comparison of three strategies for conjunctive use of groundwater and surface water

USGS Publications Warehouse

Khan, Mahfuzur R.; Voss, Clifford I.; Yu, Winston; Michael, Holly A.

2014-01-01

The most difficult water resources management challenge in the Ganges Basin is the imbalance between water demand and seasonal availability. More than 80 % of the annual flow in the Ganges River occurs during the 4-month monsoon, resulting in widespread flooding. During the rest of the year, irrigation, navigation, and ecosystems suffer because of water scarcity. Storage of monsoonal flow for utilization during the dry season is one approach to mitigating these problems. Three conjunctive use management strategies involving subsurface water storage are evaluated in this study: Ganges Water Machine (GWM), Pumping Along Canals (PAC), and Distributed Pumping and Recharge (DPR). Numerical models are used to determine the efficacy of these strategies. Results for the Indian State of Uttar Pradesh (UP) indicate that these strategies create seasonal subsurface storage from 6 to 37 % of the yearly average monsoonal flow in the Ganges exiting UP over the considered range of conditions. This has clear implications for flood reduction, and each strategy has the potential to provide irrigation water and to reduce soil waterlogging. However, GWM and PAC require significant public investment in infrastructure and management, as well as major shifts in existing water use practices; these also involve spatially-concentrated pumping, which may induce land subsidence. DPR also requires investment and management, but the distributed pumping is less costly and can be more easily implemented via adaptation of existing water use practices in the basin.

Rio Grande valley Colorado new Mexico and Texas

USGS Publications Warehouse

Ellis, Sherman R.; Levings, Gary W.; Carter, Lisa F.; Richey, Steven F.; Radell, Mary Jo

1993-01-01

Two structural settings are found in the study unit: alluvial basins and bedrock basins. The alluvial basins can have through-flowing surface water or be closed basins. The discussion of streamflow and water quality for the surface-water system is based on four river reaches for the 750 miles of the main stem. the quality of the ground water is affected by both natural process and human activities and by nonpoint and point sources. Nonpoint sources for surface water include agriculture, hydromodification, and mining operations; point sources are mainly discharge from wastewater treatment plants. Nonpoint sources for ground water include agriculture and septic tanks and cesspools; point sources include leaking underground storage tanks, unlined or manure-lined holding ponds used for disposal of dairy wastes, landfills, and mining operations.

National assessment of geologic carbon dioxide storage resources: allocations of assessed areas to Federal lands

USGS Publications Warehouse

Buursink, Marc L.; Cahan, Steven M.; Warwick, Peter D.

2015-01-01

Following the geologic basin-scale assessment of technically accessible carbon dioxide storage resources in onshore areas and State waters of the United States, the U.S. Geological Survey estimated that an area of about 130 million acres (or about 200,000 square miles) of Federal lands overlies these storage resources. Consequently, about 18 percent of the assessed area associated with storage resources is allocated to Federal land management. Assessed areas are allocated to four other general land-ownership categories as follows: State lands about 4.5 percent, Tribal lands about 2.4 percent, private and other lands about 72 percent, and offshore areas about 2.6 percent.

Electrochemical Behaviour and Galvanic Effects of Titanium Implants Coupled to Metallic Suprastructures in Artificial Saliva

PubMed Central

Mellado-Valero, Ana; Igual Muñoz, Anna; Guiñón Pina, Virginia

2018-01-01

The aim of the present study is to analyze the electrochemical behavior of five different dental alloys: two cobalt-chromium alloys (CoCr and CoCr-c), one nickel-chromium-titanium alloy (NiCrTi), one gold-palladium alloy (Au), and one titanium alloy (Ti6Al4V), and the galvanic effect when they are coupled to titanium implants (TiG2). It was carried out by electrochemical techniques (open circuit measurements, potentiodynamic curves and Zero-Resistance Ammetry) in artificial saliva (AS), with and without fluorides in different acidic conditions. The studied alloys are spontaneously passivated, but NiCrTi alloy has a very narrow passive domain and losses its passivity in presence of fluorides, so is not considered as a good option for implant superstructures. Variations of pH from 6.5 to 3 in artificial saliva do not change the electrochemical behavior of Ti, Ti6Al4V, and CoCr alloys, and couples, but when the pH of the artificial saliva is below 3.5 and the fluoride content is 1000 ppm Ti and Ti6Al4V starts actively dissolving, and CoCr-c superstructures coupled to Ti show acceleration of corrosion due to galvanic effects. Thus, NiCrTi is not recommended for implant superstructures because of risk of Ni ion release to the body, and fluorides should be avoided in acidic media because Ti, Ti6Al4V, and CoCr-c superstructures show galvanic corrosion. The best combinations are Ti/Ti6Al4V and Ti/CoCr as alternative of noble gold alloys. PMID:29361767

Electrochemical Behaviour and Galvanic Effects of Titanium Implants Coupled to Metallic Suprastructures in Artificial Saliva.

PubMed

Mellado-Valero, Ana; Muñoz, Anna Igual; Pina, Virginia Guiñón; Sola-Ruiz, Ma Fernanda

2018-01-22

The aim of the present study is to analyze the electrochemical behavior of five different dental alloys: two cobalt-chromium alloys (CoCr and CoCr-c), one nickel-chromium-titanium alloy (NiCrTi), one gold-palladium alloy (Au), and one titanium alloy (Ti6Al4V), and the galvanic effect when they are coupled to titanium implants (TiG2). It was carried out by electrochemical techniques (open circuit measurements, potentiodynamic curves and Zero-Resistance Ammetry) in artificial saliva (AS), with and without fluorides in different acidic conditions. The studied alloys are spontaneously passivated, but NiCrTi alloy has a very narrow passive domain and losses its passivity in presence of fluorides, so is not considered as a good option for implant superstructures. Variations of pH from 6.5 to 3 in artificial saliva do not change the electrochemical behavior of Ti, Ti6Al4V, and CoCr alloys, and couples, but when the pH of the artificial saliva is below 3.5 and the fluoride content is 1000 ppm Ti and Ti6Al4V starts actively dissolving, and CoCr-c superstructures coupled to Ti show acceleration of corrosion due to galvanic effects. Thus, NiCrTi is not recommended for implant superstructures because of risk of Ni ion release to the body, and fluorides should be avoided in acidic media because Ti, Ti6Al4V, and CoCr-c superstructures show galvanic corrosion. The best combinations are Ti/Ti6Al4V and Ti/CoCr as alternative of noble gold alloys.

Characteristics of Latrines in Central Tanzania and Their Relation to Fly Catches

PubMed Central

Irish, Seth; Aiemjoy, Kristen; Torondel, Belen; Abdelahi, Faraji; Ensink, Jeroen H. J.

2013-01-01

The disposal of human excreta in latrines is an important step in reducing the transmission of diarrhoeal diseases. However, in latrines, flies can access the latrine contents and serve as a mechanical transmitter of diarrhoeal pathogens. Furthermore, the latrine contents can be used as a breeding site for flies, which may further contribute to disease transmission. Latrines do not all produce flies, and there are some which produce only a few, while others can produce thousands. In order to understand the role of the latrine in determining this productivity, a pilot study was conducted, in which fifty latrines were observed in and around Ifakara, Tanzania. The characteristics of the latrine superstructure, use of the latrine, and chemical characteristics of pit latrine contents were compared to the numbers of flies collected in an exit trap placed over the drop hole in the latrine. Absence of a roof was found to have a significant positive association (t=3.17, p=0.003) with the total number of flies collected, and temporary superstructures, particularly as opposed to brick superstructures (z=4.26, p<0.001), and increased total solids in pit latrines (z=2.57, p=0.01) were significantly associated with increased numbers of blowflies leaving the latrine. The number of larvae per gram was significantly associated with the village from which samples were taken, with the largest difference between two villages outside Ifakara (z=2.12, p=0.03). The effect of latrine superstructure (roof, walls) on fly production may indicate that improvements in latrine construction could result in decreases in fly populations in areas where they transmit diarrhoeal pathogens. PMID:23874475

Exploring the water storage changes in the largest lake (Selin Co) over the Tibetan Plateau during 2003-2012 from a basin-wide hydrological modeling

NASA Astrophysics Data System (ADS)

Zhou, Jing; Wang, Lei; Zhang, Yinsheng; Guo, Yanhong

2016-04-01

Lake water storage change (DSw) is an important indicator of the hydrologic cycle and greatly influences lake expansion/shrinkage over the Tibetan Plateau (TP). Accurate estimation of DSw will contribute to improved understanding of lake variations in the TP. Based on a water balance, this study explored the variations of DSw for the Lake Selin Co (the largest closed lake on the TP) during 2003-2012 using the Water and Energy Budget-based Distributed Hydrological Model (WEB-DHM) together with two different evapotranspiration (ET) algorithms (the Penman-Monteith method and a simple sublimation estimation approach for water area in unfrozen and frozen period). The contributions of basin discharge and climate causes to the DSw are also quantitatively analyzed. The results showed that WEB-DHM could well reproduce daily discharge, the spatial pattern, and basin-averaged values of MODIS land surface temperature (LST) during nighttime and daytime. Compared with the ET reference values estimated from the basin-wide water balance, our ET estimates showed better performance than three global ET products in reproducing basin-averaged ET. The modeled ET at point scale matches well with short-term in situ daily measurements (RMSE=0.82 mm/d). Lake inflows and precipitation over the water area had stronger relationships with DSw in the warm season and monthly scale, whereas evaporation from the water area had remarkable effects on DSw in the cold season. The total contribution of the three factors to DSw was about 90%, and accounting for 49.5%, 22.1%, and 18.3%, respectively.

Estimation of surface water storage in the Congo Basin

NASA Astrophysics Data System (ADS)

O'Loughlin, F.; Neal, J. C.; Schumann, G.; Beighley, E.; Bates, P. D.

2015-12-01

For many large river basins, especially in Africa, the lack of access to in-situ measurements, and the large areas involved, make modelling of water storage and runoff difficult. However, remote sensing datasets are useful alternative sources of information, which overcome these issues. In this study, we focus on the Congo Basin and, in particular, the cuvette central. Despite being the second largest river basin on earth and containing a large percentage of the world's tropical wetlands and forest, little is known about this basin's hydrology. Combining discharge estimates from in-situ measurements and outputs from a hydrological model, we build the first large-scale hydrodynamic model for this region to estimate the volume of water stored in the corresponding floodplains and to investigate how important these floodplains are to the behaviour of the overall system. This hydrodynamic model covers an area over 1.6 million square kilometres and 13 thousand kilometres of rivers and is calibrated to water surface heights at 33 virtual gauging stations obtained from ESA's Envisat satellite. Our results show that the use of different sources of discharge estimations and calibration via Envisat observations can produce accurate water levels and downstream discharges. Our model produced un-biased (bias =-0.08 m), sub-metre Root Mean Square Error (RMSE =0.862 m) with a Nash-Sutcliffe efficiency greater than 80% (NSE =0.81). The spatial-temporal variations in our simulated inundated areas are consistent with the pattern obtained from satellites. Overall, we find a high correlation coefficient (R =0.88) between our modelled inundated areas and those estimated from satellites.

Decadal surface water quality trends under variable climate, land use, and hydrogeochemical setting in Iowa, USA

USGS Publications Warehouse

Green, Christopher T.; Bekins, Barbara A.; Kalkhoff, Stephen J.; Hirsch, Robert M.; Liao, Lixia; Barnes, Kimberlee K.

2014-01-01

Understanding how nitrogen fluxes respond to changes in agriculture and climate is important for improving water quality. In the midwestern United States, expansion of corn cropping for ethanol production led to increasing N application rates in the 2000s during a period of extreme variability of annual precipitation. To examine the effects of these changes, surface water quality was analyzed in 10 major Iowa Rivers. Several decades of concentration and flow data were analyzed with a statistical method that provides internally consistent estimates of the concentration history and reveals flow-normalized trends that are independent of year-to-year streamflow variations. Flow-normalized concentrations of nitrate+nitrite-N decreased from 2000 to 2012 in all basins. To evaluate effects of annual discharge and N loading on these trends, multiple conceptual models were developed and calibrated to flow-weighted annual concentrations. The recent declining concentration trends can be attributed to both very high and very low discharge in the 2000s and to the long (e.g., 8 year) subsurface residence times in some basins. Dilution of N and depletion of stored N occurs in years with high discharge. Reduced N transport and increased N storage occurs in low-discharge years. Central Iowa basins showed the greatest reduction in flow-normalized concentrations, likely because of smaller storage volumes and shorter residence times. Effects of land-use changes on the water quality of major Iowa Rivers may not be noticeable for years or decades in peripheral basins of Iowa, and may be obscured in the central basins where extreme flows strongly affect annual concentration trends.

Simulation of blue and green water resources in the Wei River basin, China

NASA Astrophysics Data System (ADS)

Xu, Z.; Zuo, D.

2014-09-01

The Wei River is the largest tributary of the Yellow River in China and it is suffering from water scarcity and water pollution. In order to quantify the amount of water resources in the study area, a hydrological modelling approach was applied by using SWAT (Soil and Water Assessment Tool), calibrated and validated with SUFI-2 (Sequential Uncertainty Fitting program) based on river discharge in the Wei River basin (WRB). Sensitivity and uncertainty analyses were also performed to improve the model performance. Water resources components of blue water flow, green water flow and green water storage were estimated at the HRU (Hydrological Response Unit) scales. Water resources in HRUs were also aggregated to sub-basins, river catchments, and then city/region scales for further analysis. The results showed that most parts of the WRB experienced a decrease in blue water resources between the 1960s and 2000s, with a minimum value in the 1990s. The decrease is particularly significant in the most southern part of the WRB (Guanzhong Plain), one of the most important grain production basements in China. Variations of green water flow and green water storage were relatively small on the spatial and temporal dimensions. This study provides strategic information for optimal utilization of water resources and planning of cultivating seasons in the Wei River basin.

Monetizing Leakage Risk of Geologic CO2 Storage using Wellbore Permeability Frequency Distributions

NASA Astrophysics Data System (ADS)

Bielicki, Jeffrey; Fitts, Jeffrey; Peters, Catherine; Wilson, Elizabeth

2013-04-01

Carbon dioxide (CO2) may be captured from large point sources (e.g., coal-fired power plants, oil refineries, cement manufacturers) and injected into deep sedimentary basins for storage, or sequestration, from the atmosphere. This technology—CO2 Capture and Storage (CCS)—may be a significant component of the portfolio of technologies deployed to mitigate climate change. But injected CO2, or the brine it displaces, may leak from the storage reservoir through a variety of natural and manmade pathways, including existing wells and wellbores. Such leakage will incur costs to a variety of stakeholders, which may affect the desirability of potential CO2 injection locations as well as the feasibility of the CCS approach writ large. Consequently, analyzing and monetizing leakage risk is necessary to develop CCS as a viable technological option to mitigate climate change. Risk is the product of the probability of an outcome and the impact of that outcome. Assessment of leakage risk from geologic CO2 storage reservoirs requires an analysis of the probabilities and magnitudes of leakage, identification of the outcomes that may result from leakage, and an assessment of the expected economic costs of those outcomes. One critical uncertainty regarding the rate and magnitude of leakage is determined by the leakiness of the well leakage pathway. This leakiness is characterized by a leakage permeability for the pathway, and recent work has sought to determine frequency distributions for the leakage permeabilities of wells and wellbores. We conduct a probabilistic analysis of leakage and monetized leakage risk for CO2 injection locations in the Michigan Sedimentary Basin (USA) using empirically derived frequency distributions for wellbore leakage permeabilities. To conduct this probabilistic risk analysis, we apply the RISCS (Risk Interference of Subsurface CO2 Storage) model (Bielicki et al, 2013a, 2012b) to injection into the Mt. Simon Sandstone. RISCS monetizes leakage risk by combining 3D geospatial data with fluid-flow simulations from the ELSA (Estimating Leakage Semi-Analytically) model (e.g., Celia and Nordbotten, 2006) and the Leakage Impact Valuation (LIV) method (Pollak et al, 2013; Bielicki et al, 2013). We extend RISCS to iterate ELSA semi-analytic modeling simulations by drawing values from the frequency distribution of leakage permeabilities. The iterations assign these values to existing wells in the basin, and the probabilistic risk analysis thus incorporates the uncertainty of the extent of leakage. We show that monetized leakage risk can vary significantly over tens of kilometers, and we identify "hot spots" favorable to CO2 injection based on the monetized leakage risk for each potential location in the basin.

Partitioning of the water budget in the main river basins in High Mountain Asia with GRACE, model output, and other observations.

NASA Astrophysics Data System (ADS)

Velicogna, I.; Ciraci, E.; Grogan, D. S.; Lammers, R. B.

2017-12-01

Access to freshwater is important as world populations grow, especially in High Mountain Asia, where glaciers are a significant component of the freshwater resources, particularly in summer. Glaciers are sensitive to climate perturbations and affected by climate change. Our understanding of the contribution of glacier runoff to specific watersheds, and projections of glacier runoff in a warming climate, are critical to inform decisions, management and policy development. Here, we quantify changes in glacier mass balance in HMA using GRACE data and determine their contribution to river basin hydrology. We use GRACE data to estimate the HMA glacier mass mas balance and compare the results with changes in total water storage (TWS) for the major watersheds in the HMA regions. We designed ad-hoc mascon configurations to calculate the upstream glacier change in mass balance and contribution to major river basins water supply, determined appropriate corrections and uncertainties for the signal and evaluated the results via comparison with the Water Balance Model (WBM) output and other data (re-analysis data and satellite-derived precipitation and evapotranspiration). Most of the glacier loss is from the Himalaya region (Himalaya, Hengduan Shan S and E Tibet), whereas the western sectors (E and W Tien Shan; and Hindu Kush, Karakoram, W Kunlun, Pamir, Hissar Alay) experienced smaller losses but with larger interannual variability driven by changes in the westerly-driven winter precipitation. For the Indus basin, to evaluate the glacier contribution to the total water budget, we examine the contribution of the upper basin to the lower basin TWS change. Over the Upper Indus basin, we find that the seasonal decline in total water storage between May and September averages 88 Gt during 2002-2012. TRMM cumulative precipitation amounts to 119 Gt, leaving a runoff and evapotranspiration component of 207 Gt. This estimate compares well with an estimate for the WBM modeled runoff of 178 Gt and ET from remote sensing observations. We use these upper basin estimates to close the water budget in the downstream basin using GRACE TWS in conjunction with ancillary data from modeled and observed evapotranspiration, precipitation and runoff. We apply a similar methodology to other major basins. This work was conducted under a NASA contract.

Simulation of groundwater storage changes in the eastern Pasco Basin, Washington

USGS Publications Warehouse

Heywood, Charles E.; Kahle, Sue C.; Olsen, Theresa D.; Patterson, James D.; Burns, Erick

2016-03-29

The Miocene Columbia River Basalt Group and younger sedimentary deposits of lacustrine, fluvial, eolian, and cataclysmic-flood origins compose the aquifer system of the Pasco Basin in eastern Washington. Irrigation return flow and canal leakage from the Columbia Basin Project have caused groundwater levels to rise substantially in some areas, contributing to landslides along the Columbia River. Water resource managers are considering extraction of additional stored groundwater to supply increasing demand and possibly mitigate problems caused by the increased water levels. To help address these concerns, the transient groundwater model of the Pasco Basin documented in this report was developed to quantify the changes in groundwater flow and storage. The MODFLOW model uses a 1-kilometer finite-difference grid and is constrained by logs and water levels from 846 wells in the study area. Eight model layers represent five sedimentary hydrogeologic units and underlying basalt formations. Head‑dependent flux boundaries represent the Columbia and Snake Rivers to the west and south, respectively, underflow to and (or) from adjacent areas to the northeast, and discharge to agricultural drains, springs, and groundwater withdrawal wells. Specified flux boundaries represent recharge from infiltrated precipitation and anthropogenic sources, including irrigation return flow and leakage from water-distribution canals. The model was calibrated with the parameter‑estimation code PEST++ to groundwater levels measured from 1907 through 2013 and measured discharge to springs and estimated discharge to agricultural drains. Increased recharge since pre-development resulted in a 6.8 million acre-feet increase in storage in the 508-14 administrative area of the Pasco Basin. Four groundwater-management scenarios simulate the 7-year drawdown resulting from withdrawals in different locations. Withdrawals of 2 million gallons per day (Mgal/d) from a hypothetical well field in the upper Ringold Formation along the Columbia River could generate 30–70 feet of drawdown, which may reduce landslide susceptibility along the White Bluffs. Drawdowns resulting from a 1 Mgal/d withdrawal from wells screened in either Pasco gravels, upper Ringold Formation, or both Ringold Formation and underlying basalt are simulated in the other three scenarios, and differ because of the contrasting hydraulic conductivities within the screened intervals.

Data compilation, synthesis, and calculations used for organic-carbon storage and inventory estimates for mineral soils of the Mississippi River Basin

USGS Publications Warehouse

Buell, Gary R.; Markewich, Helaine W.

2004-01-01

U.S. Geological Survey investigations of environmental controls on carbon cycling in soils and sediments of the Mississippi River Basin (MRB), an area of 3.3 x 106 square kilometers (km2), have produced an assessment tool for estimating the storage and inventory of soil organic carbon (SOC) by using soil-characterization data from Federal, State, academic, and literature sources. The methodology is based on the linkage of site-specific SOC data (pedon data) to the soil-association map units of the U.S. Department of Agriculture State Soil Geographic (STATSGO) and Soil Survey Geographic (SSURGO) digital soil databases in a geographic information system. The collective pedon database assembled from individual sources presently contains 7,321 pedon records representing 2,581 soil series. SOC storage, in kilograms per square meter (kg/m2), is calculated for each pedon at standard depth intervals from 0 to 10, 10 to 20, 20 to 50, and 50 to 100 centimeters. The site-specific storage estimates are then regionalized to produce national-scale (STATSGO) and county-scale (SSURGO) maps of SOC to a specified depth. Based on this methodology, the mean SOC storage for the top meter of mineral soil in the MRB is approximately 10 kg/m2, and the total inventory is approximately 32.3 Pg (1 petagram = 109 metric tons). This inventory is from 2.5 to 3 percent of the estimated global mineral SOC pool.

Variability of basin-scale terrestrial water storage from a novel application of the water budget equation: the Amazon and the Mississippi

NASA Astrophysics Data System (ADS)

Yoon, J.; Zeng, N.; Mariotti, A.; Swenson, S.

2007-12-01

In an approach termed the P-E-R (or simply PER) method, we apply the basin water budget equation to diagnose the long-term variability of the total terrestrial water storage (TWS). The key input variables are observed precipitation (P) and runoff (R), and estimated evaporation (E). Unlike typical offline land-surface model estimate where only atmospheric variables are used as input, the direct use of observed runoff in the PER method imposes an important constraint on the diagnosed TWS. Although there lack basin-scale observations of evaporation, the tendency of E to have significantly less variability than the difference between precipitation and runoff (P-R) minimizes the uncertainties originating from estimated evaporation. Compared to the more traditional method using atmospheric moisture convergence (MC) minus R (MCR method), the use of observed precipitation in PER method is expected to lead to general improvement, especially in regions atmospheric radiosonde data are too sparse to constrain the atmospheric model analyzed MC such as in the remote tropics. TWS was diagnosed using the PER method for the Amazon (1970-2006) and the Mississippi Basin (1928-2006), and compared with MCR method, land-surface model and reanalyses, and NASA's GRACE satellite gravity data. The seasonal cycle of diagnosed TWS over the Amazon is about 300 mm. The interannual TWS variability in these two basins are 100-200 mm, but multi-dacadal changes can be as large as 600-800 mm. Major droughts such as the Dust Bowl period had large impact with water storage depleted by 500 mm over a decade. Within the short period 2003-2006 when GRACE data was available, PER and GRACE show good agreement both for seasonal cycle and interannual variability, providing potential to cross-validate each other. In contrast, land-surface model results are significantly smaller than PER and GRACE, especially towards longer timescales. While we currently lack independent means to verify these long-term changes, simple error analysis using 3 precipitation datasets and 3 evaporation estimates suggest that the multi-decadal amplitude can be uncertain up to a factor of 2, while the agreement is high on interannual timescales. The large TWS variability implies the remarkable capacity of land-surface in storing and taking up water that may be under-represented in models. The results also suggest the existence of water storage memories on multi-year time scales, significantly longer than typically assumed seasonal timescales associated with surface soil moisture.

Management self assessment plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Debban, B.L.

Duke Engineering and Services Hanford Inc., Spent Nuclear Fuel Project is responsible for the operation of fuel storage facilities. The SNF project mission includes the safe removal, processing and transportation of Spent Nuclear Fuel from 100 K Area fuel storage basins to a new Storage facility in the Hanford 200 East Area. Its mission is the modification of the 100 K area fuel storage facilities and the construction of two new facilities: the 100 K Area Cold Vacuum Drying Facility, and the 200 East Area Canister Storage Building. The management self assessment plan described in this document is scheduled tomore » begin in April of 1999 and be complete in May of 1999. The management self assessment plan describes line management preparations for declaring that line management is ready to commence operations.« less

Water availability and use pilot; methods development for a regional assessment of groundwater availability, southwest alluvial basins, Arizona

USGS Publications Warehouse

Tillman, Fred D.; Cordova, Jeffrey T.; Leake, Stanley A.; Thomas, Blakemore E.; Callegary, James B.

2011-01-01

Executive Summary: Arizona is located in an arid to semiarid region in the southwestern United States and is one of the fastest growing States in the country. Population in Arizona surpassed 6.5 million people in 2008, an increase of 140 percent since 1980, when the last regional U.S. Geological Survey (USGS) groundwater study was done as part of the Regional Aquifer System Analysis (RASA) program. The alluvial basins of Arizona are part of the Basin and Range Physiographic Province and cover more than 73,000 mi2, 65 percent of the State's total land area. More than 85 percent of the State's population resides within this area, accounting for more than 95 percent of the State's groundwater use. Groundwater supplies in the area are expected to undergo further stress as an increasing population vies with the State's important agricultural sector for access to these limited resources. To provide updated information to stakeholders addressing issues surrounding limited groundwater supplies and projected increases in groundwater use, the USGS Groundwater Resources Program instituted the Southwest Alluvial Basins Groundwater Availability and Use Pilot Program to evaluate the availability of groundwater resources in the alluvial basins of Arizona. The principal products of this evaluation of groundwater resources are updated groundwater budget information for the study area and a proof-of-concept groundwater-flow model incorporating several interconnected groundwater basins. This effort builds on previous research on the assessment and mapping of groundwater conditions in the alluvial basins of Arizona, also supported by the USGS Groundwater Resources Program. Regional Groundwater Budget: The Southwest Alluvial Basins-Regional Aquifer System Analysis (SWAB-RASA) study produced semiquantitative groundwater budgets for each of the alluvial basins in the SWAB-RASA study area. The pilot program documented in this report developed new quantitative estimates of groundwater budget components using recent (2000-2007) data and methods of data analysis. Estimates of inflow components, including mountain-front recharge, incidental recharge from irrigation of agriculture, managed recharge from recharge facilities, interbasin underflow from upgradient basins, and streamflow losses, are quantified for recent time periods. Mountain-front recharge is the greatest inflow component to the groundwater system and was estimated using two methods: a basin characteristic model and new precipitation information used in a previously developed regression equation. Annual mountain-front recharge for the study area for 1940-2007 estimated by the two methods is 730,000 acre-ft for the basin characteristic model and 643,000 acre-ft for the regression equation, representing 1.5 percent and 1.3 percent of precipitation, respectively. Outflow components, including groundwater withdrawals, evapotranspiration, and interbasin flow to downgradient basins, are also presented for recent time periods. Groundwater withdrawals accounted for the largest share of the water budget, with nearly 2.4 million acre-ft per year withdrawn from the study area in recent years. Evapotranspiration from groundwater was estimated at nearly 1.3 million acre-ft per year for the study area using a newly developed method incorporating vegetation indices from satellite images and land cover information. For water-budget components with temporal variation that could be assessed from available data, estimates for intervening time periods since before development were also developed. An estimate of aquifer storage change, representing both gains to and losses from the groundwater system since before development, was derived for the most developed basins in the study area using available estimates of groundwater-level changes and storage coefficients. An overall storage loss of 74.5 million acre-ft was estimated for these basins within the study area. Demonstration

Microbial Condition of Water Samples from Foreign Fuel Storage Facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berry, C.J.; Fliermans, C.B.; Santo Domingo, J.

1997-10-30

In order to assess the microbial condition of foreign nuclear fuel storage facilities, fourteen different water samples were received from facilities outside the United States that have sent spent nuclear fuel to SRS for wet storage. Each water sample was analyzed for microbial content and activity as determined by total bacteria, viable aerobic bacteria, viable anaerobic bacteria, viable sulfate- reducing bacteria, viable acid-producing bacteria and enzyme diversity. The results for each water sample were then compared to other foreign samples and to data from the receiving basin for off- site fuel (RBOF) at SRS.

Geological controls on isotopic signatures of streamflow: results from a nested catchment experiment in Luxembourg (Europe)

NASA Astrophysics Data System (ADS)

Pfister, Laurent; McDonnell, Jeffrey J.; Hissler, Christophe; Martinez-Carreras, Nuria; Gourdol, Laurent; Klaus, Julian; François Iffly, Jean; Barnich, François; Stewart, Mike K.

2014-05-01

Controls of geology and topography on hydrological metrics, like summer low flow (Grant and Tague, 2004) or dynamic storage (Sayama et al., 2011), have been identified in nested catchment experiments. However, most tracer-based studies on streamflow generation have been carried out in small (10 km2) homogenous catchments (Klaus and McDonnell, 2013). The controlling effects of catchment physiography on how catchments store and release water, and how this eventually controls stream isotope behaviour over a large range of scale are poorly understood. Here, we present results from a nested catchment analysis in the Alzette River basin (Luxembourg, Europe). Our hydro-climatological network consists of 16 recording streamgauges and 21 pluviographs. Catchment areas range from 0.47 to 285 km2, with clean and mixed combinations of distinct geologies ranging from schists to marls, sandstone, dolomite and limestone. Our objective was to identify geological controls on (i) winter runoff ratios, (ii) maximum storage and (iii) isotopic signatures in streamflow. For each catchment we determined average runoff ratios from winter season precipitation-discharge double-mass curves. Maximum catchment storage was based on the dynamic storage change approach of Sayama et al. (2011). Changes in isotopic signatures of streamflow were documented along individual catchment flow duration curves. We found strong correlations between average winter runoff ratios, maximum storage and the prevailing geological settings. Catchments with impermeable bedrock (e.g. marls or schists) were characterised by small storage potential and high average filling ratios. As a consequence, these catchments also exhibited the highest average runoff ratios. In catchments underlain by permeable bedrock (e.g. sandstone), storage potential was significantly higher and runoff ratios were considerably smaller. The isotopic signatures of streamflow showed large differences between catchments. In catchments dominated by permeable bedrock, isotopic signatures of streamflow remained stable throughout the entire flow duration curve consistent with a large storage and mixing potential. On less permeable bedrock substrate, we have observed that isotopic signatures in streamflow were much more variable, due to reduced storage volume and comparatively smaller mixing potential. Other metrics such as catchment size and flowpath length exerted a smaller secondary control on isotopic signatures of streamflow in the Alzette River sub-basins. Tague, C., Grant, G.E., 2004. A geological framework for interpreting the low-flow regimes of Cascade streams, Willamette River Basin, Oregon. Water Resources Research, 40(4), doi:10.1029/2003WR002629 Sayama, T., McDonnell, J.J., Dhakal, A., Sullivan, K., 2011. How much water can a watershed store ? Hydrological Processes 25, 3899-3908. Klaus, J., McDonnell, J.J., 2013. Hydrograph separation using stable isotopes: Review and evaluation. Journal of Hydrology 505, 47-64.

MODELING PLUMES IN SMALL STREAMS

EPA Science Inventory

Pesticides accumulate on land surfaces from agricultural, commercial, and domestic application, and wash into streams and rivers during dry and wet weather. Flood water retention basins or structures often collect this contaminated runoff, providing intermediate storage and limit...

Modelling the growth of plants with a uniform growth logistics.

PubMed

Kilian, H G; Bartkowiak, D; Kazda, M; Kaufmann, D

2014-05-21

The increment model has previously been used to describe the growth of plants in general. Here, we examine how the same logistics enables the development of different superstructures. Data from the literature are analyzed with the increment model. Increments are growth-invariant molecular clusters, treated as heuristic particles. This approach formulates the law of mass action for multi-component systems, describing the general properties of superstructures which are optimized via relaxation processes. The daily growth patterns of hypocotyls can be reproduced implying predetermined growth invariant model parameters. In various species, the coordinated formation and death of fine roots are modeled successfully. Their biphasic annual growth follows distinct morphological programs but both use the same logistics. In tropical forests, distributions of the diameter in breast height of trees of different species adhere to the same pattern. Beyond structural fluctuations, competition and cooperation within and between the species may drive optimization. All superstructures of plants examined so far could be reproduced with our approach. With genetically encoded growth-invariant model parameters (interaction with the environment included) perfect morphological development runs embedded in the uniform logistics of the increment model. Copyright © 2014 Elsevier Ltd. All rights reserved.

N ,N'-dimethylperylene-3,4,9,10-bis(dicarboximide) on alkali halide (001) surfaces

NASA Astrophysics Data System (ADS)

Fendrich, Markus; Lange, Manfred; Weiss, Christian; Kunstmann, Tobias; Möller, Rolf

2009-05-01

The growth of N ,N'-dimethylperylene-3,4,9,10-bis(dicarboximide) (DiMe-PTCDI) on KBr(001) and NaCl(001) surfaces has been studied. Experimental results have been achieved using frequency modulation atomic force microscopy at room temperature under ultrahigh vacuum conditions. On both substrates, DiMe-PTCDI forms molecular wires with a width of 10nm, typically, and a length of up to 600nm at low coverages. All wires grow along either the [110] direction (or [11¯0] direction, respectively) of the alkali halide (001) substrates. There is no wetting layer of molecules: atomic resolution of the substrates can be achieved between the wires. The wires are mobile on KBr but substantially more stable on NaCl. A p(2×2) superstructure in a brickwall arrangement on the ionic crystal surfaces is proposed based on electrostatic considerations. Calculations and Monte Carlo simulations using empirical potentials reveal possible growth mechanisms for molecules within the first layer for both substrates, also showing a significantly higher binding energy for NaCl(001). For KBr, the p(2×2) superstructure is confirmed by the simulations; for NaCl, a less dense, incommensurate superstructure is predicted.

Monitoring system of arch bridge for safety network management

NASA Astrophysics Data System (ADS)

Joo, Bong Chul; Yoo, Young Jun; Lee, Chin Hyung; Park, Ki Tae; Hwang, Yoon Koog

2010-03-01

Korea has constructed the safety management network monitoring test systems for the civil infrastructure since 2006 which includes airport structure, irrigation structure, railroad structure, road structure, and underground structure. Bridges among the road structure include the various superstructure types which are Steel box girder bridge, suspension bridge, PSC-box-girder bridge, and arch bridge. This paper shows the process of constructing the real-time monitoring system for the arch bridge and the measured result by the system. The arch type among various superstructure types has not only the structural efficiency but the visual beauty, because the arch type superstructure makes full use of the feature of curve. The main measuring points of arch bridges composited by curved members make a difference to compare with the system of girder bridges composited by straight members. This paper also shows the method to construct the monitoring system that considers the characteristic of the arch bridge. The system now includes strain gauges and thermometers, and it will include various sensor types such as CCTV, accelerometers and so on additionally. For the long term and accuracy monitoring, the latest optical sensors and equipments are applied to the system.

Stimuli-Driven Control of the Helical Axis of Self-Organized Soft Helical Superstructures.

PubMed

Bisoyi, Hari Krishna; Bunning, Timothy J; Li, Quan

2018-06-01

Supramolecular and macromolecular functional helical superstructures are ubiquitous in nature and display an impressive catalog of intriguing and elegant properties and performances. In materials science, self-organized soft helical superstructures, i.e., cholesteric liquid crystals (CLCs), serve as model systems toward the understanding of morphology- and orientation-dependent properties of supramolecular dynamic helical architectures and their potential for technological applications. Moreover, most of the fascinating device applications of CLCs are primarily determined by different orientations of the helical axis. Here, the control of the helical axis orientation of CLCs and its dynamic switching in two and three dimensions using different external stimuli are summarized. Electric-field-, magnetic-field-, and light-irradiation-driven orientation control and reorientation of the helical axis of CLCs are described and highlighted. Different techniques and strategies developed to achieve a uniform lying helix structure are explored. Helical axis control in recently developed heliconical cholesteric systems is examined. The control of the helical axis orientation in spherical geometries such as microdroplets and microshells fabricated from these enticing photonic fluids is also explored. Future challenges and opportunities in this exciting area involving anisotropic chiral liquids are then discussed. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Failure behavior of concrete pile and super-structure dynamic response as a result of soil liquefaction during earthquake

NASA Astrophysics Data System (ADS)

Kaneda, Shogo; Hayashi, Kazuhiro; Hachimori, Wataru; Tamura, Shuji; Saito, Taiki

2017-10-01

In past earthquake disasters, numerous building structure piles were damaged by soil liquefaction occurring during the earthquake. Damage to these piles, because they are underground, is difficult to find. The authors aim to develop a monitoring method of pile damage based on superstructure dynamic response. This paper investigated the relationship between the damage of large cross section cementitious piles and the dynamic response of the super structure using a centrifuge test apparatus. A dynamic specimen used simple cross section pile models consisting of aluminum rod and mortar, a saturated soil (Toyoura sand) of a relative density of 40% and a super structure model of a natural period of 0.63sec. In the shaking table test under a 50G field (length scale of 1/50), excitation was a total of 3 motions scaled from the Rinkai wave at different amplitudes. The maximum acceleration of each of the excitations was 602gal, 336gal and 299gal. The centrifuge test demonstrated the liquefaction of saturated soil and the failure behavior of piles. In the test result, the damage of piles affected the predominant period of acceleration response spectrum on the footing of the superstructure.

Understanding CO2 Plume Behavior and Basin-Scale Pressure Changes during Sequestration Projects through the use of Reservoir Fluid Modeling

USGS Publications Warehouse

Leetaru, H.E.; Frailey, S.M.; Damico, J.; Mehnert, E.; Birkholzer, J.; Zhou, Q.; Jordan, P.D.

2009-01-01

Large scale geologic sequestration tests are in the planning stages around the world. The liability and safety issues of the migration of CO2 away from the primary injection site and/or reservoir are of significant concerns for these sequestration tests. Reservoir models for simulating single or multi-phase fluid flow are used to understand the migration of CO2 in the subsurface. These models can also help evaluate concerns related to brine migration and basin-scale pressure increases that occur due to the injection of additional fluid volumes into the subsurface. The current paper presents different modeling examples addressing these issues, ranging from simple geometric models to more complex reservoir fluid models with single-site and basin-scale applications. Simple geometric models assuming a homogeneous geologic reservoir and piston-like displacement have been used for understanding pressure changes and fluid migration around each CO2 storage site. These geometric models are useful only as broad approximations because they do not account for the variation in porosity, permeability, asymmetry of the reservoir, and dip of the beds. In addition, these simple models are not capable of predicting the interference between different injection sites within the same reservoir. A more realistic model of CO2 plume behavior can be produced using reservoir fluid models. Reservoir simulation of natural gas storage reservoirs in the Illinois Basin Cambrian-age Mt. Simon Sandstone suggest that reservoir heterogeneity will be an important factor for evaluating storage capacity. The Mt. Simon Sandstone is a thick sandstone that underlies many significant coal fired power plants (emitting at least 1 million tonnes per year) in the midwestern United States including the states of Illinois, Indiana, Kentucky, Michigan, and Ohio. The initial commercial sequestration sites are expected to inject 1 to 2 million tonnes of CO2 per year. Depending on the geologic structure and permeability anisotropy, the CO2 injected into the Mt. Simon are expected to migrate less than 3 km. After 30 years of continuous injection followed by 100 years of shut-in, the plume from a 1 million tonnes a year injection rate is expected to migrate 1.6 km for a 0 degree dip reservoir and over 3 km for a 5 degree dip reservoir. The region where reservoir pressure increases in response to CO2 injection is typically much larger than the CO2 plume. It can thus be anticipated that there will be basin wide interactions between different CO2 injection sources if multiple, large volume sites are developed. This interaction will result in asymmetric plume migration that may be contrary to reservoir dip. A basin- scale simulation model is being developed to predict CO2 plume migration, brine displacement, and pressure buildup for a possible future sequestration scenario featuring multiple CO2 storage sites within the Illinois Basin Mt. Simon Sandstone. Interactions between different sites will be evaluated with respect to impacts on pressure and CO2 plume migration patterns. ?? 2009 Elsevier Ltd. All rights reserved.

Hydrologic aspects of the 1998-99 drought in the Delaware River basin

USGS Publications Warehouse

Paulachok, Gary N.; Krejmas, Bruce E.; Soden, Heidi L.

2000-01-01

A notable drought in the Delaware River Basin during late 1998 and most of 1999 had a major effect on surface and subsurface components of the hydrologic system. The drought conditions resulted from anomalous patterns in the general atmospheric circulation that diverted Gulf and subtropical Atlantic moisture away from the basin. From September 1998 to August 1999, the accumulated precipitation deficiency was greater than 12 inches in the part of the basin above Trenton, N.J. Flows in some streams, mainly in the middle and lower parts of the basin, decreased to levels near or less than those measured during the drought of the 1960's, the most severe drought of record in the basin. On several dates in August 1999, combined storage in three New York City water-supply reservoirs in the upper Delaware River Basin decreased by more than 2 billion gallons per day. The drought had a pronounced effect on ground-water levels, as the combination of below-normal recharge and elevated rates of evapotranspiration produced abnormal water-level declines and record low water levels in much of the basin. The drought was broken in mid-September 1999 when the remnants of Tropical Storm Floyd delivered drenching rains throughout the basin.

Final Environmental Assessment for Wildlife Control Actions at Williams Lake, Buckley Air Force Base, Colorado

DTIC Science & Technology

2012-06-01

Reservoir Quincy Reservoir A U R O R AD E N V E R 6th Avenue P eñ a B lv d. Denver International Airport Aurora Airport Centennial Airport N 0...of the Continental Divide. The Denver Basin is a structural depression that is 300 miles long and 200 miles wide and was formed about 67 million...hydrologic analysis: Basin contributing drainage area Width of the subwatershed Subwatershed slope Percent Imperviousness Depression storage

Hydrogeology, water quality, water budgets, and simulated responses to hydrologic changes in Santa Rosa and San Simeon Creek ground-water basins, San Luis Obispo County, California

USGS Publications Warehouse

Yates, Eugene B.; Van Konyenburg, Kathryn M.

1998-01-01

Santa Rosa and San Simeon Creeks are underlain by thin, narrow ground-water basins that supply nearly all water used for local agricultural and municipal purposes. The creeks discharge to the Pacific Ocean near the northwestern corner of San Luis Obispo County, California. The basins contain heterogeneous, unconsolidated alluvial deposits and are underlain by relatively impermeable bedrock. Both creeks usually stop flowing during the summer dry season, and most of the pumpage during that time is derived from ground-water storage. Annual pumpage increased substantially during 1956?88 and is now a large fraction of basin storage capacity. Consequently, dry-season water levels are lower and the water supply is more vulnerable to drought. The creeks are the largest source of ground-water recharge, and complete basin recharge can occur within the first few weeks of winter streamflow. Agricultural and municipal pumpages are the largest outflows and cause dry-season water-level declines throughout the San Simeon Basin. Pumping effects are more localized in the Santa Rosa Basin because of subsurface flow obstructions. Even without pumpage, a large quantity of water naturally drains out of storage at the upper ends of the basins during the dry season. Ground water is more saline in areas close to the coast than in inland areas. Although seawater intrusion has occurred in the past, it probably was not the cause of high salinity in 1988?89. Ground water is very hard, and concentrations of dissolved solids, chloride, iron, and manganese exceed drinking-water standards in some locations. Probability distributions of streamflow were estimated indirectly from a 120-year rainfall record because the periods of record for local stream-gaging stations were wetter than average. Dry-season durations with recurrence intervals between 5 and 43 years are likely to dry up some wells but not cause seawater intrusion. A winter with no streamflow is likely to occur about every 32 years and to result in numerous dry wells, seawater intrusion, and subsidence. Digital ground-water-flow models were used to estimate several items in the ground-water budgets and to investigate the effects of pumpage and drought. The models also were used to investigate the hydrologic effects of selected water-resources management alternatives. Selection of alternatives was not constrained by issues related to water rights, which were under dispute during the study. Increases in the area and intensity of irrigation could increase agricultural water demand by 26 to 35 percent, an increase that would lower water levels by as much as 10 feet and possibly cause subsidence in the lower Santa Rosa Basin. An additional municipal well in the lower Santa Rosa Basin could withdraw 100 acre-feet per year without causing seawater intrusion, but subsidence might occur. Transferring 270 acre-feet per year of treated wastewater from a percolation area near the coast to an area about 0.5 mile upstream of the municipal well field in the San Simeon Basin could raise upstream water levels by as much as 12 feet without causing significant water-table mounding or seawater intrusion. Decreases in agricultural pumping after a winter without streamflow could prevent seawater intrusion while allowing municipal pumping to continue at normal rates.

Contribution of rivers and floodplains to the global terrestrial water storage variability

NASA Astrophysics Data System (ADS)

Getirana, A.; Kumar, S.; Girotto, M.; Rodell, M.

2017-12-01

Since the launch of the GRACE mission in 2002, the scientific community has gained significant insight into terrestrial water storage (TWS) variations around the world. Still, understanding of the relationship between TWS variations and changes in its individual components (groundwater, soil moisture, surface waters, snow, and vegetation water storage) has not advanced beyond small-scale studies based on in situ data. Although a few studies have demonstrated the impact that surface water storage (SWS) has on TWS in tropical basins, the vast majority of investigations on TWS decomposition systematically neglect SWS by assuming that its contribution to TWS is trivial. Even though that assumption might be a close representation of the truth in specific locations, the actual impact of SWS on the global TWS change and its spatial variability is unknown. This study aims to quantify the contribution of rivers and floodplains on the global terrestrial water storage (TWS) variability. We use state-of-the-art models to simulate land surface processes and river dynamics in order to separate TWS into its main components. Based on a proposed impact index, we show that surface water storage (SWS) contributes to 7% of TWS globally, but that contribution highly varies spatially. The primary contribution of SWS to TWS is in the tropics, and in major rivers flowing over arid regions or at high latitudes. About 20-23% of both Amazon and Nile basins' TWS changes are due to SWS. SWS has low impact in Western U.S., Northern Africa, Middle-East and central Asia. Based on comparisons against GRACE-based estimates, we conclude that using SWS significantly improves TWS simulations in most South America, Africa and Northern India, confirming the need for SWS as a key component of TWS change.

Dam nation: A geographic census of American dams and their large-scale hydrologic impacts

NASA Astrophysics Data System (ADS)

Graf, William L.

1999-04-01

Newly available data indicate that dams fragment the fluvial system of the continental United States and that their impact on river discharge is several times greater than impacts deemed likely as a result of global climate change. The 75,000 dams in the continental United States are capable of storing a volume of water almost equaling one year's mean runoff, but there is considerable geographic variation in potential surface water impacts. In some western mountain and plains regions, dams can store more than 3 year's runoff, while in the Northeast and Northwest, storage is as little as 25% of the annual runoff. Dams partition watersheds; the drainage area per dam varies from 44 km2 (17 miles2) per dam in New England to 811 km2 (313 miles2) per dam in the Lower Colorado basin. Storage volumes, indicators of general hydrologic effects of dams, range from 26,200 m3 km-2 (55 acre-feet mile-2) in the Great Basin to 345,000 m3 km-2 (725 acre-feet mile-2) in the South Atlantic region. The greatest river flow impacts occur in the Great Plains, Rocky Mountains, and the arid Southwest, where storage is up to 3.8 times the mean annual runoff. The nation's dams store 5000 m3 (4 acre-feet) of water per person. Water resource regions have experienced individualized histories of cumulative increases in reservoir storage (and thus of downstream hydrologic and ecologic impacts), but the most rapid increases in storage occurred between the late 1950s and the late 1970s. Since 1980, increases in storage have been relatively minor.

Economic performance of irrigation capacity development to adapt to climate in the American Southwest

NASA Astrophysics Data System (ADS)

Ward, Frank A.; Crawford, Terry L.

2016-09-01

Growing demands for food security to feed increasing populations worldwide have intensified the search for improved performance of irrigation, the world's largest water user. These challenges are raised in the face of climate variability and from growing environmental demands. Adaptation measures in irrigated agriculture include fallowing land, shifting cropping patterns, increased groundwater pumping, reservoir storage capacity expansion, and increased production of risk-averse crops. Water users in the Gila Basin headwaters of the U.S. Lower Colorado Basin have faced a long history of high water supply fluctuations producing low-valued defensive cropping patterns. To date, little research grade analysis has investigated economically viable measures for irrigation development to adjust to variable climate. This gap has made it hard to inform water resource policy decisions on workable measures to adapt to climate in the world's dry rural areas. This paper's contribution is to illustrate, formulate, develop, and apply a new methodology to examine the economic performance from irrigation capacity improvements in the Gila Basin of the American Southwest. An integrated empirical optimization model using mathematical programming is developed to forecast cropping patterns and farm income under two scenarios (1) status quo without added storage capacity and (2) with added storage capacity in which existing barriers to development of higher valued crops are dissolved. We find that storage capacity development can lead to a higher valued portfolio of irrigation production systems as well as more sustained and higher valued farm livelihoods. Results show that compared to scenario (1), scenario (2) increases regional farm income by 30%, in which some sub regions secure income gains exceeding 900% compared to base levels. Additional storage is most economically productive when institutional and technical constraints facing irrigated agriculture are dissolved. Along with additional storage, removal of constraints on weak transportation capacity, limited production scale, poor information access, weak risk-bearing capacity, limited management skills, scarce labor supply, low food processing capacity, and absolute scale constraints, all can raise the economic value of additional irrigation capacity development. Our results light a path forward to policy makers, water administrators, and farm managers, who bear the burden of protecting farm income, food and water security, and rural economic development in the world's dry regions faced by the need to adapt to climate variability.

Simulation of reservoir storage and firm yields of three surface-water supplies, Ipswich River Basin, Massachusetts

USGS Publications Warehouse

Zarriello, Phillip J.

2002-01-01

A Hydrologic Simulation Program FORTRAN (HSPF) model previously developed for the Ipswich River Basin was modified to simulate the hydrologic response and firm yields of the water-supply systems of Lynn, Peabody, and Salem-Beverly. The updated model, expanded to include a portion of the Saugus River Basin that supplies water to Lynn, simulated reservoir system storage over a 35-year period (1961-95) under permitted withdrawals and hypothetical restrictions designed to maintain seasonally varied streamflow for aquatic habitat. A firm yield was calculated for each system and each withdrawal restriction by altering demands until the system failed. This is considered the maximum withdrawal rate that satisfies demands, but depletes reservoir storage. Simulations indicate that, under the permitted withdrawals, Lynn and Salem-Beverly were able to meet demands and generally have their reservoir system recover to full capacity during most years; reservoir storage averaged 83 and 82 percent of capacity, respectively. The firm yields for the Lynn and Salem-Beverly systems were 11.4 and 12.2 million gallons per day (Mgal/d), respectively, or 8 and 21 percent more than average 1998-2000 demands, respectively. Under permitted withdrawals and average 1998-2000 demands, the Peabody system failed in all years; thus Peabody purchased water to meet demands. The firm yield for the Peabody system is 3.70 Mgal/d, or 37 percent less than the average 1998-2000 demand. Simulations that limit withdrawals to levels recommended by the Ipswich River Fisheries Restoration Task Group (IRFRTG) indicate that under average 1998-2000 demands, reservoir storage was depleted in each of the three systems. Reservoir storage under average 1998-2000 demands and IRFRTG-recommended streamflow requirements averaged 15, 22, and 71 percent of capacity for the Lynn, Peabody, Salem-Beverly systems, respectively. The firm-yield estimates under the IRFRTG-recommended streamflow requirements were 6.02, 1.94, and 7.69 Mgal/d or 43, 64, and 34 percent less than the average 1998-2000 demands for the Lynn, Peabody, and Salem-Beverly systems, respectively. Simulations that limit withdrawals from the Saugus River to a less stringent set of restrictions (based on an Instream Flow Incremental Methodology study) than those previously simulated indicate that the firm yield of the Lynn system is about 31 percent less than the average 1998-2000 withdrawals (7.31 Mgal/d).

Real-time monitoring of CO2 storage sites: Application to Illinois Basin-Decatur Project

USGS Publications Warehouse

Picard, G.; Berard, T.; Chabora, E.; Marsteller, S.; Greenberg, S.; Finley, R.J.; Rinck, U.; Greenaway, R.; Champagnon, C.; Davard, J.

2011-01-01

Optimization of carbon dioxide (CO2) storage operations for efficiency and safety requires use of monitoring techniques and implementation of control protocols. The monitoring techniques consist of permanent sensors and tools deployed for measurement campaigns. Large amounts of data are thus generated. These data must be managed and integrated for interpretation at different time scales. A fast interpretation loop involves combining continuous measurements from permanent sensors as they are collected to enable a rapid response to detected events; a slower loop requires combining large datasets gathered over longer operational periods from all techniques. The purpose of this paper is twofold. First, it presents an analysis of the monitoring objectives to be performed in the slow and fast interpretation loops. Second, it describes the implementation of the fast interpretation loop with a real-time monitoring system at the Illinois Basin-Decatur Project (IBDP) in Illinois, USA. ?? 2011 Published by Elsevier Ltd.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rychel, Dwight

The Permian Basin Carbon Capture, Utilization and Storage (CCUS) Training Center was one of seven regional centers formed in 2009 under the American Recovery and Reinvestment Act of 2009 and managed by the Department of Energy. Based in the Permian Basin, it is focused on the utilization of CO 2 Enhanced Oil Recovery (EOR) projects for the long term storage of CO 2 while producing a domestic oil and revenue stream. It delivers training to students, oil and gas professionals, regulators, environmental and academia through a robust web site, newsletter, tech alerts, webinars, self-paced online courses, one day workshops, andmore » two day high level forums. While course material prominently features all aspects of the capture, transportation and EOR utilization of CO 2, the audience focus is represented by its high level forums where selected graduate students with an interest in CCUS interact with Industry experts and in-house workshops for the regulatory community.« less

Report of the River Master of the Delaware River for the period December 1, 1984 - November 30, 1985

USGS Publications Warehouse

Schaefer, F.T.; Harkness, W.E.; Cecil, L.D.

1986-01-01

A Decree of the Supreme Court of the United States in 1954 established the position of Delaware River Master. The Decree authorizes diversions of water from the Delaware River basin and requires compensating releases from certain reservoirs of the City of New York to be made under the supervision and direction of the River Master. Reports to the Court, not less frequently than annually, were stipulated. During the 1985 report year, December 1, 1984, to November 30, 1985, precipitation and runoff varied from below average to above average in the Delaware River basin. For the year as a whole, precipitation was near average. Runoff was below average. Operations were under a status of drought warning or drought from January 23, 1984, through the end of the report year. Below-normal precipitation the first half of the year resulted in decreased storage in the reservoirs to record low levels by March 1, 1985. Storage remained at record low levels from March through September. Above-normal precipitation in September and November served to break the drought and increase storage into the normal zone of the operating curves for the reservoirs. Diversions from the Delaware River basin by New York City did not exceed those authorized by the terms of the Amended Decree or those invoked by the several emergency conservation measures throughout the year. There were no diversions from the Delaware River basin by New Jersey during the year. Releases were made as directed by the River Master at rates designed to meet the Montague flow objective on 82 days between June 14 and September 28. Releases were made at conservation rates or at rates designed to relieve thermal stress in the streams downstream from the reservoirs at other times. (See also W89-04133) (USGS)

Human-induced Terrestrial Water Storage Change: A Global Analysis using Hydrological Models and GRACE

NASA Astrophysics Data System (ADS)

Felfelani, F.; Pokhrel, Y. N.

2016-12-01

Hydrological models and data derived from the Gravity Recovery and Climate Experiment (GRACE) satellite mission are used to study terrestrial water storage (TWS) change; however, both have disadvantages that necessitate the integrated use of them. While GRACE doesn't disintegrate the vertical storage into its components, most models do not account for human activities. Here we use two Land Surface Models (LSMs), i.e., HiGW-MAT and PCRGLOBWB that fully couple natural and human drivers of changes in water cycle, explicitly simulating the changes in various TWS compartments. We first evaluate the models performance with GRACE observations. Then, we quantify the human footprint over global river basins located in different geographic and climate regions. To quantify human impacts, a new framework is proposed based on the GRACE observations (representing both climate variability and human activities) together with the natural simulation of LSMs using water budget equation (P-ET-R; P for precipitation, ET for evapotranspiration, and R for runoff). Finally, we examine the uncertainty in TWS simulations arising from the uncertainties in forcing data. Results indicate that, in snow-dominated regions, PCRGLOBWB generally fails to reproduce neither the interannual variability of observed TWS nor the seasonal cycle, while HiGW-MAT model shows significantly better results. In basins with human signatures, PCRGLOBWB generally shows better agreement with GRACE compared to HiGW-MAT. It is found that HiGW-MAT tends to overestimate groundwater depletion in basins with human impacts (e.g., Amudarya, Colorado, Euphrates and Indus), which results in larger negative interannual TWS trend compared to GRACE. Euphrates and Ganges river basins experience the highest human-induced TWS deficit rates (2.08 cm/yr and 1.94 cm/yr, respectively) during the simulation period of 2002-2010. Uncertainty analysis of results from the same model but with different forcing data suggests a high standard deviation in the order of 10 cm/yr.

Site Development, Operations, and Closure Plan Topical Report 5 An Assessment of Geologic Carbon Sequestration Options in the Illinois Basin. Phase III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finley, Robert; Payne, William; Kirksey, Jim

2015-06-01

The Midwest Geological Sequestration Consortium (MGSC) has partnered with Archer Daniels Midland Company (ADM) and Schlumberger Carbon Services to conduct a large-volume, saline reservoir storage project at ADM’s agricultural products processing complex in Decatur, Illinois. The Development Phase project, named the Illinois Basin Decatur Project (IBDP) involves the injection of 1 million tonnes of carbon dioxide (CO 2) into a deep saline formation of the Illinois Basin over a three-year period. This report focuses on objectives, execution, and lessons learned/unanticipated results from the site development (relating specifically to surface equipment), operations, and the site closure plan.

Geology of the Powder River Basin, Wyoming and Montana, with reference to subsurface disposal of radioactive wastes

USGS Publications Warehouse

Beikman, Helen M.

1962-01-01

The Powder River Basin is a structural and topographic basin occupying an area of about 20,000 square miles in northeastern Wyoming arid southeastern Montana. The Basin is about 230 miles long in a northwest-southeast direction and is about 100 miles wide. It is bounded on three sides by mountains in which rocks of Precambrian age are exposed. The Basin is asymmetrical with a steep west limb adjacent to the Bighorn Mountains and a gentle east limb adjacent to the Black Hills. Sedimentary rocks within the Basin have a maximum thickness of about 18,000 feet and rocks of every geologic period are represented. Paleozoic rocks are about 2,500 feet thick and consist of marine bonate rocks and sandstone; Mesozoic rocks are about 9,500 feet thick and consist of both marine and nonmarine siltstone and sandstone; and Cenozoic rocks are from 4,000 to 6,000 feet thick and consist of coal-bearing sandstone and shale. Radioactive waste could be stored in the pore space of permeable sandstone or in shale where space could be developed. Many such rock units that could be used for storing radioactive wastes are present within the Powder River Basin. Permeable sandstone beds that may be possible reservoirs for storage of radioactive waste are present throughout the Powder River Basin. These include sandstone beds in the Flathead Sandstone and equivalent strata in the Deadwood Formation, the Tensleep Sandstone and equivalent strata in the Minnelusa Formation and the Sundance Formation in rocks of pre-Cretaceous age. However, most of the possible sandstone reservoirs are in rocks of Cretaceous age and include sandstone beds in the Fall River, Lakota, Newcastle, Frontier, Cody, and Mesaverde Formations. Problems of containment of waste such as clogging of pore space and chemical incompatibility would have to be solved before a particular sandstone unit could be selected for waste disposal. Several thick sequences of impermeable shale such as those in the Skull Creek, Mowry, Frontier, Belle Fourche, Cody, Lewis, and Pierre Formations, occur in rocks of Cretaceous age in the Basin. Limited storage space for liquid waste might be developed in impermeable shale by fracturing the shale and space for calcined or fused waste could be developed by mining cavities.

Technology, safety and costs of decommissioning reference independent spent fuel storage installations. [Contains glossary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ludwick, J D; Moore, E B

1984-01-01

Safety and cost information is developed for the conceptual decommissioning of five different types of reference independent spent fuel storage installations (ISFSIs), each of which is being given consideration for interim storage of spent nuclear fuel in the United States. These include one water basin-type ISFSI (wet) and four dry ISFSIs (drywell, silo, vault, and cask). The reference ISFSIs include all component parts necessary for the receipt, handling and storage of spent fuel in a safe and efficient manner. Three decommissioning alternatives are studied to obtain comparisons between costs (in 1981 dollars), occupational radiation doses, and potential radiation doses tomore » the public. The alternatives considered are: DECON (immediate decontamination), SAFSTOR (safe storage followed by deferred decontamination), and ENTOMB (entombment followed by long-term surveillance).« less

Irrigation infrastructure and water appropriation rules for food security

NASA Astrophysics Data System (ADS)

Gohar, Abdelaziz A.; Amer, Saud A.; Ward, Frank A.

2015-01-01

In the developing world's irrigated areas, water management and planning is often motivated by the need for lasting food security. Two important policy measures to address this need are improving the flexibility of water appropriation rules and developing irrigation storage infrastructure. Little research to date has investigated the performance of these two policy measures in a single analysis while maintaining a basin wide water balance. This paper examines impacts of storage capacity and water appropriation rules on total economic welfare in irrigated agriculture, while maintaining a water balance. The application is to a river basin in northern Afghanistan. A constrained optimization framework is developed to examine economic consequences on food security and farm income resulting from each policy measure. Results show that significant improvements in both policy aims can be achieved through expanding existing storage capacity to capture up to 150 percent of long-term average annual water supplies when added capacity is combined with either a proportional sharing of water shortages or unrestricted water trading. An important contribution of the paper is to show how the benefits of storage and a changed water appropriation system operate under a variable climate. Results show that the hardship of droughts can be substantially lessened, with the largest rewards taking place in the most difficult periods. Findings provide a comprehensive framework for addressing future water scarcity, rural livelihoods, and food security in the developing world's irrigated regions.

Floodplain soil organic carbon storage in the central Yukon River Basin

NASA Astrophysics Data System (ADS)

Lininger, K.; Wohl, E.

2017-12-01

As rivers transport sediment, organic matter, and large wood, they can deposit those materials in their floodplains, storing carbon. One aspect of the carbon cycle that isn't well understood is how much carbon is stored in rivers and floodplains. There may be more carbon in rivers and floodplains than previously thought. This is important for accounting for all aspects of the carbon cycle, which is the movement of carbon among the land, ocean, and atmosphere. We are quantifying that storage in high latitude floodplains through fieldwork along five rivers in the central Yukon River Basin within the Yukon Flats National Wildlife Refuge in interior Alaska. We find that the geomorphic environment and geomorphic characteristics of rivers influence the spatial distribution of carbon on the landscape, and that floodplains may be disproportionally important for carbon storage compared to other areas. Our study area contains discontinuous permafrost, which is soil that is perennially frozen, and is warming quickly due to climate change, as in other high latitude regions. The large amount of carbon stored in the subsurface and in permafrost in the high latitudes highlights the importance of understanding where carbon is stored within rivers and floodplains in these regions and how long that carbon remains in storage. Our research helps inform how river systems influence the carbon cycle in a region undergoing rapid change.

Synthesis of natural flows at selected sites in the upper Missouri River basin, Montana, 1928-89

USGS Publications Warehouse

Cary, L.E.; Parrett, Charles

1996-01-01

Natural monthly streamflows were synthesized for the years 1928-89 for 43 sites in the upper Missouri River Basin upstream from Fort Peck Lake in Montana. The sites are represented as nodes in a streamflow accounting model being developed by the Bureau of Reclamation. Recorded and historical flows at most sites have been affected by human activities including reservoir storage, diversions for irrigation, and municipal use. Natural flows at the sites were synthesized by eliminating the effects of these activities. Recorded data at some sites do not include the entire study period. The missing flows at these sites were estimated using a statistical procedure. The methods of synthesis varied, depending on upstream activities and information available. Recorded flows were transferred to nodes that did not have streamflow-gaging stations from the nearest station with a sufficient length of record. The flows at one node were computed as the sum of flows from three upstream tributaries. Monthly changes in reservoir storage were computed from monthend contents. The changes in storage were corrected for the effects of evaporation and precipitation using pan-evaporation and precipitation data from climate stations. Irrigation depletions and consumptive use by the three largest municipalities were computed. Synthesized natural flow at most nodes was computed by adding algebraically the upstream depletions and changes in reservoir storage to recorded or historical flow at the nodes.

Decreasing Agricultural Irrigation has not reversed Groundwater Depletion in the Yellow River Basin

NASA Astrophysics Data System (ADS)

Kang, Z.; Xie, X.; Zhu, B.

2017-12-01

Agricultural irrigation is considered as the major water use sector accounting for over 60% of the global freshwater withdrawals. Especially in the arid and semiarid areas, irrigation from groundwater storage substantially sustain crop growth and food security. China's Yellow River Basin (YRB) is a typical arid and semiarid area with average annual precipitation about 450 mm. In this basin, more than 52 million hm2 of arable land needs irrigation for planting wheat, cotton, paddy rice etc, and groundwater contributes over one-third irrigation water. However, agricultural irrigation remained a certain level or decreased to some degree due to water-saving technologies and returning farmland to forest projects. Then an interesting question arises: has the groundwater storage (GWS) in YRB kept a consistent variation with the agricultural irrigation? In this study, to address this question, we employed multi-source data from ground measurements, remote sensing monitoring and large-scale hydrological modeling. Specifically, groundwater storage variation was identified using Gravity Recovery and Climate Experiment (GRACE) data and ground observations, and groundwater recharge was estimated based on the Variable Infiltration Capacity (VIC) modeling. Results indicated that GWS in YRB still holds a significant depletion with a rate of about -3 mm per year during the past decade, which was consistently demonstrated by the GRACE and the ground observations. Ground water recharge shows negligible upward trends despite climate change. The roles of different sectors contributing to groundwater depletion have changed. Agricultural irrigation accounting for over 60% of groundwater depletion, but its impact decreased. However, the domestic and the industrial purposes play an increasing role in shaping groundwater depletion.

Simulation of daily streamflow for nine river basins in eastern Iowa using the Precipitation-Runoff Modeling System

USGS Publications Warehouse

Haj, Adel E.; Christiansen, Daniel E.; Hutchinson, Kasey J.

2015-10-14

The accuracy of Precipitation-Runoff Modeling System model streamflow estimates of nine river basins in eastern Iowa as compared to measured values at U.S. Geological Survey streamflow-gaging stations varied. The Precipitation-Runoff Modeling System models of nine river basins in eastern Iowa were satisfactory at estimating daily streamflow at 57 of the 79 calibration sites and 13 of the 14 validation sites based on statistical results. Unsatisfactory performance can be contributed to several factors: (1) low flow, no flow, and flashy flow conditions in headwater subbasins having a small drainage area; (2) poor representation of the groundwater and storage components of flow within a basin; (3) lack of accounting for basin withdrawals and water use; and (4) the availability and accuracy of meteorological input data. The Precipitation- Runoff Modeling System models of nine river basins in eastern Iowa will provide water-resource managers with a consistent and documented method for estimating streamflow at ungaged sites and aid in environmental studies, hydraulic design, water management, and water-quality projects.

Hydro-meteorological risk reduction and climate change adaptation in the Sava River Basin

NASA Astrophysics Data System (ADS)

Brilly, Mitja; Šraj, Mojca; Kryžanowski, Andrej

2017-04-01

The Sava River Basin covered the teritory of several countries. There were, in past thirty years, several flood hazard events with almost hundred years return period. Parts of the basin suffer by severe droughts also. In the presentation we covered questions of: • Flood hazard in complex hydrology structure • Landslide and flush flood in mountainous regions • Floods on karst polje • Flood risk management in the complex international and hydrological condition. • Impact of man made structures: hydropower storages, inundation ponds, river regulation, alternate streams, levees system, pumping stations, Natura 2000 areas etc. • How to manage droughts in the international river basin The basin is well covered by information and managed by international the SRB Commission (http://savacommission.org/) that could help. We develop study for climate change impact on floods on entire river basin financing by UNECE. There is also study provide climate change impact on the water management provide by World Bank and on which we take part. Recently is out call by world bank for study »Flood risk management plan for the SRB«.

Consensuses and discrepancies of basin-scale ocean heat content changes in different ocean analyses

NASA Astrophysics Data System (ADS)

Wang, Gongjie; Cheng, Lijing; Abraham, John; Li, Chongyin

2018-04-01

Inconsistent global/basin ocean heat content (OHC) changes were found in different ocean subsurface temperature analyses, especially in recent studies related to the slowdown in global surface temperature rise. This finding challenges the reliability of the ocean subsurface temperature analyses and motivates a more comprehensive inter-comparison between the analyses. Here we compare the OHC changes in three ocean analyses (Ishii, EN4 and IAP) to investigate the uncertainty in OHC in four major ocean basins from decadal to multi-decadal scales. First, all products show an increase of OHC since 1970 in each ocean basin revealing a robust warming, although the warming rates are not identical. The geographical patterns, the key modes and the vertical structure of OHC changes are consistent among the three datasets, implying that the main OHC variabilities can be robustly represented. However, large discrepancies are found in the percentage of basinal ocean heating related to the global ocean, with the largest differences in the Pacific and Southern Ocean. Meanwhile, we find a large discrepancy of ocean heat storage in different layers, especially within 300-700 m in the Pacific and Southern Oceans. Furthermore, the near surface analysis of Ishii and IAP are consistent with sea surface temperature (SST) products, but EN4 is found to underestimate the long-term trend. Compared with ocean heat storage derived from the atmospheric budget equation, all products show consistent seasonal cycles of OHC in the upper 1500 m especially during 2008 to 2012. Overall, our analyses further the understanding of the observed OHC variations, and we recommend a careful quantification of errors in the ocean analyses.

Ground water in the Redding Basin, Shasta and Tehama counties, California

USGS Publications Warehouse

Pierce, M.J.

1983-01-01

An appraisal of ground-water conditions in the Redding Basin was made by the U.S. Geological Survey and the California Department of Water Resources during 1979 and 1980. The basin covers about 510 square miles in the northern part of the Central Valley of California. Ground water in the basin is obtained principally from wells tapping continental deposits of Tertiary and/or Quaternary age. These deposits are arranged in a synclinal structure that trends and plunges southward. Recharge to the basin is from subsurface inflow; infiltration of precipitation and excess irrigation water; and percolation of certain reaches of streams and creeks. Ground-water movement is generally from the periphery of the basin towards the Sacramento River. Hydrographs for the period 1956 to 1970 show only a slight water-level decline and virtually no change between 1970 and 1979. The total estimated pumpage for 1976 was 82,000 acre-feet. Estimated usable storage capacity for the basin is about 5.5 million acre-feet. Chemical quality of ground water is rated good to excellent. Water type is a magnesium-calcium bicarbonate in character. The underlying Chico Formation contains saline marine water which is of poor quality. (USGS)

Model quantification of the CO2 storage in the Los Páramos site (Duero basin, NE Spain)

NASA Astrophysics Data System (ADS)

Nardi, Albert; Grandia, Fidel; Abarca, Elena; Motis, Kilian; Molinero, Jorge

2013-04-01

The Duero basin in NW Spain is one the most promising basin for CO2 storage in the Iberian Peninsula due to the existence of favourable deep aquifers close to large CO2 emission point sources. A number of projects are presently active either for scientific research (e.g., the Hontomín site, OXI-CFB300 EPRR project) or commercial purposes (e.g., Sahagún and Los Páramos projects). The project called Los Páramos intends to assess the injection of CO2 in a group of dome-shaped structures with an estimated total capacity of 200 Mt (ranked 2nd in the Iberian Peninsula, IGME 2010). These domes were studied in the past for hydrocarbon exploration and a large body of information is available from seismic profiles (over 170 km) and 3 deep wells. The Los Páramos site is emplaced in the San Pedro Folded Band (SPFB) that consists mainly of thick-skinned thrusts of Mesozoic rocks (Triassic and Upper Cretaceous) sealed by a thick (1200-1500 m), undeformed cover of Tertiary claystones. Dome-like structures are related to thrusts leading to favourable reservoirs. The target horizon for CO2 storage is the Utrillas Fm sandstone with high porosity (13-20%) and thickness (225-250 m). In three of the domes, the Utrillas Fm is below -800m, allowing thus the storage of CO2(sc). This sandstone hosts an aquifer containing saline water, up to 50 g·L-1, according to the data from drill wells. The presence of saline groundwater is explained by water interaction with Triassic evaporite layers just underlying the Utrillas Fm sandstones. The CO2 storage at Los Paramos site is planned via injection of supercritical CO2 (CO2(sc)) in the Utrillas Fm. In general, the next four trapping mechanisms are expected, which are of increasing importance through time (1) structural, (2) residual saturation, (3) dissolution, and (4) mineral. The prediction of the mass of CO2 stored through time in any storage systems is an essential parameter in the pre-injection assessment of a geological storage. For safety reasons, it is relevant to know the mass of CO2 trapped under the different trapping mechanisms. In this work, storage quantification in the Dome B of Los Páramos site has been performed by using multiphase transport simulations with COMSOL Multiphysics. Model results predict well the amount of CO2 trapped as residual phase and the onset of the formation of CO2-rich brine fingers and their extent and evolution.

Mutually beneficial and sustainable management of Ethiopian and Egyptian dams in the Nile Basin

NASA Astrophysics Data System (ADS)

Habteyes, Befekadu G.; Hasseen El-bardisy, Harb A. E.; Amer, Saud A.; Schneider, Verne R.; Ward, Frank A.

2015-10-01

Ongoing pressures from population growth, recurrent drought, climate, urbanization and industrialization in the Nile Basin raise the importance of finding viable measures to adapt to these stresses. Four tributaries of the Eastern Nile Basin contribute to supplies: the Blue Nile (56%), White Nile-Albert (14%), Atbara (15%) and Sobat (15%). Despite much peer reviewed work addressing conflicts on the Nile, none to date has quantitatively examined opportunities for discovering benefit sharing measures that could protect negative impacts on downstream water users resulting from new upstream water storage developments. The contribution of this paper is to examine the potential for mutually beneficial and sustainable benefit sharing measures from the development and operation of the Grand Ethiopian Renaissance Dam while protecting baseline flows to the downstream countries including flows into the Egyptian High Aswan Dam. An integrated approach is formulated to bring the hydrology, economics and institutions of the region into a unified framework for policy analysis. A dynamic optimization model is developed and applied to identify the opportunities for Pareto Improving measures to operate these two dams for the four Eastern Nile Basin countries: Ethiopia, South Sudan, Sudan, and Egypt. Results indicate a possibility for one country to be better off (Ethiopia) and no country to be worse off from a managed operation of these two storage facilities. Still, despite the optimism of our results, considerable diplomatic negotiation among the four riparians will be required to turn potential gains into actual welfare improvements.

An integrated investigation of lake storage and water level changes in the Paiku Co basin, central Himalayas

NASA Astrophysics Data System (ADS)

Lei, Yanbin; Yao, Tandong; Yang, Kun; Bird, Broxton W.; Tian, Lide; Zhang, Xiaowen; Wang, Weicai; Xiang, Yang; Dai, Yufeng; Lazhu; Zhou, Jing; Wang, Lei

2018-07-01

Since the late 1990s, lakes in the southern Tibetan Plateau (TP) have shrunk considerably, which contrasts with the rapid expansion of lakes in the interior TP. Although these spatial trends have been well documented, the underlying hydroclimatic mechanisms are not well understood. Since 2013, we have carried out comprehensive water budget observations at Paiku Co, an alpine lake in the central Himalayas. In this study, we investigate water storage and lake level changes on seasonal to decadal time scales based on extensive in-situ measurements and satellite observations. Bathymetric surveys show that Paiku Co has a mean and maximum water depth of 41.1 m and 72.8 m, respectively, and its water storage was estimated to be 109.3 × 108 m3 in June 2016. On seasonal scale between 2013 and 2017, Paiku Co's lake level decreased slowly between January and May, increased considerably between June and September, and then decreased rapidly between October and January. On decadal time scale, Paiku Co's lake level decreased by 3.7 ± 0.3 m and water storage reduced by (10.2 ± 0.8) × 108 m3 between 1972 and 2015, accounting for 8.5% of the total water storage in 1972. This change is consistent with a trend towards drier conditions in the Himalaya region during the recent decades. In contrast, glacial lakes within Paiku Co's basin expanded rapidly, indicating that, unlike Paiku Co, glacial meltwater was sufficient to compensate the effect of the reduced precipitation.

Spatiotemporal evolution of water storage changes in India from the updated GRACE-derived gravity records

NASA Astrophysics Data System (ADS)

Panda, Dileep K.; Wahr, John

2016-01-01

Investigating changes in terrestrial water storage (TWS) is important for understanding response of the hydrological cycle to recent climate variability worldwide. This is particularly critical in India where the current economic development and food security greatly depend on its water resources. We use 129 monthly gravity solutions from NASA's Gravity Recovery and Climate Experiment (GRACE) satellites for the period of January 2003 to May 2014 to characterize spatiotemporal variations of TWS and groundwater storage (GWS). The spatiotemporal evolution of GRACE data reflects consistent patterns with that of several hydroclimatic variables and also shows that most of the water loss has occurred in the northern parts of India. Substantial GWS depletion at the rate of 1.25 and 2.1 cm yr-1 has taken place, respectively in the Ganges Basin and Punjab state, which are known as the India's grain bowl. Of particular concern is the Ganges Basin's storage loss in drought years, primarily due to anthropogenic groundwater withdrawals that sustain rice and wheat cultivation. We estimate these losses to be approximately 41, 44, and 42 km3 in 2004, 2009, and 2012, respectively. The GWS depletions that constitute about 90% of the observed TWS loss are also influenced by a marked rise in temperatures since 2008. A high degree of correspondence between GRACE-derived GWS and in situ groundwater levels from observation well validates the results. This validation increases confidence level in the application of GRACE observations in monitoring large-scale storage changes in intensely irrigated areas in India and other regions around the world.

Water-quality assessment of the Albemarle-Pamlico drainage basin, North Carolina and Virginia; characterization of suspended sediment, nutrients, and pesticides

USGS Publications Warehouse

Harned, Douglas; McMahon, Gerard; Spruill, T.B.; Woodside, M.D.

1995-01-01

The 28,000-square-mile Albemarle-Pamlico drainage basin includes the Roanoke, Dan, Chowan Tar, and Neuse Rivers. The basin extends through four physiographic provinces in North Carolina and Virginia-Valley and Ridge, Blue Ridge, Piedmont and Coastal Plain. The spatial and temporal trends in ground-water and riverine water quality in the study area were characterized by using readily available data sources The primary data sources that were used included the U.S. Geological Survey's National Water Data Storage and Retrieval System (WATSTORE) database, the U.S. Environmental Protection Agency's Storage and Retrieval System (STORET) database, and results of a few investigations of pesticide occurrence. The principal water-quality constituents examined were suspended sediment, nutrients, and pesticides. The data examined generally spanned the period from 1950 to 1993. The only significant trends in suspended sediment were detected at three Chowan River tributary sites which showed long-term decreases. Suspended- and total-solids concentrations have decreased throughout the Albemarle-Pamlico drainage basin. The decreases are probably a result of (1) construction of new lakes and ponds in the basin, which trap solids, (2) improved agricultural soil management, and (3) improved wastewater treatment. Nutrient point sources are much less than nonpoint nutrient sources at the eight NASQAN basins examined for nutrient loads. The greatest nitrogen inputs are associated with crop fertilizer and biological nitrogen fixation by soybeans and peanuts, whereas atmospheric and animal-related nitrogen inputs are comparable in magnitude. The largest phosphorus inputs are associated with animal wastes. The most commonly detected pesticides in surface water in the STORET database were atrazine and aldrin.Intensive organonitrogen herbicide sampling of Chicod Creek in 1992 showed seasonal variations in pesticide concentration. The most commonly detected herbicides were atrazine, alachlor, metolachlor, prometon, and metribuzin. No relation between streamflow and pesticide concentration was evident.

Storage in alluvial deposits controls the timing of particle delivery from large watersheds, filtering upland erosional signals and delaying benefits from watershed best management practices

NASA Astrophysics Data System (ADS)

Pizzuto, J. E.; Skalak, K.; Karwan, D. L.

2017-12-01

Transport of suspended sediment and sediment-borne constituents (here termed fluvial particles) through large river systems can be significantly influenced by episodic storage in floodplains and other alluvial deposits. Geomorphologists quantify the importance of storage using sediment budgets, but these data alone are insufficient to determine how storage influences the routing of fluvial particles through river corridors across large spatial scales. For steady state systems, models that combine sediment budget data with "waiting time distributions" (to define how long deposited particles remain stored until being remobilized) and velocities during transport events can provide useful predictions. Limited field data suggest that waiting time distributions are well represented by power laws, extending from <1 to >104 years, while the probability of storage defined by sediment budgets varies from 0.1 km-1 for small drainage basins to 0.001 km-1 for the world's largest watersheds. Timescales of particle delivery from large watersheds are determined by storage rather than by transport processes, with most particles requiring 102 -104 years to reach the basin outlet. These predictions suggest that erosional "signals" induced by climate change, tectonics, or anthropogenic activity will be transformed by storage before delivery to the outlets of large watersheds. In particular, best management practices (BMPs) implemented in upland source areas, designed to reduce the loading of fluvial particles to estuarine receiving waters, will not achieve their intended benefits for centuries (or longer). For transient systems, waiting time distributions cannot be constant, but will vary as portions of transient sediment "pulses" enter and are later released from storage. The delivery of sediment pulses under transient conditions can be predicted by adopting the hypothesis that the probability of erosion of stored particles will decrease with increasing "age" (where age is defined as the elapsed time since deposition). Then, waiting time and age distributions for stored particles become predictions based on the architecture of alluvial storage and the tendency for erosional processes to preferentially remove younger deposits, improving assessment of watershed BMPs and other important applications.

Estimating basin scale evapotranspiration (ET) by water balance and remote sensing methods

USGS Publications Warehouse

Senay, G.B.; Leake, S.; Nagler, P.L.; Artan, G.; Dickinson, J.; Cordova, J.T.; Glenn, E.P.

2011-01-01

Evapotranspiration (ET) is an important hydrological process that can be studied and estimated at multiple spatial scales ranging from a leaf to a river basin. We present a review of methods in estimating basin scale ET and its applications in understanding basin water balance dynamics. The review focuses on two aspects of ET: (i) how the basin scale water balance approach is used to estimate ET; and (ii) how ‘direct’ measurement and modelling approaches are used to estimate basin scale ET. Obviously, the basin water balance-based ET requires the availability of good precipitation and discharge data to calculate ET as a residual on longer time scales (annual) where net storage changes are assumed to be negligible. ET estimated from such a basin water balance principle is generally used for validating the performance of ET models. On the other hand, many of the direct estimation methods involve the use of remotely sensed data to estimate spatially explicit ET and use basin-wide averaging to estimate basin scale ET. The direct methods can be grouped into soil moisture balance modelling, satellite-based vegetation index methods, and methods based on satellite land surface temperature measurements that convert potential ET into actual ET using a proportionality relationship. The review also includes the use of complementary ET estimation principles for large area applications. The review identifies the need to compare and evaluate the different ET approaches using standard data sets in basins covering different hydro-climatic regions of the world.

Implications of freshwater flux data from the CMIP5 multimodel output across a set of Northern Hemisphere drainage basins

NASA Astrophysics Data System (ADS)

Bring, Arvid; Asokan, Shilpa M.; Jaramillo, Fernando; Jarsjö, Jerker; Levi, Lea; Pietroń, Jan; Prieto, Carmen; Rogberg, Peter; Destouni, Georgia

2015-06-01

The multimodel ensemble of the Coupled Model Intercomparison Project, Phase 5 (CMIP5) synthesizes the latest research in global climate modeling. The freshwater system on land, particularly runoff, has so far been of relatively low priority in global climate models, despite the societal and ecosystem importance of freshwater changes, and the science and policy needs for such model output on drainage basin scales. Here we investigate the implications of CMIP5 multimodel ensemble output data for the freshwater system across a set of drainage basins in the Northern Hemisphere. Results of individual models vary widely, with even ensemble mean results differing greatly from observations and implying unrealistic long-term systematic changes in water storage and level within entire basins. The CMIP5 projections of basin-scale freshwater fluxes differ considerably more from observations and among models for the warm temperate study basins than for the Arctic and cold temperate study basins. In general, the results call for concerted research efforts and model developments for improving the understanding and modeling of the freshwater system and its change drivers. Specifically, more attention to basin-scale water flux analyses should be a priority for climate model development, and an important focus for relevant model-based advice for adaptation to climate change.

Colloidal alloys with preassembled clusters and spheres.

PubMed

Ducrot, Étienne; He, Mingxin; Yi, Gi-Ra; Pine, David J

2017-06-01

Self-assembly is a powerful approach for constructing colloidal crystals, where spheres, rods or faceted particles can build up a myriad of structures. Nevertheless, many complex or low-coordination architectures, such as diamond, pyrochlore and other sought-after lattices, have eluded self-assembly. Here we introduce a new design principle based on preassembled components of the desired superstructure and programmed nearest-neighbour DNA-mediated interactions, which allows the formation of otherwise unattainable structures. We demonstrate the approach using preassembled colloidal tetrahedra and spheres, obtaining a class of colloidal superstructures, including cubic and tetragonal colloidal crystals, with no known atomic analogues, as well as percolating low-coordination diamond and pyrochlore sublattices never assembled before.

System design optimization for stand-alone photovoltaic systems sizing by using superstructure model

NASA Astrophysics Data System (ADS)

Azau, M. A. M.; Jaafar, S.; Samsudin, K.

2013-06-01

Although the photovoltaic (PV) systems have been increasingly installed as an alternative and renewable green power generation, the initial set up cost, maintenance cost and equipment mismatch are some of the key issues that slows down the installation in small household. This paper presents the design optimization of stand-alone photovoltaic systems using superstructure model where all possible types of technology of the equipment are captured and life cycle cost analysis is formulated as a mixed integer programming (MIP). A model for investment planning of power generation and long-term decision model are developed in order to help the system engineer to build a cost effective system.

All tangled up: how cells direct, manage and exploit topoisomerase function

PubMed Central

Vos, Seychelle M.; Tretter, Elsa M.; Schmidt, Bryan H.; Berger, James M.

2015-01-01

Preface Topoisomerases are complex molecular machines that modulate DNA topology to maintain chromosome superstructure and integrity. Although capable of stand-alone activity in vitro, topoisomerases frequently are linked to larger pathways and systems that resolve specific DNA superstructures and intermediates arising from cellular processes such as DNA repair, transcription, replication, and chromosome compaction. Topoisomerase activity is indispensible to cells, but requires the transient breakage of DNA strands. This property has been exploited, often for significant clinical benefit, by various exogenous agents that interfere with cell proliferation. Despite decades of study, surprising findings involving topoisomerases continue to emerge with respect to their cellular function, regulation, and utility as therapeutic targets. PMID:22108601

Ground-water recharge to and storage in the regolith-fractured crystalline rock aquifer system, Guilford County, North Carolina

USGS Publications Warehouse

Daniel, C. C.; Harned, D.A.

1998-01-01

Quantitative information concerning recharge rates to aquifers and ground water in storage is needed to manage the development of ground- water resources. The amount of ground water available from the regolith-fractured crystalline rock aquifer system in Guilford County, North Carolina, is largely unknown. If historical patterns seen throughout the Piedmont continue into the future, the number of ground- water users in the county can be expected to increase. In order to determine the maximum population that can be supplied by ground water, planners and managers of suburban development must know the amount of ground water that can be withdrawn without exceeding recharge and(or) overdrafting water in long-term storage. Results of the study described in this report help provide this information. Estimates of seasonal and long-term recharge rates were estimated for 15 selected drainage basins and subbasins using streamflow data and an anlytical technique known as hydrograph separation. Methods for determining the quantity of ground water in storage also are described. Guilford County covers approximately 658 square miles in the central part of the Piedmont Province. The population of the county in 1990 was about 347,420; approximately 21 percent of the population depends on ground water as a source of potable supplies. Ground water is obtained from wells tapping the regolith-fractured crystalline rock aquifer system that underlies all of the county. Under natural conditions, recharge to the ground-water system in the county is derived from infiltration of precipitation. Ground-water recharge from precipitation cannot be measured directly; however, an estimate of the amount of precipitation that infiltrates into the ground and ultimately reaches the streams of the region can be determined by the technique of hydrograph separation. Data from 19 gaging stations that measure streamflow within or from Guilford County were analyzed to produce daily estimates of ground-water recharge in 15 drainage basins and subbasins in the county. The recharge estimates were further analyzed to determine seasonal and long-term recharge rates, as well as recharge duration statistics. Mean annual recharge in the 15 basins and subbasins ranges from 4.03 to 9.69 inches per year, with a mean value of 6.28 inches per year for all basins. In general, recharge rates are highest for basins in the northern and northwestern parts of the county and lowest in the southern and southeastern parts of the county. Median recharge rates in the 15 basins range from 2.47 inches per year (184 gallons per day per acre) to 9.15 inches per year (681 gallons per day per acre), with a median value of 4.65 inches per year (346 gallons per day per acre) for all basins. The distribution of recharge rates in the county suggests a correlation between recharge rates and hydrogeologic units (and derived regolith). The highest recharge estimates occur in the northwestern part of Guilford County in basins unlain by felsic igneous intrusive rocks and lesser areas of metasedimentary rocks. Recharge estimates in this area range from 6.37 to 9.33 inches per year. Basins in the southwestern, central, and northeastern parts of the county are underlain primarily by metaigneous rocks of felsic and intermediate compositions, and recharge estimates range from 5.32 to 5.51 inches per year. In the extreme southern and southeastern parts of the county, the lower Deep River subbasin and the lower Haw River subbasins have the lowest estimated recharges at 4.15 and 4.03 inches per year, respectively. Although the areas of these subbasins that lie within Guilford County are underlain primarily by metaigneous rocks of felsic and intermediate compositions, the larger part of these subbasins lies south and southeast of Guilford County in areas underlain by hydrogeologic units of metavolcanic origin. The distribution of recharge rates in the study area is almost the reverse of the distributio

Anisotropic mechanical behaviour of sedimentary basins inferred by advanced radar interferometry above gas storage fields

NASA Astrophysics Data System (ADS)

Teatini, P.; Gambolati, G.; Ferretti, A.

2010-12-01

Natural gas is commonly stored underground in depleted oil and gas fields to provide safe storage capacity and deliverability to market areas where production is limited, or to take advantage of seasonal price swings. In response to summer gas injection and winter gas withdrawal the reservoir expands and contracts with the overlying land that moves accordingly. Depending on the field burial depth, a few kilometres of the upper lithosphere are subject to local three-dimensional deformations with the related cyclic motion of the ground surface being both vertical and horizontal. Advanced Persistent Scatterer Interferometry (PSI) data, obtained by combining ascending and descending RADARSAT-1 images acquired from 2003 to 2008 above gas storage fields located in the sedimentary basin of the Po river plain, Italy, provide reliable measurement of these seasonal vertical ups and downs as well as horizontal displacements to and from the injection/withdrawal wells. Combination of the land surface movements together with an accurate reconstruction of the subsurface geology made available by three-dimensional seismic surveys and long-time records of fluid pore pressure within the 1000-1500 m deep reservoirs has allowed for the development of an accurate 3D poro-mechanical finite-element model of the gas injection/removal occurrence. Model calibration based on the observed cyclic motions, which are on the range of 10-15 mm and 5-10 mm in the vertical and horizontal west-east directions, respectively, helps characterize the nonlinear hysteretic geomechanical properties of the basin. First, using a basin-scale relationship between the oedometric rock compressibility cM in virgin loading conditions versus the effective intergranular stress derived from previous experimental studies, the modeling results show that the ratio s between loading and unloading-reloading cM is about 4, consistent with in-situ expansions measured by the radioactive marker technique in similar reservoirs of the same basin. Even more interestingly, a traditional isotropic stress-strain model does not prove suitable for simultaneously matching both the vertical and the horizontal displacements. The basin overall 3D deformation is indeed well captured by a transversally isotropic model where the medium elastic properties in a horizontal plane differ from those in a vertical plane. In particular, the satellite observations are successfully predicted by setting s=4 and with a horizontal/vertical Young modulus ratio of 3, a Poisson ratio equal to 0.15 and 0.25 in the horizontal and vertical plane, respectively, and the same shear modulus in the two directions.

Linking plant functional traits and forest carbon stocks in the Congo Basin

NASA Astrophysics Data System (ADS)

Kearsley, Elizabeth; Verbeeck, Hans; Hufkens, Koen; Lewis, Simon; Huygens, Dries; Beeckman, Hans; Steppe, Kathy; Boeckx, Pascal

2013-04-01

Accurate estimates of the amount of carbon stored in tropical forests represent crucial baseline data for recent climate change mitigation policies. Such data are needed to quantify possible emissions due to deforestation and forest degradation, and to evaluate the potential of these forests to act as carbon sinks. Currently, only rough estimates of the carbon stocks for Central African tropical forests are available due to a lack of field data, and little is known about the response of these stocks to climate change. We present the first ground-based carbon stock data for the central Congo Basin in Yangambi, D. R. Congo, based on data of 20 inventory plots of 1 ha covering different forest types. We found an average aboveground carbon stock of 163 ± 19 Mg C ha-1 for intact old-growth forest, which is significantly lower than the stocks recorded in the outer regions of the Congo Basin. Commonly studied drivers for variations of carbon stocks include climatic and edaphic factors, but detailed trait-based studies are lacking. We identified a significant difference in height-diameter relations across the Congo Basin as a driver for spatial differences in carbon stocks. The study of a more detailed interaction of the environment and the available tree species pool as drivers for differences in carbon storage could have large implications. The effect of the species pool on carbon storage can be large since species differ in their ability to sequester carbon, and the collective functional characteristics of plant communities could be a major driver of carbon accumulation. The use of a trait-based approach shows high potential for identifying and quantifying carbon stocks as an ecosystem service. We test for associations between functional trait values and carbon storage across multiple regrowth and old-growth forests types in the Yangambi study area, with soil properties and climate similar for all plots. A selection of traits associated with carbon dynamics is made, including leaf traits (specific leaf area, leaf dry matter content, leaf carbon concentration, leaf nitrogen and phosphorus concentration, 13C, 15N, 18O), stem traits (wood density, vessel diameter), and vegetative traits (tree height, light tolerance), studying 990 individuals covering 111 species. To develop a more coherent understanding of ecosystem functioning, the related carbon sequestration, and the contribution of climate and soil factors in tropical forests in the Congo Basin, we present a preliminary spatial study of plant functional traits and diversity by comparing several sites across the Congo Basin.

Comprehensive, Process-based Identification of Hydrologic Models using Satellite and In-situ Water Storage Data: A Multi-objective calibration Approach

NASA Astrophysics Data System (ADS)

Abdo Yassin, Fuad; Wheater, Howard; Razavi, Saman; Sapriza, Gonzalo; Davison, Bruce; Pietroniro, Alain

2015-04-01

The credible identification of vertical and horizontal hydrological components and their associated parameters is very challenging (if not impossible) by only constraining the model to streamflow data, especially in regions where the vertical processes significantly dominate the horizontal processes. The prairie areas of the Saskatchewan River basin, a major water system in Canada, demonstrate such behavior, where the hydrologic connectivity and vertical fluxes are mainly controlled by the amount of surface and sub-surface water storages. In this study, we develop a framework for distributed hydrologic model identification and calibration that jointly constrains the model response (i.e., streamflows) as well as a set of model state variables (i.e., water storages) to observations. This framework is set up in the form of multi-objective optimization, where multiple performance criteria are defined and used to simultaneously evaluate the fidelity of the model to streamflow observations and observed (estimated) changes of water storage in the gridded landscape over daily and monthly time scales. The time series of estimated changes in total water storage (including soil, canopy, snow and pond storages) used in this study were derived from an experimental study enhanced by the information obtained from the GRACE satellite. We test this framework on the calibration of a Land Surface Scheme-Hydrology model, called MESH (Modélisation Environmentale Communautaire - Surface and Hydrology), for the Saskatchewan River basin. Pareto Archived Dynamically Dimensioned Search (PA-DDS) is used as the multi-objective optimization engine. The significance of using the developed framework is demonstrated in comparison with the results obtained through a conventional calibration approach to streamflow observations. The approach of incorporating water storage data into the model identification process can more potentially constrain the posterior parameter space, more comprehensively evaluate the model fidelity, and yield more credible predictions.

Terrestrial Waters and Sea Level Variations on Interannual Time Scale

NASA Technical Reports Server (NTRS)

Llovel, W.; Becker, M.; Cazenave, A.; Jevrejeva, S.; Alkama, R.; Decharme, B.; Douville, H.; Ablain, M.; Beckley, B.

2011-01-01

On decadal to multi-decadal time scales, thermal expansion of sea waters and land ice loss are the main contributors to sea level variations. However, modification of the terrestrial water cycle due to climate variability and direct anthropogenic forcing may also affect sea level. For the past decades, variations in land water storage and corresponding effects on sea level cannot be directly estimated from observations because these are almost non-existent at global continental scale. However, global hydrological models developed for atmospheric and climatic studies can be used for estimating total water storage. For the recent years (since mid-2002), terrestrial water storage change can be directly estimated from observations of the GRACE space gravimetry mission. In this study, we analyse the interannual variability of total land water storage, and investigate its contribution to mean sea level variability at interannual time scale. We consider three different periods that, each, depend on data availability: (1) GRACE era (2003-2009), (2) 1993-2003 and (3) 1955-1995. For the GRACE era (period 1), change in land water storage is estimated using different GRACE products over the 33 largest river basins worldwide. For periods 2 and 3, we use outputs from the ISBA-TRIP (Interactions between Soil, Biosphere, and Atmosphere-Total Runoff Integrating Pathways) global hydrological model. For each time span, we compare change in land water storage (expressed in sea level equivalent) to observed mean sea level, either from satellite altimetry (periods 1 and 2) or tide gauge records (period 3). For each data set and each time span, a trend has been removed as we focus on the interannual variability. We show that whatever the period considered, interannual variability of the mean sea level is essentially explained by interannual fluctuations in land water storage, with the largest contributions arising from tropical river basins.

Geologic framework for the national assessment of carbon dioxide storage resources: Greater Green River Basin, Wyoming, Colorado, and Utah, and Wyoming-Idaho-Utah Thrust Belt: Chapter E in Geologic framework for the national assessment of carbon dioxide storage resources

USGS Publications Warehouse

Buursink, Marc L.; Slucher, Ernie R.; Brennan, Sean T.; Doolan, Colin A.; Drake II, Ronald M.; Merrill, Matthew D.; Warwick, Peter D.; Blondes, Madalyn S.; Freeman, P.A.; Cahan, Steven M.; DeVera, Christina A.; Lohr, Celeste D.

2014-01-01

The 2007 Energy Independence and Security Act (Public Law 110–140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO2). The methodology used by the USGS for the national CO2 assessment follows up on previous USGS work. The methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of 14 storage assessment units (SAUs) in Ordovician to Upper Cretaceous sedimentary rocks within the Greater Green River Basin (GGRB) of Wyoming, Colorado, and Utah, and eight SAUs in Ordovician to Upper Cretaceous sedimentary rocks within the Wyoming-Idaho-Utah Thrust Belt (WIUTB). The GGRB and WIUTB are contiguous with nearly identical geologic units; however, the GGRB is larger in size, whereas the WIUTB is more structurally complex. This report focuses on the characteristics, specified in the methodology, that influence the potential CO2 storage resource in the SAUs. Specific descriptions of the SAU boundaries, as well as their sealing and reservoir units, are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are typically provided to illustrate geologic factors critical to the assessment. This geologic information was employed, as specified in the USGS methodology, to calculate a probabilistic distribution of potential storage resources in each SAU. Figures in this report show SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one square mile and are derived from interpretations of variably attributed well data and a digital compilation that is known not to include all drilling.

Identification and simulation of space-time variability of past hydrological drought events in the Limpopo River basin, southern Africa

NASA Astrophysics Data System (ADS)

Trambauer, P.; Maskey, S.; Werner, M.; Pappenberger, F.; van Beek, L. P. H.; Uhlenbrook, S.

2014-08-01

Droughts are widespread natural hazards and in many regions their frequency seems to be increasing. A finer-resolution version (0.05° × 0.05°) of the continental-scale hydrological model PCRaster Global Water Balance (PCR-GLOBWB) was set up for the Limpopo River basin, one of the most water-stressed basins on the African continent. An irrigation module was included to account for large irrigated areas of the basin. The finer resolution model was used to analyse hydrological droughts in the Limpopo River basin in the period 1979-2010 with a view to identifying severe droughts that have occurred in the basin. Evaporation, soil moisture, groundwater storage and runoff estimates from the model were derived at a spatial resolution of 0.05° (approximately 5 km) on a daily timescale for the entire basin. PCR-GLOBWB was forced with daily precipitation and temperature obtained from the ERA-Interim global atmospheric reanalysis product from the European Centre for Medium-Range Weather Forecasts. Two agricultural drought indicators were computed: the Evapotranspiration Deficit Index (ETDI) and the Root Stress Anomaly Index (RSAI). Hydrological drought was characterised using the Standardized Runoff Index (SRI) and the Groundwater Resource Index (GRI), which make use of the streamflow and groundwater storage resulting from the model. Other more widely used meteorological drought indicators, such as the Standardized Precipitation Index (SPI) and the Standardized Precipitation Evaporation Index (SPEI), were also computed for different aggregation periods. Results show that a carefully set-up, process-based model that makes use of the best available input data can identify hydrological droughts even if the model is largely uncalibrated. The indicators considered are able to represent the most severe droughts in the basin and to some extent identify the spatial variability of droughts. Moreover, results show the importance of computing indicators that can be related to hydrological droughts, and how these add value to the identification of hydrological droughts and floods and the temporal evolution of events that would otherwise not have been apparent when considering only meteorological indicators. In some cases, meteorological indicators alone fail to capture the severity of the hydrological drought. Therefore, a combination of some of these indicators (e.g. SPEI-3, SRI-6 and SPI-12 computed together) is found to be a useful measure for identifying agricultural to long-term hydrological droughts in the Limpopo River basin. Additionally, it was possible to undertake a characterisation of the drought severity in the basin, indicated by its time of occurrence, duration and intensity.

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia; a summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

USGS Publications Warehouse

Skrobialowski, S.C.

1996-01-01

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

Characterizing water resources of the Nile Basin using remotely sensed data

NASA Astrophysics Data System (ADS)

Mekonnen, Z. T.; Gebremichael, M.; Demissie, S. S.

2015-12-01

The Nile is one of the largest river basin in the world with a rich biodiversity as well supporting the lives of 450 million people residing within the 11 riparian countries. This vital resource is under a growing stress due to population growth, rapid development and climate change. In this work, we explore the use of the latest various remote sensing products to capture the water resource of the basin: rainfall from GPM and TRMM, soil moisture from SMAP and SMOS, evapotranspiration from MODIS and EUMETSAT LSA-SAF, and total water storage variations from GRACE. The satellite estimates were supplemented and checked by ground measurements whenever possible. Our results show that spatiotemporal variations of the basin's water resources characteristics are well captured by remote sensing products rather than the scarce point measurements that currently exist. Several aspects of our results will be presented and discussed.

Multiple-Purpose Project. Osage River Basin, Big Bull Creek, Kansas. Hillsdale Lake Operation and Maintenance Manual. Appendix V. Embankment Criteria and Performance Report.

DTIC Science & Technology

1984-09-01

and Mississippi Rivers; provide storage for Increasing low - water flows for the Improvement of water supply, abatement of pollution, and improvement...des Cygnes, Osage and Lower Missourl River. Hillsdale Lake will have storage for sediment, low -flow supplementation, water supply, and flood control...will furnish a water supply withdrawal of 32 cubic feet per second on a 2 percent chance dependability and low flow supplementation of 13 cubic feet

Crystal Phase and Architecture Engineering of Lotus-Thalamus-Shaped Pt-Ni Anisotropic Superstructures for Highly Efficient Electrochemical Hydrogen Evolution.

PubMed

Zhang, Zhicheng; Liu, Guigao; Cui, Xiaoya; Chen, Bo; Zhu, Yihan; Gong, Yue; Saleem, Faisal; Xi, Shibo; Du, Yonghua; Borgna, Armando; Lai, Zhuangchai; Zhang, Qinghua; Li, Bing; Zong, Yun; Han, Yu; Gu, Lin; Zhang, Hua

2018-06-07

The rational design and synthesis of anisotropic 3D nanostructures with specific composition, morphology, surface structure, and crystal phase is of significant importance for their diverse applications. Here, the synthesis of well-crystalline lotus-thalamus-shaped Pt-Ni anisotropic superstructures (ASs) via a facile one-pot solvothermal method is reported. The Pt-Ni ASs with Pt-rich surface are composed of one Ni-rich "core" with face-centered cubic (fcc) phase, Ni-rich "arms" with hexagonal close-packed phase protruding from the core, and facet-selectively grown Pt-rich "lotus seeds" with fcc phase on the end surfaces of the "arms." Impressively, these unique Pt-Ni ASs exhibit superior electrocatalytic activity and stability toward the hydrogen evolution reaction under alkaline conditions compared to commercial Pt/C and previously reported electrocatalysts. The obtained overpotential is as low as 27.7 mV at current density of 10 mA cm -2 , and the turnover frequency reaches 18.63 H 2 s -1 at the overpotential of 50 mV. This work provides a new strategy for the synthesis of highly anisotropic superstructures with a spatial heterogeneity to boost their promising application in catalytic reactions. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bringing nanomagnetism to the mesoscale with artificial amorphous structures

NASA Astrophysics Data System (ADS)

Muscas, G.; Brucas, R.; Jönsson, P. E.

2018-05-01

In the quest for materials with emergent or improved properties, an effective route is to create artificial superstructures. Novel properties emerge from the coupling between the phases, but the strength of this coupling depends on the quality of the interfaces. Atomic control of crystalline interfaces is notoriously complicated and to elude that obstacle, we suggest here an all-amorphous design. Starting from a model amorphous iron alloy, we locally tune the magnetic behavior by creating boron-doped regions by means of ion implantation through a lithographic mask. This process preserves the amorphous environment, creating a non-topographic magnetic superstructure with smooth interfaces and no structural discontinuities. The absence of inhomogeneities acting as pinning centers for the magnetization reversal is demonstrated by the formation of magnetic vortexes for ferromagnetic disks as large as 20 µm in diameter embedded within a paramagnetic matrix. Rigid exchange coupling between two amorphous ferromagnetic phases in a microstructured sample is evidenced by an investigation involving first-order reversal curves. The sample consists of a soft matrix with embedded elements constituting a hard phase where the anisotropy originates from an elongated shape of the elements. We provide an intuitive explanation for the micrometer-range exchange coupling mechanism and discuss how to tailor the properties of all-amorphous superstructures.

Novel EGCG assisted ultrasound synthesis of self-assembled Ca2SiO4:Eu(3+) hierarchical superstructures: Photometric characteristics and LED applications.

PubMed

Venkataravanappa, M; Nagabhushana, H; Darshan, G P; Daruka Prasad, B; Vijayakumar, G R; Premkumar, H B; Udayabhanu

2016-11-01

This paper reports for the first time ultrasound, EGCG assisted synthesis of pure and Eu(3+) (1-5mol%) activated Ca2SiO4 nanophosphors having self-assembled superstructures with high purity. The shape, size and morphology of the product were tuned by controlling influential parameters. It was found that morphology was highly dependent on EGCG concentration, sonication time, pH and sonication power. The probable formation mechanism for various hierarchical superstructures was proposed. The PL studies of Ca2SiO4:Eu(3+) phosphors can be effectively excited by the near ultraviolet (UV) (396nm) light and exhibited strong red emission around 613nm, which was attributed to the Eu(3+) ((5)D0→(7)F2) transition. The concentration quenching phenomenon was explained based on energy transfer between defect and Eu(3+) ions, electron-phonon coupling and Eu(3+)-Eu(3+) interaction. The Judd-Ofelt intensity parameters and radiative properties were estimated by using PL emission spectra. The photometric studies indicate that the obtained phosphors could be a promising red component for possible applications in the field of white light emitting diodes. Copyright © 2016 Elsevier B.V. All rights reserved.