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Sample records for su3-flavor chiral perturbation

  1. Strange Baryon Electromagnetic Form Factors and SU(3) Flavor Symmetry Breaking

    SciTech Connect

    Lin, Huey-Wen; Orginos, Konstantinos

    2009-01-01

    We study the nucleon, Sigma and cascade octet baryon electromagnetic form factors and the effects of SU(3) flavor symmetry breaking from 2+1-flavor lattice calculations. We find that electric and magnetic radii are similar; the maximum discrepancy is about 10\\%. In the pion-mass region we explore, both the quark-component and full-baryon moments have small SU(3) symmetry breaking. We extrapolate the charge radii and the magnetic moments using three-flavor heavy-baryon chiral perturbation theory (HBXPT). The systematic errors due to chiral and continuum extrapolations remain significant, giving rise to charge radii for $p$ and $\\Sigma^-$ that are 3--4 standard deviations away from the known experimental ones. Within these systematics the predicted $\\Sigma^+$ and $\\Xi^-$ radii are 0.67(5) and 0.306(15)~fm$^2$ respectively. When the next-to-next-to-leading order of HBXPT is included, the extrapolated magnetic moments are less than 3 standard deviations away from PDG values, and the d

  2. Chiral perturbation theory with nucleons

    SciTech Connect

    Meissner, U.G.

    1991-09-01

    I review the constraints posed on the interactions of pions, nucleons and photons by the spontaneously broken chiral symmetry of QCD. The framework to perform these calculations, chiral perturbation theory, is briefly discussed in the meson sector. The method is a simultaneous expansion of the Greens functions in powers of external moments and quark masses around the massless case, the chiral limit. To perform this expansion, use is made of a phenomenological Lagrangian which encodes the Ward-identities and pertinent symmetries of QCD. The concept of chiral power counting is introduced. The main part of the lectures of consists in describing how to include baryons (nucleons) and how the chiral structure is modified by the fact that the nucleon mass in the chiral limit does not vanish. Particular emphasis is put on working out applications to show the strengths and limitations of the methods. Some processes which are discussed are threshold photopion production, low-energy compton scattering off nucleons, {pi}N scattering and the {sigma}-term. The implications of the broken chiral symmetry on the nuclear forces are briefly described. An alternative approach, in which the baryons are treated as very heavy fields, is touched upon.

  3. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    DOE PAGESBeta

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre

    2015-10-08

    Here, we study SU(3) flavor-breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD θ¯ term. We work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ¯ term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. [Phys. Lett. B 88, 123 (1979)]. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation that is respected by loopmore » corrections up to the order we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g¯0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. In addition, we derive semiprecise values for CP-violating coupling constants between heavier mesons and nucleons with ~30% uncertainty and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.« less

  4. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    DOE PAGESBeta

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the ordermore » we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.« less

  5. Lattice calculation of SU(3) flavor breaking ratios in B0-B¯0 mixing

    NASA Astrophysics Data System (ADS)

    Gadiyak, Valeriya; Loktik, Oleg

    2005-12-01

    We present an unquenched lattice calculation for the SU(3) flavor breaking ratios of the heavy-light decay constants and the ΔB=2 matrix elements. The calculation was performed on 163×32 lattices with two dynamical flavors of domain-wall quarks and inverse lattice spacing 1/a=1.69(5)GeV. Heavy quarks were implemented using an improved lattice formulation of the static approximation. In the infinite heavy-quark mass limit we obtain fBs/fBd=1.29(4)(6), BBs/BBd=1.06(6)(4), ξ=1.33(8)(8) where the first error is statistical and the second systematic.

  6. Nucleon-Nucleon Scattering Parameters in the Limit of SU(3) Flavor Symmetry

    SciTech Connect

    Beane, Silas; Chang, Emanuel; Savage, Martin; Lin, Huey-Wen; Orginos, Konstantinos; Cohen, Saul; Detmold, William; Luu, Tom; Parreno, Assumpta; Junnarkar, Parikshit; Walker-Loud, Andre Paul

    2013-08-01

    The scattering lengths and effective ranges that describe low-energy nucleon-nucleon scattering are calculated in the limit of SU(3)-flavor symmetry at the physical strange-quark mass with Lattice Quantum Chromodynamics. The calculations are performed with an isotropic clover discretization of the quark action in three volumes with spatial extents of L ~ 3.4 fm, 4.5 fm and 6.7 fm, and with a lattice spacing of b ~ 0.145 fm. With determinations of the energies of the two-nucleon systems both of which contain bound states at these light-quark masses at rest and moving in the lattice volume, Luscher's method is used to determine the low-energy phase shift in each channel, from which the scattering length and effective range are obtained. The scattering parameters in the {sup 1}S{sub 0} channel are found to be m{sub π}a{sup ({sup 1}S{sub 0})} = 9.51+/-0.74+/-1.00 and m{sub π}r{sup ({sup 1}S{sub 0})} = 4.76+/-0.37+/-0.40, and in the {sup 3}S{sub 1} channel are m{sub π}a{sup ({sup 3}S{sub 1})} = 7.45+/-0.57+/-0.71 and m{sub π}r{sup ({sup 3}S{sub 1})} = 3.71+/-0.28+/-0.28. These values are consistent with the two-nucleon system exhibiting Wigner's supermultiplet symmetry, which becomes exact in the limit of large-N{sub c}.

  7. Staggered heavy baryon chiral perturbation theory

    SciTech Connect

    Bailey, Jon A.

    2008-03-01

    Although taste violations significantly affect the results of staggered calculations of pseudoscalar and heavy-light mesonic quantities, those entering staggered calculations of baryonic quantities have not been quantified. Here I develop staggered chiral perturbation theory in the light-quark baryon sector by mapping the Symanzik action into heavy baryon chiral perturbation theory. For 2+1 dynamical quark flavors, the masses of flavor-symmetric nucleons are calculated to third order in partially quenched and fully dynamical staggered chiral perturbation theory. To this order the expansion includes the leading chiral logarithms, which come from loops with virtual decuplet-like states, as well as terms of O(m{sub {pi}}{sup 3}), which come from loops with virtual octet-like states. Taste violations enter through the meson propagators in loops and tree-level terms of O(a{sup 2}). The pattern of taste symmetry breaking and the resulting degeneracies and mixings are discussed in detail. The resulting chiral forms are appropriate to lattice results obtained with operators already in use and could be used to study the restoration of taste symmetry in the continuum limit. I assume that the fourth root of the fermion determinant can be incorporated in staggered chiral perturbation theory using the replica method.

  8. Staggered heavy baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Bailey, Jon A.

    2008-03-01

    Although taste violations significantly affect the results of staggered calculations of pseudoscalar and heavy-light mesonic quantities, those entering staggered calculations of baryonic quantities have not been quantified. Here I develop staggered chiral perturbation theory in the light-quark baryon sector by mapping the Symanzik action into heavy baryon chiral perturbation theory. For 2+1 dynamical quark flavors, the masses of flavor-symmetric nucleons are calculated to third order in partially quenched and fully dynamical staggered chiral perturbation theory. To this order the expansion includes the leading chiral logarithms, which come from loops with virtual decuplet-like states, as well as terms of O(mπ3), which come from loops with virtual octet-like states. Taste violations enter through the meson propagators in loops and tree-level terms of O(a2). The pattern of taste symmetry breaking and the resulting degeneracies and mixings are discussed in detail. The resulting chiral forms are appropriate to lattice results obtained with operators already in use and could be used to study the restoration of taste symmetry in the continuum limit. I assume that the fourth root of the fermion determinant can be incorporated in staggered chiral perturbation theory using the replica method.

  9. Tests of Chiral Perturbation Theory with COMPASS

    SciTech Connect

    Friedrich, Jan

    2010-12-28

    The COMPASS experiment at CERN studies with high precision pion-photon induced reactions on nuclear targets via the Primakoff effect. This offers the possibility to test chiral perturbation theory (ChPT) in various channels: Pion Compton scattering allows to clarify the longstanding question of the pion polarisabilities, single neutral pion production is related to the chiral anomaly, and for the two-pion production cross sections exist as yet untested ChPT predictions.

  10. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    SciTech Connect

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre

    2015-10-08

    Here, we study SU(3) flavor-breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD θ¯ term. We work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ¯ term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. [Phys. Lett. B 88, 123 (1979)]. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation that is respected by loop corrections up to the order we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g¯0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. In addition, we derive semiprecise values for CP-violating coupling constants between heavier mesons and nucleons with ~30% uncertainty and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.

  11. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    SciTech Connect

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the order we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.

  12. Applications of partially quenched chiral perturbation theory

    SciTech Connect

    Golterman, M.F.; Leung, K.C.

    1998-05-01

    Partially quenched theories are theories in which the valence- and sea-quark masses are different. In this paper we calculate the nonanalytic one-loop corrections of some physical quantities: the chiral condensate, weak decay constants, Goldstone boson masses, B{sub K}, and the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude, using partially quenched chiral perturbation theory. Our results for weak decay constants and masses agree with, and generalize, results of previous work by Sharpe. We compare B{sub K} and the K{sup +} decay amplitude with their real-world values in some examples. For the latter quantity, two other systematic effects that plague lattice computations, namely, finite-volume effects and unphysical values of the quark masses and pion external momenta, are also considered. We find that typical one-loop corrections can be substantial. {copyright} {ital 1998} {ital The American Physical Society}

  13. The baryon vector current in the combined chiral and 1/Nc expansions

    SciTech Connect

    Flores-Mendieta, Ruben; Goity, Jose L

    2014-12-01

    The baryon vector current is computed at one-loop order in large-Nc baryon chiral perturbation theory, where Nc is the number of colors. Loop graphs with octet and decuplet intermediate states are systematically incorporated into the analysis and the effects of the decuplet-octet mass difference and SU(3) flavor symmetry breaking are accounted for. There are large-Nc cancellations between different one-loop graphs as a consequence of the large-Nc spin-flavor symmetry of QCD baryons. The results are compared against the available experimental data through several fits in order to extract information about the unknown parameters. The large-Nc baryon chiral perturbation theory predictions are in very good agreement both with the expectations from the 1/Nc expansion and with the experimental data. The effect of SU(3) flavor symmetry breaking for the |Delta S|=1 vector current form factors f1(0) results in a reduction by a few percent with respect to the corresponding SU(3) symmetric values.

  14. One-loop chiral perturbation theory with two fermion representations

    NASA Astrophysics Data System (ADS)

    DeGrand, Thomas; Golterman, Maarten; Neil, Ethan T.; Shamir, Yigal

    2016-07-01

    We develop chiral perturbation theory for chirally broken theories with fermions in two different representations of the gauge group. Any such theory has a nonanomalous singlet U (1 )A symmetry, yielding an additional Nambu-Goldstone boson when spontaneously broken. We calculate the next-to-leading order corrections for the pseudoscalar masses and decay constants, which include the singlet Nambu-Goldstone boson, as well as for the two condensates. The results can be generalized to more than two representations.

  15. Chiral perturbation theory with tensor sources

    SciTech Connect

    Cata, Oscar; Cata, Oscar; Mateu, Vicent

    2007-05-21

    We construct the most general chirally-invariant Lagrangian for mesons in the presence of external sources coupled to the tensor current \\bar psi sigma_mu nu psi. In order to have only even terms in the chiral expansion, we consider the new source of O(p2). With this choice, we build the even-parity effective Lagrangian up to the p6-order (NLO). While there are only 4 new terms at the p4-order, at p6-order we find 78 terms for n_f=2 and 113 terms for n_f=3. We provide a detailed discussion on the different mechanisms that ensure that our final set of operators is complete and non-redundant. We also examine the odd-parity sector, to conclude that the first operators appear at the p8-order (NNLO).

  16. Staggered chiral perturbation theory in the two-flavor case

    SciTech Connect

    Du Xining

    2010-07-01

    I study two-flavor staggered chiral perturbation theory in the light pseudoscalar sector. The pion mass and decay constant are calculated through next-to-leading order in the partially-quenched case. In the limit where the strange quark mass is large compared to the light quark masses and the taste splittings, I show that the SU(2) staggered chiral theory emerges from the SU(3) staggered chiral theory, as expected. Explicit relations between SU(2) and SU(3) low energy constants and taste-violating parameters are given. The results are useful for SU(2) chiral fits to asqtad data and allow one to incorporate effects from varying strange quark masses.

  17. Electroproduction of pions at threshold in chiral perturbation theory

    SciTech Connect

    Lee, T.S.H.; Bernard, V.; Kaiser, N.; Meissner, U.G.

    1995-08-01

    The electroproduction of pions off protons close to threshold is studied within the framework of baryon chiral perturbation theory. The approach is based on the fundamental QCD property that at low energies the strong interactions are dictated by the spontaneously broken chiral symmetry. The calculation was done up to the 1-loop level by carrying out order-by-order renormalization procedures. A thorough study of the low-energy theorems related to electroproduction of pions was carried out. Our study showed how the axial radius of the nucleon can be related to the S-wave multipoles E{sub 0+}{sup (-)} and L{sub 0+}{sup (-)}.

  18. Staggered chiral perturbation theory for heavy-light mesons

    NASA Astrophysics Data System (ADS)

    Aubin, C.; Bernard, C.

    2006-01-01

    We incorporate heavy-light mesons into staggered chiral perturbation theory (SχPT), working to leading order in 1/mQ, where mQ is the heavy-quark mass. At first nontrivial order in the chiral expansion, staggered taste violations affect the chiral logarithms for heavy-light quantities only through the light-meson propagators in loops. There are also new analytic contributions coming from additional terms in the Lagrangian involving heavy-light and light mesons. Using this heavy-light SχPT, we perform the one-loop calculation of the B (or D) meson leptonic decay constant in the partially quenched and full QCD cases. In our treatment, we assume the validity both of the “fourth root trick” to reduce four staggered tastes to one, and of the SχPT prescription to represent this trick by insertions of factors of 1/4 for each sea-quark loop.

  19. Heavy-light semileptonic decays in staggered chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Aubin, C.; Bernard, C.

    2007-07-01

    We calculate the form factors for the semileptonic decays of heavy-light pseudoscalar mesons in partially quenched staggered chiral perturbation theory (SχPT), working to leading order in 1/mQ, where mQ is the heavy-quark mass. We take the light meson in the final state to be a pseudoscalar corresponding to the exact chiral symmetry of staggered quarks. The treatment assumes the validity of the standard prescription for representing the staggered “fourth-root trick” within SχPT by insertions of factors of 1/4 for each sea-quark loop. Our calculation is based on an existing partially quenched continuum chiral perturbation theory calculation with degenerate sea quarks by Bećirević, Prelovsek, and Zupan, which we generalize to the staggered (and nondegenerate) case. As a byproduct, we obtain the continuum partially quenched results with nondegenerate sea quarks. We analyze the effects of nonleading chiral terms, and find a relation among the coefficients governing the analytic valence mass dependence at this order. Our results are useful in analyzing lattice computations of form factors B→π and D→K, when the light quarks are simulated with the staggered action.

  20. B{sub K} in staggered chiral perturbation theory

    SciTech Connect

    Water, Ruth S. van de; Sharpe, Stephen R.

    2006-01-01

    We calculate the kaon B parameter, B{sub K}, to next-to-leading order in staggered chiral perturbation theory. We find expressions for partially quenched QCD with three sea quarks, quenched QCD, and full QCD with m{sub u}=m{sub d}{ne}m{sub s}. We extend the usual power counting to include the effects of using perturbative (rather than nonperturbative) matching factors. Taste breaking enters through the O(a{sup 2}) terms in the effective action, through O(a{sup 2}) terms from the discretization of operators, and through the truncation of matching factors. These effects cause mixing with several additional operators, complicating the chiral and continuum extrapolations. In addition to the staggered expressions, we present B{sub K} at next-to-leading order in continuum PQ{chi}PT for N{sub f}=3 sea quarks with m{sub u}=m{sub d}{ne}m{sub s}.

  1. Topological susceptibility in staggered fermion chiral perturbation theory

    SciTech Connect

    Billeter, Brian; DeTar, Carleton; Osborn, James

    2004-10-01

    The topological susceptibility of the vacuum in quantum chromodynamics has been simulated numerically using the Asqtad improved staggered fermion formalism. At nonzero lattice spacing, the residual fermion doublers (fermion tastes) in the staggered fermion formalism give contributions to the susceptibility that deviate from conventional continuum chiral perturbation theory. In this brief report, we estimate the taste-breaking artifact and compare it with results of recent simulations, finding that it accounts for roughly half of the scaling violation.

  2. Including the {delta}(1232) resonance in baryon chiral perturbation theory

    SciTech Connect

    Hacker, C.; Wies, N.; Scherer, S.; Gegelia, J.

    2005-11-01

    Baryon chiral perturbation theory with explicit {delta}(1232) degrees of freedom is considered. The most general interactions of pions, nucleons, and {delta} consistent with all underlying symmetries as well as with the constraint structure of higher-spin fields are constructed. By use of the extended on-mass-shell renormalization scheme, a manifestly Lorentz-invariant effective-field theory with a systematic power counting is obtained. As applications, we discuss the mass of the nucleon, the pion-nucleon {sigma} term, and the pole of the {delta} propagator.

  3. Improving the ultraviolet behavior in baryon chiral perturbation theory

    SciTech Connect

    Djukanovic, D.; Schindler, M.R.; Scherer, S.; Gegelia, J.

    2005-08-15

    We introduce a new formulation of baryon chiral perturbation theory which improves the ultraviolet behavior of propagators and can be interpreted as a smooth cutoff regularization scheme. It is equivalent to the standard approach, preserves all symmetries, and therefore satisfies the Ward identities. Our formulation is equally well defined in the vacuum, one-nucleon, and few-nucleon sectors of the theory. The equations (Bethe-Salpeter, Lippmann-Schwinger, etc.) for the scattering amplitudes of the few-nucleon sector are free of divergences in the new approach. Unlike the usual cutoff regularization, our 'cutoffs' are parameters of the Lagrangian and do not have to be removed.

  4. Chiral perturbation theory and off-shell electromagnetic form factors

    SciTech Connect

    Rudy, T.E.; Fearing, H.W.; Scherer, S.

    1995-05-10

    The off-shell electromagnetic vertex of pions and kaons is calculated to {ital O}({ital p}{sup 4}) in the momentum expansion within the framework of chiral perturbation theory to one loop. The formalism of Gasser and Leutwyler is extended to accommodate the most general form for off-shell Green`s functions in the pseudoscalar meson sector. To that end we identify the structures at {ital O}({ital p}{sup 4}) which were initially removed by using the equation of motion of the lowest-order lagrangian. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  5. Staggered chiral perturbation theory for heavy-light mesons

    SciTech Connect

    Aubin, C.; Bernard, C.

    2006-01-01

    We incorporate heavy-light mesons into staggered chiral perturbation theory (S{chi}PT), working to leading order in 1/m{sub Q}, where m{sub Q} is the heavy-quark mass. At first nontrivial order in the chiral expansion, staggered taste violations affect the chiral logarithms for heavy-light quantities only through the light-meson propagators in loops. There are also new analytic contributions coming from additional terms in the Lagrangian involving heavy-light and light mesons. Using this heavy-light S{chi}PT, we perform the one-loop calculation of the B (or D) meson leptonic decay constant in the partially quenched and full QCD cases. In our treatment, we assume the validity both of the 'fourth root trick' to reduce four staggered tastes to one, and of the S{chi}PT prescription to represent this trick by insertions of factors of 1/4 for each sea-quark loop.

  6. Staggered chiral perturbation theory at next-to-leading order

    SciTech Connect

    Sharpe, Stephen R.; Van de Water, Ruth S.

    2005-06-01

    We study taste and Euclidean rotational symmetry violation for staggered fermions at nonzero lattice spacing using staggered chiral perturbation theory. We extend the staggered chiral Lagrangian to O(a{sup 2}p{sup 2}), O(a{sup 4}), and O(a{sup 2}m), the orders necessary for a full next-to-leading order calculation of pseudo-Goldstone boson masses and decay constants including analytic terms. We then calculate a number of SO(4) taste-breaking quantities, which involve only a small subset of these next-to-leading order operators. We predict relationships between SO(4) taste-breaking splittings in masses, pseudoscalar decay constants, and dispersion relations. We also find predictions for a few quantities that are not SO(4) breaking. All these results hold also for theories in which the fourth root of the fermionic determinant is taken to reduce the number of quark tastes; testing them will therefore provide evidence for or against the validity of this trick.

  7. Virtual Compton scattering off the nucleon in chiral perturbation theory

    SciTech Connect

    Hemmert, T.R.; Holstein, B.R.; Knoechlein, G.; Scherer, S.

    1997-03-01

    We investigate the spin-independent part of the virtual Compton scattering (VCS) amplitude off the nucleon within the framework of chiral perturbation theory. We perform a consistent calculation to third order in external momenta according to Weinberg`s power counting. With this calculation we can determine the second- and fourth-order structure-dependent coefficients of the general low-energy expansion of the spin-averaged VCS amplitude based on gauge invariance, crossing symmetry, and the discrete symmetries. We discuss the kinematical regime to which our calculation can be applied and compare our expansion with the multipole expansion by Guichon, Liu, and Thomas. We establish the connection of our calculation with the generalized polarizabilities of the nucleon where it is possible. {copyright} {ital 1997} {ital The American Physical Society}

  8. Staggered chiral perturbation theory and the fourth-root trick

    NASA Astrophysics Data System (ADS)

    Bernard, C.

    2006-06-01

    Staggered chiral perturbation theory (SχPT) takes into account the “fourth-root trick” for reducing unwanted (taste) degrees of freedom with staggered quarks by multiplying the contribution of each sea quark loop by a factor of 1/4. In the special case of four staggered fields (four flavors, nF=4), I show here that certain assumptions about analyticity and phase structure imply the validity of this procedure for representing the rooting trick in the chiral sector. I start from the observation that, when the four flavors are degenerate, the fourth root simply reduces nF=4 to nF=1. One can then treat nondegenerate quark masses by expanding around the degenerate limit. With additional assumptions on decoupling, the result can be extended to the more interesting cases of nF=3, 2, or 1. An apparent paradox associated with the one-flavor case is resolved. Coupled with some expected features of unrooted staggered quarks in the continuum limit, in particular, the restoration of taste symmetry, SχPT then implies that the fourth-root trick induces no problems (for example, a violation of unitarity that persists in the continuum limit) in the lowest energy sector of staggered lattice QCD. It also says that the theory with staggered valence quarks and rooted staggered sea quarks behaves like a simple, partially-quenched theory, not like a mixed theory in which sea and valence quarks have different lattice actions. In most cases, the assumptions made in this paper are not only sufficient but also necessary for the validity of SχPT, so that a variety of possible new routes for testing this validity are opened.

  9. Staggered chiral perturbation theory and the fourth-root trick

    SciTech Connect

    Bernard, C.

    2006-06-01

    Staggered chiral perturbation theory (S{chi}PT) takes into account the 'fourth-root trick' for reducing unwanted (taste) degrees of freedom with staggered quarks by multiplying the contribution of each sea quark loop by a factor of 1/4. In the special case of four staggered fields (four flavors, n{sub F}=4), I show here that certain assumptions about analyticity and phase structure imply the validity of this procedure for representing the rooting trick in the chiral sector. I start from the observation that, when the four flavors are degenerate, the fourth root simply reduces n{sub F}=4 to n{sub F}=1. One can then treat nondegenerate quark masses by expanding around the degenerate limit. With additional assumptions on decoupling, the result can be extended to the more interesting cases of n{sub F}=3, 2, or 1. An apparent paradox associated with the one-flavor case is resolved. Coupled with some expected features of unrooted staggered quarks in the continuum limit, in particular, the restoration of taste symmetry, S{chi}PT then implies that the fourth-root trick induces no problems (for example, a violation of unitarity that persists in the continuum limit) in the lowest energy sector of staggered lattice QCD. It also says that the theory with staggered valence quarks and rooted staggered sea quarks behaves like a simple, partially-quenched theory, not like a mixed theory in which sea and valence quarks have different lattice actions. In most cases, the assumptions made in this paper are not only sufficient but also necessary for the validity of S{chi}PT, so that a variety of possible new routes for testing this validity are opened.

  10. Kaon B-parameter in mixed action chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, Jack; Water, Ruth S. van de

    2007-02-01

    We calculate the kaon B-parameter, B{sub K}, in chiral perturbation theory for a partially quenched, mixed-action theory with Ginsparg-Wilson valence quarks and staggered sea quarks. We find that the resulting expression is similar to that in the continuum, and in fact has only two additional unknown parameters. At 1-loop order, taste-symmetry violations in the staggered sea sector only contribute to flavor-disconnected diagrams by generating an O(a{sup 2}) shift to the masses of taste-singlet sea-sea mesons. Lattice discretization errors also give rise to an analytic term which shifts the tree-level value of B{sub K} by an amount of O(a{sup 2}). This term, however, is not strictly due to taste breaking, and is therefore also present in the expression for B{sub K} for pure Ginsparg-Wilson lattice fermions. We also present a numerical study of the mixed B{sub K} expression in order to demonstrate that both discretization errors and finite volume effects are small and under control on the MILC improved staggered lattices.

  11. Pion and kaon masses in staggered chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Aubin, C.; Bernard, C.

    2003-08-01

    We show how to compute chiral logarithms that take into account both the O(a2) taste-symmetry breaking of staggered fermions and the fourth-root trick that produces one taste per flavor. The calculation starts from the Lee-Sharpe Lagrangian generalized to multiple flavors. An error in a previous treatment by one of us is explained and corrected. The one loop chiral logarithm corrections to the pion and kaon masses in the full (unquenched), partially quenched, and quenched cases are computed as examples.

  12. Matching Pion-Nucleon Roy-Steiner Equations to Chiral Perturbation Theory.

    PubMed

    Hoferichter, Martin; Ruiz de Elvira, Jacobo; Kubis, Bastian; Meissner, Ulf-G

    2015-11-01

    We match the results for the subthreshold parameters of pion-nucleon scattering obtained from a solution of Roy-Steiner equations to chiral perturbation theory up to next-to-next-to-next-to-leading order, to extract the pertinent low-energy constants including a comprehensive analysis of systematic uncertainties and correlations. We study the convergence of the chiral series by investigating the chiral expansion of threshold parameters up to the same order and discuss the role of the Δ(1232) resonance in this context. Results for the low-energy constants are also presented in the counting scheme usually applied in chiral nuclear effective field theory, where they serve as crucial input to determine the long-range part of the nucleon-nucleon potential as well as three-nucleon forces. PMID:26588373

  13. A quenched study of the Schroedinger functional with chirally rotated boundary conditions: non-perturbative tuning

    SciTech Connect

    Gonzalez-Lopez, Jennifer; Jansen, Karl; Renner, Dru B.; Shindler, Andrea

    2013-02-01

    The use of chirally rotated boundary conditions provides a formulation of the Schroedinger functional that is compatible with automatic O(a) improvement of Wilson fermions up to O(a) boundary contributions. The elimination of bulk O(a) effects requires the non-perturbative tuning of the critical mass and one additional boundary counterterm. We present the results of such a tuning in a quenched setup for several values of the renormalized gauge coupling, from perturbative to non-perturbative regimes, and for a range of lattice spacings. We also check that the correct boundary conditions and symmetries are restored in the continuum limit.

  14. Even- and Odd-Parity Charmed Meson Masses in Heavy Hadron Chiral Perturbation Theory

    SciTech Connect

    Thomas Mehen; Roxanne Springer

    2005-03-01

    We derive mass formulae for the ground state, J{sup P} = 0{sup -} and 1{sup -}, and first excited even-parity, J{sup P} = 0{sup +} and 1{sup +}, charmed mesons including one loop chiral corrections and {Omicron}(1/m{sub c}) counterterms in heavy hadron chiral perturbation theory. We show a variety of fits to the current data. We find that certain parameter relations in the parity doubling model are not renormalized at one loop, providing a natural explanation for the equality of the hyperfine splittings of ground state and excited doublets.

  15. Correlators of left charges and weak operators in finite volume chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Hernández, Pilar; Laine, Mikko

    2003-01-01

    We compute the two-point correlator between left-handed flavour charges, and the three-point correlator between two left-handed charges and one strangeness violating DeltaI = 3/2 weak operator, at next-to-leading order in finite volume SU(3)L × SU(3)R chiral perturbation theory, in the so-called epsilon-regime. Matching these results with the corresponding lattice measurements would in principle allow to extract the pion decay constant F, and the effective chiral theory parameter g27, which determines the Delta I = 3/2 amplitude of the weak decays K to pipi as well as the kaon mixing parameter BK in the chiral limit. We repeat the calculations in the replica formulation of quenched chiral perturbation theory, finding only mild modifications. In particular, a properly chosen ratio of the three-point and two-point functions is shown to be identical in the full and quenched theories at this order.

  16. Nucleon-to-{delta} axial transition form factors in relativistic baryon chiral perturbation theory

    SciTech Connect

    Geng, L. S.; Camalich, J. Martin; Alvarez-Ruso, L.; Vacas, M. J. Vicente

    2008-07-01

    We report a theoretical study of the axial nucleon-to-delta (1232) (N{yields}{delta}) transition form factors up to one-loop order in relativistic baryon chiral perturbation theory. We adopt a formalism in which the {delta} couplings obey the spin-3/2 gauge symmetry and, therefore, decouple the unphysical spin-1/2 fields. We compare the results with phenomenological form factors obtained from neutrino bubble-chamber data and in quark models.

  17. Rare decay {eta}{r_arrow}{pi}{pi}{gamma}{gamma} in chiral perturbation theory

    SciTech Connect

    Knoechlein, G.; Scherer, S.; Drechsel, D.

    1996-04-01

    We investigate the rare radiative {eta} decay modes {eta}{r_arrow}{pi}{sup +}{pi}{sup {minus}}{gamma}{gamma} and {eta}{r_arrow}{pi}{sup 0}{pi}{sup 0}{gamma}{gamma} within the framework of chiral perturbation theory at {ital O}({ital p}{sup 4}). We present photon spectra and partial decay rates for both processes as well as a Dalitz contour plot for the charged decay. {copyright} {ital 1996 The American Physical Society.}

  18. Excited D{sub s} (and Pentaquarks) in Chiral Perturbation Theory

    SciTech Connect

    Thomas Mehen

    2005-01-01

    I present results of a heavy hadron chiral perturbation theory analysis of the decays and masses of the recently discovered excited charm mesons. The present data on the electromagnetic branching ratios are consistent with heavy quark symmetry predictions and disfavor a molecular interpretation of these states. I also discuss model independent predictions for the strong decays of pentaquarks in the 10-bar representation of SU(3) which can be used to constrain the angular momentum and parity quantum numbers of these states.

  19. Perturbative Renormalizability of Chiral Two Pion Exchange and Power Counting in Nucleon-Nucleon Scattering

    SciTech Connect

    Pavon Valderrama, Manuel

    2010-12-28

    We show how to renormalize chiral two pion exchange perturbatively if one pion exchange has already been fully iterated at leading order. This particular choice corresponds to the implementation of the counting proposal of Nogga, Timmermans and van Kolck at subleading orders. We illustrate why the perturbative treatment of the two pion exchange contributions is mandatory in order to avoid certain inconsistencies in Weinberg's counting. In addition, renormalizability implies modifications of the power counting which we explore for the particular case of the singlet channel.

  20. Pion-nucleon scattering in covariant baryon chiral perturbation theory with explicit Delta resonances

    NASA Astrophysics Data System (ADS)

    Yao, De-Liang; Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A. M.; Gegelia, J.; Krebs, H.; Meißner, Ulf-G.

    2016-05-01

    We present the results of a third order calculation of the pion-nucleon scattering amplitude in a chiral effective field theory with pions, nucleons and delta resonances as explicit degrees of freedom. We work in a manifestly Lorentz invariant formulation of baryon chiral perturbation theory using dimensional regularization and the extended on-mass-shell renormalization scheme. In the delta resonance sector, the on mass-shell renormalization is realized as a complex-mass scheme. By fitting the low-energy constants of the effective Lagrangian to the S- and P -partial waves a satisfactory description of the phase shifts from the analysis of the Roy-Steiner equations is obtained. We predict the phase shifts for the D and F waves and compare them with the results of the analysis of the George Washington University group. The threshold parameters are calculated both in the delta-less and delta-full cases. Based on the determined low-energy constants, we discuss the pion-nucleon sigma term. Additionally, in order to determine the strangeness content of the nucleon, we calculate the octet baryon masses in the presence of decuplet resonances up to next-to-next-to-leading order in SU(3) baryon chiral perturbation theory. The octet baryon sigma terms are predicted as a byproduct of this calculation.

  1. Nonfactorization of four-quark condensates at low energies within chiral perturbation theory

    SciTech Connect

    Gomez Nicola, A.; Pelaez, J. R.; Ruiz de Elvira, J.

    2010-10-01

    Four-quark correlators and the factorization hypothesis are analyzed in the meson sector within chiral perturbation theory. We define the four-quark condensate as lim{sub x{yields}0}, which is equivalent to other definitions commonly used in the literature. Factorization of the four-quark condensate holds to leading and next to leading order. However, at next to next to leading order, a term with a nontrivial space-time dependence in the four-quark correlator yields a divergent four-quark condensate, whereas the two-quark condensate and the scalar susceptibility are finite. Such a nonfactorization term vanishes only in the chiral limit. We also comment on how factorization still holds in the large N{sub c} limit, provided such a limit is taken before renormalization.

  2. Polarizability of the pion: No conflict between dispersion theory and chiral perturbation theory

    SciTech Connect

    Pasquini, B.; Drechsel, D.; Scherer, S.

    2008-06-15

    Recent attempts to determine the pion polarizability by dispersion relations yield values that disagree with the predictions of chiral perturbation theory. These dispersion relations are based on specific forms for the absorptive part of the Compton amplitudes. The analytic properties of these forms are examined, and the strong enhancement of intermediate-meson contributions is shown to be connected with spurious singularities. If the basic requirements of dispersion relations are taken into account, the results of dispersion theory and effective field theory are not inconsistent.

  3. Leading SU(3)-breaking corrections to the baryon magnetic moments in chiral perturbation theory.

    PubMed

    Geng, L S; Camalich, J Martin; Alvarez-Ruso, L; Vacas, M J Vicente

    2008-11-28

    We calculate the baryon magnetic moments using covariant chiral perturbation theory (chiPT) within the extended-on-mass-shell renormalization scheme. By fitting the two available low-energy constants, we improve the Coleman-Glashow description of the data when we include the leading SU(3)-breaking effects coming from the lowest-order loops. This success is in dramatic contrast with previous attempts at the same order using heavy-baryon chiPT and covariant infrared chiPT. We also analyze the source of this improvement with particular attention to the comparison between the covariant results.

  4. The width of the Roper resonance in baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Gegelia, Jambul; Meißner, Ulf-G.; Yao, De-Liang

    2016-09-01

    We calculate the width of the Roper resonance at next-to-leading order in a systematic expansion of baryon chiral perturbation theory with pions, nucleons, and the delta and Roper resonances as dynamical degrees of freedom. Three unknown low-energy constants contribute up to the given order. One of them can be fixed by reproducing the empirical value for the width of the Roper decay into a pion and a nucleon. Assuming that the remaining two couplings of the Roper interaction take values equal to those of the nucleon, the result for the width of the Roper decaying into a nucleon and two pions is consistent with the experimental value.

  5. Elastic pion-nucleon scattering in chiral perturbation theory: A fresh look

    NASA Astrophysics Data System (ADS)

    Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A.; Krebs, H.; Meißner, Ulf-G.

    2016-07-01

    Elastic pion-nucleon scattering is analyzed in the framework of chiral perturbation theory up to fourth order within the heavy-baryon expansion and a covariant approach based on an extended on-mass-shell renormalization scheme. We discuss in detail the renormalization of the various low-energy constants and provide explicit expressions for the relevant β functions and the finite subtractions of the power-counting breaking terms within the covariant formulation. To estimate the theoretical uncertainty from the truncation of the chiral expansion, we employ an approach which has been successfully applied in the most recent analysis of the nuclear forces. This allows us to reliably extract the relevant low-energy constants from the available scattering data at low energy. The obtained results provide clear evidence that the breakdown scale of the chiral expansion for this reaction is related to the Δ resonance. The explicit inclusion of the leading contributions of the Δ isobar is demonstrated to substantially increase the range of applicability of the effective field theory. The resulting predictions for the phase shifts are in an excellent agreement with the predictions from the recent Roy-Steiner-equation analysis of pion-nucleon scattering.

  6. The chirally rotated Schrödinger functional: theoretical expectations and perturbative tests

    NASA Astrophysics Data System (ADS)

    Brida, Mattia Dalla; Sint, Stefan; Vilaseca, Pol

    2016-08-01

    The chirally rotated Schrödinger functional (χSF) with massless Wilson-type fermions provides an alternative lattice regularization of the Schrödinger functional (SF), with different lattice symmetries and a common continuum limit expected from universality. The explicit breaking of flavour and parity symmetries needs to be repaired by tuning the bare fermion mass and the coefficient of a dimension 3 boundary counterterm. Once this is achieved one expects the mechanism of automatic O( a) improvement to be operational in the χSF, in contrast to the standard formulation of the SF. This is expected to significantly improve the attainable precision for step-scaling functions of some composite operators. Furthermore, the χSF offers new strategies to determine finite renormalization constants which are traditionally obtained from chiral Ward identities. In this paper we consider a complete set of fermion bilinear operators, define corresponding correlation functions and explain the relation to their standard SF counterparts. We discuss renormalization and O( a) improvement and then use this set-up to formulate the theoretical expectations which follow from universality. Expanding the correlation functions to one-loop order of perturbation theory we then perform a number of non-trivial checks. In the process we obtain the action counterterm coefficients to one-loop order and reproduce some known perturbative results for renormalization constants of fermion bilinears. By confirming the theoretical expectations, this perturbative study lends further support to the soundness of the χSF framework and prepares the ground for non-perturbative applications.

  7. Electromagnetic structure of the lowest-lying decuplet resonances in covariant chiral perturbation theory

    SciTech Connect

    Geng, L. S.; Camalich, J. Martin; Vacas, M. J. Vicente

    2009-08-01

    We present a calculation of the leading SU(3)-breaking O(p{sup 3}) corrections to the electromagnetic moments and charge radius of the lowest-lying decuplet resonances in covariant chiral perturbation theory. In particular, the magnetic dipole moment of the members of the decuplet is predicted fixing the only low-energy constant (LEC) present up to this order with the well-measured magnetic dipole moment of the {omega}{sup -}. We predict {mu}{sub {delta}}{sup ++}=6.04(13) and {mu}{sub {delta}}{sup +}=2.84(2), which agree well with the current experimental information. For the electric quadrupole moment and the charge radius, we use state-of-the-art lattice QCD results to determine the corresponding LECs, whereas for the magnetic octupole moment there is no unknown LEC up to the order considered here, and we obtain a pure prediction. We compare our results with those reported in large N{sub c}, lattice QCD, heavy-baryon chiral perturbation theory, and other models.

  8. Renormalization of the low-energy constants of chiral perturbation theory from loops with dynamical vector mesons

    NASA Astrophysics Data System (ADS)

    Terschlüsen, Carla; Leupold, Stefan

    2016-07-01

    Starting from a relativistic Lagrangian for pseudoscalar Goldstone bosons and vector mesons in the antisymmetric tensor representation, a one-loop calculation is performed to pin down the divergent structures that appear for the effective low-energy action at chiral orders Q2 and Q4 . The corresponding renormalization-scale dependencies of all low-energy constants up to chiral order Q4 are determined. Calculations are carried out for both the pseudoscalar octet and the pseudoscalar nonet, the latter in the framework of chiral perturbation theory in the limit of a large number of colors.

  9. K{yields}{pi} and K{yields}0 in 2+1 flavor partially quenched chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, J.; Li, S.; Lin, M. F.

    2008-11-01

    We calculate results for K{yields}{pi} and K{yields}0 matrix elements to next-to-leading order in 2+1 flavor partially quenched chiral perturbation theory. Results are presented for both the {delta}I=1/2 and 3/2 channels, for chiral operators corresponding to current-current, gluonic penguin, and electroweak penguin 4-quark operators. These formulas are useful for studying the chiral behavior of currently available 2+1 flavor lattice QCD results, from which the low-energy constants of the chiral effective theory can be determined. The low-energy constants of these matrix elements are necessary for an understanding of the {delta}I=1/2 rule, and for calculations of {epsilon}{sup '}/{epsilon} using current lattice QCD simulations.

  10. Nuclear-matter equation of state with consistent two- and three-body perturbative chiral interactions

    NASA Astrophysics Data System (ADS)

    Coraggio, L.; Holt, J. W.; Itaco, N.; Machleidt, R.; Marcucci, L. E.; Sammarruca, F.

    2014-04-01

    We compute the energy per particle of infinite symmetric nuclear matter from chiral NLO3 (next-to-next-to-next-to-leading order) two-body potentials plus NLO2 three-body forces. The low-energy constants of the chiral three-nucleon force that cannot be constrained by two-body observables are fitted to reproduce the triton binding energy and the H3-He3 Gamow-Teller transition matrix element. In this way, the saturation properties of nuclear matter are reproduced in a parameter-free approach. The equation of state is computed up to third order in many-body perturbation theory, with special emphasis on the role of the third-order particle-hole diagram. The dependence of these results on the cutoff scale and regulator function is studied. We find that the inclusion of three-nucleon forces consistent with the applied two-nucleon interaction leads to a reduced dependence on the choice of the regulator only for lower values of the cutoff.

  11. Off-shell electromagnetic form factors of pions and kaons in chiral perturbation theory

    SciTech Connect

    Rudy, T.E.; Fearing, H.W.; Scherer, S. )

    1994-07-01

    The off-shell electromagnetic vertex of a (pseudo)scalar particle contains, in general, two form factors [ital F] and [ital G] which depend, in addition to the squared momentum transfer, on the invariant masses associated with the initial and final legs of the vertex. Chiral perturbation theory to one loop is used to calculate the off-shell form factors of pions and kaons. The formalism of Gasser and Leutwyler, which was previously used to calculate the on-shell limit of the form factor [ital F], is extended to accommodate the most general form for off-shell Green's functions in the pseudoscalar meson sector. We find that chiral symmetry predicts that the form factors [ital F] of the charged pions and kaons go off-shell in the same way, i.e., the off-shell slope at the real photon point is given by the same new phenomenological constant [beta][sub 1]. Furthermore, it is shown that at order [ital p][sup 4] the form factor [ital F] of the [ital K][sup 0] does not show any off-shell dependence. The form factors [ital G] are all related to the form factors [ital F] in the correct fashion as required by the Ward-Takahashi identity. Numerical results for different off-shell kinematics are presented.

  12. Mass spectra of heavy-light mesons in heavy hadron chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Alhakami, Mohammad H.

    2016-05-01

    We study the masses of the low-lying charm and bottom mesons within the framework of heavy hadron chiral perturbation theory (HHChPT). We work to third order in the chiral expansion, where meson loops contribute. In contrast to previous approaches, we use physical meson masses in evaluating these loops. This ensures that their imaginary parts are consistent with the observed widths of the D mesons. The lowest odd- and even-parity, strange and nonstrange charm mesons provide enough constraints to determine only certain linear combinations of the low-energy constants in the effective Lagrangian. We comment on how lattice QCD could provide further information to disentangle these constants. Then, we use the results from the charm sector to predict the spectrum of odd and even parity of the bottom mesons. The predicted masses from our theory are in good agreement with experimentally measured masses for the case of the odd-parity sector. For the even-parity sector, the B -meson states have not yet been observed; thus, our results provide useful information for experimentalists investigating such states. The near degeneracy of nonstrange and strange scalar B mesons is confirmed in our predictions using HHChPT. We show why previous approaches of using HHChPT in studying the mass degeneracy in the scalar states of charm and bottom meson sectors gave unsatisfactory results.

  13. Intrinsic Optical Activity and Environmental Perturbations: Solvation Effects in Chiral Building Blocks

    NASA Astrophysics Data System (ADS)

    Lemler, Paul M.; Vaccaro, Patrick

    2016-06-01

    The non-resonant interaction of electromagnetic radiation with an isotropic ensemble of chiral molecules, which causes the incident state of linear polarization to undergo a signed rotation, long has served as a metric for gauging the enantiomeric purity of asymmetric syntheses. While the underlying phenomenon of circular birefringence (CB) typically is probed in the condensed phase, recent advances in ultrasensitive circular-differential detection schemes, as exemplified by the techniques of Cavity Ring-Down Polarimetry (CRDP), have permitted the first quantitative analyses of such processes to be performed in rarefied media. Efforts to extend vapor-phase investigations of CB to new families of chiral substrates will be discussed, with particular emphasis directed towards the elucidation of intrinsic (e.g., solvent-free) properties and their mediation by environmental perturbations (e.g., solvation). Specific species targeted by this work will include the stereoselective building blocks phenylpropylene oxide and α-methylbenzyl amine, both of which exhibit pronounced solvent-dependent changes in measured optical activity. The nature of chiroptical response in different environments will be highlighted, with quantum-chemical calculations serving to unravel the structural and electronic provenance of observed behavior.

  14. New predictions for generalized spin polarizabilities from heavy baryon chiral perturbation theory

    SciTech Connect

    Chung-Wen Kao; Barbara Pasquini; Marc Vanderhaeghen

    2004-08-01

    We extract the next-to-next-to-leading order results for spin-flip generalized polarizabilities (GPs) of the nucleon from the spin-dependent amplitudes for virtual Compton scattering (VCS) at {Omicron}(p{sup 4}) in heavy baryon chiral perturbation theory. At this order, no unknown low energy constants enter the theory, allowing us to make absolute predictions for all spin-flip GPs. Furthermore, by using constraint equations between the GPs due to nucleon crossing combined with charge conjugation symmetry of the VCS amplitudes, we get a next-to-next-to-next-to-leading order prediction for one of the GPs. We provide estimates for forthcoming double polarization experiments which allow to access these spin-flip GPs of the nucleon.

  15. New predictions for generalized spin polarizabilities from heavy baryon chiral perturbation theory

    SciTech Connect

    Kao, C.-W.; Pasquini, Barbara; Vanderhaeghen, Marc

    2004-12-01

    We extract the next-to-next-to-leading order results for spin-flip generalized polarizabilities (GPs) of the nucleon from the spin-dependent amplitudes for virtual Compton scattering at O(p{sup 4}) in heavy baryon chiral perturbation theory. At this order, no unknown low-energy constants enter the theory, allowing us to make absolute predictions for all spin-flip GPs. Furthermore, by using constraint equations between the GPs due to nucleon crossing combined with charge conjugation symmetry of the virtual Compton scattering amplitudes, we get a next-to-next-to-next-to-leading order prediction for one of the GPs. We provide estimates for forthcoming double-polarization experiments which allow one to access these spin-flip GPs of the nucleon.

  16. Heavy-baryon chiral perturbation theory approach to thermal neutron capture on {sup 3}He

    SciTech Connect

    Lazauskas, Rimantas; Park, Tae-Sun

    2011-03-15

    The cross section for radiative thermal neutron capture on {sup 3}He ({sup 3}He+n{yields}{sup 4}He+{gamma}; known as the hen reaction) is calculated based on heavy-baryon chiral perturbation theory. The relevant M1 operators are derived up to next-to-next-to-next-to-leading order (N{sup 3}LO). The initial and final nuclear wave functions are obtained from the rigorous Faddeev-Yakubovski equations for five sets of realistic nuclear interactions. Up to N{sup 3}LO, the M1 operators contain two low-energy constants, which appear as the coefficients of nonderivative two-nucleon contact terms. After determining these two constants using the experimental values of the magnetic moments of the triton and {sup 3}He, we carry out a parameter-free calculation of the hen cross section. The results are in good agreement with the data.

  17. Reply to 'Comment on 'Polarizability of the pion: No conflict between dispersion theory and chiral perturbation theory''

    SciTech Connect

    Pasquini, B.; Drechsel, D.; Scherer, S.

    2010-02-15

    We show that the alleged discrepancies between chiral perturbation theory (ChPT) and dispersion theory, reported for the polarizability of the pion by Fil'kov and Kashevarov [Phys. Rev. C 72, 035211 (2005)], result from applying dispersion theory to nonanalytic functions.

  18. Twisted mass chiral perturbation theory at next-to-leading order

    NASA Astrophysics Data System (ADS)

    Sharpe, Stephen R.; Wu, Jackson M.

    2005-04-01

    We study the properties of pions in twisted mass lattice QCD (with two degenerate flavors) using chiral perturbation theory (χPT). We work to next-to-leading order (NLO) in a power-counting scheme in which mq˜aΛ2QCD, with mq the physical quark mass and a the lattice spacing. We argue that automatic O(a) improvement of physical quantities at maximal twist, which has been demonstrated in general if mq≫aΛ2QCD, holds even if mq˜aΛ2QCD, as long as one uses an appropriate nonperturbative definition of the twist angle, with the caveat that we have shown this only through NLO in our chiral expansion. We demonstrate this with explicit calculations, for arbitrary twist angle, of all pionic quantities that involve no more than a single pion in the initial and final states: masses, decay constants, form factors, and condensates, as well as the differences between alternate definitions of twist angle. We also calculate the axial and pseudoscalar form factors of the pion, quantities which violate flavor and parity, and which vanish in the continuum limit. These are of interest because they are not automatically O(a) improved at maximal twist. They allow a determination of the unknown low-energy constants introduced by discretization errors, and provide tests of the accuracy of χPT at NLO. We extend our results into the regime where mq˜a2Λ3QCD, and argue in favor of a recent proposal that automatic O(a) improvement at maximal twist remains valid in this regime.

  19. Evaluation of the toxicity of ZnO nanoparticles to Chlorella vulgaris by use of the chiral perturbation approach.

    PubMed

    Zhou, Hui; Wang, Xiaojun; Zhou, Ying; Yao, Hongzhou; Ahmad, Farooq

    2014-06-01

    The toxicity of ZnO nanoparticles (NPs) has been widely investigated because of their extensive use in consumer products. The mechanism of the toxicity of ZnO NPs to algae is unclear, however, and it is difficult to differentiate between particle-induced toxicity and the effect of dissolved Zn(2+). In the work discussed in this paper we investigated particle-induced toxicity and the effects of dissolved Zn(2+) by using the chiral perturbation approach with dichlorprop (DCPP) as chiral perturbation factor. The results indicated that intracellular zinc is important in the toxicity of ZnO NPs, and that ZnO NPs cause oxidative damage. According to dose-response curves for DCPP and the combination of ZnO NPs with (R)-DCPP or (S)-DCPP, the toxicity of DCPP was too low to perturb the toxicity of ZnO NPs, so DCPP was suitable for use as chiral perturbation factor. The different glutathione (GSH) content of algal cells exposed to (R)-DCPP or (S)-DCPP correlated well with different production of reactive oxygen species (ROS) after exposure to the two enantiomers. Treatment of algae with ZnO NPs and (R)-DCPP resulted in reduced levels of GSH and the glutathione/oxidized glutathione (GSH/GSSG) ratio in the cells compared with the control. Treatment of algae with ZnO NPs and (S)-DCPP, however, resulted in no significant changes in GSH and GSH/GSSG. Moreover, trends of variation of GSH and GSH/GSSG were different when algae were treated with ZnSO4·7H2O and the two enantiomers. Overall, the chiral perturbation approach revealed that NPs aggravated generation of ROS and that released Zn(2+) and NPs both contribute to the toxicity of ZnO NPs.

  20. Nuclear structure with accurate chiral perturbation theory nucleon-nucleon potential: Application to 6Li and 10B

    SciTech Connect

    Navratil, P; Caurier, E

    2003-10-14

    The authors calculate properties of A = 6 system using the accurate charge-dependent nucleon-nucleon (NN) potential at fourth order of chiral perturbation theory. By application of the ab initio no-core shell model (NCSM) and a variational calculation in the harmonic oscillator basis with basis size up to 16 {h_bar}{Omega} they obtain the {sup 6}Li binding energy of 28.5(5) MeV and a converged excitation spectrum. Also, they calculate properties of {sup 10}B using the same NN potential in a basis space of up to 8 {h_bar}{Omega}. The results are consistent with results obtained by standard accurate NN potentials and demonstrate a deficiency of Hamiltonians consisting of only two-body terms. At this order of chiral perturbation theory three-body terms appear. It is expected that inclusion of such terms in the Hamiltonian will improve agreement with experiment.

  1. Chiral Perturbation Theory, the 1/N_c expansion and Regge behavior determine the structure of the lightest scalar meson

    SciTech Connect

    Pelaez, J. R.; Michael R. Pennington; de Elvira, J. Ruiz; Wilson, D. J.

    2011-11-01

    The leading 1/N{sub c} behavior of Unitarized Chiral Perturbation Theory distinguishes the nature of the {rho} and the {sigma}. At one loop order the {rho} is a {bar q}q meson, while the {sigma} is not. However, semi-local duality between resonances and Regge behaviour cannot be satisfied for larger N{sub c}, if such a distinction holds. While the {sigma} at N{sub c}= 3 is inevitably dominated by its di-pion component, Unitarised Chiral Perturbation Theory beyond one loop order reveals that as N{sub c} increases above 6-8, the {sigma} has a sub-dominant {bar q}q fraction up at 1.2 GeV. Remarkably this ensures semi-local duality is fulfilled for the range of N{sub c} {approx}< 15-30, where the unitarization procedure adopted applies.

  2. Muon capture by a proton in heavy baryon chiral perturbation theory

    SciTech Connect

    Fearing, H.W.; Lewis, R.; Mobed, N.; Scherer, S.

    1997-08-01

    The matrix element for muon capture by a proton is calculated to O(p{sup 3}) within heavy baryon chiral perturbation theory using the new O(p{sup 3}) Lagrangian of Ecker and Moj{hacek z}i{hacek s}. External nucleon fields are renormalized using the appropriate definition of the wave function renormalization factor Z{sub N}. Our expression for Z{sub N} differs somewhat from that found in the existing literature, but is the one which is consistent with the Lagrangian we use and the one which ensures, within our approach, the nonrenormalization of the vector coupling as required by the conserved vector current. Expressions for the standard muon capture form factors are derived and compared to experimental data and we determine three of the coefficients of the Ecker-Moj{hacek z}i{hacek s} Lagrangian, namely, b{sub 7}, b{sub 19}, and b{sub 23}. {copyright} {ital 1997} {ital The American Physical Society}

  3. Field transformations and the classical equation of motion in chiral perturbation theory

    SciTech Connect

    Scherer, S.; Fearing, H.W.

    1995-12-01

    The construction of effective Lagrangians commonly involves the application of the ``classical equation of motion`` to eliminate redundant structures and thus generate the minimal number of independent terms. We investigate this procedure in the framework of chiral perturbation theory with particular emphasis on the new features which appear at {ital O}({ital p}{sup 6}). The use of the ``classical equation of motion`` is interpreted in terms of field transformations. Such an interpretation is crucial if one wants to bring a given Lagrangian into a canonical form with a minimal number of terms. We emphasize that the application of field transformations leads to a modification of the coefficients of higher-order terms as well as eliminating structures, or what is equivalent, expressing certain structures in terms of already known different structures. This will become relevant once one considers the problem of expressing in canonical form a model effective interaction containing terms beyond next-to-leading order, i.e., beyond {ital O}({ital p}{sup 4}). In such circumstances the naive application of the clasical equation of motion to simply drop terms, as is commonly done at lowest order, leads to subtle errors, which we discuss.

  4. The Kaon B-parameter in mixed action chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, Jack; Van de Water, Ruth S.; /Fermilab

    2006-09-01

    We calculate the kaon B-parameter, B{sub K}, in chiral perturbation theory for a partially quenched, mixed action theory with Ginsparg-Wilson valence quarks and staggered sea quarks. We find that the resulting expression is similar to that in the continuum, and in fact has only two additional unknown parameters. At one-loop order, taste-symmetry violations in the staggered sea sector only contribute to flavor-disconnected diagrams by generating an {Omicron}(a{sup 2}) shift to the masses of taste-singlet sea-sea mesons. Lattice discretization errors also give rise to an analytic term which shifts the tree-level value of B{sub K} by an amount of {Omicron}(a{sup 2}). This term, however, is not strictly due to taste-breaking, and is therefore also present in the expression for B{sub K} for pure G-W lattice fermions. We also present a numerical study of the mixed B{sub K} expression in order to demonstrate that both discretization errors and finite volume effects are small and under control on the MILC improved staggered lattices.

  5. Decay {omega}{sup -}{yields}{xi}{sup -}{pi}{sup +}{pi}{sup -} in chiral perturbation theory

    SciTech Connect

    Antipin, Oleg; Tandean, Jusak; Valencia, G.

    2007-11-01

    We study the decay {omega}{sup -}{yields}{xi}{sup -}{pi}{sup +}{pi}{sup -} in heavy-baryon chiral perturbation theory. At leading order, the decay is completely dominated by the {xi}*{sup 0}(1530) intermediate state, and the predicted rate and {xi}{sup -}{pi}{sup +}-mass distribution are in conflict with currently available data. It is possible to resolve this conflict by considering additional contributions at next-to-leading order.

  6. Improved description of the πN-scattering phenomenology at low energies in covariant baryon chiral perturbation theory

    SciTech Connect

    Alarcón, J.M.; Martin Camalich, J.; Oller, J.A.

    2013-09-15

    We present a novel analysis of the πN scattering amplitude in covariant baryon chiral perturbation theory up to O(p{sup 3}) within the extended-on-mass-shell renormalization scheme and including the Δ(1232) explicitly in the δ-counting. We take the hadronic phase shifts provided by partial wave analyses as basic experimental information to fix the low-energy constants. Subsequently, we study in detail the various observables and low-energy theorems related to the πN scattering amplitude. In particular, we discuss the results and chiral expansion of the phase shifts, the threshold coefficients, the Goldberger–Treiman relation, the pion–nucleon sigma term and the extrapolation onto the subthreshold region. The chiral representation of the amplitude in the theory with the Δ presents a good convergence from very low energies in the subthreshold region up to energies above threshold and below the Δ(1232) peak, leading also to a phenomenological description perfectly consistent with the one reported by the respective partial wave analyses and independent determinations. We conclude that a model-independent and systematic framework to analyze πN-scattering observables using directly experimental data shall be possible in covariant baryon chiral perturbation theory. -- Highlights: •The chiral series shows a better convergence than previous analyses. •Improved prediction of the πN scattering phenomenology. •This analysis connects reliably the subthreshold and physical regions for the first time using ChPT. •Extraction of an accurate value of σ{sub πN} from experimental data. •σ{sub πN} extracted is compatible with related phenomenology.

  7. Chiral perturbation theory for staggered sea quarks and Ginsparg-Wilson valence quarks

    SciTech Connect

    Baer, Oliver; Bernard, Claude; Rupak, Gautam; Shoresh, Noam

    2005-09-01

    We study lattice QCD with staggered sea and Ginsparg-Wilson valence quarks. The Symanzik effective action for this mixed lattice theory, including the lattice spacing contributions of O(a{sup 2}), is derived. Using this effective theory we construct the leading-order chiral Lagrangian. The masses and decay constants of pseudoscalars containing two Ginsparg-Wilson valence quarks are computed at one-loop order.

  8. B -> d* l nu and b -> d l nu form-factors in staggered chiral perturbation theory

    SciTech Connect

    Laiho, Jack; Van de Water, Ruth S.; /Fermilab

    2005-12-01

    We calculate the B {yields} D and B {yields} D* form factors at zero recoil in Staggered Chiral Perturbation Theory. We consider heavy-light mesons in which only the light (u, d, or s) quark is staggered; current lattice simulations generally use a highly improved action such as the Fermilab or NRQCD action for the heavy (b or c) quark. We work to lowest order in the heavy quark expansion and to next-to-leading order in the chiral expansion. We present results for a partially quenched theory with three sea quarks in which there are no mass degeneracies (the ''1+1+1'' theory) and for a partially quenched theory in which the u and d sea quark masses are equal (the ''2+1'' theory). We also present results for full (2+1) QCD, along with a numerical estimate of the size of staggered discretization errors. Finally, we calculate the finite volume corrections to the form factors and estimate their numerical size in current lattice simulations.

  9. Axial, induced pseudoscalar, and pion-nucleon form factors in manifestly Lorentz-invariant chiral perturbation theory

    SciTech Connect

    Schindler, M. R.; Fuchs, T.; Scherer, S.; Gegelia, J.

    2007-02-15

    We calculate the nucleon form factors G{sub A} and G{sub P} of the isovector axial-vector current and the pion-nucleon form factor G{sub {pi}}{sub N} in manifestly Lorentz-invariant baryon chiral perturbation theory up to and including order O(p{sup 4}). In addition to the standard treatment including the nucleon and pions, we also consider the axial-vector meson a{sub 1} as an explicit degree of freedom. This is achieved by using the reformulated infrared renormalization scheme. We find that the inclusion of the axial-vector meson effectively results in one additional low-energy coupling constant that we determine by a fit to the data for G{sub A}. The inclusion of the axial-vector meson results in an improved description of the experimental data for G{sub A}, while the contribution to G{sub P} is small.

  10. Extension of the chiral perturbation theory meson Lagrangian to order {ital p}{sup 6}

    SciTech Connect

    Fearing, H.W.; Scherer, S.

    1996-01-01

    We have constructed the most general chirally invariant Lagrangian {ital scrL}{sub 6} for the meson sector at order {ital p}{sup 6}. The result provides an extension of the standard Gasser-Leutwyler Lagrangian {ital scrL}{sub 4} to one higher order, including as well all the odd intrinsic parity terms in the Lagrangian. The most difficult part of the construction was developing a systematic strategy so as to get all of the independent terms and eliminate the redundant ones in an efficient way. The claim to have obtained the most general Lagrangian relies on this systematic construction and on the elimination of redundant quantities using relations of which we are aware, rather than on a general formal proof of either completeness or independence. The {open_quote}{open_quote}equation-of-motion{close_quote}{close_quote} terms, which are redundant in the sense that they can be transformed away via field transformations, are separated out explicitly. The resulting Lagrangian has been separated into groupings of terms contributing to increasingly more complicated processes, so that one does not have to deal with the full result when calculating {ital p}{sup 6} contributions to simple processes. {copyright} {ital 1995 The American Physical Society.}

  11. Study of K{sup 0}{yields}{pi}{sup -}e{sup +}{nu}{sub e}e{sup +}e{sup -} in chiral perturbation theory

    SciTech Connect

    Tsuji, K.; Sato, T.

    2008-03-01

    K{sup 0}{yields}{pi}{sup -}e{sup +}{nu}{sub e}e{sup +}e{sup -} decay rates are studied up to the next-to-leading order (O{sup (4)}) in chiral perturbation theory. It is found that the O{sup (4)} terms appreciably modify the shape of the invariant mass distribution of leptons (M{sub 3e{nu}}) and the energy spectrum of neutrinos.

  12. Proton polarisability contribution to the Lamb shift in muonic hydrogen at fourth order in chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    McGovern, Judith

    2013-04-01

    The recent determination of the proton charge radius from the Lamb shift in muonic hydrogen [1] gives a value that differs by many standard deviations from the CODATA value [2] and from the results of recent electron scattering experiments [3]. In the theoretical calculations [4], the least-well-determined contribution is the ``proton polarisability'' contribution. This is the part of the two-photon exchange which involves proton excitations. The dominant effect can be determined via dispersion relations from the proton structure functions, but a subtraction term remains [5,6]. This subtraction term is the amplitude T1(0,Q^2) for forward, zero-energy, doubly-virtual Compton scattering, which we calculate in heavy-baryon chiral perturbation theory, to fourth order in the chiral expansion and with the leading contribution of the γNδ form factor. This provides a model-independent expression for the amplitude in the low-momentum region, which is the dominant one for its contribution to the Lamb shift, and allows us to significantly reduce the theoretical uncertainty in the latter [7].[4pt] [1] R. Pohl et al., Nature 466, 213 (2010).[0pt] [2] P. J. Mohr, B. N. Taylor and D. B. Newell, Rev. Mod. Phys. 80, 633 (2008) [arXiv:0801.0028].[0pt] [3] J. C. Bernauer et al. (A1 Collaboration), Phys. Rev. Lett. 105, 242001 (2010) [arXiv:1007.5076].[0pt] [4] U. D. Jentschura, Ann. Phys. 326, 500 (2011) [arXiv:1011.5275]; E. Borie, Ann. Phys. 327, 733 (2012) [arXiv:1103.1772].[0pt] [5] K. Pachucki, Phys. Rev. A 60, 3593 (1999) [arXiv:physics/9906002].[0pt] [6] C. E. Carlson and M. Vanderhaeghen, Phys. Rev. A 84, 020102 (2011) [arXiv:1101.5965]; also [arXiv:1109.3779].[0pt] [7] M. C. Birse and J. A. McGovern, Eur. Phys. J. A48, 120 (2012) [arXiv:1206.3030].

  13. Chiral perturbation theory for K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay in the continuum and on the lattice

    SciTech Connect

    Golterman, M.F.; Leung, K.C.

    1997-09-01

    In this paper we use one-loop chiral perturbation theory in order to compare lattice computations of the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude with the experimental value. This makes it possible to investigate three systematic effects that plague lattice computations: quenching, finite-volume effects, and the fact that lattice computations have been done at unphysical values of the quark masses and pion external momenta (only this latter effect shows up at the tree level). We apply our results to the most recent lattice computation and find that all three effects are substantial. We conclude that one-loop corrections in chiral perturbation theory help in explaining the discrepancy between lattice results and the real-world value. We also reexamine B{sub K}, which is closely related to the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude by chiral symmetry. {copyright} {ital 1997} {ital The American Physical Society}

  14. Up to N{sup 3}LO heavy-baryon chiral perturbation theory calculation for the M1 properties of three-nucleon systems

    SciTech Connect

    Song, Young-Ho; Lazauskas, Rimantas; Park, Tae-Sun

    2009-06-15

    M1 properties, comprising magnetic moments and radiative capture of thermal neutron observables, are studied in two- and three-nucleon systems. We use meson exchange current derived up to N{sup 3}LO using heavy baryon chiral perturbation theory a la Weinberg. Calculations have been performed for several qualitatively different realistic nuclear Hamiltonians, which permits us to analyze model dependence of our results. Our results are found to be strongly correlated with the effective range parameters such as binding energies and the scattering lengths. Taking into account such correlations, the results are in good agreement with the experimental data with small model dependence.

  15. Introduction to chiral symmetry

    SciTech Connect

    Koch, V.

    1996-01-08

    These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented.

  16. Nucleon and Delta axial-vector couplings in 1/N{sub c}-Baryon Chiral Perturbation Theory

    SciTech Connect

    Goity, Jose Luis; Calle Cordon, Alvaro

    2013-08-01

    In this contribution, baryon axial-vector couplings are studied in the framework of the combined 1/N{sub c} and chiral expansions. This framework is implemented on the basis of the emergent spin-flavor symmetry in baryons at large N{sub c} and HBChPT, and linking both expansions ({xi}-expansion), where 1/N{sub c} is taken to be a quantity order p. The study is carried out including one-loop contributions, which corresponds to order xi to the third for baryon masses and order {xi} square for the axial couplings.

  17. {K}+to {μ}+{ν}_{μ}ν overline{ν} and {K}+to {e}+{ν}eν overline{ν} decays within the Chiral Perturbation Theory

    NASA Astrophysics Data System (ADS)

    Gorbunov, D.; Mitrofanov, A.

    2016-10-01

    Decays {K}+to {μ}+{ν}_{μ}ν overline{ν} and {K}+to {e}+{ν}_eν overline{ν} are examined to the leading order in momenta in the framework of Chiral Perturbation Theory. Predictions of the Standard Model for the muon and electron differential energy spectra and branching ratios of K μ3ν and K e3ν are presented.

  18. Lattice extraction of K{yields}{pi}{pi} amplitudes to next-to-leading order in partially quenched and in full chiral perturbation theory

    SciTech Connect

    Laiho, Jack; Soni, Amarjit

    2005-01-01

    We show that it is possible to construct {epsilon}{sup '}/{epsilon} to next-to-leading order (NLO) using partially quenched chiral perturbation theory (PQChPT) from amplitudes that are computable on the lattice. We demonstrate that none of the needed amplitudes require 3-momentum on the lattice for either the full theory or the partially quenched theory; nondegenerate quark masses suffice. Furthermore, we find that the electro-weak penguin ({delta}I=3/2 and 1/2) contributions to {epsilon}{sup '}/{epsilon} in PQChPT can be determined to NLO using only degenerate (m{sub K}=m{sub {pi}}) K{yields}{pi} computations without momentum insertion. Issues pertaining to power divergent contributions, originating from mixing with lower dimensional operators, are addressed. Direct calculations of K{yields}{pi}{pi} at unphysical kinematics are plagued with enhanced finite volume effects in the (partially) quenched theory, but in simulations when the sea quark mass is equal to the up and down quark mass the enhanced finite volume effects vanish to NLO in PQChPT. In embedding the QCD penguin left-right operator onto PQChPT an ambiguity arises, as first emphasized by Golterman and Pallante. With one version [the 'PQS' (patially quenched singlet)] of the QCD penguin, the inputs needed from the lattice for constructing K{yields}{pi}{pi} at NLO in PQChPT coincide with those needed for the full theory. Explicit expressions for the finite logarithms emerging from our NLO analysis to the above amplitudes also are given.

  19. The covariant chiral ring

    NASA Astrophysics Data System (ADS)

    Bourget, Antoine; Troost, Jan

    2016-03-01

    We construct a covariant generating function for the spectrum of chiral primaries of symmetric orbifold conformal field theories with N = (4 , 4) supersymmetry in two dimensions. For seed target spaces K3 and T 4, the generating functions capture the SO(21) and SO(5) representation theoretic content of the chiral ring respectively. Via string dualities, we relate the transformation properties of the chiral ring under these isometries of the moduli space to the Lorentz covariance of perturbative string partition functions in flat space.

  20. Extraction of {gamma} from charmless hadronic B {yields} PP decays using SU(3) flavor symmetry

    SciTech Connect

    Suprun, Denis A.

    2006-07-11

    The decays of B mesons to a pair of charmless pseudoscalar mesons (PP decays) have been analyzed within the framework of flavor SU(3) symmetry and quark-diagrammatic topological approach. Flavor symmetry breaking is taken into account in tree (T) amplitudes through ratios of decay constants fK and f{pi}; exact SU(3) is assumed elsewhere. Acceptable fits to B {yields} PP branching ratios and CP asymmetries are obtained with tree, color-suppressed and QCD penguin amplitudes. Singlet penguin amplitude was introduced to describe decay amplitudes of the modes with {eta} and {eta}' mesons in the final state. Electroweak penguin amplitudes were expressed in terms of the corresponding tree-level diagrams. Values of the weak phase {gamma} were found to be consistent with the current indirect bounds from other analyses of CKM parameters.

  1. SU(3) flavor breaking in hadronic matrix elements for B-B¯ oscillations

    NASA Astrophysics Data System (ADS)

    Bernard, C.; Blum, T.; Soni, A.

    1998-07-01

    Results in the quenched approximation for SU(3) breaking ratios of the heavy-light decay constants and the ΔF=2 mixing matrix elements are reported. Using lattice simulations at 6/g2=5.7, 5.85, 6.0, and 6.3, we directly compute the mixing matrix element Mhl=. Extrapolating to the physical B meson states, B0 and B0s, we obtain Mbs/Mbd=1.76(10)+57-42 in the continuum limit. The systematic error includes the errors within the quenched approximation but not the errors of quenching. We also obtain the ratio of decay constants, fbs/fbd=1.17(2)+12-6. For the B parameters we find Bbs(2 GeV)=Bbd(2 GeV)=1.02(13); we cannot resolve the SU(3) breaking effects in this case.

  2. Complete leading order analysis in Chiral Perturbation Theory of the decays K{sub L}{r_arrow}{gamma}{gamma} and K{sub L}{r_arrow}l{sub +}l{sub {minus}}{gamma}

    SciTech Connect

    J. L. Goity; Longzhe Zhang

    1997-02-01

    The decays K{sub L}{r_arrow}{gamma}{gamma} and K{sub L}{r_arrow}l{sup +}l{sup {minus}}{gamma} are studied at the leading order p{sup 6} in Chiral Perturbation Theory. One-loop contributions stemming from the odd intrinsic parity {vert_bar}{Delta}S{vert_bar}=1 effective Lagrangian of order p{sup 4} are included and shown to be of possible relevance. They affect the decay K{sub L}{r_arrow}{gamma}{gamma} adding to the usual pole terms a piece free of counterterm uncertainties. In the case of the K{sub L}{r_arrow}l{sup +}l{sup {minus}}{gamma} decays the dependence of the form factor on the dilepton invariant mass requires a counterterm. The form factor may receive a sizeable contribution from chiral logarithms. Including considerations from the K{sub L}{r_arrow}{pi}{sup +}{pi}{sup {minus}}{gamma} direct emission amplitude, the authors obtain two consistent scenarios. In one scenario the long distance contributions from the one-loop terms are important, while in the other they are marginal. In both cases the counterterm is shown to be significant.

  3. Gluons in the chiral bag

    NASA Astrophysics Data System (ADS)

    Kahana, D. E.; Milana, J.

    1987-07-01

    A perturbative QCD calculation of gluon exchange corrections to the cranking moment of inertia of the chiral bag model is done using the full time-dependent cavity propagators. Cranking is used to construct the nucleon and delta states and a value of the effective strong coupling constant is extracted by fitting the empirical Δ N mass splitting. The MIT bag limit (large bag radius) of the chiral bag model is also examined.

  4. A construction of lattice chiral gauge theories

    NASA Astrophysics Data System (ADS)

    Narayanan, Rajamani; Neuberger, Herbert

    1995-02-01

    Path integration over Euclidean chiral fermions is replaced by the quantum mechanics of an auxiliary system of non-interacting fermions. Our construction avoids the no-go theorem and faithfully maintains all the known important features of chiral fermions, including the violation of some perturbative conservation laws by gauge field configurations of non-trivial topology.

  5. A lattice formulation of chiral gauge theories

    SciTech Connect

    Bodwin, G.T.

    1996-08-01

    We present a method for implementing gauge theories of chiral fermions on the lattice. Discussed topics include: the lattice as a UV regulator, a chiral QED model, modification of the fermion determinant, large gauge-field momenta, and a non-perturbative problem.

  6. Strangeness S = -2 baryon-baryon interaction at next-to-leading order in chiral effective field theory

    NASA Astrophysics Data System (ADS)

    Haidenbauer, J.; Meißner, Ulf-G.; Petschauer, S.

    2016-10-01

    The strangeness S = - 2 baryon-baryon interaction is studied in chiral effective field theory up to next-to-leading order. The potential at this order consists of contributions from one- and two-pseudoscalar-meson exchange diagrams and from four-baryon contact terms without and with two derivatives. SU(3) flavor symmetry is imposed for constructing the interaction in the S = - 2 sector. Specifically, the couplings of the pseudoscalar mesons to the baryons are fixed by SU(3) symmetry and, in general, also the contact terms are related via SU(3) symmetry to those determined in a previous study of the S = - 1 hyperon-nucleon interaction. The explicit SU(3) symmetry breaking due to the physical masses of the pseudoscalar mesons (π, K, η) is taken into account. It is argued that the ΞN interaction has to be relatively weak to be in accordance with available experimental constraints. In particular, the published values and upper bounds for the Ξ- p elastic and inelastic cross sections apparently rule out a somewhat stronger attractive ΞN force and, specifically, disfavor any near-threshold deuteron-like bound states in that system.

  7. Chiral squaring

    NASA Astrophysics Data System (ADS)

    Nagy, S.

    2016-07-01

    We construct the states and symmetries of N = 4 super-Yang-Mills by tensoring two N = 1 chiral multiplets and introducing two extra SUSY generators. This allows us to write the maximal N = 8 supergravity as four copies of the chiral multiplet. We extend this to higher dimensions and discuss applications to scattering amplitudes.

  8. Nuclear Chirality

    SciTech Connect

    Starosta, Krzysztof

    2005-04-05

    Nuclear chirality is a novel manifestation of spontaneous symmetry breaking resulting from an orthogonal coupling of angular momentum vectors in triaxial nuclei. Three perpendicular angular momenta can form two systems of opposite handedness; the time reversal operator, which reverses orientation of each of the angular momentum components, relates these two systems. The status of current experimental searches for chiral doubling of states, as well as recent progress on the theoretical side is reviewed.

  9. Isotopic chirality

    SciTech Connect

    Floss, H.G.

    1994-12-01

    This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

  10. Chiral nucleon-nucleon forces in nuclear structure calculations

    NASA Astrophysics Data System (ADS)

    Coraggio, L.; Gargano, A.; Holt, J. W.; Itaco, N.; Machleidt, R.; Marcucci, L. E.; Sammarruca, F.

    2016-05-01

    Realistic nuclear potentials, derived within chiral perturbation theory, are a major breakthrough in modern nuclear structure theory, since they provide a direct link between nuclear physics and its underlying theory, namely the QCD. As a matter of fact, chiral potentials are tailored on the low-energy regime of nuclear structure physics, and chiral perturbation theory provides on the same footing two-nucleon forces as well as many-body ones. This feature fits well with modern advances in ab-initio methods and realistic shell-model. Here, we will review recent nuclear structure calculations, based on realistic chiral potentials, for both finite nuclei and infinite nuclear matter.

  11. Prebiotic chirality

    NASA Astrophysics Data System (ADS)

    Mekki-Berrada, Ali

    Bringing closer phospholipids each other on a bilayer of liposome, causes their rotation around their fatty acids axis, generating a force which brings closer the two sheets of the bilayer. In this theoretical study I show that for getting the greater cohesion of the liposome, by these forces, the serine in the hydrophilic head must have a L chirality. In the case where the hydrophilic head is absent amino acids with L chirality could contribute to this cohesion by taking the place of L-serine. Some coenzymes having a configuration similar to ethanolamine may also contribute. This is the case of pyridoxamine, thiamine and tetrahydrofolic acid. The grouping of amino acids of L chirality and pyridoxamine on the wall could initialize the prebiotic metabolism of these L amino acids only. This would explain the origin of the homo-chirality of amino acids in living world. Furthermore I show that in the hydrophilic head, the esterification of glycerol-phosphate by two fatty acids go through the positioning of dihydroxyacetone-phosphate and L-glyceraldehyde-3-phosphate, but not of D-glyceraldehyde-3-phosphate, prior their hydrogenation to glycerol-3- phosphate. The accumulation of D-glyceraldehyde-3-phosphate in the cytoplasm displace the thermodynamic equilibria towards the synthesis of D-dATP from D-glyceraldehyde-3-phosphate, acetaldehyde and prebiotic adenine, a reaction which does not require a coenzyme in the biotic metabolism. D-dATP and thiamine, more prebiotic metabolism of L-amino acids on the wall, would initialize D-pentoses phosphate and D-nucleotides pathways from the reaction of D-glyceraldehyde-3-phosphate + dihydroxyacetone-phosphate + prebiotic nucleic bases. The exhaustion of the prebiotic glyceraldehyde (racemic) and the nascent biotic metabolism dominated by D-glyceraldehyde-3-phosphate, would explain the origin of homo-chirality of sugars in living world. References: http://en.wikiversity.org/wiki/Prebiotic_chirality

  12. An investigation of meson spectroscopy on isotropic clover lattices at the SU(3) flavor-symmetric point

    SciTech Connect

    Richards, David G.; Orginos, Konstantinos

    2014-06-23

    We present an investigation of the excited meson spectrum at the N_f= 3 point obtained on isotropic clover lattices with a plaquette Wilson gauge action, and a NP-improved clover fermion action, at a lattice spacing of a \\simeq 0.08 fm, and compare with corresponding calculations on an anisotropic lattice at fine temporal lattice spacing but a spatial lattice spacing of a_s \\simeq 0.125 fm. The methodology adopted follows that employed in the calculation of the spectrum on anisotropic lattices, and we test the efficacy of that approach for isotropic lattices. In particular, we explore the extent to which rotational symmetry for predominantly single-hadron states is realized. By comparison of the energy levels with that obtained using the anisotropic lattice, we obtain an indication of discretization uncertainties in the single-hadron spectrum.

  13. Light Nuclei and HyperNuclei from Quantum Chromodynamics in the Limit of SU(3) Flavor Symmetry

    SciTech Connect

    Beane, S R; Cohen, S D; Detmold, W; Lin, H W; Luu, T C; Orginos, K; Parreno, A; Savage, M J; Walker-Loud, A

    2013-02-01

    The binding energies of a range of nuclei and hypernuclei with atomic number A <= 4 and strangeness |s| <= 2, including the deuteron, di-neutron, H-dibaryon, {sup 3}He, {sub {Lambda}}{sup 3}He, {sub {Lambda}}{sup 4}He, and {sub {Lambda}{Lambda}}{sup 4}He, are calculated in the limit of flavor-SU(3) symmetry at the physical strange quark mass with quantum chromodynamics (without electromagnetic interactions). The nuclear states are extracted from Lattice QCD calculations performed with n{sub f}=3 dynamical light quarks using an isotropic clover discretization of the quark-action in three lattice volumes of spatial extent L ~ 3.4 fm, 4.5 fm and 6.7 fm, and with a single lattice spacing b ~ 0.145 fm.

  14. Quenched QED in the chiral limit. [QED (quantum electrodynamics)

    SciTech Connect

    Vandermark, S.W.

    1993-01-01

    The main goal in this project has been to understand, through analytical methods, whether there could be a continuum limit for QED. This possibility is motivated by recent lattice simulations on quenched QED which apparently exhibit a chiral phase transition at strong coupling in the chiral limit. Another goal is to develop a novel perturbation expansion which may also be usefully applied to other theories. The author begins with the general expression for the chiral order parameter, ([bar [psi

  15. Renormalization of NN Interaction with Relativistic Chiral Two Pion Exchange

    SciTech Connect

    Higa, R; Valderrama, M Pavon; Arriola, E Ruiz

    2007-06-14

    The renormalization of the NN interaction with the Chiral Two Pion Exchange Potential computed using relativistic baryon chiral perturbation theory is considered. The short distance singularity reduces the number of counter-terms to about a half as those in the heavy-baryon expansion. Phase shifts and deuteron properties are evaluated and a general overall agreement is observed.

  16. Nuclear electromagnetic charge and current operators in Chiral EFT

    SciTech Connect

    Girlanda, Luca; Marcucci, Laura Elisa; Pastore, Saori; Piarulli, Maria; Schiavilla, Rocco; Viviani, Michele

    2013-08-01

    We describe our method for deriving the nuclear electromagnetic charge and current operators in chiral perturbation theory, based on time-ordered perturbation theory. We then discuss possible strategies for fixing the relevant low-energy constants, from the magnetic moments of the deuteron and of the trinucleons, and from the radiative np capture cross sections, and identify a scheme which, partly relying on {Delta} resonance saturation, leads to a reasonable pattern of convergence of the chiral expansion.

  17. Chiral Dynamics 2006

    NASA Astrophysics Data System (ADS)

    Ahmed, Mohammad W.; Gao, Haiyan; Weller, Henry R.; Holstein, Barry

    2007-10-01

    pt. A. Plenary session. Opening remarks: experimental tests of chiral symmetry breaking / A. M. Bernstein. [Double pie symbols] scattering / H. Leutwyler. Chiral effective field theory in a [Triangle]-resonance region / V. Pascalutsa. Some recent developments in chiral perturbation theory / Ulf-G. Mei ner. Chiral extrapolation and nucleon structure from the lattice / R.D. Young. Recent results from HAPPEX / R. Michaels. Chiral symmetries and low energy searches for new physics / M.J. Ramsey-Musolf. Kaon physics: recent experimental progress / M. Moulson. Status of the Cabibbo angle / V. Cirigliano. Lattice QCD and nucleon spin structure / J.W. Negele. Spin sum rules and polarizabilities: results from Jefferson lab / J-P Chen. Compton scattering and nucleon polarisabilities / Judith A. McGovern. Virtual compton scattering at MIT-bates / R. Miskimen. Physics results from the BLAST detector at the BATES accelerator / R.P. Redwine. The [Pie sympbol]NN system, recent progress / C. Hanhart. Application of chiral nuclear forces to light nuclei / A. Nogga. New results on few-body experiments at low energy / Y. Nagai. Few-body lattice calculations / M.J. Savage. Research opportunities at the upgraded HI?S facility / H.R. Weller -- pt. B. Goldstone boson dynamics. Working group summary: Goldstone Boson dynamics / G. Colangelo and S. Giovannella. Recent results on radiative Kaon decays from NA48 and NA48/2 / S.G. López. Cusps in K-->3 [Pie symbol] decays / B. Kubis. Recent KTeV results on radiative Kaon decays / M.C. Ronquest. The [Double pie symbols] scattering amplitude / J.R. Peláez. Determination of the Regge parameters in the [Double pie symbols] scattering amplitude / I. Caprini. e+e- Hadronic cross section measurement at DA[symbol]NE with the KLOE detector / P. Beltrame. Measurement of the form factors of e+e- -->2([Pie symbol]+[Pie symbol]-), pp and the resonant parameters of the heavy charmonia at BES / H. Hu. Measurement of e+e- multihadronic cross section below 4

  18. Chiral streamers

    SciTech Connect

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya

    2015-10-15

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  19. Chiral limit of QCD

    SciTech Connect

    Gupta, R.

    1994-12-31

    This talk contains an analysis of quenched chiral perturbation theory and its consequences. The chiral behavior of a number of quantities such as the pion mass m{sub pi}{sup 2}, the Bernard-Golterman ratios R and {sub X}, the masses of nucleons, and the kaon B-parameter are examined to see if the singular terms induced by the additional Goldstone boson, {eta}{prime}, are visible in present data. The overall conclusion (different from that presented at the lattice meeting) of this analysis is that even though there are some caveats attached to the indications of the extra terms induced by {eta}{prime} loops, the standard expressions break down when extrapolating the quenched data with m{sub q} < m{sub s}/2 to physical light quarks. I then show that due to the single and double poles in the quenched {eta}{prime}, the axial charge of the proton cannot be calculated using the Adler-Bell-Jackiw anomaly condition. I conclude with a review of the status of the calculation of light quark masses from lattice QCD.

  20. Spontaneous Planar Chiral Symmetry Breaking in Cells

    NASA Astrophysics Data System (ADS)

    Hadidjojo, Jeremy; Lubensky, David

    Recent progress in animal development has highlighted the central role played by planar cell polarity (PCP) in epithelial tissue morphogenesis. Through PCP, cells have the ability to collectively polarize in the plane of the epithelium by localizing morphogenetic proteins along a certain axis. This allows direction-dependent modulation of tissue mechanical properties that can translate into the formation of complex, non-rotationally invariant shapes. Recent experimental observations[1] show that cells, in addition to being planar-polarized, can also spontaneously develop planar chirality, perhaps in the effort of making yet more complex shapes that are reflection non-invariant. In this talk we will present our work in characterizing general mechanisms that can lead to spontaneous chiral symmetry breaking in cells. We decompose interfacial concentration of polarity proteins in a hexagonal cell packing into irreducible representations. We find that in the case of polar concentration distributions, a chiral state can only be reached from a secondary instability after the cells are polarized. However in the case of nematic distributions, we show that a finite-amplitude (subcritical, or ``first-order'') nematic transition can send the system from disorder directly to a chiral state. In addition, we find that perturbing the system by stretching the hexagonal packing enables direct (supercritical, or ``second-order'') chiral transition in the nematic case. Finally, we do a Landau expansion to study competition between stretch-induced chirality and the tendency towards a non-chiral state in packings that have retained the full 6-fold symmetry.

  1. Chiral mirrors

    NASA Astrophysics Data System (ADS)

    Plum, Eric; Zheludev, Nikolay I.

    2015-06-01

    Mirrors are used in telescopes, microscopes, photo cameras, lasers, satellite dishes, and everywhere else, where redirection of electromagnetic radiation is required making them arguably the most important optical component. While conventional isotropic mirrors will reflect linear polarizations without change, the handedness of circularly polarized waves is reversed upon reflection. Here, we demonstrate a type of mirror reflecting one circular polarization without changing its handedness, while absorbing the other. The polarization-preserving mirror consists of a planar metasurface with a subwavelength pattern that cannot be superimposed with its mirror image without being lifted out of its plane, and a conventional mirror spaced by a fraction of the wavelength from the metasurface. Such mirrors enable circularly polarized lasers and Fabry-Pérot cavities with enhanced tunability, gyroscopic applications, polarization-sensitive detectors of electromagnetic waves, and can be used to enhance spectroscopies of chiral media.

  2. Chiral shielding

    SciTech Connect

    Babukhadia, L.; Berdnikov, Ya. A.; Ivanov, A. N.; Scadron, M. D.

    2000-08-01

    We demonstrate how a chiral soft pion theorem (SPT) shields the scalar meson ground-state isoscalar {sigma}(600-700) and isospinor {kappa}(800-900) from detection in a{sub 1}{yields}{pi}({pi}{pi}){sub swave}, {gamma}{gamma}{yields}2{pi}{sup 0}, {pi}{sup -}p{yields}{pi}{sup -}{pi}{sup +}n and K{sup -}p{yields}K{sup -}{pi}{sup +}n processes. While pseudoscalar meson PVV transitions are known to be determined by (only) quark loop diagrams, the above SPT also constrains scalar meson SVV transitions to be governed (only) by meson loop diagrams. We apply this latter SVV theorem to a{sub 0}{yields}{gamma}{gamma} and f{sub 0}{yields}{gamma}{gamma} decays. (c) 2000 The American Physical Society.

  3. Nuclear chiral dynamics and thermodynamics

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Kaiser, Norbert; Weise, Wolfram

    2013-11-01

    This presentation reviews an approach to nuclear many-body systems based on the spontaneously broken chiral symmetry of low-energy QCD. In the low-energy limit, for energies and momenta small compared to a characteristic symmetry breaking scale of order 1 GeV, QCD is realized as an effective field theory of Goldstone bosons (pions) coupled to heavy fermionic sources (nucleons). Nuclear forces at long and intermediate distance scales result from a systematic hierarchy of one- and two-pion exchange processes in combination with Pauli blocking effects in the nuclear medium. Short distance dynamics, not resolved at the wavelengths corresponding to typical nuclear Fermi momenta, are introduced as contact interactions between nucleons. Apart from a set of low-energy constants associated with these contact terms, the parameters of this theory are entirely determined by pion properties and low-energy pion-nucleon scattering observables. This framework (in-medium chiral perturbation theory) can provide a realistic description of both isospin-symmetric nuclear matter and neutron matter, with emphasis on the isospin-dependence determined by the underlying chiral NN interaction. The importance of three-body forces is emphasized, and the role of explicit Δ(1232)-isobar degrees of freedom is investigated in detail. Nuclear chiral thermodynamics is developed and a calculation of the nuclear phase diagram is performed. This includes a successful description of the first-order phase transition from a nuclear Fermi liquid to an interacting Fermi gas and the coexistence of these phases below a critical temperature Tc. Density functional methods for finite nuclei based on this approach are also discussed. Effective interactions, their density dependence and connections to Landau Fermi liquid theory are outlined. Finally, the density and temperature dependences of the chiral (quark) condensate are investigated.

  4. Understanding complex chiral plasmonics.

    PubMed

    Duan, Xiaoyang; Yue, Song; Liu, Na

    2015-11-01

    Chiral nanoplasmonics exhibits great potential for novel nanooptical devices due to the generation of a strong chiroptical response within nanoscale metallic structures. Recently, a number of different approaches have been utilized to create chiral nanoplasmonic structures. However, particularly for tailoring nanooptical chiral sensing devices, the understanding of the resulting chiroptical response when coupling chiral and achiral structures together is crucial and has not been completely understood to date. Here, we present a thorough and step-by-step experimental study to understand the intriguing chiral-achiral coupling scheme. We set up a hybrid plasmonic system, which bears resemblance to the 'host-guest' system in supramolecular chemistry to analyze and explain the complex chiral response both at the chiral and achiral plasmonic resonances. We also provide an elegant and simple analytical model, which can describe, predict, and comprehend the chiroptical spectra in detail. Our study will shed light on designing well-controlled chiral-achiral coupling platforms for reliable chiral sensing.

  5. Four-modulus ``Swiss Cheese'' chiral models

    NASA Astrophysics Data System (ADS)

    Collinucci, Andrés; Kreuzer, Maximilian; Mayrhofer, Christoph; Walliser, Nils-Ole

    2009-07-01

    We study the `Large Volume Scenario' on explicit, new, compact, four-modulus Calabi-Yau manifolds. We pay special attention to the chirality problem pointed out by Blumenhagen, Moster and Plauschinn. Namely, we thoroughly analyze the possibility of generating neutral, non-perturbative superpotentials from Euclidean D3-branes in the presence of chirally intersecting D7-branes. We find that taking proper account of the Freed-Witten anomaly on non-spin cycles and of the Kähler cone conditions imposes severe constraints on the models. Nevertheless, we are able to create setups where the constraints are solved, and up to three moduli are stabilized.

  6. Chiral logarithms in the massless limit tamed.

    PubMed

    Kivel, Nikolai; Polyakov, Maxim V; Vladimirov, Alexei

    2008-12-31

    We derive nonlinear recursion relations for the leading chiral logarithms (LLs) in massless theories. These relations not only provide a very efficient method of computation of LLs (e.g., the 33-loop contribution is calculated in a dozen of seconds on a PC) but also equip us with a powerful tool for the summation of the LLs. Our method is not limited to chiral perturbation theory only; it is pertinent to any nonrenormalizable effective field theory such as, for instance, the theory of critical phenomena, low-energy quantum gravity, etc.

  7. Long-range interactions between chiral molecules

    SciTech Connect

    Salam, A.

    2015-01-22

    Results of molecular quantum electrodynamics calculations of discriminatory interactions between two chiral molecules undergoing resonance energy transfer, van der Waals dispersion, and optical binding are presented. A characteristic feature of the theory is that the radiation field is quantized with signals consequently propagating between centres at the speed of light. In order to correctly describe optically active chromophores, it is necessary to include magnetic as well as electric dipole coupling terms in the time-dependent perturbation theory computations. Recent work investigating the effect of an absorptive and dispersive chiral medium on the rate of migration of energy will also be discussed.

  8. Chiral logarithms in quenched QCD

    SciTech Connect

    Y. Chen; S. J. Dong; T. Draper; I. Horvath; F. X. Lee; K. F. Liu; N. Mathur; and J. B. Zhang

    2004-08-01

    The quenched chiral logarithms are examined on a 163x28 lattice with Iwasaki gauge action and overlap fermions. The pion decay constant fpi is used to set the lattice spacing, a = 0.200(3) fm. With pion mass as low as {approx}180 MeV, we see the quenched chiral logarithms clearly in mpi2/m and fP, the pseudoscalar decay constant. The authors analyze the data to determine how low the pion mass needs to be in order for the quenched one-loop chiral perturbation theory (chiPT) to apply. With the constrained curve-fitting method, they are able to extract the quenched chiral logarithmic parameter delta together with other low-energy parameters. Only for mpi<=300 MeV do we obtain a consistent and stable fit with a constant delta which they determine to be 0.24(3)(4) (at the chiral scale Lambdachi = 0.8 GeV). By comparing to the 123x28 lattice, they estimate the finite volume effect to be about 2.7% for the smallest pion mass. They also fitted the pion mass to the form for the re-summed cactus diagrams and found that its applicable region is extended farther than the range for the one-loop formula, perhaps up to mpi {approx}500-600 MeV. The scale independent delta is determined to be 0.20(3) in this case. The authors study the quenched non-analytic terms in the nucleon mass and find that the coefficient C1/2 in the nucleon mass is consistent with the prediction of one-loop chiPT. They also obtain the low energy constant L5 from fpi. They conclude from this study that it is imperative to cover only the range of data with the pion mass less than {approx}300 MeV in order to examine the chiral behavior of the hadron masses and decay constants in quenched QCD and match them with quenched one-loop chiPT.

  9. Chiral symmetry and chiral-symmetry breaking

    SciTech Connect

    Peskin, M.E.

    1982-12-01

    These lectures concern the dynamics of fermions in strong interaction with gauge fields. Systems of fermions coupled by gauge forces have a very rich structure of global symmetries, which are called chiral symmetries. These lectures will focus on the realization of chiral symmetries and the causes and consequences of thier spontaneous breaking. A brief introduction to the basic formalism and concepts of chiral symmetry breaking is given, then some explicit calculations of chiral symmetry breaking in gauge theories are given, treating first parity-invariant and then chiral models. These calculations are meant to be illustrative rather than accurate; they make use of unjustified mathematical approximations which serve to make the physics more clear. Some formal constraints on chiral symmetry breaking are discussed which illuminate and extend the results of our more explicit analysis. Finally, a brief review of the phenomenological theory of chiral symmetry breaking is presented, and some applications of this theory to problems in weak-interaction physics are discussed. (WHK)

  10. Isospin breaking and chiral symmetry restoration

    SciTech Connect

    Gomez Nicola, A.; Torres Andres, R.

    2011-04-01

    We analyze quark condensates and chiral (scalar) susceptibilities including isospin-breaking effects at finite temperature T. These include m{sub u{ne}}m{sub d} contributions as well as electromagnetic (e{ne}0) corrections, both treated in a consistent chiral Lagrangian framework to leading order in SU(2) and SU(3) chiral perturbation theory, so that our predictions are model-independent. The chiral restoration temperature extracted from = is almost unaffected, while the isospin-breaking order parameter grows with T for the three-flavor case SU(3). We derive a sum rule relating the condensate ratio (e{ne}0)/(e=0) with the scalar susceptibility difference {chi}(T)-{chi}(0), directly measurable on the lattice. This sum rule is useful also for estimating condensate errors in staggered lattice analysis. Keeping m{sub u{ne}}m{sub d} allows one to obtain the connected and disconnected contributions to the susceptibility, even in the isospin limit, whose temperature, mass, and isospin-breaking dependence we analyze in detail. The disconnected part grows linearly, diverging in the chiral (infrared) limit as T/M{sub {pi}}, while the connected part shows a quadratic behavior, infrared regular as T{sup 2}/M{sub {eta}}{sup 2}, and coming from {pi}{sup 0{eta}} mixing terms. This smooth connected behavior suggests that isospin-breaking correlations are weaker than critical chiral ones near the transition temperature. We explore some consequences in connection with lattice data and their scaling properties, for which our present analysis for physical masses, i.e. beyond the chiral limit, provides a useful model-independent description for low and moderate temperatures.

  11. Chiral corrections to the anomalous 2. gamma. decays of. pi. sup 0 ,. eta. and. eta. prime

    SciTech Connect

    Issler, D.

    1990-11-01

    To any order in chiral perturbation theory, the anomalous Wess-Zumino term is shown to generate only chirally invariant counterterms. Explicit examples of 0(p{sub 6}) terms generated by one-loop graphs are given, some of which are relevant to the two-photon decays of {pi}{sup o}, {eta} and {eta}{prime}.

  12. Chiral rotational spectroscopy

    NASA Astrophysics Data System (ADS)

    Cameron, Robert P.; Götte, Jörg B.; Barnett, Stephen M.

    2016-09-01

    We introduce chiral rotational spectroscopy, a technique that enables the determination of the orientated optical activity pseudotensor components BX X, BY Y, and BZ Z of chiral molecules, in a manner that reveals the enantiomeric constitution of a sample and provides an incisive signal even for a racemate. Chiral rotational spectroscopy could find particular use in the analysis of molecules that are chiral solely by virtue of their isotopic constitution and molecules with multiple chiral centers. A basic design for a chiral rotational spectrometer together with a model of its functionality is given. Our proposed technique offers the more familiar polarizability components αX X, αY Y, and αZ Z as by-products, which could see it find use even for achiral molecules.

  13. Chiral atomically thin films

    NASA Astrophysics Data System (ADS)

    Kim, Cheol-Joo; Sánchez-Castillo, A.; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm–1) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra.

  14. Characterizing optical chirality

    SciTech Connect

    Bliokh, Konstantin Y.; Nori, Franco

    2011-02-15

    We examine the recently introduced measure of chirality of a monochromatic optical field [Y. Tang and A. E. Cohen, Phys. Rev. Lett. 104, 163901 (2010)] using the momentum (plane-wave) representation and helicity basis. Our analysis clarifies the physical meaning of the measure of chirality and unveils its close relation to the polarization helicity, spin angular momentum, energy density, and Poynting energy flow. We derive the operators of the optical chirality and of the corresponding chiral momentum, which acquire remarkably simple forms in the helicity representation.

  15. Chiral atomically thin films

    NASA Astrophysics Data System (ADS)

    Kim, Cheol-Joo; Sánchez-Castillo, A.; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm-1) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra.

  16. Chiral geometry in multiple chiral doublet bands

    NASA Astrophysics Data System (ADS)

    Zhang, Hao; Chen, Qibo

    2016-02-01

    The chiral geometry of multiple chiral doublet bands with identical configuration is discussed for different triaxial deformation parameters γ in the particle rotor model with . The energy spectra, electromagnetic transition probabilities B(M1) and B(E2), angular momenta, and K-distributions are studied. It is demonstrated that the chirality still remains not only in the yrast and yrare bands, but also in the two higher excited bands when γ deviates from 30°. The chiral geometry relies significantly on γ, and the chiral geometry of the two higher excited partner bands is not as good as that of the yrast and yrare doublet bands. Supported by Plan Project of Beijing College Students’ Scientific Research and Entrepreneurial Action, Major State 973 Program of China (2013CB834400), National Natural Science Foundation of China (11175002, 11335002, 11375015, 11461141002), National Fund for Fostering Talents of Basic Science (NFFTBS) (J1103206), Research Fund for Doctoral Program of Higher Education (20110001110087) and China Postdoctoral Science Foundation (2015M580007)

  17. Towards a consistent estimate of the chiral low-energy constants

    NASA Astrophysics Data System (ADS)

    Cirigliano, V.; Ecker, G.; Eidemüller, M.; Kaiser, R.; Pich, A.; Portolés, J.

    2006-10-01

    Guided by the large- N limit of QCD, we construct the most general chiral resonance Lagrangian that can generate chiral low-energy constants up to O(p). By integrating out the resonance fields, the low-energy constants are parametrized in terms of resonance masses and couplings. Information on those couplings and on the low-energy constants can be extracted by analysing QCD Green functions of currents both for large and small momenta. The chiral resonance theory generates Green functions that interpolate between QCD and chiral perturbation theory. As specific examples we consider the and Green functions.

  18. Quantum Monte Carlo calculations with chiral effective field theory interactions.

    PubMed

    Gezerlis, A; Tews, I; Epelbaum, E; Gandolfi, S; Hebeler, K; Nogga, A; Schwenk, A

    2013-07-19

    We present the first quantum Monte Carlo (QMC) calculations with chiral effective field theory (EFT) interactions. To achieve this, we remove all sources of nonlocality, which hamper the inclusion in QMC calculations, in nuclear forces to next-to-next-to-leading order. We perform auxiliary-field diffusion Monte Carlo (AFDMC) calculations for the neutron matter energy up to saturation density based on local leading-order, next-to-leading order, and next-to-next-to-leading order nucleon-nucleon interactions. Our results exhibit a systematic order-by-order convergence in chiral EFT and provide nonperturbative benchmarks with theoretical uncertainties. For the softer interactions, perturbative calculations are in excellent agreement with the AFDMC results. This work paves the way for QMC calculations with systematic chiral EFT interactions for nuclei and nuclear matter, for testing the perturbativeness of different orders, and allows for matching to lattice QCD results by varying the pion mass.

  19. Chiral Extrapolation of Lattice Data for Heavy Meson Hyperfine Splittings

    SciTech Connect

    X.-H. Guo; P.C. Tandy; A.W. Thomas

    2006-03-01

    We investigate the chiral extrapolation of the lattice data for the light-heavy meson hyperfine splittings D*-D and B*-B to the physical region for the light quark mass. The chiral loop corrections providing non-analytic behavior in m{sub {pi}} are consistent with chiral perturbation theory for heavy mesons. Since chiral loop corrections tend to decrease the already too low splittings obtained from linear extrapolation, we investigate two models to guide the form of the analytic background behavior: the constituent quark potential model, and the covariant model of QCD based on the ladder-rainbow truncation of the Dyson-Schwinger equations. The extrapolated hyperfine splittings remain clearly below the experimental values even allowing for the model dependence in the description of the analytic background.

  20. Generalized Polarizabilities and the Chiral Structure of the Nucleon

    SciTech Connect

    Hemmert, T.R.; Knoechlein, G.; Holstein, B.R.; Knoechlein, G.; Scherer, S.

    1997-07-01

    We present results of the first chiral perturbation theory calculation for the generalized polarizabilities of the nucleon and discuss the response functions in virtual Compton scattering to be measured in the scheduled electron scattering experiments. {copyright} {ital 1997} {ital The American Physical Society}

  1. Pion scattering poles and chiral symmetry restoration

    SciTech Connect

    Fernandez-Fraile, D.; Nicola, A. Gomez; Herruzo, E. T.

    2007-10-15

    Using unitarized chiral perturbation theory methods, we perform a detailed analysis of the {pi}{pi} scattering poles f{sub 0}(600) and {rho}(770) behavior when medium effects such as temperature or density drive the system towards chiral symmetry restoration. In the analysis of real poles below threshold, we show that it is crucial to extend properly the unitarized amplitudes so that they match the perturbative Adler zeros. Our results do not show threshold enhancement effects at finite temperature in the f{sub 0}(600) channel, which remains as a pole of broad nature. We also implement T=0 finite-density effects related to chiral symmetry restoration, by varying the pole position with the pion decay constant. Although this approach takes into account only a limited class of contributions, we reproduce the expected finite-density restoration behavior, which drives the poles towards the real axis, producing threshold enhancement and {pi}{pi} bound states. We compare our results with several model approaches and discuss the experimental consequences, both in relativistic heavy ion collisions and in {pi}{yields}{pi}{pi} and {gamma}{yields}{pi}{pi} reactions in nuclei.

  2. Molecular model for chirality phenomena

    NASA Astrophysics Data System (ADS)

    Latinwo, Folarin; Stillinger, Frank H.; Debenedetti, Pablo G.

    2016-10-01

    Chirality is a hallmark feature for molecular recognition in biology and chemical physics. We present a three-dimensional continuum model for studying chirality phenomena in condensed phases using molecular simulations. Our model system is based upon a simple four-site molecule and incorporates non-trivial kinetic behavior, including the ability to switch chirality or racemize, as well as thermodynamics arising from an energetic preference for specific chiral interactions. In particular, we introduce a chiral renormalization parameter that can locally favor either homochiral or heterochiral configurations. Using this model, we explore a range of chirality-specific phenomena, including the kinetics of chiral inversion, the mechanism of spontaneous chiral symmetry breaking in the liquid, chirally driven liquid-liquid phase separation, and chiral crystal structures.

  3. Synthesis of Chiral Cyclopentenones.

    PubMed

    Simeonov, Svilen P; Nunes, João P M; Guerra, Krassimira; Kurteva, Vanya B; Afonso, Carlos A M

    2016-05-25

    The cyclopentenone unit is a very powerful synthon for the synthesis of a variety of bioactive target molecules. This is due to the broad diversity of chemical modifications available for the enone structural motif. In particular, chiral cyclopentenones are important precursors in the asymmetric synthesis of target chiral molecules. This Review provides an overview of reported methods for enantioselective and asymmetric syntheses of cyclopentenones, including chemical and enzymatic resolution, asymmetric synthesis via Pauson-Khand reaction, Nazarov cyclization and organocatalyzed reactions, asymmetric functionalization of the existing cyclopentenone unit, and functionalization of chiral building blocks. PMID:27101336

  4. Kaon Thresholds and Two-Flavor Chiral Expansions for Hyperons

    SciTech Connect

    Fu-Jiun Jiang, Brian C. Tiburzi, Andre Walker-Loud

    2011-01-01

    Two-flavor chiral expansions provide a useful perturbative framework to study hadron properties. Such expansions should exhibit marked improvement over the conventional three-flavor chiral expansion. Although one can theoretically formulate two-flavor theories for the various hyperon multiplets, the nearness of kaon thresholds can seriously undermine the effectiveness of the perturbative expansion in practice. We investigate the importance of virtual kaon thresholds on hyperon properties, specifically their masses and isovector axial charges. Using a three-flavor expansion that includes SU(3) breaking effects, we uncover the underlying expansion parameter governing the description of virtual kaon thresholds. For spin-half hyperons, this expansion parameter is quite small. Consequently virtual kaon contributions are well described in the two-flavor theory by terms analytic in the pion mass-squared. For spin three-half hyperons, however, one is closer to the kaon production threshold, and the expansion parameter is not as small. Breakdown of SU(2) chiral perturbation theory is shown to arise from a pole in the expansion parameter associated with the kaon threshold. Estimating higher-order corrections to the expansion parameter is necessary to ascertain whether the two-flavor theory of spin three-half hyperons remains perturbative. We find that, despite higher-order corrections, there is a useful perturbative expansion for the masses and isovector axial charges of both spin-half and spin three-half hyperons.

  5. Catalysis of dynamical chiral symmetry breaking by chiral chemical potential

    NASA Astrophysics Data System (ADS)

    Braguta, V. V.; Kotov, A. Yu.

    2016-05-01

    In this paper, we study the properties of media with chiral imbalance parametrized by chiral chemical potential. It is shown that depending on the strength of interaction between constituents in the media the chiral chemical potential either creates or enhances dynamical chiral symmetry breaking. Thus, the chiral chemical potential plays the role of the catalyst of dynamical chiral symmetry breaking. Physically, this effect results from the appearance of the Fermi surface and additional fermion states on this surface, which take part in dynamical chiral symmetry breaking. An interesting conclusion which can be drawn is that at sufficiently small temperature chiral plasma is unstable with respect to condensation of Cooper pairs and dynamical chiral symmetry breaking even for vanishingly small interactions between constituents.

  6. Criteria of backscattering in chiral one-way photonic crystals

    NASA Astrophysics Data System (ADS)

    Cheng, Pi-Ju; Chang, Shu-Wei

    2016-03-01

    Optical isolators are important devices in photonic circuits. To reduce the unwanted reflection in a robust manner, several setups have been realized using nonreciprocal schemes. In this study, we show that the propagating modes in a strongly-guided chiral photonic crystal (no breaking of the reciprocity) are not backscattering-immune even though they are indeed insensitive to many types of scatters. Without the protection from the nonreciprocity, the backscattering occurs under certain circumstances. We present a perturbative method to calculate the backscattering of chiral photonic crystals in the presence of chiral/achiral scatters. The model is, essentially, a simplified analogy to the first-order Born approximation. Under reasonable assumptions based on the behaviors of chiral photonic modes, we obtained the expression of reflection coefficients which provides criteria for the prominent backscattering in such chiral structures. Numerical examinations using the finite-element method were also performed and the results agree well with the theoretical prediction. From both our theory and numerical calculations, we find that the amount of backscattering critically depends on the symmetry of scatter cross sections. Strong reflection takes place when the azimuthal Fourier components of scatter cross sections have an order l of 2. Chiral scatters without these Fourier components would not efficiently reflect the chiral photonic modes. In addition, for these chiral propagating modes, disturbances at the most significant parts of field profiles do not necessarily result in the most effective backscattering. The observation also reveals what types of scatters or defects should be avoided in one-way applications of chiral structures in order to minimize the backscattering.

  7. Chiral corrections to the anomalous 2{gamma} decays of {pi}{sup 0}, {eta} and {eta}{prime}

    SciTech Connect

    Issler, D.

    1990-11-01

    To any order in chiral perturbation theory, the anomalous Wess-Zumino term is shown to generate only chirally invariant counterterms. Explicit examples of 0(p{sub 6}) terms generated by one-loop graphs are given, some of which are relevant to the two-photon decays of {pi}{sup o}, {eta} and {eta}{prime}.

  8. Spintronics: Chiral damping

    PubMed Central

    Kim, Kyoung-Whan; Lee, Hyun-Woo

    2016-01-01

    The analysis of the magnetic domain wall motion in a nanostructured magnetic system with strong spin-orbit coupling shows that the energy dissipation can be chiral when the inversion symmetry is broken. PMID:26906956

  9. Nonlinear chiral transport phenomena

    NASA Astrophysics Data System (ADS)

    Chen, Jiunn-Wei; Ishii, Takeaki; Pu, Shi; Yamamoto, Naoki

    2016-06-01

    We study the nonlinear responses of relativistic chiral matter to the external fields such as the electric field E , gradients of temperature and chemical potential, ∇T and ∇μ . Using the kinetic theory with Berry curvature corrections under the relaxation time approximation, we compute the transport coefficients of possible new electric currents that are forbidden in usual chirally symmetric matter but are allowed in chirally asymmetric matter by parity. In particular, we find a new type of electric current proportional to ∇μ ×E due to the interplay between the effects of the Berry curvature and collisions. We also derive an analog of the "Wiedemann-Franz" law specific for anomalous nonlinear transport in relativistic chiral matter.

  10. The quest for chirality

    SciTech Connect

    Bonner, W.A.

    1996-07-01

    The indispensable role played by homochirality and chiral homogeneity in the self-replication of crucial biomolecules is stressed, with the conclusion that life could neither exist nor originate without these chiral molecular attributes. Hypotheses historically proposed for the origin of chiral molecules on Earth are reviewed, including biogenic theories as well as abiotic theories embracing both indeterminate and determinate mechanisms. Indeterminate mechanisms, including autocatalytic symmetry breaking, asymmetric adsorption on quartz and clay minerals, and asymmetric syntheses in chiral crystals, are discussed and evaluated in the context of the prebiotic environment. Abiotic determinate mechanisms based on electric, magnetic and gravitational fields, on circularly polarized light (CPL), and on parity violation effects are summarized, with the emphasis that only CPL has proved practicable experimentally, but that it would be implausible on the primitive Earth. Mechanisms for the amplification of small, indigenous enantiomeric excesses are discussed, with one involving the partial polymerization of amino acids and the partial hydrolysis of polypeptides suggested as potentially viable prebiotically. Aspects of the turbulent, chirality-destructive primeval environment are described, with the conclusion that all of the above mechanisms for the {ital terrestrial} prebiotic origin of chirality would be non-viable, and that an alternative extraterrestrial source for the accumulation of chiral molecules on primitive Earth must have been operative. A scenario for this is outlined, in which we postulate that asymmetric photolysis of the organic mantles on interstellar grains in molecular clouds by circularly polarized ultraviolet synchrotron radiation from the neutron star remnants of supernovae produces chiral molecules in the grain mantles. (Abstract Truncated)

  11. Nuclear axial currents in chiral effective field theory

    DOE PAGESBeta

    Baroni, Alessandro; Girlanda, Luca; Pastore, Saori; Schiavilla, Rocco; Viviani, Michele

    2016-01-11

    Two-nucleon axial charge and current operators are derived in chiral effective field theory up to one loop. The derivation is based on time-ordered perturbation theory and accounts for cancellations between the contributions of irreducible diagrams and the contributions owing to nonstatic corrections from energy denominators of reducible diagrams. Ultraviolet divergencies associated with the loop corrections are isolated in dimensional regularization. The resulting axial current is finite and conserved in the chiral limit, while the axial charge requires renormalization. As a result, a complete set of contact terms for the axial charge up to the relevant order in the power countingmore » is constructed.« less

  12. Circular Dichroism in the Photoionization of Nanoparticles from Chiral Compounds

    SciTech Connect

    Paul, J.; Doerzbach, A.; Siegmann, K.

    1997-10-01

    The dichroism in photoemission from chiral molecules is observed for the first time. Particles consisting of chiral molecules are suspended in air and irradiated alternately with right and left circularly polarized uv light. We found a polarization dependence in the total photoelectric current. The asymmetries observed are of the order of 10{sup {minus}2} to 10{sup {minus}3} , as expected from perturbation theory, and reverse their sign when the handedness of the molecules is changed. {copyright} {ital 1997} {ital The American Physical Society}

  13. Perturbative QUANTUM GRAVITY

    NASA Astrophysics Data System (ADS)

    't Hooft, Gerard

    2003-12-01

    A good understanding of Perturbative Quantum Gravity is essential for anyone who wishes to proceed towards any kind of non-perturbative approach. This lecture is a brief resumé of the main features of the perturbative regime.

  14. Chiral anomalies and differential geometry

    SciTech Connect

    Zumino, B.

    1983-10-01

    Some properties of chiral anomalies are described from a geometric point of view. Topics include chiral anomalies and differential forms, transformation properties of the anomalies, identification and use of the anomalies, and normalization of the anomalies. 22 references. (WHK)

  15. Active Chiral Plasmonics.

    PubMed

    Yin, Xinghui; Schäferling, Martin; Michel, Ann-Katrin U; Tittl, Andreas; Wuttig, Matthias; Taubner, Thomas; Giessen, Harald

    2015-07-01

    Active control over the handedness of a chiral metamaterial has the potential to serve as key element for highly integrated polarization engineering approaches, polarization sensitive imaging devices, and stereo display technologies. However, this is hard to achieve as it seemingly involves the reconfiguration of the metamolecule from a left-handed into a right-handed enantiomer and vice versa. This type of mechanical actuation is intricate and usually neither monolithically realizable nor viable for high-speed applications. Here, enabled by the phase change material Ge3Sb2Te6 (GST-326), we demonstrate a tunable and switchable mid-infrared plasmonic chiral metamaterial in a proof-of-concept experiment. A large tunability range of the circular dichroism response from λ = 4.15 to 4.90 μm is achieved, and we experimentally demonstrate that the combination of a passive bias-type chiral layer with the active chiral metamaterial allows for switchable chirality, that is, the reversal of the circular dichroism sign, in a fully planar, layered design without the need for geometrical reconfiguration. Because phase change materials can be electrically and optically switched, our designs may open up a path for highly integrated mid-IR polarization engineering devices that can be modulated on ultrafast time scales.

  16. Chiral corrections to the vector and axial couplings of quarks and baryons

    SciTech Connect

    Faessler, Amand; Gutsche, Thomas; Lyubovitskij, Valery E.; Holstein, Barry R.

    2008-06-01

    We calculate chiral corrections to the semileptonic vector and axial quark coupling constants using a manifestly Lorentz covariant chiral quark approach up to order O(p{sup 4}) in the two- and three-flavor pictures. These couplings are then used in the evaluation of the corresponding couplings which govern the semileptonic transitions between octet baryon states. In the calculation of baryon matrix elements we use a general ansatz for the spatial form of the quark wave function, without referring to a specific realization of hadronization and confinement of quarks in baryons. Matching the physical amplitudes calculated within our approach to the model-independent predictions of baryon chiral perturbation theory allows us to deduce a connection between our parameters and those of baryon chiral perturbation theory.

  17. A preliminary analysis of {eta}'{yields}{eta}{pi}{pi} in chiral theories

    SciTech Connect

    Escribano, R.

    2010-08-05

    Preliminary results for the Dalitz plot distribution of {eta}'{yields}{eta}{pi}{pi} decays in the frameworks of Large-N{sub c} Chiral Perturbation Theory and Resonance Chiral Theory are given. We hope our results to be of some relevance for the present and forthcoming analysis of these decays at GAMS, CLEO, VES, KLOE-2, Crystal Ball, Crystal Barrel, WASA, and BES-III.

  18. Chiral condensate in a constant electromagnetic field at O(p{sup 6})

    SciTech Connect

    Werbos, Elizabeth S.

    2008-06-15

    We examine the shift in the chiral condensate due to a constant electromagnetic field at O(p{sup 6}) using SU(2) chiral perturbation theory and a realistic M{sub {pi}}=140 MeV. We find that this value differs significantly from the value calculated using M{sub {pi}}=0, while the magnitude of the two-loop correction is unclear due to the uncertainty in the experimentally determined value of the relevant L{sub 6} LEC.

  19. Chirality and Life

    NASA Astrophysics Data System (ADS)

    Barron, Laurence D.

    Chirality, meaning handedness, pervades much of modern science, from the physics of elementary particles to the chemistry of life. The amino acids and sugars from which the central molecules of life—proteins and nucleic acids—are constructed exhibit homochirality, which is expected to be a key biosignature in astrobiology. This article provides a brief review of molecular chirality and its significance for the detection of extant or extinct life on other worlds. Fundamental symmetry aspects are emphasized since these bring intrinsic physical properties of the universe to bear on the problem of the origin and role of homochirality in the living world.

  20. Chirality and Life

    NASA Astrophysics Data System (ADS)

    Barron, Laurence D.

    2008-03-01

    Chirality, meaning handedness, pervades much of modern science, from the physics of elementary particles to the chemistry of life. The amino acids and sugars from which the central molecules of life—proteins and nucleic acids—are constructed exhibit homochirality, which is expected to be a key biosignature in astrobiology. This article provides a brief review of molecular chirality and its significance for the detection of extant or extinct life on other worlds. Fundamental symmetry aspects are emphasized since these bring intrinsic physical properties of the universe to bear on the problem of the origin and role of homochirality in the living world.

  1. Staggered fermions and chiral symmetry breaking in transverse lattice regulated QED

    SciTech Connect

    Griffin, P.A.

    1992-07-01

    Staggered fermions are constructed for the transverse lattice regularization scheme. The weak perturbation theory of transverse lattice non-compact QED is developed in light-cone gauge, and we argue that for fixed lattice spacing this theory is ultraviolet finite, order by order in perturbation theory. However, by calculating the anomalous scaling dimension of the link fields, we find that the interaction Hamiltonian becomes non-renormalizable for g{sup 2}(a) > 4{pi}, where g(a) is the bare (lattice) QED coupling constant. We conjecture that this is the critical point of the chiral symmetry breaking phase transition in QED. Non-perturbative chiral symmetry breaking is then studied in the strong coupling limit. The discrete remnant of chiral symmetry that remains on the lattice is spontaneously broken, and the ground state to lowest order in the strong coupling expansion corresponds to the classical ground state of the two-dimensional spin one-half Heisenberg antiferromagnet.

  2. Determination of the chiral condensate from QCD Dirac spectrum on the lattice

    SciTech Connect

    Fukaya, H.; Onogi, T.; Aoki, S.; Chiu, T. W.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Noaki, J.

    2011-04-01

    We calculate the chiral condensate of QCD with 2, 2+1, and 3 flavors of sea quarks. Lattice QCD simulations are performed employing dynamical overlap fermions with up- and down-quark masses covering a range between 3 and 100 MeV. On L{approx}1.8-1.9 fm lattices at a lattice spacing {approx}0.11 fm, we calculate the eigenvalue spectrum of the overlap-Dirac operator. By matching the lattice data with the analytical prediction from chiral perturbation theory at the next-to-leading order, the chiral condensate in the massless limit of up and down quarks is determined.

  3. Intrinsic transverse momentum and dynamical chiral symmetry breaking

    SciTech Connect

    Christian Weiss, Peter Schweitzer, Mark Strikman

    2013-01-01

    We study the effect of QCD vacuum structure on the intrinsic transverse momentum distribution of partons in the nucleon at a low scale. The dynamical breaking of chiral symmetry is caused by non-perturbative interactions at distances of the order rho ~ 0.2 - 0.3 fm, much smaller than the typical nucleon size R ~ 1 fm, resulting in a two-scale picture of nucleon structure. Using an effective dynamical model based on chiral constituent quark degrees of freedom and the 1/N_c expansion (chiral quark-soliton model), we calculate the transverse momentum distribution of quarks and antiquarks at a low scale. The distribution of valence quarks is localized at p_T ~ 1/R. The distribution of flavor-singlet unpolarized sea quarks exhibits a power-like tail extending up to the chiral-symmetry-breaking scale 1/{rho}. A similar tail is present in the flavor-nonsinglet polarized sea. These features are model-independent and represent the imprint of the QCD vacuum on the nucleon's partonic structure. At the level of the nucleon's light-cone wave function, we show that sea quarks partly exist in correlated pairs of transverse size {rho} << R, analogous to short-range NN correlations in nuclei. We discuss the implications of our findings for the transverse momentum distributions in hard scattering processes (semi-inclusive DIS, Drell-Yan pair production) and possible experimental tests of the non-perturbative parton correlations induced by QCD vacuum structure.

  4. Chiral Lagrangian from Duality and Monopole Operators in Compactified QCD.

    PubMed

    Cherman, Aleksey; Schäfer, Thomas; Ünsal, Mithat

    2016-08-19

    We show that there exists a special compactification of QCD on R^{3}×S^{1} in which the theory has a domain where continuous chiral symmetry breaking is analytically calculable. We give a microscopic derivation of the chiral Lagrangian, the chiral condensate, and the Gell-Mann-Oakes-Renner relation m_{π}^{2}f_{π}^{2}=-m_{q}⟨q[over ¯]q⟩. Abelian duality, monopole operators, and flavor-twisted boundary conditions play the main roles. The flavor twisting leads to the new effect of fractional jumping of fermion zero modes among monopole instantons. Chiral symmetry breaking is induced by monopole-instanton operators, and the Nambu-Goldstone pions arise by color-flavor transmutation from gapless "dual photons." We also give a microscopic picture of the "constituent quark" masses. Our results are consistent with expectations from chiral perturbation theory at large S^{1}, and yield strong support for adiabatic continuity between the small-S^{1} and large-S^{1} regimes. We also find concrete microscopic connections between N=1 and N=2 supersymmetric gauge theory dynamics and nonsupersymmetric QCD dynamics. PMID:27588843

  5. Invariant regularization of anomaly-free chiral theories

    NASA Astrophysics Data System (ADS)

    Chang, Lay Nam; Soo, Chopin

    1997-02-01

    We present a generalization of the Frolov-Slavnov invariant regularization scheme for chiral fermion theories in curved spacetimes. The Lagrangian level regularization is explicitly invariant under all the local gauge symmetries of the theory, including local Lorentz invariance. The perturbative scheme works for arbitrary representations which satisfy the chiral gauge anomaly and the mixed Lorentz-gauge anomaly cancellation conditions. Anomalous theories on the other hand manifest themselves by having divergent fermion loops which remain unregularized by the scheme. Since the invariant scheme is promoted to include also local Lorentz invariance, spectator fields which do not couple to gravity cannot be, and are not, introduced. Furthermore, the scheme is truly chiral (Weyl) in that all fields, including the regulators, are left handed; and only the left-handed spin connection is needed. The scheme is, therefore, well suited for the study of the interaction of matter with all four known forces in a completely chiral fashion. In contrast with the vectorlike formulation, the degeneracy between the Adler-Bell-Jackiw current and the fermion number current in the bare action is preserved by the chiral regularization scheme.

  6. Chiral Lagrangian from Duality and Monopole Operators in Compactified QCD

    NASA Astrophysics Data System (ADS)

    Cherman, Aleksey; Schäfer, Thomas; Ünsal, Mithat

    2016-08-01

    We show that there exists a special compactification of QCD on R3×S1 in which the theory has a domain where continuous chiral symmetry breaking is analytically calculable. We give a microscopic derivation of the chiral Lagrangian, the chiral condensate, and the Gell-Mann-Oakes-Renner relation mπ2fπ2=-mq⟨q ¯ q ⟩ . Abelian duality, monopole operators, and flavor-twisted boundary conditions play the main roles. The flavor twisting leads to the new effect of fractional jumping of fermion zero modes among monopole instantons. Chiral symmetry breaking is induced by monopole-instanton operators, and the Nambu-Goldstone pions arise by color-flavor transmutation from gapless "dual photons." We also give a microscopic picture of the "constituent quark" masses. Our results are consistent with expectations from chiral perturbation theory at large S1, and yield strong support for adiabatic continuity between the small-S1 and large-S1 regimes. We also find concrete microscopic connections between N =1 and N =2 supersymmetric gauge theory dynamics and nonsupersymmetric QCD dynamics.

  7. Chiral EFT based nuclear forces: achievements and challenges

    NASA Astrophysics Data System (ADS)

    Machleidt, R.; Sammarruca, F.

    2016-08-01

    During the past two decades, chiral effective field theory has become a popular tool to derive nuclear forces from first principles. Two-nucleon interactions have been worked out up to sixth order of chiral perturbation theory and three-nucleon forces up to fifth order. Applications of some of these forces have been conducted in nuclear few- and many-body systems—with a certain degree of success. But in spite of these achievements, we are still faced with great challenges. Among them is the issue of a proper uncertainty quantification of predictions obtained when applying these forces in ab initio calculations of nuclear structure and reactions. A related problem is the order by order convergence of the chiral expansion. We start this review with a pedagogical introduction and then present the current status of the field of chiral nuclear forces. This is followed by a discussion of representative examples for the application of chiral two- and three-body forces in the nuclear many-body system including convergence issues.

  8. Perturbative search for dead-end CFTs

    NASA Astrophysics Data System (ADS)

    Nakayama, Yu

    2015-05-01

    To explore the possibility of self-organized criticality, we look for CFTs without any relevant scalar deformations (a.k.a. dead-end CFTs) within power-counting renormalizable quantum field theories with a weakly coupled Lagrangian description. In three dimensions, the only candidates are pure (Abelian) gauge theories, which may be further deformed by Chern-Simons terms. In four dimensions, we show that there are infinitely many non-trivial candidates based on chiral gauge theories. Using the three-loop beta functions, we compute the gap of scaling dimensions above the marginal value, and it can be as small as and robust against the perturbative corrections. These classes of candidates are very weakly coupled and our perturbative conclusion seems difficult to refute. Thus, the hypothesis that non-trivial dead-end CFTs do not exist is likely to be false in four dimensions.

  9. Optical properties of chiral nanotubes

    NASA Astrophysics Data System (ADS)

    Cecilia, Noguez; Román-Velázquez Carlos, E.; Ariadna, Sánchez; Montes Lilia, Meza

    2004-03-01

    A recent theoretical model [1] is applied to study the optical properties chiral nanostructures like carbon nanotubes. We calculate the Circular Dichroism (CD) spectra for carbon nanotubes with different chirality. The calculated CD spectra show features that allow us to distinguish between nanotubes with different indexes of chirality. Other nanostructures, like chiral fullerenes are also investigated.These results provide theoretical support for the quantification of chirality and its measurement, using the CD lineshapes of chiral. This work has been partly financed by CONACyT grant No. 36651-E and by DGAPA-UNAM grants No. IN104201. [1] C. E. Roman-Velazquez, et al., J. of Phys. Chem. B (Letter) 107, 12035 (2003)

  10. ENANTIOMER-SPECIFIC EFFECTS OF CHIRAL POLLUTANTS

    EPA Science Inventory

    Enantiomers, the mirror image isomers of chiral pollutants, are known to be selective in their interaction with other chiral molecules, including enzymes and other biochemicals. Considerable research has shown, for example, that chiral pesticides are degraded selectively by micr...

  11. Chiral symmetry and pentaquarks

    SciTech Connect

    Dmitri Diakonov

    2004-07-01

    Spontaneous chiral symmetry breaking, mesons and baryons are illustrated in the language of the Dirac theory. Various forces acting between quarks inside baryons are discussed. I explain why the naive quark models typically overestimate pentaquark masses by some 500 MeV and why in the fully relativistic approach to baryons pentaquarks turn out to be light. I discuss briefly why it can be easier to produce pentaquarks at low than at high energies.

  12. Chiral Biomarkers in Meteorites

    NASA Technical Reports Server (NTRS)

    Hoover, Richard B.

    2010-01-01

    The chirality of organic molecules with the asymmetric location of group radicals was discovered in 1848 by Louis Pasteur during his investigations of the rotation of the plane of polarization of light by crystals of sodium ammonium paratartrate. It is well established that the amino acids in proteins are exclusively Levorotary (L-aminos) and the sugars in DNA and RNA are Dextrorotary (D-sugars). This phenomenon of homochirality of biological polymers is a fundamental property of all life known on Earth. Furthermore, abiotic production mechanisms typically yield recemic mixtures (i.e. equal amounts of the two enantiomers). When amino acids were first detected in carbonaceous meteorites, it was concluded that they were racemates. This conclusion was taken as evidence that they were extraterrestrial and produced by abiologically. Subsequent studies by numerous researchers have revealed that many of the amino acids in carbonaceous meteorites exhibit a significant L-excess. The observed chirality is much greater than that produced by any currently known abiotic processes (e.g. Linearly polarized light from neutron stars; Circularly polarized ultraviolet light from faint stars; optically active quartz powders; inclusion polymerization in clay minerals; Vester-Ulbricht hypothesis of parity violations, etc.). This paper compares the measured chirality detected in the amino acids of carbonaceous meteorites with the effect of these diverse abiotic processes. IT is concluded that the levels observed are inconsistent with post-arrival biological contamination or with any of the currently known abiotic production mechanisms. However, they are consistent with ancient biological processes on the meteorite parent body. This paper will consider these chiral biomarkers in view of the detection of possible microfossils found in the Orgueil and Murchison carbonaceous meteorites. Energy dispersive x-ray spectroscopy (EDS) data obtained on these morphological biomarkers will be

  13. Generalized simplicial chiral models

    NASA Astrophysics Data System (ADS)

    Alimohammadi, Masoud

    2000-02-01

    Using the auxiliary field representation of the simplicial chiral models on a ( d-1)-dimensional simplex, the simplicial chiral models are generalized through replacing the term Tr (AA †) in the Lagrangian of these models by an arbitrary class function of AA †; V(AA †) . This is the same method used in defining the generalized two-dimensional Yang-Mills theories (gYM 2) from ordinary YM 2. We call these models the "generalized simplicial chiral models". Using the results of the one-link integral over a U( N) matrix, the large- N saddle-point equations for eigenvalue density function ρ( z) in the weak ( β> βc) and strong ( β< βc) regions are computed. In d=2, where the model is in some sense related to the gYM 2 theory, the saddle-point equations are solved for ρ( z) in the two regions, and the explicit value of critical point βc is calculated for V(B)= Tr B n(B=AA †) . For V(B)= Tr B 2, Tr B 3, and Tr B4, the critical behaviour of the model at d=2 is studied, and by calculating the internal energy, it is shown that these models have a third order phase transition.

  14. Chiral microemulsion electrokinetic chromatography with two chiral components: Improved separations via synergies between a chiral surfactant and a chiral cosurfactant.

    PubMed

    Kahle, Kimberly A; Foley, Joe P

    2006-02-01

    In this study, the combination of two chiral components in a microemulsion formulation for the separation of enantiomers via microemulsion EKC (MEEKC) was successfully accomplished. Previous publications of chiral microemulsions have utilized only one chiral entity; the surfactant, cosurfactant, or oil was chiral. This is the first study, to date, of the effects of using two chiral species in a single pseudostationary phase (PSP). The chiral surfactant dodecoxycarbonylvaline (DDCV) was used in conjunction with the chiral cosurfactant S-2-hexanol. Ethyl acetate was incorporated as the oil core of the microemulsion and the buffer was 50 mM phosphate at a pH of 7. Additionally, a microemulsion prepared with racemic 2-hexanol was used for comparison to a previous DDCV microemulsion and as a baseline for the newly formulated dual chiral microemulsion. The efficiencies, resolutions, and enantioselectivities for the S-2-hexanol, racemic 2-hexanol, and original 1-butanol DDCV microemulsions are compared. The hexanol-based PSPs provide improved efficiencies and resolutions. To evaluate the combination of each DDCV enantiomer (R and S) with S-2-hexanol, changes in Gibb's free energy were calculated. A synergistic effect was found when two chiral components were combined to form a microemulsion.

  15. Chiral drag force

    NASA Astrophysics Data System (ADS)

    Rajagopal, Krishna; Sadofyev, Andrey V.

    2015-10-01

    We provide a holographic evaluation of novel contributions to the drag force acting on a heavy quark moving through strongly interacting plasma. The new contributions are chiral in the sense that they act in opposite directions in plasmas containing an excess of left- or right-handed quarks. The new contributions are proportional to the coefficient of the axial anomaly, and in this sense also are chiral. These new contributions to the drag force act either parallel to or antiparallel to an external magnetic field or to the vorticity of the fluid plasma. In all these respects, these contributions to the drag force felt by a heavy quark are analogous to the chiral magnetic effect (CME) on light quarks. However, the new contribution to the drag force is independent of the electric charge of the heavy quark and is the same for heavy quarks and antiquarks, meaning that these novel effects do not in fact contribute to the CME current. We show that although the chiral drag force can be non-vanishing for heavy quarks that are at rest in the local fluid rest frame, it does vanish for heavy quarks that are at rest in a suitably chosen frame. In this frame, the heavy quark at rest sees counterpropagating momentum and charge currents, both proportional to the axial anomaly coefficient, but feels no drag force. This provides strong concrete evidence for the absence of dissipation in chiral transport, something that has been predicted previously via consideration of symmetries. Along the way to our principal results, we provide a general calculation of the corrections to the drag force due to the presence of gradients in the flowing fluid in the presence of a nonzero chemical potential. We close with a consequence of our result that is at least in principle observable in heavy ion collisions, namely an anticorrelation between the direction of the CME current for light quarks in a given event and the direction of the kick given to the momentum of all the heavy quarks and

  16. Density perturbation theory

    SciTech Connect

    Palenik, Mark C.; Dunlap, Brett I.

    2015-07-28

    Despite the fundamental importance of electron density in density functional theory, perturbations are still usually dealt with using Hartree-Fock-like orbital equations known as coupled-perturbed Kohn-Sham (CPKS). As an alternative, we develop a perturbation theory that solves for the perturbed density directly, removing the need for CPKS. This replaces CPKS with a true Hohenberg-Kohn density perturbation theory. In CPKS, the perturbed density is found in the basis of products of occupied and virtual orbitals, which becomes ever more over-complete as the size of the orbital basis set increases. In our method, the perturbation to the density is expanded in terms of a series of density basis functions and found directly. It is possible to solve for the density in such a way that it makes the total energy stationary even if the density basis is incomplete.

  17. Isothermal Titration Calorimetry of Chiral Polymeric Nanoparticles.

    PubMed

    Werber, Liora; Preiss, Laura C; Landfester, Katharina; Muñoz-Espí, Rafael; Mastai, Yitzhak

    2015-09-01

    Chiral polymeric nanoparticles are of prime importance, mainly due to their enantioselective potential, for many applications such as catalysis and chiral separation in chromatography. In this article we report on the preparation of chiral polymeric nanoparticles by miniemulsion polymerization. In addition, we describe the use of isothermal titration calorimetry (ITC) to measure the chiral interactions and the energetics of the adsorption of enantiomers from aqueous solutions onto chiral polymeric nanoparticles. The characterization of chirality in nano-systems is a very challenging task; here, we demonstrate that ITC can be used to accurately determine the thermodynamic parameters associated with the chiral interactions of nanoparticles. The use of ITC to measure the energetics of chiral interactions and recognition at the surfaces of chiral nanoparticles can be applied to other nanoscale chiral systems and can provide further insight into the chiral discrimination processes of nanomaterials.

  18. Optical activity of chirally distorted nanocrystals

    NASA Astrophysics Data System (ADS)

    Tepliakov, Nikita V.; Baimuratov, Anvar S.; Baranov, Alexander V.; Fedorov, Anatoly V.; Rukhlenko, Ivan D.

    2016-05-01

    We develop a general theory of optical activity of semiconductor nanocrystals whose chirality is induced by a small perturbation of their otherwise achiral electronic subsystems. The optical activity is described using the quantum-mechanical expressions for the rotatory strengths and dissymmetry factors introduced by Rosenfeld. We show that the rotatory strengths of optically active transitions are decomposed on electric dipole and magnetic dipole contributions, which correspond to the electric dipole and magnetic dipole transitions between the unperturbed quantum states. Remarkably, while the two kinds of rotatory strengths are of the same order of magnitude, the corresponding dissymmetry factors can differ by a factor of 105. By maximizing the dissymmetry of magnetic dipole absorption one can significantly enhance the enantioselectivity in the interaction of semiconductor nanocrystals with circularly polarized light. This feature may advance chiral and analytical methods, which will benefit biophysics, chemistry, and pharmaceutical science. The developed theory is illustrated by an example of intraband transitions inside a semiconductor nanocuboid, whose rotatory strengths and dissymmetry factors are calculated analytically.

  19. Chiral dynamics of deeply bound pionic atoms.

    PubMed

    Kolomeitsev, E E; Kaiser, N; Weise, W

    2003-03-01

    We present and discuss a systematic calculation, based on two-loop chiral perturbation theory, of the pion-nuclear s-wave optical potential. A proper treatment of the explicit energy dependence of the off-shell pion self-energy together with (electromagnetic) gauge invariance of the Klein-Gordon equation turns out to be crucial. Accurate data for the binding energies and widths of the 1s and 2p levels in pionic 205Pb and 207Pb are well reproduced without need for a notorious "missing repulsion" in the pion-nuclear s-wave optical potential. The connection with the in-medium change of the pion decay constant is clarified.

  20. Chiral Crystallization of Ethylenediamine Sulfate

    ERIC Educational Resources Information Center

    Koby, Lawrence; Ningappa, Jyothi B.; Dakesssian, Maria; Cuccia, Louis A.

    2005-01-01

    The optimal conditions for the crystallization of achiral ethylenediamine sulfate into large chiral crystals that are ideal for polarimetry studies and observation using Polaroid sheets are presented. This experiment is an ideal undergraduate experiment, which clearly demonstrates the chiral crystallization of an achiral molecule.

  1. CHIRAL PESTICIDES: OCCURRENCE AND SIGNIFICANCE

    EPA Science Inventory

    Like amino acids, certain pesticides exist in "left-handed" and "right-handed" (chiral) forms. Commercially available chiral pesticides are produced as racemic mixtures in which the ratio of the two forms (or enantiomers) is 1:1. Enantiomers have the same ...

  2. Chiral symmetry and effective field theories for hadronic, nuclear and stellar matter

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Rho, Mannque; Weise, Wolfram

    2016-03-01

    Chiral symmetry, first entering in nuclear physics in the 1970s for which Gerry Brown played a seminal role, has led to a stunningly successful framework for describing strongly-correlated nuclear dynamics both in finite and infinite systems. We review how the early, germinal idea conceived with the soft-pion theorems in the pre-QCD era has evolved into a highly predictive theoretical framework for nuclear physics, aptly assessed by Steven Weinberg: "it (chiral effective field theory) allows one to show in a fairly convincing way that what they (nuclear physicists) have been doing all along... is the correct first step in a consistent approximation scheme". Our review recounts both how the theory presently fares in confronting Nature and how one can understand its extremely intricate workings in terms of the multifaceted aspects of chiral symmetry, namely, chiral perturbation theory, skyrmions, Landau Fermi-liquid theory, the Cheshire cat phenomenon, and hidden local and mended symmetries.

  3. Convergence of the Chiral Expansion in Two-Flavor Lattice QCD

    SciTech Connect

    Noaki, J.; Matsufuru, H.; Shintani, E.; Aoki, S.; Chiu, T. W.; Fukaya, H.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Hsieh, T. H.; Onogi, T.

    2008-11-14

    We test the convergence property of the chiral perturbation theory using a lattice QCD calculation of pion mass and decay constant with two dynamical quark flavors. The lattice calculation is performed using the overlap fermion formulation, which realizes exact chiral symmetry at finite lattice spacing. By comparing various expansion prescriptions, we find that the chiral expansion is well saturated at the next-to-leading order for pions lighter than {approx}450 MeV. Better convergence behavior is found, in particular, for a resummed expansion parameter {xi}, with which the lattice data in the pion mass region 290-750 MeV can be fitted well with the next-to-next-to-leading order formulas. We obtain the results in two-flavor QCD for the low energy constants l{sub 3} and l{sub 4} as well as the pion decay constant, the chiral condensate, and the average up and down quark mass.

  4. Controlling Chirality of Entropic Crystals

    NASA Astrophysics Data System (ADS)

    Damasceno, Pablo F.; Karas, Andrew S.; Schultz, Benjamin A.; Engel, Michael; Glotzer, Sharon C.

    2015-10-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams.

  5. Controlling Chirality of Entropic Crystals.

    PubMed

    Damasceno, Pablo F; Karas, Andrew S; Schultz, Benjamin A; Engel, Michael; Glotzer, Sharon C

    2015-10-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. PMID:26550757

  6. Chiral Shielding Revisited

    SciTech Connect

    Scadron, M. D.

    2008-08-31

    A model-independent chiral soft-pion theorem (SPT) shields the now observed scalar-meson ground-state isoscalar {sigma}(600) and isospinor {kappa}(800) resonances from detection in a{sub 1}{yields}{pi}({pi}{pi}){sub S-wave}, {gamma}{gamma}{yields}2{pi}{sup 0}, {pi}{sup -}P{yields}{pi}{sup -}{pi}{sup +}n, and K{sup -}P{yields}K{sup -}{pi}{sup +}n processes. Moreover, for pseudoscalar-to-vector-vector (PVV) decays, quark loops only are required.

  7. Visualizing the chiral anomaly in Dirac and Weyl semimetals with photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Behrends, Jan; Grushin, Adolfo G.; Ojanen, Teemu; Bardarson, Jens H.

    2016-02-01

    Quantum anomalies are the breaking of a classical symmetry by quantum fluctuations. They dictate how physical systems of diverse nature, ranging from fundamental particles to crystalline materials, respond topologically to external perturbations, insensitive to local details. The anomaly paradigm was triggered by the discovery of the chiral anomaly that contributes to the decay of pions into photons and influences the motion of superfluid vortices in 3He-A. In the solid state, it also fundamentally affects the properties of topological Weyl and Dirac semimetals, recently realized experimentally. In this work we propose that the most identifying consequence of the chiral anomaly, the charge density imbalance between fermions of different chirality induced by nonorthogonal electric and magnetic fields, can be directly observed in these materials with the existing technology of photoemission spectroscopy. With angle resolution, the chiral anomaly is identified by a characteristic note-shaped pattern of the emission spectra, originating from the imbalanced occupation of the bulk states and a previously unreported momentum dependent energy shift of the surface state Fermi arcs. We further demonstrate that the chiral anomaly likewise leaves an imprint in angle averaged emission spectra, facilitating its experimental detection. Thereby, our work provides essential theoretical input to foster the direct visualization of the chiral anomaly in condensed matter, in contrast to transport properties, such as negative magnetoresistance, which can also be obtained in the absence of a chiral anomaly.

  8. Microscopically constrained mean-field models from chiral nuclear thermodynamics

    NASA Astrophysics Data System (ADS)

    Rrapaj, Ermal; Roggero, Alessandro; Holt, Jeremy W.

    2016-06-01

    We explore the use of mean-field models to approximate microscopic nuclear equations of state derived from chiral effective field theory across the densities and temperatures relevant for simulating astrophysical phenomena such as core-collapse supernovae and binary neutron star mergers. We consider both relativistic mean-field theory with scalar and vector meson exchange as well as energy density functionals based on Skyrme phenomenology and compare to thermodynamic equations of state derived from chiral two- and three-nucleon forces in many-body perturbation theory. Quantum Monte Carlo simulations of symmetric nuclear matter and pure neutron matter are used to determine the density regimes in which perturbation theory with chiral nuclear forces is valid. Within the theoretical uncertainties associated with the many-body methods, we find that select mean-field models describe well microscopic nuclear thermodynamics. As an additional consistency requirement, we study as well the single-particle properties of nucleons in a hot/dense environment, which affect e.g., charged-current weak reactions in neutron-rich matter. The identified mean-field models can be used across a larger range of densities and temperatures in astrophysical simulations than more computationally expensive microscopic models.

  9. Off-equilibrium photon production during the chiral phase transition

    SciTech Connect

    Michler, Frank; Hees, Hendrik van; Dietrich, Dennis D.; Leupold, Stefan; Greiner, Carsten

    2013-09-15

    In the early stage of ultrarelativistic heavy-ion collisions chiral symmetry is restored temporarily. During this so-called chiral phase transition, the quark masses change from their constituent to their bare values. This mass shift leads to the spontaneous non-perturbative creation of quark–antiquark pairs, which effectively contributes to the formation of the quark–gluon plasma. We investigate the photon production induced by this creation process. We provide an approach that eliminates possible unphysical contributions from the vacuum polarization and renders the resulting photon spectra integrable in the ultraviolet domain. The off-equilibrium photon numbers are of quadratic order in the perturbative coupling constants while a thermal production is only of quartic order. Quantitatively, we find, however, that for the most physical mass-shift scenarios and for photon momenta larger than 1 GeV the off-equilibrium processes contribute less photons than the thermal processes. -- Highlights: •We investigate first-order photon emission arising from the chiral mass shift. •We provide an ansatz eliminating possible unphysical vacuum contributions. •Our ansatz leads to photon spectra being integrable in the ultraviolet domain.

  10. Chiral current generation in QED by longitudinal photons

    NASA Astrophysics Data System (ADS)

    Acosta Avalo, J. L.; Pérez Rojas, H.

    2016-08-01

    We report the generation of a pseudovector electric current having imbalanced chirality in an electron-positron strongly magnetized gas in QED. It propagates along the external applied magnetic field B as a chiral magnetic effect in QED. It is triggered by a perturbative electric field parallel to B, associated to a pseudovector longitudinal mode propagating along B. An electromagnetic chemical potential was introduced, but our results remain valid even when it vanishes. A nonzero fermion mass was assumed, which is usually considered vanishing in the literature. In the quantum field theory formalism at finite temperature and density, an anomaly relation for the axial current was found for a medium of massive fermions. It bears some analogy to the Adler-Bell-Jackiw anomaly. From the expression for the chiral current in terms of the photon self-energy tensor in a medium, it is obtained that electrons and positrons scattered by longitudinal photons (inside the light cone) contribute to the chiral current, as well as the to pair creation due to longitudinal photons (out of light cone). In the static limit, an electric pseudovector current is obtained in the lowest Landau level.

  11. Automated Lattice Perturbation Theory

    SciTech Connect

    Monahan, Christopher

    2014-11-01

    I review recent developments in automated lattice perturbation theory. Starting with an overview of lattice perturbation theory, I focus on the three automation packages currently "on the market": HiPPy/HPsrc, Pastor and PhySyCAl. I highlight some recent applications of these methods, particularly in B physics. In the final section I briefly discuss the related, but distinct, approach of numerical stochastic perturbation theory.

  12. Perturbative tests of non-perturbative counting

    NASA Astrophysics Data System (ADS)

    Dabholkar, Atish; Gomes, João

    2010-03-01

    We observe that a class of quarter-BPS dyons in mathcal{N} = 4 theories with charge vector ( Q, P) and with nontrivial values of the arithmetic duality invariant I := gcd( Q∧ P) are nonperturbative in one frame but perturbative in another frame. This observation suggests a test of the recently computed nonperturbative partition functions for dyons with nontrivial values of the arithmetic invariant. For all values of I, we show that the nonperturbative counting yields vanishing indexed degeneracy for this class of states everywhere in the moduli space in precise agreement with the perturbative result.

  13. Chiral quantum dot based materials

    NASA Astrophysics Data System (ADS)

    Govan, Joseph; Loudon, Alexander; Baranov, Alexander V.; Fedorov, Anatoly V.; Gun'ko, Yurii

    2014-05-01

    Recently, the use of stereospecific chiral stabilising molecules has also opened another avenue of interest in the area of quantum dot (QD) research. The main goal of our research is to develop new types of technologically important quantum dot materials containing chiral defects, study their properties and explore their applications. The utilisation of chiral penicillamine stabilisers allowed the preparation of new water soluble white emitting CdS quantum nanostructures which demonstrated circular dichroism in the band-edge region of the spectrum. It was also demonstrated that all three types of QDs (D-, L-, and Rac penicillamine stabilised) show very broad emission bands between 400 and 700 nm due to defects or trap states on the surfaces of the nanocrystals. In this work the chiral CdS based quantum nanostructures have also been doped by copper metal ions and new chiral penicilamine stabilized CuS nanoparticles have been prepared and investigated. It was found that copper doping had a strong effect at low levels in the synthesis of chiral CdS nanostructures. We expect that this research will open new horizons in the chemistry of chiral nanomaterials and their application in biotechnology, sensing and asymmetric synthesis.

  14. Chiral Bosonic Phases on the Haldane Honeycomb Lattice

    NASA Astrophysics Data System (ADS)

    Vasic, Ivana; Petrescu, Alexandru; Le Hur, Karyn; Hofstetter, Walter; Collaboration Collaboration

    2015-03-01

    Motivated by its recent realization in an ultracold atom experiment, we investigate the honeycomb lattice tight-binding model introduced by Haldane, for bosons with local interactions at the average filling of one boson per site. We uncover in the ground state phase diagram three phases: a uniform superfluid (SF), a chiral superfluid (CSF) and a plaquette Mott insulator with local current loops (PMI). Nearest-neighbor and next-nearest neighbor currents distinguish CSF from SF, and the phase transition between them is first order. We apply bosonic dynamical mean field theory and exact diagonalization to obtain the zero temperature phase diagram, complementing numerics with calculations of excitation spectra in strong and weak coupling perturbation theory. Furthermore, we explore the possibility of chiral Mott insulating phases at the average filling of one boson every two sites. The characteristic density fluctuations, current correlation functions, and excitation spectra are measurable in ultracold atom experiments.

  15. Frame independent cosmological perturbations

    SciTech Connect

    Prokopec, Tomislav; Weenink, Jan E-mail: j.g.weenink@uu.nl

    2013-09-01

    We compute the third order gauge invariant action for scalar-graviton interactions in the Jordan frame. We demonstrate that the gauge invariant action for scalar and tensor perturbations on one physical hypersurface only differs from that on another physical hypersurface via terms proportional to the equation of motion and boundary terms, such that the evolution of non-Gaussianity may be called unique. Moreover, we demonstrate that the gauge invariant curvature perturbation and graviton on uniform field hypersurfaces in the Jordan frame are equal to their counterparts in the Einstein frame. These frame independent perturbations are therefore particularly useful in relating results in different frames at the perturbative level. On the other hand, the field perturbation and graviton on uniform curvature hypersurfaces in the Jordan and Einstein frame are non-linearly related, as are their corresponding actions and n-point functions.

  16. Instantons and chiral symmetry in string theory

    NASA Astrophysics Data System (ADS)

    Jensen, Steuard B.

    The study of non-perturbative effects has played an important role in many recent developments in physics. String theory has proven to be an especially fertile ground for such studies: not only is its own non-perturbative structure interesting, but it has emerged as a framework in which to study the strongly coupled behavior of a variety of models in quantum field theory as well. In this thesis, I present results demonstrating the use of string theory in both these ways. First, I discuss non-perturbative corrections to the Kaluza-Klein monopole in string theory. As usually described, this object has an isometry around a compact circle and is related by T-duality to a "smeared" NS5-brane which retains that isometry. The true NS5-brane solution is localized at a point on the circle, so duality implies that the Kaluza-Klein monopole should show some corresponding behavior. By expressing the Kaluza-Klein monopole as a gauged linear sigma model in two dimensions, I show that worldsheet instantons give corrections to its geometry. These corrections can be understood as a localization in "winding space" which could be probed by strings with winding charge around the circle. Second, I discuss a configuration of D-branes in string theory whose low energy physics corresponds to a 3+1-dimensional quantum field theory with dynamically broken chiral symmetry. In a weakly coupled region of parameter space, this theory is a non-local generalization of the Nambu-Jona-Lasinio model. Indications are given that this model dynamically breaks chiral symmetry at arbitrarily weak 't Hooft coupling. At strong coupling this field theory is no longer solvable directly, but an alternate weakly coupled description can be found from the string theory model: the dynamics is determined by replacing a stack of D-branes by their near-horizon geometry and studying the low energy theory on probe D-branes in that background. In yet another region of parameter space, this D-brane configuration gives

  17. Chiral analysis by capillary electrophoresis using antibiotics as chiral selector.

    PubMed

    Desiderio, C; Fanali, S

    1998-05-20

    The separation of chiral compounds by capillary electrophoresis (CE) is a very interesting field of research in different areas such as pharmaceutical, environmental, agricultural analysis etc. The separation of two enantiomers can be achieved in CE using a chiral environment interacting with the two analytes on forming diastereoisomers with different stability constants and thus different mobilities. A wide number of chiral selectors have been employed in CE and among them glycopeptide antibiotics exhibited excellent enantioselective properties towards a wide number of racemic compounds. Vancomycin, ristocetin A, rifamycins, teicoplanin, kanamycin, streptomycin, fradiomycin, and two vancomycin analogues, added to the background electrolyte (BGE), are the antibiotics studied by CE running the separation in untreated and/or coated fused-silica capillary. Due to adsorption and absorption phenomena, some drawbacks can be expected when using bare fused-silica capillary, e.g., changes of electroosmotic flow (EOF), broaden peaks, reduced efficiency and low sensitivity. Coated capillary and counter current mode can be the solution to overcome the above mentioned problems. This review surveys the separation of enantiomers by CE when macrocyclic antibiotics are used as chiral selector. The enantioselectivity can be easily controlled modifying several parameters such as antibiotic type and concentration, pH, ionic strength and concentration of the background electrolyte, organic modifier etc. The paper also presents a list of the latest chiral separations achieved by CE where antibiotics were used as chiral selector.

  18. Chirality in photonic systems

    NASA Astrophysics Data System (ADS)

    Solnyshkov, Dmitry; Malpuech, Guillaume

    2016-10-01

    The optical modes of photonic structures are the so-called TE and TM modes that bring intrinsic spin-orbit coupling and chirality to these systems. This, combined with the unique flexibility of design of the photonic potential, and the possibility to mix photon states with excitonic resonances, sensitive to magnetic field and interactions, allows us to achieve many phenomena, often analogous to other solid-state systems. In this contribution, we review in a qualitative and comprehensive way several of these realizations, namely the optical spin Hall effect, the creation of spin currents protected by a non-trivial geometry, the Berry curvature for photons, and the photonic/polaritonic topological insulator.

  19. Amino Acids and Chirality

    NASA Technical Reports Server (NTRS)

    Cook, Jamie E.

    2012-01-01

    Amino acids are among the most heavily studied organic compound class in carbonaceous chondrites. The abundance, distributions, enantiomeric compositions, and stable isotopic ratios of amino acids have been determined in carbonaceous chondrites fi'om a range of classes and petrographic types, with interesting correlations observed between these properties and the class and typc of the chondritcs. In particular, isomeric distributions appear to correlate with parent bodies (chondrite class). In addition, certain chiral amino acids are found in enantiomeric excess in some chondrites. The delivery of these enantiomeric excesses to the early Earth may have contributed to the origin of the homochirality that is central to life on Earth today. This talk will explore the amino acids in carbonaceous chondritcs and their relevance to the origin of life.

  20. Chiral Bosonization of Superconformal Ghosts

    NASA Technical Reports Server (NTRS)

    Shi, Deheng; Shen, Yang; Liu, Jinling; Xiong, Yongjian

    1996-01-01

    We explain the difference of the Hilbert space of the superconformal ghosts (beta,gamma) system from that of its bosonized fields phi and chi. We calculate the chiral correlation functions of phi, chi fields by inserting appropriate projectors.

  1. Life's chirality from prebiotic environments

    NASA Astrophysics Data System (ADS)

    Gleiser, Marcelo; Walker, Sara Imari

    2012-10-01

    A key open question in the study of life is the origin of biomolecular homochirality: almost every life-form on Earth has exclusively levorotary amino acids and dextrorotary sugars. Will the same handedness be preferred if life is found elsewhere? We review some of the pertinent literature and discuss recent results suggesting that life's homochirality resulted from sequential chiral symmetry breaking triggered by environmental events. In one scenario, autocatalytic prebiotic reactions undergo stochastic fluctuations due to environmental disturbances, in a mechanism reminiscent of evolutionary punctuated equilibrium: short-lived destructive events may lead to long-term enantiomeric excess. In another, chiral-selective polymerization reaction rates influenced by environmental effects lead to substantial chiral excess even in the absence of autocatalysis. Applying these arguments to other potentially life-bearing platforms has implications to the search for extraterrestrial life: we predict that a statistically representative sampling of extraterrestrial stereochemistry will be racemic (chirally neutral) on average.

  2. Rotation of the chiral bag

    NASA Astrophysics Data System (ADS)

    Kahana, David E.; Jackson, A. D.; Ripka, G.

    1986-11-01

    Cranking of the chiral bag model is carried out in order to generate the correct quantum numbers for SU(2) baryons. The moment of inertia of the system is found to be divided between the meson and quark sectors. A numerical evaluation of the contributions to the moment of inertia from valence quarks and from mesons is presented. Finally, a discussion is given of the nucleon-delta mass splitting predicted in the chiral bag model.

  3. The Perturbed Puma Model

    NASA Astrophysics Data System (ADS)

    Rong, Shu-Jun; Liu, Qiu-Yu

    2012-04-01

    The puma model on the basis of the Lorentz and CPT violation may bring an economical interpretation to the conventional neutrinos oscillation and part of the anomalous oscillations. We study the effect of the perturbation to the puma model. In the case of the first-order perturbation which keeps the (23) interchange symmetry, the mixing matrix element Ue3 is always zero. The nonzero mixing matrix element Ue3 is obtained in the second-order perturbation that breaks the (23) interchange symmetry.

  4. Optical properties of chiral nanostructures

    NASA Astrophysics Data System (ADS)

    Cecilia, Noguez; Román-Velázquez, Carlos E.; Garzón, Ignacio L.

    2004-03-01

    We present a computational model to study the optical properties chiral nanostructures[1] . In this work the nanostructures of interest are composed by N atoms, where each one is represented by a polarizable point dipole located at theposition of the atom. We assume that the dipole located is characterized by a polarizability. The nanostructure is excited by a circularly polarized incident wave, such that, each dipole is subject to a total electric field due to: (i) the incident radiation field, plus (ii) the radiation field resulting from all of the other induced dipoles. Once we solve the complex-linear equations, the dipole moment on each atom in the cluster can be determined and we can find the extinction cross section of the whole nanoparticle. Circular dichroism (CD) spectra of chiral bare and thiol-passivated gold nanoclusters have been calculated within the dipole approximation. The calculated CD spectra show features that allow us to distinguish between clusters with different indexes of chirality. The main factor responsible of the differences in the CD lineshapes is the distribution of interatomic distances that characterize the chiral cluster geometry. These results provide theoretical support for the quantification of chirality and its measurement, using the CD lineshapes of chiral metal nanoclusters. [1] C. E. Roman-Velazquez, et al., J. of Phys. Chem. B (Letter) 107, 12035 (2003) This work has been partly supported by DGAPA-UNAM grants No. IN104201 and IN104402, and by CONACyT grant 36651-E.

  5. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

    PubMed Central

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-01-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application. PMID:27401541

  6. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

    NASA Astrophysics Data System (ADS)

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-07-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application.

  7. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation.

    PubMed

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-07-12

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application.

  8. Correlation between structures of chiral polymers and their efficiency for chiral resolution by crystallization.

    PubMed

    Menahem, Tali; Pravda, Martin; Mastai, Yitzhak

    2009-10-01

    In this work, we describe the correlation between chiral polymer structures, particularly alpha-helical and random coil conformations, and their efficiency as chiral resolving agents in crystallization processes. A set of chiral block copolymers based on polyethylene oxide with chiral glutamic acid oligopeptide segments (PEG(113)-b-(+)-(S)-Glu(20)) were synthesized and employed as additives in the crystallization of rac-threonine. CD spectroscopy demonstrates that structures of chiral polymers could be switched between a helical and a disordered random coil by pH. The effect of these polymers at different conformations on the crystallization kinetics, crystal morphology, and chiral resolution of rac-threonine is reported. Our study demonstrates that only chiral polymers with alpha-helical conformations of the chiral segment are effective as additives for chiral resolution throughout crystallization. Overall, our results provide useful guidelines for the selection and design of chiral polymer additives that will act efficiently for chiral resolution by crystallization. PMID:19455618

  9. Ward identities and chiral anomalies for coupled fermionic chains

    SciTech Connect

    Costa, L. C.; Ferraz, A.; Mastropietro, Vieri

    2013-12-15

    Coupled fermionic chains are usually described by an effective model written in terms of bonding and anti-bonding fermionic fields with linear dispersion in the vicinities of the respective Fermi points. We derive for the first time exact Ward Identities (WI) for this model, proving the existence of chiral anomalies which verify the Adler-Bardeen non-renormalization property. Such WI are expected to play a crucial role in the understanding of the thermodynamic properties of the system. Our results are non-perturbative and are obtained analyzing Grassmann functional integrals by means of constructive quantum field theory methods.

  10. Peripheral NN scattering from subtractive renormalization of chiral interactions

    SciTech Connect

    Batista, E. F.; Szpigel, S.; Timóteo, V. S.

    2014-11-11

    We apply five subtractions in the Lippman-Schwinger (LS) equation in order to perform a non-perturbative renormalization of chiral N3LO nucleon-nucleon interactions. Here we compute the phase shifts for the uncoupled peripheral waves at renormalization scales between 0.1 fm{sup −1} and 1 fm{sup −1}. In this range, the results are scale invariant and provide an overall good agreement with the Nijmegen partial wave analysis up to at least E{sub lab} = 150 MeV, with a cutoff at Λ = 30 fm{sup −1}.

  11. Exploring the chiral regime of QCD in the interacting instanton liquid model

    SciTech Connect

    Cristoforetti, M.; Faccioli, P.; Traini, M. C.; Negele, J. W.

    2007-02-01

    The interacting instanton liquid model (IILM) is used to explore the role of instanton-induced dynamics in hadron structure. To support the validity of this model in the chiral regime, the quark mass dependencies of several properties are shown to agree with chiral perturbation theory, including the density of eigenmodes of the Dirac operator and the mass of the pion. A quark mass m*=80 MeV emerging naturally from the model is shown to specify the mass scale above which the fermion determinant is suppressed, the zero modes become subdominant, and the density of quasizero modes become independent of the quark mass.

  12. Nucleon sigma term and strange quark content from lattice QCD with exact chiral symmetry

    SciTech Connect

    Ohki, H.; Fukaya, H.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Matsufuru, H.; Noaki, J.; Shintani, E.; Onogi, T.

    2008-09-01

    We calculate the nucleon sigma term in two-flavor lattice QCD utilizing the Feynman-Hellman theorem. Both sea and valence quarks are described by the overlap fermion formulation, which preserves exact chiral and flavor symmetries on the lattice. We analyze the lattice data for the nucleon mass using the analytical formulae derived from the baryon chiral perturbation theory. From the data at valence quark mass set different from sea quark mass, we may extract the sea quark contribution to the sigma term, which corresponds to the strange quark content. We find that the strange quark content is much smaller than the previous lattice calculations and phenomenological estimates.

  13. Neutron matter with Quantum Monte Carlo: chiral 3N forces and static response

    DOE PAGESBeta

    Buraczynski, M.; Gandolfi, S.; Gezerlis, A.; Schwenk, A.; Tews, I.

    2016-03-01

    Neutron matter is related to the physics of neutron stars and that of neutron-rich nuclei. Moreover, Quantum Monte Carlo (QMC) methods offer a unique way of solving the many-body problem non-perturbatively, providing feedback on features of nuclear interactions and addressing scenarios that are inaccessible to other approaches. Our contribution goes over two recent accomplishments in the theory of neutron matter: a) the fusing of QMC with chiral effective field theory interactions, focusing on local chiral 3N forces, and b) the first attempt to find an ab initio solution to the problem of static response.

  14. On Yang--Mills Theories with Chiral Matter at Strong Coupling

    SciTech Connect

    Shifman, M.; Unsal, Mithat; /SLAC /Stanford U., Phys. Dept.

    2008-08-20

    Strong coupling dynamics of Yang-Mills theories with chiral fermion content remained largely elusive despite much effort over the years. In this work, we propose a dynamical framework in which we can address non-perturbative properties of chiral, non-supersymmetric gauge theories, in particular, chiral quiver theories on S{sub 1} x R{sub 3}. Double-trace deformations are used to stabilize the center-symmetric vacuum. This allows one to smoothly connect smaller(S{sub 1}) to larger(S{sub 1}) physics (R{sub 4} is the limiting case) where the double-trace deformations are switched off. In particular, occurrence of the mass gap in the gauge sector and linear confinement due to bions are analytically demonstrated. We find the pattern of the chiral symmetry realization which depends on the structure of the ring operators, a novel class of topological excitations. The deformed chiral theory, unlike the undeformed one, satisfies volume independence down to arbitrarily small volumes (a working Eguchi-Kawai reduction) in the large N limit. This equivalence, may open new perspectives on strong coupling chiral gauge theories on R{sub 4}.

  15. Can a Non-Chiral Object Be Made of Two Identical Chiral Moieties?

    ERIC Educational Resources Information Center

    LeMarechal, Jean Francois

    2008-01-01

    Several pedagogical objects can be used to discuss chirality. Here, we use the cut of an apple to show that the association of identical chiral moieties can form a non-chiral object. Octahedral chirality is used to find situations equivalent to the cut of the apple. (Contains 5 figures.)

  16. Strange Disoriented Chiral Condensates

    NASA Astrophysics Data System (ADS)

    Abdel-Aziz, Mohamed; Gavin, Sean

    2002-10-01

    Enhancement of omega and anti-omega baryon production in Pb+Pb collisions at the CERN SPS can be explained by the formation of many small regions of disordered chiral condensate. This explanation implies that neutral and charged kaons as well as pions must exhibit novel isospin fluctuations. Fluctuations due to transient behavior of the Polyakov Loop condensate can produce similar phenomena. Kapusta and Gavin have computed the distribution of the fraction of neutral pions and kaons from such regions. We proposed robust statistical observables that can be used to extract the novel isospin fluctuations from background contributions in neutral/charged pion and K-short/K-charged correlation measurements at RHIC and LHC. The STAR experiment is currently examining K-short/K-charged correlations. Note that Pruneau, Voloshin and Gavin have proposed similar observables to study net-charge fluctuations. To obtain a baseline for comparison to RHIC and SPS experiments, Abdel-Aziz and Gavin compute these observables using numerical simulations using HIJING and URQMD event generators. We also obtain limits on the size and number of disordered regions by comparing to photon and charged-pion searches from WA98 and other SPS experiments. We will compare to the first results from STAR K-short/K-charged analysis.

  17. Phase diagram of chirally imbalanced QCD matter

    SciTech Connect

    Chernodub, M. N.; Nedelin, A. S.

    2011-05-15

    We compute the QCD phase diagram in the plane of the chiral chemical potential and temperature using the linear sigma model coupled to quarks and to the Polyakov loop. The chiral chemical potential accounts for effects of imbalanced chirality due to QCD sphaleron transitions which may emerge in heavy-ion collisions. We found three effects caused by the chiral chemical potential: the imbalanced chirality (i) tightens the link between deconfinement and chiral phase transitions; (ii) lowers the common critical temperature; (iii) strengthens the order of the phase transition by converting the crossover into the strong first order phase transition passing via the second order end point. Since the fermionic determinant with the chiral chemical potential has no sign problem, the chirally imbalanced QCD matter can be studied in numerical lattice simulations.

  18. Chiral Chlordane Components in Environmental Matrices

    EPA Science Inventory

    Chlordane, a persistent, bioaccumulative and toxic organochlorine pesticide, has been studied for many years. Since the advent of chiral analysis for environmental samples, over 2,400 measurements have been made of various chiral chlordane components. Chlordane enantiomer fractio...

  19. Tactoids of chiral liquid crystals

    NASA Astrophysics Data System (ADS)

    Palacio-Betancur, Viviana; Villada-Gil, Stiven; Zhou, Ye; Armas-Pérez, Julio C.; de Pablo, Juan José; Hernández-Ortiz, Juan Pablo

    The phase diagram of chiral liquid crystals confined in ellipsoids is obtained, by following a theoretically informed Monte Carlo relaxation of the tensor alignment field Q. The free energy of the system is described by a functional in the framework of the Landau-de Gennes formalism. This study also includes the effect of anchoring strength, curvature, and chirality of the system. In the low chirality region of the phase diagram we found the twist bipolar (BS) phase and some cholesteric phases such as the radial spherical structure (RSS), twist cylinder (TC) and double twist cylinder (DTC) whose axis of rotation is not necessarily aligned with the major axis of the geometry. For high chirality scenarios, the disclination lines are twisted or bent near the surface preventing the formation of symmetric networks of defects, although an hexagonal pattern is formed on the surface which might serve as open sites for collocation of colloids. By analyzing the free energies of isochoric systems, prolate geometries tend to be more favorable for high chirality and low anchoring conditions. Universidad Nacional de Colombia Ph.D. grant and COLCIENCIAS under the Contract No. 110-165-843-748. CONACYT for Postdoctoral Fellowships Nos. 186166 and 203840.

  20. Controlling Chirality of Entropic Crystals

    NASA Astrophysics Data System (ADS)

    Damasceno, Pablo; Karas, Andrew; Schultz, Benjamin; Engel, Michael; Glotzer, Sharon

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. Work supported by the National Science Foundation, Division of Materials Research Award No. DMR 1120923, U.S. Army Research Office under Grant Award No. W911NF-10-1-0518, and also by the DOD/ASD (R&E) under Award No. N00244-09-1-0062.

  1. Chiral Thirring–Wess model

    SciTech Connect

    Rahaman, Anisur

    2015-10-15

    The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson.

  2. Chirality: a relational geometric-physical property.

    PubMed

    Gerlach, Hans

    2013-11-01

    The definition of the term chirality by Lord Kelvin in 1893 and 1904 is analyzed by taking crystallography at that time into account. This shows clearly that chirality is a relational geometric-physical property, i.e., two relations between isometric objects are possible: homochiral or heterochiral. In scientific articles the relational term chirality is often mistaken for the two valued measure for the individual (absolute) sense of chirality, an arbitrary attributive term.

  3. Power counting regime of chiral effective field theory and beyond.

    SciTech Connect

    Hall, J. M.M.; Leinweber, D. B.; Young, R. D.; Physics; Univ. of Adelaide

    2010-08-10

    Chiral effective field theory ({chi}EFT) complements numerical simulations of quantum chromodynamics (QCD) on a space-time lattice. It provides a model-independent formalism for connecting lattice simulation results at finite volume and a variety of quark masses to the physical world. The asymptotic nature of the chiral expansion places the focus on the first few terms of the expansion. Thus, knowledge of the power-counting regime (PCR) of {chi}EFT, where higher-order terms of the expansion may be regarded as negligible, is as important as knowledge of the expansion itself. Through the consideration of a variety of renormalization schemes and associated parameters, techniques to identify the PCR where results are independent of the renormalization scheme are established. The nucleon mass is considered as a benchmark for illustrating this general approach. Because the PCR is small, the numerical simulation results are also examined to search for the possible presence of an intrinsic scale which may be used in a nonperturbative manner to describe lattice simulation results outside of the PCR. Positive results that improve on the current optimistic application of chiral perturbation theory ({chi}PT) beyond the PCR are reported.

  4. Power counting regime of chiral effective field theory and beyond

    SciTech Connect

    Hall, J. M. M.; Leinweber, D. B.; Young, R. D.

    2010-08-01

    Chiral effective field theory ({chi}EFT) complements numerical simulations of quantum chromodynamics (QCD) on a space-time lattice. It provides a model-independent formalism for connecting lattice simulation results at finite volume and a variety of quark masses to the physical world. The asymptotic nature of the chiral expansion places the focus on the first few terms of the expansion. Thus, knowledge of the power-counting regime (PCR) of {chi}EFT, where higher-order terms of the expansion may be regarded as negligible, is as important as knowledge of the expansion itself. Through the consideration of a variety of renormalization schemes and associated parameters, techniques to identify the PCR where results are independent of the renormalization scheme are established. The nucleon mass is considered as a benchmark for illustrating this general approach. Because the PCR is small, the numerical simulation results are also examined to search for the possible presence of an intrinsic scale which may be used in a nonperturbative manner to describe lattice simulation results outside of the PCR. Positive results that improve on the current optimistic application of chiral perturbation theory ({chi}PT) beyond the PCR are reported.

  5. Chiral lattice fermions with correct vacuum polarization and chiral anomaly

    SciTech Connect

    Pryor, C. )

    1991-04-15

    An action for chiral lattice fermions is proposed, which avoids the Nielsen-Ninomiya theorem by virtue of its nonlocality and nonbilinearity. The action is constructed by eliminating the extra fermion modes with a gauge-violating Majorana-type Wilson mass, which is then rendered invariant by an integration over gauge transformations. The free propagator is calculated, and the one-loop vacuum polarization is shown to be identical to that for Wilson fermions, even at nonzero lattice spacing. Also the chiral anomaly is shown to be the same as for Wilson fermions in the continuum limit.

  6. Field induced spin chirality and chirality switching in magnetic multilayers

    NASA Astrophysics Data System (ADS)

    Tartakovskaya, Elena V.

    2015-05-01

    The physical origin of the field-induced spin chirality experimentally observed in rare earth multilayers is determined. It is shown that the effect is possible due to the interplay between solid-state exchange interactions (the Ruderman-Kittel-Kasuya-Yosida and the Dsyaloshinsky-Moriya interactions), the external magnetic field and a special confinement of magnetic constituents. The presented model describes a certain temperature dependence of the chirality factor in agreement with experimental data and opens a new way to design nanostructured objects with predicted handedness.

  7. Perturbations for transient acceleration

    SciTech Connect

    Vargas, Cristofher Zuñiga; Zimdahl, Winfried; Hipólito-Ricaldi, Wiliam S. E-mail: hipolito@ceunes.ufes.br

    2012-04-01

    According to the standard ΛCDM model, the accelerated expansion of the Universe will go on forever. Motivated by recent observational results, we explore the possibility of a finite phase of acceleration which asymptotically approaches another period of decelerated expansion. Extending an earlier study on a corresponding homogeneous and isotropic dynamics, in which interactions between dark matter and dark energy are crucial, the present paper also investigates the dynamics of the matter perturbations both on the Newtonian and General Relativistic (GR) levels and quantifies the potential relevance of perturbations of the dark-energy component. In the background, the model is tested against the Supernova type Ia (SNIa) data of the Constitution set and on the perturbative level against growth rate data, among them those of the WiggleZ survey, and the data of the 2dFGRS project. Our results indicate that a transient phase of accelerated expansion is not excluded by current observations.

  8. Vortex perturbation dynamics

    NASA Technical Reports Server (NTRS)

    Criminale, W. O.; Lasseigne, D. G.; Jackson, T. L.

    1995-01-01

    An initial value approach is used to examine the dynamics of perturbations introduced into a vortex under strain. Both the basic vortex considered and the perturbations are taken as fully three-dimensional. An explicit solution for the time evolution of the vorticity perturbations is given for arbitrary initial vorticity. Analytical solutions for the resulting velocity components are found when the initial vorticity is assumed to be localized. For more general initial vorticity distributions, the velocity components are determined numerically. It is found that the variation in the radial direction of the initial vorticity disturbance is the most important factor influencing the qualitative behavior of the solutions. Transient growth in the magnitude of the velocity components is found to be directly attributable to the compactness of the initial vorticity.

  9. Chiral cardiovascular drugs: an overview.

    PubMed

    Ranade, Vasant V; Somberg, John C

    2005-01-01

    Stereochemistry in drug molecules is rapidly becoming an important aspect in drug research, design, and development. Recently, individual stereoisomers of drug molecules with asymmetric centers such as fexofenadine, cetirizine, verapamil, fluoxetine, levalbutarol, and amphetamine, for example, have been separated and developed as individual drugs. These stereoisomers have different therapeutic activity, and each isomer has contributed differently with respect to its formulation's pharmacologic activity, side effects, and toxicity. The present overview discusses chirality among a select group of cardiovascular drugs, their stereochemical synthesis/preparation, isolation techniques using chiral chromatography, methods for confirmation of their enantiomeric purity, pharmacodynamics, and pharmacokinetics. Chirality has been visualized as an important factor in cardiovascular research. It is also becoming evident in other areas of therapeutics.

  10. Chirality and gravitational parity violation.

    PubMed

    Bargueño, Pedro

    2015-06-01

    In this review, parity-violating gravitational potentials are presented as possible sources of both true and false chirality. In particular, whereas phenomenological long-range spin-dependent gravitational potentials contain both truly and falsely chiral terms, it is shown that there are models that extend general relativity including also coupling of fermionic degrees of freedom to gravity in the presence of torsion, which give place to short-range truly chiral interactions similar to that usually considered in molecular physics. Physical mechanisms which give place to gravitational parity violation together with the expected size of the effects and their experimental constraints are discussed. Finally, the possible role of parity-violating gravity in the origin of homochirality and a road map for future research works in quantum chemistry is presented. PMID:25919812

  11. Chirality and gravitational parity violation.

    PubMed

    Bargueño, Pedro

    2015-06-01

    In this review, parity-violating gravitational potentials are presented as possible sources of both true and false chirality. In particular, whereas phenomenological long-range spin-dependent gravitational potentials contain both truly and falsely chiral terms, it is shown that there are models that extend general relativity including also coupling of fermionic degrees of freedom to gravity in the presence of torsion, which give place to short-range truly chiral interactions similar to that usually considered in molecular physics. Physical mechanisms which give place to gravitational parity violation together with the expected size of the effects and their experimental constraints are discussed. Finally, the possible role of parity-violating gravity in the origin of homochirality and a road map for future research works in quantum chemistry is presented.

  12. Determination of the Chiral Condensate from (2+1)-Flavor Lattice QCD

    SciTech Connect

    Fukaya, H.; Aoki, S.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Noaki, J.; Onogi, T.

    2010-03-26

    We perform a precise calculation of the chiral condensate in QCD using lattice QCD with 2+1 flavors of dynamical overlap quarks. Up and down quark masses cover a range between 3 and 100 MeV on a 16{sup 3}x48 lattice at a lattice spacing {approx}0.11 fm. At the lightest sea quark mass, the finite volume system on the lattice is in the {epsilon} regime. By matching the low-lying eigenvalue spectrum of the Dirac operator with the prediction of chiral perturbation theory at the next-to-leading order, we determine the chiral condensate in (2+1)-flavor QCD with strange quark mass fixed at its physical value as {Sigma}{sup MS}(2 GeV)=[242(04)((+19/-18)) MeV]{sup 3} where the errors are statistical and systematic, respectively.

  13. On the renormalization of the electroweak chiral Lagrangian with a Higgs

    NASA Astrophysics Data System (ADS)

    Gavela, M. B.; Kanshin, K.; Machado, P. A. N.; Saa, S.

    2015-03-01

    We consider the scalar sector of the effective non-linear electroweak Lagrangian with a light "Higgs" particle. For a leading order Lagrangian, the complete one-loop off-shell renormalization procedure is performed, including the effects of a finite Higgs mass. This determines the complete set of independent chiral invariant scalar counterterms required for consistency; these include bosonic operators often disregarded. A novel general parametrization of the Goldstone boson matrix is proposed, which reduces to the various usual ones for specific values of its parameter. Furthermore, new counterterms involving the Higgs field which are apparently chiral non-invariant are identified in the perturbative analysis. A redefinition of the Goldstone boson fields which absorbs all chiral non-invariant counterterms is then explicitly determined. The physical results translate into renormalization group equations which may be useful when comparing future Higgs data at different energies.

  14. Collisions in Chiral Kinetic Theory.

    PubMed

    Chen, Jing-Yuan; Son, Dam T; Stephanov, Mikhail A

    2015-07-10

    Using a covariant formalism, we construct a chiral kinetic theory Lorentz invariant to order O(ℏ), which includes collisions. We find a new contribution to the particle number current due to the side jumps required by the conservation of angular momentum during collisions. We also find a conserved symmetric stress-energy tensor as well as the H function obeying Boltzmann's H theorem. We demonstrate their use by finding a general equilibrium solution and the values of the anomalous transport coefficients characterizing the chiral vortical effect.

  15. Chiral symmetry on the lattice

    SciTech Connect

    Creutz, M.

    1994-11-01

    The author reviews some of the difficulties associated with chiral symmetry in the context of a lattice regulator. The author discusses the structure of Wilson Fermions when the hopping parameter is in the vicinity of its critical value. Here one flavor contrasts sharply with the case of more, where a residual chiral symmetry survives anomalies. The author briefly discusses the surface mode approach, the use of mirror Fermions to cancel anomalies, and finally speculates on the problems with lattice versions of the standard model.

  16. Non-perturbative QCD Modeling and Meson Physics

    SciTech Connect

    Nguyen, T.; Souchlas, N. A.; Tandy, P. C.

    2009-04-20

    Using a ladder-rainbow kernel previously established for light quark hadron physics, we explore the extension to masses and electroweak decay constants of ground state pseudoscalar and vector quarkonia and heavy-light mesons in the c- and b-quark regions. We make a systematic study of the effectiveness of a constituent mass concept as a replacement for a heavy quark dressed propagator for such states. The difference between vector and axial vector current correlators is explored within the same model to provide an estimate of the four quark chiral condensate and the leading distance scale for the onset of non-perturbative phenomena in QCD.

  17. Non-perturbative aspects of hadron structure in QCD

    SciTech Connect

    Thomas, Anthony W.

    2012-09-26

    We review recent developments in the understanding of hadron structure in the context of QCD. These developments build on the success of lattice QCD and discoveries in chiral perturbation theory. We focus particularly on tests of QCD through the strangeness content of the nucleon, the investigation of excited states of the nucleon, where lattice QCD, experiment and phenomenology meet. Lastly, we discuss the implications of these developments in hadron structure for our understanding of nuclear structure and the equation of state of dense matter.

  18. Non-perturbative QCD Modeling and Meson Physics

    NASA Astrophysics Data System (ADS)

    Nguyen, T.; Souchlas, N. A.; Tandy, P. C.

    2009-04-01

    Using a ladder-rainbow kernel previously established for light quark hadron physics, we explore the extension to masses and electroweak decay constants of ground state pseudoscalar and vector quarkonia and heavy-light mesons in the c- and b-quark regions. We make a systematic study of the effectiveness of a constituent mass concept as a replacement for a heavy quark dressed propagator for such states. The difference between vector and axial vector current correlators is explored within the same model to provide an estimate of the four quark chiral condensate and the leading distance scale for the onset of non-perturbative phenomena in QCD.

  19. Chiral xenobiotics bioaccumulations and environmental health prospectives.

    PubMed

    Hussain, Iqbal; ALOthman, Zeid A; Alwarthan, Abdulrahman A; Sanagi, Mohd Marsin; Ali, Imran

    2015-08-01

    The chiral xenobiotics are very dangerous for all of us due to the different enantioselective toxicities of the enantiomers. Besides, these have different enantioselective bioaccumulations and behaviors in our body and other organisms. It is of urgent need to understand the enantioselective bioaccumulations, toxicities, and the health hazards of the chiral xenobiotics. The present article describes the classification, sources of contamination, distribution, enantioselective bioaccumulation, and the toxicities of the chiral xenobiotics. Besides, the efforts are also made to discuss the prevention and remedial measures of the havoc of the chiral xenobiotics. The challenges of the chiral xenobiotics have also been highlighted. Finally, future prospectives are also discussed.

  20. Cosmological perturbations in antigravity

    NASA Astrophysics Data System (ADS)

    Oltean, Marius; Brandenberger, Robert

    2014-10-01

    We compute the evolution of cosmological perturbations in a recently proposed Weyl-symmetric theory of two scalar fields with oppositely signed conformal couplings to Einstein gravity. It is motivated from the minimal conformal extension of the standard model, such that one of these scalar fields is the Higgs while the other is a new particle, the dilaton, introduced to make the Higgs mass conformally symmetric. At the background level, the theory admits novel geodesically complete cyclic cosmological solutions characterized by a brief period of repulsive gravity, or "antigravity," during each successive transition from a big crunch to a big bang. For simplicity, we consider scalar perturbations in the absence of anisotropies, with potential set to zero and without any radiation. We show that despite the necessarily wrong-signed kinetic term of the dilaton in the full action, these perturbations are neither ghostlike nor tachyonic in the limit of strongly repulsive gravity. On this basis, we argue—pending a future analysis of vector and tensor perturbations—that, with respect to perturbative stability, the cosmological solutions of this theory are viable.

  1. Scalar cosmological perturbations

    NASA Astrophysics Data System (ADS)

    Uggla, Claes; Wainwright, John

    2012-05-01

    Scalar perturbations of Friedmann-Lemaitre cosmologies can be analyzed in a variety of ways using Einstein’s field equations, the Ricci and Bianchi identities, or the conservation equations for the stress-energy tensor, and possibly introducing a timelike reference congruence. The common ground is the use of gauge invariants derived from the metric tensor, the stress-energy tensor, or from vectors associated with a reference congruence, as basic variables. Although there is a complication in that there is no unique choice of gauge invariants, we will show that this can be used to advantage. With this in mind our first goal is to present an efficient way of constructing dimensionless gauge invariants associated with the tensors that are involved, and of determining their inter-relationships. Our second goal is to give a unified treatment of the various ways of writing the governing equations in dimensionless form using gauge-invariant variables, showing how simplicity can be achieved by a suitable choice of variables and normalization factors. Our third goal is to elucidate the connection between the metric-based approach and the so-called 1 + 3 gauge-invariant approach to cosmological perturbations. We restrict our considerations to linear perturbations, but our intent is to set the stage for the extension to second-order perturbations.

  2. Chirality effect in disordered graphene ribbon junctions

    NASA Astrophysics Data System (ADS)

    Long, Wen

    2012-05-01

    We investigate the influence of edge chirality on the electronic transport in clean or disordered graphene ribbon junctions. By using the tight-binding model and the Landauer-Büttiker formalism, the junction conductance is obtained. In the clean sample, the zero-magnetic-field junction conductance is strongly chirality-dependent in both unipolar and bipolar ribbons, whereas the high-magnetic-field conductance is either chirality-independent in the unipolar or chirality-dependent in the bipolar ribbon. Furthermore, we study the disordered sample in the presence of magnetic field and find that the junction conductance is always chirality-insensitive for both unipolar and bipolar ribbons with adequate disorders. In addition, the disorder-induced conductance plateaus can exist in all chiral bipolar ribbons provided the disorder strength is moderate. These results suggest that we can neglect the effect of edge chirality in fabricating electronic devices based on the magnetotransport in a disordered graphene ribbon.

  3. Micropatterning of cells reveals chiral morphogenesis

    PubMed Central

    2013-01-01

    Invariant left-right (LR) patterning or chirality is critical for embryonic development. The loss or reversal of LR asymmetry is often associated with malformations and disease. Although several theories have been proposed, the exact mechanism of the initiation of the LR symmetry has not yet been fully elucidated. Recently, chirality has been detected within single cells as well as multicellular structures using several in vitro approaches. These studies demonstrated the universality of cell chirality, its dependence on cell phenotype, and the role of physical boundaries. In this review, we discuss the theories for developmental LR asymmetry, compare various in vitro cell chirality model systems, and highlight possible roles of cell chirality in stem cell differentiation. We emphasize that the in vitro cell chirality systems have great promise for helping unveil the nature of chiral morphogenesis in development. PMID:23672821

  4. Liouvillian perturbations of black holes

    NASA Astrophysics Data System (ADS)

    Couch, W. E.; Holder, C. L.

    2007-10-01

    We apply the well-known Kovacic algorithm to find closed form, i.e., Liouvillian solutions, to the differential equations governing perturbations of black holes. Our analysis includes the full gravitational perturbations of Schwarzschild and Kerr, the full gravitational and electromagnetic perturbations of Reissner-Nordstrom, and specialized perturbations of the Kerr-Newman geometry. We also include the extreme geometries. We find all frequencies ω, in terms of black hole parameters and an integer n, which allow Liouvillian perturbations. We display many classes of black hole parameter values and their corresponding Liouvillian perturbations, including new closed-form perturbations of Kerr and Reissner-Nordstrom. We also prove that the only type 1 Liouvillian perturbations of Schwarzschild are the known algebraically special ones and that type 2 Liouvillian solutions do not exist for extreme geometries. In cases where we do not prove the existence or nonexistence of Liouvillian perturbations we obtain sequences of Diophantine equations on which decidability rests.

  5. Basics of Resonance Chiral Theory

    SciTech Connect

    Portoles, J.

    2010-12-28

    We review the main components that have to be considered, within Resonance Chiral Theory, in the study of processes whose dynamics is dominated by hadron resonances. We show its application in the study of the {tau}{yields}{pi}{pi}{pi}{nu}{sub {tau}} decay.

  6. Chiral asymmetry in spiral galaxies?

    PubMed

    Kondepudi, D K; Durand, D J

    2001-07-01

    Spiral galaxies are chiral entities when coupled with the direction of their recession velocity. As viewed from the Earth, the S-shaped and Z-shaped spiral galaxies are two chiral forms. What is the nature of chiral symmetry in spiral galaxies? In the Carnegie Atlas of Galaxies that lists photographs of a total of 1,168 galaxies, we found 540 galaxies, classified as normal or barred spirals, that are clearly identifiable as S- or Z- type. The recession velocities for 538 of these galaxies could be obtained from this atlas and other sources. A statistical analysis of this sample reveals no overall asymmetry but there is a significant asymmetry in certain subclasses: dominance of S-type galaxies in the Sb class of normal spiral galaxies and a dominance of Z-type in the SBb class of barred spiral galaxies. Both S- and Z-type galaxies seem to have similar velocity distribution, indicating no spatial segregation of the two chiral forms.

  7. Baryon and chiral symmetry breaking

    SciTech Connect

    Gorsky, A.; Krikun, A.

    2014-07-23

    We briefly review the generalized Skyrmion model for the baryon recently suggested by us. It takes into account the tower of vector and axial mesons as well as the chiral symmetry breaking. The generalized Skyrmion model provides the qualitative explanation of the Ioffe’s formula for the baryon mass.

  8. Small field inflation in {N} = 1 supergravity with a single chiral superfield

    NASA Astrophysics Data System (ADS)

    Bernardo, Heliudson; Nastase, Horatiu

    2016-09-01

    We consider "new inflation" inflationary models at small fields, embedded in minimal {N} = 1 supergravity with a single chiral superfield. Imposing a period of inflation compatible with experiment severely restricts possible models, classified in perturbation theory. If moreover we impose that the field goes to large values and very small potential at the current time, like would be needed for instance for the inflaton being the volume modulus in large extra dimensional scenarios, the possible models are restricted to very contrived superpotentials.

  9. The Effects of Regulators on NN and 3N forces in Chiral Effective Field Theory

    NASA Astrophysics Data System (ADS)

    Dyhdalo, Alex; Furnstahl, Richard; Hebeler, Kai; Tews, Ingo

    2015-10-01

    For potentials derived using Chiral Effective Field Theory, it is necessary to choose a regulator and cutoff scale for the theory. Under Weinberg's power counting prescription, the perturbatively derived potential is iterated to all orders, leading to artifacts (e.g., residual cutoff dependence) from the regulator. We investigate different choices of regulators and their associated artifacts in the uniform system at finite density for two- and three-body forces. We find significant effects from different regulator choices at Hartree-Fock and 2nd order in the perturbative many-body energy expansion. The potential implications of regulator and scale choice on the theory's power counting is discussed.

  10. Light meson electromagnetic form factors from three-flavor lattice QCD with exact chiral symmetry

    NASA Astrophysics Data System (ADS)

    Aoki, S.; Cossu, G.; Feng, X.; Hashimoto, S.; Kaneko, T.; Noaki, J.; Onogi, T.

    2016-02-01

    We study the chiral behavior of the electromagnetic (EM) form factors of pions and kaons in three-flavor lattice QCD. In order to make a direct comparison of the lattice data with chiral perturbation theory (ChPT), we employ the overlap quark action that has exact chiral symmetry. Gauge ensembles are generated at a lattice spacing of 0.11 fm with four pion masses ranging between Mπ≃290 MeV and 540 MeV and with a strange quark mass ms close to its physical value. We utilize the all-to-all quark propagator technique to calculate the EM form factors with high precision. Their dependence on ms and on the momentum transfer is studied by using the reweighting technique and the twisted boundary conditions for the quark fields, respectively. A detailed comparison with SU(2) and SU(3) ChPT reveals that the next-to-next-to-leading order terms in the chiral expansion are important to describe the chiral behavior of the form factors in the pion mass range studied in this work. We estimate the relevant low-energy constants and the charge radii, and find reasonable agreement with phenomenological and experimental results.

  11. Aspects of perturbative unitarity

    NASA Astrophysics Data System (ADS)

    Anselmi, Damiano

    2016-07-01

    We reconsider perturbative unitarity in quantum field theory and upgrade several arguments and results. The minimum assumptions that lead to the largest time equation, the cutting equations and the unitarity equation are identified. Using this knowledge and a special gauge, we give a new, simpler proof of perturbative unitarity in gauge theories and generalize it to quantum gravity, in four and higher dimensions. The special gauge interpolates between the Feynman gauge and the Coulomb gauge without double poles. When the Coulomb limit is approached, the unphysical particles drop out of the cuts and the cutting equations are consistently projected onto the physical subspace. The proof does not extend to nonlocal quantum field theories of gauge fields and gravity, whose unitarity remains uncertain.

  12. Renormalized Lie perturbation theory

    SciTech Connect

    Rosengaus, E.; Dewar, R.L.

    1981-07-01

    A Lie operator method for constructing action-angle transformations continuously connected to the identity is developed for area preserving mappings. By a simple change of variable from action to angular frequency a perturbation expansion is obtained in which the small denominators have been renormalized. The method is shown to lead to the same series as the Lagrangian perturbation method of Greene and Percival, which converges on KAM surfaces. The method is not superconvergent, but yields simple recursion relations which allow automatic algebraic manipulation techniques to be used to develop the series to high order. It is argued that the operator method can be justified by analytically continuing from the complex angular frequency plane onto the real line. The resulting picture is one where preserved primary KAM surfaces are continuously connected to one another.

  13. Degenerate density perturbation theory

    NASA Astrophysics Data System (ADS)

    Palenik, Mark C.; Dunlap, Brett I.

    2016-09-01

    Fractional occupation numbers can be used in density functional theory to create a symmetric Kohn-Sham potential, resulting in orbitals with degenerate eigenvalues. We develop the corresponding perturbation theory and apply it to a system of Nd degenerate electrons in a harmonic oscillator potential. The order-by-order expansions of both the fractional occupation numbers and unitary transformations within the degenerate subspace are determined by the requirement that a differentiable map exists connecting the initial and perturbed states. Using the X α exchange-correlation (XC) functional, we find an analytic solution for the first-order density and first- through third-order energies as a function of α , with and without a self-interaction correction. The fact that the XC Hessian is not positive definite plays an important role in the behavior of the occupation numbers.

  14. Perturbed Trojan satellites

    NASA Astrophysics Data System (ADS)

    Morais, M. H. M.; Murray, C. D.

    1999-09-01

    We present some mechanisms that can lead to instability of initially small eccentricity Trojan-type orbits associated with planetary satellites. Dermott & Murray (1981) showed that in the context of the hierarchical restricted three-body problem (M>> m), stable small eccentricity coorbital motion associated with the mass m, occurs within a region of relative width in semi-major axis a_s=0.74 epsilon (where epsilon is the dimensionless Hill's radius). However, for large eccentricities, the size of the stable coorbital region shrinks as a_s=4 (epsilon /e)(1/2) epsilon (Namouni 1999). The perturbations from other nearby bodies can cause increases in both eccentricity and semi-major axis, leading to ejection from the coorbital region via collisions with the parent body or a nearby perturber. We show that mean motion resonances among saturnian satellites can cause chaotic diffusion of both the eccentricity and the semi-major axis of their associated Trojan orbits. Moreover, we show that secular resonances inside the coorbital regions of some uranian and saturnian satellites can induce significant increases in the eccentricity of Trojan objects. A better insight into the complicated dynamics exhibited by Trojan objects when they are being subject to perturbations is fundamental to be able to assess the likelihood of finding real examples of these configurations. Dermott & Murray (1981). Icarus 48, 1-11. Namouni (1999). Icarus 137, 293-314.

  15. Covariant Bardeen perturbation formalism

    NASA Astrophysics Data System (ADS)

    Vitenti, S. D. P.; Falciano, F. T.; Pinto-Neto, N.

    2014-05-01

    In a previous work we obtained a set of necessary conditions for the linear approximation in cosmology. Here we discuss the relations of this approach with the so-called covariant perturbations. It is often argued in the literature that one of the main advantages of the covariant approach to describe cosmological perturbations is that the Bardeen formalism is coordinate dependent. In this paper we will reformulate the Bardeen approach in a completely covariant manner. For that, we introduce the notion of pure and mixed tensors, which yields an adequate language to treat both perturbative approaches in a common framework. We then stress that in the referred covariant approach, one necessarily introduces an additional hypersurface choice to the problem. Using our mixed and pure tensors approach, we are able to construct a one-to-one map relating the usual gauge dependence of the Bardeen formalism with the hypersurface dependence inherent to the covariant approach. Finally, through the use of this map, we define full nonlinear tensors that at first order correspond to the three known gauge invariant variables Φ, Ψ and Ξ, which are simultaneously foliation and gauge invariant. We then stress that the use of the proposed mixed tensors allows one to construct simultaneously gauge and hypersurface invariant variables at any order.

  16. REVIEW ARTICLE: Chiral metamaterials: simulations and experiments

    NASA Astrophysics Data System (ADS)

    Wang, Bingnan; Zhou, Jiangfeng; Koschny, Thomas; Kafesaki, Maria; Soukoulis, Costas M.

    2009-11-01

    Electromagnetic metamaterials are composed of periodically arranged artificial structures. They show peculiar properties, such as negative refraction and super-lensing, which are not seen in natural materials. The conventional metamaterials require both negative epsilon and negative μ to achieve negative refraction. Chiral metamaterial is a new class of metamaterials offering a simpler route to negative refraction. In this paper, we briefly review the history of metamaterials and the developments on chiral metamaterials. We study the wave propagation properties in chiral metamaterials and show that negative refraction can be realized in chiral metamaterials with a strong chirality, with neither epsilon nor μ negative required. We have developed a retrieval procedure, adopting a uniaxial bi-isotropic model to calculate the effective parameters such as n ± , κ, epsilon and μ of the chiral metamaterials. Our work on the design, numerical calculations and experimental measurements of chiral metamaterials is introduced. Strong chiral behaviors such as optical activity and circular dichroism are observed and negative refraction is obtained for circularly polarized waves in these chiral metamaterials. We show that 3D isotropic chiral metamaterials can eventually be realized.

  17. Chiral sensing by nonchiral tetrapyrroles.

    PubMed

    Labuta, Jan; Hill, Jonathan P; Ishihara, Shinsuke; Hanyková, Lenka; Ariga, Katsuhiko

    2015-03-17

    Enantiomeric excess (ee) is a measure of the purity of an enantiomer of a chiral compound with respect to the presence of the complementary enantiomer. It is an important aspect of chemistry, especially in the fields of pharmaceuticals and asymmetric catalysis. Existing methods for determination of enantiomeric excesses using nuclear magnetic resonance (NMR) spectroscopy mostly rely on special chiral reagents (auxiliaries) that form two or more diastereomeric complexes with a chiral compound. As a result of this, the NMR spectrum of each enantiomer is different, allowing the determination of enantiomeric excess. In this Account, we describe a molecular design process that has allowed us to prepare prochiral solvating agents for NMR determination of ee of a wide variety of analyte types. At the outset of this work, we initially encountered the phenomenon of NMR peak splitting in the oxoporphyrinogen (OxP) host component of a supramolecular host-guest complex, where the extent of the splitting is apparently proportional to the guests' ee. Upon closer examination of the mechanism of action, it was found that several complicating factors, including prototropic tautomerism, macrocyclic inversion (ring-flipping), and 1:2 host-guest stoichiometry, obstruct potential applications of OxP as a chiral solvating agent. By considering the molecular conformation of the OxP host, a saddle-shaped calix[4]pyrrole, we moved to study the tetraphenylporphyrin (TPP) dication since it has a similar form, and it was found that it could also be used to probe ee. However, although TPP does not suffer from disadvantageous tautomeric processes, it is still subject to macrocyclic inversion and has the additional serious disadvantage of operating for ee sensing only at depressed temperatures. The intrinsic disadvantages of the OxP and TPP systems were finally overcome by covalently modifying the OxP chromophore by regioselective N-alkylation at one face of the molecule. This procedure yields a

  18. Molecular chirality and chiral capsule-type dimer formation of cyclic triamides via hydrogen-bonding interactions.

    PubMed

    Fujimoto, Noriko; Matsumura, Mio; Azumaya, Isao; Nishiyama, Shizuka; Masu, Hyuma; Kagechika, Hiroyuki; Tanatani, Aya

    2012-05-18

    Chiral properties of bowl-shaped cyclic triamides bearing functional groups with hydrogen-bonding ability were examined. Chiral induction of cyclic triamide 3a was observed by addition of chiral amine in solution, and chiral separation was achieved by simple crystallization to afford chiral capsule-type dimer structure of 4a.

  19. Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters

    NASA Astrophysics Data System (ADS)

    Katsuno, Hiroyasu; Uwaha, Makio

    2016-01-01

    By grinding crystals in a solution, the chirality of crystal structure (and the molecular chirality for the case of chiral molecules as well) can be converted, and the cause of the phenomenon is attributed to crystal growth with chiral clusters. We show that the recently found chirality conversion with a periodic change of temperature can also be explained by crystal growth with chiral clusters. With the use of a generalized Becker-Döring model, which includes enantio-selective incorporation of small chiral clusters to large solid clusters, the change of cluster distribution and the mass flow between clusters are studied. The chiral clusters act as a reservoir to pump out the minority species to the majority, and the exponential amplification of the enantiomeric excess found in the experiment is reproduced in the numerical calculation.

  20. Stable Pentaquarks from Strange Chiral Multiplets

    SciTech Connect

    Silas Beane

    2004-12-01

    The assumption of strong diquark correlations in the QCD spectrum suggests flavor multiplets of hadrons that are degenerate in the chiral limit. Generally it would be unnatural for there to be degeneracy in the hadron spectrum that is not protected by a QCD symmetry. Here we show--for pentaquarks constructed from diquarks--that these degeneracies can be naturally protected by the full chiral symmetry of QCD. The resulting chiral multiplet structure recovers the ideally-mixed pentaquark mass spectrum of the diquark model, and interestingly, requires that the axial couplings of the pentaquarks to states outside the degenerate multiplets vanish in the chiral limit. This result suggests that if these hadrons exist, they are stable in the chiral limit and therefore have widths that scale as the fourth power of the kaon mass over the chiral symmetry breaking scale. Natural-size widths are of order a few MeV.

  1. Asymmetric synthesis using chiral-encoded metal.

    PubMed

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-08-26

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity.

  2. Asymmetric synthesis using chiral-encoded metal.

    PubMed

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-01-01

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity. PMID:27562028

  3. Anomalous Maxwell equations for inhomogeneous chiral plasma

    NASA Astrophysics Data System (ADS)

    Gorbar, E. V.; Shovkovy, I. A.; Vilchinskii, S.; Rudenok, I.; Boyarsky, A.; Ruchayskiy, O.

    2016-05-01

    Using the chiral kinetic theory we derive the electric and chiral current densities in inhomogeneous relativistic plasma. We also derive equations for the electric and chiral chemical potentials that close the Maxwell equations in such a plasma. The analysis is done in the regimes with and without a drift of the plasma as a whole. In addition to the currents present in the homogeneous plasma (Hall current, chiral magnetic, chiral separation, and chiral electric separation effects, as well as Ohm's current) we derive several new terms associated with inhomogeneities of the plasma. Apart from various diffusionlike terms, we find also new dissipationless terms that are independent of relaxation time. Their origin can be traced to the Berry curvature modifications of the kinetic theory.

  4. Asymmetric synthesis using chiral-encoded metal

    PubMed Central

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-01-01

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity. PMID:27562028

  5. Asymmetric synthesis using chiral-encoded metal

    NASA Astrophysics Data System (ADS)

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-08-01

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity.

  6. Enantioselective recognition at mesoporous chiral metal surfaces

    PubMed Central

    Wattanakit, Chularat; Côme, Yémima Bon Saint; Lapeyre, Veronique; Bopp, Philippe A.; Heim, Matthias; Yadnum, Sudarat; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2014-01-01

    Chirality is widespread in natural systems, and artificial reproduction of chiral recognition is a major scientific challenge, especially owing to various potential applications ranging from catalysis to sensing and separation science. In this context, molecular imprinting is a well-known approach for generating materials with enantioselective properties, and it has been successfully employed using polymers. However, it is particularly difficult to synthesize chiral metal matrices by this method. Here we report the fabrication of a chirally imprinted mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and chiral template molecules. The porous platinum retains a chiral character after removal of the template molecules. A matrix obtained in this way exhibits a large active surface area due to its mesoporosity, and also shows a significant discrimination between two enantiomers, when they are probed using such materials as electrodes. PMID:24548992

  7. On chirality of slime mould.

    PubMed

    Dimonte, Alice; Adamatzky, Andrew; Erokhin, Victor; Levin, Michael

    2016-02-01

    Left-right patterning and lateralised behaviour is an ubiquitous aspect of plants and animals. The mechanisms linking cellular chirality to the large-scale asymmetry of multicellular structures are incompletely understood, and it has been suggested that the chirality of living cells is hardwired in their cytoskeleton. We examined the question of biased asymmetry in a unique organism: the slime mould Physarum polycephalum, which is unicellular yet possesses macroscopic, complex structure and behaviour. In laboratory experiment using a T-shape, we found that Physarum turns right in more than 74% of trials. The results are in agreement with previously published studies on asymmetric movement of muscle cells, neutrophils, liver cells and growing neural filaments, and for the first time reveal the presence of consistently-biased laterality in the fungi kingdom. Exact mechanisms of the slime mould's direction preference remain unknown.

  8. On chirality of slime mould.

    PubMed

    Dimonte, Alice; Adamatzky, Andrew; Erokhin, Victor; Levin, Michael

    2016-02-01

    Left-right patterning and lateralised behaviour is an ubiquitous aspect of plants and animals. The mechanisms linking cellular chirality to the large-scale asymmetry of multicellular structures are incompletely understood, and it has been suggested that the chirality of living cells is hardwired in their cytoskeleton. We examined the question of biased asymmetry in a unique organism: the slime mould Physarum polycephalum, which is unicellular yet possesses macroscopic, complex structure and behaviour. In laboratory experiment using a T-shape, we found that Physarum turns right in more than 74% of trials. The results are in agreement with previously published studies on asymmetric movement of muscle cells, neutrophils, liver cells and growing neural filaments, and for the first time reveal the presence of consistently-biased laterality in the fungi kingdom. Exact mechanisms of the slime mould's direction preference remain unknown. PMID:26747637

  9. On lattice chiral gauge theories

    NASA Technical Reports Server (NTRS)

    Maiani, L.; Rossi, G. C.; Testa, M.

    1991-01-01

    The Smit-Swift-Aoki formulation of a lattice chiral gauge theory is presented. In this formulation the Wilson and other non invariant terms in the action are made gauge invariant by the coupling with a nonlinear auxilary scalar field, omega. It is shown that omega decouples from the physical states only if appropriate parameters are tuned so as to satisfy a set of BRST identities. In addition, explicit ghost fields are necessary to ensure decoupling. These theories can give rise to the correct continuum limit. Similar considerations apply to schemes with mirror fermions. Simpler cases with a global chiral symmetry are discussed and it is shown that the theory becomes free at decoupling. Recent numerical simulations agree with those considerations.

  10. Optically controllable THz chiral metamaterials.

    PubMed

    Kenanakis, G; Zhao, R; Katsarakis, N; Kafesaki, M; Soukoulis, C M; Economou, E N

    2014-05-19

    Switchable and tunable chiral metamaterial response is numerically demonstrated here in different uniaxial chiral metamaterial structures operating in the THz regime. The structures are based on the bi-layer conductor design and the tunable/switchable response is achieved by replacing parts of the metallic components of the structures by photoconducting Si, which can be transformed from an insulating to an almost conducting state through photoexcitation, achievable under external optical pumping. All the structures proposed and discussed here exhibit frequency regions with giant tunable circular dichroism, as well as regions with giant tunable optical activity, showing unique potential in the achievement of active THz polarization components, like tunable polarizers and polarization filters. PMID:24921336

  11. Bootstrapping N=2 chiral correlators

    NASA Astrophysics Data System (ADS)

    Lemos, Madalena; Liendo, Pedro

    2016-01-01

    We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.

  12. Chiral anomaly, bosonization, and fractional charge

    SciTech Connect

    Mignaco, J.A.; Monteiro, M.A.R.

    1985-06-15

    We present a method to evaluate the Jacobian of chiral rotations, regulating determinants through the proper-time method and using Seeley's asymptotic expansion. With this method we compute easily the chiral anomaly for ..nu.. = 4,6 dimensions, discuss bosonization of some massless two-dimensional models, and handle the problem of charge fractionization. In addition, we comment on the general validity of Fujikawa's approach to regulate the Jacobian of chiral rotations with non-Hermitian operators.

  13. Thin-wire scatterers in chiral media.

    PubMed

    Jaggard, D L; Liu, J C; Grot, A; Pelet, P

    1991-06-01

    The effect of the handedness of chiral materials on the differential scattering cross section of embedded conducting wires is examined. The bow-tie-shaped induced current distributions and the resulting forbidden zone of radiation are explained through fundamental physical principles. We find that thin-wire scatterers can be divided into subchiral, chiral, and superchiral classes according to the degree of chirality of the host material and the electromagnetic length of the wire.

  14. Chirality operators for Heisenberg spin systems

    SciTech Connect

    Subrahmanyam, V. )

    1994-09-01

    The ground state of closed Heisenberg spin chains with an odd number of sites has a chiral degeneracy, in addition to a twofold Kramers degeneracy. A nonzero chirality implies that the spins are not coplanar, and is a measure of handedness. The chirality operator, which can be treated as a spin-1/2 operator, is explicitly constructed in terms of the spin operators, and is given as commutator of permutation operators.

  15. Flat-space chiral gravity.

    PubMed

    Bagchi, Arjun; Detournay, Stéphane; Grumiller, Daniel

    2012-10-12

    We provide the first evidence for a holographic correspondence between a gravitational theory in flat space and a specific unitary field theory in one dimension lower. The gravitational theory is a flat-space limit of topologically massive gravity in three dimensions at a Chern-Simons level of k=1. The field theory is a chiral two-dimensional conformal field theory with a central charge of c=24. PMID:23102291

  16. Anomalies and Discrete Chiral Symmetries

    SciTech Connect

    Creutz, M.

    2009-09-07

    The quantum anomaly that breaks the U(1) axial symmetry of massless multi-flavored QCD leaves behind a discrete flavor-singlet chiral invariance. With massive quarks, this residual symmetry has a close connection with the strong CP-violating parameter theta. One result is that if the lightest quarks are degenerate, then a first order transition will occur when theta passes through pi. The resulting framework helps clarify when the rooting prescription for extrapolating in the number of flavors is valid.

  17. Staggered chiral random matrix theory

    SciTech Connect

    Osborn, James C.

    2011-02-01

    We present a random matrix theory for the staggered lattice QCD Dirac operator. The staggered random matrix theory is equivalent to the zero-momentum limit of the staggered chiral Lagrangian and includes all taste breaking terms at their leading order. This is an extension of previous work which only included some of the taste breaking terms. We will also present some results for the taste breaking contributions to the partition function and the Dirac eigenvalues.

  18. Chiral symmetry and nucleon structure

    SciTech Connect

    Holstein, B.R. . Dept. of Physics and Astromony Washington Univ., Seattle, WA . Inst. for Nuclear Theory)

    1992-01-01

    Recently it has been realized that significant tests of the validity of QCD are available in low energy experiments (E < 500 MeV) by exploiting the property of (broken) chiral symmetry. This technique has been highly developed in The Goldstone boson sector by the work of Gasser and Leutwyler. Application to the nucleon system is much more difficult and is now being carefully developed.

  19. Discrete reductive perturbation technique

    SciTech Connect

    Levi, Decio; Petrera, Matteo

    2006-04-15

    We expand a partial difference equation (P{delta}E) on multiple lattices and obtain the P{delta}E which governs its far field behavior. The perturbative-reductive approach is here performed on well-known nonlinear P{delta}Es, both integrable and nonintegrable. We study the cases of the lattice modified Korteweg-de Vries (mKdV) equation, the Hietarinta equation, the lattice Volterra-Kac-Van Moerbeke equation and a nonintegrable lattice KdV equation. Such reductions allow us to obtain many new P{delta}Es of the nonlinear Schroedinger type.

  20. Chiral plasmons without magnetic field

    PubMed Central

    Song, Justin C. W.; Rudner, Mark S.

    2016-01-01

    Plasmons, the collective oscillations of interacting electrons, possess emergent properties that dramatically alter the optical response of metals. We predict the existence of a new class of plasmons—chiral Berry plasmons (CBPs)—for a wide range of 2D metallic systems including gapped Dirac materials. As we show, in these materials the interplay between Berry curvature and electron–electron interactions yields chiral plasmonic modes at zero magnetic field. The CBP modes are confined to system boundaries, even in the absence of topological edge states, with chirality manifested in split energy dispersions for oppositely directed plasmon waves. We unveil a rich CBP phenomenology and propose setups for realizing them, including in anomalous Hall metals and optically pumped 2D Dirac materials. Realization of CBPs will offer a powerful paradigm for magnetic field-free, subwavelength optical nonreciprocity, in the mid-IR to terahertz range, with tunable splittings as large as tens of THz, as well as sensitive all-optical diagnostics of topological bands. PMID:27071090

  1. Objects of Maximum Electromagnetic Chirality

    NASA Astrophysics Data System (ADS)

    Fernandez-Corbaton, Ivan; Fruhnert, Martin; Rockstuhl, Carsten

    2016-07-01

    We introduce a definition of the electromagnetic chirality of an object and show that it has an upper bound. Reciprocal objects attain the upper bound if and only if they are transparent for all the fields of one polarization handedness (helicity). Additionally, electromagnetic duality symmetry, i.e., helicity preservation upon interaction, turns out to be a necessary condition for reciprocal objects to attain the upper bound. We use these results to provide requirements for the design of such extremal objects. The requirements can be formulated as constraints on the polarizability tensors for dipolar objects or on the material constitutive relations for continuous media. We also outline two applications for objects of maximum electromagnetic chirality: a twofold resonantly enhanced and background-free circular dichroism measurement setup, and angle-independent helicity filtering glasses. Finally, we use the theoretically obtained requirements to guide the design of a specific structure, which we then analyze numerically and discuss its performance with respect to maximal electromagnetic chirality.

  2. Chiral plasmons without magnetic field.

    PubMed

    Song, Justin C W; Rudner, Mark S

    2016-04-26

    Plasmons, the collective oscillations of interacting electrons, possess emergent properties that dramatically alter the optical response of metals. We predict the existence of a new class of plasmons-chiral Berry plasmons (CBPs)-for a wide range of 2D metallic systems including gapped Dirac materials. As we show, in these materials the interplay between Berry curvature and electron-electron interactions yields chiral plasmonic modes at zero magnetic field. The CBP modes are confined to system boundaries, even in the absence of topological edge states, with chirality manifested in split energy dispersions for oppositely directed plasmon waves. We unveil a rich CBP phenomenology and propose setups for realizing them, including in anomalous Hall metals and optically pumped 2D Dirac materials. Realization of CBPs will offer a powerful paradigm for magnetic field-free, subwavelength optical nonreciprocity, in the mid-IR to terahertz range, with tunable splittings as large as tens of THz, as well as sensitive all-optical diagnostics of topological bands. PMID:27071090

  3. Chiral methyl-branched pheromones.

    PubMed

    Ando, Tetsu; Yamakawa, Rei

    2015-07-01

    Insect pheromones are some of the most interesting natural products because they are utilized for interspecific communication between various insects, such as beetles, moths, ants, and cockroaches. A large number of compounds of many kinds have been identified as pheromone components, reflecting the diversity of insect species. While this review deals only with chiral methyl-branched pheromones, the chemical structures of more than one hundred non-terpene compounds have been determined by applying excellent analytical techniques. Furthermore, their stereoselective syntheses have been achieved by employing trustworthy chiral sources and ingenious enantioselective reactions. The information has been reviewed here not only to make them available for new research but also to understand the characteristic chemical structures of the chiral pheromones. Since biosynthetic studies are still limited, it might be meaningful to examine whether the structures, particularly the positions and configurations of the branched methyl groups, are correlated with the taxonomy of the pheromone producers and also with the function of the pheromones in communication systems. PMID:25849023

  4. Lateral chirality-sorting optical forces.

    PubMed

    Hayat, Amaury; Mueller, J P Balthasar; Capasso, Federico

    2015-10-27

    The transverse component of the spin angular momentum of evanescent waves gives rise to lateral optical forces on chiral particles, which have the unusual property of acting in a direction in which there is neither a field gradient nor wave propagation. Because their direction and strength depends on the chiral polarizability of the particle, they act as chirality-sorting and may offer a mechanism for passive chirality spectroscopy. The absolute strength of the forces also substantially exceeds that of other recently predicted sideways optical forces. PMID:26453555

  5. Generation of a Chiral Giant Micelle.

    PubMed

    Ito, Thiago H; Salles, Airton G; Priebe, Jacks P; Miranda, Paulo C M L; Morgon, Nelson H; Danino, Dganit; Mancini, Giovanna; Sabadini, Edvaldo

    2016-08-23

    Over the past few years, chiral supramolecular assemblies have been successfully used for recognition, sensing and enantioselective transformations. Several approaches are available to control chirality of discrete assemblies (e.g., cages and capsules), but few are efficient in assuring chirality for micellar aggregates. Optically active amino acid-derived surfactants are commonly used to generate chiral spherical micelles. To circumvent this limitation, we benefited from the uniaxial growth of spherical micelles into long cylindrical micelles usually called wormlike or giant micelles, upon the addition of cosolutes. This paper describes the unprecedented formation of chiral giant micelles in aqueous solutions of cetyltrimethylammonium bromide (CTAB) upon increasing addition of enantiopure sodium salt of 1,1'-bi-2-naphthol (Na-binaphtholate) as a cosolute. Depending on the concentrations of CTAB and Na-binaphtholate, chiral gel-like systems are obtained. The transition from spherical to giant micellar structures was probed using rheology, cryo-transmission electron microscopy, polarimetry, and electronic circular dichroism (CD). CD can be effectively used to monitor the incorporation of Na-binaphtholate into the micelle palisade as well as to determine its transition to giant micellar structures. Our approach expands the scope for chirality induction in micellar aggregates bringing the possibility to generate "smart" chiral systems and an alternative asymmetric chiral environment to perform enantioselective transformations. PMID:27499127

  6. Chiral selection on inorganic crystalline surfaces

    NASA Technical Reports Server (NTRS)

    Hazen, Robert M.; Sholl, David S.

    2003-01-01

    From synthetic drugs to biodegradable plastics to the origin of life, the chiral selection of molecules presents both daunting challenges and significant opportunities in materials science. Among the most promising, yet little explored, avenues for chiral molecular discrimination is adsorption on chiral crystalline surfaces - periodic environments that can select, concentrate and possibly even organize molecules into polymers and other macromolecular structures. Here we review experimental and theoretical approaches to chiral selection on inorganic crystalline surfaces - research that is poised to open this new frontier in understanding and exploiting surface-molecule interactions.

  7. Chiral Magnetic Effect in Hydrodynamic Approximation

    NASA Astrophysics Data System (ADS)

    Zakharov, Valentin I.

    We review derivations of the chiral magnetic effect (ChME) in hydrodynamic approximation. The reader is assumed to be familiar with the basics of the effect. The main challenge now is to account for the strong interactions between the constituents of the fluid. The main result is that the ChME is not renormalized: in the hydrodynamic approximation it remains the same as for non-interacting chiral fermions moving in an external magnetic field. The key ingredients in the proof are general laws of thermodynamics and the Adler-Bardeen theorem for the chiral anomaly in external electromagnetic fields. The chiral magnetic effect in hydrodynamics represents a macroscopic manifestation of a quantum phenomenon (chiral anomaly). Moreover, one can argue that the current induced by the magnetic field is dissipation free and talk about a kind of "chiral superconductivity". More precise description is a quantum ballistic transport along magnetic field taking place in equilibrium and in absence of a driving force. The basic limitation is the exact chiral limit while temperature—excitingly enough—does not seemingly matter. What is still lacking, is a detailed quantum microscopic picture for the ChME in hydrodynamics. Probably, the chiral currents propagate through lower-dimensional defects, like vortices in superfluid. In case of superfluid, the prediction for the chiral magnetic effect remains unmodified although the emerging dynamical picture differs from the standard one.

  8. Variational Monte Carlo study of chiral spin liquid in quantum antiferromagnet on the triangular lattice

    NASA Astrophysics Data System (ADS)

    Hu, Wen-Jun; Gong, Shou-Shu; Sheng, D. N.

    2016-08-01

    By using Gutzwiller projected fermionic wave functions and variational Monte Carlo technique, we study the spin-1 /2 Heisenberg model with the first-neighbor (J1), second-neighbor (J2), and additional scalar chiral interaction JχSi.(Sj×Sk) on the triangular lattice. In the nonmagnetic phase of the J1-J2 triangular model with 0.08 ≲J2/J1≲0.16 , recent density-matrix renormalization group (DMRG) studies [Zhu and White, Phys. Rev. B 92, 041105(R) (2015), 10.1103/PhysRevB.92.041105 and Hu, Gong, Zhu, and Sheng, Phys. Rev. B 92, 140403(R) (2015), 10.1103/PhysRevB.92.140403] find a possible gapped spin liquid with the signal of a competition between a chiral and a Z2 spin liquid. Motivated by the DMRG results, we consider the chiral interaction JχSi.(Sj×Sk) as a perturbation for this nonmagnetic phase. We find that with growing Jχ, the gapless U(1) Dirac spin liquid, which has the best variational energy for Jχ=0 , exhibits the energy instability towards a gapped spin liquid with nontrivial magnetic fluxes and nonzero chiral order. We calculate topological Chern number and ground-state degeneracy, both of which identify this flux state as the chiral spin liquid with fractionalized Chern number C =1 /2 and twofold topological degeneracy. Our results indicate a positive direction to stabilize a chiral spin liquid near the nonmagnetic phase of the J1-J2 triangular model.

  9. Evaluation of Dalbavancin as chiral selector for HPLC and comparison with Teicoplanin based chiral stationary phases

    PubMed Central

    ZHANG, XIAOTONG; BAO, YE; HUANG, KE; BARNETT-RUNDLETT, KIMBER L.; ARMSTRONG, DANIEL W.

    2015-01-01

    Dalbavancin is a new compound of the macrocyclic glycopeptide family. It was covalently linked to 5μm silica particles by using two different binding chemsitries. Approximately two hundred and fifty racemates including (A) heterocyclic compounds; (B) chiral acids; (C) chiral amines; (D) chiral alcohols; (E) chiral sulfoxides and sulfilimines; (F) amino acids and amino acid derivatives; and (G) other chiral compounds were tested on the two new chiral stationary phases (CSP) using three different mobile phases. As dalbavancin is structurally related to teicoplanin, the same set of chiral compounds was screened on two commercially available teicoplanin CSPs for comparison. The dalbavancin CSPs were able to separate some enantiomers that were not separated by the teicoplanin CSPs and also showed improved separations for many racemates. However, there were other compounds only separated or better separated on teicoplanin CSPS. Therefore, the dalbavancin CSPs are complementary to the teicoplanin CSPs. PMID:19676111

  10. Chiral symmetry breaking and confinement beyond rainbow-ladder truncation

    NASA Astrophysics Data System (ADS)

    Bashir, Adnan; Raya, Alfredo; Sánchez-Madrigal, Saúl

    2011-08-01

    A nonperturbative construction of the 3-point fermion-boson vertex which obeys its Ward-Takahashi or Slavnov-Taylor identity, ensures the massless fermion and boson propagators transform according to their local gauge covariance relations, reproduces perturbation theory in the weak coupling regime and provides a gauge independent description for dynamical chiral symmetry breaking and confinement has been a long-standing goal in physically relevant gauge theories such as quantum electrodynamics (QED) and quantum chromodynamics. In this paper, we demonstrate that the same simple and practical form of the vertex can achieve these objectives not only in 4-dimensional quenched QED but also in its 3-dimensional counterpart. Employing this convenient form of the vertex ansatz into the Schwinger-Dyson equation for the fermion propagator, we observe that it renders the critical coupling in 4-dimensional quenched QED markedly gauge independent in contrast with the bare vertex and improves on the well-known Curtis-Pennington construction. Furthermore, our proposal yields gauge independent order parameters for confinement and dynamical chiral symmetry breaking in 3-dimensional quenched QED.

  11. Vortex Crystals with Chiral Stripes in Itinerant Magnets

    NASA Astrophysics Data System (ADS)

    Ozawa, Ryo; Hayami, Satoru; Barros, Kipton; Chern, Gia-Wei; Motome, Yukitoshi; Batista, Cristian D.

    Noncoplanar spin textures in itinerant magnets are generating increasing interest because of the associated spin Berry phase, which induces a tremendous effective magnetic field on the itinerant electrons. Such noncoplanar spin textures appear frequently in itinerant magnets, even with vanishingly small spin-orbit coupling. We explore a generic condition for noncoplanar spin ordering, with a focus on ``frustration'' in itinerant magnets, that is characterized by multiple global maxima in the magnetic susceptibility. In a simple square Kondo lattice model, we find that a noncoplanar vortex-antivortex crystal with a one-dimensional modulation of spin scalar chirality becomes stable in a wide range of electron filling fraction. The unexpected result is obtained by careful analyses of higher-order terms in the perturbative expansion in terms of the Kondo exchange coupling and the degree of noncoplanarity, as well as numerical simulation based on the Langevin and stochastic Landau-Lifshitz-Gilbert dynamics with the kernel polynomial method.

  12. Chiral bosonic phases on the Haldane honeycomb lattice

    NASA Astrophysics Data System (ADS)

    Vasić, Ivana; Petrescu, Alexandru; Le Hur, Karyn; Hofstetter, Walter

    2015-03-01

    Recent experiments in ultracold atoms and photonic analogs have reported the implementation of artificial gauge fields in lattice systems, facilitating the realization of topological phases. Motivated by such advances, we investigate the Haldane honeycomb lattice tight-binding model, for bosons with local interactions at the average filling of one boson per site. We analyze the ground-state phase diagram and uncover three distinct phases: a uniform superfluid (SF), a chiral superfluid (CSF), and a plaquette Mott insulator with local current loops (PMI). Nearest-neighbor and next-nearest-neighbor currents distinguish CSF from SF, and the phase transition between them is first order. We apply bosonic dynamical mean-field theory and exact diagonalization to obtain the phase diagram, complementing numerics with calculations of excitation spectra in strong and weak coupling perturbation theory. The characteristic density fluctuations, current correlation functions, and excitation spectra are measurable in ultracold atom experiments.

  13. Perturbative unidirectional invisibility

    NASA Astrophysics Data System (ADS)

    Mostafazadeh, Ali

    2015-08-01

    We outline a general perturbative method of evaluating scattering features of finite-range complex potentials and use it to examine complex perturbations of a rectangular barrier potential. In optics, these correspond to modulated refractive index profiles of the form n (x ) =n0+f (x ) , where n0 is real, f (x ) is complex valued, and |f (x ) | ≪1 ≤n0 . We give a comprehensive description of the phenomenon of unidirectional invisibility for such media, proving five general theorems on its realization in P T -symmetric and non-P T -symmetric material. In particular, we establish the impossibility of unidirectional invisibility for P T -symmetric samples whose refractive index has a constant real part and show how a simple scaling transformation of a unidirectionally invisible P T -symmetric index profile with n0=1 may be used to generate a hierarchy of unidirectionally invisible P T -symmetric index profiles with n0>1 . The results pertaining to unidirectional invisibility for n0>1 open the way for the experimental studies of this phenomenon in a variety of active materials. As an application of our general results, we show that a medium with n (x ) =n0+ζ ei K x , ζ and K real, and |ζ |≪1 can support unidirectional invisibility only for n0=1 . We then construct unidirectionally invisible index profiles of the form n (x ) =n0+∑ℓzℓei Kℓx with zℓ complex, Kℓ real, | zℓ|≪1 , and n0>1 .

  14. Chiral hypervalent iodine reagents: synthesis and reactivity.

    PubMed

    Parra, Alejandro; Reboredo, Silvia

    2013-12-16

    Chiral hypervalent iodine chemistry has been steadily increasing in importance in recent years. This review catalogues enantioselective transformations triggered by chiral hypervalent iodine(III/V) reagents, in stoichiometric or catalytic quantities, highlighting the different reactivities in terms of yield and enantioselectivity. Moreover, the synthesis of the most remarkable and successful catalysts has been illustrated in detail.

  15. Three-dimensional Chiral Plasmonic Oligomers

    NASA Astrophysics Data System (ADS)

    Hentschel, Mario

    2013-03-01

    We demonstrate chiral optical response in stacked arrangements of plasmonic nanostructures. We show that three-dimensional arrangements of plasmonic ``meta-atoms'' only exhibit a chiral optical response if similar plasmonic ``atoms'' are arranged in a handed fashion as we require resonant plasmonic coupling. Moreover, we demonstrate that such particle groupings, similarly to molecular systems, possess the capability to encode their three-dimensional arrangement in unique and well-modulated spectra, making them ideal candidates for a three-dimensional chiral plasmon ruler. Furthermore, we discuss the onset of a broadband chiral optical response in the wavelength regime between 700 nm and 3500 nm upon charge transfer between the nanoparticles. We show in experiment and simulation that this response is due to the ohmic contact between adjacent particles which causes a strong red-shift of the fundamental mode. The geometrical shape of the resulting fused particles allows for efficient excitation of higher order modes. Calculated spectra and field distributions confirm our interpretation and show a number of interacting plasmonic modes. Finally, we will discuss plasmonic diastereomers which consist of multiple chiral centers. We find that the chiral optical response of the composite molecules can be traced back to the properties of the constituting building blocks. We demonstrate that the optical response of complex chiral plasmonic systems can be decomposed and understood in terms of fundamental building blocks, offering simple and straightforward design rules for future applications such as chiral optical elements and enantiomer sensors.

  16. Color Confinement and Dynamical Chiral Symmetry Breaking

    NASA Astrophysics Data System (ADS)

    Nakamura, Naoki; Suzuki, Tsuneo

    We study the relation between the quark confinement and the dynamical chiral symmetry breaking in SU(2) QCD by deriving an effective Lagrangian of a monopole field and the chiral fields from the dual Ginzburg-Landau type Lagrangian(DGL Lagrangian)…

  17. Quantization of the chiral soliton in medium

    NASA Astrophysics Data System (ADS)

    Nagai, S.; Sawado, N.; Shiiki, N.

    2006-01-01

    Chiral solitons coupled with quarks in medium are studied based on the Wigner-Seitz approximation. The chiral quark soliton model is used to obtain the classical soliton solutions. To investigate nucleon and Δ in matter, the semi-classical quantization is performed by the cranking method. The saturation for nucleon matter and Δ matter are observed.

  18. Generalized electromagnetic fields in a chiral medium

    NASA Astrophysics Data System (ADS)

    Bisht, P. S.; Singh, Jivan; Negi, O. P. S.

    2007-09-01

    The time-dependent Dirac-Maxwell's equations in the presence of electric and magnetic sources are reformulated in a chiral medium, and the solutions for the classical problem are obtained in a unique, simple and consistent manner. The quaternion reformulation of generalized electromagnetic fields in the chiral medium has also been discussed in a compact, simple and consistent manner.

  19. Chiral gravity, log gravity, and extremal CFT

    SciTech Connect

    Maloney, Alexander; Song Wei; Strominger, Andrew

    2010-03-15

    We show that the linearization of all exact solutions of classical chiral gravity around the AdS{sub 3} vacuum have positive energy. Nonchiral and negative-energy solutions of the linearized equations are infrared divergent at second order, and so are removed from the spectrum. In other words, chirality is confined and the equations of motion have linearization instabilities. We prove that the only stationary, axially symmetric solutions of chiral gravity are BTZ black holes, which have positive energy. It is further shown that classical log gravity--the theory with logarithmically relaxed boundary conditions--has finite asymptotic symmetry generators but is not chiral and hence may be dual at the quantum level to a logarithmic conformal field theories (CFT). Moreover we show that log gravity contains chiral gravity within it as a decoupled charge superselection sector. We formally evaluate the Euclidean sum over geometries of chiral gravity and show that it gives precisely the holomorphic extremal CFT partition function. The modular invariance and integrality of the expansion coefficients of this partition function are consistent with the existence of an exact quantum theory of chiral gravity. We argue that the problem of quantizing chiral gravity is the holographic dual of the problem of constructing an extremal CFT, while quantizing log gravity is dual to the problem of constructing a logarithmic extremal CFT.

  20. Orientation-Dependent Handedness and Chiral Design

    NASA Astrophysics Data System (ADS)

    Efrati, Efi; Irvine, William T. M.

    2014-01-01

    Chirality occupies a central role in fields ranging from biological self-assembly to the design of optical metamaterials. The definition of chirality, as given by Lord Kelvin, associates chirality with the lack of mirror symmetry: the inability to superpose an object on its mirror image. While this definition has guided the classification of chiral objects for over a century, the quantification of handed phenomena based on this definition has proven elusive, if not impossible, as manifest in the paradox of chiral connectedness. In this work, we put forward a quantification scheme in which the handedness of an object depends on the direction in which it is viewed. While consistent with familiar chiral notions, such as the right-hand rule, this framework allows objects to be simultaneously right and left handed. We demonstrate this orientation dependence in three different systems—a biomimetic elastic bilayer, a chiral propeller, and optical metamaterial—and find quantitative agreement with chirality pseudotensors whose form we explicitly compute. The use of this approach resolves the existing paradoxes and naturally enables the design of handed metamaterials from symmetry principles.

  1. Chiral THz metamaterial with tunable optical activity

    SciTech Connect

    Zhou, Jiangfeng; Taylor, Antoinette; O' Hara, John; Chowdhury, Roy; Zhao, Rongkuo; Soukoullis, Costas M

    2010-01-01

    Optical activity in chiral metamaterials is demonstrated in simulation and shows actively tunable giant polarization rotation at THz frequencies. Electric current distributions show that pure chirality is achieved by our bi-Iayer chiral metamaterial design. The chirality can be optically controlled by illumination with near-infrared light. Optical activity, occurring in chiral materials such as DNA, sugar and many other bio-molecules, is a phenomenon of great importance to many areas of science including molecular biology, analytical chemistry, optoelectronics and display applications. This phenomenon is well understood at an effective medium level as a magnetic/electric moment excited by the electric/magnetic field of the incident electromagnetic (EM) wave. Usually, natural chiral materials exhibit very weak optical activity e.g. a gyrotropic quartz crystal. The optical activity of chiral metamaterials, however, can be five orders of magnitude stronger. Chiral metamaterials are made of sub-wavelength resonators lacking symmetry planes. The asymmetry allows magnetic moments to be excited by the electric field of the incident EM wave and vice versa. Recently, chiral metamaterials have been demonstrated and lead to prospects in giant optical activity, circular dichroism, negative refraction and reversing the Casmir force. These fascinating optical properties require strong chirality, which may be designed through the microscopic structure of chiral metamaterials. However, these metamaterials have a fixed response function, defined by the geometric structuring, which limits their ability to manipulate EM waves. Active metamaterials realize dynamic control of response functions and have produced many influential applications such as ultra-fast switching devices, frequency and phase modulation and memory devices. Introducing active designs to chiral metamaterials will give additional freedom in controlling the optical activity, and therefore enable dynamic manipulation

  2. Tunable lithography masks using chiral nematic fluids

    NASA Astrophysics Data System (ADS)

    Jeong, Hyeon Su; Srinivasarao, Mohan; Jung, Hee-Tae

    2013-03-01

    We present a facile route for pattern formation using chiral nematic fluids as tunable masks in lithography process. The chiral nematic phase prepared by adding a chiral dopant (CB15) to 5CB acted as a set of parallel cylindrical lenses and as a polarization selective photomask for the preparation of periodic line patterns. The pitch of the helical twist was easily controlled by the concentration of chiral agent and the feature size of the resulting pattern was easily tuned. Because of the high mobility of the small liquid crystalline compound, the preparation of chiral nematic fluids based lithography masks requires only a few seconds. This approach has significant advantages including facility, range of surface ordering, and rate of forming periodic arrays. Current affiliation: SK Innovation, Daejeon, Korea

  3. Enantioselective environmental toxicology of chiral pesticides.

    PubMed

    Ye, Jing; Zhao, Meirong; Niu, Lili; Liu, Weiping

    2015-03-16

    The enantioselective environmental toxic effect of chiral pesticides is becoming more important. As the industry develops, increasing numbers of chiral insecticides and herbicides will be introduced into use, potentially posing toxic effects on nontarget living beings. Chiral pesticides, including herbicides such as acylanilides, phenoxypropanoic acids, and imidazolinones, and insecticides such as synthetic pyrethroids, organophosphates, and DDT often behave enantioselectively during agricultural use. These compounds also pose unpredictable enantioselective ecological threats to nontarget living beings and/or humans, affecting the food chain and entire ecosystems. Thus, to investigate the enantioselective toxic effects of chiral insecticides and herbicides is necessary during environmental protection. The environmental toxicology of chiral pesticides, especially the findings obtained from studies conducted in our laboratory during the past 10 years, is reviewed. PMID:25643169

  4. Chiral magnetic effect in condensed matter systems

    DOE PAGESBeta

    Li, Qiang; Kharzeev, Dmitri E.

    2016-12-01

    The chiral magnetic effect is the generation of electrical current induced by chirality imbalance in the presence of magnetic field. It is a macroscopic manifestation of the quantum anomaly in relativistic field theory of chiral fermions. In the quark-gluon plasma, the axial anomaly induces topological charge changing transition that results in the generation of electrical current along the magnetic field. In condensed matter systems, the chiral magnetic effect was first predicted in the gapless semiconductors with tow energy bands having pointlike degeneracies. In addition, thirty years later after this prediction, the chiral magnetic effect was finally observed in the 3Dmore » Dirac/Weyl semimetals.« less

  5. A liquid crystalline chirality balance for vapours

    NASA Astrophysics Data System (ADS)

    Ohzono, Takuya; Yamamoto, Takahiro; Fukuda, Jun-Ichi

    2014-04-01

    Chiral discrimination of vapours plays an important role in olfactory perception of biological systems and its realization by artificial sensors has been an intriguing challenge. Here, we report a simple method that tangibly visualizes the chirality of a diverse variety of molecules dissolved from vapours with high sensitivity, by making use of a structural change in a periodic microstructure of a nematic liquid crystal confined in open microchannels. This microstructure is accompanied by a topological line defect of a zigzag form with equal lengths of ‘zig’ and ‘zag.’ We find that a tiny amount of vapour of chiral molecules injected onto the liquid crystal induces the imbalance of ‘zig’ and ‘zag’ depending on its enantiomeric excess within a few seconds. Our liquid-crystal-based ‘chirality balance’ offers a simple, quick and versatile chirality-sensing/-screening method for gas-phase analysis (for example, for odours, environmental chemicals or drugs).

  6. Canonical density matrix perturbation theory.

    PubMed

    Niklasson, Anders M N; Cawkwell, M J; Rubensson, Emanuel H; Rudberg, Elias

    2015-12-01

    Density matrix perturbation theory [Niklasson and Challacombe, Phys. Rev. Lett. 92, 193001 (2004)] is generalized to canonical (NVT) free-energy ensembles in tight-binding, Hartree-Fock, or Kohn-Sham density-functional theory. The canonical density matrix perturbation theory can be used to calculate temperature-dependent response properties from the coupled perturbed self-consistent field equations as in density-functional perturbation theory. The method is well suited to take advantage of sparse matrix algebra to achieve linear scaling complexity in the computational cost as a function of system size for sufficiently large nonmetallic materials and metals at high temperatures. PMID:26764847

  7. Cosmological perturbations in massive bigravity

    SciTech Connect

    Lagos, Macarena; Ferreira, Pedro G. E-mail: p.ferreira1@physics.ox.ac.uk

    2014-12-01

    We present a comprehensive analysis of classical scalar, vector and tensor cosmological perturbations in ghost-free massive bigravity. In particular, we find the full evolution equations and analytical solutions in a wide range of regimes. We show that there are viable cosmological backgrounds but, as has been found in the literature, these models generally have exponential instabilities in linear perturbation theory. However, it is possible to find stable scalar cosmological perturbations for a very particular choice of parameters. For this stable subclass of models we find that vector and tensor perturbations have growing solutions. We argue that special initial conditions are needed for tensor modes in order to have a viable model.

  8. Canonical density matrix perturbation theory.

    PubMed

    Niklasson, Anders M N; Cawkwell, M J; Rubensson, Emanuel H; Rudberg, Elias

    2015-12-01

    Density matrix perturbation theory [Niklasson and Challacombe, Phys. Rev. Lett. 92, 193001 (2004)] is generalized to canonical (NVT) free-energy ensembles in tight-binding, Hartree-Fock, or Kohn-Sham density-functional theory. The canonical density matrix perturbation theory can be used to calculate temperature-dependent response properties from the coupled perturbed self-consistent field equations as in density-functional perturbation theory. The method is well suited to take advantage of sparse matrix algebra to achieve linear scaling complexity in the computational cost as a function of system size for sufficiently large nonmetallic materials and metals at high temperatures.

  9. Axially chiral allenyl gold complexes.

    PubMed

    Johnson, Alice; Laguna, Antonio; Gimeno, M Concepción

    2014-09-17

    Unprecedented allenyl gold complexes have been achieved starting from triphenylpropargylphosphonium bromide. Two different coordination modes of the allene isomer of triphenylphosphoniumpropargylide to gold have been found depending on the gold oxidation state. Bromo-, pentafluorophenyl-, and triphenylphosphine-gold(I) allenyl complexes were prepared in which the α carbon coordinates to the gold(I) center. A chiral pentafluorophenyl-gold(III) allenyl complex with the gold atoms coordinated to the γ carbon was also prepared. All the complexes have been structurally characterized by X-ray diffraction showing the characteristic distances for a C═C═C unit.

  10. Nuclear forces and chiral theories

    SciTech Connect

    Friar, J.L. |

    1995-09-01

    Recent successes in ab initio calculations of light nuclei (A=2-6) will be reviewed and correlated with the dynamical consequences of chiral symmetry. The tractability of nuclear physics evinced by these results is evidence for that symmetry. The relative importance of three-nucleon forces, four-nucleon forces, multi-pion exchanges, and relativistic corrections will be discussed in the context of effective field theories and dimensional power counting. Isospin violation in the nuclear force will also be discussed in this context.

  11. Pion-photon reactions and chiral dynamics in Primakoff processes at COMPASS

    NASA Astrophysics Data System (ADS)

    Krämer, Markus

    2016-05-01

    At the COMPASS experiment at CERN, pion-photon reactions are investigated using the Primakoff effect, where high-energetic pions react with the quasi-real photons surrounding the target nuclei. The production of a single hard photon in such a pion scattering, at lowest momentum transfer to the nucleus, is related to pion Compton scattering. Studying the energy distribution of the outgoing photons, the pion polarizability can be extracted. In addition to the measurement with a pion beam, control measurements with a muon beam allow us to estimate the systematics. The COMPASS result is in tension with earlier dedicated measurements and rather in agreement with the theoretical expectation from chiral perturbation theory. Based on the same data set, reactions with neutral and charged pions in the final state are studied. At low invariant mass of the pion-photon system, these reactions are governed by chiral dynamics. Using partial-wave analysis techniques, the absolute cross sections for the production of π-π+π- and π-π0π0 states from π-γ interactions are measured and compared to predictions from chiral perturbation theory. At higher pion-photon masses, the production of 3π resonances is studied with the focus on their radiative couplings.

  12. Chiral Potts spin glass in d =2 and 3 dimensions

    NASA Astrophysics Data System (ADS)

    Ćaǧlar, Tolga; Berker, A. Nihat

    2016-09-01

    The chiral spin-glass Potts system with q =3 states is studied in d =2 and 3 spatial dimensions by renormalization-group theory and the global phase diagrams are calculated in temperature, chirality concentration p , and chirality-breaking concentration c , with determination of phase chaos and phase-boundary chaos. In d =3 , the system has ferromagnetic, left-chiral, right-chiral, chiral spin-glass, and disordered phases. The phase boundaries to the ferromagnetic, left- and right-chiral phases show, differently, an unusual, fibrous patchwork (microreentrances) of all four (ferromagnetic, left-chiral, right-chiral, chiral spin-glass) ordered phases, especially in the multicritical region. The chaotic behavior of the interactions, under scale change, are determined in the chiral spin-glass phase and on the boundary between the chiral spin-glass and disordered phases, showing Lyapunov exponents in magnitudes reversed from the usual ferromagnetic-antiferromagnetic spin-glass systems. At low temperatures, the boundaries of the left- and right-chiral phases become thresholded in p and c . In d =2 , the chiral spin-glass Potts system does not have a spin-glass phase, consistently with the lower-critical dimension of ferromagnetic-antiferromagnetic spin glasses. The left- and right-chirally ordered phases show reentrance in chirality concentration p .

  13. Static and dynamic effects of chirality in dielectric media

    NASA Astrophysics Data System (ADS)

    Lakes, R. S.

    2016-09-01

    Chiral dielectrics are considered from the perspective of continuum representations of spatial heterogeneity. Static effects in isotropic chiral dielectrics are predicted, provided the electric field has nonzero third spatial derivatives. The effects are compared with static chiral phenomena in Cosserat elastic materials which obey generalized continuum constitutive equations. Dynamic monopole-like magnetic induction is predicted in chiral dielectric media.

  14. Chiral magnetism at oxide interfaces

    NASA Astrophysics Data System (ADS)

    Randeria, Mohit

    2014-03-01

    There are tantalizing hints of magnetism at the n-type LaAlO3/SrTiO3 interface, but the experimental evidence remains controversial in view of some of the differences between different samples and probes. I will argue that if magnetism exists at interfaces, symmetry arguments imply chiral interactions that lead to a spiral ground state in zero external field and skyrmion crystals for H ≠ 0 . I will next present a microscopic model that provides a possible mechanism for the formation of local moments. I will show that the coupling of these moments to itinerant electrons leads to ferromagnetic double exchange together with Dzyaloshinskii-Moriya (DM) interactions and an easy-plane ``compass'' anisotropy, which arise from Rashba spin-orbit coupling (SOC) due to the lack of inversion symmetry at the interface. The compass term, often ignored in the literature on chiral magnetism, is shown to play a crucial role in determining the magnetic ground state. I will compare our results with existing torque magnetometry data on LAO/STO and try to reconcile it with scanning SQUID magnetometry. Finally, I will present the phase diagram in a field and show that easy-plane anisotropy stabilizes an unexpectedly large skyrmion crystal phase and describe its properties. (Work done in collaboration with Sumilan Banerjee, Onur Erten, Daniel Kestner and James Rowland). Supported by DOE-BES DE-SC0005035, NSF-DMR-1006532 and NSF MRSEC DMR-0820414.

  15. Nucleic acids, proteins, and chirality

    NASA Technical Reports Server (NTRS)

    Usher, D. A.; Profy, A. T.; Walstrum, S. A.; Needels, M. C.; Bulack, S. C.; Lo, K. M.

    1984-01-01

    The present investigation is concerned with experimental results related, in one case, to the chirality of nucleotides, and, in another case, to the possibility of a link between the chirality of nucleic acids, and that of peptides. It has been found that aminoacylation of the 'internal' hydroxyl group of a dinucleoside monophosphate can occur stereoselectively. However, this reaction has not yet been made a part of a working peptide synthesis scheme. The formation and cleavage of oligonucleotides is considered. In the event of the formation of a helical complex between the oligonucleotide and the polymer, 1-prime,5-prime-bonds in the oligomer are found to become more resistant towards cleavage. The conditions required for peptide bond formation are examined, taking into account the known structures of RNA and possible mechanisms for prebiotic peptide bond formation. The possibility is considered that the 2-prime,5-prime-internucleotide linkage could have played an important part in the early days of biological peptide synthesis.

  16. Hierarchical chirality transfer in the growth of Towel Gourd tendrils

    NASA Astrophysics Data System (ADS)

    Wang, Jian-Shan; Wang, Gang; Feng, Xi-Qiao; Kitamura, Takayuki; Kang, Yi-Lan; Yu, Shou-Wen; Qin, Qing-Hua

    2013-10-01

    Chirality plays a significant role in the physical properties and biological functions of many biological materials, e.g., climbing tendrils and twisted leaves, which exhibit chiral growth. However, the mechanisms underlying the chiral growth of biological materials remain unclear. In this paper, we investigate how the Towel Gourd tendrils achieve their chiral growth. Our experiments reveal that the tendrils have a hierarchy of chirality, which transfers from the lower levels to the higher. The change in the helical angle of cellulose fibrils at the subcellular level induces an intrinsic torsion of tendrils, leading to the formation of the helical morphology of tendril filaments. A chirality transfer model is presented to elucidate the chiral growth of tendrils. This present study may help understand various chiral phenomena observed in biological materials. It also suggests that chirality transfer can be utilized in the development of hierarchically chiral materials having unique properties.

  17. Hierarchical chirality transfer in the growth of Towel Gourd tendrils.

    PubMed

    Wang, Jian-Shan; Wang, Gang; Feng, Xi-Qiao; Kitamura, Takayuki; Kang, Yi-Lan; Yu, Shou-Wen; Qin, Qing-Hua

    2013-01-01

    Chirality plays a significant role in the physical properties and biological functions of many biological materials, e.g., climbing tendrils and twisted leaves, which exhibit chiral growth. However, the mechanisms underlying the chiral growth of biological materials remain unclear. In this paper, we investigate how the Towel Gourd tendrils achieve their chiral growth. Our experiments reveal that the tendrils have a hierarchy of chirality, which transfers from the lower levels to the higher. The change in the helical angle of cellulose fibrils at the subcellular level induces an intrinsic torsion of tendrils, leading to the formation of the helical morphology of tendril filaments. A chirality transfer model is presented to elucidate the chiral growth of tendrils. This present study may help understand various chiral phenomena observed in biological materials. It also suggests that chirality transfer can be utilized in the development of hierarchically chiral materials having unique properties. PMID:24173107

  18. Hierarchical chirality transfer in the growth of Towel Gourd tendrils

    PubMed Central

    Wang, Jian-Shan; Wang, Gang; Feng, Xi-Qiao; Kitamura, Takayuki; Kang, Yi-Lan; Yu, Shou-Wen; Qin, Qing-Hua

    2013-01-01

    Chirality plays a significant role in the physical properties and biological functions of many biological materials, e.g., climbing tendrils and twisted leaves, which exhibit chiral growth. However, the mechanisms underlying the chiral growth of biological materials remain unclear. In this paper, we investigate how the Towel Gourd tendrils achieve their chiral growth. Our experiments reveal that the tendrils have a hierarchy of chirality, which transfers from the lower levels to the higher. The change in the helical angle of cellulose fibrils at the subcellular level induces an intrinsic torsion of tendrils, leading to the formation of the helical morphology of tendril filaments. A chirality transfer model is presented to elucidate the chiral growth of tendrils. This present study may help understand various chiral phenomena observed in biological materials. It also suggests that chirality transfer can be utilized in the development of hierarchically chiral materials having unique properties. PMID:24173107

  19. Determination of the chiral couplings L{sub 10} and C{sub 87} from semileptonic {tau} decays

    SciTech Connect

    Gonzalez-Alonso, Martin; Pich, Antonio; Prades, Joaquim

    2008-12-01

    Using recent precise hadronic {tau}-decay data on the V-A spectral function, and general properties of QCD such as analyticity, the operator product expansion, and chiral perturbation theory, we get accurate values for the QCD chiral order parameters L{sub 10}{sup r}(M{sub {rho}}) and C{sub 87}{sup r}(M{sub {rho}}). These two low-energy constants appear at order p{sup 4} and p{sup 6}, respectively, in the chiral perturbation theory expansion of the V-A correlator. At order p{sup 4} we obtain L{sub 10}{sup r}(M{sub {rho}})=-(5.22{+-}0.06)x10{sup -3}. Including in the analysis the two-loop (order p{sup 6}) contributions, we get L{sub 10}{sup r}(M{sub {rho}})=-(4.06{+-}0.39)x10{sup -3} and C{sub 87}{sup r}(M{sub {rho}})=(4.89{+-}0.19)x10{sup -3} GeV{sup -2}. In the SU(2) chiral effective theory, the corresponding low-energy coupling takes the value l{sub 5}=13.30{+-}0.11 at order p{sup 4}, and l{sub 5}=12.24{+-}0.21 at order p{sup 6}.

  20. On dark energy isocurvature perturbation

    SciTech Connect

    Liu, Jie; Zhang, Xinmin; Li, Mingzhe E-mail: limz@nju.edu.cn

    2011-06-01

    Determining the equation of state of dark energy with astronomical observations is crucially important to understand the nature of dark energy. In performing a likelihood analysis of the data, especially of the cosmic microwave background and large scale structure data the dark energy perturbations have to be taken into account both for theoretical consistency and for numerical accuracy. Usually, one assumes in the global fitting analysis that the dark energy perturbations are adiabatic. In this paper, we study the dark energy isocurvature perturbation analytically and discuss its implications for the cosmic microwave background radiation and large scale structure. Furthermore, with the current astronomical observational data and by employing Markov Chain Monte Carlo method, we perform a global analysis of cosmological parameters assuming general initial conditions for the dark energy perturbations. The results show that the dark energy isocurvature perturbations are very weakly constrained and that purely adiabatic initial conditions are consistent with the data.

  1. Perturbation theory in electron diffraction

    NASA Astrophysics Data System (ADS)

    Bakken, L. N.; Marthinsen, K.; Hoeier, R.

    1992-12-01

    The Bloch-wave approach is used for discussing multiple inelastic electron scattering and higher-order perturbation theory in inelastic high-energy electron diffraction. In contrast to previous work, the present work describes three-dimensional diffraction so that higher-order Laue zone (HOLZ) effects are incorporated. Absorption is included and eigenvalues and eigenvectors are calculated from a structure matrix with the inclusion of an absorptive potential. Centrosymmetric as well as non-centrosymmetric crystal structures are allowed. An iteration method with a defined generalized propagation function for solving the inelastic coupling equations is described. It is shown that a similar iteration method with the same propagation function can be used for obtaining higher-order perturbation terms for the wave-function when a perturbation is added to the crystal potential. Finally, perturbation theory by matrix calculations when a general perturbation is added to the structure matrix is considered.

  2. Modulated preheating and isocurvature perturbations

    SciTech Connect

    Enqvist, Kari; Rusak, Stanislav E-mail: stanislav.rusak@helsinki.fi

    2013-03-01

    We consider a model of preheating where the coupling of the inflaton to the preheat field is modulated by an additional scalar field which is light during inflation. We establish that such a model produces the observed curvature perturbation analogously to the modulated reheating scenario. The contribution of modulated preheating to the power spectrum and to non-Gaussianity can however be significantly larger compared to modulated perturbative reheating. We also consider the implications of the current constraints on isocurvature perturbations in case where the modulating field is responsible for cold dark matter. We find that existing bounds on CDM isocurvature perturbations imply that modulated preheating is unlikely to give a dominant contribution to the curvature perturbation and that the same bounds suggest important constraints on non-Gaussianity and the amount of primordial gravitational waves.

  3. Broken chiral symmetry on a null plane

    SciTech Connect

    Beane, Silas R.

    2013-10-15

    On a null-plane (light-front), all effects of spontaneous chiral symmetry breaking are contained in the three Hamiltonians (dynamical Poincaré generators), while the vacuum state is a chiral invariant. This property is used to give a general proof of Goldstone’s theorem on a null-plane. Focusing on null-plane QCD with N degenerate flavors of light quarks, the chiral-symmetry breaking Hamiltonians are obtained, and the role of vacuum condensates is clarified. In particular, the null-plane Gell-Mann–Oakes–Renner formula is derived, and a general prescription is given for mapping all chiral-symmetry breaking QCD condensates to chiral-symmetry conserving null-plane QCD condensates. The utility of the null-plane description lies in the operator algebra that mixes the null-plane Hamiltonians and the chiral symmetry charges. It is demonstrated that in a certain non-trivial limit, the null-plane operator algebra reduces to the symmetry group SU(2N) of the constituent quark model. -- Highlights: •A proof (the first) of Goldstone’s theorem on a null-plane is given. •The puzzle of chiral-symmetry breaking condensates on a null-plane is solved. •The emergence of spin-flavor symmetries in null-plane QCD is demonstrated.

  4. Chirally symmetric but confining dense, cold matter

    NASA Astrophysics Data System (ADS)

    Glozman, L. Ya.; Wagenbrunn, R. F.

    2008-03-01

    The folklore tradition about the QCD phase diagram is that at the chiral restoration phase transition at finite density hadrons are deconfined and there appears the quark matter. We address this question within the only known exactly solvable confining and chirally symmetric model. It is postulated within this model that there exists linear Coulomb-like confining interaction. The chiral symmetry breaking and the quark Green function are obtained from the Schwinger-Dyson (gap) equation while the color-singlet meson spectrum results from the Bethe-Salpeter equation. We solve this model at T=0 and finite chemical potential μ and obtain a clear chiral restoration phase transition at the critical value μcr. Below this value the spectrum is similar to the previously obtained one at μ=0. At μ>μcr the quarks are still confined and the physical spectrum consists of bound states which are arranged into a complete set of exact chiral multiplets. This explicitly demonstrates that a chirally symmetric matter consisting of confined but chirally symmetric hadrons at finite chemical potential is also possible in QCD. If so, there must be nontrivial implications for astrophysics.

  5. Chirally symmetric but confining dense, cold matter

    SciTech Connect

    Glozman, L. Ya.; Wagenbrunn, R. F.

    2008-03-01

    The folklore tradition about the QCD phase diagram is that at the chiral restoration phase transition at finite density hadrons are deconfined and there appears the quark matter. We address this question within the only known exactly solvable confining and chirally symmetric model. It is postulated within this model that there exists linear Coulomb-like confining interaction. The chiral symmetry breaking and the quark Green function are obtained from the Schwinger-Dyson (gap) equation while the color-singlet meson spectrum results from the Bethe-Salpeter equation. We solve this model at T=0 and finite chemical potential {mu} and obtain a clear chiral restoration phase transition at the critical value {mu}{sub cr}. Below this value the spectrum is similar to the previously obtained one at {mu}=0. At {mu}>{mu}{sub cr} the quarks are still confined and the physical spectrum consists of bound states which are arranged into a complete set of exact chiral multiplets. This explicitly demonstrates that a chirally symmetric matter consisting of confined but chirally symmetric hadrons at finite chemical potential is also possible in QCD. If so, there must be nontrivial implications for astrophysics.

  6. Chiral Alfvén Wave in Anomalous Hydrodynamics.

    PubMed

    Yamamoto, Naoki

    2015-10-01

    We study the hydrodynamic regime of chiral plasmas at high temperature. We find a new type of gapless collective excitation induced by chiral effects in an external magnetic field. This is a transverse wave, and it is present even in incompressible fluids, unlike the chiral magnetic and chiral vortical waves. The velocity is proportional to the coefficient of the gravitational anomaly. We briefly discuss the possible relevance of this "chiral Alfvén wave" in physical systems. PMID:26551804

  7. Elastic waves in structurally chiral composites

    SciTech Connect

    Yang, Shiuhkuang.

    1990-01-01

    Elastic wave propagation through structurally chiral (handed) media was studied. The primary objectives are to construct structurally chiral composites and to characterize their properties. Structurally chiral composites are constructed by stacking identical uniaxial plates, whose consecutive symmetric axes describe either a right- or a left-handed spiral. A matrix representation method is used to solve the elastic wave propagation in such layered composites. Numerical computation of the plane wave reflection and transmission characteristics for chiral arrangements are compared with those for the non-chiral one. It is concluded that the co-polarized characteristics are unaffected by the structural chirality, while the cross-polarized reflected and transmitted fields are greatly influenced by it. Numerical modeling is also applied for the real samples. The polarization ellipse of the transmitted field of each sample is calculated. To verify the form chirality, four glass-reinforced chiral and non-chiral composite samples are made from helix tape, molded, debulked, and cured individually under identical temperature and pressure histories. The spiral composites are characterized using shear and longitudinal wave transducers in ultrasonic experiments. Both the material properties and the polarization ellipse of the transmitted field of each sample are measured. It is proved conclusively that left and right handedness in the microstructures of a material rotates the plane of polarization of a propagating shear wave in the opposite directions. Thus it is now possible to say that by reducing the length scale of the handed microstructures tone more appropriate to its propagating wavelength, a medium is obtained that gives rise to effects similar to optical radar and optical dichroism.

  8. Extreme optical chirality of plasmonic nanohole arrays due to chiral Fano resonance

    NASA Astrophysics Data System (ADS)

    Kondratov, A. V.; Gorkunov, M. V.; Darinskii, A. N.; Gainutdinov, R. V.; Rogov, O. Y.; Ezhov, A. A.; Artemov, V. V.

    2016-05-01

    We study the physical origin of extreme optical chirality of subwavelength arrays of chiral holes in metal. We reconstruct the nanoscale relief of the hole arrays by the atomic-force microscopy and post-process the data to acquire an average unit-cell shape clear of noise and defects. For this shape, we perform the electromagnetic finite difference time domain simulations that reproduce all important features observed by the light-transmission experiments, including the notably strong circular dichroism and optical activity covering the whole range of possible values. To interpret the simulation results, we develop a chiral coupled-mode model which yields analytical expressions that fit accurately the numerical data in a broad wavelength range. Our conclusions undoubtedly link the extreme optical chirality to the plasmon resonances of chiral holes and the associated chiral Fano-type transmission resonance.

  9. Induced chirality through electromagnetic coupling between chiral molecular layers and plasmonic nanostructures.

    PubMed

    Abdulrahman, Nadia A; Fan, Z; Tonooka, Taishi; Kelly, Sharon M; Gadegaard, Nikolaj; Hendry, Euan; Govorov, Alexander O; Kadodwala, Malcolm

    2012-02-01

    We report a new approach for creating chiral plasmonic nanomaterials. A previously unconsidered, far-field mechanism is utilized which enables chirality to be conveyed from a surrounding chiral molecular material to a plasmonic resonance of an achiral metallic nanostructure. Our observations break a currently held preconception that optical properties of plasmonic particles can most effectively be manipulated by molecular materials through near-field effects. We show that far-field electromagnetic coupling between a localized plasmon of a nonchiral nanostructure and a surrounding chiral molecular layer can induce plasmonic chirality much more effectively (by a factor of 10(3)) than previously reported near-field phenomena. We gain insight into the mechanism by comparing our experimental results to a simple electromagnetic model which incorporates a plasmonic object coupled with a chiral molecular medium. Our work offers a new direction for the creation of hybrid molecular plasmonic nanomaterials that display significant chiroptical properties in the visible spectral region.

  10. Chiral effective-field theory in the {delta}(1232) region. II. Radiative pion photoproduction

    SciTech Connect

    Pascalutsa, Vladimir; Vanderhaeghen, Marc

    2008-01-01

    We present a theoretical study of the radiative pion photoproduction on the nucleon ({gamma}N{yields}{pi}N{gamma}{sup '}) in the {delta}-resonance region, with the aim to determine the magnetic dipole moment (MDM) of the {delta}{sup +}(1232). The study is done within the framework of chiral effective-field theory, where the expansion is performed (to next-to-leading order) in the {delta} power-counting scheme, an extension of chiral perturbation theory to the {delta}-resonance energy region. We present the results for the absorptive part of the {delta} MDM, as well as perform a sensitivity study of the dependence of {gamma}N{yields}{pi}N{gamma}{sup '} observables on the real part of the {delta} MDM. We find that an asymmetry for circular polarization of the photon beam may provide a model-independent way to measure the {delta} MDM.

  11. Nonlinear, driven-dissipative hydrodynamics and effective chiral description of an exciton-polariton superfluid

    NASA Astrophysics Data System (ADS)

    Kulkarni, Manas; Kolmakov, German

    2015-03-01

    Given recent remarkable experimental success on capturing hydrodynamic features of exciton-polariton condensates in optical microcavities and their potential implications for quantum and optical computing and information technologies, we present an effective chiral description for such systems. This description captures the fingerprints of hydrodynamics, namely, nonlinearity, dispersion and dissipation in the exciton-polariton system. The resulting chiral equation for the condensate perturbation wave dynamics is found to be of Burgers-type thereby providing a more transparent understanding of the complicated underlying coupled exciton-photon dynamics. By using analytical calculations and numerical simulations, we describe the phenomenon of polariton shock waves, solitons and defects in such systems. Our mapping is expected to have broad implications for other polariton and photon systems including dipolar exciton and magnon condensates. This mapping can further help one in engineering a delicate balance between the pump and damping to produce stable optical signals propagating in polariton circuits.

  12. Pion- and strangeness-baryon σ terms in the extended chiral constituent quark model

    NASA Astrophysics Data System (ADS)

    An, C. S.; Saghai, B.

    2015-07-01

    Within an extended chiral constituent quark formalism, we investigate contributions from all possible five-quark components in the octet baryons to the pion-baryon (σπ B) and strangeness-baryon (σs B) sigma terms: B ≡N ,Λ ,Σ ,Ξ . The probabilities of the quark-antiquark components in the ground-state baryon octet wave functions are calculated by taking the baryons to be admixtures of three- and five-quark components, with the relevant transitions handled via the 3P0 mechanism. Predictions for σπ B and σs B obtained by using input parameters taken from the literature are reported. Our results turn out to be, in general, consistent with the findings via lattice QCD and chiral perturbation theory.

  13. Chiral effective field theory predictions for muon capture on deuteron and {3}He.

    PubMed

    Marcucci, L E; Kievsky, A; Rosati, S; Schiavilla, R; Viviani, M

    2012-02-01

    The muon-capture reactions {2}H(μ{-},ν{μ})nn and {3}He(μ{-},ν{μ}){3}H are studied with nuclear potentials and charge-changing weak currents, derived in chiral effective field theory. The low-energy constants (LECs) c{D} and c{E}, present in the three-nucleon potential and (c{D}) axial-vector current, are constrained to reproduce the A=3 binding energies and the triton Gamow-Teller matrix element. The muon-capture rates on deuteron and {3}He are predicted to be 399±3  sec{-1} and 1494±21  sec{-1}, respectively. The spread accounts for the cutoff sensitivity, as well as uncertainties in the LECs and electroweak radiative corrections. By comparing the calculated and precisely measured rates on {3}He, a value for the induced pseudoscalar form factor is obtained in good agreement with the chiral perturbation theory prediction.

  14. Recent progress towards a chiral effective field theory for the NN system

    NASA Astrophysics Data System (ADS)

    Yang, C. J.; Long, Bingwei

    2015-10-01

    Since Weinberg's proposal two decades ago, chiral effective field theory in the NN sector has been developed and applied up to order O((Q/Mhi)4). In principle it could provide a model-independent description of nuclear force from QCD. However, in spite of its huge success, some open issues such as the renormalization group invariance and power counting, still remain to be solved. In this talk we refine the chiral effective field theory approach to the NN system based on a renormalization group analysis. Our results show that a truly model-independent description of NN system can be obtained by a new power counting which treats the subleading order corrections perturbatively.

  15. Chiral effective-field theory in the Delta(1232) region : II. radiative pion photoproduction

    SciTech Connect

    Vladimir Pascalutsa; Marc Vanderhaeghen

    2007-10-12

    We present a theoretical study of the radiative pion photoproduction on the nucleon ($\\gamma N \\rightarrow \\pi N \\gamma'$) in the $\\De$-resonance region, with the aim to determine the magnetic dipole moment (MDM) of the $\\Delta^+(1232)$. The study is done within the framework of chiral effective-field theory where the expansion is performed (to next-to-leading order) in the $\\delta$ power-counting scheme which is an extension of chiral perturbation theory to the $\\Delta$-resonance energy region. We present in detail the results for the absorptive part of the $\\Delta$ MDM, as well as a sensitivity study for the radiative pion photoproduction observables on the real part of the $\\Delta$ MDM. We find that an asymmetry for circular polarization of the photon beam may provide a model-independent way to measure the $\\Delta$ MDM.

  16. Enhanced Chiral Recognition by Cyclodextrin Dimers

    PubMed Central

    Voskuhl, Jens; Schaepe, Kira; Ravoo, Bart Jan

    2011-01-01

    In this article we investigate the effect of multivalency in chiral recognition. To this end, we measured the host-guest interaction of a β-cyclodextrin dimer with divalent chiral guests. We report the synthesis of carbohydrate-based water soluble chiral guests functionalized with two borneol, menthol, or isopinocampheol units in either (+) or (−) configuration. We determined the interaction of these divalent guests with a β-cyclodextrin dimer using isothermal titration calorimetry. It was found that—in spite of a highly unfavorable conformation—the cyclodextrin dimer binds to guest dimers with an increased enantioselectivity, which clearly reflects the effect of multivalency. PMID:21845101

  17. Towards chirality-pure carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Zhang, Yani; Zheng, Lianxi

    2010-10-01

    Current as-grown single-walled carbon nanotubes vary in diameter and chirality, which results in variations in their electronic and optical properties. Two approaches have been intensively studied to obtain chirality-pure nanotube structures and thus uniform properties for advanced applications. The first approach involves the post-synthesis separation according to the nanotubes' chiral vectors (n, m), and the second one involves direct synthes of carbon nanotubes with the same (n, m). This paper reviews the efforts along these two directions, with emphasis on the most recent progress of post-synthesis separation and the perspectives of controllable synthesis.

  18. Chiral Isotropic Liquids from Achiral Molecules

    SciTech Connect

    L Hough; M Spannuth; M Nakata; D Coleman; C Jones; G Dantlgraber; C Tschierske; J Watanabe; N Clark; et al.

    2011-12-31

    A variety of simple bent-core molecules exhibit smectic liquid crystal phases of planar fluid layers that are spontaneously both polar and chiral in the absence of crystalline order. We found that because of intralayer structural mismatch, such layers are also only marginally stable against spontaneous saddle splay deformation, which is incompatible with long-range order. This results in macroscopically isotropic fluids that possess only short-range orientational and positional order, in which the only macroscopically broken symmetry is chirality - even though the phases are formed from achiral molecules. Their conglomerate domains exhibit optical rotatory powers comparable to the highest ever found for isotropic fluids of chiral molecules.

  19. Synthesis of chiral dopants based on carbohydrates.

    PubMed

    Tsuruta, Toru; Koyama, Tetsuo; Yasutake, Mikio; Hatano, Ken; Matsuoka, Koji

    2014-07-01

    Chiral dopants based on carbohydrates for nematic liquid crystals were synthesized from D-glucose, and their helical twisting power (HTP) values were evaluated. The chiral dopants induced helices in the host nematic liquid crystals. An acetyl derivative having an ether-type glycosidic linkage between carbohydrate and a mesogenic moiety showed the highest HTP value of 10.4 μm(-1), while an acetyl derivative having an anomeric ester-type linkage did not show any HTP. It was surprising that this molecule had no HTP despite the presence of chirality in the molecule. A relationship between HTP and specific rotation was not observed in this study.

  20. A lattice chiral theory with multifermion couplings

    NASA Astrophysics Data System (ADS)

    Xue, She-Sheng

    1996-02-01

    Analyzing an SUL(2) ⊗ UR(1) chiral theory with multifermion couplings on a lattice, we find a possible region in the phase space of multifermion couplings, where no spontaneous symmetry breaking occurs, doublers are decoupled as massive Dirac fermions consistently with the SUL(2) ⊗ UR(1) chiral symmetry, the “spectator” fermion ψR( x) is free mode, whereas the normal mode of ψLi( x) is plausibly speculated to be chiral in the continuum limit. This is not in agreement with the general belief of the definite failure of theories so constructed.

  1. Undoubled Chiral Fermions on a Lattice

    NASA Astrophysics Data System (ADS)

    Xue, She-Sheng

    1997-02-01

    We analyze the dynamics of an SU L(2)⊗ U R(1) chiral theory on the lattice with a strong multifermion coupling. It is shown that no spontaneous symmetry breaking occurs; the "spectator" fermion ψR is a free mode; doublers are decoupled as massive Dirac fermions consistently with the chiral symmetries. In 1+1 dimension, we show that the right-handed three-fermion state disappears at the threshold and an undoubled left-handed chiral fermion remains in the continuum limit.

  2. The paradigm of Pseudodual Chiral Models

    SciTech Connect

    Zachos, C.K.; Curtright, T.L.

    1994-08-01

    This is a synopsis and extension of Phys. Rev. D49 5408 (1994). The Pseudodual Chiral Model illustrates 2-dimensional field theories which possess an infinite number of conservation laws but also allow particle production, at variance with naive expectations-a folk theorem of integrable models. We monitor the symmetries of the pseudodual model, both local and nonlocal, as transmutations of the symmetries of the (very different) usual Chiral Model. We refine the conventional algorithm to more efficiently produce the nonlocal symmetries of the model. We further find the canonical transformation which connects the usual chiral model to its fully equivalent dual model, thus contradistinguishing the pseudodual theory.

  3. The convoluted evolution of snail chirality

    NASA Astrophysics Data System (ADS)

    Schilthuizen, M.; Davison, A.

    2005-11-01

    The direction that a snail (Mollusca: Gastropoda) coils, whether dextral (right-handed) or sinistral (left-handed), originates in early development but is most easily observed in the shell form of the adult. Here, we review recent progress in understanding snail chirality from genetic, developmental and ecological perspectives. In the few species that have been characterized, chirality is determined by a single genetic locus with delayed inheritance, which means that the genotype is expressed in the mother's offspring. Although research lags behind the studies of asymmetry in the mouse and nematode, attempts to isolate the loci involved in snail chirality have begun, with the final aim of understanding how the axis of left-right asymmetry is established. In nature, most snail taxa (>90%) are dextral, but sinistrality is known from mutant individuals, populations within dextral species, entirely sinistral species, genera and even families. Ordinarily, it is expected that strong frequency-dependent selection should act against the establishment of new chiral types because the chiral minority have difficulty finding a suitable mating partner (their genitalia are on the ‘wrong’ side). Mixed populations should therefore not persist. Intriguingly, however, a very few land snail species, notably the subgenus Amphidromus sensu stricto, not only appear to mate randomly between different chiral types, but also have a stable, within-population chiral dimorphism, which suggests the involvement of a balancing factor. At the other end of the spectrum, in many species, different chiral types are unable to mate and so could be reproductively isolated from one another. However, while empirical data, models and simulations have indicated that chiral reversal must sometimes occur, it is rarely likely to lead to so-called ‘single-gene’ speciation. Nevertheless, chiral reversal could still be a contributing factor to speciation (or to divergence after speciation) when

  4. New chiral zinc complexes: synthesis, structure, and induction of axial chirality.

    PubMed

    Degenbeck, Helmut; Felten, Anne-Sophie; Escudero-Adán, Eduardo C; Benet-Buchholz, Jordi; Di Bari, Lorenzo; Pescitelli, Gennaro; Vidal-Ferran, Anton

    2012-08-20

    We describe an efficient methodology for the preparation of new chiral zinc complexes by assembling dynamically racemic biphenol derivatives and chiral 1,2-diamines with suitable zinc(II) precursors. Mononuclear and dinuclear zinc(II) complexes were formed from differently substituted biphenols. The solid-state and solution structural characterization of the resulting compounds allowed us to demonstrate a preferential sense of induced axial chirality for mononuclear complexes, a phenomenon that was not observed for the dinuclear ones. PMID:22862880

  5. Stochastic calculation of the Dirac spectrum on the lattice and a determination of chiral condensate in 2 + 1-flavor QCD†

    NASA Astrophysics Data System (ADS)

    Cossu, Guido; Fukaya, Hidenori; Hashimoto, Shoji; Kaneko, Takashi; Noaki, Jun-Ichi

    2016-09-01

    We compute the chiral condensate in 2 + 1-flavor QCD through the spectrum of low-lying eigenmodes of the Dirac operator. The number of eigenvalues of the Dirac operator is evaluated using a stochastic method with an eigenvalue filtering technique on the background gauge configurations generated by lattice QCD simulations including the effects of dynamical up, down, and strange quarks described by the Möbius domain-wall fermion formulation. The low-lying spectrum is related to the chiral condensate, which is one of the leading-order low-energy constants in chiral effective theory, as dictated by the Banks-Casher relation. The spectrum shape and its dependence on the sea quark masses calculated in numerical simulations are consistent with the expectation from one-loop chiral perturbation theory. After taking the chiral limit as well as the continuum limit using the data at three lattice spacings in the range 0.080-0.045 fm, we obtain Σ(2 GeV) = 270.0(4.9) MeV, with the error combining those from statistical and various sources of systematic error. The finite volume effect is confirmed to be under control by a direct comparison of the results from two different volumes at the lightest available sea quarks corresponding to 230 MeV pions.

  6. Resonance saturation of the chiral couplings at next-to-leading order in 1/N{sub C}

    SciTech Connect

    Rosell, Ignasi; Ruiz-Femenia, Pedro; Sanz-Cillero, Juan Jose

    2009-04-01

    The precision obtainable in phenomenological applications of chiral perturbation theory is currently limited by our lack of knowledge on the low-energy constants (LECs). The assumption that the most important contributions to the LECs come from the dynamics of the low-lying resonances, often referred to as the resonance saturation hypothesis, has stimulated the use of large-N{sub C} resonance Lagrangians in order to obtain explicit values for the LECs. We study the validity of the resonance saturation assumption at the next-to-leading order in the 1/N{sub C} expansion within the framework of resonance chiral theory. We find that, by imposing QCD short-distance constraints, the chiral couplings can be written in terms of the resonance masses and couplings and do not depend explicitly on the coefficients of the chiral operators in the Goldstone boson sector of resonance chiral theory. As we argue, this is the counterpart formulation of the resonance saturation statement in the context of the resonance Lagrangian. Going beyond leading order in the 1/N{sub C} counting allows us to keep full control of the renormalization scale dependence of the LEC estimates.

  7. Sea quark transverse momentum distributions and dynamical chiral symmetry breaking

    SciTech Connect

    Schweitzer, Peter; Strikman, Mark; Weiss, Christian

    2014-01-01

    Recent theoretical studies have provided new insight into the intrinsic transverse momentum distributions of valence and sea quarks in the nucleon at a low scale. The valence quark transverse momentum distributions (q - qbar) are governed by the nucleon's inverse hadronic size R{sup -1} ~ 0.2 GeV and drop steeply at large p{sub T}. The sea quark distributions (qbar) are in large part generated by non-perturbative chiral-symmetry breaking interactions and extend up to the scale rho{sup -1} ~ 0.6 GeV. These findings have many implications for modeling the initial conditions of perturbative QCD evolution of TMD distributions (starting scale, shape of p{sub T}. distributions, coordinate-space correlation functions). The qualitative difference between valence and sea quark intrinsic p{sub T}. distributions could be observed experimentally, by comparing the transverse momentum distributions of selected hadrons in semi-inclusive deep-inelastic scattering, or those of dileptons produced in pp and pbar-p scattering.

  8. Controlled chiral supramolecular assemblies of water soluble achiral porphyrins induced by chiral counterions.

    PubMed

    Rananaware, Anushri; La, Duong Duc; Al Kobaisi, Mohammad; Bhosale, Rajesh S; Bhosale, Sidhanath V; Bhosale, Sheshanath V

    2016-08-11

    We demonstrate a controlled chiral supramolecular assembly of achiral porphyrins induced by chiral d- and l-arginine (Arg) in water. Induction of chirality was confirmed by circular dichroism. TEM and SEM images confirm that these twisted ribbons are indeed formed by right- and left-handed helices with d- and l-Arg in water, respectively. The chiral assembly pathways described here are hierarchical, opening up the possibility that simple changes on microscopic (nm) length scales can be used to control structures on macroscopic (mm) length scales. PMID:27464524

  9. Chiral supramolecular polymers consisting of planar-chiral pillar[5]arene enantiomers.

    PubMed

    Ogoshi, Tomoki; Furuta, Takuya; Yamagishi, Tada-Aki

    2016-09-14

    Supramolecular polymers with diverse chiralities were constructed by supramolecular polymerization of planar-chiral host-guest conjugates in pS and pR forms. Hetero-chiral supramolecular polymerization using a racemic mixture of host-guest conjugates with pS and pR forms afforded a supramolecular polymer with a larger hydrodynamic radius than that obtained through homo-chiral supramolecular polymerization of host-guest conjugates with either pS or pR forms alone. PMID:27510359

  10. Disformal transformation of cosmological perturbations

    NASA Astrophysics Data System (ADS)

    Minamitsuji, Masato

    2014-10-01

    We investigate the gauge-invariant cosmological perturbations in the gravity and matter frames in the general scalar-tensor theory where two frames are related by the disformal transformation. The gravity and matter frames are the extensions of the Einstein and Jordan frames in the scalar-tensor theory where two frames are related by the conformal transformation, respectively. First, it is shown that the curvature perturbation in the comoving gauge to the scalar field is disformally invariant as well as conformally invariant, which gives the predictions from the cosmological model where the scalar field is responsible both for inflation and cosmological perturbations. Second, in case that the disformally coupled matter sector also contributes to curvature perturbations, we derive the evolution equations of the curvature perturbation in the uniform matter energy density gauge from the energy (non)conservation in the matter sector, which are independent of the choice of the gravity sector. While in the matter frame the curvature perturbation in the uniform matter energy density gauge is conserved on superhorizon scales for the vanishing nonadiabatic pressure, in the gravity frame it is not conserved even if the nonadiabatic pressure vanishes. The formula relating two frames gives the amplitude of the curvature perturbation in the matter frame, once it is evaluated in the gravity frame.

  11. Scalar Mesons and Chiral States

    NASA Astrophysics Data System (ADS)

    Ishida, M.; Ishida, S.

    2004-08-01

    The essential points and physical backgrounds of the covariant level-classification scheme, based on Ū(12)SF⊗O(3, 1)L, are reviewed: This scheme is extended from the non-relativistic SU(6)SF⊗O(3)L scheme by introducing the new SU(2)-spin (ρ-spin) degree of freedom, which is necessary for covariant description of composite hadrons. Our scheme predicts the existence of new type of chiral mesons and baryons (Chiralons) out of the conventional SU(6)SF⊗O(3)L scheme. The σ nonet is a typical example of chiralons to be assigned to the (qq¯) relativistic S-wave state. The new narrow mesons Ds(2317)/Ds(2463) are naturally assigned as the ground-state scalar and axial-vector chiralons in the (cs¯) system.

  12. Chiral exceptional points in metasurfaces

    NASA Astrophysics Data System (ADS)

    Kang, Ming; Chen, Jing; Chong, Y. D.

    2016-09-01

    An exceptional point (EP) is a degeneracy occurring in a non-energy-conserving system, in which two eigenvectors of a non-Hermitian Hamiltonian coalesce. We explore how EPs can be realized in a metamaterial surface, or metasurface, consisting of a pair of lossy coupled linear antennas in each unit cell. EPs appear in the eigenvectors of the transmission matrix by tuning the frequency and the coupling and loss rates of the metasurface. Each EP is associated with the appearance of a circularly polarized transmission eigenstate; hence, within the parameter space of the system, the EPs lie along pairs of curves with distinct chirality. Our results are obtained using finite-difference time-domain simulations, as well as a fitted coupled-mode theory. The coupled-mode theory agrees well with the numerical results and is capable of accurately predicting the EP f curves.

  13. Black Holes, q-Deformed 2d Yang-Mills, and Non-perturbative Topological Strings

    SciTech Connect

    Aganagic, Mina; Ooguri, Hirosi; Saulina, Natalia; Vafa, Cumrun

    2005-01-28

    We count the number of bound states of BPS black holes on local Calabi-Yau three-folds involving a Riemann surface of genus g. We show that the corresponding gauge theory on the brane reduces to a q-deformed Yang-Mills theory on the Riemann surface. Following the recent connection between the black hole entropy and the topological string partition function, we find that for a large black hole charge N, up to corrections of O(e^-N), Z_BH is given as a sum of a square of chiral blocks, each of which corresponds to a specific D-brane amplitude. The leading chiral block, the vacuum block, corresponds to the closed topological string amplitudes. The sub-leading chiral blocks involve topological string amplitudes with D-brane insertions at 2g-2 points on the Riemann surface analogous to the Omega points in the large N 2d Yang-Mills theory. The finite N amplitude provides a non-perturbative definition of topological strings in these backgrounds. This also leads to a novel non-perturbative formulation of c=1 non-critical string at the self-dual radius.

  14. Instantons, chiral dynamics, and hadronic resonances

    SciTech Connect

    Cristoforetti, M.; Faccioli, P.; Traini, M.

    2007-03-01

    We use the interacting instanton liquid model (IILM) as a tool to study the role played by the chiral interactions in the lowest-lying vector and axial-vector meson resonances. We find that narrow a{sub 1} and {rho} meson resonances can be generated by instanton-induced chiral forces, even in the absence of confinement. In the IILM, these hadrons are found to have masses only about 30% larger than the experimental value and small width < or approx. 10-50 MeV. This result suggests that chiral interactions are very important in these systems and provide most of their mass. We explore the decaying patterns of the {rho} meson, in the absence of confinement. We argue that, in our model where only chiral forces are switched on, this meson decays dissociating into its quark-antiquark constituents.

  15. Personal recollections on chiral symmetry breaking

    NASA Astrophysics Data System (ADS)

    Kobayashi, Makoto

    2016-07-01

    The author's work on the mass of pseudoscalar mesons is briefly reviewed. The emergence of the study of CP violation in the renormalizable gauge theory from consideration of chiral symmetry in the quark model is discussed.

  16. Chiral Magnetic Effect in Heavy Ion Collisions

    DOE PAGESBeta

    Liao, Jinfeng

    2016-12-01

    The Chiral Magnetic Effect (CME) is a remarkable phenomenon that stems from highly nontrivial interplay of QCD chiral symmetry, axial anomaly, and gluonic topology. We show it is of fundamental importance to search for the CME in experiments. The heavy ion collisions provide a unique environment where a hot chiral-symmetric quark-gluon plasma is created, gluonic topological fluctuations generate chirality imbalance, and very strong magnetic fields |Β→|~m2π are present during the early stage of such collisions. Significant efforts have been made to look for CME signals in heavy ion collision experiments. Lastly, in this contribution we give a brief overview onmore » the status of such efforts.« less

  17. Application of cyclodextrins in chiral capillary electrophoresis.

    PubMed

    Rezanka, Pavel; Navrátilová, Klára; Rezanka, Michal; Král, Vladimír; Sýkora, David

    2014-10-01

    CE represents a very powerful separation tool in the area of chiral separations. CD-mediated chiral CE is a continuously flourishing technique within the frame of the electromigration methods. In this review, a brief overview of the synthetic procedures leading to modified CDs is provided first. Next, selected aspects related to the utilization of CDs in chiral CE are discussed specifically in the view of recently published data. Advantages of CDs and basic principles of chiral CE are remained. The topic of the determination of binding constants is touched. Particular attention is paid to the effort aiming at better understanding of the molecular level of the enantiorecognition between CDs and the analyte in the solution. Powerful approaches extensively utilized in this field are NMR, molecular modeling, and computer simulations. Then, a summary of applications of CDs in the CE enantioseparations is given, covering years 2008-2013. Finally, the general trend of modified CDs use in separation science is statistically evaluated.

  18. Chiral Pesticide Pharmacokinetics: A Range of Values

    EPA Science Inventory

    Approximately 30% of pesticides are chiral and used as mixtures of two or more stereoisomers. In biological systems, these stereoisomers can exhibit significantly different pharmacokinetics (absorption, distribution, metabolism, and elimination). In spite of these differences, th...

  19. Chirality in thiolate-protected gold clusters.

    PubMed

    Knoppe, Stefan; Bürgi, Thomas

    2014-04-15

    Over recent years, research on thiolate-protected gold clusters Au(m)(SR)n has gained significant interest. Milestones were the successful determination of a series of crystal structures (Au102(SR)44, Au25(SR)18, Au38(SR)24, Au36(SR)24, and Au28(SR)20). For Au102(SR)44, Au38(SR)24, and Au28(SR)20, intrinsic chirality was found. Strong Cotton effects (circular dichroism, CD) of gold clusters protected by chiral ligands have been reported a long time ago, indicating the transfer of chiral information from the ligand into the cluster core. Our lab has done extensive studies on chiral thiolate-protected gold clusters, including those protected with chiral ligands. We demonstrated that vibrational circular dichroism can serve as a useful tool for the determination of conformation of the ligand on the surface of the cluster. The first reports on crystal structures of Au102(SR)44 and Au38(SR)24 revealed the intrinsic chirality of these clusters. Their chirality mainly arises from the arrangement of the ligands on the surface of the cluster cores. As achiral ligands are used to stabilize the clusters, racemic mixtures are obtained. However, the separation of the enantiomers by HPLC was demonstrated which enabled the measurement of their CD spectra. Thermally induced inversion allows determination of the activation parameters for their racemization. The inversion demonstrates that the gold-thiolate interface is anything but fixed; in contrast, it is rather flexible. This result is of fundamental interest and needs to be considered in future applications. A second line of our research is the selective introduction of chiral, bidentate ligands into the ligand layer of intrinsically chiral gold clusters. The ligand exchange reaction is highly diastereoselective. The bidentate ligand connects two of the protecting units on the cluster surface and thus effectively stabilizes the cluster against thermally induced inversion. A minor (but significant) influence of chiral ligands to

  20. DH(*) in chiral smectics under electric field.

    PubMed

    Meyer, C; Rabette, C; Gisse, P; Antonova, K; Dozov, I

    2016-07-01

    The behavior of double helices (DH(*) formed in the temperature interval N(*) -SmA(*) in compounds of non-chiral liquid crystals doped with chiral molecules was investigated. Two different systems presenting left-handed and right-handed chirality were studied. A statistics of the handedness of the DH(*) revealed a correlation with the mixture chirality, as predicted theoretically in C. Meyer, Yu. A. Nastishin, M. Kleman, Phys. Rev. E 82, 031704 (2010). By applying a gradually increasing AC electric field, one can observe the shrinking of the cylinder circumscribing the DH(*) . This shrink is accompanied by a reduction of the DH(*) 's pitch. This effect was similar to the one produced by the decrease of temperature in the absence of the field. PMID:27465656

  1. Nondipole Photoemission from Chiral Enantiomers of Camphor

    NASA Astrophysics Data System (ADS)

    Bowen, K. P.; Stolte, W. C.; Young, J. A.; Demchenko, I. N.; Guillemin, R.; Hemmers, O.; Piancastelli, M. N.; Lindle, D. W.

    2010-03-01

    K-shell photoemission from the carbonyl carbon in the chiral molecule camphor has been studied in the region just above the core-shell ionization threshold. Differences between angular distributions of emitted photoelectrons from the two enantiomers are attributed to the influence of chirality combined with nondipole effects in the photoemission process, despite the fact the measurements were taken using linearly polarized x-rays. The results suggest the possibility of a new form of linear dichroism.

  2. Chiral susceptibility in an effective interaction model

    SciTech Connect

    Min He; Yu Jiang; Sun Weimin; Zong Hongshi

    2008-04-01

    A closed integral expression for the chiral susceptibility at finite temperature is derived. The corresponding disconnected part, which proves to be of major physical relevance and free from the additive quadratic ultraviolet divergence, is identified. Then a calculation based on an effective model gluon propagator is conducted within the framework of the Dyson-Schwinger equations for two flavors in the chiral limit. A narrow, divergent peak is observed as temperature varies, and its implications are discussed.

  3. Chiral extrapolation of SU(3) amplitudes

    SciTech Connect

    Ecker, Gerhard

    2011-05-23

    Approximations of chiral SU(3) amplitudes at NNLO are proposed to facilitate the extrapolation of lattice data to the physical meson masses. Inclusion of NNLO terms is essential for investigating convergence properties of chiral SU(3) and for determining low-energy constants in a controllable fashion. The approximations are tested with recent lattice data for the ratio of decay constants F{sub K}/F{sub {pi}}.

  4. Control of normal chirality at hexagonal interfaces

    SciTech Connect

    Haraldsen, Jason T; Fishman, Randy Scott

    2010-01-01

    We study the net chirality created by the Dzyaloshinkii-Moriya interaction (DMI) at the boundary between hexagonal layers of magnetic and non-magnetic materials. It is shown that another mechanism besides elastic torsion is required to understand the change in chirality observed in Dy/Y multilayers during field-cooling. The paper shows that due to the overlap between magnetic and non-magnetic atoms, interfacial steps may produce a DMI normal to the interface in magnetic heterostructures.

  5. Analysis of rainbow scattering by a chiral sphere.

    PubMed

    Shang, Qing-Chao; Wu, Zhen-Sen; Qu, Tan; Li, Zheng-Jun; Bai, Lu; Gong, Lei

    2013-09-23

    Based on the scattering theory of a chiral sphere, rainbow phenomenon of a chiral sphere is numerically analyzed in this paper. For chiral spheres illuminated by a linearly polarized wave, there are three first-order rainbows, with whose rainbow angles varying with the chirality parameter. The spectrum of each rainbow structure is presented and the ripple frequencies are found associated with the size and refractive indices of the chiral sphere. Only two rainbow structures remain when the chiral sphere is illuminated by a circularly polarized plane wave. Finally, the rainbows of chiral spheres with slight chirality parameters are found appearing alternately in E-plane and H-plane with the variation of the chirality.

  6. Analysis of rainbow scattering by a chiral sphere.

    PubMed

    Shang, Qing-Chao; Wu, Zhen-Sen; Qu, Tan; Li, Zheng-Jun; Bai, Lu; Gong, Lei

    2013-09-23

    Based on the scattering theory of a chiral sphere, rainbow phenomenon of a chiral sphere is numerically analyzed in this paper. For chiral spheres illuminated by a linearly polarized wave, there are three first-order rainbows, with whose rainbow angles varying with the chirality parameter. The spectrum of each rainbow structure is presented and the ripple frequencies are found associated with the size and refractive indices of the chiral sphere. Only two rainbow structures remain when the chiral sphere is illuminated by a circularly polarized plane wave. Finally, the rainbows of chiral spheres with slight chirality parameters are found appearing alternately in E-plane and H-plane with the variation of the chirality. PMID:24104080

  7. Causal compensated perturbations in cosmology

    NASA Technical Reports Server (NTRS)

    Veeraraghavan, Shoba; Stebbins, Albert

    1990-01-01

    A theoretical framework is developed to calculate linear perturbations in the gravitational and matter fields which arise causally in response to the presence of stiff matter sources in a FRW cosmology. It is shown that, in order to satisfy energy and momentum conservation, the gravitational fields of the source must be compensated by perturbations in the matter and gravitational fields, and the role of such compensation in containing the initial inhomogeneities in their subsequent evolution is discussed. A complete formal solution is derived in terms of Green functions for the perturbations produced by an arbitrary source in a flat universe containing cold dark matter. Approximate Green function solutions are derived for the late-time density perturbations and late-time gravitational waves in a universe containing a radiation fluid. A cosmological energy-momentum pseudotensor is defined to clarify the nature of energy and momentum conservation in the expanding universe.

  8. A Molecular Model for Chiral Symmetry Breaking

    NASA Astrophysics Data System (ADS)

    Latinwo, Folarin; Stillinger, Frank; Debenedetti, Pablo

    In this work, we present a new class of molecular models for chiral phenomena in condensed matter systems. A key feature of these models is the ability of the four-site (tetramer) ``molecules'' to inter-convert between two distinct chiral forms (enantiomers). Given this feature, we use analytical theory and computer simulations to investigate the emergent chiral properties (including symmetry breaking) over a range of conditions. In particular, we consider the single-molecule level and condensed-phase behavior of our model system. Interestingly, we find that our liquid-phase predictions are in excellent agreement with recent experimental reports on chiral self-sorting in isotropic liquids. From this perspective, our model demonstrates accurate predictive capabilities, as well as a platform for understanding the microscopic origins of a variety of chiral phenomena. In a broader context, we anticipate that this class of models will be relevant to chirality-dominated areas such as the pharmaceutical industry and pre-biotic geochemistry.

  9. Chirality measures of α-amino acids.

    PubMed

    Jamróz, Michał H; Rode, Joanna E; Ostrowski, Sławomir; Lipiński, Piotr F J; Dobrowolski, Jan Cz

    2012-06-25

    To measure molecular chirality, the molecule is treated as a finite set of points in the Euclidean R(3) space supplemented by k properties, p(1)((i)), p(2)((i)), ..., p(k)((i)) assigned to the ith atom, which constitute a point in the Property P(k) space. Chirality measures are described as the distance between a molecule and its mirror image minimized over all its arbitrary orientation-preserving isometries in the R(3) × P(k) Cartesian product space. Following this formalism, different chirality measures can be estimated by taking into consideration different sets of atomic properties. Here, for α-amino acid zwitterionic structures taken from the Cambridge Structural Database and for all 1684 neutral conformers of 19 biogenic α-amino acid molecules, except glycine and cystine, found at the B3LYP/6-31G** level, chirality measures have been calculated by a CHIMEA program written in this project. It is demonstrated that there is a significant correlation between the measures determined for the α-amino acid zwitterions in crystals and the neutral forms in the gas phase. Performance of the studied chirality measures with changes of the basis set and computation method was also checked. An exemplary quantitative structure–activity relationship (QSAR) application of the chirality measures was presented by an introductory model for the benchmark Cramer data set of steroidal ligands of the sex-hormone binding globulin.

  10. Strangeness S =-1 hyperon-nucleon scattering in covariant chiral effective field theory

    NASA Astrophysics Data System (ADS)

    Li, Kai-Wen; Ren, Xiu-Lei; Geng, Li-Sheng; Long, Bingwei

    2016-07-01

    Motivated by the successes of covariant baryon chiral perturbation theory in one-baryon systems and in heavy-light systems, we study relevance of relativistic effects in hyperon-nucleon interactions with strangeness S =-1 . In this exploratory work, we follow the covariant framework developed by Epelbaum and Gegelia to calculate the Y N scattering amplitude at leading order. By fitting the five low-energy constants to the experimental data, we find that the cutoff dependence is mitigated, compared with the heavy-baryon approach. Nevertheless, the description of the experimental data remains quantitatively similar at leading order.

  11. Updated determination of chiral couplings and vacuum condensates from hadronic τ decay data

    NASA Astrophysics Data System (ADS)

    González-Alonso, Martín; Pich, Antonio; Rodríguez-Sánchez, Antonio

    2016-07-01

    We analyze the lowest spectral moments of the left-right two-point correlation function, using all known short-distance constraints and the recently updated ALEPH V -A spectral function from τ decays. This information is used to determine the low-energy couplings L10 and C87 of chiral perturbation theory and the lowest-dimensional contributions to the operator product expansion of the left-right correlator. A detailed statistical analysis is implemented to assess the theoretical uncertainties, including violations of quark-hadron duality.

  12. Chiral phase from three-spin interactions in an optical lattice

    SciTech Connect

    D'Cruz, Christian; Pachos, Jiannis K.

    2005-10-15

    A spin-1/2 chain model that includes three-spin interactions can effectively describe the dynamics of two species of bosons trapped in an optical lattice with a triangular-ladder configuration. A perturbative theoretical approach and numerical study of its ground state is performed that reveals a rich variety of phases and criticalities. We identify phases with periodicity one, two, or three, as well as critical points that belong in the same universality class as the Ising or the three-state Potts model. We establish a range of parameters, corresponding to a large degeneracy present between phases with period 2 and 3, that nests a gapless incommensurate chiral phase.

  13. Chiral recognition of zinc phthalocyanine on Cu(100) surface

    NASA Astrophysics Data System (ADS)

    Chen, Feng; Chen, Xiu; Liu, Lacheng; Song, Xin; Liu, Shuyi; Liu, Juan; Ouyang, Hongping; Cai, Yingxiang; Liu, Xiaoqing; Pan, Haibing; Zhu, Junfa; Wang, Li

    2012-02-01

    The windmill-like chiral nature of individual ZnPc molecules adsorbed on Cu(100) surface at room temperature has been revealed by scanning tunneling microscopy (STM) and the origin of such chirality is attributed to asymmetrical charge transfer between the molecules and the copper surface. Such chiral enantiomers do recognize each other in molecular level and spontaneously form second-level chiral supramolecular structures with the same chirality during thermally driven movements. The interactions between the ZnPc molecules during such chiral recognition process have been discussed based on the analysis of the sub-molecule-resolution STM images.

  14. Integration of inherent and induced chirality into subphthalocyanine analogue

    NASA Astrophysics Data System (ADS)

    Zhao, Luyang; Qi, Dongdong; Wang, Kang; Wang, Tianyu; Han, Bing; Tang, Zhiyong; Jiang, Jianzhuang

    2016-06-01

    Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore. In this work, chiral binaphthyl segment is directly fused into the central chromophore of a subphthalocyanine skeleton, resulting in a novel type of chiral subphthalocyanine analogue (R/S)-1 of integrated inherent and induced chirality. Impressively, an obviously enhanced optical activity is discerned for (R/S)-1 molecules, and corresponding enhancement mechanism is elucidated in detail. The synthesis strategy based on rational molecular design will open the door towards fabrication of chiral materials with giant optical activity, which will have great potential in chiroptical devices.

  15. [Advances in polymer materials as chiral stationary phase].

    PubMed

    Dai, Rongji; Wang, Huiting; Sun, Weiwei; Deng, Yulin; Lü, Fang; Liu, Xiujie

    2016-01-01

    The applications of chiral drugs had a profound impact on human health. With the development of disciplines of chemistry, materials and life science, the research on the separation and analysis of chiral drugs became intensified. Chromatography and the selection of chiral stationary phase played important roles in resolving chiral drugs. The optimization of polymer materials and their derivatives as chiral stationary phase become the main issue in recent years. Recent studies as well as prospects in polymer materials used as chiral stationary phase are presented in this paper. PMID:27319162

  16. The asymmetric alkylation of dimethylhydrazones; intermolecular chirality transfer using sparteine as chiral ligand.

    PubMed

    McSweeney, Christina M; Foley, Vera M; McGlacken, Gerard P

    2014-12-01

    The asymmetric alkylation of ketones represents a fundamental transformation in organic chemistry. Chiral auxiliaries have been used almost exclusively for this transformation. Herein we describe a strategy for the generation of enantiomerically enriched α-alkylated ketones up to an er of 83 : 17, using a chiral ligand protocol.

  17. Salan ligands assembled around chiral bipyrrolidine: predetermination of chirality around octahedral Ti and Zr centres.

    PubMed

    Sergeeva, Ekaterina; Kopilov, Jacob; Goldberg, Israel; Kol, Moshe

    2009-06-01

    The first synthesis of Salan ligands assembled around the chiral 2,2'-bipyrrolidine backbone is described; as chelation to a metal can only occur via specific faces of the two pyrrolidine nitrogens, these ligands lead to predetermined chirality at metal centres of octahedral titanium and zirconium complexes. PMID:19462084

  18. Vibrational circular dichroism from ab initio molecular dynamics and nuclear velocity perturbation theory in the liquid phase

    NASA Astrophysics Data System (ADS)

    Scherrer, Arne; Vuilleumier, Rodolphe; Sebastiani, Daniel

    2016-08-01

    We report the first fully ab initio calculation of dynamical vibrational circular dichroism spectra in the liquid phase using nuclear velocity perturbation theory (NVPT) derived electronic currents. Our approach is rigorous and general and thus capable of treating weak interactions of chiral molecules as, e.g., chirality transfer from a chiral molecule to an achiral solvent. We use an implementation of the NVPT that is projected along the dynamics to obtain the current and magnetic dipole moments required for accurate intensities. The gauge problem in the liquid phase is resolved in a twofold approach. The electronic expectation values are evaluated in a distributed origin gauge, employing maximally localized Wannier orbitals. In a second step, the gauge invariant spectrum is obtained in terms of a scaled molecular moments, which allows to systematically include solvent effects while keeping a significant signal-to-noise ratio. We give a thorough analysis and discussion of this choice of gauge for the liquid phase. At low temperatures, we recover the established double harmonic approximation. The methodology is applied to chiral molecules ((S)-d2-oxirane and (R)-propylene-oxide) in the gas phase and in solution. We find an excellent agreement with the theoretical and experimental references, including the emergence of signals due to chirality transfer from the solute to the (achiral) solvent.

  19. Vibrational circular dichroism from ab initio molecular dynamics and nuclear velocity perturbation theory in the liquid phase.

    PubMed

    Scherrer, Arne; Vuilleumier, Rodolphe; Sebastiani, Daniel

    2016-08-28

    We report the first fully ab initio calculation of dynamical vibrational circular dichroism spectra in the liquid phase using nuclear velocity perturbation theory (NVPT) derived electronic currents. Our approach is rigorous and general and thus capable of treating weak interactions of chiral molecules as, e.g., chirality transfer from a chiral molecule to an achiral solvent. We use an implementation of the NVPT that is projected along the dynamics to obtain the current and magnetic dipole moments required for accurate intensities. The gauge problem in the liquid phase is resolved in a twofold approach. The electronic expectation values are evaluated in a distributed origin gauge, employing maximally localized Wannier orbitals. In a second step, the gauge invariant spectrum is obtained in terms of a scaled molecular moments, which allows to systematically include solvent effects while keeping a significant signal-to-noise ratio. We give a thorough analysis and discussion of this choice of gauge for the liquid phase. At low temperatures, we recover the established double harmonic approximation. The methodology is applied to chiral molecules ((S)-d2-oxirane and (R)-propylene-oxide) in the gas phase and in solution. We find an excellent agreement with the theoretical and experimental references, including the emergence of signals due to chirality transfer from the solute to the (achiral) solvent. PMID:27586898

  20. The chiral magnetic effect and chiral symmetry breaking in SU(3) quenched lattice gauge theory

    SciTech Connect

    Braguta, V. V.; Buividovich, P. V. Kalaydzhyan, T. Kuznetsov, S. V. Polikarpov, M. I.

    2012-04-15

    We study some properties of the non-Abelian vacuum induced by strong external magnetic field. We perform calculations in the quenched SU(3) lattice gauge theory with tadpole-improved Luescher-Weisz action and chirally invariant lattice Dirac operator. The following results are obtained: The chiral symmetry breaking is enhanced by the magnetic field. The chiral condensate depends on the strength of the applied field as a power function with exponent {nu} = 1.6 {+-} 0.2. There is a paramagnetic polarization of the vacuum. The corresponding susceptibility and other magnetic properties are calculated and compared with the theoretical estimations. There are nonzero local fluctuations of the chirality and electromagnetic current, which grow with the magnetic field strength. These fluctuations can be a manifestation of the Chiral Magnetic Effect.

  1. Diastereoselective aziridination of chiral electron-deficient olefins with N-chloro-N-sodiocarbamates catalyzed by chiral quaternary ammonium salts.

    PubMed

    Murakami, Yuta; Takeda, Youhei; Minakata, Satoshi

    2011-08-01

    Chiral quaternary ammonium salt-catalyzed diastereoselective aziridination of electron-deficient olefins that possess a chiral auxiliary with N-chloro-N-sodiocarbamates was developed. The key to high stereoselectivity was found to be the employment of the "matching" stereochemical combination of chiral auxiliary/ammonium salt. For example, when 3-phenyl-(4R,7S)-4-methyl-7-isopropyl-4,5,6,7-tetrahydroindazole (L-menthopyrazole) as a chiral auxiliary and a cinchonidine-derived chiral ammonium salt as a catalyst were applied to the reaction system, perfect diastereoselectivity was realized. Furthermore, the preparation of enantiomerically pure aziridines by removal of the chiral auxiliary was demonstrated.

  2. Formation of Enhanced Uniform Chiral Fields in Symmetric Dimer Nanostructures

    PubMed Central

    Tian, Xiaorui; Fang, Yurui; Sun, Mengtao

    2015-01-01

    Chiral fields with large optical chirality are very important in chiral molecules analysis, sensing and other measurements. Plasmonic nanostructures have been proposed to realize such super chiral fields for enhancing weak chiral signals. However, most of them cannot provide uniform chiral near-fields close to the structures, which makes these nanostructures not so efficient for applications. Plasmonic helical nanostructures and blocked squares have been proved to provide uniform chiral near-fields, but structure fabrication is a challenge. In this paper, we show that very simple plasmonic dimer structures can provide uniform chiral fields in the gaps with large enhancement of both near electric fields and chiral fields under linearly polarized light illumination with polarization off the dimer axis at dipole resonance. An analytical dipole model is utilized to explain this behavior theoretically. 30 times of volume averaged chiral field enhancement is gotten in the whole gap. Chiral fields with opposite handedness can be obtained simply by changing the polarization to the other side of the dimer axis. It is especially useful in Raman optical activity measurement and chiral sensing of small quantity of chiral molecule. PMID:26621558

  3. Symmetry, Structure, and Dynamics of Monoaxial Chiral Magnets

    NASA Astrophysics Data System (ADS)

    Togawa, Yoshihiko; Kousaka, Yusuke; Inoue, Katsuya; Kishine, Jun-ichiro

    2016-11-01

    Nontrivial spin orders with magnetic chirality emerge in a particular class of magnetic materials with structural chirality, which are frequently referred to as chiral magnets. Various interesting physical properties are expected to be induced in chiral magnets through the coupling of chiral magnetic orders with conduction electrons and electromagnetic fields. One promising candidate for achieving these couplings is a chiral spin soliton lattice. Here, we review recent experimental observations mainly carried out on the monoaxial chiral magnetic crystal CrNb3S6 via magnetic imaging using electron, neutron, and X-ray beams and magnetoresistance measurements, together with the strategy for synthesizing chiral magnetic materials and underlying theoretical backgrounds. The chiral soliton lattice appears under a magnetic field perpendicular to the chiral helical axis and is very robust and stable with phase coherence on a macroscopic length scale. The tunable and topological nature of the chiral soliton lattice gives rise to nontrivial physical properties. Indeed, it is demonstrated that the interlayer magnetoresistance scales to the soliton density, which plays an essential role as an order parameter in chiral soliton lattice formation, and becomes quantized with the reduction of the system size. These interesting features arising from macroscopic phase coherence unique to the chiral soliton lattice will lead to the exploration of routes to a new paradigm for applications in spin electronics using spin phase coherence.

  4. B- and D-meson decay constants from three-flavor lattice QCD

    SciTech Connect

    Bazavov, A.; et al.

    2012-06-01

    We calculate the leptonic decay constants of B_{(s)} and D_{(s)} mesons in lattice QCD using staggered light quarks and Fermilab bottom and charm quarks. We compute the heavy-light meson correlation functions on the MILC asqtad-improved staggered gauge configurations which include the effects of three light dynamical sea quarks. We simulate with several values of the light valence- and sea-quark masses (down to ~m_s/10) and at three lattice spacings (a ~ 0.15, 0.12, and 0.09 fm) and extrapolate to the physical up and down quark masses and the continuum using expressions derived in heavy-light meson staggered chiral perturbation theory. We renormalize the heavy-light axial current using a mostly nonperturbative method such that only a small correction to unity must be computed in lattice perturbation theory and higher-order terms are expected to be small. We obtain f_{B^+} = 196.9(8.9) MeV, f_{B_s} = 242.0(9.5) MeV, f_{D^+} = 218.9(11.3) MeV, f_{D_s} = 260.1(10.8) MeV, and the SU(3) flavor-breaking ratios f_{B_s}/f_{B} = 1.229(26) and f_{D_s}/f_{D} = 1.188(25), where the numbers in parentheses are the total statistical and systematic uncertainties added in quadrature.

  5. Chiral dynamics and peripheral transverse densities

    SciTech Connect

    Granados, Carlos G.; Weiss, Christian

    2014-01-01

    In the partonic (or light-front) description of relativistic systems the electromagnetic form factors are expressed in terms of frame-independent charge and magnetization densities in transverse space. This formulation allows one to identify the chiral components of nucleon structure as the peripheral densities at transverse distances b = O(M{sub {pi}}{sup -1}) and compute them in a parametrically controlled manner. A dispersion relation connects the large-distance behavior of the transverse charge and magnetization densities to the spectral functions of the Dirac and Pauli form factors near the two--pion threshold at timelike t = 4 M{ sub {pi}}{sup 2}, which can be computed in relativistic chiral effective field theory. Using the leading-order approximation we (a) derive the asymptotic behavior (Yukawa tail) of the isovector transverse densities in the "chiral" region b = O(M{sub {pi}}{sup -1}) and the "molecular" region b = O(M{sub N}{sup 2}/M{sub {pi}}{sup 3}); (b) perform the heavy-baryon expansion of the transverse densities; (c) explain the relative magnitude of the peripheral charge and magnetization densities in a simple mechanical picture; (d) include Delta isobar intermediate states and study the peripheral transverse densities in the large-N{ sub c} limit of QCD; (e) quantify the region of transverse distances where the chiral components of the densities are numerically dominant; (f) calculate the chiral divergences of the b{sup 2}-weighted moments of the isovector transverse densities (charge and anomalous magnetic radii) in the limit M{sub {pi}} -> 0 and determine their spatial support. Our approach provides a concise formulation of the spatial structure of the nucleon's chiral component and offers new insights into basic properties of the chiral expansion. It relates the information extracted from low-t elastic form factors to the generalized parton distributions probed in peripheral high-energy scattering processes.

  6. Base case and perturbation scenarios

    SciTech Connect

    Edmunds, T

    1998-10-01

    This report describes fourteen energy factors that could affect electricity markets in the future (demand, process, source mix, etc.). These fourteen factors are believed to have the most influence on the State's energy environment. A base case, or most probable, characterization is given for each of these fourteen factors over a twenty year time horizon. The base case characterization is derived from quantitative and qualitative information provided by State of California government agencies, where possible. Federal government databases are nsed where needed to supplement the California data. It is envisioned that a initial selection of issue areas will be based upon an evaluation of them under base case conditions. For most of the fourteen factors, the report identities possible perturbations from base case values or assumptions that may be used to construct additional scenarios. Only those perturbations that are plausible and would have a significant effect on energy markets are included in the table. The fourteen factors and potential perturbations of the factors are listed in Table 1.1. These perturbations can be combined to generate internally consist.ent. combinations of perturbations relative to the base case. For example, a low natural gas price perturbation should be combined with a high natural gas demand perturbation. The factor perturbations are based upon alternative quantitative forecasts provided by other institutions (the Department of Energy - Energy Information Administration in some cases), changes in assumptions that drive the quantitative forecasts, or changes in assumptions about the structure of the California energy markets. The perturbations are intended to be used for a qualitative reexamination of issue areas after an initial evaluation under the base case. The perturbation information would be used as a "tiebreaker;" to make decisions regarding those issue areas that were marginally accepted or rejected under the base case. Hf a

  7. Identification of perturbation modes and controversies in ekpyrotic perturbations

    NASA Astrophysics Data System (ADS)

    Hwang, Jai-Chan; Noh, Hyerim

    2002-10-01

    If the linear perturbation theory is valid through the bounce, the surviving fluctuations from the ekpyrotic scenario (cyclic one as well) should have very blue spectra with suppressed amplitude for the scalar-type structure. We derive the same (and consistent) result using the curvature perturbation in the uniform-field (comoving) gauge and in the zero-shear gauge. Previously, Khoury et al. interpreted results from the latter gauge condition incorrectly and claimed the scale-invariant spectrum, thus generating controversy in the literature. We also correct similar errors in the literature based on wrong mode identification and joining condition. No joining condition is needed for the derivation.

  8. Consistency of the {pi}{delta} interaction in chiral perturbation theory

    SciTech Connect

    Wies, N.; Scherer, S.; Gegelia, J.

    2006-05-01

    We analyze the constraint structure of a spin-3/2 particle interacting with a pseudoscalar. Requiring the self consistency of the considered effective field theory imposes restrictions on the possible interaction terms. In the present case we derive two constraints among the three lowest-order {pi}{delta} interaction terms. From these constraints we find that the total Lagrangian is invariant under the so-called point transformation. On the other hand, demanding the invariance under the point transformation alone is less stringent and produces only classes of relations among the coupling constants.

  9. Improved Measure of Local Chirality

    SciTech Connect

    Terrence Draper; Andrei Alexandru; Ying Chen; Shao-Jing Dong; Ivan Horvath; Frank Lee; Nilmani Mathur; Harry B. Thacker; Sonali Tamhankar; Jianbo Zhang

    2004-06-01

    It is popular to probe the structure of the QCD vacuum indirectly by studying individual fermion eigenmodes, because this provides a natural way to filter out UV fluctuations. The double-peaking in the distribution of the local chiral orientation parameter (X) has been offered as evidence, by some, in support of a particular model of the vacuum. Here we caution that the X-distribution peaking varies significantly with various versions of the definition of X. Furthermore, each distribution varies little from that resulting from a random reshuffling of the left-handed (and independently the right-handed) fields, which destroys any QCD-induced left-right correlation; that is, the double-peaking is mostly a phase-space effect. We propose a new universal definition of the X parameter whose distribution is uniform for randomly reshuffled fields. Any deviations from uniformity for actual data can then be directly attributable to QCD-induced dynamics. We find that the familiar double peak disappears.

  10. Resurgence in quantum field theory: nonperturbative effects in the principal chiral model.

    PubMed

    Cherman, Aleksey; Dorigoni, Daniele; Dunne, Gerald V; Ünsal, Mithat

    2014-01-17

    We explain the physical role of nonperturbative saddle points of path integrals in theories without instantons, using the example of the asymptotically free two-dimensional principal chiral model (PCM). Standard topological arguments based on homotopy considerations suggest no role for nonperturbative saddles in such theories. However, the resurgence theory, which unifies perturbative and nonperturbative physics, predicts the existence of several types of nonperturbative saddles associated with features of the large-order structure of the perturbation theory. These points are illustrated in the PCM, where we find new nonperturbative "fracton" saddle point field configurations, and suggest a quantum interpretation of previously discovered "uniton" unstable classical solutions. The fractons lead to a semiclassical realization of IR renormalons in the circle-compactified theory and yield the microscopic mechanism of the mass gap of the PCM.

  11. The synthesis and structure of chiral enamine N-oxides.

    PubMed

    O'Neil, I A; McConville, M; Zhou, K; Brooke, C; Robertson, C M; Berry, N G

    2014-07-14

    Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.

  12. Macroscopic chirality of a liquid crystal from nonchiral molecules

    SciTech Connect

    Jakli, A.; Nair, G. G.; Lee, C. K.; Sun, R.; Chien, L. C.

    2001-06-01

    The transfer of chirality from nonchiral polymer networks to the racemic B2 phase of nonchiral banana-shaped molecules is demonstrated. This corresponds to the transfer of chirality from an achiral material to another achiral material. There are two levels of chirality transfers. (a) On a microscopic level the presence of a polymer network (chiral or nonchiral) favors a chiral state over a thermodynamically stable racemic state due to the inversion symmetry breaking at the polymer-liquid crystal interfaces. (b) A macroscopically chiral (enantimerically enriched) sample can be produced if the polymer network has a helical structure, and/or contains chemically chiral groups. The chirality transfer can be locally suppressed by exposing the liquid crystal to a strong electric field treatment.

  13. METHODS DEVELOPMENT FOR THE ANALYSIS OF CHIRAL PESTICIDES

    EPA Science Inventory

    Chiral compounds exist as a pair of nonsuperimposable mirror images called enantiomers. Enantiomers have identical physical-chemical properties, but their interactions with other chiral molecules, toxicity, biodegradation, and fate are often different. Many pharmaceutical com...

  14. Chiral heteropoly blues and controllable switching of achiral polyoxometalate clusters.

    PubMed

    Wang, Yizhan; Li, Haolong; Wu, Che; Yang, Yang; Shi, Lei; Wu, Lixin

    2013-04-22

    Managing the blues: Chiral heteropoly blues of achiral polyoxometalate clusters were created through an intermolecular interaction with a chiral organic compound. Controllable chiroptical switching of the cluster complexes was possible through reversible photochromism of the polyoxometalates (see picture).

  15. PESTICIDE EXPOSURE AND CHIRAL CHEMISTRY: THE PYRETHROID FAMILY

    EPA Science Inventory

    Advances in chiral chromatography significantly advanced the ability to analyze individual enantiomers of chiral compounds. These techniques are being employed at the U.S. EPA for human exposure and ecological research studies. Enantiomer fractions (EFs) were measured for cisp...

  16. Jet Perturbation by HE target

    SciTech Connect

    Poulsen, P; Kuklo, R M

    2001-03-01

    We have previously reported the degree of attenuation and perturbation by a Cu jet passing through Comp B explosive. Similar tests have now been performed with high explosive (HE) targets having CJ pressures higher than and lower than the CJ pressure of Comp B. The explosives were LX-14 and TNT, respectively. We found that the measured exit velocity of the jet where it transitions from perturbed to solid did not vary significantly as a function of HE type for each HE thickness. The radial momentum imparted to the perturbed jet segment did vary as a function of HE type, however, and we report the radial spreading of the jet and the penetration of a downstream target as a function of HE type and thickness.

  17. On the chiral imbalance and Weibel instabilities

    NASA Astrophysics Data System (ADS)

    Kumar, Avdhesh; Bhatt, Jitesh R.; Kaw, P. K.

    2016-06-01

    We study the chiral-imbalance and the Weibel instabilities in presence of the quantum anomaly using the Berry-curvature modified kinetic equation. We argue that in many realistic situations, e.g. relativistic heavy-ion collisions, both the instabilities can occur simultaneously. The Weibel instability depends on the momentum anisotropy parameter ξ and the angle (θn) between the propagation vector and the anisotropy direction. It has maximum growth rate at θn = 0 while θn = π / 2 corresponds to a damping. On the other hand the pure chiral-imbalance instability occurs in an isotropic plasma and depends on difference between the chiral chemical potentials of right and left-handed particles. It is shown that when θn = 0, only for a very small values of the anisotropic parameter ξ ∼ξc, growth rates of the both instabilities are comparable. For the cases ξc < ξ ≪ 1 or ξ ≳ 1 at θn = 0, the Weibel modes dominate over the chiral-imbalance instability if μ5 / T ≤ 1. However, when μ5 / T ≥ 1, it is possible to have dominance of the chiral-imbalance modes at certain values of θn for an arbitrary ξ.

  18. Chirality dependent spin polarization of carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Wang, Jia; Jiang, Wanrun; Wang, Bo; Gao, Yang; Wang, Zhigang; Zhang, Rui-Qin

    2016-02-01

    The spin polarization of carbon nanotubes (CNTs) offers a tunable building block for spintronic devices and is also crucial for realizing carbon-based electronics. However, the effect of chiral CNTs is still unclear. In this paper, we use the density functional theory (DFT) method to investigate the spin polarization of a series of typical finite-length chiral CNTs (9, m). The results show that the spin density of chiral CNTs (9, m) decreases gradually with the increase in m and vanishes altogether when m is larger than or equal to 6. The armchair edge units on both ends of the (9, m) CNTs exhibit a clear inhibition of spin polarization, allowing control of the spin density of (9, m) CNTs by adjusting the number of armchair edge units on the tube end. Furthermore, analysis of the orbitals shows that the spin of the ground state for (9, m) CNTs mainly comes from the contributions of the frontier molecular orbitals (MOs), and the energy gap decreases gradually with the spin density for chiral CNTs. Our work further develops the study of the spin polarization of CNTs and provides a strategy for controlling the spin polarization of functional molecular devices through chiral vector adjustment.

  19. Ratchet transport powered by chiral active particles

    PubMed Central

    Ai, Bao-quan

    2016-01-01

    We numerically investigate the ratchet transport of mixtures of active and passive particles in a transversal asymmetric channel. A big passive particle is immersed in a ‘sea’ of active particles. Due to the chirality of active particles, the longitudinal directed transport is induced by the transversal asymmetry. For the active particles, the chirality completely determines the direction of the ratchet transport, the counterclockwise and clockwise particles move to the opposite directions and can be separated. However, for the passive particle, the transport behavior becomes complicated, the direction is determined by competitions among the chirality, the self-propulsion speed, and the packing fraction. Interestingly, within certain parameters, the passive particle moves to the left, while active particles move to the right. In addition, there exist optimal parameters (the chirality, the height of the barrier, the self-propulsion speed and the packing fraction) at which the rectified efficiency takes its maximal value. Our findings could be used for the experimental pursuit of the ratchet transport powered by chiral active particles. PMID:26795952

  20. A liquid crystalline chirality balance for vapours

    PubMed Central

    Ohzono, Takuya; Yamamoto, Takahiro; Fukuda, Jun-ichi

    2014-01-01

    Chiral discrimination of vapours plays an important role in olfactory perception of biological systems and its realization by artificial sensors has been an intriguing challenge. Here, we report a simple method that tangibly visualizes the chirality of a diverse variety of molecules dissolved from vapours with high sensitivity, by making use of a structural change in a periodic microstructure of a nematic liquid crystal confined in open microchannels. This microstructure is accompanied by a topological line defect of a zigzag form with equal lengths of ‘zig’ and ‘zag.’ We find that a tiny amount of vapour of chiral molecules injected onto the liquid crystal induces the imbalance of ‘zig’ and ‘zag’ depending on its enantiomeric excess within a few seconds. Our liquid-crystal-based ‘chirality balance’ offers a simple, quick and versatile chirality-sensing/-screening method for gas-phase analysis (for example, for odours, environmental chemicals or drugs). PMID:24781531

  1. Ratchet transport powered by chiral active particles.

    PubMed

    Ai, Bao-quan

    2016-01-01

    We numerically investigate the ratchet transport of mixtures of active and passive particles in a transversal asymmetric channel. A big passive particle is immersed in a 'sea' of active particles. Due to the chirality of active particles, the longitudinal directed transport is induced by the transversal asymmetry. For the active particles, the chirality completely determines the direction of the ratchet transport, the counterclockwise and clockwise particles move to the opposite directions and can be separated. However, for the passive particle, the transport behavior becomes complicated, the direction is determined by competitions among the chirality, the self-propulsion speed, and the packing fraction. Interestingly, within certain parameters, the passive particle moves to the left, while active particles move to the right. In addition, there exist optimal parameters (the chirality, the height of the barrier, the self-propulsion speed and the packing fraction) at which the rectified efficiency takes its maximal value. Our findings could be used for the experimental pursuit of the ratchet transport powered by chiral active particles.

  2. Effects of copper ions on DNA binding and cytotoxic activity of a chiral salicylidene Schiff base.

    PubMed

    Fei, Bao-Li; Xu, Wu-Shuang; Tao, Hui-Wen; Li, Wen; Zhang, Yu; Long, Jian-Ying; Liu, Qing-Bo; Xia, Bing; Sun, Wei-Yin

    2014-03-01

    A chiral Schiff base HL N-(5-bromo-salicylaldehyde)dehydroabietylamine (1) and its chiral dinuclear copper complex [Cu2L4]·4DMF (2) have been synthesized and fully characterized. The interactions of 1 and 2 with salmon sperm DNA have been investigated by viscosity measurements, UV, fluorescence and circular dichroism (CD) spectroscopic techniques. Absorption spectral (Kb=3.30 × 10(5)M(-)(1) (1), 6.63 × 10(5)M(-)(1)(2)), emission spectral (Ksv=7.58 × 10(3)M(-)(1) (1), 1.52 × 10(4)M(-)(1) (2)), and viscosity measurements reveal that 1 and 2 interact with DNA through intercalation and 2 exhibits a higher DNA binding ability. In addition, CD study indicates 2 cause a more evident perturbation on the base stacking and helicity of B-DNA upon binding to it. In fluorimetric studies, the enthalpy (ΔH>0) and entropy (ΔS>0) changes of the reactions between the compounds with DNA demonstrate hydrophobic interactions. 1 and 2 were also screened for their cytotoxic ability and 2 demonstrates higher growth inhibition of the selected cancer cells at concentration of 50 μM, this result is identical with their DNA binding ability order. All the experimental results show that the involvement of Cu (II) centers has some interesting effect on DNA binding ability and cytotoxicity of the chiral Schiff base.

  3. Chiral representation of the πN scattering amplitude and the pion-nucleon sigma term

    NASA Astrophysics Data System (ADS)

    Alarcón, J. M.; Camalich, J. Martin; Oller, J. A.

    2012-03-01

    We present a novel analysis of the πN scattering amplitude in Lorentz covariant baryon chiral perturbation theory renormalized in the extended-on-mass-shell scheme. This amplitude, valid up to O(p3) in the chiral expansion, systematically includes the effects of the Δ(1232) in the δ-counting, has the right analytic properties, and is renormalization-scale independent. This approach overcomes the limitations that previous chiral analyses of the πN scattering amplitude had, providing an accurate description of the partial wave phase shifts of the Karlsruhe-Helsinki and George-Washington groups up to energies just below the resonance region. We also study the solution of the Matsinos group which focuses on the parameterization of the data at low energies. Once the values of the low-energy constants are determined by adjusting the center-of-mass energy dependence of the amplitude to the scattering data, we obtain predictions on different observables. In particular, we extract an accurate value for the pion-nucleon sigma term, σπN. This allows us to avoid the usual method of extrapolation to the unphysical region of the amplitude. Our study indicates that the inclusion of modern meson-factory and pionic-atom data favors relatively large values of the sigma term. We report the value σπN=59(7)MeV and comment on implications that this result may have.

  4. Perturbation theory in thermosphere dynamics

    NASA Technical Reports Server (NTRS)

    Mayr, H. G.; Volland, H.

    1976-01-01

    It is shown that density and pressure throughout the thermosphere can be adequately described in a logarithmic expansion that provides a sound basis for the application of perturbation theory. This expansion eliminates most of the important nonlinearities associated with density variations. On the basis of this expansion, the validity of perturbation theory can be extended to cover a large variety of atmospheric conditions in which the relative temperature amplitude is less than 0.5 and wind velocities are significantly less than the speed of sound.

  5. Acylation of Chiral Alcohols: A Simple Procedure for Chiral GC Analysis

    PubMed Central

    Oromí-Farrús, Mireia; Torres, Mercè; Canela, Ramon

    2012-01-01

    The use of iodine as a catalyst and either acetic or trifluoroacetic acid as a derivatizing reagent for determining the enantiomeric composition of acyclic and cyclic aliphatic chiral alcohols was investigated. Optimal conditions were selected according to the molar ratio of alcohol to acid, the reaction time, and the reaction temperature. Afterwards, chiral stability of chiral carbons was studied. Although no isomerization was observed when acetic acid was used, partial isomerization was detected with the trifluoroacetic acid. A series of chiral alcohols of a widely varying structural type were then derivatized with acetic acid using the optimal conditions. The resolution of the enantiomeric esters and the free chiral alcohols was measured using a capillary gas chromatograph equipped with a CP Chirasil-DEX CB column. The best resolutions were obtained with 2-pentyl acetates (α = 3.00) and 2-hexyl acetates (α = 1.95). This method provides a very simple and efficient experimental workup procedure for analyzing chiral alcohols by chiral-phase GC. PMID:22649749

  6. Chirality Change by Grinding Crystals in Solution

    NASA Astrophysics Data System (ADS)

    Viedma, Cristobal

    2010-07-01

    One of the greatest unsolved problems in chemistry is the origin of homochirality in the biosphere, that is, the fact that l-amino acids and d-sugars dominate in biology, while laboratory experiments with stereoselective reactions only produce racemic mixtures. Several models have been proposed to address the question of how enantiomerically pure solutions or crystalline phases could have emerged from a presumably racemic prebiotic world. Here we show that two populations of amino acid crystals of "left" and "right" hand cannot coexist in solution: one of the chiral populations disappears in an irreversible autocatalytic process that nurtures the other one. Final and complete chiral purity seems to be an inexorable fate in our systems, under grinding, in the course of the common process of growth-dissolution. This unexpected chiral symmetry breaking has become firmly established but the underlying mechanism is being debated and we have no definitive answer.

  7. Chirality Change by Grinding Crystals in Solution

    SciTech Connect

    Viedma, Cristobal

    2010-07-22

    One of the greatest unsolved problems in chemistry is the origin of homochirality in the biosphere, that is, the fact that l-amino acids and d-sugars dominate in biology, while laboratory experiments with stereoselective reactions only produce racemic mixtures. Several models have been proposed to address the question of how enantiomerically pure solutions or crystalline phases could have emerged from a presumably racemic prebiotic world. Here we show that two populations of amino acid crystals of 'left' and 'right' hand cannot coexist in solution: one of the chiral populations disappears in an irreversible autocatalytic process that nurtures the other one. Final and complete chiral purity seems to be an inexorable fate in our systems, under grinding, in the course of the common process of growth-dissolution. This unexpected chiral symmetry breaking has become firmly established but the underlying mechanism is being debated and we have no definitive answer.

  8. A semiclassical formulation of the chiral magnetic effect and chiral anomaly in even d + 1 dimensions

    NASA Astrophysics Data System (ADS)

    Dayi, Ömer F.; Elbistan, Mahmut

    2016-05-01

    In terms of the matrix valued Berry gauge field strength for the Weyl Hamiltonian in any even space-time dimensions a symplectic form whose elements are matrices in spin indices is introduced. Definition of the volume form is modified appropriately. A simple method of finding the path integral measure and the chiral current in the presence of external electromagnetic fields is presented. It is shown that within this new approach the chiral magnetic effect as well as the chiral anomaly in even d + 1 dimensions are accomplished straightforwardly.

  9. Chiral Molecules Revisited by Broadband Microwave Spectroscopy

    NASA Astrophysics Data System (ADS)

    Schnell, Melanie

    2014-06-01

    Chiral molecules have fascinated chemists for more than 150 years. While their physical properties are to a very good approximation identical, the two enantiomers of a chiral molecule can have completely different (bio)chemical activities. For example, the right-handed enantiomer of carvone smells of spearmint while the left-handed one smells of caraway. In addition, the active components of many drugs are of one specific handedness, such as in the case of ibuprofen. However, in nature as well as in pharmaceutical applications, chiral molecules often exist in mixtures with other chiral molecules. The analysis of these complex mixtures to identify the molecular components, to determine which enantiomers are present, and to measure the enantiomeric excesses (ee) remains a challenging task for analytical chemistry, despite its importance for modern drug development. We present here a new method of differentiating enantiomers of chiral molecules in the gas phase based on broadband rotational spectroscopy. The phase of the acquired signal bares the signature of the enantiomer, as it depends upon the combined quantity, μ_a μ_b μ_c, which is of opposite sign between enantiomers. It thus also provides information on the absolute configuration of the particular enantiomer. Furthermore, the signal amplitude is proportional to the ee. A significant advantage of our technique is its inherent mixture compatibility due to the fingerprint-like character of rotational spectra. In this contribution, we will introduce the technique and present our latest results on chiral molecule spectroscopy and enantiomer differentiation. D. Patterson, M. Schnell, J.M. Doyle, Nature 497 (2013) 475-477 V.A. Shubert, D. Schmitz, D. Patterson, J.M. Doyle, M. Schnell, Angewandte Chemie International Edition 53 (2014) 1152-1155

  10. Chirality: a blueprint for the future.

    PubMed

    Burke, D; Henderson, D J

    2002-04-01

    The chirality that is inherent in the enzyme systems of living organisms results in an abundance of enantiopure organic molecules in the living world. In addition to the optical properties first noticed by Pasteur, stereospecific interactions at recognition sites result in differences in both biological and toxicological effects. This fact underlies the continuing growth in chiral chemistry, rooted as it is in fundamental biochemistry. The pharmaceutical industry has undergone a strategic shift and embraced the wide spectrum of asymmetrical synthetic methods now available. The use of these processes in developmental synthesis and large-scale manufacturing has provided new challenges in drug discovery, motivated by a desire to improve industrial efficacy and decrease the time from the conception of a new drug to the market. The economic impact of the industrial production of chiral drugs is now huge--more than 50% of the 500 top-selling drugs were single-enantiomers in 1997. Sales have continued to increase by more than 20% for the past 6 yr and worldwide annual sales of enantiomeric drugs exceeded US$100 billion for the first time in the year 2000, chiral drugs representing close to one-third of all sales worldwide. While some 'chiral switches' may be of less apparent benefit, or indeed detrimental in some cases, encouragement by the regulatory agencies and the ability to extend the life cycle of a drug coming off patent promotes the trend. However, it may turn out to be the ability to provide chiral templates, and thereby attack the key targets of selectivity and specificity, that will lead to the greatest benefits. Research into new chemical entities that can interact specifically with enzyme families may potentially lead to new therapies for complex disease processes. As Richards has stated, the approach is designed to create a made to measure product, rather than one off the peg.

  11. Matter perturbations in Galileon cosmology

    SciTech Connect

    De Felice, Antonio; Kase, Ryotaro; Tsujikawa, Shinji

    2011-02-15

    We study the evolution of matter density perturbations in Galileon cosmology where the late-time cosmic acceleration can be realized by a field kinetic energy. We obtain full perturbation equations at linear order in the presence of five covariant Lagrangians L{sub i} (i=1,{center_dot}{center_dot}{center_dot},5) satisfying the Galileon symmetry {partial_derivative}{sub {mu}}{phi}{yields}{partial_derivative}{sub {mu}}{phi}{sup +}b{sub {mu}} in the flat space-time. The equations for a matter perturbation as well as an effective gravitational potential are derived under a quasistatic approximation on subhorizon scales. This approximation can reproduce full numerical solutions with high accuracy for the wavelengths relevant to large-scale structures. For the model parameters constrained by the background expansion history of the Universe, the growth rate of matter perturbations is larger than that in the {Lambda}-cold dark matter model, with the growth index {gamma} today typically smaller than 0.4. We also find that, even on very large scales associated with the integrated-Sachs-Wolfe effect in cosmic microwave background temperature anisotropies, the effective gravitational potential exhibits a temporal growth during the transition from the matter era to the epoch of cosmic acceleration. These properties are useful to distinguish the Galileon model from the {Lambda}-cold dark matter model in future high-precision observations.

  12. Disformal invariance of curvature perturbation

    NASA Astrophysics Data System (ADS)

    Motohashi, Hayato; White, Jonathan

    2016-02-01

    We show that under a general disformal transformation the linear comoving curvature perturbation is not identically invariant, but is invariant on superhorizon scales for any theory that is disformally related to Horndeski's theory. The difference between disformally related curvature perturbations is found to be given in terms of the comoving density perturbation associated with a single canonical scalar field. In General Relativity it is well-known that this quantity vanishes on superhorizon scales through the Poisson equation that is obtained on combining the Hamiltonian and momentum constraints, and we confirm that a similar result holds for any theory that is disformally related to Horndeski's scalar-tensor theory so long as the invertibility condition for the disformal transformation is satisfied. We also consider the curvature perturbation at full nonlinear order in the unitary gauge, and find that it is invariant under a general disformal transformation if we assume that an attractor regime has been reached. Finally, we also discuss the counting of degrees of freedom in theories disformally related to Horndeski's.

  13. VHS Movies: Perturbations for Morphogenesis.

    ERIC Educational Resources Information Center

    Holmes, Danny L.

    This paper discusses the concept of a family system in terms of an interactive system of interrelated, interdependent parts and suggests that VHS movies can act as perturbations, i.e., change promoting agents, for certain dysfunctional family systems. Several distinct characteristics of a family system are defined with particular emphasis on…

  14. Adaptation Strategies in Perturbed /s/

    ERIC Educational Resources Information Center

    Brunner, Jana; Hoole, Phil; Perrier, Pascal

    2011-01-01

    The purpose of this work is to investigate the role of three articulatory parameters (tongue position, jaw position and tongue grooving) in the production of /s/. Six normal speakers' speech was perturbed by a palatal prosthesis. The fricative was recorded acoustically and through electromagnetic articulography in four conditions: (1) unperturbed,…

  15. Basics of QCD perturbation theory

    SciTech Connect

    Soper, D.E.

    1997-06-01

    This is an introduction to the use of QCD perturbation theory, emphasizing generic features of the theory that enable one to separate short-time and long-time effects. The author also covers some important classes of applications: electron-positron annihilation to hadrons, deeply inelastic scattering, and hard processes in hadron-hadron collisions. 31 refs., 38 figs.

  16. Seven topics in perturbative QCD

    SciTech Connect

    Buras, A.J.

    1980-09-01

    The following topics of perturbative QCD are discussed: (1) deep inelastic scattering; (2) higher order corrections to e/sup +/e/sup -/ annihilation, to photon structure functions and to quarkonia decays; (3) higher order corrections to fragmentation functions and to various semi-inclusive processes; (4) higher twist contributions; (5) exclusive processes; (6) transverse momentum effects; (7) jet and photon physics.

  17. PERTURBATION APPROACH FOR QUANTUM COMPUTATION

    SciTech Connect

    G. P. BERMAN; D. I. KAMENEV; V. I. TSIFRINOVICH

    2001-04-01

    We discuss how to simulate errors in the implementation of simple quantum logic operations in a nuclear spin quantum computer with many qubits, using radio-frequency pulses. We verify our perturbation approach using the exact solutions for relatively small (L = 10) number of qubits.

  18. CHIRAL LIMIT AND LIGHT QUARK MASSES IN 2+1 FLAVOR DOMAIN WALL QCD.

    SciTech Connect

    SCHOLZ,E.; LIN, M.

    2007-07-30

    We present results for meson masses and decay constants measured on 24{sup 3} x 64 lattices using the domain wall fermion formulation with an extension of the fifth dimension of L{sub s} = 16 for N{sub f} 2 + 1 dynamical quark flavors. The lightest dynamical meson mass in our set-up is around 331MeV. while partially quenched mesons reach masses as low as 250MeV. The applicability of SU(3) x SU(3) and SU(2) x SU(2) (partially quenched) chiral perturbation theory will be compared and we quote values for the low-energy constants from both approaches. We will extract the average light quark and strange quark masses and use a non-perturbative renormalization technique (RI/MOM) to quote their physical values. The pion and kaon decay constants are determined at those values from our chiral fits and their ratio is used to obtain the CKM-matrix element |V{sub us}|. The results presented here include statistical errors only.

  19. Probing Chiral Interactions in Light Nuclei

    SciTech Connect

    Nogga, A; Barrett, B R; Meissner, U; Witala, H; Epelbaum, E; Kamada, H; Navratil, P; Glockle, W; Vary, J P

    2004-01-08

    Chiral two- and three-nucleon interactions are studied in a few-nucleon systems. We investigate the cut-off dependence and convergence with respect to the chiral expansion. It is pointed out that the spectra of light nuclei are sensitive to the three-nucleon force structure. As an example, we present calculations of the 1{sup +} and 3{sup +} states of {sup 6}Li using the no-core shell model approach. The results show contributions of the next-to-next-to-leading order terms to the spectra, which are not correlated to the three-nucleon binding energy prediction.

  20. Chiral thermoelectrics with quantum Hall edge states.

    PubMed

    Sánchez, Rafael; Sothmann, Björn; Jordan, Andrew N

    2015-04-10

    The thermoelectric properties of a three-terminal quantum Hall conductor are investigated. We identify a contribution to the thermoelectric response that relies on the chirality of the carrier motion rather than on spatial asymmetries. The Onsager matrix becomes maximally asymmetric with configurations where either the Seebeck or the Peltier coefficients are zero while the other one remains finite. Reversing the magnetic field direction exchanges these effects, which originate from the chiral nature of the quantum Hall edge states. The possibility to generate spin-polarized currents in quantum spin Hall samples is discussed. PMID:25910147

  1. Chiral Thermoelectrics with Quantum Hall Edge States

    NASA Astrophysics Data System (ADS)

    Sánchez, Rafael; Sothmann, Björn; Jordan, Andrew N.

    2015-04-01

    The thermoelectric properties of a three-terminal quantum Hall conductor are investigated. We identify a contribution to the thermoelectric response that relies on the chirality of the carrier motion rather than on spatial asymmetries. The Onsager matrix becomes maximally asymmetric with configurations where either the Seebeck or the Peltier coefficients are zero while the other one remains finite. Reversing the magnetic field direction exchanges these effects, which originate from the chiral nature of the quantum Hall edge states. The possibility to generate spin-polarized currents in quantum spin Hall samples is discussed.

  2. Asymmetric petasis reactions catalyzed by chiral biphenols.

    PubMed

    Lou, Sha; Schaus, Scott E

    2008-06-01

    Chiral biphenols catalyze the enantioselective Petasis reaction of alkenyl boronates, secondary amines, and ethyl glyoxylate. The reaction requires the use of 15 mol % of (S)-VAPOL as the catalyst, alkenyl boronates as nucleophiles, ethyl glyoxylate as the aldehyde component, and 3 A molecular sieves as an additive. The chiral alpha-amino ester products are obtained in good yields (71-92%) and high enantiomeric ratios (89:11-98:2). Mechanistic investigations indicate single ligand exchange of acyclic boronate with VAPOL and tetracoordinate boronate intermediates. PMID:18459782

  3. Consistent Two-Dimensional Chiral Gravity

    NASA Astrophysics Data System (ADS)

    Smailagic, A.; Spallucci, E.

    We study chiral induced gravity in the light-cone gauge and show that the theory is consistent for a particular choice of chiralities. The corresponding Kac-Moody central charge has no forbidden region of complex values. Generalized analysis of the critical exponents is given and their relation to the SL(2,R) vacuum states is elucidated. All the parameters containing information about the theory can be traced back to the characteristics of the residual symmetry group in the light-cone gauge.

  4. Chirality, quantum mechanics, and biological determinism

    NASA Astrophysics Data System (ADS)

    Davies, P. C. W.

    2006-08-01

    The holy grail of astrobiology is the discovery of a second sample of life that has emerged de novo, independently of life on Earth (as opposed to extraterrestrial life that shares a common origin with terrestrial life via a panspermia process). It would then be possible to separate aspects of biology that are lawlike and expected from those that are accidental and contingent, and thus to address the question of whether the laws of nature are intrinsically bio-friendly. The popular assumption that life is an almost inevitable product of physics and chemistry, and therefore widespread in the universe, is known as biological determinism. It remains an open question whether biological determinism is correct, as there is little direct evidence in its favour from fundamental physics. Homochirality is a deep property of known life, and provides an important test case for the competing ideas of contingency versus lawfulness - or chance versus necessity. Conceivably, a chiral signature is imprinted on life by fundamental physics via parity-violating mixing of the weak and electromagnetic interactions. If so, homochirality would be universal and lawlike. On the other hand, it may be the result of chance: a random molecular accident during the pre-biotic phase. If the latter explanation is correct, one could expect that a second sample of life may have opposite chiral signature even if it resembled known life in its basic biochemistry. There is thus a curious obverse relationship between chirality and biogenesis in relation to biological determinism. If the chiral signature of life is the product of chance, we may hope to discover "mirror life" (i.e. organisms with opposite chiral signature) as evidence of a second genesis, and the latter would establish that life's emergence from non-life is quasi-deterministic. On the other hand, if the chiral signature is determined by fundamental physics, then it may be much harder to establish an independent origin for extraterrestrial

  5. Possible chiral bands in {sup 194}Tl

    SciTech Connect

    Masiteng, P. L.; Ramashidzha, T. M.; Maliage, S. M.; Sharpey-Schafer, J. F.; Vymers, P. A.; Lawrie, E. A.; Lawrie, J. J.; Bark, R. A.; Mullins, S. M.; Murray, S. H. T.; Kau, J.; Komati, F.; Lindsay, R.; Matamba, I.; Mutshena, P.; Zhang, Y.

    2011-10-28

    High spin states in {sup 194}Tl, excited through the {sup 181}Ta({sup 18}O,5n) fusion evaporation reaction, were studied using the AFRODITE array at iThemba LABS. Candidate chiral bands built on the {pi}h{sub 9/2} x {nu}i{sub 13/2}{sup 1} configuration were found. Furthermore these bands were observed through a band crossing caused by the excitation of a {nu}i{sub 13/2} pair. Above the band crossing the excitation energies remain close, suggesting that chirality may persist for the four quasiparticle configuration too.

  6. Supernovae, neutron stars and biomolecular chirality.

    PubMed

    Bonner, W A; Rubenstein, E

    1987-01-01

    Recent theoretical and experimental investigations of the origin of biomolecular chirality are reviewed briefly. Biotic and abiotic theories are evaluated critically with the conclusion that asymmetric photochemical processes with circulary polarized light (CPL), particularly asymmetric photolyses, constitute the most viable mechanisms. Solar CPL sources appear too weak and random to be effective. We suggest an alternative CPL source, namely, the synchrotron radiation from the neutron star remnants of supernova explosions. This could asymmetrically process racemic compounds in the organic mantles of the dust grains in interstellar clouds, and the resulting chiral molecules could be transferred to Earth by cold accretion as the solar system periodically traverses these interstellar clouds.

  7. Generalized Bloch theorem and chiral transport phenomena

    NASA Astrophysics Data System (ADS)

    Yamamoto, Naoki

    2015-10-01

    Bloch theorem states the impossibility of persistent electric currents in the ground state of nonrelativistic fermion systems. We extend this theorem to generic systems based on the gauged particle number symmetry and study its consequences on the example of chiral transport phenomena. We show that the chiral magnetic effect can be understood as a generalization of the Bloch theorem to a nonequilibrium steady state, similarly to the integer quantum Hall effect. On the other hand, persistent axial currents are not prohibited by the Bloch theorem and they can be regarded as Pauli paramagnetism of relativistic matter. An application of the generalized Bloch theorem to quantum time crystals is also discussed.

  8. Chiral pesticides: Identification, description, and environmental implications

    USGS Publications Warehouse

    Ulrich, Elin M.; Morrison, Candice N.; Goldsmith, Michael R.; Foreman, William T.

    2012-01-01

    Anthropogenic chemicals, including pesticides, are a major source of contamination and pollution in the environment. Pesticides have many positive uses: increased food production, decreased damage to crops and structures, reduced disease vector populations, and more. Nevertheless, pesticide exposure can pose risks to humans and the environment, so various mitigation strategies are exercised to make them safer, minimize their use, and reduce their unintended environment effects. One strategy that may help achieve these goals relies on the unique properties of chirality or molecular asymmetry. Some common terms related to chirality are defined in Table 1.

  9. Sensitive chiral analysis by capillary electrophoresis.

    PubMed

    García-Ruiz, Carmen; Marina, María Luisa

    2006-01-01

    In this review, an updated view of the different strategies used up to now to enhance the sensitivity of detection in chiral analysis by CE will be provided to the readers. With this aim, it will include a brief description of the fundamentals and most of the recent applications performed in sensitive chiral analysis by CE using offline and online sample treatment techniques (SPE, liquid-liquid extraction, microdialysis, etc.), on-column preconcentration techniques based on electrophoretic principles (ITP, stacking, and sweeping), and alternative detection systems (spectroscopic, spectrometric, and electrochemical) to the widely used UV-Vis absorption detection.

  10. Band structure controlled by chiral imprinting

    NASA Astrophysics Data System (ADS)

    Castro-Garay, P.; Adrian Reyes, J.; Ramos-Garcia, R.

    2007-09-01

    Using the configuration of an imprinted cholesteric elastomer immersed in a racemic solvent, the authors find the solution of the boundary-value problem for the reflection and transmission of incident optical waves due to the elastomer. They show a significant width reduction of the reflection band for certain values of nematic penetration depth, which depends on the volume fraction of molecules from the solvent, whose handedness is preferably absorbed. The appearance of nested band gaps of both handednesses during the sorting mixed chiral process is also obtained. This suggests the design of chemically controlled optical filters and optically monitored chiral pumps.

  11. Band Structure Controlled by Chiral Imprinting

    NASA Astrophysics Data System (ADS)

    Reyes Cervantes, Adrian; Castro-Garay, P.; Ramos-Garcia, Ruben

    2008-03-01

    Using the configuration of an imprinted cholesteric elastomer immersed in a racemic solvent, we find the solution of the boundary--value problem for the reflection and transmission of incident optical waves due to the elastomer. We show a significant width reduction of the reflection band for certain values of nematic penetration depth, which depends on the volume fraction of molecules from the solvent, whose handedness is preferably absorbed. The appearance of nested bandgaps of both handednesses during the sorting mixed chiral process is also obtained. This suggests the design of chemically controlled optical filters and optically monitored chiral pumps.

  12. Heavy-tailed chiral random matrix theory

    NASA Astrophysics Data System (ADS)

    Kanazawa, Takuya

    2016-05-01

    We study an unconventional chiral random matrix model with a heavy-tailed probabilistic weight. The model is shown to exhibit chiral symmetry breaking with no bilinear condensate, in analogy to the Stern phase of QCD. We solve the model analytically and obtain the microscopic spectral density and the smallest eigenvalue distribution for an arbitrary number of flavors and arbitrary quark masses. Exotic behaviors such as non-decoupling of heavy flavors and a power-law tail of the smallest eigenvalue distribution are illustrated.

  13. Steering Chiral Swimmers along Noisy Helical Paths

    NASA Astrophysics Data System (ADS)

    Friedrich, Benjamin M.; Jülicher, Frank

    2009-08-01

    Chemotaxis along helical paths towards a target releasing a chemoattractant is found in sperm cells and many microorganisms. We discuss the stochastic differential geometry of the noisy helical swimming path of a chiral swimmer. A chiral swimmer equipped with a simple feedback system can navigate in a concentration gradient of chemoattractant. We derive an effective equation for the alignment of helical paths with a concentration gradient which is related to the alignment of a dipole in an external field and discuss the chemotaxis index.

  14. Topological strings and large N phase transitions II: chiral expansion of q-deformed Yang-Mills theory

    NASA Astrophysics Data System (ADS)

    Caporaso, Nicola; Cirafici, Michele; Griguolo, Luca; Pasquetti, Sara; Seminara, Domenico; Szabo, Richard J.

    2006-01-01

    We continue our study of the large N phase transition in q-deformed Yang-Mills theory on the sphere and its role in connecting topological strings to black hole entropy. We study in detail the chiral theory defined in terms of uncoupled single U(N) representations at large N and write down the resulting partition function by means of the topological vertex. The emergent toric geometry has three Kähler parameters, one of which corresponds to the expected fibration over Bbb P1. By taking a suitable double-scaling limit we recover the chiral Gross-Taylor string expansion. To analyse the phase transition we construct a matrix model which describes the chiral gauge theory. It has three distinct phases, one of which should be described by the closed topological string expansion. We verify this expectation by explicit comparison between the matrix model and the chiral topological string free energies. We also show that the critical point in the pertinent phase of the matrix model corresponds to a divergence of the topological string perturbation series.

  15. Dispersion relations for electromagnetic wave propagation in chiral plasmas

    SciTech Connect

    Gao, M. X.; Guo, B. Peng, L.; Cai, X.

    2014-11-15

    The dispersion relations for electromagnetic wave propagation in chiral plasmas are derived using a simplified method and investigated in detail. With the help of the dispersion relations for each eignwave, we explore how the chiral plasmas exhibit negative refraction and investigate the frequency region for negative refraction. The results show that chirality can induce negative refraction in plasmas. Moreover, both the degree of chirality and the external magnetic field have a significant effect on the critical frequency and the bandwidth of the frequency for negative refraction in chiral plasmas. The parameter dependence of the effects is calculated and discussed.

  16. Disordered two-dimensional electron systems with chiral symmetry

    NASA Astrophysics Data System (ADS)

    Markoš, P.; Schweitzer, L.

    2012-10-01

    We review the results of our recent numerical investigations on the electronic properties of disordered two dimensional systems with chiral unitary, chiral orthogonal, and chiral symplectic symmetry. Of particular interest is the behavior of the density of states and the logarithmic scaling of the smallest Lyapunov exponents in the vicinity of the chiral quantum critical point in the band center at E=0. The observed peaks or depressions in the density of states, the distribution of the critical conductances, and the possible non-universality of the critical exponents for certain chiral unitary models are discussed.

  17. Chirally Symmetric but Confined Hadrons at Finite Density

    NASA Astrophysics Data System (ADS)

    Ya. Glozman, L.; Wagenbrunn, R. F.

    At a critical finite chemical potential and low temperature QCD undergoes the chiral restoration phase transition. The folklore tradition is that simultaneously hadrons are deconfined and there appears the quark matter. We demonstrate that it is possible to have confined but chirally symmetric hadrons at a finite chemical potential and hence beyond the chiral restoration point at a finite chemical potential and low temperature there could exist a chirally symmetric matter consisting of chirally symmetric but confined hadrons. If it does happen in QCD, then the QCD phase diagram should be reconsidered with obvious implications for heavy ion programs and astrophysics.

  18. When Chiral Photons Meet Chiral Fermions: Photoinduced Anomalous Hall Effects in Weyl Semimetals.

    PubMed

    Chan, Ching-Kit; Lee, Patrick A; Burch, Kenneth S; Han, Jung Hoon; Ran, Ying

    2016-01-15

    The Weyl semimetal is characterized by three-dimensional linear band touching points called Weyl nodes. These nodes come in pairs with opposite chiralities. We show that the coupling of circularly polarized photons with these chiral electrons generates a Hall conductivity without any applied magnetic field in the plane orthogonal to the light propagation. This phenomenon comes about because with all three Pauli matrices exhausted to form the three-dimensional linear dispersion, the Weyl nodes cannot be gapped. Rather, the net influence of chiral photons is to shift the positions of the Weyl nodes. Interestingly, the momentum shift is tightly correlated with the chirality of the node to produce a net anomalous Hall signal. Application of our proposal to the recently discovered TaAs family of Weyl semimetals leads to an order-of-magnitude estimate of the photoinduced Hall conductivity which is within the experimentally accessible range. PMID:26824561

  19. HPLC SEPARATION OF CHIRAL ORGANOPHOSPHORUS PESTICIDES ON POLYSACCHARIDE CHIRAL STATIONARY PHASES

    EPA Science Inventory

    High-performance liquid chromatographic separation of the individual enantiomers of 12 organophosphorus pesticides (OPs) were obtained on polysaccharide chiral HPLC columns using an alkane-alcohol mobile phase. The OP pesticides were crotoxyphos, dialifor, dyfonate, fenamiphos, ...

  20. When Chiral Photons Meet Chiral Fermions: Photoinduced Anomalous Hall Effects in Weyl Semimetals

    NASA Astrophysics Data System (ADS)

    Chan, Ching-Kit; Lee, Patrick A.; Burch, Kenneth S.; Han, Jung Hoon; Ran, Ying

    2016-01-01

    The Weyl semimetal is characterized by three-dimensional linear band touching points called Weyl nodes. These nodes come in pairs with opposite chiralities. We show that the coupling of circularly polarized photons with these chiral electrons generates a Hall conductivity without any applied magnetic field in the plane orthogonal to the light propagation. This phenomenon comes about because with all three Pauli matrices exhausted to form the three-dimensional linear dispersion, the Weyl nodes cannot be gapped. Rather, the net influence of chiral photons is to shift the positions of the Weyl nodes. Interestingly, the momentum shift is tightly correlated with the chirality of the node to produce a net anomalous Hall signal. Application of our proposal to the recently discovered TaAs family of Weyl semimetals leads to an order-of-magnitude estimate of the photoinduced Hall conductivity which is within the experimentally accessible range.

  1. Spintronics and chirality: spin selectivity in electron transport through chiral molecules.

    PubMed

    Naaman, Ron; Waldeck, David H

    2015-04-01

    Recent experiments have demonstrated that the electron transmission yield through chiral molecules depends on the electron spin orientation. This phenomenon has been termed the chiral-induced spin selectivity (CISS) effect, and it provides a challenge to theory and promise for organic molecule-based spintronic devices. This article reviews recent developments in our understanding of CISS. Different theoretical models have been used to describe the effect; however, they all presume an unusually large spin-orbit coupling in chiral molecules for the effect to display the magnitudes seen in experiments. A simplified model for an electron's transport through a chiral potential suggests that these large couplings can be manifested. Techniques for measuring spin-selective electron transport through molecules are overviewed, and some examples of recent experiments are described. Finally, we present results obtained by studying several systems, and we describe the possible application of the CISS effect for memory devices.

  2. Intelligent chiral sensing based on supramolecular and interfacial concepts.

    PubMed

    Ariga, Katsuhiko; Richards, Gary J; Ishihara, Shinsuke; Izawa, Hironori; Hill, Jonathan P

    2010-01-01

    Of the known intelligently-operating systems, the majority can undoubtedly be classed as being of biological origin. One of the notable differences between biological and artificial systems is the important fact that biological materials consist mostly of chiral molecules. While most biochemical processes routinely discriminate chiral molecules, differentiation between chiral molecules in artificial systems is currently one of the challenging subjects in the field of molecular recognition. Therefore, one of the important challenges for intelligent man-made sensors is to prepare a sensing system that can discriminate chiral molecules. Because intermolecular interactions and detection at surfaces are respectively parts of supramolecular chemistry and interfacial science, chiral sensing based on supramolecular and interfacial concepts is a significant topic. In this review, we briefly summarize recent advances in these fields, including supramolecular hosts for color detection on chiral sensing, indicator-displacement assays, kinetic resolution in supramolecular reactions with analyses by mass spectrometry, use of chiral shape-defined polymers, such as dynamic helical polymers, molecular imprinting, thin films on surfaces of devices such as QCM, functional electrodes, FET, and SPR, the combined technique of magnetic resonance imaging and immunoassay, and chiral detection using scanning tunneling microscopy and cantilever technology. In addition, we will discuss novel concepts in recent research including the use of achiral reagents for chiral sensing with NMR, and mechanical control of chiral sensing. The importance of integration of chiral sensing systems with rapidly developing nanotechnology and nanomaterials is also emphasized.

  3. Intelligent Chiral Sensing Based on Supramolecular and Interfacial Concepts

    PubMed Central

    Ariga, Katsuhiko; Richards, Gary J.; Ishihara, Shinsuke; Izawa, Hironori; Hill, Jonathan P.

    2010-01-01

    Of the known intelligently-operating systems, the majority can undoubtedly be classed as being of biological origin. One of the notable differences between biological and artificial systems is the important fact that biological materials consist mostly of chiral molecules. While most biochemical processes routinely discriminate chiral molecules, differentiation between chiral molecules in artificial systems is currently one of the challenging subjects in the field of molecular recognition. Therefore, one of the important challenges for intelligent man-made sensors is to prepare a sensing system that can discriminate chiral molecules. Because intermolecular interactions and detection at surfaces are respectively parts of supramolecular chemistry and interfacial science, chiral sensing based on supramolecular and interfacial concepts is a significant topic. In this review, we briefly summarize recent advances in these fields, including supramolecular hosts for color detection on chiral sensing, indicator-displacement assays, kinetic resolution in supramolecular reactions with analyses by mass spectrometry, use of chiral shape-defined polymers, such as dynamic helical polymers, molecular imprinting, thin films on surfaces of devices such as QCM, functional electrodes, FET, and SPR, the combined technique of magnetic resonance imaging and immunoassay, and chiral detection using scanning tunneling microscopy and cantilever technology. In addition, we will discuss novel concepts in recent research including the use of achiral reagents for chiral sensing with NMR, and mechanical control of chiral sensing. The importance of integration of chiral sensing systems with rapidly developing nanotechnology and nanomaterials is also emphasized. PMID:22163577

  4. The sonochemical synthesis and characterization of mesoporous chiral titania using a chiral inorganic precursor.

    PubMed

    Gabashvili, Alexandra; Major, Dan T; Perkas, Nina; Gedanken, Aharon

    2010-03-01

    The paper presents a successful sonochemical attempt to synthesize mesoporous chiral titania using a chiral inorganic precursor and dodecylamine, as the surfactant template. The resulting porous structure was characterized by nitrogen sorption experiments, transmission electron microscopy, and small-angle XRD. The enantioselectivity of this mesoporous titania after the extraction of the amine was examined by selective adsorption of enantiomers and racemic aqueous solution of camphor. The selective adsorption was measured by circular dichroism (CD) spectroscopy. PMID:19942471

  5. Resurgence in η-deformed Principal Chiral Models

    NASA Astrophysics Data System (ADS)

    Demulder, Saskia; Dorigoni, Daniele; Thompson, Daniel C.

    2016-07-01

    We study the SU(2) Principal Chiral Model (PCM) in the presence of an integrable η-deformation. We put the theory on {R}× {S}^1 with twisted boundary conditions and then reduce the circle to obtain an effective quantum mechanics associated with the Whittaker-Hill equation. Using resurgent analysis we study the large order behaviour of perturbation theory and recover the fracton events responsible for IR renormalons. The fractons are modified from the standard PCM due to the presence of this η-deformation but they are still the constituents of uniton-like solutions in the deformed quantum field theory. We also find novel SL(2,{C}) saddles, thus strengthening the conjecture that the semi-classical expansion of the path integral gives rise to a resurgent transseries once written as a sum over Lefschetz thimbles living in a complexification of the field space. We conclude by connecting our quantum mechanics to a massive deformation of the {N} = 2 4-d gauge theory with gauge group SU(2) and N f = 2.

  6. Chiral Light-Matter Interaction in Optical Resonators.

    PubMed

    Yoo, SeokJae; Park, Q-Han

    2015-05-22

    The Purcell effect explains the modification of the spontaneous decay rate of quantum emitters in a resonant cavity. For quantum emitters such as chiral molecules, however, the cavity modification of the spontaneous decay rate has been little known. Here we extend Purcell's work to the chiral light-matter interaction in optical resonators and find the differential spontaneous decay rate of chiral molecules coupled to left and right circularly polarized resonator modes. We determine the chiral Purcell factor, which characterizes the ability of optical resonators to enhance chiroptical signals, by the quality factor and the chiral mode volume of a resonator, representing, respectively, the temporal confinement of light and the spatial confinement of the helicity of light. We show that the chiral Purcell effect can be applied to chiroptical spectroscopy. Specifically, we propose a realistic scheme to achieve resonator enhanced chiroptical spectroscopy that uses the double fishnet structure as a nanoscale cuvette supporting the chiral Purcell effect.

  7. New chiral liquid crystal with unconventional dioxane terminal unit

    NASA Astrophysics Data System (ADS)

    Perkowski, Paweł; Bubnov, Alexej; Mrukiewicz, Mateusz; Pociecha, Damian; Piecek, Wiktor; Hamplová, Věra; Kašpar, Miroslav

    2014-11-01

    While designing new chiral self-assembling materials, i.e. those possessing the liquid crystalline behaviour, special attention should be paid to the specific architecture of different molecular parts, in particular: molecular core, linkage groups, type and place of the lateral substituents, structure of the chiral centre and the chiral and non-chiral chains. For the first time a new chiral photosensitive liquid crystalline compound possessing an unconventional 1,3-dioxanylmethyl terminal unit attached to the non-chiral chain has been designed and synthesized. On cooling from the isotropic phase, the material possesses only one tilted liquid crystalline phase, namely the smectic I* phase with hexagonal ordering. The crystal phase has been detected at lower temperatures. The self-assembling and structural behaviour have been studied by different techniques and compared to that of the materials with similar molecular structure but possessing structurally different terminal units in the non-chiral chain.

  8. Circularly polarized luminescence by visible-light absorption in a chiral O-BODIPY dye: unprecedented design of CPL organic molecules from achiral chromophores.

    PubMed

    Sánchez-Carnerero, Esther M; Moreno, Florencio; Maroto, Beatriz L; Agarrabeitia, Antonia R; Ortiz, María J; Vo, Bryan G; Muller, Gilles; de la Moya, Santiago

    2014-03-01

    Circularly polarized luminescence (CPL) in simple (small, nonaggregated, nonpolymeric) O-BODIPYs (R)-1 and (S)-1 by irradiation with visible light is first detected as proof of the ability of a new structural design to achieve CPL from inherently achiral monochromophore systems in simple organic molecules. The measured level of CPL (|g(lum)|) in solution falls into the usual range of that obtained from other simple organic molecules (10(-5)-10(-2) range), but the latter having more complex architectures since axially chiral chromophores or multichromophore systems are usually required. The new design is based on chirally perturbing the acting achiral chromophore by orthogonally tethering a single axially chiral 1,1'-binaphtyl moiety to it. The latter does not participate as a chromophore in the light-absorption/emission phenomenon. This simple design opens up new perspectives for the future development of new small-sized CPL organic dyes (e.g., those based on other highly luminescent achiral chromophores and/or chirally perturbing moieties), as well as for the improvement of the CPL properties of the organic molecules spanning their use in photonic applications.

  9. Chiral High-Speed Counter-Current Chromatography: Future Strategies for Chiral Selector Development.

    PubMed

    Ma, Ying; Ito, Yoichiro

    2014-01-01

    In conventional high-performance liquid chromatography, chiral separations are performed by chiral column with a chiral selector (CS) chemically boned to the solid support. In contrast, high-speed counter-current chromatography (HSCCC) performs chiral separations by dissolving CS in the liquid stationary phase. During the past two decades, several CSs were developed to successfully carry out chiral HSCCC which include N-dodecanoyl-L-proline-3,5-dimethylanilide, β-cyclodextrin derivatives, vancomycin, cinchona alkaloid derivatives, cellulose and amylose derivatives, tartaric acid derivatives, etc. Compared to HPLC which uses over hundred different kinds of CSs, the number of CSs effectively used in HSCCC is limited to several compounds. This may be due to the violent molecular movement of CS dissolved in the liquid stationary phase which reduces chiral selectivity based on steric affinity. Future development strategy of CS for HSCC proposed here is to suppress the molecular movement of the CS in the liquid stationary phase by the following three ways: 1) using viscous stationary phase such as aqueous-aqueous polymer phase system; 2) attaching a long hydrophobic chain to the asymmetric carbon, or 3) chemically bonding CS onto hydrophobic small particles such as carbon nanotubes, gold colloidal particles, and submicron silica particles.

  10. Chiral High-Speed Counter-Current Chromatography: Future Strategies for Chiral Selector Development

    PubMed Central

    Ma, Ying; Ito, Yoichiro

    2014-01-01

    In conventional high-performance liquid chromatography, chiral separations are performed by chiral column with a chiral selector (CS) chemically boned to the solid support. In contrast, high-speed counter-current chromatography (HSCCC) performs chiral separations by dissolving CS in the liquid stationary phase. During the past two decades, several CSs were developed to successfully carry out chiral HSCCC which include N-dodecanoyl-L-proline-3,5-dimethylanilide, β-cyclodextrin derivatives, vancomycin, cinchona alkaloid derivatives, cellulose and amylose derivatives, tartaric acid derivatives, etc. Compared to HPLC which uses over hundred different kinds of CSs, the number of CSs effectively used in HSCCC is limited to several compounds. This may be due to the violent molecular movement of CS dissolved in the liquid stationary phase which reduces chiral selectivity based on steric affinity. Future development strategy of CS for HSCC proposed here is to suppress the molecular movement of the CS in the liquid stationary phase by the following three ways: 1) using viscous stationary phase such as aqueous-aqueous polymer phase system; 2) attaching a long hydrophobic chain to the asymmetric carbon, or 3) chemically bonding CS onto hydrophobic small particles such as carbon nanotubes, gold colloidal particles, and submicron silica particles. PMID:24611132

  11. Separation of chiral nanotubes with an opposite handedness by chiral oligopeptide adsorption: A molecular dynamics study.

    PubMed

    Raffaini, Giuseppina; Ganazzoli, Fabio

    2015-12-18

    The separation of enantiomeric chiral nanotubes that can form non-covalent complexes with an unlike stability upon adsorption of chiral molecules is a process of potential interest in different fields and applications. Using fully atomistic molecular dynamics simulations, we report in this paper a theoretical study of the adsorption and denaturation of an oligopeptide formed by 16 chiral amino acids having a helical structure in the native state on both the inner and the outer surface of the chiral (10, 20) and (20, 10) single-walled carbon nanotubes having an opposite handedness, and of the armchair (16, 16) nanotube with a similar diameter for comparison. In the final adsorbed state, the oligopeptide loses in all cases its native helical conformation, assuming elongated geometries that maximize its contact with the surface through all the 16 amino acids. We find that the complexes formed by the two chiral nanotubes and the chosen oligopeptide have a strongly unlike stability both when adsorption takes place on the outer convex surface of the nanotube, and when it occurs on the inner concave surface. Thus, our molecular simulations indicate that separation of chiral, enantiomeric carbon nanotubes for instance by chromatographic methods can indeed be carried out using oligopeptides of a sufficient length.

  12. Dual Ginzburg-Landau Theory on Non-Perturbative QCD Phenomena

    NASA Astrophysics Data System (ADS)

    Toki, H.

    The fundamental building blocks of matter are quarks. They are the elementary particles in the standard theory together with the leptons. Hence, it is fundamental to describe hadrons and nuclei in terms of quarks and gluons, the subject of which is called Quark Nuclear Physics. The quark-gluon dynamics is described by quantum chromodynamics (QCD). Our interest is the non-perturbative aspect of QCD as confinement, chiral symmetry breaking, hadronization, etc. We introduce the dual Ginzburg-Landau theory (DGL), where the color monopole fields and their condensation in the QCD vacuum play essential roles in describing these non-perturbative phenomena. We discuss the connection of the monopole fields with instantons, which are the classical solutions of the non-abelian gauge theory.

  13. Chiral separation and twin-beam photonics

    NASA Astrophysics Data System (ADS)

    Bradshaw, David S.; Andrews, David L.

    2016-03-01

    It is well-known that, in a homogeneous fluid medium, most optical means that afford discrimination between molecules of opposite handedness are intrinsically weak effects. The reason is simple: the wide variety of origins for differential response commonly feature real or virtual electronic transitions that break a parity condition. Despite being electric dipole allowed, they manifest the chirality of the material in which they occur by breaking a selection rule that would otherwise preclude the simultaneous involvement of magnetic dipole or electric quadrupole forms of coupling. Although the latter are typically weaker than electric dipole effects by several orders of magnitude, it is the involvement of these weak forms of interaction that are responsible for chiral sensitivity. There have been a number of attempts to cleverly exploit novel optical configurations to enhance the relative magnitude - and hence potentially the efficiency - of chiral discrimination. The prospect of success in any such venture is enticing, because of the huge impact that such an advance might be expected to have in the health, food and medical sectors. Some of these proposals have utilized mirror reflection, and others surface plasmon coupling, or optical binding methods. Several recent works in the literature have drawn attention to a further possibility: the deployment of optical beam interference as a means to achieve chiral separations of sizeable extent. In this paper the underlying theory is fully developed to identify the true scope and limitations of such an approach.

  14. Efficient Biocatalytic Synthesis of Chiral Chemicals.

    PubMed

    Zhang, Zhi-Jun; Pan, Jiang; Ma, Bao-Di; Xu, Jian-He

    2016-01-01

    Chiral chemicals are a group of important chiral synthons for the synthesis of a series of pharmaceuticals, agrochemicals, and fine chemicals. In past decades, a number of biocatalytic approaches have been developed for the green and effective synthesis of various chiral chemicals. However, the practical application of these biocatalytic processes is still hindered by the lack of highly efficient and robust biocatalysts, which usually results in the low volumetric productivity and high cost of the bioprocesses. Further step forward of biocatalysis in industrial application strongly requires the development of versatile and highly efficient biocatalysts, aiming to increase the process efficiency and facilitate the downstream processing. Recently, the fast growth of genome sequences in the database in post-genomic era offers great opportunities for accessing numerous biocatalysts with practical application potential, and the so-called genome mining approach provides time-effective and highly specific strategy for the fast identification of target enzymes with desired properties and outperforms the traditional screening of soil samples for microbial enzyme producers of interest. A number of biocatalytic processes with industrial application potential were developed thereafter. Further development of protein engineering strategies, process optimization, and cooperative work between biologists, organic chemists, and engineers is expected to make biocatalysis technology the first choice approach for the eco-friendly, highly efficient, and cost-effective synthesis of chiral chemicals in the near future.

  15. Polar Superhelices in Ferroelectric Chiral Nanosprings

    NASA Astrophysics Data System (ADS)

    Shimada, Takahiro; Lich, Le Van; Nagano, Koyo; Wang, Jian-Shan; Wang, Jie; Kitamura, Takayuki

    2016-10-01

    Topological objects of nontrivial spin or dipolar field textures, such as skyrmions, merons, and vortices, interacting with applied external fields in ferroic materials are of great scientific interest as an intriguing playground of unique physical phenomena and novel technological paradigms. The quest for new topological configurations of such swirling field textures has primarily been done for magnets with Dzyaloshinskii-Moriya interactions, while the absence of such intrinsic chiral interactions among electric dipoles left ferroelectrics aside in this quest. Here, we demonstrate that a helical polarization coiled into another helix, namely a polar superhelix, can be extrinsically stabilized in ferroelectric nanosprings. The interplay between dipolar interactions confined in the chiral geometry and the complex strain field of mixed bending and twisting induces the superhelical configuration of electric polarization. The geometrical structure of the polar superhelix gives rise to electric chiralities at two different length scales and the coexistence of three order parameters, i.e., polarization, toroidization, and hypertoroidization, both of which can be manipulated by homogeneous electric and/or mechanical fields. Our work therefore provides a new geometrical configuration of swirling dipolar fields, which offers the possibility of multiple order-parameters, and electromechanically controllable dipolar chiralities and associated electro-optical responses.

  16. Chiral anomaly and transport in Weyl metals.

    PubMed

    Burkov, A A

    2015-03-25

    We present an overview of our recent work on transport phenomena in Weyl metals, which may be connected to their nontrivial topological properties, particularly to chiral anomaly. We argue that there are two basic phenomena, which are related to chiral anomaly in Weyl metals: anomalous Hall effect (AHE) and chiral magnetic effect (CME). While AHE is in principle present in any ferromagnetic metal, we demonstrate that a magnetic Weyl metal is distinguished from an ordinary ferromagnetic metal by the absence of the extrinsic and the Fermi surface part of the intrinsic contributions to the AHE, as long as the Fermi energy is sufficiently close to the Weyl nodes. The AHE in a Weyl metal is thus shown to be a purely intrinsic, universal property, fully determined by the location of the Weyl nodes in the first Brillouin zone. In other words, a ferromagnetic Weyl metal may be thought of as the only example of a ferromagnetic metal with a purely intrinsic AHE. We further develop a fully microscopic theory of diffusive magnetotransport in Weyl metals. We derive coupled diffusion equations for the total and axial (i.e. node-antisymmetric) charge densities and show that chiral anomaly manifests as a magnetic-field-induced coupling between them. We demonstrate that an experimentally-observable consequence of CME in magnetotransport in Weyl metals is a quadratic negative magnetoresistance, which will dominate all other contributions to magnetoresistance under certain conditions and may be regarded as a smoking-gun transport characteristic, unique to Weyl metals.

  17. Chiral damping in magnetic domain walls dynamics

    NASA Astrophysics Data System (ADS)

    Jué, Emilie

    Domain wall (DW) motion in materials with structural inversion asymmetry (SIA) and high spin-orbit coupling has attracted much interest in the recent years due to the discovery of unexpected physical mechanisms. Especially, it has been shown that the DW dynamics in such materials can be explained by chiral DWs with (partly or fully) Néel structure, whose stability derives from an interfacial Dzyaloshinskii-Moriya interaction (DMI). In this work, we show that DMI is not the only effect inducing chiral dynamics and demonstrate the existence of a chiral damping. This result is supported by the study of the asymmetry induced by an in-plane magnetic field on field induced domain wall motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. Using time reversal properties, we show that this asymmetry cannot be attributed to an effective field but originates from a purely dissipative mechanism. The observation of chiral damping, not only enriches the spectrum of physical phenomena engendered by the SIA, but since it can coexist with DMI it is essential for conceiving DW and skyrmion devices

  18. Chiral damping of magnetic domain walls

    NASA Astrophysics Data System (ADS)

    Jué, Emilie; Safeer, C. K.; Drouard, Marc; Lopez, Alexandre; Balint, Paul; Buda-Prejbeanu, Liliana; Boulle, Olivier; Auffret, Stephane; Schuhl, Alain; Manchon, Aurelien; Miron, Ioan Mihai; Gaudin, Gilles

    2016-03-01

    Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics, current-induced spin-orbit torques and some topological magnetic structures. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii-Moriya interaction (DMI) exhibit identical spatial symmetry. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. ).

  19. Polar Superhelices in Ferroelectric Chiral Nanosprings

    PubMed Central

    Shimada, Takahiro; Lich, Le Van; Nagano, Koyo; Wang, Jian-Shan; Wang, Jie; Kitamura, Takayuki

    2016-01-01

    Topological objects of nontrivial spin or dipolar field textures, such as skyrmions, merons, and vortices, interacting with applied external fields in ferroic materials are of great scientific interest as an intriguing playground of unique physical phenomena and novel technological paradigms. The quest for new topological configurations of such swirling field textures has primarily been done for magnets with Dzyaloshinskii-Moriya interactions, while the absence of such intrinsic chiral interactions among electric dipoles left ferroelectrics aside in this quest. Here, we demonstrate that a helical polarization coiled into another helix, namely a polar superhelix, can be extrinsically stabilized in ferroelectric nanosprings. The interplay between dipolar interactions confined in the chiral geometry and the complex strain field of mixed bending and twisting induces the superhelical configuration of electric polarization. The geometrical structure of the polar superhelix gives rise to electric chiralities at two different length scales and the coexistence of three order parameters, i.e., polarization, toroidization, and hypertoroidization, both of which can be manipulated by homogeneous electric and/or mechanical fields. Our work therefore provides a new geometrical configuration of swirling dipolar fields, which offers the possibility of multiple order-parameters, and electromechanically controllable dipolar chiralities and associated electro-optical responses. PMID:27713540

  20. Chiral anomaly and transport in Weyl metals

    NASA Astrophysics Data System (ADS)

    Burkov, A. A.

    2015-03-01

    We present an overview of our recent work on transport phenomena in Weyl metals, which may be connected to their nontrivial topological properties, particularly to chiral anomaly. We argue that there are two basic phenomena, which are related to chiral anomaly in Weyl metals: anomalous Hall effect (AHE) and chiral magnetic effect (CME). While AHE is in principle present in any ferromagnetic metal, we demonstrate that a magnetic Weyl metal is distinguished from an ordinary ferromagnetic metal by the absence of the extrinsic and the Fermi surface part of the intrinsic contributions to the AHE, as long as the Fermi energy is sufficiently close to the Weyl nodes. The AHE in a Weyl metal is thus shown to be a purely intrinsic, universal property, fully determined by the location of the Weyl nodes in the first Brillouin zone. In other words, a ferromagnetic Weyl metal may be thought of as the only example of a ferromagnetic metal with a purely intrinsic AHE. We further develop a fully microscopic theory of diffusive magnetotransport in Weyl metals. We derive coupled diffusion equations for the total and axial (i.e. node-antisymmetric) charge densities and show that chiral anomaly manifests as a magnetic-field-induced coupling between them. We demonstrate that an experimentally-observable consequence of CME in magnetotransport in Weyl metals is a quadratic negative magnetoresistance, which will dominate all other contributions to magnetoresistance under certain conditions and may be regarded as a smoking-gun transport characteristic, unique to Weyl metals.

  1. Monopoles and fractional vortices in chiral superconductors

    PubMed Central

    Volovik, G. E.

    2000-01-01

    I discuss two exotic objects that must be experimentally identified in chiral superfluids and superconductors. These are (i) the vortex with a fractional quantum number (N = 1/2 in chiral superfluids, and N = 1/2 and N = 1/4 in chiral superconductors), which plays the part of the Alice string in relativistic theories and (ii) the hedgehog in the ^l field, which is the counterpart of the Dirac magnetic monopole. These objects of different dimensions are topologically connected. They form the combined object that is called a nexus in relativistic theories. In chiral superconductors, the nexus has magnetic charge emanating radially from the hedgehog, whereas the half-quantum vortices play the part of the Dirac string. Each half-quantum vortex supplies the fractional magnetic flux to the hedgehog, representing 1/4 of the “conventional” Dirac string. I discuss the topological interaction of the superconductor's nexus with the ‘t Hooft–Polyakov magnetic monopole, which can exist in Grand Unified Theories. The monopole and the hedgehog with the same magnetic charge are topologically confined by a piece of the Abrikosov vortex. Such confinement makes the nexus a natural trap for the magnetic monopole. Other properties of half-quantum vortices and monopoles are discussed as well, including fermion zero modes. PMID:10716980

  2. Skyrme-Einstein closed cosmic chiral strings

    SciTech Connect

    Rybakov, Yu. P. Ivanova, I. S.

    2007-07-15

    Within the theory of general relativity, the configuration of a closed string (vortex) characterized by a topological charge of the degree type is described for the Skyrme-Einstein SU (2) chiral model. In the approximation of a large vortex-closure radius (a), a solution to equations of motion is obtained, along with estimates for the vortex energy and radius.

  3. Chiral anomaly and transport in Weyl metals.

    PubMed

    Burkov, A A

    2015-03-25

    We present an overview of our recent work on transport phenomena in Weyl metals, which may be connected to their nontrivial topological properties, particularly to chiral anomaly. We argue that there are two basic phenomena, which are related to chiral anomaly in Weyl metals: anomalous Hall effect (AHE) and chiral magnetic effect (CME). While AHE is in principle present in any ferromagnetic metal, we demonstrate that a magnetic Weyl metal is distinguished from an ordinary ferromagnetic metal by the absence of the extrinsic and the Fermi surface part of the intrinsic contributions to the AHE, as long as the Fermi energy is sufficiently close to the Weyl nodes. The AHE in a Weyl metal is thus shown to be a purely intrinsic, universal property, fully determined by the location of the Weyl nodes in the first Brillouin zone. In other words, a ferromagnetic Weyl metal may be thought of as the only example of a ferromagnetic metal with a purely intrinsic AHE. We further develop a fully microscopic theory of diffusive magnetotransport in Weyl metals. We derive coupled diffusion equations for the total and axial (i.e. node-antisymmetric) charge densities and show that chiral anomaly manifests as a magnetic-field-induced coupling between them. We demonstrate that an experimentally-observable consequence of CME in magnetotransport in Weyl metals is a quadratic negative magnetoresistance, which will dominate all other contributions to magnetoresistance under certain conditions and may be regarded as a smoking-gun transport characteristic, unique to Weyl metals. PMID:25712419

  4. Neptune's story. [Triton's orbit perturbation

    NASA Technical Reports Server (NTRS)

    Goldreich, P.; Murray, N.; Longaretti, P. Y.; Banfield, D.

    1989-01-01

    It is conjectured that Triton was captured from a heliocentric orbit as the result of a collision with what was then one of Neptune's regular satellites. The immediate post-capture orbit was highly eccentric. Dissipation due to tides raised by Neptune in Triton caused Triton's orbit to evolve to its present state in less than one billion years. For much of this time Triton was almost entirely molten. While its orbit was evolving, Triton cannibalized most of the regular satellites of Neptune and also perturbed Nereid, thus accounting for that satellite's highly eccentric and inclined orbit. The only regular satellites of Neptune that survived were those that formed well within 5 Neptune radii, and they move on inclined orbits as the result of chaotic perturbations forced by Triton.

  5. Cosmological perturbations in unimodular gravity

    SciTech Connect

    Gao, Caixia; Brandenberger, Robert H.; Cai, Yifu; Chen, Pisin E-mail: rhb@hep.physics.mcgill.ca E-mail: chen@slac.stanford.edu

    2014-09-01

    We study cosmological perturbation theory within the framework of unimodular gravity. We show that the Lagrangian constraint on the determinant of the metric required by unimodular gravity leads to an extra constraint on the gauge freedom of the metric perturbations. Although the main equation of motion for the gravitational potential remains the same, the shift variable, which is gauge artifact in General Relativity, cannot be set to zero in unimodular gravity. This non-vanishing shift variable affects the propagation of photons throughout the cosmological evolution and therefore modifies the Sachs-Wolfe relation between the relativistic gravitational potential and the microwave temperature anisotropies. However, for adiabatic fluctuations the difference between the result in General Relativity and unimodular gravity is suppressed on large angular scales. Thus, no strong constraints on the theory can be derived.

  6. The status of perturbative QCD

    SciTech Connect

    Ellis, R.K.

    1988-10-01

    The advances in perturbative QCD are reviewed. The status of determinations of the coupling constant ..cap alpha../sub S/ and the parton distribution functions is presented. New theoretical results on the spin dependent structure functions of the proton are also reviewed. The theoretical description of the production of vector bosons, jets and heavy quarks is outlined with special emphasis on new results. Expected rates for top quark production at hadronic colliders are presented. 111 refs., 8 figs.

  7. Quantum fields with classical perturbations

    SciTech Connect

    Dereziński, Jan

    2014-07-15

    The main purpose of these notes is a review of various models of Quantum Field Theory (QFT) involving quadratic Lagrangians. We discuss scalar and vector bosons, spin 1/2 fermions, both neutral and charged. Beside free theories, we study their interactions with classical perturbations, called, depending on the context, an external linear source, mass-like term, current or electromagnetic potential. The notes may serve as a first introduction to QFT.

  8. Recent advances in SPE-chiral-HPLC methods for enantiomeric separation of chiral drugs in biological samples.

    PubMed

    Ali, Imran; Alam, Syed Dilshad; Al-Othman, Zeid A; Farooqi, Javed A

    2013-08-01

    In medical practices, the determination of enantiomeric ratio of the chiral drugs is very important for their activities, bioavailabilities and biodegradation. Only homochiral medication is safe for humans. The chiral analysis in biological samples is the first and most important step. The present article describes the technical strategies of the enantiomeric resolution of racemic drugs in biological samples. Attempts have been made to describe sample preparation by solid-phase extraction and enantiomeric resolution by chiral high-performance liquid chromatography. Various chiral stationary phases used in chiral separations of racemic drugs have been described. Efforts are also made to discuss the chiral recognition mechanism and future perspectives of chiral analyses in biological samples.

  9. Perturbation growth in accreting filaments

    NASA Astrophysics Data System (ADS)

    Clarke, S. D.; Whitworth, A. P.; Hubber, D. A.

    2016-05-01

    We use smoothed particle hydrodynamic simulations to investigate the growth of perturbations in infinitely long filaments as they form and grow by accretion. The growth of these perturbations leads to filament fragmentation and the formation of cores. Most previous work on this subject has been confined to the growth and fragmentation of equilibrium filaments and has found that there exists a preferential fragmentation length-scale which is roughly four times the filament's diameter. Our results show a more complicated dispersion relation with a series of peaks linking perturbation wavelength and growth rate. These are due to gravo-acoustic oscillations along the longitudinal axis during the sub-critical phase of growth. The positions of the peaks in growth rate have a strong dependence on both the mass accretion rate onto the filament and the temperature of the gas. When seeded with a multiwavelength density power spectrum, there exists a clear preferred core separation equal to the largest peak in the dispersion relation. Our results allow one to estimate a minimum age for a filament which is breaking up into regularly spaced fragments, as well as an average accretion rate. We apply the model to observations of filaments in Taurus by Tafalla & Hacar and find accretion rates consistent with those estimated by Palmeirim et al.

  10. R evolution: Improving perturbative QCD

    SciTech Connect

    Hoang, Andre H.; Jain, Ambar; Stewart, Iain W.; Scimemi, Ignazio

    2010-07-01

    Perturbative QCD results in the MS scheme can be dramatically improved by switching to a scheme that accounts for the dominant power law dependence on the factorization scale in the operator product expansion. We introduce the ''MSR scheme'' which achieves this in a Lorentz and gauge invariant way and has a very simple relation to MS. Results in MSR depend on a cutoff parameter R, in addition to the {mu} of MS. R variations can be used to independently estimate (i.) the size of power corrections, and (ii.) higher-order perturbative corrections (much like {mu} in MS). We give two examples at three-loop order, the ratio of mass splittings in the B*-B and D*-D systems, and the Ellis-Jaffe sum rule as a function of momentum transfer Q in deep inelastic scattering. Comparing to data, the perturbative MSR results work well even for Q{approx}1 GeV, and power corrections are reduced compared to MS.

  11. A Cross-chiral RNA Polymerase Ribozyme

    PubMed Central

    Sczepanski, Jonathan T.; Joyce, Gerald F.

    2014-01-01

    Thirty years ago it was shown that the non-enzymatic, template-directed polymerization of activated mononucleotides proceeds readily in a homochiral system, but is severely inhibited by the presence of the opposing enantiomer.1 This finding poses a severe challenge for the spontaneous emergence of RNA-based life, and has led to the suggestion that either RNA was preceded by some other genetic polymer that is not subject to chiral inhibition2 or chiral symmetry was broken through chemical processes prior to the origin of RNA-based life.3,4 Once an RNA enzyme arose that could catalyze the polymerization of RNA, it would have been possible to distinguish among the two enantiomers, enabling RNA replication and RNA-based evolution to occur. It is commonly thought that the earliest RNA polymerase and its substrates would have been of the same handedness, but this is not necessarily the case. Replicating D-and L-RNA molecules may have emerged together, based on the ability of structured RNAs of one handedness to catalyze the templated polymerization of activated mononucleotides of the opposite handedness. Such a cross-chiral RNA polymerase has now been developed using in vitro evolution. The D-RNA enzyme, consisting of 83 nucleotides, catalyzes the joining of L-mono- or oligonucleotide substrates on a complementary L-RNA template, and similarly for the L-enzyme with D-substrates and a D-template. Chiral inhibition is avoided because the 106-fold rate acceleration of the enzyme only pertains to cross-chiral substrates. The enzyme's activity is sufficient to generate full-length copies of its enantiomer through the templated joining of 11 component oligonucleotides. PMID:25363769

  12. Chiral Sensitivity in Electron-Molecule Interactions

    NASA Astrophysics Data System (ADS)

    Dreiling, Joan

    2015-09-01

    All molecular forms of life possess a chiral asymmetry, with amino acids and sugars found respectively in L- and D-enantiomers only. The primordial origin of this enantiomeric excess is unknown. One possible explanation is given by the Vester- Ulbricht hypothesis, which suggests that left-handed electrons present in beta-radiation, produced by parity-violating weak decays, interacted with biological precursors and preferentially destroyed one of the two enantiomers. Experimental tests of this idea have thus far yielded inconclusive results. We show direct evidence for chirally-dependent bond breaking through a dissociative electron attachment (DEA) reaction when spin-polarized electrons are incident on gas-phase chiral molecules. This provides unambiguous evidence for a well-defined, chirally-sensitive destructive molecular process and, as such, circumstantial evidence for the Vester-Ulbricht hypothesis. I will also present the results of our systematic study of the DEA asymmetry for different chiral halocamphor molecules. Three halocamphor molecules were investigated: 3-bromocamphor (C10H15BrO), 3-iodocamphor(C10H15IO), and 10-iodocamphor. The DEA asymmetries collected for bromocamphor and iodocamphor are qualitatively different, suggesting that the atomic number of the heaviest atom in the molecule plays a crucial role in the asymmetric interactions. The DEA asymmetry data for 3- and 10-iodocamphor have the same qualitative behavior, but the 10-iodocamphor asymmetry is about twice as large at the lowest energies investigated, so the location of the heavy atom in the camphor molecule also affects the asymmetries. This work was performed at the University of Nebraska-Lincoln. This project is funded by NSF Grant PHY-1206067.

  13. Chemical synthesis of chiral conducting polymers

    SciTech Connect

    Wang, Hsing-Lin; Li, Wenguang

    2006-07-11

    An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts. The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40.times.103 degree-cm2/decimole to about 700.times.103 degree-cm2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

  14. Chemical synthesis of chiral conducting polymers

    SciTech Connect

    Wang, Hsing-Lin; Li, Wenguang

    2009-01-13

    An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts.The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40.times.10.sup.3 degree-cm.sup.2/decimole to about 700.times.10.sup.3 degree-cm.sup.2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

  15. Engineering chiral density waves and topological band structures by multiple-Q superpositions of collinear up-up-down-down orders

    NASA Astrophysics Data System (ADS)

    Hayami, Satoru; Ozawa, Ryo; Motome, Yukitoshi

    2016-07-01

    Magnetic orders characterized by multiple ordering vectors harbor noncollinear and noncoplanar spin textures and can be a source of unusual electronic properties through the spin Berry phase mechanism. We theoretically show that such multiple-Q states are stabilized in itinerant magnets in the form of superpositions of collinear up-up-down-down (UUDD) spin states, which accompany the density waves of vector and scalar chirality. The result is drawn by examining the ground state of the Kondo lattice model with classical localized moments, especially when the Fermi surface is tuned to be partially nested by the symmetry-related commensurate vectors. We unveil the instability toward a double-Q UUDD state with vector chirality density waves on the square lattice and a triple-Q UUDD state with scalar chirality density waves on the triangular lattice, using the perturbative theory and variational calculations. The former double-Q state is also confirmed by large-scale Langevin dynamics simulations. We also show that, for a sufficiently large exchange coupling, the chirality density waves can induce rich nontrivial topology of electronic structures, such as the massless Dirac semimetal, Chern insulator with quantized topological Hall response, and peculiar edge states which depend on the phase of chirality density waves at the edges.

  16. Significant Enhancement of the Chiral Correlation Length in Nematic Liquid Crystals by Gold Nanoparticle Surfaces Featuring Axially Chiral Binaphthyl Ligands.

    PubMed

    Mori, Taizo; Sharma, Anshul; Hegmann, Torsten

    2016-01-26

    Chirality is a fundamental scientific concept best described by the absence of mirror symmetry and the inability to superimpose an object onto its mirror image by translation and rotation. Chirality is expressed at almost all molecular levels, from single molecules to supramolecular systems, and present virtually everywhere in nature. Here, to explore how chirality propagates from a chiral nanoscale surface, we study gold nanoparticles functionalized with axially chiral binaphthyl molecules. In particular, we synthesized three enantiomeric pairs of chiral ligand-capped gold nanoparticles differing in size, curvature, and ligand density to tune the chirality transfer from nanoscale solid surfaces to a bulk anisotropic liquid crystal medium. Ultimately, we are examining how far the chirality from a nanoparticle surface reaches into a bulk material. Circular dichroism spectra of the gold nanoparticles decorated with binaphthyl thiols confirmed that the binaphthyl moieties form a cisoid conformation in isotropic organic solvents. In the chiral nematic liquid crystal phase, induced by dispersing the gold nanoparticles into an achiral anisotropic nematic liquid crystal solvent, the binaphthyl moieties on the nanoparticle surface form a transoid conformation as determined by imaging the helical twist direction of the induced cholesteric phase. This suggests that the ligand density on the nanoscale metal surfaces provides a dynamic space to alter and adjust the helicity of binaphthyl derivatives in response to the ordering of the surrounding medium. The helical pitch values of the induced chiral nematic phase were determined, and the helical twisting power (HTP) of the chiral gold nanoparticles calculated to elucidate the chirality transfer efficiency of the binaphthyl ligand capped gold nanoparticles. Remarkably, the HTP increases with increasing diameter of the particles, that is, the efficiency of the chirality transfer of the binaphthyl units bound to the nanoparticle

  17. Memorized chiral arrangement of gemini surfactant assemblies in nanometric hybrid organic-silica helices.

    PubMed

    Ryu, Naoya; Okazaki, Yutaka; Hirai, Kana; Takafuji, Makoto; Nagaoka, Shoji; Pouget, Emilie; Ihara, Hirotaka; Oda, Reiko

    2016-04-30

    Hybrid nanohelices were obtained from silicification of self-assemblies of gemini surfactants with tartrate counterions. The chiral arrangement of these non-chiral gemini surfactants was preserved in the silica matrix even after the counterion exchange for a non-chiral bromide, and was capable of inducing the chiral organisation of a non-chiral dye, methyl orange. PMID:26961377

  18. Optical properties and circular dichroism of chiral metal nanoparticles

    NASA Astrophysics Data System (ADS)

    Fan, Zhiyuan; Govorov, Alexander; OU Team

    2013-03-01

    In nature, biological systems are built up by homochiral building blocks, such as a sugar and protein. Circular dichroism (CD) is an effective tool of resolving molecular conformations. It utilizes circularly polarized light to detect differential absorption of chiral materials. In medicine, it will help us to develop new drugs and therapies, if we understand the connection between the physical or chemical properties of drug molecules and their conformations. With the rapid development of nanotechnologies, chiral nanomaterials attract lots of attention nowadays. CD signals of chiral molecules can be enhanced or shifted to the visible band in the presence of plasmonic nanocrystals. Here we present a plasmonic CD mechanism from a single chiral metal nanocrystal. The mechanism is essentially different from the dipolar plasmon-plasmon interaction in a chiral NP assembly, which mimics the CD mechanism of chiral molecules. Chiral metal nanocrystals are expected to have promising applications in biosensing. Recently a few experimental papers reported successful realizations of chiral nanocrystals in a macroscopic ensemble in solution. Particularly the paper described silver nanoparticles grown on chiral template molecules and demonstrating characteristic CD signals at a plasmonic wavelength. The plasmonic CD signals in Ref. can come from a dipolar plasmon-molecule interaction or from a chiral shape of nanocrystals. This work was supported by the NSF (project: CBET- 0933782) and by the Volkswagen Foundation.

  19. Cosmological perturbations: Vorticity, isocurvature and magnetic fields

    NASA Astrophysics Data System (ADS)

    Christopherson, Adam J.

    2014-10-01

    In this paper, I review some recent, interlinked, work undertaken using cosmological perturbation theory — a powerful technique for modeling inhomogeneities in the universe. The common theme which underpins these pieces of work is the presence of nonadiabatic pressure, or entropy, perturbations. After a brief introduction covering the standard techniques of describing inhomogeneities in both Newtonian and relativistic cosmology, I discuss the generation of vorticity. As in classical fluid mechanics, vorticity is not present in linearized perturbation theory (unless included as an initial condition). Allowing for entropy perturbations, and working to second order in perturbation theory, I show that vorticity is generated, even in the absence of vector perturbations, by purely scalar perturbations, the source term being quadratic in the gradients of first order energy density and isocurvature, or nonadiabatic pressure perturbations. This generalizes Crocco's theorem to a cosmological setting. I then introduce isocurvature perturbations in different models, focusing on the entropy perturbation in standard, concordance cosmology, and in inflationary models involving two scalar fields. As the final topic, I investigate magnetic fields, which are a potential observational consequence of vorticity in the early universe. I briefly review some recent work on including magnetic fields in perturbation theory in a consistent way. I show, using solely analytical techniques, that magnetic fields can be generated by higher order perturbations, albeit too small to provide the entire primordial seed field, in agreement with some numerical studies. I close this paper with a summary and some potential extensions of this work.

  20. Geometric Hamiltonian structures and perturbation theory

    SciTech Connect

    Omohundro, S.

    1984-08-01

    We have been engaged in a program of investigating the Hamiltonian structure of the various perturbation theories used in practice. We describe the geometry of a Hamiltonian structure for non-singular perturbation theory applied to Hamiltonian systems on symplectic manifolds and the connection with singular perturbation techniques based on the method of averaging.

  1. Superconvergent perturbation method in quantum mechanics

    SciTech Connect

    Scherer, W. )

    1995-02-27

    An analog of Kolmogorov's superconvergent perturbation theory in classical mechanics is constructed for self-adjoint operators. It is different from the usual Rayleigh-Schroedinger perturbation theory and yields expansions for eigenvalues and eigenvectors in terms of functions of the perturbation parameter.

  2. Analysis of Chiral Carboxylic Acids in Meteorites

    NASA Technical Reports Server (NTRS)

    Burton, A. S.; Elsila, J. E.; Hein, J. E.; Aponte, J. C.; Parker, E. T.; Glavin, D. P.; Dworkin, J. P.

    2015-01-01

    Homochirality of amino acids in proteins and sugars in DNA and RNA is a critical feature of life on Earth. In the absence of a chiral driving force, however, reactions leading to the synthesis of amino acids and sugars result in racemic mixtures. It is currently unknown whether homochirality was necessary for the origins of life or if it was a product of early life. The observation of enantiomeric excesses of certain amino acids of extraterrestrial origins in meteorites provides evidence to support the hypothesis that there was a mechanism for the preferential synthesis or destruction of a particular amino acid enantiomer [e.g., 1-3]. The cause of the observed chiral excesses is un-clear, although at least in the case of the amino acid isovaline, the degree of aqueous alteration that occurred on the meteorite parent body is correlated to the isovaline L-enantiomeric excess [3, 4]. This suggests that chiral symmetry is broken and/or amplified within the meteorite parent bodies. Besides amino acids, there have been only a few reports of other meteoritic compounds found in enantiomeric excess: sugars and sugar acids [5, 6] and the hydroxy acid lactic acid [7]. Determining whether or not additional types of molecules in meteorites are also present in enantiomeric excesses of extraterrestrial information will provide insights into mechanisms for breaking chiral symmetry. Though the previous measurements (e.g., enantiomeric composition of lactic acid [7], and chiral carboxylic acids [8]) were made by gas chromatography-mass spectrometry, the potential for increased sensitivity of liquid chromatography-mass spectrometry (LC-MS) analyses is important because for many meteorite samples, only small sample masses are available for study. Furthermore, at least in the case of amino acids, many of the largest amino acid enantiomeric excesses were observed in samples that contained lower abundances (tens of ppb) of a given amino acid enantiomer. In the present work, we describe

  3. Model of complex chiral drug metabolic systems and numerical simulation of the remaining chirality toward analysis of dynamical pharmacological activity.

    PubMed

    Ogino, Yoshiyuki; Asahi, Toru

    2015-05-21

    In this study, systems of complicated pathways involved in chiral drug metabolism were investigated. The development of chiral drugs resulted in significant improvement in the remedies available for the treatment of various severe sicknesses. Enantiopure drugs undergo various biological transformations that involve chiral inversion and thus result in the generation of multiple enantiomeric metabolites. Identification of the specific active substances determining a given drug׳s efficacy among such a mixture of different metabolites remains a challenge. To comprehend this complexity, we constructed a mathematical model representing the complicated metabolic pathways simultaneously involving chiral inversion. Moreover, this model is applied to the metabolism of thalidomide, which has recently been revived as a potentially effective prescription drug for a number of intractable diseases. The numerical simulation results indicate that retained chirality in the metabolites reflects the original chirality of the unmetabolized drug, and a higher level of enantiomeric purity is preserved during spontaneous degradation. In addition, chirality remaining after equilibration is directly related to the rate constant not only for chiral inversion but also for generation and degradation. Furthermore, the retention of chirality is quantitatively predictable using this combination of kinetic parameters. Our simulation results well explain the behavior of thalidomide in the practical biological experimental data. Therefore, this model promises a comprehensive understanding of dynamic metabolic systems involving chiral drugs that express multiple enantiospecific drug efficacies.

  4. Model of complex chiral drug metabolic systems and numerical simulation of the remaining chirality toward analysis of dynamical pharmacological activity.

    PubMed

    Ogino, Yoshiyuki; Asahi, Toru

    2015-05-21

    In this study, systems of complicated pathways involved in chiral drug metabolism were investigated. The development of chiral drugs resulted in significant improvement in the remedies available for the treatment of various severe sicknesses. Enantiopure drugs undergo various biological transformations that involve chiral inversion and thus result in the generation of multiple enantiomeric metabolites. Identification of the specific active substances determining a given drug׳s efficacy among such a mixture of different metabolites remains a challenge. To comprehend this complexity, we constructed a mathematical model representing the complicated metabolic pathways simultaneously involving chiral inversion. Moreover, this model is applied to the metabolism of thalidomide, which has recently been revived as a potentially effective prescription drug for a number of intractable diseases. The numerical simulation results indicate that retained chirality in the metabolites reflects the original chirality of the unmetabolized drug, and a higher level of enantiomeric purity is preserved during spontaneous degradation. In addition, chirality remaining after equilibration is directly related to the rate constant not only for chiral inversion but also for generation and degradation. Furthermore, the retention of chirality is quantitatively predictable using this combination of kinetic parameters. Our simulation results well explain the behavior of thalidomide in the practical biological experimental data. Therefore, this model promises a comprehensive understanding of dynamic metabolic systems involving chiral drugs that express multiple enantiospecific drug efficacies. PMID:25791284

  5. Identifying Network Perturbation in Cancer

    PubMed Central

    Logsdon, Benjamin A.; Gentles, Andrew J.; Lee, Su-In

    2016-01-01

    We present a computational framework, called DISCERN (DIfferential SparsE Regulatory Network), to identify informative topological changes in gene-regulator dependence networks inferred on the basis of mRNA expression datasets within distinct biological states. DISCERN takes two expression datasets as input: an expression dataset of diseased tissues from patients with a disease of interest and another expression dataset from matching normal tissues. DISCERN estimates the extent to which each gene is perturbed—having distinct regulator connectivity in the inferred gene-regulator dependencies between the disease and normal conditions. This approach has distinct advantages over existing methods. First, DISCERN infers conditional dependencies between candidate regulators and genes, where conditional dependence relationships discriminate the evidence for direct interactions from indirect interactions more precisely than pairwise correlation. Second, DISCERN uses a new likelihood-based scoring function to alleviate concerns about accuracy of the specific edges inferred in a particular network. DISCERN identifies perturbed genes more accurately in synthetic data than existing methods to identify perturbed genes between distinct states. In expression datasets from patients with acute myeloid leukemia (AML), breast cancer and lung cancer, genes with high DISCERN scores in each cancer are enriched for known tumor drivers, genes associated with the biological processes known to be important in the disease, and genes associated with patient prognosis, in the respective cancer. Finally, we show that DISCERN can uncover potential mechanisms underlying network perturbation by explaining observed epigenomic activity patterns in cancer and normal tissue types more accurately than alternative methods, based on the available epigenomic data from the ENCODE project. PMID:27145341

  6. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect

    Francisco Zaera

    2012-03-21

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration

  7. Advanced dress-up chiral columns: New removable chiral stationary phases for enantioseparation of chiral carboxylic acids.

    PubMed

    Todoroki, Kenichiro; Ishii, Yasuhiro; Ide, Takafumi; Min, Jun Zhe; Inoue, Koichi; Huang, Xin; Zhang, Wei; Hamashima, Yoshitaka; Toyo'oka, Toshimasa

    2015-07-01

    This paper describes the preparation of new dress-up columns featuring reproducibly removable and replaceable chiral stationary phases. After synthesizing perfluroalkylated quinine and quinidine derivatives as chiral stationary phase compounds (F-CSPs), we adsorbed them reversibly onto a fluorous LC column through pumping of their solutions. Using this dress-up chiral column and fluorophobic elution of aqueous ammonium formate/MeOH mixtures, we could enantioseparate four racemic N-acetyl amino acids, dichlorprop, and sixteen fluorescent 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate (AQC)-derivatized amino acids. Dressing and undressing of the coated F-CSPs could be controlled by varying the fluorophilicity and fluorophobicity of the eluent. The relative standard deviations of the retention times, the retention factors, the number of theoretical plates, the enantioseparation factors, and the resolutions of each of four preparations of such dress-up columns were all less than or equal to 5.26% (from 20 repeated analyses); the reproducibilities from four different preparations were all less than or equal to 10.6%. These columns also facilitated highly sensitive and selective analyses of AQC-amino acids when detected using LC-MS/MS.

  8. Perturbation analyses of intermolecular interactions.

    PubMed

    Koyama, Yohei M; Kobayashi, Tetsuya J; Ueda, Hiroki R

    2011-08-01

    Conformational fluctuations of a protein molecule are important to its function, and it is known that environmental molecules, such as water molecules, ions, and ligand molecules, significantly affect the function by changing the conformational fluctuations. However, it is difficult to systematically understand the role of environmental molecules because intermolecular interactions related to the conformational fluctuations are complicated. To identify important intermolecular interactions with regard to the conformational fluctuations, we develop herein (i) distance-independent and (ii) distance-dependent perturbation analyses of the intermolecular interactions. We show that these perturbation analyses can be realized by performing (i) a principal component analysis using conditional expectations of truncated and shifted intermolecular potential energy terms and (ii) a functional principal component analysis using products of intermolecular forces and conditional cumulative densities. We refer to these analyses as intermolecular perturbation analysis (IPA) and distance-dependent intermolecular perturbation analysis (DIPA), respectively. For comparison of the IPA and the DIPA, we apply them to the alanine dipeptide isomerization in explicit water. Although the first IPA principal components discriminate two states (the α state and PPII (polyproline II) + β states) for larger cutoff length, the separation between the PPII state and the β state is unclear in the second IPA principal components. On the other hand, in the large cutoff value, DIPA eigenvalues converge faster than that for IPA and the top two DIPA principal components clearly identify the three states. By using the DIPA biplot, the contributions of the dipeptide-water interactions to each state are analyzed systematically. Since the DIPA improves the state identification and the convergence rate with retaining distance information, we conclude that the DIPA is a more practical method compared with the

  9. Transport Studies Using Perturbative Experiments

    SciTech Connect

    Hogeweij, G.M.D.

    2004-03-15

    By inducing a small electron temperature perturbation in a plasma in steady state one can in principle determine the conductive and convective components of the electron heat ux, and the associated thermal diffusivity and convection velocity. The same can be done for other plasma parameters, like density or ion temperature.In this paper experimental and analysis techniques are briey reviewed. The fundamental question whether the uxes are linear functions of the gradients or not is discussed. Experimental results are summarized, including so-called 'non-local' phenomena.

  10. Perturbation analyses of intermolecular interactions

    NASA Astrophysics Data System (ADS)

    Koyama, Yohei M.; Kobayashi, Tetsuya J.; Ueda, Hiroki R.

    2011-08-01

    Conformational fluctuations of a protein molecule are important to its function, and it is known that environmental molecules, such as water molecules, ions, and ligand molecules, significantly affect the function by changing the conformational fluctuations. However, it is difficult to systematically understand the role of environmental molecules because intermolecular interactions related to the conformational fluctuations are complicated. To identify important intermolecular interactions with regard to the conformational fluctuations, we develop herein (i) distance-independent and (ii) distance-dependent perturbation analyses of the intermolecular interactions. We show that these perturbation analyses can be realized by performing (i) a principal component analysis using conditional expectations of truncated and shifted intermolecular potential energy terms and (ii) a functional principal component analysis using products of intermolecular forces and conditional cumulative densities. We refer to these analyses as intermolecular perturbation analysis (IPA) and distance-dependent intermolecular perturbation analysis (DIPA), respectively. For comparison of the IPA and the DIPA, we apply them to the alanine dipeptide isomerization in explicit water. Although the first IPA principal components discriminate two states (the α state and PPII (polyproline II) + β states) for larger cutoff length, the separation between the PPII state and the β state is unclear in the second IPA principal components. On the other hand, in the large cutoff value, DIPA eigenvalues converge faster than that for IPA and the top two DIPA principal components clearly identify the three states. By using the DIPA biplot, the contributions of the dipeptide-water interactions to each state are analyzed systematically. Since the DIPA improves the state identification and the convergence rate with retaining distance information, we conclude that the DIPA is a more practical method compared with the

  11. Chiral separation of new designer drugs (Cathinones) on chiral ion-exchange type stationary phases.

    PubMed

    Wolrab, Denise; Frühauf, Peter; Moulisová, Alena; Kuchař, Martin; Gerner, Christopher; Lindner, Wolfgang; Kohout, Michal

    2016-02-20

    We present the enantioseparation of new designer drugs from the cathinone family on structurally different chiral ion-exchange type stationary phases. A novel strong cation-exchange type chiral stationary phase was synthesized and its performance compared with previously reported ion-exchange type chiral stationary phases. The influence of structural elements of the chiral selectors on their chromatographic performance was studied and the possibilities of tuning chromatographic parameters by varying the polarity of the employed mobile phases were determined. Evidence is provided that a change in mobile phase composition strongly influences the solvation shell of the polarized and polarizable units of the selectors and analytes, as well as ionizable mobile phase additives. Furthermore, the structural features of the selectors (e.g. the size of aromatic units and their substitution pattern) are shown to play a key role in the effective formation of diastereomeric complexes with analytes. Thus, we have achieved the enantioseparation of all test analytes with a mass spectrometry-compatible mobile phase with a chiral strong cation-exchange type stationary phase.

  12. Simple chiral urea gelators, (R)- and (S)-2-heptylurea: their gelling ability enhanced by chirality.

    PubMed

    Kim, Jong-Uk; Schollmeyer, Dieter; Brehmer, Martin; Zentel, Rudolf

    2011-05-15

    We present the first report on the synthesis of chiral ureas, (R)- and (S)-2-heptylurea, and their gelling behaviors. The ureas were prepared by the reactions of chiral amines and phenyl carbamate in the presence of triethylamine. On cooling from homogeneous solutions, the chiral ureas form gels in water and various nonpolar organic solvents, such as cyclohexane, toluene, and tetrachloromethane, while the racemate gelatinize only toluene and tetrachloromethane among the solvents we examined. The gelling ability of the enantiomeric urea is higher than the racemate, as the critical gelling concentrations in toluene, for example, were 0.2% and 0.7% (wt/wt), respectively. The enhanced gelling ability of the enantiomeric ureas is due to the 1D supramolecular structure formed during gelation. In contrast, the racemate crystallizes into two-dimensional lamellae, where the (R)- and (S)-2-heptylurea exist alternatingly in a plane (P2(1)/c space group). Powder X-ray diffraction pattern of the enantiomeric urea showed that it has a different crystal lattice from that of the racemate, implying that the steric effect by the methyl group at the chiral center prevents the pure enantiomers from having 2D hydrogen bonding networks, which lead to sheet-like structures for the racemate and the achiral analog. Thus the pure enantiomers self-organize into one-dimensional fibrous structures. The simplicity and the ambidextrous gelling behaviors of the chiral ureas in forming both hydrogels and organogels present numerous possibilities for future applications. PMID:21396655

  13. Chiral assembly of weakly curled hard rods: Effect of steric chirality and polarity

    SciTech Connect

    Wensink, H. H. Morales-Anda, L.

    2015-10-14

    We theoretically investigate the pitch of lyotropic cholesteric phases composed of slender rods with steric chirality transmitted via a weak helical deformation of the backbone. In this limit, the model is amenable to analytical treatment within Onsager theory and a closed expression for the pitch versus concentration and helical shape can be derived. Within the same framework, we also briefly review the possibility of alternative types of chiral order, such as twist-bend or screw-like nematic phases, finding that cholesteric order dominates for weakly helical distortions. While long-ranged or “soft” chiral forces usually lead to a pitch decreasing linearly with concentration, steric chirality leads to a much steeper decrease of quadratic nature. This reveals a subtle link between the range of chiral intermolecular interaction and the pitch sensitivity with concentration. A much richer dependence on the thermodynamic state is revealed for polar helices where parallel and anti-parallel pair alignments along the local director are no longer equivalent. It is found that weak temperature variations may lead to dramatic changes in the pitch, despite the lyotropic nature of the assembly.

  14. Integration of inherent and induced chirality into subphthalocyanine analogue

    PubMed Central

    Zhao, Luyang; Qi, Dongdong; Wang, Kang; Wang, Tianyu; Han, Bing; Tang, Zhiyong; Jiang, Jianzhuang

    2016-01-01

    Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore. In this work, chiral binaphthyl segment is directly fused into the central chromophore of a subphthalocyanine skeleton, resulting in a novel type of chiral subphthalocyanine analogue (R/S)-1 of integrated inherent and induced chirality. Impressively, an obviously enhanced optical activity is discerned for (R/S)-1 molecules, and corresponding enhancement mechanism is elucidated in detail. The synthesis strategy based on rational molecular design will open the door towards fabrication of chiral materials with giant optical activity, which will have great potential in chiroptical devices. PMID:27294871

  15. Electrical magnetochiral anisotropy in a bulk chiral molecular conductor.

    PubMed

    Pop, Flavia; Auban-Senzier, Pascale; Canadell, Enric; Rikken, Geert L J A; Avarvari, Narcis

    2014-01-01

    So far, no effect of chirality on the electrical properties of bulk chiral conductors has been observed. Introduction of chiral information in tetrathiafulvalene precursors represents a powerful strategy towards the preparation of crystalline materials in which the combination of chirality and conducting properties might allow the observation of the electrical magnetochiral anisotropy effect. Here we report the synthesis by electrocrystallization of both enantiomers of a bulk chiral organic conductor based on an enantiopure tetrathiafulvalene derivative. The enantiomeric salts crystallize in enantiomorphic hexagonal space groups. Single crystal resistivity measurements show metallic behaviour for the enantiopure salts down to 40 K, in agreement with band structure calculations. We describe here the first experimental evidence of electrical magnetochiral anisotropy in these crystals, confirming the chiral character of charge transport in our molecular materials. PMID:24796572

  16. Detecting Chirality in Molecules by Linearly Polarized Laser Fields

    NASA Astrophysics Data System (ADS)

    Yachmenev, Andrey; Yurchenko, Sergei N.

    2016-07-01

    A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal anisotropic contributions to the electric polarizability tensor for two enantiomers have different signs. Exploiting this property, we are able to excite a coherent unidirectional rotation of two enantiomers with a π phase difference in the molecular electric dipole moment. The approach is robust and suitable for relatively high temperatures of molecular samples, making it applicable for selective chiral analysis of mixtures, and to chiral molecules with low barriers between enantiomers. As an illustration, we present nanosecond laser-driven dynamics of a tetratomic nonrigid chiral molecule with short-lived chirality. The ultrafast time scale of the proposed technique is well suited to study parity violation in molecular systems in short-lived chiral states.

  17. Progress of quartz crystal microbalance in chiral analysis.

    PubMed

    Guo, Huishi

    2014-02-01

    Chiral analysis is one of the most important/challenging analytical tasks due to the necessity for differentiation of very slight differences in the molecular configurations between chiral isomers. It consists of two processes, chiral recognition and signal transduction. Quartz crystal microbalance (QCM) holds a great promise for the next-generation sensors, due to its remarkable mass sensitivity, fast response, capable of online detection and low cost. It has been the focus of academic and practical research on chiral analysis during the last two decades. This review provides a detailed overview of recent advances made in chiral analysis based on QCM detection with regard to the recognition elements, which include synthetic macromolecules, molecular imprinting polymers (MIPs), proteins, amino acids and their derivatives, etc. The prospects of using QCM for chiral analysis are also put forward.

  18. Study of surface plasmon chirality induced by Archimedes' spiral grooves.

    PubMed

    Ohno, Tomoki; Miyanishi, Shintaro

    2006-06-26

    A chirality of surface plasmons excited on a silver film with Archimedes' spiral grooves during incidence of a circularly polarized light is analytically and numerically studied by using the finite-difference time-domain (FDTD) modeling method. We found that the surface of a plasmon has selective chirality, which is given by the sum of the chiralities of the incident light and the spiral structure. The surface plasmons with the chirality lead to zero-order, first-order, and high-order evanescent Bessel beams with electric charge distributions on the film. This selectivity could be widely applied for chiral detection of the incident light and chiral excitation of several optical modes in nanophotonics.

  19. Achiral flexible liquid crystal trimers exhibiting chiral conglomerates.

    PubMed

    Sasaki, Haruna; Takanishi, Yoichi; Yamamoto, Jun; Yoshizawa, Atsushi

    2016-04-14

    Chiral conglomerates of domains with opposite handedness have attracted much attention from researchers. We prepared a homologous series of achiral liquid crystal trimers in which two phenylpyrimidine units and one biphenyl unit were connected via flexible methylene spacers. We investigated their phase transition behaviour. Some trimers possessing odd-numbered spacers were found to exhibit a nematic phase and a dark chiral conglomerate phase possessing a layered structure. The chiral characteristics were confirmed by uncrossing the polarizers in opposite directions. The layer spacing detected using X-ray diffraction was about 80% of the molecular length. The structure-property relations indicate that intermolecular interactions cause a conformational change in the trimers possessing flexible odd-numbered methylene spacers to form helical conformers with axial chirality, which might induce chiral segregation and layer deformation to drive the chiral conglomerates.

  20. A molecular propeller effect for chiral separation and analysis

    NASA Astrophysics Data System (ADS)

    Clemens, Jonathon B.; Kibar, Osman; Chachisvilis, Mirianas

    2015-07-01

    Enantiomers share nearly identical physical properties but have different chiral geometries, making their identification and separation difficult. Here we show that when exposed to a rotating electric field, the left- and right-handed chiral molecules rotate with the field and act as microscopic propellers; moreover, owing to their opposite handedness, they propel along the axis of field rotation in opposite directions. We introduce a new molecular parameter called hydrodynamic chirality to characterize the coupling of rotational motion of a chiral molecule into its translational motion and quantify the direction and velocity of such motion. We demonstrate >80% enrichment level of counterpart enantiomers in solution without using chiral selectors or circularly polarized light. We expect our results to have an impact on multiple applications in drug discovery, analytical and chiral chemistry, including determination of absolute configuration, as well as in influencing the understanding of artificial and natural molecular systems where rotational motion of the molecules is involved.

  1. Development of chiral sulfoxide ligands for asymmetric catalysis.

    PubMed

    Trost, Barry M; Rao, Meera

    2015-04-20

    Nitrogen-, phosphorus-, and oxygen-based ligands with chiral backbones have been the historic workhorses of asymmetric transition-metal-catalyzed reactions. On the contrary, sulfoxides containing chirality at the sulfur atom have mainly been used as chiral auxiliaries for diastereoselective reactions. Despite several distinct advantages over traditional ligand scaffolds, such as the proximity of the chiral information to the metal center and the ability to switch between S and O coordination, these compounds have only recently emerged as a versatile class of chiral ligands. In this Review, we detail the history of the development of chiral sulfoxide ligands for asymmetric catalysis. We also provide brief descriptions of metal-sulfoxide bonding and strategies for the synthesis of enantiopure sulfoxides. Finally, insights into the future development of this underutilized ligand class are discussed.

  2. Detecting Chirality in Molecules by Linearly Polarized Laser Fields.

    PubMed

    Yachmenev, Andrey; Yurchenko, Sergei N

    2016-07-15

    A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal anisotropic contributions to the electric polarizability tensor for two enantiomers have different signs. Exploiting this property, we are able to excite a coherent unidirectional rotation of two enantiomers with a π phase difference in the molecular electric dipole moment. The approach is robust and suitable for relatively high temperatures of molecular samples, making it applicable for selective chiral analysis of mixtures, and to chiral molecules with low barriers between enantiomers. As an illustration, we present nanosecond laser-driven dynamics of a tetratomic nonrigid chiral molecule with short-lived chirality. The ultrafast time scale of the proposed technique is well suited to study parity violation in molecular systems in short-lived chiral states. PMID:27472111

  3. A molecular propeller effect for chiral separation and analysis

    PubMed Central

    Clemens, Jonathon B.; Kibar, Osman; Chachisvilis, Mirianas

    2015-01-01

    Enantiomers share nearly identical physical properties but have different chiral geometries, making their identification and separation difficult. Here we show that when exposed to a rotating electric field, the left- and right-handed chiral molecules rotate with the field and act as microscopic propellers; moreover, owing to their opposite handedness, they propel along the axis of field rotation in opposite directions. We introduce a new molecular parameter called hydrodynamic chirality to characterize the coupling of rotational motion of a chiral molecule into its translational motion and quantify the direction and velocity of such motion. We demonstrate >80% enrichment level of counterpart enantiomers in solution without using chiral selectors or circularly polarized light. We expect our results to have an impact on multiple applications in drug discovery, analytical and chiral chemistry, including determination of absolute configuration, as well as in influencing the understanding of artificial and natural molecular systems where rotational motion of the molecules is involved. PMID:26216219

  4. Emergence of Chirality from Isotropic Interactions of Three Length Scales

    NASA Astrophysics Data System (ADS)

    Mkhonta, S. K.; Elder, K. R.; Huang, Zhi-Feng

    2016-05-01

    Chirality is known to play a pivotal role in determining material properties and functionalities. However, it remains a great challenge to understand and control the emergence of chirality and the related enantioselective process particularly when the building components of the system are achiral. Here we explore the generic mechanisms driving the formation of two-dimensional chiral structures in systems characterized by isotropic interactions and three competing length scales. We demonstrate that starting from isotropic and rotationally invariant interactions, a variety of chiral ordered patterns and superlattices with anisotropic but achiral units can self-assemble. The mechanisms for selecting specific states are related to the length-scale coupling and the selection of resonant density wave vectors. Sample phase diagrams and chiral elastic properties are identified. These findings provide a viable route for predicting chiral phases and selecting the desired handedness.

  5. Supramolecular chirality in self-assembled peptide amphiphile nanostructures.

    PubMed

    Garifullin, Ruslan; Guler, Mustafa O

    2015-08-11

    Induced supramolecular chirality was investigated in the self-assembled peptide amphiphile (PA) nanosystems. Having shown that peptide chirality can be transferred to the covalently-attached achiral pyrene moiety upon PA self-assembly, the chiral information is transferred to molecular pyrene via weak noncovalent interactions. In the first design of a supramolecular chiral system, the chromophore was covalently attached to a peptide sequence (VVAGH) via an ε-aminohexanoic acid spacer. Covalent attachment yielded a PA molecule self-assembling into nanofibers. In the second design, the chromophore was encapsulated within the hydrophobic core of self-assembled nanofibers of another PA consisting of the same peptide sequence attached to lauric acid. We observed that supramolecular chirality was induced in the chromophore by PA assembly into chiral nanostructures, whether it was covalently attached, or noncovalently bound. PMID:26146021

  6. Generation of chiral spin state by quantum simulation

    NASA Astrophysics Data System (ADS)

    Tanamoto, Tetsufumi

    2016-06-01

    Chirality of materials in nature appears when there are asymmetries in their lattice structures or interactions in a certain environment. Recent development of quantum simulation technology has enabled the manipulation of qubits. Accordingly, chirality can be realized intentionally rather than passively observed. Here we theoretically provide simple methods to create a chiral spin state in a spin-1/2 qubit system on a square lattice. First, we show that switching on and off the Heisenberg and X Y interactions produces the chiral interaction directly in the effective Hamiltonian without controlling local fields. Moreover, when initial states of spin qubits are appropriately prepared, we prove that the chirality with desirable phase is dynamically obtained. Finally, even for the case where switching on and off the interactions is infeasible and the interactions are always on, we show that, by preparing an asymmetric initial qubit state, the chirality whose phase is π /2 is dynamically generated.

  7. Self-shaping of bioinspired chiral composites

    NASA Astrophysics Data System (ADS)

    Rong, Qing-Qing; Cui, Yu-Hong; Shimada, Takahiro; Wang, Jian-Shan; Kitamura, Takayuki

    2014-08-01

    Self-shaping materials such as shape memory polymers have recently drawn considerable attention owing to their high shape-changing ability in response to changes in ambient conditions, and thereby have promising applications in the biomedical, biosensing, soft robotics and aerospace fields. Their design is a crucial issue of both theoretical and technological interest. Motivated by the shape-changing ability of Towel Gourd tendril helices during swelling/deswelling, we present a strategy for realizing self-shaping function through the deformation of micro/nanohelices. To guide the design and fabrication of self-shaping materials, the shape equations of bent configurations, twisted belts, and helices of slender chiral composite are developed using the variation method. Furthermore, it is numerically shown that the shape changes of a chiral composite can be tuned by the deformation of micro/nanohelices and the fabricated fiber directions. This work paves a new way to create self-shaping composites.

  8. New approaches in sensitive chiral CE.

    PubMed

    Sánchez-Hernández, Laura; Guijarro-Diez, Miguel; Marina, María Luisa; Crego, Antonio L

    2014-01-01

    CE has shown to have a big potential for chiral separations, with advantages such as high efficiency, high resolution, and low sample and reagents consumption. Nevertheless, when UV detection is employed, CE has some drawbacks, especially the low sensitivity obtained due to the short optical path length. Notwithstanding, sensitivity improvements can be achieved when different approaches are employed, such as sample treatment strategies (off-line or on-line), in-capillary sample preconcentration techniques, and/or alternative detection systems to UV-Vis (such as fluorescence, conductimetry, electrochemiluminiscence, MS, etc.). This article reviews the most recent methodological and instrumental advances reported from June 2011 to May 2013 for enhancing the sensitivity in chiral analysis by CE. The sensitivity achieved for the enantioseparated analytes and the applications carried out using the developed methodologies are also summarized.

  9. Active control of chirality in nonlinear metamaterials

    SciTech Connect

    Zhu, Yu; Chai, Zhen; Yang, Hong; Hu, Xiaoyong Gong, Qihuang

    2015-03-02

    An all-optical tunabe chirality is realized in a photonic metamaterial, the metamolecule of which consists of a nonlinear nano-Au:polycrystalline indium-tin oxide layer sandwiched between two L-shaped gold nano-antennas twisted 90° with each other. The maximum circular dichroism reached 30%. Under excitation of a 40 kW/cm{sup 2} weak pump light, the peak in the circular dichroism shifts 45 nm in the short-wavelength direction. An ultrafast response time of 35 ps is maintained. This work not only opens up the possibility for the realization of ultralow-power and ultrafast all-optical tunable chirality but also offers a way to construct ultrahigh-speed on-chip biochemical sensors.

  10. Nonperturbative Regulator for Chiral Gauge Theories?

    PubMed

    Grabowska, Dorota M; Kaplan, David B

    2016-05-27

    We propose a nonperturbative gauge-invariant regulator for d-dimensional chiral gauge theories on the lattice. The method involves simulating domain wall fermions in d+1 dimensions with quantum gauge fields that reside on one d-dimensional surface and are extended into the bulk via gradient flow. The result is a theory of gauged fermions plus mirror fermions, where the mirror fermions couple to the gauge fields via a form factor that becomes exponentially soft with the separation between domain walls. The resultant theory has a local d-dimensional interpretation only if the chiral fermion representation is anomaly free. A physical realization of this construction would imply the existence of mirror fermions in the standard model that are invisible except for interactions induced by vacuum topology, and which could gravitate differently than conventional matter. PMID:27284646

  11. Imprintable membranes from incomplete chiral coalescence

    NASA Astrophysics Data System (ADS)

    Zakhary, Mark J.; Gibaud, Thomas; Nadir Kaplan, C.; Barry, Edward; Oldenbourg, Rudolf; Meyer, Robert B.; Dogic, Zvonimir

    2014-01-01

    Coalescence is an essential phenomenon that governs the equilibrium behaviour in a variety of systems from intercellular transport to planetary formation. In this report, we study coalescence pathways of circularly shaped two-dimensional colloidal membranes, which are one rod-length-thick liquid-like monolayers of aligned rods. The chirality of the constituent rods leads to three atypical coalescence pathways that are not found in other simple or complex fluids. In particular, we characterize two pathways that do not proceed to completion but instead produce partially joined membranes connected by line defects—π-wall defects or alternating arrays of twisted bridges and pores. We elucidate the structure and energetics of these defects and ascribe their stability to a geometrical frustration inherently present in chiral colloidal membranes. Furthermore, we induce the coalescence process with optical forces, leading to a robust on-demand method for imprinting networks of channels and pores into colloidal membranes.

  12. On Gauge Independent Dynamical Chiral Symmetry Breaking

    SciTech Connect

    Bashir, A.; Raya, A.

    2006-09-25

    Schwinger-Dyson equations (SDEs) are an ideal framework to study nonperturbative phenomena such as dynamical chiral symmetry breaking (DCSB). Loss of gauge invariance is an obstacle to achieve fully reliable predictions from these equations. In addition to Ward-Green-Takahashi identity (WGTI), Landau-Khalatnikov-Fradkin transformations (LKFT) also play an important role in restoring the said invariance at the level of physical observables. On one hand, they impose useful constraints on the transverse part of the fermion-boson vertex and on the other, they govern the change in dynamically generated fermion propagator with a variation of gauge. We consider the latter in this article and study the gauge (in)dependence of chiral condensate in quantum electrodynamics in (2+1) space-time dimensions (QED3)

  13. Chiral patterning in Paenibacillus colonies under stress

    NASA Astrophysics Data System (ADS)

    Levine, Herbert

    2012-02-01

    One of the most striking examples of bacterial colony patterning occurs in the C-morphotype of Paenibacillus strains. Here, macroscopic chirality results from the interaction of local liquid-crystal ordering of the long bacterial cells with the self-propelled motility driven by the non-reflection-symmetric flagella. This talk will review some of the original experimental data from the Ben-Jacob lab as well as recent insight obtained via genomics. I will then discuss attempts to model and simulate the chiral patterns via solving reaction-diffusion equations on random lattices. At the end, I will introduce the challenges still to be faced in understanding transitions between these patterns and more common branching structures

  14. Optical tractor beam with chiral light

    NASA Astrophysics Data System (ADS)

    Fernandes, David E.; Silveirinha, Mário G.

    2015-06-01

    We suggest a novel mechanism to induce the motion of a chiral material body towards an optical source with no optical traps. Our solution is based on the interference between a chiral light beam and its reflection on an opaque mirror. Surprisingly, it is theoretically shown that the electromagnetic response of the material may be tailored in such a way that independent of the specific body location with respect to the mirror, it is always pulled upstream against the photon flow associated with the incoming wave. Moreover, it is proven that by controlling the handedness of the incoming light it may be possible to harness the sign of the optical force, switching from a pulling force to a pushing force.

  15. Check for chirality in {sup 102}Rh

    SciTech Connect

    Tonev, D.; Goutev, N.; Yavahchova, M. S.; Petkov, P.; Angelis, G. de; Bhowmik, R. K.; Singh, R. P.; Muralithar, S.; Madhavan, N.; Kumar, R.; Raju, M. Kumar; Kaur, J.; Mahanto, G.; Singh, A.; Kaur, N.; Garg, R.; Sukla, A.; Marinov, Ts. K.; Brant, S.

    2012-10-20

    Excited states in {sup 102}Rh, populated by the fusion-evaporation reaction {sup 94}Zr({sup 11}B,3n){sup 102}Rh at a beam energy of 36 MeV, were studied using the INGA spectrometer at IUAC, New Delhi. The angular correlations and the electromagnetic character of some of the gamma-ray transitions observed were investigated in details. A new chiral candidate sister band was found in the level-scheme of {sup 102}Rh. Lifetimes of exited states in {sup 102}Rh were measured by means of the Doppler-shift attenuation technique. The experimental results do not support the presence of static chirality in {sup 102}Rh.

  16. Chiral meta-atoms rotated by light

    SciTech Connect

    Liu Mingkai; Powell, David A.; Shadrivov, Ilya V.

    2012-07-16

    We study the opto-mechanical properties of coupled chiral meta-atoms based on a pair of twisted split-ring resonators. By using a simple analytical model in conjunction with the Maxwell stress tensor, we capture insight into the mechanism and find that this structure can be used as a general prototype of subwavelength light-driven actuators over a wide range of frequencies. This coupled structure can provide a strong and tunable torque, and can support different opto-mechanical modes, including uniform rotation, periodically variable rotation and damped oscillations. Our results suggest that chiral meta-atoms are good candidates for creating sub-wavelength motors or wrenches controlled by light.

  17. Chiral fermions as classical massless spinning particles

    NASA Astrophysics Data System (ADS)

    Duval, C.; Horváthy, P. A.

    2015-02-01

    Semiclassical chiral fermion models with Berry term are studied in a symplectic framework. In the free case, the system can be obtained from Souriau's model for a relativistic massless spinning particle by "enslaving" the spin. The Berry term is identified with the classical spin two-form of the latter model. The Souriau model carries a natural Poincaré symmetry that we highlight, but spin enslavement breaks the boost symmetry. However the relation between the models allows us to derive a Poincaré symmetry of unconventional form for chiral fermions. Then we couple our system to an external electromagnetic field. For gyromagnetic ratio g =0 we get curious superluminal Hall-type motions; for g =2 and in a pure constant magnetic field in particular, we find instead spiraling motions.

  18. Absence of equilibrium chiral magnetic effect

    NASA Astrophysics Data System (ADS)

    Zubkov, M. A.

    2016-05-01

    We analyze the (3 +1 )D equilibrium chiral magnetic effect (CME). We apply derivative expansion to the Wigner transform of the two-point Green function. This technique allows us to express the response of electric current to the external electromagnetic field strength through the momentum space topological invariant. We consider the wide class of the lattice regularizations of quantum field theory (that includes, in particular, the regularization with Wilson fermions) and also certain lattice models of solid state physics (including those of Dirac semimetals). It appears that in these models the mentioned topological invariant vanishes identically at nonzero chiral chemical potential. That means that the bulk equilibrium CME is absent in those systems.

  19. Oscillating chiral tensor spectrum from axionic inflation

    NASA Astrophysics Data System (ADS)

    Obata, Ippei; Soda, Jiro

    2016-08-01

    We study axionic inflation with a modulated potential and examine if the primordial tensor power spectrum exhibits oscillatory feature, which is testable with future space-based gravitational-wave experiments such as DECIGO and BBO. In the case of single-field axion monodromy inflation, it turns out that it is difficult to detect an oscillation in the spectrum due to the suppression of the sub-Planckian decay constant of the axion. On the other hand, in the case of aligned chromo-natural inflation where the axion is coupled to a SU(2) gauge field, it turns out that a sizable oscillation in the tensor spectrum can occur due to the enhancement of chiral gravitational waves sourced by the gauge field. We expect that this feature will be a new probe for axion phenomenologies in the early Universe through chiral gravitational waves.

  20. Terahertz chiral metamaterials with giant and dynamically tunable optical activity

    SciTech Connect

    Zhou, Jiangfeng; Chowdhury, Dibakar Roy; Zhao, Rongkuo; Azad, Abul K.; Chen, Hou-Tong; Soukoulis, Costas M.; Taylor, Antoinette J.; O'Hara, John F.

    2012-07-27

    We demonstrated giant optical activity using a chiral metamaterial composed of an array of conjugated bilayer metal structures. The chiral metamaterials were further integrated with photoactive inclusions to accomplish a wide tuning range of the optical activity through illumination with near-infrared light. The strong chirality observed in our metamaterials results in a negative refractive index, which can also be well controlled by the near-infrared optical excitation.