On the measurement of the crack tip stress field as a means of determining Delta K(sub eff) under conditions of fatigue crack closure

NASA Technical Reports Server (NTRS)

Wallhead, Ian R.; Edwards, Lyndon; Poole, Peter

1994-01-01

The optical method of caustics has been successfully extended to enable stress intensity factors as low as 1MPa square root of m to be determined accurately for central fatigue cracks in 2024-T3 aluminium alloy test panels. The feasibility of using this technique to study crack closure, and to determine the effective stress intensity factor range, Delta K(sub eff), has been investigated. Comparisons have been made between the measured values of stress intensity factor, K(sub caus), and corresponding theoretical values, K(sub theo), for a range of fatigue cracks grown under different loading conditions. The values of K(sub caus) and K(sub theo) were in good agreement at maximum stress, where the cracks are fully open, while K(sub caus) exceeded K(sub theo) at minimum stress, due to crack closure. However, the levels of crack closure and values of Delta K(sub eff) obtained could not account for the variations of crack growth rate with loading conditions. It is concluded that the values of Delta K(sub eff), based on caustic measurements in a 1/square root of r stress field well outside the plastic zone, do not fully reflect local conditions which control crack tip behavior.

Tuning exchange bias in Fe/γ-Fe{sub 2}O{sub 3} core-shell nanoparticles: Impacts of interface and surface spins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khurshid, Hafsa, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu; Phan, Manh-Huong, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu; Mukherjee, Pritish

A comparative study has been performed of the exchange bias (EB) effect in Fe/γ-Fe{sub 2}O{sub 3} core-shell nanoparticles with the same thickness of the γ-Fe{sub 2}O{sub 3} shell (∼2 nm) and the diameter of the Fe core varying from 4 nm to 11 nm. Transmission electron microscopy (TEM) and high-resolution TEM confirmed the high quality of the core-shell nanostructures. A systematic analysis of magnetization versus magnetic field measurements under zero-field-cooled and field-cooled regimes using the Meiklejohn-Bean model and deconvoluting superparamagnetic and paramagnetic contribution to the total magnetic moment Langevin function shows that there exists a critical particle size (∼10 nm), above which the spinsmore » at the interface between Fe and γ-Fe{sub 2}O{sub 3} contribute primarily to the EB, but below which the surface spin effect is dominant. Our finding yields deeper insight into the collective contributions of interface and surface spins to the EB in core-shell nanoparticle systems, knowledge of which is the key to manipulating EB in magnetic nanostructures for spintronics applications.« less

THE ASTROPHYSICAL IMPLICATIONS OF DUST FORMATION DURING THE ERUPTIONS OF HOT, MASSIVE STARS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kochanek, C. S.

2011-12-10

Dust formation in the winds of hot stars is inextricably linked to the classic eruptive state of luminous blue variables because it requires very high mass-loss rates, M-dot {approx}>10{sup -2.5} M{sub sun} year{sup -1}, for grains to grow and for the non-dust optical depth of the wind to shield the dust formation region from the true stellar photosphere. Thus, dusty shells around hot stars trace the history of 'great' eruptions, and the statistics of such shells in the Galaxy indicate that these eruptions are likely the dominant mass-loss mechanism for evolved, M{sub ZAMS} {approx}> 40 M{sub Sun} stars. Dust formationmore » at such high M-dot also explains why very large grains (a{sub max} {approx}> 1 {mu}m) are frequently found in these shells, since a{sub max}{proportional_to} M-dot . The statistics of these shells (numbers, ages, masses, and grain properties such as a{sub max}) provide an archaeological record of this mass-loss process. In particular, the velocities v{sub shell}, transient durations (where known), and ejected masses M{sub shell} of the Galactic shells and the supernova (SN) 'impostors' proposed as their extragalactic counterparts are very different. While much of the difference is a selection effect created by shell lifetimes {proportional_to}(v{sub shell}{radical}(M{sub shell})){sup -1}, more complete Galactic and extragalactic surveys are needed to demonstrate that the two phenomena share a common origin given that their observed properties are essentially disjoint. If even small fractions (1%) of SNe show interactions with such dense shells of ejecta, as is currently believed, then the driving mechanism of the eruptions must be associated with the very final phases of stellar evolution, suggestive of some underlying nuclear burning instability.« less

Dielectronic recombination of the 4p and 4d open sub-shell tungsten ions

NASA Astrophysics Data System (ADS)

Li, M. J.; Fu, Y. B.; Zhang, G. D.; Zhang, Y. Z.; Dong, C. Z.; Koike, F.

2014-04-01

Dielectronic recombination rate coefficients are given theoretically for several highly charged tungsten ions. As 4p open sub-shell ions, Ga-, Ge-, As-, Br-, Kr-like ions are considered. Rb-like ion is further considered as a 4d open sub-shell ion. Theoretical calculations are carried out using a relativistic atomic code FAC. The effect of configuration interaction is taking into account. Inner-shell electron excitations play a significant role for the dielectronic recombination process. Simple analytical formulae are given for the total rate coefficients by fitting to the presently obtained numerical results.

L-shell x-ray production cross sections in Nd, Gd, Ho, Yb, Au and Pb for 25-MeV carbon and 32-MeV oxygen ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andrews, M.C.; McDaniel, F.D.; Duggan, J.L.

1984-01-01

L-shell x-ray production cross sections in /sub 60/Nd, /sub 64/Gd, /sub 67/Ho, /sub 70/Yb, /sub 79/Au and /sub 82/Pb have been measured for incident 25 MeV /sub 6//sup 12/C/sup +q/(q = 4,5,6) and 32 MeV /sub 8//sup 16/O/sup +q/(q = 5,7,8) ions. Measurements were made on targets ranging in thickness from 1 to 100 ..mu..g/cm/sup 2/. Echancement in the L-shell x-ray production cross section for projectiles with one or two K-shell vacancies over those for projectiles with no K-shell vacancies is observed. The sum of direct ionization to the continuum (DI) plus electron capture (EC) to the L,M,N ... shellsmore » and EC to the K-shell of the projectile have been extracted from the data. Calculations in the first Born approximation are approx. 10 times larger than the data. Predictions of the ECPSSR theory that accounts for the energy-loss, Coulomb deflection, perturbed-stationary state, and relativistic effects are in good agreement with the data for both ions.« less

B(E2)↑ Measurements for Radioactive Neutron-Rich Ge Isotopes: Reaching the N=50 Closed Shell

NASA Astrophysics Data System (ADS)

Padilla-Rodal, E.; Galindo-Uribarri, A.; Baktash, C.; Batchelder, J. C.; Beene, J. R.; Bijker, R.; Brown, B. A.; Castaños, O.; Fuentes, B.; del Campo, J. Gomez; Hausladen, P. A.; Larochelle, Y.; Lisetskiy, A. F.; Mueller, P. E.; Radford, D. C.; Stracener, D. W.; Urrego, J. P.; Varner, R. L.; Yu, C.-H.

2005-03-01

The B(E2;0+1→2+1) values for the radioactive neutron-rich germanium isotopes 78,80Ge and the closed neutron shell nucleus 82Ge were measured at the HRIBF using Coulomb excitation in inverse kinematics. These data allow a study of the systematic trend between the subshell closures at N=40 and 50. The B(E2) behavior approaching N=50 is similar to the trend observed for heavier isotopic chains. A comparison of the experimental results with a shell model calculation demonstrates persistence of the N=50 shell gap and a strong sensitivity of the B(E2) values to the effective interaction.

New nuclear structure data beyond 136Sn

NASA Astrophysics Data System (ADS)

Lozeva, Radomira

2018-05-01

Exotic nuclei beyond the 132Sn double shell-closure are influenced by both the Sn superfluity and the evolving collectivity only few nucleons away. Toward even more neutron-rich nuclei, especially at intermediate mass number, the interplay between single-particle and collective particle-hole excitations competes. In some cases with the extreme addition of neutrons also other effects as the formation of neutron skin, stabilization as sub-shell gaps or orbital crossings may be expected. The knowledge of nuclear ingredients is especially interesting beyond 132Sn and little is known on how the excitation modes develop with the addition of both protons and neutrons and for example systematic prompt and decay studies can be such very sensitive probe. Recently, we have approached this region of nuclei in several experimental measurements following 238U projectile fission on 9Be and n-induced fission on 241Pu and 235U. Consistent data analysis allows to access various spins and excitation energies and provide new input to theory. Examples from these studies on several nuclei in the A 140 region were presented during the conference together with the possible interpretation of the new data. Here, we will illustrate one example on 136I using two complementary data sets.

One-Neutron Removal Measurement Reveals {sup 24}O as a New Doubly Magic Nucleus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kanungo, R.; Perro, C.; Nociforo, C.

The first measurement of the momentum distribution for one-neutron removal from {sup 24}O at 920A MeV performed at GSI, Darmstadt is reported. The observed distribution has a width (FWHM) of 99{+-}4 MeV/c in the projectile rest frame and a one-neutron removal cross section of 63{+-}7 mb. The results are well explained with a nearly pure 2s{sub 1/2} neutron spectroscopic factor of 1.74{+-}0.19 within the eikonal model. This large s-wave probability shows a spherical shell closure thereby confirming earlier suggestions that {sup 24}O is a new doubly magic nucleus.

Neutrinoless double-β decay of 48Ca in the shell model: Closure versus nonclosure approximation

NASA Astrophysics Data System (ADS)

Sen'kov, R. A.; Horoi, M.

2013-12-01

Neutrinoless double-β decay (0νββ) is a unique process that could reveal physics beyond the Standard Model. Essential ingredients in the analysis of 0νββ rates are the associated nuclear matrix elements. Most of the approaches used to calculate these matrix elements rely on the closure approximation. Here we analyze the light neutrino-exchange matrix elements of 48Ca 0νββ decay and test the closure approximation in a shell-model approach. We calculate the 0νββ nuclear matrix elements for 48Ca using both the closure approximation and a nonclosure approach, and we estimate the uncertainties associated with the closure approximation. We demonstrate that the nonclosure approach has excellent convergence properties which allow us to avoid unmanageable computational cost. Combining the nonclosure and closure approaches we propose a new method of calculation for 0νββ decay rates which can be applied to the 0νββ decay rates of heavy nuclei, such as 76Ge or 82Se.

Contributions from inner and outer shell electron energies to reaction heats for C/sub 1/, C/sub 2/, and C/sub 3/ hydrocarbons

DOE Office of Scientific and Technical Information (OSTI.GOV)

George, P.; Bock, C.W.; Trachtman, M.

1979-04-01

The expectation energy values E/sub k/, V/sub ee/, V/sub nn/, V/sub en/, and E/sub T/ have been calculated for H/sub 2/ and the C/sub 1/, C/sub 2/, and C/sub 3/ hydrocarbons using a (9,5) basis set and the experimental geometries. Treating the theoretical reaction heat, ..delta..E/sub T/, as the resultant of the nuclear repulsion term, ..delta..V/sub nn/, and the net electron energy term, ..delta..E/sub elec/ = ..delta..E/sub k/ + ..delta..V/sub ee/ + ..delta..V/sub en/, the contribution of inner and outer shell electron energies to ..delta..E/sub elec/, and hence to ..delta..E/sub T/, has been calculated for a large number of hydrocarbonmore » reactions by evaluating the Coulson--Neilson energies eta/sub i/, where eta/sub i/ = E/sub elec/. For the vast majority of reactions, 67/84, the change in inner shell electron energy, (..delta sigma..eta/sub i/)/sub inner/, accounts for more than 10% of ..delta..E/sub elec/, in many cases being as high as 20-35%. Furthermore, in addition to these cases in which the change in inner shell electron energy serves to augment (significantly) the change in outer shell electron energy, there are other cases in which the change in inner shell electron energy either exceeds in magnitude the change in outer shell energy, or is even opposite in sign, indicative of inner and outer shell electrons acting contrariwise. Inner shell electron energies contribute to the reaction heats because they are structure dependent, like the more familiar orbital energies epsilon, but the dependence is of a different kind.« less

Recent Direct Reaction Experimental Studies with Radioactive Tin Beams

DOE PAGES

Jones, K. L.; Ahn, S.; Allmond, J. M.; ...

2015-01-01

Direct reaction techniques are powerful tools to study the single-particle nature of nuclei. Performing direct reactions on short-lived nuclei requires radioactive ion beams produced either via fragmentation or the Isotope Separation OnLine (ISOL) method. Some of the most interesting regions to study with direct reactions are close to the magic numbers where changes in shell structure can be tracked. These changes can impact the final abundances of explosive nucleosynthesis. The structure of the chain of tin isotopes is strongly influenced by the Z = 50 proton shell closure, as well as the neutron shell closures lying in the neutron-rich, Nmore » = 82, and neutron-deficient, N = 50, regions. Here, we present two examples of direct reactions on exotic tin isotopes. The first uses a one-neutron transfer reaction and a low-energy reaccelerated ISOL beam to study states in Sn-131 from across the N = 82 shell closure. The second example utilizes a one-neutron knockout reaction on fragmentation beams of neutron-deficient Sn- 106,108Sn. In conclusion, In both cases, measurements of γ rays in coincidence with charged particles proved to be invaluable.« less

Glass shell manufacturing in space

NASA Technical Reports Server (NTRS)

Downs, R. L.; Ebner, M. A.; Nolen, R. L., Jr.

1981-01-01

Highly-uniform, hollow glass spheres (shells), which are used for inertial confinement fusion targets, were formed from metal-organic gel powder feedstock in a vertical furnace. As a result of the rapid pyrolysis caused by the furnace, the gel is transformed to a shell in five distinct stages: (a) surface closure of the porous gel; (b) generation of a closed-cell foam structure in the gel; (c) spheridization of the gel and further expansion of the foam; (d) coalescence of the closed-cell foam to a single-void shell; and (e) fining of the glass shell. The heat transfer from the furnace to the falling gel particle was modeled to determine the effective heating rate of the gel. The model predicts the temperature history for a particle as a function of mass, dimensions, specific heat, and absorptance as well as furnace temperature profile and thermal conductivity of the furnace gas. A model was developed that predicts the gravity-induced degradation of shell concentricity in falling molten shells as a function of shell characteristics and time.

Summary of Group Development and Testing for Single Shell Tank Closure at Hanford

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harbour, John, R.

2005-04-28

This report is a summary of the bench-scale and large scale experimental studies performed by Savannah River National Laboratory for CH2M HILL to develop grout design mixes for possible use in producing fill materials as a part of Tank Closure of the Single-Shell Tanks at Hanford. The grout development data provided in this report demonstrates that these design mixes will produce fill materials that are ready for use in Hanford single shell tank closure. The purpose of this report is to assess the ability of the proposed grout specifications to meet the current requirements for successful single shell tank closuremore » which will include the contracting of services for construction and operation of a grout batch plant. The research and field experience gained by SRNL in the closure of Tanks 17F and 20F at the Savannah River Site was leveraged into the grout development efforts for Hanford. It is concluded that the three Hanford grout design mixes provide fill materials that meet the current requirements for successful placement. This conclusion is based on the completion of recommended testing using Hanford area materials by the operators of the grout batch plant. This report summarizes the regulatory drivers and the requirements for grout mixes as tank fill material. It is these requirements for both fresh and cured grout properties that drove the development of the grout formulations for the stabilization, structural and capping layers.« less

Structural and electrical properties of TiO{sub 2}/ZnO core–shell nanoparticles synthesized by hydrothermal method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vlazan, P.; Ursu, D.H.; Irina-Moisescu, C.

TiO{sub 2}/ZnO core–shell nanoparticles were successfully synthesized by hydrothermal method in two stages: first stage is the hydrothermal synthesis of ZnO nanoparticles and second stage the obtained ZnO nanoparticles are encapsulated in TiO{sub 2}. The obtained ZnO, TiO{sub 2} and TiO{sub 2}/ZnO core–shell nanoparticles were investigated by means of X-ray diffraction, transmission electron microscopy, Brunauer, Emmett, Teller and resistance measurements. X-ray diffraction analysis revealed the presence of both, TiO{sub 2} and ZnO phases in TiO{sub 2}/ZnO core–shell nanoparticles. According to transmission electron microscopy images, ZnO nanoparticles have hexagonal shapes, TiO{sub 2} nanoparticles have a spherical shape, and TiO{sub 2}/ZnO core–shellmore » nanoparticles present agglomerates and the shape of particles is not well defined. The activation energy of TiO{sub 2}/ZnO core–shell nanoparticles was about 101 meV. - Graphical abstract: Display Omitted - Highlights: • TiO{sub 2}/ZnO core–shell nanoparticles were synthesized by hydrothermal method. • TiO{sub 2}/ZnO core–shell nanoparticles were investigated by means of XRD, TEM and BET. • Electrical properties of TiO{sub 2}/ZnO core–shell nanoparticles were investigated. • The activation energy of TiO{sub 2}/ZnO core–shell nanoparticles was about E{sub a} = 101 meV.« less

Electronic properties of core-shell nanowire resonant tunneling diodes

PubMed Central

2014-01-01

The electronic sub-band structure of InAs/InP/InAs/InP/InAs core-shell nanowire resonant tunneling diodes has been investigated in the effective mass approximation by varying the core radius and the thickness of the InP barriers and InAs shells. A top-hat, double-barrier potential profile and optimal energy configuration are obtained for core radii and surface shells >10 nm, InAs middle shells <10 nm, and 5 nm InP barriers. In this case, two sub-bands exist above the Fermi level in the InAs middle shell which belongs to the m = 0 and m = 1 ladder of states that have similar wave functions and energies. On the other hand, the lowest m = 0 sub-band in the core falls below the Fermi level but the m = 1 states do not contribute to the current transport since they reside energetically well above the Fermi level. We compare the case of GaAs/AlGaAs/GaAs/AlGaAs/GaAs which may conduct current with smaller applied voltages due to the larger effective mass of electrons in GaAs and discuss the need for doping. PMID:25288912

Electronic properties of core-shell nanowire resonant tunneling diodes.

PubMed

Zervos, Matthew

2014-01-01

The electronic sub-band structure of InAs/InP/InAs/InP/InAs core-shell nanowire resonant tunneling diodes has been investigated in the effective mass approximation by varying the core radius and the thickness of the InP barriers and InAs shells. A top-hat, double-barrier potential profile and optimal energy configuration are obtained for core radii and surface shells >10 nm, InAs middle shells <10 nm, and 5 nm InP barriers. In this case, two sub-bands exist above the Fermi level in the InAs middle shell which belongs to the m = 0 and m = 1 ladder of states that have similar wave functions and energies. On the other hand, the lowest m = 0 sub-band in the core falls below the Fermi level but the m = 1 states do not contribute to the current transport since they reside energetically well above the Fermi level. We compare the case of GaAs/AlGaAs/GaAs/AlGaAs/GaAs which may conduct current with smaller applied voltages due to the larger effective mass of electrons in GaAs and discuss the need for doping.

Magnetically separable {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-Ce-doped TiO{sub 2} core-shell nanocomposites: Fabrication and visible-light-driven photocatalytic activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Minqiang, E-mail: jbmwgkc@126.com; Li, Di; Jiang, Deli

2012-08-15

Novel visible-light-induced {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-Ce-doped-TiO{sub 2} core-shell nanocomposite photocatalysts capable of magnetic separation have been synthesized by a facile sol-gel and after-annealing process. The as-obtained core-shell nanocomposite is composed of a central {gamma}-Fe{sub 2}O{sub 3} core with a strong response to external fields, an interlayer of SiO{sub 2}, and an outer layer of Ce-doped TiO{sub 2} nanocrystals. UV-vis spectra analysis indicates that Ce doping in the compound results in a red-shift of the absorption edge, thus offering increased visible light absorption. We show that such a {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-Ce-doped-TiO{sub 2} core-shell nanocomposite with appreciated Ce doping amount exhibitsmore » much higher visible-light photocatalytic activity than bare TiO{sub 2} and undoped {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-TiO{sub 2} core-shell nanocomposite toward the degradation of rhodamine B (RhB). Moreover, the {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-Ce-doped-TiO{sub 2} core-shell nanocomposite photocatalysts could be easily separated and reused from the treated water under application of an external magnetic field. - Graphical abstract: Novel {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-Ce-doped-TiO{sub 2} core/shell nanocomposite photocatalysts with enhanced photocatalytic activity and fast magnetic separability were prepared. Highlights: Black-Right-Pointing-Pointer Novel {gamma}-Fe{sub 2}O{sub 3}-SiO{sub 2}-Ce-doped TiO{sub 2} core/shell composite photocatalysts were prepared. Black-Right-Pointing-Pointer The resulting core/shell composite show high visible light photocatalytic activity. Black-Right-Pointing-Pointer The nanocomposite photocatalysts can be easily recycled with excellent durability.« less

Fabrication of core-shell Fe{sub 3}O{sub 4}@MIL-100(Fe) magnetic microspheres for the removal of Cr(VI) in aqueous solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Qingxiang, E-mail: qxyangzz@163.com; Zhao, Qianqian; Ren, ShuangShuang

Facile regeneration of an adsorbent is very important for commercial feasibility. One typical highly porous metal-organic framework (MOF) materials based on MIL-100(Fe) and magnetic iron oxide particles (denoted as MMCs) with diameter about of 350 nm were successfully synthesized. The growth of MIL-100(Fe) shell on the surface of Fe{sub 3}O{sub 4} was utilized precursor as crystal seed via in-situ step hydrothermal reaction. It is a simple way to obtain well organized core-shell MOF composites, compared to the step-by-step method. MMCs were firstly used to uptake of Cr(VI) anions in aqueous solution. Adsorption experiments were carried out in batch sorption mode investigatingmore » with the factors of contact time (0–1000 min), pH (from 2 to 12), dose of adsorbent (4–25 mg), and initial Cr(VI) concentration (range from 10 to 100 ppm). - Graphical abstract: One typical highly porous metal-organic framework (MOF) materials based on MIL-100(Fe) and magnetic iron oxide particles (denoted as MMCs) were successfully synthesized. Utilizing Fe{sub 3}O{sub 4} precursor as crystal seed to grow MIL-100(Fe) shell by in-situ step hydrothermal reaction. It is a simple way to obtain core-shell MOF composites. MMCs could effectively uptake of Cr(VI) anions in aqueous solution. - Highlights: • Fe{sub 3}O{sub 4}@MIL-100(Fe) composites with core-shell structure were successfully prepared through a simple method. • The influence factors on Cr(VI) adsorption by Fe{sub 3}O{sub 4}@MIL-100(Fe) were investigated. • Cr(VI) can efficiently adsorbed by Fe{sub 3}O{sub 4}@MIL-100(Fe) composites from aqueous solution.« less

/sub 1//sup 1/H/sup +/- and /sub 2//sup 4/He/sup +/-induced M-shell x-ray-production cross sections for selected elements in the rare-earth region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mehta, R.; Duggan, J.L.; Price, J.L.

1983-12-01

The measurements of M-shell x-ray-production cross sections induced by /sub 1//sup 1/H/sup +/ and /sub 2//sup 4/He/sup +/ ions are compared to the first-Born-approximation and ECPSSR (energy loss, Coulomb-deflection effects; perturbed-stationary-state approximation, with relativistic corrections) theories. Most of the reported experimental data were measured in our laboratory and the other measurements were taken from the literature. The data from our laboratory were for incident H/sup +/ and He/sup +/ ions in the energy range from 0.25 to 2.5 MeV. The M-shell x-ray-production cross sections were measured for the following thin targets: /sub 59/Pr, /sub 60/Nd, /sub 63/Eu, /sub 64/Gd, /submore » 66/Dy, /sub 67/Ho, /sub 68/Er, /sub 70/Yb, and /sub 72/Hf. The data from the literature were for protons and He/sup +/ ions in the energy range from 30 keV to 40 MeV. These data were for the following elements: /sub 54/Xe, /sub 59/Pr, /sub 60/Nd, /sub 62/Sm, /sub 63/Eu, /sub 64/Gd, /sub 65/Tb, /sub 66/Dy, /sub 67/Ho, /sub 68/Er, /sub 70/Yb, /sub 72/Hf, /sub 73/Ta, /sub 74/W, /sub 78/Pt, /sub 79/Au, /sub 80/Hg, /sub 82/Pb, /sub 83/Bi, and /sub 92/U. The first-Born-approximation calculations of the ionization cross section were made using the plane-wave Born approximation for direct ionization and the Oppenheimer-Brinkman-Kramers approximation of Nikolaev for electron capture. The ECPSSR theory of Brandt and Lapicki (Phys. Rev. A 23, 1717 (1981)) goes beyond the first Born approximation and accounts for the energy loss, Coulomb deflection, and relativistic effects in the perturbed-stationary-state theory. The first Born approximation overpredicts all measurements. The ECPSSR theory predicts the M-shell production cross sections correctly for Z/sub 2/>70 and energies per ..mu..>0.25 MeV/..mu...« less

Sample-morphology effects on x-ray photoelectron peak intensities. III. Simulated spectra of model core–shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Powell, Cedric J., E-mail: cedric.powell@nist.gov; Chudzicki, Maksymilian; Werner, Wolfgang S. M.

2015-09-15

The National Institute of Standards and Technology database for the simulation of electron spectra for surface analysis has been used to simulate Cu 2p photoelectron spectra for four types of spherical copper–gold nanoparticles (NPs). These simulations were made to extend the work of Tougaard [J. Vac. Sci. Technol. A 14, 1415 (1996)] and of Powell et al. [J. Vac. Sci. Technol. A 31, 021402 (2013)] who performed similar simulations for four types of planar copper–gold films. The Cu 2p spectra for the NPs were compared and contrasted with analogous results for the planar films and the effects of elastic scatteringmore » were investigated. The new simulations were made for a monolayer of three types of Cu/Au core–shell NPs on a Si substrate: (1) an Au shell of variable thickness on a Cu core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; (2) a Cu shell of variable thickness on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; and (3) an Au shell of variable thickness on a 1 nm Cu shell on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. For these three morphologies, the outer-shell thickness was varied until the Cu 2p{sub 3/2} peak intensity was the same (within 2%) as that found in our previous work with planar Cu/Au morphologies. The authors also performed similar simulations for a monolayer of spherical NPs consisting of a CuAu{sub x} alloy (also on a Si substrate) with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. In the latter simulations, the relative Au concentration (x) was varied to give the same Cu 2p{sub 3/2} peak intensity (within 2%) as that found previously. For each morphology, the authors performed simulations with elastic scattering switched on and off. The authors found that elastic-scattering effects were generally strong for the Cu-core/Au-shell and weak for the Au-core/Cu-shell NPs; intermediate elastic-scattering effects were found for the Au-core/Cu-shell/Au-shell NPs. The shell thicknesses required to give the selected Cu 2p{sub 3/2} peak intensity for the three types of core–shell NPs were less than the corresponding film thicknesses of planar samples since Cu 2p photoelectrons can be detected from the sides and, for the smaller NPs, bottoms of the NPs. Elastic-scattering effects were also observed on the Au atomic fractions found for the CuAu{sub x} NP alloys with different diameters.« less

The effect of oxide shell thickness on the structural, electronic, and optical properties of Si-SiO{sub 2} core-shell nano-crystals: A (time dependent)density functional theory study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nazemi, Sanaz, E-mail: s.nazemi@ut.ac.ir, E-mail: pourfath@ut.ac.ir; Soleimani, Ebrahim Asl; Pourfath, Mahdi, E-mail: s.nazemi@ut.ac.ir, E-mail: pourfath@ut.ac.ir

2016-04-14

Due to their tunable properties, silicon nano-crystals (NC) are currently being investigated. Quantum confinement can generally be employed for size-dependent band-gap tuning at dimensions smaller than the Bohr radius (∼5 nm for silicon). At the nano-meter scale, however, increased surface-to-volume ratio makes the surface effects dominant. Specifically, in Si-SiO{sub 2} core-shell semiconductor NCs the interfacial transition layer causes peculiar electronic and optical properties, because of the co-existence of intermediate oxidation states of silicon (Si{sup n+}, n = 0–4). Due to the presence of the many factors involved, a comprehensive understanding of the optical properties of these NCs has not yet been achieved. Inmore » this work, Si-SiO{sub 2} NCs with a diameter of 1.1 nm and covered by amorphous oxide shells with thicknesses between 2.5 and 4.75 Å are comprehensively studied, employing density functional theory calculations. It is shown that with increased oxide shell thickness, the low-energy part of the optical transition spectrum of the NC is red shifted and attenuated. Moreover, the absorption coefficient is increased in the high-energy part of the spectrum which corresponds to SiO{sub 2} transitions. Structural examinations indicate a larger compressive stress on the central silicon cluster with a thicker oxide shell. Examination of the local density of states reveals the migration of frontier molecular orbitals from the oxide shell into the silicon core with the increase of silica shell thickness. The optical and electrical properties are explained through the analysis of the density of states and the spatial distribution of silicon sub-oxide species.« less

Lithium sulfide compositions for battery electrolyte and battery electrode coatings

DOEpatents

Liang, Chengdu; Liu, Zengcai; Fu, Wunjun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

2013-12-03

Methods of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electroytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one or .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

Lithium sulfide compositions for battery electrolyte and battery electrode coatings

DOEpatents

Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

2014-10-28

Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

Low temperature grown ZnO@TiO{sub 2} core shell nanorod arrays for dye sensitized solar cell application

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goh, Gregory Kia Liang; Le, Hong Quang, E-mail: lehq@imre.a-star.edu.sg; Huang, Tang Jiao

High aspect ratio ZnO nanorod arrays were synthesized on fluorine-doped tin oxide glasses via a low temperature solution method. By adjusting the growth condition and adding polyethylenimine, ZnO nanorod arrays with tunable length were successfully achieved. The ZnO@TiO{sub 2} core shells structures were realized by a fast growth method of immersion into a (NH{sub 4}){sub 2}·TiF{sub 6} solution. Transmission electron microscopy, X-ray Diffraction and energy dispersive X-ray measurements all confirmed the existence of a titania shell uniformly covering the ZnO nanorod's surface. Results of solar cell testing showed that addition of a TiO{sub 2} shell to the ZnO nanorod significantlymore » increased short circuit current (from 4.2 to 5.2 mA/cm{sup 2}), open circuit voltage (from 0.6 V to 0.8 V) and fill factor (from 42.8% to 73.02%). The overall cell efficiency jumped from 1.1% for bare ZnO nanorod to 3.03% for a ZnO@TiO{sub 2} core shell structured solar cell with a 18–22 nm shell thickness, a nearly threefold increase. - Graphical abstract: The synthesis process of coating TiO{sub 2} shell onto ZnO nanorod core is shown schematically. A thin, uniform, and conformal shell had been grown on the surface of the ZnO core after immersing in the (NH{sub 4}){sub 2}·TiF{sub 6} solution for 5–15 min. - Highlights: • ZnO@TiO{sub 2} core shell nanorod has been grown on FTO substrate using low temperature solution method. • TEM, XRD, EDX results confirmed the existing of titana shell, uniformly covered rod's surface. • TiO{sub 2} shell suppressed recombination, demonstrated significant enhancement in cell's efficiency. • Core shell DSSC's efficiency achieved as high as 3.03%, 3 times higher than that of ZnO nanorods.« less

Photoelastic investigations of stress concentration in perforated cylindrical shells with internal pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dranchenko, B.N.; Portnov, B.B.; Seleznev, A.V.

1994-06-01

Cylindrical shells with regular perforation are widely used in power generating equipment and in particular in collectors 1 of the circuit of steam generators of power generating installations with water-water reactors (WWPR) The state of stress of collectors is determined by a broad spectrum of technological and operational loads, it is therefore difficult to analyze it theoretically. The aim of the present work is the experimental investigation of stresses in the cylindrical shells of collectors subjected to internal pressure, the generalization and systematization of empirical data in the form of engineering formulas and nomographs. The investigations were carried out withmore » photoelastic three-dimensional models with the use of {open_quotes}freezing{close_quotes}. The basic characteristics of the state of stress of perforated shells (in particular those used in calculations of the strength and life of collectors) are the values of the stress intensity factor K and of the stress intensification factor {gamma}{sub {bar {sigma}}}{sub me} of the mean integral stress level in the neck between neighboring holes. The presented data make it possible to establish quantitatively the regularities of change of K and {gamma}{sub {bar {sigma}}}{sub me} in dependence on the geometry of the perforated shells. These data were systematized according to a special program of multifactor regression analysis. It follows from the presented formulas and nomographs in particular that in the ranges of the geometry of the perforated shells K may change from 2.5 to 4.0, and {gamma}{sub {bar {sigma}}}{sub me} from 1.1 to 2.3. Therefore varied geometric parameters have a substantial effect on the load intensity of perforated shells, and that once again confirms how topical it is to obtain new experimental data, to generalize and systematize them.« less

Ferromagnetic behavior and exchange bias effect in akaganeite nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tadic, Marin, E-mail: marint@vinca.rs; Milosevic, Irena; Motte, Laurence

We report ferromagnetic-like properties and exchange bias effect in akaganeite (β-FeOOH) nanorods. They exhibit a Néel temperature T{sub N} = 259 K and ferromagnetic-like hysteresis behavior both below and above T{sub N}. An exchange bias effect is observed below T{sub N} and represents an interesting behavior for akaganeite nanorods. These results are explained on the basis of a core-shell structure in which the core has bulk akaganeite magnetic properties (i.e., antiferromagnetic ordering) while the shell exhibits a disordered spin state. Thus, the nanorods show ferromagnetic properties and an exchange bias effect at the same time, increasing their potential for use in practical applications.

URANIUM DIOXIDE OXIDATION WITH FORMING INTERMEDIATE PHASES (in German)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scheibe, H.; Ermischer, W.

1964-02-01

An experimental study was made of the UO/sub 2/ to U/sub 3/O/sub 8/ oxidation process. At low temperatures, depending on the activity of the powder, the oxidation of UO/sub 2/ yield a U/sub 3/O/sub 7/ shell around the UO/sub 2/ grain (160 to 220 deg C). Further oxidation is determined by the diffusion of oxygen through this shell and yields U/sub 5/O/sub 12/ (280 to 290 deg C). Their follows U/sub 5/O/sub (375 to 400 deg C) and finally U/sub 3/O/sub 8/ as more oxigen is absorbed. No further increase of the oxygen content occurs up to 800 deg C.more » The exothermal effects established through differential thermal analysis may be due to lattice transformation. (OTS)« less

EFFECTS OF A DEEP MIXED SHELL ON SOLAR g-MODES, p-MODES, AND NEUTRINO FLUX

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolff, Charles L.

2009-08-10

A mixed-shell model that reflects g-modes away from the Sun's center is developed further by calibrating its parameters and evaluating a mixing mechanism: buoyancy. The shell roughly doubles g-mode oscillation periods and would explain why there is no definitive detection of their periods. But the shell has only minor effects on most p-modes. The model provides a mechanism for causing short-term fluctuations in neutrino flux and makes plausible the correlations between this flux and solar activity levels. Relations are derived for a shell heated asymmetrically by transient increases in nuclear burning in small 'hot spots'. The size of these spotsmore » and the timing of a heating event are governed by sets(l) of standing asymptotic g-modes, coupled by a maximal principle that greatly enhances their excitation and concentrates power toward the equator, assisting the detection of higher-l sets. Signals from all sets, except one, in the range 2 {<=} l {<=} 8 are identified by difference periods between consecutive radial states using the method of Garcia et al. and reinterpreting their latest spectrum. This confirms two detections of sets in a similar range of l by their rotation rates. The mean radius of shell mixing is r{sub m} = 0.16 R{sub sun}, which improves an earlier independent estimate of 0.18 by the author. The shell may cause the unexplained dip in measured sound speed at its location. Another sound speed error, centered near 0.67 R{sub sun}, and reversing flows in the same place with a period originally near 1.3 yr suggest that the g-modes are depositing there about 3% of the solar luminosity. That implies the shell at r{sub m} is receiving a similar magnitude of power, which would be enough energy to mix the corresponding shell in a standard solar model in <<10{sup 7} yr.« less

Irreversible phase transitions due to laser-based T-jump heating of precursor Eu:ZrO{sub 2}/Tb:Y{sub 2}O{sub 3} core/shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gunawidjaja, Ray; Diez-y-Riega, Helena; Eilers, Hergen, E-mail: eilers@wsu.edu

2015-09-15

Amorphous precursors of Eu-doped-ZrO{sub 2}/Tb-doped-Y{sub 2}O{sub 3} (p-Eu:ZrO{sub 2}/p-Tb:Y{sub 2}O{sub 3}) core/shell nanoparticles are rapidly heated to temperatures between 200 °C and 950 °C for periods between 2 s and 60 s using a CO{sub 2} laser. During this heating process the nanoparticles undergo irreversible phase changes. The fluorescence spectra due to Eu{sup 3+} dopants in the core and Tb{sup 3+} dopants in the shell are used to identify distinct phases within the material and to generate time/temperature phase diagrams. Such phase diagrams can potentially help to determine unknown time/temperature histories in thermosensor applications. - Graphical abstract: A CO{sub 2}more » laser is used for rapid heating of p-Eu:ZrO{sub 2}/p-Tb:Y{sub 2}O{sub 3} core/shell nanoparticles. Optical spectra are used to identify distinct phases and to determine its thermal history. - Highlights: • Synthesized oxide precursors of lanthanide doped core/shell nanoparticles. • Heated core/shell nanoparticles via laser-based T-jump technique. • Observed time- and temperature-dependent irreversible phase transition.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yao, Aihua, E-mail: aihyao@126.com; Ai, Fanrong; Liu, Xin

Hollow hydroxyapatite microspheres, consisting of a hollow core and a porous shell, were prepared by converting Li{sub 2}O-CaO-B{sub 2}O{sub 3} glass microspheres in dilute phosphate solution at 37 {sup o}C. The results confirmed that Li{sub 2}O-CaO-B{sub 2}O{sub 3} glass was transformed to hydroxyapatite without changing the external shape and dimension of the original glass object. Scanning electron microscopy images showed the shell wall of the microsphere was built from hydroxyapatite particles, and these particles spontaneously align with one another to form a porous sphere with an interior cavity. Increase in phosphate concentration resulted in an increase in the reaction rate,more » which in turn had an effect on shell wall structure of the hollow hydroxyapatite microsphere. For the Li{sub 2}O-CaO-B{sub 2}O{sub 3} glass microspheres reacted in low-concentration K{sub 2}HPO{sub 4} solution, lower reaction rate and a multilayered microstructure were observed. On the other hand, the glass microspheres reacted in higher phosphate solution converted more rapidly and produced a single hydroxyapatite layer. Furthermore, the mechanism of forming hydroxyapatite hollow microsphere was described.« less

Constrained Hartree-Fock Theory and Study of Deformed Structures of Closed Shell Nuclei

NASA Astrophysics Data System (ADS)

Praharaj, Choudhury

2016-03-01

We have studied some N or Z = 50 nuclei in a microscopic model with effective interaction in a reasonably large shell model space. Excitation of particles across 50 shell closure leads to well-deformed excited prolate configurations. The potential energy surfaces of nuclei are studied using Hartree-Fock theory with quadrupole constraint to explore the various deformed configurations of N = 50 nuclei 82Ge , 84Se and 86Kr . Energy spectra are calculated from various intrinsic states using Peierls-Yoccoz angular momentum projection technique. Results of spectra and electromagnetic moments and transitions will be presented for N = 50 nuclei and for Z = 50 114Sn nucleus. Supported by Grant No SB/S2/HEP-06/2013 of DST.

Feasibility and Practical Limits for the Use of Lightweight Prestressed Concrete (LWPC) as a Shipbuilding Material.

DTIC Science & Technology

1982-10-01

centerline by stanchions. A concrete beam is provided at the ship centerline to transfer unbalanced stanchion loads longitudinally along the shell . The 01...Place Cast-in-Place Concrete Connections -- Connections betw. an precast shell elements are made using cast-in-place concrete closure pours. See Figure...buckling using the column provi sions of the ACI code. For shells , the critical radius to thickness ratio is about 200 for cylindrical shells loaded in

Type I band alignment in GaAs{sub 81}Sb{sub 19}/GaAs core-shell nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, T.; Key Laboratory of Advanced Display and System Application, Shanghai University, 149 Yanchang Road, Shanghai 200072; Wei, M. J.

2015-09-14

The composition and band gap of the shell that formed during the growth of axial GaAs/GaAs{sub 81}Sb{sub 19}/ GaAs heterostructure nanowires have been investigated by transmission electron microscopy combined with energy dispersion spectroscopy, scanning tunneling spectroscopy, and density functional theory calculations. On the GaAs{sub 81}Sb{sub 19} intermediate segment, the shell is found to be free of Sb (pure GaAs shell) and transparent to the tunneling electrons, despite the (110) biaxial strain that affects its band gap. As a result, a direct measurement of the core band gap allows the quantitative determination of the band offset between the GaAs{sub 81}Sb{sub 19}more » core and the GaAs shell and identifies it as a type I band alignment.« less

Engineering of high performance supercapacitor electrode based on Fe-Ni/Fe{sub 2}O{sub 3}-NiO core/shell hybrid nanostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Ashutosh K., E-mail: ashuvishen@gmail.com, E-mail: aksingh@bose.res.in; Mandal, Kalyan

The present work reports on fabrication and supercapacitor applications of a core/shell Fe-Ni/Fe{sub 2}O{sub 3}-NiO hybrid nanostructures (HNs) electrode. The core/shell Fe-Ni/Fe{sub 2}O{sub 3}-NiO hybrid nanostructures have been fabricated through a two step method (nanowire fabrication and their controlled oxidation). The 1D hybrid nanostructure consists of highly porous shell layer (redox active materials NiO and Fe{sub 2}O{sub 3}) and the conductive core (FeNi nanowire). Thus, the highly porous shell layer allows facile electrolyte diffusion as well as faster redox reaction kinetics; whereas the conductive FeNi nanowire core provides the proficient express way for electrons to travel to the current collector,more » which helps in the superior electrochemical performance. The core/shell Fe-Ni/Fe{sub 2}O{sub 3}-NiO hybrid nanostructures electrode based supercapacitor shows very good electrochemical performances in terms of high specific capacitance nearly 1415 F g{sup −1} at a current density of 2.5 A g{sup −1}, excellent cycling stability and rate capability. The high quality electrochemical performance of core/shell hybrid nanostructures electrode shows its potential as an alternative electrode for forthcoming supercapacitor devices.« less

Systematics of first 2+ state g factors around mass 80

NASA Astrophysics Data System (ADS)

Mertzimekis, T. J.; Stuchbery, A. E.; Benczer-Koller, N.; Taylor, M. J.

2003-11-01

The systematics of the first 2+ state g factors in the mass 80 region are investigated in terms of an IBM-II analysis, a pairing-corrected geometrical model, and a shell-model approach. Subshell closure effects at N=38 and overall trends were examined using IBM-II. A large-space shell-model calculation was successful in describing the behavior for N=48 and N=50 nuclei, where single-particle features are prominent. A schematic truncated-space calculation was applied to the lighter isotopes. The variations of the effective boson g factors are discussed in connection with the role of F -spin breaking, and comparisons are made between the mass 80 and mass 180 regions.

A novel fabrication of Cu{sub 2}O@Cu{sub 7}S{sub 4} core-shell micro/nanocrystals from Cu{sub 2}O temples and enhanced photocatalytic activities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Junqi, E-mail: sfmlab@163.com; Sun, Long; Yan, Ying

2016-08-15

Highlights: • The Cu{sub 2}O@Cu{sub 7}S{sub 4} core-shell crystals maintained the same morphology with template. • The crystals exhibit enhanced photocatalytic activity than the pure Cu{sub 2}O crystals. • The photocatalytic activity of different R crystals is diverse from each other. • A possible formation mechanism has been proposed. - Abstract: Uniform and monodispersed Cu{sub 2}O@Cu{sub 7}S{sub 4} core-shell micro/nanocrystals have been synthesized successfully at room temperature via a simple chemical etching reaction, using Cu{sub 2}O as sacrificial template. The structure and properties of the crystals were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM),more » X-ray photoelectron spectra (XPS). The photocatalytic activity of the Cu{sub 2}O@Cu{sub 7}S{sub 4} crystals was evaluated by photocatalytic decolorization of MeO (methyl orange) aqueous solution at ambient temperature under visible-light irradiation. The results show that the as-prepared Cu{sub 2}O@Cu{sub 7}S{sub 4} crystals revealed core-shell structure, which maintained the same morphology with corresponding template and were composed of cuboctahedron Cu{sub 7}S{sub 4} shell and active Cu{sub 2}O core. Due to the unique Cu{sub 2}O@Cu{sub 7}S{sub 4} core-shell structure, the crystals exhibit enhanced photocatalytic activity than that of the pure Cu{sub 2}O crystals, and the photocatalytic activity of different R crystals is diverse from each other. A possible formation mechanism has been proposed.« less

NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} core/shell nanocomposite: A highly efficient visible-light-driven photocatalyst utilizing upconversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Yuanyuan; Wang, Wenzhong, E-mail: wzwang@mail.sic.ac.cn; Sun, Songmei

2014-04-01

Highlights: • Design and synthesis of NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} based on upconversion. • NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} nanocomposite was prepared for the first time. • Core–shell structure benefits the properties. • Upconversion contributed to the enhanced photocatalytic activity. • Helps to understand the functionality of new type photocatalysts. - Abstract: NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} core/shell nanocomposite was designed and prepared for the first time based on upconversion. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution TEM (HRTEM), energy dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectra (DRS). The results revealed that the as-synthesizedmore » NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} consisted of spheres with a core diameter of about 26 nm and a shell diameter of around 6 nm. The core was upconversion illuminant NaYF{sub 4}:Er,Yb and the shell was Bi{sub 2}MoO{sub 6} around the core, which was confirmed by EDS. The NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} exhibited higher photocatalytic activity for the photodecomposition of Rhodamine B (RhB) under the irradiation of Xe lamp and green light emitting diode (g-LED). The mechanism of the high photocatalytic activity was discussed by photoluminescence spectra (PL), which is mainly attributed to upconversion of NaYF{sub 4}:Er,Yb in the NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} nanocomposite and the core–shell structure.« less

Investigation on the preparation and luminescence emission of LaF{sub 3}:Eu{sup 3+}@LaF{sub 3}/SiO{sub 2} core-shell nanostructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shao, Jun, E-mail: jun-shao@snnu.edu.cn; Wang, Zhaojin; Wang, Ruibo

LaF{sub 3}:Eu{sup 3+}, LaF{sub 3}:Eu{sup 3+}@LaF{sub 3}, LaF{sub 3}:Eu{sup 3+}@CeF{sub 3} and LaF{sub 3}:Eu{sup 3+}@SiO{sub 2} nanoparticles were successfully synthesized via hydrothermal route and modified Stöber method. The surface property of LaF{sub 3}:Eu{sup 3+} particle was successfully modified by coating LaF{sub 3} and SiO{sub 2} shell onto the particle, which resulted in the change of the surface property and luminescence emission of LaF{sub 3}:Eu{sup 3+}. It was found that the surface quenchers were decreased and thus the nonradiative pathways were reduced with core/shell structure, which not only enhanced the yellow emission of the sample, but also changed the intensity ratiomore » of the yellow to orange emission. The dependence of the shell property and shell thickness on the luminescence emission spectra were investigated systematically. The current investigation can provide useful information for developing applications in biological imaging, detection, and sensing and other aspects.« less

Thermal ring closure in Mo(CO){sub 5}L (L = bpy, dmbpy, dpbpy) transients generated by pulsed laser flash photolysis. Mechanistic information from high-pressure effects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddy, K.B.; Hoffmann, R.; Konya, G.

1992-06-01

The kinetics of the ring-closure reactions of Mo(CO){sub 5}L, produced during the laser flash photolysis of Mo(CO){sub 6} and L where L = 2,2{prime}-bipyridine (bpy), 4,4{prime}-dimethyl-2,2{prime}-bipyridine (dpbpy) and 4,4{prime}-dephenyl-2,2{prime}-bipyridine (dpbpy) were studied as a function of temperature and pressure. The values of the activation parameters and pressure. The values of the activation parameters {Delta}S and {Delta}V are small and negative for L = bpy and dmbpy supporting an associative interchange mechanism (I{sub a}) for CO extrusion. For L = dpbpy, {Delta}V is small and positive in line with a dissociative interchange mechanism (I{sub d}). The results demonstrate a changeover inmore » mechanism from I{sub a} to I{sub d} with increasing steric hindrance on the bidentate ligand L. 36 refs., 1 fig., 2 tabs.« less

Crossover from disordered to core-shell structures of nano-oxide Y{sub 2}O{sub 3} dispersed particles in Fe

DOE Office of Scientific and Technical Information (OSTI.GOV)

Higgins, M. P.; Wang, L. M.; Gao, F., E-mail: gaofeium@umich.edu

Molecular dynamic simulations of Y{sub 2}O{sub 3} in bcc Fe and transmission electron microscopy (TEM) observations were used to understand the structure of Y{sub 2}O{sub 3} nano-clusters in an oxide dispersion strengthened steel matrix. The study showed that Y{sub 2}O{sub 3} nano-clusters below 2 nm were completely disordered. Y{sub 2}O{sub 3} nano-clusters above 2 nm, however, form a core-shell structure, with a shell thickness of 0.5–0.7 nm that is independent of nano-cluster size. Y{sub 2}O{sub 3} nano-clusters were surrounded by off-lattice Fe atoms, further increasing the stability of these nano-clusters. TEM was used to corroborate our simulation results and showed a crossover frommore » a disordered nano-cluster to a core-shell structure.« less

Probing the N = 14 subshell closure: g factor of the 26Mg (21+) state

NASA Astrophysics Data System (ADS)

McCormick, B. P.; Stuchbery, A. E.; Kibédi, T.; Lane, G. J.; Reed, M. W.; Eriksen, T. K.; Hota, S. S.; Lee, B. Q.; Palalani, N.

2018-04-01

The first-excited state g factor of 26Mg has been measured relative to the g factor of the 24Mg (21+) state using the high-velocity transient-field technique, giving g = + 0.86 ± 0.10. This new measurement is in strong disagreement with the currently adopted value, but in agreement with the sd-shell model using the USDB interaction. The newly measured g factor, along with E (21+) and B (E 2) systematics, signal the closure of the νd5/2 subshell at N = 14. The possibility that precise g-factor measurements may indicate the onset of neutron pf admixtures in first-excited state even-even magnesium isotopes below 32Mg is discussed and the importance of precise excited-state g-factor measurements on sd shell nuclei with N ≠ Z to test shell-model wavefunctions is noted.

First Direct Mass Measurements of Nuclides around Z =100 with a Multireflection Time-of-Flight Mass Spectrograph

NASA Astrophysics Data System (ADS)

Ito, Y.; Schury, P.; Wada, M.; Arai, F.; Haba, H.; Hirayama, Y.; Ishizawa, S.; Kaji, D.; Kimura, S.; Koura, H.; MacCormick, M.; Miyatake, H.; Moon, J. Y.; Morimoto, K.; Morita, K.; Mukai, M.; Murray, I.; Niwase, T.; Okada, K.; Ozawa, A.; Rosenbusch, M.; Takamine, A.; Tanaka, T.; Watanabe, Y. X.; Wollnik, H.; Yamaki, S.

2018-04-01

The masses of 246Es, 251Fm, and the transfermium nuclei Md-252249 and 254No, produced by hot- and cold-fusion reactions, in the vicinity of the deformed N =152 neutron shell closure, have been directly measured using a multireflection time-of-flight mass spectrograph. The masses of 246Es and 249,250,252Md were measured for the first time. Using the masses of Md,250249 as anchor points for α decay chains, the masses of heavier nuclei, up to 261Bh and 266Mt, were determined. These new masses were compared with theoretical global mass models and demonstrated to be in good agreement with macroscopic-microscopic models in this region. The empirical shell gap parameter δ2 n derived from three isotopic masses was updated with the new masses and corroborates the existence of the deformed N =152 neutron shell closure for Md and Lr.

Microscopic description of quadrupole collectivity in neutron-rich nuclei across the N = 126 shell closure

NASA Astrophysics Data System (ADS)

Rodríguez-Guzmán, R.; Robledo, L. M.; Sharma, M. M.

2015-06-01

The quadrupole collectivity in Nd, Sm, Gd, Dy, Er, Yb, Hf and W nuclei with neutron numbers 122 ≤ N ≤ 156 is studied, both at the mean field level and beyond, using the Gogny energy density functional. Besides the robustness of the N = 126 neutron shell closure, it is shown that the onset of static deformations in those isotopic chains with increasing neutron number leads to an enhanced stability and further extends the corresponding two-neutron drip lines far beyond what could be expected from spherical calculations. Independence of the mean-field predictions with respect to the particular version of the Gogny energy density functional employed is demonstrated by comparing results based on the D1S and D1M parameter sets. Correlations beyond mean field are taken into account in the framework of the angular momentum projected generator coordinate method calculation. It is shown that N = 126 remains a robust neutron magic number when dynamical effects are included. The analysis of the collective wave functions, average deformations and excitation energies indicate that, with increasing neutron number, the zero-point quantum corrections lead to dominant prolate configurations in the 0{1/+}, 0{2/+}, 2{1/+} and 2{2/+} states of the studied nuclei. Moreover, those dynamical deformation effects provide an enhanced stability that further supports the mean-field predictions, corroborating a shift of the r-process path to higher neutron numbers. Beyond mean-field calculations provide a smaller shell gap at N = 126 than the mean-field one in good agreement with previous theoretical studies. However, the shell gap still remains strong enough in the two-neutron drip lines.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li Shun; School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083; Lin Yuanhua

Anatase titania-coated bismuth ferrite nanocomposites (BiFeO{sub 3}/TiO{sub 2}) have been fabricated via a hydrothermal approach combined with a hydrolysis precipitation processing. Analysis of the microstructure and phase composition reveals that a core-shell BiFeO{sub 3}/TiO{sub 2} structure can be formed, which results in a significant redshift in the UV-vis absorption spectra as compared to a simple mechanical mixture of BiFeO{sub 3}-TiO{sub 2} nanopowders. The core-shell structured BiFeO{sub 3}/TiO{sub 2} nanocomposites exhibit higher photocatalytic activity for photodegradation of Congo red under visible-light ({lambda}>400 nm) irradiation, which should be attributed to the enhancement of the quantum efficiency by separating the electrons and holesmore » effectively. The obtained BiFeO{sub 3}/TiO{sub 2} nanocomposites can be used as potential visible-light driven photocatalysts.« less

Disorders of metal metabolism

PubMed Central

Ferreira, Carlos R.; Gahl, William A.

2017-01-01

Trace elements are chemical elements needed in minute amounts for normal physiology. Some of the physiologically relevant trace elements include iodine, copper, iron, manganese, zinc, selenium, cobalt and molybdenum. Of these, some are metals, and in particular, transition metals. The different electron shells of an atom carry different energy levels, with those closest to the nucleus being lowest in energy. The number of electrons in the outermost shell determines the reactivity of such an atom. The electron shells are divided in sub-shells, and in particular the third shell has s, p and d sub-shells. Transition metals are strictly defined as elements whose atom has an incomplete d sub-shell. This incomplete d sub-shell makes them prone to chemical reactions, particularly redox reactions. Transition metals of biologic importance include copper, iron, manganese, cobalt and molybdenum. Zinc is not a transition metal, since it has a complete d sub-shell. Selenium, on the other hand, is strictly speaking a nonmetal, although given its chemical properties between those of metals and nonmetals, it is sometimes considered a metalloid. In this review, we summarize the current knowledge on the inborn errors of metal and metalloid metabolism. PMID:29354481

Nuclear Structure of 186Re

DTIC Science & Technology

2016-12-24

D population-depopulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 AME Atomic Mass Evaluation...this mass region are important for validating models of nuclear structure and reactions. The ENSDF feeds a specific data library relevant to nuclear...spherically asymmetric. Spherical asymmetry is common for nuclei between shell closures, such as those in the mid-shell 150  A  190 mass range of interest

Growth and characterization of dilute nitride GaN{sub x}P{sub 1−x} nanowires and GaN{sub x}P{sub 1−x}/GaN{sub y}P{sub 1−y} core/shell nanowires on Si (111) by gas source molecular beam epitaxy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sukrittanon, S.; Kuang, Y. J.; Dobrovolsky, A.

2014-08-18

We have demonstrated self-catalyzed GaN{sub x}P{sub 1−x} and GaN{sub x}P{sub 1−x}/GaN{sub y}P{sub 1−y} core/shell nanowire growth by gas-source molecular beam epitaxy. The growth window for GaN{sub x}P{sub 1−x} nanowires was observed to be comparable to that of GaP nanowires (∼585 °C to ∼615 °C). Transmission electron microscopy showed a mixture of cubic zincblende phase and hexagonal wurtzite phase along the [111] growth direction in GaN{sub x}P{sub 1−x} nanowires. A temperature-dependent photoluminescence (PL) study performed on GaN{sub x}P{sub 1−x}/GaN{sub y}P{sub 1−y} core/shell nanowires exhibited an S-shape dependence of the PL peaks. This suggests that at low temperature, the emission stems from N-related localizedmore » states below the conduction band edge in the shell, while at high temperature, the emission stems from band-to-band transition in the shell as well as recombination in the GaN{sub x}P{sub 1−x} core.« less

Curvature-Induced Instabilities of Shells

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Steranka, Mark P.; Bade, Abdikhalaq J.; Holmes, Douglas P.

2018-01-01

Induced by proteins within the cell membrane or by differential growth, heating, or swelling, spontaneous curvatures can drastically affect the morphology of thin bodies and induce mechanical instabilities. Yet, the interaction of spontaneous curvature and geometric frustration in curved shells remains poorly understood. Via a combination of precision experiments on elastomeric spherical shells, simulations, and theory, we show how a spontaneous curvature induces a rotational symmetry-breaking buckling as well as a snapping instability reminiscent of the Venus fly trap closure mechanism. The instabilities, and their dependence on geometry, are rationalized by reducing the spontaneous curvature to an effective mechanical load. This formulation reveals a combined pressurelike term in the bulk and a torquelike term in the boundary, allowing scaling predictions for the instabilities that are in excellent agreement with experiments and simulations. Moreover, the effective pressure analogy suggests a curvature-induced subcritical buckling in closed shells. We determine the critical buckling curvature via a linear stability analysis that accounts for the combination of residual membrane and bending stresses. The prominent role of geometry in our findings suggests the applicability of the results over a wide range of scales.

The role of interfacial metal silicates on the magnetism in FeCo/SiO{sub 2} and Fe{sub 49%}Co{sub 49%}V{sub 2%}/SiO{sub 2} core/shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Desautels, R. D., E-mail: rddesautels@physics.umanitoba.ca; Toyota Research Institute of North America, Ann Arbor, Michigan 48169; Freeland, J. W.

2015-05-07

We have investigated the role of spontaneously formed interfacial metal silicates on the magnetism of FeCo/SiO{sub 2} and Fe{sub 49%}Co{sub 49%}V{sub 2%}/SiO{sub 2} core/shell nanoparticles. Element specific x-ray absorption and photoelectron spectroscopy experiments have identified the characteristic spectral features of metallic iron and cobalt from within the nanoparticle core. In addition, metal silicates of iron, cobalt, and vanadium were found to have formed spontaneously at the interface between the nanoparticle core and silica shell. X-ray magnetic circular dichroism experiments indicated that the elemental magnetism was a result of metallic iron and cobalt with small components from the iron, cobalt, andmore » vanadium silicates. Magnetometry experiments have shown that there was no exchange bias loop shift in the FeCo nanoparticles; however, exchange bias from antiferromagnetic vanadium oxide was measured in the V-doped nanoparticles. These results showed clearly that the interfacial metal silicates played a significant role in the magnetism of these core/shell nanoparticles, and that the vanadium percolated from the FeCo-cores into the SiO{sub 2}-based interfacial shell.« less

Does the 4f-shell contribute to bonding in tetravalent lanthanide halides?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ji, Wen-Xin; School of Chemistry and Chemical Engineering, Ningxia University, 750015 Yinchuan; Xu, Wei

2014-12-28

Lanthanide tetrahalide molecules LnX{sub 4} (Ln = Ce, Pr, Tb; X = F, Cl, Br, I) have been investigated by density functional theory at the levels of the relativistic Zero Order Regular Approximation and the relativistic energy-consistent pseudopotentials, using frozen small- and medium-cores. The calculated bond lengths and vibrational frequencies are close to the experimental data. Our calculations indicate 4f shell contributions to bonding in LnX{sub 4}, in particular for the early lanthanides, which show significant overlap between the Ln 4f-shell and the halogen np-shells. The 4f shells contribute to Ln-X bonding in LnX{sub 4} about one third more thanmore » in LnX{sub 3}.« less

Closure system

DOEpatents

Hertelendy, N.A.

1987-04-22

A pressure resistant seal for a metallic container is formed between a cylindrical portion having one end open and a cap which seals the open end of the shell. The cap is in the form of a frusto-conical flange which is inserted narrow end first into the open end of the shell and the container is sealed by means of a capping tool which pulls the flange against a die, deforming the flange and forcing the edge of the flange into the wall of the shell. 6 figs.

Closure system

DOEpatents

Hertelendy, Nicholas A [Kennewick, WA

1989-01-01

A pressure resistant seal for a metallic container is formed between a cylindrical portion having one end open and a cap which seals the open end of the shell. The cap is in the form of a frusto-conical flange which is inserted narrow end first into the open end of the shell and the container is sealed by means of a capping tool which pulls the flange against a die, deforming the flange and forcing the edge of the flange into the wall of the shell.

Closure system

DOEpatents

Hertelendy, Nicholas A.

1989-04-04

A pressure resistant seal for a metallic container is formed between a cylindrical portion having one end open and a cap which seals the open end of the shell. The cap is in the form of a frusto-conical flange which is inserted narrow end first into the open end of the shell and the container is sealed by means of a capping tool which pulls the flange against a die, deforming the flange and forcing the edge of the flange into the wall of the shell.

First Images of R Aquarii and Its Asymmetric H2O Shell

NASA Astrophysics Data System (ADS)

Ragland, S.; Le Coroller, H.; Pluzhnik, E.; Cotton, W. D.; Danchi, W. C.; Monnier, J. D.; Traub, W. A.; Willson, L. A.; Berger, J.-P.; Lacasse, M. G.

2008-05-01

We report imaging observations of the symbiotic long-period Mira variable R Aquarii (R Aqr) at near-infrared and radio wavelengths. The near-infrared observations were made with the IOTA imaging interferometer in three narrowband filters centered at 1.51, 1.64, and 1.78 μm, which sample mainly water, continuum, and water features, respectively. Our near-infrared fringe visibility and closure phase data are analyzed using three models. (1) A uniform disk model with wavelength-dependent sizes fails to fit the visibility data, and is inconsistent with the closure phase data. (2) A three-component model, consisting of a Mira star, water shell, and an off-axis point source, provide a good fit to all data. (3) A model generated by a constrained image reconstruction analysis provides more insight, suggesting that the water shell is highly nonuniform, i.e., clumpy. The VLBA observations of SiO masers in the outer molecular envelope show evidence of turbulence, with jetlike features containing velocity gradients.

Synthesis and thermal stability of W/WS{sub 2} inorganic fullerene-like nanoparticles with core-shell structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang Lianxia; Yang Haibin; Fu Wuyou

W/WS{sub 2} inorganic fullerene-like (IF) nanoparticles with core-shell structure are synthesized by the reaction of tungsten nanospheres and sulfur at relatively low temperatures (380-600 deg. C) under hydrogen atmosphere, in which tungsten nanospheres were prepared by wire electrical explosion method. Images of transmission electron microscopy and high-resolution transmission electron microscopy show that the composite particles are of core-shell structure with spherical shape and the shell thickness is about 10 nm. X-ray powder diffraction results indicate that the interlayer spacing of IF-WS{sub 2} shell decreases and approaches that of 2H-WS{sub 2} with increasing annealing temperatures, representing an expansion of 3.3-1.6%. Amore » mechanism of IF-WS{sub 2} formation via sulfur diffusion into fullerene nanoparticles is discussed. Thermal analysis shows that the nanoparticles obtained at different temperatures exhibit similar thermal stability and the onset temperature of oxidization is about 410 deg. C. Encapsulating hard tungsten core into IF-WS{sub 2} and the spherical shape of the core-shell structures may enhance their performance in tribological applications.« less

Ab-initio study of the segregation and electronic properties of neutral and charged B and P dopants in Si and Si/SiO{sub 2} nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schoeters, Bob, E-mail: bob.schoeters@uantwerpen.be; IMEC, Kapeldreef 75, B-3001 Leuven; Leenaerts, Ortwin, E-mail: ortwin.leenaerts@uantwerpen.be

We perform first-principles calculations to investigate the preferred positions of B and P dopants, both neutral and in their preferred charge state, in Si and Si/SiO{sub 2} core-shell nanowires (NWs). In order to understand the observed trends in the formation energy, we isolate the different effects that determine these formation energies. By making the distinction between the unrelaxed and the relaxed formation energy, we separate the impact of the relaxation from that of the chemical environment. The unrelaxed formation energies are determined by three effects: (i) the effect of strain caused by size mismatch between the dopant and the hostmore » atoms, (ii) the local position of the band edges, and (iii) a screening effect. In the case of the SiNW (Si/SiO{sub 2} NW), these effects result in an increase of the formation energy away from the center (interface). The effect of relaxation depends on the relative size mismatch between the dopant and host atoms. A large size mismatch causes substantial relaxation that reduces the formation energy considerably, with the relaxation being more pronounced towards the edge of the wires. These effects explain the surface segregation of the B dopants in a SiNW, since the atomic relaxation induces a continuous drop of the formation energy towards the edge. However, for the P dopants, the formation energy starts to rise when moving from the center but drops to a minimum just next to the surface, indicating a different type of behavior. It also explains that the preferential location for B dopants in Si/SiO{sub 2} core-shell NWs is inside the oxide shell just next to the interface, whereas the P dopants prefer the positions next to the interface inside the Si core, which is in agreement with recent experiments. These preferred locations have an important impact on the electronic properties of these core-shell NWs. Our simulations indicate the possibility of hole gas formation when B segregates into the oxide shell.« less

An Attempt to Derive the epsilon Equation from a Two-Point Closure

NASA Technical Reports Server (NTRS)

Canuto, V. M.; Cheng, Y.; Howard, A. M.

2010-01-01

The goal of this paper is to derive the equation for the turbulence dissipation rate epsilon for a shear-driven flow. In 1961, Davydov used a one-point closure model to derive the epsilon equation from first principles but the final result contained undetermined terms and thus lacked predictive power. Both in 1987 and in 2001, attempts were made to derive the epsilon equation from first principles using a two-point closure, but their methods relied on a phenomenological assumption. The standard practice has thus been to employ a heuristic form of the equation that contains three empirical ingredients: two constants, c(sub 1 epsilon), and c(sub 2 epsilon), and a diffusion term D(sub epsilon) In this work, a two-point closure is employed, yielding the following results: 1) the empirical constants get replaced by c(sub 1), c(sub 2), which are now functions of Kappa and epsilon; 2) c(sub 1) and c(sub 2) are not independent because a general relation between the two that are valid for any Kappa and epsilon are derived; 3) c(sub 1), c(sub 2) become constant with values close to the empirical values c(sub 1 epsilon), c(sub epsilon 2), (i.e., homogenous flows); and 4) the empirical form of the diffusion term D(sub epsilon) is no longer needed because it gets substituted by the Kappa-epsilon dependence of c(sub 1), c(sub 2), which plays the role of the diffusion, together with the diffusion of the turbulent kinetic energy D(sub Kappa), which now enters the new equation (i.e., inhomogeneous flows). Thus, the three empirical ingredients c(sub 1 epsilon), c(sub epsilon 2), D (sub epsilon)are replaced by a single function c(sub 1)(Kappa, epsilon ) or c(sub 2)(Kappa, epsilon ), plus a D(sub Kappa)term. Three tests of the new equation for epsilon are presented: one concerning channel flow and two concerning the shear-driven planetary boundary layer (PBL).

Theoretical investigation of geometries, stabilities, electronic and optical properties for advanced Ag{sub n}@(ZnO){sub 42} (n=6-18) hetero-nanostructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Hai-Xia; Department of Physics, National University of Singapore, 117542; Wang, Xiao-Xu

The structural properties of Ag{sub n}@(ZnO){sub 42} (n=6-18) core-shell nanoparticles have been investigated by the first principles calculations, and the core-shell nanostructure with n=13 is proved to be the most stable one for the first time. Ag{sub 13}@(ZnO){sub 42} core-shell nanostructure possesses higher chemistry activity and shows a red shift phenomenon in the light of the absorption spectrum compare to the (ZnO){sub 48}, this can be confirmed by the calculated electron structure. The visible-light could be absorbed by Ag{sub 13}@(ZnO){sub 42} to improve the photo-catalysis of (ZnO){sub 48} nanostructure. Our results show good agreement with experiments.

Ocean Turbulence. Paper 3; Two-Point Closure Model Momentum, Heat and Salt Vertical Diffusivities in the Presence of Shear

NASA Technical Reports Server (NTRS)

Canuto, V. M.; Dubovikov, M. S.; Howard, A.; Cheng, Y.

1999-01-01

In papers 1 and 2 we have presented the results of the most updated 1-point closure model for the turbulent vertical diffusivities of momentum, heat and salt, K(sub m,h,s). In this paper, we derive the analytic expressions for K(sub m,h,s) using a new 2-point closure model that has recently been developed and successfully tested against some approx. 80 turbulence statistics for different flows. The new model has no free parameters. The expressions for K(sub m, h. s) are analytical functions of two stability parameters: the Turner number R(sub rho) (salinity gradient/temperature gradient) and the Richardson number R(sub i) (temperature gradient/shear). The turbulent kinetic energy K and its rate of dissipation may be taken local or non-local (K-epsilon model). Contrary to all previous models that to describe turbulent mixing below the mixed layer (ML) have adopted three adjustable "background diffusivities" for momentum. heat and salt, we propose a model that avoids such adjustable diffusivities. We assume that below the ML, K(sub m,h,s) have the same functional dependence on R(sub i) and R(sub rho) derived from the turbulence model. However, in order to compute R(sub i) below the ML, we use data of vertical shear due to wave-breaking measured by Gargett et al. (1981). The procedure frees the model from adjustable background diffusivities and indeed we use the same model throughout the entire vertical extent of the ocean. Using the new K(sub m,h, s), we run an O-GCM and present a variety of results that we compare with Levitus and the KPP model. Since the traditional 1-point (used in papers 1 and 2) and the new 2-point closure models used here represent different modeling philosophies and procedures, testing them in an O-GCM is indispensable. The basic motivation is to show that the new 2-point closure model gives results that are overall superior to the 1-point closure in spite of the fact that the latter rely on several adjustable parameters while the new 2-point closure has none. After the extensive comparisons presented in papers 1 and 2, we conclude that the new model presented here is overall superior for it not only is parameter free but also 2 because is part of a more general turbulence model that has been previously successfully tested on a wide variety of other types of turbulent flows.

IBM-2 calculation with configuration mixing for Ge isotopes

NASA Astrophysics Data System (ADS)

Padilla-Rodal, Elizabeth; Galindo-Uribarri, Alfredo

2005-04-01

Recent results on Coulomb excitation experiments of radioactive neutron-rich Ge isotopes at the Holifield Radioactive Ion Beam Facility allow the study of the systematic trend of B(E2; 0^+ ->2^+) between the sub-shell closures at N=40 and the N=50 [1]. The new information on the E2 transition strengths constitutes a stringent test for the nuclear models and has motivated us to revisit the use of Interacting Boson Model in this region. We show that the IBM-2 with configuration mixing is a successful model to describe the shape transition phenomena that take place around N=40 in stable germanium isotopes, as well as the predictions given by this model about the evolution of the structure for the radioactive ^78, 80, 82Ge nuclei. [1] E. Padilla-Rodal Ph.D. Thesis UNAM; submitted for publication.

Hollow nanoparticle cathode materials for sodium electrochemical cells and batteries

DOEpatents

Shevchenko, Elena; Rajh, Tijana; Johnson, Christopher S.; Koo, Bonil

2016-07-12

A cathode comprises, in its discharged state, a layer of hollow .gamma.-Fe.sub.2O.sub.3 nanoparticles disposed between two layers of carbon nanotubes, and preferably including a metallic current collector in contact with one of the layers of carbon nanotubes. Individual particles of the hollow .gamma.-Fe.sub.2O.sub.3 nanoparticles comprise a crystalline shell of .gamma.-Fe.sub.2O.sub.3 including cation vacancies within the crystal structure of the shell (i.e., iron vacancies of anywhere between 3% to 90%, and preferably 44 to 77% of available octahedral iron sites). Sodium ions are intercalated within at least some of the cation vacancies within the crystalline shell of the hollow .gamma.-Fe.sub.2O.sub.3 nanoparticles.

Effects of cluster-shell competition and BCS-like pairing in 12C

NASA Astrophysics Data System (ADS)

Matsuno, H.; Itagaki, N.

2017-12-01

The antisymmetrized quasi-cluster model (AQCM) was proposed to describe α-cluster and jj-coupling shell models on the same footing. In this model, the cluster-shell transition is characterized by two parameters, R representing the distance between α clusters and Λ describing the breaking of α clusters, and the contribution of the spin-orbit interaction, very important in the jj-coupling shell model, can be taken into account starting with the α-cluster model wave function. Not only the closure configurations of the major shells but also the subclosure configurations of the jj-coupling shell model can be described starting with the α-cluster model wave functions; however, the particle-hole excitations of single particles have not been fully established yet. In this study we show that the framework of AQCM can be extended even to the states with the character of single-particle excitations. For ^{12}C, two-particle-two-hole (2p2h) excitations from the subclosure configuration of 0p_{3/2} corresponding to a BCS-like pairing are described, and these shell model states are coupled with the three α-cluster model wave functions. The correlation energy from the optimal configuration can be estimated not only in the cluster part but also in the shell model part. We try to pave the way to establish a generalized description of the nuclear structure.

Development of magnetic luminescent core/shell nanocomplex particles with fluorescence using Rhodamine 6G

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Hee Uk; Song, Yoon Seok; Park, Chulhwan

2012-12-15

Graphical abstract: Display Omitted Highlights: ► A simple method was developed to synthesize Co-B/SiO{sub 2}/dye/SiO{sub 2} composite particles. ► The magnetic particle shows that highly luminescent and core/shell particles are formed. ► Such core/shell particles can be easily suspended in water. ► The magnetic particles could detect fluorescence for the application of biosensor. -- Abstract: A simple and reproducible method was developed to synthesize a novel class of Co-B/SiO{sub 2}/dye/SiO{sub 2} composite core/shell particles. Using a single cobalt core, Rhodamine 6G of organic dye molecules was entrapped in a silica shell, resulting in core/shell particles of ∼200 nm diameter. Analysesmore » using a variety of techniques such as transmission electron microscopy, X-ray photoelectron spectroscopy, vibration sample magnetometry, confocal laser scanning microscopy, and fluorescence intensity demonstrated that dye molecules were trapped inside the core/shell particles. A photoluminescence investigation showed that highly luminescent and photostable core/shell particles were formed. Such core/shell particles can be easily suspended in water. The synthesized magnetic particles could be used to detect fluorescence on glass substrate arrays for bioassay and biosensor applications.« less

Interplay of quasiparticle-vibration coupling and pairing correlations on β-decay half-lives

NASA Astrophysics Data System (ADS)

Niu, Y. F.; Niu, Z. M.; Colò, G.; Vigezzi, E.

2018-05-01

The nuclear β-decay half-lives of Ni and Sn isotopes, around the closed shell nuclei 78Ni and 132Sn, are investigated by computing the distribution of the Gamow-Teller strength using the Quasiparticle Random Phase Approximation (QRPA) with quasiparticle-vibration coupling (QPVC), based on ground-state properties obtained by Hartree-Fock-Bogoliubov (HFB) calculations. We employ the effective interaction SkM* and a zero-range effective pairing force. The half-lives are strongly reduced by including the QPVC. We study in detail the effects of isovector (IV) and isoscalar (IS) pairing. Increasing the IV strength tends to increase the lifetime for nuclei in the proximity of, but lighter than, the closed-shell ones in QRPA calculations, while the effect is significantly reduced by taking into account the QPVC. On the contrary, the IS pairing mainly plays a role for nuclei after the shell closure. Increasing its strength decreases the half-lives, and the effect at QRPA and QRPA+QPVC level is comparable. The effect of IS pairing is particularly pronounced in the case of the Sn isotopes, where it turns out to be instrumental to obtain good agreement with experimental data.

Charge radii of neutron-deficient Ca isotopes

NASA Astrophysics Data System (ADS)

Miller, A. J.; Minamisono, K.; Klose, A.; Everett, N.; Kalman, C.; Powel, R. C.; Watkins, J.; Garand, D.; Sumithrarachchi, C.; Krämer, J.; Maa, B.; Nörtershäuser, W.; Rossi, D. M.; Kujawa, C.; Pineda, S.; Lantis, J.; Liu, Y.; Mantica, P. F.; Pearson, M. R.

2017-09-01

Nucleon shell closures are generally associated with a local minimum in mean-square charge radii, 〈r2 〉 , along an isotopic chain. The 〈r2 〉 of 18Ar and 19K isotopes, however, do not show this signature at the N = 20 neutron shell closure. To gain a microscopic understanding of this abnormal behavior, measurements of 〈r2 〉 of neutron-deficient Ca isotopes below N = 20 have been proposed at the BEam COoling and LAser spectroscopy (BECOLA) facility at NSCL/MSU. Preliminary results will be presented and the deduced charge radii will be compared to theoretical calculations and the trends in the nearby isotopic chains. Work supported in part by NSF Grant PHY-15-65546, U.S. DOE Grant DE-NA0002924 and by the Deutsche Forschungsgemeinschaft through Grant SFB 1245.

Magnetization-induced enhancement of photoluminescence in core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia, Yanmin, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Zhou, Zhihua; Wei, Yongbin

2013-12-07

After the core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite synthesized through a facile sol-gel method was magnetized under an external magnetic field of 0.25 T for 4 h, an enhancement of ∼56% in photoluminescence intensity was observed. The remanent magnetization of the CoFe{sub 2}O{sub 4} core increases the intensity of the excited charge transfer transition of VO{sub 4}{sup 3−} group in YVO{sub 4}:Eu{sup 3+} shell, which may enhance the probability related to the Eu{sup 3+} radiative transition {sup 5}D{sub 0}-{sup 7}F{sub 2}, yielding to a high photoluminescence. The obvious remanent-magnetization-induced enhancement in photoluminescence is helpful in developing excellent magnetic/luminescent material for themore » practical display devices.« less

Thermal annealing dynamics of carbon-coated LiFePO{sub 4} nanoparticles studied by in-situ analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krumeich, Frank, E-mail: krumeich@inorg.chem.ethz.ch; Waser, Oliver; Pratsinis, Sotiris E.

The thermal behavior of core-shell carbon-coated lithium iron phosphate (LiFePO{sub 4}-C) nanoparticles made by flame spray pyrolysis (FSP) during annealing was investigated by in-situ transmission electron microscopy (TEM), in-situ X-ray powder diffraction (XRD) as well as ex-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Crystallization of the initially glassy LiFePO{sub 4}-C nanoparticles starts at quite low temperatures (T=400 °C), forming single crystals inside the confinement of the carbon shell. Upon increasing the temperature to T≥700 °C, LiFePO{sub 4} starts to diffuse through the carbon shell resulting in cavities inside the mostly intact carbon shell. By increasing the temperature further tomore » T≥800 °C, the initial core-shell morphology converts into open carbon shells (flakes and cenospheres) and bulky LiFePO{sub 4} particles (diameter in the range 300–400 nm), in agreement with ex-situ experiments. - Graphical abstract: TEM images of a typical sample area recorded at room temperature and after heating in-situ heating reveal the growth of particles and the formation of empty carbon cages. - Highlights: • LiFePO{sub 4} coated by a carbon shell is produced by flame spray pyrolysis. • The amorphous LiFePO{sub 4} starts to crystallize at 400 °C as revealed by in-situ XRD. • Crystal growth was visualized by TEM heating experiments. • The formation of empty carbon cages starts at 700 °C.« less

Solvation of carbonaceous molecules by para-H{sub 2} and ortho-D{sub 2} clusters. I. Polycyclic aromatic hydrocarbons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Calvo, F., E-mail: florent.calvo@univ-grenoble-alpes.fr; Yurtsever, E.

This work theoretically examines the progressive coating of planar polycyclic aromatic hydrocarbon (PAH) molecules ranging from benzene to circumcoronene (C{sub 54}H{sub 18}) by para-hydrogen and ortho-deuterium. The coarse-grained Silvera-Goldman potential has been extended to model the interactions between hydrogen molecules and individual atoms of the PAH and parametrized against quantum chemical calculations for benzene-H{sub 2}. Path-integral molecular dynamics simulations at 2 K were performed for increasingly large amounts of hydrogen coating the PAH up to the first solvation shell and beyond. From the simulations, various properties were determined such as the size of the first shell and its thickness asmore » well as the solvation energy. The degree of delocalization was notably quantified from an energy landscape perspective, by monitoring the fluctuations among inherent structures sampled by the trajectories. Our results generally demonstrate a high degree of localization owing to relatively strong interactions between hydrogen and the PAH, and qualitatively minor isotopic effects. In the limit of large hydrogen amounts, the shell size and solvation energy both follow approximate linear relations with the numbers of carbon and hydrogen in the PAH.« less

Limacina retroversa's response to combined effects of ocean acidification and sea water freshening

NASA Astrophysics Data System (ADS)

Manno, C.; Morata, N.; Primicerio, R.

2012-11-01

Anthropogenic carbon dioxide emissions induce ocean acidification, thereby reducing carbonate ion concentration, which may affect the ability of calcifying organisms to build shells. Pteropods, the main planktonic producers of aragonite in the worlds' oceans, may be particularly vulnerable to changes in sea water chemistry. The negative effects are expected to be most severe at high-latitudes, where natural carbonate ion concentrations are low. In this study we investigated the combined effects of ocean acidification and freshening on Limacina retroversa, the dominant pteropod in sub polar areas. Living L. retroversa, collected in Northern Norwegian Sea, were exposed to four different pH values ranging from the pre-industrial level to the forecasted end of century ocean acidification scenario. Since over the past half-century the Norwegian Sea has experienced a progressive freshening with time, each pH level was combined with a salinity gradient in two factorial, randomized experiments investigating shell degradation, swimming behavior and survival. In addition, to investigate shell degradation without any physiologic influence, one perturbation experiments using only shells of dead pteropods was performed. Lower pH reduced shell mass whereas shell dissolution increased with pCO2. Interestingly, shells of dead organisms had a higher degree of dissolution than shells of living individuals. Mortality of Limacina retroversa was strongly affected only when both pH and salinity reduced simultaneously. The combined effects of lower salinity and lower pH also affected negatively the ability of pteropods to swim upwards. Results suggest that the energy cost of maintaining ion balance and avoiding sinking (in low salinity scenario) combined with the extra energy cost necessary to counteract shell dissolution (in high pCO2 scenario), exceed the available energy budget of this organism causing the pteropods to change swimming behavior and begin to collapse. Since L. retroversa play an important role in the transport of carbonates to the deep oceans these findings have significant implications for the mechanisms influencing the inorganic carbon cycle in the sub-polar area.

K{sub β} to K{sub α} X-ray intensity ratios and K to L shell vacancy transfer probabilities of Co, Ni, Cu, and Zn

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anand, L. F. M.; Gudennavar, S. B., E-mail: shivappa.b.gudennavar@christuniversity.in; Bubbly, S. G.

The K to L shell total vacancy transfer probabilities of low Z elements Co, Ni, Cu, and Zn are estimated by measuring the K{sub β} to K{sub α} intensity ratio adopting the 2π-geometry. The target elements were excited by 32.86 keV barium K-shell X-rays from a weak {sup 137}Cs γ-ray source. The emitted K-shell X-rays were detected using a low energy HPGe X-ray detector coupled to a 16 k MCA. The measured intensity ratios and the total vacancy transfer probabilities are compared with theoretical results and others’ work, establishing a good agreement.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hall, J.; Richard, P.; Gray, T.J.

The systematics of single and double K-shell-vacancy production in titanium has been investigated in the limit of zero target thickness (approx.1 ..mu..g/cm/sup 2/) for incident C, N, O, F, Mg, Al, Si, S, and Cl ions over a maximum energy range of 0.5 to 6.5 MeV/amu. This corresponds to collision systems with 0.27< or =Z/sub 1//Z/sub 2/< or =0.77 and 0.24< or =v/sub 1//vK< or =0.85, where v/sub 1/ is the projectile nuclear velocity and vK is the mean velocity of an electron in the target K shell. The present work is divided into four major sections. (1) Single K-shell-vacancymore » production has been investigated by measuring K..cap alpha.. and K..beta.. p satellite x-ray-production cross sections for projectiles incident with no K-shell vacancies. For incident ions with Z/sub 1/> or =9, the contribution due to electron-transfer processes from the target K shell to outer shells of the projectile has also been noted. (2) Single K-shell--to--K-shell electron-transfer cross sections have been obtained indirectly by the measuring of the enhancement in the Ti K x-ray production cross section for bare incident projectiles over ions incident with no initial K-shell vacancies. (3) Double K-vacancy production has been investigated by measuring the K..cap alpha.. hypersatellite intensity in ratio to the total K..cap alpha.. intensity. (4) Double K-shell--to--K-shell electron-transfer cross sections have been obtained indirectly with the use of a procedure similar to that used for single K to K transfer. The measured cross sections have been compared to theoretical models for direct Coulomb ionization and inner-shell electron transfer and have been used to investigate the relative importance of these mechanisms for K-vacancy production in heavy-ion--atom collisions.« less

High performance of SDC and GDC core shell type composite electrolytes using methane as a fuel for low temperature SOFC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Irshad, Muneeb; Siraj, Khurram, E-mail: razahussaini786@gmail.com, E-mail: khurram.uet@gmail.com; Javed, Fayyaz

Nanocomposites Samarium doped Ceria (SDC), Gadolinium doped Ceria (GDC), core shell SDC amorphous Na{sub 2}CO{sub 3} (SDCC) and GDC amorphous Na{sub 2}CO{sub 3} (GDCC) were synthesized using co-precipitation method and then compared to obtain better solid oxide electrolytes materials for low temperature Solid Oxide Fuel Cell (SOFCs). The comparison is done in terms of structure, crystallanity, thermal stability, conductivity and cell performance. In present work, XRD analysis confirmed proper doping of Sm and Gd in both single phase (SDC, GDC) and dual phase core shell (SDCC, GDCC) electrolyte materials. EDX analysis validated the presence of Sm and Gd in bothmore » single and dual phase electrolyte materials; also confirming the presence of amorphous Na{sub 2}CO{sub 3} in SDCC and GDCC. From TGA analysis a steep weight loss is observed in case of SDCC and GDCC when temperature rises above 725 °C while SDC and GDC do not show any loss. The ionic conductivity and cell performance of single phase SDC and GDC nanocomposite were compared with core shell GDC/amorphous Na{sub 2}CO{sub 3} and SDC/ amorphous Na{sub 2}CO{sub 3} nanocomposites using methane fuel. It is observed that dual phase core shell electrolytes materials (SDCC, GDCC) show better performance in low temperature range than their corresponding single phase electrolyte materials (SDC, GDC) with methane fuel.« less

Structure of neutron-rich nuclei around the N = 50 shell-gap closure

NASA Astrophysics Data System (ADS)

Faul, T.; Duchêne, G.; Thomas, J.-C.; Nowacki, F.; Huyse, M.; Van Duppen, P.

2010-04-01

The structure of neutron-rich nuclei in the vicinity of 78Ni have been investigated via the β-decay of 71,73,75Cu isotopes (ISOLDE, CERN). Experimental results have been compared with shell-model calculations performed with the ANTOINE code using a large (2p3/21f5/22p1/21g9/2) valence space and a 56/28Ni28 core.

Theory of electron capture from a hydrogen-like ion by a bare ion with extensions to inner-shell capture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alston, S.G.

1982-01-01

A complete systematic derivation is given of a new approximation for the calculation of the cross section for electron capture from a hydrogen-like ion of large nuclear charge Z/sub T/e by a bare ion of charge Z/sub p/e moving with speed v. The amplitude in the wave treatment is obtained through consistent expansion in the small parameters Z/sub p//Z/sub T/ and Z/sub p/e/sup 2//hv; however, the ratio Z/sub T/e/sup 2//hv is not assumed small. Electron-target nucleus interactions are included to all orders and electron-projectile interactions were included consistently to first order so that the theory is called the strong potentialmore » Born (SPB). Following a careful analysis of the approach to the energy shell, an off-shell factor is seen to arise which does not appear in the impulse approximation (IA). The effects of this factor on the capture amplitude are explored. It is shown that, in comparison with the IA, the correct weighting of the target spectrum of intermediate states in the SPB significantly alters the 1s ..-->.. ns cross section and at the same time makes peaking approximations to the amplitude more realistic, even for intermediate velocity Z/sub p/e/sup 2//h<« less

Site specific atomic polarizabilities in endohedral fullerenes and carbon onions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zope, Rajendra R., E-mail: rzope@utep.edu; Baruah, Tunna; Computational Science Program, The University of Texas at El Paso, El Paso, Texas 79958

2015-08-28

We investigate the polarizability of trimetallic nitride endohedral fullerenes by partitioning the total polarizability into site specific components. This analysis indicates that the polarizability of the endohedral fullerene is essentially due to the outer fullerene cage and has insignificant contribution from the encapsulated unit. Thus, the outer fullerene cages effectively shield the encapsulated clusters and behave like Faraday cages. The polarizability of endohedral fullerenes is slightly smaller than the polarizability of the corresponding bare carbon fullerenes. The application of the site specific polarizabilities to C{sub 60}@C{sub 240} and C{sub 60}@C{sub 180} onions shows that, compared to the polarizability of isolatedmore » C{sub 60} fullerene, the encapsulation of the C{sub 60} in C{sub 240} and C{sub 180} fullerenes reduces its polarizability by 75% and 83%, respectively. The differences in the polarizability of C{sub 60} in the two onions is a result of differences in the bonding (intershell electron transfer), fullerene shell relaxations, and intershell separations. The site specific analysis further shows that the outer atoms in a fullerene shell contribute most to the fullerene polarizability.« less

Atomic x-ray production by relativistic heavy ions. [Cross sections, K and L shells, ionization 3 and 4. 88 GEV holes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ioannou, J.G.

1977-12-01

The interaction of heavy ion projectiles with the electrons of target atoms gives rise to the production, in the target, of K-, L- or higher shell vacancies which are in turn followed by the emission of characteristic x-rays. The calculation of the theoretical value of the K- and L-shells vacancy production cross section was carried out for heavy ion projectiles of any energy. The transverse component of the cross section is calculated for the first time in detail and extensive tables of its numerical value as a function of its parameters are also given. Experimental work for 4.88 GeV protonsmore » and 3 GeV carbon ions is described. The K vacancy cross section has been measured for a variety of targets from Ti to U. The agreement between the theoretical predictions and experimental results for the 4.88 GeV protons is rather satisfactory. For the 3 GeV carbon ions, however, it is observed that the deviation of the theoretical and experimental values of the K vacancy production becomes larger with the heavier target element. Consequently, the simple scaling law of Z/sub 1//sup 2/ for the cross section of the heavy ion with atomic number Z/sub 1/ to the proton cross section is not true, for the K-shell at least. A dependence on the atomic number Z/sub 2/ of the target of the form (Z/sub 1/ - ..cap alpha..Z/sub 2/)/sup 2/, instead of Z/sub 1//sup 2/, is found to give extremely good agreement between theory and experiment. Although the exact physical meaning of such dependence is not yet clearly understood, it is believed to be indicative of some sort of screening effect of the incoming fast projectile by the fast moving in Bohr orbits K-shell electrons of the target. The enhancement of the K-shell ionization cross section by relativistic heavy ions on heavy targets is also discussed in terms of its practical applications in various branches of science and technology.« less

Cofiring lignite with hazelnut shell and cotton residue in a pilot-scale fluidized bed combustor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zuhal Gogebakan; Nevin Selcuk

In this study, cofiring of high ash and sulfur content lignite with hazelnut shell and cotton residue was investigated in 0.3 MWt METU Atmospheric Bubbling Fluidized Bed Combustion (ABFBC) Test Rig in terms of combustion and emission performance of different fuel blends. The results reveal that cofiring of hazelnut shell and cotton residue with lignite increases the combustion efficiency and freeboard temperatures compared to those of lignite firing with limestone addition only. CO{sub 2} emission is not found sensitive to increase in hazelnut shell and cotton residue share in fuel blend. Cofiring lowers SO{sub 2} emissions considerably. Cofiring of hazelnutmore » shell reduces NO and N{sub 2}O emissions; on the contrary, cofiring cotton residue results in higher NO and N{sub 2}O emissions. Higher share of biomass in the fuel blend results in coarser cyclone ash particles. Hazelnut shell and cotton residue can be cofired with high ash and sulfur-containing lignite without operational problems. 32 refs., 12 figs., 11 tabs.« less

Improve the catalytic activity of {alpha}-Fe{sub 2}O{sub 3} particles in decomposition of ammonium perchlorate by coating amorphous carbon on their surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Yifu; Liu Xinghai, E-mail: liuxh@whu.edu.c; Nie Jiaorong

2011-02-15

Sphere- and pod-like {alpha}-Fe{sub 2}O{sub 3} particles have been selectively synthesized using NH{sub 3}.H{sub 2}O and NaOH solution to adjust the pH value of the designed synthetic system, respectively. The sphere-like {alpha}-Fe{sub 2}O{sub 3} particles with diameter about 25 nm on average were encapsulated into carbon shells to fabricate a novel core-shell composite ({alpha}-Fe{sub 2}O{sub 3}-C) through the coating experiments. The catalytic performance of the products on the thermal decomposition of ammonium perchlorate (AP) was investigated by thermal gravimetric analyzer (TG) and differential thermal analysis (DTA). The thermal decomposition temperatures of AP in the presence of pod-like {alpha}-Fe{sub 2}O{sub 3},more » sphere-like {alpha}-Fe{sub 2}O{sub 3} and {alpha}-Fe{sub 2}O{sub 3}-C are reduced by 72, 81 and 109 {sup o}C, respectively, which show that {alpha}-Fe{sub 2}O{sub 3}-C core-shell composites have higher catalytic activity than that of {alpha}-Fe{sub 2}O{sub 3}. -- Graphical abstract: The catalytic performance of pod-like {alpha}-Fe{sub 2}O{sub 3}, sphere-like {alpha}-Fe{sub 2}O{sub 3} and {alpha}-Fe{sub 2}O{sub 3}-C on the thermal decomposition of ammonium perchlorate (AP). Display Omitted Research highlights: {yields} Sphere- and pod-like {alpha}-Fe{sub 2}O{sub 3} particles have been selectively synthesized using NH{sub 3}.H{sub 2}O and NaOH solution to adjust the pH value. {yields} A novel core-shell composite ({alpha}-Fe{sub 2}O{sub 3}-C core-shell structured composite) has been successfully synthesized using sphere-like {alpha}-Fe{sub 2}O{sub 3} particles as the cores and glucose as the source of carbon. {yields} The thermal decomposition temperatures of AP in the presence of pod-like {alpha}-Fe{sub 2}O{sub 3}, sphere-like {alpha}-Fe{sub 2}O{sub 3} and {alpha}-Fe{sub 2}O{sub 3}-C are reduced by 72, 81 and 109 {sup o}C, respectively, which shows that these materials have high catalytic activity.« less

Seasonal Variations of the Earth's Gravitational Field: An Analysis of Atmospheric Pressure, Ocean Tidal, and Surface Water Excitation

NASA Technical Reports Server (NTRS)

Dong, D,; Gross, R.S.; Dickey, J.

1996-01-01

Monthly mean gravitational field parameters (denoted here as C(sub even)) that represent linear combinations of the primarily even degree zonal spherical harmonic coefficients of the Earth's gravitational field have been recovered using LAGEOS I data and are compared with those derived from gridded global surface pressure data of the National meteorological center (NMC) spanning 1983-1992. The effect of equilibrium ocean tides and surface water variations are also considered. Atmospheric pressure and surface water fluctuations are shown to be the dominant cause of observed annual C(sub even) variations. Closure with observations is seen at the 1sigma level when atmospheric pressure, ocean tide and surface water effects are include. Equilibrium ocean tides are shown to be the main source of excitation at the semiannual period with closure at the 1sigma level seen when both atmospheric pressure and ocean tide effects are included. The inverted barometer (IB) case is shown to give the best agreement with the observation series. The potential of the observed C(sub even) variations for monitoring mass variations in the polar regions of the Earth and the effect of the land-ocean mask in the IB calculation are discussed.

Buckling and Damage Resistance of Transversely-Loaded Composite Shells

NASA Technical Reports Server (NTRS)

Wardle, Brian L.

1998-01-01

Experimental and numerical work was conducted to better understand composite shell response to transverse loadings which simulate damage-causing impact events. The quasi-static, centered, transverse loading response of laminated graphite/epoxy shells in a [+/-45(sub n)/O(sub n)](sub s) layup having geometric characteristics of a commercial fuselage are studied. The singly-curved composite shell structures are hinged along the straight circumferential edges and are either free or simply supported along the curved axial edges. Key components of the shell response are response instabilities due to limit-point and/or bifurcation buckling. Experimentally, deflection-controlled shell response is characterized via load-deflection data, deformation-shape evolutions, and the resulting damage state. Finite element models are used to study the kinematically nonlinear shell response, including bifurcation, limit-points, and postbuckling. A novel technique is developed for evaluating bifurcation from nonlinear prebuckling states utilizing asymmetric spatial discretization to introduce numerical perturbations. Advantages of the asymmetric meshing technique (AMT) over traditional techniques include efficiency, robustness, ease of application, and solution of the actual (not modified) problems. The AMT is validated by comparison to traditional numerical analysis of a benchmark problem and verified by comparison to experimental data. Applying the technique, bifurcation in a benchmark shell-buckling problem is correctly identified. Excellent agreement between the numerical and experimental results are obtained for a number of composite shells although predictive capability decreases for stiffer (thicker) specimens which is attributed to compliance of the test fixture. Restraining the axial edge (simple support) has the effect of creating a more complex response which involves unstable bifurcation, limit-point buckling, and dynamic collapse. Such shells were noted to bifurcate into asymmetric deformation modes but were undamaged during testing. Shells in this study which were damaged were not observed to bifurcate. Thus, a direct link between bifurcation and atypical damage could not be established although the mechanism (bifurcation) was identified. Recommendations for further work in these related areas are provided and include extensions of the AMT to other shell geometries and structural problems.

Ion-sculpting of nanopores in amorphous metals, semiconductors, and insulators

DOE Office of Scientific and Technical Information (OSTI.GOV)

George, H. Bola; Madi, Charbel S.; Aziz, Michael J.

2010-06-28

We report the closure of nanopores to single-digit nanometer dimensions by ion sculpting in a range of amorphous materials including insulators (SiO{sub 2} and SiN), semiconductors (a-Si), and metallic glasses (Pd{sub 80}Si{sub 20})--the building blocks of a single-digit nanometer electronic device. Ion irradiation of nanopores in crystalline materials (Pt and Ag) does not cause nanopore closure. Ion irradiation of c-Si pores below 100 deg. C and above 600 deg. C, straddling the amorphous-crystalline dynamic transition temperature, yields closure at the lower temperature but no mass transport at the higher temperature. Ion beam nanosculpting appears to be restricted to materials thatmore » either are or become amorphous during ion irradiation.« less

Single and multi-layered core-shell structures based on ZnO nanorods obtained by aerosol assisted chemical vapor deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sáenz-Trevizo, A.; Amézaga-Madrid, P.; Pizá-Ruiz, P.

2015-07-15

Core–shell nanorod structures were prepared by a sequential synthesis using an aerosol assisted chemical vapor deposition technique. Several samples consisting of ZnO nanorods were initially grown over TiO{sub 2} film-coated borosilicate glass substrates, following the synthesis conditions reported elsewhere. Later on, a uniform layer consisting of individual Al, Ni, Ti or Fe oxides was grown onto ZnO nanorod samples forming the so-called single MO{sub x}/ZnO nanorod core–shell structures, where MO{sub x} was the metal oxide shell. Additionally, a three-layer core–shell sample was developed by growing Fe, Ti and Fe oxides alternately, onto the ZnO nanorods. The microstructure of the core–shellmore » materials was characterized by grazing incidence X-ray diffraction, scanning and transmission electron microscopy. Energy dispersive X-ray spectroscopy was employed to corroborate the formation of different metal oxides. X-ray diffraction outcomes for single core–shell structures showed solely the presence of ZnO as wurtzite and TiO{sub 2} as anatase. For the multi-layered shell sample, the existence of Fe{sub 2}O{sub 3} as hematite was also detected. Morphological observations suggested the existence of an outer material grown onto the nanorods and further microstructural analysis by HR-STEM confirmed the development of core–shell structures in all cases. These studies also showed that the individual Al, Fe, Ni and Ti oxide layers are amorphous; an observation that matched with X-ray diffraction analysis where no apparent extra oxides were detected. For the multi-layered sample, the development of a shell consisting of three different oxide layers onto the nanorods was found. Overall results showed that no alteration in the primary ZnO core was produced during the growth of the shells, indicating that the deposition technique used herein was and it is suitable for the synthesis of homogeneous and complex nanomaterials high in quality and purity. In addition, materials absorptance determined from the total transmittance and reflectance spectra revealed a broader absorption interval including visible light, indicating potential uses of these nanostructures on solar energy appliances. - Graphical abstract: Display Omitted - Highlights: • Uniform ZnO nanorods (core)–metal oxide (shell) were obtained sequentially by AACVD. • Shells were structured of homogeneous single or multi-layered non-mixed metal oxides. • ZnO nanorod core was preserved during the shell synthesis. • Optical absorptance revealed visible interval absorption for FeO{sub x} shell samples. • Materials can be suitable for photocatalytic or photovoltaic applications.« less

Preparation and thermal stability of the spindle α-Fe{sub 2}O{sub 3}@SiO{sub 2} core–shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Xin; Niu, Yongan; Li, Yang

2014-03-15

The spindle α-Fe{sub 2}O{sub 3}@SiO{sub 2} core–shell nanoparticles (NPs) are prepared via hydrothermal synthesis and modified Stöber method. During these processes, shell thicknesses could be easily adjusted by the amount of tetraethylorthosilicate (TEOS), and the formation of core-free SiO{sub 2} could be effectively avoided. The structures and compositions of α-Fe{sub 2}O{sub 3}@SiO{sub 2} NPs are investigated by transmission electron microscope (TEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and ultraviolet–visible (UV–vis) absorption spectroscopy. These results reveal that the α-Fe{sub 2}O{sub 3}@SiO{sub 2} NPs with certain sizes are monodisperse and homogeneous. To estimate the thermal stability, the α-Fe{sub 2}O{submore » 3}, α-Fe{sub 2}O{sub 3}@SiO{sub 2} and SiO{sub 2} NPs are annealed at 600, 800 and 1000 °C for 1 h under air atmosphere, respectively. Furthermore, the stabilities of these NPs are confirmed by thermal analysis methods. The structure and shape stabilities of these as-prepared α-Fe{sub 2}O{sub 3}@SiO{sub 2} NPs are investigated by XRD and scanning electron microscope (SEM). -- Graphical abstract: Schematic of preparation of the monodisperse spindle α-Fe{sub 2}O{sub 3}@SiO{sub 2} nanoparticles (NPs). Highlights: • The spindle α-Fe{sub 2}O{sub 3}@SiO{sub 2} nanoparticles (NPs) are successfully prepared by hydrothermal synthesis and modified Stöber method. • Optical properties are estimated and calculated by UV vis absorption spectrum. • Thermal stability of the α-Fe{sub 2}O{sub 3}, α-Fe{sub 2}O{sub 3}@SiO{sub 2} and SiO{sub 2} NPs are compared and analyzed by the SEM technique. • The structural changes of α-Fe{sub 2}O{sub 3}@SiO{sub 2} NPs are measured by XRD measurement.« less

Structural analysis of Fe–Mn–O nanoparticles in glass ceramics by small angle scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raghuwanshi, Vikram Singh, E-mail: vikram.raghuwanshi@helmholtz-berlin.de; Harizanova, Ruzha; Tatchev, Dragomir

2015-02-15

Magnetic nanocrystals containing Fe and Mn were obtained by annealing of silicate glasses with the composition 13.6Na{sub 2}O–62.9SiO{sub 2}–8.5MnO–15.0Fe{sub 2}O{sub 3−x} (mol%) at 580 °C for different periods of time. Here, we present Small Angle Neutron Scattering using Polarized neutrons (SANSPOL) and Anomalous Small Angle X-ray Scattering (ASAXS) investigation on these glass ceramic samples. Analysis of scattering data from both methods reveals the formation of spherical core–shell type of nanoparticles with mean sizes between 10 nm and 100 nm. ASAXS investigation shows the particles have higher concentration of iron atoms and the shell like region surrounding the particles is enrichedmore » in SiO{sub 2}. SANSPOL investigation shows the particles are found to be magnetic and are surrounded by a non-magnetic shell-like region. - Graphical abstract: Magnetic spherical core–shell nanoparticles in glass ceramics: SANSPOL and ASAXS investigations. - Highlights: • Formation and growth mechanisms of magnetic nanoparticles in silicate glass. • SANSPOL and ASAXS methods employed to evaluate quantitative information. • Analyses showed formation of nanoparticles with spherical core–shell structures. • Core of the particle is magnetic and surrounded by weak magnetic shell like region.« less

Quasiballistic quantum transport through Ge/Si core/shell nanowires

NASA Astrophysics Data System (ADS)

Kotekar-Patil, D.; Nguyen, B.-M.; Yoo, J.; Dayeh, S. A.; Frolov, S. M.

2017-09-01

We study signatures of ballistic quantum transport of holes through Ge/Si core/shell nanowires at low temperatures. We observe Fabry-Pérot interference patterns as well as conductance plateaus at integer multiples of 2e 2/h at zero magnetic field. Magnetic field evolution of these plateaus reveals relatively large effective Landé g-factors. Ballistic effects are observed in nanowires with silicon shell thickness of 1-3 nm, but not in bare germanium wires. These findings inform the future development of spin and topological quantum devices which rely on ballistic sub-band-resolved transport.

Quasiballistic quantum transport through Ge/Si core/shell nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kotekar-Patil, D.; Nguyen, B-M; Yoo, J.

We study signatures of ballistic quantum transport of holes through Ge/Si core/shell nanowires at low temperatures. We observe Fabry–Pérot interference patterns as well as conductance plateaus at integer multiples of 2e 2/h at zero magnetic field. Magnetic field evolution of these plateaus reveals relatively large effective Landé g-factors. Ballistic effects are observed in nanowires with silicon shell thickness of 1–3 nm, but not in bare germanium wires. These findings inform the future development of spin and topological quantum devices which rely on ballistic sub-band-resolved transport.

Quasiballistic quantum transport through Ge/Si core/shell nanowires

DOE PAGES

Kotekar-Patil, D.; Nguyen, B-M; Yoo, J.; ...

2017-09-04

We study signatures of ballistic quantum transport of holes through Ge/Si core/shell nanowires at low temperatures. We observe Fabry–Pérot interference patterns as well as conductance plateaus at integer multiples of 2e 2/h at zero magnetic field. Magnetic field evolution of these plateaus reveals relatively large effective Landé g-factors. Ballistic effects are observed in nanowires with silicon shell thickness of 1–3 nm, but not in bare germanium wires. These findings inform the future development of spin and topological quantum devices which rely on ballistic sub-band-resolved transport.

Stabilization of Pt monolayer catalysts under harsh conditions of fuel cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Xiaoming; Yu, Shansheng; Zheng, Weitao, E-mail: wtzheng@jlu.edu.cn, E-mail: pingliu3@bnl.gov

2015-05-21

We employed density functional theory to explore the stability of core (M = Cu, Ru, Rh, Pd, Ag, Os, Ir, Au)-shell (Pt) catalysts under harsh conditions, including solutions and reaction intermediates involved in the oxygen reduction reaction (ORR) in fuel cells. A pseudomorphic surface alloy (PSA) with a Pt monolayer (Pt{sub 1ML}) supported on an M surface, Pt{sub 1ML}/M(111) or (001), was considered as a model system. Different sets of candidate M cores were identified to achieve a stable Pt{sub 1ML} shell depending on the conditions. In vacuum conditions, the Pt{sub 1ML} shell can be stabilized on the most ofmore » M cores except Cu, Ag, and Au. The situation varies under various electrochemical conditions. Depending on the solutions and the operating reaction pathways of the ORR, different M should be considered. Pd and Ir are the only core metals studied, being able to keep the Pt{sub ML} shell intact in perchloric acid, sulfuric acid, phosphoric acid, and alkaline solutions as well as under the ORR conditions via different pathways. Ru and Os cores should also be paid attention, which only fall during the ORR via the *OOH intermediate. Rh core works well as long as the ORR does not undergo the pathway via *O intermediate. Our results show that PSAs can behave differently from the near surface alloy, Pt{sub 1ML}/M{sub 1ML}/Pt(111), highlighting the importance of considering both chemical environments and the atomic structures in rational design of highly stable core-shell nanocatalysts. Finally, the roles that d-band center of a core M played in determining the stability of supported Pt{sub 1ML} shell were also discussed.« less

Chameleon scalar fields in relativistic gravitational backgrounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsujikawa, Shinji; Tamaki, Takashi; Tavakol, Reza, E-mail: shinji@rs.kagu.tus.ac.jp, E-mail: tamaki@gravity.phys.waseda.ac.jp, E-mail: r.tavakol@qmul.ac.uk

2009-05-15

We study the field profile of a scalar field {phi} that couples to a matter fluid (dubbed a chameleon field) in the relativistic gravitational background of a spherically symmetric spacetime. Employing a linear expansion in terms of the gravitational potential {Phi}{sub c} at the surface of a compact object with a constant density, we derive the thin-shell field profile both inside and outside the object, as well as the resulting effective coupling with matter, analytically. We also carry out numerical simulations for the class of inverse power-law potentials V({phi}) = M{sup 4+n}{phi}{sup -n} by employing the information provided by ourmore » analytical solutions to set the boundary conditions around the centre of the object and show that thin-shell solutions in fact exist if the gravitational potential {Phi}{sub c} is smaller than 0.3, which marginally covers the case of neutron stars. Thus the chameleon mechanism is present in the relativistic gravitational backgrounds, capable of reducing the effective coupling. Since thin-shell solutions are sensitive to the choice of boundary conditions, our analytic field profile is very helpful to provide appropriate boundary conditions for {Phi}{sub c}{approx}« less

L-shell x-ray production cross sections of Ni, Cu, Ge, As, Rb, Sr, Y, Zr, and Pd by (0. 25--2. 5)-MeV protons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duggan, J.L.; Kocur, P.M.; Price, J.L.

1985-10-01

L-shell x-ray production cross sections by /sub 1//sup 1/H/sup +/ ions are reported. The data are compared to the first Born approximation (plane-wave Born approximation for direct ionization and Oppenheimer-Brinkman-Kramers approximation for electron capture) and to the ECPSSR (energy-loss and Coulomb-deflection effects, perturbed stationary-state approximation with relativistic correction) theory. The energy of the protons ranged from 0.25 to 2.5 MeV in steps of 0.25 MeV. The targets used in these measurements were /sub 28/Ni, /sub 29/Cu, /sub 32/Ge, /sub 33/As, /sub 37/Rb, /sub 38/Sr, /sub 39/Y, /sub 40/Zr, and /sub 46/Pd. The first Born theory generally agrees with the datamore » found in the literature at high energies and overpredicts them below 1.5 MeV. The ECPSSR predictions are in better agreement with experimental cross sections. At 0.25 MeV our data, however, are underestimated by this theory and tend to agree with the first Born approximation.« less

Ocean Turbulence. Paper 2; One-Point Closure Model Momentum, Heat and Salt Vertical Diffusivities in the Presence of Shear

NASA Technical Reports Server (NTRS)

Canuto, V. M.; Howard, A.; Cheng, Y.; Dubovikov, M. S.

1999-01-01

We develop and test a 1-point closure turbulence model with the following features: 1) we include the salinity field and derive the expression for the vertical turbulent diffusivities of momentum K(sub m) , heat K(sub h) and salt K(sub s) as a function of two stability parameters: the Richardson number R(sub i) (stratification vs. shear) and the Turner number R(sub rho) (salinity gradient vs. temperature gradient). 2) to describe turbulent mixing below the mixed layer (ML), all previous models have adopted three adjustable "background diffusivities" for momentum, heat and salt. We propose a model that avoids such adjustable diffusivities. We assume that below the ML, the three diffusivities have the same functional dependence on R( sub i) and R(sub rho) as derived from the turbulence model. However, in order to compute R(sub i) below the ML, we use data of vertical shear due to wave-breaking.measured by Gargett et al. The procedure frees the model from adjustable background diffusivities and indeed we employ the same model throughout the entire vertical extent of the ocean. 3) in the local model, the turbulent diffusivities K(sub m,h,s) are given as analytical functions of R(sub i) and R(sub rho). 5) the model is used in an O-GCM and several results are presented to exhibit the effect of double diffusion processes. 6) the code is available upon request.

Shell evolution above Z ,N =50 within Skyrme density functional theory: The impact of deformation and tensor interactions

NASA Astrophysics Data System (ADS)

Shi, Yue

2017-03-01

Background: Recent years have seen considerable effort in associating the shell evolution (SE) for a chain of isotones or isotopes with the underlying nuclear interactions. In particular, it has been fairly well established that the tensor part of the Skyrme interaction is indispensable for understanding certain SE above Z ,N =50 shell closures, as a function of nucleon numbers. Purpose: The purpose of the present work is twofold: (1) to study the effect of deformation due to blocking on the SE above Z ,N =50 shell closures and (2) to examine the optimal parametrizations in the tensor part which gives a proper description of the SE above Z ,N =50 shell closures. Methods: I use the Skyrme-Hartree-Fock-Bogoliubov (SHFB) method to compute the even-even vacua of the Z =50 isotopes and N =50 isotones. For Sb and odd-A Sn isotopes, I perform calculations with a blocking procedure which accounts for the polarization effects, including deformations. Results: The blocking SHFB calculations show that the light odd-A Sb isotopes, with only one valence proton occupying down-sloping Ω =11 /2- and Ω =7 /2+ Nilsson orbits, assume finite oblate deformations. This reduces the energy differences between 11 /2- and 7 /2+ states by about 500 keV for 51Sb56 -66 , bringing the energy-difference curve closer to the experimental one. With une2t1 energy density functional (EDF), which differs from unedf2 parametrization by tensor terms, a better description of the slope of Δ e (π 1 h11 /2-π 1 g7 /2) as a function of neutron number has been obtained. However, the trend of Δ e (π 1 g7 /2-π 2 d5 /2) curve is worse using une2t1 EDF. Δ e (ν 3 s1 /2-ν 2 d5 /2) and Δ e (ν 1 g7 /2-ν 2 d5 /2) curve for N =50 isotones using une2t1 seems to be consistent with experimental data. The neutron SE of Δ e (ν 1 h11 /2-ν 1 g7 /2) and Δ e (ν 1 g7 /2-ν 2 d5 /2) for Sn isotopes are shown to be sensive to αT tensor parameter. Conclusions: Within the Skyrme self-consistent mean-field model, the deformation degree of freedom has to be taken into account for Sb isotopes, N =51 isotones, and odd-A Sn isotopes when discussing variation of quantities like shell gap etc. The tensor terms are important for describing the strong variation of Δ E (Ωπ=11 /2--7 /2+) in Sb isotopes. The SE of 1 /2+ and 7 /2+ states in N =51 isotones may show signature for the existence of tensor interaction. The experimental excitation energies of 11 /2- and 7 /2+ states in odd-A Sn isotopes close to 132Sn give prospects for constraining the αT parameter.

The jump-off velocity of an impulsively loaded spherical shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chabaud, Brandon M.; Brock, Jerry S.

2012-04-13

We consider a constant temperature spherical shell of isotropic, homogeneous, linearly elastic material with density {rho} and Lame coefficients {lambda} and {mu}. The inner and outer radii of the shell are r{sub i} and r{sub o}, respectively. We assume that the inside of the shell is a void. On the outside of the shell, we apply a uniform, time-varying pressure p(t). We also assume that the shell is initially at rest. We want to compute the jump-off time and velocity of the pressure wave, which are the first time after t = 0 at which the pressure wave from themore » outer surface reaches the inner surface. This analysis computes the jump-off velocity and time for both compressible and incompressible materials. This differs substantially from [3], where only incompressible materials are considered. We will consider the behavior of an impulsively loaded, exponentially decaying pressure wave p(t) = P{sub 0{sup e}}{sup -{alpha}t}, where {alpha} {ge} 0. We notice that a constant pressure wave P(t) = P{sub 0} is a special case ({alpha} = 0) of a decaying pressure wave. Both of these boundary conditions are considered in [3].« less

Ground-state properties of neutron magic nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saxena, G., E-mail: gauravphy@gmail.com; Kaushik, M.

2017-03-15

A systematic study of the ground-state properties of the entire chains of even–even neutron magic nuclei represented by isotones of traditional neutron magic numbers N = 8, 20, 40, 50, 82, and 126 has been carried out using relativistic mean-field plus Bardeen–Cooper–Schrieffer approach. Our present investigation includes deformation, binding energy, two-proton separation energy, single-particle energy, rms radii along with proton and neutron density profiles, etc. Several of these results are compared with the results calculated using nonrelativistic approach (Skyrme–Hartree–Fock method) along with available experimental data and indeed they are found with excellent agreement. In addition, the possible locations of themore » proton and neutron drip-lines, the (Z, N) values for the new shell closures, disappearance of traditional shell closures as suggested by the detailed analyzes of results are also discussed in detail.« less

Evidence for the Role of Proton Shell Closure in Quasifission Reactions from X-Ray Fluorescence of Mass-Identified Fragments

NASA Astrophysics Data System (ADS)

Morjean, M.; Hinde, D. J.; Simenel, C.; Jeung, D. Y.; Airiau, M.; Cook, K. J.; Dasgupta, M.; Drouart, A.; Jacquet, D.; Kalkal, S.; Palshetkar, C. S.; Prasad, E.; Rafferty, D.; Simpson, E. C.; Tassan-Got, L.; Vo-Phuoc, K.; Williams, E.

2017-12-01

The atomic numbers and the masses of fragments formed in quasifission reactions are simultaneously measured at scission in 48Ti + 238U reactions at a laboratory energy of 286 MeV. The atomic numbers are determined from measured characteristic fluorescence x rays, whereas the masses are obtained from the emission angles and times of flight of the two emerging fragments. For the first time, thanks to this full identification of the quasifission fragments on a broad angular range, the important role of the proton shell closure at Z =82 is evidenced by the associated maximum production yield, a maximum predicted by time-dependent Hartree-Fock calculations. This new experimental approach gives now access to precise studies of the time dependence of the N /Z (neutron over proton ratios of the fragments) evolution in quasifission reactions.

Gram-Scale Synthesized Pd2Co-Supported PtMonolayers Electrocatalysts for Oxygen Reduction Reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, W.P.; Sasaki, K.; Su, D.

2010-04-21

Gram-scale synthesis of Pt{sub ML} electrocatalysts with a well-defined core-shell structure has been carried out using method involving galvanic displacement of an underpotential deposition Cu layer. The Pt shell thickness can be controlled by stepwise deposition. The Pt{at}Pd{sub 2}Co/C nanoparticles were characterized by X-ray powder diffraction, aberration-corrected scanning transmission electron microscopy, high-resolution energy-loss spectrometry, and in situ X-ray absorption spectroscopy. A complete Pt shell of 0.6 nm on a Pd{sub 2}Co core has been confirmed. The Pt{at}Pd{sub 2}Co/C core-shell electrocatalysts showed a very high activity for the oxygen reduction reaction; the Pt mass and specific activity were 0.72 A mg{supmore » -1}{sub Pt} and 0.5 mA cm{sup -2}, respectively (3.5 and 2.5 times higher than the corresponding values for commercial Pt catalysts), at 0.9 V in 0.1 M HClO{sub 4} at room temperature. In an accelerated potential cycling test, a loss in active surface area and a decrease in catalytic activity for gram-scale-synthesized Pt{sub ML} catalysts were also determined.« less

A systematic study of superheavy nuclei for Z = 114 and beyond using the relativistic mean field approach

NASA Astrophysics Data System (ADS)

Patra, S. K.; Wu, Cheng-Li; Praharaj, C. R.; Gupta, Raj K.

1999-05-01

We have studied the structural properties of even-even, neutron deficient, Z = 114-126, superheavy nuclei in the mass region A ˜ 270-320, using an axially deformed relativistic mean field model. The calculations are performed with three parameter sets (NL1, TM1 and NL-SH), in order to see the dependence of the structural properties on the force used. The calculated ground state shapes are found to be parameter dependent. For some parameter sets, many of the nuclei are degenerate in their ground state configuration. Special attention is given to the investigation of the magic structures (spherical shell closures) in the superheavy region. We find that some known magic numbers are absent and new closed shells are predicted. Large shell gaps appear at Z = 80, 92, (114), 120 and 138, N = 138, (164), (172), 184, (198), (228) and 258, irrespective of the parameter sets used. The numbers in parenthesis are those which correspond to relatively smaller gaps. The existence of new magic numbers in the valley of superheavy elements is discussed. It is suggested that nuclei around Z = 114 and N = 164 ˜ 172 could be considered as candidates for the next search of superheavy nuclei. The existence of superheavy islands around Z = 120 and N = 172 or N = 184 double shell closure is also discussed.

Two-nucleon high-spin states, the Bansal-French model and the crude shell model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chan, T.U.

Recent data on two-nucleon stretched high-spin states agree well with the crude shell model predictions. For two-neutron high-spin states, the A and T linear dependence of B/sub 2n/ in the Bansal-French model can be deduced from the A and T linear dependence of B/sub n/ and the crude shell model. 7/sub 2//sup -/ states in some Zn and Ge even nuclei might be two-proton states. This hypothesis should be confirmed by two-proton transfer reaction.

Preparation and characterization of WO{sub 3} nanoparticles, WO{sub 3}/TiO{sub 2} core/shell nanocomposites and PEDOT:PSS/WO{sub 3} composite thin films for photocatalytic and electrochromic applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boyadjiev, Stefan I., E-mail: boiajiev@gmail.com; Santos, Gustavo dos Lopes; Szűcs, Júlia

2016-03-25

In this study, monoclinic WO{sub 3} nanoparticles were obtained by thermal decomposition of (NH{sub 4}){sub x}WO{sub 3} in air at 600 °C. On them by atomic layer deposition (ALD) TiO{sub 2} films were deposited, and thus core/shell WO{sub 3}/TiO{sub 2} nanocomposites were prepared. We prepared composites of WO{sub 3} nanoparticles with conductive polymer as PEDOT:PSS, and deposited thin films of them on glass and ITO substrates by spin coating. The formation, morphology, composition and structure of the as-prepared pure and composite nanoparticles, as well thin films, were studied by TEM, SEM-EDX and XRD. The photocatalytic activity of both the WO{submore » 3} and core/shell WO{sub 3}/TiO{sub 2} nanoparticles was studied by decomposing methyl orange in aqueous solution under UV light irradiation. Cyclic voltammetry measurements were performed on the composite PEDOT:PSS/WO{sub 3} thin films, and the coloring and bleaching states were studied.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nag, Somnath; Singh, A. K.; Hagemann, G. B.

In this paper, high-spin states in 124Xe have been populated using the 80Se( 48Ca, 4n) reaction at a beam energy of 207 MeV and high-multiplicity, γ-ray coincidence events were measured using the Gammasphere spectrometer. Six high-spin rotational bands with moments of inertia similar to those observed in neighboring nuclei have been observed. The experimental results are compared with calculations within the framework of the Cranked Nilsson-Strutinsky model. Finally, it is suggested that the configurations of the bands involve excitations of protons across the Z = 50 shell gap coupled to neutrons within the N = 50 - 82 shell ormore » excited across the N = 82 shell closure.« less

Calcium effects on stomatal movement in Commelina communis L

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwartz, A.; Ilan, N.; Grantz, D.A.

1988-07-01

Stomatal movements depends on both ion influx and efflux: attainment of steady state apertures reflects modulation of either or both processes. The role of Ca{sup 2+} in those two processes was investigated in isolated epidermal strips of Commelina communis, using the Ca{sup 2+} chelator EGTA to reduce apoplastic (Ca{sup 2+}). The results suggest that a certain concentration of Ca{sup 2+} is an absolute requirement for salt efflux and stomatal closure. EGTA (2 millimolar) increased KCl-dependent stomatal opening in darkness and completely inhibited the dark-induced closure of initially open stomata. Closure was inhibited even in a KCl-free medium. Thus, maintenance ofmore » stomata in the open state does not necessarily depend on continued K{sup +} influx but on the inhibition of salt efflux. Opening in the dark was stimulated by IAA in a concentration-dependent manner, up to 15.4 micrometer without reaching saturation, while the response to EGTA leveled off at 9.2 micrometer. IAA did not inhibit stomatal closure to the extent it stimulated opening. The response to IAA is thus consistent with a primary stimulation of opening, while EGTA can be considered a specific inhibitor of stomatal closing since it inhibits closure to a much larger degree than it stimulates opening. CO{sub 2} causes concentration-dependent reduction in the steady state stomatal aperture. EGTA completely reversed CO{sub 2}-induced closing of open stomata but only partially prevented the inhibition of opening.« less

Temperature effects on prevalent structures of hydrated Fe{sup +} complexes: Infrared spectroscopy and DFT calculations of Fe{sup +}(H{sub 2}O){sub n} (n = 3–8)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohashi, Kazuhiko, E-mail: kazu@chem.kyushu-univ.jp; Sekiya, Hiroshi; Sasaki, Jun

2014-12-07

Hydrated Fe{sup +} ions are produced in a laser-vaporization cluster source of a triple quadrupole mass spectrometer. The Fe{sup +}(H{sub 2}O){sub n} (n = 3–8) complexes are mass-selected and probed with infrared (IR) photodissociation spectroscopy in the OH-stretch region. Density functional theory (DFT) calculations are also carried out for analyzing the experimental IR spectra and for evaluating thermodynamic quantities of low-lying isomers. Solvation through H-bonding instead of direct coordination to Fe{sup +} is observed already at n = 3, indicating the completion of the first hydration shell with two H{sub 2}O molecules. Size dependent variations in the spectra for nmore » = 5–7 provide evidence for the second-shell completion at n = 6, where a linearly coordinated Fe{sup +}(H{sub 2}O){sub 2} subunit is solvated with four H{sub 2}O molecules. Overall spectral features for n = 3–8 agree well with those predicted for 2-coordinated structures. DFT calculations predict that such 2-coordinated structures are lowest in energy for smaller n. However, 4-coordinated isomers are predicted to be more stable for n = 7 and 8; the energy ordering is in conflict with the IR spectroscopic observation. Examination of free energy as a function of temperature suggests that the ordering of the isomers at warmer temperatures can be different from the ordering near 0 K. For n = 7 and 8, the 4-coordinated isomers should be observed at low temperatures because they are lowest in enthalpy. Meanwhile, outer-shell waters in the 2-coordinated structures are bound less rigidly; their contribution to entropy is rather large. The 2-coordinated structures become abundant at warmer temperatures, owing to the entropy effect.« less

EXTENDED NEUTRAL HYDROGEN IN THE ALIGNED SHELL GALAXIES Arp 230 AND MCG -5-7-1: FORMATION OF DISKS IN MERGING GALAXIES?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiminovich, David; Van Gorkom, J. H.; Van der Hulst, J. M.

2013-02-01

As part of an ongoing study of the neutral hydrogen (H I) morphology and kinematics of 'shell' elliptical galaxies, we present Very Large Array observations of two shell galaxies with aligned shells, Arp 230 and MCG -5-7-1. Our data provide the first H I images of Arp 230 and deeper images of MCG -5-7-1 than previously reported. Optical images of Arp 230 reveal a bright, aligned, interleaved shell system, making it an ideal candidate for 'phase-wrapped' shell formation following a radial encounter with a smaller companion. The fainter, non-interleaved shells of MCG -5-7-1 do not clearly favor a particular formationmore » scenario. The H I we detect in both galaxies extends to nearly the same projected distance as the optical shells. In Arp 230 this gas appears to be anti-correlated with the aligned shells, consistent with our expectations for phase-wrapped shells produced in a radial encounter. In MCG -5-7-1, we observe gas associated with the shells making a 'spatial wrapping' or looping scenario more plausible. Although the extended gas component in both galaxies is unevenly distributed, the gas kinematics are surprisingly regular, looking almost like complete disks in rotation. We use the H I kinematics and optical data to determine mass-to-light ratios M/L{sub B} of 2.4{sup +3.0}{sub -0.5} (at 13.5 kpc, 4.5 R{sub e} ) for Arp 230 and M/L{sub B} of 30 {+-} 7 (at 40 kpc, 7 R{sub e} ) in MCG -5-7-1. In both systems we find that this ratio changes as a function of radius, indicating the presence of a dark halo. By comparing orbital and precession timescales, we conclude that the potentials are slightly flattened. We infer a 5%-10% flattening for Arp 230 and less flattening in the case of MCG -5-7-1. Finally, we present images of the H I associated with the inner disk or (polar) ring of each galaxy and discuss possible explanations for their different present-day star formation rates. We detect total H I masses of 1.1 Multiplication-Sign 10{sup 9} M{sub Sun} in Arp 230 and 3.7 Multiplication-Sign 10{sup 9} M{sub Sun} in MCG -5-7-1. Both systems have H I masses, scale sizes, and regular kinematics similar to those of non-aligned shell galaxies we have previously studied (Cen A and NGC 2865). Furthermore, we (re-)emphasize in this paper that shell galaxies such as MCG -5-7-1, along with previously studied galaxies NGC 5128 (Cen A) and NGC 2865, are unique in that they provide evidence of recent accretion with gas and collisionless stars showing clear association, though the displacement suggests the presence of significant gas-dynamical interaction.« less

Neutrinoless double-β decay of Se82 in the shell model: Beyond the closure approximation

NASA Astrophysics Data System (ADS)

Sen'kov, R. A.; Horoi, M.; Brown, B. A.

2014-05-01

We recently proposed a method [R. A. Senkov and M. Horoi, Phys. Rev. C 88, 064312 (2013), 10.1103/PhysRevC.88.064312] to calculate the standard nuclear matrix elements for neutrinoless double-β decay (0νββ) of Ca48 going beyond the closure approximation. Here we extend this analysis to the important case of Se82, which was chosen as the base isotope for the upcoming SuperNEMO experiment. We demonstrate that by using a mixed method that considers information from closure and nonclosure approaches, one can get excellent convergence properties for the nuclear matrix elements, which allows one to avoid unmanageable computational costs. We show that in contrast with the closure approximation the mixed approach has a very weak dependence on the average closure energy. The matrix elements for the heavy neutrino-exchange mechanism that could contribute to the 0νββ decay of Se82 are also presented.

An Eddy-Diffusivity Mass-flux (EDMF) closure for the unified representation of cloud and convective processes

NASA Astrophysics Data System (ADS)

Tan, Z.; Schneider, T.; Teixeira, J.; Lam, R.; Pressel, K. G.

2014-12-01

Sub-grid scale (SGS) closures in current climate models are usually decomposed into several largely independent parameterization schemes for different cloud and convective processes, such as boundary layer turbulence, shallow convection, and deep convection. These separate parameterizations usually do not converge as the resolution is increased or as physical limits are taken. This makes it difficult to represent the interactions and smooth transition among different cloud and convective regimes. Here we present an eddy-diffusivity mass-flux (EDMF) closure that represents all sub-grid scale turbulent, convective, and cloud processes in a unified parameterization scheme. The buoyant updrafts and precipitative downdrafts are parameterized with a prognostic multiple-plume mass-flux (MF) scheme. The prognostic term for the mass flux is kept so that the life cycles of convective plumes are better represented. The interaction between updrafts and downdrafts are parameterized with the buoyancy-sorting model. The turbulent mixing outside plumes is represented by eddy diffusion, in which eddy diffusivity (ED) is determined from a turbulent kinetic energy (TKE) calculated from a TKE balance that couples the environment with updrafts and downdrafts. Similarly, tracer variances are decomposed consistently between updrafts, downdrafts and the environment. The closure is internally coupled with a probabilistic cloud scheme and a simple precipitation scheme. We have also developed a relatively simple two-stream radiative scheme that includes the longwave (LW) and shortwave (SW) effects of clouds, and the LW effect of water vapor. We have tested this closure in a single-column model for various regimes spanning stratocumulus, shallow cumulus, and deep convection. The model is also run towards statistical equilibrium with climatologically relevant large-scale forcings. These model tests are validated against large-eddy simulation (LES) with the same forcings. The comparison of results verifies the capacity of this closure to realistically represent different cloud and convective processes. Implementation of the closure in an idealized GCM allows us to study cloud feedbacks to climate change and to study the interactions between clouds, convections, and the large-scale circulation.

Facile synthesis and microwave absorbability of C@Ni–NiO core–shell hybrid solid sphere and multi-shelled NiO hollow sphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Hongjing, E-mail: wuhongjing@mail.nwpu.edu.cn; Wu, Guanglei, E-mail: wuguanglei@mail.xjtu.edu.cn; Wu, Qiaofeng

2014-11-15

We reported the preparation of C@Ni–NiO core–shell hybrid solid spheres or multi-shelled NiO hollow spheres by combining a facile hydrothermal route with a calcination process in H{sub 2} or air atmosphere, respectively. The synthesized C@Ni–NiO core–shell solid spheres with diameters of approximately 2–6 μm were in fact built from dense NiO nanoparticles coated by random two-dimensional metal Ni nanosheets without any visible pores. The multi-shelled NiO hollow spheres were built from particle-like ligaments and there are a lot of pores with size of several nanometers on the surface. Combined Raman spectra with X-ray photoelectron spectra (XPS), it suggested that themore » defects in the samples play a limited role in the dielectric loss. Compared with the other samples, the permeability of the samples calcined in H{sub 2} and air was increased slightly and the natural resonance frequency shifted to higher frequency (7, 11 and 14 GHz, respectively), leading to an enhancement of microwave absorption property. For the sample calcined in H{sub 2}, an optimal reflection loss less than − 10 was obtained at 7 GHz with a matching thickness of 5.0 mm. Our study demonstrated the potential application of C@Ni–NiO core–shell hybrid solid sphere or multi-shelled NiO hollow sphere as a more efficient electromagnetic (EM) wave absorber. - Highlights: • C@Ni–NiO core–shell hybrid solid sphere was synthesized by a facile method. • Multi-shelled NiO hollow sphere was synthesized by a facile method. • It suggested that the defects in the samples play a limited role in dielectric loss. • The permeability of the samples calcined in H{sub 2} and air was increased. • Microwave absorbability of C@Ni–NiO core–shell hybrid solid sphere was investigated.« less

Preparation, characterization, and infrared emissivity property of optically active polyurethane/TiO{sub 2}/SiO{sub 2} multilayered microspheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang Yong; Zhou Yuming, E-mail: ymzhou@seu.edu.cn; Ge Jianhua

Optically active polyurethane/titania/silica (LPU/TiO{sub 2}/SiO{sub 2}) multilayered core-shell composite microspheres were prepared by the combination of titania deposition on the surface of silica spheres and subsequent polymer grafting. LPU/TiO{sub 2}/SiO{sub 2} was characterized by FT-IR, UV-vis spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), SEM and TEM, and the infrared emissivity value (8-14 {mu}m) was investigated in addition. The results indicated that titania and polyurethane had been successfully coated onto the surfaces of silica microspheres. LPU/TiO{sub 2}/SiO{sub 2} exhibited clearly multilayered core-shell construction. The infrared emissivity values reduced along with the increase of covering layers thus provedmore » that the interfacial interactions had direct influence on the infrared emissivity. Besides, LPU/TiO{sub 2}/SiO{sub 2} multilayered microspheres based on the optically active polyurethane took advantages of the orderly secondary structure and strengthened interfacial synergistic actions. Consequently, it possessed the lowest infrared emissivity value. - Graphical Abstract: Optically active polyurethane/titania/silica (LPU/TiO{sub 2}/SiO{sub 2}) multilayered core-shell composite microspheres were prepared by the combination of titania deposition on the surface of silica spheres and subsequent polymer grafting. Highlights: > Optically active polyurethane based on tyrosine was used for the modification of nanoparticles. > LPU/TiO{sub 2}/SiO{sub 2} multilayered core-shell microspheres were prepared and characterized. > Interfacial interactions and secondary structure affected the infrared emissivity of composite.« less

QM/MM investigation of the concentration effects on the second-order nonlinear optical responses of solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hidalgo Cardenuto, Marcelo, E-mail: marcelo.hidalgo@unamur.be, E-mail: benoit.champagne@unamur.be; Instituto de Física, Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP; Champagne, Benoît, E-mail: marcelo.hidalgo@unamur.be, E-mail: benoit.champagne@unamur.be

2014-12-21

A multiscale approach combining quantum mechanics (QM) and molecular mechanics methods has been employed to investigate the effects of solute-solute interactions and therefore of concentration on the first hyperpolarizability of solutions of nitrobenzene in benzene. First, spatial distributions of solute and solvent molecules are generated using Monte Carlo simulations where the intermolecular interactions are described using the Lennard-Jones potentials and Coulomb terms. Then, a reduced number of statistically-uncorrelated configurations are sampled and submitted to time-dependent Hartree-Fock calculations of the first hyperpolarizability. When only one molecule is described quantum-mechanically and is embedded in the electrostatic polarization field of the solution describedmore » by point charges, β{sub HRS} and β{sub //} as well as the depolarization ratio increase in parallel with the concentration in nitrobenzene. This effect is attributed to the increase of the polarization field associated with the presence of polar nitrobenzene molecules in the surrounding. Then, the first solvation shell is considered explicitly in the QM calculation to address solute-solute interactions effects. When the number of nitrobenzenes in the first solvation shell increases, β{sub HRS} and β{sub //} normalized to the number of nitrobenzene molecules decrease and this decrease attains roughly 50% when there are 3 nitrobenzene molecules in the first solvation shell. These drastic reductions of the first hyperpolarizability result from (partial) centro-symmetric arrangements between the nitrobenzene molecules, as supported by the relationship between β and the angle between the nitrobenzene charge transfer axes. Moreover, these β decreases originate mostly from the reduction of the dipolar β component, whereas the octupolar one is rather constant as a function of the nitrobenzene concentration.« less

Shell Model Far From Stability: Island of Inversion Mergers

NASA Astrophysics Data System (ADS)

Nowacki, F.; Poves, A.

2018-02-01

In this study we propose a common mechanism for the disappearance of shell closures far from stabilty. With the use of Large Scale Shell Model calculations (SM-CI), we predict that the region of deformation which comprises the heaviest Chromium and Iron isotopes at and beyond N=40 will merge with a new one at N=50 in an astonishing parallel to the N=20 and N=28 case in the Neon and Magnesium isotopes. We propose a valence space including the full pf-shell for the protons and the full sdg shell for the neutrons, which represents a come-back of the the harmonic oscillator shells in the very neutron rich regime. Our calculations preserve the doubly magic nature of the ground state of 78Ni, which, however, exhibits a well deformed prolate band at low excitation energy, providing a striking example of shape coexistence far from stability. This new Island of Inversion (IoI) adds to the four well documented ones at N=8, 20, 28 and 40.

A new LiNbO{sub 3}-type polar oxide with closed-shell cations: ZnPbO{sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Runze, E-mail: yu.r.aa@m.titech.ac.jp, E-mail: mazuma@msl.titech.ac.jp; Hojo, Hajime; Azuma, Masaki, E-mail: yu.r.aa@m.titech.ac.jp, E-mail: mazuma@msl.titech.ac.jp

2015-09-07

A new lithium-niobate (LiNbO{sub 3})-type polar compound, namely, ZnPbO{sub 3} (a = 5.41605(7) Å and c = 14.33151(3) Å), with closed-shell ions only was synthesized under high pressure and high temperature (8 GPa and 1273 K). A point-charge-model calculation based on atomic positions refined by Rietveld analysis of synchrotron X-ray diffraction data gave an electrical ionic polarization of 77 μC/cm{sup 2} along the hexagonal c-axis. Detailed structural analysis indicated that the contribution of Pb{sup 4+} in ZnPbO{sub 3} to the polarization was almost twice as large as that of Sn{sup 4+} in ZnSnO{sub 3}. Transport measurement showed metallic behavior of ZnPbO{sub 3} from room temperature to lowmore » temperature despite the fact that both cations are closed-shell ions.« less

LXA{sub 4} actions direct fibroblast function and wound closure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Herrera, Bruno S.; Microbiology Branch, US Army Dental and Trauma Research Detachment, Institute of Surgical Research, JBSA Fort Sam Houston, TX; Kantarci, Alpdogan

Timely resolution of inflammation is crucial for normal wound healing. Resolution of inflammation is an active biological process regulated by specialized lipid mediators including the lipoxins and resolvins. Failure of resolution activity has a major negative impact on wound healing in chronic inflammatory diseases that is manifest as excess fibrosis and scarring. Lipoxins, including Lipoxin A{sub 4} (LXA{sub 4}), have known anti-fibrotic and anti-scarring properties. The goal of this study was to elucidate the impact of LXA{sub 4} on fibroblast function. Mouse fibroblasts (3T3 Mus musculus Swiss) were cultured for 72 h in the presence of TGF-β1, to induce fibroblast activation.more » The impact of exogenous TGF-β1 (1 ng/mL) on LXA{sub 4} receptor expression (ALX/FPR2) was determined by flow cytometry. Fibroblast proliferation was measured by bromodeoxyuridine (BrdU) labeling and migration in a “scratch” assay wound model. Expression of α-smooth muscle actin (α-SMA), and collagen types I and III were measured by Western blot. We observed that TGF-β1 up-regulates LXA{sub 4} receptor expression, enhances fibroblast proliferation, migration and scratch wound closure. α-SMA levels and Collagen type I and III deposition were also enhanced. LXA{sub 4} slowed fibroblast migration and scratch wound closure at early time points (24 h), but wound closure was equal to TGF-β1 alone at 48 and 72 h. LXA{sub 4} tended to slow fibroblast proliferation at both concentrations, but had no impact on α-SMA or collagen production by TGF-β1 stimulated fibroblasts. The generalizability of the actions of resolution molecules was examined in experiments repeated with resolvin D2 (RvD2) as the agonist. The activity of RvD2 mimicked the actions of LXA{sub 4} in all assays, through an as yet unidentified receptor. The results suggest that mediators of resolution of inflammation enhance wound healing and limit fibrosis in part by modulating fibroblast function. - Highlights: • TGF-β1 up-regulates LXA{sub 4} receptor (ALX/FPR2) expression on fibroblast. • LXA{sub 4} regulates fibroblast migration and proliferation induced by TGF-β1. • SPMs have no impact on α-SMA, collagen type-I and III expression by fibroblast. • RvD2 regulates TGF-β1-induced fibroblast proliferation and scratch wound closure.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnesen, Christian; Rothstein, Ira Z.; Zupan, Jure

Using Tevatron bounds we derive upper limits on the LHC Higgs boson production rate assuming that no beyond the standard model (BSM) particles are being produced near their mass shell. A violation of these limits would constitute a smoking gun for light BSM particles. Furthermore, we demonstrate how R{sub T}, the ratio of the partially integrated Higgs transverse momentum distribution to the inclusive rate, can also be used as a probe of light BSM particles. This ratio is insensitive to heavy virtual effects and is approximately model independent. The perturbative expansion for R{sub T} has reduced renormalization scale dependence, duemore » to a cancellation of Wilson coefficients. A deviation from the SM value implies that light BSM particles are being produced near their mass shell. A model with colored scalars is used to investigate the model independence of R{sub T}.« less

Shell-model predictions for Lambda Lambda hypernuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gal, A.; Millener, D.

2011-06-02

It is shown how the recent shell-model determination of {Lambda}N spin-dependent interaction terms in {Lambda} hypernuclei allows for a reliable deduction of {Lambda}{Lambda} separation energies in {Lambda}{Lambda} hypernuclei across the nuclear p shell. Comparison is made with the available data, highlighting {sub {Lambda}{Lambda}}{sup 11}Be and {sub {Lambda}{Lambda}}{sup 12}Be which have been suggested as possible candidates for the KEK-E373 HIDA event.

Homoepitaxial n-core: p-shell gallium nitride nanowires: HVPE overgrowth on MBE nanowires.

PubMed

Sanders, Aric; Blanchard, Paul; Bertness, Kris; Brubaker, Matthew; Dodson, Christopher; Harvey, Todd; Herrero, Andrew; Rourke, Devin; Schlager, John; Sanford, Norman; Chiaramonti, Ann N; Davydov, Albert; Motayed, Abhishek; Tsvetkov, Denis

2011-11-18

We present the homoepitaxial growth of p-type, magnesium doped gallium nitride shells by use of halide vapor phase epitaxy (HVPE) on n-type gallium nitride nanowires grown by plasma-assisted molecular beam epitaxy (MBE). Scanning electron microscopy shows clear dopant contrast between the core and shell of the nanowire. The growth of magnesium doped nanowire shells shows little or no effect on the lattice parameters of the underlying nanowires, as measured by x-ray diffraction (XRD). Photoluminescence measurements of the nanowires show the appearance of sub-bandgap features in the blue and the ultraviolet, indicating the presence of acceptors. Finally, electrical measurements confirm the presence of electrically active holes in the nanowires.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Shuling, E-mail: shulingliu@aliyun.com; College of Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi 710021; Ma, Lanbing

Highlights: • ZnS/Ni{sub 2}P composites have been firstly synthesized via a gentle hydrothermal route. • The composites have been characterized by XRD, SEM and TEM. • ZnS/Ni{sub 2}P showed enhanced photocatalytic degradation activity for pyronine B. • The reason for the enhanced photocatalytic activity has been discussed. - Abstract: ZnS/Ni{sub 2}P core/shell composites were successfully synthesized using a hydrothermal method. The composites have been characterized by XRD, SEM, TEM and the corresponding results showed that the composites were composed of the cubic ZnS microspheres, which were made up of ZnS nanoparticles, and Ni{sub 2}P nanoparticles coated on the surfaces ofmore » ZnS microspheres. Compared with ZnS microspheres, ZnS/Ni{sub 2}P core/shell composites showed enhanced photocatalytic degradation activity for pyronine B under UV irradiation. This may be related to the effective separation of photogenerated electron–hole pairs in ZnS/Ni{sub 2}P composites which can greatly reduce the chance of their recombination. Furthermore, superoxide ions and hydroxyl radical can be more easily produced through ZnS/Ni{sub 2}P composites, which is also beneficial for the degradation of pyronine B.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ford, A.L.; Reading, J.F.; Becker, R.L.

Theoretical methods used previously for H/sup +/, He/sup 2 +/, and C/sup 6 +/ collisions with neutral argon atoms have been applied to collisions of H/sup +/, He/sup 2 +/, and Li/sup 3 +/ projectiles with neon, and to collisions of H/sup +/ with carbon targets. The energy range covered by the calculations is 0.4 to 4.0 MeV/amu for the neon target, and 0.2 to 2.0 MeV/amu for carbon. We calculate single-electron amplitudes for target K-shell ionization and target K- and L-shell, to projectile K-shell, charge transfer. These single-electron amplitudes are used, in an independent-particle model that allows for multielectronmore » processes, to compute K-shell vacancy production cross sections sigma/sup IPM//sub V/K, and cross sections sigma/sup IPM//sub C/,VK for producing a charge-transfer state of the projectile in the coincidence with a K-shell vacancy in the target. These cross sections are in reasonable agreement with the recent experiments of Rodbro et al. at Aarhus. In particular, the calculated, as well as the experimental, sigma/sub C/,VK scale with projectile nuclear charge Z/sub p/ less strongly than the Z/sup 5//sub p/ of the Oppenheimer-Brinkman-Kramers (OBK) approximation. For He/sup 2 +/ and Li/sup 3 +/ projectiles at collision energies below where experimental data are available, our calculated multielectron corrections to the single-electron approximation for sigma/sub C/,VK are large.« less

An Enriched Shell Element for Delamination Simulation in Composite Laminates

NASA Technical Reports Server (NTRS)

McElroy, Mark

2015-01-01

A formulation is presented for an enriched shell finite element capable of delamination simulation in composite laminates. The element uses an adaptive splitting approach for damage characterization that allows for straightforward low-fidelity model creation and a numerically efficient solution. The Floating Node Method is used in conjunction with the Virtual Crack Closure Technique to predict delamination growth and represent it discretely at an arbitrary ply interface. The enriched element is verified for Mode I delamination simulation using numerical benchmark data. After determining important mesh configuration guidelines for the vicinity of the delamination front in the model, a good correlation was found between the enriched shell element model results and the benchmark data set.

Synthesis, structure, and bonding of two lanthanum indium germanides with novel structures and properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guloy, A.M.; Corbett, J.D.

1996-04-24

The new tetragonal phases La{sub 3}In{sub 4}Ge and La{sub 3}InGe are obtained from high-temperature reactions of the elements in welded Ta followed by annealing. The structures of both were established by single-crystal X-ray diffraction in tetragonal space group I4/mcm (Z = 4 and 16, {alpha} = 8.5165(3) and 12.3083(2) {Angstrom}, c = 11.9024(4) and 16.0776(4) {Angstrom}, respectively). La{sub 3}In{sub 4}Ge contains layers or slabs of three-connected indium built of puckered 8-rings and 4-rings, or of squashed tetrahedra ({open_quotes}butterflies{close_quotes}) interlinked at all vertices, and these are separated by layers of La and isolated Ge. The phase is deficient of being amore » Zintl phase by three electrons per formula unit and is better described in terms of an alternate optimized and delocalized bonding picture and an open-shell metallic better described in terms of an alternate optimized and delocalized bonding picture and an open-shell metallic behavior for the In slabs. The more complex La{sub 3}InGe, isostructural with Gd{sub 3}Ga{sub 2}, is also layered. This phase contains pairs of mixed-occupancy (0.75 In, 0.25 Ge) sites separated by 3.020 {Angstrom}, as well as isolated In and Ge atoms. The former appear to be fully reduced closed-shell atoms (relative to the bonded Ga dimers in Gd{sub 3}Ga{sub 2}) that are held in somewhat close proximity by cation matrix effects. The compound appears to be semiconducting and thus is a classical Zintl phase, (La{sup +3}){sub 3}In{sup {minus}5}Ge{sup {minus}4} in the simplest oxidation state notation. High Coulomb energies are presumably important for the nature of the bonding and the stabilities of both compounds.« less

Formation of Hyper Hydrogen isotopes in light p-shell nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jolos, R. V., E-mail: jolos@theor.jinr.ru; Majling, L.; Majlingova, O.

Recent experiment by A1 Collaboration at Mainz, namely identification of {sub Λ}{sup 4}H hyperfragment from primary {sub Λ}{sup 9}Li hypernucleus produced in reaction (e, e′K{sup +}), stirred renewed interest in baryonic decay of hypernuclei. The important role of s{sup −1}s{sub Λ} excitation in p-shell hypernuclei as well as the existence of selection rules connected with [f] (Young diagram) was noted earlier within Translational Invariant Shell Model (TISM). The particular conditions of the present experiment (reaction is not selective and produces highly excited states) dictate extension of the simplest TISM: expansion of the harmonic oscillator basis space and compression of multipletsmore » (to only (λμ) for L and [f] for S, T). Such modified TISM explains abundance production of {sub Λ}{sup 4}H hyperfragment and predicts production of another Hyper Hydrogen {sub Λ}{sup 6}H.« less

Production of n-rich Nuclei along the Closed Shell N=126 in the collision 136Xe + 208Pb @E lab =870 MeV

NASA Astrophysics Data System (ADS)

Quero, D.; Vardaci, E.; Kozulin, E. M.; Zagrebaev, V. A.; Corradi, L.; Pulcini, A.; La Rana, G.; Itkis, I. M.; Knyazheva, G. N.; Novikov, K.; Harca, I.; Fioretto, E.; Stefanini, A. M.; Montanari, D.; Montagnoli, G.; Scarlassara, F.; Szilner, S.; Mijatović, T.; Trzaska, W. H.

2018-05-01

Multi-nucleon transfer reactions are nowadays the only known mean to produce neutron-rich nuclei in the Terra Incognita. The closed-shell region N=126 is crucial for both studying shell-quenching in exotic nuclei and the r-process, being its last “waiting-point”. The choice of suitable reactions is challenging and a favorable case is 136Xe+208Pb, near the Coulomb barrier, because their neutron shell-closures play a stabilizing role, favoring the proton-transfer from lead to xenon. TOF-TOF data were analyzed to reconstruct the mass-energy distribution of the primary fragments. Preliminary results of an experiment held at Laboratori Nazionali di Legnaro with PRISMA, aimed at A and Z identification of the products, will be shown.

Sub-seasonal oxygen and carbon isotope variations in shells of modern Radix sp. (Gastropoda) from the Tibetan Plateau: potential of a new archive for palaeoclimatic studies

NASA Astrophysics Data System (ADS)

Taft, Linda; Wiechert, Uwe; Riedel, Frank; Weynell, Marc; Zhang, Hucai

2012-02-01

Carbon and oxygen isotope ratios have been measured for nine aragonite shells of the gastropod genus Radix from the lake Bangda Co (30°29'N, 97°04'E, 4450 m a.s.l.) at the south-eastern edge and from two characteristic sites at the lake Kyaring Co (31°09'N, 88°17'E, 4650 m a.s.l.) on the central Tibetan Plateau. Radix shells were sampled for isotope ratio analysis with high spatial resolution along the ontogenetic spiral of growth providing the basis of isotope records with a sub-seasonal time-resolution. δ18O values of shells from Bangda Co are on average ˜-15.0‰ relative to PDB and the pattern exhibits a clear onset and progression of the summer monsoon precipitation indicated by a strong "amount effect". This pattern mirrors the precipitation pattern in the respective year and region as expected for a small (surface area ca 0.3 km2) and shallow (<5 m) lake or habitat with short water residence times and little evaporative 18O enrichment of the lake water. In contrast, δ18O values of Radix shells from Kyaring Co habitat A which is connected to the deep (several tens of metres) and big (surface area ca 660 km2) lake, average at ˜-13.0‰ consistent with a higher evaporation rate and longer water residence time. The latter is supported by more 18O enriched water in this habitat. The δ18O values of Radix shells from Kyaring Co habitat B are nearly as low as shells from Bangda Co due to the similar habitat characteristic but isotopic patterns of these shells exhibit a weaker "amount effect". In both lake systems δ13C values of the shells are coupled with oxygen isotopes because a large amount of isotopically light carbon is washed from mountain slopes into the lake during the rainy season. Although other processes influence the isotopic patterns, e.g. biological productivity (δ13C) or temperature (δ18O), these influences are minor compared with the monsoon signal or the effect of evaporation in the Radix shell records. The overall weaker amount effect in Radix shells from Kyaring Co habitat B compared with shells from Bangda Co are consistent with a current decreasing monsoon influence from the south-eastern edge towards the central Tibetan Plateau. Thus, fossil shells of the gastropod genus Radix are a valuable archive for reconstructing climatic and environmental changes on the Tibetan Plateau and provide information about former habitat sizes and depths.

Toward Aerosol/Cloud Condensation Nuclei (CCN) Closure during CRYSTAL-FACE

NASA Technical Reports Server (NTRS)

VanReken, Timothy M.; Rissman, Tracey, A.; Roberts, Gregory C.; Varutbangkul, Varuntida; Jonsson, Haflidi H.; Flagan, Richard C.; Seinfeld, John H.

2003-01-01

During July 2002, measurements of cloud condensation nuclei were made in the vicinity of southwest Florida as part of the Cirrus Regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) field campaign. These observations, at supersaturations of 0.2 and 0.85%, are presented here. The performance of each of the two CCN counters was validated through laboratory calibration and an in situ intercomparison. The measurements indicate that the aerosol sampled during the campaign was predominantly marine in character: the median concentrations were 233 cm-3 (at S = 0.2%) and 371 cm(sup -3) (at S = 0.85%). Three flights during the experiment differed from this general trend; the aerosol sampled during the two flights on 18 July was more continental in character, and the observations on 28 July indicate high spatial variability and periods of very high aerosol concentrations. This study also includes a simplified aerosol/CCN closure analysis. Aerosol size distributions were measured simultaneously with the CCN observations, and these data are used to predict a CCN concentration using Kohler theory. For the purpose of this analysis, an idealized composition of pure ammonium sulfate was assumed. The analysis indicates that in this case, there was good general agreement between the predicted and observed CCN concentrations: at S = 0.2%, N(sub predicted)/N(sub observed)= 1.047 (R(sup 2)= 0.911)); at S = 0.85%, N(sub predicted)/N(sub observed)=1.201 (R(sup 2)= 0.835)). The impacts of the compositional assumption and of including in-cloud data in the analysis are addressed. The effect of removing the data from the 28 July flight is also examined; doing so improves the result of the closure analysis at S = 0.85%. When omitting that atypical flight, N(sub predicted)/N(sub observed) = 1.085 (R(sup 2) = 0.770) at S = 0.85%.

Groundwater quality assessment plan for single-shell waste management area B-BX-BY at the Hanford Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

SM Narbutovskih

2000-03-31

Pacific Northwest National Laboratory conducted a first determination groundwater quality assessment at the Hanford Site. This work was performed for the US Department of Energy, Richland Operations Office, in accordance with the Federal Facility Compliance Agreement during the time period 1996--1998. The purpose of the assessment was to determine if waste from the Single-Shell Tank (SST) Waste Management Area (WMA) B-BX-BY had entered the groundwater at levels above the drinking water standards (DWS). The resulting assessment report documented evidence demonstrating that waste from the WMA has, most likely, impacted groundwater quality. Based on 40 CFR 265.93 [d] paragraph (7), themore » owner-operator must continue to make the minimum required determinations of contaminant level and of rate/extent of migrations on a quarterly basis until final facility closure. These continued determinations are required because the groundwater quality assessment was implemented prior to final closure of the facility.« less

Structure and magnetic properties of chromium doped cobalt molybdenum nitrides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guskos, Niko; Żołnierkiewicz, Grzegorz; Typek, Janusz

Four nanocomposites containing mixed phases of Co{sub 3}Mo{sub 3}N and Co{sub 2}Mo{sub 3}N doped with chromium have been prepared. A linear fit is found for relation between Co{sub 2}Mo{sub 3}N and chromium concentrations. The magnetization in ZFC and FC modes at different temperatures (2–300 K) and in applied magnetic fields (up to 70 kOe) have been investigated. It has been detected that many magnetic characteristics of the studied four nanocomposites correlate not with the chromium concentration but with nanocrystallite sizes. The obtained results were interpreted in terms of magnetic core-shell model of a nanoparticle involving paramagnetic core with two magneticmore » sublattices and a ferromagnetic shell related to chromium doping. - Highlights: • A new chromium doped mixed Co-Mn-N nanocomposites were synthesized. • Surface ferromagnetism was detected in a wide temperature range. • Core-shell model was applied to explain nanocomposites magnetism.« less

Systematic study of α decay of nuclei around the Z =82 , N =126 shell closures within the cluster-formation model and proximity potential 1977 formalism

NASA Astrophysics Data System (ADS)

Deng, Jun-Gang; Zhao, Jie-Cheng; Chu, Peng-Cheng; Li, Xiao-Hua

2018-04-01

In the present work, we systematically study the α decay preformation factors Pα within the cluster-formation model and α decay half-lives by the proximity potential 1977 formalism for nuclei around Z =82 ,N =126 closed shells. The calculations show that the realistic Pα is linearly dependent on the product of valance protons (holes) and valance neutrons (holes) NpNn . It is consistent with our previous works [Sun et al., Phys. Rev. C 94, 024338 (2016), 10.1103/PhysRevC.94.024338; Deng et al., Phys. Rev. C 96, 024318 (2017), 10.1103/PhysRevC.96.024318], in which Pα are model dependent and extracted from the ratios of calculated α half-lives to experimental data. Combining with our previous works, we confirm that the valance proton-neutron interaction plays a key role in the α preformation for nuclei around Z =82 ,N =126 shell closures whether the Pα is model dependent or microcosmic. In addition, our calculated α decay half-lives by using the proximity potential 1977 formalism taking Pα evaluated by the cluster-formation model can well reproduce the experimental data and significantly reduce the errors.

Transition Quadrupole Collectivity of Ar and Cl Isotopes Near N = 28

NASA Astrophysics Data System (ADS)

Winkler, R.; Gade, A.; Brown, B. A.; Glasmacher, T.; Baugher, T. R.; Bazin, D.; Grinyer, G. F.; McDaniel, S.; Meharchand, R.; Ratkiewicz, A.; Stroberg, R.; Walsh, K.; Weisshaar, D.; Riley, L. A.

2010-11-01

Measurements of the reduced quadrupole transition strengths, B(E2; 0^+ -> 2^+) of even-even nuclei guide our understanding of the onset collectivity with the addition of valence nucleons beyond the known shell structure of the atomic nucleus. The study of the quadrupole collectivity of neutron-rich ^47,48Ar and ^45,46Cl via relativistic Coulomb excitation was performed using a cocktail of exotic beams produced by the coupled cyclotron facility at NSCL. Particle tracking and identification was achieved on an event-by-event basis using the S800 high-resolution spectrograph. Gamma rays emitted at the reaction target position in coincidence with the detection of scattered particles were observed with the segmented high-purity Germanium array SeGA, a vital tool for the Doppler reconstruction of each observed event. Results from the present work provide insight into the persistence of the N = 28 shell closure and will be discussed in the framework of the shell model utilizing modern effective interactions in the sdpf valence space. This work is supported by the National Science Foundation under Grants No. PHY-0606007 and PHY-0758099.

Raman spectroscopy and time-resolved photoluminescence of BN and BxCyNz nanotubes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, J.; Han, Wei-Qiang; Walukiewicz, W.

2004-01-21

We report Raman and time-resolved photoluminescence spectroscopic studies of multiwalled BN and B{sub x}C{sub y}N{sub z} nanotubes. The Raman spectroscopy shows that the as-grown B{sub x}C{sub y}N{sub z} charge recombination, respectively. Comparison of the photoluminescence of BN nanotubes to that decay process is characterized by two time constants that are attributed to intra- and inter-BN sheet nanotubes as predicted by theory. nanotubes are radially phase separated into BN shells and carbon shells. The photoluminescence of hexagonal BN is consistent with the existence of a spatially indirect band gap in multi-walled BN.

Microstructure and dielectric properties of BaTiO{sub 3} ceramic doped with yttrium, magnesium, gallium and silicon for AC capacitor application

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Min-Jia; Yang, Hui; Zhejiang California International NanoSystems Institute, Hangzhou 310029

2014-12-15

Graphical abstract: Core–shell structure can be obtained in BaTiO{sub 3} ceramics co-doped with Y–Mg-Ga-Si. Y-Mg-Ga-Si co-dopant can obviously reduce dielectric loss, improve AC breakdown voltage and flatten temperature dependence of capacitance curve. - Highlights: • Y-Mg-Ga-Si co-doped BaTiO{sub 3} ceramics with core-shell structure were prepared. • Y{sup 3+}, Mg{sup 2+}, and Ga{sup 3+} dissolved in the lattice BaTiO{sub 3} replacing Ba{sup 2+} site or Ti{sup 4+} site. • Y{sup 3+} and Ga{sup 3+} tended to remain close to the grain boundaries as a shell maker. • Y-Mg-Ga-Si co-doped BaTiO{sub 3} ceramics show high AC breakdown voltage and low tanδ. -more » Abstract: The microstructures and dielectric properties of Y-Mg-Ga-Si co-doped barium titanate ceramics were investigated. Y{sup 3+} dissolved in the lattice of BaTiO{sub 3} replacing both Ba{sup 2+} site and Ti{sup 4+} site, and Mg{sup 2+} replaced Ti{sup 4+} site. The replacements of Y{sup 3+} and Mg{sup 2+} inhibit the grain growth, cause tetragonal-to-pseudocubic phase transition, reduce the dielectric loss, and flatten the temperature dependence of capacitance curve. The incorporation of Ga{sup 3+} can improve sintering and increase permittivity. Y{sup 3+} and Ga{sup 3+} tended to remain close to the grain boundaries, and play an important role as a shell maker in the formation of the core–shell structure in the co-doped BaTiO{sub 3} ceramics. Excellent dielectric properties: ϵ{sub r} = ∼2487, tanδ = ∼0.7% (at 1 kHz), ΔC/C{sub 25} < ∼6.56% (from −55 °C to 125 °C) and alternating current breakdown voltage E < ∼4.02 kV/mm can be achieved in the BaTiO{sub 3}–0.02Y{sub 2}O{sub 3}–0.03MgO–0.01Ga{sub 2}O{sub 3}–0.005SiO{sub 2} ceramics sintered at 1380 °C. This material has a potential application in alternating current multilayer ceramic capacitor.« less

Surfactant-assisted synthesis of mono-dispersed cubic BaTiO{sub 3} nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hai, Chunxi; Inukai, Koji; Takahashi, Yosuke

2014-09-15

Mono-dispersed BaTiO{sub 3} nanoparticles have been prepared via the assistance of capping agent poly(vinylpyrrolidone) (PVP). - Highlights: • BaTiO{sub 3} nanoparticles with single cubic crystal structure. • Poor dispersibility of nanoparticles has been overcome by in situ modification way. • Growth competition between BaTiO3 core and polymer shell. - Abstract: In this study, poly(vinylpyrrolidone)-assisted synthesis of mono-dispersed BaTiO{sub 3} nanoparticles have been reported. The various processing parameters, namely, refluxing temperature, KOH concentration, and poly(vinylpyrrolidone) concentration, have been varied, and the effects on the growth of BaTiO{sub 3} particles have been analyzed systematically. X-ray diffraction studies indicated that poly(vinylpyrrolidone) did notmore » affect the crystal structure, but rather influenced the crystal lattice structure. In addition, the use of surfactant poly(vinylpyrrolidone) hindered the agglomeration of the nanoparticles, and facilitated the formation of mono-dispersed core–shell organic/inorganic hybrid nanocomposite. Furthermore, the mineralizer KOH promoted the dissolution of reactants and promoted the crystallization of BaTiO{sub 3} particles. Accordingly, the dissolution-precipitation scheme was believed to be the mechanism underlying the formation of BaTiO{sub 3} particles. This was further substantiated by the experimental observations, which indicated that the nucleation and crystallization of the particles was affected by the KOH concentration in the reaction system. Finally, the formation of mono-dispersed core–shell nanocomposites proceeded via reaction limited cluster aggregation. We believe that the method proposed in this study could be extended for the synthesis of mono-dispersed nanoparticles for industrial applications.« less

Following electron impact excitations of Rn, Ra, Th, U and Pu single atom L sub-shells ionization cross section calculations by using Lotz’s equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ayinol, M., E-mail: aydinolm@dicle.edu.tr; Aydeniz, D., E-mail: daydeniz@hotmail.com

L shell ionization cross section and L{sub i} subshells ionization cross sections of Rn, Ra, Th, U, Pu atoms calculated. For each of atoms, ten different electron impact energy values (E{sub o}) are used. Calculations carried out by using Lotz equation in Matlab. First, calculations done for non-relativistic case by using non-relativistic Lotz equation then repeated with relativistic Lotz equation. σ{sub L} total and σ{sub Li}(i = 1,2,3) subshells ionisation cross section values obtained for E{sub o} values in the energy range of E{sub Li}

Assessment of sub-grid scale dispersion closure with regularized deconvolution method in a particle-laden turbulent jet

NASA Astrophysics Data System (ADS)

Wang, Qing; Zhao, Xinyu; Ihme, Matthias

2017-11-01

Particle-laden turbulent flows are important in numerous industrial applications, such as spray combustion engines, solar energy collectors etc. It is of interests to study this type of flows numerically, especially using large-eddy simulations (LES). However, capturing the turbulence-particle interaction in LES remains challenging due to the insufficient representation of the effect of sub-grid scale (SGS) dispersion. In the present work, a closure technique for the SGS dispersion using regularized deconvolution method (RDM) is assessed. RDM was proposed as the closure for the SGS dispersion in a counterflow spray that is studied numerically using finite difference method on a structured mesh. A presumed form of LES filter is used in the simulations. In the present study, this technique has been extended to finite volume method with an unstructured mesh, where no presumption on the filter form is required. The method is applied to a series of particle-laden turbulent jets. Parametric analyses of the model performance are conducted for flows with different Stokes numbers and Reynolds numbers. The results from LES will be compared against experiments and direct numerical simulations (DNS).

Double-detonation Sub-Chandrasekhar Supernovae: Synthetic Observables for Minimum Helium Shell Mass Models

NASA Astrophysics Data System (ADS)

Kromer, M.; Sim, S. A.; Fink, M.; Röpke, F. K.; Seitenzahl, I. R.; Hillebrandt, W.

2010-08-01

In the double-detonation scenario for Type Ia supernovae, it is suggested that a detonation initiates in a shell of helium-rich material accreted from a companion star by a sub-Chandrasekhar-mass white dwarf. This shell detonation drives a shock front into the carbon-oxygen white dwarf that triggers a secondary detonation in the core. The core detonation results in a complete disruption of the white dwarf. Earlier studies concluded that this scenario has difficulties in accounting for the observed properties of Type Ia supernovae since the explosion ejecta are surrounded by the products of explosive helium burning in the shell. Recently, however, it was proposed that detonations might be possible for much less massive helium shells than previously assumed (Bildsten et al.). Moreover, it was shown that even detonations of these minimum helium shell masses robustly trigger detonations of the carbon-oxygen core (Fink et al.). Therefore, it is possible that the impact of the helium layer on observables is less than previously thought. Here, we present time-dependent multi-wavelength radiative transfer calculations for models with minimum helium shell mass and derive synthetic observables for both the optical and γ-ray spectral regions. These differ strongly from those found in earlier simulations of sub-Chandrasekhar-mass explosions in which more massive helium shells were considered. Our models predict light curves that cover both the range of brightnesses and the rise and decline times of observed Type Ia supernovae. However, their colors and spectra do not match the observations. In particular, their B - V colors are generally too red. We show that this discrepancy is mainly due to the composition of the burning products of the helium shell of the Fink et al. models which contain significant amounts of titanium and chromium. Using a toy model, we also show that the burning products of the helium shell depend crucially on its initial composition. This leads us to conclude that good agreement between sub-Chandrasekhar-mass explosions and observed Type Ia supernovae may still be feasible but further study of the shell properties is required.

Evaluation of columns packed with shell particles with compounds of pharmaceutical interest.

PubMed

Ruta, Joséphine; Zurlino, Daria; Grivel, Candice; Heinisch, Sabine; Veuthey, Jean-Luc; Guillarme, Davy

2012-03-09

The commercial C18 columns packed with sub-3 μm shell particles were tested and compared to a reference UHPLC column, in terms of kinetic performance as well as selectivity, retention capability, peak shape and loading capacity. For this purpose, a set of pharmaceutically relevant molecules was selected, including acidic, neutral and basic drugs. Regarding kinetic performance, h(opt) values for the shell particles were found between 1.7 and 2, while the UHPLC column provided a value of approximately 2.5. However, this impressive performance should be considered with caution, particularly for the construction of kinetic plots since h(opt) values were sometimes related to the column dimensions, depending on the provider (h(opt) comprised between 1.8 and 2.6 for longer columns of 150 mm packed with shell particles). Despite the non-porous inner core of the shell particles representing between 25 and 36% of the particle, we demonstrated that the decrease in retention was on the maximum equal to 15% for Ascentis column while Acquity and Poroshell were strictly equivalent in terms of retention. Concerning loading capacity, it remains comparable to that of fully porous sub-2 μm particles and always more pronounced with 0.1% formic acid vs. phosphate buffer. The loading capacity of the different columns was found to be better correlated to the pore volume or surface coverage than the shell thickness. Experimentally, the most pronounced overloading was observed with the Poroshell. Finally, the selectivity and peak shape were evaluated using a mixture of basic and acidic drugs. It appears that results were very similar between sub-3 μm shell particles and fully porous sub-2-μm particles for our mixture of compounds, showing the ability to transfer existing methods to shell particles, with only limited adjustments. This study confirms the potential of columns packed with shell particles and demonstrates the interest of such column technology with pharmaceutical compounds. Copyright © 2011 Elsevier B.V. All rights reserved.

Surface-engineered core-shell nano-size ferrites and their antimicrobial activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baraliya, Jagdish D., E-mail: jdbaraliya@yahoo.co.in; Joshi, Hiren H., E-mail: jdbaraliya@yahoo.co.in

We report the results of biological study on core-shell structured MFe{sub 2}O{sub 4} (where M = Co, Mn, Ni) nanoparticles and influence of silica- DEG dual coating on their antimicrobial activity. Spherical MFe{sub 2}O{sub 4} nanoparticles were prepared via a Co-precipitation method. The microstructures and morphologies of these nanoparticles were studied by x-ray diffraction and FTIR. The antimicrobial activity study carried out in nutrient agar medium with addition of antimicrobial synthesis compound which is tested for its activity against different types of bacteria.

Review of A2B2O7 Pyrochlore Response to Irradiation and Pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lang, M.; Zhang, F; Zhang, J

2010-01-01

This article reviews recent research on swift heavy-ion irradiations and high-pressure studies on pyrochlores of the Gd{sub 2}Zr{sub 2-x}Ti{sub x}O{sub 7} binary. Applying three complementary analytical techniques (synchrotron X-ray diffraction, Raman spectroscopy and transmission electron microscopy) allowed for the investigation of the response of pyrochlore to irradiation and/or pressure. The chemical composition of pyrochlore has a strong effect on the character and energetics of the type of structural modifications that can be obtained under pressure or irradiation: For Ti-rich pyrochlores, the crystalline-to-amorphous transition is the dominant process. When Zr is substituted for Ti, an order-disorder transformation to the defect-fluorite structuremore » becomes the increasingly dominant process. Except for Gd{sub 2}Zr{sub 2}O{sub 7}, single ion tracks in pyrochlore consist of an amorphous core, surrounded by a crystalline, but disordered, defect-fluorite shell. This shell is surrounded by a defect-rich pyrochlore region. In contrast to similar effects observed when pressure or irradiation are applied separately, the response of the pyrochlore structure is significantly different when it is exposed simultaneously to pressure and irradiation. The combination of relativistic heavy ions with high pressure results in the formation of a new metastable pyrochlore phase. TEM and quantum-mechanical calculations suggest that these novel structural modifications are caused by the formation of nanocrystals and the modified energetics of nanomaterials.« less

Observation of high-spin bands with large moments of inertia in Xe 124

DOE PAGES

Nag, Somnath; Singh, A. K.; Hagemann, G. B.; ...

2016-09-07

In this paper, high-spin states in 124Xe have been populated using the 80Se( 48Ca, 4n) reaction at a beam energy of 207 MeV and high-multiplicity, γ-ray coincidence events were measured using the Gammasphere spectrometer. Six high-spin rotational bands with moments of inertia similar to those observed in neighboring nuclei have been observed. The experimental results are compared with calculations within the framework of the Cranked Nilsson-Strutinsky model. Finally, it is suggested that the configurations of the bands involve excitations of protons across the Z = 50 shell gap coupled to neutrons within the N = 50 - 82 shell ormore » excited across the N = 82 shell closure.« less

Light-stimulated cargo release from a core–shell structured nanocomposite for site-specific delivery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cai, Yun; Ling, Li; Li, Xiaofang

This paper reported a core–shell structured site-specific delivery system with a light switch triggered by low energy light (λ=510 nm). Its core was composed of supermagnetic Fe{sub 3}O{sub 4} nanoparticles for magnetic guiding and targeting. Its outer shell consisted of mesoporous silica molecular sieve MCM-41 which offered highly ordered hexagonal tunnels for cargo capacity. A light switch N1-(4aH-cyclopenta[1,2-b:5,4-b′]dipyridin-5(5aH)-ylidene)benzene-1, 4-diamine (CBD) was covalently grafted into these hexagonal tunnels, serving as light stimuli acceptor with loading content of 1.1 μM/g. This composite was fully characterized and confirmed by SEM, TEM, XRD patterns, N{sub 2} adsorption/desorption, thermogravimetric analysis, IR, UV–vis absorption and emissionmore » spectra. Experimental data suggested that this composite had a core as wide as 150 nm and could be magnetically guided to specific sites. Its hexagonal tunnels were as long as 180 nm. Upon light stimuli of “on” and “off” states, controllable release was observed with short release time of ~900 s (90% capacity). - Graphical abstract: A core–shell structured site-specific delivery system with a light switch triggered by yellow light was constructed. Controllable release was observed with short release time of ~900 s (90% capacity). - Highlights: • A core–shell structured site-specific delivery system was constructed. • It consisted of Fe{sub 3}O{sub 4} core and MCM-41 shell grafted with light switch. • This delivery system was triggered by low energy light. • Controllable release was observed with short release time of ~900 s.« less

Magnetically separable core–shell ZnFe{sub 2}O{sub 4}@ZnO nanoparticles for visible light photodegradation of methyl orange

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kulkarni, Suresh D., E-mail: suresh.dk@manipal.edu; Kumbar, Sagar; Menon, Samvit G.

Highlights: • Phase pure, magnetic ZnFe{sub 2}O{sub 4}@ZnO nanoparticles synthesized with excellent yield. • ZnFe{sub 2}O{sub 4}@ZnO displayed higher UV photocatalytic efficiency than ZnO nanoparticles. • First report on visible light photodegradation of methyl orange by ZnFe{sub 2}O{sub 4}@ZnO. • Excellent reusability of ZnFe{sub 2}O{sub 4}@ZnO nanoparticles observed for azo dye removal. - Abstract: Visible light photodegradation of aqueous methyl orange using magnetically separable core–shell ZnFe{sub 2}O{sub 4}@ZnO nanoparticles is reported. A combination of low temperature (190 °C) microwave synthesis and hydrothermal method were used to prepare phase pure material with excellent yield (95%). The magnetic separability, surface area ofmore » 41 m{sup 2}/g and visible light absorption make ZnFe{sub 2}O{sub 4}@ZnO nanoparticles a good solar photocatalyst. ZnFe{sub 2}O{sub 4}@ZnO displayed greater UV photocatalytic efficiency than ZnO owing to the generation of large number of electron-hole pairs. Visible light photodegradation of MO using ZnFe{sub 2}O{sub 4}@ZnO nanoparticles is reported for the first time. Higher first order rate constants under both UV and visible light for core-shell nanoparticles suggested their superiority over its individual oxides. The ZnFe{sub 2}O{sub 4}@ZnO showed excellent reusability with high photocatalytic efficiencies suggesting its suitability for solar photocatalytic applications.« less

Modeling of the L-shell copper X-pinch plasma produced by the compact generator of Ecole polytechnique using pattern recognition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Larour, Jean; Aranchuk, Leonid E.; Danisman, Yusuf

2016-03-15

Principal component analysis is applied and compared with the line ratios of special Ne-like transitions for investigating the electron beam effects on the L-shell Cu synthetic spectra. The database for the principal component extraction is created over a non Local Thermodynamic Equilibrium (non-LTE) collisional radiative L-shell Copper model. The extracted principal components are used as a database for Artificial Neural Network in order to estimate the plasma electron temperature, density, and beam fractions from a representative time-integrated spatially resolved L-shell Cu X-pinch plasma spectrum. The spectrum is produced by the explosion of 25-μm Cu wires on a compact LC (40more » kV, 200 kA, and 200 ns) generator. The modeled plasma electron temperatures are about T{sub e} ∼ 150 eV and N{sub e} = 5 × 10{sup 19} cm{sup −3} in the presence of the fraction of the beams with f ∼ 0.05 and a centered energy of ∼10 keV.« less

Off-energy-shell p-p scattering at sub-Coulomb energies via the Trojan horse method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tumino, A.; Dipartimento di Metodologie Fisiche e Chimiche per l'Ingegneria, Universita di Catania, Catania; Universita Kore di Enna, Enna

2008-12-15

Two-proton scattering at sub-Coulomb energies has been measured indirectly via the Trojan horse method applied to the p + d{yields}p + p + n reaction to investigate off-energy shell effects for scattering processes. The three-body experiment was performed at 5 and 4.7 MeV corresponding to a p-p relative energy ranging from 80 to 670 keV. The free p-p cross section exhibits a deep minimum right within this relative energy region due to Coulomb plus nuclear destructive interference. No minimum occurs instead in the Trojan horse p-p cross section, which was extracted by employing a simple plane-wave impulse approximation. A detailedmore » formalism was developed to build up the expression of the theoretical half-off-shell p-p cross section. Its behavior agrees with the Trojan horse data and in turn formally fits the n-n, n-p, and nuclear p-p cross sections given the fact that in its expression the Coulomb amplitude is negligible with respect to the nuclear one. These results confirm the Trojan horse suppression of the Coulomb amplitude for scattering due to the off-shell character of the process.« less

Deciphering the Origin of Plume-Textured Geodes.

ERIC Educational Resources Information Center

Garlick, George Donald; Jones, Francis Tucker

1990-01-01

Presented is an interpretation of the inward and outward growth and formation of plume textured geodes available from southern Brazil. Field occurrence, morphology of vesicles, growth history, closure of the agate shell, microscopic features, coherent reflection of light from convoluted surfaces, and accessory minerals of the inner cavity are…

The bioeconomic impact of different management regulations on the Chesapeake Bay blue crab fishery

USGS Publications Warehouse

Bunnell, David B.; Lipton, Douglas W.; Miller, Thomas J.

2010-01-01

The harvest of blue crabs Callinectes sapidus in Chesapeake Bay declined 46% between 1993 and 2001 and remained low through 2008. Because the total market value of this fishery has declined by an average of US $ 3.3 million per year since 1993, the commercial fishery has been challenged to maintain profitability. We developed a bioeconomic simulation model of the Chesapeake Bay blue crab fishery to aid managers in determining which regulations will maximize revenues while ensuring a sustainable harvest. We compared 15 different management scenarios, including those implemented by Maryland and Virginia between 2007 and 2009, that sought to reduce female crab harvest and nine others that used seasonal closures, different size regulations, or the elimination of fishing for specific market categories. Six scenarios produced the highest revenues: the 2008 and 2009 Maryland regulations, spring and fall closures for female blue crabs, and 152- and 165-mm maximum size limits for females. Our most important finding was that for each state the 2008 and 2009 scenarios that implemented early closures of the female crab fishery produced higher revenues than the 2007 scenario, in which no early female closures were implemented. We conclude that the use of maximum size limits for female crabs would not be feasible despite their potentially high revenue, given the likelihood that the soft-shell and peeler fisheries cannot be expanded beyond their current capacity and the potentially high mortality rate for culled individuals that are the incorrect size. Our model results support the current use of seasonal closures for females, which permit relatively high exploitation of males and soft-shell and peeler blue crabs (which have high prices) while keeping the female crab harvest sustainable. Further, our bioeconomic model allows for the inclusion of an economic viewpoint along with biological data when target reference points are set by managers.

SiC/Si{sub 3}N{sub 4} nanotubes from peanut shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qadri, S. B.; Rath, B. B.; Gorzkowski, E. P.

2016-06-15

Nanotubes and nanoparticles of SiC and Si{sub 3}N{sub 4} were produced from the thermal treatment of peanut shells in argon and nitrogen atmospheres respectively, at temperatures in excess of 1350°C. Using x-ray diffraction, Raman spectroscopy and transmission electron microscopy analysis, the processed samples in argon atmosphere were shown to consist of 2H and 3C polytypes of SiC nanoparticles and nanotubes. Whereas the samples prepared in nitrogen atmosphere consisted of α-phase of Si{sub 3}N{sub 4}. Nanostructures formed by a single direct reaction provide a sustainable synthesis route for nanostructured SiC and Si{sub 3}N{sub 4}, for potential engineering applications due to theirmore » exceptional mechanical and electro-optic properties.« less

Validation of a Pseudo-Sound Theory for the Pressure-Dilatation in DNS of Compressible Turbulence

NASA Technical Reports Server (NTRS)

Ristorcelli, J. R.; Blaisdell, G. A.

1997-01-01

The results of an asymptotic theory for statistical closures for compressible turbulence are explored and validated with the direct numerical simulation of the isotropic decay and the homogeneous shear. An excellent collapse of the data is seen. The slow portion is found to scale, as predicted by the theory, with the quantity M(sub t)(sup 2) and epsilon(sub s). The rapid portion has an unambiguous scaling with alpha(sup 2)M(sub t)(sup s)epsilon(sub s)[P(sub k)/epsilon - l](Sk/epsilon)(sup 2). Implicit in the scaling is a dependence, as has been noted by others, on the gradient Mach number. A new feature of the effects of compressibility, that of the Kolmogorov scaling coefficient, alpha, is discussed. It is suggested that alpha may contain flow specific physics associated with large scales that might provide further insight into the structural effects of compressibility.

Synthesis, microstructure and magnetic properties of Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} soft magnetic composite core

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Jian, E-mail: snove418562@163.com; Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081; Fan, Xi’an, E-mail: groupfxa@163.com

2015-11-15

Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} soft magnetic composite core have been synthesized via a modified stöber method combined with following high temperature sintering process. Most of conductive Fe{sub 3}Si{sub 0.7}Al{sub 0.3} particles could be uniformly coated by insulating SiO{sub 2} using the modified stöber method. The Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles exhibited good soft magnetic properties with low coercivity and high saturation magnetization. The reaction 4Al+3SiO{sub 2}=2α-Al{sub 2}O{sub 3}+3Si took place during the sintering process. As a result the new Fe{sub 3}Si/Al{sub 2}O{sub 3} composite was formed. The Fe{sub 3}Si/Al{sub 2}O{submore » 3} composite core displayed more excellent soft magnetic properties, better frequency stability at high frequencies, much higher electrical resistivity and lower core loss than the pure Fe{sub 3}Si{sub 0.7}Al{sub 0.3} core. The method of introducing insulating layers surrounding magnetic particles provides a promising route to develop new and high compact soft magnetic materials with good magnetic and electric properties. - Graphical abstract: In Fe{sub 3}Si/Al{sub 2}O{sub 3} composite, Fe{sub 3}Si phases are separated by Al{sub 2}O{sub 3} layers and the eddy currents are confined in Fe{sub 3}Si phases, thus increasing resistivity and reducing core loss. - Highlights: • Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} cores were prepared. • Fe{sub 3}Si{sub 0.7}Al{sub 0.3} particles could be uniformly coated by nano-sized SiO{sub 2} clusters. • Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} cores showed good soft magnetic properties. • Fe{sub 3}Si/Al{sub 2}O{sub 3} had lower core loss and better frequency stability than Fe{sub 3}Si{sub 0.7}Al{sub 0.3} cores.« less

Comparative study of new shell-type, sub-2 micron fully porous and monolith stationary phases, focusing on mass-transfer resistance.

PubMed

Oláh, Erzsébet; Fekete, Szabolcs; Fekete, Jeno; Ganzler, Katalin

2010-06-04

Today sub-2 microm packed columns are very popular to conduct fast chromatographic separations. The mass-transfer resistance depends on the particle size but some practical limits exist not to reach the theoretically expected plate height and mass-transfer resistance. Another approach applies particles with shortened diffusion path to enhance the efficiency of separations. In this study a systematical evaluation of the possibilities of the separations obtained with 5 cm long narrow bore columns packed with new 2.6 microm shell particles (1.9 microm nonporous core surrounded by a 0.35 microm porous shell, Kinetex, Core-Shell), packed with other shell-type particles (Ascentis Express, Fused-Core), totally porous sub-2 microm particles and a 5 cm long narrow bore monolith column is presented. The different commercially available columns were compared by using van Deemter, Knox and kinetic plots. Theoretical Poppe plots were constructed for each column to compare their kinetic performance. Data are presented on polar neutral real-life analytes. Comparison of a low molecular weight compounds (MW=270-430) and a high molecular weight one (MW approximately 900) was conducted. This study proves that the Kinetex column packed with 2.6 microm shell particles is worthy of rivaling to sub-2 microm columns and other commercially available shell-type packings (Ascentis Express or Halo), both for small and large molecule separation. The Kinetex column offers a very flat C term. Utilizing this feature, high flow rates can be applied to accomplish very fast separations without significant loss in efficiency. Copyright 2010 Elsevier B.V. All rights reserved.

Transcatheter closure of post-operative residual ventricular septal defect using a patent ductus arteriosus closure device in an adult: a case report.

PubMed

Djer, Mulyadi M; Idris, Nikmah S; Alwi, Idrus; Wijaya, Ika P

2014-07-01

Transcatheter closure of perimembranous and muscular ventricular septal defect (VSD) has been performed widely and it has more advantages compare to surgery. However, transcatheter closure of residual VSD post operation of complex congenital heart disease is still challenging because of the complexity of anatomy and concern about device stability, so the operator should meticulously choose the most appropriate technique and device. We would like to report a case of transcatheter closure of residual VSD post Rastelli operation in a patient with double outlet right ventricle (DORV), sub-aortic VSD, severe infundibulum pulmonary stenosis (PS) and single coronary artery. The patient had undergone operations for four times, but he still had intractable heart failure that did not response to medications. On the first attempt. we closed the VSD using a VSD occluder, unfortunately the device embolized into the descending aorta, but fortunately we was able to snare it out. Then we decided to close the VSD using a patent ductus arteriosus (PDA occluder). On transesophageal echocardiography (TEE) and angiography evaluation, the device position was stable. Post transcatheter VSD closure, the patient clinical condition improved significantly and he could finally be discharged after a long post-surgery hospitalization. Based on this experience we concluded that the transcatheter closure of residual VSD in complex CHD using PDA occluder could be an effective alternative treatment.

Closure of fatigue cracks at high strains

NASA Technical Reports Server (NTRS)

Iyyer, N. S.; Dowling, N. E.

1985-01-01

Experiments were conducted on smooth specimens to study the closure behavior of short cracks at high cyclic strains under completely reversed cycling. Testing procedures and methodology, and closure measurement techniques, are described in detail. The strain levels chosen for the study cover from predominantly elastic to grossly plastic strains. Crack closure measurements are made at different crack lengths. The study reveals that, at high strains, cracks close only as the lowest stress level in the cycle is approached. The crack opening is observed to occur in the compressive part of the loading cycle. The applied stress needed to open a short crack under high strain is found to be less than for cracks under small scale yielding. For increased plastic deformations, the value of sigma sub op/sigma sub max is observed to decrease and approaches the value of R. Comparison of the experimental results with existing analysis is made and indicates the limitations of the small scale yielding approach where gross plastic deformation behavior occurs.

Constrained optimization framework for interface-aware sub-scale dynamics models for voids closure in Lagrangian hydrodynamics

DOE PAGES

Barlow, Andrew; Klima, Matej; Shashkov, Mikhail

2018-04-02

In hydrocodes, voids are used to represent vacuum and model free boundaries between vacuum and real materials. We give a systematic description of a new treatment of void closure in the framework of the multimaterial arbitrary Lagrangian–Eulerian (ALE) methods. This includes a new formulation of the interface-aware sub-scale-dynamics (IA-SSD) closure model for multimaterial cells with voids, which is used in the Lagrangian stage of our indirect ALE scheme. The results of the comprehensive testing of the new model are presented for one- and two-dimensional multimaterial calculations in the presence of voids. Finally, we also present a sneak peek of amore » realistic shaped charge calculation in the presence of voids and solids.« less

Constrained optimization framework for interface-aware sub-scale dynamics models for voids closure in Lagrangian hydrodynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barlow, Andrew; Klima, Matej; Shashkov, Mikhail

In hydrocodes, voids are used to represent vacuum and model free boundaries between vacuum and real materials. We give a systematic description of a new treatment of void closure in the framework of the multimaterial arbitrary Lagrangian–Eulerian (ALE) methods. This includes a new formulation of the interface-aware sub-scale-dynamics (IA-SSD) closure model for multimaterial cells with voids, which is used in the Lagrangian stage of our indirect ALE scheme. The results of the comprehensive testing of the new model are presented for one- and two-dimensional multimaterial calculations in the presence of voids. Finally, we also present a sneak peek of amore » realistic shaped charge calculation in the presence of voids and solids.« less

Surface characterization of ZnO/ZnMn{sub 2}O{sub 4} and Cu/Mn{sub 3}O{sub 4} powders obtained by thermal degradation of heterobimetallic complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barrault, Joeel, E-mail: joel.barrault@univ-poitiers.fr; Makhankova, Valeriya G., E-mail: leram@univ.kiev.ua; Khavryuchenko, Oleksiy V.

2012-03-15

From the selective transformation of the heterometallic (Zn-Mn or Cu-Mn) carboxylate complexes with 2,2 Prime -bipyridyl by thermal degradation at relatively low (350 Degree-Sign C) temperature, it was possible to get either well defined spinel ZnMn{sub 2}O{sub 4} over zinc oxide or well dispersed copper particles surrounded by a manganese oxide (Mn{sub 3}O{sub 4}) in a core-shell like structure. Morphology of the powder surface was examined by scanning electron microscopy with energy dispersive X-ray microanalysis (SEM/EDX). Surface composition was determined by X-ray photoelectron spectroscopy (XPS). Specific surface of the powders by nitrogen adsorption was found to be 33{+-}0.2 and 9{+-}0.06more » m{sup 2} g{sup -1} for Zn-Mn and Cu-Mn samples, respectively, which is comparable to those of commercial products. - Graphical abstract: From the selective transformation of heterometallic (Zn-Mn or Cu-Mn) carboxylate complexes, it was possible to get either well defined spinel ZnMn{sub 2}O{sub 4} over zinc oxide or well dispersed copper particles surrounded by a manganese oxide (Mn{sub 3}O{sub 4}) in a core-shell like structure. Highlights: Black-Right-Pointing-Pointer Thermal degradation of heterometallic complexes results in fine disperse particles. Black-Right-Pointing-Pointer Core-shell Cu/Mn{sub 3}O{sub 4} particles are obtained. Black-Right-Pointing-Pointer ZnMn{sub 2}O{sub 4} spinel layer covers ZnO particles.« less

Stretched proton-neutron configurations in fp-shell nuclei (II). Systematics

NASA Astrophysics Data System (ADS)

von Neumann-Cosel, P.; Fister, U.; Jahn, R.; Schenk, P.; Trelle, T. K.; Wenzel, D.; Wienands, U.

1994-03-01

The systematics of the binding energies of stretched proton-neutron configurations ( f{7}/{2}, g{9}/{2}) 8 -, ( p{3}/{2}, g{9}/{2}) 6 -, ( g{9}/{2}, p{3}/{2}) 6- and ( g{9}/{2}) 29 + are studied over a wide range of f p-shell nuclei. The effective proton-neutron interaction energies deduced from the data are nearly constant for ( p{3}/{2}, g{9}/{2}) 6 -and ( g{9}/{2}) 29 + states while the ( f{7}/{2}, g{9}/{2}) 8 - configuration reveals an additional repulsive term proportional to the partial filling of the f{7}/{2} orbit in the target ground state. Two-body matrix elements are extracted. A crude shell model, which predicts that the excitation energy of a stretched state is equal to the sum of the single-particle energies, works well for the 6 - and 9 + states, but fails for the 8 - levels due to neglect of the additional interactions described above. The physics underlying the empirically introduced basic assumptions of the crude shell model is discussed. The binding energies are found to be linearly dependent on the mass number A and the isospin Tz component and are well described by the weak-coupling model of Bansal and French. The derived parameters agree with averaged values of a similar analysis for the single-particle states in the corresponding odd-even neighbours. The data indicate a significant change of the particle-hole energies with closure of the proton f{7}/{2} shell.

Laminated Thin Shell Structures Subjected to Free Vibration in a Hygrothermal Environment

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Guptill, James D.

1994-01-01

Parametric studies were performed to assess the effects of various parameters on the free-vibration behavior (natural frequencies) of (+/- theta)(sub 2) angle-ply, fiber composite, thin shell structures in a hygrothermal environment. Knowledge of the natural frequencies of structures is important in considering their response to various kinds of excitation, especially when structures and force systems are complex and when excitations are not periodic. The three dimensional, finite element structural analysis computer code CSTEM was used in the Cray YMP computer environment. The fiber composite shell was assumed to be cylindrical and made from T300 graphite fibers embedded in an intermediate-modulus, high-strength matrix. The following parameters were investigated: the length and the laminate thickness of the shell, the fiber orientation, the fiber volume fraction, the temperature profile through the thickness of the laminate, and laminates with different ply thicknesses. The results indicate that the fiber orientation and the length of the laminated shell had significant effects on the natural frequencies. The fiber volume fraction, the laminate thickness, and the temperature profile through the shell thickness had weak effects on the natural frequencies. Finally, the laminates with different ply thicknesses had an insignificant influence on the behavior of the vibrated laminated shell. Also, a single through-the-thickness, eight-node, three dimensional composite finite element analysis appears to be sufficient for investigating the free-vibration behavior of thin, composite, angle-ply shell structures.

In-beam γ -ray spectroscopy of the neutron-rich platinum isotope 200Pt toward the N =126 shell gap

NASA Astrophysics Data System (ADS)

John, P. R.; Valiente-Dobón, J. J.; Mengoni, D.; Modamio, V.; Lunardi, S.; Bazzacco, D.; Gadea, A.; Wheldon, C.; Rodríguez, T. R.; Alexander, T.; de Angelis, G.; Ashwood, N.; Barr, M.; Benzoni, G.; Birkenbach, B.; Bizzeti, P. G.; Bizzeti-Sona, A. M.; Bottoni, S.; Bowry, M.; Bracco, A.; Browne, F.; Bunce, M.; Camera, F.; Corradi, L.; Crespi, F. C. L.; Melon, B.; Farnea, E.; Fioretto, E.; Gottardo, A.; Grente, L.; Hess, H.; Kokalova, Tz.; Korten, W.; Kuşoǧlu, A.; Lenzi, S.; Leoni, S.; Ljungvall, J.; Menegazzo, R.; Michelagnoli, C.; Mijatović, T.; Montagnoli, G.; Montanari, D.; Napoli, D. R.; Podolyák, Zs.; Pollarolo, G.; Recchia, F.; Reiter, P.; Roberts, O. J.; Şahin, E.; Salsac, M.-D.; Scarlassara, F.; Sferrazza, M.; Söderström, P.-A.; Stefanini, A. M.; Szilner, S.; Ur, C. A.; Vogt, A.; Walshe, J.

2017-06-01

The neutron-rich nucleus 200Pt is investigated via in-beam γ -ray spectroscopy to study the shape evolution in the neutron-rich platinum isotopes towards the N =126 shell closure. The two-neutron transfer reaction 198Pt(82Se, 80Se)200Pt is used to populate excited states of 200Pt. The Advanced Gamma Ray Tracking Array (AGATA) demonstrator coupled with the PRISMA spectrometer detects γ rays coincident with the 80Se recoils, the binary partner of 200Pt. The binary partner method is applied to extract the γ -ray transitions and build the level scheme of 200Pt. The level at 1884 keV reported by Yates et al. [S. W. Yates, E. M. Baum, E. A. Henry, L. G. Mann, N. Roy, A. Aprahamian, R. A. Meyer, and R. Estep, Phys. Rev. C 37, 1889 (1988)] was confirmed to be at 1882.1 keV and assigned as the (61+) state. An additional γ ray was found and it presumably deexcites the (81+) state. The results are compared with state-of-the-art beyond mean-field calculations, performed for the even-even 190 -204Pt isotopes, revealing that 200Pt marks the transition from the γ -unstable behavior of lighter Pt nuclei towards a more spherical one when approaching the N =126 shell closure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Orce, J. N.; McKay, C. J.; Lesher, S. R.

A careful determination of the lifetime and measurement of the branching ratio for decay of the first 2{sub T=1}{sup +} state in 42Sc has allowed an accurate experimental test of charge independence in the A = 42 isobaric triplet. A lifetime of 69(17) fs was measured at the University of Kentucky, while relative intensities for the 975 keV and 1586 keV transitions depopulating the first 2{sub T=1}{sup +} state have been determined at the University of Cologne as 100(1) and 8(1), respectively. Both measurements give an isoscalar matrix element, M0, of 6.4(9) (W.u.)1/2. This result confirms charge independence for themore » A=42 isobaric triplet. Shell model calculations have been carried out for understanding the global trend of M0 values for A = 4n + 2 isobaric triplets ranging from A = 18 to A = 42. The 2{sub 1(T=1)}{sup +} {yields} 0{sub 1(T=1)}{sup +} transition energies, reduced transition probabilities and M0 values are reproduced to a high degree of accuracy. The trend of M0 strength along the sd shell is interpreted in terms of the shell structure. Certain discrepancies arise at the extremes of the sd shell, for the A = 18 and A 38 isobaric triplets, which might be explained in terms of the low valence space at the extremes of the sd shell.« less

THE SPATIAL DISTRIBUTION OF COMPLEX ORGANIC MOLECULES IN THE L1544 PRE-STELLAR CORE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiménez-Serra, Izaskun; Vasyunin, Anton I.; Caselli, Paola

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T < 10 K) has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modeling on COM chemistry at low temperatures has provided new insight into these processes predicting that COM formation depends strongly on parameters such as visual extinction and the level of CO freeze out. We report deep observations of COMs toward two positions in the L1544 pre-stellar core: the dense, highly extinguished continuum peak with A{sub V}≥ 30 mag within the inner 2700 au; and a low-densitymore » shell with average A{sub V}∼ 7.5–8 mag located at 4000 au from the core’s center and bright in CH{sub 3}OH. Our observations show that CH{sub 3}O, CH{sub 3}OCH{sub 3}, and CH{sub 3}CHO are more abundant (by factors of ∼2–10) toward the low-density shell than toward the continuum peak. Other COMs such as CH{sub 3}OCHO, c-C{sub 3}H{sub 2}O, HCCCHO, CH{sub 2}CHCN, and HCCNC show slight enhancements (by factors ≤3), but the associated uncertainties are large. This suggests that COMs are actively formed and already present in the low-density shells of pre-stellar cores. The modeling of the chemistry of O-bearing COMs in L1544 indicates that these species are enhanced in this shell because (i) CO starts freezing out onto dust grains driving an active surface chemistry; (ii) the visual extinction is sufficiently high to prevent the UV photo-dissociation of COMs by the external interstellar radiation field; and (iii) the density is still moderate to prevent severe depletion of COMs onto grains.« less

Tuning the tetrahedrality of the hydrogen-bonded network of water: Comparison of the effects of pressure and added salts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prasad, Saurav, E-mail: saurav7188@gmail.com, E-mail: cyz118212@chemistry.iitd.ac.in; Chakravarty, Charusita

Experiments and simulations demonstrate some intriguing equivalences in the effect of pressure and electrolytes on the hydrogen-bonded network of water. Here, we examine the extent and nature of equivalence effects between pressure and salt concentration using relationships between structure, entropy, and transport properties based on two key ideas: first, the approximation of the excess entropy of the fluid by the contribution due to the atom-atom pair correlation functions and second, Rosenfeld-type excess entropy scaling relations for transport properties. We perform molecular dynamics simulations of LiCl–H{sub 2}O and bulk SPC/E water spanning the concentration range 0.025–0.300 molefraction of LiCl at 1more » atm and pressure range from 0 to 7 GPa, respectively. The temperature range considered was from 225 to 350 K for both the systems. To establish that the time-temperature-transformation behaviour of electrolyte solutions and water is equivalent, we use the additional observation based on our simulations that the pair entropy behaves as a near-linear function of pressure in bulk water and of composition in LiCl–H{sub 2}O. This allows for the alignment of pair entropy isotherms and allows for a simple mapping of pressure onto composition. Rosenfeld-scaling implies that pair entropy is semiquantitatively related to the transport properties. At a given temperature, equivalent state points in bulk H{sub 2}O and LiCl–H{sub 2}O (at 1 atm) are defined as those for which the pair entropy, diffusivity, and viscosity are nearly identical. The microscopic basis for this equivalence lies in the ability of both pressure and ions to convert the liquid phase into a pair-dominated fluid, as demonstrated by the O–O–O angular distribution within the first coordination shell of a water molecule. There are, however, sharp differences in local order and mechanisms for the breakdown of tetrahedral order by pressure and electrolytes. Increasing pressure increases orientational disorder within the first neighbour shell while addition of ions shifts local orientational order from tetrahedral to close-packed as water molecules get incorporated in ionic hydration shells. The variations in local order within the first hydration shell may underlie ion-specific effects, such as the Hofmeister series.« less

Three Dimensional Constraint Effects on the Estimated (Delta)CTOD during the Numerical Simulation of Different Fatigue Threshold Testing Techniques

NASA Technical Reports Server (NTRS)

Seshadri, Banavara R.; Smith, Stephen W.

2007-01-01

Variation in constraint through the thickness of a specimen effects the cyclic crack-tip-opening displacement (DELTA CTOD). DELTA CTOD is a valuable measure of crack growth behavior, indicating closure development, constraint variations and load history effects. Fatigue loading with a continual load reduction was used to simulate the load history associated with fatigue crack growth threshold measurements. The constraint effect on the estimated DELTA CTOD is studied by carrying out three-dimensional elastic-plastic finite element simulations. The analysis involves numerical simulation of different standard fatigue threshold test schemes to determine how each test scheme affects DELTA CTOD. The American Society for Testing and Materials (ASTM) prescribes standard load reduction procedures for threshold testing using either the constant stress ratio (R) or constant maximum stress intensity (K(sub max)) methods. Different specimen types defined in the standard, namely the compact tension, C(T), and middle cracked tension, M(T), specimens were used in this simulation. The threshold simulations were conducted with different initial K(sub max) values to study its effect on estimated DELTA CTOD. During each simulation, the DELTA CTOD was estimated at every load increment during the load reduction procedure. Previous numerical simulation results indicate that the constant R load reduction method generates a plastic wake resulting in remote crack closure during unloading. Upon reloading, this remote contact location was observed to remain in contact well after the crack tip was fully open. The final region to open is located at the point at which the load reduction was initiated and at the free surface of the specimen. However, simulations carried out using the constant Kmax load reduction procedure did not indicate remote crack closure. Previous analysis results using various starting K(sub max) values and different load reduction rates have indicated DELTA CTOD is independent of specimen size. A study of the effect of specimen thickness and geometry on the measured DELTA CTOD for various load reduction procedures and its implication in the estimation of fatigue crack growth threshold values is discussed.

Inner-shell excitation and ionic fragmentation of molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hitchcock, A.P.; Tyliszczak, T.; Cavell, R.G.

1997-04-01

Inner-shell excitation and associated decay spectroscopies are site specific probes of electronic and geometrical structure and photoionization dynamics. X-ray absorption probes the geometric and electronic structure, while time-of-flight mass spectrometry with multi-coincidence detection provides information on the photofragmentation dynamics of the initially produced inner-shell state. Auger decay of inner-shell excited and ionised states is an efficient source of multiply charged ions. The charge separation and fragmentation of these species, studied by photoelectron-photoion-photoion coincidence (also called charge separation mass spectrometry) gives insights into bonding and electronic structure. In molecules, the dependence of the fragmentation process on the X-ray energy can revealmore » cases of site and/or state selective fragmentation. At the ALS the authors have examined the soft X-ray spectroscopy and ionic fragmentation of a number of molecules, including carboranes, silylenes, phosphorus halides, SF{sub 6} and CO{sub 2}. Their work is illustrated using results from the carborane and PF{sub 3} studies.« less

Facile Synthesis of Carbon Nanosphere/NiCo2O4 Core-shell Sub-microspheres for High Performance Supercapacitor

PubMed Central

Li, Delong; Gong, Youning; Zhang, Yupeng; Luo, Chengzhi; Li, Weiping; Fu, Qiang; Pan, Chunxu

2015-01-01

This paper introduced a process to prepare the carbon nanosphere (CNS)/NiCo2O4 core-shell sub-microspheres. That is: 1) CNSs were firstly prepared via a simple hydrothermal method; 2) a layer of NiCo2O4 precursor was coated on the CNS surface; 3) finally the composite was annealed at 350 °C for 2 hours in the air, and the CNS/NiCo2O4 core-shell sub-microspheres were obtained. This core-shell sub-microsphere was prepared with a simple, economical and environmental-friendly hydrothermal method, and was suitable for large-scale production, which expects a promising electrode candidate for high performance energy storage applications. Electrochemical experiments revealed that the composite exhibited remarkable electrochemical performances with high capacitance and desirable cycle life at high rates, such as: 1) the maximum specific capacitance was up to 1420 F/g at 1 A/g; 2) about 98.5% of the capacitance retained after 3000 charge-discharge cycles; 3) the capacitance retention was about 72% as the current density increase from 1 A/g to 10 A/g. PMID:26245982

Exchange bias effect and glassy-like behavior of EuCrO{sub 3} and CeCrO{sub 3} nano-powders

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taheri, M., E-mail: maryam.taheri@brocku.ca; Razavi, F. S.; Kremer, R. K.

2015-09-28

The magnetic properties of nano-sized EuCrO{sub 3} and CeCrO{sub 3} powders, synthesized by a solution combustion method, were investigated using DC/AC magnetization measurements. An exchange bias effect, magnetization irreversibility and AC susceptibility dispersion in these samples provided evidence for the presence of the spin disorder magnetic phase. The exchange bias phenomenon, which is assigned to the exchange coupling between the glassy-like shell and canted antiferromagnetic core, showed the opposite sign in EuCrO{sub 3} and CeCrO{sub 3} at low temperatures, suggesting different exchange interactions at the interfaces in these compounds. We also observed a sign reversal of exchange bias in CeCrO{submore » 3} at different temperatures.« less

The Effect of Levetiracetam on Closure of the Midline in Early Chicken Embryos.

PubMed

Ozgural, Onur; Armagan, Ercan; Bozkurt, Melih; Eroglu, Umit; Kahilogullari, Gokmen; Unlu, Agahan

2015-01-01

Genetic predisposition and some environmental factors play an important role in the development of neural tube defects. Levetiracetam is a new drug that has been approved in the treatment of partial seizures. We aimed in this study to determine the effect of levetiracetam on chick embryos. One hundred and sixty fertile non-pathogenic Super Nick eggs were incubated for 24 hours and were divided into four groups of 40 eggs each. Levetiracetam was administered via the sub-blastodermic route. The eggs were incubated for another 24 hours. All eggs were opened at the 48th hour, and the embryos were evaluated morphologically and histopathologically. The effects of levetiracetam on the embryo were correlated with the dose of levetiracetam. In the light of the results, it was determined that the use of increasing doses of levetiracetam led to defects of midline closure in early chicken embryos. Levetiracetam, a new antiepileptic drug that is effective especially on calcium ion concentration, leads to defects in midline closure in embryos in a dose-dependent manner. Further studies are needed to show the mechanism of embryonic damage and the mechanisms of its teratogenous effects associated with genetic and environmental factors.

Proton configurations and pairing correlations at the N=80 superdeformed shell closure: Study of 145Tb

NASA Astrophysics Data System (ADS)

Mullins, S. M.; Schmeing, N. C.; Flibotte, S.; Hackman, G.; Rodriguez, J. L.; Waddington, J. C.; Yao, L.; Andrews, H. R.; Galindo-Uribarri, A.; Janzen, V. P.; Radford, D. C.; Ward, D.; Degraaf, J.; Drake, T. E.; Pilotte, S.; Paul, E. S.

1994-11-01

A superdeformed band has been observed in the N=80 nucleus 145Tb which was produced with the reactions 112Sn(37Cl,2p2n) and 118Sn(31P,4n) at bombarding energies of 187 and 160 MeV, respectively. Since superdeformed bands also exist in the three lighter N=80 isotones 142Sm, 143Eu, and 144Gd, it is now possible to understand the valence-proton configurations of these bands in a systematic way. The T(2) dynamic moment of inertia in 145Tb shows no evidence for the N = 6 quasiproton crossing that is observed in 144Gd. Comparison with cranked Woods-Saxon and total Routhian surface calculations suggests that the proton configuration in 145Tb is 61⊗[404]29/2+ in which the quasiproton crossing is blocked. Furthermore, like 143Eu and 142Sm, there is no evidence in the T (2) for the N=6 quasineutron crossing predicted by the calculations. This may indicate that static neutron pairing correlations are quenched at the N=80 superdeformed shell closure.

Design and Analysis of Tow-Steered Composite Shells Using Fiber Placement

NASA Technical Reports Server (NTRS)

Wu, K. Chauncey

2008-01-01

In this study, a sub-scale advanced composite shell design is evaluated to determine its potential for use on a future aircraft fuselage. Two composite shells with the same nominal 8-ply [+/-45/+/-Theta](sub s) layup are evaluated, where Theta indicates a tow-steered ply. To build this shell, a fiber placement machine would be used to steer unidirectional prepreg tows as they are placed around the circumference of a 17-inch diameter right circular cylinder. The fiber orientation angle varies continuously from 10 degrees (with respect to the shell axis of revolution) at the crown, to 45 degrees on the side, and back to 10 degrees on the keel. All 24 tows are placed at each point on every fiber path in one structure designated as the shell with overlaps. The resulting pattern of tow overlaps causes the laminate thickness to vary between 8 and 16 plies. The second shell without tow overlaps uses the capability of the fiber placement machine to cut and add tows at any point along the fiber paths to fabricate a shell with a nearly uniform 8-ply laminate thickness. Issues encountered during the design and analysis of these shells are presented and discussed. Static stiffness and buckling loads of shells with tow-steered layups are compared with the performance of a baseline quasi-isotropic shell using both finite element analyses and classical strength of materials theory.

BaTiO3-core Au-shell nanoparticles for photothermal therapy and bimodal imaging.

PubMed

Wang, Yanfei; Barhoumi, Aoune; Tong, Rong; Wang, Weiping; Ji, Tianjiao; Deng, Xiaoran; Li, Lele; Lyon, Sophie A; Reznor, Gally; Zurakowski, David; Kohane, Daniel S

2018-05-01

We report sub-100 nm metal-shell (Au) dielectric-core (BaTiO 3 ) nanoparticles with bimodal imaging abilities and enhanced photothermal effects. The nanoparticles efficiently absorb light in the near infrared range of the spectrum and convert it to heat to ablate tumors. Their BaTiO 3 core, a highly ordered non-centrosymmetric material, can be imaged by second harmonic generation, and their Au shell generates two-photon luminescence. The intrinsic dual imaging capability allows investigating the distribution of the nanoparticles in relation to the tumor vasculature morphology during photothermal ablation. Our design enabled in vivo real-time tracking of the BT-Au-NPs and observation of their thermally-induced effect on tumor vessels. Photothermal therapy induced by plasmonic nanoparticles has emerged as a promising approach to treating cancer. However, the study of the role of intratumoral nanoparticle distribution in mediating tumoricidal activity has been hampered by the lack of suitable imaging techniques. This work describes metal-shell (Au) dielectric-core (BaTiO 3 ) nanoparticles (abbreviated as BT-Au-NP) for photothermal therapy and bimodal imaging. We demonstrated that sub-100 nm BT-Au-NP can efficiently absorb near infrared light and convert it to heat to ablate tumors. The intrinsic dual imaging capability allowed us to investigate the distribution of the nanoparticles in relation to the tumor vasculature morphology during photothermal ablation, enabling in vivo real-time tracking of the BT-Au-NPs and observation of their thermally-induced effect on tumor vessels. Copyright © 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Charge Radii of Neutron Deficient Fe,5352 Produced by Projectile Fragmentation

NASA Astrophysics Data System (ADS)

Minamisono, K.; Rossi, D. M.; Beerwerth, R.; Fritzsche, S.; Garand, D.; Klose, A.; Liu, Y.; Maaß, B.; Mantica, P. F.; Miller, A. J.; Müller, P.; Nazarewicz, W.; Nörtershäuser, W.; Olsen, E.; Pearson, M. R.; Reinhard, P.-G.; Saperstein, E. E.; Sumithrarachchi, C.; Tolokonnikov, S. V.

2016-12-01

Bunched-beam collinear laser spectroscopy is performed on neutron deficient Fe,5352 prepared through in-flight separation followed by a gas stopping. This novel scheme is a major step to reach nuclides far from the stability line in laser spectroscopy. Differential mean-square charge radii δ ⟨r2⟩ of Fe,5352 are determined relative to stable 56Fe as δ ⟨r2⟩56 ,52=-0.034 (13 ) fm2 and δ ⟨r2⟩56 ,53=-0.218 (13 ) fm2 , respectively, from the isotope shift of atomic hyperfine structures. The multiconfiguration Dirac-Fock method is used to calculate atomic factors to deduce δ ⟨r2⟩. The values of δ ⟨r2⟩ exhibit a minimum at the N =28 neutron shell closure. The nuclear density functional theory with Fayans and Skyrme energy density functionals is used to interpret the data. The trend of δ ⟨r2⟩ along the Fe isotopic chain results from an interplay between single-particle shell structure, pairing, and polarization effects and provides important data for understanding the intricate trend in the δ ⟨r2⟩ of closed-shell Ca isotopes.

Loads imposed on intermediate frames of stiffened shells

NASA Technical Reports Server (NTRS)

Kuhn, Paul

1939-01-01

The loads imposed on intermediate frames by the curvature of the longitudinal and by the diagonal-tension effects are treated. A new empirical method is proposed for analyzing diagonal-tension effects. The basic formulas of the pure diagonal-tension theory are used, and the part of the total shear S carried by diagonal tension is assumed to be given the expression S (sub DT) = S (1-tau sub o/tau)(sup n) where tau (sub o) is the critical shear stress, tau the total (nominal shear stress), and n = 3 - sigma/tau where sigma is the stress in the intermediate frame. Numerical examples illustrate all cases treated.

Utilization of wasted cockle shell as a natural coagulant and a neutralizer of polluted water in Bangka Belitung islands, Indonesia

NASA Astrophysics Data System (ADS)

Tiandho, Y.; Aldila, H.; Mustari; Megiyo; Afriani, F.

2018-05-01

Bangka Belitung Islands is the largest tin producer in Indonesia. The high activity of tin mining caused the environmental damage which had an impact on the emergence of clean water crisis in some areas in this province. In this paper, a simple water quality improvement method based on wasted cockle shell was developed. Based on x-ray diffraction analysis it is known that calcination of cockle shell powder at 700°C will decompose the powder into calcium oxide compound. The addition of calcined cockle shell powder into acidic water from Merawang Sub-district will increase the pH of water through the process of forming hydroxide groups in the water. The calcined cockle shell powder can also coagulate pollutants in some polluted water from Koba Sub-district. The coagulation results were analyzed using SEM/EDS.

Spectroscopy of the odd-odd fp-shell nucleus {sup 52}Sc from secondary fragmentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gade, A.; Bazin, D.; Mueller, W.F.

2006-03-15

The odd-odd fp-shell nucleus {sup 52}Sc was investigated using in-beam {gamma}-ray spectroscopy following secondary fragmentation of a {sup 55}V and {sup 57}Cr cocktail beam. Aside from the known {gamma}-ray transition at 674(5) keV, a new decay at E{sub {gamma}}=212(3) keV was observed. It is attributed to the depopulation of a low-lying excited level. This new state is discussed in the framework of shell-model calculations with the GXPF1, GXPF1A, and KB3G effective interactions. These calculations are found to be fairly robust for the low-lying level scheme of {sup 52}Sc irrespective of the choice of the effective interaction. In addition, the frequencymore » of spin values predicted by the shell model is successfully modeled by a spin distribution formulated in a statistical approach with an empirical, energy-independent spin-cutoff parameter.« less

Core–shell interaction and its impact on the optical absorption of pure and doped core-shell CdSe/ZnSe nanoclusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Xinqin; Cui, Yingqi; Zeng, Qun

The structural, electronic, and optical properties of core-shell nanoclusters, (CdSe){sub x}@(CdSe){sub y} and their Zn-substituted complexes of x = 2–4 and y = 16–28, were studied with density functional theory calculations. The substitution was applied in the cores, the shells, and/or the whole clusters. All these clusters are characterized by their core-shell structures in which the core-shell interaction was found different from those in core or in shell, as reflected by their bondlengths, volumes, and binding energies. Moreover, the core and shell combine together to compose a new cluster with electronic and optical properties different from those of separated individuals,more » as reflected by their HOMO-LUMO gaps and optical absorptions. With the substitution of Cd by Zn, the structural, electronic, and optical properties of clusters change regularly. The binding energy increases with Zn content, attributed to the strong Zn–Se bonding. For the same core/shell, the structure with a CdSe shell/core has a narrower gap than that with a ZnSe shell/core. The optical absorption spectra also change accordingly with Zn substitution. The peaks blueshift with increasing Zn concentration, accompanying with shape variations in case large number of Cd atoms are substituted. Our calculations reveal the core-shell interaction and its influence on the electronic and optical properties of the core-shell clusters, suggesting a composition–structure–property relationship for the design of core-shell CdSe and ZnSe nanoclusters.« less

Landscape of α preformation probability for even-even nuclei in medium mass region

NASA Astrophysics Data System (ADS)

Qian, Yibin; Ren, Zhongzhou

2018-03-01

The behavior of α cluster preformation probability, in α decay, is a rich source of the structural information, such as the clustering, pairing, and shell evolution in heavy nuclei. Meanwhile, the experimental α decay data have been very recently compiled in the newest table NUBASE2016. Through a least square fit to the available experimental data of nuclear charge radii plus the neutron skin thickness, we obtain a new set of parameters for the two-parameter Fermi nucleon density distributions in target nuclei. Subsequently, we make use of these refreshed inputs, involved in the density-dependent cluster model, to extract α preformation factor ({P}α ) for a large range of medium α emitters with N < 126 from the newest data table. Besides checking the supposed smooth pattern of P α in the open-shell region, the special attention has been paid to those exotic α-decaying nuclei around the Z = 50 and N = 82 shell closures. Moreover, the correlation between the α preformation factor and the microscopic correction of nuclear mass, corresponding to the effect of shell and pairing plus deformation, is in particular investigated, to pursue the valuable knowledge of the P α pattern over the nuclide chart. The feature of α preformation factor along with the neutron-proton asymmetry is then detected and discussed to some extent.

Ethics and Economics: An Introduction to a Christian Document Now Little Remembered

ERIC Educational Resources Information Center

Doughty, Howard A.

2009-01-01

In the early 1980s, it was not sub-prime mortgages and toxic assets, bank failures and factory closures that crowded the pages of the business section of the daily newspapers. It was something called "stagflation," a noxious combination of inflationary pressures on currency and stagnating levels of production. Still, the effects were…

Neutron Diffraction Studies of the Atomic Vibrations of Bulk and Surface Atoms of Nanocrystalline SiC

NASA Technical Reports Server (NTRS)

Stelmakh, S.; Grzanka, E.; Zhao, Y.; Palosz, W.; Palosz, B.

2004-01-01

Thermal atomic motions of nanocrystalline Sic were characterized by two temperature atomic factors B(sub core), and B(sub shell). With the use of wide angle neutron diffraction data it was shown that at the diffraction vector above 15A(exp -1) the Wilson plots gives directly the temperature factor of the grain interior (B(sub core)). At lower Q values the slope of the Wilson plot provides information on the relative amplitudes of vibrations of the core and shell atoms.

Al{sub 2}O{sub 3} - TiO{sub 2}-A simple sol-gel strategy to the synthesis of low temperature sintered alumina-aluminium titanate composites through a core-shell approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jayasankar, M.; Ananthakumar, S.; Mukundan, P.

A simple sol-gel based core-shell approach for the synthesis of alumina-aluminium titanate composite is reported. Alumina is the core and titania is the shell. The coating of titania has been performed in aqueous medium on alumina particle by means of heterocoagulation of titanyl chloride. Further heat treatment results in low temperature formation of aluminium titanate as well as low temperature sintering of alumina-aluminium titanate composites. The lowering of the reaction temperature can be attributed to the maximisation of the contact surface between the reactants due to the core-shell approach involving nanoparticles. The mechanism of formation of aluminium titanate and themore » observations on densification features in the present process are compared with that of mixture of oxides under identical conditions. The sintered alumina-aluminium titanate composite has an average grain size of 2 {mu}m. - Graphical abstract: The article presents a simple sol-gel process through core-shell approach to the synthesis of low temperature sintered alumina-aluminium titanate. The lowering of the reaction temperature can be attributed to the maximisation of the contact surface between the reactant due to the core-shell approach. This material showed the better microstructure control compared to the standard solid-state mixing route.« less

X-ray relative intensities at incident photon energies across the L{sub i} (i=1–3) absorption edges of elements with 35≤Z≤92

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puri, Sanjiv, E-mail: sanjivpurichd@yahoo.com

The intensity ratios, I{sub Lk}/I{sub Lα1} (k=l,η,α{sub 2},β{sub 1},β{sub 2,15},β{sub 3},β{sub 4},β{sub 5,7},β{sub 6},β{sub 9,10},γ{sub 1,5},γ{sub 6,8},γ{sub 2,3},γ{sub 4}) and I{sub Lj}/I{sub Lα} (j=β,γ), have been evaluated at incident photon energies across the L{sub i} (i=1–3) absorption edge energies of all the elements with 35≤Z≤92. Use is made of what are currently considered to be more reliable theoretical data sets of different physical parameters, namely, the L{sub i} (i=1–3) sub-shell photoionization cross sections based on the relativistic Hartree–Fock–Slater (RHFS) model, the X-ray emission rates based on the Dirac–Fock model, and the fluorescence and Coster–Kronig yields based on the Dirac–Hartree–Slater model.more » In addition, the Lα{sub 1} X-ray production cross sections for different elements at various incident photon energies have been tabulated so as to facilitate the evaluation of production cross sections for different resolved L X-ray components from the tabulated intensity ratios. Further, to assist evaluation of the prominent (L{sub i}−S{sub j}) (S{sub j}=M{sub j}, N{sub j} and i=1–3, j=1–7) resonant Raman scattered (RRS) peak energies for an element at a given incident photon energy (below the L{sub i} sub-shell absorption edge), the neutral-atom electron binding energies based on the relaxed orbital RHFS calculations are also listed so as to enable identification of the RRS peaks, which can overlap with the fluorescent X-ray lines. -- Highlights: •The L X-ray relative intensities and Lα{sub 1} XRP cross sections are evaluated using physical parameters based on the IPA models. •Comparison of the intensity ratios evaluated using the DHS and DF models based photoionization cross sections is presented. •Importance of many body effects including electron exchange effects is highlighted.« less

High-resolution elemental records of Glycymeris glycymeris (Bivalvia) shells from the Iberian upwelling system: Ontogeny and environmental control

NASA Astrophysics Data System (ADS)

Freitas, Pedro; Richardson, Christopher; Chenery, Simon; Butler, Paul; Reynolds, David; Gaspar, Miguel; Scourse, James

2015-04-01

The great potential of bivalve shells as a high-resolution geochemical proxy archive of environmental conditions at the time of growth has been known for several decades. The elemental composition of bivalve shells has been studied with the purpose of reconstructing environmental conditions: e.g. seawater temperature (Sr and Mg), primary productivity (Li, Mn, Mo and Ba), redox conditions (Mn and Mo), terrigenous inputs (Li) and pollution (Cu, Zn, Cd and Pb). However, the interpretation of such records remains extremely challenging and complex, with processes affecting element incorporation in the shell (e.g. crystal fabrics, organic matrix, shell formation mechanisms and physiological processes) and the influence of more than one environmental parameter affecting elemental composition of bivalve shells. Nevertheless, bivalve shells remain an underused source of information on environmental conditions, with the potential to record high-resolution (sub-weekly to annually), multi-centennial time series of geochemical proxy data. The relatively long-lived bivalve (>100 years) Glycymeris glycymeris occurs in coastal shelf seas of Europe and North West Africa and is a valid annually resolved sclerochronological archive for palaeonvironmental reconstructions. The temporal framework provided by absolute annually dated shell material makes Glycymeris glycymeris a valuable, albeit unexplored, resource for investigating sub-annually resolved geochemical proxies. We present a first evaluation on the potential of Ba, P and U, the latter two elements rarely studied in bivalves, in Glycymeris glycymeris shells to record variations in the environmental conditions, respectively primary productivity, dissolved inorganic phosphorus and carbonate ion concentration/pH. High-resolution (31 to 77 samples per year) profiles of elemental/Ca ratios (E/Ca) over four years of growth (2001 to 2004) were obtained by LA-ICP-MS on two shells (13 and 16 years old) live-collected in 2010 at 30 m water depth on the Iberia upwelling system. In both shells, clear E/Ca annual cycles with significant higher-frequency variability (weekly to sub-monthly) were observed over the four years of growth analysed. However, E/Ca ratios and the amplitude of the annual E/Ca cycles were lower in the older shell and showed decreasing trends with age (ontogenetic effects). E/Ca ratios were age-detrended using statistical techniques derived from dendrochronology, resulting in similar and coherent profiles in both shells. It seems unlikely that enough variability in E/Ca ratios will be recorded in the shell after 15 to 20 years of age to allow the retrieval of an environmental signal by age-detrending E/Ca ratios. Detrended P/Ca, Ba/Ca and U/Ca in Glycymeris glycymeris shells showed coherent variations with coeval modelled and instrumental oceanographic series from the Iberia upwelling system that suggest a robust potential as an archive of environmental conditions in the first 15 to 20 years of growth. Nevertheless a robust calibration is required to distinguish between the influences of multiple environmental parameters. This study was financed and conducted in the frame of the Portuguese FCT GLYCY Project (contract PTDC/AAC-CLI/118003/2010).

Analyses of Fatigue Crack Growth and Closure Near Threshold Conditions for Large-Crack Behavior

NASA Technical Reports Server (NTRS)

Newman, J. C., Jr.

1999-01-01

A plasticity-induced crack-closure model was used to study fatigue crack growth and closure in thin 2024-T3 aluminum alloy under constant-R and constant-K(sub max) threshold testing procedures. Two methods of calculating crack-opening stresses were compared. One method was based on a contact-K analyses and the other on crack-opening-displacement (COD) analyses. These methods gave nearly identical results under constant-amplitude loading, but under threshold simulations the contact-K analyses gave lower opening stresses than the contact COD method. Crack-growth predictions tend to support the use of contact-K analyses. Crack-growth simulations showed that remote closure can cause a rapid rise in opening stresses in the near threshold regime for low-constraint and high applied stress levels. Under low applied stress levels and high constraint, a rise in opening stresses was not observed near threshold conditions. But crack-tip-opening displacement (CTOD) were of the order of measured oxide thicknesses in the 2024 alloy under constant-R simulations. In contrast, under constant-K(sub max) testing the CTOD near threshold conditions were an order-of-magnitude larger than measured oxide thicknesses. Residual-plastic deformations under both constant-R and constant-K(sub max) threshold simulations were several times larger than the expected oxide thicknesses. Thus, residual-plastic deformations, in addition to oxide and roughness, play an integral part in threshold development.

Advances in Structural Integrity Analysis Methods for Aging Metallic Airframe Structures with Local Damage

NASA Technical Reports Server (NTRS)

Starnes, James H., Jr.; Newman, James C., Jr.; Harris, Charles E.; Piascik, Robert S.; Young, Richard D.; Rose, Cheryl A.

2003-01-01

Analysis methodologies for predicting fatigue-crack growth from rivet holes in panels subjected to cyclic loads and for predicting the residual strength of aluminum fuselage structures with cracks and subjected to combined internal pressure and mechanical loads are described. The fatigue-crack growth analysis methodology is based on small-crack theory and a plasticity induced crack-closure model, and the effect of a corrosive environment on crack-growth rate is included. The residual strength analysis methodology is based on the critical crack-tip-opening-angle fracture criterion that characterizes the fracture behavior of a material of interest, and a geometric and material nonlinear finite element shell analysis code that performs the structural analysis of the fuselage structure of interest. The methodologies have been verified experimentally for structures ranging from laboratory coupons to full-scale structural components. Analytical and experimental results based on these methodologies are described and compared for laboratory coupons and flat panels, small-scale pressurized shells, and full-scale curved stiffened panels. The residual strength analysis methodology is sufficiently general to include the effects of multiple-site damage on structural behavior.

In vivo carotid artery closure by laser activation of hyaluronan-embedded gold nanorods

NASA Astrophysics Data System (ADS)

Matteini, Paolo; Ratto, Fulvio; Rossi, Francesca; Rossi, Giacomo; Esposito, Giuseppe; Puca, Alfredo; Albanese, Alessio; Maira, Giulio; Pini, Roberto

2010-07-01

We prove the first application of near-infrared-absorbing gold nanorods (GNRs) for in vivo laser closure of a rabbit carotid artery. GNRs are first functionalized with a biopolymeric shell and then embedded in hyaluronan, which gives a stabilized and handy laser-activable formulation. Four rabbits undergo closure of a 3-mm longitudinal incision performed on the carotid artery by means of a 810-nm diode laser in conjunction with the topical application of the GNRs composite. An effective surgery is obtained by using a 40-W/cm2 laser power density. The histological and electron microscopy evaluation after a 30-day follow-up demonstrates complete healing of the treated arteries with full re-endothelization at the site of GNRs application. The absence of microgranuloma formation and/or dystrophic calcification is evidence that no host reaction to nanoparticles interspersed through the vascular tissue occurred. The observation of a reshaping and associated blue shift of the NIR absorption band of GNRs after laser treatment supports the occurrence of a self-terminating process, and thus of additional safety of the minimally invasive laser procedure. This study underlines the feasibility of using GNRs for in vivo laser soldering applications, which represents a step forward toward the introduction of nanotechnology-based therapies in minimally invasive clinical practices.

Non-conductive ferromagnetic carbon-coated (Co, Ni) metal/polystyrene nanocomposites films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takacs, H., E-mail: helene.takacs@gmail.com; LTM-CNRS-UJF, CEA, LETI, Minatec Campus, Grenoble 38054; Viala, B.

2016-03-07

This article reports non-conductive ferromagnetic properties of metal/polymer nanocomposite films intended to be used for RF applications. The nanocomposite arrangement is unique showing a core double-shell structure of metal-carbon-polystyrene: M/C//P{sub 1}/P{sub 2}, where M = Co, Ni is the core material, C = graphene or carbon is the first shell acting as a protective layer against oxidation, P{sub 1} = pyrene-terminated polystyrene is the second shell for electrical insulation, and P{sub 2} = polystyrene is a supporting matrix (// indicates actual grafting). The nanocomposite formulation is briefly described, and the film deposition by spin-coating is detailed. Original spin-curves are reported and analyzed. One key outcome is the achievementmore » of uniform and cohesive films at the wafer scale. Structural properties of films are thoroughly detailed, and weight and volume fractions of M/C are considered. Then, a comprehensive overview of DC magnetic and electrical properties is reported. A discussion follows on the magnetic softness of the nanocomposites vs. that of a single particle (theoretical) and the raw powder (experimental). Finally, unprecedented achievement of high magnetization (∼0.6 T) and ultra-high resistivity (∼10{sup 10 }μΩ cm) is shown. High magnetization comes from the preservation of the existing protective shell C, with no significant degradation on the particle net-moment, and high electrical insulation is ensured by adequate grafting of the secondary shell P{sub 1}. To conclude, the metal/polymer nanocomposites are situated in the landscape of soft ferromagnetic materials for RF applications (i.e., inductors and antennas), by means of two phase-diagrams, where they play a crucial role.« less

Sub-daily growth patterns and environmental recording in the shell of the Chilean coastal gastropod Concholepas concholepas

NASA Astrophysics Data System (ADS)

Guzman, N.; Cuif, J.-P.; Ortlieb, L.

2003-04-01

It is nowadays well established that paleo-oceanographic reconstructions based on variations of the geochemical composition of molluscs shells require a good understanding of many biological and biogeochemical processes affecting the shell formation and of the different kinds of diagenetic effects superimposed to the biominerals. Therefore, the parameters which control the growth modality as well as the ecological behaviour of the organisms become a prerequisite in the study of geochemical variations within carbonate skeletons. Such studies involve a calibration of the relationships between the actual environmental parameters and the registered variations of the elements or isotopes measured within the biominerals. This approach must take into account the size of the measured samples (eventually limited by instrumental techniques) and the variation of the relevant parameters during the time period covered by the sample. In a study aimed to reconstruct ENSO and upwelling impacts from geochemical variations within shells of a coastal gastropod of northern Chile, Concholepas concholepas, we undertook microstructural, mineralogical, biochemical analyses. Preliminary stable isotope analyses made with 0.3 mm standard drills provided δ18O values between 1,0 and 2,5 (/PDB) and Mg/Ca ratios between 2,0 and 5,5 mmol/mol for the calcitic layers of shells that grew in 1998--2000 (temperature range: 15--21^oC). Sr, Ba and Cd measured in the water are in the order of 10 ppm, 4,5 ppb and 0,040 ppb respectively, while the composition of the same elements (with respect to Ca) in the shells amount to mean values of 1,5 mmol/mol, 0,6 μmol/mol and 0,1 μmol/mol. For high resolution calibration studies, to be developed with laser ICP-MS and ionic microprobes, it is necessary to identify with a great (sub-daily) precision the time of formation of the considered fragment of shells that are subsampled. To achieve this requisite, we have grown Concholepas concholepas individuals in a culture tank in which the water temperature was recorded every 30 minutes. The shells were marked with calceine during a few hours every week. The fluorescent growth lines thus allow a determination of the growth history and a precise identification of the shell portions to be analysed. For the considered species, analyses of δ18O, δ13C and trace elements can be envisioned at a sub-daily resolution. Work supported by (PNEDC) Project CONCHAS

Computing aerodynamic sound using advanced statistical turbulence theories

NASA Technical Reports Server (NTRS)

Hecht, A. M.; Teske, M. E.; Bilanin, A. J.

1981-01-01

It is noted that the calculation of turbulence-generated aerodynamic sound requires knowledge of the spatial and temporal variation of Q sub ij (xi sub k, tau), the two-point, two-time turbulent velocity correlations. A technique is presented to obtain an approximate form of these correlations based on closure of the Reynolds stress equations by modeling of higher order terms. The governing equations for Q sub ij are first developed for a general flow. The case of homogeneous, stationary turbulence in a unidirectional constant shear mean flow is then assumed. The required closure form for Q sub ij is selected which is capable of qualitatively reproducing experimentally observed behavior. This form contains separation time dependent scale factors as parameters and depends explicitly on spatial separation. The approximate forms of Q sub ij are used in the differential equations and integral moments are taken over the spatial domain. The velocity correlations are used in the Lighthill theory of aerodynamic sound by assuming normal joint probability.

LA-ICP-MS-derived U-concentrations and microstructural domains within biogenic aragonite of Arctica islandica shell.

PubMed

Helama, Samuli; Heikkilä, Pasi; Rinne, Katja; Nielsen, Jan Kresten; Nielsen, Jesper Kresten

2015-05-01

Understanding of the uranium uptake processes (both in vivo and post-mortem) into the skeletal structures of marine calcifiers is a subject of multi-disciplinary interest. U-concentration changes within the molluscan shell may serve as a paleoceanographic proxy of the pH history. A proxy of this type is needed to track the effects of fossil fuel emissions to ocean acidification. Moreover, attaining reliable U-series dates using shell materials would be a geochronological breakthrough. Picturing the high-resolution changes of U-concentrations in shell profiles is now possible by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Here, we analyzed in situ U-concentration variations in sub-fossilized shells of ocean quahog (Arctica islandica), a commonly studied bivalve species in Quaternary geoscience, using LA-ICP-MS. Microstructural details of the shell profiles were achieved by the scanning electron microscopy (SEM). Comparison of the shell aragonite microstructure with the changes in U-concentration revealed that uranium of possibly secondary origin is concentrated into the porous granular layers of the shell. Our results reinforce the hypothesis that U-concentration variations can be linked with microstructural differences within the shell. A combination of LA-ICP-MS and SEM analyses is recommended as an interesting approach for understanding the U-concentration variations in similar materials.

Many-molecule encapsulation by an icosahedral shell

PubMed Central

Perlmutter, Jason D; Mohajerani, Farzaneh; Hagan, Michael F

2016-01-01

We computationally study how an icosahedral shell assembles around hundreds of molecules. Such a process occurs during the formation of the carboxysome, a bacterial microcompartment that assembles around many copies of the enzymes ribulose 1,5-bisphosphate carboxylase/ oxygenase and carbonic anhydrase to facilitate carbon fixation in cyanobacteria. Our simulations identify two classes of assembly pathways leading to encapsulation of many-molecule cargoes. In one, shell assembly proceeds concomitantly with cargo condensation. In the other, the cargo first forms a dense globule; then, shell proteins assemble around and bud from the condensed cargo complex. Although the model is simplified, the simulations predict intermediates and closure mechanisms not accessible in experiments, and show how assembly can be tuned between these two pathways by modulating protein interactions. In addition to elucidating assembly pathways and critical control parameters for microcompartment assembly, our results may guide the reengineering of viruses as nanoreactors that self-assemble around their reactants. DOI: http://dx.doi.org/10.7554/eLife.14078.001 PMID:27166515

Multifunctional polymer-capped mesoporous silica nanoparticles for pH-responsive targeted drug delivery.

PubMed

Niedermayer, Stefan; Weiss, Veronika; Herrmann, Annika; Schmidt, Alexandra; Datz, Stefan; Müller, Katharina; Wagner, Ernst; Bein, Thomas; Bräuchle, Christoph

2015-05-07

A highly stable modular platform, based on the sequential covalent attachment of different functionalities to the surface of core-shell mesoporous silica nanoparticles (MSNs) for targeted drug delivery is presented. A reversible pH-responsive cap system based on covalently attached poly(2-vinylpyridine) (PVP) was developed as drug release mechanism. Our platform offers (i) tuneable interactions and release kinetics with the cargo drug in the mesopores based on chemically orthogonal core-shell design, (ii) an extremely robust and reversible closure and release mechanism based on endosomal acidification of the covalently attached PVP polymer block, (iii) high colloidal stability due to a covalently coupled PEG shell, and (iv) the ability to covalently attach a wide variety of dyes, targeting ligands and other functionalities at the outer periphery of the PEG shell. The functionality of the system was demonstrated in several cell studies, showing pH-triggered release in the endosome, light-triggered endosomal escape with an on-board photosensitizer, and efficient folic acid-based cell targeting.

Coulomb Excitation of n-rich nuclei along the N = 50 shell closure

NASA Astrophysics Data System (ADS)

Padilla-Rodal, E.; Galindo-Uribarri, A.; Batchelder, J. C.; Beene, J. R.; Bingham, C.; Brown, B. A.; Lagergren, K. B.; Mueller, P. E.; Radford, D. C.; Stracener, D. W.; Urrego-Blanco, J. P.; Varner, R. L.; Yu, C.-H.

2008-04-01

Recently, we have been investigating characteristics of nuclear states around the neutron-rich mass A=80 region [1]. Using the Radioactive Ion Beams (RIBs) produced at HRIBF, we have successfully measured the B(E2) values for ^78,80,82Ge , using Coulomb excitation in inverse kinematics. For the germanium isotopes, these data allow a study of the systematic trend between the subshell N= 40 and the N=50 shell. Using the same technique, we have measured the B(E2) value of various nuclei along the N=50 shell including the radioactive nucleus ^84Se. This value together with our previously measured ^82Ge, and the recent result on ^80Zn from ISOLDE [2] are providing basic experimental information needed for a better understanding of the neutron-rich nuclei around A˜80. We report the new results and compare with shell model calculations. [1] E. Padilla-Rodal et al., Phys. Rev. Lett. 94 (2005) 122501. [2] J. Van de Walle et al., Phys. Rev. Lett. 99 (2007) 142501.

New calculations of gross β-decay properties for astrophysical applications: Speeding-up the classical r process

NASA Astrophysics Data System (ADS)

Möller, Peter; Pfeiffer, Bernd; Kratz, Karl-Ludwig

2003-05-01

Recent compilations of experimental gross β-decay properties, i.e., half-lives (T1/2) and neutron-emission probabilities (Pn), are compared to improved global macroscopic-microscopic model predictions. The model combines calculations within the quasiparticle (QP) random-phase approximation for the Gamow-Teller (GT) part with an empirical spreading of the QP strength and the gross theory for the first-forbidden part of β- decay. Nuclear masses are either taken from the 1995 data compilation of Audi et al., when available, otherwise from the finite-range droplet model. Especially for spherical and neutron-(sub-)magic isotopes a considerable improvement compared to our earlier predictions for pure GT decay (ADNDT, 1997) is observed. T1/2 and Pn values up to the neutron drip line have been used in r-process calculations within the classical “waiting-point” approximation. With the new nuclear-physics input, a considerable speeding-up of the r-matter flow is observed, in particular at those r-abundance peaks which are related to magic neutron-shell closures.

Rhythmic patterns in ancient shells: Can we reconstruct sub-annual cyclicity in trace element and stable isotope profiles from rudist bivalves?

NASA Astrophysics Data System (ADS)

de Winter, N.; Sinnesael, M.; Vansteenberge, S.; Goderis, S.; Snoeck, C.; Van Malderen, S. J. M.; Vanhaecke, F. F.; Claeys, P.

2017-12-01

Well-preserved shells of Torreites rudists from the Late Campanian Saiwan Formation in Oman exhibit fine internal layering. These fine (±20 µm) laminae are rhythmically bundled (±400 µm) and subdivide the shells' larger scale annual lamination (±15 mm), suggesting the presence of several interfering cycles in shell growth rate. The aim of the present study is to determine the duration and chemical signature of these rhythmic variations in shell composition. To achieve this, a range of micro-analytical techniques is applied on cross sections through the shells. Firstly, microscopy-based layer counting and colorimetric analysis are carried out on thin sections of shell calcite. Secondly, X-Ray Fluorescence (XRF) and Fourier Transform InfraRed (FTIR) mapping of cross sections of the shells reveal chemical and structural differences between laminae in 2D. Thirdly, high-resolution XRF (25 µm) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS; 10 µm) trace element profiles are used to quantify variations in chemical composition between shell laminae. Fourthly, annual chronology is established based on micro-sampled stable carbon and oxygen stable isotope measurements (250 µm) along the growth axis of the shells. Finally, spectral analysis routines are applied to extract rhythmic patterns matched to the shell laminae from the structural, chemical and colorimetric data. Combining these methods allows for a full evaluation of the structural and chemical characteristics as well as the timing of sub-annual lamination in rudist shells. The results of this study shed light on the external factors that influenced growth rates in rudist bivalves. A better understanding of the timing of deposition of these laminae allows them to be used to improve age models of geochemical records in rudist shells. Characterization of small scale variations in shell composition will characterize the uncertainties contained within lower resolution proxy records from these fossil bivalves. Finally, the study of these laminae enables the reconstruction of sub-annual cyclicity in the environment of Late Cretaceous rudist bivalves. This may in turn shed light on the mechanics of climate in this shallow marine hothouse setting, which provide an analogue of future climate in the light of anthropogenic climate change.

Mantle mixing and thermal evolution during Pangaea assembly and breakup

NASA Astrophysics Data System (ADS)

Rudolph, M. L.; Li, M.; Zhong, S.; Manga, M.

2016-12-01

Continents insulate the underlying mantle, and it has been suggested that the arrangement of the continents can have a significant effect on sub-continental mantle temperatures. Additionally, the dispersal or agglomeration of continents may affect the efficacy of continental insulation, with some studies suggesting warming of 100K beneath supercontinents. During the most recent supercontinent cycle, Pangaea was encircled by subduction, potentially creating a `curtain' of subducted material that may have prevented mixing of the sub-Pangaea mantle with the sub-Panthalassa mantle. Using 3D spherical shell geometry mantle convection simulations, we quantify the effect of insulation by continents and supercontinents. We explore the differences in model predictions for purely thermal vs. thermochemical convection, and we use tracers to quantify the exchange of material between the sub-oceanic to the sub-continental mantle.

Analytic first derivatives for a spin-adapted open-shell coupled cluster theory: Evaluation of first-order electrical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Datta, Dipayan, E-mail: datta@uni-mainz.de; Gauss, Jürgen, E-mail: gauss@uni-mainz.de

2014-09-14

An analytic scheme is presented for the evaluation of first derivatives of the energy for a unitary group based spin-adapted coupled cluster (CC) theory, namely, the combinatoric open-shell CC (COSCC) approach within the singles and doubles approximation. The widely used Lagrange multiplier approach is employed for the derivation of an analytical expression for the first derivative of the energy, which in combination with the well-established density-matrix formulation, is used for the computation of first-order electrical properties. Derivations of the spin-adapted lambda equations for determining the Lagrange multipliers and the expressions for the spin-free effective density matrices for the COSCC approachmore » are presented. Orbital-relaxation effects due to the electric-field perturbation are treated via the Z-vector technique. We present calculations of the dipole moments for a number of doublet radicals in their ground states using restricted open-shell Hartree-Fock (ROHF) and quasi-restricted HF (QRHF) orbitals in order to demonstrate the applicability of our analytic scheme for computing energy derivatives. We also report calculations of the chlorine electric-field gradients and nuclear quadrupole-coupling constants for the CCl, CH{sub 2}Cl, ClO{sub 2}, and SiCl radicals.« less

Direct Polishing of Full-Shell, High-Resolution X-Ray Optics

NASA Technical Reports Server (NTRS)

Roche, Jacqueline M.; Gubarev, Mikhail V.; Smith, W. Scott; O'Dell, Stephen L.; Kolodziejczak, Jeffrey J.; Weisskopf, Martin C.; Ramsey, Brian D.; Elsner, Ronald F.

2014-01-01

Future x-ray telescopes will likely require lightweight mirrors to attain the large collecting areas needed to accomplish the science objectives. Understanding and demonstrating processes now is critical to achieving sub-arcsecond performance in the future. Consequently, designs not only of the mirrors but of fixtures for supporting them during fabrication, metrology, handling, assembly, and testing must be adequately modeled and verified. To this end, MSFC is using finite-element modeling to study the effects of mounting on thin, full-shell grazing-incidence mirrors, during all processes leading to a flight.

Neutral carbon in the Egg Nebula (AFGL 2688)

NASA Technical Reports Server (NTRS)

Beichman, C. A.; Keene, J.; Phillips, T. G.; Huggins, P. J.; Wooten, H. A.; Masson, C.; Frerking, M. A.

1983-01-01

A search for sub-mm C I emission from seven stars that are surrounded by dense molecular gas shells led to the detection, in the case of the "Egg Nebula' (AFGL 2688), of an 0.9 K line implying a C I/CO value greater than 5. The material surrounding this star must be extremely carbon-rich, and it is suggested that the apparently greater extent of the C I emission region may be due to the effects of the galactic UV field on the shell's chemistry, as suggested by Huggins and Glassgold (1982).

Panel Stiffener Debonding Analysis using a Shell/3D Modeling Technique

NASA Technical Reports Server (NTRS)

Krueger, Ronald; Ratcliffe, James G.; Minguet, Pierre J.

2008-01-01

A shear loaded, stringer reinforced composite panel is analyzed to evaluate the fidelity of computational fracture mechanics analyses of complex structures. Shear loading causes the panel to buckle. The resulting out -of-plane deformations initiate skin/stringer separation at the location of an embedded defect. The panel and surrounding load fixture were modeled with shell elements. A small section of the stringer foot, web and noodle as well as the panel skin near the delamination front were modeled with a local 3D solid model. Across the width of the stringer fo to, the mixed-mode strain energy release rates were calculated using the virtual crack closure technique. A failure index was calculated by correlating the results with a mixed-mode failure criterion of the graphite/epoxy material. The objective was to study the effect of the fidelity of the local 3D finite element model on the computed mixed-mode strain energy release rates and the failure index.

Panel-Stiffener Debonding and Analysis Using a Shell/3D Modeling Technique

NASA Technical Reports Server (NTRS)

Krueger, Ronald; Ratcliffe, James G.; Minguet, Pierre J.

2007-01-01

A shear loaded, stringer reinforced composite panel is analyzed to evaluate the fidelity of computational fracture mechanics analyses of complex structures. Shear loading causes the panel to buckle. The resulting out-of-plane deformations initiate skin/stringer separation at the location of an embedded defect. The panel and surrounding load fixture were modeled with shell elements. A small section of the stringer foot, web and noodle as well as the panel skin near the delamination front were modeled with a local 3D solid model. Across the width of the stringer foot, the mixed-mode strain energy release rates were calculated using the virtual crack closure technique. A failure index was calculated by correlating the results with a mixed-mode failure criterion of the graphite/epoxy material. The objective was to study the effect of the fidelity of the local 3D finite element model on the computed mixed-mode strain energy release rates and the failure index.

Systematics of nuclear ground state properties in 78-100Sr by laser spectroscopy

NASA Astrophysics Data System (ADS)

Buchinger, F.; Ramsay, E. B.; Arnold, E.; Neu, W.; Neugart, R.; Wendt, K.; Silverans, R. E.; Lievens, P.; Vermeeren, L.; Berdichevsky, D.; Fleming, R.; Sprung, D. W. L.; Ulm, G.

1990-06-01

Hyperfine structures and isotope shifts of strontium isotopes with A=78 to A=98 and A=100 were measured by collinear fast beam laser spectroscopy. Nuclear spins, moments and changes in mean square charge radii are extracted from the data. The spins and moments of most of the odd isotopes are explained in the framework of the single particle model. The changes in mean square charge radii are compared with predictions of the droplet model and of Hartree-Fock-plus-BCS calculations. For the isotopes in the transitional regions below and above the N=50 shell closure, the inclusion of quadrupole zero point motion in the Droplet model describes part of the observed shell effect. An additional change in the surface region of the charge distribution at spherical shape is suggested by the microscopic model. Furthermore, we propose that the isotopes 78Sr and 80Sr may show an unusual shape-sharing structure, with different mean deformations in the ground and 2+1 excited states.

Chemical changes in carbon Nanotube-Nickel/Nickel Oxide Core/Shell nanoparticle heterostructures treated at high temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chopra, Nitin, E-mail: nchopra@eng.ua.edu; McWhinney, Hylton G.; Shi Wenwu

2011-06-15

Heterostructures composed of carbon nanotube (CNT) coated with Ni/NiO core/shell nanoparticles (denoted as CNC heterostructures) were synthesized in a wet-chemistry and single-step synthesis route involving direct nucleation of nanoparticles on CNT surface. Two different aspects of CNC heterostructures were studied here. First, it was observed that the nanoparticle coatings were more uniform on the as-produced and non-purified CNTs compared to purified (or acid treated) CNTs. These heterostructures were characterized using electron microscopy, Raman spectroscopy, and energy dispersive spectroscopy. Second, thermal stability of CNC heterostructures was studied by annealing them in N{sub 2}-rich (O{sub 2}-lean) environment between 125 and 750 deg.more » C for 1 h. A detailed X-ray photoelectron spectroscopy and Raman spectroscopy analysis was performed to evaluate the effects of annealing temperatures on chemical composition, phases, and stability of the heterostructures. It was observed that the CNTs present in the heterostructures completely decomposed and core Ni nanoparticle oxidized significantly between 600 and 750 deg. C. - Research Highlights: {yields} Heterostructures composed of CNTs coated with Ni/NiO core/shell nanoparticles. {yields} Poor nanoparticle coverage on purified CNT surface compared to non-purified CNTs. {yields} CNTs in heterostructures decompose between 600 and 750 deg. C in N{sub 2}-rich atmosphere. {yields} Metallic species in heterostructures were oxidized at higher temperatures.« less

Biological and climate controls on North Atlantic marine carbon dynamics over the last millennium: Insights from an absolutely-dated shell based record from the North Icelandic Shelf

NASA Astrophysics Data System (ADS)

Hall, I. R.; Reynolds, D.; Scourse, J. D.; Richardson, C.; Wanamaker, A. D.; Butler, P. G.

2017-12-01

Given the rapid increase in atmospheric carbon dioxide concentrations (pCO2) over the industrial era there is a pressing need to construct longterm records of natural carbon cycling prior to this perturbation and to develop a more robust understanding of the role the oceans play in the sequestration of atmospheric carbon. Here we reconstruct the historical biological and climatic controls on the carbon isotopic (δ13C-shell) composition of the North Icelandic shelf waters over the last millennium derived from the shells of the long-lived marine bivalve mollusc Arctica islandica. Variability in the annually resolved δ13C-shell record is dominated by multi-decadal variability with a negative trend (-0.003±0.002‰yr-1) over the industrial era (1800-2000). This trend is consistent with the marine Suess effect brought about by the sequestration of isotopically light carbon (δ13C of CO2) derived from the burning of fossil fuels. Comparison of the δ13C-shell record with contemporary proxy archives, over the last millennium, and instrumental data over the 20th century, suggests that primary productivity and climate conditions over the sub-polar North Atlantic region played a vital role in driving inter-annual to multi-decadal scale variability in the δ13C-shell record. Our results highlight that relative shifts in the proportion of sub-polar mode waters and Arctic intermediate waters entrained onto the North Icelandic shelf, coupled with atmospheric circulation patterns associated with the winter North Atlantic Oscillation (wNAO), are the likely physical mechanisms that drive natural variations in seawater δ13C variability on the North Icelandic shelf.

X-ray fluorescence cross sections for K and L x rays of the elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krause, M.O.; Nestor, C.W. Jr.; Sparks, C.J. Jr.

1978-06-01

X-ray fluorescence cross sections are calculated for the major x rays of the K series 5 less than or equal to Z less than or equal to 101, and the three L series 12 less than or equal to Z less than or equal to 101 in the energy range 1 to 200 keV. This calculation uses Scofield's theoretical partical photoionization cross sections, Krause's evaluation of fluorescence and Coster-Kronig yields, and Scofield's theoretical radiative rates. Values are presented in table and graph format, and an estimate of their accuracy is made. The following x rays are considered: K..cap alpha../sub 1/,more » K..cap alpha../sub 1/,/sub 2/, K..beta../sub 1/, K..beta../sub 1/,/sub 3/, L..cap alpha../sub 1/, L..cap alpha../sub 1/,/sub 2/, L..beta../sub 1/, L..beta../sub 2/,/sub 15/, L..beta../sub 3/, Ll, L..gamma../sub 1/, L..gamma../sub 4/, and L/sub 1/ ..-->.. L/sub 2/,/sub 3/. For use in x-ray fluorescence analysis, K..cap alpha.. and L..cap alpha.. fluorescence cross sections are presented at specific energies: TiK identical with 4.55 keV, CrK identical with 5.46 keV, CoK identical with 7.00 keV, CuK identical with 8.13 keV, MoK..cap alpha.. identical with 17.44 keV, AgK identical with 22.5 keV, DyK identical with 47.0 keV, and /sup 241/Am identical with 59.54 keV. Supplementary material includes fluorescence and Coster--Kronig yields, fractional radiative rates, fractional fluorescence yields, total L-shell fluorescence cross sections, fluorescence and Coster-Kronig yields in condensed matter, effective fluorescence yields, average L-shell fluorescence yield, L-subshell photoionization cross section ratios, and conversion factors from barns per atom to square centimeters per gram.« less

An Investigation of Differential Deposition for Figure Corrections in Full-Shell Grazing-Incidents X-Ray Optics

NASA Technical Reports Server (NTRS)

Gubarev, Mikhail V.; Kilaru, Kirenmayee; Ramsey, Brian D.

2009-01-01

We are investigating differential deposition as a way of correcting small figure errors inside full-shell grazing-incidence x-ray optics. The optics in our study are fabricated using the electroformed-nickel-replication technique, and the figure errors arise from fabrication errors in the mandrel, from which the shells are replicated, as well as errors induced during the electroforming process. Combined, these give sub-micron-scale figure deviations which limit the angular resolution of the optics to approx. 10 arcsec. Sub-micron figure errors can be corrected by selectively depositing (physical vapor deposition) material inside the shell. The requirements for this filler material are that it must not degrade the ultra-smooth surface finish necessary for efficient x-ray reflection (approx. 5 A rms), and must not be highly stressed. In addition, a technique must be found to produce well controlled and defined beams within highly constrained geometries, as some of our mirror shells are less than 3 cm in diameter.

Shell and small particles; evaluation of new column technology.

PubMed

Fekete, Szabolcs; Fekete, Jeno; Ganzler, Katalin

2009-01-15

The performance of 5 cm long columns packed with shell particles was compared to totally porous sub-2 microm particles in gradient and isocratic elution separations of hormones (dienogest, finasteride, gestodene, levonorgestrel, estradiol, ethinylestradiol, noretistherone acetate, bicalutamide and tibolone). Peak capacities around 140-150 could be achieved in 25 min with the 5 cm long columns. The Ascentis Express column (packed with 2.7 microm shell particles) showed similar efficiency to sub-2 microm particles under gradient conditions. Applying isocratic separation, the column of 2.7 microm shell particles had a reduced plate height minimum of approximately h=1.6. It was much smaller than obtained with totally porous particles (h approximately = 2.8). The impedance time also proved more favorable with 2.7 microm shell particles than with totally porous particles. The influence of extra-column volume on column efficiency was investigated. The extra-column dispersion of the chromatographic system may cause a shift of the HETP curves.

DART model for irradiation-induced swelling of dispersion fuel elements including aluminum-fuel interaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rest, J.; Hofman, G.L.

1997-12-01

The Dispersion Analysis Research Tool (DART) contains models for fission-gas-induced fuel swelling, interaction of fuel with the matrix aluminum, for the resultant reaction-product swelling, and for the calculation of the stress gradient within the fuel particle. The effects of an aluminide shell on fuel particle swelling are evaluated. Validation of the model is demonstrated by a comparison of DART calculations of fuel swelling of U{sub 3}SiAl-Al and U{sub 3}Si{sub 2}-Al for various dispersion fuel element designs with the data.

DART model for irradiation-induced swelling of uranium silicide dispersion fuel elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rest, J.; Hofman, G.L.

1999-04-01

Models for the interaction of uranium silicide dispersion fuels with an aluminum matrix, for the resultant reaction product swelling, and for the calculation of the stress gradient within the fuel particles are described within the context of DART fission-gas-induced swelling models. The effects of an aluminide shell on fuel particle swelling are evaluated. Validation of the model is demonstrated by comparing DART calculations with irradiation data for the swelling of U{sub 3}SiAl-Al and U{sub 3}Si{sub 2}-Al in variously designed dispersion fuel elements.

Impact of high pCO2 on shell structure of the bivalve Cerastoderma edule.

PubMed

Milano, Stefania; Schöne, Bernd R; Wang, Schunfeng; Müller, Werner E

2016-08-01

Raised atmospheric emissions of carbon dioxide (CO2) result in an increased ocean pCO2 level and decreased carbonate saturation state. Ocean acidification potentially represents a major threat to calcifying organisms, specifically mollusks. The present study focuses on the impact of elevated pCO2 on shell microstructural and mechanical properties of the bivalve Cerastoderma edule. The mollusks were collected from the Baltic Sea and kept in flow-through systems at six different pCO2 levels from 900 μatm (control) to 24,400 μatm. Extreme pCO2 levels were used to determine the effects of potential leaks from the carbon capture and sequestration sites where CO2 is stored in sub-seabed geological formations. Two approaches were combined to determine the effects of the acidified conditions: (1) Shell microstructures and dissolution damage were analyzed using scanning electron microscopy (SEM) and (2) shell hardness was tested using nanoindentation. Microstructures of specimens reared at different pCO2 levels do not show significant changes in their size and shape. Likewise, the increase of pCO2 does not affect shell hardness. However, dissolution of ontogenetically younger portions of the shell becomes more severe with the increase of pCO2. Irrespective of pCO2, strong negative correlations exist between microstructure size and shell mechanics. An additional sample from the North Sea revealed the same microstructural-mechanical interdependency as the shells from the Baltic Sea. Our findings suggest that the skeletal structure of C. edule is not intensely influenced by pCO2 variations. Furthermore, our study indicates that naturally occurring shell mechanical property depends on the shell architecture at μm-scale. Copyright © 2016 Elsevier Ltd. All rights reserved.

Sphagnum-dwelling testate amoebae in subarctic bogs are more sensitive to soil warming in the growing season than in winter: the results of eight-year field climate manipulations.

PubMed

Tsyganov, Andrey N; Aerts, Rien; Nijs, Ivan; Cornelissen, Johannes H C; Beyens, Louis

2012-05-01

Sphagnum-dwelling testate amoebae are widely used in paleoclimate reconstructions as a proxy for climate-induced changes in bogs. However, the sensitivity of proxies to seasonal climate components is an important issue when interpreting proxy records. Here, we studied the effects of summer warming, winter snow addition solely and winter snow addition together with spring warming on testate amoeba assemblages after eight years of experimental field climate manipulations. All manipulations were accomplished using open top chambers in a dry blanket bog located in the sub-Arctic (Abisko, Sweden). We estimated sensitivity of abundance, diversity and assemblage structure of living and empty shell assemblages of testate amoebae in the living and decaying layers of Sphagnum. Our results show that, in a sub-arctic climate, testate amoebae are more sensitive to climate changes in the growing season than in winter. Summer warming reduced species richness and shifted assemblage composition towards predominance of xerophilous species for the living and empty shell assemblages in both layers. The higher soil temperatures during the growing season also decreased abundance of empty shells in both layers hinting at a possible increase in their decomposition rates. Thus, although possible effects of climate changes on preservation of empty shells should always be taken into account, species diversity and structure of testate amoeba assemblages in dry subarctic bogs are sensitive proxies for climatic changes during the growing season. Copyright © 2011 Elsevier GmbH. All rights reserved.

Inference of turbulence parameters from a ROMS simulation using the k-ε closure scheme

NASA Astrophysics Data System (ADS)

Thyng, Kristen M.; Riley, James J.; Thomson, Jim

2013-12-01

Comparisons between high resolution turbulence data from Admiralty Inlet, WA (USA), and a 65-meter horizontal grid resolution simulation using the hydrostatic ocean modelling code, Regional Ocean Modeling System (ROMS), show that the model's k-ε turbulence closure scheme performs reasonably well. Turbulent dissipation rates and Reynolds stresses agree within a factor of two, on average. Turbulent kinetic energy (TKE) also agrees within a factor of two, but only for motions within the observed inertial sub-range of frequencies (i.e., classic approximately isotropic turbulence). TKE spectra from the observations indicate that there is significant energy at lower frequencies than the inertial sub-range; these scales are not captured by the model closure scheme nor the model grid resolution. To account for scales not present in the model, the inertial sub-range is extrapolated to lower frequencies and then integrated to obtain an inferred, diagnostic total TKE, with improved agreement with the observed total TKE. The realistic behavior of the dissipation rate and Reynolds stress, combined with the adjusted total TKE, imply that ROMS simulations can be used to understand and predict spatial and temporal variations in turbulence. The results are suggested for application to siting tidal current turbines.

Probable alpha and 14C cluster emission from hyper Ac nuclei

NASA Astrophysics Data System (ADS)

Santhosh, K. P.

2013-10-01

A systematic study on the probability for the emission of 4He and 14C cluster from hyper {Λ/207-234}Ac and non-strange normal 207-234Ac nuclei are performed for the first time using our fission model, the Coulomb and proximity potential model (CPPM). The predicted half lives show that hyper {Λ/207-234}Ac nuclei are unstable against 4He emission and 14C emission from hyper {Λ/217-228}Ac are favorable for measurement. Our study also show that hyper {Λ/207-234}Ac are stable against hyper {Λ/4}He and {Λ/14}C emission. The role of neutron shell closure ( N = 126) in hyper {Λ/214}Fr daughter and role of proton/neutron shell closure ( Z ≈ 82, N = 126) in hyper {Λ/210}Bi daughter are also revealed. As hyper-nuclei decays to normal nuclei by mesonic/non-mesonic decay and since most of the predicted half lives for 4He and 14C emission from normal Ac nuclei are favourable for measurement, we presume that alpha and 14C cluster emission from hyper Ac nuclei can be detected in laboratory in a cascade (two-step) process.

Petrology and geochemistry of the orbicular granitoid of Caldera, northern Chile. Models and hypotheses on the formation of radial orbicular textures

NASA Astrophysics Data System (ADS)

Díaz-Alvarado, Juan; Rodríguez, Natalia; Rodríguez, Carmen; Fernández, Carlos; Constanzo, Ítalo

2017-07-01

The orbicular granitoid of Caldera, located at the northern part of the Chilean Coastal Range, is a spectacular example of radial textures in orbicular structures. The orbicular body crops out as a 375 m2 tabular to lensoidal intrusive sheet emplaced in the Lower Jurassic Relincho pluton. The orbicular structures are 3-7 cm in diameter ellipsoids hosted in a porphyritic matrix. The orbicules are comprised by a Qtz-dioritic core (3-5 cm in diameter) composed by Pl + Hbl + Qtz + Bt ± Kfs with equiaxial textures and a gabbroic shell (2-3 cm in diameter) characterized by feathery and radiate textures with a plagioclase + hornblende paragenesis. The radial shell crystals are rooted and orthogonally disposed in the irregular contact with the core. The radial shell, called here inner shell, is in contact with the granodioritic equiaxial interorbicular matrix through a 2-3 mm wide poikilitic band around the orbicule (outer shell). The outer shell and the matrix surrounding the orbicules are characterized by the presence of large hornblende and biotite oikocrystals that include fine-grained rounded plagioclase and magnetite. The oikocrystals of both the outer shell and the matrix have a circumferential arrangement around the orbicule, i.e. orthogonal to the radial inner shell. The coarse-grained granodioritic interorbicular matrix present pegmatitic domains with large acicular hornblende and K-feldspar megacrysts. This work presents a review of the textural characteristics of the orbicules and a complete new mineral and whole-rock geochemical study of the different parts of the orbicular granitoid, together with thermobarometric and crystallographic data, and theoretical modeling of the crystallization and element partitioning processes. We propose a model for the formation of the orbicular radial textures consisting of several processes that are suggested to occur fast and consecutively: superheating, volatile exsolution, undercooling, geochemical fractionation and columnar and equiaxial crystallization. According to the obtained results, the formation of the orbicular granitoid of Caldera may have initiated 1) during the generation of a magmatic fracture in the crystallization front of the Relincho pluton, where the water released by the host crystal mush was dissolved in the new batch of dioritic magma. 2) The high influx of water-rich liquids induced superheating conditions in the newly intruding magma that became a depolymerized liquid, where the only solid particules were the small irregular fragments of the host mush dragged from the fracture walls. 3) Volatile exsolution promoted crystallization under undercooling conditions. 4) Undercooling and nucleation around the core (cold germs) involved the physical and geochemical fractionation between two sub-systems: a gabbroic sub-system that comprises the solid paragénesis with a residual water-rich liquid and a granodioritic sub-system. 5) The orbicules, including core and inner shell, behaved as viscous bodies (crystals + residual liquid) floating in the granodioritic magma. 6) Higher undercooling rates occurred at the starting stage, close to the liquidus, promoting columnar crystallization around the cores and formation of the shells. Conversely, in the granodioritic matrix sub-system, equiaxial crystallization was promoted by low relative crystallization rates. 7) The rest of the crystallization process evolved later in the outer shell and the matrix, as suggested by the poikilitic textures observed in both sides of the orbicule contact, and under conditions close to the solidus of both sub-systems (shell and matrix). The water-rich residual liquid expelled during the orbicular shell crystallization was mingled with the partially crystallized matrix magma, generating the pegmatitic domains with large Kfs megacrysts.

Deep Brain Stimulation Reveals a Dissociation of Consummatory and Motivated Behaviour in the Medial and Lateral Nucleus Accumbens Shell of the Rat

PubMed Central

van der Plasse, Geoffrey; Schrama, Regina; van Seters, Sebastiaan P.; Vanderschuren, Louk J. M. J.

2012-01-01

Following the successful application of deep brain stimulation (DBS) in the treatment of Parkinson's disease and promising results in clinical trials for obsessive compulsive disorder and major depression, DBS is currently being tested in small patient-populations with eating disorders and addiction. However, in spite of its potential use in a broad spectrum of disorders, the mechanisms of action of DBS remain largely unclear and optimal neural targets for stimulation in several disorders have yet to be established. Thus, there is a great need to examine site-specific effects of DBS on a behavioural level and to understand how DBS may modulate pathological behaviour. In view of the possible application of DBS in the treatment of disorders characterized by impaired processing of reward and motivation, like addiction and eating disorders, we examined the effect of DBS of the nucleus accumbens (NAcc) on food-directed behavior. Rats were implanted with bilateral stimulation electrodes in one of three anatomically and functionally distinct sub-areas of the NAcc: the core, lateral shell (lShell) and medial shell (mShell). Subsequently, we studied the effects of DBS on food consumption, and the motivational and appetitive properties of food. The data revealed a functional dissociation between the lShell and mShell. DBS of the lShell reduced motivation to respond for sucrose under a progressive ratio schedule of reinforcement, mShell DBS, however, profoundly and selectively increased the intake of chow. DBS of the NAcc core did not alter any form of food-directed behavior studied. DBS of neither structure affected sucrose preference. These data indicate that the intake of chow and the motivation to work for palatable food can independently be modulated by DBS of subregions of the NAcc shell. As such, these findings provide important leads for the possible future application of DBS as a treatment for eating disorders such as anorexia nervosa. PMID:22428054

Deep brain stimulation reveals a dissociation of consummatory and motivated behaviour in the medial and lateral nucleus accumbens shell of the rat.

PubMed

van der Plasse, Geoffrey; Schrama, Regina; van Seters, Sebastiaan P; Vanderschuren, Louk J M J; Westenberg, Herman G M

2012-01-01

Following the successful application of deep brain stimulation (DBS) in the treatment of Parkinson's disease and promising results in clinical trials for obsessive compulsive disorder and major depression, DBS is currently being tested in small patient-populations with eating disorders and addiction. However, in spite of its potential use in a broad spectrum of disorders, the mechanisms of action of DBS remain largely unclear and optimal neural targets for stimulation in several disorders have yet to be established. Thus, there is a great need to examine site-specific effects of DBS on a behavioural level and to understand how DBS may modulate pathological behaviour. In view of the possible application of DBS in the treatment of disorders characterized by impaired processing of reward and motivation, like addiction and eating disorders, we examined the effect of DBS of the nucleus accumbens (NAcc) on food-directed behavior. Rats were implanted with bilateral stimulation electrodes in one of three anatomically and functionally distinct sub-areas of the NAcc: the core, lateral shell (lShell) and medial shell (mShell). Subsequently, we studied the effects of DBS on food consumption, and the motivational and appetitive properties of food. The data revealed a functional dissociation between the lShell and mShell. DBS of the lShell reduced motivation to respond for sucrose under a progressive ratio schedule of reinforcement, mShell DBS, however, profoundly and selectively increased the intake of chow. DBS of the NAcc core did not alter any form of food-directed behavior studied. DBS of neither structure affected sucrose preference. These data indicate that the intake of chow and the motivation to work for palatable food can independently be modulated by DBS of subregions of the NAcc shell. As such, these findings provide important leads for the possible future application of DBS as a treatment for eating disorders such as anorexia nervosa.

Theoretical X-ray production cross sections at incident photon energies across L{sub i} (i=1-3) absorption edges of Br

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puri, Sanjiv

The X-ray production (XRP) cross sections, σ{sub Lk} (k = l, η, α, β{sub 6}, β{sub 1}, β{sub 3}, β{sub 4}, β{sub 9,10}, γ{sub 1,5}, γ{sub 2,3}) have been evaluated at incident photon energies across the L{sub i}(i=1-3) absorption edge energies of {sub 35}Br using theoretical data sets of different physical parameters, namely, the L{sub i}(i=1-3) sub-shell the X-ray emission rates based on the Dirac-Fock (DF) model, the fluorescence and Coster Kronig yields based on the Dirac-Hartree-Slater (DHS) model, and two sets of the photoionisation cross sections based on the relativistic Hartree-Fock-Slater (RHFS) model and the Dirac-Fock (DF) model, inmore » order to highlight the importance of electron exchange effects at photon energies in vicinity of absorption edge energies.« less

Charge radii of neutron deficient Fe 52 , 53 produced by projectile fragmentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Minamisono, K.; Rossi, D. M.; Beerwerth, R.

Bunched-beam collinear laser spectroscopy is performed on neutron deficient 52,53Fe prepared through in-flight separation followed by a gas stopping. This novel scheme is a major step to reach nuclides far from the stability line in laser spectroscopy. Differential mean-square charge radii δmore » $$\\langle$$r 2$$\\rangle$$ of 52,53Fe are determined relative to stable 56Fe as δ$$\\langle$$r2$$\\rangle$$ 56,52=$-$0.034(13) fm 2 and δ$$\\langle$$r 2$$\\rangle$$56,53=$-$0.218(13) fm 2, respectively, from the isotope shift of atomic hyperfine structures. The multiconfiguration Dirac-Fock method is used to calculate atomic factors to deduce δ$$\\langle$$r 2$$\\rangle$$. The values of δ$$\\langle$$r 2$$\\rangle$$ exhibit a minimum at the N=28 neutron shell closure. The nuclear density functional theory with Fayans and Skyrme energy density functionals is used to interpret the data. As a result, the trend of δ$$\\langle$$r 2$$\\rangle$$ along the Fe isotopic chain results from an interplay between single-particle shell structure, pairing, and polarization effects and provides important data for understanding the intricate trend in the δ$$\\langle$$r 2$$\\rangle$$ of closed-shell Ca isotopes« less

Charge radii of neutron deficient Fe 52 , 53 produced by projectile fragmentation

DOE PAGES

Minamisono, K.; Rossi, D. M.; Beerwerth, R.; ...

2016-12-15

Bunched-beam collinear laser spectroscopy is performed on neutron deficient 52,53Fe prepared through in-flight separation followed by a gas stopping. This novel scheme is a major step to reach nuclides far from the stability line in laser spectroscopy. Differential mean-square charge radii δmore » $$\\langle$$r 2$$\\rangle$$ of 52,53Fe are determined relative to stable 56Fe as δ$$\\langle$$r2$$\\rangle$$ 56,52=$-$0.034(13) fm 2 and δ$$\\langle$$r 2$$\\rangle$$56,53=$-$0.218(13) fm 2, respectively, from the isotope shift of atomic hyperfine structures. The multiconfiguration Dirac-Fock method is used to calculate atomic factors to deduce δ$$\\langle$$r 2$$\\rangle$$. The values of δ$$\\langle$$r 2$$\\rangle$$ exhibit a minimum at the N=28 neutron shell closure. The nuclear density functional theory with Fayans and Skyrme energy density functionals is used to interpret the data. As a result, the trend of δ$$\\langle$$r 2$$\\rangle$$ along the Fe isotopic chain results from an interplay between single-particle shell structure, pairing, and polarization effects and provides important data for understanding the intricate trend in the δ$$\\langle$$r 2$$\\rangle$$ of closed-shell Ca isotopes« less

Fabrication of sub-micrometer-sized jingle bell-shaped hollow spheres from multilayered core-shell particles.

PubMed

Gu, Shunchao; Kondo, Tomohiro; Mine, Eiichi; Nagao, Daisuke; Kobayashi, Yoshio; Konno, Mikio

2004-11-01

Jingle bell-shaped hollow spheres were fabricated starting from multilayered particles composed of a silica core, a polystyrene inner shell, and a titania outer shell. Composite particles of silica core-polystyrene shell, synthesized by coating a 339-nm-sized silica core with a polystyrene shell of thickness 238 nm in emulsion polymerization, were used as core particles for a succeeding titania-coating. A sol-gel method was employed to form the titania outer shell with a thickness of 37 nm. The inner polystyrene shell in the multilayered particles was removed by immersing them in tetrahydrofuran. These successive procedures could produce jingle bell-shaped hollow spheres that contained a silica core in the titania shell.

A test for correction made to spin systematics for coupled band in doubly-odd nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Vinod, E-mail: vinod2.k2@gmail.com

2015-12-15

Systematic Spin Assignments were generally made by using the argument that the energy of levels is a function of neutron number. In the present systematics, the excitation energy of the levels incorporated the effect of nuclear deformation and signature splitting. The nuclear deformation changes toward the mid-shell, therefore a smooth variation in the excitation energy of the levels is observed towards the mid-shell, that intended to make systematics as a function of neutron number towards the mid-shell. Another term “signature splitting” that push the energy of levels for odd- and even-spin sequences up and down, caused the different energy variationmore » pattern for odd- and even-spin sequences. The corrections made in the spin systematics were tested for the known spins of various isotopic chain. In addition, the inconsistency in spin assignments made by the spin systematics and other methods of the configuration πh{sub 11/2} ⊗ νh{sub 11/2} band belonging to {sup 112,114,116}Cs, {sup 126}Pr, and {sup 138}Pr, as an example, was resolved by the correctionmade in the present spin systematics.« less

Evaluation of the Momentum Closure Schemes in MPAS-Ocean

NASA Astrophysics Data System (ADS)

Zhao, Shimei; Liu, Yudi; Liu, Wei

2018-04-01

In order to compare and evaluate the performances of the Laplacian viscosity closure, the biharmonic viscosity closure, and the Leith closure momentum schemes in the MPAS-Ocean model, a variety of physical quantities, such as the relative reference potential energy (RPE) change, the RPE time change rate (RPETCR), the grid Reynolds number, the root mean square (RMS) of kinetic energy, and the spectra of kinetic energy and enstrophy, are calculated on the basis of results of a 3D baroclinic periodic channel. Results indicate that: 1) The RPETCR demonstrates a saturation phenomenon in baroclinic eddy tests. The critical grid Reynolds number corresponding to RPETCR saturation differs between the three closures: the largest value is in the biharmonic viscosity closure, followed by that in the Laplacian viscosity closure, and that in the Leith closure is the smallest. 2) All three closures can effectively suppress spurious dianeutral mixing by reducing the grid Reynolds number under sub-saturation conditions of the RPETCR, but they can also damage certain physical processes. Generally, the damage to the rotation process is greater than that to the advection process. 3) The dissipation in the biharmonic viscosity closure is strongly dependent on scales. Most dissipation concentrates on small scales, and the energy of small-scale eddies is often transferred to large-scale kinetic energy. The viscous dissipation in the Laplacian viscosity closure is the strongest on various scales, followed by that in the Leith closure. Note that part of the small-scale kinetic energy is also transferred to large-scale kinetic energy in the Leith closure. 4) The characteristic length scale L and the dimensionless parameter D in the Leith closure are inherently coupled. The RPETCR is inversely proportional to the product of D and L. When the product of D and L is constant, both the simulated RPETCR and the inhibition of spurious dianeutral mixing are the same in all tests using the Leith closure. The dissipative scale in the Leith closure depends on the parameter L, and the dissipative intensity depends on the parameter D. 5) Although optimal results may not be achieved by using the optimal parameters obtained from the 2D barotropic model in the 3D baroclinic simulation, the total energies are dissipative in all three closures. Dissipation is the strongest in the biharmonic viscosity closure, followed by that in the Leith closure, and that in the Laplacian viscosity closure is the weakest. Mesoscale eddies develop the fastest in the biharmonic viscosity closure after the baroclinic adjustment process finishes, and the kinetic energy reaches its maximum, which is attributed to the smallest dissipation of enstrophy in the biharmonic viscosity closure. Mesoscale eddies develop the slowest, and the kinetic energy peak value is the smallest in the Laplacian viscosity closure. Results in the Leith closure are between that in the biharmonic viscosity closure and the Laplacian viscosity closure.

Tensor force effect on the evolution of single-particle energies in some isotopic chains in the relativistic Hartree-Fock approximation

NASA Astrophysics Data System (ADS)

López-Quelle, M.; Marcos, S.; Niembro, R.; Savushkin, L. N.

2018-03-01

Within a nonlinear relativistic Hartree-Fock approximation combined with the BCS method, we study the effect of the nucleon-nucleon tensor force of the π-exchange potential on the spin- and pseudospin-orbit doublets along the Ca and Sn isotopic chains. We show how the self-consistent tensor force effect modifies the splitting of both kinds of doublets in an interdependent form, leading, quite generally, to opposite effects in the accomplishment of the spin and pseudospin symmetries (the one is restored, the other one deteriorates and vice versa). The ordering of the single-particle energy levels is crucial to this respect. Also, we observe a mutual dependence on the evolution of the shell closure gap Z = 50 and the energy band outside the core, along the Sn chain, as due to the tensor force. In fact, when the shell gap is quenched the outside energy band is enlarged, and vice versa. A reduction of the strength of the pion tensor force with respect to its experimental value from the nucleon-nucleon scattering is needed to get results closer to the experiment. Pairing correlations act to some extent in the opposite direction of the tensor term of the one-pion-exchange force.

Comparison of nonmesonic hypernuclear decay rates computed in laboratory and center-of-mass coordinates

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Conti, C.; Barbero, C.; Galeão, A. P.

In this work we compute the one-nucleon-induced nonmesonic hypernuclear decay rates of {sub Λ}{sup 5}He, {sub Λ}{sup 12}C and {sub Λ}{sup 13}C using a formalism based on the independent particle shell model in terms of laboratory coordinates. To ascertain the correctness and precision of the method, these results are compared with those obtained using a formalism in terms of center-of-mass coordinates, which has been previously reported in the literature. The formalism in terms of laboratory coordinates will be useful in the shell-model approach to two-nucleon-induced transitions.

Fast gradient screening of pharmaceuticals with 5 cm long, narrow bore reversed-phase columns packed with sub-3 μm core-shell and sub-2 μm totally porous particles.

PubMed

Fekete, Szabolcs; Fekete, Jeno

2011-04-15

The performance of 5 cm long narrow-bore columns packed with 2.6-2.7 μm core-shell particles and a column packed with 1.7 μm totally porous particles was compared in very fast gradient separations of polar neutral active pharmaceutical compounds. Peak capacities as a function of flow-rate and gradient time were measured. Peak capacities around 160-170 could be achieved within 25 min with these 5 cm long columns. The highest peak capacity was obtained with the Kinetex column however it was found that as the flow-rate increases, the peak capacity of the new Poroshell-120 column is getting closer to that obtained with the Kinetex column. Considering the column permeability, peak capacity per unit time and per unit pressure was also calculated. In this comparison the advantage of sub-3 μm core-shell particles is more significant compared to sub-2 μm totally porous particles. Moreover it was found that the very similar sized (d(p)=2.7 μm) and structured (ρ=0.63) new Poroshell-120 and the earlier introduced Ascentis Express particles showed different efficiency. Results obtained showed that the 5 cm long narrow bore columns packed with sub-3 μm core-shell particles offer the chance of very fast and efficient gradient separations, thus these columns can be applied for fast screening measurements of routine pharmaceutical analysis such as cleaning validation. Copyright © 2011 Elsevier B.V. All rights reserved.

S{sub 2}SA preconditioning for the S{sub n} equations with strictly non negative spatial discretization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bruss, D. E.; Morel, J. E.; Ragusa, J. C.

2013-07-01

Preconditioners based upon sweeps and diffusion-synthetic acceleration have been constructed and applied to the zeroth and first spatial moments of the 1-D S{sub n} transport equation using a strictly non negative nonlinear spatial closure. Linear and nonlinear preconditioners have been analyzed. The effectiveness of various combinations of these preconditioners are compared. In one dimension, nonlinear sweep preconditioning is shown to be superior to linear sweep preconditioning, and DSA preconditioning using nonlinear sweeps in conjunction with a linear diffusion equation is found to be essentially equivalent to nonlinear sweeps in conjunction with a nonlinear diffusion equation. The ability to use amore » linear diffusion equation has important implications for preconditioning the S{sub n} equations with a strictly non negative spatial discretization in multiple dimensions. (authors)« less

Neutral carbon in the Egg Nebula (AFGL 2688)

NASA Technical Reports Server (NTRS)

Huggins, P. J.; Masson, C.; Frerking, M. A.; Beichman, C. A.; Keene, J.; Phillips, T. G.; Wootten, H. A.

1983-01-01

A search for sub-mm C I emission from seven stars that are surrounded by dense molecular gas shells has led to the detection, in the case of the 'Egg Nebula' (AFGL 2688), of an 0.9 K line implying a C I/CO value greater than 5. The material surrounding this star must be extremely carbon-rich, and it is suggested that the apparently greater extent of the C I emission region may be due to the effects of the the galactic UV field on the shell's chemistry, as suggested by Huggins and Glassgold (1982).

Mounting for Fabrication, Metrology, and Assembly of Full Shell Grazing Incidence Optics

NASA Technical Reports Server (NTRS)

Roche, Jacqueline M.; Gubarev, Mikhail V.; O'Dell, Stephen L.; Kolodziejczak, Jeffery; Weisskopf, Martin C.; Ramsey, Brian D.; Elsner, Ronald F.

2014-01-01

Future x-ray telescopes will likely require lightweight mirrors to attain the large collecting areas needed to accomplish the science objectives. Understanding and demonstrating processes now is critical to achieving sub-arcsecond performance in the future. Consequently, designs not only of the mirrors but of fixtures for supporting them during fabrication, metrology, handling, assembly, and testing must be adequately modeled and verified. To this end, MSFC is using finite-element modeling to study the effects of mounting on full-shell grazing-incidence mirrors, during all processes leading to flight mirror assemblies. Here we report initial results of this study.

Stable isotope ratios in freshwater mussel shells as high resolution recorders of riverine environmental variation

NASA Astrophysics Data System (ADS)

Kukolich, S.; Kendall, C.; Dettman, D. L.

2017-12-01

The geochemical record stored in growth increments of freshwater mussel shells reveals annual to sub-annual changes in environmental conditions during the lifetime of the organism. The carbon, nitrogen, and oxygen stable isotope composition of aragonite shells responds to changes in water chemistry, temperature, streamflow, turbidity, growth rate, size, age, and reproduction. The goals of this study are to determine how stable isotopes can be used to reconstruct the conditions in which the mussels lived and to illuminate any vital effects that might obscure the isotopic record of those conditions. Previous research has suggested that annual δ13C values decrease in older freshwater mussel shells due to lower growth rates and greater incorporation of dietary carbon into the shell with increasing age. However, a high-resolution, seasonal investigation of δ13C, δ15N, and δ18O as they relate to organism age has not yet been attempted in freshwater mussels. A total of 28 Unionid mussels of three different species were collected live in 2011 in the Tennessee River near Paducah, Kentucky, USA. In this study, we analyzed the shell nacre and external organic layers for stable carbon, nitrogen, and oxygen isotope ratios, focusing on growth bands formed between 2006 and 2011. We present a time series of shell δ13C, δ18O, and δ15N values with monthly resolution. We also compare the shell-derived geochemical time series to a time series of the δ13C and δ15N of particulate organic matter, δ13C of DIC, δ18OWater, and water temperature in which the mussels lived. Results show that environmental factors such as water temperature and primary productivity dominate shell chemistry while animal age has little or no effect.

Flower-like NiCo2S4 Hollow Sub-microspheres with Mesoporous Nanoshells Support Pd Nanoparticles for Enhanced Hydrogen Evolution Reaction Electrocatalysis in Both Acidic and Alkaline Conditions.

PubMed

Sheng, Guoqing; Chen, Jiahui; Li, Yunming; Ye, Huangqing; Hu, Zhixiong; Fu, Xian-Zhu; Sun, Rong; Huang, Weixin; Wong, Ching-Ping

2018-06-14

Flower-like NiCo2S4 hollow sub-microspheres are synthesized through Cu2O templates to support Pd nanoparticles as high-efficiency catalysts for HER. The diameter and shells size of NiCo2S4 hollow sub-microspheres are about 400 nm and 16 nm, respectively. In addition, the surface of shells is constructed by petal-like nanosheets. About 3 nm Pd particles uniformly incorporate with the flower-like NiCo2S4 hollow sub-microsphere to form NiCo2S4/Pd heterostructure. The NiCo2S4/Pd catalysts exhibit significantly lower overpotential of only 87 mV and 83 mV at 10 mA/cm2 for HER in both acidic and alkaline conditions, respectively, relative to NiCo2S4 (247 mV, 226 mV) and Pd (175 mV, 385mV) catalysts. Besides, the NiCo2S4/Pd catalysts also exhibit excellent stability of HER in these two conditions. The superior HER performance of NiCo2S4/Pd might be resulted from the unique architecture of metal nanoparticles anchored on the bimetallic sulfides flower-like hollow sub-microspheres which could provide high surface area, lots of active sites, strong synergetic effect and stable structure.

Heating and scattering of ring-beam distributions by turbulence

NASA Technical Reports Server (NTRS)

Gray, P. C.; Pontius, D. H., Jr.; Matthaeus, W. H.

1995-01-01

Pickup ions in the solar wind are initially are born in ring-beam distributions, i.e. f(v) varies as delta(v(sub perpendicular) - V(sub sw)sin(Theta)) delta(v(sub parallel) - V(sub sw)cos(Theta)), where Theta is the angle between the solar wind velocity and the IMF(Interplanetary Magnetic Field), and V(sub sw) is the solar wind speed. Often the distribution has been presumed to relax to a distribution that is isotropic in Theta and essentially mono-energetic, a shell or a 'bi-spherical distribution.' However solar wind turbulence is capable of heating the ring distribution on the timescale of a few tens of gyroperiods, a timescale not greatly distinct from that required for pitch angle scattering to a shell. To describe this effect, we have performed test-particle studies of the heating/scattering of the ring beam distribution by MHD turbulence, adopting various models for the MHD fluctuations, including slab and fully dynamic 2D and 3D incompressible turbulence. Furthermore, a system composed of a cold ion ring and a background plasma is unstable to several kinetic plasma instabilities. We carried out kinetic simulations of the ring beam distribution, showing that plasma instabilities also rapidly energize and scatter particles. Results will be presented comparing relaxation and heating rates of the ring-beam distribution by the various mechanisms.

Analysis of Composite Skin-Stiffener Debond Specimens Using Volume Elements and a Shell/3D Modeling Technique

NASA Technical Reports Server (NTRS)

Krueger, Ronald; Minguet, Pierre J.; Bushnell, Dennis M. (Technical Monitor)

2002-01-01

The debonding of a skin/stringer specimen subjected to tension was studied using three-dimensional volume element modeling and computational fracture mechanics. Mixed mode strain energy release rates were calculated from finite element results using the virtual crack closure technique. The simulations revealed an increase in total energy release rate in the immediate vicinity of the free edges of the specimen. Correlation of the computed mixed-mode strain energy release rates along the delamination front contour with a two-dimensional mixed-mode interlaminar fracture criterion suggested that in spite of peak total energy release rates at the free edge the delamination would not advance at the edges first. The qualitative prediction of the shape of the delamination front was confirmed by X-ray photographs of a specimen taken during testing. The good correlation between prediction based on analysis and experiment demonstrated the efficiency of a mixed-mode failure analysis for the investigation of skin/stiffener separation due to delamination in the adherents. The application of a shell/3D modeling technique for the simulation of skin/stringer debond in a specimen subjected to three-point bending is also demonstrated. The global structure was modeled with shell elements. A local three-dimensional model, extending to about three specimen thicknesses on either side of the delamination front was used to capture the details of the damaged section. Computed total strain energy release rates and mixed-mode ratios obtained from shell/3D simulations were in good agreement with results obtained from full solid models. The good correlations of the results demonstrated the effectiveness of the shell/3D modeling technique for the investigation of skin/stiffener separation due to delamination in the adherents.

Evolution of a superbubble blastwave in a magnetized medium

NASA Technical Reports Server (NTRS)

Ferriere, Katia M.; Zweibel, Ellen G.; Maclow, Mordecai-Mark

1990-01-01

Researchers investigate the effects of interstellar magnetic fields on the evolution and structure of interstellar superbubbles, using both analytic and numerical magnetohydrodynamic (MHD) calculations. These cavities of hot gas, surrounded by shells of cold dense material preceded by a shock wave result from the combined action of stellar winds and supernova explosions in OB associations. If the medium in which a superbubble goes off is homogeneous and unmagnetized, the blast wave expands isotropically. As the interstellar gas flows through the shock, it cools significantly and gets strongly compressed such that thermal pressure remains approximately equal to ram pressure. Hence, the swept up material is confined to a very thin shell. However, if the ambient medium is permeated by a uniform magnetic field B sub o approx. 3 mu G (typical value for the interstellar matter (ISM)), the configuration loses its spherical symmetry, and, due to magnetic pressure, the shell of swept up material does not remain thin. Researchers found the following qualitative differences: (1) Except in the immediate vicinity of the magnetic poles, the shell is supported by magnetic pressure. (2) The refraction of field lines at the shock and the thermal pressure gradient along the shell both contribute to accelerating the gas toward the equator. The resulting mass flux considerably decreases the column density at the magnetic poles. (3) Away from the poles, magnetic tension in the shell causes the field lines (particularly the inner boundary) to elongate in the direction of B sub o. In contrast, the shock wave radius increases with increasing theta. (4) The reduced inertia of a parcel in the polar neighborhood makes it easier to decelerate, and accounts for the dimple which appears at the poles in numerical simulations. This dimple also results from the necessity to call on intermediate shocks in order to insure a smooth transition between a purely thermal shock at the poles and a magnetic shock in the rest of the shell. (5) The shock wave propagates faster than in the absence of magnetic field, except near the poles where the reduced mass of the shell allows it to be more efficiently decelerated.

Communication: Spin densities within a unitary group based spin-adapted open-shell coupled-cluster theory: Analytic evaluation of isotropic hyperfine-coupling constants for the combinatoric open-shell coupled-cluster scheme

DOE Office of Scientific and Technical Information (OSTI.GOV)

Datta, Dipayan, E-mail: datta.dipayan@gmail.com; Gauss, Jürgen, E-mail: gauss@uni-mainz.de

We report analytical calculations of isotropic hyperfine-coupling constants in radicals using a spin-adapted open-shell coupled-cluster theory, namely, the unitary group based combinatoric open-shell coupled-cluster (COSCC) approach within the singles and doubles approximation. A scheme for the evaluation of the one-particle spin-density matrix required in these calculations is outlined within the spin-free formulation of the COSCC approach. In this scheme, the one-particle spin-density matrix for an open-shell state with spin S and M{sub S} = + S is expressed in terms of the one- and two-particle spin-free (charge) density matrices obtained from the Lagrangian formulation that is used for calculating themore » analytic first derivatives of the energy. Benchmark calculations are presented for NO, NCO, CH{sub 2}CN, and two conjugated π-radicals, viz., allyl and 1-pyrrolyl in order to demonstrate the performance of the proposed scheme.« less

Magnetic interaction reversal in watermelon nanostructured Cr-doped Fe nanoclusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaur, Maninder; Qiang, You, E-mail: youqiang@uidaho.edu; Dai, Qilin

2013-11-11

Cr-doped core-shell Fe/Fe-oxide nanoclusters (NCs) were synthesized at varied atomic percentages of Cr from 0 at. % to 8 at. %. The low concentrations of Cr (<10 at. %) were selected in order to inhibit the complete conversion of the Fe-oxide shell to Cr{sub 2}O{sub 3} and the Fe core to FeCr alloy. The magnetic interaction in Fe/Fe-oxide NCs (∼25 nm) can be controlled by antiferromagnetic Cr-dopant. We report the origin of σ-FeCr phase at very low Cr concentration (2 at. %) unlike in previous studies, and the interaction reversal from dipolar to exchange interaction in watermelon-like Cr-doped core-shell NCs.

Synthesis of bimetallic Pt-Pd core-shell nanocrystals and their high electrocatalytic activity modulated by Pd shell thickness

NASA Astrophysics Data System (ADS)

Li, Yujing; Wang, Zhi Wei; Chiu, Chin-Yi; Ruan, Lingyan; Yang, Wenbing; Yang, Yang; Palmer, Richard E.; Huang, Yu

2012-01-01

Bimetallic Pt-Pd core-shell nanocrystals (NCs) are synthesized through a two-step process with controlled Pd thickness from sub-monolayer to multiple atomic layers. The oxygen reduction reaction (ORR) catalytic activity and methanol oxidation reactivity of the core-shell NCs for fuel cell applications in alkaline solution are systematically studied and compared based on different Pd thickness. It is found that the Pd shell helps to reduce the over-potential of ORR by up to 50mV when compared to commercial Pd black, while generating up to 3-fold higher kinetic current density. The carbon monoxide poisoning test shows that the bimetallic NCs are more resistant to the CO poisoning than Pt NCs and Pt black. It is also demonstrated that the bimetallic Pt-Pd core-shell NCs can enhance the current density of the methanol oxidation reaction, lowering the over-potential by 35 mV with respect to the Pt core NCs. Further investigation reveals that the Pd/Pt ratio of 1/3, which corresponds to nearly monolayer Pd deposition on Pt core NCs, gives the highest oxidation current density and lowest over-potential. This study shows for the first time the systematic investigation of effects of Pd atomic shells on Pt-Pd bimetallic nanocatalysts, providing valuable guidelines for designing high-performance catalysts for fuel cell applications.Bimetallic Pt-Pd core-shell nanocrystals (NCs) are synthesized through a two-step process with controlled Pd thickness from sub-monolayer to multiple atomic layers. The oxygen reduction reaction (ORR) catalytic activity and methanol oxidation reactivity of the core-shell NCs for fuel cell applications in alkaline solution are systematically studied and compared based on different Pd thickness. It is found that the Pd shell helps to reduce the over-potential of ORR by up to 50mV when compared to commercial Pd black, while generating up to 3-fold higher kinetic current density. The carbon monoxide poisoning test shows that the bimetallic NCs are more resistant to the CO poisoning than Pt NCs and Pt black. It is also demonstrated that the bimetallic Pt-Pd core-shell NCs can enhance the current density of the methanol oxidation reaction, lowering the over-potential by 35 mV with respect to the Pt core NCs. Further investigation reveals that the Pd/Pt ratio of 1/3, which corresponds to nearly monolayer Pd deposition on Pt core NCs, gives the highest oxidation current density and lowest over-potential. This study shows for the first time the systematic investigation of effects of Pd atomic shells on Pt-Pd bimetallic nanocatalysts, providing valuable guidelines for designing high-performance catalysts for fuel cell applications. Electronic supplementary information (ESI) available: Supplementary TEM, EELS, EDS, Electro-chemical measurement data can be found. See DOI: 10.1039/c1nr11374g

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vyas, S.N.; Patwardhan, S.R.; Vijayalakshmi, S.

Adsorption on carbon molecular sieves (CMS) prepared by coke deposition has become an interesting area of adsorption due to its microporous nature and favorable separation factor on size and shape selectivity basis for many gaseous systems. In the present work CMS was synthesized from coconut shell through three major steps, namely, carbonization, activation, and coke deposition by hydrocarbon cracking. The crushed, washed, and sieved granules of coconut shell (particle size 2--3 mm) were pretreated with sodium silicate solution and oven-dried at 150 C to create the inorganic sites necessary for coke deposition. Carbonization and activation of the dried granules weremore » carried out at 800 C, for 30 min each. The activated char thus produced was subjected to hydrocarbon cracking at 600 C for periods varying from 30 to 180 min. The product samples were characterized in terms of adsorption isotherm, kinetic adsorption curve, surface area, pore volume, pore size distribution, and characteristic energy for adsorption by using O[sub 2], N[sub 2], C[sub 2]H[sub 2], CO[sub 2], C[sub 3]H[sub 6], and CH[sub 4].« less

Modelling the carbon AGB star R Sculptoris. Constraining the dust properties in the detached shell based on far-infrared and sub-millimeter observations

NASA Astrophysics Data System (ADS)

Brunner, M.; Maercker, M.; Mecina, M.; Khouri, T.; Kerschbaum, F.

2018-06-01

Context. On the asymptotic giant branch (AGB), Sun-like stars lose a large portion of their mass in an intensive wind and enrich the surrounding interstellar medium with nuclear processed stellar material in the form of molecular gas and dust. For a number of carbon-rich AGB stars, thin detached shells of gas and dust have been observed. These shells are formed during brief periods of increased mass loss and expansion velocity during a thermal pulse, and open up the possibility to study the mass-loss history of thermally pulsing AGB stars. Aims: We study the properties of dust grains in the detached shell around the carbon AGB star R Scl and aim to quantify the influence of the dust grain properties on the shape of the spectral energy distribution (SED) and the derived dust shell mass. Methods: We modelled the SED of the circumstellar dust emission and compared the models to observations, including new observations of Herschel/PACS and SPIRE (infrared) and APEX/LABOCA (sub-millimeter). We derived present-day mass-loss rates and detached shell masses for a variation of dust grain properties (opacities, chemical composition, grain size, and grain geometry) to quantify the influence of changing dust properties to the derived shell mass. Results: The best-fitting mass-loss parameters are a present-day dust mass-loss rate of 2 × 10-10 M⊙ yr-1 and a detached shell dust mass of (2.9 ± 0.3) × 10-5 M⊙. Compared to similar studies, the uncertainty on the dust mass is reduced by a factor of 4. We find that the size of the grains dominates the shape of the SED, while the estimated dust shell mass is most strongly affected by the geometry of the dust grains. Additionally, we find a significant sub-millimeter excess that cannot be reproduced by any of the models, but is most likely not of thermal origin. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, C.Y.; Paesler, M.A.; Sayers, D.E.

1987-12-15

Extended x-ray-absorption fine-structure measurements have been made on three reversible and reproducible cycles of thermally annealed and light-soaked amorphous As/sub 2/S/sub 3/ films. Associated with the light-soaked material are (1) a very small increase in the population of wrong bonds in the first shell, (2) an enlarged As: S: As bond angle with an expansion of As: As distance in the second shell, (3) a larger spread in the distribution of As: S: As bond angles, and (4) an absence of any change in the third As: S shell. From these data, we present the first quantitative correlation between observedmore » local atomic structural changes and measured macroscopic properties that are associated with photodarkening. Our data demonstrate that the photoinduced structural changes mainly involve bonding alterations at S atoms as well as a change in the dihedral angle relationship between adjacent AsS/sub 3/ pyramids joined at S atoms.« less

DART model for thermal conductivity of U{sub 3}Si{sub 2} aluminum dispersion fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rest, J.; Snelgrove, J.L.; Hofman, G.L.

1995-09-01

This paper describes the primary physical models that form the basis of the DART model for calculating irradiation-induced changes in the thermal conductivity of aluminium dispersion fuel. DART calculations of fuel swelling, pore closure, and thermal conductivity are compared with measured values.

The effects of collision orientation and energy dependence in multinucleon transfer reactions

NASA Astrophysics Data System (ADS)

Li, Jingjing; Li, Cheng; Wen, Peiwei; Zhang, Feng-Shou

2018-05-01

Multinucleon transfer (MNT) reaction 136Xe+208Pb near Coulomb barrier energies are investigated within the dinuclear system (DNS) model. It is found that the collision orientation has an important influence on the mass distributions attributed to the depth of pocket in the driving potential. The calculation results of the isotopic production show that the energy dependence in neutron-deficient side is more sensitive than that in neutron-rich side. The production of the N = 126 isotones are calculated by GRAZING model, DNS+GEMINI model, and ImQMD+GEMINI model, respectively. It demonstrates that MNT reaction is a promising way to produce neutron-rich isotopes in the region of the neutron shell closure N = 126.

Soil calcium availability influences shell ecophenotype formation in the sub-antarctic land snail, Notodiscus hookeri.

PubMed

Charrier, Maryvonne; Marie, Arul; Guillaume, Damien; Bédouet, Laurent; Le Lannic, Joseph; Roiland, Claire; Berland, Sophie; Pierre, Jean-Sébastien; Le Floch, Marie; Frenot, Yves; Lebouvier, Marc

2013-01-01

Ecophenotypes reflect local matches between organisms and their environment, and show plasticity across generations in response to current living conditions. Plastic responses in shell morphology and shell growth have been widely studied in gastropods and are often related to environmental calcium availability, which influences shell biomineralisation. To date, all of these studies have overlooked micro-scale structure of the shell, in addition to how it is related to species responses in the context of environmental pressure. This study is the first to demonstrate that environmental factors induce a bi-modal variation in the shell micro-scale structure of a land gastropod. Notodiscus hookeri is the only native land snail present in the Crozet Archipelago (sub-Antarctic region). The adults have evolved into two ecophenotypes, which are referred to here as MS (mineral shell) and OS (organic shell). The MS-ecophenotype is characterised by a thick mineralised shell. It is primarily distributed along the coastline, and could be associated to the presence of exchangeable calcium in the clay minerals of the soils. The Os-ecophenotype is characterised by a thin organic shell. It is primarily distributed at high altitudes in the mesic and xeric fell-fields in soils with large particles that lack clay and exchangeable calcium. Snails of the Os-ecophenotype are characterised by thinner and larger shell sizes compared to snails of the MS-ecophenotype, indicating a trade-off between mineral thickness and shell size. This pattern increased along a temporal scale; whereby, older adult snails were more clearly separated into two clusters compared to the younger adult snails. The prevalence of glycine-rich proteins in the organic shell layer of N. hookeri, along with the absence of chitin, differs to the organic scaffolds of molluscan biominerals. The present study provides new insights for testing the adaptive value of phenotypic plasticity in response to spatial and temporal environmental variations.

Soil Calcium Availability Influences Shell Ecophenotype Formation in the Sub-Antarctic Land Snail, Notodiscus hookeri

PubMed Central

Charrier, Maryvonne; Marie, Arul; Guillaume, Damien; Bédouet, Laurent; Le Lannic, Joseph; Roiland, Claire; Berland, Sophie; Pierre, Jean-Sébastien; Le Floch, Marie; Frenot, Yves; Lebouvier, Marc

2013-01-01

Ecophenotypes reflect local matches between organisms and their environment, and show plasticity across generations in response to current living conditions. Plastic responses in shell morphology and shell growth have been widely studied in gastropods and are often related to environmental calcium availability, which influences shell biomineralisation. To date, all of these studies have overlooked micro-scale structure of the shell, in addition to how it is related to species responses in the context of environmental pressure. This study is the first to demonstrate that environmental factors induce a bi-modal variation in the shell micro-scale structure of a land gastropod. Notodiscus hookeri is the only native land snail present in the Crozet Archipelago (sub-Antarctic region). The adults have evolved into two ecophenotypes, which are referred to here as MS (mineral shell) and OS (organic shell). The MS-ecophenotype is characterised by a thick mineralised shell. It is primarily distributed along the coastline, and could be associated to the presence of exchangeable calcium in the clay minerals of the soils. The Os-ecophenotype is characterised by a thin organic shell. It is primarily distributed at high altitudes in the mesic and xeric fell-fields in soils with large particles that lack clay and exchangeable calcium. Snails of the Os-ecophenotype are characterised by thinner and larger shell sizes compared to snails of the MS- ecophenotype, indicating a trade-off between mineral thickness and shell size. This pattern increased along a temporal scale; whereby, older adult snails were more clearly separated into two clusters compared to the younger adult snails. The prevalence of glycine-rich proteins in the organic shell layer of N. hookeri, along with the absence of chitin, differs to the organic scaffolds of molluscan biominerals. The present study provides new insights for testing the adaptive value of phenotypic plasticity in response to spatial and temporal environmental variations. PMID:24376821

The effect of canopy closure on chimpanzee nest abundance in Lagoas de Cufada National Park, Guinea-Bissau.

PubMed

Sousa, Joana; Casanova, Catarina; Barata, André V; Sousa, Cláudia

2014-04-01

The present study aimed to gather baseline information about chimpanzee nesting and density in Lagoas de Cufada Natural Park (LCNP), in Guinea-Bissau. Old and narrow trails were followed to estimate chimpanzee density through marked-nest counts and to test the effect of canopy closure (woodland savannah, forest with a sparse canopy, and forest with a dense canopy) on nest distribution. Chimpanzee abundance was estimated at 0.79 nest builders/km(2), the lowest among the areas of Guinea-Bissau with currently studied chimpanzee populations. Our data suggest that sub-humid forest with a dense canopy accounts for significantly higher chimpanzee nest abundance (1.50 nests/km of trail) than sub-humid forest with a sparse canopy (0.49 nests/km of trail) or woodland savannah (0.30 nests/km of trail). Dense-canopy forests play an important role in chimpanzee nesting in the patchy and highly humanized landscape of LCNP. The tree species most frequently used for nesting are Dialium guineense (46%) and Elaeis guineensis (28%). E. guineensis contain nests built higher in the canopy, while D. guineense contain nests built at lower heights. Nests observed during baseline sampling and replications suggest seasonal variations in the tree species used for nest building.

Synthesis and characterization of Pd(0), PdS, and Pd-PdO core-shell nanoparticles by solventless thermolysis of a Pd-thiolate cluster

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jose, Deepa; Jagirdar, Balaji R., E-mail: jagirdar@ipc.iisc.ernet.i

2010-09-15

Colloids of palladium nanoparticles have been prepared by the solvated metal atom dispersion (SMAD) method. The as-prepared Pd colloid consists of particles with an average diameter of 2.8{+-}0.1 nm. Digestive ripening of the as-prepared Pd colloid, a process involving refluxing the as-prepared colloid at or near the boiling point of the solvent in the presence of a passivating agent, dodecanethiol resulted in a previously reported Pd-thiolate cluster, [Pd(SC{sub 12}H{sub 25}){sub 2}]{sub 6} but did not render the expected narrowing down of the particle size distribution. Solventless thermolysis of the Pd-thiolate complex resulted in various Pd systems such as Pd(0), PdS,more » and Pd-PdO core-shell nanoparticles thus demonstrating its versatility. These Pd nanostructures have been characterized using high-resolution electron microscopy and powder X-ray diffraction methods. - Graphical abstract: Solventless thermolysis of a single palladium-thiolate cluster affords various Pd systems such as Pd(0), Pd-PdO core-shell, and PdS nanoparticles demonstrating the versatility of the precursor and the methodology.« less

Atomistic Simulation and Electronic Structure of Lithium Doped Ionic Liquids: Structure, Transport, and Electrochemical Stability

NASA Technical Reports Server (NTRS)

Haskins, Justin B.; Bauschlicher, Charles W.; Lawson, John W.

2015-01-01

Zero-temperature density functional theory (DFT), density functional theory molecular dynamics (DFT-MD), and classical molecular dynamics using polarizable force fields (PFF-MD) are employed to evaluate the influence of Lithium ion on the structure, transport, and electrochemical stability of three potential ionic liquid electrolytes: N--methyl-N-butylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([pyr14][TFSI]), N--methyl-N-propylpyrrolidinium bis(fluorosulfonyl)imide ([pyr13][FSI]), and 1-ethyl-3--methylimidazolium boron tetrafluoride ([EMIM][BF4]). We characterize the Lithium ion solvation shell through zero-temperature DFT simulations of [Li(Anion)sub n](exp n-1) -clusters, DFT-MD simulations of isolated lithium ions in small ionic liquid systems, and PFF-MD simulations with high Li-doping levels in large ionic liquid systems. At low levels of Li-salt doping, highly stable solvation shells having 2-3 anions are seen in both [pyr14][TFSI] and [pyr13][FSI], while solvation shells with 4 anions dominate in [EMIM][BF sub 4]. At higher levels of doping, we find the formation of complex Li-network structures that increase the frequency of 4 anion-coordinated solvation shells. A comparison of computational and experimental Raman spectra for a wide range of [Li(Anion) sub n](exp n -1) - clusters shows that our proposed structures are consistent with experiment. We estimate the ion diffusion coefficients and quantify both size and simulation time effects. We find estimates of lithium ion diffusion are a reasonable order of magnitude and can be corrected for simulation time effects. Simulation size, on the other hand, is also important, with diffusion coefficients from long PFF-MD simulations of small cells having 20-40% error compared to large-cell values. Finally, we compute the electrochemical window using differences in electronic energy levels of both isolated cation/anion pairs and small ionic liquid systems with Li-salt doping. The single pair and liquid-phase systems provide similar estimates of electrochemical window, while Li-doping in the liquid-phase systems results in electrochemical windows little changed from the neat systems. Pure and hybrid functionals systematically provide an upper and lower bound, respectively, to the experimental electrochemical window for the systems studied here.

Correlations of neutron multiplicity and γ -ray multiplicity with fragment mass and total kinetic energy in spontaneous fission of Cf 252

DOE PAGES

Wang, Taofeng; Li, Guangwu; Zhu, Liping; ...

2016-01-08

The dependence of correlations of neutron multiplicity ν and γ-ray multiplicity M γ in spontaneous fission of 252Cf on fragment mass A* and total kinetic energy (TKE) have been investigated by employing the ratio of M γ/ν and the form of M γ(ν). We show for the first time that M γ and ν have a complex correlation for heavy fragment masses, while there is a positive dependence of Mγ for light fragment masses and for near-symmetric mass splits. The ratio M γ/ν exhibits strong shell effects for neutron magic number N=50 and near doubly magic number shell closure atmore » Z=50 and N=82. The γ-ray multiplicity Mγ has a maximum for TKE=165-170 MeV. Above 170 MeV M γ(TKE) is approximately linear, while it deviates significantly from a linear dependence at lower TKE. The correlation between the average neutron and γ-ray multiplicities can be partly reproduced by model calculations.« less

Using HT and DT gamma rays to diagnose mix in Omega capsule implosions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schmitt, M. J.; Herrmann, H. W.; Kim, Y. H.

Experimental evidence [1] indicates that shell material can be driven into the core of Omega capsule implosions on the same time scale as the initial convergent shock. It has been hypothesized that shock-generated temperatures at the fuel/shell interface in thin exploding pusher capsules diffusively drives shell material into the gas core between the time of shock passage and bang time. Here, we propose a method to temporally resolve and observe the evolution of shell material into the capsule core as a function of fuel/shell interface temperature (which can be varied by varying the capsule shell thickness). Our proposed method usesmore » a CD plastic capsule filled with 50/50 HT gas and diagnosed using gas Cherenkov detection (GCD) to temporally resolve both the HT "clean" and DT "mix" gamma ray burn histories. Simulations using Hydra [2] for an Omega CD-lined capsule with a sub-micron layer of the inside surface of the shell pre-mixed into a fraction of the gas region produce gamma reaction history profiles that are sensitive to the depth to which this material is mixed. Furthermore, we observe these differences as a function of capsule shell thickness is proposed to determine if interface mixing is consistent with thermal diffusion λ ii~T 2/Z 2ρ at the gas/shell interface. Finally, since hydrodynamic mixing from shell perturbations, such as the mounting stalk and glue, could complicate these types of capsule-averaged temporal measurements, simulations including their effects also have been performed showing minimal perturbation of the hot spot geometry.« less

In-life pteropod shell dissolution as an indicator of past ocean carbonate saturation

NASA Astrophysics Data System (ADS)

Wall-Palmer, Deborah; Smart, Christopher W.; Hart, Malcolm B.

2013-12-01

Recent concern over the effects of ocean acidification upon calcifying organisms has highlighted the aragonitic shelled thecosomatous pteropods as being at a high risk. Both in-situ and laboratory studies have shown that an increased dissolved CO2 concentration, leading to decreased water pH and low carbonate concentration, causes reduced calcification rates and enhanced dissolution in the shells of living pteropods. In fossil records unaffected by post-depositional dissolution, this in-life shell dissolution can be detected. Here we present the first evidence of variations of in-life pteropod shell dissolution due to variations in surface water carbonate concentration during the Late Pleistocene by analysing the surface layer of pteropod shells in marine sediment cores from the Caribbean Sea and Indian Ocean. In-life shell dissolution was determined by applying the Limacina Dissolution Index (LDX) to the sub-tropical pteropod Limacina inflata. Average shell size information shows that high in-life dissolution is accompanied by smaller shell sizes in L. inflata, which may indicate a reduction in calcification rate. Comparison of the LDX profile to Late Pleistocene Vostok atmospheric CO2 concentrations, shows that in-life pteropod dissolution is closely associated to variations in past ocean carbonate saturation. This study confirms the findings of laboratory studies, showing enhanced shell dissolution and reduced calcification in living pteropods when surface ocean carbonate concentrations were lower. Results also demonstrate that oceanic pH levels that were less acidic and changing less rapidly than those predicted for the 21st Century, negatively affected pteropods during the Late Pleistocene.

Using HT and DT gamma rays to diagnose mix in Omega capsule implosions

DOE PAGES

Schmitt, M. J.; Herrmann, H. W.; Kim, Y. H.; ...

2016-05-26

Experimental evidence [1] indicates that shell material can be driven into the core of Omega capsule implosions on the same time scale as the initial convergent shock. It has been hypothesized that shock-generated temperatures at the fuel/shell interface in thin exploding pusher capsules diffusively drives shell material into the gas core between the time of shock passage and bang time. Here, we propose a method to temporally resolve and observe the evolution of shell material into the capsule core as a function of fuel/shell interface temperature (which can be varied by varying the capsule shell thickness). Our proposed method usesmore » a CD plastic capsule filled with 50/50 HT gas and diagnosed using gas Cherenkov detection (GCD) to temporally resolve both the HT "clean" and DT "mix" gamma ray burn histories. Simulations using Hydra [2] for an Omega CD-lined capsule with a sub-micron layer of the inside surface of the shell pre-mixed into a fraction of the gas region produce gamma reaction history profiles that are sensitive to the depth to which this material is mixed. Furthermore, we observe these differences as a function of capsule shell thickness is proposed to determine if interface mixing is consistent with thermal diffusion λ ii~T 2/Z 2ρ at the gas/shell interface. Finally, since hydrodynamic mixing from shell perturbations, such as the mounting stalk and glue, could complicate these types of capsule-averaged temporal measurements, simulations including their effects also have been performed showing minimal perturbation of the hot spot geometry.« less

Using HT and DT gamma rays to diagnose mix in Omega capsule implosions

NASA Astrophysics Data System (ADS)

Schmitt, M. J.; Herrmann, H. W.; Kim, Y. H.; McEvoy, A. M.; Zylstra, A.; Hammel, B. A.; Sepke, S. M.; Leatherland, A.; Gales, S.

2016-05-01

Experimental evidence [1] indicates that shell material can be driven into the core of Omega capsule implosions on the same time scale as the initial convergent shock. It has been hypothesized that shock-generated temperatures at the fuel/shell interface in thin exploding pusher capsules diffusively drives shell material into the gas core between the time of shock passage and bang time. We propose a method to temporally resolve and observe the evolution of shell material into the capsule core as a function of fuel/shell interface temperature (which can be varied by varying the capsule shell thickness). Our proposed method uses a CD plastic capsule filled with 50/50 HT gas and diagnosed using gas Cherenkov detection (GCD) to temporally resolve both the HT “clean” and DT “mix” gamma ray burn histories. Simulations using Hydra [2] for an Omega CD-lined capsule with a sub-micron layer of the inside surface of the shell pre-mixed into a fraction of the gas region produce gamma reaction history profiles that are sensitive to the depth to which this material is mixed. An experiment to observe these differences as a function of capsule shell thickness is proposed to determine if interface mixing is consistent with thermal diffusion λii∼T2/Z2ρ at the gas/shell interface. Since hydrodynamic mixing from shell perturbations, such as the mounting stalk and glue, could complicate these types of capsule-averaged temporal measurements, simulations including their effects also have been performed showing minimal perturbation of the hot spot geometry.

Synthesis of Highly Active Sub-Nanometer Pt@Rh Core-Shell Nanocatalyst via a Photochemical Route: Porous Titania Nanoplates as a Superior Photoactive Support.

PubMed

Zhan, Wen-Wen; Zhu, Qi-Long; Dang, Song; Liu, Zheng; Kitta, Mitsunori; Suenaga, Kazutomo; Zheng, Lan-Sun; Xu, Qiang

2017-04-01

Sub-nanometer Pt@Rh nanoparticles highly dispersed on MIL-125-derived porous TiO 2 nanoplates are successfully prepared for the first time by a photochemical route, where the porous TiO 2 nanoplates with a relatively high specific surface area play a dual role as both effective photoreductant and catalyst support. The resulting Pt@Rh/p-TiO 2 can be utilized as a highly active catalyst. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nekkab, M., E-mail: mohammed-nekkab@yahoo.com; LESIMS laboratory, Physics Department, Faculty of Sciences, University of Setif 1, 19000 Setif; Kahoul, A.

The analytical methods based on X-ray fluorescence are advantageous for practical applications in a variety of fields including atomic physics, X-ray fluorescence surface chemical analysis and medical research and so the accurate fluorescence yields (ω{sub K}) are required for these applications. In this contribution we report a new parameters for calculation of K-shell fluorescence yields (ω{sub K}) of elements in the range of 11≤Z≤30. The experimental data are interpolated by using the famous analytical function (ω{sub k}/(1−ω{sub k})){sup 1/q} (were q=3, 3.5 and 4) vs Z to deduce the empirical K-shell fluorescence yields. A comparison is made between the resultsmore » of the procedures followed here and those theoretical and other semi-empirical fluorescence yield values. Reasonable agreement was typically obtained between our result and other works.« less

Effect of wave function on the proton induced L XRP cross sections for {sub 62}Sm and {sub 74}W

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shehla,; Kaur, Rajnish; Kumar, Anil

The L{sub k}(k= 1, α, β, γ) X-ray production cross sections have been calculated for {sub 74}W and {sub 62}Sm at different incident proton energies ranging 1-5 MeV using theoretical data sets of different physical parameters, namely, the Li(i=1-3) sub-shell X-ray emission rates based on the Dirac-Fork (DF) model, the fluorescence and Coster Kronig yields based on the Dirac- Hartree-Slater (DHS) model and two sets the proton ionization cross sections based on the DHS model and the ECPSSR in order to assess the influence of the wave function on the XRP cross sections. The calculated cross sections have been compared withmore » the measured cross sections reported in the recent compilation to check the reliability of the calculated values.« less

Making sense of the conflicting magic numbers in WSi{sub n} clusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abreu, Marissa Baddick; Reber, Arthur C.; Khanna, Shiv N.

2015-08-21

First principles studies on the geometric structure, stability, and electronic structure of WSi{sub n} clusters, n = 6-16, have been carried out to show that the observed differing “magic sizes” for WSi{sub n} clusters are associated with the nature of the growth processes. The WSi{sub 12} cluster, observed as a magic species in experiments reacting transition metal ions with silane, is not stable due to a filled shell of 18 electrons, as previously proposed, but due to its atomic structure that arrests further growth because of an endohedral transition metal site. In fact, it is found that all of thesemore » clusters, n = 6-16, have filled 5d shells except for WSi{sub 12}, which has a 5d{sup 8} configuration that is caused by crystal field splitting. The stability of WSi{sub 15}{sup +}, observed as highly stable in clusters generated by vaporizing silicon and metal carbonyls, is shown to be associated with a combination of geometric and electronic features. The findings are compared with previous results on CrSi{sub n} clusters.« less

Neutron knockout from 68,70Ni ground and isomeric states.

NASA Astrophysics Data System (ADS)

Recchia, F.; Weisshaar, D.; Gade, A.; Tostevin, J. A.; Janssens, R. V. F.; Albers, M.; Bader, V. M.; Baugher, T.; Bazin, D.; Berryman, J. S.; Brown, B. A.; Campbell, C. M.; Carpenter, M. P.; Chen, J.; Chiara, C. J.; Crawford, H. L.; Hoffman, C. R.; Kondev, F. G.; Korichi, A.; Langer, C.; Lauritsen, T.; Liddick, S. N.; Lunderberg, E.; Noji, S.; Prokop, C.; Stroberg, S. R.; Suchyta, S.; Wimmer, K.; Zhu, S.

2018-02-01

Neutron-rich isotopes are an important source of new information on nuclear physics. Specifically, the spin-isospin components in the nucleon-nucleon (NN) interaction, e.g., the proton-neutron tensor force, are expected to modify shell structure in exotic nuclei. These potential changes in the intrinsic shell structure are of fundamental interest. The study of the excitation energy of states corresponding to specific configurations in even-even isotopes, together with the single-particle character of the first excited states of odd-A, neutron-rich Ni isotopes, probes the evolution of the neutron orbitals around the Fermi surface as a function of the neutron number a step forward in the understanding of the region and the nature of the NN interaction at large N/Z ratios. In an experiment carried out at the National Superconducting Cyclotron Laboratory [1], new spectroscopic information was obtained for 68Ni and the distribution of single-particle strengths in 67,69Ni was characterized by means of single-neutron knockout from 68,70Ni secondary beams. The spectroscopic strengths, deduced from the measured partial cross sections to the individual states tagged by their de-exciting gamma rays, is used to identify and quantify configurations that involve neutron excitations across the N = 40 harmonic oscillator shell closure. The de-excitation γ rays were measured with the GRETINA tracking array [2]. The results challenge the validity of the most current shell-model Hamiltonians and effective interactions, highlighting shortcomings that cannot yet be explained. These results suggest that our understanding of the low-energy states in such nuclei is not complete and requires further investigation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Derbin, A. V., E-mail: derbin@pnpi.spb.r; Fomenko, K. A., E-mail: fomenko@jinr.r

The Pauli exclusion principle was tested for nucleons in the {sup 12}C nucleus by using data from the Borexino detector. The approach used consisted in seeking photons, neutrons, and protons, as well as electrons and positrons, emitted in the Pauli-forbidden transitions of nucleons from the 1P{sub 3/2} shell to the filled 1S{sub 1/2} shell. Owing to a uniquely low background level in the Borexino detector and its large mass, the currently most stringent experimental limits were obtained for the probabilities and relative intensities of Pauli-forbidden transitions for the electromagnetic, strong, and weak channels.

Evolution of Structure in Nuclei: Meditation by Sub-Shell Modifications and Relation to Binding Energies

NASA Astrophysics Data System (ADS)

Casten, R. F.; Cakirli, R. B.

2009-03-01

Understanding the development of configuration mixing, coherence, collectivity, and deformation in nuclei is one of the crucial challenges in nuclear structure physics, and one which has become all the more important with the advent of next generation facilities for the study of exotic nuclei. We will discuss recent work on phase/shape transitional behavior in nuclei, and the role of changes in sub-shell structure in mediating such transitional regions. We will also discuss a newly found, much deeper, link between nuclear structure and nuclear binding energies.

Properties of coupled-cluster equations originating in excitation sub-algebras

NASA Astrophysics Data System (ADS)

Kowalski, Karol

2018-03-01

In this paper, we discuss properties of single-reference coupled cluster (CC) equations associated with the existence of sub-algebras of excitations that allow one to represent CC equations in a hybrid fashion where the cluster amplitudes associated with these sub-algebras can be obtained by solving the corresponding eigenvalue problem. For closed-shell formulations analyzed in this paper, the hybrid representation of CC equations provides a natural way for extending active-space and seniority number concepts to provide an accurate description of electron correlation effects. Moreover, a new representation can be utilized to re-define iterative algorithms used to solve CC equations, especially for tough cases defined by the presence of strong static and dynamical correlation effects. We will also explore invariance properties associated with excitation sub-algebras to define a new class of CC approximations referred to in this paper as the sub-algebra-flow-based CC methods. We illustrate the performance of these methods on the example of ground- and excited-state calculations for commonly used small benchmark systems.

Structural and functional maturation of rat gastrointestinal barrier with thyroxine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Israel, E.J.; Pang, K.Y.; Harmatz, P.R.

It has been noted that the closure of the intestinal barrier to immunoglobulins is a normal maturational process in the rat. It has also been noted that the microvillus membrane (MVM) of newborn animals differs from adult MVM. The purpose of this study is to document whether thyroid hormone can induce closure in vivo in the rat and to relate this effect of thyroxine to the structural and functional maturation of the intestinal MVM. To assess closure, 2-wk-old rats were fed in rat immunoglobulin G (IgG), and serum antibody binding activity was measured 4 h later. The antibody binding activitymore » of treated animals (T) was 1.5-2 times less than that of controls (C), indicating that thyroxine stimulates closure. The MVM similarly showed signs of maturation. Structural maturation was demonstrated by the lower fluidity of the thyroid-treated animals' membranes. Under the influence of thyroxine, the number of receptors on the MVM for IgG had decreased, while the K/sub a/ remained the same, demonstrating the functional maturation of the MVM. In conclusion, thryoid hormone can induce both structural and functional maturation of the intestinal MVM and can enhance the intestinal mucosal barrier by decreasing the penetration of antibodies.« less

Crystal Structure Studies of Low-Ca Pyroxenes from LL-Group Chondritic Meteorites

NASA Astrophysics Data System (ADS)

Artioli, G.; Davoli, G.; Sighinolfi, G. P.

1993-07-01

One orthorhombic (Pbca) and two monoclinic (P2(sub)1/c) single crystals of low-Ca pyroxenes were extracted from unequilibrated chondritic meteorites of the LL-group. The results of the crystal structure refinements performed using x-ray diffraction data indicate that: (1) the intracrystalline Fe-Mg distribution over the M1 and M2 crystallographic sites of the Parnallee (LL-3) orthoenstatite is consistent with a temperature of 960 degrees C for the closure of the exchange equilibrium process; and (2) the structural state and intracristalline Fe-Mg order in the Soko Banja (LL-4) and Jolomba (LL-6) clinoenstatites indicate a closing temperature of at least 1000-1100 degrees C, with no significant reequilibration at lower temperatures. The present data represent the first detailed crystallographic investigation of pyroxenes from LL-chondrites and support the hypothesis that the chondrule pyroxenes bear a distinct memory of rapid cooling in the solar nebular and that thermal metamorphism in the parent body, if present, was totally unsufficient to allow reequilibration of the pyroxene minerals to the low-temperature ordered crystal structures. The data also indicate that, assuming low or mild pressure and shock effects, there is no well-defined correlation between equilibrium temperature of the mineral phases and the alleged petrologic type of the meteorites. This evidence is consistent with a rubble-pile model for the parent body accretional history, or with an onion-shell model with very low thermal-peak metamorphism, as it is assumed for a very small object.

A Side by Side Comparison of Filter-Based PM(sub 2.5) Measurements at a Suburban Site: A Closure Study

NASA Technical Reports Server (NTRS)

Haines, Jennifer C.; Chen, Lung-Wen A.; Taubman, Brett F.; Doddridge, Bruce G.; Dickerson, Russell R.

2007-01-01

Reliable determination of the effects of air quality on public health and the environment requires accurate measurement of PM(sub 2.5) mass and the individual chemical components of fine aerosols. This study seeks to evaluate PM(sub 2.5) measurements that are part of a newly established national network by comparing them with a more conventional sampling system. Experiments were carried out during 2002 at a suburban site in Maryland, United States, where two samplers from the U.S. Environmental Protection Agency (USEPA) Speciation Trends Network: Met One Speciation Air Sampling System STNS and Thermo Scientific Reference Ambient Air Sampler STNR, two Desert Research Institute Sequential Filter Samplers DRIF, and a continuous TEOM monitor (Thermo Scientific Tapered Element Oscillating Microbalance) were sampling air in parallel. These monitors differ not only in sampling configuration but also in protocol-specific sample analysis procedures. Measurements of PM(sub 2.5) mass and major contributing species were well correlated among the different methods with r-values > 0.8. Despite the good correlations, daily concentrations of PM(sub 2.5) mass and major contributing species were significantly different at the 95% confidence level from 5 to 100% of the time. Larger values of PM(sub 2.5) mass and individual species were generally reported from STNR and STNS. The January STNR average PM(sub 2.5) mass (8.8 (micro)g/per cubic meter) was 1.5 (micro)g/per cubic meter larger than the DRIF average mass. The July STNS average PM(sub 2.5) mass (27.8 (micro)g/per cubic meter) was 3.8 (micro)g/per cubic meter larger than the DRIF average mass. These differences can only be partially accounted for by known random errors. Variations in flow control, face velocity, and sampling artifacts likely influence the measurement of PM(sub 2.5) speciation and mass closure. Simple statistical tests indicate that the current uncertainty estimates used in the STN network may underestimate the actual uncertainty.

Ocean Turbulence I: One-Point Closure Model Momentum and Heat Vertical Diffusivities

NASA Technical Reports Server (NTRS)

Canuto, V. M.; Howard, A.; Cheng, Y.; Dubovikov, M. S.

1999-01-01

Since the early forties, one-point turbulence closure models have been the canonical tools used to describe turbulent flows in many fields. In geophysics, Mellor and Yamada applied such models using the 1980 state-of-the art. Since then, no improvements were introduced to alleviate two major difficulties: 1) closure of the pressure correlations, which affects the correct determination of the critical Richardson number Ri(sub cr) above which turbulent mixing is no longer possible and 2) the need to express the non-local third-order moments (TOM) in terms of lower order moments rather than via the down-gradient approximation as done thus far, since the latter seriously underestimates the TOMs. Since 1) and 2) are still being dealt with adjustable parameters which weaken the credibility of the models, alternative models, not based on turbulence modeling, have been suggested. The aim of this paper is to show that new information, partly derived from the newest 2-point closure model discussed, can be used to solve these shortcomings. The new one-point closure model, which in its simplest form is algebraic and thus simple to implement, is first shown to reproduce a variety of data. Then, it is used in a Ocean-General Circulation Model (O-GCM) where it reproduces well a large variety of ocean data. While phenomenological models are specifically tuned to ocean turbulence, the present model is not. It is first tested against laboratory data on stably stratified flows and then used in an O-GCM. It is more general, more predictive and more resilient, e.g., it can incorporate phenomena like wave-breaking at the surface, salinity diffusivity, non-locality, etc. One important feature that naturally comes out of the new model is that the predicted Richardson critical value Ri(sub cr) is Ri (sub cr approx. = 1) in agreement with both Large Eddy Simulations (LES) and empirical evidence while all previous models predicted Ri (sub cr approx. = 0.2) which led to a considerable underestimate of the extent of turbulent mixing and thus to an incorrect mixed layer depth. The predicted temperature and salinity profiles (vs. depth) are presented and compared with those of the Kolmogorov-Petruvsky-Piskunuv (KPP) model and Levitus data.

Synthesis of NiO-TiO2 hybrids/mSiO2 yolk-shell architectures embedded with ultrasmall gold nanoparticles for enhanced reactivity

NASA Astrophysics Data System (ADS)

Fang, Jiasheng; Zhang, Yiwei; Zhou, Yuming; Zhao, Shuo; Zhang, Chao; Huang, Mengqiu; Gao, Yan

2017-08-01

Novel NiO-TiO2 hybrids/mSiO2 yolk-shell architectures loaded with ultrasmall Au nanoparticles (STNVS-Au) were developed via the rational synthetic strategy. The hierarchical yolk-shell nanostructures (STNVS) with high surface areas were constructed by a facile "bottom-up" assembly process using SiO2 materials and polymer resins as cores/shells and sacrificial templates, accompanied by a simple hydrothermal incorporation of NiO into uniform amorphous TiO2 layers that were converted to NiO-anatase TiO2 p-n heterojunction hybrids. Then, numerous sub-3 nm Au nanoparticles were post encapsulated within STNVS nanostructures through the low-temperature hydrogen reduction based on the unique deposition-precipitation method with Au(en)2Cl3 compounds as gold precursors. The NiO-TiO2 hybrids alloying with Au nanoparticles were effectively protected and entrapped within STNVS architectures, and interacted with outer mSiO2-Au shells, which comprised the powerful STNVS-Au yolk-shell nanoreactors and produced stronger configural synergies in enhancing the heterogeneous catalysis. Into catalyzing the reduction of 4-nitrophenol to 4-aminophenol, the STNVS-Au was shown with outstanding activity and reusability, and its pristine morphology was well retained during the recycling process.

Description of strong M1 transitions between 4^+ states at N=52 within the sdg-IBM-2

NASA Astrophysics Data System (ADS)

Casperson, R. J.; Werner, V.; Heinze, S.

2009-10-01

The interplay between collective and single-particle degrees of freedom for nuclei near the N=50 shell closure have recently been under investigation. In Molybdenum and Ruthenium nuclei, collective symmetric and mixed-symmetric structures have been identified, while in Zirconium, underlying shell-structure plays an enhanced role. The one-phonon 2^+ mixed-symmetry state was identified from its strong M1 transition to the 2^+1 state. Similar transitions were observed between 4^+ states in ^94Mo and ^92Zr, and shell model calculations indicate that hexadecapole excitations play a role. These phenomena will be investigated within the sdg-Interacting Boson Model-2 in order to gain a better understanding about the structure of the states involved, and to which extent the hexadecapole degree of freedom is important at relatively low energies. First calculations within this model, using an F-spin conserving Hamiltonian to disentangle symmetric and mixed- symmetric structures, will be presented and compared to data.

1p3/2 proton-hole state in 132Sn and the shell structure along N = 82.

PubMed

Taprogge, J; Jungclaus, A; Grawe, H; Nishimura, S; Doornenbal, P; Lorusso, G; Simpson, G S; Söderström, P-A; Sumikama, T; Xu, Z Y; Baba, H; Browne, F; Fukuda, N; Gernhäuser, R; Gey, G; Inabe, N; Isobe, T; Jung, H S; Kameda, D; Kim, G D; Kim, Y-K; Kojouharov, I; Kubo, T; Kurz, N; Kwon, Y K; Li, Z; Sakurai, H; Schaffner, H; Steiger, K; Suzuki, H; Takeda, H; Vajta, Zs; Watanabe, H; Wu, J; Yagi, A; Yoshinaga, K; Benzoni, G; Bönig, S; Chae, K Y; Coraggio, L; Covello, A; Daugas, J-M; Drouet, F; Gadea, A; Gargano, A; Ilieva, S; Kondev, F G; Kröll, T; Lane, G J; Montaner-Pizá, A; Moschner, K; Mücher, D; Naqvi, F; Niikura, M; Nishibata, H; Odahara, A; Orlandi, R; Patel, Z; Podolyák, Zs; Wendt, A

2014-04-04

A low-lying state in 131In82, the one-proton hole nucleus with respect to double magic 132Sn, was observed by its γ decay to the Iπ=1/2- β-emitting isomer. We identify the new state at an excitation energy of Ex=1353  keV, which was populated both in the β decay of 131Cd83 and after β-delayed neutron emission from 132Cd84, as the previously unknown πp3/2 single-hole state with respect to the 132Sn core. Exploiting this crucial new experimental information, shell-model calculations were performed to study the structure of experimentally inaccessible N=82 isotones below 132Sn. The results evidence a surprising absence of proton subshell closures along the chain of N=82 isotones. The consequences of this finding for the evolution of the N=82 shell gap along the r-process path are discussed.

Single-neutron orbits near 78Ni: Spectroscopy of the N = 49 isotope 79Zn

DOE PAGES

Orlandi, R.; Mücher, D.; Raabe, R.; ...

2014-12-09

Single-neutron states in the Z=30, N=49 isotope 79Zn have been populated using the 78Zn(d, p) 79Zn transfer reaction at REX-ISOLDE, CERN. The experimental setup allowed the combined detection of protons ejected in the reaction, and of γ rays emitted by 79Zn. The analysis reveals that the lowest excited states populated in the reaction lie at approximately 1 MeV of excitation, and involve neutron orbits above the N=50 shell gap. From the analysis of γ -ray data and of proton angular distributions, characteristic of the amount of angular momentum transferred, a 5/2 + configuration was assigned to a state at 983more » keV. Comparison with large-scale-shell-model calculations supports a robust neutron N=50 shell-closure for 78Ni. Finally, these data constitute an important step towards the understanding of the magicity of 78Ni and of the structure of nuclei in the region.« less

Coulomb Excitation of Neutron-Rich Zn Isotopes: First Observation of the 21+ State in Zn80

NASA Astrophysics Data System (ADS)

van de Walle, J.; Aksouh, F.; Ames, F.; Behrens, T.; Bildstein, V.; Blazhev, A.; Cederkäll, J.; Clément, E.; Cocolios, T. E.; Davinson, T.; Delahaye, P.; Eberth, J.; Ekström, A.; Fedorov, D. V.; Fedosseev, V. N.; Fraile, L. M.; Franchoo, S.; Gernhauser, R.; Georgiev, G.; Habs, D.; Heyde, K.; Huber, G.; Huyse, M.; Ibrahim, F.; Ivanov, O.; Iwanicki, J.; Jolie, J.; Kester, O.; Köster, U.; Kröll, T.; Krücken, R.; Lauer, M.; Lisetskiy, A. F.; Lutter, R.; Marsh, B. A.; Mayet, P.; Niedermaier, O.; Nilsson, T.; Pantea, M.; Perru, O.; Raabe, R.; Reiter, P.; Sawicka, M.; Scheit, H.; Schrieder, G.; Schwalm, D.; Seliverstov, M. D.; Sieber, T.; Sletten, G.; Smirnova, N.; Stanoiu, M.; Stefanescu, I.; Thomas, J.-C.; Valiente-Dobón, J. J.; van Duppen, P.; Verney, D.; Voulot, D.; Warr, N.; Weisshaar, D.; Wenander, F.; Wolf, B. H.; Zielińska, M.

2007-10-01

Neutron-rich, radioactive Zn isotopes were investigated at the Radioactive Ion Beam facility REX-ISOLDE (CERN) using low-energy Coulomb excitation. The energy of the 21+ state in Zn78 could be firmly established and for the first time the 2+→01+ transition in Zn80 was observed at 1492(1) keV. B(E2,21+→01+) values were extracted for Zn74,76,78,80 and compared to large scale shell model calculations. With only two protons outside the Z=28 proton core, Zn80 is the lightest N=50 isotone for which spectroscopic information has been obtained to date. Two sets of advanced shell model calculations reproduce the observed B(E2) systematics. The results for N=50 isotones indicate a good N=50 shell closure and a strong Z=28 proton core polarization. The new results serve as benchmarks to establish theoretical models, predicting the nuclear properties of the doubly magic nucleus Ni78.

Unstrained and strained flamelets for LES of premixed combustion

NASA Astrophysics Data System (ADS)

Langella, Ivan; Swaminathan, Nedunchezhian

2016-05-01

The unstrained and strained flamelet closures for filtered reaction rate in large eddy simulation (LES) of premixed flames are studied. The required sub-grid scale (SGS) PDF in these closures is presumed using the Beta function. The relative performances of these closures are assessed by comparing numerical results from large eddy simulations of piloted Bunsen flames of stoichiometric methane-air mixture with experimental measurements. The strained flamelets closure is observed to underestimate the burn rate and thus the reactive scalars mass fractions are under-predicted with an over-prediction of fuel mass fraction compared with the unstrained flamelet closure. The physical reasons for this relative behaviour are discussed. The results of unstrained flamelet closure compare well with experimental data. The SGS variance of the progress variable required for the presumed PDF is obtained by solving its transport equation. An order of magnitude analysis of this equation suggests that the commonly used algebraic model obtained by balancing source and sink in this transport equation does not hold. This algebraic model is shown to underestimate the SGS variance substantially and the implications of this variance model for the filtered reaction rate closures are highlighted.

Kelly mud saver valve sub

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddoch, J.A.

1986-12-02

A mud saver valve is described for preventing drilling mud from escaping from a kelly when a drill string is broken below the kelly, the valve comprising: a tubular valve body having first and second ends, the first end being provided with means for attachment in fluid communicating relationship with the kelly, the second end being provided with means for attachment to the drill string; an annular seat fixed in the interior of the valve body adjacent its first end; a tubular closure member within the valve body. The closure member is provided with a selectively closed seating end formore » seating in valve closing engagement with the annular seat, an open non-seating end in fluid communicating relationship with the drill string, and an annular expansion in the outer diameter of the closure member adjacent the seating end; a top and bottom spacer ring disposed in sliding relationship around the tubular closure member intermediate the annular expansion and the non-seating end of the closure member. The spacer ring and annular expansion cooperatively define an annular chamber around the closure member; and a helical spring disposed around the closure member towards the annular seat.« less

Parametric Analysis of Life Support Systems for Future Space Exploration Missions

NASA Technical Reports Server (NTRS)

Swickrath, Michael J.; Anderson, Molly S.; Bagdigian, Bob M.

2011-01-01

The National Aeronautics and Space Administration is in a process of evaluating future targets for space exploration. In order to maintain the welfare of a crew during future missions, a suite of life support technology is responsible for oxygen and water generation, carbon dioxide control, the removal of trace concentrations of organic contaminants, processing and recovery of water, and the storage and reclamation of solid waste. For each particular life support subsystem, a variety competing technologies either exist or are under aggressive development efforts. Each individual technology has strengths and weaknesses with regard to launch mass, power and cooling requirements, volume of hardware and consumables, and crew time requirements for operation. However, from a system level perspective, the favorability of each life support architecture is better assessed when the sub-system technologies are analyzed in aggregate. In order to evaluate each specific life support system architecture, the measure of equivalent system mass (ESM) was employed to benchmark system favorability. Moreover, the results discussed herein will be from the context of loop-closure with respect to the air, water, and waste sub-systems. Specifically, closure relates to the amount of consumables mass that crosses the boundary of the vehicle over the lifetime of a mission. As will be demonstrated in this manuscript, the optimal level of loop closure is heavily dependent upon mission requirements such as duration and the level of extra-vehicular activity (EVA) performed. Sub-system level trades were also considered as a function of mission duration to assess when increased loop closure is practical. Although many additional factors will likely merit consideration in designing life support systems for future missions, the ESM results described herein provide a context for future architecture design decisions toward a flexible path program.

Outer organic layer and internal repair mechanism protects pteropod Limacina helicina from ocean acidification

NASA Astrophysics Data System (ADS)

Peck, Victoria L.; Tarling, Geraint A.; Manno, Clara; Harper, Elizabeth M.; Tynan, Eithne

2016-05-01

Scarred shells of polar pteropod Limacina helicina collected from the Greenland Sea in June 2012 reveal a history of damage, most likely failed predation, in earlier life stages. Evidence of shell fracture and subsequent re-growth is commonly observed in specimens recovered from the sub-Arctic and further afield. However, at one site within sea-ice on the Greenland shelf, shells that had been subject to mechanical damage were also found to exhibit considerable dissolution. It was evident that shell dissolution was localised to areas where the organic, periostracal sheet that covers the outer shell had been damaged at some earlier stage during the animal's life. Where the periostracum remained intact, the shell appeared pristine with no sign of dissolution. Specimens which appeared to be pristine following collection were incubated for four days. Scarring of shells that received periostracal damage during collection only became evident in specimens that were incubated in waters undersaturated with respect to aragonite, ΩAr≤1. While the waters from which the damaged specimens were collected at the Greenland Sea sea-ice margin were not ΩAr≤1, the water column did exhibit the lowest ΩAr values observed in the Greenland and Barents Seas, and was likely to have approached ΩAr≤1 during the winter months. We demonstrate that L. helicina shells are only susceptible to dissolution where both the periostracum has been breached and the aragonite beneath the breach is exposed to waters of ΩAr≤1. Exposure of multiple layers of aragonite in areas of deep dissolution indicate that, as with many molluscs, L. helicina is able to patch up dissolution damage to the shell by secreting additional aragonite internally and maintain their shell. We conclude that, unless breached, the periostracum provides an effective shield for pteropod shells against dissolution in waters ΩAr≤1, and when dissolution does occur the animal has an effective means of self-repair. We suggest that future studies of pteropod shell condition are undertaken on specimens from which the periostracum has not been removed in preparation.

Buckling analysis of Big Dee Vacuum Vessel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lightner, S.; Gallix, R.

1983-12-01

A simplified three-dimensional shell buckling analysis of the GA Technologies Inc., Big Dee Vacuum Vessel (V/V) was performed using the finite element program TRICO. A coarse-mesh linear elastic model, which accommodated the support boundary conditions, was used to determine the buckling mode shape under a uniform external pressure. Using this buckling mode shape, refined models were used to calculate the linear buckling load (P/sub crit/) more accurately. Several different designs of the Big Dee V/V were considered in this analysis. The supports for the V/V were equally-spaced radial pins at the outer diameter of the mid-plane. For all the casesmore » considered, the buckling mode was axisymmetric in the toroidal direction. Therefore, it was possible to use only a small angular sector of a toric shell for the refined analysis. P/sub crit/ for the Big Dee is about 60 atm for a uniform external pressure. Also investigated in this analysis were the effects of geometrical imperfections and non-uniform pressure distributions.« less

Fabrication and characterization of copper oxide (CuO)–gold (Au)–titania (TiO{sub 2}) and copper oxide (CuO)–gold (Au)–indium tin oxide (ITO) nanowire heterostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chopra, Nitin, E-mail: nchopra@eng.ua.edu; Department of Biological Sciences, The University of Alabama, Tuscaloosa, AL 35487; Shi, Wenwu

2014-10-15

Nanoscale heterostructures composed of standing copper oxide nanowires decorated with Au nanoparticles and shells of titania and indium tin oxide were fabricated. The fabrication process involved surfactant-free and wet-chemical nucleation of gold nanoparticles on copper oxide nanowires followed by a line-of-sight sputtering of titania or indium tin oxide. The heterostructures were characterized using high resolution electron microscopy, diffraction, and energy dispersive spectroscopy. The interfaces, morphologies, crystallinity, phases, and chemical compositions were analyzed. The process of direct nucleation of gold nanoparticles on copper oxide nanoparticles resulted in low energy interface with aligned lattice for both the components. Coatings of polycrystalline titaniamore » or amorphous indium tin oxide were deposited on standing copper oxide nanowire–gold nanoparticle heterostructures. Self-shadowing effect due to standing nanowire heterostructures was observed for line-of-sight sputter deposition of titania or indium tin oxide coatings. Finally, the heterostructures were studied using Raman spectroscopy and ultraviolet–visible spectroscopy, including band gap energy analysis. Tailing in the band gap energy at longer wavelengths (or lower energies) was observed for the nanowire heterostructures. - Highlights: • Heterostructures comprised of CuO nanowires coated with Au nanoparticles. • Au nanoparticles exhibited nearly flat and low energy interface with nanowire. • Heterostructures were further sputter-coated with oxide shell of TiO{sub 2} or ITO. • The process resulted in coating of polycrystalline TiO{sub 2} and amorphous ITO shell.« less

Generalized emission functions for photon emission from quark-gluon plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suryanarayana, S. V.

The Landau-Pomeranchuk-Migdal effects on photon emission from the quark-gluon plasma have been studied as a function of photon mass, at a fixed temperature of the plasma. The integral equations for the transverse vector function [f-tilde)(p-tilde){sub (perpendicular)})] and the longitudinal function [g-tilde)(p-tilde){sub (perpendicular)})] consisting of multiple scattering effects are solved by the self-consistent iterations method and also by the variational method for the variable set {l_brace}p{sub 0},q{sub 0},Q{sup 2}{r_brace}. We considered the bremsstrahlung and the off shell annihilation (aws) processes. We define two new dynamical scaling variables, x{sub T},x{sub L}, for bremsstrahlung and aws processes which are functions of variables p{submore » 0},q{sub 0},Q{sup 2}. We define four new emission functions for massive photon emission represented by g{sub T}{sup b},g{sub T}{sup a},g{sub L}{sup b},g{sub L}{sup a} and we constructed these using the exact numerical solutions of the integral equations. These four emission functions have been parametrized by suitable simple empirical fits. Using the empirical emission functions, we calculated the imaginary part of the photon polarization tensor as a function of photon mass and energy.« less

AN INFRARED SEARCH FOR HDO IN COMET D/2012 S1 (ISON) AND IMPLICATIONS FOR iSHELL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gibb, Erika L.; Bonev, Boncho P.; Villanueva, Geronimo L.

2016-01-10

We performed a sensitive search for HDO in comet D/2012 S1 (ISON) on 2013 November 16, 17, and 22 using CSHELL and the NASA Infrared Telescope Facility. We constrained the HDO/H{sub 2}O ratio to <2.0 VSMOW (the terrestrial ocean value) at the 3σ uncertainty level from two independent measurements corresponding to different H{sub 2}O outgassing rates. This represents the best constrained HDO/H{sub 2}O ratio for a comet using a small (3 m) telescope and illustrates that when CSHELL is replaced with iSHELL, 3 m class telescopes are still strong contenders for detecting minor volatile species in moderately bright comets.

Crack Turning Mechanics of Composite Wing Skin Panels

NASA Technical Reports Server (NTRS)

Yuan, F. G.; Reeder, James R. (Technical Monitor)

2001-01-01

The safety of future composite wing skin integral stiffener panels requires a full understanding of failure mechanisms of these damage tolerance critical structures under both in-plane and bending loads. Of primary interest is to derive mathematical models using fracture mechanics in anisotropic cracked plate structures, to assess the crack turning mechanisms, and thereby to enhance the residual strength in the integral stiffener composite structures. The use of fracture mechanics to assess the failure behavior in a cracked structure requires the identification of critical fracture parameters which govern the severity of stress and deformation field ahead of the flaw, and which can be evaluated using information obtained from the flaw tip. In the three-year grant, the crack-tip fields under plane deformation, crack-tip fields for anisotropic plates and anisotropic shells have been obtained. In addition, methods for determining the stress intensity factors, energy release rate, and the T-stresses have been proposed and verified. The research accomplishments can be summarized as follows: (1) Under plane deformation in anisotropic solids, the asymptotic crack-tip fields have been obtained using Stroh formalism; (2) The T-stress and the coefficient of the second term for sigma(sub y), g(sub 32), have been obtained using path-independent integral, the J-integral and Betti's reciprocal theorem together with auxiliary fields; (3) With experimental data performed by NASA, analyses indicated that the mode-I critical stress intensity factor K(sub Q) provides a satisfactory characterization of fracture initiation for a given laminate thickness, provided the failure is fiber-dominated and crack extends in a self-similar manner; (4) The high constraint specimens, especially for CT specimens, due to large T-stress and large magnitude of negative g(sub 32) term may be expected to inhibit the crack extension in the same plane and promote crack turning; (5) Crack turning out of crack plane in generally anisotropic solids under plane deformation has been studied; (6) The role of T-stress and the higher-order term of sigma(sub y) on the crack turning and stability of the kinked crack has been quantified; (7) Asymptotic crack-tip fields including the effect of transverse shear deformation (Reissner plate theory) in an anisotropic plate under bending, twisting moments, and transverse shear loads has been presented; (8) The expression of the path-independent J-integral in terms of the generalized stress and strain has been derived; (9) Asymptotic crack-tip fields including the effect of transverse shear deformation (Reissner shallow shell theory) in a general anisotropic shell has been developed; (10) The Stroh formalism was used to characterize the crack tip fields in shells up to the second term and the energy release rate was expressed in a very compact form.

Synergistic effect between D-AP5 and muscimol in the nucleus accumbens shell on memory consolidation deficit in adult male Wistar rats: An isobologram analysis.

PubMed

Nasehi, Mohammad; Ostadi, Elaheh; Khakpai, Fatemeh; Ebrahimi-Ghiri, Mohaddeseh; Zarrindast, Mohammad-Reza

2017-05-01

The nucleus accumbens (NAc) glutamatergic and GABAergic systems are involved in memory processes. This study was investigated the involvement of NAc shell GABAergic system on D-AP5 induced memory consolidation deficit. The elevated plus-maze (EPM) test-retest paradigm was employed to assess memory in adult male Wistar rats. The results indicated that post-training intra-NAc shell injection of bicuculline (GABA A receptor antagonist) did not alter emotional memory consolidation. However, post-training intra-NAc shell microinjection of muscimol (GABA A receptor agonist, 0.1μg/rat) and D-AP5 (a competitive NMDA receptor antagonist, 4μg/rat) decreased emotional memory consolidation, suggesting the drugs induced amnesia. Moreover, a sub-threshold dose of muscimol (0.05μg/rat) potentiated the D-AP5 (2μg/rat) response on memory consolidation impairment. On the other hand, the middle dose of bicuculline (0.25μg/rat) reversed memory impairment induced by D-AP5 at the higher dose. Interestingly, there is a synergistic effect between D-AP5 and muscimol on impairment of emotional memory consolidation. None of the above doses changed the locomotor activity. Our results suggest that the glutamatergic and GABAergic neurons of the NAc shell interact with each other for modulation of emotional memory consolidation. Copyright © 2017 Elsevier Inc. All rights reserved.

Solutions of the chemical kinetic equations for initially inhomogeneous mixtures.

NASA Technical Reports Server (NTRS)

Hilst, G. R.

1973-01-01

Following the recent discussions by O'Brien (1971) and Donaldson and Hilst (1972) of the effects of inhomogeneous mixing and turbulent diffusion on simple chemical reaction rates, the present report provides a more extensive analysis of when inhomogeneous mixing has a significant effect on chemical reaction rates. The analysis is then extended to the development of an approximate chemical sub-model which provides much improved predictions of chemical reaction rates over a wide range of inhomogeneities and pathological distributions of the concentrations of the reacting chemical species. In particular, the development of an approximate representation of the third-order correlations of the joint concentration fluctuations permits closure of the chemical sub-model at the level of the second-order moments of these fluctuations and the mean concentrations.

Buckling analysis of curved composite sandwich panels subjected to inplane loadings

NASA Technical Reports Server (NTRS)

Cruz, Juan R.

1993-01-01

Composite sandwich structures are being considered for primary structure in aircraft such as subsonic and high speed civil transports. The response of sandwich structures must be understood and predictable to use such structures effectively. Buckling is one of the most important response mechanisms of sandwich structures. A simple buckling analysis is derived for sandwich structures. This analysis is limited to flat, rectangular sandwich panels loaded by uniaxial compression (N(sub x)) and having simply supported edges. In most aerospace applications, however, the structure's geometry, boundary conditions, and loading are usually very complex. Thus, a general capability for analyzing the buckling behavior of sandwich structures is needed. The present paper describes and evaluates an improved buckling analysis for cylindrically curved composite sandwich panels. This analysis includes orthotropic facesheets and first-order transverse shearing effects. Both simple support and clamped boundary conditions are also included in the analysis. The panels can be subjected to linearly varying normal loads N(sub x) and N(sub y) in addition to a constant shear load N(sub xy). The analysis is based on the modified Donnell's equations for shallow shells. The governing equations are solved by direct application of Galerkin's method. The accuracy of the present analysis is verified by comparing results with those obtained from finite element analysis for a variety of geometries, loads, and boundary conditions. The limitations of the present analysis are investigated, in particular those related to the shallow shell assumptions in the governing equations. Finally, the computational efficiency of the present analysis is considered.

Inherent and Apparent Scattering Properties of Coated or Uncoated Spheres Embedded in an Absorbing Host Medium

NASA Technical Reports Server (NTRS)

Yang, P.; Gao, B.-C.; Wiscombe, W. J.; Mishchenko, M. I.; Platnick, S.; Huang, H.-L.; Baum, B. A.; Hu, Y. X.; Winkler, D,; Tsay, S.-C.;

Fabrication and characterization of millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} ceramic hollow spheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Haoting; Liao, Qilong, E-mail: liaoqilong@swust.edu.cn; Dai, Yunya

2016-04-15

Highlights: • Millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} hollow spheres have been prepared. • The diameters of the prepared hollow spheres are 500–1300μm. • The degree of sphericity for the prepared hollow spheres is above 98%. • The mechanisms of transparency are discussed. - Abstract: Millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} ceramic hollow spheres have been successfully prepared using the oil-in-water (paraffin-in-alumina sol) droplets as precursors made by self-made T-shape micro-emulsion device. The main crystalline phase of the obtained hollow sphere is alpha alumina. The prepared translucent La{sub 2}O{sub 3}-containing Al{sub 2}O{sub 3} ceramic hollow spheresmore » have diameters of 500–1300 μm, wall thickness of about 23 μm and the degree of sphericity of above 98%. With the increase of the La{sub 2}O{sub 3} content, grains and grain-boundaries of the alumina spherical shell for the prepared millimeter-scale hollow spheres become regular and clear gradually. When the La{sub 2}O{sub 3} content is 0.1 wt.%, the crystal surface of the obtained Al{sub 2}O{sub 3} spherical shell shows optimal grains and few pores, and its transmittance reaches 42% at 532 nm laser light. This method provides a promising technique of preparing millimeter-scale translucent ceramic hollow spheres for laser inertial confined fusion.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Su, Yang; Zhou, Xin; Yang, Ji

HESS J1912+101 is a shell-like TeV source that has no clear counterpart in multiwavelength. Using CO and H i data, we reveal that V {sub LSR} ∼ +60 km s{sup −1} molecular clouds (MCs), together with shocked molecular gas and high-velocity neutral atomic shells, are concentrated toward HESS J1912+101. The prominent wing profiles up to V {sub LSR} ∼ +80 km s{sup −1} seen in {sup 12}CO ( J = 1–0 and J = 3–2) data, as well as the high-velocity expanding H i shells up to V {sub LSR} ∼ +100 km s{sup −1}, exhibit striking redshifted-broadening relative tomore » the quiescent gas. These features provide compelling evidences for large-scale perturbation in the region. We argue that the shocked MCs and the high-velocity H i shells may originate from an old supernova remnant (SNR). The distance to the SNR is estimated to be ∼4.1 kpc based on the H i self-absorption method, which leads to a physical radius of 29.0 pc for the ∼(0.7–2.0) × 10{sup 5} years old remnant with an expansion velocity of ≳40 km s{sup −1}. The +60 km s{sup −1} MCs and the disturbed gas are indeed found to coincide with the bright TeV emission, supporting the physical association between them. Naturally, the shell-like TeV emission comes from the decay of neutral pions produced by interactions between the accelerated hadrons from the SNR and the surrounding high-density molecular gas.« less

50 CFR 648.201 - AMs and harvest controls.

Code of Federal Regulations, 2014 CFR

2014-10-01

... Atlantic Herring Fishery § 648.201 AMs and harvest controls. (a) AMs—(1) Herring sub-ACLs and ACL—(i) Management area closure. If NMFS projects that catch will reach 92 percent of the annual sub-ACL allocated to...-ACL allocated to a seasonal period as set forth in paragraph (d) of this section, NMFS shall prohibit...

50 CFR 648.201 - AMs and harvest controls.

Code of Federal Regulations, 2013 CFR

2013-10-01

... Atlantic Herring Fishery § 648.201 AMs and harvest controls. (a) AMs—(1) Herring sub-ACLs and ACL—(i) Management area closure. If NMFS projects that catch will reach 92 percent of the annual sub-ACL allocated to...-ACL allocated to a seasonal period as set forth in paragraph (d) of this section, NMFS shall prohibit...

Spontaneous vortex nanodomain arrays at ferroelectric heterointerfaces.

PubMed

Nelson, Christopher T; Winchester, Benjamin; Zhang, Yi; Kim, Sung-Joo; Melville, Alexander; Adamo, Carolina; Folkman, Chad M; Baek, Seung-Hyub; Eom, Chang-Beom; Schlom, Darrell G; Chen, Long-Qing; Pan, Xiaoqing

2011-02-09

The polarization of the ferroelectric BiFeO(3) sub-jected to different electrical boundary conditions by heterointerfaces is imaged with atomic resolution using a spherical aberration-corrected transmission electron microscope. Unusual triangular-shaped nanodomains are seen, and their role in providing polarization closure is understood through phase-field simulations. Heterointerfaces are key to the performance of ferroelectric devices, and this first observation of spontaneous vortex nanodomain arrays at ferroelectric heterointerfaces reveals properties unlike the surrounding film including mixed Ising-Néel domain walls, which will affect switching behavior, and a drastic increase of in-plane polarization. The importance of magnetization closure has long been appreciated in multidomain ferromagnetic systems; imaging this analogous effect with atomic resolution at ferroelectric heterointerfaces provides the ability to see device-relevant interface issues. Extension of this technique to visualize domain dynamics is envisioned.

Kinetic investigation of narrow-bore columns packed with prototype sub-2 μm superficially porous particles with various shell thickness.

PubMed

Gritti, Fabrice; Omamogho, Jesse; Guiochon, Georges

2011-10-07

The recent successful breakthrough of sub-3 μm shell particles in HPLC has triggered considerable research efforts toward the design of new brands of core-shell particles. We investigated the mass transfer mechanism of a few analytes in narrow-bore columns packed with prototype 1.7 μm shell particles, made of 1.0, 1.2, and 1.4 μm solid nonporous cores surrounded by porous shells 350, 250, and 150 nm thick, respectively. Three probe solutes, uracil, naphthalene, and insulin, were chosen to assess the kinetic performance of these columns. Inverse size exclusion chromatography, peak parking experiments, and the numerical integration of the experimental peak profiles were carried out in order to measure the external, internal, and total column porosities, the true bulk diffusion coefficients of these analytes, the height equivalent to a theoretical plate, the longitudinal diffusion term, and the trans-particle mass transfer resistance term. The residual eddy diffusion term was measured by difference. The results show the existence of important trans-column velocity biases (7%) possibly due to the presence of particle multiplets in the slurry mixture used during the packing process. Our results illustrates some of the difficulties encountered by scientists preparing and packing shell particles into narrow-bore columns. Copyright © 2011 Elsevier B.V. All rights reserved.

Evaluating Microstructure Preservation using Scanning Electron Microscopy in an Extinct Bivalve, Lahillia larseni

NASA Astrophysics Data System (ADS)

Mohr, R. C.; Tobin, T. S.

2017-12-01

Ontogenetic stable isotope (δ18O) sampling of accretionary carbonate shells can provide sub-annual records of environmental conditions, such as seawater temperature, during the life of an organism. These records of seasonal temperature variations can refine our understanding of ancient climates and past climate change. However, because original isotopic signatures can be altered by diagenesis, it is necessary to examine potential specimens for evidence of diagenetic alteration. Abundant aragonitic Lahillia larseni bivalves from the latest Cretaceous and Early Paleogene on Seymour Island, Antarctica, provide excellent opportunities for sclerochronological investigations. Shells of L. larseni preserve clear annual growth bands, which make them ideal candidates for high-resolution δ18O sampling to produce sub-annual records of seawater temperature variation. While the good visual condition of these shells and the preservation of original aragonitic material suggests a high level of preservation suitable for isotopic analysis, subtle alteration of the original shell microstructures can still compromise the original isotopic signatures. Scanning electron microscopy (SEM) can be used to evaluate the preservation of these microstructures. This study compares methods for imaging L. larseni bivalve shells with SEM and seeks a consistent way to evaluate their various microstructures for evidence of diagenetic alteration. High-resolution ontogenetic isotopic sampling will also be conducted on several L. larseni shells, as roughly sinusoidal δ18O profiles are often an indication that the original isotopic signatures have been preserved.

Aeroperformance and Acoustics of the Nozzle with Permeable Shell

NASA Technical Reports Server (NTRS)

Gilinsky, M.; Blankson, I. M.; Chernyshev, S. A.; Chernyshev, S. A.

1999-01-01

Several simple experimental acoustic tests of a spraying system were conducted at the NASA Langley Research Center. These tests have shown appreciable jet noise reduction when an additional cylindrical permeable shell was employed at the nozzle exit. Based on these results, additional acoustic tests were conducted in the anechoic chamber AK-2 at the Central Aerohydrodynamics Institute (TsAGI, Moscow) in Russia. These tests examined the influence of permeable shells on the noise from a supersonic jet exhausting from a round nozzle designed for exit Mach number, M (sub e)=2.0, with conical and Screwdriver-shaped centerbodies. The results show significant acoustic benefits of permeable shell application especially for overexpanded jets by comparison with impermeable shell application. The noise reduction in the overall pressure level was obtained up to approximately 5-8%. Numerical simulations of a jet flow exhausting from a convergent-divergent nozzle designed for exit Mach number, M (sub e)=2.0, with permeable and impermeable shells were conducted at the NASA LaRC and Hampton University. Two numerical codes were used. The first is the NASA LaRC CFL3D code for accurate calculation of jet mean flow parameters on the basis of a full Navier-Stokes solver (NSE). The second is the numerical code based on Tam's method for turbulent mixing noise (TMN) calculation. Numerical and experimental results are in good qualitative agreement.

Dust around Mira variables: An analysis of IRAS LRS spectra

NASA Technical Reports Server (NTRS)

Slijkhuis, S.

1989-01-01

The spatial extent and spectral appearance of the thin dust shell around Mira variables is determined largely by the dust absorptivity, Q(sub abs)(lambda), and the dust condensation temperature T(sub cond). Both Q(sub abs)(lambda) and T(sub cond) are extracted from IRAS low-resolution spectra (LRS) spectra. In order to do this, the assumption that the ratio of total power in the 10 micron feature to that in the 20 micron feature should be equal to that measured in other amorphous silicates (e.g., synthesized amorphous Mg2SiO4). It was found that T(sub cond) decreases with decreasing strength of the 10 micron feature, from T(sub cond) = 1000 K to 500 K (estimated error 20 percent). A value for the near-infrared dust absorptivity could not be determined. Although this parameter strongly affects the condensation radius, it hardly affects the shape of the LRS spectrum (as long as the optically thin approximation is valid), because it scales the spatial distribution of the dust. Information on the magnitude of the near-infrared dust absorptivity may be deduced from the unique carbon star BM Gem. This star has a LRS spectrum with silicate features indication an inner dust shell temperature of at least 1000 K. However, on the basis of observations in the 1920s-30s one may infer an inner dust shell radius of at least 6x10(exp 12)m. To have this high temperature at such a large distance, the near-infrared absorptivity of the dust must be high.

Survey of the (. cap alpha. ,/sup 2/He) reaction on 1p- and 2s1d-shell nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jahn, R.; Stahel, D.P.; Wozniak, G.J.

A /sup 2/He detection system has been developed and used to investigate the (..cap alpha..,/sup 2/He) reaction at bombarding energies of 55 and 65 MeV on targets of /sup 12/C, /sup 13/C, /sup 14/N, /sup 15/N, /sup 16/O, /sup 18/O, /sup 20/Ne, /sup 22/Ne, /sup 24/Mg, /sup 26/Mg, /sup 28/Si, /sup 29/Si, /sup 32/S, /sup 36/Ar, /sup 38/Ar, and /sup 40/Ca. Preferential population of two-neutron states with dominant (d/sub 5/2/)/sup 2//sub 4/, (d/sub 3/2/f/sub 7/2/)/sub 5/, and (f/sub 7/2/)/sup 2//sub 6/ character was observed. A linear A dependence of the binding energies of the J/sup ..pi../ = 5/sup -/ andmore » 6/sup +/ states was obtained. This systematic behavior is well described by the Bansal-French model, using the parameters a = - 0.30 MeV and b = 2.6 MeV. Simple shell-model calculations for the 2n configurations are in good agreement with the experimental data.« less

Electrodeposition of hierarchical ZnO/Cu{sub 2}O nanorod films for highly efficient visible-light-driven photocatalytic applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ren, S. T.; Fan, G. H.; Liang, M. L.

2014-02-14

The development of high-performance visible-light-responsive photocatalytic materials has attracted widespread interest due to their potential applications in the environmental and energy industries. In this work, hierarchical ZnO nanorods films were successfully prepared on the stainless steel mesh substrates via a simple two-step seed-assisted electrodeposition route. Cu{sub 2}O nanoparticles were then electrodeposited on the surface of ZnO nanorods to form the core-shell heterostructure. The synthesized ZnO/Cu{sub 2}O nanocomposites were characterized by X-ray diffraction, field-emission scanning electron microscopy, and UV-visible spectrophotometer. Due to the branched hierarchical morphologies and core-shell structure, ZnO/Cu{sub 2}O nanomaterials show a prominent visible-light-driven photocatalytic performance under the low-intensitymore » light irradiation (40 mW/cm{sup 2}). The influence of some experimental parameters, such as Cu{sub 2}O loading amount, ZnO morphologies, the substrate type, and the PH of the Cu{sub 2}O precursor solution on ZnO/Cu{sub 2}O photocatalytic performance was evaluated.« less

Accidental degeneracy in photonic bands and topological phase transitions in two-dimensional core-shell dielectric photonic crystals.

PubMed

Xu, Lin; Wang, Hai-Xiao; Xu, Ya-Dong; Chen, Huan-Yang; Jiang, Jian-Hua

2016-08-08

A simple core-shell two-dimensional photonic crystal is studied where the triangular lattice symmetry and the C₆ point group symmetry give rich physics in accidental touching points of photonic bands. We systematically evaluate different types of accidental nodal points at the Brillouin zone center for transverse-magnetic harmonic modes when the geometry and permittivity of the core-shell material are continuously tuned. The accidental nodal points can have different dispersions and topological properties (i.e., Berry phases). These accidental nodal points can be the critical states lying between a topological phase and a normal phase of the photonic crystal. They are thus very important for the study of topological photonic states. We show that, without breaking time-reversal symmetry, by tuning the geometry of the core-shell material, a phase transition into the photonic quantum spin Hall insulator can be achieved. Here the "spin" is defined as the orbital angular momentum of a photon. We study the topological phase transition as well as the properties of the edge and bulk states and their application potentials in optics.

The Rocket Investigation of Current Closure in the Ionosphere (RICCI) mission: A novel application of CubeSats from a sounding rocket platform

NASA Astrophysics Data System (ADS)

Cohen, I. J.; Anderson, B. J.; Lessard, M.; Bonnell, J. W.; Bounds, S. R.; Lysak, R. L.; Erlandson, R. E.

2017-12-01

The transfer of energy and momentum between the terrestrial magnetosphere and ionosphere is substantially mediated by large-scale field-aligned currents (FACs), driven by magnetopause dynamics and magnetospheric pressures and closing through the ionosphere where the dissipation and drag are governed. While significant insight into ionospheric electrodynamics and the nature of magnetosphere-ionosphere (M-I) coupling have been gained by rocket and satellite measurements, in situ measurement of these ionospheric closure currents remains challenging. To date the best estimates of ionospheric current densities are inferred from ground-based radar observations combining electric fields calculated from drifts with conductivities derived from densities. RICCI aims to observe the structure of the ionospheric currents in situ to determine how the altitude structure of these currents is related to precipitation and density cavities, electromagnetic dynamics, and governs energy dissipation in the ionosphere. In situ measurement of the current density using multi-point measurements of the magnetic field requires precise attitude knowledge for which the only demonstrated technique is the use of star camera systems. The low vehicle rotation rates required for miniature commercial off-the-shelf (COTS) star cameras prohibit the use of available rocket sub-payload technologies at Wallops Flight Facility (WFF) which use high rates of spin to stabilize attitude. However, CubeSat attitude systems are already designed to achieve low vehicle rotation rates, so RICCI will use a set of three CubeSat sub-payloads deployed from a main low altitude payload with apogee of 160 km to provide precise current density measurement through the ionospheric closure altitude regime, together with a second rocket with apogee near 320 km to measure the incident input energy flux and convection electric field. The two rocket payloads and CubeSate sub-payloads are all instrumented with star cameras and science-grade magnetometers. We discuss the mission design, payload complement, and science closure of this sub-orbital mission to obtain the first direct measurement of ionospheric currents associated with an auroral arc.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Talwar, R.; Kay, B. P.; Mitchell, A. J.

The nu 0h(9/2) and nu 0i(13/2) strength at Xe-137, a single neutron outside the N = 82 shell closure, has been determined using the Xe-136(alpha, He-3)Xe-137 reaction carried out at 100 MeV. We confirm the recent observation of the second 13/2(+) state and reassess previous data on the 9/2(-) states, obtaining spectroscopic factors. These new data provide additional constraints on predictions of the same single-neutron excitations at Sn-133.

The Basic Surgical Skills Course in Sub-Saharan Africa: An Observational Study of Effectiveness.

PubMed

Fergusson, Stuart J; Sedgwick, David M; Ntakiyiruta, Georges; Ntirenganya, Faustin

2018-04-01

The Basic Surgical Skills (BSS) course is a common component of postgraduate surgical training programmes in sub-Saharan Africa, but was originally designed in a UK context, and its efficacy and relevance have not been formally assessed in Africa. An observational study was carried out during a BSS course delivered to early-stage surgical trainees from Rwanda and the Democratic Republic of the Congo. Technical skill in a basic wound closure task was assessed in a formal Objective Structured Assessment of Technical Skills (OSAT) before and after course completion. Participants completed a pre-course questionnaire documenting existing surgical experience and self-perceived confidence levels in surgical skills which were to be taught during the course. Participants repeated confidence ratings and completed course evaluation following course delivery. A cohort of 17 participants had completed a pre-course median of 150 Caesarean sections as primary operator. Performance on the OSAT improved from a mean of 10.5/17 pre-course to 14.2/17 post-course (mean of paired differences 3.7, p < 0.001). Improvements were seen in 15/17 components of wound closure. Pre-course, only 47% of candidates were forming hand-tied knots correctly and 38% were appropriately crossing hands with each throw, improving to 88 and 76%, respectively, following the course (p = 0.01 for both components). Confidence levels improved significantly in all technical skills taught, and the course was assessed as highly relevant by trainees. The Basic Surgical Skills course is effective in improving the basic surgical technique of surgical trainees from sub-Saharan Africa and their confidence in key technical skills.

Imaging the asymmetric dust shell around CI Cam with long baseline optical interferometry

NASA Astrophysics Data System (ADS)

Thureau, N. D.; Monnier, J. D.; Traub, W. A.; Millan-Gabet, R.; Pedretti, E.; Berger, J.-P.; Garcia, M. R.; Schloerb, F. P.; Tannirkulam, A.-K.

2009-09-01

We present the first high angular resolution observation of the B[e] star/X-ray transient object CI Cam, performed with the two-telescope Infrared Optical Telescope Array (IOTA), its upgraded three-telescope version (IOTA3T) and the Palomar Testbed Interferometer (PTI). Visibilities and closure phases were obtained using the IONIC-3 integrated optics beam combiner. CI Cam was observed in the near-infrared H and K spectral bands, wavelengths well suited to measure the size and study the geometry of the hot dust surrounding CI Cam. The analysis of the visibility data over an 8yr period from soon after the 1998 outburst to 2006 shows that the dust visibility has not changed over the years. The visibility data show that CI Cam is elongated which confirms the disc-shape of the circumstellar environment and totally rules out the hypothesis of a spherical dust shell. Closure phase measurements show direct evidence of asymmetries in the circumstellar environment of CI Cam and we conclude that the dust surrounding CI Cam lies in an inhomogeneous disc seen at an angle. The near-infrared dust emission appears as an elliptical skewed Gaussian ring with a major axis a = 7.58 +/- 0.24mas, an axis ratio r = 0.39 +/- 0.03 and a position angle θ = 35° +/- 2°.

Rapid determination of parabens in seafood sauces by high-performance liquid chromatography: A practical comparison of core-shell particles and sub-2 μm fully porous particles.

PubMed

Ye, Jing; Cao, Xiaoji; Cheng, Zhuo; Qin, Ye; Lu, Yanbin

2015-12-01

In this work, the chromatographic performance of superficially porous particles (Halo core-shell C18 column, 50 mm × 2.1 mm, 2.7 μm) was compared with that of sub-2 μm fully porous particles (Acquity BEH C18 , 50 mm × 2.1 mm, 1.7 μm). Four parabens, methylparaben, ethylparaben, propylparaben, and butylparaben, were used as representative compounds for calculating the plate heights in a wide flow rate range and analyzed on the basis of the Van Deemter and Knox equations. Theoretical Poppe plots were constructed for each column to compare their kinetic performance. Both phases gave similar minimum plate heights when using nonreduced coordinates. Meanwhile, the flat C-term of the core-shell column provided the possibilities for applying high flow rates without significant loss in efficiency. The low backpressure of core-shell particles allowed this kind of column, especially compatible with conventional high-performance liquid chromatography systems. Based on these factors, a simple high-performance liquid chromatography method was established and validated for the determination of parabens in various seafood sauces using the Halo core-shell C18 column for separation. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Microcavity surface plasmon resonance bio-sensors

NASA Astrophysics Data System (ADS)

Mosavian, Nazanin

This work discusses a miniature surface plasmon biosensor which uses a dielectric sub- micron diameter core with gold spherical shell. The shell has a subwavelength nanoaperture believed to excite stationary plasmon resonances at the biosensor's surface. The sub-micron cavity enhances the measurement sensitivity of molecules binding to the sensor surface. We used visible-range optical spectroscopy to study the wavelength shift as bio-molecules absorbed-desorbed at the shell surface. We also used Scanning Electron Microscopy (SEM) and Focused Ion Beam (FIB) ablation to study the characteristics of microcavity surface plasmon resonance sensor (MSPRS) and the inner structure formed with metal deposition and its spectrum. We found that resonances at 580 nm and 670 nm responded to bound test agents and that Surface Plasmon Resonance (SPR) sensor intensity could be used to differentiate between D-glucose and L-glucose. The responsiveness of the system depended upon the mechanical integrity of the metallic surface coating.

Recombination of open-f-shell tungsten ions

NASA Astrophysics Data System (ADS)

Krantz, C.; Badnell, N. R.; Müller, A.; Schippers, S.; Wolf, A.

2017-03-01

We review experimental and theoretical efforts aimed at a detailed understanding of the recombination of electrons with highly charged tungsten ions characterised by an open 4f sub-shell. Highly charged tungsten occurs as a plasma contaminant in ITER-like tokamak experiments, where it acts as an unwanted cooling agent. Modelling of the charge state populations in a plasma requires reliable thermal rate coefficients for charge-changing electron collisions. The electron recombination of medium-charged tungsten species with open 4f sub-shells is especially challenging to compute reliably. Storage-ring experiments have been conducted that yielded recombination rate coefficients at high energy resolution and well-understood systematics. Significant deviations compared to simplified, but prevalent, computational models have been found. A new class of ab initio numerical calculations has been developed that provides reliable predictions of the total plasma recombination rate coefficients for these ions.

IMPACT OF NEW GAMOW–TELLER STRENGTHS ON EXPLOSIVE TYPE IA SUPERNOVA NUCLEOSYNTHESIS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mori, Kanji; Famiano, Michael A.; Kajino, Toshitaka

2016-12-20

Recent experimental results have confirmed a possible reduction in the Gamow–Teller (GT{sub +}) strengths of pf-shell nuclei. These proton-rich nuclei are of relevance in the deflagration and explosive burning phases of SNe Ia. While prior GT strengths result in nucleosynthesis predictions with a lower-than-expected electron fraction, a reduction in the GT{sub +} strength can result in a slightly increased electron fraction compared to previous shell model predictions, though the enhancement is not as large as previous enhancements in going from rates computed by Fuller, Fowler, and Newman based on an independent particle model. A shell model parametrization has been developed thatmore » more closely matches experimental GT strengths. The resultant electron-capture rates are used in nucleosynthesis calculations for carbon deflagration and explosion phases of SNe Ia, and the final mass fractions are compared to those obtained using more commonly used rates.« less

LOW MACH NUMBER MODELING OF CONVECTION IN HELIUM SHELLS ON SUB-CHANDRASEKHAR WHITE DWARFS. II. BULK PROPERTIES OF SIMPLE MODELS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacobs, A. M.; Zingale, M.; Nonaka, A.

2016-08-10

The dynamics of helium shell convection driven by nuclear burning establish the conditions for runaway in the sub-Chandrasekhar-mass, double-detonation model for SNe Ia, as well as for a variety of other explosive phenomena. We explore these convection dynamics for a range of white dwarf core and helium shell masses in three dimensions using the low Mach number hydrodynamics code MAESTRO. We present calculations of the bulk properties of this evolution, including time-series evolution of global diagnostics, lateral averages of the 3D state, and the global 3D state. We find a variety of outcomes, including quasi-equilibrium, localized runaway, and convective runaway.more » Our results suggest that the double-detonation progenitor model is promising and that 3D dynamic convection plays a key role.« less

Low Mach Number Modeling of Convection in Helium Shells on Sub-Chandrasekhar White Dwarfs. II. Bulk Properties of Simple Models

DOE PAGES

Jacobs, A. M.; Zingale, M.; Nonaka, A.; ...

2016-08-10

The dynamics of helium shell convection driven by nuclear burning establish the conditions for runaway in the sub-Chandrasekhar-mass, double-detonation model for SNe Ia, as well as for a variety of other explosive phenomena. In this paper, we explore these convection dynamics for a range of white dwarf core and helium shell masses in three dimensions using the low Mach number hydrodynamics code MAESTRO. We present calculations of the bulk properties of this evolution, including time-series evolution of global diagnostics, lateral averages of the 3D state, and the global 3D state. We find a variety of outcomes, including quasi-equilibrium, localized runaway,more » and convective runaway. Finally, our results suggest that the double-detonation progenitor model is promising and that 3D dynamic convection plays a key role.« less

BPS magnetic monopole bags

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Ki-Myeong; Weinberg, Erick J.; Physics Department, Columbia University, New York, New York 10027

2009-01-15

We explore the characteristics of spherical bags made of large numbers of BPS magnetic monopoles. There are two extreme limits. In the Abelian bag, N zeros of the Higgs field are arranged in a quasiregular lattice on a sphere of radius R{sub cr}{approx}N/v, where v is the Higgs vacuum expectation value. The massive gauge fields of the theory are largely confined to a thin shell at this radius that separates an interior with almost vanishing magnetic and Higgs fields from an exterior region with long-range Coulomb magnetic and Higgs fields. In the other limiting case, which we term a non-Abelianmore » bag, the N zeros of the Higgs field are all the origin, but there is again a thin shell of radius R{sub cr}. In this case the region enclosed by this shell can be viewed as a large monopole core, with small Higgs field but nontrivial massive and massless gauge fields.« less

50 CFR 660.360 - Recreational fishery-management measures.

Code of Federal Regulations, 2011 CFR

2011-10-01

... authorized for recreational fishing are hook-and-line and spear. Spears may be propelled by hand or by... when the closure is in effect. The closure is not in effect at this time. This closure may be imposed... when the closure is in effect. The closure is not in effect at this time. This closure may be imposed...

50 CFR 660.360 - Recreational fishery-management measures.

Code of Federal Regulations, 2012 CFR

2012-10-01

... authorized for recreational fishing are hook-and-line and spear. Spears may be propelled by hand or by... when the closure is in effect. The closure is not in effect at this time. This closure may be imposed... when the closure is in effect. The closure is not in effect at this time. This closure may be imposed...

THE LAST MINUTES OF OXYGEN SHELL BURNING IN A MASSIVE STAR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Müller, Bernhard; Viallet, Maxime; Janka, Hans-Thomas

We present the first  4 π– three-dimensional (3D) simulation of the last minutes of oxygen shell burning in an 18 M {sub ⊙} supernova progenitor up to the onset of core collapse. A moving inner boundary is used to accurately model the contraction of the silicon and iron core according to a one-dimensional stellar evolution model with a self-consistent treatment of core deleptonization and nuclear quasi-equilibrium. The simulation covers the full solid angle to allow the emergence of large-scale convective modes. Due to core contraction and the concomitant acceleration of nuclear burning, the convective Mach number increases to ∼0.1 at collapse,more » and an ℓ  = 2 mode emerges shortly before the end of the simulation. Aside from a growth of the oxygen shell from 0.51 M {sub ⊙} to 0.56 M {sub ⊙} due to entrainment from the carbon shell, the convective flow is reasonably well described by mixing-length theory, and the dominant scales are compatible with estimates from linear stability analysis. We deduce that artificial changes in the physics, such as accelerated core contraction, can have precarious consequences for the state of convection at collapse. We argue that scaling laws for the convective velocities and eddy sizes furnish good estimates for the state of shell convection at collapse and develop a simple analytic theory for the impact of convective seed perturbations on shock revival in the ensuing supernova. We predict a reduction of the critical luminosity for explosion by 12% – 24% due to seed asphericities for our 3D progenitor model relative to the case without large seed perturbations.« less

THE HYDRODYNAMICAL MODELS OF THE COMETARY COMPACT H ii REGION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Feng-Yao; Zhu, Qing-Feng; Li, Juan

2015-10-10

We have developed a full numerical method to study the gas dynamics of cometary ultracompact H ii regions, and associated photodissociation regions (PDRs). The bow-shock and champagne-flow models with a 40.9/21.9 M{sub ⊙} star are simulated. In the bow-shock models, the massive star is assumed to move through dense (n = 8000 cm{sup −3}) molecular material with a stellar velocity of 15 km s{sup −1}. In the champagne-flow models, an exponential distribution of density with a scale height of 0.2 pc is assumed. The profiles of the [Ne ii] 12.81 μm and H{sub 2} S(2) lines from the ionized regionsmore » and PDRs are compared for two sets of models. In champagne-flow models, emission lines from the ionized gas clearly show the effect of acceleration along the direction toward the tail due to the density gradient. The kinematics of the molecular gas inside the dense shell are mainly due to the expansion of the H ii region. However, in bow-shock models the ionized gas mainly moves in the same direction as the stellar motion. The kinematics of the molecular gas inside the dense shell simply reflects the motion of the dense shell with respect to the star. These differences can be used to distinguish two sets of models.« less

Design and fabrication of a boron reinforced intertank skirt

NASA Technical Reports Server (NTRS)

Henshaw, J.; Roy, P. A.; Pylypetz, P.

1974-01-01

Analytical and experimental studies were performed to evaluate the structural efficiency of a boron reinforced shell, where the medium of reinforcement consists of hollow aluminum extrusions infiltrated with boron epoxy. Studies were completed for the design of a one-half scale minimum weight shell using boron reinforced stringers and boron reinforced rings. Parametric and iterative studies were completed for the design of minimum weight stringers, rings, shells without rings and shells with rings. Computer studies were completed for the final evaluation of a minimum weight shell using highly buckled minimum gage skin. The detail design is described of a practical minimum weight test shell which demonstrates a weight savings of 30% as compared to an all aluminum longitudinal stiffened shell. Sub-element tests were conducted on representative segments of the compression surface at maximum stress and also on segments of the load transfer joint. A 10 foot long, 77 inch diameter shell was fabricated from the design and delivered for further testing.

H{sub 2} MOLECULAR CLUSTERS WITH EMBEDDED MOLECULES AND ATOMS AS THE SOURCE OF THE DIFFUSE INTERSTELLAR BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernstein, L. S.; Clark, F. O.; Lynch, D. K., E-mail: larry@spectral.com, E-mail: dave@thulescientific.com

2013-05-01

We suggest that the diffuse interstellar bands (DIBs) arise from absorption lines of electronic transitions in molecular clusters primarily composed of a single molecule, atom, or ion ({sup s}eed{sup )}, embedded in a single-layer shell of H{sub 2} molecules. Less abundant variants of the cluster, including two seed molecules and/or a two-layer shell of H{sub 2} molecules, may also occur. The lines are broadened, blended, and wavelength-shifted by interactions between the seed and surrounding H{sub 2} shell. We refer to these clusters as contaminated H{sub 2} clusters (CHCs). We show that CHC spectroscopy matches the diversity of observed DIB spectralmore » profiles and provides good fits to several DIB profiles based on a rotational temperature of 10 K. CHCs arise from {approx}centimeter-sized, dirty H{sub 2} ice balls, called contaminated H{sub 2} ice macro-particles (CHIMPs), formed in cold, dense, giant molecular clouds (GMCs), and later released into the interstellar medium (ISM) upon GMC disruption. Attractive interactions, arising from Van der Waals and ion-induced dipole potentials, between the seeds and H{sub 2} molecules enable CHIMPs to attain centimeter-sized dimensions. When an ultraviolet (UV) photon is absorbed in the outer layer of a CHIMP, it heats the icy matrix and expels CHCs into the ISM. While CHCs are quickly destroyed by absorbing UV photons, they are replenished by the slowly eroding CHIMPs. Since CHCs require UV photons for their release, they are most abundant at, but not limited to, the edges of UV-opaque molecular clouds, consistent with the observed, preferred location of DIBs. An inherent property of CHCs, which can be characterized as nanometer size, spinning, dipolar dust grains, is that they emit in the radio-frequency region. We also show that the CHCs offer a natural explanation for the anomalous microwave emission feature in the {approx}10-100 GHz spectral region.« less

Effects of magnetic field treatment on dielectric properties of CCTO@Ni/PVDF composite with low concentration of ceramic fillers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chi, Q. G., E-mail: qgchi@hotmail.com, E-mail: empty-cy@l63.com; State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049; Gao, L.

2015-11-15

Using melt mixing, we produced a ceramic/polymer composite with a matrix of polyvinylidene fluoride (PVDF) and a filler of 5 vol.% Ni-deposited CaCu{sub 3}Ti{sub 4}O{sub 12} core-shell ceramic particles (CCTO@Ni), and studied its prominent dielectric characteristics for the first. Its phase composition and morphology were analyzed by X-ray diffraction and scanning electron microscopy, respectively. After treating the composite films with various durations of a magnetic field treatment, we compared their dielectric properties. We found that the CCTO@Ni ceramic had a typical urchin-like core-shell structure, and that different durations of the magnetic field treatment produced different distributions of ceramic particles inmore » the PVDF matrix. The dielectric permittivity of the untreated CCTO@Ni/PVDF composite was 20% higher than that of neat PVDF, and it had a low loss tangent. However, only the composite treated for 30 min in the magnetic field had an ultra-high dielectric permittivity of 1.41 × 10{sup 4} at 10 Hz, three orders of magnitude higher than the untreated composite, which declined dramatically with increasing frequency, accompanied by an insulating-conducting phase transition and an increase in loss tangent. Our results demonstrate that changes in the dielectric properties of PVDF composites with magnetic field treatment are closely related to the percolation effect and interfacial polarization.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flores-Tlalpa, A.; Novales-Sanchez, H.; Toscano, J. J.

The one-loop contribution of the excited Kaluza-Klein (KK) modes of the SU{sub L}(2) gauge group on the off-shell W{sup -}W{sup +}{gamma} and W{sup -}W{sup +}Z vertices is calculated in the context of a pure Yang-Mills theory in five dimensions and its phenomenological implications discussed. The use of a gauge-fixing procedure for the excited KK modes that is covariant under the standard gauge transformations of the SU{sub L}(2) group is stressed. A gauge-fixing term and the Faddeev-Popov ghost sector for the KK gauge modes that are separately invariant under the standard gauge transformations of SU{sub L}(2) are presented. It is shownmore » that the one-loop contributions of the KK modes to the off-shell W{sup -}W{sup +}{gamma} and W{sup -}W{sup +}Z vertices are free of ultraviolet divergences and well-behaved at high energies. It is found that for a size of the fifth dimension of R{sup -1{approx}}1 TeV, the one-loop contribution of the KK modes to these vertices is about 1 order of magnitude lower than the corresponding standard model radiative correction. This contribution is similar to the one estimated for new gauge bosons contributions in other contexts. Tree-level effects on these vertices induced by operators of higher canonical dimension are also investigated. It is found that these effects are lower than those generated at the one-loop order by the KK gauge modes.« less

Metabotropic glutamate receptor modulation of dopamine release in the nucleus accumbens shell is unaffected by phencyclidine pretreatment: In vitro assessment using fast-scan cyclic voltammetry rat brain slices.

PubMed

Gupta, Ishan; Young, Andrew M J

2018-05-15

The non-competitive glutamate antagonist, phencyclidine is used in rodents to model behavioural deficits see in schizophrenia. Importantly, these deficits endure long after the cessation of short-term chronic treatment (sub-chronic), indicating that the drug treatment causes long-term changes in the physiology and/or chemistry of the brain. There is evidence that this may occur through glutamatergic modulation of mesolimbic dopamine release, perhaps involving metabotropic glutamate receptors (mGluR). This study sought to investigate the effect of sub-chronic phencyclidine pretreatment on modulation of dopamine neurotransmission by metabotropic glutamate receptors 2 and 5 (mGluR2 and mGluR5) in the nucleus accumbens shell in vitro, with the hypothesis that phencyclidine pretreatment would disrupt the mGluR-mediated modulation of dopamine release. We showed that the orthosteric mGluR2 agonist LY379268 (0.1 µM, 1 µM and 10 µM) and mGluR5 positive allosteric modulator CDPPB (1 µM and 10 µM) both attenuated potassium-evoked dopamine release, underscoring their role in modulating dopamine neurotransmission in the nucleus accumbens. Sub-chronic PCP treatment, which caused cognitive deficits measured by performance in the novel object recognition task, modelling aspects of behavioral deficits seen in schizophrenia, induced neurobiological changes that enhanced dopamine release in the nucleus accumbens, but had no effect on mGluR2 or mGluR5 mediated changes in dopamine release. Therefore it is unlikely that schizophrenia-related behavioural changes seen after sub-chronic phencyclidine pre-treatment are mediated through mGluR modulation of dopamine release. Copyright © 2018 Elsevier B.V. All rights reserved.

Fracture Mechanics Analysis of Stitched Stiffener-Skin Debonding

NASA Technical Reports Server (NTRS)

Glaessgen, E. H.; Raju, I. S.; Poe, C. C., Jr.

1998-01-01

An analysis based on plate finite elements and the virtual crack closure technique has been implemented to study the effect of stitching on mode I and mode II strain energy release rates for debond configurations. The stitches were modeled as discrete nonlinear fastener elements with a compliance determined by experiment. The axial and shear behavior of the stitches was considered, however, the two compliances and failure loads were assumed to be independent. Both a double cantilever beam (mode I) and a mixed mode skin-stiffener debond configuration were studied. In the double cantilever beam configurations, G(sub I) began to decrease once the debond had grown beyond the first row of stitches and was reduced to zero for long debonds. In the mixed-mode skin-stiffener configurations, G(sub I) showed a similar behavior as in the double cantilever beam configurations, however, G(sub u), continued to increase with increasing debond length.

Halogenation effects on electron collisions with CF{sub 3}Cl, CF{sub 2}Cl{sub 2}, and CFCl{sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Freitas, T. C., E-mail: tcf03@fisica.ufpr.br; Lopes, A. R.; Bettega, M. H. F.

2016-04-28

We report differential and integral elastic cross sections for low-energy electron collisions with CF{sub 3}Cl, CF{sub 2}Cl{sub 2}, and CFCl{sub 3} molecules for energies ranging from 0.1 eV to 30 eV. The calculations were performed using the Schwinger multichannel method with pseudopotentials in the static-exchange and static-exchange plus polarization approximations. The influence of the permanent electric dipole moment on the cross sections was included using the Born closure scheme. A very good agreement between our calculations and the experimental results of Jones [J. Chem. Phys. 84, 813 (1986)], Mann and Linder [J. Phys. B 25, 1621 (1992); 25, 1633 (1992)]more » and Hoshino et al. [J. Chem. Phys. 138, 214305 (2013)] was found. We also compare our results with the calculations of Beyer et al. [Chem. Phys. 255, 1 (2000)] using the R-matrix method, where we find good agreement with respect to the location of the resonances, and with the calculations of Hoshino et al. using the independent atom method with screening corrected additivity rule, where we find qualitative agreement at energies above 20 eV. Additional electronic structure calculations were carried out in order to help in the interpretation of the scattering results. The stabilization the lowest σ{sup ∗} resonance due to the exchange of fluorine by chlorine atoms (halogenation effect) follows a simple linear relation with the energy of the lowest unoccupied molecular orbitals and can be considered as a signature of the halogenation effect.« less

A comprehensive alpha-heating model for inertial confinement fusion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Christopherson, A. R.; Betti, R.; Bose, A.

In this paper, a comprehensive model is developed to study alpha-heating in inertially confined plasmas. It describes the time evolution of a central low-density hot spot confined by a compressible shell, heated by fusion alphas, and cooled by radiation and thermal losses. The model includes the deceleration, stagnation, and burn phases of inertial confinement fusion implosions, and is valid for sub-ignited targets with ≤10× amplification of the fusion yield from alpha-heating. The results of radiation-hydrodynamic simulations are used to derive realistic initial conditions and dimensionless parameters for the model. It is found that most of the alpha energy (~90%) producedmore » before bang time is deposited within the hot spot mass, while a small fraction (~10%) drives mass ablation off the inner shell surface and its energy is recycled back into the hot spot. Of the bremsstrahlung radiation emission, ~40% is deposited in the hot spot, ~40% is recycled back in the hot spot by ablation off the shell, and ~20% leaves the hot spot. We show here that the hot spot, shocked shell, and outer shell trajectories from this analytical model are in good agreement with simulations. Finally, a detailed discussion of the effect of alpha-heating on the hydrodynamics is also presented.« less

A comprehensive alpha-heating model for inertial confinement fusion

NASA Astrophysics Data System (ADS)

Christopherson, A. R.; Betti, R.; Bose, A.; Howard, J.; Woo, K. M.; Campbell, E. M.; Sanz, J.; Spears, B. K.

2018-01-01

A comprehensive model is developed to study alpha-heating in inertially confined plasmas. It describes the time evolution of a central low-density hot spot confined by a compressible shell, heated by fusion alphas, and cooled by radiation and thermal losses. The model includes the deceleration, stagnation, and burn phases of inertial confinement fusion implosions, and is valid for sub-ignited targets with ≤10 × amplification of the fusion yield from alpha-heating. The results of radiation-hydrodynamic simulations are used to derive realistic initial conditions and dimensionless parameters for the model. It is found that most of the alpha energy (˜90%) produced before bang time is deposited within the hot spot mass, while a small fraction (˜10%) drives mass ablation off the inner shell surface and its energy is recycled back into the hot spot. Of the bremsstrahlung radiation emission, ˜40% is deposited in the hot spot, ˜40% is recycled back in the hot spot by ablation off the shell, and ˜20% leaves the hot spot. We show here that the hot spot, shocked shell, and outer shell trajectories from this analytical model are in good agreement with simulations. A detailed discussion of the effect of alpha-heating on the hydrodynamics is also presented.

A comprehensive alpha-heating model for inertial confinement fusion

DOE PAGES

Christopherson, A. R.; Betti, R.; Bose, A.; ...

2018-01-08

In this paper, a comprehensive model is developed to study alpha-heating in inertially confined plasmas. It describes the time evolution of a central low-density hot spot confined by a compressible shell, heated by fusion alphas, and cooled by radiation and thermal losses. The model includes the deceleration, stagnation, and burn phases of inertial confinement fusion implosions, and is valid for sub-ignited targets with ≤10× amplification of the fusion yield from alpha-heating. The results of radiation-hydrodynamic simulations are used to derive realistic initial conditions and dimensionless parameters for the model. It is found that most of the alpha energy (~90%) producedmore » before bang time is deposited within the hot spot mass, while a small fraction (~10%) drives mass ablation off the inner shell surface and its energy is recycled back into the hot spot. Of the bremsstrahlung radiation emission, ~40% is deposited in the hot spot, ~40% is recycled back in the hot spot by ablation off the shell, and ~20% leaves the hot spot. We show here that the hot spot, shocked shell, and outer shell trajectories from this analytical model are in good agreement with simulations. Finally, a detailed discussion of the effect of alpha-heating on the hydrodynamics is also presented.« less

Growth And Gas Sensing Properties Of Dielectrophoretically Isolated CuO-W{sub 18}O{sub 49} Heterostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jain, Chhavi; Mukund, Vignesh; Kaur, Manmeet

2010-12-01

Hierarchical heterostructures consisting of W{sub 18}O{sub 49} nanowires grown on CuO nanowires have been prepared and studied for their gas sensing properties. SEM images show that W{sub 18}O{sub 49} initially grow as an shell over core CuO nanowire with protusion like branches whose thickness depends on oxygen partial pressure. These CuO:W{sub 18}O{sub 49} structures were dielectrophoretically isolated and studied for their gas sensing properties. The results show potential of use of tailored hierarchical heterostructures for the fabrication of gas sensors.

Diamagnetic susceptibility of a hydrogenic donor in a group IV-VI quantum dot-quantum well heterostructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saravanamoorthy, S. N.; Peter, A. John, E-mail: a.john.peter@gmail.com

2016-05-23

Electronic properties of a hydrogenic donor impurity in a CdSe/Pb{sub 0.8}Cd{sub 0.2}Se/CdSe quantum dot quantum well system are investigated for various radii of core with shell materials. Confined energies are obtained taking into account the geometrical size of the system and thereby the donor binding energies are found. The diamagnetic susceptibility is estimated for a confined shallow donor in the well system. The results show that the diamagnetic susceptibility strongly depends on core and shell radii and it is more sensitive to variations of the geometrical size of the well material.

Au@Y 2O 3:Eu 3+ rare earth oxide hollow sub-microspheres with encapsulated gold nanoparticles and their optical properties

NASA Astrophysics Data System (ADS)

Min, Yu-Lin; Wan, Yong; Yu, Shu-Hong

2009-01-01

A facile method to synthesize novel Au@Y 2O 3:Eu 3+ hollow sub-microspheres encapsulated with moveable gold nanoparticle core and Y 2O 3:Eu 3+ as shell via two-step coating processes and a succeeding calcination process has been developed. Silica coating on citrate-stabilized gold nanoparticles with a size of 25 nm can be obtained through a slightly modified Stöber process. Gold particles coated with double shell silica and Eu doped Y(OH) 3 can be obtained by coating on the Au@SiO 2 spheres through simply adding Y(NO 3) 3, Eu(NO 3) 3 and an appropriate quantity of NH 3·H 2O. Au@Y 2O 3:Eu 3+ hollow sub-microspheres with moveable individual Au nanoparticle as core can be obtained after calcination of Au@Y 2O 3:Eu 3+ particles at 600 °C for 2 h. These new core-shell structures with encapsulated gold nanoparticles have combined optical properties of both the Au nanoparticles and the Y 2O 3:Eu 3+ phosphor materials which might have potential applications.

Debond Analyses for Stitched Composite Structures

NASA Technical Reports Server (NTRS)

Glaessgen, E. H.; Raju, I. S.; Poe, C. C., Jr.

1998-01-01

The effect of stitching on mode I and mode II strain energy release rates for debond configurations is studied using an analysis based on plate finite elements and the virtual crack closure technique. The stitches were modeled as discrete nonlinear fastener elements with a compliance determined by experiment. The axial and shear behavior of the stitches was considered with both the compliances and failure loads assumed to be independent. The mode I strain energy release rate, G(sub I), was shown to decrease once the debond had grown beyond the first row of stitches and was reduced to zero for long debonds, however, the mode II strain energy release rate, G(sub II), continued to be of significant magnitude over the range of debond lengths considered.

Influence of surface morphology and UFG on damping and mechanical properties of composite reinforced with spinel MgAl{sub 2}O{sub 4}-SiC core-shell microcomposites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Subhash; Pal, Kaushik, E-mail: pl_kshk@yaho

Interface between ceramic particulate and matrix is known to control the response of the materials and functionality of the composite. Among numerous physical properties, grain structure of the materials has also played a significant role in defining the behaviour of metal matrix composites. Usually, silicon carbide (SiC) particles show poor interfacial wettability in aluminium melt. Herein, we were successfully synthesized magnesium oxide (MgO) and nanocrystalline magnesium aluminate (MgAl{sub 2}O{sub 4}) spinel coated silicon carbide (SiC) core-shell micro-composites through sol-gel technique to improve the wettability of dispersoids. Core-shell structures of submicron size were thoroughly investigated by various characterization techniques. Further, aluminiummore » matrix composites incorporated with pristine SiC, MgO grafted SiC and MgAl{sub 2}O{sub 4} grafted SiC particles were fabricated by stir casting technique, respectively. Additionally, as-cast composites were processed via friction stir processing (FSP) technique to observe the influence of grain refinement on mechanical and damping properties. Electron back scattered diffraction (EBSD), Field emission scanning electron microscopy (FE-SEM) and X-ray energy dispersion spectroscopy (EDX) analysis were conducted for investigating grain size refinement, adequate dispersion, stability and de-agglomeration of encapsulated SiC particles in aluminium matrix. The mechanical as well as thermal cyclic (from − 100 to 400 °C) damping performance of the as-cast and friction stir processed composites were studied, respectively. Finally, the enhanced properties were attributable to reduced agglomeration, stabilization and proper dispersion of the tailored SiC particles Al matrix. - Highlights: •Synthesizing a novel coating layer of MgO and MgAl{sub 2}O{sub 4} spinel onto SiC particles •Significant improvement in UTS and hardness by reinforcing tailored SiC in Al •Significant grain refinements were obtained through FSP •SiC/MgAl{sub 2}O{sub 4}/Al exhibits ~ 61% higher storage modulus as compare to pure Al after FSP.« less

Study of near-stability nuclei populated as fission fragments in heavy-ion fusion reactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fotiadis, Nikolaos; Nelson, Ronald O; Devlin, Matthew

2010-01-01

Examples are presented to illustrate the power of prompt {gamma}-ray spectroscopy of fission fragments from compound nuclei with A {approx} 200 formed in fusion-evaporation reactions in experiments using the Gammasphere Ge-detector array. Complementary methods, such as Coulomb excitation and deep-inelastic processes, are also discussed. In other cases (n, xn{gamma}) reactions on stable isotopes have been used to establish neutron excitation functions for {gamma}-rays using a pulsed 'white'-neutron source, coupled to a high-energy-resolution germanium-detector array. The excitation functions can unambiguously assign {gamma}-rays to a specific reaction product. Results from all these methods bridge the gaps in the systematics of high-spin statesmore » between the neutron-deficient and neutron-rich nuclei. Results near shell closures should motivate new shell model calculations.« less

Assessment of dynamic closure for premixed combustion large eddy simulation

NASA Astrophysics Data System (ADS)

Langella, Ivan; Swaminathan, Nedunchezhian; Gao, Yuan; Chakraborty, Nilanjan

2015-09-01

Turbulent piloted Bunsen flames of stoichiometric methane-air mixtures are computed using the large eddy simulation (LES) paradigm involving an algebraic closure for the filtered reaction rate. This closure involves the filtered scalar dissipation rate of a reaction progress variable. The model for this dissipation rate involves a parameter βc representing the flame front curvature effects induced by turbulence, chemical reactions, molecular dissipation, and their interactions at the sub-grid level, suggesting that this parameter may vary with filter width or be a scale-dependent. Thus, it would be ideal to evaluate this parameter dynamically by LES. A procedure for this evaluation is discussed and assessed using direct numerical simulation (DNS) data and LES calculations. The probability density functions of βc obtained from the DNS and LES calculations are very similar when the turbulent Reynolds number is sufficiently large and when the filter width normalised by the laminar flame thermal thickness is larger than unity. Results obtained using a constant (static) value for this parameter are also used for comparative evaluation. Detailed discussion presented in this paper suggests that the dynamic procedure works well and physical insights and reasonings are provided to explain the observed behaviour.

An Optimal Parametrization of Turbulent Scales

NASA Astrophysics Data System (ADS)

Thalabard, S.

2015-12-01

To numerically capture the large-scale dynamics of atmospheric flows, geophysicists need to rely on reasonable parametrizations of the energy transfers to and from the non-resolved small scale eddies, mediated through turbulence. The task is notoriously not trivial, and is typically solved by ingenious but ad-hoc elaborations on the concept of eddy viscosities. The difficulty is tied into the intrinsic Non-Gaussianity of turbulence, a feature that may explain why standard Quasi-Normal cumulant discard statistical closure strategies can fail dramatically, an example being the development of negative energy spectra in Millionshtchikov's 1941 Quasi-Normal (QN) theory. While Orszag's 1977 Eddy Damped Quasi Normal Markovian closure (EDQNM) provides an ingenious patch to the issue, the reason why the QN theory fails so badly is not so clear. Are closures necessarily either trivial or ad-hoc, when proxies for true ensemble averages are taken to be Gaussian ? The purpose of the talk is to answer negatively, using the lights of a new ``optimal closure framework'' recently exposed by [Turkington,2013]. For turbulence problems, the optimal closure allows a consistent use of a Gaussian Ansatz (and corresponding vanishing third cumulant) that also retains an intrinsic damping. The key to this apparent paradox lies in a clear distinction between the true ensemble averages and their proxies, most easily grasped provided one uses the Liouville equation as a starting point, rather than the cumulant hierarchy. Schematically said, closure is achieved by minimizing a lack-of-fit residual, which retains the intrinsic features of the true dynamics. The optimal closure is not restricted to the Gaussian modeling. Yet, for the sake of clarity, I will discuss the optimal closure on a problem where it can be entirely implemented, and compared to DNS : the relaxation of an arbitrarily far from equilibrium energy shell towards the Gibbs equilibrium for truncated Euler dynamics. Predictive insights are obtained, among which a non-trivial universal relaxation profile for the inverse temperatures (see associated figure). It is associated to a non-standard dissipation operator responsible for the turbulent damping, possibly relevant for atmospheric dynamics.

EPR Investigation of Gamma-Irradiated Rapana Thomasiana (Gastropoda, Muricidae) Shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seletchi, Emilia Dana; Duliu, Octavian G.; Georgescu, Rodica

2007-04-23

The shell of Rapana Thomasiana snail, a carnivorous gastropod collected from the coasts of the Black Sea (Romania) was investigated by using Electron Paramagnetic Resonance (EPR) spectroscopy. The samples in powder form were irradiated with a 60Co gamma-ray source at ambient temperature in the dose range between 1.06 and 11.3 kGy. The measurements showed that the EPR signal intensity enhanced following saturation exponential with the absorbed dose. The estimated EPR parameters: g1 = 1.9976, g2 = 2.0006, g3 = 2.0015, g4 = 2.0030 and g5 = 2.0043 revealed a complex spectrum consisting of CO{sub 2}{sup -}, CO{sub 3}{sup 3-} andmore » CO{sub 3}{sup -} species. A very weak signal at g6 = 2.0057 was associated to SO{sub 2}{sup -} electron center. All EPR signals of gamma-irradiated samples decreased with various rate with the of 100 deg. C isothermal annealing time.« less

Shortest recurrence periods of novae

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kato, Mariko; Saio, Hideyuki; Hachisu, Izumi

Stimulated by the recent discovery of the 1 yr recurrence period nova M31N 2008-12a, we examined the shortest recurrence periods of hydrogen shell flashes on mass-accreting white dwarfs (WDs). We discuss the mechanism that yields a finite minimum recurrence period for a given WD mass. Calculating the unstable flashes for various WD masses and mass accretion rates, we identified a shortest recurrence period of about two months for a non-rotating 1.38 M {sub ☉} WD with a mass accretion rate of 3.6 × 10{sup –7} M {sub ☉} yr{sup –1}. A 1 yr recurrence period is realized for very massivemore » (≳ 1.3 M {sub ☉}) WDs with very high accretion rates (≳ 1.5 × 10{sup –7} M {sub ☉} yr{sup –1}). We revised our stability limit of hydrogen shell burning, which will be useful for binary evolution calculations toward Type Ia supernovae.« less

Multifunctional nanoparticles as a tissue adhesive and an injectable marker for image-guided procedures

NASA Astrophysics Data System (ADS)

Shin, Kwangsoo; Choi, Jin Woo; Ko, Giho; Baik, Seungmin; Kim, Dokyoon; Park, Ok Kyu; Lee, Kyoungbun; Cho, Hye Rim; Han, Sang Ihn; Lee, Soo Hong; Lee, Dong Jun; Lee, Nohyun; Kim, Hyo-Cheol; Hyeon, Taeghwan

2017-07-01

Tissue adhesives have emerged as an alternative to sutures and staples for wound closure and reconnection of injured tissues after surgery or trauma. Owing to their convenience and effectiveness, these adhesives have received growing attention particularly in minimally invasive procedures. For safe and accurate applications, tissue adhesives should be detectable via clinical imaging modalities and be highly biocompatible for intracorporeal procedures. However, few adhesives meet all these requirements. Herein, we show that biocompatible tantalum oxide/silica core/shell nanoparticles (TSNs) exhibit not only high contrast effects for real-time imaging but also strong adhesive properties. Furthermore, the biocompatible TSNs cause much less cellular toxicity and less inflammation than a clinically used, imageable tissue adhesive (that is, a mixture of cyanoacrylate and Lipiodol). Because of their multifunctional imaging and adhesive property, the TSNs are successfully applied as a hemostatic adhesive for minimally invasive procedures and as an immobilized marker for image-guided procedures.

The Impact of Trampling on Reef Macrobenthos in Northeastern Brazil: How Effective are Current Conservation Strategies?

NASA Astrophysics Data System (ADS)

Santos, Gleice S.; Burgos, Douglas C.; Lira, Simone M. A.; Schwamborn, Ralf

2015-10-01

Tropical reefs are used for intensive tourism in various parts of the world. However, few studies have investigated the effect of regular trampling on these fragile ecosystems. The aim of this study was to assess the effect of different conservation strategies (open access, partial protection, and total long-term closure) on intertidal reef tops in Porto de Galinhas and Tamandaré, Pernambuco State, Brazil. Analysis of the macrobenthic community was performed with photo transects and image analysis (CPCe). Twenty-seven transects were surveyed from January to August 2012, in intensively impacted (I) open-access sites, in partially protected (P) sites with occasional, illegal trampling, and in a permanently closed (C) site. In I sites, total live cover was half the cover found in adjacent P sites. The area of bare rock averaged 53.6 and 25.0 % in I and P sites, respectively. In the C site, the area of bare rock was only 19.8 %. In I and P sites, macroalgae ( Palisada perforata) were dominating, while in the C site, the zoanthid Zoanthus sociatus was most abundant. Shell-bearing vermetids ( Petaloconchus varians) and bivalves ( Isognomon bicolor) were more abundant at the C site, being possible bioindicators for areas with zero or little trampling. Twelve years of total closure produced near-pristine communities in the C site, dominated by zoanthids and fragile mollusks. This study showed that trampling has severe and long-lasting consequences for the structure of these ecosystems.

The Impact of Trampling on Reef Macrobenthos in Northeastern Brazil: How Effective are Current Conservation Strategies?

PubMed

Santos, Gleice S; Burgos, Douglas C; Lira, Simone M A; Schwamborn, Ralf

2015-10-01

Tropical reefs are used for intensive tourism in various parts of the world. However, few studies have investigated the effect of regular trampling on these fragile ecosystems. The aim of this study was to assess the effect of different conservation strategies (open access, partial protection, and total long-term closure) on intertidal reef tops in Porto de Galinhas and Tamandaré, Pernambuco State, Brazil. Analysis of the macrobenthic community was performed with photo transects and image analysis (CPCe). Twenty-seven transects were surveyed from January to August 2012, in intensively impacted (I) open-access sites, in partially protected (P) sites with occasional, illegal trampling, and in a permanently closed (C) site. In I sites, total live cover was half the cover found in adjacent P sites. The area of bare rock averaged 53.6 and 25.0% in I and P sites, respectively. In the C site, the area of bare rock was only 19.8%. In I and P sites, macroalgae (Palisada perforata) were dominating, while in the C site, the zoanthid Zoanthus sociatus was most abundant. Shell-bearing vermetids (Petaloconchus varians) and bivalves (Isognomon bicolor) were more abundant at the C site, being possible bioindicators for areas with zero or little trampling. Twelve years of total closure produced near-pristine communities in the C site, dominated by zoanthids and fragile mollusks. This study showed that trampling has severe and long-lasting consequences for the structure of these ecosystems.

Reynolds stress closure in jet flows using wave models

NASA Technical Reports Server (NTRS)

Morris, Philip J.

1990-01-01

A collection of papers is presented. The outline of this report is as follows. Chapter three contains a description of a weakly nonlinear turbulence model that was developed. An essential part of the application of such a closure scheme to general geometry jets is the solution of the local hydrodynamic stability equation for a given jet cross-section. Chapter four describes the conformal mapping schemes used to map such geometries onto a simple computational domain. Chapter five describes a solution of a stability problem for circular, elliptic, and rectangular geometries. In chapter six linear models for the shock shell structure in non-circular jets is given. The appendices contain reprints of papers also published during this study including the following topics: (1) instability of elliptic jets; (2) a technique for predicting the shock cell structure in non-circular jets using a vortex sheet model; and (3) the resonant interaction between twin supersonic jets.

High-j neutron excitations outside 136Xe

NASA Astrophysics Data System (ADS)

Talwar, R.; Kay, B. P.; Mitchell, A. J.; Adachi, S.; Entwisle, J. P.; Fujita, Y.; Gey, G.; Noji, S.; Ong, H. J.; Schiffer, J. P.; Tamii, A.

2017-08-01

The ν 0 h9 /2 and ν 0 i13 /2 strength at 137Xe, a single neutron outside the N =82 shell closure, has been determined using the 136Xe(α ,3He)137Xe reaction carried out at 100 MeV. We confirm the recent observation of the second 13 /2+ state and reassess previous data on the 9 /2- states, obtaining spectroscopic factors. These new data provide additional constraints on predictions of the same single-neutron excitations at 133Sn.

Atomic radii for atoms with the 6s shell outermost: The effective atomic radius and the van der Waals radius from {sub 55}Cs to {sub 80}Hg

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tatewaki, Hiroshi, E-mail: htatewak@nsc.nagoya-cu.ac.jp; Institute of Advanced Studies in Artificial Intelligence, Chukyo University, Toyota, Aichi 470-0393; Hatano, Yasuyo

We consider, for atoms from {sub 55}Cs to {sub 80}Hg, the effective atomic radius (r{sub ear}), which is defined as the distance from the nucleus at which the magnitude of the electric field is equal to that in He at one half of the equilibrium bond length of He{sub 2}. The values of r{sub ear} are about 50% larger than the mean radius of the outermost occupied orbital of 6s, . The value of r{sub ear} decreases from {sub 55}Cs to {sub 56}Ba and undergoes increases and decreases with rising nuclear charge from {sub 57}La to {sub 70}Y b. Inmore » fact r{sub ear} is understood as comprising two interlaced sequences; one consists of {sub 57}La, {sub 58}Ce, and {sub 64}Gd, which have electronic configuration (4f{sup n−1})(5d{sup 1})(6s{sup 2}), and the remaining atoms have configuration (4f{sup n})(6s{sup 2}). The sphere defined by r{sub ear} contains 85%–90% of the 6s electrons. From {sub 71}Lu to {sub 80}Hg the radius r{sub ear} also involves two sequences, corresponding to the two configurations 5d{sup n+1}6s{sup 1} and 5d{sup n}6s{sup 2}. The radius r{sub ear} according to the present methodology is considerably larger than r{sub vdW} obtained by other investigators, some of who have found values of r{sub vdW} close to .« less

Copper detection in the Asiatic clam Corbicula fluminea: optimum valve closure response.

PubMed

Tran, Damien; Fournier, Elodie; Durrieu, Gilles; Massabuau, Jean-Charles

2004-02-25

When exposed to a contaminant, bivalves close their shell as a protective strategy. The aim of the present study was to estimate the maximum expected dissolved copper sensitivity in the freshwater bivalve Corbicula fluminea using a new approach to determine their potential and limit to detect contaminants. To take into account the rate of spontaneous closures, we integrated stress problems associated with fixation by a valve in usual valvometers and the spontaneous rhythm associated with nycthemeral activity, to optimize the response in conditions where the probability of spontaneous closing was lowest. Moreover, we used an original system with impedance valvometry, using lightweight impedance electrodes, to study free-ranging animals in low stress conditions combined with an analytical approach describing dose-response curves by logistic regression, with valve closure reaction as a function of response time and concentration of contaminant. In C. fluminea, we estimated that copper concentrations > 4 microg/l (95% confidence interval (CI95%), 2.3-8.8 microg/l) must be detected within 5 h after Cu addition. Lower values could not be distinguished from background noise. The threshold values were 2.5 times lower than the values reported in the literature.

Copper detection in the Asiatic clam Corbicula fluminea: optimum valve closure response.

PubMed

Tran, Damien; Fournier, Elodie; Durrieu, Gilles; Massabuau, Jean Charles

2003-11-19

When exposed to a contaminant, bivalves close their shell as a protective strategy. The aim of the present study was to estimate the maximum expected dissolved copper sensitivity in the freshwater bivalve Corbicula fluminea using a new approach to determine their potential and limit to detect contaminants. To take into account the rate of spontaneous closures, we integrated stress problems associated with fixation by a valve in usual valvometers and the spontaneous rhythm associated with nycthemeral activity, to optimize the response in conditions where the probability of spontaneous closing was lowest. Moreover, we used an original system with impedance valvometry, using lightweight impedance electrodes, to study free-ranging animals in low stress conditions combined with an analytical approach describing dose-response curves by logistic regression, with valve closure reaction as a function of response time and concentration of contaminant. In C. fluminea, we estimated that copper concentrations >4 microg/l (95% confidence interval (CI(95%)), 2.3-8.8 microg/l) must be detected within 5 h after Cu addition. Lower values could not be distinguished from background noise. The threshold values were 2.5 times higher than the values reported in the literature.

Role of projections from ventral subiculum to nucleus accumbens shell in context-induced reinstatement of heroin seeking in rats.

PubMed

Bossert, Jennifer M; Adhikary, Sweta; St Laurent, Robyn; Marchant, Nathan J; Wang, Hui-Ling; Morales, Marisela; Shaham, Yavin

2016-05-01

In humans, exposure to contexts previously associated with heroin use can provoke relapse. In rats, exposure to heroin-paired contexts after extinction of drug-reinforced responding in different contexts reinstates heroin seeking. We previously demonstrated that the projections from ventral medial prefrontal cortex (vmPFC) to nucleus accumbens (NAc) shell play a role in this reinstatement. The ventral subiculum (vSub) sends glutamate projections to NAc shell and vmPFC. Here, we determined whether these projections contribute to context-induced reinstatement. We trained rats to self-administer heroin (0.05-0.1 mg/kg/infusion) for 3 h per day for 12 days; drug infusions were paired with a discrete tone-light cue. Lever pressing in the presence of the discrete cue was subsequently extinguished in a different context. We then tested the rats for reinstatement in the heroin- and extinction-associated contexts under extinction conditions. We combined Fos with the retrograde tracer Fluoro-Gold (FG) to determine projection-specific activation during the context-induced reinstatement tests. We also used anatomical disconnection procedures to determine whether the vSub → NAc shell and vSub → vmPFC projections are functionally involved in this reinstatement. Exposure to the heroin but not the extinction context reinstated lever pressing. Context-induced reinstatement of heroin seeking was associated with increased Fos expression in vSub neurons, including those projecting to NAc shell and vmPFC. Anatomical disconnection of the vSub → NAc shell projection, but not the vSub → vmPFC projection, decreased this reinstatement. Our data indicate that the vSub → NAc shell glutamatergic projection, but not the vSub → vmPFC projection, contributes to context-induced reinstatement of heroin seeking.

Sub-grid scale models for discontinuous Galerkin methods based on the Mori-Zwanzig formalism

NASA Astrophysics Data System (ADS)

Parish, Eric; Duraisamy, Karthk

2017-11-01

The optimal prediction framework of Chorin et al., which is a reformulation of the Mori-Zwanzig (M-Z) formalism of non-equilibrium statistical mechanics, provides a framework for the development of mathematically-derived closure models. The M-Z formalism provides a methodology to reformulate a high-dimensional Markovian dynamical system as a lower-dimensional, non-Markovian (non-local) system. In this lower-dimensional system, the effects of the unresolved scales on the resolved scales are non-local and appear as a convolution integral. The non-Markovian system is an exact statement of the original dynamics and is used as a starting point for model development. In this work, we investigate the development of M-Z-based closures model within the context of the Variational Multiscale Method (VMS). The method relies on a decomposition of the solution space into two orthogonal subspaces. The impact of the unresolved subspace on the resolved subspace is shown to be non-local in time and is modeled through the M-Z-formalism. The models are applied to hierarchical discontinuous Galerkin discretizations. Commonalities between the M-Z closures and conventional flux schemes are explored. This work was supported in part by AFOSR under the project ''LES Modeling of Non-local effects using Statistical Coarse-graining'' with Dr. Jean-Luc Cambier as the technical monitor.

Buckling of circular cylindrical shells under dynamically applied axial loads

NASA Technical Reports Server (NTRS)

Tulk, J. D.

1972-01-01

A theoretical and experimental study was made of the buckling characteristics of perfect and imperfect circular cylindrical shells subjected to dynamic axial loading. Experimental data included dynamic buckling loads (124 data points), high speed photographs of buckling mode shapes and observations of the dynamic stability of shells subjected to rapidly applied sub-critical loads. A mathematical model was developed to describe the dynamic behavior of perfect and imperfect shells. This model was based on the Donnell-Von Karman compatibility and equilibrium equations and had a wall deflection function incorporating five separate modes of deflection. Close agreement between theory and experiment was found for both dynamic buckling strength and buckling mode shapes.

Finalizing the DTAG: Implementation and Testing of Design Improvements for Reliability and Availability

DTIC Science & Technology

2015-09-30

acoustics and fine scale motion. The success of the Dtag has resulted in an increased demand for the instrument from researchers both within the...sensor blocks sound when the animal is close to the surface. The polyethylene shell was eliminated in the Dtag-3 design to improve acoustic ...into 3 main sub-assemblies (Figure 5): 1) foam sub-assembly, 2) sensor sub-assembly, and 3) Electronics sub-assembly. This separation enables rapid

Measurement of the interference structure function R{sub LT} for the {sup 12}C(e,e{sup {prime}}p) reaction in the quasielastic region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holtrop, M.; Jordan, D.; McIlvain, T.

1998-12-01

The coincidence cross section and the interference structure function, R{sub LT}, were measured for the {sup 12}C(e,e{sup {prime}}p)thinsp{sup 11}B reaction at quasielastic kinematics and central momentum transfer of {vert_bar}{rvec q}{vert_bar}=400thinspMeV/c. The measurement was at an opening angle of {theta}{sub pq}=11{degree}, covering a range in missing energy of E{sub m}=0 to 65 MeV. The R{sub LT} structure function is found to be consistent with zero for E{sub m}{gt}50thinspMeV, confirming an earlier study which indicated that R{sub L} vanishes in this region. The integrated strengths of the p- and s-shell are compared with a distorted wave impulse approximation (DWIA) calculation. The s-shellmore » strength and shape are also compared with a Hartree Fock{endash}random phase approximation (HF-RPA) calculation. The DWIA calculation does not succeed in giving a consistent description of both the cross section data and the extracted R{sub LT} response for either shell. The HF-RPA calculation describes the data more consistently, which may be due to the inclusion of 2-body currents in this calculation. {copyright} {ital 1998} {ital The American Physical Society}« less

Effects of anisotropic electron-ion interactions in atomic photoelectron angular distributions

NASA Technical Reports Server (NTRS)

Dill, D.; Starace, A. F.; Manson, S. T.

1974-01-01

The photoelectron asymmetry parameter beta in LS-coupling is obtained as an expansion into contributions from alternative angular momentum transfers j sub t. The physical significance of this expansion of beta is shown to be that: (1) the electric dipole interaction transfers to the atom a charcteristic single angular momentum j sub t = sub o, where sub o is the photoelectron's initial orbital momentum; and (2) angular momentum transfers indicate the presence of anisotropic interaction of the outgoing photoelectron with the residual ion. For open shell atoms the photoelectron-ion interaction is generally anisotropic; photoelectron phase shifts and electric dipole matrix elements depend on both the multiplet term of the residual ion and the total orbital momentum of the ion-photoelectron final state channel. Consequently beta depends on the term levels of the residual ion and contains contributions from all allowed values of j sub t. Numerical calculations of the asymmetry parameters and partial cross sections for photoionization of atomic sulfur are presented.

Fatigue life and crack growth prediction methodology

NASA Technical Reports Server (NTRS)

Newman, J. C., Jr.; Phillips, E. P.; Everett, R. A., Jr.

1993-01-01

The capabilities of a plasticity-induced crack-closure model and life-prediction code to predict fatigue crack growth and fatigue lives of metallic materials are reviewed. Crack-tip constraint factors, to account for three-dimensional effects, were selected to correlate large-crack growth rate data as a function of the effective-stress-intensity factor range (delta(K(sub eff))) under constant-amplitude loading. Some modifications to the delta(K(sub eff))-rate relations were needed in the near threshold regime to fit small-crack growth rate behavior and endurance limits. The model was then used to calculate small- and large-crack growth rates, and in some cases total fatigue lives, for several aluminum and titanium alloys under constant-amplitude, variable-amplitude, and spectrum loading. Fatigue lives were calculated using the crack growth relations and microstructural features like those that initiated cracks. Results from the tests and analyses agreed well.

Computed tomography image using sub-terahertz waves generated from a high-T{sub c} superconducting intrinsic Josephson junction oscillator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kashiwagi, T., E-mail: kashiwagi@ims.tsukuba.ac.jp; Minami, H.; Kadowaki, K.

2014-02-24

A computed tomography (CT) imaging system using monochromatic sub-terahertz coherent electromagnetic waves generated from a device constructed from the intrinsic Josephson junctions in a single crystalline mesa structure of the high-T{sub c} superconductor Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+δ} was developed and tested on three samples: Standing metallic rods supported by styrofoam, a dried plant (heart pea) containing seeds, and a plastic doll inside an egg shell. The images obtained strongly suggest that this CT imaging system may be useful for a variety of practical applications.

Optical and structural properties of ensembles of colloidal Ag{sub 2}S quantum dots in gelatin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ovchinnikov, O. V., E-mail: Ovchinnikov-O-V@rambler.ru; Smirnov, M. S.; Shapiro, B. I.

2015-03-15

The size dependences of the absorption and luminescence spectra of ensembles of hydrophilic colloidal Ag{sub 2}S quantum dots produced by the sol-gel method and dispersed in gelatin are analyzed. By X-ray diffraction analysis and transmission electron microscopy, the formation of core/shell nanoparticles is detected. The characteristic feature of the nanoparticles is the formation of crystalline cores, 1.5–2.0 nm in dimensions, and shells of gelatin and its complexes with the components of synthesis. The observed slight size dependence of the position of infrared photoluminescence bands (in the range 1000–1400 nm) in the ensembles of hydrophilic colloidal Ag{sub 2}S quantum dots ismore » explained within the context of the model of the radiative recombination of electrons localized at structural and impurity defects with free holes.« less

Nb{sub 2}O{sub 5} hollow nanospheres as anode material for enhanced performance in lithium ion batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sasidharan, Manickam; Gunawardhana, Nanda; Yoshio, Masaki, E-mail: yoshio@cc.saga-u.ac.jp

2012-09-15

Graphical abstract: Nb{sub 2}O{sub 5} hollow nanosphere constructed electrode delivers high capacity of 172 mAh g{sup −1} after 250 cycles and maintains structural integrity and excellent cycling stability. Highlights: ► Nb{sub 2}O{sub 5} hollow nanospheres synthesis was synthesized by soft-template. ► Nb{sub 2}O{sub 5} hollow nanospheres were investigated as anode material in Li-ion battery. ► Nanostructured electrode delivers high capacity of 172 mAh g{sup −1} after 250 cycles. ► The electrode maintains the structural integrity and excellent cycling stability. ► Nanosized shell domain facilitates fast lithium intercalation/deintercalation. -- Abstract: Nb{sub 2}O{sub 5} hollow nanospheres of average diameter ca. ∼29 nmmore » and hollow cavity size ca. 17 nm were synthesized using polymeric micelles with core–shell–corona architecture under mild conditions. The hollow particles were thoroughly characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), infrared spectroscopy (FTIR), thermal (TG/DTA) and nitrogen adsorption analyses. Thus obtained Nb{sub 2}O{sub 5} hollow nanospheres were investigated as anode materials for lithium ion rechargeable batteries for the first time. The nanostructured electrode delivers high capacity of 172 mAh g{sup −1} after 250 cycles of charge/discharge at a rate of 0.5 C. More importantly, the hollow particles based electrodes maintains the structural integrity and excellent cycling stability even after exposing to high current density 6.25 A g{sup −1}. The enhanced electrochemical behavior is ascribed to hollow cavity coupled with nanosized Nb{sub 2}O{sub 5} shell domain that facilitates fast lithium intercalation/deintercalation kinetics.« less

M sub shell X-ray emission cross section measurements for Pt, Au, Hg, Pb, Th and U at 8 and 10 keV synchrotron photons

NASA Astrophysics Data System (ADS)

Kaur, Gurpreet; Gupta, Sheenu; Tiwari, M. K.; Mittal, Raj

2014-02-01

M sub shell X-ray emission cross sections of Pt, Au, Hg, Pb, Th and U at 8 and 10 keV photon energies have been determined with linearly polarized photon beam from Indus-2 synchrotron source. The measured cross sections have been reported for the first time and were used to check the available theoretical Dirac-Hartree-Slater (DHS) and Dirac-Fock (DF) values reported in literature and also the presently derived Non Relativistic Hartree-Slater (NRHS), DF and DHS values for Mξ, Mδ, Mα, Mβ, Mγ, Mm1 and Mm2 group of X-rays.

Simulation of Deep Convective Clouds with the Dynamic Reconstruction Turbulence Closure

NASA Astrophysics Data System (ADS)

Shi, X.; Chow, F. K.; Street, R. L.; Bryan, G. H.

2017-12-01

The terra incognita (TI), or gray zone, in simulations is a range of grid spacing comparable to the most energetic eddy diameter. Spacing in mesoscale and simulations is much larger than the eddies, and turbulence is parameterized with one-dimensional vertical-mixing. Large eddy simulations (LES) have grid spacing much smaller than the energetic eddies, and use three-dimensional models of turbulence. Studies of convective weather use convection-permitting resolutions, which are in the TI. Neither mesoscale-turbulence nor LES models are designed for the TI, so TI turbulence parameterization needs to be discussed. Here, the effects of sub-filter scale (SFS) closure schemes on the simulation of deep tropical convection are evaluated by comparing three closures, i.e. Smagorinsky model, Deardorff-type TKE model and the dynamic reconstruction model (DRM), which partitions SFS turbulence into resolvable sub-filter scales (RSFS) and unresolved sub-grid scales (SGS). The RSFS are reconstructed, and the SGS are modeled with a dynamic eddy viscosity/diffusivity model. The RSFS stresses/fluxes allow backscatter of energy/variance via counter-gradient stresses/fluxes. In high-resolution (100m) simulations of tropical convection use of these turbulence models did not lead to significant differences in cloud water/ice distribution, precipitation flux, or vertical fluxes of momentum and heat. When model resolutions are coarsened, the Smagorinsky and TKE models overestimate cloud ice and produces large-amplitude downward heat flux in the middle troposphere (not found in the high-resolution simulations). This error is a result of unrealistically large eddy diffusivities, i.e., the eddy diffusivity of the DRM is on the order of 1 for the coarse resolution simulations, the eddy diffusivity of the Smagorinsky and TKE model is on the order of 100. Splitting the eddy viscosity/diffusivity scalars into vertical and horizontal components by using different length scales and strain rate components helps to reduce the errors, but does not completely remedy the problem. In contrast, the coarse resolution simulations using the DRM produce results that are more consistent with the high-resolution results, suggesting that the DRM is a more appropriate turbulence model for simulating convection in the TI.

Progressive Fracture of Fiber Composite Thin Shell Structures Under Internal Pressure and Axial Loads

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Chamis, Christos C.; Minnetyan, Levon

1996-01-01

Graphite/epoxy composite thin shell structures were simulated to investigate damage and fracture progression due to internal pressure and axial loading. Defective and defect-free structures (thin cylinders) were examined. The three different laminates examined had fiber orientations of (90/0/+/-0)(sub s), where 0 is 45, 60, and 75 deg. CODSTRAN, an integrated computer code that scales up constituent level properties to the structural level and accounts for all possible failure modes, was used to simulate composite degradation under loading. Damage initiation, growth, accumulation, and propagation to fracture were included in the simulation. Burst pressures for defective and defect-free shells were compared to evaluate damage tolerance. The results showed that damage initiation began with matrix failure whereas damage and/or fracture progression occurred as a result of additional matrix failure and fiber fracture. In both thin cylinder cases examined (defective and defect-free), the optimum layup configuration was (90/0/+/-60)(sub s) because it had the best damage tolerance with respect to the burst pressure.

Plasmonic enhancement of light-harvesting efficiency in tandem dye-sensitized solar cells using multiplexed gold core/silica shell nanorods

NASA Astrophysics Data System (ADS)

Zheng, Yan-Zhen; Tao, Xia; Zhang, Jin-Wen; Lai, Xue-Sen; Li, Nan

2018-02-01

Incorporation of plasmonic metal nanocrystals is a promising approach for broadening and enhancing the light harvesting of dye-sensitized solar cells (DSSCs). In this work, we report a facile and versatile route to tune the photoresponse of tandem DSSCs via incorporating Au nanorods with multiplexed length-to-diameter aspect ratios in the two sub-cells. Plasmonic Au nanorods with length-to-diameter aspect ratio of 2.5 (Au NRs-1) and 3.9 (Au NRs-2) are prepared, exhibiting their plasmon band at 500-700 nm and 500-900 nm, respectively. Au NRs-1 core/SiO2 shell (Au NRs@SiO2-1) and Au NRs-2 core/SiO2 shell (Au NRs@SiO2-2) are separately incorporated in TiO2 photoanodes and then coupled with commercial dye N719 and N749 for the top and bottom sub-cells of a tandem DSSC, achieving a power conversion efficiency (PCE) of 10.73% for relative to 9.02% of reference (TiO2 only) devices. By virtue of morphological, spectral and electrochemical characterizations and analysis, we find that the integration of Au NRs within dye-sensitized TiO2 photoanode film enables to increase the sunlight harvesting from visible to near infrared region by plasmonic enhancement effect, reduce the charge recombination probability and facilitate charge transport via Au NRs, leading to enhancement of PCE.

Coulomb Excitation of the N = 50 nucleus 80Zn

NASA Astrophysics Data System (ADS)

van de Walle, J.; Aksouh, F.; Ames, F.; Behrens, T.; Bildstein, V.; Blazhev, A.; Cederkäll, J.; Clément, E.; Cocolios, T. E.; Davinson, T.; Delahaye, P.; Eberth, J.; Ekström, A.; Fedorov, D. V.; Fedosseev, V. N.; Fraile, L. M.; Franchoo, S.; Gernhauser, R.; Georgiev, G.; Habs, D.; Heyde, K.; Huber, G.; Huyse, M.; Ibrahim, F.; Ivanov, O.; Iwanicki, J.; Jolie, J.; Kester, O.; Köster, U.; Kröll, T.; Krücken, R.; Lauer, M.; Lisetskiy, A. F.; Lutter, R.; Marsh, B. A.; Mayet, P.; Niedermaier, O.; Nilsson, T.; Pantea, M.; Perru, O.; Raabe, R.; Reiter, P.; Sawicka, M.; Scheit, H.; Schrieder, G.; Schwalm, D.; Seliverstov, M. D.; Sieber, T.; Sletten, G.; Smirnova, N.; Stanoiu, M.; Stefanescu, I.; Thomas, J.-C.; Valiente-Dobón, J. J.; van Duppen, P.; Verney, D.; Voulot, D.; Warr, N.; Weisshaar, D.; Wenander, F.; Wolf, B. H.; Zielińska, M.

2008-05-01

Neutron rich Zinc isotopes, including the N = 50 nucleus 80Zn, were produced and post-accelerated at the Radioactive Ion Beam (RIB) facility REX-ISOLDE (CERN). Low-energy Coulomb excitation was induced on these isotopes after post-acceleration, yielding B(E2) strengths to the first excited 2+ states. For the first time, an excited state in 80Zn was observed and the 21+ state in 78Zn was established. The measured B(E2,21+-->01+) values are compared to two sets of large scale shell model calculations. Both calculations reproduce the observed B(E2) systematics for the full Zinc isotopic chain. The results for N = 50 isotones indicate a good N = 50 shell closure and a strong Z = 28 proton core polarization. The new results serve as benchmarks to establish theoretical models, predicting the nuclear properties of the doubly magic nucleus 78Ni.

Analysis of local delaminations caused by angle ply matrix cracks

NASA Technical Reports Server (NTRS)

Salpekar, Satish A.; Obrien, T. Kevin; Shivakumar, K. N.

1993-01-01

Two different families of graphite/epoxy laminates with similar layups but different stacking sequences, (0,theta,-theta) sub s and (-theta/theta/0) sub s were analyzed using three-dimensional finite element analysis for theta = 15 and 30 degrees. Delaminations were modeled in the -theta/theta interface, bounded by a matrix crack and the stress free edge. The total strain energy release rate, G, along the delamination front was computed using three different techniques: the virtual crack closure technique (VCCT), the equivalent domain Integral (EDI) technique, and a global energy balance technique. The opening fracture mode component of the strain energy release rate, Gl, along the delamination front was also computed for various delamination lengths using VCCT. The effect of residual thermal and moisture stresses on G was evaluated.

Surface spins enhanced magnetoelectric coefficient and impedance spectroscopy of BaFe{sub 0.01}Ti{sub 0.99}O{sub 3} and BaFe{sub 0.015}Ti{sub 0.985}O{sub 3} nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Verma, Kuldeep Chand, E-mail: kuldeep0309@yahoo.co.in; Akal School of Physics, Eternal University, Baru Sahib, Himachal Pradesh 173101; Tripathi, S.K.

2015-08-15

Highlights: • Multiferroic Fe-doped BaTiO{sub 3} nanorods. • Sol–gel. • Magnetoelectric coefficient. • Transmission electron microscopy. • Cole–Cole plots. - Abstract: Multiferroic BaFe{sub 0.01}Ti{sub 0.99}O{sub 3} (BFT1) and BaFe{sub 0.015}Ti{sub 0.985}O{sub 3} (BFT15) nanorods were prepared by a sol–gel synthesis and annealed at 700 °C/2 h. The tetragonal phase and nano dimensions of BFT samples are identified by X-ray diffraction and transmission electron microscopy. The enhancement in ferroelectricity depends upon low porosity, tetragonal phase, space charge field, larger surface area and oriented growth. The ferromagnetism depends upon partially filled inner shells, surface spins and oxygen vacancies. The magnetoelectric coefficient ismore » explained on the basis of surface spins, short-range interactions near surface boundary, compressive stress and twin structure contributed by nano grains which can reside stress near grain boundaries. The frequency dependent real (Z′) and imaginary (Z″) parts of impedance spectra are confirmed by the variations that observed in dielectric properties. The values of resistance of grain boundaries, R{sub gb} is higher than grains, R{sub g} indicating that the effect of grain boundaries is dominant in BFT nanorods.« less

On the non-existence of a sharp cooling break in gamma-ray burst afterglow spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Uhm, Z. Lucas; Zhang, Bing, E-mail: uhm@physics.unlv.edu, E-mail: zhang@physics.unlv.edu

Although the widely used analytical afterglow model of gamma-ray bursts (GRBs) predicts a sharp cooling break ν {sub c} in its afterglow spectrum, the GRB observations so far rarely show clear evidence for a cooling break in their spectra or a corresponding temporal break in their light curves. Employing a Lagrangian description of the blast wave, we conduct a sophisticated calculation of the afterglow emission. We precisely follow the cooling history of non-thermal electrons accelerated into each Lagrangian shell. We show that a detailed calculation of afterglow spectra does not in fact give rise to a sharp cooling break atmore » ν {sub c}. Instead, it displays a very mild and smooth transition, which occurs gradually over a few orders of magnitude in energy or frequency. The main source of this slow transition is that different mini shells have different evolutionary histories of the comoving magnetic field strength B, so that deriving the current value of ν {sub c} of each mini shell requires an integration of its cooling rate over the time elapsed since its creation. We present the time evolution of optical and X-ray spectral indices to demonstrate the slow transition of spectral regimes and discuss the implications of our result in interpreting GRB afterglow data.« less

Synthesis of superparamagnetic silica-coated magnetite nanoparticles for biomedical applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaur, Navjot, E-mail: navjot.dhindsa2989@gmail.com; Chudasama, Bhupendra, E-mail: bnchudasama@gmail.com

Multifunctional superparamagnetic iron oxide nanoparticles (SPIONs) coated with silica are widely researched for biomedical applications such as magnetic resonance imaging, tissue repair, cell separation, hyperthermia, drug delivery, etc. In this article synthesis of magnetite (Fe{sub 3}O{sub 4}) nanoparticles and their coating with SiO{sub 2} is reported. Fe{sub 3}O{sub 4} nanoparticles were synthesized by chemical co-precipitation and it was coated with silica by hydrolysis and condensation of tetraethylorthosilicate. XRD, FTIR, TEM and VSM techniques were used to characterize bare and coated nanoparticles. Results indicated that the average size of SPIONS was 8.4 nm. X-ray diffraction patterns of silica coated SPIONS were identicalmore » to that of SPIONS confirming the inner spinal structure of SPIONS. FTIR results confirmed the binding of silica with the magnetite and the formation of the silica shell around the magnetite core. Magnetic properties of SPIONS and silica coated SPIONS are determined by VSM. They are superparamagnetic. The major conclusion drawn from this study is that the synthesis route yields stable, non-aggregated magnetite-silica core-shell nanostructures with tailored morphology and excellent magnetic properties.« less

DETECTION OF BROAD Hα EMISSION LINES IN THE LATE-TIME SPECTRA OF A HYDROGEN-POOR SUPERLUMINOUS SUPERNOVA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Lin; Masci, F.; Quimby, R.

2015-12-01

iPTF13ehe is a hydrogen-poor superluminous supernova (SLSN) at z = 0.3434, with a slow-evolving light curve and spectral features similar to SN2007bi. It rises in 83–148 days to reach a peak bolometric luminosity of ∼1.3 × 10{sup 44} erg s{sup −1}, then decays slowly at 0.015 mag day{sup −1}. The measured ejecta velocity is ∼ 13,000 km s{sup −1}. The inferred explosion characteristics, such as the ejecta mass (70–220 M{sub ⊙}), and the total radiative and kinetic energy (E{sub rad} ∼ 10{sup 51} erg, E{sub kin} ∼ 2 × 10{sup 53} erg), are typical of slow-evolving H-poor SLSN events. However,more » the late-time spectrum taken at +251 days (rest, post-peak) reveals a Balmer Hα emission feature with broad and narrow components, which has never been detected before among other H-poor SLSNe. The broad component has a velocity width of ∼4500 km s{sup −1} and a ∼300 km s{sup −1} blueward shift relative to the narrow component. We interpret this broad Hα emission with a luminosity of ∼2 × 10{sup 41} erg s{sup −1} as resulting from the interaction between the supernova ejecta and a discrete H-rich shell, located at a distance of ∼4 × 10{sup 16} cm from the explosion site. This interaction causes the rest-frame r-band LC to brighten at late times. The fact that the late-time spectra are not completely absorbed by the shock-ionized H-shell implies that its Thomson scattering optical depth is likely ≤1, thus setting upper limits on the shell mass ≤30 M{sub ⊙}. Of the existing models, a Pulsational Pair Instability supernova model can naturally explain the observed 30 M{sub ⊙} H-shell, ejected from a progenitor star with an initial mass of (95–150) M{sub ⊙} about 40 years ago. We estimate that at least ∼15% of all SLSNe-I may have late-time Balmer emission lines.« less

Effective boson g factors in the mass 80 region

NASA Astrophysics Data System (ADS)

Mertzimekis, T. J.; Taylor, M. J.; Kumbartzki, G.; Benczer-Koller, N.; Stuchbery, A. E.

2002-10-01

Recent precision g factors have been obtained by using the transient field technique combined with Coulomb excitation in inverse kinematics in several, near spherical, nuclei around A ˜ 80. The g factors were analyzed in terms of an IBA-II formulation which treats the n and p boson effective g factors as mass-independent free parameters (A.Wolf et al.), Phys. Lett. B190, 19 (1987).. The data yielded more accurate effective boson g factors than obtained in the previous systematics for this region, g_π=0.50(3), g_ν=0.24(5) and g_π=0.45(3), g_ν=0.35(3) for the regions 28 <= N <= 50 and 38 <= N <= 50 respectively, with comparable i^2's. Evidence of shell closure for N=38 (K.-H. Speidel et al.), Phys. Rev. C57, 2181 (1998). prompted the need to examine these two regions separately. The deviations of g_π from unity and g_ν from zero indicate the importance of the underlying fermion structure.

Bright Localized Near-Infrared Emission at 1-4 AU in the AB Aurigae Disk Revealed by IOTA Closure Phases

NASA Astrophysics Data System (ADS)

Millan-Gabet, R.; Monnier, J. D.; Berger, J.-P.; Traub, W. A.; Schloerb, F. P.; Pedretti, E.; Benisty, M.; Carleton, N. P.; Haguenauer, P.; Kern, P.; Labeye, P.; Lacasse, M. G.; Malbet, F.; Perraut, K.; Pearlman, M.; Thureau, N.

2006-07-01

We report on the detection of localized off-center emission at 1-4 AU in the circumstellar environment of the young stellar object AB Aurigae. We used closure-phase measurements in the near-infrared that were made at the long-baseline interferometer IOTA, the first obtained on a young stellar object using this technique. When probing sub-AU scales, all closure phases are close to zero degrees, as expected given the previously determined size of the AB Aurigae inner-dust disk. However, a clear closure-phase signal of -3.5d +/- 0.5d is detected on one triangle containing relatively short baselines, requiring a high degree of non-point symmetry from emission at larger (AU-sized) scales in the disk. We have not identified any alternative explanation for these closure-phase results, and we demonstrate that a ``disk hot spot'' model can fit our data. We speculate that such detected asymmetric near-infrared emission might arise as a result of localized viscous heating due to a gravitational instability in the AB Aurigae disk, or to the presence of a close stellar companion or accreting substellar object.

Average M shell fluorescence yields for elements with 70≤Z≤92

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kahoul, A., E-mail: ka-abdelhalim@yahoo.fr; LPMRN laboratory, Department of Materials Science, Faculty of Sciences and Technology, Mohamed El Bachir El Ibrahimi University, Bordj-Bou-Arreridj 34030; Deghfel, B.

2015-03-30

The theoretical, experimental and analytical methods for the calculation of average M-shell fluorescence yield (ω{sup ¯}{sub M}) of different elements are very important because of the large number of their applications in various areas of physical chemistry and medical research. In this paper, the bulk of the average M-shell fluorescence yield measurements reported in the literature, covering the period 1955 to 2005 are interpolated by using an analytical function to deduce the empirical average M-shell fluorescence yield in the atomic range of 70≤Z≤92. The results were compared with the theoretical and fitted values reported by other authors. Reasonable agreement wasmore » typically obtained between our result and other works.« less

Effects of phosphates on shellfish and on calcium carbonate crystallization in vitro. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilbur, K.M.

1986-07-17

It has been known that inorganic phosphate inhibits the precipitation of calcium carbonate in artificial sea water. This work addresses the question of whether phosphate also affects the deposition of CaCO/sub 3/ in the exoskeletons of invertebrates. Tetrasodiumpyrophosphate and pentasodiumtripolyphosphate in concentrations of 15 ppM caused abnormality, mortality, and inhibition of shell deposition in trochophore larvae of the oyster Crassostrea. Inhibition of shell growth resulting from pollution at 15 ppM could be expected in Rangia with orthophosphate, tetrasodium pyrophosphate, and sodiumtripolyphosphate, in Helisoma with tetrasodium pyrophosphate, and pentasodium tripolyphosphate, and in larvae of Crassostea the relative inhibitory action of shellmore » growth was tetrasodiumpyrophosphate > sodiumtripolyphosphate > sodium orthophosphate greater than or equal to sodium hexametaphosphate. 4 refs.« less

Fatigue crack growth in unidirectional metal matrix composite

NASA Technical Reports Server (NTRS)

Ghosn, Louis J.; Telesman, Jack; Kantzos, Peter

1990-01-01

The weight function method was used to determine the effective stress intensity factor and the crack opening profile for a fatigue tested composite which exhibited fiber bridging. The bridging mechanism was modeled using two approaches; the crack closure approach and the shear lag approach. The numerically determined stress intensity factor values from both methods were compared and correlated with the experimentally obtained crack growth rates for SiC/Ti-15-3 (0)(sub 8) oriented composites. The near crack tip opening profile was also determined for both methods and compared with the experimentally obtained measurements.

The role of nonmagnetic d{sup 0} vs. d{sup 10}B-type cations on the magnetic exchange interactions in osmium double perovskites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feng, Hai L., E-mail: Hai.Feng@cpfs.mpg.de; Yamaura, Kazunari; Tjeng, Liu Hao

Polycrystalline samples of double perovskites Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) were synthesized by solid state reactions. They adopt the cubic double perovskite structures (space group, Fm-3m) with ordered B and Os arrangements. Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) show antiferromagnetic transitions at 93 K, 69 K, and 28 K, respectively. The Weiss-temperatures are −590 K for Ba{sub 2}ScOsO{sub 6}, −571 K for Ba{sub 2}YOsO{sub 6}, and −155 K for Ba{sub 2}InOsO{sub 6}. Sc{sup 3+} and Y{sup 3+} have the open-shell d{sup 0} electronic configuration, while In{sup 3+} has the closed-shell d{sup 10}. This indicates that a d{sup 0} B-typemore » cation induces stronger overall magnetic exchange interactions in comparison to a d{sup 10}. Comparison of Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) to their Sr and Ca analogues shows that the structural distortions weaken the overall magnetic exchange interactions. - Graphical abstract: Magnetic properties of osmium double perovskites Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) were studied. Comparison of Ba{sub 2}BOsO{sub 6}indicates that a d{sup 0} B-type cation induces stronger overall magnetic exchange interactions in comparison to a d{sup 10}. - Highlights: • Magnetic properties of double perovskites Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) were studied. • A d{sup 0}B-type cation induces stronger magnetic interactions than a d{sup 10}. • Structural distortions weaken the overall Os{sup 5+}-Os{sup 5+} magnetic interactions.« less

Maximum Energies of Shock-Accelerated Electrons in Young Shell Supernova Remnants

NASA Technical Reports Server (NTRS)

Reynolds, Stephen P.; Keohane, Jonathan W.; White, Nicholas E. (Technical Monitor)

1999-01-01

Young supernova remnants (SNRs) are often assumed to be the source of cosmic rays up to energies approaching the slight steepening in the cosmic ray spectrum at around 1000 TeV, known as the "knee." We show that the observed X-ray emission of 14 radio-bright shell remnants, including all five historical shells, can be used to put limits on E(sub max), the energy at which the electron energy distribution must steepen from its slope at radio-emitting energies. Most of the remnants show thermal spectra, so any synchrotron component must fall below the observed X-ray fluxes. We obtain upper limits on E(sub max) by considering the most rapid physically plausible cutoff in the relativistic electron distribution, an exponential, which is as sharp or sharper than found in any more elaborate models. This maximally curved model then gives us the highest possible E(sub max) consistent with not exceeding observed X-rays. Our results are thus independent of particular models for the electron spectrum in SNRs. Assuming homogeneous emitting volumes with a constant magnetic field strength of 10 uG, no object could reach 1000 TeV, and only one, Kes 73, has an upper limit on E(sub max), above 100 TeV. All the other remnants have limits at or below 80 TeV. E(sub max) is probably set by the finite remnant lifetime rather than by synchrotron losses for remnants younger than a few thousand years, so that an observed electron steepening should be accompanied by steepening at the same energy for protons. More complicated, inhomogeneous models could allow higher values of E(sub max) in parts of the remnant, but the emission-weighted average value, that characteristic of typical electrons, should obey these limits. The young remnants are not expected to improve much over their remaining lives at producing the highest energy Galactic cosmic rays; if they cannot, this picture of cosmic-ray origin may need major alteration.

Biofiltration of methanol in an organic biofilter using peanut shells as medium.

PubMed

Ramirez-Lopez, E M; Corona-Hernandez, J; Avelar-Gonzalez, F J; Omil, F; Thalasso, F

2010-01-01

Biofiltration consists of a filter-bed of organic matter serving both as carrier for the active biomass and as nutrient supply, through which the polluted gas passes. The selection of a suitable medium material is of major importance to ensure optimum biofilter efficiency. Peanut shells are an agricultural byproduct locally available in large quantities at a low price in most tropical and sub-tropical countries. A previous study showed that peanut shells are physically and chemically suitable for biofiltration. This paper presents the results obtained during a six month biofiltration experiment using peanut shells as medium and methanol as air pollutant. It is shown that peanut shells are potentially suitable as biofiltration medium, since degradation rates of up to 30 kg MeOH/m(3)d with an empty bed residence time of 19s was obtained. The biofilter showed a good resistance to shock load and no operational problems were observed.

Internal stresses in pre-stressed micron-scale aluminum core-shell particles and their improved reactivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levitas, Valery I., E-mail: vlevitas@iastate.edu; McCollum, Jena; Pantoya, Michelle L.

2015-09-07

Dilatation of aluminum (Al) core for micron-scale particles covered by alumina (Al{sub 2}O{sub 3}) shell was measured utilizing x-ray diffraction with synchrotron radiation for untreated particles and particles after annealing at 573 K and fast quenching at 0.46 K/s. Such a treatment led to the increase in flame rate for Al + CuO composite by 32% and is consistent with theoretical predictions based on the melt-dispersion mechanism of reaction for Al particles. Experimental results confirmed theoretical estimates and proved that the improvement of Al reactivity is due to internal stresses. This opens new ways of controlling particle reactivity through creating and monitoringmore » internal stresses.« less

ALMA sub-mm maser and dust distribution of VY Canis Majoris

NASA Astrophysics Data System (ADS)

Richards, A. M. S.; Impellizzeri, C. M. V.; Humphreys, E. M.; Vlahakis, C.; Vlemmings, W.; Baudry, A.; De Beck, E.; Decin, L.; Etoka, S.; Gray, M. D.; Harper, G. M.; Hunter, T. R.; Kervella, P.; Kerschbaum, F.; McDonald, I.; Melnick, G.; Muller, S.; Neufeld, D.; O'Gorman, E.; Parfenov, S. Yu.; Peck, A. B.; Shinnaga, H.; Sobolev, A. M.; Testi, L.; Uscanga, L.; Wootten, A.; Yates, J. A.; Zijlstra, A.

2014-12-01

Aims: Cool, evolved stars have copious, enriched winds. Observations have so far not fully constrained models for the shaping and acceleration of these winds. We need to understand the dynamics better, from the pulsating stellar surface to ~10 stellar radii, where radiation pressure on dust is fully effective. Asymmetric nebulae around some red supergiants imply the action of additional forces. Methods: We retrieved ALMA Science Verification data providing images of sub-mm line and continuum emission from VY CMa. This enables us to locate water masers with milli-arcsec accuracy and to resolve the dusty continuum. Results: The 658, 321, and 325 GHz masers lie in irregular, thick shells at increasing distances from the centre of expansion. For the first time this is confirmed as the stellar position, coinciding with a compact peak offset to the NW of the brightest continuum emission. The maser shells overlap but avoid each other on scales of up to 10 au. Their distribution is broadly consistent with excitation models but the conditions and kinematics are complicated by wind collisions, clumping, and asymmetries. Appendices are available in electronic form at http://www.aanda.org

Origin of the magnetic transition at 100 K in ɛ-Fe2O3 nanoparticles studied by x-ray absorption fine structure spectroscopy

NASA Astrophysics Data System (ADS)

López-Sánchez, J.; Muñoz-Noval, A.; Castellano, C.; Serrano, A.; del Campo, A.; Cabero, M.; Varela, M.; Abuín, M.; de la Figuera, J.; Marco, J. F.; Castro, G. R.; Rodríguez de la Fuente, O.; Carmona, N.

2017-12-01

The current study unveils the structural origin of the magnetic transition of the ɛ-Fe2O3 polymorph from an incommensurate magnetic order to a collinear ferrimagnetic state at low temperature. The high crystallinity of the samples and the absence of other iron oxide polymorphs have allowed us to carry out temperature-dependent x-ray absorption fine structure spectroscopy experiments out. The deformation of the structure is followed by the Debye-Waller factor for each selected Fe-O and Fe-Fe sub-shell. For nanoparticle sizes between 7 and 15 nm, the structural distortions between the Fete and Fe-D1oc sites are localized in a temperature range before the magnetic transition starts. On the contrary, the inherent interaction between the other sub-shells (named Fe-O1,2 and Fe-Fe1) provokes cooperative magneto-structural changes in the same temperature range. This means that the Fete with Fe-D1oc polyhedron interaction seems to be uncoupled with temperature dealing with these nanoparticle sizes wherein the structural distortions are likely moderate due to surface effects.

Modeling of the Dust and Gas Outflows from OH 26.5+0.6: The Superwind

NASA Technical Reports Server (NTRS)

Justtanont, K.; Skinner, C. J.; Tielens, A. G. G. M.; Meixner, M.; Baas, F.

1996-01-01

We have observed the extreme OH/IR star, OH 26.5+0.6, in the infrared dust continuum and in the sub- millimeter rotational lines of CO. Mid-infrared images reveal the compact nature of the circumstellar shell (less than 0.5 sec). A deep 9.7 microns absorption feature and an absorption at 18 microns show that the dust mass-loss rate is very high. However, the low antenna temperatures of CO J = 1-0 and 2-1 lines suggest that the outer part of the circumstellar shell is much more tenuous. In order to resolve this discrepancy, we have observed the J = 3-2 and 4-3 CO rotational transitions. We have developed a model for the circumstellar shell for OH 26.5 + 0.6 which is consistent with the infrared and submillimeter observations. The dust and gas data are well fitted by a two-shell model, consisting of a dense shell surrounded by a more tenuous shell. The former we identify with the superwind (M = 5.5 x 10(exp -4) solar mass/ yr), and the latter we identify with mass loss on the asymptotic giant branch (AGB) (M = 10(exp -6) solar mass/ yr). The transition between the two mass-loss phases is shown to be rather abrupt ((Delta)t less than 150 yr). Depending on the mass of the progenitor, this superwind phase may be the last thermal pulse (for M(sub *) less than 1.5 solar mass), or the first of a series of the superwind phases (for up to 8 solar mass), punctuated by a period of low mass-loss rates, before the star evolves off the AGB.

Enceladus's south polar thermal anomaly in light of weak thermal convection

NASA Astrophysics Data System (ADS)

Besserer, Jonathan; Golabek, Gregor J.; Rozel, Antoine; Tackley, Paul J.

2014-05-01

The south polar thermal anomaly of Enceladus, contrasting with older and colder northern regions, suggests an asymmetrical heat transfer in the satellite's ice shell. Most of the current models that explain such a distribution prescribe an a priori asymmetry by mean of a mechanical or topographical anomaly in or below the south polar ice shell. We present here a series of simulations with a 2D-spherical convection model to investigate the possibility of self-consistently generating a localized mechanical anomaly in the ice shell. We focus on the non-Newtonian character of ice rheology, and on the stability of a single-plume (i.e. localized convection) and low-degree convection regimes. We show that the non-Newtonian rheology favors a localized (tidally heated) convection surrounded by a conductive ice mantle, even with a global, liquid water ocean at the base of the ice shell. We find that the single-plume state is very unlikely to remain stable if the rheology is Newtonian. The proposed thermal regime for Enceladus's ice shell is therefore weak, single-plume thermal convection focused at the south pole (e.g., remnant of a formerly more vigorous convection). Such weak-to-sub-critical regimes may be important for icy satellites, as recently pointed out by Solomatov (2012, PEPI). We will discuss the effects of ice plasticity on heat focusing in Enceladus's South Polar Terrain, together with the possibility of an ice shell a factor ~2 thinner than previously thought (Hemingway et al., AGU 2013; Stevenson et al., AGU 2013).

The oil palm Shell gene controls oil yield and encodes a homologue of SEEDSTICK

PubMed Central

Singh, Rajinder; Leslie Low, Eng-Ti; Ooi, Leslie Cheng-Li; Ong-Abdullah, Meilina; Chin, Ting Ngoot; Nagappan, Jayanthi; Nookiah, Rajanaidu; Amiruddin, Mohd Din; Rosli, Rozana; Abdul Manaf, Mohamad Arif; Chan, Kuang-Lim; Halim, Mohd Amin; Azizi, Norazah; Lakey, Nathan; Smith, Steven W; Budiman, Muhammad A; Hogan, Michael; Bacher, Blaire; Van Brunt, Andrew; Wang, Chunyan; Ordway, Jared M; Sambanthamurthi, Ravigadevi; Martienssen, Robert A

2014-01-01

A key event in the domestication and breeding of the oil palm, Elaeis guineensis, was loss of the thick coconut-like shell surrounding the kernel. Modern E. guineensis has three fruit forms, dura (thick-shelled), pisifera (shell-less) and tenera (thin-shelled), a hybrid between dura and pisifera1–4. The pisifera palm is usually female-sterile but the tenera yields far more oil than dura, and is the basis for commercial palm oil production in all of Southeast Asia5. Here, we describe the mapping and identification of the Shell gene responsible for the different fruit forms. Using homozygosity mapping by sequencing we found two independent mutations in the DNA binding domain of a homologue of the MADS-box gene SEEDSTICK (STK) which controls ovule identity and seed development in Arabidopsis. The Shell gene is responsible for the tenera phenotype in both cultivated and wild palms from sub-Saharan Africa, and our findings provide a genetic explanation for the single gene heterosis attributed to Shell, via heterodimerization. This gene mutation explains the single most important economic trait in oil palm, and has implications for the competing interests of global edible oil production, biofuels and rainforest conservation6. PMID:23883930

The Effect of Rural Hospital Closures on Community Economic Health

PubMed Central

Holmes, George M; Slifkin, Rebecca T; Randolph, Randy K; Poley, Stephanie

2006-01-01

Objective To examine the effect of rural hospital closures on the local economy. Data Sources U.S. Census Bureau, OSCAR, Medicare Cost Reports, and surveys of individuals knowledgeable about local hospital closures. Study Design Economic data at the county level for 1990–2000 were combined with information on hospital closures. The study sample was restricted to rural counties experiencing a closure during the sample period. Longitudinal regression methods were used to estimate the effect of hospital closure on per-capita income, unemployment rate, and other community economic measures. Models included both leading and lagged closure terms allowing a preclosure economic downturn as well as time for the closure to be fully realized by the community. Data Collection Information on closures was collected by contacting every state hospital association, reconciling information gathered with that contained in the American Hospital Association file and OIG reports. Principal Findings Results indicate that the closure of the sole hospital in the community reduces per-capita income by $703 (p<0.05) or 4 percent (p<0.05) and increases the unemployment rate by 1.6 percentage points (p<0.01). Closures in communities with alternative sources of hospital care had no long-term economic impact, although income decreased for 2 years following the closure. Conclusions The local economic effects of a hospital closure should be considered when regulations that affect hospitals' financial well-being are designed or changed. PMID:16584460

Inorganic mercury detection by valve closure response in the freshwater clam Corbicula fluminea: integration of time and water metal concentration changes.

PubMed

Tran, Damien; Fournier, Elodie; Durrieu, Gilles; Massabuau, Jean-Charles

2007-07-01

The objective of the present study was to monitor water-quality assessment by a biological method. Optimum dissolved inorganic mercury sensitivity in the freshwater bivalve Corbicula fluminea was estimated using a combined approach to determine their potentials and limits in detecting contaminants. Detection by bivalves is based on shell closure, a protective strategy when exposed to a water contaminant. To take the rate of spontaneous closures into account, stress associated with fixation by one valve in common valvometers was integrated, and the spontaneous rhythm was associated with daily activity. The response in conditions where the probability of spontaneous closing is the lowest was thus taken into account. To develop dose-response curves, impedance valvometry, in which lightweight impedance electrodes are applied to study free-ranging animals in low-stress conditions, also was used combined with a new analytical approach. The logistic regression dose-response curves take into account variations in both response time and metal concentration in water to significantly improve the methods aiming at determining the optimal sensitivity threshold response. This approach demonstrates that in C. fluminea, inorganic mercury concentrations under the range of 2.0 to 5.1 microg/L (95% confidence interval) cannot be detected within 5 h of addition.

A statistical approach to develop a detailed soot growth model using PAH characteristics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raj, Abhijeet; Celnik, Matthew; Shirley, Raphael

A detailed PAH growth model is developed, which is solved using a kinetic Monte Carlo algorithm. The model describes the structure and growth of planar PAH molecules, and is referred to as the kinetic Monte Carlo-aromatic site (KMC-ARS) model. A detailed PAH growth mechanism based on reactions at radical sites available in the literature, and additional reactions obtained from quantum chemistry calculations are used to model the PAH growth processes. New rates for the reactions involved in the cyclodehydrogenation process for the formation of 6-member rings on PAHs are calculated in this work based on density functional theory simulations. Themore » KMC-ARS model is validated by comparing experimentally observed ensembles on PAHs with the computed ensembles for a C{sub 2}H{sub 2} and a C{sub 6}H{sub 6} flame at different heights above the burner. The motivation for this model is the development of a detailed soot particle population balance model which describes the evolution of an ensemble of soot particles based on their PAH structure. However, at present incorporating such a detailed model into a population balance is computationally unfeasible. Therefore, a simpler model referred to as the site-counting model has been developed, which replaces the structural information of the PAH molecules by their functional groups augmented with statistical closure expressions. This closure is obtained from the KMC-ARS model, which is used to develop correlations and statistics in different flame environments which describe such PAH structural information. These correlations and statistics are implemented in the site-counting model, and results from the site-counting model and the KMC-ARS model are in good agreement. Additionally the effect of steric hindrance in large PAH structures is investigated and correlations for sites unavailable for reaction are presented. (author)« less

Scaling laws for homogeneous turbulent shear flows in a rotating frame

NASA Technical Reports Server (NTRS)

Speziale, Charles G.; Mhuiris, Nessan Macgiolla

1988-01-01

The scaling properties of plane homogeneous turbulent shear flows in a rotating frame are examined mathematically by a direct analysis of the Navier-Stokes equations. It is proved that two such shear flows are dynamically similar if and only if their initial dimensionless energy spectrum E star (k star, 0), initial dimensionless shear rate SK sub 0/epsilon sub 0, initial Reynolds number K squared sub 0/nu epsilon sub 0, and the ration of the rotation rate to the shear rate omega/S are identical. Consequently, if universal equilibrium states exist, at high Reynolds numbers, they will only depend on the single parameter omega/S. The commonly assumed dependence of such equilibrium states on omega/S through the Richardson number Ri=-2(omega/S)(1-2 omega/S) is proven to be inconsistent with the full Navier-Stokes equations and to constitute no more than a weak approximation. To be more specific, Richardson number similarity is shown to only rigorously apply to certain low-order truncations of the Navier-Stokes equations (i.e., to certain second-order closure models) wherein closure is achieved at the second-moment level by assuming that the higher-order moments are a small perturbation of their isotropic states. The physical dependence of rotating turbulent shear flows on omega/S is discussed in detail along with the implications for turbulence modeling.

AN IMAGE-PLANE ALGORITHM FOR JWST'S NON-REDUNDANT APERTURE MASK DATA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greenbaum, Alexandra Z.; Pueyo, Laurent; Sivaramakrishnan, Anand

2015-01-10

The high angular resolution technique of non-redundant masking (NRM) or aperture masking interferometry (AMI) has yielded images of faint protoplanetary companions of nearby stars from the ground. AMI on James Webb Space Telescope (JWST)'s Near Infrared Imager and Slitless Spectrograph (NIRISS) has a lower thermal background than ground-based facilities and does not suffer from atmospheric instability. NIRISS AMI images are likely to have 90%-95% Strehl ratio between 2.77 and 4.8 μm. In this paper we quantify factors that limit the raw point source contrast of JWST NRM. We develop an analytic model of the NRM point spread function which includesmore » different optical path delays (pistons) between mask holes and fit the model parameters with image plane data. It enables a straightforward way to exclude bad pixels, is suited to limited fields of view, and can incorporate effects such as intra-pixel sensitivity variations. We simulate various sources of noise to estimate their effect on the standard deviation of closure phase, σ{sub CP} (a proxy for binary point source contrast). If σ{sub CP} < 10{sup –4} radians—a contrast ratio of 10 mag—young accreting gas giant planets (e.g., in the nearby Taurus star-forming region) could be imaged with JWST NIRISS. We show the feasibility of using NIRISS' NRM with the sub-Nyquist sampled F277W, which would enable some exoplanet chemistry characterization. In the presence of small piston errors, the dominant sources of closure phase error (depending on pixel sampling, and filter bandwidth) are flat field errors and unmodeled variations in intra-pixel sensitivity. The in-flight stability of NIRISS will determine how well these errors can be calibrated by observing a point source. Our results help develop efficient observing strategies for space-based NRM.« less

AT Cnc: A SECOND DWARF NOVA WITH A CLASSICAL NOVA SHELL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shara, Michael M.; Mizusawa, Trisha; Zurek, David

2012-10-20

We are systematically surveying all known and suspected Z Cam-type dwarf novae for classical nova shells. This survey is motivated by the discovery of the largest known classical nova shell, which surrounds the archetypal dwarf nova Z Camelopardalis. The Z Cam shell demonstrates that at least some dwarf novae must have undergone classical nova eruptions in the past, and that at least some classical novae become dwarf novae long after their nova thermonuclear outbursts, in accord with the hibernation scenario of cataclysmic binaries. Here we report the detection of a fragmented 'shell', 3 arcmin in diameter, surrounding the dwarf novamore » AT Cancri. This second discovery demonstrates that nova shells surrounding Z Cam-type dwarf novae cannot be very rare. The shell geometry is suggestive of bipolar, conical ejection seen nearly pole-on. A spectrum of the brightest AT Cnc shell knot is similar to that of the ejecta of the classical nova GK Per, and of Z Cam, dominated by [N II] emission. Galaxy Evolution Explorer FUV imagery reveals a similar-sized, FUV-emitting shell. We determine a distance of 460 pc to AT Cnc, and an upper limit to its ejecta mass of {approx}5 Multiplication-Sign 10{sup -5} M {sub Sun }, typical of classical novae.« less

Multilevel Optimization Framework for Hierarchical Stiffened Shells Accelerated by Adaptive Equivalent Strategy

NASA Astrophysics Data System (ADS)

Wang, Bo; Tian, Kuo; Zhao, Haixin; Hao, Peng; Zhu, Tianyu; Zhang, Ke; Ma, Yunlong

2017-06-01

In order to improve the post-buckling optimization efficiency of hierarchical stiffened shells, a multilevel optimization framework accelerated by adaptive equivalent strategy is presented in this paper. Firstly, the Numerical-based Smeared Stiffener Method (NSSM) for hierarchical stiffened shells is derived by means of the numerical implementation of asymptotic homogenization (NIAH) method. Based on the NSSM, a reasonable adaptive equivalent strategy for hierarchical stiffened shells is developed from the concept of hierarchy reduction. Its core idea is to self-adaptively decide which hierarchy of the structure should be equivalent according to the critical buckling mode rapidly predicted by NSSM. Compared with the detailed model, the high prediction accuracy and efficiency of the proposed model is highlighted. On the basis of this adaptive equivalent model, a multilevel optimization framework is then established by decomposing the complex entire optimization process into major-stiffener-level and minor-stiffener-level sub-optimizations, during which Fixed Point Iteration (FPI) is employed to accelerate convergence. Finally, the illustrative examples of the multilevel framework is carried out to demonstrate its efficiency and effectiveness to search for the global optimum result by contrast with the single-level optimization method. Remarkably, the high efficiency and flexibility of the adaptive equivalent strategy is indicated by compared with the single equivalent strategy.

C/sub 60/La: a deflated soccer ball

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cox, D.M.; Trevor, D.J.; Reichmann, K.C.

1986-04-30

A recent paper reported very exciting results; the production and detection of C/sub n/La complexes, n = 44, 46, 48,...76, with n = 60 the dominant species. For the dominant C/sub n/La species, C/sub 60/La, the metal atom was postulated, on the basis of the experimental photoionization mass spectroscopy data, to be strongly bound within a spheroidal carbon shell possessing unusually high stability. In this paper we present further experimental evidence which when added to the information presented by HOZLCKTS and Kroto et al. (KHOCS) seriously challenges this enticing conclusion.

Deformation effect in the fast neutron total cross section of aligned /sup 59/Co

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fasoli, U.; Pavan, P.; Toniolo, D.

1983-05-01

The variation of the total neutron cross section, ..delta..sigma/sub align/, on /sup 59/Co due to nuclear alignment of the target has been measured over the energy range from 0.8 to 20 MeV employing a cobalt single crystal with a 34% nuclear alignment. The results show that ..delta..sigma/sub align/ oscillates from a minimum of -5% at about 2.5 MeV to a maximum of +1% at about 10 MeV. The data were successfully fitted by optical model coupled-channel calculations. The coupling terms were deduced from a model representing the /sup 59/Co nucleus as a vibrational /sup 60/Ni core coupled to a protonmore » hole in a (1f/sub 7/2/) shell, without free parameters. The optical model parameters were determined by fitting the total cross section, which was independently measured. The theoretical calculations show that, at lower energies, ..delta..sigma/sub align/ depends appreciably on the coupling with the low-lying levels.« less

Effect of CeLa addition on the microstructures and mechanical properties of Al-Cu-Mn-Mg-Fe alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, Jiandi

Development of high strength lithium battery shell alloy is highly desired for new energy automobile industry. The microstructures and mechanical properties of Al-Cu-Mn-Mg-Fe alloy with different CeLa additions were investigated through optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Rietveld refinement and tensile testing. Experimental results indicate that Al{sub 8}Cu{sub 4}Ce and Al{sub 6}Cu{sub 6}La phases formed due to CeLa addition. Addition of 0.25 wt.% CeLa could promote the formation of denser precipitation of Al{sub 20}Cu{sub 2}Mn{sub 3} and Al{sub 6}(Mn, Fe) phases, which improved the mechanical properties of the alloy at room temperature.more » However, up to 0.50 wt.% CeLa addition could promote the formation of coarse Al{sub 8}Cu{sub 4}Ce phase, Al{sub 6}Cu{sub 6}La phase and Al{sub 6}(Mn, Fe) phase, which resulted in weakened mechanical properties. - Highlights: •Al-Cu-Mn-Mg-Fe alloys with different CeLa addition were fabricated through casting and rolling. •Al{sub 8}Cu{sub 4}Ce and Al{sub 6}Cu{sub 6}La phases formed after CeLa addition. •Addition of 0.25 wt.% CeLa promoted formation of denser precipitates of Al{sub 20}Cu{sub 2}Mn{sub 3} and Al{sub 6}(Mn, Fe). •Mechanical properties of the alloy was improved after 0.25 wt.% CeLa addition.« less

On the thermo-chemical origin of the stratified region at the top of the Earth's core

NASA Astrophysics Data System (ADS)

Nakagawa, Takashi

2018-03-01

I developed a combined model of the thermal and chemical evolution of the Earth's core and investigated its influence on a thermochemically stable region beneath the core-mantle boundary (CMB). The chemical effects of the growing stable region are caused by the equilibrium chemical reaction between silicate and the metallic core. The thermal effects can be characterized by the growth of the sub-isentropic shell, which may have a rapid growth rate compared to that of the chemically stable region. When the present-day CMB heat flow was varied, the origin of the stable region changed from chemical to thermochemical to purely thermal because the rapid growth of the sub-isentropic shell can replace the chemically stable region. Physically reasonable values of the present-day CMB heat flow that can maintain the geodynamo action over 4 billion years should be between 8 and 11 TW. To constrain the thickness of the thermochemically stable region beneath the CMB, the chemical diffusivity is important and should be ∼O(10-8) m2/s to obtain a thickness of the thermochemically stable region beneath the CMB consistent with that inferred from geomagnetic secular variations (140 km). However, the strength of the stable region found in this study is too high to be consistent with the constraint on the stability of the stable region inferred from geomagnetic secular variations.

Evidence for prevalent Z = 6 magic number in neutron-rich carbon isotopes.

PubMed

Tran, D T; Ong, H J; Hagen, G; Morris, T D; Aoi, N; Suzuki, T; Kanada-En'yo, Y; Geng, L S; Terashima, S; Tanihata, I; Nguyen, T T; Ayyad, Y; Chan, P Y; Fukuda, M; Geissel, H; Harakeh, M N; Hashimoto, T; Hoang, T H; Ideguchi, E; Inoue, A; Jansen, G R; Kanungo, R; Kawabata, T; Khiem, L H; Lin, W P; Matsuta, K; Mihara, M; Momota, S; Nagae, D; Nguyen, N D; Nishimura, D; Otsuka, T; Ozawa, A; Ren, P P; Sakaguchi, H; Scheidenberger, C; Tanaka, J; Takechi, M; Wada, R; Yamamoto, T

2018-04-23

The nuclear shell structure, which originates in the nearly independent motion of nucleons in an average potential, provides an important guide for our understanding of nuclear structure and the underlying nuclear forces. Its most remarkable fingerprint is the existence of the so-called magic numbers of protons and neutrons associated with extra stability. Although the introduction of a phenomenological spin-orbit (SO) coupling force in 1949 helped in explaining the magic numbers, its origins are still open questions. Here, we present experimental evidence for the smallest SO-originated magic number (subshell closure) at the proton number six in 13-20 C obtained from systematic analysis of point-proton distribution radii, electromagnetic transition rates and atomic masses of light nuclei. Performing ab initio calculations on 14,15 C, we show that the observed proton distribution radii and subshell closure can be explained by the state-of-the-art nuclear theory with chiral nucleon-nucleon and three-nucleon forces, which are rooted in the quantum chromodynamics.

50 CFR 660.360 - Recreational fishery-management measures.

Code of Federal Regulations, 2013 CFR

2013-10-01

... authorized for recreational fishing are hook-and-line and spear. Spears may be propelled by hand or by... at § 660.70, subpart C, on dates when the closure is in effect. The closure is not in effect at this... coordinates at § 660.70, subpart C, on dates when the closure is in effect. The closure is not in effect at...

50 CFR 660.360 - Recreational fishery-management measures.

Code of Federal Regulations, 2014 CFR

2014-10-01

... authorized for recreational fishing are hook-and-line and spear. Spears may be propelled by hand or by... at § 660.70, subpart C, on dates when the closure is in effect. The closure is not in effect at this... coordinates at § 660.70, subpart C, on dates when the closure is in effect. The closure is not in effect at...

Optically enhanced SnO{sub 2}/CdSe core/shell nanostructures grown by sol-gel spin coating method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Vijay, E-mail: vijaynadda83@gmail.com; Goswami, Y. C.; Rajaram, P.

2015-08-28

Synthesis of SnO{sub 2}/CdSe metal oxide/ chalcogenide nanostructures on glass micro slides using ultrasonic sol-gel process followed by spin coating has been reported. Stannous chloride, cadmium chloride and selenium dioxide compounds were used for Sn, Cd and Se precursors respectively. Ethylene glycol was used as complexing agent. The samples were characterized by XRD, SEM, AFM and UV-spectrophotometer. All the peaks shown in diffractograms are identified for SnO{sub 2}. Peak broadening observed in core shell due to stress behavior of CdSe lattice. Scanning electron microscope and AFM exhibits the conversion of cluster in to nanorods structures forms. Atomic force microscope showsmore » the structures in nanorods form and a roughness reduced 1.5194 nm by the deposition of CdSe. Uv Visible spectra shows a new absorption edge in the visible region make them useful for optoelectronic applications.« less

Cooperative bi-exponential decay of dye emission coupled via plasmons.

PubMed

Lyvers, David P; Moazzezi, Mojtaba; de Silva, Vashista C; Brown, Dean P; Urbas, Augustine M; Rostovtsev, Yuri V; Drachev, Vladimir P

2018-06-22

Bi-exponential decay of dye fluorescence near the surface of plasmonic metamaterials and core-shell nanoparticles is shown to be an intrinsic property of the coupled system. Indeed, the Dicke, cooperative states involve two groups of transitions: super-radiant, from the most excited to the ground states and sub-radiant, which cannot reach the ground state. The relaxation in the sub-radiant system occurs mainly due to the interaction with the plasmon modes. Our theory shows that the relaxation leads to the population of the sub-radiant states by dephasing the super-radiant Dicke states giving rise to the bi-exponential decay in agreement with the experiments. We use a set of metamaterial samples consisting of gratings of paired silver nanostrips coated with Rh800 dye molecules, having resonances in the same spectral range. The bi-exponential decay is demonstrated for Au\\SiO 2 \\ATTO655 core-shell nanoparticles as well, which persists even when averaging over a broad range of the coupling parameter.

Ionization competition effects on population distribution and radiative opacity of mixture plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Yongjun; Gao, Cheng; Tian, Qinyun

2015-11-15

Ionization competition arising from the electronic shell structures of various atomic species in the mixture plasmas was investigated, taking SiO{sub 2} as an example. Using a detailed-level-accounting approximation, we studied the competition effects on the charge state population distribution and spectrally resolved and Planck and Rosseland mean radiative opacities of mixture plasmas. A set of coupled equations for ionization equilibria that include all components of the mixture plasmas are solved to determine the population distributions. For a given plasma density, competition effects are found at three distinct temperature ranges, corresponding to the ionization of M-, L-, and K-shell electrons ofmore » Si. Taking the effects into account, the spectrally resolved and Planck and Rosseland mean opacities are systematically investigated over a wide range of plasma densities and temperatures. For a given mass density, the Rosseland mean decreases monotonically with plasma temperature, whereas Planck mean does not. Although the overall trend is a decrease, the Planck mean increases over a finite intermediate temperature regime. A comparison with the available experimental and theoretical results is made.« less

Phase separation in SiGe nanocrystals embedded in SiO{sub 2} matrix during high temperature annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mogaddam, N. A. P.; Turan, R.; Alagoz, A. S.

2008-12-15

SiGe nanocrystals have been formed in SiO{sub 2} matrix by cosputtering Si, Ge, and SiO{sub 2} independently on Si substrate. Effects of the annealing time and temperature on structural and compositional properties are studied by transmission electron microscopy, x-ray diffraction (XRD), and Raman spectroscopy measurements. It is observed that Ge-rich Si{sub (1-x)}Ge{sub x} nanocrystals do not hold their compositional uniformity when annealed at high temperatures for enough long time. A segregation process leading to separation of Ge and Si atoms from each other takes place. This process has been evidenced by a double peak formation in the XRD and Ramanmore » spectra. We attributed this phase separation to the differences in atomic size, surface energy, and surface diffusion disparity between Si and Ge atoms leading to the formation of nonhomogenous structure consist of a Si-rich SiGe core covered by a Ge-rich SiGe shell. This experimental observation is consistent with the result of reported theoretical and simulation methods.« less

On the Accuracy of Probabilistic Bucking Load Prediction

NASA Technical Reports Server (NTRS)

Arbocz, Johann; Starnes, James H.; Nemeth, Michael P.

2001-01-01

The buckling strength of thin-walled stiffened or unstiffened, metallic or composite shells is of major concern in aeronautical and space applications. The difficulty to predict the behavior of axially compressed thin-walled cylindrical shells continues to worry design engineers as we enter the third millennium. Thanks to extensive research programs in the late sixties and early seventies and the contributions of many eminent scientists, it is known that buckling strength calculations are affected by the uncertainties in the definition of the parameters of the problem such as definition of loads, material properties, geometric variables, edge support conditions, and the accuracy of the engineering models and analysis tools used in the design phase. The NASA design criteria monographs from the late sixties account for these design uncertainties by the use of a lump sum safety factor. This so-called 'empirical knockdown factor gamma' usually results in overly conservative design. Recently new reliability based probabilistic design procedure for buckling critical imperfect shells have been proposed. It essentially consists of a stochastic approach which introduces an improved 'scientific knockdown factor lambda(sub a)', that is not as conservative as the traditional empirical one. In order to incorporate probabilistic methods into a High Fidelity Analysis Approach one must be able to assess the accuracy of the various steps that must be executed to complete a reliability calculation. In the present paper the effect of size of the experimental input sample on the predicted value of the scientific knockdown factor lambda(sub a) calculated by the First-Order, Second-Moment Method is investigated.

Closed-Shell Polycyclic Aromatic Hydrocarbon Cations: A New Category of Interstellar Polycyclic Aromatic Hydrocarbons

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; Bauschlicher, Charles W., Jr.; Allamandola, Louis J.; DeVincenzi, Donald (Technical Monitor)

2001-01-01

Density functional theory has been employed to calculate the harmonic frequencies and intensities of a range of polycyclic aromatic hydrocarbon (PAH) cations that explore both size and electronic structure effects of the infrared spectroscopic properties of these species. The sample extends the size range of PAH species considered to more than 50 carbon atoms and includes several representatives from each of two heretofore unexplored categories of PAH cations: (1) fully benzenoid PAH cations whose carbon skeleton is composed of an odd number of carbon atoms (C(sub odd) PAHs); and (2) protonated PAH cations (HPAH+). Unlike the radical electronic structures of the PAH cations that have been the subject of previous theoretical and experimental work, the species in these two classes have a closed-shell electronic configuration. The calculated spectra of circumcoronene, C54H18 in both neutral and (radical) cationic form are also reported and compared with those of the other species. Overall, the C(sub odd) PAHs spectra are dominated by strong CC stretching modes near 1600 cm(exp -1) and display spectra that are remarkably insensitive to molecular size. The HPAH+ species evince a more complex spectrum consistent with the added contributions of aliphatic modes and their generally lower symmetry. Finally, for both classes of closed-shell cations, the intensity of the aromatic CH stretching modes is found to increase with molecular size far out of proportion with the number of CH groups, approaching a value more typical of neutral PAHs for the largest species studied.

Substantial Impact of School Closure on the Transmission Dynamics during the Pandemic Flu H1N1-2009 in Oita, Japan

PubMed Central

2015-01-01

Background School closure is considered as an effective measure to prevent pandemic influenza. Although Japan has implemented many class, grade, and whole school closures during the early stage of the pandemic 2009, the effectiveness of such a school closure has not been analysed appropriately. In addition, analysis based on evidence or data from a large population has yet to be performed. We evaluated the preventive effect of school closure against the pandemic (H1N1) 2009 and examined efficient strategies of reactive school closure. Materials and Methods Data included daily reports of reactive school closures and the number of infected students in the pandemic in Oita City, Japan. We used a regression model that incorporated a time delay to analyse the daily data of school closure based on a time continuous susceptible-exposed-infected-removed model of infectious disease spread. The delay was due to the time-lag from transmission to case reporting. We simulated the number of students infected daily with and without school closure and evaluated the effectiveness. Results The model with a 3-day delay from transmission to reporting yielded the best fit using R 2 (the coefficient of determination). This result suggests that the recommended period of school closure is more than 4 days. Moreover, the effect of school closure in the simulation of school closure showed the following: the number of infected students decreased by about 24% at its peak, and the number of cumulative infected students decreased by about 8.0%. Conclusions School closure was an effective intervention for mitigating the spread of influenza and should be implemented for more than 4 days. School closure has a remarkable impact on decreasing the number of infected students at the peak, but it does not substantially decrease the total number of infected students. PMID:26669757

Three dimensional equilibrium solutions for a current-carrying reversed-field pinch plasma with a close-fitting conducting shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koliner, J. J.; Boguski, J., E-mail: boguski@wisc.edu; Anderson, J. K.

2016-03-15

In order to characterize the Madison Symmetric Torus (MST) reversed-field pinch (RFP) plasmas that bifurcate to a helical equilibrium, the V3FIT equilibrium reconstruction code was modified to include a conducting boundary. RFP plasmas become helical at a high plasma current, which induces large eddy currents in MST's thick aluminum shell. The V3FIT conducting boundary accounts for the contribution from these eddy currents to external magnetic diagnostic coil signals. This implementation of V3FIT was benchmarked against MSTFit, a 2D Grad-Shafranov solver, for axisymmetric plasmas. The two codes both fit B{sub θ} measurement loops around the plasma minor diameter with qualitative agreementmore » between each other and the measured field. Fits in the 3D case converge well, with q-profile and plasma shape agreement between two distinct toroidal locking phases. Greater than 60% of the measured n = 5 component of B{sub θ} at r = a is due to eddy currents in the shell, as calculated by the conducting boundary model.« less

Comparison of Large eddy dynamo simulation using dynamic sub-grid scale (SGS) model with a fully resolved direct simulation in a rotating spherical shell

NASA Astrophysics Data System (ADS)

Matsui, H.; Buffett, B. A.

2017-12-01

The flow in the Earth's outer core is expected to have vast length scale from the geometry of the outer core to the thickness of the boundary layer. Because of the limitation of the spatial resolution in the numerical simulations, sub-grid scale (SGS) modeling is required to model the effects of the unresolved field on the large-scale fields. We model the effects of sub-grid scale flow and magnetic field using a dynamic scale similarity model. Four terms are introduced for the momentum flux, heat flux, Lorentz force and magnetic induction. The model was previously used in the convection-driven dynamo in a rotating plane layer and spherical shell using the Finite Element Methods. In the present study, we perform large eddy simulations (LES) using the dynamic scale similarity model. The scale similarity model is implement in Calypso, which is a numerical dynamo model using spherical harmonics expansion. To obtain the SGS terms, the spatial filtering in the horizontal directions is done by taking the convolution of a Gaussian filter expressed in terms of a spherical harmonic expansion, following Jekeli (1981). A Gaussian field is also applied in the radial direction. To verify the present model, we perform a fully resolved direct numerical simulation (DNS) with the truncation of the spherical harmonics L = 255 as a reference. And, we perform unresolved DNS and LES with SGS model on coarser resolution (L= 127, 84, and 63) using the same control parameter as the resolved DNS. We will discuss the verification results by comparison among these simulations and role of small scale fields to large scale fields through the role of the SGS terms in LES.

STREAM INJECTION INTO FRACTURE BEDROCK AT LORING AFB

EPA Science Inventory

The Quarry at the former Loring Air Force Base in Limestone, Maine, was used for the disposal of drums containing spent chlorinated solvents, mainly tetrachloroethene (PCE). After closure of the base, surface geophysics were used to locate the drums, and they were removed. Subs...

WHAT IS THE SHELL AROUND R CORONAE BOREALIS?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montiel, Edward J.; Clayton, Geoffrey C.; Marcello, Dominic C.

2015-07-15

The hydrogen-deficient, carbon-rich R Coronae Borealis (RCB) stars are known for being prolific producers of dust which causes their large iconic declines in brightness. Several RCB stars, including R Coronae Borealis (R CrB), itself, have large extended dust shells seen in the far-infrared. The origin of these shells is uncertain but they may give us clues to the evolution of the RCB stars. The shells could form in three possible ways. (1) They are fossil Planetary Nebula (PN) shells, which would exist if RCB stars are the result of a final, helium-shell flash, (2) they are material left over frommore » a white-dwarf (WD) merger event which formed the RCB stars, or (3) they are material lost from the star during the RCB phase. Arecibo 21 cm observations establish an upper limit on the column density of H I in the R CrB shell implying a maximum shell mass of ≲0.3 M{sub ☉}. A low-mass fossil PN shell is still a possible source of the shell although it may not contain enough dust. The mass of gas lost during a WD merger event will not condense enough dust to produce the observed shell, assuming a reasonable gas-to-dust ratio. The third scenario where the shell around R CrB has been produced during the star’s RCB phase seems most likely to produce the observed mass of dust and the observed size of the shell. But this means that R CrB has been in its RCB phase for ∼10{sup 4} years.« less

Effective Numerical Methods for Solving Elliptical Problems in Strengthened Sobolev Spaces

NASA Technical Reports Server (NTRS)

D'yakonov, Eugene G.

1996-01-01

Fourth-order elliptic boundary value problems in the plane can be reduced to operator equations in Hilbert spaces G that are certain subspaces of the Sobolev space W(sub 2)(exp 2)(Omega) is identical with G(sup (2)). Appearance of asymptotically optimal algorithms for Stokes type problems made it natural to focus on an approach that considers rot w is identical with (D(sub 2)w - D(sub 1)w) is identical with vector of u as a new unknown vector-function, which automatically satisfies the condition div vector of u = 0. In this work, we show that this approach can also be developed for an important class of problems from the theory of plates and shells with stiffeners. The main mathematical problem was to show that the well-known inf-sup condition (normal solvability of the divergence operator) holds for special Hilbert spaces. This result is also essential for certain hydrodynamics problems.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adib, F.; Bagreev, A.; Bandosz, T.J.

The H{sub 2}S breakthrough capacity was measured on two series of activated carbons of a coconut shell and a bituminous coal origins. To broaden the spectrum of surface features the samples were oxidized using nitric acid or ammonium persulfate under conditions chosen to preserve their pore structures. Then the carbons were characterized using Boehm titration, potentiometric titration, thermal analysis, temperature programmed desorption, sorption of nitrogen, and sorption of water. It was found that the choice of unimpregnated carbon for application as H{sub 2}S adsorbent should be made based on parameters of its acidity such as number of acidic groups, pHmore » of surface, amount of surface groups oxygen, or weight loss associated to decomposition of surface oxygen species. The results obtained from the analyses of six unimpregnated carbon samples suggest that there are certain threshold values of these quantities which, when exceeded, have a dramatic effect on the H{sub 2}S breakthrough capacity.« less

Sol–gel auto-combustion synthesis of PVP/CoFe{sub 2}O{sub 4} nanocomposite and its magnetic characterization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kurtan, U.; Topkaya, R., E-mail: rtopkaya@gyte.edu.tr; Baykal, A.

2013-11-15

Graphical abstract: - Highlights: • The Poly(vinyl pyrrolidone) (PVP) was used as a surface capping agent. • PVP/CoFe{sub 2}O{sub 4} nanocomposite was synthesized by a sol-gel auto-combustion method. • The existence of the spin-disordered surface layer was established. - Abstract: Poly(vinyl pyrrolidone)/CoFe{sub 2}O{sub 4} nanocomposite has been fabricated by a sol–gel auto-combustion method. Poly(vinyl pyrrolidone) was used as a reducing agent as well as a surface capping agent to prevent particle aggregation and stabilize the particles. The average crystallite size estimated from X-ray line profile fitting was found to be 20 ± 7 nm. The high field irreversibility and unsaturatedmore » magnetization behaviours indicate the presence of the core–shell structure in the sample. The exchange bias effect observed at 10 K suggests the existence of the magnetically aligned core surrounded by spin-disordered surface layer. The reduced remanent magnetization value of 0.6 at 10 K (higher than the theoretical value of 0.5) shows the PVP/CoFe{sub 2}O{sub 4} nanocomposite to have cubic magnetocrystalline anisotropy according to the Stoner–Wohlfarth model.« less

Rate of Iron Transfer Through the Horse Spleen Ferritin Shell Determined by the Rate of Formation of Prussian Blue and Fe-desferrioxamine Within the Ferritin Cavity

NASA Technical Reports Server (NTRS)

Zhang, Bo; Watt, Richard K.; Galvez, Natividad; Dominquez-Vera, Jose M.; Watt, Gerald D.

2005-01-01

Iron (2+ and 3+) is believed to transfer through the three-fold channels in the ferritin shell during iron deposition and release in animal ferritins. However, the rate of iron transit in and out through these channels has not been reported. The recent synthesis of [Fe(CN)(sub 6)](3-), Prussian Blue (PB) and desferrioxamine (DES) all trapped within the horse spleen ferritin (HoSF) interior makes these measurements feasible. We report the rate of Fe(2+) penetrating into the ferritin interior by adding external Fe(2+) to [Fe(CN)(sub 6)](3-) encapsulated in the HoSF interior and measuring the rate of formation of the resulting encapsulated PB. The rate at which Fe(2+) reacts with [Fe(CN)(sub 6)](3-) in the HoSF interior is much slower than the formation of free PB in solution and is proceeded by a lag period. We assume this lag period and the difference in rate represent the transfer of Fe(2+) through the HoSF protein shell. The calculated diffusion coefficient, D approx. 5.8 x 10(exp -20) square meters per second corresponds to the measured lag time of 10-20 s before PB forms within the HoSF interior. The activation energy for Fe(2+) transfer from the outside solution through the protein shell was determined to be 52.9 kJ/mol by conducting the reactions at 10 to approximately 40 C. The reaction of Fe(3+) with encapsulated [Fe(CN)6](4-) also readily forms PB in the HoSF interior, but the rate is faster than the corresponding Fe(2+) reaction. The rate for Fe(3+) transfer through the ferritin shell was confirmed by measuring the rate of the formation of Fe-DES inside HoSF and an activation energy of 58.4 kJ/mol was determined. An attempt was made to determine the rate of iron (2+ and 3+) transit out from the ferritin interior by adding excess bipyridine or DES to PB trapped within the HoSF interior. However, the reactions are slow and occur at almost identical rates for free and HoSF-encapsulated PB, indicating that the transfer of iron from the interior through the protein shell is faster than the rate-limiting step of PB dissociation. The method described in this work presents a novel way of determining the rate of transfer of iron and possibly other small molecules through the ferritin shell.

Measurement of the sizes of circumstellar dust shells around evolved stars with high mass loss rates

NASA Technical Reports Server (NTRS)

Phillips, T. G.; Knapp, G. R.

1992-01-01

The research supported by the NASA ADP contract NAG5-1153 has been completed. The attached paper, which will be submitted for publication in the Astrophysical Journal in January 1992, presents the results of this work. Here is a summary of the project and its results. A set of computer programs was developed to process the raw 60 micron and 100 micron IRAS survey data. The programs were designed to detect faint extended emission surrounding a bright unresolved source. Candidate objects were chosen from a list of red giant stars and young planetary nebulae which have been detected in millimeter/submillimeter lines of CO. Of the 279 stars examined, 55 were resolved at 60 microns. The principle results of the study are given. The average age for the shells surrounding the 9 Mira-type stars which are extended is 6 x 10(exp 4) yr. This suggests that the period during which these stars lose mass lasts for approx 10(exp 5) yr. The oldest shell found surrounds U Ori, and the youngest surrounds Mira itself. Some shells appear to be detached from the central star. This phenomenon is more common among older stars, suggesting that the mass loss becomes more episodic as the star sheds its envelope. Although all 8 stars less distant than 200 pc are resolved in the IRAS 60 micron data, 29 stars within 500 pc were not. These stars probably have younger circumstellar shells than those which were resolved. Almost all the carbon stars with distances of 500 pc or less have resolved shells, while only 1/2 of the oxygen-rich stars do. The resolved carbon star shells also are older on average than the oxygen-rich ones. These facts imply that carbon stars have been losing mass for a longer period, on average, than oxygen-rich red giants. Large circumstellar shells tend to be found at large distances from the galactic plane, confirming that the ISM density limits the size to which a dust shell can grow. Surprisingly, even very large shells seem to be nearly spherical, and do not appear to be distorted by ram-pressure caused by the star's motion with respect to the ISM. Radiative transfer models and the value of I sub 60 microns/I sub 100 microns allow the average dust temperature in the outer regions of a circumstellar shell to be estimated. The typical value obtained in about 35 K.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makarov, Nikolay S.; Lin, Qianglu; Pietryga, Jeffrey M.

One source of efficiency losses in photovoltaic cells is their transparency toward solar photons with energies below the band gap of the absorbing layer. This loss can be reduced using a process of up-conversion whereby two or more sub-band-gap photons generate a single above-gap exciton. Traditional approaches to up-conversion, such as nonlinear two-photon absorption (2PA) or triplet fusion, suffer from low efficiency at solar light intensities, a narrow absorption bandwidth, nonoptimal absorption energies, and difficulties for implementing in practical devices. We show that these deficiencies can be alleviated using the effect of Auger up-conversion in thick-shell PbSe/CdSe quantum dots. Thismore » process relies on Auger recombination whereby two low-energy, core-based excitons are converted into a single higher-energy, shell-based exciton. When compared to their monocomponent counterparts, the tailored PbSe/CdSe heterostructures feature enhanced absorption cross-sections, a higher efficiency of the “productive” Auger pathway involving re-excitation of a hole, and longer lifetimes of both core- and shell-localized excitons. These features lead to effective up-conversion cross-sections that are more than 6 orders of magnitude higher than for standard nonlinear 2PA, which allows for efficient up-conversion of continuous wave infrared light at intensities as low as a few watts per square centimeter.« less

BFV-BRST quantization of two-dimensional supergravity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fujiwara, T.; Igarashi, Y.; Kuriki, R.

1996-01-01

Two-dimensional supergravity theory is quantized as an anomalous gauge theory. In the Batalin-Fradkin (BF) formalism, the anomaly-canceling super-Liouville fields are introduced to identify the original second-class constrained system with a gauge-fixed version of a first-class system. The BFV-BRST quantization applies to formulate the theory in the most general class of gauges. A local effective action constructed in the configuration space contains two super-Liouville actions; one is a noncovariant but local functional written only in terms of two-dimensional supergravity fields, and the other contains the super-Liouville fields canceling the super-Weyl anomaly. Auxiliary fields for the Liouville and the gravity supermultiplets aremore » introduced to make the BRST algebra close off-shell. Inclusion of them turns out to be essentially important especially in the super-light-cone gauge fixing, where the supercurvature equations ({partial_derivative}{sup 3}{sub {minus}}{ital g}{sub +}{sub +}={partial_derivative}{sup 2}{sub {minus}}{chi}{sub +}{sub +}=0) are obtained as a result of BRST invariance of the theory. Our approach reveals the origin of the OSp(1,2) current algebra symmetry in a transparent manner. {copyright} {ital 1996 The American Physical Society.}« less

Polarizabilities and van der Waals C{sub 6} coefficients of fullerenes from an atomistic electrodynamics model: Anomalous scaling with number of carbon atoms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saidi, Wissam A., E-mail: alsaidi@pitt.edu; Norman, Patrick

2016-07-14

The van der Waals C{sub 6} coefficients of fullerenes are shown to exhibit an anomalous dependence on the number of carbon atoms N such that C{sub 6} ∝ N{sup 2.2} as predicted using state-of-the-art quantum mechanical calculations based on fullerenes with small sizes, and N{sup 2.75} as predicted using a classical-metallic spherical-shell approximation of the fullerenes. We use an atomistic electrodynamics model where each carbon atom is described by a polarizable object to extend the quantum mechanical calculations to larger fullerenes. The parameters of this model are optimized to describe accurately the static and complex polarizabilities of the fullerenes bymore » fitting against accurate ab initio calculations. This model shows that C{sub 6} ∝ N{sup 2.8}, which is supportive of the classical-metallic spherical-shell approximation. Additionally, we show that the anomalous dependence of the polarizability on N is attributed to the electric charge term, while the dipole–dipole term scales almost linearly with the number of carbon atoms.« less

Exact analytical solution of shear-induced flexural vibration of functionally graded piezoelectric beam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Pankaj, E-mail: psharma@rtu.ac.in; Parashar, Sandeep Kumar, E-mail: parashar2@yahoo.com

The priority of this paper is to obtain the exact analytical solution for free flexural vibration of FGPM beam actuated using the d{sub 15} effect. In piezoelectric actuators, the potential use of d{sub 15} effect has been of particular interest for engineering applications since shear piezoelectric coefficient d15 is much higher than the other piezoelectric coupling constants d{sub 31} and d{sub 33}. The applications of shear actuators are to induce and control the flexural vibrations of beams and plates. In this study, a modified Timoshenko beam theory is used where electric potential is assumed to vary sinusoidaly along the thicknessmore » direction. The material properties are assumed to be graded across the thickness in accordance with power law distribution. Hamilton's principle is employed to obtain the equations of motion along with the associated boundary conditions for FGPM beams. Exact analytical solution is derived thus obtained equations of motion. Results for clamped-clamped and clamped-free boundary conditions are presented. The presented result and method shell serve as benchmark for comparing the results obtained from the other approximate methods.« less

Influence of P{sub 2}O{sub 5} and Al{sub 2}O{sub 3} content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bourhis, Kevin, E-mail: k.bourhis@argolight.com; Massera, Jonathan; Petit, Laeticia

2015-03-15

Highlights: • Reorganization of the glass structure induced by the addition of P{sub 2}O{sub 5} or Al{sub 2}O{sub 3}. • Emission properties related to the presence of P or Al in the Er{sup 3+} coordination shell. • Declustering observed upon addition of P{sub 2}O{sub 5}. • No declustering upon addition of Al{sub 2}O{sub 3}. - Abstract: The effect of P{sub 2}O{sub 5} and/or Al{sub 2}O{sub 3} addition in Er-doped borosilicate glasses on the physical, thermal, optical, and luminescence properties is investigated. The changes in these glass properties are related to the glass structure modifications induced by the addition of P{submore » 2}O{sub 5} and/or Al{sub 2}O{sub 3}, which were probed by FTIR, {sup 11}B MAS NMR and X-ray photoelectron spectroscopies. Variations of the polymerization degree of the silicate tetrahedra and modifications in the {sup [3]}B/{sup [4]}B ratio are explained by a charge compensation mechanism due to the formation of AlO{sub 4}, PO{sub 4} groups and the formation of Al-O-P linkages in the glass network. From the absorption and luminescence properties of the Er{sup 3+} ions at 980 nm and 1530 nm, declustering is suspected for the highest P{sub 2}O{sub 5} concentrations while for the highest Al{sub 2}O{sub 3} concentrations no declustering is observed.« less

Resonant inelastic x-ray scattering on iso-C{sub 2}H{sub 2}Cl{sub 2} around the chlorine K-edge: Structural and dynamical aspects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawerk, Elie, E-mail: eliekawerk@hotmail.com, E-mail: ekawerk@units.it; Sorbonne Universités, UPMC Université Paris 06, UMR 7614, Laboratoire de Chimie Physique-Matière et Rayonnement, F-75005 Paris; Laboratoire de Physique Appliquée, Faculté des Sciences II, Université Libanaise, 90656 Jdeidet el Metn, Liban

2014-10-14

We report a theoretical and experimental study of the high resolution resonant K{sub α} X-ray emission lines around the chlorine K-edge in gas phase 1,1-dichloroethylene. With the help of ab initio electronic structure calculations and cross section evaluation, we interpret the lowest lying peak in the X-ray absorption and emission spectra. The behavior of the K{sub α} emission lines with respect to frequency detuning highlights the existence of femtosecond nuclear dynamics on the dissociative Potential Energy Surface of the first K-shell core-excited state.

X-ray production cross sections at incident photon energies across the M{sub i} (i=1-5) edges of {sub 90}Th

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaur, Rajnish; Shehla,; Kumar, Anil

2015-08-28

The X-ray production cross sections for the M{sub k} (k= ξ, δ, α, β, ζ, γ, m{sub 1}, m{sub 2}) groups of X-rays have been evaluated at incident photon energies across the M{sub i} (i =1-5) edges of {sub 90}Th using the relativistic Hartree-Fock-Slater model based photoionisation cross sections and recently reported values of the M-shell X-ray emission rates, fluorescence and Coster Kronig yields. Further, the energies of the prominent (M{sub i}-S{sub j}) (S{sub j}=N{sub j}, O{sub j} and i =1-3, j =1-7) resonant Raman scattered (RRS) peaks at different incident photon energies have also been evaluated using the neutral-atommore » electron binding energies (E{sub sj}) based on the relaxed orbital relativistic Hartree-Fock-Slater model.« less

Enhanced photocatalytic H{sub 2} evolution over CdS/Au/g-C{sub 3}N{sub 4} composite photocatalyst under visible-light irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ding, Xiaoling; University of Chinese Academy of Sciences, Beijing 100049; Li, Yingxuan, E-mail: yxli@ms.xjb.ac.cn, E-mail: cywang@ms.xjb.ac.cn

2015-10-01

A novel heterojunction structured composite photocatalyst CdS/Au/g-C{sub 3}N{sub 4} has been developed by depositing CdS/Au with a core (Au)-shell (CdS) structure on the surface of g-C{sub 3}N{sub 4}. The photocatalytic hydrogen production activity of the developed photocatalyst was evaluated under visible-light irradiation (λ > 420 nm) using methanol as a sacrificial reagent. As a result, its activity is about 125.8 times higher than that of g-C{sub 3}N{sub 4} and is even much higher than that of Pt/g-C{sub 3}N{sub 4}. The enhancement in photocatalytic activity is attributed to efficient separation of the photoexcited charges due to the anisotropic junction in themore » CdS/Au/g-C{sub 3}N{sub 4} system.« less

δ15N Values in Crassostrea virginica Shells Provides Early Direct Evidence for Nitrogen Loading to Chesapeake Bay

NASA Astrophysics Data System (ADS)

Black, H. D.; Andrus, C. F. T.; Lambert, W. J.; Rick, T. C.; Gillikin, D. P.

2017-03-01

Crassostrea virginica is one of the most common estuarine bivalves in the United States’ east coast and is frequently found in archaeological sites and sub-fossil deposits. Although there have been several sclerochronological studies on stable carbon and oxygen isotopes in the shells of this species, less is known about δ15N values within their shells, which could be a useful paleoenvironmental proxy to assess estuarine nitrogen dynamics. Modern C. virginica samples were collected in Chesapeake Bay for comparison with archaeological shells from nearby sites ranging in age from ~100 to 3,200 years old. Left valves were sampled by milling the hinge area and the resulting powder was analyzed for %N and δ15N values. Comparison of δ15N values between C. virginica shells shows relatively constant values from ~1250 BC to ~1800 AD. After ~1800 AD, there are rapid increases in 15N enrichment in the shells, which continue to increase in value up to the modern shell values. The increase in δ15N values is evidence of early anthropogenic impact in Chesapeake Bay. These results corroborate the observation that coastal nitrogen pollution occurred earlier than the 19th century and support the use of oyster shell δ15N values as a useful environmental proxy.

Projected shell model study on nuclei near the N = Z line

NASA Astrophysics Data System (ADS)

Sun, Y.

2003-04-01

Study of the N ≈ Z nuclei in the mass-80 region is not only interesting due to the existence of abundant nuclear-structure phenomena, but also important in understanding the nucleosynthesis in the rp-process. It is difficult to apply a conventional shell model due to the necessary involvement of the g 9/2 sub-shell. In this paper, the projected shell model is introduced to this study. Calculations are systematically performed for the collective levels as well as the quasi-particle excitations. It is demonstrated that calculations with this truncation scheme can achieve a comparable quality as the large-scale shell model diagonalizations for 48 Cr, but the present method can be applied to much heavier mass regions. While the known experimental data of the yrast bands in the N ≈ Z nuclei (from Se to Ru) are reasonably described, the present calculations predict the existence of high- K states, some of which lie low in energy under certain structure conditions.

Atomic-level simulation of ferroelectricity in perovskite solid solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sepliarsky, M.; Instituto de Fisica Rosario, CONICET-UNR, Rosario,; Phillpot, S. R.

2000-06-26

Building on the insights gained from electronic-structure calculations and from experience obtained with an earlier atomic-level method, we developed an atomic-level simulation approach based on the traditional Buckingham potential with shell model which correctly reproduces the ferroelectric phase behavior and dielectric and piezoelectric properties of KNbO{sub 3}. This approach now enables the simulation of solid solutions and defected systems; we illustrate this capability by elucidating the ferroelectric properties of a KTa{sub 0.5}Nb{sub 0.5}O{sub 3} random solid solution. (c) 2000 American Institute of Physics.

Role of atomistic structure in the stochastic nature of conductivity in substoichiometric tantalum pentoxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bondi, Robert J., E-mail: rjbondi@sandia.gov; Fox, Brian P.; Marinella, Matthew J.

2016-03-28

First-principles calculations of electrical conductivity (σ{sub o}) are revisited to determine the atomistic origin of its stochasticity in a distribution generated from sampling 14 ab-initio molecular dynamics configurations from 10 independently quenched models (n = 140) of substoichiometric amorphous Ta{sub 2}O{sub 5}, where each structure contains a neutral O monovacancy (V{sub O}{sup 0}). Structural analysis revealed a distinct minimum Ta-Ta separation (dimer/trimer) corresponding to each V{sub O}{sup 0} location. Bader charge decomposition using a commonality analysis approach based on the σ{sub o} distribution extremes revealed nanostructural signatures indicating that both the magnitude and distribution of cationic charge on the Ta subnetwork havemore » a profound influence on σ{sub o}. Furthermore, visualization of local defect structures and their electron densities reinforces these conclusions and suggests σ{sub o} in the amorphous oxide is best suppressed by a highly charged, compact Ta cation shell that effectively screens and minimizes localized V{sub O}{sup 0} interaction with the a-Ta{sub 2}O{sub 5} network; conversely, delocalization of V{sub O}{sup 0} corresponds to metallic character and high σ{sub o}. The random network of a-Ta{sub 2}O{sub 5} provides countless variations of an ionic configuration scaffold in which small perturbations affect the electronic charge distribution and result in a fixed-stoichiometry distribution of σ{sub o}; consequently, precisely controlled and highly repeatable oxide fabrication processes are likely paramount for advancement of resistive memory technologies.« less

All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures.

PubMed

Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng

2013-01-01

Noble metal nanoparticles stabilized by organic ligands are important for applications in assembly, site-specific bioconjugate labelling and sensing, drug delivery and medical therapy, molecular recognition and molecular electronics, and catalysis. Here we report crystal structures and theoretical analysis of three Ag44(SR)30 and three Au12Ag32(SR)30 intermetallic nanoclusters stabilized with fluorinated arylthiols (SR=SPhF, SPhF2 or SPhCF3). The nanocluster forms a Keplerate solid of concentric icosahedral and dodecahedral atom shells, protected by six Ag2(SR)5 units. Positive counterions in the crystal indicate a high negative charge of 4(-) per nanoparticle, and density functional theory calculations explain the stability as an 18-electron superatom shell closure in the metal core. Highly featured optical absorption spectra in the ultraviolet-visible region are analysed using time-dependent density functional perturbation theory. This work forms a basis for further understanding, engineering and controlling of stability as well as electronic and optical properties of these novel nanomaterials.

The influence of temperature on limestone sulfation and attrition under fluidized bed combustion conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montagnaro, Fabio; Salatino, Piero; Dipartimento di Ingegneria Chimica - Universita degli Studi di Napoli Federico II, Piazzale Vincenzo Tecchio 80, 80125 Napoli

2010-04-15

The influence of temperature on attrition of two limestones during desulfurization in a fluidized bed reactor was investigated. Differences in the microstructure of the two limestones were reflected by a different thickness of the sulfate shell formed upon sulfation and by a different value of the ultimate calcium conversion degree. Particle attrition and fragmentation were fairly small under moderately bubbling fluidization conditions for both limestones. An increase of temperature from 850 C to 900 C led to an increase of the attrition rate, most likely because of a particle weakening effect caused by a faster CO{sub 2} evolution during calcination.more » This weakening effect, however, was not sufficiently strong to enhance particle fragmentation in the bed. The progress of sulfation, associated to the build-up of a hard sulfate shell around the particles, led in any case to a decrease of the extent of attrition. Sulfation at 900 C was less effective than at 850 C, and this was shown to be related to the porosimetric features of the different samples. (author)« less

Near-Unity Quantum Yields of Biexciton Emission from CdSe=CdS Nanocrystals Measured Using Single-Particle Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Young-Shin; Malko, Anton V.; Vela, Javier

2011-05-03

Biexciton photoluminescence (PL) quantum yields (Q 2X) of individual CdSe/CdS core-shell nanocrystal quantum dots with various shell thicknesses are derived from independent PL saturation and two-photon correlation measurements. We observe a near-unity Q{sub 2X} for some nanocrystals with an ultrathick 19-monolayer shell. High Q 2X’s are, however, not universal and vary widely among nominally identical nanocrystals indicating a significant dependence of Q 2X upon subtle structural differences. Interestingly, our measurements indicate that high Q 2X’s are not required to achieve complete suppression of PL intensity fluctuations in individual nanocrystals.

Direct Reaction Measurements Using GODDESS

DOE PAGES

Pain, S. D.; Ratkiewicz, A.; Baugher, T.; ...

2017-10-26

GODDESS is a coupling of the charged-particle detection system ORRUBA to the gamma-ray detector array Gammasphere. This coupling has been developed in order to facilitate the high-resolution measurement of direct reactions in normal and inverse kinematics with stable and radioactive beams. GODDESS has been commissioned using a beam of 134Xe at 10 MeV/A, in a campaign of stable beam measurements. The measurement demonstrates the capabilities of GODDESS under radioactive beam conditions, and provides the first data on the single-neutron states in 135Xe, including previously unobserved states based on the orbitals above the N=82 shell closure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aydinol, M., E-mail: aydinolm@dicle.edu.tr; Aydeniz, D., E-mail: daydeniz@hotmail.com

L shell ionization cross section and {sub Li} subshells ionization cross sections of Os, Pt, Hg, Pb, Po atoms calculated. For each atom, ten different electron impacty energy values E{sub oi} used. Calculations carried out by using nonrelativistic Lotz equation in Matlab. Ionization cross section values obtained for Eoi values in the energy range of E{sub Li} ≤E{sub oi}≤4E{sub Li} for each atom. Starting allmost from E{sub oi} = E{sub Li} (i = 1,2,3) values of the each subshell ionization threshold energy, ionization cross section are increasing rapidly with E{sub oi}. For a fixed E{sub oi} = 3. E{sub Li}more » values, while Z increases from Z = 76 to Z = 84, ionization cross section are decrease. These results help to understand some results which obtained from other electron-sigle atom impact studies on σ{sub Li} subshells.« less

[Epidemiologic and economic effectiveness of school closure during influenza epidemics and pandemics].

PubMed

Gendon, Iu Z; Vasil'ev, Iu M

2012-01-01

Epidemiologic and economic effectiveness of school closure during influenza epidemics and pandemics is discussed. Optimal effect of school closure is observed when this measure is taken at the start of the epidemic or pandemic and for a sufficiently long time. School closure during high morbidity among schoolchildren, in the middle (at the peak) and by the end of epidemic or pandemic does not influence significantly the spread of influenza or morbidity. Significant economic losses and other negative consequences of school closure are noted. School closure may be the most appropriate during the emergence of influenza pandemic when the pandemic vaccine is not yet available, however timely mass immunization of schoolchildren against influenza may be a more appropriate measure than school closure for the reduction of influenza morbidity and spread during seasonal influenza epidemics.

GROWING WHITE DWARFS TO THE CHANDRASEKHAR LIMIT: THE PARAMETER SPACE OF THE SINGLE DEGENERATE SN Ia CHANNEL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hillman, Y.; Prialnik, D.; Kovetz, A.

Can a white dwarf (WD), accreting hydrogen-rich matter from a non-degenerate companion star, ever exceed the Chandrasekhar mass and explode as a SN Ia? We explore the range of accretion rates that allow a WD to secularly grow in mass, and derive limits on the accretion rate and on the initial mass that will allow it to reach 1.4M{sub ⊙}—the Chandrasekhar mass. We follow the evolution through a long series of hydrogen flashes, during which a thick helium shell accumulates. This determines the effective helium mass accretion rate for long-term, self-consistent evolutionary runs with helium flashes. We find that netmore » mass accumulation always occurs despite helium flashes. Although the amount of mass lost during the first few helium shell flashes is a significant fraction of that accumulated prior to the flash, that fraction decreases with repeated helium shell flashes. Eventually no mass is ejected at all during subsequent flashes. This unexpected result occurs because of continual heating of the WD interior by the helium shell flashes near its surface. The effect of heating is to lower the electron degeneracy throughout the WD, especially in the outer layers. This key result yields helium burning that is quasi-steady state, instead of explosive. We thus find a remarkably large parameter space within which long-term, self-consistent simulations show that a WD can grow in mass and reach the Chandrasekhar limit, despite its helium flashes.« less

Process for the preparation of methane and/or ethane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wagstaff, N.

1981-09-22

According to Shell, methane and ethane can be produced from a C/sub 2/-C/sub 4/ paraffin feed stream (such as the by-product of mineral-oil production) by contacting the stream with certain crystalline silicates at temperatures of 800/sup 0/-1200/sup 0/F and 145 psi pressure. The crystalline silicates must be specially prepared to obtain the required characteristics.

Investigation of ion kinetic effects in direct-drive exploding-pusher implosions at the NIF

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosenberg, M. J., E-mail: mrosenbe@mit.edu; Zylstra, A. B.; Séguin, F. H.

Measurements of yield, ion temperature, areal density (ρR), shell convergence, and bang time have been obtained in shock-driven, D{sub 2} and D{sup 3}He gas-filled “exploding-pusher” inertial confinement fusion (ICF) implosions at the National Ignition Facility to assess the impact of ion kinetic effects. These measurements probed the shock convergence phase of ICF implosions, a critical stage in hot-spot ignition experiments. The data complement previous studies of kinetic effects in shock-driven implosions. Ion temperature and fuel ρR inferred from fusion-product spectroscopy are used to estimate the ion-ion mean free path in the gas. A trend of decreasing yields relative to themore » predictions of 2D DRACO hydrodynamics simulations with increasing Knudsen number (the ratio of ion-ion mean free path to minimum shell radius) suggests that ion kinetic effects are increasingly impacting the hot fuel region, in general agreement with previous results. The long mean free path conditions giving rise to ion kinetic effects in the gas are often prevalent during the shock phase of both exploding pushers and ablatively driven implosions, including ignition-relevant implosions.« less

Effect of fiber and dye degradation products (FDP) on burn wound healing.

PubMed

Knox, F S; Wachtel, T L; McCahan, G R; Knapp, S C

1979-10-01

Upon exposure to the thermal environment of an aircraft fire, many fire retardant fabrics off-gas fiber and dye degradation products (FDP). Condensation of these products on human skin raises questions concerning possible deleterious effects on burn wound healing. A porcine bioassay was used to study the physiological effects of FDP. Selected areas of living skin, protected by dyed aromatic polyamides and polybenzimidazole fabrics, were exposed to a thermal source adjusted to simulate a postcrash JP-4 fuel fire. Burn sites contaminated with FDP were evaluated by clinical observation ane to begin epithelialization, time to closure of an open wound, and the amount and type of cicatrix formation. The experiment showed that each fabric has unique off-gasing products. The greatest amount of FDP was deposited on the skin when the skin was covered by a single layer of shell fabric separated by a 6.35-mm air gap. The presence of an intervening cotton T-shirt decreased the amount of FDP deposited on the skin. We found no evidence that FDP caused alterations in wound healing.

Masses from an inhomogeneous partial difference equation with higher-order isospin contributions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Masson, P.J.; Jaenecke, J.

In the present work, a mass equation obtained as the solution of an inhomogeneous partial difference equation is used to predict masses of unknown neutron-rich and proton-rich nuclei. The inhomogeneous source terms contain shell-dependent symmetry energy expressions (quadratic in isospin), and include, as well, an independently derived shell-model Coulomb energy equation which describes all known Coulomb displacement energies with a standarad deviation of sigma/sub c/ = 41 keV. Perturbations of higher order in isospin, previously recognized as a cause of systematic effects in long-range mass extrapolations, are also incorporated. The most general solutions of the inhomogeneous difference equation have beenmore » deduced from a chi/sup 2/-minimization procedure based on the recent atomic mass adjustment of Wapstra, Audi, and Hoekstra. Subjecting the solutions further to the condition of charge symmetry preserves the accuracy of Coulomb energies and allows mass predictions for nuclei with both Ngreater than or equal toZ and Z>N. The solutions correspond to a mass equation with 470 parameters. Using this equation, 4385 mass values have been calculated for nuclei with Agreater than or equal to16 (except N = Z = odd for A<40), with a standard deviation of sigma/sub m/ = 194 keV from the experimental masses. copyright 1988 Academic Press, Inc.« less

Microwave electromagnetic and absorption properties of SiO2/C core/shell composites plated with metal cobalt

NASA Astrophysics Data System (ADS)

Shen, Guozhu; Fang, Xumin; Wu, Hongyan; Wei, Hongyu; Li, Jingfa; Li, Kaipeng; Mei, Buqing; Xu, Yewen

2017-04-01

A facile method has been developed to fabricate magnetic core/shell SiO2/C/Co sub-microspheres via the pyrolysis of SiO2/PANI (polyaniline) and electroless plating method. The electromagnetic parameters of these SiO2/C and SiO2/C/Co composites were measured and the microwave reflection loss properties were evaluated in the frequency range of 2-18 GHz. The results show that the dielectric loss of SiO2/C composite increases with the increase of carbonization temperature and the magnetic loss enhances due to the deposition of cobalt on the SiO2/C sub-microspheres. The reflection loss results exhibit that the microwave absorption properties of the SiO2/C/Co composites are more excellent than those of SiO2/C composites for each thickness. The maximum effective absorption bandwidth (reflection loss ≤ -10 dB) arrives at 5.0 GHz (13.0-18 GHz) for SiO2/C/Co composite with 1.5 mm of thickness and the minimum reflection loss value is -24.0 dB at 5.0 GHz with 4.0 mm of thickness. The microwave loss mechanism of the SiO2/C/Co composites was also discussed in this paper.

Spectroastrometric Study of Ro-vibrational CO Emission from the Herbig Ae Star HD 179218 with ISHELL on the NASA Infrared Telescope Facility

NASA Astrophysics Data System (ADS)

Brittain, Sean D.; Carr, John S.; Najita, Joan R.

2018-07-01

We present analysis of commissioning M-band data acquired with the infrared echelle spectrograph (iSHELL) on NASA’s Infrared Telescope Facility. In this paper we describe the delivered performance of the instrument for these M-band observations and the data reduction process. The feasibility of using iSHELL for spectro-astrometry is tested on the Herbig Ae/Be star HD 179218 and we show that sub-milliarcsecond fidelity is achievable..

Preparation and Evaluation of Adsorbents from Coal and Irvingia gabonensis Seed Shell

NASA Astrophysics Data System (ADS)

Ezeokonkwo, Mercy A.; Ofor, Okechukwu F.; Ani, Julius U.

2017-12-01

The adsorption of Cd(II) and Pb(II) ions on adsorbents prepared from sub-bituminous coal, lignite and a blend of coal and Irvingia gabonensis seed shells was investigated. Fourier transform infrared, scanning electron microscope and X-ray fluorescence analyses implicated hydroxyl, carbonyl, Al2O3 and SiO2 as being responsible for binding the metal ions on the porous adsorbents. The optimum adsorption of carbonized lignite for the removal of Cd(II) and Pb(II) ions from aqueous media were 80.93% and 87.85%, respectively. Batch adsorption was done by effect of adsorbent dosage, pH, contact time, temperature, particle size, and initial concentration. Equilibrium for the removal of Pb(II) and Cd(II) was established within 100 and 120 min respectively. Blending the lignite-derived adsorbent with Irvingia gabonensis seed shell improved the performance significantly. More improvement was observed on modification of the blend using NaOH and H3PO4. Pb(II) was preferentially adsorbed than Cd(II) in all cases. Adsorption of Cd(II) and Pb(II) ions followed Langmuir isotherm. The kinetics of adsorption was best described by pseudo-second order model. The potential for using a blend of coal and agricultural byproduct (Irvingia gabonensis seed shell) was found to be a viable alternative for removal of toxic heavy metals from aqueous solutions.

Simulating school closure policies for cost effective pandemic decision making

PubMed Central

2012-01-01

Background Around the globe, school closures were used sporadically to mitigate the 2009 H1N1 influenza pandemic. However, such closures can detrimentally impact economic and social life. Methods Here, we couple a decision analytic approach with a mathematical model of influenza transmission to estimate the impact of school closures in terms of epidemiological and cost effectiveness. Our method assumes that the transmissibility and the severity of the disease are uncertain, and evaluates several closure and reopening strategies that cover a range of thresholds in school-aged prevalence (SAP) and closure durations. Results Assuming a willingness to pay per quality adjusted life-year (QALY) threshold equal to the US per capita GDP ($46,000), we found that the cost effectiveness of these strategies is highly dependent on the severity and on a willingness to pay per QALY. For severe pandemics, the preferred strategy couples the earliest closure trigger (0.5% SAP) with the longest duration closure (24 weeks) considered. For milder pandemics, the preferred strategies also involve the earliest closure trigger, but are shorter duration (12 weeks for low transmission rates and variable length for high transmission rates). Conclusions These findings highlight the importance of obtaining early estimates of pandemic severity and provide guidance to public health decision-makers for effectively tailoring school closures strategies in response to a newly emergent influenza pandemic. PMID:22713694

Planar dicyclic B{sub 6}S{sub 6}, B{sub 6}S{sub 6}{sup −}, and B{sub 6}S{sub 6}{sup 2−} clusters: Boron sulfide analogues of naphthalene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Da-Zhi; Bai, Hui; Ou, Ting

2015-01-07

Inorganic analogues of hydrocarbons or polycyclic aromatic hydrocarbons (PAHs) are of current interest in chemistry. Based upon global structural searches and B3LYP and CCSD(T) calculations, we present herein the perfectly planar dicyclic boron sulfide clusters: D{sub 2h} B{sub 6}S{sub 6} (1, {sup 1}A{sub g}), D{sub 2h} B{sub 6}S{sub 6}{sup −} (2, {sup 2}B{sub 3u}), and D{sub 2h} B{sub 6}S{sub 6}{sup 2−} (3, {sup 1}A{sub g}). These are the global minima of the systems, being at least 0.73, 0.81, and 0.53 eV lower in energy, respectively, than their alternative isomers at the CCSD(T) level. The D{sub 2h} structures feature twin B{submore » 3}S{sub 2} five-membered rings, which are fused together via a B{sub 2} unit and terminated by two BS groups. Bonding analyses show that the closed-shell B{sub 6}S{sub 6}{sup 2−} (3) cluster possesses 10 delocalized π electrons, closely analogous to the bonding pattern of the aromatic naphthalene C{sub 10}H{sub 8}. The B{sub 6}S{sub 6}{sup −} (2) and B{sub 6}S{sub 6} (1) species are readily obtained upon removal of one or two π electrons from B{sub 6}S{sub 6}{sup 2−} (3). The results build a new analogous relationship between boron sulfide clusters and their PAH counterparts. The B{sub 6}S{sub 6}{sup −} (2) monoanion and B{sub 6}S{sub 6}{sup 2−} (3) dianion can be effectively stabilized in neutral LiB{sub 6}S{sub 6} and Li{sub 2}B{sub 6}S{sub 6} salts, respectively.« less

Plasmon-induced charge separation at two-dimensional gold semishell arrays on SiO{sub 2}@TiO{sub 2} colloidal crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Ling; Nishi, Hiroyasu; Tatsuma, Tetsu, E-mail: tatsuma@iis.u-tokyo.ac.jp

2015-10-01

Photoelectrodes based on plasmonic Au semishell (or halfshell) arrays are developed. A colloidal crystal consisting of SiO{sub 2}@TiO{sub 2} core-shell particles is prepared on a TiO{sub 2}-coated transparent electrode. A Au semishell (or halfshell) array is deposited by sputtering or evaporation on the colloidal crystal. An electrode with the semishell (or halfshell) array exhibits negative photopotential shifts and anodic photocurrents under visible light at 500-800 nm wavelengths in an aqueous electrolyte containing an electron donor. In particular, hydroquinone and ethanol are good electron donors. The photocurrents can be explained in terms of plasmon-induced charge separation at the Au-TiO{sub 2} interface.

Evaluating Water Budget Closure Across Spatial Scales: An Observational Approach through Texas Water Observatory

NASA Astrophysics Data System (ADS)

Gaur, N.; Jaimes, A.; Vaughan, S.; Morgan, C.; Moore, G. W.; Miller, G. R.; Everett, M. E.; Lawing, M.; Mohanty, B.

2017-12-01

Applications varying from improving water conservation practices at the field scale to predicting global hydrology under a changing climate depend upon our ability to achieve water budget closure. 1) Prevalent heterogeneity in soils, geology and land-cover, 2) uncertainties in observations and 3) space-time scales of our control volume and available data are the main factors affecting the percentage of water budget closure that we can achieve. The Texas Water Observatory presents a unique opportunity to observe the major components of the water cycle (namely precipitation, evapotranspiration, root zone soil moisture, streamflow and groundwater) in varying eco-hydrological regions representative of the lower Brazos River basin at multiple scales. The soils in these regions comprise of heavy clays that swell and shrink to create complex preferential pathways in the sub-surface, thus, making the hydrology in this region difficult to quantify. This work evaluates the water budget of the region by varying the control volume in terms of 3 temporal (weekly, monthly and seasonal) and 3 different spatial scales. The spatial scales are 1) Point scale - that is typical for process understanding of water dynamics, 2) Eddy Covariance footprint scale - that is typical of most eco-hydrological applications at the field scale and, 3) Satellite footprint scale- that is typically used in regional and global hydrological analysis. We employed a simple water balance model to evaluate the water budget at all scales. The point scale water budget was assessed using direct observations from hydro-geo-thematically located observation locations within different eddy covariance footprints. At the eddy covariance footprint scale, the sub-surface of each eddy covariance footprint was intensively characterized using electromagnetic induction (EM 38) and the resultant data was used to calculate the inter-point variability to upscale the sub-surface storage while the satellite scale water budget was evaluated using SMAP satellite observations supplemented with reanalysis products. At the point scale, we found differences in sub-surface storage in the same land-cover depending on the landscape position of the observation point while land-cover significantly affected water budget at the larger scales.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shertz, R.D.; Kender, W.J.; Musselman, R.C.

Three cultivars of greenhouse-grown apple trees (Malus domestica, Borkh.) were fumigated for single, 4-hour exposures with ozone (O/sub 3/) and/or sulfur dioxide (SO/sub 2/) at 0.40 and 0.80 ppm. Fumigations were performed in a plexiglass chamber situated within a controlled environment walk-in growth chamber. All 3 cultivars responded to treatments in a similar manner. When applied separately both gases induced characteristic foliar injury. In general, apple trees were more sensitive to 0.40 ppm O/sub 3/ than to 0.40 ppm SO/sub 2/; but they responded similarly to 0.80 ppm O/sub 3/ or SO/sub 2/. Foliar injury, leaf abscission, and shoot growthmore » reduction were greatest when 0.80 ppm O/sub 3/ and 0.80 ppm SO/sub 2/ were combined. The data showed a less-than additive response when the 2 pollutants were combined; a response due, in part, to the high amount of injury induced by single pollutants at these concentrations. All O/sub 3/ and/or SO/sub 2/ fumigations resulted in stomatal closure.« less

Multi-scale hierarchy of Chelydra serpentina: microstructure and mechanical properties of turtle shell.

PubMed

Balani, Kantesh; Patel, Riken R; Keshri, Anup K; Lahiri, Debrupa; Agarwal, Arvind

2011-10-01

Carapace, the protective shell of a freshwater snapping turtle, Chelydra serpentina, shields them from ferocious attacks of their predators while maintaining light-weight and agility for a swim. The microstructure and mechanical properties of the turtle shell are very appealing to materials scientists and engineers for bio-mimicking, to obtain a multi-functional surface. In this study, we have elucidated the complex microstructure of a dry Chelydra serpentina's shell which is very similar to a multi-layered composite structure. The microstructure of a turtle shell's carapace elicits a sandwich structure of waxy top surface with a harder sub-surface layer serving as a shielding structure, followed by a lamellar carbonaceous layer serving as shock absorber, and the inner porous matrix serves as a load-bearing scaffold while acting as reservoir of retaining water and nutrients. The mechanical properties (elastic modulus and hardness) of various layers obtained via nanoindentation corroborate well with the functionality of each layer. Elastic modulus ranged between 0.47 and 22.15 GPa whereas hardness varied between 53.7 and 522.2 MPa depending on the microstructure of the carapace layer. Consequently, the modulus of each layer was represented into object oriented finite element (OOF2) modeling towards extracting the overall effective modulus of elasticity (~4.75 GPa) of a turtle's carapace. Stress distribution of complex layered structure was elicited with an applied strain of 1% in order to understand the load sharing of various composite layers in the turtle's carapace. Copyright © 2011 Elsevier Ltd. All rights reserved.

The effects of school closures on influenza outbreaks and pandemics: systematic review of simulation studies.

PubMed

Jackson, Charlotte; Mangtani, Punam; Hawker, Jeremy; Olowokure, Babatunde; Vynnycky, Emilia

2014-01-01

School closure is a potential intervention during an influenza pandemic and has been investigated in many modelling studies. To systematically review the effects of school closure on influenza outbreaks as predicted by simulation studies. We searched Medline and Embase for relevant modelling studies published by the end of October 2012, and handsearched key journals. We summarised the predicted effects of school closure on the peak and cumulative attack rates and the duration of the epidemic. We investigated how these predictions depended on the basic reproduction number, the timing and duration of closure and the assumed effects of school closures on contact patterns. School closures were usually predicted to be most effective if they caused large reductions in contact, if transmissibility was low (e.g. a basic reproduction number <2), and if attack rates were higher in children than in adults. The cumulative attack rate was expected to change less than the peak, but quantitative predictions varied (e.g. reductions in the peak were frequently 20-60% but some studies predicted >90% reductions or even increases under certain assumptions). This partly reflected differences in model assumptions, such as those regarding population contact patterns. Simulation studies suggest that school closure can be a useful control measure during an influenza pandemic, particularly for reducing peak demand on health services. However, it is difficult to accurately quantify the likely benefits. Further studies of the effects of reactive school closures on contact patterns are needed to improve the accuracy of model predictions.

RELAP-7 Closure Correlations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zou, Ling; Berry, R. A.; Martineau, R. C.

The RELAP-7 code is the next generation nuclear reactor system safety analysis code being developed at the Idaho National Laboratory (INL). The code is based on the INL’s modern scientific software development framework, MOOSE (Multi-Physics Object Oriented Simulation Environment). The overall design goal of RELAP-7 is to take advantage of the previous thirty years of advancements in computer architecture, software design, numerical integration methods, and physical models. The end result will be a reactor systems analysis capability that retains and improves upon RELAP5’s and TRACE’s capabilities and extends their analysis capabilities for all reactor system simulation scenarios. The RELAP-7 codemore » utilizes the well-posed 7-equation two-phase flow model for compressible two-phase flow. Closure models used in the TRACE code has been reviewed and selected to reflect the progress made during the past decades and provide a basis for the colure correlations implemented in the RELAP-7 code. This document provides a summary on the closure correlations that are currently implemented in the RELAP-7 code. The closure correlations include sub-grid models that describe interactions between the fluids and the flow channel, and interactions between the two phases.« less

SN 2009ip: CONSTRAINING THE LATEST EXPLOSION PROPERTIES BY ITS LATE-PHASE LIGHT CURVE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moriya, Takashi J., E-mail: moriyatk@astro.uni-bonn.de

We constrain the explosion and circumstellar properties at the 2012b event of SN 2009ip based on its recently reported late-phase bolometric light curve. The explosion energy and ejected mass at the 2012b event are estimated as 0.01 M{sub ⊙} and 2 × 10{sup 49} erg, respectively. The circumstellar medium is assumed to have two components: an inner shell and an outer wind. The inner shell, which is likely created at the 2012a event, has a mass of 0.2 M{sub ⊙}. The outer wind is created by the wind mass loss before the 2012a mass ejection, and the progenitor is estimatedmore » to have had a mass-loss rate of about 0.1 M{sub ⊙} yr{sup −1} with a wind velocity of 550 km s{sup −1} before the 2012a event. The estimated explosion energy and ejected mass indicate that the 2012b event is not caused by a regular SN.« less

X-RAY EMISSION FROM THE WOLF-RAYET BUBBLE S 308

DOE Office of Scientific and Technical Information (OSTI.GOV)

Toala, J. A.; Guerrero, M. A.; Chu, Y.-H.

The Wolf-Rayet (WR) bubble S 308 around the WR star HD 50896 is one of the only two WR bubbles known to possess X-ray emission. We present XMM-Newton observations of three fields of this WR bubble that, in conjunction with an existing observation of its northwest quadrant, map most of the nebula. The X-ray emission from S 308 displays a limb-brightened morphology, with a central cavity {approx}22' in size and a shell thickness of {approx}8'. This X-ray shell is confined by the optical shell of ionized material. The spectrum is dominated by the He-like triplets of N VI at 0.43more » keV and O VII at 0.57 keV, and declines toward high energies, with a faint tail up to 1 keV. This spectrum can be described by a two-temperature optically thin plasma emission model (T{sub 1} {approx} 1.1 Multiplication-Sign 10{sup 6} K, T{sub 2} {approx} 13 Multiplication-Sign 10{sup 6} K), with a total X-ray luminosity {approx}2 Multiplication-Sign 10{sup 33} erg s{sup -1} at the assumed distance of 1.5 kpc.« less

Tailoring characteristic thermal stability of Ni-Au binary nanocrystals via structure and composition engineering: theoretical insights into structural evolution and atomic inter-diffusion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Bangquan; Wang, Hailong; Xing, Guozhong

We report on the structural evolution and atomic inter-diffusion characteristics of the bimetallic Ni-Au nanocrystals (NCs) by molecular dynamics simulations studies. Our results reveal that the thermal stability dynamics of Ni-Au NCs strongly depends on the atomic configurations. By engineering the structural construction with Ni:Au = 1:1 atomic composition, compared with core-shell Au@Ni and alloy NCs, the melting point of core-shell Ni@Au NCs is significantly enhanced up to 1215 K. Unexpectedly, with atomic ratio of Au:Ni= 1:9, the melting process initiates from the atoms in the shell of Ni@Au and alloy NCs, while starts from the core of Au@Ni NCs.more » The corresponding features and evolution process of structural motifs, mixing and segregation are illustrated via a series of dynamic simulations videos. Moreover, our results revealed that the face centered cubic phase Au{sub 0.75}Ni{sub 0.25} favorably stabilizes in NCs form but does not exist in the bulk counterpart, which elucidates the anomalies of previously reported experimental results on such bimetallic NCs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tam, M.S.; Antal, M.J. Jr.

A novel, three-step process for the production of high-quality activated carbons from macadamia nut shell and coconut shell charcoals is described. In this process the charcoal is (1) heated to a high temperature (carbonized), (2) oxidized in air following a stepwise heating program from low (ca. 450 K) to high (ca. 660 K) temperatures (oxygenated), and (3) heated again in an inert environment to a high temperature (activated). By use of this procedure, activated carbons with surface areas greater than 1,000 m{sub 2}/g are manufactured with an overall yield of 15% (based on the dry shell feed). Removal of carbonmore » mass by the development of mesopores and macropores is largely responsible for increases in the surface area of the carbons above 600 m{sub 2}/g. Thus, the surface area per gram of activated carbon can be represented by an inverse function of the yield for burnoffs between 15 and 60%. These findings are supported by mass-transfer calculations and pore-size distribution measurements. A kinetic model for gasification of carbon by oxygen, which provides for an Eley-Rideal type reaction of a surface oxide with oxygen in air, fits the measured gasification rates reasonably well over the temperature range of 550--660 K.« less

The Far-Ultraviolet Spectra of Two Hot PG1159 Stars

NASA Technical Reports Server (NTRS)

Werner, K.; Rauch, T.; Kruk, J. W.

2016-01-01

PG 1159 stars are hot, hydrogen-deficient (pre-) white dwarfs with atmospheres mainly composed of helium, carbon, and oxygen. The unusual surface chemistry is the result of a late helium-shell flash. Observed element abundances enable us to test stellar evolution models quantitatively with respect to their nucleosynthesis products formed near the helium-burning shell of the progenitor asymptotic giant branch stars. Because of the high effective temperatures (T(sub eff)), abundance determinations require ultraviolet spectroscopy and non-local thermodynamic equilibrium model atmosphere analyses. Up to now, we have presented results for the prototype of this spectral class and two cooler members (T(sub eff) in the range 85,000-140,000 K). Here we report on the results for two even hotter stars (PG 1520+525 and PG 1144+005, both with T(sub eff) = 150,000 K) which are the only two objects in this temperature-gravity region for which useful far-ultraviolet spectra are available, and revisit the prototype star. Previous results on the abundances of some species are confirmed, while results on others (Si, P, S) are revised. In particular, a solar abundance of sulphur is measured in contrast to earlier claims of a strong S deficiency that contradicted stellar evolution models. For the first time, we assess the abundances of Na, Al, andCl with newly constructed non-LTE model atoms. Besides the main constituents (He, C, O), we determine the abundances (or upper limits) of N, F, Ne, Na, Al, Si, P, S, Cl, Ar, and Fe. Generally, good agreement with stellar models is found.

Magnetic anisotropy of metal functionalized phthalocyanine 2D networks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Guojun; Zhang, Yun; Xiao, Huaping, E-mail: hpxiao@xtu.edu.cn

2016-06-15

The magnetic anisotropy of metal including Cr, Mn, Fe, Co, Mo, Tc, Ru, Rh, W, Re, Os, Ir atoms functionalized phthalocyanine networks have been investigated with first-principles calculations. The magnetic moments can be expressed as 8-n μ{sub B} with n the electronic number of outmost d shell in the transition metals. The huge magnetocrystalline anisotropy energy (MAE) is obtained by torque method. Especially, the MAE of Re functionalized phthalocyanine network is about 20 meV with an easy axis perpendicular to the plane of phthalocyanine network. The MAE is further manipulated by applying the external biaxial strain. It is found thatmore » the MAE is linear increasing with the external strain in the range of −2% to 2%. Our results indicate an effective approach to modulate the MAE for practical application. - Graphical abstract: The charge density redistribution (ρ{sub MPc}-ρ{sub M}-ρ{sub Pc}) and spin density of the CoPc molecule, from top- and side-views. Purple and green isosurfaces indicate charge depletion and accumulation, respectively. Display Omitted.« less

76 FR 4373 - Notice of Temporary Closure of Caves With Significant Bat Resources on Public Lands in New Mexico

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-25

... Temporary Closure of Caves With Significant Bat Resources on Public Lands in New Mexico AGENCY: Bureau of... temporary closure of caves and abandoned mines (sites) with significant bat resources is in effect on public... bat populations from white- nosed syndrome. DATES: This closure will be in effect from January 25...

Burn Wound Healing and Tissue Engineering.

PubMed

Singer, Adam J; Boyce, Steven T

In 2016 the American Burn Association held a State of the Science conference to help identify burn research priorities for the next decade. The current paper summarizes the work of the sub-committee on Burn Wound Healing and Tissue Engineering. We first present the priorities in wound healing research over the next 10 years. We then summarize the current state of the science related to burn wound healing and tissue engineering including determination of burn depth, limiting burn injury progression, eschar removal, management of microbial contamination and wound infection, measuring wound closure, accelerating wound healing and durable wound closure, and skin substitutes and tissue engineering. Finally, a summary of the round table discussion is presented.

/sup 45/Ca efflux for myometrial cells: comparison of the effects of prostaglandin F/sub 2/. cap alpha. (PGF/sub 2/), oxytocin (OT) and arachidonate (A)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katona, G.; Molnar, M.; Toth, M.

1986-03-01

The aim of this study was to measure PGF/sub 2..cap alpha../-induced Ca/sup 2 +/ release from uterine cells and to compare this to the actions of OT and A. Smooth muscle cells isolated from the uterus (shell gland) of laying hens were cultured for 7 days in M199 plus 10% fetal calf serum. The cells were treated with digitonin (20..mu..M) and preloaded with /sup 45/Ca for 40 min. Addition of PGF/sub 2..cap alpha../ caused a biphasic /sup 45/Ca-efflux. There was a small but significant /sup 45/Ca-release within 30 sec (rapid phase) followed by a larger one within 7 min (slowmore » phase). In comparison, both OT and A stimulated /sup 45/Ca efflux during a single, slow phase. The maximal effect of A was observed at < 7 min, whereas that of OT was slower, peaking after 7 min. Mepacrin, an inhibitor of A release, attenuated the action of OT without having any effect on A promoted /sup 45/Ca-efflux. Indomethacin, an inhibitor of PG synthase, failed to suppress the Ca-releasing effect of A suggesting the A itself or a lipoxygenase product may have been responsible for the observed effects. Moreover, these results provide suggestive evidence that A release is an important step in the action of various uterotonic agents converging on the mobilization of intracellular Ca.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Young, B.C.; Musich, M.A.

A fixed-bed reactor system with continuous Hg{sup 0} analysis capabilities was used to evaluate commercial carbon sorbents for the removal of elemental mercury from simulated flue gas. The objectives of the program were to compare the sorbent effectiveness under identical test conditions and to identify the effects of various flue gas components on elemental mercury sorption. Sorbents tested included steam-activated lignite, chemical-activated hardwood and bituminous coal, iodated steam-activated coconut shell, and sulfur-impregnated steam-activated bituminous coal. The iodated carbon was the most effective carbon, showing over 99% mercury removal according to EPA Method 101A. Data indicate that O{sub 2} (4 vol%)more » and SO{sub 2} (500 ppm) improved the mercury removal of the other carbons for tests at 150{degrees}C using 100 {mu}g/m{sup 3} Hg{sup 0}. Further, the presence of HCl (at 50 ppm) produced a magnitude increase in mercury removal for the steam-activated and sulfur-impregnated bituminous coal-based carbons.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shi, X. M.; Wang, X. D., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn; Yu, Q.

The atomic structures of Al{sub 89}Y{sub 11}, Al{sub 90}Y{sub 6.5}La{sub 3.5}, and Al{sub 82.8}Y{sub 6.07}Ni{sub 8}La{sub 3.13} metallic glasses have been studied by using high energy X-ray diffraction, X-ray absorption fine structure combined with the ab initio molecular dynamics and reverse Monte Carlo simulations. It is demonstrated that the partial replacement of Y atoms by La has limited improvement of the glass forming ability (GFA), although La atoms reduce the ordering around Y atoms and also the fractions of icosahedron-like polyhedra centered by Al atoms. In contrast, Ni atoms can significantly improve the GFA, which are inclined to locate inmore » the shell of polyhedra centered by Al, Y, and La atoms, mainly forming Ni-centered icosahedron-like polyhedra to enhance the spatial connectivity between clusters and suppress the crystallization.« less

Seasonality of bottom water temperature in the northern North Sea reconstructed from the oxygen isotope composition of the bivalve Arctica islandica

NASA Astrophysics Data System (ADS)

Trofimova, Tamara; Andersson, Carin; Bonitz, Fabian

2017-04-01

The seasonality of temperature changes is an important characteristic of climate. However, observational data for the ocean are only available for the last 150 year from a limited number of locations. Prior to 18th century information is only available from proxy reconstructions. The vast majority of such reconstructions depend on land-based archives, primarily from dendrochronology. Established marine proxy records for the ocean, especially at high latitudes, are both sparsely distributed and poorly resolved in time. Therefore, the identification and development of proxies for studying key ocean processes at sub-annual resolution that can extend the marine instrumental record is a clear priority in marine climate science. In this study, we have developed a record of early Holocene seasonal variability of bottom water temperature from the Viking Bank in the northern most North Sea. This area is of a particular interest since the hydrography is controlled by the inflow of Atlantic water. The reconstruction is based on the oxygen isotope composition of the growth increments in two sub-fossil shells of Arctica islandica (Bivalvia), dated to 9600-9335 cal. yr BP. By combining radiocarbon dating and sclerochronological techniques a floating chronology spanning over 200 years was constructed. Using the chronology as an age model, oxygen isotope measurements from 2 shells were combined into a 22-years long record. The results from this oxygen isotope record are compared with stable oxygen isotope profiles from modern shells to estimate changes in the mean state and seasonality between present and early Holocene. Shell-derived oxygen isotope values together with ice-volume corrected oxygen isotope values for the seawater were used to calculate bottom-water temperatures on a sub-annual time-scale. Preliminary results of the reconstructed early Holocene bottom water temperature indicate higher seasonality and lower minimum temperature compared to the present.

Theoretical analysis of aqueous solutions of mixed strong electrolytes by a smaller-ion shell electrostatic model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fraenkel, Dan, E-mail: dfraenkel@eltronresearch.com

2014-02-07

In spite of the great importance of mixed electrolytes in science and technology, no compelling theoretical explanation has been offered yet for the thermodynamic behavior of such systems, such as their deviation from ideality and the variation of their excess functions with ionic composition and concentration. Using the newly introduced Smaller-ion Shell treatment – an extension of the Debye–Hückel theory to ions of dissimilar size (hence DH–SiS) – simple analytic mathematical expressions can be derived for the mean and single-ion activity coefficients of binary electrolyte components of ternary ionic systems. Such expressions are based on modifying the parallel DH–SiS equationsmore » for pure binary ionic systems, by adding to the three ion-size parameters – a (of counterions), b{sub +} (of positive coions), and b{sub −} (of negative coions) – a fourth parameter. For the (+ + −) system, this is “b{sub ++},” the contact distance between non-coion cations. b{sub ++} is derived from fits with experiment and, like the other b’s, is constant at varying ion concentration and combination. Four case studies are presented: (1) HCl–NaCl–H{sub 2}O, (2) HCl–NH{sub 4}Cl–H{sub 2}O, (3) (0.01 M HX)–MX–H{sub 2}O with X = Cl, Br, and with M = Li, Na, K, Cs, and (4) HCl–MCl{sub n}–H{sub 2}O with n = 2, M = Sr, Ba; and n = 3, M = Al, Ce. In all cases, theory is fully consistent with experiment when using a of the measured binary electrolyte as the sole fitting parameter. DH–SiS is thus shown to explain known “mysteries” in the behavior of ternary electrolytes, including Harned rule, and to adequately predict the pH of acid solutions in which ionized salts are present at different concentrations.« less

Resolving the Shell of the Superbubble 30 Doradus C with Chandra

NASA Astrophysics Data System (ADS)

Lopez, Laura

2017-09-01

We propose to observe the superbubble (SB) 30 Doradus C (30 Dor C) with ACIS-S for 100 ks to resolve and characterize the non-thermal shell, point sources, and the young supernova remnant (SNR) J0536 6913 at sub-arcsecond scales. 30 Dor C has been imaged off axis repeatedly by Chandra due to its proximity to SN 1987A, but the majority of the shell has only been observed <20 ks at off-axis distances of >10 arcminutes. The on-axis spatial resolution, sensitivity, and low background of ACIS-S are necessary to disentangle point sources from diffuse emission, to localize synchrotron filaments associated with accelerated electrons, and to investigate the SNR J0536 6913.

Auger Up-Conversion of Low-Intensity Infrared Light in Engineered Quantum Dots

DOE PAGES

Makarov, Nikolay S.; Lin, Qianglu; Pietryga, Jeffrey M.; ...

2016-11-29

One source of efficiency losses in photovoltaic cells is their transparency toward solar photons with energies below the band gap of the absorbing layer. This loss can be reduced using a process of up-conversion whereby two or more sub-band-gap photons generate a single above-gap exciton. Traditional approaches to up-conversion, such as nonlinear two-photon absorption (2PA) or triplet fusion, suffer from low efficiency at solar light intensities, a narrow absorption bandwidth, nonoptimal absorption energies, and difficulties for implementing in practical devices. We show that these deficiencies can be alleviated using the effect of Auger up-conversion in thick-shell PbSe/CdSe quantum dots. Thismore » process relies on Auger recombination whereby two low-energy, core-based excitons are converted into a single higher-energy, shell-based exciton. When compared to their monocomponent counterparts, the tailored PbSe/CdSe heterostructures feature enhanced absorption cross-sections, a higher efficiency of the “productive” Auger pathway involving re-excitation of a hole, and longer lifetimes of both core- and shell-localized excitons. These features lead to effective up-conversion cross-sections that are more than 6 orders of magnitude higher than for standard nonlinear 2PA, which allows for efficient up-conversion of continuous wave infrared light at intensities as low as a few watts per square centimeter.« less

Field-portable supercritical CO{sub 2} extractor

DOEpatents

Wright, B.W.; Zemanian, T.S.; Robins, W.H.; Woodcock, L.J.

1997-06-10

The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending there between, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell. 10 figs.

Field-portable supercritical CO.sub.2 extractor

DOEpatents

Wright, Bob W.; Zemanian, Thomas S.; Robins, William H.; Woodcock, Leslie J.

1997-01-01

The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending therebetween, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell.

Enclosed ground-flare incinerator

DOEpatents

Wiseman, Thomas R.

2000-01-01

An improved ground flare is provided comprising a stack, two or more burner assemblies, and a servicing port so that some of the burner assemblies can be serviced while others remain in operation. The burner assemblies comprise a burner conduit and nozzles which are individually fitted to the stack's burner chamber and are each removably supported in the chamber. Each burner conduit is sealed to and sandwiched between a waste gas inlet port and a matching a closure port on the other side of the stack. The closure port can be opened for physically releasing the burner conduit and supplying sufficient axial movement room for extracting the conduit from the socket, thereby releasing the conduit for hand removal through a servicing port. Preferably, the lower end of the stack is formed of one or more axially displaced lower tubular shells which are concentrically spaced for forming annular inlets for admitting combustion air. An upper tubular exhaust stack, similarly formed, admits additional combustion air for increasing the efficiency of combustion, increasing the flow of exhausted for improved atmospheric dispersion and for cooling the upper stack.

Mesenchymal stromal cells reverse hypoxia-mediated suppression of α-smooth muscle actin expression in human dermal fibroblasts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Faulknor, Renea A.; Olekson, Melissa A.; Nativ, Nir I.

During wound healing, fibroblasts deposit extracellular matrix that guides angiogenesis and supports the migration and proliferation of cells that eventually form the scar. They also promote wound closure via differentiation into α-smooth muscle actin (SMA)-expressing myofibroblasts, which cause wound contraction. Low oxygen tension typical of chronic nonhealing wounds inhibits fibroblast collagen production and differentiation. It has been suggested that hypoxic mesenchymal stromal cells (MSCs) secrete factors that promote wound healing in animal models; however, it is unclear whether these factors are equally effective on the target cells in a hypoxic wound environment. Here we investigated the impact of MSC-derived solublemore » factors on the function of fibroblasts cultured in hypoxic fibroblast-populated collagen lattices (FPCLs). Hypoxia alone significantly decreased FPCL contraction and α-SMA expression. MSC-conditioned medium restored hypoxic FPCL contraction and α-SMA expression to levels similar to normoxic FPCLs. (SB431542), an inhibitor of transforming growth factor-β{sub 1} (TGF-β{sub 1})-mediated signaling, blocked most of the MSC effect on FPCL contraction, while exogenous TGF-β{sub 1} at levels similar to that secreted by MSCs reproduced the MSC effect. These results suggest that TGF-β{sub 1} is a major paracrine signal secreted by MSCs that can restore fibroblast functions relevant to the wound healing process and that are impaired in hypoxia. - Highlights: • Fibroblasts were cultured in collagen lattices (FPCLs) as model contracting wounds. • Hypoxia decreased FPCL contraction and fibroblast α-smooth muscle actin expression. • Mesenchymal stromal cells (MSCs) restored function of hypoxic fibroblasts. • MSCs regulate fibroblast function mainly via secreted transforming growth factor-β{sub 1}.« less

PI3 kinase is involved in cocaine behavioral sensitization and its reversal with brain area specificity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Xiuwu; Mi Jing; Wetsel, William C.

Phosphatidylinositol 3-kinase (PI3K) is an important signaling molecule involved in cell differentiation, proliferation, survival, and phagocytosis, and may participate in various brain functions. To determine whether it is also involved in cocaine sensitization, we measured the p85{alpha}/p110 PI3K activity in the nuclear accumbens (NAc) shell, NAc core, and prefrontal cortex (PFC) following establishment of cocaine sensitization and its subsequent reversal. Naive rats were rank-ordered and split into either daily cocaine or saline pretreatment group based on their locomotor responses to an acute cocaine injection (7.5 mg/kg, i.p.). These two groups were then injected with cocaine (40 mg/kg, s.c.) or salinemore » for 4 consecutive days followed by 9-day withdrawal. Cocaine sensitization was subsequently reversed by 5 daily injections of the D{sub 1}/D{sub 2} agonist pergolide (0.1 mg/kg, s.c.) in combination with the 5-HT{sub 3} antagonist ondansetron (0.2 mg/kg, s.c., 3.5 h after pergolide injection). After another 9-day withdrawal, behavioral cocaine sensitization and its reversal were confirmed with an acute cocaine challenge (7.5 mg/kg, i.p.), and animals were sacrificed the next day for measurement of p85{alpha}/p110 PI3K activity. Cocaine-sensitized animals exhibited increased PI3K activity in the NAc shell, and this increase was reversed by combined pergolide/ondansetron treatment, which also reversed behavioral sensitization. In the NAc core and PFC, cocaine sensitization decreased and increased the PI3K activity, respectively. These changes, in contrast to that in the NAc shell, were not normalized following the reversal of cocaine-sensitization. Interestingly, daily injections of pergolide alone in saline-pretreated animals induced PI3K changes that were similar to the cocaine sensitization-associated changes in the NAc core and PFC but not the NAc shell; furthermore, these changes in saline-pretreated animals were prevented by ondansetron given 3.5 h after pergolide. The present study suggests that selective enhancement of the PI3K activity in the NAc shell may be one of key alterations underlying the long-term cocaine sensitization. To the extent cocaine sensitization is an important factor in human cocaine abuse, pharmacological interventions targeted toward the NAc shell PI3K alteration may be useful in cocaine abuse treatment.« less

Household Effects of School Closure during Pandemic (H1N1) 2009, Pennsylvania, USA

PubMed Central

Palekar, Rakhee S.; Sodha, Samir V.; Kent, Charlotte K.; Fagan, Ryan P.; Archer, W. Roodly; Edelson, Paul J.; Marchbanks, Tiffany; Bhattarai, Achuyt; Swerdlow, David; Ostroff, Stephen; Meltzer, Martin I.

2010-01-01

To determine the effects of school closure, we surveyed 214 households after a 1-week elementary school closure because of pandemic (H1N1) 2009. Students spent 77% of the closure days at home, 69% of students visited at least 1 other location, and 79% of households reported that adults missed no days of work to watch children. PMID:20678335

Household effects of school closure during pandemic (H1N1) 2009, Pennsylvania, USA.

PubMed

Gift, Thomas L; Palekar, Rakhee S; Sodha, Samir V; Kent, Charlotte K; Fagan, Ryan P; Archer, W Roodly; Edelson, Paul J; Marchbanks, Tiffany; Bhattarai, Achuyt; Swerdlow, David; Ostroff, Stephen; Meltzer, Martin I

2010-08-01

To determine the effects of school closure, we surveyed 214 households after a 1-week elementary school closure because of pandemic (H1N1) 2009. Students spent 77% of the closure days at home, 69% of students visited at least 1 other location, and 79% of households reported that adults missed no days of work to watch children.

Microsolvation of the potassium ion with aromatic rings: comparison between hexafluorobenzene and benzene.

PubMed

Marques, J M C; Llanio-Trujillo, J L; Albertí, M; Aguilar, A; Pirani, F

2013-08-22

We employ a recently developed methodology to study structural and energetic properties of the first solvation shells of the potassium ion in nonpolar environments due to aromatic rings, which is important to understand the selectivity of several biochemical phenomena. Our evolutionary algorithm is used in the global optimization study of clusters formed of K(+) solvated with hexafluorobenzene (HFBz) molecules. The global intermolecular interaction for these clusters has been decomposed in HFBz-HFBz and in K(+)-HFBz contributions, using a potential model based on different decompositions of the molecular polarizability of hexafluorobenzene. Putative global minimum structures of microsolvation clusters up to 21 hexafluorobenzene molecules were obtained and compared with the analogous K(+)-benzene clusters reported in our previous work (J. Phys. Chem. A 2012, 116, 4947-4956). We have found that both K(+)-(Bz)n and K(+)-(HFBz)n clusters show a strong magic number around the closure of the first solvation shell. Nonetheless, all K(+)-benzene clusters have essentially the same first solvation shell geometry with four solvent molecules around the ion, whereas the corresponding one for K(+)-(HFBz)n is completed with nine HFBz species, and its structural motif varies as n increases. This is attributed to the ion-solvent interaction that has a larger magnitude for K(+)-Bz than in the case of K(+)-HFBz. In addition, the ability of having more HFBz than Bz molecules around K(+) in the first solvation shell is intimately related to the inversion in the sign of the quadrupole moment of the two solvent species, which leads to a distinct ion-solvent geometry of approach.

Primary closure versus delayed closure for non bite traumatic wounds within 24 hours post injury.

PubMed

Eliya-Masamba, Martha C; Banda, Grace W

2013-10-22

Acute traumatic wounds are one of the common reasons why people present to the emergency department. Primary closure has traditionally been reserved for traumatic wounds presenting within six hours of injury and considered 'clean' by the attending surgeon, with the rest undergoing delayed primary closure as a means of controlling wound infection. Primary closure has the potential benefit of rapid wound healing but poses the potential threat of increased wound infection. There is currently no evidence to guide clinical decision-making on the best timing for closure of traumatic wounds. To determine the effect on time to healing of primary closure versus delayed closure for non bite traumatic wounds presenting within 24 hours post injury. To explore the adverse effects of primary closure compared with delayed closure for non bite traumatic wounds presenting within 24 hours post injury. In May 2013, for this first update we searched the Cochrane Wounds Group Specialised Register; the Cochrane Central Register of Controlled Trials (CENTRAL) (The Cochrane Library); Ovid MEDLINE; Ovid MEDLINE (In-Process & Other Non-Indexed Citations); Ovid EMBASE; and EBSCO CINAHL. There were no restrictions with respect to language, date of publication or study setting. Randomised controlled trials comparing primary closure with delayed closure of non bite traumatic wounds. Two review authors independently evaluated the results of the searches against the inclusion criteria. No studies met the inclusion criteria for this review. Since no studies met the inclusion criteria, neither a meta-analysis nor a narrative description of studies was possible. There is currently no systematic evidence to guide clinical decision-making regarding the timing for closure of traumatic wounds. There is a need for robust research to investigate the effect of primary closure compared with delayed closure for non bite traumatic wounds presenting within 24 hours of injury.

Intriguing structures and magic sizes of heavy noble metal nanoclusters around size 55 governed by relativistic effect and covalent bonding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, X. J.; Xue, X. L.; Jia, Yu

Nanoclusters usually display exotic physical and chemical properties due to their intriguing geometric structures in contrast to their bulk counterparts. By means of first-principles calculations within density functional theory, we find that heavy noble metal Pt{sub N} nanoclusters around the size N = 55 begin to prefer an open configuration, rather than previously reported close-packed icosahedron or core-shell structures. Particularly, for Pt{sub N}, the widely supposed icosahedronal magic cluster is changed to a three-atomic-layered structure with D{sub 6h} symmetry, which can be well addressed by our recently established generalized Wulff construction principle (GWCP). However, the magic number of Pt{sub N}more » clusters around 55 is shifted to a new odd number of 57. The high symmetric three-layered Pt{sub 57} motif is mainly stabilized by the enhanced covalent bonding contributed by both spin-orbital coupling effect and the open d orbital (5d{sup 9}6s{sup 1}) of Pt, which result in a delicate balance between the enhanced Pt–Pt covalent bonding of the interlayers and negligible d dangling bonds on the cluster edges. These findings about Pt{sub N} clusters are also applicable to Ir{sub N} clusters, but qualitatively different from their earlier neighboring element Os and their later neighboring element Au. The magic numbers for Os and Au are even, being 56 and 58, respectively. The findings of the new odd magic number 57 are the important supplementary of the recently established GWCP.« less

Evaporation residue cross-section measurements for 48Ti-induced reactions

NASA Astrophysics Data System (ADS)

Sharma, Priya; Behera, B. R.; Mahajan, Ruchi; Thakur, Meenu; Kaur, Gurpreet; Kapoor, Kushal; Rani, Kavita; Madhavan, N.; Nath, S.; Gehlot, J.; Dubey, R.; Mazumdar, I.; Patel, S. M.; Dhibar, M.; Hosamani, M. M.; Khushboo, Kumar, Neeraj; Shamlath, A.; Mohanto, G.; Pal, Santanu

2017-09-01

Background: A significant research effort is currently aimed at understanding the synthesis of heavy elements. For this purpose, heavy ion induced fusion reactions are used and various experimental observations have indicated the influence of shell and deformation effects in the compound nucleus (CN) formation. There is a need to understand these two effects. Purpose: To investigate the effect of proton shell closure and deformation through the comparison of evaporation residue (ER) cross sections for the systems involving heavy compound nuclei around the ZCN=82 region. Methods: A systematic study of ER cross-section measurements was carried out for the 48Ti+Nd,150142 , 144Sm systems in the energy range of 140 -205 MeV . The measurement has been performed using the gas-filled mode of the hybrid recoil mass analyzer present at the Inter University Accelerator Centre (IUAC), New Delhi. Theoretical calculations based on a statistical model were carried out incorporating an adjustable barrier scaling factor to fit the experimental ER cross section. Coupled-channel calculations were also performed using the ccfull code to obtain the spin distribution of the CN, which was used as an input in the calculations. Results: Experimental ER cross sections for 48Ti+Nd,150142 were found to be considerably smaller than the statistical model predictions whereas experimental and statistical model predictions for 48Ti+144Sm were of comparable magnitudes. Conclusion: Though comparison of experimental ER cross sections with statistical model predictions indicate considerable non-compound-nuclear processes for 48Ti+Nd,150142 reactions, no such evidence is found for the 48Ti+144Sm system. Further investigations are required to understand the difference in fusion probabilities of 48Ti+142Nd and 48Ti+144Sm systems.

Theoretical investigation of the relative stability of Na{sup +}He{sub n} (n = 2–24) clusters: Many-body versus delocalization effects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Issaoui, Noureddine, E-mail: issaoui-noureddine@yahoo.fr; Abdessalem, Kawther; Ghalla, Houcine

2014-11-07

The solvation of the Na{sup +} ion in helium clusters has been studied theoretically using optimization methods. A many-body empirical potential was developed to account for Na{sup +}–He and polarization interactions, and the most stable structures of Na{sup +}He{sub n} clusters were determined using the basin-hopping method. Vibrational delocalization was accounted for using zero-point energy corrections at the harmonic or anharmonic levels, the latter being evaluated from quantum Monte Carlo simulations for spinless particles. From the static perspective, many-body effects are found to play a minor role, and the structures obtained reflect homogeneous covering up to n = 10, followedmore » by polyicosahedral packing above this size, the cluster obtained at n = 12 appearing particularly stable. The cationic impurity binds the closest helium atoms sufficiently to negate vibrational delocalization at small sizes. However, this snowball effect is obliterated earlier than shell completion, the nuclear wavefunctions of {sup 4}He{sub n}Na{sup +} with n = 5–7, and n > 10 already exhibiting multiple inherent structures. The decrease in the snowball size due to many-body effects is consistent with recent mass spectrometry measurements.« less

Noise pollution limits metal bioaccumulation and growth rate in a filter feeder, the Pacific oyster Magallana gigas

PubMed Central

Charifi, Mohcine; Miserazzi, Alison; Sow, Mohamedou; Perrigault, Mickael; Gonzalez, Patrice; Ciret, Pierre; Benomar, Soumaya

2018-01-01

Shipping has increased dramatically in recent decades and oysters can hear them. We studied the interaction between noise pollution and trace metal contamination in the oyster Magallana gigas. Four oyster-groups were studied during a 14-day exposure period. Two were exposed to cadmium in the presence of cargo ship-noise ([Cd++]w ≈ 0.5 μg∙L-1; maximum sound pressure level 150 dBrms re 1 μPa), and 2 were exposed only to cadmium. The Cd concentration in the gills ([Cd]g) and the digestive gland ([Cd]dg), the valve closure duration, number of valve closures and circadian distribution of opening and closure, the daily shell growth-rate and the expression of 19 genes in the gills were studied. Oysters exposed to Cd in the presence of cargo ship-noise accumulated 2.5 times less Cd in their gills than did the controls without ship noise and their growth rate was 2.6 times slower. In the presence of ship noise, oysters were closed more during the daytime, and their daily valve activity was reduced. Changes in gene activity in the gills were observed in 7 genes when the Cd was associated with the ship noise. In the absence of ship noise, a change in expression was measured in 4 genes. We conclude that chronic exposure to cargo ship noise has a depressant effect on the activity in oysters, including on the volume of the water flowing over their gills (Vw). In turn, a decrease in the Vw and valve-opening duration limited metal exposure and uptake by the gills but also limited food uptake. This latter conclusion would explain the slowing observed in the fat metabolism and growth rate. Thus, we propose that cargo ship noise exposure could protect against metal bioaccumulation and affect the growth rate. This latter conclusion points towards a potential risk in terms of ecosystem productivity. PMID:29617387

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elihn, K.; Landstroem, L.; Alm, O.

Iron nanoparticles enclosed in carbon shells were formed by laser-assisted chemical vapor decomposition of ferrocene (Fe(C{sub 5}H{sub 5}){sub 2}) vapor in Ar gas atmosphere. The particle size dependence on the total ambient gas pressure and on laser fluence of the pulsed ArF excimer laser was examined and, e.g., an effective size decrease of the iron core was observed at elevated laser fluences. Characterizations of the iron and carbon microstructures were performed by x-ray diffraction and transmission electron microscopy, while relative iron deposition rates were measured by x-ray fluorescence spectroscopy. Both {alpha}-Fe and {gamma}-Fe phases were found for the single crystallinemore » iron cores, surrounded by graphitic (inner) and amorphous (outer) carbon layers. The temperature rise of the laser-excited particles was also determined by optical spectroscopy of the emitted thermal radiation, which allowed an estimation of the iron loss of the nanoparticles due to evaporation. The estimated and measured iron losses are in good agreement.« less

Doublet-spacing enhancement caused by {Lambda}N-{Sigma}N coupling in {sub {Lambda}L}i hypernuclear isotopes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Umeya, Atsushi; Harada, Toru; Research Center for Physics and Mathematics, Osaka Electro-Communication University, Neyagawa, Osaka 572-8530

2011-03-15

We theoretically investigate energy spacings of doublets in {sub {Lambda}L}i hypernuclear isotopes with A=7-10 in shell-model calculations with a {Lambda}N-{Sigma}N coupling effect. The calculated results show that the energy shifts are {Delta}{epsilon}=0.09-0.28 MeV and the {Sigma}-mixing probabilities are P{sub {Sigma}}=0.10%-0.34% in {Lambda} ground states for the isotopes because of the {Lambda}N-{Sigma}N coupling in the first-order perturbation. It is found that the energy spacing of the doublet is enhanced as a neutron number N increases; the contribution of the {Lambda}N-{Sigma}N coupling interaction is comparable to that of the {Lambda}N interaction in the neutron-rich {Lambda} hypernuclei. The coherent mechanism of this doublet-spacingmore » enhancement is also discussed in terms of Fermi-type and Gamow-Teller-type {Lambda}N-{Sigma}N couplings.« less

Identification of Selected Child-Resistant Closures (Continuous Thread, Lug-Bayonet, and Snap Closures).

ERIC Educational Resources Information Center

Gross, Rosalind L.; White, Harry E.

This publication describes a selected group of child-resistant closures used in packaging five categories of medicine and household products. The material in the document was collected to train survey personnel to identify closures for a planned household study of the effectiveness of child-resistant packaging. The 39 closures described are of…

Search for long lived heaviest nuclei beyond the valley of stability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chowdhury, P. Roy; Samanta, C.; Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000

2008-04-15

The existence of long lived superheavy nuclei (SHN) is controlled mainly by spontaneous fission and {alpha}-decay processes. According to microscopic nuclear theory, spherical shell effects at Z=114, 120, 126 and N=184 provide the extra stability to such SHN to have long enough lifetime to be observed. To investigate whether the so-called 'stability island' could really exist around the above Z, N values, the {alpha}-decay half-lives along with the spontaneous fission and {beta}-decay half-lives of such nuclei are studied. The {alpha}-decay half-lives of SHN with Z=102-120 are calculated in a quantum tunneling model with DDM3Y effective nuclear interaction using Q{sub {alpha}}more » values from three different mass formulas prescribed by Koura-Uno-Tachibana-Yamada (KUTY), Myers-Swiatecki (MS), and Muntian-Hofmann-Patyk-Sobiczewski (MMM). Calculation of spontaneous fission (SF) half-lives for the same SHN are carried out using a phenomenological formula and compared with SF half-lives predicted by Smolanczuk et al. A possible source of discrepancy between the calculated {alpha}-decay half-lives of some nuclei and the experimental data of GSI, JINR-FLNR, RIKEN, is discussed. In the region of Z=106-108 with N{approx}160-164, the {beta}-stable SHN {sub 106}{sup 268}Sg{sub 162} is predicted to have highest {alpha}-decay half-life (T{sub {alpha}}{approx}3.2 h) using Q{sub {alpha}} value from MMM. Interestingly, it is much greater than the recently measured T{sub {alpha}} ({approx}22 s) of deformed doubly magic {sub 108}{sup 270}Hs{sub 162} nucleus. A few fission-survived long-lived SHN which are either {beta}-stable or having large {beta}-decay half-lives are predicted to exist near {sup 294}110{sub 184}, {sup 293}110{sub 183}, {sup 296}112{sub 184}, and {sup 298}114{sub 184}. These nuclei might decay predominantly through {alpha}-particle emission.« less

SCBUCKLE user's manual: Buckling analysis program for simple supported and clamped panels

NASA Technical Reports Server (NTRS)

Cruz, Juan R.

1993-01-01

The program SCBUCKLE calculates the buckling loads and mode shapes of cylindrically curved, rectangular panels. The panel is assumed to have no imperfections. SCBUCKLE is capable of analyzing specially orthotropic symmetric panels (i.e., A(sub 16) = A(sub 26) = 0.0, D(sub 16) = D(sub 26) = 0.0, B(sub ij) = 0.0). The analysis includes first-order transverse shear theory and is capable of modeling sandwich panels. The analysis supports two types of boundary conditions: either simply supported or clamped on all four edges. The panel can be subjected to linearly varying normal loads N(sub x) and N(sub y) in addition to a constant shear load N(sub xy). The applied loads can be divided into two parts: a preload component; and a variable (eigenvalue-dependent) component. The analysis is based on the modified Donnell's equations for shallow shells. The governing equations are solved by Galerkin's method.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cieza, Lucas A.; Mathews, Geoffrey S.; Kraus, Adam L.

We present deep Sparse Aperture Masking (SAM) observations obtained with the ESO Very Large Telescope of the pre-transitional disk object FL Cha (SpT = K8, d = 160 pc), the disk of which is known to have a wide optically thin gap separating optically thick inner and outer disk components. We find non-zero closure phases, indicating a significant flux asymmetry in the K{sub S} -band emission (e.g., a departure from a single point source detection). We also present radiative transfer modeling of the spectral energy distribution of the FL Cha system and find that the gap extends from 0.06{sup +0.05}{submore » -0.01} AU to 8.3 {+-} 1.3 AU. We demonstrate that the non-zero closure phases can be explained almost equally well by starlight scattered off the inner edge of the outer disk or by a (sub)stellar companion. Single-epoch, single-wavelength SAM observations of transitional disks with large cavities that could become resolved should thus be interpreted with caution, taking the disk and its properties into consideration. In the context of a binary model, the signal is most consistent with a high-contrast ({Delta}K{sub S} {approx} 4.8 mag) source at a {approx}40 mas (6 AU) projected separation. However, the flux ratio and separation parameters remain highly degenerate and a much brighter source ({Delta}K{sub S} {approx} 1 mag) at 15 mas (2.4 AU) can also reproduce the signal. Second-epoch, multi-wavelength observations are needed to establish the nature of the SAM detection in FL Cha.« less

Efficient electrocatalytic conversion of CO.sub.2 to CO using ligand-protected Au.sub.25 clusters

DOEpatents

Kauffman, Douglas; Matranga, Christopher; Qian, Huifeng; Jin, Rongchao; Alfonso, Dominic R.

2015-09-22

An apparatus and method for CO.sub.2 reduction using an Au.sub.25 electrode. The Au.sub.25 electrode is comprised of ligand-protected Au.sub.25 having a structure comprising an icosahedral core of 13 atoms surrounded by a shell of six semi-ring structures bonded to the core of 13 atoms, where each semi-ring structure is typically --SR--Au--SR--Au--SR or --SeR--Au--SeR--Au--SeR. The 12 semi-ring gold atoms within the six semi-ring structures are stellated on 12 of the 20 faces of the icosahedron of the Au.sub.13 core, and organic ligand --SR or --SeR groups are bonded to the Au.sub.13 core with sulfur or selenium atoms. The Au.sub.25 electrode and a counter-electrode are in contact with an electrolyte comprising CO.sub.2 and H+, and a potential of at least -0.1 volts is applied from the Au.sub.25 electrode to the counter-electrode.

Metal explosion chambers: designing, manufacturing, application

NASA Astrophysics Data System (ADS)

Stoyanovskii, O. I.; Zlobin, B. S.; Shtertser, A. A.; Meshcheryakov, Y. P.

2017-10-01

Designing of explosion chambers is based on research investigations of the chamber body stress-strain state, which is determined by numerical computation and experimentally by the strain gage technique. Studies show that chamber bottoms are the most loaded elements, and maximal stresses arise in chamber poles. Increasing the shell thickness around poles by welding-in an insert is a simple and saving way to solve this problem. There are structural solutions, enabling reliable hermetic closure and preventing leakage of detonation products from the chamber. Explosion chambers are employed in scientific research and in different industrial applications: explosive welding and hardening, synthesis of new materials, disposal of expired ammunition, and etc.

ORNL actinide materials and a new detection system for superheavy nuclei

NASA Astrophysics Data System (ADS)

Rykaczewski, Krzysztof P.; Roberto, James B.; Brewer, Nathan T.; Utyonkov, Vladimir K.

2016-12-01

The actinide resources and production capabilities at Oak Ridge National Laboratory (ORNL) are reviewed, including potential electromagnetic separation of rare radioactive materials. The first experiments at the Dubna Gas Filled Recoil Separator (DGFRS) with a new digital detection system developed at ORNL and University of Tennessee Knoxville (UTK) are presented. These studies used 240Pu material provided by ORNL and mixed-Cf targets made at ORNL. The proposal to use an enriched 251Cf target and a large dose of 58Fe beam to reach the N = 184 shell closure and to observe new elements with Z = 124, 122 and 120 is discussed.

Mg/Ca, Sr/Ca, and stable isotopes in modern and Holocene Protothaca staminea shells from a northern California coastal upwelling region

USGS Publications Warehouse

Takesue, R.K.; VanGeen, A.

2004-01-01

This study explores the potential of intertidal Protothaca staminea shells as high-resolution geochemical archives of environmental change in a coastal upwelling region. Mg/Ca and Sr/Ca ratios were analyzed by excimer laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) at sub-weekly temporal resolution in shells growing ???1 mm per month. Growth patterns of a modern P. staminea shell from Humboldt Bay, California, collected in December 1999 made it possible to infer a lifespan from 1993 to 1998. Growth hiatuses in the shell may have excluded records of extreme events. Mg/Ca ratios appeared to be partly controlled by water temperature; the correlation coefficient between temperature and Mg/Ca was r = 0.71 in one of four growth increments. Significant year-to-year differences in the sensitivity of Mg/Ca to temperature in P. staminea could not be explained, however. Sr/Ca ratios appeared to be more closely related to shell growth rate. Oxygen isotopes, measured at 2-week temporal resolution in the same shell, did not show a clear relation to local temperature in summer, possibly because temperatures were higher and less variable at the King Salmon mudflat, where the shell was collected, than in the main channel of Humboldt Bay, where water properties were monitored. Negative shell ??13C values (<-0.5???) marked spring and summer coastal upwelling events. The Mg contents of P. staminea midden shells dated to ???3 ka and ???9 ka were significantly lower than in the modern shell. This may have resulted from degradation of a Mg-rich shell organic matrix and precluded quantitative interpretation of the older high-resolution records. Elevated ??13C values in the ???3 ka shell suggested that the individual grew in highly productive or stratified environment, such as a shallow coastal embayment or lagoon. Copyright ?? 2004 Elsevier Ltd.

Cost-Effectiveness of Percutaneous Closure of the Left Atrial Appendage in Atrial Fibrillation Based on Results From PROTECT AF Versus PREVAIL.

PubMed

Freeman, James V; Hutton, David W; Barnes, Geoffrey D; Zhu, Ruo P; Owens, Douglas K; Garber, Alan M; Go, Alan S; Hlatky, Mark A; Heidenreich, Paul A; Wang, Paul J; Al-Ahmad, Amin; Turakhia, Mintu P

2016-06-01

Randomized trials of left atrial appendage (LAA) closure with the Watchman device have shown varying results, and its cost effectiveness compared with anticoagulation has not been evaluated using all available contemporary trial data. We used a Markov decision model to estimate lifetime quality-adjusted survival, costs, and cost effectiveness of LAA closure with Watchman, compared directly with warfarin and indirectly with dabigatran, using data from the long-term (mean 3.8 year) follow-up of Percutaneous Closure of the Left Atrial Appendage Versus Warfarin Therapy for Prevention of Stroke in Patients With Atrial Fibrillation (PROTECT AF) and Prospective Randomized Evaluation of the Watchman LAA Closure Device in Patients With Atrial Fibrillation (PREVAIL) randomized trials. Using data from PROTECT AF, the incremental cost-effectiveness ratios compared with warfarin and dabigatran were $20 486 and $23 422 per quality-adjusted life year, respectively. Using data from PREVAIL, LAA closure was dominated by warfarin and dabigatran, meaning that it was less effective (8.44, 8.54, and 8.59 quality-adjusted life years, respectively) and more costly. At a willingness-to-pay threshold of $50 000 per quality-adjusted life year, LAA closure was cost effective 90% and 9% of the time under PROTECT AF and PREVAIL assumptions, respectively. These results were sensitive to the rates of ischemic stroke and intracranial hemorrhage for LAA closure and medical anticoagulation. Using data from the PROTECT AF trial, LAA closure with the Watchman device was cost effective; using PREVAIL trial data, Watchman was more costly and less effective than warfarin and dabigatran. PROTECT AF enrolled more patients and has substantially longer follow-up time, allowing greater statistical certainty with the cost-effectiveness results. However, longer-term trial results and postmarketing surveillance of major adverse events will be vital to determining the value of the Watchman in clinical practice. © 2016 American Heart Association, Inc.

Growth rates and geochemical proxies in Late Campanian bivalves - New insights from micro-X-ray Fluorescence mapping and numerical growth modelling

NASA Astrophysics Data System (ADS)

de Winter, Niels; Goderis, Steven; van Malderen, Stijn; Vanhaecke, Frank; Claeys, Philippe

2017-04-01

Understanding the Late Cretaceous greenhouse climate is of vital importance for understanding present and future climate change. While a lot of good work has been done to reconstruct climate in this interesting period, most paleoclimatic studies have focused on long-term climate change[1]. Alternatively, multi-proxy records from marine bivalves provide us with a unique opportunity to study past climate on a seasonal scale. However, previous fossil bivalve studies have reported ambiguous results with regard to the interpretation of trace element and stable isotope proxies in marine bivalve shells[2]. One major problem in the interpretation of such records is the bivalve's vital effect and the occurrence of disequilibrium fractionation during bivalve growth. Both these problems are linked to the annual growth cycle of marine bivalves, which introduces internal effects on the incorporation of isotopes and trace elements into the shell[3]. Understanding this growth cycle in extinct bivalves is therefore of great importance for the interpretation of seasonal proxy records in their shells. In this study, three different species of extinct Late Campanian bivalves (two rudist species and one oyster species) that were found in the same stratigraphic interval are studied. Micro-X-Ray Fluorescence line scanning and mapping of trace elements such as Mg, Sr, S and Zn, calibrated by LA-ICP-MS measurements, is combined with microdrilled stable carbon and oxygen isotope analysis on the well-preserved part of the shells. Data of this multi-proxy study is compared with results from a numerical growth model written in the open-source statistics package R[4] and based on annual growth increments observed in the shells and shell thickness. This growth model is used together with proxy data to reconstruct rates of trace element incorporation into the shell and to calculate the mass balance of stable oxygen and carbon isotopes. In order to achieve this goal, 2D mapping of bivalve shell surfaces is combined with high-precision point measurements and linescans to characterize different carbonate facies within the shell and to model changes in proxy data in three dimensions. Comparison of sub-annual variations in growth rate and shell geometry with proxy data sheds light on the degree to which observed seasonal variations in geochemical proxies are dependent on internal mechanisms of shell growth as opposed to external mechanisms such as climatic and environmental change. The use of three different species of bivalve from the same paleoenvironment allows the examination of species-specific responses to environmental change. This study attempts to determine which proxies in which species of bivalve are suitable for paleoenvironmental reconstruction and will aid future paleoseasonality studies in interpreting seasonally resolved multi-proxy records. References 1 DeConto R.M., et al. Cambridge University Press; 2000. 2 Elliot M, et al., PPP 2009. 3 Steuber T. Geology. 1996. 4 R core team, 2004, www.R-project.org

The 3-D ionization structure and evolution of NGC 7009 (Saturn Nebula)

NASA Astrophysics Data System (ADS)

Sabbadin, F.; Turatto, M.; Cappellaro, E.; Benetti, S.; Ragazzoni, R.

2004-03-01

Tomographic and 3-D analyses for extended, emission-line objects are applied to long-slit ESO NTT + EMMI high-resolution spectra of the intriguing planetary nebula NGC 7009, covered at twelve position angles. We derive the gas expansion law, the diagnostics and ionic radial profiles, the distance and the central star parameters, the nebular photo-ionization model and the spatial recovery of the plasma structure and evolution. The Saturn Nebula (distance≃1.4 kpc, age≃6000 yr, ionized mass≃0.18 M⊙) consists of several interconnected components, characterized by different morphology, physical conditions, excitation and kinematics. We identify four ``large-scale'', mean-to-high excitation sub-systems (the internal shell, the main shell, the outer shell and the halo), and as many ``small-scale'' ones: the caps (strings of low-excitation knots within the outer shell), the ansae (polar, low-excitation, likely shocked layers), the streams (high-excitation polar regions connecting the main shell with the ansae), and an equatorial, medium-to-low excitation pseudo-ring within the outer shell. The internal shell, the main shell, the streams and the ansae expand at Vexp≃4.0 × R arcsec km s-1, the outer shell, the caps and the equatorial pseudo-ring at Vexp≃3.15 × R arcsec km s-1, and the halo at Vexp≃10 km s-1. We compare the radial distribution of the physical conditions and the line fluxes observed in the eight sub-systems with the theoretical profiles coming from the photo-ionization code CLOUDY, inferring that all the spectral characteristics of NGC 7009 are explainable in terms of photo-ionization by the central star, a hot ( log T* ≃4.95) and luminous ( log L*/L⊙≃3.70) 0.60-0.61 M⊙ post-AGB star in the hydrogen-shell nuclear burning phase. The 3-D shaping of the Saturn Nebula is discussed within an evolutionary scenario dominated by photo-ionization and supported by the fast stellar wind: it begins with the superwind ejection (first isotropic, then polar deficient), passes through the neutral, transition phase ({lasting} ≃3000 yr), the ionization start (occurred ≃2000 yr ago), and the full ionization of the main shell (≃1000 yr ago), at last reaching the present days: the whole nebula is optically thin to the UV stellar flux, except the caps (mean latitude condensations in the outer shell, shadowed by the main shell) and the ansae (supersonic ionization fronts along the major axis). Based on observations made with: ESO Telescopes at the La Silla Observatories (program ID 65.I-0524), and the NASA/ESA Hubble Space Telescope, obtained from the data archive at the Space Telescope Institute. Observing programs: GO 6117 (P.I. Bruce Balick), GO 6119 (P.I. Howard Bond) and GO 8390 (P.I. Arsen Hajian). STScI is operated by the association of Universities for Research in Astronomy, Inc. under the NASA contract NAS 5-26555. We extensively apply the photo-ionization code CLOUDY, developed at the Institute of Astronomy of the Cambridge University (Ferland et al. 1998).

Composite thermochemistry of gas phase U(VI)-containing molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bross, David H.; Peterson, Kirk A., E-mail: kipeters@wsu.edu

Reaction energies have been calculated for a series of reactions involving UF{sub 6}, UO{sub 3}, UO{sub 2}(OH){sub 2}, and UO{sub 2}F{sub 2} using coupled cluster singles and doubles with perturbative triples, CCSD(T), with a series of correlation consistent basis sets, including newly developed pseudopotential (PP)- and all-electron (AE) Douglas-Kroll-Hess-based sets for the U atom. The energies were calculated using a Feller-Peterson-Dixon composite approach in which CCSD(T) complete basis set (CBS) limits were combined with a series of additive contributions for spin-orbit coupling, outer-core correlation, and quantum electrodynamics effects. The calculated reaction enthalpies (both PP and AE) were combined with themore » accurately known heat of formation of UF{sub 6} to determine the enthalpies of formation of UO{sub 3}, UO{sub 2}(OH){sub 2}, and UO{sub 2}F{sub 2}. The contribution to the reaction enthalpies due to correlation of the 5s5p5d electrons of U was observed to be very slowly convergent with basis set and at the CBS limit their impact on the final enthalpies was on the order of 1 kcal/mol or less. For these closed shell molecules, spin-orbit effects contributed about 1 kcal/mol to the final enthalpies. Interestingly, the PP and AE approaches yielded quite different spin-orbit contributions (similar magnitude but opposite in sign), but the total scalar plus spin-orbit results from the two approaches agreed to within ∼1 kcal/mol of each other. The final composite heat of formation for UO{sub 2}F{sub 2} was in excellent agreement with experiment, while the two results obtained for UO{sub 3} were just outside the ±2.4 kcal/mol error bars of the currently recommended experimental value. An improved enthalpy of formation (298 K) for UO{sub 2}(OH){sub 2} is predicted from this work to be −288.7 ± 3 kcal/mol, compared to the currently accepted experimental value of −292.7 ± 6 kcal/mol.« less

Avoiding Accountability: How Charter Operators Evade Ohio's Automatic Closure Law. K-12 Education

ERIC Educational Resources Information Center

DePaoli, Jennifer; van Lier, Piet

2013-01-01

Ohio's charter-closure law is touted as one of the toughest in the nation because it requires the automatic closure of charter schools that consistently fail to meet academic standards. Ohio's charter-closure law, which became effective in 2008 and was revised in 2011, calls for automatic closure of schools rated in Academic Emergency for at least…

77 FR 75186 - Notice of Closure, Target Shooting Public Safety Closure on the Lake Mountains in Utah County, UT

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-19

... Closure, Target Shooting Public Safety Closure on the Lake Mountains in Utah County, UT AGENCY: Bureau of... Lake Mountains in Utah County, Utah, to recreational target shooting to protect public safety. This... shooting closure within the described area will remain in effect no longer than two years from December 19...

Thermal-mechanical fatigue crack growth in Inconel X-750

NASA Technical Reports Server (NTRS)

Marchand, N.; Pelloux, R. M.

1984-01-01

Thermal-mechanical fatigue crack growth (TMFCG) was studied in a gamma-gamma' nickel base superalloy Inconel X-750 under controlled load amplitude in the temperature range from 300 to 650 C. In-phase (T sub max at sigma sub max), out-of-phase (T sub min at sigma sub max), and isothermal tests at 650 C were performed on single-edge notch bars under fully reversed cyclic conditions. A dc electrical potential method was used to measure crack length. The electrical potential response obtained for each cycle of a given wave form and R value yields information on crack closure and crack extension per cycle. The macroscopic crack growth rates are reported as a function of delta k and the relative magnitude of the TMFCG are discussed in the light of the potential drop information and of the fractographic observations.

Sclerochronology - a highly versatile tool for mariculture and reconstruction of life history traits of the queen conch, textit{Strombus gigas} (Gastropoda)

NASA Astrophysics Data System (ADS)

Radermacher, Pascal; Schöne, Bernd R.; Gischler, Eberhard; Oschmann, Wolfgang; Thébault, Julien; Fiebig, Jens

2010-05-01

The shell of the queen conch Strombus gigas provides a rapidly growing palaeoenvironmental proxy archive, allowing the detailed reconstruction of important life-history traits such as ontogeny, growth rate and growth seasonality. In this study, modern sclerochronological methods are used to cross-date the palaeotemperatures derived from the shell with local sea surface temperature (SST) records. The growth history of the shell suggests a bimodal seasonality in growth, with the growing season confined to the interval between April and November. In Glovers Reef, offshore Belize, the queen conch accreted shell carbonate at rates of up to 6 mm day-1 during the spring (April-June) and autumn (September-November). However a reduced period of growth occurred during the mid-summer months (July-August). The shell growth patterns indicate a positive response to annual seasonality with regards to precipitation. It seems likely that when precipitation levels are high, food availability is increased as the result of nutrient input to the ecosystem in correspondence with an increase in coastal runoff. Slow growth rates occur when precipitation, and as a consequence riverine runoff, is low. The SST however appears to influence growth only on a secondary level. Despite the bimodal growing season and the winter cessation in growth, the growth rates reconstructed here from two S. gigas shells are among the fastest yet reported for this species. The S. gigas specimens from Belize reached their final shell height (of 22.7 and 23.5 cm in distance between the apex and the siphonal notch) at the transition to adulthood in just 2 years. The extremely rapid growth as observed in this species permits detailed, high-resolution reconstructions of life-history traits where sub-daily resolutions can be achieved with ease. The potential for future studies has yet to be further explored. Queen conch sclerochronology provides an opportunity to recover extremely high-resolution palaeotemperature records, which could be used to improve numeric climate models, where the shells essentially function as mineralized buoys. The shell recorder may also help to reveal changes in biogeochemical dynamics in benthic ecosystems on intra-seasonal timescales in the fossil record. Furthermore, sclerochronology provides a rapid, effective and highly versatile investigative strategy when compared to time- and cost-consuming fieldwork for improving fisheries management and maricultural pursuits.

SPRAY CALCINATION REACTOR

DOEpatents

Johnson, B.M.

1963-08-20

A spray calcination reactor for calcining reprocessin- g waste solutions is described. Coaxial within the outer shell of the reactor is a shorter inner shell having heated walls and with open regions above and below. When the solution is sprayed into the irner shell droplets are entrained by a current of gas that moves downwardly within the inner shell and upwardly between it and the outer shell, and while thus being circulated the droplets are calcined to solids, whlch drop to the bottom without being deposited on the walls. (AEC) H03 H0233412 The average molecular weights of four diallyl phthalate polymer samples extruded from the experimental rheometer were redetermined using the vapor phase osmometer. An amine curing agent is required for obtaining suitable silver- filled epoxy-bonded conductive adhesives. When the curing agent was modified with a 47% polyurethane resin, its effectiveness was hampered. Neither silver nor nickel filler impart a high electrical conductivity to Adiprenebased adhesives. Silver filler was found to perform well in Dow-Corning A-4000 adhesive. Two cascaded hot-wire columns are being used to remove heavy gaseous impurities from methane. This purified gas is being enriched in the concentric tube unit to approximately 20% carbon-13. Studies to count low-level krypton-85 in xenon are continuing. The parameters of the counting technique are being determined. The bismuth isotopes produced in bismuth irradiated for polonium production are being determined. Preliminary data indicate the presence of bismuth207 and bismuth-210m. The light bismuth isotopes are probably produced by (n,xn) reactions bismuth-209. The separation of uranium-234 from plutonium-238 solutions was demonstrated. The bulk of the plutonium is removed by anion exchange, and the remainder is extracted from the uranium by solvent extraction techniques. About 99% of the plutonium can be removed in each thenoyltrifluoroacetone extraction. The viscosity, liquid density, and selfdiffusion coefficient for lanthanum, cerium, and praseodymium were determined. The investigation of phase relationships in the plutonium-cerium-copper ternary system was continued on samples containing a high concentration of copper. These analyses indicate that complete solid solution exists between the binary compounds CeCu/sub 2/ and PuCu/sub 2/, thus forming a quasi-binary system. The study of high temperature ceramic fuel materials has continued with the homogenization and microspheroidization of binary mixtures of plutonium dioxide and zirconium dioxide. Sintering a die-pressed pellet of the mixed powders for one hour at 1450 deg C was not sufficient to completely react the constituents. Complete homogenization was obtained when the pellet was melted in the plasma flame. In addition to the plutonium dioxide-zirconium dioxide microspheres, pure beryllium oxide microspheres were produced in the plasma torch. The electronic distribution functions for the 10% by weight PuO/sub 2/ dissolved in a silicate glass were determined. The plutonium-oxygen interaction at about 2.2A is less than the plutonium-oxygen distance for the 5% PuO/sub 2/. The decrease in the interionic distance is indicative of a stronger plutonium-oxygen association for the more concentrated composition. Potassium plutonium sulfate is being evaluated as a reagent to quantitatively separate plutonium from aqueous solutions. The compound containing two waters of hydration was prepared for thermogravimetric studies using analytically pure plutonium-239. Because of the stability of this compound, it is being evaluated as a calorimetric standard for plutonium-238. (auth)

Numerical Investigation Into Effect of Fuel Injection Timing on CAI/HCCI Combustion in a Four-Stroke GDI Engine

NASA Astrophysics Data System (ADS)

Cao, Li; Zhao, Hua; Jiang, Xi; Kalian, Navin

2006-02-01

The Controlled Auto-Ignition (CAI) combustion, also known as Homogeneous Charge Compression Ignition (HCCI), was achieved by trapping residuals with early exhaust valve closure in conjunction with direct injection. Multi-cycle 3D engine simulations have been carried out for parametric study on four different injection timings in order to better understand the effects of injection timings on in-cylinder mixing and CAI combustion. The full engine cycle simulation including complete gas exchange and combustion processes was carried out over several cycles in order to obtain the stable cycle for analysis. The combustion models used in the present study are the Shell auto-ignition model and the characteristic-time combustion model, which were modified to take the high level of EGR into consideration. A liquid sheet breakup spray model was used for the droplet breakup processes. The analyses show that the injection timing plays an important role in affecting the in-cylinder air/fuel mixing and mixture temperature, which in turn affects the CAI combustion and engine performance.

HR Del REMNANT ANATOMY USING TWO-DIMENSIONAL SPECTRAL DATA AND THREE-DIMENSIONAL PHOTOIONIZATION SHELL MODELS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moraes, Manoel; Diaz, Marcos

2009-12-15

The HR Del nova remnant was observed with the IFU-GMOS at Gemini North. The spatially resolved spectral data cube was used in the kinematic, morphological, and abundance analysis of the ejecta. The line maps show a very clumpy shell with two main symmetric structures. The first one is the outer part of the shell seen in H{alpha}, which forms two rings projected in the sky plane. These ring structures correspond to a closed hourglass shape, first proposed by Harman and O'Brien. The equatorial emission enhancement is caused by the superimposed hourglass structures in the line of sight. The second structuremore » seen only in the [O III] and [N II] maps is located along the polar directions inside the hourglass structure. Abundance gradients between the polar caps and equatorial region were not found. However, the outer part of the shell seems to be less abundant in oxygen and nitrogen than the inner regions. Detailed 2.5-dimensional photoionization modeling of the three-dimensional shell was performed using the mass distribution inferred from the observations and the presence of mass clumps. The resulting model grids are used to constrain the physical properties of the shell as well as the central ionizing source. A sequence of three-dimensional clumpy models including a disk-shaped ionization source is able to reproduce the ionization gradients between polar and equatorial regions of the shell. Differences between shell axial ratios in different lines can also be explained by aspherical illumination. A total shell mass of 9 x 10{sup -4} M {sub sun} is derived from these models. We estimate that 50%-70% of the shell mass is contained in neutral clumps with density contrast up to a factor of 30.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Young, B.C.; Musich, M.A.

A fixed-bed reactor system with continuous Hg{sup 0} analysis capabilities was used to evaluate commercial carbon sorbents for the removal of elemental mercury from simulated flue gas. The objectives of the program were to compare the sorbent effectiveness under identical test conditions and to identify the effects of various flue gas components on elemental mercury sorption. Sorbents tested included steam-activated lignite, chemically activated hardwood, chemically activated bituminous coal, iodated steam-activated coconut shell, and sulfur-impregnated steam-activated bituminous coal. The iodated carbon was the most effective sorbent, showing over 99% mercury removal according to U.S. Environmental Protection Agency (EPA) Method 101A. Datamore » indicate that adding O{sub 2} at 4 vol% reduced the effectiveness of the steam-activated lignite, chemically activated hardwood, and sulfur- impregnated steam-activated bituminous coal. Adding SO{sub 2} at 500 ppm improved the mercury removal of the sulfur-impregnated carbon. Further, the presence of HCl gas (at 50 ppm) produced an order of magnitude increase in mercury removal with the chemically activated and sulfur-impregnated bituminous coal-based carbons.« less

Experimental study of neutron-rich nuclei near the N = 82 closed shell using the {sub 40}{sup 96}Zr+{sub 50}{sup 124}Sn reaction with GASP and PRISMA-CLARA arrays

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodríguez, W.; Torres, D. A.; Cristancho, F.

2014-11-11

In this contribution an experimental study of the deep-inelastic reaction {sub 40}{sup 96}Zr+{sub 50}{sup 124}Sn at 530 MeV, using the GASP and PRISMA-CLARA arrays, is presented. The experiments populate a wealth of projectile-like and target-like binary fragments, in a large neutron-rich region around N ≥ 50 and Z ≈ 40. Preliminary results on the study of the yrast and near-yrast states for {sup 95}Nb will be shown, along with a comparison of the experimental yields obtained in the experiments.

Mobile fishing gear reduces benthic megafaunal production on Georges Bank

USGS Publications Warehouse

Hermsen, J.M.; Collie, J.S.; Valentine, P.C.

2003-01-01

This study addresses the effect of mobile fishing gear disturbance on benthic megafaunal production on the gravel pavement of northern Georges Bank. From 1994 to 2000, we sampled benthic megafauna with a 1 m Naturalists' dredge at shallow (47 to 62 m) and deep (80 to 90 m) sites. The cessation of fishing in large areas of Georges Bank in January 1995 allowed us to monitor changes in production at a previously disturbed site. Production at a shallow disturbed site varied little over the sampling period (32 to 57 kcal m-2 yr-1) and was markedly lower than production at the nearby recovering site, where production increased from 17 kcal m-2yr -1 in 1994 before the closure to 215 kcal m-2 yr -1 in 2000. Atlantic sea scallops Placopecten magellanicus and green sea urchins Strongylocentrotus droebachiensis dominated production at the recovering site. The community production:biomass ratio decreased over time at the recovering site as the sea scallop population matured. At the deep sites, production remained significantly higher at undisturbed sites (174 to 256 kcal m-2 yr-1) than at disturbed sites (30 to 52 kcal m -2 yr-1). The soft-bodied tube-building polychaete Thelepus cincinnatus dominated production at the undisturbed site, while hard-shelled bivalve molluscs Astarte spp. and P. magellanicus were prevalent at the disturbed site. Mobile fishing gear disturbance has a conspicuous effect on benthic megafaunal production in this hard-bottom habitat. Cessation of mobile fishing has resulted in a marked increase in benthic megafaunal production. These findings should help fishery managers to gauge the costs and benefits of management tools such as area closures and low-impact fishing gears.

Increased nuclear energy yields from the fast implosion of cold shells driven by nonlinear laser plasma interactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hora, H.

1976-02-01

The nonlinear interaction force between intense laser fields and cold plasma shells efficiently transforms radiant energy into mechanical energy of implosion. This transfer of energy has been considered before in numerical experiments and it is treated here analytically in a didactic example starting with an inhomogeneous Rayleigh density profile. Up to 50% of the laser energy can be transformed into the energy of compression if a single ''untailored'' pulse of 2.5 x 10/sup 16/ W/cm/sup 2/ intensity and of only a few picosecond duration is used for spherical illumination of a shell. If the pulse is short enough to reducemore » collisional thermalization, then the collapse and compression of the plasma can remain at the threshold of Fermi degeneracy and still be adiabatic. This results in nuclear reaction gains G, based on the deposited energy, E/sub 0/, and without ..cap alpha..-particle reheating, of G=400 for E/sub 0/=2.25 kJ ((D--T reaction), 900 kJ (D--D), 13 MJ (H--B). About 1000 times less laser energy is necessary than in the case of gas dynamic ablation resulting in the same nuclear reaction yields. (AIP)« less